WorldWideScience

Sample records for retention mechanisms viscosity

  1. Gas bubble retention and its effect on waste properties: Retention mechanisms, viscosity, and tensile and shear strengths

    International Nuclear Information System (INIS)

    Gauglitz, P.A.; Rassat, S.D.; Powell, M.R.

    1995-08-01

    Several of the underground nuclear storage tanks at Hanford have been placed on a flammable gas watch list, because the waste is either known or suspected to generate, store, and episodically release flammable gases. Because retention and episodic release of flammable gases from these tanks containing radioactive waste slurries are critical safety concerns, Pacific Northwest Laboratory (PNL) is studying physical mechanisms and waste properties that contribute to the episodic gas release from these storage tanks. This study is being conducted for Westinghouse Hanford Company as part of the PNL Flammable Gas project. Previous investigations have concluded that gas bubbles are retained by the slurry or sludge that has settled at the bottom of the tanks; however, the mechanisms responsible for the retention of these bubbles are not well understood. Understanding the rheological behavior of the waste, particularly of the settled sludge, is critical to characterizing the tendency of the waste to retain gas bubbles and the dynamics of how these bubbles are released from the waste. The presence of gas bubbles is expected to affect the rheology of the sludge, specifically its viscosity and tensile and shear strengths, but essentially no literature data are available to assess the effect of bubbles. The objectives of this study were to conduct experiments and develop theories to understand better how bubbles are retained by slurries and sludges, to measure the effect of gas bubbles on the viscosity of simulated slurries, and to measure the effect of gas bubbles on the tensile and shear strengths of simulated slurries and sludges. In addition to accomplishing these objectives, this study developed correlations, based on the new experimental data, that can be used in large-scale computations of waste tank physical phenomena

  2. Gas bubble retention and its effect on waste properties: Retention mechanisms, viscosity, and tensile and shear strengths

    Energy Technology Data Exchange (ETDEWEB)

    Gauglitz, P.A.; Rassat, S.D.; Powell, M.R. [and others

    1995-08-01

    Several of the underground nuclear storage tanks at Hanford have been placed on a flammable gas watch list, because the waste is either known or suspected to generate, store, and episodically release flammable gases. Because retention and episodic release of flammable gases from these tanks containing radioactive waste slurries are critical safety concerns, Pacific Northwest Laboratory (PNL) is studying physical mechanisms and waste properties that contribute to the episodic gas release from these storage tanks. This study is being conducted for Westinghouse Hanford Company as part of the PNL Flammable Gas project. Previous investigations have concluded that gas bubbles are retained by the slurry or sludge that has settled at the bottom of the tanks; however, the mechanisms responsible for the retention of these bubbles are not well understood. Understanding the rheological behavior of the waste, particularly of the settled sludge, is critical to characterizing the tendency of the waste to retain gas bubbles and the dynamics of how these bubbles are released from the waste. The presence of gas bubbles is expected to affect the rheology of the sludge, specifically its viscosity and tensile and shear strengths, but essentially no literature data are available to assess the effect of bubbles. The objectives of this study were to conduct experiments and develop theories to understand better how bubbles are retained by slurries and sludges, to measure the effect of gas bubbles on the viscosity of simulated slurries, and to measure the effect of gas bubbles on the tensile and shear strengths of simulated slurries and sludges. In addition to accomplishing these objectives, this study developed correlations, based on the new experimental data, that can be used in large-scale computations of waste tank physical phenomena.

  3. Magnetisation processes and magnetic viscosity of mechanically alloyed SmCo5

    International Nuclear Information System (INIS)

    Ding, J.; Smith, P.A.I.; McCormick, P.G.; Street, R.

    1996-01-01

    Mechanically alloyed SmCo 5 materials with coercivities in the range of 50-75 kOe were studied in this work. Irreversible magnetisation processes were investigated by measuring remanences after initial magnetisation and after demagnetisation. A large deviation of the demagnetisation remanence from the Wohlfarth relationship indicated that interactions between grains play an important role in the irreversible magnetisation process. Viscosity tests showed nearly linear relationship between the magnetic field and the viscosity parameter for the initial magnetisation, while the viscosity was not strongly dependent on the field for the demagnetisation. High values of the viscosity parameter, Λ, between 120 to 220 Oe were measured at fields near coercivity. (orig.)

  4. Magnetic viscosity and coercivity mechanisms in sintered and melt spun NdFeB

    International Nuclear Information System (INIS)

    Street, R.; Bingham, D.; Day, R.K.; Dunlop, J.B.

    1988-01-01

    Magnetic viscosity parameters kT/q(=Sv) of sintered and melt spun NdFeB vary with internal field. During initial magnetization of thermally demagnetized specimens signifiant viscosity occurs with melt spun NdFeB but is negligible with sintered NdFeB. Differences in mechanisms of magnetization account for this behaviour

  5. VISCOSE BASED MAGNETIC YARNS – PHYSICAL AND MECHANICAL CHARACTERIZATION

    Directory of Open Access Journals (Sweden)

    GROSU Marian-Cătălin

    2017-05-01

    Full Text Available In the context of the rapid growth in the number of electrical and electronic devices and accessories that emit electromagnetic energy in different frequency bands we present and characterize here several magnetic functionalized viscose twisted yarns. A 100% viscose twisted staple yarn was covered through an in-house developed process with a polymeric solution containing micrometric sized barium hexaferrite magnetic powder. The in-house developed process allows deposition of micrometric thickness polymeric paste layer on the yarn surface. Barium hexaferrite is a hard magnetic material exhibiting high chemical stability and corrosion resistivity, relatively large saturation and residual magnetization and microwave absorbing properties. Five different percentages of the magnetic powder in the polymer solution were used, i.e. ranging from 15 wt% to 45 wt%. Physical characterization shows a very good adherence between the highly hygroscopic viscose staple fibers and the polymeric solution that contains polyvinyl acetate and polyurethane as binders. SEM images evidenced the fact that the polymeric solution penetrated more than 1/3 of the yarn diameter. The concentration of magnetic powder in the polymeric solution has a direct influence on the coating amount, diameter and density. The mechanical characterization of the coated yarns revealed that the breaking force is increasing with increasing magnetic powder content up to o certain value and then decreased because the magnetic layer became stiffer. At the same time, the elongation at brake is decreasing.

  6. Mechanism of viscosity effect on magnetic island rotation

    Energy Technology Data Exchange (ETDEWEB)

    Mikhailovskii, A.B.; Konovalov, S.V. [Institute of Nuclear Fusion, Russian Research Centre ' Kurchatov Institute' , Kurchatov Sq., 1, Moscow (Russian Federation); Pustovitov, V.D. [National Inst. for Fusion Science, Toki, Gifu (Japan); Tsypin, V.S. [Institute of Physics, University of Sao Paulo, Rua do Matao, Travessa R, SP (Brazil)

    2000-04-01

    It is shown that plasma viscosity does not influence the magnetic island rotation directly. Nevertheless, it leads to nonstationarity of the plasma velocity. This nonstationarity is the reason of the viscosity effect on island rotation. (author)

  7. Antioxidative activity, moisture retention, film formation, and viscosity stability of Auricularia fuscosuccinea, white strain water extract.

    Science.gov (United States)

    Liao, Wayne C; Hsueh, Chiu-Yen; Chan, Chin-Feng

    2014-01-01

    This study showed that both water extracts (WAF-W) and ethanol extracts (EAF-W) of Auricularia fuscosuccinea (Montagne) Farlow, white strain (AF-W) demonstrated significantly stronger antioxidative effects than did commercially available Tremella fuciformis sporocarp extracts (WSK; with the exception of EAF-W in terms of superoxide radical scavenging activity levels). The moisture retention capacity of WAF-W is as potent as that of sodium hyaluronate (SHA), but less than that of WSK. No corrugation or fissures were observed in WAF-W film; only the SHA and WSK films demonstrated such effects in low-moisture conditions. The WAF-W solution also exhibited stable viscosity at high temperatures, indicating that the WAF-W film was more stable compared with the SHA and WSK films. WAF-W induced no adverse effects when a hen's egg test was performed on the chorioallantoic membrane (CAM). This study demonstrated that WAF-W exhibits excellent potential as a topical material for skin moisturizing and anti-aging effects.

  8. Mixed retention mechanism of proteins in weak anion-exchange chromatography.

    Science.gov (United States)

    Liu, Peng; Yang, Haiya; Geng, Xindu

    2009-10-30

    Using four commercial weak anion-exchange chromatography (WAX) columns and 11 kinds of different proteins, we experimentally examined the involvement of hydrophobic interaction chromatography (HIC) mechanism in protein retention on the WAX columns. The HIC mechanism was found to operate in all four WAX columns, and each of these columns had a better resolution in the HIC mode than in the corresponding WAX mode. Detailed analysis of the molecular interactions in a chromatographic system indicated that it is impossible to completely eliminate hydrophobic interactions from a WAX column. Based on these results, it may be possible to employ a single WAX column for protein separation by exploiting mixed modes (WAX and HIC) of retention. The stoichiometric displacement theory and two linear plots were used to show that mechanism of the mixed modes of retention in the system was a combination of two kinds of interactions, i.e., nonselective interactions in the HIC mode and selective interactions in the IEC mode. The obtained U-shaped elution curve of proteins could be distinguished into four different ranges of salt concentration, which also represent four retention regions.

  9. Predicting the Mechanical Properties of Viscose/Lycra Knitted Fabrics Using Fuzzy Technique

    Directory of Open Access Journals (Sweden)

    Ismail Hossain

    2016-01-01

    Full Text Available The main objective of this research is to predict the mechanical properties of viscose/lycra plain knitted fabrics by using fuzzy expert system. In this study, a fuzzy prediction model has been built based on knitting stitch length, yarn count, and yarn tenacity as input variables and fabric mechanical properties specially bursting strength as an output variable. The factors affecting the bursting strength of viscose knitted fabrics are very nonlinear. Hence, it is very challenging for scientists and engineers to create an exact model efficiently by mathematical or statistical model. Alternatively, developing a prediction model via ANN and ANFIS techniques is also difficult and time consuming process due to a large volume of trial data. In this context, fuzzy expert system (FES is the promising modeling tool in a quality modeling as FES can map effectively in nonlinear domain with minimum experimental data. The model derived in the present study has been validated by experimental data. The mean absolute error and coefficient of determination between the actual bursting strength and that predicted by the fuzzy model were found to be 2.60% and 0.961, respectively. The results showed that the developed fuzzy model can be applied effectively for the prediction of fabric mechanical properties.

  10. Viscosity and not biological mechanisms often controls the effects of temperature on ciliary activity and swimming velocity of small aquatic organisms

    DEFF Research Database (Denmark)

    Larsen, Poul Scheel; Riisgård, H. U.

    2009-01-01

    organisms using cilia or small appendages for propulsion. Here we summarize results from the literature and from own studies on bio-mechanical activities in response to changing temperature or manipulated viscosity at constant temperature, both having the same change in kinematic viscosity. The survey......A number of studies have shown that temperature-dependent viscosity of the ambient water controls or strongly affects bio-mechanical activity such as beat frequency of water-pumping cilia in mussels and ascidians, swimming velocity of sperm cells, ciliates and small (micro- and meso-scale) aquatic...

  11. Influence Of Specific Mechanical Energy On Cornmeal Viscosity Measured By An On-line System During Twin-screw Extrusion

    OpenAIRE

    Chang Y.K.; Martinez-Bustos F.; Park T.S.; Kokini J.L.

    1999-01-01

    The influence of specific mechanical energy (SME) on cornmeal viscosity during the twin-screw extrusion at feed moisture contents of 25 and 30% and screw speeds in the range from 100 to 500 rpm was measured. Cornmeal was extruded in a co-rotating, intermeshing twin-screw coupled to a slit die rheometer. One approach to the on-line rheological measurement is to use a slit die with the extruder. In the present work it was show that shear viscosity decreased as a function of SME. The viscosity o...

  12. A comparative analysis of salivary factors and maxillary denture retention in different arch forms: An in vivo study

    Directory of Open Access Journals (Sweden)

    Abhishek Shekhar

    2018-01-01

    Conclusions: Complete denture acts as a mechanical stimulant thus increasing flow rate and pH immediately after complete denture insertion. Density, total protein, and viscosity of saliva decreased after complete denture insertion which may be due to increase in water content of saliva. The retention of maxillary complete denture does not seem to depend on the rate of change of the salivary factors, before and after complete denture insertion. Total basal surface area and maxillary denture retention values were highest in square arch form and least in tapered arch form.

  13. The influence of specific mechanical energy on cornmeal viscosity measured by an on-line system during twin-screw extrusion

    OpenAIRE

    CHANG, Y. K.; MARTINEZ-BUSTOS, F.; PARK, T. S.; KOKINI, J .L.

    1999-01-01

    The influence of specific mechanical energy (SME) on cornmeal viscosity during the twin-screw extrusion at feed moisture contents of 25 and 30% and screw speeds in the range from 100 to 500 rpm was measured. Cornmeal was extruded in a co-rotating, intermeshing twin-screw coupled to a slit die rheometer. One approach to the on-line rheological measurement is to use a slit die with the extruder. In the present work it was show that shear viscosity decreased as a function of SME. The viscosity o...

  14. Mechanisms of renal NaCl retention in proteinuric disease

    DEFF Research Database (Denmark)

    Svenningsen, Per; Friis, Ulla G; Versland, Jostein B

    2013-01-01

    In diseases with proteinuria, for example nephrotic syndrome and pre-eclampsia, there often are suppression of plasma renin-angiotensin-aldosterone system components, expansion of extracellular volume and avid renal sodium retention. Mechanisms of sodium retention in proteinuria are reviewed...... of proteolytic activation of ENaC has been explored. Proteolysis leads to putative release of an inhibitory peptide from the extracellular domain of the gamma ENaC subunit. This leads to full activation of the channel. Plasminogen has been demonstrated in urine from patients with nephrotic syndrome and pre-eclampsia...

  15. Influence of the mechanical properties of resilient denture liners on the retention of overdenture attachments.

    Science.gov (United States)

    Kubo, Keitaro; Koike, Takashi; Ueda, Takayuki; Sakurai, Kaoru

    2018-03-15

    Information is lacking about the selection criteria for silicone resilient denture liners applied as a matrix material for attachments on overdentures. The purpose of this in vitro study was to investigate the mechanical properties of silicone resilient denture liners and their influence on the initial retention force of overdenture attachments and the reduction in retention force over time. Nine types of silicone resilient denture liner were injected and fixed to the matrix section of an experimental denture base. They were then fitted to an epoxy resin model that simulated the residual ridge with a patrix ball attachment (n=10). The retention force of the denture was measured with a digital force gauge, and the maximum force of traction (N) was regarded as the initial retention force. The retention force reduction (N) after repeated insertion and removal (n=5) was calculated by subtracting the retention force after 3348 cycles (3-year simulated insertion and removal) from the initial retention force. The intaglio of the matrix was observed with a scanning electron microscope (SEM) before and after the 3348 cycles. Four mechanical properties (hardness, strain-in-compression, tensile strength, and arithmetic mean roughness) of the resilient denture liners were measured. One-way ANOVA of the initial retention force of each lining material was performed, followed by the Scheffe test (α=.05). Pearson correlation analysis was used (α=.05) to analyze correlations of the initial retention force with the retention force reduction after insertion and removal and the mechanical properties of each material. Multiple regression analysis with the stepwise method extracted the initial retention force and the retention force reduction as dependent variables, and the resilient denture liner mechanical properties as explanatory variables (α=.05). The initial retention force of the resilient denture liners was 1.3 to 5.4 N. Multiple comparisons showed significant differences in

  16. The influence of specific mechanical energy on cornmeal viscosity measured by an on-line system during twin-screw extrusion

    Directory of Open Access Journals (Sweden)

    Y. K. CHANG

    1999-09-01

    Full Text Available The influence of specific mechanical energy (SME on cornmeal viscosity during the twin-screw extrusion at feed moisture contents of 25 and 30% and screw speeds in the range from 100 to 500 rpm was measured. Cornmeal was extruded in a co-rotating, intermeshing twin-screw coupled to a slit die rheometer. One approach to the on-line rheological measurement is to use a slit die with the extruder. In the present work it was show that shear viscosity decreased as a function of SME. The viscosity of cornmeal at the exit die was influenced by screw speed, rate of total mass flow, mass temperature inside the extruder and SME. An increase in screw speed resulted in an increase in SME and a decrease in viscosity. A reduction in slit die height and an increase in screw speed and mass temperature led to a remarkable macromolecular degradation of the starch, as evidenced by the decrease in viscosity.

  17. Effects of interactions between powder particle size and binder viscosity on agglomerate growth mechanisms in a high shear mixer.

    Science.gov (United States)

    Johansen, A; Schaefer, T

    2001-01-01

    A study was performed in order to elucidate the effects of the interactions between powder particle size and binder viscosity on the mechanisms involved in agglomerate formation and growth. Calcium carbonates having mean particle sizes in the range of 5-214 microm and polyethylene glycols having viscosities in the range of approximately 50-100000 mPas were melt agglomerated in a high shear mixer. Agglomerate growth by nucleation and coalescence was found to dominate when agglomerating small powder particles and binders with a low viscosity. Increasing the binder viscosity increased the formation of agglomerates by immersion of powder particles in the surface of the binder droplets. With a larger powder particle size, an increasing binder viscosity was necessary in order to obtain an agglomerate strength being sufficient to avoid breakage. Due to a low agglomerate strength, a satisfying agglomeration of very large particles (214 microm) could not be obtained, even with very viscous binders. The study demonstrated that the optimum agglomerate growth occurred when the agglomerates were of an intermediate strength causing an intermediate deformability of the agglomerates. In order to produce spherical agglomerates (pellets), a low viscosity binder has to be chosen when agglomerating a powder with a small particle size, and a high viscosity binder must be applied in agglomeration of powders with large particles.

  18. Praying Mantis Bending Core Breakoff and Retention Mechanism

    Science.gov (United States)

    Badescu, Mircea; Sherrit, Stewart; Bar-Cohen, Yoseph; Bao, Xiaoqi; Lindermann, Randel A.

    2011-01-01

    Sampling cores requires the controlled breakoff of the core at a known location with respect to the drill end. An additional problem is designing a mechanism that can be implemented at a small scale, yet is robust and versatile enough to be used for a variety of core samples. The new design consists of a set of tubes (a drill tube, an outer tube, and an inner tube) and means of sliding the inner and outer tubes axially relative to each other. Additionally, a sample tube can be housed inside the inner tube for storing the sample. The inner tube fits inside the outer tube, which fits inside the drill tube. The inner and outer tubes can move axially relative to each other. The inner tube presents two lamellae with two opposing grabbing teeth and one pushing tooth. The pushing tooth is offset axially from the grabbing teeth. The teeth can move radially and their motion is controlled by the outer tube. The outer tube presents two lamellae with radial extrusions to control the inner tube lamellae motion. In breaking the core, the mechanism creates two support points (the grabbing teeth and the bit tip) and one push point. The core is broken in bending. The grabbing teeth can also act as a core retention mechanism. The praying mantis that is disclosed herein is an active core breaking/retention mechanism that requires only one additional actuator other than the drilling actuator. It can break cores that are attached to the borehole bottom as

  19. A Discussion of SY-101 Crust Gas Retention and Release Mechanisms

    International Nuclear Information System (INIS)

    Mendoza, D.P.; Mahoney, L.A.; Gauglitz, P.A.; Rassat, S.D.; Caley, S.M.

