Sample records for rutenium tanji shokubai

  1. Hydrogenation of heteroaromatics by high pressure DTA techniques. 3; Koatsu DTA ho ni yoru hokozoku kagobutsu no suisoka (rutenium tanji shokubai ni yoru kakusuisoka datsu hetero hanno)

    Yamamoto, M.; Yoshida, T. [Hokkaido National Industrial Research Institute, Sapporo (Japan); Kotanigawa, T. [Japan International Cooperation Agency, Tokyo (Japan)


    Ring-opening of heteroaromatics and heteroatom-removal reaction were studied experimentally using the acidic catalyst containing phosphoric acid for improvement of an upgrading method of coal derived oils. In experiment, some Ru-carrying metal oxide catalysts such as RMZ, RML and RMN catalyst, and MNP catalyst containing phosphoric acid were used as specimens. Nuclear hydrogenation reaction and hydro-denitrogenation reaction of dibenzothiophene and carbazole were compared with each other. The experimental results are as follows. Both RMN and RMNP catalysts offer a superior selectivity in nuclear hydrogenation reaction and hydro-denitrogenation reaction of carbazole. Although both catalysts offer an extremely high nuclear hydrogenation activity at 360{degree}C, these offer the high selectivity of denitrogenation products at 430{degree}C. In comparison of the activities of MN and MNP catalysts with the same Mn2O3:NiO ratio, MNP catalyst offers the higher denitrogenation activity than MN catalyst at 430{degree}C. 1 ref., 3 tabs.

  2. Influences of species of metals and supports on the hydrogenation activity of carbon-supported metal sulfides catalysts; Tanso biryushi tanji shokubai no suisoka kassei ni taisuru kassei kinzoku oyobi tantaishu no eikyo

    Sakanishi, K.; Hasuo, H.; Taniguchi, H.; Nagamatsu, T.; Mochida, I. [Kyushu University, Fukuoka (Japan). Institute of Advanced Material Study


    In order to design catalysts suitable for primary liquefaction stage and secondary upgrading stage respectively in the multi-stage liquefaction process, various carbon-supported catalysts were prepared. Catalytic activities of them were investigated for the hydrogenation of 1-methylnaphthalene, to discuss the influences of metals and carbon species on the catalytic activity. Various water soluble and oil soluble Mo and Ni salts were used for NiMo supported catalysts. Among various carbon supports, Ketjen Black (KB) was effective for preparing the catalyst showing the most excellent hydrogenation activity. The KB and Black Pearl 2000 (BP2000) showing high hydrogenation activity were fine particles having high specific surface area more than 1000 m{sup 2}/g and primary particle diameter around 30 nm. This was inferred to contribute to the high dispersion support of active metals. Since such fine particles of carbon exhibited hydrophobic surface, they were suitable for preparing catalysts from the methanol-soluble metals. Although Ni and Mo added iron-based catalysts provided lower aromatic hydrogenation activity, they exhibited liquefaction activity competing with the NiMo/KB catalyst. 3 refs., 1 fig., 3 tabs.

  3. Latent catalyst; Senzaisei shokubai



    Epoxy resin, an important function material to support such main industries as electric and electronic devices, automobiles, civil engineering, and building construction, is demanded of development of single liquid type resin having excellent quick hardening performance and storage stability. This requirement comes from environmental problems with an intention of saving energies and reducing resin wastes. The Company, using freely its independent phase separation technology that controls molecular structure of catalysts, developed a latent catalyst having excellent storage stability and high-temperature quick hardening performance. Its major features may be summarized as follows: (1) excellent storage stability at room temperature keeping the product stable for 2.5 months or longer (2 days in conventional products); (2) quick hardening performance hardening the resin in seven seconds at 150 degrees C (equivalent to conventional products); and (3) excellent insulation performance of hardened resin at 140 degrees C of 7 times 10 {sup 13} (ohm) (center dot) cm (2 times 10 {sup 12} (ohm) (center dot) cm in conventional products) (translated by NEDO)

  4. Photo catalyst; Ko shokubai



    While titanium oxide is excited by the light, electrons of titanium oxide are taken away by the light energy to form positive holes. Water will be decomposed into hydrogen ion and hydroxy radical (OH) by these positive holes. This hydroxy radical is a strong reactive substance called active oxygen, it decomposes organisms. Besides this photo- catalyst function, the titanium oxide can also make surface of a substance superhydrophilic. The super hydrophilicity results in not forming water drops on the glass surface but spreading all over the surface to prevent a covering of fog on the glass surface. The published patents concerning the photo catalysts were 593 from Jan. 1998 to Jan. 1999. The applicant order is the first TOTO 143, the second Daikin Industry 19, the third Toshiba Raitech, Nitto Denko, Hitachi 17 respectively. (NEDO)

  5. Studies of structure change of iron sulfates and its catalysis; Ryusantetsukei shokubai no kozo henka to sono shokubai sayo

    Ogata, E.; Horie, K. [The University of Tokyo, Tokyo (Japan). Faculty of Engineering; Nishijima, A. [National Institute of Materials and Chemical Research, Tsukuba (Japan)


    Since a huge amount of coal containing inorganic ash is treated for the commercial hydroliquefaction process, cheap catalysts widely distributing on the earth with large reserves are desired rather than expensive catalysts. This paper describes the effects of addition of sulfur on the catalysis of iron sulfates during the hydroconversion of 1-methylnaphthalene (1-MN). Reactions of 1-MN were conducted at the same charging amount of iron in the reaction system. Sulfur was directly added in the reaction system using ferrous sulfate (FeSO4) as precursor. Consequently, it was found that FeSO4 provides lower but similar catalytic activity to the synthetic pyrite catalyst prepared through the complex processes with the precise control. Thus, it was revealed that high performance pyrrhotite (Fe(1-x)S) catalyst can be prepared for the hydrogenation of aromatic-rings by adding solid sulfur into the reaction system using commercial reagent, FeSO4 as a precursor of the catalyst. 9 figs.

  6. Change in catalyst properties during coal liquefaction; Kokoritsu sekitan ekika shokubai no kaihatsu (Hanno no shinko ni tomonau shokubai seijo no henka). 1

    Koyama, T.; Sato, K.; Kaneko, T.; Shimasaki, K. [Nippon Brown Coal Liquefaction Co. Ltd., Tokyo (Japan)


    The purpose of this study is to prevent the deactivation of catalysts recycled in the 0.1 t/d bench scale unit (BSU). Catalysts recovered during reactions in the BSU and after reactions in the 5-liter autoclave were analyzed, to investigate the influences of the reaction condition on the property and activity of catalysts. Were used {gamma}-iron oxyhydroxide ({gamma}-FeOOH), {alpha}-iron oxyhydroxide ({alpha}-FeOOH), and natural pyrite (FeS2) as catalysts. At the S/Fe atomic ration of 1.2 under the BSU reaction condition, troilite was more easily formed from {gamma}-FeOOH compared with pyrite and {alpha}-FeOOH. As the reaction proceeded through the first, second, and third reactors, the crystal size increased, the pyrrhotite content decreased, and the troilite content increased. Deactivation due to the formation of troilite was irreversible. At the S/Fe of 3.0, however, both the formation of troilite and the crystal growth of pyrrhotite were not observed. It was found that the deactivation of catalysts can be remarkably suppressed. 5 refs., 6 figs., 1 tab.

  7. Mechanism of pyrrhotite formation from ferric oxyhydroxide catalyst; Kokoritsu sekitan ekika shokubai no kaihatsu (Okishi suisankatetsu shokubai karano pyrrhotite seisei kyodo)

    Tazawa, K.; Koyama, T.; Kaneko, T.; Shimasaki, K. [Nippon Brown Coal Liquefaction Co. Ltd., Tokyo (Japan)


    It is thought that iron-based catalysts for coal liquefaction exercise their catalytic activity by forming pyrrhotite (Fe(1-x)S). However, there are still a lot of unknown problems remained concerning the formation and agglomeration behaviors of pyrrhotite. These make a difficulty for improving the activity of iron-based catalysts. In this study, sulfiding behaviors of {alpha}-iron oxyhydroxide ({alpha}-FeOOH) and {gamma}-iron oxyhydroxide ({gamma}-FeOOH) were investigated to reveal the formation and agglomeration behaviors of pyrrhotite. It was found that pyrrhotite was easily converted from ferric oxyhydroxide catalysts having large specific surface areas at the sulfiding temperature below 250{degree}C, and fine crystallites of pyrrhotite were formed at the initial stage of sulfiding. Crystal growth of pyrrhotite at the sulfiding temperature over 350{degree}C depended on the catalyst forms. It was also found that smaller crystallites of pyrrhotite were formed from {gamma}-FeOOH than from {alpha}-FeOOH and amorphous iron oxyhydroxide. 5 refs., 7 figs., 1 tab.

