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Sample records for rmn calculos teoricos

  1. Magnetic structure analyses of multiferroics RMnO3 and RMn2O5

    International Nuclear Information System (INIS)

    Arima, Taka-hisa; Kimura, Hiroyuki

    2010-01-01

    Magnetic structure of typical multiferroic materials RMnO 3 and RMn 2 O 5 (R:rare earth) has been investigated by neutron diffraction. Magnetic structure analysis using single crystal revealed that both the materials have a cycloidal magnetic structure, where ferroelectricity arises. Polarized neutron diffraction under electric field found the one-to-one correspondence between the direction of cycloidal rotation (spin chirality) and the direction of the electric polarization, evincing that the electric polarization is directly induced by the cycloidal magnetic order. (author)

  2. INTERVALOS DE INTEGRACIÓN UNIFICADOS PARA LA CARACTERIZACIÓN ESTRUCTURAL DE PETRÓLEOS, CARBONES O SUS FRACCIONES POR RMN 1H Y RMN 13C

    Directory of Open Access Journals (Sweden)

    Avella Eliseo

    2010-09-01

    Full Text Available Con base en la revisión de publicaciones, hechas entre 1972 y 2006, se evidenció que hay imprecisiones en los límites de los intervalos de integración que los autores asignan a las señales en resonancia magnética nuclear (RMN para hacer la caracterización estructural de petróleos, carbones o sus fracciones derivadas, a partir de sus espectros de hidrógeno (RMN 1H o de carbono (RMN 13C. En consecuencia, se determinaron límites unificados para la integración de los espectros RMN 1H y RMN 13C de tales muestras mediante un tratamiento estadístico aplicado a los límites de los intervalos de integración ya publicados. Con esos límites unificados se elaboraron cartas de correlación en RMN útiles para la asignación de la integral en esos intervalos, y aun en otros de menor extensión definidos en función de la intersección entre asignaciones diferentes. Además se plantearon ecuaciones necesarias para establecer la integral atribuible a fragmentos más específicos en un intento por hacer una caracterización estructural más exacta a partir de los espectros RMN de petróleos, carbones o sus fracciones derivadas.

  3. Calculation of uncertainties; Calculo de incertidumbres

    Energy Technology Data Exchange (ETDEWEB)

    Diaz-Asencio, Misael [Centro de Estudios Ambientales de Cienfuegos (Cuba)

    2012-07-01

    metodologico para la obtencion de informacion (mesurando) de un sistema material (poblacion). Ello supone la necesidad de la definicion del problema, la eleccion de los metodos de muestreo y medicion adecuados y la ejecucion de estas actividades para la obtencion de la informacion. El resultado de una medicion solo es una aproximacion o estimacion del valor del mesurando, el cual se completa solo cuando va acompanado por una estimacion de la incertidumbre del proceso analitico. Segun el 'Vocabulario de Terminos Basicos y Generales de Metrologia' la incertidumbre de medicion 'es el parametro asociado con el resultado de la medicion que caracteriza la dispersion de los valores que razonablemente pudiera ser atribuida al mensurando (o magnitud). Este parametro podria ser una desviacion estandar o un intervalo de confianza'. La evaluacion de la incertidumbre exige que observemos detalladamente todas sus posibles fuentes, pero no de forma desproporcionada. Podemos realizar una buena estimacion de la incertidumbre concentrando el esfuerzo en las mayores contribuciones. Los pasos fundamentales del proceso de determinacion de la incertidumbre en las mediciones son: - la especificacion del mesurando; - la identificacion de las fuentes de incertidumbre; - la cuantificacion de las componentes individuales de la incertidumbre; - el calculo de la incertidumbre estandar combinada; - informe de la incertidumbre.

  4. Intervalos de integración unificados para la caracterización estructural de petróleos, carbones o sus fracciones por rmn 1h y rmn 13c

    OpenAIRE

    Eliseo, Avella; Fierro, Ricardo

    2010-01-01

    Con base en la revisión de publicaciones, hechas entre 1972 y 2006, se evidenció que hay imprecisiones en los límites de los intervalos de integración que los autores asignan a las señales en resonancia magnética nuclear (RMN) para hacer la caracterización estructural de petróleos, carbones o sus fracciones derivadas, a partir de sus espectros de hidrógeno (RMN 1H) o de carbono (RMN 13C). En consecuencia, se determinaron límites unificados para la integración de los espectros RMN 1H y RMN 13C...

  5. Difusão de spins nucleares em meios porosos - uma abordagem computacional da RMN

    OpenAIRE

    Éverton Lucas-Oliveira

    2015-01-01

    A Ressonância Magnética Nuclear (RMN) é uma importante técnica empregada nas principais áreas de conhecimento, tais como, Física, Química e Medicina. Importantes trabalhos da RMN aplicada ao estudo da dinâmica de moléculas em fluidos presentes em meios porosos permitiram que esta técnica ganhasse também notoriedade na indústria do petróleo. O presente projeto é fundamentado em alguns destes trabalhos seminais, reproduzindo, através de modelos físico-computacionais, os principais efeitos físic...

  6. Effect of ionic size on the orbital ordering transition in RMnO3+δ

    NARCIS (Netherlands)

    Maris, G.; Volotchaev, V.; Palstra, T.T.M.

    2004-01-01

    We present high-temperature powder x-ray diffraction data of the orbital-order-induced structural distortion of RMnO3, with R a rare earth element. The associated phase transition takes place in a temperature interval of ≈200K in which the orbitally ordered phase and the orbitally disordered phase

  7. Specific heat and magnetization of RMn2(H,D)2

    International Nuclear Information System (INIS)

    Tarnawski, Z.; Kolwicz-Chodak, L.; Figiel, H.; Kim-Ngan, N.-T.H.; Havela, L.; Miliyanchuk, K.; Sechovsky, V.; Santava, E.; Sebek, J.

    2007-01-01

    The effect of hydrogen absorption on magnetic and thermodynamic properties of hydrides compounds RMn 2 (H,D) 2 (R = Y, Nd, Tb, Ho, and Er) have been investigated by performing specific heat and magnetization measurements in the temperature range of 2-320 K and in magnetic fields up to 9 T. The phase transition to the antiferromagnetic order accompanying a crystal structure transformation have been revealed by complicated-structure anomalies in specific heat and weak anomalies in magnetization

  8. 13 Facile application de la RMN du carbone-13 à l'identification et à ...

    African Journals Online (AJOL)

    AKA BOKO

    de bois [13] en utilisant l'analyse directe avec RMN du carbone-13 assistée par ordinateur sans séparation préalable ont démontré la facilité et fiabilité de cette méthode éminemment non invasive. Dans une étude antérieure, nous avons appliqué cette méthodologie dans l'analyse qualitative et quantitative des sucres.

  9. Analysis of the Anisotropic Magnetocaloric Effect in RMn2O5 Single Crystals

    Directory of Open Access Journals (Sweden)

    Mohamed Balli

    2017-11-01

    Full Text Available Thanks to the strong magnetic anisotropy shown by the multiferroic RMn2O5 (R = magnetic rare earth compounds, a large adiabatic temperature change can be induced (around 10 K by rotating them in constant magnetic fields instead of the standard magnetization-demagnetization method. Particularly, the TbMn2O5 single crystal reveals a giant rotating magnetocaloric effect (RMCE under relatively low constant magnetic fields reachable by permanent magnets. On the other hand, the nature of R3+ ions strongly affects their RMCEs. For example, the maximum rotating adiabatic temperature change exhibited by TbMn2O5 is more than five times larger than that presented by HoMn2O5 in a constant magnetic field of 2 T. In this paper, we mainly focus on the physics behind the RMCE shown by RMn2O5 multiferroics. We particularly demonstrate that the rare earth size could play a crucial role in determining the magnetic order, and accordingly, the rotating magnetocaloric properties of RMn2O5 compounds through the modulation of exchange interactions via lattice distortions. This is a scenario that seems to be supported by Raman scattering measurements.

  10. I concetti di "materia", "forma" e "ordine" nel pensiero teorico musicale medievale e contemporaneo

    Directory of Open Access Journals (Sweden)

    Cecilia Panti

    2011-01-01

    Full Text Available La dimensione teorica della musica occidentale, nella sua evoluzione storica, ha inevitabilmente fatto uso di concetti essenziali alla definizione di come il suono è musicalmente organizzato o organizzabile. Fra questi, risultano imprescindibili le nozioni di materia, forma e ordine, che implicano rispettivamente, nei pur diversi ambiti linguistici e contesti storico-filosofici di riferimento, ciò di cui è fatta la musica, ciò a cui la materia sonora tende, e come tale tensione è realizzata. Scopo di questo contributo è una valutazione d’insieme sulla valenza filosofica e l’uso di tali concetti nel pensiero musicale occidentale altomedievale e in quello del Novecento, che nonostante la distanza cronologica presentano convergenze significative. Nel Medioevo, un lungo processo di elaborazione teorico-pratica permise la matematizzazione dello spazio (e, più tardi, anche del tempo musicale, attraverso l’adattamento di moduli melodici, trasmessi oralmente, alle strutture scalari desunte dalla teoria greco-boeziana. La forma e l’ordo musicali furono quindi riferiti ai criteri fisico-matematici atti a distinguere nella materia sonora, in sé disorganica e indefinita, ciò che è musicale da ciò che non lo è. Tale concezione sparisce con l’affermarsi del sistema tonale, ove il suono fisico è concepito come “pre-formato” e “pre-ordinato” nella gamma scalare e nei vincoli attrattivi “naturali” degli armonici. In conseguenza, i concetti di forma e ordine abbandonano il contesto acustico, andando a definire i criteri teorici della composizione artistica, in linea con l’idea filosofica del loro esprimere la coerenza logico-sintattica dell’“insieme organico” (la Formenlehre teorizzata da Widmann. Nell’ambito del pensiero musicale del Novecento, la crisi del sistema tonale e la messa a punto di nuove modalità e tecniche di produzione del suono hanno riorientato la valenza significante e l’uso di questi tre concetti

  11. Theoretical Aspects of Phonon Dispersion Curves for Metals; Aspects Theoriques des Courbes de Dispersion des Phonons pour les Metaux; Teoreticheskie aspekty fononnykh dispersionnykh krivykh dlya metallov; Aspectos Teoricos de las Curvas de Dispersion Fononica en Metales

    Energy Technology Data Exchange (ETDEWEB)

    Cochran, W. [Department of Natural Philosophy, University of Edinburgh, Scotland (United Kingdom)

    1965-04-15

    , manifiestan la presencia de fuerzas de alcance relativamente grande, que se extienden a varios espacios interatomicos. Los resultados relativos al plomo son particularmente interesantes; no fue posible ajustarlos a un modelo de constantes de fuerza, pero las curvas de dispersion de los vectores de onda en las direcciones de simetria, analizadas en funcion de las constantes de fuerza entre planos atomicos, revelan la existencia de un potencial interatomico de caracter oscilatorio que se extiende a distancias superiores a 20A. La memoria trata de trabajos teoricos recientes, relacionados con el calculo de las curvas de dispersion fononica en metales y con la explicacion del largo alcance del potencial interatomico. En la actualidad, el metodo mas prometedor para abordar con criterio general la interaccion atomica en los metales parece ser el de los 'pseudoatomos neutros ', denominacion recientemente acunada por Ziman. Se exponen los principios de esta teoria de Aproximacion y se examina su relacion con las anomalias de Kohn en las curvas de dispersion fononica. En el caso del sodio, los valores experimentales concuerdan con los datos teoricos, y el potencial interatomico varia periodicamente en la distancia {pi}/k{sub F}, donde hk{sub F} es el momento de Fermi, como ha demostrado Koenig por un procedimiento diferente. Toya y Sham han realizado calculos mas exactos para el sodio; se examinan las relaciones existentes entre los diferentes metodos y otros trabajos de indole mas general, tales como los de Harrison. (author) [Russian] V nastojashhee vremja v rezul'tate jeksperimentov po neuprugomu rassejaniju nejtronov dovol'no polno izucheny fononnye dispersionnye krivye po krajnej mere dlja djuzhiny metallicheskih jelementov i intermetallicheskih soedinenij. Rezul'taty imejut odnu obshhuju oso- oennost': analiz ih s tochki zrenija konstant mezhatomnyh sil pokazyvaet nalichie dovol'no dal'nodejstvujushhih sil, prostirajushhihsja na neskol'ko mezhatomnyh rasstojanij. Osobyj interes

  12. RA-0 reactor. New neutronic calculations; Reactor RA-0. Nuevos calculos neutronicos

    Energy Technology Data Exchange (ETDEWEB)

    Rumis, D; Leszczynski, F

    1991-12-31

    An updating of the neutronic calculations performed at the RA-0 reactor, located at the Natural, Physical and Exact Sciences Faculty of Cordoba National University, are herein described. The techniques used for the calculation of a reactor like the RA-0 allows prediction in detail of the flux behaviour in the core`s interior and in the reflector, which will be helpful for experiments design. In particular, the use of WIMSD4 code to make calculations on the reactor implies a novelty in the possible applications of this code to solve the problems that arise in practice. (Author). [Espanol] En este trabajo se actualizan los calculos neutronicos realizados para el reactor RA-0, instalado en la Facultad de Ciencias Exactas, Fisicas y Naturales de la Universidad Nacional de Cordoba. Se describen los calculos realizados hasta la fecha y los resultados obtenidos. Las tecnicas incorporadas al calculo de un reactor como el RA-0 permiten predecir en detalle el comportamiento del flujo en el interior del nucleo y en el reflector, lo que sera una importante ayuda en el diseno de experimentos. En particular, el empleo del codigo WIMSD4 para calculos del reactor completo constituye una novedad en las posibles aplicaciones de ese codigo para resolver problemas que se presentan en la practica. (Autor).

  13. Relation between ferroelectric and antiferromagnetic order in RMn2O5

    International Nuclear Information System (INIS)

    Noda, Yukio; Kimura, Hiroyuki; Kamada, Youichi; Osawa, Toshihiro; Fukuda, Yosikazu; Ishikawa, Yoshihisa; Kobayashi, Satoru; Wakabayashi, Yusuke; Sawa, Hiroshi; Ikeda, Naoshi; Kohn, Kay

    2006-01-01

    RMn 2 O 5 (R=Y and rare earth) shows successive magnetic and ferroelectric phase transitions at about 45, 40, 39, 20 and 10K. We have reinvestigated the magnetic structure of YMn 2 O 5 at the commensurate phase (T=25K) using a single crystal four-circle diffractometer in order to discuss the mechanism of magnetoelectric interaction and the origin of ferroelectricity. We also observed the lattice modulation vectors (q L ) to compare the magnetic propagation vectors (q M ) by synchrotron X-ray diffraction. Improved magnetic structure data are compared with the theory recently proposed

  14. Ferrielectricity in DyMn2O5: A golden touchstone for multiferroicity of RMn2O5 family

    Directory of Open Access Journals (Sweden)

    J.-M. Liu

    2015-06-01

    Full Text Available The RMn2O5 manganite compounds represent one class of multiferroic family with magnetic origins, which has been receiving continuous attention in the past decade. So far, our understanding of the magnetic origins for ferroelectricity in RMn2O5 is associated with the nearly collinear antiferromagnetic structure of Mn ions, while the exchange striction induced ionic displacements are the consequence of the spin frustration competitions. While this scenario may be applied to almost all RMn2O5 members, its limitation is either clear: the temperature-dependent behaviors of electric polarization and its responses to external stimuli are seriously materials dependent. These inconsistences raise substantial concern with the state-of-the-art physics of ferroelectricity in RMn2O5. In this mini-review, we present our recent experimental results on the roles of the 4f moments from R ions which are intimately coupled with the 3d moments from Mn ions. DyMn2O5 is a golden figure for illustrating these roles. It is demonstrated that the spin structure accommodates two nearly collinear sublattices which generate respectively two ferroelectric (FE sublattices, enabling DyMn2O5 an emergent ferrielectric (FIE system rarely identified in magnetically induced FEs. The evidence is presented from several aspects, including FIE-like phenomena and magnetoelectric responses, proposed structural model, and experimental check by nonmagnetic substitutions of the 3d and 4f moments. Additional perspectives regarding possible challenges in understanding the multiferroicity of RMn2O5 as a generalized scenario are discussed.

  15. Double-flat-spiral magnetic structures: Theory and application to the RMn6X6 compounds

    International Nuclear Information System (INIS)

    Rosenfeld, E.V.; Mushnikov, N.V.

    2008-01-01

    We studied magnetic structure of a layered magnetic material, the lattice of which consists of magnetic layers separated by alternating non-magnetic layers (slabs) of two different types. For such structure, the exchange integrals between the nearest magnetic layers separated by different slabs may have different values, while the next-nearest neighbor exchange integral is the same for all magnetic layers. We developed a model based on three different interlayer exchange integrals. In the framework of this model we analyzed conditions of the appearance of a magnetic structure of the double-flat-spiral type and its distortion in external magnetic field. The results are most obtained in the analytical form. The model was applied to analyze the magnetic structure and magnetization process of the RMn 6 X 6 (R=Y, Sc, Lu; X=Sn, Ge) compounds with the layered crystal structure

  16. Calculo de la Barra Antivuelco de un Vehículo Automotor.

    Directory of Open Access Journals (Sweden)

    Javier García de la Figal

    2005-09-01

    Full Text Available El presente trabajo trata acerca del calculo de la barra antivuelco del FORD modelo A, desarrollado por elInstituto de Desarrollo Automotriz, IDA, teniendo en cuenta las fuerzas que la cinta de seguridad de losautomovilistas, ejerce sobre la citada barra, ante un choque que provoca una aceleración de 20 g en elvehículo. El calculo se hace mediante la confección de un modelo de elementos finitos de la barra y lacarrocería, para lo cual se hace uso de un programa profesional de elementos finitos.Se determinan los esfuerzos máximos y los equivalentes, tanto de las partes metálicas del sistema, queson fundamentalmente tubos de acero, como de las partes de material compuesto (poliéster con fibras devidrio E, propios de la carrocería del vehículo. Todo lo cual permite hacer los cálculos y comprobacionesa resistencia de todo el conjunto. Así mismo, se determinan los desplazamientos en todos los sentidos detodos las partes del sistema, para poder realizar los correspondientes análisis de rigidez.El objetivo final de todos los análisis es determinar lo adecuado o no de las soluciones y materialespropuestos para el sistema, bajo la acción de la citada carga de impacto.

  17. Algorithm for the calculation of a steam generator efficiency; Algoritmo para el calculo de la eficiencia de un generador de vapor

    Energy Technology Data Exchange (ETDEWEB)

    Franco, David; Ambriz, Juan Jose; Romero Paredes, Hernando [Universidad Autonoma Metropolitana-Iztapalapa, Mexico, D. F. (Mexico)

    1994-12-31

    The efficiency calculation of steam generators is not always simple. The purpose of this paper is to propose an algorithm for the calculation of steam generators efficiency, easy to understand and carry out, in the form of a series of steps to be followed. It takes as starting point that the person in charge of applying these calculations has knowledge of the combustion processes and thermodynamic principles that rule such processes. [Espanol] El calculo de la eficiencia de los generadores de vapor no siempre es sencillo, el presente trabajo tiene como objetivo el de proponer un algoritmo de calculo de eficiencia de generadores de vapor, el cual sea facil de entender y de llevar a cabo, en forma de una serie de pasos a seguir. Se toma como punto de partida, que la persona encargada de aplicar estos calculos tenga el conocimiento de los procesos de combustion y principios termodinamicos que rigen tales procesos.

  18. Synthesis RMn{sub 2}O{sub 5} (R = Gd and Sm) nano- and microstructures by a simple hydrothermal method

    Energy Technology Data Exchange (ETDEWEB)

    Zhu Gangqiang, E-mail: zgq2006@snnu.edu.cn [School of Physics and Information Technology, Shaanxi Normal University, Xi' an 710062 (China); Liu Peng [School of Physics and Information Technology, Shaanxi Normal University, Xi' an 710062 (China); Hojamberdiev, Mirabbos [Shaanxi Key Laboratory of Nano-materials and Technology, Xi' an University of Architecture and Technology, Xi' an 710055 (China); Ge Bao [School of Physics and Information Technology, Shaanxi Normal University, Xi' an 710062 (China); Liu Yun; Miao Hongyan; Tan Guoqiang [College of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi' an 710021 (China)

    2009-12-15

    Single-phase RMn{sub 2}O{sub 5} (R = Gd and Sm) nano- and microstructures have been successfully synthesized via a simple hydrothermal process at 250 deg. C for 24 h using NaOH as mineralizer. X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM) and selective area electron diffraction patterns (SAED) were used to characterize the as-synthesized GdMn{sub 2}O{sub 5} and SmMn{sub 2}O{sub 5} samples. The effect of NaOH concentration and the molar ratio of Mn{sup 2+}/Mn{sup 7+} on the morphology and size of the final products was studied, and a possible formation mechanism of RMn{sub 2}O{sub 5} (R = Gd and Sm) nanoplates and nanorods under hydrothermal conditions was proposed.

  19. The pseudogap and anisotropic thermal expansion in RMn{sub 4}Al{sub 8} (R = La,Y,Lu and Sc)

    Energy Technology Data Exchange (ETDEWEB)

    Muro, Y; Nakamura, H; Kohara, T [Graduate School of Material Science, University of Hyogo, Kamigori, Ako-gun, Hyogo 678-1297 (Japan)

    2006-04-26

    The temperature dependence of the magnetic susceptibility shows a broad maximum at {approx}550 and 630 K for LuMn{sub 4}Al{sub 8} and ScMn{sub 4}Al{sub 8}, respectively, which can be interpreted as due to the presence of a pseudogap in the effective bands as in LaMn{sub 4}Al{sub 8} and YMn{sub 4}Al{sub 8}. The anisotropic thermal expansion observed for RMn{sub 4}Al{sub 8} (R = La, Y, Lu and Sc) and the sensitive volume dependence of the gap width throughout the RMn{sub 4}Al{sub 8} system suggest dominant magnetic coupling in Mn spin chains along the c axis.

  20. Les écoulements par RMN à gradient pulsé Pulsed Gradient Nmr Techniques for Studying Flows

    Directory of Open Access Journals (Sweden)

    Lebon L.

    2006-12-01

    Full Text Available Nous présentons ici les techniques de RMN à gradient pulsé qui permettent d'étudier les écoulements multiphasiques en canalisation ou en milieu poreux. Les principaux avantages sont de pouvoir travailler sur des milieux non transparents et d'accéder à des échelles de longueurs faibles. On montre qu'il est possible d'obtenir des informations locales sur l'écoulement, telles que le profil de vitesse et ses fluctuations dans les écoulements diphasiques, ou les cartes de distribution des probabilités de déplacement dans des échantillons poreux hétérogènes. Pulsed gradient NMR techniques are presented here. They allow the study of multiphase flow in pipes as well as porous media. The main advantages are the possibilities of studying non transparent media at small length scales. We show that it is possible to obtain local information on the fluid flow, such as velocity profiles in two phase systems, or maps of distribution of displacement probabilities in heterogeneous porous media.

  1. Symmetry, incommensurate magnetism and ferroelectricity: The case of the rare-earth manganites RMnO3

    International Nuclear Information System (INIS)

    Ribeiro, J L

    2010-01-01

    The complete irreducible co-representations of the paramagnetic space group provide a simple and direct path to explore the symmetry restrictions of magnetically driven ferroelectricity. The method consists of a straightforward generalization of the method commonly used in the case of displacive modulated systems and allows us to determine, in a simple manner, the full magnetic symmetry of a given phase originated from a given magnetic order parameter. The potential ferroic and magneto-electric properties of that phase can then be established and the exact Landau free energy expansions can be derived from general symmetry considerations. In this work, this method is applied to the case of the orthorhombic rare-earth manganites RMnO 3 . This example will allow us to stress some specific points, such as the differences between commensurate or incommensurate magnetic phases regarding the ferroic and magnetoelectric properties, the possible stabilization of ferroelectricity by a single irreducible order parameter or the possible onset of a polarization oriented parallel to the magnetic modulation. The specific example of TbMnO 3 will be considered in more detail, in order to characterize the role played by the magneto-electric effect in the mechanism for the polarization rotation induced by an external magnetic field.

  2. Ab initio study of the structural, electronic, elastic and thermal properties of RMn{sub 2}Ge{sub 2} (R = Ca, Nd and Y) intermetallic compounds

    Energy Technology Data Exchange (ETDEWEB)

    Miloud Abid, O.; Yakoubi, A. [Laboratoire d’Etudes des Matériaux et Instrumentations Expérimentales, Université Djilali Liabes de Sidi Bel-Abbes, 22000 (Algeria); Tadjer, A. [Modeling and Simulation in Materials Science Laboratory, Physics Department, University of Sidi Bel-Abbes, Sidi Bel-Abbes (Algeria); Khenata, R., E-mail: khenata_rabah@yahoo.fr [Laboratoire de Physique Quantique de la Modélisation Mathématique (LPQ3M), Université de Mascara, 29000 (Algeria); Ahmed, R. [Department of Physics, Faculty of Science, Universiti Teknologi Malaysia, UTM Skudai, 81310 Johor (Malaysia); Murtaza, G. [Materials Modeling Laboratory, Department of Physics, Islamia College University, Peshawar (Pakistan); Bin Omran, S. [Department of Physics and Astronomy, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451 (Saudi Arabia); Azam, Sikander [New Technologies – Research Center, University of West Bohemia, Univerzitni 8, 306 14 Pilsen (Czech Republic)

    2014-12-15

    Highlights: • The calculated structural parameters of RMn{sub 2}Ge{sub 2} (R = Ca, Nd and Y) compounds are found in good agreement with the experimental data. • The structural and band structure calculation reveals that these compounds are ferromagnetic brittle metals. • The elastic and thermodynamic properties for the herein studied compounds are investigated for the first time. - Abstract: Intermetallic RMn{sub 2}Ge{sub 2} ternary compounds have attracted considerable attention from researchers in recent years because they show strong indications for novel magnetic characteristics and they have the potential to reveal the mechanism of superlattices. The study of the paramagnetic, ferromagnetic and antiferromagnetic phases affirms the strong dependence to the distance between atomic species in these compounds. In this study, we investigated the structural, elastic, electronic and thermodynamic properties of the intermetallic RMn{sub 2}Ge{sub 2} (R = Ca, Nd and Y) compounds. To carry out this study, we used the full potential (FP) linearized (L) augmented plane wave plus local orbitals (APW + lo), a scheme of calculations developed within the frame work of density functional theory (DFT). To incorporate the exchange correlation (XC) energy and corresponding potential into the total energy calculations, local density approximation (LDA) parameterized by Perdew and Wang is taken into account. Analysis of the density of states (DOS) profile illustrates the conducting nature of these intermetallic compounds; with a predominantly contribution from the R and Mn-d states. At ambient conditions, calculations for elastic constants (C{sub 11}, C{sub 12}, C{sub 13}, C{sub 44}, C{sub 33} and C{sub 66}) are also performed, which point to their brittle character. In addition, the quasi harmonic Debye model was used to predict the thermal properties, together with relative expansion coefficients and heat capacity.

  3. Control para un equipo de análisis químico por RMN basado en un microprocesador de 32 bits

    OpenAIRE

    Palacio Tárrega, Víctor Manuel

    2009-01-01

    El objetivo del PFC es desarrollar el sistema de control de un equipo de análisis quimico por RMN. Las especificacions del sistema de control implican que este integre los ortos dos componentes del equipo de análisis ( procesado de señal y sistema de raiofrecuencia ) con una interfaz gráfica para el usuario.Se desarrollan dos componentes para el sistema de control, hardware y software, El hardware de control incrustado está basado en un procesador ARM de 32 bits,, y se completado con todos lo...

  4. Estudio teorico de las interacciones de dos modelos de ácidos húmicos con los cationes Al3+, Ca2+, Mg2+, Zn2+, K+ y NH4+ a un nivel de calculo DFT y un modelo de solvatación PCM

    Directory of Open Access Journals (Sweden)

    Eduardo Espinosa-Fuentes

    Full Text Available In this paper, two models of humic acids, the Temple-Northeastern-Birmingham (TNB and Kolla models, were studied. Also, the complexation reaction of the structures formed by the interaction of the TNB and Kolla models with Al3+, Ca2+, Mg2+, Zn2+, K+ and NH4+ cations, common in agricultural soils, was studied. These calculations were made for the complexes, at PM6 and DFT / LANL2DZ level of theory, both in vacuum and in aqueous medium. We found a strong affinity between Kolla and TNB models, and Al3+, Ca2+, Mg2+, Zn2+, K+ and NH4+ cations, influenced by the solvent that affected the interaction sites; the solvent increased the rate of reactivity and affinity for the cations in nucleophilic regions and decreased it in electrophilic regions of the structures. Calculations of molecular electronic potential, MEP and atomic charges, the local smoothness, Fukui functions and the HSAB principle adequately described the HA/cations interactions which were affected by the number of hydrogen bonds. The most reactive sites were the hydroxyl, phenolic, carbonyls oxygens and nitrogens at both vacuum and aqueous medium, especially carbonyl oxygens. These results are consistent with the properties of HA that make them attractive as components of agricultural soils.

  5. Desarrollo de una interfaz gráfica de usuario en entorno MATLAB para el manejo de software de segmentación de imágenes RMN

    OpenAIRE

    Cancio del Busto, Javier

    2011-01-01

    Cancio Del Busto, J. (2010). Desarrollo de una interfaz gráfica de usuario en entorno MATLAB para el manejo de software de segmentación de imágenes RMN. http://hdl.handle.net/10251/10184. Archivo delegado

  6. Evidencias espectroscópicas de RMN de ¹H y 13C en la formación inusual de un "carbonilo inorgánico", derivado de la lactona costunólida

    OpenAIRE

    Díaz, Eduardo; Barrios, Héctor; Fuentes, Aydeé; Corona, David; Guzmán, Ángel

    2002-01-01

    El uso de la RMN de ¹H y 13C permitió determinar la estructura inusual de un "carbonilo inorgánico" derivado de la lactona dehidrocostus. 1H and 13C NMR of an unusual "inorganic carbonyl" derived from costunolide lactone are described.

  7. Excange interactions and induced Eu3+ magnetic order in RMnO3 investigated using resonant X-ray diffraction

    International Nuclear Information System (INIS)

    Skaugen, Arvid

    2015-03-01

    The so-called multiferroics, materials that concomitantly exhibit more than one ferroic order, have in recent years attracted much attention owing to their possible applications in high density data storage, high sensitivity ac magnetic field sensors and novel spintronic devices. In particular, multiferroics with strong magnetoelectric coupling are more attractive. Among such multiferroics, an interesting special class is the orthorhombic manganites with perovskite structure. In these compounds, frustration serves to destabilize ordinary ferromagnetic or antiferromagnetic ordering, giving rise to rich phase diagrams due to several competing magnetic interactions. Interactions between strong rare earth magnetic moments and weaker transition metal moments add another level of complexity, as well as interest. The current dissertation presents results obtained investigating the magnetic structure responsible for ferroelectricity in a few selected multiferroic compounds, using x-ray resonant magnetic scattering (XRMS). In particular, single crystals of Eu 1-x Y x MnO 3 have been studied at low temperatures and in high magnetic fields. This series of compounds is similar in structure to the heavily studied RMnO 3 (R=Tb,Gd,Dy), only without rare earth magnetism. The novel technique of full polarization analysis has been used to determine the complicated cycloidal Mn magnetic ordering, and additional components due to the Dzyaloshinskii-Moriya interactions have been identified. In the compound Eu 0.8 Y 0.2 MnO 3 , two coexisting multiferroic phases were observed, and a magnetoelectric coupling between the two was established. Moreover, magnetic order of the formally non-magnetic rare earth ion Eu 3+ was observed in the same compound. It has been concluded to result from a Van Vleck type excitation of the J = 0 ground state due to the symmetry-breaking internal exchange field from the Mn magnetic moments. In addition, this dissertation reports on high field investigations

  8. Development of applications in Internet for the calculation of solar control devices; Desarrollo de una aplicacion en Internet para el calculo de dispositivos de control solar

    Energy Technology Data Exchange (ETDEWEB)

    Perez V, Jesus B; Robles G, Saul; Villa M, Hector A; Cabanillas L, Rafael E [Universidad de Sonora, Hermosillo, Sonora (Mexico)

    2000-07-01

    In this work the development of an interactive software, visible over the World Wide Web, is presented to support the basic calculation required to control the solar gain inside buildings and houses. The site has two main parts: one part describes in a very required parameters to design devices for the control of the illumination inside the buildings, like overhangs and wingwalls for shading. The other part has the routines and procedures to calculate the sun position for any date and position over the earth, and the horizontal and vertical protection angles. The part to implement the calculations has been developed as a Java applet which can run on any platform and let the users, in an interactive way, to get the results. This software makes possible that any Internet user can run the application from his/her own computer without having to compile of use sophisticated procedures as it happens with traditional languages. With this web site it is intended to cover the necessity of having simple and reliable means for architects and civil engineers to support the use of solar energy and the saving of energy in bioclimatic design of buildings. [Spanish] En este trabajo se presenta el desarrollo de un sitio interactivo visible en el World Wide Web (WWW) que pretende servir de apoyo para los calculos basicos de control de asoleamiento en viviendas y edificios. El sitio esta conformado por dos partes principales: una parte cubre el aspecto informativo, donde en forma sencilla y clara, se explican los conceptos y parametros necesarios para disenar los dispositivos de control, alerones y parteluces. La otra parte contiene los procedimientos y las rutinas de calculo para la determinacion de la posicion solar para cualquier fecha del ano desde cualquier punto sobre la tierra, asi como los angulos de sombreado vertical y horizontal. Para la realizacion de los calculos se ha construido un applet de Java, el cual puede ejecutarse desde cualquier plataforma de computacion y

  9. DETERMINACIÓN RÁPIDA Y PRECISA DEL CONTENIDO DE HIDRÓGENO EN MEZCLAS DE HIDROCARBUROS POR RMN 1H

    Directory of Open Access Journals (Sweden)

    Eliseo Avella

    2011-12-01

    Full Text Available Se presentan y discuten resultados de ladeterminación de hidrógeno en mezclasde hidrocarburos y de fracciones pesadasde petróleo por integración de las señalesen sus espectros RMN 1H de alta resolución.Los resultados muestran la posibilidadde cuantificar de manera rápida yprecisa el hidrógeno en 37 fragmentosestructurales, además del hidrógeno totalen la muestra, mediante aplicación deintervalos de integración unificados. Adiferencia de los métodos publicados enla literatura, la determinación de hidrógenoes posible con menor cantidad demuestra en disolución, con corto tiempode reciclado, d1, sin ajustes estrictos detemperatura ni adición de agente de relajacióno uso de algún estándar de cuantificaciónexterno.

  10. Competing exchange interactions and their relevance for the magnetisation process in RMn6-xCrxSn6 powders (R=Y, Gd, Tb, Dy, Ho, Er)

    International Nuclear Information System (INIS)

    Brabers, J.H.V.J.; Zhou, G.F.; Colpa, J.H.P.; Buschow, K.H.J.; De Boer, F.R.

    1994-01-01

    The free-powder magnetisation of RMn 6-x Cr x Sn 6 compounds has been measured for compounds with R=Y, Gd, Tb, Dy, Ho, Er in fields up to 38 T, and interpreted in terms of a simple model, which is also outlined in this paper. From the measurements, estimates for the R-3d mean-field coupling constant (n RT ) could be derived for the cases where R=Gd, Tb, Dy, Ho, Er. In turn, the n RT values can be related to the microscopic spin-coupling constant (J RT ). In the case of YMn 6 Sn 6 the high-field measurement presents evidence for a very weak antiferromagnetic coupling between the Mn layers. Furthermore, values for the Mn moments (μ Mn ) were also derived from the magnetisation measurements. The estimated μ Mn values are of the order of 2.0 μ B . ((orig.))

  11. Movilidad de litio en conductores iónicos rápidos analizada mediante espectroscopia RMN

    Directory of Open Access Journals (Sweden)

    Sanz, J.

    2010-02-01

    -red (T1 y spin-spin (T2 con la temperatura, ha permitido deducir los tiempos de residencia de los iones Li en los sitios estructurales. La comparación de estos valores con los deducidos a partir de las conductividades ac y dc, hace posible describir de un modo más preciso la dinámica de los iones. A temperaturas crecientes, los movimientos se vuelven menos correlacionados, produciéndose una disminución de la energía de activación. El análisis de los movimientos a larga distancia requiere medidas a baja frecuencia (medidas de T2 y conductividad-dc. Desviaciones de la conductividad del comportamiento Arrhenius, a menudo observadas en conductores iónicos rápidos, han sido adscritas a transiciones de orden-desorden en las que el movimiento de los iones se hace menos correlacionado. Una medida directa de los coeficientes de difusión ha sido obtenida con la técnica RMN de gradiente de campo pulsado (PFG. Finalmente se analiza la importancia de los fenómenos de percolación de vacantes en los procesos de conducción.

  12. Measurement and calculation of dynamic coefficients in hydrodynamic bearings of gas films; Medicion y calculo de coeficientes dinamicos en cojinetes hidrodinamicos de peliculas de gas

    Energy Technology Data Exchange (ETDEWEB)

    Ruiz, Rafael O.; Di Liscia, Marcelo H.; Diaz, Sergio E. [Universidad Simon Bolivar, Sartendejas, Baruta (Venezuela)

    2007-11-15

    dynamic coefficients. [Spanish] La identificacion de los coeficientes dinamicos en cojinetes de aire es fundamental para un adecuado analisis rotodinamico. El presente trabajo muestra el desarrollo de un algoritmo que permite la obtencion directa de los coeficientes dinamicos en cojinetes hidrodinamicos de aire tanto de forma numerica como experimental. El banco de pruebas utilizado consta de dos cojinetes magneticos, los cuales soportan al rotor en sus extremos y a su vez funcionan como actuadores permitiendo inducir orbitas controladas en el rotor. El cojinete de prueba se encuentra ubicado entre los cojinetes magneticos. Las fuerzas dinamicas generadas en el cojinete de aire se registran a partir de tres celdas de carga. El algoritmo fue desarrollado en un codigo comercial de programacion grafica, a traves del cual se pueden colectar, controlar y procesar las senales. El comportamiento no lineal de este tipo de cojinetes dificulta el calculo de los coeficientes dinamicos, por esta razon el procesamiento de las senales en espacio frecuencial facilita de cierta manera su manejo. Por otra parte, el modelo numerico se comparo con los resultados experimentales obteniendo aproximaciones aceptables tanto en magnitud como en comportamiento. El calculo de los coeficientes dinamicos numericos se realizo resolviendo la ecuacion diferencial de Reynolds para un fluido compresible en el espesor de la pelicula de gas, tomando en consideracion el flujo masico del fluido que se introduce, asi como la perdida de presion que sufre el mismo al pasar a traves de los orificios de alimentacion. Los metodos numericos utilizados incluyen la resolucion de la ecuacion diferencial de Reynolds por diferencias finitas, el calculo del perfil de presiones realizando iteraciones sucesivas y el calculo de las fuerzas hidrodinamicas a traves de una integracion numerica de Simpson. Los coeficientes dinamicos numericos fueron hallados aplicando una tecnica de minimos cuadrados a las fuerzas hidrodinamicas

  13. Structure par RMN d'un complexe AlcR(1-60)-ADN: Reconnaissance du petit sillon par la partie N-terminale

    Science.gov (United States)

    Cahuzac, B.; Félenbok, B.; Guittet, E.

    1999-10-01

    Aspergillus nidulans is a filamentous fungus able to use ethanol as sole energy source. The activation of the ethanol regulon genes expression is mediated by the AlcR protein. Its DNA-binding domain is located in the N-terminus (residues 1 to 60), and its NMR solution structure shows a global zinc binuclear cluster fold, with two helices in addition to the basic binuclear motif. A small number of crystallographic structures of DNA complexes of binuclear cluster proteins is yet known, and points out the major groove and the first helix as the principal sites of interaction on the DNA and the protein respectively. In this article we show evidences that the N-terminus of the protein is involved in binding to the minor groove. Aspergillus nidulans est un champignon filamenteux capable d'utiliser l'éthanol comme source unique d'énergie. La protéine AlcR est responsable de l'activation de l'expression des gènes du régulon éthanol. Le domaine de liaison à l'ADN est situé dans la partie N-terminale de la protéine (a.a. 1 à 60), et sa structure déterminée par RMN en solution montre un repliement global en bouquet binucléaire à zinc, avec deux hélices supplémentaires par rapport au motif de base. Alors que les structures déjà connues de complexes ADN - bouquets binucléaires permettent de situer dans le grand sillon la quasi-totalité des interactions, nous montrons dans la présente étude l'implication du début de la séquence dans la reconnaissance du petit sillon de l'ADN (a.a. 5 et 6).

  14. Valence and magnetic state of transition-metal and rare-earth ions in single-crystal multiferroics RMn{sub 2}O{sub 5} (R = Y, Bi, Eu, Gd) from X-ray photoelectron spectroscopy data

    Energy Technology Data Exchange (ETDEWEB)

    Kozakov, A.T. [Scientific-Research Institute of Physics at Southern Federal University, 194 Stachki, Rostov-na-Donu 344194 (Russian Federation); Kochur, A.G., E-mail: agk@rgups.ru [Rostov State University of Transport Communication, 2 Narodnogo Opolcheniya, Rostov-na-Donu 344038 (Russian Federation); Nikolsky, A.V.; Googlev, K.A.; Smotrakov, V.G.; Eremkin, V.V. [Scientific-Research Institute of Physics at Southern Federal University, 194 Stachki, Rostov-na-Donu 344194 (Russian Federation)

    2011-11-15

    Highlights: {yields} Single crystals RMn{sub 2}O{sub 5} (R = Y, Bi, Eu, Gd) and YMnO{sub 3} are grown. {yields} Core level XPS are measured and calculated with inclusion of temperature effect. {yields} Mn2p, Mn3s, R4s, and R4d (R = Eu, Gd) XPS are sensitive to valence and spin state. {yields} Paramagnetic moments per structural cell are estimated. - Abstract: Single crystals of orthorhombic multiferroics RMn{sub 2}O{sub 5} (R = Y, Bi, Eu, Gd), and of hexagonal manganite YMnO{sub 3} are grown. X-ray photoelectron spectra of the core levels of the Mn, Y, Bi, Eu, Gd, and O atoms in multiferroics are obtained at room temperature with the ESCALAB 250 microprobe system with monochromatization of the exciting X-ray radiation. X-ray photoelectron spectra of Mn2p, Mn3s, R4s, and R4d (R = Eu, Gd) levels are assigned based on one-configuration isolated-ion approximation calculations with taking the temperature effect into account. It is shown using the photoelectron spectroscopy methods that both Mn{sup 3+} and Mn{sup 4+} ions are present in orthorhombic multiferroics, while Eu and Gd are in trivalent state. Paramagnetic moments per structural unit are calculated and compared with those determined from our spectroscopic data and with the data from other authors.

  15. SUSTENTABILIDAD URBANA PLANTEAMIENTOS TEORICOS Y CONCEPTUALES

    OpenAIRE

    Verónica Miranda Rosales

    2011-01-01

    El estudio del fenómeno ambiental en nuestras ciudades es fundamental para alcanzar una mejor calidad de vida de nuestra sociedad; el desarrollo sostenible busca aminorar los estragos de la urbanización acelerada y del modo de producción predominante. A pesar de que han surgido alternativas teóricas y conceptuales para caracterizar el fenómeno, como es el desarrollo sustentable, Ecodesarrollo, la Globalización y el Comercio Internacional y desarrollo urbano sustentable, éstas se consideran in...

  16. Theoretical model to determine the energy behavior of test modules at scale of constructions for the efficient use of energy; Modelo teorico para determinar el comportamiento energetico de modulos de prueba a escala de edificaciones para el uso eficiente de la energia

    Energy Technology Data Exchange (ETDEWEB)

    Acoltzi, Higinio; Alvarez, Gabriela [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2001-07-01

    In this work a theoretical model of the energy behavior of test modules and its experimental verification is presented. The model determines the history of electrical energy consumption to maintain the comfort conditions in the interior of the modules, with respect to the variation of the materials of ceilings and windows with the purpose of establishing criteria of application of these materials in the construction industry. The measured results of the consumption of the accumulated energy are presented. [Spanish] En este trabajo se presenta un modelo teorico del comportamiento energetico de modulos de prueba y su verificacion experimental. El modelo determina la historia del consumo de energia electrica para mantener las condiciones de confort al interior de los modulos, respecto a la variacion de los materiales de los techos y ventanas, con el objeto de establecer criterios de aplicacion de dichos materiales en la industria de la edificacion. Se presentan los resultados medidos del consumo de energia acumulada.

  17. Thickness calculation software of the thermal insulation in facilities using thermal solar energy; Software para el calculo de espesores del aislante termico en instalaciones de aprovechamiento de energia solar termica

    Energy Technology Data Exchange (ETDEWEB)

    Portillo Jimenez, Canek [Universidad Autonoma de Sinaloa, Culiacan, Sinaloa (Mexico)]. E-mail: cnk@uas.uasnet.mx

    2010-11-15

    It is presented a software application for calculating the thickness of the thermal insulation used in various facilities where there are thermal systems using solar energy. The software facilitates the calculation of the thermal cover thickness over components such as pipes (flat or round), storage and other devices that require thermal protection, installed in outdoors or indoors. The software was programmed in Visual Basic by following the technical specifications of the current regulations in the field. Application examples are performed, obtaining certain results that are discussed briefly. [Spanish] Se presenta un software de aplicacion para el calculo de los espesores de los aislantes termicos, utilizados en diferentes instalaciones donde existen sistemas de aprovechamiento termico de energia solar. El software facilita el calculo del grosor del recubrimiento termico en componentes tales como: tuberias (planas o circulares), depositos acumuladores y otros aparatos que necesiten proteccion termica, instalados en exteriores o en interiores. El software fue programado en Visual Basic siguiendo las especificaciones tecnicas de la normatividad vigente en la materia. Se realizan ejemplos de aplicacion, donde se obtienen ciertos resultados de los cuales se hace una breve discusion.

  18. Computer program for the calculation of stresses in rotary equipment discs; Programas de computo para el calculo de esfuerzos en discos de equipo rotatorio

    Energy Technology Data Exchange (ETDEWEB)

    Gutierrez Delgado, Wilson; Kubiak, Janusz; Serrano Romero, Luis Enrique [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1990-12-31

    In the preliminary design and diagnosis of rotary machines is very common to utilize simple calculation methods for the mechanical and thermal stresses, dynamic and thermodynamic analysis and flow of fluids in this machines (Gutierrez et al., 1989). The analysis with these methods provides the necessary results for the project initial stage of the machine. Later on, more complex tools are employed to refine the design of some machine components. In the Gutierrez report et al., (1989) 34 programs were developed for the preliminary design and diagnosis of rotating equipment; in this article, one of them is presented in which a method for the analysis of mechanical and thermal stresses is applied in discs of uniform or variable thickness that are normally found in turbomachines and rotary equipment. [Espanol] En el diseno preliminar y diagnostico de maquinas rotatorias es muy comun emplear metodos de calculo sencillos para el analisis de esfuerzos mecanicos y termicos, analisis dinamico y termodinamico y de flujo de fluidos en estas maquinas (Gutierrez et al., 1989). El analisis con estos metodos proporcionan los resultados necesarios para la etapa del proyecto inicial de la maquina. Posteriormente, para refinar el diseno de algunos componentes de la maquina, se aplican las herramientas mas complejas. En el informe de Gutierrez et al., (1989) se desarrollan 34 programas para el diseno preliminar y diagnostico de equipo rotatorio; en este articulo, se presenta uno de ellos, en el que se emplea un metodo para el analisis de esfuerzos mecanicos y termicos en discos de espesor constante o variable que se encuentran comunmente en turbomaquinas y en equipos rotatorios.

  19. Computer program for the calculation of stresses in rotary equipment discs; Programas de computo para el calculo de esfuerzos en discos de equipo rotatorio

    Energy Technology Data Exchange (ETDEWEB)

    Gutierrez Delgado, Wilson; Kubiak, Janusz; Serrano Romero, Luis Enrique [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1991-12-31

    In the preliminary design and diagnosis of rotary machines is very common to utilize simple calculation methods for the mechanical and thermal stresses, dynamic and thermodynamic analysis and flow of fluids in this machines (Gutierrez et al., 1989). The analysis with these methods provides the necessary results for the project initial stage of the machine. Later on, more complex tools are employed to refine the design of some machine components. In the Gutierrez report et al., (1989) 34 programs were developed for the preliminary design and diagnosis of rotating equipment; in this article, one of them is presented in which a method for the analysis of mechanical and thermal stresses is applied in discs of uniform or variable thickness that are normally found in turbomachines and rotary equipment. [Espanol] En el diseno preliminar y diagnostico de maquinas rotatorias es muy comun emplear metodos de calculo sencillos para el analisis de esfuerzos mecanicos y termicos, analisis dinamico y termodinamico y de flujo de fluidos en estas maquinas (Gutierrez et al., 1989). El analisis con estos metodos proporcionan los resultados necesarios para la etapa del proyecto inicial de la maquina. Posteriormente, para refinar el diseno de algunos componentes de la maquina, se aplican las herramientas mas complejas. En el informe de Gutierrez et al., (1989) se desarrollan 34 programas para el diseno preliminar y diagnostico de equipo rotatorio; en este articulo, se presenta uno de ellos, en el que se emplea un metodo para el analisis de esfuerzos mecanicos y termicos en discos de espesor constante o variable que se encuentran comunmente en turbomaquinas y en equipos rotatorios.

  20. PCRELAP5: data calculation program for RELAP 5 code; PCRELAP5: programa de calculo dos dados de entrada para o codigo RELAP5

    Energy Technology Data Exchange (ETDEWEB)

    Silvestre, Larissa Jacome Barros

    2016-07-01

    Nuclear accidents in the world led to the establishment of rigorous criteria and requirements for nuclear power plant operations by the international regulatory bodies. By using specific computer programs, simulations of various accidents and transients likely to occur at any nuclear power plant are required for certifying and licensing a nuclear power plant. Based on this scenario, some sophisticated computational tools have been used such as the Reactor Excursion and Leak Analysis Program (RELAP5), which is the most widely used code for the thermo-hydraulic analysis of accidents and transients in nuclear reactors in Brazil and worldwide. A major difficulty in the simulation by using RELAP5 code is the amount of information required for the simulation of thermal-hydraulic accidents or transients. The preparation of the input data requires a great number of mathematical operations to calculate the geometry of the components. Thus, for those calculations performance and preparation of RELAP5 input data, a friendly mathematical preprocessor was designed. The Visual Basic for Application (VBA) for Microsoft Excel demonstrated to be an effective tool to perform a number of tasks in the development of the program. In order to meet the needs of RELAP5 users, the RELAP5 Calculation Program (Programa de Calculo do RELAP5 - PCRELAP5) was designed. The components of the code were codified; all entry cards including the optional cards of each one have been programmed. In addition, an English version for PCRELAP5 was provided. Furthermore, a friendly design was developed in order to minimize the time of preparation of input data and errors committed by users. In this work, the final version of this preprocessor was successfully applied for Safety Injection System (SIS) of Angra 2. (author)

  1. Nuclear Calculations of Light-Water Moderated Reactors and Experimental Correlations; Calculs de Riacteurs Ralentis a l'Eau Ordinaire et Comparaison avec les Risultats Expirimentaux; Raschet reaktorov s zamedlitelem iz obychnoj vody i sravnenie s ehksperimental'nymi rezul'tatami; Calculos Nucleares de Reactores Moderados por Agua Ligera y Correlacion Experimental

    Energy Technology Data Exchange (ETDEWEB)

    Solanilla, R. [Comision Nacional de Energia Atomica, Buenos Aires (Argentina)

    1964-02-15

    nombreuses geometries - faite par comparaison avec certains des principaux parametres d'un reseau y/o de multiplication effective, est satisfaisante, l'ecart entre la reactivite obtenue par le calcul et le chiffre donne par l'experience,n'etant pas, en general, superieur a 2%. (author) [Spanish] Con el empleo de la teoria de dos grupos modificados por fisiones epitermales, se ha analizado un conjunto de sistemas criticos dotados de reflector y moderador de agiia liviana y variado enriquecimiento en {sup 235}U del combustible nuclear. Las secciones eficaces del grupo termal empleadas son las consignadas en las Tablas de Amster para mezclas hidrogenadas a diferentes temperaturas; concentraciones de {sup 235}U y absorbedores en 1/v. El efecto de heterogeneidad en las secciones eficaces ha sido tratado aproximadamente modificando las concentraciones de los absorbedores por variacion espacial del flujo termico en la celda elemental. El factor de desventaja ha sido calculado empleando la formula de Amouyal-Benoist. El coeficiente de difusion termal ha sido definido como la inversa del triple de la seccion eficaz macroscopica de transporte homogeneizada sobre el volumen de la celda elemental. Las constantes del grupo rapido han sido calculadas'de acuerdo al esquema de Ombrellaro de tres grupos rapidos de difusion (10 MeV a 0,821 MeV; 0,821 MeV a 5,5 keV; 5,5 keV a 0,625 eV) con secciones eficacesmicroscopicas ajustadas para cada grupo. La definicion de Ombrellaro de las constantes neutionicas de los tres,grupos rapidos en funcion de las secciones eficaces ajustadas ha sido modificada para el tercer grupo de acuerdo al tratamiento de Hick de la absorcion efectiva de resonancia del {sup 238}U, basada en el computo de la integral de resonancia efectiva. Los calculos han sido realizadas computando la integral de resonancia efectiva del: {sup 238}U por la formula obtenida, por el autor, del calculo teorico, con reduccion de la relacion S/M de acuerdo a la aproximacion del Bell del

  2. Caracterização de nanocompósitos de poliuretano/montmorilonita organofílica por RMN de baixo campo Characterization of polyurethane/organophilic montmorilonite nanocomposites by low field NMR

    Directory of Open Access Journals (Sweden)

    Marcos Anacleto da Silva

    2012-01-01

    Full Text Available Poliuretanos são materiais poliméricos importantes e versáteis, principalmente devido a algumas de suas propriedades, como alta resistência à abrasão, resistência ao rasgo, excelente absorção de choques mecânicos, boa flexibilidade e elasticidade. No entanto, existem também algumas desvantagens, como a baixa estabilidade térmica e propriedade de barreira. Para superar essas desvantagens, têm sido produzidos nanocompósitos de poliuretano/montmorilonita organofílica. A investigação da estrutura dos nanocompósitos de poliuretano/argila tem sido realizada principalmente por difração de raios X (DRX e microscopia eletrônica de transmissão (TEM. Neste trabalho, foram estudados filmes de nanocompósitos de PU/argila organofílica obtidos por intercalação por solução. Os nanocompósitos foram caracterizados por DRX e, principalmente, por ressonância magnética nuclear de baixo campo (RMN-BC. As medidas de RMN-BC, com a determinação do tempo de relaxação spin-rede do núcleo de hidrogênio, forneceram informações ímpares e importantes sobre a dinâmica molecular desses nanocompósitos. Para validar esse estudo foram realizadas análises de difração de raios X, que confirmaram os resultados de RMN. A estabilidade térmica dos materiais também foi determinada por análise termogravimétrica em atmosfera de gás inerte, observando-se pequena melhora na estabilidade do nanocompósito quando comparado com o poliuretano.Polyurethanes are important and versatile materials, mainly due to some of their properties, such as high resistance to abrasion and tearing, excellent absorption of mechanical shocks and good flexibility and elasticity. However, they have some drawbacks as well, such as low thermal stability and barrier properties. To overcome these disadvantages, various studies have been conducted involving organophilic polyurethane/montmorillonite nanocomposites. The investigation of the structure of polyurethane

  3. Torque calculation in the induction motor with the finite element method; Calculo del par en el motor de induccion con el metodo del elemento finito

    Energy Technology Data Exchange (ETDEWEB)

    Castillo Diaz, Ramon

    2002-06-15

    In this work the method of the finite element is applied to the bi-dimensional analysis of the induction motor in operation in steady state, excited by sine sources of laminar currents and sine sources of voltage. The analysis is focused mainly in the calculation of the electromagnetic torque. The topics of electromagnetic theory are covered and in an idealized model of the induction motor, analytically and numerically with the method of the finite element, in the variant method of Galerkin, the vectorial potential and the torque are calculated. The results obtained with the analytical and numerical methods are compared. Three formulations are developed to calculate the torque with the method of the finite element, using triangular elements of first order, based in the equation of force of Lorentz, the Maxwell tensor and the principle of the virtual work. Finally, a motor of induction of real characteristics is simulated, assuming it is connected to a three-phase voltage source. In this motor it is analyzed the convergence and the evolution in the results obtained of the torque with different discretions, and the torque-velocity performance curve is calculated. [Spanish] En este trabajo se aplica el metodo del elemento finito al analisis bidimensional del motor de induccion en operacion en estado estable, excitado por fuentes de corriente laminar senoidales y fuentes de voltaje senoidales. El analisis se enfoca principalmente en el calculo del par electromagnetico. Se tratan los topicos de teoria electromagnetica involucrados y en un modelo idealizado del motor de induccion, se calculan analitica y numericamente con el metodo del elemento finito, en la variante metodo de Galerkin, el potencial vectorial y el par. Se comparan resultados obtenidos con los metodos analiticos y numericos. Se desarrollan tres formulaciones para calcular el par con el metodo del elemento finito, utilizando elementos triangulares de primer orden, basadas en la ecuacion de fuerza de

  4. IDENTIFICAÇÃO DE PRODUTOS DA OXIDAÇÃO DE ÓLEOS COMESTÍVEIS ATRAVÉS DA ESPECTROSCOPIA DE RMN DE 1H / IDENTIFICATION OF OXIDATION PRODUCTS IN EDIBLE OIL BY MEANS OF 1H NMR SPECTROSCOPY

    Directory of Open Access Journals (Sweden)

    MARINA COLZATO

    2009-11-01

    Full Text Available A espectroscopia por ressonância magnética nuclear de 1H de alta resolução (RMN de 1H é uma ferramenta útil para monitorar os produtos de oxidação em óleos comestíveis. O método é rápido, relativamente simples e preciso, permitindo o acompanhamento e a caracterização da formação de produtos primários de oxidação, como os hidroperóxidos e os dienos conjugados. Neste trabalho, óleos de canola, azeite de oliva e de macadâmia foram objetos de oxidação acelerada por 30 dias e os produtos de oxidação avaliados por RMN de 1H. Os resultados indicaram uma maior estabilidade (resistência ao estresse térmico, para o óleo de oliva > macadâmia > canola, respectivamente.

  5. Calculation of economic viability of alternative energy sources considering its environmental costs for small communities of Northeast Brazil; Calculo de viabilidade economica de fontes alternativas de energia considerando seus custos ambientais para pequenas comuidades da regiao nordeste brasileira

    Energy Technology Data Exchange (ETDEWEB)

    Stecher, Luiza Chourkalo

    2014-09-01

    There has been an increasing concern about current environmental issues caused by human activity, as the world searches for development. The production of electricity is an extremely relevant factor in this scenario since it is responsible for a large portion of the emissions that cause the greenhouse effect. Due to this fact, a sustainable development with alternative energy sources, which are attractive for such purpose, must be proposed, especially in places that are not supplied by the conventional electricity grid such as many communities in the Northeast Brazil. This work aims to calculate the environmental cost for the alternative sources of energy - solar, wind and biomass - during electricity generation, and to estimate the economic feasibility of those sources in small communities of Northeast Brazil, considering the avoided costs. The externalities must be properly identified and valued so the costs or benefits can be internalized and reflect accurately the economic feasibility or infeasibility of those sources. For this, the method of avoided costs was adopted for the calculation of externalities. This variable was included in the equation developed for all considered alternative energy sources. The calculations of economic feasibility were performed taking the new configurations in consideration, and the new equation was reprogrammed in the Programa de Calculo de Custos de Energias Alternativas, Solar, Eolica e Biomassa (PEASEB). The results demonstrated that the solar photovoltaic energy in isolated systems is the most feasible and broadly applicable source for small communities of Northeast Brazil. (author)

  6. COMUNICACIÓN EN SALUD: CONCEPTOS Y MODELOS TEORICOS

    Directory of Open Access Journals (Sweden)

    Iván Ríos Hernández

    2011-01-01

    Full Text Available A través de este artículo de revisión de tema se analiza el concepto comunicación en salud y algunas de las definiciones esbozadas hasta el momento por organismos internacionales y expertos del tema. Se presenta una mirada crítica y reflexiva sobre algunos de los principales modelos teóricos desarrollados en el campo de la comunicación en salud. Se esboza un análisis del paradigma de la Comunicación para el Cambio Social y se compara con las otras teorías y modelos de comunicación en salud discutidos en el escrito. Luego del análisis reflexivo se concluye que el apoderamiento de las comunidades en las estrategias de prevención de enfermedades, representa un reto para los estudios concernientes a las teorías y modelos que tratan de explicar de forma simplificada los elementos inmersos en un proceso de comunicación en salud.

  7. Reinvestigación de la formación de alquinilciclopropanocarbonitrilos a partir de complejos carbeno de Fischer: Diastereoselectividad y Mecanismo

    OpenAIRE

    Solis Moreno, Guillermo

    2015-01-01

    La reinvestigación de la síntesis de los alquinilciclopropanocarbonitrilos ha permitido corregir la configuración asignada al diastereoisómero mayoritario de la reacción, en la publicación original a través de experimentos de RMN de NOE y NOESY. Adicionalmente, aparece detallado el mecanismo de la reacción estudiado a través de calculos computacionales.

  8. Fósforo num Cambissolo cultivado com cana-de-açúcar por longo tempo: II - análise de ácidos húmicos por RMN 31P Phosphorus in an Inceptsoil under long-term sugarcane: II - humic acid analysis by NMR 31P

    Directory of Open Access Journals (Sweden)

    Jader Galba Busato

    2005-12-01

    Full Text Available Sistemas de manejo da lavoura de cana-de-açúcar que favoreçam a matéria orgânica do solo podem aumentar o conteúdo de nutrientes disponíveis e diminuir a necessidade de aplicação de fertilizantes industriais. Apesar da importância dos componentes orgânicos no fornecimento de P, pouco se conhece sobre a sua dinâmica em ambientes tropicais. O objetivo deste trabalho foi identificar, por meio da ressonância magnética nuclear (RMN 31P, as espécies de P nos ácidos húmicos de um Cambissolo Háplico Ta eutrófico vértico, localizado no Município de Campos dos Goytacazes, norte do Estado do Rio de Janeiro, e cultivado com cana-de-açúcar com preservação do palhiço e adição de vinhaça por longo tempo. Por meio da análise de RMN 31P foi possível observar acúmulo de P orgânico em formas mais facilmente mineralizadas nas áreas com preservação de matéria orgânica, tal como P em ligações diésteres. Nas áreas de cana queimada, houve maior participação de espécies orgânicas mais estáveis, como o ortofosfato em ligações monoésteres. Os resultados da espectroscopia de RMN 31P mostram que, nas áreas com maior aporte de resíduo orgânico (i.e., cana crua e cana queimada com adição de vinhaça, os ácidos húmicos constituem uma reserva importante de P orgânico prontamente disponível. Já, nas áreas de cana queimada, o acúmulo de P orgânico recalcitrante nos ácidos húmicos indica utilização do P-lábil das substâncias húmicas como fonte importante para nutrição das plantas.Crop management systems that favor soil organic matter can improve the available nutrient content for plants and reduce the use of industrial fertilizer. Despite the importance of organic compounds as a P source, little is known about its dynamics in tropical environments. The objective of this study was to identify organic P species present in humic acids by NMR 31P analysis in a fine clay Fluventic Eutrochrepts in Campos dos

  9. Validation of Hiriart equation to compute steam production by the lip pressure method; Validacion de la ecuacion de Hiriart para calculo de gasto de vapor por el metodo de presion de labio

    Energy Technology Data Exchange (ETDEWEB)

    Flores Armenta, Magaly [Gerencia de Proyectos Geotermoelectricos de la Comision Federal de Electricidad, Morelia (Mexico)

    1996-09-01

    Mainly in new geothermal wells, it is necessary to evaluate the production in a very fast, simple and not expensive way, to know the convenience to install surface equipment, such as silencers and separators, to drive the steam to the commercial gathering system. In practice, one of the most known methods is the lip pressure one, which requires a simple set of installations. The objective of this paper is to validate the steam flow rate calculated by the lip pressure method, with respect to the ASME method. The ASME method is known for its accuracy, and is done by measuring the steam and liquid after a high pressure separator, by an orifice plate of known diameter and a triangular weir. Results of the validation show up the feasibility of application of the lip pressure method by using a simple adjustment equation. Percentage of mistake results less than 1%, without any notable influence of the production enthalpy. That equation to be applied in a general case, is as follows: Q{nu} =(20642)(F*P*D{sup 2}/{radical}h-2000). For the particular case of the Los Azufres geothermal field, the equation is: Q{nu}= 810*P*D{sup 2} [Espanol] En los pozos geotermicos, principalmente en los nuevos, es necesario evaluar su produccion de manera rapida, sencilla y economica, para determinar la conveniencia de instalar equipo superficial, como separadores, silenciadores, etc., que permita la integracion del vapor al sistema comercial de generacion electrica. Para fines practicos uno de los metodos mas conocidos es el de presion de labio, que solo requiere un arreglo sencillo de instalaciones superficiales. En este documento se validan y ajustan los calculos de produccion de vapor por ese metodo de presion de labio, con respecto a las mediciones exactas efectuadas con el metodo ASME. Este ultimo es reconocido internacionalmente por su precision, y se lleva a cabo separando la mezcla obtenida en superficie en un recipiente a presion para medir el vapor a traves de una placa de orificio

  10. Calculation of the temperature distribution and thermal stresses in a gas turbine nozzle cooled by air film; Calculo de la distribucion de temperaturas y esfuerzos termicos en una tobera de turbina de gas enfriada por pelicula de aire

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez R, Alejandro; Garcia I, Rafael; Mazur C, Zdislaw [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2004-07-01

    temperaturas. Con las temperaturas correctamente importadas, se realizaron las simulaciones para el calculo de los esfuerzos termicos en la tobera.

  11. A review of calculation methods for fast and intermediate reactors; Expose des methodes pour le calcul de reacteurs a neutrons rapides et intermediaires; Obzor metodov rascheta reaktorov na promezhutochnykh i bystrykh nejtronakh; Estudio panoramico de los metodos de calculo de los reactores rapidos e intermedios

    Energy Technology Data Exchange (ETDEWEB)

    Marchuk, G I [Akademiya Nauk, Moskva, Union of Soviet Socialist Republics (Russian Federation)

    1962-03-15

    This paper discusses the development of methods for calculating intermediate and fast reactors. It deals with various approaches to the problems of physical calculation. The calculation of resonance effects is discussed. Consideration is given to multi-group systems of fundamental and conjugate equations, various applications of perturbation theory to the problems of physical reactor calculation, and numerical methods of solving fundamental and conjugate reactor equations, which approximate the method of spherical harmonics. The paper describes an application of the response method to the solution of critical-mass problems, and methods of calculating reactors with hydrogeneous moderators. The fundamental features of an effective one-group reactor model are described. (author) [French] L'auteur examine la mise au point de methodes pour le calcul de reacteurs a neutrons rapides et intermediaires . Il decrit diverses manieres d'aborder les problemes des calculs sur la physique des reacteurs, notamment le calcul des effets de resonance. Il s'attache particulierement aux points suivants: systemes d'equations fondamentales et conjuguees a plusieurs groupes; diverses applications de la theorie des perturbations aux problemes de calculs sur la physique des reacteurs; methodes numeriques pour resoudre les equations fondamentales et conjuguees, voisines de la methode des harmoniques spheriques. L'auteur decrit ensuite une maniere d'appliquer la methode de la reponse aux problemes de la masse critique ainsi que des methodes pour le calcul de reacteurs ralentis a l'hydrogene. Il decrit les caracteristique s fondamentale s d'un modele de reacteur a un groupe effectif. (author) [Spanish] El autor analiza el desarrollo de los metodos de calculo de los reactores nucleares que trabajan con neutrones rapidos y con neutrones intermedios. Examina diversos planteos de los problemas del calculo fisico. Indica la forma de tomar en cuenta los efectos de resonancia y menciona los sistemas

  12. Critical experiments and nuclear calculations - LAMPRE-I; Experiences critiques et calculs nucleaires concernant le LAMPRE-I; Kriticheskie opyty i yadernye raschety - LAMPRE-I; Experimentos criticos u calculos nucleares relativos al LAMPRE-I

    Energy Technology Data Exchange (ETDEWEB)

    Battat, M E [Los Alamos Scientific Laboratory, University of California, Los Alamos, NM (United States)

    1962-03-15

    utilise la methode S{sub n} pour resoudre le probleme du transport neutronique. La comparaison entre les valeurs calculees et les valeurs mesurees des parametres, tels que le coefficient thermique, l'efficacite des barres de controle et la masse critique, presente aussi de l'interet pour evaluer le degre de confiance que l'on peut accorder aux calculs des bureaux d'etudes. (author) [Spanish] Como parte de un programa de ensayos de combustibles de plutonio para reactores reproductores de neutrones rapidos, se ha construido y puesto en marcha en el Los Alamos Scientific Laboratory un reactor experimental de 1 MW refrigerado por sodio, cuyo cuerpo contiene una aleacion fundida de plutonio y hierro (90 atomos por ciento de Pu y 10 atomos por ciento de Fe; punto de fusion: 410 deg. C). La reactividad se regula por medio de un reflector de acero inoxidable y de cuatro barras de control de niquel situadas fuera del nucleo. Se han llevado a cabo experimentos a temperaturas (isotermicas) de 80, 160 y 480 deg. C en el cuerpo, a fin de determinar la masa critica y la eficacia del reflector a cada una de esas temperaturas. Tambien se midio la eficacia de las barras de control, por registro de los periodos y del coeficiente termico de la reactividad. Aplicando el metodo S{sub n} de resolucion del problema del transporte neutronico, se efectuaron calculos para determinar los parametros nucleares basicos del reactor. La comparacion entre los valores calculados y los valores medidos de parametros tales como el coeficiente termico, la eficacia de las barras de control y la masa critica, presenta tambien interes en lo que se refiere a la evaluacion del grado de confianza que puede atribuirse a los calculos del proyectista. (author) [Russian] V kachestve chasti programmy po razvitiyu plutonievogo topliva dlya reaktorov-razmnozhitele j na bystrykh nejtronakh Los-Alamosskaya nauchnaya laboratoriya skonstruirovala i ehkspluatiruet ispytatel'nyj reaktor s natrievym okhlazhdeniem moshchnost'yu v

  13. Manifestations of spine infections for RMN; Manifestaciones de infecciones de columna por RMN

    Energy Technology Data Exchange (ETDEWEB)

    Mejia, Mauricio; Valencia, Alexandra

    1998-12-01

    Instead of demonstrate the utility and benefits of MRI imaging in infectious processes of the spine, 8 patients with lumbar pain affected by spondilodiscitis were studied. T1 SE, T2, SE with and without fat sat and proton density imaging was performed, axial; sagittal and coronal views were obtained. Contrast media was used in 1 Patient. hypointense lesions in T1 and hyperintense lesions in T2 compatible with esponsilodiscitis were observed in every patient. Images with great anatomic detail of bone and soft tissue structures were obtained. MRI is an alternative diagnostic method with multiplanar images and excellent contrast that permits a precise diagnosis in any of the stages of infectious processes of the spine.

  14. Measurements and Calculations of the Slowing-Down and Migration Time; Mesures et Calcul du Temps de Ralentissement et de Migration; Izmereniya i raschety vremeni zamedleniya i migratsii; Medicion y Calculo del Tiempo de Moderacion y de Migracion

    Energy Technology Data Exchange (ETDEWEB)

    Profio, A. E.; Koppel, J. U. [General Atomic Division of General Dynamics Corporation, John Jay Hopkins Laboratory for Pure and Applied Science, San Diego, CA (United States); Adamantiades, A. [Massachusetts Institute of Technology, Cambridge, MA (United States)

    1965-08-15

    transcurre hasta que la velocidad de los neutrones pulsados disminuya en la medida necesaria para que estos alcancen la energia, el angulo y la posicion de observacion apetecidas. El tiempo medio es una correccion de las mediciones de espectros neutronicos en la masa hechas segun el metodo del tiempo de vuelo, y la variacion impone limites al poder de resolucion efectivo de tales experimentos. Estos parametros son igualmente importantes en los detectores cuyo funcionamiento se base en la moderacion, en los experimentos con el metodo de tiempo de vuelo en los que un moderador situado cerca de la fuente de neutrones pulsados proporciona neutrones de baja energia, y en la espectrometria del tiempo de moderacion. Se han ideado diversos metodos analfticos y numericos para calcular la distribucion espacio-energia angulo-tiempo o sus integrales. Ha podido demostrarse que los momentos temporales Empty-Set {sup (n)} (r, {Omega}, v, t) = {integral}{sub 0}{sup {infinity}}t{sup n} Empty-Set (r, {Omega}, v, t)dt, pueden calcularse aplicando repetidamente una clave de transporte en regimen estacionario. El termino de la fuente para el calculo del momento 'n'es igual a nv{sup -1} Empty-Set {sup (n-1)}. Los autores presentan los resultados correspondientes a maquetas del reactor TRIGA en las que se emplean medios multiplicadores y no multiplicadores. Otro valioso metodo de calculo consiste en emplear una clave de Monte Cario en funcion del tiempo. Los autores exponen los resultados del calculo de un flujo que escapa de una delgada placa de plomo. Se han hecho mediciones del tiempo de moderacion hasta la energia de corte del Cd y hasta la resonancia de 1,46 eV del In en agua y en tolueno. Los rayos gamma de captura se detectaron con un contador de centelleo. Esta tecnica exige disponer de una fuente de suficiente intensidad y de un detector eficaz debido a la brevedad del ciclo de trabajo (escasa anchura de las rafagas para la resolucion del tiempo de moderacion y amplio intervalo entre los

  15. Theoretical Studies of Electron Injection and E-Layer Build-Up in Astron; Etudes Theoriques sur l'Injection d'Electrons et la Formation de la Couche E dans l'Astron; Teoreticheskie izucheniya ehlektronnoj inzhektsii i narashchivaniya sloya-E v ustanovke ''Astron''; Estudios Teoricos de Electrones y Formacion de la Capa E en la Instalacion Astron

    Energy Technology Data Exchange (ETDEWEB)

    Killeen, J.; Neil, V. K.; Heckrotte, W. [Lawrence Radiation Laboratory, Livermore, CA (United States)

    1966-04-15

    disipacion de energia. Los autores estudiaron teoricamente un modelo unidimensional del dispositivo Astron. Calcularon analiticamente las funciones de Green representativas de los campos propios electrico y magnetico, y las incorporaron a la ecuacion de Vlasov que rige el movimiento axial de los electrones. Los resultados de los calculos permiten establecer una comparacion cualitativa con los resultados experimentales obtenidos mediante la instalacion Astron. Tal como se suponia, los electrones atrapados forman una capa cilindrica de intensidad suficiente para que el campo magnetico propio sea comparable con el campo aplicado. El modelo matematico que explica la formacion de la capa electronica y del campo propio es la ecuacion de Vlasov en funcion del tiempo, unida a las ecuaciones de Maxwell. El.sistema tiene simetria axial y se supone electricamente neutro. Los componentes del campo B{sub r} y B{sub z} pueden deducirse a partir de una funcion de flujo {psi} (r, z, t). El momento angular canonico es una constante del movimiento, lo que permite considerar una funcion de distribucion de los electrones del tipo f{sub e} (r, z, P{sub r}, P{sub z}). Las ecuaciones diferenciales parciales en f{sub e} y {psi} se resuelven numericamente usando el metodo de las diferencias finitas. El espacio de las fases consiste en mas de 160 000 puntos, a saber 81 en z, 12 en r, 19 en P{sub z} y 9 en P{sub r} . En cada paso, la integracion de f{sub e} en el espacio de las cantidades de movimiento da la densidad de corriente j{sub {theta}} (r, z, t); el campo propio se calcula luego resolviendo la ecuacion para {psi} (r, z, t). Los autores presentan una serie de experimentos correspondientes a varios campos magneticos en el vacio y distintas condiciones de inyeccion. Las distribuciones de electrones obtenidas difieren sensiblemente segun cual sea el campo de espejo aplicado. En todos estos experimentos se forman regiones de B mfnimo y algunos se han desarrollado lo suficiente como para lograr la

  16. Calculation of attenuation by rain using the DAH model and diameter of antennas for the Ka Band in Mexico; Calculo de atenuacion por lluvia usando el modelo DAH y diametro de antena para Banda Ka en Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Landeros-Ayala, S.; Neri-Vela, R; Cruz-Sanchez, H.; Hernandez-Bautista, H. [Universidad Nacional Autonoma de Mexico, Mexico, D.F. (Mexico)

    2002-03-01

    Fatim Haidara), combinado con los mapas globales de distribucion de lluvia de Crane, para el calculo de la atencion por lluvia en sistema de comunicacion por satelite que operen en la Banda Ka. Ademas, se proponen diametros de antena para los sistemas de comunicaciones en Banda Ka en diferentes localidades de la Republica Mexicana, empleando para ello, los margenes de atencion por lluvia obtenidos a trav del Modelo DAH, y usando como referencia las caracteristicas del satelite de comunicaciones ANIK F2 y de una estacion terrena VSAT.Se muestra una fig. de la atenuacion por lluvia a 27.5 gHz y de los diametros de antena para banda Ka en Mexico. Se da una tabla de la atenuacion por lluvia a 29.5 GHz y a 20.2 GHz.

  17. Systems for the calculation of electrical parameters and energy efficiency for high-capacity hydroelectric generators; Sistemas para el calculo de parametros electricos y eficiencia energetica para generadores hidroelectricos de gran capacidad

    Energy Technology Data Exchange (ETDEWEB)

    Reyes Martinez, Oscar Alfonso; Pascacio de los Santos, Alberth; Perez Abad, Carlos Alberto [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico); Leon Rivera, Nicolas [CFE-LAPEM, Irapuato, Guanajuato (Mexico)

    2012-07-01

    construccion es la Central Hidroelectrica La Yesca, el cual concluira a finales de 2012 y consiste en dos generadores electricos de 375 MW, 17 kV. Sera el segundo en potencia y el tercero en generacion electrica en el sistema. De acuerdo con las normas nacionales e internacionales, debe efectuarse un conjunto de pruebas estaticas y dinamicas en estos generadores antes de la puesta en servicio, para asegurar su operacion apropiada. La prueba de resistencia de alto voltaje del devanado del estator, la prueba de corto circuito subito trifasico y el calculo de eficiencia energetica son algunas de las pruebas mas importantes por realizar en un nuevo generador electrico. Estas pruebas son dificiles de efectuar en sitio debido a la capacidad del equipo requerido, por lo que muy pocas companias en el mundo pueden conducirlas.