    1999-01-01

    The flammable gas hazard in Hanford waste tanks was made an issue by the behavior of double-shell Tank (DST) 241-SY-101 (SY-101). Shortly after SY-101 was filled in 1980, the waste level began rising periodically, due to the generation and retention of gases within the slurry, and then suddenly dropping as the gases were released. An intensive study of the tank's behavior revealed that these episodic releases posed a safety hazard because the released gas was flammable, and, in some cases, the volume of gas released was sufficient to exceed the lower flammability limit (LFL) in the tank headspace (Alleinann et al. 1993). A mixer pump was installed in SY-101 in late 1993 to prevent gases from building up in the settled solids layer, and the large episodic gas releases have since ceased (Allemann et al. 1994; Stewart et al. 1994; Brewster et al. 1995). However, the surface level of SY-101 has been increasing since at least 1995, and in recent months the level growth has shown significant and unexpected acceleration. Based on a number of observations and measurements, including data from the void fraction instrument (VFI), we have concluded that the level growth is caused largely by increased gas retention in the floating crust. In September 1998, the crust contained between about 21 and 43% void based on VFI measurements (Stewart et al. 1998). Accordingly, it is important to understand the dominant mechanisms of gas retention, why the gas retention is increasing, and whether the accelerating level increase will continue, diminish or even reverse. It is expected that the retained gas in the crust is flammable, with hydrogen as a major constituent. This gas inventory would pose a flammable gas hazard if it were to release suddenly. In May 1997, the mechanisms of bubble retention and release from crust material were the subject of a workshop. The evaluation of the crust and potential hazards assumed a more typical void of roughly 15% gas. It could be similar to

  20. A Discussion of SY-101 Crust Gas Retention and Release Mechanisms

    Energy Technology Data Exchange (ETDEWEB)

    SD Rassat; PA Gauglitz; SM Caley; LA Mahoney; DP Mendoza

    1999-02-23

    The flammable gas hazard in Hanford waste tanks was made an issue by the behavior of double-shell Tank (DST) 241-SY-101 (SY-101). Shortly after SY-101 was filled in 1980, the waste level began rising periodically, due to the generation and retention of gases within the slurry, and then suddenly dropping as the gases were released. An intensive study of the tank's behavior revealed that these episodic releases posed a safety hazard because the released gas was flammable, and, in some cases, the volume of gas released was sufficient to exceed the lower flammability limit (LFL) in the tank headspace (Allemann et al. 1993). A mixer pump was installed in SY-101 in late 1993 to prevent gases from building up in the settled solids layer, and the large episodic gas releases have since ceased (Allemann et al. 1994; Stewart et al. 1994; Brewster et al. 1995). However, the surface level of SY-101 has been increasing since at least 1995, and in recent months the level growth has shown significant and unexpected acceleration. Based on a number of observations and measurements, including data from the void fraction instrument (VFI), we have concluded that the level growth is caused largely by increased gas retention in the floating crust. In September 1998, the crust contained between about 21 and 43% void based on VFI measurements (Stewart et al. 1998). Accordingly, it is important to understand the dominant mechanisms of gas retention, why the gas retention is increasing, and whether the accelerating level increase will continue, diminish or even reverse. It is expected that the retained gas in the crust is flammable, with hydrogen as a major constituent. This gas inventory would pose a flammable gas hazard if it were to release suddenly. In May 1997, the mechanisms of bubble retention and release from crust material were the subject of a workshop. The evaluation of the crust and potential hazards assumed a more typical void of roughly 15% gas. It could be similar to

  1. Gas distribution effects on waste properties: Viscosities of bubbly slurries

    International Nuclear Information System (INIS)

    Gauglitz, P.A.; Shah, R.R.; Davis, R.L.

    1994-09-01

    The retention and episodic release of flammable gases are critical safety concerns for double-shell tanks that contain waste slurries. The rheological behavior of the waste, particularly of the settled sludge, is critical to characterizing the tendency of the waste to retain gas bubbles. The presence of gas bubbles is expected to affect the rheology of the sludge, but essentially no literature data are available to assess the effect of bubbles. Accordingly, the objectives of this study are to develop models for the effect of gas bubbles on the viscosity of a particulate slurry, develop an experimental method (capillary rheometer), collect data on the viscosity of a bubbly slurry, and develop a theoretical basis for interpreting the experimental data from the capillary rheometer

  2. Suprathermal viscosity of dense matter

    International Nuclear Information System (INIS)

    Alford, Mark; Mahmoodifar, Simin; Schwenzer, Kai

    2010-01-01

    Motivated by the existence of unstable modes of compact stars that eventually grow large, we study the bulk viscosity of dense matter, taking into account non-linear effects arising in the large amplitude regime, where the deviation μ Δ of the chemical potentials from chemical equilibrium fulfills μ Δ > or approx. T. We find that this supra-thermal bulk viscosity can provide a potential mechanism for saturating unstable modes in compact stars since the viscosity is strongly enhanced. Our study confirms previous results on strange quark matter and shows that the suprathermal enhancement is even stronger in the case of hadronic matter. We also comment on the competition of different weak channels and the presence of suprathermal effects in various color superconducting phases of dense quark matter.

  3. Molecular mechanism of the viscosity of aqueous glucose solutions

    Science.gov (United States)

    Bulavin, L. A.; Zabashta, Yu. F.; Khlopov, A. M.; Khorol'skii, A. V.

    2017-01-01

    Experimental relations are obtained for the viscosity of aqueous glucose solutions in the temperature range of 10-80°C and concentration range 0.01-2.5%. It is found that the concentration dependence of fluidity is linear when the concentration is higher than a certain value and varies at different temperatures. The existence of such a dependence indicates that the mobilities of solvent and solute molecules are independent of the concentration of solutions. This assumption is used to construct a theoretical model, in which the structure of an aqueous glucose solution is presented as a combination of two weakly interacting networks formed by hydrogen bonds between water molecules and between glucose molecules. Theoretical relations are obtained using this model of network solution structure for the concentration and temperature dependence of solution viscosity. Experimental data are used to calculate the activation energies for water ( U w = 3.0 × 10-20 J) and glucose molecules ( U g = 2.8 × 10-20 J). It is shown that the viscosity of a solution in such a network structure is governed by the Brownian motion of solitons along the chains of hydrogen bonds. The weak interaction between networks results in the contributions to solution fluidity made by the motion of solitons in both of them being almost independent.

  4. Physico-Chemistry and Corium Properties for In-Vessel Retention

    International Nuclear Information System (INIS)

    Froment, K.; Seiler, J.M.; Gueneau, C.; Dauvois, V.; Barbier, F.; Bellon, M.; Tourasse, M.; Ducros, G.; Cognet, G.; Sudreau, F.

    1999-01-01

    This paper focuses on some important aspects of consequences of material behaviour and interactions on in-vessel retention capabilities. It discusses the behaviour of corium oxide mixtures at elevated temperatures (miscibility gap and density effects, separation due to density effects in the solid-liquid mixture according to the analysis of the Rasplav experiment results), and then the interaction between metallic layer and vessel wall (physical-chemical interaction of corium with the carbon steel vessel wall, migration of low melting point metallic elements in the solid vessel wall). It proposes a mode for the calculation of melt viscosity (liquid phase viscosity and viscosity in the solidification range), addresses the issue of barium release and residual power and of distribution of the residual power in an oxidic corium

  5. Effect of ceramic membrane channel diameter on limiting retentate protein concentration during skim milk microfiltration.

    Science.gov (United States)

    Adams, Michael C; Barbano, David M

    2016-01-01

    Our objective was to determine the effect of retentate flow channel diameter (4 or 6mm) of nongraded permeability 100-nm pore size ceramic membranes operated in nonuniform transmembrane pressure mode on the limiting retentate protein concentration (LRPC) while microfiltering (MF) skim milk at a temperature of 50°C, a flux of 55 kg · m(-2) · h(-1), and an average cross-flow velocity of 7 m · s(-1). At the above conditions, the retentate true protein concentration was incrementally increased from 7 to 11.5%. When temperature, flux, and average cross-flow velocity were controlled, ceramic membrane retentate flow channel diameter did not affect the LRPC. This indicates that LRPC is not a function of the Reynolds number. Computational fluid dynamics data, which indicated that both membranes had similar radial velocity profiles within their retentate flow channels, supported this finding. Membranes with 6-mm flow channels can be operated at a lower pressure decrease from membrane inlet to membrane outlet (ΔP) or at a higher cross-flow velocity, depending on which is controlled, than membranes with 4-mm flow channels. This implies that 6-mm membranes could achieve a higher LRPC than 4-mm membranes at the same ΔP due to an increase in cross-flow velocity. In theory, the higher LRPC of the 6-mm membranes could facilitate 95% serum protein removal in 2 MF stages with diafiltration between stages if no serum protein were rejected by the membrane. At the same flux, retentate protein concentration, and average cross-flow velocity, 4-mm membranes require 21% more energy to remove a given amount of permeate than 6-mm membranes, despite the lower surface area of the 6-mm membranes. Equations to predict skim milk MF retentate viscosity as a function of protein concentration and temperature are provided. Retentate viscosity, retentate recirculation pump frequency required to maintain a given cross-flow velocity at a given retentate viscosity, and retentate protein

  6. Thorough investigation of the retention mechanisms and retention behavior of amides and sulfonamides on amino column in hydrophilic interaction liquid chromatography.

    Science.gov (United States)

    Jovanović, Marko; Stojanović, Biljana Jančić

    2013-08-02

    In this paper detailed analysis of a mixture of four amides (tropicamide, nicotinamide, tiracetam, and piracetam) and six sulfonamides (sulfanilamide, sulfacetamide, sulfamethoxazole, sulfafurazole, furosemide, and bumetanide) on aminopropyl column in hydrophilic interaction chromatography (HILIC) was carried out. Since, there are no papers on the topic of the assessment of the contribution of ion-exchange retention mechanism involved in the separation of the acidic compounds on aminopropyl column in HILIC mode, the authors utilized the retention data of the acidic sulfonamides for this purpose. Next, broad range of the aqueous buffer concentrations in the mobile phase was examined providing the separation under either HILIC or RP conditions. Turning points between these two mechanisms were determined and then the fitting of the experimental data in the localized and non-localized adsorption models in both RP and HILIC regions was assessed. Since not many papers in the literature were dealing with the estimation of factor influence on the retention behavior of neutral and acidic compounds on aminopropyl column in HILIC, Box-Behnken design and Response Surface Methodology were applied. On the basis of the obtained data, ten quadratic models were proposed and their adequacy was confirmed using ANOVA test. Furthermore, retention data was graphically evaluated by the construction of 3D response surface plots. Finally, good predictive ability of the suggested models was proved with five additional verification experiments. Copyright © 2013 Elsevier B.V. All rights reserved.

  7. The experimental viscosity and calculated relative viscosity of liquid In-Sn allcoys

    International Nuclear Information System (INIS)

    Wu, A.Q.; Guo, L.J.; Liu, C.S.; Jia, E.G.; Zhu, Z.G.

    2007-01-01

    The experimental measured viscosity of liquid pure Sn, In 20 Sn 80 and In 80 Sn 20 alloys was studied, and to make a comparison, the calculated relative viscosity based on the pair distribution functions, g(r), has also been studied. There is one peak in each experimental viscosity and calculated relative-viscosity curve of liquid pure Sn about 1000 deg. C. One valley appears in each experimental viscosity and calculated viscosity curve of liquid In 20 Sn 80 alloy about 700 deg. C. There is no abnormal behavior on In 80 Sn 20 alloy. The behavior of experimental viscosity and calculated relative viscosity is coincident with each other. Those results conformed that the temperature-induced structure anomalies reported before did take place

  8. Contrast Media Viscosity versus Osmolality in Kidney Injury: Lessons from Animal Studies

    Science.gov (United States)

    Seeliger, Erdmann; Lenhard, Diana C.; Persson, Pontus B.

    2014-01-01

    Iodinated contrast media (CM) can induce acute kidney injury (AKI). CM share common iodine-related cytotoxic features but differ considerably with regard to osmolality and viscosity. Meta-analyses of clinical trials generally failed to reveal renal safety differences of modern CM with regard to these physicochemical properties. While most trials' reliance on serum creatinine as outcome measure contributes to this lack of clinical evidence, it largely relies on the nature of prospective clinical trials: effective prophylaxis by ample hydration must be employed. In everyday life, patients are often not well hydrated; here we lack clinical data. However, preclinical studies that directly measured glomerular filtration rate, intrarenal perfusion and oxygenation, and various markers of AKI have shown that the viscosity of CM is of vast importance. In the renal tubules, CM become enriched, as water is reabsorbed, but CM are not. In consequence, tubular fluid viscosity increases exponentially. This hinders glomerular filtration and tubular flow and, thereby, prolongs intrarenal retention of cytotoxic CM. Renal cells become injured, which triggers hypoperfusion and hypoxia, finally leading to AKI. Comparisons between modern CM reveal that moderately elevated osmolality has a renoprotective effect, in particular, in the dehydrated state, because it prevents excessive tubular fluid viscosity. PMID:24707482

  9. Determination of Viscosity-Average Molecular Weight of Chitosan using Intrinsic Viscosity Measurement

    International Nuclear Information System (INIS)

    Norzita Yacob; Norhashidah Talip; Maznah Mahmud

    2011-01-01

    Molecular weight of chitosan can be determined by different techniques such as Gel Permeation Chromatography (GPC), Static Light Scattering (SLS) and intrinsic viscosity measurement. Determination of molecular weight by intrinsic viscosity measurement is a simple method for characterization of chitosan. Different concentrations of chitosan were prepared and measurement was done at room temperature. The flow time data was used to calculate the intrinsic viscosity by extrapolating the reduced viscosity to zero concentration. The value of intrinsic viscosity was then recalculated into the viscosity-average molecular weight using Mark-Houwink equation. (author)

  10. Localisation and mechanism of renal retention of radiolabelled somatostatin analogues

    Energy Technology Data Exchange (ETDEWEB)

    Melis, Marleen; Krenning, Eric P.; Bernard, Bert F.; Jong, Marion de [Erasmus MC, Department of Nuclear Medicine, Rotterdam (Netherlands); Barone, Raffaella [UCL, Centre of Nuclear Medicine and Laboratory of PET, Brussels (Belgium); Visser, Theo J. [Erasmus MC, Department of Internal Medicine, Rotterdam (Netherlands)

    2005-10-01

    Radiolabelled somatostatin analogues, such as octreotide and octreotate, are used for tumour scintigraphy and radionuclide therapy. The kidney is the most important critical organ during such therapy owing to the reabsorption and retention of radiolabelled peptides. The aim of this study was to investigate in a rat model both the localisation and the mechanism of renal uptake after intravenous injection of radiolabelled somatostatin analogues. The multi-ligand megalin/cubilin receptor complex, responsible for reabsorption of many peptides and proteins in the kidney, is an interesting candidate for renal endocytosis of these peptide analogues. For localisation studies, ex vivo autoradiography and micro-autoradiography of rat kidneys were performed 1-24 h after injection of radiolabelled somatostatin analogues and compared with the renal anti-megalin immunohistochemical staining pattern. To confirm a role of megalin in the mechanism of renal retention of [{sup 111}In-DTPA]octreotide, the effects of three inhibitory substances were explored in rats. Renal ex vivo autoradiography showed high cortical radioactivity and lower radioactivity in the outer medulla. The distribution of cortical radioactivity was inhomogeneous. Micro-autoradiography indicated that radioactivity was only retained in the proximal tubules. The anti-megalin immunohistochemical staining pattern showed a strong similarity with the renal [{sup 111}In-DTPA]octreotide ex vivo autoradiograms. Biodistribution studies showed that co-injection of positively charged d-lysine reduced renal uptake to 60% of control. Sodium maleate reduced renal [{sup 111}In-DTPA]octreotide uptake to 15% of control. Finally, cisplatin pre-treatment of rats reduced kidney uptake to 70% of control. Renal retention of [{sup 111}In-DTPA]octreotide is confined to proximal tubules in the rat kidney, in which megalin-mediated endocytosis may play an important part. (orig.)

  11. Retention and radionuclide migration mechanisms in the environment of a radioactive waste repository in granitic formation

    International Nuclear Information System (INIS)

    Rancon, D.; Miara, P; Vinson, J.M.; Petronin, J.C.; Dozol, J.F.

    1986-01-01

    A laboratory pre-determination of retention mechanisms of radionuclides migrating outside the primary waste containers in repository surroundings was started up. Backfillings materials (clay and sand) as well as granite and its weathering products are concerned here. A method allowing the evaluation of the sorption and desorption of radionuclides of the surfaces of fractures by measuring surface retention coefficients, had initially been started up as well as a laboratory device developed for experiments in a reducing environment. The experiments have consisted of studying the sorbing properties of granite minerals of Auriat and its weathering products and of determining the retention of Np, Pu, AM, CS and Sr on the surface fractures of this granite. The influence of a reducing environment on the behaviour of activities has been studied. Complementary percolation tests have also been carried out on clays, at raised temperature and under irradiation. These experiments have enabled a deeper knowledge of retention mechanisms, the taking of parametric sensitivity measurements and the preparation of elaborating more performing experimental devices which included the parameters needed for a realistic simulation of transfer phenomena

  12. Investigating the Retention Mechanisms of Liquid Chromatography Using Solid-Phase Extraction Cartridges

    Science.gov (United States)

    O'Donnell, Mary E.; Musial, Beata A.; Bretz, Stacey Lowery; Danielson, Neil D.; Ca, Diep

    2009-01-01

    Liquid chromatography (LC) experiments for the undergraduate analytical laboratory course often illustrate the application of reversed-phase LC to solve a separation problem, but rarely compare LC retention mechanisms. In addition, a high-performance liquid chromatography instrument may be beyond what some small colleges can purchase. Solid-phase…

  13. A bulk viscosity driven inflationary model

    International Nuclear Information System (INIS)

    Waga, I.; Falcao, R.C.; Chanda, R.

    1985-01-01

    Bulk viscosity associated with the production of heavy particles during the GUT phase transition can lead to exponential or 'generalized' inflation. The condition of inflation proposed is independent of the details of the phase transition and remains unaltered in presence of a cosmological constant. Such mechanism avoids the extreme supercooling and reheating needed in the usual inflationary models. The standard baryongenesis mechanism can be maintained. (Author) [pt

  14. Determination of viscosity-average molecular weight of chitosan using intrinsic viscosity measurement

    International Nuclear Information System (INIS)

    Norzita Yacob; Norhashidah Talip; Maznah Mahmud; Nurul Aizam Idayu Mat Sani; Nor Akma Samsuddin; Norafifah Ahmad Fabillah

    2013-01-01

    Determination of molecular weight by intrinsic viscosity measurement is a simple method for characterization of chitosan. To study the effect of radiation on molecular weight, chitosan was first irradiated using electron beam at different doses prior to measurement. Different concentrations of chitosan were prepared and measurement was done at room temperature. The flow time data was used to calculate the intrinsic viscosity by extrapolating the reduced viscosity to zero concentration. The value of intrinsic viscosity was then recalculated into the viscosity-average molecular weight using Mark-Houwink equation. (Author)

  15. Mechanisms of gas retention and release: Experimental results for Hanford waste tanks 241-AW-101 and 241-AN-103

    Energy Technology Data Exchange (ETDEWEB)

    Rassat, S.D.; Gauglitz, P.A.; Bredt, P.R.; Mahoney, L.A.; Forbes, S.V.; Tingey, S.M.