  8. Idea of environmental catalyst and its application; Kankyo shokubai no hasso to sono riyo

    Inumaru, K. [The University of Tokyo, Tokyo (Japan)


    The catalyst creating environmental conservation and comfortable environment is generally named an `environmental catalyst (EC).` EC is roughly classified into direct and indirect type ECs. Purification catalysts for automobile exhaust gas, and catalysts for chemical production process are under investigation as direct and indirect type ECs, respectively. The catalyst was found which can remove NOx under the coexistence of oxygen by using hydrocarbon as reductant. In addition, the practical exhaust gas purification catalyst was also developed for lean-burn engines by combining noble metal catalysts with NOx absorbing materials or zeolite superior in reductant adsorbing power. {epsilon}-caprolactam as raw material of nylon 6 is synthesized from cyclohexanoneoxime through Beckmann` rearrangement reaction. Zeolite system solid catalysts using no ammonia are under investigation. An environment-friendly synthesis method using not phosgene but catalyst was proposed for production of dimethyl carbonate. How to utilize catalysts for global material circulation remains unsolved for the future study. 5 refs.

  9. Catalytic activity of pyrite for coal liquefaction reaction; Tennen pyrite no shokubai seino ni kansuru kento

    Hirano, K.; Kozu, M.; Okada, T.; Kobayashi, M. [Nippon Coal Oil Co. Ltd., Tokyo (Japan)


    Since natural pyrite is easy to obtain and cheap as coal liquefaction catalyst, it is to be used for the 150 t/d scale NEDOL process bituminous coal liquefaction pilot plant. NEDO and NCOL have investigated the improvement of catalytic activity of pulverized natural pyrite for enhancing performance and economy of the NEDOL process. In this study, coal liquefaction tests were conducted using natural pyrite catalyst pulverized by dry-type bowl mill under nitrogen atmosphere. Mechanism of catalytic reaction of the natural pyrite was discussed from relations between properties of the catalyst and liquefaction product. The natural pyrite provided an activity to transfer gaseous hydrogen into the liquefaction product. It was considered that pulverized pyrite promotes the hydrogenation reaction of asphaltene because pulverization increases its contact rate with reactant and the amount of active points on its surface. It was inferred that catalytic activity of pyrite is affected greatly by the chemical state of Fe and S on its surface. 3 refs., 4 figs., 1 tab.

  10. Development of catalyst for diesel engine; Diesel engine yo shokubai no kaihatsu

    Ueno, H.; Furutani, T.; Nagami, T. [Toyota Motor Corp., Aichi (Japan); Aono, N.; Goshima, H.; Kasahara, K. [Cataler Industrial Co. Ltd., Shizuoka (Japan)


    The new concept catalyst for diesel engine has been developed. When the exhaust temperature is low, SOF and HC are temporarily adsorbed by the adsorbent within the catalyst and are oxidized as the temperature rise. The process of this development have manifested as follows. (1) The coating material is important factor to govern the oxidation activity. (2) SOF is reduced by the coating material in low temperature less than 200degC. (3) The coating material, which has low SO2 adsorbing rate suppress the sulfate formation at high temperature. 2 refs., 11 figs., 1 tab.

  11. Mesoporous activated carbons with metal-oxide particles prepared from Morwell coal; Morwell tan wo genryo to shita kinzoku sankabutsu tanji kasseitan no saiko kozo

    Yoshizawa, N.; Yamada, Y.; Shiraishi, M. [National Institute for Resources and Environment, Tsukuba (Japan); Kojima, S.; Tamai, H.; Yasuda, H. [Hiroshima University, Hiroshima (Japan). Faculty of Engineering


    The metal dependence of mesoporous activated carbons with various metal acetylacetonate (acac) particles prepared from Morwell coal was studied. In experiment, the mixture of Morwell coal and acac metal complexes were dissipated into tetrahydrofuran, and after agitation in Ar atmosphere, the solvent was removed by vacuum distillation. Coal specimens with Fe(acac)3, Ni(acac)2 and Co(acac)2 as acac complexes were activated by exchanging flow gas with water vapor after heat treatment in N2 gas flow at 900{degree}C. The pore sizes of the specimens were obtained from N2 adsorption isotherms by BET method and BJH method. Conditions of pores and metals in the specimens were examined by XRD measurement and TEM observation. The relation between the above conditions and pore characteristics obtained from adsorption experiment was also examined. As a result, the difference in mesopore ratio between the specimens and blank specimens was larger in the order of Fe, Co and Ni, and the effect of added metal complexes was also larger in this order. 3 refs., 3 figs., 3 tabs.

  12. Biomimetic oxidations using transition metal complex catalysts; Sen`i kinzoku sakutai wo mochiiru seigoseigata sanka shokubai hanno

    Murahashi, S. [Osaka University, Osaka (Japan). Faculty of Engineering Science


    Simulation of the functions of flavoenzyme and cytochrome P-450 with transition metal complex catalysts led to the discovery of biomimetic catalytic oxidation. The first section highlights the catalytic oxidation of secondary amides to nitrones by simulation of flavoenzymes. The second section is the simulation of the function of cytochrome P-450 with low valent ruthenium complexes and peroxides. Biomimetic ruthenium-paralyzed oxidations of tertiary amides, amides, {beta}-lactams, alkenes, and alkanes can be performed selectively under mild conditions. These general approaches provide highly useful strategies for synthesis of fine chemicals and biologically active compounds. 15 refs.

  13. Behavior of catalyst and mineral matter in coal liquefaction; Sekitan ekika hannochu no kobusshitsu to shokubai no kyodo

    Iwasaki, K.; Wang, J.; Tomita, A. [Tohoku University, Sendai (Japan). Institute for Chemical Reaction Science


    Mineral matter in coals is important in various senses for coal liquefaction. It is possible that the catalytic activity is affected by the interaction between catalyst and mineral matter. Iron-based catalyst forms pyrrhotite in the process of liquefaction, but the interaction between it and mineral matter is not known in detail. In this study, the interaction between mineral matter and catalyst and the selective reaction between them were investigated. Tanito Harum coal was used for this study. This coal contains a slight amount of siderite and jarosite besides pyrite as iron compounds. Liquefaction samples were obtained from the 1 t/d NEDOL process PSU. The solid deposits in the reactor mainly contained pyrrhotite and quartz. A slight amount of kaolinite was observed, and pyrite was little remained. It was found that the catalyst (pyrrhotite) often coexisted with quartz, clay and calcite. 8 figs., 2 tabs.

  14. Surface wettability control by titanium dioxide photo-induced reaction. Super-hydrophilic properties. Sanka chitan ni yoru hikari reiki shinsuika gijutsu. Hikari shokubai chosinsuisei

    Watanabe, T. (The University of Tokyo, Tokyo (Japan). Research Center for Advanced Science and Technology)


    Hydrophilicity results when the surface of titanium dioxide is reduced for the specified oxygen to be replaced by hydroxyl groups. The ease with which such a structural change occurs is subject to variation between titanium dioxide crystal surfaces, and is dependent greatly on the atmosphere. No hydrophilic trend is observed in an atmosphere of oxygen only without moisture and, in darkness without light, hydrophobicity occurs early. Although the contacta angle titanium dioxide with water with stability is not known, yet it is presumed, on the analogy of the case of strontium titanate, that it is in the range of 20-40 degrees. A hydrophilic trend below the range is attrributed to structural changes. The control of surface wettability is one of the basic tasks to fulfill in various kinds of mechanisms and manufacturing processes. The technology of wettability control using a titanium dioxide coating which is quite durable will be applied not only to functions involving defogging, dripproof, and self-cleaning, but also to the control of heat transmission in the mechanism and to the bonding process. (NEDO)

  15. Surface wettability control by titanium dioxide photo-induced reaction. Super-hydrophilic properties; Sanka chitan ni yoru hikari reiki shinsuika gijutsu. Hikari shokubai chosinsuisei

    Watanabe, T. [The University of Tokyo, Tokyo (Japan). Research Center for Advanced Science and Technology


