WorldWideScience

Sample records for sakugen ni kakawaru

  1. Fiscal 1996 survey of potential international cooperation for a long-term scenario on CO2 reduction; 1996 nendo CO2 sakugen ni kakawaru choki shinario ni kansuru kokusai kyoryoku kanosei chosa

    NONE

    1997-03-01

    For the purpose of working out a CO2 reduction scenario and a CO2 policy introduction scenario, a survey was conducted of comparisons between ten and several models which are world-known and models of the New Earth 21, potential international cooperation to be carried out in the future, etc. The survey included organizations which are developing CO2 policy evaluation models, survey reports made in the past, details of literature for the analysis and arrangement. From the result, details of the questionnaire survey and organizations to be surveyed were decided on for the questionnaire survey. Objects for the survey were 7 countries and 22 organizations, and survey items were places for information exchange, sending/receiving of researchers, exchange of input data, comparative calculation based on the common database, joint research work, economy, the carbon tax, impact, renewable energy, how to handle and think of the carbon isolation, etc. As a result of the survey, proposed were a workshop on CO2 reduction, a comparative study of simulation models, etc. 25 refs., 50 figs., 12 tabs.

  2. Feasible study of international cooperation on the long-term scenario for reducing CO2. DNE-21 simulation database; CO2 sakugen ni kakawaru choki scenario ni kansuru kokusai kyoryoku kanosei chosa. DNE21 simulation database

    NONE

    1997-03-01

    This report describes calculation codes of DNE-21 which can simulate the optimization model for reducing CO2. The DNE-21 was modified from the former NE-21. The term was set between 2000 and 2100. Optimization can be conducted across the different time. Non-conventional petroleum was removed from the primary energy. Capacity of nuclear power generation facilities was taken in the model for the optimization. Decision making analysis can be done by considering the uncertainty. The DNE-21 has eleven input files including the model operation, technical property related data, cost related data, data of tax, subsidy and customs, and scenario data of future energy demand and supply, GNP, population and nuclear power. The DNE-21 has fifteen output files including the optimization calculation results for the world, Oceania, the Middle East, North Africa, Central America, South America, former USSR, and OECD countries. 2 figs.

  3. Fiscal 1998 research report. Study on the possibility of international cooperation for high- efficiency urban heat use systems for CO{sub 2} reduction; 1998 nendo chosa hokokusho. CO{sub 2} sakugen no tame no toshi netsu riyo system kokoritsuka ni kakawaru kokusai kyoryoku kanosei chosa hokokusho

    NONE

    1999-03-01

    This research aims at study on the possibility of international cooperation such as technology transfer and technical cooperation between developed countries for introduction of high-efficiency urban heat use systems into developing countries from the viewpoint of global warming control. On the case of a city in the south-eastern district in China, this research studies the principle of international cooperation such as technology transfer and research cooperation through survey on social and economical restrictions to their introduction into developing countries and study on a CO{sub 2} reduction effect by the introduction. This report describes the current technology for high-efficiency urban heat use systems in developed countries, the current energy use in Chinese cities and some issues, current heat use technologies, the case study on the potential and constraint of high- efficiency urban heat use systems, and the case study on the CO{sub 2} reduction effect of the high-efficiency urban heat use system. Expectation for Japanese technical cooperation as such international cooperation is described. (NEDO)

  4. Achievement report for fiscal 1995 on the research and development of comprehensive basic technologies on marine resources (manganese nodule mining system) in industrial and scientific technology research and development project. Trends and forecasts of the supply-demand for metal resources (Ni, Co, Cu, Fe, Mn) that are contained in manganese nodules; 1995 nendo kaiyo shigen sogo kiban gijutsu no kenkyu kaihatsu (mangan dankai saiko system) seika hokokusho. Mangan dankai ni kakawaru kinzoku shigen (Ni, Co, Cu, Fe, Mn) no kyokyu ni kansuru shorai doko no suitei

    NONE

    1996-12-01

    Living standards improving in developing countries especially in China are the most influential factor to determine the demand for Cu. Consumption of Ni will depend on the trends of advanced technologies such as Ni-hydrogen battery, fuel cell, shape memory alloy, hydrogen absorbing alloy, in addition to increase in global population and developing countries' living standards improvement. Co is far more dependent on advanced technologies than Ni is. On the land, Ni ore is increasingly lower in quality and Co is being retrieved from by-products of Cu production, both meeting the problem of unstable supply. Consideration is made to apply new extraction methods to Cu production; there are some potential resources for Fe and Mn. The Mn nodule exists in great quantities and is a attractive source of supply, but a long time will be required before it is exploited. It is necessary to speed up the study to exploit the Mn nodule, but first of all the problem of its competition with land resources in terms of cost has to be solved. It needs to be found out at what stage of production the Mn nodule is competitive with land products. In any case, Japan should undertake the efforts of marine resources exploitation leading other countries of the world. (NEDO)

  5. Study of the O2/CO2 combustion technology; Sanso nensho gijutsu ni kakawaru chosa kenkyu

    Kato, M [Center for Coal Utilization, Japan, Tokyo (Japan); Kiga, T; Yamada, T [Ishikawajima-Harima Heavy Industries Co. Ltd., Tokyo (Japan); Arai, K [Nippon Sanso K.K., Tokyo (Japan); Mori, T [Inst. of Research and Innovation, Tokyo (Japan); Kimura, N; Okawa, M [Electric Power Development Co. Ltd., Tokyo (Japan)

    1996-09-01

    This study is being progressed during a period from 1992 to 1999 as part of the NEDO`s clean coal technology program. This paper describes what has been discussed to date. The absorption method and the adsorption method may be used to recover CO2 as means to deal with the problem of global warming resulted from burning coals. These methods, however, have problems in economy caused from concentration of CO2 in flue gas being low. The present study is intended to raise the CO2 concentration in flue gas by using oxygen plus circulated flue gas in the place of combustion air, so that CO2 may be recovered as it is without being separated from the flue gas. Therefore, an oxygen-blown pulverized coal fired power generation plant having a cryogenic oxygen manufacturing equipment was designed to discuss the plant operability and economy, and the pulverized coal combustion technology by using a dynamic simulation. A large number of findings have been obtained already, and the study has reached a level at which grasping the whole image is now possible. 13 figs.

  6. Fiscal 1998 research report. Feasibility study on international cooperation for technology transfer; 1998 nendo chosa hokokusho. Gijutsu iten ni kakawaru kokusai kanosei chosa

    NONE

    1999-03-01

    CTI (Climate Technology Initiative) is a framework for use by developed countries in international cooperation and voluntary promotion of the development and diffusion of technologies contributory to reduction of greenhouse gas emissions. The CTI's activity goal is to accelerate the transfer and diffusion of technologies for climate change control. As the first step toward personnel development programs relating to energy efficiency, CTI organized its workshop on that theme. The results of the workshop have been examined, and its achievements were reported at COP4 meeting, while responses by participatory countries were studied to evaluate the potential of international cooperation with regard to personnel development for reducing greenhouse gas emissions. In fiscal 1998, the CTI workshop 'Energy Efficiency' was held. The participants from developing countries understood the necessity and importance of energy saving enough through discussions in the workshop, and announced their message toward the world at COP4 meeting. (NEDO)

  7. Fiscal 1999 survey report. Survey of feasibility of international cooperation in the transfer of technology; 1999 nendo gijutsu iten ni kakawaru kokusai kyoryoku kanosei chosa hokokusho

    NONE

    2000-03-01

    Among the activity goals of CTI (climate technology initiative), which is a framework designed to encourage international cooperation of leading nations in the voluntary development and diffusion of technologies supposed to contribute to the reduction of greenhouse gas emissions, there is the promotion of the transfer and diffusion of climate change preventing technologies. To achieve the goal, energy efficiency oriented workshops will be held as part of the training for the raising of people skilled in energy saving, the results will be examined, the achievements attained at such events will be introduced at COP5 (Conference of the Parties at Bonn), and the responses of the respective countries will be reviewed, all these for the investigation of the feasibility of international cooperation for raising people dedicated to the reduction of greenhouse gas emission. In this fiscal year, aiming to make clear the possibility of contribution to the transfer of software-related technologies through cooperation of multiple nations, lecturers from leading countries and participants from developing nations met, held a workshop over energy efficiency technologies, and the results were compiled. (NEDO)

  8. Survey on the possibility of international cooperation on production technology of biohydrogen; Bio suiso seizo gijutsu ni kakawaru kokusai kyoryoku kanosei chosa

    NONE

    1997-03-01

    R and D on the production technology of hydrogen by biotechnology is one of the effective projects for worldwide energy supply technology and global environment protection technology in the 21st century. The research trend of various institutions promoting R and D on production technology of biohydrogen in the U.S.A. and other countries was surveyed together with the possibility of international cooperation. The production technology of biohydrogen is being watched over the world. Various researches are in promotion corresponding to environmental conditions as follows: search of not only photosynthetic bacteria but also such bacteria with hydrogen productivity as algae and anaerobic bacteria, and the gene engineering study for improving the hydrogen productivity of target microorganisms. All the institutions visited for this survey have great expectations in wide cooperative study in the future. On the possibility of international cooperation on the production technology of biohydrogen, the further precise survey should be promoted for developing more effective technologies based on the previous survey results. 156 refs., 10 tabs.

  9. Fiscal 2000 report. Feasibility study on international cooperation concerning technology transfer; 2000 nendo gijutsu iten ni kakawaru kokusai kyoryoku kanosei chosa hokokusho

    NONE

    2001-03-01

    A workshop was held concerning technology transfer in the software of environmental technologies, for the purpose of contributing to CTI (Climate Technology Initiative), an international framework for dealing with technological problems in preventing climate change, with the results of the workshop compiled. The workshop was held for a period from September 10 to September 23, 2000; the contents were, for example, an outline on energy conservation, introduction to cleaner production, lectures on related technologies, seminars on actual cases including case studies, factory tours, etc., and discussion session by all participants; and, in general, the workshop was conducted so as to promote understanding on cleaner production and energy conservation. Four lecturers were invited to this workshop from an international organization, U.S. and Japan. In addition, two staff members and two technical consultants from ICETT (the International Center for Environmental Technology Transfer) gave lectures and advice as technology advisers. Three environmental specialists were invited from each of the five countries, China, Indonesia, Thailand, Philippines, and Vietnam. (NEDO)

  10. Feasibility study on the demonstrative test on the hybrid mini hydroelectric power generation technology. 2; Hybrid gata mini suiryoku hatsuden gijutsu ni kakawaru jissho shiken kanosei chosa. 2

    NONE

    1996-03-01

    A study was made for the purpose of electrification of unelectrified zones of the mountainous areas in developing countries using extremely small hydroelectric power facilities. The target for this project is a development of a micro hydroelectric power system with a size of about 5kW, which is estimated regarding that 1 village has 80 houses and each house needs electricity of 60W. In the study, the low-head system using a weir of irrigation channels in Subang pref. of West Java state was selected by the evaluation of access, stability of flow rate, natural conditions, etc. The hydroelectric power plant is of a flow-in method in which water is taken from the left bank and is injected/discharged to the downstream of the left bank. As the hybrid complementary power source, hybrid battery with a two-hour charging time at peak and a capacity of 3.5kWh was considered. When estimating the construction cost of the hybrid micro hydroelectric power system and equalizing by durable years, the operational cost per kW is 15 times higher than the benefits which local people receive. It was judged to be difficult to say that the micro hydroelectric power system is economically feasible. It was predicted that the financial profit during the demonstrative test is good, according to a trial calculation of income from power rates and the operational cost. 18 refs., 90 figs., 53 tabs.

  11. Report on surveys in fiscal 2000 on the surveys and researches in relation to nano-technology; 2000 nendo nano technology ni kakawaru chosa kenkyu hokokusho

    NONE

    2001-03-01

    In order to view over the situation surrounding the nano-technology as a whole, surveys and discussions were given by means of questionnaire and open discussion meetings. In the questionnaire, the answer that the products utilizing nano-scale structure have already been, or scheduled to be put on sale has exceeded half of the total answers. Experts view that the nano-technology is infiltrating steadily into the actual society. In view of the applicable fields, and in the opening discussion meetings, drastic innovation was expected in the industrial technologies in the future not too far away as a dream world, by using the 'nano-technology' that utilizes a principle completely different from the principles that have been practically used. In order to achieve that goal, a recognition was made clear that the braeakthrough in other fields is important, and the field crossing fusion such as coordination with academia, and exchanges between different businesses and different fields is important. In the comparison of competitive edges of Japan, America and Europe, Japan was recognized to possess sufficient competitive power, but the sense of crisis is felt toward the latent technological power of America of the future. (NEDO)

  12. {Gamma}-ray prospecting of major faults of Miocene basins; Chushinto taisekibon no keisei ni kakawaru danso wo taisho to shita hoshano tansa

    Iwata, A. [Shimada Technical Consultants, Ltd., Shimane (Japan); Yamauchi, S.; Adachi, K. [Shimane University, Shimane (Japan); Yoon, S.; Kil, R, [Pusan National University, Pusan (Korea, Republic of)

    1997-05-27

    The Masuda basin in the western edge of Shimane Prefecture and the Pohang basin in the southern part of the east cost of Korea had been formed in the middle of Miocene epoch of Neogene period, and show similarity in their geology and structure. A gamma-ray prospecting was carried out on major faults that have had been involved in forming these basins. A portable gamma-ray analysis device, model 8630 made by Clearpulse Corporation was used for the measurement. Emanation of radon and its migration are known generally, whereas rise in radon is recognized above crevices with deep opening trend. The present faults having been involved in forming the basins are thought to have large falls in positive faults and often accompany crevices with opening trend. This estimation is thought endorsed by the result of the present prospecting. In addition, such faults may often form geological boundaries, and the present survey has had geological division made easily with total gamma-ray. A gamma-ray exploration using both of the spectrum method and the total count method is a process sufficiently utilizable in geological surveys on structures in peripheries of sedimentary basins. 6 refs., 7 figs.

  13. Evaluation report on the development of high-function ultrathin film for new oil refining process; Shinsekiyu seisei process ni kakawaru kinosei chousumaku no kaihatsu

    NONE

    2001-03-01

    This evaluation committee report covers the project entitled 'Development of high-function ultrathin film for new oil refining process' which was under way for three years from fiscal 1998 through 2000. The evaluation committee is so designed that researchers outside the organization responsible for the project performs an objective and impartial evaluation of the national project concerned as to its objective, goal, plan, operation, implementation system, rate of progress toward achievement, and the significance of the results achieved. The committee aims to disclose to the taxpayer the actualities of State-run research and development projects by making them transparent to people's eyes, which is one of the duties of the committee, and to elevate the value of the research results by impartially and duly evaluating them. In this report, the outlines of the project and of the obtained research results are introduced in Chapter 1, and then the details of the evaluation of the project are described in Chapter 2. It is stated that the organic/inorganic laminate membrane fabrication technology utilizing low temperature TiO{sub 2} film formation is evaluated high. It is also stated that the effect of the analysis and evaluation technology is expected to spread and find its use in various industrial fields. (NEDO)

  14. Fiscal 1998 research report. Feasibility study on international cooperation for technology transfer; 1998 nendo chosa hokokusho. Gijutsu iten ni kakawaru kokusai kanosei chosa

    NONE

    1999-03-01

    CTI (Climate Technology Initiative) is a framework for use by developed countries in international cooperation and voluntary promotion of the development and diffusion of technologies contributory to reduction of greenhouse gas emissions. The CTI's activity goal is to accelerate the transfer and diffusion of technologies for climate change control. As the first step toward personnel development programs relating to energy efficiency, CTI organized its workshop on that theme. The results of the workshop have been examined, and its achievements were reported at COP4 meeting, while responses by participatory countries were studied to evaluate the potential of international cooperation with regard to personnel development for reducing greenhouse gas emissions. In fiscal 1998, the CTI workshop 'Energy Efficiency' was held. The participants from developing countries understood the necessity and importance of energy saving enough through discussions in the workshop, and announced their message toward the world at COP4 meeting. (NEDO)

  15. Report on surveys in fiscal 2000 on the surveys and researches in relation to nano-technology; 2000 nendo nano technology ni kakawaru chosa kenkyu hokokusho

    NONE

    2001-03-01

    In order to view over the situation surrounding the nano-technology as a whole, surveys and discussions were given by means of questionnaire and open discussion meetings. In the questionnaire, the answer that the products utilizing nano-scale structure have already been, or scheduled to be put on sale has exceeded half of the total answers. Experts view that the nano-technology is infiltrating steadily into the actual society. In view of the applicable fields, and in the opening discussion meetings, drastic innovation was expected in the industrial technologies in the future not too far away as a dream world, by using the 'nano-technology' that utilizes a principle completely different from the principles that have been practically used. In order to achieve that goal, a recognition was made clear that the braeakthrough in other fields is important, and the field crossing fusion such as coordination with academia, and exchanges between different businesses and different fields is important. In the comparison of competitive edges of Japan, America and Europe, Japan was recognized to possess sufficient competitive power, but the sense of crisis is felt toward the latent technological power of America of the future. (NEDO)

  16. Actual conditions of energy management in office buildings; Results of quetionaire inquiry about load leveling. Gyomu yo biru ni okeru energy kanri no jittai ni tsuite; Fuka heijunka ni kakawaru anketo chosa kekka

    Okubo, Katsuhiko (The Inst. of Applied Energy, Tokyo, (Japan))

    1989-07-20

    The electric power demand in Japan is increasing, and it is expected that annual load factor shows decreasing tendency. All electric power companies endeavor to improve load leveling than as it was, and intend to introduce direct saving system to control the loading equipments of consumers as well as indirect control such as midnight power system. Therefore, quetionaire inquiry about this new system was made for business power consumers in which power there are much difference in consumed power between day and night and much efficacy for power saving. As the results of the inquiry, it was understood that equipment of automatic or remote control for loading equipments were already introduced by many consumers and adoption of airconditioners controlled at every floor or every room is increased. So, about the control of the equipments in cosumers a method is also required so that electric power companies shall control the maximum demand by consumers and selection of control equipments are left on consumers' decision and judgment, and it is considered to be important that control by electric power companies shall not only turn on or off switchs but also realize convenience and economy of consumers. 9 figs., 3 tabs.

  17. FY 2000 Development of technologies for reducing power consumption during the stand-by period. Report on the research and development results of rationally reducing power consumption by home electric appliances; 2000 nendo taikiji shohi denryoku sakugen gijutsu kaihatsu seika hokokusho. Kaden seihin no taikiji shohi denryoku no goriteki sakugen ni kansuru kenkyu kaihatsu

    NONE

    2001-03-01

    The research and development project is implemented for development of the system which automatically switches off the power source for a standing-by appliance by analyzing life pattern in each home, in order to reduce consumed power during the stand-by period. The actual service conditions of appliances in each home are surveyed through the questionnaires and recording in the diary. The analysis results indicate that as high as 70% of those who are inquired take interest in energy saving, especially high among full-time housewives. The home electric appliances considered by many to wastefully consume power are functional-keeping types, e.g., (jar pots) and (toilet seats equipped with a washing function with warm water), and heating appliances, e.g., (hot carpets). The power consumption trends at each time in each home are measured and grasped by the aid of a tool with built-in personal computer, and the algorithm for predicting use of the appliances in each home is developed for each home, based on the analysis results. The prototype energy-saving adapter and centralized controller are developed, and subjected to various tests to develop the learning/controlling algorithms. The demonstration tests of the energy-saving adapter developed confirm that power consumption during the stand-by period can be reduced at least by 10%. (NEDO)

  18. Achievement report for fiscal 1999 on development of technology to promote reduction of discharge of dioxins. Development of technology to reduce discharge of dioxins in steel manufacturing processes; 1999 nendo dioxin rui haishutsu sakugen sokushin gijutsu kaihatsu seika hokokusho. Seiko kotei ni okeru dioxin rui haishutsu sakugen gijutsu kaihatsu

    NONE

    2001-03-01

    Research and development has been performed on a scrap melting process to make dioxins emission concentration to 0.2 ng-TEQ/Nm{sup 3} or less in steel making electric furnaces. The testing facility is of semi-sealed structure, consisting of an arc dissolution furnace, an exhaust gas combustion section, an auxiliary combustion chamber, and a quenching chamber. In the arc dissolution chamber, oxygen and coke are blown in at the same time as turning the arc power supply on, and then secondary combustion air was blown in to burn carbon monoxide gas generated from steel melting. The temperature was raised to about 850 degrees C at which dioxins are decomposed in the auxiliary combustion chamber, and then quenched to 200 degrees C or lower in the quenching chamber to prevent recombination of dioxins. As a result of the test, the exhaust gas temperature after the combustion was estimated to have reached about 900 degrees C at which dioxins are decomposed. In addition, because it was possible to control the exhaust gas temperature at the outlet of the auxiliary combustion chamber to about 850 degrees C and the exhaust gas temperature at the outlet of the quenching chamber to 200 degrees C or lower, the dioxins concentration at the outlet of the quenching chamber was reduced successfully to the targeted value or lower. (NEDO)

  19. FY 2000 report on the results of the development of the stand-by consumption power reduction technology. R and D of the stand-by consumption power reduction technology in relation to machine tools; 2000 nendo taikiji shohi denryoku sakugen gijutsu kaihatsu seika hokokusho. Kosaku kiki ni kanrensuru taikiji shohi denryoku sakugen gijutsu no kenkyu kaihatsu

    NONE

    2001-03-01

    In relation to machine tools, a method was studied for reducing consumption power at the time of standing-by, keeping the present processing accuracy, processing efficiency and operability, and the results of the study were as follows. As to the chip conveyer, the stand-by consumption power was reduced by approximately 75% by reducing the motor capacity by reviewing the effective operation method and the structure. Concerning the mist collector, a reduction of approximately 85% was confirmed by adopting the efficient operation method and high-efficient motor. Relating to the oil controller, an experiment was made on the frame thermal circulation system and the self-forced air cooling system. In terms of the rise in temperature, the controller is lower than the existing one, but it was found out that the consumption power could be reduced by about 14% and about 98%, respectively. About the coolant pump, the optimum inclination angle/necessary minimum flow rate of oil pan were confirmed, and a reduction of 47% was confirmed. As to the hydraulic pump, study was made of a method to substitute other power source for oil pressure and the intermittent operation of hydraulic unit, and effects of each were confirmed. Further studies were made of the control disc, reduction in air consumption, etc. (NEDO)

  20. Basic investigation on promotion of joint implementation in fiscal 2000. Survey on energy saving and CO2 emission reduction in Cilacap Refinery; 2000 nendo kyodo jisshi nado suishin kiso chosa hokokusho. Cilacap seiyusho ni okeru shoene CO2 sakugen chosa

    NONE

    2001-03-01

    With an objective of saving energy and reducing greenhouse gas emission, a basic survey has been performed on the atmospheric crude oil distillation units and the high vacuum distillation units at Cilacap Refinery in Indonesia. The first site survey in September 2000 has carried out a survey on the situation of the facilities and operation upon obtaining the facility data and operation information from Pertamina. As a result, it was revealed that there is a room of improvement in the heat recovery, whereas a modification design was executed on the improvement proposals on the heat exchanger system. However, the second site survey in November 2000 has revealed that Pertamina had executed in 1998 through 1999 the de-bottlenecking project on the crude oil atmospheric distillation units (two units) and the high vacuum distillation units (two units), by which the capability has been expanded, and the heat recovery rate has been increased. It is not possible to look for extremely large enhancement of the heat recovery rate beyond that point, and the reduction of CO2 emission would also be small. As a result of discussions, the present project was found capable of reducing annually the CO2 emission by 36,500 tons. (NEDO)

  1. Dynamic programming for reduction of fuel consumption in a photovoltaic/wind/diesel generating system; Doteki keikakuho ni yoru taiyoko/furyoku/diesel hatsuden system no nenryo shohiryo no sakugen

    Ishikawa, K.; Kenmoku, Y.; Sakakibara, T. [Toyohashi University of Technology, Aichi (Japan); Nakagawa, S. [Maizuru National College of Technology, Kyoto (Japan); Kawamoto, T. [Shizuoka University, Shizuoka (Japan)

    1997-11-25

    Dynamic programming is employed in the study of the operation of the diesel engine in a photovoltaic/wind-force/diesel-engine power generating system, which aims at reduction in the system fuel consumption and at determining an optimum system constitution. The parameters set in this system are the photovoltaic/wind-force supply rate, photovoltaic/wind-force power generation ratio, and battery capacity. An island in Ise Bay, with an annual load power of approximately 1.59-million kWh and mean daily load power of approximately 4336kWh is assumed as the location for the system. Observation data of Ommaezaki Weather Station are utilized for the calculation of the amount of photovoltaic/wind-force power generation. It is found as the result that the fuel consumption of the diesel engine in this system decreases to 82-84% when the natural energy supply rate is 20%. It is also found that the fuel consumption of the system records the minimum at a photovoltaic/wind-force ratio of 60/40, irrespective of the battery capacity or natural energy supply rate, and this ratio is the optimum ratio. 3 refs., 9 figs., 1 tab.

  2. FY 2000 Report on survey results. Curtailment of the carbon dioxide emission by effective use of woody biomass system waste; 2000 nendo mokushitsu biomass kei haikibutsu no yuko riyo ni yoru nisanka tanso haishutsu no sakugen

    NONE

    2001-03-01

    It is estimated that the woody biomass resources in Japan total 42.70 million t/y on a dry basis (indigenous production: 20.00 million t/y), which corresponds to 18.00 million t/y as oil. This project studies effective utilization of low-quality biomass resources now discarded, e.g., thinning materials and demolition woods, by reference to biomass utilization pursued in European and North American countries. The study activities cover the 3 areas of woody biomass wastes, current status of biomass utilization technologies in the overseas countries, and feasibility of introduction of the utilization technologies, after investigating necessity of abatement of the green-effect gases, current status of energy demands and policies, and woody biomass. Utilization of biomass resources for low-temperature heat purposes, which is the central issue in Japan, is not well established both technologically and politically. Moreover, the biomass resources are not exposed to price competition. Based on these premises, a total of 6 scenarios are proposed to promote utilization of biomass resources, including power/heat co-generation at a wood processing center, and dual firing at existing coal-fired boilers. (NEDO)

  3. FY 2000 Fundamental study for promotion of jointed implementations. Feasibility study on reducing greenhouse gas emissions by modernizing Thanlyin Refinery in Myanmar; 2000 nendo Myanmar koku Thanlyin seiyusho kindaika ni yoru onshitsu koka gas haishutsu sakugen kanosei chosa hokokusho

    NONE

    2001-03-01

    The feasibility study was conducted on a project in Myanmar for the energy saving effect and reduction of the greenhouse gas emissions by introducing modern refining facilities in Thanlyin Refinery of Myanmar Petrochemical Enterprise. The project items selected as a result of the study are improvement in the heat recovery efficiency of crude distillation unit, improvement in the furnace efficiency of crude distillation unit and coker plant, improvement in the efficiency of power plant, reduction of steam loss, modernization of the cooling water system, recovery and reuse of off-gas and LPG in crude distillation unit, and modernization of intermediate products run-down system. The conceptual designs and studies on these items indicate that implementation of these projects could lead to energy saving of 25,844 tons/y as crude and CO2 emission abatement of 57,457 tons/y, 46% and 33% reduction from the baseline. The total expenses for all of these items are estimated at 4,300 million yen. These are judged to be promising projects, with estimated investment recovery period of 9 years and internal profit rate of 12.9%, when the special yen loans are available. (NEDO)

  4. Fiscal 1999 research report. Basic research for promotion of joint implementation programs (Survey of energy saving and CO2 reduction at Omsk Refinery); 1999 nendo Omsk seiyusho ni okeru shoene CO{sub 2} sakugen chosa hokokusho

    NONE

    2000-03-01

    The results of basic research conducted for scouting out projects which will attain the goals set forth in the COP3 (Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change) protocol are compiled into a report. The atmospheric distillation unit for crude of the Omsk Refinery sited at Omsk City, Russian Federation, is the object of the research. A feasibility study is made about energy saving and reduction in CO2 emissions using various data acquired by an on-site survey, and seven modification plans are presented. In the preparation of the modification plans, 'the optimization of process systems,' 'the modification of the waste heat boiler,' and 'the installation of a new heating furnace' are taken into consideration. In relation to 'the optimization of process systems,' installation of a new heat exchanger and move to a different location of the existing heat exchanger are suggested in Modification Plan 1 and Modification Plan 2. Ultimately, seven modification plans are reviewed, which are combinations of Modification Plan 1, Modification Plan 2, 'the modification of the waste heat boiler,' and 'the installation of a new heating furnace.' Modification Plan 1 and Modification Plan 2 are attractive because they are high in performance for the small funds they require. Modification Plan 3 which includes 'the installation of a new heating furnace' demands a larger initial investment, but it achieves a greater reduction in CO2 emissions. (NEDO)

  5. Effect of heat-insulating wall on input energy of a photovoltaic/solar/air-heat system for a residence; Jutaku no kodannetsuka ni yoru taiyoko netsu/taiki netsu system no donyu energy sakugen koka

    Kenmoku, Y; Sakakibara, T [Toyohashi University of Technology, Aichi (Japan); Nakagawa, S [Maizuru College of Technology, Kyoto (Japan)

    1996-10-27

    A proposal was made to introduce a photovoltaic/solar/air-heat system which positively utilizes natural energy in order to curtail consumption of fossil energy, corroborating that the system has greatly reduced energy input in the primary energy level in a house. This paper examines the effect of curtailment of energy input in the case of reducing the load of air conditioning through the high heat insulation of a house. The energy input was evaluated by calculating additional equipment energy needed newly for the high heat insulation. The system performance and the energy load varied greatly depending on weather conditions. The subject system consisted of solar cells, inverter, heat concentrator, heat storage tank, heat pump and gas hot-water supply device. The thickening of the insulation sharply reduced heating load in the house, thereby decreasing fuel energy substantially. An insulation material of 100mm thick was capable of reducing energy input by 16-23% compared with that of 50mm thick. 5 refs., 5 figs, 3 tabs.

  6. Simulation study on reduction of peak power demand and energy consumption in residential houses with solar thermal and PV systems; Taiyo energy riyo jutaku no fuka heijunka oyobi energy sakugen koka no simulation ni yoru kento

    Endo, T. [Yokohama City Office, Yokohama (Japan); Udagawa, M. [Kogakuin Univ., Tokyo (Japan). Faculty of Engineering

    1995-11-20

    In this study, taking the all factors involved in the energy consumption in residential houses as subjects, the effectiveness of the solar PV system and solar thermal utilizing system in residential houses has been studied by simulating a model residential house considering the improvement of the residual environment in the future. Therefore, a model residual house is assumed, 18 kinds of combinations of construction style, cooling and heating type and solar energy utilizing form are assumed and year round simulation is carried out. The conclusions obtained by the simulation are as follows. The energy consumption in residential houses may decrease greatly by using a solar hot water supplying system. If combined with a solar PV system, the energy consumption in one year is about 8.7 to 9.7 MWh. The combined use of a solar thermal utilizing system and a PV system is more effective to reduce the second-time energy in comparison with the PV system only. 36% of the space heating energy consumption may be decreased by using the solar space heating system, but the decrease effect of the energy consumption of the solar space heating system is smaller than the solar hot water supplying system. 12 refs., 26 figs., 3 tabs.

  7. Study on reduction of consumption and peak demand of electric power used in residential houses with solar heating and PV systems; Solar house no fuka heijunka to energy sakugen koka ni kansuru kenkyu

    Udagawa, M.; Endo, T. [Kogakuin University, Tokyo (Japan)

    1994-12-08

    A model house was simulated to reduce the consumption and peak demand for the photovoltaic power generation system, and solar heat air heating and hot water supply system in the solar house. As a type of construction, both wooden construction and reinforced concrete (RC) construction were selected with a total floor area of 125m{sup 2}. All the rooms were equipped with an air conditioner by heat pump from the air thermal source. A solar heat floor heater was simultaneously installed on the first floor. The hot water supply load was 4.8MWh per year. A commercial grid-connected on-site system was applied to the photovoltaic power generation with a 20m{sup 2} wide monocrystalline Si solar cell panel. As for the fluctuation in power load, the peak at the time of rising is more reduced in the RC house than in the wooden house, because the former is smaller in temperature fluctuation than the latter during the intermittence of air conditioning (as per the specified operational schedule). Therefore, the power is more leveled off in the former than in the latter. Between both, difference was hardly made in energy consumption per year. The ratio of dependency was 47% upon the photovoltaic power generation system, while it was 50% and 77%, under the air heating power load and hot water supply power load, respectively, upon the solar heat air heating and hot water supply system, so that both systems were considerably effective in saving the energy. 5 refs., 7 figs., 1 tab.

  8. Fiscal 1999 basic survey report for promotion of joint implementation. Study on energy saving and CO2 reduction at Balikpapan refinery; 1999 nendo Balikpapan seiyusho ni okeru shoene CO{sub 2} sakugen chosa hokokusho

    NONE

    2000-03-01

    Concerning the reduction of greenhouse gas emissions for the embodiment of clean development mechanisms (CDMs) in Indonesia, a survey is conducted about energy saving and CO2 reduction at its Balikpapan refinery. At the refinery, a crude-oil atmospheric distillation unit operates at 200,000 BPSD (barrels per stream day) and a vacuum distillation unit at 81,000 BPSD, with the fuel consumed by the two units discharging approximately 470,000 tons/year of CO2. The result of the survey discloses that there is need for some improvement in relation with heat recovery and that the great distance between the two distillation units presents a problem in relation with heat efficiency. To settle the problems, heat recovery will be enhanced and the fuel to be burned in the heating furnace will be reduced. A plan to modify the heat exchanger system is worked out using JGC Corporation's energy-saving technology, and a rough design is drafted for the modification. When the modification is carried out, there will be a CO2 reduction of 18,636-61,597 tons/year. The Pertamina also wants the plan to be realized, wishing that technical and financial aids will be available. The plan when realized will serve as a stimulus to the local community and to the industry as a whole. (NEDO)

  9. Reduction of energy essential to human life by 70%. Environment-friendly residence `ED-1` utilizing the sunlight effectively; Seikatsu ni hitsuyona energy no 70% sakugen. Taiyoko riyo no kankyo kyosei jutaku ED-1

    NONE

    1996-09-01

    This paper presents the environment-friendly residence `ED-1` utilizing the sunlight effectively. ED-1 of 97m{sup 2} in first floor area and 81m{sup 2} in second one has, on its roof, the photovoltaic power generation system, the solar hot water collector which supplies hot water by circulating heated antifreezing solution into a hot storage tank, and the solar hot wind collector which largely contributes to energy saving together with a hot room named an S unit on the first floor. The small S unit faced toward the south adjacent to a dining room is made of timber and thermal insulation glass. The S unit stores heat in a floor by taking the sunlight into a room in winter, while enhances a heating effect by discharging stored heat in nighttime. In some cases, duct circulation of heated wind is possible. Solar radiation of 90% can be removed by outside glass fiber screen of the S unit together with double glazing coated by special metal film. Roof material is superior in heat insulation, air tightness and energy saving, while floor material in sound insulation and heat storage. The target for reducing energy essential to human life by 70% was thus nearly achieved. 1 fig.

  10. Study on strategies in joint implementation and its improvement to reduce CO2 emissions; CO2 sakugen no tame no kyodo jisshi ni okeru senryaku oyobi sono kaizen hosaku no kenkyu

    Matsuhashi, R.; Ishitani, H. [The University of Tokyo, Tokyo (Japan)

    1998-10-01

    In order to reduce greenhouse gas emissions, we have to introduce measures to suppress economic differences between developed countries (DC) and less developed countries (LDC) as well as accelerate technology improvement. In this sense, Joint Implementation (JI) is a promising measure not only to economically reduce greenhouse gas emissions, but also to facilitate technology transfer from DC to LDC. In this article, we first investigated JI strategies, in which LDC can improve industrial energy efficiency under financial support of DC. Strategies of countries involved in JI was represented with Stackelberg game. Analytical results revealed that JI activities may considerably be diminished in Stackelberg equilibrium, depending on shapes of the marginal cost functions of reducing CO2. Therefore we proposed measures to prevent the suppression of JI and quantitatively evaluated the potential of this improved JI system. As far as actual data on economy and industry are concerned, we used the ones of Japan and China, since China has been rapidly increasing its economic scale and greenhouse gas emissions. However implications from these analyses are useful also for other countries. 8 refs., 7 figs.

  11. Fiscal 1999 basic survey for promotion of joint implementation. Overall study report on energy saving and CO2 reduction at Indocement Company; 1999 nendo Indo cement ni okeru shoene CO{sub 2} sakugen sogo chosa hokokusho

    NONE

    2000-03-01

    A study is made about the feasibility of energy saving and CO2 reduction at the Citeureup Plant of the Indocement Company, Indonesia. Future embodiment of a clean development mechanism (CDM) is also discussed. Points examined for improvement involve air quenching clinker cooler (AQC) efficiency (mixing of raw materials, use of combustion control technology, and modification into a new type AQC); the finishing process (installation of a preliminary clinker crusher and a high-efficiency classifier); and waste heat cogeneration using AQC exhaust. The amount of energy to be saved will be 61,866 tons/year in oil, promising a 10.9% energy saving and CO2 reduction. The project requires a fund of 5,988,025,000 yen in total. The financial internal rate of return (FIRR) based on the environmental special yen credit is a little low, but the payout period of 11 years is reasonable. A similar result is obtained when export financing by the ex-Exim Bank is studied. A general loan is not proper in view of overall profitability. With precedents showing that it is near impossible for such a project to enjoy environmental special yen credit, it is necessary for the Japanese Government to build a CDM-oriented system under which environmental special yen credit will be offered to private sectors. (NEDO)

  12. FY 1998 annual report on the CO{sub 2} reduction by 30 manufacturing companies (plants) through energy conservation. Thailand; Seizogyo 30 sha (kojo) no sho energy ni yoru CO{sub 2} haishutsuryo sakugen 1998 nendo chosa hokokusho. Taikoku

    NONE

    1999-03-01

    This project is aimed at energy-saving diagnosis of 30 energy-intensive manufacturing plants in Thailand, to draw the project plans and clarify, e.g., greenhouse effect gas reduction and cost-effectiveness effects, on the basis of transferring and applying the energy management and energy-saving equipment technologies now being used by the manufacturing sector in Japan. The 30 plants analyzed are 6 metal-related plants, 3 non-ferrous plants, 5 chemical plants, 6 ceramics plant, 4 textile plants, 4 food processing plants and 2 pulp plants. Two or more feasible energy-saving measures are studied for each plant. A total of 178 improvement measures (approximately 6 on the average for each plant) are identified as the ones related to energy-saving and operation controlling techniques. These measures could reduce CO2 emissions by 145,000 t/y from 1,370,000 t/y released from the 30 plants. The measures of high cost-effectiveness are (use of an appropriate pressure for air compressors) and (resting of transformers on non-working days). (NEDO)

  13. Effect of insolation forecasting error on reduction of electricity charges for solar hot water system; Taiyonetsu kyuto system no denki ryokin sakugen koka ni oyobosu nissharyo yosoku gosa no eikyo

    Nakagawa, S [Maizuru National College of Technology, Kyoto (Japan); Kenmoku, Y; Sakakibara, T [Toyohashi University of Technology, Aichi (Japan); Kawamoto, T [Shizuoka University, Shizuoka (Japan)

    1996-10-27

    A solar hot water system can be economically operated if inexpensive midnight power is purchased to cover the shortage of solar energy predicted for the following day. Investigations were conducted because error in insolation prediction affects the system operation and electric charge reduction effect. The target temperature of the heat accumulation tank at every predetermined time point is calculated on the previous evening in consideration of predicted insolation so that the water will be as hot as prescribed at the feeding time on the following day. Midnight power is used for uniform heating to attain the target temperature for 7 o`clock on the following morning. The uniform heating continues from 8 o`clock to the feeding time, this time using solar energy and daytime power to attain the target temperature. Accordingly, the division between the midnight power and daytime power is determined in view of the target temperature for 7 o`clock on the following morning, which target temperature is so set that the charge will be the minimum by optimizing the allocation of the above-said two. When the insolation prediction error rate is beyond 30%, the electric charge grows higher as the rate rises. But, when the rate is not higher than 30%, the charge is little affected by a rise in the rate. 5 refs., 10 figs., 1 tab.

  14. FY 2000 report on the basic study/survey on the policy mix for reducing the greenhouse gas emissions; 2000 nendo onshitsu koka gas haishutsu sakugen no policy mix ni kansuru kisoteki kento

    NONE

    2001-03-01

    Described herein are the FY 2000 results of the survey on policies for reducing the greenhouse gas emissions. For Japan to meet the emission reduction targets stated in the Kyoto Protocol, it is necessary to examine in detail what the most desirable policy measures should be for each sector. In this context, it is also essential to determine particular features of the various policies that may include action plans, environment taxes, and emission trading in addition to conventional regulations and subsidy measures, and to assess their anticipated effects and problems. After examining the policies adopted by various countries to reduce greenhouse gas emissions, this study has attempted to identify the merits and demerits of the various emission reduction policies and to present a systematic account of progress achieved in Japan during basic investigations into this issue. This reports provides a systematic overview of the action plans adopted by the other major countries to prevent global warming and makes a comparative study of the contents of the policies that have been introduced by these countries; identifies the arguments raised in the overseas debates on the effects and problems of global warming prevention policies, and attempts to put the arguments into some systematic order; examines the statuses of the current progress made by various countries with regard to methane and N{sub 2}O emission reduction policies, and discusses the related problems; gives a systematic account of how the policy options are being scrutinized by the government as the base for studying the policy mix for Japan; and examines statuses of the current progress made by Japan with regard to methane and N{sub 2}O emission reduction policies. (NEDO)

  15. Fiscal 1999 survey report. Part 2. Research study on restraint of carbon dioxide generation by green chemistry; 1999 nendo green chemistry ni yoru CO{sub 2} hassei yokusei ni kakawaru chosa kenkyu. 2

    NONE

    2000-03-01

    In connection with green chemistry, a concept of bringing paradigm shift to chemical technologies as something that makes reduction in environmental load compatible with economic activities; surveys were made this year on the developments of fine chemicals from renewable resources such as cellulose among the cases of developing chemical substances/products to be called 'green chemicals' reducing environmental load; developments of surfactants produced by certain microorganism, plastic additives with reduced pollutant loads, particularly fire retardants and environmentally benign reactant solvents; concept of green chemistry in the development of chlorofluorocarbon-alternatives; and up-to-date technological level concerning a design method of chemical materials and an estimation method for chemical safety using quantum chemistry calculation. In regard to the chemical materials and products intrinsically containing a certain level of risk, R and D should be reinforced and accelerated in the future on the alternative materials/products reducing their toxicity. In this case, along with the importance of discussing compatibility of technological possibility with economical adaptability, sociological study seems to be necessary in incorporating environmental load reduction into economic evaluation. (NEDO)

  16. Fiscal 1997 survey report. 2. Survey on the preparation of technical information in the APEC region (downstream field); 1997 nendo chosa hokokusho. 2. APEC ikinai ni okeru gijutsu joho seibi ni kakawaru (karyu bun`ya)

    NONE

    1998-03-01

    The Japanese government is conducting the training on the CCT downstream field for the persons concerned in the CCT utilization field in the APEC region, especially in nations as new comer into the CCT utilization field where the coal consumption is expected to rapidly increase (China, Indonesia, Thailand, and the Philippines). The demand for CCT diffusion/education to the persons concerned in coal utilization in the APEC region is increasing from each country, and the CCT diffusion/education is becoming a more and more important issue. Accordingly, for the purpose of increasing the understanding of CCT and improving the ability of the persons concerned in APEC countries, the paper surveyed and arranged the environmental protection technology out of the CCT technical information of Japan, and inputted the results into CD-ROM. The results are planned to be used for the understanding of Japan`s advanced CCT and ability improvement in the CCT training course to be planned for managers and engineers from APEC countries. The CD-ROM includes the coal combustion flue gas related technologies such as desulfurization technology, denitrification technology and dust collecting technology which are the environmental protection technology out of the coal utilization technologies in Japan

  17. FY 2000 Report on the survey results. Survey on international cooperation for development of a system for supporting low-invasion surgical operations; 2000 nendo teishinshu shujutsu shien system kaihatsu ni kakawaru kokusai kyoryoku ni kansuru chosa hokokusho

    NONE

    2001-03-01

    The international Medical Treatment Symposium and Exhibition were held from July 20 to the end of August, 2000 in Hannover in Germany, in which the Japan's system for supporting low-invasion surgical operations was presented and information was exchanged for the system. A total of 50 to 100 neurosurgeons visited the exhibition, held as part of the symposium, every day from July 21 to 24. The system for supporting low-invasion surgical operations is rated as the most advanced one in the world. It attracted much attention, because a number of attendees applied for operating manipulator. The research trends seen in the symposium point to early diagnosis of diseases, finer surgical operations, low-invasion type operations, use of high-function diagnosis devices for improving operations, real-time imaging, and application of DNA diagnosis to pathological diagnosis, among others. Japan is leading the world in the technological areas of micromachines, robotics, high-vision and diagnosis. The bold researches, e.g., those on artificial visual and hearing systems to be embedded in the head, are pursued more extensively in the overseas countries. (NEDO)

  18. Report on surveys in fiscal 2000 on the survey on preparing list of names of well-informed persons in industrial technological fields; 2000 nendo sangyo gijutsu bun'ya ni okeru yushikisha meibo sakutei ni kakawaru chosa hokokusho

    NONE

    2001-03-01

    In order to identify, in establishing plans for industrial technological fields, the well-informed persons from whom useful knowledge and comments can be obtained, a well-informed person survey was conducted by surveying and hearing the roles and selection processes of the well-informed persons inside and outside the country. For the organizations in Japan, the survey was made on Japan Society for the Promotion of Science, and Japan Science Technology Organization. For the organizations outside the country, surveys were made on two organizations in the U.S., one organization in Germany, and one organization in U.K. All of them are the research aiding organizations established to allocate the national budget to the research investments. As compared to Japan, the organizations in foreign countries are characterized as follows: technological fields that are given priority are declared clearly by the organizations; in selecting the publicly advertised projects, the guidelines on the research scope are strict, but flexibility is given in fund allocation; the first screening process is carried out by researchers and scholars in the same technological field, and the second screening is performed by the authorization committee. Extraction of well-informed persons and preparation of a name list were performed for some of the technological fields in Japan by means of the hearing survey. (NEDO)

  19. Outline of investigation on restraint of carbon dioxide generation by green chemistry. 1999.1-1999.3; 1998 nendo green chemistry ni yoru CO2 hassei yokusei ni kakawaru chosa kenkyu chosa hokokusho

    NONE

    1999-03-01

    Investigations were conducted into the above in some leading OECD (Organization for Economic Cooperation and Development) member states. Green chemistry is a new concept in which clean technology, environment-friendly chemistry, and the like are combined, and is a chemical solution for reducing or stopping the use or generation of materials, products, by-products, solvents, reagents, etc., which are dangerous to health and environments, throughout the whole life cycle of chemicals covering the processes of their designing, manufacturing, dumping, and recycling. In this fiscal year, the actual state of the generation of biomass, regarded as representative of reproducible materials, and its feasibility as chemical resources were investigated. In an effort at finding out chemical reactions safer to health and causing less environmental impact, investigations were also conducted into the recent trends of catalysts, novel reactions for organic syntheses, use of supercritical fluids, photocatalysts, biomimetic processes, etc. The development of substitutes for plastic additives was also studied. Since acceptance by the citizenry is quite important for green chemistry to take effect, educating and enlightening activities in the U.S., Britain, France, and Germany were inquired into. (NEDO)

  20. Fiscal 1997 report on the survey of the actual state of various coal related industrial furnaces in China; 1997 nendo chosa hokokusho (Chugoku ni okeru sekitan ni kakawaru kakushu kogyoro no jittai chosa)

    NONE

    1998-03-01

    It is thought that environmental prevention technologies related to boilers which are the largest coal use field in China have been almost all made model projects till now. Further, coal or coke is used in various industrial furnaces except boilers in every industrial sector in China. The amount of coal use there is large next to that in boilers, which is a cause of the country`s serious air pollution. Accordingly, an investigation was commenced in fiscal 1997 aiming at grasping the actual state of environmental pollution caused by various coal related industrial furnaces in China and studying the environmental improvement. This time, various industrial furnaces were examined in chemical and iron/steel industries. It could be inferred that both industries made efforts to enhance and rationalize production activities and then give consideration also to the environmental prevention. Generally, however, most plants still have old-fashioned production facilities, while the facilities are being modernized little by little. It was found that in China productivity was lower than Japan and the environmental pollution was in a serious condition. 16 refs., 28 figs., 69 tabs.

  1. Ni hombres ni mujeres providenciales

    Montaño Virreira, Sonia

    2000-01-01

    Debo advertir a la y el lector de este texto que lo que a continuación se presenta no es, ni de lejos, una propuesta realista, si por ella entendemos la traducción, enclave mujer, de las actuales tendencias de liderazgo político vigentes en la región. Por el contrario, intento argumentaren favor de un liderazgo que supere el caudillismo como estilo y se aproxime al máximo hacia el respeto de las formas, entendiendo que sin ellas no es posible construir la democracia. Para hacerlo reviso rápid...

  2. Fiscal 1999 basic study for promotion of joint implementation. Study of greenhouse gas reduction by modifying the power generation system of a power station in the Republic of Kazakhstan; 1999 nendo Kazakhstan ni okeru hatsudensho no hatsuden system kaishu ni yoru onshitsu koka gas sakugen ni kansuru chosa hokokusho

    NONE

    2000-03-01

    A feasibility study is conducted aiming to reduce greenhouse gas emissions by refurbishing obsolete power stations in Shymkent City, the Republic of Kazakhstan. The clean development mechanism is also discussed. Aircraft engine-derived 20MW-class gas turbine cogenerators will be introduced, one each into a 1st and 2nd power stations. A simple-cycle model of the same will also be introduced into the 1st power station. The facility costs will be US$61.279 million for the 1st power station and US$33.590 million for the 2nd power station. The amount of fuel to be saved will be 238.6-thousand tons/year in terms of oil, totalling 5,964-thousand tons in a 25-year period. As for the reduction of greenhouse gas emissions, there will be a 737.9-thousand tons/year reduction in terms of CO2, meaning a total reduction of 18.448-thousand ton in a 25-year period. An FIRRROI (Financial Internal Rate of Return on Investment) is tentatively calculated using power and heat prices presented by the other party. The result of calculation shows that the net cash flow before and after tax stays negative throughout the whole operating period, which means a total lack of cost effectiveness. This is attributed to the low power and heat unit prices set by the other party, extremely lower than the internationally accepted prices. The FIRRROI after tax will turn positive when the unit prices are 1.5 times higher and the total investment is reduced by 20%. (NEDO)

  3. Fiscal 1998 research report. Feasibility study on the CO{sub 2} reduction project by residue power generation at the oil refinery in China; 1998 nendo chosa hokokusho. Chugoku no seiyusho ni okeru zansa hatsuden ni yoru CO{sub 2} sakugen project ni kansuru F/S chosa

    NONE

    1999-03-01

    As a part of the basic research on joint project promotion, this feasibility study supposed introduction of IGCC (integrated gasification combined cycle) to Nanjing oil refinery of Jinling Petrochemical Corp. (JPC) in China, estimated the CO{sub 2} emission reduction effect by in-refinery efficient power generation using petroleum coke residue as fuel, and assessed the feasibility of the project together with a cost benefit. The feasibility study result showed the effectiveness of IGCC introduction to the oil refinery for reducing CO{sub 2} emissions, occupying the interest of JPC. However, Nanjing oil refinery already making a decision to adopt another system (BTG) answered that early adoption of this project is difficult. The feasibility study result also showed that efficient operation of IGCC is difficult because of lower generation efficiency of petroleum coke residue, and achievement of the supposed CO{sub 2} emission reduction effect and profitability is difficult. The project based on this feasibility study result is probably difficult to be realized. (NEDO)

  4. FY 2000 Fundamental study for promotion of jointed implementations. Feasibility study on energy saving effect and reducing CO2 emissions by use of RDF in cement plants in China; 2000 nendo Chugoku cement kojo ni okeru RDF katsuyo ni yoru shoene koka oyobi nisanka tanso haishutsu sakugen ni kansuru feasibility study chosa hokokusho

    NONE

    2001-03-01

    The feasibility study was conducted on a project in China for energy saving and greenhouse gas emission reduction by introducing the energy-saving and alternative energy technologies in cement plants. The cement plant selected for the feasibility study is Shanghai Plant of Shanghai Allied Cement Co., Ltd. (SAC), for RDF receive and supply facility, chlorine bypass facility, exhaust heat power generation facility and RDF production facility. The study results indicate that the exhaust power generation can save energy of 4,700 tons/y as crude, or energy saving rate of 25.5%, and that replacing part of coal by RDF and exhaust power generation can reduce CO2 emissions by 25,500 and 18,500 tons/y, respectively. For the investment recovery, it is estimated that the investment can be recovered in 9 years, and the project value is 81.399 million Yuan with the initial investment and project profit in each year discounted to the present value. These results fail to satisfy the SAC's investment standards. (NEDO)

  5. FY 2000 Report on the results of the survey/research on advanced medical treatment equipment technology of the next generation; 2000 nendo jisedai senshin iryo kiki gijutsu ni kakawaru chosa kenkyu hokokusho

    NONE

    2001-03-01

    For development of the advanced medical treatment equipment technology of the next generation, attempts are made to translate the policy targets, established through open discussions at the workshops and others, into the concrete techniques. As a result, the basic plans are concretely drafted for the (development of the gene-aided diagnostic system equipment for clinical purposes) and (development of heart disease treatment system equipment). The program for the (development of the gene-aided diagnostic system equipment for clinical purposes) is aimed at development of the system equipment which utilizes DNA microarrays and others to analyze the gene information highly reliably, quickly at low cost by simple procedure. The program for the (development of heart disease treatment system equipment) is aimed at development of various techniques, e.g., low-invasion type supercompact composite sensors capable of continuously measuring two or more types of information from a living body, basic techniques therefor, living hybridization techniques for stably operating these devices in a living body for extended periods, and intelligent drug delivery systems carrying multi-channel information transmission mechanisms and two or more types of drugs, and capable of delivering drugs independently at high precision. (NEDO)

  6. Fiscal 1993 international joint projects under New Sunshine Program. Surveys of bilateral cooperation and solar energy technology; 1993 nendo kokusai kyoryoku jigyo nikokukan kyoryoku taiyo energy gijutsu ni kakawaru gijutsu chosa

    NONE

    1994-03-01

    Concerning bilateral projects, overseas surveys were conducted about Japan-Australian and Japan-US technical cooperation. Concerning technological development, information was collected at the Solar World Congress of the International Solar Energy Society (ISES), and information was collected and opinions were exchanged at the 15th International Conference on Amorphous Semiconductors. A survey was conducted of Russia's development of solar cells and of their performance evaluation, and an overseas survey was conducted of the development of spaceborne photovoltaic power generation system practicalization technology. Surveys were conducted of international joint projects for the development of photovoltaic power generation system practicalization technology in Europe and the US. Overseas surveys were conducted of international joint projects concerning the development of photovoltaic power generation system practicalization technology, and a survey was conducted of the research and development of photovoltaic power generation in the US and of the state of introduction and diffusion of the same. A survey was also conducted of the state of element technology development for solar energy utilization in Europe. (NEDO)

  7. Fiscal 1999 international energy conservation model project. Report on result of demonstrative research concerning cement clinker cooling system; 1999 nendo kokusai energy shohi koritsuka nado model jigyo seika hokokusho. Cement clinker reikyaku sochi ni kakawaru jissho kenkyu

    NONE

    2000-03-01

    For the purpose of reducing energy consumption and CO2 discharge in a cement plant in Indonesia, R and D was conducted on new clinker cooling system, high performance kiln combustion system, and technology for steady kiln operation and control, with the fiscal 1999 results reported. In the research on the optimum clinker cooling system, a new type clinker cooling system (CCS) was developed in which air beams are applied only to stationary grate rows, in an air beam type clinker cooling system where cooling air is fed to each block, with grate plates used as the air duct. This year, in an actual machine testing equipment (capacity 2,500 t/d), the whole heat recuperation area was modified for the CCS, with the operation started since February, 1999, aiming at the optimal clinker cooling effect and high heat recovery efficiency. The heat quantity for the entire system showed a decrease of 60 kcal/kg in the heat consumption rate through CCS modification, kiln burner adjustment, etc. So long as the demonstration plant is concerned, design of a new type burner and study/design for the kiln stabilization were nearly completed. (NEDO)

  8. Fiscal 2000 research achievement report on the pioneering research and development involving next-generation liquid crystal process base technologies; 2000 nendo jisedai ekisho process kiban gijutsu ni kakawaru sendo kenkyu kaihatsu seika hokokusho

    NONE

    2001-03-01

    For the enhancement of energy conservation in the liquid crystal display manufacturing process, activities are conducted in the three fields of (1) low temperature thin film fabrication technology, (2) zone-selective thin film growth technology, and (3) next-generation liquid crystal process base technology and comprehensive surveys. Conducted in field (1) are pioneering studies of low temperature high quality Si film fabrication by electromagnetic annealing, low temperature high quality thin film fabrication by EPA (electron plasma annealing), and low temperature normal pressure film fabrication. Conducted in field (2) are pioneering studies of zone-selective fabrication of high quality Si crystal film, high precision control of reforming (doping), and free pattern low resistance wiring fabrication. Conducted in field (3) are tentative fabrication, evaluation, and analysis of ultimate performance TFTs (thin film transistors) produced by the state-of-the-art purification enhancement technology; next-generation liquid crystal process; and surveys of functional thin film to be a novel material for substrates. In the pioneering study of low temperature high quality Si film fabrication by means of electromagnetic annealing, microwave annealing is studied as an energy efficient process to replace the currently favored ELA (excimer laser annealing) method, and then it is proved that the microwave annealing method is much higher in energy efficiency than the ELA method. (NEDO)

  9. Report on the FY 1992 basic survey for industrialization related to the survey of overseas geological structure (Embalut West area, Indonesia); 1996 nendo kaigai chishitsu kozo nado chosa ni kakawaru kigyoka kiso chosa hokokusho (Indonesia Embalut nishi chiku)

    NONE

    1993-03-01

    The paper reported the FY 1992 basic survey for the coal mine development/industrialization in the Embalut West area of Indonesia. The geological structure in the survey area is under the Loa Haur Syncline which lies approximately north and south to the west of the area, and is regarded as the stabilized structure having no faults. The three beams from the upper part, S14, S13 and S12, are assumed to be the coal seams to be drilled. The average seam thickness is 1.17, 2.35 and 3.09m, respectively, and the continuity is good. In S14 beam, which is thin, it is difficult to mine coal using equipment. The theoretical minable reserve of the three coal seams is 18,859,000 tons. The recoverable coal reserve is 12,258,000 tons at a mining recovery of 65%. In case of annual production of 0.4 million tons, it is possible to mine more than 30 years. The coal is classified into a subbituminous coal-brown coal rank of the JIS coal classification. It is high in water content and medium in heating value, but is an environmental protection type with low ash and low sulfur content. In the case of mines in the Mahakam River basin, barge transport is indispensable. For sea transportation, the following should be studied in the light of the international price competition: reinforcement of shipping facilities on Mahakam River, increase in barge size, joint use of Balikpapan Coal Center, etc. (NEDO)

  10. Report for fiscal 1998 on basic commercialization survey related to geological structure surveys in overseas countries (Manguerra, the Philippines); 1998 nendo kaigai chishitsu kozo nado chosa ni kakawaru kigyoka kiso chosa (Philippines Manguerra) hokokusho

    NONE

    1999-03-01

    Commercialization survey was performed on the mines in the Manguerra district in the Philippines by means of geological structure surveys. The site surveys included geological and test drilling surveys, and those on conditions for developing underground mining mines, and infrastructures. The geological survey area spread out about 5 km{sup 2}, two test wells were drilled (to depths of 330 m and 290 m), trench survey was performed on 58 locations, and coal sample collection and analysis were carried out on eight locations. Furthermore, surveys were extended to the Manguerra mine operating status, on-the-ground facilities, roads for transportation, marketing, and related laws and regulations. As a result of the surveys, the Manguerra district was suggested of frequent sea water inundation into the coal field, leading to a view that the district is unstable from the viewpoint of development of coal beds. However, samples collected from the existing mining area indicated to have less water content and ash and high calorific power. The coal has high product value. The result of coal quantity calculation indicated 320122 tons as the total of defined and estimated quantity. The great depth mining plan was prepared from the viewpoints of actual yield, productivity, safety aspects, technological enhancement, and suppression of additional investments to minimum. (NEDO)

  11. FY 2000 survey on technical trends. Survey of technical trends on materials for heightening of performance for power generation facility use; 2000 nendo gijutsu doko nado chosa. Hatsuden shisetsuyo koseinoka zairyo ni kakawaru gijutsu doko nado chosa

    NONE

    2001-03-01

    As to high performance/high function plastic materials used in power generation facilities, technical trends were surveyed on the recycle situation and recycle R and D to study the subjects to be solved. For wire covering materials, vinyl chloride, polyethylene, rubber, etc. are used, and the recycle of resin has not been advanced. Concerning the generation of waste plastic, the existence of a lot of plastics different in characteristics makes the recycle difficult. As to the use of waste plastic as resource, the material recycle and recovery of combustion energy are being made, but only a part of the plastic is reused as chemical raw materials. Relating to the R and D of the chemical recycle technology, there are sample studies on the pyrolysis of polyolefine, dechlorination of chlorine base resins, etc. Recently, the following have been made public: proposal of depolymerization monomer based on the cyclic monomer, study of liquefaction of approximately 100% of the thermosetting resin, approach to the solvolysis by supercritical solvent. (NEDO)

  12. Investigations in relation with prevention of global warming in fiscal 2000. Structuring of strategies related to emission trading; 2000 nendo chikyu ondanka boshi kanren chosa hokokusho. Haishutsuryo torihiki ni kakawaru senryaku kochiku

    NONE

    2001-03-01

    Investigations in relation with the greenhouse effect gas emission trading system have been performed on introduction and discussion of the system in major countries in order to discuss basically the emission trading system in Japan. The EU has been advancing the discussion with the introduction thereof to start in 2005 kept in mind, whereas the points of issue for the system designing include the followings: what roles should be taken by the EU and membership countries, consistency between the membership countries with regard to the participating organizations, and the scheme for initial allocation. In Denmark, the emission trading system has been introduced in January 2001 between the electric power companies. The objects of the allocation are only the eight power generation companies, making the management of emission right retaining quantities by the government simple. The United Kingdom has a schedule of introducing the emission trading system in April 2001, but the trading itself will start in 2002. Management of the trading scheme, and acceptability of banking after 2008 are the main points of issue. In the fundamental discussions on designing the emission trading system in Japan, discussion items were extracted, and the points of issue were put into order. (NEDO)

  13. Basic research on promotion of joint implementation. Research on the overseas trend of activities implemented jointly; Kyodo jisshi suishin kiso chosa jigyo. Kyodo jisshi katsudo ni kakawaru kaigai doko chosa

    NONE

    1996-03-01

    The pilot phase of the activities implemented jointly (AIJ) was approved in 1995 in the 1st Conference of the Parties (COPI) of the United Nations Framework Convention on Climate Change to reduce greenhouse gas emission. In order to promote the AIJ Japan program smoothly, some practical examples in every preceding country and the situations and demands of Asian countries were researched. It was confirmed that since larger cost-effectiveness is achieved just in countries lower in emission control cost, AIJ can enhance the cost-effectiveness and promote environmental technology transfer. Japanese government had studied establishment of the framework for AIJ, and decided the basic framework of the AIJ Japan program in 1995. The government also approved the evaluation guidelines of this program which include confirmed and considered matters necessary for government offices related to this program to evaluate and approve each project.

  14. FY 1999 report on the investigational study of the actual state of the utilization of clean energy vehicles for the transport business use; 1999 nendo chosa hokokusho. Unso jigyo yo clean energy jidosha no shiyo jittai ni kakawaru chosa kenkyu

    NONE

    2000-03-01

    For the purpose of promoting the utilization of clean energy vehicles (CEV), survey was made on the assessment of the pollution by the CEVs introduced by now, subjects on the utilization, etc. As to the transport business use CEV running in the market, CNG vehicle is mostly used, and therefore, the gas emitted from them was tested. As a result, it was found out that CNG vehicle emits fewer NOx, PM and soot/smoke than diesel cars and contributes to improving the air pollution in large cities. However, it emits more CO2 than diesel car, and accordingly, it is necessary to reduce the fuel consumption. The practicality in the limited running distance is almost the same as that of diesel car, but it is desirable to improve startability, acceleration and gradability. Further, the occurrence of any troubles was pointed out in a third of the total numbers of CEV vehicle. Improvement in reliability is a must. CEV is higher in car cost than diesel car, and for the spread/promotion, it is necessary to prepare for assistance such as subsidy. Moreover, there are many requests for improvement in number, business hours, supply capacity, etc. of fuel supply station. (NEDO)

  15. Report on the FY 1993 basic survey for industrialization related to the survey of overseas geological structure (Tebulan East area, Malaysia); 1993 nendo kaigai chishitsu kozo nado chosa ni kakawaru kigyoka kiso chosa (Malaysia Tebulan higashi chiku) hokokusho

    NONE

    1994-03-01

    The survey was conducted based on 'Scope of work for detailed coal exploration in the Tebulan East block of the Merit Pila coal field, Sarawak, Malaysia' concluded on June 19, 1993 between NEDO and Global Mineral which owns the mining right. The field survey was for the geological survey, survey of conditions of open pit mining, and infrastructure survey. The confirmed/estimated coal amount totaled 22,65 million tons in 4 coal seams. The all sulfur content is low, approximately 0.12%. The heating value is 5,820 kcal/kg. As to the infrastructure, various conditions are good for transportation, shipping facilities, etc. from mine site to truck transport/barge transport/external route shipping. The drilling was planned to be made by open pit mining by the truck and shovel system, and the scale of the planned production was 0.3 million tons. The ash is low in amount, and there was no coal preparation. Clean coal is produced by crushing, sieving and washing. Attached were the borehole log (JN9940782), route map, and trench sketch (JN9940783). (NEDO)

  16. Report on survey of international cooperation possibility on chemical CO2 fixation and utilization technology in FY 1997; 1997 nendo chosa hokokusho (kagakuteki CO2 koteika yuko riyo gijutsu ni kakawaru kokusai kyoryoku kanosei chosa)

    NONE

    1998-03-01

    This survey focused on the end of the more promising companion and promoting the international cooperation on chemical CO2 fixation and utilization technology. As a result, the way of the carrying-forward of the international cooperation with more than one companion could be arranged beforehand. It led to getting an arrangement about a secrecy agreement respectively with Lurgi company and ABB company in Europe, and to providing a catalyst sample developed by RITE to implement an examination by the other party and to show related technical information. In addition, it concluded a cooperation agreement about a total system of the chemical CO2 fixation and utilization technology and methanol synthesis with ZSW. In Australia, negotiation about international cooperation with CSIRO which is a federal research organization and CRC (Cooperative Research Centre) for renewable energy has been started. The ideal circumstances are being ready for the chemical CO2 fixation project for which the international cooperation with the country where the natural energy is rich like Australia is essential when coming to practical use. To do alternating current with further high density in the following year it is desired to build a concrete study cooperation system. 1 fig., 4 tabs.