    1997-09-01

    The 177 storage tanks at Hanford contain a vast array of radioactive waste forms resulting, primarily, from nuclear materials processing. Through radiolytic, thermal, and other decomposition reactions of waste components, gaseous species including hydrogen, ammonia, and the oxidizer nitrous oxide are generated within the waste tanks. Many of these tanks are known to retain and periodically release quantities of these flammable gas mixtures. The primary focus of the Flammable Gas Project is the safe storage of Hanford tank wastes. To this end, we strive to develop an understanding of the mechanisms of flammable gas retention and release in Hanford tanks through laboratory investigations on actual tank wastes. These results support the closure of the Flammable Gas Unreviewed Safety Question (USQ) on the safe storage of waste tanks known to retain flammable gases and support resolution of the broader Flammable Gas Safety Issue. The overall purpose of this ongoing study is to develop a comprehensive and thorough understanding of the mechanisms of flammable gas retention and release. The first objective of the current study was to classify bubble retention and release mechanisms in two previously untested waste materials from Tanks 241-AN-103 (AN-103) and 241-AW-101 (AW-101). Results were obtained for retention mechanisms, release characteristics, and the maximum gas retention. In addition, unique behavior was also documented and compared with previously studied waste samples. The second objective was to lengthen the duration of the experiments to evaluate the role of slowing bubble growth on the retention and release behavior. Results were obtained for experiments lasting from a few hours to a few days.

  16. Mechanisms of gas retention and release: Experimental results for Hanford waste tanks 241-AW-101 and 241-AN-103

    International Nuclear Information System (INIS)

    Rassat, S.D.; Gauglitz, P.A.; Bredt, P.R.; Mahoney, L.A.; Forbes, S.V.; Tingey, S.M.

    1997-09-01

    The 177 storage tanks at Hanford contain a vast array of radioactive waste forms resulting, primarily, from nuclear materials processing. Through radiolytic, thermal, and other decomposition reactions of waste components, gaseous species including hydrogen, ammonia, and the oxidizer nitrous oxide are generated within the waste tanks. Many of these tanks are known to retain and periodically release quantities of these flammable gas mixtures. The primary focus of the Flammable Gas Project is the safe storage of Hanford tank wastes. To this end, we strive to develop an understanding of the mechanisms of flammable gas retention and release in Hanford tanks through laboratory investigations on actual tank wastes. These results support the closure of the Flammable Gas Unreviewed Safety Question (USQ) on the safe storage of waste tanks known to retain flammable gases and support resolution of the broader Flammable Gas Safety Issue. The overall purpose of this ongoing study is to develop a comprehensive and thorough understanding of the mechanisms of flammable gas retention and release. The first objective of the current study was to classify bubble retention and release mechanisms in two previously untested waste materials from Tanks 241-AN-103 (AN-103) and 241-AW-101 (AW-101). Results were obtained for retention mechanisms, release characteristics, and the maximum gas retention. In addition, unique behavior was also documented and compared with previously studied waste samples. The second objective was to lengthen the duration of the experiments to evaluate the role of slowing bubble growth on the retention and release behavior. Results were obtained for experiments lasting from a few hours to a few days

  17. Crystallization, Microstructure, and Viscosity Evolutions in Lithium Aluminosilicate Glass-Ceramics

    Directory of Open Access Journals (Sweden)

    Qiang Fu

    2016-11-01

    Full Text Available Lithium aluminosilicate glass-ceramics have found widespread commercial success in areas such as consumer products, telescope mirrors, fireplace windows, etc. However, there is still much to learn regarding the fundamental mechanisms of crystallization, especially related to the evolution of viscosity as a function of the crystallization (ceramming process. In this study, the impact of phase assemblage and microstructure on the viscosity was investigated using high temperature X-ray diffraction (HTXRD, beam bending viscometry (BBV, and transmission electron microscopy (TEM. Results from this study provide a first direct observation of viscosity evolution as a function of ceramming time and temperature. Sharp viscosity increases due to phase separation, nucleation and phase transformation are noticed through BBV measurement. A near-net shape ceramming can be achieved in TiO2-containing compositions by keeping the glass at a high viscosity (> 109 Pa.s throughout the whole thermal treatment.

  18. Experimental results on mechanisms of action of electrical neuromodulation in chronic urinary retention.

    Science.gov (United States)

    Schultz-Lampel, D; Jiang, C; Lindström, S; Thüroff, J W

    1998-01-01

    Sacral foramen neuromodulation--initially applied for the treatment of urinary incontinence--has proved to be effective in patients with chronic urinary retention. Thus far, the underlying neurophysiological mechanisms have not been elucidated. In an experimental study on the neurophysiological basis of sacral neurostimulation, one objective was to investigate the mechanisms responsible for initiation of micturition in chronic urinary retention. In ten female cats anesthetized with alpha-chloralose the clinical situation of sacral foramen stimulation was experimentally reproduced by isolated S2 nerve stimulation after L6-S3 laminectomy. Stimulation responses were recorded from the bladder, peripheral nerves, and striated muscles of the foot and pelvic floor. The effect of sudden cessation of prolonged S2 stimulation, during which the bladder was completely inhibited, was evaluated in 70 stimulation sequences in 5 cats. Sacral nerve stimulation induced excitatory and inhibitory effects on the bladder, depending on the frequency and intensity of stimulation. With unilateral S2 stimulation, bladder excitation was best at frequencies of 2-5 Hz and at intensities ranging between 0.8 and 1.4 times the threshold for the M-response of the foot muscle. Inhibition was the dominating effect at frequencies of 7-10 Hz and at intensities exceeding 1.4 times the threshold. Prolonged S2 stimulation above the threshold produced complete bladder inhibition during stimulation but induced strong bladder contractions after sudden interruption of stimulation, with amplitudes being significantly higher than that of spontaneous contractions preceding the stimulation. These results confirm the hypothesis of a "rebound" phenomenon as the mechanism of action for induction of spontaneous voiding in patients with chronic urinary retention.

  19. Motor learning in childhood reveals distinct mechanisms for memory retention and re-learning.

    Science.gov (United States)

    Musselman, Kristin E; Roemmich, Ryan T; Garrett, Ben; Bastian, Amy J

    2016-05-01

    Adults can easily learn and access multiple versions of the same motor skill adapted for different conditions (e.g., walking in water, sand, snow). Following even a single session of adaptation, adults exhibit clear day-to-day retention and faster re-learning of the adapted pattern. Here, we studied the retention and re-learning of an adapted walking pattern in children aged 6-17 yr. We found that all children, regardless of age, showed adult-like patterns of retention of the adapted walking pattern. In contrast, children under 12 yr of age did not re-learn faster on the next day after washout had occurred-they behaved as if they had never adapted their walking before. Re-learning could be improved in younger children when the adaptation time on day 1 was increased to allow more practice at the plateau of the adapted pattern, but never to adult-like levels. These results show that the ability to store a separate, adapted version of the same general motor pattern does not fully develop until adolescence, and furthermore, that the mechanisms underlying the retention and rapid re-learning of adapted motor patterns are distinct. © 2016 Musselman et al.; Published by Cold Spring Harbor Laboratory Press.

  20. Radionuclide Retention Mechanisms in Secondary Waste-Form Testing: Phase II

    Energy Technology Data Exchange (ETDEWEB)

    Um, Wooyong; Valenta, Michelle M.; Chung, Chul-Woo; Yang, Jungseok; Engelhard, Mark H.; Serne, R. Jeffrey; Parker, Kent E.; Wang, Guohui; Cantrell, Kirk J.; Westsik, Joseph H.

    2011-09-26

    This report describes the results from laboratory tests performed at Pacific Northwest National Laboratory (PNNL) for Washington River Protection Solutions (WRPS) to evaluate candidate stabilization technologies that have the potential to successfully treat liquid secondary waste stream effluents produced by the Hanford Tank Waste Treatment and Immobilization Plant (WTP). WRPS is considering the design and construction of a Solidification Treatment Unit (STU) for the Effluent Treatment Facility (ETF) at Hanford. The ETF, a multi-waste, treatment-and-storage unit that has been permitted under the Resource Conservation and Recovery Act (RCRA), can accept dangerous, low-level, and mixed wastewaters for treatment. The STU needs to be operational by 2018 to receive secondary liquid waste generated during operation of the WTP. The STU will provide the additional capacity needed for ETF to process the increased volume of secondary waste expected to be produced by WTP. This report on radionuclide retention mechanisms describes the testing and characterization results that improve understanding of radionuclide retention mechanisms, especially for pertechnetate, {sup 99}TcO{sub 4}{sup -} in four different waste forms: Cast Stone, DuraLith alkali aluminosilicate geopolymer, encapsulated fluidized bed steam reforming (FBSR) product, and Ceramicrete phosphate bonded ceramic. These data and results will be used to fill existing data gaps on the candidate technologies to support a decision-making process that will identify a subset of the candidate waste forms that are most promising and should undergo further performance testing.

  1. A Viscosity-Based Model for Bubble-Propelled Catalytic Micromotors

    Directory of Open Access Journals (Sweden)

    Zhen Wang

    2017-06-01

    Full Text Available Micromotors have shown significant potential for diverse future applications. However, a poor understanding of the propelling mechanism hampers its further applications. In this study, an accurate mechanical model of the micromotor has been proposed by considering the geometric asymmetry and fluid viscosity based on hydrodynamic principles. The results obtained from the proposed model are in a good agreement with the experimental results. The effects of the semi-cone angle on the micromotor are re-analyzed. Furthermore, other geometric parameters, like the length-radius aspect ratio, exert great impact on the velocity. It is also observed that micromotors travel much slower in highly viscous solutions and, hence, viscosity plays an important role.

  2. A Simple BODIPY-Based Viscosity Probe for Imaging of Cellular Viscosity in Live Cells

    Directory of Open Access Journals (Sweden)

    Dongdong Su

    2016-08-01

    Full Text Available Intracellular viscosity is a fundamental physical parameter that indicates the functioning of cells. In this work, we developed a simple boron-dipyrromethene (BODIPY-based probe, BTV, for cellular mitochondria viscosity imaging by coupling a simple BODIPY rotor with a mitochondria-targeting unit. The BTV exhibited a significant fluorescence intensity enhancement of more than 100-fold as the solvent viscosity increased. Also, the probe showed a direct linear relationship between the fluorescence lifetime and the media viscosity, which makes it possible to trace the change of the medium viscosity. Furthermore, it was demonstrated that BTV could achieve practical applicability in the monitoring of mitochondrial viscosity changes in live cells through fluorescence lifetime imaging microscopy (FLIM.

  3. Dynamic viscosity of polymer solutions

    Energy Technology Data Exchange (ETDEWEB)

    Peterlin, A

    1982-03-01

    The dynamic viscosity investigation of solutions of long chain polymers in very viscous solvents has definitely shown the existence of the low and high frequency plateau with the gradual transition between them. In both extreme cases the extrapolation of the measured Newtonian viscosities of the plateaus to the infinite dilution yields the limiting intrinsic viscosities. Such a behavior is expected from the dynamic intrinsic viscosity of the necklace model of the linear polymer with finite internal viscosity. The plateau at low frequency shows up in any model of polymer solution. This work shows the constant dynamic intrinsic viscosity in both extreme cases is well reproducible by the necklace model with the internal viscosity acting only between the beads on the same link. 20 references.

  4. The viscosity of Earth's lower mantle inferred from sinking speed of subducted lithosphere

    NARCIS (Netherlands)

    Čížková, H.; van den Berg, A.P.; Spakman, W.; Matyska, C.

    2012-01-01

    The viscosity of the mantle is indispensable for predicting Earth's mechanical behavior at scales ranging from deep mantle material flow to local stress accumulation in earthquakes zones. But, mantle viscosity is not well determined. For the lower mantle, particularly, only few constraints result

  5. Spectroscopic studies on di-pophyrin rotor as micro-viscosity sensor

    Science.gov (United States)

    Doan, H.; Raut, S.; Kimbal, J.; Gryczynski, Z.; Dzyuba, S.; Balaz, M.

    2015-03-01

    In typical biological systems the fluid compartment makes up more than 70% percent of the system weight. A variety of mass and signal transportation as well as intermolecular interactions are often governed by viscosity. It is important to be able to measure/estimate viscosity and detect the changes in viscosity upon various stimulations. Understanding the influence of changes in viscosity is crucial and development of the molecular systems that sensitive to micro-viscosity is a goal of many researches. Molecular rotors have been considered the potential target since they present enhanced sensitivity to local viscosity that can strongly restrict molecular rotation. To understand the mechanics of rotor interaction with the environment we have been studied conjugated pophyrin-dimer rotor (DP) that emit in the near IR. Our goal is to investigate the photo physical properties such as absorption, transition moment orientation, emission and excitation, polarization anisotropy and fluorescence lifetime in various mediums of different viscosities from ethanol to poly vinyl alcohol (PVA) matrices. The results imply the influences of the medium's viscosity on the two distinct confirmations: planar and twisted conformations of DP. Linear dichroism from polarized absorption in PVA matrices shows various orientations of transition moments. Excitation anisotropy shows similar transition splitting between two conformations. Time resolved intensity decay at two different observations confirms the two different emission states and furthermore the communication between the two states in the form of energy transfer upon excitation.

  6. Sensor for Viscosity and Shear Strength Measurement

    International Nuclear Information System (INIS)

    Dillon, J.; Moore, J.E. Jr.; Ebadian, M.A.; Jones, W.K.

    1998-01-01

    Measurement of the physical properties (viscosity and density) of waste slurries is critical in evaluating transport parameters to ensure turbulent flow through transport pipes. The environment for measurement and sensor exposure is extremely harsh; therefore, reliability and ruggedness are critical in the sensor design. The work for this project will be performed in three phases. The first phase, carried out in FY96, involved (1) an evaluation of acoustic and other methods for viscosity measurement; (2) measurement of the parameters of slurries over the range of percent solids found in tanks and transport systems; (3) a comparison of physical properties (e.g., viscosity and density) to percent solids found composition; and (4) the design of a prototype sensor. The second phase (FY97) will involve the fabrication of a prototype hybrid sensor to measure the viscosity and mechanical properties of slurries in remote, high-radiation environments. Two different viscometer designs are being investigated in this study: a magnetostrictive pulse wave guide viscometer; an oscillating cylinder viscometer. In FY97, the Hemispheric Center for Environmental Technology (HCET) at Florida International University (FIU), which has printed circuit, thick film, thin film, and co-fired ceramic fabrication capability, will fabricate five probes for demonstration after technology selection and evaluation

  7. Properties of bioadhesive ketoprofen liquid suppositories: preparation, determination of gelation temperature, viscosity studies and evaluation of mechanical properties using texture analyzer by 4 × 4 factorial design.

    Science.gov (United States)

    Ozgüney, Işık; Kardhiqi, Anita

    2014-12-01

    Development and evaluation of thermosensitive and bioadhesive liquid suppositories containing ketoprofen (KP). This study was conducted to develope thermosensitive and bioadhesive liquid suppositories containing KP using poloxamer and different bioadhesive polymers and to investigate their gelation temperature, viscosity and mechanical properties. Bioadhesive liquid suppositories were prepared by the cold method using poloxamer 407 (P 407), Poloxamer 188 (P 188) and various amounts of different bioadhesive polymers. Their gelation temperatures, viscosity values and mechanical properties were determined using texture analyzer by 4 × 4 factorial design. It was seen that in presence of KP, gelation temperature of formulation P 407/P 188 (4/20%) significantly decreased from 64 to 37.1 °C. It is to be noted that addition of increasing concentrations of bioadhesive polymers lowered gelation temperature and its decrease was highest with addition of Carbopol 934 P (C). Results of texture profile analysis (TPA) showed that formulations containing C have significantly higher hardness and adhesiveness values than other bioadhesive formulations. According to TPA, gel structure of liquid suppository formulation F5, containing P 407/P 188/KP/C (4/20/2.5/0.8%), exhibited the greatest hardness, compressibilty, adhesiveness and besides greatest viscosity. According to mechanical properties and viscosity values, it was concluded that F5 could be a promising formulation.

  8. Nickel release from orthodontic retention wires: the action of mechanical loading and pH

    NARCIS (Netherlands)

    Milheiro, A.; Kleverlaan, C.; Muris, J.; Feilzer, A.; Pallav, P.

    2012-01-01

    Nickel (Ni) is a potent sensitizer and may induce innate and adaptive immune responses. Ni is an important component of orthodontic appliances (8-50 wt%). Due to chemical and mechanical factors in the oral environment, Ni is released from these appliances. Retention wires are in situ for a long

  9. Colloidal suspensions hydrodynamic retention mechanisms in model porous media

    International Nuclear Information System (INIS)

    Salehi, N.

    1996-01-01

    This study deals with the retention mechanisms of colloidal particles in porous media flows, and the subsequent reduction in permeability in the case of stable and non adsorbing colloids. It combines experimental results and modelling. This study has been realised with stable dispersion of monodispersed carboxylate polystyrene latexes negatively charged injected through negatively charged polycarbonate membranes having mono-sized cylindrical pores. The mean particle diameter is smaller than the mean pore diameter. Both batch and flow experiments in Nuclepore membranes have been done. The results of batch experiments have proved no adsorption of the colloidal latex particles on the surface of the Nuclepore membranes without flow at low salinity. In flow experiments at low particle concentration, only deposition on the upstream side of the membrane have been induced by hydrodynamic forces even for non adsorbing particles without creating any permeability reduction. The retention levels are zero at low and high Peclet numbers with a maximum at intermediate values. Partial plugging was observed at higher colloid concentration even at low salinity without any upstream surface deposition. The modelling of plugging processes is achieved by considering the particle concentration, fluid rate and ratio between the mean pore diameter and the mean particle diameter. This study can be particularly useful in the fields of water treatment and of restoration of lands following radioactive contamination. (author). 96 refs., 99 figs., 29 tabs

  10. Effect of Fluid Dynamic Viscosity on the Strength of Chalk

    DEFF Research Database (Denmark)

    Hedegaard, K.; Fabricius, Ida Lykke

    The mechanical strength of high porosity and weakly cemented chalk is affected by the fluid in the pores. In this study, the effect of the dynamic viscosity of non-polar fluids has been measured on outcrop chalk from Sigerslev Quarry, Stevns, Denmark. The outcome is that the measured strength...... of the chalk decreases with increasing dynamic viscosity. The proposed qualitative explanation is that pressure difference supports and enhances the generation of microscopic shear and tensile failures....

  11. Influence of Oil Viscosity on Alkaline Flooding for Enhanced Heavy Oil Recovery

    Directory of Open Access Journals (Sweden)

    Yong Du

    2013-01-01

    Full Text Available Oil viscosity was studied as an important factor for alkaline flooding based on the mechanism of “water drops” flow. Alkaline flooding for two oil samples with different viscosities but similar acid numbers was compared. Besides, series flooding tests for the same oil sample were conducted at different temperatures and permeabilities. The results of flooding tests indicated that a high tertiary oil recovery could be achieved only in the low-permeability (approximately 500 mD sandpacks for the low-viscosity heavy oil (Zhuangxi, 390 mPa·s; however, the high-viscosity heavy oil (Chenzhuang, 3450 mPa·s performed well in both the low- and medium-permeability (approximately 1000 mD sandpacks. In addition, the results of flooding tests for the same oil at different temperatures also indicated that the oil viscosity put a similar effect on alkaline flooding. Therefore, oil with a high-viscosity is favorable for alkaline flooding. The microscopic flooding test indicated that the water drops produced during alkaline flooding for oils with different viscosities differed significantly in their sizes, which might influence the flow behaviors and therefore the sweep efficiencies of alkaline fluids. This study provides an evidence for the feasibility of the development of high-viscosity heavy oil using alkaline flooding.

