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Sample records for saitekika ni tsuite

  1. Optimization of the ship type using waveform by means of Rankine source method; Rankine source ho ni yoru hakei wo mochiita funagata saitekika ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Hirayama, A; Eguchi, T [Mitsui Engineering and Shipbuilding Co. Ltd., Tokyo (Japan)

    1996-04-10

    Among the numerical calculation methods for steady-state wave-making problems, the panel shift Rankine source (PSRS) method has the advantages of rather precise determination of wave pattern of practical ship types, and short calculation period. The wave pattern around the hull was calculated by means of the PSRS method. The waveform analysis was carried out for the wave, to obtain an amplitude function of the original ship type. Based on the amplitude function, a ship type improvement method aiming at the optimization of ship type was provided using a conditional calculus of variation. A Series 60 (Cb=0.6) ship type was selected for the ship type improvement, to apply this technique. It was suggested that optimum design can be made for reducing the wave making resistance by means of this method. For the improvement of Series 60 ship type using this method, a great degree of reduction in the wave making resistance was recognized from the results of numerical waveform analysis. It was suggested that the ship type improvement aiming at the reduction of wave-making resistance can be made in shorter period and by smaller labor compared with the method using a waveform analysis of cistern tests. 5 refs., 9 figs.

  2. Optimization of dynamic source depth for seismic surveys. Part 7; Dynamite shingen no hasshin shindo no saitekika ni tsuite (hyoso kozo no suitei (kusssetsuho jishin tansa oyobi denki denjiho tansa)). 7

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, H; Murayama, R; Mitsuhata, Y; Ishikawa, H [Japan National Oil Corp., Tokyo (Japan). Technology Research Center

    1996-05-01

    For the improvement of quality of data collected by reflection aided seismic exploration using dynamite as the seismic source, information has to be collected about the surface layer structure before the charge depth is determined. For this purpose, refraction, electric, and electromagnetic exploration methods were tried. In the refraction method, an impactor was used as the seismic source. In the records, the surface wave prevails because vibration was generated on the surface. Analysis was made by the use of the initial travel time tomography. In the electric exploration, a double pole array was used to measure resistivity. The measured data was subjected to a fully automatic inversion for analysis. As the result, it was disclosed that it was useful to know the deep-level structure directly by use of tomographic methods in refraction seismic exploration so as to find the optimum charge level. Furthermore, about the electric and electromagnetic exploration techniques, it was found that these methods can be applied making use of resistivity to the evaluation of groundwater saturation. 7 refs., 5 figs., 3 tabs.

  3. Easy steel tower elevation. Development of a steel tower elevating aiding device; Tetto shoko wo rakuraku to. Tetto shoko hojo sochi no kaihatsu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Tobe, Y. [Kansai Electric Power Co. Inc., Osaka (Japan)

    1999-02-10

    Elevation of a transmission line steel tower is performed by an operator`s own force upon fixing a safety device to prevent a fall on a safety wire (SW) previously installed on a specified tower leg. It is a considerable burden for the operator to move the tower having a height of 80 to 100 m up and down several times a day. In order to reduce the fatigue, a portable, small and light-weight steel tower elevation aiding device was developed. The existing SW is used to fix the device, requiring no additional facility to be fixed on the tower. Safety assurance depends on the safety device on the SW as currently used. The device has pulling force of 50 kgf (the device operates in a range of 4 to 50 kgf to assure workability in elevation and stopping), and elevation speed of 15 to 20 m/minute (equivalent to the present work. The braking force can be adjusted in three steps at descent according to the ability of the operator). An Ni-hydrogen battery is used, capable of two returns on a tower per charge. Considering the device to be transported in mountainous area, the shape is such that a single unit can be put into a backpack. The device can also be used in general construction sites. (NEDO)

  4. Modified asphalt; Kairyo asphalt ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Takarabe, A. [Mitsubishi Oil Co. Ltd., Tokyo (Japan)

    1994-12-28

    Modified asphalt in the area of road pavement in the relation of measures against flow on a road surface was introduced. The condition of road damage includes the print of a wheel, crack, and wear and semi-blown asphalt whose deformation is difficult even if temperature is increased to approximately 60 {degree}C and asphalt with rubber and resin are used to prevent these. The semi-blown asphalt is obtained by adding cut-back material to the normal asphalt, heating it, blowing air into it, and then oxidizing and polymerizing it, is harder and is more elastic than the normal asphalt, and has smaller viscosity change due to temperature change. The viscosity at 60 {degree}C was determined to be 10000{plus_minus}2000 poise according to the relationship between viscosity and crack using a large-scale execution experiment. The asphalt with rubber and resin is formed by adding modified material of styrene - butadiene copolymer and by adding thermoplastic elastomer and the former is used for preventing slide and the latter is used for preventing flow and wear. 10 refs., 6 figs., 2 tabs.

  5. Asphalt emulsion; Asphalt nyuzai ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, T. [Toa Doro Kogyo Co. Ltd., Tokyo (Japan)

    1994-12-28

    The emulsification, manufacture, type, applications, etc. of asphalt emulsion were introduced. The emulsification of asphalt is obtained by mixing heated asphalt into an emulsification liquid where emulsifier is added to water and then agitating it. The emulsifier has both hydrophilic and lipophilic parts in the same molecule, prevents collision between asphalt particles after being arranged properly on the surface of asphalt particles, and prevent separation into water and asphalt. The emulsion is available for penetration and for mixing depending on applications and can be classified into cation emulsion, anion emulsion, and nonionic emulsion according to the property. The emulsion is mainly applied to road pavement, reaching approximately 90 % of the total manufactured emulsion. It is also used for other areas such as the filler of a slab race of each bullet train of Sanyo, Tohoku, and Jyoetsu and is also applied to the formation of a water-proof layer by spraying a high-concentration emulsion with rubber, agricultural water channels using asphalt emulsion and nonwoven cloth, etc. in civil engineering and agricultural fields. 2 refs., 13 figs., 8 tabs.

  6. Space photovoltaic power generation. Uchu taiyo hatsuden ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kudo, I [Electrotechnical Laboratory, Tsukuba (Japan)

    1993-07-20

    Introduction is made of space photovoltaic power generation which is the ultimate clean energy source. This is a system to obtain electric energy from the solar cells placed on a geostatic orbit and transmit the power onto the earth by microwave. The US formulates a plan of placing 60[times]5GW power generation satellites to obtain 300GW power on the earth in 2000. As for the scale of space structure, the array of solar cells is dimensionally 10km[times]5km and the power transmitting antenna is 1km in diameter. The electric energy is amplified to microwave and power-transmitted by wireless onto the earth. The ground rectenna which receives it is dimensionally 10km[times]13km. The biggest difficulty consists in transportation of construction materials onto the orbit. In Japan, activity comprises three matters, which are research committee organized three years ago by the Agency of Industrial Science and technology, 10MW class model conceptually designed by the Institute of Space and Astronautical Science, and experiment conducted by Kyoto University on the power transmission by wireless. Pertaining to the research on the space power generation, the following two points are judged still unclarified: Reason for which the electric power companies did not apply the power transmission by wireless regarded as high in transmission efficiency. Influence of the microwave on the ionosphere and biosystem. 7 refs., 4 figs.

  7. Mixed materials for concrete. Concrete yo konwazai ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kono, K [Tokushima Univ., Tokushima (Japan). Faculty of Engineering

    1994-07-05

    The materials except cement, water and aggregate added into the cement paste, mortar or concrete before the execution of smashing are called mixed materials. The mixed materials are indispensable to the concrete for improving the quality of the fresh concrete as well as the hardened concrete; providing the characteristics suitable for the operation; and increasing the economy. In this paper, the main mixed materials including fly ash, which is the by-product in coal thermoelectric power station; silica fume; micropowder of slag in blast furnace; expansive materials and so on are described summarily. Especially, silica fume is the by-product, which are the super micro-powders with the average size around 0.1 micrometer, collected by the dust-collector from the waste gas generated during the manufacture in the electric furnace of ferrosilicon, which is an alloy iron, or silicon metal used as the deacidificating and desulfurizing agents in the steel production. But the most part thereof is depended on the import since the domestic output is low. 38 refs., 19 figs., 6 tabs.

  8. New infiniti Q45. Shingata Infiniti Q45'' ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Oka, T; Ochiai, A; Kato, Y [Nissan Motor Co. Ltd., Tokyo (Japan)

    1989-12-25

    This report introduces the concept for development and the outline of the Infiniti Q45, a new luxury sedan Nissan has developed, and special activities Nissan makes to produce luxury cars. This sedan was developed with the concept of producing a large-sized luxury car of evidently Japanese make to earn the world appraisal; a touring saloon whose style is original and unique based on the sensitivity of Japanese and yet which has the performance of a sports car. Every part of the Infiniti Q45, from the V8 engine and the 4.5 L DOHC 32 valve engine to the hydraulic active suspension, the first to be loaded on a mass production car, features Nissan's innovative and leading-edge technology. Moreover, to provide maximum customer satisfaction in every scene from the purchase of a car to services, various constructive programs have been adopted with the key word, Total Ownership Experience. 8 figs., 2 tabs.

  9. Modified asphalt for pavements; Hosoyo kaishitsu asufuaruto ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Tsukagoshi, T. [Nippon Oil Co. Ltd., Yokohama (Japan)

    1997-10-01

    Modified asphalt has been used widely in such applications as countermeasure against rutting, countermeasure against wear caused by tire chains in snowy and cold areas, or bridge deck pavement. Features of various kinds of modified asphalt, standards, and standard properties are introduced. Modified asphalt containing natural asphalt is used for steel plate deck pavement. Semi-blown asphalt is used when emphasis must be given to the countermeasure for flowing resistance of asphalt pavement. Features and standards of asphalt containing rubber, thermoplastic elastomer, and thermoplastic resin are described. Asphalt containing heat-setting resin shows excellent characteristics, which other types of modified asphalt do not possess, in the laboratory resistance test for fatigue, flowing, and wear. Change in the history of modified asphalt in Japan from the initial stage to the present are explained and shown in a table together with time and phenomena, and the change in the production of modified asphalt is shown. 15 refs., 5 figs., 5 tabs.

  10. Reincarnation platn of globe. Chikyu saisei keikaku ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Matsuyama, T. (Agency of Natural Resources and Energy, Tokyo (Japan))

    1990-11-30

    The period of 200 years since the Industrial Revolution has taken for the occurence of global warming up problem, and it may require to face the problem comprehensively and for long period of 100 years unit to resolve it. This reincarnation plan of globe aims to reincarnate the changed global environment hereafter by using time of about 100 years, and proposes to make the comprehensive and long term actions to suppress and reduce exhaust gases resulting the greenhouse effect by the cooperation of all nations in the world. In the former 50 years, feasible countermeasures such as deepenung of scientific knowkedges, promotion of worldwide energy saving, introduction of clean energy, development of revolutional environmental technology, expansion of CO {sub 2} absorbing sources, and technological development of energy for the next generation will be executed continuously. In the latter 50 years, the gas exhausting amount resulting the green house effect will be reduced and suppressed from these results. Owing to these measures, the reduction of gas resulting the greenhouse effect which exceeds the expectation, can clean the globe after 100 years because the cleaning results will be incorporated into the natural circulation and the green globe will be reincarnated. 1 fig., 1 tab

  11. Gravitational observation in central Hokkaido; Hokkaido chuobu ni okeru juryoku sokutei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Murata, Y; Makino, M [Geological Survey of Japan, Tsukuba (Japan)

    1997-10-22

    To compile a base map of gravity in Hokkaido, gravity was measured in central Hokkaido where gravity data are absent. Gravity anomaly was made clear in this region. Survey area was 87 km in the east-west and 224 km in the north-south. A topographic map with a scale of 25,000:1 was initially used for determining location and altitude of gravity measuring points. Since the GPS survey was found to be very useful for gravitational observation in the region of Hyogo-ken Nanbu Earthquake in 1995, the GPS has been used in this survey from 1996. Based on new measurements at 2,148 points in addition to existing points, Bouguer anomaly map was made, and density distribution of surface layer of the crust was estimated. As a result, the gravity anomaly pattern in the north-south direction and gravity anomaly in basins and volcanoes were made clear. Quantitative analysis is to be conducted using these gravity data. Using these gravity data, the density distribution of surface layer of the crust was estimated. This distribution agreed well with the geological map in this region. 4 refs., 6 figs.

  12. Study on the time-domain electromagnetic responses; TDEM ho ni okeru denji oto ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Noguchi, K; Endo, M [Waseda University, Tokyo (Japan). School of Science and Engineering

    1997-05-27

    With an objective to perform three-dimensional analysis with high accuracy in using the electromagnetic exploration method, characteristics in electromagnetic response were analyzed, and conditions for acquiring necessary data were discussed. The discussion defined a parameter called `response anomaly` which uses response from media to standardize response only from substances with abnormal resistivity. The receivers were located uniformly on the same plane, and the response anomaly was derived from electromagnetic response from each of the three horizontal and vertical components at each receiving point, which was expressed as a contour map. The parameter for the abnormal body was consisted of location and resistivity contrast with media. Discussions using the contour map were given on the response when these factors for the parameter were varied. As a result, it was found that the response anomaly appears in the form that reflects the abnormal body, and the response anomaly of the horizontal component is superior in terms of being large. It was also referred that, as a requirement for the abnormal body which gives larger impact from the electromagnetic response, the abnormal body should have lower resistivity than that in the media, and resistivity contrast with the media should be greater. 2 refs., 7 figs., 1 tab.

  13. Global environmental problems in the electric industry. Denki jigyo ni okeru chikyu kankyo mondai ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Sugi, T [Tokyo Electric Power Co., Inc. (Japan)

    1992-09-30

    Since the electric industry has grappled with a prevention of the environmental pollution such as the air pollution and water contamination as a forerunner in case of construction and operation of the power facilities, and at the same time has conducted actively the environmental conservation countermeasures, it has consequently achieved the environmental conservation level as a top level in the world. On the other hand, as for the emission quantity of CO2 relating to the earth warming, the power field occupies about one fourth of total Japan. Therefore the electric industry should aim at the electric energy supply considering the influence on the environment, such as the power supply structure to restrain CO2 emission as less as possible, higher efficiency of equipments, higher efficiency of energy utilization by using the unused energy and so forth. In addition to it, the consumer side should aim at the social structure with a recycle type such as saving resources and saving energy, and aim at changeover of life style. It is hoped to conduct the overall measure including the items mentioned above. In this report, the recent trend of earth enviromental problems, grappling with the environmental problems as a forerunner such as the prevention measure of air pollution in the thermal power plant, etc., and the correspondence to the earth warming problems are outlined. 11 refs., 9 figs., 3 tabs.

  14. Adaptation of topology optimization on truck-structure; Kinshitsukaho ni yoru iso saitekika shuho no truck kozo eno tekiyo

    Energy Technology Data Exchange (ETDEWEB)

    Tachibana, H; Kojima, A; Chiba, S [Mitsubishi Motors Corp., Tokyo (Japan)

    1997-10-01

    An optimization using the homogenization method has been applied to a truck-structure on the concept design stage. A truck-structure is grouped into 3 classes (thin plate structure , thick plate structure and solid structure), then example, effectiveness and method for the application for the purpose of weight reduction , high rigidity and high eigen-frequency are introduced. 3 refs., 24 figs., 1 tab.

  15. Optimum differential terms for lateral motion control performance on the vehicle; Yokoundo seigyo seino ni oyobosu hisenkei bibunko no saitekika

    Energy Technology Data Exchange (ETDEWEB)

    Miyamori, A [Japan Consumer Information Center, Tokyo (Japan); Nakaya, H [Shibaura Institute of Technology, Tokyo (Japan)

    1997-10-01

    As general knowledge, the lateral control performance of vehicle improves as differential terms increases. But subjective rating has its limits of effect. The coefficient of differential terms and saturated steer angle velocity were set up using the experimental vehicle in several steps. Consequently, the optimum range, that subjective and objective rating were compatible, were made clear. 4 refs., 6 figs., 1 tab.

  16. Price negotiation on coal shipped in fiscal 1994. 1994 nendozumi no sekitan kakaku kosho ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Chimura, A. (The Institute of Energy Economics, Tokyo (Japan))

    1994-07-01

    Price negotiation on metallurgical coal imported by Japan in fiscal 1994, which started in December 1993, came to a conclusion at once over nearly all brands of both countries of Australia and Canada, taking a conclusion of three brands of Canada on 24th of January as a turning point. The width of reduction in price was 3.85$ (7.81%) at heavy caking coal, 3.50$ (8.00%) at semi-caking coal, and 3.30$ (8.30%) at combined non- and slight caking coal. Reduction in steel production in Japan and abundance in coal production in the world produced this result. The conclusions mentioned above were followed by conclusions in negotiation on metallurgical coal of South Africa and China. Concerning steam coal, negotiation on an export/import treaty between China and Japan was concluded on 29th of March as the head of a series of steam coal shipped in fiscal 1994. The quantity was increased by 800 kton than in fiscal 1993, the price was reduced by 3.30$ or 3.20$ (9.2% or 9.4%). Negotiations on steam coal of Australia, Indonesia, and the Western U.S. were concluded after hard negotiations, although negotiation is being continued for South Africa steam coal. 1 fig., 7 tabs.

  17. On Furuto-sui in Chikuho coal field. Chikuho tanden no furutosui ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Yamashita, Akio [Kyushu Univ., Faculty of Engineering, Fukuoka (Japan)

    1989-11-30

    This paper described the Furuto-sui(goaf water) in Chikuho Coal Field where coal mining was made for 100 years, remaining mined traces in wide range. This is called Furuto and water collected in or passed through Furuto is called Furuto-sui. The Furuto was made by coal layer mining and the distribution is coincident to the geological structure of coal layer. This Furuto structure is shallower to westward direction, deeper to eastward direction and identical to the north-southward direction. The Furuto can be said as the artificially built reservior for ground water. The coal mining was perfectly stopped in 1976 and the Furuto-sui filled in mined cavities. At low ground area, springs or humid areas appeared. Water quality is diverse but the typical ones are the type of Ca-SO{sub 4} of 3-5 pH, type of Na-HCO{sub 3}*SO{sub 4} of 8-9pH, and type of Na-SO{sub 4} of 7 pH. A part of Furuto-sui is utilized as the water for home use but must be utilized much more as water reservior. 12 refs., 9 figs.

  18. Satellite communication transponders and their reliability; Eisei tosai tsushin kiki oyobi shinraisei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Ogawa, H [NTT Wireless System Laboratories, Kanagawa (Japan)

    1994-11-01

    The Engineering Test Satellite-VI is a large composite test satellite weighing two tons to perform different communication experiments. Adoption of the multi-beam satellite communication system has made possible to increase the transmission capacity, reduce the sizes of earth stations, and utilize frequencies more effectively. This paper describes the configuration of the relaying devices mounted thereon, the newly developed circuit technologies, and their reliability. The multi-beam satellite communication system mounts a number of transponders, with the frequency bands used divided into the 2.6/2.5 GHz band between the moving body and the satellite, the 6/4 GHz band for the channels between the earth stations and the satellite, and the 30/20 GHz band for the fixed communications. These arrangements were intended to achieve large size reduction as a result of applying the integrated circuit technology. The transmitters and the receivers corresponding to each beam are connected by using the satellite switches (16 inputs {times} 12 outputs). The parts used were general purpose ones rather than those specified in the MIL standards because of their number having reached so huge. Their reliability was ensured by long-term burn-in operations. 5 refs., 6 figs., 1 tab.

  19. Mathematical structure of ocean container transport systems; Kaiyo container yuso system no suriteki kozo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Shinkai, A [Kyushu University, Fukuoka (Japan). Faculty of Engineering; Chikushi, Y [Nippon Telegraph and Telephone Corp., Tokyo (Japan)

    1997-10-01

    Mathematical structure of a vessel arrangement program was discussed in order to learn roles of container ships in ocean transport systems among China, NIES/ASEAN countries and Japan. Formulation is possible on a mathematical handling method for sailing route connection diagrams between ports, a transport network to indicate container movements, a service network to indicate sailing routes, and a network generalizing them. This paper describes an analysis made on the container transport system between Japan and China, taken as an example. Four ports were selected each from Japan and China, and the statistical database for fiscals 1996 and 1994 was utilized to set models for: (a) the liner network system with transshipment at the port of Shanghai and (b) the cruising route system going through the ports of Yokohama, Nagoya and Kobe. A hypothesis was set that a consortium (coordinated ship allocation) can be implemented ideally and completely. The transport network (a) is lower by 10% in total cost than the transport network (b), resulting in 1.6 times greater productivity. Actual service network is closer to the network (b), but the system can be utilized for discussing guidelines on vessel arrangement programs with which shipping companies pursue better management efficiency under a condition that the consortium can be formed. 10 refs., 6 figs., 2 tabs.

  20. Technologies for high performance and energy saving in room air conditioners. Shoenegata kokoritsu eakon ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kawai, N. (Toshiba Corp., Tokyo (Japan))

    1994-05-31

    An energy saving inverter type air-conditioner was introduced. It is important to increase the efficiency in the low capacity zone below the rated capacity to realize the energy saving. For the reduction of peak, improving the efficiency in the high capacity operation is also necessary. The power consumption in compressor and in inverter is about 90 % of the total power consumption in air-conditioner. The other 10 % are distributed to the fan motor and the control unit. For achieving the energy saving, the reduction of this 10 % part is also necessary because this 10 % part is constant regardless of the capacity of air-conditioner. The compressor motor was modified to the brushless DC motor with rotor position detecting device to improve the rotor structure and the position detection system. The heat exchanger was changed to a room heat exchanger with slit pattern. For the outdoor heat exchanger, the complex curvature blade fan was adopted. The control system of air-conditioner was changed. The PMV was previously learned and input in the microcomputer to calculate the data. Resultantly, the power consumption was reduced by about 20 % as compared with the conventional air-conditioner. 10 figs., 1 tab.

  1. New infiniti Q45. Shingata Infiniti Q45'' ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Oka, T.; Ochiai, A.; Kato, Y. (Nissan Motor Co. Ltd., Tokyo (Japan))

    1989-12-25

    This report introduces the concept for development and the outline of the Infiniti Q45, a new luxury sedan Nissan has developed, and special activities Nissan makes to produce luxury cars. This sedan was developed with the concept of producing a large-sized luxury car of evidently Japanese make to earn the world appraisal; a touring saloon whose style is original and unique based on the sensitivity of Japanese and yet which has the performance of a sports car. Every part of the Infiniti Q45, from the V8 engine and the 4.5 L DOHC 32 valve engine to the hydraulic active suspension, the first to be loaded on a mass production car, features Nissan's innovative and leading-edge technology. Moreover, to provide maximum customer satisfaction in every scene from the purchase of a car to services, various constructive programs have been adopted with the key word, Total Ownership Experience. 8 figs., 2 tabs.

  2. Fluid dynamic interface between hull and hydrofoil; Sentai to suichuyoku no ryutai rikigakuteki kansho ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kataoka, K; Ando, J; Nakatake, K [Kyushu University, Fukuoka (Japan). Faculty of Engineering

    1996-04-10

    For the high-speed ship with hydrofoil, it is important to grasp the mutual interference between its hydrofoil and hull. In this study, effects of the state of hydrofoils and velocity on the hull were fluid-dynamically investigated through the numerical calculation by means of Rankine source method using a Wigley model with two hydrofoils. Before considering the model with hydrofoils, the attitude change of a hull without hydrofoils during traveling in high-speed was examined. For the high-speed ship, various measuring systems have been conceived due to the large change in its attitude. The Wigley model has been used for the numerical calculation when considering the attitude change in the medium- and low-speed regions. In this study, resistance tests without constraining the sinkage and trim were conducted using a Wigley model in the high-speed region around Fn=1.0, which have not been usually conducted. The attitude changes were compared with the numerical calculation results by the Rankine source method. The wave making resistance and attitude change of the Wigley model with hydrofoils were also calculated. 12 refs., 10 figs.

  3. New stage of clean coal technology in Japan; Clean coal technology no aratana tenkai ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kawaguchi, Y [Agency of Natural Resources and Energy, Tokyo (Japan)

    1996-09-01

    The paper described the positioning and new development of clean coal technology. Coal is an important resource which supplies approximately 30% of the energy consumed in all the world. In the Asian/Pacific region, especially, a share of coal in energy is high, around 60% of the world, and it is indispensable to continue using coal which is abundantly reserved. Japan continues using coal as an important energy among petroleum substituting energies taking consideration of the global environment, and is making efforts for development and promotion of clean coal technology aiming at further reduction of environmental loads. Moreover, in the Asian region where petroleum depends greatly upon outside the region, it is extremely important for stabilization of Japan`s energy supply that coal producing countries in the region promote development/utilization of their coal resources. For this, it is a requirement for Japan to further a coal policy having an outlook of securing stable coal supply/demand in the Asian region. 6 figs., 2 tabs.

  4. Properties of soap prepared from waste edible oil. Haishokuyu kara sakuseishita sekken no seijo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kajinoto, G.; Yamaguchi, H. (Kobe Gakuin University, Kobe (Japan). Faculty of Nutrition)

    1992-08-30

    Discussions were given on properties of soap prepared from waste edible oil. A fresh oil, and soybean and rapeseed oils with different thermal oxidation degrees were used to prepare soap. On the other hand soap was made using wast edible oil after used at home. Soap made from fresh oil and thermally oxidized oil under a 3-hour heating at 90[degree]C has less non-saponified fat. Soap made from a large amount of waste edible oil. taking 34 days had much residual fat, proving these were insufficiently saponified. Slightly higher values were recognized in the soap from fresh oil for anisidine value (An.V), carbonyl value (CV), peroxide value (POV) and the content of oxidized fatty acids than in fresh oil itself. On the other hand, the An.V and CV in the soap made from thermally oxidized oil were lower than those for thermally oxidized oil itself. The An. V and CV in the soap made from waste edible oil were higher than those in waste edible oil itself. As the soap has been stored, all of the soap showed increase in the An.V, the CV, the POV and the oxidized fatty acid amount, but the fatty acid composition showed no change. 9 refs., 4 figs., 4 tabs.

  5. High-rate oil removing scouring agent. Koyubun jokyoyo seirenzai ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Ishihara, K.; Sato, Y. (Dai-Ichi Kogyo Seiyaku Co. Ltd., Kyoto (Japan))

    1991-11-01

    Fiber forming, scutching and knitting processes in recent years are performed three to five times faster than in the conventional processes. Associated therewith, oil solutions are taken importantly for their stability and workability, such as smoothing properties, heat resistance and abrasion resistance. On the other hand, difficulty is increasing in removing the oils after scutching and knitting. This paper explains basic rinsing activities required in oil removal, and describes various test characteristics and compatibility of various high-rate oil removing scouring agents. An oil-in-water rinsing mechanism relies upon comprehensive actions of a surfactant in wetting, permeation, emulsified dispersion and solubilization. The most importantly taken among them is the emulsifying action, which largely depends upon its chemical structure. Therefore, for a high-rate oil removing scouring agent, creation of activators is required that make the above basic characteristics and activities compatible for various applications. For example, the above product covers a great variety of kinds for diverse applications, based on non-ionic and anion-based activators. 6 figs., 20 tabs.

  6. Geothermal gradients map of Hokkaido; Hokkaido no chion kobaizu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Akita, F.; Matsunami, T.; Wakahama, H. [Hokkaido Geological Survey, Sapporo (Japan)

    1997-06-15

    This paper outlines the newly prepared geothermal gradient map (GGM) of Hokkaido which is important for survey on geothermal and hot spring resources. The temperature data of 687 wells were compiled by data collection and field survey. The geothermal gradient was calculated from the ratio of the temperature difference between the bottom (deepest well log) and the ground surface (10degC) to a bottom depth. GGM was prepared using data of 85 wells which show real geothermal temperatures through conductive temperature profiles, or SBHT (static bottom hole temperature) calculation is possible. Geological profiles were classified into three types based on base rocks. The thermal structure of GGM was clearly divided into a high geothermal gradient over 10degC/100m, and a low one within 3degC/100m. The former showed active volcano and high geothermal areas, while the latter showed a volcanic front arc area. This underground temperature structure relates to the formation process of volcanos and the origin of magma, and is also similar to the trend of a crust thermal flow rate. The geothermal gradient increases with a decrease in Curie point depth. 26 refs., 10 figs., 2 tabs.

  7. Design of Usui bridge (PC cable stayed bridge). Usuihashi (PC shachokyo) no sekkei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kido, M.; Iizuka, Y. (Japan Highway Public Corp., Tokyo (Japan)); Tanaka, S.; Otsuka, K. (P.S. Concrete Co. Ltd. Kajima Corp. Joint Venture, Tokyo (Japan)); Kitakuni, S. (Kajima Corp., Tokyo (Japan))

    1991-11-30

    Structure and design of single suspension PC cable bridge, which is first kind of high way bridge in Japan and aiming to start for general use by March, 1993, are reported. As a construction outline, main construction quantity and general layout of the whole bridge together with the selective detail and characteristics of the diagonal member, tower, main girder and tower support member, are cited. Design conditions( load, materials, allowable stress and others ), basic plan of the design, and structure analysis( surface stress framed structure analysis, stereoscopic framework analysis and FEM analysis of local stress ) are explained. Design of structure member like main girder is based on diagonal member tension, wave shearing force, level of diagonal strain stress, bending stress when diagonal member anchors the deformed main tower caused by living load during earth quake, principal stress of main tower junction and local stress etc. Main tower support member design is based on the results of corbel shearing force at varied cross section and main stress, and diagonal member design is decided by allowable stress. Diagonal member anchorage traverse beam design depends on bending moment of traverse beam and shearing force. 3 refs., 15 figs., 1 tab.

  8. On noise, traffic and factory vibrations in Akita city; Akitashi ni okeru soon oyobi kotsu kojo shindo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Nogoshi, M; Kikuchi, T; Morino, T; Sannohe, M [Akita University, Akita (Japan). College of Education

    1996-05-01

    Noise and vibration were measured in Akita City. In 1994, noise and traffic-caused vibration were measured along the trunk lines and other roads across the entire Akita City area. In 1995, the effort centered on the Ibarashima manufacturing quarters, the important source of noise and vibration in Akita city. The general-purpose noise meter LA-220S was used to measure noise and the vibration level meter VR-5100 was used to measure vibration. The results of noise measurement carried out at 122 points in Akita City indicated that the noise level was high along Route 7, Route 13, and the southern line belonging to the newly built national highway, marking the highest of approximately 74dB. As compared with the measurement made in 1968, the value was higher by 3-13dB. A roughly similar trend was seen in vibration. The noise level measurement of 1995 accomplished at 100 points in the vicinity of Ibarashima district indicated that the factories were responsible for high levels of noise and vibration. It was found that the levels lowered in proportion to the increase in the distance from the factories. 11 figs., 1 tab.

  9. Elevator group control during morning rush-hours; Erebeta gun kanri ni okeru shukkinji unten ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Hikita, S. [Mitsubishi Electric Corp., Tokyo (Japan); Komaya, K. [Mitsubishi Electric Corp., Tokyo (Japan). Industrial Electronics and Systems Lab.

    1995-11-30

    In a high-rising building, a group control system is indispensable which controls elevators systematically in order to improve efficiency of transportation. The group control and supervision are divided into two kinds namely the allocated control and the operation control. The former is the control to determine the optimal elevator which is to respond to a call of an individual passenger and the latter is the control to determine the operational practice as an elevator group in response to changes of the macroscopic traffic flows which are repeated periodically like morning rush hours or a lunch time. In this article, the meaning of the operation during morning rush hours has been discussed, the effect of the operation during the rush hours has been verified through simulation, and as a result, it has been verified that the determination of number of elevator cages to be arranged by the number of passengers (in particular the number of passengers from the main floor) is not necessarily related to improvement of total transportation efficiency. Besides, after analyzing the behavior of the group of elevators under the morning rush hour operation, the new index for determination of the optimal number of elevator cages at the main floor has been established, a new practice for determining the number of cages to be arranged based on the above has been proposed, and its effect has been verified. 7 refs., 10 figs.

  10. Chlorofluorocarbons (CFCs) destruction technology by induction coupled plasma; Koshuha purazuma ni yoru tokutei furon hakai gijutsu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, A. [Nippon Steel Corp., Tokyo (Japan)

    1999-09-05

    Abolishing flon in which the reuse by pollution and degradation is difficult by recovery flon and recovery and recycling process which do not rotate for the middle reuse that the recovery system is constructed is arising. And, the specific flon recovery quantity increases with the progress of development of the recent CFC substitute and renewal to the CFC substitute correspondence machine. Specific flon collapse technique using rf plasma introduced in this paper cultivated the basic technology in Agency of Industrial Science and Technology, resources environment integrated research place. The demonstrated operation research was carried out under Ministry of International Trade and Industry, New Energy and Industrial Technology Development Organization since December 1994. (NEDO)

  11. Research on brake noise. Concerning LT drum brake; Brake noise ni kansuru kenkyu. LT Drum brake ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Chikamori, S; Shimizu, Y [Seikei University, Tokyo (Japan); Yano, M [Mitsubishi Motor Corp., Tokyo (Japan)

    1997-10-01

    The four degrees of freedom of shoe motion were adopted by considering the bending for the shoe vibration, and the simulation model was derived. Using this model, the mechanism by which the squeal is generated was reviewed. And conditions for the occurrence of squeal vibration were determined by a series of simulations. Then father analysis was conducted on the influences of various parameters upon the occurrence of squeal vibration. 2 refs., 10 figs.

  12. High-accuracy measurement of ship velocities by DGPS; DGPS ni yoru sensoku keisoku no koseidoka ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Yamaguchi, S; Koterayama, W [Kyushu Univ., Fukuoka (Japan). Research Inst. for Applied Mechanics

    1996-04-10

    The differential global positioning system (DGPS) can eliminate most of errors in ship velocity measurement by GPS positioning alone. Through two rounds of marine observations by towing an observation robot in summer 1995, the authors attempted high-accuracy measurement of ship velocities by DGPS, and also carried out both positioning by GPS alone and measurement using the bottom track of ADCP (acoustic Doppler current profiler). In this paper, the results obtained by these measurement methods were examined through comparison among them, and the accuracy of the measured ship velocities was considered. In DGPS measurement, both translocation method and interference positioning method were used. ADCP mounted on the observation robot allowed measurement of the velocity of current meter itself by its bottom track in shallow sea areas less than 350m. As the result of these marine observations, it was confirmed that the accuracy equivalent to that of direct measurement by bottom track is possible to be obtained by DGPS. 3 refs., 5 figs., 1 tab.

  13. Test results of cultivation of vegetables with fish breeding water; Yogyosui riyo ni yoru yasai saibai shiken kekka ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Nishida, S. [Hokuriku Electric Power Co. Inc., Toyama (Japan)

    1997-10-28

    Entrails of fish, fowls and domestic animals are mostly incinerated at large expenses, although partly used as foods. This study is to test `possibility of vegetable cultivation with fish breeding water,` where the entrail wastes are used as baits for fish breeding, and fish excretions are used as the fertilizer for vegetable cultivation to purify water for fish breeding. The cultivation bed consists of two sections, one for fish breeding/vegetable cultivation and the other for vegetable cultivation by the normal method. Vegetable grow notably less in the former than in the latter, 54.6 to 79.5 versus 100. Spinach contains slightly higher contents of vitamins A and C by 6 and 13%, when cultivated in the former than in the latter. Quantities of total nitrogen, phosphorus and potassium as the fertilizer components in the former are 49, 49 and 1.7% of those in the latter. It is predicted, judging from growth of the vegetables, that the former gives a harvest comparable with that by the latter, when given a 6 to 13 days longer cultivation period. 3 figs., 2 tabs.

  14. Test results on vegetable cultivation using fish breeding water; Yogyosui riyo ni yoru yasai saibai shikenkekka ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Nishida, S. [Hokuriku Electric Power Co. Inc., Toyama (Japan)

    1997-10-30

    Although a part of the entrails of fishes, birds and livestock is used for food, most of them are treated by costly combustion because of their bad odor and looking, and International Environment and Welfare Laboratory, Toyama prefecture in Japan is studying their profitable treatment. As a part of such study, possibility of hydroponic cultivation of vegetable was tested using fish breeding water including excretions of fishes and residual feeds after use of waste as feed, and the growth condition, safety and effectiveness of cultured vegetable were verified. Three-hundred and fifty viviparous Oryzias were released into a breeding water area with no controlled pH and EC (electric conductivity). For comparison a culture solution area of 6.0 in pH and 1.2ms/cm in EC was prepared. The result on cultivation of 6 kinds of vegetable in culture beds supported by circulation of these water showed that hydroponic cultivation of vegetable using fish breeding water is possible, and average growth of 68% is obtained although difference in growth for every vegetable is found. 8 figs., 5 tabs.

  15. Flat plate approximation in the three-dimensional slamming; Heiban kinji ni yoru sanjigen suimen shogeki keisanho ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Toyama, Y. [Mitsui Engineering and Shipbuilding Co. Ltd., Tokyo (Japan)

    1996-12-31

    A slamming load generated by interactive motions between a ship body and water face is an important load in ensuring safety of the ship. A flat plate approximation developed by Wagner is used as a two-dimensional slamming theory, but it has a drawback in handling edges of a flat plate. Therefore, an attempt was made to expand the two-dimensional Wagner`s theory to three dimensions. This paper first shows a method to calculate water face slamming of an arbitrary axisymmetric body by using circular plate approximation. The paper then proposes a method to calculate slamming pressure distribution and slamming force for the case when shape of the water contacting surface may be approximated by an elliptic shape. Expansion to the three dimensions made clear to some extent the characteristics of the three-dimensional slamming. In the case of two dimensions or a circular column for example, the water contacting area increases rapidly in the initial stage generating large slamming force. However, in the case of three dimensions, since the water contacting area expands longitudinally and laterally, the slamming force tends to increase gradually. Maximum slamming pressure was found proportional to square of moving velocity in a water contacting boundary in the case of three dimensions, and similar to stagnation pressure on a gliding plate. 12 refs., 17 figs., 1 tab.

  16. Measurement of organic carbon quantity at chemoautorophic bacterium; Kagaku dokuritsu eiyo saikin ni okeru yuki tansoryo no sokutei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Tsuda, I; Kato, K; Nozaki, K [Electrotechnical Laboratory, Tsukuba (Japan); Kurokawa, K [Tokyo University of Agriculture and Technology, Tokyo (Japan)

    1996-10-27

    Described herein is the method for analyzing quantity of organic carbon synthesized by chemoautotrophic bacterium. It is based on the combustion-infrared spectroscopy, which is normally adopted for quantitative analysis of organic carbon. The problems involved in the measurement of organic compounds synthesized by iron-oxidizing bacteria are noise by culture medium components, aging of gas analyzer and contamination with organic compounds from a silicon plug. The measures taken in this study against these problems include comparison of the results with a medium containing iron-oxidizing bacteria with those with a medium free of these bacteria, calibration with the standard solution for each measurement, and replacement of a silicone plug by a silicon cap. Organic carbon is measured by a TOC-5000 analyzer equipped with an automatic sample feeder ASI-5000. Biomass density is determined by the MPN method. It is confirmed that organic carbon quantity is almost in proportion to biomass density, a phenomenon which can be used to determine organic carbon quantity. 7 refs., 6 figs., 1 tab.

  17. Flat plate approximation in the three-dimensional slamming; Heiban kinji ni yoru sanjigen suimen shogeki keisanho ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Toyama, Y [Mitsui Engineering and Shipbuilding Co. Ltd., Tokyo (Japan)

    1997-12-31

    A slamming load generated by interactive motions between a ship body and water face is an important load in ensuring safety of the ship. A flat plate approximation developed by Wagner is used as a two-dimensional slamming theory, but it has a drawback in handling edges of a flat plate. Therefore, an attempt was made to expand the two-dimensional Wagner`s theory to three dimensions. This paper first shows a method to calculate water face slamming of an arbitrary axisymmetric body by using circular plate approximation. The paper then proposes a method to calculate slamming pressure distribution and slamming force for the case when shape of the water contacting surface may be approximated by an elliptic shape. Expansion to the three dimensions made clear to some extent the characteristics of the three-dimensional slamming. In the case of two dimensions or a circular column for example, the water contacting area increases rapidly in the initial stage generating large slamming force. However, in the case of three dimensions, since the water contacting area expands longitudinally and laterally, the slamming force tends to increase gradually. Maximum slamming pressure was found proportional to square of moving velocity in a water contacting boundary in the case of three dimensions, and similar to stagnation pressure on a gliding plate. 12 refs., 17 figs., 1 tab.

  18. Optimum stamping die structure based on analytical method of die deformation during draw process; Seikei katei no kanagata henkei kaiseki ni motozuku, press kanagata kozo no saitekika

    Energy Technology Data Exchange (ETDEWEB)

    Nakahara, T; Tamai, H [Mazda Motor Corp., Hiroshima (Japan)

    1997-10-01

    We measured an actual deformation and pressure distribution in draw process of bending cam, and analyzed deformation process of die structure, in order to eliminate adjusting work considering die deformation by stamping force. We studied die structure improvement with simulation based on analytical method. This report describes a sample of die structure improvement based on a simulation and actual measurement. 1 ref., 11 figs., 1 tab.

  19. New computational and experimental stress analysis method for the design decision on optimum piston configuration. Piston oryoku no computer simulation to shinshikenho ni yoru keijo saitekika

    Energy Technology Data Exchange (ETDEWEB)

    Anno, N; Sugita, J [Honda R and D, Co. Ltd., Saitama (Japan)

    1993-03-01

    Piston troubles are mostly caused by cracks generating in each part of a piston. The finite element method (FEM) has been used for stress analysis of the piston, but has not been applied enough to design optimum configurations due to too much time for making models. In this study, stress analysis was carried out by the boundary element method (BEM), with which it is easy to make models and to change configurations, with various improvements. In addition, methods to execute a thermal load fatigue test and an actual running test to confirm analytical results were also improved. BEASY was used as basic software for analysis by BEM, and some improvements such as reduction of CPU time and optimization of memory using methods were carried out. It was easy to change configurations of the models by BEM, and the effect of the change in the piston boss configuration upon the stress agreed well with the actual test result. Design and evaluation of the optimum configuration has become easier by feedback of the results of the newly developed thermal load fatigue test to the analysis by BEM. 5 refs., 12 figs., 2 tabs.

  20. Solution of combinatorial optimization problems by an accelerated hopfield neural network. Kobai kasokugata poppu firudo nyuraru netto ni yoru kumiawase saitekika mondai no kaiho

    Energy Technology Data Exchange (ETDEWEB)

    Ohori, T.; Yamamoto, H.; Setsu, Nenso; Watanabe, K. (Hokkaido Inst. of Technology, Hokkaido (Japan))

    1994-04-20

    The accelerated approximate solution of combinatorial optimization problems by symmetry integrating hopfield neural network (NN) has been applied to many combinatorial problems such as the traveling salesman problem, the network planning problem, etc. However, the hopfield NN converges to local minimum solutions very slowly. In this paper, a general inclination model composed by introducing an accelerated parameter to the hopfield model is proposed, and it has been shown that the acceleration parameter can make the model converge to the local minima more quickly. Moreover, simulation experiments for random quadratic combinatorial problems with two and twenty-five variables were carried out. The results show that the acceleration of convergence makes the attraction region of the local minimum change and the accuracy of solution worse. If an initial point is selected around the center of unit hyper cube, solutions with high accuracy not affected by the acceleration parameter can be obtained. 9 refs., 8 figs., 3 tabs.

  1. Optimization of the catalytic converter internal flow by using 3D-CFD; Sanjigen nagare kaiseki ni yoru shokubai converter nai nagare no saitekika

    Energy Technology Data Exchange (ETDEWEB)

    Toi, M; Sugiura, S [Toyota Motor Corp., Tokyo (Japan)

    1997-10-01

    By using computational fluid dynamics and statistical quality control method, we investigated the contribution of front and rear catalytic converter cone shape for the pressure loss and the partial flow, also led the optimal terms and the predictional formulations efficiently. According to this, we can investigate the optimal position of the catalytic converter from the planning. 8 figs., 6 tabs.

  2. Detection of vehicle crossing path at intersection; Mitoshi no yoi kosaten ni okeru deaigashira jiko ni tsuite (Ibarakiken ni okeru jiko tahatsu zone no tokucho)

    Energy Technology Data Exchange (ETDEWEB)

    Fujita, K; Uchida, N; Katayama, T [Japan Automobile Research Institute Inc., Tsukuba (Japan)

    1997-10-01

    An investigation was excuted to understand the actual state of accidents happened at intersections where there were no constructive obstacles in field of view. First, the aspects of fatal accidents are described under the basis of the data published by the police of Ibaraki prefecture. Then it is shown that there are at least 336 intersections where the accidents happened in the last two years. It is also clarified that many dangerous zones were located in line along rivers. The authors stress that it is urgent to inform the existence of dangerous zones to prevent the accidents. 2 refs., 5 figs.

  3. On the relationship between the irregular reflector and the data processing by stacking; Hanshamen keijo to jugo shori ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Matsushima, J; Yokota, T; Miyazaki, T [Geological Survey of Japan, Tsukuba (Japan); Rokukawa, S [The University of Tokyo, Tokyo (Japan). Faculty of Engineering

    1996-05-01

    An examination was made on the possibility of data processing by stacking with scattered waves assumed in a seismic exploration analysis (diffraction stacking method). In the examination, a CDP stacking method and the diffraction stacking method were compared through numerical experiments in the case of imaging a flat reflection surface and an irregular reflection surface. As a result, it was revealed that the CDP stacking method for stacking mirror reflection waves was merely a processing to raise S/N ratio while the diffraction stacking method for stacking with scattered waves assumed contained a migrational aspect as well as an aspect to raise S/N ratio. Consequently, it was shown that, if an oscillator was properly arranged, a structural imaging was possible not by the shape of a reflection surface but by the diffraction stacking method. Additionally, the diffraction stacking method revealed that the imaging effect varied by frequency with the stacking effect decreased at high frequencies, and that no stacking effect decreased at low frequencies but resolution lowered in horizontal direction. 4 refs., 8 figs.

  4. Development of offroad unmanned dump truck navigation system. Dump truck mujin soko system no kaihatsu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Horii, Z [Nittetsu Mining Co. Ltd., Tokyo (Japan)

    1992-08-25

    A large offroad unmanned dump truck navigation system has been developed, and is in practical operation mounted on dump trucks at Torigatayama Limestone Quarry of Nittetsu Mining Company. The system functions in a manual dump truck navigation mode, wireless navigation mode, and unmanned control mode. The unmanned control mode further includes a mode to navigate the truck on a predetermined course with its data having been input in a computer and a mode that when the truck was moved on a course under a wireless control, the computer learns the course and drives the truck autonomously thereafter. The safety measures are divided into the hardware safety function to detect abnormalities in brakes and other vehicle parts, and the software safety functions of data communications, sensor action check, and prevention of collision of trucks with each other. The system has resulted in a productivity of average one-way travel distance of 345 m, and average unmanned navigation cycle time of 9 minutes and 26 seconds for a transportation efficiency of 541 t/hour/truck, having reached at least the manned operation level. 4 figs., 1 tab.

  5. Wave-free floating body forms for a shallow sea area; Senkaiiki no naminashi futai keijo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kyozuka, Y; Nariai, Y [Kyushu University, Fukuoka (Japan)

    1997-10-01

    In column footing or semi-submergible type marine structures, a vertical wave force vanishes at a specific period of waves. This phenomenon is called wave-free characteristics. This wave-free characteristics make it possible to design marine structures superior in oscillation performance in waves. Since Bessho`s wave-free theory is useful only for an infinite water depth, this paper studied the wave-free theory for a shallow sea area. On a wave-free singularity and required floating body form, 2-D and 3-D axisymmetric floating body forms were determined, and vertical wave force characteristics of the obtained body forms were calculated and verified experimentally. Since the source term of the wave-free singularity was weaker in a shallow sea area than an infinite deep water area, resulting in the narrow width of the obtained wave-free body forms in a shallow sea area. The wave-free theory for a shallow sea area was verified by both numerical calculation based on a singularity distribution method and model experiment for these floating body forms. 3 refs., 10 figs.

  6. Electrical properties (dielectric constant and conductivity) of igneous rock specimens; Kaseigan shiryo no hiyudenritsu, dodenritsu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Toida, M; Miyajima, Y; Inaba, T [Kajima Corp., Tokyo (Japan)

    1997-10-22

    Dielectric constants and conductivity of several volcanic and plutonic rock specimens are measured and their dielectric characteristics and water contents are examined for the purpose of achieving a high-accuracy evaluation of the result of electromagnetic wave tomography conducted in situ. A total of 13 kinds of igneous rocks are examined, the volcanic rocks including andesite, basalt, and rhyolite and the plutonic rocks including granite and granodiorite. The specimens are caused to get wet and to be dried up, their resistance and static capacity are measured, and their dielectric constants and conductivity are determined. It is found that the dielectric constant increases upon addition of water and the rate of increase is greatly influenced by porosity, that conductivity increases upon addition of water and the rate of increase is much higher than that of the dielectric constant, and that the impact of added water on the electromagnetic wave propagation velocity and damping coefficient as calculated from actually measured dielectric constant and conductivity is greater on the damping coefficient than on the electromagnetic wave propagation velocity. 6 refs., 10 figs., 1 tab.

  7. Recent technologies for reduction of aircraft propulsion noise. Kokuki engine soon teigenka no saikin no gijutsu shinpo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, H [National Aerospace Lab., Chofu, Tokyo (Japan)

    1994-03-10

    Inside the jet engine, the propulsion engine for an aircraft, a high speed air current is flowing, and the rotors such as the fan, compress or, turbine and so forth are rotating with a high speed in its flowing current. The flow itself in which a high speed exhaust jet is discharged in the air from engine exhaust port, and the aerodynamic noise generated by an interaction of the flow with the material bodies are the main noise sources of the aircraft engine. Because the supersonic planes are necessary to fly with mach number 2 - 3 during cruising, the turbojet engine with a large jet exhaust speed or the low bypass ratio turbofan engine is selected. Since a noise reduction by reducing the jet exhaust speed, which was an effective measure for the high subsonic speed passenger plane, can not be applied, a reduction of the supersonic jet noise, which is hard to be reduced, becomes a necessity. In addition, in recent years, a research and development of the advanced turbo prop (ATP) aircraft with a further higher thrust efficiency are advanced as well. The aerodynamical noise reduction technologies of these engines for supersonic airplanes are summarized. 14 refs., 11 figs., 1 tab.

  8. On practicality of a hybrid car with solar cells; Taiyo denchi wo tosaishita hybrid car no jitsuyosei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Sasaki, K; Nagayoshi, H; Kamisako, K [Tokyo University of Agriculture and Technology, Tokyo (Japan)

    1997-11-25

    The paper stated a development of a hybrid car which is a parallel type with gasoline engine and electric motor as driving source (connecting each according to the situation) and is also equipped with solar cells. Specifications are gasoline engine of 1200cc, induction motor of 5.5kW, lead battery of 288V and 7.2kWh, monocrystal silicon solar cells of 180W maximum output, and body weight of 1100kg. The rear wheel is driven by electric motor, and the front wheel by gasoline engine. The car is loaded with battery charge use solar cells on hood and roof. To enhance cleaning degree, 1.6kW solar cells are installed as an installed power system and used for battery charge. Even by an electric motor with output less than that of the usual electric car, harmful exhaust gas emitted in start-up can be controlled. This is because the electric motor can be used in accelerating. It was confirmed that the power required for it could be supplied by solar cells installed on the car. The hybrid car is practically useful for prevention of local air pollution. 5 refs., 4 figs., 2 tabs.

  9. Prediction of strong acceleration motion depended on focal mechanism; Shingen mechanism wo koryoshita jishindo yosoku ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kaneda, Y; Ejiri, J [Obayashi Corp., Tokyo (Japan)

    1996-10-01

    This paper describes simulation results of strong acceleration motion with varying uncertain fault parameters mainly for a fault model of Hyogo-ken Nanbu earthquake. For the analysis, based on the fault parameters, the strong acceleration motion was simulated using the radiation patterns and the breaking time difference of composite faults as parameters. A statistic waveform composition method was used for the simulation. For the theoretical radiation patterns, directivity was emphasized which depended on the strike of faults, and the maximum acceleration was more than 220 gal. While, for the homogeneous radiation patterns, the maximum accelerations were isotopically distributed around the fault as a center. For variations in the maximum acceleration and the predominant frequency due to the breaking time difference of three faults, the response spectral value of maximum/minimum was about 1.7 times. From the viewpoint of seismic disaster prevention, underground structures including potential faults and non-arranging properties can be grasped using this simulation. Significance of the prediction of strong acceleration motion was also provided through this simulation using uncertain factors, such as breaking time of composite faults, as parameters. 4 refs., 4 figs., 1 tab.

  10. Proposal on an automatic ship shell member arranging system; Sengai buzai jido seiri system no teian ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Yoshitomi, T; Azumi, N [Kyushu Kyoritsu University, Fukuoka (Japan)

    1996-04-10

    Based on an investigation on the current status of member sorting and on analysis on restrictions to automation of the ship shell process, this paper describes a basic plan for a system to automate sorting works for members. The system is intended for power saving in new fields, improvement in safety and hygiene, and prevention of errors in member sorting. The automation is intended on small bones that are large in number and tend to cause errors in sorting. The area of an elbow plate of 2,000 mm {times} 800 mm thought to be small bones of the largest class is 0.80 m{sup 2}, and the weight of the small bones is made almost constant at 80 kgf. Therefore, a robot working as a major component is selected from models that have a capability of carrying a weight of 100 kgf and are capable of numerical control. A robot body is mounted on a moving trolley to sort out members cut out from steel sheets. Because the data to operate the robot can be created automatically from the data base, sorting errors due to human mistakes decrease. Amount of the member finding and handling works also decrease in the assembly process. 4 figs.

  11. Geological evaluation on productibility of coal seam gas; Coal seam gas no chishitsugakuteki shigen hyoka ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Fujii, K [University of Shizuoka, Shizuoka (Japan). Faculty of Education

    1996-09-01

    Coal seam gas is also called coal bed methane gas, indicating the gas existing in coal beds. The gas is distinguished from the oil field based gas, and also called non-conventional type gas. Its confirmed reserve is estimated to be 24 trillion m {sup 3}, with the trend of its development seen worldwide as utilization of unused resource. For the necessity of cultivating relevant technologies in Japan, this paper considers processes of production, movement, stockpiling, and accumulation of the gas. Its productibility is controlled by thickness of a coal bed, degree of coalification, gas content, permeability, groundwater flow, and deposition structure. Gas generation potential is evaluated by existing conditions of coal and degree of coalification, and methane production by biological origin and thermal origin. Economically viable methane gas is mainly of the latter origin. Evaluating gas reserve potential requires identification of the whole mechanism of adsorption, accumulation and movement of methane gas. The gas is expected of effect on environmental aspects in addition to availability as utilization of unused energy. 5 figs.

  12. What have pneumatic manufacturers tried in energy saving; Kukiatsu maker wa sho energy ni tsuite donoyona kokoromi wo shitekitaka

    Energy Technology Data Exchange (ETDEWEB)

    Oneyama, N [SMC Corp., Tokyo (Japan)

    1996-05-15

    Presented herein are new energy-saving type products by pneumatic manufacturers. The pneumatic slide rule was developed in 1974, when the whirlwind of energy-saving as a result of the oil crisis raved all over the industries. The word energy-saving for pneumatic systems is changed into the word air-saving, which is more straightforward and directly related to saved money, and the slide rule exhibits its ability as a diagnostic tool for air-saving without adversely affecting the system functions. Noting that output required by clamping, calking and conveyance as typical works for a double acting cylinder is generated only by the forward stroke, the PFC valve was developed, in which the return stroke is set at a minimum indispensable pressure. This reduces air consumption by 20 to 30%. The other products developed include energy-saving lifter and economy valve. A new cylinder driving method was developed to reduce air consumption. The system concept of the right pressure in the right place was proposed to provide a local compressor in a production line of low pressure and high capacity. It is necessary to develop in the future an index which allows direct comparison of an energy-saving system with other driving systems. 5 refs., 14 figs.

  13. Approach undertaken by our Company for leveling electric loads; Chubu Denryoku Kabushi Kaisha no fuka heijunka eno torikumi ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-07-01

    Measures for leveling the electric loads relying upon two facets - tariff system and business activities - in Chubu Electric Power Co., Inc. are presented. Firstly, the existing pricing systems for midnight electric power and electric light according to the period of time for the household as well as those of seasonal and time zone electric power, modifiable contract with the time zone and so forth for large industry users, together with a similar contract for the owner of regenerating installation are outlined. In addition, a price reduction system is indicated in favor of a scheduled shutdown of large industry operations as a means of avoiding electric consumption during weekdays in summer and between 13h and 16h when large demands exist. Further, a selective contract system put in service in 1995 and the price reduction for ice regenerating air conditioning system are cited. As for business facet, 1995 is regarded as the first year of the ice regenerator for its generalization through exhibition and promotive campaign to the foods processing industry, and the application of the latent heat regenerative system to perishable foods is recommended. Moreover, installation of energy saving type automatic vending machine, so-called eco-vendor is encouraged for its merit of peak-cut and energy price lowering. Lastly, activities to extend the use of electric calorifiers and the regenerative floor heating are mentioned. 2 figs., 1 tab.

  14. Load leveling efforts of The Hokkaido Electric Power Co. Inc.; Hokkaido Denryoku no fuka heijunka eno torikumi ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-04-01

    The Hokkaido Electric Power Co., Inc., aiming to enhance power generation efficiency through power load levelling, strives to expand and substantiate its electricity billing menu and to popularize and encourage the use of levelling-oriented apparatuses and systems most of which are designed for utilizing midnight power. The billing menu has in it a snow-melting power which is cut off for load levelling during the peak demand time zone. For domestic use, a time zone-specified lighting system named Dream Eight is created, which is one of the billing systems dependent upon time zone. Introduced therein for industrial use is a demand/supply adjustment contract system. Furthermore, in compliance with the amended Electricity Business Law that came into force in 1995, efforts are under way for revising the period wherein power is to be supplied for melting snow, expanding the scope of application of the power supply system dependent upon time zone, and newly introducing a heat accumulation assisted peak adjustment contract system and an operation adjustment contract system. As for business efforts in relation to load levelling, the company proposes household electrical systems centering about 200V high-efficiency apparatuses, electric water warmer contributing to the enhancement of year-round load levelling, popularization and reinforcement of electric snow melting systems, and power utilizing technologies capable of meeting local demands raised for example by agriculture and fishery.

  15. Efforts of load leveling in Tohoku Electric Power Co. Inc.; Tohoku denryoku no fuka heijunka eno torikumi ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-05-01

    This paper describes efforts of load leveling in Tohoku Electric Power Co., Inc. from the viewpoint of the rate system and business development. For the approach from the rate system, various rate menus for the peak shift have been arranged for domestic and large industry customers. To create the midnight demand, spread and expansion of electric hot water service are promoted. Consequently, the contract of midnight power has reached 914,000 kW at the end of 1995, which was 774,000 kW in 1985. To spread the ice regenerative air conditioning systems, the grant of incentive to the manufacturers and special discount of electricity rate have been conducted. These systems have been introduced in the eight places of Tohoku Electric Power`s business. The spread incident system has been created to introduce the automatic vending machines for beverages with the power peak cut function. Unused energy, such as exhaust heat from the non-treated sewage water and substations has been utilized as a heat supply project for city redevelopment. Multi-functional heat pump with regenerative function has been developed. This system aims at the peak shift by combining multi-functional heat pump and electric hot water service. 2 figs., 2 tabs.

  16. Experimental study of improvement on combustion control of fluidized bed combustion chamber; Ryudosho shokyakuro no nenshosei no kaizen ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Izumiya, T.; Baba, K.; Koshida, H.; Uetani, J.; Furuta, M.

    1998-10-29

    Nippon Steel Corporation has carried out an experimental study using the Yawata waste incinerator plant in order to improve combustion control of a fluidized bed combustion chamber. For controlling the forming of dioxin, combustion control is very important in addition to conventional methods. In this paper, we report two studies about improvements on combustion control. In the first study, we verified improvement on combustion control by modifying gas flow at the freeboard. The operational results of the experiments were studied using the numerical model of the combustion chamber. The modification of gas flow at freeboard was confirmed to be effective to obtain a compact design of fluidized bed combustion chamber for municipal waste. In the second, study we improved combustion control for sewage combustion with municipal waste. In burning municipal waste and sewage, it is especially required to take combustion control into careful consideration. In this experiment, we developed a new device for supplying sewage for the appropriate controlling combustion, and verified its effectiveness to combustion control and an effective reduction of dioxin. (author)

  17. Kurokawa 150-kW wind turbine generator demonstration; 150 kW Kurokawa furyoku hatsudensho ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Okamoto, M; Shinohara, M; Sugiyama, T [Kansai Electric Power Co. Inc., Osaka (Japan)

    1996-10-27

    This paper presents the 150kW wind turbine generator erected at a site near Kurokawa dam lake of Kansai Electric Power Co. in Hyogo prefecture. This generator is composed of a horizontal-axis propeller with 3 blades of 27m in diameter and 36/27rpm, and a tower of 30m high. Harmony with the environment was also considered because of the site in a natural park area. Its demonstration test started in Oct. 1996 at annual mean wind velocity of 2m/s. Soft start was realized by controlling inrush current and preventing voltage drop in system interconnection by use of a thyristor circuit. The dual operation system was adopted of a 30kW small generator at lower wind velocity and a 150kW large one at higher velocity. Two kinds of brakes are used, and rotor revolution was reduced by air brake (blade tip spoiler). Mechanical disk brake works for the stopped rotor or emergency stopping. Even if the wind turbine was stopped by exterior factor, if no anomaly of the turbine is found, it automatically re-starts after removal of the factor. The generator is controlled from a remote control station 150km apart through NTT communication line. 6 figs., 2 tabs.

  18. On the building of Momoyama hydraulic power station on Kiso river. Kisogawa Momoyama suiryoku hatsudensho no kenchiku ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kotera, T [Nagoya University, Nagoya (Japan). Faculty of Engineering

    1991-09-30

    This paper investigates Momoyama hydraulic power station built on the middle reaches of the Kiso River in Uematsu-cho, Kiso-gun, Nagano Prefecture in Japan, in 1923 by relating to the feature of the building of the hydraulic power station and the architect, Shiro Sato. The hydraulic power station originally was a functional and industrial building which puts a priority on the efficiency of business economy, at the same time it was often required to present a beautiful appearance. The building of Momoyama hydraulic power station was founded on the crane girder structure covered with reinforced concrete(RC) walls. A Hat roof of RC slab was applied to the roof of the building. It was generally designed in Neo-Gothic style. More specifically, however, the wall surface was designed in church style and the upper part was like a castle in the middle ages. Therefore the total design was eclectic. The outer surfaces of the building were remained to be bare concrete as cast. Such a multiple building symbolizes the situation of Japanes architecture in the 1920s. 4 figs.

  19. Study of an optimization of regeneration for an absorbent used in the solar desiccant cooling system; Taiyonetsu riyo desiccant reibo ni mochiirareru kyushuzai saisei tokusei no saitekika ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Saito, Y [Osaka Institute of Technology, Osaka (Japan)

    1997-11-25

    A desiccant cooling system uses concentrated aqueous solution of an absorbent to reduce humidity, hence the resultant absorbent solution becomes dilute. Regeneration of the dilute solution uses solar heat, where the regeneration characteristics are affected by solution temperature, vapor pressure, water content, air-liquid flow rate, and other factors. Therefore, mutual relationship among these different factors were investigated, and an optimum operating condition was discussed. The regeneration characteristics of the absorbent is strongly affected by temperature of triethylene glycol (TEG). This is because vapor pressure, Ps, in the TEG aqueous solution increases as the TEG temperature rises. This means that preheating the solution is effective in regenerating the absorbent. As the regeneration progresses, the water content, Ww, decreases, and the regeneration rate decreases. This is because of reduction in the Ps in association with decrease in the Ww of the TEG. This suggests that it is important in the absorbent regeneration to reduce flow rate of the TEG aqueous solution as low as possible. Raised air temperature reduces difference in vapor partial pressure between the TEG and the air, resulting in reduced regeneration rate. 5 refs., 9 figs.

  20. Pseudo-random data acquisition geometry in 3D seismic survey; Sanjigen jishin tansa ni okeru giji random data shutoku reiauto ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Minegishi, M; Tsuburaya, Y [Japan National Oil Corp., Tokyo (Japan). Technology Research Center

    1996-10-01

    Influence of pseudo-random geometry on the imaging for 3D seismic exploration data acquisition has been investigate using a simple model by comparing with the regular geometry. When constituting wave front by the interference of elemental waves, pseudo-random geometry data did not always provide good results. In the case of a point diffractor, the imaging operation, where the constituted wave front was returned to the point diffractor by the interference of elemental waves for the spatial alias records, did not always give clear images. In the case of multi point diffractor, good images were obtained with less noise generation in spite of alias records. There are a lot of diffractors in the actual geological structures, which corresponds to the case of multi point diffractors. Finally, better images could be obtained by inputting records acquired using the pseudo-random geometry rather than by inputting spatial alias records acquired using the regular geometry. 7 refs., 6 figs.

  1. Matching of wind turbine type and system scale to wind conditions; Chiten no fukyo ni taisuru furyoku turbine no keitai to sytem taikaku no seigosei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Wakui, T. [Japan Society for the Promotion of Science, Tokyo (Japan); Tanzawa, Y. [Nippon Institute of Technology, Saitama (Japan); Ota, E. [Waseda University, Tokyo (Japan). School of Science and Engineering; Hashizume, T.

    2000-09-25

    The matching of the wind turbine type and system scale of the stand-alone wind turbine generator system to wind conditions is investigated using our dynamic simulation model. This paper examines three types of wind turbines: the Darrieus-Savonius hybrid wind turbine, the Darrieus turbine proper and the up-wind Propeller turbine. These systems are mainly operated at a constant tip speed ratio, which refers to a maximum power coefficient. As a computed result of the net extracting energy under fluctuations of wind speed and direction, the Darrieus turbine proper has little conformability to wind fluctuations because of its output characteristics. As for other wind turbines, large-scale systems do not always have advantages over small-scale systems as the effect of the dynamic characteristics. Furthermore, it is confirmed that the net extracting power of the Propeller turbine under wind direction fluctuations is much reduced when compared with that of the hybrid wind turbine. Thus, it is concluded that the appropriate wind turbine type and system scale exist for each wind condition. (author)

  2. Some future projects in space activities. Centering around utilization of moon and satellite; Uchu kaihatsu no mirai koso ni tsuite. Tsuki/wakusei no riyo wo chushin ni

    Energy Technology Data Exchange (ETDEWEB)

    Saito, T [Obayashi Corp., Osaka (Japan); Kobayashi, H [Taisei Corp., Tokyo (Japan); Takagi, K [Shimizu Corp., Tokyo (Japan)

    1994-09-05

    Imagining a space in the middle of the 21st century, a space station installed with the artificial gravity generation facility is constructed, and a space factory utilizing a gravity free environment is also constructed. The construction materials for the space structures of this kind are prepared from the resources of the Luna. A solar power generation satellite being arranged with the solar cells manufactured from a silicon of the Luna is allocated on a geostationary orbit, and a power generated is supplied to the earth by the microwave. In such a time, a regular liner to the Luna and a ferry boat to the Mars will have come to fly, and furthermore an oxygen used for the propellant to them as well will be supplied from the Luna. In order to realize such a conception, there are various problems to be overcome such as a transportation problem first of all, a long life problem in the Luna and Mars bases and so forth. Furthermore a consideration to the environmental conservation of the Luna and Mars is also required. The nature of the Luna without a crustal alteration, meteorological phenomena, and organisms has no force to restore an environmental destruction. As for a space development in the future, it is desired that it should not damage a nature of the space and should be a field to chase a possibility of the human beings for a long time. 30 refs., 14 figs., 1 tab.

  3. Interpretation SP anomaly caused by subsurface fluid flow; Chika ryudokei ni yoru shizen den`i anomaly no kaishaku ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Yasukawa, K [Geological Survey of Japan, Tsukuba (Japan); Mogi, T; Kawahira, M [Kyushu University, Fukuoka (Japan). Faculty of Engineering

    1996-05-01

    A PTSP simulator, developed by combining a fluid flow simulator and a simulator for computing the spontaneous potential (SP) out of flow velocity distribution, was used to investigate the impact of the distribution of terrain, permeability, and resistivity upon the ground surface SP. SP computation using simple models such as highlands or cliffs indicated that the terrain-caused SP anomaly was negatively dependent upon elevation. It was also indicated, however, that, in some types of resistivity distribution, the SP profile changes, the peak goes out of place, and even the apparent polarity may reverse in extreme cases. In the study of the SP profile for the Takeyu hot spa, Oita Prefecture, PTSP-aided modeling was carried out. It was then found that fluid flows caused by the terrain were not enough to explain the peak at the middle of the mountain, which suggested the existence of a fluid flow caused by temperature distribution. 11 refs., 5 figs.