  17. FY 1992 Report on the survey results. Surveys on trends of research and development of advanced materials for severe environments (Intermetallic compounds); 1992 nendo chotaikankyosei senshin zairyo no kenkyu kaihatsu (kinzokukan kagobutsu) ni kakawaru kenkyu doko chosa

    NONE

    1993-03-01

    The trends of the ongoing researches on intermetallic compounds are surveyed through interviews and inquiries, in order to evaluate the results of the projects and research and development of the advanced materials for severe environments, and also to survey the research trends. The survey results are pigeonholed into 4 general categories; (1) research trends in the USA, UK and Germany, (2) notable topics of recent progress in intermetallic research and development, (3) evaluation of the projects, and (4) lists of the results of the researches on the Al-Ti and Al-Nb intermetallic compounds. The ongoing projects include those for intermetallic compounds of high specific strength and of high melting point, the former being represented by Al-Ti compounds and the latter by Al-Nb compounds, for aircraft and space development purposes. The projects are evaluated, viewed from materials and purposes/targets pursued by the projects, R and D organizations, and degree of attention the projects are attracting. The intermetallic compounds are extensively studied and attracting attention in various countries, but possibilities of achieving the set targets are rather pessimistic. (NEDO)

  18. Report on the achievements in fiscal 1998 on research and development related to the next generation ultra high speed communication node technology; 1998 nendo jisedai chokosoku tsushin nodo gijutsu ni kakawaru kenkyu kaihatsu seika hokokusho

    NONE

    2000-03-01

    Research and development has been performed on a new system COPM that links signals from LAN to an ultra high speed network of tera-bit class, and on the element technology required thereon. This paper summarizes the achievements. The transmission system using the COPM modulates beam signals by using image signals of 155 mega-bits per second; compresses the modulated beam pulse strings as much as sixteen times to transmit the light pulse as the light pulse of 2.5 giga-bits per second; and the pulses are expanded again at the receiver side to demodulate them into electric signal to project them as images on a TV screen. This demonstration was performed successfully. In addition, in order to mitigate the problems in raising the compression rate only in the beam zone, a proposal was made on a hybrid type compression device that combines the electric compression with the compression in the beam zone in series. As a result, it was shown that compression of up to about 10 giga-bit per second is possible in the electric zone by using an electric memory. Further research and development has been advanced on the element technologies, and the initial objective has been nearly achieved. (NEDO)

  19. Fiscal 1997 research report on the survey on public test and evaluation organizations for development of welfare equipment; 1997 nendo fukushi kiki kaihatsu ni kakawaru koteki shiken hyoka kikan chosa hokokusho

    NONE

    1998-03-01

    This research studies the construction policy of public test and evaluation systems for future development and practical use of welfare equipment, through survey on the current methods for development, practical test and evaluation of welfare equipment in countries advanced in welfare, and preparation of basic data for promoting establishment of public test and evaluation functions in Japan. Infrastructure preparation for standards and public test and evaluation organizations for developing welfare equipment is being promoted by Technical Laboratory of Bicycle Industry Promotion Association and some national organizations such as Product Evaluation Technical Center, Mechanical Engineering Laboratory, National Institute of Bioscience and Human Technology, and Living and JIS Center. However, preparation of objective and across test and evaluation systems for developing welfare equipment is still insufficient. Product Evaluation Technical Center is now approaching to evaluation and standardization of welfare equipment. Public test and evaluation organizations of the UK, Sweden and Denmark are presented. (NEDO)

  20. Fiscal 1992 research report. Research trend survey of research and development of advanced materials for extreme environments (Carbon composite material); 1992 nendo chotaikankyosei senshin zairyo no kenkyu kaihatsu chosa hokokusho. Tansokei fukugo zairyo ni kakawaru kenkyu doko chosa

    NONE

    1993-03-01

    Trends of research on carbon based composite materials were surveyed through studying various reports and technical literature and evaluation of the project named above was conducted through holding interviews with researchers. In the survey of research trends for which technical literature perusal was the main tool, it was found that in most technical articles the important task was the enhancement of oxidation resistance, that SiC coating was in use for this purpose, that the technology would meet its limit at 1,600-1,700 degrees C, and that it would turn useless at temperatures beyond 1,800 degrees C. For the evaluation of the project, interviews were held with nine researchers not taking part in the project. The researchers favored the project as far as the popularity of the project and the main implementing body and system were concerned, but they negatively evaluated the project's goal of using such materials at 2,000 degrees C in the atmosphere. This research report comprises four chapters which cover (1) trends of research on C/C (carbon/carbon) composites, (2) a summarized research report on C/C composites, (3) survey of patents associated with C/C composites, and (4) opinions expressed toward the project and the results of evaluation conducted on the same. (NEDO)

  1. FY 2000 Report on the survey results. Report on the survey/study on development of technologies for aging societies; 2000 nendo koreika taio gijutsu kaihatsu ni kakawaru chosa kenkyu hokokusho

    NONE

    2001-03-01

    The survey/study is conducted for (development of technologies for aging societies) by, e.g., the discussions at the (committee for investigating the technological development programs for activating the aging societies) and activities by the subordinate working groups, and the surveys on the aging societies and welfare-related technologies. The following results are obtained. The care-needing aged is not the sole stratum growing as a result of progress of the aging societies, because 87% of the aged can be self-supporting, needing no cares or other special aids. It is necessary to develop the industrial policies which combine the results of the promoted engineering research and development of the techniques/services for (active self-supporting) of the aged with the welfare-related equipment and services. It is also necessary to discuss the (technological development programs for activating the aging societies) through concerted efforts by the research organizations and industrial circles related to welfare equipment and government, to recognize their own roles. In these programs, acceleration and continuation of the technological development of the medical treatment/welfare equipment as one of the promising industrial areas are important. (NEDO)

  2. Fiscal 1993 international joint projects under New Sunshine Program. Surveys of bilateral cooperation and solar energy technology; 1993 nendo kokusai kyoryoku jigyo nikokukan kyoryoku taiyo energy gijutsu ni kakawaru gijutsu chosa

    NONE

    1994-03-01

    Concerning bilateral projects, overseas surveys were conducted about Japan-Australian and Japan-US technical cooperation. Concerning technological development, information was collected at the Solar World Congress of the International Solar Energy Society (ISES), and information was collected and opinions were exchanged at the 15th International Conference on Amorphous Semiconductors. A survey was conducted of Russia's development of solar cells and of their performance evaluation, and an overseas survey was conducted of the development of spaceborne photovoltaic power generation system practicalization technology. Surveys were conducted of international joint projects for the development of photovoltaic power generation system practicalization technology in Europe and the US. Overseas surveys were conducted of international joint projects concerning the development of photovoltaic power generation system practicalization technology, and a survey was conducted of the research and development of photovoltaic power generation in the US and of the state of introduction and diffusion of the same. A survey was also conducted of the state of element technology development for solar energy utilization in Europe. (NEDO)

  3. Report on the invitation program for developing countries concerning technology promotion project of global environmental industry in FY 1997; 1997 nendo chikyu kankyo sangyo gijutsu suishin jigyo ni kakawaru chikyu kankyo kanren gijutsu kaigai kenkyusha shohei jigyo hokokusho

    NONE

    1998-03-01

    In an effort to help preserve the global environment, International Center for Environmental Technology Transfer (ICETT) contributes to the solution of global environmental problems by promoting research exchanges with developing countries. As a part of this effort, ICETT hosted an environmental development researcher who visited Japan from the Institute of Environmental Research of Chulalongkorn University in Bangkok, Thailand. The invitation was extended at the request of NEDO. During the period of this investigation between September 16 and December 14, 1997, a photocatalyst was prepared and its performance was evaluated under the theme ``Application of photocatalysis to purification of atmospheric environment.`` At the same time, roadside test spots were inspected to study the practical application of optical photocatalysis. The visiting researcher also visited the National Institute for Resources and Environment to discuss with the staff of institute. This helped to deepen understandings of the state of air pollution problems confronting Japan, Europe, and North America, as well as issues related to the technologies that have been developed to solve these problems. The visiting researcher toured the RITE and examined Japan`s progress in the development of environmental control technology through joint research involving government, industry, and academia. At ICETT, the visiting researcher received training in Japan`s approaches to environmental problems in developing countries

  4. Fiscal 2000 report of investigation. Survey on technological trend concerning in si-tu remediation technology of contaminated soil; 2000 nendo osen dojo no gen'ichi joka gijutsu ni kakawaru gijutsu doko chosa hokokusho

    NONE

    2001-03-01

    In connection with contamination of soil and ground water, a survey was made on domestic patent information and existing literature or the like, in view of remediation technologies capable of in si-tu or on-site treatment, with arrangement and classification carried out by the method of cleaning contaminants. Arranged and classified were 209 pieces in the patent information, and 145 pieces in the literature from Geo-Environmental Protection Center, an incorporated body. In the methods of extracting contaminants from under the ground, the majority was the methods of pumping up ground water and those of excavating and removing. In the methods of cleaning contaminants, those of 'separation by heat', 'separation/decomposition method using water' and 'suction of gases' are found roughly in equal numbers. In the trend of the patent information, remediation technologies have started in 1990's, while bio-remediation as well as technologies of separation/decomposition through water is still increasing in the number of applications. Meantime, solidification technologies reached a peak around 1998 and have been decreasing in recent years. In the technologies of late, combinations of plural cleaning methods are also seen for the purpose of dealing with contamination with high to low concentration and compound contamination including organo-chloric compounds, heavy metals, etc. (NEDO)

  5. National research and development project. Report on evaluation of research and development of remotely controlled excavators for highly deep submarine oil fields; Ogata kenkyu kaihatsu project. Daishindo enkaku sosa kaitei sekiyu kussaku sochi no kenkyu kaihatsu ni kakawaru hyoka hokokusho

    NONE

    1976-02-04

    Described herein are results of evaluation of the developed excavators remotely controlled for highly deep submarine oil fields. The excavator system was designed to work at the target water depth of 200 to 250 m and excavation depth of 8,000 to 9,000 m, though not quite satisfactorily. There were several practical problems to be solved, e.g., those found in accuracy of reentry in the excavated section, cables connecting the driving equipment to the excavated section, and entangled hoses. The works were divided and system was configured in an attempt to secure all-weather type serviceability and to improve economic viability. The other major works included attempts to improve equipment functions and reduce manpower cost. Nevertheless, however, the construction cost was considered to be higher than expected, and no firm prospect was obtained whether the new excavator system was economically competitive with the conventional rig. The factors that pushed up the construction cost were various facilities needed by the new system with the separated excavation and driving sections, e.g., those facilities for helping the system land on the sea bottoms, material supply/storage facilities, and automated/unmanned facilities. The system failure and other items related to reliability are no clearly understood, making it difficult to compare it with the conventional rig in service factor. It was not adequate, therefore, to advance the next R and D phase as planned, and decided that the project was suspended to see the world development trends, because the clear plans for the future could not be drawn at that time. (NEDO)

  6. Fiscal 1995 survey report on the environmentally friendly type coal utilization system introduction support project. Verification project on the circulating fluidized bed boiler; Kankyo chowagata sekitan riyo system donyu shien jigyo. Junkan ryudosho boiler ni kakawaru jissho jigyo

    NONE

    1996-12-01

    In relation to the circulating fluidized bed boiler which reduces the amount of sulfur oxides emitted in coal utilization, a verification project was carried out on installation of the equipment and spread activity in China and the Philippines contributing to the control of environmental pollutant associated with coal utilization and the effective use of energy. At the Fanshan area, installed was a 10t/h internal circulating fluidized bed boiler. At the performance test, coal includes around 7% of impurities such as stone, and the impurities should be excluded continuously at the time of actual run. Therefore, the boiler efficiency had to be changed from 89.5% to 85.8%. Further, power generation facilities have not yet been finished, and the overall operation of boiler turbine has not been executed. At the Zibo area, a 30t/h external circulating fluidized bed boiler was installed. The boiler efficiency reached 86.1%, over the targeted value. At the Batangas area in the Philippines, a 10t/h internal circulating fluidized bed boiler was installed. The boiler efficiency reached 85.8%, over the designed value. About the coal produced in the Philippines, slagging was feared, but the combustion state was favorable. 82 figs., 21 tabs.

  7. FY1998 Report of surveys on network possibility involved with proliferation and transfer of environmental technologies (Europe, Australia and New Zealand); 1998 nendo kankyo gijutsu no fukyu iten ni kakawaru network kanosei chosa hokokusho . Oshu Goshu New Zealand

    NONE

    1999-03-01

    At the third Conference of the Parties to the United Nations Framework Convention for Climate Change (COP3) held in December 1997, the industrialized nations have agreed on development and proliferation of innovative technologies under international cooperation and transfer of environmental technologies to developing countries by expanding and strengthening CTI being the framework to be progressed spontaneously. Under the international strategic research project for global environment, NEDO has been promoting positively the research and development, whose support is urged to be expanded further in the future upon receiving the present agreement. Therefore, NEDO has performed the present survey in order to propose frameworks and measures for strengthening and expanding CTI. From among the policies and measures to be taken by the related countries based on the COP3 protocol, fiscal 1997 has performed review and new establishment of plans involved with execution of the items related to technology development, and surveys on action movements such as review and expansion of the measures, as the first stage. Fiscal 1998 has executed surveys focusing on the network for technology proliferation and transfer to developing countries as the second stage. (NEDO)

  8. Fiscal 2000 survey report on technological trends. Survey on trend of high-density energy beam technology concerning conservation of energy; 2000 nendo gijutsu doko nado chosa hokokusho. Energy shiyo gorika ni kakawaru komitsudo energy beam technology no doko chosa

    NONE

    2001-03-01

    There is a possibility that machining technology using high-density energy beam will bring an epoch-making change to micro-nano area processing. In particular, a laser beam having high controllability is indispensable. This is a report of the fiscal 2000 survey. The survey was conducted on laser beam generation, control and nano-diagnostic techniques, micro-nano optics technologies and machining technologies, with the development problems and targets summarized. Laser beam generation/control technologies, which become the basic tools for micro-nano manufacturing, were investigated, as were inspection technologies for the purpose of checking the functions of nano structures created. Particularly, the investigation elucidated the significance of development of a femtosecond solid state laser based on a semiconductor laser and the control techniques of their phase. Further, necessity was emphasized in developing X-ray probing, infrared and terahertz spectroscopy which are essential for nano-diagnostic techniques. In optics technologies, the paper described the importance of photonic crystals which enable less-than-wavelength machining or electrical beam control using interference effect. The possibility of fabricating photocatalysts with nano-particles was also mentioned, as was the manufacturing of nano-functional structures. (NEDO)

  9. Report on a commercialization fundamental investigation (in Batulicin Area, Indonesia) in relation to FY 1997 investigations on geological structures in overseas countries; 1997 nendo kaigai chishitsu kozo nado chosa ni kakawaru kigyoka kiso chosa (Indonesia Batulicin chiku) hokokusho

    NONE

    1998-03-01

    A fundamental coal mine development investigation was carried out in Batulicin Area, Kalimantan, the Republic of Indonesia. The investigation included ground surface surveys, preparation of topographical maps and geological maps, trial drilling investigation, physical logging, chemical analysis, and infrastructure investigation. The trial drilling investigation was intended to identify the existence conditions of coal beds and coal quality, and was performed by forming grids with about 500-meter interval, and using 21 trial drillings to depths of 104 to 240 meters for a total drilling length of 3463 meters. The physical logging included electric logging, radioactivity logging and pore size logging, and the trial drilling cores were subjected to chemical analysis. For infrastructures, investigations were carried out on necessity of modifying existing roads, privilege relationship, the current status of barge loading points, water depths, and land acquisition. The result of the investigation revealed that minable coal quantity in underground mining of the coal bed B would be 13.189 million tons, and that annual production of original coal at 733,000 tons would be possible by adopting a long-wall type mechanized coal mining system. 14 refs., 99 figs., 25 tabs.

  10. Investigation under international cooperation on the mentality/intellect-based technology. Development of mind-based technology; Shinsei chisei kiban gijutsu kokusai kyodo kenkyu chosa. Mind-Based Technology no kaihatsu ni kakawaru kenkyu chosa

    NONE

    1994-03-01

    The mind-based technology (MBT) was investigated to be developed, for materializing the world where the human race and machinery live together without sense of incompatibility. Based on the human mind, the MBT is a technology to support the personal expression which respects the value judgment, diversity and individuality in the human life. For it, it is important to technologically comprehend the human mind and physiological/psychological state, and particularly, control the human will. In order to structure the social system in which the human race and technology live together, it is also important to build a life system information processing model which simulates the formation process to integrate the feeling, knowledge and conscience, together with an action system to be established. As an image to which the MBT is applied, support will be extended to the life fulfillment, personal expression and hearty communication. Development is expected toward the social security technology with robots living in the human society. Pursuing the mental richness and worthwhile life, the high-grade mature society needs the technology to communicate with the machinery gentle to the human race on the mutual interface. 21 refs., 8 figs.

  11. FY 1992 report on the survey of geothermal development promotion. Supplementary survey on data processing (No.38 - West area of Mt. Aso); 1991 nendo chinetsu kaihatsu sokushin chosa. Data shori ni kakawaru hosoku chosa hokokusho (No.38 Asosan seibu chiiki)

    NONE

    1993-09-01

    As a part of the survey of geothermal development promotion in FY 1992, chemical/isotopic analysis of fumarolic gas in the Yoshioka district was made to elucidate the underground geothermal structure in the west area of Mt. Aso in Kumamoto Prefecture. Items for analysis of fumarolic gas were 16 items including the temperature, concentration of non-condensable gas, CO2, H2O, CH{sub 4}, {delta}D(CH{sub 4}) and {delta}{sup 13}C(CO2). Items for analysis of condensed water were 9 items including pH, Na, NH{sub 4}, {delta}D(H2O) and {delta}{sup 18}O. As a result of the analysis, the main component of non-condensable gas of fumarolic gas was CO2, and the composition was similar to that of the fumarolic gas in the Yunoya/Tarutama district in the periphery. It was presumed that the origin and formation mechanism of fumarolic gas were also similar to those in the Yunoya/Tarutama district. It was presumed that the deep geothermal reservoir which is the source of vapor/gas generation was composed of the neutral or alkalescent geothermal water, and a possibility that the reservoir is connected with the deep geothermal reservoir in the Yunoya district was presumed from a viewpoint of geographical location. (NEDO)

  12. Report on fundamental surveys for such as cases and effects in relation with development of new energy technologies in fiscal 1999; 1999 nendo shin energy gijutsu kaihatsu ni kakawaru jirei koka nado kiso chosa hokokusho

    NONE

    2000-03-01

    This paper describes the fundamental surveys in fiscal 1999 on cases and effects in relation with development of new energy technologies. Among the projects having been performed by NEDO in commemoration of the 20th anniversary of the NEDO foundation, the economic and social situations in the times in which the projects have been carried out with the focus placed particularly on new energies were put into order and analyzed to make clear the positioning of the project significance in the nation's energy policies. In addition, the roles of NEDO were recognized afresh to use them as the fundamental materials to serve for the future policy development. For the past thirty years before and after the oil crises, the time division that can be used universally for the project evaluation was established, based on the trends inside and outside the country, social currents, related indexes, and the status of development execution. Work hypotheses were presented regarding the basic conception in the evaluation, specific evaluation viewpoints, and their contents. Based on the hypotheses, three subjects were taken up as representative cases, that is, photovoltaic power generation, coal liquefaction, and phosphoric acid type fuel cell technology development. Time points that are considered as the important turning points were specified to give evaluations at respective turning points. Analyses were also made on decision making factors for project planning, continuation, direction change, suspension, and completion. (NEDO)

  13. FY 1999 Report on feasibility research and development for next generation liquid crystal process basic technologies; 1999 nendo jisedai ekisho process kiban gijutsu ni kakawaru sendo kenkyu kaihatsu seika hokokusho

    NONE

    2000-03-01

    Described herein are the FY 1999 results of the feasibility study on the next generation liquid crystal processes. Technology for low-temperature thin film formation fabricates high-purity, high-density Si films useful as the laser annealing (crystallization) precursor by the IBD method, without using thermal annealing. Formation of thin films of a-Si and SiNx on substrates kept at 200 degrees C or lower is studied using a high-density plasma source, and the surface conditions are uniformly controlled over a large area of the film precursor. The new technology needs less power to produce the film than the conventional CVD method which uses parallel flat plates by controlling the plasma-generating region. Resources- and energy-saving using the TFT method are essential for production of liquid-crystal displays, and the techniques for forming the thin films at low temperature are studied. Reduction in wiring resistance (signal transmission delay) is studied for the next generation TFT, and it is found that the Cu film is selectively formed on TiN but not on SiO{sub 2} by the MOCVD method at 150 to 180 degrees C. Similarly, the selective film formation is confirmed in the plating technology. The comprehensive investigations for the next generation liquid crystal process technologies cover high-quality polycrystalline Si films and lithography (exposed to light). (NEDO)

  14. Research program for environmentally-friendly coal utilization system. Follow-up project for simplified desulfurizers (Weifang Chemical Industry Works); Kankyo chowagata sekitan riyo system donyu shien jigyo. Kan`i datsuryu setsubi ni kakawaru follow up jigyo (Weifang kakosho)

    NONE

    1997-03-01

    To suppress the emission of environmental pollutants from coal utilization in China and to contribute to stable security of Japan`s energy, demonstration of clean coal technology and consolidation of diffusion base to be introduced into China have been promoted. Demonstration program for diffusing simplified desulfurizers has been promoted. For accelerating the achievement, experts of desulfurizers were delegated to Weifang Chemical Industry Works, to support the program. Exhaust gas is introduced from boiler via water spray dust remover, suction fan and centralized stack into absorption tower of the simplified wet-type desulfurizer. In the ascending process, the exhaust gas contacts with absorbent, to remove SO2 and dust. The absorbent is blasted up through the spray nozzle. The absorbent is oxidized by the air into sulfate ion in the liquid chamber at the lower part of tower, and neutralized by hydrated lime to form gypsum. Through the continuous operation for two years, understandings were remarkably increased. However, good treatment of the tax system is required for further diffusion. Though there are no problems for ordinary start and stop, emergency operation is insufficient. There are some problems in the maintenance due to the delay of finding failures. 16 figs., 1 tab.

  15. Fiscal 1997 survey report on a feasibility of international collaboration on bio-hydrogen R and D; 1997 nendo chosa hokokusho (bio suiso seizo gijutsu ni kakawaru kokusai kyoryoku kanosei chosa)

    NONE

    1998-03-01

    R and D of the production technology of biohydrogen is an option effective for the world energy supply technology and the world environmental preservation technology in the 21st century. At present, a project named `R and D of the environment harmony type hydrogen production technology` tackles the R and D of the hydrogen production technology using photosynthetic microorganisms, and promotes the R and D in this field from both aspects of a basis and application as seen in a workshop held including interchanges with researchers and research institutes overseas. With the recently increasing interest in bio-hydrogen production technology also overseas, search and bleeding/improvement of microorganisms related to the hydrogen production and utilization technology of biomass have been advancing. For development in this field, it is necessary to construct a widespread research network and promote the comprehensive research and development. In this survey, most of the research institutes visited recognized an importance of international cooperation in this field and agreed to make future research interchanges in a wide range. Based on the survey, a feasibility of concrete international collaboration is searched. 146 refs., 2 figs., 11 tabs.

  16. FY 1998 survey report on the feasibility study of environmental cooperation in environmental protection technology, system, etc. for spread to developing countries; 1998 nendo kankyo taisaku gijutsu seidonado no tojokoku fukyu ni kakawaru kankyo kyoryoku kanosei chosa hokokusho

    NONE

    1999-03-01

    The paper arranged the present situation and the problems of environmental cooperation for developing countries, and studied based thereon how to cooperate in environmental protection for developing countries in the future. At the same time, it arranged the problems/subjects posed when environment-related companies in Japan try to transfer environmental technology to developing countries, for the purpose of using them as data in studying possibility of reviewing the environmental cooperation presently conducted. A view on environmental cooperation is that as security of mankind, it is necessary to help developing countries in technology/knowledge/fund. However, a trial calculation indicated that the initial investment of 11.1 trillion yen is needed only for desulfurization and water treatment in China and ASEAN countries. Such a huge amount of money cannot be paid at all even by developed countries. As the support of environmental protection measures, the one also including energy and resource is needed. Further, the support of environmental protection measures should be the one that has the exhibition effect and influential effect, promotes efforts of developing countries' own, and pushes independent environmental measures forward. From this point of view, a study was made on what the details of the environmental cooperation should be like. (NEDO)

  17. Fiscal 2000 report of investigation. Survey on technological trend concerning in si-tu remediation technology of contaminated soil; 2000 nendo osen dojo no gen'ichi joka gijutsu ni kakawaru gijutsu doko chosa hokokusho

    NONE

    2001-03-01

    In connection with contamination of soil and ground water, a survey was made on domestic patent information and existing literature or the like, in view of remediation technologies capable of in si-tu or on-site treatment, with arrangement and classification carried out by the method of cleaning contaminants. Arranged and classified were 209 pieces in the patent information, and 145 pieces in the literature from Geo-Environmental Protection Center, an incorporated body. In the methods of extracting contaminants from under the ground, the majority was the methods of pumping up ground water and those of excavating and removing. In the methods of cleaning contaminants, those of 'separation by heat', 'separation/decomposition method using water' and 'suction of gases' are found roughly in equal numbers. In the trend of the patent information, remediation technologies have started in 1990's, while bio-remediation as well as technologies of separation/decomposition through water is still increasing in the number of applications. Meantime, solidification technologies reached a peak around 1998 and have been decreasing in recent years. In the technologies of late, combinations of plural cleaning methods are also seen for the purpose of dealing with contamination with high to low concentration and compound contamination including organo-chloric compounds, heavy metals, etc. (NEDO)

  18. Feasibility study for international collaboration on photovoltaic power generation and long-distance energy transmission technologies utilizing desert areas environment; Sabaku chiiki wo riyoshita taiyoko hatsuden chokyori yuso gijutsu ni kakawaru kokusai kyoryoku kanosei chosa

    NONE

    1997-03-01

    A workshop was held at Tokyo in March, 1997 on the research and development and feasibility study for international collaboration on photovoltaic (PV) power generation and long-distance energy transmission technologies utilizing desert areas environment. Two speakers from the USA, one from Italy, and two from China were invited, and four speakers in Japan presented papers. A total of 48 persons participated. In the technical sessions, `World energy demand and PV system potential` by Prof. Kurokawa, `Long distance transmission of PV power` by Mr. A. Invenizzi, `Case studies of large scale PV systems distributed throughout desert areas of the world` by Mr. Hirasawa, `Linking renewable energy resources around the world` by Mr. P. Meisen, `Properties of large scale PV plant in the USA` by Mr. J. Benner, `Future prospect of PV electrification in China` by Mr. Kong Li, `Application of large-scale PV systems in deserts in China` by Mr. Isomura, and `Effects of large-scale PV power plant in a climatic desert areas` by Prof. Ihara were presented. 38 refs., 62 figs., 29 tabs.

  19. Report on achievements in fiscal 1998. Demonstrative research of an alkali recovery process in the non-wood pulp paper manufacturing industry; 1998 nendo himokuzai pulp seishi sangyo arukari kaishu process ni kakawaru jissho kenkyu seika hokokusho

    NONE

    1999-09-01

    This project is intended of performing demonstrative research jointly with China on a system to efficiently extract, condense, and combust black liquor in a non-wood pulp paper manufacturing plant in China to recover alkaline solution and heat energy, and to contribute to proliferation of the system. Specifically, an alkali recovery plant is built in Cangshan Paper Making Plant in Shandong Province to verify conservation in energy and reduction environmental load. This fiscal year has performed (1) component researches and related technology investigations, and (2) device design and fabrication. For Item 1, the extractor adopted the spiral net type, and the condensation device adopted the falling film evaporator of full-can plate type. For the silica removing agent, data were acquired on reduction of silica in the black liquor and effect of reducing the black liquor viscosity. Basic design requirements were established for an alkali recovery process for a pulp production plant of 75 t/d. Regarding Item 2, prepared were the material and heat balance tables for the black liquor extractor and the black liquor condenser, process flow diagrams (PFD), device specifications, a meter list, and a summary utility consumption list, and confirmed them with the Chinese side. For the black liquor combustion device and the caustification device, PFD and device list prepared by the Chinese side were acquired to start the basic design. (NEDO)

  20. FY 2000 report on the investigational study of the introduction/spread of clean energy vehicles for transportation business use; 2000 nendo chosa hokokusho. Unso jigyo yo clean energy jidosha no donyu fukyu ni kakawaru chosa kenkyu

    NONE

    2001-03-01

    A comparative study of the cost effectiveness in improvement of emission gas was made between the diesel particulate filter (DPF) which is studied as measures against toxic emission gas from the vehicles already sold and the compressed natural gas (CNG) vehicle which has a large number of spread among clean energy vehicles. In the trial calculation, 18 cases were set up using measures by year against diesel car emission gas, use period and annual running distance as valuables. As a result of the study, the following conclusions were obtained. At the present time, when the vehicle price dropped approximately 40% from that at the beginning of the introduction, the cost effectiveness of CNG vehicle is larger than that of diesel car with DPF. Since the unit price of natural gas is comparatively higher than that of light oil, the longer the annual running distance is, the smaller the cost effectiveness of CNG vehicle is than that of diesel car with DPF. The durability period of DPF is considered not so long, and therefore, the longer the use period is, the larger the cost effectiveness of CNG vehicle is than that of diesel car with DPF. (NEDO)

  1. Report for fiscal 1999 on basic commercialization survey related to geological structure surveys in overseas countries (Kalewa area, Myanmar); 1999 nendo kaigai chishitsu kozo nado chosa ni kakawaru kigyoka kiso chosa (Myanmar Kalewa chiku) hokokusho

    NONE

    2000-03-01

    Commercialization survey was performed on the coal beds in the Kalewa area in the Union of Myanmar by means of geological structure surveys. The site surveys included on-the-ground survey, test drilling survey, sample collection and analysis, and infrastructure survey. The on-the-ground survey area spread out about 5.5 km{sup 2}, wherein nine test wells were drilled (for total distance of 2,046.74 m), and coal and rock sample collection and analysis were carried out on six samples. The infrastructure survey was performed on coal transporting roads, and barge loading planned points and facilities. As a result of the test drilling survey, existence of coal beds with thickness of 4 ft, 9 ft and 6ft was identified. Since the 9-ft bed in particular exists stably with inclination of 40 to 42 degrees over the whole subject area, it was made clear that the bed can be the object of mining as the main coal bed. The coal is the ordinary coal with such good qualities as ash content of 4.72%, total sulfur content of 0.22%, and total calorific power of 6,500 to 6,570 kcal/kg. The defined coal quantity for the 9-ft bed is four million tons, or 7.7 million tons in total if the estimated coal quantity is added. The quantity will amount to 15.3 million tons when those of the 4-ft and 6-ft beds are added. (NEDO)

  2. FY 2000 Project of developing international standards for supporting new industries. Comprehensive study for promotion of the international standardization; 2000 nendo shinki sangyo shiengata kokusai hyojun kaihatsu jigyo seika hokokusho. Kokusai hyojunka suishin ni kakawaru hokatsuteki chosa kenkyu

    NONE

    2001-03-01

    This project studies the schemes for the international standardization, trends of the international standardization by the international standardization organizations and related organizations, and activities for the international standardization by the enterprises in the advanced countries, among others, in order to promote the international standardization for the 8 research and development themes. These themes are SMIL (synchronized multimedia integration language) tag standard of the three-dimensional image data, based on MXL; systems for detecting gene recombination products; methods for testing mileage of gas-fueled automobiles; measurement of multi-colors; testing/evaluation methods for highly coherent lasers; methods of evaluating optical performance of microlenses for optical information processing; recycled CFRPs; and devices for measuring marine environments. The study results indicate that progress of the development of the international standardization of the advanced technologies can be followed by investigating the characteristics of the ISO publications; ISO is studying the business plans being developed by each TC, in order to improve market adaptability of the international standards; and the European countries add conditions for standardization when the research and development themes are contracted. (NEDO)

  3. Decay of 57Ni

    Santos Scardino, A.M. dos.

    1987-01-01

    The decay of 57 Ni to 57 Co was studied by gamma ray spectroscopy using both singles and coincidence spectra. The sources were obtained with the 58 Ni (Y,n) 57 Ni reaction. Natural metallic nickel was irradiated in the bremsstrahluhng beam of the linear accelerator of the Instituto de Fisica da Universidade de Sao Paulo with 30 MeV electrons. The singles espectra were taken with 104 cc HPGe detector and the coincidences espectra with 27 and 53cc Ge(Li) and 104 cc. HPGe detectors. The energies of transitions that follow the 57 Ni decay were measured using 56 Co as standard (which was obtained by (Y,np) reaction in 58 Ni) and taking into account the cascade cross-over relations. (author) [pt

  4. Bridging exchange bias effect in NiO and Ni(core)@NiO(shell) nanoparticles

    Rinaldi-Montes, Natalia, E-mail: nataliarin@gmail.com [Departamento de Física, Universidad de Oviedo, E-33007 Oviedo (Spain); Gorria, Pedro [Departamento de Física & IUTA, EPI, Universidad de Oviedo, E-33203 Gijón (Spain); Martínez-Blanco, David [Servicios Científico-Técnicos, Universidad de Oviedo, E-33006 Oviedo (Spain); Fuertes, Antonio B. [Instituto Nacional del Carbón, CSIC, E-33080 Oviedo (Spain); Fernández Barquín, Luis [CITIMAC, Facultad de Ciencias, Universidad de Cantabria, E-39005 Santander (Spain); Puente-Orench, Inés [Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza and Institut Laue-Langevin, BP 156, F-38042 Grenoble Cedex 9 (France); Blanco, Jesús A. [Departamento de Física, Universidad de Oviedo, E-33007 Oviedo (Spain)

    2016-02-15

    Among all bi-magnetic core(transition metal)@shell(transition metal oxide) nanoparticles (NPs), Ni@NiO ones show an onset temperature for the exchange bias (EB) effect far below the Néel temperature of bulk antiferromagnetic NiO. In this framework, the role played by the magnetism of NiO at the nanoscale is investigated by comparing the microstructure and magnetic properties of NiO and Ni@NiO NPs. With the aim of bridging the two systems, the diameter of the NiO NPs (~4 nm) is chosen to be comparable to the shell thickness of Ni@NiO ones (~2 nm). The EB effect in Ni@NiO NPs is attributed to the exchange coupling between the core and the shell, with an interfacial exchange energy of ΔE~0.06 erg cm{sup −2}, thus comparable to previous reports on Ni/NiO interfaces both in thin film and NP morphologies. In contrast, the EB detected in NiO NPs is explained in a picture where uncompensated spins located on a magnetically disordered surface shell are exchange coupled to the antiferromagnetic core. In all the studied NPs, the variation of the EB field as a function of temperature is described according to a negative exponential law with a similar decay constant, yielding a vanishing EB effect around T~40–50 K. In addition, the onset temperature for the EB effect in both NiO and Ni@NiO NPs seems to follow a universal dependence with the NiO crystallite size. - Highlights: • Comparison of the exchange bias effect in NiO and Ni(core)@NiO(shell) nanoparticles. • Universal temperature dependence of the exchange bias effect. • Suggested similar physical origin of the effect in both systems. • Size and crystallinity of the NiO shell hold the key for exchange bias properties.

  5. Fiscal 2000 survey on electrical power supply system for the purpose of reducing greenhouse effect gas. Three scenarios for spread of distributed power generation by 2010; 2000 nendo onshitsu koka gas sakugen no tame no denryoku kyokyu system ni kansuru chosa hokokusho. 2010 nen made no bunsangata dengen fukyu ni kansuru mittsu no scenario

    NONE

    2001-03-01

    An examination was conducted concerning the course of spread of distributed power generation (on-site power generation of 2,000 kW or less) by the year 2010, with three scenarios prepared. In the scenario 1, the government will completely deregulates the power market and take no other steps, leaving the matter to market competition. The universal service will be abandoned, which means higher power prices for remote regions, contributing to the spread of home power generation. In the scenario 2, the government, having reached the limits of the nuclear propulsion policy, will adopt natural gas as the center of its electrical power policy, providing preferential treatments such as subsidies and tax exemptions and requesting the power companies to increase their usage. This will lead to higher transmission charges, with distributed power generation more advantageous to the IPPs in terms of cost. In the scenario 3, environmental awareness will make increase in the capacity quite difficult including power generation facilities and transmission/distribution network, and will invite a power crisis in the long run through insufficient capacity in power generation and transmission/distribution volume. Distributed power generation requiring no reinforcement to the grid will spread such as household-use type without system interconnection, solar cells or small fuel cells. (NEDO)

  6. Fiscal 2000 report of investigation. Research study on reduction of carbon dioxide discharge by increase in octane number in gasoline through use of biomass; 2000 nendo biomass wo riyoshita gasoline no octane ka kojo ni yoru nisanka tanso haishutsu sakugen ni kansuru chosa kenkyu hokokusho

    NONE

    2001-03-01

    An investigative research was conducted on the means of reducing fuel consumption of motor vehicles and reducing greenhouse effect gases, by making octane boosters for gasoline through the use of alcohol derived from biomass feedstock. As a result of the investigation, the following proposals were made. In present gasoline-fueled motor vehicles, an increase in the octane number by 5 will allow a higher compression by 1, thereby reducing fuel consumption by 2.5% during running. The suitable octane boosters are MTBE (methyl tertiary butylether) and ETBE (ethyl tertiary butylether) both of which can be produced from either methanol or ethanol derived from biomass feedstock. Blending regular gasoline with an octane number of 90 and either MTBE or ETBE by 18% may make gasoline having an octane number of 95, leading to a reduction of carbon dioxide emission by 4.8% and 6.8% respectively. The amount of alcohol needed for these octane boosters is 2.2 megatons of methanol per year for MTBE production and 2.7 megatons of ethanol per year for ETBE; this requires 12 plants nationwide for producing the octane boosters at 0.5 megatons per year; and, in view of the cost of transportation, alcohol producing plants are desirably located near the octane booster producing plants. (NEDO)

  7. Report on a survey in fiscal 1999. Survey on trends in developing innovative technologies related to reducing CO2 emission in departments consuming great quantity of energy, such as petrochemical industry; 1999 nendo sekiyu kagaku kogyo nado energy tashohi bumon ni okeru CO{sub 2} sakugen ni kansuru kakushinteki gijutsu kaihatsu doko chosa hokokusho

    NONE

    2000-03-01

    A survey was performed on the state of developing energy saving and CO2 emission reducing technologies in the following fields: (1) distillation technologies, (2) combustion technologies, (3) heat transfer and conduction technologies, and (4) technologies to convert and fix generated CO2. While the technologies in the field (1) are of the matured domain, technologies providing 20 to 60% energy saving effect have been developed. In the field (2), gas turbine combustion can achieve an overall plant thermal efficiency of 50% or more, whereas a trial calculation indicates that CO2 emission can be reduced by 22%. Catalytic combustion is noticed as a measure to make low NOx emission possible. A composite type catalytic combustor for gas turbines demonstrated that NOx emission of less than 5 ppm can be achieved. In the field (3), energy saving effect higher by 52% than in the warm wind room heating system has been obtained. Development has been made on heat storing materials that have phase change temperature of higher than 80 degrees C and large latent heat storage quantity. In the field (4), researches are advanced in a TiO{sub 2} catalyst that uses sunlight. A catalyst that is methanated at high speed with CO2 conversion rate at nearly 100% has been developed. In methanol synthesis, a catalyst that has high selectivity even at low temperatures has been developed. (NEDO)

  8. FY 2000 report on the basic survey to promote the joint implementation. Potential survey of the greenhouse effect gas reduction by high-efficient utilization of the oil residue in Bataan Refinery in the Philippines; 2000 nendo kyodo jisshi nado suishin kiso chosa hokokusho. Philippines koku Bataan seiyusho ni okeru sekiyu zansa kokoritsu riyo ni yoru onshitsu koka gas sakugen kanosei chosa

    NONE

    2001-03-01

    For the purpose of reducing the CO2 emitted from electricity/vapor supply facilities of Bataan Refinery in the Philippines, study was conducted of optimum energy supply facilities considering the effective use of the oil residue and future reinforcement of the refinery. Concerning the high-pressure/high-temperature condensing extraction boiler/turbine cogeneration, gas turbine cogeneration and low speed diesel engine cogeneration, comparative study was carried out in terms of thermal efficiency, reliability/preservation, environmental acceptability, effectiveness of measures for the future excessive oil residue, etc. As a result, the study was concluded as follows: the electric power consumption will markedly increase in the future; however, in the light of the situation of the refinery where the vapor demand will not increase, it is the most suitable to use low speed diesel engine cogeneration facilities as on-site power generation facilities which can burn the excessively increasing oil residue as direct fuel. The CO2 reduction effect estimated from the project on the present scale was 132,880 t-CO2/y, and the energy conservation effect estimated was 50,861 toe/y. (NEDO)

  9. OpenNI cookbook

    Falahati, Soroush

    2013-01-01

    This is a Cookbook with plenty of practical recipes enriched with explained code and relevant screenshots to ease your learning curve. If you are a beginner or a professional in NIUI and want to write serious applications or games, then this book is for you. Even OpenNI 1 and OpenNI 1.x programmers who want to move to new versions of OpenNI can use this book as a starting point. This book uses C++ as the primary language but there are some examples in C# and Java too, so you need to have about a basic working knowledge of C or C++ for most cases.

  10. FY 1999 report on the results of the introductory study on the global environmental industry technology. Investigational study on the environmental creation technology by the application of ecosystem information functions; 1999 nendo chikyu kankyo sangyo gijutsu ni kakawaru sendo kenkyu seika hokokusho. Seitaikei joho kino oyo ni yoru kankyo sozo gijutsu ni kansuru chosa kenkyu

    NONE

    2000-03-01

    To know the state of environmental pollution before it clearly exists, an investigational study was made on the technology to measure environmental stress at high sensitivity, in wide range and at high speed using functions to respond chemical substances, etc. which living organisms have. The FY 1999 results were outlined. As to the application of ecosystem information functions, survey was conduced paying attention to the environmental stress response of each of the bacteria, algae, plants and animals, responses viewed from the manifestation of immunity antibodies which occurs inside living organisms and changes at genetic level, and responses of algae and plants in case of specifying environmental pollutants. In relation to the application of the biological amplification mechanism, survey was carried out on environmental stress signals sent from plants, selection of environmental stress index plants, detection of environmental pollutants using bacteria, high sensitivity detection using animal (nematode), etc. Concerning the standardization of the environmental measuring technology by the application of ecosystem information functions, survey was conducted on artificial molecular recognition sensor, antibody device sensor, biochips, system construction, etc. (NEDO)

  11. Fiscal 2000 technology trend survey. Survey of technology trend relating to next-generation metal-based material compatible with inverse manufacturing leading to energy use rationalization; 2000 nendo gijutsu doko chosa hokokusho. Energy shiyo gorika ni kakawaru inverse manufacturing ni tekigoushita jisedai kinzoku kei zairyo ni kansuru gijutsu doko chosa

    NONE

    2001-03-01

    For the construction of a recycling system consuming less energy and therefore higher in efficiency, studies were made about the feasibility of metallic material developing/recycling systems more congruent with the objective through the application of inverse manufacturing (IM). Concerning metallic materials and recycling technologies, steel, aluminum alloys, and magnesium alloys were taken up, and a survey was made of hazardous elements in steel materials, unification of materials to constitute aluminum alloy parts, yield of magnesium in die casting, and the like. In the survey of recycling of automobiles, it was pointed out that the treatment of resin-based shredder dust was posing problems and that the use of metallic materials high in recyclability was essential to IM. In conclusion, three propositions were presented, which involved technologies for the advanced use of magnesium alloys as materials leading to the realization of IM, the development of recycling-oriented general-purpose alloys (with Mg and Al as mother metals), and the development of functional bonding technology enabling debonding (debondable bonding technology). (NEDO)

  12. Leading research for fiscal 1998 on innovative technology for the earth. Researches on technologies for creating ecology using ecosystem's information transmitting function; 1998 nendo chikyu kankyo sangyo gijutsu ni kakawaru sendo kenkyu. Seiteikei joho kino oyo ni yoru kankyo sozo gijutsu ni kansuru chosa kenkyu

    NONE

    1999-03-01

    The aim is to develop a technology for detecting environmental pollution before it becomes apparent and thereby to contribute to the development of technologies to minimize the damage that may be inflicted upon the global environment. For this purpose, researches are conducted in search of techniques to detect, at high speed with high sensitivity over a wide scope, the response of living organisms to chemicals. In a research on the application of the reaction of ecosystem to environmental stress, communication between living organisms in coping with environmental chemicals is investigated. It is then found that the growth of vegetable roots may be used as a measure for the detection of environmental pollutants but that the method is too low in sensitivity. A research is conducted on the creation of an ecological reporter function using the biological amplification technique. It is then found that the immunoreaction-aided measuring of environmental pollutants yields an excellent result in terms of sensitivity but that it has a problem in its resistance to environmental conditions. In a research on the standardization of environmental measurements using ecological information, it is found that the primary object of research and development should be a systematization technology compatible with biological functions. (NEDO)

  13. Leading research for fiscal 1998 on innovative technology for the earth. Researches on technologies for creating ecology using ecosystem's information transmitting function; 1998 nendo chikyu kankyo sangyo gijutsu ni kakawaru sendo kenkyu. Seiteikei joho kino oyo ni yoru kankyo sozo gijutsu ni kansuru chosa kenkyu

    NONE

    1999-03-01

    The aim is to develop a technology for detecting environmental pollution before it becomes apparent and thereby to contribute to the development of technologies to minimize the damage that may be inflicted upon the global environment. For this purpose, researches are conducted in search of techniques to detect, at high speed with high sensitivity over a wide scope, the response of living organisms to chemicals. In a research on the application of the reaction of ecosystem to environmental stress, communication between living organisms in coping with environmental chemicals is investigated. It is then found that the growth of vegetable roots may be used as a measure for the detection of environmental pollutants but that the method is too low in sensitivity. A research is conducted on the creation of an ecological reporter function using the biological amplification technique. It is then found that the immunoreaction-aided measuring of environmental pollutants yields an excellent result in terms of sensitivity but that it has a problem in its resistance to environmental conditions. In a research on the standardization of environmental measurements using ecological information, it is found that the primary object of research and development should be a systematization technology compatible with biological functions. (NEDO)

  14. Gd-Ni-Si system

    Bodak, O.I.; Shvets, A.F.

    1983-01-01

    By X-ray phase analysis method isothermal cross section of phase diagram of the Gd-Ni-Si system at 870 K is studied. The existence of nine previously known compounds (GdNisub(6.72)Sisub(6.28), GdNi 10 Si 2 , GdNi 5 Si 3 , GdNi 4 Si, GdNi 2 Si 2 , GdNiSi 3 , GdNiSi 2 , Gd 3 Ni 6 Si 2 and GdNiSi) is confirmed and three new compounds (GdNisub(0.2)Sisub(1.8), Gdsub(2)Nisub(1-0.8)Sisub(1-1.2), Gd 5 NiSi 4 ) are found. On the base of Gd 2 Si 3 compound up to 0.15 at. Ni fractions, an interstitial solid solution is formed up to 0.25 at Ni fractions dissolution continues of substitution type. The Gd-Ni-Si system is similar to the Y-Ni-Si system

  15. Internal carbonitriding behavior of Ni-V, Ni-Cr, and Ni-3Nb alloys

    Allen, A.T.; Douglass, D.L.

    1999-01-01

    Ni-2V, Ni-5V, Ni-12V, Ni-10Cr, Ni-20Cr, and Ni-3Nb alloys were carbonitrided in C 3 H 6 and NH 3 gas mixtures (bal H 2 ) over the range 700--1,000 C. Carbonitridation of Ni-12V and Ni-20Cr in C 3 H 6 /NH 3 /H 2 (1.5/1.5/97 v/o) and (1.5/10/88.5 v/o) produced duplex subscales consisting of near-surface nitrides with underlying carbides. Growth of each zone obeyed the parabolic rate law under most conditions. The presence of carbon generally did not effect the depth of the nitride zones compared to nitriding the alloys in NH 3 /H 2 (10/90 v/o). However, at 700 C, the nitride zones were deeper in the carbonitrided Ni-V alloys and Ni-20Cr. The presence of nitrogen generally increased the depth of the carbide zones in Ni-12V and Ni-20Cr compared to carburizing these alloys in C 3 H 6 /H 2 (1.5/98.5 v/o). VN, CrN, and NbN formed in Ni-V, Ni-Cr, and Ni-Nb alloys, respectively, whereas the underlying carbide layers contained V 4 C 3 in Ni-12V, Cr 3 C 2 above a zone of Cr 7 C 3 in Ni-20Cr, and NbC in Ni-3Nb. The solubilities and diffusivities of nitrogen and carbon in nickel were determined. Nitrogen and carbon each exhibited retrograde solubility with temperature in pure Ni in both carbonitriding environments. Nitrogen diffusion in nickel was generally lower in each carbonitriding mixture compared to nitrogen diffusion in a nitriding environment, except at 700 C when nitrogen diffusion was higher. Carbon diffusion in nickel was generally higher in the carbonitriding environments compared to carbon diffusion in a carburizing environment

  16. Nipah Virus (NiV)

    ... Form Controls Cancel Submit Search the CDC Nipah Virus (NiV) Note: Javascript is disabled or is not ... gov . Recommend on Facebook Tweet Share Compartir Nipah virus (NiV) is a member of the family Paramyxoviridae , ...

  17. Ni República parlamentaria ni presidencialista

    Álvarez Tardío, Manuel

    2004-01-01

    Revista de Estudios Políticos (Nueva Época), Núm. 123. Enero-Marzo 2004 Este trabajo está dedicado al estudio de un aspecto básico del sistema político de la II República española (1931-1936): el modelo de presidencia de la República y de relaciones de la misma con el parlamento y el gobierno. Aquí se sostiene que la Segunda República, de acuerdo con su Constitución, no fue un régimen parlamentario ni presidencial. Combinó de forma extraña y ambigua elementos de ambos modelos. Probablement...

  18. Microstructural development in NiAl/Ni-Si-B/Ni transient liquid phase bonds

    Gale, W.F.; Orel, S.V.

    1996-01-01

    A transmission electron microscopy (TEM) based investigation of microstructural development during transient liquid phase bonding of near-stoichiometric NiAl to commercial purity nickel is presented in this article. The work described employed Ni-4.5 wt pct Si-3.2 wt pct B (BNi-3) melt-spun interlayers. The precipitation of both Ni-Al based phases and borides within the joint and adjacent substrate regions is discussed. The article considers martensite formation (within the NiAl substrate) and the precipitation of L1 2 type phases (both within the joint and at the interface with the NiAl substrate). The relative roles of the two substrate materials (NiAl and Ni) in the isothermal resolidification process are identified. The preferential formation of Ni 3 B boride phases in the Ni substrate near the original location of the Ni substrate-joint interface is discussed and contrasted with the absence of similar events in the NiAl substrate

  19. Ni landsbyer i Danmark

    Larsen, Jacob Norvig

    Denne rapport beskriver en evaluering af statsstøttede forsøg med at styrke og udvikle mindre lokalsamfund. Forsøgene er gennemført i ni kommuner. Da der i disse år er stor opmærksomhed om de små byers og samfunds udviklingsmuligheder, har erfaringerne fra forsøgsprojekterne bred interesse. Forsø...

  20. Reduction mechanism of Ni2+ into Ni nanoparticles prepared from ...

    journal of. March 2009 physics pp. 577–586. Reduction mechanism of Ni2+ into Ni ..... and at high field, no domain wall is available and hence, the system becomes a .... [23] J Ding, T Tsuzuki, P G McCormick and R Street, J. Phys. D: Appl.

  1. Achievement report for fiscal 1999 on development of 'technology to promote reduction of discharge of dioxins and development of technology to suppress discharge of dioxins in aluminum product manufacturing processes'; 1999 nendo dioxine rui haishutsu sakugen sokushin gijutsu kaihatsu seika hokokusho. Aluminium seihin seizo kotei ni okeru dioxin rui no haishutsu yokusei seigyo no kaihatsu

    NONE

    2001-03-01

    Research and development has been performed with an objective to reduce discharge of dioxins in aluminum product manufacturing processes. With regard to the quantity of chlorine used in aluminum molten metal refining process, the refining tests using 100% chlorine gas and the mixed gas (nitrogen gas mixed at 80%) revealed that either gas has approximately the same degassing performance, and the use of the mixed gas can reduce the amount of chlorine used. Dioxin concentrations in the gas discharged from the refining process were measured under the refining condition using less amount of chlorine. As a result, it was verified that, in the case of using 20% chlorine gas plus 80% nitrogen gas, the concentrations of dioxins decrease to about l/6, or 0.6 ng-TEQ/N{sup 3}. The studies on suppressing the discharge of dioxins from the facility to wash chlorine treatment exhaust gas discovered that dioxin concentration in the scrubber circulating solution can be suppressed to 1/10 or less by means of gravity precipitation and separation of the suspended liquid. It was also made clear that pH should preferably be controlled to 10.5 to separate suspended substances from the precipitated solution. (NEDO)

  2. Fiscal 1999 report on basic research for promotion of joint implementation programs. Gas pipeline system optimization involving Ukrainian pipeline modification for reduction in global warming gas emissions; 1999 nendo ondanka gas haishutsu sakugen no tame no Ukraina ni okeru gas pipeline no kaishu wo fukumu pipeline system no saitekika chosa hokokusho

    NONE

    2000-03-01

    The result of a survey which involves a 520km-long gas pipeline (Shebelinka-Dikanka-Kyiv) modification in the Ukraine is described, which will promote joint implementation programs under COP3 (Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change). Since the greenhouse effect of methane gas is 21 times as serious as that of CO2, it is important to ensure good maintenance and structural soundness for natural gas transporting pipeline systems. The currently available Ukrainian gas turbines and compressors are so obsolescent that their efficiency rate is as low as 23%. The rate will rise to 36% when the old ones are replaced by high power equipment capable of high efficiency combustion. Pipelines will be checked for deterioration due to stress corrosion cracking and dangerous pipes will be replaced, with attention paid particularly to joint sections. It is expected that there will be a greenhouse gas reduction of 512,000 tons (in terms of CO2) and a saving of 103,000 tons on fuel (in terms of crude). Balance is tentatively estimated in case the expected reduction in emissions is transacted in emission trading. Profitability will occur, in view of profit from emission trading and gas sales revenue after gas leakage prevention thanks to project implementation, when the emission right sells at 30 dollars/ton or higher. The rippling effect will be great now that the Ukrainian pipeline system is quite extensive (with 30% thereof superannuated). (NEDO)

  3. FY 2000 Development of technologies for optimization control of reducing power loss during the service period. Report on the research and development results of the 'building total cooperation control by micro-internet technologies'; 2000 nendo kadoji denki sonshitsu sakugen saiteki seigyo gijutsu kaihatsu seika hokokusho. Micro internet gijutsu ni yoru biru total kyocho seigyo

    NONE

    2001-03-01

    The research and development project is implemented for development of the energy-saving optimization/control system which continuously monitors/controls all of the energy-consuming appliances in a building for their optimization, and the FY 2000 results are reported. The program for the sensing technologies involves a human tracking system aided by fish-eye images and human region sensing technologies based on the neuro technologies, and introduces an animated image simulation system aided by a personal computer. The researches on the building total cooperation control involve establishment of the system designs for controlling heat sources, based on the thermal loads predicted by the information network system. The researches on the micro-internet technologies involve development of the prototype unit which collects information from indoor environment sensors (e.g., for room temperature, luminous intensity and CO2 concentration), and interface devices which collect information from the sub-systems, e.g., air conditioners and heat sources. These systems are completed. The demonstration and assessment program involves designs of the instrumentation systems and network environments. The designs are completed, and various sensors and monitors are installed. (NEDO)

  4. Fiscal 1999 report on basic research for promotion of joint implementation programs. Research on introduction of dual mode bus system for greenhouse gas reduction; 1999 nendo onshitsu koka gas sakugen no tame no dual mode bus system donyu ni kansuru chosa hokokusho

    NONE

    2000-03-01

    A feasibility study is conducted of the above-named system in Malaysia, to be linked to COP3 (Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change) clean development mechanism (CDM). The dual mode bus system (DMBS) is a combination of advantages of the rail running stock such as monorails and the road running stock in that the buses when running on dedicated roads are automatedly formed into a linear formation and travel at a specified economical speed. When running on ordinary roads, the formation is broken into individual buses, and they spread in the town where they travel in a planar pattern. The economical speed and reduction in air drag thanks to the linear formation saves fuel and reduces CO2 emissions. The complementary relationship to be formed with the existing public transportation systems will also function positively. Studies are conducted on condition that two routes be laid in the Kuala Lumpur urban area and one in the new city Putra Jaya. All the three routes exhibit a high economic internal rate of return, but their financial internal rate of return indicates that probabilities are low that they will pay as private businesses. They will need financial supports such as subsidies. Contribution to CO2 reduction may be slight when attention is paid only to the partial changeover from the existing bus system to DMBS but larger contribution will be found in crossover from private cars to DMBS which is higher in quality of service. (NEDO)

  5. Report on survey of the CO2 reducing effects of regional heat supply system for urban areas in FY 1997; 1997 nendo chosa hokokusho (toshiiki wo taisho to shita koiki netsu kyokyu system no CO2 sakugen koka ni kansuru chosa)

    NONE

    1998-03-01

    This report introduces regional heat supply systems using unused energy in Japan and overseas. Evaluation examples of their CO2 reducing effects are arranged. The introduction effects were quantitatively evaluated in some urban areas in Tokyo. For the evaluation, not only the conventional energy efficiency but also energy saving and CO2 reducing effects secondarily derived from the release of a rise of temperature in urban areas were quantified, to investigate their economy. Synthetic introduction effects were estimated. As a result of the case study, the system was confirmed to be a prospective option to make CO2 reduction more than 10% in the target district. Particularly in summer, about one-fourth of the effect was brought by the restriction of heat island phenomenon. When soil heat source type district heating and cooling system was applied to the whole redevelopment area, it was found that CO2 reducing effect of the whole Tokyo is only less than 0.1%. 40 refs., 64 figs., 43 tabs.

  6. FY 2000 Development of technologies for optimization control of reducing power loss during the service period. Report on the research and development results of the 'building total cooperation control by micro-internet technologies'; 2000 nendo kadoji denki sonshitsu sakugen saiteki seigyo gijutsu kaihatsu seika hokokusho. Micro internet gijutsu ni yoru biru total kyocho seigyo

    NONE

    2001-03-01

    The research and development project is implemented for development of the energy-saving optimization/control system which continuously monitors/controls all of the energy-consuming appliances in a building for their optimization, and the FY 2000 results are reported. The program for the sensing technologies involves a human tracking system aided by fish-eye images and human region sensing technologies based on the neuro technologies, and introduces an animated image simulation system aided by a personal computer. The researches on the building total cooperation control involve establishment of the system designs for controlling heat sources, based on the thermal loads predicted by the information network system. The researches on the micro-internet technologies involve development of the prototype unit which collects information from indoor environment sensors (e.g., for room temperature, luminous intensity and CO2 concentration), and interface devices which collect information from the sub-systems, e.g., air conditioners and heat sources. These systems are completed. The demonstration and assessment program involves designs of the instrumentation systems and network environments. The designs are completed, and various sensors and monitors are installed. (NEDO)

  7. Report on a survey in fiscal 1999. Survey on electric power systems for reducing CO2 emission (an approach to scenario analyses); 1999 nendo CO{sub 2} sakugen no tame no denryoku system ni kansuru chosa hokokusho. Scenario kaiseki no approach

    NONE

    2000-03-01

    The purpose of this survey is to extract by using scenario analyses the unreliable factors having great influence on change in the Japanese power supply configurations, and verify how the unreliability of these factors would affect the future structures and what the resultant ratio of the power mixes would be in the future. The survey is also intended to verify, through a series of work of calculating how much CO2 emission quantity would be changed in the stage of the year 2012 in each power supply configuration, whether or not the approach by using the scenario analyses will provide information sufficiently reasonable to judge policies to realize reduction in CO2 emission around the electric power business. Although including many hypotheses and vagueness, the trial calculation subjected to each scenario prepared presently suggested that it is not possible to accomplish the target of reducing 9% from the 1990 emission level only by the single efforts inside Japan. This result shows the same contents and directionality that are shown by the results of a large number of surveys. However, the result has created a common recognition among the participants that {sup t}here is a possibility that some kind of effective countermeasures could be discovered{sup .} (NEDO)

  8. Research report for fiscal 1998. Basic research for promoting joint implementation for CO{sub 2} reduction at Keio University; 1998 nendo chosa hokokusho. Keio Gijuku Daigaku ni yoru CO{sub 2} sakugen no tame no kyodo jisshi suishin kiso chosa

    NONE

    1999-03-01

    A research is conducted into China's current problems of energy-related environments, and studies are made for the assessment of its potentials for greenhouse gas reduction, such as CO2 from coal, and for the prevention of environmental pollution in urban areas. By the survey of the current states of the supply and demand of energy and heat in China, and in Beijin, it is found that fuel conversion, which means the disuse of coal in this case, is necessary for a success in SO2 measures in the heat supply department. Since the rate of concentrated heat supply undertaken by heat supply businesses is low, it is inferred that potentials for CO2 reduction are quite high in this department. Concerning technological problems about conversion from coal to natural gas and heat supply, deliberation is made on a scenario covering how to approach the energy demand model, combustion in the natural gas boiler, and the home heating fuel. In discussing air pollution in China, the difficulty known as transboundary air pollution is taken up. It is concluded that conversion from coal to natural gas or coal disuse will serve effectively the purposes of energy saving, SO2 reduction, and CO2 reduction. (NEDO)

  9. Report on achievement in the preceding research related to global industry technologies for the global industry technology research and development project. Research on gas systems substituting global warming gases such as PFC used in manufacturing semiconductors; 1998 nendo chikyu kankyo sangyo gijutsu ni kakawaru sendo kenkyu. Handotai seizo nado ni shiyosuru PFC nado no chikyu ondanka gas no daitai gas system no kenkyu

    NONE

    1999-03-01

    The present semiconductor manufacturing process uses a great amount of PFC having large global warming coefficients and extremely long atmospheric life. A research was made particularly on reduction of its emission from etching processes. After introducing how the semiconductor industry has been working conventionally on protection of the global environment, this paper makes clear the purpose and positioning of this preceding research, as well as how it is moved forward. The paper also reports the results of analyzing and discussing the exhaust gases from etching devices using several kinds of substitute PFC gases. Survey results are reported on the possibilities of new substitute gases, plasma decomposition and treatment of exhaust gases, reaction process simulation, and in-situ analyzing and evaluating technologies. Investigations were made on the possibility of using no PFC in wiring processes which consume greater amount of PFC, as well as on wiring techniques using inter-layer insulation film with low dielectric rate, a new wiring structure forming technology, new functional elements, circuits and systems in a wide range. Proposals were given on specific research and development themes and plans that begin in fiscal 1999. (NEDO)

  10. FY 1999 report on the results of the introductory study on the global environmental industry technology. Study of the technology to recycle organic waste as resource in the chemical industry; 1999 nendo chikyu kankyo sangyo gijutsu ni kakawaru sendo kenkyu seika hokokusho. Kagaku kogyo ni okeru yukisei haikibutsu no saishigenka gijutsu no kenkyu

    NONE

    2000-03-01

    An investigational study was conducted of applicability/viability of the technology to recycle as resource the organic waste and CO2 discharged from the chemical industry, etc., and the FY 1999 results were summarized. As to the production of hydrogen from the organic waste, a bioreactor was developed which enables the production of hydrogen of 58 mmol/L/hr using Enterobactor aerogenes by the isolation bacteria method, and it successfully enabled the production of hydrogen from biomass resource. Further, the micro-flora method can be responded to a variety of substrates, but in this method the hydrogen production rate is not as high as in the isolation bacteria method at the present time. Concerning the method to convert CO2 to useful organic resource by the hydrogen produced, an experimental value of the maximum production rate of 149g/L/d which is high was obtained in case of acetic acid. Moreover, the paper described an outline and the basic concept of the recycle system of energy and carbon resource which integrates the production of energy from organic waste being considered at the present time and the production of useful matters from CO2. (NEDO)

  11. Fiscal 2000 research report on the study on new device material, measurement, and analysis technologies for data communication base improvement program; 2000 nendo joho tsushin kiban kodoka program ni kakawaru shin device zairyo keisoku kaiseki gijutsu ni kansuru chosa kenkyu hokokusho

    NONE

    2001-02-01

    Concerning the 'new device material, measurement, and analysis technologies' which is one of the important technological constituent of the data communication base improvement program, investigations were conducted as to the future direction of middle-term technology development efforts and the important tasks to discharge. Workshops were organized to deal with the subjects named below, and the results of discussion were made into a report. It is proposed in the report that common recognition be fomented about future feasibility of the development of the new device material, measurement, and analysis technologies; that presentations be made as to how the development of the new device material, measurement, and analysis technologies should be carried out in what direction; that the tasks to discharge for the new device material, measurement, and analysis technologies be clearly defined; and the like. It is also decided that findings offered by experienced people of the industrial, academic, and government circles be fully utilized at deliberation conferences and that studies be conducted for the implementation in the future of the data communication base improvement program. Materials on the 1st-4th semiconductor program study meetings and EIAJ (Electronic Industries Association of Japan)/NEDO (New Energy and Industrial Technology Development Organization) workshops are collected in the report. (NEDO)

  12. Fiscal 1999 survey report on basic feasibility concerning model project for energy conservation in fiber dyeing and processing industry in Thailand; 1999 nendo Tai ni okeru sen'i senshoku kako sangyo no sho energy ka model jigyo ni kakawaru kihonteki jisshi kanosei chosa hokokusho

    NONE

    2001-03-01

    A feasibility study was conducted for the implementation of the optimum model project in the fiber dyeing and processing industry in Thailand. This paper describes the results of fiscal 1999. Seventy percent of about 400 companies are those heavily consuming energy, while small-scale businesses having a production capacity of less than one million yards/month take the sixty percent of the industry. Their energy conserving measures are behind. Measures against ground subsidence and drainage cost these companies greatly. Trade competition with China and others is being intensified. Although designated under the Energy Saving Promotion Act, the plants are not enjoying the privilege. Needed for the energy saving measures are grasp of the current situation such as energy consumption status, thorough operation management, improvement of energy efficiency in the present production facilities, renewal/additional installation of production equipment, and implementation of developmental energy saving measures. As energy conservation measures are deemed adaptable to the industry if the investment recovery period is two years or less, diagnostic analysis was made on six plants, with diffusion of the result examined. The total energy consumption of the industry was estimated to be reducible by 35% through high-recovery-rate measures such as improvement of boilers, recovery of exhaust heat, control of energy consumption rate, and introduction of dyeing machines having low liquor ratio. (NEDO)

  13. Feasibility study of international cooperation in the research/development of a solar energy utilization system by the innovative solar thermochemical process; Kakushinteki solar netsukagaku process ni yoru taiyo energy riyo system no kaihatsu kenkyu ni kakawaru kokusai kyoryoku kanosei chosa

    NONE

    1998-03-01

    At COP3 in 1997, an agreement was made to the innovative technical development/promotion by international cooperation, and the promotion of transfer of environmental technology to developing countries. Under the agreement, a feasibility study of international cooperation was made, and especially a study was conducted of the utilization/development of solar energy by the innovative solar thermochemical process. The main reason for global warming is emissions of a large amount of CO2 caused by the direct combustion of fossil fuels. Therefore, a CO2 recycle system taken up in the study enables a more substantial decline in CO2 emission (kg/kWh) per unit generation than the conventional thermal power system by composing solar methanol or solar dimethyl ether using fossil fuels including coal, water, CO2, etc. as raw materials and using solar energy as heat source, and by using this as fuel (solar fuel). CO2 can be reduced by 13% to 14% by substituting solar methanol or solar dimethyl ether produced from petroleum/methane equivalent-mol mixed raw materials for the equivalent mol coal and natural gas of the thermal power plant (CO2 recovery is not necessary). 34 refs., 47 figs., 34 tabs.