  12. Cellular Viscosity in Prokaryotes and Thermal Stability of Low Molecular Weight Biomolecules.

    Science.gov (United States)

    Cuecas, Alba; Cruces, Jorge; Galisteo-López, Juan F; Peng, Xiaojun; Gonzalez, Juan M

    2016-08-23

    Some low molecular weight biomolecules, i.e., NAD(P)H, are unstable at high temperatures. The use of these biomolecules by thermophilic microorganisms has been scarcely analyzed. Herein, NADH stability has been studied at different temperatures and viscosities. NADH decay increased at increasing temperatures. At increasing viscosities, NADH decay rates decreased. Thus, maintaining relatively high cellular viscosity in cells could result in increased stability of low molecular weight biomolecules (i.e., NADH) at high temperatures, unlike what was previously deduced from studies in diluted water solutions. Cellular viscosity was determined using a fluorescent molecular rotor in various prokaryotes covering the range from 10 to 100°C. Some mesophiles showed the capability of changing cellular viscosity depending on growth temperature. Thermophiles and extreme thermophiles presented a relatively high cellular viscosity, suggesting this strategy as a reasonable mechanism to thrive under these high temperatures. Results substantiate the capability of thermophiles and extreme thermophiles (growth range 50-80°C) to stabilize and use generally considered unstable, universal low molecular weight biomolecules. In addition, this study represents a first report, to our knowledge, on cellular viscosity measurements in prokaryotes and it shows the dependency of prokaryotic cellular viscosity on species and growth temperature. Copyright © 2016 Biophysical Society. Published by Elsevier Inc. All rights reserved.

  13. Calculation of the viscosity of nuclear waste glass systems

    International Nuclear Information System (INIS)

    Shah, R.; Behrman, E.C.; Oksoy, D.

    1990-01-01

    Viscosity is one of the most important processing parameters and one of the most difficult to calculate theoretically, particularly for multicomponent systems like nuclear waste glasses. Here, the authors propose a semi-empirical approach based on the Fulcher equation, involving identification of key variables, for which coefficients are then determined by regression analysis. Results are presented for two glass systems, and compared to results of previous workers and to experiment. The authors also sketch a first-order statistical mechanical perturbation theory calculation for the effects on viscosity of a change in composition of the melt

  14. Mineralocorticoid-induced sodium appetite and renal salt retention: Evidence for common signaling and effector mechanisms

    Science.gov (United States)

    Fu, Yiling; Vallon, Volker

    2014-01-01

    An increase in renal sodium chloride (salt) retention and an increase in sodium appetite is the body's response to salt restriction or depletion in order to restore salt balance. Renal salt retention and increased sodium appetite can also be maladaptive and sustain the pathophysiology in conditions like salt-sensitive hypertension and chronic heart failure. Here we review the central role of the mineralocorticoid aldosterone in both the increase in renal salt reabsorption and sodium appetite. We discuss the working hypothesis that aldosterone activates similar signaling and effector mechanisms in the kidney and brain, including the mineralocorticoid receptor, the serum-and-glucocorticoid-induced kinase SGK1, the ubiquitin ligase NEDD4-2, and the epithelial sodium channel ENaC. The latter also mediates the gustatory salt sensing in the tongue, which is required for the manifestation of increased salt intake. Effects of aldosterone on both brain and kidney synergize with the effects of angiotensin II. Thus, mineralocorticoids appear to induce similar molecular pathways in the kidney, brain, and possibly tongue, which could provide opportunities for more effective therapeutic interventions. Inhibition of renal salt reabsorption is compensated by stimulation of salt appetite and vice versa; targeting both mechanisms should be more effective. Inhibiting the arousal to consume salty food may improve a patient's compliance to reducing salt intake. While a better understanding of the molecular mechanisms is needed and will provide new options, current pharmacological interventions that target both salt retention and sodium appetite include mineralocorticoid receptor antagonists and potentially inhibitors of angiotensin II and ENaC. PMID:25376899

  15. Viscosity change of coal during carbonization; Sekitan tanka hannochu no nendo henka

    Energy Technology Data Exchange (ETDEWEB)

    Matsuoka, K.; Hayashi, J.; Kumagai, H.; Chiba, T. [Hokkaido University, Sapporo (Japan). Center for Advanced Research of Energy Technology

    1996-10-28

    In relation to softening, melting and solidification of coal during heating, the effect of heating rate and nitrogen gas pressure on viscosity change, and change with time in the yield of pyridine extract were measured to study the mechanism of viscosity change. In experiment, six kinds of coals were used, and their needle penetration and dilatation were measured using compacted disk coal pellets. The coking and slight coking coal heat-treated under the same condition as the above experiment were used for pyridine extraction. As the experimental result, the apparent viscosity during coal heating was dependent on heating rate, nitrogen pressure and coal kinds. The minimum apparent viscosity decreased with an increase in heating rate and nitrogen pressure, and approached to a constant value. Like apparent viscosity change, the yield of pyridine extract was also dependent on heating rate, and its temperature range nearly agreed with that of apparent viscosity change. It was suggested that the viscosity is dependent on not only the mass fraction of plastic intermediate but also temperature and the relation between plastic intermediate and other components. 3 refs., 5 figs., 1 tab.

  16. Gas viscosity measurement with diamagnetic-levitation viscometer based on electromagnetically spinning system.

    Science.gov (United States)

    Shimokawa, Y; Matsuura, Y; Hirano, T; Sakai, K

    2016-12-01

    Utilizing a graphite-disk probe attached with a thin aluminum disk, we have developed a friction-free viscosity measurement system. The probe is levitated above a NdFeB magnet because of diamagnetic effect and rotated by an electromagnetically induced torque. The probe is absolutely free form mechanical friction, and therefore, the accurate measurements of the viscosity of gases can be achieved. To demonstrate the accuracy and sensitivity of our method, we measured the viscosity of 8 kinds of gases and its temperature change from 278 K to 318 K, and we confirmed a good agreement between the obtained values and literature values. This paper demonstrates that our method has the ability to measure the fluid viscosity in the order of μPa ⋅ s.

  17. Gas viscosity measurement with diamagnetic-levitation viscometer based on electromagnetically spinning system

    Science.gov (United States)

    Shimokawa, Y.; Matsuura, Y.; Hirano, T.; Sakai, K.

    2016-12-01

    Utilizing a graphite-disk probe attached with a thin aluminum disk, we have developed a friction-free viscosity measurement system. The probe is levitated above a NdFeB magnet because of diamagnetic effect and rotated by an electromagnetically induced torque. The probe is absolutely free form mechanical friction, and therefore, the accurate measurements of the viscosity of gases can be achieved. To demonstrate the accuracy and sensitivity of our method, we measured the viscosity of 8 kinds of gases and its temperature change from 278 K to 318 K, and we confirmed a good agreement between the obtained values and literature values. This paper demonstrates that our method has the ability to measure the fluid viscosity in the order of μPa ṡ s.

  18. Effect of viscosity on tear drainage and ocular residence time.

    Science.gov (United States)

    Zhu, Heng; Chauhan, Anuj

    2008-08-01

    An increase in residence time of dry eye medications including artificial tears will likely enhance therapeutic benefits. The drainage rates and the residence time of eye drops depend on the viscosity of the instilled fluids. However, a quantitative understanding of the dependence of drainage rates and the residence time on viscosity is lacking. The current study aims to develop a mathematical model for the drainage of Newtonian fluids and also for power-law non-Newtonian fluids of different viscosities. This study is an extension of our previous study on the mathematical model of tear drainage. The tear drainage model is modified to describe the drainage of Newtonian fluids with viscosities higher than the tear viscosity and power-law non-Newtonian fluids with rheological parameters obtained from fitting experimental data in literature. The drainage rate through canaliculi was derived from the modified drainage model and was incorporated into a tear mass balance to calculate the transients of total solute quantity in ocular fluids and the bioavailability of instilled drugs. For Newtonian fluids, increasing the viscosity does not affect the drainage rate unless the viscosity exceeds a critical value of about 4.4 cp. The viscosity has a maximum impact on drainage rate around a value of about 100 cp. The trends are similar for shear thinning power law fluids. The transients of total solute quantity, and the residence time agrees at least qualitatively with experimental studies. A mathematical model has been developed for the drainage of Newtonian fluids and power-law fluids through canaliculi. The model can quantitatively explain different experimental observations on the effect of viscosity on the residence of instilled fluids on the ocular surface. The current study is helpful for understanding the mechanism of fluid drainage from the ocular surface and for improving the design of dry eye treatments.

  19. The Role of Viscosity in Causing the Plasma Poloidal Motion in Magnetic Clouds

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Ake; Wang, Yuming; Liu, Jiajia; Zhou, Zhenjun; Shen, Chenglong; Liu, Rui; Zhuang, Bin; Zhang, Quanhao, E-mail: ymwang@ustc.edu.cn [CAS Key Laboratory of Geospace Environment, Department of Geophysics and Planetary Sciences, University of Science and Technology of China, Hefei, Anhui 230026 (China)

    2017-08-20

    An interesting phenomenon, plasma poloidal motion, has been found in many magnetic clouds (MCs), and viscosity has been proposed as a possible mechanism. However, it is not clear how significant the role of viscosity is in generating such motion. In this paper, we conduct a statistical study of the MCs detected by the Wind spacecraft during 1995–2012. It is found that, for 19% of all the studied MCs (186), the poloidal velocities of the MC plasma near the MC boundaries are well correlated with those of the corresponding ambient solar wind plasma. A non-monotonic increase from inner to outer MCs suggests that the viscosity does play a role, albeit weak, on the poloidal motion in the MC statistically. The possible dependence on the solar wind parameters is then studied in detail for the nine selected crossings, which represent the viscosity characteristic. There is an evident negative correlation between the viscosity and the density, a weak negative correlation between the viscosity and the turbulence strength, and no clear correlation between the viscosity and the temperature.

  20. Inference of viscosity jump at 670 km depth and lower mantle viscosity structure from GIA observations

    Science.gov (United States)

    Nakada, Masao; Okuno, Jun'ichi; Irie, Yoshiya

    2018-03-01

    A viscosity model with an exponential profile described by temperature (T) and pressure (P) distributions and constant activation energy (E_{{{um}}}^{{*}} for the upper mantle and E_{{{lm}}}^* for the lower mantle) and volume (V_{{{um}}}^{{*}} and V_{{{lm}}}^*) is employed in inferring the viscosity structure of the Earth's mantle from observations of glacial isostatic adjustment (GIA). We first construct standard viscosity models with an average upper-mantle viscosity ({\\bar{η }_{{{um}}}}) of 2 × 1020 Pa s, a typical value for the oceanic upper-mantle viscosity, satisfying the observationally derived three GIA-related observables, GIA-induced rate of change of the degree-two zonal harmonic of the geopotential, {\\dot{J}_2}, and differential relative sea level (RSL) changes for the Last Glacial Maximum sea levels at Barbados and Bonaparte Gulf in Australia and for RSL changes at 6 kyr BP for Karumba and Halifax Bay in Australia. Standard viscosity models inferred from three GIA-related observables are characterized by a viscosity of ˜1023 Pa s in the deep mantle for an assumed viscosity at 670 km depth, ηlm(670), of (1 - 50) × 1021 Pa s. Postglacial RSL changes at Southport, Bermuda and Everglades in the intermediate region of the North American ice sheet, largely dependent on its gross melting history, have a crucial potential for inference of a viscosity jump at 670 km depth. The analyses of these RSL changes based on the viscosity models with {\\bar{η }_{{{um}}}} ≥ 2 × 1020 Pa s and lower-mantle viscosity structures for the standard models yield permissible {\\bar{η }_{{{um}}}} and ηlm (670) values, although there is a trade-off between the viscosity and ice history models. Our preferred {\\bar{η }_{{{um}}}} and ηlm (670) values are ˜(7 - 9) × 1020 and ˜1022 Pa s, respectively, and the {\\bar{η }_{{{um}}}} is higher than that for the typical value of oceanic upper mantle, which may reflect a moderate laterally heterogeneous upper

  1. Viscosity measurements on metal melts at high pressure and viscosity calculations for the earth's core

    International Nuclear Information System (INIS)

    Mineev, Vladimir N; Funtikov, Aleksandr I

    2004-01-01

    A review is given of experimental and calculated data on the viscosity of iron-based melts on the melting curve. The interest in these data originates in the division of opinion on whether viscosity increases rather moderately or considerably in the high-pressure range. This disagreement is especially pronounced in the interpretation of the values of molten iron and its compounds in the environment of the earth's outer core. The conclusion on a substantial rise in viscosity mostly follows from the universal law, proposed by Brazhkin and Lyapin [1], of viscosity changing along the metal melting curve in the high-pressure range. The review analyzes available experimental and computational data, including the most recent ones. Data on viscosity of metals under shock wave compression in the megabar pressure range are also discussed. It is shown that data on viscosity of metal melts point to a small increase of viscosity on the melting curve. Specifics are discussed of the phase diagram of iron made more complex by the presence of several phase transitions and by the uncertainty in the position of the melting curve in the high-pressure range. Inaccuracies that arise in extrapolating the results of viscosity measurements to the pressure range corresponding to the earth's core environment are pointed out. (reviews of topical problems)

  2. Relationship between viscosity of the ankle joint complex and functional ankle instability for inversion ankle sprain patients.

    Science.gov (United States)

    Lin, Che-Yu; Kang, Jiunn-Horng; Wang, Chung-Li; Shau, Yio-Wha

    2015-03-01

    Measurement of viscosity of the ankle joint complex is a novel method to assess mechanical ankle instability. In order to further investigate the clinical significance of the method, this study intended to investigate the relationship between ankle viscosity and severity of functional ankle instability. Cross-sectional study. 15 participants with unilateral inversion ankle sprain and 15 controls were recruited. Their ankles were further classified into stable and unstable ankles. Ankle viscosity was measured by an instrumental anterior drawer test. Severity of functional ankle instability was measured by the Cumberland Ankle Instability Tool. Unstable ankles were compared with stable ankles. Injured ankles were compared with uninjured ankles of both groups. The spearman's rank correlation coefficient was applied to determine the relationship between ankle viscosity and severity of functional ankle instability in unstable ankles. There was a moderate relationship between ankle viscosity and severity of functional ankle instability (r=-0.64, pankles exhibited significantly lower viscosity (pankle instability (pankles. Injured ankles exhibited significantly lower viscosity and more severe functional ankle instability than uninjured ankles (pankle viscosity and severity of functional ankle instability. This finding suggested that, severity of functional ankle instability may be partially attributed to mechanical insufficiencies such as the degenerative changes in ankle viscosity following the inversion ankle sprain. In clinical application, measurement of ankle viscosity could be a useful tool to evaluate severity of chronic ankle instability. Copyright © 2014 Sports Medicine Australia. Published by Elsevier Ltd. All rights reserved.

  3. Technological characteristics of meat - viscosity

    OpenAIRE

    DIBĎÁK, Tomáš

    2012-01-01

    This bachelor thesis is focused on the technological characteristics of meat, mainly viscosity of meat. At the beginning I dealt with construction of meat and various types of meat: beef, veal, pork, mutton, rabbit, poultry and venison. Then I described basic chemical composition of meat and it?s characteristic. In detail I dealt with viscosity of meat. Viscosity is the ability of meat to bind water both own and added. I mentioned influences, which effects viscosity and I presented the possib...

  4. Colloid and radionuclide retention mechanisms in fractured rock under near-natural flow conditions

    International Nuclear Information System (INIS)

    Delos, A.; Schaefer, T.; Geckeis, H.; Guimera, J.; Carrera, J.; Fanghaenel, T.

    2005-01-01

    Full text of publication follows: Experiments in fractured host rock (Grimsel Test Site, GTS, Switzerland) revealed that the colloid relevance for actinide migration is high due to the specific geochemical groundwater conditions [1]. However, even under such conditions it is found that retention of colloids and colloid-borne actinides becomes significant under near-natural groundwater flow rates (1-10 m/a) [2]. Underlying mechanisms of colloid and radionuclide retention are not well understood up to now. The present study co-funded by the NoE ACTINET-6 focuses on (i) the kinetics of actinide-colloid interactions and (ii) the relevance of matrix diffusion as a competition process to other retention mechanisms which affect the actinides behavior in fractured rock systems such as the Grimsel granodiorite. Colloid migration is studied with well defined model colloids as e.g. fluorescence dyed carboxylated polystyrene particles, and natural colloids extracted from bentonite (FEBEX) and from fracture filling material (GTS). In order to study the influence of matrix porosity on actinides migration, those experiments are performed in columns of well defined geometry filled with microporous unmodified silica spheres, porous ceramic material and natural fracture filling material from the GTS. The behaviour of actinides (Pu(IV) and Am(III)) sorbed onto bentonite colloids is investigated in column and batch experiments. All experiments are performed under anoxic conditions. Colloid characterization methods used in this study include the combination of photon correlation spectroscopy (PCS), laser-induced breakdown detection (LIBD), fluorimetry and field flow fractionation (FFF). Experimental results and their application to the parametrisation of reactive colloid transport models are discussed. [1] Geckeis H, Schaefer T, Hauser W, Rabung T, Missana T, Degueldre C, Moeri A, Eikenberg J, Fierz T, Alexander WR (2004) Results of the Colloid and Radionuclide Retention experiment

  5. Reversing the direction of galvanotaxis with controlled increases in boundary layer viscosity

    Science.gov (United States)

    Kobylkevich, Brian M.; Sarkar, Anyesha; Carlberg, Brady R.; Huang, Ling; Ranjit, Suman; Graham, David M.; Messerli, Mark A.

    2018-05-01

    Weak external electric fields (EFs) polarize cellular structure and direct most migrating cells (galvanotaxis) toward the cathode, making it a useful tool during tissue engineering and for healing epidermal wounds. However, the biophysical mechanisms for sensing weak EFs remain elusive. We have reinvestigated the mechanism of cathode-directed water flow (electro-osmosis) in the boundary layer of cells, by reducing it with neutral, viscous polymers. We report that increasing viscosity with low molecular weight polymers decreases cathodal migration and promotes anodal migration in a concentration dependent manner. In contrast, increased viscosity with high molecular weight polymers does not affect directionality. We explain the contradictory results in terms of porosity and hydraulic permeability between the polymers rather than in terms of bulk viscosity. These results provide the first evidence for controlled reversal of galvanotaxis using viscous agents and position the field closer to identifying the putative electric field receptor, a fundamental, outside-in signaling receptor that controls cellular polarity for different cell types.