  4. Analysis of the pressure response of high angle multiple (HAM) fractures intersecting a welbore; Kokeisha multi fracture (HAM) kosei ni okeru atsuryoku oto kaiseki ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Ujo, S; Osato, K [Geothermal Energy Research and Development Co. Ltd., Tokyo (Japan); Arihara, N [Waseda University, Tokyo (Japan); Schroeder, R

    1996-05-01

    This paper reports pressure response analysis on wells piercing a high angle multi (HAM) fracture model. In this model which is defined on a three-dimensional space, a plurality of slanted fractures intersect with wells at high angles (however, intersection of fractures with each other is not considered). With respect to the pressure response analysis method using this model, the paper presents a basic differential equation on pressure drawdown and boundary conditions in the wells taking flows in the fractures pseudo-linear, as well as external boundary conditions in calculation regions (a reservoir spreads to an infinite distance, and its top and bottom are closed by non-water permeating beds). The paper also indicates that results of calculating a single vertical fracture model and a slanted fracture model by using a numerical computation program (MULFRAC) based on the above equations agree well respectively with the existing calculation results (calculations performed by Erlougher and Cinco et al). 5 refs., 6 figs.

  5. Starting and stopping control on power conditioner in photovoltaic power system; Taiyoko hatsuden system ni okeru power conditioner no kido teishi seigyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Hirose, M.; Ishihara, Y.; Todaka, T.; Harada, K. [Doshisha University, Kyoto (Japan); Oshiro, H.; Nakamura, H. [Japan Quality Assurance Organization, Tokyo (Japan)

    1997-11-25

    Studies are made about the control of the power conditioner over the maximum power point tracking (MPPT) function in a photovoltaic power generation system. The analysis is conducted by means of computer simulation into the effect of a start/stop function added to the control of MPPT and the effect on the generation of power of the setting of parameters in the start/stop function. The reduction in output power due to difference between the actual operation point and the optimum operation point is evaluated by use of a load matching correction factor. In this simulation, it is assumed that the solar cell array consists of 13 rows in 5 parallel columns, is capable of a normal output of 3.149kW, has a panel tilted at 30 degrees, and faces due south. The power conditioner is assumed to be a system rated at 3kVA, equipped with system interconnection and back flow features. As a result, it is learned that the stop voltage should be set at 180V or lower and the steady voltage near 185.5V for a good result and that there is not much need after all for the start/stop technique. 2 refs., 8 figs., 2 tabs.

  6. Efficient conditions for the elution of poliovirus transferred to activated sludge; Kassei odei ni ikoshita poliovirus no yushutsu joken ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kim, T.; Shiragami, N.; Unno, H. [Tokyo Institute of Technology, Tokyo (Japan); Honda, H. [Nagoya University, Nagoya (Japan). Faculty of Engineering; Yano, K. [Tokyo Metropolitan Research Laboratory of Public Health, Tokyo (Japan)

    1994-08-10

    Enteric virus discharged from human being is treated together with sewage water, but the activated sludge process cannot treat it completely. It is, therefore, important to ascertain its behavior and clarify the treatment criteria. For quantification of virus transferred to the activated sludge phase, the virus is put in a free state by using an adequate eluate to make measurement possible by means of a plaque forming method. This paper discusses the eluate used in this case and its conditions, and obtains the following conclusions: a basic region including neutral region is more effective than acidic region when beef extract is used as an eluate; among the chaotropic salts used, NaNO3 is the most effective, and has a capability of elution in a wide range regardless of pH; and the optimal eluting condition involves a combination of certain amounts of beef extract and NaNO3 that can block the electrostatic actions and hydrophobic interactions between the activated sludge and the virus. 20 refs., 7 figs., 3 tabs.

  7. Estimation of performance of a high-speed boat by using the Rankine source method; Kosokutei no rankinsosuho ni yoru seino suitei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Eguchi, T [Mitsui Engineering and Shipbuilding Co. Ltd., Tokyo (Japan)

    1997-10-01

    This paper describes estimation of performance of a high-speed boat by using the Rankine source method. An orthogonal coordinate system is considered, which uses the center of a hull as the zero point, and is made dimensionless by using the hull length. The catamaran boat or the single hull boat being the subject of the discussion is supposed to have a transom stern, and to be sailing at a constant speed in the -X direction. A governing equation and a border condition were formulated using disturbance speed potential and X-direction speed differentiation. An inverse specular image was employed as a specular image system upon considering attitude change in the high-speed boat. As to the division of hull surface, the portions protruded above the static water surface were cut off from among the panel data of boat CAD. Considering a high speed condition in which the water surface is completely separated at the transom section, the water level at the transom section was supposed to be at the same height as at the rear end of the hull. Blow-out intensity at the water surface was derived in such a way that a CAD panel of the rear end of the hull is searched and wave height agrees with the height of the transom in the Z direction. A resistance curve may be obtained easily by using a personal computer. 4 refs., 8 figs.

  8. On the VPP and current administrative strategies of US OSHA; Beikoku OSHA ni okeru jishuteki anzen eisei kanri program (VPP) oyobi saikin no seisaku doko ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Hanayasu, S [Research Inst. of Industrial Safety, Tokyo (Japan)

    1998-02-15

    This paper describes VPP (Voluntary Protection Programs) and current administrative strategies of US Department of Labor, OSHA (Occupational Safety and Health Administration). Although VPP is conducted by the Federal Government or the state governments with original VPP, it is properly a voluntary program in which entrepreneurs independently participate. OSHA inspects the content and execution condition of every program based on a VPP standard, and after certifying a business establishment satisfying the standard as excellent one, OSHA excludes it from inspection objects for a certain period. After such a period, reinspection and renewal are repeated. This system is derived from that a voluntary program proposed by constructor of Calif. in 1978 was markedly effective to protect workers from damages. Safety and health problem includes various keywords such as internationalization, new technology, risk assessment, process control, self responsibility, information opening, and diverse policies. Although uniform regal safety and health measures are important, promotion and establishment of activities by workers and entrepreneurs themselves in a field are also important. 8 refs., 2 figs.

  9. Results of photovoltaic power generation system operation in Tokyo Electric Power Company; Tokyo Denryoku ni okeru taiyoko hatsuden setsubi no unten jisseki ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Fukuda, H; Itokawa, K [Tokyo Electric Power Co. Inc., Tokyo (Japan)

    1996-10-27

    A report was made on the measurement of data and the results of the analysis at 14 sites of photovoltaic power generation facilities operated under system interconnection by Tokyo Electric Power Company. This type of system is provided in 40 sites as of the end of fiscal 1995, generating 479kw. The items measured were the generated electric energy at all 14 sites, and the quantity of solar radiation, outside air temperature, panel temperature, etc., at limited sites; and the capacity of each equipment, azimuth and inclination of the panel were also recorded simultaneously. Hourly values were used for the analysis. Five minute values were utilized, however, in the examination of the cause of lowered output and in the situation recognition of the influence of the shade or the change of weather. The utilization factor of the facilities was in the average 10.8% in fiscal 1994 and 10.7% in fiscal 1995. The factor decreased slightly unless the panel azimuth faced due south. The utilization factor at the panel inclination of 35 degrees and 45 degrees showed both 10.4% through the year making no difference. The system seemed to show no overwhelming possibilities in coping with electric power demand. The reason was that deviation existed for 2 hours or so in the peak and that reliability was low as basic power facilities. However, it was determined that the system be continuously examined in future. 9 figs., 1 tab.

  10. Electrolyte loss mechanism of molten carbonate fuel cells. 1; Yoyu tansan`engata nenryo denchi ni okeru denkaishitsu loss kiko ni tsuite. 1

    Energy Technology Data Exchange (ETDEWEB)

    Sonai, A; Murata, K [Toshiba Research and Development Center, Kawasaki (Japan)

    1993-11-01

    During a single-cell disassembly test of molten carbonate fuel cells having been operated for 90 hours to 5500 hours, correlativity was discovered between decrease in the retained amount of electrolyte due to decrease in pore capacity of electrodes and electrolyte plates and the electrolyte loss. The electrolyte loss amount cannot be explained with the conventional mechanisms, thereby a new model was proposed. The cathode has shown very little change in the capacity change in pores with diameters smaller than 2 {mu}m per unit area. The anode has remained almost constant after 1000 hours, but the electrolyte plates have shown remarkable decrease. Therefore, it is possible to estimate that the electrolyte plates should have been the major cause for the electrolyte loss. The result of measuring the electrolyte loss amount agreed well with that estimated using pore capacity curves. This fact suggests that the electrolyte loss can be explained by a new mechanism that hypothesizes the existence of a largest size of retaining pores that can support carbonates and defines that the electrolyte loss is generated from decrease in the pore capacity. 7 refs., 8 figs., 1 tab.

  11. High resolution aeromagnetic and radiometric survey in the Hokusatsu district, Japan; Hokusatsu Kushikino chiiki ni okeru kobunkaino kuchu jiki hoshano tansa kekka ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Hishida, H; Yoshioka, K [Metal Mining Agency of Japan, Tokyo (Japan)

    1997-10-22

    In FY 1996, aeromagnetic and radiometric survey was performed in the whole area of Hokusatsu district using a helicopter fixed with a stinger mount system with high density 200 m line spacing at low altitude of 80 m, which was the first in Japan. Based on the existing geological maps, Landsat TM data and radiometric data, lithologies and geological structures were extracted in response to individual magnetic characteristics in the whole magnetic map. Obtained geological characteristics are as follows. Straight magnetic anomalies suggested volcanic lava flows. Isolated ring-shaped magnetic anomalies suggested intrusive rocks. Ring-shaped weak magnetic anomalies suggested the centers of volcanoes. Wide range intense magnetic anomalies were caused by deep intrusive rocks. Wide range weak magnetic anomalies were caused by dissipation of magnetite due to hydrothermal alteration. Faults and fracture zones were recognized as linear configurations of magnetic anomaly and divided magnetic anomalies. Based on these results, local geological structures, hydrothermal alterations, and mineralization of known ore deposits were interpreted. 6 refs., 5 figs.

  12. On the sea-covering effect of a huge floating structure on the surrounding water; Choogata futai shuhen no kaisui ni taisuru kaimen shahei no eikyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Fujino, M; Kagemoto, H; Hamada, T [The University of Tokyo, Tokyo (Japan)

    1997-12-31

    The numerical analysis program based on the difference method for dynamics of sea water with sea-surface displacement, flow rate, salt content and temperature as the parameters is modified to more accurately assess the effects of a huge marine structure on surrounding environment by adding the effects of insolation and boundary conditions of the sea-covering effects of the floating structure. The numerical simulation was done for summer and winter seasons, not in a sea area but using a rectangular bay with the floating structure at the center. A new flow evolves around the floating structure, due to the sea-covering effect. The flow patterns in summer and winter are clearly different, due to difference in insolation. The predicted flow is also sensitive whether stratification is considered or not, by which is meant that it is important what stratification effect is taken into account. Daily insolation changes are accompanied by vertical distribution of water temperature and its temporal change. These effects are also observed under the floating structure which shields insolation. 10 refs., 17 figs., 4 tabs.

  13. Study of fuel control strategy based on an fuel behavior model for starting conditions; Nenryo kyodo model ni motozuita shidoji no nenryo hosei hosho ni tsuite no kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Nakajima, Y; Uchida, M; Iwano, H; Oba, H [Nissan Motor Co. Ltd., Tokyo (Japan)

    1997-10-01

    We have applied a fuel behavior model to a fuel injection system which we call SOFIS (Sophisticated and Optimized Fuel Injection System) so that we get air/fuel ratio control accuracy and good driveability. However the fuel behavior under starting conditions is still not clear. To meet low emission rules and to get better driveability under starting conditions, better air/fuel ratio control is necessary. Now we have understood the ignition timing, injection timing, and injection pulse width required in such conditions. In former days, we analyzed the state of the air/fuel mixture under cold conditions and made a new fuel behavior model which considered fuel loss such as hydrocarbons and dissolution into oil and so on. Al this time, we have applied this idea to starting. We confirm this new model offers improved air/fuel ratio control. 6 refs., 9 figs., 3 tabs.

  14. Influence of frequency spectra to annoyance caused by road traffic noise; Doro kotsu soon no urusasa ni oyobosu shuhasu supekutoru no eikyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Ishiyama, T [Japan Automobile Research Institute Inc., Tsukuba (Japan); Hashimoto, T [Seikei University, Tokyo (Japan)

    1997-10-01

    This paper describes a study of annoyance to road traffic noise in laboratories. To measure the annoyance to road traffic noise, subjective evaluation test was carried out using 48 road traffic noise recorded at various points in the city. Among the frequency spectra of these noise, the differences on the SPL of high frequency component were significant. As a result, we found that: (1) annoyance was different while A-weighted SPLs were the same, (2) fluctuation strength had the highest correlation with annoyance, (3) besides A-weighted SPL, roughness and sharpness contributed to annoyance -simultaneously, (4) contribution of high frequency noise was significant to annoyance. 2 refs., 11 figs., 1 tab.

  15. Fixed position holding control for self-propulsion barges under disturbance condition; Gairanka ni okeru jiko baji no teiten hoji seigyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kijima, K; Murata, W; Furukawa, Y [Kyushu University, Fukuoka (Japan). Faculty of Engineering

    1996-04-10

    In direct hoisting work in suspension bridge construction, since a cable crane directly hoists a bridge beam block put on a barge on the sea, precise fixed position holding function is required for a barge. The control system was then designed on the basis of an ILQ control theory, and the effect of change in time constant as design parameter on fixed position holding performance was studied. In addition, the critical disturbance for fixed position holding control was studied through numerical simulation under various disturbance conditions using the above designed control system. As a result, in the design of control systems on the basis of an ILQ control theory, the precise control system could be designed by diminishing, in particular, the time constant for state variable around a z axis among time constants according to the extent of disturbance. The control performance was largely affected by response delay period from sensing of disturbance to beginning of control. 3 refs., 7 figs., 2 tabs.

  16. On the sea-covering effect of a huge floating structure on the surrounding water; Choogata futai shuhen no kaisui ni taisuru kaimen shahei no eikyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Fujino, M.; Kagemoto, H.; Hamada, T. [The University of Tokyo, Tokyo (Japan)

    1996-12-31

    The numerical analysis program based on the difference method for dynamics of sea water with sea-surface displacement, flow rate, salt content and temperature as the parameters is modified to more accurately assess the effects of a huge marine structure on surrounding environment by adding the effects of insolation and boundary conditions of the sea-covering effects of the floating structure. The numerical simulation was done for summer and winter seasons, not in a sea area but using a rectangular bay with the floating structure at the center. A new flow evolves around the floating structure, due to the sea-covering effect. The flow patterns in summer and winter are clearly different, due to difference in insolation. The predicted flow is also sensitive whether stratification is considered or not, by which is meant that it is important what stratification effect is taken into account. Daily insolation changes are accompanied by vertical distribution of water temperature and its temporal change. These effects are also observed under the floating structure which shields insolation. 10 refs., 17 figs., 4 tabs.

  17. Characteristics of radiation temperature and radiosity coefficient by means of infrared radiometer. Sekigai hoshakei ni yoru zairyo hyomen no hosha tokusei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Okamoto, Y; Kaminaga, F [Ibaraki University, Ibaraki (Japan). Faculty of Engineering; Ishii, T; Sato, K [Ibaraki University, Ibaraki (Japan); Kurokawa, T [NEC San-ei Instrumentsu Ltd., Tokyo (Japan)

    1991-12-25

    A radiation thermometer was applied to the measurement and analysis of radiation temperature of the material surface. In this paper, the characteristics of the radiation temperature and the radiosity coefficient of gray body materials are investigatied. An infrared radiometer was used, which detects radiation energy in the region between 8 and 13{mu}m of wavelength. This infared radiometer has a Hg-Cd-Te photon radiation sensor. The variation of emissivity was measured for the four kinds of non-metalic materials, i.e., graphite, carbon fiber composite, Si-SiC ceramic, and black paint spread on an aluminum plate. As a result, the relationship between material temperature and radiation energy was made clear. Furthermore, the space-dependent variation of the radiation temperature and the radiosity coefficient was derived from the two-dimensional CRT image of the infrared radiometer. Consequently, the emmisivity variation gave a maximum for the carbon fiber composite surface rich in irregularity, and decreased in the order of graphite, Si-SiC, and black paint. 7 refs., 15 figs.

  18. Pitting corrosion of copper in aqueous solutions containing phosphonic acid as an inhibitor. Hosuhon san wo inhibita toshite fukumu suiyoekichu ni okeru do no koshiku ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Yamada, Y. (Muroran Univ., Hokkaido (Japan). Graduate School); Seri, O.; Tagashira, K. (Muroran Univ., Hokkaido (Japan)); Nagata, K. (Sumitomo Light Metal Co. Ltd., Tokyo (Japan). Technical Research Lab.)

    1993-09-15

    Phosphonic acid-based inhibitors that are poured into cooling water for copper-tube circulation systems for open heat-accumulators were studied on their influence on pitting corrosion of copper. Amino trimethylene phosphonic acid (ATMP) dissolved into distilled water to 50 ppm was used for the immersion corrosion test. The corrosion-proof effect of additives such as ZnSO4, benzotriazole (BTA) was tested too. 0.5 mm thick phosphate-treated copper plates with a hole of 5 mm in diameter were used as test specimens. Pitting corrosion on the copper plate occurred when ATMP, BTA and ZnSO4 coexisted. It was proved that SO4 [sup 2-] is essential since Na2SO4 in stead of ZnSO4 induced also corrosion. The pitting took place when 0.6 ppm or more of SO4 [sup 2-] was present in a BTA-added ATMP solution. It was observed that the pitting is prone to occur with increase of SO4 [sup 2-] and the number of pitting increases. The following relationship is established when pitting corrosion occurs; E[sub b] [le] E[sub corr], where the former is a potential value at which current density shows a steep increase and the latter is an average value of spontaneous electrode potential showing a plateau. 8 refs., 11 figs., 1 tab.

  19. Development of multi-filter spectroradiometry; Filter hoshiki ni yoru bunka hosharyo no keisoku hoho to sono supekutoru no hyogen hoho ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Miyake, Y; Aoshima, T; Minoda, T; Kato, T; Kondo, S [Eiko Instruments Trading Co. Ltd., Tokyo (Japan)

    1996-10-27

    Described in this paper is a technique of solar radiation spectroradiometry in which high-resolution wavelength computation adds to a multi-filter method. The solar spectrum upon entering the atmosphere is scattered and absorbed by parameter-constituting elements such as gas, aerosol, cloud particles, etc., and its spectral contour is complicatedly deformed relative to wavelength. Taking advantage of the fact that the scattering and absorbing characteristics of some of the elements are constant relative to wavelength, a simple equation was constructed to enable high-resolution spectrum measurement wavelength-wise, and this compensates for the limit in measurable wavelength that the conventional multi-filter method suffers from. The new method discussed here is not so expensive as the grating method thanks to the employment of filters, is capable of determining spectral radiation quantities with a precision of {plus_minus}5%, and is reduced in terms of the capacity of memory for data storage. The new method enables data collection under various atmospheric conditions that the four seasons present, which the difficult-to-apply and expensive spectroradiometer fails. It is expected that this method will find its use in collecting basic data for the designing of photovoltaic power generation systems, in the study of photochemical reaction in agriculture, and in collecting basic data for daylight lighting. 1 ref., 6 figs., 2 tabs.

  20. Analysis method on the factors of slope disaster occurring place with its application. Shamen saigai hassei chiten ni okeru soin bunseki no ichishuho to oyosei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Setojima, M [Kokusai Kogyo Co. Ltd., Tokyo (Japan); Shiraishi, K [Public works Research Institute, Tokyo (Japan)

    1992-06-10

    A proposal is made on a method to analyze a slope disaster in detail from a viewpoint of ''where the disaster occurred'' (to analyze in a line pattern the apertures of a collapse and main scarps in a land slide). Methodological emphasis was placed on superimposing aerial photograph images taken before and after a disaster over imaged information on factors based on land conditions including topographical characteristics. Applicability of this method was discussed using a landslide location in Niigata Prefecture as an example. This paper describes the result of tb discussion by the following items: Imaging the aerial photographs and correcting their geometrical distortion; extracting items of line-pattern information from the aerial photographs and classifying the land coverage; and analyzing factors of causing the landslide using an image superimposing process. The papers also mentioned a view that this method may be applied effectively on disasters occurring on ground surface. 11 refs., 8 figs., 2 tabs.

  1. Design and construction of landslide preventive construction at Yamasubara hydroelectric power plant site. Yamasubata hatsudensho chiten ni okeru jisuberi taisaku koji no sekkei seko ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Takase, H; Ito, M; Sakata, M [The Kyushu Electric Power Co. Inc., Fukuoka (Japan)

    1993-07-30

    This paper reports the design and construction of landslide preventive construction at the site of the Yamasubara hydroelectric power plant (with a maximum output of 40,700 kW) and the result of slope stability verification after completion of the construction. The moderate slope on top of the primary slide has sands presumed to be colluvial deposit distributed with a depth of 10 m or more, where occurrence of a secondary slip was feared as triggered by the primary slide. The power plant protective constructions consisted of concrete walls to protect the entire power plant including buildings, and falling stone protective fences installed around the surge tanks. The temporary measures were so set that groundwater levels are lowered to a level that can assure the slide safety factor of 1.0 or more by means of drain boring using the down-the-hole hammer type. The permanent protective construction used rock anchors that are superior in constructability and economy. The stability of sliding slope faces was verified to confirm effects of the protective constructions. The verification included observations of groundwater level behavior, water well-up from drain holes, and movements in the slopes. The result showed that the protective constructions have give sufficient effects. Continued slope stability control is important. 16 figs., 7 tabs.

  2. On the muscle activity control in the hierarchy motor systems. Hierarchy undo system ni okeru kin no kassei seigyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Akiba, M.; Miyamoto, Y. (Osaka Industrial University, Osaka (Japan). Faculty of Engineering)

    1991-10-31

    Excitory impulses for motor systems are controlled by the psychophysiological nervous systems in the body either autonomically or voluntarily. Involved in the voluntary control loop are motor cortex, basal gangalia, thalamus, cerebellum, etc. The purpose of this study is to confirm whether it is possible to reduce or emphasize the muscle contraction voluntarily through electromyogram (EMG) feedback training. EMG can indicate the excitory impulses of motor units. In the experiments, electrodes were placed on the skin above muscles. A significant reduction effect was observed for subjects trained in relaxation of the forehead musculature through EMG feedback. Results of the experiments suggested that biofeedback training for relaxation of the forehead tensional muscle might be effective in eliminating muscle contraction, and that feedback training for activation of damaged muscles might be effective in emphasizing muscle contraction. 4 refs., 9 figs.

  3. Quantitative analysis of the relationship between driver`s behavior and vehicle motion; Sharyo unten ni taisuru untensha no kyodo no teiryoka bunseki ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Nakagawa, H; Matsuura, Y [Osaka Sangyo University, Osaka (Japan); Masuda, T

    1997-10-01

    In order to study the subject of driving safety about the human-vehicle interaction, driver`s maneuvering behavior was shot by CCD-cameras installed in a cabin and the motion of traveling vehicle was simultaneously taken by VTR-cameras set on the test course. These pictures were analyzed using the three-dimensional image processing system (Peak Motus system). Consequently, this system was effectively able to use for these measurements and analysis and introduced the correlation between the vehicle movement and the driver`s action. 4 refs., 12 figs., 2 tabs.

  4. Evaluation of a countermeasure against wake galloping using wire connection method; Wake galloping ni taisuru seishin wire no yukosei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Takeda, T.; Mukai, H.; Sano, N. [Kajima Corp., Tokyo (Japan)

    1994-10-31

    A plurality of parallel cables have been recently employed for long-span cable-stayed bridges. Use of such parallel cables thereupon leads to a special type of wind-induced vibration called wake galloping (simply referred to as WG.) owing to air turbulence caused by upstream cables. This paper attempts to evaluate measures against the WG using a wire connecting method, and identifies the most important influencing factor and the validity of the measures through wind tunnel tests. The following results are hereby clarified. Even if the deformation rigidity of the cables is increased, it is impossible to raise the wind velocity of the WG. The wind velocity of the WG can not be reduced from a wind tunnel wind velocity using non-dimensional wind velocity. The wire connecting method proves to be more effective for reducing the amplitude of the vibration. Provided cables are coupled into a multi-stage using the wire connection method, overall vibration with a greater amplitude can be restricted. To the factor of the restriction additional deformation rigidity of the cables more contributes compared with additional weight of the cables. 9 refs., 13 figs., 2 tabs.

  5. Study on a small diesel engine with direct injection impinging distribution spray combustion system. Optimum of injection system and combustion chamber; Shototsu kakusan hoshiki kogata diesel kikan ni kansuru kenkyu. Funshakei to nenshoshitsu no saitekika

    Energy Technology Data Exchange (ETDEWEB)

    Fujita, K; Kato, S; Saito, T [Kanazawa Institute of Technology, Ishikawa (Japan); Tanabe, H [Gunma University, Gunma (Japan)

    1997-10-01

    This study is concerned with a small bore (93mm) diesel engine using impinged fuel spray, named OSKA system. The higher rate of injection show lower smoke emission with higher NOx Emission. The exhaust emission and performance were investigated under different compression ratio with higher rate of injection. The experimental results show that this OSKA system is capable for reducing the smoke emission without the deterioration of NOx emission and fuel consumption compared with the conventional DI diesel engine. 5 refs., 8 figs., 3 tabs.

  6. Energy-saving by the optimization of the operation conditions in the vinylcloride lining steel pipe baking furnace. Enbirainingu kokan yakitsukero no sogyo joken saitekika ni yoru sho energy

    Energy Technology Data Exchange (ETDEWEB)

    Kinoshita, Y. (Kawasaki Steel Corp., Tokyo (Japan))

    1991-02-04

    By the investigation of the operation conditions in the small experimental furnace, the improvement of the heat pattern of the steel pipes, and the remodeling and arrangement of the furnace, the progress of the yield and the productivity, and the reduction of the fuel unit were expected. In baking of a PVC pipe with a steel pipe, defects of PVC pipes as the blister of the inner surface occurred often. Accordingly the conditions when the blister occurred were investigated in the experimental furnace and optimized operation conditions when it does not occur were established. Next the flow rate of the hot air and the temperature distribution in the actual furnace were examined and the mechanism of occurrence of the defects of the blister of the inner surface was investigated. As a result, it was proved that the deviation of the hot air flux and the intrusion of the outer air cause it, and the places where the outer air intruded were closed by steel plates. After the improvements the rate of the defects of PVC pipes of the blister of the inner surface was decreased from 5% to 0.5%. Further, by the optimization of the operation conditions the fuel unit decreased and 31% of the rate of the energy-saving was achieved. The reduction of 10,414,000 yen a year was achieved. 29 figs., 4 tabs.

  7. Fiscal 1997 for the upgrading of the Asia/Pacific coal development. Survey of the optimization of the coal transportation system in Indonesia; 1997 nendo Asia Taiheiyo sekitan kaihatsu kodoka chosa. Indonesia ni okeru sekitan yuso system saitekika chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper summarized the results of Phase 1 and Phase 2 surveys conducted based on `Agreement on the comprehensive survey of a coal transportation system in South Sumatra` concluded between NEDO and the Ministry of Mine and Energy in Indonesia. In addition to the data collection and site surveys made in Phase 1, conducted in Phase 2 were determination of sites for harbors, determination of a scenario on coal transportation from coal mines to harbors, optimization of the coal transportation system, social/economic assessment, and proposal on the optimum transportation system. The results of the simulation were as follows: It is the most advantageous to transport coal from coal deposit area to harbor by rail and from harbor to Paiton by barge weighed over 10,000 tons. Tanjung Api Api is the most advantageous as harbor. The production scale which is profitable became more than 15 million tons. The present coal price of PTBA is $25/t arriving Suralaya. The coal in this case is said to be 5500kcal/kg in quality, and the coal of the same quality to this is only profitable. 8 refs., 68 figs., 104 tabs.

  8. Design optimization of ideal non-imaging concentrators for solar collectors by use of yearly insolation model with frequency distribution; Dosu bunpu wo koryoshita nenkan nissha model ni yoru shunetsuyo riso hikessho shukoki no saitekika

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, A [Tokyo University of Agriculture and Technology, Tokyo (Japan)

    1996-10-27

    Optimization was carried out for the 2D-CPC (compound parabolic concentrator) known as an ideal 2-dimensional non-imaging concentrator for its application to stationary solar heat concentrators. A non-imaging optical system is a system that has an angle for incident light called an acceptance angle, and is treated as an effective tool in the field of solar energy application. Analysis was conducted from the viewpoint of energy and exergy on the presumption of constant temperature operation. For the analysis of constant temperature heat concentration, it needs to be presumed that heat concentrators are in operation only in the presence of insolation that is more than a specified level (critical insolation). When the acceptance angle is fixed for optimization, energy efficiency does not have a peak with respect to the critical probability insolation intensity (in a probability model considering frequency distribution). On the other hand, for the optimization of exergy efficiency, the half-acceptance angle should be within a 35-40{degree} range (agreeing with the optimum angle cost-wise), and the critical probability insolation should be set at 250-300W/m{sup 2} (1/4 of the maximum insolation intensity). The obtained results are low in model dependency and are sufficiently reliable. 14 refs., 4 figs.

  9. Drift data of the sea-gravity meter (SL-2) installed on the R/V Hakurei-maru; `Hakureimaru` senjo jurokei (SL-2) no drift ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Joshima, M [Geological Survey of Japan, Tsukuba (Japan); Ishihara, T [Japan National Oil Corp., Tokyo (Japan)

    1996-05-01

    This paper reports a rapid change in the drift of a sea-gravity meter SL-2 after 1987 and after its modification in 1993. In order to confirm the accuracy of the sea-gravity meter of the Hakurei-maru, changes in the lapse of time were summarized on the relative gravity value at the Funabashi base and on the drift rate in each voyage. The drift rates in the case of departing from and returning to Funabashi base were all less than 0.1mgal/day except the first year of 1987, which was presumably due to the growing stability of the gravimeter. The drift value of 1992 was 0.05mgal/day, producing an error of only 2mgal without drift compensation at the end of a 40 day voyage. The gravimeter after the total renewal of the control part in 1993 produced a large drift in the direction opposite to the conventional drift. The cause of these phenomena was supposed to be some kind of change in the spring property during the gap of one year; this large drift seemed to be settling down after the elapse of approximately one year. 4 refs., 8 figs., 2 tabs.

  10. On the prediction of hydroelastic behaviors of a huge floating structure in waves. 2nd Report; Choogata futai no harochu dansei kyodo no suiteiho ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Murai, M.; Kagemoto, H.; Fujino, M. [The University of Tokyo, Tokyo (Japan)

    1997-08-01

    On the hydroelastic behaviors of a huge floating structure, a mutual interaction theory based on the area division method is used for the analysis of a fluid problem and a mode analysis method is used for the analysis of deformation. On the continuous deformation of a floating structure, the structure is considered as a set of partial structures obtained when the plane shape was divided into squares and discretely handled as a series of rigid motions in the small partial structures obtained by dividing the partial structures more finely. The experimental result in a water tank and the distribution method at a singular point were compared on the deformation of the elastic floating structure estimated by calculation based on this formulation. The result showed that the estimation method on the hydroelastic problem proposed in this paper is valid. On the prediction of hydroelastic behaviors of a huge floating structure, various calculation examples indicate that the hydroelastic behavior is not only the relation between the structure length and wavelength, but also that the bending rigidity of a structure is a very important factor. For a huge floating structure in the 5,000 m class, up to shorter wavelength of about {lambda}/L = 1/100 must be investigated. 6 refs., 14 figs., 5 tabs.

  11. Wastes disposal on board a ship. Disposal of sewage and waste water; Senjo no haikibutsu shori. Osui oyobi haisui no shori ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, K. [Mitsui Engineering and Shipbuilding Co. Ltd., Tokyo (Japan)

    1996-07-25

    This paper describes technologies and devices suitable for disposing of sewage and waste water produced in a ship. Methods for disposing of sewage in a ship include such physico-chemical disposition methods as disinfection and sterilization, and such biological disposition methods as activated sludge sewage disposition and catalytic oxidation (biological membrane treatment). Sewage treatment devices include a storage tank type sewage treatment device often used in inner sea liners such as ferry boats, and a biological treatment device (aeration device) used as a mainstream in merchant ships, large passenger liners, and governmental ships. With the storage tank type sewage treatment device, sewage is stored in a storage tank provisionally while a ship is cruising in a discharge prohibited sea area, and discharged in a sea area allowing the discharge or when the ship enters a port. The method is simple, but limited in storage volume. An activated sludge sewage treatment device consists of a tank divided into an aeration chamber, a sedimentation chamber and a disinfection chamber, an air compressor, a chlorine dissolving apparatus, and a screen. Sewage is digested and decomposed by activated sludge, and the top clear water is disinfected by chlorine, and then discharged. 1 tab.

  12. Method for calculating steady-state waves in an air cushion vehicle. Part 2; Air cushion vehicle no teijo zoha keisanho ni tsuite. 2

    Energy Technology Data Exchange (ETDEWEB)

    Eguchi, T [Mitsui Engineering and Shipbuilding Co. Ltd., Tokyo (Japan)

    1997-10-01

    Discussions were given on a method to estimate resistance constituents in wave resistance made in an air chamber of an air cushion vehicle (ACV). An orthogonal coordinate system is considered, which uses the center of a hull as the zero point and is made dimensionless by using cushion length. Flow around the ACV is supposed as an ideal flow, whereas speed potential is defined in the flow field. Then, a linear free surface condition is hypothesized on water surface Z = 0. Number and density of waves were used to introduce a condition to be satisfied by the speed potential. A numerical calculation method arranged a blow-out panel on the water surface, and used a panel shift type Rankine source method which satisfies the free surface condition at Z = 0. Cushion pressure distribution becomes a step-like discontinuous function, and mathematical infinity is generated in the differentiation values. Under an assumption that the pressure rises per one panel where pressure jump is present, the distribution was approximated by providing one panel with inclination of the finite quantity therein. Estimation on wave height distribution in the cushion chamber showed a tendency of qualitatively agreeing with the experimental result, but the wave heights shown in the experiment had the average level decreased as it goes toward the rear of the hull. 5 refs., 5 figs.

  13. Survey and research on how large-scale technological development should be in the future; Kongo no ogata gijutsu kaihatsu no hoko ni tsuite no chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1982-03-01

    Tasks to be subjected to research and development under the large-scale industrial technology research and development system are discussed. Mentioned in the fields of resources and foods are a submarine metal sulfide mining system, a submarine oil development system for ice-covered sea areas, an all-weather type useful vegetable automatic production system, etc. Mentioned in the fields of social development, security, and disaster prevention are a construction work robot, shelter system technologies, disaster control technologies in case of mega-scale disasters, etc. Mentioned in the fields of health, welfare, and education are biomimetics, biosystems, cancer diagnosis and treatment systems, etc. Mentioned in the field of commodity distribution, service, and software are a computer security system, an unmanned collection and distribution system, etc. Mentioned in the field of process conversion are aluminum refining, synzyme technologies for precise synthesis, etc. Mentioned in the field of data processing are optical computers, bioelectronics, etc. Various tasks are pointed out also in the fields of aviation, space, ocean, and machining. (NEDO)

  14. S/N improvement method for 3D seismic data; Sanjigen jishin tansa data no S/N hi kaizenho ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Minegishi, M; Sato, M [Japan National Oil Corp., Tokyo (Japan). Technology Research Center

    1997-10-22

    Discussions were given on a method to suppress coherent noise in data derived from a non-uniform vibration transmitting-receiving point layout in three-dimensional seismic exploration. The discussions attempted suppression of coherent noise by utilizing a prediction filter for the frequency-space zone. The prediction filter for the frequency-space zone is a filter which handles coherent waveforms found in the record as a signal, and attenuates random noise. Methods to remove coherent noise may include paralleling of signals, making the tracing order random, use of an FX prediction filter, restoration of the tracing order, and restoration of the signal positions. As a result of the discussion using a simple model, it was made clear that coherent noise distributed spatially can be suppressed and signals can be extracted by applying the frequency-space zone filter. In addition, the signals extracted by this operation were found to maintain well the original waveforms. 7 refs., 9 figs.

  15. Simulation of emergency evacuation behaviour during disaster by using distinct element method; Hisaiji no gunshu hinan kodo simulation eno kobetsu yosoho no tekiyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kiyono, J.; Miura, F.; Takimoto, K. [Yamaguchi Univ., Yamaguchi (Japan). Faculty of Engineering

    1996-04-21

    In this study, the possibility to apply the Distinct Element Method (DEM) to human evacuation behavior during a disaster was investigated, evacuation from rooms to outside though a passage or steps and a jam were examined as a basic consideration. The main results were obtained as follows: according to an analysis of evacuation behavior when elements of DEM were substituted for individual humans, the trace of individual people and force acting there to and the trace of the whole group so every time can be understood, analysis can also be conducted from local to macro. In the DEM analysis, a mutual distance between people and characteristics of behavior can be expressed well by introducing an imaginary bane into the elements. Evacuation time due to change of space shape can be compared and time series change of force acting on individual people can be understood according to the investigation on evacuation time difference due to shape change at the exit and entrance and the jam caused by the arch effect happened when the crowed flow appeared at the exit and entrance. 16 refs., 21 figs., 4 tabs.

  16. Anfo and prill ammonium nitrate. Technological view of their origin and development; ANFO oyobi prill shoan ni tsuite. Tanjo to hatten no gijutsuteki kosatsu

    Energy Technology Data Exchange (ETDEWEB)

    Yamada, T. [Okamoto Machine Tool Works, Ltd., Yokohama (Japan)

    1997-06-30

    Anfo (Ammonium Nitrate and Fuel Oil)is an explosive consisting of prill ammonium nitrate and light oil that immediately spread across the world upon its debut in the U.S. around 1956, but the details of its birth, for example the name of its inventor, are not known. Granular ammonium nitrate is in production, with its porosity enhanced to elevate oil absorption efficiency to the level for the nitrate to be proper as the material for the anfo by adjusting the water content at approximately 4% in the ammonium nitrate mother liquid before corning. Efforts are being exerted by manufacturers to improve the drying process to remove excess water efficiently from granular ammonium nitrate. In Japan, industrial production of prill ammonium nitrate for the anfo began in 1964. Since then, the problem of anfo sensitivity to detonation has been solved by adjusting the oil absorption rate of prill ammonium nitrate to be in the range of 10-12%, and the problem of ammonium nitrate solidification has been solved by the development of a solidification preventing technology that utilizes solidification preventing agents based on organic surface active agents (while inorganic anti-bonding agents are in popular use in the U.S. and Europe)

  17. On the improvement of mechanical properties of monolithic silica aerogels (for transparent insulating material); Silica aerogel (tomei dannetsu zairyo) kyodo no kaizen ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Tajiri, K; Igarashi, K; Tanemura, S [National Industrial Research Institute of Nagoya, Nagoya (Japan)

    1997-11-25

    Study was made on improvement of the strength of silica aerogel as transparent insulating material. Silica aerogel is a low-density porous material with high heat insulation and transparency. To develop a insulating material with high transparency, monolithic silica aerogel was studied. For direct use of it for windows, its strength improvement was attempted. The aerogel was prepared by supercritical drying (alcohol or CO2) of silica wet gel obtained by hydrolysis and condensation of silicon alkoxide solution. To prepare the aerogel bonded on plate glass for strength improvement, the aerogel was bonded to alkoxide by exposing active silanol radical through F-etching of plate glass surface. However, to obtain the practical large-area bonded aerogel, shrinkage control of the aerogel in supercritical drying was necessary. Addition of Laponite into a silica network for strength improvement by polymer increased the bending strength by 50%. Although some reduction of its transparency was observed because of clouding, its heat insulation was stable. Further strength improvement is necessary for its practical use. 5 figs., 1 tab.

  18. Standing steady-state wave-making calculation method for air cushion vehicles; Air cushion vehicle no teijo zoha keisanho ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Eguchi, T [Mitsui Engineering and Shipbuilding Co. Ltd., Tokyo (Japan)

    1996-04-10

    The pulse-height distribution of a cushion room of air cushion vehicle (ACV) has been tried to be approached by means of the panel shift type Rankine source method. When using this method, it was not required to introduce the pressure distribution model simulating the fall-off effect for the step-formed cushion pressure distribution. The wave form and wave making resistance could be estimated precisely by assigning the pressure gradient to one longitudinal direction panel in the calculation. The waveform shape within the cushion room could be calculated rather precisely by comparing with the analytic solution. This calculation method did have an ability providing the pulse-height information in the cushion room of ACV for seal design and configuration of ships. The analytic solution using for the comparison was sufficient for determining the pulse-height in the high speed region. However, it was hard to respond to non-linear problems or optional shape problems. It was pointed out to be further improved. 5 refs., 8 figs.

  19. Measures to prevent oil pollution in oceans, and their preservation effect; Kaiyo no abura osen no boshi taisaku to hozen koka ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Shinoda, T; Fukuchi, N; Fujii, H [Kyushu University, Fukuoka (Japan). Faculty of Engineering; Sato, S

    1996-04-10

    It was intended to confirm, based on various problems surrounding oil flow-out accidents, that oil fences whose use is first considered when an oil flow-out accident occurs cause oil leakage due to oil pass-through phenomenon as the largest defect in performance of oil fences. Therefore, oil fence performance was analyzed by using a simulation. Furthermore, several types of diffusion prevention and avoidance measures, and combinations thereof were evaluated by using multi-criteria analysis. It was also elucidated how recognitions on the importance of methods to prevent oil pollution differ depending on standpoints. Difference in oil flow-out prevention performance of oil fences due to variation in tidal currents was made clear by combining a diffusion simulation using the finite element method with the prevention performance of oil fences relative to the tidal currents. In areas with no good hydrographic conditions where pollution spreads rapidly, it is necessary to suppress oil diffusion by extending oil fences double or triple, and using gelling agents. 4 refs., 8 figs.

  20. Flow field calculation around the measuring part of a circulated flow tank for measurement; Keisokuyo kairyu suiso sokuteibu no ryujo keisan ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Nishimoto, H; Ogura, R; Yamazaki, R [West Japan Fluid Engineering Co. Ltd., Nagasaki (Japan)

    1996-04-10

    In order to increase a fluid dynamic understanding of the flow field around the measuring part as for the leveling of free surface of the circulated flow tank for measurement, the velocity and free surface profile at the measuring part have been calculated by applying the numerical fluid dynamics. The results were compared with actual phenomena. For the average velocity at the measuring part, inclining angle of surpressing plate, and quantity of water in the tank, the flow field simulation by the numerical fluid dynamics has provided a qualitative agreement with actual phenomena. Especially, it was clarified from the viewpoint of numerical fluid dynamics that the fine adjustment of the inclining angle of surpressing plate and quantity of water in the tank greatly affect the creation of horizontal free surface at the measuring part. Furthermore, effects of the length of measuring part and the ceiling tilt angle of pipe conduit in the downstream of measuring part, which were hard to be analyzed experimentally from the viewpoint of facility and cost, were investigated. Consequently, it was clarified that there are critical length of the measuring part and optimum ceiling tilt angle in the leveling of horizontal free surface. Thus, an instruction for designing was obtained. The present flow field simulation was useful for the fluid dynamic understanding of the flow field at the measuring part, as for the leveling of horizontal free surface. 1 ref., 8 figs.

  1. Development of melting system using oxy-coal combustion; Sekitan chokusetsu riyo kinzoku yoyu system gijutsu (NSR) (pilot setsubi unten jokyo ni tsuite)

    Energy Technology Data Exchange (ETDEWEB)

    Sugiyama, T [Center for Coal Utilization, Japan, Tokyo (Japan); Suwa, T; Kobayashi, N; Iino, K; Yamamoto, Y; Igarashi, H [Nippon Sanso K.K., Tokyo (Japan)

    1996-09-01

    This metal melting system is a process to efficiently melt and regenerate scraps of aluminum, copper and iron by utilizing high-temperature energy obtained from pulverized coal-oxygen combustion. The process is intended to utilize coal in place of petroleum for reduced fuel cost. Joint studies have been carried out as a subsidy operation of the Agency of Natural Resources and Energy with a schedule of six years starting fiscal 1992. Development tests are being performed using a 5-ton/ch pilot plant facility since fiscal 1995 after having gone through experiments using a 1-ton/ch bench scale furnace. This paper reports the results obtained to date. Using the pilot plant facility, fiscal 1995 has achieved the initial target values, such as thermal efficiency of 55% or higher, and yield of 96% or higher for non-ferrous metals and 94% or higher for iron. The melting behavior in the furnace has improved the thermal efficiency as a whole by retaining the conditions in the preheating step for an extended period of time. The thermal efficiency has been improved better than with the bench furnace as a result of upscaling effect. 9 figs., 3 tabs.

  2. On an outline of investigation results of earthquake damage estimation for Akita prefecture; Akitaken jishin higai sotei chosa kekka no gaiyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Nogoshi, M [Akita University, Akita (Japan). College of Education

    1997-05-27

    This paper reports an outline of investigation results of earthquake damage estimation carried out in Akita Prefecture. The basic policy for this investigation consists of the following: (1) an indication on existence of a blank area in the Akita off-coast earthquake shall be viewed so importantly that a fault model is set to estimate damages; (2) because most of the earthquakes in history of Akita Prefecture are inland earthquakes with magnitude of about M=7, four earthquakes in the past shall be adopted as the set model; and (3) the central Sea of Japan earthquake in 1983 was an earthquake occurred in the Sea of Japan side and caused a great deal of damages to Akita Prefecture, and its epicenter model and damages were investigated in detail, hence these data shall be utilized in verifying the procedure and method for estimating damages studied in the present investigation. This paper reports finally estimated human damages. With an assumed earthquake as strong as the Tencho earthquake in the year of 830, more than 1000 deaths will occur in the city of Akita; with an earthquake in the scale of the Noshiro earthquake in 1694, more than 50 deaths will be counted in the city of Noshiro; one as strong as the Rikuu earthquake in 1896 will cause about 300 deaths in the cities of Yokote and Omagari, respectively; one with the scale of the 1914 Goushu earthquake will result in about 300 people to be killed in the city of Omagari and about 200 people in the city of Yuzawa; and an earthquake estimated to occur in the blank area off the Akita coast will force 33% of the residents of the Kisakata town to be evacuated from their homes. 1 fig.

  3. Technical engineers exchange project (coal mine technology field). Training in China; Gijutsusha koryu jigyo (tanko gijutsu bun`ya). Chugoku no kenshu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Adachi, T. [Japan Coal Energy Center, Tokyo (Japan)

    1998-07-01

    The paper described JCOAL`s project on the exchange of technical coal engineers of China. In the project on sending of engineers to China in the first term, coal mine engineers of Japan (Taiheiyo Coal Mine, Kushiro Works, Training Center) were sent to the Daitun coal-thermal power plant, Peixuan city, Jiangsu province, in September, 1997 to introduce the production control technology in Japan. They contributed to the heightening of productivity in coal mines in China. Eighteen Chinese participated in the training. Mechanization has been comparatively well in progress, and it was 83% in coal mining and 91% in drilling. The kind of coal is mostly a raw material coal. The stuff members are 30,000, and expert engineers are 4,200. The plant has an output of 130,000 kWh, owns its railroad, is run on the general multiple management, and is largely developing. The project on sending of engineers to China in the last term was carried out in February 1998 for tracing/confirming how the results of the training conducted in September are made the most of and if or not there is something bad and for obtaining the detailed data. A certain degree of promotion and effects were able to be confirmed. A project on training of the head, sub-head, etc. who were invited to Japan to lean production/management control was also carried out in November and December 1997. 1 tab.

  4. On the mining situation and future for Kibushi and Gairome clay in Tono-district. Tono chiku no kibushi nendo gairome nendo no sanjo to shorai ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Omaru, I [Inagaki Clay Mining Co. Ltd., Gifu (Japan)

    1993-07-10

    The Kibushi clay and the Gairome clay which have been taking the role as the domestic produced bonding materials for refractories are running out. This paper reports their current situation and measures from the standpoint of producers. The Kibushi clay production has been decreasing since it has peaked in 1975 at 855,000 tons down to as low as its half at 400,000 tons in 1989. The Gairome clay production has also been decreased sharply from having been produced at 30 mines to 7 mines in Gifu Prefecture. The current situation is such that not only higher cost is incurred in removing gravel beds covering the clay bed, but also no gravel disposal areas can be procured, and no profitability can be assumed because of degradation in clay quality. On the other hand, demand as raw material for sanitary earthenwares and potteries has been increasing rapidly from 2,265,000 tons to 2,779,000 tons, hence import dependence of the material is rising. Positive activities as measures against the ore depletion include an establishment of a company jointly invested by five companies in 1991, which intends to develop the industry from a mining industry to a manufacturing industry by custom-blending and reforming various kinds of clays produced in different locations, including imports, to achieve stable supply. 1 tab.

  5. On statistical properties of wave amplitudes in stormy sea. Effect of short-crestedness; Daihakoji no haro no tokeiteki seishitsu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Yoshimoto, H. [Ship Research Inst., Tokyo (Japan)

    1996-12-31

    Since ocean waves encountered by ocean vessels or offshore structures in actual sea areas present extremely irregular variations, a stochastic method is necessary to estimate their statistical properties. This paper first shows a calculation method for probability density function for water level variation which strictly incorporates a secondary non-linear effect containing directional dispersibility by modeling ocean waves as short-crested irregular waves. Then, the paper specifically elucidates effects of the directional dispersibility of ocean waves on statistical amount of amplitudes by deriving the statistical amount of the amplitudes based on the probability density function of the water level variation and by using a numerical simulation. The paper finally takes up data of waves in stormy sea observed in an experiment in an actual sea area, compares the result with that of theoretical calculations, and evaluates reasonability of this method. With this estimation method, individual secondary components or components of difference and sum may be subjected to influence of the directional dispersibility, but they do not differ much from the case of long-crested irregular waves on the whole. 21 refs., 11 figs., 2 tabs.

  6. Field test of trash removal screen utilizing current energy in irrigation canal; Ryusui energy wo riyoshita suisha jojinki no jissho shiken ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Goto, M; Katayama, S [National Research Institute of Agricultural Engineering, Tsukuba (Japan)

    1996-10-27

    A trash removal system working by current energy has been developed for agricultural waterway. It consists of a wheel, shaft, screen and conveyor to exhaust collected trash. Current energy is converted by the wheel into rotational power, which drives the screen lake and conveyor. It is installed in an agricultural water way, 1.2m wide, 1/5000 in gradient and 1m/s in flow speed. Observed in the field test were service conditions of the system and torque limiter, water level at each portion, wheel speed, and types and quantity of trash collected. It is found to be serviceable at a low cost. The troubles, such as noise and bent lake occurring when the chain is out of place, have been solved. The test also has clarified types of trash discarded in the waterway. 3 refs., 11 figs.

  7. Evaluation of the performance in the solar assisted heat pump system; Taiyonetsu riyo heat pump system no seino hyoka ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Saito, Y [Osaka Institute of Technology, Osaka (Japan)

    1996-10-27

    Performance of a solar heating system with a hydrothermal source heat pump was evaluated and compared with that of a direct solar heating system. The sun-dependency rates ({Sigma}D and {Sigma}H)of the direct system and heat pump (HP)-provided system were expressed as a function of the rate ({alpha}) of the auxiliary heat against the collected heat and as a function of the performance coefficient and {alpha}, respectively. When the sun-dependency rates are compared, it is found that the HP-provided system is the more advantageous when {Sigma}H/{Sigma}D>1. The relationship between the {alpha}`s of the two systems was clarified and computation was performed to compare the sun-dependency rates on condition that the two are equal in the heat collecting area. Although the sun-dependence rate cannot be elevated to 100% in the HP-provided system, it achieves a sun-dependency rate higher than that of the direct system even when the heat collecting area is small. In cases where the building is economically limited, for instance, with respect to the area for solar collector installation, it is advantageous to employ the HP-provided system. 5 figs., 1 tab.

  8. Present conditions and future tasks of Japan`s ship machinery industry; Nihon hakuyo kogyo no genjo to kongo no kadai ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Akahoshi, S. [Ministry of Transportation, Tokyo (Japan)

    1994-09-01

    Although Japan`s shipbuilding industry has been maintaining a seat for the first place in the world over 30 years or more in a contract award quantity for the new shipbuilding work, Korea got ahead of Japan and has come to be a top at the first time in 1993. Even though the various factors could be thought, it has become a turning point to be reconsidered how Japan`s shipbuilding industry should be from now on for the naval architects and persons concerned in Japan. While Japan`s production of the maritime industrial products has been in general showing the recovering tendency by a demand restoration of the large scale vessels and so forth since 1987 afterward, on the other hand, affected by an influence of the recession of the world economic activities, the total production amount in 1993 has turned to a little bit decrease and its amount was 831.8 billion yen (a ratio to the previous year: 96.4%). Though a business environment surrounding the maritime industry, in order to successively continue the work shop site inside this country as an important industry through this industry from now on, it is thought that a restoration of the price competition should be made an effort on one hand by a standardization of the maritime equipments and tools making an exclusion of the wastefulness as an object, and a strengthening of the international competitiveness at the non-price aspects such as a functionality of the products, a reliability and so forth is indispensable on the other hand. 6 figs., 3 tabs.

  9. Observations and analysis of free groundwater levels and groundwater pressure in landslide slopes. Jisuberi shamen no jiyu chikasuii, chikasuiatsu no kansoku to kaiseki ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, S; Nakano, T [Niigata Univ., Niigata (Japan). Faculty of Agriculture; Inaba, K [Niigata Univ., Niigata (Japan). Graduate School; Sato, O [Niigata Univ., Niigata (Japan)

    1991-12-25

    It is well known that the landslides in Tertiary systems abundantly found in Niigata Prefecture, etc., frequently occur especially in the snow melting season or the heavy rain season. For studying the occurrence of such landslides, exploration of the actual condition of groundwater and evaluation of the strength of earth are very important even when the landslide occurring mechanism can be presumed in a relatively simple way about the soil mechanics. Therefore, great importance is attached to the observation and investigation on the groundwater level and pressure at landslide sites and stability analyses have been actively performed. However, it is considered that several fundamental problems still exist in the method for estimating the groundwater level and pressure in landslide slopes from the observation method and data on groundwater levels and pressure (pore pressure). In this paper, these fundamental problems are examined on the basis of concrete observations made by the writers on landslide slopes at Matunoyamagoe and Higashimusikame landslide sites in Niigata Prefecture for the past several years. 6 ref., 6 figs., 2 tabs.

  10. On the variations of strength of the CO sub 2 -silicate mould. CO sub 2 igata no kyodo henka ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Takano, Kenzo; Natori, Yoshikatsu; Suganuma, Sadao (Koei Co., Ltd., Saitama, (Japan) Nippon Chemical Industrial Co., Ltd., Tokyo, (Japan))

    1990-01-25

    Moulds prepared by uniform hardening were stored in normal foundry atmosphere and in the humidity controlled chamber to investigate properties of mould. Then, the relationship between the reaction rate of CO {sub 2} and Na {sub 2} 0 contained in mould binder and mould strength was studied. Followings were found: Turning point between absorption and desorption of mould exsits between 81-83% relative humidity (RH). Under the hith RH of the turning point or more, more the water glass addition, more the absorbed amount. When moulds were stored in the humidity controlled chamber, close relation was found between RH%, desorption or absorption rate and mould strength, that is, higher the desorption rate, higher the strength. Further, the reversible relationship was found between the strength and absorpion or desorption rate. Although any deterioration of strength was not found for moulds stored in the humidity controlled chamber (RH of 44-81%), moulds stored in normal foundry stmosphere lost the strength or deteriorated gradually. 7 refs., 11 figs., 2 tabs.

  11. Organic materials for semiconductor. Epoxy molding compound for IC encapsulation; Handotai kanren no yuki zairyo. Handotai fushiyo epoxy seikei zairyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kusuhara, A. [Sumitomo Bakelite Co. Ltd., Tokyo (Japan)

    1998-11-05

    This paper describes organic materials for semiconductor. Based on the composition and raw material, typical materials are epoxy resins, curing agents including phenol-novolak resins, fillers including silica and alumina, flame retardants including brominated epoxy resin and antimony oxide, hardening accelerators including amine compounds and phosphorus compounds, coupling agents including silane compounds and titanate compounds, and the others including colorants and mold lubricants. Raw materials are heated and kneaded after mixing, and produced as tablets after cooling and crushing. Recently, the packages have changed from insertion type to surface mounting type for the small thin IC package and for improving the efficiency of soldering during the incorporation of IC package on the print circuit substrate. High temperature of 260degC has been employed from the conventional limit of 100degC. Reduction of water absorption, improvement of adhesion, reduction of thermal expansion coefficient, and reduction of elastic modulus during heating are promoted for avoiding the peeling and cracking due to the sudden evaporation of adsorbed moisture. This paper also describes the organic materials for BGA. 10 figs., 4 tabs.

  12. International joint research of reforestation techniques for tropical rain forests in Indonesia; Indonesia tono nettairin saisei gijutsu no kyodo kenkyu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, T. [Kansai Electric Power Co. Inc., Osaka (Japan)

    1998-10-30

    The purposes of this research are to establish large-scale reforestation techniques, and to transfer these techniques into Indonesia for contributing to the preservation of tropical rain forests and the protection of global warming. Lauan trees provide disease and drying resistance properties by inoculating their roots with mycorrhizal fungi, to promote their growth. This is due to the symbiotic relationship between them, in which mycelia of mycorrhizal fungi collect and bring water and nutritive substances in the soil to the roots of lauan trees and intake sugars from the roots as nutrition. Since lauan trees are local variety, they are suitable for the preservation of biosystem. Since their growth life is long, they are suitable for the fixation of CO2. However, the reforestation techniques have not yet been established. Between FY 1992 and 1997, a high survival rate about 60% was obtained through a method in which natural seedlings in mountains were implanted and a method in which seeds were planted in the nursery. About 34000 lauan trees have been planted for the reforestation tests. An inoculation method was established for the accelerated growth of seedlings with mycorrhizal fungi. Through the inoculation, the growth rate was increased up to three times of that without inoculation. The lauan trees grew up to 5 m, and the survival rate was also increased up to twice. 11 figs., 3 tabs.

  13. Effects of air pollution on the health of regional inhabitants. Part I. Survey of disease state by Enquete. Taiki osen ga chiiki jumin no kenko ni oyobosu eikyo ni tsuite-dai ippo; anketo ni yoru shojo chosa

    Energy Technology Data Exchange (ETDEWEB)

    1973-01-01

    From May to July 1972, the disease states of 2096 inhabitants (710 men and 1386 women) in the Fukushima Ward of Osaka City, where the concentration of sulfur trioxide in the air was (yearly average) 1.81 mg/day/100 sq cm and that of carbon monoxide was 5.3 ppM, and that of nitrogen dioxide was 5.3 ppM, were surveyed. The number of persons surveyed was 2.9% of all the inhabitants of the Ward. Twenty-two point one percent were in their thirties, 20.1% in their forties, 16.5% in their sixties, and 15.3% in their fifties. Those who experienced chest diseases were 2.9% of the total, and those with heart diseases were 1.5%. Non-smoking men were 31.7% of the total. The percentage of long-term complaints of cough and sputum was 11.8% in the eastern section, 11.2% in the northern section, 10.0% in the southern section, 6.8% in the western section of the Ward. The frequency of complaints was highest in the sixties (12.7%), followed by 11.5% in the fifties, 11.3% in the thirties, and 8.6% in the forties. The frequency of complaints from men was 11.1% and that from women was 6%. The frequency of complaints was 19.8% in smokers, 8.5% in those who smoked less, and 6.8% in non-smokers. The frequency of complaints classified by residential area showed 12.6% in industrial areas, and 7.8% in residential and commercial areas. The frequency of complaints of inhabitants who live along National Road No. 2 was relatively high, ranging from 15.0 to 18.8%, and the frequency of complaints of inhabitants was apparently higher than those of people who only work in the Ward.

  14. Characteristic analysis of methane-gas generation by oxidizing heat of stored coal and hold ventilation control; Sekitan unpansen ni okeru sanka hatsunetsu ni yoru methane gas hassei to sonai kankyo seigyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Fukuchi, N; Nakashima, T [Kyushu Univ., Fukuoka (Japan); Kudo, S

    1999-12-31

    A demand of coal shows the tendency in the increase worldwide, with this, the marine transportation of the coal gradually increases, and the collier has also enlarged. The traffic pattern of coal is mainly the bulk transportation. In this transportation system, by the oxidation exothermic reaction of the coal, methane gas is produced, simultaneously the coal quality such as coking property or heat quantity is decreased and sometimes spontaneous ignition is caused. Therefore, it is necessary to equip with a ventilator to control the concentration of methane gas and to avoid the self heating of the coal. In this study, the quantity of methane-gas produced by heating coal using an electric furnace was measured and the experiment to investigate the temperature dependency of the methane-gas generated from the coal was conducted. By using the result of the measurement, the quantity of methane-gas produced from the coal stored in the hold of a coal cargo was estimated. And, the mathematical analyses on the changing degree depend on the times of a temperature in the hold under navigation, a concentration of oxygen and a concentration of methane-gas, were conducted. 11 refs., 19 figs., 2 tabs.

  15. Estimation of overprotection region on the painted steel plate under impressed-current cathodic protection. Gaibu dengenho ni yoru inkyoku boshoku ka no toso kohan ni okeru kaboshoku iki ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Iwata, M.; Huang, Y.; Fujimoto, Y. (Hiroshima Univ., hiroshima (Japan). Faculty of Engineering)

    1992-09-04

    Painting and cathodic protection are used in combination as a corrosion resisting measure for ship hull. n analytic method which uses the boundary element method for protection electric field by impressed-current method is proposed to show that rational determination is possible for the arrangement and current of the anode, and the arrangement and set voltage of the reference electrode used to control the current. However, repetitive calculation is necessary until overprotection voltage disappears from the surface of the painted steel plate while giving optional insulated area because the insulated area of adequate dimension is unknown. To decrease the number of this repetitive calculation, a study is made on a method of estimating the magnitude of the insulated area to be input as the initial value in the electric field analysis by the boundary element method. Although the insulated area has been empirically obtained, such formurization may be useful for automatic optimization using a computer of the location and number of anode, anode current, arrangement and set voltage of the reference electrode, magnitude of the insulated area, etc. in the impressed-current cathodic protection system. 2 refs., 10 figs., 1 tab.

  16. Relationship between the electric resistivity and the rain fall in discontinuity zone of rock slope by the continuous measurement; Renzoku tokei ni yoru ganban shamen no furenzokutaibu ni okeru mikake hiteiko henka to kou tono kankei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kusumi, H; Nishida, K [Kansai University, Osaka (Japan). Faculty of Engineering; Nakamura, M [Newjec Inc., Osaka (Japan)

    1996-10-01

    The relationship between change in resistivity and rainfall was studied by continuously measuring resistivities of fracture zone and stratum boundary along the measuring line of 95m long from the top to bottom of rock slope. The measurement field was located on a hill of 150-200m high at the northern part of Arima-Takatsuki tectonic line. Electrodes of 30m in maximum measuring depth were arranged at 289 points by dipole-dipole method. Resistivity was continuously measured at time intervals of 6 hours. Apparent resistivity was hardly affected by rainfall at points with less infiltration of stormwater from the ground surface, while it decreased by rainfall at points on fracture zone, stratum boundary or bleeding channel. The change rate of apparent resistivity could be approximated with the exponential function of rainfall. In such case, the apparent resistivity under most dried condition at the concerned point should be used as reference maximum apparent resistivity. The change rate of apparent resistivity due to rainfall in fracture zone reflects infiltration of stormwater, suggesting to be useful for disaster prevention of slopes. 5 refs., 6 figs.

  17. Actual conditions of energy management in office buildings; Results of quetionaire inquiry about load leveling. Gyomu yo biru ni okeru energy kanri no jittai ni tsuite; Fuka heijunka ni kakawaru anketo chosa kekka

    Energy Technology Data Exchange (ETDEWEB)

    Okubo, Katsuhiko (The Inst. of Applied Energy, Tokyo, (Japan))

    1989-07-20

    The electric power demand in Japan is increasing, and it is expected that annual load factor shows decreasing tendency. All electric power companies endeavor to improve load leveling than as it was, and intend to introduce direct saving system to control the loading equipments of consumers as well as indirect control such as midnight power system. Therefore, quetionaire inquiry about this new system was made for business power consumers in which power there are much difference in consumed power between day and night and much efficacy for power saving. As the results of the inquiry, it was understood that equipment of automatic or remote control for loading equipments were already introduced by many consumers and adoption of airconditioners controlled at every floor or every room is increased. So, about the control of the equipments in cosumers a method is also required so that electric power companies shall control the maximum demand by consumers and selection of control equipments are left on consumers' decision and judgment, and it is considered to be important that control by electric power companies shall not only turn on or off switchs but also realize convenience and economy of consumers. 9 figs., 3 tabs.

  18. Ni hombres ni mujeres providenciales

    OpenAIRE

    Montaño Virreira, Sonia

    2000-01-01

    Debo advertir a la y el lector de este texto que lo que a continuación se presenta no es, ni de lejos, una propuesta realista, si por ella entendemos la traducción, enclave mujer, de las actuales tendencias de liderazgo político vigentes en la región. Por el contrario, intento argumentaren favor de un liderazgo que supere el caudillismo como estilo y se aproxime al máximo hacia el respeto de las formas, entendiendo que sin ellas no es posible construir la democracia. Para hacerlo reviso rápid...

  19. FY 2000 report on the survey on global warming prevention measures in main E.U. countries; 2000 nendo EU shuyokoku ni okeru ondanka boshi taisaku no gaiyo ni tsuite hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    This report dealt with the background of energy policies in E.U. countries and energy plans. At COP3, E.U. countries internationally gave a pledge that they will reduce the emission of greenhouse effect gas 8% from that as of 1990 during 2008-2012, which is stricter than those given by Japan and the U.S. Actually, the European Commission made public 'Toward the European Climate Change Programme' and 'Green Paper on Emissions Trading in the E.U.' These are correspondent to E.U.' global warming preventive strategy which is called the twin track approach by the European Commission. The former is a frame for coordinating individual reduction measures taken under the responsibility of member countries as the whole E.U. As to the latter, for the specified sectors from energy supply sectors to large energy consumption industries, it was planned to be started in 2005. And, the basic policy on the trade and concrete subjects/problems on the trading system were arranged. (NEDO)

  20. Processing of the reflection seismic data which were acquired in the continental shelf off the north-west Australia; Australia hokusei tairikudana chiiki ni oite shutokusareta hanshaho chishitsu tansa data no shori ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Amano, H [Japan National Oil Corp., Tokyo (Japan)

    1996-05-01

    Reflection exploration of earthquakes was conducted in the continental shelf off the north-west Australia, and a report is made concerning the processing of the acquired data. A GI gun was used as the vibration source, and a wave quite similar to a pulse was generated. Hydrophones were arranged with group intervals of 12.5m, and high-resolution field data were acquired. An analog low cut filter was used to suppress the large-amplitude swell noise attributable to sea conditions. A digital filter was designed for the purpose of eliminating coherent noises from other survey ships. At the ultimate stage the f-k filter was applied to each of the shot records, and the effectiveness was verified. The traverse line was as long as 6700km and therefore the design window was set relatively long at 2.0-4.0s in the residual static correction phase. It was found that this setup is effective in improving the continuity of the reflection surface. 5 figs., 1 tab.

  1. Time domain electromagnetic method for petroleum exploration. Part 3. Case study in Yoneyama area; Sekiyu tansa ni okeru TDEM ho data shutoku to kaiseki ni tsuite. 3. Niigataken Yoneyama chiiki deno tekiyorei

    Energy Technology Data Exchange (ETDEWEB)

    Ishikawa, H; Mitsuhata, Y [Japan National Oil Corp., Tokyo (Japan); Shiga, N [Mitsui Mineral Development Engineering Co. Ltd., Tokyo (Japan)

    1996-05-01

    The result is reported of a TDEM method-based survey for oil exploration conducted in the Yoneyama district, Niigata Prefecture. The survey covered the southern part of the sedimentary basin in the prefecture, known for the poor quality of the seismic prospecting data that had been recorded. The purpose of the TDEM method-assisted survey was to probe the high-resistivity volcanic rock structure and low-resistivity sedimentary layer, and to know their details. The obtained data were subjected to interpretation by use of the 1D inversion method. A 4000m-deep level was subjected to interpretation, 34 data were inputted, and the early model consisted of 20 layers. As the result, it was found that there was a high-resistivity layer ranging from the ground surface down to a depth of approximately 500m, that a low-resistivity layer 2500-3000m in thickness lay thereunder, and that the lowest layer had a high resistivity of approximately 100 Ohm m. By comparing these data with the geological structure, structures were disclosed corresponding to the rock bed depth, Ukawa syncline, Ishiguro anticline, and Yoneyama mountain mass. 3 refs., 10 figs., 1 tab.