    Hydrophilicity results when the surface of titanium dioxide is reduced for the specified oxygen to be replaced by hydroxyl groups. The ease with which such a structural change occurs is subject to variation between titanium dioxide crystal surfaces, and is dependent greatly on the atmosphere. No hydrophilic trend is observed in an atmosphere of oxygen only without moisture and, in darkness without light, hydrophobicity occurs early. Although the contacta angle titanium dioxide with water with stability is not known, yet it is presumed, on the analogy of the case of strontium titanate, that it is in the range of 20-40 degrees. A hydrophilic trend below the range is attrributed to structural changes. The control of surface wettability is one of the basic tasks to fulfill in various kinds of mechanisms and manufacturing processes. The technology of wettability control using a titanium dioxide coating which is quite durable will be applied not only to functions involving defogging, dripproof, and self-cleaning, but also to the control of heat transmission in the mechanism and to the bonding process. (NEDO)

  16. Hydrogenation of carbon monoxide over mixed catalysts. Co-Ni/MnO-ZrO sub 2 to zeolite kara naru kongo shokubai wo mochiita issankatanso no suisoka

    Ishihara, T.; Iwakuni, H.; Eguchi, K.; Arai, H. (Graduate School of Engineering Sciences, Kyushu Univ., Fukuoka (Japan). Department of Materials Science and Technology)


    The mechanical mixtures of Co-Ni/MnO-ZrO {sub 2} and zeolite were used as catalysts for the selective synthesis of gasoline by CO hydrogenation. Formation of branched-paraffins was promoted but that of higher hydrocarbons than carbon number of 10 was suppressed by combination with zeolite. The product distribution strongly depended on the type of zeolite catalyst. Pentasil zeolite was active for the formation of branched-paraffins, probably because of the cracking reaction occurring on the strong acid sites. The formation of branched paraffin was further promoted by ion-exchange with Pt. The mixture of Co-Ni/MnO-ZrO {sub 2} and PtH-pentasil zeolite was very active for the formation of gasoline with high octane number. 34 refs., 10 figs., 2 tabs.

  17. Influence of catalytic activity and reaction conditions on the product distribution in coal liquefaction; Sekitan ekikayu no seiseibutsu bunpu ni taisuru shokubai kassei oyobi hanno joken no eikyo

    Hasuo, H.; Sakanishi, K.; Mochida, I. [Kyushu University, Fukuoka (Japan). Institute of Advanced Material Study


    The NiMo sulfide supported on Ketjen Black (KB) was more effective and yielded lighter oil products containing light fractions with their boiling point below 300{degree}C during the two stage liquefaction combining low temperature and high temperature hydrogenation the conventional NiMo/alumina catalyst and FeS2 catalyst. Although the NiMo/alumina yielded increased oil products during the two stage liquefaction, the lighter oil fractions did not increase and the heavier fractions increased mainly. This suggests that the hydrogenation of aromatic rings and successive cleavage of the rings are necessary for producing the light oil, which is derived from the sufficient hydrogenation of aromatic rings using catalysts. For the two stage reaction with NiMo/KB catalyst, it was considered that sufficient hydrogen was directly transferred to coal molecules at the first stage of the low temperature reaction, which promoted the solubilization of coal and the successive hydrogenation at the high temperature reaction. Thus, high activity of the catalyst must be obtained. It is expected that further high quality distillates can be produced through the optimization of catalysts and solvents at the two stage reaction. 1 ref., 4 figs., 1 tab.

  18. Effects of solvent and catalysts on the hydrogenolysis of alkylnaphthalenes; Alkylnaphthalene no suisoka bunkai ni okeru yobai to shokubai no koka

    Futamura, S. [National Institute for Resources and Environment, Tsukuba (Japan)


    Catalytic effects of metal and carbon materials, which promote hydrogen transfer from hydrogen donor solvents, are investigated during hydrogenolysis of benzyl-1-methylnaphthalenes (BMN) selected as a hydrogen acceptor. For the isomer distribution of BMN after the reaction, almost the same molecular ratio before the reaction was obtained independent of the presence of catalysts. Selectivity of position during the addition of hydrogen atoms from tetralin was not found. For the reaction of BMN in tetralin, 1-methylnaphthalene and toluene were obtained as products, but the formation of benzylnaphthalene was not found. As for the nuclear hydride of BMN, the trace amount formation was confirmed by gas chromatography. For the hydrogen transfer from tetralin progressed catalytically, it was found that the nuclear of naphthalene can not be hydrogenated easily. This was considered to be due to the obstruction of hydrogen transfer from tetralin by the strong adsorption of BMN on the Ni surface. 1 ref., 1 fig., 2 tabs.

  19. Characterization of the various catalyst for solvent hydrogenation at 1t/d PSU; 1t/d PSU ni okeru kakushu yozai suisoka shokubai no seino hyoka

    Kakebayashi, H.; Nogami, Y.; Inokuchi, K. [Mitsui SRC Development Co. Ltd., Tokyo (Japan); Aihara, Y.; Imada, K. [Nippon Steel Corp., Tokyo (Japan)


    Performance of various catalysts for hydrogenation of recycle solvent was evaluated for the operation of NEDOL process 1 t/d process supporting unit (PSU). Distillate between 220 and 538{degree}C derived from the liquefaction of Tanito Harum coal was used as recycle solvent. Deactivation behaviors of catalysts were compared using a prediction equation of catalyst life, by which aromatic carbon index (fa) after hydrogenation can be determined from the fa of recycle oil before hydrogenation, reaction temperature, and total hydrogenation time. Total hydrogenation time satisfying the {Delta}fa, 0.05 before and after hydrogenation were 8,000, 4,000, and 2,000 hours for NiMo-based catalysts C, A, and B, respectively. Catalyst C showed the longest life. Used catalysts were also characterized. The catalyst C showed larger mean pore size than those of the others, which resulted in the longer life due to the delay of pore blockage. From measurements by XPS and EPMA, relative atomic concentration of carbon increased remarkably after the use for all of catalysts, which was considered to be due to the adhesion of hydrocarbons. Increase of metal atoms, such as Fe and Cr, was also observed due to the contamination of entrainment residues. Deactivation of catalysts was caused by the adhesion of hydrocarbons, and metallic compounds, such as Fe and Cr. 3 refs., 1 fig., 5 tabs.

  20. FY 1998 annual report on the fourth international forum on environmental catalysis (IFEC 99); Dai 4 kai kankyo shokubai kokusai forum (IFEC '99) 1998 nendo hokokusho



    The 4th international forum on environmental catalysis, held in January 1999 in Chemical Society of Japan's Hall, had a total attendees exceeding 170, including 10 foreign attendees invited. A total of 20 papers (including 10 by foreign attendees) were presented, discussing diversified problems; 3 keynote addresses regarding (to what extent environmental catalyst can contribute); and 5 for the session of catalysts for clean processes, 6 for the session of eco-friendly chemistry, and 8 for the session of environmental catalysts for air pollution. The lectures included (global environmental problems and environmental catalysts) by Prof. Segawa of Sophia University as the opening address; solid base catalysts by Prof. Ono of Tokyo Institute of Technology in the session of (catalysts for clean processes); activation of dioxygen by transition metal complexes-new approach to highly selective catalytic oxidation with molecular oxygen by Prof. Moro-oka of Tokyo Institute of Technology in the session of (Eco-friendly chemistry; and environmental catalysts-present and future as the comprehensive review by Prof. Misono of University of Tokyo in the session of (environmental catalysts for air pollution). (NEDO)

  1. Immobilization of biocatalysts using crosslinked acetoacetyl polyvinyl alcohol hydrogels. Acetoacetyl ka polyvinyl alcohol kakyo suisei gel ni yoru seitai shokubai no kateika

    Kondo, M.; Mannen, T. (Food Research Institute, Aichi Prefectural Government, Nagoya (Japan)); Shimokawa, w.; Fukumori, k. (Hoechst Gosei Co. Ltd., Shizuoka (Japan))


    In order to develop crosslinked hydrogels competent for immobilization of biocatalysts, gelation of acetoacetyl polyvinyl alcohol (AA-PVA) and immobilization of biocatalysts using the gel were investigated. AA-PVA solution formed crosslinked hydrogels when it was treated with bifunctional gelating agents such as albehyde and hydrazide. Since the gelating times were adjustable at appropriate pH, the hydrogels were able to be formed in various shapes such as granules and thin films. The appearance of the hydrogels was similar to calcium alginate gels, and they were stable under conditions which would cause decomposition of the latter. Acetic acid fermentation by immobilized growing cells were tested using the hydrogels, and then acetic acid productivity up to 3.7 g{center dot} l{sup {minus}1} {center dot} h {minus}1 and stability over six months were exhibited. In addition, activities of immobilized alcohol dehydrogenase using the hydrogels were measured. As the results, the hydrogels were concluded to be useful as immpbilization supports for microorganisms and enzymes. 14 refs., 6 figs., 2 tabs.