  6. A technique for evaluating the oil/heavy-oil viscosity changes under ultrasound in a simulated porous medium.

    Science.gov (United States)

    Hamidi, Hossein; Mohammadian, Erfan; Junin, Radzuan; Rafati, Roozbeh; Manan, Mohammad; Azdarpour, Amin; Junid, Mundzir

    2014-02-01

    Theoretically, Ultrasound method is an economical and environmentally friendly or "green" technology, which has been of interest for more than six decades for the purpose of enhancement of oil/heavy-oil production. However, in spite of many studies, questions about the effective mechanisms causing increase in oil recovery still existed. In addition, the majority of the mechanisms mentioned in the previous studies are theoretical or speculative. One of the changes that could be recognized in the fluid properties is viscosity reduction due to radiation of ultrasound waves. In this study, a technique was developed to investigate directly the effect of ultrasonic waves (different frequencies of 25, 40, 68 kHz and powers of 100, 250, 500 W) on viscosity changes of three types of oil (Paraffin oil, Synthetic oil, and Kerosene) and a Brine sample. The viscosity calculations in the smooth capillary tube were based on the mathematical models developed from the Poiseuille's equation. The experiments were carried out for uncontrolled and controlled temperature conditions. It was observed that the viscosity of all the liquids was decreased under ultrasound in all the experiments. This reduction was more significant for uncontrolled temperature condition cases. However, the reduction in viscosity under ultrasound was higher for lighter liquids compare to heavier ones. Pressure difference was diminished by decreasing in the fluid viscosity in all the cases which increases fluid flow ability, which in turn aids to higher oil recovery in enhanced oil recovery (EOR) operations. Higher ultrasound power showed higher liquid viscosity reduction in all the cases. Higher ultrasound frequency revealed higher and lower viscosity reduction for uncontrolled and controlled temperature condition experiments, respectively. In other words, the reduction in viscosity was inversely proportional to increasing the frequency in temperature controlled experiments. It was concluded that cavitation

  7. Capillary waves with surface viscosity

    Science.gov (United States)

    Shen, Li; Denner, Fabian; Morgan, Neal; van Wachem, Berend; Dini, Daniele

    2017-11-01

    Experiments over the last 50 years have suggested a correlation between the surface (shear) viscosity and the stability of a foam or emulsion. With recent techniques allowing more accurate measurements of the elusive surface viscosity, we examine this link theoretically using small-amplitude capillary waves in the presence of the Marangoni effect and surface viscosity modelled via the Boussinesq-Scriven model. The surface viscosity effect is found to contribute a damping effect on the amplitude of the capillary wave with subtle differences to the effect of the convective-diffusive Marangoni transport. The general wave dispersion is augmented to take into account the Marangoni and surface viscosity effects, and a first-order correction to the critical damping wavelength is derived. The authors acknowledge the financial support of the Shell University Technology Centre for fuels and lubricants.

  8. Lennard-Jones triple-point bulk and shear viscosities. Green-Kubo theory, Hamiltonian mechanics, and nonequilibrium molecular dynamics

    International Nuclear Information System (INIS)

    Hoover, W.G.; Evans, D.J.; Hickman, R.B.; Ladd, A.J.C.; Ashurst, W.T.; Moran, B.

    1980-01-01

    A new Hamiltonian method for deformation simulations is related to the Green-Kubo fluctuation theory through perturbation theory and linear-response theory. Numerical results for the bulk and shear viscosity coefficients are compared to corresponding Green-Kubo calculations. Both viscosity coefficients depend similarly on frequency, in a way consistent with enhanced ''long-time tails.''

  9. Effect of ionic and non-ionic contrast media on whole blood viscosity, plasma viscosity and hematocrit in vitro

    International Nuclear Information System (INIS)

    Aspelin, P.

    1978-01-01

    The effect of the ionic contrast media diatrizoate, iocarmate and metrizoate and the non-ionic metrizamide on whole blood viscosity, plasma viscosity and hematocrit was investigated. All the contrast media increased whole blood and plasma viscosity and reduced the hematocrit. The whole blood viscosity increased with increasing osmolality of the contrast medium solutions, whereas the plasma viscosity increased with increasing viscosity of the contrast medium solutions. The higher the osmolality of the contrast media, the lower the hematocrit became. The normal shear-thinning (decreasing viscosity with increasing shear rate) property of blood was reduced when contrast medium was added to the blood. At 50 per cent volume ratio (contrast medium to blood), the ionic contrast media converted the blood into a shear-thickening (increasing viscosity with increasing shear rate) suspension, indicating a marked rigidification of the single red cell, while the non-ionic contrast medium still produced shear-thinning, indicating less rigidification of the red cell (p<0.01). (Auth.)

  10. The viscosity of dimethyl ether

    DEFF Research Database (Denmark)

    Sivebæk, Ion Marius; Jakobsen, Jørgen

    2007-01-01

    and NOx traps are installed. The most significant problem encountered when engines are fuelled with DME is that the injection equipment breaks down prematurely due to extensive wear. This tribology issue can be explained by the very low lubricity and viscosity of DME. Recently, laboratory methods have...... appeared capable of measuring these properties of DME. The development of this is rendered difficult because DME has to be pressurised to remain in the liquid state and it dissolves most of the commercially available elastomers. This paper deals fundamentally with the measurement of the viscosity of DME...... and extends the discussion to the difficulty of viscosity establishing of very thin fluids. The main issue here is that it is not easy to calibrate the viscometers in the very low viscosity range corresponding to about one-fifth of that of water. The result is that the low viscosity is measured at high...

  11. Superrotation of Earth’s Inner Core, Extraterrestrial Impacts, and the Effective Viscosity of Outer Core

    OpenAIRE

    Pirooz Mohazzabi; John D. Skalbeck

    2015-01-01

    The recently verified superrotation of Earth’s inner core is examined and a new model is presented which is based on the tidal despinning of the mantle and the viscosity of the outer core. The model also takes into account other damping mechanisms arising from the inner core superrotation such as magnetic and gravitational coupling as well as contribution from eddy viscosity in the outer core. The effective viscosity obtained in this model confirms a previously well constrained value of about...

  12. Chemical adhesion rather than mechanical retention enhances resin bond durability of a dental glass-ceramic with leucite crystallites

    International Nuclear Information System (INIS)

    Meng, X F; Yoshida, K; Gu, N

    2010-01-01

    This study aims to evaluate the effect of chemical adhesion by a silane coupler and mechanical retention by hydrofluoric acid (HFA) etching on the bond durability of resin to a dental glass ceramic with leucite crystallites. Half of the ceramic plates were etched with 4.8% HFA (HFA group) for 60 s, and the other half were not treated (NoHFA group). The scale of their surface roughness and rough area was measured by a 3D laser scanning microscope. These plates then received one of the following two bond procedures to form four bond test groups: HFA/cement, NoHFA/cement, HFA/silane/cement and NoHFA/silane/cement. The associated micro-shear bond strength and bond failure modes were tested after 0 and 30 000 thermal water bath cycles. Four different silane/cement systems (Monobond S/Variolink II, GC Ceramic Primer/Linkmax HV, Clearfil Ceramic Primer/Clearfil Esthetic Cement and Porcelain Liner M/SuperBond C and B) were used. The data for each silane/cement system were analyzed by three-way ANOVA. HFA treatment significantly increased the surface R a and R y values and the rough area of the ceramic plates compared with NoHFA treatment. After 30 000 thermal water bath cycles, the bond strength of all the test groups except the HFA/Linkmax HV group was significantly reduced, while the HFA/Linkmax HV group showed only adhesive interface failure. The other HFA/cement groups and all NoHFA/cement groups lost bond strength completely, and all NoHFA/silane/cement groups with chemical adhesion had significantly higher bond strength and more ceramic cohesive failures than the respective HFA/cement groups with mechanical retention. The result of the HFA/silane/cement groups with both chemical adhesion and mechanical retention revealed that HFA treatment could enhance the bond durability of resin/silanized glass ceramics, which might result from the increase of the chemical adhesion area on the ceramic rough surface and subsequently reduced degradation speed of the silane coupler

  13. Mechanistic failure mode investigation and resolution of parvovirus retentive filters.

    Science.gov (United States)

    LaCasse, Daniel; Lute, Scott; Fiadeiro, Marcus; Basha, Jonida; Stork, Matthew; Brorson, Kurt; Godavarti, Ranga; Gallo, Chris

    2016-07-08

    Virus retentive filters are a key product safety measure for biopharmaceuticals. A simplistic perception is that they function solely based on a size-based particle removal mechanism of mechanical sieving and retention of particles based on their hydrodynamic size. Recent observations have revealed a more nuanced picture, indicating that changes in viral particle retention can result from process pressure and/or flow interruptions. In this study, a mechanistic investigation was performed to help identify a potential mechanism leading to the reported reduced particle retention in small virus filters. Permeate flow rate or permeate driving force were varied and analyzed for their impact on particle retention in three commercially available small virus retentive filters. © 2016 American Institute of Chemical Engineers Biotechnol. Prog., 32:959-970, 2016. © 2016 American Institute of Chemical Engineers.

  14. Viscosity in Modified Gravity 

    Directory of Open Access Journals (Sweden)

    Iver Brevik

    2012-11-01

    Full Text Available A bulk viscosity is introduced in the formalism of modified gravity. It is shownthat, based on a natural scaling law for the viscosity, a simple solution can be found forquantities such as the Hubble parameter and the energy density. These solutions mayincorporate a viscosity-induced Big Rip singularity. By introducing a phase transition inthe cosmic fluid, the future singularity can nevertheless in principle be avoided. 

  15. Mobile phase effects on the retention on polar columns with special attention to the dual hydrophilic interaction-reversed-phase liquid chromatography mechanism, a review.

    Science.gov (United States)

    Jandera, Pavel; Hájek, Tomáš

    2018-01-01

    Hydrophilic interaction liquid chromatography on polar columns in aqueous-organic mobile phases has become increasingly popular for the separation of many biologically important compounds in chemical, environmental, food, toxicological, and other samples. In spite of many new applications appearing in literature, the retention mechanism is still controversial. This review addresses recent progress in understanding of the retention models in hydrophilic interaction liquid chromatography. The main attention is focused on the role of water, both adsorbed by the column and contained in the bulk mobile phase. Further, the theoretical retention models in the isocratic and gradient elution modes are discussed. The dual hydrophilic interaction liquid chromatography reversed-phase retention mechanism on polar columns is treated in detail, especially with respect to the practical use in one- and two-dimensional liquid chromatography separations. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. A blood-oxygenation-dependent increase in blood viscosity due to a static magnetic field

    International Nuclear Information System (INIS)

    Yamamoto, Toru; Nagayama, Yuki; Tamura, Mamoru

    2004-01-01

    As the magnetic field of widely used MR scanners is one of the strongest magnetic fields to which people are exposed, the biological influence of the static magnetic field of MR scanners is of great concern. One magnetic interaction in biological subjects is the magnetic torque on the magnetic moment induced by biomagnetic substances. The red blood cell is a major biomagnetic substance, and the blood flow may be influenced by the magnetic field. However, the underlying mechanisms have been poorly understood. To examine the mechanisms of the magnetic influence on blood viscosity, we measured the time for blood to fall through a glass capillary inside and outside a 1.5 T MR scanner. Our in vitro results showed that the blood viscosity significantly increased in a 1.5 T MR scanner, and also clarified the mechanism of the interaction between red blood cells and the external magnetic field. Notably, the blood viscosity increased depending on blood oxygenation and the shear rate of the blood flow. Thus, our findings suggest that even a 1.5 T magnetic field may modulate blood flow

  17. Effect of viscosity on learned satiation

    NARCIS (Netherlands)

    Mars, M.; Hogenkamp, P.S.; Gosses, A.M.; Stafleu, A.; Graaf, C.de

    2009-01-01

    A higher viscosity of a food leads to a longer orosensory stimulation. This may facilitate the learned association between sensory signals and metabolic consequences. In the current study we investigated the effect of viscosity on learned satiation. In two intervention groups a low viscosity (LV)

  18. Antiwear performance of ionic liquid+graphene dispersions with anomalous viscosity-temperature behavior

    OpenAIRE

    Pamies Porras, Ramón Francisco; Arias Pardilla, Joaquín; Espinosa Rodríguez, Tulia; Carrión Vilches, Francisco José; Bermúdez Olivares, María Dolores; Sanes Molina, José; Avilés González, María Dolores

    2018-01-01

    New dispersions of few-layers graphene (G) in 1-ethyl-3-methylimidazolium ([EMIM]) ionic liquids (ILs) with dicyanamide ([DCA]) or bis(trifluoromethylsulfonyl)imide ([TFSI]) anions have been obtained by mechanical mixing and sonication. IL+0.5 wt% G dispersions show constant viscosity values from 357K (for IL = [EMIM][DCA]) or from 385K (for IL = [EMIM][TFSI]) to 393K. IL + G dispersions with G > 0.5 wt% show linear viscosity increases with increasing temperature, from 306K (for [EMIM][DCA]+1...

  19. Comparison of parallel viscosity with neoclassical theory

    International Nuclear Information System (INIS)

    Ida, K.; Nakajima, N.

    1996-04-01

    Toroidal rotation profiles are measured with charge exchange spectroscopy for the plasma heated with tangential NBI in CHS heliotron/torsatron device to estimate parallel viscosity. The parallel viscosity derived from the toroidal rotation velocity shows good agreement with the neoclassical parallel viscosity plus the perpendicular viscosity. (μ perpendicular = 2 m 2 /s). (author)

  20. Study of the water retention and the consolidation of partially saturated soils in a thermo-hydro-mechanical framework

    International Nuclear Information System (INIS)

    Salager, Simon

    2007-01-01

    This work is concerned with the study of water retention and consolidation of unsaturated soils in a thermo-hydro-mechanical framework. It is organized into two parts which deal respectively with deformation and temperature effects on hydric behaviour, and suction and temperature effects on mechanical behaviour. In the first part, we point out the relevance of the characteristic surface concept for soils as opposed to the retention curve, which has limited modelling power in the case of deformable media. The characteristic surface concept is experimentally illustrated for the example of a clayey silty sand. Its modelling is based on a large sample of experimental investigations with about 240 measurements of the triplet void ratio, water content, suction. In addition, a thermo-hydric behaviour model is proposed in order to determine the characteristic surface and the retention curve for a given temperature. This model is validated for the case of two materials: a ceramic and a clayey silty sand through direct testing, and for other materials on the basis of an analysis of the literature. Finally, we present an application to the determination of the permeability of unsaturated soils taking into account deformation and temperature. In the second part, temperature and suction effects on the mechanical behaviour are studied through consolidation tests on 'Sion' silt. These tests are performed for different temperatures and suctions. For each test, swelling and compression indexes, as well as the pre-consolidation pressure are measured. The influence of temperature and suction on these essential parameters of mechanical behaviour is determined. Finally, we propose a theoretical model which account for pre-consolidation pressure as a function of temperature and suction. (author)

  1. Lack of age-related increase in carotid artery wall viscosity in cardiorespiratory fit men

    Science.gov (United States)

    Kawano, Hiroshi; Yamamoto, Kenta; Gando, Yuko; Tanimoto, Michiya; Murakami, Haruka; Ohmori, Yumi; Sanada, Kiyoshi; Tabata, Izumi; Higuchi, Mitsuru; Miyachi, Motohiko

    2013-01-01

    Objectives: Age-related arterial stiffening and reduction of arterial elasticity are attenuated in individuals with high levels of cardiorespiratory fitness. Viscosity is another mechanical characteristic of the arterial wall; however, the effects of age and cardiorespiratory fitness have not been determined. We examined the associations among age, cardiorespiratory fitness and carotid arterial wall viscosity. Methods: A total of 111 healthy men, aged 25–39 years (young) and 40–64 years (middle-aged), were divided into either cardiorespiratory fit or unfit groups on the basis of peak oxygen uptake. The common carotid artery was measured noninvasively by tonometry and automatic tracking of B-mode images to obtain instantaneous pressure and diameter hysteresis loops, and we calculated the effective compliance, isobaric compliance and viscosity index. Results: In the middle-aged men, the viscosity index was larger in the unfit group than in the fit group (2533 vs. 2018 mmHg·s/mm, respectively: P viscosity index was increased with advancing age, but these parameters were unaffected by cardiorespiratory fitness level. Conclusion: These results suggest that the wall viscosity in the central artery is increased with advancing age and that the age-associated increase in wall viscosity may be attenuated in cardiorespiratory fit men. PMID:24029868

  2. Papillary Ductal Plugging is a Mechanism for Early Stone Retention in Brushite Stone Disease

    DEFF Research Database (Denmark)

    Williams, James C; Borofsky, Michael S; Bledsoe, Sharon B

    2018-01-01

    PURPOSE: Mechanisms of early stone retention in the kidney are under studied and poorly understood. To date attachment via Randall's plaque is the only widely accepted theory in this regard, which is best described in idiopathic calcium oxalate stone formers. Brushite stone formers are known...... to have distinct papillary morphology relative to calcium oxalate stone formers. As such we sought to determine whether stone attachment mechanisms in such patients may be similarly unique. MATERIALS AND METHODS: Patients undergoing percutaneous and or ureteroscopic procedures for stone removal consented...... to endoscopic renal papillary examination and individual stone collection. Each removed stone was processed using micro computerized tomography to assess the 3-dimensional microstructure and the minerals contained, and search for common structural features indicative of novel mechanisms of early growth...

  3. Preparation of low viscosity epoxy acrylic acid photopolymer prepolymer in light curing system

    Science.gov (United States)

    Li, P.; Huang, J. Y.; Liu, G. Z.

    2018-01-01

    With the integration and development of materials engineering, applied mechanics, automatic control and bionics, light cured composite has become one of the most favourite research topics in the field of materials and engineering at home and abroad. In the UV curing system, the prepolymer and the reactive diluent form the backbone of the cured material together. And they account for more than 90% of the total mass. The basic properties of the cured product are mainly determined by the prepolymer. A low viscosity epoxy acrylate photosensitive prepolymer with a viscosity of 6800 mPa • s (25 °C ) was obtained by esterification of 5 hours with bisphenol A epoxy resin with high epoxy value and low viscosity.

  4. Dynamic modeling of the horizontal eddy viscosity coefficient for quasigeostrophic ocean circulation problems

    Directory of Open Access Journals (Sweden)

    Romit Maulik

    2016-12-01

    Full Text Available This paper puts forth a simplified dynamic modeling strategy for the eddy viscosity coefficient parameterized in space and time. The eddy viscosity coefficient is dynamically adjusted to the local structure of the flow using two different nonlinear eddy viscosity functional forms to capture anisotropic dissipation mechanism, namely, (i the Smagorinsky model using the local strain rate field, and (ii the Leith model using the gradient of the vorticity field. The proposed models are applied to the one-layer and two-layer wind-driven quasigeostrophic ocean circulation problems, which are standard prototypes of more realistic ocean dynamics. Results show that both models capture the quasi-stationary ocean dynamics and provide the physical level of eddy viscosity distribution without using any a priori estimation. However, it is found that slightly less dissipative results can be obtained by using the dynamic Leith model. Two-layer numerical experiments also reveal that the proposed dynamic models automatically parameterize the subgrid-scale stress terms in each active layer. Furthermore, the proposed scale-aware models dynamically provide higher values of the eddy viscosity for smaller resolutions taking into account the local resolved flow information, and addressing the intimate relationship between the eddy viscosity coefficients and the numerical resolution employed by the quasigeostrophic models.

  5. Evaluations of Mechanisms for Pu Uptake and Retention within Spherical Resorcinol-Formaldehyde Resin Columns

    Energy Technology Data Exchange (ETDEWEB)

    Delegard, Calvin H. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Levitskaia, Tatiana G. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Fiskum, Sandra K. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2016-09-15

    The unexpected uptake and retention of plutonium (Pu) onto columns containing spherical resorcinol-formaldehyde (sRF) resin during ion exchange testing of Cs (Cs) removal from alkaline tank waste was observed in experiments at both the Pacific Northwest National Laboratory (PNNL) and the Savannah River National Laboratory (SRNL). These observations have raised concern regarding the criticality safety of the Cs removal unit operation within the low-activity waste pretreatment system (LAWPS). Accordingly, studies have been initiated at Washington River Protection Solutions (WRPS), who manages the operations of the Hanford Site tank farms, including the LAWPS, PNNL, and elsewhere to investigate these findings. As part of these efforts, PNNL has prepared the present report to summarize the laboratory testing observations, evaluate these phenomena in light of published and unpublished technical information, and outline future laboratory testing, as deemed appropriate based on the literature studies, with the goal to elucidate the mechanisms for the observed Pu uptake and retention.