  18. Theoretical and Applied Aspects of Radiation D-Values for Spores of Clostridium Botulinum; Aspects Theoriques et Pratiques des Valeurs D de Rayonnement Appliquees aux Spores de Clostridium Botulinum; Teoreticheskie i prikladnye aspekty koehffitsienta izlucheniya odlya spor Clostridium Botulinum; Aspectos Teoricos y Practicos de los Valores D para Esporas del Clostridium Botulinum

    Energy Technology Data Exchange (ETDEWEB)

    Grecz, N. [Biophysics Laboratory, Illinois Institute Of Technology, Chicago, IL (United States)

    1966-11-15

    los alimentos por irradiacion. La copiosa informacion obtenida por los autores en su laboratorio ha puesto de manifiesto: a) que el valor D{sup 10} de una determinada cepa depende de la temperatura, del medio y de la cantidad de inoculo de esporas, y b) que segun el metodo de calculo empleado y como consecuencia de variaciones desconocidas entre un experimento y otro, pueden obtenerse valores D fundamentalmente distintos. Esta informacion justifica una reevaluacion del concepto de 12 X D. Puede demostrarse que la temperatura empleada durante la irradiacion influye indirectamente, de distintas formas, sobre los radicales: a) su formacion;, b) reactividad quimica; c) duracion del recocido y d) difusion, particularmente durante la transicion de lfquido a solido del medio en torno a los 0 Degree-Sign C. La combinacion de estos efectos, que son funcion de la temperatura, explica por que las esporas son mas sensibles cuando se las irradia a 0 Degree-Sign C que cuando se emplean temperaturas mas altas o mas bajas. Ademas de sus efectos sobre los radicales, la temperatura afecta tambien, directamente, a los blancos esenciales (ADN). En esto interviene el estado vibracional asf como el grado de hidratacion de las moleculas de ADN. La hidratacion aparente del.ADN esta relacionada con el intervalo de accion de los efectos indirectos, que para el C. botulinum 33A puede calcularse que anade 30 A al radio del ADN (10, 5A), es decir, casi se, triplica el efecto de la radiacion. Esta variacion del volumen radiosensible se refleja en-un cambio correspondiente del valor D{sub 37}, que pasa de 1,6 x 10{sup 5} rad para las esporas secas a 6,6 x 10{sup 4} rad para las esporas humedas. El medio de suspension puede competir por los radicales (por ejemplo: la mayoria de los alimentos y de los medios microbiologicos son depuradores de radicales), o facilitar la formacion de radicales per judiciales (por ejemplo: el fosfato amortiguador forma acido fosffnico y el oxfgeno forma radicales

  19. Caracterização de acetato de celulose obtido a partir do bagaço de cana-de-açúcar por ¹H-RMN 1H-NMR characterization of cellulose acetate obtained from sugarcane bagasse

    Directory of Open Access Journals (Sweden)

    Daniel A. Cerqueira

    2010-06-01

    Full Text Available A celulose do bagaço de cana-de-açúcar foi usada para sintetizar acetato de celulose com diferentes graus de substituição, os quais foram caracterizados por ¹H-RMN através da relação entre as áreas dos picos dos átomos de hidrogênio presentes nos grupos acetato (-(C=OOCH3 e os picos dos hidrogênios ligados aos átomos de carbono dos anéis glicosídicos. A supressão de alguns sinais foi feita para remover sinais de ressonância da água residual nos materiais e também para remover sinais de impurezas no triacetato de celulose. Um método de deconvolução para o cálculo computacional do grau de substituição foi proposto. Os graus de substituição das amostras de acetato de celulose foram 2,94 e 2,60, o que está de acordo com os resultados por determinação química através de uma titulação ácido base.Cellulose from sugarcane bagasse was used for synthesizing cellulose acetate with different degrees of substitution, which were characterized by ¹H-NMR through the relationship between the peak areas of the hydrogen atoms of the acetate groups (-(C=OOCH3 and the peaks of the hydrogen bonded to the carbon atoms of the glucosidic rings. Suppression of some signals was carried out in order to remove the residual water resonance in the materials and those related to impurities in cellulose triacetate as well. A deconvolution method for the computation of the degree of substitution of acetylation is proposed. The degrees of substitution for the cellulose samples were 2.94 and 2.60, in good agreement with those obtained by chemical determination through an acid-base titration.

  20. Use of Pulsed Nmr Spectroscopy to Measure the Amount of Solid Deposits As a Function of Temperature in Waxy Crudes Utilisation de la spectroscopie RMN pulsée pour mesurer la quantité de dépôts solides en fonction de la température dans les bruts paraffiniques

    Directory of Open Access Journals (Sweden)

    Ruffier-Meray V.

    2006-12-01

    Full Text Available Paraffin crystallization in crude oils and in gas condensates is a major problem for petroleum exploitation. Thermodynamic models are used to evaluate the risk. With them, one calculates the Wax Appearance Temperature (WAT as well as the crystallized fraction as a function of temperature, for temperatures below the WAT. During development, these models are tested against experimental data. Although different methods for measuring the WAT are available in the literature and at petroleum companies, such methods unfortunately do not exist for measuring the crystallized fraction as a function of temperature. In this work, we have developed a low resolution NMR method for measuring the crystallized fraction as a function of temperature. The method was first evaluated using pure samples and was then applied to crude oils. The results were compared to those obtained both from differential calorimetry and from the model. La cristallisation des paraffines dans les pétroles bruts et même dans les gaz à condensat est un problème majeur dans le domaine de l'exploitation pétrolière. Afin d'évaluer ce risque, on utilise des modèles thermodynamiques. Ils permettent de calculer la température de cristallisation commençante (TCC ou Wax Appearance Temperature (WAT ainsi que la fraction cristallisée en fonction de la température (pour des températures inférieures à la TCC. Lors de leur développement, ces modèles doivent être évalués sur des données expérimentales. Il existe dans la littérature et chez les pétroliers différentes méthodes pour mesurer la TCC, malheureusement il n'en est pas de même pour la fraction cristallisée en fonction de la température. Dans cet article, nous avons développé une méthode de RMN basse résolution afin de mesurer la fraction cristallisée en fonction de la température. Elle a d'abord été évaluée sur des mélanges de corps purs puis elle a été appliquée à des pétroles bruts. Les r

  1. Caracterização dos constituintes poliméricos da Maytenus ilicifolia por relaxação nuclear de ¹H por RMN no estado sólido Characterization of Maytenus ilicifolia Samples by ¹H NMR relaxation in the solid state

    Directory of Open Access Journals (Sweden)

    Mônica S. de M. Preto

    2011-01-01

    Full Text Available A Maytenus ilicifolia, conhecida como espinheira-santa, é uma planta popular de uso diverso, como chá é empregada no combate a problemas de doenças gástricas e da diabetes, por exemplo. As plantas possuem em sua constituição polímeros naturais como polissacarídeos, politerpenoides, celulose e fibras. O estudo dos constituintes poliméricos nesse tipo de material tem importância fundamental tanto na identificação, ou seja, qualificação quanto na adulteração da planta. É sabido que podem ser encontrados diversos produtos rotulados como sendo originário da mesma planta, entretanto, muitas das vezes a origem da planta é similar, mas não a mesma, o que pode gerar algum desconforto ou não atividade biológica dos chás quando da ingestão destes. Na literatura não são encontrados muitos trabalhos que envolvam a caracterização comparativa dos constituintes poliméricos, como polissacarídeos e fibras presentes em amostras de origens distintas, para comprovação de adulteração destes produtos. Uma técnica que pode ser promissora para este tipo de estudo é a Ressonância Magnética Nuclear (RMN em estado sólido, já que permite analisar a amostra in natura não sendo um método destrutivo ou invasivo. Esta espectroscopia analisa amostras em campos magnéticos de diferentes potências ou forças. Neste trabalho é apresentado um estudo de caracterização dos constituintes poliméricos majoritários presentes na M. ilicifolia. Três amostras foram estudadas: uma amostra denominada controle e duas comerciais. O estudo envolveu a determinação dos tempos de relaxação spin-rede (T1 do ¹H utilizando a técnica de campo cíclico rápido (FFC, numa gama de frequências que variou de 100 kHz a 10 MHz. Assim, o principal objetivo deste trabalho foi estudar a possibilidade de utilização da RMN de baixo campo magnético na elaboração de um método expedito de análise que permita realizar a caracterização estrutural

  2. Development of a human body RMN imaging device

    International Nuclear Information System (INIS)

    Saint-Jalmes, H.

    1984-03-01

    Imaging device for human body is studied in this thesis. The section images presented are got by a projection-reconstruction method associated to a section plane selection by an oscillating gradient application. Different stages of the machine development are presented: - design and calculation of a resistive magnet for very homogeneous field imaging - design of gradient coils for imaging magnets - realization of control and acquisition interfaces - realization of imaging software in real time [fr

  3. Definizione, modellazione teorico – sperimentale ed energy management di sistemi termo – fotovoltaici a concentrazione

    OpenAIRE

    Petito, Fabio

    2017-01-01

    2015 - 2016 The evolution in the renewable energies field led to search for solutions that allow the combined achievement of heterogeneous energy vectors. This theme introduces multiple levels of analysis, from the definition of new systems and the environmental impact analysis to the overall economic performances, in the traditional cost – benefit paradigm. In this context, the Green Renewable Technologies redefines the concept of innovative solution, as they represent a choice based o...

  4. ESTUDIO CONFORMACIONAL EN ALGUNAS 1,3-OXAZINAS Y 1,3-BENZOXAZINAS EMPLEANDO METODOS TEORICOS.

    OpenAIRE

    HURTADO OCAMPO, SANDRA MARCELA; HURTADO OCAMPO, SANDRA MARCELA

    2007-01-01

    En la década del cincuenta, resultados experimentales entregados por Urbanski y colaboradores [1] pusieron en evidencia propiedades antituberculósicas y antitumorales en compuestos del tipo 5-nitro-R-N-1 ,3- oxazínicos. Como resultado de un proceso relati 187p.

  5. UN MODELLO TEORICO PER LA VALORIZZAZIONE DEL PAESAGGIO CULTURALE DELLA DIETA MEDITERRANEA

    Directory of Open Access Journals (Sweden)

    Tiziana Meduri

    2015-12-01

    Full Text Available The study aims to identify guidelines for defining a model of cultural planning oriented to the development of the emerging sector of the territory of Reggio Calabria’s metropolitan city, specifically rural areas, to provide an integrated plan of development of cultural identity. The methodology consisted of a preliminary fact-finding investigation. This has lead to, in theory, an operating model where it is proved that the first action to be performed is the accurate identification of an effective tool that can be applied to the province towed to the emergence and local development: the Mediterranean diet. The second step involved the selection of municipalities able to apply the best practices in the area for the promotion of the Mediterranean Diet. Through a checklist, formulated ad hoc, is checked for quality valorization plans that each municipality must prepare. What you intend to prove is that a careful and participatory cultural program could be the possible way out from the narrow vision of culture as a marginal aspect of economic life and in fact placed in the policies of socio-economic development of the territory.

  6. Sullo statuto teorico dell'offerta di moneta: un dibattito con Augusto Graziani

    OpenAIRE

    Cavalieri, Duccio

    1996-01-01

    In this article the debate between Prof. Augusto Graziani and the author on the monetary theory of production is carried further on. The main purpose of the paper is to delineate - along Keynesian lines and in opposition to the theory of the credit money circuit - a consistent and realistic view of the nature of the supply of money, general enough to embrace as limit-cases both a strictly endogenous and a strictly exogenous money supply. The interdependence of the supply and demand for money ...

  7. Contribution to the study of the {sup 31}P, {sup 1}H spin spin coupling constant N. M. R. in three co-ordinated phosphorus compounds. Influence of the bond orientation and of the nature of the substituent around the phosphorus atom; Contribution a l'etude des constantes de couplage {sup 31}P, {sup 1}H en R.M.N. dans les composes organo-phosphores tricoordines. Influence des facteurs geometriques et de la nature des substituants au niveau du phosphore

    Energy Technology Data Exchange (ETDEWEB)

    Robert, J B [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1969-07-01

    niveau du phosphore. Les constantes de couplage sont du type {sup 3}J{sub PH} au travers des fragments P-C-C-H et P-O-C-H, et {sup 2}J{sub PH} au travers du fragment P-CH. Les resultats montrent que, pour les temps d'observation de la RMN, la disposition des liaisons au niveau du phosphore dans l'ensemble des composes etudies (dioxaphospholanes-1,3,2, dioxaphosphorinanes-1,3,2, phosphacyclopentenes-3, phosphorinanones-4) qui portent des substituants varies au niveau du phosphore, est pyramidale et fixe. Ce resultat s'applique egalement aux phosphines secondaires. Le couplage depend tres peu des substituants fixes sur le phosphore sauf dans le cas d'un azote. Pour les couplages {sup 3}J, les resultats montrent que la dependance attendue, basee uniquement sur l'angle diedre de type ''Karplus'', ne suffit pas. La direction du doublet libre donne lieu a une variation supplementaire sur J. Dans le cas des couplages {sup 2}J{sub P-C-H} cette influence est le facteur principal, les variations de J allant de + 25 cps a -6 cps: les valeurs peuvent etre traduites par une loi J = f({alpha}) (0 {<=} {alpha} {<=} 180) {alpha} etant l'angle diedre des plans H-C-P et C-P-X, X representant la direction du doublet libre (axe ternaire de la pyramide passant par le phosphore). (auteur)

  8. Dosimetry in intravascular brachytherapy; Calculos dosimetricos em braquiterapia intravascular

    Energy Technology Data Exchange (ETDEWEB)

    Campos, Laelia Pumilla Botelho

    2000-03-01

    Among the cardiovascular diseases responsible for deaths in the adult population in almost all countries of the world, the most common is acute myocardial infarction, which generally occurs because of the occlusion of one or more coronary arteries. Several diagnostic techniques and therapies are being tested for the treatment of coronary artery disease. Balloon angioplasty has been a popular treatment which is less invasive than traditional surgeries involving revascularization of the myocardium, thus promising a better quality of life for patients. Unfortunately, the rate of restenosis (re-closing of the vessel) after balloon angioplasty is high (approximately 30-50% within the first year after treatment).Recently, the idea of delivering high radiation doses to coronary arteries to avoid or delay restenosis has been suggested. Known as intravascular brachytherapy, the technique has been used with several radiation sources, and researchers have obtained success in decreasing the rate of restenosis in some patient populations. In order to study the radiation dosimetry in the patient and radiological protection for the attending staff for this therapy, radiation dose distributions for monoenergetic electrons and photons (at nine discrete energies) were calculated for blood vessels of diameter 0.15, o,30 and 0.45 cm with balloon and wire sources using the radiation transport code MCNP4B. Specific calculations were carried out for several candidate radionuclides as well. Two s tent sources (metallic prosthesis that put inside of patient's artery through angioplasty) employing {sup 32} P are also simulated. Advantages and disadvantages of the various radionuclides and source geometries are discussed. The dosimetry developed here will aid in the realization of the benefits obtained in patients for this promising new technology. (author)

  9. Analisis del rendimiento y consumo de programas orientados al calculo

    OpenAIRE

    Ruiz Ramírez, Marcos

    2016-01-01

    Estudio que pretende crear una implementación de computación paralela/vectorial a las funciones y rutinas de cálculo del primer nivel del BLAS, recogida en una librería (estática o dinámica), analizando su impacto energético.

  10. Dosimetry in intravascular brachytherapy; Calculos dosimetricos em braquiterapia intravascular

    Energy Technology Data Exchange (ETDEWEB)

    Campos, Laelia Pumilla Botelho

    2000-03-01

    Among the cardiovascular diseases responsible for deaths in the adult population in almost all countries of the world, the most common is acute myocardial infarction, which generally occurs because of the occlusion of one or more coronary arteries. Several diagnostic techniques and therapies are being tested for the treatment of coronary artery disease. Balloon angioplasty has been a popular treatment which is less invasive than traditional surgeries involving revascularization of the myocardium, thus promising a better quality of life for patients. Unfortunately, the rate of restenosis (re-closing of the vessel) after balloon angioplasty is high (approximately 30-50% within the first year after treatment).Recently, the idea of delivering high radiation doses to coronary arteries to avoid or delay restenosis has been suggested. Known as intravascular brachytherapy, the technique has been used with several radiation sources, and researchers have obtained success in decreasing the rate of restenosis in some patient populations. In order to study the radiation dosimetry in the patient and radiological protection for the attending staff for this therapy, radiation dose distributions for monoenergetic electrons and photons (at nine discrete energies) were calculated for blood vessels of diameter 0.15, o,30 and 0.45 cm with balloon and wire sources using the radiation transport code MCNP4B. Specific calculations were carried out for several candidate radionuclides as well. Two s tent sources (metallic prosthesis that put inside of patient's artery through angioplasty) employing {sup 32} P are also simulated. Advantages and disadvantages of the various radionuclides and source geometries are discussed. The dosimetry developed here will aid in the realization of the benefits obtained in patients for this promising new technology. (author)

  11. Estimation of hydraulic conductivity on clay content in soil determined from resistivity data

    Energy Technology Data Exchange (ETDEWEB)

    Shevnin, Vladimir; Delgado-Rodriguez, Omar; Mousatov, Aleksandr [Mexican Petroleum Institute, Mexico, D.F. (Mexico); Ryjov, Albert [Moscow State Geological Prospecting Academy, Geophysical Faculty, Moscow (Russian Federation)

    2006-07-15

    The influence of clay content in sandy and clayey soils on hydraulic conductivity (filtration coefficient) is considered. A review of published experimental data on the relationship of hydraulic conductivity with soil lithology and grain size, as dependent on clay content is presented. Theoretical calculations include clay content. Experimental and calculated data agree, and several approximation formulas for filtration coefficient vs clay content are presented. Clay content in soil is estimated from electric resistivity data obtained from 2D VES interpretation. A two-step method is proposed, the first step including clay content calculating from soil resistivity and groundwater salinity, and the second step including filtration coefficient estimating from clay content. Two applications are presented. [Spanish] El contenido de arcilla en suelos areno-arcillosos influye sobre la permeabilidad hidraulica (coeficiente de filtracion). Se presenta una revision de datos experimentales publicados que relacionan el coeficiente de filtracion con el tipo litologico del suelo y el tamano de las particulas. A partir de calculos teoricos, se modifican las conocidas formulas que relacionan el coeficiente de filtracion con el contenido de arcilla. Se estima el contenido de arcilla a partir de los datos interpretados por el metodo SEV, y se propone un procedimiento para la estimacion del coeficiente de filtracion: (a) calculo del contenido de arcilla a partir de la resistividad del suelo y de la salinidad del agua subterranea, (b) estimacion del coeficiente de filtracion a partir del contenido de arcilla. Se presentan algunos ejemplos de la aplicacion de esta metodologia.

  12. Analisi teorico-sperimentale di collegamenti dissipativi a parziale ripristino di resistenza in strutture intelaiate in acciaio

    OpenAIRE

    Latour, Massimo

    2011-01-01

    2009 - 2010 Before seismic events of Northridge (Los Angeles, 17 January 1994) and Hyogoken-Nanbu (Kobe, 17 January 1995) MRFs were supposed to be the most reliable seismic resistant systems due to the high number of dissipative zones that are able to develop Before these earthquakes, especially in United States, MRFs were realized, generally, by adopting fully welded connections, which, at the time, were retained to perform better compared to other joint typologies. In a...

  13. FILOSOFIA DE LA MENTE; APORTES TEORICOS Y EXPERIMENTALES A LA VISIÓN EMERGENTISTA DEL VINCULO MENTE-CEREBRO.

    Directory of Open Access Journals (Sweden)

    Paul Ruiz Santos

    2011-01-01

    Full Text Available El presente trabajo intenta sumar alprograma emergentista dentro del mapa teórico referido a la Filosofía de la Mente, tomando como referentes a disciplinas y teorías naturalizadas. Algunos puentes vinculantes desde la naturalización pueden ser por ejemplo el neuro-psicoanálisis, las neuronas espejo, la psicosomática, entre otros. Dichos puentes son posibles de ser tendidos a través de la naturalización de los procesos psicológicos vinculándolos a diferentes procesos biológicos. El objetivo del trabajo no pretende obturar los procesos psicológicos a través de la simplificación y reduccionismo de los mismos, ni biologizar la psicología a través de planteos cartesianos. Sino, de la mano de la neuro-fenomenología, acceder a más y nuevas evidencias sobre el vínculo mente-cerebro y sus implicancias aportando a una visión interaccionista y emergentista del vínculo.

  14. Bases para um referencial teorico sobre o fenômeno da cognição

    OpenAIRE

    Moreira, Adelson Fernandes; Borges, Oto

    2008-01-01

    Apresentamos um referencial teórico para investigar a sala de aula, que articulamos a partir das seguintes matrizes teórico-metodológicas: cognição situada, etnometodologia, fundamentos biológicos da cognição, cognição distribuída e fenomenologia. Discutimos as contribuições que extraímos dessas matrizes ao longo de uma investigação que comparouas práticas de interpretação de alunos em diferentes ambientes de aprendizagem. Com base nessa discussão propomos direções para olhar a sala de aula, ...

  15. Theoretical fundamentals for the new regulation of the electric power sector; Fundamentos teoricos de la nueva regulacion electrica

    Energy Technology Data Exchange (ETDEWEB)

    Perez Arriaga, J.I.

    1998-12-01

    Regulatory models for the electric power industry throughout the world are experiencing significative changes at a umprecedented pace. It is then justified to speak of a new regulation of the electric power sector, with features of its own. This paper presents the theoretical background for this new regulation, focusing on the identification characterization and analysis of the several activities comprised in electricity supply, as well as the most suitable regulatory approach for each one of them. (Author)

  16. EL PAPEL DE LOS MUNICIPIOS COLOMBIANOS EN LA PLANEACION Y GESTION DEL DESARROLLO LOCAL: SUS FUNDAMENTOS TEORICO-CONCEPTUALES

    Directory of Open Access Journals (Sweden)

    Oscar Hernan Muñoz

    2001-07-01

    Full Text Available A partir de la crisis de los paradigmas del desarrollo y el neoliberalismo se dio un cambio en el tratamiento del desarrollo, visto como “un desarrollo a escala humana”, que acepta lo global, lo regional y lo local. Este nuevo enfoque del Desarrollo Local Endógeno permite reforzar la capacidad de la localidad para buscar formas autónomas de Desarrollo económico, social, político, etc., con base en la utilización plena de sus recursos. Dentro de este contexto se identifican seis condiciones básicas, que permiten potenciar el Desarrollo Local Endógeno: existencia de un tejido humano dinámico; identidad social; existencia de centros sociales dinámicos; densidad y diversidad de redes de información; capacidad social para asimilar cambios y el grado de diversificación del mercado de trabajo. Al mismo tiempo, se presentan factores que pueden obstaculizar el desarrollo como: bajos niveles de formación del recurso humano; carencias en el acopio y procesamiento de información; escaso desarrollo de la planificación y de gestión pública y privada, entre otros. Para abordar el estudio del Desarrollo Local Endógeno es necesario analizar la dinámica interna y sus interrelaciones con otros espacios. A escala interna se analizan aspectos locales relacionados con los recursos materiales y humanos, el poder y la organización social local y las relaciones económicas. A escala externa, el análisis del Desarrollo Local abarca elementos relacionados con vías de acceso; control y manejo del transporte y aprovechamiento de productos y personas; capacidad de liderazgo político y económico; sistemas locales de información y políticas de apoyo al desarrollo social. Un factor básico de la planeación y gestión del Desarrollo Local es el relacionado con la construcción de procesos de comunicación entre los actores locales, públicos, privados y comunitarios. La nueva lógica de la planeación tiene como objetivo la estructuración de “formas de autopedagogía colectiva” que lleven a los agentes a desarrollar una conciencia colectiva de su territorio y de su porvenir. En Colombia, el ordenamiento constitucional y el enfoque del Desarrollo Local Endógeno, les confieren a los municipios un papel preponderante en la planeación y gestión del desarrollo local; es decir, que el municipio debe ser, por excelencia, el espacio propicio para la formulación y ejecución de una verdadera política social, que brinde respuestas oportunas y concretas a las necesidades y expectativas de la comunidad local. Dentro de este contexto, las administraciones locales deben articular de una manera clara y coherente todas las acciones dirigidas específicamente a la promoción del desarrollo social del municipio, concertando con las entidades privadas locales las políticas, programas e instrumentos de empleo.

  17. Las multiples violencias de la "violencia" en la escuela: desarrollo de un enfoque teorico y metodologico integrativo

    Directory of Open Access Journals (Sweden)

    María Inés Bringiotti

    2004-12-01

    Full Text Available Foram investigados diversos tipos de violência, no âmbito escolar, que ocasionam aumento do risco para a ocorrência de maltrato infantil. Na primeira etapa a amostra ficou composta por quatro escolas de Buenos Aires, duas de educação inicial e duas primárias, selecionadas ao acaso, em dois distritos predominantemente com classes sociais diferentes (média e baixa. Foram encontradas correlações entre o potencial de maltrato, a História da Educação, nível sócio econômico e educacional da mãe, problemas comportamentais e emocionais da criança. Mediante a análise de regressão foram obtidos modelos específicos para os dois grupos da amostra e encontrados aspectos de violência social, institucional e na interação com os pares (infantil. Na segunda etapa foram encontradas correlações entre o potencial de maltrato, depressão, apoio social. Foram implementados programas de intervenção para pais e, para docentes e autoridades de um jardim da infância, analisando as variáveis de cambio e as que resistiram a uma modificação.

  18. Fundamentos teoricos de la creacion de un modelo de adquisicion corporativa internacional: Caso de las principales empresas de Nuevo Leon

    Directory of Open Access Journals (Sweden)

    Cabeza, L.

    2008-07-01

    Full Text Available The importance to propose a success Model in the international corporate acquisitions consists of offering to the important Mexican firms the factors that will allow having greater success with the international investments. In this research we selected four of the most important firms of Nuevo Leon that have important experience with international acquisitions and present them the questionnaire that was designed to validate the variables of the Model. In this paper we present the theories that give the theoretical foundations to the variables of the proposed Model that consist of 6 variables or key success factors that need to be considered for an international acquisitions, which are: Country Knowledge, Industry Knowledge, Customer relationship, Supplier relationship, Technology and Market.

  19. Theoretical study of excitonic complexes in semiconductors quantum wells; Estudo teorico de complexos excitonicos em pocos quanticos de semicondutores

    Energy Technology Data Exchange (ETDEWEB)

    Dacal, Luis Carlos Ogando

    2001-08-01

    A physical system where indistinguishable particles interact with each other creates the possibility of studying correlation and exchange effect. The simplest system is that one with only two indistinguishable particles. In condensed matter physics, these complexes are represented by charged excitons, donors and acceptors. In quantum wells, the valence band is not parabolic, therefore, the negatively charged excitons and donors are theoretically described in a simpler way. Despite the fact that the stability of charged excitons (trions) is known since the late 50s, the first experimental observation occurred only at the early 90s in quantum well samples, where their binding energies are one order of magnitude larger due to the one dimensional carriers confinement. After this, these complexes became the subject of an intense research because the intrinsic screening of electrical interactions in semiconductor materials allows that magnetic fields that are usual in laboratories have strong effects on the trion binding energy. Another rich possibility is the study of trions as an intermediate state between the neutral exciton and the Fermi edge singularity when the excess of doping carriers is increased. In this thesis, we present a theoretical study of charged excitons and negatively charged donors in GaAs/Al{sub 0.3}Ga{sub 0.7}As quantum wells considering the effects of external electric and magnetic fields. We use a simple, accurate and physically clear method to describe these systems in contrast with the few and complex treatments s available in the literature. Our results show that the QW interface defects have an important role in the trion dynamics. This is in agreement with some experimental works, but it disagrees with other ones. (author)

  20. Teorizando acerca del Conocimiento Productivo para Entender la Educacion Teorico Profesional (Theorizing about Productive Knowledge To Understand Professional Technical Education).

    Science.gov (United States)

    Hidalgo, Abelardo Castro; Carrasco, Decler Martinez

    2000-01-01

    States that, internationally, Professional Technical Education emerges as a method of providing educational solutions for poor sectors of the population. Cites University of Chalmer (Sweden) and University of Bio-Bio (Chile) as institutions transformed into technological universities. Discusses what is productive knowledge and conditions under…

  1. Marxismo como referencial teorico-metodologico em saude coletiva: implicacoes para a revisao sistematica e sintese de evidencias

    Directory of Open Access Journals (Sweden)

    Cassia Baldini Soares

    2013-12-01

    Full Text Available O objeto deste estudo é a incorporação em revisões sistemáticas de resultados de pesquisas desenvolvidas na vertente marxista de produção do conhecimento, como evidências em saúde. Os objetivos são: rever os pressupostos do materialismo histórico e dialético (MHD e discutir as implicações da dialética para a revisão da literatura e síntese de evidências. O MHD constitui um referencial potente para geração de conhecimento e transformação das políticas e práticas em saúde, a partir da explicação de que as contradições sociais estão na base do processo saúde-doença, construção teórica fundamental no campo da saúde coletiva. Atualmente observa-se considerável influência do paradigma crítico, de origem marxista, na construção do conhecimento em saúde. Pesquisas no paradigma crítico apresentam métodos complexos de apreensão do objeto, inerentes às diretrizes da dialética, oferecendo resultados que constituem evidências em saúde. Revisões sistemáticas devem enfrentar a dificuldade metodológica de integrar esses resultados plenamente ao cuidado em saúde.

  2. N.M.R. study of organo-phosphorus compounds: non equivalence of methylenic protons in the {alpha} position of an asymmetric phosphorus atom. Application to study of coupling constants J{sub P,H} and J{sub H,H}; R.M.N. de composes organo-phosphores: non equivalence de protons methyleniques en {alpha} d'un phosphore asymetrique. Application a l'etude des constantes de couplage J{sub P,H} et J{sub H,H}

    Energy Technology Data Exchange (ETDEWEB)

    Albrand, J P [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1969-07-01

    Non-equivalent methylenic protons, with respect to an asymmetric center, have been observed in the n.m.r. spectra of some three- and tetra-coordinated phosphorus compounds. The analysis of these spectra yield the following results: in the studied secondary phosphines, the inversion rate at the phosphorus atom is slow on the n.m.r. time scale; the geminal coupling constant, for a free-rotating methylene group attached to a phosphorus atom, is negative; in phosphines the non equivalence of methylenic protons reveals two {sup 2}J{sub P-C-H} coupling constants which differ by about 5 Hz. This result is in agreement with previous studies on cyclic phosphines. In phosphine oxides, the {sup 2}J{sub P-C-H} values are negative. The {sup 3}J{sub H-P-C-H} coupling constant is positive in both phosphines and phosphine oxides. In phosphines, the non-equivalent methylenic protons exhibit two nearly equal values for this coupling constant. (author) [French] La non-equivalence de protons methyleniques observee dans quelques composes phosphores tricoordines et tetracoordines a apporte les resultats suivants, concernant la stereochimie et les constantes de couplage dans ces composes: dans les phosphines secondaires, la structure pyramidale des liaisons issues du phosphore est fixe a l'echelle de temps de mesure de la R.M.N.; la constante de couplage {sup 2}J{sub H-C-H}, pour un methylene en libre rotation en {alpha} d'un atome de phosphore, est negative; dans les phosphines etudiees, la non-equivalence. observee pour les protons methyleniques s'accompagne d'une difference importante (5 Hz) entre les deux constantes de couplage {sup 2}J{sub P-C-H} determinees par l'analyse; ce resultat est en accord avec la stereospecificite deja observee pour ce couplage dans les phosphines cycliques. Les valeurs observees pour {sup 2}J{sub P-C-H} dans les oxydes de phosphines sont negatives. Les valeurs de la constante de couplage {sup 3}J{sub H-P-C-H}, dans les phosphines et oxydes de phosphine

  3. Contribution to the study of the {sup 31}P, {sup 1}H spin spin coupling constant N. M. R. in three co-ordinated phosphorus compounds. Influence of the bond orientation and of the nature of the substituent around the phosphorus atom; Contribution a l'etude des constantes de couplage {sup 31}P, {sup 1}H en R.M.N. dans les composes organo-phosphores tricoordines. Influence des facteurs geometriques et de la nature des substituants au niveau du phosphore

    Energy Technology Data Exchange (ETDEWEB)

    Robert, J.B. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1969-07-01

    substituants au niveau du phosphore. Les constantes de couplage sont du type {sup 3}J{sub PH} au travers des fragments P-C-C-H et P-O-C-H, et {sup 2}J{sub PH} au travers du fragment P-CH. Les resultats montrent que, pour les temps d'observation de la RMN, la disposition des liaisons au niveau du phosphore dans l'ensemble des composes etudies (dioxaphospholanes-1,3,2, dioxaphosphorinanes-1,3,2, phosphacyclopentenes-3, phosphorinanones-4) qui portent des substituants varies au niveau du phosphore, est pyramidale et fixe. Ce resultat s'applique egalement aux phosphines secondaires. Le couplage depend tres peu des substituants fixes sur le phosphore sauf dans le cas d'un azote. Pour les couplages {sup 3}J, les resultats montrent que la dependance attendue, basee uniquement sur l'angle diedre de type ''Karplus'', ne suffit pas. La direction du doublet libre donne lieu a une variation supplementaire sur J. Dans le cas des couplages {sup 2}J{sub P-C-H} cette influence est le facteur principal, les variations de J allant de + 25 cps a -6 cps: les valeurs peuvent etre traduites par une loi J = f({alpha}) (0 {<=} {alpha} {<=} 180) {alpha} etant l'angle diedre des plans H-C-P et C-P-X, X representant la direction du doublet libre (axe ternaire de la pyramide passant par le phosphore). (auteur)

  4. In vivo NMR spectroscopy of the liver. Spectroscopie RMN du foie in vivo

    Energy Technology Data Exchange (ETDEWEB)

    Jehenson, P.; Cuenod, C.A.; Syrota, A. (CEA, 91 - Orsay (FR). Service Hospitalier Frederic Joliot)

    1989-01-01

    The application of in vivo MR spectroscopy to the study of the liver is currently an expanding field of research. Owing to technical difficulties, the results obtained thus far were mainly those of animal observations. Several nuclei have been considered: hydrogen, phosphorus, carbon or fluorine. This non-traumatic method allows following and quantifying the various metabolic pathways, especially during hepatic diseases. The major metabolic pathways, i.e. neoglycogenesis, glycogenolysis, Krebs' cycle, etc., are studied, as well as their alterations during diseases such as ischemia, diabetes or alcoholism. The development of this promising technique requires the cooperation of various clinical and fundamental disciplines.

  5. Transformée de Fourier applications en RMN et IRM

    CERN Document Server

    Verdun, Francis R

    1995-01-01

    Les méthodes spectroscopiques de Résonance Magnétique Nucléaire et l'Imagerie par Résonance Magnétique ont aujourd'hui largement dépassé le seul cadre du laboratoire. Un nombre croissant de personnes est confronté à leur utilisation ou à l'interprétation des résultats délivrés. Or les interfaces entre l'appareil et l'utilisateur font appel à un traitement mathématique sophistiqué qu'il est souhaitable de comprendre.

  6. Construction of a NMR permanent magnet; Construcao de um ima permanente para RMN

    Energy Technology Data Exchange (ETDEWEB)

    Colnago, Luiz Alberto; Martins Neto, Ladislau; Oste, Rene de [Empresa Brasileira de Pesquisa Agropecuaria (EMBRAPA), Sao Carlos, SP (Brazil). Nucleo de Pesquisa e Desenvolvimento de Instrumentacao Agropecuaria

    1992-12-31

    Viewing the development of the pulsed, low resolution NMR spectrometers for quantitative analysis, the electronic part of a NMR spectrometer has first been constructed, based on a 1.4 Tesla magnet of a 60 MHz Varian device, with a gap increased to 23 mm, therefore reducing the field to .66 Tesla (28 MHz for the hydrogen). For the complete construction of the spectrometer in Brazil, a permanent magnet for NMR has also been constructed 9 refs., 3 figs.

  7. A NMR spectrometer for educational purposes; Espectrometro de RMN para ensino

    Energy Technology Data Exchange (ETDEWEB)

    Colnago, Luiz A; Torre Neto, Andre [Empresa Brasileira de Pesquisa Agropecuaria (EMBRAPA), Sao Carlos, SP (Brazil). Nucleo de Pesquisa e Desenvolvimento de Instrumentacao Agropecuaria; Villar, Jose D.F.; Seidl, Peter R [Instituto Militar de Engenharia (IME), Rio de Janeiro, RJ (Brazil)

    1992-12-31

    A NMR spectrometer has been constructed for educational purposes, such as teaching of the technique basic principles and instrumentation. The spectrometer has been designed with a minimum number of components so that the students may have acquittance with both the spectrometer, through block diagrams, and the small numbers of existent components . The device was based on a 0.t Tesla magnet from the continuous wave spectrometer (E M 300 - Varian) existent at the Instituto Militar de Engenharia, and it is expected to facilitate the comprehension of the commercial spectrometers 1 ref., 3 figs.

  8. Interface card for NMR data acquisition; Cartao de aquisicao de dados para RMN

    Energy Technology Data Exchange (ETDEWEB)

    Torre Neto, Andre; Colnago, Luiz Alberto [Empresa Brasileira de Pesquisa Agropecuaria (EMBRAPA), Sao Carlos, SP (Brazil). Nucleo de Pesquisa e Desenvolvimento de Instrumentacao Agropecuaria

    1992-12-31

    A NMR spectrometer constructed by NPDIA is being used for analysis of seed oil contents in projects of oil seeds improvement. Some improvements have been introduced in this spectrometer, and this work presents an IBM-Pc compatible interface card. This interface has some characteristics which are exclusive for NMR 6 refs., 3 figs.

  9. Nuclear magnetic relaxation and origins of RMN signals from GdAl2

    International Nuclear Information System (INIS)

    Santos Oliveira Junior, I. dos.

    1988-12-01

    The intermetallic compound GdAl 2 crystallizes in the cubic Laves phase C15. It is a simple ferromagnet below 176K. The easy direction of magnetization in this compound is such that the Al ions are distributed among two magnetically inequivalent sites. The pulsed NMR technique was used to study the origin of the signals from these two sites and the nuclear magnetic relaxation. (author) [pt

  10. Pressure induced magneto-structural phase transitions in layered RMn2X2 compounds (invited)

    International Nuclear Information System (INIS)

    Kennedy, Shane; Wang, Jianli; Campbell, Stewart; Hofmann, Michael; Dou, Shixue

    2014-01-01

    We have studied a range of pseudo-ternaries derived from the parent compound PrMn 2 Ge 2 , substituting for each constituent element with a smaller one to contract the lattice. This enables us to observe the magneto-elastic transitions that occur as the Mn-Mn nearest neighbour distance is reduced and to assess the role of Pr on the magnetism. Here, we report on the PrMn 2 Ge 2−x Si x , Pr 1−x Y x Mn 2 Ge 2 , and PrMn 2−x Fe x Ge 2 systems. The pressure produced by chemical substitution in these pseudo-ternaries is inherently non-uniform, with local pressure variations dependent on the local atomic distribution. We find that concentrated chemical substitution on the R or X site (e.g., in Pr 0.5 Y 0.5 Mn 2 Ge 2 and PrMn 2 Ge 0.8 Si 1.2 ) can produce a separation into two distinct magnetic phases, canted ferromagnetic and canted antiferromagnetic, with a commensurate phase gap in the crystalline lattice. This phase gap is a consequence of the combination of phase separation and spontaneous magnetostriction, which is positive on transition to the canted ferromagnetic phase and negative on transition to the canted antiferromagnetic phase. Our results show that co-existence of canted ferromagnetic and antiferromagnetic phases depends on chemical pressure from the rare earth and metalloid sites, on local lattice strain distributions and on applied magnetic field. We demonstrate that the effects of chemical pressure bear close resemblance to those of mechanical pressure on the parent compound

  11. Conceptuaciones de los estudiantes de las facultades de educacion y ciencias naturales de la Universidad de Puerto Rico, recinto de Rio Piedras, acerca de la ciencia y la pseudociencia

    Science.gov (United States)

    Reyes Medina, Hector A.

    Esta investigacion describe las conceptuaciones de los estudiantes de tercer ano o mas a nivel de bachillerato de los programas de Educacion en Ciencia y Ciencias Naturales de la Universidad de Puerto Rico, Recinto de Rio Piedras, acerca de lo establecido en la literatura para distinguir el conocimiento cientifico de las creencias pseudocientificas. Este estudio se guio por un diseno tipo encuesta transversal que permitio conocer de manera consistente las conceptuaciones de los estudiantes encuestados acerca de la Ciencia y la Pseudociencia. Ademas, permitio desarrollar inferencias estadisticas relacionadas a la poblacion de estudio, sus conceptuaciones y su inclinacion teorica en torno al Realismo y al Racionalismo cientifico moderados. El instrumento utilizado fue el Cuestionario acerca de las concepciones de la ciencia y la pseudocienca en estudiantes universitarios, Reyes (2015). Este cuestionario fue validado mediante la recopilacion de diversas fuentes de evidencias, entre estas se encuentran las evidencias basadas en el contenido, el proceso de respuesta, la estructura interna y de constructo. Tambien, se calculo el Alfa de Crombach para la escala total y para cada componente y se realizo un analisis de factores que demostro la presencia de seis componentes claramente definidos de acuerdo a lo esperado sobre las caracteristicas originales del instrumento. Las estadisticas utilizadas fueron descriptivas. Participaron 302 alumnos, de las facultades de educacion y ciencias naturales. Se encontro que las conceptuaciones de los estudiantes de ambas facultades se inclinan en un 66.2% a favor con lo establecido en el modelo teorico en torno al Realismo y al Racionalismo cientifico moderados. Sin embargo, aun hay un 33.8% de los estudiantes de ambas facultades que poseen conceptuaciones distintas al modelo teorico propuesto.

  12. {sup 137}Cs applicability to soil erosion assessment: theoretical and empirical model; Aplicabilidade do {sup 137}Cs para medir erosao do solo: modelos teoricos e empiricos

    Energy Technology Data Exchange (ETDEWEB)

    Andrello, Avacir Casanova

    2004-02-15

    The soil erosion processes acceleration and the increase of soil erosion rates due to anthropogenic perturbation in soil-weather-vegetation equilibrium has influenced in the soil quality and environment. So, the possibility to assess the amplitude and severity of soil erosion impact on the productivity and quality of soil is important so local scale as regional and global scale. Several models have been developed to assess the soil erosion so qualitative as quantitatively. {sup 137}Cs, an anthropogenic radionuclide, have been very used to assess the superficial soil erosion process Empirical and theoretical models were developed on the basis of {sup 137} Cs redistribution as indicative of soil movement by erosive process These models incorporate many parameters that can influence in the soil erosion rates quantification by {sup 137} Cs redistribution. Statistical analysis was realized on the models recommended by IAEA to determinate the influence that each parameter generates in results of the soil redistribution. It was verified that the most important parameter is the {sup 137} Cs redistribution, indicating the necessity of a good determination in the {sup 137} Cs inventory values with a minimum deviation associated with these values. After this, it was associated a 10% deviation in the reference value of {sup 137} Cs inventory and the 5% in the {sup 137} Cs inventory of the sample and was determinate the deviation in results of the soil redistribution calculated by models. The results of soil redistribution was compared to verify if there was difference between the models, but there was not difference in the results determinate by models, unless above 70% of {sup 137} Cs loss. Analyzing three native forests and an area of the undisturbed pasture in the Londrina region, can be verified that the {sup 137} Cs spatial variability in local scale was 15%. Comparing the {sup 137} Cs inventory values determinate in the three native forest with the {sup 137} Cs inventory value determinate in the area of undisturbed pasture in the Londrina region, was verified that there was not difference in the values, so that the {sup 137} Cs inventory determinate in area of native forest can be used to represent the reference value of {sup 137} Cs inventory. Comparing the {sup 137}Cs inventory values determinate to Londrina region with the {sup 137} Cs inventory value determinate in an area of the native pasture in the Porto Alegre region, the {sup 137} Cs spatial variability in the regional scale was 15%, but when was compared with the {sup 137} Cs inventory determinate in the Piracicaba region, the {sup 137} Cs spatial variability was 37%. Utilizing soil erosion plots in the experimental area of the IAPAR (Londrina), can be verified that the proportional model is a good approximation to determine the soil redistribution, but when were utilized soil erosion plots in the experimental area of the UFRGS, it was not so evident. Although there was influence of the parameters incorporated in the models on the results, due to 137 Cs spatial variability that gives deviation in the results of models, there was not difference between the results of models. So, it is convenient to utilize the proportional model, the most simple and easy to use, to assess the soil redistribution, which gives similar results to the most sophisticated models when the deviation is taking to account. (author)

  13. Development of a monoenergetic neutron beam (Theoretical aspects, experimental developments and applications); Desarrollo de un haz de neutrones monoenergeticos (Aspectos teoricos, desarrollos experimentales y aplicaciones)

    Energy Technology Data Exchange (ETDEWEB)

    Varela G, A

    2003-07-01

    By the use of a neutron time of flight system at the Tandem Accelerator of the National Nuclear Research Institute; with neutrons provided by means of the {sup 2} H(d, n) {sup 3} He we intend to use the associated particle technique in order to have monoenergetic neutrons. This neutron beam will be used both in basic and applied research. (Author)

  14. Propriedad intelectual en el marco del acuerdo Mercosur – Union Europea de 1995: apuntes teoricos para las negociaciones intercontinentales (1999-2002

    Directory of Open Access Journals (Sweden)

    Astrid Uzcátegui

    2002-09-01

    Full Text Available El presente artículo buscapresentar consideraciones científicas sobrela propiedad intelectual que pueden ser utilizadaspor los negociadores intercontinentalesdel Mercado Común del Sur convistas a alcanzar mejores resultados en elcomplejo proceso de negociación con laUnión Europea que resultará en la primeraZona de Libre Comercio entre dos unionesaduaneras a escala intercontinental. En estesentido, la superación de las eventualestrabas por los dos bloques regionales daráal mundo una verdadera prueba de lavalidez de un regionalismo abierto.Abstract: The present article presentsscientific considerations on intellectualproperty which may be used by intercontinentalnegotiators of the Mercosur, with theaim of accomplishing better results in thecomplex negotiation process whose resultwill be the first Free Trade Zone betweentwo customs unions in an intercontinentalscale. In this sense, overcoming eventualobstacles between these two regional blockswill offer the world a true evidence of thevalidity of an open regionalism.

  15. Theoretical study on air flow in a solar chimney with real insulation conditions; Estudo teorico do escoamento de ar em uma chamine solar com condicoes reais de insolacao

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Andre Guimaraes; Cortez, Marcio Fonte-Boa; Molina Valle, Ramon; Brasil, Cristiana Santiago [Minas Gerais Univ., Belo Horizonte, MG, (Brazil). Dept. de Engenharia Mecanica]. E-mail: ferreira@demec.ufmg.br

    2000-07-01

    This paper presents a theoretical analysis of the turbulent air flow with real conditions of insulation inside a solar chimney. The flow is described by the mass, momentum and energy conservation equations, besides the transport equations of the quantities in the turbulence model (k and epsilon). Dimensionless parameters are presented at way out the device, as function of time and the insulation conditions, represented by the soil and the roof heating.

  16. ESTUDIO TEORICO-EXPERIMENTAL DE LA REACCION DE AMINAS CON METILGLIOXAL; HACIA LA COMPRENSION DE LOS PROCESOS CAUSANTES DE LA CATARATA Y A SU POSIBLE PREVENCION

    OpenAIRE

    FLORES MORALES ; PATRICIO; FLORES MORALES ; PATRICIO

    2009-01-01

    Esta tesis se sitúa en el contexto de la reacción de glicación, también conocida como la reacción de Maillard (formación de una base de Schiff y posterior reordenamiento de Amidori), que sufren las proteínas del lente ocular humano y ocasiona la opalecencia y su posterior derivación en catarata. El estudio comenzó con el entendimiento del mecanismo de la reacción de Maillard visto desde un punto de vista teórico-computacion al analizado para un sistema modelo que permitió identificar las inte...

  17. Biomass gasification in fixed bed type down draft: theoretical and experimental aspects; Gasificacao de biomassa em leito fixo tipo concorrente: aspectos teoricos e experimentais

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, Juan Daniel; Andrade, Rubenildo Vieira; Lora, Electo Eduardo Silva [Universidade Federal de Itajuba (UNIFEI), MG (Brazil). Inst. de Engenharia Mecanica. Nucleo de Excelencia em Geracao Termeletrica e Distribuida

    2008-07-01

    Actually are recognizing the advantages of biomass in reducing dependence on fossil fuels and significant reduction in emissions of greenhouse effect gases such as Co2. Also are known the different conversion of biomass routes for their use or exploitation, such as thermochemical process (gasification, pyrolysis and combustion), the biological process (fermentation and transesterification) and the physical process (densification, reducing grain and mechanical pressing). In this sense, the gasification is regarded as the most promising mechanism to obtain a homogeneous gaseous fuel with sufficient quality in the small scale distributed generation. This work presents some aspects of biomass gasification in fixed bed, as well as some preliminary results in the evaluation and operation of fixed bed down draft gasifier with double stage air supply of the NEST, identifying the adequate air supply quantity (equivalence ratio in the range of 0,35 to 0,45) for obtaining a fuel gas with lower heating value around 4 MJ/N m3. (author)

  18. La formación del directivo empresarial como variable estratégica de cambio

    Directory of Open Access Journals (Sweden)

    FRANCISCO PARRA LUNA

    1997-01-01

    Full Text Available desde una perspectiva critica, se pretende señalar que relevantes teorias organizacionales no han sido todavia incorporadas a los curricula basicos de los directivos empresariales, asi como la pervivencia de la tradicional desconexion universidad-empresa. entre los enfoques teoricos que formarian parte de esta "distancia conceptual" se encontrarian el concepto axiologico de empresa (productora, exclusivante, de sistemas de valores ; el calculo de la eficiencia empresarial (o relacion entre los valores producidos y medios empleados ; el concepto de entorno al que debe adaptarse la empresa (analisis de los cambios sociales, economicos, culturales y otros ; la concepcion de la empresa como "sistema suma no cero" (lo que potenciaria o daria lugar a procesos de negociacion sinergicos versus homeostaticos y, por ultimo, el diseño de un concepto de formacion como correlato del plan estrategico de la empresa en respuesta a los desarios del entorno. se apunta finalmente un proceso formativo al nivel global de empresa, que consta de ocho fases, llamado "plan estrategico-participativo de formacion".

  19. Power factor correction at the Miguel Hidalgo refinery; Correccion del factor de potencia en la refineria Miguel Hidalgo

    Energy Technology Data Exchange (ETDEWEB)

    Dominguez Gonzalez, Gustavo [Petroleos Mexicanos, Refineria Miguel Hidalgo, Tula de Allende (Mexico)

    1993-12-31

    In this paper the theoretical fundament and formulae of the power factor are analyzed and a relationship among kilowatts, kilovars and power factor, is shown; also it deals with power factor in combination with load groups, as well as the numerical calculation of the required kvar for the desired improvement of the power factor. Additionally the technical and economical aspects of the capacitors and synchronous motors are contemplated, as well as their location in the electric system in order to achieve the maximum benefits. Finally, the savings obtained with the installation of capacitors in the electric power system of the Miguel Hidalgo refinery, are explained. [Espanol] En el presente trabajo se analizan los fundamentos teoricos y formulas del factor de potencia y se muestra la relacion entre kilowatts, kilovars y factor de potencia; tambien trata al factor de potencia combinado de grupos de cargas, asi como el calculo numerico de los KVAR necesarios para la mejora deseada del factor de potencia. Ademas se contemplan aspectos tecnicos y economicos de los capacitores y los motores sincronos, asi como la ubicacion de los mismos en el sistema electrico para lograr los maximos beneficios. Finalmente se explican las ganancias economicas que se obtuvieron al instalarse capacitores en el sistema electrico de potencia de la refineria Miguel Hidalgo.

  20. Power factor correction at the Miguel Hidalgo refinery; Correccion del factor de potencia en la refineria Miguel Hidalgo

    Energy Technology Data Exchange (ETDEWEB)

    Dominguez Gonzalez, Gustavo [Petroleos Mexicanos, Refineria Miguel Hidalgo, Tula de Allende (Mexico)

    1992-12-31

    In this paper the theoretical fundament and formulae of the power factor are analyzed and a relationship among kilowatts, kilovars and power factor, is shown; also it deals with power factor in combination with load groups, as well as the numerical calculation of the required kvar for the desired improvement of the power factor. Additionally the technical and economical aspects of the capacitors and synchronous motors are contemplated, as well as their location in the electric system in order to achieve the maximum benefits. Finally, the savings obtained with the installation of capacitors in the electric power system of the Miguel Hidalgo refinery, are explained. [Espanol] En el presente trabajo se analizan los fundamentos teoricos y formulas del factor de potencia y se muestra la relacion entre kilowatts, kilovars y factor de potencia; tambien trata al factor de potencia combinado de grupos de cargas, asi como el calculo numerico de los KVAR necesarios para la mejora deseada del factor de potencia. Ademas se contemplan aspectos tecnicos y economicos de los capacitores y los motores sincronos, asi como la ubicacion de los mismos en el sistema electrico para lograr los maximos beneficios. Finalmente se explican las ganancias economicas que se obtuvieron al instalarse capacitores en el sistema electrico de potencia de la refineria Miguel Hidalgo.

  1. Characteristic parameters of drift chambers calculation; Calculo de los parametros caracteristicos de camaras de deriva

    Energy Technology Data Exchange (ETDEWEB)

    Duran, I; Martinez-Laso, L

    1989-07-01

    We present here the methods we used to analyse the characteristic parameters of drift chambers. The algorithms to calculate the electric potential in any point for any drift chamber geometry are presented. We include the description of the programs used to calculate the electric field, the drift paths, the drift velocity and the drift time. The results and the errors are discussed. (Author) 7 refs.

  2. Sugarcane exergy calculation; Calculo de la exergia de la cana de azucar

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez P, Maria I.; Nebra P, Silvia A. [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Mecanica. Dept. de Energia]. E-mails: mariai@fem.unicamp.br.; sanebra@fem.unicamp.br; Martinez R, Arnaldo [Universidade de Oriente, Santiago de Cuba (Cuba). Facultad de Ingenieria Mecanica. Centro de Estudios de Refrigeracion Luis Fernando Brossard Perez]. E-mail: arnaldo@fim.ceefe.uo.edu.cu

    2000-07-01

    This paper presents a sugarcane exergy calculation, carried out considering the material as constituted by dry fiber and juice, being the last one that includes all the sucrose and water present in sugarcane. The variation intervals of sugarcane chemical composition and consequently the chemical composition of fibre and juice were obtained from a bibliography research. the finals results show that, the fibre exergy, as was considered totally dry and without sucrose, is a function of it chemical composition only. The quotient between the exergy and low calorific value has a middle value of 1,14 and the middle value of it exergy was 2329 kJ/kg of cane. Based on the environmental reference proposed by Szargut for the sugarcane juice exergy determination, it was obtained that the mixture component of the juice exergy has no piratical influence in the total exergy juice value, being the value of the reactive exergy component the determining of a middle value of sugarcane juice exergy of 2814,25 kJ/kg of juice and 2380Kj/Kg of cane. The sugarcane exergy value obtained for 8-18% of fiber, 75-82% of water and 14.5-22% of sucrose was 4709Kj/kg of cane. (author)

  3. Un error en los calculos matematicos destroza el acelerador de particulas del CERN

    CERN Multimedia

    Cernuda, Olalla

    2007-01-01

    The most famous particle accelerator in the world, who is at CERN, has suffered a catastrophic damage after a great explosion took place in its depths. This explosion has an absolutely scientific explanation: a mathematical mistake in the design of the anchorages of great magnets. (1 page)

  4. Calculo de volúmenes en modelos remallados de elementos finitos

    Directory of Open Access Journals (Sweden)

    Andrés Lapuebla-Ferri

    2011-06-01

    Full Text Available El Método de los Elementos Finitos asistido por ordenador es una herramienta muy extendida en ingeniería. En ciertas aplicaciones, se precisa modificar la malla del modelo a lo largo del proceso de simulación, lo que se conoce como remallado. En estos casos, además, suele ser necesario realizar mediciones en el modelo de elementos finitos, como por ejemplo calcular el volumen de ciertas regiones del mismo. Los paquetes comerciales disponibles en la actualidad permiten satisfacer algunas de estas necesidades, aunque adolecen de ciertas limitaciones. En este trabajo se presenta una aplicación desarrollada en el código propio de MatlabQc, que permite el cálculo aproximado del volumen de una región del espacio comprendida entre una malla de elementos finitos cuadriláteros lineales y otra malla topológicamente equivalente a la anterior, esta última obtenida a través de un proceso de remallado.

  5. La Vision que tienen del Calculo los Diplomados en Empresariales: Un Test Final

    Directory of Open Access Journals (Sweden)

    Seijas Macías, J. Antonio

    2008-01-01

    Full Text Available Como docentes de Matemáticas Aplicadas a la Economía y Empresa somos conscientes de las a veces difíciles relaciones entre ambas disciplinas. ¿En qué sentido se diluyen las matemáticas en la economía? ¿Qué queda de ellas en los alumnos de empresa al acabar la carrera? ¿El lenguaje matemático sigue teniendo significado para ellos? Este trabajo pretende responder a estas preguntas tomando como referencia un test pasado a los alumnos del último año de la diplomatura de Ciencias Empresariales de la Universidad de A Coruña.

  6. ESTUDIO TEÓRICO DE LA MOLÉCULA DE HIDROGENO CALCULO AB-INITIO

    Directory of Open Access Journals (Sweden)

    N. Quitián

    2010-09-01

    Full Text Available Utilizando la técnica LCGO-SCF-MO (Combinación Lineal de los Orbitales Moleculares en Orbitales Gausianos, en el método del Campo Auto-Coherente, se determinaron las energías de orbital, la energía electrónica total, la energía de repulsión nuclear y la energía de Hartree-Fock de la molécula de hidrógeno en su estado fundamental, mediante un cálculo ab initio y utilizando una base de funciones gausianas. Los orbitales moleculares fueron desarrollados en términos de una función Is contraída por átomo de hidrógeno, obtenida por la minimización de los coeficientes y de los exponentes de los orbitales gausianos para el átomo aislado. Los resultados obtenidos nos permiten afirmar que la base molecular mejora sensiblemente los resultados, acercándose más al límite de Hartree-Fock.

  7. Soil pro consolidation load and settlement computation; Preconsolidacion de los suelos y calculo de asentamiento

    Energy Technology Data Exchange (ETDEWEB)

    Delgado Martinez, D. E.

    2009-07-01

    It is estimated that cohesive soils are present in about in about 80% of the Cuban territory. Most of these soils are pre consolidated as a result of the country's geo-environmental conditions. That's why it is important, in the Cuban context, to determine accurately the soil pre consolidation load, correct the oedometric curve and apply these concepts to settlement computation. In this paper, a study is presented to define how to estimate the pre consolidation pressure by using several methods. A database was created. It consisted of 102 pre consolidated soils, which are typical from the central region of Cuban. These soil we analyzed by several Cuban geotechnical research centers. (Author) 12 refs.

  8. Shield calculations, optimization vs. paradigm; Calculos de blindajes, optimizacion vs. paradigma

    Energy Technology Data Exchange (ETDEWEB)

    Cornejo D, N.; Hernandez S, A.; Martinez G, A. [Centro de Proteccion e Higiene de las Radiaciones, Calle 20 No. 4113 e/41 y 47 Playa C.P. 11300 LaHabana (Cuba)]. e-mail: nestor@cphr.edu.cu

    2006-07-01

    Many shieldings have been designed under the criteria of 'Maximum dose rates of project'. It has created the paradigm of those 'low dose rates', for the one which not few specialists would consider unacceptable levels of dose rate superior to the units of {mu}Sv.h{sup -1}, independently of the exposure times. At the present time numerous shieldings are being designed considering dose restrictions in real times of exposure. After these new shieldings, the dose rates could be notably superior to those after traditional shieldings, without it implies inadequate designs or constructive errors. In the work significant differences in levels of dose rates and thickness of shieldings estimated by both methods for some typical facilities. It was concluded that the use of real times of exposure is more adequate for the optimization of the Radiological Protection, although this method demands bigger care in its application. (Author)

  9. Validation in life for dosimetric calculations in PET; Validacion de vida para calculos dosimetricos en PET

    Energy Technology Data Exchange (ETDEWEB)

    Ocampo ramos, J. C.; Petoussi-Henss, N.; Zankl, M.

    2015-07-01

    The LIFE program (VOXEL-PHANTOM-BASED SOFTWARE FOR INTERNAL DOSE ASSESSMENT) is developing new software for dose assessment in patients undergoing nuclear medicine examinations. This paper shows some of the validation and comparison tests that have been carried out for the case of the F-18 FDG. Unlike current programs (eg. OLINDA) using phantoms stylized size reference, the new developed software uses the pre calculated library Specific Absorption Fractions (SAF) of photons and electrons based on different anthropomorphic phantoms voxelized and the SAF new computational phantoms of the ICRP for photons, electrons, neutrons and alphas. In addition, the software uses the latest information from nuclear decay of the ICRP 107 (2008). The software is being widely put on trial and comparison with other methods of calculation available. (Author)

  10. Calculo de Parámetros Electrónicos Para el Grafito Bernal

    Directory of Open Access Journals (Sweden)

    Claudia Villaquirán

    2002-06-01

    Full Text Available Using ab-initio calculation, we have computed different electronic parameters associated with the transport coefficients of graphite Bernal. Software CRYSTAL¹ was used with a Pople standard STO- 21G* basis set. Different hamiltonians were tested, choosing a restricted Hartree-Fock one, because it generated the best qualitative results. All graphites studied present a valence bandwidth near 0.60 a.u., in agreement with the literature. In hexagonal Bernal graphite the splitting of the valence P band was accentuated, and E F = -0.00140 a.u. The surface Fermi is located around the HKH edge of the first Brillouin zone. In general such surfaces present a central electron orbit of maximal size in the plane, which diminish in size when the z component of the vector moves in KH direction. Integrating on the surface Fermi calculates the time relaxation parallel and the time relaxation perpendicular and finally we evaluate the parallel and perpendicular resistivity.

  11. Methods in nuclear reactors calculations; Metodos de calculo en reactores nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Velarde, G

    1966-07-01

    Studies are made of the neutron transport equation corresponding to the the real and virtual reactors, as well as the starting hypotheses. Methods are developed to solve the transport equation in slab geometry, and P{sub l}; B{sub l}; M{sub l}; S{sub n} and discrete ordinates approximations. (Author)

  12. Calculation of reactivity without Lagrange interpolation; Calculo de la reactividad sin interpolacion de Lagrange

    Energy Technology Data Exchange (ETDEWEB)

    Suescun D, D.; Figueroa J, J. H. [Pontificia Universidad Javeriana Cali, Departamento de Ciencias Naturales y Matematicas, Calle 18 No. 118-250, Cali, Valle del Cauca (Colombia); Rodriguez R, K. C.; Villada P, J. P., E-mail: dsuescun@javerianacali.edu.co [Universidad del Valle, Departamento de Fisica, Calle 13 No. 100-00, Cali, Valle del Cauca (Colombia)

    2015-09-15

    A new method to solve numerically the inverse equation of punctual kinetics without using Lagrange interpolating polynomial is formulated; this method uses a polynomial approximation with N points based on a process of recurrence for simulating different forms of nuclear power. The results show a reliable accuracy. Furthermore, the method proposed here is suitable for real-time measurements of reactivity, with step sizes of calculations greater that Δt = 0.3 s; due to its precision can be used to implement a digital meter of reactivity in real time. (Author)

  13. Calculos de estabilidade e divisão de fases por meio de redes neurais artificiais

    OpenAIRE

    Jones Erni Schmitz

    2006-01-01

    Resumo: A simulação de processos é um componente fundamental de uma grande variedade de atividades de Engenharia de Processos, tais como a Otimização Online, o controle em Tempo Real, a Identificação, etc. O cálculo de Equilíbrio de Fases é uma atividade fundamental em qualquer simulação de processos de separação. O elevado tempo computacional deste cálculo provocado pela sua natureza iterativa pode criar incompatibilidades entre a atividade de simulação e as aplicações em tempo real que ela ...

  14. Calculo del valor en riesgo del futuro de energia e internacionalizacion del sector energetico en Colombia

    OpenAIRE

    Esquivel Fonseca, Leidy Gioanna

    2013-01-01

    El presente trabajo de grado busca definir cuál es el mejor método para determinar el valor en riesgo del contrato de futuro de energía eléctrica que se transa en Colombia, para cumplir con este objetivo se toma como referencia el marco histórico del VaR y de los futuros seguido de las características de la fijación de precios, la estructura del contrato, que políticas y métodos hay para cubrirse del riesgo y como se realiza en otros países, realizando algunos cálculos de los modelos más trad...

  15. Equilibrio liquido-liquido-vapor de misturas ternarias : algoritimo de calculo e aspectos termodinamicos

    OpenAIRE

    Maria Helena Cano de Andrade

    1991-01-01

    Resumo: Este trabalho é uma contribuição ao estudo de processos de separação envolvendo fases em equilibrio liquido-liquido-vapor. Os seguintes aspectos são abordados: (1) desenvolvimento de um algoritmo eficiente de cálculo de flash liquido-liquido-vapor e sua aplicação para gerar diagramas de fases e em cálculos de destilação; (2) avaliação da utilização de parâmetros binários do modelo UNIQUAC obtidos de dados bifásicos em cálculos trifásicos de misturas ternárias; (3) medidas experimentai...

  16. Shielding calculations using computer techniques; Calculo de blindajes mediante tecnicas de computacion

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez Portilla, M. I.; Marquez, J.

    2011-07-01

    Radiological protection aims to limit the ionizing radiation received by people and equipment, which in numerous occasions requires of protection shields. Although, for certain configurations, there are analytical formulas, to characterize these shields, the design setup may be very intensive in numerical calculations, therefore the most efficient from to design the shields is by means of computer programs to calculate dose and dose rates. In the present article we review the codes most frequently used to perform these calculations, and the techniques used by such codes. (Author) 13 refs.

  17. Evidencias de hidrógenos metilénicos gemínales no equivalentes en RMN

    Directory of Open Access Journals (Sweden)

    Jaime Bernal Castillo

    2009-07-01

    Full Text Available Se estudian los espectros de RMP para compuestos del tipo PcSi [OCH(CH2Y2]2 en donde Y = NME2, QEt, NH2 y SH. En cuatro de estas ftalocianinas los protrones metilénicos no son equivalentes. Se demuestra que la agrupación YCH2 CH en los primeros dos derivados constituyen nítidamente un sistema de acoplamiento de espines AMX.

  18. NMR study of hydrated calcium silicates; Etude par RMN de la structure des silicates de calcium hydrates

    Energy Technology Data Exchange (ETDEWEB)

    Klur, I

    1996-02-26

    Radioactive wastes storage methods are developed by the CEA. As cements are important materials as well for hours living radioisotopes than for years living radioisotopes, a better knowledge of this material will allow to anticipate its behaviour and to obtain safer storage methods. The structure of calcium silicates (C-S-H) (main constituent of cements) have then been determined in this thesis by nuclear magnetic resonance. This method has allow to explain in structural terms, the different calcium rates that can be measured in the C-S-H too. (O.M.) 101 refs.

  19. [mu]SR magnetic response in frustrated antiferromagnets of type RMn[sub 2] (R = rare earth)

    Energy Technology Data Exchange (ETDEWEB)

    Weber, M. (Physics Dept., TU Munich, Garching (Germany)); Asch, L. (Physics Dept., TU Munich, Garching (Germany)); Kratzer, A. (Physics Dept., TU Munich, Garching (Germany)); Kalvius, G.M. (Physics Dept., TU Munich, Garching (Germany)); Muench, K.H. (Physics Dept., TU Munich, Garching (Germany)); Ballou, R. (Lab. Louis Neel, CNRS, 38 Grenoble (France)); Deportes, J. (Lab. Louis Neel, CNRS, 38 Grenoble (France)); Waeppling, R. (Dept. of Physics, Univ. of Uppsala (Sweden)); Litterst, F.J. (Inst. for Metal Physics, TU Braunschweig (Germany)); Klauss, H.H. (Inst. for Metal Physics, TU Braunschweig (Germany)); Niedermayer, C. (Faculty for Physics, Univ. Konstanz (Germany)); Chappert, J. (CEA/DRFMC, CEN Grenoble, 38 (France))

    1994-07-01

    Zero, longitudinal and transverse field [mu]SR was carried out in the antiferromagnets YMn[sub 2], Y[sub 0.95] Tb[sub 0.15] Mn[sub 2], Y[sub 0.9]Tb[sub 0.1]Mn[sub 2], Y[sub 0.99] Sc[sub 0.01] Mn[sub 2], Y[sub 0.98]Sc[sub 0.02]Mn[sub 2] and TbMn[sub 2]. The dynamics of Mn magnetic moments above T[sub N] is typical for an itinerant antiferromagnet. Within a certain temperature range above T[sub N] part of the material enters a randomly ordered (spin glass like) magnetic state as an out-come of frustration. At temperatures above [approx] 150 K the muon spin relaxation rate indicates that the muon has become mobile. (orig.)

  20. X-ray resonant magnetic scattering investigations of hexagonal multiferroics RMnO3 (R = Dy, Ho, Er)

    International Nuclear Information System (INIS)

    Nandi, Shibabrata

    2009-01-01

    Electricity and magnetism were unified into a common subject by James Clerk Maxwell in the nineteenth century yielding the electromagnetic theory. Four equations govern the dynamics of electric charges and magnetic fields, commonly known as Maxwell's equations. Maxwell's equations demonstrate that an accelerated charged particle can produce magnetic fields and a time varying magnetic field can induce a voltage - thereby linking the two phenomena. However, in solids, electric and magnetic ordering are most often considered separately and usually with good reason: the electric charges of electrons and ions are responsible for the charge effects, whereas the electron spin governs magnetic properties.

  1. DADOS ESPECTROSCÓPICOS DE DITERPENOS LABDÂNICOS: UMA ANÁLISE TEÓRICA VIA RMN E DFT

    Directory of Open Access Journals (Sweden)

    Fabrine S. de Souza

    2015-05-01

    Full Text Available Labdane diterpenes exhibit important bioactivities such as cardiovascular effects in rats as well as effects in the treatment of autoimmune diseases and Alzheimer syndrome. Recently, the labdane diterpenes ent-13-epi-manoil oxide, ribenone and ribenol were isolated from Croton palanostigma. The computational method DFT/B3LYP/cc-pVDZ was used to optimize the structures of these diterpenes and to calculate infrared data. Chemical shifts (δH and δC of the minimum energy structures (local minimum were calculated and compared with the experimental data. Comparison of the NMR data by simple linear regression (SLR showed satisfactory statistical results with a correlation coefficient (R2 and predictive ability (Q2 of over 98%. The predicted NMR data were used to confirm the δH values that have not been published.

  2. Characterization of derivates of carbo-anhydride by NMR; Caracterizacao de derivados do anidrido carbico por RMN

    Energy Technology Data Exchange (ETDEWEB)

    Campos, Marcos Pery Amaral [Instituto Militar de Engenharia (IME), Rio de Janeiro, RJ (Brazil); Bergter, Lothar [Cia. Souza Cruz, Rio de Janeiro, RJ (Brazil); Seidl, Peter Rudolf [Centro de Tecnologia Mineral, Rio de Janeiro, RJ (Brazil)

    1994-12-31

    The term molecular recognition may be applied to several phenomena of different complexities. The compounds which work as blockers or acceptors in this process are generally complexes with functional groups positioned in specific positions. This work presents the NMR characterization of carbo-anhydride derivates which are important in the preparation of synthetic acceptors 2 figs.

  3. Estudio cinético de la interconversión de Astilbina mediante espectroscopia de 1H-rmn

    Directory of Open Access Journals (Sweden)

    Omar Estrada

    2012-12-01

    Full Text Available The interconversion kinetics of astilbin to a mixture of their respective diasteroisomers was studied by nuclear magnetic resonance spectroscopy using selective irradiation experiments (TOCSY in dimethylsulfoxide. It is proposed a model which allowed establishing a trend to equilibrium for H-3 (astilbin interconversion to neoisoastilbin

  4. Use of NMR as an online sensor in industrial processes; Uso da RMN como um sensor online em processos industriais

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, Fabiana Diuk de [Universidade de Sao Paulo (IQSC/USP), Sao Carlos, SP (Brazil). Inst. de Quimica; Colnago, Luiz Alberto, E-mail: colnago@cnpdia.embrapa.br [Embrapa Instrumentacao, Sao Carlos, SP (Brazil)

    2012-07-01

    Nuclear magnetic resonance (NMR) is one of the most versatile analytical techniques for chemical, biochemical and medical applications. Despite this great success, NMR is seldom used as a tool in industrial applications. The first application of NMR in flowing samples was published in 1951. However, only in the last ten years Flow NMR has gained momentum and new and potential applications have been proposed. In this review we present the historical evolution of flow or online NMR spectroscopy and imaging, and current developments for use in the automation of industrial processes. (author)

  5. Camphor: a good model for illustrating NMR techniques; Canfora: um bom modelo para ilustrar tecnicas de RMN

    Energy Technology Data Exchange (ETDEWEB)

    Yoneda, Julliane Diniz; Leal, Katia Zaccur [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Dept. de Fisico-Quimica]. E-mail: kzl@rmn.uff.br; Seidl, Peter Rudolf [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Escola de Quimica. Dept. de Processos Organicos; Azeredo, Rodrigo Bagueira de V. [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Inst. de Quimica. Dept. de Quimica Organica; Kleinpeter, Erich [Universitaet Potsdam (Germany). Chemisches Institut

    2007-07-01

    The use of Nuclear Magnetic Resonance spectroscopy to establish the three-dimensional structures of molecules is an important component of modern Chemistry courses. The combination of techniques that can be used for this purpose is conveniently illustrated by their application to the camphor molecule. This paper presents applications of several techniques used in NMR spectral interpretation in an increasing order of complexity. The result of individual experiments is illustrated in order to familiarize the user with the way connectivity through bonds and through space is established from 1D/2D-NMR spectra and molecular stereochemistry is determined from different NMR experiments. (author)

  6. Strong CO+ and {{\\rm{N}}}_{2}^{+} Emission in Comet C/2016 R2 (Pan-STARRS)

    Science.gov (United States)

    Cochran, Anita L.; McKay, Adam J.

    2018-02-01

    We report on imaging and spectroscopic observations of comet C/2016 R2 (Pan-STARRS) obtained with the 0.8 m and 2.7 m telescopes of McDonald Observatory in 2017 November and December, respectively. The comet was at a heliocentric distance greater than 3 au during both sets of observations. The images showed a well-developed tail with properties that suggested it was an ion tail. The spectra confirmed that we were observing well-developed bands of CO+ and {{{N}}}2+. The {{{N}}}2+ detection was unequivocally cometary and was one of the strongest bands of {{{N}}}2+ detected in a comet spectrum. We derived the ratio of these two ions and from that we were able to derive that N2/CO = 0.15. This is the highest such ratio reported for a comet. This Letter includes data taken at The McDonald Observatory of The University of Texas at Austin.

  7. The Norm NOM-008-ENER-2001 offers an important saving option; La Norma NOM-008-ENER-2001 ofrece una importante opcion de ahorro

    Energy Technology Data Exchange (ETDEWEB)

    Lalana, Emiliano Ramiro [Fideicomiso para el Ahorro de la Energia Electrica (Mexico)

    2006-01-15

    The Norm NOM-008-ENER-2001 no longer commands the efficient handling of energy from functional equipment or apparatuses but from a well planned architectural design that allows diminishing the energy use for cooling purposes, consequently this Norm refers to the conduction and radiation principles regulating the heat gain through the cover portions of a building. The Norm defines a reference theoretical building that will dictate the propitious heat gain for the projected buildings. Here the functioning logic of the Norm in respect to both principles is mathematically explained as well as an application example is developed considering the calculations made for the Norm's reference building and for the projected one, the final revision of the fulfillment of the norm, proposals of solutions and the conclusions. [Spanish] La Norma NOM-008-ENER-2001 comanda el manejo eficiente de energia electrica ya no a partir de equipos o aparatos funcionales sino a partir de un bien planeado diseno arquitectonico que permita disminuir el uso de energia para fines de enfriamiento. Por ende, esta norma se refiere a los principios de conduccion y radiacion regulando la ganancia de calor a traves de la envolvente y porciones de un edificio. La Norma define un edificio teorico de referencia que dictara la ganancia de calor propicia para los edificios proyectados. Aqui se explica matematicamente la logica de funcionamiento de la Norma respecto a ambos principios asi como se desarrolla un ejemplo de aplicacion que considera los calculos realizados para el edificio de referencia de la Norma y para el proyectado, la revision final del cumplimiento de la Norma, propuestas de solucion y conclusiones.

  8. Thermal efficiency of Duovent array glassing; Eficiencia termica de arreglos de vidrios Duovent

    Energy Technology Data Exchange (ETDEWEB)

    Alvarez Garcia G; Cortina Leyva, C; Flores Prieto, Jose J [Centro Nacional de Investigacion y Tecnologico, DGIT SEP, Cuernavaca, Morelos (Mexico)

    2000-07-01

    This paper presents an experimental study of the thermal performance of duovent glazing with different solar control coatings. The thermal efficiency, {eta}, was determined. The duovent array consists of 6 mm glass+solar coating+air layer+6 mm glass. The width of the air layer between the two glasses is 12 mm. The experimental work was carried out using a calorimeter setup calling DEMETEV. The DEMETEV was specially designed to measure the heat gains through sample glassings. The heat flux, the shading coefficients and the thermal efficiency curve as a function of the temperature difference and incident radiative flux are presented. Comparing the results for duovent with clear glasses with the ones reported by Dubrous show a difference of 2.2%. Also this study verifies the theoretical model reported. [Spanish] En este trabajo se presenta un estudio experimental del comportamiento termico de vidrios Duovent con diferentes filtros solares mediante el calculo de la eficiencia termica, {eta}. El arreglo lo comprende vidrio+filtro+aire+vidrio de 6 mm de espesor con un espacio con aire entre vidrios de 12 mm. El trabajo experimental se llevo a cabo haciendo uso del dispositivo calorimetrico experimental, denominado DEMETEV, que fue disenado especialmente para medir las ganancias de calor a traves de vidrios. Se presentan los flujos de calor, los coeficientes de sombreado y la curva de eficiencia termica como funcion de la diferencia de temperaturas y del flujo radioactivo incidente. Los resultados obtenidos para vidrios claros fueron comparados con los que se obtuvieron en el trabajo reportado por Dubrous obteniendo una diferencia del 2.2%. Tambien se presenta la validacion de los datos experimentales con un modelo teorico reportado.

  9. Efecto de la concentracion de hidrogeno en la red de hierro bcc por calculos ab-initio

    OpenAIRE

    Sánchez, Javier; Andrés, Pedro L. de; Fullea, J.; Andrade, C.

    2008-01-01

    Utilizando cálculos mecano-cuánticos de primeros principios hemos estudiado la interacción del hidrógeno con la red cúbica centrada en el cuerpo del hierro. El hidrógeno intersticial puede ocupar dos posiciones de alta simetría en la red: el hueco octaédrico y el tetraédrico. Nuestros cálculos nos proporcionan barreras de difusión entre ambos huecos, que analizamos para entender la propagación del hidrogeno a través de la red de hierro. Se ha estudiado el efecto de la concentración de hidróge...

  10. Experimental method for calculation of effective doses in interventional radiology; Metodo experimental para calculo de dosis efectivas en radiologia intervencionista

    Energy Technology Data Exchange (ETDEWEB)

    Herraiz Lblanca, M. D.; Diaz Romero, F.; Casares Magaz, O.; Garrido Breton, C.; Catalan Acosta, A.; Hernandez Armas, J.