  2. Trend of research on future development of new biocatalysts. 2; Shinki bio shokubai no sosei ni kansuru kenkyu doko chosa. 2



    Creation of new biocatalysts was surveyed to convert chemical reactions into environment-friendly processes. Biocatalysts are characterized by their high catalytic activity, uniqueness of reactions, and non-pollution under mild conditions. Stability is required for them, such as heat resistance, solvent resistance, acid resistance and alkali resistance, under severe conditions. For the development of new biocatalysts, it is necessary to multiply utilize the techniques containing enzymes, ribozymes, mold synthetic polymers, chemical modification, and non-natural proteins. Natural enzymes have been conventionally improved through the search, imitation and modification. Hereafter, new biocatalysts with functions required for the reactions should be created by integrating information regarding functions, structures and activation of these enzymes. It is indispensable to cooperate closely with supporting techniques, such as gene engineering, organic synthesis, biophysics and computer chemistry. 35 refs., 26 figs., 1 tab.

  3. Studies on surface structures and mechanism of photocatalytic action of semiconductor oxides; Handotai hikari shokubai no hyomen kozo seigyo to sayo kiko kaimei ni kansuru kenkyu

    Takeuchi, H.; Sona, S.; Koike, H.; Hori, H.; Negishi, N.; Kohara, H.; Ibusuki, A. [National Institute for Resources and Environment, Tsukuba (Japan); Vakhtin, A.; Borovkov, V. [New Energy and Industrial Technology Development Organization, Tokyo, (Japan)


    Studies are made to define the working mechanism of semiconductor photocatalysts such as TiO2 and to establish designing guidelines for improving on their activity and functions. TiO2 in the air actively produces oxygen seeds for the oxidation and removal of NOx, etc. It is desired that a catalyst have a specific surface area large enough to retain the product of its action. To meet the need, a thin-film photocatalyst which is an aggregate of TiO2 crystals is produced by burning a film of a sol/gel system of reaction doped with macromolecules. This product has a larger specific surface area and is higher in pollutant-removing performance, and may be put into practical use. In another experiment, metal-carrying particles TiO2 suspended in water are employed for the reduction of CO2. Though the main product of catalysts carrying Pt or Pd is methane, a photocatalyst carrying RuO2 produces acetic acid mainly and loses less activity with the passage of time. A hybrid photocatalyst is composed of an organic pigment and inorganic semiconductor, synthesized through a covalent bond between a sililated-surface thin TiO2 film and porphyrin. It is confirmed that the newly developed process brings about an increase in electron migration efficiency. 3 figs.

  4. Survey on synthesis and reaction of environmentally benign water-soluble metal complex catalysts; Kankyo chowagata suiyosei sakutai shokubai no gosei hanno no chosa



    This report describes the research trend survey results on the synthesis and reaction of water-soluble metal complexes which are regarded as environmentally benign catalysts. For the synthesis and catalysis of water-soluble complexes, synthetic methods of water-soluble phosphines, such as sulfonated TPPMS and TPPTS, are described in detail. Synthesis and reactivity of hydroxymethylphosphines are introduced, and the application of electrospray mass spectroscopy is elucidated as a tool for the analysis of them. Changes of the application of transition metal complexes with water-soluble phosphines to catalysis are described. Dual catalysts which have both functions of phase transfer catalysts and homogeneous catalysts are introduced. Concept of counter phase transfer catalysts is also introduced, and some catalytic reactions are described. In addition, this report introduces catalysis of water-soluble polymer-supported metal complexes, immobilization of metal colloids with water-soluble ligands and their analysis, and water-soluble complexes as hybrid catalysts. 144 refs., 94 figs., 10 tabs.

  5. Preparation of a catalytic reactor composed of a microchannel etched on a silicon wafer; Shirikon ueha jo ni sakuseishita mikuro channeru wo mochiiru shokubai hanno sochi no shisaku

    Tsubota, T.; Miyagawa, D.; Kusakabe, K.; Morooka, S. [Kyushu Univ., Fukuoka (Japan). Dept. of Applied Chemistry


    A Microchannel (upper width = 280 {mu}m, lower width = 138 {mu}m, depth 100 {mu}m, length = 27 mm) was formed on a (100) silicon wafer by means of wet chemical etching, and a platinum layer was then coated on the microchannel walls by sputtering. The resulting channel was sealed with a glass cover by an anodic bonding technique. Cyclohexane vapor, carried by a stream of nitrogen, was then introduced into the microreactor at 400 degree C, and the concentrations of both the reactant, and the products of the ensuing dehydrogenation reaction over the platinum catalyst, were determined by means of a micro gas chromatograph. Thus, a series of procedures for manufacturing and testing a microreactor such as lithography of a microchannel, the formation of a catalytic Pt film, the introduction of a reactant into the covered microchannel, or an analysis of reactants and products was established and verified. (author)

  6. Effects of fuel properties and oxidation catalyst on diesel exhaust emissions; Keiyu seijo oyobi sanka shokubai no diesel haishutsu gas eno eikyo

    Aihara, S.; Morihisa, H.; Tamanouchi, M.; Araki, H.; Yamada, S. [Petroleum Energy Center, Advanced Technology and Research Institute, Tokyo (Japan)


    Effects of fuel properties (T90 and Poly-Aromatic Hydrocarbons: PAH) and oxidation catalyst on diesel exhaust emissions were studied using three DI diesel engines and two diesel passenger cars. (IDI engine) PM emissions were found to increase as T90 and PAH increased and could be decreased considerably for each fuel if an oxidation catalyst was installed. 5 refs., 9 figs., 3 tabs.

  7. Function development on gel to be fixed simultaneously plural kinds of biocatalysts; Fukusu no seitai shokubai wo geru e doji koteikashita toki no kino hatsugen

    Yoshimoto, M. [Yamaguchi Univ., Yamguchi (Japan)


    This paper introduces the report written by Fersh et. al. proposing a novel method for realization on reactivation of non-activated protein with high-density and high-efficiency by preparation of gel carrier fixed simultaneously plural kinds of biocatalysts imitating complex reaction in organism. Cn5 of scorpion toxin is objective protein and its reactive catalytic effects were examined by selecting mini GroEL, DsbA, PPI as catalysts fixing into agarose gel discretely or simultaneously. Cn5 activated completely was recovered with high yield (87%) in case of coexisting gel fixed three kinds of catalysts simultaneously. It is inferred that optimal net-work for controlling simultaneously complex reaction for formation of architectural constitution of protein substrates and chemical link. (translated by NEDO)

  8. Photocatalytic removal of nitrogen oxides from ambient air using solar energy; Taiyo energy wo riyoshita taikichu no NOx no hikari shokubai jokyo

    Fukaya, M.; Taoda, H.; Watanabe, E.; Nonami, T.; Iseda, K.; Kato, K. [National Industrial Research Institute of Nagoya, Nagoya (Japan); Kunieda, S. [NGK Insulators, Ltd., Nagoya (Japan); Kato, S.


    Experiment was made on removal of NOx from ambient air using ceramic blocks coated with a newly developed easy-to- handle TiO2 film photocatalyst. After TiO2 sol was prepared by hydrolyzing titanium tetraisopropoxide, the photocatalytic blocks were prepared through drying and sintering after immersing the blocks in TiO2 sol. The effect of the number of coating on catalytic performance was studied using the single-coated and triple-coated blocks. Artificial solar light of 1mW/cm{sup 2} was used as light source for flowing reaction experiment of air (containing NOx) in a laboratory. NOx concentration rapidly decreased with irradiation, and 94% and 98% of NOx were removed by the single- and triple-coated blocks, respectively. NOx was completely oxidized to HNO3 through NO2 by triple-coated blocks. The demonstration test of removal of NOx from ambient air in Okazaki city showed a removal rate of nearly 90% in noonday and 40% or more in average, while not 0% but 5-20% even in the nighttime. The latter is probably derived from adsorption by the porous photocatalytic blocks. 2 figs., 4 tabs.