  2. How large-scale technological development should be in the future. Survey and research on highly automated machines; Kongo no daikibo gijutsu kaihatsu no hoko ni tsuite. Kodo jidoka kikai ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1982-03-01

    A survey is conducted about highly automated machines such as industrial robots. The task to be subjected to development as derived from a survey conducted about needs is the construction of a dangerous work robot. It is pointed out that work in coal mines, tall buildings, industrial complexes, or nuclear power plants may encounter large-scale accidents, and the task is how to perform such work in an automated way. The tasks concluded to be subjected to development after a seed survey analysis are categorized into three groups of element technologies, namely, sensors and recognition function, mechanism and materials, and control and data processing. These element technologies are to be ultimately integrated into a robot, for critical work which is a combination of a highly intelligent robot main body and an integrated management system. Since it will happen that humans have to directly operate such a robot under delicate conditions and share the burden of judgement and thinking, it is also necessary to develop technologies to solve problems of man-to-robot engineering. It is proposed that a dangerous work robot research and development program be established before development is started. (NEDO)

  3. Assessment of a Mega-Float on water quality and ecosystem in Tokyo bay; Choogata futaishiki kaiyo kozobutsu ga Tokyowan no suishitsu to seitaikei ni oyobosu eikyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kyozuka, Y.; Hu, C.; Hasemi, H. [Kyushu University, Fukuoka (Japan). Faculty of Engineering; Hikai, A.

    1997-08-01

    The effect on the marine environment in the bay when a Mega-Float is installed in a bay was investigated. The physical process such as a residual flow (including tidal currents, water temperature, salt, density, and density currents), and the ecosystem model for which floating organic matter and plankton are handled were incorporated to develop a program for water quality calculation in a bay. The program was used for Tokyo Bay and compared with the conventional calculation result and the oceanograhpic observation result. Simultaneously, the effect on the Mega-Float was considered. On the flow in Tokyo Bay in summer, the calculation result that comparatively coincided with the observation value in a residual flow level was obtained. The horizontal distribution of COD comparatively coincides with the existing observation result. The influence that the Mega-Float exerts on the flow, water temperature, water quality, and ecosystem in the ambient sea area was little and local in the calculation scale (L {times} B {times} d = 6 km {times} 3 km {times} 2 m) of this time. However, the difference occurring due to the design position must also be investigated in future. 12 refs., 8 figs., 5 tabs.

  4. FY 2000 report on the survey on global warming prevention measures in main E.U. countries; 2000 nendo EU shuyokoku ni okeru ondanka boshi taisaku no gaiyo ni tsuite hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    This report dealt with the background of energy policies in E.U. countries and energy plans. At COP3, E.U. countries internationally gave a pledge that they will reduce the emission of greenhouse effect gas 8% from that as of 1990 during 2008-2012, which is stricter than those given by Japan and the U.S. Actually, the European Commission made public 'Toward the European Climate Change Programme' and 'Green Paper on Emissions Trading in the E.U.' These are correspondent to E.U.' global warming preventive strategy which is called the twin track approach by the European Commission. The former is a frame for coordinating individual reduction measures taken under the responsibility of member countries as the whole E.U. As to the latter, for the specified sectors from energy supply sectors to large energy consumption industries, it was planned to be started in 2005. And, the basic policy on the trade and concrete subjects/problems on the trading system were arranged. (NEDO)

  5. Relation between front suspension layout and handling performance. Analysis depending on the Taguchi method and ADAMS; Front suspension layout to soda tokusei no kankei ni tsuite. Kiko kaiseki gengo wo mochiita hinshitsu kogaku ni yoru kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Okada, K [Daihatsu Motor Co. Ltd., Osaka (Japan)

    1997-10-01

    A variation of suspension layout gives an influence to the vehicle dynamics. Examined the suspension layout variation to make the handling performance change small. Analyzed the effect of suspension layout variation about steering response delay and gain besides the tire wear effect and movable load. 3 refs., 12 figs., 4 tabs.

  6. Estimation of the crack growth mechanism in the coking process. ; Behavior of fracture mechanics parameter. Cokes sonai kiretsu shinten ni kansuru ichikosatsu. ; Hakai rikigaku parameter no kyodo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Yoshino, H; Sato, H; Nogami, H; Miura, T [Tohoku University, Sendai (Japan). Faculty of Engineering

    1991-07-10

    Cracks generated in coke layers during a coking furnace operation are an important factor not only to decide quality of the product, but also govern the energy consumption affecting the heat transfer and material transfer. This paper describes estimations of thermal stress and observations to fracture mechanics parameters, applying the incremental theory to surface cracks seen in the initial stage of carbonization. As a result of calculations using the crack tip opening displacement (CTOD) as a parameter to evaluate displacement in the vicinity of crack tips, the values increased with the increasing heating rate, and agreed qualitatively with the trend found in the experiments. The CTOD relates closely to the temperature dependence of the contraction coefficient, and varies largely at the transition point from the first maximum point to the second maximum point, from which the surface cracks are predicted to have been generated in this temperature region. Also, an estimation was made on the stress expansion coefficient from the stress distribution, and a result that can explain the experimental resultswas obtained. 10 refs., 11 figs.

  7. Experimental study of gas combustion fluidized bed and radiation contribution to heat transfer inside the bed. Gas nensho ryudoso to sono sonai netsudentatsu ni okeru fukusha no kiyo ni tsuite no jikkenteki kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Yamada, Y; Takahashi, S [Mechanical Engineering Lab., Tsukuba, Ibaraki (Japan); Maki, H [Science Univ. of Tokyo, Noda, Chiba (Japan). Faculty of Science and Technology

    1992-11-25

    Fluidized bed as a coal combustion boiler has a practical application, but, there is not an example of which gas like helium as a cooling medium flow in a thin tube with diameter of 6 mm like a stirling engine and necessary data for selecting the medium of fluidized bed and estimating the heat transfer coefficient. Specially, it is difficult to correctly estimate the radiation effect concerned with the heat transfer coefficient in case of interposing the heat transfer tube at 800 [degree]C in the high-temperature fluidized bed at more than 900 [degree]C. Therefore, for investigating the thermal characteristics when the temperature of pipe itself is at high temperature, in the gas combustion fluidized bed in which alumina particle as fluidized medium is filled, the cooling tubes by using carbonic acid gas as a cooling medium was interposed, heat transfer coefficient was measured, radiation effect was clarified by experiment, and characteristics of the gas combustion and of the exhaust gas of fluidized bed when gas is used for a fuel was investigated. 13 refs., 12 figs., 1 tab.

  8. Electrolyte loss mechanism of molten carbonate fuel cells. 2.; Application to the cell with matrix electrolyte layer; Yoyu tansan`engata nenryo denchi ni okeru denkaishitsu loss kiko ni tsuite. 2.; Matrix gata denkaishitsuso wo yusuru denchi eno oyo

    Energy Technology Data Exchange (ETDEWEB)

    Sonai, A; Murata, K [Toshiba Research and Development Center, Kawasaki (Japan)

    1993-11-01

    A single cell of molten carbonate fuel cell using a matrix electrolyte layer fabricated by using the doctor blade process has been operated for several thousand hours, measured of electrolyte loss amount, and analyzed by using a new electrolyte loss mechanism. The result may be summarized as follows: according to a result of measuring the matrix layer pore distribution, the average pore size has increased little by little; pores with diameters greater than 2 {mu}m at which no electrolyte retention becomes possible remain at nearly constant ratio up to 1800 hours, but increased after 2500 hours; the pore capacity in ports with the largest electrolyte retaining diameter of 2 {mu}m or less showed slight decrease with time in the anode, and an initial decrease followed by flatness, and then a sharp decrease after 1800 hours in the matrix layer; the electrolyte loss measurement values have remained nearly constant for 25 hours to 1800 hours, but increased sharply thereafter; and the electrolyte loss in this single cell due to pore capacity decrease in pores as power generating parts with diameters smaller than 2 {mu}m was explained quantitatively by a new electrolyte loss mechanism. 11 refs., 6 figs.

  9. Estimation of a subsurface structure by using shallow seismic engineering exploration system with multiple function (SWS); Takino danseiha tansa sochi (SWS) ni yoru senbu chika kozo tansa ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Y [Beijing Shuidian Research Institute of Geophysical Surveying, Beijing (China); Ling, S [Nihon Nessui Corp., Tokyo (Japan); Okada, H [Hokkaido University, Sapporo (Japan)

    1997-10-22

    The Beijing Shuidian Research Institute of Geophysical Surveying has performed ocean seismic exploration in the area where the Fujian Pingtan bridge was planned to be constructed. The elastic wave exploration device is of a multi-functional type. The device has functions of acquiring, processing and analyzing data in seismic exploration using the reflection method, and can visualize subsurface conditions at the same time as performing the exploration. The planned bridge building area spans over a sea area of about 3500 m long with water depths from several meters to 30 meters. The foundation bed consists of dacite lithologic tuff and granodiorite. The seal level varies from 4.0 m to 4.8 m between high and low tides. According to the result of other measurements, the elastic wave propagation velocities of the sea water were found from 1475 to 1485 m/s, and the elastic wave propagation velocities at the surface bed of the sea bottom were from 1550 to 1700 m/s. The exploration used a workboat which moves at a constant speed while maintaining the offset between a transmitting source and a receiving source constant, executing vibration transmitting, receiving and recording all on the sea. The result of the exploration revealed that neither obstacles such as sunken ships nor marks of occurrence of ocean bottom landslides were present. 1 ref., 5 figs.

  10. High-fidelity simulation of turbofan engine. ; Verification and improvement of model's dynamical characteristics in linear operating range. Turbofan engine no koseito simulation. ; Senkei sado han'i ni okeru model dotokusei no kensho to seido kojo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Yamane, H; Kagiyama, S [Defence Agency, Tokyo (Japan)

    1993-09-25

    This paper describes providing pulse inputs to a fuel supply in trial operation of a turbofan engine, measurement of its response, and calculation of the frequency characteristics and time constants to acquire dynamic characteristics of the engine on the ground. The resultant engine characteristics were compared with the model characteristics of numerically analyzing a mathematical simulation model, and corrected to develop a high-accuracy simulation model. An element model and a dynamics model were prepared in detail on the main engine components, such as fans, a compressor, a combustor, and a turbine, along a flow diagram from the air intake opening to the exhaust nozzle. The pulses were inputted into the fuel supply by opening and closing an electromagnetic valve. Closing of the illustrated electromagnetic valve for about 0.7 second caused a difference (of phase and trend) in both characteristics of high and low frequencies as a result of pulse-like change in the flow rate. To correct the model characteristics, the combustion delay tie was set to 0.02 second upon considering the combustion delay time relative to the heat capacity of the combustor. Improvement in the model was verified as the phase characteristics was approximated to the engine characteristics. 13 refs., 17 figs., 2 tabs.

  11. FY 1997 report of survey on the intellectual property in international collaboration research project; 1997 nendo chosa hokokusho (kokusai kyodo kenkyu ni okeru chiteki zaisanken ni tsuite no chosa hokokusho)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In promoting international collaboration research project, coordination of the patent system of each country which participants to the project belong to has broad implications in concluding the contract for the project. For example, in Japan, 100% of the patent belongs to the government for contrast or collaboration project with the government. While, in the USA, the patent developed by the private company belongs to the private company even for the contrast project. In Japan, the shared patent can not be transferred to the third party or implemented without agreement with the partner. While, in the USA, the shared patent can be transferred to the third party or implemented without agreement with the partner. Due to such a difference, some projects can not be established by ill coordination of intellectual property even when the meaning of the projects is well understood. In this survey, was investigated the outline of patent systems of major countries to study about what should well balanced treatment of intellectual property in international collaboration research project be in the future. 4 figs., 8 tabs.

  12. On the hydroelastic response of box-shaped floating structure with shallow draft. Tank test with large scale model; Senkitsusui hakogata futai no harochu dansei oto ni tsuite. Ogata mokei ni yoru suiso shiken

    Energy Technology Data Exchange (ETDEWEB)

    Yago, K; Endo, H [Ship Research Inst., Tokyo (Japan)

    1997-12-31

    The hydroelastic response test was carried out in waves using an approximately 10m long large model, and the numerical analysis was done by the direct method, for a commercial-size (300m long) box-shaped floating structure with shallow draft. The scale ratio of the model is 1/30.8, and the minimum wave cycle is around 0.7s from wave-making capacity of the tank, which corresponds to 4 to 14s with the commercial-size structure. Elastic displacement and bending strain were measured. The calculated results by the direct method are in good agreement with the observed results. The fluid dynamic mutual interference effects between elements are weak in added mass but strong in damping force, indicating that the range of mutual interference is strongly related to rolling cycle in the range of mutual interference. Wave pressure on the floating structure bottom is high at the upper side of the wave, greatly damping towards the downside of the wave. However, response amplitude of elastic displacement tends to increase at the ends, both in upside and downside of the wave. For the floating structure studied, the 0 to 4th mode components are predominant in longitudinal waves, and the 6th or higher mode components are negligibly low. 21 refs., 15 figs., 2 tabs.

  13. Measurement method of a motion of traveling vehicle via three-dimensional image processing system; Sanjigen gazo kaisekiho ni yoru sharyo undo no keisoku to sono bunseki ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Yamada, Y; Matsuura, Y [Osaka Sangyo University, Osaka (Japan)

    1997-10-01

    Motion of traveling vehicle was taken by VTR-cameras set on the test course, as well as it also was measured by conventional measurement methods using sensors and devices installed in the vehicle. lotion pictures of the VTR were analyzed using three-dimensional image processing system (Peak lotus system). As a result, this system was especially effective for the measurement of traveling traces of the actual vehicle and the results were good agreement with the data obtained by conventional measurement methods. 2 refs., 8 figs.

  14. FY 2000 report on the survey on the global warming prevention measures in the U.S.; 2000 nendo Beikoku ni okeru ondanka boshi taisaku no gaiyo ni tsuite hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The results of the overseas survey were summed up mostly of global warming prevention measures taken by the U.S. government and those by private companies. At COP3 in 1997, the U.S. gave a pledge internationally that they would reduce greenhouse effect gas emissions during 2008-2012 7% below from that in 1990. But the U.S. government seems hesitating to take concrete measures in regions. Hesitating, however, they are publicly making it a target to find how to eliminate a risk of global warming which is now a global problem in cooperation with other countries and international organizations. Concretely, programs are as follows: ranking of the energy consumption amount of household electric appliances, housing loan programs taking energy efficiency into account, preferential taxing system, incentive money system in case of using the substituting energy transportation program, waste management program, commendation of men of achievements and prize-winning, etc. (NEDO)

  15. Computation accuracy of flow conditions around a very large floating structure using a multi-layer model. Comparison with experimental results; Taso model ni yoru choogata futai mawari no ryukyo keisan seido ni tsuite. Jikken tono hikaku

    Energy Technology Data Exchange (ETDEWEB)

    Kyotsuka, Y [Kyushu University, Fukuoka (Japan); Omori, H; Nakagawa, H; Kobayashi, M [Mitsui Engineering and Shipbuilding Co. Ltd., Tokyo (Japan)

    1996-04-10

    As one of the environmental problems in sea areas surrounding a very large floating structure (VLFS), change in flow condition is important, and it is one of the factors dominating the prediction of succeeding diffusion and ecosystems. Although a multi-layer model is in wide use for computation of flow condition and diffusion in one inner bay, its applicability should be reexamined because of no consideration of VLFSs. In this study, flow velocity profiles around a barge were then measured through the towing test of a barge in shallow water, and compared with computation results using a multi-layer model. The multi-layer model computed the flow velocity profiles by dividing the flow region to be computed into normal one and that under VLFS, and determined pressures under VLFS by 2-D Poisson`s equation. Slip condition was used as boundary condition at the bottom considering the number of layers under VLFS. Further numerical computation was conducted by 2-D MAC method, in particular, to compare flow around the wake of VLFS with experimental one. Both computation results well agreed with experimental one. 3 refs., 9 figs., 1 tab.

  16. On the calculation of scattered fields by 3-D structure in the time-domain electromagnetic (TDEM) method; Jikan ryoiki denjiho ni okeru sanjigen kozo kara no sanranba no keisan ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Murakami, Y [Geological Survey of Japan, Tsukuba (Japan); Saito, A; Oya, T [Mitsui Mineral Development Engineering Co. Ltd., Tokyo (Japan)

    1996-10-01

    This paper describes the calculation method of 3-D underground structures in TDME method which measures only field components. Recently, FDTD method was developed as calculation method in time domain difference calculus, and the forward analysis accuracy of 3-D fields was rapidly improved. The survey results using a large-scale loop (600m{times}360m) were numerically analyzed by FDTD method. 16 measuring lines were prepared in both X and Y directions, and measuring points were prepared on intersection points of the measuring lines. Since signal current is staircase one, step and impulse responses of the ground were determined by calculating magnetic field and its time differentiation. The rectangular body (120m{times}120m{times}100m) of 0.2S/m in conductivity (5 ohm m in resistivity) was installed 160m under the ground as 3-D resistivity anomaly. The ground of 0.01S/m (100 ohm m) was assumed. Time variation in horizontal magnetic field vector plot of impulse responses of the uniform ground could be observed. The position of the resistivity anomaly could be also determined from spacial differentiation of magnetic field of grid pattern measuring points. 1 ref., 6 figs.

  17. Engineering characteristics of the improved soil by deep mixing method using coal ash; Sekitanbai wo riyoshita FGC shinso kongo shori koho ni yoru kairyodo no kogakuteki seishitsu to kongo no tenbo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, T [Center for Coal Utilization, Japan, Tokyo (Japan); Azuma, K; Watanabe, M [Electric Power Development Co. Ltd., Tokyo (Japan)

    1996-09-01

    Japan currently produces about six million tons of coal ash annually, whose effective bulk utilization to earth engineering materials is an important issue of technological development. A slurry may be made by mixing the following three kinds of materials: fly ash discharged from power plants exclusively burning dust coal (F), gypsum generated as a by-product in a stack gas desulfurizing process (G), and commercially available cement (C). The slurry would be called an FGC slurry taking the first letters of the materials. This paper presents the results of laboratory tests, in-situ execution tests and centrifuge model testing on engineering characteristics of soils improved by the FGC slurry when the slurry is applied to implementing the deep mixing method. As a result, a large number of findings were obtained including the following matters: the FGC deep mixing method makes it possible to improve ground beds having small deformation coefficient with the same accuracy as in the cement-based deep mixing (CDM) method at strengths lower than 5 kg/cm {sup 2} which is difficult with the CDM method, not to speak of strengths equivalent to that is possible with the normal CDM method; and development of a ground bed with improved strength is possible without being governed by quality and kinds of the fly ash. 1 ref., 23 figs., 5 tabs.

  18. Estimation of subsurface structures in a Minami Noshiro 3D seismic survey region by seismic-array observations of microtremors; Minami Noshiro sanjigen jishin tansa kuikinai no hyoso kozo ni tsuite. Bido no array kansoku ni yoru suitei

    Energy Technology Data Exchange (ETDEWEB)

    Okada, H; Ling, S; Ishikawa, K [Hokkaido University, Sapporo (Japan); Tsuburaya, Y; Minegishi, M [Japan National Oil Corp., Tokyo (Japan). Technology Research Center

    1997-05-27

    Japan National Oil Corporation Technology Research Center has carried out experiments on the three-dimensional seismic survey method which is regarded as an effective means for petroleum exploration. The experiments were conducted at the Minami Noshiro area in Akita Prefecture. Seismometer arrays were developed in radii of 30 to 300 m at seven points in the three-dimensional seismic exploration region to observe microtremors. The purpose is to estimate S-wave velocities from the ground surface to the foundation by using surface waves included in microtremors. Estimation of the surface bed structure is also included in the purpose since this is indispensable in seismic exploration using the reflection method. This paper reports results of the microtremor observations and the estimation on S-wave velocities (microtremor exploration). One or two kinds of arrays with different sizes composed of seven observation points per area were developed to observe microtremors independently. The important point in the result obtained in the present experiments is that a low velocity bed suggesting existence of faults was estimated. It will be necessary to repeat experiments and observations in the future to verify whether this microtremor exploration method has that much of exploration capability. For the time being, however, interest is addressed to considerations on comparison with the result of 3D experiments using the reflection method. 4 refs., 7 figs.

  19. On the hydroelastic response of box-shaped floating structure with shallow draft. Tank test with large scale model; Senkitsusui hakogata futai no harochu dansei oto ni tsuite. Ogata mokei ni yoru suiso shiken

    Energy Technology Data Exchange (ETDEWEB)

    Yago, K.; Endo, H. [Ship Research Inst., Tokyo (Japan)

    1996-12-31

    The hydroelastic response test was carried out in waves using an approximately 10m long large model, and the numerical analysis was done by the direct method, for a commercial-size (300m long) box-shaped floating structure with shallow draft. The scale ratio of the model is 1/30.8, and the minimum wave cycle is around 0.7s from wave-making capacity of the tank, which corresponds to 4 to 14s with the commercial-size structure. Elastic displacement and bending strain were measured. The calculated results by the direct method are in good agreement with the observed results. The fluid dynamic mutual interference effects between elements are weak in added mass but strong in damping force, indicating that the range of mutual interference is strongly related to rolling cycle in the range of mutual interference. Wave pressure on the floating structure bottom is high at the upper side of the wave, greatly damping towards the downside of the wave. However, response amplitude of elastic displacement tends to increase at the ends, both in upside and downside of the wave. For the floating structure studied, the 0 to 4th mode components are predominant in longitudinal waves, and the 6th or higher mode components are negligibly low. 21 refs., 15 figs., 2 tabs.

  20. FY 1997 report on the research study for preparation of NEDO`s vision. Biomass energy; 1997 nendo chosa hokokusho (NEDO vision sakutei ni muketa chosa kenkyu). Biomass energy ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Research study was made on the current usage, technological development and future subjects of biomass energy. The current use of biomass energy over the world estimated to be nearly a billion t/y oil equivalent. This value is estimated to be only a part of a pure primary biomass yield of 73 billion t/y oil equivalent showing a large supply potential. The evaluation result of a biomass energy potential in the world by GLUE (Global Land Use and Energy Model) considering worldwide biomass flow and competition of land use showed that no change of land use form in advanced areas is predicted, and no production of new biomass energy from forests in advancing areas is also expected. Production of biomass energy from farm products is promising in advanced areas, while the potential of biomass residue is high in advancing areas showing the possibility of energy development. Development of new biotechnologies such as molecular control of bio-production functions is expected to increase biomass resources. 76 refs., 26 figs., 30 tabs.

  1. Survey report for fiscal 1998. Evaluation by industrial circles of the COP3 outcome and their future response (America); 1998 nendo chosa hokokusho. COP3 no kekka ni taisuru sangyokai no hyoka oyobi kongo no taio ni tsuite (Beikoku)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Response in America to COP3 (Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change) is investigated. Office of Energy Efficiency and Renewable Energy (EE) of America's Department of Energy conducts activities designed to protect environments and supports America's economic competitiveness. The scope of EE activities is quite wide, covering efforts at energy efficiency improvement and renewal energy utilization for all energy consuming sectors involving construction work and equipment for buildings, various industries and public utility works, and transportation. EE also supports and promotes the development of advanced industrial materials, electric vehicles, hybrid vehicles, fuel cells, etc. In the field of renewable energy, it deals with the exploitation of sunlight, biomass, wind force, water power, geothermal energy, etc. It also supports efficiency improvement efforts being undertaken through studies of advanced power transmission and distribution, high-temperature superconduction, energy storage, etc. The said supports are provided not only by Federal Government but also by state governments, and include financial aids. A number of programs are under way, worked out and promoted by the respective bureaus and departments. They are evaluated, protected, and implemented through the partnership of official and civilian organizations. (NEDO)

  2. Result of comparative experiment on environmental comfort in room using hot heat environment testing unit. Onnetsu kankyo shiken unit ni yoru shitsunai kankyo no kaitekisa no hikaku jikken kekka ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Fujiwara, T; Kawashima, K [The Hokkaido Electric Power Co. Inc., Sapporo (Japan)

    1991-11-20

    Measurements were carried out on three buildings having different heat insulation, airtightness and heat capacity for testing the hot heast enviroments (having a room size of about 4.6 m{times}3.7m{times}2.3 m) as to the temperature differences between the upper and lower parts of the room and the MRT (mean radiation temperature, representing the temperature of radiation from the wall face). These are compared according to types of heating appliance. The result is summarize as follows: The temperature difference in the upper and lower parts is affected largely by the airtightness of the building, the difference being capable of getting reduced by rasing the airtightness even in a buildings low in heat insulation. In a building with low airtightness, type of heating appliance and its installation location affect the temperature difference. The MRT is determined determined nearly completely by the heat insulation of the wall face in a room, but it tends to be affected easily by the specification and area of windows. A floor heating system increases the MRT and generates very little difference in temperatures in the upper and lower parts of the room. A comparison using a PMV (one of the indexes for enviromental comfort in a room) was also conducted. 12 figs., 7tabs.

  3. Experimental investigation on wake galloping appeared in tandem cables of cable-stayed bridges subjected to wind in skewed direction; Normal narabini dimple tsuki heiretsu cable ni senpu ga sayoshita baai no wake galloping tokusei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Yoneda, M.; Miyachi, S.; Edamoto, K.; Mochizuki, H.; Setouchi, H. [Kawada Industries Inc., Tokyo (Japan)

    1996-03-20

    Concerning the smooth surface and dimpled surface cables, experiments were conducted to investigate relationship between their wake galloping characteristics and aerostatic force characteristics they demonstrate when exposed to wind blowing in a skewed direction. The wind tunnel used for the experiment was a closed type measuring wind tunnel, 2.0m wide, 2.5m high, and 15.0m long. In the wind tunnel, two cables were arranged with the distance between the cable centers three times as large as the cable diameter D, and with relative vertical difference of 0.25-0.50D, and spring-supported experiments for evaluating wake galloping characteristics and aerostatic force coefficient determining experiments were carried out. It was deemed as the result that turbulence exerts influence on the wake galloping characteristics of the dimpled surface cable more than on those of the smooth surface cable, that on a real bridge the effect of turbulence may be expected in case of exposure to natural wind of turbulence with intensity higher than 5-7%, and that therefore application of some damping by dampers will adequately damp wake galloping even in case of the 0.37D vertical difference. 12 refs., 23 figs.

  4. Decay of 57Ni

    International Nuclear Information System (INIS)

    Santos Scardino, A.M. dos.

    1987-01-01

    The decay of 57 Ni to 57 Co was studied by gamma ray spectroscopy using both singles and coincidence spectra. The sources were obtained with the 58 Ni (Y,n) 57 Ni reaction. Natural metallic nickel was irradiated in the bremsstrahluhng beam of the linear accelerator of the Instituto de Fisica da Universidade de Sao Paulo with 30 MeV electrons. The singles espectra were taken with 104 cc HPGe detector and the coincidences espectra with 27 and 53cc Ge(Li) and 104 cc. HPGe detectors. The energies of transitions that follow the 57 Ni decay were measured using 56 Co as standard (which was obtained by (Y,np) reaction in 58 Ni) and taking into account the cascade cross-over relations. (author) [pt

  5. Bridging exchange bias effect in NiO and Ni(core)@NiO(shell) nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Rinaldi-Montes, Natalia, E-mail: nataliarin@gmail.com [Departamento de Física, Universidad de Oviedo, E-33007 Oviedo (Spain); Gorria, Pedro [Departamento de Física & IUTA, EPI, Universidad de Oviedo, E-33203 Gijón (Spain); Martínez-Blanco, David [Servicios Científico-Técnicos, Universidad de Oviedo, E-33006 Oviedo (Spain); Fuertes, Antonio B. [Instituto Nacional del Carbón, CSIC, E-33080 Oviedo (Spain); Fernández Barquín, Luis [CITIMAC, Facultad de Ciencias, Universidad de Cantabria, E-39005 Santander (Spain); Puente-Orench, Inés [Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza and Institut Laue-Langevin, BP 156, F-38042 Grenoble Cedex 9 (France); Blanco, Jesús A. [Departamento de Física, Universidad de Oviedo, E-33007 Oviedo (Spain)

    2016-02-15

    Among all bi-magnetic core(transition metal)@shell(transition metal oxide) nanoparticles (NPs), Ni@NiO ones show an onset temperature for the exchange bias (EB) effect far below the Néel temperature of bulk antiferromagnetic NiO. In this framework, the role played by the magnetism of NiO at the nanoscale is investigated by comparing the microstructure and magnetic properties of NiO and Ni@NiO NPs. With the aim of bridging the two systems, the diameter of the NiO NPs (~4 nm) is chosen to be comparable to the shell thickness of Ni@NiO ones (~2 nm). The EB effect in Ni@NiO NPs is attributed to the exchange coupling between the core and the shell, with an interfacial exchange energy of ΔE~0.06 erg cm{sup −2}, thus comparable to previous reports on Ni/NiO interfaces both in thin film and NP morphologies. In contrast, the EB detected in NiO NPs is explained in a picture where uncompensated spins located on a magnetically disordered surface shell are exchange coupled to the antiferromagnetic core. In all the studied NPs, the variation of the EB field as a function of temperature is described according to a negative exponential law with a similar decay constant, yielding a vanishing EB effect around T~40–50 K. In addition, the onset temperature for the EB effect in both NiO and Ni@NiO NPs seems to follow a universal dependence with the NiO crystallite size. - Highlights: • Comparison of the exchange bias effect in NiO and Ni(core)@NiO(shell) nanoparticles. • Universal temperature dependence of the exchange bias effect. • Suggested similar physical origin of the effect in both systems. • Size and crystallinity of the NiO shell hold the key for exchange bias properties.

  6. OpenNI cookbook

    CERN Document Server

    Falahati, Soroush

    2013-01-01

    This is a Cookbook with plenty of practical recipes enriched with explained code and relevant screenshots to ease your learning curve. If you are a beginner or a professional in NIUI and want to write serious applications or games, then this book is for you. Even OpenNI 1 and OpenNI 1.x programmers who want to move to new versions of OpenNI can use this book as a starting point. This book uses C++ as the primary language but there are some examples in C# and Java too, so you need to have about a basic working knowledge of C or C++ for most cases.

  7. Fiscal 1992 survey report. Promotion of coal importing base buildup (How ocean freight system should be in the future); 1992 nendo kaigaitan yunyu kiban seibi sokushin chosa. Kongo no gaiko yuso taisei no arikata ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-03-01

    When a general view is taken of coal chains that connect overseas coal suppliers to Japan's end users, it is found that no survey has ever been made to sufficiently explain marine transportation of coal. It is now expected that the gap between supply of and demand for shipping tonnage will widen thanks to a sharp increase supposed to emerge in the demand for overseas coal in the future and that a scarcity of tonnage will impede stable space securing for coal and economically viable coal transportation. Such being the case, this project aims to investigate the ocean freight systems to serve between overseas coal shipping ports and Japan's coal receiving bases and the current states and problems of cargo facilities in Japan, to study how to build up a shipping space securing system which will properly deal with an increase in the import of steam coal from abroad, and to contribute to the formation of measures for enabling smooth transportation of coal from overseas. The survey conducted for this purpose covers the present conditions of Japan's ocean freight systems and of its coal receiving bases, present conditions of transportation by oceangoing ships in the Pacific basin, compilation of a list of oceangoing ships, prediction of ocean freight transportation and supply of transportation service, prediction of ocean freight cost in the future, and putting in an easy-to-review order the tasks to be accomplished for the enhancement of coal transportation by oceangoing ships. (NEDO)

  8. Effect of deep structure and surface layer (a) simulation study on the heavy damage belt of the 1995 Hyogoken Nanbu earthquake; Hado simulation wo mochiita `shinsai no obi` ni tsuite no kento

    Energy Technology Data Exchange (ETDEWEB)

    Feng, S; Ishikawa, K; Kaji, Y [Chuokaihatsu Corp., Tokyo (Japan)

    1996-05-01

    A simulation study was done to identify the causes for the so-called heavy damage belt observed as a result of the Hyogoken Nanbu Earthquake. This study determines distributions of the maximum amplitudes on the ground surfaces, and discusses the effects of deep structures and low-velocity surface layers, based on the simulation by the wave equation with the underground model of Higashinada-ku and its vicinity in the north-south direction, observed seismic records and artificial waves. The two-dimensional scalar wave equation is used for the analysis. The velocity structure model used for the simulation is established, based on the elastic wave seismic survey results. The focus function is drawn by expanding or contracting the time scale, using the seismic records at Kobe Port Island and artificial waves. The analysis results show that the damage belt coincides with the areas at which the focusing zone of the deep structure overlap the amplification zone in the low-velocity ground surfaces, where relative density is amplified 1.5 to 2 times. It is also observed that large peaks repeat 2 to 3 times on the time scale. 5 refs., 8 figs., 1 tab.

  9. On the fault system and basement structure in and around the epicentral region of the 1995 Hyogo-ken Nanbu earthquake; 1995 nen Hyogoken nanbu jishin shingen shuhen no danso kiso kozo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Yokokura, T; Kano, N; Yamaguchi, K; Miyazaki, T [Geological Survey of Japan, Tsukuba (Japan); Ikawa, T; Ota, Y; Kawanaka, T [Japex Jeoscience Institute, Tokyo (Japan)

    1996-05-01

    A reflection elastic wave seismic survey was carried out as part of the emergency survey of active faults in relation with the Hyogo-ken Nanbu Earthquake. This paper presents an interim report on the survey covering a wide area with deep structure as the survey object. The paper mentions that processing the survey data has been nearly completed, and is in the stage of making analyses and interpretations of the result of the processing, and that the survey was an attempt of making a unified survey over land areas, shallow sea areas, and seas by setting twelve traverse lines in and around the epicenter region. The paper also introduces briefly what has been found on hypocenters used, vibration receivers, vibration intervals, and CPD intervals, and on shapes of faults, particularly the continuity (the relationship of the Ashiya fault, Koyo fault and Osaka bay fault with the above two faults, branching of the Osaka bay fault, faults between the Wada promontory fault, Awaji Island and the Osaka bay fault, the fault off the east coast at the central part of Awaji Island, the Shichiku fault on the west coast of Awaji Island, and the basement fault). Mention is given also on the basement structure chart of the Osaka bay prepared preliminarily for the purpose of reference. 2 figs.

  10. Runoff characteristics of water quality from small agricultural watershed having topographical chain and irrigation; Chikei rensa to suiden kangai wo yusuru nogyo shoshu suiiki kara ryushutsusuru suishitsu no tokucho ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Nakasone, H; Kuroda, H; Kubota, K [Ibaraki University, Ibaraki (Japan). School of Agriculture

    1996-01-10

    An investigation was carried out on characteristics of concentration and load amount of water flowing out from a small watershed with an area of 205 ha which is utilized mostly for agriculture. The basin subjected to the investigation was a district with typical tableland topography in Dejima Village in Ibaraki Prefecture. The land on this tableland in the district is utilized mainly for a truck farm, raising mainly vegetables and fruit trees. However, dry rice fields, which were converted from the truck farms into irrigated rice fields, exist on the tableland in this district. It is known that the dry rice fields have as high water permeability as inconceivable in ordinary paddy rice fields. Paddy fields developing below the tableland are called valley paddy fields, which are ill-drained paddy fields having small downward water permeation. It is an interesting subject to know what effects are given on the quality of runoff water by the topography in this watershed that has such a specific topographical chain as described. Furthermore, the dry rice fields are irrigated from the Dejima water canal taking water from Kasumigaura Lake, whereas large effects are anticipated on the amounts of runoff water and load because of such a large water permeation amount. This paper discusses the characteristics in amounts of runoff water and load in such a watershed as described. 20 refs., 17 figs., 2 tabs.

  11. Spread of `Eco-vendor`, an energy-saving type automatic vending machine for beverages with a peak cut function; Shoenegata seiryo inryoyo jido hanbaiki (peak cut kino tsuki) `eko benda` no fukyu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-05-01

    `Eco-vendor`, an energy-saving type automatic vending machine for beverages with a peak cut function has been developed in 1995 through cooperation by Tokyo Electric Power Company, Coca-Cola Japan, and Fuji Electric Co., Ltd. It can cut 90 percent of the power consumption during 13:00 to 16:00 on weekdays in summer, and can save 10 to 15 percent of annual power consumption. Since the heat insulation performance has been improved to keep beverages at the set temperature during the peak cut operation, the energy-saving effect for cold products in summer and for hot products in winter has been enhanced. For the manufacturing of `Eco-vendor`, Fuji Electric Co., Ltd. has offered its technical know-how to five manufacturers of automatic vending machine for beverages without compensation, and each manufacturer has accepted the offer. Electric power companies of Japan have cooperated to pay incident of 10,000 yen per an `Eco-vendor` to the manufacturers. Japan`s automatic vending machine industries and nationwide beverage industries have positively cooperated. Consequently, Tokyo Electric Power Company has successfully spread 2,600 machines up to the end of fiscal 1995, and aims at the spread of 16,000 machines in fiscal 1996. 2 figs.

  12. Study on electromagnetic noise reduction in building spaces. Propagation of electromagnetic noise generated by an elevator and its countermeasurement; Kenchiku kukan no denjiha noise hogyo no kenkyu. Elevator kara hasseisuru denjiha noise no denpa jokyo to taisaku ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, Y.; Yoshida, K.; Zama, A. [Obayashi Corp., Tokyo (Japan)

    1995-08-10

    With the progress of power-electronics, a inverter has been generally applied to building facility equipment. This equipment go by chapping a current in high frequency, so secondarily generates electromagnetic noise. The characteristics and propagation of electromagnetic noise generated by an elevator machine were measured. From this, it was recognized that high-level spectrum was included in the frequencies under 100kHz, and electromagnetic noise was scattered a wide area on the roof and the highest floor of the building. By intercepting the conductive noise on the motor main distribution line, the area influenced by the noise was restricted to only a small area around the elevator machine room. 4 refs., 8 figs., 2 tabs.

  13. Design of the control system for fixed-point keeping in FPSO (Floating Production Storage and Offloading); FPSO no teiten hoji no tame no seigyokei no sekkei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kijima, K; Murata, W; Furukawa, Y [Kyushu University, Fukuoka (Japan). Faculty of Engineering

    1997-10-01

    The control system for keeping the fixed-point of ships against disturbance was designed by applying an ILQ (Inverse Linear Quadratic) control (possible to specify the response of controlled systems with time constant) theory, to study the effect of different time constants as design parameter on a fixed-point keeping performance. It was assumed that the controlled ship is equipped with two bow thrusters and one stern thruster of 30ton in output to generate a control force. For fixed-point keeping control, the state equation was derived to slave the controlled system to a target input. The ILQ design method uses the result of the inverse problem of optimum regulators. For designing control systems by using the ILQ control theory, the smallest time constant should be selected according to the most severe disturbance condition considering the response performance of controllers, to achieve fixed-point keeping of ships. In fixed-point keeping, it is also essential to put the initial position as close as possible to the target point. 2 refs., 6 figs., 2 tabs.

  14. Development of a forecasting method of a region`s electric power demand. 1. Forecasting economic and social indexes; Chiikibetsu denryoku juyo yosoku shuhono kaihatsu ni tsuite. 1. Keizai shakai shihyo no yosoku

    Energy Technology Data Exchange (ETDEWEB)

    Minato, Y. [Shikoku Research Institute Inc., Kagawa (Japan); Yokoi, Y. [The University of Tokushima, Tokushima (Japan)

    1996-01-20

    This paper relates to the forecasting method of the electric power demands (kWh and kW) of a region, approached by not only time series analysis but economic and social indexes. Those indexes, based on historical statistics such as census and establishment statistics, are rearranged from an administrative division to a managerial division of the electric power company, and applied as fundamental information for forecasting the area`s kWh and also sales promotion. This method of forecasting the area`s kWh is based on the concept that area`s kWh is strongly connected with the population their lifestyle and their activity within the region. In the paper, the framework of the computational model system and forecast result are discussed. The population, number of households and their members, and number of employed persons, are all evaluated. The forecasting method of the area`s population proposed here is based on the concept that the transition of population consists of both natural growth and immigration. By estimating both factors, the future area`s population can be easily forecasted. The information of whether the population is increasing or decreasing is useful for forecasting the region`s kWh and required sales promotion. 8 refs., 8 figs., 3 tabs.

  15. Study on deep crustal resistivity structure using wideband magnetotellurics. In the case of eastern part of Hokkaido, Japan; Kotaiiki MT ho wo mochiita shinbu chikakuhi teiko kozo no kenkyu. Hokkaido Tobu chiiki ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Sato, H; Tanimoto, K; Maeda, T; Nishida, Y [Hokkaido University, Sapporo (Japan); Takada, M; Tamura, M [Hokkaido University, Sapporo (Japan). Research Center of Earthquake Prediction; Ogawa, Y [Geological Survey of Japan, Tsukuba (Japan); Nagao, T [Tokai Univ., Tokyo (Japan)

    1997-10-22

    Wide-range MT (magnetotelluric) observation is conducted to collect knowledge of the middle and lower parts of the crust of the above-named region, about which but a little information is available, for comparison with information about Kurile islands arc tectonics. Three traverse lines crossing the Kurile islands roughly in the north-south direction and two lines running from east to west are used, with the observation stations totalling 48. The distance between observation stations is 7-8km on the Nijibetsu line, and approximately 15km on the Nakashibetsu and Akan lines. A very wide frequency range of 320-0.0005Hz is used for measuring, and these results in detection with success of resistivity structure details from shallow to deep layers in the crust. The collected data are analyzed, and it is estimated that the northern and central parts have a high-low-high three-layer structure while the southern part has a low-high two-layer structure. Since the data obtained at observation stations at the middle of the lines, in particular, have an extremely low apparent value of several ohm/m at about 1Kz in the absence of splits in the TM (transverse magnetic) and TE (transverse electric) modes, it is inferred that the low-resistivity layer is considerably thick and is distributed rather uniformly. 13 refs., 5 figs.

  16. Application of waste tires to asphalt pavement. Improvement of adhesion of asphalt with rubber particles; Haitaiya no asphalt hoso eno tekiyo. Asphalt to gomu ryushi no fuchakusei no kairyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Nakaoka, I. [Kansai Electric Power Co. Inc., Osaka (Japan)

    1994-10-10

    With an objective to apply waste tires to asphalt pavement, an experiment was carried out to improve adhesion of asphalt with rubber particles by using polymers. The state of interface on rubber particle and asphalt mixture was observed by a scanning electron microscope. As a result, it was found that the surface of untreated rubber particles is not bonded with the asphalt, but polymer treated mixture was found to have the affinity of rubber particles with asphalt improved. Tensile bonding strength was tested on rubber plates and asphalt. The result revealed that the polymer-reformed mixture has two times as large tensile bonding strength as that of the untreated mixture. With regard to the characters of asphalt mixture mixed with rubber particles, the stability shows a decreasing trend as compared with the standard asphalt concrete, but presents an excellent performance in wear. The fluidity resistance value is inferior to the standard, but not as great as presenting a problem under normal using environment, where its applicability as a road paving material was verified. 4 figs., 2 tabs.

  17. On the wave induced responses for a high-speed hydrofoil catamaran. Part 2. Cabin connected to hull by spring and response to vibration; Suichuyokutsuki kosoku sodotei no harochu oto ni tsuite. 2. Dokuritsu kozogata cabin to yodo oto

    Energy Technology Data Exchange (ETDEWEB)

    Nobukawa, H; Kitamura, M; Kawamura, T [Hiroshima University, Hiroshima (Japan). Faculty of Engineering

    1996-04-10

    A high-speed hydrofoil catamaran under development has such a structure that an independent cabin is mounted on catamaran hulls, the cabin is connected with the hulls by using four soft springs, and hydrofoils are attached to the front and rear of the cabin. The structural design conception was as follows: the self-weight of the cabin is supported by lifting power of the hydrofoils while the boat is cruising; longitudinal motions of the catamaran hulls are absorbed by soft spring struts to make the motions more difficult to be transmitted into the cabin; and vibration excited by engines rotating at high speeds, attached to rear of the catamaran hulls, is not transmitted directly to the cabin structurally. A towing experiment was carried out by using divided models of about 1/10 scale in counter waves and regular waves to investigate their vibration response characteristics in waves. Furthermore, an experimental boat made of aluminum alloy with about 1/3 scale of the design boat was attached with composite structural struts made of springs and rubber parts to perform cruising experiments on an actual sea area. As a result, it was found that vibration excited by main engines in the catamaran hulls is transmitted very little to the cabin. 2 refs., 10 figs., 1 tab.

  18. Adoption of a fiber reinforced plastics (FRP) inner cylinder for the chimney stack at the Wakayama power plant; Wakayama hatsudensho entotsu eno FRP sei naito no saiyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Hirakawa, M. [Kansai Electric Power Co. Inc., Osaka (Japan)

    2000-05-10

    The chimney stack at the Wakayama power plant is planned to adopt a fiber reinforced plastics (FRP) inner cylinder having greater cost reduction effect than a steel made inner cylinder. The present study has performed different experiments on FRP under the gas emitting condition at the Wakayama power plant, and discussed structural plans based on the result therefrom. The Wakayama power plant has the waste gas raised in temperature because of difference in the power generation system. Therefore, physical constant verification tests and heat resistance tests were performed on FRP to verify its applicability. Structural discussions to pursue economy were given on the 'joints' and 'suspension points' (supporting points to suspend the FRP inner cylinder) being the major FRP structures based on the actual record at the Nanko power plant. The tests have placed focus on the 'heat resistance', and different experiments were carried out upon selecting two kinds of novolak-based vinyl ester resins. As a result, applicability of the FRP made inner cylinder to high waste gas temperatures was verified, and so were various property values to be used for designing the cylinder. Structural design was performed by applying design safety factor to the derived property values, and the basic structural plan was established for the FRP inner cylinder. (NEDO)

  19. Advanced honeycomb adsorbent and scaling-up technique for thermal swing adsorptive VOC concentrator; Samarusuingu kyuchakushiki VOC noshuku sochiyo hanikamu kyuchakutai no kaizen to sukeru up gijutsu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Mitsuma, Y.; Kuwa, T.; Yamauchi, H. [Seibu Giken Co. Ltd., Fukuoka (Japan); Hirose, T. [Kumamoto Univ. (Japan). Faculty of Engineering

    1998-03-01

    On the honeycomb type adsorptive concentrator, a manufacturing method of the honeycomb adsorbent rotor, retention of mechanical strength corresponding with a large-scale processing and minimization of air leakage resulting in performance deterioration were technically examined. Honeycomb structure was formed from an alumina-silica fiber paper, and high silica-content zeolite was deposited in the fiber void of the matrix. The adsorbent rotor using sepiolite as an inorganic adhesive for honeycomb fabrication showed fracture strength of from 1.6 to 3.2 times the conventional adsorbent rotor. Two types of differently shaped fluorinated rubber seal were developed for the adsorbent rotor. Amount of air leakage from the seal between each zone as well as to outside was sufficiently small. A large-scale VOC concentrator with the 3950 mm diameter and 450 mm length was manufactured with the adsorbent rotor and seal structure in accordance with the aforementioned method. Results of the real machine operation showed same concentration performance at those of the small-scale experiment. 10 refs., 15 figs., 2 tabs.

  20. Survey and research report on how large-scale technological development should be in the future; Kongo no daikibo gijutsu kaihatsu no hoko ni tsuite no chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1980-03-01

    Mentioned as data processing technologies to be developed in the 1980s are a computer-assisted system of document translation, supercomputer, knowledge-based information system, and an automated Japanese language office work processing system. Mentioned in relation with the utilization of thermonuclear energy are atomic steel making, liquefied coal gasification, heavy oil gasification, and cracking of heavy oil into lighter oils. In relation with process conversion and new materials technologies, the development and application of functional membrane materials and the conversion of biomass into chemical materials are taken up. In relation with aviation and space technologies, a high-speed turboprop airplane, highly efficient aeroengine, ultralight aircraft, and a transport plane powered by methane or hydrogen are taken up. In relation with electronics or mechanics, an ultra-precision high order production system, automotive ceramic engine, industrial robot system, intelligent database machine system, and a transportable synchrotron are taken up. In addition, a number of subjects are mentioned in relation with social system technology, optoelectronic technology, resources and ocean development technologies, etc. (NEDO)

  1. Fiscal 1992 survey report. Promotion of coal importing base buildup (How ocean freight system should be in the future); 1992 nendo kaigaitan yunyu kiban seibi sokushin chosa. Kongo no gaiko yuso taisei no arikata ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-03-01

    When a general view is taken of coal chains that connect overseas coal suppliers to Japan's end users, it is found that no survey has ever been made to sufficiently explain marine transportation of coal. It is now expected that the gap between supply of and demand for shipping tonnage will widen thanks to a sharp increase supposed to emerge in the demand for overseas coal in the future and that a scarcity of tonnage will impede stable space securing for coal and economically viable coal transportation. Such being the case, this project aims to investigate the ocean freight systems to serve between overseas coal shipping ports and Japan's coal receiving bases and the current states and problems of cargo facilities in Japan, to study how to build up a shipping space securing system which will properly deal with an increase in the import of steam coal from abroad, and to contribute to the formation of measures for enabling smooth transportation of coal from overseas. The survey conducted for this purpose covers the present conditions of Japan's ocean freight systems and of its coal receiving bases, present conditions of transportation by oceangoing ships in the Pacific basin, compilation of a list of oceangoing ships, prediction of ocean freight transportation and supply of transportation service, prediction of ocean freight cost in the future, and putting in an easy-to-review order the tasks to be accomplished for the enhancement of coal transportation by oceangoing ships. (NEDO)

  2. Study on wind turbine for Yamagata wind energy institute. Comparison of the actual and estimate values for electric power; Yamagata furyoku hatsudensho no fusha ni tsuite. Hatsudenryo yosoku to jissekichi no hikaku

    Energy Technology Data Exchange (ETDEWEB)

    Nagai, H [Nihon University, Tokyo (Japan); Kojima, T [Yamagata Wind Energy Institute, Yamagata (Japan)

    1996-10-27

    For two 400kW wind turbines erected in Jan. 1996 of Yamagata Wind Energy Institute, their estimated power output was compared with actual output for 7 months. AMeDAS data in 1985-94 were totaled every month to use as basic data. The altitude and surface roughness model necessary for WAsP analysis recommended by NEDO`s wind condition close inspection manual were prepared using 1/25,000 maps and aerial photographs. The obstacle model for estimating wind conditions at height of the wind turbine was prepared using the data obtained by field survey. Mean wind velocity and latent energy were determined by statistical analysis of wind velocity occurrence relative frequencies and Weibull distribution parameters. The power output of 717,700kWh was obtained for 7 months, which is equivalent to 88.5% of the estimated output of 810,730kWh for the same period. It was clarified from obtained characteristic wind conditions at the site that the wind power generation is promising at the site not only in winter but also in summer. Although the test period was too short, this method was effective as analytical method of output estimation in the planning stage of wind turbines. 3 refs., 8 figs., 4 tabs.

  3. Application of a temperature selective heat storage tank to a solar system. Part 3. Solar heat collecting system; Ondo sentaku chikunetsuso no solar system eno tekiyo. 3. Shunetsu hoshiki ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kamiya, Y [Kanto Gakuin University, Yokohama (Japan); Kanayama, K [Kitami Institute of Technology, Hokkaido (Japan)

    1996-10-27

    The tank system and tank-less system when the temperature selective heat storage tank is applied to a solar system were considered. In the tank system, the simulation shows that the annual supplementary heat consumption is reduced as the tank capacity becomes lower. The most suitable operating time set for determining the reference time is about five hours in winter and about nine hours in summer. The annual operating time is about 6.5 hours. In the tank-less system, the most suitable minimum flow rate per solar collector area of a heating medium in Tokyo and its districts is 10 L/hm{sup 2} for both three-step flow control and constant flow control. The tank-less system is slightly lower in annual supplementary heat consumption than the tank system. For the three-step flow control, a change in the annual supplementary heat consumption is lower than that in the minimum flow rate. For the constant flow control, however, the annual supplementary heat consumption rapidly increases when the flow rate more decreases than the optimum value. The number of pump start/stop counts for the three-step flow control is less than two times as high as for the constant flow control. 4 refs., 6 figs., 1 tab.

  4. On a research of the jet stream power generation. Part 2. Maximum height of a flying kite; Jet kiryu hatsuden no kenkyu. 2. Tako no totatsu kodo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Miyashita, J. [Nihon University, Tokyo (Japan). College of Science and Technology

    1998-04-05

    Tethering cable was investigated as a part of a research of jet stream power generation using balloon and kite. Recently, there appeared new materials with light and high strength properties, such as carbon and polyamide resin. When these are used as tethering cables, flying ability of tethered bodies is remarkably improved. Tethered balloon at the altitude of 6500 feet and large-scale kite at the altitude of 5000 m are proposed for the idea of jet stream power generation. A computer program was developed for determining the flying ability of a kite, to calculate it. Similarity rule was also determined by the dimensional analysis. For a kite with a tethering cable having uniform diameter and specific gravity, the similarity can be obtained when two kinds of similarity rules are satisfied. One is (length of tethering cable/width of kite wing)times(dynamic pressure of air/tensile strength of cable){sup 1/2}=(constant). Another is (length of tethering cable)times(density of cable/tensile strength of cable)=(constant). Since the maximum height is in proportion to (strength/specific gravity) of the cable, it increases drastically using high performance materials. It is affected by the aerodynamic performance of the kite and the safety factor of strength of the cable. 4 refs., 45 figs., 2 tabs.

  5. Practical use of dry desulfurization equipment using coal ash and effective use of used desulfurizer. Sekitanbai riyo kanshiki datsuryu sochi no jitsuyoka to shiyozumi datsuryuzai no yukoriyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, T.; Ueno, T. (The Hokkaido Electric Power CO. Inc., Hokkaido (Japan))

    1992-01-30

    Practical use of dry desulfurization equipment using coal ash installed in Atsuma power plant no.1 is explained. Outline of dry desulferization process is consisted of basic principles and structure of the process which includes desulfurizer production equipment and absorption equipment. When compared with conventional wet process, equipments for waste water and for reheating of exhaust gas are not necessary, and operation maintenance has been more convenient with the simplification of the system and absorber has graded up the elimination function. Advantages of simplification of treatment of used desulfurizer, and absorption of sulfurdioxide by desulfurizer together with characteristics of desulfurizer production are given. As far as practical macineries are concerned, outline of instrument facilities, construction technology and results of experimental operation are reported. Effective Use of desulfurizer using deodorant and hedro treatment has been verified from ammonium absorption experiment and practical investigation results. However use of hedro material has required, conformity of surface caking technology, under water caking technology, under water covering technology and effect on under water living environment. 13 figs., 4 tabs.

  6. Concerning problems of petroleum refining facilities. ; Promote international lateral work sharing, and strengthening of infrastructures in petroleum industry. Sekiyu seisei setsubi mondai ni tsuite. ; Kokusei suihei bungyo no suishin to sekiyu sangyo no kiban kyoka wo

    Energy Technology Data Exchange (ETDEWEB)

    1991-06-05

    This paper discusses how to promote international lateral work sharing and how to strengthen infrastructures in the petroleum industry, as a problem prevailing over the petroleum refining facilities in Japan. Excess distillation facilities have been applied with the disposition policy. However, in view of the supply and demand situation in petroleum products for medium to long term span in the world with the pan-Pacific region as the main concern, that applicable to Japan, and that experienced during the Persian Gulf crisis, the excess facility disposition policy was revised, particularly on white kerosene, of which supply and demand tightness is concerned about, so that production capacities may be increased as required. Japan, a large presence in the international economics, is required to work more positively on petroleum refining facilities located in the oil producing countries and intermediate locations to promote the international lateral work sharing. On the one hand, in order to strengthen the infrastructures in the Japanese petroleum industry, it is necessary to promote rationalization and use at higher efficiency of the oil supply system, and convergence of the the petroleum industry, including joint investments for projects exceeding capabilities of individual enterprises. 3 tabs.

  7. Survey on improvement in development of coal in Asia-Pacific region in fiscal 1998. Survey on optimization of coal transportation system in Kalimantan, Indonesia (South Kalimantan State); 1998 nendo Asia Taiheiyo sekitan kaihatsu kodoka chosa. Indonesia Karimantan ni okeru sekitan yuso system saitekika chosa (Minami Karimantan shu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Based on the June 1998 agreement with Indonesia on a comprehensive survey of the Kalimantan coal transportation system, plans for developing transportation infrastructures and coal mines were established, and a survey was carried out to realize efficient coal development and transportation. In proceeding with the future development of the South Kalimantan coal, it was made clear that the domestic Indonesian demand and export demand thereon can be fully expected, and latent supply capability thereto exists sufficiently. However, although the latent supply capability is available, the coal transportation infrastructures are insufficient, hence new construction of railways and coal shipping ports is necessary. The present survey has prepared an LP model for the coal transportation infrastructures, and performed case studies on six coal transportation scenarios composed of potential existing or new roads, waterways, railways and coal shipping ports. It was found promising economically that, for either case of domestic or export supply, Tg. Selatan port shall be newly built in addition to IBT port and NPLCT port, to link the ports by a railway network to be built newly. (NEDO)

  8. Fiscal 1999 report on basic research for promotion of joint implementation programs. Gas pipeline system optimization involving Ukrainian pipeline modification for reduction in global warming gas emissions; 1999 nendo ondanka gas haishutsu sakugen no tame no Ukraina ni okeru gas pipeline no kaishu wo fukumu pipeline system no saitekika chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The result of a survey which involves a 520km-long gas pipeline (Shebelinka-Dikanka-Kyiv) modification in the Ukraine is described, which will promote joint implementation programs under COP3 (Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change). Since the greenhouse effect of methane gas is 21 times as serious as that of CO2, it is important to ensure good maintenance and structural soundness for natural gas transporting pipeline systems. The currently available Ukrainian gas turbines and compressors are so obsolescent that their efficiency rate is as low as 23%. The rate will rise to 36% when the old ones are replaced by high power equipment capable of high efficiency combustion. Pipelines will be checked for deterioration due to stress corrosion cracking and dangerous pipes will be replaced, with attention paid particularly to joint sections. It is expected that there will be a greenhouse gas reduction of 512,000 tons (in terms of CO2) and a saving of 103,000 tons on fuel (in terms of crude). Balance is tentatively estimated in case the expected reduction in emissions is transacted in emission trading. Profitability will occur, in view of profit from emission trading and gas sales revenue after gas leakage prevention thanks to project implementation, when the emission right sells at 30 dollars/ton or higher. The rippling effect will be great now that the Ukrainian pipeline system is quite extensive (with 30% thereof superannuated). (NEDO)

  9. 18th national meeting for energy saving promotion (prize winning case awarded by Minstry of International Trade and Industry). ; Optimization of additive carrying argon gas in continuous casting. Dai 18 kai sho energy suishin zenkoku taikai (tsusho sangyo daijinsho jusho jirei). ; Renzoku chuzo ni okeru tenkazai hansoyo argon gas no saitekika

    Energy Technology Data Exchange (ETDEWEB)

    1993-01-30

    An optimal amount of argon gas carrying CaSi additive particles was discovered in a continuous casting process and a stable operation method was established to conserve energy and cost. CaSi particles are added into molten steel to prevent steel materials from cracking, and argon gas is used in carrying the CaSi particles to prevent oxygen and nitrogen from mixing into the molten steel. The proposed modification plan intends to use the existing facilities up to the seal rotary machine, and to reduce the size and length of the carrying pipes thereafter, the length of the flexible tubes, and the size of the booster. A verification test was carried out. As a result of measuring the CaSi particle scattering distribution, it was found that an in-pipe flow velocity of 25 m/s produces a narrow scattering distribution and has the particles impinge on the molten steel dropping position concentratedly. It was also learned that the in-pipe flow velocity of 25 m/s can increase the solid-air ratio to 0.81 to 1.21. Operations of the modified machine reduced the argon gas amount by 5.2 m[sup 3]N/min (reduction rate of 61%) and realized stabler CaSi particle injection which improved the Ca yield by 9.4%. 14 figs., 7 tabs.

  10. Investigation cost subsidizing project for improving development of overseas coals in fiscal 1999. Investigations on improving development of Asian and Pacific coals (Investigation on optimizing the coal transportation system in East Karimantan Province in Indonesia); 1999 nendo Asia Taiheiyo sekitan kaihatsu kodoka chosa. Indonesia Higashi Karimantan shu ni okeru sekitan yuso system saitekika chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Evaluation was given on coal production quantity and coal transportation capability in areas scheduled of future development in Karimantan, Indonesia. Discussions were given on an optimal coal transportation system in East Karimantan Province. The coal production quantity in East Karimantan in fiscal 1999 was 35.27 million tons, accounting for 48% of the total Indonesian coal production. Production of 81.90 million tons is anticipated in 2020. Quality of the coal being produced is low in ash and high in water content in general. Calorific power is 5800 kcal or more. Sulfur content is 0.5% or more, not necessarily a low sulfur coal. The result of analyzing the optimal transportation routes by using the LP model may be summarized as follows: such scenarios are regarded to be largely profitable and advantageous that assume making railways utilizable as the land transportation in addition to use of trucks, belt conveyers, and barges, expanding coal terminals at the ports of PBCT, KPC, BCT and NPLCT, and newly building ports at Tarakan, TgSengatta, BPCTH, and Mangkapadie. (NEDO)

  11. Gd-Ni-Si system

    International Nuclear Information System (INIS)

    Bodak, O.I.; Shvets, A.F.

    1983-01-01

    By X-ray phase analysis method isothermal cross section of phase diagram of the Gd-Ni-Si system at 870 K is studied. The existence of nine previously known compounds (GdNisub(6.72)Sisub(6.28), GdNi 10 Si 2 , GdNi 5 Si 3 , GdNi 4 Si, GdNi 2 Si 2 , GdNiSi 3 , GdNiSi 2 , Gd 3 Ni 6 Si 2 and GdNiSi) is confirmed and three new compounds (GdNisub(0.2)Sisub(1.8), Gdsub(2)Nisub(1-0.8)Sisub(1-1.2), Gd 5 NiSi 4 ) are found. On the base of Gd 2 Si 3 compound up to 0.15 at. Ni fractions, an interstitial solid solution is formed up to 0.25 at Ni fractions dissolution continues of substitution type. The Gd-Ni-Si system is similar to the Y-Ni-Si system

  12. Internal carbonitriding behavior of Ni-V, Ni-Cr, and Ni-3Nb alloys

    International Nuclear Information System (INIS)

    Allen, A.T.; Douglass, D.L.

    1999-01-01

    Ni-2V, Ni-5V, Ni-12V, Ni-10Cr, Ni-20Cr, and Ni-3Nb alloys were carbonitrided in C 3 H 6 and NH 3 gas mixtures (bal H 2 ) over the range 700--1,000 C. Carbonitridation of Ni-12V and Ni-20Cr in C 3 H 6 /NH 3 /H 2 (1.5/1.5/97 v/o) and (1.5/10/88.5 v/o) produced duplex subscales consisting of near-surface nitrides with underlying carbides. Growth of each zone obeyed the parabolic rate law under most conditions. The presence of carbon generally did not effect the depth of the nitride zones compared to nitriding the alloys in NH 3 /H 2 (10/90 v/o). However, at 700 C, the nitride zones were deeper in the carbonitrided Ni-V alloys and Ni-20Cr. The presence of nitrogen generally increased the depth of the carbide zones in Ni-12V and Ni-20Cr compared to carburizing these alloys in C 3 H 6 /H 2 (1.5/98.5 v/o). VN, CrN, and NbN formed in Ni-V, Ni-Cr, and Ni-Nb alloys, respectively, whereas the underlying carbide layers contained V 4 C 3 in Ni-12V, Cr 3 C 2 above a zone of Cr 7 C 3 in Ni-20Cr, and NbC in Ni-3Nb. The solubilities and diffusivities of nitrogen and carbon in nickel were determined. Nitrogen and carbon each exhibited retrograde solubility with temperature in pure Ni in both carbonitriding environments. Nitrogen diffusion in nickel was generally lower in each carbonitriding mixture compared to nitrogen diffusion in a nitriding environment, except at 700 C when nitrogen diffusion was higher. Carbon diffusion in nickel was generally higher in the carbonitriding environments compared to carbon diffusion in a carburizing environment

  13. Nipah Virus (NiV)

    Science.gov (United States)

    ... Form Controls Cancel Submit Search the CDC Nipah Virus (NiV) Note: Javascript is disabled or is not ... gov . Recommend on Facebook Tweet Share Compartir Nipah virus (NiV) is a member of the family Paramyxoviridae , ...

  14. Ni República parlamentaria ni presidencialista

    OpenAIRE

    Álvarez Tardío, Manuel

    2004-01-01

    Revista de Estudios Políticos (Nueva Época), Núm. 123. Enero-Marzo 2004 Este trabajo está dedicado al estudio de un aspecto básico del sistema político de la II República española (1931-1936): el modelo de presidencia de la República y de relaciones de la misma con el parlamento y el gobierno. Aquí se sostiene que la Segunda República, de acuerdo con su Constitución, no fue un régimen parlamentario ni presidencial. Combinó de forma extraña y ambigua elementos de ambos modelos. Probablement...

  15. Study on unified fatigue strength assessment method for welded structure. Hot spot stress evaluating method for various combinations of plate thickness and weld leg length; Yosetsu kozo no toitsutekina hiro kyodo hyokaho ni kansuru kenkyu. Itaatsu to yosetsu ashinaga no kumiawase ni taisuru hot spot oryoku sanshutsu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Nihei, K.; Inamura, F.; Koe, S. [Kawasaki Heavy Industries, Ltd., Kobe (Japan)

    1996-12-31

    There has been tried to apply unified assessment method using hot spot stress, which is effective to evaluate fatigue strength of fillet welded structures for ships and marine structures. This method can be applied to complicated structures and is independent of welding processes. In this study, first, stress analysis has been conducted for two-dimensional fillet welded joint models with various combinations of plate thickness and weld leg length of general fillet structures by means of boundary element method. Then, critical position, which is not affected by local stress concentration due to bead, was determined from the detailed stress distribution in the vicinity of weld toe. As a result, a general equation has been proposed to estimate the hot spot stress by one-point representative method. Second, the fatigue tests of typical fillet welded joints have been conducted by applying this method. Consequently, it was demonstrated that the unified fatigue strength can be evaluated by the S-N data based on hot spot stress range determined from the proposed equation, independent of structural stress concentration. 22 refs., 14 figs.

  16. Comparative analysis of thermal storage cooling and storage battery cooling using photovoltaic generation. Part 2. Research on architectural systematization of energy conversion devices; Taiyoko hatsuden ni yoru chikunetsu reibo to chikuden reibo ni tsuite. 2. Energy henkan no kenchiku system ka ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Ito, N; Kimura, G; Fukao, S; Shimizu, T; Sunaga, N; Tsunoda, M; Muro, K; Yamanaka, S [Tokyo Metropolitan University, Tokyo (Japan)

    1996-10-27

    For use in energy self-sufficient buildings, a system was studied capable of retaining for its own use the excess of power produced by a photovoltaic power generation system without releasing it to the commercial system. Summertime cooling was considered. The storage battery cooling system was provided with two solar cell systems and, in the daytime, one was used for cooling and the other for charging batteries for nighttime cooling. In the cold heat storage cooling system, cold heat accumulators (red bricks) were provided in the wall and floor, and under the floor, and the floor was a grating for proper ventilation between the room and underfloor space. With the solar cell-driven air conditioner out of operation, cold heat was fed to the room from the underfloor cold heat accumulators by a fan. In storage battery cooling, solar power covered 60% of what the air conditioner used. In the presence of sufficient power in storage, the air conditioner stayed on at night without buying commercial power, when the room temperature was 25{degree}C. In the cold heat accumulation cooling, 50% of the air conditioner power consumption was covered by solar power. It is recommended to install cold heat accumulators not in the room but in a separate space, such as the underfloor space, where they are exposed to the cooling cold air direct from an air conditioner for future retrieval of cold heat. 2 refs., 9 figs., 3 tabs.