    2013-07-01

    This paper proposes a method that allows you to calculate the effective dose in any interventional radiology procedure using an anthropomorphic mannequin Alderson RANDO and dosimeters TLD 100 chip. This method has been applied to an angio Radiology procedure: the biliary drainage. The objectives that have been proposed are: to) put together a method that, on an experimental basis, allows to know dosis en organs to calculate effective dose in complex procedures and b) apply the method to the calculation of the effective dose of biliary drainage. (Author)

  11. Calculation of sensitivities in electrical systems with SIFLETCA devices; Calculo de sensibilidades en sistemas electricos con dispositivos SIFLETCA

    Energy Technology Data Exchange (ETDEWEB)

    Rubio Marroquin, Gabriel Omar

    2004-03-15

    With the purpose of avoiding the installation of new transmission lines, some researches have proposed the installation of SIFLETCA devices. Therefore in this thesis, different models in steady state of diverse SIFLETCA devices are described, such as: compensator variable series (VSC), static compensator of VArs (SCV), transformer phase shifter (TPS), transformer with changer under load (TWCL) and the universal controller of power flows (UCPF). In addition, it is developed in this thesis the equations used in the Jacobean of the method Newton-Raphson, to solve power flows including SIFLETCA devices. The different applications that are obtained when installing a device, such as prevention of flows in ring, electronic barrier, increment in the transmission capacity and specification of the power flow in transmission lines. On the other hand in the thesis, an analysis of sensitivities of a power system in steady state is developed. Also the control parameters are proposed in the thesis for which the sensitivities are calculated. Also, a performance index is used to measure the degree of congestion of an electrical system. In calculating the sensitivities the obtained results of the power flows are utilized. Four electrical networks are used to find where each SIFLETCA device must be located to reduce the congestion in the system. Also, the method developed in the thesis is compared with a method of sensitivities that uses DC flows, for validation and to show the advantages of using the Newton method in power flows. [Spanish] Con el fin de evitar instalar nuevas lineas de transmision, algunos investigadores han propuesto la instalacion de los dispositivos SIFLETCA. Por lo tanto en esta tesis, se describe diferentes modelos en estado estacionario de diversos dispositivos SIFLETCA, siendo: compensador serie variable (CSV), compensador estatico de VArs (CEV), transformador desfasador (TD), transformador con cambiador bajo carga (TTC) y el controlador universal de flujos de potencia (CUFP). Ademas, se desarrolla en esta tesis las ecuaciones utilizadas en el Jacobiano del metodo Newton-Raphson, para resolver flujos de potencia incluyendo los dispositivos SIFLETCA. Se muestra diferentes aplicaciones que se tienen al instalar un dispositivo, tales como prevencion de flujos en anillo, barrera electronica, incremento en la capacidad de transmision y especificacion del flujo de potencia en lineas de transmision. Por otra parte, se desarrolla en la tesis un analisis de sensibilidades de un sistema de potencia en estado estacionario. Tambien se proponen en la tesis los parametros de control para los cuales se calcula las sensibilidades. Asimismo, se utiliza un indice de desempeno para medir el grado de congestion de un sistema electrico. Al calcular las sensibilidades se utiliza los resultados obtenidos de los flujos de potencia. Se usa 4 redes electricas para encontrar donde se debe situar cada dispositivo SIFLETCA para reducir la congestion en el sistema. Tambien, se compara el metodo desarrollado en la tesis con un metodo de sensibilidades que emplea flujos de CD para validacion y mostrar las ventajas de usar el metodo Newton en flujos de potencia.

  12. Calculation of absorbed dose in water by chemical Fricke dosimetry; Calculo de dose absorvida na agua por dosimetria quimica Fricke

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, Adenilson Paiva, E-mail: adenilson-fisica@hotmail.com.br [Universidade do Estado do Rio de Janeiro (UERJ), Rio de Janeiro, RJ (Brazil); Meireles, Ramiro Conceicao [Fundacao do Cancer, Rio de Janeiro, RJ (Brazil)

    2016-07-01

    This work is the result of a laboratory activity performed in Radiological Sciences Laboratory (CRL), linked to the State University of Rio de Janeiro (UERJ). This practice aimed to determine the absorbed dose to water, through the primary calibration method called dosimetry Fricke, which consists of ferrous ions (Fe + 2) to ferric (Fe + 3), generated by water radiolysis products which is the structural change of water molecule caused by ionizing radiation. A spectrophotometer was used to extract data for analysis at a wavelength (λ) 304 and 224 nm with function of measuring the absorbance using bottles with irradiated and nonirradiated Fricke solution. (author)

  13. Consideraciones respecto al calculo de empalmes atornillados de perfiles estructurales de GFRP sometidos a flexión

    Directory of Open Access Journals (Sweden)

    Serna, Eduardo

    2003-06-01

    Full Text Available A composite material can be defined as the combination of two or more materials with the aim of obtaining a new product with improved properties. Composite materials, composed of a polymer matrix reinforced with fibers, are currently used as structural elements, in spite of the uncertainties on strength, deformability and durability. The use of pultruded profiles in shapes similar to those used in metallic construction, results in an interesting solution for this material when high resistance. protection against chemical attacks and lightness are required. The structural key point of those materials are the joints. The present paper is focused on joints composed of bolted plates on the wings of IPN pultruded profiles. Different tests conducted in LABEIN are described. Likewise, this paper deals with tests carried out with the purpose of analysing the feasibility of joints with high resistance bolts.Se entiende como material compuesto la combinación de dos o más materiales para obtener un nuevo producto que mejore las propiedades individuales de cada uno ellos. Se está comenzando a emplear el material compuesto. formado por una matriz de tipo polimérico o resina reforzada con fibras. como elementos estructurales. pero con reticencias originadas por las incertidumbres existentes en la actualidad relativas a su resistencia, deformabilidad y durabilidad. Este material aporta un importante interés cuando se quieren obtener elementos estructurales de alta resistencia . protección frente a ataques químicos y ligereza. utilizando perfiles a la manera de la estructura metálica. fabricados por pultrusión, Debido a que el punto crítico estructural se encuentra en las uniones. el presente artículo se centrará en los empalmes atornillados con cubrejuntas de alas de perfiles pultruídos IPN, describiendo los ensayos de diferente naturaleza realizados en las instalaciones del Centro Tecnológico LABEIN. A su vez se recogen los ensayos previos desarrollados para analizar la viabilidad de ejecutar uniones por rozamiento con tornillos de alta resistencia.

  14. Reação peritoneal tardia ao calculo biliar humano, de colesterol, deixado na cavidade abdominal de ratos

    Directory of Open Access Journals (Sweden)

    Luiz Carlos Bertges

    Full Text Available Foram avaliados os resultados tardios da colocação de cálculos biliares humanos, de colesterol, na cavidade peritoneal de ratos. Constituíram-se cinco grupos: cinco ratos foram apenas laparotomizados com manuseio da cavidade; cinco foram laparotomizados e receberam um ponto com fio monofilamentar cinco zeros no sulco paracólico direito e mesentério; dez receberam cálculos que foram deixados livres na cavidade peritoneal; em dez, os clculos foram fixados no sulco paracólico direito e, finalmente, dez tiveram clculos fixados no mesentério. Os animais foram mortos após cinco meses de pós-operatório quando se observou a cavidade abdominal e foi coletado material para estudo histopatológico. Concluiu-se que os cálculos não foram absorvidos, desenvolveram uma reação peritoneal do tipo corpo estranho com formação de plastrão e foram envolvidos por tecido fibroso e células inflamatórias.

  15. Calculo de tanque de PRFV de 200 000 litros de capacidad. // 200 000 liters capacity PRFV tank calculation.

    Directory of Open Access Journals (Sweden)

    J. García de la Figal Costales

    2002-01-01

    Full Text Available La tarea que se acomete es el cálculo a resistencia y rigidez de un tanque para el almacenamiento de agua, de 200 000 litrosde capacidad, construido de plástico reforzado con fibras de vidrio, PRFV. El mismo es cilíndrico vertical, de 8 metros dediámetro por 4.2 metros de altura. Los materiales seleccionados para la conformación de las láminas con las que se haránlos laminados de PRFV, fueron: resina poliéster isosftálica, y fibras de vidrio E.La carga fundamental a soportar por el tanque será la presión debida a la columna de agua en su interior, pero por estar a laintemperie y en zona de playa, se considerará también la acción de las dilataciones debidas a la temperatura, así como laacción de un ciclón.Palabras claves: resistencia, recipiente, composites, elementos finitos._____________________________________________________________________________Abstract.The stress and strains calculation of a water reinforced fiber glass container is carried out by means of a modern FiniteElement program, because the high complexity of calculus. The soported main load is the pressure caused by the column ofwater.Key words: Resistance, vessels, composites, finite elements.

  16. Application of Melcor code for the calculo of TMLB sequence in PWR with natural circulating into the vessel

    International Nuclear Information System (INIS)

    Marten-Fuertes, F.

    1995-01-01

    The use of computer codes to analyze the phenomena of severe accidents is very important to take decisions in Nuclear Safety. This paper presents the MELCOR code used to calculate the TMLB sequence of PWR with natural circulation into the vessels. The main goal of this code is its application for the PSA (probabilistic safety analysis)

  17. Criticality calculation of the nuclear material warehouse of the ININ; Calculo de criticidad del almacen del material nuclear del ININ

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, T.; Angeles, A.; Flores C, J., E-mail: teodoro.garcia@inin.gob.mx [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2013-10-15

    In this work the conditions of nuclear safety were determined as much in normal conditions as in the accident event of the nuclear fuel warehouse of the reactor TRIGA Mark III of the Instituto Nacional de Investigaciones Nucleares (ININ). The warehouse contains standard fuel elements Leu - 8.5/20, a control rod with follower of standard fuel type Leu - 8.5/20, fuel elements Leu - 30/20, and the reactor fuel Sur-100. To check the subcritical state of the warehouse the effective multiplication factor (keff) was calculated. The keff calculation was carried out with the code MCNPX. (Author)

  18. Componentes Principales (C.P. de los sistemas de calculo del IPC base 92 y sistema IPC base 2001

    Directory of Open Access Journals (Sweden)

    Julio Pallas González

    2002-01-01

    Full Text Available Nueve años después de que se adoptara un cambio de base en el cálculo del IPC para el Estado Español, asistimos a un cambio de sistema en el cálculo del mismo, naciendo el sistema de índices de precios, base 2001. A lo largo de este trabajo y utilizando el programa estadístico SPSS, se tratará de realizar un análisis multivariante, sobre las distintas variables que componen el IPC base 92, del estado español, y las del índice, atendiendo al nuevo sistema base 2001, que entró en vigor en enero de 2002. De todas las técnicas multivariantes susceptibles de ser aplicadas en este trabajo, se utilizaran el análisis de componentes principales y el análisis factorial, con el fin de obtener factores no observables que permitan explicar, perdiendo la mínima información, las variables originales que representan.

  19. Nueva formula matemática para el calculo de la proteinuria de 24 horas en niños

    Directory of Open Access Journals (Sweden)

    José R. Salabarría

    1996-08-01

    Full Text Available Se elaboró una fórmula matemática para la cuantificación de la excreción urinaria de proteínas en 24 horas en niños y adolescentes, derivada de la relación proteinuria creatinuria (RPC. Se procesaron 104 muestras de orina de 24 horas, las cuales se dividieron en 2 grupos de acuerdo con la excreción diaria de creatinina. La proteinuria de 24 horas se determinó en cada grupo por el método tradicional y mediante la fórmula propuesta. Se obtuvo una excelente correlación (r = 0,994 y una elevada concordancia en el grupo con recolecciones adecuadas de orina, no así en el grupo con recolecciones inadecuadas (r = 0,896. Al comparar las RPC en 30 muestras de orina obtenidas en 3 diferentes períodos, con la RPC de 24 horas correspondiente se obtuvo una elevada correlación (r 0,99; no obstante la que guardó mayor identidad fue la del período comprendido entre las 7:00 a.m. y 12:00 m.A mathematical formula for the quantification of 24-hour urinary protein excretion in children and adolescents, derived from the proteinuria-creatinuria relation (PCR was elaborated. 104 urine specimens were processed and divided into two groups according to daily creatinine excretion. 24-hour proteinuria was determined in each group by the traditional method and by the formula proposed. An excelent correlation (r=0,994 and an elevated correspondence in the group with adequate urine collections were obtained, but it was not so in the group with inadequate collections (r=0,896. On comparing the PCR in 30 urine specimens collected at three different periods with the corresponding 24-hour PCR, an elevated correlation (r 0,99 was obtained; however, the one with the greatest identity was that collected between 7:00 a.m. and 12:00 m.

  20. Introduction to energy balance of biomass production; Introduccion al calculo del balance energetico de la produccion de Biomasa

    Energy Technology Data Exchange (ETDEWEB)

    Manzanares, P.

    1997-11-01

    During last years, energy crops have been envisaged as an interesting alternative to biomass residues utilization as renewable energy source. In this work, main parameters used in calculating the energy balance of an energy crop are analyzed. The approach consists of determining energy equivalents for the different inputs and outputs of the process, thus obtaining energy ratios of the system, useful to determine if the energy balance is positive, that is, if the system generates energy. Energy costs for inputs and assessment approaches for energy crop yields (output) are provided. Finally, as a way of illustration, energy balances of some representative energy crops are shown. (Author) 15 refs.

  1. Calculo Preliminar de la Tasa de Meteorización del Batolito Antioqueño, Cordillera Central, Colombia

    OpenAIRE

    Carolina Garcia; Michel Hermelin

    2004-01-01

    Este trabajo es una estimación preliminar del tiempo necesario para generar la espesa capa de saprolito que caracteriza el perfil de meteorización actual de un batolito cuarzodiorítico cretácico que aflora en altiplanos de la Cordillera Central de Colombia, entre 5º50' y 7º00' de latitud Norte y 74º50' y 75º35' de longitud Oeste y a alturas entre 750 y 2700 m.Se utilizan datos obtenidos previamente mediante el análisis de la composición química de las aguas superficiales d...

  2. Manual method for dose calculation in gynecologic brachytherapy; Metodo manual para o calculo de doses em braquiterapia ginecologica

    Energy Technology Data Exchange (ETDEWEB)

    Vianello, Elizabeth A.; Almeida, Carlos E. de [Instituto Nacional do Cancer, Rio de Janeiro, RJ (Brazil); Biaggio, Maria F. de [Universidade do Estado, Rio de Janeiro, RJ (Brazil)

    1998-09-01

    This paper describes a manual method for dose calculation in brachytherapy of gynecological tumors, which allows the calculation of the doses at any plane or point of clinical interest. This method uses basic principles of vectorial algebra and the simulating orthogonal films taken from the patient with the applicators and dummy sources in place. The results obtained with method were compared with the values calculated with the values calculated with the treatment planning system model Theraplan and the agreement was better than 5% in most cases. The critical points associated with the final accuracy of the proposed method is related to the quality of the image and the appropriate selection of the magnification factors. This method is strongly recommended to the radiation oncology centers where are no treatment planning systems available and the dose calculations are manually done. (author) 10 refs., 5 figs.

  3. Calculation of reactivity for safety in nuclear reactors; Calculo de la reactividad para seguridad en reactores nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Suescun D, D. [Universidad Surcolombiana, Av. Pastrana Borrero - Carrera 1, Neiva, Huila (Colombia); Rojas A, O., E-mail: daniel.suescun@usco.edu.co [Universidad Popular Autonoma del Estado de Puebla, Av. 9 Pte 1908, Barrio de Santiago, 72410 Puebla (Mexico)

    2017-09-15

    The measurement of reactivity is a function of time and its calculation results from the variation in nuclear power from the inverse equation of punctual kinetics. This equation is a differential integral, where the term of the integral conserves the historical power and the differential part is directly related to the period of the reactor. In practice, in a nuclear plant, sensors are required to record the signals. For example, the movements of the control rods that cause the fluctuations of nuclear power over time commonly generate signals with noise, an event that makes difficult to estimate the reactivity. Thus is necessary and very useful to build digital reactivity meters in real time, since allows a reactor to be operated with greater security. The calculation of the reactivity is carried out using punctual kinetics, especially the concentration of delayed neutron precursors. In this work we present a new way to reduce the fluctuations in the calculation of the reactivity, for the high precision we propose the generalization of the predictor and corrector of the Adams-Bashforth-Moulton (ABM) method of order 4 to solve numerically the equations of the point kinetics for the calculation of the reactivity, without using the power history, due to the nature of the equations of the punctual kinetics, the modifiers of the different predictors are used to increase the accuracy in the approximation obtained accompanied by the filter known as Savitzky-Golay (Sg), allow to reduce the fluctuations of reactivity. It is known that the Sg filter softens and does not attenuate the nuclear power regardless of its shape, guarantees to reduce noise levels up to σ = 0.01, with a calculation time step of σ = 0.01, s. This formulation uses a polynomial approximation of Gram, with a degree d = 2, to calculate the convolution coefficients by means of an analytical formula that is implemented computationally and avoids problems of bad conditioning, caused by the inversion of a linear system. This formulation uses a polynomial approximation of Gram, with a degree d = 2, to calculate the convolution coefficients by means of an analytical formula that is implemented computationally and avoids problems of bad conditioning, caused by the inversion of a linear system. In addition, this article presents a hybrid method that allows simulating the Gaussian random noise, which is distributed around the medium power and the fluctuations of the reactivity are reduced. The results show better values in the maximum difference and in the average absolute error of the reactivity compared to that reported in the literature. (Author)

  4. Calculation of dose equivalents for photon skyshine production; Calculo da dose equivalente para fotons decorrente da producao de skyshine

    Energy Technology Data Exchange (ETDEWEB)

    Frota, Marco A.; Kelecom, Alphonse [Universidade Federal Fluminense, Niteroi, RJ (Brazil). Dept. de Biologia Geral. Lab. de Radiobiologia e Radiometria (LARARA)]. E-mail: egbakel@vm.uff.br

    2005-07-01

    Some radiation facilities are designed with little shielding in the ceiling above the accelerator. A problem may then arise as a result of the radiation scattered by the atmosphere to points at ground level outside the treatment room. Stray radiation of this type is referred to as skyshine, and the National Council on Radiation Protection and Measurements Report No. 51 (NCRP 1977) gives methods for the calculation of skyshine for accelerator facilities. McGinley (1993) has compared skyshine measurements made at an 18 MeV medical accelerator facility with values calculated using the techniques presented in NCRP Report No. 51. Measurements were made of the photon levels outside a treatment room housing a Varian 2100 deg C. The roof above the accelerator was designed for weather protection only and offered little shielding for the primary beam and scattered radiation. The distance from the treatment room floor to the roof was 4.27 m, and the primary walls were constructed of concrete 2.0 m thick.The secondary walls were fabricated of concrete 0.99 m thick. The results for the photon skyshine rate dose as a function of distance from the isocenter using Monte Carlo code, are compared with those in NCRP publication 74 and measured obtained. The photon skyshine dose rates simulated for real clinic spectra transmitted through roof range from 4.7 to 14.6 nSv.s{sup -1}. (author)

  5. Methods of calculus for neutron spectrometry in proportional counters; Metodos de calculo para espectrometria de neutrones en contadores proporcionales

    Energy Technology Data Exchange (ETDEWEB)

    Butragueno, J L; Blazquez, J B; Barrado, J M

    1976-07-01

    Response functions for cylindrical proportional counters with hydrogenated gases have been determined, taking in account only wall effect, by means of two independent calculus methods. One of them is a Monte Carlo application and the other one analytica at all. Results of both methods have been compared. (Author)

  6. Elementary computation of radiation doses and shieldings for radiochemical laboratories; Calculo Elemental de dosis y blindajes para laboratorios radioquimicos

    Energy Technology Data Exchange (ETDEWEB)

    Jimeno de Osso, F

    1971-07-01

    Simple procedures for the calculation of radiation exposition, half thickness, shield thickness, etc. are described and equations and graphs are included for those gamma-emitting radionuclides, that are more often used in radiochemical laboratories. Application is made of these procedures to three radionuclides, bromine-82, sodium-24 and cobalt-60 which cover a rather wl.de energy range; theoretical results are compared with those obtained from experimental measurements. (Author) 23 refs.

  7. Diseño y calculo de estructura para una industria fotovoltaica en el parque tecnologico de paterna (Valencia)

    OpenAIRE

    MEDINA RUIZ, VÍCTOR MANUEL

    2016-01-01

    [ES] El objetivo fundamental del presente trabajo es el diseño y cálculo de la estructura metálica, así como su cimentación, de una nave para una industria dedicada a la fabricación de paneles fotovoltaicos en el Parque Tecnológico de Paterna (Valencia). El espacio interior debe ser suficiente para contener todas las áreas necesarias en una industria de dichas características: Oficinas, Vestuarios, Almacén y Línea de Producción (Soldadura, montaje…). Para la realización del cál...

  8. Model for calculation of spot prices and uncertainties integration; Modelo de calculo de precos spot e integracao de incertezas

    Energy Technology Data Exchange (ETDEWEB)

    Saraiva, J. Tome [Instituto de Engenharia de Sistemas e Computadores (INESC), Porto (Portugal). E-mail: jsaraiva@inescn.pt

    1999-07-01

    This paper presents a model for systematic and structured impact evaluation of the uncertainties existent in the load powers, on the spot prices on the various bars of a electric power system. The application developed allows the specification of load power as inaccurate trapezoidal numbers and adopts the DC model for the representation of system exploration conditions. Considering the influence of the loss power on the formulation of a spot prices spatial distribution, the model allows the inclusion of transmission network loss estimation. The results correspond to appurtenance functions of spot prices in each barm, consisting of a discrete set of ordered pais which integrates the spot price values and the appurtenance or compatibility level, in accordance with Fuzzy Sets.

  9. Description of the CAREM Reactor Neutronic Calculation Codes; Descripcion de la Linea de Calculo Neutronica del CAREM

    Energy Technology Data Exchange (ETDEWEB)

    Villarino, Eduardo; Hergenreder, Daniel [Investigacion Aplicada, INVAP, San Carlos de Bariloche (Argentina)

    2000-07-01

    In this work is described the neutronic calculation line used to design the CAREM reactor.A description of the codes used and the interfaces between the different programs are presented.Both, the normal calculation line and the alternative or verification calculation line are included.The calculation line used to obtain the kinetics parameters (effective delayed-neutron fraction and prompt-neutron lifetime) is also included.

  10. Calculation of the Doppler broadening function using Fourier analysis;Calculo da funcao de alargamento Doppler utilizando analise de Fourier

    Energy Technology Data Exchange (ETDEWEB)

    Goncalves, Alessandro da Cruz

    2010-07-01

    An efficient and precise method for calculation of Doppler broadening function is very important to obtain average group microscopic cross sections, self shielding factors, resonance integrals and others reactor physics parameter. In this thesis two different methods for calculation of Doppler broadening function and interference term will be presented. The main method is based on a new integral form for Doppler broadening function {psi}(x,{zeta}) which gives a mathematical interpretation of the approximation proposed by Bethe and Placzek, as the convolution of the Lorentzian function with a Gaussian function. This interpretation besides leading to a new integral form for {psi}(x,{zeta}), enables to obtain a simple analytic solution for the Doppler broadening function. (author)

  11. Resonance integral analytical calculation considering shadowing effect. Calculo analitico da integral de ressonancia considerando o efeito de sombreamento

    Energy Technology Data Exchange (ETDEWEB)

    Monteiro, M A.M. [NUCLEN, Rio de Janeiro, RJ (Brazil); Martinez, A S [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia

    1990-01-01

    It is presented a method for the Resonance Integral Calculation in the fuel and moderator regions, including the shadowing effect. This effect appears due to the presence of several fuel rods in a infinite moderator region. The method is based on the approximations to the J ({xi}, {beta}) function and theirs partial derivatives in relation to {beta}. The dependence of the Resonance Integral in the J ({xi}, {beta}) comes from the rational approximation to the neutron escape probability. The final results were obtained in a very simple and fast way, and they show the good accuracy of the method. (author).

  12. Precise magnetostatic field using the finite element method; Calculo de campos magnetostaticos com precisao utilizando o metodo dos elementos finitos

    Energy Technology Data Exchange (ETDEWEB)

    Nascimento, Francisco Rogerio Teixeira do

    2013-07-01

    The main objective of this work is to simulate electromagnetic fields using the Finite Element Method. Even in the easiest case of electrostatic and magnetostatic numerical simulation some problems appear when the nodal finite element is used. It is difficult to model vector fields with scalar functions mainly in non-homogeneous materials. With the aim to solve these problems two types of techniques are tried: the adaptive remeshing using nodal elements and the edge finite element that ensure the continuity of tangential components. Some numerical analysis of simple electromagnetic problems with homogeneous and non-homogeneous materials are performed using first, the adaptive remeshing based in various error indicators and second, the numerical solution of waveguides using edge finite element. (author)

  13. Study on radiographic and minerals characteristics of renal calculus; Estudo das caracteristicas radiograficas e minerais de calculos renais

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes, Marco A.R., E-mail: mfernandes@fmb.unesp.b [Universidade Estadual Paulista Julio de Mesquita Filho (FMB/UNESP), Botucatu, SP (Brazil). Fac. de Medicina. Dept. de Dermatologia e Radioterapia; Goldberg, Jose [Universidade Estadual Paulista Julio de Mesquita Filho (FMB/UNESP), Botucatu, SP (Brazil). Fac. de Medicina. Dept. de Urologia; Sakate, Makoto [Universidade Estadual Paulista Julio de Mesquita Filho (FMB/UNESP), Botucatu, SP (Brazil). Fac. de Medicina. Dept. de Doencas Tropicais e Diagnostico por Imagem; Louzada, Mario J.Q. [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Aracatuba, SP (Brazil). Curso de Medicina Veterinaria; Fernandes, Marco F.S. [Santa Casa de Misericordia de Sao Jose do Rio Preto, SP (Brazil). Dept. de Cirurgia Geral

    2010-07-01

    Radiological Images of kidneys stones were analyzed, quantifying the optical density (D.O.) and the blackening degree in the radiographic film of the samples. Studies of the literature, analyses of samples and interviews with specialists of the Center of Sciences and Technologies of Materials (CCTM) of the Institute of Energy and Nuclear Researches (IPEN/CNEN-SP), after crystallographic analysis for absorption techniques and diffraction of ray-X, showed that D.O. of the stones it is more directly dependent of their dimensions of what of their contents concentration. It is the researchers' consensus that as larger D.O. of the radiographic image of the calculation renal, larger her density (g/cm{sup 3}) and therefore larger the importance of the application of an appropriate energy for the fragmentation of the calculation. This energy, supplied by the equipment extracorporeal shock wave lithotripsy (ESWL) it depends on several parameters inside the ones which the anatomy and the patient's position and of the own limitations of the lithotripsy equipment. This interpretation, at least for the analyzed samples, it disappoints a simplistic correlation among the parameters of the shock waves used in the lithotripsy procedures and the measures of D.O. and characteristics minerals. Another restriction factor is the discrepancy of the radiological image the kidneys stones camped in the patient, surrounded by the organs and interposed bone structures, and gotten her through the analysis of the fragments expelled after the accomplishment of ESWL, which present great variety of granulations. (author)

  14. Treatment calculation program for reverse osmosis facilities; Programa de calculo de tratamiento para instalaciones de osmosis inversa

    Energy Technology Data Exchange (ETDEWEB)

    Adroer, M.; Bodas, J.; Coma, J.

    2001-07-01

    Reverse osmosis if a technique used ever more frequently for the desalination of water. it is very important to maintain the permeability of the membrane as much as possible throughout its life, and in order to do this, is necessary to know the incrustations properties of the water in contact with the membrane. The Adicro program has been developed to calculate the characteristics of this water from the analysis of the intake water, the type of membrane used, and the recovery percentage. It also calculates the necessary inhibitor doses and, finally, whether the supply water is apt for use in the plant under the predicted conditions or whether it should be modified. (Author) 2 refs.

  15. The cost calculus model for the hull roughness; Um modelo para calculo do custo da rugosidade do casco

    Energy Technology Data Exchange (ETDEWEB)

    Marco, Antonino Di [International Paint (Akzo Nobel Ltda.), Sao Paulo, SP (Brazil)

    2004-07-01

    The economic importance of the condition of the immersed hull cannot be underestimated; any increase of the roughness may result in a significant increase in the operational costs of a ship. There are two main types of roughness, biological and physical, each one with its proper characteristics of macro and micro roughness; when an increase in the roughness of the underwater hull occurs, the frictional resistance of the ship or .drag. also increases, resulting in additional power and consequent increase of the fuel consumption to keep the speed of the ship. Keeping the power constant will result in lower speed and greater voyage times. Aiming the better understanding of the effect of the roughness in the performance, costs and operational efficiency of a ship, International Paint developed a new model called 'Hull Roughness Penalty Calculator', a program that predicts the increase of the hull roughness during in service time specified service and combines it with the fouling risk associated with different types of antifoulings. The model compares fuel consumptions and costs of different types of TBT free antifoulings to derive the potential benefit, and also can be used to compare the emissions of carbon dioxide and sulphur oxides. (author)

  16. Calculo Preliminar de la Tasa de Meteorización del Batolito Antioqueño, Cordillera Central, Colombia

    Directory of Open Access Journals (Sweden)

    Carolina Garcia

    2004-12-01

    Full Text Available Este trabajo es una estimación preliminar del tiempo necesario para generar la espesa capa de saprolito que caracteriza el perfil de meteorización actual de un batolito cuarzodiorítico cretácico que aflora en altiplanos de la Cordillera Central de Colombia, entre 5º50' y 7º00' de latitud Norte y 74º50' y 75º35' de longitud Oeste y a alturas entre 750 y 2700 m.Se utilizan datos obtenidos previamente mediante el análisis de la composición química de las aguas superficiales de cuatro cuencas con áreas diferentes, ubicadas sobre el Batolito Antioqueño, al este de Medellín. Los cáculos se hicieron con el método basado en la pérdida de componentes en solución utilizando diferentes valores de solutos. Al utilizar la pérdida de sílice se obtiene un tiempo de meteorización de unos 6 x 10 6 años, comparable con el obtenido mediante la datación de las cenizas volcánicas mas antiguas que recubren la topografía actual y que indican la fecha mínima de configuración de la superficie de erosión.A pesar de resultar de una serie de suposiciones simplificadoras, este resultado es interesante y justifica la realización de determinaciones mas detalladas. Confirma la larga preservación de superficies de erosión antiguas conformadas sobre un saprolito que desde hace varios millones de años no ha sido sometido a una erosión profunda, fenómeno poco común en una zona tectónicamente activa como la estudiada.

  17. RAMA Methodology for the Calculation of Neutron Fluence; Metodologia RAMA para el Calculo de la Fluencia Neutronica

    Energy Technology Data Exchange (ETDEWEB)

    Villescas, G.; Corchon, F.

    2013-07-01

    he neutron fluence plays an important role in the study of the structural integrity of the reactor vessel after a certain time of neutron irradiation. The NRC defined in the Regulatory Guide 1.190, the way must be estimated neutron fluence, including uncertainty analysis of the validation process (creep uncertainty is ? 20%). TRANSWARE Enterprises Inc. developed a methodology for calculating the neutron flux, 1,190 based guide, known as RAMA. Uncertainty values obtained with this methodology, for about 18 vessels, are less than 10%.

  18. Estimations of internal dosimetry: practical calculations of incorporated activity; Estimaciones de dosimetria interna: calculos practicos de actividad incorporada

    Energy Technology Data Exchange (ETDEWEB)

    Cortes C, A. [CNSNS, Dr. Barragan 779, 03020 Mexico D.F. (Mexico)

    2003-07-01

    The National Commission of Nuclear Security and Safeguards (CNSNS) carries out periodically measurements of corporal activity to Occupationally Exposed Personnel (POE) to determine that the received doses are in according to that settled down in the General Regulation of Radiological Security. In this work the results of the incorporated activity estimates starting from the results of the measurements that were carried out in the one CNSNS laboratory are presented, with which it should be determine lastly the internal dose. Its were used different methodologies to estimate the incorporated activity: estimate with isolated data, estimate with global data and method of the best estimate, demonstrating this last to be the more appropriate to determine the internal dose. (Author)

  19. Theoretical and practical aspects about corrosion of refractories used in steel metallurgy: part 3: characterization of commercial refractories; Aspectos teoricos e praticos sobre a corrosao de refratarios utilizados na metalurgia: caracterizacao de refratarios comerciais

    Energy Technology Data Exchange (ETDEWEB)

    Braganca, S.R., E-mail: saulorb@ufrgs.br [Universidade Federal do Rio Grande Sul (DEMAT/UFRGS), RS (Brazil)

    2012-07-01

    In this study, it was reviewed the main aspects found in the literature about refractories corrosion, evaluating the feasibility of certain tests and relating them with experimental results. The physical properties and microstructure of commercial refractories were analyzed, considering the differences between them and the quality implications and probable life of the refractory. Thus, it was studied the various types of refractories used as lining on steel ladle. Magnesia-carbon and doloma-carbon refractories were analyzed, highlighting the differences between them. The examined refractory showed characteristics favoring high resistance to corrosion process, presenting a series of properties to be selected in accordance with industry practice. (author)

  20. Theoretical thermodynamics analysis of cooling cycle bu advanced gas absorption using solar energy; Analisis teorico-experimental de un ciclo de refrigeracion por absorcion avanzado gax, operando con energia solar

    Energy Technology Data Exchange (ETDEWEB)

    Gomez, V. E.; Vidal, A. S.; Garcia, C. A.; Garcia-Valladares, O.; Best, R. B.; Hernandez, J. G.; Velazquez, N. L.

    2004-07-01

    In this article a solar system of refrigeration by absorption with heat exchange generator absorber (GAX) was analyzed. A theoretical thermodynamic analysis of the energetic behavior of the GAX absorption system was made. Experimental results were obtained with generation temperatures of 190 and 220 C, the evaporation temperature was set at 9 C and temperatures of cooling fluids (air and water) were set at 30 C and 28 C, respectively. It was possible to appreciate that the GAX effect decrease whether absorber, type falling film, is operated in option of parallel flow and it was increased when the absorber was operated in option of counterflow. (Author)

  1. Radon 222 and Tritium in the identification and quantification of NAPL contamination in ground water. 1. Theoretical principles; Radon 222 y Tritio en la identificacion y cuantificacion de la contaminacion por hidrocarburos (LFNA) en las aguas subterraneas. 1. Principios teoricos

    Energy Technology Data Exchange (ETDEWEB)

    Molerio Leon, LF [Inversiones Gamma, La Habana (Cuba); Fernandez Gomez, IM; Carrazana Gonzalez, J A, E-mail: especialistaprincipal@gmail.com [Centro de Proteccion e Higiene de las Radiaciones (CPHR), La Habana (Cuba)

    2012-07-01

    This is the first of two papers presenting the basic concepts and the main results of the application of environmental Rn{sup 222a}nd Tritium in the identification and quantification of Non-Aqueous Phase Liquids contamination of Cuban ground waters and their relation with sea water intrusion and/or spills of produced waters. The interpretation technique is based on the partition properties of the tracers involved and in the geochemical affinity of some major and minor constituents of the ground waters occurring beneath the exploration and production facilities of the Northern Havana-Matanzas Heavy Oil Belt. The second paper in this series discusses several cases of interaction among the fresh water aquifer, the sea, the sea water-fresh water interface and oil contamination.

  2. Theoretical and experimental studies of reverse osmosis separation of inorganic salts in aqueous solutions; Estudio teorico y experimental de parametros de transporte a traves de membranas de osmosis inversa : Efecto de varios tipos de sales

    Energy Technology Data Exchange (ETDEWEB)

    Khavet, M.; Mengual, J. I.

    2004-07-01

    Theoretical and experimental studies of reverse osmosis separation of inorganic salts in aqueous solutions have been carried out. In this study, a polyamide thin film composite membrane in spiral wound configuration was used. The free energy of different inorganic monovalent (LiCl, NaCl, KCl, NaBr, NaI, LiBr, KBr) and divalent (MgCl2, MnCl2, CaCl2, MgBr2) salts has been calculated. The solute transport parameters were related to the free energy of the corresponding cations and anions. The mass transfer coefficient at the high pressure feed side of the spiral wound module was determined for each type of salt. The obtained theoretical values were compared to the experimental ones. The good agreements observed between the experimental and theoretical results confirm the validity of the theoretical procedure, which may be applied in modelling solar reverse osmosis plants for the prediction of the separation factor of various types of inorganic salts. (Author)

  3. Stability analysis of a recycling circuit of a BWR type reactor. Theoretical study; Analisis de estabilidad de un circuito de recirculacion de un reactor del tipo BWR. Estudio teorico

    Energy Technology Data Exchange (ETDEWEB)

    Salinas H, J.G.; Espinosa P, G. [Universidad Autonoma Metropolitana-Iztapalapa, 09000 Mexico D.F. (Mexico); Gonzalez M, V.M. [Comision Nacional de Seguridad Nuclear y Salvaguardias, 04000 Mexico D.F. (Mexico)

    2000-07-01

    The Technology, Regulation and Services Management of the National Commission of Nuclear Safety and Safeguards financed and in coordinate form with the I.P.H. Department of the Metropolitan Autonomous-Iztapalapa University developed the present project with the purpose of studying the effect of the recycling system on the linear stability of a BWR reactor whose reference central is the Laguna Verde power station. The present project forms part of a work series focused to the linear stability of the nuclear reactor of the Unit 1 at Laguna Verde power station. The components of the recycling system considered for the study of stability are the recycling external circuit (recycling pumps, valves) and the internal circuit (downcomer, jet pumps, lower full, driers, separators). The mathematical model is obtained applying mass balances and movement quantity in each one of the mentioned circuits. With respect to the nucleus model two regions are considered, the first one is made of a flow in one phase and the second one of a flow in two phases. For modelling the biphasic region it is considered homogenous flow. Generally it is studied the system behavior in the frequency domain starting from the transfer function applied to four operational states which correspond to the lower stability zone in the map power-flow of the Unit 1 of Laguna Verde power station. The Nyquist diagrams corresponding to each state as well as their characteristic frequency were determined. The results show that exists a very clear dependence of the power-flow relation on the stability of the system. It was found that the boiling length is an important parameter for the linear stability of the system. The obtained results show that the characteristic frequencies in unstability zones are similar to the reported data of the Unit 1 of the Laguna Verde power station in the event of power oscillations carried out in January 1995. (Author)

  4. Theoretical study of hydrogen adsorption of graphene and carbon nanotubes decorated with palladium; Estudio teorico de la adsorcion de hidrogeno sobre grafeno y nanotubos de carbono decorados con paladio

    Energy Technology Data Exchange (ETDEWEB)

    Lopez Corral, Ignacio; German, Estefania [Departamento de Fisica, Universidad Nacional del Sur (UNS), Bahia Blanca (Argentina); Volpe, Maria A [Planta Piloto de Ingenieria Quimica (UNS/CONICET), Bahia Blanca (Argentina); Brizuela, Graciela; Juan, Alfredo [Departamento de Fisica, Universidad Nacional del Sur (UNS), Bahia Blanca (Argentina)

    2008-10-15

    Since their discovery in 1991, carbon nanotubes (CNT) have awakened great interest in materials science thanks to their extraordinary structural, electronic and mechanical properties which facilitate their application in many different areas. One of the most promising applications is the possibility of using CNT to store hydrogen for use in small scale fuel cells. Unfortunately, experimental studies performed some years ago have often led to controversial conclusions, causing a continuing debate that has still not been resolved. The most recent work suggests that the storage of hydrogen for practical purposes can be achieved with CNT decorated with transition metals, for example Pd. In this context, theoretical modeling methods have to be used for a detailed understanding of the influence and scope of this type of modification in the interaction of the nanotubes with atomic or molecular hydrogen. This work studied hydrogen adsorption in single-walled carbon nanotubes (SWCNT) doped with Pd atoms, using density functional theory (DFT) and semi-empirical methods. As a preliminary approximation to the system a graphene sheet was used, modeled with a 190 atom cluster of C in a hexagonal arrangement, on which a single Pd atom was placed in adsorption sites. Then C{sub 190} clusters were used to simulate two different types of SWCNT: the zigzag SWCNT of quirality (10.0) and the armchair SWCNT of quirality (5.5), both decorated similarly on the graphene. Geometric optimization procedures for the system's different components were carried out with these models, and then the changes produced during the adsorption process in the electronic occupation of atomic orbitals and unions, for which crystal orbital overlap population (COOP) curves and overlap population (OP) values were evaluated. The results obtained with the graphene and nanotube approximations are in agreement and show that the SWCNT modified with Pd have more capacity to trap hydrogen than the non doped SWCNT. The interaction can occur directly through the Pd atoms, or by prior dissociation to produce atomic H, with highly favorable adsorption results. Theoretical methods are used to describe the mechanisms by which the nanotubes decorated with Pd can be used as hydrogen storage systems, in accordance with the experimental evidence (au)

  5. The TMS34010 graphic processor - an architecture for image visualization in NMR tomography; O processador grafico TMS34010 - uma arquitetura para visualizacao de imagem em tomografia por RMN

    Energy Technology Data Exchange (ETDEWEB)

    Slaets, Jan Frans Willem; Paiva, Maria Stela Veludo de; Almeida, Lirio O B

    1990-12-31

    This abstract presents a description of the minimum system implemented with the graphic processor TMS34010, which will be used in the reconstruction, treatment and interpretation f images obtained by NMR tomography. The project is being developed in the LIE (Electronic Instrumentation Laboratory), of the Sao Carlos Chemistry and Physical Institute, S P, Brazil and is already in operation 4 refs., 7 figs.

  6. {sup 1} H and {sup 13} C NMR of phenyl barbiturilidene; RMN de H-1 e C-13 de fenil barbiturilidenos

    Energy Technology Data Exchange (ETDEWEB)

    Villar, Jose Daniel Figueroa; Santos, Nedina Lucia dos; Cruz, Elizabete Rangel [Instituto Militar de Engenharia (IME), Rio de Janeiro, RJ (Brazil). Secao de Quimica

    1991-12-31

    The condensation of barbituric acids with aromatic aldehydes gives the phenyl barbiturilidenes, which are studied as intermediary compounds in the synthesis of new heterocyclic compounds for pharmaceutical use. One of the most characteristic reactions of these compounds is the Michael type addition reaction, in the exocyclic carbon-carbon double binding. The reaction with 2,4-di nitrophenyl hydrazine reaction is been used as a test of this type of reactivity, which supplies the respective hydrazone and barbituric acid. In this work, preliminary studies have been performed for establishing correlations between the Brown parameter ({sigma}{sup +}), the chemical shifts ({delta}) of the barbiturilidene atoms involved in the reaction, and their reactivities 3 refs., 1 fig., 6 tabs.

  7. Study of crystalline morphology and phase structure in poly(styrene-b-ethylene oxide-b-styrene) triblock copolymers bu solid state RMN spin diffusion

    International Nuclear Information System (INIS)

    Mantovani, Gerson L.; Phan, Trang; Bertin, Denis; Azevedo, Eduardo R. de; Bonagamba, Tito J.

    2009-01-01

    The phase structure and crystalline morphology of a series of polystyrene-b-polyethylene oxide-b-polystyrene (PS-b- PEO-b-PS) triblock copolymers, with different compositions and molecular weights, has been studied by solid-state NMR. WAXS and DSC measurements were used to detect the presence of crystalline domains of polyethylene oxide (PEO) blocks at room temperature as a function of the copolymer composition. 1 H NMR spin diffusion analyses provided an estimation of the size of the dispersed phases of the nano structured copolymers. (author)

  8. Time domain NMR and conductivity study of apple pectin biopolymers; Estudo por RMN no dominio do tempo e condutividade em filmes biopolimericos de pectina de maca

    Energy Technology Data Exchange (ETDEWEB)

    Mattos, Ritamara I.; Souto, Sergio; Tambelli, Caio E., E-mail: cristal_br@yahoo.com.br [Universidade de sao Paulo (USP), Pirassununga, SP (Brazil). Faculdade de Zootecnia e Engenharia de Alimentos

    2015-07-01

    This communication presents results of {sup 1}H nuclear magnetic resonance of continuous distributions of spin-spin relaxation time (T{sub 2}) and A.C. conductivity of apple pectin biopolymers plasticized with glycerol and containing acetic acid. The continuous distributions reveals up to three components of spin-spin relaxation times (T{sub 2}). The two short T{sub 2} components were associated with protons of pectin polymer chain and the longer T{sub 2} can be attributed with the protons of the glycerol. The conductivity values increase with glycerol concentration with maximum at 7.9 x 10{sup -4} S cm{sup -1} for sample with 3.0 g of glycerol at 83 deg C. The behavior of activation energy and T{sub 2} continuous distribution indicate an increase of proton mobility due the structural changes caused by glycerol addition. (author)

  9. Time domain NMR study of Agar-gelatin blends; Estudo por RMN no dominio do tempo de blendas de Agar- gelatina

    Energy Technology Data Exchange (ETDEWEB)

    Mattos, Ritamara; Pericini, H.A.; Tambelli, Caio E., E-mail: tambelli@usp.br [Universidade de Sao Paulo (USP), Pirassununga, SP (Brazil). Faculdade de Zootecnia e Engenharia de Alimentos; Raphael, Ellen [Universidade Federal de Sao Joao del Rei (UFSJ), MG (Brazil). Departamento de Ciencias Naturais; Magon, Claudio J.; Donoso, P. [Universidade de Sao Paulo (USP), Sao Carlos, SP (Brazil). Instituto de Fisica

    2015-07-01

    This communication presents results of {sup 1}H time domain nuclear magnetic resonance of Agar-Gelatin blends plasticised with glycerol, cross-linked with formaldehyde and containing acetic acid. The spin-spin relaxation decay curves of samples obtained from CPMG experiments were inverted into corresponding distributions of relaxation times using NNLS (Non Negative Least Square) algorithm. The continuous distributions reveals up to four components of spin-spin relaxation times (T{sub 2}). The two components at short T{sub 2} were associated with protons in different environments of Agar and gelatin polymer chain. The two components at longer T{sub 2} can be associated with the glycerol that is the responsible to promote the proton conduction in the blend. (author)

  10. The TMS34010 graphic processor - an architecture for image visualization in NMR tomography; O processador grafico TMS34010 - uma arquitetura para visualizacao de imagem em tomografia por RMN

    Energy Technology Data Exchange (ETDEWEB)

    Slaets, Jan Frans Willem; Paiva, Maria Stela Veludo de; Almeida, Lirio O.B

    1989-12-31

    This abstract presents a description of the minimum system implemented with the graphic processor TMS34010, which will be used in the reconstruction, treatment and interpretation f images obtained by NMR tomography. The project is being developed in the LIE (Electronic Instrumentation Laboratory), of the Sao Carlos Chemistry and Physical Institute, S P, Brazil and is already in operation 4 refs., 7 figs.

  11. Confirmation of the definitive structure of Fleishmann`s lactone by NMR; Confirmacao da estrutura definitiva da lactona de Fleishmann por RMN

    Energy Technology Data Exchange (ETDEWEB)

    Figueroa Villar, Jose Daniel [Instituto Militar de Engenharia (IME), Rio de Janeiro, RJ (Brazil). Secao de Quimica

    1993-12-31

    The reaction between 4-hydroxy-6-methyl-pyrone and ethyl-acetic-acetate produces a compound known since the beginning of the century, named Fleishman lactone in honor to its discover. The structure of this compound has been the aim of several researches due to its similarity with several poly-pyrones which are important in synthesis of important products. This work presents the accurate determination of the structure of the Fleishman lactone. The methodology is presented as well as confirmation tests 9 refs., 2 tabs.

  12. NMR of proteins (4Fe-4S): structural properties and intramolecular electron transfer; RMN de proteines (4Fe-4S): proprietes structurales et transfert electronique intramoleculaire

    Energy Technology Data Exchange (ETDEWEB)

    Huber, J G

    1996-10-17

    NMR started to be applied to Fe-S proteins in the seventies. Its use has recently been enlarged as the problems arising from the paramagnetic polymetallic clusters ware overcome. Applications to [4Fe-4S] are presented herein. The information derived thereof deepens the understanding of the redox properties of these proteins which play a central role in the metabolism of bacterial cells. The secondary structure elements and the overall folding of Chromatium vinosum ferredoxin (Cv Fd) in solution have been established by NMR. The unique features of this sequence have been shown to fold as an {alpha} helix at the C-terminus and as a loop between two cysteines ligand of one cluster: these two parts localize in close proximity from one another. The interaction between nuclear and electronic spins is a source of additional structural information for (4Fe-AS] proteins. The conformation of the cysteine-ligands, as revealed by the Fe-(S{sub {gamma}}-C{sub {beta}}-H{sub {beta}})Cys dihedral angles, is related to the chemical shifts of the signals associated with the protons of these residues. The longitudinal relaxation times of the protons depend on their distance to the cluster. A quantitative relationship has been established and used to show that the solution structure of the high-potential ferredoxin from Cv differs significantly from the crystal structure around Phe-48. Both parameters (chemical shifts and longitudinal relaxation times) give also insight into the electronic and magnetic properties of the [4Fe-4S] clusters. The rate of intramolecular electron transfer between the two [4FE-4S] clusters of ferredoxins has been measured by NMR. It is far slower in the case of Cv Fd than for shorter ferredoxins. The difference may be associated with changes in the magnetic and/or electronic properties of one cluster. The strong paramagnetism of the [4Fe-4S] clusters, which originally limited the applicability of NMR to proteins containing these cofactors, has been proven instrumental in affording new information about the structural and kinetic properties of such proteins. (author).

  13. NMR study of electrode materials for lithium ion-batteries; Etude par RMN de materiaux d'electrode pour batteries lithium-ion

    Energy Technology Data Exchange (ETDEWEB)

    Chazel, C.

    2006-01-15

    This work is devoted to the study of LiMO{sub 2} et LiM{sub 2}O{sub 4} (M: transition metal) intercalation compounds used as electrode material for lithium-ion batteries. Solid state NMR allows one to characterise the local environment of the lithium ions present in these phases by the use of the hyperfine interactions due to the presence of some electron spin density coming from localised electrons (Fermi-contact shift) or itinerant electrons (Knight shift) on the lithium nucleus. By following the transformation of the LiNiO{sub 2} layered phase into the LiNi{sub 2}O{sub 4} spinel material using lithium NMR, we studied the nature of the asymmetric signal observed for LiNiO{sub 2}, and the influence of the departure from the ideal stoichiometry; we showed a coupled ion/electron hopping in Li{sub X}NiO{sub 2} phases linked to Li/vacancy and Ni{sup 3+}/Ni{sup 4+} ordering, and finally showed the existence of structural defects within the LiNi{sub 2}O{sub 4} spinel phase obtained by thermal treatment of Li{sub 0.5}NiO{sub 2}. Lithium NMR of the intercalated materials obtained from the LiTi{sub 2}O{sub 4} and Li{sub 4}Ti{sub 5}O{sub 12} spinels showed a metallic behaviour for Li{sub 2}Ti{sub 2}O{sub 4} with a Knight shift of the NMR signal similar to that of LiTi{sub 2}O{sub 4}, and signals intermediate in nature between Knight and Fermi-contact shifts for Li{sub 7}Ti{sub 5}O{sub 12}. (author)

  14. Evaluation of thermoplastic starch/MMT nanocomposites by nuclear magnetic resonance (NMR); Avaliacao de nanocompositos de amido termoplastico e argila por RMN

    Energy Technology Data Exchange (ETDEWEB)

    Schlemmer, D.; Rodrigues, Tiago C.A.F.; Resck, I.S.; Sales, M.J.A., E-mail: danielas@unb.b [Universidade de Brasilia (LabPol/UnB), DF (Brazil). Inst. de Quimica. Lab. de Pesquisa em Polimeros

    2010-07-01

    Starch has been studied for replace petrochemical plastics for short shelf life. However, the starch films have limitations: sensitivity to moisture and poor mechanical strength. This can be improved by incorporating loads such as montmorillonite, forming nanocomposites. Nanocomposites were prepared with 1, 3, 5 and 10% of montmorillonite, using vegetable oils of Brazilian Cerrado as plasticizers. The NMR spectra of oils are similar, but the intensities of the signals varying with the proportion of fatty acids. The molar mass of the oils was also calculated by NMR. The spectrum of CP/MAS {sup 13}C NMR for starch presented a duplet in 97 and 98 ppm, on the amorphous domains of C-1, indicating a crystal type A. The spectra of the nanocomposites are similar to those of starch and oils. No new peaks appear, suggesting that there are no strong chemical bonds between components. (author)

  15. Time domain NMR and conductivity study of apple pectin biopolymers; Estudo por RMN no dominio do tempo e condutividade em filmes biopolimericos de pectina de maca

    Energy Technology Data Exchange (ETDEWEB)

    Mattos, Ritamara; Souto, Sergio; Tambelli, Caio E., E-mail: cristal_br@yahoo.com.br [Universidade de Sao Paulo (USP), Pirassununga, SP (Brazil). Faculdade de Zootecnia e Engenharia de Alimentos

    2013-07-01

    This communication presents results of {sup 1}H nuclear magnetic resonance of continuous distributions of spin-spin relaxation time (T{sub 2}) and A.C. conductivity of apple pectin biopolymers plasticised with glycerol and containing acetic acid. The continuous distributions reveals up to three components of spin-spin relaxation times (T{sub 2}). The two short T{sub 2} components were associated with protons of pectin polymer chain and the longer T{sub 2} can be attributed with the protons of the glycerol. The conductivity values increase with glycerol concentration with maximum at 7.9 x 10{sup -4} S cm{sup -1} for sample with 3.0 g of glycerol at 83 deg C. The behavior of activation energy and T{sub 2} continuous distribution indicate an increase of proton mobility due the structural changes caused by glycerol addition. (author)

  16. CONTRIBUTION DE LA RMN 13C A L'ANALYSE D'HUILES ESSENTIELLES ET D'OLEORESINES : CARACTERISATION DE GENEVRIERS ET DU PIN MARITIME DE CORSE

    OpenAIRE

    Ottavioli , Joséphine

    2009-01-01

    The objective of this study was to characterize various plants growing wild in Corsica (juniper, maritime pine) through the composition of their essential oils and resins. For this, we used various chromatographic and spectroscopic techniques, including an analytical method for complex natural mixtures based on 13C NMR spectroscopy, developed in our laboratory. Thus, we showed various aspects of this method of analysis by 13C NMR through i) the study of essential oils of the genus Cymbopogon,...

  17. Computer software for linear and nonlinear regression in organic NMR; Programa de computador para regressao linear e nao linear em R.M.N. organica

    Energy Technology Data Exchange (ETDEWEB)

    Canto, Eduardo Leite do; Rittner, Roberto [Universidade Estadual de Campinas, SP (Brazil). Inst. de Quimica

    1992-12-31

    Calculation involving two variable linear regressions, require specific procedures generally not familiar to chemist. For attending the necessity of fast and efficient handling of NMR data, a self explained and Pc portable software has been developed, which allows user to produce and use diskette recorded tables, containing chemical shift or any other substituent physical-chemical measurements and constants ({sigma}{sub T}, {sigma}{sup o}{sub R}, E{sub s}, ...) 9 refs., 1 fig.

  18. NMR study of quasi-one-dimensional itinerant-electron magnets RMn{sub 4}Al{sub 8} (R=Y, Lu and Sc)

    Energy Technology Data Exchange (ETDEWEB)

    Muro, Y. [Graduate School of Material Science, University of Hyogo, Kamigori, Ako-gun, Hyogo 678-1297 (Japan)], E-mail: rk04j052@yahoo.co.jp; Nakamura, H.; Kohara, T. [Graduate School of Material Science, University of Hyogo, Kamigori, Ako-gun, Hyogo 678-1297 (Japan)

    2008-04-01

    {sup 55}Mn-NMR measurements, which revealed previously the presence of spin pseudogap in YMn{sub 4}Al{sub 8}, have been extended to LuMn{sub 4}Al{sub 8} and ScMn{sub 4}Al{sub 8}. Temperature (T) dependences of the Knight shift, K, and the nuclear spin-lattice relaxation rate, 1/T{sub 1}, are well explained by the same pseudogap model used to explain a broad maximum observed in the T-dependence of the susceptibility, indicating common nature in the spin excitation spectrum in the quasi-one-dimensional itinerant-electron compounds.

  19. 12. Brazilian meeting on magnetic resonance; mini-course in NMR. Abstracts and program; 12. Jornada brasileira de ressonancia magnetica; mini-curso em RMN

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-07-01

    Theoretical and experimental papers are presented in these proceedings comprehending the following subjects: nuclear magnetic resonance, organic and non organic compounds, polymers, petroleum, physical chemistry, chemical structures, molecular biology, molecular structures and proteins.

  20. Effect of substitution groups in carbon-13 NMR of tri-substituted camphors; Efeitos de substituintes em RMN de carbono-13 de canforas 3-substituidas

    Energy Technology Data Exchange (ETDEWEB)

    Kaiser, Carlos R; Rittner, Roberto [Universidade Estadual de Campinas, SP (Brazil). Inst. de Quimica; Basso, Ernani A [Universidade Estadual de Maringa, PR (Brazil). Dept. de Quimica Inorganica

    1994-12-31

    This work presents and discusses the empirical effects of substitution groups in the carbon-13 NMR spectra of tri-substituted camphors and their correlation with the chemical properties of such substitution groups such as electronegativity. The obtained results are presented and discussed

  1. Mono terpenes characterization by {sup 1} H and {sup 13} C-1 NMR; Caracterizacao de monoterpenos por RMN - {sup 1} H e de {sup 13} C-1

    Energy Technology Data Exchange (ETDEWEB)

    Araujo, Martha T. de [Universidade Federal Fluminense, Niteroi, RJ (Brazil). Dept. de Fisico-Quimica; Silveira, Carmen L.P. [Universidade Federal Fluminense, Niteroi, RJ (Brazil). Dept. de Quimica Organica; Mcchesney, James D [Mississippi Univ., University, MS (United States). Research Inst. of Pharmaceutical Sciences

    1992-12-31

    Artemisinine, a new lactone sesquiterpene containing one peroxide binding, is the main anti malarial agent obtained from the Artemisia annua L. Viewing to obtain a simple synthetic route for artemisinic acid preparation, which is the key intermediary for total synthesis of this type of anti malarial agent, R-carvone has been chosen as starting material. The S-carvone was used as model for reaction optimization and preparation of derivatives to be used for NMR studies. The main objective of this work is the signalling of the {sup 13} C and {sup 1} H NMR spectra, using the 2 D-COSY and 2 D-Hector spectra 4 refs., 3 figs., 1 tab

  2. Studies on kinetic of water phase transition by NMR micro images; Estudos da cinetica de transicao de fase da agua por microimagens de RMN

    Energy Technology Data Exchange (ETDEWEB)

    Crestana, S [Empresa Brasileira de Pesquisa Agrpecuaria (EMBRAPA), Sao Carlos, SP (Brazil). Nucleo de Pesquisa e Desenvolvimento de Instrumentacao Agropecuaria; Posadas D, A [Sao Paulo Univ., Sao Carlos, SP (Brazil). Inst. de Fisica e Quimica; Nielsen, D R [California Univ., Davis, CA (United States)

    1992-12-31

    Nuclear magnetic resonance micro images have been used for studying the fusion and ice formation processes in an unsaturated porous column, containing sand submitted to a variable temperature gradient 3 refs., 5 figs.

  3. {sup 1} H and {sup 13} C NMR of phenyl barbiturilidene; RMN de H-1 e C-13 de fenil barbiturilidenos

    Energy Technology Data Exchange (ETDEWEB)

    Villar, Jose Daniel Figueroa; Santos, Nedina Lucia dos; Cruz, Elizabete Rangel [Instituto Militar de Engenharia (IME), Rio de Janeiro, RJ (Brazil). Secao de Quimica

    1992-12-31

    The condensation of barbituric acids with aromatic aldehydes gives the phenyl barbiturilidenes, which are studied as intermediary compounds in the synthesis of new heterocyclic compounds for pharmaceutical use. One of the most characteristic reactions of these compounds is the Michael type addition reaction, in the exocyclic carbon-carbon double binding. The reaction with 2,4-di nitrophenyl hydrazine reaction is been used as a test of this type of reactivity, which supplies the respective hydrazone and barbituric acid. In this work, preliminary studies have been performed for establishing correlations between the Brown parameter ({sigma}{sup +}), the chemical shifts ({delta}) of the barbiturilidene atoms involved in the reaction, and their reactivities 3 refs., 1 fig., 6 tabs.

  4. {sup 77} Se NMR of deuteride vinyl and acetylene selenides; RMn de {sup 77} Se de selenetos vinilicos e acetilenicos deuterados

    Energy Technology Data Exchange (ETDEWEB)

    Roque, L C; Stefani, H A; Arruda Campos, I.P. de; Comasseto, J V [Sao Paulo Univ., SP (Brazil). Inst. de Quimica

    1992-12-31

    The main objective of this work is a contribution for establishing a data base sufficient for interpretation of the selenium organic compound spectra. Due to the short literature on acetylene and vinyl selenides, the investigation of these compounds using {sup 77} Se NMR has been considered interesting. Particularly, compounds containing the selenium phenyl group have been selected, as they are larger used in organic chemistry. Non usual deuterated compounds have been applied, viewing simplification of the experimental results interpretation, since the use of deuterium virtually eliminates the Se-H coupling constants, due to the protons of the selenium phenyl group 5 refs., 2 tabs.

  5. Solid NMR characterization of hydrogen solid storage matrices; Caracterisation par RMN du solide des matrices de stockage solide de l'hydrogene

    Energy Technology Data Exchange (ETDEWEB)

    Pilette, M.A.; Charpentier, T.; Berthault, P. [CEA Saclay, Dept. de Recherche sur l' Etat Condense, les Atomes et les Molecules, Lab. de Structure et Dynamique par Resonance Magnetique Lab. Claude Frejacques - CEA/CNRS URA 331, DSM/DRECAM/SCM, 91 - Gif sur Yvette (France)

    2007-07-01

    The aim of this work is to develop and validate characterization tools by NMR imagery and spectroscopy of the structure of materials for hydrogen storage, and of their evolution during load/unload cycles. The two main topics of this work are in one hand the analysis of the local structure of the materials and the understanding of their eventual modifications, and in another hand, the in-situ analysis of the distribution and diffusion of hydrogen inside the storage material. (O.M.)

  6. Cânfora: um bom modelo para ilustrar técnicas de RMN Camphor: a good model for illustrating NMR techniques

    Directory of Open Access Journals (Sweden)

    Julliane Diniz Yoneda

    2007-01-01

    Full Text Available The use of Nuclear Magnetic Resonance spectroscopy to establish the three-dimensional structures of molecules is an important component of modern Chemistry courses. The combination of techniques that can be used for this purpose is conveniently illustrated by their application to the camphor molecule. This paper presents applications of several techniques used in NMR spectral interpretation in an increasing order of complexity. The result of individual experiments is illustrated in order to familiarize the user with the way connectivity through bonds and through space is established from 1D/2D-NMR spectra and molecular stereochemistry is determined from different NMR experiments.

  7. Aplicación y nuevos desarrollos de la espectroscopía por RMN para el estudio de procesos de reconocimiento molecular entre carbohidratos y sus receptores

    OpenAIRE

    Berbís Moreno, Manuel Álvaro

    2014-01-01

    Los carbohidratos constituyen uno de los tipos de biomoléculas más complejos y ubicuos, cuyo reconocimiento por parte de receptores proteicos pertenecientes a diversas familias (lectinas, anticuerpos, enzimas y virus) determina una variedad de respuestas relacionadas con procesos fisiológicos y patológicos. El conocimiento, a nivel atómico, de la estructura de los carbohidratos y de sus interacciones con proteínas es esencial para una completa comprensión de muchos procesos vitales, así como ...

  8. Characterization of polyurethane/organophilic montmorillonite nanocomposites by low field NMR; Caracterizacao de nanocompositos de poliuretano/montmorilonita organofilica por RMN de baixo campo

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Marcos Anacleto da [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Laboratorio de Nanocompositos Polimericos; Tavares, Maria I.B.; Nascimento, Suelen A.M.; Rodrigues, Elton J. da R [Universidade Federal do Rio de Janeiro (NUCAT/PEQ/COPPE/UFRJ), RJ (Brazil). Laboratorio de Nanocompositos Polimericos

    2012-07-01

    Polyurethanes are important and versatile materials, mainly due to some of their properties, such as high resistance to abrasion and tearing, excellent absorption of mechanical shocks and good flexibility and elasticity. However, they have some drawbacks as well, such as low thermal stability and barrier properties. To overcome these disadvantages, various studies have been conducted involving organophilic polyurethane/montmorillonite nanocomposites. The investigation of the structure of polyurethane/clay nanocomposites has mainly been done by X-ray diffraction (XRD) and transmission electron microscopy (TEM). In this work, PU/clay nanocomposite films obtained by solution intercalation were studied. The nanocomposites were characterized by XRD and low-field nuclear magnetic resonance (LF-NMR). The LF-NMR measurements, with determination of the spin-lattice relaxation time of the hydrogen nucleus, supplied important information about the molecular dynamics of these nanocomposites. The X-ray diffraction measurements validated the results found by NMR. The thermal stability of the material was also determined by thermogravimetric analysis (TGA) under an inert atmosphere. A slight improvement in this stability was observed in the nanocomposite in comparison with polyurethane (author)

  9. Simulation of NMR signals through the Bloch equations; Simulação de sinais de RMN através das equações de Bloch

    Energy Technology Data Exchange (ETDEWEB)

    Moraes, Tiago Bueno, E-mail: tiagobuemoraes@gmail.com [Universidade de Sao Paulo (USP), Sao Carlos, SP (Brazil). Inst. de Física; Colnago, Luiz Alberto, E-mail: tiagobuemoraes@gmail.com [Embrapa Instrumentação, São Carlos, SP (Brazil)

    2014-07-01

    The aim of this paper was to present a simple and fast way of simulating Nuclear Magnetic Resonance signals using the Bloch equations. These phenomenological equations describe the classical behavior of macroscopic magnetization and are easily simulated using rotation matrices. Many NMR pulse sequences can be simulated with this formalism, allowing a quantitative description of the influence of many experimental parameters. Finally, the paper presents simulations of conventional sequences such as Single Pulse, Inversion Recovery, Spin Echo and CPMG. (author)

  10. Análise do teor e da qualidade dos lipídeos presentes em sementes de oleaginosas por rmn de baixo campo

    Directory of Open Access Journals (Sweden)

    André F. Constantino

    2014-01-01

    Full Text Available To choose among the variety of oleaginous plants for biodiesel production, the oil content of several matrices was determined through different low-field ¹H nuclear magnetic resonance (NMR experiments with varied pulse sequences, namely single-pulse, spin-echo, CPMG, and CWFP. The experiments that involved the first three sequences showed high correlation with each other and with the solvent extraction method. The quality of the vegetable oils was also evaluated on the basis of the existing correlation between the T2 values of the oils and their properties, such as viscosity, iodine index, and cetane index. These analyses were performed using HCA and PCA chemometric tools. The results were sufficiently significant to allow separation of the oleaginous matrices according to their quality. Thus, the low-field ¹H NMR technique was confirmed as an important tool to aid in the selection of oleaginous matrices for biodiesel production.

  11. Propiedades Físico-químicas por RMN de 1H y Constituyentes en el Aceite de Carapa guianensis por ESI-MS

    Directory of Open Access Journals (Sweden)

    Elson Farias Silva

    2015-01-01

    Full Text Available The Andiroba belongs to the botanical family Meliaceae, found in the Amazon mainly two varieties, Carapa guianensis and C. procera. They are species with large logging utility and extracted oil has many uses, especially in lighting, such as healing use, insecticide and anti-inflammatory. In this paper the physico-chemical properties of oil of C. guianensis in São João da Beacon, Roraima through calculations from 1H NMR spectrum using the computer program PROTÓLEOS properties are studied by ESI-MS technique to determine the constituents of said oil are linolenic acid (9.99%, linoleic acid (13.14%, oleic acid (47.32%, unsaturated (70.45% fatty acid and saturated fatty acids (29.55%. The extracted oil of andiroba oil has a yield of 67.03% being the physicochemical properties of the oil as follows: 48.4 mg I2 / g of iodine; 161.67 mg KOH / g of saponification; 1.84% of acid; 1004.02 g / mol average molecular weight; 159.83 mg KOH / g of ester value; 98.87% percent of ester and 0.9166 g / cm3 for the density at 25 ° C. Constituents determined by ESI-MS include: 1,1'-methyl-2,2'-dicarboxylate diantraquinona, dimethyl pirofosfatosantoninate, 2,4,6-tris- (3,5-di-butyl-4-tec -hidroxibencil styrene, (2,3,7,8,12,13,17,18-octanoilporfirinate -Mg (II.

  12. Análise por RMN de produtos de degradação forçada em fármacos

    OpenAIRE

    Ana Cristina Isler

    2014-01-01

    Resumo: A degradação forçada ou teste de estresse é uma boa estratégia para demonstrar as rotas de degradação e os produtos formados durante a estocagem do fármaco ou do produto formulado. O principal objetivo desse teste é demonstrar a especificidade dos métodos indicativos de estabilidade. Tratam-se de ensaios que visam desafiar e confirmar a especificidade e seletividade da metodologia analítica empregada na quantificação do princípio ativo presente no medicamento e na manutenção dessas ca...

  13. A espectroscopia de RMN como ferramenta elucidativa: estruturas moleculares, mecanismos de reação e metabonômica

    OpenAIRE

    SILVA, Ricardo Oliveira da

    2010-01-01

    A espectroscopia de ressonância magnética nuclear é uma poderosa ferramenta para a elucidação estrutural e para o estudo de transformações químicas, intensamente utilizada na área de química orgânica. Recentemente, a fronteira de suas aplicações tem se expandido para incluir a análise de biofluidos com o fim de tentar identificar padrões associados às mais variadas condições fisiopatológicas que, ao afetarem o metabolismo, deixam sua marca de forma reconhecível nos espectros...

  14. Seguridad del paciente en Radioterapia Intraoperatoria: Impacto de los elementos controlados por el Radiofisico

    Science.gov (United States)

    Tarjuelo, Juan Lopez

    tambien se uso para estudiar la estabilidad de las camaras de ionizacion mencionadas. Se realizo la dosimetria in vivo en 45 pacientes con MOSFET reforzados mobile TN-502RDM-H, pelicula radiocromica Gafchromic MD-55-2, y se elaboro un modelo teorico para explicar los datos. Por ultimo, al precisarse el uso en RIO de la simulacion virtual y del calculo de la dosis absorbida en el paciente virtual, se ha ilustrado este apartado con la aceptacion y el estado de referencia inicial del planificador de tratamientos modulados con calculo de Monte Carlo Elekta Monaco. Para ello se utilizaron la camara de ionizacion TW31016-0104 y la matriz seven29 de PTW-Freiburg, pelicula radiocromica Gafchromic EBT-2, y diferentes maniquies. Resultados: El FMEA identifico 57 modos de fallo y efectos potenciales. No se experimentaron sucesos relativos a una administracion inadecuada de la dosis absorbida. Se identificaron las revisiones dobles y por un par como claves para reducir los riesgos asociados al equipo de profesionales involucrado en la RIO. Se identificaron tambien oportunidades de mejora con el uso de la automatizacion y el enclavamiento. En cuanto al SPC, los indices de capacidad del proceso abarcaron de 1,6 a 9,3 para un nivel de especificaciones del +/-2%. Las intervenciones simuladas alcanzaron del 2% al 34% de las sesiones de medida. Las camaras de ionizacion Farmer derivaron en direcciones opuestas en un periodo de 6 anos; aunque ello no se aprecio en los informes de calibracion del laboratorio acreditado. No derivo la camara PPC-40. En la dosimetria in vivo, las medidas de los MOSFET no se desviaron significativamente de las medidas con pelicula. Los valores centrales de las dosis absorbidas quedaron entre la dosis absorbida prescrita y la maxima, con lo que indicaron un tratamiento correcto del lecho tumoral. Las anchuras de los intervalos de confianza de las dosis absorbidas esperadas segun el modelo teorico al nivel del 95% abarcaron del 8,6% al 14,7%. Las verificaciones de

  15. Interaction and transport of cysteamine (MEA) through membrane models. {sup 15}N-NMR et {sup 1}H-NMR; Interaction et transport de la cysteamine (MEA) a travers des membranes modeles. Etude par {sup 15}N-RMN et {sup 1}H-RMN

    Energy Technology Data Exchange (ETDEWEB)

    Lagoueyte, C.; Subra, G.; Bonnet, P.A.; Chapat, J.P.; Debouzy, J.C.; Fauvelle, F.; Berleur, F.; Roman, V.; Fatome, M.; Fernandez, J.P.

    1995-12-31

    We investigated by {sup 15}N-NMR the interactions of [{sup 15}N]-MEA, a radio-protecting aminothiol, with model membranes (SUVs and LUVs) of egg yolk phosphatidylcholine and phosphatidic acid. We prepared LUVs with a pH gradient between the intravesicular space and the bulk medium. Even though the external pH was low, MEA penetrates into the vesicles. With SUVs, {sup 1}H-NMR revealed that the interactions of unlabeled MEA within the hydrophobic core of the bilayer vary with external pH value. (author). 5 refs.

  16. Cannabinoid antagonist in nanostructured lipid carriers (NLCs): design, characterization and in vivo study

    Energy Technology Data Exchange (ETDEWEB)

    Esposito, Elisabetta; Ravani, Laura [Department of Life Sciences and Biotechnology, University of Ferrara, I-44121 Ferrara (Italy); Drechsler, Markus [BIMF/Soft Matter Electron Microscopy, University of Bayreuth (Germany); Mariani, Paolo [Department of Life and Environmental Sciences and CNISM, Università Politecnica delle Marche, I-60100 Ancona (Italy); Contado, Catia [Department of Chemical and Pharmaceutical Sciences, University of Ferrara, I-44121 Ferrara (Italy); Ruokolainen, Janne [Department of Applied Physics, Aalto University, 00076 Aalto (Finland); Ratano, Patrizia; Campolongo, Patrizia [Department of Physiology and Pharmacology, Sapienza University of Rome, 00185 Roma (Italy); Trezza, Viviana [Department of Science, Roma Tre University, 00146 Roma (Italy); Nastruzzi, Claudio, E-mail: nas@unife.it [Department of Life Sciences and Biotechnology, University of Ferrara, I-44121 Ferrara (Italy); Cortesi, Rita [Department of Life Sciences and Biotechnology, University of Ferrara, I-44121 Ferrara (Italy)

    2015-03-01

    This study describes the preparation, characterization, and in vivo evaluation in rats of nanostructured lipid carriers (NLCs) encapsulating rimonabant (RMN) as prototypical cannabinoid antagonist. A study was conducted in order to optimize NLC production by melt and ultrasonication method. NLCs were prepared by alternatively adding the lipid phase into the aqueous one (direct protocol) or the aqueous phase into the lipid one (reverse protocol). RMN-NLCs have been characterized by cryogenic transmission electron microscopy (cryo-TEM), X-ray, photon correlation spectroscopy (PCS) and sedimentation field flow fractionation (SdFFF). Reverse NLCs were treated with polysorbate 80. RMN release kinetics have been determined in vitro by dialysis method. In vivo RMN biodistribution in rats was evaluated after intranasal (i.n.) administration of reverse RMN-NLC. The reverse protocol enabled to prevent the lost of lipid phase and to achieve higher RMN encapsulation efficacy (EE) with respect to the direct protocol (98% w/w versus 67% w/w). The use of different protocols did not affect NLC morphology and dimensional distribution. An in vitro dissolutive release rate of RMN was calculated. The in vivo data indicate that i.n. administration of RMN by reverse NLC treated with polysorbate 80 increased RMN concentration in the brain with respect to the drug in solution. The nanoencapsulation protocol presented here appears as an optimal strategy to improve the low solubility of cannabinoid compounds in an aqueous system suitable for in vivo administration. - Highlights: • Rimonabant (RMN) can be encapsulated in nanostructured lipid carriers (NLCs). • Nanoencapsulation improves RMN solubility in a stable physiologic aqueous formulation. • RMN is released in vitro from NLC by a controlled dissolutive release modality. • I.n. administration leads to higher RMN concentration in the brain with respect to plasma. • NLC increases RMN concentration in the brain with respect to

  17. Determination of the Effectiveness of Control Rods in the VVER Reactor Fuel Assemblies; Determination de l'Efficacite des Barres de Reglage dans les Ensembles Combustibles du reacteur VVER; Opredelenie ehffektivnosti reguliruyushchikh sterzhnej v sborkakh reaktora VVEHR; Determinacion de la Eficacia de las Barras de Control en los Conjuntos de Elementos Combustibles del Reactor VVER

    Energy Technology Data Exchange (ETDEWEB)

    Semenov, V. N.; Lunin, G. L.; Komissarov, L. V.; Kamyshan, A. N.; Halizev, V. I.; Andrianov, G. Ja.; Voznesenskij, V. A.; Kuz' micheva, V. A.; Lebedev, V. I. [Ordena Lenina Institut Atomnoj Energii Im. I.V. Kurchatova, Moskva, SSSR (Russian Federation)

    1964-06-15

    The paper describes experiments done in homogeneous mock-ups of the fuel assemblies from the VVER Reactor (at one level of enrichment) to determine the effectiveness of absorbing systems comprising shim fuel assemblies or water cavities and of absorbing rods clad in jackets made of differing materials. The paper also gives data on some experiments that have been done in mock-ups of assemblies with differing levels of enrichment. These experiments make it possible to verify the methods used in calculation and to evaluate the prospects of using them for heterogeneous reactors. (author) [French] Le memoire decrit les experiences qui ont ete faites pour determiner l 'efficacite des absorbants contenus dans les barres de compensation, l'effet cavitaire et l 'efficacite des absorbants gaines de materiaux divers, au moyen d'assemblages homogenes de cartouches de combustible du reacteur VVER (reacteur de puissance ralenti et refroidi a l 'eau ayant le meme taux d'enrichissement. On y trouve en outre des donnees sur certaines experiences executees a l 'aide d'assemblages de cartouches de combustible taux d'enrichissement differents. Ces travaux permettent de verifier la methode de calcul et d'evaluer ses possibilites d'application aux reacteurs non homogenes. (author) [Spanish] Se describen en la memoria experimentos para determinar la eficacia de los materiales absorbentes contenidos en las barras de compensacion, el efecto de cavitacion y la eficacia de los materiales absorbentes revestidos de diversos materiales, realizados con ayuda de los conjuntos homogeneos de elementos combustibles del reactor VVER (reactor de potencia moderado y refrigerado por agua) con un solo grado de enriquecimiento. Ademas, se exponen datos sobre los experimentos efectuados con ayuda de conjuntos de grados de enriquecimientos; variados. Tales experimentos permiten verificar el metodo de calculo teorico, utilizad o y evaluar la posibilidad de aplicarlo a los reactores no homogeneos. (author

  18. Criticality Studies in a Pilot Plant for Processing MTR-Type Irradiated Fuels; Estudios de Criticidad de una Planta Piloto para el Tratamiento de Combustibles Irradiados Tipo ' MTR '

    Energy Technology Data Exchange (ETDEWEB)

    Pereira Sanchez, G.; Uriarte Hueda, A. [Junta de Energia Nuclear, Division de Materiales Madrid (Spain)

    1966-05-15

    A number of theoretical studies on nuclear safety have been carried out in a pilot plant being constructed at the Junta de Energia Nuclear in Madrid for processing irradiated fuels from the MTR-type experimental reactor JEN-1. The study was carried out working with aqueous and organic solutions at two levels of {sup 235}U enrichment - 20% and 93%. The paper is divided into two main parts: the first deals with the individual items of equipment, and the interactions between these are studied in the second part. The calculations in this second part have been made using three different methods to make it more certain that the system as a whole can never be critical. The first method employed is based on the solid angle concept and makes it possible to fix the maximum {sup 235}U concentrations within the system. The second method, based on the albedo, supplies the value of the multiplication factor K of the whole assembly as a function of the concentration of {sup 235}U. In the last part, the distribution of the equipment is compared with other similar systems and experimental tests from other sources. Finally, the paper specifies the conditions for working the installation which ensure that a nuclear accident can never occur. (author) [Spanish] Se ha efectuado una serie de estudios teoricos sobre la seguridad nuclear de una planta piloto, que se encuentra en construccion en la Junta de Energfa Nuclear situada en Madrid, para el tratamiento de combustibles irradiados procedentes del reactor experimental JEN-1 del tipo MTR. El estudio se ha realizado utilizando disoluciones, tanto acuosas como organicas, con dos grados de enriquecimiento, 20% y 93% en {sup 235}U. Este trabajo comprende dos partes principales: en la primera se han considerado las distintas unidades del equipo individualmente y en la segunda se han estudiado las interacciones entre ellas. El calculo de esta segunda parte se ha hecho por tres metodos diferentes para tener una mayor seguridad de que el

  19. Development of computer programme for the use of empirical calculation of mining subsidence; Desarrollo informatico para utilizacion de los metodos empiricos de calculo de subsidencia minera

    Energy Technology Data Exchange (ETDEWEB)

    1999-09-01

    The fundamental objective of the project is the elaboration of a user friendly computer programme which allows to mining technicians an easy application of the empirical calculation methods of mining subsidence. As is well known these methods use, together with a suitable theoretical support, the experimental data obtained during a long period of mining activities in areas of different geological and geomechanical nature. Thus they can incorporate to the calculus the local parameters that hardly could be taken into account by using pure theoretical methods. In general, as basic calculation method, it has been followed the procedure development by the VNIMI Institute of Leningrad, a particularly suitable method for application to the most various conditions that may occur in the mining of flat or steep seams. The computer programme has been worked out on the basis of MicroStation System (5.0 version) of INTERGRAPH which allows the development of new applications related to the basic aims of the project. An important feature, of the programme that may be quoted is the easy adaptation to local conditions by adjustment of the geomechanical or mining parameters according to the values obtained from the own working experience. (Author)

  20. Personal dosimetry calculations by means of radio pharmacokinetic and gamma graphic studies; Calculos de dosimetria personalizada por medio de estudios radiofarmacocineticos y gammagraficos

    Energy Technology Data Exchange (ETDEWEB)

    Arteaga de Murphy, C; Ferro F, G; Pedraza L, M; Montoya M, C E [Departamento de Medicina Nuclear, Instituto Nacional de Ciencias Medicas y Nutricion, Vasco de Quiroga 15, 14000 Mexico D.F. (Mexico)

    2000-07-01

    The determination of the absorbed radiation dose is an essential factor to assess the risk to patient with a diagnostic study of nuclear medicine but over all it is indispensable for predicting the efficiency of individualized radio pharmacotherapy and weighting up the risk/benefit of the treatment. In studies for diagnostic or/and treatment of nuclear medicine generally the absorbed radiation dose is not determined for each patient since the methods for estimating it are laborious and include complex models such biological as mathematical, therefore is very important to have a relatively easy method. The obtained data with {sup 99m} Tc-Abp., a new radiopharmaceutical for osseous gammagraphy, were used with the purpose of exemplifying a practical method. The radio pharmacokinetic parameters were determined during 24 hours in 10 health voluntaries and serial gamma grams were taken during two hours to another voluntaries. The obtained data were used to estimate, with the MIRDOSE3 computer program, the absorbed radiation dose in an osseous dragging with {sup 99m} Tc-Abp. is low: 0.00472 m Gy/MBq to osseous marrow, mainly to the vertebral column and femur, and 0.00169 m Gy/ MBq to whole body. These data are lower than those informed in the medical literature for other bis phosphonates. (Author)

  1. Syrio. A program for the calculation of the inverse of a matrix; Syrio. Programa para el calculo de la inversa de una matriz

    Energy Technology Data Exchange (ETDEWEB)

    Garcia de Viedma Alonso, L.