  14. FY 1999 survey report on the research survey on the formation of a social consensus on the introduction of the global warming mitigation technology; 1999 nendo ondanka taisaku gijutsu no donyu ni kakawaru shakaiteki goi keisei ni kansuru chosa kenkyu hokokusho

    NONE

    2000-03-01

    As to the development and introduction of the global warming mitigation technology, the paper studied an approach to the formation of a social consensus and how to apply concrete methods and proposed a realistic approach in the light of the present situation of public enterprises in Japan. As tools and rules which are particularly important in activities of forming the consensus, the paper cited up what the PR control should be, responses to mass communications, HP making and regulation/preparation of the related laws, and made a concrete study. As examples in which there occurred friction with the society due to the insufficient formation of consensus, the following construction plans were taken up to consider problems, etc. in disclosure of the information in the plans: Underground Research Laboratory, movable weir in the Yoshino River, and waste disposal facilities at Fuimae tideland. Also in Japan, some methods for the consensus formation have been carried out, and in the survey, as concepts for classifying the methods, two different approaches, Public Outreach and Public Relations, were introduced. As to the former, a consensus formation method in the construction of power plants in Japan was introduced, and as to the latter, a method in consensus conferences in the U.K. (NEDO)

  15. FY 2000 report on the survey project on the environmentally friendly energy community, excluding mostly projects on electric power generation. Survey project on the environmentally friendly energy community in the Nagoya area; 2000 nendo kankyo chowagata energy community chosa jigyo 'shutoshite hatsuden jigyo ni kakawaru mono wo nozoku' chosa hokokusho. Nagoya chiiki ni okeru kankyo chowagata energy community chosa jigyo

    NONE

    2001-03-01

    The paper studied the working-out of the basic plan on the RPF (refuse paper and plastic fuel) production business in the area mainly including Nagoya city and of the business profitability. RPF is a solid fuel made by grinding, mixing and pressurizing paper and plastics in appropriate sizes. Its shape and calorific value can be adjusted according to the needs. In the Nagoya area, the demand for RPF is more than the supply, and therefore a much larger amount of RPF is in need. In Phase 1, business was studied for paper and plastics in the container packing paper waste and business-derived general waste. As a result, the RPF production amount was 21,000 t/y, which is equivalent to the effect of reduction of the same amount of coal. As to the profitability, it was made clear that the business can be profitable if collecting 41,400 yen/ton as the re-commercialization cost. In Phase 2, the design of the facilities was made for the larger-sized commercialization by adding industrial waste plastics to the waste in Phase 1. (NEDO)

  16. FY 1999 report on the potential survey of the environmental friendly type coal utilization system. Survey on the spread/promotion of circulating fluidized bed boilers in China; 1999 nendo chosa hokoksho. Kankyo chowagata sekitan riyo system kanosei chosa. Chugoku ni okeru junkan yukaboira no fukyu sokushin ni kakawaru chosa

    NONE

    2000-03-01

    For the purpose of contributing to the spread/promotion of Japanese-make circulating fluidized bed boilers with desulfurization function, survey was conducted of the state of utilization of circulating fluidized bed boilers, the needs, etc. in China. In the survey, field survey was made at two boiler manufacturers and four companies using boilers in Beijing city, Fujian province, Hubei province, etc. to grasp the state of utilization and study conditions for the spread/promotion of circulating fluidized bed boilers. The Chinese government is making efforts for the spread of circulating fluidized bed boilers. The number of the domestically existing circulating fluidized bed boilers is estimated at approximately 800, but almost none of them conducts furnace desulfurization. Further, the operating rate of boiler is not always high. The reasons are as follows: desulfurization costs high without connecting to the production; environmental regulation is still mild in China; reliability and maintenance technique are still at low levels. It is urgently desirable to spread highly reliable circulating fluidized bed boilers with desulfurization function, and accordingly, it is necessary to reduce the cost of Japanese-make boilers. (NEDO)

  17. Fiscal 2000 technology trend survey. Survey and study report on the development of high-frequency devices to support IT revolution leading to energy use rationalization; 2000 nendo gijutsu doko to chosa. Energy shiyo gorika ni kakawaru IT kakumei wo support suru koshuha device no kaihatsu ni kansuru chosa kenkyu hokokusho

    NONE

    2001-03-01

    Surveys and studies were conducted for the development of technologies basic to the construction of an ultrahigh-speed huge-capacity high-frequency radio access and communication network, especially the network infrastructure, in the several 10 to several 100 GHz band. Some surveys covered the positioning of high-frequency high-output device modules as the key component, needs for their use in radio communication equipment, devices to be needed for their construction, technologies for their manufacture, process technologies for their embodiment, basic technologies for their materials, and so forth. Some others covered research on the marketability of high-frequency devices in the future, development of relevant technologies abroad, and so forth. The mainstream of high-frequency devices these days rests on the secondary electron gas system based on GaAs and InP, and therefore it is intrinsically difficult for them to yield high outputs. It is deemed to be important to develop technologies based on novel semiconductor materials, such as nitride semiconductors which have excellent properties as materials, toward the construction of a network infrastructure for the next generation. (NEDO)

  18. Achievement report for fiscal 1981 on Sunshine Program-assisted project. Survey of Australian industrial capability and construction capability relative to Australian brown coal liquefaction plant construction project; 1981 nendo Goshu kattan ekika plant no kensetsu ni kakawaru kogyoryoku, kensetsu kojiryoku ni kansuru chosa seika hokokusho

    NONE

    1982-03-01

    The industrial capability and construction capability of Australia are surveyed in relation with the project of constructing a brown coal liquefaction plant there. Australian heavy industry is conspicuously advanced in the field of mining machinery involving coal, iron ore, and other mineral resources. On the other hand, in the fields of general-purpose machinery for plants and of civil engineering machinery, it is behind other countries in terms of technology and cost because of the small market. When an industrial project is implemented in Australia, consulting firms, engineering contractors, etc., operate independently from each other, and the project is propelled forward under a perfect specialization system. Labor-related problems in the civil engineering and construction industry are the recruitment of laborers which is difficult and the delay in and suspension of construction due to labor disputes that take place very frequently. In Victoria State where a brown coal liquefaction plant is under construction, the availability of laborers specializing in construction is rather higher than in other states, and there is no important problem in this respect. One cannot be too prudent in Victoria State, however, since it includes a region which is the most notorious in Australia in terms of labor-management dispute. (NEDO)

  19. Fiscal 2000 project for promoting international cooperation. Survey report on preparation of technological information in APEC region (Upstream area: preparation of video for training); 2000 nendo kokusai kyoryoku suishin jigyo chosa hokokusho. APEC iki nai ni okeru gijutsu joho seibi ni kakawaru chosa (Joryu bunya - kenshu you video sakusei)

    NONE

    2001-03-01

    With the purpose of spreading and promoting clean coal technology (CCT) in coal producing countries in the APEC region, videos for training use were prepared so as to contribute to the reduction in environmental problems through the introduction of the coal cleaning and wastewater treatment technologies used in Japanese mines. In the video, comparison is made between the untreated wastewater and cleaned water flowing in and out of a present coal-cleaning plant, with the purification ratio determined, recognisably showing the effect by the cleaning facilities, and introducing the type of equipment required to satisfy the standard under the regulation. Also introduced is a technology for utilizing sludge collected in a sedimentation pond and fly ash scavenged in a private power plant. The videotape was prepared for 40 reels in English, 40 in Chinese, and 20 in Indonesian. The video title is 'Environmental safeguard of coal cleaning plant', and the contents are the importance of wastewater treatment and measures against water pollution, wastewater treatment technology in Taiheiyo coal mines, and wastewater treatment technology in Ikeshima coal mines. (NEDO)

  20. Research report of fiscal 1997. Research on the projects on Activities Implemented Jointly Japan Program (feasibility research on energy saving by improving heat management for hot blast stoves and heating furnaces); 1997 nendo chosa hokokusho. `Kyodo jisshi katsudo Japan Program` ni kakawaru project chosa (neppuro, kanetsuro no netsukanri kaizen ni yoru sho energy kanosei chosa)

    NONE

    1998-03-01

    Research was made on joint implementation (JI) for preventing global climate changes in China. Since such the stove and furnace consume a large amount of energy, their improvement and energy saving are important for integrated iron plants. Maanshan iron plant was selected for the research. All the furnaces were manually operated without combustion control systems, and oxygen meters for exhaust gas frequently troubled. As measures for the stoves, operation at a proper air fuel ratio, improvement of over heat storage combustion, and dust cleaning for waste heat recovery gas heaters were proposed. For the furnaces, a proper oxygen content at the end of furnaces (reduction of invasion air) was proposed to improve exhaust gas loss up to that in Japan. For this target, reinforced instrument management and standardized combustion control are essential. JI of software improvement for operation and management can reduce annual greenhouse effect gas emission to 45,900t and 6,300t in carbon equivalent for the stove and furnace, respectively. CO2 reduction is also estimated to be 1,173,000t and 205,000t in China of 107,570,000t in raw steel production, respectively. 28 figs., 32 tabs.

  1. Survey report in fiscal 1999 on investigations for the current status in energy and environmental problems in Japan and the U.S.A., and investigations on technological development related to energies; 1999 nendo Nichibei ni okeru energy kankyo mondai no genjo chosa oyobi energy ni kakawaru gijutsu kaihatsu chosa hokokusho

    NONE

    2000-03-01

    This paper reports the surveys in fiscal 1999 on energy and developmental problems in Japan and the U.S.A. New and complex environmental problems are rising to the surface, such as global warming, ozone layer destruction, and chemical harms. It is necessary to deepen quickly scientific understanding of the problems, and identify accurately their impacts on human bodies and ecological systems. Within the limitation of the scientific understanding, political decisions on economy and environmental risks are also important and difficult questions, with the environmental hormones being the typical examples. Establishing chemical substance verification systems is important, whereas joint researches by Japan and the U.S.A. are desired. Policy decisions on handling the researches must also be made jointly, and acceptance by citizens must be asked for at international workshops. While energies are the base of economic activities, and the sustained development thereof is indispensable, how to take balance with health and environment in the global scale is a large assignment. Joint Japan-U.S. discussions are required on technological innovation, such as for regenerative energies, energy conservation, safety of and wastes from nuclear reactors, clean use of fossil fuels, and fuel cells. International cooperation, including that from developing countries, is also important. (NEDO)

  2. Achievement report for fiscal 1998 on the preceding research related to global environment industry technologies. Survey and research on reduction of nitrogen monoxide; 1998 nendo chikyu sangyo gijutsu ni kakawaru sendo kenkyu asanka chisso no haishutsu teigen ni kansuru chosa kenkyu seika hokokusho

    NONE

    1999-03-01

    Nitrogen monoxide is a strong greenhouse effect gas having warming up index per molecule 300 times greater than that of CO2, and is designated as the object of reduction in the Kyoto Conference. The present preceding research discusses necessity of performing research and development works related to reducing the emission of nitrogen monoxide, and if it is necessary, places the final objective on proposition of what researches should be planned. Fiscal 1997 being the first fiscal year of the preceding research has surveyed emission amount from different emission sources, and enumerated the research and development assignments. Fiscal 1998 falling under the final fiscal year summarizes the emission amount including the future trends, surveys the feasibility of the promising technological measures through experiments, and proposed finally a research and development plan desired of implementation in the future. The proposal contains a research plan placing development of nitrogen monoxide decomposing catalysts and automobile catalysts as the main objectives. Among the domestic nitrogen monoxide generating sources, about 2/3 is the man-made generation sources, hence catalysts, if developed, may be applied to such facilities as combustion furnaces. (NEDO)

  3. Fiscal 2000 survey report. High-efficiency energy system introduction promotion project for houses and structures - Houses (Technical classification tables prepared by analysis of proposed systems, and comments on the same); 2000 nendo jutaku kenchikubutsu kokoritsu energy system donyu sokushin jigyo (jutaku ni kakawaru mono) teian system no bunseki ni yoru gijutsu bunruihyo oyobi dokaisetsu

    NONE

    2001-03-01

    As an energy conservation promotion measure, a project is under development for introducing and subsidizing high-efficiency energy systems and for letting their effect known publicly and widely. The number of proposed energy systems has increased greatly and technical divisions to follow in classifying them have become vague, from which problems are now arising over the execution of follow-up checks and the maintenance of fair treatment. In the effort to solve this problem, 376 propositions are analyzed and classified, a technical classification method is proposed, and an instruction manual on the method is compiled. The classification involves (1) proposed classification, (2) variation, (3) energy reduction rate, and (4) tentatively calculated cost. Item (1) deals with the basic classification (air-conditioning, ventilation, and hot water supply, and, to be considered in combination with them, options which are cooking, illumination, and others) and, item (2) covers eight items such as new/old construction, structure, and structural frame. In Chapter 1 of the report, the 376 propositions are put in order according to common classification items and an original classification table is prepared. In Chapter 2, the goals are clarified and the classification principles are defined. In Chapter 3, the classification is checked for its validity and some realistic ways of grouping are described. In Chapter 4, a classification implementation flow chart is shown. (NEDO)

  4. Reactive Ni/Ti nanolaminates

    Adams, D. P.; Bai, M. M.; Rodriguez, M. A.; McDonald, J. P.; Jones, E. Jr.; Brewer, L.; Moore, J. J.

    2009-01-01

    Nickel/titanium nanolaminates fabricated by sputter deposition exhibited rapid, high-temperature synthesis. When heated locally, self-sustained reactions were produced in freestanding Ni/Ti multilayer foils characterized by average propagation speeds between ∼0.1 and 1.4 m/s. The speed of a propagating reaction front was affected by total foil thickness and bilayer thickness (layer periodicity). In contrast to previous work with compacted Ni-Ti powders, no preheating of Ni/Ti foils was required to maintain self-propagating reactions. High-temperature synthesis was also stimulated by rapid global heating demonstrating low ignition temperatures (T ig )∼300-400 deg. C for nanolaminates. Ignition temperature was influenced by bilayer thickness with more coarse laminate designs exhibiting increased T ig . Foils reacted in a vacuum apparatus developed either as single-phase B2 cubic NiTi (austenite) or as a mixed-phase structure that was composed of monoclinic B19 ' NiTi (martensite), hexagonal NiTi 2 , and B2 NiTi. Single-phase, cubic B2 NiTi generally formed when the initial bilayer thickness was made small.

  5. Electroplated Ni on the PN Junction Semiconductor

    Kim, Jin Joo; Uhm, Young Rang; Son, Kwang Jae; Kim, Jong Bum; Choi, Sang Moo; Park, Jong Han; Hong, Jintae [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-05-15

    Nickel (Ni) electroplating was implemented by using a metal Ni powder in order to establish a Ni-63 plating condition on the PN junction semiconductor needed for production of betavoltaic battery. PN junction semiconductors with a Ni seed layer of 500 and 1000 A were coated with Ni at current density from 10 to 50 mA cm{sup 2}. The surface roughness and average grain size of Ni deposits were investigated by XRD and SEM techniques. The roughness of Ni deposit was increased as the current density was increased, and decreased as the thickness of Ni seed layer was increased.

  6. Electroplated Ni on the PN Junction Semiconductor

    Kim, Jin Joo; Uhm, Young Rang; Son, Kwang Jae; Kim, Jong Bum; Choi, Sang Moo; Park, Jong Han; Hong, Jintae

    2015-01-01

    Nickel (Ni) electroplating was implemented by using a metal Ni powder in order to establish a Ni-63 plating condition on the PN junction semiconductor needed for production of betavoltaic battery. PN junction semiconductors with a Ni seed layer of 500 and 1000 A were coated with Ni at current density from 10 to 50 mA cm 2 . The surface roughness and average grain size of Ni deposits were investigated by XRD and SEM techniques. The roughness of Ni deposit was increased as the current density was increased, and decreased as the thickness of Ni seed layer was increased

  7. Synthesis and electrochemical behavior of nanostructured cauliflower-shape Co-Ni/Co-Ni oxides composites

    Gupta, Vinay; Kawaguchi, Toshikazu; Miura, Norio

    2009-01-01

    Nanostructured Co-Ni/Co-Ni oxides were electrochemically deposited onto stainless steel electrode by electrochemical method and characterized for their structural and supercapacitive properties. The SEM images indicated that the obtained Co-Ni/Co-Ni oxides had cauliflower-type nanostructure. The X-ray diffraction pattern showed the formation of Co 3 O 4 , NiO, Co and Ni. The EDX elemental mapping images indicated that Ni, Co and O are distributed uniformly. The deposited Co-Ni/Co-Ni oxides showed good supercapacitive characteristics with a specific capacitance of 331 F/g at 1 mA/cm 2 current density in 1 M KOH electrolyte. A mechanism of the formation of cauliflower-shape Co-Ni/Co-Ni oxides was proposed. A variety of promising applications in the fields such as energy storage devices and sensors can be envisioned from Co-Ni/Co-Ni oxides

  8. Radiochemical method for 63Ni

    Holm, E.; Nilsson, U.; Hallstadius, L.

    1985-01-01

    A radianalytical method for the determination of 63 Ni content in environmental samples of activated corrosion products is described. After chemical separation and electrodepositing of 63 Ni on silver briquets, the chemical yield is determined by X-ray fluorescence analysis. For the detection of low-energy beta activity, an open gas flow GM-counter with an anticoincidence guard counter is put to use

  9. Electronic structure of Ni/sub 3/Al and Ni/sub 3/Ga alloys

    Pong, W F; Chang, Y K; Tsai, M H; Hsieh, H H; Pieh, J Y; Tseng, P K; Lee, J F; Hsu, L S

    1999-01-01

    This work investigates the charge transfer and Al(Ga) p-Ni d hybridization effects in the intermetallic Ni/sub 3/Al(Ni/sub 3/Ga) alloy using the NiL/sub 3.2/- and K-edge and Al(Ga)K X-ray absorption near edge structure (XANES) measurements. We find that the intensity of white-line features at the NiL/sub 3.2/-edge in the Ni/sub 3/Al(Ni /sub 3/Ga) alloy decreased in comparison with that of pure Ni, which can be attributed to the enhancement of Ni3d states filling and the depletion of the density of Ni 3d unoccupied states in the Ni/sub 3 /Al(Ni/sub 3/Ga) alloy. Two clear features are also observed in the Ni/sub 3/Al(Ni/sub 3/Ga) XANES spectrum at the Al(Ga) K-edge, which can be assigned to the Al(Ga) unoccupied 3p (4p) states and their hybridized states with the Ni 3d/4sp states above the Fermi level in Ni/sub 3/Al(Ni/sub 3/Ga). The threshold at Al K-edge XANES for Ni/sub 3/Al clearly shifts towards higher photon energies relative to that of pure Al, indicating that Al loses charges upon forming Ni/sub 3 /Al. ...

  10. Nitriding behavior of Ni and Ni-based binary alloys

    Fonovic, Matej

    2015-01-15

    Gaseous nitriding is a prominent thermochemical surface treatment process which can improve various properties of metallic materials such as mechanical, tribological and/or corrosion properties. This process is predominantly performed by applying NH{sub 3}+H{sub 2} containing gas atmospheres serving as the nitrogen donating medium at temperatures between 673 K and 873 K (400 C and 600 C). NH{sub 3} decomposes at the surface of the metallic specimen and nitrogen diffuses into the surface adjacent region of the specimen whereas hydrogen remains in the gas atmosphere. One of the most important parameters characterizing a gaseous nitriding process is the so-called nitriding potential (r{sub N}) which determines the chemical potential of nitrogen provided by the gas phase. The nitriding potential is defined as r{sub N} = p{sub NH{sub 3}}/p{sub H{sub 2}{sup 3/2}} where p{sub NH{sub 3}} and p{sub H{sub 2}} are the partial pressures of the NH{sub 3} and H{sub 2} in the nitriding atmosphere. In contrast with nitriding of α-Fe where the nitriding potential is usually in the range between 0.01 and 1 atm{sup -1/2}, nitriding of Ni and Ni-based alloys requires employing nitriding potentials higher than 100 atm{sup -1/2} and even up to ∞ (nitriding in pure NH{sub 3} atmosphere). This behavior is compatible with decreased thermodynamic stability of the 3d-metal nitrides with increasing atomic number. Depending on the nitriding conditions (temperature, nitriding potential and treatment time), different phases are formed at the surface of the Ni-based alloys. By applying very high nitriding potential, formation of hexagonal Ni{sub 3}N at the surface of the specimen (known as external nitriding) leads to the development of a compound layer, which may improve tribological properties. Underneath the Ni{sub 3}N compound layer, two possibilities exist: (i) alloying element precipitation within the nitrided zone (known as internal nitriding) and/or (ii) development of metastable and

  11. Ni4Ti3 precipitate structures in Ni-rich NiTi shape memory alloys

    Holec, D.; Bojda, O.; Dlouhy, A.

    2008-01-01

    Non-uniform distributions of Ni 4 Ti 3 precipitate crystallographic variants are investigated in a Ni-rich NiTi shape memory alloy after aging, assisted by external stress. A finite-element method model is presented that considers the elastic anisotropy of the B2 parent phase and also mutual misorientations of grains in a polycrystalline sample. On loading by the external stress, the stress is redistributed in the microstructure and the precipitation of some Ni 4 Ti 3 crystallographic variants becomes distinctly favorable in grain boundary regions since these variant configurations minimize the elastic interaction energy. The volume fraction of the affected grain boundary regions is calculated and the numerical results are compared with the data obtained by differential scanning calorimetry and transmission electron microscopy

  12. Ni4Ti3 precipitate structures in Ni-rich NiTi shape memory alloys

    Holec, David; Bojda, Ondřej; Dlouhý, Antonín

    2008-01-01

    Roč. 481, Sp. Iss. (2008), s. 462-465 ISSN 0921-5093. [ESOMAT 2006. Bochum, 10.09.2006-15.09.2006] R&D Projects: GA ČR(CZ) GA106/05/0918 Institutional research plan: CEZ:AV0Z20410507 Keywords : NiTi shape memory alloys * Ni4Ti3 precipitates * Multi-step martensitic transformations Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.806, year: 2008

  13. Electronic structure of Ni-- and Ni2--ethylene cluster complexes

    Basch, H.; Newton, M.D.; Moskowitz, J.W.

    1978-01-01

    The electronic structure of metal cluster--ethylene complexes has been investigated by carrying out ab initio bonding pair-correlated, self-consistent field, and configuration interaction (CI) calculations on the NiC 2 H 4 and Ni 2 C 2 H 4 species. The π-NiC 2 H 4 and π-Ni 2 C 2 H 4 cluster complexes are found to be bound, the former only with CI, while disigma-Ni 2 C 2 H 4 has only a repulsive Ni 2 --C 2 H 4 ground state potential curve. The bonding in the π-type cluster complexes can be described as follows: The metal atom configuration is 3d 9 4s 1 with the 4s hybridized (by the metal 4p) away from the ethylene molecule, thereby allowing the π orbital to form a dative sigma bond with the metal atom. The bonding interaction is promoted by the presence of a second nickel atom behind the first one, leading to a 4s orbital electron deficiency of the bonded nickel atom and thus making this nickel atom a better electron acceptor. Back donation from the occupied metal 3d into the ethylene π* molecular orbital also takes place to some extent, and thus both features of the classical Dewar--Chatt--Duncanson model are observed. The π-Ni 2 C 2 H 4 species is analyzed in terms of the addition of a bare nickel atom to a π-NiC 2 H 4 cluster complex, with concomitant stabilization of the orbitals of the bonded nickel atom. A study of the excited electronic states of π-NiC 2 H 4 shows that low-lying 4s→π* and 3d→π* (M→L) charge transfer transitions are predicted. The former is not observed experimentally, probably due to the diffuse nature of the 4s orbital. The relationship between small cluster--ethylene complex systems and ethylene chemisorption on a nickel metal surface is discussed

  14. Fiscal 1997 survey report on the jointly executed/promoted basic survey project (the jointly executed activity Japan Program). Feasibility survey for CO2 reduction by deregulating heavy traffic at specified crossings in Bangkok, Thailand; 1997 nendo chosa hokokusho (kyodo jisshi suishin kiso chosa jigyo (kyodo jisshi katsudo Japan program)). Taikoku Bangkok no tokutei kosaten ni okeru kotsu jutai kanwa ni yoru CO2 sakugen kanosei chosa

    NONE

    1998-03-01

    The monetary crisis in Thailand with the baht drop in July 1997 as a beginning rapidly worsened the Thai economy. With it, the number of automobiles sold sharply declined, and automobile manufacturers were also heavily damaged as seen in the temporary discontinued production, etc. Under such economic situation, a discussion was made on execution of the project with the Thai Automotive Industry Association (TAIA), a partner at the Thai side. As a result, agreement was made on the positioning of the project, role sharing, and selection of measures against heavy traffic as follows: Japan Automobile Manufacturers Association (JAMA) conducts a feasibility study, proposal of a construction plan and confirmation of effects, and bears the costs. TAIA bears the execution and cost of construction (Due to the worsened Thai economy, JAMA paid almost all the construction expenses). In the light of the economic situation in Thailand, `improvement of the signal control system` was selected as an execution candidate, which has the highest cost effect among the measures against heavy traffic. In the future, the application, registration and execution are done for joint activities for the project. 49 figs., 59 tabs.

  15. Fiscal 1999 basic survey report for promotion of joint implementation. Basic survey for promotion of joint implementation (Feasibility study about CO2 emission reduction by introducing energy-efficient facilities into three leading paper and pulp plants in the Philippines); 1999 nendo Philippines kami pulp shuyo 3 kojo eno sho energy setsubi donyu ni yoru CO{sub 2} haishutsu sakugen ni kansuru FS chosa hokokusho

    NONE

    2000-03-01

    A feasibility study is conducted on the assumption of introducing Japan's energy-saving technology into three leading paper and pulp plants in the Philippines for a reduction in greenhouse gas emissions. In the future, the effort will be associated with the clean development mechanism (CDM). The three target plants are TIPCO (Trust International Paper Corporation), UPPC (United Pulp and Paper Co., Inc.), and CCP (Container Corporation of the Philippines). The energy-saving facilities to be installed involve energy-efficient screens, variable-speed motors, conversion of winder unwinding sections into rheostatic brakes, hermetic design for dryer hoods, exhaust heat recovery facilities, etc. A study of the plant and equipment investment standards of the respective corporations indicates that energy-saving alone will not realize a full payback. It will be necessary, therefore, to have the project implemented as a CDM activity for a transfer from the Philippines of some CO2 emission reduced amount credit for Japan to bear a part of the necessary funds. Since the CDM framework and the value of reduced amount credit are not clear at the current stage, negotiations will have to be furthered about Japan's share of funds etc. as soon as the situation becomes clear. Since the Philippine Government is not well-disposed towards CDM, there is no possibility that this project will be approved as a CDM effort. (NEDO)

  16. Radioactive 63Ni in biological research

    Kasprzak, K.S.; Sunderman, F.W. Jr.

    1979-01-01

    Applications of 63 Ni in biological research are reviewed, with emphasis upon recent investigations of nickel metabolism and toxicology in experimental animals. The radiochemistry of 63 Ni is summarized, including consideration of the preparation of certain 63 Ni compounds (e.g. 63 Ni(CO) 4 and 63 Ni 3 S 2 ) that are of current interest in toxicology, teratology and cancer research. Practical guidance is given regarding the detection and determination of 63 Ni in biological materials by autoradiography and liquid scintillation spectrometry. (author)

  17. Superstructure of NiAs

    Nozue, Tatsuhiro; Kobayashi, Hisao; Kamimura, Takashi; Yamaguchi, Yasuo

    2001-01-01

    The structural transition in NiAs was studied by neutron diffraction on the single crystalline sample. The crystal structure of NiAs has been reported to be bottom-centered orthorhombic with Cmc2 1 symmetry (niccolite-type). The measurement of temperature dependence of the powder X-ray diffraction revealed that NiAs undergoes a structural transition to the NiAs-type at T t =335 K. In present neutron diffraction experiment at room temperature, we observed the reflections indexed on the basis of the orthorhombic unit cell. The intensities of these reflections are qualitatively explained in terms of the niccolite-type structure with taking account of three domain structures, except for the weak reflections indexed as (001), (003) and (012). Then, the intensities of (001), (002) and (004) reflections were measured in temperature range of 20 to 420 K. The temperature dependences of (002) and (004) reflections qualitatively agree with those of the calculated intensities using the atomic positions of niccolite-type structure. However, the temperature dependence of (001) reflection shows the anomaly around T t , which suggests the symmetry of crystal structure of NiAs is not the Cmc2 1 symmetry. (author)

  18. Thermal stability and electrical characteristics of NiSi films with electroplated Ni(W) alloy

    Xin Yuhang; Hu Anmin; Li Ming; Mao Dali

    2011-01-01

    In this study, an electroplating method to deposited Ni, crystalline NiW(c-NiW), amorphous NiW (a-NiW) films on P-type Si(1 0 0) were used to form Ni-silicide (NiSi) films. After annealed at various temperatures, sheet resistance of Ni/Cu, c-NiW/Cu and a-NiW/Cu was measured to observe the performance of those diffusion barrier layers. With W added in the barrier layer, the barrier performance was improved. The results of XRD and resistance measurement of the stacked Si/Ni(W)/Cu films reveal that Cu atom could diffuse through Ni barrier layer at 450 deg. C, could diffuse through c-NiW at 550 deg. C, but could hardly diffuse through a-NiW barrier layer. c-NiW layer has a better barrier performance than Ni layer, meanwhile the resistance is lower than a-NiW layer.

  19. Giant magnetoimpedance effect in sputtered single layered NiFe film and meander NiFe/Cu/NiFe film

    Chen, L.; Zhou, Y.; Lei, C.; Zhou, Z.M.; Ding, W.

    2010-01-01

    Giant magnetoimpedance (GMI) effect on NiFe thin film is very promising due to its application in developing the magnetic field sensors with highly sensitivity and low cost. In this paper, the single layered NiFe thin film and NiFe/Cu/NiFe thin film with a meander structure are prepared by the MEMS technology. The influences of sputtering parameters, film structure and conductor layer width on GMI effect in NiFe single layer and meander NiFe/Cu/NiFe film are investigated. Maximum of the GMI ratio in single layer and sandwich film is 5% and 64%, respectively. The results obtained are useful for developing the high-performance magnetic sensors based on NiFe thin film.

  20. High Ni in Archean tholeiites

    Arndt, Nicholas T.

    1991-03-01

    Archean tholeiites generally have higher Ni, Co. Cr and Fe than most younger tholeiites with similar MgO contents. These characteristics cannot be attributed to high T or P batch melting in the Archean mantle, because, although such melts are enriched in siderophile elements, they have higher MgO than normal tholeiites. As primary melts fractionate to lower MgO, they lose Ni, Co and Cr. Nor can the differences between Archean and younger tholeiites be attributed to secular variation in mantle compositions because Archean komatiites have Ni, Co, Cr contents similar to modern (Gorgona) komatiites. It is suggested that the high siderophile element content of Archean tholeiites results from mixing of either komatiitic with basaltic magmas, as might occur in an ascending, melting mantle plume or column, or of komatiite and more evolved rocks, as may take place when komatiite encounters and assimilates crustal rocks.

  1. Relation between shape of Ni-particles and Ni migration in Ni-YSZ electrodes – a hypothesis

    Mogensen, Mogens Bjerg; Hauch, Anne; Sun, Xiufu

    2016-01-01

    This is an attempt to explain a phenomenon of total depletion of Ni next to the electrolyte in Ni-YSZ cermet electrodes in solid oxide electrolysis cells during electrolysis at high current density/overpotential. Intuitively, we would think that Ni would always migrate down the steam partial...

  2. Ni-NiO core-shell inverse opal electrodes for supercapacitors.

    Kim, Jae-Hun; Kang, Soon Hyung; Zhu, Kai; Kim, Jin Young; Neale, Nathan R; Frank, Arthur J

    2011-05-14

    A general template-assisted electrochemical approach was used to synthesize three-dimensional ordered Ni core-NiO shell inverse opals (IOs) as electrodes for supercapacitors. The Ni-NiO IO electrodes displayed pseudo-capacitor behavior, good rate capability and cycling performance. © The Royal Society of Chemistry 2011

  3. CONFIGURATION-INTERACTION IN NI METAL AND NI-ALLOYS AND HIGH-ENERGY SPECTROSCOPY

    TANAKA, A; JO, T; SAWATZKY, GA

    We discuss the electronic state of Ni atoms in Ni metal and of Ni impurity in Cu and Au metals from the viewpoint of 3d configuration interaction (CI) using the Anderson impurity model including atomic multiplets. On the basis of the discussion, we give an interpretation for the Ni 2p-core X-ray

  4. Iodine capture by Hofmann-type clathrate Ni(II)(pz)[Ni(II)(CN)_4

    Massasso, Giovanni; Long, Jerome; Haines, Julien; Devautour-Vinot, Sabine; Maurin, Guillaume; Larionova, Joulia; Guerin, Christian; Guari, Yannick; Grandjean, Agnes; Onida, Barbara; Donnadieu, Bruno

    2014-01-01

    The thermally stable Hofmann-type clathrate framework Ni(II)(pz)[Ni(II)(CN)_4] (pz = pyrazine) was investigated for the efficient and reversible sorption of iodine (I_2) in the gaseous phase and in solution with a maximum adsorption capacity of 1 mol of I_2 per 1 mol of Ni(II)pz)[Ni(II)(CN)_4] in solution. (authors)

  5. Density functional theory study of the interfacial properties of Ni/Ni3Si eutectic alloy

    Zhao, Yuhong; Wen, Zhiqin; Hou, Hua; Guo, Wei; Han, Peide

    2014-01-01

    In order to clarify the heterogeneous nucleation potential of α-Ni grains on Ni 3 Si particles in Ni-Ni 3 Si eutectic alloy, the work of adhesion (W ad ), fracture toughness (G), interfacial energy (γ i ), and electronic structure of the index (0 0 1), (1 1 0) and (1 1 1) Ni/Ni 3 Si interfaces with two different cohesive manners are investigated using first-principles method based on density functional theory. Results indicate that the center site stacking sequence (OM) is preferable to continue the natural stacking sequence of bulk Ni and Ni 3 Si. Since OM stacking interfaces have larger W ad , G and γ i than that of the top site stacking (OT) interfaces. The Ni/Ni 3 Si (1 1 0) interface with OM stacking has the best mechanical properties. Therefore, the formation of this interface can improve the stability, ductility and fracture toughness of Ni-Ni 3 Si eutectic alloy. The calculated interfacial energy of Ni/Ni 3 Si (0 0 1), (1 1 0) and (1 1 1) interfaces with OM stacking proves the excellent nucleation potency of Ni 3 Si particles for α-Ni phase from thermodynamic considerations. Besides, the electronic structure and chemical bonding of (1 1 0) interface with OM stacking are also discussed.

  6. Density of Liquid Ni-Cr Alloy

    2003-01-01

    The density of liquid Ni-Cr alloy was measured by a modified sessile drop method. The density of liquid Ni-Cr alloywas found to decrease with increasing temperature and Cr concentration in the alloy. The molar volume of liquidNi-Cr alloy increases with increasing the Cr concentration in the alloy. The molar volume of Ni-Cr alloy determinedin the present work shows a positive deviation from the linear molar volume.

  7. Achievement report for fiscal 1981 on Sunshine Program-assisted project. Survey of Australian industrial capability and construction capability relative to Australian brown coal liquefaction plant construction project (Annexed materials: Lists of projects undertaken by important corporations in Australia); 1981 nendo Goshu kattan ekika plant no kensetsu ni kakawaru kogyoryoku, kensetsu kojiryoku ni kansuru chosa seika hokokusho (fuzoku shiryo). Australia ni okeru shuyo kigyo no jisshi project list

    NONE

    1982-03-01

    In relation with the construction of an Australian brown coal liquefaction plant, a survey is conducted into projects being undertaken by important businesses in Australia, and lists are compiled about them. Mentioned in the lists are the head office, directors, number of employees, line of business, contents of projects, the names of clients, etc., for each of 12 corporations including consulting firms and engineering contractors such as the Bechtel Pacific Corporation Limited. Named in the lists also are 17 manufacturers of pipes and tubes, pressure vessels, heat exchangers, tower tanks, steel structures and other fabricated metallic items, boilers, water treatment systems, pumps, electrical equipment, instrumentation, valves, iron and steel, etc. Furthermore, in relation with civil engineering and construction, 7 corporations including the Citra Constructions Limited are mentioned. (NEDO)

  8. Report on the survey in fiscal 1998. A survey on long-term energy technology strategy (a survey related to arrangement of information groups and aiding means for establishing policies related to research and development of energy and environment technologies); 1998 nendo choki energy gijutsu senryaku chosa. Energy kankyo gijutsu kenkyu kaihatsu ni kakawaru seisaku kettei no tame no johogun no seibi narabi ni shien shuho ni kansuru chosa

    NONE

    1999-03-01

    This paper discusses aiding means for establishing the research and development strategy for maximizing greenhouse effect gas reduction for a short period (year 2010) and an ultra long period (year 2030 and on). First, the situation surrounding the existing energy and environment technologies and technological assignments (themes) were put into order. Rough calculations were made on the selected themes as to their effect of greenhouse effect gas reduction. Based on the result of these reduction amount calculations, provisionary introduction scenarios including analyses by groups and users were prepared according to each theme. On the other hand, data groups related to the energy and environment technologies were investigated and put into order. The data groups include literatures and achievements of the past researches, and are expected of utilization for estimating the introduction potential to calculate effects of future research and development. In addition, discussions were given on methods to analyze cost-effect relationship in the energy and environment technologies. Importance was placed on the case surveys inside and outside the country, and simple models suitable for themes in the New Sunshine Project were built for an attempt of case studies. (NEDO)

  9. Laser alloyed Al-Ni-Fe coatings

    Pityana, SL

    2008-10-01

    Full Text Available The aim of this work was to produce crack-free thin surface layers consisting of binary (Al-Ni, Al-Fe) and ternary (Al-Ni-Fe) intermetallic phases by means of a high power laser beam. The laser surface alloying was carried out by melting Fe and Ni...

  10. Nanostructure analysis of friction welded Pd-Ni-P/Pd-Cu-Ni-P metallic glass interface

    Ohkubo, T.; Shoji, S.; Kawamura, Y.; Hono, K.

    2005-01-01

    Friction welded Pd 40 Ni 40 P 20 /Pd 40 Cu 30 Ni 10 P 20 metallic glass interface has been characterized by energy filtering transmission electron microscopy. The interface is fully amorphous with a gradual compositional change of Cu and Ni in the range of 30 nm. By annealing above T g , the interdiffusion of Cu and Ni progressed in the supercooled liquid region, and the crystallization occurred from the Pd 40 Ni 40 P 20 glass

  11. Study of dipole interaction in micron-width NiFe/Cu/NiFe/NiO wire using exchange anisotropy

    Kimura, Takashi; Itagaki, Yoshio; Wakaya, Fujio; Gamo, Kenji

    2001-01-01

    The dipole interaction between a NiFe layer pinned by a NiO and a free NiFe layer in a micron-wide NiFe/Cu/NiFe/NiO wire was studied by changing the direction of the exchange bias from the NiO layer. The effect of the dipole interaction when the exchange bias was perpendicular to the wire axis was larger than that when the exchange bias was parallel to the wire axis, and was consistently explained by the stray field caused by the magnetic charges of the pinned layer. It was demonstrated that this method, using exchange anisotropy, is useful for investigating the dipole interaction between ferromagnetic materials separated by a nonmagnetic material in small-scale magnetic multilayers. [copyright] 2001 American Institute of Physics

  12. Effects of Ni particle morphology on cell performance of Na/NiCl2 battery

    Kim, Mangi; Ahn, Cheol-Woo; Hahn, Byung-Dong; Jung, Keeyoung; Park, Yoon-Cheol; Cho, Nam-ung; Lee, Heesoo; Choi, Joon-Hwan

    2017-11-01

    Electrochemical reaction of Ni particle, one of active cathode materials in the Na/NiCl2 battery, occurs on the particle surface. The NiCl2 layer formed on the Ni particle surface during charging can disconnect the electron conduction path through Ni particles because the NiCl2 layer has very low conductivity. The morphology and size of Ni particles, therefore, need to be controlled to obtain high charge capacity and excellent cyclic retention. Effects of the Ni particle size on the cell performance were investigated using spherical Ni particles with diameters of 0.5 μm, 6 μm, and 50 μm. The charge capacities of the cells with spherical Ni particles increased when the Ni particle size becomes smaller because of their higher surface area but their charge capacities were significantly decreased with increasing cyclic tests owing to the disconnection of electron conduction path. The inferior cyclic retention of charge capacity was improved using reticular Ni particles which maintained the reliable connection for the electron conduction in the Na/NiCl2 battery. The charge capacity of the cell with the reticular Ni particles was higher than the cell with the small-sized spherical Ni particles approximately by 26% at 30th cycle.

  13. One dimensional motion of interstitial clusters and void growth in Ni and Ni alloys

    Yoshiie, T.; Ishizaki, T.; Xu, Q.; Satoh, Y.; Kiritani, M.

    2002-12-01

    One dimensional (1-D) motion of interstitial clusters is important for the microstructural evolution in metals. In this paper, the effect of 2 at.% alloying with elements Si (volume size factor to Ni: -5.81%), Cu (7.18%), Ge (14.76%) and Sn (74.08%) in Ni on 1-D motion of interstitial clusters and void growth was studied. In neutron irradiated pure Ni, Ni-Cu and Ni-Ge, well developed dislocation networks and voids in the matrix, and no defects near grain boundaries were observed at 573 K to a dose of 0.4 dpa by transmission electron microscopy. No voids were formed and only interstitial type dislocation loops were observed near grain boundaries in Ni-Si and Ni-Sn. The reaction kinetics analysis which included the point defect flow into planar sink revealed the existence of 1-D motion of interstitial clusters in Ni, Ni-Cu and Ni-Ge, and lack of such motion in Ni-Si and Ni-Sn. In Ni-Sn and Ni-Si, the alloying elements will trap interstitial clusters and thereby reduce the cluster mobility, which lead to the reduction in void growth.

  14. First-principles calculations for the elastic properties of Ni-base model superalloys: Ni/Ni3Al multilayers

    Yun-Jiang, Wang; Chong-Yu, Wang

    2009-01-01

    A model system consisting of Ni[001](100)/Ni 3 Al[001](100) multi-layers are studied using the density functional theory in order to explore the elastic properties of single crystal Ni-based superalloys. Simulation results are consistent with the experimental observation that rafted Ni-base superalloys virtually possess a cubic symmetry. The convergence of the elastic properties with respect to the thickness of the multilayers are tested by a series of multilayers from 2γ'+2γ to 10γ'+10γ atomic layers. The elastic properties are found to vary little with the increase of the multilayer's thickness. A Ni/Ni 3 Al multilayer with 10γ'+10γ atomic layers (3.54 nm) can be used to simulate the mechanical properties of Ni-base model superalloys. Our calculated elastic constants, bulk modulus, orientation-dependent shear modulus and Young's modulus, as well as the Zener anisotropy factor are all compatible with the measured results of Ni-base model superalloys R1 and the advanced commercial superalloys TMS-26, CMSX-4 at a low temperature. The mechanical properties as a function of the γ' phase volume fraction are calculated by varying the proportion of the γ and γ' phase in the multilayers. Besides, the mechanical properties of two-phase Ni/Ni 3 Al multilayer can be well predicted by the Voigt–Reuss–Hill rule of mixtures. (classical areas of phenomenology)

  15. Flowsheet for 63Ni production

    Williams, D.F.; Knauer, J.B.; O'Kelley, G.D.; Wiggins, J.T.; Porter, C.E.

    1992-01-01

    The production of large quantities of high specific activity 63 Ni (>10Ci/g) requires both a highly enriched 62 Ni target and a long irradiation period at high neutron flux. Trace impurities in the nickel and associated target materials are also activated and account for a significant fraction of the discharged activity and essentially all of the gamma activity. While most of these undesirable activation products (mainly transition metals) can be easily removed as chloride complexes during anion exchange, chromium, present as 51 Cr, and manganese, present as 54 Mn, are exceptions and require solvent extraction of the in-cell product to achieve the desired purity. In addition to summarizing the current development and production experience, optimized flowsheets are discussed

  16. Microstructural investigations of Ni and Ni2Al3 coatings exposed in biomass power plants

    Wu, D. L.; Dahl, K. V.; Christiansen, T. L.

    2018-01-01

    The present work investigates the corrosion resistance of Ni and Ni2Al3 coated austenitic stainless steel (TP347H) tubes, which were exposed in a biomass-fired boiler with an outlet steam temperature of 540 °C for 6757 h. The Ni2Al3 coating was produced by electroplating Ni followed by low...... temperature pack cementation. After exposure, microstructural investigations were performed by light optical and electron microscopy (SEM-EDS). Electroplated Ni coatings were not protective in straw firing power plants and exhibited similar corrosion morphology as uncoated tubes. For Ni2Al3 coatings...

  17. Influence of ni thickness on oscillation coupling in Cu/Ni multilayers

    Gagorowska, B; Dus-Sitek, M [Institute of Physics, Czestochowa University of Technology, Al. Armii Krajowej 19, 42-200 Czestochowa (Poland)

    2007-08-15

    The results of investigation of magnetic properties of [Cu/Ni]x100 were presented. Samples were deposited by face-to-face sputtering method onto the silicon substrate, the thickness of Cu layer was constant (d{sub Cu} = 2 nm) and the thickness of Ni layer - variable (1 nm {<=} d{sub Ni} {<=} 6 nm). In Cu/Ni multilayers, for the thickness of Ni layer bigger than 2 nm antiferromagnetic coupling (A-F) were observed, for the thickness of Ni smaller than 2 nm A-F coupling is absent.

  18. Influence of ni thickness on oscillation coupling in Cu/Ni multilayers

    Gagorowska, B; Dus-Sitek, M

    2007-01-01

    The results of investigation of magnetic properties of [Cu/Ni]x100 were presented. Samples were deposited by face-to-face sputtering method onto the silicon substrate, the thickness of Cu layer was constant (d Cu = 2 nm) and the thickness of Ni layer - variable (1 nm ≤ d Ni ≤ 6 nm). In Cu/Ni multilayers, for the thickness of Ni layer bigger than 2 nm antiferromagnetic coupling (A-F) were observed, for the thickness of Ni smaller than 2 nm A-F coupling is absent

  19. Exclusive study of Ni+Ni and Ni+Au central collisions: phase coexistence and spinodal decomposition; Etude exclusive des collisions centrales Ni+Ni et Ni+Au: coexistence de phase et decomposition spinodale

    Guiot, B

    2002-12-01

    The INDRA multidetector allowed us to study the Ni+Ni collisions at 32A MeV and the Ni+Au collisions at 52,4 MeV. Central collisions leading to 'quasi-fused' systems were isolated using multidimensional analysis techniques: the Discriminant Analysis and the Principal Component Analysis. Comparison with a statistical model shows that the selected events are compatible with thermodynamical equilibrium. The average thermal excitation energy is 5A MeV for both systems. Calculations of heat capacities show that the deexcitation of the hot sources are akin to a liquid-gas phase transition of nuclear matter. Indeed heat capacities exhibit a negative branch as expected for a phase transition of a finite system. The dynamics of this phase transition has been investigated by applying the charge correlation method. An enhanced production of events with equal-sized fragments has been evidenced for Ni+Au at 52A MeV. No signal was found for Ni+Ni at 32A MeV. Finally this method was improved by taking into account the total charge conservation. The signal is seen more clearly for Ni+Au at 52A MeV, but is ambiguous for Ni+Ni at 32A MeV. The path followed in the state diagram, or the involved time scales, seem to be different for these systems. (authors)

  20. niños preescolares

    Claudia Rosario Portilla Ramírez

    2007-01-01

    Full Text Available Este estudio explora la relación entre la escritura y la comprensión de la referencia a través de una tarea de sinonimia en niños entre 5 y 6 años de edad, de origen latinoamericano, escolarizados en Barcelona (España. Las variables relacionadas con la tarea de sinonimia fueron (a la comprensión de la entidad lingüística nombre y (b el nivel de conceptualización de la escritura de los niños y la presencia de etiquetas escritas durante la tarea. Para la tarea de sinonimia se utilizaron pares de sinónimos dialectales del español (de Latinoamérica y de la Península Ibérica. Los resultados mostraron una diferenciación en el razonamiento de los niños, la cual dependía de la comparación entre lenguaje oral y lenguaje escrito en el desarrollo de la tarea, evidenciando una mayor aceptación de la sinonimia en la modalidad de lenguaje oral que en la modalidad de lenguaje escrito.

  1. Reinvestigation of 56Ni decay

    Sur, B.; Norman, E.B.; Lesko, K.T.; Browne, E.; Larimer, R.

    1990-01-01

    In a series of experiments, we have reinvestigated the decay of the doubly magic nucleus 56 Ni, which is believed to be copiously produced in supernovae. We have confirmed its previously known decay scheme and half-life, and have searched for several rare decay modes. We establish an upper limit of 5.8x10 -7 for the branching ratio of the second forbidden unique β + decay to the 158-keV level in 56 Co, leading to a lower limit of 2.9x10 4 yr for the half-life of fully ionized 56 Ni nuclei in cosmic rays. We also establish an upper limit of 5.0x10 -3 for the branching ratio of the isospin forbidden Fermi electron capture transition to the 1451-keV level in 56 Co, which in turn leads to an upper limit of 124 keV for the isospin mixing Coulomb matrix element of the 56 Ni ground state

  2. On the nature of Ni···Ni interaction in a model dimeric Ni complex.

    Kamiński, Radosław; Herbaczyńska, Beata; Srebro, Monika; Pietrzykowski, Antoni; Michalak, Artur; Jerzykiewicz, Lucjan B; Woźniak, Krzysztof

    2011-06-07

    A new dinuclear complex (NiC(5)H(4)SiMe(2)CHCH(2))(2) (2) was prepared by reacting nickelocene derivative [(C(5)H(4)SiMe(2)CH=CH(2))(2)Ni] (1) with methyllithium (MeLi). Good quality crystals were subjected to a high-resolution X-ray measurement. Subsequent multipole refinement yielded accurate description of electron density distribution. Detailed inspection of experimental electron density in Ni···Ni contact revealed that the nickel atoms are bonded and significant deformation of the metal valence shell is related to different populations of the d-orbitals. The existence of the Ni···Ni bond path explains the lack of unpaired electrons in the complex due to a possible exchange channel.

  3. Synthesis of Ni core NiO shell nanostructure and magnetic investigation for shell thickness determination

    Arabi, H.; Bruck, E.; Tichelaar, F.D.

    2007-01-01

    Full text: Nickel oxide has received a considerable amount of attention in recent years for its catalytic, electronic and magnetic properties. Ni nanoparticles with an average size of 8 nm were prepared by dc - arc discharge in argon atmosphere. A current of 130 A and 300 milli bar pressure of argon have been applied. The produced Ni nanoparticles were annealed for oxidizing in air at 350 for six hours to produce antiferromagnetic NiO particles. The structure of Ni and NiO nanoparticles and size estimation of them studied by means of X-ray diffraction. The size and morphology of the particles were also characterized by high resolution transmission microscopy (TEM). The Ni core NiO shell structure, resulting from the oxidation process, were studied by magnetic properties measurements. A quantum design squid magnetometer, model MPMS5S was used for measuring saturation magnetization of both nanoparticles of Ni with and without NiO layer. By knowing the density of Ni and NiO, we were able to deduce the thickness of the Ni core and NiO outer layer. They are around 3 and 5 nanometers respectively. (authors)

  4. Report on a survey in fiscal 1999. Survey on possibilities of environmental cooperation in relation with proliferation of environment preservation technologies and institutions in developing countries; 1999 nendo kankyo taisaku gijutsu seido nado no tojokoku fukyu ni kakawaru kankyo kyoryoku kanoseichosa hokokusho

    NONE

    2000-03-01

    Cooperation in energy and environment aspects with developing countries is considered very important in view of the following points: (1) the cooperation will help developing countries to grow economically while minimizing the damages from industrial pollution and environmental problems; (2) conservation of energies and promotion of use of new energies will contribute to solving pollution problems associated with energy production, and will result in assurance of stability of primary energy availability for Japan; (3) preservation of environments in countries exporting foods to Japan will link to maintaining health of Japanese people and increasing their welfare; and (4) Japanese industrial pollution preventing technologies and knowledge whose levels are high worldwide may be utilized to create new business chances for Japanese business entities. The present survey has discussed the importance by territories, the importance by cooperation modes, and sharing of roles by governmental and private organizations, and performed case studies. Considerations were given from the discussion results on how the environmental projects should be planned in the environment cooperation, the contents to be of win/win from the viewpoint of motivation, the project image for subjected territories being composite and comprehensive, and the cases from the viewpoint of mutual coexistence referred to as prevention of global warming and assurance of food and energy resources. (NEDO)

  5. FY2000 report on the survey results of medical/engineering cooperative research project, additional research on {sup 13}C-MRS for non-invasion type brain metabolism measurement; 2000 nendo igaku kogaku renkeigata kenkyu jigyo mushinshuteki no taisha keisokuyo {sup 13}C-MRS sochi ni kakawaru tsuka kenkyu

    NONE

    2001-07-01

    The basic data are collected by the experiments, in order to optimize the {sup 13}C-MRS analyzer for non-invasion type brain metabolism measurement. The tests are conducted for normal aged volunteers and volunteer patients of, e.g., dementia as the subjects. Each subject is orally dosed with glucose marked with {sup 13}C at the 1-site, and the metabolized {sup 13}C glucose signals from two points in the back of the head are observed as the MR spectra for a total of 3 hours. The time-series data of the {sup 13}C glutamic acid and glutamine signals are analyzed, to determine metabolism speed of the TCA circuits, among others, which provides important information for understanding the brain cell functions. It is 0.33{mu}mol/g/minute as the average of the 5 subjects of normal aged volunteers, which is on a level with that of the young volunteers. On the other hand, it is 0.26{mu}mol/g/minute as the average of the 4 subjects of volunteer patients of dementia, although there is no difference of statistical significance between these values. These results, therefore, suggest that the patients of dementia tend to have deteriorated brain metabolism than the healthy persons. (NEDO)

  6. FY 2000 report on the survey of the project to promote and support the formation of the environmentally friendly energy community. Feasibility study on the waste utilization high efficiency power generation project; Kankyo chowagata energy community keisei sokushin jigyo chosa hokokusho. Haikibutsu riyo kokoritsu hatsuden jigyo ni kakawaru FS chosa

    NONE

    2001-03-01

    An investigational study was conducted on energy recovery (power generation) in disposal of industrial waste. The capacity of power generation facilities in incineration processing of industrial waste reached approximately 200,000kW (50 facilities) in the total nationwide. The incineration-processed waste is mainly chips of wood, waste tire and bagasse. Almost all the electric power is for non-utility use, and there are no examples of selling it outside. In the metropolitan area, there is only one example of the industrial waste incineration power generation in Tochigi prefecture. This is because there are extremely very few enterprises which are sources producing the waste as target. However, if the industrial waste market is targeted, there is a future. The industrial waste has a lot of disadvantages as power generation use fuel because of its diversification, but the use of it as fuel is technically easier than the use of the general waste as RDF. Accordingly, it can be used for power generation with no need of special technology or facilities. When picking up facilities with a potentiality of high efficiency power generation from the existing incinerators in operation of persons in charge of industrial waste processing, approximately 125,000 kW can be obtained only from remodeling of the existing facilities. (NEDO)

  7. Initiative research in fiscal 2000 in relation with global environment industrial technologies. Achievement report on investigations and researches of emission-free manufacturing (EFM); 2000 nendo chikyu kankyo sangyo gijutsu ni kakawaru sendo kenkyu seika hokokusho. Emission free manufacturing (EFM) no chosa kenkyu

    NONE

    2001-03-01

    Three working groups were established, each having assignments of developing a technology to evaluate environmental load imposed by processing processes, developing a new manufacturing process intended of reducing environmental load, and remarkably improving the existing manufacturing technologies. Investigations and researches were performed on the current technological trends and technological problems in relation with emission-free manufacturing. In the environmental load evaluation technology, it was indicated that the amount of charged energy per one million yen of products made by metal machine tools is 10040 Gcal/M yen, and that, with regard to CO2 emission amount and resource depleting load at the small machining center, the amounts attributable to the raw materials are 80% and 90% respectively, wherein either item can be reduced by recycling iron. For the comprehensive low-emission processing technology, investigations were carried out on a casting process not using sandmolds, substitute lubricants, dry forging, semi-solid processing, and deep drawing process using ultra-high pressure water. For the functional low-emission production technology, investigations were performed on performance improvement in processing machines, energy saving, and reduction in emission. (NEDO)

  8. Fiscal 2000 operation report. Fiscal 2000 model project for promoting advanced utilization of coal (Survey on data control system for advanced utilization of coal in Japan); 2000 nendo sekitan kodo riyo shuishin moderu jigyo gyomu hokokusho. Nihon no sekitan kodo riyo ni kakawaru data kanri system chosa

    NONE

    2001-03-01

    With the purpose of contributing to the drafting of, for example, measures for securing coal resources for Japan and strategies for developing coal utilization technologies from the standpoint of the world climate of the coal supply/demand in the future, database was built concerning coal information such as coal-related supply/demand trend, technological development and utilization status in Japan and foreign countries, with the results of fiscal 2000 reported. In the preparation of related applications, a jump function in the case of pages unregistered with related subjects was added to the coal information retrieval system completed last year, as were a subdividing function of retrieval conditions and a link function to pages of a technical term dictionary. In the arrangement of the database classified by the fields, programs were prepared on 14 tables primarily in relation to supply and demand, with the collection, processing and registration of the data performed. In addition, in order to deal with the clarification of the patent licensing of GIF related technologies, there was developed a graph display program using a general-purpose language, Java. (NEDO)

  9. Achievement report on the incoming projects related to ITS. Research and survey involving 'Research and development of universal design vehicle based on ITS technology'; ITS renkei kokei project an. 'ITS gijutsu wo tenkaishita universal design vehicle no kenkyu kaihatsu' ni kakawaru kenkyu chosa

    NONE

    2001-02-01

    For the promotion of 'Report on Strategy of Automobile Industrial Technologies - Strategy 2 - Promotion of Development of Vehicle Environment Recognition Technology and Driver's State Detection Technology,' investigations and studies including overseas surveys are conducted over six selected subjects which are (1) ITS (Intelligent Transportation System) and VCSS (Voice Communications Switching System), (2) old people, handicapped people, and universal design, (3) intelligent interface, (4) techniques of assessing bionic data and load of driving, (5) driving simulator and virtual reality, and (6) data communication, mobile data communication in particular. It is then found that, on the assumption that there exists a mobile communications environment such as ITS or Internet aboard the automobile, it is important to develop a universal design automobile which adapts itself to the driver thereby respecting driver's viewpoint and that such is to be accomplished by grasping driver's characteristics especially under extraordinary conditions in the way of Kansei engineering and by redesigning the driver's operating system making use of the active interface technology. A conclusion is reached that development should continue in compliance with the separately specified 6 items which are indispensable for the research and development of an ITS based man-adaptive automobile. (NEDO)

  10. FY 2000 report on the survey of policies on cooperation in new energy/energy conservation for developing countries by developed countries/international organizations. Survey of collection/analysis of information on effective energy utilization, etc.; 2000 nendo senshinkoku kokusai kikan no tai tojokoku shin energy sho energy kyoryoku seisaku ni kakawaru chosa hokokusho. Energy yuko riyo nado joho shushu bunseki chosa

    NONE

    2001-03-01

    Looking for measures for cooperation in effective energy conservation for developing countries, the paper arranged characteristics of the policies, systems and organizations in relation to energy conservation/new energy policies in developed countries and international organizations excluding Japan. Concretely, survey was made of the following 5 fields: 1) new energy cooperation (project) for developing countries by developed countries and international organizations excluding Japan; 2) outline of activities by aid giving organizations; 3) energy conservation policies of developing countries and cooperation of developed countries and international organizations; 4) policies of new energy introduction in developed countries; 5) study to reinforce cooperation for helping developing countries by Japan and developed countries/international organizations excluding Japan. In 1), survey is composed of case study of the main project and study of the outline of activities by aid giving organizations. The activities by the following aid giving organizations were surveyed: the World Bank group, International Finance Corporation (IFC), United Nations Development Program (UNDP), the European Committee and the Asian Development Bank (ADB). (NEDO)

  11. Achievement report for fiscal 1998. Energy consumption efficiency improvement model business for developing nations (Demonstration research project on new cooling system in cement clinker production); Hatten tojokoku energy shohi koritsuka model jigyo seika hokokusho. Cement clinker reikyaku sochi ni kakawaru jissho kenkyu

    NONE

    1999-03-01

    The project aims at energy saving and CO2 emission reduction for a clinker cooling system (CCS), and a demonstration test was conducted at a demonstration cement plant in Indonesia. The plant started operation using the new CCS aiming for the enhancement of cooling and heat recovery efficiency. The actually achieved heat recovery efficiency attributable to the adoption of the new CCS was 60.8% against the target of 68%, this meaning an improvement of 8% over the value recorded prior to the new CCS adoption. As for increase in recovered heat due to heat recovery efficiency improvement of the CCS itself, it was 31kcal/kg-clinker. The heat reduction rate throughout the system thanks to the new CCS was 40kcal/kg-clinker. The kiln secondary air temperature increased for improved burner combustion performance for a rise of the clinker burning degree to 12kcal/kg in terms of calorie, and thus a reduction of 52kcal/kg-clinker in total was achieved. No mechanical trouble was reported with the new CCS. Investigations were conducted into cement supply/demand and technological trends in Indonesia, Vietnam, and China. Learnings from the investigation of German cement making technologies were fully utilized in the designing of the new system. (NEDO)

  12. Fiscal 1999 technical research report. Development project on prompt-effect international standards for developing new industry (Comprehensive survey and research concerning promotion of international standardization); 1999 nendo shinki sangyo ikusei sokkogata kokusai hyojun kaihatsu jigyo seika hokokusho. Kokusai hyojunka suishin ni kakawaru sogo chosa kenkyu

    NONE

    2000-03-01

    For encouraging the promotion of international standardization involving the six subjects of advanced technology taken up under the above-named project, wide-range investigations are conducted into measures for international standardization, the activities of international standardizing agencies and organizations, and the approaches of European and American business corporations to this issue. Technical literature and material are studied in Japan, and interviews are held overseas with responsible persons at organizations and corporations engaged in this task. At Standards Development Organization (SDO) of America, verification tests are under way for early development into international standards of technical standards it has so far developed independently. For the strategical utilization of intellectual property incorporated into its technical standards, SDO accepts that the best policy is to win approvals from patent proprietors at the early stage of standardization process by presenting them with conditions about patent implementation. In Europe and America, for the enhancement of their competitive power in the international theater, governments and civil sectors cooperate with each other for the establishment of international standards and, in business corporations, the management takes the initiative in coping with the issue with an understanding that there are business opportunities in international standardization. (NEDO)

  13. Reports on 1977 result of research. Investigation for selecting site location of pilot plant for 7,000Nm{sup 3}/day class high calorie gasification; 1977 nendo sunshine keikaku ni kakawaru plant kenkyu kaihatsu seika hokoku. 7,000Nm{sup 3}/nichi kyu kokarori gas ka pilot plant yochi no ricchi sentei chosa

    NONE

    1978-03-20

    A report was made on the result of investigation for selecting a suitable site for a coal gasification pilot plant. The high calorie gasification plant under the Sunshine Project is scheduled to have a parallel operation of two methods. It could be decided on one only method depending on the future studies. One is the 'water gasification method' using coal only as the raw material, with hydrogen gas added to contrive methanization. The other is the 'hybrid gasification method' using mixed slurry of powdered coal and heavy oil as the raw material, with oxygen supplied to it to form a clean gas. The sites proposed for the pilot plant are the cities of Yubari, Iwaki, Kita-Ibaraki, Tagawa, Iizuka and Imari. The items for assessment of cost effectiveness are the expenses of development of a site, road construction, removal of existing obstacles, plant construction, power receiving equipment construction, irrigation supply facilities construction, wastewater treatment system construction, ash discharging system construction, transportation, and supply/processing-related maintenance. As a result of the assessment, Iwaki city was picked up as the area almost free from drawbacks to cost effectiveness. (NEDO)

  14. Report on investigations in fiscal 2000 on the projects to support introduction of environment friendly coal utilization system. Green helmet project for briquette production plant - Mae Moh coal mine, Thailand; 2000 nendo kankyo chowagata sekitan riyo system donyu shien jigyo chosa hokokusho. Briquette seizo setsubi ni kakawaru green helmet jigyo (Thai koku Mae Moh tanko)

    NONE

    2001-06-01

    This Green Helmet Project is intended to suppress generation of environment polluting substances in association with coal utilization in Thailand by demonstrating and improving the proliferation infrastructure for the clean coal technology to be used widely in Thailand. The project is also intended to serve for stabilized assurance of energies for Japan. The demonstration project related to briquette manufacturing facilities executed as one of the 'Projects to support introduction of environment friendly coal utilization system' is intended to manufacture at low cost a briquette which is low in odor, free of smoke, and suppressed largely of sulfur oxide generation. The briquette is made by adding clayish minerals, sulfur, a fixing agent and a binder into brown coal being a low grade coal. The project implements proliferation of the technology to reduce environmental load associated with coal utilization in developing countries according to the situation and needs of the counterpart countries. The present project has performed the site surveys and guidance of operation and maintenance techniques as follow-up works of the demonstration project having been completed by cooperation between Japan and Thailand. It is considered that what had been intended in the beginning has been achieved sufficiently. (NEDO)

  15. Report on the supplementary survey on the data processing in the FY 1997 survey of the promotion of geothermal development. Gravity filter analysis (No. B-6 Tsujino-dake area); 1997 nendo chinetsu kaihatsu sokushin chosa data shori ni kakawaru hosoku chosa (juryoku filter kaiseki) hokokusno. No.B-6 Tsujinodake chiiki

    NONE

    1998-08-01

    As a part of the FY 1997 survey of the promotion of geothermal development, the gravity filter analysis was made of the data processing in the Tsujino-dake area of Kagoshima prefecture, and the results were summarized. The geothermal fluid used in the Yamagawa geothermal power plant has the residual magma brought by activities of volcanic rocks of the Ata central shield volcano as heat source, and the fracture system and deep intrusive rocks are reservoirs. A small scale of gravity anomaly area is located, and it reflects high-density volcanic rock masses which are distributed on the earth surface or shallowly under the ground. The ridge stretching from Kiyomi-dake to the Narukawa tunnel and the ridge connecting Kuze-dake and Tsujino-dake are in the high-gravity area and reflect high-density rocks in the shallow part and deep part. There is a possibility of the existence of the fracture system in the high-density deep basement. Calderas continue close to the south of the high-gravity ridge stretching from the Kiyomi-dake to the Narukawa tunnel, and the fracture system which brings the eruption of volcanic rocks of the Ata central shield volcano and the fracture system forming caldera exist in parallel. From the aspect of the geothermal structure, a consideration was made of rock layers which possibly compose the rise of high-density basement in the deep part near the Tsujino-dake. (NEDO)

  16. Report on the FY 1993 basic survey for industrialization related to the survey of overseas geological structure (Muara Lakitan area, Indonesia). Tables and drawings; 1993 nendo kaigai chishitsu kozo nado chosa ni kakawaru kigyoka kiso chosa hokokusho (Indonesia Muara Lankin chiku). Hyo oyobi zumen

    NONE

    1994-03-01

    These are tables and drawings for the FY 1993 basic survey for the coal mine development/industrialization in the Muara Lakitan area of Indonesia. The geological structure in the survey area is under six sets of the anticline/syncline structure which have an NW-SE axis of fold, and exposes the Muaraenim seam repeatedly. The theoretical coal reserve in the depth down to 200m of each of the seams, Nos. 1, 2, 5, 12 and 13, which are great in coal seam change and exist relatively stably, is 143 million tons. The depth for adoption of the shovel/truck system open pit mining seems to be 50m or shallower, and the production is to be approximately 70 million tons. The coal is classified into a subbituminous coal-brown coal rank of the JIS classification. As tables, included were a table of the calculation of coal amount by seam and a table of the analytical result of coal by seam. As drawings, included were borehole logs of coal seam by boring, diagrams of thickness by seam such as the seam thickness/diagrams of thickness by seam such as the coal thickness, diagrams of range of calculating the coal amount, etc. Besides, in relation to coal properties, the report included value diagrams by seam of the inherent moisture, the ash, the volatile matter, the fixed carbon, the heating value, and the total sulfur content. (NEDO)

  17. Fiscal 2000 strategic surveys for respective technical fields. Hydrogen-based energy working group (Analysis of project results relating to hydrogen technology); 2000 nendo bun'yabetsu senryaku chosa hokokusho. Suisokei energy WG (Suiso kanren gijutsu ni kakawaru jigyo seika tou bunseki chosa)

    NONE

    2001-03-01

    Attention is focused on the molten carbonate fuel cell (MCFC) technology which has enjoyed the largest number of industrial property applications out of hydrogen-related technologies under development by NEDO (New Energy and Industrial Technology Development Organization). The patent application is utilized as a tool for analysis, and endeavors are made to systematize and then analyze the correlations between the tasks to discharge and the results of studies in the process of MCFC development. Findings are described below. It is quite difficult to specify the technology involved by the study of patent abstracts. Since an applicant for patent is inclined to describe the application so that it will cover an extensive scope (or, so that the patent will be taken in a broad sense), it takes much time for researchers other than the applicant to specify the field of technological studies where the application originates. Such being the case, it cannot be easily determined whether or not a patent applied for by a private-sector corporation has its origin in a NEDO-implemented project. In addition, it is found that there is not necessarily a correlationship between the importance of a research and development goal and the number of patents generated. (NEDO)

  18. Report on the FY 1995 basic survey for industrialization related to the survey of overseas geological structure (Pondok Labu East area, Indonesia). Data attached 3 (BIP survey report); 1995 nendo kaigai chishitsu kozo nado chosa ni kakawaru kigyoka kiso chosa (Indonesia Pondok Labu higashi chiku) hokokusho. Tenpu shiryo 3 (BIP chosa hokokusho)

    NONE

    1996-03-01

    The survey was conducted based on 'Scope of work for detailed coal exploration in the Pondok Labu East area of East Kalimantan Province, Kalimantan, Indonesia' concluded on June 16, 1995 between NEDO and P.T. Tanito Harum which owns the mining right. This is a BIP survey report. The strike/dip read from the isobath diagram drawn from the result of the boring little agreed with the stratification in the BIP survey. The BIP stratification is greater in strike and dip than in depth. The latter possibly includes false beds and surfaces cut-off/separated by channel, but roughly speaking the structure becomes such a structure as in the isobath diagram. It suggests that there is local undulation everywhere. Judging from the appearance frequency of open type cracks and the size of hole, there are no problems of the crack type decline at frequency of less than one per 5m at the time of drilling mine roadway. The state of upper/lower basement was not good. Refer to the paper (JN9940854). (NEDO)

  19. FY1995 research report on the survey of cryogenic energy utilization systems for environmentally friendly energy community project. Case studies of LNG cryogenic energy cascade-wise utilization; 1995 nendo kankyo chowagata energycommunity jigyo ni kakawaru reinetsu riyo system kento chosa hokokusho. LNG reinetsu no cascade teki riyo case study