  17. Study on unified fatigue strength assessment method for welded structure. Hot spot stress evaluating method for various combinations of plate thickness and weld leg length; Yosetsu kozo no toitsutekina hiro kyodo hyokaho ni kansuru kenkyu. Itaatsu to yosetsu ashinaga no kumiawase ni taisuru hot spot oryoku sanshutsu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Nihei, K; Inamura, F; Koe, S [Kawasaki Heavy Industries, Ltd., Kobe (Japan)

    1997-12-31

    There has been tried to apply unified assessment method using hot spot stress, which is effective to evaluate fatigue strength of fillet welded structures for ships and marine structures. This method can be applied to complicated structures and is independent of welding processes. In this study, first, stress analysis has been conducted for two-dimensional fillet welded joint models with various combinations of plate thickness and weld leg length of general fillet structures by means of boundary element method. Then, critical position, which is not affected by local stress concentration due to bead, was determined from the detailed stress distribution in the vicinity of weld toe. As a result, a general equation has been proposed to estimate the hot spot stress by one-point representative method. Second, the fatigue tests of typical fillet welded joints have been conducted by applying this method. Consequently, it was demonstrated that the unified fatigue strength can be evaluated by the S-N data based on hot spot stress range determined from the proposed equation, independent of structural stress concentration. 22 refs., 14 figs.

  18. Microstructural development in NiAl/Ni-Si-B/Ni transient liquid phase bonds

    International Nuclear Information System (INIS)

    Gale, W.F.; Orel, S.V.

    1996-01-01

    A transmission electron microscopy (TEM) based investigation of microstructural development during transient liquid phase bonding of near-stoichiometric NiAl to commercial purity nickel is presented in this article. The work described employed Ni-4.5 wt pct Si-3.2 wt pct B (BNi-3) melt-spun interlayers. The precipitation of both Ni-Al based phases and borides within the joint and adjacent substrate regions is discussed. The article considers martensite formation (within the NiAl substrate) and the precipitation of L1 2 type phases (both within the joint and at the interface with the NiAl substrate). The relative roles of the two substrate materials (NiAl and Ni) in the isothermal resolidification process are identified. The preferential formation of Ni 3 B boride phases in the Ni substrate near the original location of the Ni substrate-joint interface is discussed and contrasted with the absence of similar events in the NiAl substrate

  19. Ni landsbyer i Danmark

    DEFF Research Database (Denmark)

    Larsen, Jacob Norvig

    Denne rapport beskriver en evaluering af statsstøttede forsøg med at styrke og udvikle mindre lokalsamfund. Forsøgene er gennemført i ni kommuner. Da der i disse år er stor opmærksomhed om de små byers og samfunds udviklingsmuligheder, har erfaringerne fra forsøgsprojekterne bred interesse. Forsø...

  20. Reduction mechanism of Ni2+ into Ni nanoparticles prepared from ...

    Indian Academy of Sciences (India)

    journal of. March 2009 physics pp. 577–586. Reduction mechanism of Ni2+ into Ni ..... and at high field, no domain wall is available and hence, the system becomes a .... [23] J Ding, T Tsuzuki, P G McCormick and R Street, J. Phys. D: Appl.

  1. Reactive Ni/Ti nanolaminates

    International Nuclear Information System (INIS)

    Adams, D. P.; Bai, M. M.; Rodriguez, M. A.; McDonald, J. P.; Jones, E. Jr.; Brewer, L.; Moore, J. J.

    2009-01-01

    Nickel/titanium nanolaminates fabricated by sputter deposition exhibited rapid, high-temperature synthesis. When heated locally, self-sustained reactions were produced in freestanding Ni/Ti multilayer foils characterized by average propagation speeds between ∼0.1 and 1.4 m/s. The speed of a propagating reaction front was affected by total foil thickness and bilayer thickness (layer periodicity). In contrast to previous work with compacted Ni-Ti powders, no preheating of Ni/Ti foils was required to maintain self-propagating reactions. High-temperature synthesis was also stimulated by rapid global heating demonstrating low ignition temperatures (T ig )∼300-400 deg. C for nanolaminates. Ignition temperature was influenced by bilayer thickness with more coarse laminate designs exhibiting increased T ig . Foils reacted in a vacuum apparatus developed either as single-phase B2 cubic NiTi (austenite) or as a mixed-phase structure that was composed of monoclinic B19 ' NiTi (martensite), hexagonal NiTi 2 , and B2 NiTi. Single-phase, cubic B2 NiTi generally formed when the initial bilayer thickness was made small.

  2. Electroplated Ni on the PN Junction Semiconductor

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jin Joo; Uhm, Young Rang; Son, Kwang Jae; Kim, Jong Bum; Choi, Sang Moo; Park, Jong Han; Hong, Jintae [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-05-15

    Nickel (Ni) electroplating was implemented by using a metal Ni powder in order to establish a Ni-63 plating condition on the PN junction semiconductor needed for production of betavoltaic battery. PN junction semiconductors with a Ni seed layer of 500 and 1000 A were coated with Ni at current density from 10 to 50 mA cm{sup 2}. The surface roughness and average grain size of Ni deposits were investigated by XRD and SEM techniques. The roughness of Ni deposit was increased as the current density was increased, and decreased as the thickness of Ni seed layer was increased.

  3. Electroplated Ni on the PN Junction Semiconductor

    International Nuclear Information System (INIS)

    Kim, Jin Joo; Uhm, Young Rang; Son, Kwang Jae; Kim, Jong Bum; Choi, Sang Moo; Park, Jong Han; Hong, Jintae

    2015-01-01

    Nickel (Ni) electroplating was implemented by using a metal Ni powder in order to establish a Ni-63 plating condition on the PN junction semiconductor needed for production of betavoltaic battery. PN junction semiconductors with a Ni seed layer of 500 and 1000 A were coated with Ni at current density from 10 to 50 mA cm 2 . The surface roughness and average grain size of Ni deposits were investigated by XRD and SEM techniques. The roughness of Ni deposit was increased as the current density was increased, and decreased as the thickness of Ni seed layer was increased

  4. Synthesis and electrochemical behavior of nanostructured cauliflower-shape Co-Ni/Co-Ni oxides composites

    International Nuclear Information System (INIS)

    Gupta, Vinay; Kawaguchi, Toshikazu; Miura, Norio

    2009-01-01

    Nanostructured Co-Ni/Co-Ni oxides were electrochemically deposited onto stainless steel electrode by electrochemical method and characterized for their structural and supercapacitive properties. The SEM images indicated that the obtained Co-Ni/Co-Ni oxides had cauliflower-type nanostructure. The X-ray diffraction pattern showed the formation of Co 3 O 4 , NiO, Co and Ni. The EDX elemental mapping images indicated that Ni, Co and O are distributed uniformly. The deposited Co-Ni/Co-Ni oxides showed good supercapacitive characteristics with a specific capacitance of 331 F/g at 1 mA/cm 2 current density in 1 M KOH electrolyte. A mechanism of the formation of cauliflower-shape Co-Ni/Co-Ni oxides was proposed. A variety of promising applications in the fields such as energy storage devices and sensors can be envisioned from Co-Ni/Co-Ni oxides

  5. Radiochemical method for 63Ni

    International Nuclear Information System (INIS)

    Holm, E.; Nilsson, U.; Hallstadius, L.

    1985-01-01

    A radianalytical method for the determination of 63 Ni content in environmental samples of activated corrosion products is described. After chemical separation and electrodepositing of 63 Ni on silver briquets, the chemical yield is determined by X-ray fluorescence analysis. For the detection of low-energy beta activity, an open gas flow GM-counter with an anticoincidence guard counter is put to use

  6. Electronic structure of Ni/sub 3/Al and Ni/sub 3/Ga alloys

    CERN Document Server

    Pong, W F; Chang, Y K; Tsai, M H; Hsieh, H H; Pieh, J Y; Tseng, P K; Lee, J F; Hsu, L S

    1999-01-01

    This work investigates the charge transfer and Al(Ga) p-Ni d hybridization effects in the intermetallic Ni/sub 3/Al(Ni/sub 3/Ga) alloy using the NiL/sub 3.2/- and K-edge and Al(Ga)K X-ray absorption near edge structure (XANES) measurements. We find that the intensity of white-line features at the NiL/sub 3.2/-edge in the Ni/sub 3/Al(Ni /sub 3/Ga) alloy decreased in comparison with that of pure Ni, which can be attributed to the enhancement of Ni3d states filling and the depletion of the density of Ni 3d unoccupied states in the Ni/sub 3 /Al(Ni/sub 3/Ga) alloy. Two clear features are also observed in the Ni/sub 3/Al(Ni/sub 3/Ga) XANES spectrum at the Al(Ga) K-edge, which can be assigned to the Al(Ga) unoccupied 3p (4p) states and their hybridized states with the Ni 3d/4sp states above the Fermi level in Ni/sub 3/Al(Ni/sub 3/Ga). The threshold at Al K-edge XANES for Ni/sub 3/Al clearly shifts towards higher photon energies relative to that of pure Al, indicating that Al loses charges upon forming Ni/sub 3 /Al. ...

  7. Nitriding behavior of Ni and Ni-based binary alloys

    Energy Technology Data Exchange (ETDEWEB)

    Fonovic, Matej

    2015-01-15

    Gaseous nitriding is a prominent thermochemical surface treatment process which can improve various properties of metallic materials such as mechanical, tribological and/or corrosion properties. This process is predominantly performed by applying NH{sub 3}+H{sub 2} containing gas atmospheres serving as the nitrogen donating medium at temperatures between 673 K and 873 K (400 C and 600 C). NH{sub 3} decomposes at the surface of the metallic specimen and nitrogen diffuses into the surface adjacent region of the specimen whereas hydrogen remains in the gas atmosphere. One of the most important parameters characterizing a gaseous nitriding process is the so-called nitriding potential (r{sub N}) which determines the chemical potential of nitrogen provided by the gas phase. The nitriding potential is defined as r{sub N} = p{sub NH{sub 3}}/p{sub H{sub 2}{sup 3/2}} where p{sub NH{sub 3}} and p{sub H{sub 2}} are the partial pressures of the NH{sub 3} and H{sub 2} in the nitriding atmosphere. In contrast with nitriding of α-Fe where the nitriding potential is usually in the range between 0.01 and 1 atm{sup -1/2}, nitriding of Ni and Ni-based alloys requires employing nitriding potentials higher than 100 atm{sup -1/2} and even up to ∞ (nitriding in pure NH{sub 3} atmosphere). This behavior is compatible with decreased thermodynamic stability of the 3d-metal nitrides with increasing atomic number. Depending on the nitriding conditions (temperature, nitriding potential and treatment time), different phases are formed at the surface of the Ni-based alloys. By applying very high nitriding potential, formation of hexagonal Ni{sub 3}N at the surface of the specimen (known as external nitriding) leads to the development of a compound layer, which may improve tribological properties. Underneath the Ni{sub 3}N compound layer, two possibilities exist: (i) alloying element precipitation within the nitrided zone (known as internal nitriding) and/or (ii) development of metastable and

  8. Ni4Ti3 precipitate structures in Ni-rich NiTi shape memory alloys

    International Nuclear Information System (INIS)

    Holec, D.; Bojda, O.; Dlouhy, A.

    2008-01-01

    Non-uniform distributions of Ni 4 Ti 3 precipitate crystallographic variants are investigated in a Ni-rich NiTi shape memory alloy after aging, assisted by external stress. A finite-element method model is presented that considers the elastic anisotropy of the B2 parent phase and also mutual misorientations of grains in a polycrystalline sample. On loading by the external stress, the stress is redistributed in the microstructure and the precipitation of some Ni 4 Ti 3 crystallographic variants becomes distinctly favorable in grain boundary regions since these variant configurations minimize the elastic interaction energy. The volume fraction of the affected grain boundary regions is calculated and the numerical results are compared with the data obtained by differential scanning calorimetry and transmission electron microscopy

  9. Typing of the sausage-shaped bacteria forming A-type sulfur-turf according to cell length distributions of natural populations and physico-chemical conditions of hot spring waters; Saibo chobunpu to seiiku kankyo kara mita A gata io shiba shizen kotaigun ni okeru okamagata saikin no katabetsu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Aki, Y. [Iwate University, Iwate (Japan). Faculty of Humanities and Social Sciences

    1996-01-25

    In order to type the sausage-shaped bacteria forming A-type sulfur-turf, cell length distributions and physics-chemical conditions of hot spring waters were investigated on twelve samples collected from all over Japan. The frequency distributions of the cell length of eight samples were bimodal, while the other four samples were unimodal. In seven samples with bimodal distributions, two types (large and small) of the sausage-shaped bacteria could be differentiated. The cell length of the large-type was between 10.1 and 31.9{mu}m, while that of the small-type ranged 2.2 to 6.6{mu}m. The pH of seven hot spring waters were between 6 and 8, and the two types (large and small) formed together sulfur-turf. In contrast, pH of the three hot springs were over 8, and the two types of the sausage-shaped bacteria could not be detected in the sulfur-turf. Therefore, it is reasonable to set a third type of the sausage-shaped bacteria which prefers high-pH (over 8) and low calcium condition. The cell lengths of the third type were in the range of 5.5 to 8.6{mu}m, which correspond to the sausage-shaped bacteria of medium size. 20 refs., 5 figs., 2 tabs.

  10. Report on the survey in fiscal 1998. Evaluation by Industry on the result of COP3 and the future activities (Britain); 1998 nendo chosa hokokusho. COP3 no kekka ni taisuru sangyokai no hyoka oyobi kongo no taio ni tsuite (Eikoku)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    A survey was carried out to identify the evaluation by British Industry on COP3 and the nation's future activities. In Britain, the gas emission level in 2000 is estimated to achieve sufficiently the initial target as the level is lower by 4 to 8% than that in 1990. This is largely attributable to substitution of coal by natural gas. At the Kyoto Conference, the European Union agreed with its target to reduce the emission of greenhouse effect gas over the period 2008-2012 to 8% below its 1990 level. Britain agreed to share its reduction rate at 12.5%. The Labour Party had set an election pledge since before the general election to reduce carbon oxide emission by 20% (against the 1990 level) by 2010, and the Prime Minister Tony Blair has also confirmed his commitment to this target. The policy making work to achieve the COP3 target has begun in 1998 when the UK Climate Change Program (consultation paper) was issued, and will continue until February 1999. The Advisory Committee of Business and Environment representing British Industry has already published their advice on how to achieve Britain's COP3 objective, which are considered by the government in the above mentioned paper. (NEDO)

  11. Feasibility study on environmental control in green house with air drawn from an abandoned mine. Part 5. ; Prediction and monitoring for development and design of rock. Haikonai wo toshita kiryu ni yoru onshitsu reidanbo no jitsuyosei ni tsuite. 5. ; Ganban kaihatsu sekkei no tameno yosoku to monitaringu

    Energy Technology Data Exchange (ETDEWEB)

    Mizuta, Y; Sano, O [Yamaguchi Univ., Yamaguchi (Japan). Faculty of Engineering; Zhang, Xiaoming [Yamaguchi Univ., Yamaguchi (Japan). Graduate School

    1994-03-25

    The horizontal land was made by burying the valley made by abandoned mine with waste rocks in Okawa Village in Kochi prefecture, and hydroponic cultivation was carried out. Possibility of use of air flow heat energy using the mine ventilation in order to economize and save energy of this cultivation was studied. If continuous green house ventilation is carried using air drawn from tunnel, applicable house temperature and humidity for certain scale of green house was possible to control within constant limit. When warming of 4 green houses from November to April was carried out, the maximum power load, the heating load for January, was 1,746.43kW and ventilation rate was 5.51 times/hour. Consumption for February was higher than January because of decrease of airflow drawn energy inside the tunnel. As for cooling from July to September, for August as the hottest month, maximum consumed energy required to maintain green house temperature was 2,058.28kW, and demand of airflow rate drawn inside the tunnel was 128.38m[sup 3]/s. 7 refs., 7 figs., 5 tabs.

  12. Study on fabrication methods of composite structures (1st. report); Joule effect curing of CFRP composite structures and its application to bonding and repair. Fukugo zai kozo no seikei kako ho ni kansuru kenkyu (Dai 1po); CFRP kozo no Joule koka wo riyo shita cure ho to setsugoter dot hoshu e no oyo ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Moriya, K. (The National Defense Academy, Kanagawa (Japan))

    1990-07-05

    A method for curing CFRP composite structures by using Joule effect is presented. Due to the presence of fiber to fiber contact, CFRP composites and their prepregs exhibit electrical conductivity in the direction transverse to fibers as well as in the fiber direction, and they can be considered as electrically homogeneous on a gross scale. Therefore, passing an electric current through a CFRP prepreg, it is self-heated due to the Joule effect. Feedback current control maintains the prepreg temperature at a desired level and makes the prepreg be cured by a specified cure cycle. Experimental verifiactions have been carried out to demonstrate the feasibility of the present technique. The applications to the bonding of CFRP components and to the patch repairs of effective CFRP structure are also described. 12 refs., 12 figs.

  13. Report on the survey in fiscal 1998. Evaluation by the industry on the result of COP3 and the future activities (Germany); 1998 nendo chosa hokokusho. COP3 no kekka ni taisuru sangyokai no hyoka oyobi kongo no taio ni tsuite (Doitsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    A survey was carried out on activities taken in Germany. The industry has a strong opinion to take voluntary regulations rather than those by laws. The nation's activities are being moved forward centrally with the suppression policies that follow the declaration on the voluntary regulation by the German industry to prevent global warming, which had been submitted by the German Industry Federation to the federal government in 1996. The participation to the declaration, which is optional, covers 71% of the energy consumption by manufacturing industries and 99% of the public electric power consumption, but large-scale industrial departments such as machine and electric power sectors who have not participated can also been found. The plan calls for reduction of inherent CO2 and energy per added value production amount in the entire industry by as much as 20% of the result in 1990 by 2005. According to the third party monitoring system employed by the federal government, the industry submits results of periodical analyses to the government. According to the result, the industries participated in the voluntary regulation have achieved annual exhaust suppression of 42 million tons during the period of 1990 to 1996. The public electric power industrial department whose CO2 emission accounts for a little less than 30% of the nation's total emission amount has a great effect. The industry is making efforts to improve the power generation efficiency aiming at reduction of CO2 emission of 12% of the 1990 result by 2015. (NEDO)

  14. Report on the survey in fiscal 1998. Evaluation by the industry on the result of COP3 and the future activities in relation with the result of COP3 (Canada); 1998 nendo chosa hokokusho. COP3 no kekka ni taisuru sangyokai no hyoka oyobi kongo no taio ni tsuite (Canada)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    A survey was carried out on activities in Canada in relation with COP3. The Office of Energy Efficiency is promoting the energy efficiency improvement and substituting energy plan applicable to housings, commercial and manufacturing industries, public organizations and transportation department. It is also implementing a comprehensive plan incorporating consumer information, national energy utilization data base, and energy technology innovation initiative. The energy technology innovation plus plan strengthens coordination with industrial societies in each sector, and makes finances for improvement of energy efficiency. There is also an institution to promote energy efficiency improvement in newly built houses. The manufacturing industry energy technology innovation initiative is an institution to present means to transfer pledges in each department into a company-wide activity. In the energy conservation encouragement plan for commercial buildings, an annual federal fund of ten million dollars is allotted, and incentive money is paid. The automotive fuel consumption enhancement plan provides purchasers with fuel consumption information, and encourages production of energy saving cars. The substituting transportation fuel market developing initiative promotes development and utilization of methanol, ethanol, hydrogen, and electric power. (NEDO)

  15. Development of tire road noise chassis-dynamometer simulator. Effect of ISO surface replica model pad on tire road noise; Shisakushita tire romen soon shiken`yo jissha daijo simulator ni tsuite. ISO romen mogi pad wo sochakushita koka ni kansuru kisoteki kento

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, T; Murakami, T; Ogata, S; Sakamoto, I [Traffic Safety and Nuisance Research Inst., Tokyo (Japan)

    1997-10-01

    As a new test facility to clarify noise reduction method of tire road noise, Tire Road Noise Chassis-Dynamometer Simulator was developed. ISO surface replica pads made by copying the texture of ISO surface were attached on the roller surface of this system to simulate tire road noise. This paper described the specifications and characteristics of this system, and the effects of ISO surface replica pads on tire noise measurement by comparing the sound intensity in horizontal plane of tire noise measured in this system with that measured in a single drum tester with safety walk surface. 4 refs., 10 figs., 1 tab.

  16. Research report for fiscal 1998. Industrial circles' evaluation of the outcome of COP3 and their response thereto (France); 1998 nendo chosa hokokusho. COP3 no kekka ni taisuru sangyokai no hyoka oyobi kongo no taio ni tsuite (France)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Since the CO{sub 2} emission reduction cost is high under the COP3 (Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change) rulings, they have made it clear that they will positively resort to the flexibility mechanism. This is to reserve a room for freely selecting power generation methods other than nuclear technologies with their nuclear power plants scheduled for renovation in the neighborhood of 2010. But the industrial circles are slow in responding, failing to accept the carbon fund concept. As for measures for greenhouse gas emissions reduction, since they depend on energy saving for their success, the response specially of the transportation division will be the key. In the industrial division, success depends on a voluntary consensus among industries that consume much energy. As steps to economize the trend of people's energy consumption, an energy tax and environmental tax are scheduled to be imposed. An overall program for greenhouse gas emission reduction is being drafted by a government committee, with the outline to be made known in May 1999 for finalization in autumn the same year. A power market liberalization bill has already been prepared, and a decision will soon be made on a plan for the second phase targets. France with take part in COP5, Bonn, Germany, with a general proposal carrying what are stated above. (NEDO)

  17. Research report of fiscal 1997. Research on building up of a NEDO vision (summary of subsidy researches and their future direction); 1997 nendo chosa hokokusho. NEDO vision no sakutei ni muketa chosa (kofukin chosa no matome to kongo no hosaku ni tsuite)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The planning department of NEDO is required to control development sections, and present the basic policy of activities. The department has thus carried out the following subsidy researches: medium/long-range introduction of new energies, study on the NEDO vision, excavation of concrete project seeds and effective use of its result, systematic preparation of basic data on new energy and energy saving. These subsidy researches sums to 480 for the first 17 years. The department now summarized each previous research data for easy understanding, and constructed the system which can systematically arrange data on future subsidy researches. The department also facilitated building up of the NEDO vision by proposing the direction of future subsidy researches, and prepared a database of the subsidy research reports. The trend of the researches was analyzed by systematically classifying the research results, and an easy retrieval system was constructed by giving retrieval codes to each data. The basic direction of a future research policy and effective use of research results is proposed. 23 figs., 7 tabs.

  18. Experimental model for architectural systematization and its basic thermal performance. Part 1. Research on architectural systematization of energy conversion devices; Kenchiku system ka model no gaiyo to kihon seino ni tsuite. 1. Energy henkan no kenchiku system ka ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Sunaga, N; Ito, N; Kimura, G; Fukao, S; Shimizu, T; Tsunoda, M; Muro, K [Tokyo Metropolitan University, Tokyo (Japan)

    1996-10-27

    The outline of a model for architectural systematization of natural energy conversion and the experiment result on the basic thermal performance in winter are described. The model is about 20 m{sup 2} in floor space. Foam polystyrene of 100 mm and 200 mm thick was used for the outer wall as heat insulating materials. The model has a solar battery and air conditioner and uses red brick as a heat reservoir. An experiment was made on seven modes obtained when three elements (heating, heat storage, and night insulated door) are combined. The information obtained by the experiment showed that a model for architectural systematization has high heat insulation and tightness and can be used as an energy element or an evaluation model for architectural systematization. In this model for architectural systematization, the power consumption of an air conditioner in winter can be fully supplied by only the power generation based on a solar battery. In an architectural element, the heating energy consumption can be remarkably reduced and the indoor thermal environment can be greatly improved, by the combination of a heat reservoir and night heat insulated door. 1 ref., 6 figs., 3 tabs.

  19. Study on flow the impeller outlet of a winnowing fan. 1st Report. Comparisons on the flow between experiments and CFD; Karami fan no haneguruma deguchibu kinbo no nagare ni kansuru kenkyu. 1. Hane shuhen no nagare ni tsuite no CFD to jikkenchitono hikaku

    Energy Technology Data Exchange (ETDEWEB)

    Kawase, M. [Tokushima University, Tokushima (Japan); Fukutomi, J.; Nakase, Y. [Tokushima University, Tokushima (Japan). Faculty of Engineering

    2000-03-25

    The winnowing fan used for head feeding type combines draw in air along the axis from the inlet of both sides, and then radially discharges it into scroll. Therefore, the internal flow of this fan shows a strong three-dimensionality and the efficiency is low. In order to improve the efficiency and make the axial distribution of discharge flow uniform, the experimental and numerical investigations were carried out. Numerical results using CFD agree well with experimental ones for the mean flow. It is found that this numerical simulation method is useful for investigation of the effect of blade and casing configurations. Moreover unsteady flow conditions in the impeller though rotations are shown. For example, in the impeller, a vortex formed around the leading edge of the blade, grows connect with another one, reduce and disappear. (author)

  20. Ni4Ti3 precipitate structures in Ni-rich NiTi shape memory alloys

    Czech Academy of Sciences Publication Activity Database

    Holec, David; Bojda, Ondřej; Dlouhý, Antonín

    2008-01-01

    Roč. 481, Sp. Iss. (2008), s. 462-465 ISSN 0921-5093. [ESOMAT 2006. Bochum, 10.09.2006-15.09.2006] R&D Projects: GA ČR(CZ) GA106/05/0918 Institutional research plan: CEZ:AV0Z20410507 Keywords : NiTi shape memory alloys * Ni4Ti3 precipitates * Multi-step martensitic transformations Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.806, year: 2008

  1. Electronic structure of Ni-- and Ni2--ethylene cluster complexes

    International Nuclear Information System (INIS)

    Basch, H.; Newton, M.D.; Moskowitz, J.W.

    1978-01-01

    The electronic structure of metal cluster--ethylene complexes has been investigated by carrying out ab initio bonding pair-correlated, self-consistent field, and configuration interaction (CI) calculations on the NiC 2 H 4 and Ni 2 C 2 H 4 species. The π-NiC 2 H 4 and π-Ni 2 C 2 H 4 cluster complexes are found to be bound, the former only with CI, while disigma-Ni 2 C 2 H 4 has only a repulsive Ni 2 --C 2 H 4 ground state potential curve. The bonding in the π-type cluster complexes can be described as follows: The metal atom configuration is 3d 9 4s 1 with the 4s hybridized (by the metal 4p) away from the ethylene molecule, thereby allowing the π orbital to form a dative sigma bond with the metal atom. The bonding interaction is promoted by the presence of a second nickel atom behind the first one, leading to a 4s orbital electron deficiency of the bonded nickel atom and thus making this nickel atom a better electron acceptor. Back donation from the occupied metal 3d into the ethylene π* molecular orbital also takes place to some extent, and thus both features of the classical Dewar--Chatt--Duncanson model are observed. The π-Ni 2 C 2 H 4 species is analyzed in terms of the addition of a bare nickel atom to a π-NiC 2 H 4 cluster complex, with concomitant stabilization of the orbitals of the bonded nickel atom. A study of the excited electronic states of π-NiC 2 H 4 shows that low-lying 4s→π* and 3d→π* (M→L) charge transfer transitions are predicted. The former is not observed experimentally, probably due to the diffuse nature of the 4s orbital. The relationship between small cluster--ethylene complex systems and ethylene chemisorption on a nickel metal surface is discussed

  2. Radioactive 63Ni in biological research

    International Nuclear Information System (INIS)

    Kasprzak, K.S.; Sunderman, F.W. Jr.

    1979-01-01

    Applications of 63 Ni in biological research are reviewed, with emphasis upon recent investigations of nickel metabolism and toxicology in experimental animals. The radiochemistry of 63 Ni is summarized, including consideration of the preparation of certain 63 Ni compounds (e.g. 63 Ni(CO) 4 and 63 Ni 3 S 2 ) that are of current interest in toxicology, teratology and cancer research. Practical guidance is given regarding the detection and determination of 63 Ni in biological materials by autoradiography and liquid scintillation spectrometry. (author)

  3. Superstructure of NiAs

    International Nuclear Information System (INIS)

    Nozue, Tatsuhiro; Kobayashi, Hisao; Kamimura, Takashi; Yamaguchi, Yasuo

    2001-01-01

    The structural transition in NiAs was studied by neutron diffraction on the single crystalline sample. The crystal structure of NiAs has been reported to be bottom-centered orthorhombic with Cmc2 1 symmetry (niccolite-type). The measurement of temperature dependence of the powder X-ray diffraction revealed that NiAs undergoes a structural transition to the NiAs-type at T t =335 K. In present neutron diffraction experiment at room temperature, we observed the reflections indexed on the basis of the orthorhombic unit cell. The intensities of these reflections are qualitatively explained in terms of the niccolite-type structure with taking account of three domain structures, except for the weak reflections indexed as (001), (003) and (012). Then, the intensities of (001), (002) and (004) reflections were measured in temperature range of 20 to 420 K. The temperature dependences of (002) and (004) reflections qualitatively agree with those of the calculated intensities using the atomic positions of niccolite-type structure. However, the temperature dependence of (001) reflection shows the anomaly around T t , which suggests the symmetry of crystal structure of NiAs is not the Cmc2 1 symmetry. (author)

  4. Thermal stability and electrical characteristics of NiSi films with electroplated Ni(W) alloy

    International Nuclear Information System (INIS)

    Xin Yuhang; Hu Anmin; Li Ming; Mao Dali

    2011-01-01

    In this study, an electroplating method to deposited Ni, crystalline NiW(c-NiW), amorphous NiW (a-NiW) films on P-type Si(1 0 0) were used to form Ni-silicide (NiSi) films. After annealed at various temperatures, sheet resistance of Ni/Cu, c-NiW/Cu and a-NiW/Cu was measured to observe the performance of those diffusion barrier layers. With W added in the barrier layer, the barrier performance was improved. The results of XRD and resistance measurement of the stacked Si/Ni(W)/Cu films reveal that Cu atom could diffuse through Ni barrier layer at 450 deg. C, could diffuse through c-NiW at 550 deg. C, but could hardly diffuse through a-NiW barrier layer. c-NiW layer has a better barrier performance than Ni layer, meanwhile the resistance is lower than a-NiW layer.

  5. Giant magnetoimpedance effect in sputtered single layered NiFe film and meander NiFe/Cu/NiFe film

    International Nuclear Information System (INIS)

    Chen, L.; Zhou, Y.; Lei, C.; Zhou, Z.M.; Ding, W.

    2010-01-01

    Giant magnetoimpedance (GMI) effect on NiFe thin film is very promising due to its application in developing the magnetic field sensors with highly sensitivity and low cost. In this paper, the single layered NiFe thin film and NiFe/Cu/NiFe thin film with a meander structure are prepared by the MEMS technology. The influences of sputtering parameters, film structure and conductor layer width on GMI effect in NiFe single layer and meander NiFe/Cu/NiFe film are investigated. Maximum of the GMI ratio in single layer and sandwich film is 5% and 64%, respectively. The results obtained are useful for developing the high-performance magnetic sensors based on NiFe thin film.

  6. High Ni in Archean tholeiites

    Science.gov (United States)

    Arndt, Nicholas T.

    1991-03-01

    Archean tholeiites generally have higher Ni, Co. Cr and Fe than most younger tholeiites with similar MgO contents. These characteristics cannot be attributed to high T or P batch melting in the Archean mantle, because, although such melts are enriched in siderophile elements, they have higher MgO than normal tholeiites. As primary melts fractionate to lower MgO, they lose Ni, Co and Cr. Nor can the differences between Archean and younger tholeiites be attributed to secular variation in mantle compositions because Archean komatiites have Ni, Co, Cr contents similar to modern (Gorgona) komatiites. It is suggested that the high siderophile element content of Archean tholeiites results from mixing of either komatiitic with basaltic magmas, as might occur in an ascending, melting mantle plume or column, or of komatiite and more evolved rocks, as may take place when komatiite encounters and assimilates crustal rocks.

  7. Relation between shape of Ni-particles and Ni migration in Ni-YSZ electrodes – a hypothesis

    DEFF Research Database (Denmark)

    Mogensen, Mogens Bjerg; Hauch, Anne; Sun, Xiufu

    2016-01-01

    This is an attempt to explain a phenomenon of total depletion of Ni next to the electrolyte in Ni-YSZ cermet electrodes in solid oxide electrolysis cells during electrolysis at high current density/overpotential. Intuitively, we would think that Ni would always migrate down the steam partial...

  8. Ni-NiO core-shell inverse opal electrodes for supercapacitors.

    Science.gov (United States)

    Kim, Jae-Hun; Kang, Soon Hyung; Zhu, Kai; Kim, Jin Young; Neale, Nathan R; Frank, Arthur J

    2011-05-14

    A general template-assisted electrochemical approach was used to synthesize three-dimensional ordered Ni core-NiO shell inverse opals (IOs) as electrodes for supercapacitors. The Ni-NiO IO electrodes displayed pseudo-capacitor behavior, good rate capability and cycling performance. © The Royal Society of Chemistry 2011

  9. CONFIGURATION-INTERACTION IN NI METAL AND NI-ALLOYS AND HIGH-ENERGY SPECTROSCOPY

    NARCIS (Netherlands)

    TANAKA, A; JO, T; SAWATZKY, GA

    We discuss the electronic state of Ni atoms in Ni metal and of Ni impurity in Cu and Au metals from the viewpoint of 3d configuration interaction (CI) using the Anderson impurity model including atomic multiplets. On the basis of the discussion, we give an interpretation for the Ni 2p-core X-ray

  10. Iodine capture by Hofmann-type clathrate Ni(II)(pz)[Ni(II)(CN)_4

    International Nuclear Information System (INIS)

    Massasso, Giovanni; Long, Jerome; Haines, Julien; Devautour-Vinot, Sabine; Maurin, Guillaume; Larionova, Joulia; Guerin, Christian; Guari, Yannick; Grandjean, Agnes; Onida, Barbara; Donnadieu, Bruno

    2014-01-01

    The thermally stable Hofmann-type clathrate framework Ni(II)(pz)[Ni(II)(CN)_4] (pz = pyrazine) was investigated for the efficient and reversible sorption of iodine (I_2) in the gaseous phase and in solution with a maximum adsorption capacity of 1 mol of I_2 per 1 mol of Ni(II)pz)[Ni(II)(CN)_4] in solution. (authors)

  11. Density functional theory study of the interfacial properties of Ni/Ni3Si eutectic alloy

    International Nuclear Information System (INIS)

    Zhao, Yuhong; Wen, Zhiqin; Hou, Hua; Guo, Wei; Han, Peide

    2014-01-01

    In order to clarify the heterogeneous nucleation potential of α-Ni grains on Ni 3 Si particles in Ni-Ni 3 Si eutectic alloy, the work of adhesion (W ad ), fracture toughness (G), interfacial energy (γ i ), and electronic structure of the index (0 0 1), (1 1 0) and (1 1 1) Ni/Ni 3 Si interfaces with two different cohesive manners are investigated using first-principles method based on density functional theory. Results indicate that the center site stacking sequence (OM) is preferable to continue the natural stacking sequence of bulk Ni and Ni 3 Si. Since OM stacking interfaces have larger W ad , G and γ i than that of the top site stacking (OT) interfaces. The Ni/Ni 3 Si (1 1 0) interface with OM stacking has the best mechanical properties. Therefore, the formation of this interface can improve the stability, ductility and fracture toughness of Ni-Ni 3 Si eutectic alloy. The calculated interfacial energy of Ni/Ni 3 Si (0 0 1), (1 1 0) and (1 1 1) interfaces with OM stacking proves the excellent nucleation potency of Ni 3 Si particles for α-Ni phase from thermodynamic considerations. Besides, the electronic structure and chemical bonding of (1 1 0) interface with OM stacking are also discussed.

  12. Density of Liquid Ni-Cr Alloy

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The density of liquid Ni-Cr alloy was measured by a modified sessile drop method. The density of liquid Ni-Cr alloywas found to decrease with increasing temperature and Cr concentration in the alloy. The molar volume of liquidNi-Cr alloy increases with increasing the Cr concentration in the alloy. The molar volume of Ni-Cr alloy determinedin the present work shows a positive deviation from the linear molar volume.

  13. Laser alloyed Al-Ni-Fe coatings

    CSIR Research Space (South Africa)

    Pityana, SL

    2008-10-01

    Full Text Available The aim of this work was to produce crack-free thin surface layers consisting of binary (Al-Ni, Al-Fe) and ternary (Al-Ni-Fe) intermetallic phases by means of a high power laser beam. The laser surface alloying was carried out by melting Fe and Ni...

  14. Nanostructure analysis of friction welded Pd-Ni-P/Pd-Cu-Ni-P metallic glass interface

    International Nuclear Information System (INIS)

    Ohkubo, T.; Shoji, S.; Kawamura, Y.; Hono, K.

    2005-01-01

    Friction welded Pd 40 Ni 40 P 20 /Pd 40 Cu 30 Ni 10 P 20 metallic glass interface has been characterized by energy filtering transmission electron microscopy. The interface is fully amorphous with a gradual compositional change of Cu and Ni in the range of 30 nm. By annealing above T g , the interdiffusion of Cu and Ni progressed in the supercooled liquid region, and the crystallization occurred from the Pd 40 Ni 40 P 20 glass

  15. Study of dipole interaction in micron-width NiFe/Cu/NiFe/NiO wire using exchange anisotropy

    International Nuclear Information System (INIS)

    Kimura, Takashi; Itagaki, Yoshio; Wakaya, Fujio; Gamo, Kenji

    2001-01-01

    The dipole interaction between a NiFe layer pinned by a NiO and a free NiFe layer in a micron-wide NiFe/Cu/NiFe/NiO wire was studied by changing the direction of the exchange bias from the NiO layer. The effect of the dipole interaction when the exchange bias was perpendicular to the wire axis was larger than that when the exchange bias was parallel to the wire axis, and was consistently explained by the stray field caused by the magnetic charges of the pinned layer. It was demonstrated that this method, using exchange anisotropy, is useful for investigating the dipole interaction between ferromagnetic materials separated by a nonmagnetic material in small-scale magnetic multilayers. [copyright] 2001 American Institute of Physics

  16. Effects of Ni particle morphology on cell performance of Na/NiCl2 battery

    Science.gov (United States)

    Kim, Mangi; Ahn, Cheol-Woo; Hahn, Byung-Dong; Jung, Keeyoung; Park, Yoon-Cheol; Cho, Nam-ung; Lee, Heesoo; Choi, Joon-Hwan

    2017-11-01

    Electrochemical reaction of Ni particle, one of active cathode materials in the Na/NiCl2 battery, occurs on the particle surface. The NiCl2 layer formed on the Ni particle surface during charging can disconnect the electron conduction path through Ni particles because the NiCl2 layer has very low conductivity. The morphology and size of Ni particles, therefore, need to be controlled to obtain high charge capacity and excellent cyclic retention. Effects of the Ni particle size on the cell performance were investigated using spherical Ni particles with diameters of 0.5 μm, 6 μm, and 50 μm. The charge capacities of the cells with spherical Ni particles increased when the Ni particle size becomes smaller because of their higher surface area but their charge capacities were significantly decreased with increasing cyclic tests owing to the disconnection of electron conduction path. The inferior cyclic retention of charge capacity was improved using reticular Ni particles which maintained the reliable connection for the electron conduction in the Na/NiCl2 battery. The charge capacity of the cell with the reticular Ni particles was higher than the cell with the small-sized spherical Ni particles approximately by 26% at 30th cycle.

  17. One dimensional motion of interstitial clusters and void growth in Ni and Ni alloys

    Science.gov (United States)

    Yoshiie, T.; Ishizaki, T.; Xu, Q.; Satoh, Y.; Kiritani, M.

    2002-12-01

    One dimensional (1-D) motion of interstitial clusters is important for the microstructural evolution in metals. In this paper, the effect of 2 at.% alloying with elements Si (volume size factor to Ni: -5.81%), Cu (7.18%), Ge (14.76%) and Sn (74.08%) in Ni on 1-D motion of interstitial clusters and void growth was studied. In neutron irradiated pure Ni, Ni-Cu and Ni-Ge, well developed dislocation networks and voids in the matrix, and no defects near grain boundaries were observed at 573 K to a dose of 0.4 dpa by transmission electron microscopy. No voids were formed and only interstitial type dislocation loops were observed near grain boundaries in Ni-Si and Ni-Sn. The reaction kinetics analysis which included the point defect flow into planar sink revealed the existence of 1-D motion of interstitial clusters in Ni, Ni-Cu and Ni-Ge, and lack of such motion in Ni-Si and Ni-Sn. In Ni-Sn and Ni-Si, the alloying elements will trap interstitial clusters and thereby reduce the cluster mobility, which lead to the reduction in void growth.

  18. First-principles calculations for the elastic properties of Ni-base model superalloys: Ni/Ni3Al multilayers

    International Nuclear Information System (INIS)

    Yun-Jiang, Wang; Chong-Yu, Wang

    2009-01-01

    A model system consisting of Ni[001](100)/Ni 3 Al[001](100) multi-layers are studied using the density functional theory in order to explore the elastic properties of single crystal Ni-based superalloys. Simulation results are consistent with the experimental observation that rafted Ni-base superalloys virtually possess a cubic symmetry. The convergence of the elastic properties with respect to the thickness of the multilayers are tested by a series of multilayers from 2γ'+2γ to 10γ'+10γ atomic layers. The elastic properties are found to vary little with the increase of the multilayer's thickness. A Ni/Ni 3 Al multilayer with 10γ'+10γ atomic layers (3.54 nm) can be used to simulate the mechanical properties of Ni-base model superalloys. Our calculated elastic constants, bulk modulus, orientation-dependent shear modulus and Young's modulus, as well as the Zener anisotropy factor are all compatible with the measured results of Ni-base model superalloys R1 and the advanced commercial superalloys TMS-26, CMSX-4 at a low temperature. The mechanical properties as a function of the γ' phase volume fraction are calculated by varying the proportion of the γ and γ' phase in the multilayers. Besides, the mechanical properties of two-phase Ni/Ni 3 Al multilayer can be well predicted by the Voigt–Reuss–Hill rule of mixtures. (classical areas of phenomenology)

  19. Flowsheet for 63Ni production

    International Nuclear Information System (INIS)

    Williams, D.F.; Knauer, J.B.; O'Kelley, G.D.; Wiggins, J.T.; Porter, C.E.

    1992-01-01

    The production of large quantities of high specific activity 63 Ni (>10Ci/g) requires both a highly enriched 62 Ni target and a long irradiation period at high neutron flux. Trace impurities in the nickel and associated target materials are also activated and account for a significant fraction of the discharged activity and essentially all of the gamma activity. While most of these undesirable activation products (mainly transition metals) can be easily removed as chloride complexes during anion exchange, chromium, present as 51 Cr, and manganese, present as 54 Mn, are exceptions and require solvent extraction of the in-cell product to achieve the desired purity. In addition to summarizing the current development and production experience, optimized flowsheets are discussed

  20. Microstructural investigations of Ni and Ni2Al3 coatings exposed in biomass power plants

    DEFF Research Database (Denmark)

    Wu, D. L.; Dahl, K. V.; Christiansen, T. L.

    2018-01-01

    The present work investigates the corrosion resistance of Ni and Ni2Al3 coated austenitic stainless steel (TP347H) tubes, which were exposed in a biomass-fired boiler with an outlet steam temperature of 540 °C for 6757 h. The Ni2Al3 coating was produced by electroplating Ni followed by low...... temperature pack cementation. After exposure, microstructural investigations were performed by light optical and electron microscopy (SEM-EDS). Electroplated Ni coatings were not protective in straw firing power plants and exhibited similar corrosion morphology as uncoated tubes. For Ni2Al3 coatings...

  1. Influence of ni thickness on oscillation coupling in Cu/Ni multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Gagorowska, B; Dus-Sitek, M [Institute of Physics, Czestochowa University of Technology, Al. Armii Krajowej 19, 42-200 Czestochowa (Poland)

    2007-08-15

    The results of investigation of magnetic properties of [Cu/Ni]x100 were presented. Samples were deposited by face-to-face sputtering method onto the silicon substrate, the thickness of Cu layer was constant (d{sub Cu} = 2 nm) and the thickness of Ni layer - variable (1 nm {<=} d{sub Ni} {<=} 6 nm). In Cu/Ni multilayers, for the thickness of Ni layer bigger than 2 nm antiferromagnetic coupling (A-F) were observed, for the thickness of Ni smaller than 2 nm A-F coupling is absent.

  2. Influence of ni thickness on oscillation coupling in Cu/Ni multilayers

    International Nuclear Information System (INIS)

    Gagorowska, B; Dus-Sitek, M

    2007-01-01

    The results of investigation of magnetic properties of [Cu/Ni]x100 were presented. Samples were deposited by face-to-face sputtering method onto the silicon substrate, the thickness of Cu layer was constant (d Cu = 2 nm) and the thickness of Ni layer - variable (1 nm ≤ d Ni ≤ 6 nm). In Cu/Ni multilayers, for the thickness of Ni layer bigger than 2 nm antiferromagnetic coupling (A-F) were observed, for the thickness of Ni smaller than 2 nm A-F coupling is absent

  3. Exclusive study of Ni+Ni and Ni+Au central collisions: phase coexistence and spinodal decomposition; Etude exclusive des collisions centrales Ni+Ni et Ni+Au: coexistence de phase et decomposition spinodale

    Energy Technology Data Exchange (ETDEWEB)

    Guiot, B

    2002-12-01

    The INDRA multidetector allowed us to study the Ni+Ni collisions at 32A MeV and the Ni+Au collisions at 52,4 MeV. Central collisions leading to 'quasi-fused' systems were isolated using multidimensional analysis techniques: the Discriminant Analysis and the Principal Component Analysis. Comparison with a statistical model shows that the selected events are compatible with thermodynamical equilibrium. The average thermal excitation energy is 5A MeV for both systems. Calculations of heat capacities show that the deexcitation of the hot sources are akin to a liquid-gas phase transition of nuclear matter. Indeed heat capacities exhibit a negative branch as expected for a phase transition of a finite system. The dynamics of this phase transition has been investigated by applying the charge correlation method. An enhanced production of events with equal-sized fragments has been evidenced for Ni+Au at 52A MeV. No signal was found for Ni+Ni at 32A MeV. Finally this method was improved by taking into account the total charge conservation. The signal is seen more clearly for Ni+Au at 52A MeV, but is ambiguous for Ni+Ni at 32A MeV. The path followed in the state diagram, or the involved time scales, seem to be different for these systems. (authors)

  4. niños preescolares

    Directory of Open Access Journals (Sweden)

    Claudia Rosario Portilla Ramírez

    2007-01-01

    Full Text Available Este estudio explora la relación entre la escritura y la comprensión de la referencia a través de una tarea de sinonimia en niños entre 5 y 6 años de edad, de origen latinoamericano, escolarizados en Barcelona (España. Las variables relacionadas con la tarea de sinonimia fueron (a la comprensión de la entidad lingüística nombre y (b el nivel de conceptualización de la escritura de los niños y la presencia de etiquetas escritas durante la tarea. Para la tarea de sinonimia se utilizaron pares de sinónimos dialectales del español (de Latinoamérica y de la Península Ibérica. Los resultados mostraron una diferenciación en el razonamiento de los niños, la cual dependía de la comparación entre lenguaje oral y lenguaje escrito en el desarrollo de la tarea, evidenciando una mayor aceptación de la sinonimia en la modalidad de lenguaje oral que en la modalidad de lenguaje escrito.

  5. Reinvestigation of 56Ni decay

    International Nuclear Information System (INIS)

    Sur, B.; Norman, E.B.; Lesko, K.T.; Browne, E.; Larimer, R.

    1990-01-01

    In a series of experiments, we have reinvestigated the decay of the doubly magic nucleus 56 Ni, which is believed to be copiously produced in supernovae. We have confirmed its previously known decay scheme and half-life, and have searched for several rare decay modes. We establish an upper limit of 5.8x10 -7 for the branching ratio of the second forbidden unique β + decay to the 158-keV level in 56 Co, leading to a lower limit of 2.9x10 4 yr for the half-life of fully ionized 56 Ni nuclei in cosmic rays. We also establish an upper limit of 5.0x10 -3 for the branching ratio of the isospin forbidden Fermi electron capture transition to the 1451-keV level in 56 Co, which in turn leads to an upper limit of 124 keV for the isospin mixing Coulomb matrix element of the 56 Ni ground state

  6. On the nature of Ni···Ni interaction in a model dimeric Ni complex.

    Science.gov (United States)

    Kamiński, Radosław; Herbaczyńska, Beata; Srebro, Monika; Pietrzykowski, Antoni; Michalak, Artur; Jerzykiewicz, Lucjan B; Woźniak, Krzysztof

    2011-06-07

    A new dinuclear complex (NiC(5)H(4)SiMe(2)CHCH(2))(2) (2) was prepared by reacting nickelocene derivative [(C(5)H(4)SiMe(2)CH=CH(2))(2)Ni] (1) with methyllithium (MeLi). Good quality crystals were subjected to a high-resolution X-ray measurement. Subsequent multipole refinement yielded accurate description of electron density distribution. Detailed inspection of experimental electron density in Ni···Ni contact revealed that the nickel atoms are bonded and significant deformation of the metal valence shell is related to different populations of the d-orbitals. The existence of the Ni···Ni bond path explains the lack of unpaired electrons in the complex due to a possible exchange channel.

  7. Synthesis of Ni core NiO shell nanostructure and magnetic investigation for shell thickness determination

    International Nuclear Information System (INIS)

    Arabi, H.; Bruck, E.; Tichelaar, F.D.

    2007-01-01

    Full text: Nickel oxide has received a considerable amount of attention in recent years for its catalytic, electronic and magnetic properties. Ni nanoparticles with an average size of 8 nm were prepared by dc - arc discharge in argon atmosphere. A current of 130 A and 300 milli bar pressure of argon have been applied. The produced Ni nanoparticles were annealed for oxidizing in air at 350 for six hours to produce antiferromagnetic NiO particles. The structure of Ni and NiO nanoparticles and size estimation of them studied by means of X-ray diffraction. The size and morphology of the particles were also characterized by high resolution transmission microscopy (TEM). The Ni core NiO shell structure, resulting from the oxidation process, were studied by magnetic properties measurements. A quantum design squid magnetometer, model MPMS5S was used for measuring saturation magnetization of both nanoparticles of Ni with and without NiO layer. By knowing the density of Ni and NiO, we were able to deduce the thickness of the Ni core and NiO outer layer. They are around 3 and 5 nanometers respectively. (authors)

  8. Exclusive study of Ni+Ni and Ni+Au central collisions: phase coexistence and spinodal decomposition

    International Nuclear Information System (INIS)

    Guiot, B.

    2002-12-01

    The INDRA multidetector allowed us to study the Ni+Ni collisions at 32A MeV and the Ni+Au collisions at 52,4 MeV. Central collisions leading to 'quasi-fused' systems were isolated using multidimensional analysis techniques: the Discriminant Analysis and the Principal Component Analysis. Comparison with a statistical model shows that the selected events are compatible with thermodynamical equilibrium. The average thermal excitation energy is 5A MeV for both systems. Calculations of heat capacities show that the deexcitation of the hot sources are akin to a liquid-gas phase transition of nuclear matter. Indeed heat capacities exhibit a negative branch as expected for a phase transition of a finite system. The dynamics of this phase transition has been investigated by applying the charge correlation method. An enhanced production of events with equal-sized fragments has been evidenced for Ni+Au at 52A MeV. No signal was found for Ni+Ni at 32A MeV. Finally this method was improved by taking into account the total charge conservation. The signal is seen more clearly for Ni+Au at 52A MeV, but is ambiguous for Ni+Ni at 32A MeV. The path followed in the state diagram, or the involved time scales, seem to be different for these systems. (authors)

  9. Atomistic calculations of hydrogen interactions with Ni3Al grain boundaries and Ni/Ni3Al interfaces

    International Nuclear Information System (INIS)

    Baskes, M.I.; Angelo, J.E.; Moody, N.R.

    1995-01-01

    Embedded Atom Method (EAM) potentials have been developed for the Ni/Al/H system. The potentials have been fit to numerous properties of this system. For example, these potentials represent the structural and elastic properties of bulk Ni, Al, Ni 3 Al, and NiAl quite well. In addition the potentials describe the solution and migration behavior of hydrogen in both nickel and aluminum. A number of calculations using these potentials have been performed. It is found that hydrogen strongly prefers sites in Ni 3 Al that are surrounded by 6 Ni atoms. Calculations of the trapping of hydrogen to a number of grain boundaries in Ni 3 Al have been performed as a function of hydrogen chemical potential at room temperature. The failure of these bicrystals under tensile stress has been examined and will be compared to the failure of pure Ni 3 Al boundaries. Boundaries containing a preponderance of nickel are severely weakened by hydrogen. In order to investigate the potential embrittlement of γ/γ' alloys, trapping of hydrogen to a spherical Ni 3 Al precipate in nickel as a function of chemical potential at room temperature has been calculated. It appears that the boundary is not a strong trap for hydrogen, hence embrittlement in these alloys is not primarily due to interactions of hydrogen with the γ/γ interface

  10. Structural features in Ni-Al alloys

    International Nuclear Information System (INIS)

    Abylkalykova, R.B.; Kveglis, L.I.; Rakhimova, U.A.; Nasokhova, Sh.B.; Tazhibaeva, G.B.

    2007-01-01

    Purpose of the work is study of structural transformations under diverse memory effect in Ni-Al alloys. Examination were conducted in following composition samples: Ni -75 at.% and Al - 25 at.%. The work is devoted to clarification reasons both formation atom-ordered structures in inter-grain boundaries of bulk samples under temperature action and static load. Revealed inter-grain inter-boundary layers in Ni-Al alloy both bulk and surface state have complicated structure

  11. Compositional and structural characterisation of Ni-phyllosilicates in hydrous silicate type Ni-laterite deposits

    OpenAIRE

    Villanova de Benavent, Cristina

    2015-01-01

    Ni-bearing Mg-phyllosilicates (commonly known as garnierites) are significant ore minerals in many Ni-laterite deposits worldwide. However, the characterisation of these mineral phases is complex, as well as their classification and nomenclature, due to their fine-grained nature, low crystallinity and frequent occurrence as mixtures. The aim of this study is to shed some light to the nature of the Ni-bearing Mg-phyllosilicates occurring at the Falcondo Ni-laterite. In this deposit, these ...

  12. Thermal capture cross section for 58Ni (n,γ)59 Ni reaction

    International Nuclear Information System (INIS)

    Carbonari, A.W.; Pecequilo, B.R.S.

    1989-01-01

    The 58 Ni total thermal capture cross section was determined by suming the partial cross sections calculated for the primary transitions of the reaction 58 Ni (n,γ) 59 Ni. The primary transitions energies and intensities were determined from the 58 Ni thermal neutrons prompt gamma capture gamma rays spectrum in the 3.7 to 9.3 MeV region. The obtained value for the total cross section was 4.52 + 0.10b. (author) [pt

  13. Formation enthalpy of NiBe and Ni5Be21

    International Nuclear Information System (INIS)

    Ivanov, M.I.; Karpova, T.F.; Dalago, N.Yu.

    1981-01-01

    The method of dissolution calorimetry is used to determine standard enthalpies of NiBe and Ni 5 Be 21 formation, which are 84.8+-2.2 and (-669+-37)kJ/mol. The enthalpy values of NiBe and Ni 5 Be 21 at 331 K are shown to coincide (within the limits of errors of these values) with the values at the standard temperature of 298.15 K [ru

  14. Effects of Ni vacancy, Ni antisite, Cr and Pt on the third-order elastic constants and mechanical properties of NiAl

    KAUST Repository

    Wu, Shaohua; Wu, Xiaozhi; Wang, Rui; Liu, Qing; Gan, Liyong

    2014-01-01

    Effects of Ni vacancy, Ni antisite in Al sublattice, Cr in Al sublattice, Pt in Ni sublattice on the second-order elastic constants (SOECs) and third-order elastic constants (TOECs) of the B2 NiAl have been investigated using the first-principles methods. Lattice constant and the SOECs of NiAl are in good agreement with the previous results. The brittle/ductile transition map based on Pugh ratio G/B and Cauchy pressure Pc shows that Ni antisite, Cr, Pt and pressure can improve the ductility of NiAl, respectively. Ni vacancy and lower pressure can enhance the Vickers hardness Hv of NiAl. The density of states (DOS) and the charge density difference are also used to analysis the effects of vacancy, Ni antisite, Cr and Pt on the mechanical properties of NiAl, and the results are in consistent with the transition map. © 2014 Elsevier Ltd. All rights reserved.

  15. Effects of Ni vacancy, Ni antisite, Cr and Pt on the third-order elastic constants and mechanical properties of NiAl

    KAUST Repository

    Wu, Shaohua

    2014-12-01

    Effects of Ni vacancy, Ni antisite in Al sublattice, Cr in Al sublattice, Pt in Ni sublattice on the second-order elastic constants (SOECs) and third-order elastic constants (TOECs) of the B2 NiAl have been investigated using the first-principles methods. Lattice constant and the SOECs of NiAl are in good agreement with the previous results. The brittle/ductile transition map based on Pugh ratio G/B and Cauchy pressure Pc shows that Ni antisite, Cr, Pt and pressure can improve the ductility of NiAl, respectively. Ni vacancy and lower pressure can enhance the Vickers hardness Hv of NiAl. The density of states (DOS) and the charge density difference are also used to analysis the effects of vacancy, Ni antisite, Cr and Pt on the mechanical properties of NiAl, and the results are in consistent with the transition map. © 2014 Elsevier Ltd. All rights reserved.

  16. Creep and shrinkage of Mo(Ni)

    International Nuclear Information System (INIS)

    Kaysser, W.A.; Hofmann-Amtenbrink, M.; Petzow, G.

    1984-01-01

    To avoid some of the errors inherent in a quantitative interpretation of shrinkage of powder compacts as Mo-Ni, other experiments were looked for, where the influence of Ni on the material transport properties of Mo could be measured semi-quantitatively during heating up to temperature and subsequent isothermal annealing. The bending of thin Mo foils under small loads was found to be an experimental arrangement, where variations in stress, in Ni-concentration and in intrinsic material properties could be realized. The results of these creep experiments will be compared in a qualitative sense with sintering experiments in Mo-Ni done under similar conditions as the creep experiments

  17. Structure-activity relations for Ni-containing zeolites during NO reduction. II. Role of the chemical state of Ni

    NARCIS (Netherlands)

    Mosqueda Jimenez, B.I.; Jentys, A.; Seshan, Kulathuiyer; Lercher, J.A.

    2003-01-01

    The influence of the metal in Ni-containing zeolites used as catalysts for the reduction of NO with propane and propene was studied. In the fresh catalysts, Ni is located in ion exchange positions for Ni/MOR, Ni/ZSM-5, and Ni/MCM-22. The formation of carbonaceous deposits, the removal of Al from

  18. Ni-P/Zn-Ni compositionally modulated multilayer coatings - Part 2: Corrosion and protection mechanisms

    Science.gov (United States)

    Bahadormanesh, Behrouz; Ghorbani, Mohammad

    2018-06-01

    The Ni-P/Zn-Ni compositionally modulated multilayer coatings CMMCs were electrodeposited from a single bath by switching the deposition current density. The corrosion resistance of the deposits was studied and compared with that of monolayers of Ni-P and Zn-Ni alloys via Tafel polarization, EIS and salt spray tests. Characterization of corrosion products by means of EDS and XRD revealed more details from the corrosion mechanism of the monolayers and multilayers. The corrosion current density of Ni-P/Zn-Ni CMMCs were around one tenth of Zn-Ni monolayer. The CMMC with incomplete layers performed lower polarization resistance and higher corrosion current density compared to the CMMC with complete layers. The electrical circuit that was proposed for modeling the corrosion process based on the EIS spectrum, proved that layering reduces the porosity and consequently improves the barrier properties. Although, layering of Zn-Ni layers with Ni-P deposits increased the time to red rust in salt spray test, the time for white rust formation decreased. The corrosion mechanism of both Zn-Ni and Ni-P (containing small amount of Zn) was preferential dissolution of Zn and the corrosion products were comprised of mainly Zn hydroxychloride and Zn hydroxycarbonate. Also, Ni and P did not take part in the corrosion products. Based on the electrochemical character of the layers and the morphology of the corroded surface, the corrosion mechanism of multilayers was discussed.

  19. Joining of Ni-TiC FGM and Ni-Al Intermetallics by Centrifugal Combustion Synthesis

    International Nuclear Information System (INIS)

    Ohmi, Tatsuya; Matsuura, Kiyotaka; Iguchi, Manabu; Mizuma, Kiminori

    2008-01-01

    A centrifugal combustion synthesis (CCS) process has been investigated to join a Ni-Al intermetallic compound and a Ni-TiC cermet. The cermet, a tubular graphite mold, and a green compact of reactants consisting of Al, Ni and NiO were set in a centrifugal caster. When the combustion synthesis reaction was induced in the centrifugal force field, a synthesized molten Ni-Al alloy flowed into the graphite mold and joined to the cermet. The soundness of the joint interface depended on the volume percentage of TiC phase in the cermet. A lot of defects were formed near the interface between the Ni-TiC cermet and the cast Ni-Al alloy when the volume percentage of TiC was 50% or higher. For this kind of cermet system, using a functionally graded cermet such as Ni-10 vol.%TiC/Ni-25 vol.%TiC/Ni-50 vol.%TiC overcame this difficulty. The four-point bending strength of the joined specimen consisting of the three-layered FGM cermet and cast Ni-29 mol%Al alloy was 1010 MPa which is close to the result for a Ni-29 mol%Al alloy specimen

  20. Dynamic recovery in nanocrystalline Ni

    International Nuclear Information System (INIS)

    Sun, Z.; Van Petegem, S.; Cervellino, A.; Durst, K.; Blum, W.; Van Swygenhoven, H.

    2015-01-01

    The constant flow stress reached during uniaxial deformation of electrodeposited nanocrystalline Ni reflects a quasi-stationary balance between dislocation slip and grain boundary (GB) accommodation mechanisms. Stress reduction tests allow to suppress dislocation slip and bring recovery mechanisms into the foreground. When combined with in situ X-ray diffraction it can be shown that grain boundary recovery mechanisms play an important role in producing plastic strain while hardening the microstructure. This result has a significant consequence for the parameters of thermally activated glide of dislocations, such as athermal stress and activation volume, which are traditionally derived from stress/strain rate change tests

  1. Morphological control of Ni/NiO core/shell nanoparticles and production of hollow NiO nanostructures

    International Nuclear Information System (INIS)

    Chopra, Nitin; Claypoole, Leslie; Bachas, Leonidas G.

    2010-01-01

    Chemical synthesis coupled with a microwave irradiation process allowed for the control of size (6-40 nm), shape, and shell thickness of Ni/NiO core/shell nanoparticles. In this unique synthetic route, the size of Ni nanoparticles (NiNPs) was strongly influenced by the nickel salt-to-stabilizer ratio and the amount of the stabilizer. Interestingly, it was observed that the shape of the nanoparticles was altered by varying the reaction time, where longer reaction times resulted in annealing effects and rupture of the stabilizer micelle leading to distinct shapes of Ni/NiO core/shell nanostructures. Product cooling rate was another important parameter identified in this study that not only affected the shape, but also the crystal structure of the core/shell nanoparticles. In addition, a simple and cost-effective method of microwave irradiation of NiNPs led to the formation of distinctly shaped hollow NiO nanoparticles. These high surface area core/shell nanoparticles with well-controlled morphologies are important and can lead to significant advancement in the design of improved fuel cells, electrochromic display devices, and catalysis systems.

  2. Morphological control of Ni/NiO core/shell nanoparticles and production of hollow NiO nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Chopra, Nitin [University of Alabama, Department of Metallurgical and Materials Engineering, Center for Materials for Information Technology (MINT) (United States); Claypoole, Leslie [Fairmont State University (United States); Bachas, Leonidas G., E-mail: bachas@uky.ed [University of Kentucky, Department of Chemistry (United States)

    2010-10-15

    Chemical synthesis coupled with a microwave irradiation process allowed for the control of size (6-40 nm), shape, and shell thickness of Ni/NiO core/shell nanoparticles. In this unique synthetic route, the size of Ni nanoparticles (NiNPs) was strongly influenced by the nickel salt-to-stabilizer ratio and the amount of the stabilizer. Interestingly, it was observed that the shape of the nanoparticles was altered by varying the reaction time, where longer reaction times resulted in annealing effects and rupture of the stabilizer micelle leading to distinct shapes of Ni/NiO core/shell nanostructures. Product cooling rate was another important parameter identified in this study that not only affected the shape, but also the crystal structure of the core/shell nanoparticles. In addition, a simple and cost-effective method of microwave irradiation of NiNPs led to the formation of distinctly shaped hollow NiO nanoparticles. These high surface area core/shell nanoparticles with well-controlled morphologies are important and can lead to significant advancement in the design of improved fuel cells, electrochromic display devices, and catalysis systems.

  3. Continuum mechanics simulations of NiO/Ni-YSZ composites during reduction and re-oxidation

    DEFF Research Database (Denmark)

    Pihlatie, Mikko; Frandsen, Henrik Lund; Kaiser, Andreas

    2010-01-01

    for the dimensional change arises from the volumetric change related to the phase change NiO ↔ Ni. The measurable change in bulk length is given by the ceramic YSZ backbone as a response to the stress created by the chemical strain. The different subprocesses described in the model for YSZ were elastic and anelastic...... expansion, diffusional creep, grain boundary sliding (GBS) and microcracking due to excessive stress. In the Ni/NiO phase, nonelastic strains in terms of diffusional and power law creep were implemented, and additionally for NiO deformation due to microcracking and/or pseudoplasticity. Semi...

  4. Niños y niñas como cuidadores familiares

    OpenAIRE

    María Rosa Estupiñán Aponte

    2015-01-01

    En el contexto familiar, el cuidado de otra persona por parte de niños y niñas constituye un terreno inexplorado tanto en su significado como en las implicaciones que podrían darse en el proceso. Aunque históricamente se ha asignado el cuidado familiar a las mujeres generando condiciones de inequidad, incrementada con los cambios sociales de los últimos tiempos, es necesario reconocer que en muchos hogares niños y niñas se han visto obligados a desempeñar esta labor sin la preparación ni las ...

  5. .';.:NI~

    African Journals Online (AJOL)

    al wat ons werd was. Na middagete op 29 Junie, is ek per kar suid om die grand te gaan besigtig en om te sien hoe my stellings, van die vyandelike oogpunt, daaruit .... van Gatt se optrede moes die. Nieu-Seelanders, in 'n briljante nagaanval, met gevelde bajonette, 'n weg baan deur die vyand am daardie nag te ontvlug.

  6. Water dissociation on Ni(100) and Ni(111): Effect of surface temperature on reactivity

    International Nuclear Information System (INIS)

    Seenivasan, H.; Tiwari, Ashwani K.

    2013-01-01

    Water adsorption and dissociation on Ni(100) and Ni(111) surfaces are studied using density functional theory calculations. Water adsorbs on top site on both the surfaces, while H and OH adsorb on four fold hollow and three fold hollow (fcc) sites on Ni(100) and Ni(111), respectively. Transition states (TS) on both surfaces are identified using climbing image-nudged elastic band method. It is found that the barrier to dissociation on Ni(100) surface is slightly lower than that on Ni(111) surface. Dissociation on both the surfaces is exothermic, while the exothermicity on Ni(100) is large. To study the effect of lattice motion on the energy barrier, TS calculations are performed for various values of Q (lattice atom coordinate along the surface normal) and the change in the barrier height and position is determined. Calculations show that the energy barrier to reaction decreases with increasing Q and increases with decreasing Q on both the surfaces. Dissociation probability values at different surface temperatures are computed using semi-classical approximation. Results show that the influence of surface temperature on dissociation probability on the Ni(100) is significantly larger compared to that of Ni(111). Moreover, on Ni(100), a dramatic shift in energy barrier to lower incident energy values is observed with increasing surface temperature, while the shift is smaller in the case of Ni(111)

  7. Creatividad en niños superdotados

    OpenAIRE

    González Román, María del Pilar

    1992-01-01

    Se ha realizado un estudio sobre la creatividad en los niños superdotados. Analizándose los diferentes modelos de creatividad y superdotacion avalados por un estudio empírico, en el cual se han valorado las diferencial que existen entre los niños superdotados y contraste a nivel verbal y grafico-espacial.

  8. Preparation of one-step NiO/Ni-CGO composites using factorial design

    International Nuclear Information System (INIS)

    Araujo, A.J.M. de; Sousa, A R.O. de; Camposa, L.F.A.; Macedo, D.A.; Loureiro, F. J.A.; Fagg, D.P.