  9. Evaluation report on the development of polymeric material from renewable resource using biocatalyst; Seitai shokubai wo riyoshita saisei kano shigen kara no kobunshi sozai no kaihatsu hyoka hokokusho



    The project aims to develop a biocatalyst-assisted synthesizing method for efficiently manufacturing sugar containing polymers and polylactic acids which generate less environmental impact. Methods were developed using the ALP-901 originating in actinomycetes for changing esterification-shy isopropylidene glucose into vinyladipic ester and for esterifying arbutin. A study was made of the polymerization of sugar ester monomers, and a polymer with a molecular weight of scores of thousands was obtained. The biodegradability of sugar containing polymers was confirmed. Using an enzyme, a polymer with a molecular weight of 1200 was obtained. Using a lipase derived from psudomonas cepacia, a polylactic acid was obtained from lactide. A high-function polylactic acid was obtained in a reaction between methyl lactate and divinyladipate. In a reaction between butanediol and lactide, several lactic oligomers different in molecular weight were synthesized, which were then brought into reaction with divinylcarboxylic acid in the presence of an enzyme for the production of polymerizable lactic oligomers. Similarly, polymerizable lactic oligomer derivatives were obtained from glucose and lactide. The oligomers and derivatives were brought into polymerization in the presence of a radical polymerization initiator for the production of polymeric gels, respectively. (NEDO)

  10. Environments of Ga in MFI-type Ga-silicates and their catalytic performance; MFI gata Ga-silicate chu no Ga no sonzai jotai to shokubai seino

    Nagata, H.; Takiyama, Y.; Higashida, K.; Otsuka, S.; Kishida, M.; Wakabayashi, K. [Kyushu University, Fukuoka (Japan); Shoji, H. [Maruzen Petrochemical Co. Ltd., Chiba (Japan)


    MFI-type Ga-silicates (GaS) of varying atomic Si/Ga ratio are synthesized from the gel stocks, to compare them one another for their properties and C4H10 conversion performance. GaS (M) synthesized by the Mobil method shows a broader Ga-MASNMR spectral peak relevant to the GaO4 tetrahedron and lower unit cell increase rate, when it contains a high proportion of Ga, than GaS (A) synthesized by the alkoxide method. It is therefore considered that GaS (M) has an increased content of the GaO4 tetrahedron of low symmetry, as Ga content increases. GaS (M) loses a larger quantity of Ga eluted out as a result of HCl treatment than GaS (A), indicating that the former contains the GaO4 tetrahedron of low symmetry under a less stable condition. GaS (M) gives a higher aromatic hydrocarbon yield in the C4H10 conversion than GaS (A), as its Ga content increases. This results from difference between their dehydrogenation performances, indicating that Ga in the GaO4 tetrahedron of lower symmetry has a higher dehydrogenation performance. 19 refs., 6 figs., 3 tabs.

  11. Evaluating Pt-Ru/C mixtures as ethanol electro-oxidation catalysers

    Bibian Alonso Hoyos


    Full Text Available This work studies ethanol electro-catalytic oxidation by cyclic voltametry in sulphuric acid solutions at different temperatures and concetrations, using platinum.rutenium mixtures supported in vitreous carbon as catalysers. The results indicate that ethanol oxidation in theses electrodes is irreversible, has slow kinetics, is controlled by charge transfer and is brought about by a bi-functional reaction mechanism, this being ethanol adsorption on platinum atoms and additional oxidation of specties adsorbed in the presence of platinum and retenium oxides. Experimental results show increased catalytic activity with electrodes, followed by reduced activity for electrodes having a greater quantity of rutenium.

  12. Reaction performance of methanation of carbon monoxide and carbon dioxide over supported ruthenium catalysts. ; Mainly on effects of remaining chlorine and dechlorination. Ruthenium tanji shokubaijo no issanka tanso oyobi nisanka tanso no methane ka no hanno tokusei. ; Shutoshite zanryu enso no eikyo to datsuenso shori no koka

    Kasaoka, S.; Sasaoka, E.; Okazaki, Y.; Hanaya, M. (Okayama University, Okayama (Japan). Faculty of Engineering)


    An establishment of the methanation catalytic process is desired on CO and CO {sub 2} generated in coal gasification and other various processes. In this study as one reply to this requirement, Ru catalysts supported on ZrO {sub 2}, Al {sub 2} O {sub 3} ({theta}) and SiO {sub 2} were prepared, and the relationship between the reaction condition and the catalytic reaction performance was investigated, especially from a view to the effects of remaining chlorine in catalysts and dechlorination based on raw salt of Ru. Experiments were carried out using a flow fixed-bed reactor under an atmospheric temperature at mainly 120-350 {degree}C. The results are as follows: Knowledge was obtained about the amount of remaining chlorine after a hydrogen reduction treatment or after washing with warm water at 85 {degree}C; the effect of remaining chlorine one the catalytic activity was much larger for CO {sub 2} methanation than for CO methanation; the remaining chlorine suppresses the formation of carbonaceous species on the catalyst surface and decreases the catalytic activity; and Ru/ZrO {sub 2}, dechlorinated with water washing at 85 {degree}C is most active. 10 refs., 12 figs., 1 tab.

  13. Fabrication of Pt/(Ta2O5+Pt) coated titanium electrodes using combination of partial thermal decomposition and electrolytic reduction of Pt and Ta complex; Tofu-bubun netsubunkai to denkai kangenho wo kumiawaseta hakkin/(sanka tantaru+hakkin) tanji chitan kitai denkyoku no sakusei

    Kamegaya, Y. [Ishifuku Metal Industry Co. Ltd., Saitama (Japan); Saito, J.; Kobayashi, H.; Mitamura, T. [Saitama Univ., Saitama (Japan). Faculty of Engineering; Okuyama, M. [Oyama National College of Technology, Tochigi (Japan)


    Recently, the authors proposed a new method, a combination of painting/partial thermal decomposition and electrolytic reduction, for the fabrication of Pt coated electrode. When Pt support carbon substrate electrode and Pt support Ti substrate electrode were fabricated using this method, any of these electrode has higher surface area than that of electrode fabricated by conventional painting/partial thermal decomposition method. In this report, in order to make possible to long life for Ti substrate coated electrode, the fabrication of coated electrode structure made of up catalyst layer/interlayer/electrode substrate was carried out using the electrode fabrication method proposed by authors. As a result, the amount of Ta support for including (Ta2O5+Pt) interlayer having sufficient electric conductivity and corrosion resistance into the coated electrode structure was necessary at least{sup -2} if the amount of Pt was{sup -2}. Further, the fabricated Pt/(Ta2O5+Pt)/Ti electrode had higher surface area and electrode life was 2 times longer than that of Pt/Ti electrode and had better stability. 9 refs., 7 figs.

  14. Countermeasures for exhaust prevention of organic solvents at print shop. 3. Removal of organic solvents by catalytic oxidation method; Insatsu kojo ni okeru yuki yozai haishutsu boshi taisaku. 3. Shokubai sankaho ni yoru yuki yozai no jokyo

    Yano, H. [Shimizu Corp., Tokyo (Japan); Shoda, M. [Tokyo Institute of Technology, Tokyo (Japan). Research Laboratory of Resources Utilization


    This paper summarizes circumstances of a catalytic oxidation type deodorizing experiment and a demonstration test on exhaust gas discharged actually from a print shop. The catalytic oxidation method is a method to burn the odor constituents, which are ethyl acetate, isopropyl alcohol and toluene, at temperatures of 200 to 300 degC. Space velocity was used as a parameter, and two kinds of platinum systems and two kinds of manganese + copper systems were used as catalysts. Elucidation was made on the space velocity and removal efficiency, removal efficiency of each catalyst, unreacted decomposition originated constituents at low temperatures (150 to 180 degC), and efficiency of each catalyst to remove each constituent. The result revealed that nearly 100% removal is possible at a space velocity of 33000 hr {sup -1} when the platinum-based catalyst and the manganese + copper based catalyst (both in pellet form) are combined. It was also found that the combination is advantageous in terms of cost. A demonstration test was performed at a new factory. Under a condition of combination of the above catalysts at 1:1 ratio, the space velocity of 30000 hr {sup -1}, and gas temperature at catalyst layer inlet of 200 degC, the removal efficiency was 97.9% to 98.7%, which clears the exhaust regulation value specified by the Tokyo Metropolitan Government. Average concentration in the working environment was 120.9 ppm, which cleared the maximum permissible concentration. 7 refs., 7 figs., 3 tabs.