    NONE

    1996-03-01

    Japan's import of LNG (liquefied natural gas) has increased in these 15 years from 13-million tons to 43-million tons at a high rate of 2-million tons a year. At present LNG is used only in power generation and town gas business, and its cryogenic feature which may be useful in various fields is not being utilized. In this survey, factors impeding the wider application of the cryogenic energy are investigated, methods for using the energy more widely and mechanisms required therefor are studied, and discussion is made about the feasibility of the utilization of the energy in a cascade-wise form under the environmentally friendly energy community project. Researches are conducted and the results are evaluated in a study carried out on the comprehensive utilization of LNG cryogenic energy. These researches involve the actualities and trends of LNG cryogenic energy utilization in Japan; current status and prospect of the involvement of LNG bases with their neighboring industries and communities; technological measures for cryogenic energy utilization; technological measures related to low-temperature media and cold heat transportation systems; technological measures for the cascade-wise multidirectional utilization of cryogenic energy; and case studies on assumed local models. (NEDO)

  20. Survey for development feasibility in fiscal 1999 investigation of geothermal development and promotion. Evaluation report on practicability technology survey SWD method (Evaluation report concerning verification test); 1999 nendo chinetsu kaihatsu sokushin chosa no uchi kaihatsu kanosei chosa. Jitsuyoka gijutsu chosa SWD ho hyoka hokokusho (jissho shiken ni kakawaru hyoka hokokusho)

    NONE

    2000-05-01

    An evaluation test was conducted on SWD (Seismic While Drilling) method as a part of the investigation of geothermal development and promotion. The test was implemented at the time of drilling of N11-MD-3 well in the northeast base area of Busadake, Hokkaido. The test items were such as verification of direct waves propagating from a bit to the surface, identification of signals passing through a fault zone using direct waves and reflected waves, estimation of distance between a fault and a bent zone, and grasping the direction of signal propagation at the time of inclined drilling. As a result of the experiments and studies, following conclusions were obtained. Reflected waves extracted are not necessarily limited to those from a reflection area from which the shape of a fault can be grasped; unless there is a clear reflection area that can be picked up on the surface near a fault, the application of this method is not effective. In an analysis using direct waves, it was possible to obtain an inclined angle of a fault plane from the estimation of velocity structure, propagation route, and assumption of the shape of the fault plane and, therefore, to grasp the shape of the fault. Obtaining reference data is essential for identifying bit signals. (NEDO)

  1. FY 2000 Immediate-effect type project for research and development for international standards supporting information technology industries. Comprehensive study on promotion of international standardization; 2000 nendo joho sangyo shien sokkogata kokusai hyojun kaihatsu jigyo seika hokokusho. Kokusai hyojunka suishin ni kakawaru sogo chosa kenkyu

    NONE

    2001-03-01

    The information technology and international standardization are studied for the elementary information technology, mechanical safety areas and electronic trading, aimed at achieving the international standards in a short time for the information industrial sector, which shows rapid technological development. The program for the elementary information technology includes development/standardization of the testing/evaluation methods for transparent electroconductive films for notebook computers, liquid crystal monitors or the like, specifically for the mechanical and physical properties. The program for mechanical safety areas includes definition of the closed space type mechanical safety monitoring techniques and use of safety-confirmation type sensors for the techniques, and standardization of the requirements of the protectors for use of the safety-confirmation type sensors, among others. The program for the electronic trading includes standardization of the electronic catalogues of the instrumentation devices, dictionaries of the instrumentation devices and device-screening processes. The other efforts include development of the applications and system infrastructure functions, construction of the demonstration test systems, and demonstration tests. (NEDO)

  2. Project in fiscal 2000 of developing international standards for supporting new industries. Comprehensive surveys and researches in relation with promotion of international standardization; 2000 nendo shinki sangyo shiengata kokusai hyojun kaihatsu jigyo seika hokokusho. Kokusai hyojunka suishin ni kakawaru sogo chosa kenkyu

    NONE

    2001-03-01

    With an objective of promoting the international standardization efficiently and strategically, surveys were performed on trends of international standardization in Europe and America, and researches on means for the international standardization. The standards strategy in the U.S. is to increase the U.S. competitive power in overseas countries, support strongly the domestic markets, and at the same time, deal with problems such as those of the environment. It attempts to structure a framework that can be utilized by any concerned parties, including business entities, the government, and consumers, whereas the National Standards Strategy (NSS) has proposed the initiative. In Europe, targeting to establish international standards originated from Europe, works are becoming more active for new technologies such as information communicating technologies from the R and D phase to the test and evaluation methods, taking the standardization into consideration. These works are being carried out within the scope of the common EU R and D, represented by the 'Framework program' and the 'EUREKA program'. In the survey and research on means to complete the international standardization, analyses and surveys were performed on the latest information, such as TC/SC, which are scheduled of proposition. Advices were given on giving the directionality and establishing the strategy. (NEDO)

  3. Report on the results of the FY 1999 study on the standardization of the measuring/database method for data on human body shape characteristics; 1999 nendo shinki sangyo ikusei sokkogata kokusai hyojun kaihatsu jigyo. Shintai keitai tokusei data no keisoku database ka shuho ni kakawaru hyojunka

    NONE

    2000-03-01

    The purpose of the present project is to conduct studies on three-dimensional human body measurement; the method of describing measurement results; the method of developing a database using measurement data; and the method of statistical data processing. Results of these studies are to be used to establish an international standard on three-dimensional human shape data. In the course of the project, the state of relevant studies conducted outside Japan was investigated. As a result, it has been found that studies on the method of processing three-dimensional human body shape data are being promoted independently by different research institutes. At present, it is impossible to build up a consensus on the method among these institutes. Additionally, standardizing the method may stifle the creativity of researchers. We have therefore decided to exclude the standardization of body shape data processing method from the scope of the project. Our conclusion is that the standard proposed in the project should be based on the human body shape data format, obtained through a study on the method of describing three-dimensional body shape data. And it should provide for a data format for three-dimensional human body measurement, which can store all data required for product of space design (e.g. data on human body sizes, landmarks and texture). According to our plan, this standard will be proposed in the form of a technical report, since it is yet too early to se out establishing the standard as an international standard. (NEDO)

  4. FY1995 research report on the survey of cryogenic energy utilization systems for environmentally friendly energy community project. Case studies of LNG cryogenic energy cascade-wise utilization; 1995 nendo kankyo chowagata energycommunity jigyo ni kakawaru reinetsu riyo system kento chosa hokokusho. LNG reinetsu no cascade teki riyo case study

    NONE

    1996-03-01

    Japan's import of LNG (liquefied natural gas) has increased in these 15 years from 13-million tons to 43-million tons at a high rate of 2-million tons a year. At present LNG is used only in power generation and town gas business, and its cryogenic feature which may be useful in various fields is not being utilized. In this survey, factors impeding the wider application of the cryogenic energy are investigated, methods for using the energy more widely and mechanisms required therefor are studied, and discussion is made about the feasibility of the utilization of the energy in a cascade-wise form under the environmentally friendly energy community project. Researches are conducted and the results are evaluated in a study carried out on the comprehensive utilization of LNG cryogenic energy. These researches involve the actualities and trends of LNG cryogenic energy utilization in Japan; current status and prospect of the involvement of LNG bases with their neighboring industries and communities; technological measures for cryogenic energy utilization; technological measures related to low-temperature media and cold heat transportation systems; technological measures for the cascade-wise multidirectional utilization of cryogenic energy; and case studies on assumed local models. (NEDO)

  5. FY 1999 Report on the technical results. Research and development project for creation of the quick-effect type international standards (Standardization in the field of safety of machinery); 1999 nendo sokkogata kokusai hyojun sosei kenkyu kaihatsu jigyo seika hokokusho. Kikai anzensei ni kakawaru hyojunka

    NONE

    2000-03-01

    It is necessary to standardize the concepts and terminology of safety, design principles, protection and technology for evaluation of safety over a wide range including designs and specifications, in order to secure safety of the users. The international standardization has been promoted, based on the European voluntary standards EN. It is necessary for Japan to propose the international standards reflecting the industrial environments of Japan, in order to keep and expand her international competitiveness. Those technologies developed for the above purposes include the safety-related ones based on the Japanese electronic technologies, electronized operation-controlling technologies with dynamic fail safe signal processing, DC power supply circuit with a failure-sensing circuit, opto-ultrasonic hybrid type personal sensing device and pressure-sensitive mat sensor, emergency stop devices having no electrical contact to eliminate the contact fusing risk, and video camera system which facilitates emergency stop action of machinery. These results are submitted to the related technical committees of ISO or IEC. A total of 46 items of the international standard proposal drafts related to IEC/TC44 are also submitted. (NEDO)

  6. FY 1999 report on the results of the verification study on the alkali recovery process of the non-wood pulp/paper manufacturing industry; 1999 nendo seika hokokusho. Hi-mokuzai parupu seishi sangyo arukari kaishu purosesu ni kakawaru jissho shiken

    NONE

    2001-03-01

    For the purpose of contributing to energy conservation and environmental improvement in China, a joint verification study with China was made of a system for alkali recovery and heat recovery by effectively extracting/concentrating/burning black liquid in non-wood pulp/paper manufacturing plants in China, and the FY 1999 results were reported. Concretely, in the plan, an alkali recovery plant is to be constructed in Shandong Province to verify energy conservation and reduction in environmental loads. In the element study and the study of the related technology, an investigational study was made of the performance of waste water treatment facilities of paper manufacturing plants in China. Study was further made of the effect of desiliconizing agent on freeness and the method for treatment of waste water at the middle stage. As to the system design/manufacture, the basic design (material balance, heat balance, PID, layout, specifications, etc.) and detailed design were finished based on articles upon the technology to be adopted to facilities for verification and the basic design. Besides, the following were carried out: survey/selection of makers, order for all equipment, management of the jobs to be done by makers, etc. Equipment was sent in to the site. (NEDO)

  7. FY 2000 report on the survey of new energy policies by developing countries. Survey of collection/analysis of information on effective energy utilization, etc.; 2000 nendo tojokoku no shin energy seisaku ni kakawaru chosa hokokusho. Energy yuko riyo nado joho shushu bunseki chosa

    NONE

    2001-03-01

    For the purpose of effectively introducing technologies for new energy/energy conservation in developing countries, the paper arranged the policies, systems and organizations in relation to new energy in developing countries. Survey was made of the following two fields: 1) new energy in developing countries; 2) situation of new energy introduction in developing countries (India, Indonesia, Thailand, Malaysia, the Philippines and China). In 2), about India, for example, survey was made on the following: outline of the new energy policy, regulation for new energy promotion and law specifying concrete measures, departments in charge/promotion organizations for new energy, system and setup for new energy promotion, numerical target of new energy introduction, support from developed countries including the E.U. and the U.S. and the effects, support from international organizations including the World Bank and UNDP and the effects, the country's main industries related to new energy, the government's policy for the domestic production, outline of the use of India's biomass project, etc. (NEDO)

  8. Report on fiscal 1998 investigation of geothermal development and promotion and on supplementary investigation concerning data processing (geology/decomposed zone investigation and gravitational probing). No. B-7 Kuwanosawa area; 1998 nendo chinetsu kaihatsu sokushin chosa. Data shori ni kakawaru hosoku chosa (chishitsu henshitsutai chosa oyobi juryoku tansa) hokokusho (No.B-7 Kuwanosawa chiiki)

    NONE

    1999-09-30

    A geology/alteration zone investigation and gravitational probing were carried out, with the results summarized, for the purpose of elucidating the structure of geothermal reservoir structure in the Kuwanosawa area. The investigation was implemented in the southeast part of Akita prefecture including Yuzawa city and Ogachimachi during the period between June 9 and August 31, 1999. The results were as follows. The geology of the investigation area consists of granite, as the base rock, and the covering Doroyu layer, Minasegawa layer, Sanzugawa layer and intrusive rocks in the Neo Tertiary system as well as Kabutosan layer and volcanic rocks in the Quaternary system. No wide area alteration zone existed, while vein-like alterations and hydrothermal veins along cracks were recognized, with the fluid inclusion homogenizing temperature showing 240-260 degrees C, which presumably indicates the existence of local hydrothermal activity until comparatively recently. The geothermal structure of the subject area is very likely dependent on thermal conduction from a deep thermal source existing in the Wasabizawa district. In the underground depth, it is inferred that a hydrothermal system is formed in the NW fault structure, lower part of cracks accompanying NS hydrothermal vein, and in the NNW/NE structures inferable from the gravitational probing. (NEDO)

  9. FY 2000 report on the trend survey of technical development of high speed/high function electronic devices such as quantum functional devices in association with the rationalization of energy utilization; 2000 nendo energy shiyo gorika ni kakawaru ryoshika kino soshi nado kosoku kokino denshi device no gijutsu kaihatsu doko chosa hokokusho

    NONE

    2001-03-01

    Concerning the results of the R and D made by NEDO of superlattice devices (FY 1981-1990) and quantum functional devices (QFD) (FY 1991-2000) as high speed/high function electronic devices, this survey was aimed at investigating the trend of the newest technology to grasp the technical effects, the state of commercialization/product-making, and the future. The effects, technical subjects, etc. in the R and D of superlattice devices were succeeded to the R and D of QFD as the succeeding project. Here, therefore, the paper arranged the outlook of the commercialization/product-making in relation to the R and D of QFD and the future R and D subjects. In the R and D, features of QFD as target were made clear. The commercialization is limited to Motorola's QMMIC, Fujitsu's RHET, etc. As to the other R and D items, subjects of the technical development to be implemented toward the commercialization just became clear. The subject is the heightening of micro (nano meter) processing technology. The important subject, in particular, is compatibility of the heightening of micro processing and the improvement of throughput. (NEDO)

  10. Research report of FY 1997 on the environmentally acceptable coal utilization system introduction support project. Demonstration project on simplified desulfurizers; 1997 nendo seika hokokusho. Kankyo chowagata sekitan riyo system donyu shien jigyo (kan`i datsuryu setsubi ni kakawaru jissho jigyo)

    NONE

    1998-03-01

    To reduce SOx with coal utilization, a desulfurizer is introduced in Thailand as diffusion activities in the demonstration program. The purpose is to reduce the environmental pollutants. For this desulfurizer, lime mud mainly composed of lime stone is used as an absorber. SO2 in the flue gas is absorbed by the slurry of lime mud, to form calcium sulfite. The calcium sulfite blown in the bottom of recycling tank is oxidized by oxygen in the air, to form gypsum. The gypsum is recovered as a by-product. In this fiscal year, a feeder of lime stone, spray nozzles, and various analysis apparatuses were supplied. Supervisors for electric instrumentation/control were also dispatched as well as for main body construction, to carry out the instrumentation setting works, check of sequences, and adjustment of apparatuses. After the test operation, supervisors for the demonstration operation were dispatched up to March 1998, to conduct the cooperation works between Japan and Thailand sides. Thus, successful and successive demonstration operation was confirmed. 21 figs., 6 tabs.

  11. Report on survey in fiscal 1999 for promotion of geothermal development. Supplementary survey on data processing (fluid inclusion test) for Tsujinodake Area No. B-6; 1998 nendo chinetsu kaihatsu sokushin chosa hokokusho. Data shori ni kakawaru hosoku chosa (ryutai gan'yubutsu shiken nado) No.B-6 Tsujinodake chiiki

    NONE

    1999-10-01

    This paper reports the fluid inclusion test in the Tsujinodake area in fiscal 1998 for the survey on promotion of geothermal development. The fluid inclusions were classified into three types: those with the maximum value or the average value of the homogenizing temperature agreeing nearly with the saturated boiling curve, those with the homogenizing temperature showing the interim temperature between the present well temperature and the saturated boiling curve, and those agreeing nearly with the present well temperature. It is presumed that the bed temperatures in depths of 1,125.30 m and 1,427.50 m have changed very little since after formation of the present circulating and flowing systems of geothermal waters until now. In contrast at the depth of 1,691.75 m, the bed temperature was estimated to have fallen slightly from that in the most active period of the geothermal water activities. As a result of the rock age measurement, it is estimated that, in the Nansatsu bed groups distributing around the N10-TD-1 well, the temperature has fallen gradually after having been subjected to hot water alteration actions at higher than 200 degrees C, and cooling has taken place down to 200 to 250 degrees C as the fission track date temperature of zircon in the relatively late period (about several hundred thousand years before). There should have been no thermal change that affects the age measurement up to now since then. (NEDO)

  12. Research report for fiscal 1998. Research of feasibility of international cooperation over technologies of photovoltaic power generation in deserts and long-range transportation of generated power; 1998 nendo chosa hokokusho. Sabaku chiiki wo riyoshita taiyoko hatsuden chokyori yuso gijutsu ni kakawaru kokusai kyoryoku kanosei chosa

    NONE

    1999-03-01

    Studies were conducted about the construction of systems for the above. A working group on international cooperation feasibility was established inviting several scientists and specialists, and a VLS-PV (very large-scale photovoltaic) system feasibility study plan was drafted which was to construct a framework in which international cooperation would be carried out. At preliminary meetings etc., participated in by members of the Task VI workshop and of several IEA (International Energy Agency) member states, opinions were heard on the Japanese plan, which was also improved there. An agreement was reached between CTI and IEA/PVPS that a preliminary feasibility study be conducted for one year under IEA/PVPS Task VI, and, in compliance with this agreement, a 2nd specialists' meeting was held at Milan, Italy, and then a 3rd at Kyoto, Japan. The fruit was 'A Preliminary Analysis for the VLS-PV Survey' completed through the cooperation of the participating countries. (NEDO)

  13. Research report of FY 1997 on the environmentally acceptable coal utilization system introduction support project. Demonstration project of circulating fluidized bed boiler (Jinzhou Coal-Thermal Power Corporation); 1997 nendo seika hokokusho (kankyo chowagata sekitan riyo system donyu shien jigyo). Junkan ryudosho boiler ni kakawaru jissho jigyo (Jinzhou netsuden sokoji)

    NONE

    1998-03-01

    To verify the clean coal technology to be diffused in China and consolidate its diffusion basis, demonstration project of circulating fluidized bed boiler was conducted through the cooperation with China which is positive in its introduction. This report describes its characteristics. Coal and limestone are supplied in a lower part of combustion chamber, and are mixed with circulating ash by fluidized air for combustion. Densely fluidized bed the same as the bubbling fluidized bed is formed in the lower part of combustion chamber, which provides excellent stability in ignition and combustion. Particles including ash, char and limestone formed during the combustion are discharged into the cyclone through the convection heat transfer part at the outlet of combustion chamber with the combustion gas flow. Since the gas temperature is lowered to 400 to 500degC at the convection heat transfer part, troubles of the ash circulating system can be prevented. The combustion gas separated from ash at the cyclone is discharged through the heat exchanger and precipitator, and the collected ash is returned to the lower part of combustion chamber. In FY 1997, design, fabrication, procurement/inspection, field survey/meeting, survey of visitors/meeting, and education were carried out. 4 figs., 4 tabs.

  14. Report on the fiscal 1997 result of the Japan-China joint demonstration project of environment-friendly cost utilization systems. Low grade coal combustion system (Zhejiang Huba Co. Ltd.); 1997 nendo seika hokokusho kankyo chowagata sekitan riyo system kyodo jissho jigyo. Teihin`itan nensho system ni kakawaru jissho jigyo

    NONE

    1998-03-01

    This demonstration project aims at reduction of pollutants derived from coal utilization in China by demonstration of CCT to be diffused in China and preparation of diffusion bases, and stable import of energy for Japan. A low-grade coal combustion system burns low-grade coal by use of an internal circulating fluidized bed boiler which burns coal by uniform mixing and circulation of coal and some particles such as limestone and ash. Main specifications of the boiler are as follows: evaporation rate of 35t/h, steam pressure of 3.82MPa (39.0kg/cm{sup 2}), steam temperature of 450degC, water supply temperature of 150degC, internal circulating fluidized bed combustion type, boiler efficiency of 75%, and desulfurization rate of 90% or more. Main properties of low-grade coal are as follows: calorific value of 1830kcal/kg, coal size of 10mm or less, total water content of 2.5%, total S content of 2.7%, ash content of 67.7%, limestone purity of 50% or more, and stone size of 3mm or less. The results in fiscal 1997 are as follows: field survey and arrangement, basic planning and design, design, production and procurement of equipment, training, and dispatch of field supervisor. 26 figs., 3 tabs.

  15. Research report of FY 1997 on the environmentally acceptable coal utilization system introduction support project. Follow-up project on circulating fluidized bed boiler introduction (Calaca Batangas Thermal Power Station); 1997 nendo chosa hokokusho. Kankyo chowagata sekitan riyo system donyu shien jigyo (junkan ryudosho boiler ni kakawaru follow up jigyo (Calaca Batangas karyoku hatsudensho))

    NONE

    1998-03-01

    For the follow-up project, to promote the diffusion of results of the clean coal technology (CCT) model projects, experts of circulating fluidized bed boilers were dispatched, to guide and advise for the operation of facilities introduced in these projects. The purpose of these projects is to diffuse the CCTs, and to support the promotion of environmental measures. Some guidance and advice about operation processes, data processing, operation regulation, maintenance, and boiler maintenance works were provided to the Ministry of Energy and Electric Power Corporation of the Philippines. Semirara, Malangas, and Samar coals in the Philippines were used for the tests. The boiler facilities could be operated by Philippine operators themselves. Based on the guidance and advice about operation processes, combustion tests using various Philippine coals were also planned and conducted by themselves. The maintenance techniques were transferred to Philippine operators through the inspection, repair and advice. The Philippine side understood the technologies well, and the circulating fluidized bed boiler technology was independently educated in the Philippines. 23 figs., 16 tabs.

  16. FY 1999 project on the development of new industry support type international standards. Comprehensive survey research on the promotion of international standardization; 1999 nendo shinki sangyo shiengata kokusai hyojun kaihatsu jigyo seika hokokusho. Kokusai hyojunka suishin ni kakawaru sogo chosa kenkyu

    NONE

    2000-03-01

    For the purpose of promoting the international standardization effectively/strategically, a comprehensive survey was made, and the FY 1999 results were summarized. In the trend survey on the comprehensive international standardization, survey was conducted for companies in the material field (plastics, rubber and iron steel) and in the mechanical field (robot, machinery, aircraft, etc.). As a result of the survey, it was found out that they have few headquarters systems and experts, but they tackle it strategically and defensively, taking the standardization as business. Also as to the trend of CEN/CENELEC, importance of the continued trend survey was pointed out. In the survey of policy for the international standardization, survey was carried out on the trend of the process for working out the international standards (TS, ITS and SDO). Further, in relation to the technology standards and intellectual property rights in the hi-tech field, survey was made on the present situation of rules for handling intellectual property rights of organizations, groups, etc. for standardization, how to handle intellectual property rights in the standardization process, problems and the solution, etc. (NEDO)

  17. Fiscal 1991 research report. Research trend survey for next-generation industrial structure technology research and development project - Research and development of advanced materials for extreme environments; 1991 nendo jisedai sangyo kiban gijutsu kenkyu kaihatsu project ni kakawaru kenkyu doko chosa hokokusho. Chotaikankyosei senshin zairyo no kenkyu kaihatsu (sekitoku daiene)

    NONE

    1992-03-01

    Efforts were exerted to develop intermetallic compounds and C/C (carbon/carbon) composites to serve as advanced materials for extreme environments. In relation with advanced materials, especially with intermetallic compounds and fiber reinforced intermetallic compound composite materials, a technical research survey was conducted covering the three fields of (1) summarization of activities conducted up to fiscal 1991, (2) contents of associated aerospace projects, and (3) aeroengine components. In Field (1), the ground on which the project was created and the project's basic plans, goals, and systems, and its ripple effects are discussed, and the fruits produced so far are summarized. In Field (2), aeroengine component related projects of America, Britain, France, Germany, and Japan are investigated. In Field (3), aluminum alloys, titanium alloys, alloy steel, superalloys, intermetallic compounds, and intermetallic compound composite materials are discussed with attention paid to their current status and future trend, characteristics they are supposed to finally assume, and technical tasks to discharge for the development of technologies concerned. (NEDO)

  18. FY 1998 annual report on the compilation of database of experts for development of welfare equipment. Surveys for collecting information of institutes supporting, e.g., welfare equipment research and development; 1998 nendo fukushi yogu no kaihatsu ni kakawaru senmonteki chiken wo yushita jinzai database no kochiku chosa hokokusho. Fukushi yogu kenkyu kaihatsu nado shien kikan joho seibi chosa

    NONE

    1999-03-01

    In order to promote supply of high-quality, inexpensive welfare equipment, the data about public testing and research institutes throughout Japan are collected for their organizations, research themes, expertized areas, relations with welfare equipment, future activity guidelines and the like, and expert employees, so that enterprises can have adequate advises from them, when they plan to start researches on and development of related equipment. Information was obtained by means of questionnaires returned back from a total of 127 institutes related to industrial testing and researches, and 61 institutes, e.g., rehabilitation centers, deeply related to welfare equipment. This reports compiles information on 48 institutes which are conducting researches or the like on welfare equipment. The compiled lists of the local institutes supporting welfare equipment research and development activities describe, e.g., their total expenses, numbers of technical experts, conditions of windows responsible for welfare equipment or the like, percentages of expenses related to welfare equipment on total expenses, percentages of numbers of technical experts responsible for welfare equipment on total numbers of technical experts, and major research themes on welfare equipment. (NEDO)

  19. Achievement report on the incoming projects related to ITS. Research and survey involving 'Research and development of universal design vehicle based on ITS technology'; ITS renkei kokei project an. 'ITS gijutsu wo tenkaishita universal design vehicle no kenkyu kaihatsu' ni kakawaru kenkyu chosa

    NONE

    2001-02-01

    For the promotion of 'Report on Strategy of Automobile Industrial Technologies - Strategy 2 - Promotion of Development of Vehicle Environment Recognition Technology and Driver's State Detection Technology,' investigations and studies including overseas surveys are conducted over six selected subjects which are (1) ITS (Intelligent Transportation System) and VCSS (Voice Communications Switching System), (2) old people, handicapped people, and universal design, (3) intelligent interface, (4) techniques of assessing bionic data and load of driving, (5) driving simulator and virtual reality, and (6) data communication, mobile data communication in particular. It is then found that, on the assumption that there exists a mobile communications environment such as ITS or Internet aboard the automobile, it is important to develop a universal design automobile which adapts itself to the driver thereby respecting driver's viewpoint and that such is to be accomplished by grasping driver's characteristics especially under extraordinary conditions in the way of Kansei engineering and by redesigning the driver's operating system making use of the active interface technology. A conclusion is reached that development should continue in compliance with the separately specified 6 items which are indispensable for the research and development of an ITS based man-adaptive automobile. (NEDO)

  20. Reports on 1977 result of research. Investigation for selecting site location of pilot plant for 7,000Nm{sup 3}/day class high calorie gasification; 1977 nendo sunshine keikaku ni kakawaru plant kenkyu kaihatsu seika hokoku. 7,000Nm{sup 3}/nichi kyu kokarori gas ka pilot plant yochi no ricchi sentei chosa

    NONE

    1978-03-20

    A report was made on the result of investigation for selecting a suitable site for a coal gasification pilot plant. The high calorie gasification plant under the Sunshine Project is scheduled to have a parallel operation of two methods. It could be decided on one only method depending on the future studies. One is the 'water gasification method' using coal only as the raw material, with hydrogen gas added to contrive methanization. The other is the 'hybrid gasification method' using mixed slurry of powdered coal and heavy oil as the raw material, with oxygen supplied to it to form a clean gas. The sites proposed for the pilot plant are the cities of Yubari, Iwaki, Kita-Ibaraki, Tagawa, Iizuka and Imari. The items for assessment of cost effectiveness are the expenses of development of a site, road construction, removal of existing obstacles, plant construction, power receiving equipment construction, irrigation supply facilities construction, wastewater treatment system construction, ash discharging system construction, transportation, and supply/processing-related maintenance. As a result of the assessment, Iwaki city was picked up as the area almost free from drawbacks to cost effectiveness. (NEDO)

  1. Project in fiscal 2000 of developing international standards for supporting new industries. Comprehensive surveys and researches in relation with promotion of international standardization; 2000 nendo shinki sangyo shiengata kokusai hyojun kaihatsu jigyo seika hokokusho. Kokusai hyojunka suishin ni kakawaru sogo chosa kenkyu

    NONE

    2001-03-01

    With an objective of promoting the international standardization efficiently and strategically, surveys were performed on trends of international standardization in Europe and America, and researches on means for the international standardization. The standards strategy in the U.S. is to increase the U.S. competitive power in overseas countries, support strongly the domestic markets, and at the same time, deal with problems such as those of the environment. It attempts to structure a framework that can be utilized by any concerned parties, including business entities, the government, and consumers, whereas the National Standards Strategy (NSS) has proposed the initiative. In Europe, targeting to establish international standards originated from Europe, works are becoming more active for new technologies such as information communicating technologies from the R and D phase to the test and evaluation methods, taking the standardization into consideration. These works are being carried out within the scope of the common EU R and D, represented by the 'Framework program' and the 'EUREKA program'. In the survey and research on means to complete the international standardization, analyses and surveys were performed on the latest information, such as TC/SC, which are scheduled of proposition. Advices were given on giving the directionality and establishing the strategy. (NEDO)

  2. Fiscal 1999 report on results of joint demonstrative project for environmentally benign coal utilization system. Demonstrative project concerning coal preparation technology (China); 1999 nendo kankyo chowagata sekitan riyo system kyodo jissho jigyo seika hokokusho. Sentan gijutsu ni kakawaru jissho jigyo (Chugoku)

    NONE

    2001-03-01

    This paper describes the demonstrative project for coal preparation technology, as a part of the measures against environmental pollution due to the structuring of demonstration and dissemination basis for clean coal technologies in China, The results for fiscal 1999 is reported. In the utilization of coal in China, a problem of urgency is the highly efficient selection and removal of sulfur contents in raw coal. Coal production in Chongquing City is yearly 30 million tons, of which 90% contains sulfur contents of 3% or higher. At Jinjia Colliery of Panjiang Coal and Electric Co. Ltd., Guizhou Province, a site for the present project, a number of coal seams are unsuitable for single utilization because of high sulfur contents. The coal preparation technologies to be introduced are expected to improve coal preparation efficiency and desulfurization ratio in terms of both the washability of raw coal and the accuracy of the coal washer. This is the third year of the project, with the following activities performed, namely, research/design, manufacturing/procurement of equipment, design for construction work, training of operators or the like, and documentation. The manufacturing and procurement are for such equipment as vacuum disk filter with accessories, waste water thickener, pressure filter for tailings with accessories, flocculant pump/piping, slurry tank/pump, high-shear mixer with accessories, and electric instrumentation. All the equipment arrived at the site in January, 2001. (NEDO)

  3. Fiscal 1991 research report. Research trend survey for next-generation industrial structure technology research and development project - Research and development of advanced materials for extreme environments; 1991 nendo jisedai sangyo kiban gijutsu kenkyu kaihatsu project ni kakawaru kenkyu doko chosa hokokusho. Chotaikankyosei senshin zairyo no kenkyu kaihatsu (sekitoku sekiyu)

    NONE

    1992-03-01

    Efforts were exerted to develop intermetallic compounds and advanced C/C (carbon/carbon) composite materials usable under extreme environments such as high temperatures. In relation with advanced composite materials, especially with projects for developing composite materials using oil as raw material, a survey was conducted of the three fields of (1) summarization of activities conducted up to fiscal 1991, (2) contents of associated aerospace projects, and (3) oil based composite material technology. In Field (1), past achievements are summarized. In Field (2), aerospace projects under way across the world are broken down by airframe and engine, and are reviewed from the viewpoint of needs for materials. In Field (3), the present and future of heat resisting thermosetting composite materials, thermoplastic composite materials, and C/C composites are discussed. Characteristics such materials are supposed to finally assume and tasks to discharge for technical development are also taken up. (NEDO)

  4. Exclusive study of Ni+Ni and Ni+Au central collisions: phase coexistence and spinodal decomposition

    Guiot, B.

    2002-12-01

    The INDRA multidetector allowed us to study the Ni+Ni collisions at 32A MeV and the Ni+Au collisions at 52,4 MeV. Central collisions leading to 'quasi-fused' systems were isolated using multidimensional analysis techniques: the Discriminant Analysis and the Principal Component Analysis. Comparison with a statistical model shows that the selected events are compatible with thermodynamical equilibrium. The average thermal excitation energy is 5A MeV for both systems. Calculations of heat capacities show that the deexcitation of the hot sources are akin to a liquid-gas phase transition of nuclear matter. Indeed heat capacities exhibit a negative branch as expected for a phase transition of a finite system. The dynamics of this phase transition has been investigated by applying the charge correlation method. An enhanced production of events with equal-sized fragments has been evidenced for Ni+Au at 52A MeV. No signal was found for Ni+Ni at 32A MeV. Finally this method was improved by taking into account the total charge conservation. The signal is seen more clearly for Ni+Au at 52A MeV, but is ambiguous for Ni+Ni at 32A MeV. The path followed in the state diagram, or the involved time scales, seem to be different for these systems. (authors)

  5. Atomistic calculations of hydrogen interactions with Ni3Al grain boundaries and Ni/Ni3Al interfaces

    Baskes, M.I.; Angelo, J.E.; Moody, N.R.

    1995-01-01

    Embedded Atom Method (EAM) potentials have been developed for the Ni/Al/H system. The potentials have been fit to numerous properties of this system. For example, these potentials represent the structural and elastic properties of bulk Ni, Al, Ni 3 Al, and NiAl quite well. In addition the potentials describe the solution and migration behavior of hydrogen in both nickel and aluminum. A number of calculations using these potentials have been performed. It is found that hydrogen strongly prefers sites in Ni 3 Al that are surrounded by 6 Ni atoms. Calculations of the trapping of hydrogen to a number of grain boundaries in Ni 3 Al have been performed as a function of hydrogen chemical potential at room temperature. The failure of these bicrystals under tensile stress has been examined and will be compared to the failure of pure Ni 3 Al boundaries. Boundaries containing a preponderance of nickel are severely weakened by hydrogen. In order to investigate the potential embrittlement of γ/γ' alloys, trapping of hydrogen to a spherical Ni 3 Al precipate in nickel as a function of chemical potential at room temperature has been calculated. It appears that the boundary is not a strong trap for hydrogen, hence embrittlement in these alloys is not primarily due to interactions of hydrogen with the γ/γ interface

  6. Structural features in Ni-Al alloys

    Abylkalykova, R.B.; Kveglis, L.I.; Rakhimova, U.A.; Nasokhova, Sh.B.; Tazhibaeva, G.B.

    2007-01-01

    Purpose of the work is study of structural transformations under diverse memory effect in Ni-Al alloys. Examination were conducted in following composition samples: Ni -75 at.% and Al - 25 at.%. The work is devoted to clarification reasons both formation atom-ordered structures in inter-grain boundaries of bulk samples under temperature action and static load. Revealed inter-grain inter-boundary layers in Ni-Al alloy both bulk and surface state have complicated structure

  7. Compositional and structural characterisation of Ni-phyllosilicates in hydrous silicate type Ni-laterite deposits

    Villanova de Benavent, Cristina

    2015-01-01

    Ni-bearing Mg-phyllosilicates (commonly known as garnierites) are significant ore minerals in many Ni-laterite deposits worldwide. However, the characterisation of these mineral phases is complex, as well as their classification and nomenclature, due to their fine-grained nature, low crystallinity and frequent occurrence as mixtures. The aim of this study is to shed some light to the nature of the Ni-bearing Mg-phyllosilicates occurring at the Falcondo Ni-laterite. In this deposit, these ...

  8. Thermal capture cross section for 58Ni (n,γ)59 Ni reaction

    Carbonari, A.W.; Pecequilo, B.R.S.

    1989-01-01

    The 58 Ni total thermal capture cross section was determined by suming the partial cross sections calculated for the primary transitions of the reaction 58 Ni (n,γ) 59 Ni. The primary transitions energies and intensities were determined from the 58 Ni thermal neutrons prompt gamma capture gamma rays spectrum in the 3.7 to 9.3 MeV region. The obtained value for the total cross section was 4.52 + 0.10b. (author) [pt

  9. Formation enthalpy of NiBe and Ni5Be21

    Ivanov, M.I.; Karpova, T.F.; Dalago, N.Yu.

    1981-01-01

    The method of dissolution calorimetry is used to determine standard enthalpies of NiBe and Ni 5 Be 21 formation, which are 84.8+-2.2 and (-669+-37)kJ/mol. The enthalpy values of NiBe and Ni 5 Be 21 at 331 K are shown to coincide (within the limits of errors of these values) with the values at the standard temperature of 298.15 K [ru

  10. Effects of Ni vacancy, Ni antisite, Cr and Pt on the third-order elastic constants and mechanical properties of NiAl

    Wu, Shaohua; Wu, Xiaozhi; Wang, Rui; Liu, Qing; Gan, Liyong

    2014-01-01

    Effects of Ni vacancy, Ni antisite in Al sublattice, Cr in Al sublattice, Pt in Ni sublattice on the second-order elastic constants (SOECs) and third-order elastic constants (TOECs) of the B2 NiAl have been investigated using the first-principles methods. Lattice constant and the SOECs of NiAl are in good agreement with the previous results. The brittle/ductile transition map based on Pugh ratio G/B and Cauchy pressure Pc shows that Ni antisite, Cr, Pt and pressure can improve the ductility of NiAl, respectively. Ni vacancy and lower pressure can enhance the Vickers hardness Hv of NiAl. The density of states (DOS) and the charge density difference are also used to analysis the effects of vacancy, Ni antisite, Cr and Pt on the mechanical properties of NiAl, and the results are in consistent with the transition map. © 2014 Elsevier Ltd. All rights reserved.

  11. Effects of Ni vacancy, Ni antisite, Cr and Pt on the third-order elastic constants and mechanical properties of NiAl

    Wu, Shaohua

    2014-12-01

    Effects of Ni vacancy, Ni antisite in Al sublattice, Cr in Al sublattice, Pt in Ni sublattice on the second-order elastic constants (SOECs) and third-order elastic constants (TOECs) of the B2 NiAl have been investigated using the first-principles methods. Lattice constant and the SOECs of NiAl are in good agreement with the previous results. The brittle/ductile transition map based on Pugh ratio G/B and Cauchy pressure Pc shows that Ni antisite, Cr, Pt and pressure can improve the ductility of NiAl, respectively. Ni vacancy and lower pressure can enhance the Vickers hardness Hv of NiAl. The density of states (DOS) and the charge density difference are also used to analysis the effects of vacancy, Ni antisite, Cr and Pt on the mechanical properties of NiAl, and the results are in consistent with the transition map. © 2014 Elsevier Ltd. All rights reserved.

  12. Creep and shrinkage of Mo(Ni)

    Kaysser, W.A.; Hofmann-Amtenbrink, M.; Petzow, G.

    1984-01-01

    To avoid some of the errors inherent in a quantitative interpretation of shrinkage of powder compacts as Mo-Ni, other experiments were looked for, where the influence of Ni on the material transport properties of Mo could be measured semi-quantitatively during heating up to temperature and subsequent isothermal annealing. The bending of thin Mo foils under small loads was found to be an experimental arrangement, where variations in stress, in Ni-concentration and in intrinsic material properties could be realized. The results of these creep experiments will be compared in a qualitative sense with sintering experiments in Mo-Ni done under similar conditions as the creep experiments

  13. Structure-activity relations for Ni-containing zeolites during NO reduction. II. Role of the chemical state of Ni

    Mosqueda Jimenez, B.I.; Jentys, A.; Seshan, Kulathuiyer; Lercher, J.A.

    2003-01-01

    The influence of the metal in Ni-containing zeolites used as catalysts for the reduction of NO with propane and propene was studied. In the fresh catalysts, Ni is located in ion exchange positions for Ni/MOR, Ni/ZSM-5, and Ni/MCM-22. The formation of carbonaceous deposits, the removal of Al from

  14. Ni-P/Zn-Ni compositionally modulated multilayer coatings - Part 2: Corrosion and protection mechanisms

    Bahadormanesh, Behrouz; Ghorbani, Mohammad

    2018-06-01

    The Ni-P/Zn-Ni compositionally modulated multilayer coatings CMMCs were electrodeposited from a single bath by switching the deposition current density. The corrosion resistance of the deposits was studied and compared with that of monolayers of Ni-P and Zn-Ni alloys via Tafel polarization, EIS and salt spray tests. Characterization of corrosion products by means of EDS and XRD revealed more details from the corrosion mechanism of the monolayers and multilayers. The corrosion current density of Ni-P/Zn-Ni CMMCs were around one tenth of Zn-Ni monolayer. The CMMC with incomplete layers performed lower polarization resistance and higher corrosion current density compared to the CMMC with complete layers. The electrical circuit that was proposed for modeling the corrosion process based on the EIS spectrum, proved that layering reduces the porosity and consequently improves the barrier properties. Although, layering of Zn-Ni layers with Ni-P deposits increased the time to red rust in salt spray test, the time for white rust formation decreased. The corrosion mechanism of both Zn-Ni and Ni-P (containing small amount of Zn) was preferential dissolution of Zn and the corrosion products were comprised of mainly Zn hydroxychloride and Zn hydroxycarbonate. Also, Ni and P did not take part in the corrosion products. Based on the electrochemical character of the layers and the morphology of the corroded surface, the corrosion mechanism of multilayers was discussed.

  15. Joining of Ni-TiC FGM and Ni-Al Intermetallics by Centrifugal Combustion Synthesis

    Ohmi, Tatsuya; Matsuura, Kiyotaka; Iguchi, Manabu; Mizuma, Kiminori

    2008-01-01

    A centrifugal combustion synthesis (CCS) process has been investigated to join a Ni-Al intermetallic compound and a Ni-TiC cermet. The cermet, a tubular graphite mold, and a green compact of reactants consisting of Al, Ni and NiO were set in a centrifugal caster. When the combustion synthesis reaction was induced in the centrifugal force field, a synthesized molten Ni-Al alloy flowed into the graphite mold and joined to the cermet. The soundness of the joint interface depended on the volume percentage of TiC phase in the cermet. A lot of defects were formed near the interface between the Ni-TiC cermet and the cast Ni-Al alloy when the volume percentage of TiC was 50% or higher. For this kind of cermet system, using a functionally graded cermet such as Ni-10 vol.%TiC/Ni-25 vol.%TiC/Ni-50 vol.%TiC overcame this difficulty. The four-point bending strength of the joined specimen consisting of the three-layered FGM cermet and cast Ni-29 mol%Al alloy was 1010 MPa which is close to the result for a Ni-29 mol%Al alloy specimen

  16. Dynamic recovery in nanocrystalline Ni

    Sun, Z.; Van Petegem, S.; Cervellino, A.; Durst, K.; Blum, W.; Van Swygenhoven, H.

    2015-01-01

    The constant flow stress reached during uniaxial deformation of electrodeposited nanocrystalline Ni reflects a quasi-stationary balance between dislocation slip and grain boundary (GB) accommodation mechanisms. Stress reduction tests allow to suppress dislocation slip and bring recovery mechanisms into the foreground. When combined with in situ X-ray diffraction it can be shown that grain boundary recovery mechanisms play an important role in producing plastic strain while hardening the microstructure. This result has a significant consequence for the parameters of thermally activated glide of dislocations, such as athermal stress and activation volume, which are traditionally derived from stress/strain rate change tests

  17. Morphological control of Ni/NiO core/shell nanoparticles and production of hollow NiO nanostructures

    Chopra, Nitin; Claypoole, Leslie; Bachas, Leonidas G.

    2010-01-01

    Chemical synthesis coupled with a microwave irradiation process allowed for the control of size (6-40 nm), shape, and shell thickness of Ni/NiO core/shell nanoparticles. In this unique synthetic route, the size of Ni nanoparticles (NiNPs) was strongly influenced by the nickel salt-to-stabilizer ratio and the amount of the stabilizer. Interestingly, it was observed that the shape of the nanoparticles was altered by varying the reaction time, where longer reaction times resulted in annealing effects and rupture of the stabilizer micelle leading to distinct shapes of Ni/NiO core/shell nanostructures. Product cooling rate was another important parameter identified in this study that not only affected the shape, but also the crystal structure of the core/shell nanoparticles. In addition, a simple and cost-effective method of microwave irradiation of NiNPs led to the formation of distinctly shaped hollow NiO nanoparticles. These high surface area core/shell nanoparticles with well-controlled morphologies are important and can lead to significant advancement in the design of improved fuel cells, electrochromic display devices, and catalysis systems.

  18. Morphological control of Ni/NiO core/shell nanoparticles and production of hollow NiO nanostructures

    Chopra, Nitin [University of Alabama, Department of Metallurgical and Materials Engineering, Center for Materials for Information Technology (MINT) (United States); Claypoole, Leslie [Fairmont State University (United States); Bachas, Leonidas G., E-mail: bachas@uky.ed [University of Kentucky, Department of Chemistry (United States)

    2010-10-15

    Chemical synthesis coupled with a microwave irradiation process allowed for the control of size (6-40 nm), shape, and shell thickness of Ni/NiO core/shell nanoparticles. In this unique synthetic route, the size of Ni nanoparticles (NiNPs) was strongly influenced by the nickel salt-to-stabilizer ratio and the amount of the stabilizer. Interestingly, it was observed that the shape of the nanoparticles was altered by varying the reaction time, where longer reaction times resulted in annealing effects and rupture of the stabilizer micelle leading to distinct shapes of Ni/NiO core/shell nanostructures. Product cooling rate was another important parameter identified in this study that not only affected the shape, but also the crystal structure of the core/shell nanoparticles. In addition, a simple and cost-effective method of microwave irradiation of NiNPs led to the formation of distinctly shaped hollow NiO nanoparticles. These high surface area core/shell nanoparticles with well-controlled morphologies are important and can lead to significant advancement in the design of improved fuel cells, electrochromic display devices, and catalysis systems.

  19. Continuum mechanics simulations of NiO/Ni-YSZ composites during reduction and re-oxidation

    Pihlatie, Mikko; Frandsen, Henrik Lund; Kaiser, Andreas

    2010-01-01

    for the dimensional change arises from the volumetric change related to the phase change NiO ↔ Ni. The measurable change in bulk length is given by the ceramic YSZ backbone as a response to the stress created by the chemical strain. The different subprocesses described in the model for YSZ were elastic and anelastic...... expansion, diffusional creep, grain boundary sliding (GBS) and microcracking due to excessive stress. In the Ni/NiO phase, nonelastic strains in terms of diffusional and power law creep were implemented, and additionally for NiO deformation due to microcracking and/or pseudoplasticity. Semi...

  20. Niños y niñas como cuidadores familiares

    María Rosa Estupiñán Aponte

    2015-01-01

    En el contexto familiar, el cuidado de otra persona por parte de niños y niñas constituye un terreno inexplorado tanto en su significado como en las implicaciones que podrían darse en el proceso. Aunque históricamente se ha asignado el cuidado familiar a las mujeres generando condiciones de inequidad, incrementada con los cambios sociales de los últimos tiempos, es necesario reconocer que en muchos hogares niños y niñas se han visto obligados a desempeñar esta labor sin la preparación ni las ...

  1. .';.:NI~

    al wat ons werd was. Na middagete op 29 Junie, is ek per kar suid om die grand te gaan besigtig en om te sien hoe my stellings, van die vyandelike oogpunt, daaruit .... van Gatt se optrede moes die. Nieu-Seelanders, in 'n briljante nagaanval, met gevelde bajonette, 'n weg baan deur die vyand am daardie nag te ontvlug.

  2. Water dissociation on Ni(100) and Ni(111): Effect of surface temperature on reactivity

    Seenivasan, H.; Tiwari, Ashwani K.

    2013-01-01

    Water adsorption and dissociation on Ni(100) and Ni(111) surfaces are studied using density functional theory calculations. Water adsorbs on top site on both the surfaces, while H and OH adsorb on four fold hollow and three fold hollow (fcc) sites on Ni(100) and Ni(111), respectively. Transition states (TS) on both surfaces are identified using climbing image-nudged elastic band method. It is found that the barrier to dissociation on Ni(100) surface is slightly lower than that on Ni(111) surface. Dissociation on both the surfaces is exothermic, while the exothermicity on Ni(100) is large. To study the effect of lattice motion on the energy barrier, TS calculations are performed for various values of Q (lattice atom coordinate along the surface normal) and the change in the barrier height and position is determined. Calculations show that the energy barrier to reaction decreases with increasing Q and increases with decreasing Q on both the surfaces. Dissociation probability values at different surface temperatures are computed using semi-classical approximation. Results show that the influence of surface temperature on dissociation probability on the Ni(100) is significantly larger compared to that of Ni(111). Moreover, on Ni(100), a dramatic shift in energy barrier to lower incident energy values is observed with increasing surface temperature, while the shift is smaller in the case of Ni(111)

  3. Creatividad en niños superdotados

    González Román, María del Pilar

    1992-01-01

    Se ha realizado un estudio sobre la creatividad en los niños superdotados. Analizándose los diferentes modelos de creatividad y superdotacion avalados por un estudio empírico, en el cual se han valorado las diferencial que existen entre los niños superdotados y contraste a nivel verbal y grafico-espacial.

  4. Preparation of one-step NiO/Ni-CGO composites using factorial design

    Araujo, A.J.M. de; Sousa, A R.O. de; Camposa, L.F.A.; Macedo, D.A.; Loureiro, F. J.A.; Fagg, D.P.

    2016-01-01

    This work deals with the synthesis, processing and characterization of NiO/Ni- CGO composite materials as potential solid oxide fuel cell (SOFC) anodes. The particulate materials were obtained by a one-step synthesis method and characterized by thermal analysis (prior to calcination) and X-ray diffraction (calcined powder). The ceramic processing of samples containing from 30 to 70 wt.% NiO was carried out by factorial design. Besides the NiO content controlled during the chemical synthesis, the impacts of the pore-former content (citric acid, used in proportions of 0, 7.5 and 15 wt.%) and the sintering temperature (1300, 1350 and 1400 °C) were also investigated. The open porosity of NiO-CGO composites and reduced Ni-CGO cermets was modeled as a function of factors (NiO content, citric acid content and sintering temperature) and interaction of factors. (author)

  5. Nanoscale structural heterogeneity in Ni-rich half-Heusler TiNiSn

    Douglas, Jason E.; Pollock, Tresa M.; Chater, Philip A.; Brown, Craig M.; Seshadri, Ram

    2014-01-01

    The structural implications of excess Ni in the TiNiSn half-Heusler compound are examined through a combination of synchrotron x-ray and neutron scattering studies, in conjunction with first principles density functional theory calculations on supercells. Despite the phase diagram suggesting that TiNiSn is a line compound with no solid solution, for small x in TiNi 1+x Sn there is indeed an appearance—from careful analysis of the scattering—of some solubility, with the excess Ni occupying the interstitial tetrahedral site in the half-Heusler structure. The analysis performed here would point to the excess Ni not being statistically distributed, but rather occurring as coherent nanoclusters. First principles calculations of energetics, carried out using supercells, support a scenario of Ni interstitials clustering, rather than a statistical distribution.

  6. Microstructural evolution of Ni40Zr60 alloy during early stage of mechanical alloying of intermetallic compounds NiZr2 and Ni11Zr9

    Lee Peeyew; Koch, C.C.

    1994-01-01

    The microstructural change of Ni 40 Zr 60 alloy during mechanical alloying of mixtures of the intermetallic compounds NiZr 2 and Ni 11 Zr 9 has been studied by transmission electron microscopy. A specific ''cauliflower'' phase was formed during early stage of mechanical alloying process. It is suggested that the solid state reaction between intermetallic compounds NiZr 2 and Ni 11 Zr 9 is not the only origin for the formation of the ''cauliflower'' phase. ((orig.))

  7. Microstructure and tribological properties of NiMo/Mo2Ni3Si intermetallic 'in-situ' composites

    Gui Yongliang; Song Chunyan; Yang Li; Qin Xiaoling

    2011-01-01

    Research highlights: → Wear resistant NiMo/Mo 2 Ni 3 Si intermetallic 'in-situ' composites was fabricated successfully with Mo-Ni-Si powder blends as the starting materials. Microstructure of the NiMo/Mo 2 Ni 3 Si composites consists of Mo 2 Ni 3 Si primary dendrites, binary intermetallic phase NiMo and small amount of Ni/NiMo eutectics structure. The NiMo/Mo 2 Ni 3 Si composites exhibited high hardness and outstanding tribological properties under room-temperature dry-sliding wear test conditions which were attributed to the covalent-dominant strong atomic bonds and excellent combination of strength and ductility and toughness. - Abstract: Wear resistant NiMo/Mo 2 Ni 3 Si intermetallic 'in-situ' composites with a microstructure of ternary metal silicide Mo 2 Ni 3 Si primary dendritic, the long strip-like NiMo intermetallic phase, and a small amount of Ni/NiMo eutectics structure were designed and fabricated using molybdenum, nickel and silicon elemental powders. Friction and wear properties of NiMo/Mo 2 Ni 3 Si composites were evaluated under different contact load at room-temperature dry-sliding wear test conditions. Microstructure, worn surface morphologies and subsurface microstructure were characterized by OM, XRD, SEM and EDS. Results indicate that NiMo/Mo 2 Ni 3 Si composites have low fiction coefficient, excellent wear resistance and sluggish wear-load dependence. The dominant wear mechanisms of NiMo/Mo 2 Ni 3 Si composites are soft abrasion and slightly superficial oxidative wear.

  8. Fundamental cooperation project in fiscal 2000 for improving international energy consumption efficiency. Investigations in relation with prevention of global warming (analytical comparison centering around cost effectiveness related to greenhouse effect gas (GHG) reduction in overseas countries); 2000 nendo kokusai energy shohi koritsu ka chosa nado kyoryoku kiso jigyo - chikyu ondanka boshi kanren chosa hokokusho. Kaigai deno GHG sakugen ni kansuru hiyo tai koka wo chushin to shita bunseki hikaku

    NONE

    2001-03-01

    In order to provide discussion materials for measures to achieve the GHG emission reduction target, investigations and discussions have been made on the following subjects: cost effectiveness of reducing GHG emission by target countries and target technologies, use of maps and databases on the possible reduction quantity of GHG emission, the targeted countries and business categories. Regarding the target countries, investigations were made on the general situation of the energy consumption efficiency, difference between their energy consumption efficiency by industries and that in Japan, and the GHG emission quantities by sectors. As a result, 31 counties hopeful in reducing CO2 emission were selected. With regard to technologies to reduce CO2 emission, technologies having been practically used and proliferated in Japan were used as the base, whereas 43 technologies were systematized for such departments as industries, business operations, households, and transportation. According to a trial calculation on the effect of CO2 emission reduction, if the 43 technologies are applied to the 31 target countries, CO2 emission reduction of 698 million tons as a whole would be possible, for which the required expense was calculated as 114.4 trillion yen. In evaluating the CO2 emission reducing technologies, the cost effectiveness of each technology was evaluated by cost per GHG emission reduction of 1t-CO2. (NEDO)

  9. Fiscal 1996 project on the modeling for effective energy consumption in developing countries under a consignment from NEDO. Recent on the results of the demonstrative study on scrap preheater of electric furnace in the iron making process (for public); 1996 nendo hatten tojokoku energy shohi koritsuka model jigyo Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Seitetsu katei ni okeru denkiro no genryo yonetsu sochi ni kakawaru jissho kenkyu seika hokokusho (kokaiyo)

    NONE

    1997-03-01

    Indonesia is the biggest iron steel producing country in the ASEAN countries. Most of the production is produced by the electric furnace method in which iron steel scrap is used as a material. However, an energy saving measure in this method, the electric furnace scrap preheater using flue gas, has not yet been spread on a full scale. This R and D is aimed at developing jointly with Indonesia an electric furnace scrap preheater for medium/small size electric furnaces which are adoptable to the present iron making situation in Indonesia and installing it to the electric furnace of the iron making plant in Indonesia for a demonstrative study on energy saving, etc. Spread/expansion of the electric furnace scrap preheater which is an excellent energy saving system targeted expansion of energy saving technology not only of Indonesia, but of ASEAN countries and Japan. In this fiscal year, remodeling of part of the system was made by change of flue gas flow for increasing the energy saving effect, and at the same time, a research study was made of a scrap reheater effective as a total system. Moreover, the paper investigated technical data/information in Japan and overseas. 3 figs., 9 tabs.

  10. Nonenzymatic Glucose Sensor Based on In Situ Reduction of Ni/NiO-Graphene Nanocomposite

    Xiaohui Zhang

    2016-10-01

    Full Text Available Ni/NiO nanoflower modified reduced graphene oxide (rGO nanocomposite (Ni/NiO-rGO was introduced to screen printed electrode (SPE for the construction of a nonenzymatic electrochemical glucose biosensor. The Ni/NiO-rGO nanocomposite was synthesized by an in situ reduction process. Graphene oxide (GO hybrid Nafion sheets first chemical adsorbed Ni ions and assembled on the SPE. Subsequently, GO and Ni ions were reduced by hydrazine hydrate. The electrochemical properties of such a Ni/NiO-rGO modified SPE were carefully investigated. It showed a high activity for electrocatalytic oxidation of glucose in alkaline medium. The proposed nonenzymatic sensor can be utilized for quantification of glucose with a wide linear range from 29.9 μM to 6.44 mM (R = 0.9937 with a low detection limit of 1.8 μM (S/N = 3 and a high sensitivity of 1997 μA/mM∙cm−2. It also exhibited good reproducibility as well as high selectivity.

  11. Enthalpy of mixing of liquid Ni-Zr and Cu-Ni-Zr alloys

    Witusiewicz, V.T.; Sommer, F.

    2000-01-01

    Since the Al-Cu-Ni-Zr system is a basis for the production of bulk amorphous materials by rapid solidification techniques from the liquid state, it is of great scientific interest to determine the partial and the integral thermodynamic functions of liquid and undercooled liquid alloys. Such data, as was pointed out previously, are important in order to understand their extremely good glass-forming ability in multicomponent metallic systems as well as for processing improvements. In order to measure the thermodynamic properties of the Al-Cu-Ni-Zr quaternary, it is necessary to have reliable thermochemical data for its constituent canaries and ternaries first. In a series of articles, the authors have reported in detail the thermodynamic properties of liquid Al-Cu, Al-Ni, Cu-Ni, Cu-Zr, Al-Zr, Al-Cu-Ni, and Al-Cu-Zr alloys. This article deals with the direct calorimetric measurements of the partial and the integral enthalpies of mixing of liquid Ni-Zr and Cu-Ni-Zr alloys and the heat capacity of liquid Ni 26 Zr 74 . In a subsequent article, the authors will present similar data for the liquid ternary Al-Ni-Zr and for the liquid quaternary Al-Cu-Ni-Zr alloys

  12. The Ni-YSZ interface

    Jensen, Karin Vels

    The anode/electrolyte interface in solid oxide fuel cells (SOFC) is known to cause electrical losses. Geometrically simple Ni/yttria-stabilised zirconia (YSZ) interfaces were examined to gain information on the structural and chemical changes occurring during experiments at 1000°C in an atmosphere...... of 97% H2/3% H2O. Electrochemical impedance spectroscopy at open circuit voltage (OCV) and at anodic and cathodic polarisations (100 mV) was performed. A correlation of the electrical data with the structure development and the chemical composition was attempted. Nickel wires with different impurity...... between polarised and non-polarised samples. With pure nickel wires, however, the microstructures depended on the polarisation/non-polarisation conditions. At non-polarised conditions a hill and valley type structure was found. Anodic polarisation produced an up to 1 μm thick interface layer consisting...

  13. Study of the central collisions in the reactions Ni + Al and Ni + Ni at 28 A.MeV; Etude des collisions centrales dans les reactions Ni + Al et Ni + Ni a 28 A.MeV

    Lebreton, L.

    1995-12-01

    The work is in characterisation of mechanisms in the energy range of onset of multifragmentation (excitation energy of composed nucleus around 4 - 5 AMeV). This work focused on an experiment performed at the SARA facility, in Grenoble, using the AMPHORA multi detection array. I have been particularly interested in central collisions in the Ni + Al and Ni + Ni systems. The possibility to detect complete events for Ni + Al, and quasi-complete events for the Ni + Ni case, is the reason of this choice. Furthermore Ni + Ni presents the interest of a symmetrical system, for which the excitation energy per nucleon is maximum. The study of these reactions has been focused on the quasi-complete events (events for which at least 80 % of the total charge has been detected). Heavy ions produced in peripheral collisions are very likely emitted along the beam line or stopped in the plastic detectors, energy thresholds are too high for the quasi-target products detection, consequently by requiring complete or quasi-complete measurement of the total charge, we are able to detect mostly central events. The knowledge of informations like charge, energy or detection angles allows to isolate the source(s) and to reconstruct the size and the excitation energy of the source(s). Comparisons with simulations like sequential emission (GEMINI code), very deep inelastic collision or instantaneous emission (Berliner code) allows to characterise the first stage of the collision (binary collisions or central collisions) and the type of deexcitation of the source(s). Some calculations was also performed with the statistical model code MODGAN. Indeed azimuthal correlations seem to be a good tool in getting more information about involved reaction mechanisms. Comparisons with MODGAN provide information about angular momentum of the source and time delay between emissions of the two particles (separation between sequential or instantaneous process). (author). 69 refs.

  14. Electrochemical preparation and characteristics of Ni-Co-LaNi{sub 5} composite coatings as electrode materials for hydrogen evolution

    Wu Gang; Li Ning; Dai Changsong; Zhou Derui

    2004-02-15

    Electrocatalytic activity for the hydrogen evolution reaction on Ni-Co-LaNi{sub 5} composite electrodes prepared by electrochemical codeposition technique was evaluated. The relationship between the current density for hydrogen evolution reaction and the amount of LaNi{sub 5} particles in Ni-Co baths is like the well-known 'volcano plot'. The Surface morphology and microstructure of Ni-Co-LaNi{sub 5} coatings were determined by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). The kinetic parameters were determined from electrochemical steady-state Tafel polarization and electrochemical impedance spectroscopy technology in 1 M NaOH solution. The values obtained for the apparent energies of activation are 32.48, 46.29 and 57.03 kJ mol{sup -1} for the Ni-Co-LaNi{sub 5}, Ni-Co and Ni electrodes, respectively. The hydrogen evolution reaction on Ni-Co-LaNi{sub 5} proceeds via Volmer-Tafel reaction route with the mixed rate determining characteristics. The composite coating Ni-Co-LaNi{sub 5} is catalytically more active than Ni and Ni-Co electrodes due to the increase in its real surface areas and the decrease in the apparent free energy of activation caused by the electrocatalytic synergistic effect of the Ni-Co alloys and the hydrogen storage intermetallic particles on the electrode surface.

  15. Electrochemical preparation and characteristics of Ni-Co-LaNi5 composite coatings as electrode materials for hydrogen evolution

    Wu Gang; Li Ning; Dai Changsong; Zhou Derui

    2004-01-01

    Electrocatalytic activity for the hydrogen evolution reaction on Ni-Co-LaNi 5 composite electrodes prepared by electrochemical codeposition technique was evaluated. The relationship between the current density for hydrogen evolution reaction and the amount of LaNi 5 particles in Ni-Co baths is like the well-known 'volcano plot'. The Surface morphology and microstructure of Ni-Co-LaNi 5 coatings were determined by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). The kinetic parameters were determined from electrochemical steady-state Tafel polarization and electrochemical impedance spectroscopy technology in 1 M NaOH solution. The values obtained for the apparent energies of activation are 32.48, 46.29 and 57.03 kJ mol -1 for the Ni-Co-LaNi 5 , Ni-Co and Ni electrodes, respectively. The hydrogen evolution reaction on Ni-Co-LaNi 5 proceeds via Volmer-Tafel reaction route with the mixed rate determining characteristics. The composite coating Ni-Co-LaNi 5 is catalytically more active than Ni and Ni-Co electrodes due to the increase in its real surface areas and the decrease in the apparent free energy of activation caused by the electrocatalytic synergistic effect of the Ni-Co alloys and the hydrogen storage intermetallic particles on the electrode surface

  16. Synthesis of Supported NiPt Bimetallic Nanoparticles, Methods for Controlling the Surface Coverage of Ni Nanoparticles With Pt, Methods Of Making NiPt Multilayer Core-Shell Structures and Application of the Supported Catalysts for CO2 Reforming

    Li, Lidong; Anjum, Dalaver H.; Zhou, Lu; Laveille, Paco; Basset, Jean-Marie

    2015-01-01

    Embodiments of the present disclosure provide for supported Ni/Pt bimetallic nanoparticles, compositions including supported NiPt nanoparticles, methods of making supported NiPt nanoparticles, methods of using supported NiPt nanoparticles

  17. Synthesis of Supported NiPt Bimetallic Nanoparticles, Methods for Controlling the Surface Coverage of Ni Nanoparticles With Pt, Methods Of Making NiPt Multilayer Core-Shell Structures and Application of the Supported Catalysts for CO2 Reforming

    Li, Lidong

    2015-06-25

    Embodiments of the present disclosure provide for supported Ni/Pt bimetallic nanoparticles, compositions including supported NiPt nanoparticles, methods of making supported NiPt nanoparticles, methods of using supported NiPt nanoparticles, and the like.

  18. Growth of single-crystal W whiskers during humid H2/N2 reduction of Ni, Fe-Ni, and Co-Ni doped tungsten oxide

    Wang Shiliang; He Yuehui; Zou Jou; Wang Yong; Huang Han

    2009-01-01

    Numbers of W whiskers were obtained by reducing Ni, Ni-Fe, and Ni-Co doped tungsten oxide in a mixed atmosphere of humid H 2 and N 2 . The phases and morphologies of the reduction products were characterized by XRD and SEM. Intensive TEM and EDS analyses showed that the obtained whiskers were W single crystals which typical have alloyed particles (Ni-W, Fe-Ni, or Co-Ni-W) at the growth tips. The formed W whiskers were presumed to be induced by the alloyed particles. Our experimental results revealed that, during the reduction process of tungsten oxide, the pre-reduced Ni, Fe-Ni, or Co-Ni particles not only served as nucleation aids for the initial growth of W phase from W oxide but also played the roles of catalysts during the reductive decomposition of gaseous WO 2 (OH) 2 .

  19. Exchange bias variations of the seed and top NiFe layers in NiFe/FeMn/NiFe trilayer as a function of seed layer thickness

    Sankaranarayanan, V.K.; Yoon, S.M.; Kim, C.G.; Kim, C.O.

    2005-01-01

    Development of exchange bias at the seed and top NiFe layers in the NiFe (t nm)/FeMn(10 nm)/NiFe(5 nm) trilayer structure is investigated as a function of seed layer thickness, in the range of 2-20 nm. The seed NiFe layer shows maximum exchange bias at 4 nm seed layer thickness. The bias shows inverse thickness dependence with increasing thickness. The top NiFe layer on the other hand shows only half the bias of the seed layer which is retained even after the sharp fall in seed layer bias. The much smaller bias for the top NiFe layer is related to the difference in crystalline texture and spin orientations at the top FeMn/NiFe interface, in comparison to the bottom NiFe/FeMn interface which grows on a saturated NiFe layer with (1 1 1) orientation

  20. An Ultrastable and High-Performance Flexible Fiber-Shaped Ni-Zn Battery based on a Ni-NiO Heterostructured Nanosheet Cathode.

    Zeng, Yinxiang; Meng, Yue; Lai, Zhengzhe; Zhang, Xiyue; Yu, Minghao; Fang, Pingping; Wu, Mingmei; Tong, Yexiang; Lu, Xihong

    2017-11-01

    Currently, the main bottleneck for the widespread application of Ni-Zn batteries is their poor cycling stability as a result of the irreversibility of the Ni-based cathode and dendrite formation of the Zn anode during the charging-discharging processes. Herein, a highly rechargeable, flexible, fiber-shaped Ni-Zn battery with impressive electrochemical performance is rationally demonstrated by employing Ni-NiO heterostructured nanosheets as the cathode. Benefiting from the improved conductivity and enhanced electroactivity of the Ni-NiO heterojunction nanosheet cathode, the as-fabricated fiber-shaped Ni-NiO//Zn battery displays high capacity and admirable rate capability. More importantly, this Ni-NiO//Zn battery shows unprecedented cyclic durability both in aqueous (96.6% capacity retention after 10 000 cycles) and polymer (almost no capacity attenuation after 10 000 cycles at 22.2 A g -1 ) electrolytes. Moreover, a peak energy density of 6.6 µWh cm -2 , together with a remarkable power density of 20.2 mW cm -2 , is achieved by the flexible quasi-solid-state fiber-shaped Ni-NiO//Zn battery, outperforming most reported fiber-shaped energy-storage devices. Such a novel concept of a fiber-shaped Ni-Zn battery with impressive stability will greatly enrich the flexible energy-storage technologies for future portable/wearable electronic applications. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Synthesis of a novel Au nanoparticles decorated Ni-MOF/Ni/NiO nanocomposite and electrocatalytic performance for the detection of glucose in human serum.