  6. Temperature dependence of deuterium retention mechanisms in tungsten

    Energy Technology Data Exchange (ETDEWEB)

    Roszell, J.P. [University of Toronto Institute for Aerospace Studies, 4925 Dufferin Street, Toronto, Ontario, M3H 5T6 (Canada); Davis, J.W., E-mail: jwdavis@starfire.utias.utoronto.ca [University of Toronto Institute for Aerospace Studies, 4925 Dufferin Street, Toronto, Ontario, M3H 5T6 (Canada); Haasz, A.A. [University of Toronto Institute for Aerospace Studies, 4925 Dufferin Street, Toronto, Ontario, M3H 5T6 (Canada)

    2012-10-15

    The retention of 500 eV D{sup +} was measured as a function of implantation temperature in single- (SCW) and poly-crystalline (PCW) tungsten. The results show a decrease in retention of {approx}2 orders of magnitude over the temperature range of 350-550 K in SCW and a decrease of an order of magnitude over the temperature range of 600-700 K in PCW. Inspection of the TDS spectra showed a shift in peak location from 600 to 800 K as temperature was increased above 350 K in SCW and above 450 K in PCW specimens. TMAP modeling showed that the change in peak location corresponds to a change in trapping energy from 1.3 eV for the 600 K peak to 2.1 eV for the 800 K peak. It is proposed that for implantations performed above 350 K in SCW and 450 K in PCW, deuterium-containing vacancies are able to diffuse and combine to create stable nano-bubbles within the crystal lattice. The formation of nano-bubbles due to the annihilation of deuterium-vacancy complexes results in a change in the trapping energy from 1.3 to 2.1 eV as well as a decrease in retention as some of the deuterium-vacancy complexes will be destroyed at surfaces or grain boundaries, decreasing the number of trapping sites available.

  7. Temperature dependence of deuterium retention mechanisms in tungsten

    International Nuclear Information System (INIS)

    Roszell, J.P.; Davis, J.W.; Haasz, A.A.

    2012-01-01

    The retention of 500 eV D + was measured as a function of implantation temperature in single- (SCW) and poly-crystalline (PCW) tungsten. The results show a decrease in retention of ∼2 orders of magnitude over the temperature range of 350–550 K in SCW and a decrease of an order of magnitude over the temperature range of 600–700 K in PCW. Inspection of the TDS spectra showed a shift in peak location from 600 to 800 K as temperature was increased above 350 K in SCW and above 450 K in PCW specimens. TMAP modeling showed that the change in peak location corresponds to a change in trapping energy from 1.3 eV for the 600 K peak to 2.1 eV for the 800 K peak. It is proposed that for implantations performed above 350 K in SCW and 450 K in PCW, deuterium-containing vacancies are able to diffuse and combine to create stable nano-bubbles within the crystal lattice. The formation of nano-bubbles due to the annihilation of deuterium-vacancy complexes results in a change in the trapping energy from 1.3 to 2.1 eV as well as a decrease in retention as some of the deuterium-vacancy complexes will be destroyed at surfaces or grain boundaries, decreasing the number of trapping sites available.

  8. Temperature dependence of deuterium retention mechanisms in tungsten

    Science.gov (United States)

    Roszell, J. P.; Davis, J. W.; Haasz, A. A.

    2012-10-01

    The retention of 500 eV D+ was measured as a function of implantation temperature in single- (SCW) and poly-crystalline (PCW) tungsten. The results show a decrease in retention of ˜2 orders of magnitude over the temperature range of 350-550 K in SCW and a decrease of an order of magnitude over the temperature range of 600-700 K in PCW. Inspection of the TDS spectra showed a shift in peak location from 600 to 800 K as temperature was increased above 350 K in SCW and above 450 K in PCW specimens. TMAP modeling showed that the change in peak location corresponds to a change in trapping energy from 1.3 eV for the 600 K peak to 2.1 eV for the 800 K peak. It is proposed that for implantations performed above 350 K in SCW and 450 K in PCW, deuterium-containing vacancies are able to diffuse and combine to create stable nano-bubbles within the crystal lattice. The formation of nano-bubbles due to the annihilation of deuterium-vacancy complexes results in a change in the trapping energy from 1.3 to 2.1 eV as well as a decrease in retention as some of the deuterium-vacancy complexes will be destroyed at surfaces or grain boundaries, decreasing the number of trapping sites available.

  9. Excessive Additive Effect On Engine Oil Viscosity

    Directory of Open Access Journals (Sweden)

    Vojtěch Kumbár

    2014-01-01

    Full Text Available The main goal of this paper is excessive additive (for oil filling effect on engine oil dynamic viscosity. Research is focused to commercially distribute automotive engine oil with viscosity class 15W–40 designed for vans. There were prepared blends of new and used engine oil without and with oil additive in specific ratio according manufacturer’s recommendations. Dynamic viscosity of blends with additive was compared with pure new and pure used engine oil. The temperature dependence dynamic viscosity of samples was evaluated by using rotary viscometer with standard spindle. Concern was that the oil additive can moves engine oil of several viscosity grades up. It is able to lead to failure in the engine. Mathematical models were used for fitting experimental values of dynamic viscosity. Exponential fit function was selected, which was very accurate because the coefficient of determination R2 achieved high values (0.98–0.99. These models are able to predict viscosity behaviour blends of engine oil and additive.

  10. Long-time stability effects of quadrature and artificial viscosity on nodal discontinuous Galerkin methods for gas dynamics

    Science.gov (United States)

    Durant, Bradford; Hackl, Jason; Balachandar, Sivaramakrishnan

    2017-11-01

    Nodal discontinuous Galerkin schemes present an attractive approach to robust high-order solution of the equations of fluid mechanics, but remain accompanied by subtle challenges in their consistent stabilization. The effect of quadrature choices (full mass matrix vs spectral elements), over-integration to manage aliasing errors, and explicit artificial viscosity on the numerical solution of a steady homentropic vortex are assessed over a wide range of resolutions and polynomial orders using quadrilateral elements. In both stagnant and advected vortices in periodic and non-periodic domains the need arises for explicit stabilization beyond the numerical surface fluxes of discontinuous Galerkin spectral elements. Artificial viscosity via the entropy viscosity method is assessed as a stabilizing mechanism. It is shown that the regularity of the artificial viscosity field is essential to its use for long-time stabilization of small-scale features in nodal discontinuous Galerkin solutions of the Euler equations of gas dynamics. Supported by the Department of Energy Predictive Science Academic Alliance Program Contract DE-NA0002378.

  11. Hyaluronan supplementation as a mechanical regulator of cartilage tissue development under joint-kinematic-mimicking loading.

    Science.gov (United States)

    Wu, Yabin; Stoddart, Martin J; Wuertz-Kozak, Karin; Grad, Sibylle; Alini, Mauro; Ferguson, Stephen J

    2017-08-01

    Articular cartilage plays an essential role in joint lubrication and impact absorption. Through this, the mechanical signals are coupled to the tissue's physiological response. Healthy synovial fluid has been shown to reduce and homogenize the shear stress acting on the cartilage surfaces due to its unique shear-thinning viscosity. As cartilage tissues are sensitive to mechanical changes in articulation, it was hypothesized that replacing the traditional culture medium with a healthy non-Newtonian lubricant could enhance tissue development in a cartilage engineering model, where joint-kinematic-mimicking mechanical loading is applied. Different amounts of hyaluronic acid were added to the culture medium to replicate the viscosities of synovial fluid at different health states. Hyaluronic acid supplementation, especially at a physiologically healthy concentration (2.0 mg ml -1 ), promoted a better preservation of chondrocyte phenotype. The ratio of collagen II to collagen I mRNA was 4.5 times that of the control group, implying better tissue development (however, with no significant difference of measured collagen II content), with a good retention of collagen II and proteoglycan in the mechanically active region. Simulating synovial fluid properties by hyaluronic acid supplementation created a favourable mechanical environment for mechanically loaded constructs. These findings may help in understanding the influence of joint articulation on tissue homeostasis, and moreover, improve methods for functional cartilage tissue engineering. © 2017 The Author(s).

  12. Chemical adhesion rather than mechanical retention enhances resin bond durability of a dental glass-ceramic with leucite crystallites

    Energy Technology Data Exchange (ETDEWEB)

    Meng, X F [Department of Prosthodontics, The Stomatological Hospital Affiliated Medical School, Nanjing University, Nanjing 210008 (China); Yoshida, K [Division of Applied Prosthodontics, Graduate School of Biomedical Sciences, Nagasaki University, Nagasaki 852-8588 (Japan); Gu, N, E-mail: mengsoar@nju.edu.c [Jiangsu Key Laboratory for Biomaterials and Devices, School of Biological Science and Medical Engineering, Southeast University, Nanjing 210096 (China)

    2010-08-01

    This study aims to evaluate the effect of chemical adhesion by a silane coupler and mechanical retention by hydrofluoric acid (HFA) etching on the bond durability of resin to a dental glass ceramic with leucite crystallites. Half of the ceramic plates were etched with 4.8% HFA (HFA group) for 60 s, and the other half were not treated (NoHFA group). The scale of their surface roughness and rough area was measured by a 3D laser scanning microscope. These plates then received one of the following two bond procedures to form four bond test groups: HFA/cement, NoHFA/cement, HFA/silane/cement and NoHFA/silane/cement. The associated micro-shear bond strength and bond failure modes were tested after 0 and 30 000 thermal water bath cycles. Four different silane/cement systems (Monobond S/Variolink II, GC Ceramic Primer/Linkmax HV, Clearfil Ceramic Primer/Clearfil Esthetic Cement and Porcelain Liner M/SuperBond C and B) were used. The data for each silane/cement system were analyzed by three-way ANOVA. HFA treatment significantly increased the surface R{sub a} and R{sub y} values and the rough area of the ceramic plates compared with NoHFA treatment. After 30 000 thermal water bath cycles, the bond strength of all the test groups except the HFA/Linkmax HV group was significantly reduced, while the HFA/Linkmax HV group showed only adhesive interface failure. The other HFA/cement groups and all NoHFA/cement groups lost bond strength completely, and all NoHFA/silane/cement groups with chemical adhesion had significantly higher bond strength and more ceramic cohesive failures than the respective HFA/cement groups with mechanical retention. The result of the HFA/silane/cement groups with both chemical adhesion and mechanical retention revealed that HFA treatment could enhance the bond durability of resin/silanized glass ceramics, which might result from the increase of the chemical adhesion area on the ceramic rough surface and subsequently reduced degradation speed of the silane

  13. Conditions of viscosity measurement for detecting irradiated peppers

    International Nuclear Information System (INIS)

    Hayashi, Toru; Todoriki, Setsuko; Okadome, Hiroshi; Kohyama, Kaoru

    1995-01-01

    Viscosity of gelatinized suspensions of black and white peppers decreased depending upon dose. The viscosity was influenced by gelatinization and viscosity measurement conditions. The difference between unirradiated pepper and an irradiated one was larger at a higher pH and temperature for gelatinization. A viscosity parameter normalized with the starch content of pepper sample and the viscosity of a 5% suspension of corn starch could get rid of the influence of the conditions for viscosity measurement such as type of viscometer, shear rate and temperature. (author)

  14. Longitudinal and bulk viscosities of expanded rubidium

    International Nuclear Information System (INIS)

    Zaheri, Ali Hossein Mohammad; Srivastava, Sunita; Tankeshwar, K

    2003-01-01

    First three non-vanishing sum rules for the bulk and longitudinal stress auto-correlation functions have been evaluated for liquid Rb at six thermodynamic states along the liquid-vapour coexistence curve. The Mori memory function formalism and the frequency sum rules have been used to calculate bulk and longitudinal viscosities. The results thus obtained for the ratio of bulk viscosity to shear viscosity have been compared with experimental and other theoretical predictions wherever available. The values of the bulk viscosity have been found to be more than the corresponding values of the shear viscosity for all six thermodynamic states investigated here

  15. Comparative evaluation of aqueous humor viscosity.

    Science.gov (United States)

    Davis, Kyshia; Carter, Renee; Tully, Thomas; Negulescu, Ioan; Storey, Eric

    2015-01-01

    To evaluate aqueous humor viscosity in the raptor, dog, cat, and horse, with a primary focus on the barred owl (Strix varia). Twenty-six raptors, ten dogs, three cats, and one horse. Animals were euthanized for reasons unrelated to this study. Immediately, after horizontal and vertical corneal dimensions were measured, and anterior chamber paracentesis was performed to quantify anterior chamber volume and obtain aqueous humor samples for viscosity analysis. Dynamic aqueous humor viscosity was measured using a dynamic shear rheometer (AR 1000 TA Instruments, New Castle, DE, USA) at 20 °C. Statistical analysis included descriptive statistics, unpaired t-tests, and Tukey's test to evaluate the mean ± standard deviation for corneal diameter, anterior chamber volume, and aqueous humor viscosity amongst groups and calculation of Spearman's coefficient for correlation analyses. The mean aqueous humor viscosity in the barred owl was 14.1 centipoise (cP) ± 9, cat 4.4 cP ± 0.2, and dog 2.9 cP ± 1.3. The aqueous humor viscosity for the horse was 1 cP. Of the animals evaluated in this study, the raptor aqueous humor was the most viscous. The aqueous humor of the barred owl is significantly more viscous than the dog (P humor viscosity of the raptor, dog, cat, and horse can be successfully determined using a dynamic shear rheometer. © 2014 American College of Veterinary Ophthalmologists.

  16. The Friction Theory for Viscosity Modeling

    DEFF Research Database (Denmark)

    Cisneros, Sergio; Zeberg-Mikkelsen, Claus Kjær; Stenby, Erling Halfdan

    2001-01-01

    , in the case when experimental information is available a more accurate modeling can be obtained by means of a simple tuning procedure. A tuned f-theory general model can deliver highly accurate viscosity modeling above the saturation pressure and good prediction of the liquid-phase viscosity at pressures......In this work the one-parameter friction theory (f-theory) general models have been extended to the viscosity prediction and modeling of characterized oils. It is demonstrated that these simple models, which take advantage of the repulsive and attractive pressure terms of cubic equations of state...... such as the SRK, PR and PRSV, can provide accurate viscosity prediction and modeling of characterized oils. In the case of light reservoir oils, whose properties are close to those of normal alkanes, the one-parameter f-theory general models can predict the viscosity of these fluids with good accuracy. Yet...

  17. Increasing viscosity and inertia using a robotically-controlled pen improves handwriting in children

    Science.gov (United States)

    Ben-Pazi, Hilla; Ishihara, Abraham; Kukke, Sahana; Sanger, Terence D

    2010-01-01

    The aim of this study was to determine the effect of mechanical properties of the pen on the quality of handwriting in children. Twenty two school aged children, ages 8–14 years wrote in cursive using a pen attached to a robot. The robot was programmed to increase the effective weight (inertia) and stiffness (viscosity) of the pen. Speed, frequency, variability, and quality of the two handwriting samples were compared. Increased inertia and viscosity improved handwriting quality in 85% of children (pHandwriting quality did not correlate with changes in speed, suggesting that improvement was not due to reduced speed. Measures of movement variability remained unchanged, suggesting that improvement was not due to mechanical smoothing of pen movement by the robot. Since improvement was not explained by reduced speed or mechanical smoothing, we conclude that children alter handwriting movements in response to pen mechanics. Altered movement could be caused by changes in proprioceptive sensory feedback. PMID:19794098

  18. Proteinuric diseases with sodium retention: Is plasmin the link?

    DEFF Research Database (Denmark)

    Svenningsen, Per; Skøtt, Ole; Jensen, Boye L

    2012-01-01

    1. Sodium retention in disease states characterized by proteinuria, such as nephrotic syndrome, preeclampsia, and diabetic nephropathy, occurs through poorly understood mechanism(s). 2. In the nephrotic syndrome, data from experimental and clinical studies indicate that the sodium retention...... originates in the renal cortical collecting duct and involves hyper-activity of the epithelial sodium channel (ENaC). 3. The stimulus for the increased ENaC activity does not appear to involve any of the classical sodium retaining mechanisms, such as the renin-angiotensin-aldosterone system, arginine...... and diabetic nephropathy, which are also characterized by proteinuria and sodium retention. 7. In this review, we will examine the evidence for a role of urinary serine protease activity in the development of sodium and water retention in diseases characterised by proteinuria with a focus on the nephrotic...

  19. VISCOSITY DICTATES METABOLIC ACTIVITY of Vibrio ruber

    Directory of Open Access Journals (Sweden)

    Maja eBoric

    2012-07-01

    Full Text Available Little is known about metabolic activity of bacteria, when viscosity of their environment changes. In this work, bacterial metabolic activity in media with viscosity ranging from 0.8 to 29.4 mPas was studied. Viscosities up to 2.4 mPas did not affect metabolic activity of Vibrio ruber. On the other hand, at 29.4 mPas respiration rate and total dehydrogenase activity increased 8 and 4-fold, respectively. The activity of glucose-6-phosphate dehydrogenase increased up to 13-fold at higher viscosities. However, intensified metabolic activity did not result in faster growth rate. Increased viscosity delayed the onset as well as the duration of biosynthesis of prodigiosin. As an adaptation to viscous environment V. ruber increased metabolic flux through the pentose phosphate pathway and reduced synthesis of a secondary metabolite. In addition, V. ruber was able to modify the viscosity of its environment.

  20. Colloidal suspensions hydrodynamic retention mechanisms in model porous media; Mecanismes de retention hydrodynamique de suspensions colloidales en milieux poreux modeles

    Energy Technology Data Exchange (ETDEWEB)

    Salehi, N

    1996-04-19

    This study deals with the retention mechanisms of colloidal particles in porous media flows, and the subsequent reduction in permeability in the case of stable and non adsorbing colloids. It combines experimental results and modelling. This study has been realised with stable dispersion of monodispersed carboxylate polystyrene latexes negatively charged injected through negatively charged polycarbonate membranes having mono-sized cylindrical pores. The mean particle diameter is smaller than the mean pore diameter. Both batch and flow experiments in Nuclepore membranes have been done. The results of batch experiments have proved no adsorption of the colloidal latex particles on the surface of the Nuclepore membranes without flow at low salinity. In flow experiments at low particle concentration, only deposition on the upstream side of the membrane have been induced by hydrodynamic forces even for non adsorbing particles without creating any permeability reduction. The retention levels are zero at low and high Peclet numbers with a maximum at intermediate values. Partial plugging was observed at higher colloid concentration even at low salinity without any upstream surface deposition. The modelling of plugging processes is achieved by considering the particle concentration, fluid rate and ratio between the mean pore diameter and the mean particle diameter. This study can be particularly useful in the fields of water treatment and of restoration of lands following radioactive contamination. (author). 96 refs., 99 figs., 29 tabs.

  1. Bulk viscosity of spin-one color superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Sa' d, Basil A.

    2009-08-27

    The bulk viscosity of several quark matter phases is calculated. It is found that the effect of color superconductivity is not trivial, it may suppress, or enhance the bulk viscosity depending on the critical temperature and the temperature at which the bulk viscosity is calculated. Also, is it found that the effect of neutrino-emitting Urca processes cannot be neglected in the consideration of the bulk viscosity of strange quark matter. The results for the bulk viscosity of strange quark matter are used to calculate the r-mode instability window of quark stars with several possible phases. It is shown that each possible phase has a different structure for the r-mode instability window. (orig.)