    1963-07-01

    SYRIO is a code for the inversion of a non-singular square matrix whose order is not higher than 40 for the UNIVAC-UCT (SS-90). The treatment stands from the inversion formula of sherman and Morrison, and following the Herbert S. Wilf's method for special matrices, generalize the procedure to any kind of non-singular square matrices. the limitation of the matrix order is not inherent of the program itself but imposed by the storage capacity of the computer for which it was coded. (Author)

  2. Parameter calculation tool for the application of radiological dose projection codes; Herramienta de calculo de parametros para la aplicacion de codigos de proyeccion de dosis radiologicas

    Energy Technology Data Exchange (ETDEWEB)

    Galindo G, I. F.; Vergara del C, J. A.; Galvan A, S. J. [Instituto Nacional de Electricidad y Energias Limpias, Reforma 113, Col. Palmira, 62490 Cuernavaca, Morelos (Mexico); Tijerina S, F., E-mail: francisco.tijerina@cfe.gob.mx [CFE, Central Nucleoelectrica Laguna Verde, Carretera Federal Cardel-Nautla Km 42.5, 91476 Municipio Alto Lucero, Veracruz (Mexico)

    2016-09-15

    The use of specialized codes to estimate the radiation dose projection to an emergency postulated event at a nuclear power plant requires that certain plant data be available according to the event being simulated. The calculation of the possible radiological release is the critical activity to carry out the emergency actions. However, not all of the plant data required are obtained directly from the plant but need to be calculated. In this paper we present a computational tool that calculates the plant data required to use the radiological dose estimation codes. The tool provides the required information when there is a gas emergency venting event in the primary containment atmosphere, whether well or dry well and also calculates the time in which the spent fuel pool would be discovered in the event of a leak of water on some of the walls or floor of the pool. The tool developed has mathematical models for the processes involved such as: compressible flow in pipes considering area change and for constant area, taking into account the effects of friction and for the case of the spent fuel pool hydraulic models to calculate the time in which a container is emptied. The models implemented in the tool are validated with data from the literature for simulated cases. The results with the tool are very similar to those of reference. This tool will also be very supportive so that in postulated emergency cases can use the radiological dose estimation codes to adequately and efficiently determine the actions to be taken in a way that affects as little as possible. (Author)

  3. GIS (Geographic Information Systems) based calculation on hydrocarbon generated volume: Amazon Basin example; O uso de SIG no calculo de hidrocarbonetos gerados: exemplo da Bacia do Amazonas

    Energy Technology Data Exchange (ETDEWEB)

    Pedrinha, Saulo; Simoes, Leonardo; Goncalves, Felix T.T.; Carneiro, Jason T.G. [Petroleum Geoscience Technology Ltda. (PGT), Rio de Janeiro, RJ (Brazil)

    2008-07-01

    The calculation of the volume of hydrocarbons generated from a particular source rock a sedimentary basin provides numerical data that help to better describe the petroleum system, and evaluate its potential. Among the various methodologies developed for calculating the volume of oil there is a proposal by Schmoker (1994), which has the advantage to take into account the occurrence of the source rock area in the basin, and the spatial variations in the main geological parameters. Using the tools of a GIS, through the manipulation of georeferred maps, it is possible to calculate the volume of oil generated in a way that would be virtually impossible by using punctual data, only. Even the discretiation maps in minors areas allows, via attribute table in the GIS, the application of a Monte Carlo simulation, which allows to incorporate all the uncertainties related to the input data in the calculation, obtaining distributions of volumes associated with various parts of the final map being integrated throughout the basin. Isopac and maturation maps (Gonzaga et al., 2000), along with TOC data from Barreirinha formation, Amazon Basin, have been scanned and georeferred and, once in the GIS database, were treated in order to spatially distribute the geological properties of the source rock. Then, such maps were handled in accordance with Schmoker (1994) method, leading to a map of mass and distribution of oil generated in the basin at the regional scale. (author)

  4. Nomograms to calculate stability in slate and granite spoil heaps; Abacos para el calculo de estabilidad en escombreras de pizarra y granito

    Energy Technology Data Exchange (ETDEWEB)

    Paz Freire, M.; Taboada Castro, J.; Rivas Brea, T.; Giraldez Perez, E.; Araujo Fernandez, M.

    2011-07-01

    One of the main problems involved in the mining of slate and ornamental granite is the unavoidable generation of waste rock, which must be stored in spoil heaps under suitably integrated, secure and stable conditions. Our work here focuses on this last point. To study the risk of instability within spoil heaps we have analysed the performance of a wide number of models with regard to circular slope failure, taking into account the different degrees of compactness of the material, the characteristics of the material itself, the effect of water pressure and the geometry of the heap. From this analysis we obtained more than 300 safety criteria, which were then used to draw up a series of nomograms to allow us to determine the risk of sliding in any granite or slate spoil heap. Thus, nomograms prove themselves to be suitable, quick, easy-to-use tools for preliminary studies of new structures, for periodic analyses of existing structures and to investigate structures that are due to be modified. (Author) 24 refs.

  5. User's and Programmer's Guide for HPC Platforms in CIEMAT; Guia de Utilizacion y programacion de las Plataformas de Calculo del CIEMAT

    Energy Technology Data Exchange (ETDEWEB)

    Munoz Roldan, A.

    2003-07-01

    This Technical Report presents a description of the High Performance Computing platforms available to researchers in CIEMAT and dedicated mainly to scientific computing. It targets to users and programmers and tries to help in the processes of developing new code and porting code across platforms. A brief review is also presented about historical evolution in the field of HPC, ie, the programming paradigms and underlying architectures. (Author) 32 refs.

  6. Calculation of the backscattering in water and compared to the values in air; Calculo del factor de retrodispersion en agua y comparativa con los valores en aire

    Energy Technology Data Exchange (ETDEWEB)

    Minano Herrero, J. A.; Sarasa Rubio, A.; Roldan Arjona, J. M.

    2011-07-01

    The purpose of this paper is to calculate values of BSF in water and comparison with data on air 11SF found in the literature. For this simulations have been performed by the Monte Carlo method for calculating values ??kerma water in the presence of a manikin of this material and in the absence thereof. The simulations were performed for monoenergetic beams in order to facilitate the calculation of the BSF for any spectral distribution of those found in the field of radiology.

  7. Calculate the high solar radiation for photovoltaic panels in Chile; Aproximacio al calculo de la oferta de energia por paneles fotovoltaicos en Chile

    Energy Technology Data Exchange (ETDEWEB)

    Cancino, Beatriz; Roth, Pedro; Stolz, German [Universidad Tecnica Federico Santa Maria, Valparaiso (Chile); Bonneschky, Alexis [Cottbus University, Cottbus (Germany)

    2000-07-01

    The aim of this work was to develop a method which permits to calculate and predict the theoretically possible electrical energy which can be obtained in different places in Chile with photovoltaic panels used in solar home systems. Chile is a country with a high solar radiation, specially in its northern part, between parallels 18 degrees with a daily mean energy of 4600 Wh/m{sup 2} over the year and 37 degrees, with 3700 Wh/m{sup 2}. Therefore, the use of photovoltaic power is an interesting alternative to be studied and used. Nevertheless, the photovoltaic possibilities have not been studied and no evaluation of real possibilities exist. In a previous paper, the absence of an installation guide for solar home systems have been mentioned. And also the lack of information regarding the real electrical energy needs of people. This work pretends to be the first approximation to a detailed chart and list of possible electric supplies using photovoltaic panels in different locations of Chile. It is made with a computer program which permits to calculate the solar radiation on a tilted surface, on a hourly bases. It uses geographical data and the daily average of monthly radiation. Therefore, the hourly energy, harnessed by the panel can be established and the total energy for some place calculated. [Spanish] El objetivo de este trabajo, es el de mostrar a traves de un listado y un mapa nacional, la cantidad teorica de energia electrica que puede ser obtenida a traves del uso de paneles fotovoltaicos principalmente destinados a Solar Home System (SHS) en Chile. Chile es un pais con una alta oferta de energia solar ubicada principalmente en la zona norte y centro del pais, aproximadamente entre los paralelos 18 grados (sobre 4600 Wh/m{sup 2} dia promedio anual) y 37 grados Sur (sobre 3700 Wh/m{sup 2} dia promedio anual). Por lo que el uso de paneles fotovoltaicos representa una alternativa interesante de ser estudiada y aprovechada. Sin embargo, no existe una evaluacion del potencial solar fotovoltaico en Chile. En un trabajo previo, se detecto la falta de una guia obligatoria y general para la instalacion de los SHS, ademas de la falta de informacion en relacion al potencial electrico real para lograr satisfacer el consumo de las personas. Este trabajo pretende ser la primera aproximacion a una carta detallada de la oferta electrica para el uso de paneles fotovoltaicos en Chile. El mapa de oferta electrica se realiza con la ayuda de un programa computacional el que contiene las ecuaciones necesarias a fin de obtener la radiacion solar para superficie inclinada hora a hora a partir de los datos geograficos y de radiacion solar global promedio mensual sobre superficie horizontal del lugar. Ademas el programa contiene las ecuaciones de un panel fotovoltaico con las que es posible obtener la energia en un lapso de una hora, utilizando como dato de entrada la radiacion a traves de un dia tipico de cada mes y la curva de oferta de energia electrica o curva de energia electrica proporcionada por el panel fotovoltaico escogido.

  8. Adjusting of the power-factor correction. Technical, economic and financial implications; Calculo de correccion del factor de potencia. Implicaciones tecnicas, economicas y financieras

    Energy Technology Data Exchange (ETDEWEB)

    Eficiencia Energetica aplicada (Energiza) [Ciudad Juarez, Chihuahua (Mexico)

    2005-07-01

    A power-factor is a device formed by a dielectric set and electrodes within a container with terminals, able to contribute with capacitance to an electrical circuit, such as: transformers, induction motors, regulators, air conditioning, welding machines, induction furnaces and ballasts. This document also tells us about the location of capacitors in their system, the electrical conductor, the monthly consumption electricity bill, of the benefits when adjusting the power-factor, the liberation of power of the transformer, the reduction of current in feeders, the reduction of losses in feeders, the diminution of the tension fall and the approximate average sale price. [Spanish] Un factor de potencia es un dispositivo formado por un conjunto de dielectrico y electrodos dentro de un recipiente con terminales, capaz de aportar capacitancia a un circuito electrico, como lo son: transformadores, motores de induccion, reguladores, aire acondicionado, maquinas soldadoras, hornos de induccion y balastros. Este documento tambien nos habla acerca de la localizacion de capacitores en su sistema, del conductor electrico, del recibo de consumo mensual de energia, de los beneficios al corregir factor de potencia, la liberacion de potencia del transformador, la reduccion de corriente en alimentadores, la reduccion de perdidas en alimentadores, la disminucion de la caida de tension y el precio de venta promedio aproximado.

  9. Fluid dynamic calculations for the cooling of the European Spallation Source (ESS) target; Calculos fluidodinamicos para la refrigeracion del target de la Fuente Europea de Espalacin (ESS)

    Energy Technology Data Exchange (ETDEWEB)

    Magan Romero, M.; Sordo Balbin, F.; Domingo, S.; Bermejo, J.; Perlado, J. M.

    2010-07-01

    In this document is simulated the tantalum water cooling, that is going to be used in the ESS-Bilbao, using fluent. The target mesh, the models used and the options choices are displayed. At the end, the results and design recommendations are analyzed.

  10. Calculation of the magnetic vector potential in the TJ-II; Calculo del Potencial Magnetico Vector en el TJ-II

    Energy Technology Data Exchange (ETDEWEB)

    Lopez Fraguas, A.; Lopez Bruna, D.; Romero, J. A.

    2005-07-01

    The properties of the vector magnetic potential and its usefulness to calculate magnetic fluxes in both stationary and time-dependent conditions are p revised in this report. We have adapted to the TJ-II Flexible Heliac efficient numerical expressions to calculate the vector potential, calculating in addition the magnetic flux with this formalism in circumstances whose complexity makes very convenient the use of the vector potential. The result on induced voltages offer theoretical support to the measurements of induced voltage due to the OH coils in the plasma, like the measurements provided by the loop voltage diagnostic installed in the TJ-II, as well as to the cylindrical approximation of the plasma often used to interpret experimental data. (Author) 11 refs.

  11. Modelo para calculo estimación del carbono en Tipo Forestal Roble-Raulí-Coigüe en la Reserva Nacional Malleco: Chile

    Directory of Open Access Journals (Sweden)

    Norman Moreno Garcia

    2011-12-01

    Full Text Available El objetivo de este trabajo es la selección de un modelo para estimación de carbono en Tipo Forestal Roble-Raulí y Coigüe. La recolección de datos se realizo en la Reserva Nacional Malleco. Cada sitio fue representado por un grupo de 5 parcelas (cuadradas, de lado 35m, superficie 1225m2, ubicadas en un transecto según la pendiente más fuerte. Fueron estimados los volúmenes de madera con y sin corteza de la totalidad de los individuos por medio de funciones para cada especie del tipo forestal en estudio. La cantidad de carbono almacenado a nivel de fuste de las parcelas fue estimada aplicando la función universal de carbono. En cada parcela se contabilizaron los árboles por clase diamétrico de DAP, siendo definidas las clases a partir del DAP mínimo de 3 cm y con una amplitud de 5 cm. Fueron ajustados los modelos de Spurr, Meyer, Stoate, Naslund y Schumacher-Hall. El modelo Schumacher-Hall presento el mejor ajuste de acuerdo a los indicadores estadísticos considerados, además de una mejor distribución de residuales.

  12. El papel de sistemas de calculo formal en la comprensión de las matemáticas: el caso de la integral definida

    Directory of Open Access Journals (Sweden)

    Vicente D. Estruch

    2010-06-01

    Full Text Available Este estudio forma parte de una investigación más amplia que pretende estudiar la incidencia de la tecnología de la información y de la comunicación (Tic en la comprensión de nociones básicas del cálculo. En concreto, en este artículo mostraremos una serie de actividades diseñadas con un asistente matemático (MatlabQc y bajo el marco teórico constructivista Acción-Proceso-Objeto y eSquema (Apos, que pretenden mejorar la comprensión de la integral definida en alumnos de ingenierías relacionadas con el medio ambiente y la naturaleza. Estas prácticas se diseñaron pensando en estudiantes con un conocimiento básico del programa; no obstante pueden plantarse actividades que requieran un mayor conocimiento del asistente.

  13. Incertidumbre en los valores de la fuerza de oscilador de las lineas espectrales y su influencia en el calculo de abundancias

    Science.gov (United States)

    Marchiano, P. E.; Di Rocco, H. O.; Cruzado, A.

    In this paper; we compare oscillator strengths values from XeII lines theoretically obtained with values obtained via experimentation. We put forward a working hypothesis aimed at reaching the best possible agreement; and applying it to the study of abundances of other elements in the atmospheres of chemically peculiar stars. FULL TEXT IN SPANISH

  14. Calculo y comparacion de la prima de un reaseguro de salud usando el modelo de opciones de Black-Scholes y el modelo actuarial

    Directory of Open Access Journals (Sweden)

    Luis Eduardo Giron

    2015-12-01

    Full Text Available La presente investigación pretende calcular y comparar la prima de un reaseguro  usando el modelo de opciones de Black-Scholes y el modelo clásico actuarial tradicional. El período de análisis va desde enero de 2011 hasta diciembre de 2012. Los resultados obtenidos muestran que el modelo de Black-Scholes, que se utiliza normalmente para valorar opciones financieras, puede ser también usado para la estimación de primas de reaseguros de salud; y que la prima neta estimada a partir de este modelo se aproxima a las establecidas por el método actuarial, excepto cuando el deducible del reaseguro es muy alto (por encima de $200.000.000.

  15. Calculation of neutron fluence to dose equivalent conversion coefficients using GEANT4; Calculo de coeficientes de fluencia de neutrons para equivalente de dose individual utilizando o GEANT4

    Energy Technology Data Exchange (ETDEWEB)

    Ribeiro, Rosane M.; Santos, Denison de S.; Queiroz Filho, Pedro P. de; Mauricio, CLaudia L.P.; Silva, Livia K. da; Pessanha, Paula R., E-mail: rosanemribeiro@oi.com.br [Instituto de Radioprotecao e Dosimetria (IRD/CNEN-RJ), Rio de Janeiro, RJ (Brazil)

    2014-07-01

    Fluence to dose equivalent conversion coefficients provide the basis for the calculation of area and personal monitors. Recently, the ICRP has started a revision of these coefficients, including new Monte Carlo codes for benchmarking. So far, little information is available about neutron transport below 10 MeV in tissue-equivalent (TE) material performed with Monte Carlo GEANT4 code. The objective of this work is to calculate neutron fluence to personal dose equivalent conversion coefficients, H{sub p} (10)/Φ, with GEANT4 code. The incidence of monoenergetic neutrons was simulated as an expanded and aligned field, with energies ranging between thermal neutrons to 10 MeV on the ICRU slab of dimension 30 x 30 x 15 cm{sup 3}, composed of 76.2% of oxygen, 10.1% of hydrogen, 11.1% of carbon and 2.6% of nitrogen. For all incident energy, a cylindrical sensitive volume is placed at a depth of 10 mm, in the largest surface of the slab (30 x 30 cm{sup 2}). Physic process are included for neutrons, photons and charged particles, and calculations are made for neutrons and secondary particles which reach the sensitive volume. Results obtained are thus compared with values published in ICRP 74. Neutron fluence in the sensitive volume was calculated for benchmarking. The Monte Carlo GEANT4 code was found to be appropriate to calculate neutron doses at energies below 10 MeV correctly. (author)

  16. Approximate calculus of the auto transformers and power transformers capacitances; Calculo aproximado de las capacitancias de autotransformadores y transformadores de potencia

    Energy Technology Data Exchange (ETDEWEB)

    Carrasco, Gustavo [C.V.G. Electrificacion del Caroni, C.A. (EDELCA), Caracas (Venezuela)]. E-mail: gcarrasco@edelca.com.ve

    2001-07-01

    This paper develops a mathematical relation for the approximated calculus of the capacitances of the EDELCA power transformers and auto transformers. This mathematical relation is based on the type of transformers construction (Nucleus and shell type), the dielectric properties of the internal insulation material and the electric parameters (Voltage and power)

  17. Calculation of the CAREM reactor with the HUEMUL-PUMA-THERMIT chain of codes; Calculo del reactor CAREM con la cadena de codigos HUEMUL-PUMA-THERMIT

    Energy Technology Data Exchange (ETDEWEB)

    Notari, Carla; Grant, Carlos R [Comision Nacional de Energia Atomica, General San Martin (Argentina)

    2000-07-01

    The purpose of the work was the evaluation of the the CAREM 25 reactor core, using a chain of codes (HUEMUL-PUMA-THERMIT) different to the one used in the original design (CONDOR-CITVAP-THERMIT). First, we performed a partial validation of the our codes in lattices similar to CAREM and reproduced a benchmark for simulation of gadolinium burnup. The results were considered satisfactory for this stage of the project. Then, we calculated the core along the normal operating equilibrium cycle and in hot and cold shut-down conditions. The main outcome of our evaluation confirms the general behaviour of the reference calculations except in one important point referring to the cold shut down. In this condition, the failure of one single rod of bank number 13 of the shut down system, leaves the core in a supercritical state at the beginning of the cycle and this anomaly persists during almost a third of the overall cycle. A new design of the core is proposed with minor modifications of the reference one, without introducing new types of fuel elements and keeping the same fuel management scheme. This new core fulfills all the design requirements. (author)

  18. Anomalies in Ward identities revisited. Explicit calculation of the three point functions; Anomalias em identidades de Ward revisitadas. Calculo explicito das funcoes de tres pontos

    Energy Technology Data Exchange (ETDEWEB)

    Dalmolin, Fabricio Tronco

    2007-07-01

    The occurrence of unavoidable violations in symmetry properties of physical amplitudes is certainly one of the most intriguing problems in the context of Quantum Field Theory (QFT). These violations, which are called anomalies, play a crucial role in the construction of such theories due to the requirement of renormalizability. These phenomena can be established through very general mathematical arguments which are valid also for eventual exact solutions of the associated equations of motion. Exact exact solutions, however, are rarely possible, in this context. Given this limitation, the explicit verification of the violations in symmetry properties of physical amplitudes needs to be done within the context of perturbative solutions. The complication of this task is the occurrence of divergences in the perturbative physical amplitudes and all well known problems such as ambiguities associated to the internal momenta routing in loops, which, due to the divergence degree involved, invariably plague the anomalous amplitudes. Due to this fact, anomalies are commonly presented in the literature in a way associated to the referred ambiguities. This traditional association has been questioned in the light of a new strategy for manipulations and calculations involving divergent amplitudes in QFT. Within the context of the referred technique the mentioned ambiguities can be consistently eliminated and all the amplitudes of all the theories and models are dealt in an identical way. The symmetry properties, of non anomalous amplitudes, are simultaneously satisfied for the consistently regularized (ambiguities free) version of the amplitudes. It is also possible to obtain an adequate description of the anomalous amplitudes in a simultaneous way, i.e., by using absolutely the same prescription adopted for the treatment of those non anomalous, which we will show in details along the present work. The investigation which we will report here, in certain sense are complementary to others already performed within the same issue. In particular, in one of such investigation a pioneer and traditional reference has been revisited by using the alternative strategy mentioned above. In such study, a systematic treatment of purely fermionic one, two and three point functions, associated to scalar, pseudo-scalar, vector and axial-vector densities, has done. There, however, only the explicit expressions for one and two point functions were developed. The conclusions pointed out, in a very clear way, that the association between intrinsic ambiguities of the perturbative calculation and violations in symmetry properties is not consistent. At the same time, it was concluded that only in an investigation where the explicit forms for the three point functions involved are considered clean and sound conclusions can be extracted. This is due to the fact that, in the relevant symmetry properties, it is involved three ward identities and a low energy limit. This is precisely the main purpose of the present work: to promote a detailed investigation of the relations among green functions and ward identities, within the context of a model having only one specie of 1/2 spin fermionic field, that consider all the amplitudes having superficial degree of divergence higher than the logarithmic one, in a similar way as that made in the work of Gerstein and Jackiw, taking however the explicit form for the three point functions. This is one to get in the analysis, simultaneously, the ward identities and the low energy limits involved in the anomalous amplitudes as required by the Sutherland-Veltman theorem, in order to get an adequate understanding of the anomaly phenomena. We will show that our final results can be mapped in those found with the use of the Dimensional Regularization, in situation where this technique can be applied, or in those of Gerstein and Jackiw, however with conflicting interpretations. Finally, we will show that in the context of the adopted technique the desired results emerge, in a natural way, within the context of an universal interpretation for the amplitudes where the ambiguities are automatically eliminated. (author)

  19. Orintsol. Surfaces with assorted inclination: software to calculate the solar radiation; Orientsol. Superficies con distinta inclinacion Software para el calculo de la radiacion solar

    Energy Technology Data Exchange (ETDEWEB)

    Rus, C.; Almonacid, F.; Hontoria, L.; Perez, P. J.; Munoz, F. J.

    2009-07-01

    The Universidad de Jaen, conscious of the importance of using energy sources respectful with the environment, offers in its Technical Industry Engineer degree, in the specialties of: Mechanics, Electricity and Industrial electronics the optional subjects Solar electricity and Photovoltaic Facilities. With these matters is intended that the students acquire the capability of design, calculate, analyze their different applications. A fundamental aspect in solar facilities is how to know the incident radiation in the plant which we want to analyze or the size. Orintsol software tool, with a didactic aim, facilitates so teaching as learning about solar radiation received on inclined surfaces. (Author) 8 refs.

  20. SHIELD 1.0: development of a shielding calculator program in diagnostic radiology; SHIELD 1.0: desenvolvimento de um programa de calculo de blindagem em radiodiagnostico

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Romulo R.; Real, Jessica V.; Luz, Renata M. da [Hospital Sao Lucas (PUCRS), Porto Alegre, RS (Brazil); Friedrich, Barbara Q.; Silva, Ana Maria Marques da, E-mail: ana.marques@pucrs.br [Pontificia Universidade Catolica do Rio Grande do Sul (PUCRS), Porto Alegre, RS (Brazil)

    2013-08-15

    In shielding calculation of radiological facilities, several parameters are required, such as occupancy, use factor, number of patients, source-barrier distance, area type (controlled and uncontrolled), radiation (primary or secondary) and material used in the barrier. The shielding design optimization requires a review of several options about the physical facility design and, mainly, the achievement of the best cost-benefit relationship for the shielding material. To facilitate the development of this kind of design, a program to calculate the shielding in diagnostic radiology was implemented, based on data and limits established by National Council on Radiation Protection and Measurements (NCRP) 147 and SVS-MS 453/98. The program was developed in C⌗ language, and presents a graphical interface for user data input and reporting capabilities. The module initially implemented, called SHIELD 1.0, refers to calculating barriers for conventional X-ray rooms. The program validation was performed by the comparison with the results of examples of shielding calculations presented in NCRP 147.

  1. Formulation of coarse mesh finite difference to calculate mathematical adjoint flux; Formulacao de diferencas finitas de malha grossa para calculo do fluxo adjunto matematico

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Valmir; Martinez, Aquilino Senra; Silva, Fernando Carvalho da [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia. Programa de Engenharia Nuclear

    2002-07-01

    The objective of this work is the obtention of the mathematical adjoint flux, having as its support the nodal expansion method (NEM) for coarse mesh problems. Since there are difficulties to evaluate this flux by using NEM. directly, a coarse mesh finite difference program was developed to obtain this adjoint flux. The coarse mesh finite difference formulation (DFMG) adopted uses results of the direct calculation (node average flux and node face averaged currents) obtained by NEM. These quantities (flux and currents) are used to obtain the correction factors which modify the classical finite differences formulation . Since the DFMG formulation is also capable of calculating the direct flux it was also tested to obtain this flux and it was verified that it was able to reproduce with good accuracy both the flux and the currents obtained via NEM. In this way, only matrix transposition is needed to calculate the mathematical adjoint flux. (author)

  2. Calculation of electromagnetic field in electric machines through the finite element: Electromagnetic modeling; Calculo de campos electromagneticos en maquinas electricas mediante elemento finito: Modelacion electromagnetica

    Energy Technology Data Exchange (ETDEWEB)

    Rosales, Mario F [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1988-12-31

    In this article are presented the general characteristics of the electromagnetic phenomena that can be described by means of the software CALIIE-2D of the Instituto de Investigaciones Electricas (IIE) derived from a modeling based in the magnetic and electric potentials, always using the MKS rationalized units system. Closed regions are considered with axial or moving symmetry to incorporate the bi-dimensional behavior of the electromagnetic fields. The possibility of means with movement is also included. [Espanol] En este articulo se presentan las caracteristicas generales de los fenomenos electromagneticos que pueden describirse mediante el programa de computo CALIIE-2D, del Instituto de Investigaciones Electricas (IIE), que provienen de una modelacion basada en los potenciales magnetico y electrico, en esta se utiliza sistema MKS racionalizado de unidades. Se consideran regiones cerradas con simetria axial o traslacional para incorporar el comportamiento bidimensional de los campos electromagneticos, se incluye tambien la posibilidad de medios con movimiento.

  3. Calculation of electromagnetic fields in electric machines by means of the finite element. Computational aspects; Calculo de campos electromagneticos en maquinas electricas mediante elemento finito. Aspectos computacionales

    Energy Technology Data Exchange (ETDEWEB)

    Rosales, Mario; De la Torre, Octavio [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1990-12-31

    In this article are described the computational characteristics of the Package CALIIE 2D of the Instituto de Investigaciones Electricas (IIE), for the calculation of bi-dimensional electromagnetic fields. The computational implementation of the package is based in the electromagnetic and numerical statements formerly published in this series. [Espanol] En este articulo se describen las caracteristicas computacionales del paquete CALIIE 2D del Instituto de Investigaciones Electricas (IIE), para calcular campos electromagneticos bidimensionales. La implantacion computacional del paquete se basa en los planteamientos electromagneticos y numericos antes publicados en esta serie.

  4. Calculation of electromagnetic fields in electric machines by means of the finite element. Computational aspects; Calculo de campos electromagneticos en maquinas electricas mediante elemento finito. Aspectos computacionales

    Energy Technology Data Exchange (ETDEWEB)

    Rosales, Mario; De la Torre, Octavio [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1989-12-31

    In this article are described the computational characteristics of the Package CALIIE 2D of the Instituto de Investigaciones Electricas (IIE), for the calculation of bi-dimensional electromagnetic fields. The computational implementation of the package is based in the electromagnetic and numerical statements formerly published in this series. [Espanol] En este articulo se describen las caracteristicas computacionales del paquete CALIIE 2D del Instituto de Investigaciones Electricas (IIE), para calcular campos electromagneticos bidimensionales. La implantacion computacional del paquete se basa en los planteamientos electromagneticos y numericos antes publicados en esta serie.

  5. Code Betal to calculation Alpha/Beta activities in environmental samples; Programa de ordenador Betal para el calculo de la actividad Beta/Alfa de muestras ambientales

    Energy Technology Data Exchange (ETDEWEB)

    Romero, L.; Travesi, A.

    1983-07-01

    A codes, BETAL, was developed, written in FORTRAN IV, to automatize calculations and presentations of the result of the total alpha-beta activities measurements in environmental samples. This code performs the necessary calculations for transformation the activities measured in total counts, to pCi/1., bearing in mind the efficiency of the detector used and the other necessary parameters. Further more, it appraise the standard deviation of the result, and calculus the Lower limit of detection for each measurement. This code is written in iterative way by screen-operator dialogue, and asking the necessary data to perform the calculation of the activity in each case by a screen label. The code could be executed through any screen and keyboard terminal, (whose computer accepts Fortran IV) with a printer connected to the said computer. (Author) 5 refs.

  6. Comparative analysis of the serial/parallel numerical calculation of boiling channels thermohydraulics; Analisis comparativo del calculo numerico serie/paralelo de la termohidraulica de canales con ebullicion

    Energy Technology Data Exchange (ETDEWEB)

    Cecenas F, M., E-mail: mcf@iie.org.mx [Instituto Nacional de Electricidad y Energias Limpias, Reforma 113, Col. Palmira, 62490 Cuernavaca, Morelos (Mexico)

    2017-09-15

    A parallel channel model with boiling and punctual neutron kinetics is used to compare the implementation of its programming in C language through a conventional scheme and through a parallel programming scheme. In both cases the subroutines written in C are practically the same, but they vary in the way of controlling the execution of the tasks that calculate the different channels. Parallel Virtual Machine is used for the parallel solution, which allows the passage of messages between tasks to control convergence and transfer the variables of interest between the tasks that run simultaneously on a platform equipped with a multi-core microprocessor. For some problems defined as a study case, such as the one presented in this paper, a computer with two cores can reduce the computation time to 54-56% of the time required by the same program in its conventional sequential version. Similarly, a processor with four cores can reduce the time to 22-33% of execution time of the conventional serial version. These results of substantially reducing the computation time are very motivating of all those applications that can be prepared to be parallelized and whose execution time is an important factor. (Author)

  7. Renewability emergy index calculation in the evaluation of the sustainability of a national economy; Calculo do indice de renovabillidade emergetica na avaliacao da sustentabilidade de uma economia nacional

    Energy Technology Data Exchange (ETDEWEB)

    Siche Jara, Raul Benito [Universidad Nacional de Trujillo, La Libertad (Peru). Fac. de Ciencias Agropecuarias. Escuela de Ingenieria Agroindustrial], e-mail: Siche.J.R@gmail.com; Ortega Rodriguez, Enrique [Universidade Estadual de Campinas (DEA/FEA/UNICAMP), SP (Brazil). Lab. de Engenharia Ecologica e Informatica Aplicada], e-mail: ortega@fea.unicamp.br

    2006-07-01

    In this study, the emergy methodology was used to analyze the sustainability of the Peruvian economic system. The resources (natural and not natural) and importations had been accounting in units of solar emergy using data of the Peruvian economy for the year 2004. Emergy is an energy measure based in the contribution of the resources and its influence, defined as the energy of a type required producing a flow or storage of another type. The focus of this study is the calculation of the emergy index call 'renewability' (REN), considered as a general measure of the ecological sustainability. In a long period, only systems or processes with high REN are sustainable. This index is calculated by the accounting of the resources renewed used in the economy in emergy units (2.17E+23 seJ) and divided by emergy total that enters to the economic system (6.93E+23 seJ), resulting a REN of 0.31. The renewable resources that use Peru almost represent 20% of the total of renewable resources available in the system. The great amount of renewable resources that Peru can potentially use was calculated in 11.44E+23 seJ, meaning that the system can be more sustainable if the economy is based on increasing the use of renewable resources and to diminish the use of non-renewable resources and imported resources. These data show that Peru has a relatively sustainable economy that can improve or get worse, depending of its politics in the use of resources. (author)

  8. Independent dose calculation of the Tps Iplan in radiotherapy conformed with MLC; Calculo independiente de dosis del TPS Iplan en radioterapia conformada con MLC

    Energy Technology Data Exchange (ETDEWEB)

    Adrada, A.; Tello, Z.; Medina, L.; Garrigo, E.; Venencia, D., E-mail: jorge.alberto.adrada@gmail.com [Instituto Privado de Radioterapia, Obispo Oro 423, X5000BFI Cordoba (Argentina)

    2014-08-15

    The systems utilization of independent dose calculation in three dimensional-Conformal Radiation Therapy (3D-Crt) treatments allows a direct verification of the treatments times. The utilization of these systems allows diminishing the probability of errors occurrence generated by the treatment planning system (Tps), allowing a detailed analysis of the dose to delivering and review of the normalization point (Np) or prescription. The independent dose calculation is realized across the knowledge of dosimetric parameters of the treatment machine and particular characteristics of every individual field. The aim of this work is develops a calculation system of punctual doses for isocentric fields conformed with multi-leaf collimation systems (MLC), where the dose calculation is in conformity with the suggested ones by ICRU Report No. 42, 1987. Calculation software was realized in C ++ under a free platform of programming (Code::Blocks). The system uses files in format Rtp, exported from the Tps to systems of record and verification (Lantis). This file contains detailed information of the dose, Um, position of the MLC sheets and collimators for every field of treatment. The size of equivalent field is obtained from the positions of every sheet; the effective depth of calculation can be introduced from the dosimetric report of the Tps or automatically from the DFS of the field. The 3D coordinates of the isocenter and the Np for the treatment plan must be introduced manually. From this information the system looks the dosimetric parameters and calculates the Um. The calculations were realized in two accelerators a NOVALIS Tx (Varian) with 120 sheets of high definition (hd-MLC) and a PRIMUS Optifocus (Siemens) with 82 sheets. 705 patients were analyzed for a total of 1082, in plans made for both equipment s, the average uncertainty with regard to the calculation of the Tps is-0.43% ± 2.42% in a range between [-7.90 %, 7.50 %]. The major uncertainty was in Np near of the MLC. The software checks the dose in any Np, helps to detect mistakes in the planning. Therefore, concludes that the calculation point should not be in semidarkness zones (near the MLC), because it is what causes the most uncertainty in the independent calculation. (author)

  9. Improvement of a computational algorithm that calculates a simulated distillation curve of crude; Aprimoramento de algoritmo computacional para calculo de curva de destilacao simulada de petroleo bruto

    Energy Technology Data Exchange (ETDEWEB)

    Le Roux, Galo A.C.; Medeiros, Claudia Larini; Gatti, Anderson C. [Universidade de Sao Paulo (USP), SP (Brazil). Escola Politecnica

    2008-07-01

    The objective of this work is the implementation of a software that calculates the Simulated Distillation (SimDis) curve of a crude oil, according to ASTM D5307 (Standard Test Method for the Determination of Boiling Range Distribution of Crude Petroleum by Gas Chromatography). The software is based on the principle that the area of a chromatogram is proportional to the mass percent of crude oil recovered at a given retention time. The boiling points and retention times are correlated by a calibration curve. In order to make the software friendly windows were implemented, that are organized in a menu. Therefore the software turned up more easy to use and practical for the computation of Simulated Distillation Analysis. (author)

  10. Multi-user software of radio therapeutical calculation using a computational network; Software multiusuario de calculo radioterapeutico usando una red de computo

    Energy Technology Data Exchange (ETDEWEB)

    Allaucca P, J.J.; Picon C, C.; Zaharia B, M. [Departamento de Radioterapia, Instituto de Enfermedades Neoplasicas, Av. Angamos Este 2520, Lima 34 (Peru)

    1998-12-31

    It has been designed a hardware and software system for a radiotherapy Department. It runs under an Operative system platform Novell Network sharing the existing resources and of the server, it is centralized, multi-user and of greater safety. It resolves a variety of problems and calculation necessities, patient steps and administration, it is very fast and versatile, it contains a set of menus and options which may be selected with mouse, direction arrows or abbreviated keys. (Author)

  11. HADES. A computer code for fast neutron cross section from the Optical Model; HADES. Un programa numerico para el calculo de seccciones eficaces neutronicas mediante el modelo optico

    Energy Technology Data Exchange (ETDEWEB)

    Guasp, J; Navarro, C

    1973-07-01

    A FORTRAN V computer code for UNIVAC 1108/6 using a local Optical Model with spin-orbit interaction is described. The code calculates fast neutron cross sections, angular distribution, and Legendre moments for heavy and intermediate spherical nuclei. It allows for the possibility of automatic variation of potential parameters for experimental data fitting. (Author) 55 refs.

  12. User's and Programmer's Guide for HPC Platforms in CIEMAT; Guia de Utilizacion y programacion de las Plataformas de Calculo del CIEMAT

    Energy Technology Data Exchange (ETDEWEB)

    Munoz Roldan, A

    2003-07-01

    This Technical Report presents a description of the High Performance Computing platforms available to researchers in CIEMAT and dedicated mainly to scientific computing. It targets to users and programmers and tries to help in the processes of developing new code and porting code across platforms. A brief review is also presented about historical evolution in the field of HPC, ie, the programming paradigms and underlying architectures. (Author) 32 refs.

  13. Calculation of electromagnetic field in electric machines through the finite element: Electromagnetic modeling; Calculo de campos electromagneticos en maquinas electricas mediante elemento finito: Modelacion electromagnetica

    Energy Technology Data Exchange (ETDEWEB)

    Rosales, Mario F. [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1987-12-31

    In this article are presented the general characteristics of the electromagnetic phenomena that can be described by means of the software CALIIE-2D of the Instituto de Investigaciones Electricas (IIE) derived from a modeling based in the magnetic and electric potentials, always using the MKS rationalized units system. Closed regions are considered with axial or moving symmetry to incorporate the bi-dimensional behavior of the electromagnetic fields. The possibility of means with movement is also included. [Espanol] En este articulo se presentan las caracteristicas generales de los fenomenos electromagneticos que pueden describirse mediante el programa de computo CALIIE-2D, del Instituto de Investigaciones Electricas (IIE), que provienen de una modelacion basada en los potenciales magnetico y electrico, en esta se utiliza sistema MKS racionalizado de unidades. Se consideran regiones cerradas con simetria axial o traslacional para incorporar el comportamiento bidimensional de los campos electromagneticos, se incluye tambien la posibilidad de medios con movimiento.

  14. Mathematical model for heat loss calculation through a window; Modelo para el calculo de la perdida de calor por una ventana

    Energy Technology Data Exchange (ETDEWEB)

    Fissore Sch, Adelqui; Cuevas B, Cristian [Universidad de Concepcion (Chile). Facultad de Ingenieria. Dept. de Ingenieria Mecanica]. E-mail: afissore@udec.cl; ccuevas@udec.cl

    2000-07-01

    In the present work a semi-empirical model for heat loss by convection at an indoor window surface with curtain or blind is given. With this model, the convection heat transfer coefficient and temperature of the air at confined space between the curtain and the glass can be calculated. The curtain was modeled with a paper due to the low thermal inertia that it has. The model is based on experimental data obtained for four separations between the paper and the window. Data from numerical simulation program are also used. (author)

  15. Developing a verification tool for calculations dissemination through COBAYA; Desarrollo de una herramienta de verificacion para calculos de difusion mediante COBAYA

    Energy Technology Data Exchange (ETDEWEB)

    Sabater Alcaraz, A.; Rucabado Rucabado, G.; Cuervo Gomez, D.; Garcia Herranz, N.

    2014-07-01

    The development of a software tool that automates the comparison of results with previous versions of the code and results using models of accuracy is crucial for implementing the code new functionalities. The work presented here has been the generation the mentioned tool and the set of reference cases that have set up the afore mentioned matrix. (Author)

  16. Calculos de potenciais de ionização de algumas bases e aza-analogas utilizando o metodo semi-empirico HAM/3

    OpenAIRE

    Jose Jair Vianna Cirino

    1994-01-01

    Resumo: Inicialmente procedeu-se a otimização de geometrias das bases purinas guanina, 8-azaguanjna, xantina, 8-azaxantina e hipoxantina com o uso dos métodos semi-empíricos MNDO, AMI e MNDO-PM3. Nesta etapa também fez-se uso de métodos ab initio utilizando o conjunto de base cep-31G. Os potenciais de ionização dos elétrons do caroço das bases purinas foram calculados posteriormente por meio do método semi-empírico HAM/3 empregando as geometrias otimizadas pelos métodos semi-empíricos na etap...

  17. Comparison between calculation methods of dose rates in gynecologic brachytherapy; Comparacion entre metodos de calculo de tasa de dosis en braquiterapia ginecologica8

    Energy Technology Data Exchange (ETDEWEB)

    Vianello, E.A.; Biaggio, M.F.; Dr, M.F.; Almeida, C.E. de [Laboratorio de Ciencias Radiologicas- (L.C.R.)-D.B.B.- UERJ- R. Sao Francisco Xavier, 524- Pav. HLC- sala 136- CEP 20550-013 Rio de Janeiro (Brazil)

    1998-12-31

    In treatments with radiations for gynecologic tumors is necessary to evaluate the quality of the results obtained by different calculation methods for the dose rates on the points of clinical interest (A, rectal, vesicle). The present work compares the results obtained by two methods. The Manual Calibration Method (MCM) tri dimensional (Vianello E., et.al. 1998), using orthogonal radiographs for each patient in treatment, and the Theraplan/T P-11 planning system (Thratonics International Limited 1990) this last one verified experimentally (Vianello et.al. 1996). The results show that MCM can be used in the physical-clinical practice with a percentile difference comparable at the computerized programs. (Author)

  18. The role of advanced calculation and simulation tools in the evolution of fuel; El papel de las herramientas avanzadas de calculo y simulacion en la evolucion del combustible

    Energy Technology Data Exchange (ETDEWEB)

    Munoz-Reja, C.; Cerracin, A.; Corpa, R.

    2015-07-01

    This article is focused on the role of the advanced calculation/simulation tools on the development of the fuel designs as well as in the assessment of the effect of the changes in the operation. With this purpose, the article describes and shows some examples of the use by ENUSA of some of these tools in the fuel engineering. To conclude, the future on the evolution of the advanced tools is also presented. (Author)

  19. Calculating seismic of slabs ITA NNP Garona; Calculo sismico de las losas del ATI de C.N. Santa maria de Garona

    Energy Technology Data Exchange (ETDEWEB)

    Ezeberry, J. I.; Guerrero, A.; Gamarra, J.; Beltran, F.

    2014-07-01

    This article describes the methodology that Idom has employed to perform the seismic evaluation of slabs within the ITA project of the NPP Santa Maria de Garona. Seismic calculations that have been conducted include consideration of the effects of the interaction of soil structure as well as the possible take-off containers with respect to slab during the earthquake. Therefore, the main contribution of the work is the study of the coupling of rolling containers with the flexibility of the whole ground-slab For calculations has been used ABAQUS/Explicit program, allowing to solve effectively the nonlinearities listed above using explicit integration algorithms over time. The results of the calculations reflect the importance of jointly analyse the seismic responses of slab and containers. (Author)

  20. Simplified calculation of investment costs involved in purifying industrial waste water. Calculo simplificado de los costes de inversion en la depuracion de aguas residuales industriales

    Energy Technology Data Exchange (ETDEWEB)

    Queralt, R. (Junta de Saneamientos. Generalidad de Catalua (Spain))

    1993-03-01

    The calculation of the investment involved in purifying industrial waste water poses certain problems since this is affected either by employing complicated methods which require a great deal of data or, as the sole alternative, through subjective estimates. The present article purposes an intermediate system based on simplified formulas for which it is only necessary to know three parameters, namely, (in the majority of cases) the industrial activity, the flow and the Q.O.D. (Author)

  1. Use of the 'DRAGON' program for the calculation of reactivity devices; Utilizacion del programa DRAGON para el calculo de mecanismos de reactividad

    Energy Technology Data Exchange (ETDEWEB)

    Mollerach, Ricardo; Fink, Jose [Nucleoelectrica Argentina SA (NASA), Buenos Aires (Argentina)

    2003-07-01

    DRAGON is a computer program developed at the Ecole Polytechnique of the University of Montreal and adopted by AECL for the transport calculations associated to reactivity devices. This report presents aspects of the implementation in NASA of the DRAGON program. Some cases of interest were evaluated. Comparisons with results of known programs as WIMS D5, and with experiments were done. a) Embalse (CANDU 6) cell without burnup and leakage. Calculations of macroscopic cross sections with WIMS and DRAGON show very good agreement with smaller differences in the thermal constants. b) Embalse fresh cell with different leakage options. c) Embalse cell with leakage and burnup. A comparison of k-infinity and k-effective with WIMS and DRAGON as a function of burnup shows that the differences ((D-W)/D) for fresh fuel are -0.17% roughly constant up to about 2500 MWd/tU, and then decrease to -0.06 % for 8500 MWd/tU. Experiments made in 1977 in ZED-2 critical facility, reported in [3], were used as a benchmark for the cell and supercell DRAGON calculations. Calculated fluxes were compared with experimental values and the agreement is so good. d) ZED-2 cell calculation. The measured buckling was used as geometric buckling. This case can be considered an experimental verification. The calculated reactivity with DRAGON is about 2 mk, and can be considered satisfactory. WIMS k-effective value is about one mk higher. e) Supercell calculations for ZED-2 vertical and horizontal tube and rod adjuster using 2D and 3D models were done. Comparisons between measured and calculated fluxes in the vicinity of the adjuster rods. Incremental cross sections for these adjusters were calculated using different options. f) ZED-2 reactor calculations with PUMA reveal a good concordance with critical heights measured in experiments. The report describes also particular features of the code and recommendations regarding its use that may be useful for new users. (author)

  2. Calculation methods of reactivity using derivatives of nuclear power and Filter fir; Metodos para o calculo da reatividade usando derivadas da potencia nuclear e o filtro FIR

    Energy Technology Data Exchange (ETDEWEB)

    Diaz, Daniel Suescun

    2007-07-01

    This work presents two new methods for the solution of the inverse point kinetics equation. The first method is based on the integration by parts of the integral of the inverse point kinetics equation, which results in a power series in terms of the nuclear power in time dependence. Applying some conditions to the nuclear power, the reactivity is represented as first and second derivatives of this nuclear power. This new calculation method for reactivity has special characteristics, amongst which the possibility of using different sampling periods, and the possibility of restarting the calculation, after its interruption associated it with a possible equipment malfunction, allowing the calculation of reactivity in a non-continuous way. Apart from this reactivity can be obtained with or without dependency on the nuclear power memory. The second method is based on the Laplace transform of the point kinetics equations, resulting in an expression equivalent to the inverse kinetics equation as a function of the power history. The reactivity can be written in terms of the summation of convolution with response to impulse, characteristic of a linear system. For its digital form the Z-transform is used, which is the discrete version of the Laplace transform. In this method it can be pointed out that the linear part is equivalent to a filter named Finite Impulse Response (Fir). The Fir filter will always be, stable and non-varying in time, and, apart from this, it can be implemented in the non-recursive way. This type of implementation does not require feedback, allowing the calculation of reactivity in a continuous way. The proposed methods were validated using signals with random noise and showing the relationship between the reactivity difference and the degree of the random noise. (author)

  3. Criteria for calculation of effective dose from the individual monitoring; Criterios para calculo de dose efetiva a partir da monitoracao individual

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-11-15

    This Regulation refers to the requirements of the Regulation CNEN-NN.3.01. 'Basic Act of Radiological Protection', as expressed in the section 5.9, and its application to the effective dose calculation for individual occupationally exposed. from the internal and external individual monitoring data

  4. Spectroscopical analysis and molecular mechanics calculation of 8,9-Seco-lanostane; Analise espectroscopica e calculos de mecanica molecular de 8,9-seco-lanostanos

    Energy Technology Data Exchange (ETDEWEB)

    Rehder, Vera G; Fujiwara, Fred Y; Marsaioli, Anita J [Universidade Estadual de Campinas, SP (Brazil). Inst. de Quimica

    1992-12-31

    8.9-Seco-lanostane derivatives have been synthesized visualizing their application as intermediates in chiral building block syntheses and we are here presenting their spectroscopy analyses and MM2 molecular mechanic calculations. (author) 5 refs., 4 figs.

  5. UNA APROXIMACION A LOS DETERMINANTES SOCIOECONOMICOS DE LA MORTALIDAD INFANTIL Y DE NIÑEZ EN BOLIVIA: USO DE METODOS INDIRECTOS DE CALCULO DE MORTALIDAD Y ANALISIS BIVARIADO

    Directory of Open Access Journals (Sweden)

    Pamela Córdova

    2016-01-01

    Full Text Available A pesar de las importantes mejoras en los resultados de salud infantil y de niñez durante el Siglo XXI en América Latina, las tasas de mortalidad infantil y de niñez permanecen inaceptablemente altas en Bolivia encontrándose entre las más elevadas la región, solo por debajo de Haití, dirigiéndose a una deficiente salud infantil y de niñez. Estos resultados requieren de evidencia científica sobre la mejor manera de hacer frente a sus determinantes. Este estudio aproxima, teóricamente, mediante el marco teórico propuesto por Mosley-Chen y Sastry, los determinantes de la mortalidad infantil y de niñez en Bolivia enfocados en características individuales, del hogar y contextual. Además se examina de manera preliminar los niveles y magnitudes de la mortalidad mediante el uso de métodos directos e indirectos de estimación mediante la técnica propuesta por la versión Trussel y la versión Palloni-Heligman del Método de Brass y se realiza un análisis bivariado que da cuenta de relaciones existentes entre la mortalidad infantil y de niñez y las variables a nivel del hogar, individual y contextual relacionado con las políticas públicas.

  6. Validation of analytical method to calculate the concentration of conjugated monoclonal antibody; Validacao de metodo analitico para calculo de concentracao de anticorpo monoclonal conjugado

    Energy Technology Data Exchange (ETDEWEB)

    Alcarde, Lais F.; Massicano, Adriana V.F.; Oliveira, Ricardo S.; Araujo, Elaine B. de, E-mail: lais_alcarde@hotmail.com [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2013-07-01

    The objective of this study was to develop a quantitative analytical method using high performance liquid chromatography (HPLC) to determine the antibody concentration in conjunction with bifunctional chelator. Assays were performed using a high performance liquid chromatograph, and the following conditions were used: flow rate of 1 mL / min, 15 min run time, 0.2 M sodium phosphate buffer pH 7.0 as the mobile phase and column of molecular exclusion BioSep SEC S-3000 (300 x 7.8 mm, 5 μM - Phenomenex). The calibration curve was obtained with AcM diluted in 0.2 M sodium phosphate buffer pH 7.0 by serial dilution, yielding the concentrations: 400 μg/mL, 200 μg/mL, 100 μg/mL, 50 μg/mL, 25 μg/mL and 12.5 μg/mL. From the calibration curve calculated the equation of the line and with it the concentration of the immunoconjugate. To ensure the validity of the method accuracy and precision studies were conducted. The accuracy test consisted in the evaluation of 3 samples of known concentration, being this test performed with low concentrations (50 μg/mL), medium (100 μg/mL) and high (200 μg/mL). The precision test consisted of 3 consecutive measurements of one sample of known concentration, subject to the conditions set forth above for the other tests. The correlation coefficient of the standard curve was greater than 97%, the accuracy was satisfactory at low concentrations as well as accuracy. The method was validated by showing it for the accurate and precise determination of the concentration of the immunoconjugate. Furthermore, this assay was found to be extremely important, because using the correct mass of the protein, the radiochemical purity of the radioimmunoconjugate was above 95% in all studies.

  7. Analyse of the international recommendations on the calculation of absorbed dose in the biota; Analise das recomendacoes internacionais sobre calculo de dose absorvida na biota

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Wagner de S.; Py Junior, Delcy de A., E-mail: wspereira@inb.gov.b, E-mail: delcy@inb.gov.b [Industrias Nucleares do Brasil (UTM/INB), Pocos de Caldas, MG (Brazil). Unidade de Tratamento de Minerios; Universidade Federal Fluminense (LARARA/UFF), Niteroi, RJ (Brazil). Lab. de Radiobiologia e Radiometria; Kelecom, Alphonse [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Programa de Pos-Graduacao em Ciencia Ambiental

    2011-10-26

    This paper evaluates the recommendations of ICRP which has as objective the environmental radioprotection. It was analysed the recommendations 26, 60, 91, 103 and 108 of the ICRP. The ICRP-103 defined the concept of animal and plant of reference (APR) to be used in the RAP based on the calculation of absorbed dose based on APR concept. This last view allows to build a legal framework of environmental protection with a etic, moral and scientific visualization, more defensible than the anthropomorphic concept

  8. Calculation of modification to the toroidal magnetic field of the Tokamak Novillo. Part II; Calculo de modificacion al campo magnetico toroidal del Tokamak nivillo. Parte II

    Energy Technology Data Exchange (ETDEWEB)

    Melendez L, L.; Chavez A, E.; Colunga S, S.; Valencia A, R.; Lopez C, R.; Gaytan G, E

    1992-03-15

    In a cylindrical magnetic topology. the confined plasma experiences 'classic' collisional transport phenomena. When bending the cylinder with the purpose of forming a toro, the magnetic field that before was uniform now it has a radial gradient which produces an unbalance in the magnetic pressure that is exercised on the plasma in the transverse section of the toro. This gives place to transport phenomena call 'neo-classicist'. In this work the structure of the toroidal magnetic field produced by toroidal coils of triangular form, to which are added even of coils of compensation with form of half moon is analyzed. With this type of coils it is looked for to minimize the radial gradient of the toroidal magnetic field. The values and characteristics of B (magnetic field) in perpendicular planes to the toro in different angular positions in the toroidal direction, looking for to cover all the cases of importance are exhibited. (Author)

  9. Activation calculation of steel of the control rods of TRIGA Mark III reactor; Calculo de activacion del acero de las barras de control del reactor TRIGA Mark III

    Energy Technology Data Exchange (ETDEWEB)

    Garcia M, T.; Cruz G, H. S.; Ruiz C, M. A.; Angeles C, A., E-mail: teodoro.garcia@inin.gob.mx [ININ, Carretera Mexico-Toluca sn, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2014-10-15

    In the pool of TRIGA Mark III reactor of the Instituto Nacional de Investigaciones Nucleares (ININ), there are control rods that were removed from the core, and which are currently on shelves of decay. These rods were part of the reactor core when only had fuel standard (from 1968-1989). To conduct a proper activation analysis of the rods, is very important to have well-characterized the materials which are built, elemental composition of the same ones, the atomic densities and weight fractions of the elements that constitute them. To determine the neutron activation of the control rods MCNP5 code was used, this code allows us to have well characterized the radionuclides inventory that were formed during irradiation of the control rods. This work is limited to determining the activation of the steel that is part of the shielding of the control rods, the nuclear fuel that is in the fuel follower does not include. The calculation model of the code will be validated with experimental measurements and calculating the activity of fission products of the fuel follower which will take place at the end of 2014. (Author)

  10. Calculating the movement speed of a contaminated material in soil; Calculo de la velocidad de movimiento de un material contaminado en suelo

    Energy Technology Data Exchange (ETDEWEB)

    Lopez G, D.

    2014-07-01

    The present work describes the project which consisted in the development of an application to facilitate and display a graphic where the displacement and behavior of radioactive contaminants in soil could be observed. Once the data are introduced to the system, this makes the necessary calculations to display a graphic where the displacement of the substance is displayed in a given time. Through the graphs resulting from the program, we can quickly see the behavior and movement of a contaminant substance, but by numerical simulation, it can determine the possible impact caused by a supposition spills of a radioactive substance in soil and thus able to take the appropriate measures to control or avoid an impact resulting highly harmful to health and the environment, so as to determine the distance and time in which the substance already change or transform into another. (Author)

  11. Calculation engine of the planning system for radiotherapy with microbeams; Motor de calculo del sistema de planificacion para la radioterapia con microhaces

    Energy Technology Data Exchange (ETDEWEB)

    Martinez-Rovira, I.; Sempau, J.; Bravin, A.; Prezado, Y.

    2011-07-01

    The TPS calculation engine includes a full modeling of the synchrotron source (energy spectrum, phase space and polarization of the incident photons) and transport through 42 m of optical elements to position the patient, where generating a phase space file (PSF) with the state of the particles. This PSF is used as input for the calculation of doses in a model of the patient, based on computed axial tomography (CT).

  12. Considerations on the calculation of volumes in two planning systems; Consideraciones sobre el calculo de volumenes en dos sistemas de planificacion

    Energy Technology Data Exchange (ETDEWEB)

    Gomez-Tenedor Alonso, S.; Rincon Perez, M.; Penedo Cobos, J. M.; Garcia Castejon, M. A.

    2011-07-01

    The discrepancies in the calculation of the same volume between different planning systems impact on dose-volume histograms and therefore clinical assessment of dosimetry for patients. The transfer, by a local network, tomographic study (CT) and contours of critical organs of patients, between our two planning systems allows us to evaluate the calculation of identical volumes.

  13. Monte Carlo calculations for doses in organs and tissues to oral radiography; Calculo de Monte Carlo para doses em orgaos e tecidos para radiologia oral

    Energy Technology Data Exchange (ETDEWEB)

    Sampaio, E V.M.

    1986-12-31

    Using the MIRD 5 phantom and Monte Carlo technique, organ doses in patients undergoing external dental examination were calculated taking into account the different x-ray beam geometries and the various possible positions of x-ray source with regard to the head of the patient. It was necessary to introduce in the original computer program a new source description specific for dental examinations. To have a realistic evaluation of organ doses during dental examination it was necessary to introduce a new region in the phantom heat which characterizes the teeth and salivary glands. The attenuation of the x-ray beam by the lead shield of the radiographic film was also introduced in the calculation. (author).

  14. Operating Cell Temperature Determination in Flat-Plate Photovoltaic Modules; Calculo de la Temperature de Operacion de Celulas Solares en un Panel Fotovoltaico Plano

    Energy Technology Data Exchange (ETDEWEB)

    Chenlo, F.

    2002-07-01

    Two procedures (simplified and complete) to determine the operating cell temperature in photovoltaic modules operating in real conditions assuming isothermal stationary modules are presented in this work. Some examples are included that show the dependence of this temperature on several environment (sky, ground and ambient temperatures, solar irradiance, wind speed, etc.) and structural (module geometry and size, encapsulating materials, antirreflexive optical coatings, etc) factors and also on electrical module performance. In a further step temperature profiles for non-isothermal modules are analysed besides transitory effects due to variable irradiance and wind gusts. (Author)

  15. Preliminary shielding calculation for the system of CyberKnife robotic radiosurgery; Calculo de blindagem preliminar para o sistema de radiocirurgia robotica CyberKnife

    Energy Technology Data Exchange (ETDEWEB)

    Toreti, Dalila; Xavier, Clarice; Moura, Fabio, E-mail: clarice.xavier@rem.ind.b, E-mail: fabio.moura@rem.ind.b [REM Industria e Comercio Ltda., Sao Paulo, SP (Brazil)

    2011-10-26

    The CyberKnife robotic system uses a manipulator with six grade of freedom for positioning a 6 MV Linac accelerator for treatment of lesions. This paper presents calculations for a standard room, with 200 cm of thickness walls primary, build for a CyberKnife system, and calculations for a room originally designed for a Linac conventional (with gantry), with secondary barriers of 107 cm thickness. After the realization of shielding for both rooms, the results shown that walls of standard room with 200 cm thickness are adequate for the secondary shield, and for a room with a conventional Linac, from all six evaluated points, two would require additional shielding of nine cm and four cm of concrete with 2.4 g/cubic cm. This shows that the CyberKnife system can be installed in a originally designed room for a conventional Linac with neither restrict nor any shielding, since no incidence of beams on the secondary barriers is existent

  16. Syrio. A program for the calculation of the inverse of a matrix; Syrio. Programa para el calculo de la inversa de una matriz

    Energy Technology Data Exchange (ETDEWEB)

    Garcia de Viedma Alonso, L.

    1963-07-01

    SYRIO is a code for the inversion of a non-singular square matrix whose order is not higher than 40 for the UNIVAC-UCT (SS-90). The treatment stands from the inversion formula of sherman and Morrison, and following the Herbert S. Wilf's method for special matrices, generalize the procedure to any kind of non-singular square matrices. the limitation of the matrix order is not inherent of the program itself but imposed by the storage capacity of the computer for which it was coded. (Author)

  17. DIMCO. A new system for mechanical and bidimensional, of nuclear fuel pins; DIMCO un nuevo sistema de calculo mecanico de combustibles nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Moreno, A

    1977-07-01

    The system developed in JEN, for: the mechanical analysis uni and bidimensional, of nuclear fuels is presented. The mathematical and numerical foundations used, are here described. And so the models developed for effects such as swelling, cracking, clad growth etc. Numerical results for several cases are presented. a) Numerical test in one and two dimensions. b) Applicability range, c) Interaction effects. d) Influence of the power history. (Author) 17 refs.

  18. ORBITALES. A program for the calculation of wave functions with an analytical central potential; ORBITALES. Programa de calculo de Funciones de Onda para una Potencial Central Analitico

    Energy Technology Data Exchange (ETDEWEB)

    Carretero, Yunta; Rodriguez Mayquez, E

    1974-07-01

    In this paper is described the objective, basis, carrying out in FORTRAN language and use of the program ORBITALES. This program calculate atomic wave function in the case of ths analytical central potential (Author) 8 refs.

  19. Paradigm shift in LUNG SBRT dose calculation associated with Heterogeneity correction; Cambio de paradigma en SBRT pulmonar asociada al calculo de dosis con correccion de heterogeneidad

    Energy Technology Data Exchange (ETDEWEB)

    Zucca Aparicio, D.; Perez Moreno, J. M.; Fernandez Leton, P.; Garcia Ruiz-Zorrilla, J.; Pinto Monedero, M.; Marti Asensjo, J.; Alonso Iracheta, L.

    2015-07-01

    Treatment of lung injury SBRT requires great dosimetric accuracy, the increasing clinical importance of dose calculation heterogeneities introducing algorithms that adequately model the transport of particles narrow beams in media of low density, as with Monte Carlo calculation. (Author)

  20. Calculation about a modification to the toroidal magnetic field of the Tokamak Novillo. Part I; Calculo sobre una modificacion al campo magnetico toroidal del Tokamak Novillo. Parte I

    Energy Technology Data Exchange (ETDEWEB)

    Chavez A, E.; Melendez L, L.; Colunga S, S.; Valencia A, R.; Lopez C, R.; Gaytan G, E

    1991-07-15

    The charged particles that constitute the plasma in the tokamaks are located in magnetic fields that determine its behavior. The poloidal magnetic field of the plasma current and the toroidal magnetic field of the tokamak possess relatively big gradients, which produce drifts on these particles. These drifts are largely the cause of the continuous lost of particles and of energy of the confinement region. In this work the results of numerical calculations of a modification to the 'traditional' toroidal magnetic field that one waits it diminishes the drifts by gradient and improve the confinement properties of the tokamaks. (Author)

  1. Counting efficiency for radionuclides decaying by beta and gamma-ray emission; Calculo de la eficiencia de recuento de nucleidos que experimentan desintegracion beta y desexcitacion gamma simple

    Energy Technology Data Exchange (ETDEWEB)

    Grau, A.; Garcia-Torano, E.

    1988-07-01

    In this paper, counting efficiency vs figure of merit for beta and gamma-ray emitters has been computed. It is assumed that the decay scheme has only a gamma level and the beta-ray emission may be coincident with the gamma-rays or the internal-conversion electrons. The radionuclides tabulated are: 20 {sub 0}, 20{sub p}, 28{sub A}l, 35{sub p}, 41{sub A}r, 42{sub K}, 47{sub S}e, 62{sub F}e, 66{sub C}u, 81{sub G}e, 86{sub B}b, 108{sub R}u, 112{sub p}d, 121{sub S}n(Ni), 122{sub I}n, 129{sub I}, 141{sub C}e 171{sub T}m, 194{sub O}s, 2O3{sub H}g, 205{sub H}g, 210{sub p}b, 225{sub R}a, 142{sub p}r, 151{sub S}m, 244{sub A}m(m). It has been assumed that the liquid is a toluene based scintillator solution in standard glass vials containing 10 cm''3. (Author) 8 refs.

  2. Calculation of the frequency of excedence in Full Spectrum LOCA by FSR; Calculo de la Frecuencia de excedencia en Full Spectrum LOCA mediante metodologia ISA

    Energy Technology Data Exchange (ETDEWEB)

    Gomez Magan, J. J.; Queral Salazar, C.; Sanchez Perea, M.

    2012-07-01

    In this application LOCA sequences was taken into account the uncertainty in the size of rupture and the operator action times as cooling and depressurization through steam generators. The simulations were performed using the tool SCAIS, dynamically coupled with MAAP code.

  3. Theory and control calculations. Application to BWR and PWR; Teoria y calculo de elementos de control, Aplicacion a PWR y BWR

    Energy Technology Data Exchange (ETDEWEB)

    Velarde, G; Guerra, J

    1972-07-01

    A theoretical method to extend the applicability of P{sub 1} approximation to strong absorbers is given. Tables of effective diffusion parameters for slab and cylindrical geometry as well as a summary of expressions for obtaining the extrapolation length in cases of interest, are included. (Author) 21 refs.

  4. Development of a computational code for calculations of shielding in dental facilities; Desenvolvimento de um codigo computacional para calculos de blindagem em instalacoes odontologicas

    Energy Technology Data Exchange (ETDEWEB)

    Lava, Deise D.; Borges, Diogo da S.; Affonso, Renato R.W.; Guimaraes, Antonio C.F.; Moreira, Maria de L., E-mail: deise_dy@hotmail.com, E-mail: diogosb@outlook.com, E-mail: raoniwa@yahoo.com.br, E-mail: tony@ien.gov.br, E-mail: malu@ien.gov.br [Instituto de Engenharia Nuclear (IEN/CNEN-RJ), Rio de Janeiro, RJ (Brazil)

    2014-07-01

    This paper is prepared in order to address calculations of shielding to minimize the interaction of patients with ionizing radiation and / or personnel. The work includes the use of protection report Radiation in Dental Medicine (NCRP-145 or Radiation Protection in Dentistry), which establishes calculations and standards to be adopted to ensure safety to those who may be exposed to ionizing radiation in dental facilities, according to the dose limits established by CNEN-NN-3.1 standard published in September / 2011. The methodology comprises the use of computer language for processing data provided by that report, and a commercial application used for creating residential projects and decoration. The FORTRAN language was adopted as a method for application to a real case. The result is a programming capable of returning data related to the thickness of material, such as steel, lead, wood, glass, plaster, acrylic, acrylic and leaded glass, which can be used for effective shielding against single or continuous pulse beams. Several variables are used to calculate the thickness of the shield, as: number of films used in the week, film load, use factor, occupational factor, distance between the wall and the source, transmission factor, workload, area definition, beam intensity, intraoral and panoramic exam. Before the application of the methodology is made a validation of results with examples provided by NCRP-145. The calculations redone from the examples provide answers consistent with the report.

  5. 19th International Seapower Symposium

    Science.gov (United States)

    2010-07-01

    mentioning about the newly feder- ated T-RMN. RMN stands for Royal Malaysian Navy, that’s where I come from; but actually in this regard, T-RMN stands for...customs offices, with the taxation departments, with organizations that do the ac- tual invoicing, and with the maritime authorities, which in the case...collaborations have also been proposed. Chief of the Royal Malaysian Navy Admiral Abdul Aziz, for example, has mooted the idea of the Maritime

  6. Analysis of uncertainties, associated to the calculating hypothesis, in discharge tables for high flows estimating, based on mathematics models for calculating water surface profiles fore steady gradually varied flow; Analisis de las incertidumbres, asociadas a las hipotesis de calculo, en la estimacion de curvas de gasto para crcidas, basada en el empleo de modelo matematico de calculo hidraulico en regimen permanente

    Energy Technology Data Exchange (ETDEWEB)

    Aldana Valverde, A. L.; Gonzalez Rodriguez, J. C.

    1999-08-01

    In this paper are analyzed some of the most important factors which can influence on the results of calculating water surface profiles for steady gradually varied flow. In this case, the objective of this kind of modeling, has been the estimation of discharges tables for high flows of river station gages connected to the hydrologic automatic information system (SAIH) of the Confederacion Hidrografica del Sur de Espana, system named red Hidrosur. (Author) 3 refs

  7. Survey of shielding calculation parameters in radiotherapy rooms used in the country and its impact in the existing calculation methodologies; Levantamento de parametros de calculos de blindagem de salas de radioterapia utilizados no pais e seu impacto nas metodologias de calculo existentes

    Energy Technology Data Exchange (ETDEWEB)

    Japiassu, Fernando Parois

    2013-07-01

    When designing radiotherapy treatment rooms, the dimensions of barriers are established on the basis of American calculation methodologies specifically; NCRP Report N° 49, NCRP Report N° 51, and more recently, NCRP Report N° 151. Such barrier calculations are based on parameters reflecting predictions of treatments to be performed within the room; which, in tum, reftect a specific reality found in a country. There exists, however, a variety of modern radiotherapy techniques, such as Intensity Modulated Radiation Therapy (IMRT); Total Body Irradiation (TBl) and radiosurgery (SRS); where patierits are treated in a much different way than during more conventional treatrnents, which are not taken into account the traditional shielding calculation methodology. This may lead to a faulty design of treattnent rooms. In order to establish a comparison between the methodology used to calculate shielding design and the reality of treatments performed in Brazil, two radiotherapy facilitie were selected, both of them offering traditional and modern treatment techniqued as described above. Data in relation with reatments perfotmed over a period of six (6)months of operations in both institutions were collected. Based on tlis informaton, a new set of realistic parameters required for shielding design was estãblished, whicb in turn allowed for a nwe caculation of barrier thickness for both facilities. The barrier thickness resultaing from this calculation was then compared with the barrier thickness propose as part of the original shielding design, approved by the regulatory authority. First, concerning the public facility, the thickness of all primary barriers proposed in the shielding design was actually larger than the thickness resulting from calculations based on realistic parameters. Second, concerning the private facility, the new data show that the thickness of three out of the four primary barriers described in the project is larger than the thickness oresulting from calculation based on current operating conditions. When it comes to thickness of secondary barriers, calculations based on averages of treatments over six months show results below the proposed thicknesses in the shielding design of the public facility. However, data reflecting the most extreme situations observed in routine operations how that the thickness proposed in the design project does not meet hielding requirements. In the private facility, more conservative estimates were used in the shielding design, which resultedin suitable barrier thickness in both normal and extreme operation conditions. In fact, the actual barrier thicknesis in average 31 cm greater than the ehickness required by the reality-based data. The primary barrier thickness resulting from reality-based calculations supports the assumption than smaller primary barrier thickness is required in facilities using modern techniques of radiation therap, as opposed to thickness requirements in facilities that only uses conventional treatment techniques. The hypothesis of increased thickness requirements for secondary barriers of installations using IMRT was confirmed by data obtained from the public facility. The results obtained from the private facility denote that the addition of conservative factors in the calculation method will produce barriers suitable for both average and extreme conditions of accelerator usage. However, corresponding increased costs must also be considered. (author)

  8. The use of stochastic method for the calculation of liquid-vapor multicomponent equilibrium and the contribution of groups theory for the evaluation of fugacity coefficient; Uso de um metodo estocastico para calculo do equilibrio liquido-vapor de sistemas multicomponentes e avaliacao de uma abordagem por contribuicao de grupos para o calculo do coeficiente de fugacidade

    Energy Technology Data Exchange (ETDEWEB)

    Cavalcanti, Rafaelly L.; Oliveira, Jackson A. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Dept. de Engenharia Quimica; Rojas, Leopoldo O.A. [Centro de Tecnologias do Gas (CTGAS), Natal, RN (Brazil)

    2008-07-01

    This work has the main objective of evaluating the mathematical model developed by Jaubert e Mutelet (2004) in terms of the prediction capacity for the calculation of the vapor-liquid equilibrium (VLE). This model is based on Peng-Robinson equation of state (EOS) and it considers the binary interaction parameters (Kij(T)) estimated by a contribution group method and dependent of the temperature. The model proposed by Jaubert e Mutelet (2004), named PPR78 (Predictive Peng-Robinson), was implemented in this work by using the Fortran language. An optimization approach based on the stochastic algorithm of Particle Swarm Optimization (PSO) was used in order to calculate the vapor-liquid equilibrium. Simulations were accomplished for several binary systems and the results were concordant with some experimental data of the investigated systems. However, for some systems different from those presented by Jaubert and Mutelet (2004), the model presented low prediction capacity. In spite of the great demand of computational performance, the algorithm PSO demonstrated robustness during the calculation of VLE and it assured convergence in most of the cases. (author)

  9. Transducer project and optimization of the ultra low magnetic field NMR tomograph reception system system; Projeto de transdutores e otimizacao do sistema de recepcao do tomografo de RMN de campo magnetico ultra baixo

    Energy Technology Data Exchange (ETDEWEB)

    Vidoto, Edson Luiz Gea

    1995-12-31

    The aim of the present work was to optimize the signal to noise ratio in our NMR imaging system (TORM 005) by improving transducer`s reception quality through better designed coils, balanced tuning circuit for this coils and power decoupling circuits and by reducing interference from the electromagnetic environment. For this purpose, we had to modify the internal electromagnetic shielding and incorporate line filters in the more critical signals paths. Also, new types of coils were developed, improving the signal to noise ratio, and allowing us to make clinical exams with superior quality for several anatomies. Balanced circuits for tuning and matching of the coil were studied and built, allowing a reduction of the coil losses because patient`s load. This produced a more reliable coil tuning after positioning each new patient. Circuits to avoid the receiver input overload and decoupling circuits for the isolation of receiver coils from excitation coil were designed and incorporated to the TORM 005. All these alterations of our imaging system (TORM 005) contributed to a significant improvement in the signal to noise ratio, reliability and reproducibility of the system. This permitted to operate the system routinely for clinical applications, research and development in the area of ultra low magnetic field tomography. (author) 46 refs., 66 figs., 11 tabs.

  10. O uso da RMN na caracterização e quantificação de metabólitos produzidos por microorganismos com potencial biotecnológico

    OpenAIRE

    Angela Maria Montes Peral Valente

    2007-01-01

    Atualmente, os microrganismos são responsáveis pela produção de vários antibióticos, imunossupressores e anti-tumorais, além de serem importantíssimos em processos industriais. O presente trabalho descreve os processos de produção e isolamento da citrinina (234,6 mg/L) e do ácido micofenólico (371,2 mg/L) com alto grau de pureza no processo de extração de uma fermentação de 8 e 12 dias respectivamente de um cultivo em meio líquido Czapek enriquecido com 0,2 % de extrato de levedura utilizando...

  11. Synthesis of poly(D,L-lactide-co-glycolide) copolymers and its chemical characterization by NMR and FTIR; Sintese e caracterizacao quimica por RMN e FTIR do copolimero poli(D,L-lactideo-co-glicolideo)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    Poly(D,L-lactide-co-glycolide) copolymer is of great interest for medical applications. This interest is justified by the fact that it is bioreabsorbable, biocompatible and non-toxic, while its degradation kinetics can be modified by the copolymerization ratio of the monomers. In this study, copolymers were synthesized at 175 deg C by opening the rings of the cyclic dimers of the D,L-lactide and glycolide monomers in the presence of stannous octoate initiator and lauryl alcohol co-initiator. The efficient application of a vacuum to the reaction medium, coupled with adequate stirring, is fundamental for the success of the synthesis. The following analysis techniques were used to characterize the synthesized copolymers: Nuclear Magnetic Resonance Spectroscopy (NMR) and Fourier Transform Infrared Spectroscopy (FTIR). The chemical composition and the ratio of the monomers in the synthesized copolymer were determined. (author)

  12. Characterization of Amazon fibers of the peach palm, balsa, and babassu by XDR, TGA and NMR; Caracterizacao das fibras amazonicas de pupunha, babacu e balsa atraves de DRX, TG e RMN

    Energy Technology Data Exchange (ETDEWEB)

    Martins, Maria A.; Marconcini, Jose M., E-mail: mariaalice@cnpdia.embrapa.br [Embrapa Instrumentacao, Sao Carlos-SP (Brazil); Morelli, Carolina L.; Marinelli, Alessandra L.; Bretas, Rosario E.S. [Universidade Federal de Sao Carlos - UFSCar, Sao Carlos, SP (Brazil)

    2011-07-01

    The aim of this work was to present the results by testing X-ray diffraction (XRD), thermogravimetric analysis (TG), nuclear magnetic resonance (NMR) and determining the moisture content of the peach palm, balsa and babassu fibers for assessing the feasibility of composite materials. The fibers of peach palm, balsa and babassu showed characteristic chemical structure of lignocellulosic material, and good thermal stability up to 220 deg C. The fiber with the highest crystallinity index (Ic) is the peach palm (72%) and the less crystalline is the babassu (37%), while the balsa fibers have Ic equal to 64%. The results have shown that these fibers can be used in the manufacture of composite materials. (author)

  13. NMR studies of the molecules dynamics to the solid-liquid interfaces: from graded porous materials to oil rocks; Etudes RMN de la dynamique des molecules aux interfaces solide-liquide: des materiaux poreux calibres aux roches petroliferes

    Energy Technology Data Exchange (ETDEWEB)

    Godefroy, S

    2001-11-01

    Low field NMR relaxation for laboratory or in-situ applications provides critical information for oil recovery such as porosity, saturation, and permeability of rocks. In addition, pore size distribution and wettability can also be obtained in some cases. The technique relies on the measurement of proton longitudinal (T{sub 1}) or transverse (T{sub 2}) nuclear relaxation times. For better predictions, the surface micro-dynamics and the chemical properties of the liquids entrapped in the pore space are important and must be characterized. It is well known that the NMR relaxation is enhanced by the paramagnetic impurities at the pore surface but many other parameters influence the relaxation time distributions. These parameters are used to derive the petrophysical properties of the rocks. We propose here an original method to probe the dynamics of water and oil at the pore surface. In the present study, we used both nuclear relaxation at 2.2 MHz and field cycling Nuclear Magnetic Relaxation Dispersion (NMRD) techniques. We applied these two techniques to different kinds of water or oil saturated macroporous media (grain packings, outcrop and reservoir rocks with SiO{sub 2} or CaCO{sub 3} surfaces). We studied the dependence of NMR relaxation on pore size, magnetic field and temperature. Varying the pore size and the surface density of paramagnetic impurities of water saturated grain packings allowed experimental evidence for the two limiting regimes of the water relaxation in pores (surface- and diffusion-limited regimes). NMRD technique (evolution of 1/T{sub 1} with the magnetic field) allowed us to probe liquid surface dynamics in water or oil fully saturated grain packing, outcrop rocks or reservoir rocks (water- and oil-wet surfaces). We evidenced a two-dimensional molecular surface diffusion and directly estimated important parameters such as correlation times, residence times and molecular self-diffusion on the surface. Finally, we proved that the temperature dependence of T{sub 1} and T{sub 2} is directly related to the surface chemistry of the rocks. Such a dependence is clearly important for oil field in-situ measurements (well logging). (author)

  14. ESTUDO ATRAVÉS DE RMN DE 13C NO ESTADO SÓLIDO SOBRE A SÍNTESE DE OXIDO DE GRAFITE UTILIZANDO DIFERENTES PRECURSORES GRAFÍTICOS

    Directory of Open Access Journals (Sweden)

    Mariana A. Vieira

    Full Text Available The influence of the structural and microstructural characteristics of graphitic precursors on the production of graphite oxide (GO is investigated in the present work. Six different graphitic precursors were used to produce GO following a modified Hummers method, namely: natural graphite, commercial lubricant graphite, milled graphite, graphite flakes, high-purity graphite and graphite recycled from Li-ion batteries. The products were characterized by X-ray diffraction (XRD, thermogravimetry, solid-state 13C nuclear magnetic resonance (NMR and scanning electron microscopy (SEM. 13C NMR spectra revealed the presence of epoxy, hydroxyl, carbonyl and lactol groups in the synthesized GOs. However, the oxidation degree of each product was found to be dependent on the average crystallite size (Lc and particle size of the graphitic precursors, with the best GO samples being produced from the milled graphite and the graphite recycled from ion-Li batteries. These results were rationalized in terms of the structural and microstructural differences among the graphitic precursors, as revealed by the XRD patterns and SEM images, evidencing the importance of the correct choice of the precursor aiming the achievement of a well-developed structure for the GO product.