    Chen, Jingyuan; Xu, Qin; Shu, Yun; Hu, Xiaoya

    2018-07-01

    A nonenzymatic glucose electrochemical sensor was constructed based on Au nanoparticles (AuNPs) decorated Ni metal-organic-framework (MOF)/Ni/NiO nanocomposite. Ni-MOF/Ni/NiO nanocomposite was synthesized by one-step calcination of Ni-MOF. Then AuNPs were loaded onto the Ni-based nanocomposites' surface through electrostatic adsorption. Through characterization by transmission electron microscopy (TEM), high resolution TEM (HRTEM) and energy disperse spectroscopy (EDS) mapping, it is found that the AuNPs were well distributed on the surface of Ni-based nanocomposite. Cyclic voltammetric (CV) study showed the electrocatalytic activity of Au-Ni nanocomposite was highly improved after loading AuNPs onto it. Amperometric study demonstrated that the Au-Ni nanocomposites modified glassy carbon electrode (GCE) exhibited a high sensitivity of 2133.5 mA M -1 cm -2 and a wide linear range (0.4-900 μM) toward the oxidation of glucose with a detection limit as low as 0.1 μM. Moreover, the reproducibility, selectivity and stability of the sensor all exhibited outstanding performance. We applied the as-fabricated high performance sensor to measure the glucose levels in human serum and obtained satisfactory results. It is believed that AuNPs decorated Ni MOF/Ni/NiO nanocomposite provides a new platform for developing highly performance electrochemical sensors in practical applications. Copyright © 2018 Elsevier B.V. All rights reserved.

  2. Ni antagelser om Situationel Dialektisk Videnskabsteori

    Dakwar, Julia Rytter; Lorentzen, Anne-Christine Rosfeldt; Smedegaard, Flemming

    2017-01-01

    I artiklen præsenteres et præliminært bud på en Situationel Dialektisk Videnskabsteori (SDV) i form af ni antagelser. Situationel, fordi antagelserne ikke er statiske, men alle overvejelser og valg under de enkelte antagelser er afhængige af situationen. Dialektisk, fordi alle ni antagelser...... opererer med dialektiske modsætninger, og alle videnskabsteoretiske valg ses som valg på kontinua. De ni antagelser, som bliver præsenteret og diskuteret i artiklen, er: Antagelse 1: Teori og praksis fordrer hinanden Antagelse 2: Del og helhed hænger sammen Antagelse 3: Forbundne sagsforhold påvirker...

  3. New developments in Ni/Ti multilayers

    Anderson, I; Hoghoj, P [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France)

    1997-04-01

    It is now 20 years since super-mirrors were first used as a neutron optical element. Since then the field of multilayer neutron-optics has matured with multilayers finding their way to application in many neutron scattering instruments. However, there is still room for progress in terms of multilayer quality, performance and application. Along with work on multilayers for neutron polarisation Ni/Ti super-mirrors have been optimised. The state-of-the-art Ni/Ti super-mirror performance and the results obtained in two neutron-optics applications of Ni/Ti multilayers are presented. (author).

  4. Site occupancy of Fe in ternary Ni 75-x

    The results of a detailed structural and magnetic study clearly indicate that regardless of the thermal history of the samples, Fe has a strong preference for the Ni sites in Ni-poor (non-stoichiometric) Ni75Al25 alloys. Fe substitution has a profound effect on the nature of magnetism in Ni75Al25.

  5. Reduction of a Ni/Spinel Catalyst for Methane Reforming

    Kehres, Jan; Andreasen, Jens Wenzel; Fløystad, Jostein Bø

    2015-01-01

    microscopy (HRTEM) was performed on the fresh catalyst sample. The Ni particles in the fresh catalyst sample were observed to exhibit a Ni/NiO core/shell structure. A decrease of the Ni lattice parameter is observed during the reduction in a temperature interval from 413 – 453 K, which can be related...

  6. Influence of Ni Solute segregation on the intrinsic growth stresses in Cu(Ni) thin films

    Kaub, T.M.; Felfer, P.; Cairney, J.M.; Thompson, G.B.

    2016-01-01

    Using intrinsic solute segregation in alloys, the compressive stress in a series of Cu(Ni) thin films has been studied. The highest compressive stress was noted in the 5 at.% Ni alloy, with increasing Ni concentration resulting in a subsequent reduction of stress. Atom probe tomography quantified Ni's Gibbsian interfacial excess in the grain boundaries and confirmed that once grain boundary saturation is achieved, the compressive stress was reduced. This letter provides experimental support in elucidating how interfacial segregation of excess adatoms contributes to the post-coalescence compressive stress generation mechanism in thin films. - Graphical abstract: Cu(Ni) film stress relationship with Ni additions. Atom probe characterization confirms solute enrichment in the boundaries, which was linked to stress response.

  7. NiCo-lead zirconium titanate-NiCo trilayered magnetoelectric composites prepared by electroless deposition

    Zhou, M. H.; Wang, Y. G.; Bi, K.; Fan, H. P.; Zhao, Z. S.

    2015-01-01

    The NiCo layers with various Ni/Co atomic ratio have been successfully electroless deposited on PZT layers by varying the bath composition. As the cobalt atomic ratio in the deposited layer increases from 17.2 to 54.8 wt%, the magnetostrictive coefficient decreases. The magnetoelectric effect depends strongly on the magnetostrictive properties of magnetostrictive phase. The magnetoelectric coefficient of NiCo/PZT/NiCo trilayers increases with Ni/Co atomic ratio of the deposited NiCo layers increasing from 45:55 to 83:17. A maximum ME voltage coefficient of α E,31 = 2.8 V ⋅ cm −1 ⋅ Oe −1 is obtained at a frequency of about 88 kHz, which makes these trilayers suitable for applications in actuators, transducers and sensors

  8. NiCo-lead zirconium titanate-NiCo trilayered magnetoelectric composites prepared by electroless deposition

    Zhou, M. H.; Wang, Y. G.; Bi, K., E-mail: bike@bupt.edu.cn [State Key Laboratory of Information Photonics and Optical Communications and School of Science, Beijing University of Posts and Telecommunications, Beijing 100876 (China); Fan, H. P. [School of Mechanical and Electrical Engineering, Qingdao Technological University Qindao College, Qingdao 266106 (China); Zhao, Z. S. [Shandong Engineering Consulting Institute, Jinan 250013 (China)

    2015-04-15

    The NiCo layers with various Ni/Co atomic ratio have been successfully electroless deposited on PZT layers by varying the bath composition. As the cobalt atomic ratio in the deposited layer increases from 17.2 to 54.8 wt%, the magnetostrictive coefficient decreases. The magnetoelectric effect depends strongly on the magnetostrictive properties of magnetostrictive phase. The magnetoelectric coefficient of NiCo/PZT/NiCo trilayers increases with Ni/Co atomic ratio of the deposited NiCo layers increasing from 45:55 to 83:17. A maximum ME voltage coefficient of α{sub E,31} = 2.8 V ⋅ cm{sup −1} ⋅ Oe{sup −1} is obtained at a frequency of about 88 kHz, which makes these trilayers suitable for applications in actuators, transducers and sensors.

  9. Fe-solubility of Ni7S6 and Ni9S8: Thermodynamic analysis

    Waldner, P.

    2011-01-01

    Experimental data on phase equilibria have been used for thermodynamic analysis of the iron solubility of the nickel sulfides Ni 7 S 6 and Ni 9 S 8 . For both compounds, a two-sublattice approach within the framework of the compound energy formalism has been applied to perform Gibbs free energy modelling at 0.1 MPa total pressure consistently embedded in recent thermodynamic assessment studies of other iron-nickel-sulfides. The predicted maxima of iron solubility around 3 at% of Ni 7 S 6 and 5.5 at% of Ni 9 S 8 are confirmed by experimental data. The calculations of complex ternary phase relations with Fe-bearing Ni 7 S 6 and Ni 9 S 8 gain further improvement. The first internally consistent description of all thermodynamically stable phases known in the literature for the iron-nickel-sulfur system is completed.

  10. Phase stability and magnetism in NiPt and NiPd alloys

    Paudyal, Durga; Mookerjee, Abhijit

    2004-01-01

    We show that the differences in stability of 3d-5d NiPt and 3d-4d NiPd alloys arise mainly due to relativistic corrections. The magnetic properties of disordered NiPd and NiPt alloys also differ due to these corrections, which lead to increase in the separation between the s-d bands of 5d elements in these alloys. For the magnetic case we also analyse the results in terms of splitting of majority and minority spin d band centres of the 3d elements. We further examine the effect of relativistic corrections to the pair energies and order-disorder transition temperatures in these alloys. The magnetic moments and Curie temperatures have also been studied along with the short range ordering/segregation effects in NiPt/NiPd alloys

  11. Precipitation of Ni4Ti3-variants in a polycrystalline Ni-rich NiTi shape memory alloy

    Bojda, Ondřej; Eggeler, G.; Dlouhý, Antonín

    2005-01-01

    Roč. 53, č. 1 (2005), s. 99-104 ISSN 1359-6462 R&D Projects: GA ČR(CZ) GA106/05/0918 Institutional research plan: CEZ:AV0Z20410507 Keywords : NiTi shape memory alloys * Ni4Ti3 precipitation * Transmission electron microscopy Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.228, year: 2005

  12. Ni-Ni ion pair excitation transfer in D sub(3h) symmetry

    Terrile, M.C.

    1990-01-01

    The mechanisms contributing to excitation transfer are examined for Ni-Ni ion pairs in order to explain the delocalized character of electronic excitations observed in CsNiF sub(3). Using both first-and second-order perturbation theory and from symmetry arguments, the kind of interactions giving matrix elements between states connecting different sites for the position of the excitation are discussed. (author)

  13. Electronic structure of graphene on Ni surfaces with different orientation

    Pudikov, D.A.; Zhizhin, E.V.; Rybkin, A.G.; Rybkina, A.A.; Zhukov, Y.M.; Vilkov, O. Yu.; Shikin, A.M.

    2016-01-01

    An experimental study of the graphene, synthesized by propylene cracking on Ni surfaces with different orientation: (100) and (111), using angle-resolved photoemission, has been performed. It has been shown that graphene on Ni(111) had a perfect lateral structure due to consistency of their lattices, whereas graphene/Ni(100) consisted of a lot of domains. For both systems electronic structure was quite similar and demonstrated a strong bonding of graphene to the underlying Ni surface. After Au intercalation the electronic structure of graphene in both systems was shifted to the Fermi level and became linear in the vicinity of the K point of the Brillouin zone. - Highlights: • Graphene on Ni(111) is well-ordered, whereas on Ni(100) – multi-domain. • Graphene on Ni(111) and Ni(100) is strongly bonded with substrate. • Intercalation of Au atoms restores the linearity in dispersion and makes graphene quasi-free on both Ni(100) and Ni(111).

  14. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    Kabir, L.; Mandal, A.R. [Department of Physics, Visva-Bharati, Santiniketan-731 235 (India); Mandal, S.K., E-mail: sk_mandal@hotmail.co [Department of Physics, Visva-Bharati, Santiniketan-731 235 (India)

    2010-04-15

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni{sup 2+} clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni{sup 2+} clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  15. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    Kabir, L.; Mandal, A. R.; Mandal, S. K.

    2010-04-01

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni 2+ clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni 2+ clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  16. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    Kabir, L.; Mandal, A.R.; Mandal, S.K.

    2010-01-01

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni 2+ clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni 2+ clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  17. Modeling and simulation of NiO dissolution and Ni deposition in molten carbonate fuel cells

    Nam, Suk Woo; Choi, Hyung-Joon; Lim, Tae Hoon [Korea Institute of Science & Technology, Seoul (Korea, Republic of)] [and others

    1996-12-31

    Dissolution of NiO cathode into the electrolyte matrix is an important phenomena limiting the lifetime of molten carbonate fuel cell (MCFC). The dissolved nickel diffuses into the matrix and is reduced by dissolved hydrogen leading to the formation of metallic nickel films in the pores of the matrix. The growth of Ni films in the electrolyte matrix during the continuous cell operation results eventually in shorting between cathode and anode. Various mathematical and empirical models have been developed to describe the NiO dissolution and Ni deposition processes, and these models have some success in estimating the lifetime of MCFC by correlating the amount of Ni deposited in the matrix with shorting time. Since the exact mechanism of Ni deposition was not well understood, deposition reaction was assumed to be very fast in most of the models and the Ni deposition region was limited around a point in the matrix. In fact, formation of Ni films takes place in a rather broad region in the matrix, the location and thickness of the film depending on operating conditions as well as matrix properties. In this study, we assumed simple reaction kinetics for Ni deposition and developed a mathematical model to get the distribution of nickel in the matrix.

  18. Layering and temperature-dependent magnetization and anisotropy of naturally produced Ni/NiO multilayers

    Pappas, S. D.; Trachylis, D.; Velgakis, M. J. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Kapaklis, V.; Joensson, P. E.; Papaioannou, E. Th. [Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden); Delimitis, A. [Chemical Process Engineering Research Institute (CPERI), Centre for Research and Technology Hellas (CERTH), 57001 Thermi, Thessaloniki (Greece); Poulopoulos, P. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Institut fuer Experimentalphysik, Freie Universitaet Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Materials Science Department, University of Patras, 26504 Patras (Greece); Fumagalli, P. [Institut fuer Experimentalphysik, Freie Universitaet Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Politis, C. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Department of Materials Science and Engineering, University of Texas at Arlington, Arlington, Texas 76019 (United States)

    2012-09-01

    Ni/NiO multilayers were grown by magnetron sputtering at room temperature, with the aid of the natural oxidation procedure. That is, at the end of the deposition of each single Ni layer, air is let to flow into the vacuum chamber through a leak valve. Then, a very thin NiO layer ({approx}1.2 nm) is formed. Simulated x-ray reflectivity patterns reveal that layering is excellent for individual Ni-layer thickness larger than 2.5 nm, which is attributed to the intercalation of amorphous NiO between the polycrystalline Ni layers. The magnetization of the films, measured at temperatures 5-300 K, has almost bulk-like value, whereas the films exhibit a trend to perpendicular magnetic anisotropy (PMA) with an unusual significant positive interface anisotropy contribution, which presents a weak temperature dependence. The power-law behavior of the multilayers indicates a non-negligible contribution of higher order anisotropies in the uniaxial anisotropy. Bloch-law fittings for the temperature dependence of the magnetization in the spin-wave regime show that the magnetization in the multilayers decreases faster as a function of temperature than the one of bulk Ni. Finally, when the individual Ni-layer thickness decreases below 2 nm, the multilayer stacking vanishes, resulting in a dramatic decrease of the interface magnetic anisotropy and consequently in a decrease of the perpendicular magnetic anisotropy.

  19. XRD studies on solid state amorphisation in electroless Ni/P and Ni/B deposits

    Sampath Kumar, P.; Kesavan Nair, P.

    1996-01-01

    The decomposition of electroless Ni-P and Ni-B deposits on annealing at various temperature is studied using x-ray diffraction techniques employing profile deconvolution and line profile analysis. It appears that solid state amorphisation takes place in the Ni-B deposits in a narrow temperature range just prior to the onset of crystallization of amorphous phase. In the case of Ni-P deposits no evidence for solid state amorphisation could be obtained. Thermodynamic and kinetic considerations also support such a conclusion

  20. Ni adsorption and Ni-Al LDH precipitation in a sandy aquifer: An experimental and mechanistic modeling study

    Regelink, I.C.; Temminghoff, E.J.M.

    2011-01-01

    Mining activities and industries have created nickel (Ni) contaminations in many parts of the world. The objective of this study is to increase our understanding of Ni adsorption and Nickel-Aluminium Layered Double Hydroxide (Ni-Al LDH) precipitation to reduce Ni mobility in a sandy soil aquifer. At

  1. Core/shell AgNi/PtAgNi nanoparticles as methanol-tolerant oxygen reduction electrocatalysts

    Wu, Dengfeng; Cheng, Daojian

    2015-01-01

    A core/shell AgNi/PtAgNi nanoparticle (NP) was synthesized via a new seed-mediated growth method in organic solvent medium. The as-synthesized AgNi/PtAgNiNP exhibits an AgNi core coated with PtAgNi shell, which was confirmed by transmission electron microscopy (TEM), ultraviolet–visible absorption spectroscopy and X-ray Photoelectron Spectroscopy (XPS). The AgNi/PtAgNiNPs/C catalyst possesses higher oxygen reduction reaction (ORR) activity and better durability compared with the commercial Pt/C catalyst. It is found that the ORR polarization curve of the AgNi/PtAgNiNPs/C catalyst shows an onset potential of 0.91 V vs. RHE, which is superior to the commercial Pt/C (0.88 V vs. RHE). In addition, the AgNi/PtAgNiNPs/C catalyst shows much better durability than the commercial Pt/C catalyst. More interestingly, the AgNi/PtAgNiNPs/C catalyst displays much higher methanol tolerance than the commercial Pt/C catalyst in 0.1 M KOH solution in the presence of 0.5 M methanol. Our results show that core/shell AgNi/PtAgNiNPs possess selective activity for ORR even in the presence of methanol, showing potential application as methanol-tolerant cathode catalysts in direct methanol fuel cells.

  2. Grain boundaries in Ni3Al. 2

    Kung, H.; Sass, S.L.

    1992-01-01

    This paper discusses the dislocation structure of small angle tilt and twist boundaries in ordered Ni 3 Al, with and without boron, investigated using transmission electron microscopy. Dislocation with Burgers vectors that correspond to anti-phase boundary (APB)-coupled superpartials were found in small angle twist boundaries in both boron-free and boron-doped Ni 3 Al, and a small angle tilt boundary in boron-doped Ni 3 Al. The boundary structures are in agreement with theoretical models proposed by Marcinkowski and co-workers. The APB energy determined from the dissociation of the grain boundary dislocations was lower than values reported for isolated APBs in Ni 3 Al. For small angle twist boundaries the presence of boron reduced the APB energy at the interface until it approached zero. This is consistent with the structure of these boundaries containing small regions of increased compositional disorder in the first atomic plane next to the interface

  3. Ni-ZrB2 electrocomposites

    Pushpavanam, M.; Natarajan, S.R.

    1992-01-01

    New generation materials require high temperature oxidation resistance besides many other tribological properties. Ni-ZrB 2 composites and their properties are dealt with in this paper. (author). 7 refs., 3 figs., 4 tabs

  4. Not in Traffic Surveillance (NiTS)

    Department of Transportation — The Not-in-Traffic Surveillance (NiTS) system is a virtual data collection system designed to provide counts and details regarding fatalities and injuries that occur...

  5. Niños y Violencia

    International Child Development Centre

    1997-01-01

    Este Innocenti Digest explora la violencia de los niños y hacia los niños, usando el marco de la Convención de los Derechos del Niño de las Naciones Unidas. Se centra en la violencia interpersonal, tanto intrafamiliar como extrafamiliar. Se incluye el abuso sexual y la explotación ya que a pesar de no implicar obligatoriamente violencia o coerción, la mayor parte de la evidencia demuestra su efectos dañinos tanto físicos como psicológicos. También se discute la implicación de los niños en los...

  6. Collision strengths for transitions in Ni XIX

    4l configurations of Ni XIX, for which flexible atomic code. (FAC) has been ... atomic data (namely energy levels, radiative rates, collision strengths, excitation rates, etc.) ... Zhang and Sampson, who adopted the Coulomb–Born-exchange.

  7. Root morphology of Ni-treated plants

    Leskova, A.; Fargasova, A.; Giehl, R. F. H.; Wiren, N. von

    2015-01-01

    Plant roots are very important organs in terms of nutrient and water acquisition but they also serve as anchorages for the aboveground parts of the plants. The roots display extraordinary plasticity towards stress conditions as a result of integration of environmental cues into the developmental processes of the roots. Our aim was to investigate the root morphology of Arabidopsis thaliana plants exposed to a particular stress condition, excess Ni supply. We aimed to find out which cellular processes - cell division, elongation and differentiation are affected by Ni, thereby explaining the seen root phenotype. Our results reveal that a distinct sensitivity exists between roots of different order and interference with various cellular processes is responsible for the effects of Ni on roots. We also show that Ni-treated roots have several auxin-related phenotypes. (authors)

  8. Density and Structure Analysis of Molten Ni-W Alloys

    Feng XIAO; Liang FANG

    2004-01-01

    Density of molten Ni and Ni-W alloys was measured in the temperature range of 1773~1873 K with a sessile drop method.The density of molten Ni and Ni-W alloys trends to decrease with increasing temperature. The density and molar volume of the alloys trend to increase with increasing W concentration in the alloys. The calculation result shows an ideal mixing of Ni-W alloys.

  9. Fe-Cr-Ni system alloys

    Levin, F.L.

    1986-01-01

    Phase diagram of Fe-Cr-Ni system, which is the basic one for production of corrosion resistant alloys, is considered. Data on corrosion resistance of such alloys are correlated depending on a number of factors: quality and composition of modifying elements, corrosion medium, temperature, alloy structure, mechanical and thermal treatment. Grades of Fe-Ni-Cr alloys are presented, and fields of their application are pointed out

  10. Synthesis of Ni3Ta, Ni2Ta and NiTa by high-energy ball milling and subsequent heat treatment

    Benites, H.S.N.; Silva, B.P da; Ramos, A.S.; Silva, A.A.A.P.; Coelho, G.C.; Lima, B.B. de

    2014-01-01

    The tantalum has relevance for the development of multicomponent Ni-based superalloys which are hardened by solid solution and precipitation mechanisms. Master alloys are normally used in the production step in order to produce refractory metals and alloys. The present work reports on the synthesis of Ni_3Ta, Ni_2Ta and NiTa by high-energy ball milling and subsequent heat treatment. The elemental Ni-25Ta, Ni-33Ta and Ni-50Ta (at.-%) powder mixtures were ball milled under Ar atmosphere using stainless steel balls and vials, 300 rpm and a ball-to-powder weight ratio of 10:1. Following, the as-milled samples were uniaxially compacted and heat-treated at 1100 deg C for 4h under Ar atmosphere. The characterization of as-milled and heat-treated samples was conducted by means of X-ray diffraction, scanning electron microscopy, and energy dispersive spectrometry. A large amount of Ni_3Ta, Ni_2Ta and NiTa was formed in the mechanically alloyed heat-treated Ni-25Ta, Ni-33Ta and Ni-50Ta alloys. (author)

  11. Structural Investigation of Fe-Ni-S and Fe-Ni-Si Melts by High-temperature Fluorescence XAFS Measurements

    Manghnani, Murli H.; Balogh, John; Hong Xinguo; Newville, Matthew; Amulele, G.

    2007-01-01

    Iron-nickel (Fe-Ni) alloy is regarded as the most abundant constituent of Earth's core, with an amount of 5.5 wt% Ni in the core based on geochemical and cosmochemical models. The structural role of nickel in liquid Fe-Ni alloys with light elements such as S or Si is poorly understood, largely because of the experimental difficulties of high-temperature melts. Recently, we have succeeded in acquiring Ni K-edge fluorescence x-ray absorption fine structure (XAFS) spectra of Fe-Ni-S and Fe-Ni-Si melts and alloys. Different structural environment of Ni atoms in Fe-Ni-S and Fe-Ni-Si melts is observed, supporting the effect of light elements in Fe-Ni melts

  12. The complex transfer reaction (14C, 15O) on Ni, Zn and Ge targets: existence and mass of 69Ni

    Dessagne, P.; Bernas, M.; Langevin, M.; Pougheon, F.; Roussel, P.; Morrison, G.C.

    1984-01-01

    The ( 14 C, 15 O) complex transfer reaction has been studied at 72 MeV incident energy on 58 Ni, 60 Ni, 62 Ni, 64 Ni, 68 Zn, 70 Zn and 74 Ge, 76 Ge targets. Spectra and differential cross sections have been measured in a 5 0 angular range centred around a laboratory angle of 6 0 . The nucleus 69 Ni has been observed and its mass determined for the first time

  13. Electroless Ni-P/Ni-B duplex coatings: preparation and evaluation of microhardness, wear and corrosion resistance

    Narayanan, T.S.N. Sankara; Krishnaveni, K.; Seshadri, S.K.

    2003-01-01

    The present work deals with the formation of Ni-P/Ni-B duplex coatings by electroless plating process and evaluation of their hardness, wear resistance and corrosion resistance. The Ni-P/Ni-B duplex coatings were prepared using dual baths (acidic hypophosphite- and alkaline borohydride-reduced electroless nickel baths) with both Ni-P and Ni-B as inner layers and with varying single layer thickness. Scanning electron microscopy (SEM) was used to assess the duplex interface. The microhardness, wear resistance and corrosion resistance of electroless nickel duplex coatings were compared with electroless Ni-P and Ni-B coatings of similar thickness. The study reveals that the Ni-P and Ni-B coatings are amorphous in their as-plated condition and upon heat-treatment at 450 deg. C for 1 h, both Ni-P and Ni-B coatings crystallize and produce nickel, nickel phosphide and nickel borides in the respective coatings. All the three phases are formed when Ni-P/Ni-B and Ni-B/Ni-P duplex coatings are heat-treated at 450 deg. C for 1 h. The duplex coatings are uniform and the compatibility between the layers is good. The microhardness, wear resistance and corrosion resistance of the duplex coating is higher than Ni-P and Ni-B coatings of similar thickness. Among the two types of duplex coatings studied, hardness and wear resistance is higher for coatings having Ni-B coating as the outer layer whereas better corrosion resistance is offered by coatings having Ni-P coating as the outer layer

  14. Heavy metal environmental impact. Nickel (Ni); Impatto ambientale da metalli pesanti. Il Nichel (Ni)

    Bressa, G. [Padua Univ. Padua (Italy). Dipt. di Farmacologia, Lab. di Tossicologia

    2001-02-01

    Nickel (Ni) is a heavy metal in over 3.000 different alloys used to produce kitchen utensils, batteries, coins, etc.. Human extractive and industrial activities are therefore a cause for environmental dispersion of this metal into the biosphere. This shows how in urban areas car traffic and house-heating are the main sources of nickel pollution. Nickel is relatively non-toxic, such as iron, cobalt, copper and zinc; nevertheless prolonged inhalation of dust containing such compounds as Ni O or NiCl{sub 2} concurs in the outbreak of respiratory pathologies. The carcinogenic effect of such compounds as Ni S, Ni O and Ni(CO){sub 4} has been confirmed by experiments on laboratory animals. Ni potentially toxic concentrations, and as a consequence of potential environmental impact, are to be mainly found in populated areas where the main sources are represented by industries and landfills. [Italian] Il nichel (Ni) e' un metallo presente in oltre 3.000 differenti leghe che vengono utilizzate per la produzione di utensili da cucina, batterie, monete, ecc.. Le attivita' estrattive ed industriali dell'uomo sono quindi causa di una dispersione del metallo nella biosfera. Sono stati riscontrati elevati tassi di Ni nell'atmosfera di aree urbane. Cio' sta a dimostrare che nelle aree urbane il traffico automobilistico e il riscaldamento domestico sono le fonti principali di inquinamento da tale metallo. Il nichel e' relativamente atossico, analogamente a ferro, cobalto, rame e zinco, tuttavia l'inalazione protratta di polveri contenenti composti come il NiO o il NiCl{sub 2} contribuisce al manifestarsi di patologie dell'apparato respiratorio. E' stato confermato sperimentalmente su animali da laboratorio l'effetto cancerogeno di alcuni composti quali NiS, NiO e Ni(CO){sub 4}. Concentrazioni potenzialmente tossiche di Ni, e quindi di probabile impatto ambientale, sono maggiormente da ricercare nelle zone antropizzate dove le fonti

  15. Ultrathin NiO/NiFe2O4 Nanoplates Decorated Graphene Nanosheets with Enhanced Lithium Storage Properties

    Du, Dejian; Yue, Wenbo; Fan, Xialu; Tang, Kun; Yang, Xiaojing

    2016-01-01

    Highlights: • Ultrathin NiO/NiFe 2 O 4 nanoplates derived from NiFe layered double hydroxides are fabricated on the graphene. • NiO/NiFe 2 O 4 nanoplates on the graphene show superior electrochemical performance compared to pure NiO/NiFe 2 O 4 aggregates. • The effects of the content and the particle size/component of NiO/NiFe 2 O 4 on the electrochemical performances are studied. • Graphene-encapsulated NiO/NiFe 2 O 4 is prepared and shows slightly decreased performance compared to graphene-based composite. - Abstract: As anode materials for lithium-ion batteries, bicomponent metal oxide composites show high reversible capacities; but the morphology and particle size of the composites are hardly controllable, which may reduce their electrochemical properties. In this work, ultrathin NiO/NiFe 2 O 4 nanoplates with a diameter of 5 ∼ 7 nm and a thickness of ∼2 nm are controllably fabricated on the graphene derived from NiFe layered double hydroxides (NiFe-LDHs), and exhibit superior electrochemical performance compared to pure NiO/NiFe 2 O 4 aggregates without graphene. The nanosized NiO and NiFe 2 O 4 plates are separated from each other and the graphene substrate can prevent the aggregation of NiO/NiFe 2 O 4 as well as enhance the electronic conductivity of the composite, which is beneficial to improving the electrochemical performance. Moreover, the effects of the content and the particle size/component of NiO/NiFe 2 O 4 on the electrochemical performances are also studied in order to achieve optimal performance. Ultrathin NiO/NiFe 2 O 4 nanoplates are further encapsulated by graphene nanosheets and show slightly decreased performance compared to those supported by graphene nanosheets. The different electrochemical behaviors of graphene-containing composites may be attributed to the different interactions between graphene nanosheets and NiO/NiFe 2 O 4 nanoplates.

  16. Investigation into the MgF2-NiF2, CaF2-NiF2, SrF2-NiF2 systems

    Ikrami, D.D.; Petrov, S.V.; Fedorov, P.P.; Ol'khovaya, L.A.; Luginina, A.A.; AN SSSR, Moscow. Inst. Fizicheskikh Problem; AN SSSR, Moscow. Inst. Kristallografii)

    1984-01-01

    Using the methods of differential thermal and X-ray phase analyses the systems MgF 2 -NiF 2 , CaF 2 -NiF 2 , SrF 2 -NiF 2 have been studied. In the system SrF 2 -NiF 2 the only orthorhombic compounds SrNiF 4 (a=14.43; b=3.93; c=5.66 (+-0.01 A)) is formed. SrNiF 4 density constitutes: dsub(X-ray)=4.60+-0.01 g/cm 3 , dsub(exp.)=4.60+-0.03 g/cm 3 . Refraction indices are as follows SrNiF 4 :Ng=1.500; Nsub(m)=1.497; Nsub(p)=1.479. SrNiF 4 magnetic ordering temperature Tsub(N) approximately 100 K

  17. Microstructure and mechanical properties of sputter deposited Ni/Ni{sub 3}Al multilayer films at elevated temperature

    Zhang, Chao [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Feng, Kai, E-mail: fengkai@sjtu.edu.cn [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Li, Zhuguo, E-mail: lizg@sjtu.edu.cn [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Lu, Fenggui; Huang, Jian; Wu, Yixiong [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China)

    2016-08-15

    Highlights: • Ni/Ni{sub 3}Al multilayers are prepared by magnetron sputtering. • Both grain size and phase constitution of annealed Ni/Ni{sub 3}Al multilayers are dependent on individual layer thickness. • The hardness of annealed Ni/Ni{sub 3}Al multilayers varies with individual layer thickness and annealing temperature. • 40 nm Ni/Ni{sub 3}Al multilayer exhibits excellent hardness at elevated temperature. - Abstract: Nano-structured Ni/Ni{sub 3}Al multilayer was prepared by magnetron sputtering, with individual layer thicknesses h varying from 10 to 160 nm. The microstructure and hardness of Ni/Ni{sub 3}Al multilayer were investigated by X-ray diffraction, transmission electron microscopy and nanoindentation. The results show that the hardness increases with decreasing h for as-deposited and 500 °C annealed multilayers. When annealed at 700 °C, the hardness approach a peak value at h = 40 nm with followed by softening at smaller h. The influence of individual layer thickness, grain size as well as formation of ordered Ni{sub 3}Al on strengthening mechanisms of Ni/Ni{sub 3}Al multilayers at elevated temperature are discussed.

  18. Enhanced Electrocatalytic Activity for Water Splitting on NiO/Ni/Carbon Fiber Paper

    Ruoyu Zhang

    2016-12-01

    Full Text Available Large-scale growth of low-cost, efficient, and durable non-noble metal-based electrocatalysts for water splitting is crucial for future renewable energy systems. Atomic layer deposition (ALD provides a promising route for depositing uniform thin coatings of electrocatalysts, which are useful in many technologies, including the splitting of water. In this communication, we report the growth of a NiO/Ni catalyst directly on carbon fiber paper by atomic layer deposition and report subsequent reduction and oxidation annealing treatments. The 10–20 nm NiO/Ni nanoparticle catalysts can reach a current density of 10 mA·cm−2 at an overpotential of 189 mV for hydrogen evolution reactions and 257 mV for oxygen evolution reactions with high stability. We further successfully achieved a water splitting current density of 10 mA·cm−2 at 1.78 V using a typical NiO/Ni coated carbon fiber paper two-electrode setup. The results suggest that nanoparticulate NiO/Ni is an active, stable, and noble-metal-free electrocatalyst, which facilitates a method for future water splitting applications.

  19. Ni(salen): a system that forms many solvates with interacting Ni atoms

    Siegler, M.A.M.; Lutz, M.

    2009-01-01

    Recrystallization of [N,N’-Ethylene-bis(salicylideneiminato)]-nickel(II) [Ni(salen)] has been carried out from a large selection of solvents. Crystals can be either solvent free or solvates. This study is based on X-ray crystal structure determinations, which include the redetermination of Ni(salen)

  20. Thermal stability of electrodeposited Ni and Ni-Co layers; an EBSD-study

    Rasmussen, Anette Alsted; Gholinia, A.; Trimby, P.W.

    2004-01-01

    The influence of heat treatment on the microstructure and the microtexture of electrodeposited Ni and Ni-Co layers was investigated with Electron Backscatter Diffraction (EBSD) with high resolution. Samples were annealed for 1 hour at 523 K and 673 K, the temperature region wherein...

  1. The role of Ni in sulfided carbon-supported Ni-Mo hydrodesulfurization catalysts

    Bouwens, S.M.A.M.; Barthe-Zahir, N.; Beer, de V.H.J.; Prins, R.

    1991-01-01

    The thiophene hydrodesulfurization activities of Ni and Ni---Mo sulfide catalysts supported on activated carbon were measured at atmospheric pressure and the catalyst structures were studied by means of X-ray photoelectron spectroscopy, dynamic oxygen chemisorption, and chemical sulfur analysis. The

  2. Mechanical properties of NiO/Ni-YSZ composites depending on temperature, porosity and redox cycling

    Pihlatie, Mikko; Kaiser, Andreas; Mogensen, Mogens Bjerg

    2009-01-01

    The Impulse Excitation Technique (IET) was used to determine the elastic modulus and specific damping of different Ni/NiO-YSZ composites suitable for use in solid oxide fuel cells (SOFC). The porosity of the as-sintered samples varied from 9 to 38% and that of the reduced ones from 31 to 52%. For...

  3. Climate Prediction Center - El Niño/La Niña Home

    Weather Service NWS logo - Click to go to the NWS home page Climate Prediction Center Site Map News Information CPC Web Team HOME > El Niño/La Niña Forecasts Current U.S. Climate Outlook SST Forecasts Temperature and Anomalies NOAA/ National Weather Service National Centers for Environmental Prediction Climate

  4. Synthesis and magnetic properties of multilayer Ni/Cu and NiFe/Cu ...

    The diameter of wires can be easily varied by pore size of alumina, ranging ... saturated HgCl2 solution to remove the remaining Al, and then dipped in 5 wt% ... for NiFe alloy it is 1.3 V, that is higher than for Ni/Cu nanowires to diminish Cu.

  5. Effect of solute atoms on swelling in Ni alloys and pure Ni under He + ion irradiation

    Wakai, E.; Ezawa, T.; Imamura, J.; Takenaka, T.; Tanabe, T.; Oshima, R.

    2002-12-01

    The effects of solute atoms on microstructural evolutions have been investigated using Ni alloys under 25 keV He + irradiation at 500 °C. The specimens used were pure Ni, Ni-Si, Ni-Co, Ni-Cu, Ni-Mn and Ni-Pd alloys with different volume size factors. The high number densities of dislocation loops about 1.5×10 22 m -3 were formed in the specimens irradiated to 1×10 19 ions/m 2, and they were approximately equivalent, except for Ni-Si. The mean size of loops tended to increase with the volume size factor of solute atoms. In a dose of 4×10 20 ions/m 2, the swelling was changed from 0.2% to 4.5%, depending on the volume size factors. The number densities of bubbles tended to increase with the absolute values of the volume size factor, and the swelling increased with the volume size factors. This suggests that the mobility of helium and vacancy atoms may be influenced by the interaction of solute atoms with them.

  6. Bonding Strength of Ni/Ni3Al Interface with Different Lattice Misfit

    Ping PENG; Caixing ZHENG; Shaochang HAN; Zhaohui JIN; Rui YANG; Zhuangqi HU

    2003-01-01

    The interfacial binding covalent bond density (CBD) and the local environmental total bond order (LTBO) of the Ni/Ni3Alinterface with different lattice misfits (δ) were calculated by using first-principles discrete variation Xα method. It was foundthat

  7. Electrochemical Behaviour of Ni and Ni-PVC Electrodes for the Electroxidation of Ethanol

    Mohd Syafiq Hamdan; Norazzizi Nordin; Siti Fathrita Mohd Amir; Riyanto; Mohamed Rozali Othman

    2011-01-01

    In this study, two nickel based electrodes were prepared; nickel foil and nickel-polyvinylchloride (Ni-PVC), in order to study their electrochemical behavior using cyclic voltammetry, CV and chronocoulometry, CC. Ni electrode was prepared from Ni metal foil while Ni-PVC electrode was prepared by mixing a weighed portion of Ni powder and PVC in THF solvent, swirled until the suspension was homogeneous and drying the suspension in an oven at 50 degree Celsius for 3 h. The dry sample was then placed in a 1 cm diameter stainless steel mould and pressed at 10 ton/ cm 2 . From CV data, Ni-PVC electrode showed a better electrochemical behavior compared to Ni metal foil electrode. The use of Ni-PVC electrode at higher concentration of supporting electrolyte (1.0 M KOH) was better than at lower concentration of the same supporting electrolyte in electroxidation of ethanol. In addition to acetic acid, the oxidation of ethanol also produced ethyl acetate and acetaldehyde. (author)

  8. Room-temperature ferromagnetism in Dy films doped with Ni

    Edelman, I. [Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036 (Russian Federation)], E-mail: ise@iph.krasn.ru; Ovchinnikov, S. [Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036 (Russian Federation); Siberian Federal University, Av. Svobodnyi 71, Krasnoyarsk 660074 (Russian Federation); Markov, V.; Kosyrev, N.; Seredkin, V.; Khudjakov, A.; Bondarenko, G. [Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036 (Russian Federation); Kesler, V. [Institute of Semiconductor Physics, Siberian Division, Russian Academy of Sciences, Av. Akademika Lavrent' eva 13, Novosibirsk 630090 (Russian Federation)

    2008-09-01

    Temperature, magnetic field and spectral dependences of magneto-optical effects (MOEs) in bi-layer films Dy{sub (1-x)}Ni{sub x}-Ni and Dy{sub (1-x)}(NiFe){sub x}-NiFe were investigated, x changes from 0 to 0.06. Peculiar behavior of the MOEs was revealed at temperatures essentially exceeding the Curie temperature of bulk Dy which is explained by the magnetic ordering of the Dy layer containing Ni under the action of two factors: Ni impurities distributed homogeneously over the whole Dy layer and atomic contact of this layer with continues Ni layer. The mechanism of the magnetic ordering is suggested to be associated with the change of the density of states of the alloy Dy{sub (1-x)}Ni{sub x} owing to hybridization with narrow peaks near the Fermi level character for Ni.

  9. Room-temperature ferromagnetism in Dy films doped with Ni

    Edelman, I.; Ovchinnikov, S.; Markov, V.; Kosyrev, N.; Seredkin, V.; Khudjakov, A.; Bondarenko, G.; Kesler, V.

    2008-01-01

    Temperature, magnetic field and spectral dependences of magneto-optical effects (MOEs) in bi-layer films Dy (1-x) Ni x -Ni and Dy (1-x) (NiFe) x -NiFe were investigated, x changes from 0 to 0.06. Peculiar behavior of the MOEs was revealed at temperatures essentially exceeding the Curie temperature of bulk Dy which is explained by the magnetic ordering of the Dy layer containing Ni under the action of two factors: Ni impurities distributed homogeneously over the whole Dy layer and atomic contact of this layer with continues Ni layer. The mechanism of the magnetic ordering is suggested to be associated with the change of the density of states of the alloy Dy (1-x) Ni x owing to hybridization with narrow peaks near the Fermi level character for Ni

  10. Elementary martensitic transformation processes in Ni-rich NiTi single crystals with Ni4Ti3 precipitates

    Michutta, J.; Somsen, Ch.; Yawny, A.; Dlouhy, A.; Eggeler, G.

    2006-01-01

    The present study shows that multiple-step martensitic transformations can be observed in aged Ni-rich NiTi single crystals. Ageing of solution-annealed and water-quenched Ni-rich NiTi single crystals results in a homogeneous precipitation of coherent Ni 4 Ti 3 particles. When the interparticle spacing reaches a critical value (order of magnitude: 200 nm), three distinct transformation processes are observed on cooling from the high-temperature phase using differential scanning calorimetry and in situ transmission electron microscopy. The transformation sequence begins with the formation of R-phase starting from all precipitate/matrix interfaces (first step). The transformation continues with the formation of B19' and its subsequent growth along all precipitate/matrix interfaces (second step). Finally, the matrix in between the precipitates transforms to B19' (third step). Elementary transformation mechanisms which account for two- and three-step transformations in a system with small-scale microstructural heterogeneities were identified

  11. Probing the semi-magicity of $^{68}$Ni via the $^{3}$H($^{66}$Ni,$^{68}$Ni)p two-neutron transfer reaction in inverse kinematics

    Reiter, P; Blazhev, A A; Kruecken, R; Franchoo, S; Mertzimekis, T; Darby, I G; Van de walle, J; Raabe, R; Elseviers, J; Gernhaeuser, R A; Sorlin, O H; Georgiev, G P; Bree, N C F; Habs, D; Chapman, R; Gaudefroy, L; Diriken, J V J; Jenkins, D G; Kroell, T; Axiotis, M; Huyse, M L; Patronis, N

    We propose to perform the two-neutron transfer reaction $^{3}$H($^{66}$Ni, $^{68}$Ni)$p$ using the ISOLDE radioactive ion beam at 2.7 $A$ MeV and the MINIBALL + T-REX setup to characterize the 0$^{+}$ and 2$^{+}$ states in $^{68}$Ni.

  12. Mechanical alloying of the FeNi-Ag system

    Gonzalez, G.; Ibarra, D.; Ochoa, J.; Villalba, R.; Sagarzazu, A.

    2007-01-01

    The Fe-Ni-Ag system is of particular interest for its potential applications as soft magnetic granular material with small magnetic grains embedded in a non-magnetic metal matrix. Under equilibrium conditions: Fe-Ag and Ni-Ag are immiscible and Fe-Ni shows complete solubility. These materials are particularly important for magnetoresistivity properties. The properties of these alloys are closely related to their microstructure; therefore, a detailed study of the transformations occurring during milling was undertaken using pre-alloyed Fe x Ni 100-x (x = 30, 50 and 70) further milled with different Ag content to give the following alloys compositions (Fe x -Ni 100-x ) 100-y Ag y (y = 5, 20, 60). Consolidation of the mechanically alloyed powders by sintering at 950 o C was performed. Morphological and structural characterization of the sintered powders was carried out by scanning and transmission electron microscopy and X-ray diffraction. Fe 30 Ni 70 and Fe 50 Ni 50 formed ordered FeNi 3 compound. Fe 70 Ni 30 showed the formation of a mixture of γ-(Fe,Ni) and α-Fe(Ni) solid solutions. The mixture of these systems with Ag showed the metal solid solutions surrounded by Ag islands of Fe x Ni y -Ag, There was also evidence of Ag diffusing into the γ-(Fe,Ni). High Ag content (60%) shows formation of islands of FeNi surrounded by Ag. Sintering is always improved with the Ag content

  13. Effect of amount of glycine as fuel in obtaining nanocomposite Ni/NiO

    Simoes, A.N.; Simoes, V.N.; Neiva, L.S.; Quirino, M.R.; Vieira, D.A.; Gama, L.

    2010-01-01

    This paper proposes to investigate the effect of the amount of glycine in obtaining nanocomposite Ni/NiO synthesized by combustion reaction technique. The amount of glycine used was calculated on the stoichiometric composition of 50% and 100%. Characterizations by X-ray diffraction (XRD), N2 adsorption by the BET method and scanning electron microscopy (SEM) were performed with powder of Ni/NiO result. The analysis of X-ray diffraction showed the presence of crystalline NiO phase in the presence of nickel as a secondary phase, whose amount increased with the amount of glycine. Increasing the concentration of glycine also caused an increase in surface area, which ranged from 1.1 to 1.4 m 2 /g. The micrographs revealed the formation of soft agglomerates with porous appearance and easy dispersions. It can be concluded that the synthesis is effective to obtain nanosized powders. (author)

  14. Neutron enrichment at midrapidity in 58Ni + 58Ni at 52 MeV/u

    Theriault, D.; Vallee, A.; Gingras, L.; Larochelle, Y.; Roy, R.; April, A.; Beaulieu, L.; Grenier, F.; Lemieux, F.; Moisan, J.; Samri, M.; Saint-Pierre, C.; Turbide, S.; Yennello, S.J.; Martin, E.; Winchester, E.

    2003-01-01

    By combining data from a charged particle 58 Ni + 58 Ni experiment at 52 MeV/u with an 36 Ar + 58 Ni experiment at 50 MeV/u for which free neutrons have been detected, an increase in the neutron to proton ratio of the whole nuclear material at midrapidity has been experimentally observed in the reaction 58 Ni + 58 Ni at 52 MeV/u. The neutron to proton ratio is measured above the initial neutron to proton ratio of the system. Neutron to proton ratio of the quasi-projectile emission is analysed for the same reactions and is seen to decrease below the ratio of the initial system. (authors)

  15. Improvement of thermoelectric properties for half-Heusler TiNiSn by interstitial Ni defects

    Hazama, Hirofumi; Matsubara, Masato; Asahi, Ryoji; Takeuchi, Tsunehiro

    2011-01-01

    We have synthesized off-stoichiometric Ti-Ni-Sn half-Heusler thermoelectrics in order to investigate the relation between randomly distributed defects and thermoelectric properties. A small change in the composition of Ti-Ni-Sn causes a remarkable change in the thermal conductivity. An excess content of Ni realizes a low thermal conductivity of 2.93 W/mK at room temperature while keeping a high power factor. The low thermal conductivity originates in the defects generated by an excess content of Ni. To investigate the detailed defect structure, we have performed first-principles calculations and compared with x ray photoemission spectroscopy measurement. Based on these analyses, we conclude that the excess Ni atoms randomly occupy the vacant sites in the half-Heusler structure, which play as phonon scattering centers, resulting in significant improvement of the figure of merit without any substitutions of expensive heavy elements, such as Zr and Hf.

  16. Magnetoresistance of nanogranular Ni/NiO controlled by exchange anisotropy

    Del Bianco, L.; Spizzo, F.; Tamisari, M.; Allia, P.

    2013-01-01

    A link between exchange anisotropy and magnetoresistance has been found to occur in a Ni/NiO sample consisting of Ni nanocrystallites (mean size ∼13 nm, Ni content ∼33 vol%) dispersed in a NiO matrix. This material shows metallic-type electric conduction and isotropic spin-dependent magnetoresistance as well as exchange bias effect. The latter is the outcome of an exchange anisotropy arising from the contact interaction between the Ni phase and the NiO matrix. Combined analysis of magnetization M(H) and magnetoresistance MR(H) loops measured in the 5–250 K temperature range after zero-field-cooling (ZFC) and after field-cooling (FC) from 300 K reveals that the magnetoresistance is influenced by exchange anisotropy, which is triggered by the FC process and can be modified in strength by varying the temperature. Compared to the ZFC case, the exchange anisotropy produces a horizontal shift of the FC MR(H) loop along with a reduction of the MR response associated to the reorientation of the Ni moments. A strict connection between magnetoresistance and remanent magnetization of FC loops on one side and the exchange field on the other, ruled by exchange anisotropy, is indicated. - Highlights: • Nanogranular Ni/NiO with giant magnetoresistance (MR) and exchange bias effect. • Exchange anisotropy produces a shift of the field-cooled MR(H) loop and reduces MR. • MR, remanence of field-cooled loops and exchange field are three correlated quantities. • It is possible to control MR of nanogranular systems through the exchange anisotropy

  17. Ferromagnetic resonance study of sputtered NiFe/V/NiFe heterostructures

    Alayo, W., E-mail: willian.rodriguez@ufpel.edu.br [Departamento de Física – IFM, Universidade Federal de Pelotas, 96010-900 Rio Grande do Sul (Brazil); Pelegrini, F. [Instituto de Física, Universidade Federal de Goiás, Goiânia, 74001-970 (Brazil); Baggio-Saitovitch, E. [Centro Brasileiro de Pesquisas Físicas, Rio de Janeiro, RJ, 22290-180 (Brazil)

    2015-03-01

    The Ni{sub 81}Fe{sub 19}/V/Ni{sub 81}Fe{sub 19} heterostructures has been produced by magnetron sputtering and analyzed by ferromagnetic resonance. Two systems were investigated: the non symmetrical NiFe(50 Å)/V(t)/NiFe(30 Å) trilayers and the symmetrical NiFe(80 Å)/V(t)/NiFe(80 Å) trilayers, with variable ultrathin V thickness t. Ferromagnetic exchange coupling was evidenced for t below 10 Å by the excitation of the optic mode, in the case of the non symmetrical samples, and by the observation of a single resonance mode for the symmetrical trilayers. For larger V thickness, all samples exhibited two modes, which were attributed to the resonance of the individual NiFe layers with different effective magnetizations. The analysis with the equilibrium and resonance conditions provided the exchange coupling constants and effective magnetizations. - Highlights: • We present a study of symmetrical and non symmetrical NiFe/V/NiFe trilayers deposited on Si single crystals by ferromagnetic resonance (FMR) at room temperature. • For the non symmetrical trilayers, the FMR spectra show the optic and acoustic modes for samples with very thin V layer thicknesses, evidencing ferromagnetic exchange coupling, whereas, for larger V thickness, the spectra exhibited two well resolved modes associated to each independent NiFe layer. For the symmetrical trilayers, strong ferromagnetic exchange coupling is evidenced by the observation of a single resonance mode. • The analysis with the equilibrium condition and dispersion relation provides the exchange coupling constants and effective magnetizations.

  18. Hydrogen absorption kinetics and structural properties of Mg85Ni10Ca5 and Mg90Ni10

    Aoki, Masakazu; Saito, Katsushi; Towata, Shin-ichi

    2005-01-01

    Mg 85 Ni 10 Ca 5 and Mg 90 Ni 10 were prepared by melting mixtures of the elements in mild steel crucibles and pouring them into copper molds. Hydrogen absorption kinetics and structural properties of the alloys were characterized by the volumetric method using a Sievert's apparatus, X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The crystallite size of Mg in Mg 85 Ni 10 Ca 5 , which is evaluated by XRD peak broadening, is about 50% smaller than that in Mg 90 Ni 10 . In addition, the nanometer-scale structure composed of Mg, Mg 2 Ni, Mg 2 Ca was observed in Mg 85 Ni 10 Ca 5 . Mg 85 Ni 10 Ca 5 shows better hydrogen absorption kinetics than Mg 90 Ni 10 in the temperature range of room temperature to 573 K. The better absorption kinetics of Mg 85 Ni 10 Ca 5 is mainly attributed to the nanometer-scale structure

  19. Sputtering Yields of Si and Ni from the Ni1-xSix System Studied by Rutherford Backscattering Spectrometry

    Kim, Su Chol; Yamaguchi, Satoru; Kataoka, Yoshihide; Iwami, Motohiro; Hiraki, Akio; Satou, Mamoru; Fujimoto, Fuminori

    1982-01-01

    Sputtering yields of Si and Ni from thin layer films of Ni-Si compounds (Ni1-xSix), including the pure materials (Ni and Si), caused by 5 keV Ar+ ion bombardment were investigated using backscattering spectrometry. The sputtering yield for Si from Ni1-xSix increased with increasing Si concentration. However, there is an abrupt decrease in the yield for Si concentrations above NiSi2 to pure Si. This is in clear contrast to the sputtering yield of Ni from Ni1-xSix which increased with increasing Ni concentration monotonously. These results are discussed on the basis of both the difference in the atomic density and the electronic state of the alloy.

  20. Phase Equilibria of the Sn-Ni-Si Ternary System and Interfacial Reactions in Sn-(Cu)/Ni-Si Couples

    Fang, Gu; Chen, Chih-chi

    2015-07-01

    Interfacial reactions in Sn/Ni-4.5 wt.%Si and Sn-Cu/Ni-4.5 wt.%Si couples at 250°C, and Sn-Ni-Si ternary phase equilibria at 250°C were investigated in this study. Ni-Si alloys, which are nonmagnetic, can be regarded as a diffusion barrier layer material in flip chip packaging. Solder/Ni-4.5 wt.%Si interfacial reactions are crucial to the reliability of soldered joints. Phase equilibria information is essential for development of solder/Ni-Si materials. No ternary compound is present in the Sn-Ni-Si ternary system at 250°C. Extended solubility of Si in the phases Ni3Sn2 and Ni3Sn is 3.8 and 6.1 at.%, respectively. As more Si dissolves in these phases their lattice constants decrease. No noticeable ternary solubility is observed for the other intermetallics. Interfacial reactions in solder/Ni-4.5 wt.%Si are similar to those for solder/Ni. Si does not alter the reaction phases. No Si solubility in the reaction phases was detected, although rates of growth of the reaction phases were reduced. Because the alloy Ni-4.5 wt.%Si reacts more slowly with solders than pure Ni, the Ni-4.5 wt.%Si alloy could be a potential new diffusion barrier layer material for flip chip packaging.

  1. Ni/boride interfaces and environmental embrittlement in Ni-based superalloys: A first-principles study

    Sanyal, Suchismita; Waghmare, Umesh V.; Hanlon, Timothy; Hall, Ernest L.

    2011-01-01

    Highlights: ► Fracture strengths of Ni/boride interfaces through first-principles calculations. ► Fracture strengths of Ni/boride interfaces are higher than Ni/Ni 3 Al and NiΣ5 grain boundaries. ► Ni/boride interfaces have higher resistance to O-embrittlement than Ni/Ni 3 Al and NiΣ5 grain boundaries. ► CrMo-borides are more effective than Cr-borides in resisting O-embrittlement. ► Electronegativity differences between alloying elements correlate with fracture strengths. - Abstract: Motivated by the vital role played by boride precipitates in Ni-based superalloys in improving mechanical properties such as creep rupture strength, fatigue crack growth rates and improved resistance towards environmental embrittlement , we estimate fracture strength of Ni/boride interfaces through determination of their work of separation using first-principles simulations. We find that the fracture strength of Ni/boride interfaces is higher than that of other commonly occurring interfaces in Ni-alloys, such as Ni Σ-5 grain boundaries and coherent Ni/Ni 3 Al interfaces, and is less susceptible to oxygen-induced embrittlement. Our calculations show how the presence of Mo in Ni/M 5 B 3 (M = Cr, Mo) interfaces leads to additional reduction in oxygen-induced embrittlement. Through Electron-Localization-Function based analyses, we identify the electronic origins of effects of alloying elements on fracture strengths of these interfaces and observe that chemical interactions stemming from electronegativity differences between different atomic species are responsible for the trends in calculated strengths. Our findings should be useful towards designing Ni-based alloys with higher interfacial strengths and reduced oxygen-induced embrittlement.

  2. Nickel distribution and isotopic fractionation in a Brazilian lateritic regolith: Coupling Ni isotopes and Ni K-edge XANES

    Ratié, G.; Garnier, J.; Calmels, D.; Vantelon, D.; Guimarães, E.; Monvoisin, G.; Nouet, J.; Ponzevera, E.; Quantin, C.

    2018-06-01

    Ultramafic (UM) rocks are known to be nickel (Ni) rich and to weather quickly, which makes them a good candidate to look at the Ni isotope systematics during weathering processes at the Earth's surface. The present study aims at identifying the Ni solid speciation and discussing the weathering processes that produce Ni isotope fractionation in two deep laterite profiles under tropical conditions (Barro Alto, Goiás State, Brazil). While phyllosilicates and to a lower extent goethite are the main Ni-bearing phases in the saprolitic part of the profile, iron (Fe) oxides dominate the Ni budget in the lateritic unit. Nickel isotopic composition (δ60Ni values) has been measured in each unit of the regolith, i.e., rock, saprock, saprolite and laterite (n = 52). δ60Ni varies widely within the two laterite profiles, from -0.10 ± 0.05‰ to 1.43 ± 0.05‰, showing that significant Ni isotope fractionation occurs during the weathering of UM rocks. Overall, our results show that during weathering, the solid phase is depleted in heavy Ni isotopes due to the preferential sorption and incorporation of light Ni isotopes into Fe oxides; the same mechanisms likely apply to the incorporation of Ni into phyllosilicates (type 2:1). However, an isotopically heavy Ni pool is observed in the solid phase at the bottom of the saprolitic unit. This feature can be explained by two hypotheses that are not mutually exclusive: (i) a depletion in light Ni isotopes during the first stage of weathering due to the preferential dissolution of light Ni-containing minerals, and (ii) the sorption or incorporation of isotopically heavy Ni carried by percolating waters (groundwater samples have δ60Ni of 2.20 and 2.27‰), that were enriched in heavy Ni isotopes due to successive weathering processes in the overlying soil and laterite units.

  3. The acceleration intermediate phase (NiS and Ni3S2) evolution by nanocrystallization in Li/NiS2 thermal batteries with high specific capacity

    Jin, Chuanyu; Zhou, Lingping; Fu, Licai; Zhu, Jiajun; Li, Deyi; Yang, Wulin

    2017-06-01

    The intermediate phase of NiS2 is thought to be a bottleneck currently to improve the overall performance of Li/NiS2 thermal batteries because of its low conductivity and close formation enthalpy between NiS2 and the intermediate phase (NiS, Ni3S2, etc). For improving the discharge performances of Li/NiS2 thermal batteries, the nano NiS2 with an average size of 85 ± 5 nm is designated as a cathode material. The electrochemical measurements show that the specific capacity of nano NiS2 cathode is higher than micro NiS2. The nano NiS2 cathode exhibits excellent electrochemical performances with high specific capacities of 794 and 654 mAh g-1 at current density of 0.1 and 0.5 A cm-2 under a cut-off voltage of 0.5 V, respectively. These results show that the rapid intermediate phase evolution from the nanocrystallization can obviously enhance use efficiency of NiS2 and improve discharge performances of thermal batteries.

  4. Room temperature isotherms for Mo and Ni

    Masse, J.L.

    1986-11-01

    Isotherms at room temperature for Mo and Ni are proposed. They are of three types: BIRCH, KEANE and BORN-MIE. The adjustable constants appearing in these isotherms have been determined from experimental quantities at zero pressure. An evaluation of the limit of (δB T /δP) T as P #-> # ∞, where B T is the isothermal bulk modulus, has been also used. These three isotherms obtained for Mo and Ni are compared with isotherms derived from shock-wave data according to the PRIETO's model. There is a good agreement between these and these derived from shock-wave data. The three isotherms proposed for Mo and Ni can be considered as valid until pressures of several B To , where B To is the bulk modulus B T at P = o [fr

  5. Advances in developing TiNi nanoparticles

    Castro, A. Torres; Cuellar, E. Lopez; Mendez, U. Ortiz; Yacaman, M. Jose

    2006-01-01

    The elaboration of nanoparticles has become a field of great interest for many scientists. Nanoparticles possess different properties than those ones shown in bulk materials. Shape memory alloys have the exceptional ability to recuperate its original shape by simple heating after being 'plastically' deformed. When this process is originated, important changes in properties, as mechanical and electrical, are developed in bulk material. If there is possible to obtain nanoparticles with shape memory effects, these nanoparticles could be used in the elaboration of nanofluids with the ability to change their electrical and thermal conductivity with temperature changes, i.e., smart nanofluids. In this work, some recent results and discussion of TiNi nanoparticles obtained by ion beam milling directly from a TiNi wire with shape memory are presented. The nanoparticles obtained by this process are about 2 nm of diameter with a composition of Ti-41.0 at.% Ni. Synthesized nanoparticles elaborated by this method have an ordered structure

  6. Cutting NiTi with Femtosecond Laser

    L. Quintino

    2013-01-01

    Full Text Available Superelastic shape memory alloys are difficult to machine by thermal processes due to the facility for Ti oxidation and by mechanical processes due to their superelastic behavior. In this study, femtosecond lasers were tested to analyze the potential for machining NiTi since femtosecond lasers allow nonthermal processing of materials by ablation. The effect of processing parameters on machining depth was studied, and material removal rates were computed. Surfaces produced were analyzed under SEM which shows a resolidified thin layer with minimal heat affected zones. However, for high cutting speeds, that is, for short interaction times, this layer was not observed. A depletion of Ni was seen which may be beneficial in biomedical applications since Ni is known to produce human tissue reactions in biophysical environments.

  7. La niña proletaria

    Cartabia, Sabrina A.

    2011-12-01

    Full Text Available El presente trabajo se propone trazar un paralelo entre el cuento de Osvaldo Lamborghini “El niño proletario”, el cual, según la autora del ensayo, introduce al lector en la lucha de clases y el sometimiento de los/as proletarios/as, que sufren las mujeres, en particular a través de la violencia sexual. De esa forma la autora se pregunta si el poder que ciertas clases detentan sobre otras no influye también sobre el sometimiento de la mujer. El ensayo analiza además cómo la violencia sexual es una herramienta que constituye la base de la desigualdad, el sometimiento y la degradación de la mujer, al igual que constituye una herramienta de opresión de otros grupos vulnerables como los niños y niñas.

  8. Effects of phase transformation and interdiffusion on the exchange bias of NiFe/NiMn

    Lai, Chih-Huang; Lien, W. C.; Chen, F. R.; Kai, J. J.; Mao, S.

    2001-01-01

    The correlation between the exchange field of NiFe/NiMn and the phase transformation of NiMn was investigated. Transmission electron microscopy (TEM) dark-field images, contributed by the order phase of NiMn, were used to identify the location and volume fraction of the order phase. TEM selected area diffraction patterns showed the (110) superlattice diffraction rings of NiMn, verifying the existence of the order phase in the annealed samples. The order volume fraction can be calculated by the dark field image contributed by the (110) diffraction. The exchange field increased almost linearly with increasing order volume fraction. Energy dispersive x-ray spectroscopy attached to TEM indicated that Mn diffused into NiFe for annealing at 280 degreeC, leading to a larger coercivity and small coercivity squareness. Part of the NiMn still maintains the paramagnetic phase even after annealing at 280 degreeC. [copyright] 2001 American Institute of Physics

  9. Ni3Si2 nanowires grown in situ on Ni foam for high-performance supercapacitors

    Jiang, Yizhe; Li, Zhihui; Li, Beibei; Zhang, Jinying; Niu, Chunming

    2016-07-01

    Ni3Si2 nanowires and nanoawls have grown in situ on the surface of Ni foams by a controlled low pressure chemical vapor deposition process. Structural characterization shows that the individual Ni3Si2 nanowire is single crystal covered with a thin layer (1-2 nm) of SiO2 with a diameter of ∼20-30 nm and length of ten's micrometers. Individual nanoawl with a circular cone shape is polycrystalline. Both Ni3Si2 nanowire and nanoawl samples are evaluated as potential electrode materials for supercapacitors. The nanowire electrode delivers a very high specific capacitance and excellent rate capability. A specific capacitance of 760 F g-1 is measured at current density of 0.5 A g-1, which decreases to 518 F g-1 when the current density increases to 10 A g-1. The capacitance is dominated by pseudocapacitance with a mechanism similar to that of NiO or Ni(OH)2 widely studied in the literature. An asymmetric supercapacitor fabricated by pairing Ni3Si2 nanowire electrode with an activated carbon electrode exhibits energy densities of 17.5 Wh kg-1 and 8.8 Wh kg-1 at power densites of 301 W kg-1 and 3000 W kg-1.

  10. Exchange bias in finite sized NiO nanoparticles with Ni clusters

    Gandhi, Ashish Chhaganlal; Lin, Jauyn Grace, E-mail: jglin@ntu.edu.tw

    2017-02-15

    Structural and magnetic properties of finite sized NiO nanoparticles are investigated with synchrotron X-ray diffraction (XRD), transmission electron microscopy, magnetometer and ferromagnetic resonance (FMR) spectroscopy. A minor Ni phase is detected with synchrotron XRD, attributed to the oxygen defects in the NiO core. A considerable exchange bias of ~100 Oe is observed at 50 K and it drops abruptly and vanishes above 150 K, in association with the reduction of frozen spins. FMR data indicate a strong interaction between ferromagnetic (FM) and antiferromagnetic (AFM) phases below 150 K, consistent with the picture of isolated FM clusters in AFM matrix. - Highlights: • Structural and magnetic properties of finite sized NiO nanoparticles are systematically investigated with several advanced techniques. • A strong interaction between ferromagnetic and antiferromagnetic phases is found below 150 K. • Exchange bias field in finite sized NiO nanoparticles is due to anisotropy energy of Ni clusters over riding the domain wall energy of NiO.

  11. Radiation damage buildup and dislocation evolution in Ni and equiatomic multicomponent Ni-based alloys

    Levo, E. [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Granberg, F., E-mail: fredric.granberg@helsinki.fi [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Fridlund, C.; Nordlund, K. [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Djurabekova, F. [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Helsinki Institute of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland)

    2017-07-15

    Single-phase multicomponent alloys of equal atomic concentrations (“equiatomic”) have proven to exhibit promising mechanical and corrosion resistance properties, that are sought after in materials intended for use in hazardous environments like next-generation nuclear reactors. In this article, we investigate the damage production and dislocation mobility by simulating irradiation of elemental Ni and the alloys NiCo, NiCoCr, NiCoFe and NiFe, to assess the effect of elemental composition. We compare the defect production and the evolution of dislocation networks in the simulation cells of two different sizes, for all five studied materials. We find that the trends in defect evolution are in good agreement between the different cell sizes. The damage is generally reduced with increased alloy complexity, and the dislocation evolution is specific to each material, depending on its complexity. We show that increasing complexity of the alloys does not always lead to decreased susceptibility to damage accumulation under irradiation. We show that, for instance, the NiCo alloy behaves very similarly to Ni, while presence of Fe or Cr in the alloy even as a third component reduces the saturated level of damage substantially. Moreover, we linked the defect evolution with the dislocation transformations in the alloys. Sudden drops in defect number and large defect fluctuations from the continuous irradiation can be explained from the dislocation activity.

  12. Corrosion Resistance Of Electroless Ni-P/Cu/Ni-P Multilayer Coatings

    Zhao G.L.

    2015-06-01

    Full Text Available Ni-P/Cu/Ni-P multilayer coatings were prepared by deposition of Cu layer between two Ni–P layers. The Cu layer was deposited by metal displacement reaction between Cu2+ and Fe atoms. Corrosion behavior of single-layer Ni-P coatings, double-layer Ni-P/Cu coatings, and three-layer Ni-P/Cu/Ni-P coatings were investigated by electrochemical tests in 3.5% NaCl solution. The three-layer coatings exhibited more positive Ecorr and decreased Icorr compared with conventional single-layer Ni-P coatings, which indicated an improved corrosion resistance. The polarization curves of the three-layer coatings were characterized by two passive regions. The improved corrosion resistance was not only attributed to the function of the blocked pores of Cu. The Cu interlayer also acted as a sacrificial layer instead of a barrier in the coatings, which altered the corrosion mechanism and further improved the corrosion resistance of the coatings.