  15. Improvement of liquefaction solvent. Increase of light oil yield with a reduction in catalyst addition; Ekika yozai no kairyo kenkyu. Sekitan ekikayu no keishitsuka to shokubai tenkaryo no teigen

    Okuyama, N.; Yasumuro, M.; Sato, K.; Komatsu, N.; Okui, T.; Shimasaki, K. [Nippon Brown Coal Liquefaction Co. Ltd., Tokyo (Japan)


    For developing coal liquefaction processes, it is an important problem to improve the light oil yield with increased oil yield. It was previously reported that distillate mainly containing lighter fraction can be produced with high oil yield by reducing the iron/sulfur catalyst addition in slurry, by recycling gas in the process operation, by utilizing these effects, and by using heavy oil as recycling solvent. In this study, the maximum distillate yield of Victorian brown coal was investigated through continuous liquefaction using a bench scale unit. In addition, operation conditions for obtaining sufficient oil yield were investigated under the reduced catalyst addition into one-third. Consequently, it was confirmed that the maximum content of lighter fraction in distillate product was obtained with reduced catalyst addition by using heavy oil as recycling solvent, by adopting new catalyst, and by utilizing effects of CLB recycling and gas recycling in maximum. It was also revealed that lighter distillate can be produced compared with the oil product obtained by recycling conventional solvent. 3 refs., 6 figs., 2 tabs.

  16. BTX production by in-situ contact reforming of low-temperature tar from coal with zeolite-derived catalysts; Zeolite kei shokubai wo mochiita sekitan teion tar no sesshoku kaishitsu ni yoru BTX no seisei

    Matsunaga, T.; Fuda, K.; Murakami, K.; Kyo, M.; Hosoya, S.; Kobayashi, S. [Akita University, Akita (Japan). Mining College


    On BTX production process from low-temperature tar obtained by pyrolysis of coal, the effect of exchanged metallic species and reaction temperature were studied using metallic ion-exchanged Y-zeolite as catalyst. In experiment, three kinds of coals with different produced tar structures such as Taiheiyo and PSOC-830 sub-bituminous coals and Loy Yang brown coal were used. Y-zeolite ion-exchanged with metal chloride aqueous solution was used as catalyst. Zn{sup 2+}, Ni{sup 2+} and In{sup 3+} were used as metal ions to be exchanged. The experiment was conducted by heating a pyrolysis section up to 600{degree}C for one hour after preheating a contact reforming section up to a certain proper temperature. As a result, the Ni system catalyst was effective for BTX production from aromatic-abundant tar, while the Zn system one from lower aromatic tar. In general, relatively high yields of toluene and xylene were obtained at lower temperature, while those of benzene at higher temperature. 4 figs., 1 tab.

  17. Fiscal 1999 research result report. Research on improvement of boiling heat transfer characteristics by photocatalyst wall; 1999 nendo hikari shokubai hekimen ni yoru futto netsu dentatsu tokusei kaizen ni kansuru kenkyu chosa hokokusho



    Research was made on improvement of the wettability and boiling heat transfer characteristics of a photocatalyst wall. Measurement experiment of the wettability was made for anatase type titan oxide-coated Al, SUS and Pb plates, rutil type titan oxide-flame coated SUS plate, raw plate, and oxide-plasma coated titan plate. In the ground experiment, the contact angles of distilled water and oil on specimen surfaces were measured. In the microgravity experiment, falling droplet images were recorded by using the facility of Japan Microgravity Center (JAMIC). For obtaining the effect of radioactive emission, UV irradiation, {gamma} ray and neutron beam irradiation by nuclear reactor, and {gamma} ray irradiation by Co-60 were carried out. As the experiment result, the rutil type titan oxide-flame coated SUS plate, nonconductor-coated titan plate, and zircaloy plate showed large improvement of the wettability by {gamma} ray irradiation with Co-60. It was also confirmed that in particular, titan shows the large effect of radioactive emission, and the wettability deteriorates rapidly after {gamma} ray irradiation. (NEDO)

  18. Deactivation of REY zeolite during catalytic cracking of heavy oil obtained from the pyrolysis of waste plastics; REY zeolite shokubai ni yoru hai plastic netsu bunkaiyu no sesshoku bunkai hanno no kassei rekka

    Masuda, T.; Mukai, S.; Akiyama, T.; Fujikata, Y.; Hashimoto, K. [Kyoto University, Kyoto (Japan)


    A model has been developed to represent the deactivation of REY zeolite caused by coke deposition during catalytic cracking of heavy oil obtained from pyrolysis of waste plastics. Coke deposition not only leads to coverage of the acid sites, which contribute to the reaction, but also leads to a decrease in the intracrystalline diffusivity of the zeolite due to the reduction in effective pore opening, resulting in deactivation of the catalyst. In this work, firstly the amount of strong acid sites and the diffusivity of catalysts with different amounts of coke loading were measured, and empirical equations, which represent the relationships between the amount of coke loading and these two values, were obtained. Finally, a model was developed to calculate the transient change of the catalyst activity and the concentration distributions of the components within the reactor by employing the obtained empirical equations. The calculated results agreed well with experimental results. Using this model, it was found that the deactivation rate of the catalyst was reduced under diffusion control conditions, and large catalyst particles could maintain their activity longer than small catalyst particles. 12 refs., 9 figs., 1 tab.

  19. Long-term storage and long-distance transportation of hydrogen by use of catalyst-addisted decalin dehydrogenation/naphthalene hydrogenation pair; Dekarin dassuiso/nafutarensuisoka shokubai hannotai wo mochiiru suiso no chokikan chozo/chokyori yuso

    Liu, C.; Sakaguchi, M.; Saito, Y. [Scince Univ.of Tokyo, Tokyo (Japan)


    To enable taking in and out hydrogen with little energy consumption, it is sufficient if decalin is dehydrogenated to naphthalene under moderate heating condition. It is found that carbon supporting metal catalyst in liquid film state shows extremely high dehydrogeno-aromatization activity of decalin. The result of comparison with liquid hydrogen or metal hydride as media for hydrogen storage and transportation media is reported. The platinum-tungsten composite metal catalyst is prepared from an aqueous solution of K2PtC16 and Li2WO4 in the ratio of 1 to 1 so as to achieve 5wt-metal% carbon supporting. When hydrogen and naphthalene are discharged from the liquid phase reaction medium to the vapor phase and solid phase, respectively, under boiling and refluxing conditions, hydrogen is produced steadily by heating at 200 to 210degC. If economical efficiency is ignored, development of an inter-season energy storage system is desired to be developed which can be used in the season between summertime when sufficient hydrogen is obtained by photovoltaic power generation and electrolysis of water and wintertime when heat source is obtained by catalytic combustion of hydrogen. 11 refs., 4 figs., 4 tabs.

  20. FY 1998 annual report on the decomposition/removal of harmful compounds in the gaseous phase by porous membrane provided with a catalytic function; 1998 nendo shokubai kinotsuki fuyo takomaku ni yoru kisochu yugai busshitsu no bunkai jokyo chosa hokokusho



    Harmful compounds, e.g., dioxins and nitrogen oxides, released into the air are causing severer environmental problems on a global scale. In order to solve these problems, it is necessary to efficiently remove the released compounds in the vicinity of the living environments, while preventing, as far as possible, their formation at the sources. An attempt has been made to develop porous membranes impregnated with composites of a variety of metallic oxides showing activities as photocatalysts and for dark reactions by the ion engineering method, in order to drastically solve the above problems. Described herein are the FY 1998 results. Thin films of various titanium oxide crystals (anatase, rutile, and their combinations) are formed on Si substrates by the ion engineering method, as the photocatalysts for decomposition of aldehyde and water (for hydrogen production), to validate the optimum crystalline structures for the photocatalysis. Porous bodies of Ni and carbon are also impregnated with anatase TiO{sub 2} for decomposition of harmful gaseous compounds and water, to validate the effects of the porous membranes provided with catalytic functions. (NEDO)

  1. Asymmetric carbon-carbon bond forming reactions catalyzed by chiral titanium complexes. Efficient synthesis of optically active secondary alcohols; Kiraru na chitan shokubai ni yoru fuseitanso-tanso ketsugo keisei. Kogaku kassei dainikyu arukoru no gosei

    Hayashi, M. [Yamaguchi Univ., Yamaguchi (Japan). Faculty of Science


    For asymmetric metal complex catalysts with high catalytic activity and ability for recognizing asymmetry, it is most important to choose center metals and design asymmetric organic ligands. When the authors began to study on the title reactions, combination of titanium alkoxides as center metals and chiral Schiff bases as organic ligands was unknown, although two moieties had been used independently for asymmetric reactions with excellent results. Asymmetric silylcyanation of aldehydes and enantio-selective addition of diketone to aldehydes are introduced, that have been achieved by authors using titanium complexes of the above combination. In the silylcyanation, reactivity is remarkably improved, compared with a single catalyst of titanium isopropoxide. Cyanohydrin of R from was obtained preferentially with salicyladehyde, particularly having 3-tert butyl group, in an asymmetric yield of 85 % ee. In the latter addition reaction, 5-hydroxy-3-ketoesters were obtained from benzaldehyde in an asymmetric yield as high as 91 % ee. 9 refs., 2 figs.