  2. Bulk viscosity of spin-one color superconductors

    International Nuclear Information System (INIS)

    Sa'd, Basil A.

    2009-01-01

    The bulk viscosity of several quark matter phases is calculated. It is found that the effect of color superconductivity is not trivial, it may suppress, or enhance the bulk viscosity depending on the critical temperature and the temperature at which the bulk viscosity is calculated. Also, is it found that the effect of neutrino-emitting Urca processes cannot be neglected in the consideration of the bulk viscosity of strange quark matter. The results for the bulk viscosity of strange quark matter are used to calculate the r-mode instability window of quark stars with several possible phases. It is shown that each possible phase has a different structure for the r-mode instability window. (orig.)

  3. SUMMARY OF FY11 SULFATE RETENTION STUDIES FOR DEFENSE WASTE PROCESSING FACILITY GLASS

    Energy Technology Data Exchange (ETDEWEB)

    Fox, K.; Edwards, T.

    2012-05-08

    This report describes the results of studies related to the incorporation of sulfate in high level waste (HLW) borosilicate glass produced at the Savannah River Site (SRS) Defense Waste Processing Facility (DWPF). A group of simulated HLW glasses produced for earlier sulfate retention studies was selected for full chemical composition measurements to determine whether there is any clear link between composition and sulfate retention over the compositional region evaluated. In addition, the viscosity of several glasses was measured to support future efforts in modeling sulfate solubility as a function of predicted viscosity. The intent of these studies was to develop a better understanding of sulfate retention in borosilicate HLW glass to allow for higher loadings of sulfate containing waste. Based on the results of these and other studies, the ability to improve sulfate solubility in DWPF borosilicate glasses lies in reducing the connectivity of the glass network structure. This can be achieved, as an example, by increasing the concentration of alkali species in the glass. However, this must be balanced with other effects of reduced network connectivity, such as reduced viscosity, potentially lower chemical durability, and in the case of higher sodium and aluminum concentrations, the propensity for nepheline crystallization. Future DWPF processing is likely to target higher waste loadings and higher sludge sodium concentrations, meaning that alkali concentrations in the glass will already be relatively high. It is therefore unlikely that there will be the ability to target significantly higher total alkali concentrations in the glass solely to support increased sulfate solubility without the increased alkali concentration causing failure of other Product Composition Control System (PCCS) constraints, such as low viscosity and durability. No individual components were found to provide a significant improvement in sulfate retention (i.e., an increase of the magnitude

  4. Viscosity of particle laden films

    Directory of Open Access Journals (Sweden)

    Timounay Yousra

    2017-01-01

    Full Text Available We perform retraction experiments on soap films where large particles bridge the two interfaces. Local velocities are measured by PIV during the unstationnary regime. The velocity variation in time and space can be described by a continuous fluid model from which effective viscosity (shear and dilatational of particulate films is measured. The 2D effective viscosity of particulate films η2D increases with particle surface fraction ϕ: at low ϕ, it tends to the interfacial dilatational viscosity of the liquid/air interfaces and it diverges at the critical particle surface fraction ϕc ≃ 0.84. Experimental data agree with classical viscosity laws of hard spheres suspensions adapted to the 2D geometry, assuming viscous dissipation resulting from the squeeze of the liquid/air interfaces between the particles. Finally, we show that the observed viscous dissipation in particulate films has to be considered to describe the edge velocity during a retraction experiment at large particle coverage.

  5. Viscosity of particle laden films

    Science.gov (United States)

    Timounay, Yousra; Rouyer, Florence

    2017-06-01

    We perform retraction experiments on soap films where large particles bridge the two interfaces. Local velocities are measured by PIV during the unstationnary regime. The velocity variation in time and space can be described by a continuous fluid model from which effective viscosity (shear and dilatational) of particulate films is measured. The 2D effective viscosity of particulate films η2D increases with particle surface fraction ϕ: at low ϕ, it tends to the interfacial dilatational viscosity of the liquid/air interfaces and it diverges at the critical particle surface fraction ϕc ≃ 0.84. Experimental data agree with classical viscosity laws of hard spheres suspensions adapted to the 2D geometry, assuming viscous dissipation resulting from the squeeze of the liquid/air interfaces between the particles. Finally, we show that the observed viscous dissipation in particulate films has to be considered to describe the edge velocity during a retraction experiment at large particle coverage.

  6. Translocation of a polymer through a nanopore across a viscosity gradient.

    Science.gov (United States)

    de Haan, Hendrick W; Slater, Gary W

    2013-04-01

    The translocation of a polymer through a pore in a membrane separating fluids of different viscosities is studied via several computational approaches. Starting with the polymer halfway, we find that as a viscosity difference across the pore is introduced, translocation will predominately occur towards one side of the membrane. These results suggest an intrinsic pumping mechanism for translocation across cell walls which could arise whenever the fluid across the membrane is inhomogeneous. Somewhat surprisingly, the sign of the preferred direction of translocation is found to be strongly dependent on the simulation algorithm: for Langevin dynamics (LD) simulations, a bias towards the low viscosity side is found while for Brownian dynamics (BD), a bias towards the high viscosity is found. Examining the translocation dynamics in detail across a wide range of viscosity gradients and developing a simple force model to estimate the magnitude of the bias, the LD results are demonstrated to be more physically realistic. The LD results are also compared to those generated from a simple, one-dimensional random walk model of translocation to investigate the role of the internal degrees of freedom of the polymer and the entropic barrier. To conclude, the scaling of the results across different polymer lengths demonstrates the saturation of the directional preference with polymer length and the nontrivial location of the maximum in the exponent corresponding to the scaling of the translocation time with polymer length.

  7. Whole-blood viscosity and the insulin-resistance syndrome.

    Science.gov (United States)

    Høieggen, A; Fossum, E; Moan, A; Enger, E; Kjeldsen, S E

    1998-02-01

    In a previous study we found that elevated blood viscosity was linked to the insulin resistance syndrome, and we proposed that high blood viscosity may increase insulin resistance. That study was based on calculated viscosity. To determine whether directly measured whole-blood viscosity was related to the insulin-resistance syndrome in the same way as calculated viscosity had been found to be. Healthy young men were examined with the hyperinsulinemic isoglycemic glucose clamp technique, and we related insulin sensitivity (glucose disposal rate) to other metabolic parameters and to blood viscosity. We established a technique for direct measurement of whole-blood viscosity. There were statistically significant negative correlations between glucose disposal rate and whole-blood viscosity at low and high shear rates (r = -0.41, P = 0.007 for both, n = 42). Whole-blood viscosity was correlated positively (n = 15) to serum triglyceride (r = 0.54, P = 0.04) and total cholesterol (r = 0.52, P = 0.05), and negatively with high-density lipoprotein cholesterol (r = -0.53, P = 0.04) concentrations. Insulin sensitivity index was correlated positively to high-density lipoprotein cholesterol (r = 0.54, P = 0.04) and negatively to serum triglyceride (r = -0.69, P = 0.005) and to total cholesterol (r = -0.81, P = 0.0003) concentrations. The present results demonstrate for the first time that there is a negative relationship between directly measured whole-blood viscosity and insulin sensitivity as a part of the insulin-resistance syndrome. Whole-blood viscosity contributes to the total peripheral resistance, and these results support the hypothesis that insulin resistance has a hemodynamic basis.

  8. The effectivity of bentonites in cesium retention of cemented waste products

    International Nuclear Information System (INIS)

    Tello, Cledola Cassia Oliveira de

    2001-01-01

    The nuclear energy has been used for the human development in different areas, as in the medicine, in the agriculture, in the industry and in the environmental protection, besides the electricity generation. As in other activities, in the use of nuclear energy, residues are also generated. They are considered radioactive wastes when the contaminant content can bring a potential negative impact in the human health and in the environment. In this case they should be properly managed and should not be released without treatment. In general the waste processing consists in a volume reduction followed by solidification and/or conditioning. A number of materials can be considered as immobilisation matrices for the wastes, with the objective of maintain the radioactive material physical and chemically stable. The cement is extensively used because it is easy to obtain, there is large. experience in its use and the processing is done at room temperature. Many materials have been studied to improve the fixation characteristics of the radionuclides in the cemented product. The aim of this study was to search, among Brazilian natural materials, those that could be effective in the contaminant retention without jeopardising the process and other characteristics of the waste product. Four types of bentonite were selected to the process and product evaluation tests. Many mixtures were prepared with simulated waste, cement and bentonite in different proportions. The viscosity, set time, compressive strength and leaching were evaluated. In addition it was verified if the products were monolithic and without free water. Inactive caesium was used as tracer. The leaching resistance is the most important parameter in the product evaluation, because it indicates the retention capacity of the matrix for radionuclides when the product is in contact with the water. In 1985 leaching tests were begun and they have been continued till now and from their results it was proved that the

  9. Effect of viscosity, basicity and organic content of composite flocculant on the decolorization performance and mechanism for reactive dyeing wastewater

    Institute of Scientific and Technical Information of China (English)

    Yuanfang Wang; Baoyu Gao; Qinyan Yue; Yah Wang

    2011-01-01

    A coagulation/flocculation process using the composite floceulant polyaluminum chloride-epichlorohydrin dimethylamine (PAC-EPI-DMA) was employed for the treatment of an anionic azo dye (Reactive Brilliant Red K-2BP dye).The effect of viscosity (η),basicity (B =[OH]/[Al]) and organic content (Wp) on the flocculation performance as well as the mechanism of PAC-EPI-DMA flocculant were investigated.The η was the key factor affecting the dye removal efficiency of PAC-EPI-DMA.PAC-EPI-DMA with an intermediate η (2400 mPa-sec) gave higher decolorization efficiency by adsorption bridging and charge neutralization due to the co-effect of PAC and EPI-DMA polymers.The Wp of the composite flocculant was a minor important factor for the flocculation.The adsorption bridging of PAC-EPI-DMA with η of 300 or 4300 mPa.sec played an important role with the increase of Wp,whereasthe charge neutralization of them was weaker with the increase of Wp.There was interaction between Wp and B on the removal of reactive dye.The composite flocculant with intermediate viscosity and organic content was effective for the treatment of reactive dyeing wastewater,which could achieve high reactive dye removal efficiency with low organic dosage.

  10. Ciliary-propelling mechanism, effect of temperature and viscosity on swimming speed, and adaptive significance of ‘jumping’ in the ciliate Mesodinium rubrum

    DEFF Research Database (Denmark)

    Riisgård, Hans Ulrik; Larsen, Poul Scheel

    2009-01-01

    , hence increasing viscosity, from 9.6 +/- 0.3 mm/s at 21C to 5.2 +/- 0.7 mm/s at 9.8C for seawater, and down to 3.7 +/- 0.5 mm/s at a temperature equivalent Te = 5.8C for PVP-manipulated viscosity, and further, the swimming velocity was found to decrease with increasing viscosity according to the power...

  11. Near Wellbore Hydraulic Fracture Propagation from Perforations in Tight Rocks: The Roles of Fracturing Fluid Viscosity and Injection Rate

    Directory of Open Access Journals (Sweden)

    Seyed Hassan Fallahzadeh

    2017-03-01

    Full Text Available Hydraulic fracture initiation and near wellbore propagation is governed by complex failure mechanisms, especially in cased perforated wellbores. Various parameters affect such mechanisms, including fracturing fluid viscosity and injection rate. In this study, three different fracturing fluids with viscosities ranging from 20 to 600 Pa.s were used to investigate the effects of varying fracturing fluid viscosities and fluid injection rates on the fracturing mechanisms. Hydraulic fracturing tests were conducted in cased perforated boreholes made in tight 150 mm synthetic cubic samples. A true tri-axial stress cell was used to simulate real far field stress conditions. In addition, dimensional analyses were performed to correspond the results of lab experiments to field-scale operations. The results indicated that by increasing the fracturing fluid viscosity and injection rate, the fracturing energy increased, and consequently, higher fracturing pressures were observed. However, when the fracturing energy was transferred to a borehole at a faster rate, the fracture initiation angle also increased. This resulted in more curved fracture planes. Accordingly, a new parameter, called fracturing power, was introduced to relate fracture geometry to fluid viscosity and injection rate. Furthermore, it was observed that the presence of casing in the wellbore impacted the stress distribution around the casing in such a way that the fracture propagation deviated from the wellbore vicinity.

  12. Studies on the retention mechanism of solutes in hydrophilic interaction chromatography using stoichiometric displacement theory I. The linear relationship of lgk' vs. lg[H2O].

    Science.gov (United States)

    Wang, Fei; Yang, Fan; Tian, Yang; Liu, Jiawei; Shen, Jiwei; Bai, Quan

    2018-01-01

    A stoichiometric displacement model for retention (SDM-R) of small solutes and proteins based on hydrophilic interaction chromatography (HILIC) was presented. A linear equation that related the logarithm of the capacity factor of the solute to the logarithm of the concentration of water in the mobile phase was derived. The stoichiometric displacement parameters, Z (the number of water molecules required to displace a solute from ligands) and lgI (containing a number of constants that relate to the affinity of solute to the ligands) could be obtained from the slope and the intercept of the linear plots of lgk' vs. lg[H 2 O]. The retention behaviors and retention mechanism of 15 kinds of small solutes and 6 kinds of proteins on 5 kinds HILIC columns with different ligands were investigated with SDM-R in typical range of water concentration in mobile phase. A good linear relationship between lgk' and lg[H 2 O] demonstrated that the most rational retention mechanism of solute in HILIC was a stoichiometric displacement process between solute and solvent molecules with water as displacing agents, which was not only valid for small solutes, but also could be used to explain the retention mechanism of biopolymers in HILIC. Comparing with the partition and adsorption models in HILIC, SDM-R was superior to them. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. Viscose kink and drift-kink modes in a tokamak

    International Nuclear Information System (INIS)

    Kuvshinov, B.N.; Mikhajlovskij, A.B.

    1988-01-01

    Intristic kink modes in a tokamak are theoretically investigated taking account of longitudinal viscosity of ions and electrons and drift effect. It is marked that dispersion equation of investigated modes coinsides in form with that for ballooning modes. It is shown that five types of intrinsic kink instability may be distinguished in disregard of viscosity and drift effects. Effect of stabilizing quasiideal viscose kink and viscose resistive kink modes by finite Larmuir ion radius is investigated. A branch of viscose reclosure mode which instability is due to electron viscosity is pointed out. A series of other viscose and drift-kink tokamak modes is considered. Both general disperse equations of the above-mentioned kink instability varieties, taking account of viscose and drift ones, and disperse equations of separate branches are presented

  14. Idiosyncrasies of volcanic sulfur viscosity and the triggering of unheralded volcanic eruptions

    Directory of Open Access Journals (Sweden)

    Teresa eScolamacchia

    2016-03-01

    Full Text Available Unheralded blue-sky eruptions from dormant volcanoes cause serious fatalities, such as at Mt. Ontake (Japan on 27 September 2014. Could these events result from magmatic gas being trapped within hydrothermal system aquifers by elemental sulfur (Se clogging pores, due to sharp increases in its viscosity when heated above 159oC? This mechanism was thought to prime unheralded eruptions at Mt. Ruapehu in New Zealand. Impurities in sulfur (As, Te, Se are known to modify S-viscosity and industry experiments showed that organic compounds, H2S, and halogens dramatically influence Se viscosity under typical hydrothermal heating/cooling rates and temperature thresholds. However, the effects of complex sulfur compositions are currently ignored at volcanoes, despite its near ubiquity in long-lived volcano-hydrothermal systems. Models of impure S behavior must be urgently formulated to detect pre-eruptive warning signs before the next blue-sky eruption

  15. A mathematical model for the movement of food bolus of varying viscosities through the esophagus

    Science.gov (United States)

    Tripathi, Dharmendra

    2011-09-01

    This mathematical model is designed to study the influence of viscosity on swallowing of food bolus through the esophagus. Food bolus is considered as viscous fluid with variable viscosity. Geometry of esophagus is assumed as finite length channel and flow is induced by peristaltic wave along the length of channel walls. The expressions for axial velocity, transverse velocity, pressure gradient, volume flow rate and stream function are obtained under the assumptions of long wavelength and low Reynolds number. The impacts of viscosity parameter on pressure distribution, local wall shear stress, mechanical efficiency and trapping are numerically discussed with the help of computational results. On the basis of presented study, it is revealed that swallowing of low viscous fluids through esophagus requires less effort in comparison to fluids of higher viscosity. This result is similar to the experimental result obtained by Raut et al. [1], Dodds [2] and Ren et al. [3]. It is further concluded that the pumping efficiency increases while size of trapped bolus reduces when viscosity of fluid is high.

  16. VISCOSITY TEST OF VEHICLE ENGINE OILS

    OpenAIRE

    Rita Prasetyowati

    2016-01-01

    This study aims to determine the value of the kinematic viscosity lubricants motorcycle that has been used at various temperatures and the use of distance. This study also aims to remedy mengtahui how the value of the kinematic viscosity of the lubricant car that has been used in a wide range of temperature variation and distance usage. Viscosity liquid, in this case is the lubricants, can be determined using the Redwood viscometer By using Redwood viscometer, can be measured flow time requir...

  17. Viscosity Control Experiment Feasibility Study

    Energy Technology Data Exchange (ETDEWEB)

    Morris, Heidi E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Bradley, Paul Andrew [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2018-01-31

    Turbulent mix has been invoked to explain many results in Inertial Confinement Fusion (ICF) and High Energy Density (HED) physics, such as reduced yield in capsule implosions. Many ICF capsule implosions exhibit interfacial instabilities seeded by the drive shock, but it is not clear that fully developed turbulence results from this. Many simulations use turbulent mix models to help match simulation results to data, but this is not appropriate if turbulence is not present. It would be useful to have an experiment where turbulent mixing could be turned on or off by design. The use of high-Z dopants to modify viscosity and the resulting influence on turbulence is considered here. A complicating factor is that the plasma in some implosions can become strongly coupled, which makes the Spitzer expression for viscosity invalid. We first consider equations that cover a broad parameter space in temperature and density to address regimes for various experimental applications. Next, a previous shock-tube and other ICF experiments that investigate viscosity or use doping to examine the effects on yield are reviewed. How viscosity and dopants play a role in capsule yield depends on the region and process under consideration. Experiments and simulations have been performed to study the effects of viscosity on both the hot spot and the fuel/ablator mix. Increases in yield have been seen for some designs, but not all. We then discuss the effect of adding krypton dopant to the gas region of a typical OMEGA and a 2-shock NIF implosion to determine approximately the effect of adding dopant on the computed Reynolds number. Recommendations for a path forward for possible experiments using high-Z dopants to affect viscosity and turbulence are made.

  18. A comparative study of high-viscosity cement percutaneous vertebroplasty vs. low-viscosity cement percutaneous kyphoplasty for treatment of osteoporotic vertebral compression fractures.