  15. Applications of artificial intelligence techniques to organic chemistry. Study on sup 13 C NMR of steroids using computer. Aplicacoes de tecnicas de inteligencia artificial em quimica organica. Estudo, por computador, de RMN sup 13 C de esteroides

    Energy Technology Data Exchange (ETDEWEB)

    Lins, A P [Instituto Biologico, Sao Paulo, SP (Brazil). Secao de Farmacologia; Furlan, M [UNESP, Araraquara, SP (Brazil). Inst. de Quimica; Gastmans, G P [UNESP, Guaratingueta, SP (Brazil). Inst. de Quimica e Fisica; Emerenciano, V P [Sao Paulo Univ., SP (Brazil). Inst. de Quimica

    1991-01-01

    This work describes the utilization of two groups of programs in searching for characteristic signals of NMR {sup 13}C steroidal compounds. The first group of programs used data bases with the spectral data and a methodology that enables the choice and the search of substructures. The chemical shifts and multiplicities for each specific substructure are used as rules to identify different types and subtypes of steroidal compounds. The second one was built to apply the rules formulated by the first group of programs and to foresee any skeletal based on a spectral analysis. (author).

  16. Interaction study of polyisobutylene with paraffins by NMR using the evaluation of spin-lattice relaxation times for hydrogen nuclei; Estudo da interacao do poliisobutileno com parafinas por RMN no estado solido

    Energy Technology Data Exchange (ETDEWEB)

    Marques, Rosana G.G. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas - CENPES]. E-mail: garrido@cenpes.petrobras.com.br; Tavares, Maria I.B. [Universidade Federal, Rio de Janeiro, RJ (Brazil). Inst. de Macromoleculas]. E-mail: mibt@ima.ufrj.br

    2001-07-01

    The evaluation of spin-lattice relaxation times of {sup 1}H for polyisobutylene/paraffin systems, were obtained using the classic inversion recovery technique, and also through Cross Polarization Magic Angle Spinning (CP/MAS) techniques varying the contact time and also by the delayed contact time pulse sequence. NMR results showed that the polyisobutylene/paraffin systems in which high molecular weight paraffins were used, is heterogeneous. However, for paraffins with low molecular weight, the system presents good homogeneity. (author)

  17. Magnetic field dependence observed by {sup 27} Al NMR of species contained in alumina colloidal dispersions; Dependencia de campo magnetico observada por RMN {sup 27} Al de especies presentes em dispersoes coloidais de alumina

    Energy Technology Data Exchange (ETDEWEB)

    Morgado Junior, Edisson; Menezes, Sonia M.C. [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas; San Gil, Rosane [Universidade Federal, Rio de Janeiro, RJ (Brazil). Inst. de Quimica

    1995-12-31

    The behaviour of some aluminium species front a magnetic field have been investigated by {sup 27} Al NMR analysis, this method was used for characterization of an octahedric aluminium specie from sols prepared by bohemite acid peptization. X-ray diffraction data have identified the mineral structure. The results have been shown and discussed, and NMR spectra were also presented and studied. Concluding this work, the nature of a colloidal specie of alumina was clarified through the dependence research of magnetic field by {sup 27} Al NMR 12 refs., 4 figs., 2 tabs.

  18. {sup 1}H-NMR characterization of cellulose acetate obtained from sugarcane bagasse; Caracterizacao de acetato de celulose obtido a partir do bagaco de cana-de-acucar por {sup 1}H-RMN

    Energy Technology Data Exchange (ETDEWEB)

    Cerqueira, Daniel A., E-mail: daniel.cerqueira@ufba.b [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Inst. de Ciencias Ambientais e Desenvolvimento Sustentavel; Rodrigues Filho, Guimes [Universidade Federal de Uberlandia (UFU), MG (Brazil). Inst. de Quimica; Carvalho, Rui de A. [Universidade de Coimbra (Portugal). Dept. de Bioquimica; Valente, Artur J.M. [Universidade de Coimbra (Portugal). Dept. de Quimica

    2010-07-01

    Cellulose from sugarcane bagasse was used for synthesizing cellulose acetate with different degrees of substitution, which were characterized by {sup 1}H-NMR through the relationship between the peak areas of the hydrogen atoms of the acetate groups (-(C=O)OCH{sub 3}) and the peaks of the hydrogen bonded to the carbon atoms of the glycosidic rings. Suppression of some signals was carried out in order to remove the residual water resonance in the materials and those related to impurities in cellulose triacetate as well. A deconvolution method for the computation of the degree of substitution of acetylation is proposed. The degrees of substitution for the cellulose samples were 2.94 and 2.60, in good agreement with those obtained by chemical determination through an acid-base titration. (author)

  19. Characterization of cellulose acetate obtained from sugarcane bagasse by {sup 1}H-NMR; Caracterizacao de acetato de celulose obtido a partir do bagaco de cana-de-acucar por {sup 1}H-RMN

    Energy Technology Data Exchange (ETDEWEB)

    Cerqueira, Daniel A.; Rodrigues Filho, Guimes, E-mail: d.a.cerqueira@gmail.co [Universidade Federal de Uberlendia (IQ/UFU), MG (Brazil). Inst. de Quimica; Carvalho, Rui A. [Universidade de Coimbra (UC) (Portugal). Dept. de Bioquimica; Valente, Artur J.M. [Universidade de Coimbra (UC) (Portugal). Dept. de Quimica

    2009-07-01

    Cellulose from sugarcane bagasse was used for synthesizing cellulose acetate with different degrees of substitution, which were characterized by {sup 1}H-NMR through the relationship between the peak areas of the hydrogen atoms present at the acetate groups (-(C=O)OCH{sub 3} ) and the peaks of the hydrogen bonded to the carbon atoms of the glycosidic rings. Suppression was carried out in order to remove the peak of residual water in the materials and the peak related to impurities in cellulose triacetate. Degree of substitution values obtained through the resonance deconvolution were compared to those obtained by chemical determination through an acid-base titration. The determined degrees of substitution of the cellulose samples were 2.94 and 2.60. (author)

  20. Study of lignin standard-substances type biphenyl by {sup 13} C NMR; Estudo de substancias-modelo de lignina do tipo bifenila, por RMN de {sup 13} C

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, Marcia Alves; Drumond, Mariza Guimaraes; Veloso, Dorila Pilo [Minas Gerais Univ., Belo Horizonte, MG (Brazil). Dept. de Quimica

    1995-12-31

    Lignins structural study by NMR has utilized standard-substances spectral comparative analysis. This work has present relaxation time studies for lignin standard-substance, and {sup 13} C NMR chemical shift values were also shown and compared for several compounds. NMR spectra were commented besides experimental data analysis 2 figs., 4 tabs.

  1. Methodology for the identification of tri-terpenes mixtures components by {sup 13} C NMR; Metodologia para identificao dos componentes de misturas de triterpenos por RMN de {sup 13} C

    Energy Technology Data Exchange (ETDEWEB)

    Olea, Roberto S.G.

    1991-12-31

    This work describes a methodology for the identification of tri terpenes complex mixtures by {sup 13} C NMR. The use of {sup 13} C NMR techniques, such as obtention of noise decoupled spectra, DEPT 135 and DEPT 90 sequences, allowed the identification of components of triterpene mixtures with identical functionality through comparison of observed {sup 13} C NMR chemical shifts with {sup 13} C NMR chemical shifts reported in the literature. The method proved to be specially helpful in the identification of triterpenes by analysis of chemical shifts assignable to doubly bonded carbons, since the particular position of such double bonds is characteristic of some triterpene skeletons. Application of this methodology indicated the presence of bauerenol, {alpha}-amyrin and {beta}-amyrin in Acmanthera latifolis Griseb. (Malpighiaceae); of germanicone, lupenone, {alpha}-amyrenone and {beta}-amyrenone in Alibertia macrophylla A. Rich. (Rubiaceae); of {alpha}-amyrin acetate, lupeol acetate and {beta}-amyrin acetate in Vernonia polyanthes Schreb. (Asteraceae); {alpha}-amyrenone, {beta}-amyrenone, boehmerone, friedelin, lupenone, {alpha}-amyrin, {beta}-amyrin and glutinol in Scoparia dulcis L. (Scrophulariaceae). (author). 37 refs., 93 figs.

  2. Determinação por RMN das configurações relativas e conformações de alcalóides oxindólicos isolados de Uncaria guianensis

    Directory of Open Access Journals (Sweden)

    Carbonezi Carlos Alberto

    2004-01-01

    Full Text Available Phytochemical studies with leaves of Uncaria guianensis resulted in the isolation of the oxindole alkaloids isomitraphylline (1, 3-isoajmalicine (2 mitraphylline (3, and isomitraphylinic acid (4. Structural assignments of these alkaloids, including relative configurations and conformations, were performed through spectral data and physical properties. 1D and 2D homonuclear and heteronuclear NMR spectroscopy was a valuable tool for the establishment of the relative stereochemistry of those compounds.

  3. Determination of relative configurations and conformations of oxindole alkaloids from Uncaria guianensis by NMR; Determinacao por RMN das configuracoes relativas e conformacoes de alcaloides oxindolicos isolados de Uncaria guianensis

    Energy Technology Data Exchange (ETDEWEB)

    Carbonezi, Carlos Alberto; Hamerski, Lidilhone; Flausino Junior, Otavio Aparecido; Furlan, Maysa; Bolzani, Vanderlan da Silva [UNESP, Araraquara, SP (Brazil). Inst. de Quimica]. E-mail: bolzaniv@iq.unesp.br; Young, Maria Claudia Marx [Instituto de Botanica, Sao Paulo, SP (Brazil). Secao de Fisiologia e Bioquimica de Plantas

    2004-12-01

    Phytochemical studies with leaves of Uncaria guianensis resulted in the isolation of the oxindole alkaloids isomitraphylline (1), 3-isoajmalicine (2) mitraphylline (3), and isomitraphylinic acid (4). Structural assignments of these alkaloids, including relative configurations and conformations, were performed through spectral data and physical properties. 1D and 2D homonuclear and heteronuclear NMR spectroscopy was a valuable tool for the establishment of the relative stereochemistry of those compounds. (author)

  4. NMR study of hyper-polarized {sup 129}Xe and applications to liquid-phase NMR experiments; Etude de la resonance magnetique nucleaire du Xenon{sup 129} hyperpolarise et applications en RMN des liquides

    Energy Technology Data Exchange (ETDEWEB)

    Marion, D

    2008-07-15

    In liquid samples where both nuclear polarization and spin density are strong, the magnetization dynamics, which can be analysed by NMR (nuclear magnetic resonance) methods, is deeply influenced by the internal couplings induced by local dipolar fields. The present thesis describes some of the many consequences associated to the presence in the sample of concentrated xenon hyper-polarized by an optical pumping process. First, we deal with the induced modifications in frequency and line width of the proton and xenon spectra, then we present the results of SPIDER, a coherent polarization transfer experiment designed to enhance the polarization of protons, in order to increase their NMR signal level. A third part is dedicated to the description of the apparition of repeated chaotic maser emissions by un unstable xenon magnetization coupled to the detection coil tuned at the xenon Larmor frequency (here 138 MHz). In the last part, we present a new method allowing a better tuning of any NMR detection probe and resulting in sensible gains in terms of sensitivity and signal shaping. Finally, we conclude with a partial questioning of the classical relaxation theory in the specific field of highly polarized and concentrated spin systems in a liquid phase. (author)

  5. Determination of the percentage of quitine desacetilation reaction by solid state carbon-13 NMR; Determinacao do porcentual de reacao de desacetilacao de quitina por RMN {sup 13} C no estado solido

    Energy Technology Data Exchange (ETDEWEB)

    Ferracin, Ricardo J. [Sao Carlos Univ., SP (Brazil). Centro de Caracterizacao e Desenvolvimento; Cass, Quezia B.; Bassi, Ana L. [Sao Carlos Univ., SP (Brazil). Lab. de Sintese Organica

    1997-12-31

    Quitine is a bi-polymer largely found in invertebrates. As most compounds of this class are insoluble in common organic solvents, the des-acetylation percentile was obtained by carbon-13 solid state nuclear magnetic resonance. The methodology is presented. Results are presented 3 refs., 1 figs.

  6. Chemical constituents from leaves of the Qualea grandiflora: attribution of the NMR data of two diastereoisomeric acylated flavonoid glycosides; Constituintes quimicos das folhas de Qualea grandiflora: atribuicao dos dados de RMN de dois flavoides glicosilados acilados diastereoisomericos

    Energy Technology Data Exchange (ETDEWEB)

    Ayres, Mariane Cruz Costa; Escorcio, Samuel Portela; Costa, Danielly Albuquerque da; Chaves, Mariana H. [Universidade Federal do Piaui, Teresina, PI (Brazil). Dept. de Quimica]. E-mail: mariana@ufpi.br; Gerardo, Magela Vieira Junior; Cavalheiro, Alberto J. [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Araraquara, SP (Brazil). Inst. de Quimica. Dept. de Quimica Organica

    2008-07-01

    Phytochemical investigation from leaves of the Qualea grandiflora (Vochysiaceae) resulted in the isolation and identification of kaempferol-3-O-alpha-L-(4{sup -}E-p-coumaroyl)-rhamnoside, kaempferol-3-O-alpha-L-(4{sup -}Z-p-coumaroyl)-rhamnoside, squalene, phytol, lupeol, alpha-amyrin, beta-amyrin, sitosterol, sitostenone, sitosterol-3-O-beta-D-glucopyranoside, ursolic and oleanolic acids. The structures of the compounds were identified by 1D- and 2D-NMR experiments, mass and UV spectrometry and comparison with literature data. (author)

  7. Desarrollo de nuevas formulaciones de látex de caucho natural libres de n-nitrosaminas, hipoalergénicas y ecológicas, y su caracterización por RMN de campo bajo

    OpenAIRE

    Brasero Espada, Justo

    2016-01-01

    Los artículos de látex de caucho natural están extensamente presentes en nuestra sociedad, ya que se cifran en más de 40,000 los artículos que contienen látex, incluyendo más de 400 dispositivos bio‐médicos. Este éxito se debe a que es un material idóneo para fabricar artículos de paredes muy delgadas con excelentes propiedades barrera y elásticas. Estas propiedades barrera proporcionan una protección muy eficaz contra virus y bacterias que, unidas a la durabilidad, costo y confort, han hecho...

  8. Methodology for the identification of tri-terpenes mixtures components by {sup 13} C NMR; Metodologia para identificao dos componentes de misturas de triterpenos por RMN de {sup 13} C

    Energy Technology Data Exchange (ETDEWEB)

    Olea, Roberto S.G.

    1990-12-31

    This work describes a methodology for the identification of tri terpenes complex mixtures by {sup 13} C NMR. The use of {sup 13} C NMR techniques, such as obtention of noise decoupled spectra, DEPT 135 and DEPT 90 sequences, allowed the identification of components of triterpene mixtures with identical functionality through comparison of observed {sup 13} C NMR chemical shifts with {sup 13} C NMR chemical shifts reported in the literature. The method proved to be specially helpful in the identification of triterpenes by analysis of chemical shifts assignable to doubly bonded carbons, since the particular position of such double bonds is characteristic of some triterpene skeletons. Application of this methodology indicated the presence of bauerenol, {alpha}-amyrin and {beta}-amyrin in Acmanthera latifolis Griseb. (Malpighiaceae); of germanicone, lupenone, {alpha}-amyrenone and {beta}-amyrenone in Alibertia macrophylla A. Rich. (Rubiaceae); of {alpha}-amyrin acetate, lupeol acetate and {beta}-amyrin acetate in Vernonia polyanthes Schreb. (Asteraceae); {alpha}-amyrenone, {beta}-amyrenone, boehmerone, friedelin, lupenone, {alpha}-amyrin, {beta}-amyrin and glutinol in Scoparia dulcis L. (Scrophulariaceae). (author). 37 refs., 93 figs.

  9. γ-decay of {}_{8}^{16}{{\\rm{O}}}_{8}\\,{and}\\,{}_{7}^{16}{{\\rm{N}}}_{9} in proton-neutron Tamm-Dancoff and random phase approximations with optimized surface δ interaction

    Science.gov (United States)

    Pahlavani, M. R.; Firoozi, B.

    2016-09-01

    γ-ray transitions from excited states of {}16{{N}} and {}16{{O}} isomers that appear in the γ spectrum of the {}616{{{C}}}10\\to {}716{{{N}}}9\\to {}816{{{O}}}8 beta decay chain are investigated. The theoretical approach used in this research starts with a mean-field potential consisting of a phenomenological Woods-Saxon potential including spin-orbit and Coulomb terms (for protons) in order to obtain single-particle energies and wave functions for nucleons in a nucleus. A schematic residual surface delta interaction is then employed on the top of the mean field and is treated within the proton-neutron Tamm-Dancoff approximation (pnTDA) and the proton-neutron random phase approximation. The goal is to use an optimized surface delta interaction interaction, as a residual interaction, to improve the results. We have used artificial intelligence algorithms to establish a good agreement between theoretical and experimental energy spectra. The final results of the ‘optimized’ calculations are reasonable via this approach.

  10. Characterization of polymer-type ionic conductors using nuclear magnetic resonance and thermal analysis. Humidity sensor; Caracterizacao de condutores ionicos de tipo polimerico por ressonancia magnetica nuclear (RMN) e analises termicas. Sensor de umidade

    Energy Technology Data Exchange (ETDEWEB)

    Cavalcante, Maria Goretti

    1992-04-01

    We report a study using Nuclear Magnetic Resonance (NMR), Thermogravimetry Analysis, Differential Scanning Calorimetry and Infrared Spectroscopy in polymeric complexes formed poly(ethylene oxide), (PEO), and lithium salts. These complexes have have shown a large potential for technological applications in batteries, sensors, etc. We developed and characterized humidity sensors and discussed how the humidity affects the conformation of the complexes, the mobility of ionic species, and the polymeric chains. The results indicate that the hydration affects the conformation of polymeric complexes by plasticizing the water, which induces a volumetric expansion in the PEO chain. The processes was completely reversible for the level of hydration studied. NMR was used to distinguish the movement of polymeric chains from the movement of the ionic species. From the analysis of the second moment of resonance lines from the study of the nuclear relaxation we were able to estimate the average distance between the ionic species and the proton in the complexes chains. The behaviour of spin -lattice relaxation of hydrogen and fluorine in the P(EO) - Li B F, as a function of temperature and frequency reflects the nature of the disorder and the complexity of the ionic conduction process in these materials. (author). 91 refs., 69 figs., 2 tabs.

  11. Structural characterization of alkyl-benzene fractions by carbon-13, hydrogen-1, NMR; Caracterizacao estrutural de fracoes de alquilbenzenos por RMN de {sup 13} C e de {sup 1} H

    Energy Technology Data Exchange (ETDEWEB)

    Queiroz, Jorge F. de; San Gil, Rosane A.S. [Universidade Federal, Rio de Janeiro, RJ (Brazil). Inst. de Quimica; Marques, Rosana G.G. [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas

    1994-12-31

    This work presents studies concerning the utilization of carbon-13, hydrogen-1, NMR as chemical analytical technique to evaluate molecular characteristics of alkyl-benzene fractions. The methodology is described, including standards solutions and their preparations, as well as the experimental techniques used. The results are presented and discussed 2 refs., 4 tabs.

  12. {sup 1} H and {sup 13} C NMR studies on the enoling of 5-benzyl barbituric acids; Estudos por H-1 e C-13 RMN da enolizacao de acidos 5-benzil barbituricos

    Energy Technology Data Exchange (ETDEWEB)

    Villar, Jose Daniel Figueroa; Santos, Nedina Lucia dos; Cruz, Elizabete Rangel [Instituto Militar de Engenharia (IME), Rio de Janeiro, RJ (Brazil). Secao de Quimica

    1992-12-31

    This work shows that the derivatives of the 5-benzyl barbituric acids hydroxylated at the ortho position of the aromatic ring only exist in the enol form. and that the alkylation of this hydroxyl gives products which exist mainly in the ketone form of the DMSO 5 refs., 2 figs., 2 tabs.

  13. Carbonaceous species (coke) characterization in zeolites by solid state {sup 13} C NMR; Caracterizacao de especies carbonaceas (coque) em zeolitos por RMN de {sup 13} C estado solido (CP/MAS)

    Energy Technology Data Exchange (ETDEWEB)

    Mota, Claudio J.A.; Menezes, Sonia C [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas

    1992-12-31

    This work applies solid state {sup 13} C NMR for characterization of carbonaceous species (coke) deposited on zeolites after contact with n-hexane at 370 deg C. The results have shown two types of carbon: saturated (sp{sup 3}) and unsaturated (sp{sup 2}) 4 refs., 4 tabs.

  14. Use of 2 D-NMR in the structural study of a Trichilia hirta (Meliaceae) isolated limonoid; Utilizacao de RMN-2D na elucidacao estrutural de um limonoide isolado de Trichilia hirta (meliaceae)

    Energy Technology Data Exchange (ETDEWEB)

    Cortez, Diogenes A.G. [Universidade Estadual de Maringa, PR (Brazil). Dept. de Farmacia-Bioquimica; Vieira, Paulo C; Fernandes, Joao B; Silva, M.Fatima G.F. da; Ferreira, A Gilberto [Sao Carlos Univ., SP (Brazil). Dept. de Quimica

    1992-12-31

    We have recently studied a T. hirta specie and obtained a limonoid which has a structure similar to the hirtine. The obtained limonoid differs from the hirtine by the absence of an epoxy group in C-14 and C-15, and a propionyl oxy group replacement by a iso butyryl oxy bound to a C-12. NMR-2 D has been used for the structural study of the limonoid obtained from the Trichilia hirta (meliaceae) 8 refs., 1 fig., 3 tabs.

  15. NMR study of the epoxidation of liquid hydrolyzed poly-butadiene and meta-chloro-per-benzoic acid; Estudo atraves de RMN da reacao de epoxidacao de polibutadieno liquido hidroxilado (PBLH) e acido m-cloro perbenzoico (AMCPB)

    Energy Technology Data Exchange (ETDEWEB)

    Aguiar, Marcelo [Universidade Federal, Rio de Janeiro, RJ (Brazil). Inst. de Quimica; Akcelrud, L [Universidade Federal, Rio de Janeiro, RJ (Brazil). Escola de Quimica; Menezes, Sonia Cabral de [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas

    1994-12-31

    This work presents a study concerning the selectivity of the different configurations of the double bond present in liquid hydrolyzed poly-butadiene towards the epoxidation reaction with meta-chloro-per-benzoic acid through hydrogen-1, carbon-13 NMR aiming the production of new materials, varying the epoxidation level 12 refs., 7 figs., 4 tabs.

  16. Seed prepare for oil content determination by NMR method in six cotton varieties; Preparo de sementes para determinacao do teor de oleo pelo metodo de RMN em seis variedades de algodoeiro

    Energy Technology Data Exchange (ETDEWEB)

    Gondim-Tomaz, Rose Marry Araujo; Erismann, Norma de Magalhaes; Sabino, Nelson Paulieri; Kondo, Julio Isao; Cia, Edivaldo; Azzini, Anisio [Instituto Agronomico de Campinas, SP (Brazil). Centro de Algodao e Fibrosas Diversas]. E-mail: gondim@cec.iac.br; Soave, Daise [Instituto Agronomico de Campinas, SP (Brazil). Centro de Genetica, Biologia Molecular e Fitoquimica

    1998-07-01

    Three comparative methods (chemical seed-delinting with sulphuric acid solution, flaming and seed with linter) to prepare cotton seeds for oil determination by the Nuclear Magnetic Resonance (NMR) technique were considered. The chemical treatment with sulphuric acid was the best as long the linter interference was eliminated. The seed oil contents were determined by the NMR method in six cotton varieties from the national variety test. The IAPAR (Instituto Agronomico do Parana) 71 PR3 and IAC (Instituto Agronomico de Campinas) 20 varieties presented the highest oil content followed by the CNPA 7H, CS 50, IAC 22 and CNPA Precoce 2. (author)

  17. Carbon-13 solid state NMR studies in the aromatization of residual coals from hydropyrolised cellulose; Estudo por {sup 13} C RMN em estado solido da aromatizacao em carvoes residuais de celulose hidropirolisada

    Energy Technology Data Exchange (ETDEWEB)

    Rocha, J.D.; Luengo, C.A. [Universidade Estadual de Campinas, SP (Brazil). Inst. de Fisica; Snape, C.A. [Dept. Pure and Apllied Chemistry, Glasgow (United Kingdom)

    1997-12-31

    Pure cellulose was pyrolyzed is a fixed-bed reactor under hydrogen pressure (hydropyrolysis). Residual chars were collected and analysed by solid state nmr {sup 13} C (CP-MAS) and elemental. Hydrophyrolysis parameters such as final temperature in the range of 300 to 520 deg C and hydrogen pressure from 5 to 100 atm gave different char samples. CP-MAS spectra were obtained in a BRUKER MSL-100 spectrometer. The results showed that the aromatic and aliphatic fractions had strong dependence with temperature and no influence with pressure. Elemental analysis indicated the carbon content increased more with temperature than the pressure increasing. (author) 6 refs., 2 figs., 2 tabs.

  18. Transducer project and optimization of the ultra low magnetic field NMR tomograph reception system system; Projeto de transdutores e otimizacao do sistema de recepcao do tomografo de RMN de campo magnetico ultra baixo

    Energy Technology Data Exchange (ETDEWEB)

    Vidoto, Edson Luiz Gea

    1996-12-31

    The aim of the present work was to optimize the signal to noise ratio in our NMR imaging system (TORM 005) by improving transducer`s reception quality through better designed coils, balanced tuning circuit for this coils and power decoupling circuits and by reducing interference from the electromagnetic environment. For this purpose, we had to modify the internal electromagnetic shielding and incorporate line filters in the more critical signals paths. Also, new types of coils were developed, improving the signal to noise ratio, and allowing us to make clinical exams with superior quality for several anatomies. Balanced circuits for tuning and matching of the coil were studied and built, allowing a reduction of the coil losses because patient`s load. This produced a more reliable coil tuning after positioning each new patient. Circuits to avoid the receiver input overload and decoupling circuits for the isolation of receiver coils from excitation coil were designed and incorporated to the TORM 005. All these alterations of our imaging system (TORM 005) contributed to a significant improvement in the signal to noise ratio, reliability and reproducibility of the system. This permitted to operate the system routinely for clinical applications, research and development in the area of ultra low magnetic field tomography. (author) 46 refs., 66 figs., 11 tabs.

  19. Evaluation of natural rubber from IAC series clones by solid state {sup 13}C NMR; Avaliacao da borracha natural de clones da serie IAC por {sup 13}C RMN no estado solido

    Energy Technology Data Exchange (ETDEWEB)

    Martins, Maria A.; Moreno, Rogerio M.B.; Goncalves, Paulo S. [Instituto Agronomico de Campinas, SP (Brazil). Centro de Cafe e Plantas Tropicais. Programa Seringueira]. E-mails: paulog@iac.sp.gov.br; mariaalice@cnpdia.embrapa.br; Forato, Lucimara A.; Colnago, Luiz A.; Mattoso, Luiz H.C. [EMBRAPA Instrumentacao Agropecuaria, Sao Carlos, SP (Brazil)]. E-mail: colnago@cnpdia.embrapa.br; forato@cnpdia.embrapa.br; rogerio@cnpdia.embrapa.br; mattoso@cnpdia.embrapa.br; Job, Aldo E. [Universidade Estadual Paulista (UNESP), Presidente Prudente, SP (Brazil). Departamento de Fisica, Quimica e Biologia

    2005-07-01

    Agronomic Institute (IAC) and EMBRAPA Agricultural Instrumentation (EMBRAPA/CNPDIA) have been studied Hevea species in order to increase the production of the natural rubber and to develop new clones more appropriated to Brazil's soil and climate. Structural characterization of natural rubber [Hevea brasiliensis (Willd. ex Adr. de Juss.) Muell. - Arg.] from new clones of the IAC series (IAC 300, 301, 302, 303, 35, 40, and 56) and from RRIM 600 clone has been studied by high-resolution solid-state {sup 13}C NMR and by single pulse technique. The results have shown that the application of solid-state {sup 13}C NMR using the single pulse technique is a powerful tool to study natural rubber. The spectra obtained through this technique confirmed that natural rubber from all clones studied are cis-1,4-polyisoprene (author) form.(author)

  20. Palm oil based polymer materials obtained by ROMP: study by low field NMR; Materiais polimericos obtidos via ROMP a partir de oleo de palma: estudo por RMN de baixo campo

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes, Henrique; Azevedo, Eduardo R. de; Lima-Neto, Benedito S., E-mail: benedito@iqsc.usp.br [Universidade de Sao Paulo (USP), Sao Carlos, SP (Brazil)

    2015-07-01

    Aiming to study and develop new materials synthesized from sustainable sources, several polymers were prepared using in its monomeric composition, different amounts of NPO (Norbornenyl Palm Oil) monomer. This monomer was developed based on a vegetable oil rather produced in northern Brazil, the Palm Oil. Since this oil have a low content of unsaturation, its use in developing new monomer for ROMP (Ring-Opening Metathesis Polymerization) is not exploited. In this regard, polymeric materials were obtained using the NOP and both the reaction process and the resulting products were analyzed by Nuclear Magnetic Resonance in the time domain (TD-NMR) at low magnetic field. (author)

  1. Palm oil based polymer materials obtained by romp: study by low field NMR; Materiais polimericos obtidos via ROMP a partir de oleo de palma: estudo por RMN de baixo campo

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes, Henrique; Lima-Neto, Benedito S., E-mail: benedito@iqsc.usp.br [Universidade de Sao Paulo (USP), Sao Carlos, SP (Brazil). Instituto de Quimica de; Azevedo, Eduardo R. de [Universidade de Sao Paulo (USP), Sao Carlos, SP (Brazil). Instituto de Fisica

    2013-07-01

    Aiming to study and develop new materials synthesized from sustainable sources, several polymers were prepared using in its monomeric composition, different amounts of NPO (Norbornenyl Palm Oil) monomer. This monomer was developed based on a vegetable oil rather produced in northern Brazil, the Palm Oil. Since this oil have a low content of unsaturation, its use in developing new monomer for ROMP (Ring-Opening Metathesis Polymerization) is not exploited. In this regard, polymeric materials were obtained using the NOP and both the reaction process and the resulting products were analyzed by Nuclear Magnetic Resonance in the time domain (TD-NMR) at low magnetic field. (author)

  2. Analysis of oil content and oil quality in oilseeds by low-field NMR; Analise do teor e da qualidade dos lipideos presentes em sementes de oleaginosas por RMN de baixo campo

    Energy Technology Data Exchange (ETDEWEB)

    Constantino, Andre F.; Lacerda Junior, Valdemar; Santos, Reginaldo B. dos; Greco, Sandro J.; Silva, Renzo C.; Neto, Alvaro C.; Barbosa, Lucio L.; Castro, Eustaquio V.R. de [Universidade Federal do Espirito Santo (UFES), Vitoria, ES (Brazil). Departamento de Quimica; Freitas, Jair C.C. [Universidade Federal do Espirito Santo (UFES), Vitoria, ES (Brazil). Departamento de Fisica

    2014-07-01

    To choose among the variety of oleaginous plants for biodiesel production, the oil content of several matrices was determined through different low-field {sup 1}H nuclear magnetic resonance (NMR) experiments with varied pulse sequences, namely single-pulse, spin-echo, CPMG, and CWFP. The experiments that involved the first three sequences showed high correlation with each other and with the solvent extraction method. The quality of the vegetable oils was also evaluated on the basis of the existing correlation between the T{sub 2} values of the oils and their properties, such as viscosity, iodine index, and cetane index. These analyses were performed using HCA and PCA chemometric tools. The results were sufficiently significant to allow separation of the oleaginous matrices according to their quality. Thus, the low-field {sup 1}H NMR technique was confirmed as an important tool to aid in the selection of oleaginous matrices for biodiesel production. (author)

  3. Determination of unreacted monomers in restorative dental resins based on dimethacrylate by NMR hydrogen; Determinacao do teor de monomero residual em resinas restauradoras a base de dimetacrilatos por RMN de hidrogenio

    Energy Technology Data Exchange (ETDEWEB)

    Correa, Ivo Carlos; Miranda Junior, Walter G. [Sao Paulo Univ., SP (Brazil). Faculdade de Odontologia. Dept. de Materiais Dentarios]. E-mail: ivo@fo.usp.br; Tavares, Maria Ines B. [Universidade Federal, Rio de Janeiro, RJ (Brazil). Inst. de Macromoleculas]. E-mail: mibt@ima.ufrj.br

    2001-07-01

    The presence of unreacted monomers after photo-activation of dental composites causes mechanical and biological properties to decrease and could be detected by NMR analysis. The aim of this study was to evaluate the percentage of leachable monomers of light-cured composites under the effect of variations of exposure time of photo activation by nuclear magnetic resonance of hydrogen in solution (NMR{sup 1}H). The composite resins tested Z250 and Fill Magic obtained similar values of unreacted monomers (%) at photo curing time suggested by the manufacturer and values were also lower than Durafill and A110 concentrations. From the NMR results, one day extractable time was efficient to quantify the amount of residual monomers in the dental composites tested, unless for Durafill composite. (author)

  4. Comparative study of the formation of fenchenes and of their N.M.R. spectra; Etude comparative de la formation des fenchenes et de leurs spectres de R.M.N

    Energy Technology Data Exchange (ETDEWEB)

    Coulombeau, A. [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1970-01-01

    The dehydration of {alpha}-fenchyl alcohol and {alpha}-iso-fenchyl alcohol is studied in detail: two new techniques (chromatography on silica with silver nitrate, and nuclear magnetic resonance) permit to analyse the formation of various fenchenes and to achieve the synthesis of {alpha}- and {beta}-fenchenes. (author) [French] On etudie en detail la deshydratation de l'{alpha}-fenchol et de l'{alpha}-isofenchol: grace a l'utilisation de deux techniques nouvelles (chromatographie sur silice impregnee de nitrate d'argent et resonance magnetique nucleaire), on a pu analyser la formation des divers fenchenes. On met au point la preparation de l'{alpha}- et du {beta}-fenchenes. (auteur)

  5. Caracterização e Predição de Propriedades Físicas e Químicas de Destilados de Petróleo por Ressonância Magnética Nuclear (RMN)

    OpenAIRE

    MONTES, L. F.

    2016-01-01

    Separar os componentes individuais do petróleo é praticamente impossível, assim a maneira mais conveniente de se analisar destilados de petróleo é por meio da determinação de suas composições químicas e de suas propriedades visto que muitas delas estão relacionadas com a constituição química. Neste trabalho, quatro amostras de petróleo com °API entre 34,9 e 17,9 foram submetidos à destilação PEV (ponto de ebulição verdadeiro) seguindo a norma ASTM D 2892, o que permitiu a obtenção de 42 desti...

  6. Characterization of PHB, zinc oxide and organophilic clay nanocomposites with low field; Caracterizacao de nanocompositos de PHB com oxido de zinco e argila organofilica por RMN de baixo campo

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Mariana B.R.; Tavares, Maria Ines B.; Junior, Alberto W.M.; Neto, Roberto P.C. [Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, RJ (Brazil)

    2015-07-01

    Nanoparticles of zinc oxide and organophilic clay (Viscogel B8) were added to PHB matrix in some different proportions. The nanocomposites containing both nanoparticles were obtained from solution casting method using chloroform as solvent. The films obtained were analyzed with X-ray diffraction and low field nuclear magnetic resonance to obtain answers about the interactions, dispersion and homogeneity of nanoparticles in the polymer matrix, just like the synergistic effects and the influence of them over some characteristics of the polymer. The synergistic effect achieved from the addition of both nanoparticles was also observed through hydrogen nuclear relaxation time values. (author)

  7. Proceedings of the 11. Brazilian meeting on magnetic resonance. Short courses on NMR. Abstracts and program; Anais da 11. Jornada brasileira de ressonancia magnetica. Mini-cursos em RMN. Resumos e programa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-07-01

    This annual meeting, held in Brazil from August 4 - 6, 2010 comprised : mini-courses about the use of nuclear magnetic resonance for various analytical purposes; major conferences and short conferences with invited speakers from Brazil and other countries; results from research works, most being carried out by scientific groups from various Brazilian R and D institutions, presented as oral communications and as congress panels/posters. Prizes to remarkable works of undergrad and post-grad students have been awarded, and a General Assembly meeting of AUREMN, the Brazilian Association of Nuclear Magnetic Resonance Users, also took place at the end of the event. Main topics of the research works presented at this meeting were thus distributed: 52% in chemical sciences (mainly organic chemistry, both experimental and theoretical works), 28% in applied life sciences (agricultural and food sciences, biological sciences and medicine), 18% in materials science (including nanocomposites, petroleum and alternative fuels), and 4% regarding development of equipment accessories for improving NMR techniques and environmental science-related themes

  8. Comparative study of the formation of fenchenes and of their N.M.R. spectra; Etude comparative de la formation des fenchenes et de leurs spectres de R.M.N

    Energy Technology Data Exchange (ETDEWEB)

    Coulombeau, A [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires

    1970-01-01

    The dehydration of {alpha}-fenchyl alcohol and {alpha}-iso-fenchyl alcohol is studied in detail: two new techniques (chromatography on silica with silver nitrate, and nuclear magnetic resonance) permit to analyse the formation of various fenchenes and to achieve the synthesis of {alpha}- and {beta}-fenchenes. (author) [French] On etudie en detail la deshydratation de l'{alpha}-fenchol et de l'{alpha}-isofenchol: grace a l'utilisation de deux techniques nouvelles (chromatographie sur silice impregnee de nitrate d'argent et resonance magnetique nucleaire), on a pu analyser la formation des divers fenchenes. On met au point la preparation de l'{alpha}- et du {beta}-fenchenes. (auteur)

  9. Phosphorus in chronosequence of burnt sugar cane in Brazilian cerrado: humic acid analysis by {sup 31}P NMR; Fosforo em cronossequencia de cana-de-acucar queimada no cerrado goiano: analise de acidos humicos por RMN de {sup 31}P

    Energy Technology Data Exchange (ETDEWEB)

    Rossi, Celeste Q.; Pereira, Marcos G.; Garcia, Andreas C., E-mail: mgervasiopereira@gmail.com [Universidade Federal Rural do Rio de Janeiro (UFRRJ), Seropedica, RJ (Brazil). Dept. de Solos; Perin, Adriano; Gazolla, Paulo R. [Instituto Federal de Educacao, Ciencia e Tecnologia Goiano, Rio Verde, GO (Brazil); Gonzalez, Antonio P. [Universidade de Coruna, ES (Spain). Faculdad de Ciencias

    2013-10-01

    The aim of this study was to identify, with the use of {sup 31}P NMR spectroscopy, organic P species in humic acids (HA) in samples from Oxisol cultivated in chronosequence with sugar cane, pasture and Cerrado. The main forms of P-type found were orthophosphate, monoester-P (phosphate sugars) and P-diester (orthophosphate). The {sup 31}P NMR technique proved capable of identifying changes in the areas studied as a function of sugar cane burning time. In areas with 1 and 5 years of burnt cane, a decrease in recalcitrant organic P in humic acids indicated the need for use of P-humic substances for plant nutrition (author)

  10. Spectroscopic data of Labdane Diterpenes: a theoretical analysis via NMR and DFT; Dados espectroscópicos de diterpenos Labdânicos: uma análise teórica via RMN e DFT

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Fabrine S. de; Silva, Silvana de O.; Alves, Cláudio N.; Guilhon, Giselle M.S.P. [Universidade Federal do Pará (UFPA), Belém, PA (Brazil). Instituto de Ciências Exatas e Naturais; Faria, Lênio J.G. de; Brasil, Davi do S.B., E-mail: davibb@ufpa.br [Universidade Federal do Pará, Belém, PA (Brazil). Instituto de Tecnologia; Muller, Adolfo H. [Centro Universitário do Estado do Pará, Belém, PA (Brazil)

    2015-06-15

    Labdane diterpenes exhibit important bioactivities such as cardiovascular effects in rats as well as effects in the treatment of autoimmune diseases and Alzheimer syndrome. Recently, the labdane diterpenes ent-13-epi-manoil oxide, ribenone and ribenol were isolated from Croton palanostigma. The computational method DFT/B3LYP/cc-pVDZ was used to optimize the structures of these diterpenes and to calculate infrared data. Chemical shifts (δ{sub H} and δ{sub C}) of the minimum energy structures (local minimum) were calculated and compared with the experimental data. Comparison of the NMR data by simple linear regression (SLR) showed satisfactory statistical results with a correlation coefficient (R{sup 2} ) and predictive ability (Q{sup 2}) of over 98%. The predicted NMR data were used to confirm the δ{sub H} values that have not been published. (author)

  11. Validation of quantitative {sup 1}H NMR method for the analysis of pharmaceutical formulations; Validacao de metodo quantitativo por RMN de {sup 1}H para analises de formulacoes farmaceuticas

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Maiara da S. [Universidade de Sao Paulo (USP), Sao Carlos, SP (Brazil). Instituto de Quimica; Colnago, Luiz Alberto, E-mail: luiz.colnago@embrapa.br [Embrapa Instrumentacao, Sao Carlos, SP (Brazil)

    2013-09-01

    The need for effective and reliable quality control in products from pharmaceutical industries renders the analyses of their active ingredients and constituents of great importance. This study presents the theoretical basis of Superscript-One H NMR for quantitative analyses and an example of the method validation according to Resolution RE N. 899 by the Brazilian National Health Surveillance Agency (ANVISA), in which the compound paracetamol was the active ingredient. All evaluated parameters (selectivity, linearity, accuracy, repeatability and robustness) showed satisfactory results. It was concluded that a single NMR measurement provides structural and quantitative information of active components and excipients in the sample. (author)

  12. Aplicación de Resonancia Magnética Nuclear para la caracterización de fracciones pesadas del petróleo en el proceso de desasfaltado por extracción (DEMEX)

    OpenAIRE

    Avella Moreno, Eliseo

    2011-01-01

    En la literatura, se encontró una gran variedad de criterios para la preparación de muestras y para la adquisición y el procesamiento de los espectros de resonancia magnética nuclear de hidrógeno-1 (RMN 1H) o de carbono-13 (RMN 13C) de petróleos, carbones y sus fracciones. Se definieron 33 nuevos intervalos de integración en los espectros de RMN 1H y 47, en los espectros de RMN 13C. Se unificaron sus límites inferior y superior mediante un tratamiento estadístico realizado con ...

  13. A theoretical quantum study on the distribution of electrophilic and nucleophilic active sites on Cu(100) surfaces modeled as finite clusters; Un estudio teorico cuantico sobre la distribucion de sitios activos electrofilicos y nucleofilicos sobre superficies de Cu(100) modeladas como cumulos finitos

    Energy Technology Data Exchange (ETDEWEB)

    Rios R, C.H.; Romero R, M. [Universidad Autonoma Metropolitana-Azcapotzalco, Departamento de Materiales, Av. San Pablo 180, Col. Reynosa Tamaulipas, 02200 Mexico D.F. (Mexico); Ponce R, A.; Mendoza H, L.H. [Universidad Autonoma del Estado de Hidalgo, Centro de Investigaciones Quimicas, Carretera Pachuca-Tulancingo km. 4.5, 42181 Pachuca, Hidalgo (Mexico)]. e-mail: clara_hrr@yahoo.es

    2008-07-01

    In this work, it is shown a theoretical quantum study of the active sites distribution on a monocrystalline surface of Cu(100). The copper surface was modeled as finite clusters of 14, 23, 38 and 53 atoms. We performed Hartree-Fock and Density Functional Theory (B3LYP) ab initio calculations employing the pseudopotentials of Hay and Wadt (LANLlMB y LANL2DZ). From calculations, we found a work function value of 4.1 eV. The mapping of the HOMO and LUMO in the frozen core approximation, allowed us finding the electrophilic and nucleophilic active sites distribution, respectively. The results indicated that electrophilic sites on the Cu(100) surface were located on hollow position and its numerical density was 8.6 x 10{sup 16} sites cm{sup -2}. From the nucleophilic local softness study, it was found that the nucleophilic sites were formed by a group of atoms and it had a numerical density of 2.4x 10{sup 16} sitescm{sup -2} . Last results indicated that adsorptions with 2 x 2 and 3 x 3 distributions can be favored onto a Cu(100) surface for the electrophilic and nucleophilic cases, respectively. (Author)

  14. Theory of Pulsed Neutron Experiments in Highly Heterogeneous Multiplying Media; Theorie des Experiences au Moyen des Neutrons Pulses, dans les Milieux Multiplicateurs Tres Heterogenes; O teorii ehksperimentov s impul'snymi neitronami v geterogennykh razmnozhayushchikh sredakh; Aspectos Teoricos de los Experimentos con Neutrones Pulsados en Medios Multiplicadores Muy Heterogeneos

    Energy Technology Data Exchange (ETDEWEB)

    Corno, S. E. [Instituto di Fisica ' ' A. Volta' ' (Italy); Unversity of Pavia, Pavia (Italy); SNAM, Milan [Italy

    1965-10-15

    In this work we investigate the time and space dependence of the neutron flux within a highly heterogeneous assembly, in which pulsed or sinusoidally modulated neutrons are injected. We consider, for the sake of simplicity, a device consisting of a cylindrical block of heavy moderator, along the axis of which a line-shaped region of fissionable material is located. The driving neutron source is assumed to be located on one of the end faces of the cylinder. The extent of the fissionable region allows us to deal with it as with an absorbing and multiplying singularity of the neutron field. As our attention is mostly concentrated on space and time variation of the neutron flux, rather crude approximations are assumed as far as the energy dependence of the neutron population is concerned. Within the limits of the age-diffusion theory, the response of the device to any neutron excitation may be found in closed form. For a sinusoidally modulated source of given frequency, it may easily be shown that, if the axial singularity were a purely absorbing one, the neutron waves being propagated along the device would possess a phase shift; a wavelength and an attenuation constant depending on the absorbing properties of the singularity. This picture becomes more and more complicated when neutron multiplication occurs. For this general case the solution derived in our paper obviously turns out to be dependent on both absorption and multiplication properties of the singularity. This circumstance suggests, among others, the idea of using a device of the type described above for testing fuel elements of heterogeneous reactors. (author) [French] L'auteur etudie les variations du flux de neutrons en fonction du temps et du lieu dans un assemblage tres heterogene ou l'on injecte des neutrons puises ou modules sinusoidalement. Il envisage, pour des raisons de simplicite, un dispositif constitue par un ralentisseur lourd en forme de bloc cylindrique sur l'axe duquel est placee une zone de matiere fissile ayant une forme lineaire. La source de neutrons puises est supposee etre placee sur l'unfe des bases du cylindre. L'etendue de la zone de matiere fissile permet a l'auteur de la traiter comme s'il s'agissait d'une zone singuliere d'absorption et de multiplication dans le champ de neutrons. Comme il concentre son attention principalement sur les variations du flux de neutrons en fonction du lieu et du temps, il adopte des approximations assez grossieres pour ce qui est des variations de la population de neutrons en fonction de l'energie. Dans les limites de la theorie diffusion-age, il se peut que la reponse du dispositif a une excitation neutronique quelconque soit obtenue sous forme fermee. Avec une source modulee sinusoidalement de frequence donnee, on peut aisement montrer que, si la zone axiale singuliere est purement absorbante, le dephasage, la longueur d'onde et la constante d'attenuation des ondes neutroniques propagees le long du cylindre dependent des proprietes absoibantes de cette zone. Cet etat de choses se complique de plus en plus lorsqu'une multiplication des neutrons se produit. Dans ce cas general, la solution a laquelle l'auteur aboutit se revele evidemment etre dependante des proprietes d'absorption et de multiplication de la zone singuliere, ce qui peut donner, entre autres, l'idee d'utiliser un dispositif du modele decrit ci-dessus pour soumettre a des essais les elements de combustible des reacteurs heterogenes. (author) [Spanish] El autor ha investigado la variacion del flujo neutronico en funcion del tiempo y del espacio en un conjunto muy heterogeneo en el que se inyectan neutrones pulsados o de modulacion sinusoidal. Para mayor sencillez se opera con una instalacion formada por un bloque cilindrico de moderador pesado, en cuyo eje se encuentra una region lineal de material fisionable. La fuente neutronica se supone situada en una de las caras del cilindro. Gracias a sus dimensiones, la region fisionable puede considerarse como punto singular absorbente y multiplicador del campo neutronico. Como el auto: estudia sobre todo la variacion espacial y temporal del flujo neutronico, utiliza valores relativamente poco precisos por lo que respecta a la variacion de la poblacion neutronica en funcion de la energia. Dentro de los limites de validez de la teorfe de la edad de difusion, la instalacion responde en forma analitica a una excitacion provocada por los neutrones. Cuando se trata de una fuente de modulacion sinusoidal de frecuencia determinada, puede demostrarse facilmente que si el punto singular axial fuese puramente absorbente, las ondas neutronicas que se propagaran a lo largo de la instalacion poseerfan una fase, una longitud de onda y una constante de atenuacion dependiente de las propiedades absorbentes del punto singular. Esto se complica en caso de multiplicacion neutronica. Para este caso general, la solucion presentada en la memoria depende, desde luego, de las propiedades absorbentes y multiplicadoras del punto singular. Esta circunstancia, entre otras, ha inducido a utilizar una instalacion como la que se acaba de describir para ensayar los elementos combustibles de los reactores heterogeneos. (author) [Russian] Issledovalis' vremennaja i prostranstvennaja zavisimosti nejtronnogo potoka na vysoko geterogennoj sborke, kuda inzhektirujutsja impul'snye ili sinusoidno modulirovannye nejtrony. Dlja prostoty rassmatrivaetsja ustrojstvo, sostojashhee iz cilindricheskogo bloka zamedlitelja tjazhelyh nejtronov, po osi kotorogo nahoditsja vytjanutaja oblast' rasshhepljajushhegosja materiala. Predpolagaetsja, chto usiljajushhij istochnik nejtronov razmeshhaetsja na odnoj iz storon cilindra. Razmer rasshhepljajushhejsja oblasti pozvoljaet rassmatrivat' ee kak absorbirujushhuju i razmnozhajushhuju singuljarnuju sostavljajushhuju nejtronnogo polja. Poskol'ku vnimanie koncentriruvalos' glavnym obrazom na prostranstvennom i vremennom izmenenii nejtronnogo potoka, to sdelany dovol'no grubye priblizhenija otnositel'no jenergeticheskoj zavisimosti opredelennoj populjacii nejtronov. V ramkah vozrastno-diffuzionnoj teorii reakcija pribora na ljuboe vozbuzhdenie nejtronov mozhet imet' zakrytuju formu. Dlja sinusoidal'no modulirovannogo istochnika dannoj chastoty mozhno legko pokazat', chto esli osial'naja singuljarnaja sostavljajushhaja javljaetsja chisto absorbirujushhej, to nejtronnye volny, prohodjashhie cherez pribor, budut obladat' fazoj, dlinoj volny i postojannoj oslablenija, kotorye zavisjat ot absorbirujushhih svojstv singuljarnoj sostavljajushhej. Jeta kartina vse bolee uslozhnjaetsja, kogda proishodit razmnozhenie nejtronov. Dlja dannogo obshhego sluchaja reshenie, kotoroe privoditsja v nashem doklade, ochevidno, javljaetsja zavisimym kak ot absorbirujushhih, tak i ot razmnozhajushhih svojstv singuljarnoj sostavljajushhej. Jeto obstojatel'stvo predpolagaet, pomimo prochego, vozmozhnost' ispol'zovanija pribora vysheukazannogo tipa dlja ispytanija toplivnyh jelementov geterogennyh reaktorov. (author)

  15. Community and corporate social responsibility in sector of oil, gas and mining: short approach considering practice and theory aspects; Responsabilidade social corporativa e comunitaria nos setores de petroleo, gas e mineracao no Brasil: breve reflexao sobre a evolucao teorico-pratica

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Edison D.R.; Danciguer, Lucilene; Macarini, Samuel; Pereira, Maira de S.; Lopes, Luciano E. [GAIA - Grupo de Aplicacao Interdisciplinar a Aprendizagem (GAIA), Campinas, SP (Brazil)

    2008-07-01

    The evolution of the debate about corporate and community social responsibility has been happening, in Brazil, with the implementation of programs for the quality of services and products; the improvement of the performance of activities related to environmental conservation, the increase in security and health of workers and communities; the intensification of communication and relationship with workers, communities, and other stakeholders. This work discusses the evolution of this culture in petroleum, gas and mining sectors in Brazil during the last 20 years. It was based on the experience of the Interdisciplinary Learning Application Group (GAIA) with both, the internal public (including all employees) and the communities directly or indirectly affected by old or new activities. The cases analyzed are good examples of this cultural change, which prioritizes the development of humanist and progressive approaches to corporate education. The results GAIA obtained actuating during the last 15 years in partnership with corporations from several sectors evidenced that the incorporation of social responsibility objectives and targets as part of corporation's business brought benefits for all stakeholders. To the managers it brought an improvement in administration considering the stakeholders. To the workers it helped developing their self-esteem and citizenship. To the communities it enhanced their capacity to dialogue and created sustainable initiatives that improve their quality of life. (author)

  16. Theorical and experimental study of the induced forces by the mixed, divergent, convergent and straight labyrinth of seal systems on the steam turbines, gas turbines and compressor rotors; Estudio teorico-experimental de las fuerzas inducidas por los sistemas de sellos de laberinto rectos, convergentes, divergentes y mixtos sobre los rotores de turbinas de vapor, turbinas de gas y compresores

    Energy Technology Data Exchange (ETDEWEB)

    Salazar San Andres, Octavio Ramon

    1991-12-31

    A theoretical and experimental research is conducted in order to determine the labyrinth seal forces, as well as the stiffness and damping coefficients for straight, convergent, divergent, and combined shapes on turbine and compressor rotors. The mathematical model is deduced on the basis of the single volume method and its solution is obtained by the perturbation procedure. The validation is achieved with published results. Experimental work carried out on a test bench is described in the text. This involved labyrinth seals with straight, convergent, and divergent profiles, as the published information relating to mixed type is sufficient to perform the evaluation. The conclusions demonstrate that the model is able to predict and determine the performance of labyrinth seals based on forces and rotordynamic coefficients for static and dynamic motions. Finally, tests on real steam turbines of 300 MW are recommended. In this case the high pressures and use of wheels with strips on the periphery and supported by the upper part of blades, increase the susceptibility of self excited subsynchronous vibrations. [Espanol] Se presenta una investigacion teorica-experimental relacionada con la obtencion y validacion de un modelo matematico capaz de predecir las fuerzas y los coeficientes de rigidez y amortiguamiento de los sellos de laberinto de tipo recto, convergente, divergente y mixto que se emplean en turbinas y compresores tanto terrestres como aereos. El modelo matematico propuesto se deduce a partir del metodo de un solo volumen y su solucion se obtiene a traves de metodos perturbatorios. La validacion del mismo se consigue al comparar con resultados experimentales publicados en revistas especializadas y con los datos medidos en un banco de pruebas cuya descripcion se incluye en el trabajo, cualculado para sellos rectos, convergentes y divergentes, ya que la informacion publicada respecto al tipo mixto o combinado es suficiente. Las conclusiones de la investigacion demuestran que el modelo es capaz de dar una vision cualitativa y cuantitativa de las fuerzas y los coeficientes de rigidez y amortiguamiento de los sellos de laberinto con las geometrias antes mencionadas, tanto para el rotor estatico como en operacion. Por otra parte se recomienda llevar a cabo mas experimentacion con equipo instalado en plantas termoelectricas y en especial en turbinas de vapor con capacidades iguales o superiores a los 300 MW, donde las altas presiones y los sellos localizados en la parte superior de los alabes, vuelven mas susceptibles a las maquinas para autoinducir vibraciones subsincronas.

  17. Estudio Te\\'orico del espectro de emisi\\'on para un sistema microcavidad-punto cu\\'antico en una aproximaci\\'on de campo medio (Theoretical study of emission spectrum for a quantum dot-microcavity system in a mean field approximation)

    OpenAIRE

    Rojas-Arias, Juan S.; Rodriguez, B.; Vinck-Posada, Herbert

    2015-01-01

    En este trabajo, se obtiene una expresi\\'on num\\'erica para calcular el espectro de emisi\\'on de un sistema microcavidad-punto cu\\'antico usando una teor\\'ia de campo medio en el formalismo de la matriz densidad. El sistema modelado es un micropilar semiconductor que contiene un \\'unico punto cu\\'antico en el interior de la microcavidad, este sistema presenta p\\'erdida de fotones a trav\\'es de los espejos de la cavidad y bombeo de excitones al punto cu\\'antico. Obtenemos una ecuaci\\'on maestr...

  18. Efficacy and Safety of Atrial Fibrillation Ablation Using Remote Magnetic Navigation

    DEFF Research Database (Denmark)

    Jin, Q I; Pehrson, Steen; Jacobsen, Peter Karl

    2016-01-01

    .0 minutes, PerAF, P = 0.17). The overall complication rate was 0.6%. One PAF patient experienced cardiac tamponade. AF repeat ablations by RMN significantly reduced the procedural and ablation times when compared with their first ablation times. CONCLUSIONS: AF ablation guided by RMN is safe as evidenced...

  19. Radiation monitoring network of the Czech Republic

    International Nuclear Information System (INIS)

    Drabova, D.; Prouza, Z.; Malatova, I.; Bucina, I.

    1996-01-01

    Radiation Monitoring Network of the Czech Republic (RMN) was established after the Chernobyl accident. It consists of technical centers, laboratories and monitoring groups of State Office for Nuclear Safety, National Radiation Protection Institute, nuclear power plants, hydrometeorological service, army and Civil Defense, research institutes and other institutions. The structure of RMN, its basic components and responsible institutions are described. (author)

  20. Impact of catheter ablation with remote magnetic navigation on procedural outcomes in patients with persistent and long-standing persistent atrial fibrillation

    DEFF Research Database (Denmark)

    Jin, Qi; Pehrson, Steen; Jacobsen, Peter Karl

    2015-01-01

    with RMN. METHODS: A total of 313 patients (275 male, age 59 ± 9.5 years) with PsAF (187/313) or L-PsAF (126/313) undergoing ablation using RMN were included. Patients' disease history, pulmonary venous anatomy, left atrial (LA) volume, procedure time, mapping plus ablation time, radiofrequency (RF...

  1. PERCHÉ LEGGERE MICHELSTAEDTER?

    African Journals Online (AJOL)

    User

    It does so through an investigation concerning ... sinteticamente presentato a livello teorico le nozioni di “lettore implicito”, “lettore modello” e “lettore ... principalmente per la Persuasione, ha vissuto una stagione di rinascita. ...... Cerruti, Marco.

  2. Energy efficiency study of the domestic refrigerators inside of a controlled environment laboratory; Estudio de la eficiencia energetica de refrigeradores domesticos dentro de un laboratorio de ambiente controlado

    Energy Technology Data Exchange (ETDEWEB)

    Arroyo Cabanas, Fernando Gabriel

    2004-04-15

    The evaluation of the energy saving potential is looked for that exists in the park of domestic refrigerators of the country when replacing them by refrigerators of higher power efficiency, through a comparative analysis of the results obtained in experimental tests applied to domestic refrigerators, in agreement with Official Norm NOM 015-2002 and with the theoretical values reported by the manufacturers. Initially the park of domestic refrigerators used in Mexico (brand names, efficiency and electrical consumption) was studied with the objective of evaluating the electric energy consumption in the refrigerators at national level. Once with the consumption determined, a governmental program for the accelerated substitution of the park of domestic refrigerators of greater antiquity is proposed, for models of better power efficiency. Next, the characterization of the Laboratorio de Ambiente Controlado is made (preliminary tests of thermal stability and heat losses) to obtain the thermal conditions marked by Norm NOM-015-2002. Also relevant points for the experimental energy analysis are established in domestic refrigerators according to norm NOM-015-2002. Finally, a test protocol for domestic refrigerators applied in the LAC with base in this norm will be proposed and a validation of this by means of the necessary experimental tests and the required calculations will be carried out. Finally the obtained results of the tests of power efficiency applied to different models from domestic refrigerators, as well as conclusions are presented. [Spanish] Se busca evaluar el potencial de ahorro de energia que existe en el parque de refrigeradores domesticos del pais al sustituirlos por refrigeradores de mayor eficiencia energetica, a traves de un analisis comparativo de los resultados obtenidos de pruebas experimentales aplicadas a refrigeradores domesticos, de acuerdo con la Norma Oficial NOM.015-2002 y con los valores teoricos reportados por los fabricantes. Primeramente

  3. Current shaper: a new topology; Conformador de corriente: una nueva topologia

    Energy Technology Data Exchange (ETDEWEB)

    Lopez Salcedo, Josue

    2003-03-15

    el puente rectificador -en lugar de tener una conexion en serie con el puente-, denominado Conformadores de Corriente Tipo Paralelo. Se describe la teoria de la operacion y el analisis matematico de las formas de onda de la topologia de este nuevo conformador de corriente junto con el analisis teorico que determina la eficacia del sistema y las consideraciones en el diseno de la topologia. En lo referente al diseno de la etapa de potencia se presenta el filtro EMI empleado, el calculo del capacitor voluminoso, el convertidor flyback y del transformador, asi como el tipo de compensador utilizado en la parte de la etapa de control. Para corroborar el analisis de la forma de onda de la corriente de entrada se implemento un prototipo a una potencia de salida de 50W, cuyos resultados experimentales se muestran a la par del contenido armonico de la corriente de entrada necesaria para cumplir con la norma de calidad y los resultados a la respuesta dinamica del convertidor.

  4. Characterization of the billow applied to Tuxpan, Veracruz; Caracterizacion del oleaje aplicada a Tuxpan, Veracruz

    Energy Technology Data Exchange (ETDEWEB)

    Rosales Sierra, Victor

    1999-07-01

    In this work, the criteria for the wave temporal and spectral statistical analysis were reviewed. These analysis are applied to the site Tuxpan, Veracruz, in the Mexican Gulf coast. In the temporal statistic analysis, the high (Rayleigh, Tayfun and Carter) and period (Bretchneider, Cavanie and Longuet-Higgins) theoretic probability distributions are compared with field data from Tuxpan. In the other hand, in the frequency domain analysis, the theoretic spectrums (Bretchneider-Mitsuyasu, Jonswap-Hasselmann, Pierson-Moscowitz, Neumann, ITTC, ISSC, TMA and Ochi-Hubble) are compared with the one obtained from Tuxpan measurements, then changes are made to some spectrums in order to better couple to field data. Finally, some recommendations are made to improve the wave data acquisition and analysis methods. From the study results, it's important to mention that the Tayfun high probability distribution and the Cavanie period probability distribution better fit Tuxpan field data. In the spectral analysis, the Bretchneider spectrum, modified by Mitsuyasu, better coupled to the spectrum obtained from Tuxpan field data. In the temporal statistical analysis, correct the mean level using the parabolic approximation, in order to eliminate the tidal and long period wave effects, it is recommended. For the registered individual wave calculus the zero up cross method was used. [Spanish] En este trabajo se revisan los criterios para el analisis estadisticos temporal y espectral del oleaje, mismos que son aplicados para la caracterizacion del oleaje en Tuxpan, Veracruz. En cuanto al analisis estadistico temporal, se comparan las distribuciones teoricas de probabilidad de altura de Rayleigh, Tayfun y Carter; y las de periodo de Bretchneider, Cavanie y Longuet-Higgins contra las resultantes de las mediciones en campo. Por otro lado y concerniente al analisis en el dominio de la frecuencia, se comparan los espectros teoricos de Bretchneider- Mitsuyasu, Jonswap-Hasselmann, Pierson

  5. Construction of a computational exposure model for dosimetric calculations using the EGS4 Monte Carlo code and voxel phantoms; Construcao de um modelo computacional de exposicao para calculos dosimetricos utilizando o codigo Monte Carlo EGS4 e fantomas de voxels

    Energy Technology Data Exchange (ETDEWEB)

    Vieira, Jose Wilson

    2004-07-15

    The MAX phantom has been developed from existing segmented images of a male adult body, in order to achieve a representation as close as possible to the anatomical properties of the reference adult male specified by the ICRP. In computational dosimetry, MAX can simulate the geometry of a human body under exposure to ionizing radiations, internal or external, with the objective of calculating the equivalent dose in organs and tissues for occupational, medical or environmental purposes of the radiation protection. This study presents a methodology used to build a new computational exposure model MAX/EGS4: the geometric construction of the phantom; the development of the algorithm of one-directional, divergent, and isotropic radioactive sources; new methods for calculating the equivalent dose in the red bone marrow and in the skin, and the coupling of the MAX phantom with the EGS4 Monte Carlo code. Finally, some results of radiation protection, in the form of conversion coefficients between equivalent dose (or effective dose) and free air-kerma for external photon irradiation are presented and discussed. Comparing the results presented with similar data from other human phantoms it is possible to conclude that the coupling MAX/EGS4 is satisfactory for the calculation of the equivalent dose in radiation protection. (author)

  6. Characterization program, management and isotopic inventory calculation, radiological and fuel thermal irradiated in nuclear power Cofrentes; Programa Caracterizacion Gestion y calculo del inventario isotopico, radiologico y termico del combustible irradiado en la Central Nuclear de Cofrentes

    Energy Technology Data Exchange (ETDEWEB)

    Albendea, M.; Diego, J. L. de; Urrea, M.

    2012-07-01

    Characterization is a very detailed and user-friendly program takes into account the history of irradiation individualized and real all the fuel, even taking into account the interim periods are periods of discharge and recharge cycles and which have not been used.

  7. Application of Laplace transform for determination of albedo type boundary conditions for neutronic calculations; Aplicacao da transformada de Laplace para determinacao de condicoes de contorno tipo albedo para calculos neutronicos

    Energy Technology Data Exchange (ETDEWEB)

    Petersen, Claudio Zen

    2008-07-01

    In this dissertation we use the Laplace transform to derive expressions for nonstandard albedo boundary conditions for one and two non-multiplying regions at the ends of one dimensional domains. In practice, the fuel regions of reactor cores are surrounded by reflector regions that reduce neutron leakage. In order to exclude the reflector regions from the calculations, we introduce a reflection coefficient or albedo. We use the present albedo boundary conditions to solve numerically slab-geometry monoenergetic and multigroup diffusion equations using the conventional finite difference method. Numerical results are generated for fixed source and eigenvalue diffusion problems in slab geometry(author)

  8. Calculation of dose due to exposure internal in the services of nuclear medicine of Peru; Calculo de dosis debida a la exposicion interna en los servicios de medicina nuclear del Peru

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, S.; Zapata, L.; Cardenas, A.; Velasquez, M.

    2013-07-01

    The objective of this work is to improve the radiation protection of workers occupationally exposed to open source of nuclear medicine services and train those responsible for radiation protection of such installations to carry a comprehensive record of doses. (Author)

  9. Neutron spectra calculation and doses in a subcritical nuclear reactor based on thorium; Calculo de espectros de neutrones y dosis en un reactor nuclear subcritico a base de Torio

    Energy Technology Data Exchange (ETDEWEB)

    Medina C, D.; Hernandez A, P. L.; Hernandez D, V. M.; Vega C, H. R. [Universidad Autonoma de Zacatecas, Unidad Academica de Estudios Nucleares, Cipres No. 10, Fracc. La Penuela, 98068 Zacatecas, Zac. (Mexico); Sajo B, L., E-mail: dmedina_c@hotmail.com [Universidad Simon Bolivar, Laboratorio de Fisica Nuclear, Apdo. Postal 89000, Caracas 1080A (Venezuela, Bolivarian Republic of)

    2015-10-15

    This paper describes a heterogeneous subcritical nuclear reactor with molten salts based on thorium, with graphite moderator and a source of {sup 252}Cf, whose dose levels in the periphery allows its use in teaching and research activities. The design was done by the Monte Carlo method with the code MCNP5 where the geometry, dimensions and fuel was varied in order to obtain the best design. The result is a cubic reactor of 110 cm side with graphite moderator and reflector. In the central part they have 9 ducts that were placed in the direction of axis Y. The central duct contains the source of {sup 252}Cf, of 8 other ducts, are two irradiation ducts and the other six contain a molten salt ({sup 7}LiF - BeF{sub 2} - ThF{sub 4} - UF{sub 4}) as fuel. For design the k{sub eff}, neutron spectra and ambient dose equivalent was calculated. In the first instance the above calculation for a virgin fuel was called case 1, then a percentage of {sup 233}U was used and the percentage of Th was decreased and was called case 2. This with the purpose to compare two different fuels working inside the reactor. In the case 1 a value was obtained for the k{sub eff} of 0.13 and case 2 of 0.28, maintaining the subcriticality in both cases. In the dose levels the higher value is in case 2 in the axis Y with a value of 3.31 e-3 ±1.6% p Sv/Q this value is reported in for one. With this we can calculate the exposure time of personnel working in the reactor. (Author)

  10. Calculation and analysis of environmental costs of the atmospheric pollution from brazilian oil refinery; Calculo e analise dos custos ambientais da poluicao atmosferica emitida por uma refinaria de petroleo brasileira

    Energy Technology Data Exchange (ETDEWEB)

    Mariano, Jacqueline [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Programa de Planejamento Energetico

    2004-07-01

    The present study presents a calculation of the environmental costs associated with the atmospheric pollution from a brazilian oil refinery and its analysis (the name of this oil refinery is confidential, for this reason it will not be mentioned). The calculation of the costs was based on a study of north-american researchers, about the environmental costs of five main atmospheric pollutants: particulate matter, sulphur oxides, nitrogen oxides, volatile organic compounds (VOC's) and carbon monoxide. The original American study offers an statistical analysis of several other American studies about environmental costs of atmospheric pollution, that present maximum, medium and minimum costs. Based on these values, the total environmental costs of the atmospheric pollution from the brazilian oil refinery were calculated, considering a fifty year operational time for the facility. The internalization of the atmospheric pollution environmental costs by the refiners is aligned with the world tendency of enforcement of the environmental limitations faced by the oil refining sector, and therefore, the adoption of a pro-active attitude is recommended by the present study. (author)

  11. Calculation of conversion coefficients of dose of a computational anthropomorphic simulator sit exposed to a plane source; Calculo de coeficientes de conversao de dose de um simulador antropomorfico computacional sentado exposto a uma fonte plana

    Energy Technology Data Exchange (ETDEWEB)

    Santos, William S.; Carvalho Junior, Alberico B. de; Pereira, Ariana J.S.; Santos, Marcos S.; Maia, Ana F., E-mail: williathan@yahoo.com.b, E-mail: ablohem@gmail.co, E-mail: ariana-jsp@hotmail.co, E-mail: m_souzasantos@hotmail.co, E-mail: afmaia@ufs.b [Universidade Federal de Sergipe (UFS), Aracaju, SE (Brazil)

    2011-10-26

    In this paper conversion coefficients (CCs) of equivalent dose and effective in terms of kerma in the air were calculated suggested by the ICRP 74. These dose coefficients were calculated considering a plane radiation source and monoenergetic for a spectrum of energy varying from 10 keV to 2 MeV. The CCs were obtained for four geometries of irradiation, anterior-posterior, posterior-anterior, lateral right side and lateral left side. It was used the radiation transport code Visual Monte Carlo (VMC), and a anthropomorphic simulator of sit female voxel. The observed differences in the found values for the CCs at the four irradiation sceneries are direct results of the body organs disposition, and the distance of these organs to the irradiation source. The obtained CCs will be used for estimative more precise of dose in situations that the exposed individual be sit, as the normally the CCs available in the literature were calculated by using simulators always lying or on their feet

  12. Evaluation of errors set-up and setting margins calculation in treatments 3-D conformal radiotherapy; Evaluacion de errores de set-up y calculo de margenes de configuracion en tratamientos de radioterapia CONFORMADA 3-D

    Energy Technology Data Exchange (ETDEWEB)

    Donis, S.; Robayna, B.; Gonzalez, A.; Hernandez Armas, J.

    2011-07-01

    The use of IGRT techniques provide knowledge of the mistakes made in the positioning of a patient, to population studies and estimate the margins for each population.In this paper we evaluate the errors of set-up in 3 different locations and from these margins are calculated configuration (SM).

  13. Methodologies for the calculation of relative efficiency: description and application for natural gas distributors in Latin America; Metodologias para el calculo de eficiencia relativa: descripcion y aplicacion para distribuidores de gas natural en Latinoamerica

    Energy Technology Data Exchange (ETDEWEB)

    Escandon Jimenez, Alejandro C. [Mexico, D.F. (Mexico)

    2004-06-15

    The importance of knowing the performance of the companies within a productive sector has increased in the last years, demonstrating the necessity of knowing and applying tools that help us to know the performance of a company with respect to the others with which it is competing. Recently, a great variety of tools have been developed to know the efficiency or productivity of a company in a certain sector. Nevertheless, the two more used, up to now, are those that will be described in the present in study. Finally, one practical example of the two methodologies will be presented, applied to the natural gas industry for distributing companies of this energy in Latin America. [Spanish] La importancia de conocer el desempeno de las empresas dentro de un sector productivo ha incrementado en los ultimos anos, demostrando la necesidad de conocer y aplicar herramientas que nos ayuden a conocer el desempeno de una empresa con respecto a las demas con las cuales se esta compitiendo. Recientemente, se han desarrollado gran variedad de herramientas para conocer la eficiencia o productividad de una compania en un determinado sector. Sin embargo, las dos mas utilizadas, hasta el momento, son las que se describiran en el presente estudio. Finalmente, se presentara un ejemplo practico de las dos metodologias, aplicado a la industria del gas natural para companias distribuidoras de este energetico en Latinoamerica.

  14. Calculation of the protons stopping power in water using dielectric formalism in the MELF-GOS approach; Calculo do poder de freamento de protons em agua utilizando o formalismo dieletrico na aproximacao MELF-GOS

    Energy Technology Data Exchange (ETDEWEB)

    Ribeiro, Franciane; Mazer, Amanda Cristina; Hormaza, Joel Mesa [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Botucatu, SP (Brazil)

    2016-07-01

    In order to calculate the stopping power of protons, there are many very successful models at high energies, which are extrapolated to low-energy regions. From the point of view of application of proton beam in cancer treatment is just this low energy region the most relevant due to the dose deposition profile in depth for protons. In this work, we present a calculation of the stopping power of protons in a water target using the dielectric formalism in MELF-GOS approach. The results when compared to other models show good agreement for energies above 100 keV and lower values below this energy. This result should impact the range of values of protons and the Bragg peak position. (author)

  15. Shield calculation of project for instrument calibration integrated laboratory of IPEN-Sao Paulo, Brazil; Calculo das blindagens do projeto de um laboratorio integrado de calibracao de instrumentos no IPEN - Sao Paulo, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Barros, Gustavo A.S.J.; Caldas, Linda V.E., E-mail: gustavaobarros@gmail.co, E-mail: lcaldas@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2009-07-01

    This work performed the shield calculation of the future rooms walls of the five X-ray equipment of the Instrument Calibration Laboratory of the IPEN, Sao Paulo, Brazil, which will be constructed in project of laboratory enlargement. The obtained results by application of a calculation methodology from an international regulation have shown that the largest thickness of shielding (25.7 cm of concrete or 7.1 mm of lead) will be of the wall which will receive the primary beam of the equipment with a 320 kV voltage. The cost/benefit analysis indicated the concrete as the best material option for the shielding

  16. Quantification of tomography images for dose calculation for diagnosis and therapy in nuclear medicine; Quantificacao de imagens tomograficas para calculo de dose em diagnose e terapia em medicina nuclear

    Energy Technology Data Exchange (ETDEWEB)

    Massicano, Felipe

    2010-07-01

    The nuclear medicine area has an increasing slope in the therapy of diseases, particularly in the treatment of radiosensitive tumors. Due to the high dose levels in radionuclide therapy, it is very important the accurate quantify of the dose distribution to avoid deleterious effects on healthy tissues. In Brazil, the internal dosimetry system used is the MIRD (Medical Internal Radiation Dose) based on a reference model that does not have adequate patient data to obtain a dose accurate assessment in therapy. However, in recent years, internal radionuclide dosimetry evaluates the spatial dose distribution base ad on information obtained from CT and SPECT or PET images together with the using of Monte Carlo codes. Those systems are called patient-specific dosimetry systems. In the Nuclear Engineering Center at IPEN, this methodology is in development. When the CT images are inserted into the Monte Carlo code MCNP5 through of use of a interface software called SCMS the dosimetry can be accomplished using patient-specific data, resulting in a more accurate energy deposition in organs of interest. This work aim to contribute with the development of part of that patient-specific dosimetry for therapy. To achieve this goal we have proposed three specific objectives: (1) Development of a software to convert images from Computed Tomography (CT) in the tissue parameters ({rho}, {omega}({iota})); (2) Development of a software to perform attenuation correction in nuclear medicine tomographic images (SPECT or PET) and to provide the map of relative activity and (3) Provide data to the SCMS code by these two software. The software developed for the rst specific objective was the Image Converter Computed Tomography (ICCT), which obtained a good accuracy to determine the density and the tissue composition; the elements that had high variation were carbon and oxygen. Fortunately, this variation for the energy range used in radionuclide therapy is not detrimental to the dose distribution. A major advantage is the high accuracy obtained to calcium and phosphorus which have great influence on the dose distribution calculation. For the second objective it was developed the Attenuation Corretion SPECT PET (ACPS) software which performs the attenuation correction in PET and SPECT images through of 1a order Chang method and create the relative activity distribution within of patient. Finally, the data generated by the two software, was formatted to SCMS which in provides the complete information do the MCNP5 Monte Carlo code for radiation transport simulation for dose distribution estimation. (author)

  17. Thermical Load Calculation and Capacity of Cooling and Venting Equipment of a Diesel Engine Emissions Study Bench; Calculo de Cargas Termicas y Capacidad de los Equipos de Refrigeracion y Ventilacion de un Banco de Estudio de Emisiones de Motores Diesel

    Energy Technology Data Exchange (ETDEWEB)

    Rojas Garcia, E.; Fonseca Gonzalez, N. A.