    2016-01-01

    This work deals with the synthesis, processing and characterization of NiO/Ni- CGO composite materials as potential solid oxide fuel cell (SOFC) anodes. The particulate materials were obtained by a one-step synthesis method and characterized by thermal analysis (prior to calcination) and X-ray diffraction (calcined powder). The ceramic processing of samples containing from 30 to 70 wt.% NiO was carried out by factorial design. Besides the NiO content controlled during the chemical synthesis, the impacts of the pore-former content (citric acid, used in proportions of 0, 7.5 and 15 wt.%) and the sintering temperature (1300, 1350 and 1400 °C) were also investigated. The open porosity of NiO-CGO composites and reduced Ni-CGO cermets was modeled as a function of factors (NiO content, citric acid content and sintering temperature) and interaction of factors. (author)

  9. Nanoscale structural heterogeneity in Ni-rich half-Heusler TiNiSn

    International Nuclear Information System (INIS)

    Douglas, Jason E.; Pollock, Tresa M.; Chater, Philip A.; Brown, Craig M.; Seshadri, Ram

    2014-01-01

    The structural implications of excess Ni in the TiNiSn half-Heusler compound are examined through a combination of synchrotron x-ray and neutron scattering studies, in conjunction with first principles density functional theory calculations on supercells. Despite the phase diagram suggesting that TiNiSn is a line compound with no solid solution, for small x in TiNi 1+x Sn there is indeed an appearance—from careful analysis of the scattering—of some solubility, with the excess Ni occupying the interstitial tetrahedral site in the half-Heusler structure. The analysis performed here would point to the excess Ni not being statistically distributed, but rather occurring as coherent nanoclusters. First principles calculations of energetics, carried out using supercells, support a scenario of Ni interstitials clustering, rather than a statistical distribution.

  10. Microstructural evolution of Ni40Zr60 alloy during early stage of mechanical alloying of intermetallic compounds NiZr2 and Ni11Zr9

    International Nuclear Information System (INIS)

    Lee Peeyew; Koch, C.C.

    1994-01-01

    The microstructural change of Ni 40 Zr 60 alloy during mechanical alloying of mixtures of the intermetallic compounds NiZr 2 and Ni 11 Zr 9 has been studied by transmission electron microscopy. A specific ''cauliflower'' phase was formed during early stage of mechanical alloying process. It is suggested that the solid state reaction between intermetallic compounds NiZr 2 and Ni 11 Zr 9 is not the only origin for the formation of the ''cauliflower'' phase. ((orig.))

  11. Microstructure and tribological properties of NiMo/Mo2Ni3Si intermetallic 'in-situ' composites

    International Nuclear Information System (INIS)

    Gui Yongliang; Song Chunyan; Yang Li; Qin Xiaoling

    2011-01-01

    Research highlights: → Wear resistant NiMo/Mo 2 Ni 3 Si intermetallic 'in-situ' composites was fabricated successfully with Mo-Ni-Si powder blends as the starting materials. Microstructure of the NiMo/Mo 2 Ni 3 Si composites consists of Mo 2 Ni 3 Si primary dendrites, binary intermetallic phase NiMo and small amount of Ni/NiMo eutectics structure. The NiMo/Mo 2 Ni 3 Si composites exhibited high hardness and outstanding tribological properties under room-temperature dry-sliding wear test conditions which were attributed to the covalent-dominant strong atomic bonds and excellent combination of strength and ductility and toughness. - Abstract: Wear resistant NiMo/Mo 2 Ni 3 Si intermetallic 'in-situ' composites with a microstructure of ternary metal silicide Mo 2 Ni 3 Si primary dendritic, the long strip-like NiMo intermetallic phase, and a small amount of Ni/NiMo eutectics structure were designed and fabricated using molybdenum, nickel and silicon elemental powders. Friction and wear properties of NiMo/Mo 2 Ni 3 Si composites were evaluated under different contact load at room-temperature dry-sliding wear test conditions. Microstructure, worn surface morphologies and subsurface microstructure were characterized by OM, XRD, SEM and EDS. Results indicate that NiMo/Mo 2 Ni 3 Si composites have low fiction coefficient, excellent wear resistance and sluggish wear-load dependence. The dominant wear mechanisms of NiMo/Mo 2 Ni 3 Si composites are soft abrasion and slightly superficial oxidative wear.

  12. Nonenzymatic Glucose Sensor Based on In Situ Reduction of Ni/NiO-Graphene Nanocomposite

    Directory of Open Access Journals (Sweden)

    Xiaohui Zhang

    2016-10-01

    Full Text Available Ni/NiO nanoflower modified reduced graphene oxide (rGO nanocomposite (Ni/NiO-rGO was introduced to screen printed electrode (SPE for the construction of a nonenzymatic electrochemical glucose biosensor. The Ni/NiO-rGO nanocomposite was synthesized by an in situ reduction process. Graphene oxide (GO hybrid Nafion sheets first chemical adsorbed Ni ions and assembled on the SPE. Subsequently, GO and Ni ions were reduced by hydrazine hydrate. The electrochemical properties of such a Ni/NiO-rGO modified SPE were carefully investigated. It showed a high activity for electrocatalytic oxidation of glucose in alkaline medium. The proposed nonenzymatic sensor can be utilized for quantification of glucose with a wide linear range from 29.9 μM to 6.44 mM (R = 0.9937 with a low detection limit of 1.8 μM (S/N = 3 and a high sensitivity of 1997 μA/mM∙cm−2. It also exhibited good reproducibility as well as high selectivity.

  13. Enthalpy of mixing of liquid Ni-Zr and Cu-Ni-Zr alloys

    International Nuclear Information System (INIS)

    Witusiewicz, V.T.; Sommer, F.

    2000-01-01

    Since the Al-Cu-Ni-Zr system is a basis for the production of bulk amorphous materials by rapid solidification techniques from the liquid state, it is of great scientific interest to determine the partial and the integral thermodynamic functions of liquid and undercooled liquid alloys. Such data, as was pointed out previously, are important in order to understand their extremely good glass-forming ability in multicomponent metallic systems as well as for processing improvements. In order to measure the thermodynamic properties of the Al-Cu-Ni-Zr quaternary, it is necessary to have reliable thermochemical data for its constituent canaries and ternaries first. In a series of articles, the authors have reported in detail the thermodynamic properties of liquid Al-Cu, Al-Ni, Cu-Ni, Cu-Zr, Al-Zr, Al-Cu-Ni, and Al-Cu-Zr alloys. This article deals with the direct calorimetric measurements of the partial and the integral enthalpies of mixing of liquid Ni-Zr and Cu-Ni-Zr alloys and the heat capacity of liquid Ni 26 Zr 74 . In a subsequent article, the authors will present similar data for the liquid ternary Al-Ni-Zr and for the liquid quaternary Al-Cu-Ni-Zr alloys

  14. The Ni-YSZ interface

    DEFF Research Database (Denmark)

    Jensen, Karin Vels

    The anode/electrolyte interface in solid oxide fuel cells (SOFC) is known to cause electrical losses. Geometrically simple Ni/yttria-stabilised zirconia (YSZ) interfaces were examined to gain information on the structural and chemical changes occurring during experiments at 1000°C in an atmosphere...... of 97% H2/3% H2O. Electrochemical impedance spectroscopy at open circuit voltage (OCV) and at anodic and cathodic polarisations (100 mV) was performed. A correlation of the electrical data with the structure development and the chemical composition was attempted. Nickel wires with different impurity...... between polarised and non-polarised samples. With pure nickel wires, however, the microstructures depended on the polarisation/non-polarisation conditions. At non-polarised conditions a hill and valley type structure was found. Anodic polarisation produced an up to 1 μm thick interface layer consisting...

  15. Study of the central collisions in the reactions Ni + Al and Ni + Ni at 28 A.MeV; Etude des collisions centrales dans les reactions Ni + Al et Ni + Ni a 28 A.MeV

    Energy Technology Data Exchange (ETDEWEB)

    Lebreton, L.

    1995-12-01

    The work is in characterisation of mechanisms in the energy range of onset of multifragmentation (excitation energy of composed nucleus around 4 - 5 AMeV). This work focused on an experiment performed at the SARA facility, in Grenoble, using the AMPHORA multi detection array. I have been particularly interested in central collisions in the Ni + Al and Ni + Ni systems. The possibility to detect complete events for Ni + Al, and quasi-complete events for the Ni + Ni case, is the reason of this choice. Furthermore Ni + Ni presents the interest of a symmetrical system, for which the excitation energy per nucleon is maximum. The study of these reactions has been focused on the quasi-complete events (events for which at least 80 % of the total charge has been detected). Heavy ions produced in peripheral collisions are very likely emitted along the beam line or stopped in the plastic detectors, energy thresholds are too high for the quasi-target products detection, consequently by requiring complete or quasi-complete measurement of the total charge, we are able to detect mostly central events. The knowledge of informations like charge, energy or detection angles allows to isolate the source(s) and to reconstruct the size and the excitation energy of the source(s). Comparisons with simulations like sequential emission (GEMINI code), very deep inelastic collision or instantaneous emission (Berliner code) allows to characterise the first stage of the collision (binary collisions or central collisions) and the type of deexcitation of the source(s). Some calculations was also performed with the statistical model code MODGAN. Indeed azimuthal correlations seem to be a good tool in getting more information about involved reaction mechanisms. Comparisons with MODGAN provide information about angular momentum of the source and time delay between emissions of the two particles (separation between sequential or instantaneous process). (author). 69 refs.

  16. Electrochemical preparation and characteristics of Ni-Co-LaNi{sub 5} composite coatings as electrode materials for hydrogen evolution

    Energy Technology Data Exchange (ETDEWEB)

    Wu Gang; Li Ning; Dai Changsong; Zhou Derui

    2004-02-15

    Electrocatalytic activity for the hydrogen evolution reaction on Ni-Co-LaNi{sub 5} composite electrodes prepared by electrochemical codeposition technique was evaluated. The relationship between the current density for hydrogen evolution reaction and the amount of LaNi{sub 5} particles in Ni-Co baths is like the well-known 'volcano plot'. The Surface morphology and microstructure of Ni-Co-LaNi{sub 5} coatings were determined by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). The kinetic parameters were determined from electrochemical steady-state Tafel polarization and electrochemical impedance spectroscopy technology in 1 M NaOH solution. The values obtained for the apparent energies of activation are 32.48, 46.29 and 57.03 kJ mol{sup -1} for the Ni-Co-LaNi{sub 5}, Ni-Co and Ni electrodes, respectively. The hydrogen evolution reaction on Ni-Co-LaNi{sub 5} proceeds via Volmer-Tafel reaction route with the mixed rate determining characteristics. The composite coating Ni-Co-LaNi{sub 5} is catalytically more active than Ni and Ni-Co electrodes due to the increase in its real surface areas and the decrease in the apparent free energy of activation caused by the electrocatalytic synergistic effect of the Ni-Co alloys and the hydrogen storage intermetallic particles on the electrode surface.

  17. Electrochemical preparation and characteristics of Ni-Co-LaNi5 composite coatings as electrode materials for hydrogen evolution

    International Nuclear Information System (INIS)

    Wu Gang; Li Ning; Dai Changsong; Zhou Derui

    2004-01-01

    Electrocatalytic activity for the hydrogen evolution reaction on Ni-Co-LaNi 5 composite electrodes prepared by electrochemical codeposition technique was evaluated. The relationship between the current density for hydrogen evolution reaction and the amount of LaNi 5 particles in Ni-Co baths is like the well-known 'volcano plot'. The Surface morphology and microstructure of Ni-Co-LaNi 5 coatings were determined by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). The kinetic parameters were determined from electrochemical steady-state Tafel polarization and electrochemical impedance spectroscopy technology in 1 M NaOH solution. The values obtained for the apparent energies of activation are 32.48, 46.29 and 57.03 kJ mol -1 for the Ni-Co-LaNi 5 , Ni-Co and Ni electrodes, respectively. The hydrogen evolution reaction on Ni-Co-LaNi 5 proceeds via Volmer-Tafel reaction route with the mixed rate determining characteristics. The composite coating Ni-Co-LaNi 5 is catalytically more active than Ni and Ni-Co electrodes due to the increase in its real surface areas and the decrease in the apparent free energy of activation caused by the electrocatalytic synergistic effect of the Ni-Co alloys and the hydrogen storage intermetallic particles on the electrode surface

  18. FY1998 survey on IEA international cooperation project on demonstration and survey of new load leveling methods (participation in the IEA/DSM task VI); 1998 nendo fuka heijunka shinshuho jissho chosa IEA kokusai kyoryoku jigyo 'IEA/DSM task 6 eno sanka ni tsuite' chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    It is intended to participate in the IEA international cooperation project related to DSA, exchange items of information, and promote demonstration and survey of new load leveling methods. The existing and newly proposed DSM mechanisms as the achievement of the previous tasks were put into order. The arena of information exchange and discussions was prepared through use of the Internet homepage for the IEA/DSM implementation agreement. Necessary official policies were also made available. Points of precautions when the mechanisms of other countries are used in Japan: the key to the success depends on social or cultural situations that work as the base; therefore, comparisons and analyses are necessary on such elements as customers as the object, energy projects and governments; compatibility of the situation and pattern of the demand side with the DSM technologies governs the reasonability thereof; the types of the mechanisms are narrowed down by size of the customer division, consumption pattern, electric power quality and safety, and needs on the flexibility; proliferation levels of the DSM technologies determine the appropriate mechanisms; and how the DSM is conceived against the final consumption is governed by the conception by both of the customers and the government. (NEDO)

  19. Reaction mechanism of coal liquefaction: hydrogenolysis of model compound using synthetic pyrite as catalysts. 7. Property change of synthetic pyrite catalyst with the time after production; Sekitan ekika hanno kiko (model kagobutsu no hanno). 7. Gosei ryukatetsu shokubai no keiji henka ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Ito, H.; Meno, H.; Uemaki, O.; Shibata, T.; Tsuji, T. [Hokkaido University, Sapporo (Japan)

    1996-10-28

    Reactions of various model compounds were investigated using synthetic pyrites for coal liquefaction. In this study, successive changes of the catalysts were investigated from the reactions of model compounds by using three different synthetic pyrites with the lapse of time after production. Benzyl phenyl ether, dibenzyl, and n-octylbenzene were used as model compounds. Reactions were conducted in an autoclave, into which sample, catalyst, decalin as solvent, and initial hydrogen pressure 10 MPa were charged. The autoclave was held at 450 or 475{degree}C of reaction temperature for 1 hour. The catalyst with a shorter lapse of time after production acted to hydrogen transfer, and inhibited the formation of condensation products due to the stabilization of decomposed fragment. It also acted to isomerization of materials by cutting alkyl side chains. When adding sulfur to the catalyst with longer lapse of time after production under these reaction conditions, it inhibited the formation of condensation products for the reaction of benzyl phenyl ether. However, it did not provide the effect for the reaction of n-octylbenzene. 5 refs., 3 figs.

  20. Fiscal 2000 achievement report on the venture business assisting type regional consortium - Core industry creation type. Comprehensive research and development for reducing ABS (MABS) sensor system into small module for enhancing vehicle steering safety; 2000 nendo chiiki consortium kenkyu kaihatsu jigyo seika hokokusho. Koji no sharyo soansei wo jitsugensuru ABS (MABS) sensor system no kogata module ka ni tsuite no sogo kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The effort aims to develop a sensor system to enable overall VDC (vehicle dynamic control). The goal is to manufacture a small module type sensor system more than 20 times higher than the conventional type in responding speed and accuracy, which will use a novel ABS (anti-lock braking system) capable of direct and real-time measurement of axial forces in the four directions. The prototype module will be a package in which a system-on-a-chip accommodating peripheral circuits is integrated with a sensor. In the effort to develop a novel multi-axial sensing system (MASS) for a smaller ABS, a circuit optimization technology was developed. A dedicated IC (integrated circuit) was developed for a system to process a large volume of signals. In the effort to develop technologies for packaging the novel sensor system and for constructing modules, technologies were developed for integrating sensor components and an IC into one, module junctioning, module installation, simplification of the installation process, and for the manufacturing of modules. Developed in the effort to optimize MASS were technologies involving the selection and evaluation of sensor components and the enhancement of such processes, optimization of the sensor itself, and the improvement of the sensor system for higher efficiency in calculation. Sensor modules were tested aboard vehicles and the compatibility of the system-on-a-chip with the MASS module was confirmed. (NEDO)

  1. Report on the surveys in fiscal 1999 on the demonstrative investigation of a new load leveling method. Participation to the IEA/DSM task VI, an IEA international cooperation project; 1999 nendo fuka heijunka shinshuho jissho chosa hokokusho. IEA kokusai kyoryoku jigyo IEA/DSM task VI eno sanka ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Participation was implemented to the IEA/DSM task VI as the demonstrative investigation of a new load leveling method. The DSM strategy is a means to achieve the public objectives of wide range, wherein the DSM mechanism is important, that can obtain accurate and useful information in competitive markets. Consumer protecting activities have close relation with general information needs. A financial incentive mechanism is also necessary to support nurturing of business organizations and new ESCO industries. A market forming mechanism using the DSM can solve the problem of disagreement in the incentives (for example, private profit of electric power companies and the public nature of the government). These include system plans considering the DSM, setting of upper limit in the profit, demand side bidding, and green charge institution. It is important to utilize affluent findings and means used in the past and utilize each mechanism to meet the needs for public benefit at the present and in the future, while structuring an electric power business structure incorporating the DSM. The DSM promoting mechanisms in each country were classified and put into order of regulations, supports, funds, and markets. (NEDO)

  2. Demonstration test on the heat pump system, thermally utilizing the domestic waste water. Result of the collecting test on an air conditioning system, Hokkaido Electric Power Gymnasium, Tomari; Seikatsu haisui netsuriyo heat pump system jissho shiken. Tomari Hokuden taiikukan reidanbo system no sainetsu shiken kekka ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Honma, T; Yamada, K; Watanabe, K [Hokkaido Electric Power Co. Inc., Sapporo (Japan)

    1995-06-14

    A heat pump system utilizing the domestic waste water was introduced into a gymnasium owned by Hokkaido Electric Power to elucidate the applicability of domestic waste water as a thermal source of heat pump in the cold region. The gymnasium is a two-storied concrete building with the floor space of 2292m{sup 2}. Ground water at temperatures from 10 to 20{degree}C is utilized for the water supply. Made to flow together as waste water, the dirty water and daily exhaust water are discharged at the rate of 100t/day into a river after passing through the septic tank. Higher by 5 to 15{degree}C than the atmospheric temperature, the discharging temperature is kept higher than 10{degree}C even during the very cold period. The domestic waste water is almost neutral in pH, and normal in both SS and BOD. The heat pump was utilized for two stages, i.e., thermal collection and temperature heightening. The capacity of a sewage storage tank tank was made to be 170m{sup 3} to meet the thermal load of 139000kcal/h in the gymnasium. The temperature of 15{degree}C could be kept during the air heating trial. The system is about 2 in coefficient of performance. The K-value of heat exchanger decreased by about 30% after seven months of operation. Upon its overhauling, its K-value recovered to 2.37, so that it must be overhauled once a year. 5 refs., 15 figs. 4 tabs.

  3. On the wave induced responses for a high-speed hydrofoil catamaran. Part 1. Cabin connected to hull by spring and its riding comfort in waves; Suichuyokutsuki kosoku sodotei no harochu oto ni tsuite. 1. Dokuritsu kozogata cabin to harochu norigokochi

    Energy Technology Data Exchange (ETDEWEB)

    Saito, K; Nobukawa, H; Honda, Y [Hiroshima University, Hiroshima (Japan)

    1996-04-10

    Riding comfort in a cabin of a high-speed hydrofoil catamaran was evaluated by comparing with that in ordinary boats as to acceleration in the vertical direction as one of the responses of the catamaran in waves. First, an equation of motion in waves was introduced, and considerations were given while comparing the result of calculations in regular waves with that of model experiments. Comparison and verification were also performed on response characteristics in irregular waves. A new-type boat, whose cabin is supported with four springs, and provided with hydrofoils in front and rear thereof, was verified to have much less motions of the catamaran bodies and the cabin than in the ordinary boats both in regular and irregular waves. This result was proven by numerical calculations and model experiments. Hydrofoils affect largely the reduction in motions. The correlational data between the results of calculations and experiments are considered sufficient to provide design data, although there are still some points to be improved. These results revealed that the riding comfort of the new-type boat has been improved over that in the ordinary boats. 6 refs., 11 figs., 3 tabs.

  4. FY 1997 report on the verification survey of new mechanisms for load leveling. IEA`s international collaboration `Participation of Japan in IEA/DSM Task VI`; 1997 nendo chosa hokokusho (fuka heijunka shinshuho jissho chosa). IEA kokusai kyoryoku jigyo `IEA/DSM task IV eno sanka ni tsuite`

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Current electricity markets in Europe and the USA are drastically changing due to the introduction of competition principle and the reconsideration of business systems. Are also changing the activities and their forms of DSM (demand side management) for load leveling which has been conventionally conducted by electricity companies for the efficient operation of facilities. Task IV and Task VI aim at developing new mechanisms to promote DSM in the changing electricity markets as well as disseminating and communicating information on the new mechanism. Japan participates in Sub-task IV/6 and 7 and Task VI. Activities for developing new mechanisms are divided into Phase 1 and Phase 2. The Phase 1 includes review of existing mechanisms and preliminary development and evaluation of new mechanisms. The Phase 2 includes the detailed development of new mechanisms and evaluation criteria, communication and information about mechanisms, and identification of the public policy implications which would follow a decision by the responsible authorities to implement each of various DSM mechanisms. The time frame of Phase 1 is between February 1996 and March 1997, and that of Phase 2 is between January 1997 and December 1999. 2 figs., 4 tabs.

  5. Fiscal 2000 survey report. Survey for verification of new load levelling technique - IEA international joint project (Participation in IEA/DSM task); 2000 nendo fuka heijunka shuho jissho chosa hokokusho. IEA kokusai kyoryoku jigyo 'IEA/DSM task eno sanka ni tsuite'

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Japan participated in IEA/DSM (International Energy Agency/demand side management) Task X (performance contracting) for collecting information on energy service contracting business designed to promote load levelling centered DSM activities on the basis of market principles for achieving efficient operation of facilities. Task X aims to adjust and popularize the energy service contracting business. In the energy service contracting business, the facility related party and the energy service related party work under a contract to enhance efficiency of facility operation, and share the gains between them. In concrete terms, information was collected and exchanged at the 14th and 15th executive committee meeting of IEA/DSM Task X (Turkey in April 2000, Sweden in September 2000); new task preparation conference (Sweden in September 2000); 1st specialist conference (France in February 2001); and 17th annual convention of All-America ESCO (energy service company) Council (U.S. in November 2000). (NEDO)

  6. Analysis of energy demand-supply of city and evaluation of energy conservation and peak suppression of environmental symbiosis city; Toshi no energy jukyu bunseki to shoene toshi no shoene fuka heijunka koka no hyoka (kankyo kyosei sho energy wo mezashita 60 mannin shintoshi ni tsuite no kento)

    Energy Technology Data Exchange (ETDEWEB)

    Iwatsubo, T.; Hashimoto, K. [Central Research Institute of Electric Power Industry, Tokyo (Japan)

    1997-05-01

    The paper developed an analysis method of the energy supply/demand structure of city and compared the conventional city and a city considering energy conservation. An energy supply/demand flow chart was newly proposed. From this flow chart, `energy sustainability ratios` was proposed as a new index for comprehensively evaluating two elements of the energy conservation by load reduction and heightening of energy conversion rates and the utilization of waste heat and renewable energy. A method for analysis of the energy supply/demand structure of city was developed including daily supply/demand patterns in the area where individual equipment in every residence/building correspond to the energy supply and the area where centralized energy systems such as district energy supply correspond it. From the developed analysis method, analysis was made of a newly developed city with a 0.6 million population in terms of the conventional city and energy conservation city, to clarify the present energy supply/demand structure of city and to express it in an energy flow chart. At the same time, validity of the analysis method and evaluation indexes were confirmed by comparing the conventional city and energy conservation city. 15 refs, 27 figs., 17 tabs.

  7. Amendment of oil related systems. Abolishment of the temporary measure law for importing specific petroleum products and amendment of the oil storage law and the volatile oil selling business law; Sekiyu kanren no seido kaisei ni tsuite. Tokutei sekiyu seihin yunyu oyobi kihatsuyu hanbaigyoho no kaisei

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, I. [Small and Medium Enterprise Agency, Tokyo (Japan)

    1995-07-20

    This paper describes the following matters related to amendment of oil related systems which will be enforced according to the result of discussions at the Petroleum Council on the ways the oil product supply should be in the future. The temporary measure law for importing specific oil products shall be abolished when it will be expired in March 1996. This is because the law has limited the oil product importing organizations only to oil companies who have oil refining capabilities, and the continuation of the law would lose its justifiability under the present circumstances in the petroleum industry. The oil reservation law is then amended so that the emergency handling ability on oil supply will not be hampered even after possible expansion in the number of oil product importing organizations as a result of the abolishment of the temporary measure law. The quality management systems for oil products will also be revised so that the present level on quality items of the minimum necessity will not be declined with respect to the environments and safety. Furthermore, the area designating system that has been limiting erection of oil service stations will be repealed by October 1996. 2 tabs.

  8. Synthesis of Supported NiPt Bimetallic Nanoparticles, Methods for Controlling the Surface Coverage of Ni Nanoparticles With Pt, Methods Of Making NiPt Multilayer Core-Shell Structures and Application of the Supported Catalysts for CO2 Reforming

    KAUST Repository

    Li, Lidong; Anjum, Dalaver H.; Zhou, Lu; Laveille, Paco; Basset, Jean-Marie

    2015-01-01

    Embodiments of the present disclosure provide for supported Ni/Pt bimetallic nanoparticles, compositions including supported NiPt nanoparticles, methods of making supported NiPt nanoparticles, methods of using supported NiPt nanoparticles

  9. Synthesis of Supported NiPt Bimetallic Nanoparticles, Methods for Controlling the Surface Coverage of Ni Nanoparticles With Pt, Methods Of Making NiPt Multilayer Core-Shell Structures and Application of the Supported Catalysts for CO2 Reforming

    KAUST Repository

    Li, Lidong

    2015-06-25

    Embodiments of the present disclosure provide for supported Ni/Pt bimetallic nanoparticles, compositions including supported NiPt nanoparticles, methods of making supported NiPt nanoparticles, methods of using supported NiPt nanoparticles, and the like.

  10. Growth of single-crystal W whiskers during humid H2/N2 reduction of Ni, Fe-Ni, and Co-Ni doped tungsten oxide

    International Nuclear Information System (INIS)

    Wang Shiliang; He Yuehui; Zou Jou; Wang Yong; Huang Han

    2009-01-01

    Numbers of W whiskers were obtained by reducing Ni, Ni-Fe, and Ni-Co doped tungsten oxide in a mixed atmosphere of humid H 2 and N 2 . The phases and morphologies of the reduction products were characterized by XRD and SEM. Intensive TEM and EDS analyses showed that the obtained whiskers were W single crystals which typical have alloyed particles (Ni-W, Fe-Ni, or Co-Ni-W) at the growth tips. The formed W whiskers were presumed to be induced by the alloyed particles. Our experimental results revealed that, during the reduction process of tungsten oxide, the pre-reduced Ni, Fe-Ni, or Co-Ni particles not only served as nucleation aids for the initial growth of W phase from W oxide but also played the roles of catalysts during the reductive decomposition of gaseous WO 2 (OH) 2 .

  11. Exchange bias variations of the seed and top NiFe layers in NiFe/FeMn/NiFe trilayer as a function of seed layer thickness

    International Nuclear Information System (INIS)

    Sankaranarayanan, V.K.; Yoon, S.M.; Kim, C.G.; Kim, C.O.

    2005-01-01

    Development of exchange bias at the seed and top NiFe layers in the NiFe (t nm)/FeMn(10 nm)/NiFe(5 nm) trilayer structure is investigated as a function of seed layer thickness, in the range of 2-20 nm. The seed NiFe layer shows maximum exchange bias at 4 nm seed layer thickness. The bias shows inverse thickness dependence with increasing thickness. The top NiFe layer on the other hand shows only half the bias of the seed layer which is retained even after the sharp fall in seed layer bias. The much smaller bias for the top NiFe layer is related to the difference in crystalline texture and spin orientations at the top FeMn/NiFe interface, in comparison to the bottom NiFe/FeMn interface which grows on a saturated NiFe layer with (1 1 1) orientation

  12. An Ultrastable and High-Performance Flexible Fiber-Shaped Ni-Zn Battery based on a Ni-NiO Heterostructured Nanosheet Cathode.

    Science.gov (United States)

    Zeng, Yinxiang; Meng, Yue; Lai, Zhengzhe; Zhang, Xiyue; Yu, Minghao; Fang, Pingping; Wu, Mingmei; Tong, Yexiang; Lu, Xihong

    2017-11-01

    Currently, the main bottleneck for the widespread application of Ni-Zn batteries is their poor cycling stability as a result of the irreversibility of the Ni-based cathode and dendrite formation of the Zn anode during the charging-discharging processes. Herein, a highly rechargeable, flexible, fiber-shaped Ni-Zn battery with impressive electrochemical performance is rationally demonstrated by employing Ni-NiO heterostructured nanosheets as the cathode. Benefiting from the improved conductivity and enhanced electroactivity of the Ni-NiO heterojunction nanosheet cathode, the as-fabricated fiber-shaped Ni-NiO//Zn battery displays high capacity and admirable rate capability. More importantly, this Ni-NiO//Zn battery shows unprecedented cyclic durability both in aqueous (96.6% capacity retention after 10 000 cycles) and polymer (almost no capacity attenuation after 10 000 cycles at 22.2 A g -1 ) electrolytes. Moreover, a peak energy density of 6.6 µWh cm -2 , together with a remarkable power density of 20.2 mW cm -2 , is achieved by the flexible quasi-solid-state fiber-shaped Ni-NiO//Zn battery, outperforming most reported fiber-shaped energy-storage devices. Such a novel concept of a fiber-shaped Ni-Zn battery with impressive stability will greatly enrich the flexible energy-storage technologies for future portable/wearable electronic applications. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. Synthesis of a novel Au nanoparticles decorated Ni-MOF/Ni/NiO nanocomposite and electrocatalytic performance for the detection of glucose in human serum.

    Science.gov (United States)

    Chen, Jingyuan; Xu, Qin; Shu, Yun; Hu, Xiaoya

    2018-07-01

    A nonenzymatic glucose electrochemical sensor was constructed based on Au nanoparticles (AuNPs) decorated Ni metal-organic-framework (MOF)/Ni/NiO nanocomposite. Ni-MOF/Ni/NiO nanocomposite was synthesized by one-step calcination of Ni-MOF. Then AuNPs were loaded onto the Ni-based nanocomposites' surface through electrostatic adsorption. Through characterization by transmission electron microscopy (TEM), high resolution TEM (HRTEM) and energy disperse spectroscopy (EDS) mapping, it is found that the AuNPs were well distributed on the surface of Ni-based nanocomposite. Cyclic voltammetric (CV) study showed the electrocatalytic activity of Au-Ni nanocomposite was highly improved after loading AuNPs onto it. Amperometric study demonstrated that the Au-Ni nanocomposites modified glassy carbon electrode (GCE) exhibited a high sensitivity of 2133.5 mA M -1 cm -2 and a wide linear range (0.4-900 μM) toward the oxidation of glucose with a detection limit as low as 0.1 μM. Moreover, the reproducibility, selectivity and stability of the sensor all exhibited outstanding performance. We applied the as-fabricated high performance sensor to measure the glucose levels in human serum and obtained satisfactory results. It is believed that AuNPs decorated Ni MOF/Ni/NiO nanocomposite provides a new platform for developing highly performance electrochemical sensors in practical applications. Copyright © 2018 Elsevier B.V. All rights reserved.

  14. Ni antagelser om Situationel Dialektisk Videnskabsteori

    DEFF Research Database (Denmark)

    Dakwar, Julia Rytter; Lorentzen, Anne-Christine Rosfeldt; Smedegaard, Flemming

    2017-01-01

    I artiklen præsenteres et præliminært bud på en Situationel Dialektisk Videnskabsteori (SDV) i form af ni antagelser. Situationel, fordi antagelserne ikke er statiske, men alle overvejelser og valg under de enkelte antagelser er afhængige af situationen. Dialektisk, fordi alle ni antagelser...... opererer med dialektiske modsætninger, og alle videnskabsteoretiske valg ses som valg på kontinua. De ni antagelser, som bliver præsenteret og diskuteret i artiklen, er: Antagelse 1: Teori og praksis fordrer hinanden Antagelse 2: Del og helhed hænger sammen Antagelse 3: Forbundne sagsforhold påvirker...

  15. New developments in Ni/Ti multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, I; Hoghoj, P [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France)

    1997-04-01

    It is now 20 years since super-mirrors were first used as a neutron optical element. Since then the field of multilayer neutron-optics has matured with multilayers finding their way to application in many neutron scattering instruments. However, there is still room for progress in terms of multilayer quality, performance and application. Along with work on multilayers for neutron polarisation Ni/Ti super-mirrors have been optimised. The state-of-the-art Ni/Ti super-mirror performance and the results obtained in two neutron-optics applications of Ni/Ti multilayers are presented. (author).

  16. Site occupancy of Fe in ternary Ni 75-x

    Indian Academy of Sciences (India)

    The results of a detailed structural and magnetic study clearly indicate that regardless of the thermal history of the samples, Fe has a strong preference for the Ni sites in Ni-poor (non-stoichiometric) Ni75Al25 alloys. Fe substitution has a profound effect on the nature of magnetism in Ni75Al25.

  17. Reduction of a Ni/Spinel Catalyst for Methane Reforming

    DEFF Research Database (Denmark)

    Kehres, Jan; Andreasen, Jens Wenzel; Fløystad, Jostein Bø

    2015-01-01

    microscopy (HRTEM) was performed on the fresh catalyst sample. The Ni particles in the fresh catalyst sample were observed to exhibit a Ni/NiO core/shell structure. A decrease of the Ni lattice parameter is observed during the reduction in a temperature interval from 413 – 453 K, which can be related...

  18. Influence of Ni Solute segregation on the intrinsic growth stresses in Cu(Ni) thin films

    International Nuclear Information System (INIS)

    Kaub, T.M.; Felfer, P.; Cairney, J.M.; Thompson, G.B.

    2016-01-01

    Using intrinsic solute segregation in alloys, the compressive stress in a series of Cu(Ni) thin films has been studied. The highest compressive stress was noted in the 5 at.% Ni alloy, with increasing Ni concentration resulting in a subsequent reduction of stress. Atom probe tomography quantified Ni's Gibbsian interfacial excess in the grain boundaries and confirmed that once grain boundary saturation is achieved, the compressive stress was reduced. This letter provides experimental support in elucidating how interfacial segregation of excess adatoms contributes to the post-coalescence compressive stress generation mechanism in thin films. - Graphical abstract: Cu(Ni) film stress relationship with Ni additions. Atom probe characterization confirms solute enrichment in the boundaries, which was linked to stress response.

  19. NiCo-lead zirconium titanate-NiCo trilayered magnetoelectric composites prepared by electroless deposition

    International Nuclear Information System (INIS)

    Zhou, M. H.; Wang, Y. G.; Bi, K.; Fan, H. P.; Zhao, Z. S.

    2015-01-01

    The NiCo layers with various Ni/Co atomic ratio have been successfully electroless deposited on PZT layers by varying the bath composition. As the cobalt atomic ratio in the deposited layer increases from 17.2 to 54.8 wt%, the magnetostrictive coefficient decreases. The magnetoelectric effect depends strongly on the magnetostrictive properties of magnetostrictive phase. The magnetoelectric coefficient of NiCo/PZT/NiCo trilayers increases with Ni/Co atomic ratio of the deposited NiCo layers increasing from 45:55 to 83:17. A maximum ME voltage coefficient of α E,31 = 2.8 V ⋅ cm −1 ⋅ Oe −1 is obtained at a frequency of about 88 kHz, which makes these trilayers suitable for applications in actuators, transducers and sensors

  20. NiCo-lead zirconium titanate-NiCo trilayered magnetoelectric composites prepared by electroless deposition

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, M. H.; Wang, Y. G.; Bi, K., E-mail: bike@bupt.edu.cn [State Key Laboratory of Information Photonics and Optical Communications and School of Science, Beijing University of Posts and Telecommunications, Beijing 100876 (China); Fan, H. P. [School of Mechanical and Electrical Engineering, Qingdao Technological University Qindao College, Qingdao 266106 (China); Zhao, Z. S. [Shandong Engineering Consulting Institute, Jinan 250013 (China)

    2015-04-15

    The NiCo layers with various Ni/Co atomic ratio have been successfully electroless deposited on PZT layers by varying the bath composition. As the cobalt atomic ratio in the deposited layer increases from 17.2 to 54.8 wt%, the magnetostrictive coefficient decreases. The magnetoelectric effect depends strongly on the magnetostrictive properties of magnetostrictive phase. The magnetoelectric coefficient of NiCo/PZT/NiCo trilayers increases with Ni/Co atomic ratio of the deposited NiCo layers increasing from 45:55 to 83:17. A maximum ME voltage coefficient of α{sub E,31} = 2.8 V ⋅ cm{sup −1} ⋅ Oe{sup −1} is obtained at a frequency of about 88 kHz, which makes these trilayers suitable for applications in actuators, transducers and sensors.

  1. Fe-solubility of Ni7S6 and Ni9S8: Thermodynamic analysis

    International Nuclear Information System (INIS)

    Waldner, P.

    2011-01-01

    Experimental data on phase equilibria have been used for thermodynamic analysis of the iron solubility of the nickel sulfides Ni 7 S 6 and Ni 9 S 8 . For both compounds, a two-sublattice approach within the framework of the compound energy formalism has been applied to perform Gibbs free energy modelling at 0.1 MPa total pressure consistently embedded in recent thermodynamic assessment studies of other iron-nickel-sulfides. The predicted maxima of iron solubility around 3 at% of Ni 7 S 6 and 5.5 at% of Ni 9 S 8 are confirmed by experimental data. The calculations of complex ternary phase relations with Fe-bearing Ni 7 S 6 and Ni 9 S 8 gain further improvement. The first internally consistent description of all thermodynamically stable phases known in the literature for the iron-nickel-sulfur system is completed.

  2. Phase stability and magnetism in NiPt and NiPd alloys

    International Nuclear Information System (INIS)

    Paudyal, Durga; Mookerjee, Abhijit

    2004-01-01

    We show that the differences in stability of 3d-5d NiPt and 3d-4d NiPd alloys arise mainly due to relativistic corrections. The magnetic properties of disordered NiPd and NiPt alloys also differ due to these corrections, which lead to increase in the separation between the s-d bands of 5d elements in these alloys. For the magnetic case we also analyse the results in terms of splitting of majority and minority spin d band centres of the 3d elements. We further examine the effect of relativistic corrections to the pair energies and order-disorder transition temperatures in these alloys. The magnetic moments and Curie temperatures have also been studied along with the short range ordering/segregation effects in NiPt/NiPd alloys

  3. Precipitation of Ni4Ti3-variants in a polycrystalline Ni-rich NiTi shape memory alloy

    Czech Academy of Sciences Publication Activity Database

    Bojda, Ondřej; Eggeler, G.; Dlouhý, Antonín

    2005-01-01

    Roč. 53, č. 1 (2005), s. 99-104 ISSN 1359-6462 R&D Projects: GA ČR(CZ) GA106/05/0918 Institutional research plan: CEZ:AV0Z20410507 Keywords : NiTi shape memory alloys * Ni4Ti3 precipitation * Transmission electron microscopy Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.228, year: 2005

  4. Ni-Ni ion pair excitation transfer in D sub(3h) symmetry

    International Nuclear Information System (INIS)

    Terrile, M.C.

    1990-01-01

    The mechanisms contributing to excitation transfer are examined for Ni-Ni ion pairs in order to explain the delocalized character of electronic excitations observed in CsNiF sub(3). Using both first-and second-order perturbation theory and from symmetry arguments, the kind of interactions giving matrix elements between states connecting different sites for the position of the excitation are discussed. (author)

  5. Electronic structure of graphene on Ni surfaces with different orientation

    International Nuclear Information System (INIS)

    Pudikov, D.A.; Zhizhin, E.V.; Rybkin, A.G.; Rybkina, A.A.; Zhukov, Y.M.; Vilkov, O. Yu.; Shikin, A.M.

    2016-01-01

    An experimental study of the graphene, synthesized by propylene cracking on Ni surfaces with different orientation: (100) and (111), using angle-resolved photoemission, has been performed. It has been shown that graphene on Ni(111) had a perfect lateral structure due to consistency of their lattices, whereas graphene/Ni(100) consisted of a lot of domains. For both systems electronic structure was quite similar and demonstrated a strong bonding of graphene to the underlying Ni surface. After Au intercalation the electronic structure of graphene in both systems was shifted to the Fermi level and became linear in the vicinity of the K point of the Brillouin zone. - Highlights: • Graphene on Ni(111) is well-ordered, whereas on Ni(100) – multi-domain. • Graphene on Ni(111) and Ni(100) is strongly bonded with substrate. • Intercalation of Au atoms restores the linearity in dispersion and makes graphene quasi-free on both Ni(100) and Ni(111).

  6. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    Energy Technology Data Exchange (ETDEWEB)

    Kabir, L.; Mandal, A.R. [Department of Physics, Visva-Bharati, Santiniketan-731 235 (India); Mandal, S.K., E-mail: sk_mandal@hotmail.co [Department of Physics, Visva-Bharati, Santiniketan-731 235 (India)

    2010-04-15

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni{sup 2+} clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni{sup 2+} clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  7. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    Science.gov (United States)

    Kabir, L.; Mandal, A. R.; Mandal, S. K.

    2010-04-01

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni 2+ clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni 2+ clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  8. Polymer stabilized Ni-Ag and Ni-Fe alloy nanoclusters: Structural and magnetic properties

    International Nuclear Information System (INIS)

    Kabir, L.; Mandal, A.R.; Mandal, S.K.

    2010-01-01

    We report here the structural and magnetic behaviors of nickel-silver (Ni-Ag) and nickel-iron (Ni-Fe) nanoclusters stabilized with polymer (polypyrrole). High resolution transmission electron microscopy (HRTEM) indicates Ni-Ag nanoclusters to stabilize in core-shell configuration while that of Ni-Fe nanoclusters in a mixed type of geometry. Structural characterizations by X-ray diffraction (XRD) reveal the possibility of alloying in such bimetallic nanoclusters to some extent even at temperatures much lower than that of bulk alloying. Electron paramagnetic resonance (EPR) spectra clearly reveal two different absorption behaviors: one is ascribed to non-isolated Ni 2+ clusters surrounded by either silver or iron giving rise to a broad signal, other (very narrow signal) being due to the isolated superparamagnetic Ni 2+ clusters or bimetallic alloy nanoclusters. Results obtained for Ni-Ag and Ni-Fe nanoclusters have been further compared with the behavior exhibited by pure Ni nanoclusters in polypyrrole host. Temperature dependent studies (at 300 and 77 K) of EPR parameters, e.g. linewidth, g-value, line shape and signal intensity indicating the significant influence of surrounding paramagnetic silver or ferromagnetic iron within polymer host on the EPR spectra have been presented.

  9. Modeling and simulation of NiO dissolution and Ni deposition in molten carbonate fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Nam, Suk Woo; Choi, Hyung-Joon; Lim, Tae Hoon [Korea Institute of Science & Technology, Seoul (Korea, Republic of)] [and others

    1996-12-31

    Dissolution of NiO cathode into the electrolyte matrix is an important phenomena limiting the lifetime of molten carbonate fuel cell (MCFC). The dissolved nickel diffuses into the matrix and is reduced by dissolved hydrogen leading to the formation of metallic nickel films in the pores of the matrix. The growth of Ni films in the electrolyte matrix during the continuous cell operation results eventually in shorting between cathode and anode. Various mathematical and empirical models have been developed to describe the NiO dissolution and Ni deposition processes, and these models have some success in estimating the lifetime of MCFC by correlating the amount of Ni deposited in the matrix with shorting time. Since the exact mechanism of Ni deposition was not well understood, deposition reaction was assumed to be very fast in most of the models and the Ni deposition region was limited around a point in the matrix. In fact, formation of Ni films takes place in a rather broad region in the matrix, the location and thickness of the film depending on operating conditions as well as matrix properties. In this study, we assumed simple reaction kinetics for Ni deposition and developed a mathematical model to get the distribution of nickel in the matrix.

  10. Layering and temperature-dependent magnetization and anisotropy of naturally produced Ni/NiO multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Pappas, S. D.; Trachylis, D.; Velgakis, M. J. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Kapaklis, V.; Joensson, P. E.; Papaioannou, E. Th. [Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden); Delimitis, A. [Chemical Process Engineering Research Institute (CPERI), Centre for Research and Technology Hellas (CERTH), 57001 Thermi, Thessaloniki (Greece); Poulopoulos, P. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Institut fuer Experimentalphysik, Freie Universitaet Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Materials Science Department, University of Patras, 26504 Patras (Greece); Fumagalli, P. [Institut fuer Experimentalphysik, Freie Universitaet Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Politis, C. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Department of Materials Science and Engineering, University of Texas at Arlington, Arlington, Texas 76019 (United States)

    2012-09-01

    Ni/NiO multilayers were grown by magnetron sputtering at room temperature, with the aid of the natural oxidation procedure. That is, at the end of the deposition of each single Ni layer, air is let to flow into the vacuum chamber through a leak valve. Then, a very thin NiO layer ({approx}1.2 nm) is formed. Simulated x-ray reflectivity patterns reveal that layering is excellent for individual Ni-layer thickness larger than 2.5 nm, which is attributed to the intercalation of amorphous NiO between the polycrystalline Ni layers. The magnetization of the films, measured at temperatures 5-300 K, has almost bulk-like value, whereas the films exhibit a trend to perpendicular magnetic anisotropy (PMA) with an unusual significant positive interface anisotropy contribution, which presents a weak temperature dependence. The power-law behavior of the multilayers indicates a non-negligible contribution of higher order anisotropies in the uniaxial anisotropy. Bloch-law fittings for the temperature dependence of the magnetization in the spin-wave regime show that the magnetization in the multilayers decreases faster as a function of temperature than the one of bulk Ni. Finally, when the individual Ni-layer thickness decreases below 2 nm, the multilayer stacking vanishes, resulting in a dramatic decrease of the interface magnetic anisotropy and consequently in a decrease of the perpendicular magnetic anisotropy.

  11. XRD studies on solid state amorphisation in electroless Ni/P and Ni/B deposits

    International Nuclear Information System (INIS)

    Sampath Kumar, P.; Kesavan Nair, P.

    1996-01-01

    The decomposition of electroless Ni-P and Ni-B deposits on annealing at various temperature is studied using x-ray diffraction techniques employing profile deconvolution and line profile analysis. It appears that solid state amorphisation takes place in the Ni-B deposits in a narrow temperature range just prior to the onset of crystallization of amorphous phase. In the case of Ni-P deposits no evidence for solid state amorphisation could be obtained. Thermodynamic and kinetic considerations also support such a conclusion

  12. Ni adsorption and Ni-Al LDH precipitation in a sandy aquifer: An experimental and mechanistic modeling study

    NARCIS (Netherlands)

    Regelink, I.C.; Temminghoff, E.J.M.

    2011-01-01

    Mining activities and industries have created nickel (Ni) contaminations in many parts of the world. The objective of this study is to increase our understanding of Ni adsorption and Nickel-Aluminium Layered Double Hydroxide (Ni-Al LDH) precipitation to reduce Ni mobility in a sandy soil aquifer. At

  13. Core/shell AgNi/PtAgNi nanoparticles as methanol-tolerant oxygen reduction electrocatalysts

    International Nuclear Information System (INIS)

    Wu, Dengfeng; Cheng, Daojian

    2015-01-01

    A core/shell AgNi/PtAgNi nanoparticle (NP) was synthesized via a new seed-mediated growth method in organic solvent medium. The as-synthesized AgNi/PtAgNiNP exhibits an AgNi core coated with PtAgNi shell, which was confirmed by transmission electron microscopy (TEM), ultraviolet–visible absorption spectroscopy and X-ray Photoelectron Spectroscopy (XPS). The AgNi/PtAgNiNPs/C catalyst possesses higher oxygen reduction reaction (ORR) activity and better durability compared with the commercial Pt/C catalyst. It is found that the ORR polarization curve of the AgNi/PtAgNiNPs/C catalyst shows an onset potential of 0.91 V vs. RHE, which is superior to the commercial Pt/C (0.88 V vs. RHE). In addition, the AgNi/PtAgNiNPs/C catalyst shows much better durability than the commercial Pt/C catalyst. More interestingly, the AgNi/PtAgNiNPs/C catalyst displays much higher methanol tolerance than the commercial Pt/C catalyst in 0.1 M KOH solution in the presence of 0.5 M methanol. Our results show that core/shell AgNi/PtAgNiNPs possess selective activity for ORR even in the presence of methanol, showing potential application as methanol-tolerant cathode catalysts in direct methanol fuel cells.

  14. Grain boundaries in Ni3Al. 2

    International Nuclear Information System (INIS)

    Kung, H.; Sass, S.L.

    1992-01-01

    This paper discusses the dislocation structure of small angle tilt and twist boundaries in ordered Ni 3 Al, with and without boron, investigated using transmission electron microscopy. Dislocation with Burgers vectors that correspond to anti-phase boundary (APB)-coupled superpartials were found in small angle twist boundaries in both boron-free and boron-doped Ni 3 Al, and a small angle tilt boundary in boron-doped Ni 3 Al. The boundary structures are in agreement with theoretical models proposed by Marcinkowski and co-workers. The APB energy determined from the dissociation of the grain boundary dislocations was lower than values reported for isolated APBs in Ni 3 Al. For small angle twist boundaries the presence of boron reduced the APB energy at the interface until it approached zero. This is consistent with the structure of these boundaries containing small regions of increased compositional disorder in the first atomic plane next to the interface

  15. Ni-ZrB2 electrocomposites

    International Nuclear Information System (INIS)

    Pushpavanam, M.; Natarajan, S.R.

    1992-01-01

    New generation materials require high temperature oxidation resistance besides many other tribological properties. Ni-ZrB 2 composites and their properties are dealt with in this paper. (author). 7 refs., 3 figs., 4 tabs

  16. Not in Traffic Surveillance (NiTS)

    Data.gov (United States)

    Department of Transportation — The Not-in-Traffic Surveillance (NiTS) system is a virtual data collection system designed to provide counts and details regarding fatalities and injuries that occur...

  17. Niños y Violencia

    OpenAIRE

    International Child Development Centre

    1997-01-01

    Este Innocenti Digest explora la violencia de los niños y hacia los niños, usando el marco de la Convención de los Derechos del Niño de las Naciones Unidas. Se centra en la violencia interpersonal, tanto intrafamiliar como extrafamiliar. Se incluye el abuso sexual y la explotación ya que a pesar de no implicar obligatoriamente violencia o coerción, la mayor parte de la evidencia demuestra su efectos dañinos tanto físicos como psicológicos. También se discute la implicación de los niños en los...

  18. Collision strengths for transitions in Ni XIX

    Indian Academy of Sciences (India)

    4l configurations of Ni XIX, for which flexible atomic code. (FAC) has been ... atomic data (namely energy levels, radiative rates, collision strengths, excitation rates, etc.) ... Zhang and Sampson, who adopted the Coulomb–Born-exchange.

  19. Root morphology of Ni-treated plants

    International Nuclear Information System (INIS)

    Leskova, A.; Fargasova, A.; Giehl, R. F. H.; Wiren, N. von

    2015-01-01

    Plant roots are very important organs in terms of nutrient and water acquisition but they also serve as anchorages for the aboveground parts of the plants. The roots display extraordinary plasticity towards stress conditions as a result of integration of environmental cues into the developmental processes of the roots. Our aim was to investigate the root morphology of Arabidopsis thaliana plants exposed to a particular stress condition, excess Ni supply. We aimed to find out which cellular processes - cell division, elongation and differentiation are affected by Ni, thereby explaining the seen root phenotype. Our results reveal that a distinct sensitivity exists between roots of different order and interference with various cellular processes is responsible for the effects of Ni on roots. We also show that Ni-treated roots have several auxin-related phenotypes. (authors)

  20. Density and Structure Analysis of Molten Ni-W Alloys

    Institute of Scientific and Technical Information of China (English)

    Feng XIAO; Liang FANG

    2004-01-01

    Density of molten Ni and Ni-W alloys was measured in the temperature range of 1773~1873 K with a sessile drop method.The density of molten Ni and Ni-W alloys trends to decrease with increasing temperature. The density and molar volume of the alloys trend to increase with increasing W concentration in the alloys. The calculation result shows an ideal mixing of Ni-W alloys.

  1. Fe-Cr-Ni system alloys

    International Nuclear Information System (INIS)

    Levin, F.L.

    1986-01-01

    Phase diagram of Fe-Cr-Ni system, which is the basic one for production of corrosion resistant alloys, is considered. Data on corrosion resistance of such alloys are correlated depending on a number of factors: quality and composition of modifying elements, corrosion medium, temperature, alloy structure, mechanical and thermal treatment. Grades of Fe-Ni-Cr alloys are presented, and fields of their application are pointed out

  2. Synthesis of Ni3Ta, Ni2Ta and NiTa by high-energy ball milling and subsequent heat treatment

    International Nuclear Information System (INIS)

    Benites, H.S.N.; Silva, B.P da; Ramos, A.S.; Silva, A.A.A.P.; Coelho, G.C.; Lima, B.B. de

    2014-01-01

    The tantalum has relevance for the development of multicomponent Ni-based superalloys which are hardened by solid solution and precipitation mechanisms. Master alloys are normally used in the production step in order to produce refractory metals and alloys. The present work reports on the synthesis of Ni_3Ta, Ni_2Ta and NiTa by high-energy ball milling and subsequent heat treatment. The elemental Ni-25Ta, Ni-33Ta and Ni-50Ta (at.-%) powder mixtures were ball milled under Ar atmosphere using stainless steel balls and vials, 300 rpm and a ball-to-powder weight ratio of 10:1. Following, the as-milled samples were uniaxially compacted and heat-treated at 1100 deg C for 4h under Ar atmosphere. The characterization of as-milled and heat-treated samples was conducted by means of X-ray diffraction, scanning electron microscopy, and energy dispersive spectrometry. A large amount of Ni_3Ta, Ni_2Ta and NiTa was formed in the mechanically alloyed heat-treated Ni-25Ta, Ni-33Ta and Ni-50Ta alloys. (author)

  3. Structural Investigation of Fe-Ni-S and Fe-Ni-Si Melts by High-temperature Fluorescence XAFS Measurements

    International Nuclear Information System (INIS)

    Manghnani, Murli H.; Balogh, John; Hong Xinguo; Newville, Matthew; Amulele, G.

    2007-01-01

    Iron-nickel (Fe-Ni) alloy is regarded as the most abundant constituent of Earth's core, with an amount of 5.5 wt% Ni in the core based on geochemical and cosmochemical models. The structural role of nickel in liquid Fe-Ni alloys with light elements such as S or Si is poorly understood, largely because of the experimental difficulties of high-temperature melts. Recently, we have succeeded in acquiring Ni K-edge fluorescence x-ray absorption fine structure (XAFS) spectra of Fe-Ni-S and Fe-Ni-Si melts and alloys. Different structural environment of Ni atoms in Fe-Ni-S and Fe-Ni-Si melts is observed, supporting the effect of light elements in Fe-Ni melts

  4. Robust optimum design with maximum entropy method; Saidai entropy ho mochiita robust sei saitekika sekkeiho

    Energy Technology Data Exchange (ETDEWEB)

    Kawaguchi, K; Egashira, Y; Watanabe, G [Mazda Motor Corp., Hiroshima (Japan)

    1997-10-01

    Vehicle and unit performance change according to not only external causes represented by the environment such as temperature or weather, but also internal causes which are dispersion of component characteristics and manufacturing processes or aged deteriorations. We developed the design method to estimate thus performance distributions with maximum entropy method and to calculate specifications with high performance robustness using Fuzzy theory. This paper describes the details of these methods and examples applied to power window system. 3 refs., 7 figs., 4 tabs.

  5. Today and tomorrow on optimization of structural systems. Kozo system saitekika no genjo to shorai

    Energy Technology Data Exchange (ETDEWEB)

    1992-07-20

    It has been 30 years since a conception structurally optimized design method'' was advocated as a new structural design system which links three factors; mathematical programming, a finite element method, and computers. This paper summarizes the current states in the optimizing technologies in Japan and views over their future, with reference mainly to the two symposiums held in the past as an activity of the subcommittee for structural system optimization in the Japan Society of Civil Engineers. The summary covers the following matters: Optimizing algorithms for structural designs, fuzzy theories, practical use of expert systems and AI, maintenance and management systems for structures, vibration control, shock resistant designs, inverse problems and structure identifying problems, and designs of underground and off-shore structures. For instance, examples of bridge designs include a minimum mass design on a pedestrians' bridge incorporating vibration sensitivities into restricting conditions, comparisons of economics in suspension bridges using a multi-stage determination method, and many others. Optimizing technologies are believed to advance greatly in the future and be used as a very routine design tool. 145 refs., 1 fig., 3 tabs.

  6. The complex transfer reaction (14C, 15O) on Ni, Zn and Ge targets: existence and mass of 69Ni

    International Nuclear Information System (INIS)

    Dessagne, P.; Bernas, M.; Langevin, M.; Pougheon, F.; Roussel, P.; Morrison, G.C.

    1984-01-01

    The ( 14 C, 15 O) complex transfer reaction has been studied at 72 MeV incident energy on 58 Ni, 60 Ni, 62 Ni, 64 Ni, 68 Zn, 70 Zn and 74 Ge, 76 Ge targets. Spectra and differential cross sections have been measured in a 5 0 angular range centred around a laboratory angle of 6 0 . The nucleus 69 Ni has been observed and its mass determined for the first time

  7. Electroless Ni-P/Ni-B duplex coatings: preparation and evaluation of microhardness, wear and corrosion resistance

    International Nuclear Information System (INIS)

    Narayanan, T.S.N. Sankara; Krishnaveni, K.; Seshadri, S.K.

    2003-01-01

    The present work deals with the formation of Ni-P/Ni-B duplex coatings by electroless plating process and evaluation of their hardness, wear resistance and corrosion resistance. The Ni-P/Ni-B duplex coatings were prepared using dual baths (acidic hypophosphite- and alkaline borohydride-reduced electroless nickel baths) with both Ni-P and Ni-B as inner layers and with varying single layer thickness. Scanning electron microscopy (SEM) was used to assess the duplex interface. The microhardness, wear resistance and corrosion resistance of electroless nickel duplex coatings were compared with electroless Ni-P and Ni-B coatings of similar thickness. The study reveals that the Ni-P and Ni-B coatings are amorphous in their as-plated condition and upon heat-treatment at 450 deg. C for 1 h, both Ni-P and Ni-B coatings crystallize and produce nickel, nickel phosphide and nickel borides in the respective coatings. All the three phases are formed when Ni-P/Ni-B and Ni-B/Ni-P duplex coatings are heat-treated at 450 deg. C for 1 h. The duplex coatings are uniform and the compatibility between the layers is good. The microhardness, wear resistance and corrosion resistance of the duplex coating is higher than Ni-P and Ni-B coatings of similar thickness. Among the two types of duplex coatings studied, hardness and wear resistance is higher for coatings having Ni-B coating as the outer layer whereas better corrosion resistance is offered by coatings having Ni-P coating as the outer layer

  8. Heavy metal environmental impact. Nickel (Ni); Impatto ambientale da metalli pesanti. Il Nichel (Ni)

    Energy Technology Data Exchange (ETDEWEB)

    Bressa, G. [Padua Univ. Padua (Italy). Dipt. di Farmacologia, Lab. di Tossicologia

    2001-02-01

    Nickel (Ni) is a heavy metal in over 3.000 different alloys used to produce kitchen utensils, batteries, coins, etc.. Human extractive and industrial activities are therefore a cause for environmental dispersion of this metal into the biosphere. This shows how in urban areas car traffic and house-heating are the main sources of nickel pollution. Nickel is relatively non-toxic, such as iron, cobalt, copper and zinc; nevertheless prolonged inhalation of dust containing such compounds as Ni O or NiCl{sub 2} concurs in the outbreak of respiratory pathologies. The carcinogenic effect of such compounds as Ni S, Ni O and Ni(CO){sub 4} has been confirmed by experiments on laboratory animals. Ni potentially toxic concentrations, and as a consequence of potential environmental impact, are to be mainly found in populated areas where the main sources are represented by industries and landfills. [Italian] Il nichel (Ni) e' un metallo presente in oltre 3.000 differenti leghe che vengono utilizzate per la produzione di utensili da cucina, batterie, monete, ecc.. Le attivita' estrattive ed industriali dell'uomo sono quindi causa di una dispersione del metallo nella biosfera. Sono stati riscontrati elevati tassi di Ni nell'atmosfera di aree urbane. Cio' sta a dimostrare che nelle aree urbane il traffico automobilistico e il riscaldamento domestico sono le fonti principali di inquinamento da tale metallo. Il nichel e' relativamente atossico, analogamente a ferro, cobalto, rame e zinco, tuttavia l'inalazione protratta di polveri contenenti composti come il NiO o il NiCl{sub 2} contribuisce al manifestarsi di patologie dell'apparato respiratorio. E' stato confermato sperimentalmente su animali da laboratorio l'effetto cancerogeno di alcuni composti quali NiS, NiO e Ni(CO){sub 4}. Concentrazioni potenzialmente tossiche di Ni, e quindi di probabile impatto ambientale, sono maggiormente da ricercare nelle zone antropizzate dove le fonti

  9. Ultrathin NiO/NiFe2O4 Nanoplates Decorated Graphene Nanosheets with Enhanced Lithium Storage Properties

    International Nuclear Information System (INIS)

    Du, Dejian; Yue, Wenbo; Fan, Xialu; Tang, Kun; Yang, Xiaojing

    2016-01-01

    Highlights: • Ultrathin NiO/NiFe 2 O 4 nanoplates derived from NiFe layered double hydroxides are fabricated on the graphene. • NiO/NiFe 2 O 4 nanoplates on the graphene show superior electrochemical performance compared to pure NiO/NiFe 2 O 4 aggregates. • The effects of the content and the particle size/component of NiO/NiFe 2 O 4 on the electrochemical performances are studied. • Graphene-encapsulated NiO/NiFe 2 O 4 is prepared and shows slightly decreased performance compared to graphene-based composite. - Abstract: As anode materials for lithium-ion batteries, bicomponent metal oxide composites show high reversible capacities; but the morphology and particle size of the composites are hardly controllable, which may reduce their electrochemical properties. In this work, ultrathin NiO/NiFe 2 O 4 nanoplates with a diameter of 5 ∼ 7 nm and a thickness of ∼2 nm are controllably fabricated on the graphene derived from NiFe layered double hydroxides (NiFe-LDHs), and exhibit superior electrochemical performance compared to pure NiO/NiFe 2 O 4 aggregates without graphene. The nanosized NiO and NiFe 2 O 4 plates are separated from each other and the graphene substrate can prevent the aggregation of NiO/NiFe 2 O 4 as well as enhance the electronic conductivity of the composite, which is beneficial to improving the electrochemical performance. Moreover, the effects of the content and the particle size/component of NiO/NiFe 2 O 4 on the electrochemical performances are also studied in order to achieve optimal performance. Ultrathin NiO/NiFe 2 O 4 nanoplates are further encapsulated by graphene nanosheets and show slightly decreased performance compared to those supported by graphene nanosheets. The different electrochemical behaviors of graphene-containing composites may be attributed to the different interactions between graphene nanosheets and NiO/NiFe 2 O 4 nanoplates.

  10. Investigation into the MgF2-NiF2, CaF2-NiF2, SrF2-NiF2 systems

    International Nuclear Information System (INIS)

    Ikrami, D.D.; Petrov, S.V.; Fedorov, P.P.; Ol'khovaya, L.A.; Luginina, A.A.; AN SSSR, Moscow. Inst. Fizicheskikh Problem; AN SSSR, Moscow. Inst. Kristallografii)

    1984-01-01

    Using the methods of differential thermal and X-ray phase analyses the systems MgF 2 -NiF 2 , CaF 2 -NiF 2 , SrF 2 -NiF 2 have been studied. In the system SrF 2 -NiF 2 the only orthorhombic compounds SrNiF 4 (a=14.43; b=3.93; c=5.66 (+-0.01 A)) is formed. SrNiF 4 density constitutes: dsub(X-ray)=4.60+-0.01 g/cm 3 , dsub(exp.)=4.60+-0.03 g/cm 3 . Refraction indices are as follows SrNiF 4 :Ng=1.500; Nsub(m)=1.497; Nsub(p)=1.479. SrNiF 4 magnetic ordering temperature Tsub(N) approximately 100 K

  11. Microstructure and mechanical properties of sputter deposited Ni/Ni{sub 3}Al multilayer films at elevated temperature

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Chao [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Feng, Kai, E-mail: fengkai@sjtu.edu.cn [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Li, Zhuguo, E-mail: lizg@sjtu.edu.cn [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Lu, Fenggui; Huang, Jian; Wu, Yixiong [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China)

    2016-08-15

    Highlights: • Ni/Ni{sub 3}Al multilayers are prepared by magnetron sputtering. • Both grain size and phase constitution of annealed Ni/Ni{sub 3}Al multilayers are dependent on individual layer thickness. • The hardness of annealed Ni/Ni{sub 3}Al multilayers varies with individual layer thickness and annealing temperature. • 40 nm Ni/Ni{sub 3}Al multilayer exhibits excellent hardness at elevated temperature. - Abstract: Nano-structured Ni/Ni{sub 3}Al multilayer was prepared by magnetron sputtering, with individual layer thicknesses h varying from 10 to 160 nm. The microstructure and hardness of Ni/Ni{sub 3}Al multilayer were investigated by X-ray diffraction, transmission electron microscopy and nanoindentation. The results show that the hardness increases with decreasing h for as-deposited and 500 °C annealed multilayers. When annealed at 700 °C, the hardness approach a peak value at h = 40 nm with followed by softening at smaller h. The influence of individual layer thickness, grain size as well as formation of ordered Ni{sub 3}Al on strengthening mechanisms of Ni/Ni{sub 3}Al multilayers at elevated temperature are discussed.

  12. Enhanced Electrocatalytic Activity for Water Splitting on NiO/Ni/Carbon Fiber Paper

    Directory of Open Access Journals (Sweden)

    Ruoyu Zhang

    2016-12-01

    Full Text Available Large-scale growth of low-cost, efficient, and durable non-noble metal-based electrocatalysts for water splitting is crucial for future renewable energy systems. Atomic layer deposition (ALD provides a promising route for depositing uniform thin coatings of electrocatalysts, which are useful in many technologies, including the splitting of water. In this communication, we report the growth of a NiO/Ni catalyst directly on carbon fiber paper by atomic layer deposition and report subsequent reduction and oxidation annealing treatments. The 10–20 nm NiO/Ni nanoparticle catalysts can reach a current density of 10 mA·cm−2 at an overpotential of 189 mV for hydrogen evolution reactions and 257 mV for oxygen evolution reactions with high stability. We further successfully achieved a water splitting current density of 10 mA·cm−2 at 1.78 V using a typical NiO/Ni coated carbon fiber paper two-electrode setup. The results suggest that nanoparticulate NiO/Ni is an active, stable, and noble-metal-free electrocatalyst, which facilitates a method for future water splitting applications.

  13. Ni(salen): a system that forms many solvates with interacting Ni atoms

    NARCIS (Netherlands)

    Siegler, M.A.M.; Lutz, M.

    2009-01-01

    Recrystallization of [N,N’-Ethylene-bis(salicylideneiminato)]-nickel(II) [Ni(salen)] has been carried out from a large selection of solvents. Crystals can be either solvent free or solvates. This study is based on X-ray crystal structure determinations, which include the redetermination of Ni(salen)

  14. Thermal stability of electrodeposited Ni and Ni-Co layers; an EBSD-study

    DEFF Research Database (Denmark)

    Rasmussen, Anette Alsted; Gholinia, A.; Trimby, P.W.

    2004-01-01

    The influence of heat treatment on the microstructure and the microtexture of electrodeposited Ni and Ni-Co layers was investigated with Electron Backscatter Diffraction (EBSD) with high resolution. Samples were annealed for 1 hour at 523 K and 673 K, the temperature region wherein...

  15. The role of Ni in sulfided carbon-supported Ni-Mo hydrodesulfurization catalysts

    NARCIS (Netherlands)

    Bouwens, S.M.A.M.; Barthe-Zahir, N.; Beer, de V.H.J.; Prins, R.