  2. Fe(CO)5-catalyzed coprocessing of coal and heavy oil vacuum residue using syngas-water as a hydrogen source; Fe(CO)5 shokubai ni yoru gosei gas-mizu wo suisogen to suru sekitan-jushitsuyu no coprocessing

    Hata, K.; Wada, K.; Mitsudo, T. [Kyoto University, Kyoto (Japan)


    Improvement in efficiency and profitability of hydrogenation reaction of heavy hydrocarbon resources is the most important matter to be done. In this study, coprocessing of coal and heavy oil vacuum residue was conducted using syngas-water as a hydrogen source. For the investigation of effect of the reaction temperature during the coprocessing of Wandoan coal and Arabian heavy vacuum residue using Fe(CO)5 as a catalyst, the conversion, 66.0% was obtained at 425{degree}C. For the investigation of effect of reaction time, the yield of light fractions further increased during the two stage reaction at 400{degree}C for 60 minutes and at 425{degree}C for 60 minutes. Finally, almost 100% of THF-soluble matter was obtained through the reaction using 2 mmol of Fe(CO)5 catalyst at 400{degree}C for 60 minutes, and hydrogenation of heavy oil was proceeded simultaneously. When comparing coprocessing reactions using three kinds of hydrogen sources, i.e., hydrogen, CO-water, and syngas-water, the conversion yield and oil yield obtained by using syngas-water were similar to those obtained by using hydrogen, which demonstrated the effectiveness of syngas-water. 2 refs., 2 figs., 2 tabs.

  3. Reaction mechanism of coal liquefaction: hydrogenolysis of model compound using synthetic pyrite as catalysts. 7. Property change of synthetic pyrite catalyst with the time after production; Sekitan ekika hanno kiko (model kagobutsu no hanno). 7. Gosei ryukatetsu shokubai no keiji henka ni tsuite

    Ito, H.; Meno, H.; Uemaki, O.; Shibata, T.; Tsuji, T. [Hokkaido University, Sapporo (Japan)


    Reactions of various model compounds were investigated using synthetic pyrites for coal liquefaction. In this study, successive changes of the catalysts were investigated from the reactions of model compounds by using three different synthetic pyrites with the lapse of time after production. Benzyl phenyl ether, dibenzyl, and n-octylbenzene were used as model compounds. Reactions were conducted in an autoclave, into which sample, catalyst, decalin as solvent, and initial hydrogen pressure 10 MPa were charged. The autoclave was held at 450 or 475{degree}C of reaction temperature for 1 hour. The catalyst with a shorter lapse of time after production acted to hydrogen transfer, and inhibited the formation of condensation products due to the stabilization of decomposed fragment. It also acted to isomerization of materials by cutting alkyl side chains. When adding sulfur to the catalyst with longer lapse of time after production under these reaction conditions, it inhibited the formation of condensation products for the reaction of benzyl phenyl ether. However, it did not provide the effect for the reaction of n-octylbenzene. 5 refs., 3 figs.

  4. Test and survey on a next generation coal liquefying catalyst. Coal molecule scientific test and survey as the base for commercializing the coal liquefying technology; Jisedai sekitan ekika shokubai shiken chosa. Sekitan ekika gijutsu shogyoka kiban to shite no sekitan bunshi kagaku shiken chosa



    The test and survey on a next generation coal liquefying catalyst present a new proposal to raise catalytic activity in coal liquefaction, and perform demonstration experiments in a laboratory scale to search for possibility of developing a new coal liquefying catalyst from various viewpoints. To explain, discussions were given on the catalyst to perform the followings: liquefaction under extremely mild conditions by using ultra strong acids not limited only to metals; ion exchange method and swell carrying method to raise catalyst dispersion very highly, enhance the catalytic activity, and reduce the amount of catalyst to be used; mechanism of producing catalyst activating species to further enhance the activity of iron catalysts; and pursuit of morphological change in the activating species. The coal molecule scientific test and survey as the base for commercializing the coal liquefying technology performed the studies on the following items: pretreatment of coal that can realize reduction of coal liquefaction cost; configuration of the liquefaction reaction, liquefying catalysts, hydrocarbon gas generating mechanism, status of catalysts after liquefaction reaction, and reduction in gas purification cost by using gas separating membranes. Future possibilities were further searched through frank and constructive opinion exchanges among the committee members. (NEDO)

  5. Fiscal 1993 international research cooperation project. Feasibility study of finding out the seeds of international joint research (technology for environmental preservation using biotechnology, technology for effective use of unused hydrocarbon resource, technology for development of environmental harmony type catalyst); 1995 nendo kokusai kyoryoku jigyo. Kokusai kyodo kenkyu seeds hakkutsu no tame no FS chosa (biotechnology ni yoru kankyo taisaku gijutsu, miriyo tanka suiso shigen no yuko riyo gijutsu, kankyo chowagata shokubai kaihatsu gijutsu)



    This project is aimed at internationally cooperating in the R and D of industrial technology and improving industrial technology of Japan. For it, the following three technologies were investigated: 1) environmental preservation technology using biotechnology, 2) technology for effective use of unused hydrocarbon resource, 3) technology for development of environmental harmony type catalyst. In 1), a survey was conducted of applicability of biological surfactant to prevention measures of pollution by heavy distillate. It showed that part of the biological surfactants is reaching a stage of its being industrially produced by gene recombination bacteria, but as a whole, biosynthetic genes have hardly been elucidated. In 2), a survey of high-grade treatment technology of petroleum coke was made. It pointed out that it is necessary to develop a technology which makes the most of features of petroleum coke and allows defects. In 3), scientists and engineers of Japan and Europe searched for themes on which they can jointly study in the fields of NOx removal catalyst, up-grading of fuel, and development of catalyst combustion of fuel. 287 refs., 136 figs., 128 tabs.

  6. Bone changes caused by experimental Solanum malacoxylon poisoning in rabbits

    José Ignacio Aguirre


    Full Text Available The aim of this study was to describe the bone changes observed after a daily oral administration of the calcinogenic plant Solanum malacoxylon (syn. S. glaucophyllum (Sm during 9 days. The Sm-poisoned rabbits had an increase of bone resorption in the endosteal surface of the cortical zone and also in the surface covered by osteoblasts of the primary and secondary spongiosa of the trabecular bone compartment. Moreover, the epiphyseal growth plates in long bones appeared narrower than in the control rabbits, with reduction of the proliferative and hyperthrophic chondrocyte zones. The electron microscopic study revealed a significant decrease of proteoglycans in the hyperthrophic chondrocyte zone evidenced by a significant reduction of rutenium red positive granules in the poisoned rabbit. Altogether, these data suggest that cell differentiation may play a pivotal role in the pathogenesis of Sm-induced bone lesions.