    2005-07-01

    The present report tries to develop the calculation of thermical loads and to define the capacity of the equipments of cooling and ventilation that should have the engines test bench that is being ensemble in the installation of the CIEMAT named {sup D}iesel engine emissions study bench (E65-P0). The test bench is formed essentially by a dynamometrical brake and an engine connected at previous one, both of them inside a cabin of isolation acoustic. The thermical loads to be dissipated will be calculated for all the elements that compose the bench and considering his maximum values, to determine the suitable system of cooling air - water of the devices and ventilation in the cabin. (Author) 2 refs.

  18. Calculo de funciones de onda lcao para el estado fundamental de solidos. aplicación al estudio teórico de la estructura de los cristales de litio y de nitruro de boro. I.

    Directory of Open Access Journals (Sweden)

    Nepomuceno Quitian C.

    2009-07-01

    Full Text Available En esta primera publicación se ha aplicado el formulismo de la Química Cuántica del Estado Sólido, al estudio teórico de los cristales de Litio y de Nitruro de Boro, utilizando una base de funciones Gausianas dentro del método LCAO— SCF—MO (Linear Combination of Atomic Orbitals- Self Consistent Fields – Molecular Orbltals. Se calculan los factores de estructura teóricos a partir de los elementos de la matriz de densidad y las integrales de recubrimiento Generalizadas. Se calcula igualmente la densidad electrónica y una función delta (A a partir de los factores de estructura teóricos, con el fin de poner en evidencia la unión Química.

  19. Development of a program for calculation of second dose and securities in brachytherapy high dose rate; Elaboracion de un programa para el segundo calculo de la dosis y seguridades en braquiterapia de alta tasa de dosis

    Energy Technology Data Exchange (ETDEWEB)

    Esteve Sanchez, S.; Martinez Albaladejo, M.; Garcia Fuentes, J. D.; Bejar Navarro, M. J.; Capuz Suarez, B.; Moris de Pablos, R.; Colmenares Fernandez, R.

    2015-07-01

    We assessed the reliability of the program with 80 patients in the usual points of prescription of each pathology. The average error of the calculation points is less than 0.3% in 95% of cases, finding the major differences in the axes of the applicators (maximum error -0.798%). The program has proved effective previously testing him with erroneous dosimetry. Thanks to the implementation of this program is achieved by the calculation of the dose and part of the process of quality assurance program in a few minutes, highlighting the case of HDR prostate due to having a limited time. Having separate data sheet allows each institution to its protocols modify parameters. (Author)

  20. Design of a PET/CT facility considering the shielding calculation in accordance with AAPM TG-108; Diseno de una instalacion PET/CT considerando el calculo de blindaje segun AAPM TG-108

    Energy Technology Data Exchange (ETDEWEB)

    Guevara R, V. Y.; Romero C, N. [Empresa QC DOSE S. A. C., Av. Tomas Marsano 1915, Surquillo, Lima 34 (Peru); Berrocal T, M., E-mail: vguevara@qcdose.com [Universidad Nacional Mayor de San Marcos, C. German Amezaga 375, Edif. Jorge Basadre, Ciudad Universitaria, Lima 1 (Peru)

    2014-08-15

    A Positron Emission Tomography / Computed Tomography facility may require protection barriers on floor, ceiling and walls, because the patient becomes a radioactive source that emits photons of 0.511 MeV, after having received a radiopharmaceutical, usually F-18 fluorodeoxyglucose (F-18 FDG). This work has as objective to propose the design of a PET/CT facility, taking into account technical and radiation protection considerations applied internationally, and also develop the necessary shielding for such installation by applying as published by the American Association of Physicists in Medicine Task Group Report 108. A shielding spreadsheet in Excel program was developed with reference to the recommendations of the AAPM TG - 08, to determine the shielding required for the walls, floor and ceiling. For fixing the radiation levels in the shielding calculation has been considered the actual restrictions for the occupationally exposed personnel (100 μSv/week) as well as the people in general (20 μSv/ week). The radiopharmaceutical used as a reference for the shielding calculation was the F-18 FDG. With the assistance of an architectural plan were determined distances from potential sources of radiation in facility (uptake and image acquisition living rooms) to points of interest around them. Finally the thickness of the protective barriers in lead and concrete necessary to achieve the established radiation levels were calculated and these results were stored in a table. This paper shows that technical aspects considered in the design of the installation and environments distribution can improve work processes within the PET/CT facility, consequently resulting in a reduction of the dose levels for people in general. (author)

  1. Evaluation of the Analytical Anisotropic Algorithm (AAA) in dose calculation for fields with non-uniform fluences considering heterogeneity correction; Avaliacao do Algoritmo Analitico Anisotropico (AAA) no calculo de dose para campos com fluencia nao uniforme considerando correcao de heterogeneidade

    Energy Technology Data Exchange (ETDEWEB)

    Bornatto, P.; Funchal, M.; Bruning, F.; Toledo, H.; Lyra, J.; Fernandes, T.; Toledo, F.; Marciao, C., E-mail: pricila_bornatto@yahoo.com.br [Hospital Erasto Gaertner (LPCC), Curitiba, PR (Brazil). Departamento de Radioterapia

    2014-08-15

    The purpose of this study is to evaluate the calculation of dose distribution AAA (Varian Medical Systems) for fields with non-uniform fluences considering heterogeneity correction. Five different phantoms were used with different density materials. These phantoms were scanned in the CT BrightSpeed (©GE Healthcare) upon the array of detectors MAPCHECK2 TM (Sun Nuclear Corporation) and irradiated in a linear accelerator 600 CD (Varian Medical Systems) 6MV and rate dose 400MU/min with isocentric setup. The fluences used were exported from IMRT plans, calculated by ECLIPSE™ planning system (Varian Medical Systems), and a 10x10 cm{sup 2} field to assess the heterogeneity correction for uniform fluence. The measured dose distribution was compared to the calculated by Gamma analysis with approval criteria of 3% / 3 mm and 10% threshold. The evaluation was performed using the software SNCPatient (Sun Nuclear Corporation) and considering absolute dose normalized at maximum. The phantoms best performers were those with low density materials, with an average of 99.2% approval. Already phantoms with plates of higher density material presented various fluences below 95% of the points approved. The average value reached 94.3%. It was observed a dependency between fluency and approved percentage points, whereas for the same fluency, 100% of the points have been approved in all phantoms. The approval criteria for IMRT plans recommended in most centers is 3% / 3mm with at least 95% of points approved, it can be concluded that, under these conditions, the IMRT plans with heterogeneity correction can be performed , however the quality control must be careful because the difficulty of the system to accurately predict the dose distribution in certain situations. (author)

  2. Calculation of the uncertainty of H{sub P} (10) evaluation for a thermoluminescent dosimetry system; Calculo da incerteza da avaliacao do H{sub P} (10) para um sistema de dosimetria termoluminescente

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, M.S.; Silva, E.R.; Mauricio, C.L.P., E-mail: max.das.ferreira@gmail.com [Instituto de Radioprotecao e Dosimetria (IRD/CNEN-RJ), Rio de Janeiro, RJ (Brazil)

    2016-07-01

    Full interpretation of dose assessment only can be performed when the uncertainty of the measurement is known. The aim of this study is to calculate the uncertainty of the TL dosimetry system of the LDF/IRD for evaluation of H{sub P} (10) for photons. It has been done by experimental measurements, extraction of information from documents and calculation of uncertainties based on ISO GUM. Energy and angular dependence is the most important source to the combined u{sub c}(y) and expanded (U) uncertainty. For 10 mSv, it was obtained u{sub c}(y) = 1,99 mSv and U = 3,98 mSv for 95% of coverage interval. (author)

  3. Inventory of programs. Calculation of the isotope inventory after a hypothetical accident at the Cofrentes Nuclear power; Calculo del inventario isotopico despues de un hipotetico accidente en la Central Nuclear de Cofrentes

    Energy Technology Data Exchange (ETDEWEB)

    Albendea, M.

    2014-07-01

    Iberdrola is developing a new application to calculate the inventory of radiological material, then of a hypothetical accident, with the name of inventory. This application allows you to calculate the inventory isotopic, analysers and accurate thermal of all or part of the nucleus of the plant of Cofrentes, even of any single element, based on its history of irradiation and specific periods of decay, since the reactor at any time after the shutdown. (Author)

  4. Dose calculation for {sup 40}K ingestion in samples of beans using spectrometry and MCNP; Calculo de dose devido a ingestao de {sup 40}K em amostras de feijao utilizando espectrometria e MCNP

    Energy Technology Data Exchange (ETDEWEB)

    Garcez, R.W.D.; Lopes, J.M.; Silva, A.X., E-mail: marqueslopez@yahoo.com.br [Coordenacao dos Programas de Pos-Graduacao em Engenharia (COPPE/PEN/UFRJ), Rio de Janeiro, RJ (Brazil). Centro de Tecnologia; Domingues, A.M. [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Instituto de Fisica; Lima, M.A.F. [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Instituto de Biologia

    2014-07-01

    A method based on gamma spectroscopy and on the use of voxel phantoms to calculate dose due to ingestion of {sup 40}K contained in bean samples are presented in this work. To quantify the activity of radionuclide, HPGe detector was used and the data entered in the input file of MCNP code. The highest value of equivalent dose was 7.83 μSv.y{sup -1} in the stomach for white beans, whose activity 452.4 Bq.Kg{sup -1} was the highest of the five analyzed. The tool proved to be appropriate when you want to calculate the dose in organs due to ingestion of food. (author)

  5. Mathematical models evaluation of the calculation of the spread in the rolling of ellipsoidal and diamond profiles; Avaliacao de modelos matematicos para calculo do alargamento na laminacao dos perfis oval e losango

    Energy Technology Data Exchange (ETDEWEB)

    Schaeffer, Lirio; Guedes, Luiz F.M. [Rio Grande do Sul Univ., Porto Alegre, RS (Brazil). Programa de Pos-graduacao em Engenharia Metalurgica e dos Materiais

    1987-12-31

    In this work, general considerations are initially performed about the spread and the main factors which influence it in the rolling process.It was established a prior analysis of the models in the case of oval and diamond profiles rolling. Afterwards, three mathematical models to calculate the spread are presented. It was notes that for some mathematical models, because their expressions are presented for the rectangular sections rolling, it was necessary to use auxiliary methods, which are also shown in this work. 14 refs., 5 figs., 5 tabs.

  6. Numerical Calculation of Transport Based on the Drift-Kinetic Equation for Plasmas in General Toroidal Magnetic Geometry: Numerical Methods; Calculo Numerico de Transporte mediante la Ecuacion Cinetica de Deriva para Plasmas en Geometria Magnetica Toroidal: Metodos Numericos

    Energy Technology Data Exchange (ETDEWEB)

    Reynolds, J. M.; Lopez-Bruna, D.

    2009-10-12

    In this report we continue with the description of a newly developed numerical method to solve the drift kinetic equation for ions and electrons in toroidal plasmas. Several numerical aspects, already outlined in a previous report [Informes Tecnicos Ciemat 1165, mayo 2009], will be treated now in more detail. Aside from discussing the method in the context of other existing codes, various aspects will be now explained from the viewpoint of numerical methods: the way to solve convection equations, the adopted boundary conditions, the real-space meshing procedures along with a new software developed to build them, and some additional questions related with the parallelization and the numerical integration. (Author) 16 refs.

  7. Model for the estimate of the global subsidence in sublevel caving of wide layers in big slopes; Modelo para el Calculo de la Subsidencia Global en la Exploatacion de Capas Anchas y de Fuerte Pendiente por Sutiraje

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-31

    The Sociedad Anonima Hullera Vasco-Leonesa (HVL) is working in a highly tectonised deposit, which very thick and irregular sub vertical seams, whose particular characteristics led to follow an investigation project for the final preparation of a model to estimate the global subsidence produced during and after the works. The working method in use has been basically observatory, until the necessary values were achieved to establish a representative model of the subsidence phenomenon. The information was gathered in two stages: the most interesting details in existence were collected in the first stage and in the second one, a wide measurement work was accomplished, in order to how the ground moved while the subsidence process. The movements of the ground were measured on the surface, with classical topographic means, as well as in the underground with extensometers. Different methods have been followed for the final preparation of the estimate model, in order to select the most suitable one. Some models have been studied: the classical procedures of influence functions, the tenso-deformational models solved by means of numerical models in computers and the theoretical models based on closed solutions. A theoretical model has been selected, following J. LITWINSISZYN and S. G. AVERSHING`s theory, which has been solved using the method of finite differences in an elasticity system. Finally two computer applications were created: one of them which allows to obtain subsidence previsions and deformations, and another one focused to make the accomplishment of topographic control measurement easier. As a whole, it can be stated that, starting from this project, HVL has a suitable means to continue controlling the evolution of the subsidence and, if needed, to adjust adequately the defined model. (Author)

  8. Development of a computational code for the internal doses assessment of the main radionuclides of occupational exposure at IPEN; Desenvolvimento de um codigo computacional de apoio ao calculo de dose interna para radionuclideos de interesse do IPEN

    Energy Technology Data Exchange (ETDEWEB)

    Claro, Thiago Ribeiro

    2011-07-01

    The dose resulting from internal contamination can be estimated with the use of biokinetic models combined with experimental results obtained from bioanalysis and assessment of the time of incorporation. The biokinetics models are represented by a set of compartments expressing the transportation, retention and elimination of radionuclides from the body. The ICRP publications, number 66, 78 and 100, present compartmental models for the respiratory tract, gastrointestinal tract and for systemic distribution for an array of radionuclides of interest for the radiological protection. The objective of this work is to develop a computational code for the internal doses assessment of the main radionuclides of occupational exposure at IPEN. Consequently serving as a agile and efficient tool for the designing, visualization and resolution of compartmental models of any nature. The architecture of the system was conceived containing two independent software: CBT - responsible for the setup and manipulation of models and SSID - responsible for the mathematical solution of the models. Four different techniques are offered for the resolution of system of equations, including semi-analytical and numerical methods, allowing for comparison of precision and performance of both. The software was developed in C{ne} programming, using a Microsoft Access database and XML standards for file exchange with other applications. Compartmental models for uranium, thorium and iodine radionuclides were generated for the validation of the CBT software. The models were subsequently solved via SSID software and the results compared with the values published in the issue 78 of ICRP. In all cases the system replicated the values published by ICRP. (author)

  9. Determination of Fe-55 and Ni-63 in Environmental Samples. Analytical Problems. Characteristic Limits. Automatized Calculation; Determinacion de 55{sup F}e y 63{sup N}i en Muestras Ambientales. Problemas Analiticos. Limites Caracteristicos. Calculo Automatizado

    Energy Technology Data Exchange (ETDEWEB)

    Gasco, C; Navarro, N; Gonzalez, P; Heras, M C; Gapan, M P; Alonso, C; Calderon, A; Sanchez, D; Morante, R; Fernandez, M; Gajate, A; Alvarez, A

    2008-08-06

    The Department of Vigilance Radiologica y Radiactividad Ambiental from CIEMAT has developed an appropriate analytical methodology for Fe-55 and Ni-63 sequential determination in environmental samples based on the procedure used by RIS0 Laboratories. The experimental results obtained in the mayor and minor elements behaviour (soil and air constituents) in the different types of resins used for separating Fe-55 and Ni-63 are showed in this report. The measuring method of both isotopes by scintillation counting has been optimized with Ultima Gold liquid with different concentrations of stable element Fe and Ni. The decontamination factors of different gamma-emitters are experimentally determined in this method with the presence of soil matrix. The Fe-55 and Ni-63 activity concentrations and their associated uncertainties have been calculated from the counting data and sample preparation. A computer application has been implemented in Visual Basic in excel sheets for: (I) obtaining the counting data from spectrometer and counts in each window, (II) representing graphically the background and sample spectrums, (III) determining the activity concentration and its associated uncertainty and (IV) calculating the characteristic limits using ISO 11929 (2007) with various confidence levels. (Author) 30 refs.

  10. Analysis of radioactive waste contamination in soils. Part III: estimation of apparent diffusion coefficient; Analise de contaminacao de residuo radioativo em solos. Parte 3: calculo do coeficiente de difusao aparente

    Energy Technology Data Exchange (ETDEWEB)

    Souza, R.; Pereira, L.M.; Orlande, H.R.B.; Cotta, R.M. [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia. Dept. de Engenharia Mecanica

    1997-12-31

    This paper deals with the estimation of the apparent diffusion coefficient of KBr in sand saturated with water. The present inverse parameter estimation problem is solved with Levenberg-Marquardt method. Simulated experimental data is used in order to assess the accuracy of this method as applied to the estimation of the apparent diffusion coefficient. The experimental apparatus is described and the value estimated for the parameter obtained with actual experimental data is presented in the paper. A statistical analysis is performed in order to obtain an estimate for the standard deviation for the parameter. (author) 12 refs., 7 figs., 3 tabs.; helcio at serv.com.ufrj.br

  11. Calculation of source term in spent PWR fuel assemblies for dry storage and shipping cask design; Calculo de los terminos fuente de combustibles irradiados PWR para el diseno de contenedores de almacenamiento y transporte

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez, J L; Lopez, J

    1986-07-01

    Using the ORIGEN-2 Coda, the decay heat and neutron and photon sources for an irradiated PWR fuel element have been calculated. Also, parametric studies on the behaviour of the magnitudes with the burn-up, linear heat power and irradiation and cooling times were performed. Finally, a comparison between our results and other design calculations shows a good agreement and confirms the validity of the used method. (Author) 6 refs.

  12. Advanced calculations developed for the ITER project within of engineering support framework contracts to F4E; Calculos avanzados desarrollados para el proyecto ITER dentro de los contratos marco de soporte de ingenieria para F4E

    Energy Technology Data Exchange (ETDEWEB)

    Bosch, C.; Polo, J.; Garcia Cid, J.; Guirao, J.; Fernandez, E.; Bayon, A.; Caixas, J.

    2013-07-01

    Present the different kind of analyses carried out within the engineering support framework contracts for F4E in the period 2009-2013 and its evolution according to project needs and Vacuum Vessel manufacturing status.

  13. Development and implementation of a software for assessment of calculations in radiotherapy monitor units; Elaboracao e implementacao de um programa para verificacao dos calculos das unidades monitoras em radioterapia

    Energy Technology Data Exchange (ETDEWEB)

    Mueller, Marcio Rogerio; Silva, Marco Antonio da; Rodrigues, Laura Natal [Sao Paulo Univ., SP (Brazil). Hospital das Clinicas. Servico de Radioterapia]. E-mail: mrmuller@usp.br

    2005-12-01

    Objective: To develop and implement a software based on the manual calculation algorithm for verification of the calculations in radiotherapy monitor units and to establish acceptance levels as a mechanism of quality assurance. Materials and methods: Data were obtained from Clinac 600C and 2100C Varian linear accelerators and the computerized treatment planning system used was CadPlan{sup TM}. Results: For the 6 MV beams the acceptance levels for deviations among the calculations of monitor units, divided by treatment area, were the following: breast (0.0%{+-}1.7%), head and neck (1.5%{+-}0.5%), hypophysis (-1.7%{+-}0.5%), pelvis (2.1%{+-}2.1%) and thorax (0.2%{+-}1.3%). For the 15 MV beams the suggested level for pelvis in all the treatment techniques was (3.2%{+-}1.3%). Conclusion: The present data are sufficient to justify the use of the software in the clinical practice as a tool for the quality assurance program. (author)

  14. Simplified methodology for control cell constant calculations of the reactor cores for the space kinetics; Metodologia simplificada para calculos das constantes das celulas de controles dos nucleos de reatores para a cinetica espacial

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Rubens Souza dos [Instituto de Engenharia Nuclear (IEN), Rio de Janeiro, RJ (Brazil); Martinez, Aquilino Senra; Alvim, Antonio Carlos Marques [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia. Programa de Engenharia Nuclear

    2002-07-01

    In this work is presented a methodology which focuses the distribution of neutron absorber rods in nuclear reactor power plants, for utilizing in space kinetic calculations, principally in the cluster ejection transients of control rods. A numerical model for macroscopic constant calculations based on the knowledge of the neutron flux without the control rods is proposed, as alternative to the analytical models, based on the hypothesis of the null current on the cell super boundaries. The proposed model in this work has itself showed adequate to deal with problems with strong space dependence, once that the model showed consistence in the global average built in the analytical model. (author)

  15. Aquelarre. A computer code for fast neutron cross sections from the statistical model; AQUELARRE. Un programa numerico para el calculo de secciones eficaces neutronicas mediante el modelo de nucleo compuesto

    Energy Technology Data Exchange (ETDEWEB)

    Guasp, J.

    1974-07-01

    A Fortran V computer code for Univac 1108/6 using the partial statistical (or compound nucleus) model is described. The code calculates fast neutron cross sections for the (n, n'), (n, p), (n, d) and (n, {alpha}) reactions and the angular distributions and Legendre moments for the (n, n) and (n, n') processes in heavy and intermediate spherical nuclei. A local Optical Model with spin-orbit interaction for each level is employed, allowing for the width fluctuation and Moldauer corrections, as well as the inclusion of discrete and continuous levels. (Author) 67 refs.

  16. Thermal-hydraulic feedback model to calculate the neutronic cross-section in PWR reactions; Modelo termohidraulico para realimentacao do calculo de secoes de choque neutronicas em reatores PWR

    Energy Technology Data Exchange (ETDEWEB)

    Santiago, Daniela Maiolino Norberto

    2011-07-01

    In neutronic codes,it is important to have a thermal-hydraulic feedback module. This module calculates the thermal-hydraulic feedback of the fuel, that feeds the neutronic cross sections. In the neutronic co de developed at PEN / COPPE / UFRJ, the fuel temperature is obtained through an empirical model. This work presents a physical model to calculate this temperature. We used the finite volume technique of discretized the equation of temperature distribution, while calculation the moderator coefficient of heat transfer, was carried out using the ASME table, and using some of their routines to our program. The model allows one to calculate an average radial temperature per node, since the thermal-hydraulic feedback must follow the conditions imposed by the neutronic code. The results were compared with to the empirical model. Our results show that for the fuel elements near periphery, the empirical model overestimates the temperature in the fuel, as compared to our model, which may indicate that the physical model is more appropriate to calculate the thermal-hydraulic feedback temperatures. The proposed model was validated by the neutronic simulator developed in the PEN / COPPE / UFRJ for analysis of PWR reactors. (author)

  17. Equivalent Coil Model for Computing Levitation Forces Between Permanent Magnets and High Temperatures Superconductors; Modelo de Espira Equivalente para el Calculo de Fuerzas de Levitacion Magnetica entre Imanes Permanentes y Superconductores de Alta Temperatura Critica

    Energy Technology Data Exchange (ETDEWEB)

    Cavia Santos, S; Garcia-Tabares, L

    1998-05-01

    A new simple theory has been developed for the study of levitation forces between a permanent magnet and a HTc superconductor. This theory is based on the assumption that both, the magnet and the superconductor, can be modelled by an equivalent coil placed on their surface. While the current flowing through the permanent magnet is constant, the equivalent current through the superconductor can be iether corresponding to screen the overall flux or a constant current corresponding to critical current density when the superconductor is saturated. A test facility has been designed and built for measuring levitation forces at variable approaching speeds. Comparison between theoretical and experimental measurements are presented in the report as well as a general description of the test facility. (Author)

  18. On line CALDose{sub X}: real time Monte Carlo calculation via Internet for dosimetry in radiodiagnostic; CALDose{sub X} online: Calculos de Monte Carlo em tempo real via Internet para dosimetria em radiodiagnostico

    Energy Technology Data Exchange (ETDEWEB)

    Kramer, Richard; Cassola, Vagner Ferreira; Lira, Carlos Alberto Brayner de Oliveira; Khoury, Helen Jamil, E-mail: rkramer@uol.com.b, E-mail: vagner.cassola@gmail.co [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Dept. de Energia Nuclear; Cavalcanti, Arthur; Lins, Rafael Dueire, E-mail: rdl@ufpe.b [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Centro de Tecnologia e Geociencias. Dept. de Eletronica e Sistemas

    2011-10-26

    The CALDose{sub X} 4.1 is a software which uses thr MASH and FASH phantoms. Patient dosimetry with reference phantoms is limited because the results can be applied only for patients which possess the same body mass and right height that the reference phantom. In this paper, the dosimetry of patients for diagnostic with X ray was extended by using a series of 18 phantoms with defined gender, different body masses and heights, in order to cover the real anatomy of the patients. It is possible to calculate absorbed doses in organs and tissues by real time Monte Carlo dosimetry through the Internet through a dosimetric service called CALDose{sub X} on line

  19. Calculation of the thicknesses of the walls of the radiographic inspection building of the NKS enterprise; Calculo de los espesores de los muros del edificio de inspeccion radiografica de la empresa NKS

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez A, G; Gutierrez R, C

    1983-07-15

    During the month of February, 1983, the Structural Civil Department of the Latin American of Engineering, S.A. de C.V. company (LATISA), outline to the Engineering and Industry Applications Management of the ININ that the industrial group NKS had taken charge them the design of a building where it would lodge a linear electron accelerator of 4 MeV, one source of Co-60 of 30 Ci and an X-ray equipment, tube type, of range of 60 to 300 KV and that to make the design they required to know the necessary thickness of the walls, doors and roof to protect to the workers, outside of the building, of the X and gamma radiations generated by the sources mentioned during the radiographic inspections of metal-mechanical pieces. (Author)

  20. Computerization of effluent management and external dose calculation using the 'ODCM' methodology applied to Almaraz-NPP; Mecanizacion informatica de la gestion de efluentes y calculo de dosis al exterior usando la metodologia MCDE aplicada a C.N. Almaraz

    Energy Technology Data Exchange (ETDEWEB)

    Garcia Gutierrez, M E [Empresarios Agrupados, A.I.E., Madrid (Spain); Sustacha Duo, D [C.N. Almaraz, Caceres (Spain)

    1993-12-15

    The ODCM (Offsite Dose Calculation Manual), the official operational document for all nuclear power plants develops the details for the technical specifications for discharges and governs their practical application. The use of ODCM methodology for managing and controlling data associated with radioactive discharges, as well as the subsequent processing of this data to assess the radiological impact, requires and generates a large volume of data, which demands the frequent application of laborious and complex calculation processes, making computerization necessary. The computer application created for Almaraz NPP has the capacity to store and manage data on all discharges, evaluate their effects, presents reports and copies the information to be sent periodically to the CSN (Spanish Nuclear Regulatory Commission) on a magnetic tape. The radiological impact of an actual or possible discharge can be evaluated at anytime and, furthermore, general or particular reports and graphs on the discharges and doses over time can be readily obtained. The application is run on a personal computer under a relational database management system. This interactive application is based on menus and windows. (author)

  1. Calculation of neutron activation of control rods of a nuclear reactor, using MCNP5; Calculo de activacion neutronica de barras de control de un reactor nuclear, utilizando MCNP5

    Energy Technology Data Exchange (ETDEWEB)

    Pena V, J.D.

    2016-07-01

    The control rods of a nuclear reactor are activated by neutron irradiation. The generated activity produces a dose around the rod which is irrelevant inside the reactor, but significant when the rod is withdrawn and placed in a storage pool, because this dose is a potential risk to the surrounding personnel. On the other hand, most of the activation occurs in the stainless steel components of the rod. The Monte Carlo model can reliably determine the activation produced in a stainless steel part exposed to a neutron flux in a reactor and the dose measurement around this part. This thesis presents the Monte Carlo models developed for the activation of the control rods of the TRIGA Mark III reactor of Instituto Nacional de Investigaciones Nucleares (ININ) when only standard fuel was available. Therefore, the validations of the Monte Carlo models are reliable. (Author)

  2. Development of a computational model for the calculation of neutron dose equivalent in laminated primary barriers of radiotherapy rooms; Desenvolvimento de um modelo computacional para calculo do equivalente de dose de neutrons em barreiras primarias laminadas de salas de radioterapia

    Energy Technology Data Exchange (ETDEWEB)

    Rezende, Gabriel Fonseca da Silva

    2015-06-01

    Many radiotherapy centers acquire 15 and 18 MV linear accelerators to perform more effective treatments for deep tumors. However, the acquisition of these equipment must be accompanied by an additional care in shielding planning of the rooms that will house them. In cases where space is restricted, it is common to find primary barriers made of concrete and metal. The drawback of this type of barrier is the photoneutron emission when high energy photons (e.g. 15 and 18 MV spectra) interact with the metallic material of the barrier. The emission of these particles constitutes a problem of radiation protection inside and outside of radiotherapy rooms, which should be properly assessed. A recent work has shown that the current model underestimate the dose of neutrons outside the treatment rooms. In this work, a computational model for the aforementioned problem was created from Monte Carlo Simulations and Artificial Intelligence. The developed model was composed by three neural networks, each being formed of a pair of material and spectrum: Pb18, Pb15 and Fe18. In a direct comparison with the McGinley method, the Pb18 network exhibited the best responses for approximately 78% of the cases tested; the Pb15 network showed better results for 100% of the tested cases, while the Fe18 network produced better answers to 94% of the tested cases. Thus, the computational model composed by the three networks has shown more consistent results than McGinley method. (author)

  3. Aspectos a considerar en los calculos de efectividad de una cobertura de valor razonable en donde el swap de tasa de interes intercambia una tasa flotante por otra tasa flotante

    Directory of Open Access Journals (Sweden)

    Miguel A. Garcia

    2009-07-01

    Full Text Available This article analyzes the hedge accounting of fair value hedge on a variable-tovariable swap. Following the effectiveness valuation procedure established in Bulletin C-10 “Derivative Financial Instruments and Hedge Activities” under Mexican GAAP will generate distorted effectiveness outcome even though the critical terms between the hedge item and the hedging instrument are the same in all aspects. To show this effect we present a hypothetic example for a fair value hedge relationship LIBOR-TIIE. Our conclusion is that this distortion is due to a valuation effect known as “pull to par” especially when the coupon reset dates of the hedge item and the hedging instrument does not match with the valuation date. Finally, it propones alternative ways to book this kind of transactions that eliminate the temporal distortion that this pull to par effect generates.

  4. Qualification of the WIMS lattice code, for the design, operation and accident analysis of nuclear reactors; Calificacion del programa WIMS de calculo neutronico para diseno, seguimiento de operacion y analisis de accidentes de reactores nucleares

    Energy Technology Data Exchange (ETDEWEB)

    Lerner, A M [Ente Nacional Regulador Nuclear, Buenos Aires (Argentina)

    1997-12-31

    A basic problem in nuclear reactor physics in that of the description of the neutron population behaviour in the multiplicative medium of a nuclear fuel. Due to the magnitude of the physical problem involved and the present degree of technological evolution regarding computing resources, of increasing complexity and possibilities, the calculation programs or codes have turned to be a basic auxiliary tool in reactor physics. In order to analyze the global problem, several aspects should be taken into consideration. The first aspect to be considered is that of the availability of the necessary nuclear data. The second one is the existence of a variety of methods and models to perform the calculations. The final phase for this kind of analysis is the qualification of the computing programs to be used, i.e. the verification of the validity domain of its nuclear data and the models involved. The last one is an essential phase, and in order to carry it on great variety of calculations are required, that will check the different aspects contained in the code. We here analyze the most important physical processes that take place in a nuclear reactor cell, and we consider the qualification of the lattice code WIMS, that calculates the neutronic parameters associated with such processes. Particular emphasis has been put in the application to natural uranium fuelled reactor, heavy water cooled and moderated, as the Argentinean power reactors now in operation. A wide set of experiments has been chosen: a.-Fresh fuel in zero-power experimental facilities and power reactors; b.-Irradiated fuel in both types of facilities; c.-Benchmark (prototype) experiments with loss of coolant. From the whole analysis it was concluded that for the research reactors, as well as for the heavy water moderated power reactors presently operating in our country, or those that could operate in a near future, the lattice code WIMS is reliable and produces results within the experimental values and their errors, and as good as those produced by the most reliable calculation tools available at present. (author). refs., figs., tabs.

  5. Calculation of dose distribution in the patient for verification of plans of intensity modulated radiation therapy; Calculo de la distribucion de dosis en el paciente para la verificacion de planes de radioterapia de intensidad modulada

    Energy Technology Data Exchange (ETDEWEB)

    Perez Moreno, J. M.; Zucca Aparicio, D.; Garcia Ruiz-Zorrila, J.; Fernandez Leton, J. P.; Minambres Moro, A.

    2013-07-01

    The precision in the delivery of radiation therapy treatments intensity modulated depends on, among other things, of the proper administration of the sequence of radiation calculated on the planning system. In recent years the electronic devices of imaging portal have shown as a useful tool for the measurement of dose distribution with high resolution. An algorithm has been developed to calculate the distribution of dose in the patient's Anatomy, using the accelerator as measuring equipment electronic imaging of portal In this way the acceptance criteria can be changed in the dosimetry verifications pretreatment of radiation therapy treatments, from those based on evaluation of gamma index to others based on the evaluation of the distribution of dose in the patient. (Author)

  6. Calculation of conversion factor of Kerma in the air for ambient dose equivalent in radiotherapy; Calculo dos fatores de conversao de Kerma no ar para equivalente de dose ambiental em radioterapia

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Marco Antonio Frota

    2000-03-01

    This work aims to estimate the average conversion factor of Kerma in air to H {sup *} (10) using photon beams coming from clinic linear accelerators, transmitted through concrete walls of a radiotherapic treatment room. The transmitted photon spectra by both 1 meter and 2 meters concrete walls, in an area of 40 x 40 cm{sup 2}, were calculated when the primary beam impart in an angle of 0 deg. The (secondary) photon beams transmitted respectively by 0,5 meter, 1,0 meter, 1,0 meter and 2,0 meter concrete walls, after they scattered by an angle of 90 deg in a cylindric phantom inside the room, were also determined. Generally, 50 millions of histories were computed for each simulation made for the primary beam. For the 90 deg spread, the number of histories was 100 millions. The computational code used on this work was the MCNP4B. The most common clinic accelerators used on radiotheraphic treatments were used on this work CLINAC-4, CLINAC-6, CLINAC-18 and CLINAC-2500. From the spectra analysis obtained in this work, it was possible to dispose the conversion factor for realistic beams found in radiotherapeutic establishment. (author)

  7. Dosimetric calculations by Monte Carlo for treatments of radiosurgery with the Leksell Gamma Knife, homogeneous and non homogeneous cases; Calculos dosimetricos por Monte Carlo para tratamientos de radiocirugia con el Leksell Gamma Knife, casos homogeneo y no homogeneo

    Energy Technology Data Exchange (ETDEWEB)

    Rojas C, E.L. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico); Lallena R, A.M. [Universidad de Granada (Spain)

    2004-07-01

    In this work dose profiles are calculated that are obtained modeling treatments of radiosurgery with the Leksell Gamma Knife. This was made with the simulation code Monte Carlo Penelope for an homogeneous mannequin and one not homogeneous. Its were carried out calculations with the irradiation focus coinciding with the center of the mannequin as in near areas to the bone interface. Each one of the calculations one carries out for the 4 skull treatment that it includes the Gamma Knife and using a model simplified of their 201 sources of {sup 60} Co. It was found that the dose profiles differ of the order of 2% when the isocenter coincides with the center of the mannequin and they ascend to near 5% when the isocenter moves toward the skull. (Author)

  8. Independent dose calculation in IMRT for the Tps Iplan using the Clarkson modified integral; Calculo independiente de dosis en IMRT para el TPS Iplan usando la integral modificada de Clarkson

    Energy Technology Data Exchange (ETDEWEB)

    Adrada, A.; Tello, Z.; Garrigo, E.; Venencia, D., E-mail: jorge.alberto.adrada@gmail.com [Instituto Privado de Radioterapia, Obispo Oro 423, X5000BFI Cordoba (Argentina)

    2014-08-15

    Intensity-Modulated Radiation Therapy (IMRT) treatments require a quality assurance (Q A) specific patient before delivery. These controls include the experimental verification in dose phantom of the total plan as well as dose distributions. The use of independent dose calculation (IDC) is used in 3D-Crt treatments; however its application in IMRT requires the implementation of an algorithm that allows considering a non-uniform intensity beam. The purpose of this work was to develop IDC software in IMRT with MLC using the algorithm proposed by Kung (Kung et al. 2000). The software was done using Matlab programming. The Clarkson modified integral was implemented on each flowing, applying concentric rings for the dose determination. From the integral of each field was calculated the dose anywhere. One time finished a planning; all data are exported to a phantom where a Q A plan is generated. On this is calculated the half dose in a representative volume of the ionization chamber and the dose at the center of it. Until now 230 IMRT planning were analyzed carried out ??in the treatment planning system (Tps) Iplan. For each one of them Q A plan was generated, were calculated and compared calculated dose with the Tps, IDC system and measurement with ionization chamber. The average difference between measured and calculated dose with the IDC system was 0.4% ± 2.2% [-6.8%, 6.4%]. The difference between the measured and the calculated doses by the pencil-beam algorithm (Pb) of Tps was 2.6% ± 1.41% [-2.0%, 5.6%] and with the Monte Carlo algorithm was 0.4% ± 1.5% [-4.9%, 3.7%]. The differences of the carried out software are comparable to the obtained with the ionization chamber and Tps in Monte Carlo mode. (author)

  9. Calculating of radiation doses in rutinary unloads of liquid wastes from Laguna Verde nuclear power plant.; Calculo de las dosis de radiacion debidas a las descargas rutinarias de desechos liquidos de la central nucleoelectrica de Laguna Verde.

    Energy Technology Data Exchange (ETDEWEB)

    Molina, G

    1986-12-31

    Utilization of nuclear energy to generate electricity is increasingly being used to replace fossil fuels. During operation of nuclear power plants, radioactive materials are produced, a small fraction of which are released to environment as liquid or gaseous effluents. Estimation of radiation doses caused by effluents release has three purposes. During design phase of a nuclear station it is useful to adapt the wastes treatment systems to acceptable limits. During licensing phase, the regulator organism verifies the design of nuclear station effectuating estimation of doses. Finally, during operation, before every unload of radioactive effluents, radiation doses should be evaluated in order to fulfill technical specifications limiting the release of radioactive materials to environment. 1. To perform calculations of individual doses due to liquid radioactive effluents unload in units 1 and 2 of Laguna Verde nuclear power plant (In licensing phase). 2. To perform a parametric study of the effect of unload recirculation over individual dose, since recirculation has two principal effects: thermodynamical effects in nuclear station and radioactivity concentration; the last can affect the fullfilment of dose limits. 3. To perform the calculation of collective doses causes by unloads of liquid effluents within a radius of 80 km of the plant caused by unload of liquid radioactive effluents during normal operation and does not include doses during accident conditions. In Mexico the organism in charge of regulation of peaceful uses of nuclear energy is Comision Nacional de Seguridad Nuclear y Salvaguardias (CNSNS) and for Laguna Verde licensing, the regulations of the country who manufactured the reactor (USA). In Appendix C, units are explained.

  10. Lateral hydraulic forces calculation on PWR fuel assemblies with computational fluid dynamics codes; Calculo de fuerzas laterales hidraulicas en elementos combustibles tipo PWR con codigos de dinamica de fluidos coputacional

    Energy Technology Data Exchange (ETDEWEB)

    Corpa Masa, R.; Jimenez Varas, G.; Moreno Garcia, B.

    2016-08-01

    To be able to simulate the behavior of nuclear fuel under operating conditions, it is required to include all the representative loads, including the lateral hydraulic forces which were not included traditionally because of the difficulty of calculating them in a reliable way. Thanks to the advance in CFD codes, now it is possible to assess them. This study calculates the local lateral hydraulic forces, caused by the contraction and expansion of the flow due to the bow of the surrounding fuel assemblies, on of fuel assembly under typical operating conditions from a three loop Westinghouse PWR reactor. (Author)

  11. The criteria for setting the natural gas reference price for purposes of government take calculation; Os criterios para fixacao do preco de referencia do gas natural para fins de calculo das participacoes governamentais

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Flavio Augusto Pimentel de; Rosa, Renata Gualberto Cordeiro [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2008-07-01

    The Petroleum Law states that the concession contract will also have provisions regarding the government takes established by the bid tender. However, the criteria for calculating the value of Royalties are set forth in the Decree 2.705/98, enacted to set such criteria, taking into account the volumes of production and the reference prices for oil and natural gas. The following aspects are analyzed in this paper: the method for calculating the volumes subject to the impact of Royalties; definition of the reference price for natural gas, the general rule for setting up the reference price in case the sale was made at market price; the special rule in case the sale was not made on a market basis, in case there is no sale or in case of breach of the conditions set in that Decree; and the settlement of the reference price in situations where only part of the volumes produced are sold on contracts that meet the requirements of the Decree. In conclusion the problems caused by gaps in legislation will be highlighted, particularly with regard to concessions granted to consortia as well as the inconsistencies between the applicable legislation, which may provide different analysis, including by the ANP, according to the features of each case. (author)

  12. Estimating effective wedge factor for enhanced dynamic wedge 2100CD a Varian Clinac; Calculo De factor cuna efectiva para cuna dinamica mejorada de un Clinac 2100CD de Varian

    Energy Technology Data Exchange (ETDEWEB)

    Pizarro Trigo, F.; Morillas Ruiz, J.; Nunuz Martinez, L.; Sanchez Jimenez, J.

    2011-07-01

    The purpose of this paper is to compare different methods of calculating the effective factor enhanced dynamic wedge (EDWF) with the values ??obtained in measurements of symmetric and asymmetric fields.

  13. Calculation of the internal pressure of fuel rod from measurements of krypton-85 at its plenum; Calculo de la presion interna de barra combustible a partir de la medida de kripton-85 en su plenum

    Energy Technology Data Exchange (ETDEWEB)

    Arana, I.; Doncel, N.; Casado, C.

    2012-07-01

    ENUSA carried out numerous campaigns of measurement internal pressure of fuel rod irradiated. All of them have been performed of form destructively in a hot cell laboratory which implies a time high to obtain results and a high economic cost to obtain a single data by rod, representative of the end of the irradiation. The objective of the project is to develop a non-destructive measurement and a methodology for reliable calculation that eliminates these problems.

  14. Coupling between the differential and perturbation theory methods for calculating sensitivity coefficients in nuclear transmutation problems; Acoplamento entre os metodos diferencial e da teoria da perturbacao para o calculo dos coeficientes de sensibilidade em problemas de transmutacao nuclear

    Energy Technology Data Exchange (ETDEWEB)

    Rossi, Lubianka Ferrari Russo

    2014-07-01

    The main target of this study is to introduce a new method for calculating the coefficients of sensibility through the union of differential method and generalized perturbation theory, which are the two methods generally used in reactor physics to obtain such variables. These two methods, separated, have some issues turning the sensibility coefficients calculation slower or computationally exhaustive. However, putting them together, it is possible to repair these issues and build a new equation for the coefficient of sensibility. The method introduced in this study was applied in a PWR reactor, where it was performed the sensibility analysis for the production and {sup 239}Pu conversion rate during 120 days (1 cycle) of burnup. The computational code used for both burnup and sensibility analysis, the CINEW, was developed in this study and all the results were compared with codes widely used in reactor physics, such as CINDER and SERPENT. The new mathematical method for calculating the sensibility coefficients and the code CINEW provide good numerical agility and also good efficiency and security, once the new method, when compared with traditional ones, provide satisfactory results, even when the other methods use different mathematical approaches. The burnup analysis, performed using the code CINEW, was compared with the code CINDER, showing an acceptable variation, though CINDER presents some computational issues due to the period it was built. The originality of this study is the application of such method in problems involving temporal dependence and, not least, the elaboration of the first national code for burnup and sensitivity analysis. (author)

  15. Optimization of the parameter calculation the process of production historic by using Parallel Virtual Machine-PVM; Otimizacao do calculo de parametros no processo de ajuste de historicos de producao usando PVM

    Energy Technology Data Exchange (ETDEWEB)

    Vargas Cuervo, Carlos Hernan

    1997-03-01

    The main objective of this work is to develop a methodology to optimize the simultaneous computation of two parameters in the process of production history matching. This work describes a procedure to minimize an objective function established to find the values of the parameters which are modified in the process. The parameters are chosen after a sensibility analysis. Two optimization methods are tested: a Region Search Method (MBR) and Polytope Method. Both are based in direct search methods which do not require the function derivative. The software PVM (Parallel Virtual Machine) is used to parallelize the simulation runs, allowing the acceleration of the process and the search of multiple solutions. The validation of the methodology is applied to two reservoir models: one homogeneous and other heterogeneous. The advantages of each method and of the parallelization are also present. (author)

  16. Calculation of cooling internal circuits loss of load curve in giant electric machines; Calculo da curva de perda de carga dos circuitos axiais internos de refrigeracao de maquinas eletricas gigantes

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Hilton Penha [Parana Univ., Curitiba, PR (Brazil). Dept. de Engenharia Mecanica. Dept. de Engenharia do Produto; Passos, Alex Sandro Barbosa [Parana Univ., Curitiba, PR (Brazil). Dept. de Engenharia Mecanica. Dept. de Pesquisa e Desenvolvimento do Produto

    2001-07-01

    This article describes a method for calculation of the loss of load curve for the ventilation axial circuits. The method assumes the ventilation circuit representation in a way similar to the electrical circuits. The great difficulty of circuit solution resides in the non linearity of the loss of load resistances and the equations relating the pressures and flows. The method is based on the association of the resistance curves of loss of load in a such way that, when the resistance curve of the total circuit loss of load is obtained, the blower operation point can be easily obtained and, consequently, the individual flows for each section of the circuit.

  17. Coordinated Use of Heterogeneous Infrastructures for Scientific Computing at CIEMAT by means of Grid Technologies; Aprovechamiento Coordinado de las Infraestructuras Heterogeneas para Calculo Cientifico Participadas por el CIEMAT por medio de Tecnologias Grid

    Energy Technology Data Exchange (ETDEWEB)

    Rubio-Montero, A. J.

    2008-08-06

    Usually, research data centres maintain platforms from a wide range of architectures to cover the computational needs of their scientists. These centres are also frequently involved in diverse national and international Grid projects. Besides, it is very difficult to achieve a complete and efficient utilization of these recourses, due to the heterogeneity in their hardware and software configurations and their unequal use along the time. This report offers a solution to the problem of enabling a simultaneous and coordinated access to the variety of computing infrastructures and platforms available in great Research Organisms such as CIEMAT. For this purpose, new Grid technologies have been deployed in order to facilitate a common interface which enables the final user to access the internal and external resources. The previous computing infrastructure has not been modified and the independence on its administration has been guaranteed. For a sake of comparison, a feasibility study has been performed with the execution of the Drift Kinetic Equation solver (Dikes) tool, a high throughput scientific application used in the TJ-II Flexible Heliac at National Fusion Laboratory. (Author) 35 refs.

  18. Monte Carlo method for dose calculation due to oral X-rays; Coeficientes de conversao para calculo de doses devidos a radiografias odontologicas utilizando o metodo de Monte Carlo

    Energy Technology Data Exchange (ETDEWEB)

    Loureiro, Eduardo Cesar de Miranda

    1998-06-01

    The increasing utilization of oral X-rays, especially in youngsters and children, calls for the assessment of equivalent doses in their organs and tissues. With this purpose, a Monte Carlo code was adapted to simulate an X-ray source irradiating phantoms of the MIRD-5 type with different ages (10, 15 and 40 years old) to calculate the conversion coefficients which transform the exposure at skin to equivalent doses at several organs and tissues of interest. In order to check the computer program, simulations were performed for adult patients using the original code (ADAM.FOR developed at the GSF-Germany) and the adapted program (MCDRO.PAS). Good agreement between results obtained with both codes was observed. Irradiations of the incisive, canine and molar teeth were simulated. The conversion factors were calculated for the following organs and tissues: thyroid, active bone narrow (head and whole body), bone (facial skeleton, cranium and whole body), skin (head and whole body) and crystalline. Based on the obtained results, it follows that the younger the patient and the larger the field area, the higher the dose in assessed organs and tissues. The variation of the source-skin distance does not change the conversion coefficients. On the other hand, the increase in the voltage applied to the X-ray tube causes an increase in the calculated conversion coefficients. (author)

  19. Calculation errors of Set-up in patients with tumor location of prostate. Exploratory study; Calculo de errores de Set-up en pacientes con localizacion tumoral de prostata. Estudio exploratorio

    Energy Technology Data Exchange (ETDEWEB)

    Donis Gil, S.; Robayna Duque, B. E.; Jimenez Sosa, A.; Hernandez Armas, O.; Gonzalez Martin, A. E.; Hernandez Armas, J.

    2013-07-01

    The calculation of SM is done from errors in positioning (set-up). These errors are calculated from movements in 3D of the patient. This paper is an exploratory study of 20 patients with tumor location of prostate in which errors of set-up for two protocols of work are evaluated. (Author)

  20. Axial profiles of burned and fraction of holes for calculations of criticality with credit for BWR fuel burning; Perfiles axiales de quemado y fraccion de huecos para calculos de criticidad con credito al quemado para combustible BWR

    Energy Technology Data Exchange (ETDEWEB)

    Casado Sanchez, C.; Rubio Oviedo, P.

    2014-07-01

    This paper presents a method to define surround profiles of burning and fraction of holes suited for use in applications of credit to burning of BWR fuel from results obtained with the module STARBUCS of SCALE. (Author)

  1. Main features and possibilities of the new scale module for calculation of sensitivity and uncertainty by sampling: SAMPLER; Principlaes caracteristicas y posibilidades del nuevo modulo de SCALE 6.2 para calculo de sensibilidad e incertidumbre por muestreo: SAMPLER

    Energy Technology Data Exchange (ETDEWEB)

    Mesado, C.; Miro, R.; Barrachina, T.; Verdu, G.

    2014-07-01

    Due to the importance of calculating sensitivity and uncertainty in the calculation of field engineering, and especially in the nuclear world, it has been decided to present the main features of the new module present in the new version of SCALE 6.2 (currently beta 3 version) called SAMPLER. This module allows the calculation of uncertainty in a wide range of effective sections, neutron parameters, composition and physical parameters. However, the calculation of sensitivity is not present in the beta 3 release. Even so, this module can be helpful for participants of the proposed Benchmark by Expert Group on Uncertainty Analysis in Modelling (UAM-LWR), as well as to analysts in general. (Author)

  2. Revision of the equation Calculated Cetane Index for the characteristics of diesel commercialized in the Parana-Brazil; Revisao da equacao de Calculo do Indice de Cetano para as caracteristicas do diesel comercializado no Parana

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Tatiana Bittencourt de; Yamamoto, Carlos Itsuo; Cocco, Lilian Cristina [Universidade Federal do Parana (UFPR), Curitiba, PR (Brazil). Lab. de Analise de Combustiveis Automotivos (LACAUTets)

    2008-07-01

    This work presents the development of models for Calculated Cetane Index (CCI) determination with the purpose of tailor it to the diesel oil sold in Brazil, using optimization techniques. As the diesel is the main fuel on the Brazilian territory, their quality is of great importance. The CCI calculation is important to evaluate the diesel quality. The standard ASTM D 4737 does not take into account the presence of cetane booster additive and biodiesel, which creates the need to recast the equation of the CCI determination. About 300 representative samples were selected of diesel in Parana, during the 2006 to 2007 period, which had their physic-chemical properties determined using the methodology adopted by the ANP - the Brazilian petroleum, natural gas and biofuel agency. The Derived Cetane Number was obtained in the IQT apparatus and several models were proposed, all with better predictive capability than the equation of the standard ASTM D 4737. It is pointed out that biodiesel can act as cetane booster additive depending upon its origin, mostly in concentrations above 5%. The methodology can be expanded to generate a representative equation for the diesel sold in the whole Brazilian territory. (author)

  3. Evaluation of the shield calculation adequacy of radiotherapy rooms through Monte Carlo Method and experimental measures; Avaliacao da adequacao do calculo de blindagens de salas de radioterapia atraves do metodo de Monte Carlos e medidas experimentais

    Energy Technology Data Exchange (ETDEWEB)

    Meireles, Ramiro Conceicao

    2016-07-01

    The shielding calculation methodology for radiotherapy services adopted in Brazil and in several countries is that described in publication 151 of the National Council on Radiation Protection and Measurements (NCRP 151). This methodology however, markedly employs several approaches that can impact both in the construction cost and in the radiological safety of the facility. Although this methodology is currently well established by the high level of use, some parameters employed in the calculation methodology did not undergo to a detailed assessment to evaluate the impact of the various approaches considered. In this work the MCNP5 Monte Carlo code was used with the purpose of evaluating the above mentioned approaches. TVLs values were obtained for photons in conventional concrete (2.35g / cm{sup 3}), considering the energies of 6, 10 and 25 MeV, respectively, first considering an isotropic radiation source impinging perpendicular to the barriers, and subsequently a lead head shielding emitting a shaped beam, in the format of a pyramid trunk. Primary barriers safety margins, taking in account the head shielding emitting photon beam pyramid-shaped in the energies of 6, 10, 15 and 18 MeV were assessed. A study was conducted considering the attenuation provided by the patient's body in the energies of 6,10, 15 and 18 MeV, leading to new attenuation factors. Experimental measurements were performed in a real radiotherapy room, in order to map the leakage radiation emitted by the accelerator head shielding and the results obtained were employed in the Monte Carlo simulation, as well as to validate the entire study. The study results indicate that the TVLs values provided by (NCRP, 2005) show discrepancies in comparison with the values obtained by simulation and that there may be some barriers that are calculated with insufficient thickness. Furthermore, the simulation results show that the additional safety margins considered when calculating the width of the primary barrier of radiotherapy rooms are conservative. They also show that the attenuation provided by the patient's body decreases with increased energy, with the highest attenuation being 0.54, for the energy of 6 MeV. (author)

  4. Dosimetric implications associated to heterogeneity dose correction in stereotactic body radiation therapy (SBRT) of lung cancer; Implicaciones dosimetricas asociadas al calculo de dosis con correccion de heterogeneidad en radioterapia estereotaxica extracraneal (SBRT) de pulmon

    Energy Technology Data Exchange (ETDEWEB)

    Zucca Aparicio, D.; Perez Moreno, J. M.; Fernandez Leton, P.; Garcia Ruiz-Zorrila

    2016-10-01

    Treatment of lung lesions using stereotactic body radiation therapy (SBRT) requires algorithms with corrections that adequately model the behavior of narrow beams in the presence of tissue heterogeneities, although protocols such as RTOG 0236 excluded these kind of corrections. 100 cases were evaluated retrospectively following the RTOG 0813 and RTOG 0915 guidelines, by obtaining the deviations of the relevant dosimetric indicators from Monte Carlo (MC) and Pencil Beam (PB), maintaining the same configuration and monitor units (MU). Deviations between MC and PB have been classified according to the volume and density of the lesion. The greatest variations (up to 45% difference in D50%) are found for cases with lower volume and density, where the lesion is almost equivalent to lung tissue, given the higher proportion of air surrounding the periphery of the tumor, and the reduction of the radiation fields, resulting in a lack of electronic equilibrium that must be properly considered in the treatment planning system. These deviations involve dosimetric implications which are observable in clinical outcomes, determining how to proceed in treatment planning, to ensure that the actual dose delivered is performed accordingly to the prescription dose, while requiring the use of algorithms with a proper heterogeneity correction. (Author)

  5. REPERCUSION DEL USO DE LA PLATAFORMA VIRTUAL MATHXL EN EL RENDIMIENTO ACADEMICO DE LOS ALUMNOS EN EL CURSO CALCULO INTEGRAL DEL PROGRAMA PROFESIONAL INGENIERIA CIVIL DE LA UNIVERSIDAD CATOLICA DE SANTA MARIA DE AREQUIPA 2010-II Y 2011-II

    OpenAIRE

    SÁNCHEZ-MORENO MESTAS, MARTHA BEATRIZ

    2013-01-01

    EL APRENDIZAJE DEFINICIONES TIPOS DE APRENDIZAJE APRENDIZAJE POR ENSAYO Y ERROR TEORÍAS DEL APRENDIZAJE LAS ESTRATEGIAS DE APRENDIZAJE EL MODELO DE ENSEÑANZA-APRENDIZAJE EN LA UNIVERSIDAD LA ENSEÑANZA-APRENDIZAJE Y LOS ENTORNOS VIRTUALES EL AULA VIRTUAL DEFINICIÓN DE AULA VIRTUAL USOS DEL AULA VIRTUAL LA ENSEÑANZA VIRTUAL UNIVERSITARIA AMBIENTES HÍBRIDOS DE APRENDIZAJE PLATAFORMAS VIRTUALES DE APRENDIZAJE USO DE LAS PLATAFORMAS DE ENSEÑANZA VIRTUAL EN LA DOCENCIA UNIVERSITARIA VENTAJAS QUE LA...

  6. T.I.G. Welding of stainless steel. Numerical modelling for temperatures calculation in the Haz; Soldadura T.I.G. de acero inoxidable. Modelo numerico para el calculo de temperaturas en la ZAT

    Energy Technology Data Exchange (ETDEWEB)

    Martinez-Conesa, E. J.; Estrems-Amestoy, M.; Miguel-Eguia, V.; Garrido-Hernandez, A.; Guillen-Martinez, J. A.

    2010-07-01

    In this work, a numerical method for calculating the temperature field into the heat affected zone for butt welded joints is presented. The method has been developed for sheet welding and takes into account a bidimensional heat flow. It has built a computer program by MS-Excel books and Visual Basic for Applications (VBA). The model has been applied to the TIG process of AISI 304 stainless steel 2mm thickness sheet. The welding process has been considered without input materials. The numerical method may be used to help the designers to predict the temperature distribution in welded joints. (Author) 12 refs.

  7. Dose calculations for a simplified Mammosite system with the Monte Carlo Penelope and MCNPX simulation codes; Calculos de dosis para un sistema Mammosite simplificado con los codigos de simulacion Monte Carlo PENELOPE y MCNPX

    Energy Technology Data Exchange (ETDEWEB)

    Rojas C, E.L.; Varon T, C.F.; Pedraza N, R. [ININ, 52750 La Marquesa, Estado de Mexico (Mexico)]. e-mail: elrc@nuclear.inin.mx

    2007-07-01

    The treatment of the breast cancer at early stages is of vital importance. For that, most of the investigations are dedicated to the early detection of the suffering and their treatment. As investigation consequence and clinical practice, in 2002 it was developed in U.S.A. an irradiation system of high dose rate known as Mammosite. In this work we carry out dose calculations for a simplified Mammosite system with the Monte Carlo Penelope simulation code and MCNPX, varying the concentration of the contrast material that it is used in the one. (Author)

  8. Calculation of absorbed doses in sphere volumes around the Mammosite using the Monte Carlo simulation code MCNPX; Calculo de dosis absorbida en volumenes esfericos alrededor del Mammosite utilizando el codigo de simulacion Monte Carlo MCNPX

    Energy Technology Data Exchange (ETDEWEB)

    Rojas C, E. L. [ININ, Carretera Mexico-Toluca s/n, Ocoyoacac 52750, Estado de Mexico (Mexico)

    2008-07-01

    The objective of this study is to investigate the changes observed in the absorbed doses in mammary gland tissue when irradiated with a equipment of high dose rate known as Mammosite and introducing material resources contrary to the tissue that constitutes the mammary gland. The modeling study is performed with the code MCNPX, 2005 version, the equipment and the mammary gland and calculating the absorbed doses in tissue when introduced small volumes of air or calcium in the system. (Author)

  9. Criticality calculations of a generic fuel container for fuel assemblies PWR, by means of the code MCNP; Calculos de criticidad de un contenedor de combustible generico para ensambles combustibles PWR, mediante el codigo MCNP

    Energy Technology Data Exchange (ETDEWEB)

    Vargas E, S.; Esquivel E, J.; Ramirez S, J. R., E-mail: samuel.vargas@inin.gob.mx [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2013-10-15

    The purpose of the concept of burned consideration (Burn-up credit) is determining the capacity of the calculation codes, as well as of the nuclear data associates to predict the isotopic composition and the corresponding neutrons effective multiplication factor in a generic container of spent fuel during some time of relevant storage. The present work has as objective determining this capacity of the calculation code MCNP in the prediction of the neutrons effective multiplication factor for a fuel assemblies arrangement type PWR inside a container of generic storage. The calculations are divided in two parts, the first, in the decay calculations with specified nuclide concentrations by the reference for a pressure water reactor (PWR) with enriched fuel to 4.5% and a discharge burned of 50 GW d/Mtu. The second, in criticality calculations with isotopic compositions dependent of the time for actinides and important fission products, taking 30 time steps, for two actinide groups and fission products. (Author)

  10. Numerical Calculation of Transport Based on the Drift Kinetic Equation for plasmas in General Toroidal Magnetic Geometry; Calculo Numerico del Transporte mediante la Ecuacion Cinetica de Deriva para Plasmas en Geometria Magnetica Toroidal: Preliminares

    Energy Technology Data Exchange (ETDEWEB)

    Reynolds, J. M.; Lopez-Bruna, D.

    2009-12-11

    This report is the first of a series dedicated to the numerical calculation of the evolution of fusion plasmas in general toroidal geometry, including TJ-II plasmas. A kinetic treatment has been chosen: the evolution equation of the distribution function of one or several plasma species is solved in guiding center coordinates. The distribution function is written as a Maxwellian one modulated by polynomial series in the kinetic coordinates with no other approximations than those of the guiding center itself and the computation capabilities. The code allows also for the inclusion of the three-dimensional electrostatic potential in a self-consistent manner, but the initial objective has been set to solving only the neoclassical transport. A high order conservative method (Spectral Difference Method) has been chosen in order to discretized the equation for its numerical solution. In this first report, in addition to justifying the work, the evolution equation and its approximations are described, as well as the baseline of the numerical procedures. (Author) 28 refs.

  11. Numerical Calculation of Transport Based on the Drift-Kinetic Equation for Plasmas in General Toroidal Magnetic Geometry: Convergence and Testing; Calculo Numerico del Transporte mediante la Ecuacion Cinetica de Deriva para Plasmas en Geometria Magnetica Toroidal: Convergencia y Comprobaciones

    Energy Technology Data Exchange (ETDEWEB)

    Reynolds, J. M.; Lopez-Bruna, D.

    2009-12-11

    This report is the third of a series [Informes Tecnicos Ciemat 1165 y 1172] devoted to the development of a new numerical code to solve the guiding center equation for electrons and ions in toroidal plasmas. Two calculation meshes corresponding to axisymmetric tokamaks are now prepared and the kinetic equation is expanded so the standard terms of neoclassical theory --fi rst order terms in the Larmor radius expansion-- can be identified, restricting the calculations correspondingly. Using model density and temperature profiles for the plasma, several convergence test are performed depending on the calculation meshes and the expansions of the distribution function; then the results are compared with the theory [Hinton and Hazeltine, Rev. Mod. Phys. (1976)]. (Author) 18 refs.

  12. Calculation and analysis of hydrogen volume concentrations in the vent pipe rigid proposed for NPP-L V; Calculo y analisis de concentraciones volumetricas de hidrogeno en el tubo de venteo rigido propuesto para la CNLV

    Energy Technology Data Exchange (ETDEWEB)

    Gomez T, A. M.; Xolocostli M, V. [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico); Lopez M, R.; Filio L, C. [Comision Nacional de Seguridad Nuclear y Salvaguardias, Dr. Jose Ma. Barragan No. 779, Col. Narvarte, 03020 Mexico D. F. (Mexico); Royl, P., E-mail: armando.gomez@inin.gob.mx [Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz I, D-76344 Eggenstein-Leopoldshafen (Germany)

    2014-10-15

    In 2012 was modeled of primary and secondary container of the nuclear power plant of Laguna Verde (NPP-L V) for the CFD Gas-Flow code. These models were used to calculate hydrogen volume concentrations run release the reactor building in case of a severe accident. The results showed that the venting would produce detonation conditions in the venting level (level 33) and flammability at ground level of reload. One of the solutions to avoid reaching critical concentrations (flammable or detonable) inside the reactor building and thus safeguard the contentions is to make a rigid venting. The rigid vent is a pipe connected to the primary container could go to the level 33 of the secondary container and style fireplace climb to the top of the reactor building. The analysis of hydrogen transport inside the vent pipe can be influenced by various environmental criteria and factors vent, so a logical consequence of the 2012 analysis is the analysis of the gases transport within said pipe to define vent ideal conditions. For these evaluations the vent pipe was modeled with a fine mesh of 32 radial interior nodes and a coarse mesh of 4 radial interior nodes. With three-dimensional models were realized calculations that allow observing the influence of heat transfer in the long term, i.e. a complete analysis of exhaust (approx. 700 seconds). However, the most interesting results focus on the first milliseconds, when the H{sub 2} coming from the atmosphere of the primary container faces the air in the vent pipe. These first milliseconds besides allowing evaluating the detonation criteria in great detail in the different tubular sections similarly allow evaluating the pressure wave that occurs in the pipe and that at some point slows to the fluid on the last tubular section and could produce a detonation inside the pipe. Results are presented for venting fixed conditions, showing possible detonations into the pipe. (Author)

  13. Propositions of new correlations for prediction of physical-chemical properties in products of Brazilian crude oil; Proposicao de novas correlacoes para calculo de propriedades fisico-quimicas de derivados de petroleos brasileiros

    Energy Technology Data Exchange (ETDEWEB)

    Pinto, Ulysses Brandao [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2008-07-01

    The prediction of products properties is a useful tool in the petroleum industry, because it allows the estimation of quality when it is not possible to be determined it in the laboratory. Among existing correlations for properties prediction, the best known are those from the American Petroleum Institute (API), but there are limitations in the use of such models to estimate the properties of Brazilian petroleum products. A study was done to determine new correlations which would adjust to these oils. In this work a statistical treatment was used in a group of samples covering products from oils produced in several regions of Brazil. The results of this study are presented in this work. New correlations are proposed to estimate the aniline point, pour point and cloud point of Brazilian oil products. The data are showed graphically, with the experimental values plotted against the results of both the proposed and the API correlations. The average absolute deviations obtained for these correlations were smaller than those presented by the API equations, for the same data sets. This work helps to improve the quality estimation of Brazilian petroleum products using process simulators. (author)

  14. Preparation of a program for the independent verification of the brachytherapy planning systems calculations; Confeccion de un programa para la verificacion independiente de los calculos de los sistemas de planificacion en braquiterapia

    Energy Technology Data Exchange (ETDEWEB)

    V Carmona, V.; Perez-Calatayud, J.; Lliso, F.; Richart Sancho, J.; Ballester, F.; Pujades-Claumarchirant, M.C.; Munoz, M.

    2010-07-01

    In this work a program is presented that independently checks for each patient the treatment planning system calculations in low dose rate, high dose rate and pulsed dose rate brachytherapy. The treatment planning system output text files are automatically loaded in this program in order to get the source coordinates, the desired calculation point coordinates and the dwell times when it is the case. The source strength and the reference dates are introduced by the user. The program allows implementing the recommendations about independent verification of the clinical brachytherapy dosimetry in a simple and accurate way, in few minutes. (Author).

  15. Independent procedure of checking dose calculations using an independent calculus algorithm; Verificacion independiente de los parametros de planificacion, histogramas dosis volumen, y parametros radiobioligocs mediante el uso de una hoja de calculo automatizada

    Energy Technology Data Exchange (ETDEWEB)

    Perez Rozos, A.; Jerez Sainz, I.; Carrasco Rodriguez, J. L.

    2006-07-01

    In radiotherapy it is recommended the use of an independent procedure of checking dose calculations, in order to verify the main treatment planning system and double check every patient dosimetry. In this work we present and automatic spreadsheet that import data from planning system using IMPAC/RTP format and verify monitor unit calculation using an independent calculus algorithm. Additionally, it perform a personalized analysis of dose volume histograms and several radiobiological parameters like TCP and NTCP. Finally, the application automatically generate a clinical dosimetry report for every patient, including treatment fields, fractionation, independent check results, dose volume analysis, and first day forms. (Author)

  16. Verification of the calculation program for brachytherapy planning system of high dose rate (PLATO); Programa de verificacion del calculo para un sistema de planificacion de braquiterapia de alta tasa de dosis (PLATO)

    Energy Technology Data Exchange (ETDEWEB)

    Almansa, J.; Alaman, C.; Perez-Alija, J.; Herrero, C.; Real, R. del; Ososrio, J. L.

    2011-07-01

    In our treatments are performed brachytherapy high dose rate since 2007. The procedures performed include gynecological intracavitary treatment and interstitial. The treatments are performed with a source of Ir-192 activity between 5 and 10 Ci such that small variations in treatment times can cause damage to the patient. In addition the Royal Decree 1566/1998 on Quality Criteria in radiotherapy establishes the need to verify the monitor units or treatment time in radiotherapy and brachytherapy. All this justifies the existence of a redundant system for brachytherapy dose calculation that can reveal any abnormality is present.

  17. Verification of dosimetry planning in brachytherapy in format Dicom and EUD calculation of Risk in bodies; Verificacion de la planificacion dosimetria en braquiterapia en formato Dicom y calculo del EUD en organos de riesgo

    Energy Technology Data Exchange (ETDEWEB)

    Garcia Hernandez, M. J.; Sendon del Rio, J. R.; Ayala Lazaro, R.; Jimenez Rojas, M. R.; Gomez Cores, S.; Polo Cezon, R.; Lopez Bote, M. A.

    2013-07-01

    This work Describes a program that automates the verification of the schedules in brachytherapy (configuration and dosimetric treatment parameters) for sources of Ir-192 (mHDR v2) and Co-60 (Co0.A86) from the plan exported in DICOM format data. (Author)

  18. Application of shielding calculation of high-energy linear accelerators based on the NCRP-151 protocol; Aplicacion de calculo de blindajes de aceleradores lineales de alta energia basada en el protocolo NCRP-151

    Energy Technology Data Exchange (ETDEWEB)

    Torres Pozas, S.; Monja Rey, P. de la; Sanchez Carrasca, M.; Yanez Lopez, D.; Macias Verde, D.; Martin Oliva, R.

    2011-07-01

    In recent years, the progress experienced in cancer treatment with ionizing radiation can deliver higher doses to smaller volumes and better shaped, making it necessary to take into account new aspects in the calculation of structural barriers. Furthermore, given that forecasts suggest that in the near future will install a large number of accelerators, or existing ones modified, we believe a useful tool to estimate the thickness of the structural barriers of treatment rooms. The shielding calculation methods are based on standard DIN 6847-2 and the recommendations given by the NCRP 151. In our experience we found only estimates originated from the DIN. Therefore, we considered interesting to develop an application that incorporates the formulation suggested by the NCRP, together with previous work based on the rules DIN allow us to establish a comparison between the results of both methods. (Author)

  19. Marginal cost calculation of energy production in hydro thermoelectric systems considering the transmission system; Calculo do custo marginal de producao de energia em sistemas hidrotermoeletricos levando em consideracao a rede de transmissao

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, M V.F. [Pontificia Univ. Catolica do Rio de Janeiro, RJ (Brazil); Gorenstin, B G [Centro de Pesquisas de Energia Eletrica, Rio de Janeiro, RJ (Brazil); Alvarenga Filho, S [ELETROBRAS, Rio de Janeiro, RJ (Brazil)

    1990-12-31

    The alternatives for calculation of energy marginal cost in hydroelectric systems, considering the transmission one, was analysed, including fundamental concepts; generation/transmission systems, represented by linear power flow model; production marginal costs in hydrothermal systems and computation aspects. (C.G.C.). 11 refs, 5 figs.

  20. Calculation of the detection efficiency in liquid scintillators. II. Single positron emitters; Calculo de la eficiencia de deteccion en liquidos centelleadores. II Nucleidos que se desintegran por emision simple de positrones

    Energy Technology Data Exchange (ETDEWEB)

    Grau Malonda, A.; Garcia Torano, E.

    1982-07-01

    Counting efficiency as a function of the figure of merit for 30 positron emitters has been computed from the positron energy spectrum. Only the efficiency contribution of positrons has been taken into consideration. The contribution of the annihilation photons depending on the volume of the scintillator will be investigated in a near future. Efficiency vs figure of merit is plotted and tabulated. (Author) 19 refs.

  1. Determination of viscosity of fayalite slags for kv model and measurements by means of inclined plane; Estimacion de la viscosidad de escorias fayaliticas utilizando el modelo de calculo kv y el metodo experimental del plano inclinado

    Energy Technology Data Exchange (ETDEWEB)

    Bazan, V.; Goni, C.; Castella, L.; Brandaleze, E.; Verdeja, L. F.; Parra, R.

    2006-07-01

    The viscosity of the lands represents one of the most relevant variables of most of the processes metallurgical and kinetics of the refine operations, since it is one of the decisive factors of the efficiency in the reactions between metal and lag, as much as slag-refractory. In the last decades, the mathematical models of different metallurgical processes have established methods to predict viscosity of mixtures of oxides fused to high temperatures in function of the chemical composition. The model developed by Toguri, based on the data reported by Johasen and Winterhager et al has proposed the Kv model. The used index it is similar to the relationship used in the steel industry like the basicity index. It is presented in this work values determined of viscosity in experimental form by means of the technique of inclined plane. (Author)

  2. Analysis of a calculation method for the determination of the value of safety or control bars; Analisis de un metodo de calculo para la determinacion del valor de barras de seguridad o control

    Energy Technology Data Exchange (ETDEWEB)

    Aguilar H, F; Torres A, C; Filio L, C [ININ, Gcia. de Reactores, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    1982-09-15

    Due to the control or safety bars in a nuclear reactor are constituted by strongly absorbent materials, the Diffusion Theory like tool for the calculation of bar values is not directly applicable, should it use the Transport Theory. However the speed and economy of the Diffusion codes for the reactors calculation, those make attractiveness and by this reason its are used in the determination of characteristic parameters and even in the determination of bar values, not without before to make some theoretical developments that allow to make applicable this theory. The application of the Diffusion Theory in strongly absorbent media is based on the use of some effective cross sections distinct from the real ones obtained when imposing the reason that among the flow and it gradient in the external surface of such media (control element in general, bar type or flagstone) be similar to the one obtained using Transport Theory in all the control region (multiplicative and absorbent media) with those real cross sections. The effective cross sections were obtained of the Leopard-NUMICE cell code which has incorporate the respective calculation theory of effective cross sections. Later these constants its were used in the bidimensional diffusion code Exterminator-II, simulating in it, the distribution of safety or control bars. From the cell code its were also obtained the respective constants of the homogeneous fuel cell. The results as soon as those obtained bar values of the diffusion code, its were compared with some experimental results obtained in the R{phi} Swedish reactor of natural uranium and heavy water. In this work an analysis of the bar value of one of them, trying to determine the applicability of the method is made. (Author)

  3. Calculation of the detection efficiency in liquid scintillators. III. Single electron-capture radionuclides; Calculo de la eficiencia de deteccion en liquidos centelleadores. III. Nucleidos que se desintegran por captura electronica pura

    Energy Technology Data Exchange (ETDEWEB)

    Grau Malonda, A

    1982-07-01

    In this paper, counting efficiency vs figure of merit for 19 electron capture radionuclides has been computed. Toluene based s c i n t i l l a t o r solution of 15 cm{sup 3} has been assumed in the computation. The relationships to obtain the probability per decay are given and the computed efficiency tabulated.(Author)

  4. Calculations of Changes in Reactivity during some regular periods of operation of JEN-1 MOD Reactor; Calculo de vairaciones de reactividad en algunos periodos regulares de operacion del reactor JEN-1 Mod.

    Energy Technology Data Exchange (ETDEWEB)

    Alcala Ruiz, F

    1973-07-01

    By a Point-Reactor model and Perturbation Theory, changes in reactivity during some regular operating periods of JEN-1 MOD Reactor have been calculated and compared with available measured values. they were in good agreement. Also changes in reactivity have been calculated during operations at higher power levels than the present one, concluding some practical consequences for the case of increasing the present power of this reactor. (Author)

  5. Shields calculations for teletherapy equipment. Regulatory approach of the National Center of Nuclear Safety; Calculos de blindajes para equipos de teleterapia, enfoque regulatorio del Centro Nacional de Seguridad Nuclear

    Energy Technology Data Exchange (ETDEWEB)

    Fuente P, A. de la; Dumenigo G, C.; Quevedo G, J.R.; Lopez F, Y. [Centro Nacional de Seguridad Nuclear, Calle 28 No. 504 e/5 y 7 Ave. Miramar, Playa, Ciudad de la Habana (Cuba)]. e-mail: andres@orasen.co.cu

    2006-07-01

    The evaluation of applications of construction licenses for the new services of radiotherapy has occupied a significant space in the activity developed by the National Center of Nuclear Safety (CNSN) in the last 2 years. Presently work the experiences of the authors in the evaluation of the required shield for the local where cobalt therapy equipment and lineal accelerators of medical use are used its are exposed, the practical problems detected are approached during the application of the methodologies recommended in both cases and its are discussed which have been the suppositions of items accepted by the Regulatory Authority for the realization of these shield calculations. The accumulated experience allows to assure that the realistic application of the item data and the rational use of the engineering logic makes possible to design local for radiotherapy equipment that fulfill the established dose restrictions in the in use legislation in Cuba, without it implies an excessive expense of construction materials. (Author)

  6. Thermal calculations for the study of the heat evacuation in the vaults building of the centralised temporary storage (ATC); Calculos termicos para el estudio de la evacuacion de calor en el Edificio de Bovedas del Almacen Temporal Centralizado (ATC)

    Energy Technology Data Exchange (ETDEWEB)

    Perez Dominguez, J. R.; Garcia Gonzalez, M.; Huelamo, E.

    2015-07-01

    This article presents the thermal analyses of the vaults building at the future Spanish Nuclear Waste Storage facility (ATC) in which spent nuclear fuel and high activity nuclear wastes are to be stored efficiency, safety and securely. the analyses have been carried out by means of computational fluid dynamics (CFD) simulation codes, for the purpose of confirming the adequate design of the storage buildings and in order to obtain the air flow rate required to guarantee that the different thermal criteria are met. The design relies on natural convection in order to remove residual heat from the nuclear waste. The simulation model allows the designer to perform sensitivity analyses to evaluate the impact of different design parameters, to optimize the heat load per fuel canister and to provide an optimal loading plan for the facility. (Author)

  7. Criticality and shielding calculations for containers in dry of spent fuel of TRIGA Mark III reactor of ININ; Calculos de criticidad y blindaje para contenedores en seco de combustible gastado del reactor Triga Mark III del ININ

    Energy Technology Data Exchange (ETDEWEB)

    Barranco R, F.