    1991-01-01

    The thiophene hydrodesulfurization activities of Ni and Ni---Mo sulfide catalysts supported on activated carbon were measured at atmospheric pressure and the catalyst structures were studied by means of X-ray photoelectron spectroscopy, dynamic oxygen chemisorption, and chemical sulfur analysis. The

  16. Mechanical properties of NiO/Ni-YSZ composites depending on temperature, porosity and redox cycling

    DEFF Research Database (Denmark)

    Pihlatie, Mikko; Kaiser, Andreas; Mogensen, Mogens Bjerg

    2009-01-01

    The Impulse Excitation Technique (IET) was used to determine the elastic modulus and specific damping of different Ni/NiO-YSZ composites suitable for use in solid oxide fuel cells (SOFC). The porosity of the as-sintered samples varied from 9 to 38% and that of the reduced ones from 31 to 52%. For...

  17. Climate Prediction Center - El Niño/La Niña Home

    Science.gov (United States)

    Weather Service NWS logo - Click to go to the NWS home page Climate Prediction Center Site Map News Information CPC Web Team HOME > El Niño/La Niña Forecasts Current U.S. Climate Outlook SST Forecasts Temperature and Anomalies NOAA/ National Weather Service National Centers for Environmental Prediction Climate

  18. Synthesis and magnetic properties of multilayer Ni/Cu and NiFe/Cu ...

    Indian Academy of Sciences (India)

    The diameter of wires can be easily varied by pore size of alumina, ranging ... saturated HgCl2 solution to remove the remaining Al, and then dipped in 5 wt% ... for NiFe alloy it is 1.3 V, that is higher than for Ni/Cu nanowires to diminish Cu.

  19. Effect of solute atoms on swelling in Ni alloys and pure Ni under He + ion irradiation

    Science.gov (United States)

    Wakai, E.; Ezawa, T.; Imamura, J.; Takenaka, T.; Tanabe, T.; Oshima, R.

    2002-12-01

    The effects of solute atoms on microstructural evolutions have been investigated using Ni alloys under 25 keV He + irradiation at 500 °C. The specimens used were pure Ni, Ni-Si, Ni-Co, Ni-Cu, Ni-Mn and Ni-Pd alloys with different volume size factors. The high number densities of dislocation loops about 1.5×10 22 m -3 were formed in the specimens irradiated to 1×10 19 ions/m 2, and they were approximately equivalent, except for Ni-Si. The mean size of loops tended to increase with the volume size factor of solute atoms. In a dose of 4×10 20 ions/m 2, the swelling was changed from 0.2% to 4.5%, depending on the volume size factors. The number densities of bubbles tended to increase with the absolute values of the volume size factor, and the swelling increased with the volume size factors. This suggests that the mobility of helium and vacancy atoms may be influenced by the interaction of solute atoms with them.

  20. Bonding Strength of Ni/Ni3Al Interface with Different Lattice Misfit

    Institute of Scientific and Technical Information of China (English)

    Ping PENG; Caixing ZHENG; Shaochang HAN; Zhaohui JIN; Rui YANG; Zhuangqi HU

    2003-01-01

    The interfacial binding covalent bond density (CBD) and the local environmental total bond order (LTBO) of the Ni/Ni3Alinterface with different lattice misfits (δ) were calculated by using first-principles discrete variation Xα method. It was foundthat

  1. Electrochemical Behaviour of Ni and Ni-PVC Electrodes for the Electroxidation of Ethanol

    International Nuclear Information System (INIS)

    Mohd Syafiq Hamdan; Norazzizi Nordin; Siti Fathrita Mohd Amir; Riyanto; Mohamed Rozali Othman

    2011-01-01

    In this study, two nickel based electrodes were prepared; nickel foil and nickel-polyvinylchloride (Ni-PVC), in order to study their electrochemical behavior using cyclic voltammetry, CV and chronocoulometry, CC. Ni electrode was prepared from Ni metal foil while Ni-PVC electrode was prepared by mixing a weighed portion of Ni powder and PVC in THF solvent, swirled until the suspension was homogeneous and drying the suspension in an oven at 50 degree Celsius for 3 h. The dry sample was then placed in a 1 cm diameter stainless steel mould and pressed at 10 ton/ cm 2 . From CV data, Ni-PVC electrode showed a better electrochemical behavior compared to Ni metal foil electrode. The use of Ni-PVC electrode at higher concentration of supporting electrolyte (1.0 M KOH) was better than at lower concentration of the same supporting electrolyte in electroxidation of ethanol. In addition to acetic acid, the oxidation of ethanol also produced ethyl acetate and acetaldehyde. (author)

  2. Room-temperature ferromagnetism in Dy films doped with Ni

    Energy Technology Data Exchange (ETDEWEB)

    Edelman, I. [Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036 (Russian Federation)], E-mail: ise@iph.krasn.ru; Ovchinnikov, S. [Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036 (Russian Federation); Siberian Federal University, Av. Svobodnyi 71, Krasnoyarsk 660074 (Russian Federation); Markov, V.; Kosyrev, N.; Seredkin, V.; Khudjakov, A.; Bondarenko, G. [Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036 (Russian Federation); Kesler, V. [Institute of Semiconductor Physics, Siberian Division, Russian Academy of Sciences, Av. Akademika Lavrent' eva 13, Novosibirsk 630090 (Russian Federation)

    2008-09-01

    Temperature, magnetic field and spectral dependences of magneto-optical effects (MOEs) in bi-layer films Dy{sub (1-x)}Ni{sub x}-Ni and Dy{sub (1-x)}(NiFe){sub x}-NiFe were investigated, x changes from 0 to 0.06. Peculiar behavior of the MOEs was revealed at temperatures essentially exceeding the Curie temperature of bulk Dy which is explained by the magnetic ordering of the Dy layer containing Ni under the action of two factors: Ni impurities distributed homogeneously over the whole Dy layer and atomic contact of this layer with continues Ni layer. The mechanism of the magnetic ordering is suggested to be associated with the change of the density of states of the alloy Dy{sub (1-x)}Ni{sub x} owing to hybridization with narrow peaks near the Fermi level character for Ni.

  3. Room-temperature ferromagnetism in Dy films doped with Ni

    International Nuclear Information System (INIS)

    Edelman, I.; Ovchinnikov, S.; Markov, V.; Kosyrev, N.; Seredkin, V.; Khudjakov, A.; Bondarenko, G.; Kesler, V.

    2008-01-01

    Temperature, magnetic field and spectral dependences of magneto-optical effects (MOEs) in bi-layer films Dy (1-x) Ni x -Ni and Dy (1-x) (NiFe) x -NiFe were investigated, x changes from 0 to 0.06. Peculiar behavior of the MOEs was revealed at temperatures essentially exceeding the Curie temperature of bulk Dy which is explained by the magnetic ordering of the Dy layer containing Ni under the action of two factors: Ni impurities distributed homogeneously over the whole Dy layer and atomic contact of this layer with continues Ni layer. The mechanism of the magnetic ordering is suggested to be associated with the change of the density of states of the alloy Dy (1-x) Ni x owing to hybridization with narrow peaks near the Fermi level character for Ni

  4. Elementary martensitic transformation processes in Ni-rich NiTi single crystals with Ni4Ti3 precipitates

    International Nuclear Information System (INIS)

    Michutta, J.; Somsen, Ch.; Yawny, A.; Dlouhy, A.; Eggeler, G.

    2006-01-01

    The present study shows that multiple-step martensitic transformations can be observed in aged Ni-rich NiTi single crystals. Ageing of solution-annealed and water-quenched Ni-rich NiTi single crystals results in a homogeneous precipitation of coherent Ni 4 Ti 3 particles. When the interparticle spacing reaches a critical value (order of magnitude: 200 nm), three distinct transformation processes are observed on cooling from the high-temperature phase using differential scanning calorimetry and in situ transmission electron microscopy. The transformation sequence begins with the formation of R-phase starting from all precipitate/matrix interfaces (first step). The transformation continues with the formation of B19' and its subsequent growth along all precipitate/matrix interfaces (second step). Finally, the matrix in between the precipitates transforms to B19' (third step). Elementary transformation mechanisms which account for two- and three-step transformations in a system with small-scale microstructural heterogeneities were identified

  5. Probing the semi-magicity of $^{68}$Ni via the $^{3}$H($^{66}$Ni,$^{68}$Ni)p two-neutron transfer reaction in inverse kinematics

    CERN Multimedia

    Reiter, P; Blazhev, A A; Kruecken, R; Franchoo, S; Mertzimekis, T; Darby, I G; Van de walle, J; Raabe, R; Elseviers, J; Gernhaeuser, R A; Sorlin, O H; Georgiev, G P; Bree, N C F; Habs, D; Chapman, R; Gaudefroy, L; Diriken, J V J; Jenkins, D G; Kroell, T; Axiotis, M; Huyse, M L; Patronis, N

    We propose to perform the two-neutron transfer reaction $^{3}$H($^{66}$Ni, $^{68}$Ni)$p$ using the ISOLDE radioactive ion beam at 2.7 $A$ MeV and the MINIBALL + T-REX setup to characterize the 0$^{+}$ and 2$^{+}$ states in $^{68}$Ni.

  6. Mechanical alloying of the FeNi-Ag system

    International Nuclear Information System (INIS)

    Gonzalez, G.; Ibarra, D.; Ochoa, J.; Villalba, R.; Sagarzazu, A.

    2007-01-01

    The Fe-Ni-Ag system is of particular interest for its potential applications as soft magnetic granular material with small magnetic grains embedded in a non-magnetic metal matrix. Under equilibrium conditions: Fe-Ag and Ni-Ag are immiscible and Fe-Ni shows complete solubility. These materials are particularly important for magnetoresistivity properties. The properties of these alloys are closely related to their microstructure; therefore, a detailed study of the transformations occurring during milling was undertaken using pre-alloyed Fe x Ni 100-x (x = 30, 50 and 70) further milled with different Ag content to give the following alloys compositions (Fe x -Ni 100-x ) 100-y Ag y (y = 5, 20, 60). Consolidation of the mechanically alloyed powders by sintering at 950 o C was performed. Morphological and structural characterization of the sintered powders was carried out by scanning and transmission electron microscopy and X-ray diffraction. Fe 30 Ni 70 and Fe 50 Ni 50 formed ordered FeNi 3 compound. Fe 70 Ni 30 showed the formation of a mixture of γ-(Fe,Ni) and α-Fe(Ni) solid solutions. The mixture of these systems with Ag showed the metal solid solutions surrounded by Ag islands of Fe x Ni y -Ag, There was also evidence of Ag diffusing into the γ-(Fe,Ni). High Ag content (60%) shows formation of islands of FeNi surrounded by Ag. Sintering is always improved with the Ag content

  7. Effect of amount of glycine as fuel in obtaining nanocomposite Ni/NiO

    International Nuclear Information System (INIS)

    Simoes, A.N.; Simoes, V.N.; Neiva, L.S.; Quirino, M.R.; Vieira, D.A.; Gama, L.

    2010-01-01

    This paper proposes to investigate the effect of the amount of glycine in obtaining nanocomposite Ni/NiO synthesized by combustion reaction technique. The amount of glycine used was calculated on the stoichiometric composition of 50% and 100%. Characterizations by X-ray diffraction (XRD), N2 adsorption by the BET method and scanning electron microscopy (SEM) were performed with powder of Ni/NiO result. The analysis of X-ray diffraction showed the presence of crystalline NiO phase in the presence of nickel as a secondary phase, whose amount increased with the amount of glycine. Increasing the concentration of glycine also caused an increase in surface area, which ranged from 1.1 to 1.4 m 2 /g. The micrographs revealed the formation of soft agglomerates with porous appearance and easy dispersions. It can be concluded that the synthesis is effective to obtain nanosized powders. (author)

  8. Neutron enrichment at midrapidity in 58Ni + 58Ni at 52 MeV/u

    International Nuclear Information System (INIS)

    Theriault, D.; Vallee, A.; Gingras, L.; Larochelle, Y.; Roy, R.; April, A.; Beaulieu, L.; Grenier, F.; Lemieux, F.; Moisan, J.; Samri, M.; Saint-Pierre, C.; Turbide, S.; Yennello, S.J.; Martin, E.; Winchester, E.

    2003-01-01

    By combining data from a charged particle 58 Ni + 58 Ni experiment at 52 MeV/u with an 36 Ar + 58 Ni experiment at 50 MeV/u for which free neutrons have been detected, an increase in the neutron to proton ratio of the whole nuclear material at midrapidity has been experimentally observed in the reaction 58 Ni + 58 Ni at 52 MeV/u. The neutron to proton ratio is measured above the initial neutron to proton ratio of the system. Neutron to proton ratio of the quasi-projectile emission is analysed for the same reactions and is seen to decrease below the ratio of the initial system. (authors)

  9. Improvement of thermoelectric properties for half-Heusler TiNiSn by interstitial Ni defects

    International Nuclear Information System (INIS)

    Hazama, Hirofumi; Matsubara, Masato; Asahi, Ryoji; Takeuchi, Tsunehiro

    2011-01-01

    We have synthesized off-stoichiometric Ti-Ni-Sn half-Heusler thermoelectrics in order to investigate the relation between randomly distributed defects and thermoelectric properties. A small change in the composition of Ti-Ni-Sn causes a remarkable change in the thermal conductivity. An excess content of Ni realizes a low thermal conductivity of 2.93 W/mK at room temperature while keeping a high power factor. The low thermal conductivity originates in the defects generated by an excess content of Ni. To investigate the detailed defect structure, we have performed first-principles calculations and compared with x ray photoemission spectroscopy measurement. Based on these analyses, we conclude that the excess Ni atoms randomly occupy the vacant sites in the half-Heusler structure, which play as phonon scattering centers, resulting in significant improvement of the figure of merit without any substitutions of expensive heavy elements, such as Zr and Hf.

  10. Magnetoresistance of nanogranular Ni/NiO controlled by exchange anisotropy

    International Nuclear Information System (INIS)

    Del Bianco, L.; Spizzo, F.; Tamisari, M.; Allia, P.

    2013-01-01

    A link between exchange anisotropy and magnetoresistance has been found to occur in a Ni/NiO sample consisting of Ni nanocrystallites (mean size ∼13 nm, Ni content ∼33 vol%) dispersed in a NiO matrix. This material shows metallic-type electric conduction and isotropic spin-dependent magnetoresistance as well as exchange bias effect. The latter is the outcome of an exchange anisotropy arising from the contact interaction between the Ni phase and the NiO matrix. Combined analysis of magnetization M(H) and magnetoresistance MR(H) loops measured in the 5–250 K temperature range after zero-field-cooling (ZFC) and after field-cooling (FC) from 300 K reveals that the magnetoresistance is influenced by exchange anisotropy, which is triggered by the FC process and can be modified in strength by varying the temperature. Compared to the ZFC case, the exchange anisotropy produces a horizontal shift of the FC MR(H) loop along with a reduction of the MR response associated to the reorientation of the Ni moments. A strict connection between magnetoresistance and remanent magnetization of FC loops on one side and the exchange field on the other, ruled by exchange anisotropy, is indicated. - Highlights: • Nanogranular Ni/NiO with giant magnetoresistance (MR) and exchange bias effect. • Exchange anisotropy produces a shift of the field-cooled MR(H) loop and reduces MR. • MR, remanence of field-cooled loops and exchange field are three correlated quantities. • It is possible to control MR of nanogranular systems through the exchange anisotropy

  11. Ferromagnetic resonance study of sputtered NiFe/V/NiFe heterostructures

    Energy Technology Data Exchange (ETDEWEB)

    Alayo, W., E-mail: willian.rodriguez@ufpel.edu.br [Departamento de Física – IFM, Universidade Federal de Pelotas, 96010-900 Rio Grande do Sul (Brazil); Pelegrini, F. [Instituto de Física, Universidade Federal de Goiás, Goiânia, 74001-970 (Brazil); Baggio-Saitovitch, E. [Centro Brasileiro de Pesquisas Físicas, Rio de Janeiro, RJ, 22290-180 (Brazil)

    2015-03-01

    The Ni{sub 81}Fe{sub 19}/V/Ni{sub 81}Fe{sub 19} heterostructures has been produced by magnetron sputtering and analyzed by ferromagnetic resonance. Two systems were investigated: the non symmetrical NiFe(50 Å)/V(t)/NiFe(30 Å) trilayers and the symmetrical NiFe(80 Å)/V(t)/NiFe(80 Å) trilayers, with variable ultrathin V thickness t. Ferromagnetic exchange coupling was evidenced for t below 10 Å by the excitation of the optic mode, in the case of the non symmetrical samples, and by the observation of a single resonance mode for the symmetrical trilayers. For larger V thickness, all samples exhibited two modes, which were attributed to the resonance of the individual NiFe layers with different effective magnetizations. The analysis with the equilibrium and resonance conditions provided the exchange coupling constants and effective magnetizations. - Highlights: • We present a study of symmetrical and non symmetrical NiFe/V/NiFe trilayers deposited on Si single crystals by ferromagnetic resonance (FMR) at room temperature. • For the non symmetrical trilayers, the FMR spectra show the optic and acoustic modes for samples with very thin V layer thicknesses, evidencing ferromagnetic exchange coupling, whereas, for larger V thickness, the spectra exhibited two well resolved modes associated to each independent NiFe layer. For the symmetrical trilayers, strong ferromagnetic exchange coupling is evidenced by the observation of a single resonance mode. • The analysis with the equilibrium condition and dispersion relation provides the exchange coupling constants and effective magnetizations.

  12. Hydrogen absorption kinetics and structural properties of Mg85Ni10Ca5 and Mg90Ni10

    International Nuclear Information System (INIS)

    Aoki, Masakazu; Saito, Katsushi; Towata, Shin-ichi

    2005-01-01

    Mg 85 Ni 10 Ca 5 and Mg 90 Ni 10 were prepared by melting mixtures of the elements in mild steel crucibles and pouring them into copper molds. Hydrogen absorption kinetics and structural properties of the alloys were characterized by the volumetric method using a Sievert's apparatus, X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The crystallite size of Mg in Mg 85 Ni 10 Ca 5 , which is evaluated by XRD peak broadening, is about 50% smaller than that in Mg 90 Ni 10 . In addition, the nanometer-scale structure composed of Mg, Mg 2 Ni, Mg 2 Ca was observed in Mg 85 Ni 10 Ca 5 . Mg 85 Ni 10 Ca 5 shows better hydrogen absorption kinetics than Mg 90 Ni 10 in the temperature range of room temperature to 573 K. The better absorption kinetics of Mg 85 Ni 10 Ca 5 is mainly attributed to the nanometer-scale structure

  13. Sputtering Yields of Si and Ni from the Ni1-xSix System Studied by Rutherford Backscattering Spectrometry

    Science.gov (United States)

    Kim, Su Chol; Yamaguchi, Satoru; Kataoka, Yoshihide; Iwami, Motohiro; Hiraki, Akio; Satou, Mamoru; Fujimoto, Fuminori

    1982-01-01

    Sputtering yields of Si and Ni from thin layer films of Ni-Si compounds (Ni1-xSix), including the pure materials (Ni and Si), caused by 5 keV Ar+ ion bombardment were investigated using backscattering spectrometry. The sputtering yield for Si from Ni1-xSix increased with increasing Si concentration. However, there is an abrupt decrease in the yield for Si concentrations above NiSi2 to pure Si. This is in clear contrast to the sputtering yield of Ni from Ni1-xSix which increased with increasing Ni concentration monotonously. These results are discussed on the basis of both the difference in the atomic density and the electronic state of the alloy.

  14. Phase Equilibria of the Sn-Ni-Si Ternary System and Interfacial Reactions in Sn-(Cu)/Ni-Si Couples

    Science.gov (United States)

    Fang, Gu; Chen, Chih-chi

    2015-07-01

    Interfacial reactions in Sn/Ni-4.5 wt.%Si and Sn-Cu/Ni-4.5 wt.%Si couples at 250°C, and Sn-Ni-Si ternary phase equilibria at 250°C were investigated in this study. Ni-Si alloys, which are nonmagnetic, can be regarded as a diffusion barrier layer material in flip chip packaging. Solder/Ni-4.5 wt.%Si interfacial reactions are crucial to the reliability of soldered joints. Phase equilibria information is essential for development of solder/Ni-Si materials. No ternary compound is present in the Sn-Ni-Si ternary system at 250°C. Extended solubility of Si in the phases Ni3Sn2 and Ni3Sn is 3.8 and 6.1 at.%, respectively. As more Si dissolves in these phases their lattice constants decrease. No noticeable ternary solubility is observed for the other intermetallics. Interfacial reactions in solder/Ni-4.5 wt.%Si are similar to those for solder/Ni. Si does not alter the reaction phases. No Si solubility in the reaction phases was detected, although rates of growth of the reaction phases were reduced. Because the alloy Ni-4.5 wt.%Si reacts more slowly with solders than pure Ni, the Ni-4.5 wt.%Si alloy could be a potential new diffusion barrier layer material for flip chip packaging.

  15. Ni/boride interfaces and environmental embrittlement in Ni-based superalloys: A first-principles study

    International Nuclear Information System (INIS)

    Sanyal, Suchismita; Waghmare, Umesh V.; Hanlon, Timothy; Hall, Ernest L.

    2011-01-01

    Highlights: ► Fracture strengths of Ni/boride interfaces through first-principles calculations. ► Fracture strengths of Ni/boride interfaces are higher than Ni/Ni 3 Al and NiΣ5 grain boundaries. ► Ni/boride interfaces have higher resistance to O-embrittlement than Ni/Ni 3 Al and NiΣ5 grain boundaries. ► CrMo-borides are more effective than Cr-borides in resisting O-embrittlement. ► Electronegativity differences between alloying elements correlate with fracture strengths. - Abstract: Motivated by the vital role played by boride precipitates in Ni-based superalloys in improving mechanical properties such as creep rupture strength, fatigue crack growth rates and improved resistance towards environmental embrittlement , we estimate fracture strength of Ni/boride interfaces through determination of their work of separation using first-principles simulations. We find that the fracture strength of Ni/boride interfaces is higher than that of other commonly occurring interfaces in Ni-alloys, such as Ni Σ-5 grain boundaries and coherent Ni/Ni 3 Al interfaces, and is less susceptible to oxygen-induced embrittlement. Our calculations show how the presence of Mo in Ni/M 5 B 3 (M = Cr, Mo) interfaces leads to additional reduction in oxygen-induced embrittlement. Through Electron-Localization-Function based analyses, we identify the electronic origins of effects of alloying elements on fracture strengths of these interfaces and observe that chemical interactions stemming from electronegativity differences between different atomic species are responsible for the trends in calculated strengths. Our findings should be useful towards designing Ni-based alloys with higher interfacial strengths and reduced oxygen-induced embrittlement.

  16. Nickel distribution and isotopic fractionation in a Brazilian lateritic regolith: Coupling Ni isotopes and Ni K-edge XANES

    Science.gov (United States)

    Ratié, G.; Garnier, J.; Calmels, D.; Vantelon, D.; Guimarães, E.; Monvoisin, G.; Nouet, J.; Ponzevera, E.; Quantin, C.

    2018-06-01

    Ultramafic (UM) rocks are known to be nickel (Ni) rich and to weather quickly, which makes them a good candidate to look at the Ni isotope systematics during weathering processes at the Earth's surface. The present study aims at identifying the Ni solid speciation and discussing the weathering processes that produce Ni isotope fractionation in two deep laterite profiles under tropical conditions (Barro Alto, Goiás State, Brazil). While phyllosilicates and to a lower extent goethite are the main Ni-bearing phases in the saprolitic part of the profile, iron (Fe) oxides dominate the Ni budget in the lateritic unit. Nickel isotopic composition (δ60Ni values) has been measured in each unit of the regolith, i.e., rock, saprock, saprolite and laterite (n = 52). δ60Ni varies widely within the two laterite profiles, from -0.10 ± 0.05‰ to 1.43 ± 0.05‰, showing that significant Ni isotope fractionation occurs during the weathering of UM rocks. Overall, our results show that during weathering, the solid phase is depleted in heavy Ni isotopes due to the preferential sorption and incorporation of light Ni isotopes into Fe oxides; the same mechanisms likely apply to the incorporation of Ni into phyllosilicates (type 2:1). However, an isotopically heavy Ni pool is observed in the solid phase at the bottom of the saprolitic unit. This feature can be explained by two hypotheses that are not mutually exclusive: (i) a depletion in light Ni isotopes during the first stage of weathering due to the preferential dissolution of light Ni-containing minerals, and (ii) the sorption or incorporation of isotopically heavy Ni carried by percolating waters (groundwater samples have δ60Ni of 2.20 and 2.27‰), that were enriched in heavy Ni isotopes due to successive weathering processes in the overlying soil and laterite units.

  17. The acceleration intermediate phase (NiS and Ni3S2) evolution by nanocrystallization in Li/NiS2 thermal batteries with high specific capacity

    Science.gov (United States)

    Jin, Chuanyu; Zhou, Lingping; Fu, Licai; Zhu, Jiajun; Li, Deyi; Yang, Wulin

    2017-06-01

    The intermediate phase of NiS2 is thought to be a bottleneck currently to improve the overall performance of Li/NiS2 thermal batteries because of its low conductivity and close formation enthalpy between NiS2 and the intermediate phase (NiS, Ni3S2, etc). For improving the discharge performances of Li/NiS2 thermal batteries, the nano NiS2 with an average size of 85 ± 5 nm is designated as a cathode material. The electrochemical measurements show that the specific capacity of nano NiS2 cathode is higher than micro NiS2. The nano NiS2 cathode exhibits excellent electrochemical performances with high specific capacities of 794 and 654 mAh g-1 at current density of 0.1 and 0.5 A cm-2 under a cut-off voltage of 0.5 V, respectively. These results show that the rapid intermediate phase evolution from the nanocrystallization can obviously enhance use efficiency of NiS2 and improve discharge performances of thermal batteries.

  18. Room temperature isotherms for Mo and Ni

    International Nuclear Information System (INIS)

    Masse, J.L.

    1986-11-01

    Isotherms at room temperature for Mo and Ni are proposed. They are of three types: BIRCH, KEANE and BORN-MIE. The adjustable constants appearing in these isotherms have been determined from experimental quantities at zero pressure. An evaluation of the limit of (δB T /δP) T as P #-> # ∞, where B T is the isothermal bulk modulus, has been also used. These three isotherms obtained for Mo and Ni are compared with isotherms derived from shock-wave data according to the PRIETO's model. There is a good agreement between these and these derived from shock-wave data. The three isotherms proposed for Mo and Ni can be considered as valid until pressures of several B To , where B To is the bulk modulus B T at P = o [fr

  19. Advances in developing TiNi nanoparticles

    International Nuclear Information System (INIS)

    Castro, A. Torres; Cuellar, E. Lopez; Mendez, U. Ortiz; Yacaman, M. Jose

    2006-01-01

    The elaboration of nanoparticles has become a field of great interest for many scientists. Nanoparticles possess different properties than those ones shown in bulk materials. Shape memory alloys have the exceptional ability to recuperate its original shape by simple heating after being 'plastically' deformed. When this process is originated, important changes in properties, as mechanical and electrical, are developed in bulk material. If there is possible to obtain nanoparticles with shape memory effects, these nanoparticles could be used in the elaboration of nanofluids with the ability to change their electrical and thermal conductivity with temperature changes, i.e., smart nanofluids. In this work, some recent results and discussion of TiNi nanoparticles obtained by ion beam milling directly from a TiNi wire with shape memory are presented. The nanoparticles obtained by this process are about 2 nm of diameter with a composition of Ti-41.0 at.% Ni. Synthesized nanoparticles elaborated by this method have an ordered structure

  20. Cutting NiTi with Femtosecond Laser

    Directory of Open Access Journals (Sweden)

    L. Quintino

    2013-01-01

    Full Text Available Superelastic shape memory alloys are difficult to machine by thermal processes due to the facility for Ti oxidation and by mechanical processes due to their superelastic behavior. In this study, femtosecond lasers were tested to analyze the potential for machining NiTi since femtosecond lasers allow nonthermal processing of materials by ablation. The effect of processing parameters on machining depth was studied, and material removal rates were computed. Surfaces produced were analyzed under SEM which shows a resolidified thin layer with minimal heat affected zones. However, for high cutting speeds, that is, for short interaction times, this layer was not observed. A depletion of Ni was seen which may be beneficial in biomedical applications since Ni is known to produce human tissue reactions in biophysical environments.

  1. La niña proletaria

    Directory of Open Access Journals (Sweden)

    Cartabia, Sabrina A.

    2011-12-01

    Full Text Available El presente trabajo se propone trazar un paralelo entre el cuento de Osvaldo Lamborghini “El niño proletario”, el cual, según la autora del ensayo, introduce al lector en la lucha de clases y el sometimiento de los/as proletarios/as, que sufren las mujeres, en particular a través de la violencia sexual. De esa forma la autora se pregunta si el poder que ciertas clases detentan sobre otras no influye también sobre el sometimiento de la mujer. El ensayo analiza además cómo la violencia sexual es una herramienta que constituye la base de la desigualdad, el sometimiento y la degradación de la mujer, al igual que constituye una herramienta de opresión de otros grupos vulnerables como los niños y niñas.

  2. Effects of phase transformation and interdiffusion on the exchange bias of NiFe/NiMn

    International Nuclear Information System (INIS)

    Lai, Chih-Huang; Lien, W. C.; Chen, F. R.; Kai, J. J.; Mao, S.

    2001-01-01

    The correlation between the exchange field of NiFe/NiMn and the phase transformation of NiMn was investigated. Transmission electron microscopy (TEM) dark-field images, contributed by the order phase of NiMn, were used to identify the location and volume fraction of the order phase. TEM selected area diffraction patterns showed the (110) superlattice diffraction rings of NiMn, verifying the existence of the order phase in the annealed samples. The order volume fraction can be calculated by the dark field image contributed by the (110) diffraction. The exchange field increased almost linearly with increasing order volume fraction. Energy dispersive x-ray spectroscopy attached to TEM indicated that Mn diffused into NiFe for annealing at 280 degreeC, leading to a larger coercivity and small coercivity squareness. Part of the NiMn still maintains the paramagnetic phase even after annealing at 280 degreeC. [copyright] 2001 American Institute of Physics

  3. Ni3Si2 nanowires grown in situ on Ni foam for high-performance supercapacitors

    Science.gov (United States)

    Jiang, Yizhe; Li, Zhihui; Li, Beibei; Zhang, Jinying; Niu, Chunming

    2016-07-01

    Ni3Si2 nanowires and nanoawls have grown in situ on the surface of Ni foams by a controlled low pressure chemical vapor deposition process. Structural characterization shows that the individual Ni3Si2 nanowire is single crystal covered with a thin layer (1-2 nm) of SiO2 with a diameter of ∼20-30 nm and length of ten's micrometers. Individual nanoawl with a circular cone shape is polycrystalline. Both Ni3Si2 nanowire and nanoawl samples are evaluated as potential electrode materials for supercapacitors. The nanowire electrode delivers a very high specific capacitance and excellent rate capability. A specific capacitance of 760 F g-1 is measured at current density of 0.5 A g-1, which decreases to 518 F g-1 when the current density increases to 10 A g-1. The capacitance is dominated by pseudocapacitance with a mechanism similar to that of NiO or Ni(OH)2 widely studied in the literature. An asymmetric supercapacitor fabricated by pairing Ni3Si2 nanowire electrode with an activated carbon electrode exhibits energy densities of 17.5 Wh kg-1 and 8.8 Wh kg-1 at power densites of 301 W kg-1 and 3000 W kg-1.

  4. Exchange bias in finite sized NiO nanoparticles with Ni clusters

    Energy Technology Data Exchange (ETDEWEB)

    Gandhi, Ashish Chhaganlal; Lin, Jauyn Grace, E-mail: jglin@ntu.edu.tw

    2017-02-15

    Structural and magnetic properties of finite sized NiO nanoparticles are investigated with synchrotron X-ray diffraction (XRD), transmission electron microscopy, magnetometer and ferromagnetic resonance (FMR) spectroscopy. A minor Ni phase is detected with synchrotron XRD, attributed to the oxygen defects in the NiO core. A considerable exchange bias of ~100 Oe is observed at 50 K and it drops abruptly and vanishes above 150 K, in association with the reduction of frozen spins. FMR data indicate a strong interaction between ferromagnetic (FM) and antiferromagnetic (AFM) phases below 150 K, consistent with the picture of isolated FM clusters in AFM matrix. - Highlights: • Structural and magnetic properties of finite sized NiO nanoparticles are systematically investigated with several advanced techniques. • A strong interaction between ferromagnetic and antiferromagnetic phases is found below 150 K. • Exchange bias field in finite sized NiO nanoparticles is due to anisotropy energy of Ni clusters over riding the domain wall energy of NiO.

  5. Radiation damage buildup and dislocation evolution in Ni and equiatomic multicomponent Ni-based alloys

    Energy Technology Data Exchange (ETDEWEB)

    Levo, E. [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Granberg, F., E-mail: fredric.granberg@helsinki.fi [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Fridlund, C.; Nordlund, K. [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Djurabekova, F. [Department of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland); Helsinki Institute of Physics, P.O. Box 43, FIN-00014, University of Helsinki (Finland)

    2017-07-15

    Single-phase multicomponent alloys of equal atomic concentrations (“equiatomic”) have proven to exhibit promising mechanical and corrosion resistance properties, that are sought after in materials intended for use in hazardous environments like next-generation nuclear reactors. In this article, we investigate the damage production and dislocation mobility by simulating irradiation of elemental Ni and the alloys NiCo, NiCoCr, NiCoFe and NiFe, to assess the effect of elemental composition. We compare the defect production and the evolution of dislocation networks in the simulation cells of two different sizes, for all five studied materials. We find that the trends in defect evolution are in good agreement between the different cell sizes. The damage is generally reduced with increased alloy complexity, and the dislocation evolution is specific to each material, depending on its complexity. We show that increasing complexity of the alloys does not always lead to decreased susceptibility to damage accumulation under irradiation. We show that, for instance, the NiCo alloy behaves very similarly to Ni, while presence of Fe or Cr in the alloy even as a third component reduces the saturated level of damage substantially. Moreover, we linked the defect evolution with the dislocation transformations in the alloys. Sudden drops in defect number and large defect fluctuations from the continuous irradiation can be explained from the dislocation activity.

  6. Corrosion Resistance Of Electroless Ni-P/Cu/Ni-P Multilayer Coatings

    Directory of Open Access Journals (Sweden)

    Zhao G.L.

    2015-06-01

    Full Text Available Ni-P/Cu/Ni-P multilayer coatings were prepared by deposition of Cu layer between two Ni–P layers. The Cu layer was deposited by metal displacement reaction between Cu2+ and Fe atoms. Corrosion behavior of single-layer Ni-P coatings, double-layer Ni-P/Cu coatings, and three-layer Ni-P/Cu/Ni-P coatings were investigated by electrochemical tests in 3.5% NaCl solution. The three-layer coatings exhibited more positive Ecorr and decreased Icorr compared with conventional single-layer Ni-P coatings, which indicated an improved corrosion resistance. The polarization curves of the three-layer coatings were characterized by two passive regions. The improved corrosion resistance was not only attributed to the function of the blocked pores of Cu. The Cu interlayer also acted as a sacrificial layer instead of a barrier in the coatings, which altered the corrosion mechanism and further improved the corrosion resistance of the coatings.

  7. PRECIPITATION HARDENING IN B2-ORDERED NiAl BY Ni2AlTiCOMPOUND

    Institute of Scientific and Technical Information of China (English)

    W.H. Tian; K. Ohishi; M. Nemoto

    2001-01-01

    Microstructural variations and correlated hardness changes in B2-ordered NiAl containing fine precipitation of Ni2AlTi have been investigated by means of transmission electron microscopy (TEM) and hardness tests. The amount of age hardening is not large as compared to the large microstructural variations during aging. TEM observations have revealed that the L21-type Ni2AlTi precipitates keep a lattice coherency with the NiAl matrix at the beginning of aging. By longer periods of aging Ni2AlTi precipitates lose their coherency and change their morphology to the globular ones surrounded by misfit dislocations. The temperature dependence of the yield strength of precipitate-containing B2-ordered NiAl was investigated by compression tests over the temperature range of 873-1273K. The fine precipitation of Ni2AlTi was found to enhance greatly the yield strength and the high-temperature strength is comparison with that of superalloy Mar-M200.``

  8. Development of small-scale electroplating system for Ni-63 electroplating onto Ni foil

    International Nuclear Information System (INIS)

    Kim, Jin Joo; Choi, Sang Mu; Son, Kwang Jae; Hong, Jintae

    2016-01-01

    Betavoltaic battery is a device that converts the decay energy of beta-emitting radioisotopes into electric energy. Ni-63 is pure betaemitter with a low energy spectrum and significantly long half-life of 100.1 years and thus is widely used as the power source of betavoltaic battery. There are several methods for the formation of a Ni deposit onto a semiconductor such as electroplating, electroless plating, and chemical vapor deposition. In this study, small-scale radioisotope electroplating system was designed and fabricated to perform electroplating with a small amount of plating buffer and minimum exposure of radioactive materials. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery. In this study, an electroplating system for small-scale Ni electroplating was designed and manufactured. The process for the fabrication of a Ni-63 foil as the energy source of a betavoltaic battery was developed using the minimum concentration of Ni. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery

  9. Development of small-scale electroplating system for Ni-63 electroplating onto Ni foil

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jin Joo; Choi, Sang Mu; Son, Kwang Jae; Hong, Jintae [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-10-15

    Betavoltaic battery is a device that converts the decay energy of beta-emitting radioisotopes into electric energy. Ni-63 is pure betaemitter with a low energy spectrum and significantly long half-life of 100.1 years and thus is widely used as the power source of betavoltaic battery. There are several methods for the formation of a Ni deposit onto a semiconductor such as electroplating, electroless plating, and chemical vapor deposition. In this study, small-scale radioisotope electroplating system was designed and fabricated to perform electroplating with a small amount of plating buffer and minimum exposure of radioactive materials. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery. In this study, an electroplating system for small-scale Ni electroplating was designed and manufactured. The process for the fabrication of a Ni-63 foil as the energy source of a betavoltaic battery was developed using the minimum concentration of Ni. These procedures and the manufactured electroplating device can be applied to radioactive Ni-63 electroplating for the fabrication of a betavoltaic battery.

  10. Exchange bias in finite sized NiO nanoparticles with Ni clusters

    International Nuclear Information System (INIS)

    Gandhi, Ashish Chhaganlal; Lin, Jauyn Grace

    2017-01-01

    Structural and magnetic properties of finite sized NiO nanoparticles are investigated with synchrotron X-ray diffraction (XRD), transmission electron microscopy, magnetometer and ferromagnetic resonance (FMR) spectroscopy. A minor Ni phase is detected with synchrotron XRD, attributed to the oxygen defects in the NiO core. A considerable exchange bias of ~100 Oe is observed at 50 K and it drops abruptly and vanishes above 150 K, in association with the reduction of frozen spins. FMR data indicate a strong interaction between ferromagnetic (FM) and antiferromagnetic (AFM) phases below 150 K, consistent with the picture of isolated FM clusters in AFM matrix. - Highlights: • Structural and magnetic properties of finite sized NiO nanoparticles are systematically investigated with several advanced techniques. • A strong interaction between ferromagnetic and antiferromagnetic phases is found below 150 K. • Exchange bias field in finite sized NiO nanoparticles is due to anisotropy energy of Ni clusters over riding the domain wall energy of NiO.

  11. Tipos especiales de niños

    Directory of Open Access Journals (Sweden)

    Mercedes Rodrigo Bellido

    1946-09-01

    Full Text Available En las tres últimas lecciones han sido expuestas algunas consideraciones referentes a niños y adolescentes desde el nacimiento hasta el dintel de la juventud. En todas ellas hemos procurado poner de relieve la necesidad de individualizar el conocimiento de cada niño para obtener mejores resultados en su adaptación a su futura vida de adultos, En todas ellas  nos hemos referido al llamado niño normal. Nos corresponde en la lección de hoy ocuparnos can la superficialidad característica de estas charlas tipo-muestrario, de otras categorías de niños muy dignos de interés.. quienes unas por exceso, otros por defecto, otros por dificultades de adaptación por diferentes causas, se desvían de la línea media de la normalidad. Consideramos que no está fuera del lugar, aquí, el tema de los niños excepcionales y por el contrario que es necesario intensificar el estudio de los trastornos de la vida mental y emocional de los niños en la preparación de los estudiantes de Medicina. Y no es nuestra solo esta opinión; no hace mucho tiempo en la Medical School de Ia Universidad de Minnessota hemos sabido que se ha hecho un intento de considerar y evaluar factores emocionales ambientales sobre las mismas bases que los descubrimientos fisiológicos.

  12. Ni Foam-Ni3 S2 @Ni(OH)2 -Graphene Sandwich Structure Electrode Materials: Facile Synthesis and High Supercapacitor Performance.

    Science.gov (United States)

    Wang, Xiaobing; Hu, Jiangjiang; Su, Yichang; Hao, Jin; Liu, Fanggang; Han, Shuang; An, Jian; Lian, Jianshe

    2017-03-23

    A novel Ni foam-Ni 3 S 2 @Ni(OH) 2 -graphene sandwich-structured electrode (NF-NN-G) with high areal mass loading (8.33 mg cm -2 ) has been developed by sulfidation and hydrolysis reactions. The conductivity of Ni 3 S 2 and Ni(OH) 2 were both improved. The upper layer of Ni(OH) 2 , covered with a thin graphene film, is formed in situ from the surface of the lower layer of Ni 3 S 2 , whereas the Ni 3 S 2 grown on Ni foam substrate mainly acts as a rough support bridging the Ni(OH) 2 and Ni foam. The graphene stabilized the Ni(OH) 2 and the electrochemical properties were effectively enhanced. The as-synthesized NF-NN-G-5mg electrode shows a high specific capacitance (2258 F g -1 at 1 A g -1 or 18.81 F cm -2 at 8.33 mA cm -2 ) and an outstanding rate property (1010 F g -1 at 20 Ag -1 or 8.413 F cm -2 at 166.6 mA cm -2 ). This result is around double the capacitance achieved in previous research on Ni 3 S 2 @Ni(OH) 2 /3DGN composites (3DGN=three-dimensional graphene network). In addition, the as-fabricated NF-NN-G-5mg composite electrode has an excellent cycle life with no capacitance loss after 3000 cycles, indicating a potential application as an efficient electrode. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. Salud mental del niño

    OpenAIRE

    Ospina de González, Bernarda

    1987-01-01

    Es ya reconocida por todos las importancia de los primeros años de vida en la estructutración de la personalidad y, por consiguiente, en la salud mental del niño. En este artículo se hace una síntesis de los diferentes aspectos del desarrollo de la personalidad infanltil que seben ser conocidos por el personal de salud para estar en condiciones de brindar una atención integral a la madre y al niño. Con igual propósito se señalan algunos patrones de tipo psicosocial que influyen en la estabili...

  14. Magnetic anisotropy of Ni/Cr multilayers

    International Nuclear Information System (INIS)

    Kang, S.; Xia, H.

    1997-01-01

    The magnetic anisotropy of Ni/Cr multilayers has been investigated by using vibrating sample magnetometer (VSM) and ferromagnetic resonance techniques (FMR). The FMR spectra are obtained as a function of the orientation of the applied magnetic field from in-plane to out-of-plane. The results are fitted theoretically to determine the magnetic anisotropy. From VSM and FMR, a positive value for Ni/Cr interface anisotropy is obtained, which favours a perpendicular easy axis. The possible mechanism for the perpendicular anisotropy has been discussed and it may be attributed to the magnetostriction, caused by intrinsic stress due to lattice mismatch. (orig.). With 005 figs., 001 tabs

  15. Ionizing Radiation Effects in Ni Nanotubes

    Science.gov (United States)

    Shlimas, D.; Kozlovsky, A.; Shumskaya, A.; Kaniukov, E.; Ibragimova, M.; Zdorovets, M.; Kadyrzhanov, K.

    2017-01-01

    Polycrystalline nickel nanotubes with diameter of 380 nm and wall thickness 95 nm were synthesized by electrochemical method using PET track-etched membranes with thickness of 12 μm. A comprehensive study of the structural, morphological and electrical characteristics of Ni nanotubes irradiated with C+13 ions with energy 1.75 MeV/nucleon and fluence ranging from 109 to 5 × 1011 cm-2 was carried out. The ability of modification of structural parameters such as lattice parameter and the average size of crystallites and conductivity of Ni nanotubes by irradiation was shown.

  16. Optimization of process parameters for synthesis of silica–Ni ...

    Indian Academy of Sciences (India)

    Optimization of process parameters for synthesis of silica–Ni nanocomposite by design of experiment ... Sol–gel; Ni; design of experiments; nanocomposites. ... Kolkata 700 032, India; Rustech Products Pvt. Ltd., Kolkata 700 045, India ...

  17. Ni hollow spheres as catalysts for methanol and ethanol electrooxidation

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Changwei [Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632 (China); School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Hu, Yonghong; Rong, Jianhua; Liu, Yingliang [Department of Chemistry and Institute of Nanochemistry, Jinan University, Guangzhou 510632 (China); Jiang, San Ping [School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798 (Singapore)

    2007-08-15

    In this paper, we successfully synthesized Ni hollow spheres consisting of needle-like nickel particles by using silica spheres as template with gold nanoparticles seeding method. The Ni hollow spheres are applied to methanol and ethanol electrooxidation in alkaline media. The results show that the Ni hollow spheres give a very high activity for alcohol electrooxidation at a very low nickel loading of 0.10 mg cm{sup -2}. The current on Ni hollow spheres is much higher than that on Ni particles. The onset potential and peak potential on Ni hollow spheres are more negative than that on Ni particles for methanol and ethanol electrooxidation. The Ni hollow spheres may be of great potential in alcohol sensor and direct alcohol fuel cells. (author)

  18. Separation and preparation of "6"2Ni isotope

    International Nuclear Information System (INIS)

    Ren Xiuyan; Mi Yajing; Zeng Ziqiang; Li Gongliang; Tu Rui

    2014-01-01

    Micro nuclear battery is the perfect power of space craft equipment. "6"3Ni is the core operation material of the "6"3Ni battery. It can produce radioisotope "6"3Ni while high abundance "6"2Ni is irradiated in the reactor. In order to meet the requirements of the abundance and the purity, research of the separation for "6"2Ni isotope was developed. The magnetic field and beam transmission status were simulated. The improvement designs of the ion source and the collector pocket were carried out. The process flow of high abundance "6"2Ni using electromagnetic separation method was established. The experiment of "6"2Ni isotope was developed by using electromagnetism isotope separator. The results show that the enrichment of "6"2Ni isotope is more than 90%. (authors)

  19. X-ray fluorescence analysis of Fe - Ni - Mo systems

    International Nuclear Information System (INIS)

    Belyaev, E.E.; Ershov, A.V.; Mashin, A.I.; Mashin, N.I.; Rudnevskij, N.K.

    1998-01-01

    Procedures for the X-ray fluorescence determination of the composition and thickness of Fe - Ni - Mo thin films and the concentration of elements in thick films of the Fe - Ni - Mo alloy are developed [ru

  20. Structure characterization of Ni/NiO and Ti/TiO2 interfaces

    International Nuclear Information System (INIS)

    Lamine, Brahim

    1983-01-01

    This research thesis reports the structure characterization of Ni-NiO and Ti-TiO 2 interfaces through an in-situ investigation of thin blade oxidation, of oxide germination and growth, and through a determination of mutual metal/oxide orientation relationships. Thin films of TiO 2 have also been characterized and the study of the influence of vacuum annealing on TiO 2 layer structure and morphology has been attempted. The examination of metal-oxide interface reveals a duplex structure of NiO and TiO 2 layers, and a preferential grain boundary oxidation of the underlying metal [fr

  1. Structure of Ni-rich Ni--Cr--B--Si coating alloys

    International Nuclear Information System (INIS)

    Knotek, O.; Lugscheider, E.; Reimann, H.

    1975-01-01

    The structures of quaternary, nickel-rich Ni--Cr--B--Si alloys were analyzed at a constant boron content of 10 at. percent and a temperature of 850 0 C. The composition range for silicide formation was determined. In these quaternary alloys, known binary nickel silicides, nickel and chromium borides, and the ternary silico-boride Ni 6 Si 2 B were confirmed. A new composition for the W 5 Si 3 -type phase in the Ni--B--Si system was proposed. (U.S.)

  2. The study of quasi-projectiles produced in Ni+Ni and Ni+Au collisions: excitation energy and spin

    International Nuclear Information System (INIS)

    Buta, A.

    2003-02-01

    During the collision between the projectile and the target nuclei in the intermediate energy regime (E < 100 MeV/nucleon) two excited nuclei are mainly observed in the exit channel, the quasi projectile (QP) and the quasi target. They disintegrate by particle emission. However, this binary picture is perturbed by the emission of particles and light fragments with velocities intermediate between the projectile velocity and the target one, all along the interaction (midrapidity component). This work aim to determine the excitation energy and the intrinsic angular momentum (or spin) of quasi-projectiles produced in the Ni+Ni and Ni+Au collisions at 52 and 90 MeV/nucleon. The excitation energy is deduced from the kinematical characteristics of particles emitted by the quasi-projectile. They have to be separated from midrapidity particles. Three different scenarios have been used for this purpose. The spin of the quasi-projectile has been extracted from the experimental data by mean of proton and alpha particles multiplicities emitted by the QP in the Ni+Au at 52 MeV/nucleon reaction. The results have been compared to the predictions of a theoretical model based on nucleon transfers. Their evolution is qualitatively reproduced as a function of the violence of the collision. (author)

  3. Low temperature gaseous nitriding of Ni based superalloys

    DEFF Research Database (Denmark)

    Eliasen, K. M.; Christiansen, Thomas Lundin; Somers, Marcel A. J.

    2010-01-01

    In the present work the nitriding response of selected Ni based superalloys at low temperatures is addressed. The alloys investigated are nimonic series nos. 80, 90, 95 and 100 and nichrome (Ni/Cr......In the present work the nitriding response of selected Ni based superalloys at low temperatures is addressed. The alloys investigated are nimonic series nos. 80, 90, 95 and 100 and nichrome (Ni/Cr...

  4. Giant magnetocaloric effect in isostructural MnNiGe-CoNiGe system by establishing a Curie-temperature window

    KAUST Repository

    Liu, E. K.; Zhang, H. G.; Xu, G. Z.; Zhang, X. M.; Ma, R. S.; Wang, W. H.; Chen, J. L.; Zhang, H. W.; Wu, G. H.; Feng, L.; Zhang, Xixiang

    2013-01-01

    An effective scheme of isostructural alloying was applied to establish a Curie-temperature window in isostructural MnNiGe-CoNiGe system. With the simultaneous accomplishment of decreasing structural-transition temperature and converting

  5. The large magnetoelectric effect in Ni-lead zirconium titanate-Ni trilayers derived by electroless deposition

    International Nuclear Information System (INIS)

    Bi, K; Wang, Y G; Wu, W; Pan, D A

    2010-01-01

    Magnetoelectric (ME) Ni-lead zirconium titanate-Ni trilayers with neither electrodes nor bonding layers have been derived by electroless deposition. The structure and magnetic properties of the electroless deposited Ni layers with different pH values are characterized by x-ray diffraction and vibrating sample magnetometer. The influence of the bias magnetic field and the magnetic field frequency (f) on ME coupling is discussed. It is seen that α E,31 depends strongly on H dc and f. The value of the ME coefficient increases as the thickness of the Ni layer and the pH of the bath increase. A maximum of the ME voltage coefficient α E,31 = 5.77 V cm -1 Oe -1 at resonance frequency with a deposited Ni layer thickness t Ni = 302 μm is obtained. The large ME coefficient makes these Ni-PZT-Ni trilayers suitable for applications in sensors, actuators and transducers. (fast track communication)

  6. Development of the dentistry alloy Ni-Cr-Nb; Desenvolvimento de ligas odontologicas Ni-Cr-Nb

    Energy Technology Data Exchange (ETDEWEB)

    Souza, M.A.; Ramos, A.S.; Hashimoto, T.M., E-mail: mari_sou@hotmail.co [UNESP/FEG, Guaratingueta, SP (Brazil). Fac. de Engenharia. Dept. de Materiais e Tecnologia

    2010-07-01

    This work reports on the structural characterization of Ni-Cr-Mo and Ni-Cr-Nb alloys produced by arc melting. Samples were characterized by means of optical microscopy, X-ray diffraction, scanning electron microscopy, and EDS analysis. Results indicated that the arc melting process was efficient to produce homogeneous structures in Ni-Cr-Mo and Ni-Cr-Nb alloys. The nickel dissolved large amounts of Cr, Mo and Nb, which was detected by EDS analysis and X-ray diffraction. The alloy containing molybdenum indicated the presence of structure based on Ni{sub SS}, while that the alloys containing niobium presented primary grains of Ni{sub SS} and precipitates formed by the simultaneous transformation of the Ni and Ni{sub 3}Nb phases. (author)

  7. Microstructure and electrochemical characterization of laser melt-deposited Ti2Ni3Si/NiTi intermetallic alloys

    International Nuclear Information System (INIS)

    Dong Lixin; Wang Huaming

    2008-01-01

    Corrosion and wear resistant Ti 2 Ni 3 Si/NiTi intermetallic alloys with Ti 2 Ni 3 Si as the reinforcing phase and the ductile NiTi as the toughening phase were designed and fabricated by the laser melt-deposition manufacturing process. Electrochemical behavior of the alloys was investigated using potentiodynamic polarization testing and electrochemical impedance spectroscopy in an NaOH solution. The results showed that the alloys have outstanding corrosion resistance due to the formation of a protective passive surface film of Ni(OH) 2 as well as the high chemical stability and strong inter-atomic bonds inherent to Ti 2 Ni 3 Si and NiTi intermetallics. The Ti 2 Ni 3 Si content has a significant influence on the microstructure of the alloys but only a slight effect on electrochemical corrosion properties

  8. Homotopic mapping solution of an oscillator for the El Niño/La Niña-southern oscillation

    International Nuclear Information System (INIS)

    Xian-Chun, Zhou; Yi-Hua, Lin; Wan-Tao, Lin; Jia-Qi, Mo

    2009-01-01

    This paper considers a class of oscillator for the El Niño/La Niña-southern oscillation (ENSO) model. By using the homotopic mapping method, it obtains approximations of the solution for the ENSO model. (general)

  9. Electrochemical reduction of NiO in a composite electrode

    DEFF Research Database (Denmark)

    Hu, Qiang; Jacobsen, Torben; Hansen, Karin Vels

    2013-01-01

    a lower overpotential. Microstructures of NiO with different reduction degrees are shown. Electrochemical impedance spectroscopy is carried out during the reduction process. Electrochemical reduction of NiO may need an induction period. When NiO is reduced at a constant voltage the current initially...

  10. Morphological and compositional engineering of Ni/carbon ...

    Indian Academy of Sciences (India)

    Ni/multi-walled carbon nanotubes (MWCNTs) composite films were deposited on the glassy carbon electrode (GCE) by a Ni plating bath containing homogeneously dispersed MWCNTs using polyvinylpyrrolidone (PVP) as dispersion additive. Incorporation of MWCNTs into Ni matrix was greatly enhanced by the application ...

  11. CLASSICAL AREAS OF PHENOMENOLOGY: First-principles calculations for the elastic properties of Ni-base model superalloys: Ni/Ni3Al multilayers

    Science.gov (United States)

    Wang, Yun-Jiang; Wang, Chong-Yu

    2009-10-01

    A model system consisting of Ni[001](100)/Ni3Al[001](100) multi-layers are studied using the density functional theory in order to explore the elastic properties of single crystal Ni-based superalloys. Simulation results are consistent with the experimental observation that rafted Ni-base superalloys virtually possess a cubic symmetry. The convergence of the elastic properties with respect to the thickness of the multilayers are tested by a series of multilayers from 2γ'+2γ to 10γ'+10γ atomic layers. The elastic properties are found to vary little with the increase of the multilayer's thickness. A Ni/Ni3Al multilayer with 10γ'+10γ atomic layers (3.54 nm) can be used to simulate the mechanical properties of Ni-base model superalloys. Our calculated elastic constants, bulk modulus, orientation-dependent shear modulus and Young's modulus, as well as the Zener anisotropy factor are all compatible with the measured results of Ni-base model superalloys R1 and the advanced commercial superalloys TMS-26, CMSX-4 at a low temperature. The mechanical properties as a function of the γ' phase volume fraction are calculated by varying the proportion of the γ and γ' phase in the multilayers. Besides, the mechanical properties of two-phase Ni/Ni3Al multilayer can be well predicted by the Voigt-Reuss-Hill rule of mixtures.

  12. Low-field spin dynamics of Cr7Ni and Cr7Ni-Cu -Cr 7Ni molecular rings as detected by μ SR

    Science.gov (United States)

    Sanna, S.; Arosio, P.; Bordonali, L.; Adelnia, F.; Mariani, M.; Garlatti, E.; Baines, C.; Amato, A.; Sabareesh, K. P. V.; Timco, G.; Winpenny, R. E. P.; Blundell, S. J.; Lascialfari, A.

    2017-11-01

    Muon spin rotation measurements were used to investigate the spin dynamics of heterometallic Cr7Ni and Cr7Ni -Cu-Cr7Ni molecular clusters. In Cr7Ni the magnetic ions are arranged in a quasiplanar ring and interact via an antiferromagnetic exchange coupling constant J , while Cr7Ni -Cu-Cr7Ni is composed of two Cr7Ni linked by a bridging moiety containing one Cu ion, that induces an inter-ring ferromagnetic interaction J'≪J . The longitudinal muon relaxation rate λ collected at low magnetic fields μ0H BPP)-like heuristic fitting model that takes into account of a distribution of electronic spin characteristic times for T >5 K, while the shoulder presented by Cr7Ni can be reproduced by a BPP function that incorporates a single electronic characteristic time theoretically predicted to dominate for T <5 K. The flattening of λ (T ) in Cr7Ni -Cu-Cr7Ni occurring at very low temperature can be tentatively attributed to field-dependent quantum effects and/or to an inelastic term in the spectral density of the electronic spin fluctuations.

  13. Microporous Ni@NiO nanoparticles prepared by chemically dealloying Al_3Ni_2@Al nanoparticles as a high microwave absorption material

    International Nuclear Information System (INIS)

    Pang, Yu; Xie, Xiubo; Li, Da; Chou, Wusheng; Liu, Tong

    2017-01-01

    The Al_3Ni_2@Al nanoparticles (NPs) were prepared from Ni_4_5Al_5_5 master alloy by hydrogen plasma-metal reaction method, and were subsequently dealloyed to produce porous Ni@NiO NPs of 36 nm. The pore size ranges from 0.7 to 1.6 nm, leading to large specific surface area of 69.5 m"2/g and big pore volume of 0.507 cc/g. The saturation magnetization (M_S) and coercivity (H_C) of the microporous Ni@NiO NPs are 11.5 emu/g and 5.2 Oe. They exhibit high microwave absorption performance with a minimum reflection coefficient (RC) of −86.9 dB and an absorption bandwidth of 2.6 GHz (RC≤−10 dB) at thickness of 4.5 mm. The enhanced microwave absorption properties are attributed to the synergistic effect of the magnetic Ni core and dielectric NiO shell, and the micropore architecture. The NPs with micropore morphology and core/shell structure open a new way to modify the microwave absorption performance. - Graphical abstract: The microporous Ni/NiO nanoparticles prepared by chemically dealloying Al_3Ni_2@Al NPs exhibit high microwave absorption intensity (−86.9 dB) and wide absorption bandwidth (2.6 GHz for RC≤−10 dB). - Highlights: • Microporous Ni/NiO nanoparticals were prepared by chemically dealloying method. • They possessed micropores of 0.7–1.6 nm with a surface area of 69.5 m"2/g. • They showed high microwave absorption intensity and wide absorption bandwidth. • Microwave absorption mechanism was explained by micropore and core/shell structures.

  14. Microporous Ni@NiO nanoparticles prepared by chemically dealloying Al{sub 3}Ni{sub 2}@Al nanoparticles as a high microwave absorption material

    Energy Technology Data Exchange (ETDEWEB)

    Pang, Yu; Xie, Xiubo; Li, Da [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing 100191 (China); Chou, Wusheng [School of Mechanical Engineering and Automation, Beihang University, Beijing 100191 (China); Liu, Tong, E-mail: tongliu@buaa.edu.cn [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing 100191 (China)

    2017-03-15

    The Al{sub 3}Ni{sub 2}@Al nanoparticles (NPs) were prepared from Ni{sub 45}Al{sub 55} master alloy by hydrogen plasma-metal reaction method, and were subsequently dealloyed to produce porous Ni@NiO NPs of 36 nm. The pore size ranges from 0.7 to 1.6 nm, leading to large specific surface area of 69.5 m{sup 2}/g and big pore volume of 0.507 cc/g. The saturation magnetization (M{sub S}) and coercivity (H{sub C}) of the microporous Ni@NiO NPs are 11.5 emu/g and 5.2 Oe. They exhibit high microwave absorption performance with a minimum reflection coefficient (RC) of −86.9 dB and an absorption bandwidth of 2.6 GHz (RC≤−10 dB) at thickness of 4.5 mm. The enhanced microwave absorption properties are attributed to the synergistic effect of the magnetic Ni core and dielectric NiO shell, and the micropore architecture. The NPs with micropore morphology and core/shell structure open a new way to modify the microwave absorption performance. - Graphical abstract: The microporous Ni/NiO nanoparticles prepared by chemically dealloying Al{sub 3}Ni{sub 2}@Al NPs exhibit high microwave absorption intensity (−86.9 dB) and wide absorption bandwidth (2.6 GHz for RC≤−10 dB). - Highlights: • Microporous Ni/NiO nanoparticals were prepared by chemically dealloying method. • They possessed micropores of 0.7–1.6 nm with a surface area of 69.5 m{sup 2}/g. • They showed high microwave absorption intensity and wide absorption bandwidth. • Microwave absorption mechanism was explained by micropore and core/shell structures.

  15. Tracer diffusion of 60Co and 63Ni in amorphous NiZr alloy

    International Nuclear Information System (INIS)

    Hoshino, K.; Averback, R.S.; Hahn, H.; Rothman, S.J.

    1987-01-01

    Tracer diffusion of 60 Co and 63 Ni in equiatomic amorphous NiZr alloy in the temperature range between 486 and 641 0 K can be described by: D/sub Co/sup */ = 3.7 x 10 -7 exp[-(135 +- 14) kJ mole -1 /RT] m 2 /sec and D/sub Ni//sup */ = 1.7 x 10 -7 exp[-(140 +- 9) kJ mole -1 /RT] m 2 /sec. The values of D/sub Ni//sup */ are in reasonable agreement with those measured by the Rutherford backscattering technique. The measured diffusivities were independent of time, indicating that no relaxation took place during diffusion. 27 refs., 2 tabs

  16. Precipitation-induced of partial annealing of Ni-rich NiTi shape memory alloy

    Science.gov (United States)

    Nashrudin, Muhammad Naqib; Mahmud, Abdus Samad; Mohamad, Hishamiakim

    2018-05-01

    NiTi shape memory alloy behavior is very sensitive to alloy composition and heat treatment processes. Thermomechanical behavior of near-equiatomic alloy is normally enhanced by partial anneal of a cold-worked specimen. The shape memory behavior of Ni-rich alloy can be enhanced by ageing precipitation. This work studied the effect of simultaneous partial annealing and ageing precipitation of a Ni-rich cold drawn Ti-50.9at%Ni wire towards martensite phase transformation behavior. Ageing treatment of a non-cold worked specimen was also done for comparison. It was found that the increase of heat treatment temperature caused the forward transformation stress to decrease for the cold worked and non-cold worked specimens. Strain recovery on the reverse transformation of the cold worked wire improved compared to the non-cold worked wire as the temperature increased.

  17. Corrosion behaviour of electrodeposited nanocrystalline Ni-W and Ni-Fe-W alloys

    International Nuclear Information System (INIS)

    Sriraman, K.R.; Ganesh Sundara Raman, S.; Seshadri, S.K.

    2007-01-01

    The present work deals with evaluation of corrosion behaviour of electrodeposited nanocrystalline Ni-W and Ni-Fe-W alloys. Corrosion behaviour of the coatings deposited on steel substrates was studied using polarization and electrochemical impedance spectroscopy techniques in 3.5% NaCl solution while their passivation behaviour was studied in 1N sulphuric acid solution. The corrosion resistance of Ni-W alloys increased with tungsten content up to 7.54 at.% and then decreased. In case of Ni-Fe-W alloys it increased with tungsten content up to 9.20 at.% and then decreased. The ternary alloy coatings exhibited poor corrosion resistance compared to binary alloy coatings due to preferential dissolution of iron from the matrix. Regardless of composition all the alloys exhibited passivation behaviour over a wide range of potentials due to the formation of tungsten rich film on the surface

  18. Evolution of collectivity in the 78Ni region: Coulomb excitation of 74Ni at intermediate energies.

    Directory of Open Access Journals (Sweden)

    Marchi T.

    2014-03-01

    Full Text Available The study of the collective properties of nuclear excitations far from stability provides information about the shell structure at extreme conditions. Spectroscopic observables such as the energy or the transition probabilities of the lowest states, in nuclei with large neutron excess, allow to probe the density and isospin dependence of the effective interaction. Indeed, it was recently shown that tensor and three-body forces play an important role in breaking and creating magic numbers. Emblematic is the case of the evolution of the Ni isotopic chain where several features showed up moving from the most neutron rich stable isotope (64Ni towards the 78Ni nucleus where the large neutron excess coincides with a double shell closure. In this framework, we have recently performed an experiment with the goal to extract the B(E2; 0+ → 2+ value for the 74Ni nucleus in an intermediate-energy Coulomb excitation experiment: preliminary results are discussed.

  19. Rate of hydrogen motion in Ni-substituted LaNi5Hx from NMR

    International Nuclear Information System (INIS)

    Mendenhall, Michael P.; Bowman, Robert C.; Ivancic, Timothy M.; Conradi, Mark S.

    2007-01-01

    Partial substitution of Sn, Ge, or Si for Ni in LaNi 5 H x greatly enhances the stability under repeated hydrogen-cycling. Proton NMR relaxation measurements are reported here to determine the rates of H hopping in the substituted metals LaNi 4.6 M 0.4 H x with M = Sn, Ge, and Si, for comparison to bare LaNi 5 H x . The relaxation times T 2 * (FID), T 2 (Hahn echo), T 2 -CPMG, T 1 , and T 1ρ were determined from 130 to 375 K. The three substituents result in only small increases in the average rate of motion at a given temperature but with a broader distribution of rates over the many inequivalent H sites and hopping paths. Evidently, the average energy barriers along the paths for H motion are only little affected by these substituents. Changes of H content x produce only minor changes in the relaxation times

  20. Moessbauer effect measurements on the intermetallic compounds Ni3Al and Ni3Ge

    International Nuclear Information System (INIS)

    Drijver, J.W.; Woude, F. van der

    1975-01-01

    Moessbauer parameters obtained from room temperature emission and absorption spectra of Ni 3 Al and Ni 3 Ga processed by a computer assuming a singlet and a doublet are given. The doublet is due to iron or cobalt atoms at the nickel site. Quadrupole splitting at 57 Fe nuclei in Ni 3 Ga is larger than in Ni 3 Al, viz. 0.52 and 0.37 mm/sec, respectively. Isomer shift at the Al/Ga position is very close to -0.02 mm/sec found in metallic nickel. Also given are the hyperfine magnetic fields at 4.2 K. Considering the preference of 57 Co and 57 Fe atoms in the lattice, the field intensities at the nickel and aluminium sites are found to be 227 +- 1 and 238 +- 1 kOe, respectively. (Z.S.)

  1. Low energy structure of even-even Ni isotopes close to 78Ni

    International Nuclear Information System (INIS)

    Rykaczewski, Krzysztof Piotr; Mazzocchi, C.; Grzywacz, Robert Kazimierz; Batchelder, J.C.; Bingham, Carrol R.; Fong, D.; Hamilton, J.H.; Hwang, J.K.; Karny, M.; Krolas, W.; Liddick, S.N.; Lisetskiy, A. F.; Morton, N.H.; Mantica, P.F.; Mueller, W.F.; Steiner, M.; Stolz, A.; Winger, J.A.