  7. Petroleum price jumped in about ten times through the first oil crisis and the second oil crisis, and concern rose in development of use of the biomass as one of sources of substitutive energy. After that, a recent petroleum price changes 15-20 dollars before and after /bbl, and crisis consciousness fades away in the country, and saving energy consciousness and the movement of the biomass fuel development research are thought to become weak, too. But, concern rises in the development, use of the biomass origin fuel with the recognition that fossil resources are limited from the viewpoint of the environment countermeasure as well again and more; Taikenronteki shokubai kaihatsu zatsukan. Hasso {center_dot} shijo {center_dot} hito

    Sato, Hiroshi. [Sumitomo Chemical Industry Corp., Osaka (Japan)


    25 years have been consistent since the entrance into a company, and the impression which relates to development of a catalyst from the position of the enterprise researcher concerned with the catalyst development research from the viewpoint of experience argument is written, and it wants to submit it for the reference. A theme is divided into three. (1) Ni teegler pattern complex catalyst, (2) aromatic composition and the development of the (3) ZSM-5 zeolite catalyst. (NEDO)

  8. Petroleum price jumped in about ten times through the first oil crisis and the second oil crisis, and concern rose in development of use of the biomass as one of sources of substitutive energy. After that, a recent petroleum price changes 15-20 dollars before and after /bbl, and crisis consciousness fades away in the country, and saving energy consciousness and the movement of the biomass fuel development research are thought to become weak, too. But, concern rises in the development, use of the biomass origin fuel with the recognition that fossil resources are limited from the viewpoint of the environment countermeasure as well again and more. Taikenronteki shokubai kaihatsu zatsukan. Hasso [center dot] shijo [center dot] hito

    Sato, Hiroshi. (Sumitomo Chemical Industry Corp., Osaka (Japan))


    25 years have been consistent since the entrance into a company, and the impression which relates to development of a catalyst from the position of the enterprise researcher concerned with the catalyst development research from the viewpoint of experience argument is written, and it wants to submit it for the reference. A theme is divided into three. (1) Ni teegler pattern complex catalyst, (2) aromatic composition and the development of the (3) ZSM-5 zeolite catalyst. (NEDO)

  9. Predictors of antipsychotic monotherapy with olanzapine during a 1-year naturalistic study of schizophrenia patients in Japan

    Ye W


    Full Text Available Wenyu Ye1, Haya Ascher-Svanum2, Jennifer A Flynn3, Yuka Tanji3, Michihiro Takahashi3,41Lilly Suzhou Pharmaceutical Co, Shanghai, People's Republic of China; 2Eli Lilly and Company, Indianapolis, IN, USA; 3Lilly Research Laboratories Japan, Eli Lilly Japan K.K., Kobe, 4Terauchi-Takahashi Psychiatric Clinic, Ashiya, JapanPurpose: Although expert guidelines for the treatment of schizophrenia recommend antipsychotic monotherapy, the use of antipsychotic polypharmacy is common. This study identified characteristics that differentiate patients with schizophrenia who are treated with olanzapine monotherapy versus polypharmacy in usual care in Japan.Patients and methods: In a large (N = 1850 prospective, observational study, Japanese patients with schizophrenia who initiated treatment with olanzapine were followed for 1 year. Consistent with past research, antipsychotic polypharmacy was defined as the concurrent use of olanzapine and another antipsychotic for at least 60 days. Switching was defined as discontinuing a prior antipsychotic therapy rather than augmenting the medication regimen. Predictors of antipsychotic monotherapy were based on information available at the time of olanzapine initiation. Baseline characteristics were compared using t-tests and Χ2 tests. Stepwise logistic regression was used to identify independent predictors of monotherapy.Results: Patients treated with olanzapine monotherapy (43.2% differed from those treated with antipsychotic polypharmacy (56.8% on demographics, treatment history, baseline symptom levels, functional levels, and treatment-emergent adverse events. Stepwise logistic regression identified multiple variables that significantly predicted monotherapy: older age, shorter duration of schizophrenia, outpatient status, comorbid medical conditions, lower body mass index, no prior anticholinergic use, no prior mood stabilizer use, and switching from a previous antipsychotic (typical or atypical

  10. Predictors of continuation with olanzapine during the 1-year naturalistic treatment of patients with schizophrenia in Japan

    Ye W


    Full Text Available Wenyu Ye1, Haya Ascher-Svanum2, Yuka Tanji3, Jennifer A Flynn3, Michihiro Takahashi3,41Lilly Suzhou Pharmaceutical Co, Shanghai, People’s Republic of China; 2Eli Lilly and Company, Indianapolis, IN, USA; 3Lilly Research Laboratories Japan, Eli Lilly Japan KK, Kobe, 4Terauchi-Takahashi Psychiatric Clinic, Ashiya, JapanPurpose: Treatment continuation is considered an important measure of antipsychotic effectiveness in schizophrenia, reflecting the medication’s efficacy, safety, and tolerability from both patients’ and clinicians’ perspectives. This study identified characteristics of patients with schizophrenia who continue olanzapine therapy for a 1-year period in Japan.Methods: In a large (N = 1850, prospective, observational study, Japanese patients with schizophrenia who initiated treatment with olanzapine were followed for 1 year. Baseline characteristics were compared using t-tests and chi-square tests. Stepwise logistic regression was used to identify independent baseline predictors of treatment continuation.Results: Most patients (68.2% continued with olanzapine therapy for the full 1-year study period, with an average duration of 265.5 ± 119.4 days. At baseline, patients who continued were significantly more likely to be male, older, and inpatients; have longer illness duration, higher negative and cognitive symptoms, better health-related quality of life, and prior anticholinergic use. Continuers were significantly less likely to engage in social activities, live independently, work for pay, or have prior antidepressant use. Continuers showed significantly greater early (3-month improvement in global symptom severity. Logistic regression found that continuation was significantly predicted by longer illness duration, lower positive symptoms, higher negative symptoms, and better health-related quality of life.Conclusions: In this large naturalistic study in Japan, most patients with schizophrenia stayed on olanzapine therapy for

  11. Perceptions and impact of bipolar disorder in Japan: results of an Internet survey

    Watanabe K


    Full Text Available Koichiro Watanabe,1 Eiji Harada,2 Takeshi Inoue,3 Yuka Tanji,2 Toshiaki Kikuchi1 1Department of Neuropsychiatry, Kyorin University, School of Medicine, Tokyo, 2Medical Science, Medicines Development Unit-Japan, Eli Lilly Japan KK, Hyogo, 3Department of Psychiatry, Tokyo Medical University, Tokyo, Japan Abstract: Bipolar disorder is a recurrent and episodic illness. This survey study assessed experiences and identified clinical insights of individuals with bipolar disorder. An Internet-based monitor system database was screened for patients with bipolar disorder in Japan (February and March 2013. Of 1,050 patients, 457 completed surveys, and results were analyzed with descriptive statistics. Approximately one-fourth of respondents were diagnosed with bipolar disorder on their first visit to medical institutions, although the most common initial diagnosis was depression/depressive state (65%. Mean time lag between first-time visit to a medical institution and receipt of correct diagnosis of bipolar disorder was 4 years; one-third of patients experienced more than 5 years of lag time. Three perceived reasons for lapsed time before correct diagnosis were “(patients Did not consider manic symptoms as illness, and did not tell the doctor about them,” “I (patient did not know of bipolar disorder,” and “Lack of communication between my doctor and myself (patient.” Among participants who believed that they were initially incorrectly diagnosed and improperly treated, most experienced socioeconomic problems, such as having long-term inability to work or to study (65%. Sources of encouragement for participants included “To have someone to consult with” (41% followed by having “People around me treat me the same as before” (40%. Individuals with bipolar disorder reported a time lag of many years before accurate diagnosis, and substantial burden imposed by the illness. Encouragement should be provided for individuals to live positively

  12. Restoration of Degraded Salt Affected Lands to Productive Forest Ecosystem

    Singh, Yash; Singh, Gurbachan; Singh, Bajrang; Cerdà, Artemi


    Soil system determines the fluxes of energy and matter in the Earth and is the source of goods, services and resources to the humankind (Keesstra et al., 2012; Brevik et al., 2015; Keesstra et al., 2016). To restore and rehabilitate the soil system is a key strategy to recover the services the soils offers (Celentano et al., 2016; Galati et al., 2016; Parras-Alcantara et al., 2016). Transformation of degraded sodic lands in biodiversity rich productive forest ecosystem is a challenging task before the researchers all over the world. The soils of the degraded sites remain almost unfavorable for the normal growth, development and multiplication of organisms; all our attempts tend to alleviate the soil constraints. Land degradation due to presence of salts in the soil is an alarming threat to agricultural productivity and sustainability, particularly in arid and semiarid regions of the world (Tanji, 1990; Qadir et al., 2006). According to the FAO Land and Nutrition Management Service (2008), over 6% of the world's lands are affected by salinity, which accounts for more than 800 million ha in 100 countries. This is due to natural causes, extensive utilization of land (Egamberdieva et al., 2008), poor drainage systems and limited availability of irrigation water which causes salinization in many irrigated soils (Town et al., 2008).In India, about 6.73 million ha are salt affected which spread in 194 districts out of 584 districts in India and represents 2.1% of the geographical area of the country (Mandal et al., 2009).Out of these, 2.8 million ha are sodic in nature and primarily occurring in the Indo-Gangetic alluvial plains. These lands are degraded in structural, chemical, nutritional, hydrological and microbiological characteristics. The reclamation of salt affected soils with chemical amendments like gypsum and phospho-gypsum are in practice for the cultivation field crops under agricultural production. Forest development on such lands although takes considerable