    2015-07-01

    In this thesis criticality and shielding calculations to evaluate the design of a container of dry storage of spent nuclear fuel generated in research reactors were made. The design of such container was originally proposed by Argentina and Brazil, and the Instituto Nacional de Investigaciones Nucleares (ININ) of Mexico. Additionally, it is proposed to modify the design of this container to store spent fuel 120 that are currently in the pool of TRIGA Mark III reactor, the Nuclear Center of Mexico and calculations and analyzes are made to verify that the settlement of these fuel elements is subcritical limits and dose rates to workers and the general public are not exceeded. These calculations are part of the design criteria for security protection systems in dry storage system (Dss for its acronym in English) proposed by the Nuclear Regulatory Commission (NRC) of the United States. To carry out these calculations simulation codes of Monte Carlo particle transport as MCNPX and MCNP5 were used. The initial design (design 1) 78 intended to store spent fuel with a maximum of 115. The ININ has 120 fuel elements and spent 3 control rods (currently stored in the reactor pool). This leads to the construction of two containers of the original design, but for economic reasons was decided to modify (design 2) to store in a single container. Criticality calculations are performed to 78, 115 and fresh fuel elements 124 within the container, to the two arrangements described in Chapter 4, modeling the three-dimensional geometry assuming normal operating conditions and accident. These calculations are focused to demonstrate that the container will remain subcritical, that is, that the effective multiplication factor is less than 1, in particular not greater than 0.95 (as per specified by the NRC). Spent fuel 78 and 124 within the container, both gamma radiation to neutron shielding calculations for only two cases were simulated. First actinides and fission products generated during irradiation of fuels, with MCNPX, then these data were obtained and used for the simulation with MCNP5 using conversion factors creep dose rate. The need to store the spent fuel (outside the reactor pool) leads to the creation of an alternative for its management, and the idea is to propose and evaluate a dry storage container arises. (Author)

  8. Calculation of dose rate in escape channel of Research Irradiating Facility Army Technology Center using code MCNPX; Calculo das taxas de dose no canal de fuga do irradiador gama de pesquisa do Centro Tecnologico do Exercito utilizando o codigo MCNPX

    Energy Technology Data Exchange (ETDEWEB)

    Gomes, Renato G.; Rebello, Wilson F.; Vellozo, Sergio O.; Moreira Junior, Luis, E-mail: renatoguedes@ime.eb.br, E-mail: rebello@ime.eb.br, E-mail: eng.cavaliere@gmail.com, E-mail: vellozo@cbpf.br, E-mail: luisjrmoreira@hotmail.com [Instituto Militar de Engenharia (IME), Rio de Janeiro, RJ (Brazil); Vital, Helio C., E-mail: vital@ctex.eb.br [Centro Tecnologico do Exercito (CTEX), Barra de Guaratiba, RJ (Brazil); Rusin, Tiago, E-mail: tiago.rusin@mma.gov.br [Ministerio do Meio Ambiente (MMA), Brasilia, DF (Brazil); Silva, Ademir X., E-mail: ademir@con.ufrj.br [Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, RJ (Brazil)

    2013-07-01

    In order to evaluate new lines of research in the area of irradiation of materials external to the research irradiating facility Army Technology Center (CTEx), it is necessary to study security parameters and magnitude of the dose rates from their channels of escape. The objective was to calculate, with the code MCNPX, dose rates (Gy / min) on the interior and exterior of the four-channel leakage gamma irradiator. The channels were designed to leak radiation on materials properly disposed in the area outside the irradiator larger than the expected volume of irradiation chambers (50 liters). This study aims to assess the magnitude of dose rates within the channels, as well as calculate the angle of beam output range outside the channel for analysis as to its spread, and evaluation of safe conditions of their operators (protection radiological). The computer simulation was performed by distributing virtual dosimeter ferrous sulfate (Fricke) in the longitudinal axis of the vertical drain channels (anterior and posterior) and horizontal (top and bottom). The results showed a collimating the beams irradiated on each of the channels to the outside, with values of the order of tenths of Gy / min as compared to the maximum amount of operation of the irradiator chamber (33 Gy / min). The external beam irradiation in two vertical channels showed a distribution shaped 'trunk pyramid', not collimated, so scattered, opening angle 83 ° in the longitudinal direction and 88 in the transverse direction. Thus, the cases allowed the evaluation of materials for irradiation outside the radiator in terms of the magnitude of the dose rates and positioning of materials, and still be able to take the necessary care in mounting shield for radiation protection by operators, avoiding exposure to ionizing radiation. (author)

  9. DosedPet application for Nuclear Medicine: Calculation of the volume of medication needed for PET/CT patient; Aplicativo DosedPet para uso em Medicina Nuclear: calculo do volume de medicamento necessario para paciente de PET/CT

    Energy Technology Data Exchange (ETDEWEB)

    Nascimento, Pedro Augusto do; Rodrigues, Araken dos S. Werneck, E-mail: pedroan88@gmail.com [Universidade de Brasilia (UnB), DF (Brazil). Programa de Pos Graduacao em Ciencias e Tecnologias em Saude

    2016-07-01

    This paper presents the application (APP) DosePet that calculates the amount of medicament for PET / CT in patients according to the predetermined radiation dose. The software has been designed using the web MIT App Inventor2 tool for Android platform. The application allows the workers to simulate the amount of radiation still existing in the facilities after the applications, increasing security and reducing exposures, and enable greater efficiency in the use of the radiopharmaceutical. (author)

  10. Calculations of hydrogen transport for the simulation of a Sbo in the NPP-L V using the code CFD GASFLOW; Calculos de transporte de hidrogeno para la simulacion de un SBO en la CNLV usando el codigo CFD GASFLOW

    Energy Technology Data Exchange (ETDEWEB)

    Gomez T, A. M.; Xolocostli M, V. [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico); Lopez M, R.; Filio L, C.; Mugica R, C. A. [Comision Nacional de Seguridad Nuclear y Salvaguardias, Dr. Jose Ma. Barragan No. 779, Col. Narvarte, 03020 Mexico D. F. (Mexico); Royl, P., E-mail: armando.gomez@inin.gob.mx [Karlsruhe Institute of Technology, Consultor, Hermann-von-Helmholtz-Platz, D-76344 Eggenstein -Leopoldshafen, Karlsruhe (Germany)

    2013-10-15

    The scenario of electric power total loss in the nuclear power plant of Laguna Verde (NPP-L V) has been analyzed using the code MELCOR previously, until reaching fault conditions of the primary container. A mitigation measure to avoid the loss of the primary contention is the realization of a venting toward the secondary contention (reactor building), however this measure bears the potential explosions occurrence risk when the hydrogen accumulated in the primary container with the oxygen of the reactor building atmosphere reacting. In this work a scenario has been supposed that considers the mentioned venting when the pressure of 4.5 kg/cm{sup 2} is reached in the primary container. The information for the hydrogen like an entrance fact is obtained of the MELCOR results and the hydrogen transport in both contentions is analyzed with the code CFD GASFLOW that allows predicting the detailed distribution of the hydrogen volumetric concentration and the possible detonation of flammability conditions in the reactor building. The results show that the venting will produce detonation conditions in the venting level (level 33) and flammability in the level of the recharge floor. The methodology here described constitutes the base of a detailed calculation system of this type of phenomena that can use to make safety evaluations in the NPP-L V on scenarios that include gases transport. (Author)

  11. Calculation of uncertainties associated to environmental radioactivity measurements and their functions. Practical Procedure; Calculo de la incertidumbre asociada al recuento en medidas de radiactividad ambiental y funciones basadas en ella. Procedimiento practico

    Energy Technology Data Exchange (ETDEWEB)

    Gasco Leonarte, C; Anton Mateos, M. P.

    1995-07-01

    This report summarizes the procedure used to calculate the uncertainties associated to environmental radioactivity measurements, focusing on those obtained by radiochemical separation in which tracers have been added. Uncertainties linked to activity concentration calculations, isotopic rat iso, inventories, sequential leaching data, chronology dating by using C.R.S. model and duplicate analysis are described in detail. The objective of this article is to serve as a guide to people not familiarized with this kind of calculations, showing clear practical examples. The input of the formulas and all the data needed to achieve these calculations into the Lotus 1, 2, 3 WTN is outlined as well. (Author) 13 refs.

  12. Calculation of uncertainties in the protocol of dosimetry for Co 60 beams in Radiotherapy; Calculo de incertidumbres en el protocolo de dosimetria para haces de Co 60 en Radioterapia

    Energy Technology Data Exchange (ETDEWEB)

    Velazquez M, S.; Carrera M, F.; Sanchez S, J. [Hospital Juan Ramon Jimenez, Ronda Norte s/n 21005 Huelva (Spain)

    1998-12-31

    The objective in this work is to show how the uncertainty is possible to know in the determination of the absorbed dose in Co 60 photon beams and to establish in a rational form, tolerance levels for this. It is took as base the spanish protocol of dosimetry in Radiotherapy. We have been centered in a Co 60 beam. We utilized the statistical theory of little samples. We allowed to suggest a new approach about the treatment of the tolerance levels and the uncertainty of the measurement. After two years of experience in the practical hospitable application we have gotten to put around 1 % uncertainty in the absolute dosimetry of the Co 60 beam. The presented protocol allows to execute the accuracy requirements in the determination of absorbed doses. (Author)

  13. Evaluation of dose calculation algorithms using the treatment planning system XiO with tissue heterogeneity correction turned on; Validacao dos algoritmos de calculo de dose do sistema de planejamento XiO considerando as correcoes para heterogeneidade dos tecidos

    Energy Technology Data Exchange (ETDEWEB)

    Fairbanks, L.R.; Barbi, G.L.; Silva, W.T. da; Reis, E.G.F. dos; Borges, L.F.; Bertucci, E.C.; Maciel, M.F.; Amaral, L.L. do, E-mail: lefairbanks@yahoo.com.b [Universidade de Sao Paulo (USP), Ribeirao Preto, SP (Brazil). Hospital das Clinicas. Servico de Radioterapia

    2010-07-01

    Since the cross-section for various radiation interactions is dependent upon tissue material, the presence of heterogeneities affects the final dose delivered. This paper aims to analyze how different treatment planning algorithms (Fast Fourier Transform, Convolution, Superposition, Fast Superposition and Clarkson) work when heterogeneity corrections are used. To that end, a farmer-type ionization chamber was positioned reproducibly (during the time of CT as well as irradiation) inside several phantoms made of aluminum, bone, cork and solid water slabs. The percent difference between the dose measured and calculated by the various algorithms was less than 5%; This is in accordance with the recommendation of several references.The convolution method shows better results for high density materials (difference {approx}1 %), whereas the Superposition algorithm is more accurate for low densities (around 1,1%).

  14. Evaluation of dose calculation algorithms using the treatment planning system Xi O with tissue heterogeneity correction turned on; Validacao dos algoritmos de calculo de dose do sistema de planejamento Xi O considerando as correcoes para heterogeneidade dos tecidos

    Energy Technology Data Exchange (ETDEWEB)

    Fairbanks, Leandro R.; Barbi, Gustavo L.; Silva, Wiliam T.; Reis, Eduardo G.F.; Borges, Leandro F.; Bertucci, Edenyse C.; Maciel, Marina F.; Amaral, Leonardo L., E-mail: lefairbanks@yahoo.com.b [Universidade de Sao Paulo (HCRP/USP), Ribeirao Preto, SP (Brazil). Hospital das Clinicas. Servico de Radioterapia

    2011-07-01

    Since the cross-section for various radiation interactions is dependent upon tissue material, the presence of heterogeneities affects the final dose delivered. This paper aims to analyze how different treatment planning algorithms (Fast Fourier Transform, Convolution, Superposition, Fast Superposition and Clarkson) work when heterogeneity corrections are used. To that end, a farmer-type ionization chamber was positioned reproducibly (during the time of CT as well as irradiation) inside several phantoms made of aluminum, bone, cork and solid water slabs. The percent difference between the dose measured and calculated by the various algorithms was less than 5%.The convolution method shows better results for high density materials (difference {approx}1 %), whereas the Superposition algorithm is more accurate for low densities (around 1,1%). (author)

  15. On the implementation of new versions of the algorithms of calculation of dose absorbed in radiotherapy external; Sobre la implementacion de nuevas versiones de los algoritmos de calculo de dosis absorbida en radioterapia externa

    Energy Technology Data Exchange (ETDEWEB)

    Latorre-Musoll, A.; Carrasco de Fez, P.; Lizondo Gisbert, M.; Jordi-Ollero, O.; Jornet Sala, N.; Eudaldo Puell, T.; Ruiz Martinez, A.; Ribas Morales, M.

    2015-07-01

    The changes of version of the algorithms of calculation of dose absorbed in radiotherapy external should implement in a time reduced due to the pressure care. A set reduced of checks could pass by high discrepancies significant between the stones and the measures experimental, as illustrate in this work. (Author)

  16. Application of perturbation theory to sensitivity calculations of PWR type reactor cores using the two-channel model; Aplicacao da teoria de perturbacao para calculos de sensibilidade em nucleos de reatores PWR, usando um modelo de dois canais

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, A.C.J.G. de

    1988-12-01

    Sensitivity calculations are very important in design and safety of nuclear reactor cores. Large codes with a great number of physical considerations have been used to perform sensitivity studies. However, these codes need long computation time involving high costs. The perturbation theory has constituted an efficient and economical method to perform sensitivity analysis. The present work is an application of the perturbation theory (matricial formalism) to a simplified model of DNB (Departure from Nucleate Boiling) analysis to perform sensitivity calculations in PWR cores. Expressions to calculate the sensitivity coefficients of enthalpy and coolant velocity with respect to coolant density and hot channel area were developed from the proposed model. The CASNUR.FOR code to evaluate these sensitivity coefficients was written in Fortran. The comparison between results obtained from the matricial formalism of perturbation theory with those obtained directly from the proposed model makes evident the efficiency and potentiality of this perturbation method for nuclear reactor cores sensitivity calculations (author). 23 refs, 4 figs, 7 tabs.

  17. Calculation of the detection efficiency in liquid scintillators. I.- Single negatrons emitters; Calculo de la eficiencia de deteccion en liquidos centelleadores. I. Nucleidos que se desintegran por emision simple de negatrones

    Energy Technology Data Exchange (ETDEWEB)

    Grau Malonda, A.; Garcia-torano, E.

    1981-07-01

    Counting efficiency for 62 single beta emitters has been computed from the beta energy distribution, the figure of merit and the ionization quenching. Efficiency v.s. figure of merit is plotted and tabulated. (Author) 16 refs.

  18. Hydrodynamic calculation of a filter sand bed type used in the containment venting systems; Calculo hidrodinamico de un filtro tipo lecho de arena usado en los sistemas de venteo de la contencion

    Energy Technology Data Exchange (ETDEWEB)

    Cuevas V, D.; Sainz M, E.; Ortiz V, J., E-mail: delfy.cu@gmail.com [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2015-09-15

    The filtered venting of the containment has been adopted in European countries to mitigate the consequences of excess pressure containment during a severe accident. When venting has taken place, the fission products are released directly into the environment, unless a filter on the same path is placed, so that various types of filters are used to trap the fission products. The venting filters of the containment currently installed use different filtration technologies that involve more than one medium. Those using water as the first stage of filtration are called wet systems and are equipped with additional steps to remove water drops and fine aerosols emissions. And even they may also be equipped with an element containing certain absorption means for the filtration of gaseous iodine species. Other designs based on filtration of deep bed as the primary retention step; called dry filters, use filtration media of metal fiber, ceramic or sand to trap aerosols. This paper evaluates the hydraulic characteristics of the filter sand bed type designed by EDF as a candidate to be installed in the containment of BWR Mark II (type of primary containment of the nuclear power plant of Laguna Verde). The evaluation of filter sand bed type was performed using the software package of open source OpenFOAM. Models of each zone of the filtered device were generated and through a series of parametric calculations of computational fluid mechanics relevant hydrodynamic characteristics of the device were obtained, such as pressure drops against mass flow rate and pressure fields and speed at different operating conditions. On the other hand, the model validation of the sand bed filter when comparing the results of experimental tests on a sand column of PITEAS program (1985-1986) against OpenFOAM simulation was realized. The results are very close to those obtained experimentally. (Author)

  19. Hydrodynamic calculation of a filter washing in liquids type used in containment venting systems; Calculo hidrodinamico de un filtro tipo lavado en liquidos usados en los sistemas de venteo de la contencion

    Energy Technology Data Exchange (ETDEWEB)

    Reyes G, A. A.; Sainz M, E.; Ortiz V, J., E-mail: alejandroantonioreyess@gmail.com [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2015-09-15

    From the nuclear accident of Chernobyl, the European nuclear power plants have chosen to install filters on the venting pipes of the containment, whose function is to help to mitigate the consequences of a severe accident, by controlled depressurization of the containment passively through a filtered venting of the containment system. These systems are designed to relieve the internal pressure of the containment by means of the deliberate opening of pressure relief devices, either a valve or rupture disc during a severe accident and be channeled to the filter unit. In this paper the hydraulic response of a filter system of gases washing by liquid is evaluated, due to this information is necessary to estimate the effect that has the pressure increase of the contention on the discharge capacity of the venting pipes. By simulation of computational of fluid dynamics with the programs: CAELINUX-2014 and OpenFOAM, the hydrodynamic characteristics of the Multi Venturi System for gases washing from the containment, which could be included in the general model of the venting pipe, were obtained. Representative models of the Venturi tubes of each concentric area that forming the washing system were generated; and using parametric calculations the average mass flow rate established through each venturi, depending on its size and depth in which it is located inside the tank was estimated. Also, the pressure and mass flow rate required to activate each concentric area depending on the pressure and mass load from the containment were calculated, to estimate the maximum flow that is established through the filter. Finally, the velocity profiles and the characteristic pressure at which each area operates as well as the pressure drop of local and global discharge also were calculated. (Author)

  20. Methodology for calculating the thickness free of sigma phase in duplex stainless steels large section parts during hiperquenching; Metodologia para el calculo de espesores limite libres de fase sigma durante el hipertemple en piezas de aceros duplex de gran seccion

    Energy Technology Data Exchange (ETDEWEB)

    Jimbert, P.; Guraya, T.; Torregary, A.; Bravo, P.

    2013-06-01

    To achieve the mechanical properties and corrosion resistance desired by duplex stainless steels used by the petrochemical and nuclear industry, parts are subjected to a hiperquenching heat treatment from about 1050 degree centigrade. This avoids the risk of intermetallic precipitation which drastically reduces the properties of these materials. However with increasing depth to which the deposits are present, the thicknesses for such pipes have been increased, resulting in higher levels of demand on all its manufacturing process, including the heat treatment. To avoid the precipitation of intermetallic phases such as sigma phase it is necessary to know the cooling profile in the center of the work piece and for this purpose to know the value of the Surface Heat Transfer Coefficient (h) is essential. This coefficient changes during the hiperquenching and its value is determined experimentally as it depends on several process parameters. Studies reveal that its value is stabilized within a few seconds. We can then assume that to know the cooling profile in the center of large sections it is only necessary to know the stabilized value of h. However, all the studies found in the literature are referred to diameters smaller than 100 mm. This paper has developed a methodology to predict the precipitation of intermetallic phases in duplex stainless steel parts with large thicknesses in industrial facilities from the calculation of h. This methodology allows us to calculate the cooling profiles without wasting any work piece using one or more sensorized patterns with thermocouples and a subsequent simulation with ANSYS. (Author)

  1. Simulation model and methodology for calculating the damage by internal radiation in a PWR reactor; Modelo de simulacion y metodologia para el calculo del dano por irradiacion en los internos de un reactor PWR

    Energy Technology Data Exchange (ETDEWEB)

    Cadenas Mendicoa, A. M.; Benito Hernandez, M.; Barreira Pereira, P.

    2012-07-01

    This study involves the development of the methodology and three-dimensional models to estimate the damage to the vessel internals of a commercial PWR reactor from irradiation history of operating cycles.

  2. Calculations of received dose for different points in the enrichment uranium oxide warehouse at 4%; Calculos de dosis recibida para diferentes puntos en el almacen de oxido de uranio enriquecido al 4%

    Energy Technology Data Exchange (ETDEWEB)

    Alonso V, G. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    1990-06-15

    In order to verifying that the received dose so much inside as outside of the warehouse of enriched uranium dioxide to 4% it doesn't represent risk to the personnel, the modelling of this and the corresponding calculations for the extreme case of dose at contact are made. (Author)

  3. Validation and calculation of uncertainties of the method of determination of creatinine in urine in internal dosimetry; Validacion y calculo de incertidumbres del metodo de determinacion de creatinina en orina en dosimetria interna

    Energy Technology Data Exchange (ETDEWEB)

    Sierra Barcedo, I.; Hernandez Gonzalez, C.; Benito Alonso, P.; Lopez Zarza, C.

    2011-07-01

    This paper describes the methodology used to conduct the validation of the quantification technique of content by spectrophotometry creatinine in urine samples of exposed workers at risk of internal counter and the study of all sources uncertainty that influence in the process. This technique is used to carry out the normalization of the amount of urine to urinary 24h, necessary for dosimetric purposes, as well as a criterion for acceptance of rejection of urine specimens received by the laboratory.

  4. Calculation of voltage drop during motors startup: power flow calculation by using the direct method; Calculo da queda de tensao na partida de motores: metodo direto do fluxo de potencia

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Monaco [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    1998-07-01

    In this paper, is presented a new theoretical approach developed in order to determine by direct method, non iterative, the load flow among the N bus bar of a generic power system. This method has been used to, from a single line simplified system of a typical industrial substation, used in the petroleum and by products storage and transportation facilities, calculate the voltage drops at bus bars and motors terminals from starting of the electric motors, after defining active and reactive power expressions flowing among bus bars, as a function of their voltages, impedance of connecting cables and of the loads connected to them. (author)

  5. Dancoff factors with partial neutrons absorption in cluster geometry by the direct method; Calculo dos fatores de Dancoff com absorcao parcial de neutrons em geometria cluster pelo metodo direto

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, Leticia Jenisch

    2007-07-01

    Accurate analysis of resonance absorption in heterogeneous systems is essential in problems like criticality, breeding ratios and fuel depletion calculations. In compact arrays of fuel rods, resonance absorption is strongly affected by the Dancoff factor, defined in mis study as the probability that a neutron emitted from the surface of a fuel element, enters another fuel element without any collusion in the moderator or cladding. In fact, in the most practical cases of irregular cells, it is observed that inaccuracies in computing both Grey and Black Dancoff factors, i.e. for partially and perfectly absorbing fuel rods, can lead to considerable errors in the calculated values of such integral quantities. For this reason, much effort has been made in the past decades to further improve the models for calculating Dancoff factors, a task that has been accomplished in connection with the development of faster computers. In the WIMS code, Black Dancoff factors based on the above mentioned collusion probability definition are computed in cluster geometry, for each one of the symmetrically distinct fuel pin positions in the cell. Sets of equally-spaced parallel lines are drawn in subroutine PIJ, at a number of discrete equally-incremented azimuthal angles, covering the whole system and forming a mesh over which the in-plane integrations of the Bickley functions are carried out by simple trapezoidal rule, leading to the first-flight collusion matrices. Although fast, the method in PIJ is inefficient, since the constructed mesh does not depended on the system details, so that regions of small relative volumes are crossed out by relatively few lines, which affects the convergence of the calculated probabilities. A new routine (PIJM) was then created to incorporate a more efficient integration scheme considering each system region individually, minimizing convergence problems and reducing the number of neutron track lines required in the in-plane integrations for any given accuracy. In this routine, the radial integrations are performed by Gauss' formula whereas the angular ones are obtained by extended trapezoidal rule. In the present work, PIJM is extended to compute Grey Dancoff factors by the collision probability definition, in two-dimensional cylindrical cells in cluster geometry. The vi effectiveness of the method is accessed by comparing Grey Dancoff factors as calculated by PIJM, with those available in the literature by the Monte Carlo method, for the irregular geometries of the Canadian CANDU 37 assembly. Dancoff factors at five symmetrically distinct fuel pin positions are found in very good agreement with the literature results. (author)

  6. Neutronic, thermal-hydraulics and safety calculations of a Miniplate Irradiation Device (MID) of dispersion type fuel elements; Calculos neutronicos, termo-hidraulicos e de seguranca de um dispositivo para Irradiacao de miniplacas (DIM) de elementos combustiveis tipo dispersao

    Energy Technology Data Exchange (ETDEWEB)

    Domingos, Douglas Borges

    2010-07-01

    Neutronic, thermal-hydraulics and accident analysis calculations were developed to estimate the safety of a Miniplate Irradiation Device (MID) to be placed in the IEA-R1 reactor core. The irradiation device is used to receive miniplates of U{sub 3}O{sub 8}-Al and U{sub 3}Si{sub 2}- Al dispersion fuels, LEU type (19.75 % {sup 235}U) with uranium densities of, respectively, 3.2 gU/cm{sup 3} and 4.8 gU/cm{sup 3}. The fuel miniplates will be irradiated to nominal {sup 235}U burnup levels of 50% and 80%, in order to qualify the above high-density dispersion fuels to be used in the Brazilian Multipurpose Reactor (RMB), now in the conception phase. For the neutronic calculation, the computer codes CITATION and 2DB were utilized. The computer code FLOW was used to calculate the coolant flow rate in the irradiation device, allowing the determination of the fuel miniplate temperatures with the computer model MTRCR-IEA-R1. A postulated Loss of Coolant Accident (LOCA) was analyzed with the computer codes LOSS and TEMPLOCA, allowing the calculation of the fuel miniplate temperatures after the reactor pool draining. The calculations showed that the irradiation should occur without adverse consequences in the IEA-R1 reactor. (author)

  7. Aplicação de metodos de otimização para o calculo do equilibrio quimico e de fases combinados para processos com gas de sintese

    OpenAIRE

    Consuelo Cristina Gomes Silva

    2008-01-01

    Resumo: Essa pesquisa consiste em aplicar métodos de otimização global para o cálculo do equilíbrio químico e de fases combinados para misturas com gás de síntese. O gás de síntese tem grande interesse industrial, pelas inúmeras possibilidades de produção de diversos compostos químicos. Dessa forma, é fundamental conhecer as condições termodinâmicas que favoreçam a obtenção de determinado produto. A aplicação de métodos de otimização global é de grande interesse para a determinação do equilíb...

  8. Dosimetric calculation of I-131 activity for the treatment to patients having differentiated thyroid cancer. Benefits and limitations; Calculo dosimetrico de la actividad de I-131 para tratamiento de pacientes con cancer diferenciado de tiroides (CADT). Beneficios y limitaciones

    Energy Technology Data Exchange (ETDEWEB)

    Cabrejas, R. C.; Chebel, G. M.; Fadel, A. M.; Rojo, A. M.; Deluca, G.; Degross, O. J.; Valdivieso, C. M.; Carbejas, M. L.

    2006-07-01

    Maximum safe activity calculation, that has to be administered for treatment to patients having Differentiated Thyroid Cancer (CADT). No important side effects should be produced. Post treatment evolution was analysed. 23 Dosimetric studies were performed determining blood and whole body uptake curves (CE)during 5 days. Using the MIRDOSE software, the maximum safe activity in the whole body (CE)was calculated. The retained activity in the body (AR), 48 hs. post tracer dose. Should have been less than 2.96 GBq so as to avoid lung fibrosis. 17 patients that received activities<11.1 GBq, had no side effects. Three patients presents special situations: high AR, users in the mouth, and plaque to and leucopenia. This methodology has benefits because AT can be estimated. This was possible for 85% of the patients. When AR was high at 48 hr, AT was diminished to avoid pulmonary lesions. Tumor absorbed dose estimation, will allow the administration of AT>11.1 GBq in the future. (Author)

  9. Development of a computer software based on geographic information for calculating voltage drop and brake points in half tension networks; Desarrollo informatico georreferenciado para calculos de caida de tension y puntos de corte en redes de media tension

    Energy Technology Data Exchange (ETDEWEB)

    Bertole, Hector; Aguero, Carlos A.; Prado, Pedro O.; Suarez, Juan A. [Universidad Nacional de Mar del Plata, Buenos Aires (Argentina). Facultad de Ingenieria

    1997-12-31

    This development is a group of tools of calculations and analysis thought to be used in the technical area of an electric power company. It allows the realization of calculations of voltage drop in the networks of half tension and the determination of the break points. It is possible to analyze the readiness of power in the distribution centers and the state of load of the conductors. (author) 8 refs., 7 figs.; e-mail: hbertole at fi.mdp.edu.ar; poprado at fi.mdp.edu.ar

  10. Correction of the calculation of the ultimate strength of studs shear connectors in solid slab composite section; Correccion del calculo de la capacidad resistente ultima de conectadores tipo perno de estructuras mixtas en la tipologia de viga-losa maciza

    Energy Technology Data Exchange (ETDEWEB)

    Bonilla Rocha, J. D.; Larrua Quevedo, R.; Recarey Morfa, C. A.; Mirambell Arrizabalaga, E.

    2009-07-01

    In this work is studied starting from the numeric simulation with previous calibration and validation, the behavior of studs shear connectors of composite structures of concrete and steel formed by beam sections and solid slab of concrete, subjected to flexion under loads static. In such a sense it is carried out a parametric study that allows to value the influence of the different factors that intervene in the behavior of the connection and allow to establish the variables of the proposed formulation, obtaining a procedure enough easy and practical. Finally a new formulation the one is achieved which supposes a significant advances with regard to the existent ones in the main ones normative international: AISC-LRFD (2005), Eurocode 4 (IN-1994-1-1:2004), as well as the normative cuban NR 080-2004, when taking in consideration in the expression new factors, redounding in a bigger in the presage of the ultimate strength capacity. (Author) 22 refs.

  11. Calculation of the electronic and magnetic structures of 3d impurities in the Hcp Fe matrix; Calculo da estrutura eletronica e magnetica de impurezas 3d na matriz do Fe HCP

    Energy Technology Data Exchange (ETDEWEB)

    Franca, Fernando

    1995-12-31

    In this work we investigate the local magnetic properties and the electronic structure of HCP Fe, as well introducing transition metals atoms 3d (Cs, Ti, Cr, Mn, Co, Ni, Cu, Zn) in HCP iron matrix. We employed the discrete variational method (DVM), which is an orbital molecular method which incorporate the Hartree-Fock-Slater theory and the linear combination of atomic orbitals (LCAO), in the self-consistent charge approximation and the local density approximation of Von Barth and Hedin to the exchange-correlation potential. We used the embedded cluster model to investigate the electronic structure and the local magnetic properties for the central atom of a cluster of 27 atoms immersed in the microcrystal representing the HCP Fe. (author) 32 refs., 19 figs., 2 tabs.

  12. Standardization of a method to calculate absolute renal uptake of {sup 99m} Tc-DMSA in children; Padronizacao do metodo para calculo da captacao renal absoluta do {sup 99m}Tc-DMSA em criancas

    Energy Technology Data Exchange (ETDEWEB)

    Ono, Carla Rachel; Sapienza, Marcelo Tatit; Watanabe, Tomoco; Costa, Paulo Luiz Aguirre; Okamoto, Miriam Roseli Yoshie; Garcez, Alexandre Teles; Buchpiguel, Carlos Alberto [Sao Paulo Univ., SP (Brazil). Hospital das Clinicas. Servico de Medicina Nuclear]. E-mail: crachelo@usp.br; Machado, Beatriz Marcondes; Machado, Marcia Melo Campos [Paulo Univ., SP (Brazil). Faculdade de Medicina. Hospital Universitario; Liberato Junior, Waldyr de Paula

    2006-01-15

    Objective:To standardize a method and determine normal values for absolute renal uptake of 99m Tc-DMSA in children with normal creatinine clearance. Materials and methods: Twenty-two children (between 7 months and 10 years of age; mean 4.5 years) without clinical evidence of renal disease were studied using 99m Tc-DMSA scintigraphy. Eighteen had normal renal ultrasonography, micturating urethrocystography, creatinine clearance and visual interpretation of the scintigraphy with 99m Tc-DMSA. Four children were excluded, one with incomplete creatinine clearance and three due to reduction in the creatinine clearance. Absolute renal uptake of 99m Tc-DMSA (DMSA-Abs) was expressed as the fraction of the administered dose retained by each kidney six hours after administration of the radiopharmaceutical. Results: DMSA-Abs was 21.8 +- 3.2% for the right kidney and 23.1 +-3.3% for the left kidney. There was no correlation between renal uptake and the age groups studied, although there was a tendency to an increase in the creatinine clearance with age. Conclusion: Normal values of DMSA-Abs can be used as an additional parameter for the initial diagnostic evaluation and during follow-up of renal diseases, mainly when bilateral impairment of renal function is suspected or in a patient with a single functioning kidney (in which renal differential function is of limited value). (author)

  13. Evolution calculations of fuel for a GFR using MCNPX-C90 and Tripoli-4-D; Calculos de evolucion de combustible para un GFR usando MCNPX-C90 y TRIPOLI-4-D

    Energy Technology Data Exchange (ETDEWEB)

    Reyes R, R.; Martin del Campo M, C.; Francois L, J. L. [UNAM, Facultad de Ingenieria, Departamento de Sistemas Energeticos, Paseo Cuauhnahuac 8532, 62550 Jiutepec, Morelos (Mexico); Brun, E.; Dumonteil, E.; Malvagi, F., E-mail: emeric.brun@cea.fr [Commissariat a l' Energie Atomique et aux Energies Alternative, Service d' Etude des Reacteurs et de Mathematiques Appliquees, Saclay, DEN/DM2S/SERMA/LTSD, Bat 470, 91191 Gif-sur-Yvette Cedex (France)

    2011-11-15

    Burnt calculations were realized for a fuel model based on the technology of the Gas-cooled Fast Reactor, GFR. The fuel design is based on bars. The code MCNPX-CINDER90 and the CSADA method for the burnt calculations were used. Models of homogeneous and heterogeneous fuel assembly were studied; for the burnt calculations of the fuel homogeneous model was considered the tracking of three series (Tiers) of evolution of the fission products. The Tier 1 tracks a reduced group of fission products, the Tier 2 tracks to the arrangement of fission products that are contained in the library of cross sections XSDIR of MCNPX; and the Tier 3 tracks 1325 fission products. The results were compared with those obtained with Tripoli-4-D in function of the calculation methods: 1) Explicit Euler, as method of first order; and 2) CSADA, as method of second order. According to the results was observed that the infinite multiplication factor varies in function of the fission products quantity that are tracked. The calculation time used by MCNPX-C90 with the series Tier 3 is more than double than the used by Tripoli-4-D, therefore this last code has advantage over MCNPX-C90 in the case of neutrons analysis of fast reactors. (Author)

  14. A combination between the differential and the perturbation theory methods for calculating sensitivity coefficients; Uma combinacao entre os metodos diferencial e da teoria de pertubacao para o calculo dos coeficientes de sensibilidade

    Energy Technology Data Exchange (ETDEWEB)

    Borges, Antonio Andrade

    1998-07-01

    A new method for the calculation of sensitivity coefficients is developed. The new method is a combination of two methodologies used for calculating theses coefficients, which are the differential and the generalized perturbation theory methods. The method utilizes as integral parameter the average flux in an arbitrary region of the system. Thus, the sensitivity coefficient contains only the component corresponding to the neutron flux. To obtain the new sensitivity coefficient, the derivatives of the integral parameter, {phi}, with respect to {sigma} are calculated using the perturbation method and the functional derivatives of this generic integral parameter with respect to {sigma} and {phi} are calculated using the differential method. (author)

  15. Aquelarre. A computer code for fast neutron cross sections from the statistical model; AQUELARRE. Un programa numerico para el calculo de secciones eficaces neutronicas mediante el modelo de nucleo compuesto

    Energy Technology Data Exchange (ETDEWEB)

    Guasp, J

    1974-07-01

    A Fortran V computer code for Univac 1108/6 using the partial statistical (or compound nucleus) model is described. The code calculates fast neutron cross sections for the (n, n'), (n, p), (n, d) and (n, {alpha}) reactions and the angular distributions and Legendre moments for the (n, n) and (n, n') processes in heavy and intermediate spherical nuclei. A local Optical Model with spin-orbit interaction for each level is employed, allowing for the width fluctuation and Moldauer corrections, as well as the inclusion of discrete and continuous levels. (Author) 67 refs.

  16. The ion exchange and its connection the industry II.- Calculation methods for installations; El cambio de ion y su relacion con la industria II.- Metodos de calculo de instalaciones

    Energy Technology Data Exchange (ETDEWEB)

    Uriarte Hueda, A; Lopez Perez, B; Gutierrez Jodra, L

    1960-07-01

    An exposure is made of calculation methods for ion exchange installations based on kinetic considerations and similarity with other unitary operations. Factors to be experimentally obtained as well as difficulties which may occur in its determination are also given. Calculation procedures most commonly used in industry are enclosed and explained with numerical resolution of a problem of water demineralization. (Author) 22 refs.

  17. Detection efficiency for radionuclides decaying by electron capture and gamma-Ray; Calculo de la eficiencia de deteccion de nucleidos que se desintegran por captura elec- tronica y emision gamma

    Energy Technology Data Exchange (ETDEWEB)

    Grau, A; Fernandez, A

    1985-07-01

    In this paper, the electron capture partial counting efficiency vs the figure of merit for electron-capture and gamma-ray emitters has been computed. The radionuclides tabulated are 48{sup c}r, 54{sup M}n, 57{sup C}o 56{sup N}i, 72{sup S}e, 73{sup A}s, 85{sup S}r, 88{sup Z}r, 92{sup N}b, 103{sup P}d, 111{sup l}n, 119{sup S}b, 125{sup I}, 139{sup C}e and 152{sup D}y. It has been assumed that the liquid is a toluene based scintillator solution in standard glass vials containing 15 cm{sup 3}. (Author) 17 refs.

  18. Use of Monte Carlo simulation software for the calculation of the effective dose in cone beam Tomography; Uso del software de simulacion Monte Carlo para el calculo de la dosis efectiva en Tomografia de haz conico

    Energy Technology Data Exchange (ETDEWEB)

    Gomes B, W. O., E-mail: wilsonottobatista@gmail.com [Instituto Federal da Bahia, Rua Emidio dos Santos s/n, Bardalho, 40301-015 Salvador, Bahia (Brazil)

    2015-10-15

    Full text: In this study irradiation geometry applicable to PCXMC and the consequent calculation of effective dose in applications of cone beam computed tomography (CBCT) was developed. Two different CBCT equipment s for dental applications were evaluated: Care Stream Cs-9000 3-Dimensional and Gendex GXCB-500 tomographs. Each protocol initially was characterized by measuring the surface kerma input and the product air kerma-area, P{sub KA}. Then, technical parameters of each of the predetermined protocols and geometric conditions in the PCXMC software were introduced to obtain the values of effective dose. The calculated effective dose is within the range of 9.0 to 15.7 μSv for Cs 9000 3-D and in the range 44.5 to 89 mSv for GXCB-500 equipment. These values were compared with dosimetric results obtained using thermoluminescent dosimeters implanted in anthropomorphic mannequin and were considered consistent. The effective dose results are very sensitive to the radiation geometry (beam position); this represents a factor of fragility software usage, but on the other hand, turns out to be a very useful tool for quick conclusions regarding the optimization process of protocols. We can conclude that the use of Monte Carlo simulation software PCXMC is useful in the evaluation of test protocols of CBCT in dental applications. (Author)

  19. Calculation of the neutron flux and fluence in the covering of the nucleus and the vessel of a BWR; Calculo del flujo neutronico y fluencia en la envolvente del nucleo y la vasija de un reactor nuclear BWR

    Energy Technology Data Exchange (ETDEWEB)

    Martinez C, E.; Del Valle G, E. [IPN, Escuela Superior de Fisica y Matematicas, U. P. Adolfo Lopez Mateos, Col. Lindavista, 07738 Mexico D. F. (Mexico); Longoria G, L. C., E-mail: evalle@esfm.ipn.mx [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2011-11-15

    One of the main objectives related with the safety in any nuclear power plant, including the nuclear power plant of Laguna Verde, is to guarantee the structural integrity of the pressure vessel of the reactor. To identify and quantifying the damage caused be neutron irradiation in the vessel of any nuclear reactor, is necessary to know as much the neutron flux as the fluence that it has been receiving during their time of operation life, since the observables damages by means of tests mechanics are products of micro-structural effects, induced by neutron irradiation, therefore, is important the study and prediction of the neutron flux to have a better knowledge of the damage that are receiving these materials. In our calculation the code DORT was used, which solves the transport equation in discreet coordinates and in two dimensions (x-y, r-{theta} and r-z), in accord to the regulator guide, it requires to make and approach of the neutron flux in three dimensions by means of the Synthesis Method. Whit this method is possible to achieve a representation of the flux in 3D combining or synthesizing the calculated fluxes by DORT code in r-{theta}, r-z and r. In this work the application of the Synthesis Method is presented, according to the Regulator Guide 1.190, to determine the fluxes 3D in the interns of a BWR using three different space meshes. (Author)

  20. Ações de enfermagem em nefrologia: um referencial expandido além da concepção biologicista de saúde Acciones de enfermería en nefrología: un referencial teorico difundido además de la concepción biologicista de salud Nursing actions in nephrology: a theoretical referral expanded beyond the biologicist health conception

    Directory of Open Access Journals (Sweden)

    Mercedes Trentini

    2005-08-01

    Full Text Available Este artigo focaliza modos de atuação da enfermagem em nefrologia nos programas de promoção de saúde. Para tanto, apresentamos um referencial teórico formado pelos conceitos de promoção da saúde, educação em saúde e tecnologias. A concepção de promoção da saúde está ancorada nos documentos da Primeira Conferência Internacional sobre o tema, realizada em Ottawa, Canadá em 1986. A educação em saúde está alicerçada no paradigma do "empowerment", visto como um processo de ação social que promove participação das pessoas no controle sobre suas vidas e saúde. O conceito de tecnologias está apresentado de acordo com a concepção de Merhy, que as classifica em tecnologias duras, leve-duras e leves. Este referencial, certamente, representará um novo desafio para enfermeiras/enfermeiros de nefrologia.Enfoca modos de actuación de la enfermería en nefrología en los proyectos de promoción de salud. Presentamos un referencial formado por los conceptos de promoción de la salud, educación en salud y tecnologías. La concepción de promoción está apoyada en la Carta de Ottawa, 1986. la educación en salud está basada en el paradigma del "empowerment", visto como un proceso de acción social que promoví participación de las personas en el control sobre sus vidas. El concepto de tecnologías está presentado en conformidad con la concepción de Merhy que las clasifica en tecnologías "duras, livianas-duras y livianas". Este referencial, representará un nuevo desafío para la enfermería de nefrología.This article focuses ways of nursing performance in nephrology in the health promotion programs. Therefore, we present a theoretical referral formed by concepts of health promotion, health education and technologies. The conception of health promotion is anchored in the First International Conference documents about the subject, which took place in Ottawa, Canada in 1986. Health education is based on the empowerment paradigm, seen as a social action process that promotes people's participation in controlling their lives and health. The concept of technologies is presented in accordance with Merhy's conception, classifying them as hard technologies, light-hard and light ones. This referral will surely represent a new challenge for nurses in nephrology.

  1. Chemical Effects of Nuclear Recoil in Organic Halide Systems: A New Theoretical Treatment and Experimental Verification of the Theory; Effets Chimiques du Recul Nucleaire dans des Systemes Organiques Halogenes: Nouveau Traitement Theorique et Verification Experimentale de la Theorie; Khimicheskie vozdejstviya yadernoj otdachi v organicheskikh galoidnykh sistemakh: novoe teoreticheskoe tolkovanie i ehksperimental'noe podtverzhdenie teorii; Efectos Quimicos del Retroceso Nuclear en Sistemas de Haluros Organicos: Nuevo Tratamiento Teorico y Verificacion Experimental de la Teoria

    Energy Technology Data Exchange (ETDEWEB)

    Kontis, S. S.; Sanitwongs, P.; Weston, M. [Londonderry Laboratory for Radiochemistry, University of Durham, Durham (United Kingdom)

    1965-04-15

    Methods have been developed for calculating the organic retention of radiohalogen to be expected following neutron activation of mixtures of two organic halides and the corresponding free halogen. The methods are based on the concepts of the Libby ''billiard-ball'' process of hot-atom labelling and retentions are expressed in terms of two types of parameters: (1) the fractional chance that collision of a hot radiohalogen atom with a particular molecule will lead to retention of the hot atom in that molecule; (2) the upper and lower energy limits for what is termed a hot bromine atom. It is shown how the former type of parameter may be derived from experiments with binary mixtures of an organic halide and the corresponding free halogen: the second type of parameter must be deduced from nuclear and chemical data. These methods have been tested by studies on the systems C{sub 2}H{sub 5}Br/CCl{sub 4}/Br{sub 2} and C{sub 2}H{sub 5}Br/C{sub 6}H{sub 5}Br/Br{sub 2}. The calculated retentions (using parameters derived from studies of the systems C{sub 2}H{sub 5}Br/Br{sub 2}, CCl{sub 4}/Br{sub 2} and C{sub 6}H{sub 5}Br/Br{sub 2}) are in good agreement with those found experimentally in mixtures with a bromine mole-fraction greater than about 0.1. It is therefore considered that the Libby mechanism is adequate to explain the observed organic retentions in such mixtures. As the bromine mole-fraction is reduced, below 0.1 the observed retentions become progressively higher than calculated values. This is attributed to there being additional modes of hot-atom labelling which become operative when the bromine concentration is not high enough to give adequate radical scavenging. (author) [French] Lesauteuts ont mis au point des methodes pour calculer la retention organique du radiohalogene a laquelle on peut s'attendre apres activation par les neutrons de melanges de deux halogenures organiques et de l'halogene libre correspondant. Ces methodes sont basees sur les principes du mecanisme de la 'boule de billard' pour le marquage par l'atome chaud, auquel Libby a donne son nom, et les retentions sont exprimees en fonction de deux types de parametres, savoir: 1. la probabilite que le choc entre un atome chaud de radiohalogene et une molecule donnee determine la retention de l'atome chaud dans cette molecule; 2. les limites superieure et inferieure des energies pour lesquelles un atome de brome est dit chaud. Les auteurs montrent comment le premier type de parametre peut etre derive d'experiences sur des melanges binaires d'un halogenure organique et de l'halogene libre correspondant; le second type de parametre doit etre deduit des constantes nucleaires et chimiques. Des etudes sur les systemes C{sub 2}H{sub 5}Br/CCl{sub 4}/Br{sub 2} et C{sub 2}H{sub 5}Br/C{sub 6}H{sub 5}Br/Br{sub 2} ont permis de faire l'essai de ces methodes. Les valeurs de retention calculees (en Utilisant des parametres derives d'etudes des systemes C{sub 2}H{sub 5}Br/Br{sub 2}, CCl{sub 4}/Br{sub 2} et C{sub 6}H{sub 5}Br/Br{sub 2}) concordent avec celles qui sont determinees experimentalement dans des melanges ou la fraction molaire de brome est superieure a 0,1 environ. Par consequent, les auteurs considerent que le mecanisme Libby permet d'expliquer les retentions organiques observees dans ces melanges. Lorsque la fraction molaire de brome devient inferieure a 0,1, les retentions observees augmentent progressivement par rapport aux valeurs calculees, ce qui est sans doute du au fait que d'autres modes de marquage par l'atome chaud interviennent lorsque la concentration en brome n'est pas assez elevee pour assurer un bon 'balayage' des radicaux. (author) [Spanish] Los autores elaboraron metodos para calcular la probable retencion organica de los halogenos radiactivos despues de activar con neutrones mezclas de dos haluros organicos y el correspondiente halogeno libre; Los metodos se basan en la teoria del proceso de ' bolas de billar ' de Hbby para la marcacion con atomos calientes; la retencion se expresa en funcion de dos tipos de parametros, a saber: 1) la probabilidad relativa de que ei choque de un atomo caliente de halogeno radiactivo con una molecula determinada produzca la retencion del atomo caliente en dicha molecula; 2) los limites energeticos superior e inferior dentro de los cuales el atomo de bromo puede considerarse caliente. Los autores demuestran como el primer tipo de parametro puede deducirse experimentalmente de mezclas binarias de un haluro organico y el correspondiente halogeno libre; el segundo tipo de parametro debe deducirse a partir de datos nucleares quimicos. Dichos metodos han sido ensayados en los sistemas C{sub 2}H{sub 5}Br/CCl{sub 4}/Br{sub 2} and C{sub 2}H{sub 5}Br/C{sub 6}H{sub 5}Br/Br{sub 2}. Los valores calculados para las retenciones (empleando parametros derivados del estudio de los sistemas C{sub 2}H{sub 5}Br/Br{sub 2}, CCl{sub 4}/Br{sub 2} and C{sub 6}H{sub 5}Br/Br{sub 2})) eoncuerdan satisfactoriamente con los dalos hallados experimentalmeme en mezclas cuya fraccion molar de bromo es superior a 0,1. De esta manera se considera que el mecanismo propuesto por Libby permite explicar las retenciones organicas observadas en dichas mezclas. Cuando la fraccion molar de bromo se va reduciendo a valores inferiores a 0,1, las retenciones observadas se hacen progresivamente mayores que los valores calculados. Este fenomeno se atribuye a la existencia de otros modos de marcacion con atomos calientes, que entran en juego cuando la concentracion de bromo no es bastante elevada para eliminar adecuadamente los radicales en virtud de mecanismos de depuracion. (author) [Russian] Byli razrabotany metody rascheta organicheskogo uderzhanija radiogalogenov, kotorye mozhno ozhidat' vsledstvie nejtronnoj aktivacii smesej dvuh organicheskih galoidov i sootvetstvujushhih svobodnyh galogenov. Jeti metody osnovany na koncepcijah processa ''bil'jardnogo shara'' Libbi po mecheniju gorjachih atomov, i uderzhanija vyrazhajutsja v vide dvuh tipov parametrov, a imenno: 1) frakcionnaja vozmozhnost' togo, chto stolknovenie gorjachego atoma radioaktivnogo galogena s kakoj-to opredelennoj molekuloj privedet k uderzhaniju gorjachego atoma v toj molekule; 2) verhnie i nizhnie predely jenergij dlja tak nazyvaemogo gorjachego atoma broma. Pokazyvaetsja, kak pervyj tip parametra mozhet byt' vyveden iz jeksperimentov s binarnymi smesjami organicheskogo galoidnogo soedinenija i sootvetstvujushhego svobodnogo galogena: vtoroj tip parametra dolzhen vyvodit'sja iz jadernyh i himicheskih dannyh. Jeti metody proverjalis' s pomoshh'ju issledovanij na sistemah C{sub 2}H{sub 5}Br/CCl{sub 4}/Br{sub 2} i C{sub 2}H{sub 5}Br/C{sub 6}H{sub 5}Br/Br{sub 2}. Vychislennye uderzhanija (s ispol'zovaniem parametrov, vyvedennyh iz issledovanij sistem C{sub 2}H{sub 5}Br/Br{sub 2}, CCl{sub 4}/Br{sub 2} i C{sub 6}H{sub 5}Br/Br{sub 2}) horosho soglasujutsja s uderzhanijami, najdennymi jeksperimental'no v smesjah s frakciej grammolekuly broma bol'she 0,1. Takim obrazom, polagajut, chto mehanizm Libbi javljaetsja podhodjashhim dlja ob'jasnenija nabljudaemyh organicheskih uderzhanij v takih smesjah. Esli frakcija grammolekuly broma opuskaetsja nizhe OD, nabljudaemye uderzhanija stanovjatsja v progressivnoj stepeni vyshe, chem rasschitannye velichiny. Jeto ob{sup j}asnjaetsja dopolnitel'nymi vidami mecheni* gorjachih atomov, kotorye stanovjatsja dejstvujushhimi, esli koncentracija broma ne javljaetsja dostatochno vysokoj, chtoby dat' sootvetstvujushhuju ochistku radikala. (author)

  2. Theoretical and Experimental Aspects of Quenching Variables from Biomedical Samples in Liquid Scintillator Systems; Aspects Theoriques et Experimentaux des Parametres d'Extinction Etudies sur des Echantillons Biomedicaux dans des Systemes a Scintillateur Liquide; Teoreticheskie i ehksperimental'nye aspekty peremennykh gasheniya iz biomeditsinskikh prob v zhidkikh stsintillyatsionnykh sistemakh; Estudio Teorico y Experimental de las Variables de Extincion en el Recuento de Sustancias Biological por Centelleo Liquido

    Energy Technology Data Exchange (ETDEWEB)

    Ross, H. H. [Oak Ridge National Laboratory, Oak Ridge, TN (United States)

    1965-10-15

    Until recently, it has not been possible to separate the individual quenching variables in liquid scintillator systems. Although conventional methods for quench correction enable the determination of the total quenching in a particular sample, the absolute contribution of colour and fluorescence quenching cannot be determined. This information is of great importance in the design of new and more efficient scintillator systems and in the critical evaluation of older systems for possible improvements. Two independent methods have been developed recently by the author to evaluate the individual quenching variables in liquid systems. The first method shows that a general mathematical model can be used to accurately predict the degree of colour quenching in any given sample using spectrophotometric data. This treatment is analogous to one for the total light absorption of a multicomponent system and finally results in an integral equation of the type Q = {integral}{sup {lambda}{sub n{sub {lambda}{sub {sub l}}}}} (K)(A)d{lambda}, which can be easily simplified for use. This technique is capable of giving accurate information for evaluating the combined effects of colour and fluorescence quenching and gives a good deal of insight into the exact factors that cause colour quenching. However, a worker faced with large numbers of routine samples will find the experimental procedure somewhat tedious. A second study describes a new experimental technique of colour-quench correction using an ''isolated internal standard''. Using this technique, in conjunction with any of the other methods for total quench correction, the separate effects of colour and chemical quenching are easily resolved. The isolated internal standard technique is based on the absorption of light photons in a colour-quenched liquid scintillator sample. However, in contrast to the above spectrophotometric method, the light source consists of a small ampoule containing an unquenched liquid scintillator spiked with the desired isotope. The photons emitted by the standard have the same fluorescence intensity and spectral distribution as those produced in the sample itself. After construction, the isolated internal standard is immersed in a pure liquid scintillator solution and counted. A second count is made with the standard immersed in a sample that exhibits colour quenching. The ratio of these two counts is a measure of the colour quenching in the sample and is unaffected by the presence of fluorescence quenching species. Because this method is straightforward in principle and easy to use, it is ideally suited to routine investigations. The individual quenching effects of various sample systems were evaluated by both correction methods. Specially prepared solutions of dyes and samples of urine, blood, and liver tissue were studied extensively. The results show that the agreement between the two methods is excellent. Also, the quenching effects of most of the urine, blood and liver samples could be determined to {+-}3%. (author) [French] Pendant tres longtemps il a ete impossible de separer les parametres d'extinction dans les systemes a scintillation liquide. Certes, les methodes classiques de correction permettent de determiner l'extinction totale dans un echantillon donne, mais il est impossible de determiner separement l'extinction de la couleur et celle de la fluorescence. Or, ces donnees seraient precieuses pour la conception d'ensembles a scintillation nouveaux et plus perfectionnes et pour l'evaluation critique des appareils actuels en vue de leur amelioration. L'auteur a mis au point deux methodes distinctes pour evaluer separement les parametres d'extinction dans les systemes liquides. La premiere methode permet d'utiliser un modele mathematique general pour predire avec precision le degre d'extinction chromatique dans tout echantillon, en partant de donnees spectro- photometriques. Ce traitement est analogue a celui que l'on utilise pour determiner l'absorption totale de lumiere dans un systeme a plusieurs composants; il aboutit finalement a une integrale du type: Q = {integral}{sup {lambda}{sub n{sub {lambda}{sub {sub l}}}}} (K)(A)d{lambda}, qui peut etre facilement simplifiee dans ses applications. Cette methode peut fournir des renseignements precis pour evaluer les effets combines de l'extinction de la couleur et de la fluorescence, et permet d'obtenir bon nombre d'indications sur les causes de l'extinction chromatique. Toutefois, le chercheur qui a normalement un grand nombre d'echantillons a etudier trouvera cette methode experimentale assez fastidieuse. La seconde methode est une nouvelle methode experimentale de correction d'extinction chromatique a l'aide d'un 'etalon interne isole'. En conjuguant cette methode avec d'autres methodes de correction totale, on peut facilement determiner separement les effets de l'extinction chromatique et de l'extinction chimique. La methode de l'etalon interne isole est fondee sur l'absorption des photons dans un echantillon de scintilla- teur liquide a extinction chromatique. Contrairement a la methode spectrophotometrique decrite plus haut, la source lumineuse est constituee cette fois par une petite ampoule contenant un scintillateur liquide sans extinction auquel est ajoute le radioisotope voulu. Les photons emis par l'etalon ont la meme intensite de fluorescence et le meme spectre que ceux que produit l'echantillon lui-meme. L'etalon interne isole, une fois constitue, est plonge dans une solution de scintillateur liquide pur et on procede au comptage. On effectue un deuxieme comptage avec l'etalon plonge dans un echantillon qui accuse une extinction chromatique. Le rapport entre le nombre de coups ainsi trouve donne la mesure de l'extinction chromatique de l'echantillon, l'extinction de la fluorescence n'ayant aucune influence. Cette methode, fondee sur un principe tres simple et d'un emploi facile, convient parfaitement pour les etudes courantes. L'auteur a evalue les effets d'extinction de diverses series d'echantillons en appliquant successivement les deux methodes de correction exposees. Il a etudie des solutions speciales de teintures, ainsi que des echantillons d'urine, de sang et de tissu hepatique. La concordance entre les deux methodes apparait excellente. En outre, l'effet d'extinction de la plupart des echantillons d'urine, de sang et de tissu hepatique peut etre determine avec une precision de {+-}3%. (author) [Spanish] Hasta hace poco no habia sido posible aislar cada una de las variables de extincion en sistemas de centelleador liquido. Si bien los metodos clasicos de correccion permiten determinar la extincion total en una muestra determinada, es imposible establecer la contribucion absoluta de la extincion cromatica y de la extincion de fluorescencia. Pero esta informacion es de gran importancia para el diseno de nuevos sistemas de centelleador mas eficientes y para la evaluacion critica de sistemas mas antiguos con la finalidad de perfeccionarlos. El autor ha elaborado recientemente dos metodos independientes para evaluar las diferentes variables de extincion en los sistemas liquidos. En virtud del primero, se demuestra que puede utilizarse un modelo matematico general para predecir con precision el grado extincion cromatica en una muestra determinada basandose en datos espectrofotometricos. Este procedimiento es analogo al que se aplica para la absorcion total de la luz en un sistema de varios componentes y da como resultado una ecuacion integral del tipo Q = {integral}{sup {lambda}{sub n{sub {lambda}{sub {sub l}}}}} (K)(A)d{lambda}, que puede simplificarse facilmente para su aplicacion practica. Esta tecnica permite obtener datos precisos para evaluar los efectos combinados de la extincion cromatica de fluorescencia, y proporciona amplios conocimientos sobre los factores que determinan la extincion cromatica. Sin embargo, un investigador que corrientemente haya de examinar grandes cantidades de muestras encontrara un tanto tedioso este procedimiento. El autor describe asimismo una nueva tecnica experimental de correccion por extincion cromatica utilizando un 'patron interno aislado'. Aplicando esta tecnica, junto con cualquiera de los otros metodos de correccion de la extincion total, se determinan sin dificultad los efectos separados de la extincion cromatica y de la extincion quimica. La tecnica de empleo del patron interno aislado se basa en la absorcion de fotones en una muestra de centelleador liquido con extincion cromatica. Sin embargo, a diferencia del metodo espectrofotometrico antes citado, la fuente de luz consiste en una pequena ampolla que contiene un centelleador liquido sin extintor adicionado del isotopo deseado. Los fotones emitidos por el patron tienen la misma intensidad de fluorescencia y distribucion espectral que los producidos en la muestra. Una vez preparado, el patron se sumerge en una solucion de centelleador liquido puro y se recuenta. Se procede a un segundo recuento con el patron sumergido en una muestra con extincion cromatica. La razon de estos dos recuentos constituye una medida de la extincion cromatica en la muestra y no es afectada por la presencia de especies extintoras de la fluorescencia. Este metodo, por la sencillez de sus principios y su facilidad de aplicacion, se presta muy bien para las investigaciones corrientes. Se han evaluado, utilizando ambos metodos de correccion, los efectos individuales de extincion en varios tipos de muestras. Se han estudiado detalladamente soluciones especiales de colorantes y muestras de orina, sangre y tejido hepatico. Los resultados indican que la concordancia entre los dos metodos es excelente. Asimismo, los efectos de extincion de la mayor parte de las muestras de orina, sangre y tejido hepatico se han determinado con una precision de {+-}3%. (author) [Russian] Do nedavnego vremeni ne predstavljalos' vozmozhnym opoznavat' individual'nye peremennye gashenija v zhidkih scintilljacionnyh sistemah. Hotja obychnye metody popravki na gashenie dajut vozmozhnost' opredeljat' obshhuju velichinu gashenija v dannoj probe, ne predstavljaetsja vozmozhnym opredeljat' absoljutnuju dolju uchastija v gashenii okraski i fluorescencii. Jeti svedenija predstavljajut bol'shoe znachenie dlja konstrukcii novyh i bolee jeffektivnyh scintilljacionnyh sistem, a takzhe dlja kriticheskoj ocenki bolee staryh sistem s cel'ju vnesenija vozmozhnyh uluchshenij. Nedavno avtoru doklada udalos' vyrabotat' dva nezavisimyh metoda dlja opredelenija, otdel'nyh vyzyvajushhih gashenie peremennyh v zhidkih sistemah. Pervyj metod pokazyvaet, chto na osnovanii spektrofotometricheskih dannyh predstavljaetsja vozmozhnym ispol'zovat' obshhuju matematicheskuju model' dlja tochnogo predskazanija stepeni obescvechivanija v ljuboj probe. Jetot podhod analogichen metodu opredelenija obshhego pogloshhenija sveta v mnogokomponentnoj sisteme, i on privodit v konechnom schete k integral'nomu uravneniju tipa: Q = {integral}{sup {lambda}{sub n{sub {lambda}{sub {sub l}}}}} (K)(A)d{lambda}, kotoroe dlja prakticheskih nadobnostej mozhno legko uprostit'. Jetot metod mozhet davat' tochnye svedenija dlja ocenki kombinirovannogo vozdejstvija gashenija okraski i fluorescencii i vmeste s tem sposobstvovat' luchshemu ponimaniju faktorov, vyzyvajushhih obescvechivanie. Odnako pri neobhodimosti analizirovat' povsednevno bol'shoe kolichestvo prob jeksperimental'naja procedura stanovitsja dovol'no trudoemkoj. Vtoroj metod - novyj jeksperimental'nyj metod vnesenija popravki na gashenie okraski putem ispol'zovanija {sup i}zolirovannogo vnutrennego standarta{sup .} Primenjaja jetot metod s ljubymi drugimi metodami opredelenija obshhej popravki na gashenie, mozhno legko otdelit' vozdejstvie gashenija okraski ot himicheskogo gashenija. Metod izolirovannogo vnutrennego standarta osnovan na pogloshhenii svetovyh fotonov v probe zhidkogo scintilljatora s gashenoj okraskoj. Odnako v protivopolozhnost' opisannomu vyshe spektrofotometricheskomu metodu istochnik sveta sostoit iz nebol'shoj ampuly, soderzhashhej negashenuju scintilljacionnuju zhidkost' s dobavkoj zhelatel'nogo radioizotopa. Fotony, izluchaemye jetim standartom, obladajut takoj zhe intensivnost'ju fluorescencii i imejut takoe zhe spektral'noe raspredelenie, kak fotony, poluchaemye v samoj probe. Posle izgotovlenija izolirovannyj vnutrennij standart pogruzhajut v chistyj zhidkij scintilljacionnyj rastvor i podvergajut schetu. Vtoroj schet proizvodjat so standartom, pogruzhennym v probu, kotoraja projavljaet obescvechivanie. Otnoshenie odnogo scheta k drugomu javljaetsja meroj gashenija okraski v probe i ne zavisit ot veshhestv, vyzyvajushhih gashenie fluorescencii. Blagodarja prostote i praktichnosti jetot metod goditsja dlja povsednevnyh issledovanij. Oba metoda vnesenija popravok ispol'zovali dlja opredelenija gasjashhego vozdejstvija v sistemah razlichnyh prob. Shiroko izuchali osobo izgotovlennye rastvory krasok i proby mochi, krovi i tkani pecheni. Rezul'taty ukazyvajut na velikolepnoe sovpadenie pokazanij oboih metodov. Gasjashhee vozdejstvie bol'shej chasti prob mochi, krovi i pecheni mozhno opredelit' s tochnost'ju do {+-}3%. (author)

  3. Use of the Neutron Die-Away Technique to Test Control Rod Effectiveness Theories; Emploi de la Methode d'Absorption des Neutrons pour Verifier les Theories sur l'Efficacite des Barres de Commande; Ispol'zovanie metoda spada potoka nejtronov dlya proverki teorij ehffektivnosti reguliruyushchikh sterzhnej; Aplicacion de la Tecnica de Extincion Neutronica a la Verificacion de las Teorias sobre la Eficacia de las Barras de Control

    Energy Technology Data Exchange (ETDEWEB)

    Perez, R. B. [University of Florida, Gainesville, FL (United States); De Saussure, G.; Silver, E. G. [University of Florida, Gainesville, FL (United States); Oak Ridge National Laboratory, Oak Ridge, TN (United States)

    1964-04-15

    . Les theories, qui ont ete verifiees sont celles de: 1. Nordheim-Scalettar, 2. Hurwitz-Roe, 3. et celle du code de diffusion numerique. Les auteurs ont calcule l'effet des barres cruciformes a l'aide de la methode de transformation conforme de Hurwitz-Roe et ont trouve pour le laplacien la valeur de 0,0188 cm{sup -2} qui est voisine du resultat de l'experience, 0,0187 {+-} 0,0006 cm-2. Pour les barres epaisses, les previsions de la theorie de Nordheim-Scallettar et de la theorie du code de diffusion depassent les resultats experimentaux d'environ lOyeo. Les deux methodes ont toutefois etabli des previsions correctes en ce qui concerne l'interaction entre les barres epaisses. Pour les barres minces, la methode Nordheim-Scalettar est extremement precise. On peut s'attendre a trouver l'ecart constate pour les barres epaisses, lorsqu'on utilise la theorie de diffusion pour calculer l'effet des barres ayant une section de dimensions comparables a celle du libre parcours moyen des neutrons dans le ralentisseur. On procede actuellement a des mesures avec des banes de dimensions intermediaires pour determiner le point a partir duquel la theorie de la diffusion n'est plus valable. (author) [Spanish] El calculo de la eficacia de las barras de control se complica por el hecho de que esta depende a la vez de la distribucion de las energias neutronicas y de la geometria del conjunto. Cuando se trata de comparar los datos teoricos con los resultados experimentales obtenidos en otros reactores o en sistemas subcriticos, surgen dificultades derivadas de la complejidad intrinseca de tales sistemas. La tecnica de la extincion neutronica brinda la posibilidad de establecer un modelo neutronico integramente termico, en el cual el efecto de la distribucion de energias neutronicas se puede separar de los efectos espaciales. Por lo tanto, es dable estudiar el factor geometrico de la eficacia de las barras de control sin reparar en las caracteristicas del espectro neutronico y luego es

  4. Argilas como catalisadores verdes na esterificação do colesterol: caracterização espectroscópica e identificação de polimorfos por métodos de análise térmica. Uma proposta laboratorial interdisciplinar para o 1º ciclo universitário Clays as green catalysts in the cholesterol esterification: spectroscopic characterization and polymorphs identification by thermal analysis methods. An interdisciplinary laboratorial proposal for the undergraduate level

    Directory of Open Access Journals (Sweden)

    Teresa M. R. Maria

    2009-01-01

    Full Text Available A laboratory experiment that enables the professor to introduce the problematic of sustainable development in pharmaceutical chemistry to undergraduate students is proposed, using a simple synthetic procedure. Cholesteryl acetate is prepared by the esterification of cholesterol using Montmorillonite K10 as heterogeneous catalyst. Cholesterol and cholesteryl acetate are characterized by spectroscopic (¹H RMN, 13C RMN, FTIR and thermal analysis techniques. The thermal methods are used to introduce the concepts of polymorphism and the nature of mesophases.

  5. Acute and long term outcomes of catheter ablation using remote magnetic navigation for the treatment of electrical storm in patients with severe ischemic heart failure

    DEFF Research Database (Denmark)

    Jin, Qi; Jacobsen, Peter Karl; Pehrson, Steen

    2015-01-01

    BACKGROUND: Catheter ablation with remote magnetic navigation (RMN) can offer some advantages compared to manual techniques. However, the relevant clinical evidence for how RMN-guided ablation affects electrical storm (ES) due to ventricular tachycardia (VT) in patients with severe ischemic heart......-guided catheter ablation can prevent VT recurrence and significantly reduce ICD shocks, suggesting that this strategy can be used as an alternative therapy for VT storm in SIHF patients with ICDs....

  6. Clays as green catalysts in the cholesterol esterification: spectroscopic characterization and polymorphs identification by thermal analysis methods. An interdisciplinary laboratorial proposal for the undergraduate level; Argilas como catalisadores verdes na esterificacao do colesterol: caracterizacao espectroscopica e identificacao de polimorfos por metodos de analise termica. Uma proposta laboratorial interdisciplinar para o primeiro ciclo universitario

    Energy Technology Data Exchange (ETDEWEB)

    Maria, Teresa M R.; Nunes, Rui M. D.; Pereira, Mariette M.; Eusebio, M. Ermelinda S. [Universidade de Coimbra, Coimbra (Portugal). Dept. de Quimica], e-mail: troseiro@ci.uc.pt

    2009-07-01

    A laboratory experiment that enables the professor to introduce the problematic of sustainable development in pharmaceutical chemistry to undergraduate students is proposed, using a simple synthetic procedure. Cholesteryl acetate is prepared by the esterification of cholesterol using Montmorillonite K10 as heterogeneous catalyst. Cholesterol and cholesteryl acetate are characterized by spectroscopic ({sup 1}H RMN, {sup 13}C RMN, FTIR) and thermal analysis techniques. The thermal methods are used to introduce the concepts of polymorphism and the nature of mesophases. (author)

  7. Clays as green catalysts in the cholesterol esterification: spectroscopic characterization and polymorphs identification by thermal analysis methods. An interdisciplinary laboratorial proposal for the undergraduate level

    International Nuclear Information System (INIS)

    Maria, Teresa M R.; Nunes, Rui M. D.; Pereira, Mariette M.; Eusebio, M. Ermelinda S.

    2009-01-01

    A laboratory experiment that enables the professor to introduce the problematic of sustainable development in pharmaceutical chemistry to undergraduate students is proposed, using a simple synthetic procedure. Cholesteryl acetate is prepared by the esterification of cholesterol using Montmorillonite K10 as heterogeneous catalyst. Cholesterol and cholesteryl acetate are characterized by spectroscopic ( 1 H RMN, 13 C RMN, FTIR) and thermal analysis techniques. The thermal methods are used to introduce the concepts of polymorphism and the nature of mesophases. (author)

  8. Thermal Neutron Spectral and Spatial Distributions in Light-Water-Moderated Uranium Lattices; Distributions Spectrale et Spatiale des Neutrons Thermiques dans des Reseaux a Uranium et a Eau Leger; Spektral'noe i prostranstvennoe raspredelenie teplovykh nejtronov v uranovykh reshetkakh s vodnym zamedlitelem; Distribuciones Espectral y Espacial de los Neutrones Termicos en los Reticulados de Uranio Moderados por Agua Ligera

    Energy Technology Data Exchange (ETDEWEB)

    Hardy, J.; Volpe, J. J.; Klein, D.; Schmidt, E.; Gelbard, E. [Bettis Atomic Power Laboratory, Pittsburgh, PA (United States)

    1964-02-15

    realizados acerca del comportamiento de los neutrones termicos en los reticulados de uranio moderados por agua ligera. Los experimentos pertenecen a dos tipos principales: mediciones del grado de utilizacion termica y mediciones, por activacion, de la distribucion espacial de los neutrones termicos en un medio acuoso uniformemente envenenado. Esos experimentos se concibieron con miras a comprobar la validez de los actuales modelos teoricos, distinguiendo los efectos espectrales de los espaciales en el interior de un reactor. Se han efectuado eomparaciones con modelos teoricos que entraflan distintas aproximaciones relacionadas con la teoria del transporte y el nucleo de dispercion de los neutrones termicos. La primera serie de experimentos consistio en medir por el procedimiento de activacion los factores de desventaja termica en distintas celdas de reticulados del conjunto TRX, que constituye un reactor de uranio ligeramente enriquecido, moderado por H{sub 2}O, con barras de combustible cilindricas dispuestas en haces hexagonales. Los autores han comparado los resultados de las mediciones del grado de utilizacion termica con los datos de calculos efectuados con arreglo al metodo de Montecarlo. Utilizaron dos nucleos, el de Radkowsky y el de N elk in. El nucleo de Radkowsky constituye una aproximacion de primer orden que se viene utilizando umversalmente en el disello de los reactores. El nucleo de Nelkin, por su parte, representa una descripcion mas reciente y mas detallada del nucleo de dispersion. Dado que los indices de absorcion calculados para los neutrones termicos dependen de la eleccion del nucleo de dispersion, especialmente si el espectro del flujo neutronico no es maxwelliano, se ideo otra serie de experimentos de activacion con ayuda del conjunto TRX para verificar de un modo mas directo la utilidad del nucleo de dispersion. Los experimentos se realizaron en condiciones tales que la deformacion espectral se debia esencialmente a un envenenamiento uniforme. Las

  9. Principal component analysis for verifying {sup 1}H NMR spectral assignments. The case of 3-aryl (1,2,4)-oxadiazole-5-carbohydrazide benzylidene; Aplicacao de analise de componentes principais para verificacao de atribuicoes de sinais nos espetros de RMN 1H. O caso dos 3-aril (1,2,4)-oxadiazol-5-carboidrazida benzilidenos

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Joao Bosco P. da; Malvestiti, Ivani; Hallwass, Fernando; Ramos, Mozart N. [Pernambuco Univ., Recife, PE (Brazil). Dept. de Quimica Fundamental]. E-mail: paraiso@ufpe.br; Leite, Lucia F.C. da Costa [Universidade Catolica de Pernambuco, Recife, PE (Brazil). Dept. de Quimica; Barreiro, Eliezer J. [Universidade Federal, Rio de Janeiro, RJ (Brazil). Faculdade de Farmacia

    2005-06-01

    The {sup 1}H NMR data set of a series of 3-aryl (1,2,4)-oxadiazole-5-carbohydrazide benzylidene derivatives synthesized in our group was analyzed using the chemometric technique of principal component analysis (PCA). Using the original 1H NMR data PCA allowed identifying some misassignments of the proton aromatic chemical shifts. As a consequence of this multivariate analysis, nuclear Overhauser difference experiments were performed to investigate the ambiguity of other assignments of the ortho and meta aromatic hydrogens for the compound with the bromine substituent. The effect of the 1,2,4-oxadiazole group as an electron acceptor, mainly for the hydrogens 12,13, has been highlighted. (author)

  10. Characterisation of the acidity and the basicity of transition alumina by NMR and FTIR spectroscopy of adsorption of probe molecules; Caracterisation par RMN et infrarouge de molecules sondes adsorbees, de l'acidite et de la basicite d'alumines de transition

    Energy Technology Data Exchange (ETDEWEB)

    Mathonneau, E.

    2003-04-01

    This work has been devoted to characterization of the acidity and the basicity of the surface of transition alumina. Three different alumina (Alumina-{gamma}, -{delta} et -{theta} ({gamma}-Al, {delta}-Al, {theta}-Al)) have been studied by adsorption of probe molecules such trimethyl phosphine and carbon monoxide (acidity study); and tri-ethyl borane (basicity study). We emphasized that the acidity increases with an increasing pretreatment temperature where as the basicity decreases. Comparing quantitative results from the different probe molecules we could show an increasing strength acidity following: {gamma}-Al > {theta}-Al > {delta}-Al, and basicity following: {delta}-Al > {gamma}-Al > {theta}-Al. We could evaluate on a qualitative (nature and repartition) and on a quantitative point of view the impact of the transformations {gamma}-Al {yields} {delta}-Al and {gamma}-Al > {theta}-Al on the acid-basicity of the surface. We could also explain catalytic reactivity differences between alumina for the position isomerization of butene-1. (author)

  11. Etude par calorimétrie à titrage isotherme (ITC) et spectroscopie de résonnance magnétique nucléaire (RMN) des effets de protonation liés à l'interaction entre l'alpha-chymotrypsine et la proflavine / Gilles Bruylants

    OpenAIRE

    Bruylants, Gilles

    2005-01-01

    Le nombre de cibles potentielles pour la conception de nouvelles molécules à activité thérapeutique ne cesse de croître. Pour chaque cible, il est nécessaire d’identifier des molécules actives et de les optimiser afin d’atteindre l’affinité et la sélectivité recherchées. Ces nouveaux défis accentuent la nécessité d’améliorer notre compréhension des facteurs qui mènent à la reconnaissance moléculaire entre une drogue potentielle et une macromolécule biologique, et particulièrement des facteurs...

  12. Effect of electroremediation application in the structure and contaminants of spent catalytics: Evaluation using NMR, EPR, DRX and XRF; Efeito da aplicacao da eletrorremediacao na estrutura e nos contaminantes de catalisador desativado: avaliacao por tecnicas de RMN, RPE, DRX e FRX

    Energy Technology Data Exchange (ETDEWEB)

    Leonel, R.F.; Valt, R.B.G.; Godoi, L.; Ponte, M.J.J.S.; Ponte, H.A. [Universidade Federal do Parana (UFPR), Curitiba, PR (Brazil). Centro Politecnico

    2015-07-01

    The electrokinetic remediation process, through the application of electric potential and different electrolytes, aimed at mobilizing and removing contaminant metals in spent catalytic cracking catalysts. In this study, FCC spent catalysts were studied after the remediation process with three different electrolytes (solutions of sodium citrate, sulfuric acid or citric acid). The techniques of XRD, XRF, NMR and EPR were used in order to evaluate the changes. The results indicated that the electrokinetic remediation tends to reorganize the internal structure of the catalyst, recovering part of the crystallinity and removing a percentage of the contaminants. (author)

  13. Características estruturais de ácidos húmicos isolados de solos com adição de resíduos orgânicos de origem urbana: composição elementar, análise de RMN 13C e Pi-CG/EM

    OpenAIRE

    L. P. Canellas; A. A. Moraes; V. M. Rumjanek; M. R. Garcia; F. Guridi; G. A. Santos; A. C. X. Velloso; R. Braz-Filho

    2002-01-01

    Foram avaliadas as alterações nas características estruturais de ácidos húmicos (AH) decorrentes da adição de matéria orgânica de resíduos urbanos. Os AH foram extraídos da camada superficial (0-20 cm) de um Argissolo Vermelho-Amarelo (Seropédica, RJ) e de um Latossolo Vermelho Amarelo (Piraí, RJ), ambos tratados com o equivalente a 80 t ha-1 (em base seca) de composto de lixo urbano e lodo de estação de tratamento de esgotos. O tempo de incubação em laboratório foi de 24 semanas à temperatur...

  14. Development in NMR spiral imaging and application to the assessment of the permeability of the blood-brain barrier on 2 models of brain tumors; Developpements en imagerie RMN spirale et application a la caracterisation de la permeabilite de la barriere hemato-encephalique sur deux modeles de tumeurs intracerebrales

    Energy Technology Data Exchange (ETDEWEB)

    Beaumont, M

    2007-12-15

    The results presented in this work were obtained as part of methodological developments in magnetic resonance imaging. First of all, the setting of the rapid imaging technique using a k-space sampling scheme along a variable density spiral is described. Numerical simulations were used to optimize the acquisitions parameters and to compare different reconstruction techniques. An original approach to calibrate the k-space trajectory was proposed. Then, spiral imaging was used to implement a method to measure the blood brain barrier permeability to Gd-DOTA. This protocol was combined to blood volume and vessel size index measurements using Sinerem. The results obtained highlighted differences between the microvascular parameters measured on C6 and RG2 tumor models. The presence of Sinerem induces a mean decrease of the transfer constant across the vascular wall (Ktrans), in the tumor, of 24 per cent. This study also showed extravasation of the Sinerem, during the first two hours after the product injection, only in the RG2 tumors. (author)

  15. Solid state {sup 13}C NMR study on the synthesis of graphite oxide from different graphitic precursors; Estudo atravéS de RMN de {sup 13}C no estado sólido sobre a síntese de oxido de grafite utilizando diferentes precursores grafíticos

    Energy Technology Data Exchange (ETDEWEB)

    Vieira, Mariana A.; Frasson, Carolina Maria R.; Costa, Tainara Luiza G.; Cipriano, Daniel F.; Schettino Junior, Miguel A.; Cunha, Alfredo G.; Freitas, Jair C.C., E-mail: marianaarpini@hotmail.com [Universidade Federal do Espírito Santo (UFES), Vitória, ES (Brazil). Lab. de Materiais Carbonosos e Cerâmicos

    2017-10-15

    The influence of the structural and microstructural characteristics of graphitic precursors on the production of graphite oxide (GO) is investigated in the present work. Six different graphitic precursors were used to produce GO following a modified Hummers method, namely: natural graphite, commercial lubricant graphite, milled graphite, graphite flakes, high-purity graphite and graphite recycled from Li-ion batteries. The products were characterized by X-ray diffraction (XRD), thermogravimetry, solid-state {sup 13}C nuclear magnetic resonance (NMR) and scanning electron microscopy (SEM). {sup 13}C NMR spectra revealed the presence of epoxy, hydroxyl, carbonyl and lactol groups in the synthesized GOs. However, the oxidation degree of each product was found to be dependent on the average crystallite size (Lc) and particle size of the graphitic precursors, with the best GO samples being produced from the milled graphite and the graphite recycled from ion-Li batteries. These results were rationalized in terms of the structural and microstructural differences among the graphitic precursors, as revealed by the XRD patterns and SEM images, evidencing the importance of the correct choice of the precursor aiming the achievement of a well-developed structure for the GO product. (author)

  16. Treatment by (N H{sub 4}){sub 2} Si F{sub 6} of hydrothermally stabilized Y zeolite: NMR, infrared and atomic absorption monitoring; Tratamento por (NH4){sub 2} SiF{sub 6} de zeolito Y estabilizado hidrotermicamente: monitoramento por RMN, IV e A.A

    Energy Technology Data Exchange (ETDEWEB)

    Martins, Ruth L; Camorim, Vera L.D.D.; Menezes, Sonia M.C. de [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas

    1992-12-31

    The kinetics of NFA leaching of a hydrothermal treated Y zeolite was determined by using AAS, IR and NMR techniques. It was observed first order with respect to NFA onto intra crystalline volume. The transformation of octahedral Aluminium into mainly tetrahedral species was observed at the first contact with the fluorinated reagent,being leached as NM{sub 4} Al F{sub 4} and, in a less amount, as (N H{sub 4}){sub 3} Al F{sub 6}. (author) 4 refs., 5 figs., 1 tab.