    2005-01-01

    The structure of magic neutron-rich nickel isotopes produced in the fragmentation of a 140 A MeV 86 Kr beam was investigated. For the first time four gamma transitions were assigned to the decay of the I π =8 + , T 1/2 = 590 +180 -110 isomer, thus establishing the 0 + -2 + -4 + -6 + -8 + ground-state band in 76 Ni. The previously unknown 2 + and 4 + levels belonging to the ground-state band in 74 Ni were identified in the β decay of 74 Co (T 1/2 =30(3) ms). The decay properties of 72 Co → 72 Ni were verified and confirmed on the basis of γ-γ coincidence data. The relevance of the measured level properties for the magicity of 78 Ni is analyzed with the help of advanced shell-model predictions

  2. The process of Ni-63 production and measurement of beta radiation of irradiated Ni-63

    International Nuclear Information System (INIS)

    Kim, Jin Joo; Uhma, Young Rang; Kim, Jong Bum; Choi, Sang Mu; Son, Kwang Jae; Hong, Jin Tae; Park, Jong Han

    2016-01-01

    It has the following characteristics: long service lifetime, high energy density, easy small-scale fabrication, and minimum maintenance. For this reasons, betavoltaic batteries are widely used in many low-power applications such as medical applications and power sources for micro electro-mechanical system (MEMS) because they can operate effectively at extreme environments. Proper selection of radioisotope is a critical factor in the design of a betavoltaic battery. The important factors affecting the performance of a betavoltaic battery are specific activity, half-life, and toxicity. In this study, a target for irradiation was produced using 99% Ni-62 metal power concentrate. Ni-62 target of 1 g was irradiated in MARIA reactor operated in Poland for 470 hours, and estimated production of Ni- 63 was calculated. Irradiated Ni-63 pellets were dissolved in HCl solution, and its beta radiation was measured by Liquid Scintillation Counter (LSC).

  3. Synthetic Ni3S2/Ni hybrid architectures as potential contrast agents in MRI

    International Nuclear Information System (INIS)

    Ma, J; Chen, K

    2016-01-01

    Traditional magnetic resonance imaging (MRI) contrast agents mainly include superparamagnetic (SPM) iron oxide nanoparticle as T 2 contrast agent for liver and paramagnetic Gd (III)-chelate as T 1 contrast agent for all organs. In this work, weak ferromagnetic kale-like and SPM cabbage-like Ni 3 S 2 @Ni hybrid architectures were synthesized and evaluated as potential T 1 MRI contrast agents. Their relatively small r 2 /r 1 ratios of 2.59 and 2.38, and high r 1 values of 11.27 and 4.89 mmol −1 L s −1 (for the kale-like and cabbage-like Ni 3 S 2 @Ni, respectively) will shed some light on the development of new-type MRI contrast agents. (paper)

  4. Hierarchical NiCo2 O4 nanosheets grown on Ni nanofoam as high-performance electrodes for supercapacitors.

    Science.gov (United States)

    Gao, Guoxin; Wu, Hao Bin; Ding, Shujiang; Liu, Li-Min; Lou, Xiong Wen David

    2015-02-18

    A high-performance electrode for supercapacitors is designed and synthesized by growing electroactive NiCo2 O4 nanosheets on conductive Ni nanofoam. Because of the structural advantages, the as-prepared Ni@NiCo2 O4 hybrid nanostructure exhibits significantly improved electrochemical performance with high capacitance, excellent rate capability, and good cycling stability. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Ni(II) complexes of dithiophosphonic acids

    Indian Academy of Sciences (India)

    aDepartment of Chemistry, Science and Research Branch, Islamic Azad ... The compounds were characterized by 1H, 13C and 31P NMR, IR spectroscopy and elemental analysis. The ... design and synthesize Ni(II) complexes with new ..... Yield: 86%. ..... 28 65. 18. Greenwood D 1989 Antimicrobial chemotherapy (New.

  6. Ni MINERALIZATION AND PGE CHARACTERIZATION IN THE ...

    African Journals Online (AJOL)

    Mgina

    fractionation, (2) the IPGEs are often associated with chromites as alloys or sulfides in ... Key words: Tanzania, Kabanga, Luhuma, PGE, Ni-Cu sulfides .... massive sulfide based on size of ore zone ... to ≤ 0.1 wt% and Fe2O3T = 80- ≈ 87 wt%.

  7. Modelling of rechargeable NiMH batteries

    NARCIS (Netherlands)

    Ledovskikh, A.; Verbitskiy, E.; Ayeb, A.; Notten, P.H.L.

    2003-01-01

    A new mathematical model has been developed for rechargeable NiMH batteries, which is based on the occurring physical–chemical processes inside. This model enables one to simultaneously simulate the battery voltage, internal gas pressures (both PO2 and PH2) and temperature during battery operation.

  8. Characterisation of a Zn / Ni Plating Bath

    Science.gov (United States)

    2009-09-03

    accelerated corrosion in the first stages which is then slowed down by its own product of corrosion, Zn(OH)212. Zinc hydroxide dehydrates in time to form ZnO ... Electrochemistry , 1991, 21, 642 [5] – Alfantasi, A.M., A study on the synthesis, characterization ans properties of pulse-plated ultrafine- grained Zn-Ni alloy

  9. Evidence for an isomer in 76Ni

    International Nuclear Information System (INIS)

    Sawicka, M.; Pfuetzner, M.; Grzywacz, R.; Daugas, J.M.; Belier, G.; Sauvestre, J.E.; Matea, I.; Lewitowicz, M.; Georgiev, G.; Grawe, H.; Mayet, P.; Becker, F.; Bingham, C.; Borcea, R.; Hammache, F.; Ibrahim, F.; Bouchez, E.; Buta, A.; Dragulescu, E.; Giovinazzo, J.; Meot, V.; Negoita, F.; De Oliveira Santos, F.; Perru, O.; Roig, O.; Rykaczewski, K.P.; Saint-Laurent, M.G.; Sorlin, O.; Stanoiu, M.; Stefan, I.; Stodel, C.; Theisen, C.; Verney, D.

    2004-01-01

    In the experiment performed at the LISE2000 spectrometer at GANIL neutron-rich nickel isotopes were studied by microsecond isomer spectroscopy. Evidence for an isomer in 76 Ni is found, consistently with the shell model prediction of an 8 + state of ν(g 9/2 ) 2 structure. (orig.)

  10. Electroplating condition for Ni nanocrystalline on metal (Ni and Cu) plates

    Energy Technology Data Exchange (ETDEWEB)

    Park, Keun Yung; Uhm, Young Rang; Son, Kwang Jae; Shim, Young Ho; Choi, Sun Ju [KAERI, Daejeon (Korea, Republic of)

    2012-10-15

    Ni 63, a beta radiation source, is prepared by the electrical deposition of radioactive Ni 63 ions on a thin non radioactive nickel foil or Cu plate. Given a half life of 100 years, a nuclear battery will still produce half of its initial starting power after 100 years. A speck of a radioisotope like nickel 63, for example, contains enough energy to power a nano nuclear battery for decades, and to do so safely. Ni 63 plating is similar to other electroplating processes that employ soluble metal anodes. It requires the passage of a direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. The charged Ni ions are formed by sulfate, sulfamate, chloride, and a Watts bath. However, the charged Ni 63 ions are formed by dissolving metal Ni 63. To established the coating condition of Ni 63, non radioactive metal Ni particles are dissolved an acid solution and electroplated on a Ni sheet. The nickel plating process is used extensively for decorative, engineering and electro forming purposes because the appearance and other properties of electrodeposited nickel can be varied over a wide range by controlling the composition and operating parameters of the plating solution. A continuous increase in the grain size versus current density has also been recognized in the direct current electrodeposition of nickel coating. On the other hand, A runa et al. reported that the current density has no significant effect on the grain size of nickel electro deposits. A review of the literature shows that saccharin has often been added to a nickel plating bath since the 1980s to improve the ductility and brightness, and in later periods as a grain refiner agent. In the present paper, not only the preparation of a Ni plating solution prepared by dissolving metal particles, but also an optimization of the deposition conditions, such as the current density, saccharin concentration in the bath, and different metal substrates were investigated

  11. Electroplating condition for Ni nanocrystalline on metal (Ni and Cu) plates

    International Nuclear Information System (INIS)

    Park, Keun Yung; Uhm, Young Rang; Son, Kwang Jae; Shim, Young Ho; Choi, Sun Ju

    2012-01-01

    Ni 63, a beta radiation source, is prepared by the electrical deposition of radioactive Ni 63 ions on a thin non radioactive nickel foil or Cu plate. Given a half life of 100 years, a nuclear battery will still produce half of its initial starting power after 100 years. A speck of a radioisotope like nickel 63, for example, contains enough energy to power a nano nuclear battery for decades, and to do so safely. Ni 63 plating is similar to other electroplating processes that employ soluble metal anodes. It requires the passage of a direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. The charged Ni ions are formed by sulfate, sulfamate, chloride, and a Watts bath. However, the charged Ni 63 ions are formed by dissolving metal Ni 63. To established the coating condition of Ni 63, non radioactive metal Ni particles are dissolved an acid solution and electroplated on a Ni sheet. The nickel plating process is used extensively for decorative, engineering and electro forming purposes because the appearance and other properties of electrodeposited nickel can be varied over a wide range by controlling the composition and operating parameters of the plating solution. A continuous increase in the grain size versus current density has also been recognized in the direct current electrodeposition of nickel coating. On the other hand, A runa et al. reported that the current density has no significant effect on the grain size of nickel electro deposits. A review of the literature shows that saccharin has often been added to a nickel plating bath since the 1980s to improve the ductility and brightness, and in later periods as a grain refiner agent. In the present paper, not only the preparation of a Ni plating solution prepared by dissolving metal particles, but also an optimization of the deposition conditions, such as the current density, saccharin concentration in the bath, and different metal substrates were investigated

  12. Synthesis of microporous Ni/NiO nanoparticles with enhanced microwave absorption properties

    International Nuclear Information System (INIS)

    Liu, Tong; Pang, Yu; Xie, Xiubo; Qi, Wen; Wu, Ying; Kobayashi, Satoru; Zheng, Jie; Li, Xingguo

    2016-01-01

    The fabrication of microporous metal materials with many potential applications is challenging due to their high chemical activities and the difficulty in controlling the pore size. By adjusting the reaction condition and the composition of the Ni–Al nanoparticle precursor, we have successfully produced the microporous Ni nanoparticles (NPs) of 22 nm by chemical dealloying method. During the passivation process, the microporous Ni NPs covered with NiO shell are generated as the result of surface oxidation. The micropores range from 0.6 to 1.2 nm in diameter with a large surface area of 68.9 m"2/g. Due to the elimination of Al atoms during dealloying process, the crystalline size of the microporous Ni NPs is sharply decreased to 2–5 nm. The specific architecture offers the microporous Ni/NiO NPs a small microwave reflection coefficient (RC) and a wide absorption bandwidth (RC ≤ −10 dB) of −49.1 dB and 5.8 GHz, much better than the nonporous counterpart of −24.1 dB and 3.7 GHz. The enhanced microwave absorption performance has been interpreted in terms of the micropore structure, core/shell structure and nanostructure effects. - Highlights: • Microporous Ni/NiO nanoparticles are prepared by chemical dealloying method. • They possess micropores of 0.6–1.2 nm with a surface area of 68.9 m"2/g. • They show minimum microwave reflection coefficient of −49.1 dB and bandwidth of 5.8 GHz. • Microwave absorption mechanism is explained by micropore and core/shell structures.

  13. Synthesis of microporous Ni/NiO nanoparticles with enhanced microwave absorption properties

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Tong, E-mail: tongliu@buaa.edu.cn [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing, 100191 (China); Pang, Yu; Xie, Xiubo [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beihang University, No.37 Xueyuan Road, Beijing, 100191 (China); Qi, Wen; Wu, Ying [China Iron & Steel Research Institute Group, Advanced Technology & Materials Co., Ltd, No.76 Xueyuannanlu, Haidian District, Beijing, 100081 (China); Kobayashi, Satoru [Faculty of Engineering, Iwate University, Ueda, Morioka, 020-8551 (Japan); Zheng, Jie; Li, Xingguo [Beijing National Laboratory for Molecular Sciences (BNLMS), The State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871 (China)

    2016-05-15

    The fabrication of microporous metal materials with many potential applications is challenging due to their high chemical activities and the difficulty in controlling the pore size. By adjusting the reaction condition and the composition of the Ni–Al nanoparticle precursor, we have successfully produced the microporous Ni nanoparticles (NPs) of 22 nm by chemical dealloying method. During the passivation process, the microporous Ni NPs covered with NiO shell are generated as the result of surface oxidation. The micropores range from 0.6 to 1.2 nm in diameter with a large surface area of 68.9 m{sup 2}/g. Due to the elimination of Al atoms during dealloying process, the crystalline size of the microporous Ni NPs is sharply decreased to 2–5 nm. The specific architecture offers the microporous Ni/NiO NPs a small microwave reflection coefficient (RC) and a wide absorption bandwidth (RC ≤ −10 dB) of −49.1 dB and 5.8 GHz, much better than the nonporous counterpart of −24.1 dB and 3.7 GHz. The enhanced microwave absorption performance has been interpreted in terms of the micropore structure, core/shell structure and nanostructure effects. - Highlights: • Microporous Ni/NiO nanoparticles are prepared by chemical dealloying method. • They possess micropores of 0.6–1.2 nm with a surface area of 68.9 m{sup 2}/g. • They show minimum microwave reflection coefficient of −49.1 dB and bandwidth of 5.8 GHz. • Microwave absorption mechanism is explained by micropore and core/shell structures.

  14. Geometric structures of thin film: Pt on Pd(110) and NiO on Ni(100)

    Energy Technology Data Exchange (ETDEWEB)

    Warren, Oden L. [Iowa State Univ., Ames, IA (United States)

    1993-07-01

    This thesis is divided into 3 papers: dynamical low-energy electron- diffraction investigation of lateral displacements in topmost layer of Pd(110); determination of (1x1) and (1x2) structures of Pt thin films on Pd(110) by dynamical low-energy electron-diffraction analysis; and structural determination of a NiO(111) film on Ni(100) by dynamical low-energy electron-diffraction analysis.

  15. Fabrication and tensile properties of rapidly solidified Cu-10wt. %Ni alloy. [Cu-10Ni

    Energy Technology Data Exchange (ETDEWEB)

    Baril, D; Angers, R; Baril, J [Dept. of Mining and Metallurgy, Laval Univ., Ste-Foy, Quebec (Canada)

    1992-10-15

    Cu-10wt.%Ni ribbons were produced by melt spinning and cut into small particles with a blade cutter mill. The powders were then hot consolidated to full density by hot pressing followed by hot extrusion. Tensile properties of the resulting pieces were measured. Cu-10wt.%Ni cast ingots were also hot extruded and mechanically tested to compare with the rapidly solidified alloy and to evaluate the possible benefits brought by the rapid solidification process.

  16. 59Ni and 63Ni separation from boric acid concentrates produced at NPP

    International Nuclear Information System (INIS)

    Fisera, O.

    2010-01-01

    Procedure for direct separation of radionickel from boric acid concentrate was developed. Quantitative separation from 100 mL of real concentrate on the column filled with 3 mL of PAN-DMG composite material was achieved. PAN-DMG material (dimethylglyoxime in porous beads of polyacrylonitrile) was compared with Ni Resin and DMG-PAN material exhibited higher sorption capacity for nickel than Ni Resin. (author)

  17. Valence electronic structure of Ni in Ni Si alloys from relative K X-ray intensity studies

    Science.gov (United States)

    Kalayci, Y.; Aydinuraz, A.; Tugluoglu, B.; Mutlu, R. H.

    2007-02-01

    The Kβ-to-Kα X-ray intensity ratio of Ni in Ni 3Si, Ni 2Si and NiSi has been determined by energy dispersive X-ray fluorescence technique. It is found that the intensity ratio of Ni decreases from pure Ni to Ni 2Si and then increases from Ni 2Si to NiSi, in good agreement with the electronic structure calculations cited in the literature. We have also performed band structure calculations for pure Ni in various atomic configurations by means of linear muffin-tin orbital method and used this data with the normalized theoretical intensity ratios cited in the literature to estimate the 3d-occupation numbers of Ni in Ni-Si alloys. It is emphasized that investigation of alloying effect in terms of X-ray intensity ratios should be carried out for the stoichiometric alloys in order to make reliable and quantitative comparisons between theory and experiment in transition metal alloys.

  18. La Niña, El Niño, and Atlantic Hurricane Damages in the United States

    Science.gov (United States)

    data discussed below), this definition results in 22 El Niño years, 29 neutral years, and 22 La Niña accounting for the most significant societal changes. To normalize past impacts data to 1997 values, losses , 169 and 186. Trenberth, K. E., 1997: The definition of El Niño. Bull. Amer. Meteor. Soc., 78, 2771

  19. Observations of defect structure evolution in proton and Ni ion irradiated Ni-Cr binary alloys

    Energy Technology Data Exchange (ETDEWEB)

    Briggs, Samuel A., E-mail: sabriggs2@wisc.edu [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); Barr, Christopher M. [Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104 (United States); Pakarinen, Janne [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); SKC-CEN Belgian Nuclear Research Centre, Boeretang 200, B-2400 Mol (Belgium); Mamivand, Mahmood [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); Hattar, Khalid [Sandia National Laboratories, PO Box 5800, Albuquerque, NM 87185 (United States); Morgan, Dane D. [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States); Taheri, Mitra [Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104 (United States); Sridharan, Kumar [University of Wisconsin-Madison, 1415 Engineering Drive, Madison, WI 53706 (United States)

    2016-10-15

    Two binary Ni-Cr model alloys with 5 wt% Cr and 18 wt% Cr were irradiated using 2 MeV protons at 400 and 500 °C and 20 MeV Ni{sup 4+} ions at 500 °C to investigate microstructural evolution as a function of composition, irradiation temperature, and irradiating ion species. Transmission electron microscopy (TEM) was applied to study irradiation-induced void and faulted Frank loops microstructures. Irradiations at 500 °C were shown to generate decreased densities of larger defects, likely due to increased barriers to defect nucleation as compared to 400 °C irradiations. Heavy ion irradiation resulted in a larger density of smaller voids when compared to proton irradiations, indicating in-cascade clustering of point defects. Cluster dynamics simulations were in good agreement with the experimental findings, suggesting that increases in Cr content lead to an increase in interstitial binding energy, leading to higher densities of smaller dislocation loops in the Ni-18Cr alloy as compared to the Ni-5Cr alloy. - Highlights: • Binary Ni-Cr alloys were irradiated with protons or Ni ions at 400 and 500 °C. • Higher irradiation temperatures yield increased size, decreased density of defects. • Hypothesize that varying Cr content affects interstitial binding energy. • Fitting CD models for loop nucleation to data supports this hypothesis.

  20. Study of the magnetic anisotropy in Ni/Cu and Ni/glass thin films

    Energy Technology Data Exchange (ETDEWEB)

    Cherif, S.-M. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse, 93340 (France); Layadi, A. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria)]. E-mail: a_layadi@yahoo.fr; Ben Youssef, J. [Laboratoire de Magnetisme de Bretagne, U.B.O., Brest 29238 (France); Nacereddine, C. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria); Roussigne, Y. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse, 93340 (France)

    2007-01-01

    The magnetic properties of evaporated Ni/Cu and Ni/glass thin films have been investigated by means of the vibrating sample magnetometer (VSM), the Brillouin light scattering (BLS) and magnetic force microscopy (MFM). The Ni thickness, t, ranges from 31 to 165 nm. The second- and fourth-order magnetic anisotropy constants, K {sub 1} and K {sub 2}, have been included; for the Ni/Cu series, K {sub 1} was found to decrease from 1.0x10{sup 6} to 0.18x10{sup 6} erg/cm{sup 3} as t increases from 31 to 165 nm, while K {sub 2} increased from 0.24x10{sup 6} to 0.8x10{sup 6} erg/cm{sup 3}. Over all the thickness range, the magnetization easy axis is in plane. For thinner films, there is a good agreement between anisotropy constant values inferred from VSM and BLS. Stripe domains were observed for t{>=}165 nm in Ni/glass and t{>=}90 nm in Ni/Cu.

  1. Study of the magnetic anisotropy in Ni/Cu and Ni/glass thin films

    International Nuclear Information System (INIS)

    Cherif, S.-M.; Layadi, A.; Ben Youssef, J.; Nacereddine, C.; Roussigne, Y.

    2007-01-01

    The magnetic properties of evaporated Ni/Cu and Ni/glass thin films have been investigated by means of the vibrating sample magnetometer (VSM), the Brillouin light scattering (BLS) and magnetic force microscopy (MFM). The Ni thickness, t, ranges from 31 to 165 nm. The second- and fourth-order magnetic anisotropy constants, K 1 and K 2 , have been included; for the Ni/Cu series, K 1 was found to decrease from 1.0x10 6 to 0.18x10 6 erg/cm 3 as t increases from 31 to 165 nm, while K 2 increased from 0.24x10 6 to 0.8x10 6 erg/cm 3 . Over all the thickness range, the magnetization easy axis is in plane. For thinner films, there is a good agreement between anisotropy constant values inferred from VSM and BLS. Stripe domains were observed for t≥165 nm in Ni/glass and t≥90 nm in Ni/Cu

  2. Effect of Ni4Ti3 precipitation on martensitic transformation in Ti-Ni

    International Nuclear Information System (INIS)

    Zhou, N.; Shen, C.; Wagner, M.F.-X.; Eggeler, G.; Mills, M.J.; Wang, Y.

    2010-01-01

    Precipitation of Ni 4 Ti 3 plays a critical role in determining the martensitic transformation path and temperature in Ni-Ti shape memory alloys. In this study, the equilibrium shape of a coherent Ni 4 Ti 3 precipitate and the concentration and stress fields around it are determined quantitatively using the phase field method. Most recent experimental data on lattice parameters, elastic constants, precipitate-matrix orientation relationship and thermodynamic database are used as model inputs. The effects of the concentration and stress fields on subsequent martensitic transformations are analyzed through interaction energy between a nucleating martensitic particle and the existing microstructure. Results indicate that R-phase formation prior to B19' phase could be attributed to both direct elastic interaction and stress-induced spatial variation in concentration near Ni 4 Ti 3 precipitates. The preferred nucleation sites for the R-phase are close to the broad side of the lenticular-shaped Ni 4 Ti 3 precipitates, where tension normal to the habit plane is highest, and Ni concentration is lowest.

  3. Fabrication of metallic alloy powder (Ni{sub 3}Fe) from Fe–77Ni scrap

    Energy Technology Data Exchange (ETDEWEB)

    Seo, Inseok [ES Materials Research Center, Research Institute of Industrial Science and Technology, Incheon 406-840 (Korea, Republic of); Shin, Shun-Myung [Extractive Metallurgy Department, Korea Institute of Geoscience and Mineral Resources, Deajeon 305-350 (Korea, Republic of); Ha, Sang-An [Department of Environmental Engineering, Silla University, Busan 46958 (Korea, Republic of); Wang, Jei-Pil, E-mail: jpwang@pknu.ac.kr [Department of Metallurgical Engineering, Pukyong National University, Busan 608-739 (Korea, Republic of)

    2016-06-15

    The oxidation behavior of Fe–77Ni alloy scrap was investigated at an oxygen partial pressure of 0.2 atm and temperatures ranging from 400 °C to 900 °C. The corresponding oxidation rate increased with increasing temperature and obeyed the parabolic rate law, as evidenced by its linear proportionality to the temperature. In addition, surface morphologies, cross-sectional views, compositions, structural properties were examined by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). Diffusion through either the spinel structure or the NiO layer, which were both present in the alloy during oxidation at elevated temperatures, was deemed the rate-limiting step of the reaction. The oxide powder less than 10 μm was obtained from Fe–77Ni alloy scrap was obtained using ball-milling and sieving processes. In fact, 15 h of milling yielded a recovery ratio of 97%. Using hydrogen gas, the oxide powder was successfully reduced to an alloy powder of Ni{sub 3}Fe and reduction rates of ∼97% were achieved after 3 h at 1000 °C. - Highlights: • The oxidation behavior of Fe–77Ni alloy scrap was investigated. • The oxide powder less than 10 μm was obtained from Fe–77Ni alloy scrap. • Using hydrogen gas, the oxide powder was successfully reclaimed. • Reduction rates of ∼97% were achieved after 3 h at 1000 °C.

  4. Positron annihilation studies in CeNiIn and LaNiIn

    International Nuclear Information System (INIS)

    Ray, R.; Giri, S.; Sen, M.; Nambissan, P.M.G.; Ghoshray, K.; Ghoshray, A.; Sen, P.

    1997-01-01

    Doppler broadened positron annihilation spectral lineshape (DBPAS) and positron lifetime measurements in the temperature range 18-280 K have been performed in CeNiIn and LaNiIn systems. The nature of the temperature variations of the lifetime in both systems is almost similar in the whole temperature range studied, whereas the nature of the temperature variation of the S parameter in CeNiIn is similar to that in LaNiIn except in the temperature region 18-40 K. For the former system there is a dip around 20 K in the S parameter versus temperature curve. The lifetime versus T curve in both systems could be explained by the thermal expansion of the lattice. The S parameter versus T curve in LaNiIn could also be attributed to the thermal expansion of the lattice, whereas in CeNiIn the above mentioned dip seems an extra feature of the thermal expansion of the lattice. To understand this low temperature behaviour other results on the same system have been discussed. (orig.)

  5. Interfacial reaction of Ni{sub 3}Sn{sub 4} intermetallic compound in Ni/SnAg solder/Ni system under thermomigration

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Yi-Shan; Yang, Chia-Jung; Ouyang, Fan-Yi, E-mail: fyouyang@ess.nthu.edu.tw

    2016-07-25

    The growth of Ni{sub 3}Sn{sub 4} intermetallic compound (IMC) between liquid–solid interface in micro-scale Ni/SnAg/Ni system was investigated under a temperature gradient of 160 °C/cm at 260 °C on a hot plate. In contrast to a symmetrical growth of Ni{sub 3}Sn{sub 4} on both interfaces under isothermally annealed at 260 °C, the interfacial Ni{sub 3}Sn{sub 4} IMC exhibited asymmetric growth under a temperature gradient; the growth of Ni{sub 3}Sn{sub 4} at cold interface was faster than that at hot side because of temperature gradient induced mass migration of Ni atoms from the hot end toward the cold end. It was found that two-stage growth behavior of Ni{sub 3}Sn{sub 4} IMC under a temperature gradient. A growth model was established and growth kinetic analysis suggested that the chemical potential gradient controlled the growth of Ni{sub 3}Sn{sub 4} at stage I (0–120 min) whereas the dynamic equilibrium between chemical potential gradient and temperature gradient forces was attained at the hot end at stage II (120–210 min). When dynamic equilibrium was achieved at 260 °C, the critical length-temperature gradient product at the hot end was experimentally estimated to be 489.18 μm × °C/cm and the moving velocity of Ni{sub 3}Sn{sub 4} interface due to Ni consumption was calculated to be 0.134 μm/h. The molar heat of transport (Q*) of Ni atoms in molten SnAg solder was calculated to be +0.76 kJ/mol. - Highlights: • Interfacial reaction in Ni/SnAg solder/Ni system under thermal gradient. • Growth rate of Ni{sub 3}Sn{sub 4} at cold end is faster than that at hot end. • Critical length-temperature gradient product at hot end is 489.2 μm°C/cm at 260 °C. • Velocity of Ni{sub 3}Sn{sub 4} moving interface is 0.134 μm/h during dynamic equilibrium. • Molar heat of transport (Q*) of Ni in molten SnAg was +0.76 kJ/mol.

  6. Evaluation of the Antitumor Activity by Ni Nanoparticles with Verbascoside

    Directory of Open Access Journals (Sweden)

    Mingyue Chen

    2013-01-01

    Full Text Available Verbascoside (VB has attracted a great deal of attention due to ITS pharmacological properties. In our study, we synthesized a multifunctional verbascoside coated Ni nanoparticles (VB-Ni. Transmission electron microscopy (TEM and high performance liquid chromatography (HPLC display the characteristics of VB-Ni nanoparticles. Compared with VB, VB-Ni has been proven to induce apoptosis and resist the growth of doxorubicin-resistant K562 cells in vitro and in vivo. Thus, VB-Ni nanoparticles can be thought of as an ideal mode of cancer treatment.

  7. A Study on Production of Carbon Nanotubes by CH4 Decomposition over LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Carbon nanotubes (CNTs) of narrow size distribution can be abundantly produced in the catalytic decomposition of CH4 over pre-reduced LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4.The CNTs obtained were characterized by means of transmission electron microscopy (TEM).Thermal oxidation of CNTs in air was monitored thermogravimetrically (TG). The resultsrevealed that a lower La/Ni ratio of the catalysts would lead to a wider diameter distribution and a higher degree of graphitic nature.

  8. Thin NiTi Films Deposited on Graphene Substrates

    Science.gov (United States)

    Hahn, S.; Schulze, A.; Böhme, M.; Hahn, T.; Wagner, M. F.-X.

    2017-03-01

    We present experimental results on the deposition of Nickel Titanium (NiTi) films on graphene substrates using a PVD magnetron sputter process. Characterization of the 2-4 micron thick NiTi films by electron microscopy, electron backscatter diffraction, and transmission electron microscopy shows that grain size and orientation of the thin NiTi films strongly depend on the type of combination of graphene and copper layers below. Our experimental findings are supported by density functional theory calculations: a theoretical estimation of the binding energies of different NiTi-graphene interfaces is in line with the experimentally determined microstructural features of the functional NiTi top layer.

  9. Properties of mechanically alloyed Mg-Ni-Ti ternary hydrogen storage alloys for Ni-MH batteries

    Science.gov (United States)

    Ruggeri, Stéphane; Roué, Lionel; Huot, Jacques; Schulz, Robert; Aymard, Luc; Tarascon, Jean-Marie

    MgNiTi x, Mg 1- xTi xNi and MgNi 1- xTi x (with x varying from 0 to 0.5) alloys have been prepared by high energy ball milling and tested as hydrogen storage electrodes. The initial discharge capacities of the Mg-Ni-Ti ternary alloys are inferior to the MgNi electrode capacity. However, an exception is observed with MgNi 0.95Ti 0.05, which has an initial discharge capacity of 575 mAh/g compared to 522 mAh/g for the MgNi electrode. The Mg-Ni-Ti ternary alloys show improved cycle life compared to Mg-Ni binary alloys with the same Mg/Ni atomic ratio. The best cycle life is observed with Mg 0.5Ti 0.5Ni electrode which retains 75% of initial capacity after 10 cycles in comparison to 39% for MgNi electrodes, in addition to improved high-rate dischargeability (HRD). According to the XPS analysis, the cycle life improvement of the Mg 0.5Ti 0.5Ni electrode can be related to the formation of TiO 2 which limits Mg(OH) 2 formation. The anodic polarization curve of Mg 0.5Ti 0.5Ni electrode shows that the current related to the active/passive transition is much less important and that the passive region is more extended than for the MgNi electrode but the corrosion of the electrode is still significant. This suggests that the cycle life improvement would be also associated with a decrease of the particle pulverization upon cycling.

  10. Densities of molten Ni-(Cr, Co, W) superalloys

    Institute of Scientific and Technical Information of China (English)

    XIAO Feng; YANG Ren-hui; FANG Liang; LIU Lan-xiao; ZHAO Hong-kai

    2008-01-01

    In order to obtain more accurate density for molten Ni-(Cr, Co, W) binary alloy, the densities of molten pure Ni and Ni-Cr, Ni-Co, Ni-W alloys were measured with a sessile drop method. It is found that the measured densities of molten pure Ni and Ni-Cr, Ni-Co, Ni-W alloys decrease with increasing temperature in the experimental temperature range. The density of alloys increases with increasing W and Co concentrations while it decreases with increasing Cr concentration in the alloy at 1 773-1 873 K. The molar volume of Ni-based alloys increases with increasing W concentration while it decreases with increasing Co concentration. The effect of Cr concentration on the molar volume of the alloy is little in the studied concentration range. The accommodation among atomic species was analyzed. The deviation of molar volume from ideal mixing shows an ideal mixing of Ni-(Cr, Co, W) binary alloys.

  11. Spectroscopic investigation of Ni speciation in hardened cement paste.

    Science.gov (United States)

    Vespa, M; Dähn, R; Grolimund, D; Wieland, E; Scheidegger, A M

    2006-04-01

    Cement-based materials play an important role in multi-barrier concepts developed worldwide for the safe disposal of hazardous and radioactive wastes. Cement is used to condition and stabilize the waste materials and to construct the engineered barrier systems (container, backfill, and liner materials) of repositories for radioactive waste. In this study, Ni uptake by hardened cement paste has been investigated with the aim of improving our understanding of the immobilization process of heavy metals in cement on the molecular level. X-ray absorption spectroscopy (XAS) coupled with diffuse reflectance spectroscopy (DRS) techniques were used to determine the local environment of Ni in cement systems. The Ni-doped samples were prepared at two different water/cement ratios (0.4, 1.3) and different hydration times (1 hour to 1 year) using a sulfate-resisting Portland cement. The metal loadings and the metal salts added to the system were varied (50 up to 5000 mg/kg; NO3(-), SO4(2-), Cl-). The XAS study showed that for all investigated systems Ni(ll) is predominantly immobilized in a layered double hydroxide (LDH) phase, which was corroborated by DRS measurements. Only a minor extent of Ni(ll) precipitates as Ni-hydroxides (alpha-Ni(OH)2 and beta-Ni(OH)2). This finding suggests that Ni-Al LDH, rather than Ni-hydroxides, is the solubility-limiting phase in the Ni-doped cement system.

  12. Design and fabrication of Ni nanowires having periodically hollow nanostructures.

    Science.gov (United States)

    Sada, Takao; Fujigaya, Tsuyohiko; Nakashima, Naotoshi

    2014-10-07

    We propose a concept for the design and fabrication of metal nanowires having periodically hollow nanostructures inside the pores of an anodic aluminum oxide (AAO) membrane using a sacrificial metal. In this study, nickel (Ni) and silver (Ag) were used as the base metal and the sacrificial metal, respectively. Alternating an applied potential between -0.4 and -1.0 V provided alternatively deposited Ni and Ag segments in a Ni-Ag 'barcode' nanowire with a diameter of 18 or 35 nm. After etching away the Ag segments, we fabricated Ni nanowires with nanopores of 12 ± 5.3 nm. Such nanostructure formation is explained by the formation of a Ni shell layer over the surface of the Ag segments due to the strong affinity of Ni(2+) for the interior surfaces of AAO. The Ni shell layer allows the Ni segments to remain even after dissolution of the Ag segments. Because the electroplating conditions can be easily controlled, we could carefully adjust the size and pitch of the periodically hollow nanospaces. We also describe a method for the fabrication of Ni nanorods by forming an Ag shell instead of a Ni shell on the Ni-Ag barcode nanowire, in which the interior of the AAO surfaces was modified with a compound bearing a thiol group prior to electroplating.

  13. Ductility of Ni3Al doped with substitutional elements

    International Nuclear Information System (INIS)

    Hanada, S.; Chiba, A.; Guo, H.Z.; Watanabe, S.

    1993-01-01

    This paper reports on ductility of B-free Ni 3 Al alloys. Recrystallized Ni 3 Al binary alloys with Ni-rich compositions show appreciable ductility when an environmental effect is eliminated, while the alloys with stoichiometric and Al-rich compositions remain brittle. The ductility in the Ni-rich Ni 3 Al alloys is associated with low ordering energy. The additions of ternary elements, which are classified as γ formers, ductilize ternary Ni 3 Al alloys(Ni-23 at% Al-2 at% X, X = Pd, Pt, Cu and Co), whereas the additions of γ' formers embrittle ternary Ni 3 Al alloys(Ni-23 at% Al-2 at% X, X = Ta, Mo, Nb, Zr, Hf, V, Ti and Si). The additions of small amounts (less than 1 at%) of γ' formers such as Zr and Hf also ductilize as-cast ternary Ni 3 Al alloys. Ductility of Ni 3 Al alloys doped with substitutional elements is discussed in terms of ordering energy and microstructure

  14. CO2 activation on bimetallic CuNi nanoparticles

    Directory of Open Access Journals (Sweden)

    Natalie Austin

    2016-10-01

    Full Text Available Density functional theory calculations have been performed to investigate the structural, electronic, and CO2 adsorption properties of 55-atom bimetallic CuNi nanoparticles (NPs in core-shell and decorated architectures, as well as of their monometallic counterparts. Our results revealed that with respect to the monometallic Cu55 and Ni55 parents, the formation of decorated Cu12Ni43 and core-shell Cu42Ni13 are energetically favorable. We found that CO2 chemisorbs on monometallic Ni55, core-shell Cu13Ni42, and decorated Cu12Ni43 and Cu43Ni12, whereas, it physisorbs on monometallic Cu55 and core-shell Cu42Ni13. The presence of surface Ni on the NPs is key in strongly adsorbing and activating the CO2 molecule (linear to bent transition and elongation of C˭O bonds. This activation occurs through a charge transfer from the NPs to the CO2 molecule, where the local metal d-orbital density localization on surface Ni plays a pivotal role. This work identifies insightful structure-property relationships for CO2 activation and highlights the importance of keeping a balance between NP stability and CO2 adsorption behavior in designing catalytic bimetallic NPs that activate CO2.

  15. NiCo2S4 nanosheet-decorated 3D, porous Ni film@Ni wire electrode materials for all solid-state asymmetric supercapacitor applications.

    Science.gov (United States)

    Saravanakumar, Balasubramaniam; Jayaseelan, Santhana Sivabalan; Seo, Min-Kang; Kim, Hak-Yong; Kim, Byoung-Suhk

    2017-12-07

    Wire type supercapacitors with high energy and power densities have generated considerable interest in wearable applications. Herein, we report a novel NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire electrode for high performance supercapacitor application. In this work, a facile method is introduced to fabricate a 3D, porous Ni film deposited on a Ni wire as a flexible electrode, followed by decoration with NiCo 2 S 4 as an electroactive material. The fabricated NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire electrode displays a superior performance with an areal and volumetric capacitance of 1.228 F cm -2 and 199.74 F cm -3 , respectively, at a current density of 0.2 mA cm -1 with a maximum volumetric energy and power density (E V : 6.935 mW h cm -3 ; P V : 1.019 W cm -3 ). Finally, the solid state asymmetric wire type supercapacitor is fabricated using the fabricated NiCo 2 S 4 -decorated 3D, porous Ni film@Ni wire as a positive electrode and N-doped reduced graphene oxide (N-rGO) as a negative electrode and this exhibits good areal and volumetric capacitances of C A : 0.12 F cm -2 and C V : 19.57 F cm -2 with a higher rate capability (92%). This asymmetric wire type supercapacitor demonstrates a low leakage current and self-discharge with a maximum volumetric energy (E V : 5.33 mW h cm -3 ) and power (P V : 855.69 mW cm -3 ) density.

  16. Surface morphology and electronic structure of Ni/Ag(100)

    International Nuclear Information System (INIS)

    Hite, D. A.; Kizilkaya, O.; Sprunger, P. T.; Howard, M. M.; Ventrice, C. A. Jr.; Geisler, H.; Zehner, D. M.

    2000-01-01

    The growth morphology and electronic structure of Ni on Ag(100) has been studied with scanning tunneling microscopy (STM) and synchrotron based angle resolved photoemission spectroscopy. At deposition temperatures at or below 300 K, STM reveals Ni cluster growth on the surface along with some subsurface growth. Upon annealing to 420 K, virtually all Ni segregates into the subsurface region forming embedded nanoclusters. The electronic structure of Ni d bands in the unannealed surface shows dispersion only perpendicular to the surface whereas the annealed surface has Ni d bands that exhibit a three-dimensional-like structure. This is a result of the increased Ni d-Ag sp hybridization bonding and increased coordination of the embedded Ni nanoclusters. (c) 2000 American Vacuum Society

  17. Measurement and analyses of molten Ni-Co alloy density

    Institute of Scientific and Technical Information of China (English)

    XIAO Feng; K. MUKAI; FANG Liang; FU Ya; YANG Ren-hui

    2006-01-01

    With the advent of powerful mathematical modeling techniques for material phenomena, there is renewed interest in reliable data for the density of the Ni-based superalloys. Up to now, there has been few report on the density of molten Ni-Co alloy.In order to obtain more accurate density data for molten Ni-Co alloy, the density of molten Ni-Co alloy was measured with a modified sessile drop method, and the accommodation of different atoms in molten Ni-Co alloy was analyzed. The density of alloy is found to decrease with increasing temperature and Co concentration in the alloy. The molar volume of molten Ni-Co alloy increases with increasing Co concentration. The molar volume of Ni-Co alloy determined shows a positive deviation from the linear molar volume, and the deviation of molar volume from ideal mixing increases with increasing Co concentration over the experimental concentration range.

  18. In situ NiTi/Nb(Ti) composite

    International Nuclear Information System (INIS)

    Jiang, Daqiang; Cui, Lishan; Jiang, Jiang; Zheng, Yanjun

    2013-01-01

    Graphical abstract: - Highlights: • In situ NiTi/Nb(Ti) composites were fabricated. • The transformation temperature was affected by the mixing Ti:Ni atomic ratios. • The NiTi component became micron-scale lamella after forging and rolling. • The composite exhibited high strength and high damping capacity. - Abstract: This paper reports on the creation of a series of in situ NiTi/Nb(Ti) composites with controllable transformation temperatures based on the pseudo-binary hypereutectic transformation of NiTi–Nb system. The composite constituent morphology was controlled by forging and rolling. It is found that the thickness of the NiTi lamella in the composite reached micron level after the hot-forging and cold-rolling. The NiTi/Nb(Ti) composite exhibited high damping capacity as well as high yield strength

  19. Ni3d-Gd4f correlation effects on the magnetic behaviour of GdNi

    Energy Technology Data Exchange (ETDEWEB)

    Paulose, P L [Tata Inst. of Fundamental Research, Bombay (India); Patil, Sujata [Tata Inst. of Fundamental Research, Bombay (India); Mallik, R [Tata Inst. of Fundamental Research, Bombay (India); Sampathkumaran, E V [Tata Inst. of Fundamental Research, Bombay (India); Nagarajan, V [Tata Inst. of Fundamental Research, Bombay (India)

    1996-07-01

    The results of magnetization and heat-capacity measurements on the alloys, Gd{sub 1-x}Y{sub x}Ni (x=0.0, 0.25, 0.5, 0.75 and 0.9) are reported. The data suggest that there is a Gd induced magnetic moment on Ni, which may in turn enhance Gd-Gd exchange interaction strength in GdNi. The induced moment (on Ni) apparently exhibits itinerant ferromagnetism in the magnetically ordered state of GdNi. (orig.).

  20. Effects of Bond Coating on NiCrBSi-Mo Composite Functional Coating Properties in Plasma Spraying NiCrBSi-Mo/Ni Coating

    OpenAIRE

    DU Ji-yu; LI Fang-yi; LU Hai-yang; SHANG Jian-tong; LI Zhen

    2017-01-01

    Nickel-based bond coating and composite functional coating were sprayed on leaf blade steel material FV520B successively by using air plasma spraying system. NiCrBSi-Mo powder deposition rate, coating porosity, bonding strength and surface hardness were tested. The results indicate that, for the NiCrBSi-Mo/Ni coating, bond coating with 180-220μm thickness can improve NiCrBSi-Mo powder deposition rate while the surface coating with lower porosity, higher bonding strength and high hardness is p...

  1. Thermodynamic characterization of Ni3TeO6, Ni2Te3O8 and NiTe2O5

    Science.gov (United States)

    Dawar, Rimpi; Babu, R.; Ananthasivan, K.; Anthonysamy, S.

    2017-09-01

    Measurement of vapour pressure of TeO2(g) over the biphasic mixture Ni3TeO6 (s) + NiO(s) in the temperature range 1143-1272 K was carried out using transpiration-thermogravimetric technique (TTG). Gibbs energy of formation of Ni3TeO6 was obtained from the temperature dependence of vapour pressure of TeO2 (g) generated by the incongruent vapourisation reaction, Ni3TeO6 (s) → NiO(s) + TeO2 (g) + 1/2 O2 in the temperature range 1143-1272 K. An isoperibol type drop calorimeter was used to measure the enthalpy increments of Ni3TeO6, Ni2Te3O8 and NiTe2O5. Thermodynamic functions viz., heat capacity, entropy and Gibbs energy functions of these compounds were derived from the experimentally measured enthalpy increment values. Third-law analysis was carried out to ascertain absence of temperature dependent systematic errors in the measurement of vapour pressure of TeO2 (g). A value of -1265.1 ± 1.5 kJ mol-1 was obtained for Δ Hf,298K o (Ni3TeO6) using third-law analysis.

  2. Structural and magnetic properties of Ni-Zn and Ni-Zn-Co ferrites

    Energy Technology Data Exchange (ETDEWEB)

    Knyazev, A.V., E-mail: knyazevav@gmail.com [N.I. Lobachevsky State University of Nizhni Novgorod, Gagarin Prospekt 23/2, 603950 Nizhni Novgorod (Russian Federation); Zakharchuk, I.; Lähderanta, E. [Lappeenranta University of Technology, P.O. Box 20, FI-53851 Lappeenranta (Finland); Baidakov, K.V.; Knyazeva, S.S. [N.I. Lobachevsky State University of Nizhni Novgorod, Gagarin Prospekt 23/2, 603950 Nizhni Novgorod (Russian Federation); Ladenkov, I.V. [Joint-stock Company “Research and Production Company “Salut”, Nizhni Novgorod (Russian Federation)

    2017-08-01

    Highlights: • Ni-Zn and Ni-Zn-Co ferrite powders were prepared by the solid-state reaction at 1073 K. • The room temperature saturation magnetizations are 59.7 emu/g for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 57.1 emu/g for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. • The coercivity of the samples is found to be much larger than that of bulk ferrites and increases with Co introduction. • The temperature dependences of magnetization exhibit large spin frustration and spin-glass-like behavior. - Abstract: Ni-Zn and Ni-Zn-Co ferrite powders with nominal compositions Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4} were prepared by the solid-state reaction synthesis with periodic regrinding during the calcination at 1073 K. The structure of Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4} was refined assuming space group F d-3m. Scanning electron microscopy revealed the average sizes of the crystalline ferrite particles are 130–630 nm for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 140–350 nm for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. The room temperature saturation magnetizations are 59.7 emu/g for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 57.1 emu/g for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. The coercivity of the samples is found to be much larger than that of bulk ferrites and increases with Co introduction. The Curie temperature tends to increase upon Zn substitution by Co, as well. The temperature dependences of magnetization measured using zero-field cooled and field cooled protocols exhibit large spin frustration and spin-glass-like behavior.

  3. Anti-corrosive and anti-microbial properties of nanocrystalline Ni-Ag coatings

    Energy Technology Data Exchange (ETDEWEB)

    Raghupathy, Y.; Natarajan, K.A.; Srivastava, Chandan, E-mail: csrivastava@materials.iisc.ernet.in

    2016-04-15

    Graphical abstract: - Highlights: • Electrodeposition yielded phase-segregated, nanocrystalline Ni-Ag coatings. • Ni-Ag alloys exhibited smaller Ni crystals compared to pure Ni. • Ultra fine Ni grains of size 12–14 nm favoured Ni-Ag solid solution. • Nanocrystalline Ag resisted bio-fouling by Sulphate Reducing bacteria. • Ni-Ag outperformed pure Ni in corrosion and bio-corrosion tests. - Abstract: Anti-corrosive and anti-bacterial properties of electrodeposited nanocrystalline Ni-Ag coatings are illustrated. Pure Ni, Ni-7 at.% Ag, & Ni-14 at.% Ag coatings were electrodeposited on Cu substrate. Coating consisted of Ni-rich and Ag-rich solid solution phases. With increase in the Ag content, the corrosion resistance of the Ni-Ag coating initially increased and then decreased. The initial increase was due to the Ni-Ag solid solution. The subsequent decrease was due to the increased galvanic coupling between the Ag-rich and Ni-rich phases. For all Ag contents, the corrosion resistance of the Ni-Ag coating was higher than the pure Ni coating. Exposure to Sulphate Reducing Bacteria (SRB) revealed that the extent of bio-fouling decreased with increase in the Ag content. After 2 month exposure to SRB, the Ni-Ag coatings demonstrated less loss in corrosion resistance (58% for Ni-7 at.% Ag and 20% for Ni-14 at.% Ag) when compared pure Ni coating (115%).

  4. Niños y niñas como cuidadores familiares

    Directory of Open Access Journals (Sweden)

    María Rosa Estupiñán Aponte

    2015-01-01

    Full Text Available En el contexto familiar, el cuidado de otra persona por parte de niños y niñas constituye un terreno inexplorado tanto en su significado como en las implicaciones que podrían darse en el proceso. Aunque históricamente se ha asignado el cuidado familiar a las mujeres generando condiciones de inequidad, incrementada con los cambios sociales de los últimos tiempos, es necesario reconocer que en muchos hogares niños y niñas se han visto obligados a desempeñar esta labor sin la preparación ni las destrezas necesarias. Desde una perspectiva de género, el artículo busca evidenciar esta situación mediante la revisión de los abordajes que sobre el tema se han hecho en países de Europa y Norteamérica, así como el análisis de información obtenida a partir de las Encuestas de Hogares y Uso del Tiempo (EUT en algunos países de Latinoamérica. Se establece la forma como las problemáticas sociales inciden en las dinámicas, tipo de tareas y responsabilidades que deben asumir niños y niñas en los hogares, mostrando delgados límites entre la colaboración al interior de las familias, la transmisión cultural de roles y funciones y las actividades que podrían incidir negativamente en su crecimiento y el ejercicio de sus derechos.

  5. Estilos de vida saludables de niños, niñas y adolescentes

    Directory of Open Access Journals (Sweden)

    Lilia Campo-Ternera

    2017-01-01

    Full Text Available Objetivo: Describir los estilos de vida saludables de niños, niñas y adolescentes de Barranquilla. Materiales y métodos: Estudio descriptivo de corte transversal en 991 niños, niñas y ado - lescentes. Se evaluó la actividad física mediante los cuestionarios de Actividad Física para Adolescentes y para niños escolares; se aplicó una encuesta que midió los conocimientos y prácticas de los escolares sobre salud bucal, lavado de manos, consumo de frutas y verduras y cuidado postural; la Lista de Chequeo “Mi Vida en la Escuela”, la cual evalúa los índices de “bullying” y agresión; y la inteligencia emocional a través dela escala TMMS -24. Resultados: El 65,4 % se categoriza como inactivos físicamente. Solo el 14,7% de los estudiantes reconoce que el peso máximo del bolso es el 10 % de su peso corporal; el 34,1 % cambia el cepillo de dientes cada 3 meses, como lo recomiendan los expertos, y 48,4 % se cepilla los dientes entre 2 y 3 veces al día. El 16,6 % no se lava las manos antes y después de ir al baño y 9,4 % no lo hace antes y después de las comidas; el 17,5 % no tiene un buen consumo de verduras y frutas; y se encontró un Índice de “bullying” en el 55,6 % de los participantes. Conclusión: Los anteriores resultados obligan a plantear intervenciones que incrementen las prácticas saludables en niños, niñas y adolescentes.

  6. Electrochemical properties of the ball-milled LaMg10NiMn alloy with Ni powders

    International Nuclear Information System (INIS)

    Wang Yi; Wang Xin; Gao Xueping; Shen Panwen

    2008-01-01

    The electrochemical characteristics of the ball-milled LaMg 10 NiMn alloys with Ni powders were investigated. It was found that the ball-milled LaMg 10 NiMn + 150 wt.% Ni composite exhibited higher first discharge capacity and better cycle performance. By means of the analysis of electrochemical impedance spectra (EIS), it was shown that the existence of manganese in LaMg 10 NiMn alloy increased the electrocatalytic activity due to its catalytic effect, and destabilized metal hydrides, and so reduced the hydrogen diffusion resistance. These contributed to the higher discharge capacity of the ball-milled LaMg 10 NiMn-Ni composite. According to the analytical results of X-ray diffraction (XRD), EIS and steady-state polarization (SSP) experiments, the inhibition of metal corrosion is not the main reason for the better cycle performance. The main reason is that the electrochemical reaction resistance of the ball-milled LaMg 10 NiMn-Ni composite is always lower than that of the ball-milled LaMg 10 Ni 2 -Ni composite because the former one contains manganese, which is a catalyst for the electrode reaction

  7. High-frequency permeability of electroplated CoNiFe and CoNiFe-C alloys

    International Nuclear Information System (INIS)

    Rhen, Fernando M.F.; McCloskey, Paul; O'Donnell, Terence; Roy, Saibal

    2008-01-01

    We have investigated CoNiFe and CoNiFe-C electrodeposited by pulse reverse plating (PRP) and direct current (DC) techniques. CoNiFe(PRP) films with composition Co 59.4 Fe 27.7 Ni 12.8 show coercivity of 95 A m -1 (1.2 Oe) and magnetization saturation flux (μ 0 M s ) of 1.8 T. Resistivity of CoNiFe (PRP) is about 24 μΩ cm and permeability remains almost constant μ r ' ∼475 up to 30 MHz with a quality factor (Q) larger than 10. Additionally, the permeability spectra analysis shows that CoNiFe exhibits a classical eddy current loss at zero bias field and ferromagnetic resonance (FMR) when biased with 0.05 T. Furthermore, a crossover between eddy current and FMR loss is observed for CoNiFe-PRP when baised with 0.05 T. DC and PRP plated CoNiFe-C, which have resistivity and permeability of 85, 38 μΩ cm, μ r '=165 and 35 with Q>10 up to 320 MHz, respectively, showed only ferromagnetic resonance losses. The ferromagnetic resonance peaks in CoNiFe and CoNiFe-C are broad and resembles a Gaussian distribution of FMR frequencies. The incorporation of C to CoNiFe reduces eddy current loss, but also reduces the FMR frequency

  8. Corrosive sliding wear behavior of laser clad Mo2Ni3Si/NiSi intermetallic coating

    International Nuclear Information System (INIS)

    Lu, X.D.; Wang, H.M.

    2005-01-01

    Many ternary metal silicides such as W 2 Ni 3 Si, Ti 2 Ni 3 Si and Mo 2 Ni 3 Si with the topologically closed-packed (TCP) hP12 MgZn 2 type Laves phase crystal structure are expected to have outstanding wear and corrosion resistance due to their inherent high hardness and sluggish temperature dependence and strong atomic bonds. In this paper, Mo 2 Ni 3 Si/NiSi intermetallic coating was fabricated on substrate of an austenitic stainless steel AISI321 by laser cladding using Ni-Mo-Si elemental alloy powders. Microstructure of the coating was characterized by optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD) and energy dispersive X-ray analysis (EDS). Wear resistance of the coating is evaluated under corrosive sliding wear test condition. Influence of corrosion solutions on the wear resistance of the coating was studied and the wear mechanism was discussed based on observations of worn surface morphology. Results showed that the laser clad Mo 2 Ni 3 Si/NiSi composite coating have a fine microstructure of Mo 2 Ni 3 Si primary dendrites and the interdendritic Mo 2 Ni 3 Si/NiSi eutectics. The coating has excellent corrosive wear resistance compared with austenitic stainless steel AISI321 under acid, alkaline and saline corrosive environments

  9. Magnetic properties of two new compounds: Pr2Ni3Si5 and Ho2Ni3Si5

    International Nuclear Information System (INIS)

    Mazumdar, C.; Padalia, B.D.; Godart, C.

    1994-01-01

    Formation of two more new materials, Pr 2 Ni 3 Si 5 and Ho 2 Ni 3 Si 5 , of the series, R 2 Ni 3 Si 5 (R = rare earth and Y) and their magnetic properties are reported here. These materials crystallize in the orthorhombic U 2 Co 3 Si 5 -type structure (space group Ibam). Magnetic susceptibility measurement in the temperature range 5 K--300 K show that the compound Pr 2 Ni 3 Si 5 order antiferromagnetically at T N ∼ 8.5 K and Ho 2 Ni 3 Si 5 at ∼ 6 K. Considering T N (Gd 2 Ni 3 Si 5 ) ∼ 15 K, T N (Pr 2 Ni 3 Si 5 ) ∼ 8.5 K is rather high. The magnetic susceptibility of both of the materials, in the paramagnetic state, follows a Curie-Weiss law with effective moment close to that of the corresponding free trivalent rare earth ion

  10. Effect of Ni Core Structure on the Electrocatalytic Activity of Pt-Ni/C in Methanol Oxidation

    Directory of Open Access Journals (Sweden)

    Vladimir Linkov

    2013-07-01

    Full Text Available Methanol oxidation catalysts comprising an outer Pt-shell with an inner Ni-core supported on carbon, (Pt-Ni/C, were prepared with either crystalline or amorphous Ni core structures. Structural comparisons of the two forms of catalyst were made using transmission electron microscopy (TEM, X-ray diffraction (XRD and X-ray photoelectron spectroscopy (XPS, and methanol oxidation activity compared using CV and chronoamperometry (CA. While both the amorphous Ni core and crystalline Ni core structures were covered by similar Pt shell thickness and structure, the Pt-Ni(amorphous/C catalyst had higher methanol oxidation activity. The amorphous Ni core thus offers improved Pt usage efficiency in direct methanol fuel cells.

  11. Hard X-ray MCD in GdNi/sub 5/ and TbNi/sub 5/ single crystals

    CERN Document Server

    Galera, R M

    1999-01-01

    XMCD experiments have been performed at the R L/sub 2,3/ and Ni K- edges on magnetically saturated single crystals of GdNi/sub 5/ and Tb Ni/sub 5/ ferromagnetic compounds. The spectra present huge and well structured dichroic $9 signals at both the R L/sub 2,3/ and the Ni K- edges. Structures from the quadrupolar (2p to 4f) transitions are clearly observed at the R L/sub 2,3/-edges. Though Ni is not magnetic, large intensities, up to 0.4, are measured at the $9 Ni K- edge. The Ni K-edge XMCD shows a three-peak structure which intensities dependent on the rare earth. (7 refs).

  12. Electrochemically induced transformation of NiS nanoparticles into Ni(OH)2 in KOH aqueous solution toward electrochemical capacitors

    International Nuclear Information System (INIS)

    Hou Linrui; Yuan Changzhou; Li Diankai; Yang Long; Shen Laifa; Zhang Fang; Zhang Xiaogang

    2011-01-01

    Highlights: → NiS is synthesized by means of the H 2 O/CS 2 interface under hydrothermal treatment. → NiS itself owns poor electrochemical capacitance in 2 M KOH solution. → NiS is electrochemically induced and transformed into electroactive Ni(OH) 2 . → Ni(OH) 2 is responsible for good energy storage of the NiS in the KOH solution. → The new formed Ni(OH) 2 delivers large energy density at high rates. - Abstract: Nickel sulfide nanoparticles (NPs) are first synthesized by virtue of a unique H 2 O/CS 2 interface under mild hydrothermal treatment. Electrochemical data reveals that the as-synthesized NiS NPs themselves own poor supercapacitive behavior at initial cyclic voltammetry (CV) cycles in 2 M KOH solution, while a specific capacitance of 893 F g -1 can be surprisingly obtained at a current density of 5 A g -1 just after continuous 320 CV cycles. X-ray diffraction and Fourier transform infrared techniques demonstrate that what is really responsible for the good electrochemical capacitance in the KOH aqueous solution is the new electrochemically formed Ni(OH) 2 phase, rather than NiS NPs themselves. The Ni(OH) 2 is slowly formed during the continuous CV cycling process, in which the electrochemically induced phase transformation from NiS to Ni(OH) 2 phase takes place. Furthermore, the new Ni(OH) 2 phase demonstrates the great ability of delivering large specific capacitance at high rates.

  13. Fe-Ni-bearing serpentines from the saprolite horizon of Caribbean Ni-laterite deposits: new insights from thermodynamic calculations

    Science.gov (United States)

    Villanova-de-Benavent, Cristina; Domènech, Cristina; Tauler, Esperança; Galí, Salvador; Tassara, Santiago; Proenza, Joaquín A.

    2017-10-01

    Fe-Ni-bearing serpentine from the saprolite horizon is the main Ni ores in hydrous silicate-type Ni laterites and formed by chemical weathering of partially serpentinized ultramafic rocks under tropical conditions. During lateritization, Mg, Si, and Ni are leached from the surface and transported downwards. Fe2+ is oxidized to Fe3+ and fixed as insoluble Fe-oxyhydroxides (mostly goethite) that incorporate Ni. This Ni is later leached from goethite and incorporated in secondary serpentine and garnierite. As a result, a serpentine-dominated saprolite horizon forms over the ultramafic protolith, overlapped by a Fe-oxyhydroxide-dominated limonite horizon. The serpentine from the protolith (serpentine I) is of hydrothermal origin and yields similar Ni (0.10-0.62 wt.% NiO) and lower Fe (mostly 1.37-5.81 wt.% FeO) concentrations than the primary olivine. In contrast, Fe-Ni-bearing serpentine from the saprolite (serpentine II) shows significantly higher and variable Fe and Ni contents, typically ranging from 2.23 to 15.59 wt.% Fe2O3 and from 1.30 to 7.67 wt.% NiO, suggesting that serpentine get enriched in Fe and Ni under supergene conditions. This study presents detailed mineralogical, textural, and chemical data on this serpentine II, as well as new insights by thermodynamic calculations assuming ideal solution between Fe-, Ni- and Mg-pure serpentines. The aim is to assess if at atmospheric pressure and temperature Fe-Ni-bearing serpentine can be formed by precipitation. Results indicate that the formation of serpentine II under atmospheric pressure and temperature is thermodynamically supported, and pH, Eh, and the equilibrium constant of the reaction are the parameters that affect the results more significantly.

  14. Ni{sub 3}Al technology transfer

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K.; Santella, M.L.; Alexander, D.J. [Oak Ridge National Laboratory, TN (United States)] [and others

    1995-05-01

    Ductile Ni{sub 3}Al and Ni{sub 3}Al-based alloys have been identified for a range of applications. These applications require the use of material in a variety of product forms such as sheet, plate, bar, tubing, piping, and castings. Although significant progress has been made in the melting, casting, and near-net-shape forming of nickel aluminides, some issues still remain. These include the need for (1)high-strength castable composition for turbochargers, furnace furniture, and hot-die applications; (2) castability (fluidity, hot-shortness, porosity, etc.); (3) weld reparability of castings; and (4) hot fabricability of cast ingots. All of the issues listed above can be {open_quotes}show stoppers{close_quotes} for the commercial application of nickel aluminides. This report describes work completed to address some of these issues during the fourth quarter of FY 1994.

  15. Ni{sub 3}Al technology transfer

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K.; Viswanathan, S.; Santella, M.L. [Oak Ridge National Lab., TN (United States)] [and others

    1997-04-01

    Ductile Ni{sub 3}Al and Ni{sub 3}Al-based alloys have been identified for a range of applications. These applications require the use of material in a variety of product forms such as sheet, plate, bar, wire, tubing, piping, and castings. Although significant progress has been made in the melting, casting, and near-net-shape forming of nickel aluminides, some issues still remain. These include the need for: (1) high-strength castable composition for many applications that have been identified; (2) castability (mold type, fluidity, hot-shortness, porosity, etc.); (3) weld reparability of castings; and (4) workability of cast or powder metallurgy product to sheet, bar, and wire. The four issues listed above can be {open_quotes}show stoppers{close_quotes} for the commercial application of nickel aluminides. This report describes the work completed to address some of these issues during FY 1996.

  16. Internal chlorination of Ni-Cr alloys

    Energy Technology Data Exchange (ETDEWEB)

    Berztiss, D.; Hennesen, K.; Grabke, H.J. [Max-Planck-Institut fuer Eisenforschung GmbH, Duesseldorf (Germany)

    1998-12-31

    In contrast to internal oxidation, sulfidation and carburization, very little information is available regarding internal chlorination, especially diffusion of chlorine in metallic alloys. This paper describes results of experiments on Ni-Cr alloys (<10 wt% Cr) exposed in an atmosphere containing radioactive HCl. The diffusion of chlorine in the alloy can be determined by measurement of residual {beta}-activity from the sample surface. Successively thin layers (0.5-10 {mu}m) of the alloy were removed by lapping and the surface activity was measured to obtain a depth profile. Both single and polycrystalline materials were tested. Through this work it should be determined if there is in fact solubility and diffusion of chlorine in Ni-based alloys as some authors have proposed or if the ingress of chlorine is mainly a grain boundary phenomenon. (orig.)

  17. Resonant Ni and Fe KLL Auger spectra photoexcited from NiFe alloys

    International Nuclear Information System (INIS)

    Koever, L.; Cserny, I.; Berenyi, Z.; Egri, S.; Novak, M.

    2005-01-01

    Complete text of publication follows. KLL Auger spectra of 3d transition metal atoms in solid environment, measured using high energy resolution, give an insight into the details of the local electronic structure surrounding the particular atoms emitting the signal Auger electrons. Fine tuning the energy of the exciting monochromatic photons across the K-absorption edge, features characteristic to resonant phenomena can be identified in the spectra. The shapes of the resonantly photoexcited KLL Auger spectra induced from 3d transition metals and alloys are well interpreted by the single step model of the Auger process, based on the resonant scattering theory. The peak shapes are strongly influenced by the 4p partial density of unoccupied electronic states around the excited atom. High energy resolution studies of KLL Auger spectra of 3d transition metals using laboratory X-ray sources, however, request very demanding experiments and yield spectra of limited statistical quality making the evaluation of the fine details in the spectra difficult. The Tunable High Energy XPS (THE- XPS) instrument at BW2 offers optimum photon x and energy resolution for spectroscopy of deep core Auger transitions. For the present measurements high purity polycrystalline Ni and Fe sheets as well as NiFe alloy samples of different compositions (Ni 80 Fe 20 , Ni 50 Fe 50 , Ni 20 Fe 80 ) were used. The surfaces of the samples were cleaned by in-situ argon ion sputtering. The measurements of the Ni and Fe KL 23 L 23 Auger spectra of the metal and alloy samples were performed with the THE-XPS instrument using high electron energy resolution (0.2 eV). In Fig.1, the measured Fe KL 23 L 23 spectrum, photoexcited at the Fe K absorption edge from Fe metal, is compared with the respective spectrum excited from a Ni 50 Fe 50 alloy. A significant broadening of the 1 D 2 peak and an enhancement of the spectral intensity at the low energy loss part of this peak observed in the alloy sample, while the

  18. Phase transitions in alloys of the Ni-Mo system

    International Nuclear Information System (INIS)

    Ustinovshikov, Y.; Shabanova, I.

    2011-01-01

    Graphical abstract: The structure of Ni-20 at.% Mo and Ni-25 at.% Mo alloys was studied by methods of TEM and XPS. It is shown that at high temperatures the tendency toward phase separation takes place in the alloys and crystalline bcc Mo particles precipitate in the liquid solution. At 900 deg. C and below, the tendency toward ordering leads to the dissolution of Mo particles and precipitation of the particles of Ni 3 Mo, Ni 2 Mo or Ni 4 Mo chemical compounds. Highlights: → 'Chemical' phase transition 'ordering-phase separation' is first discovered in alloys of the Ni-Mo system. → It is first shown that the phase separation in the alloys studied begins at temperatures above the liquidus one. → The formation of Ni 3 Mo from A1 has gone through the intervening stage of the Ni 4 Mo and Ni 2 Mo coexistence. - Abstract: The structure of Ni-20 at.% Mo and Ni-25 at.% Mo alloys heat treated at different temperatures was studied by the method of transmission electron microscopy. X-ray photoelectron spectroscopy was used to detect the sign of the chemical interaction between Ni and Mo atoms at different temperatures. It is shown that at high temperatures the tendency toward phase separation takes place. The system of additional reflections at positions {1 1/2 0} on the electron diffraction patterns testifies that the precipitation of crystalline bcc Mo particles begins in the liquid solution. At 900 deg. C and below, the tendency toward ordering leads to the precipitation of the particles of the chemical compounds. A body-centered tetragonal phase Ni 4 Mo (D1 a ) is formed in the Ni-20 at.% Mo alloy. In the Ni-25 at.% Mo alloy, the formation of the Ni 3 Mo (D0 22 ) chemical compound from the A1 solid solution has gone through the intervening stage of the Ni 4 Mo (D1 a ) and Ni 2 Mo (Pt 2 Mo) formation.