  13. PRECIPITATION HARDENING IN B2-ORDERED NiAl BY Ni2AlTiCOMPOUND

    W.H. Tian; K. Ohishi; M. Nemoto

    2001-01-01

    Microstructural variations and correlated hardness changes in B2-ordered NiAl containing fine precipitation of Ni2AlTi have been investigated by means of transmission electron microscopy (TEM) and hardness tests. The amount of age hardening is not large as compared to the large microstructural variations during aging. TEM observations have revealed that the L21-type Ni2AlTi precipitates keep a lattice coherency with the NiAl matrix at the beginning of aging. By longer periods of aging Ni2AlTi precipitates lose their coherency and change their morphology to the globular ones surrounded by misfit dislocations. The temperature dependence of the yield strength of precipitate-containing B2-ordered NiAl was investigated by compression tests over the temperature range of 873-1273K. The fine precipitation of Ni2AlTi was found to enhance greatly the yield strength and the high-temperature strength is comparison with that of superalloy Mar-M200.``

  14. Development of small-scale electroplating system for Ni-63 electroplating onto Ni foil

    Kim, Jin Joo; Choi, Sang Mu; Son, Kwang Jae; Hong, Jintae

    2016-01-01

    Betavoltaic battery is a device that converts the decay energy of beta-emitting radioisotopes into electric energy. Ni-63 is pure betaemitter with a low energy spectrum and significantly long half-life of 100.1 years and thus is widely used as the power source of betavoltaic battery. There are several methods for the formation of a Ni deposit onto a semiconductor such as electroplating, electroless plating, and chemical vapor deposition. In this study, small-scale radioisotope electroplating system was designed and fabricated to perform electroplating with a small amount of plating buffer and minimum exposure of radioactive materials. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery. In this study, an electroplating system for small-scale Ni electroplating was designed and manufactured. The process for the fabrication of a Ni-63 foil as the energy source of a betavoltaic battery was developed using the minimum concentration of Ni. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery

  15. Development of small-scale electroplating system for Ni-63 electroplating onto Ni foil

    Kim, Jin Joo; Choi, Sang Mu; Son, Kwang Jae; Hong, Jintae [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-10-15

    Betavoltaic battery is a device that converts the decay energy of beta-emitting radioisotopes into electric energy. Ni-63 is pure betaemitter with a low energy spectrum and significantly long half-life of 100.1 years and thus is widely used as the power source of betavoltaic battery. There are several methods for the formation of a Ni deposit onto a semiconductor such as electroplating, electroless plating, and chemical vapor deposition. In this study, small-scale radioisotope electroplating system was designed and fabricated to perform electroplating with a small amount of plating buffer and minimum exposure of radioactive materials. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery. In this study, an electroplating system for small-scale Ni electroplating was designed and manufactured. The process for the fabrication of a Ni-63 foil as the energy source of a betavoltaic battery was developed using the minimum concentration of Ni. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery.

  16. Exchange bias in finite sized NiO nanoparticles with Ni clusters

    Gandhi, Ashish Chhaganlal; Lin, Jauyn Grace

    2017-01-01

    Structural and magnetic properties of finite sized NiO nanoparticles are investigated with synchrotron X-ray diffraction (XRD), transmission electron microscopy, magnetometer and ferromagnetic resonance (FMR) spectroscopy. A minor Ni phase is detected with synchrotron XRD, attributed to the oxygen defects in the NiO core. A considerable exchange bias of ~100 Oe is observed at 50 K and it drops abruptly and vanishes above 150 K, in association with the reduction of frozen spins. FMR data indicate a strong interaction between ferromagnetic (FM) and antiferromagnetic (AFM) phases below 150 K, consistent with the picture of isolated FM clusters in AFM matrix. - Highlights: • Structural and magnetic properties of finite sized NiO nanoparticles are systematically investigated with several advanced techniques. • A strong interaction between ferromagnetic and antiferromagnetic phases is found below 150 K. • Exchange bias field in finite sized NiO nanoparticles is due to anisotropy energy of Ni clusters over riding the domain wall energy of NiO.

  17. Tipos especiales de niños

    Mercedes Rodrigo Bellido

    1946-09-01

    Full Text Available En las tres últimas lecciones han sido expuestas algunas consideraciones referentes a niños y adolescentes desde el nacimiento hasta el dintel de la juventud. En todas ellas hemos procurado poner de relieve la necesidad de individualizar el conocimiento de cada niño para obtener mejores resultados en su adaptación a su futura vida de adultos, En todas ellas  nos hemos referido al llamado niño normal. Nos corresponde en la lección de hoy ocuparnos can la superficialidad característica de estas charlas tipo-muestrario, de otras categorías de niños muy dignos de interés.. quienes unas por exceso, otros por defecto, otros por dificultades de adaptación por diferentes causas, se desvían de la línea media de la normalidad. Consideramos que no está fuera del lugar, aquí, el tema de los niños excepcionales y por el contrario que es necesario intensificar el estudio de los trastornos de la vida mental y emocional de los niños en la preparación de los estudiantes de Medicina. Y no es nuestra solo esta opinión; no hace mucho tiempo en la Medical School de Ia Universidad de Minnessota hemos sabido que se ha hecho un intento de considerar y evaluar factores emocionales ambientales sobre las mismas bases que los descubrimientos fisiológicos.

  18. Ni Foam-Ni3 S2 @Ni(OH)2 -Graphene Sandwich Structure Electrode Materials: Facile Synthesis and High Supercapacitor Performance.

    Wang, Xiaobing; Hu, Jiangjiang; Su, Yichang; Hao, Jin; Liu, Fanggang; Han, Shuang; An, Jian; Lian, Jianshe

    2017-03-23

    A novel Ni foam-Ni 3 S 2 @Ni(OH) 2 -graphene sandwich-structured electrode (NF-NN-G) with high areal mass loading (8.33 mg cm -2 ) has been developed by sulfidation and hydrolysis reactions. The conductivity of Ni 3 S 2 and Ni(OH) 2 were both improved. The upper layer of Ni(OH) 2 , covered with a thin graphene film, is formed in situ from the surface of the lower layer of Ni 3 S 2 , whereas the Ni 3 S 2 grown on Ni foam substrate mainly acts as a rough support bridging the Ni(OH) 2 and Ni foam. The graphene stabilized the Ni(OH) 2 and the electrochemical properties were effectively enhanced. The as-synthesized NF-NN-G-5mg electrode shows a high specific capacitance (2258 F g -1 at 1 A g -1 or 18.81 F cm -2 at 8.33 mA cm -2 ) and an outstanding rate property (1010 F g -1 at 20 Ag -1 or 8.413 F cm -2 at 166.6 mA cm -2 ). This result is around double the capacitance achieved in previous research on Ni 3 S 2 @Ni(OH) 2 /3DGN composites (3DGN=three-dimensional graphene network). In addition, the as-fabricated NF-NN-G-5mg composite electrode has an excellent cycle life with no capacitance loss after 3000 cycles, indicating a potential application as an efficient electrode. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Salud mental del niño

    Ospina de González, Bernarda

    1987-01-01

    Es ya reconocida por todos las importancia de los primeros años de vida en la estructutración de la personalidad y, por consiguiente, en la salud mental del niño. En este artículo se hace una síntesis de los diferentes aspectos del desarrollo de la personalidad infanltil que seben ser conocidos por el personal de salud para estar en condiciones de brindar una atención integral a la madre y al niño. Con igual propósito se señalan algunos patrones de tipo psicosocial que influyen en la estabili...

  20. Magnetic anisotropy of Ni/Cr multilayers

    Kang, S.; Xia, H.

    1997-01-01

    The magnetic anisotropy of Ni/Cr multilayers has been investigated by using vibrating sample magnetometer (VSM) and ferromagnetic resonance techniques (FMR). The FMR spectra are obtained as a function of the orientation of the applied magnetic field from in-plane to out-of-plane. The results are fitted theoretically to determine the magnetic anisotropy. From VSM and FMR, a positive value for Ni/Cr interface anisotropy is obtained, which favours a perpendicular easy axis. The possible mechanism for the perpendicular anisotropy has been discussed and it may be attributed to the magnetostriction, caused by intrinsic stress due to lattice mismatch. (orig.). With 005 figs., 001 tabs

  1. Ionizing Radiation Effects in Ni Nanotubes

    Shlimas, D.; Kozlovsky, A.; Shumskaya, A.; Kaniukov, E.; Ibragimova, M.; Zdorovets, M.; Kadyrzhanov, K.

    2017-01-01

    Polycrystalline nickel nanotubes with diameter of 380 nm and wall thickness 95 nm were synthesized by electrochemical method using PET track-etched membranes with thickness of 12 μm. A comprehensive study of the structural, morphological and electrical characteristics of Ni nanotubes irradiated with C+13 ions with energy 1.75 MeV/nucleon and fluence ranging from 109 to 5 × 1011 cm-2 was carried out. The ability of modification of structural parameters such as lattice parameter and the average size of crystallites and conductivity of Ni nanotubes by irradiation was shown.

  2. Optimization of process parameters for synthesis of silica–Ni ...

    Optimization of process parameters for synthesis of silica–Ni nanocomposite by design of experiment ... Sol–gel; Ni; design of experiments; nanocomposites. ... Kolkata 700 032, India; Rustech Products Pvt. Ltd., Kolkata 700 045, India ...

  3. Ni hollow spheres as catalysts for methanol and ethanol electrooxidation

    Xu, Changwei [Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632 (China); School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Hu, Yonghong; Rong, Jianhua; Liu, Yingliang [Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632 (China); Jiang, San Ping [School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798 (Singapore)

    2007-08-15

    In this paper, we successfully synthesized Ni hollow spheres consisting of needle-like nickel particles by using silica spheres as template with gold nanoparticles seeding method. The Ni hollow spheres are applied to methanol and ethanol electrooxidation in alkaline media. The results show that the Ni hollow spheres give a very high activity for alcohol electrooxidation at a very low nickel loading of 0.10 mg cm{sup -2}. The current on Ni hollow spheres is much higher than that on Ni particles. The onset potential and peak potential on Ni hollow spheres are more negative than that on Ni particles for methanol and ethanol electrooxidation. The Ni hollow spheres may be of great potential in alcohol sensor and direct alcohol fuel cells. (author)

  4. Separation and preparation of "6"2Ni isotope

    Ren Xiuyan; Mi Yajing; Zeng Ziqiang; Li Gongliang; Tu Rui

    2014-01-01

    Micro nuclear battery is the perfect power of space craft equipment. "6"3Ni is the core operation material of the "6"3Ni battery. It can produce radioisotope "6"3Ni while high abundance "6"2Ni is irradiated in the reactor. In order to meet the requirements of the abundance and the purity, research of the separation for "6"2Ni isotope was developed. The magnetic field and beam transmission status were simulated. The improvement designs of the ion source and the collector pocket were carried out. The process flow of high abundance "6"2Ni using electromagnetic separation method was established. The experiment of "6"2Ni isotope was developed by using electromagnetism isotope separator. The results show that the enrichment of "6"2Ni isotope is more than 90%. (authors)

  5. X-ray fluorescence analysis of Fe - Ni - Mo systems

    Belyaev, E.E.; Ershov, A.V.; Mashin, A.I.; Mashin, N.I.; Rudnevskij, N.K.

    1998-01-01

    Procedures for the X-ray fluorescence determination of the composition and thickness of Fe - Ni - Mo thin films and the concentration of elements in thick films of the Fe - Ni - Mo alloy are developed [ru

  6. Structure characterization of Ni/NiO and Ti/TiO2 interfaces

    Lamine, Brahim

    1983-01-01

    This research thesis reports the structure characterization of Ni-NiO and Ti-TiO 2 interfaces through an in-situ investigation of thin blade oxidation, of oxide germination and growth, and through a determination of mutual metal/oxide orientation relationships. Thin films of TiO 2 have also been characterized and the study of the influence of vacuum annealing on TiO 2 layer structure and morphology has been attempted. The examination of metal-oxide interface reveals a duplex structure of NiO and TiO 2 layers, and a preferential grain boundary oxidation of the underlying metal [fr

  7. Structure of Ni-rich Ni--Cr--B--Si coating alloys

    Knotek, O.; Lugscheider, E.; Reimann, H.

    1975-01-01

    The structures of quaternary, nickel-rich Ni--Cr--B--Si alloys were analyzed at a constant boron content of 10 at. percent and a temperature of 850 0 C. The composition range for silicide formation was determined. In these quaternary alloys, known binary nickel silicides, nickel and chromium borides, and the ternary silico-boride Ni 6 Si 2 B were confirmed. A new composition for the W 5 Si 3 -type phase in the Ni--B--Si system was proposed. (U.S.)

  8. The study of quasi-projectiles produced in Ni+Ni and Ni+Au collisions: excitation energy and spin

    Buta, A.

    2003-02-01

    During the collision between the projectile and the target nuclei in the intermediate energy regime (E < 100 MeV/nucleon) two excited nuclei are mainly observed in the exit channel, the quasi projectile (QP) and the quasi target. They disintegrate by particle emission. However, this binary picture is perturbed by the emission of particles and light fragments with velocities intermediate between the projectile velocity and the target one, all along the interaction (midrapidity component). This work aim to determine the excitation energy and the intrinsic angular momentum (or spin) of quasi-projectiles produced in the Ni+Ni and Ni+Au collisions at 52 and 90 MeV/nucleon. The excitation energy is deduced from the kinematical characteristics of particles emitted by the quasi-projectile. They have to be separated from midrapidity particles. Three different scenarios have been used for this purpose. The spin of the quasi-projectile has been extracted from the experimental data by mean of proton and alpha particles multiplicities emitted by the QP in the Ni+Au at 52 MeV/nucleon reaction. The results have been compared to the predictions of a theoretical model based on nucleon transfers. Their evolution is qualitatively reproduced as a function of the violence of the collision. (author)

  9. Low temperature gaseous nitriding of Ni based superalloys

    Eliasen, K. M.; Christiansen, Thomas Lundin; Somers, Marcel A. J.

    2010-01-01

    In the present work the nitriding response of selected Ni based superalloys at low temperatures is addressed. The alloys investigated are nimonic series nos. 80, 90, 95 and 100 and nichrome (Ni/Cr......In the present work the nitriding response of selected Ni based superalloys at low temperatures is addressed. The alloys investigated are nimonic series nos. 80, 90, 95 and 100 and nichrome (Ni/Cr...

  10. Giant magnetocaloric effect in isostructural MnNiGe-CoNiGe system by establishing a Curie-temperature window

    Liu, E. K.; Zhang, H. G.; Xu, G. Z.; Zhang, X. M.; Ma, R. S.; Wang, W. H.; Chen, J. L.; Zhang, H. W.; Wu, G. H.; Feng, L.; Zhang, Xixiang

    2013-01-01

    An effective scheme of isostructural alloying was applied to establish a Curie-temperature window in isostructural MnNiGe-CoNiGe system. With the simultaneous accomplishment of decreasing structural-transition temperature and converting

  11. The large magnetoelectric effect in Ni-lead zirconium titanate-Ni trilayers derived by electroless deposition

    Bi, K; Wang, Y G; Wu, W; Pan, D A

    2010-01-01

    Magnetoelectric (ME) Ni-lead zirconium titanate-Ni trilayers with neither electrodes nor bonding layers have been derived by electroless deposition. The structure and magnetic properties of the electroless deposited Ni layers with different pH values are characterized by x-ray diffraction and vibrating sample magnetometer. The influence of the bias magnetic field and the magnetic field frequency (f) on ME coupling is discussed. It is seen that α E,31 depends strongly on H dc and f. The value of the ME coefficient increases as the thickness of the Ni layer and the pH of the bath increase. A maximum of the ME voltage coefficient α E,31 = 5.77 V cm -1 Oe -1 at resonance frequency with a deposited Ni layer thickness t Ni = 302 μm is obtained. The large ME coefficient makes these Ni-PZT-Ni trilayers suitable for applications in sensors, actuators and transducers. (fast track communication)

  12. Development of the dentistry alloy Ni-Cr-Nb; Desenvolvimento de ligas odontologicas Ni-Cr-Nb

    Souza, M.A.; Ramos, A.S.; Hashimoto, T.M., E-mail: mari_sou@hotmail.co [UNESP/FEG, Guaratingueta, SP (Brazil). Fac. de Engenharia. Dept. de Materiais e Tecnologia

    2010-07-01

    This work reports on the structural characterization of Ni-Cr-Mo and Ni-Cr-Nb alloys produced by arc melting. Samples were characterized by means of optical microscopy, X-ray diffraction, scanning electron microscopy, and EDS analysis. Results indicated that the arc melting process was efficient to produce homogeneous structures in Ni-Cr-Mo and Ni-Cr-Nb alloys. The nickel dissolved large amounts of Cr, Mo and Nb, which was detected by EDS analysis and X-ray diffraction. The alloy containing molybdenum indicated the presence of structure based on Ni{sub SS}, while that the alloys containing niobium presented primary grains of Ni{sub SS} and precipitates formed by the simultaneous transformation of the Ni and Ni{sub 3}Nb phases. (author)

  13. Microstructure and electrochemical characterization of laser melt-deposited Ti2Ni3Si/NiTi intermetallic alloys

    Dong Lixin; Wang Huaming

    2008-01-01

    Corrosion and wear resistant Ti 2 Ni 3 Si/NiTi intermetallic alloys with Ti 2 Ni 3 Si as the reinforcing phase and the ductile NiTi as the toughening phase were designed and fabricated by the laser melt-deposition manufacturing process. Electrochemical behavior of the alloys was investigated using potentiodynamic polarization testing and electrochemical impedance spectroscopy in an NaOH solution. The results showed that the alloys have outstanding corrosion resistance due to the formation of a protective passive surface film of Ni(OH) 2 as well as the high chemical stability and strong inter-atomic bonds inherent to Ti 2 Ni 3 Si and NiTi intermetallics. The Ti 2 Ni 3 Si content has a significant influence on the microstructure of the alloys but only a slight effect on electrochemical corrosion properties

  14. Homotopic mapping solution of an oscillator for the El Niño/La Niña-southern oscillation

    Xian-Chun, Zhou; Yi-Hua, Lin; Wan-Tao, Lin; Jia-Qi, Mo

    2009-01-01

    This paper considers a class of oscillator for the El Niño/La Niña-southern oscillation (ENSO) model. By using the homotopic mapping method, it obtains approximations of the solution for the ENSO model. (general)

  15. Electrochemical reduction of NiO in a composite electrode

    Hu, Qiang; Jacobsen, Torben; Hansen, Karin Vels

    2013-01-01

    a lower overpotential. Microstructures of NiO with different reduction degrees are shown. Electrochemical impedance spectroscopy is carried out during the reduction process. Electrochemical reduction of NiO may need an induction period. When NiO is reduced at a constant voltage the current initially...

  16. Morphological and compositional engineering of Ni/carbon ...

    Ni/multi-walled carbon nanotubes (MWCNTs) composite films were deposited on the glassy carbon electrode (GCE) by a Ni plating bath containing homogeneously dispersed MWCNTs using polyvinylpyrrolidone (PVP) as dispersion additive. Incorporation of MWCNTs into Ni matrix was greatly enhanced by the application ...

  17. CLASSICAL AREAS OF PHENOMENOLOGY: First-principles calculations for the elastic properties of Ni-base model superalloys: Ni/Ni3Al multilayers

    Wang, Yun-Jiang; Wang, Chong-Yu

    2009-10-01

    A model system consisting of Ni[001](100)/Ni3Al[001](100) multi-layers are studied using the density functional theory in order to explore the elastic properties of single crystal Ni-based superalloys. Simulation results are consistent with the experimental observation that rafted Ni-base superalloys virtually possess a cubic symmetry. The convergence of the elastic properties with respect to the thickness of the multilayers are tested by a series of multilayers from 2γ'+2γ to 10γ'+10γ atomic layers. The elastic properties are found to vary little with the increase of the multilayer's thickness. A Ni/Ni3Al multilayer with 10γ'+10γ atomic layers (3.54 nm) can be used to simulate the mechanical properties of Ni-base model superalloys. Our calculated elastic constants, bulk modulus, orientation-dependent shear modulus and Young's modulus, as well as the Zener anisotropy factor are all compatible with the measured results of Ni-base model superalloys R1 and the advanced commercial superalloys TMS-26, CMSX-4 at a low temperature. The mechanical properties as a function of the γ' phase volume fraction are calculated by varying the proportion of the γ and γ' phase in the multilayers. Besides, the mechanical properties of two-phase Ni/Ni3Al multilayer can be well predicted by the Voigt-Reuss-Hill rule of mixtures.

  18. Low-field spin dynamics of Cr7Ni and Cr7Ni-Cu -Cr 7Ni molecular rings as detected by μ SR

    Sanna, S.; Arosio, P.; Bordonali, L.; Adelnia, F.; Mariani, M.; Garlatti, E.; Baines, C.; Amato, A.; Sabareesh, K. P. V.; Timco, G.; Winpenny, R. E. P.; Blundell, S. J.; Lascialfari, A.

    2017-11-01

    Muon spin rotation measurements were used to investigate the spin dynamics of heterometallic Cr7Ni and Cr7Ni -Cu-Cr7Ni molecular clusters. In Cr7Ni the magnetic ions are arranged in a quasiplanar ring and interact via an antiferromagnetic exchange coupling constant J , while Cr7Ni -Cu-Cr7Ni is composed of two Cr7Ni linked by a bridging moiety containing one Cu ion, that induces an inter-ring ferromagnetic interaction J'≪J . The longitudinal muon relaxation rate λ collected at low magnetic fields μ0H BPP)-like heuristic fitting model that takes into account of a distribution of electronic spin characteristic times for T >5 K, while the shoulder presented by Cr7Ni can be reproduced by a BPP function that incorporates a single electronic characteristic time theoretically predicted to dominate for T <5 K. The flattening of λ (T ) in Cr7Ni -Cu-Cr7Ni occurring at very low temperature can be tentatively attributed to field-dependent quantum effects and/or to an inelastic term in the spectral density of the electronic spin fluctuations.

  19. Microporous Ni@NiO nanoparticles prepared by chemically dealloying Al_3Ni_2@Al nanoparticles as a high microwave absorption material

    Pang, Yu; Xie, Xiubo; Li, Da; Chou, Wusheng; Liu, Tong

    2017-01-01

    The Al_3Ni_2@Al nanoparticles (NPs) were prepared from Ni_4_5Al_5_5 master alloy by hydrogen plasma-metal reaction method, and were subsequently dealloyed to produce porous Ni@NiO NPs of 36 nm. The pore size ranges from 0.7 to 1.6 nm, leading to large specific surface area of 69.5 m"2/g and big pore volume of 0.507 cc/g. The saturation magnetization (M_S) and coercivity (H_C) of the microporous Ni@NiO NPs are 11.5 emu/g and 5.2 Oe. They exhibit high microwave absorption performance with a minimum reflection coefficient (RC) of −86.9 dB and an absorption bandwidth of 2.6 GHz (RC≤−10 dB) at thickness of 4.5 mm. The enhanced microwave absorption properties are attributed to the synergistic effect of the magnetic Ni core and dielectric NiO shell, and the micropore architecture. The NPs with micropore morphology and core/shell structure open a new way to modify the microwave absorption performance. - Graphical abstract: The microporous Ni/NiO nanoparticles prepared by chemically dealloying Al_3Ni_2@Al NPs exhibit high microwave absorption intensity (−86.9 dB) and wide absorption bandwidth (2.6 GHz for RC≤−10 dB). - Highlights: • Microporous Ni/NiO nanoparticals were prepared by chemically dealloying method. • They possessed micropores of 0.7–1.6 nm with a surface area of 69.5 m"2/g. • They showed high microwave absorption intensity and wide absorption bandwidth. • Microwave absorption mechanism was explained by micropore and core/shell structures.

  20. Microporous Ni@NiO nanoparticles prepared by chemically dealloying Al{sub 3}Ni{sub 2}@Al nanoparticles as a high microwave absorption material

    Pang, Yu; Xie, Xiubo; Li, Da [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing 100191 (China); Chou, Wusheng [School of Mechanical Engineering and Automation, Beihang University, Beijing 100191 (China); Liu, Tong, E-mail: tongliu@buaa.edu.cn [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing 100191 (China)

    2017-03-15

    The Al{sub 3}Ni{sub 2}@Al nanoparticles (NPs) were prepared from Ni{sub 45}Al{sub 55} master alloy by hydrogen plasma-metal reaction method, and were subsequently dealloyed to produce porous Ni@NiO NPs of 36 nm. The pore size ranges from 0.7 to 1.6 nm, leading to large specific surface area of 69.5 m{sup 2}/g and big pore volume of 0.507 cc/g. The saturation magnetization (M{sub S}) and coercivity (H{sub C}) of the microporous Ni@NiO NPs are 11.5 emu/g and 5.2 Oe. They exhibit high microwave absorption performance with a minimum reflection coefficient (RC) of −86.9 dB and an absorption bandwidth of 2.6 GHz (RC≤−10 dB) at thickness of 4.5 mm. The enhanced microwave absorption properties are attributed to the synergistic effect of the magnetic Ni core and dielectric NiO shell, and the micropore architecture. The NPs with micropore morphology and core/shell structure open a new way to modify the microwave absorption performance. - Graphical abstract: The microporous Ni/NiO nanoparticles prepared by chemically dealloying Al{sub 3}Ni{sub 2}@Al NPs exhibit high microwave absorption intensity (−86.9 dB) and wide absorption bandwidth (2.6 GHz for RC≤−10 dB). - Highlights: • Microporous Ni/NiO nanoparticals were prepared by chemically dealloying method. • They possessed micropores of 0.7–1.6 nm with a surface area of 69.5 m{sup 2}/g. • They showed high microwave absorption intensity and wide absorption bandwidth. • Microwave absorption mechanism was explained by micropore and core/shell structures.

  1. Tracer diffusion of 60Co and 63Ni in amorphous NiZr alloy

    Hoshino, K.; Averback, R.S.; Hahn, H.; Rothman, S.J.

    1987-01-01

    Tracer diffusion of 60 Co and 63 Ni in equiatomic amorphous NiZr alloy in the temperature range between 486 and 641 0 K can be described by: D/sub Co/sup */ = 3.7 x 10 -7 exp[-(135 +- 14) kJ mole -1 /RT] m 2 /sec and D/sub Ni//sup */ = 1.7 x 10 -7 exp[-(140 +- 9) kJ mole -1 /RT] m 2 /sec. The values of D/sub Ni//sup */ are in reasonable agreement with those measured by the Rutherford backscattering technique. The measured diffusivities were independent of time, indicating that no relaxation took place during diffusion. 27 refs., 2 tabs

  2. Precipitation-induced of partial annealing of Ni-rich NiTi shape memory alloy

    Nashrudin, Muhammad Naqib; Mahmud, Abdus Samad; Mohamad, Hishamiakim

    2018-05-01

    NiTi shape memory alloy behavior is very sensitive to alloy composition and heat treatment processes. Thermomechanical behavior of near-equiatomic alloy is normally enhanced by partial anneal of a cold-worked specimen. The shape memory behavior of Ni-rich alloy can be enhanced by ageing precipitation. This work studied the effect of simultaneous partial annealing and ageing precipitation of a Ni-rich cold drawn Ti-50.9at%Ni wire towards martensite phase transformation behavior. Ageing treatment of a non-cold worked specimen was also done for comparison. It was found that the increase of heat treatment temperature caused the forward transformation stress to decrease for the cold worked and non-cold worked specimens. Strain recovery on the reverse transformation of the cold worked wire improved compared to the non-cold worked wire as the temperature increased.

  3. Corrosion behaviour of electrodeposited nanocrystalline Ni-W and Ni-Fe-W alloys

    Sriraman, K.R.; Ganesh Sundara Raman, S.; Seshadri, S.K.

    2007-01-01

    The present work deals with evaluation of corrosion behaviour of electrodeposited nanocrystalline Ni-W and Ni-Fe-W alloys. Corrosion behaviour of the coatings deposited on steel substrates was studied using polarization and electrochemical impedance spectroscopy techniques in 3.5% NaCl solution while their passivation behaviour was studied in 1N sulphuric acid solution. The corrosion resistance of Ni-W alloys increased with tungsten content up to 7.54 at.% and then decreased. In case of Ni-Fe-W alloys it increased with tungsten content up to 9.20 at.% and then decreased. The ternary alloy coatings exhibited poor corrosion resistance compared to binary alloy coatings due to preferential dissolution of iron from the matrix. Regardless of composition all the alloys exhibited passivation behaviour over a wide range of potentials due to the formation of tungsten rich film on the surface

  4. Evolution of collectivity in the 78Ni region: Coulomb excitation of 74Ni at intermediate energies.

    Marchi T.

    2014-03-01

    Full Text Available The study of the collective properties of nuclear excitations far from stability provides information about the shell structure at extreme conditions. Spectroscopic observables such as the energy or the transition probabilities of the lowest states, in nuclei with large neutron excess, allow to probe the density and isospin dependence of the effective interaction. Indeed, it was recently shown that tensor and three-body forces play an important role in breaking and creating magic numbers. Emblematic is the case of the evolution of the Ni isotopic chain where several features showed up moving from the most neutron rich stable isotope (64Ni towards the 78Ni nucleus where the large neutron excess coincides with a double shell closure. In this framework, we have recently performed an experiment with the goal to extract the B(E2; 0+ → 2+ value for the 74Ni nucleus in an intermediate-energy Coulomb excitation experiment: preliminary results are discussed.

  5. Rate of hydrogen motion in Ni-substituted LaNi5Hx from NMR

    Mendenhall, Michael P.; Bowman, Robert C.; Ivancic, Timothy M.; Conradi, Mark S.

    2007-01-01

    Partial substitution of Sn, Ge, or Si for Ni in LaNi 5 H x greatly enhances the stability under repeated hydrogen-cycling. Proton NMR relaxation measurements are reported here to determine the rates of H hopping in the substituted metals LaNi 4.6 M 0.4 H x with M = Sn, Ge, and Si, for comparison to bare LaNi 5 H x . The relaxation times T 2 * (FID), T 2 (Hahn echo), T 2 -CPMG, T 1 , and T 1ρ were determined from 130 to 375 K. The three substituents result in only small increases in the average rate of motion at a given temperature but with a broader distribution of rates over the many inequivalent H sites and hopping paths. Evidently, the average energy barriers along the paths for H motion are only little affected by these substituents. Changes of H content x produce only minor changes in the relaxation times

  6. Moessbauer effect measurements on the intermetallic compounds Ni3Al and Ni3Ge

    Drijver, J.W.; Woude, F. van der

    1975-01-01

    Moessbauer parameters obtained from room temperature emission and absorption spectra of Ni 3 Al and Ni 3 Ga processed by a computer assuming a singlet and a doublet are given. The doublet is due to iron or cobalt atoms at the nickel site. Quadrupole splitting at 57 Fe nuclei in Ni 3 Ga is larger than in Ni 3 Al, viz. 0.52 and 0.37 mm/sec, respectively. Isomer shift at the Al/Ga position is very close to -0.02 mm/sec found in metallic nickel. Also given are the hyperfine magnetic fields at 4.2 K. Considering the preference of 57 Co and 57 Fe atoms in the lattice, the field intensities at the nickel and aluminium sites are found to be 227 +- 1 and 238 +- 1 kOe, respectively. (Z.S.)

  7. Low energy structure of even-even Ni isotopes close to 78Ni

    Rykaczewski, Krzysztof Piotr; Mazzocchi, C.; Grzywacz, Robert Kazimierz; Batchelder, J.C.; Bingham, Carrol R.; Fong, D.; Hamilton, J.H.; Hwang, J.K.; Karny, M.; Krolas, W.; Liddick, S.N.; Lisetskiy, A. F.; Morton, N.H.; Mantica, P.F.; Mueller, W.F.; Steiner, M.; Stolz, A.; Winger, J.A.

    2005-01-01

    The structure of magic neutron-rich nickel isotopes produced in the fragmentation of a 140 A MeV 86 Kr beam was investigated. For the first time four gamma transitions were assigned to the decay of the I π =8 + , T 1/2 = 590 +180 -110 isomer, thus establishing the 0 + -2 + -4 + -6 + -8 + ground-state band in 76 Ni. The previously unknown 2 + and 4 + levels belonging to the ground-state band in 74 Ni were identified in the β decay of 74 Co (T 1/2 =30(3) ms). The decay properties of 72 Co → 72 Ni were verified and confirmed on the basis of γ-γ coincidence data. The relevance of the measured level properties for the magicity of 78 Ni is analyzed with the help of advanced shell-model predictions

  8. The process of Ni-63 production and measurement of beta radiation of irradiated Ni-63

    Kim, Jin Joo; Uhma, Young Rang; Kim, Jong Bum; Choi, Sang Mu; Son, Kwang Jae; Hong, Jin Tae; Park, Jong Han

    2016-01-01

    It has the following characteristics: long service lifetime, high energy density, easy small-scale fabrication, and minimum maintenance. For this reasons, betavoltaic batteries are widely used in many low-power applications such as medical applications and power sources for micro electro-mechanical system (MEMS) because they can operate effectively at extreme environments. Proper selection of radioisotope is a critical factor in the design of a betavoltaic battery. The important factors affecting the performance of a betavoltaic battery are specific activity, half-life, and toxicity. In this study, a target for irradiation was produced using 99% Ni-62 metal power concentrate. Ni-62 target of 1 g was irradiated in MARIA reactor operated in Poland for 470 hours, and estimated production of Ni- 63 was calculated. Irradiated Ni-63 pellets were dissolved in HCl solution, and its beta radiation was measured by Liquid Scintillation Counter (LSC).

  9. Synthetic Ni3S2/Ni hybrid architectures as potential contrast agents in MRI

    Ma, J; Chen, K

    2016-01-01

    Traditional magnetic resonance imaging (MRI) contrast agents mainly include superparamagnetic (SPM) iron oxide nanoparticle as T 2 contrast agent for liver and paramagnetic Gd (III)-chelate as T 1 contrast agent for all organs. In this work, weak ferromagnetic kale-like and SPM cabbage-like Ni 3 S 2 @Ni hybrid architectures were synthesized and evaluated as potential T 1 MRI contrast agents. Their relatively small r 2 /r 1 ratios of 2.59 and 2.38, and high r 1 values of 11.27 and 4.89 mmol −1 L s −1 (for the kale-like and cabbage-like Ni 3 S 2 @Ni, respectively) will shed some light on the development of new-type MRI contrast agents. (paper)

  10. Hierarchical NiCo2 O4 nanosheets grown on Ni nanofoam as high-performance electrodes for supercapacitors.

    Gao, Guoxin; Wu, Hao Bin; Ding, Shujiang; Liu, Li-Min; Lou, Xiong Wen David

    2015-02-18

    A high-performance electrode for supercapacitors is designed and synthesized by growing electroactive NiCo2 O4 nanosheets on conductive Ni nanofoam. Because of the structural advantages, the as-prepared Ni@NiCo2 O4 hybrid nanostructure exhibits significantly improved electrochemical performance with high capacitance, excellent rate capability, and good cycling stability. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Ni(II) complexes of dithiophosphonic acids

    aDepartment of Chemistry, Science and Research Branch, Islamic Azad ... The compounds were characterized by 1H, 13C and 31P NMR, IR spectroscopy and elemental analysis. The ... design and synthesize Ni(II) complexes with new ..... Yield: 86%. ..... 28 65. 18. Greenwood D 1989 Antimicrobial chemotherapy (New.

  12. Ni MINERALIZATION AND PGE CHARACTERIZATION IN THE ...

    Mgina

    fractionation, (2) the IPGEs are often associated with chromites as alloys or sulfides in ... Key words: Tanzania, Kabanga, Luhuma, PGE, Ni-Cu sulfides .... massive sulfide based on size of ore zone ... to ≤ 0.1 wt% and Fe2O3T = 80- ≈ 87 wt%.

  13. Modelling of rechargeable NiMH batteries

    Ledovskikh, A.; Verbitskiy, E.; Ayeb, A.; Notten, P.H.L.

    2003-01-01

    A new mathematical model has been developed for rechargeable NiMH batteries, which is based on the occurring physical–chemical processes inside. This model enables one to simultaneously simulate the battery voltage, internal gas pressures (both PO2 and PH2) and temperature during battery operation.

  14. Characterisation of a Zn / Ni Plating Bath

    2009-09-03

    accelerated corrosion in the first stages which is then slowed down by its own product of corrosion, Zn(OH)212. Zinc hydroxide dehydrates in time to form ZnO ... Electrochemistry , 1991, 21, 642 [5] – Alfantasi, A.M., A study on the synthesis, characterization ans properties of pulse-plated ultrafine- grained Zn-Ni alloy

  15. Evidence for an isomer in 76Ni

    Sawicka, M.; Pfuetzner, M.; Grzywacz, R.; Daugas, J.M.; Belier, G.; Sauvestre, J.E.; Matea, I.; Lewitowicz, M.; Georgiev, G.; Grawe, H.; Mayet, P.; Becker, F.; Bingham, C.; Borcea, R.; Hammache, F.; Ibrahim, F.; Bouchez, E.; Buta, A.; Dragulescu, E.; Giovinazzo, J.; Meot, V.; Negoita, F.; De Oliveira Santos, F.; Perru, O.; Roig, O.; Rykaczewski, K.P.; Saint-Laurent, M.G.; Sorlin, O.; Stanoiu, M.; Stefan, I.; Stodel, C.; Theisen, C.; Verney, D.

    2004-01-01

    In the experiment performed at the LISE2000 spectrometer at GANIL neutron-rich nickel isotopes were studied by microsecond isomer spectroscopy. Evidence for an isomer in 76 Ni is found, consistently with the shell model prediction of an 8 + state of ν(g 9/2 ) 2 structure. (orig.)

  16. Electroplating condition for Ni nanocrystalline on metal (Ni and Cu) plates

    Park, Keun Yung; Uhm, Young Rang; Son, Kwang Jae; Shim, Young Ho; Choi, Sun Ju [KAERI, Daejeon (Korea, Republic of)

    2012-10-15

    Ni 63, a beta radiation source, is prepared by the electrical deposition of radioactive Ni 63 ions on a thin non radioactive nickel foil or Cu plate. Given a half life of 100 years, a nuclear battery will still produce half of its initial starting power after 100 years. A speck of a radioisotope like nickel 63, for example, contains enough energy to power a nano nuclear battery for decades, and to do so safely. Ni 63 plating is similar to other electroplating processes that employ soluble metal anodes. It requires the passage of a direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. The charged Ni ions are formed by sulfate, sulfamate, chloride, and a Watts bath. However, the charged Ni 63 ions are formed by dissolving metal Ni 63. To established the coating condition of Ni 63, non radioactive metal Ni particles are dissolved an acid solution and electroplated on a Ni sheet. The nickel plating process is used extensively for decorative, engineering and electro forming purposes because the appearance and other properties of electrodeposited nickel can be varied over a wide range by controlling the composition and operating parameters of the plating solution. A continuous increase in the grain size versus current density has also been recognized in the direct current electrodeposition of nickel coating. On the other hand, A runa et al. reported that the current density has no significant effect on the grain size of nickel electro deposits. A review of the literature shows that saccharin has often been added to a nickel plating bath since the 1980s to improve the ductility and brightness, and in later periods as a grain refiner agent. In the present paper, not only the preparation of a Ni plating solution prepared by dissolving metal particles, but also an optimization of the deposition conditions, such as the current density, saccharin concentration in the bath, and different metal substrates were investigated

  17. Electroplating condition for Ni nanocrystalline on metal (Ni and Cu) plates

    Park, Keun Yung; Uhm, Young Rang; Son, Kwang Jae; Shim, Young Ho; Choi, Sun Ju

    2012-01-01

    Ni 63, a beta radiation source, is prepared by the electrical deposition of radioactive Ni 63 ions on a thin non radioactive nickel foil or Cu plate. Given a half life of 100 years, a nuclear battery will still produce half of its initial starting power after 100 years. A speck of a radioisotope like nickel 63, for example, contains enough energy to power a nano nuclear battery for decades, and to do so safely. Ni 63 plating is similar to other electroplating processes that employ soluble metal anodes. It requires the passage of a direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. The charged Ni ions are formed by sulfate, sulfamate, chloride, and a Watts bath. However, the charged Ni 63 ions are formed by dissolving metal Ni 63. To established the coating condition of Ni 63, non radioactive metal Ni particles are dissolved an acid solution and electroplated on a Ni sheet. The nickel plating process is used extensively for decorative, engineering and electro forming purposes because the appearance and other properties of electrodeposited nickel can be varied over a wide range by controlling the composition and operating parameters of the plating solution. A continuous increase in the grain size versus current density has also been recognized in the direct current electrodeposition of nickel coating. On the other hand, A runa et al. reported that the current density has no significant effect on the grain size of nickel electro deposits. A review of the literature shows that saccharin has often been added to a nickel plating bath since the 1980s to improve the ductility and brightness, and in later periods as a grain refiner agent. In the present paper, not only the preparation of a Ni plating solution prepared by dissolving metal particles, but also an optimization of the deposition conditions, such as the current density, saccharin concentration in the bath, and different metal substrates were investigated

  18. Synthesis of microporous Ni/NiO nanoparticles with enhanced microwave absorption properties

    Liu, Tong; Pang, Yu; Xie, Xiubo; Qi, Wen; Wu, Ying; Kobayashi, Satoru; Zheng, Jie; Li, Xingguo

    2016-01-01

    The fabrication of microporous metal materials with many potential applications is challenging due to their high chemical activities and the difficulty in controlling the pore size. By adjusting the reaction condition and the composition of the Ni–Al nanoparticle precursor, we have successfully produced the microporous Ni nanoparticles (NPs) of 22 nm by chemical dealloying method. During the passivation process, the microporous Ni NPs covered with NiO shell are generated as the result of surface oxidation. The micropores range from 0.6 to 1.2 nm in diameter with a large surface area of 68.9 m"2/g. Due to the elimination of Al atoms during dealloying process, the crystalline size of the microporous Ni NPs is sharply decreased to 2–5 nm. The specific architecture offers the microporous Ni/NiO NPs a small microwave reflection coefficient (RC) and a wide absorption bandwidth (RC ≤ −10 dB) of −49.1 dB and 5.8 GHz, much better than the nonporous counterpart of −24.1 dB and 3.7 GHz. The enhanced microwave absorption performance has been interpreted in terms of the micropore structure, core/shell structure and nanostructure effects. - Highlights: • Microporous Ni/NiO nanoparticles are prepared by chemical dealloying method. • They possess micropores of 0.6–1.2 nm with a surface area of 68.9 m"2/g. • They show minimum microwave reflection coefficient of −49.1 dB and bandwidth of 5.8 GHz. • Microwave absorption mechanism is explained by micropore and core/shell structures.

  19. Synthesis of microporous Ni/NiO nanoparticles with enhanced microwave absorption properties

    Liu, Tong, E-mail: tongliu@buaa.edu.cn [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing, 100191 (China); Pang, Yu; Xie, Xiubo [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing, 100191 (China); Qi, Wen; Wu, Ying [China Iron & Steel Research Institute Group, Advanced Technology & Materials Co., Ltd, No.76 Xueyuannanlu, Haidian District, Beijing, 100081 (China); Kobayashi, Satoru [Faculty of Engineering, Iwate University, Ueda, Morioka, 020-8551 (Japan); Zheng, Jie; Li, Xingguo [Beijing National Laboratory for Molecular Sciences (BNLMS), The State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871 (China)

    2016-05-15

    The fabrication of microporous metal materials with many potential applications is challenging due to their high chemical activities and the difficulty in controlling the pore size. By adjusting the reaction condition and the composition of the Ni–Al nanoparticle precursor, we have successfully produced the microporous Ni nanoparticles (NPs) of 22 nm by chemical dealloying method. During the passivation process, the microporous Ni NPs covered with NiO shell are generated as the result of surface oxidation. The micropores range from 0.6 to 1.2 nm in diameter with a large surface area of 68.9 m{sup 2}/g. Due to the elimination of Al atoms during dealloying process, the crystalline size of the microporous Ni NPs is sharply decreased to 2–5 nm. The specific architecture offers the microporous Ni/NiO NPs a small microwave reflection coefficient (RC) and a wide absorption bandwidth (RC ≤ −10 dB) of −49.1 dB and 5.8 GHz, much better than the nonporous counterpart of −24.1 dB and 3.7 GHz. The enhanced microwave absorption performance has been interpreted in terms of the micropore structure, core/shell structure and nanostructure effects. - Highlights: • Microporous Ni/NiO nanoparticles are prepared by chemical dealloying method. • They possess micropores of 0.6–1.2 nm with a surface area of 68.9 m{sup 2}/g. • They show minimum microwave reflection coefficient of −49.1 dB and bandwidth of 5.8 GHz. • Microwave absorption mechanism is explained by micropore and core/shell structures.

  20. Geometric structures of thin film: Pt on Pd(110) and NiO on Ni(100)

    Warren, Oden L. [Iowa State Univ., Ames, IA (United States)

    1993-07-01

    This thesis is divided into 3 papers: dynamical low-energy electron- diffraction investigation of lateral displacements in topmost layer of Pd(110); determination of (1x1) and (1x2) structures of Pt thin films on Pd(110) by dynamical low-energy electron-diffraction analysis; and structural determination of a NiO(111) film on Ni(100) by dynamical low-energy electron-diffraction analysis.

  1. Fabrication and tensile properties of rapidly solidified Cu-10wt. %Ni alloy. [Cu-10Ni

    Baril, D; Angers, R; Baril, J [Dept. of Mining and Metallurgy, Laval Univ., Ste-Foy, Quebec (Canada)

    1992-10-15

    Cu-10wt.%Ni ribbons were produced by melt spinning and cut into small particles with a blade cutter mill. The powders were then hot consolidated to full density by hot pressing followed by hot extrusion. Tensile properties of the resulting pieces were measured. Cu-10wt.%Ni cast ingots were also hot extruded and mechanically tested to compare with the rapidly solidified alloy and to evaluate the possible benefits brought by the rapid solidification process.

  2. 59Ni and 63Ni separation from boric acid concentrates produced at NPP

    Fisera, O.

    2010-01-01

    Procedure for direct separation of radionickel from boric acid concentrate was developed. Quantitative separation from 100 mL of real concentrate on the column filled with 3 mL of PAN-DMG composite material was achieved. PAN-DMG material (dimethylglyoxime in porous beads of polyacrylonitrile) was compared with Ni Resin and DMG-PAN material exhibited higher sorption capacity for nickel than Ni Resin. (author)

  3. Valence electronic structure of Ni in Ni Si alloys from relative K X-ray intensity studies

    Kalayci, Y.; Aydinuraz, A.; Tugluoglu, B.; Mutlu, R. H.

    2007-02-01

    The Kβ-to-Kα X-ray intensity ratio of Ni in Ni 3Si, Ni 2Si and NiSi has been determined by energy dispersive X-ray fluorescence technique. It is found that the intensity ratio of Ni decreases from pure Ni to Ni 2Si and then increases from Ni 2Si to NiSi, in good agreement with the electronic structure calculations cited in the literature. We have also performed band structure calculations for pure Ni in various atomic configurations by means of linear muffin-tin orbital method and used this data with the normalized theoretical intensity ratios cited in the literature to estimate the 3d-occupation numbers of Ni in Ni-Si alloys. It is emphasized that investigation of alloying effect in terms of X-ray intensity ratios should be carried out for the stoichiometric alloys in order to make reliable and quantitative comparisons between theory and experiment in transition metal alloys.

  4. La Niña, El Niño, and Atlantic Hurricane Damages in the United States

    data discussed below), this definition results in 22 El Niño years, 29 neutral years, and 22 La Niña accounting for the most significant societal changes. To normalize past impacts data to 1997 values, losses , 169 and 186. Trenberth, K. E., 1997: The definition of El Niño. Bull. Amer. Meteor. Soc., 78, 2771

  5. Observations of defect structure evolution in proton and Ni ion irradiated Ni-Cr binary alloys

    Briggs, Samuel A., E-mail: sabriggs2@wisc.edu [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); Barr, Christopher M. [Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104 (United States); Pakarinen, Janne [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); SKC-CEN Belgian Nuclear Research Centre, Boeretang 200, B-2400 Mol (Belgium); Mamivand, Mahmood [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); Hattar, Khalid [Sandia National Laboratories, PO Box 5800, Albuquerque, NM 87185 (United States); Morgan, Dane D. [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); Taheri, Mitra [Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104 (United States); Sridharan, Kumar [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States)

    2016-10-15

    Two binary Ni-Cr model alloys with 5 wt% Cr and 18 wt% Cr were irradiated using 2 MeV protons at 400 and 500 °C and 20 MeV Ni{sup 4+} ions at 500 °C to investigate microstructural evolution as a function of composition, irradiation temperature, and irradiating ion species. Transmission electron microscopy (TEM) was applied to study irradiation-induced void and faulted Frank loops microstructures. Irradiations at 500 °C were shown to generate decreased densities of larger defects, likely due to increased barriers to defect nucleation as compared to 400 °C irradiations. Heavy ion irradiation resulted in a larger density of smaller voids when compared to proton irradiations, indicating in-cascade clustering of point defects. Cluster dynamics simulations were in good agreement with the experimental findings, suggesting that increases in Cr content lead to an increase in interstitial binding energy, leading to higher densities of smaller dislocation loops in the Ni-18Cr alloy as compared to the Ni-5Cr alloy. - Highlights: • Binary Ni-Cr alloys were irradiated with protons or Ni ions at 400 and 500 °C. • Higher irradiation temperatures yield increased size, decreased density of defects. • Hypothesize that varying Cr content affects interstitial binding energy. • Fitting CD models for loop nucleation to data supports this hypothesis.

  6. Study of the magnetic anisotropy in Ni/Cu and Ni/glass thin films

    Cherif, S.-M. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse, 93340 (France); Layadi, A. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria)]. E-mail: a_layadi@yahoo.fr; Ben Youssef, J. [Laboratoire de Magnetisme de Bretagne, U.B.O., Brest 29238 (France); Nacereddine, C. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria); Roussigne, Y. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse, 93340 (France)

    2007-01-01

    The magnetic properties of evaporated Ni/Cu and Ni/glass thin films have been investigated by means of the vibrating sample magnetometer (VSM), the Brillouin light scattering (BLS) and magnetic force microscopy (MFM). The Ni thickness, t, ranges from 31 to 165 nm. The second- and fourth-order magnetic anisotropy constants, K {sub 1} and K {sub 2}, have been included; for the Ni/Cu series, K {sub 1} was found to decrease from 1.0x10{sup 6} to 0.18x10{sup 6} erg/cm{sup 3} as t increases from 31 to 165 nm, while K {sub 2} increased from 0.24x10{sup 6} to 0.8x10{sup 6} erg/cm{sup 3}. Over all the thickness range, the magnetization easy axis is in plane. For thinner films, there is a good agreement between anisotropy constant values inferred from VSM and BLS. Stripe domains were observed for t{>=}165 nm in Ni/glass and t{>=}90 nm in Ni/Cu.

  7. Study of the magnetic anisotropy in Ni/Cu and Ni/glass thin films

    Cherif, S.-M.; Layadi, A.; Ben Youssef, J.; Nacereddine, C.; Roussigne, Y.

    2007-01-01

    The magnetic properties of evaporated Ni/Cu and Ni/glass thin films have been investigated by means of the vibrating sample magnetometer (VSM), the Brillouin light scattering (BLS) and magnetic force microscopy (MFM). The Ni thickness, t, ranges from 31 to 165 nm. The second- and fourth-order magnetic anisotropy constants, K 1 and K 2 , have been included; for the Ni/Cu series, K 1 was found to decrease from 1.0x10 6 to 0.18x10 6 erg/cm 3 as t increases from 31 to 165 nm, while K 2 increased from 0.24x10 6 to 0.8x10 6 erg/cm 3 . Over all the thickness range, the magnetization easy axis is in plane. For thinner films, there is a good agreement between anisotropy constant values inferred from VSM and BLS. Stripe domains were observed for t≥165 nm in Ni/glass and t≥90 nm in Ni/Cu

  8. Effect of Ni4Ti3 precipitation on martensitic transformation in Ti-Ni

    Zhou, N.; Shen, C.; Wagner, M.F.-X.; Eggeler, G.; Mills, M.J.; Wang, Y.

    2010-01-01

    Precipitation of Ni 4 Ti 3 plays a critical role in determining the martensitic transformation path and temperature in Ni-Ti shape memory alloys. In this study, the equilibrium shape of a coherent Ni 4 Ti 3 precipitate and the concentration and stress fields around it are determined quantitatively using the phase field method. Most recent experimental data on lattice parameters, elastic constants, precipitate-matrix orientation relationship and thermodynamic database are used as model inputs. The effects of the concentration and stress fields on subsequent martensitic transformations are analyzed through interaction energy between a nucleating martensitic particle and the existing microstructure. Results indicate that R-phase formation prior to B19' phase could be attributed to both direct elastic interaction and stress-induced spatial variation in concentration near Ni 4 Ti 3 precipitates. The preferred nucleation sites for the R-phase are close to the broad side of the lenticular-shaped Ni 4 Ti 3 precipitates, where tension normal to the habit plane is highest, and Ni concentration is lowest.

  9. Fabrication of metallic alloy powder (Ni{sub 3}Fe) from Fe–77Ni scrap

    Seo, Inseok [ES Materials Research Center, Research Institute of Industrial Science and Technology, Incheon 406-840 (Korea, Republic of); Shin, Shun-Myung [Extractive Metallurgy Department, Korea Institute of Geoscience and Mineral Resources, Deajeon 305-350 (Korea, Republic of); Ha, Sang-An [Department of Environmental Engineering, Silla University, Busan 46958 (Korea, Republic of); Wang, Jei-Pil, E-mail: jpwang@pknu.ac.kr [Department of Metallurgical Engineering, Pukyong National University, Busan 608-739 (Korea, Republic of)

    2016-06-15

    The oxidation behavior of Fe–77Ni alloy scrap was investigated at an oxygen partial pressure of 0.2 atm and temperatures ranging from 400 °C to 900 °C. The corresponding oxidation rate increased with increasing temperature and obeyed the parabolic rate law, as evidenced by its linear proportionality to the temperature. In addition, surface morphologies, cross-sectional views, compositions, structural properties were examined by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). Diffusion through either the spinel structure or the NiO layer, which were both present in the alloy during oxidation at elevated temperatures, was deemed the rate-limiting step of the reaction. The oxide powder less than 10 μm was obtained from Fe–77Ni alloy scrap was obtained using ball-milling and sieving processes. In fact, 15 h of milling yielded a recovery ratio of 97%. Using hydrogen gas, the oxide powder was successfully reduced to an alloy powder of Ni{sub 3}Fe and reduction rates of ∼97% were achieved after 3 h at 1000 °C. - Highlights: • The oxidation behavior of Fe–77Ni alloy scrap was investigated. • The oxide powder less than 10 μm was obtained from Fe–77Ni alloy scrap. • Using hydrogen gas, the oxide powder was successfully reclaimed. • Reduction rates of ∼97% were achieved after 3 h at 1000 °C.

  10. Positron annihilation studies in CeNiIn and LaNiIn

    Ray, R.; Giri, S.; Sen, M.; Nambissan, P.M.G.; Ghoshray, K.; Ghoshray, A.; Sen, P.

    1997-01-01

    Doppler broadened positron annihilation spectral lineshape (DBPAS) and positron lifetime measurements in the temperature range 18-280 K have been performed in CeNiIn and LaNiIn systems. The nature of the temperature variations of the lifetime in both systems is almost similar in the whole temperature range studied, whereas the nature of the temperature variation of the S parameter in CeNiIn is similar to that in LaNiIn except in the temperature region 18-40 K. For the former system there is a dip around 20 K in the S parameter versus temperature curve. The lifetime versus T curve in both systems could be explained by the thermal expansion of the lattice. The S parameter versus T curve in LaNiIn could also be attributed to the thermal expansion of the lattice, whereas in CeNiIn the above mentioned dip seems an extra feature of the thermal expansion of the lattice. To understand this low temperature behaviour other results on the same system have been discussed. (orig.)

  11. Interfacial reaction of Ni{sub 3}Sn{sub 4} intermetallic compound in Ni/SnAg solder/Ni system under thermomigration

    Yang, Yi-Shan; Yang, Chia-Jung; Ouyang, Fan-Yi, E-mail: fyouyang@ess.nthu.edu.tw

    2016-07-25

    The growth of Ni{sub 3}Sn{sub 4} intermetallic compound (IMC) between liquid–solid interface in micro-scale Ni/SnAg/Ni system was investigated under a temperature gradient of 160 °C/cm at 260 °C on a hot plate. In contrast to a symmetrical growth of Ni{sub 3}Sn{sub 4} on both interfaces under isothermally annealed at 260 °C, the interfacial Ni{sub 3}Sn{sub 4} IMC exhibited asymmetric growth under a temperature gradient; the growth of Ni{sub 3}Sn{sub 4} at cold interface was faster than that at hot side because of temperature gradient induced mass migration of Ni atoms from the hot end toward the cold end. It was found that two-stage growth behavior of Ni{sub 3}Sn{sub 4} IMC under a temperature gradient. A growth model was established and growth kinetic analysis suggested that the chemical potential gradient controlled the growth of Ni{sub 3}Sn{sub 4} at stage I (0–120 min) whereas the dynamic equilibrium between chemical potential gradient and temperature gradient forces was attained at the hot end at stage II (120–210 min). When dynamic equilibrium was achieved at 260 °C, the critical length-temperature gradient product at the hot end was experimentally estimated to be 489.18 μm × °C/cm and the moving velocity of Ni{sub 3}Sn{sub 4} interface due to Ni consumption was calculated to be 0.134 μm/h. The molar heat of transport (Q*) of Ni atoms in molten SnAg solder was calculated to be +0.76 kJ/mol. - Highlights: • Interfacial reaction in Ni/SnAg solder/Ni system under thermal gradient. • Growth rate of Ni{sub 3}Sn{sub 4} at cold end is faster than that at hot end. • Critical length-temperature gradient product at hot end is 489.2 μm°C/cm at 260 °C. • Velocity of Ni{sub 3}Sn{sub 4} moving interface is 0.134 μm/h during dynamic equilibrium. • Molar heat of transport (Q*) of Ni in molten SnAg was +0.76 kJ/mol.

  12. Evaluation of the Antitumor Activity by Ni Nanoparticles with Verbascoside

    Mingyue Chen

    2013-01-01

    Full Text Available Verbascoside (VB has attracted a great deal of attention due to ITS pharmacological properties. In our study, we synthesized a multifunctional verbascoside coated Ni nanoparticles (VB-Ni. Transmission electron microscopy (TEM and high performance liquid chromatography (HPLC display the characteristics of VB-Ni nanoparticles. Compared with VB, VB-Ni has been proven to induce apoptosis and resist the growth of doxorubicin-resistant K562 cells in vitro and in vivo. Thus, VB-Ni nanoparticles can be thought of as an ideal mode of cancer treatment.

  13. A Study on Production of Carbon Nanotubes by CH4 Decomposition over LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4

    2001-01-01

    Carbon nanotubes (CNTs) of narrow size distribution can be abundantly produced in the catalytic decomposition of CH4 over pre-reduced LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4.The CNTs obtained were characterized by means of transmission electron microscopy (TEM).Thermal oxidation of CNTs in air was monitored thermogravimetrically (TG). The resultsrevealed that a lower La/Ni ratio of the catalysts would lead to a wider diameter distribution and a higher degree of graphitic nature.

  14. Thin NiTi Films Deposited on Graphene Substrates

    Hahn, S.; Schulze, A.; Böhme, M.; Hahn, T.; Wagner, M. F.-X.

    2017-03-01

    We present experimental results on the deposition of Nickel Titanium (NiTi) films on graphene substrates using a PVD magnetron sputter process. Characterization of the 2-4 micron thick NiTi films by electron microscopy, electron backscatter diffraction, and transmission electron microscopy shows that grain size and orientation of the thin NiTi films strongly depend on the type of combination of graphene and copper layers below. Our experimental findings are supported by density functional theory calculations: a theoretical estimation of the binding energies of different NiTi-graphene interfaces is in line with the experimentally determined microstructural features of the functional NiTi top layer.

  15. Properties of mechanically alloyed Mg-Ni-Ti ternary hydrogen storage alloys for Ni-MH batteries

    Ruggeri, Stéphane; Roué, Lionel; Huot, Jacques; Schulz, Robert; Aymard, Luc; Tarascon, Jean-Marie

    MgNiTi x, Mg 1- xTi xNi and MgNi 1- xTi x (with x varying from 0 to 0.5) alloys have been prepared by high energy ball milling and tested as hydrogen storage electrodes. The initial discharge capacities of the Mg-Ni-Ti ternary alloys are inferior to the MgNi electrode capacity. However, an exception is observed with MgNi 0.95Ti 0.05, which has an initial discharge capacity of 575 mAh/g compared to 522 mAh/g for the MgNi electrode. The Mg-Ni-Ti ternary alloys show improved cycle life compared to Mg-Ni binary alloys with the same Mg/Ni atomic ratio. The best cycle life is observed with Mg 0.5Ti 0.5Ni electrode which retains 75% of initial capacity after 10 cycles in comparison to 39% for MgNi electrodes, in addition to improved high-rate dischargeability (HRD). According to the XPS analysis, the cycle life improvement of the Mg 0.5Ti 0.5Ni electrode can be related to the formation of TiO 2 which limits Mg(OH) 2 formation. The anodic polarization curve of Mg 0.5Ti 0.5Ni electrode shows that the current related to the active/passive transition is much less important and that the passive region is more extended than for the MgNi electrode but the corrosion of the electrode is still significant. This suggests that the cycle life improvement would be also associated with a decrease of the particle pulverization upon cycling.

  16. Densities of molten Ni-(Cr, Co, W) superalloys

    XIAO Feng; YANG Ren-hui; FANG Liang; LIU Lan-xiao; ZHAO Hong-kai

    2008-01-01

    In order to obtain more accurate density for molten Ni-(Cr, Co, W) binary alloy, the densities of molten pure Ni and Ni-Cr, Ni-Co, Ni-W alloys were measured with a sessile drop method. It is found that the measured densities of molten pure Ni and Ni-Cr, Ni-Co, Ni-W alloys decrease with increasing temperature in the experimental temperature range. The density of alloys increases with increasing W and Co concentrations while it decreases with increasing Cr concentration in the alloy at 1 773-1 873 K. The molar volume of Ni-based alloys increases with increasing W concentration while it decreases with increasing Co concentration. The effect of Cr concentration on the molar volume of the alloy is little in the studied concentration range. The accommodation among atomic species was analyzed. The deviation of molar volume from ideal mixing shows an ideal mixing of Ni-(Cr, Co, W) binary alloys.

  17. Spectroscopic investigation of Ni speciation in hardened cement paste.

    Vespa, M; Dähn, R; Grolimund, D; Wieland, E; Scheidegger, A M

    2006-04-01

    Cement-based materials play an important role in multi-barrier concepts developed worldwide for the safe disposal of hazardous and radioactive wastes. Cement is used to condition and stabilize the waste materials and to construct the engineered barrier systems (container, backfill, and liner materials) of repositories for radioactive waste. In this study, Ni uptake by hardened cement paste has been investigated with the aim of improving our understanding of the immobilization process of heavy metals in cement on the molecular level. X-ray absorption spectroscopy (XAS) coupled with diffuse reflectance spectroscopy (DRS) techniques were used to determine the local environment of Ni in cement systems. The Ni-doped samples were prepared at two different water/cement ratios (0.4, 1.3) and different hydration times (1 hour to 1 year) using a sulfate-resisting Portland cement. The metal loadings and the metal salts added to the system were varied (50 up to 5000 mg/kg; NO3(-), SO4(2-), Cl-). The XAS study showed that for all investigated systems Ni(ll) is predominantly immobilized in a layered double hydroxide (LDH) phase, which was corroborated by DRS measurements. Only a minor extent of Ni(ll) precipitates as Ni-hydroxides (alpha-Ni(OH)2 and beta-Ni(OH)2). This finding suggests that Ni-Al LDH, rather than Ni-hydroxides, is the solubility-limiting phase in the Ni-doped cement system.

  18. Design and fabrication of Ni nanowires having periodically hollow nanostructures.

    Sada, Takao; Fujigaya, Tsuyohiko; Nakashima, Naotoshi

    2014-10-07

    We propose a concept for the design and fabrication of metal nanowires having periodically hollow nanostructures inside the pores of an anodic aluminum oxide (AAO) membrane using a sacrificial metal. In this study, nickel (Ni) and silver (Ag) were used as the base metal and the sacrificial metal, respectively. Alternating an applied potential between -0.4 and -1.0 V provided alternatively deposited Ni and Ag segments in a Ni-Ag 'barcode' nanowire with a diameter of 18 or 35 nm. After etching away the Ag segments, we fabricated Ni nanowires with nanopores of 12 ± 5.3 nm. Such nanostructure formation is explained by the formation of a Ni shell layer over the surface of the Ag segments due to the strong affinity of Ni(2+) for the interior surfaces of AAO. The Ni shell layer allows the Ni segments to remain even after dissolution of the Ag segments. Because the electroplating conditions can be easily controlled, we could carefully adjust the size and pitch of the periodically hollow nanospaces. We also describe a method for the fabrication of Ni nanorods by forming an Ag shell instead of a Ni shell on the Ni-Ag barcode nanowire, in which the interior of the AAO surfaces was modified with a compound bearing a thiol group prior to electroplating.

  19. Ductility of Ni3Al doped with substitutional elements

    Hanada, S.; Chiba, A.; Guo, H.Z.; Watanabe, S.

    1993-01-01

    This paper reports on ductility of B-free Ni 3 Al alloys. Recrystallized Ni 3 Al binary alloys with Ni-rich compositions show appreciable ductility when an environmental effect is eliminated, while the alloys with stoichiometric and Al-rich compositions remain brittle. The ductility in the Ni-rich Ni 3 Al alloys is associated with low ordering energy. The additions of ternary elements, which are classified as γ formers, ductilize ternary Ni 3 Al alloys(Ni-23 at% Al-2 at% X, X = Pd, Pt, Cu and Co), whereas the additions of γ' formers embrittle ternary Ni 3 Al alloys(Ni-23 at% Al-2 at% X, X = Ta, Mo, Nb, Zr, Hf, V, Ti and Si). The additions of small amounts (less than 1 at%) of γ' formers such as Zr and Hf also ductilize as-cast ternary Ni 3 Al alloys. Ductility of Ni 3 Al alloys doped with substitutional elements is discussed in terms of ordering energy and microstructure

  20. CO2 activation on bimetallic CuNi nanoparticles

    Natalie Austin

    2016-10-01

    Full Text Available Density functional theory calculations have been performed to investigate the structural, electronic, and CO2 adsorption properties of 55-atom bimetallic CuNi nanoparticles (NPs in core-shell and decorated architectures, as well as of their monometallic counterparts. Our results revealed that with respect to the monometallic Cu55 and Ni55 parents, the formation of decorated Cu12Ni43 and core-shell Cu42Ni13 are energetically favorable. We found that CO2 chemisorbs on monometallic Ni55, core-shell Cu13Ni42, and decorated Cu12Ni43 and Cu43Ni12, whereas, it physisorbs on monometallic Cu55 and core-shell Cu42Ni13. The presence of surface Ni on the NPs is key in strongly adsorbing and activating the CO2 molecule (linear to bent transition and elongation of C˭O bonds. This activation occurs through a charge transfer from the NPs to the CO2 molecule, where the local metal d-orbital density localization on surface Ni plays a pivotal role. This work identifies insightful structure-property relationships for CO2 activation and highlights the importance of keeping a balance between NP stability and CO2 adsorption behavior in designing catalytic bimetallic NPs that activate CO2.

  1. NiCo2S4 nanosheet-decorated 3D, porous Ni film@Ni wire electrode materials for all solid-state asymmetric supercapacitor applications.

    Saravanakumar, Balasubramaniam; Jayaseelan, Santhana Sivabalan; Seo, Min-Kang; Kim, Hak-Yong; Kim, Byoung-Suhk

    2017-12-07

    Wire type supercapacitors with high energy and power densities have generated considerable interest in wearable applications. Herein, we report a novel NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire electrode for high performance supercapacitor application. In this work, a facile method is introduced to fabricate a 3D, porous Ni film deposited on a Ni wire as a flexible electrode, followed by decoration with NiCo 2 S 4 as an electroactive material. The fabricated NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire electrode displays a superior performance with an areal and volumetric capacitance of 1.228 F cm -2 and 199.74 F cm -3 , respectively, at a current density of 0.2 mA cm -1 with a maximum volumetric energy and power density (E V : 6.935 mW h cm -3 ; P V : 1.019 W cm -3 ). Finally, the solid state asymmetric wire type supercapacitor is fabricated using the fabricated NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire as a positive electrode and N-doped reduced graphene oxide (N-rGO) as a negative electrode and this exhibits good areal and volumetric capacitances of C A : 0.12 F cm -2 and C V : 19.57 F cm -2 with a higher rate capability (92%). This asymmetric wire type supercapacitor demonstrates a low leakage current and self-discharge with a maximum volumetric energy (E V : 5.33 mW h cm -3 ) and power (P V : 855.69 mW cm -3 ) density.

  2. Surface morphology and electronic structure of Ni/Ag(100)

    Hite, D. A.; Kizilkaya, O.; Sprunger, P. T.; Howard, M. M.; Ventrice, C. A. Jr.; Geisler, H.; Zehner, D. M.