  17. químicos das folhas de Qualea grandiflora: atribuição dos dados de RMN de dois flavonóides glicosilados acilados diastereoisoméricos Chemical constituents from leaves of the Qualea grandiflora: attribution of the NMR data of two diastereoisomeric acylated flavonoid glycosids

    Directory of Open Access Journals (Sweden)

    Mariane Cruz Costa Ayres

    2008-01-01

    Full Text Available Phytochemical investigation from leaves of the Qualea grandiflora (Vochysiaceae resulted in the isolation and identification of kaempferol-3-O-α-L-(4"-E-p-coumaroyl-rhamnoside, kaempferol-3-O-α-L-(4"-Z-p-coumaroyl-rhamnoside, squalene, phytol, lupeol, α-amyrin, β-amyrin, sitosterol, sitostenone, sitosterol-3-O-β-D-glucopyranoside, ursolic and oleanolic acids. The structures of the compounds were identified by 1D- and 2D-NMR experiments, mass and UV spectrometry and comparison with literature data.

  18. Glutamine synthetase activity in solanaceous cell suspensions accumulating alkaloids or not. {sup 13}C NMR and enzymatic assay; Activite de la glutamine synthetase dans des suspensions cellulaires de solanacees productrices ou non d'alcaloides. RMN du {sup 13}C et dosage enzymatique

    Energy Technology Data Exchange (ETDEWEB)

    Mesnard, F.; Marty, D.; Monti, J.P. [Faculte de Pharmacie, 80 - Amiens (France). Laboratoire de Biophysique, Groupe de Recherche des Biomolecules: micro-environnement et Metabolisme; Gillet-Manceau, F.; Fliniaux, M.A. [Faculte de Pharmacie, 80 - Amiens (France). Laboratoire de Phytotechnologie

    1999-09-01

    The metabolism of labelled pyruvate followed by {sup 13}C NMR and the measure of glutamine synthetase (GS) showed, according to previous results, a high activity of this enzyme in suspension cells of Nicotiana plumbaginifolia. This activity could derive glutamate from the alkaloidsynthesizing pathways. However, a recent work showed that the rate of the GS gene transcription was inversely proportional to the Gln/Glu ratio. The measures of Gln and Glu concentrations in Nicotiana plumbaginifolia cells revealed that high GS activity correlates with the weak value of Gln/Glu ratio. Therefore, the hypothesis of GS dysfunction for the non-biosynthesis of alkaloids in N. plumbaginifolia suspension cells can be discarded. This conclusion is strengthened by the results obtained when using a GS inhibitor. (author)

  19. Verification of the application of NMR spectroscopy in the reading of the MAGIC-f gel dosimeter; Verificação da aplicação da espectroscopia de RMN na leitura do dosímetro gel MAGIC-f

    Energy Technology Data Exchange (ETDEWEB)

    Murakami, N.S.; Filipov, D.; Soboll, D.S., E-mail: nayarasaty@hotmail.com [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil). Programa de Pós-Graduação em Engenharia Biomédica; Barison, A.; Alib, S. [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil). Centro de RMN; Petchevistc, P.C.D. [ONCOVILLE Atendimento Oncológico Integral, Curitiba, PR (Brazil)

    2017-07-01

    This work aims to perform the processing of the MAGIC-f polymeric gel, irradiate it and verify the application of NMR spectroscopy to characterize it. Thus, this would be another method of reading the dosimeter. As an initial study, it was found that NMR spectroscopy can be a very effective method for reading the MAGIC-f gel, showing different signal intensities for each absorbed dose.

  20. RMN du deutérium sur des suspensions. Application à une boue de forage. Etude en température et en fréquence d'une argile à grands feuillets Deuterium Nmr on Suspensions Applied to Drilling Mud. a Temperature and Frequency Study of Large Stratum Shale

    Directory of Open Access Journals (Sweden)

    Letellier M.

    2006-12-01

    Full Text Available La mesure du temps de relaxation transversal T1 en fonction de la concentration permet de déterminer la surface hydrophile mouillée d'une suspension, à condition de connaître le T1 de surface. De même, la mesure de T1 en fonction du temps permet de déterminer les variations de surface lors d'une réaction lente telle que la prise d'une boue de forage, simulée par un mélange bentonite/ciment/eau lourde. L'avantage d'utiliser la résonance du deutérium est que sa relaxation dépend peu de la présence d'impuretés paramagnétiques ou de l'existence de mouvements moléculaires dans des espaces confinés, comme il est montré sur une argile à grands feuillets, la montmorillonite. Celle-ci est étudiée en fonction de la température, ce qui permet de mesurer, sans modifier la suspension, le T1 de surface. Measuring transverse T1 relaxation times as a function of concentration provides a determination of the hydrophilic surface, wetted with a suspension, as long as the surface relaxation T1 is known. Likewise, measuring T1 over time provides a determination of the surface variations during a slow reaction such as when drilling mud sets, which is simulated by a mixture of bentonite, cement and heavy water. Deuterium resonance measurements have the advantage that the relaxation depends little on the presence of paramagnetic impurities or molecular motion in a confined space, which has been demonstrated using a large stratum shale, montmorillonite. This shale has been studied as a function of temperature, which makes it possible to measure the surface relaxation T1 without modifying the suspension.

  1. NMR spectroscopy of lactate in the skeleton muscle: visibility, quantification and measurement of carbon 13 enrichment by double quantum edition; Spectroscopie RMN du lactate dans le muscle squeletique: visibilite, quantification et mesure de l'enrichissement au carbone 13 par edition a double quantum

    Energy Technology Data Exchange (ETDEWEB)

    Jouvensal, L

    1997-12-18

    The metabolism of skeleton muscles gave rise to numerous research works since the beginning of the century in order to make some reply about the muscle physiology with the will to improve the sport performances or the understanding of muscles diseases. This metabolism is complex and the lactate has an importance place; the purpose of this work is to answer these questions with some strategy studies by nuclear magnetic resonance spectroscopy. (N.C.)

  2. Supressão das anomalias de fase e batimentos laterais em espectros de RMN 13c obtidos com a sequência de precessão livre no estado estacionário Suppression of phase anomalies and sidebands on 13c NMR spectra obtained with the steady-state free precession sequence

    Directory of Open Access Journals (Sweden)

    Poliana Macedo dos Santos

    2010-01-01

    Full Text Available The Steady-State Free Precession (SSFP sequence has been widely used in low-field and low-resolution imaging NMR experiments to increase the signal-to-noise ratio (s/n of the signals. Here, we analyzed the Scrambled Steady State - SSS and Unscrambled Steady State - USS sequences to suppress phase anomalies and sidebands of the 13C NMR spectrum acquired in the SSFP regime. The results showed that the application of the USS sequence allowed a uniform distribution of the time interval between pulses (Tp, in the established time range, allowing a greater suppression of phase anomalies and sidebands, when compared with the SSS sequence.

  3. Flavonoids from Lonchocarpus araripensis (Leguminoseae): isolation, unequivocal assignment of NMR signals {sup 1}H and {sup 13}C and conformational analysis; Flavonoides de Lonchocarpus araripensis (Leguminoseae): isolamento, atribuicao inequivoca dos sinais de RMN {sup 1}H e {sup 13}C e analise conformacional

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Almi F.; Ferreira, Daniele A.; Monte, Francisco Jose Q., E-mail: fmonte@dqoi.ufc.br [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Centro de Ciencias. Departamento de Quimica Organica e Inorganica; Braz-Filho, Raimundo [Universidade Estadual do Norte Fluminense (UENF), Campo dos Goytacazes, RJ (Brazil). Centro de Ciencias Tecnologicas. Laboratorio de Ciencias Quimicas

    2014-07-01

    In a continuing investigation for potentially bioactive natural products, flavonoids were isolated from Lonchocarpus araripensis (Leguminoseae) and identified as 3-methoxy-6-O-prenyl-6'',6''-dimethylchromene-[7,8,2'',3'']-flavone (1), 3,6-dimethoxy-6'',6''-dimethylchromene-[7,8,2'',3'']-flavone (2) and 3,5,8-trimethoxy-[6,7,2{sup ,}3{sup ]}-furanoflavone (3). This is the first time compound 3 has been described. Compound 2 has been previously isolated from roots while this is the first time 1 is reported in this species. Complete NMR assignments are given for 1 ,2 and 3 together with the determination of conformation for 1. (author)

  4. Void Reactivity Effects in the Second Charge of the Halden Boiling Water Reactor; Effets Cavitaires dans la Deuxieme Charge du Reacteur a Eau Lourde Bouillante de Halden (HBWR); Ehffekty pustotnoj reaktivnosti vo vtoroj zag HBWR; Effectos de Cavitacion en la Segunda Carga del Reactor de Agua Pesada Hirviente de Halden (HBWR)

    Energy Technology Data Exchange (ETDEWEB)

    Lunde, J. E. [OECD Halden Reactor Project (Norway)

    1964-02-15

    experimento permite investigar las variaciones de la reactividad en funcion del volumen relativo de los vacios y de la posicion de las burbujas de vapor en el canal refrigerante. Se ejecuto en el conjunto noruego de energia nula, NORA, con un cuerpo consistente en 36 elementos de la segunda carga dispuestos en un reticulado de geometria identica a la del reactor HBWR. El autor estudio la variacion del efecto de cavitacion en funcion de la temperatura en un conjunto de potencia nula provisto de 100 elementos combustibles. En un elemento redujo el nivel de agua en el interior del canal refrigerante a varios valores y midio el efecto que ejercia esta perturbacion sobre la reactividad a temperaturas comprendidas entre 50 Degree-Sign C y 220 Degree-Sign C. El efecto de los huecos sobre la reactividad a regimen normal se ha medido en el reactor HBWR en funcion de la potencia para temperaturas del moderador que oscilaron entre 150 Degree-Sign C y 230 Degree-Sign C, alcanzandose a esta ultima temperatura hasta unos 16 MW. El coeficiente de cavitacion en regimen normal constituye un parametro que conviene conocer cuando se trate de determinar el comportamiento dinamico de un reactor de agua hirviente. Sin embargo, su determinacion teorica se complica por el hecho de que es preciso conocer la distribucion de las cavidades en el cuerpo. Tampoco es facil determinarla por via experimental con exactitud cuando el reactor funciona a regimen normal y, por tanto, los calculos de fisica de los reactores de los efectos de las cavidades se comprueban mejor simulando los huecos experimentalmente. Se han efectuado comparaciones preliminares entre los resultadas de esos experimentos y los datos teoricos. Los calculos se realizan por una teoria de difusion de dos grupos y se aprecia que los resultados teoricos y experimentales sobre las perturbaciones de los parametros del reticulado, para un volumen relativo de los vacios igual a 1, concuerdan satisfactoriamente tanto a temperaturas bajas como a

  5. Monika Fludernik, Verso una narratologia ‘naturale’

    Directory of Open Access Journals (Sweden)

    Filippo Pennacchio

    2013-06-01

    La traduzione del saggio è fatta precedere da un’introduzione in cui viene presentato, più in generale, il pensiero di Monika Fludernik, e insieme valutato il suo ruolo nell’ambito del dibattito teorico sviluppatosi in seno alla comunità scientifica a partire dai primi anni Duemila.

  6. Costruire e programmare robot

    Directory of Open Access Journals (Sweden)

    Barbara Caci

    2002-01-01

    Full Text Available Negli scenari riguardanti le nuove tecnologie didattiche sta progressivamente acquistando un posto di rilievo la robotica educativa. Tale termine designa una varieta' di esperienze formative, ispirate ai principi teorico metodologici del costruttivismo e della embodied cognition, e basate sull'impiego di Robotic Construction Kits come strumenti di apprendimento.

  7. Reti strategiche come evoluzione delle reti emergenti

    DEFF Research Database (Denmark)

    Brunetta, Federica; Censi, Anna; Rullani, Francesco

    2015-01-01

    che ne fanno parte in un segmento a più alto valore aggiunto della catena delvalore.Metodologia: Questo lavoro analizza il contratto di rete come fenomeno empiricoche cattura il concetto teorico di rete strategica, approfondendo il caso di due contrattidi rete stipulati nella provincia di Brescia...

  8. Marketing político: preceitos teóricos x práticas eleitorais

    OpenAIRE

    Campagnone, Zilda Maria Matheus

    2010-01-01

    Correlações entre preceitos teoricos ditados pelos especialistas em Marketing Político e as práticas eleitorais adotadas pelos candidatos a Presidência da República, que disputam o 2 turno das eleições presidenciais- Brasil/ 1989

  9. Initiation au Lambda-Calcul (An Initiation into Lambda Calculus)

    Science.gov (United States)

    1989-07-15

    6tmnt donn6 M, V et D, calculo N et W: let rec: trace (M,V) = function D1 - (MYV) f u::D -*let N = rduit M uand W = Rsidus M u V itace(NW)D;; Example...calculer lapproximation do c, par I’ex~cution do, f10). La proc6dure approx ci-dessous calculo I’approximation d’un ).-torme par r6duction normale...rente avec ce r6gime d𔄀valuation. Par contre, la rbgle 4 nWest pas utilis", c’est A dire qu’on ne, calculo pas A I’int6rieur des abstractions. Los tormes

  10. Integral physics data for fast-reactor design; Donnees de physique integrale intervenant dans les etudes de reacteur a neutrons rapides; Integral'nye fizicheskie dannye dlya raschetov reaktorov na bystrykh nejtronakh; Datos fisicos integrales para el diseno de reactores rapidos

    Energy Technology Data Exchange (ETDEWEB)

    Loewenstein, W B; Meneghetti, D [Argonne National Laboratory, Argonne, IL (United States)

    1962-03-15

    examinent ces donnees et decrivent leurs domaines d'application. Ils montrent que dans certaines analyses de spectre et d'etat critique, les resultats experimentaux et analytiques sont limites. Ils font des suggestions sur l'orientation des recherches experimentales et analytiques a venir. Elles combleraient le fosse entre la theorie et l'experience qui existe dans les systemes 'connus'. Ces propositions comprennent egalement des suggestions en vue de 'consolider' la physique de modeles theoriques de grands reacteurs surgenerateurs a neutrons rapides. (author) [Spanish] La preparacion del capitulo dedicado a la fisica de los reactores rapidos, en la segunda edicion de la publicacion 'Reactor Physics Constants' que aparecera en breve, exigio la recopilacion de los datos disponibles sobre experimentos integrales. La eleccion de los datos integrales de fisica de los reactores rapidos que se ha de incluir en esa seccion se baso en los dos criterios siguientes: a) que los datos provengan de sistemas relativamente simples que se presten para un analisis teorico sencillo; y b) que se trate de sistemas complejos que representan prototipos o maquetas que ofrecen interes general para el estudio de los reactores de potencia rapidos. Se fijo el primer criterio con la intencion de registrar los datos integrales de aquellos sistemas que tienen una utilidad mas general en la verificacion de los parametros y los procedimientos de calculo de las secciones eficaces. El segundo criterio se basa en la presentacion de los datos corrientes sobre sistemas reales de reactores de potencia reproductores rapidos. Estos son demasiado complicados para permitir un analisis teorico sencillo. Constituyen una demostracion de la complejidad del reactor real si se compara con la instalacion critica de experimentacio n mas esquematica y mas facil de analizar. Los datos fisicos integrales que intrevienen en el diseno de reactores constituyen el resultado de mediciones efectuadas en conjuntos criticos o

  11. Neutron Spectra in H{sub 2}O, D{sub 2}O, BeO and CH{sub 2}; Spectres de Neutrons dans H{sub 2}O, D{sub 2}O, BeO et CH{sub 2}; Spektry nejtronov v H{sub 2}O, D{sub 2}O, BeO i CH{sub 2}; Espectros Neutronicos en H{sub 2}O, D{sub 2}O, BeO y CH{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Neill, J. M.; Young, J. C.; Trimble, G. D.; Beyster, J. R. [General Atomic Division of General Dynamics Corporation, John Jay Hopkins Laboratory for Pure and Applied Science, San Diego, CA (United States)

    1965-08-15

    satisfaisante pour quelques applications. Cette constatation est surprenante du fait que le deuterium est avant tout un diffuseur coherent, ce que n'est pas l'hydrogene, mais elle corrobore de recentes etudes de Koppel qui montrent que les termes de diffusion dus aux interferences intramoleculaires et intermoleculaires dans D{sub 2}O tendent a s'annuler. Les auteurs presentent egalement des spectres de neutrons, variables selon l'angle, mesures dans BeO empoisonne avec de l'acier inoxydable au bore. D'une maniere generale, l'accord entre les mesures et les calculs a ete considerablement ameliore. Le noyau de diffusion theorique est fonde sur un spectre de frequences de Debye avec une frequence de coupure ajustee de maniere a satisfaire les mesures de chaleur specifique pour BeO. Dans les mesures, les auteurs ont observe un important piegeage de Bragg de neutrons de faible energie. (author) [Spanish] En los laboratorios de la General Atomic se estan midiendo espectros de neutrones termicos en moderadores de interes para la tecnologia nuclear. La finalidad de estas mediciones es verificar la validez de los modelos de dispersion propuestos para esos moderadores. En la actualidad, los nucleos de dispersion se determinan midiendo directamente las secciones eficaces de dispersion diferenciales dobles, o estudiando los movimientos de vibracion y de rotacion de las moleculas en los liquidos, o el espectro de vibraciones reticulares en los solidos. La medicion directa tropieza con algunas dificultades experimentales, tales como obtener la intensidad y el poder de resolucion deseados e introducir las correcciones adecuadas para tener en cuenta la dispersion multiple en la muestra. Para la tecnologia de los reactores, el segundo procedimiento de determinacion del ndcleo de dispersion suele dar resultados mas satisfactorios. Las mediciones integrales efectuadas, combinadas con el calculo comparado de los espectros neutronicos, permiten formular algunas observaciones sobre el estado actual

  12. Radiation monitoring network of the Czech Republic

    International Nuclear Information System (INIS)

    Kuca, P.; Novak, L.; Rulik, P.; Tecl, J.

    2003-01-01

    The Radiation Monitoring Network (RMN) of the Czech Republic was established after the Chernobyl accident in 1986 and it is developed all the time. It is co-ordinated by the State Office for Nuclear Safety in co-operation with the National Radiation Protection Institute. Czech RMN consists of the several sub-networks, which include selected or all permanent parts of RMN. The sub-networks are following: the Early Warning Network (EWN), the TLD Territorial Network, the Network of the Measuring Sites of Air Contamination, the Network of Laboratories Equipped with Gamma-spectrometric and Radiochemical Analytical Instrumentation, the Ground and Airborne Mobile Groups. The Laboratory of Monitoring of Internal Contamination and the information system (IS) are a significant part of RMN, too. The data of RMN resulting from monitoring are transferred to the central database of CRMN, processed by the information system (IS). They are used in normal and emergency situations for an evaluation of radiation situation and for preparation of recommendations for protection of the public and the environment. In 2002 any extraordinary radioactivity in the environment was not detected and also none of the measuring points recorded any exceeding of established investigation levels. In components of environment and also in human beings a very low activity of 137 Cs was still measurable, that had been released into environment after the Chernobyl accident and by the nuclear weapon tests in sixties of the last century. (authors)

  13. Computerized dosimetry of I-125 sources model 6711; Dosimetria computarizada de las fuentes de I-125 modelo 6711

    Energy Technology Data Exchange (ETDEWEB)

    Isturiz, J [Centre de Radiotherapie du Parc, Dijon (France)

    2001-07-01

    It tries on: physical presentation of the sources; radiation protection; mathematical model of I-125 source model 6711; data considered for the calculation program; experimental com probation of the dose distribution; exposure rate and apparent activity; techniques of the use given to the sources I-125; and the calculation planning systems. [Spanish] Trata sobre presentacion fisica de las fuentes, radioproteccion, modelo matematico de las fuentes I-125 modelo 6711, datos considerados en el programa de calculo, comprobacion experimental de la distribucion de dosis, tasa de exposicion y actividad aparente, tecnicas de utilizacion de las fuentes I-125; y los sistemas de planificacion del calculo de las dosis.

  14. Indium-Gallium Radiation Contour of the IRT Nuclear Reactor; Circuit d'activation d'indium-gallium dans le reacteur nucleaire IRT; Indij-gallievyj radiatsionnyj kontur yadernogo reaktora IRT; Circuito de radiaciones de indio-galio del reactor IRT

    Energy Technology Data Exchange (ETDEWEB)

    Breger, A K; Ryabukin, Y S; Tulkes, S G; Volkov, E N

    1960-07-15

    -industrielles. (author) [Spanish] Basandose en un trabajo teorico ya publicado, se preparo en el reactor IRT un circuito de radiaciones de indio-galio que constituye una nueva fuente de rayos gamma de elevada intensidad. El primer circuito de este tipo ''RK-1'' se construyo para el reactor IRT en el Instituto de Fisica de la Academia de Ciencias de la Republica Socialista Sovietica de Georgia. Este trabajo estudia los puntos siguientes: calculo de la activacion de la desintegracion del conjunto indio-galio; estructura del circuito RK-1 y su disposicion en el tanque del reactor y en la camara activa; dispositivo de admision de las sustancias liquidas y gaseosas en la zona de la irradiacion; transportador de las sustancias solidas sometidas a irradiacion. En el reactor IRT, cuya potencia es de 2 000 kW, la intensidad de irradiacion del circuito es igual a la de una fuente de radiacion gamma equivalente a 20 000 g de radio. En el trabajo se estudian las posibilidades de utilizacion de este circuito con fines semi-industriales y de investigacion. (author) [Russian] Osnovyvayas' na uzhe opublikovannoj teoreticheskoj rabote, byl podgotovlen indij-gallievyj radiatsionnyj kontur yadernogo reaktora IRT, kotoryj yavlyaetsya novym moshchnym istochnikom gamma-oblucheniya . Pervyj kontur ehtogo tipa RK-1 byl podgotovlen na reaktore IRT v Institute fiziki Akademii nauk Gruzinskoj SSR. V doklade dayutsya raschety aktivizatsij dlya indij-gallievogo splava, strukturnye kompanovki RK-1 i ikh raspolozhenie v bake reaktora i goryachej kamere, ustrojstvo podachi zhidkikh i gazoobraznykh veshchestv v zonu oblucheniya i konvejer dlya tverdykh veshchestv, kotorye podlezhat oblucheniyu. V reaktore IRT moshchnost'yu 2000 kW moshchnost' oblucheniya kontura ehkvivalentna moshchnosti oblucheniya gamma-izluchatelya, obladayushchego aktivnost'yu v 20000 g ehkv. radiya. V doklade obsuzhdayutsya perspektivy ispol'zovaniya indij-gallievogo radiatsionnogo kontura dlya issledovatel'skikh i polupromyshlennykh tselej

  15. Vibration analysis to characterize the behavior of fracture rotors operating in line; Analisis de vibracion para caracterizar el comportamiento de rotores fracturados operando en linea

    Energy Technology Data Exchange (ETDEWEB)

    Garcia Illescas, Rafael

    2001-07-01

    , in other words. Unstable response behavior is quite sensitive to such nonlinear parameters. A general overview in this area is presented as a part of a multidisciplinary study. [Spanish] En este trabajo se presenta un analisis en tres enfoques: teorico, numerico y experimental, del comportamiento dinamico y de la estabilidad vibratoria de un sistema rotor chumacera conteniendo una grieta transversal localizada a medio tramo de la longitud axial del eje. La presencia de una grieta transversal es considerada mediante la modelacion de la variacion periodica de la rigidez estructural del rotor, la cual se expresa en funcion del tiempo (o posicion angular). El amortiguamiento del sistema incluye un amortiguamiento externo debido al fluido dentro del cual se encuentra el rotor girando y, el mas significativamente, un amortiguamiento viscoso originado por la pelicula de aceite en las chumaceras. El problema en estudio consiste en un rotor extendido del tipo Jeffcott, el cual tiene un disco al centro y chumaceras hidrodinamicas identicas en los dos extremos. Un aspecto innovador que aumenta la complejidad del analisis es que se incluye el efecto que tiene la masa del eje en cada una de las chumaceras en los extremos, ademas del efecto obvio de la masa del disco. Se hace una analisis numerico de la estabilidad lineal del sistema incluyendo todos los aspectos mencionados mediante la teoria de Floquet. Algunos resultados son comparados con los obtenidos por otros investigadores en este campo como Gasch, Meng y otros. El sistema parametricamente excitado resultante es analizado utilizado una solucion de perturbacion lineal del sistema. El sistema de ecuaciones se encuentra utilizando terminos complejos y ha sido representado y escrito en programas de computo en MATLAB desarrollados por el autor de la tesis para calcular la estabilidad lineal del problema. Varias configuraciones de rotores simples y reales son estudiados con el fin de ilustrar las propiedades basicas de rotores

  16. Ramsey numbers and adiabatic quantum computing.

    Science.gov (United States)

    Gaitan, Frank; Clark, Lane

    2012-01-06

    The graph-theoretic Ramsey numbers are notoriously difficult to calculate. In fact, for the two-color Ramsey numbers R(m,n) with m, n≥3, only nine are currently known. We present a quantum algorithm for the computation of the Ramsey numbers R(m,n). We show how the computation of R(m,n) can be mapped to a combinatorial optimization problem whose solution can be found using adiabatic quantum evolution. We numerically simulate this adiabatic quantum algorithm and show that it correctly determines the Ramsey numbers R(3,3) and R(2,s) for 5≤s≤7. We then discuss the algorithm's experimental implementation, and close by showing that Ramsey number computation belongs to the quantum complexity class quantum Merlin Arthur.

  17. Computational modeling of the mathematical dummy of the Brazilian woman for calculations of internal dosimetry and ends of comparison of the fractions absorbed specific with the woman reference; Modelagem computacional do manequim matematico da mulher brasileira para calculos de dosimetria interna e para fins de comparacao das fracoes absorvidas especificas com a mulher referencia

    Energy Technology Data Exchange (ETDEWEB)

    Ximenes, Edmir

    2006-07-01

    Tools for dosimetric calculations are of the utmost importance for the basic principles of radiological protection, not only in nuclear medicine, but also in other scientific calculations. In this work a mathematical model of the Brazilian woman is developed in order to be used as a basis for calculations of Specific Absorbed Fractions (SAFs) in internal organs and in the skeleton, in accord with the objectives of diagnosis or therapy in nuclear medicine. The model developed here is similar in form to that of Snyder, but modified to be more relevant to the case of the Brazilian woman. To do this, the formalism of the Monte Carlo method was used by means of the ALGAM- 97{sup R} computational code. As a contribution to the objectives of this thesis, we developed the computational system cSAF - consultation for Specific Absorbed Fractions (cFAE from Portuguese acronym) - which furnishes several 'look-up' facilities for the research user. The dialogue interface with the operator was planned following current practices in the utilization of event-oriented languages. This interface permits the user to navigate by means of the reference models, choose the source organ, the energy desired, and receive an answer through an efficient and intuitive dialogue. The system furnishes, in addition to the data referring to the Brazilian woman, data referring to the model of Snyder and to the model of the Brazilian man. The system makes available not only individual data to the SAFs of the three models, but also a comparison among them. (author)

  18. Calculations of doses for the personnel wrapped up in the radiological accident of the Specialties Hospital of the National Medical Center ''Siglo XXI''; Calculos de dosis para el personal involucrado en el accidente radiologico del Hospital de Especialidades del Centro Medico Nacional ''Siglo XXI''

    Energy Technology Data Exchange (ETDEWEB)

    Cortes C, A. [CNSNS, Dr. Barragan 779, Col Narvarte, Mexico D.F. (Mexico)]. e-mail: acortes@cnsns.gob.mx

    2004-07-01

    In this work the methodology used by the National Commission of Nuclear Safety and Safeguards for the determination of the internal dose due to the ingestion of coffee with I-131 for the personnel of the service of nuclear medicine of the Hospital of Specialties of the National Medical Center ''Siglo XXI'' of the Mexican Institute of the Social Insurance (IMSS), that was poured in the coffeepot of the service by a deliberate act before mentioned, is presented. Three different techniques were used to determine the initial activity incorporated starting from the measurements of retained activity in thyroid for 6 people of the service of nuclear medicine; the techniques employee provided consistent results. Using the results of the technique of the best estimator, it was applied the proposed methodology by the International Commission of Radioprotection in its publication 30 to determine the absorbed doses by the personnel involved in the accident, with which the Commission determines the administrative consequences to those that it should be held the personnel and the directive of the service of nuclear medicine of the one nosocome. (Author)

  19. Comparison between dose calculation in XiO Registered-Sign and dosimetric measurements in virtual wedge photon beams; Comparacao entre o calculo da dose no XiO Registered-Sign e medidas dosimetricas em feixes de fotons com filtro virtual

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, Laila G.; Amaral, Leonardo L.; Oliveira, Harley F., E-mail: lailagalmeida@gmail.com [Universidade de Sao Paulo (HCFMRP/USP), Ribeirao Preto, SP (Brazil). Hospital das Clinicas. Servico de Radioterapia; Maia, Ana F. [Universidade Federal de Sergipe (UFS), Sao Cristovao (Sweden), (Brasil) Departamento de Fisica

    2012-08-15

    The virtual wedge is useful tool in the radiation treatment planning since it has series of advantages over the hard wedge. Quality control tests ensure correct performance of the planning done in treatment planning systems (TPS). This study aimed to compare doses calculated by TPS and doses measured by ionization chamber (CI) and an ionization chambers array in virtual wedge photon beams of 6 MV. Measures carried out in Primus linear accelerator with a solid water phantom and dosimeter positioned at 10 cm depth with gantry at 0 Degree-Sign in many fields sizes and angles in the virtual wedge. Measurements on the central axis used as dosimeter an IC and on off-axis used an IC array. The simulation in CMS-XiO used the CT images of the phantom in the same configuration of the irradiation. Maximum and minimum values of the percentage differences between the doses provided by TPS and measurements with ionization chamber on the central axis were 1.43 and -0.10%, respectively, with average percentage difference of 0.08% and confidence limit of {Delta}=1.72%. In the region off-axis, the average percentage difference was 0.04%, with a maximum of 1.9%, minimum of 0% and confidence limit of {Delta}=1.91%. All values for dose percentage differences were below 2% and lower confidence limit of 3% are thus, according to the recommendations of the Technical Report Series - TRS-430. (author)

  20. Reassessment of Seismic Design and Noise Simulation using Finite Element Calculation of the Condensate Storage Tank of Cofrentes NPP according to standard API-650 11th Ed; Reevaluacion del diseno Sismico mediante Simulacion de Fluidos y Calculo por Elementos Finitos del Deposito del Almacenamiento de Condensado de Central Nuclear de Cofrentes conforme a la norma API-650 11th Ed

    Energy Technology Data Exchange (ETDEWEB)

    Sarti Fernandez, F.; Gavilan Moreno, C.; Paez Ortega, E.

    2012-07-01

    There have been several dynamic simulations in which I analyzed: fluid-structure interaction effect of the wave, studying stress, vibration modes and possible effects of structural instability. After this process to make the changes in the tank to comply with the new rules and updated seismic conditions were designed. were performed.

  1. Graphic console for analysis of severe accidents visualization of OEs, NAEs and calculation of the source term for the NPP-LV (CoGrAAS); Consola grafica para analisis de accidentes severos visualizacion de OEs, NAEs y calculo del termino fuente para la CLV (CoGrAAS)

    Energy Technology Data Exchange (ETDEWEB)

    Sandoval V, S.; Mendoza E, P. R.; Gonzalez C, J. M.; Cecenas F, M. [Instituto Nacional de Electricidad y Energias Limpias, Reforma 113, Col. Palmira, 62490 Cuernavaca, Morelos (Mexico); Tijerina S, F., E-mail: francisco.tijerina@cfe.gob.mx [CFE, Central Nucleoelectrica Laguna Verde, Carretera Federal Cardel-Nautla Km 42.5, 91476 Municipio Alto Lucero, Veracruz (Mexico)

    2016-09-15

    In response to the Fukushima Daiichi nuclear power plant accident, the NRC conducted an analysis and issued recommendations to improve the safety of the nuclear reactors. These include strengthening and integrating emergency response capabilities and emphasizing periodic staff training, the performance of simulation exercises. As a tool to observe these recommendations, the Graphic Console was developed for Analysis of Severe Accidents, Visualization of OEs, NAEs and calculation of the source term for nuclear power plant of Laguna Verde (NPP-LV ; CoGrAAS). The CoGrAAS is a computer system that displays in an integrated, graphic and dynamic way the information of a catalog of previously simulated accident scenarios. Has core mimics, vessel, primary containment and safety systems, trend graph of thermodynamic and radiological variables and the emergency procedures (OEs), chronological list of events, windows with detailed information for the dry-well, among others. The use of CoGrAAS allows that staff to understand and become familiar with the thermo-hydraulic progression of actual scenarios that exceed the design basis including those with core damage as severe accidents. The system enables personnel to develop an integral vision of the scenarios during the exercises and drills by observing and analyzing the evolution of the main reactor, core and primary containment variables, the response of emergency systems and the influence of that progression on OEs and the emergency action levels (NAEs). The CoGrAAS allows o observe the radiological variables and obtain the source term, to make the projection of doses, at any time within the scenario evolution. Thus, not only can the phenomenology of severe accidents be analyzed and understood, it is also possible to exercise, verify and evaluate the performance of critical tasks in the application of procedures, guidelines and emergency management plans. (Author)

  2. Scenarios catalog for the graphical console for analysis of severe accidents visualization of OEs, NAEs and calculation of source term of the NPP-LV; Catalogo de escenarios para la consola grafica para analisis de accidentes severos visualizacion de OEs, NAEs y calculo del termino fuente de la CLV

    Energy Technology Data Exchange (ETDEWEB)

    Sandoval V, S. [Instituto Nacional de Electricidad y Energias Limpias, Reforma 113, Col. Palmira, 62490 Cuernavaca, Morelos (Mexico); Mendoza R, M. E.; Tijerina S, F.; Garcia C, T., E-mail: manuel.mendoza@cfe.gob.mx [CFE, Central Nucleoelectrica Laguna Verde, Carretera Federal Cardel-Nautla Km 42.5, 91476 Municipio Alto Lucero, Veracruz (Mexico)

    2016-09-15

    A nuclear power plant is operated at all times within the design criteria of structures, systems and components, and according to the operation technical specifications. For different areas of work of a nuclear power plant is necessary to carry out practices in which is useful to have the prediction of the thermo-hydraulic and radiological progression of scenarios that imply exceeding that design bases, even reaching the damage of the fuel in different degree. During the exercises and drills of the External Plan of Emergency Response, the projection of doses is done to exercise the different tasks of the plan. To make the projection of doses is required to have the radiological source term of the scenario on which is practiced. Because of this, was identified the convenience of having a catalog of scenarios for which the radiological source term was calculated. In 2004, a first version of the catalog was produced for a power of 2027 MW, and in 2011 the catalog was updated for extended power conditions, 2317 MW. Both versions were made using the severe accident simulator MAAP-3B. That catalog consists of a form and an optical storage device. The form contains tables and figures in which the characteristics of the scenario to be practiced are searched and the electronic files of the corresponding radiological source term are located in the storage device. Due to the recent development of the graphical console for analysis of severe accidents, visualization of OEs, NAEs and calculation of the source term for the nuclear power plant of Laguna Verde (NPP-LV) CoGrAAS, the catalog printed was replaced by an electronic catalog for the CoGrAAS. The new catalog retains the philosophy of the previous catalog, constituted by a wide collection of scenarios that involve different circumstances and phenomena, that can be used to practice different tasks during training exercises or simulacrums, and combined with the following advantages: the scenario selection is made from an automated scheme in the CoGrAAS, the calculation of the source term is automated and can be performed for any time during the scenario progression, the simulations were performed using a more detailed model of the Unit 1 of the NPP-LV and with a more advanced version of MAAP (version 4). (Author)

  3. Overvoltage in chain of insulators front to lightning discharges: a comparative study of the calculation methods and of the parameter Z{sub t}; Sobretensoes em cadeia de isoladores frente a descargas atmosfericas: um estudo comparativo dos metodos de calculo e do parametro Z{sub t}

    Energy Technology Data Exchange (ETDEWEB)

    Godoy, Antonio Varejao de

    1989-07-01

    This work studies in a deterministic point of view a lightning discharges that strikes directly the transmission line tower top. The calculation methods of this kind of surges: the method of successive reflections introduced by Jordan and the method of field well as compared with these purpose. Based on this two approaches a computational program is developed to calculate the overvoltage on the insulator string and the required parameters. Based on the results of this analysis, the simplest and most efficient method is chosen and where a simple sensitivity analysis is made for the following parameters: the impedance of lightning stroke channel, the tower foot impedance, time to crest of stroke shape function and tower surge impedance. This analysis is performed in order to verify the voltage variation on the insulator string. Finally, the last parameter, the tower surge impedance is emphasized comparing its calculated values with the measured values by geometrical model technique. (author)

  4. The test of intrinsic uniformity is one of the basic tests to check the status of the detectors of gamma cameras, and as such is contained in RD 1 841/1997 Quality Control in Nuclear Medicine; Protocolo NEMA para el calculo de la uniformidad intrinsica en gamma-camaras: aplicacion y comparacion con el software del fabricante

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez Soto, X. L.; Gonzalez Ruiz, C.; Lopez-Boto, M. A.; Polo Cezon, R.

    2015-07-01

    Spanish Protocol Quality Control Instrumentation in Nuclear Medicine provides guidelines for conducting this test, similar to those established in the NEMA protocol NEMA Protocol for the calculation of the uniformity intrinsic in GAMMA cameras: application and comparison with the SQFTWARE of the manufacturer. it is advisable to conduct a study to ensure that the results for the test of intrinsic uniformity of the software provided by the equipment manufacturer are equivalent to those obtained by applying the protocol recommended by the SEFM before using this software for performing quality control. (Author)

  5. Coefficients calculations of conversion of cancer risk for occupational exposure using Monte Carlo simulations in cardiac procedures of interventionist radiology; Calculo de coeficientes de conversao de risco de cancer para exposicoes medicas e ocupacionais usando simulacoes Monte Carlo em procedimentos cardiacos de radiologia intervencionista

    Energy Technology Data Exchange (ETDEWEB)

    Santos, William S.; Neves, Lucio P.; Perini, Ana P.; Caldas, Linda V.E., E-mail: wssantos@ipen.br, E-mail: lpneves@ipen.br, E-mail: aperini@ipen.br, E-mail: lcaldas@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Maia, Ana F., E-mail: afmaia@ufs.br [Universidade Federal de Sergipe (UFS), Sao Cristovao, SE (Brazil). Dept. de Fisica

    2014-07-01

    Cardiac procedures are among the most common procedures in interventional radiology (IR), and can lead to high medical and occupational exposures, as in most cases are procedures complex and long lasting. In this work, conversion coefficients (CC) for the risk of cancer, normalized by kerma area product (KAP) to the patient, cardiologist and nurse were calculated using Monte Carlo simulation. The patient and the cardiologist were represented by anthropomorphic simulators MESH, and the nurse by anthropomorphic phantom FASH. Simulators were incorporated into the code of Monte Carlo MCNPX. Two scenarios were created: in the first (1), lead curtain and protective equipment suspended were not included, and in the second (2) these devices were inserted. The radiographic parameters employed in Monte Carlo simulations were: tube voltage of 60 kVp and 120 kVp; filtration of the beam and 3,5 mmAl beam area of 10 x 10 cm{sup 2}. The average values of CCs to eight projections (in 10{sup -4} / Gy.cm{sup 2} were 1,2 for the patient, 2,6E-03 (scenario 1) and 4,9E-04 (scenario 2) for cardiologist and 5,2E-04 (scenario 1) and 4,0E-04 (Scenario 2) to the nurse. The results show a significant reduction in CCs for professionals, when the lead curtain and protective equipment suspended are employed. The evaluation method used in this work can provide important information on the risk of cancer patient and professional, and thus improve the protection of workers in cardiac procedures of RI.

  6. Variación de los índices de saturación en función del calculo de coeficientes de actividad. su aplicación a las fases mineralogicas de las lagunas de Monegros (Zaragoza, España

    Directory of Open Access Journals (Sweden)

    Mandado, J.

    1991-12-01

    Full Text Available Application of WATEQ4F and SOLMINEQ.88 speciation-solubility codes to brines fmm La Playa in Los Monegros (Zaragoza has been used to contrast different approaches in activity calculations and to determinate saturation indexo The evaporation process increases ionic force and activities of dissolved species but with notorious singularities; the salt precipitation is theoretically reached only with ionic forces greater than 3. Pitzer's formulation included in SOLMINEQ.88 options is the best one for approximation to natural observations, and WATEQ4F also shows good concordance with evolutive trendLa aplicación de los códigos de especiación WATEQ4F y SOLMINEQ.88 a los datos del sistema natural de la laguna de La Playa en Los Monegros (Zaragoza proporcionados por autores previos, ha servido para contrastar distintas opciones de cálculo. Como era de esperar, el aumento de la Fuerza Iónica con el avance de la evaporación proporciona un incremento de la actividad de las especies disueltas (y una disminución de la del agua sea cual sea la opción escogida, aunque existen notorias diferencias y singularidades. Los Indices de Saturación de las especies minerales presentes en el sistema (calcita, dolomita, yeso, anhidrita, thenardita y halita muestran que la espectacular precipitación de sales observada en el fondo de las lagunas sólo se consigue, de acuerdo con la serie de desmuestre tratada, cuando la evaporación está ya bastante avanzada y con Fuerzas Iónicas mayores de 3. De todas las opciones de cálculo analizadas, la que proporciona unos resultados más acordes con lo observado en el medio natural es la correspondiente al SOLMINEQ.88 con el desarrollo de ecuaciones de Pitzer, aunque también el WATEQ4F muestra concordancias en cuanto a las tendencias.

  7. Evaluation and temporal evolution of image quality and its dosimetric effect on the dose distributions calculated on megavoltage CT images from tomotherapy unit; Evaluacion y evolucion temporal de la calidad de imagen y su impacto dosimetrico en el calculo de distribuciones realizadas sobre imagenes de megavoltaje de la unidad de tomoterapia

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez Rubio, P.; Castro Tejero, P.; Rodriguez Romero, R.

    2015-05-01

    Over a period of five years the temporal evolution of the image quality parameters and the linearity of the Hounsfield units (HU) of megavoltage studies (MVCT) were analyzed as well as the influence of the actions of the field service engineer. Furthermore the dosimetric impact of HU variation as a result of such actions was studied in three clinical cases (prostate, head and neck, and lung). MVCT images showed an appropriate image quality for image-guided radiotherapy and adaptive radiation therapy despite its lower contrast to noise ratio in comparison to the kilo voltage studies. Because of temporal stability of the linearity between HU and mass density, MVCT studies were appropriate for dose calculation especially to avoid artifacts due to high density metallic structures. Target changes had the largest effect on the imaging parameters analyzed. Variations around 30 and 50 HU for water and bone, respectively, led to a dosimetric error of 1% for the studied locations; while discrepancies about 6% were found as a result of higher HU changes. (Author)

  8. The financial impact of the incorporation of IMRT and RapidArc™ techniques on shielding calculation of a linear accelerator; O impacto financeiro da incorporacao das tecnicas de IMRT e RapidArc™ no calculo de blindagem de um acelerador linear

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Maira R.; Silveira, Thiago B.; Garcia, Paulo L.; Trindade, Cassia; Martins, Lais P.; Batista, Delano V.S., E-mail: mairafisica@gmail.com [Instituto Nacional do Cancer (INCA), Rio de Janeiro, RJ (Brazil)

    2013-08-15

    Given the new methodology introduced in the shielding calculation due to recent modulated techniques in radiotherapy treatment, it became necessary to evaluate the impact of changes in the accelerator routine using such techniques. Based on a group of 30 patients from the National Cancer Institute (INCA) the workload multiplier factors for intensity modulated radiotherapy (IMRT factor) and for RapidArc™ (RA factor) were established. Four different routines in a 6 MV generic accelerator were proposed to estimate the impact of these modified workloads in the building cost of the secondary barriers. The results indicate that if 50% of patients are treating with IMRT, the secondary barrier becomes 14,1% more expensive than the barrier calculated for conformal treatments exclusive. While RA, in the same proportion, leads to a barrier only 3,7% more expensive. Showing that RA can, while reducing treatment time, increase the proportion of patients treated with modulation technique, without increasing the cost of the barrier, when compared with IMRT. (author)

  9. Development of a computer program of fast calculation for the pre design of advanced nuclear fuel 10 x 10 for BWR type reactors; Desarrollo de un program de computo de calculo rapido para el prediseno de celdas de combustible nuclear avanzado 10 x 10 para reactores de agua en ebullicion

    Energy Technology Data Exchange (ETDEWEB)

    Perusquia, R.; Montes, J.L.; Ortiz, J.J. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)]. e-mail: mrpc@nuclear.inin.mx

    2005-07-01

    In the National Institute of Nuclear Research (ININ) a methodology is developed to optimize the design of cells 10x10 of assemble fuels for reactors of water in boil or BWR. It was proposed a lineal calculation formula based on a coefficients matrix (of the change reason of the relative power due to changes in the enrichment of U-235) for estimate the relative powers by pin of a cell. With this it was developed the computer program of fast calculation named PreDiCeldas. The one which by means of a simple search algorithm allows to minimize the relative power peak maximum of cell or LPPF. This is achieved varying the distribution of U-235 inside the cell, maintaining in turn fixed its average enrichment. The accuracy in the estimation of the relative powers for pin is of the order from 1.9% when comparing it with results of the 'best estimate' HELIOS code. With the PreDiCeldas it was possible, at one minimum time of calculation, to re-design a reference cell diminishing the LPPF, to the beginning of the life, of 1.44 to a value of 1.31. With the cell design with low LPPF is sought to even design cycles but extensive that those reached at the moment in the BWR of the Laguna Verde Central. (Author)

  10. Calculation of the Inelastic Scattering of Neutrons from Polyethylene and Water; Calcul de la diffusion inelastique des neutrons par le polyethylene et l'eau; Raschet neuprugogo rasseyaniya nejtronov poliehtilenom i vodoj; Calculo de la dispersion inelastica de neutrones por polietileno y agua

    Energy Technology Data Exchange (ETDEWEB)

    Goldman, D T; Federighi, F D [Knolls Atomic Power Laboratory, General Electric Company, Schenectady, NY (United States)

    1963-01-15

    A model for the calculation of the scattering of thermal neutrons from chemical system was proposed by Nelkin. This model considered the actual dynamics of the scattering system as composed of a set of oscillatory motions, each describable by a Hamiltonian which commuted with each of the others. It was then possible to express the differential scattering cross-section in closed form. This model has been used to calculate the scattering of neutrons by water. Some care must be taken in performing the numerical integration over angle and energy. The scattering model has been extended to the calculation of neutron scattering from polyethylene C{sub n}H{sub 2n}. Analogous levels of polyethylene can be noted at 0.089 eV, 0.182 eV, 0.354 eV, and 0.533 eV. The differential and total cross-sections have been calculated for the scattering and the latter has been seen to be in reasonable agreement with experiment at room temperature. Scattering kernels have been calculated for a number of temperatures and where possible the results have been compared with experiment. In addition, neutron flux spectra and diffusion lengths have been calculated using the equations of reactor physics. Comparison of these Results with experimental data indicates that such integral measurements are indicative of at least the gross features of the scattering system and should be analysed in conduction with the detailed differential cross-section results. (author) [French] Nelkin a propose un modele pour calculer la diffusion de neutrons thermiques dans des systemes chimiques. Dans ce mod and le on considere que la dynamique reelle du systeme de diffusion se compose d'un ensemble de mouvements oscillatoires, chaque mouvement pouvant 6tre decrit par un hamiltonien commutant avec chacun des autres. Il est alors possible d'exprimer la section efficace differentielle de diffusion sous une forme fermee. Les auteurs ont employe ce modele pour calculer la diffusion des neutrons par l'eau. Il faut prendre quelques precautions lorsque l'on fait l'integration numerique par rapport aux angles et aux energies. Le modele de diffusion a ete etendu aux calculs de la diffusion des neutrons par le polyethylene C{sub n}H{sub 2n}. On note des niveaux analogues a 0,089 eV, 0,182 eV, 0,354 eV et 0,533 eV. Les auteurs ont calcule les sections efficaces diffe- rentielle et totale pour la diffusion et ils ont constate que la seconde est en bon accord avec l'experience a la temperature du laboratoire. Ils ont calcule des noyaux de diffusion pour un certain nombre de temperatures et, chaque fois qu'il etait possible de le faire, ils ont compare les resultats aux experiences. De plus, ils ont calcule les spectres de flux de neutrons et les longueuts de diffusion en se fondant sur les equations de la physique des reacteurs. En comparant ces resultats et les donnees experimentales, on constate que ces mesures integrales donnent au moins des indications generales sur les caracteristiques du systeme de diffusion et qu'il conviendrait de les analyser en tenant compte des resultats detailles relatifs aux sections efficaces different tielles. (author) [Spanish] Nelkin propuso un modelo para calcular la dispersion de neutrones termicos por sistemas quimicos. Con arreglo a este modelo, la dinamica real del sistema dispersante se consideraba compuesta por una serie de movimientos oscilatorios cada uno de los cuales podia describirse por un hamiltoniano que conmuta con los hamiltonianos de los otros movimientos oscilatorios. Ello permitiria; expresar la seccion eficaz diferencial de dispersion en forma cerrada. Los autores han utilizado este modelo para calcular la dispersion de neutrones por el agua. Debe procederse con cierto cuidado al efectuar la integracion numerica respecto del angulo y de la energia. El modelo sella utilizado tambien para calcular la dispersion de neutrones por polietileno (C{sub n}H{sub 2n}). A 0,089 eV, 0,182 eV, 0.354 eV y 0,533 eV, se observan niveles analogos en el polietileno. Se ha calculado la seccion eficaz dife- rencial y total de dispersion y la ultima parece concordar satisfactoriamente con los resultados de experimentos realizados a temperatura ambiente. Se han.calculado los nucleos de dispersion para varias temperaturas y, cuando es posible, los resultados se comparan con los de los experimentos. Ademas se han calculado los espectros de nujo neutronico y las longitudes de difusion utilizando para ello las ecuaciones de fisica de reactores. La comparacion de estos resultados con los datos experimentales muestra que tales mediciones integrales constituyen por lo menos un indice de las caracteristicas generales del sistema dispersante y deben analizarse conjuntamente con los resultados detallados relativos a Ies secciones eficaces diferenciales. (author)

  11. Calculation of electromagnetic fields in electric machines by means of the finite element. Algorithms for the solution of problems with known total densities. Pt. 2; Calculo de campos electromagneticos en maquinas electricas mediante elemento finito. Algoritmos para la solucion de problemas con densidades totales conocidas. Pt. 2

    Energy Technology Data Exchange (ETDEWEB)

    Rosales, Mauricio F [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1988-12-31

    This article is based in the electromagnetic modeling presented in the first part. Here are only considered the magnetic systems or electric systems in closed regions with moving or axial symmetry, whose total current density or total electric load density is known. The algorithms that have been implanted in the software CLIIE-2D of the Instituto de Investigaciones Electricas (IIE) are developed in order to obtain numerical solutions for these problems. The basic systems of algebraic equations are obtained by means of the application of the Galerkin method in the discreteness of the finite element with first order triangular elements. [Espanol] Este articulo se basa en la modelacion electromagnetica presentada en la primera parte. Aqui solo se consideran sistemas magneticos o sistemas electricos en regiones cerradas con simetria translacional o axial, cuya densidad de corriente total o densidad de carga electrica total es conocida. Se desarrollan los algoritmos que se han implantado en el programa de computo CLIIE-2D, del Instituto de Investigaciones Electricas (IIE) con el fin de obtener soluciones numericas para estos problemas. Los sistemas basicos de ecuaciones algebraicas se obtienen mediante la aplicacion del metodo de Galerkin en la discretizacion de elemento finito con elementos triangulares de primer orden.

  12. Approach to the calculation of energy deposition in a container of fuel irradiated by the neutronic codes coupling fluid-dynamics; Aprpoximacion al calculo de la deposicion energetica en un contenedor de combustible irradiado mediante el acoplamiento de codigos neutronico fluido-dinamicos

    Energy Technology Data Exchange (ETDEWEB)

    Hueso, C.; Aleman, A.; Colomer, C.; Fabbri, M.; Martin, M.; Saellas, J.

    2013-07-01

    In this work identifies a possible area of improvement through the creation of a code of coupling between deposition energy codes which calculate neutron (MCNP), and data from heading into fluid dynamics (ANSYS-Fluent) or codes thermomechanical, called MAFACS (Monte Carlo ANSYS Fluent Automatic Coupling Software), being possible to so summarize the process by shortening the needs of computing time, increasing the precision of the results and therefore improving the design of the components.

  13. Implementation of a model of atmospheric dispersion and dose calculation in the release of radioactive effluents in the Nuclear Centre; Implementacion de un modelo de dispersion atmosferica y calculo de dosis en la liberacion de efluentes radiactivos en el Centro Nuclear

    Energy Technology Data Exchange (ETDEWEB)

    Cruz L, C. A.

    2015-07-01

    In the present thesis, the software DERA (Dispersion of Radioactive Effluents into the Atmosphere) was developed in order to calculate the equivalent dose, external and internal, associated with the release of radioactive effluents into the atmosphere from a nuclear facility. The software describes such emissions in normal operation, and not considering the exceptional situations such as accidents. Several tools were integrated for describing the dispersion of radioactive effluents using site meteorological information (average speed and wind direction and the stability profile). Starting with the calculation of the concentration of the effluent as a function of position, DERA estimates equivalent doses using a set of EPA s and ICRP s coefficients. The software contains a module that integrates a database with these coefficients for a set of 825 different radioisotopes and uses the Gaussian method to calculate the effluents dispersion. This work analyzes how adequate is the Gaussian model to describe emissions type -puff-. Chapter 4 concludes, on the basis of a comparison of the recommended correlations of emissions type -puff-, that under certain conditions (in particular with intermittent emissions) it is possible to perform an adequate description using the Gaussian model. The dispersion coefficients (σ{sub y} and σ{sub z}), that using the Gaussian model, were obtained from different correlations given in the literature. Also in Chapter 5 is presented the construction of a particular correlation using Lagrange polynomials, which takes information from the Pasquill-Gifford-Turner curves (PGT). This work also contains a state of the art about the coefficients that relate the concentration with the equivalent dose. This topic is discussed in Chapter 6, including a brief description of the biological-compartmental models developed by the ICRP. The software s development was performed using the programming language Python 2.7, for the Windows operating system (the XP version or later). And several tools were integrated using the Tk inter library and graphics using Matplotlib. DERA generates files with .xls extension, an each file contains data tabulated as a function of distance for scattering coefficients and concentration and dose equivalent, both external and internal. It also contains a module to represent iso curves using the mapping tool Google Earth, using files with kml extension, generated with Python. A module that allows the coupling between the data from the meteorological tower and emission registration system was also developed. Such coupling is carried out through a system of folders and files, where emission times are specified, in order to calculate both, external and internal, annual equivalent dose. The 5 modules of the software and the technical description of development is presented in Chapter 7. It is included a methodology for verification and validation of the developed software. In the case of verification, a set of problems proposed in the literature was computed, and was verified the correct integration of the set of coefficients proposed by the EPA and the ICRP. With respect to validation, a graphical analysis between the interpolation developed, and PGT curves was performed. These topics are described in detail in Chapter 8. Finally this work is presented in such a way that serves to guide to the incipient effort to develop computational and portable tools, serving as a prelude to the future integration of more advanced methods of dispersion, or updating the set of coefficients proposed by the ICRP and EPA. (Author)

  14. Retention of Radionuclides by Infants: I. Study Techniques and Error Evaluation; Retention des Radionucleides chez les Enfants en bas Age: I. Methodes de Recherche et Evaluation des Erreurs; 0417 0410 0414 ; Retencion de Radionuclidos en los Ninos de Pecho: I. Tecnicas de Estudio y Calculo del Error

    Energy Technology Data Exchange (ETDEWEB)

    Straub, C. P.; Kahn, B.; Wellman, H. N.; Telles, N. C.; Seltzer, R. A. [Radiological Health Research Activities, Robert A. Taft Sanitary Engineering Center, US Public Health Service, Department Of Health, Education and Welfare, Cincinnati, OH (United States)

    1964-11-15

    Retention of radionuclides and stable chemicals in infants aged 1 to 11 months has been measured since 1960. Infants volunteered by staff members for study in their-respective home environments were selected,after consultation with the family paediatrician and our staff physician. The infants were fed commercially prepared prepackaged foods ad lib; in terms of quantity and kind These foods, the air breathed, and the water-used directly and in preparation of the formula constituted the normal intake of radionuclides and stable chemicals of interest. Aliquots of the food, water, diapers, and paper tissues used are analysed. Excreta were collected in disposable diapers, and separated into those containing urine or faeces. Retention of the following radionuclides and stable elements was or will be determined: strontium-90, strontium-89, caesium-137, radium-226, calcium, strontium, phosphorus, and potassium. The study differs from previous ones in several ways. The radionuclides and stable elements were at normally encountered concentrations and in their normally encountered chemical forms. Air, and water contaminated at environmental levels and commercially available-food materials were the only sources of intake, since no radionuclides or stable chemicals were, added to the diet. The infants studied were normal, healthy (not hospitalized) youngsters in their home environments. The major problems in this study consisted of (1) controlling and maintaining records of all of the food intake, (2) collecting all-of the excreta, (3) obtaining an excreta-sample large enough for accurate measurement of the radionuclide and stable components contained; and (4) measuring radionuclide and stable component concentrations in the intake and excreta accurately enough that significant retention values could be computed. A case worker was utilized for control of intake and excreta information and an electronic computer for data processing. Intake values of the analysed components were checked by comparing ''phantom meals'' with computed amounts based on aliquots. A special paper diaper with a low. stable strontium, concentration was developed and utilized. Calcium and phosphorus retention values were computed.and are now available for 30 infants. Strontium-90 retention relative to calcium was found to be higher in infants than in adults. (author) [French] Les auteurs ont mesure-depuis 1960 la retention de radionucleides et d'elements stables chez des enfants ages de 1 a 11 mois. Ils ont choisi les sujets apres consultation du pediatre de famille et du medecin de l'etablissement, parmi des enfants en bas age mis benevolement a leur disposition par des membres du personnel, en vue d'une etude dans le milieu familial. Ces enfants ont{sup e}te nourris selon leurs besoins et leurs gouts avec des preparations alimentaires conditionnees du commerce. Ces preparations renfermaient, avec l'air respire et l'eau consommee directement ou utilisee pour La confection des repas, toutes les quantites absorbees des radionucleides et des elements stables etudies. Les auteurs ont analyse des parties aliquotes des aliments, de l'eau, des couches et des serviettes en papier utilises. Ils ont recueilli les excreta dans des couches non reutilisables en separant celles qui contenaient l'urine de celles qui contenaient les feces. Ils ont determine ou determineront la retention des radionucleides et elements stables suivants: strontium 90, strontium 89, cesium 137, radium 226, calcium, strontium, phosphore et potassium. Cette etude differe en plusieurs points des etudes precedentes. Les radionucleides et elements stables se trouvaient a leur taux de concentration normal et dans leurs combinaisons chimiques habituelles. L'air et l'eau dont le taux de contamination etait le taux normal du milieu et les produits alimentaires du commerce ont. ete les seules sources d'absorption, aucun radionucleide ni element stable n ayant ete ajoute au regime. Les enfants en bas age observes etaient des sujets normalement sains (jamais hospitalises), vivant dans leur milieu familial. Les principaux problemes a resoudre au cours de cette etude portaient sur les operations suivantes: a) Verifier et comptabiliser toutes les quantites de produits alimentaires ingerees; b) Recueillir tous les excreta ; c) Prelever un echantillon d'excreta assez volumineux pour permettre un dosage precis des radionucleides et des elements stables qu'il contenait; d) Mesurer les concentrations de radionucleides et d'elements stables dans les substances absorbees et dans les excreta, de facon assez precise pour pouvoir calculer des valeurs significatives de la retention. Les auteurs ont eu recours a un enqueteur pour la verification des renseignements sur les quantites absorbees et les excreta, et ont utilise un ordinateur pour le traitement des donnees. Ils ont controle les quantites absorbees des elements etudies en comparant des 'repas fantomes' aux quantites calculees d'apres les parties aliquotes. Ils ont mis au point et utilise des couches en papier special ayant une faible concentration en strontium stable. Ils ont calcule la retention du phosphore et du calcium et ils disposent des valeurs correspondantes pour 30 enfants en bas age. Ils ont constate que le rapport entre la retention du strontium 90 et celle du calcium etait plus eleve chez les enfants en bas age que chez les adultes. (author) [Spanish] Desde 1960 se viene midiendo la retencion de ciertos radionuclidos y elementos estables en los niflos de pecho de uno a once meses. Los niflos, puestos a disposicion voluntariamente por funcionarios para el estudio en el ambiente familiar, se seleccionaron previa consulta con el pediatra de la familia y el medico de la institucion de los autores. Los ninos consumen alimentos de tipo comercial corriente, ya preparados y empaquetados, sin restriccion en lo que se refiere a cantidad y calidad. Estos productos alimenticios, el aire inhalado y el agua utilizada directamente y en preparacion del biberon constituyen la absorcion normal de radionuclidos y de elementos estables de interes. Se analizan partes alicuotas de los productos alimenticios, del agua, de los panales y del papel higienico utizados. Las excreta se recogen en panales que se desechan despues de utilizados, separandose los que contienen orina delos que contienen heces. Se ha determinado o se determinara la retencion de los siguientes radionuclidos y elementos estables: estroncio-90, estroncio-89, cesio-137, radio-226, calcio, estroncio, fosforo y potasio. El estudio difiere en varios aspectos de los anteriormente realizados. Los radionuclidos y elementos estables se presentan en concentraciones y formas quimicas normales. Las sustancias absorbidas provienen exclusivamente del aire y del agua, cuyo grado de contaminacion es el mismo que el del medio ambiente, y de los alimentos que se adquieren en el comercio, pues ningun otro radionuclido ni elemento estable se anade a dicha dieta. Los ninos examinados disfrutan de salud normal (no estan hospitalizados) y permanecen en el ambiente familiar. Los principales problemas de este estudio consistieron en: a) llevar cuenta y razon de todos los alimentos ingeridos, b) recoger todas las excreta, c) obtener una muestra de las excreta suficientemente grande para poder-determinar cuantitativamente los radionuclidos y elementos estables contenidos, d) medir las concentraciones de radionuclidos y elementos estables en los alimentos y en las excreta con exactitud suficiente para poder determinar los valores significativos de retencion. Con objeto de fiscalizar la informacion relativa a alimentos ingeridos y a excreciones se utilizaron los servicios de una persona dedicada especialmente a esa tarea, recurriendose a una calculadora electronica para la elaboracion de los datos. Los valores de ingestion de los componentes analizados se han comprobado comparando 'comidas tipo de referencia' con las cantidades calculadas partiendo de las partes alicuotas analizadas. Se ha preparado y utilizado un panal de papel especial con baja concentracion de estroncio estable. Se han calculado los valores de retencion para el calcio y el fosforo en el caso de 30 ninos. Las observaciones efectuadas demuestran que la retencion relativa de estroncio-90, referida al calcio, es mas elevada en los ninos que en los adultos. (author) [Russian] Nachinaja s 1960 goda provoditsja izmerenie stepeni zaderzhki radioizotopov i ustojchivyh himicheskih soedinenij u detej v vozraste ot 1 goda do 11 let. Za det'mi s so glasija roditelej velis' nabljudenija v sootvetstvujushhej domashnej srede, deti otbiralis' posle konsul'tacii s detskim vrachom, lechivshim rebenka, i vrachom laboratorii. Deti pitalis' gotovymi produktami ad lib opredelennogo kachestva i assortimenta. Pishhevye produkty, vdyhaemyj vozduh i voda, ispol'zuemye neposredstvenno i v processe podgotovki formuly, javljalis' istochnikom normal'nogo postuplenija v organizm izuchaemyh radioizotopov i ustojchivyh himicheskih soedinenij. Proizvodilsja'analiz obrazcov pishhevyh produktov, vody, ispol'zuemyh salfetok i bumagi. Vydelenija sobiralis' v podlezhashhie udaleniju salfetki, otdel'no mocha i kal. Opredeljalos' ili budet opredeljat'sja zaderzhka sledujushhih radioizotopov i ustojchivyh jelementov: stroncij-90, stroncij-89, cezij-137, radij-226, kal'cij, stroncij, fosfor i kalij. Jeti issledovanija znachitel'no otlichajutsja ot predydushhih. Radioizotopy i ustojchivye jelementy nahodilis' v obychnyh koncentracijah i v obychno vstrechajushhihsja himicheskih formah. Vozduh i voda, zagrjaznennye do urovnja okruzhajushhej sredy, i imejushhiesja v prodazhe pishhevye produkty javljalis' edinstvennym istochnikom pogloshhenija, poskol'ku nikakie radioizotopy i ustojchivye himicheskie soedinenija ne dobavljalis'. Issleduemye deti predstavljali soboj obychnyh zdorovyh (negospital'zirovannyh) detej v ih obychnoj domashnej srede. Osnovnye problemy pri provedenii jetih issledovanij zakljuchalis' v 1) kontrolirovanii i registracii vsej potrebljaemoj pishhi, 2) sbore vseh vydelenij, 3) poluchenii dostatochno bol'shih obrazcov vydelenij dlja tochnogo izmerenija soderzhanija radioizotopov i ustojchivyh komponentov, i 4) dostatochno tochnom izmerenii koncentracij pogloshhaemyh i vydeljaemyh radioizotopov i ustojchivyh komponentov, chtoby mozhno bylo poluchit' dostovernye velichiny zaderzhki izotopov. Dlja sbora informacii o pogloshenii i vydelenii i dlja obrabotki dannyh byl privlechen special'nyj sotrudnik i ispol'zovana jelektronnaja schetnaja mashina. Velichiny pogloshhenija analiziruemyh komponentov proverjalis' putem sravnenija ''kontrol'nyh obrazcov pishhi'' s raschetnymi dannymi, poluchennymi pri izmerenii obrazcov. Ispol'zovalis' special'nye bumazhnye salfetki s nizkoj koncentraciej ustojchivogo stroncija. Byli rasschitany velichiny zaderzhki kal'cija i fosfora dlja 30 detej. Ustanovleno, chto zaderzhka stroncija-90 po sravneniju s kal'ciem u detej bol'she, chem u vzroslyh. (author)

  15. Some Problems of Calculation and Design of High-Activity Gamma Units; Quelques aspects du calcul et de l'etablissement de projets d'installations puissantes emettrices de rayonnement gamma; Nekotorye voprosy rascheta i proektirovaniya moshchnykh gamma-ustanovok; Algunos aspectos del calculo y construccion de instalaciones de irradiacion gamma de elevada intensidad

    Energy Technology Data Exchange (ETDEWEB)

    Bibergal, A V; Leshchinsky, N I; Margulis, U Ya; Khrushev, V G [Academy of Sciences of the USSR, Moscow, Union of Soviet Socialist Republics (Russian Federation)

    1960-07-15

    The report describes the principal requirements for gamma units intended for various purposes. Several methods of calculating the dose fields for various forms of irradiators are given, as well as graphs, nomograms and formulae to estimate the amount of gamma-ray dose absorbed by the irradiated object from cobalt-60 and caesium-137. Some of the calculated data have been confirmed by experiment. The advantages of irradiators of various geometry employed in experimental and commercial units are discussed. The irradiation technique for various objects is analyzed and the optimum irradiation conditions (radiation utilization factor, dose field homogeneity, etc.) are discussed. Several rational shielding systems are suggested to simplify irradiation process and recharging, and to reduce the cost of design and operation. (author) [French] Resume Cette communication expose les conditions fondamentales auxquelles doivent satisfaire les installations emettrices de rayonnement gamma, destinees, a divers usages. Elle explique certaines methodes pour le calcul des champs recevant une dose determinee en fonction de la forme du dispositif d'irradiation; elle contient des courbes, des nomogrammes et des formules permettant de calculer la valeur de la dose de rayons gamma du cobalt-60 et du cesium-137 recue par l'echantillon soumis a l'irradiation. Certaines donnees etablies par le calcul ont ete confirmees experimentalement. On examine l'utilite d'employer des dispositifs d'irradiation de configurations variees dans des installations experimentales et des installations industrielles. Les auteurs examinent la technologie de l'irradiation de divers echantillons en vue de choisir les conditions optimales d'irradiation (facteur d'utilisation du rayonnement, uniformite du champ recevant une dose determinee, etc.). Quelques systemes rationnels de protection, simplifiant le processus d'irradiation, sont exposes ainsi que des methodes permettant un echange de charge dans les installations et reduisant le cout de la construction et de l'exploitation. (author) [Spanish] En este informe se indican los requisitos esenciales que deben reunir las instalaciones de irradiacion gamma destinadas a distintos usos. Se describen varios metodos para calcular campos de distintas intensidades en funcion de la forma de la fuente de cobalto-60 y cesio-137 empleada y se facilitan graficos, nomogramas y formulas que permiten determinar el valor de la dosis de rayos gamma absorbida por el objeto irradiado. Algunos de los datos calculados se han confirmado experimentalmente. Se examinan los usos mas convenientes de una serie de dispositivos de irradiacion de distintas configuraciones en instalaciones experimentales e industriales. Los autores estudian asimismo los procedimientos de irradiacion de diferentes muestras, que se aplican con el proposito de poder elegir unas condiciones de irradiacion optimas (coeficiente de aprovechamient o de la radiacion, uniformidad del campo de irradiacion, etc.), La memoria describe tambien algunos sistemas racionales de proteccion que simplifican las operaciones de irradiacion, asi como los dispositivos que permiten cambiar la carga y reducir de este modo los costos de construccion y de explotacion de las instalaciones. (author) [Russian] V doklade sformulirovan y osnovnye trebovaniya, pred{sup y}avlyaemye k gamma-ustanovkam razlichnogo naznacheniya. Provodyatsya nekotorye metody rascheta doznykh polej dlya razlichnykh form obluchatelej, a takzhe grafiki, nomogrammy i formuly, pozvolyayushchie poluchit' znacheniya pogloshchennoj dozy gamma-luchej kobal'ta-60 i tseziya-137 v obluchaemom ob{sup e}kte. Nekotorye raschetnye dannye podtverzhdayutsya ehksperimentami. Rassmatrivaets ya tselesoobraznost ' ispol'zovani ya obluchatelej razlichnykh konfiguratsij , primenyaemykh v ehksperimental'nykh i proizvodstvennykh ustanovkakh. Obsuzhdaetsya tekhnologiya oblucheniya razlichnykh ob{sup e}ktov s tsel'yu vybora optimal'nykh uslovij radiatsionnogo vozdejstviya (koehffitsient ispol'zovaniya izlucheniya, ravnomernost' doznogo polya i dr.). Privodyatsya nekotorye ratsional'nye skhemy zashchity, uproshchayushchie protsess oblucheniya i metody perezaryadki ustanovok, a takzhe udeshevlyayushchie konstruktsiyu i ehkspluatatsiyu ustanovok. (author)

  16. Comparison in the calculation of committed effective dose using the ICRP 30 and ICRP 60 models for a repeated incorporation by inhalation of I-125; Comparacion en el calculo de la dosis efectiva comprometida usando los modelos del ICRP 30 y del ICRP 60 para una incorporacion repetida por inhalacion de I-125

    Energy Technology Data Exchange (ETDEWEB)

    Carreno P, A.L.; Cortes C, A. [CNSNS, Dr. Barragan 779, Col. Narvarte, Mexico D.F. (Mexico); Alonso V, G.; Serrano P, F. [IPN, Edificio de Fisica Avanzada Zacatenco, 07300 Mexico D.F. (Mexico)

    2005-07-01

    Presently work, a comparison in the calculation of committed effective dose using the models of the ICRP 30 and those of the ICRP 60 for the analysis of internal dose due to repeated incorporation of I-125 is shown. The estimations of incorporated activity are obtained starting from the proportionate data for an exercise of inter comparison, with which it should be determined the internal dose later on. For to estimate the initial activity incorporated by repeated dose was assumed that this it was given through of multiple individual incorporations which happened in the middle points of the monitoring periods. The results using the models of the ICRP 30 and of the ICRP 60 are compared and the causes of the differences are analyzed. (Author)

  17. Study of the hyperfine magnetic field acting on Ce probes substituting for the rare earth and the magnetic ordering in intermetallic compounds RAg (R=rare earth) by first principles calculations; Estudo do campo hiperfino magnetico na sonda de Ce colocada nos compostos intermetalicos do tipo RAg (R=terra rara) e do ordenamento magnetico desses compostos usando calculos de primeiros principios

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Luciano Fabricio Dias

    2006-07-01

    In this work the magnetic hyperfine field acting on Ce atoms substituting the rare-earths in R Ag compounds (R = Gd e Nd) was studied by means of first-principles electronic structure calculations. The employed method was the Augmented Plane Waves plus local orbitals (APW+lo), embodied in the WIEN2k program, within the framework of the Density Functional Theory (DFT) and with the Generalized Gradient Approximation (GGA) for the exchange and correlation potential. The super-cell approach was utilized in order to simulate for the Ce atoms acting as impurities in the R Ag matrix. In order to improve for correlation effects within the 4f shells, a Hubbard term was added to the DFT Hamiltonian, within a procedure called GGA+U. It was found that the magnetic hyperfine field (MHF) generated by the Ce 4f electron is the main component of the total MHF and that the Ce 4f ground state level is probably a combination of the m{sub l} = -2 and m{sub l} = -1 sub-levels. In addition, the ground-state magnetic structure was determined for Ho Ag and Nd Ag by observing the behavior of the total energy as a function of the lattice volume for several possible magnetic ordering in these compounds, namely, ferromagnetic, and the (0,0,{pi}), ({pi},{pi},0) and (({pi},{pi},{pi}) types of anti-ferromagnetic ordering of rare-earth atoms. It was found that the ground-state magnetic structure is anti-ferromagnetic of type ({pi},{pi},0) for both, the Ho Ag and Nd Ag compounds. The energy difference of the ferromagnetic and antiferromagnetic ordering is very small in the case of the Nd Ag compound. (author)

  18. Calculation of electrical and magnetic field in electric power transmission lines aiming project optimization, environmental impact and alternatives comparisons; O calculo dos campos eletrico e magnetico de L.T. visando a otimizacao do projeto, o impacto ambiental e a comparacao de alternativas

    Energy Technology Data Exchange (ETDEWEB)

    Portela, Carlos M. [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE); Moreno O, German [Antioquia Univ., Medellin (Colombia). Dept. de Engenharia Eletrica

    1995-12-31

    The optimization of overhead electric power transmission lines leads to compact projects in which the neighbourhood electric and magnetic field are a critical restriction. The Load Simulation Method enables the reliable calculation of such fields. Presented are equations for the application of such conditions. Results are presented 9 figs., 2 tabs., 10 refs.

  19. Calculus of spatial distribution of absorbed dose to cellular level by Monte Carlo simulation for a radio-labelled peptide with {sup 188}Re and with nuclear internalization : preliminary results; Calculo de la distribucion espacial de dosis absorbida a nivel celular por simulacion Monte Carlo para un peptido radiomarcado con {sup 188}Re y con internalizacion nuclear : resultados preliminares

    Energy Technology Data Exchange (ETDEWEB)

    Rojas C, E. L. [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico); Santos C, C. L. [Universidad Autonoma del Estado de Mexico, Paseo Tollocan y Jesus Carranza, Toluca 50120, Estado de Mexico (Mexico)], e-mail: leticia.rojas@inin.gob.mx

    2009-10-15

    The {sup 188}Re is a radionuclide of radiation gamma emitter, useful in obtaining of gamma-graphic images, but it is also emitter of beta radiations and Auger electrons. A bio-molecule directed to a specific receptor of a cancer cell labeled with a emitter radionuclide of beta particles and Auger electrons, as the {sup 188}Re-Tat-Bombesin, it has the potential to be used in radiotherapy of molecular targets for its capacity to penetrate to cellular nucleus. In this system, the radiation dose is distributed in way located at microscopic levels in sub cellular specific places, where Auger emissions contributes of significant way in absorbed dose. The cellular dosimetry is realized in most of cases, using analytic or semi analytical methods, for example the cellular MIRD methodology. However, it is required to complement these calculations simulating the electrons transport and considering experimental bio kinetics data. Therefore, in this work preliminary results are presented of dosimetric calculation to sub cellular level for {sup 188}Re-Tat-Bombesin by Monte Carlo simulation, using the 2008 version of PENELOPE: PENEASY code. The spatial distribution of absorbed dose in membrane, cytoplasm and nucleus, was calculated with geometry of a cell of 10 {mu}m of diameter, a nucleus of 2 {mu}m of ratio and membrane of 0.2 {mu}m of thickness, considering elementary constitution for each cellular compartment proposal in literature. The total number of disintegrations at sub cellular level was evaluated integrating the activity in function of time starting from experimental bio kinetics data in mamma cancer cells MDA-MB231. The preliminary results show that 46.4% of total disintegrations for unit of captured activity by cell occurs in nucleus, 38.4% in membrane and 15.2% in cytoplasm. The due absorbed dose to Auger electrons for 1 Bq of {sup 188}Re located in cellular membrane were respectively of 1.32E-1 and 1.43E-1 Gy in cytoplasm and nucleus. (Author)

  20. Calculation of absorbed dose for skin contamination imparted by beta radiation through the VARSKIN modified code for 122 interesting isotopes for nuclear medicine, nuclear power plants and research; Calculo de dosis absorbida para contaminacion en piel impartida por radiacion beta mediante el codigo VARSKIN modificado para 122 isotopos de interes para medicina nuclear, plantas nucleares e investigacion

    Energy Technology Data Exchange (ETDEWEB)

    Alvarez R, J T [Depto. de Metrologia, ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    1991-07-01

    In this work the implementation of a modification of the VARSKIN code for calculation of absorbed dose for contamination in skin imparted by external radiation fields generated by Beta emitting is presented. The modification consists on the inclusion of 47 isotopes of interest even Nuclear Plants for the dose evaluation in skin generated by 'hot particles'. The approach for to add these isotopes is the correlation parameter F and the average energy of the Beta particle, with relationship to those 75 isotopes of the original code. The methodology of the dose calculation of the VARSKIN code is based on the interpolation, (and integration of the interest geometries: punctual or plane sources), of the distribution functions scaled doses in water for beta and electrons punctual sources, tabulated by Berger. Finally a brief discussion of the results for their interpretation and use with purposes of radiological protection (dose insurance in relation to the considered biological effects) is presented.