  19. Combining Ru, Ni and Ni(OH){sub 2} active sites for improving catalytic performance in benzene hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Lihua, E-mail: lihuazhu@stu.xmu.edu.cn [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Sun, Hanlei; Zheng, Jinbao [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Yu, Changlin, E-mail: yuchanglinjx@163.com [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Zhang, Nuowei [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Shu, Qing [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Chen, Bing H., E-mail: chenbh@xmu.edu.cn [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)

    2017-05-01

    In this study, the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts were successfully prepared by the simple methods of hydrazine-reduction and galvanic replacement, where 0.04/0.96 and T represented the Ru/Ni atomic ratio and reducing temperature of the catalyst in N{sub 2}+10%H{sub 2}, respectively. The nanostructures of the Ru{sub 0.04}Ni{sub 0.96} nanoparticles in the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts were controlled by modulating their annealing temperature in N{sub 2}+10%H{sub 2} and characterized by an array of techniques, including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), scanning transmission electron microscopy energy dispersive X-ray spectroscopy (STEM-EDS) mapping and high-sensitivity low-energy ion scattering (HS-LEIS). The Ru{sub 0.04}Ni{sub 0.96}/C(30) catalyst, which was composed of Ru clusters or single atoms supported on Ni/Ni(OH){sub 2} nanoparticles, exhibited much better catalytic performance for benzene hydrogenation than the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts reduced at above 30 °C, such as Ru{sub 0.04}Ni{sub 0.96}/C(160) with the nanostructure of partial Ru{sub 0.04}Ni{sub 0.9} alloy and Ru{sub 0.04}Ni{sub 0.96}/C(280) with the nanostructure of complete Ru{sub 0.04}Ni{sub 0.9} alloy. The reason was that the synergistic effect of multiple active sites – Ru, Ni and Ni(OH){sub 2} sites was present in the Ru{sub 0.04}Ni{sub 0.96}/C(30) catalyst, where hydrogen was preferentially activated at Ru sites, benzene was probably activated at Ni(OH){sub 2} surface and Ni acted as a “bridge” for transferring activated H{sup ∗} species to activated benzene by hydrogen spillover effect, hydrogenating and forming product – cyclohexane. This study also provided a typical example to illustrate that the synergy effect of multiple active sites can largely improve the catalytic hydrogenation performance. - Highlights: • The Ru

  20. Imaging magnetic domains in Ni nanostructures

    International Nuclear Information System (INIS)

    Asenjo, A.; Jaafar, M.; Gonzalez, E.M.; Martin, J.I.; Vazquez, M.; Vicent, J.L.

    2007-01-01

    The study of nanomagnets is the subject of increasing scientific effort. The size, the thickness and the geometric shape of the elements determine the magnetic properties and then the domain configuration. In this work, we fabricated by electron-beam lithography the three different arrays of Ni nanostructures keeping the size, the thickness and also the distance constant between the elements but varying the geometry: square, triangular and circular. The domain structure of the nanomagnets is studied by magnetic force microscopy

  1. Determination of 59Ni in radioactive waste

    International Nuclear Information System (INIS)

    Fisera, O.; Sebesta, F.

    2010-01-01

    Composite material PAN-DMG, containing chelating agent dimethylglyoxime (DMG) immobilized in porous matrix of binding polymer polyacrylonitrile (PAN), was used for nickel separation and concentration. Method for preparation of 59 Ni source for low energy photon spectrometry was developed using homogeneous precipitation of nickel with DMG. The proposed method was tested with two types of real radioactive waste (boric acid concentrate from nuclear power plant (NPP) evaporator and spent ion exchanger from NPP). (author)

  2. Structural, electrical and magnetic properties of evaporated Ni/Cu and Ni/glass thin films

    Energy Technology Data Exchange (ETDEWEB)

    Nacereddine, C. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria); Layadi, A. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria)]. E-mail: A_Layadi@yahoo.fr; Guittoum, A. [Centre de Recherche Nucleaire d' Alger (CRNA), Alger 16000 (Algeria); Cherif, S.-M. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse 93340 (France); Chauveau, T. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse 93340 (France); Billet, D. [Laboratoire PMTM, Institut Galilee, Univeriste Paris 13, Villetaneuse 93340 (France); Youssef, J. Ben [Laboratoire de Magnetisme de Bretagne, U.B.O., Brest 29238 (France); Bourzami, A. [Departement de Physique, Universite Ferhat Abbas, Setif 19000 (Algeria); Bourahli, M.-H. [Departement d' O. M. P., Universite Ferhat Abbas, Setif 19000 (Algeria)

    2007-01-25

    The structural, electrical and magnetic properties of Ni thin films evaporated onto glass and polycrystalline Cu substrates have been investigated. The Ni thickness ranges from 31 to 165 nm. X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM) have been used to study the structure and morphology of these systems. The Ni/Cu and Ni/glass thin films are found to be polycrystalline with a (1 1 1) texture. There is an overall increase of the grain size with increasing thickness. A negative strain was noted indicating that all the samples are under a compressive stress. Diffusion at the grain boundaries seems to be a major contribution to the electrical resistivity in this thickness range. Study of the hysteresis curves, obtained by vibrating sample magnetometer (VSM), indicates that all samples are characterized by an in-plane magnetization easy axis. Higher in-plane coercive fields seem to be associated with higher grain size, indicating that coercivity may be due to nucleation of reverse domains rather than pinning of domain walls. The saturation field and the squareness have been studied as a function of the Ni thickness.

  3. Participar como niña o niño en el mundo social

    Directory of Open Access Journals (Sweden)

    Silvia Paulina Díaz

    2010-10-01

    Full Text Available En este artículo presento la participación como resultado de un trabajo investigativo realizado durante el año 2007, con niños y niñas escolarizados habitantes de la ciudad de Medellín, Colombia, cuyo objetivo fue analizar las representaciones sociales que ellos y ellas comparten sobre el ejercicio ciudadano. El análisis de la información tiene como ejes fundamentales, la salud colectiva, la sociología de la infancia y la participación en la niñez, en una aproximación que se realiza desde un enfoque cualitativo y etnográfico. En los hallazgos, sobresale cómo las niñas y niños se muestran preparados para ejercer su derecho a la participación como aspecto de sus vidas que se haría posible dentro del marco normativo existente, pero que aún no es asumido en prácticas sociales que los incluyan.

  4. HDO of Methyl Palmitate over Silica-Supported Ni Phosphides: Insight into Ni/P Effect

    Directory of Open Access Journals (Sweden)

    Irina V. Deliy

    2017-10-01

    Full Text Available Two sets of silica-supported nickel phosphide catalysts with a nickel content of about 2.5 and 10 wt % and Ni/P molar ratio 2/1, 1/1 and 1/2 in each set, were prepared by way of a temperature-programmed reduction method using (Ni(CH3COO2 and ((NH42HPO4 as a precursor. The NixPy/SiO2 catalysts were characterized using chemical analysis N2 physisorption, XRD, TEM, 31P MAS NMR. Methyl palmitate hydrodeoxygenation (HDO was performed in a trickle-bed reactor at 3 MPa and 290 °C with LHSV ranging from 0.3 to 16 h−1. The Ni/P ratio was found to affect the nickel phosphide phase composition, POx groups content and catalytic properties in methyl palmitate HDO with the TOF increased along with a decline of Ni/P ratio and a growth of POx groups’ content. Taking into account the possible routes of methyl palmitate conversion (metal-catalyzed hydrogenolysis or acid-catalyzed hydrolysis, we proposed that the enhancement of acid POx groups’ content with the Ni/P ratio decrease provides an enhancement of the rate of methyl palmitate conversion through the acceleration of acid-catalyzed hydrolysis.

  5. Participar como niña o niño en el mundo social

    Directory of Open Access Journals (Sweden)

    Silvia Paulina Díaz

    2010-01-01

    Full Text Available En este artículo presento la participación como resultado de un trabajo investigativo realizado durante el año 2007, con niños y niñas escolarizados habitantes de la ciudad de Medellín, Colombia, cuyo objetivo fue analizar las representaciones sociales que ellos y ellas comparten sobre el ejercicio ciudadano. El análisis de la información tiene como ejes fundamentales, la salud colectiva, la sociología de la infancia y la participación en la niñez, en una aproximación que se realiza desde un enfoque cualitativo y etnográfico. En los hallazgos, sobresale cómo las niñas y niños se muestran preparados para ejercer su derecho a la participación como aspecto de sus vidas que se haría posible dentro del marco normativo existente, pero que aún no es asumido en prácticas sociales que los incluyan.

  6. Tungsten inert gas (TIG) welding of Ni-rich NiTi plates: functional behavior

    Science.gov (United States)

    Oliveira, J. P.; Barbosa, D.; Braz Fernandes, F. M.; Miranda, R. M.

    2016-03-01

    It is often reported that, to successfully join NiTi shape memory alloys, fusion-based processes with reduced thermal affected regions (as in laser welding) are required. This paper describes an experimental study performed on the tungsten inert gas (TIG) welding of 1.5 mm thick plates of Ni-rich NiTi. The functional behavior of the joints was assessed. The superelasticity was analyzed by cycling tests at maximum imposed strains of 4, 8 and 12% and for a total of 600 cycles, without rupture. The superelastic plateau was observed, in the stress-strain curves, 30 MPa below that of the base material. Shape-memory effect was evidenced by bending tests with full recovery of the initial shape of the welded joints. In parallel, uniaxial tensile tests of the joints showed a tensile strength of 700 MPa and an elongation to rupture of 20%. The elongation is the highest reported for fusion-welding of NiTi, including laser welding. These results can be of great interest for the wide-spread inclusion of NiTi in complex shaped components requiring welding, since TIG is not an expensive process and is simple to operate and implement in industrial environments.

  7. High resolution TEM study of Ni4Ti3 precipitates in austenitic Ni51Ti49

    International Nuclear Information System (INIS)

    Tirry, Wim; Schryvers, Dominique

    2003-01-01

    Binary NiTi with a composition of 51 at.% Ni was heat treated to form lens-shaped Ni 4 Ti 3 precipitates that are coherent or semi-coherent with the B2 matrix. High resolution transmission electron microscopy (HRTEM) was used to study the internal structure of the precipitates, precipitate-precipitate and matrix-precipitate interfaces and the deformation of the B2 matrix near a precipitate. Observations were made in the B2 and B2 zones and compared with computer simulated high resolution images. The B2 observations made it possible to study the [0 0 1] H zone orientation of Ni 4 Ti 3 (direction defined according to the hexagonal unit cell of Ni 4 Ti 3 ) which corresponds to the normal of the central plane of the discs. In these images the superperiodicity of the 4:3 ordering is clearly visible confirming the known atomic structure. Close to the precipitate the B2 matrix is deformed, as determined by measuring the interplanar spacing from the HRTEM images. The observed deformations are compared with theoretical models for the stress field

  8. Breakdown of antiferromagnet order in polycrystalline NiFe/NiO bilayers probed with acoustic emission

    Science.gov (United States)

    Lebyodkin, M. A.; Lebedkina, T. A.; Shashkov, I. V.; Gornakov, V. S.

    2017-07-01

    Magnetization reversal of polycrystalline NiFe/NiO bilayers was investigated using magneto-optical indicator film imaging and acoustic emission techniques. Sporadic acoustic signals were detected in a constant magnetic field after the magnetization reversal. It is suggested that they are related to elastic waves excited by sharp shocks in the NiO layer with strong magnetostriction. Their probability depends on the history and number of repetitions of the field cycling, thus testifying the thermal-activation nature of the long-time relaxation of an antiferromagnetic order. These results provide evidence of spontaneous thermally activated switching of the antiferromagnetic order in NiO grains during magnetization reversal in ferromagnet/antiferromagnet (FM/AFM) heterostructures. The respective deformation modes are discussed in terms of the thermal fluctuation aftereffect in the Fulcomer and Charap model which predicts that irreversible breakdown of the original spin orientation can take place in some antiferromagnetic grains with disordered anisotropy axes during magnetization reversal of exchange-coupled FM/AFM structures. The spin reorientation in the saturated state may induce abrupt distortion of isolated metastable grains because of the NiO magnetostriction, leading to excitation of shock waves and formation of plate (or Lamb) waves.

  9. Electric Monopole Transition Strengths in 62Ni

    Directory of Open Access Journals (Sweden)

    Evitts L. J.

    2016-01-01

    Full Text Available Excited states in 62Ni were populated with a (p, p’ reaction using the 14UD Pelletron accelerator at the Australian National University. Electric monopole transition strengths, ρ2(E0, were measured through simultaneous detection of the internal conversion electrons and γ rays emitted from the de-excitation of populated states, using the Super-e spectrometer coupled with a germanium detector. The strength of the 02+ to 01+ transition has been measured to be 77−34+23 × 10−3 and agrees with previously reported values. Upper limits have been placed on the 03+ to 01+ and 03+ to 02+ transitions. The measured ρ2(E0 value of the 22+ to 21+ transition in 62Ni has been measured for the first time and found to be one of the largest ρ2(E0 values measured to date in nuclei heavier than Ca. The low-lying states of 62Ni have previously been classified as one- and two-phonon vibrational states based on level energies. The measured electric quadrupole transition strengths are consistent with this interpretation. However as electric monopole transitions are forbidden between states which differ by one phonon number, the simple harmonic quadrupole vibrational picture is not suffcient to explain the large ρ2(E0 value for the 22+ to 21+ transition.

  10. Electric Monopole Transition Strengths in 62Ni

    Science.gov (United States)

    Evitts, L. J.; Garnsworthy, A. B.; Kibédi, T.; Moukaddam, M.; Alshahrani, B.; Eriksen, T. K.; Holt, J. D.; Hota, S. S.; Lane, G. J.; Lee, B. Q.; McCormick, B. P.; Palalani, N.; Reed, M. W.; Stroberg, S. R.; Stuchbery, A. E.

    2016-09-01

    Excited states in 62Ni were populated with a (p, p') reaction using the 14UD Pelletron accelerator at the Australian National University. Electric monopole transition strengths, ρ2(E0), were measured through simultaneous detection of the internal conversion electrons and γ rays emitted from the de-excitation of populated states, using the Super-e spectrometer coupled with a germanium detector. The strength of the 02+ to 01+ transition has been measured to be 77-34+23 × 10-3 and agrees with previously reported values. Upper limits have been placed on the 03+ to 01+ and 03+ to 02+ transitions. The measured ρ2(E0) value of the 22+ to 21+ transition in 62Ni has been measured for the first time and found to be one of the largest ρ2(E0) values measured to date in nuclei heavier than Ca. The low-lying states of 62Ni have previously been classified as one- and two-phonon vibrational states based on level energies. The measured electric quadrupole transition strengths are consistent with this interpretation. However as electric monopole transitions are forbidden between states which differ by one phonon number, the simple harmonic quadrupole vibrational picture is not suffcient to explain the large ρ2(E0) value for the 22+ to 21+ transition.

  11. Length-dependent corrosion behavior, Ni2+ release, cytocompatibility, and antibacterial ability of Ni-Ti-O nanopores anodically grown on biomedical NiTi alloy.

    Science.gov (United States)

    Hang, Ruiqiang; Liu, Yanlian; Bai, Long; Zhang, Xiangyu; Huang, Xiaobo; Jia, Husheng; Tang, Bin

    2018-08-01

    In the present work, nickel-titanium-oxygen nanopores with different length (0.55-114 μm) were anodically grown on nearly equiatomic nickel-titanium (NiTi) alloy. Length-dependent corrosion behavior, nickel ion (Ni 2+ ) release, cytocompatibility, and antibacterial ability were investigated by electrochemical, analytical chemistry, and biological methods. The results show constructing nanoporous structure on the NiTi alloy improve its corrosion resistance. However, the anodized samples release more Ni 2+ than that of the bare NiTi alloy, suggesting chemical dissolution of the nanopores rather than electrochemical corrosion governs the Ni 2+ release. In addition, the Ni 2+ release amount increases with nanopore length. The anodized samples show good cytocompatibility when the nanopore length is covers the one (1-11 μm) that the nanopores showing favorable antibacterial ability. Consequently, the nanopores with length in the range of 1-11 μm are promising as coatings of biomedical NiTi alloy for anti-infection, drug delivery, and other desirable applications. Copyright © 2018 Elsevier B.V. All rights reserved.

  12. Effects of P/Ni ratio and Ni content on performance of γ-Al_2O_3-supported nickel phosphides for deoxygenation of methyl laurate to hydrocarbons

    International Nuclear Information System (INIS)

    Zhang, Zhena; Tang, Mingxiao; Chen, Jixiang

    2016-01-01

    Graphical abstract: - Highlights: • The formation of AlPO_4 was unfavorable for that of nickel phosphides. • The phase compositions of nickel phosphide depended on the amount of reduced P. • Catalytic activity was determined by surface Ni site density and catalyst acidity. • HDO pathway was promoted by increasing P/Ni ratio and Ni content. • Nickel phosphide gave much higher carbon yield and lower H_2 consumption than Ni. - Abstract: γ-Al_2O_3-supported nickel phosphides (mNi-Pn) were prepared by the TPR method and tested for the deoxygenation of methyl laurate to hydrocarbons. The effects of the P/Ni ratio (n = 1.0–2.5) and Ni content (m = 5–15 wt.%) in the precursors on their structure and performance were investigated. Ni/γ-Al_2O_3 was also studied for comparison. It was found that the formation of AlPO_4 in the precursor inhibited the reduction of phosphate and so the formation of nickel phosphides. With increasing the P/Ni ratio and Ni content, the Ni, Ni_3P, Ni_1_2P_5 and Ni_2P phases orderly formed, accompanying with the increases of their particle size and the amount of weak acid sites (mainly due to P-OH group), while the CO uptake and the amount of medium strong acid sites (mainly related to Ni sites) reached maximum on 10%Ni-P1.5. In the deoxygenation reaction, compared with Ni/γ-Al_2O_3, the mNi-Pn catalysts showed much lower activities for decarbonylation, C−C hydrogenolysis and methanation due to the ligand and ensemble effects of P. The conversion and the selectivity to n-C11 and n-C12 hydrocarbons achieved maximum on 10%Ni-P 2.0 for the 10%Ni-Pn catalysts and on 8%Ni-P2.0 for the mNi-P2.0 catalysts, while the turnover frequency (TOF) of methyl laurate mainly increased with the P/Ni ratio and Ni content. We propose that TOF was influenced by the nickel phosphide phases, the catalyst acidity and the particle size as well as the synergetic effect between the Ni site and acid site. Again, the hydrodeoxygenation pathway of methyl

  13. Level structure of 60Ni from the 58Ni(α,2p#betta#) reaction

    International Nuclear Information System (INIS)

    Chan, T.U.; Morand, C.; Azgui, F.

    1982-03-01

    The 60 Ni nucleus has been studied via the 58 Ni (α, 2p#betta#) reaction at Esub(α)=32 MeV using in-beam #betta# spectroscopy techniques. High-spin states up to 10 MeV excitation have been established. Among the 5 branches depopulating the Yrast Jsup(π)=7 - state, has been found an E3 transition down to the 4 + state. Comparison with direct reaction results leads to assign very probably the [#betta#fsub(5/2),#betta#gsub(9/2)] 7 - configuration to the Jsup(π)=7 - Yrast state at 5349 keV. Other high-spin states might be accounted for by the breaking of the 56 Ni core

  14. Atomistic simulation of the pinning of edge dislocations in Ni by Ni3Al precipitates

    International Nuclear Information System (INIS)

    Kohler, Christopher; Kizler, Peter; Schmauder, Siegfried

    2005-01-01

    Classical molecular dynamics simulations of the interaction of edge dislocations in Ni with chains of spherical Ni 3 Al precipitates are performed using EAM potentials. The order hardening is investigated at temperature T=0 -bar K by determining the critical resolved shear stresses (CRSSs) for a superdislocation that is dissociated into four partial dislocations. The CRSS is computed as a function of the radius and the distance of the precipitates. It is found that for precipitates with a diameter smaller than the dissociation width of perfect edge dislocation in Ni, the CRSS of the trailing dislocation of the superdislocation is a fraction of about 0.4 of the CRSS of the leading dislocation

  15. Sorption properties of new composite materials suitable for radioanalytical determination of 59-Ni and 63-Ni

    International Nuclear Information System (INIS)

    Fisera, O.; Sebesta, F.

    2006-01-01

    New composite materials for separation and radioanalytical determination of radionickel ( 59, 63 Ni) were prepared and their sorption properties were examined. Chelating agents dimethylglyoxime (DMG) and diphenylglyoxime (DFG) as active components were immobilized in porous matrix of binding polymer polyacrylonitrile (PAN). Sorption properties of these materials were compared with commercial Ni Resin (Eichrom Technologies, USA). Weight distribution ratios, sorption kinetics and operating capacities were investigated during experiments performed. The highest weight distribution ratios were found for the material DFG-PAN. The sorbent DMG-PAN has the highest operating capacity. The fastest kinetics of nickel sorption was determined for the commercial Ni Resin. Elution of nickel with nitric acid solution allows subsequent and direct determination of radionickel by liquid scintillation counting. (author)

  16. Effect of amorphous Mg50Ni50 on hydriding and dehydriding behavior of Mg2Ni alloy

    International Nuclear Information System (INIS)

    Guzman, D.; Ordonez, S.; Fernandez, J.F.; Sanchez, C.; Serafini, D.; Rojas, P.A.; Aguilar, C.; Tapia, P.

    2011-01-01

    Composite Mg 2 Ni (25 wt.%) amorphous Mg 50 Ni 50 was prepared by mechanical milling starting with nanocrystalline Mg 2 Ni and amorphous Mg 50 Ni 50 powders, by using a SPEX 8000 D mill. The morphological and microstructural characterization of the powders was performed via scanning electron microscopy and X-ray diffraction. The hydriding characterization of the composite was performed via a solid gas reaction method in a Sievert's-type apparatus at 363 K under an initial hydrogen pressure of 2 MPa. The dehydriding behavior was studied by differential thermogravimetry. On the basis of the results, it is possible to conclude that amorphous Mg 50 Ni 50 improved the hydriding and dehydriding kinetics of Mg 2 Ni alloy upon cycling. A tentative rationalization of experimental observations is proposed. - Research Highlights: → First study of the hydriding behavior of composite Mg 2 Ni (25 wt.%) amorphous Mg 50 Ni 50 . → Microstructural characterization of composite material using XRD and SEM was obtained. → An improved effect of Mg 50 Ni 50 on the Mg 2 Ni hydriding behavior was verified. → The apparent activation energy for the hydrogen desorption of composite was obtained.

  17. When NiO@Ni Meets WS2 Nanosheet Array: A Highly Efficient and Ultrastable Electrocatalyst for Overall Water Splitting.

    Science.gov (United States)

    Wang, Dewen; Li, Qun; Han, Ce; Xing, Zhicai; Yang, Xiurong

    2018-01-24

    The development of low-cost, high-efficiency, and stable bifunctional electrocatalysts toward the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is of paramount importance for large-scale water splitting. Here, we develop a new strategy for the first design and synthesis of a NiO@Ni decorated WS 2 nanosheet array on carbon cloth (NiO@Ni/WS 2 /CC) composite. This composite serves as a unique three-dimensional (3D) synergistic electrocatalyst that not only combines the intrinsic properties of individual NiO@Ni and WS 2 , but also exhibits significantly improved HER and OER activities when compared to that of pure NiO@Ni and WS 2 . This electrocatalyst possesses Pt-like activity for HER and exhibits better OER performance than that for commercial RuO 2 , as well as demonstrating superior long-term durability in alkaline media. Furthermore, it enables an alkaline electrolyzer with a current density of 10 mA cm -2 at a cell voltage as 1.42 V, which is the lowest one among all reported values to date. The excellent performance is mainly attributed to the unique 3D configuration and multicomponent synergies among NiO, Ni, and WS 2 . Our findings provide a new idea to design advanced bifunctional catalysts for water splitting.

  18. Impact of Interstitial Ni on the Thermoelectric Properties of the Half-Heusler TiNiSn

    Directory of Open Access Journals (Sweden)

    Sonia A. Barczak

    2018-03-01

    Full Text Available TiNiSn is an intensively studied half-Heusler alloy that shows great potential for waste heat recovery. Here, we report on the structures and thermoelectric properties of a series of metal-rich TiNi1+ySn compositions prepared via solid-state reactions and hot pressing. A general relation between the amount of interstitial Ni and lattice parameter is determined from neutron powder diffraction. High-resolution synchrotron X-ray powder diffraction reveals the occurrence of strain broadening upon hot pressing, which is attributed to the metastable arrangement of interstitial Ni. Hall measurements confirm that interstitial Ni causes weak n-type doping and a reduction in carrier mobility, which limits the power factor to 2.5–3 mW m−1 K−2 for these samples. The thermal conductivity was modelled within the Callaway approximation and is quantitively linked to the amount of interstitial Ni, resulting in a predicted value of 12.7 W m−1 K−1 at 323 K for stoichiometric TiNiSn. Interstitial Ni leads to a reduction of the thermal band gap and moves the peak ZT = 0.4 to lower temperatures, thus offering the possibility to engineer a broad ZT plateau. This work adds further insight into the impact of small amounts of interstitial Ni on the thermal and electrical transport of TiNiSn.

  19. Controlled growth of Ni/NiO core–shell nanoparticles: Structure, morphology and tuning of magnetic properties

    Energy Technology Data Exchange (ETDEWEB)

    D’Addato, S., E-mail: sergio.daddato@unimore.it [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Spadaro, M.C. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Luches, P. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Grillo, V. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); CNR-IMEM, Parco Area delle Scienze 37/A, 43100 Parma (Italy); Frabboni, S.; Valeri, S. [CNR-NANO, S3, via G. Campi 213/a, Modena (Italy); Dipartimento FIM, Università di Modena e Reggio Emilia, via G. Campi 213/a, Modena (Italy); Ferretti, A.M.; Capetti, E.; Ponti, A. [CNR-ISTM, Laboratorio di Nanotecnologie, via G. Fantoli 16/15, 20138 Milano (Italy)

    2014-07-01

    We performed a detailed study of Ni/NiO core–shell nanoparticles (NP) obtained with a gas aggregation source. The NP oxide shells were produced by oxidizing the NP with different procedures: deposition in oxygen atmosphere, post-annealing in air, sequential deposition of (a) first NiO layer, (b) Ni NP and (c) third NiO Layer. X-ray photoelectron spectroscopy from Ni 2p core-level gave information about the chemical state of Ni in the core and in the oxide shell, while scanning electron microscopy was used for investigation of the NP morphology. High quality scanning transmission electron microscopy in high angle annular dark field mode data demonstrated core–shell structure also for NiO/Ni NP/NiO samples. Field-cooled/zero-field-cooled magnetization curves and field-cooled isothermal hysteresis cycles at T = 5 K were recorded by a SQUID magnetometer. In this way, the relation between magnetic properties and oxide shell structure was assessed, showing the role played by the control of the formation of oxide on the exchange bias and interparticle magnetic interaction.

  20. When NiO@Ni Meets WS2 Nanosheet Array: A Highly Efficient and Ultrastable Electrocatalyst for Overall Water Splitting

    Directory of Open Access Journals (Sweden)

    Dewen Wang

    2017-12-01

    Full Text Available The development of low-cost, high-efficiency, and stable bifunctional electrocatalysts toward the hydrogen evolution reaction (HER and oxygen evolution reaction (OER is of paramount importance for large-scale water splitting. Here, we develop a new strategy for the first design and synthesis of a NiO@Ni decorated WS2 nanosheet array on carbon cloth (NiO@Ni/WS2/CC composite. This composite serves as a unique three-dimensional (3D synergistic electrocatalyst that not only combines the intrinsic properties of individual NiO@Ni and WS2, but also exhibits significantly improved HER and OER activities when compared to that of pure NiO@Ni and WS2. This electrocatalyst possesses Pt-like activity for HER and exhibits better OER performance than that for commercial RuO2, as well as demonstrating superior long-term durability in alkaline media. Furthermore, it enables an alkaline electrolyzer with a current density of 10 mA cm–2 at a cell voltage as 1.42 V, which is the lowest one among all reported values to date. The excellent performance is mainly attributed to the unique 3D configuration and multicomponent synergies among NiO, Ni, and WS2. Our findings provide a new idea to design advanced bifunctional catalysts for water splitting.

  1. Enhanced optical and electrical properties of Ni inserted ITO/Ni/AZO tri-layer structure for photoelectric applications

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, M. Melvin David; Kim, Hyunki [Department of Electrical Engineering, Incheon National University, Incheon 406772 (Korea, Republic of); Park, Yun Chang [Measurement and Analysis Division, National Nanofab Center (NNFC), Daejeon 305-806 (Korea, Republic of); Kim, Joondong, E-mail: joonkim@incheon.ac.kr [Department of Electrical Engineering, Incheon National University, Incheon 406772 (Korea, Republic of)

    2015-05-15

    Highlights: • Ni-embedding transparent conductor effectively reduces the resistivity. • Ni insertion improves the carrier mobility and collection efficiencies. • ITO/Ni/AZO is effective to improve photo-responses compared to ITO/AZO. - Abstract: A thin Ni layer of 5 nm thickness was deposited in between indium-tin-oxide (ITO) and aluminum-doped-zinc oxide (AZO) layers of 50 nm thickness each. The Ni inserting tri-layer structure (ITO/Ni/AZO) showed lower resistivity of 5.51 × 10{sup −4} Ωcm which is nearly 20 times lesser than 97.9 × 10{sup −4} Ωcm of bilayer structure (ITO/AZO). A thin Ni layer in between ITO and AZO enhanced the carrier concentration, mobility and photoresponse behaviors so that figure of merit (FOM) value of ITO/Ni/AZO device was greater than that of ITO/AZO device. ITO/Ni/AZO structure showed improved quantum efficiencies over a broad range of wavelengths (∼350–950 nm) compared to that of ITO/AZO bilayer structure, resulting in enhanced photoresponses. These results show that the optical, electrical and photoresponse properties of ITO/AZO structure could be enhanced by inserting Ni layer of 5 nm thickness in between ITO and AZO layers.

  2. On the Ni-Ion release rate from surfaces of binary NiTi shape memory alloys

    Science.gov (United States)

    Ševčíková, Jana; Bártková, Denisa; Goldbergová, Monika; Kuběnová, Monika; Čermák, Jiří; Frenzel, Jan; Weiser, Adam; Dlouhý, Antonín

    2018-01-01

    The study is focused on Ni-ion release rates from NiTi surfaces exposed in the cell culture media and human vascular endothelial cell (HUVEC) culture environments. The NiTi surface layers situated in the depth of 70 μm below a NiTi oxide scale are affected by interactions between the NiTi alloys and the bio-environments. The finding was proved with use of inductively coupled plasma mass spectrometry and electron microscopy experiments. As the exclusive factor controlling the Ni-ion release rates was not only thicknesses of the oxide scale, but also the passivation depth, which was two-fold larger. Our experimental data strongly suggested that some other factors, in addition to the Ni concentration in the oxide scale, admittedly hydrogen soaking deep below the oxide scale, must be taken into account in order to rationalize the concentrations of Ni-ions released into the bio-environments. The suggested role of hydrogen as the surface passivation agent is also in line with the fact that the Ni-ion release rates considerably decrease in NiTi samples that were annealed in controlled hydrogen atmospheres prior to bio-environmental exposures.

  3. Controlled growth of Ni/NiO core–shell nanoparticles: Structure, morphology and tuning of magnetic properties

    International Nuclear Information System (INIS)

    D’Addato, S.; Spadaro, M.C.; Luches, P.; Grillo, V.; Frabboni, S.; Valeri, S.; Ferretti, A.M.; Capetti, E.; Ponti, A.

    2014-01-01

    We performed a detailed study of Ni/NiO core–shell nanoparticles (NP) obtained with a gas aggregation source. The NP oxide shells were produced by oxidizing the NP with different procedures: deposition in oxygen atmosphere, post-annealing in air, sequential deposition of (a) first NiO layer, (b) Ni NP and (c) third NiO Layer. X-ray photoelectron spectroscopy from Ni 2p core-level gave information about the chemical state of Ni in the core and in the oxide shell, while scanning electron microscopy was used for investigation of the NP morphology. High quality scanning transmission electron microscopy in high angle annular dark field mode data demonstrated core–shell structure also for NiO/Ni NP/NiO samples. Field-cooled/zero-field-cooled magnetization curves and field-cooled isothermal hysteresis cycles at T = 5 K were recorded by a SQUID magnetometer. In this way, the relation between magnetic properties and oxide shell structure was assessed, showing the role played by the control of the formation of oxide on the exchange bias and interparticle magnetic interaction.

  4. Distorted-wave calculations of electron impact ionisation in the Ni isonuclear sequence

    Energy Technology Data Exchange (ETDEWEB)

    Griffin, D C; Pindzola, M S

    1988-10-14

    Electron impact ionisation cross sections for Ni/sup +/, Ni/sup 3+/, Ni/sup 5+/, Ni/sup 6+/, Ni/sup 7+/, Ni/sup 8+/, Ni/sup 12+/, Ni/sup 14+/, and Ni/sup 16+/ are calculated in the distorted-wave approximation. These calculations include contributions from direct ionisation and inner-shell excitation followed by autoionisation. For Ni/sup 12+/, Ni/sup 14+/, and Ni/sup 16+/ we report not only on ionisation cross sections from the ground states but also from the metastable states of these ions. Experimental cross section measurements exist for all ions reported here, except Ni/sup 16+/. The agreement between experiment and theory is reasonably good and improves with ionisation stage.

  5. NiTiCu/AlN/NiTiCu shape memory thin film heterostructures for vibration damping in MEMS

    Energy Technology Data Exchange (ETDEWEB)

    Kaur, Navjot; Kaur, Davinder, E-mail: dkaurfph@iitr.ernet.in

    2014-03-25

    Highlights: • Fabrication of NiTiCu/AlN/NiTiCu heterostructure using dc/rf magnetron sputtering. • Exhibits highest hardness (38 GPa) and elastic modulus (187 GPa). • Enhanced dissipation of mechanical energy (E{sub d} = 5.7 N J). • High damping capacity (0.052) and figure of merit (∼0.62). • Can be applied for vibration damping in MEMS. -- Abstract: Shape memory alloy (NiTiCu) thin films coupled with piezoelectric AlN layer produce an intelligent material for vibration damping. In the present study pure NiTiCu, NiTiCu/AlN and NiTiCu/AlN/NiTiCu heterostructures have been deposited on Si substrate using magnetron sputtering technique. By the use of the interfaces and shape memory effect provided by NiTiCu layers, the damping capacity can be increased along with increase in stiffness and mechanical hardness. The heterostructures were characterized in terms of structural, electrical, morphological and mechanical properties by X-ray diffraction (XRD), four probe resistivity method, atomic force microscopy, field emission scanning electron microscopy, and nanoindentation. The NiTiCu/AlN/NiTiCu heterostructure exhibit enhanced mechanical and damping properties as compared to NiTiCu/AlN and pure NiTiCu. This enhancement in hardness and damping of the heterostructure could be attributed to the shape memory effect of NiTiCu, intrinsic piezoelectricity of AlN and increased number of interfaces in heterostructure that help in dissipation of mechanical vibrations. The findings of this work provide additional impetus for the application of these heterostructures in emerging fields of nanotechnology and microelectro mechanical (MEMS) devices.

  6. NiTiCu/AlN/NiTiCu shape memory thin film heterostructures for vibration damping in MEMS

    International Nuclear Information System (INIS)

    Kaur, Navjot; Kaur, Davinder

    2014-01-01

    Highlights: • Fabrication of NiTiCu/AlN/NiTiCu heterostructure using dc/rf magnetron sputtering. • Exhibits highest hardness (38 GPa) and elastic modulus (187 GPa). • Enhanced dissipation of mechanical energy (E d = 5.7 N J). • High damping capacity (0.052) and figure of merit (∼0.62). • Can be applied for vibration damping in MEMS. -- Abstract: Shape memory alloy (NiTiCu) thin films coupled with piezoelectric AlN layer produce an intelligent material for vibration damping. In the present study pure NiTiCu, NiTiCu/AlN and NiTiCu/AlN/NiTiCu heterostructures have been deposited on Si substrate using magnetron sputtering technique. By the use of the interfaces and shape memory effect provided by NiTiCu layers, the damping capacity can be increased along with increase in stiffness and mechanical hardness. The heterostructures were characterized in terms of structural, electrical, morphological and mechanical properties by X-ray diffraction (XRD), four probe resistivity method, atomic force microscopy, field emission scanning electron microscopy, and nanoindentation. The NiTiCu/AlN/NiTiCu heterostructure exhibit enhanced mechanical and damping properties as compared to NiTiCu/AlN and pure NiTiCu. This enhancement in hardness and damping of the heterostructure could be attributed to the shape memory effect of NiTiCu, intrinsic piezoelectricity of AlN and increased number of interfaces in heterostructure that help in dissipation of mechanical vibrations. The findings of this work provide additional impetus for the application of these heterostructures in emerging fields of nanotechnology and microelectro mechanical (MEMS) devices

  7. Three-dimensional electrode of Ni/Co layered double hydroxides@NiCo2S4@graphene@Ni foam for supercapacitors with outstanding electrochemical performance

    International Nuclear Information System (INIS)

    Tao, Yan; Ruiyi, Li; Lin, Zhou; Chenyang, Ma; Zaijun, Li

    2015-01-01

    We reported a new strategy for fabricating three-dimensiona electrode of Ni/Co layered double hydroxide@NiCo 2 S 4 @graphene@Ni foam for supercapacitors. The resulting 3D electrode offers a jungle-like architecture. The unique structure creates ultra fast electron transfer and electrolyte transport as well as the maximum utilization rate of the space and the surface. The electrode exhibits a prominent advantage of high specific capacitance, high-current capacitive behaviour and cycle stability. - Highlights: • The study developed a new strategy for fabricating 3D electrode of Ni/Co-LDH@NiCo 2 S 4 @G. • The as-prepared 3D electrode offers a jungle-like architecture. • The unique structure creates an efficient conduction network and high mass loading. • The electrode achieves significantly synergetic effect among different materials. • The electrode exhibits an excellent electrochemical performance for supercapacitors. - ABSTRACT: Great challenge for the fabrication of free-standing three-dimensional electrode still remains to simultaneously achieve high specific capacitance, rate performance and cycle stability. The paper reprted a new three-dimensional (3D) electrode of Ni/Co layered double hydroxide@NiCo 2 S 4 @graphene@Ni foam (Ni/Co-LDH@NiCo 2 S 4 @G) for supercapacitors. The as-prepared 3D electrode offers an unique architecture, which create an efficient conduction network and maximum utilization of space and interface. The graphene acts as well-knit and conductive skin coated on the skeleton of Ni foam for growing NiCo 2 S 4 . The conductive NiCo 2 S 4 array serves as bridge between Ni/Co-LDH and graphene, leading to ultrafast electron transfer and electrolyte transport. A slew of splits and holes existing in the NiCo 2 S 4 array play one role as the ion-reservoir to contain host of electrolyte ions. To evaluate the feasibility of 3D electrode’s application in supercapacitors, the electrochemical performance was investigated by using the three

  8. Energetic Mapping of Ni Catalysts by Detailed Kinetic Modeling

    DEFF Research Database (Denmark)

    Bjørgum, Erlend; Chen, De; Bakken, Mari G.

    2005-01-01

    Temperature-programmed desorption (TPD) of CO has been performed on supported and unsupported nickel catalysts. The unsupported Ni catalyst consists of a Ni(14 13 13) single crystal which has been studied under ultrahigh vacuum conditions. The desorption energy for CO at low CO surface coverage...... was found to be 119 kJ/mol, and the binding energy of C to the Ni(111) surface of the crystal was 703 kJ/mol. The supported catalysts consist of nickel supported on hydrotalcite-like compounds with three different Mg2+/Al3+ ratios. The experimental results show that for the supported Ni catalysts TPD of CO...... precursor seems to result in more steplike sites, kinks, and defects for carbon monoxide dissociation. A detailed kinetic modeling of the TPO results based on elementary reaction steps has been conducted to give an energetic map of supported Ni catalysts. Experimental results from the ideal Ni surface fit...

  9. Synthesis of electroplated {sup 63}Ni source and betavoltaic battery

    Energy Technology Data Exchange (ETDEWEB)

    Uhm, Young Rang; Yoo, Kwon Mo; Choi, Sang Mu; Kim, Jin Joo; Son, Kwang Jae [Radioisotope Research Division, Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-12-15

    Radioisotope (Nuclear) battery using {sup 63}Ni was prepared as beta cell. The electroplated {sup 63}Ni on Ni foil is fabricated, and beta cell and photovoltaic hybrid battery was designed to use at both day and night in space project. A Ni-plating solution is prepared by dissolving metal particles including {sup 62}Ni and {sup 63}Ni from neutron irradiation of (n,γ). Electroplating solution of a chloride bath consists on nickel ions in HCl, H{sub 3}BO{sub 3}, and KOH. The deposition was carried out at current density of 10 mA cm{sup -2}. The prepared beta source was attached on a PN junction and measured I-V properties. The power output at activity of 0.07 mCi and 0.45 mCi were 0.55 pW and 2.69 nW, respectively.

  10. Microstructure and martensitic transformation of Ni-Ti-Pr alloys

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Chunwang [Inner Mongolia University of Technology, College of Science, Hohhot (China); Shanghai Maritime University, College of Arts and Sciences, Shanghai (China); Zhao, Shilei; Jin, Yongjun; Hou, Qingyu [Inner Mongolia University of Technology, College of Science, Hohhot (China); Guo, Shaoqiang [Beihang University, Key Laboratory of Micro-nano Measurement, Manipulation and Physics (Ministry of Education), Department of Physics, Beijing (China)

    2017-09-15

    The effect of Pr addition on the microstructure and martensitic transformation behavior of Ni{sub 50}Ti{sub 50-x}Pr{sub x} (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9) alloys were investigated experimentally. Results show that the microstructures of Ni-Ti-Pr alloys consist of the NiTi matrix and the NiPr precipitate with the Ti solute. The martensitic transformation start temperature decreases gradually with the increase in Pr fraction. The stress around NiPr precipitates is responsible for the decrease in martensitic transformation temperature with the increase in Pr fraction in Ni-Ti-Pr alloys. (orig.)

  11. Near-surface segregation in irradiated Ni3Si

    International Nuclear Information System (INIS)

    Wagner, W.; Rehn, L.E.; Wiedersich, H.

    1982-01-01

    The radiation-induced growth of Ni 3 Si films on the surfaces of Ni(Si) alloys containing = 3 Si phase has been observed. Post-irradiation depth profiling by Auger electron spectroscopy, as well as in situ analysis by high-resolution Rutherford backscattering spectrometry, reveals Si-enrichment at the surfaces of Ni(Si) alloys in excess of stoichiometric Ni 3 Si during irradiation. Thin, near-surface layers with silicon concentrations of 28 to 30 at.% are observed, and even higher Si enrichment is found in the first few atom layers. Transmission electron microscopy and selected area-electron diffraction were employed to characterize these Si-enriched layers. A complex, multiple-spot diffraction pattern is observed superposed on the diffraction pattern of ordered Ni 3 Si. The d-spacings obtained from the extra spots are consistent with those of the orthohexagonal intermetallic compound Ni 5 Si 2 . (author)

  12. Crystal growth velocity in deeply undercooled Ni-Si alloys

    Science.gov (United States)

    Lü, Y. J.

    2012-02-01

    The crystal growth velocity of Ni95Si5 and Ni90Si10 alloys as a function of undercooling is investigated using molecular dynamics simulations. The modified imbedded atom method potential yields the equilibrium liquidus temperatures T L ≈ 1505 and 1387 K for Ni95Si5 and Ni90Si10 alloys, respectively. From the liquidus temperatures down to the deeply undercooled region, the crystal growth velocities of both the alloys rise to the maximum with increasing undercooling and then drop slowly, whereas the athermal growth process presented in elemental Ni is not observed in Ni-Si alloys. Instead, the undercooling dependence of the growth velocity can be well-described by the diffusion-limited model, furthermore, the activation energy associated with the diffusion from melt to interface increases as the concentration increases from 5 to 10 at.% Si, resulting in the remarkable decrease of growth velocity.

  13. Diffusion studies in amorphous NiZr alloys

    International Nuclear Information System (INIS)

    Hahn, H.; Averback, R.S.; Hoshino, K.; Rothman, S.J.

    1987-06-01

    Tracer impurity and self diffusion measurements have been made on amorphous (a-) NiZr alloys using radioactive tracer, Secondary Ion Mass Spectrometry and Rutherford backscattering techniques. The temperature dependence of diffusion in a-NiZr can be represented in the form D = D 0 exp(-Q/kT), with no structural relaxation effects being observed. The mobility of an atom in a-NiZr increased dramatically with decreasing atomic radius of the diffusing atom and also with decreasing Ni content for Ni concentrations below ≅40 at. %. These diffusion characteristics in a-NiZr are remarkably similar to those in α-Zr and α-Ti. These mechanisms assume that Zr and Ti provide a close packed structure, either crystalline or amorphous, through which small atoms diffuse by an interstitial mechanism and large atoms diffuse by a vacancy mechanism. 12 refs., 2 figs., 2 tabs

  14. Thermal variation of magnetization in Ni/V multilayers

    International Nuclear Information System (INIS)

    Benkirane, K.; Elkabil, R.; Hamdoun, A.; Lassri, M.; Abid, M.; Lassri, H.; Krishnan, R.

    2004-01-01

    The magnetic properties of Ni/V multilayers, prepared by the RF sputtering method, have been systematically studied by magnetic measurements. The magnetization decreases with a decrease in Ni layer thickness tNi and the analysis of the results at 5K indicates the presence of a dead Ni layer about 12A thick. The effective anisotropy Keff of Ni/V multilayers is obtained using a torque magnetometer. The interface contribution to the magnetic anisotropy is practically negligible. A spin-wave theory has been used to explain the temperature dependence of the magnetization and the approximate values for the bulk exchange interaction Jb, surface exchange interaction JS, and the interlayer coupling strength JI for various Ni layer thicknesses have been obtained

  15. Synthesis of electroplated 63Ni source and betavoltaic battery

    International Nuclear Information System (INIS)

    Uhm, Young Rang; Yoo, Kwon Mo; Choi, Sang Mu; Kim, Jin Joo; Son, Kwang Jae

    2015-01-01

    Radioisotope (Nuclear) battery using 63 Ni was prepared as beta cell. The electroplated 63 Ni on Ni foil is fabricated, and beta cell and photovoltaic hybrid battery was designed to use at both day and night in space project. A Ni-plating solution is prepared by dissolving metal particles including 62 Ni and 63 Ni from neutron irradiation of (n,γ). Electroplating solution of a chloride bath consists on nickel ions in HCl, H 3 BO 3 , and KOH. The deposition was carried out at current density of 10 mA cm -2 . The prepared beta source was attached on a PN junction and measured I-V properties. The power output at activity of 0.07 mCi and 0.45 mCi were 0.55 pW and 2.69 nW, respectively

  16. Equilibrium relationships in the system Ni-U-O

    International Nuclear Information System (INIS)

    Mansour, N.A.L.

    1980-01-01

    Phase relationships were established in air and in oxygen. Mixtures of NiO and U 3 O 8 oxidize to NiUO 4 . The results of analysis of NiUO 4 were identical to those previously published for NiU 3 O 10 . The uranate dissociates to NiO and U 3 O 8 at a temperature higher than that of their oxidation back to the uranate on cooling because of the difficulty of oxygen diffusion and uranate nucleation. Accordingly, dissociation temperature was taken to represent equilibrium and was used to calculate roughly ΔH and ΔS for the reaction of dissociation. In presence of NiO, U 3 O 8 melts partially and does not dissociate to the lower oxide. (orig.) [de

  17. Coercivity scaling in antidot lattices in Fe, Ni, and NiFe thin films

    Energy Technology Data Exchange (ETDEWEB)

    Gräfe, Joachim, E-mail: graefe@is.mpg.de; Schütz, Gisela; Goering, Eberhard J., E-mail: goering@is.mpg.de

    2016-12-01

    Antidot lattices can be used to artificially engineer magnetic properties in thin films, however, a conclusive model that describes the coercivity enhancement in this class of magnetic nano-structures has so far not been found. We prepared Fe, Ni, and NiFe thin films and patterned each with 21 square antidot lattices with different geometric parameters and measured their hysteretic behavior. On the basis of this extensive dataset we are able to provide a model that can describe both the coercivity scaling over a wide range of geometric lattice parameters and the influence of different materials.

  18. Sideward flow of K+ in Ru+Ru and Ni+Ni reactions sat SIS energies

    International Nuclear Information System (INIS)

    Crochet, P.; Herrmann, N.; Wisniewski, K.

    2000-01-01

    Experimental data on K + and proton sideward flow measured with the FOPI detector at SIS/GSI in the reactions Ru+Ru at 1.69 A GeV and Ni+Ni at 1.93 A GeV are presented. The K + sideward flow is found to be anti-correlated (correlated) with the one of protons at low (high) transverse momenta. When compared to the predictions of a transport model, the data favour the existence of an in-medium repulsive K + -nucleon potential. (author)

  19. Shape and size effects on layered Ni/PZT/Ni composites magnetoelectric performance

    Energy Technology Data Exchange (ETDEWEB)

    Pan, D A; Zhang, S G; Qiao, L J [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Volinsky, Alex A [Department of Mechanical Engineering, University of South Florida, Tampa FL 33620 (United States)], E-mail: lqiao@ustb.edu.cn

    2008-09-07

    This paper presents the magnetoelectric (ME) effect in trilayered Ni/PZT/Ni composites which is related to their size and shape. The ME composites with the same interfacial areas but different geometrical shapes have different ME voltage coefficients. Longitudinal resonant modes in the rectangular and triangular trilayered ME composites were studied. One should choose optimized size, shape and working frequency of the ME composites in order to gain the maximum ME effect. This study plays a guiding role for trilayered ME composites design for real applications. (fast track communication)

  20. Microstructural evolution of neutron-irradiated Ni-Si and Ni-Al alloys

    Science.gov (United States)

    Takahashi, H.; Garner, F. A.

    1992-10-01

    Additions of silicon and aluminum suppress the neutron-induced swelling of pure nickel but to different degrees. Silicon is much more effective initially when compared to aluminum on a per atom basis but silicon exhibits a nonmonotonic influence on swelling with increasing concentration. Silicon tends to segregate toward grain boundaries while aluminum segregates away from these boundaries. Whereas the formation of the Ni 3Si phase is frequently observed in charged particle irradiation experiments conducted at much higher displacement rates, it did not occur during neutron irradiation in this study. Precipitation also did not occur in Ni-5Al during neutron irradiation, nor has it been reported to occur during ion irradiation.

  1. Strengthening by ordered precipitates in a Ni--Ni4Mo system

    International Nuclear Information System (INIS)

    Goodrum, J.W.; LeFevre, B.G.

    1977-01-01

    The strength characteristics and microstructures of aged Ni-Mo alloys containing ordered (Ni 4 Mo) precipitates were studied as a function of aging time and temperature. It was found that 17 at. percent Mo alloy aged at 750 0 C produced a uniform dispersion of cuboidal β precipitates which coarsened with time producing a gradual increase in flow stress. The flow stress increment was found to vary in qualitative agreement with both order strengthening and coherency strain models. Both these models give over-estimates of the strengthening increment. A negative dependence of flow stress on temperature is attributed to coherency strain contributions

  2. The nature of strong Brønsted acidity of Ni-SMM clay

    NARCIS (Netherlands)

    Yue, C.; Liu, C.; Mezari, B.; Brückner, A.; Pidko, E.A.; Rigutto, M.S.; Hensen, E.J.M.

    2016-01-01

    The origin of the high Brønsted acidity of Ni-SMM (Ni-substituted synthetic mica-montmorillonite; beidellite structure) clays was investigated. Ni-SMM clays with varying F content, SMM with F and Ni-SMM without F in the structure were synthesized under hydrothermal conditions. Ni-SMM clays with

  3. Los niños y los videojuegos

    OpenAIRE

    Orrego Gaviria, Jaime; Fundación Valle de Lili

    2007-01-01

    Los niños y los videojuegos / Efectos perjudiciales de la utilización de los videojuegos por los niños y adolescentes/ Efectos benéficos de la de la utilización de los videojuegos por los niños y adolescentes/ Recomendaciones para favorecer el uso adecuado/ Sistema de clasificación de los videojuegos

  4. Electrochemical Characterization of Ni/(Sc)YSZ Electrodes

    DEFF Research Database (Denmark)

    Ramos, Tania; Thydén, Karl Tor Sune; Mogensen, Mogens Bjerg

    2010-01-01

    Investigations of Ni/(Sc)YSZ cermets for solid oxide cells (SOCs) were performed by electrochemical impedance spectroscopy (EIS), under varying experimental conditions and upon redox cycling, using three different designs of symmetric cells. The deconvolution and fitting of the obtained impedance...... parameters. Initial degradation results for both Ni/ScYSZ and Ni/YSZ based anodes under very high steam content are also reported. ©2010 COPYRIGHT ECS - The Electrochemical Society...

  5. Irradiation-induced precipitation in Ni--Si alloys

    International Nuclear Information System (INIS)

    Barbu, A.; Ardell, A.J.

    1975-07-01

    The microstructures of Ni + ion-irradiated Ni--Si solid-solution alloys, containing 2, 4, 6 and 8 at. percent Si were investigated as a function of dose, dose-rate, and temperature. Results of transmission electron microscopy and other data show the precipitation of γ' (Ni 3 Si) in all samples irradiated at 500 0 C. Characteristics of the precipitates are described and a mechanism for their formation is suggested. (U.S.)

  6. Ni-YSZ graded coatings produced by dipping

    International Nuclear Information System (INIS)

    Ferrari, B.; Moreno, R.

    2004-01-01

    A new colloidal processing route for the shaping of a graded Ni-YSZ composite for applications in SOFC devices is described. A Ni foil is coated by Ni/YSZ layers by dipping in aqueous suspensions with an organic binder. Behind the metal-ceramic layers introduced to improve adhesion, an outer thin layer of nanosized YSZ is formed by electrophoretic deposition. (Abstract Copyright [2004], Wiley Periodicals, Inc.)

  7. Low-field spin dynamics of Cr7Ni and Cr7Ni-Cu-Cr7Ni molecular rings as detected by μsR

    OpenAIRE

    Sanna, S.; Arosio, P.; Bordonali, L.; Adelnia, F.; Mariani, M.; Garlatti, E.; Baines, C.; Amato, A.; Sabareesh, K. P.V.; Timco, G.; Winpenny, R. E.P.; Blundell, S. J.; Lascialfari, A.

    2017-01-01

    Muon spin rotation measurements were used to investigate the spin dynamics of heterometallic Cr7Ni and Cr7Ni-Cu-Cr7Ni molecular clusters. In Cr7Ni the magnetic ions are arranged in a quasiplanar ring and interact via an antiferromagnetic exchange coupling constant J, while Cr7Ni-Cu-Cr7Ni is composed of two Cr7Ni linked by a bridging moiety containing one Cu ion, that induces an inter-ring ferromagnetic interaction J ≪ J. The longitudinal muon relaxation rate λ collected at low magnetic fields...

  8. Comparison of three Ni-Hard I alloys

    Energy Technology Data Exchange (ETDEWEB)

    Dogan, Omer N.; Hawk, Jeffrey A.; Rice, J. (Texaloy Foundry Co., Inc., Floresville, Texas)

    2004-09-01

    This report documents the results of an investigation which was undertaken to reveal the similarities and differences in the mechanical properties and microstructural characteristics of three Ni-Hard I alloys. One alloy (B1) is ASTM A532 class IA Ni-Hard containing 4.2 wt. pct. Ni. The second alloy (B2) is similar to B1 but higher in Cr, Si, and Mo. The third alloy (T1) also falls in the same ASTM specification, but it contains 3.3 wt. pct. Ni. The alloys were evaluated in both as-cast and stress-relieved conditions except for B2, which was evaluated in the stress-relieved condition only. While the matrix of the high Ni alloys is composed of austenite and martensite in both conditions, the matrix of the low Ni alloy consists of a considerable amount of bainite, in addition to the martensite and the retained austenite in as cast condition, and primarily bainite, with some retained austenite, in the stress relieved condition. It was found that the stress relieving treatment does not change the tensile strength of the high Ni alloy. Both the as cast and stress relieved high Ni alloys had a tensile strength of about 350 MPa. On the other hand, the tensile strength of the low Ni alloy increased from 340 MPa to 452 MPa with the stress relieving treatment. There was no significant difference in the wear resistance of these alloys in both as-cast and stressrelieved conditions.

  9. An investigation of the oxidized Ni/InAs interface

    International Nuclear Information System (INIS)

    Venter, A.; Botha, J.R.; Swart, H.C.; Naidoo, S.; Olivier, E.J.

    2009-01-01

    Ni was resistively deposited onto bulk InAs and subsequently oxidized in an O 2 atmosphere. The anneal temperature and time were 450 deg. C and 2.5 h, respectively. X-ray diffraction of the oxidized Ni/InAs sample revealed the formation of In 3 Ni 2 and In 2 O 3 on the front suggesting inter diffusion of In, Ni and O. NiO was not detected by X-ray diffraction. In a preliminary study, using glass as a substrate, NiO readily formed when using these oxidation parameters. Conductivity measurements of the oxidized Ni/InAs surface revealed a conducting front and insulating rear surface while TEM of the Ni/InAs interface revealed an intermediate amorphous diffusion zone between the 'oxidized' Ni layer and the bulk InAs. A closer investigation of the intermediate layer supports the X-ray diffraction results, suggesting compound formation due to diffusion of oxygen and nickel into the substrate, and out-diffusion of In and As from the bulk of the sample. AES was used to further elucidate these results.

  10. An investigation of the oxidized Ni/InAs interface

    Energy Technology Data Exchange (ETDEWEB)

    Venter, A., E-mail: andre.venter@nmmu.ac.z [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa); Botha, J.R. [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa); Swart, H.C. [Department of Physics, University of the Free State, PO Box 339, Bloemfontein 9300 (South Africa); Naidoo, S.; Olivier, E.J. [Department of Physics, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa)

    2009-12-01

    Ni was resistively deposited onto bulk InAs and subsequently oxidized in an O{sub 2} atmosphere. The anneal temperature and time were 450 deg. C and 2.5 h, respectively. X-ray diffraction of the oxidized Ni/InAs sample revealed the formation of In{sub 3}Ni{sub 2} and In{sub 2}O{sub 3} on the front suggesting inter diffusion of In, Ni and O. NiO was not detected by X-ray diffraction. In a preliminary study, using glass as a substrate, NiO readily formed when using these oxidation parameters. Conductivity measurements of the oxidized Ni/InAs surface revealed a conducting front and insulating rear surface while TEM of the Ni/InAs interface revealed an intermediate amorphous diffusion zone between the 'oxidized' Ni layer and the bulk InAs. A closer investigation of the intermediate layer supports the X-ray diffraction results, suggesting compound formation due to diffusion of oxygen and nickel into the substrate, and out-diffusion of In and As from the bulk of the sample. AES was used to further elucidate these results.

  11. Oxidation of hydrogen peroxide by [Ni III (cyclam)

    Indian Academy of Sciences (India)

    The kinetics of oxidation of H2O2 by [NiIII(cyclam)]3+, [NiIIIL1], was studied in aqueous acidic media at 25°C and I = 0.5M (NaClO4). The [NiIIIL1] to [NiIIL1] reduction was found to be fast in the presence of Cu(II) ion than the oxidation of the cyclam ligand by ·OH. The rate constant showed an inverse acid dependence on H+ ...

  12. Level density of radioactive doubly-magic nucleus 56Ni

    International Nuclear Information System (INIS)

    Santhosh Kumar, S.; Rengaiyan, R.; Victor Babu, A.; Preetha, P.

    2012-01-01

    In this work the single particle energies are obtained by diagonalising the Nilsson Hamiltonian in the cylindrical basis and are generated up to N =11 shells for the isotopes of Ni from A = 48-70, emphasizing the three magic nuclei viz, 48 Ni, 56 Ni and 68 Ni. The statistical quantities like excitation energy, level density parameter and nuclear level density which play the important roles in the nuclear structure and nuclear reactions can be calculated theoretically by means of the Statistical or Partition function method. Hence the statistical model approach is followed to probe the dynamical properties of the nucleus in the microscopic level

  13. CVD Graphene/Ni Interface Evolution in Sulfuric Electrolyte

    DEFF Research Database (Denmark)

    Yivlialin, Rossella; Bussetti, Gianlorenzo; Duò, Lamberto

    2018-01-01

    Systems comprising single and multilayer graphene deposited on metals and immersed in acid environments have been investigated, with the aim of elucidating the mechanisms involved, for instance, in hydrogen production or metal protection from corrosion. In this work, a relevant system, namely...... chemical vapor deposited (CVD) multilayer graphene/Ni (MLGr/Ni), is studied when immersed in a diluted sulfuric electrolyte. The MLGr/Ni electrochemical and morphological properties are studied in situ and interpreted in light of the highly oriented pyrolytic graphite (HOPG) electrode behavior, when...... immersed in the same electrolyte. Following this interpretative framework, the dominant role of the Ni substrate in hydrogen production is clarified....

  14. Design and fabrication of Ni nanowires having periodically hollow nanostructures

    Science.gov (United States)

    Sada, Takao; Fujigaya, Tsuyohiko; Nakashima, Naotoshi

    2014-09-01

    We propose a concept for the design and fabrication of metal nanowires having periodically hollow nanostructures inside the pores of an anodic aluminum oxide (AAO) membrane using a sacrificial metal. In this study, nickel (Ni) and silver (Ag) were used as the base metal and the sacrificial metal, respectively. Alternating an applied potential between -0.4 and -1.0 V provided alternatively deposited Ni and Ag segments in a Ni-Ag `barcode' nanowire with a diameter of 18 or 35 nm. After etching away the Ag segments, we fabricated Ni nanowires with nanopores of 12 +/- 5.3 nm. Such nanostructure formation is explained by the formation of a Ni shell layer over the surface of the Ag segments due to the strong affinity of Ni2+ for the interior surfaces of AAO. The Ni shell layer allows the Ni segments to remain even after dissolution of the Ag segments. Because the electroplating conditions can be easily controlled, we could carefully adjust the size and pitch of the periodically hollow nanospaces. We also describe a method for the fabrication of Ni nanorods by forming an Ag shell instead of a Ni shell on the Ni-Ag barcode nanowire, in which the interior of the AAO surfaces was modified with a compound bearing a thiol group prior to electroplating.We propose a concept for the design and fabrication of metal nanowires having periodically hollow nanostructures inside the pores of an anodic aluminum oxide (AAO) membrane using a sacrificial metal. In this study, nickel (Ni) and silver (Ag) were used as the base metal and the sacrificial metal, respectively. Alternating an applied potential between -0.4 and -1.0 V provided alternatively deposited Ni and Ag segments in a Ni-Ag `barcode' nanowire with a diameter of 18 or 35 nm. After etching away the Ag segments, we fabricated Ni nanowires with nanopores of 12 +/- 5.3 nm. Such nanostructure formation is explained by the formation of a Ni shell layer over the surface of the Ag segments due to the strong affinity of Ni2+ for the

  15. Comparative study of NiW, NiMo and MoW prepared by mechanical alloying

    International Nuclear Information System (INIS)

    Gonzalez, G.; Sagarzazu, A.; Villalba, R.; Ochoa, J.

    2007-01-01

    The present work concern the amorphisation process induced by mechanical alloying in the NiW, NiMo and MoW systems. The alloys chosen combine a group of transition elements varying from very similar atomic radius and electronic valences (MoW) to different ones (NiW and NiMo). The three systems achieved an amorphous state after 50 h of milling. The mechanism of amorphisation proposed for NiW and NiMo was the combined effect of an excess concentration of the solute atoms entering into the structure of one of the elements and a critical concentration of defects. Continuous formation of an amorphous phase at the interface of the crystalline phase was observed during the process. MoW seems to amorphize by continuous reduction of grain size down to a critical value where the amorphisation takes place

  16. The irradiation hardening of Ni-Mo-Cr and Ni-W-Cr alloy under Xe26+ ion irradiation

    Science.gov (United States)

    Chen, Huaican; Hai, Yang; Liu, Renduo; Jiang, Li; Ye, Xiang-xi; Li, Jianjian; Xue, Wandong; Wang, Wanxia; Tang, Ming; Yan, Long; Yin, Wen; Zhou, Xingtai

    2018-04-01

    The irradiation hardening of Ni-Mo-Cr and Ni-W-Cr alloy was investigated. 7 MeV Xe26+ ion irradiation was performed at room temperature and 650 °C with peak damage dose from 0.05 to 10 dpa. With the increase of damage dose, the hardness of Ni-Mo-Cr and Ni-W-Cr alloy increases, and reaches saturation at damage dose ≥1 dpa. Moreover, the damage dose dependence of hardness in both alloys can be described by the Makin and Minter's equation, where the effective critical volume of obstacles can be used to represent irradiation hardening resistance of the alloys. Our results also show that Ni-W-Cr alloy has better irradiation hardening resistance than Ni-Mo-Cr alloy. This is ascribed to the fact that the W, instead of Mo in the alloy, can suppress the formation of defects under ion irradiation.

  17. Flexible bottom-emitting white organic light-emitting diodes with semitransparent Ni/Ag/Ni anode.

    Science.gov (United States)

    Koo, Ja-Ryong; Lee, Seok Jae; Lee, Ho Won; Lee, Dong Hyung; Yang, Hyung Jin; Kim, Woo Young; Kim, Young Kwan

    2013-05-06

    We fabricated a flexible bottom-emitting white organic light-emitting diode (BEWOLED) with a structure of PET/Ni/Ag/Ni (3/6/3 nm)/ NPB (50 nm)/mCP (10 nm)/7% FIrpic:mCP (10 nm)/3% Ir(pq)(2) acac:TPBi (5 nm)/7% FIrpic:TPBi (5 nm)/TPBi (10 nm)/Liq (2 nm)/ Al (100 nm). To improve the performance of the BEWOLED, a multilayered metal stack anode of Ni/Ag/Ni treated with oxygen plasma for 60 sec was introduced into the OLED devices. The Ni/Ag/Ni anode effectively enhanced the probability of hole-electron recombination due to an efficient hole injection into and charge balance in an emitting layer. By comparing with a reference WOLED using ITO on glass, it is verified that the flexible BEWOLED showed a similar or better electroluminescence (EL) performance.

  18. Hydride Reactivity of Ni-II-X-Ni-II Entities : Mixed-Valent Hydrido Complexes and Reversible Metal Reduction

    NARCIS (Netherlands)

    Gehring, Henrike; Metzinger, Ramona; Herwig, Christian; Intemann, Julia; Harder, Sjoerd; Limberg, Christian

    After the lithiation of PYR-H2 (PYR2-=[{NC(Me)C(H)C(Me)NC6H3(iPr)2}2(C5H3N)]2-), which is the precursor of an expanded beta-diketiminato ligand system with two binding pockets, its reaction with [NiBr2(dme)] led to a dinuclear nickel(II)bromide complex, [(PYR)Ni(mu-Br)NiBr] (1). The bridging bromide

  19. Studies on the valence electronic structure of Fe and Ni in FexNi1−x ...

    Indian Academy of Sciences (India)

    structure of Fe and Ni in various Fex Ni1−x alloys. Since Kβ-to-Kα X-ray intensity ratio has been reported [2–7] to be a sensitive physical parameter to investigate the changes in the valence electronic structure of 3d-transition metals [2], we have undertaken the study of the valence electronic structure of Fe and Ni in the Fex ...

  20. Effects of Ni content on nanocrystalline Fe–Co–Ni ternary alloys synthesized by a chemical reduction method

    Energy Technology Data Exchange (ETDEWEB)

    Chokprasombat, Komkrich, E-mail: komkrich28@gmail.com [Department of Physics, Faculty of Science, Thaksin University, Phatthalung 93210 Thailand (Thailand); Pinitsoontorn, Supree [Integrated Nanotechnology Research Center, Department of Physics, Faculty of Science, Khon Kaen University, Khon Kaen 40002 Thailand (Thailand); Maensiri, Santi [School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000 Thailand (Thailand)

    2016-05-01

    Magnetic properties of Fe–Co–Ni ternary alloys could be altered by changing of the particle size, elemental compositions, and crystalline structures. In this work, Fe{sub 50}Co{sub 50−x}Ni{sub x} nanoparticles (x=10, 20, 40, and 50) were prepared by the novel chemical reduction process. Hydrazine monohydrate was used as a reducing agent under the concentrated basic condition with the presence of poly(vinylpyrrolidone). We found that the nanoparticles were composed of Fe, Co and Ni with compositions according to the molar ratio of the metal sources. Interestingly, the particles were well-crystalline at the as-prepared state without post-annealing at high temperature. Increasing Ni content resulted in phase transformation from body centered cubic (bcc) to face centered cubic (fcc). For the fcc phase, the average particle size decreased when increased the Ni content; the Fe{sub 50}Ni{sub 50} nanoparticles had the smallest average size with the narrowest size distribution. In additions, the particles exhibited ferromagnetic properties at room temperature with the coercivities higher than 300 Oe, and the saturation magnetiation decreased with increasing Ni content. These results suggest that the structural and magnetic properties of Fe–Co–Ni alloys could be adjusted by varying the Ni content. - Highlights: • We prepared nanocrystalline Fe–Co–Ni alloys by a novel chemical reduction process. • Elemental compositions could be well controlled by the molar ratio of metal sources. • Particle size and magnetic properties clearly depended on the Ni contents. • Fe{sub 50}Co{sub 10}Ni{sub 40} exhibited high saturation magnetization of 126.3 emu/g.