    2000-01-01

    The growth morphology and electronic structure of Ni on Ag(100) has been studied with scanning tunneling microscopy (STM) and synchrotron based angle resolved photoemission spectroscopy. At deposition temperatures at or below 300 K, STM reveals Ni cluster growth on the surface along with some subsurface growth. Upon annealing to 420 K, virtually all Ni segregates into the subsurface region forming embedded nanoclusters. The electronic structure of Ni d bands in the unannealed surface shows dispersion only perpendicular to the surface whereas the annealed surface has Ni d bands that exhibit a three-dimensional-like structure. This is a result of the increased Ni d-Ag sp hybridization bonding and increased coordination of the embedded Ni nanoclusters. (c) 2000 American Vacuum Society

  3. Measurement and analyses of molten Ni-Co alloy density

    XIAO Feng; K. MUKAI; FANG Liang; FU Ya; YANG Ren-hui

    2006-01-01

    With the advent of powerful mathematical modeling techniques for material phenomena, there is renewed interest in reliable data for the density of the Ni-based superalloys. Up to now, there has been few report on the density of molten Ni-Co alloy.In order to obtain more accurate density data for molten Ni-Co alloy, the density of molten Ni-Co alloy was measured with a modified sessile drop method, and the accommodation of different atoms in molten Ni-Co alloy was analyzed. The density of alloy is found to decrease with increasing temperature and Co concentration in the alloy. The molar volume of molten Ni-Co alloy increases with increasing Co concentration. The molar volume of Ni-Co alloy determined shows a positive deviation from the linear molar volume, and the deviation of molar volume from ideal mixing increases with increasing Co concentration over the experimental concentration range.

  4. In situ NiTi/Nb(Ti) composite

    Jiang, Daqiang; Cui, Lishan; Jiang, Jiang; Zheng, Yanjun

    2013-01-01

    Graphical abstract: - Highlights: • In situ NiTi/Nb(Ti) composites were fabricated. • The transformation temperature was affected by the mixing Ti:Ni atomic ratios. • The NiTi component became micron-scale lamella after forging and rolling. • The composite exhibited high strength and high damping capacity. - Abstract: This paper reports on the creation of a series of in situ NiTi/Nb(Ti) composites with controllable transformation temperatures based on the pseudo-binary hypereutectic transformation of NiTi–Nb system. The composite constituent morphology was controlled by forging and rolling. It is found that the thickness of the NiTi lamella in the composite reached micron level after the hot-forging and cold-rolling. The NiTi/Nb(Ti) composite exhibited high damping capacity as well as high yield strength

  5. Ni3d-Gd4f correlation effects on the magnetic behaviour of GdNi

    Paulose, P L [Tata Inst. of Fundamental Research, Bombay (India); Patil, Sujata [Tata Inst. of Fundamental Research, Bombay (India); Mallik, R [Tata Inst. of Fundamental Research, Bombay (India); Sampathkumaran, E V [Tata Inst. of Fundamental Research, Bombay (India); Nagarajan, V [Tata Inst. of Fundamental Research, Bombay (India)

    1996-07-01

    The results of magnetization and heat-capacity measurements on the alloys, Gd{sub 1-x}Y{sub x}Ni (x=0.0, 0.25, 0.5, 0.75 and 0.9) are reported. The data suggest that there is a Gd induced magnetic moment on Ni, which may in turn enhance Gd-Gd exchange interaction strength in GdNi. The induced moment (on Ni) apparently exhibits itinerant ferromagnetism in the magnetically ordered state of GdNi. (orig.).

  6. Effects of Bond Coating on NiCrBSi-Mo Composite Functional Coating Properties in Plasma Spraying NiCrBSi-Mo/Ni Coating

    DU Ji-yu; LI Fang-yi; LU Hai-yang; SHANG Jian-tong; LI Zhen

    2017-01-01

    Nickel-based bond coating and composite functional coating were sprayed on leaf blade steel material FV520B successively by using air plasma spraying system. NiCrBSi-Mo powder deposition rate, coating porosity, bonding strength and surface hardness were tested. The results indicate that, for the NiCrBSi-Mo/Ni coating, bond coating with 180-220μm thickness can improve NiCrBSi-Mo powder deposition rate while the surface coating with lower porosity, higher bonding strength and high hardness is p...

  7. Thermodynamic characterization of Ni3TeO6, Ni2Te3O8 and NiTe2O5

    Dawar, Rimpi; Babu, R.; Ananthasivan, K.; Anthonysamy, S.

    2017-09-01

    Measurement of vapour pressure of TeO2(g) over the biphasic mixture Ni3TeO6 (s) + NiO(s) in the temperature range 1143-1272 K was carried out using transpiration-thermogravimetric technique (TTG). Gibbs energy of formation of Ni3TeO6 was obtained from the temperature dependence of vapour pressure of TeO2 (g) generated by the incongruent vapourisation reaction, Ni3TeO6 (s) → NiO(s) + TeO2 (g) + 1/2 O2 in the temperature range 1143-1272 K. An isoperibol type drop calorimeter was used to measure the enthalpy increments of Ni3TeO6, Ni2Te3O8 and NiTe2O5. Thermodynamic functions viz., heat capacity, entropy and Gibbs energy functions of these compounds were derived from the experimentally measured enthalpy increment values. Third-law analysis was carried out to ascertain absence of temperature dependent systematic errors in the measurement of vapour pressure of TeO2 (g). A value of -1265.1 ± 1.5 kJ mol-1 was obtained for Δ Hf,298K o (Ni3TeO6) using third-law analysis.

  8. Structural and magnetic properties of Ni-Zn and Ni-Zn-Co ferrites

    Knyazev, A.V., E-mail: knyazevav@gmail.com [N.I. Lobachevsky State University of Nizhni Novgorod, Gagarin Prospekt 23/2, 603950 Nizhni Novgorod (Russian Federation); Zakharchuk, I.; Lähderanta, E. [Lappeenranta University of Technology, P.O. Box 20, FI-53851 Lappeenranta (Finland); Baidakov, K.V.; Knyazeva, S.S. [N.I. Lobachevsky State University of Nizhni Novgorod, Gagarin Prospekt 23/2, 603950 Nizhni Novgorod (Russian Federation); Ladenkov, I.V. [Joint-stock Company “Research and Production Company “Salut”, Nizhni Novgorod (Russian Federation)

    2017-08-01

    Highlights: • Ni-Zn and Ni-Zn-Co ferrite powders were prepared by the solid-state reaction at 1073 K. • The room temperature saturation magnetizations are 59.7 emu/g for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 57.1 emu/g for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. • The coercivity of the samples is found to be much larger than that of bulk ferrites and increases with Co introduction. • The temperature dependences of magnetization exhibit large spin frustration and spin-glass-like behavior. - Abstract: Ni-Zn and Ni-Zn-Co ferrite powders with nominal compositions Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4} were prepared by the solid-state reaction synthesis with periodic regrinding during the calcination at 1073 K. The structure of Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4} was refined assuming space group F d-3m. Scanning electron microscopy revealed the average sizes of the crystalline ferrite particles are 130–630 nm for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 140–350 nm for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. The room temperature saturation magnetizations are 59.7 emu/g for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 57.1 emu/g for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. The coercivity of the samples is found to be much larger than that of bulk ferrites and increases with Co introduction. The Curie temperature tends to increase upon Zn substitution by Co, as well. The temperature dependences of magnetization measured using zero-field cooled and field cooled protocols exhibit large spin frustration and spin-glass-like behavior.

  9. Anti-corrosive and anti-microbial properties of nanocrystalline Ni-Ag coatings

    Raghupathy, Y.; Natarajan, K.A.; Srivastava, Chandan, E-mail: csrivastava@materials.iisc.ernet.in

    2016-04-15

    Graphical abstract: - Highlights: • Electrodeposition yielded phase-segregated, nanocrystalline Ni-Ag coatings. • Ni-Ag alloys exhibited smaller Ni crystals compared to pure Ni. • Ultra fine Ni grains of size 12–14 nm favoured Ni-Ag solid solution. • Nanocrystalline Ag resisted bio-fouling by Sulphate Reducing bacteria. • Ni-Ag outperformed pure Ni in corrosion and bio-corrosion tests. - Abstract: Anti-corrosive and anti-bacterial properties of electrodeposited nanocrystalline Ni-Ag coatings are illustrated. Pure Ni, Ni-7 at.% Ag, & Ni-14 at.% Ag coatings were electrodeposited on Cu substrate. Coating consisted of Ni-rich and Ag-rich solid solution phases. With increase in the Ag content, the corrosion resistance of the Ni-Ag coating initially increased and then decreased. The initial increase was due to the Ni-Ag solid solution. The subsequent decrease was due to the increased galvanic coupling between the Ag-rich and Ni-rich phases. For all Ag contents, the corrosion resistance of the Ni-Ag coating was higher than the pure Ni coating. Exposure to Sulphate Reducing Bacteria (SRB) revealed that the extent of bio-fouling decreased with increase in the Ag content. After 2 month exposure to SRB, the Ni-Ag coatings demonstrated less loss in corrosion resistance (58% for Ni-7 at.% Ag and 20% for Ni-14 at.% Ag) when compared pure Ni coating (115%).

  10. Niños y niñas como cuidadores familiares

    María Rosa Estupiñán Aponte

    2015-01-01

    Full Text Available En el contexto familiar, el cuidado de otra persona por parte de niños y niñas constituye un terreno inexplorado tanto en su significado como en las implicaciones que podrían darse en el proceso. Aunque históricamente se ha asignado el cuidado familiar a las mujeres generando condiciones de inequidad, incrementada con los cambios sociales de los últimos tiempos, es necesario reconocer que en muchos hogares niños y niñas se han visto obligados a desempeñar esta labor sin la preparación ni las destrezas necesarias. Desde una perspectiva de género, el artículo busca evidenciar esta situación mediante la revisión de los abordajes que sobre el tema se han hecho en países de Europa y Norteamérica, así como el análisis de información obtenida a partir de las Encuestas de Hogares y Uso del Tiempo (EUT en algunos países de Latinoamérica. Se establece la forma como las problemáticas sociales inciden en las dinámicas, tipo de tareas y responsabilidades que deben asumir niños y niñas en los hogares, mostrando delgados límites entre la colaboración al interior de las familias, la transmisión cultural de roles y funciones y las actividades que podrían incidir negativamente en su crecimiento y el ejercicio de sus derechos.

  11. Estilos de vida saludables de niños, niñas y adolescentes

    Lilia Campo-Ternera

    2017-01-01

    Full Text Available Objetivo: Describir los estilos de vida saludables de niños, niñas y adolescentes de Barranquilla. Materiales y métodos: Estudio descriptivo de corte transversal en 991 niños, niñas y ado - lescentes. Se evaluó la actividad física mediante los cuestionarios de Actividad Física para Adolescentes y para niños escolares; se aplicó una encuesta que midió los conocimientos y prácticas de los escolares sobre salud bucal, lavado de manos, consumo de frutas y verduras y cuidado postural; la Lista de Chequeo “Mi Vida en la Escuela”, la cual evalúa los índices de “bullying” y agresión; y la inteligencia emocional a través dela escala TMMS -24. Resultados: El 65,4 % se categoriza como inactivos físicamente. Solo el 14,7% de los estudiantes reconoce que el peso máximo del bolso es el 10 % de su peso corporal; el 34,1 % cambia el cepillo de dientes cada 3 meses, como lo recomiendan los expertos, y 48,4 % se cepilla los dientes entre 2 y 3 veces al día. El 16,6 % no se lava las manos antes y después de ir al baño y 9,4 % no lo hace antes y después de las comidas; el 17,5 % no tiene un buen consumo de verduras y frutas; y se encontró un Índice de “bullying” en el 55,6 % de los participantes. Conclusión: Los anteriores resultados obligan a plantear intervenciones que incrementen las prácticas saludables en niños, niñas y adolescentes.

  12. Electrochemical properties of the ball-milled LaMg10NiMn alloy with Ni powders

    Wang Yi; Wang Xin; Gao Xueping; Shen Panwen

    2008-01-01

    The electrochemical characteristics of the ball-milled LaMg 10 NiMn alloys with Ni powders were investigated. It was found that the ball-milled LaMg 10 NiMn + 150 wt.% Ni composite exhibited higher first discharge capacity and better cycle performance. By means of the analysis of electrochemical impedance spectra (EIS), it was shown that the existence of manganese in LaMg 10 NiMn alloy increased the electrocatalytic activity due to its catalytic effect, and destabilized metal hydrides, and so reduced the hydrogen diffusion resistance. These contributed to the higher discharge capacity of the ball-milled LaMg 10 NiMn-Ni composite. According to the analytical results of X-ray diffraction (XRD), EIS and steady-state polarization (SSP) experiments, the inhibition of metal corrosion is not the main reason for the better cycle performance. The main reason is that the electrochemical reaction resistance of the ball-milled LaMg 10 NiMn-Ni composite is always lower than that of the ball-milled LaMg 10 Ni 2 -Ni composite because the former one contains manganese, which is a catalyst for the electrode reaction

  13. High-frequency permeability of electroplated CoNiFe and CoNiFe-C alloys

    Rhen, Fernando M.F.; McCloskey, Paul; O'Donnell, Terence; Roy, Saibal

    2008-01-01

    We have investigated CoNiFe and CoNiFe-C electrodeposited by pulse reverse plating (PRP) and direct current (DC) techniques. CoNiFe(PRP) films with composition Co 59.4 Fe 27.7 Ni 12.8 show coercivity of 95 A m -1 (1.2 Oe) and magnetization saturation flux (μ 0 M s ) of 1.8 T. Resistivity of CoNiFe (PRP) is about 24 μΩ cm and permeability remains almost constant μ r ' ∼475 up to 30 MHz with a quality factor (Q) larger than 10. Additionally, the permeability spectra analysis shows that CoNiFe exhibits a classical eddy current loss at zero bias field and ferromagnetic resonance (FMR) when biased with 0.05 T. Furthermore, a crossover between eddy current and FMR loss is observed for CoNiFe-PRP when baised with 0.05 T. DC and PRP plated CoNiFe-C, which have resistivity and permeability of 85, 38 μΩ cm, μ r '=165 and 35 with Q>10 up to 320 MHz, respectively, showed only ferromagnetic resonance losses. The ferromagnetic resonance peaks in CoNiFe and CoNiFe-C are broad and resembles a Gaussian distribution of FMR frequencies. The incorporation of C to CoNiFe reduces eddy current loss, but also reduces the FMR frequency

  14. Corrosive sliding wear behavior of laser clad Mo2Ni3Si/NiSi intermetallic coating

    Lu, X.D.; Wang, H.M.

    2005-01-01

    Many ternary metal silicides such as W 2 Ni 3 Si, Ti 2 Ni 3 Si and Mo 2 Ni 3 Si with the topologically closed-packed (TCP) hP12 MgZn 2 type Laves phase crystal structure are expected to have outstanding wear and corrosion resistance due to their inherent high hardness and sluggish temperature dependence and strong atomic bonds. In this paper, Mo 2 Ni 3 Si/NiSi intermetallic coating was fabricated on substrate of an austenitic stainless steel AISI321 by laser cladding using Ni-Mo-Si elemental alloy powders. Microstructure of the coating was characterized by optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD) and energy dispersive X-ray analysis (EDS). Wear resistance of the coating is evaluated under corrosive sliding wear test condition. Influence of corrosion solutions on the wear resistance of the coating was studied and the wear mechanism was discussed based on observations of worn surface morphology. Results showed that the laser clad Mo 2 Ni 3 Si/NiSi composite coating have a fine microstructure of Mo 2 Ni 3 Si primary dendrites and the interdendritic Mo 2 Ni 3 Si/NiSi eutectics. The coating has excellent corrosive wear resistance compared with austenitic stainless steel AISI321 under acid, alkaline and saline corrosive environments

  15. Magnetic properties of two new compounds: Pr2Ni3Si5 and Ho2Ni3Si5

    Mazumdar, C.; Padalia, B.D.; Godart, C.

    1994-01-01

    Formation of two more new materials, Pr 2 Ni 3 Si 5 and Ho 2 Ni 3 Si 5 , of the series, R 2 Ni 3 Si 5 (R = rare earth and Y) and their magnetic properties are reported here. These materials crystallize in the orthorhombic U 2 Co 3 Si 5 -type structure (space group Ibam). Magnetic susceptibility measurement in the temperature range 5 K--300 K show that the compound Pr 2 Ni 3 Si 5 order antiferromagnetically at T N ∼ 8.5 K and Ho 2 Ni 3 Si 5 at ∼ 6 K. Considering T N (Gd 2 Ni 3 Si 5 ) ∼ 15 K, T N (Pr 2 Ni 3 Si 5 ) ∼ 8.5 K is rather high. The magnetic susceptibility of both of the materials, in the paramagnetic state, follows a Curie-Weiss law with effective moment close to that of the corresponding free trivalent rare earth ion

  16. Effect of Ni Core Structure on the Electrocatalytic Activity of Pt-Ni/C in Methanol Oxidation

    Vladimir Linkov

    2013-07-01

    Full Text Available Methanol oxidation catalysts comprising an outer Pt-shell with an inner Ni-core supported on carbon, (Pt-Ni/C, were prepared with either crystalline or amorphous Ni core structures. Structural comparisons of the two forms of catalyst were made using transmission electron microscopy (TEM, X-ray diffraction (XRD and X-ray photoelectron spectroscopy (XPS, and methanol oxidation activity compared using CV and chronoamperometry (CA. While both the amorphous Ni core and crystalline Ni core structures were covered by similar Pt shell thickness and structure, the Pt-Ni(amorphous/C catalyst had higher methanol oxidation activity. The amorphous Ni core thus offers improved Pt usage efficiency in direct methanol fuel cells.

  17. Hard X-ray MCD in GdNi/sub 5/ and TbNi/sub 5/ single crystals

    Galera, R M

    1999-01-01

    XMCD experiments have been performed at the R L/sub 2,3/ and Ni K- edges on magnetically saturated single crystals of GdNi/sub 5/ and Tb Ni/sub 5/ ferromagnetic compounds. The spectra present huge and well structured dichroic $9 signals at both the R L/sub 2,3/ and the Ni K- edges. Structures from the quadrupolar (2p to 4f) transitions are clearly observed at the R L/sub 2,3/-edges. Though Ni is not magnetic, large intensities, up to 0.4, are measured at the $9 Ni K- edge. The Ni K-edge XMCD shows a three-peak structure which intensities dependent on the rare earth. (7 refs).

  18. Electrochemically induced transformation of NiS nanoparticles into Ni(OH)2 in KOH aqueous solution toward electrochemical capacitors

    Hou Linrui; Yuan Changzhou; Li Diankai; Yang Long; Shen Laifa; Zhang Fang; Zhang Xiaogang

    2011-01-01

    Highlights: → NiS is synthesized by means of the H 2 O/CS 2 interface under hydrothermal treatment. → NiS itself owns poor electrochemical capacitance in 2 M KOH solution. → NiS is electrochemically induced and transformed into electroactive Ni(OH) 2 . → Ni(OH) 2 is responsible for good energy storage of the NiS in the KOH solution. → The new formed Ni(OH) 2 delivers large energy density at high rates. - Abstract: Nickel sulfide nanoparticles (NPs) are first synthesized by virtue of a unique H 2 O/CS 2 interface under mild hydrothermal treatment. Electrochemical data reveals that the as-synthesized NiS NPs themselves own poor supercapacitive behavior at initial cyclic voltammetry (CV) cycles in 2 M KOH solution, while a specific capacitance of 893 F g -1 can be surprisingly obtained at a current density of 5 A g -1 just after continuous 320 CV cycles. X-ray diffraction and Fourier transform infrared techniques demonstrate that what is really responsible for the good electrochemical capacitance in the KOH aqueous solution is the new electrochemically formed Ni(OH) 2 phase, rather than NiS NPs themselves. The Ni(OH) 2 is slowly formed during the continuous CV cycling process, in which the electrochemically induced phase transformation from NiS to Ni(OH) 2 phase takes place. Furthermore, the new Ni(OH) 2 phase demonstrates the great ability of delivering large specific capacitance at high rates.

  19. Fe-Ni-bearing serpentines from the saprolite horizon of Caribbean Ni-laterite deposits: new insights from thermodynamic calculations

    Villanova-de-Benavent, Cristina; Domènech, Cristina; Tauler, Esperança; Galí, Salvador; Tassara, Santiago; Proenza, Joaquín A.

    2017-10-01

    Fe-Ni-bearing serpentine from the saprolite horizon is the main Ni ores in hydrous silicate-type Ni laterites and formed by chemical weathering of partially serpentinized ultramafic rocks under tropical conditions. During lateritization, Mg, Si, and Ni are leached from the surface and transported downwards. Fe2+ is oxidized to Fe3+ and fixed as insoluble Fe-oxyhydroxides (mostly goethite) that incorporate Ni. This Ni is later leached from goethite and incorporated in secondary serpentine and garnierite. As a result, a serpentine-dominated saprolite horizon forms over the ultramafic protolith, overlapped by a Fe-oxyhydroxide-dominated limonite horizon. The serpentine from the protolith (serpentine I) is of hydrothermal origin and yields similar Ni (0.10-0.62 wt.% NiO) and lower Fe (mostly 1.37-5.81 wt.% FeO) concentrations than the primary olivine. In contrast, Fe-Ni-bearing serpentine from the saprolite (serpentine II) shows significantly higher and variable Fe and Ni contents, typically ranging from 2.23 to 15.59 wt.% Fe2O3 and from 1.30 to 7.67 wt.% NiO, suggesting that serpentine get enriched in Fe and Ni under supergene conditions. This study presents detailed mineralogical, textural, and chemical data on this serpentine II, as well as new insights by thermodynamic calculations assuming ideal solution between Fe-, Ni- and Mg-pure serpentines. The aim is to assess if at atmospheric pressure and temperature Fe-Ni-bearing serpentine can be formed by precipitation. Results indicate that the formation of serpentine II under atmospheric pressure and temperature is thermodynamically supported, and pH, Eh, and the equilibrium constant of the reaction are the parameters that affect the results more significantly.

  20. Ni{sub 3}Al technology transfer

    Sikka, V.K.; Santella, M.L.; Alexander, D.J. [Oak Ridge National Laboratory, TN (United States)] [and others

    1995-05-01

    Ductile Ni{sub 3}Al and Ni{sub 3}Al-based alloys have been identified for a range of applications. These applications require the use of material in a variety of product forms such as sheet, plate, bar, tubing, piping, and castings. Although significant progress has been made in the melting, casting, and near-net-shape forming of nickel aluminides, some issues still remain. These include the need for (1)high-strength castable composition for turbochargers, furnace furniture, and hot-die applications; (2) castability (fluidity, hot-shortness, porosity, etc.); (3) weld reparability of castings; and (4) hot fabricability of cast ingots. All of the issues listed above can be {open_quotes}show stoppers{close_quotes} for the commercial application of nickel aluminides. This report describes work completed to address some of these issues during the fourth quarter of FY 1994.

  1. Ni{sub 3}Al technology transfer

    Sikka, V.K.; Viswanathan, S.; Santella, M.L. [Oak Ridge National Lab., TN (United States)] [and others

    1997-04-01

    Ductile Ni{sub 3}Al and Ni{sub 3}Al-based alloys have been identified for a range of applications. These applications require the use of material in a variety of product forms such as sheet, plate, bar, wire, tubing, piping, and castings. Although significant progress has been made in the melting, casting, and near-net-shape forming of nickel aluminides, some issues still remain. These include the need for: (1) high-strength castable composition for many applications that have been identified; (2) castability (mold type, fluidity, hot-shortness, porosity, etc.); (3) weld reparability of castings; and (4) workability of cast or powder metallurgy product to sheet, bar, and wire. The four issues listed above can be {open_quotes}show stoppers{close_quotes} for the commercial application of nickel aluminides. This report describes the work completed to address some of these issues during FY 1996.

  2. Internal chlorination of Ni-Cr alloys

    Berztiss, D.; Hennesen, K.; Grabke, H.J. [Max-Planck-Institut fuer Eisenforschung GmbH, Duesseldorf (Germany)

    1998-12-31

    In contrast to internal oxidation, sulfidation and carburization, very little information is available regarding internal chlorination, especially diffusion of chlorine in metallic alloys. This paper describes results of experiments on Ni-Cr alloys (<10 wt% Cr) exposed in an atmosphere containing radioactive HCl. The diffusion of chlorine in the alloy can be determined by measurement of residual {beta}-activity from the sample surface. Successively thin layers (0.5-10 {mu}m) of the alloy were removed by lapping and the surface activity was measured to obtain a depth profile. Both single and polycrystalline materials were tested. Through this work it should be determined if there is in fact solubility and diffusion of chlorine in Ni-based alloys as some authors have proposed or if the ingress of chlorine is mainly a grain boundary phenomenon. (orig.)

  3. Resonant Ni and Fe KLL Auger spectra photoexcited from NiFe alloys

    Koever, L.; Cserny, I.; Berenyi, Z.; Egri, S.; Novak, M.

    2005-01-01

    Complete text of publication follows. KLL Auger spectra of 3d transition metal atoms in solid environment, measured using high energy resolution, give an insight into the details of the local electronic structure surrounding the particular atoms emitting the signal Auger electrons. Fine tuning the energy of the exciting monochromatic photons across the K-absorption edge, features characteristic to resonant phenomena can be identified in the spectra. The shapes of the resonantly photoexcited KLL Auger spectra induced from 3d transition metals and alloys are well interpreted by the single step model of the Auger process, based on the resonant scattering theory. The peak shapes are strongly influenced by the 4p partial density of unoccupied electronic states around the excited atom. High energy resolution studies of KLL Auger spectra of 3d transition metals using laboratory X-ray sources, however, request very demanding experiments and yield spectra of limited statistical quality making the evaluation of the fine details in the spectra difficult. The Tunable High Energy XPS (THE- XPS) instrument at BW2 offers optimum photon x and energy resolution for spectroscopy of deep core Auger transitions. For the present measurements high purity polycrystalline Ni and Fe sheets as well as NiFe alloy samples of different compositions (Ni 80 Fe 20 , Ni 50 Fe 50 , Ni 20 Fe 80 ) were used. The surfaces of the samples were cleaned by in-situ argon ion sputtering. The measurements of the Ni and Fe KL 23 L 23 Auger spectra of the metal and alloy samples were performed with the THE-XPS instrument using high electron energy resolution (0.2 eV). In Fig.1, the measured Fe KL 23 L 23 spectrum, photoexcited at the Fe K absorption edge from Fe metal, is compared with the respective spectrum excited from a Ni 50 Fe 50 alloy. A significant broadening of the 1 D 2 peak and an enhancement of the spectral intensity at the low energy loss part of this peak observed in the alloy sample, while the

  4. Phase transitions in alloys of the Ni-Mo system

    Ustinovshikov, Y.; Shabanova, I.

    2011-01-01

    Graphical abstract: The structure of Ni-20 at.% Mo and Ni-25 at.% Mo alloys was studied by methods of TEM and XPS. It is shown that at high temperatures the tendency toward phase separation takes place in the alloys and crystalline bcc Mo particles precipitate in the liquid solution. At 900 deg. C and below, the tendency toward ordering leads to the dissolution of Mo particles and precipitation of the particles of Ni 3 Mo, Ni 2 Mo or Ni 4 Mo chemical compounds. Highlights: → 'Chemical' phase transition 'ordering-phase separation' is first discovered in alloys of the Ni-Mo system. → It is first shown that the phase separation in the alloys studied begins at temperatures above the liquidus one. → The formation of Ni 3 Mo from A1 has gone through the intervening stage of the Ni 4 Mo and Ni 2 Mo coexistence. - Abstract: The structure of Ni-20 at.% Mo and Ni-25 at.% Mo alloys heat treated at different temperatures was studied by the method of transmission electron microscopy. X-ray photoelectron spectroscopy was used to detect the sign of the chemical interaction between Ni and Mo atoms at different temperatures. It is shown that at high temperatures the tendency toward phase separation takes place. The system of additional reflections at positions {1 1/2 0} on the electron diffraction patterns testifies that the precipitation of crystalline bcc Mo particles begins in the liquid solution. At 900 deg. C and below, the tendency toward ordering leads to the precipitation of the particles of the chemical compounds. A body-centered tetragonal phase Ni 4 Mo (D1 a ) is formed in the Ni-20 at.% Mo alloy. In the Ni-25 at.% Mo alloy, the formation of the Ni 3 Mo (D0 22 ) chemical compound from the A1 solid solution has gone through the intervening stage of the Ni 4 Mo (D1 a ) and Ni 2 Mo (Pt 2 Mo) formation.

  5. Combining Ru, Ni and Ni(OH){sub 2} active sites for improving catalytic performance in benzene hydrogenation

    Zhu, Lihua, E-mail: lihuazhu@stu.xmu.edu.cn [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Sun, Hanlei; Zheng, Jinbao [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Yu, Changlin, E-mail: yuchanglinjx@163.com [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Zhang, Nuowei [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Shu, Qing [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Chen, Bing H., E-mail: chenbh@xmu.edu.cn [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)

    2017-05-01

    In this study, the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts were successfully prepared by the simple methods of hydrazine-reduction and galvanic replacement, where 0.04/0.96 and T represented the Ru/Ni atomic ratio and reducing temperature of the catalyst in N{sub 2}+10%H{sub 2}, respectively. The nanostructures of the Ru{sub 0.04}Ni{sub 0.96} nanoparticles in the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts were controlled by modulating their annealing temperature in N{sub 2}+10%H{sub 2} and characterized by an array of techniques, including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), scanning transmission electron microscopy energy dispersive X-ray spectroscopy (STEM-EDS) mapping and high-sensitivity low-energy ion scattering (HS-LEIS). The Ru{sub 0.04}Ni{sub 0.96}/C(30) catalyst, which was composed of Ru clusters or single atoms supported on Ni/Ni(OH){sub 2} nanoparticles, exhibited much better catalytic performance for benzene hydrogenation than the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts reduced at above 30 °C, such as Ru{sub 0.04}Ni{sub 0.96}/C(160) with the nanostructure of partial Ru{sub 0.04}Ni{sub 0.9} alloy and Ru{sub 0.04}Ni{sub 0.96}/C(280) with the nanostructure of complete Ru{sub 0.04}Ni{sub 0.9} alloy. The reason was that the synergistic effect of multiple active sites – Ru, Ni and Ni(OH){sub 2} sites was present in the Ru{sub 0.04}Ni{sub 0.96}/C(30) catalyst, where hydrogen was preferentially activated at Ru sites, benzene was probably activated at Ni(OH){sub 2} surface and Ni acted as a “bridge” for transferring activated H{sup ∗} species to activated benzene by hydrogen spillover effect, hydrogenating and forming product – cyclohexane. This study also provided a typical example to illustrate that the synergy effect of multiple active sites can largely improve the catalytic hydrogenation performance. - Highlights: • The Ru

  6. Imaging magnetic domains in Ni nanostructures

    Asenjo, A.; Jaafar, M.; Gonzalez, E.M.; Martin, J.I.; Vazquez, M.; Vicent, J.L.

    2007-01-01

    The study of nanomagnets is the subject of increasing scientific effort. The size, the thickness and the geometric shape of the elements determine the magnetic properties and then the domain configuration. In this work, we fabricated by electron-beam lithography the three different arrays of Ni nanostructures keeping the size, the thickness and also the distance constant between the elements but varying the geometry: square, triangular and circular. The domain structure of the nanomagnets is studied by magnetic force microscopy

  7. Determination of 59Ni in radioactive waste

    Fisera, O.; Sebesta, F.

    2010-01-01

    Composite material PAN-DMG, containing chelating agent dimethylglyoxime (DMG) immobilized in porous matrix of binding polymer polyacrylonitrile (PAN), was used for nickel separation and concentration. Method for preparation of 59 Ni source for low energy photon spectrometry was developed using homogeneous precipitation of nickel with DMG. The proposed method was tested with two types of real radioactive waste (boric acid concentrate from nuclear power plant (NPP) evaporator and spent ion exchanger from NPP). (author)

  8. Structural, electrical and magnetic properties of evaporated Ni/Cu and Ni/glass thin films

    Nacereddine, C. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria); Layadi, A. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria)]. E-mail: A_Layadi@yahoo.fr; Guittoum, A. [Centre de Recherche Nucleaire d' Alger (CRNA), Alger 16000 (Algeria); Cherif, S.-M. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse 93340 (France); Chauveau, T. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse 93340 (France); Billet, D. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse 93340 (France); Youssef, J. Ben [Laboratoire de Magnetisme de Bretagne, U.B.O., Brest 29238 (France); Bourzami, A. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria); Bourahli, M.-H. [Departement d' O. M. P., Universite Ferhat Abbas, Setif 19000 (Algeria)

    2007-01-25

    The structural, electrical and magnetic properties of Ni thin films evaporated onto glass and polycrystalline Cu substrates have been investigated. The Ni thickness ranges from 31 to 165 nm. X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM) have been used to study the structure and morphology of these systems. The Ni/Cu and Ni/glass thin films are found to be polycrystalline with a (1 1 1) texture. There is an overall increase of the grain size with increasing thickness. A negative strain was noted indicating that all the samples are under a compressive stress. Diffusion at the grain boundaries seems to be a major contribution to the electrical resistivity in this thickness range. Study of the hysteresis curves, obtained by vibrating sample magnetometer (VSM), indicates that all samples are characterized by an in-plane magnetization easy axis. Higher in-plane coercive fields seem to be associated with higher grain size, indicating that coercivity may be due to nucleation of reverse domains rather than pinning of domain walls. The saturation field and the squareness have been studied as a function of the Ni thickness.

  9. Participar como niña o niño en el mundo social

    Silvia Paulina Díaz

    2010-10-01

    Full Text Available En este artículo presento la participación como resultado de un trabajo investigativo realizado durante el año 2007, con niños y niñas escolarizados habitantes de la ciudad de Medellín, Colombia, cuyo objetivo fue analizar las representaciones sociales que ellos y ellas comparten sobre el ejercicio ciudadano. El análisis de la información tiene como ejes fundamentales, la salud colectiva, la sociología de la infancia y la participación en la niñez, en una aproximación que se realiza desde un enfoque cualitativo y etnográfico. En los hallazgos, sobresale cómo las niñas y niños se muestran preparados para ejercer su derecho a la participación como aspecto de sus vidas que se haría posible dentro del marco normativo existente, pero que aún no es asumido en prácticas sociales que los incluyan.

  10. HDO of Methyl Palmitate over Silica-Supported Ni Phosphides: Insight into Ni/P Effect

    Irina V. Deliy

    2017-10-01

    Full Text Available Two sets of silica-supported nickel phosphide catalysts with a nickel content of about 2.5 and 10 wt % and Ni/P molar ratio 2/1, 1/1 and 1/2 in each set, were prepared by way of a temperature-programmed reduction method using (Ni(CH3COO2 and ((NH42HPO4 as a precursor. The NixPy/SiO2 catalysts were characterized using chemical analysis N2 physisorption, XRD, TEM, 31P MAS NMR. Methyl palmitate hydrodeoxygenation (HDO was performed in a trickle-bed reactor at 3 MPa and 290 °C with LHSV ranging from 0.3 to 16 h−1. The Ni/P ratio was found to affect the nickel phosphide phase composition, POx groups content and catalytic properties in methyl palmitate HDO with the TOF increased along with a decline of Ni/P ratio and a growth of POx groups’ content. Taking into account the possible routes of methyl palmitate conversion (metal-catalyzed hydrogenolysis or acid-catalyzed hydrolysis, we proposed that the enhancement of acid POx groups’ content with the Ni/P ratio decrease provides an enhancement of the rate of methyl palmitate conversion through the acceleration of acid-catalyzed hydrolysis.

  11. Participar como niña o niño en el mundo social

    Silvia Paulina Díaz

    2010-01-01

    Full Text Available En este artículo presento la participación como resultado de un trabajo investigativo realizado durante el año 2007, con niños y niñas escolarizados habitantes de la ciudad de Medellín, Colombia, cuyo objetivo fue analizar las representaciones sociales que ellos y ellas comparten sobre el ejercicio ciudadano. El análisis de la información tiene como ejes fundamentales, la salud colectiva, la sociología de la infancia y la participación en la niñez, en una aproximación que se realiza desde un enfoque cualitativo y etnográfico. En los hallazgos, sobresale cómo las niñas y niños se muestran preparados para ejercer su derecho a la participación como aspecto de sus vidas que se haría posible dentro del marco normativo existente, pero que aún no es asumido en prácticas sociales que los incluyan.

  12. Tungsten inert gas (TIG) welding of Ni-rich NiTi plates: functional behavior

    Oliveira, J. P.; Barbosa, D.; Braz Fernandes, F. M.; Miranda, R. M.

    2016-03-01

    It is often reported that, to successfully join NiTi shape memory alloys, fusion-based processes with reduced thermal affected regions (as in laser welding) are required. This paper describes an experimental study performed on the tungsten inert gas (TIG) welding of 1.5 mm thick plates of Ni-rich NiTi. The functional behavior of the joints was assessed. The superelasticity was analyzed by cycling tests at maximum imposed strains of 4, 8 and 12% and for a total of 600 cycles, without rupture. The superelastic plateau was observed, in the stress-strain curves, 30 MPa below that of the base material. Shape-memory effect was evidenced by bending tests with full recovery of the initial shape of the welded joints. In parallel, uniaxial tensile tests of the joints showed a tensile strength of 700 MPa and an elongation to rupture of 20%. The elongation is the highest reported for fusion-welding of NiTi, including laser welding. These results can be of great interest for the wide-spread inclusion of NiTi in complex shaped components requiring welding, since TIG is not an expensive process and is simple to operate and implement in industrial environments.

  13. High resolution TEM study of Ni4Ti3 precipitates in austenitic Ni51Ti49

    Tirry, Wim; Schryvers, Dominique

    2003-01-01

    Binary NiTi with a composition of 51 at.% Ni was heat treated to form lens-shaped Ni 4 Ti 3 precipitates that are coherent or semi-coherent with the B2 matrix. High resolution transmission electron microscopy (HRTEM) was used to study the internal structure of the precipitates, precipitate-precipitate and matrix-precipitate interfaces and the deformation of the B2 matrix near a precipitate. Observations were made in the B2 and B2 zones and compared with computer simulated high resolution images. The B2 observations made it possible to study the [0 0 1] H zone orientation of Ni 4 Ti 3 (direction defined according to the hexagonal unit cell of Ni 4 Ti 3 ) which corresponds to the normal of the central plane of the discs. In these images the superperiodicity of the 4:3 ordering is clearly visible confirming the known atomic structure. Close to the precipitate the B2 matrix is deformed, as determined by measuring the interplanar spacing from the HRTEM images. The observed deformations are compared with theoretical models for the stress field

  14. Breakdown of antiferromagnet order in polycrystalline NiFe/NiO bilayers probed with acoustic emission

    Lebyodkin, M. A.; Lebedkina, T. A.; Shashkov, I. V.; Gornakov, V. S.

    2017-07-01

    Magnetization reversal of polycrystalline NiFe/NiO bilayers was investigated using magneto-optical indicator film imaging and acoustic emission techniques. Sporadic acoustic signals were detected in a constant magnetic field after the magnetization reversal. It is suggested that they are related to elastic waves excited by sharp shocks in the NiO layer with strong magnetostriction. Their probability depends on the history and number of repetitions of the field cycling, thus testifying the thermal-activation nature of the long-time relaxation of an antiferromagnetic order. These results provide evidence of spontaneous thermally activated switching of the antiferromagnetic order in NiO grains during magnetization reversal in ferromagnet/antiferromagnet (FM/AFM) heterostructures. The respective deformation modes are discussed in terms of the thermal fluctuation aftereffect in the Fulcomer and Charap model which predicts that irreversible breakdown of the original spin orientation can take place in some antiferromagnetic grains with disordered anisotropy axes during magnetization reversal of exchange-coupled FM/AFM structures. The spin reorientation in the saturated state may induce abrupt distortion of isolated metastable grains because of the NiO magnetostriction, leading to excitation of shock waves and formation of plate (or Lamb) waves.

  15. Electric Monopole Transition Strengths in 62Ni

    Evitts L. J.

    2016-01-01

    Full Text Available Excited states in 62Ni were populated with a (p, p’ reaction using the 14UD Pelletron accelerator at the Australian National University. Electric monopole transition strengths, ρ2(E0, were measured through simultaneous detection of the internal conversion electrons and γ rays emitted from the de-excitation of populated states, using the Super-e spectrometer coupled with a germanium detector. The strength of the 02+ to 01+ transition has been measured to be 77−34+23 × 10−3 and agrees with previously reported values. Upper limits have been placed on the 03+ to 01+ and 03+ to 02+ transitions. The measured ρ2(E0 value of the 22+ to 21+ transition in 62Ni has been measured for the first time and found to be one of the largest ρ2(E0 values measured to date in nuclei heavier than Ca. The low-lying states of 62Ni have previously been classified as one- and two-phonon vibrational states based on level energies. The measured electric quadrupole transition strengths are consistent with this interpretation. However as electric monopole transitions are forbidden between states which differ by one phonon number, the simple harmonic quadrupole vibrational picture is not suffcient to explain the large ρ2(E0 value for the 22+ to 21+ transition.

  16. Electric Monopole Transition Strengths in 62Ni

    Evitts, L. J.; Garnsworthy, A. B.; Kibédi, T.; Moukaddam, M.; Alshahrani, B.; Eriksen, T. K.; Holt, J. D.; Hota, S. S.; Lane, G. J.; Lee, B. Q.; McCormick, B. P.; Palalani, N.; Reed, M. W.; Stroberg, S. R.; Stuchbery, A. E.

    2016-09-01

    Excited states in 62Ni were populated with a (p, p') reaction using the 14UD Pelletron accelerator at the Australian National University. Electric monopole transition strengths, ρ2(E0), were measured through simultaneous detection of the internal conversion electrons and γ rays emitted from the de-excitation of populated states, using the Super-e spectrometer coupled with a germanium detector. The strength of the 02+ to 01+ transition has been measured to be 77-34+23 × 10-3 and agrees with previously reported values. Upper limits have been placed on the 03+ to 01+ and 03+ to 02+ transitions. The measured ρ2(E0) value of the 22+ to 21+ transition in 62Ni has been measured for the first time and found to be one of the largest ρ2(E0) values measured to date in nuclei heavier than Ca. The low-lying states of 62Ni have previously been classified as one- and two-phonon vibrational states based on level energies. The measured electric quadrupole transition strengths are consistent with this interpretation. However as electric monopole transitions are forbidden between states which differ by one phonon number, the simple harmonic quadrupole vibrational picture is not suffcient to explain the large ρ2(E0) value for the 22+ to 21+ transition.

  17. Length-dependent corrosion behavior, Ni2+ release, cytocompatibility, and antibacterial ability of Ni-Ti-O nanopores anodically grown on biomedical NiTi alloy.

    Hang, Ruiqiang; Liu, Yanlian; Bai, Long; Zhang, Xiangyu; Huang, Xiaobo; Jia, Husheng; Tang, Bin

    2018-08-01

    In the present work, nickel-titanium-oxygen nanopores with different length (0.55-114 μm) were anodically grown on nearly equiatomic nickel-titanium (NiTi) alloy. Length-dependent corrosion behavior, nickel ion (Ni 2+ ) release, cytocompatibility, and antibacterial ability were investigated by electrochemical, analytical chemistry, and biological methods. The results show constructing nanoporous structure on the NiTi alloy improve its corrosion resistance. However, the anodized samples release more Ni 2+ than that of the bare NiTi alloy, suggesting chemical dissolution of the nanopores rather than electrochemical corrosion governs the Ni 2+ release. In addition, the Ni 2+ release amount increases with nanopore length. The anodized samples show good cytocompatibility when the nanopore length is covers the one (1-11 μm) that the nanopores showing favorable antibacterial ability. Consequently, the nanopores with length in the range of 1-11 μm are promising as coatings of biomedical NiTi alloy for anti-infection, drug delivery, and other desirable applications. Copyright © 2018 Elsevier B.V. All rights reserved.

  18. Effects of P/Ni ratio and Ni content on performance of γ-Al_2O_3-supported nickel phosphides for deoxygenation of methyl laurate to hydrocarbons

    Zhang, Zhena; Tang, Mingxiao; Chen, Jixiang

    2016-01-01

    Graphical abstract: - Highlights: • The formation of AlPO_4 was unfavorable for that of nickel phosphides. • The phase compositions of nickel phosphide depended on the amount of reduced P. • Catalytic activity was determined by surface Ni site density and catalyst acidity. • HDO pathway was promoted by increasing P/Ni ratio and Ni content. • Nickel phosphide gave much higher carbon yield and lower H_2 consumption than Ni. - Abstract: γ-Al_2O_3-supported nickel phosphides (mNi-Pn) were prepared by the TPR method and tested for the deoxygenation of methyl laurate to hydrocarbons. The effects of the P/Ni ratio (n = 1.0–2.5) and Ni content (m = 5–15 wt.%) in the precursors on their structure and performance were investigated. Ni/γ-Al_2O_3 was also studied for comparison. It was found that the formation of AlPO_4 in the precursor inhibited the reduction of phosphate and so the formation of nickel phosphides. With increasing the P/Ni ratio and Ni content, the Ni, Ni_3P, Ni_1_2P_5 and Ni_2P phases orderly formed, accompanying with the increases of their particle size and the amount of weak acid sites (mainly due to P-OH group), while the CO uptake and the amount of medium strong acid sites (mainly related to Ni sites) reached maximum on 10%Ni-P1.5. In the deoxygenation reaction, compared with Ni/γ-Al_2O_3, the mNi-Pn catalysts showed much lower activities for decarbonylation, C−C hydrogenolysis and methanation due to the ligand and ensemble effects of P. The conversion and the selectivity to n-C11 and n-C12 hydrocarbons achieved maximum on 10%Ni-P 2.0 for the 10%Ni-Pn catalysts and on 8%Ni-P2.0 for the mNi-P2.0 catalysts, while the turnover frequency (TOF) of methyl laurate mainly increased with the P/Ni ratio and Ni content. We propose that TOF was influenced by the nickel phosphide phases, the catalyst acidity and the particle size as well as the synergetic effect between the Ni site and acid site. Again, the hydrodeoxygenation pathway of methyl

  19. Level structure of 60Ni from the 58Ni(α,2p#betta#) reaction

    Chan, T.U.; Morand, C.; Azgui, F.

    1982-03-01

    The 60 Ni nucleus has been studied via the 58 Ni (α, 2p#betta#) reaction at Esub(α)=32 MeV using in-beam #betta# spectroscopy techniques. High-spin states up to 10 MeV excitation have been established. Among the 5 branches depopulating the Yrast Jsup(π)=7 - state, has been found an E3 transition down to the 4 + state. Comparison with direct reaction results leads to assign very probably the [#betta#fsub(5/2),#betta#gsub(9/2)] 7 - configuration to the Jsup(π)=7 - Yrast state at 5349 keV. Other high-spin states might be accounted for by the breaking of the 56 Ni core

  20. Atomistic simulation of the pinning of edge dislocations in Ni by Ni3Al precipitates

    Kohler, Christopher; Kizler, Peter; Schmauder, Siegfried

    2005-01-01

    Classical molecular dynamics simulations of the interaction of edge dislocations in Ni with chains of spherical Ni 3 Al precipitates are performed using EAM potentials. The order hardening is investigated at temperature T=0 -bar K by determining the critical resolved shear stresses (CRSSs) for a superdislocation that is dissociated into four partial dislocations. The CRSS is computed as a function of the radius and the distance of the precipitates. It is found that for precipitates with a diameter smaller than the dissociation width of perfect edge dislocation in Ni, the CRSS of the trailing dislocation of the superdislocation is a fraction of about 0.4 of the CRSS of the leading dislocation

  1. Sorption properties of new composite materials suitable for radioanalytical determination of 59-Ni and 63-Ni

    Fisera, O.; Sebesta, F.

    2006-01-01

    New composite materials for separation and radioanalytical determination of radionickel ( 59, 63 Ni) were prepared and their sorption properties were examined. Chelating agents dimethylglyoxime (DMG) and diphenylglyoxime (DFG) as active components were immobilized in porous matrix of binding polymer polyacrylonitrile (PAN). Sorption properties of these materials were compared with commercial Ni Resin (Eichrom Technologies, USA). Weight distribution ratios, sorption kinetics and operating capacities were investigated during experiments performed. The highest weight distribution ratios were found for the material DFG-PAN. The sorbent DMG-PAN has the highest operating capacity. The fastest kinetics of nickel sorption was determined for the commercial Ni Resin. Elution of nickel with nitric acid solution allows subsequent and direct determination of radionickel by liquid scintillation counting. (author)

  2. Effect of amorphous Mg50Ni50 on hydriding and dehydriding behavior of Mg2Ni alloy

    Guzman, D.; Ordonez, S.; Fernandez, J.F.; Sanchez, C.; Serafini, D.; Rojas, P.A.; Aguilar, C.; Tapia, P.

    2011-01-01

    Composite Mg 2 Ni (25 wt.%) amorphous Mg 50 Ni 50 was prepared by mechanical milling starting with nanocrystalline Mg 2 Ni and amorphous Mg 50 Ni 50 powders, by using a SPEX 8000 D mill. The morphological and microstructural characterization of the powders was performed via scanning electron microscopy and X-ray diffraction. The hydriding characterization of the composite was performed via a solid gas reaction method in a Sievert's-type apparatus at 363 K under an initial hydrogen pressure of 2 MPa. The dehydriding behavior was studied by differential thermogravimetry. On the basis of the results, it is possible to conclude that amorphous Mg 50 Ni 50 improved the hydriding and dehydriding kinetics of Mg 2 Ni alloy upon cycling. A tentative rationalization of experimental observations is proposed. - Research Highlights: → First study of the hydriding behavior of composite Mg 2 Ni (25 wt.%) amorphous Mg 50 Ni 50 . → Microstructural characterization of composite material using XRD and SEM was obtained. → An improved effect of Mg 50 Ni 50 on the Mg 2 Ni hydriding behavior was verified. → The apparent activation energy for the hydrogen desorption of composite was obtained.

  3. When NiO@Ni Meets WS2 Nanosheet Array: A Highly Efficient and Ultrastable Electrocatalyst for Overall Water Splitting.

    Wang, Dewen; Li, Qun; Han, Ce; Xing, Zhicai; Yang, Xiurong

    2018-01-24

    The development of low-cost, high-efficiency, and stable bifunctional electrocatalysts toward the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is of paramount importance for large-scale water splitting. Here, we develop a new strategy for the first design and synthesis of a NiO@Ni decorated WS 2 nanosheet array on carbon cloth (NiO@Ni/WS 2 /CC) composite. This composite serves as a unique three-dimensional (3D) synergistic electrocatalyst that not only combines the intrinsic properties of individual NiO@Ni and WS 2 , but also exhibits significantly improved HER and OER activities when compared to that of pure NiO@Ni and WS 2 . This electrocatalyst possesses Pt-like activity for HER and exhibits better OER performance than that for commercial RuO 2 , as well as demonstrating superior long-term durability in alkaline media. Furthermore, it enables an alkaline electrolyzer with a current density of 10 mA cm -2 at a cell voltage as 1.42 V, which is the lowest one among all reported values to date. The excellent performance is mainly attributed to the unique 3D configuration and multicomponent synergies among NiO, Ni, and WS 2 . Our findings provide a new idea to design advanced bifunctional catalysts for water splitting.

  4. Impact of Interstitial Ni on the Thermoelectric Properties of the Half-Heusler TiNiSn

    Sonia A. Barczak

    2018-03-01

    Full Text Available TiNiSn is an intensively studied half-Heusler alloy that shows great potential for waste heat recovery. Here, we report on the structures and thermoelectric properties of a series of metal-rich TiNi1+ySn compositions prepared via solid-state reactions and hot pressing. A general relation between the amount of interstitial Ni and lattice parameter is determined from neutron powder diffraction. High-resolution synchrotron X-ray powder diffraction reveals the occurrence of strain broadening upon hot pressing, which is attributed to the metastable arrangement of interstitial Ni. Hall measurements confirm that interstitial Ni causes weak n-type doping and a reduction in carrier mobility, which limits the power factor to 2.5–3 mW m−1 K−2 for these samples. The thermal conductivity was modelled within the Callaway approximation and is quantitively linked to the amount of interstitial Ni, resulting in a predicted value of 12.7 W m−1 K−1 at 323 K for stoichiometric TiNiSn. Interstitial Ni leads to a reduction of the thermal band gap and moves the peak ZT = 0.4 to lower temperatures, thus offering the possibility to engineer a broad ZT plateau. This work adds further insight into the impact of small amounts of interstitial Ni on the thermal and electrical transport of TiNiSn.

  5. Controlled growth of Ni/NiO core–shell nanoparticles: Structure, morphology and tuning of magnetic properties

    D’Addato, S., E-mail: sergio.daddato@unimore.it [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Spadaro, M.C. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Luches, P. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Grillo, V. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); CNR-IMEM, Parco Area delle Scienze 37/A, 43100 Parma (Italy); Frabboni, S.; Valeri, S. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Ferretti, A.M.; Capetti, E.; Ponti, A. [CNR-ISTM, Laboratorio di Nanotecnologie, via G. Fantoli 16/15, 20138 Milano (Italy)

    2014-07-01

    We performed a detailed study of Ni/NiO core–shell nanoparticles (NP) obtained with a gas aggregation source. The NP oxide shells were produced by oxidizing the NP with different procedures: deposition in oxygen atmosphere, post-annealing in air, sequential deposition of (a) first NiO layer, (b) Ni NP and (c) third NiO Layer. X-ray photoelectron spectroscopy from Ni 2p core-level gave information about the chemical state of Ni in the core and in the oxide shell, while scanning electron microscopy was used for investigation of the NP morphology. High quality scanning transmission electron microscopy in high angle annular dark field mode data demonstrated core–shell structure also for NiO/Ni NP/NiO samples. Field-cooled/zero-field-cooled magnetization curves and field-cooled isothermal hysteresis cycles at T = 5 K were recorded by a SQUID magnetometer. In this way, the relation between magnetic properties and oxide shell structure was assessed, showing the role played by the control of the formation of oxide on the exchange bias and interparticle magnetic interaction.

  6. When NiO@Ni Meets WS2 Nanosheet Array: A Highly Efficient and Ultrastable Electrocatalyst for Overall Water Splitting

    Dewen Wang

    2017-12-01

    Full Text Available The development of low-cost, high-efficiency, and stable bifunctional electrocatalysts toward the hydrogen evolution reaction (HER and oxygen evolution reaction (OER is of paramount importance for large-scale water splitting. Here, we develop a new strategy for the first design and synthesis of a NiO@Ni decorated WS2 nanosheet array on carbon cloth (NiO@Ni/WS2/CC composite. This composite serves as a unique three-dimensional (3D synergistic electrocatalyst that not only combines the intrinsic properties of individual NiO@Ni and WS2, but also exhibits significantly improved HER and OER activities when compared to that of pure NiO@Ni and WS2. This electrocatalyst possesses Pt-like activity for HER and exhibits better OER performance than that for commercial RuO2, as well as demonstrating superior long-term durability in alkaline media. Furthermore, it enables an alkaline electrolyzer with a current density of 10 mA cm–2 at a cell voltage as 1.42 V, which is the lowest one among all reported values to date. The excellent performance is mainly attributed to the unique 3D configuration and multicomponent synergies among NiO, Ni, and WS2. Our findings provide a new idea to design advanced bifunctional catalysts for water splitting.

  7. Enhanced optical and electrical properties of Ni inserted ITO/Ni/AZO tri-layer structure for photoelectric applications

    Kumar, M. Melvin David; Kim, Hyunki [Department of Electrical Engineering, Incheon National University, Incheon 406772 (Korea, Republic of); Park, Yun Chang [Measurement and Analysis Division, National Nanofab Center (NNFC), Daejeon 305-806 (Korea, Republic of); Kim, Joondong, E-mail: joonkim@incheon.ac.kr [Department of Electrical Engineering, Incheon National University, Incheon 406772 (Korea, Republic of)

    2015-05-15

    Highlights: • Ni-embedding transparent conductor effectively reduces the resistivity. • Ni insertion improves the carrier mobility and collection efficiencies. • ITO/Ni/AZO is effective to improve photo-responses compared to ITO/AZO. - Abstract: A thin Ni layer of 5 nm thickness was deposited in between indium-tin-oxide (ITO) and aluminum-doped-zinc oxide (AZO) layers of 50 nm thickness each. The Ni inserting tri-layer structure (ITO/Ni/AZO) showed lower resistivity of 5.51 × 10{sup −4} Ωcm which is nearly 20 times lesser than 97.9 × 10{sup −4} Ωcm of bilayer structure (ITO/AZO). A thin Ni layer in between ITO and AZO enhanced the carrier concentration, mobility and photoresponse behaviors so that figure of merit (FOM) value of ITO/Ni/AZO device was greater than that of ITO/AZO device. ITO/Ni/AZO structure showed improved quantum efficiencies over a broad range of wavelengths (∼350–950 nm) compared to that of ITO/AZO bilayer structure, resulting in enhanced photoresponses. These results show that the optical, electrical and photoresponse properties of ITO/AZO structure could be enhanced by inserting Ni layer of 5 nm thickness in between ITO and AZO layers.

  8. On the Ni-Ion release rate from surfaces of binary NiTi shape memory alloys

    Ševčíková, Jana; Bártková, Denisa; Goldbergová, Monika; Kuběnová, Monika; Čermák, Jiří; Frenzel, Jan; Weiser, Adam; Dlouhý, Antonín

    2018-01-01

    The study is focused on Ni-ion release rates from NiTi surfaces exposed in the cell culture media and human vascular endothelial cell (HUVEC) culture environments. The NiTi surface layers situated in the depth of 70 μm below a NiTi oxide scale are affected by interactions between the NiTi alloys and the bio-environments. The finding was proved with use of inductively coupled plasma mass spectrometry and electron microscopy experiments. As the exclusive factor controlling the Ni-ion release rates was not only thicknesses of the oxide scale, but also the passivation depth, which was two-fold larger. Our experimental data strongly suggested that some other factors, in addition to the Ni concentration in the oxide scale, admittedly hydrogen soaking deep below the oxide scale, must be taken into account in order to rationalize the concentrations of Ni-ions released into the bio-environments. The suggested role of hydrogen as the surface passivation agent is also in line with the fact that the Ni-ion release rates considerably decrease in NiTi samples that were annealed in controlled hydrogen atmospheres prior to bio-environmental exposures.

  9. Controlled growth of Ni/NiO core–shell nanoparticles: Structure, morphology and tuning of magnetic properties

    D’Addato, S.; Spadaro, M.C.; Luches, P.; Grillo, V.; Frabboni, S.; Valeri, S.; Ferretti, A.M.; Capetti, E.; Ponti, A.

    2014-01-01

    We performed a detailed study of Ni/NiO core–shell nanoparticles (NP) obtained with a gas aggregation source. The NP oxide shells were produced by oxidizing the NP with different procedures: deposition in oxygen atmosphere, post-annealing in air, sequential deposition of (a) first NiO layer, (b) Ni NP and (c) third NiO Layer. X-ray photoelectron spectroscopy from Ni 2p core-level gave information about the chemical state of Ni in the core and in the oxide shell, while scanning electron microscopy was used for investigation of the NP morphology. High quality scanning transmission electron microscopy in high angle annular dark field mode data demonstrated core–shell structure also for NiO/Ni NP/NiO samples. Field-cooled/zero-field-cooled magnetization curves and field-cooled isothermal hysteresis cycles at T = 5 K were recorded by a SQUID magnetometer. In this way, the relation between magnetic properties and oxide shell structure was assessed, showing the role played by the control of the formation of oxide on the exchange bias and interparticle magnetic interaction.

  10. Distorted-wave calculations of electron impact ionisation in the Ni isonuclear sequence

    Griffin, D C; Pindzola, M S

    1988-10-14

    Electron impact ionisation cross sections for Ni/sup +/, Ni/sup 3+/, Ni/sup 5+/, Ni/sup 6+/, Ni/sup 7+/, Ni/sup 8+/, Ni/sup 12+/, Ni/sup 14+/, and Ni/sup 16+/ are calculated in the distorted-wave approximation. These calculations include contributions from direct ionisation and inner-shell excitation followed by autoionisation. For Ni/sup 12+/, Ni/sup 14+/, and Ni/sup 16+/ we report not only on ionisation cross sections from the ground states but also from the metastable states of these ions. Experimental cross section measurements exist for all ions reported here, except Ni/sup 16+/. The agreement between experiment and theory is reasonably good and improves with ionisation stage.

  11. NiTiCu/AlN/NiTiCu shape memory thin film heterostructures for vibration damping in MEMS

    Kaur, Navjot; Kaur, Davinder, E-mail: dkaurfph@iitr.ernet.in

    2014-03-25

    Highlights: • Fabrication of NiTiCu/AlN/NiTiCu heterostructure using dc/rf magnetron sputtering. • Exhibits highest hardness (38 GPa) and elastic modulus (187 GPa). • Enhanced dissipation of mechanical energy (E{sub d} = 5.7 N J). • High damping capacity (0.052) and figure of merit (∼0.62). • Can be applied for vibration damping in MEMS. -- Abstract: Shape memory alloy (NiTiCu) thin films coupled with piezoelectric AlN layer produce an intelligent material for vibration damping. In the present study pure NiTiCu, NiTiCu/AlN and NiTiCu/AlN/NiTiCu heterostructures have been deposited on Si substrate using magnetron sputtering technique. By the use of the interfaces and shape memory effect provided by NiTiCu layers, the damping capacity can be increased along with increase in stiffness and mechanical hardness. The heterostructures were characterized in terms of structural, electrical, morphological and mechanical properties by X-ray diffraction (XRD), four probe resistivity method, atomic force microscopy, field emission scanning electron microscopy, and nanoindentation. The NiTiCu/AlN/NiTiCu heterostructure exhibit enhanced mechanical and damping properties as compared to NiTiCu/AlN and pure NiTiCu. This enhancement in hardness and damping of the heterostructure could be attributed to the shape memory effect of NiTiCu, intrinsic piezoelectricity of AlN and increased number of interfaces in heterostructure that help in dissipation of mechanical vibrations. The findings of this work provide additional impetus for the application of these heterostructures in emerging fields of nanotechnology and microelectro mechanical (MEMS) devices.

  12. NiTiCu/AlN/NiTiCu shape memory thin film heterostructures for vibration damping in MEMS

    Kaur, Navjot; Kaur, Davinder

    2014-01-01

    Highlights: • Fabrication of NiTiCu/AlN/NiTiCu heterostructure using dc/rf magnetron sputtering. • Exhibits highest hardness (38 GPa) and elastic modulus (187 GPa). • Enhanced dissipation of mechanical energy (E d = 5.7 N J). • High damping capacity (0.052) and figure of merit (∼0.62). • Can be applied for vibration damping in MEMS. -- Abstract: Shape memory alloy (NiTiCu) thin films coupled with piezoelectric AlN layer produce an intelligent material for vibration damping. In the present study pure NiTiCu, NiTiCu/AlN and NiTiCu/AlN/NiTiCu heterostructures have been deposited on Si substrate using magnetron sputtering technique. By the use of the interfaces and shape memory effect provided by NiTiCu layers, the damping capacity can be increased along with increase in stiffness and mechanical hardness. The heterostructures were characterized in terms of structural, electrical, morphological and mechanical properties by X-ray diffraction (XRD), four probe resistivity method, atomic force microscopy, field emission scanning electron microscopy, and nanoindentation. The NiTiCu/AlN/NiTiCu heterostructure exhibit enhanced mechanical and damping properties as compared to NiTiCu/AlN and pure NiTiCu. This enhancement in hardness and damping of the heterostructure could be attributed to the shape memory effect of NiTiCu, intrinsic piezoelectricity of AlN and increased number of interfaces in heterostructure that help in dissipation of mechanical vibrations. The findings of this work provide additional impetus for the application of these heterostructures in emerging fields of nanotechnology and microelectro mechanical (MEMS) devices

  13. FY 2000 report on the results of the technology development of energy use reduction of machine tools, etc. Technology development of environmental load reduction related to water soluble lubricating oil, etc. (R and D of low energy coolant degradation prevention technology and waste liquid processing technology); 2000 nendo energy shiyo gorika kosaku kikai nado gijutsu kaihatsu seika hokokusho. Suiyosei junkatsuyu ni kakawaru kankyo fuka teigen nado gijutsu kanri (tei energy coolant fuhai boshi gijutsu oyobi haieki shori gijutsu no kenkyu kaihatsu)

    NONE

    2001-03-01

    The R and D were carried out on a system by which the long life of coolant of machine tools can be achieved and a system to process waste efficiently, economically and with less environmental loads, and the FY 2000 results were summed up. In the R and D of a system to prevent degradation of low energy coolant, measurement was made of effects of the degradation prevention system at a laboratory level, and it was found out that propagation of bacteria causing the degradation can be prevented with pH kept high. Further, it was admitted that the alkali effect on metal formability was not very much. As to the coolant processing, in the present situation, most of the coolant is taken back by industrial waste processing dealers. So, the development of the low energy waste liquid processing system is earnestly desired. In the R and D of the low energy waste liquid processing system, test on characteristics evaluation was conducted about each method of systems. Subjects to be improved/solved were extracted such as the point that volatile organic matters are included in condensed water after evaporation of waste liquid and there seems to be a possibility of needing the secondary processing. (NEDO)

  14. Achievement report for fiscal 2000 on development of technology related to new recycled products. Research and development of simultaneous recovery of chlorine contained in waste plastics and alkali contained in waste glass bottles; 2000 nendo shinki recycle seihin nado kanren gijutsu kaihatsu seika hokokusho. Hai plastic gan'yu enso to hai glass bin gan'yu alkali no doji kaishu ni kakawaru kenkyu kaihatsu

    NONE

    2001-03-01

    Researches have been made on a technology to have alkali contained in waste glass bottles reacted with chlorine contained in waste plastics to separate and remove salt, and reuse the residues as a resource for cement raw material. This paper summarizes the achievements in fiscal 2000. In the research, glass powder pulverized to 5 to 10 {mu} m, calcium carbonate, iron oxide, and alumina were used to prepare raw material for the ordinary Portland cement. Vinyl chloride pulverized to 3 mm was added into this cement raw material so that chlorine-alkali equivalent ration will be 1.0, and the material was sintered in a rotary kiln at 800 to 1,400 degrees C. As a result, it was discovered that salt is produced from the alkali in glass and the chlorine in vinyl chloride, whereas the produced salt volatilizes when heated to 1,200 degrees C or higher, and clinker containing low chlorine and alkali can be produced. The test result reveals that the control range of the chlorine and alkali ratio is from 1.0 to 1.1. The remaining problems are measures against carbon monoxide and dioxin contained in the exhaust gas, and treatment of dust containing salt. (NEDO)

  15. Three-dimensional electrode of Ni/Co layered double hydroxides@NiCo2S4@graphene@Ni foam for supercapacitors with outstanding electrochemical performance

    Tao, Yan; Ruiyi, Li; Lin, Zhou; Chenyang, Ma; Zaijun, Li

    2015-01-01

    We reported a new strategy for fabricating three-dimensiona electrode of Ni/Co layered double hydroxide@NiCo 2 S 4 @graphene@Ni foam for supercapacitors. The resulting 3D electrode offers a jungle-like architecture. The unique structure creates ultra fast electron transfer and electrolyte transport as well as the maximum utilization rate of the space and the surface. The electrode exhibits a prominent advantage of high specific capacitance, high-current capacitive behaviour and cycle stability. - Highlights: • The study developed a new strategy for fabricating 3D electrode of Ni/Co-LDH@NiCo 2 S 4 @G. • The as-prepared 3D electrode offers a jungle-like architecture. • The unique structure creates an efficient conduction network and high mass loading. • The electrode achieves significantly synergetic effect among different materials. • The electrode exhibits an excellent electrochemical performance for supercapacitors. - ABSTRACT: Great challenge for the fabrication of free-standing three-dimensional electrode still remains to simultaneously achieve high specific capacitance, rate performance and cycle stability. The paper reprted a new three-dimensional (3D) electrode of Ni/Co layered double hydroxide@NiCo 2 S 4 @graphene@Ni foam (Ni/Co-LDH@NiCo 2 S 4 @G) for supercapacitors. The as-prepared 3D electrode offers an unique architecture, which create an efficient conduction network and maximum utilization of space and interface. The graphene acts as well-knit and conductive skin coated on the skeleton of Ni foam for growing NiCo 2 S 4 . The conductive NiCo 2 S 4 array serves as bridge between Ni/Co-LDH and graphene, leading to ultrafast electron transfer and electrolyte transport. A slew of splits and holes existing in the NiCo 2 S 4 array play one role as the ion-reservoir to contain host of electrolyte ions. To evaluate the feasibility of 3D electrode’s application in supercapacitors, the electrochemical performance was investigated by using the three

  16. Energetic Mapping of Ni Catalysts by Detailed Kinetic Modeling

    Bjørgum, Erlend; Chen, De; Bakken, Mari G.

    2005-01-01

    Temperature-programmed desorption (TPD) of CO has been performed on supported and unsupported nickel catalysts. The unsupported Ni catalyst consists of a Ni(14 13 13) single crystal which has been studied under ultrahigh vacuum conditions. The desorption energy for CO at low CO surface coverage...... was found to be 119 kJ/mol, and the binding energy of C to the Ni(111) surface of the crystal was 703 kJ/mol. The supported catalysts consist of nickel supported on hydrotalcite-like compounds with three different Mg2+/Al3+ ratios. The experimental results show that for the supported Ni catalysts TPD of CO...... precursor seems to result in more steplike sites, kinks, and defects for carbon monoxide dissociation. A detailed kinetic modeling of the TPO results based on elementary reaction steps has been conducted to give an energetic map of supported Ni catalysts. Experimental results from the ideal Ni surface fit...

  17. Synthesis of electroplated {sup 63}Ni source and betavoltaic battery

    Uhm, Young Rang; Yoo, Kwon Mo; Choi, Sang Mu; Kim, Jin Joo; Son, Kwang Jae [Radioisotope Research Division, Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-12-15

    Radioisotope (Nuclear) battery using {sup 63}Ni was prepared as beta cell. The electroplated {sup 63}Ni on Ni foil is fabricated, and beta cell and photovoltaic hybrid battery was designed to use at both day and night in space project. A Ni-plating solution is prepared by dissolving metal particles including {sup 62}Ni and {sup 63}Ni from neutron irradiation of (n,γ). Electroplating solution of a chloride bath consists on nickel ions in HCl, H{sub 3}BO{sub 3}, and KOH. The deposition was carried out at current density of 10 mA cm{sup -2}. The prepared beta source was attached on a PN junction and measured I-V properties. The power output at activity of 0.07 mCi and 0.45 mCi were 0.55 pW and 2.69 nW, respectively.

  18. Microstructure and martensitic transformation of Ni-Ti-Pr alloys

    Zhao, Chunwang [Inner Mongolia University of Technology, College of Science, Hohhot (China); Shanghai Maritime University, College of Arts and Sciences, Shanghai (China); Zhao, Shilei; Jin, Yongjun; Hou, Qingyu [Inner Mongolia University of Technology, College of Science, Hohhot (China); Guo, Shaoqiang [Beihang University, Key Laboratory of Micro-nano Measurement, Manipulation and Physics (Ministry of Education), Department of Physics, Beijing (China)

    2017-09-15

    The effect of Pr addition on the microstructure and martensitic transformation behavior of Ni{sub 50}Ti{sub 50-x}Pr{sub x} (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9) alloys were investigated experimentally. Results show that the microstructures of Ni-Ti-Pr alloys consist of the NiTi matrix and the NiPr precipitate with the Ti solute. The martensitic transformation start temperature decreases gradually with the increase in Pr fraction. The stress around NiPr precipitates is responsible for the decrease in martensitic transformation temperature with the increase in Pr fraction in Ni-Ti-Pr alloys. (orig.)

  19. Near-surface segregation in irradiated Ni3Si

    Wagner, W.; Rehn, L.E.; Wiedersich, H.

    1982-01-01

    The radiation-induced growth of Ni 3 Si films on the surfaces of Ni(Si) alloys containing = 3 Si phase has been observed. Post-irradiation depth profiling by Auger electron spectroscopy, as well as in situ analysis by high-resolution Rutherford backscattering spectrometry, reveals Si-enrichment at the surfaces of Ni(Si) alloys in excess of stoichiometric Ni 3 Si during irradiation. Thin, near-surface layers with silicon concentrations of 28 to 30 at.% are observed, and even higher Si enrichment is found in the first few atom layers. Transmission electron microscopy and selected area-electron diffraction were employed to characterize these Si-enriched layers. A complex, multiple-spot diffraction pattern is observed superposed on the diffraction pattern of ordered Ni 3 Si. The d-spacings obtained from the extra spots are consistent with those of the orthohexagonal intermetallic compound Ni 5 Si 2 . (author)

  20. Crystal growth velocity in deeply undercooled Ni-Si alloys

    Lü, Y. J.

    2012-02-01

    The crystal growth velocity of Ni95Si5 and Ni90Si10 alloys as a function of undercooling is investigated using molecular dynamics simulations. The modified imbedded atom method potential yields the equilibrium liquidus temperatures T L ≈ 1505 and 1387 K for Ni95Si5 and Ni90Si10 alloys, respectively. From the liquidus temperatures down to the deeply undercooled region, the crystal growth velocities of both the alloys rise to the maximum with increasing undercooling and then drop slowly, whereas the athermal growth process presented in elemental Ni is not observed in Ni-Si alloys. Instead, the undercooling dependence of the growth velocity can be well-described by the diffusion-limited model, furthermore, the activation energy associated with the diffusion from melt to interface increases as the concentration increases from 5 to 10 at.% Si, resulting in the remarkable decrease of growth velocity.

  1. Diffusion studies in amorphous NiZr alloys

    Hahn, H.; Averback, R.S.; Hoshino, K.; Rothman, S.J.

    1987-06-01

    Tracer impurity and self diffusion measurements have been made on amorphous (a-) NiZr alloys using radioactive tracer, Secondary Ion Mass Spectrometry and Rutherford backscattering techniques. The temperature dependence of diffusion in a-NiZr can be represented in the form D = D 0 exp(-Q/kT), with no structural relaxation effects being observed. The mobility of an atom in a-NiZr increased dramatically with decreasing atomic radius of the diffusing atom and also with decreasing Ni content for Ni concentrations below ≅40 at. %. These diffusion characteristics in a-NiZr are remarkably similar to those in α-Zr and α-Ti. These mechanisms assume that Zr and Ti provide a close packed structure, either crystalline or amorphous, through which small atoms diffuse by an interstitial mechanism and large atoms diffuse by a vacancy mechanism. 12 refs., 2 figs., 2 tabs

  2. Thermal variation of magnetization in Ni/V multilayers

    Benkirane, K.; Elkabil, R.; Hamdoun, A.; Lassri, M.; Abid, M.; Lassri, H.; Krishnan, R.

    2004-01-01

    The magnetic properties of Ni/V multilayers, prepared by the RF sputtering method, have been systematically studied by magnetic measurements. The magnetization decreases with a decrease in Ni layer thickness tNi and the analysis of the results at 5K indicates the presence of a dead Ni layer about 12A thick. The effective anisotropy Keff of Ni/V multilayers is obtained using a torque magnetometer. The interface contribution to the magnetic anisotropy is practically negligible. A spin-wave theory has been used to explain the temperature dependence of the magnetization and the approximate values for the bulk exchange interaction Jb, surface exchange interaction JS, and the interlayer coupling strength JI for various Ni layer thicknesses have been obtained

  3. Synthesis of electroplated 63Ni source and betavoltaic battery

    Uhm, Young Rang; Yoo, Kwon Mo; Choi, Sang Mu; Kim, Jin Joo; Son, Kwang Jae

    2015-01-01

    Radioisotope (Nuclear) battery using 63 Ni was prepared as beta cell. The electroplated 63 Ni on Ni foil is fabricated, and beta cell and photovoltaic hybrid battery was designed to use at both day and night in space project. A Ni-plating solution is prepared by dissolving metal particles including 62 Ni and 63 Ni from neutron irradiation of (n,γ). Electroplating solution of a chloride bath consists on nickel ions in HCl, H 3 BO 3 , and KOH. The deposition was carried out at current density of 10 mA cm -2 . The prepared beta source was attached on a PN junction and measured I-V properties. The power output at activity of 0.07 mCi and 0.45 mCi were 0.55 pW and 2.69 nW, respectively

  4. Equilibrium relationships in the system Ni-U-O

    Mansour, N.A.L.

    1980-01-01

    Phase relationships were established in air and in oxygen. Mixtures of NiO and U 3 O 8 oxidize to NiUO 4 . The results of analysis of NiUO 4 were identical to those previously published for NiU 3 O 10 . The uranate dissociates to NiO and U 3 O 8 at a temperature higher than that of their oxidation back to the uranate on cooling because of the difficulty of oxygen diffusion and uranate nucleation. Accordingly, dissociation temperature was taken to represent equilibrium and was used to calculate roughly ΔH and ΔS for the reaction of dissociation. In presence of NiO, U 3 O 8 melts partially and does not dissociate to the lower oxide. (orig.) [de

  5. Coercivity scaling in antidot lattices in Fe, Ni, and NiFe thin films

    Gräfe, Joachim, E-mail: graefe@is.mpg.de; Schütz, Gisela; Goering, Eberhard J., E-mail: goering@is.mpg.de

    2016-12-01

    Antidot lattices can be used to artificially engineer magnetic properties in thin films, however, a conclusive model that describes the coercivity enhancement in this class of magnetic nano-structures has so far not been found. We prepared Fe, Ni, and NiFe thin films and patterned each with 21 square antidot lattices with different geometric parameters and measured their hysteretic behavior. On the basis of this extensive dataset we are able to provide a model that can describe both the coercivity scaling over a wide range of geometric lattice parameters and the influence of different materials.

  6. Sideward flow of K+ in Ru+Ru and Ni+Ni reactions sat SIS energies

    Crochet, P.; Herrmann, N.; Wisniewski, K.

    2000-01-01

    Experimental data on K + and proton sideward flow measured with the FOPI detector at SIS/GSI in the reactions Ru+Ru at 1.69 A GeV and Ni+Ni at 1.93 A GeV are presented. The K + sideward flow is found to be anti-correlated (correlated) with the one of protons at low (high) transverse momenta. When compared to the predictions of a transport model, the data favour the existence of an in-medium repulsive K + -nucleon potential. (author)

  7. Shape and size effects on layered Ni/PZT/Ni composites magnetoelectric performance

    Pan, D A; Zhang, S G; Qiao, L J [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Volinsky, Alex A [Department of Mechanical Engineering, University of South Florida, Tampa FL 33620 (United States)], E-mail: lqiao@ustb.edu.cn

    2008-09-07

    This paper presents the magnetoelectric (ME) effect in trilayered Ni/PZT/Ni composites which is related to their size and shape. The ME composites with the same interfacial areas but different geometrical shapes have different ME voltage coefficients. Longitudinal resonant modes in the rectangular and triangular trilayered ME composites were studied. One should choose optimized size, shape and working frequency of the ME composites in order to gain the maximum ME effect. This study plays a guiding role for trilayered ME composites design for real applications. (fast track communication)

  8. Microstructural evolution of neutron-irradiated Ni-Si and Ni-Al alloys

    Takahashi, H.; Garner, F. A.

    1992-10-01

    Additions of silicon and aluminum suppress the neutron-induced swelling of pure nickel but to different degrees. Silicon is much more effective initially when compared to aluminum on a per atom basis but silicon exhibits a nonmonotonic influence on swelling with increasing concentration. Silicon tends to segregate toward grain boundaries while aluminum segregates away from these boundaries. Whereas the formation of the Ni 3Si phase is frequently observed in charged particle irradiation experiments conducted at much higher displacement rates, it did not occur during neutron irradiation in this study. Precipitation also did not occur in Ni-5Al during neutron irradiation, nor has it been reported to occur during ion irradiation.

  9. Strengthening by ordered precipitates in a Ni--Ni4Mo system

    Goodrum, J.W.; LeFevre, B.G.

    1977-01-01

    The strength characteristics and microstructures of aged Ni-Mo alloys containing ordered (Ni 4 Mo) precipitates were studied as a function of aging time and temperature. It was found that 17 at. percent Mo alloy aged at 750 0 C produced a uniform dispersion of cuboidal β precipitates which coarsened with time producing a gradual increase in flow stress. The flow stress increment was found to vary in qualitative agreement with both order strengthening and coherency strain models. Both these models give over-estimates of the strengthening increment. A negative dependence of flow stress on temperature is attributed to coherency strain contributions

  10. The nature of strong Brønsted acidity of Ni-SMM clay

    Yue, C.; Liu, C.; Mezari, B.; Brückner, A.; Pidko, E.A.; Rigutto, M.S.; Hensen, E.J.M.

    2016-01-01

    The origin of the high Brønsted acidity of Ni-SMM (Ni-substituted synthetic mica-montmorillonite; beidellite structure) clays was investigated. Ni-SMM clays with varying F content, SMM with F and Ni-SMM without F in the structure were synthesized under hydrothermal conditions. Ni-SMM clays with

  11. Los niños y los videojuegos

    Orrego Gaviria, Jaime; Fundación Valle de Lili

    2007-01-01

    Los niños y los videojuegos / Efectos perjudiciales de la utilización de los videojuegos por los niños y adolescentes/ Efectos benéficos de la de la utilización de los videojuegos por los niños y adolescentes/ Recomendaciones para favorecer el uso adecuado/ Sistema de clasificación de los videojuegos

  12. Electrochemical Characterization of Ni/(Sc)YSZ Electrodes

    Ramos, Tania; Thydén, Karl Tor Sune; Mogensen, Mogens Bjerg

    2010-01-01

    Investigations of Ni/(Sc)YSZ cermets for solid oxide cells (SOCs) were performed by electrochemical impedance spectroscopy (EIS), under varying experimental conditions and upon redox cycling, using three different designs of symmetric cells. The deconvolution and fitting of the obtained impedance...... parameters. Initial degradation results for both Ni/ScYSZ and Ni/YSZ based anodes under very high steam content are also reported. ©2010 COPYRIGHT ECS - The Electrochemical Society...

  13. Irradiation-induced precipitation in Ni--Si alloys

    Barbu, A.; Ardell, A.J.

    1975-07-01

    The microstructures of Ni + ion-irradiated Ni--Si solid-solution alloys, containing 2, 4, 6 and 8 at. percent Si were investigated as a function of dose, dose-rate, and temperature. Results of transmission electron microscopy and other data show the precipitation of γ' (Ni 3 Si) in all samples irradiated at 500 0 C. Characteristics of the precipitates are described and a mechanism for their formation is suggested. (U.S.)

  14. Ni-YSZ graded coatings produced by dipping

    Ferrari, B.; Moreno, R.

    2004-01-01

    A new colloidal processing route for the shaping of a graded Ni-YSZ composite for applications in SOFC devices is described. A Ni foil is coated by Ni/YSZ layers by dipping in aqueous suspensions with an organic binder. Behind the metal-ceramic layers introduced to improve adhesion, an outer thin layer of nanosized YSZ is formed by electrophoretic deposition. (Abstract Copyright [2004], Wiley Periodicals, Inc.)

  15. Low-field spin dynamics of Cr7Ni and Cr7Ni-Cu-Cr7Ni molecular rings as detected by μsR

    Sanna, S.; Arosio, P.; Bordonali, L.; Adelnia, F.; Mariani, M.; Garlatti, E.; Baines, C.; Amato, A.; Sabareesh, K. P.V.; Timco, G.; Winpenny, R. E.P.; Blundell, S. J.; Lascialfari, A.

    2017-01-01

    Muon spin rotation measurements were used to investigate the spin dynamics of heterometallic Cr7Ni and Cr7Ni-Cu-Cr7Ni molecular clusters. In Cr7Ni the magnetic ions are arranged in a quasiplanar ring and interact via an antiferromagnetic exchange coupling constant J, while Cr7Ni-Cu-Cr7Ni is composed of two Cr7Ni linked by a bridging moiety containing one Cu ion, that induces an inter-ring ferromagnetic interaction J ≪ J. The longitudinal muon relaxation rate λ collected at low magnetic fields...

  16. Comparison of three Ni-Hard I alloys

    Dogan, Omer N.; Hawk, Jeffrey A.; Rice, J. (Texaloy Foundry Co., Inc., Floresville, Texas)

    2004-09-01

    This report documents the results of an investigation which was undertaken to reveal the similarities and differences in the mechanical properties and microstructural characteristics of three Ni-Hard I alloys. One alloy (B1) is ASTM A532 class IA Ni-Hard containing 4.2 wt. pct. Ni. The second alloy (B2) is similar to B1 but higher in Cr, Si, and Mo. The third alloy (T1) also falls in the same ASTM specification, but it contains 3.3 wt. pct. Ni. The alloys were evaluated in both as-cast and stress-relieved conditions except for B2, which was evaluated in the stress-relieved condition only. While the matrix of the high Ni alloys is composed of austenite and martensite in both conditions, the matrix of the low Ni alloy consists of a considerable amount of bainite, in addition to the martensite and the retained austenite in as cast condition, and primarily bainite, with some retained austenite, in the stress relieved condition. It was found that the stress relieving treatment does not change the tensile strength of the high Ni alloy. Both the as cast and stress relieved high Ni alloys had a tensile strength of about 350 MPa. On the other hand, the tensile strength of the low Ni alloy increased from 340 MPa to 452 MPa with the stress relieving treatment. There was no significant difference in the wear resistance of these alloys in both as-cast and stressrelieved conditions.

  17. An investigation of the oxidized Ni/InAs interface

    Venter, A.; Botha, J.R.; Swart, H.C.; Naidoo, S.; Olivier, E.J.

    2009-01-01

    Ni was resistively deposited onto bulk InAs and subsequently oxidized in an O 2 atmosphere. The anneal temperature and time were 450 deg. C and 2.5 h, respectively. X-ray diffraction of the oxidized Ni/InAs sample revealed the formation of In 3 Ni 2 and In 2 O 3 on the front suggesting inter diffusion of In, Ni and O. NiO was not detected by X-ray diffraction. In a preliminary study, using glass as a substrate, NiO readily formed when using these oxidation parameters. Conductivity measurements of the oxidized Ni/InAs surface revealed a conducting front and insulating rear surface while TEM of the Ni/InAs interface revealed an intermediate amorphous diffusion zone between the 'oxidized' Ni layer and the bulk InAs. A closer investigation of the intermediate layer supports the X-ray diffraction results, suggesting compound formation due to diffusion of oxygen and nickel into the substrate, and out-diffusion of In and As from the bulk of the sample. AES was used to further elucidate these results.

  18. An investigation of the oxidized Ni/InAs interface

    Venter, A., E-mail: andre.venter@nmmu.ac.z [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa); Botha, J.R. [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa); Swart, H.C. [Department of Physics, University of the Free State, PO Box 339, Bloemfontein 9300 (South Africa); Naidoo, S.; Olivier, E.J. [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa)

    2009-12-01

    Ni was resistively deposited onto bulk InAs and subsequently oxidized in an O{sub 2} atmosphere. The anneal temperature and time were 450 deg. C and 2.5 h, respectively. X-ray diffraction of the oxidized Ni/InAs sample revealed the formation of In{sub 3}Ni{sub 2} and In{sub 2}O{sub 3} on the front suggesting inter diffusion of In, Ni and O. NiO was not detected by X-ray diffraction. In a preliminary study, using glass as a substrate, NiO readily formed when using these oxidation parameters. Conductivity measurements of the oxidized Ni/InAs surface revealed a conducting front and insulating rear surface while TEM of the Ni/InAs interface revealed an intermediate amorphous diffusion zone between the 'oxidized' Ni layer and the bulk InAs. A closer investigation of the intermediate layer supports the X-ray diffraction results, suggesting compound formation due to diffusion of oxygen and nickel into the substrate, and out-diffusion of In and As from the bulk of the sample. AES was used to further elucidate these results.

  19. Oxidation of hydrogen peroxide by [Ni III (cyclam)

    The kinetics of oxidation of H2O2 by [NiIII(cyclam)]3+, [NiIIIL1], was studied in aqueous acidic media at 25°C and I = 0.5M (NaClO4). The [NiIIIL1] to [NiIIL1] reduction was found to be fast in the presence of Cu(II) ion than the oxidation of the cyclam ligand by ·OH. The rate constant showed an inverse acid dependence on H+ ...

  20. Level density of radioactive doubly-magic nucleus 56Ni

    Santhosh Kumar, S.; Rengaiyan, R.; Victor Babu, A.; Preetha, P.

    2012-01-01

    In this work the single particle energies are obtained by diagonalising the Nilsson Hamiltonian in the cylindrical basis and are generated up to N =11 shells for the isotopes of Ni from A = 48-70, emphasizing the three magic nuclei viz, 48 Ni, 56 Ni and 68 Ni. The statistical quantities like excitation energy, level density parameter and nuclear level density which play the important roles in the nuclear structure and nuclear reactions can be calculated theoretically by means of the Statistical or Partition function method. Hence the statistical model approach is followed to probe the dynamical properties of the nucleus in the microscopic level

  1. CVD Graphene/Ni Interface Evolution in Sulfuric Electrolyte

    Yivlialin, Rossella; Bussetti, Gianlorenzo; Duò, Lamberto

    2018-01-01

    Systems comprising single and multilayer graphene deposited on metals and immersed in acid environments have been investigated, with the aim of elucidating the mechanisms involved, for instance, in hydrogen production or metal protection from corrosion. In this work, a relevant system, namely...... chemical vapor deposited (CVD) multilayer graphene/Ni (MLGr/Ni), is studied when immersed in a diluted sulfuric electrolyte. The MLGr/Ni electrochemical and morphological properties are studied in situ and interpreted in light of the highly oriented pyrolytic graphite (HOPG) electrode behavior, when...... immersed in the same electrolyte. Following this interpretative framework, the dominant role of the Ni substrate in hydrogen production is clarified....

  2. Design and fabrication of Ni nanowires having periodically hollow nanostructures

    Sada, Takao; Fujigaya, Tsuyohiko; Nakashima, Naotoshi

    2014-09-01

    We propose a concept for the design and fabrication of metal nanowires having periodically hollow nanostructures inside the pores of an anodic aluminum oxide (AAO) membrane using a sacrificial metal. In this study, nickel (Ni) and silver (Ag) were used as the base metal and the sacrificial metal, respectively. Alternating an applied potential between -0.4 and -1.0 V provided alternatively deposited Ni and Ag segments in a Ni-Ag `barcode' nanowire with a diameter of 18 or 35 nm. After etching away the Ag segments, we fabricated Ni nanowires with nanopores of 12 +/- 5.3 nm. Such nanostructure formation is explained by the formation of a Ni shell layer over the surface of the Ag segments due to the strong affinity of Ni2+ for the interior surfaces of AAO. The Ni shell layer allows the Ni segments to remain even after dissolution of the Ag segments. Because the electroplating conditions can be easily controlled, we could carefully adjust the size and pitch of the periodically hollow nanospaces. We also describe a method for the fabrication of Ni nanorods by forming an Ag shell instead of a Ni shell on the Ni-Ag barcode nanowire, in which the interior of the AAO surfaces was modified with a compound bearing a thiol group prior to electroplating.We propose a concept for the design and fabrication of metal nanowires having periodically hollow nanostructures inside the pores of an anodic aluminum oxide (AAO) membrane using a sacrificial metal. In this study, nickel (Ni) and silver (Ag) were used as the base metal and the sacrificial metal, respectively. Alternating an applied potential between -0.4 and -1.0 V provided alternatively deposited Ni and Ag segments in a Ni-Ag `barcode' nanowire with a diameter of 18 or 35 nm. After etching away the Ag segments, we fabricated Ni nanowires with nanopores of 12 +/- 5.3 nm. Such nanostructure formation is explained by the formation of a Ni shell layer over the surface of the Ag segments due to the strong affinity of Ni2+ for the

  3. Comparative study of NiW, NiMo and MoW prepared by mechanical alloying

    Gonzalez, G.; Sagarzazu, A.; Villalba, R.; Ochoa, J.

    2007-01-01

    The present work concern the amorphisation process induced by mechanical alloying in the NiW, NiMo and MoW systems. The alloys chosen combine a group of transition elements varying from very similar atomic radius and electronic valences (MoW) to different ones (NiW and NiMo). The three systems achieved an amorphous state after 50 h of milling. The mechanism of amorphisation proposed for NiW and NiMo was the combined effect of an excess concentration of the solute atoms entering into the structure of one of the elements and a critical concentration of defects. Continuous formation of an amorphous phase at the interface of the crystalline phase was observed during the process. MoW seems to amorphize by continuous reduction of grain size down to a critical value where the amorphisation takes place

  4. The irradiation hardening of Ni-Mo-Cr and Ni-W-Cr alloy under Xe26+ ion irradiation

    Chen, Huaican; Hai, Yang; Liu, Renduo; Jiang, Li; Ye, Xiang-xi; Li, Jianjian; Xue, Wandong; Wang, Wanxia; Tang, Ming; Yan, Long; Yin, Wen; Zhou, Xingtai

    2018-04-01

    The irradiation hardening of Ni-Mo-Cr and Ni-W-Cr alloy was investigated. 7 MeV Xe26+ ion irradiation was performed at room temperature and 650 °C with peak damage dose from 0.05 to 10 dpa. With the increase of damage dose, the hardness of Ni-Mo-Cr and Ni-W-Cr alloy increases, and reaches saturation at damage dose ≥1 dpa. Moreover, the damage dose dependence of hardness in both alloys can be described by the Makin and Minter's equation, where the effective critical volume of obstacles can be used to represent irradiation hardening resistance of the alloys. Our results also show that Ni-W-Cr alloy has better irradiation hardening resistance than Ni-Mo-Cr alloy. This is ascribed to the fact that the W, instead of Mo in the alloy, can suppress the formation of defects under ion irradiation.

  5. Flexible bottom-emitting white organic light-emitting diodes with semitransparent Ni/Ag/Ni anode.

    Koo, Ja-Ryong; Lee, Seok Jae; Lee, Ho Won; Lee, Dong Hyung; Yang, Hyung Jin; Kim, Woo Young; Kim, Young Kwan

    2013-05-06

    We fabricated a flexible bottom-emitting white organic light-emitting diode (BEWOLED) with a structure of PET/Ni/Ag/Ni (3/6/3 nm)/ NPB (50 nm)/mCP (10 nm)/7% FIrpic:mCP (10 nm)/3% Ir(pq)(2) acac:TPBi (5 nm)/7% FIrpic:TPBi (5 nm)/TPBi (10 nm)/Liq (2 nm)/ Al (100 nm). To improve the performance of the BEWOLED, a multilayered metal stack anode of Ni/Ag/Ni treated with oxygen plasma for 60 sec was introduced into the OLED devices. The Ni/Ag/Ni anode effectively enhanced the probability of hole-electron recombination due to an efficient hole injection into and charge balance in an emitting layer. By comparing with a reference WOLED using ITO on glass, it is verified that the flexible BEWOLED showed a similar or better electroluminescence (EL) performance.

  6. Hydride Reactivity of Ni-II-X-Ni-II Entities : Mixed-Valent Hydrido Complexes and Reversible Metal Reduction

    Gehring, Henrike; Metzinger, Ramona; Herwig, Christian; Intemann, Julia; Harder, Sjoerd; Limberg, Christian

    After the lithiation of PYR-H2 (PYR2-=[{NC(Me)C(H)C(Me)NC6H3(iPr)2}2(C5H3N)]2-), which is the precursor of an expanded beta-diketiminato ligand system with two binding pockets, its reaction with [NiBr2(dme)] led to a dinuclear nickel(II)bromide complex, [(PYR)Ni(mu-Br)NiBr] (1). The bridging bromide

  7. Studies on the valence electronic structure of Fe and Ni in FexNi1−x ...

    structure of Fe and Ni in various Fex Ni1−x alloys. Since Kβ-to-Kα X-ray intensity ratio has been reported [2–7] to be a sensitive physical parameter to investigate the changes in the valence electronic structure of 3d-transition metals [2], we have undertaken the study of the valence electronic structure of Fe and Ni in the Fex ...

  8. Effects of Ni content on nanocrystalline Fe–Co–Ni ternary alloys synthesized by a chemical reduction method

    Chokprasombat, Komkrich, E-mail: komkrich28@gmail.com [Department of Physics, Faculty of Science, Thaksin University, Phatthalung 93210 Thailand (Thailand); Pinitsoontorn, Supree [Integrated Nanotechnology Research Center, Department of Physics, Faculty of Science, Khon Kaen University, Khon Kaen 40002 Thailand (Thailand); Maensiri, Santi [School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000 Thailand (Thailand)

    2016-05-01

    Magnetic properties of Fe–Co–Ni ternary alloys could be altered by changing of the particle size, elemental compositions, and crystalline structures. In this work, Fe{sub 50}Co{sub 50−x}Ni{sub x} nanoparticles (x=10, 20, 40, and 50) were prepared by the novel chemical reduction process. Hydrazine monohydrate was used as a reducing agent under the concentrated basic condition with the presence of poly(vinylpyrrolidone). We found that the nanoparticles were composed of Fe, Co and Ni with compositions according to the molar ratio of the metal sources. Interestingly, the particles were well-crystalline at the as-prepared state without post-annealing at high temperature. Increasing Ni content resulted in phase transformation from body centered cubic (bcc) to face centered cubic (fcc). For the fcc phase, the average particle size decreased when increased the Ni content; the Fe{sub 50}Ni{sub 50} nanoparticles had the smallest average size with the narrowest size distribution. In additions, the particles exhibited ferromagnetic properties at room temperature with the coercivities higher than 300 Oe, and the saturation magnetiation decreased with increasing Ni content. These results suggest that the structural and magnetic properties of Fe–Co–Ni alloys could be adjusted by varying the Ni content. - Highlights: • We prepared nanocrystalline Fe–Co–Ni alloys by a novel chemical reduction process. • Elemental compositions could be well controlled by the molar ratio of metal sources. • Particle size and magnetic properties clearly depended on the Ni contents. • Fe{sub 50}Co{sub 10}Ni{sub 40} exhibited high saturation magnetization of 126.3 emu/g.

  9. Effect of Ni content on the morphological evolution of Ni-YSZ solid oxide fuel cell electrodes

    Chen-Wiegart, Yu-chen Karen; Kennouche, David; Scott Cronin, J.; Barnett, Scott A.; Wang, Jun

    2016-02-01

    The coarsening of Ni in Ni-yttria-stabilized zirconia (YSZ) anodes is a potential cause of long term solid oxide fuel cells (SOFC) performance degradation. The specifics of the Ni-YSZ structure—including Ni/YSZ ratio, porosity, and particle size distributions—are normally selected to minimize anode polarization resistance, but they also impact long-term stability. A better understanding of how these factors influence long-term stability is important for designing more durable anodes. The effect of structural details, e.g., Ni-YSZ ratio, on Ni coarsening has not been quantified. Furthermore, prior measurements have been done by comparing evolved structures with control samples, such that sample-to-sample variations introduce errors. Here, we report a four dimensional (three spatial dimensions and time) study of Ni coarsening in Ni-YSZ anode functional layers with different Ni/YSZ ratios, using synchrotron x-ray nano-tomography. The continuous structural evolution was observed and analyzed at sub-100 nm resolution. It is shown quantitatively that increasing the Ni/YSZ ratio increases the Ni coarsening rate. This is due to both increased pore volume and a decrease in the YSZ volume fraction, such that there is more free volume and a less obtrusive YSZ network, both of which allow greater Ni coarsening. The results are shown to be in good agreement with a power-law coarsening model. The finding is critical for informing the design of SOFC electrode microstructures that limit coarsening and performance degradation.

  10. Formation of nickel germanides from Ni layers with thickness below 10 nm

    Jablonka, Lukas; Kubart, Tomas; Primetzhofer, Daniel; Abedin, Ahmad; Hellström, Per-Erik; Östling, Mikael; Jordan-Sweet, Jean; Lavoie, Christian; Zhang, Shi-Li; Zhang, Zhen

    2017-03-01

    The authors have studied the reaction between a Ge (100) substrate and thin layers of Ni ranging from 2 to 10 nm in thickness. The formation of metal-rich Ni5Ge3Ni5Ge3 was found to precede that of the monogermanide NiGe by means of real-time in situ x-ray diffraction during ramp-annealing and ex situ x-ray pole figure analyses for phase identification. The observed sequential growth of Ni5Ge3Ni5Ge3 and NiGe with such thin Ni layers is different from the previously reported simultaneous growth with thicker Ni layers. The phase transformation from Ni5Ge3Ni5Ge3 to NiGe was found to be nucleation-controlled for Ni thicknesses <5 nm<5 nm, which is well supported by thermodynamic considerations. Specifically, the temperature for the NiGe formation increased with decreasing Ni (rather Ni5Ge3Ni5Ge3) thickness below 5 nm. In combination with sheet resistance measurement and microscopic surface inspection of samples annealed with a standard rapid thermal processing, the temperature range for achieving morphologically stable NiGe layers was identified for this standard annealing process. As expected, it was found to be strongly dependent on the initial Ni thickness

  11. The Ni-rich Part of the Ni-P-Sn System: Isothermal Sections

    Schmetterer, C.; Vízdal, J.; Kroupa, Aleš; Kodentsov, A.; Ipser, H.

    2009-01-01

    Roč. 38, č. 11 (2009), s. 2275-2300 ISSN 0361-5235 R&D Projects: GA MŠk(CZ) OC08053 Institutional research plan: CEZ:AV0Z20410507 Keywords : lead free solder * phase diagram * Ni-P-Sn Subject RIV: BJ - Thermodynamics Impact factor: 1.428, year: 2009

  12. Fabrication of TiNi/CFRP smart composite using cold drawn TiNi wires

    Xu, Ya; Otsuka, Kazuhiro; Toyama, Nobuyuki; Yoshida, Hitoshi; Jang, Byung-Koog; Nagai, Hideki; Oishi, Ryutaro; Kishi, Teruo

    2002-07-01

    In recent years, pre-strained TiNi shape memory alloys (SMA) have been used for fabricating smart structure with carbon fibers reinforced plastics (CFRP) in order to suppress microscopic mechanical damages. However, since the cure temperature of CFRP is higher than the reverse transformation temperatures of TiNi SMA, special fixture jigs have to be used for keeping the pre-strain during fabrication, which restricted its practical application. In order to overcome this difficulty, we developed a new method to fabricate SMA/CFRP smart composites without using special fixture jigs by controlling the transformation temperatures of SMA during fabrication. This method consists of using heavily cold-worked wires to increase the reverse transformation temperatures, and of using flash electrical heating of the wires after fabrication in order to decrease the reverse transformation temperatures to a lower temperature range again without damaging the epoxy resin around SMA wires. By choosing proper cold-working rate and composition of TiNi alloys, the reverse transformation temperatures were well controlled, and the TiNi/CFRP hybrid smart composite was fabricated without using special fixture jigs. The damage suppressing effect of cold drawn wires embedded in CFRP was confirmed.

  13. Transformation dynamics of Ni clusters into NiO rings under electron beam irradiation

    Knez, Daniel, E-mail: daniel.knez@felmi-zfe.at [Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17, 8010 Graz (Austria); Graz Centre for Electron Microscopy, Steyrergasse 17, 8010 Graz (Austria); Thaler, Philipp; Volk, Alexander [Institute of Experimental Physics, Graz University of Technology, Petersgasse 16, 8010 Graz (Austria); Kothleitner, Gerald [Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17, 8010 Graz (Austria); Graz Centre for Electron Microscopy, Steyrergasse 17, 8010 Graz (Austria); Ernst, Wolfgang E. [Institute of Experimental Physics, Graz University of Technology, Petersgasse 16, 8010 Graz (Austria); Hofer, Ferdinand [Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17, 8010 Graz (Austria); Graz Centre for Electron Microscopy, Steyrergasse 17, 8010 Graz (Austria)

    2017-05-15

    We report the transformation of nickel clusters into NiO rings by an electron beam induced nanoscale Kirkendall effect. High-purity nickel clusters consisting of a few thousand atoms have been used as precursors and were synthesized with the superfluid helium droplet technique. Aberration-corrected, analytical scanning transmission electron microscopy was applied to oxidise and simultaneously analyse the nanostructures. The transient dynamics of the oxidation could be documented by time lapse series using high-angle annular dark-field imaging and electron energy-loss spectroscopy. A two-step Cabrera-Mott oxidation mechanism was identified. It was found that water adsorbed adjacent to the clusters acts as oxygen source for the electron beam induced oxidation. The size-dependent oxidation rate was estimated by quantitative EELS measurements combined with molecular dynamics simulations. Our findings could serve to better control sample changes during examination in an electron microscope, and might provide a methodology to generate other metal oxide nanostructures. - Highlights: • Beam induced conversion of Ni clusters into crystalline NiO rings has been observed. • Ni clusters were grown with the superfluid He-droplet technique. • oxidizeSTEM was utilized to investigate and simultaneously oxidize these clusters. • Oxidation dynamics was captured in real-time. • Cluster sizes and the oxidation rate were estimated via EELS and molecular dynamics.

  14. Structural conditions of achieving maximum ductility of two-phase Ni-NiO alloys

    Grabin, V.V.; Dabizha, E.V.; Movchan, B.A.

    1984-01-01

    A study was made on possibility of increasing ductility of two-phase Ni-NiO alloys, proJuced by traditional technology: ingot smelting, rolling and corresponding annealing for production of grain with certain size. The correlation of mechanical properties of Ni-NiO alloys and pure nickel shows that completion of the structural conJition D--lambda (where D - the average grain diameter, lambda - the value of free path between particles) in two-phase alloys enables: to increase the ultimate strength 1.5 times and preserve the basic level of pure nickel plasticity - at 20 deg C; to increase plasticity 1.4-1.5 times with preserved basic level of pure nickel plasticity - at 800 deg C. The conclusions testify to possibility of controlling mechanical properties of two-phase alloys using structural D and lambda parameters It is proposed that creation of structures with more unifor m particle distribution with respect to sizes will the accompanied by further increase of plasticity under D=lambda condition

  15. Experimental study of the $^{66}$Ni$(d,p)^{67}$Ni one-neutron transfer reaction

    Diriken, J.; Andreyev, A.N.; Antalic, S.; Bildstein, V.; Blazhev, A.; Darby, I.G.; De Witte, H.; Eberth, J.; Elseviers, J.; Fedosseev, V.N.; Flavigny, F.; Fransen, Ch.; Georgiev, G.; Gernhauser, R.; Hess, H.; Huyse, M.; Jolie, J.; Kröll, Th.; Krücken, R.; Lutter, R.; Marsh, B.A.; Mertzimekis, T.; Muecher, D.; Orlandi, R.; Pakou, A.; Raabe, R.; Randisi, G.; Reiter, P.; Roger, T.; Seidlitz, M.; Seliverstov, M.; Sotty, C.; Tornqvist, H.; Van De Walle, J.; Van Duppen, P.; Voulot, D.; Warr, N.; Wenander, F.; Wimmer, K.

    2015-01-01

    The quasi-SU(3) sequence of the positive parity $νg_{9/2}, d_{5/2}, s_{1/2}$ orbitals above the N=40 shell gap are assumed to induce strong quadrupole collectivity in the neutron-rich Fe (Z=26) and Cr (Z=24) isotopes below the nickel region. In this paper the position and strength of these single-particle orbitals are characterized in the neighborhood of $^{68}$Ni (Z=28,N=40) through the $^{66}$Ni($d,p$)$^{67}$Ni one-neutron transfer reaction at 2.95 MeV/nucleon in inverse kinematics, performed at the REX-ISOLDE facility in CERN. A combination of the Miniball $\\gamma$-array and T-REX particle-detection setup was used and a delayed coincidence technique was employed to investigate the 13.3-$\\mu$s isomer at 1007 keV in $^{67}$Ni. Excited states up to an excitation energy of 5.8 MeV have been populated. Feeding of the $νg_{9/2}$ (1007 keV) and $νd_{5/2}$ (2207 keV and 3277 keV) positive-parity neutron states and negative parity ($νpf$) states have been observed at low excitation energy. The extracted relativ...

  16. Energies of Electronic States of Ni (II) Ion in NiO-Al2O3 Catalyst Prepared by Impregnation

    Obadovic, D. Z.; Kiurski, J.; Marinkovic-Neducin, R. P.

    2007-01-01

    The behavior of NiO-Al2O3 catalysts is strongly dependent on the preparation method, as well as on pretreatment conditions. In the present work we investigated the influences of Ni(II) ion on NiO-Al2O3 catalysts properties due to the preparation by impregnation method. Based on experimental diffuse reflectance spectroscopy (DRS) data of electronic d-d transitions of Ni (II) promoter ion the energies of electronic states in spinel-like structure were calculated, and the most probable scheme of molecular orbital have been proposed

  17. Interacción familiar y desarrollo emocional en niños y niñas

    Gloria Cecilia Henao López

    2009-01-01

    Full Text Available En la presente investigación se tuvo como objetivo principal abordar los estilos de interacción de padres y madres de niños y niñas preescolares y su relación con el desarrollo emocional de sus hijos e hijas (235 niños y 169 niñas entre cinco y seis años de edad. Las dimensiones que se consideraron para evaluar el nivel emocional de los niños y niñas fueron: autorregulación, comprensión emocional, y empatía. Como primer aspecto describimos los tipos de interacción con sus hijos e hijas y el desarrollo emocional de los niños y niñas evaluados. Un segundo aspecto que se abordó, es el de explorar las asociaciones entre el estilo de interacción familiar y el desarrollo emocional infantil. El instrumento utilizado dirigido a los padres y madres fue la Escala de Identificación de Prácticas Educativas Familiares (PEF, versión española realizada por Alonso y Román; a los niños y niñas les aplicamos la evaluación del desempeño emocional (EDEI, que se construye como parte de esta investigación. Se trabajó con una muestra de 404 niños y niñas, y sus respectivos padres y madres. Los resultados obtenidos en esta investigación resaltan el estilo equilibrado como generador de conductas adecuadas y adaptativas en el niño o niña, al igual que rescata este estilo como el que más posibilita el nivel de comprensión emocional en los niños y niñas de nuestro estudio.

  18. Enhanced photocatalytic efficiency in zirconia buffered n-NiO/p-NiO single crystalline heterostructures by nanosecond laser treatment

    Molaei, R.; Bayati, M. R.; Alipour, H. M.; Nori, S.; Narayan, J. [Department of Materials Science and Engineering, NC State University, EB-1, Raleigh, North Carolina 27695-7907 (United States)

    2013-06-21

    We report the formation of NiO based single crystalline p-n junctions with enhanced photocatalytic activity induced by pulsed laser irradiation. The NiO epilayers were grown on Si(001) substrates buffered with cubic yttria-stabilized zirconia (c-YSZ) by using pulsed laser deposition. The NiO/c-YSZ/Si heterostructures were subsequently laser treated by 5 pulses of KrF excimer laser (pulse duration = 25 Multiplication-Sign 10{sup -9} s) at lower energies. Microstructural studies, conducted by X-ray diffraction ({theta}-2{theta} and {phi} techniques) and high resolution transmission electron microscope, showed a cube-on-cube epitaxial relationship at the c-YSZ/Si interface; the epitaxial relationship across the NiO/c-YSZ interface was established as NiO<111 > Double-Vertical-Line Double-Vertical-Line c-YSZ<001> and in-plane NiO<110> Double-Vertical-Line Double-Vertical-Line c-YSZ<100>. Electron microscopy studies showed that the interface between the laser annealed and the pristine region as well as the NiO/c-YSZ interface was atomically sharp and crystallographically continuous. The formation of point defects, namely oxygen vacancies and NiO, due to the coupling of the laser photons with the NiO epilayers was confirmed by XPS. The p-type electrical characteristics of the pristine NiO epilayers turned to an n-type behavior and the electrical conductivity was increased by one order of magnitude after laser treatment. Photocatalytic activity of the pristine (p-NiO/c-YSZ/Si) and the laser-annealed (n-NiO/p-NiO/c-YSZ/Si) heterostructures were assessed by measuring the decomposition rate of 4-chlorophenol under UV light. The photocatalytic reaction rate constants were determined to be 0.0059 and 0.0092 min{sup -1} for the as-deposited and the laser-treated samples, respectively. The enhanced photocatalytic efficiency was attributed to the suppressed charge carrier recombination in the NiO based p-n junctions and higher electrical conductivity. Besides, the oxygen vacancies

  19. Tritium-tracer study of catalytic hydrogenation reaction of ethylene on Ni, Pt and Ni-Pt

    Matsuyama, M.; Yasuda, Y.; Takeuchi, T.

    1978-01-01

    The influence of the pressure of tritiated hydrogen on the rate of the formation of tritiated ethylene, X, and that of tritiated ethane, Z, in the hydrogenation reaction of ethylene on Ni, Pt and Ni-Pt (1:1) alloy catalysts was investigated. The ratio of the rate of the exchange to that of the hydrogenation, selectivity X/Z, decreased markedly with the increase in the pressure of the tritiated hydrogen and the order of X/Z was Ni>Ni-Pt>Pt. These results were interpreted in terms of the difference in the amount of chemisorbed tritium on each metal catalyst. (orig.) [de

  20. Lamellar-crossing-structured Ni(OH){sub 2}/CNTs/Ni(OH){sub 2} nanocomposite for electrochemical supercapacitor materials

    Wu, Qingnan [Department of Chemistry, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092 (China); Wen, Ming, E-mail: m_wen@tongji.edu.cn [Department of Chemistry, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092 (China); Shanghai Key Lab of Chemical Assessment and Sustainability, Tongji University, Shanghai 200092 (China); Chen, Shipei [Department of Chemistry, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092 (China); Wu, Qingsheng [Department of Chemistry, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092 (China); Shanghai Key Lab of Chemical Assessment and Sustainability, Tongji University, Shanghai 200092 (China)

    2015-10-15

    Ni(OH){sub 2}/CNTs/Ni(OH){sub 2} lamellar-crossing-nanostructure with a single lamellar spacing of ∼5 nm was effectively constructed through two-phase-interface reaction process followed by the CNTs crossed among the lamellar-nanostructured Ni(OH){sub 2}. The resultant nanocomposite can offer large active surface areas and short diffusion paths for electrons and ions, and is investigated as a potential pseudocapacitor electrode material for electrochemical energy storage applications. Electrochemical data demonstrate that the as-prepared nanocomposite exhibits a high specific capacitance of ∼1600 F g{sup −1} at the scan rate of 1 mV s{sup −1} in 6 M KOH solution at normal pressure and temperature, which is great higher than Ni(OH){sub 2} (∼1200 F g{sup −1}). Furthermore, Ni(OH){sub 2}/CNTs/Ni(OH){sub 2} nanocomposite shows a higher energy density (∼125 Wh kg{sup −1}, 2 A g{sup −1}) and has a slightly decrease of 5% in specific capacitance after 1000 continuous charge/discharge cycles. - Graphical abstract: As-constructed Ni(OH){sub 2}/CNTs/Ni(OH){sub 2} lamellar-crossing-nanostructure exhibits remarkable enhancement in electrochemical stability and high specific capacity of ∼1600 F g{sup −1} at a scan rate of 1 mV s{sup −1}, suggesting promising potential for supercapacitor applications. - Highlights: • New designed lamellar-crossing-structured Ni(OH){sub 2}/CNTs/Ni(OH){sub 2} nanocomposites have been firstly reported in this work. • Ni(OH){sub 2}/CNTs/Ni(OH){sub 2} lamellar-crossing-nanostructures show firm nanostructure and excellent electrochemical stability. • Ni(OH){sub 2}/CNTs/Ni(OH){sub 2} nanocomposites exhibit excellent specific capacitance. • Ni(OH){sub 2}/CNTs/Ni(OH){sub 2} nanocomposites have the potential application in electrochemical energy storage applications.

  1. Amorphous NiFe-OH/NiFeP Electrocatalyst Fabricated at Low Temperature for Water Oxidation Applications

    Liang, Hanfeng

    2017-04-11

    Water splitting driven by electricity or sunlight is one of the most promising ways to address the global terawatt energy needs of future societies; however, its large-scale application is limited by the sluggish kinetics of the oxygen evolution reaction (OER). NiFe-based compounds, mainly oxides and hydroxides, are well-known OER catalysts and have been intensively studied; however, the utilization of the synergistic effect between two different NiFe-based materials to further boost the OER performance has not been achieved to date. Here, we report the rapid conversion of NiFe double hydroxide into metallic NiFeP using PH3 plasma treatment and further construction of amorphous NiFe hydroxide/NiFeP/Ni foam as efficient and stable oxygen-evolving anodes. The strong electronic interactions between NiFe hydroxide and NiFeP significantly lower the adsorption energy of H2O on the hybrid and thus lead to enhanced OER performance. As a result, the hybrid catalyst can deliver a geometrical current density of 300 mA cm–2 at an extremely low overpotential (258 mV, after ohmic-drop correction), along with a small Tafel slope of 39 mV decade–1 and outstanding long-term durability in alkaline media.

  2. Photoelectrochemical Water Splitting Properties of Ti-Ni-Si-O Nanostructures on Ti-Ni-Si Alloy

    Ting Li

    2017-10-01

    Full Text Available Ti-Ni-Si-O nanostructures were successfully prepared on Ti-1Ni-5Si alloy foils via electrochemical anodization in ethylene glycol/glycerol solutions containing a small amount of water. The Ti-Ni-Si-O nanostructures were characterized by field-emission scanning electron microscopy (FE-SEM, energy dispersive spectroscopy (EDS, X-ray diffraction (XRD, and diffuse reflectance absorption spectra. Furthermore, the photoelectrochemical water splitting properties of the Ti-Ni-Si-O nanostructure films were investigated. It was found that, after anodization, three different kinds of Ti-Ni-Si-O nanostructures formed in the α-Ti phase region, Ti2Ni phase region, and Ti5Si3 phase region of the alloy surface. Both the anatase and rutile phases of Ti-Ni-Si-O oxide appeared after annealing at 500 °C for 2 h. The photocurrent density obtained from the Ti-Ni-Si-O nanostructure photoanodes was 0.45 mA/cm2 at 0 V (vs. Ag/AgCl in 1 M KOH solution. The above findings make it feasible to further explore excellent photoelectrochemical properties of the nanostructure-modified surface of Ti-Ni-Si ternary alloys.

  3. Photoelectrochemical Water Splitting Properties of Ti-Ni-Si-O Nanostructures on Ti-Ni-Si Alloy.

    Li, Ting; Ding, Dongyan; Dong, Zhenbiao; Ning, Congqin

    2017-10-31

    Ti-Ni-Si-O nanostructures were successfully prepared on Ti-1Ni-5Si alloy foils via electrochemical anodization in ethylene glycol/glycerol solutions containing a small amount of water. The Ti-Ni-Si-O nanostructures were characterized by field-emission scanning electron microscopy (FE-SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), and diffuse reflectance absorption spectra. Furthermore, the photoelectrochemical water splitting properties of the Ti-Ni-Si-O nanostructure films were investigated. It was found that, after anodization, three different kinds of Ti-Ni-Si-O nanostructures formed in the α-Ti phase region, Ti₂Ni phase region, and Ti₅Si₃ phase region of the alloy surface. Both the anatase and rutile phases of Ti-Ni-Si-O oxide appeared after annealing at 500 °C for 2 h. The photocurrent density obtained from the Ti-Ni-Si-O nanostructure photoanodes was 0.45 mA/cm² at 0 V (vs. Ag/AgCl) in 1 M KOH solution. The above findings make it feasible to further explore excellent photoelectrochemical properties of the nanostructure-modified surface of Ti-Ni-Si ternary alloys.

  4. Characterization and electrochemical properties of Ni(Si)/Ni5Si2 multiphase coatings prepared by HVOF spraying

    Verdian, M. M.; Raeissi, K.; Salehi, M.

    2012-11-01

    Ni(Si)/Ni5Si2 powders were produced by mechanical alloying (MA) of Ni-25 at.% Si powder mixture. Then, the as-milled powders were sprayed onto copper substrate using high velocity oxy-fuel (HVOF) process. The phase composition and microstructure of the coatings were examined by X-ray diffractometry and scanning electron microscopy. Polarization tests and electrochemical impedance spectroscopy (EIS) measurements were also employed to study corrosion performance of the coatings in 3.5% NaCl solution. The results showed that although single phase Ni3Si was formed during annealing of Ni(Si)/Ni5Si2 powders, but, only Ni(Si) and Ni5Si2 are present in HVOF coatings and no new phase has been formed during spraying. The coatings had microhardness up to 746 HV0.05. Further investigations showed the corrosion performance of multiphase coatings in 3.5% NaCl solution was better than that of copper substrate. The phase transitions during MA, HVOF and annealing processes were discussed in association with Ni-Si phase diagram and nature of each process.

  5. Viviendo con VIH/SIDA: Las voces ocultas de los niños y niñas afectados

    Luz Adriana Aristizábal Becerra

    2015-01-01

    El VIH/SIDA no es solamente un problema de salud, sino también un problema social. Los primeros casos de VIH/SIDA en niños se describen en 1982 en Estados Unidos, y desde entonces el número de niños infectados y afectados continúa incrementándose, hasta convertirse en lo que en la actualidad se denota como una pandemia. Objetivo. Posibilitar un espacio para que los niños y niñas afectados por el VIH/SIDA, puedan expresar sus vivencias en torno al padecimiento propio y/o de sus padres. Metodol...

  6. Influence of Ni/Co molar ratio on electromagnetic properties and microwave absorption performances for Ni/Co paraffin composites

    Yan, S.J., E-mail: shaojiuyan@126.com [Department of Structural Steel, Functional Materials and Heat Treatment Processing, AVIC Beijing Institute of Aeronautical Materials, Beijing 100095 (China); Aviation Key Laboratory of Science and Technology on Stealth Materials, Beijing 100095 (China); Dai, S.L. [The Office of AVIC Beijing Institute of Aeronautical Materials, Beijing 100095 (China); Ding, H.Y.; Wang, Z.Y. [Aviation Key Laboratory of Science and Technology on Stealth Materials, Beijing 100095 (China); Liu, D.B [Department of Structural Steel, Functional Materials and Heat Treatment Processing, AVIC Beijing Institute of Aeronautical Materials, Beijing 100095 (China)

    2014-05-01

    Ni and Co metallic microparticles with submicron size were synthesized with a simple wet chemical reduction method at a relatively low temperature. Then their morphologies and structures were characterized by SEM and XRD. Ni metallic microparticles have spherical-shape morphology with fcc crystalline structure, however, Co has a distinct leaf-like morphology with the fcc and hcp mixed phases crystalline structures. For the characterization of their electromagnetic properties, paraffin matrix composites containing different molar ratio Ni and Co mixture powder as fillers were prepared. It was found that both the electromagnetic properties and electromagnetic microwave absorption performances of absorber layer were remarkably influenced by Ni/Co molar ratio. The electromagnetic microwave absorption performances were significantly improved by blending Ni and Co metallic microparticles into paraffin matrix with changing Ni/Co molar ratio, and enhanced mechanism were discussed. - Highlights: • Ni and Co microparticles were synthesized by a wet chemical reduction method. • EM properties of absorber were remarkably influenced by Ni/Co molar ratio. • EMA performances can be adjusted by artificially changing Co/Ni molar ratio. • Enhanced EMA performances result from multiple EM attenuation mechanisms.

  7. Synergetic interface between NiO/Ni3S2 nanosheets and carbon nanofiber as binder-free anode for highly reversible lithium storage

    Jiang, Jialin; Ma, Chao; Yang, Yinbo; Ding, Jingjing; Ji, Hongmei; Shi, Shaojun; Yang, Gang

    2018-05-01

    A novel heterostructure of NiO/Ni3S2 nanoflake is synthesized and composited with carbon nanofibers (CNF) membrane. NiO/Ni3S2 nanoflakes are homogeneously dispersed in CNF network, herein, NiO/Ni3S2 like leaf and CNF like branch. Carbon nanofibers network efficiently prevents the pulverization and buffers the volume changes of NiO/Ni3S2, meanwhile, NiO/Ni3S2 nanoflakes through the conductive channels of carbon nanofibers own improved Li+ diffusion ability and structural stability. The capacity of NiO/Ni3S2/CNF reaches to 519.2 mA g-1 after 200 cycles at the current density of 0.5 A g-1 while NiO/Ni3S2 fades to 71 mAh g-1 after 40 cycles. Owing to the synergetic structure, the resultant binder-free electrode NiO/Ni3S2/carbon nanofibers shows an excellent reversible lithium storage capability.

  8. Vacuum-Free, Maskless Patterning of Ni Electrodes by Laser Reductive Sintering of NiO Nanoparticle Ink and Its Application to Transparent Conductors

    Lee, Daeho; Paeng, Dongwoo; Park, Hee K.; Grigoropoulos, Costas P.

    2014-01-01

    © 2014 American Chemical Society. We introduce a method for direct patterning of Ni electrodes through selective laser direct writing (LDW) of NiO nanoparticle (NP) ink. High-resolution Ni patterns are generated from NiO NP thin films by a vacuum

  9. Residual stress in Ni-W electrodeposits

    Mizushima, Io; Tang, Peter Torben; Hansen, Hans Nørgaard

    2006-01-01

    In the present work, the residual stress in Ni–W layers electrodeposited from electrolytes based on NiSO4 and Na2WO4, is investigated. Citrate, glycine and triethanolamine were used as complexing agents, enabling complex formation between the nickel ion and tungstate. The results show that the type...... of complexing agent and the current efficiency have an influence on the residual stress. In all cases, an increase in tensile stress in the deposit with time after deposition was observed. Pulse plating could improve the stress level for the electrolyte containing equal amounts of citrate...

  10. Anomalous Hall effect in polycrystalline Ni films

    Guo, Zaibing

    2012-02-01

    We systematically studied the anomalous Hall effect in a series of polycrystalline Ni films with thickness ranging from 4 to 200 nm. It is found that both the longitudinal and anomalous Hall resistivity increased greatly as film thickness decreased. This enhancement should be related to the surface scattering. In the ultrathin films (46 nm thick), weak localization corrections to anomalous Hall conductivity were studied. The granular model, taking into account the dominated intergranular tunneling, has been employed to explain this phenomenon, which can explain the weak dependence of anomalous Hall resistivity on longitudinal resistivity as well. © 2011 Elsevier Ltd. All rights reserved.

  11. Comparison of Corrosion Behavior of Electrochemically Deposited Nano-Cobalt-Coated Ni Sheet

    Nasser Al-Aqeeli

    2013-01-01

    Full Text Available Corrosion behavior of nano-coblat-coated Ni sheet was compared with pure Ni and 20% Fe-Ni alloy sheet using potentiodynamic polarization and linear polarization technique in 0.1 M NaCl solution at room temperature. Results showed that corrosion resistance properties of nano-Co-coated Ni sheet were almost same as that of pure Ni sheet, however corrosion resistance of 20% Fe-Ni sheet was decreased significantly. Pitting potential of 20% Fe-Ni sheet was subsequently decreased as compared to pure Ni sheet as well as nano-cobalt-coated Ni sheet. SEM/EDS analysis of the corroded surfaces showed that both pure Ni and nano-coblat-coated Ni sheet did not show any appreciable corrosion however significant corrosion was observed in the case of 20% Fe-Ni sheet.

  12. Structure determination of the ordered (2 × 1) phase of NiSi surface alloy on Ni(111) using low-energy electron diffraction

    Sazzadur Rahman, Md.; Amirul Islam, Md.; Saha, Bidyut Baran; Nakagawa, Takeshi; Mizuno, Seigi

    2015-12-01

    The (2 × 1) structure of the two-dimensional nickel silicide surface alloy on Ni(111) was investigated using quantitative low-energy electron diffraction analysis. The unit cell of the determined silicide structure contains one Si and one Ni atom, corresponding to a chemical formula of NiSi. The Si atoms adopt substitutional face-centered cubic hollow sites on the Ni(111) substrate. The Ni-Si bond lengths were determined to be 2.37 and 2.34 Å. Both the alloy surface and the underlying first layers of Ni atoms exhibit slight corrugation. The Ni-Si interlayer distance is smaller than the Ni-Ni interlayer distance, which indicates that Si atoms and underlying Ni atoms strongly interact.

  13. Fragmentation of neutron-hole strengths in 59Ni observed in the 60Ni(p, d) 59Ni reaction at 65 MeV

    Matoba, M.; Ohgaki, H.; Kugimiya, H.; Ijiri, H.; Maki, T.; Nakano, M.

    1995-01-01

    The 60 Ni(p, d) 59 Ni reaction has been studied with 65 MeV polarized protons. Angular distributions of the differential cross section and analyzing power have been measured for neutron hole states in 59 Ni up to the excitation energies of 7 MeV. The data analysis with a standard distorted-wave Born approximation theory provides transferred angular momenta l, j and spectroscopic factors for thirty-nine transitions. The nuclear damping mechanism of the single hole states is discussed. ((orig.))

  14. COSMO OIL is the series station of 700 store reduction; Kosumo, keiretsu kyuyujo 700 ten sakugen

    NONE

    1999-10-01

    Past petroleum each sale company accelerates the reduction of the franchise gas station. 700 stores in which COSMO OIL corresponds to whole 11% further than the end the preceding fiscal year including the transfer to other company by the 99 fiscal year end are reduced. In this other, Idemitsu Kosan also reduces 600 stores which correspond to whole 9%. As the profit deteriorates in prolonging sale competition, and as the unprofitability store can not be maintained, be. (translated by NEDO)

  15. Development of refrigerator insulation with reduced CFC-11. Reizokoyo flon sakugen uretan dannetsuzai no kaihatsu

    Kai, H.; Fukuda, K.; Yoshioka, M. (Sharp Corp., Osaka (Japan))

    1992-11-10

    Polyurethane thermal insulator in which the usage of CFC-11 is 50% reduced by increasing the percentage of water has been developed for the purpose of reducing polyurethane-foaming CFC-11 used as thermal insulator of refrigerators. In this new water-intensive feedstock system, the overall OH-value in polyol was lowered; the usage of aromatic amines was curtailed; and the amount of sorbits was increased so as to secure adhesiveness at the foaming jig temperature of 35[degree]C. As for the improvement of fluidity, a combination of four kinds of polyols offered viscosity in the same level as in the conventional ones. Thermal conductivity was worsened, but the rate of its drop could be controlled below 3% by some measures such as homogenization of stock materials, choice of a suface-active agent which makes foam bubbles minute, etc. Concerning curing property which has a large effect on productivity, a reaction type amine-based catalyst delaying thickening behaviour at the time of foaming was selected and a gelling promotive tertiary amine-based catalyst which can develop foam curing promptly was combinedly used to reduce curing property from five minutes in the past to four minutes. 2 refs., 6 figs., 14 tabs.

  16. Mössbauer emission study on 57Co doped carbon-supported Ni and Ni-Mo sulfide hydrotreating catalysts : the influence of phosphorus on the structure

    Crajé, M.W.J.; Beer, de V.H.J.; Kraan, van der A.M.

    1991-01-01

    In the present study it is demonstrated that Mössbauer emission spectroscopy (MES) can generate information on the various Ni phases present in sulfided Ni containing catalysts when a small amount of 57Co is used as a probe for Ni.Application of MES to 57Co:Ni(4.5)Mo(8.0)/C and 57Co:Ni(5.6)/C

  17. Characterization of Sputtered Nickel-Titanium (NiTi) Stress and Thermally Actuated Cantilever Bimorphs Based on NiTi Shape Memory Alloy (SMA)

    2015-11-01

    necessary anneal . Following this, a thin film of NiTi was blanket sputtered at 600 °C. This NiTi blanket layer was then wet -etch patterned using a...varying the sputter parameters during NiTi deposition, such as thickness, substrate temperature during deposition and anneal , and argon pressure during...6 Fig. 4 Surface texture comparison between NiTi sputtered at RT, then annealed at 600 °C, and NiTi

  18. Using DR52c/Ni2+ mimotope tetramers to detect Ni2+ reactive CD4+ T cells in patients with joint replacement failure.

    Zhang, Yan; Wang, Yang; Anderson, Kirsten; Novikov, Andrey; Liu, Zikou; Pacheco, Karin; Dai, Shaodong

    2017-09-15

    T cell mediated hypersensitivity to nickel (Ni 2+ ) is one of the most common causes of allergic contact dermatitis. Ni 2+ sensitization may also contribute to the failure of Ni 2+ containing joint implants, and revision to non-Ni 2+ containing hardware can be costly and debilitating. Previously, we identified Ni 2+ mimotope peptides, which are reactive to a CD4 + T cell clone, ANi2.3 (Vα1, Vβ17), isolated from a Ni 2+ hypersensitive patient with contact dermatitis. This T cell is restricted to the major histocompatibility complex class II (MHCII) molecule, Human Leukocyte Antigen (HLA)-DR52c (DRA, DRB3*0301). However, it is not known if Ni 2+ induced T cell responses in sensitized joint replacement failure patients are similar to subjects with Ni 2+ induced contact dermatitis. Here, we generated DR52c/Ni 2+ mimotope tetramers, and used them to test if the same Ni 2+ T cell activation mechanism could be generalized to Ni 2+ sensitized patients with associated joint implant failure. We confirmed the specificity of these tetramers by staining of ANi2.3T cell transfectomas. The DR52c/Ni 2+ mimotope tetramer detected Ni 2+ reactive CD4 + T cells in the peripheral blood mononuclear cells (PBMC) of patients identified as Ni 2+ sensitized by patch testing and a positive Ni 2+ LPT. When HLA-typed by a DR52 specific antibody, three out of four patients were DR52 positive. In one patient, Ni 2+ stimulation induced the expansion of Vβ17 positive CD4 + T cells from 0.8% to 13.3%. We found that the percentage of DR52 positivity and Vβ17 usage in Ni 2+ sensitized joint failure patients are similar to Ni sensitized skin allergy patients. Ni 2+ independent mimotope tetramers may be a useful tool to identify the Ni 2+ reactive CD4 + T cells. Copyright © 2017 Elsevier Inc. All rights reserved.

  19. Rapid synthesis of binary α-NiS–β-NiS by microwave autoclave for rechargeable lithium batteries

    Idris, Nurul Hayati; Rahman, Md Mokhlesur; Chou, Shu-Lei; Wang Jiazhao; Wexler, David; Liu, Hua-Kun

    2011-01-01

    Highlights: ► NiS has been synthesized by a rapid, one-pot, hydrothermal microwave autoclave method. ► The α-NiS–β-NiS sample synthesized at 160 °C yielded good electrochemical performance in terms of high reversible capacity (320 mAh g −1 at 0.1C up to 100 cycles). ► At high rates, the sample operated at a good fraction of its capacity. - Abstract: To reduce the reaction time, electrical energy consumption, and cost, binary α-NiS–β-NiS has been synthesized by a rapid, one-pot, hydrothermal autoclave microwave method within 15 min at temperatures of 160–180 °C. The microstructure and morphology of the α-NiS–β-NiS products were characterized by means of X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM). At 140 °C, pure hexagonal NiAs-type α-NiS phase was identified from the XRD patterns. With increasing reaction temperature (160–180 °C), the XRD evidence indicates that an increasing fraction of rhombohedral millerite-like β-NiS is formed as a secondary phase. The α-NiS–β-NiS sample synthesized at 160 °C yielded good electrochemical performance in term of high reversible capacity (320 mAh g −1 at 0.1C up to 100 cycles). Even at high rates, the sample operated at a good fraction of its capacity. The likely contributing factor to the superior electrochemical performance of the α-NiS–β-NiS sample could be related to the improved morphology. TEM imaging confirmed that needle-like protrusions connect the clusters of α-NiS particles, and the individual protrusions indicated a very high surface area including folded sheet morphology, which helps to dissipate the surface accumulation of Li + ions and facilitate rapid mobility. These factors help to enhance the amount of lithium intercalated within the material.

  20. Coarsening of Ni-Ge solid-solution precipitates in 'inverse' Ni{sub 3}Ge alloys

    Ardell, Alan J., E-mail: alan.ardell@gmail.com [National Science Foundation, 4201 Wilson Boulevard, Arlington, VA 22230 (United States); Ma Yong [Aquatic Sensor Network Technology LLC, Storrs, CT 06268 (United States)

    2012-07-30

    Highlights: Black-Right-Pointing-Pointer We report microstructural evolution of disordered Ni-Ge precipitates in Ni{sub 3}Ge alloys. Black-Right-Pointing-Pointer Coarsening kinetics and particle size distributions are presented. Black-Right-Pointing-Pointer Data are analyzed quantitatively using the MSLW theory, but agreement is only fair. Black-Right-Pointing-Pointer The shapes of large precipitates are unusual, with discus or boomerang cross-sections. Black-Right-Pointing-Pointer Results are compared with morphology, kinetics of Ni-Al in inverse Ni{sub 3}Al alloys. - Abstract: The morphological evolution and coarsening kinetics of Ni-Ge solid solution precipitates from supersaturated solutions of hypostoichiometric Ni{sub 3}Ge were investigated in alloys containing from 22.48 to 23.50 at.% Ge at 600, 650 and 700 Degree-Sign C. The particles evolve from spheres to cuboids, though the flat portions of the interfaces are small. At larger sizes the precipitates coalesce into discus shapes, and are sometimes boomerang-shaped in cross section after intersection. The rate constant for coarsening increases strongly with equilibrium volume fraction, much more so than predicted by current theories; this is very different from the coarsening behavior of Ni{sub 3}Ge precipitates in normal Ni-Ge alloys and of Ni-Al precipitates in inverse Ni{sub 3}Al alloys. The activation energy for coarsening, 275.86 {+-} 24.17 kJ/mol, is somewhat larger than the result from conventional diffusion experiments, though within the limits of experimental error. Quantitative agreement between theory and experiment, estimated using available data on tracer diffusion coefficients in Ni{sub 3}Ge, is fair, the calculated rate constants exceeding measured ones by a factor of about 15. The particle size distributions are not in very good agreement with the predictions of any theory. These results are discussed in the context of recent theories and observations.