    Science.gov (United States)

    Sun, Kai; Liu, Yang; Peng, Hao; Tan, Jun-Feng; Zhang, Mi; Zheng, Xian-Nian; Chen, Fang-Zhou; Li, Ming-Hui

    2016-06-01

    The clinical effects of two different methods-high-viscosity cement percutaneous vertebroplasty (PVP) and low-viscosity cement percutaneous kyphoplasty (PKP) in the treatment of osteoporotic vertebral compression fractures (OVCFs) were investigated. From June 2010 to August 2013, 98 cases of OVCFs were included in our study. Forty-six patients underwent high-viscosity PVP and 52 patients underwent low-viscosity PKP. The occurrence of cement leakage was observed. Pain relief and functional activity were evaluated using the Visual Analog Scale (VAS) and Oswestry Disability Index (ODI), respectively. Restoration of the vertebral body height and angle of kyphosis were assessed by comparing preoperative and postoperative measurements of the anterior heights, middle heights and the kyphotic angle of the fractured vertebra. Nine out of the 54 vertebra bodies and 11 out of the 60 vertebra bodies were observed to have cement leakage in the high-viscosity PVP and low-viscosity PKP groups, respectively. The rate of cement leakage, correction of anterior vertebral height and kyphotic angles showed no significant differences between the two groups (P>0.05). Low-viscosity PKP had significant advantage in terms of the restoration of middle vertebral height as compared with the high-viscosity PVP (Pviscosity PVP and low-viscosity PKP have similar clinical effects in terms of the rate of cement leakage, restoration of the anterior vertebral body height, changes of kyphotic angles, functional activity, and pain relief. Low-viscosity PKP is better than high-viscosity PVP in restoring the height of the middle vertebra.

  19. Viscosity of iodinated contrast agents during renal excretion

    International Nuclear Information System (INIS)

    Jost, Gregor; Lengsfeld, Philipp; Lenhard, Diana C.; Pietsch, Hubertus; Huetter, Joachim; Sieber, Martin A.

    2011-01-01

    Objective: Modern iodinated non-ionic contrast agents (CAs) can be classified based on their molecular structure into monomeric and dimeric CAs and have at comparable iodine concentrations a different viscosity and osmolality. During their renal excretion, CAs are concentrated in the renal tubuli which might enhance the viscosity difference between monomeric and dimeric CAs. The viscosity of a CA might have an underestimated importance for renal safety, as suggested by recent publications. In this study, we investigated the viscosities of CAs at the concentrations expected to be present in renal tubules. This concentration process was simulated in vitro using dialysis. Furthermore, we investigated urine viscosity and urine flow in rodents after administration of several non-ionic monomeric and dimeric CAs. Materials and methods: To estimate the viscosity of the CAs in vivo, we performed an in vitro dialysis of monomeric and dimeric CAs at various physiological osmolalities of the renal tubulus (290, 400, 500, 700 and 1000 mOsm/kg H 2 O). Following the dialysis, the iodine concentrations and the viscosities of the CAs were determined. Furthermore, to investigate the concentration process in vivo, we measured the urine viscosity and the urine flow in Han Wister rats after the administration of Iopromide, Iohexol, Ioversol, Iomeprol, Iodixanol, and Iosimenol at comparable iodine concentrations. As a control, saline was injected at the same volume. Results: In vitro dialysis of the dimeric CA increased the iodine concentration and strongly increased the viscosity at all tested osmolalities. In contrast, for the monomeric agents an increase in concentration and viscosity was observed only at 700 as well 1000 mOsm/kg H 2 O but to a lesser extent. In summary, dialysis strongly enhanced the viscosity differences between the non-ionic monomeric and dimeric CAs. The administration of dimeric CAs leads to a strong increase in urine viscosity; this was not observed for the

  20. Viscosity of iodinated contrast agents during renal excretion

    Energy Technology Data Exchange (ETDEWEB)

    Jost, Gregor, E-mail: Gregor.Jost@bayer.com [TRG Diagnostic Imaging, Bayer Schering Pharma AG, Berlin (Germany); Lengsfeld, Philipp, E-mail: Philipp.Lengsfeld@bayer.com [Global Medical Affairs Diagnostic Imaging, Bayer Schering Pharma AG, Berlin (Germany); Lenhard, Diana C., E-mail: Diana.Lenhard@bayer.com [TRG Diagnostic Imaging, Bayer Schering Pharma AG, Berlin (Germany); Pietsch, Hubertus, E-mail: Hubertus.Pietsch@bayer.com [TRG Diagnostic Imaging, Bayer Schering Pharma AG, Berlin (Germany); Huetter, Joachim, E-mail: Joachim.Huetter@bayer.com [TRG Diagnostic Imaging, Bayer Schering Pharma AG, Berlin (Germany); Sieber, Martin A., E-mail: Martin.Sieber@bayer.com [TRG Diagnostic Imaging, Bayer Schering Pharma AG, Berlin (Germany)

    2011-11-15

    Objective: Modern iodinated non-ionic contrast agents (CAs) can be classified based on their molecular structure into monomeric and dimeric CAs and have at comparable iodine concentrations a different viscosity and osmolality. During their renal excretion, CAs are concentrated in the renal tubuli which might enhance the viscosity difference between monomeric and dimeric CAs. The viscosity of a CA might have an underestimated importance for renal safety, as suggested by recent publications. In this study, we investigated the viscosities of CAs at the concentrations expected to be present in renal tubules. This concentration process was simulated in vitro using dialysis. Furthermore, we investigated urine viscosity and urine flow in rodents after administration of several non-ionic monomeric and dimeric CAs. Materials and methods: To estimate the viscosity of the CAs in vivo, we performed an in vitro dialysis of monomeric and dimeric CAs at various physiological osmolalities of the renal tubulus (290, 400, 500, 700 and 1000 mOsm/kg H{sub 2}O). Following the dialysis, the iodine concentrations and the viscosities of the CAs were determined. Furthermore, to investigate the concentration process in vivo, we measured the urine viscosity and the urine flow in Han Wister rats after the administration of Iopromide, Iohexol, Ioversol, Iomeprol, Iodixanol, and Iosimenol at comparable iodine concentrations. As a control, saline was injected at the same volume. Results: In vitro dialysis of the dimeric CA increased the iodine concentration and strongly increased the viscosity at all tested osmolalities. In contrast, for the monomeric agents an increase in concentration and viscosity was observed only at 700 as well 1000 mOsm/kg H{sub 2}O but to a lesser extent. In summary, dialysis strongly enhanced the viscosity differences between the non-ionic monomeric and dimeric CAs. The administration of dimeric CAs leads to a strong increase in urine viscosity; this was not observed for

  1. Pressure Effect on Extensional Viscosity

    DEFF Research Database (Denmark)

    Christensen, Jens Horslund; Kjær, Erik Michael

    1999-01-01

    The primary object of these experiments was to investigate the influence of hydrostatic pressure on entrance flow. The effect of pressure on shear and extensional viscosity was evaluated using an axis symmetric capillary and a slit die where the hydrostatic pressure was raised with valves....... The experiments show a significant increase in extensional viscosity with increasing pressure....

  2. Bulk viscosity in holographic Lifshitz hydrodynamics

    International Nuclear Information System (INIS)

    Hoyos, Carlos; Kim, Bom Soo; Oz, Yaron

    2014-01-01

    We compute the bulk viscosity in holographic models dual to theories with Lifshitz scaling and/or hyperscaling violation, using a generalization of the bulk viscosity formula derived in arXiv:1103.1657 from the null focusing equation. We find that only a class of models with massive vector fields are truly Lifshitz scale invariant, and have a vanishing bulk viscosity. For other holographic models with scalars and/or massless vector fields we find a universal formula in terms of the dynamical exponent and the hyperscaling violation exponent

  3. Viscosity measurement techniques in Dissipative Particle Dynamics

    Science.gov (United States)

    Boromand, Arman; Jamali, Safa; Maia, Joao M.

    2015-11-01

    In this study two main groups of viscosity measurement techniques are used to measure the viscosity of a simple fluid using Dissipative Particle Dynamics, DPD. In the first method, a microscopic definition of the pressure tensor is used in equilibrium and out of equilibrium to measure the zero-shear viscosity and shear viscosity, respectively. In the second method, a periodic Poiseuille flow and start-up transient shear flow is used and the shear viscosity is obtained from the velocity profiles by a numerical fitting procedure. Using the standard Lees-Edward boundary condition for DPD will result in incorrect velocity profiles at high values of the dissipative parameter. Although this issue was partially addressed in Chatterjee (2007), in this work we present further modifications (Lagrangian approach) to the original LE boundary condition (Eulerian approach) that will fix the deviation from the desired shear rate at high values of the dissipative parameter and decrease the noise to signal ratios in stress measurement while increases the accessible low shear rate window. Also, the thermostat effect of the dissipative and random forces is coupled to the dynamic response of the system and affects the transport properties like the viscosity and diffusion coefficient. We investigated thoroughly the dependency of viscosity measured by both Eulerian and Lagrangian methodologies, as well as numerical fitting procedures and found that all the methods are in quantitative agreement.

  4. Viscosity properties of sodium borophosphate glasses

    International Nuclear Information System (INIS)

    Gaylord, S.; Tincher, B.; Petit, L.; Richardson, K.

    2009-01-01

    The viscosity behavior of (1 - x)NaPO 3 -xNa 2 B 4 O 7 glasses (x = 0.05-0.20) have been measured as a function of temperature using beam-bending and parallel-plate viscometry. The viscosity was found to shift to higher temperatures with increasing sodium borate content. The kinetic fragility parameter, m, estimated from the viscosity curve, decreases from 52 to 33 when x increases from 0.05 to 0.20 indicating that the glass network transforms from fragile to strong with the addition of Na 2 B 4 O 7 . The decrease in fragility with increasing x is due to the progressive depolymerization of the phosphate network by the preferred four-coordinated boron atoms present in the low alkali borate glasses. As confirmed by Raman spectroscopy increasing alkali borate leads to enhanced B-O-P linkages realized with the accompanying transition from solely four-coordinated boron (in BO 4 units) to mixed BO 4 /BO 3 structures. The glass viscosity characteristics of the investigated glasses were compared to those of P-SF67 and N-FK5 commercial glasses from SCHOTT. We showed that the dependence of the viscosity of P-SF67 was similar to the investigated glasses due to similar phosphate network organization confirmed by Raman spectroscopy, whereas N-FK5 exhibited a very different viscosity curve and fragility parameter due to its highly coordinated silicate network

  5. Orientational ordering as a possible mechanism for viscosity-enhancement of supercooled liquids

    International Nuclear Information System (INIS)

    Dattagupta, S.

    1990-07-01

    A supercooled liquid is viewed to have regions of local orientational order which can be picturized in terms of cages that restrict single particle diffusion. The mismatch in the orientation of two locally ordered neighbouring regions causes an internal stress which is added to the stress that appears in the Maxwell model of viscoelasticity. This leads to a ''renormalized'' Maxwell time which is related to the susceptibility associated with the orientational order. Hence, when the latter becomes very large, one obtains a large enhancement of the viscosity. (author). 7 refs

  6. Viscosity of aqueous and cyanate ester suspensions containing alumina nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Lawler, Katherine [Iowa State Univ., Ames, IA (United States)

    2009-01-01

    The viscosities of both aqueous and cyanate ester monomer (BECy) based suspensions of alumina nanoparticle were studied. The applications for these suspensions are different: aqueous suspensions of alumina nanoparticles are used in the production of technical ceramics made by slip casting or tape casting, and the BECy based suspensions are being developed for use in an injection-type composite repair resin. In the case of aqueous suspensions, it is advantageous to achieve a high solids content with low viscosity in order to produce a high quality product. The addition of a dispersant is useful so that higher solids content suspensions can be used with lower viscosities. For BECy suspensions, the addition of nanoparticles to the BECy resin is expected to enhance the mechanical properties of the cured composite. The addition of saccharides to aqueous suspensions leads to viscosity reduction. Through DSC measurements it was found that the saccharide molecules formed a solution with water and this resulted in lowering the melting temperature of the free water according to classic freezing point depression. Saccharides also lowered the melting temperature of the bound water, but this followed a different rule. The shear thinning and melting behaviors of the suspensions were used to develop a model based on fractal-type agglomeration. It is believed that the structure of the particle flocs in these suspensions changes with the addition of saccharides which leads to the resultant viscosity decrease. The viscosity of the BECy suspensions increased with solids content, and the viscosity increase was greater than predicted by the classical Einstein equation for dilute suspensions. Instead, the Mooney equation fits the viscosity behavior well from 0-20 vol% solids. The viscosity reduction achieved at high particle loadings by the addition of benzoic acid was also investigated by NMR. It appears that the benzoic acid interacts with the surface of the alumina particle which may

  7. Uniaxial Elongational viscosity of bidisperse polystyrene melts

    DEFF Research Database (Denmark)

    Nielsen, Jens Kromann; Rasmussen, Henrik K.; Hassager, Ole

    2006-01-01

    The startup and steady uniaxial elongational viscosity have been measured for three bidisperse polystyrene (PS) melts, consisting of blends of monodisperse PS with molecular weights of 52 kg/mole or 103 kg/mole and 390 kg/mole. The bidisperse melts have a maximum in the steady elongational...... viscosity, of up to a factor of 7 times the Trouton limit of 3 times the zero-shear viscosity....

  8. Electron treatment of wood pulp for the viscose process

    Science.gov (United States)

    Stepanik, T. M.; Ewing, D. E.; Whitehouse, R.

    2000-03-01

    Electron processing is currently being evaluated by several viscose producers for integration into their process. The viscose industry converts dissolving wood pulp into products such as staple fibre, filament, cord, film, packaging, and non-edible sausage casings. These materials are used in the clothing, drapery, hygiene, automobile, food, and packaging industries. Viscose producers are facing increasingly high production costs and stringent environmental regulations that have forced some plants to close. Electron treatment of wood pulp can significantly reduce the amounts of chemicals used for producing viscose and the production of hazardous pollutants. Acsion Industries has worked with companies worldwide to demonstrate the benefits of using electron treated pulp for producing viscose (rayon). This paper describes the viscose process, the benefits of using electron treatment in the viscose process, and Acsion's efforts in developing this technology.

  9. A MEMS Resonant Sensor to Measure Fluid Density and Viscosity under Flexural and Torsional Vibrating Modes

    Directory of Open Access Journals (Sweden)

    Libo Zhao

    2016-06-01

    Full Text Available Methods to calculate fluid density and viscosity using a micro-cantilever and based on the resonance principle were put forward. Their measuring mechanisms were analyzed and the theoretical equations to calculate the density and viscosity were deduced. The fluid-solid coupling simulations were completed for the micro-cantilevers with different shapes. The sensing chips with micro-cantilevers were designed based on the simulation results and fabricated using the micro electromechanical systems (MEMS technology. Finally, the MEMS resonant sensor was packaged with the sensing chip to measure the densities and viscosities of eight different fluids under the flexural and torsional vibrating modes separately. The relative errors of the measured densities from 600 kg/m3 to 900 kg/m3 and viscosities from 200 μPa·s to 1000 μPa·s were calculated and analyzed with different microcantilevers under various vibrating modes. The experimental results showed that the effects of the shape and vibrating mode of micro-cantilever on the measurement accuracies of fluid density and viscosity were analyzed in detail.

  10. Acoustic characteristics of bubble bursting at the surface of a high-viscosity liquid

    International Nuclear Information System (INIS)

    Liu Xiao-Bo; Zhang Jian-Run; Li Pu

    2012-01-01

    An acoustic pressure model of bubble bursting is proposed. An experiment studying the acoustic characteristics of the bursting bubble at the surface of a high-viscosity liquid is reported. It is found that the sudden bursting of a bubble at the high-viscosity liquid surface generates N-shape wave at first, then it transforms into a jet wave. The fundamental frequency of the acoustic signal caused by the bursting bubble decreases linearly as the bubble size increases. The results of the investigation can be used to understand the acoustic characteristics of bubble bursting. (electromagnetism, optics, acoustics, heat transfer, classical mechanics, and fluid dynamics)

  11. Elongational viscosity of narrow molar mass distribution polystyrene

    DEFF Research Database (Denmark)

    Bach, Anders; Almdal, Kristoffer; Rasmussen, Henrik Koblitz

    2003-01-01

    Transient and steady elongational viscosity has been measured for two narrow molar mass distribution polystyrene melts of molar masses 200 000 and 390 000 by means of a filament stretching rheometer. Total Hencky strains of about five have been obtained. The transient elongational viscosity rises...... above the linear viscoelastic prediction at intermediate strains, indicating strain hardening. The steady elongational viscosities are monotone decreasing functions of elongation rate. At elongation rates larger than the inverse reptation time, the steady elongational viscosity scales linearly...

  12. Improved High Resolution Models of Subduction Dynamics: Use of transversely isotropic viscosity with a free-surface

    Science.gov (United States)

    Liu, X.; Gurnis, M.; Stadler, G.; Rudi, J.; Ratnaswamy, V.; Ghattas, O.

    2017-12-01

    Dynamic topography, or uncompensated topography, is controlled by internal dynamics, and provide constraints on the buoyancy structure and rheological parameters in the mantle. Compared with other surface manifestations such as the geoid, dynamic topography is very sensitive to shallower and more regional mantle structure. For example, the significant dynamic topography above the subduction zone potentially provides a rich mine for inferring the rheological and mechanical properties such as plate coupling, flow, and lateral viscosity variations, all critical in plate tectonics. However, employing subduction zone topography in the inversion study requires that we have a better understanding of the topography from forward models, especially the influence of the viscosity formulation, numerical resolution, and other factors. One common approach to formulating a fault between the subducted slab and the overriding plates in viscous flow models assumes a thin weak zone. However, due to the large lateral variation in viscosity, topography from free-slip numerical models typically has artificially large magnitude as well as high-frequency undulations over subduction zone, which adds to the difficulty in making comparisons between model results and observations. In this study, we formulate a weak zone with the transversely isotropic viscosity (TI) where the tangential viscosity is much smaller than the viscosity in the normal direction. Similar with isotropic weak zone models, TI models effectively decouple subducted slabs from the overriding plates. However, we find that the topography in TI models is largely reduced compared with that in weak zone models assuming an isotropic viscosity. Moreover, the artificial `tooth paste' squeezing effect observed in isotropic weak zone models vanishes in TI models, although the difference becomes less significant when the dip angle is small. We also implement a free-surface condition in our numerical models, which has a smoothing

  13. Kinetics and mechanisms of metal retention/release in geochemical processes in soil. 1997 annual progress report

    International Nuclear Information System (INIS)

    Taylor, R.W.

    1997-01-01

    'Remediation of soils polluted with heavy metals is a major challenge facing the nation. This is especially so at many DOE facilities and other superfund sites. In many cases, speciation of the metals is inaccurate and difficult and the mechanisms by which the metals are retained/released in soils over long times are poorly understood. Consequently, the long-term fate of metals in soils cannot be precisely predicted and often, the remediation recommendations and techniques that are employed to clean up soils may be ineffective or unnecessary. Accordingly, the authors are proposing work to generate basic knowledge on the kinetics and mechanism(s) of heavy metal retention/release by soil mineral colloids as affected by inorganic anion. The nature of the interaction of Cd(II), Co(II), Cr(VI), Cu(II), Ni(II) and Pb(II) with pure soil minerals and extracted soil clays will be investigated. The colloids will be characterized in terms of surface area, surface charge and surface site density. They will be used to study the effect(s) of pH, phosphate rate, and temperature on metals retention/release. The experiments will involve using various kinetic and isothermic sorption equations as models to describe the data thus acquired. The spectroscopic methods will involve using extended x-ray absorption fine structure spectroscopy (EXAFS) and Fourier Transform Infrared Spectroscopy (FTIR). The data generated from the proposed study will assist in designing better remediation strategies to effectively clean up toxic heavy metal contaminated soils at DOE facilities and other superfund sites.'

  14. Viscosity calculations of simulated ion-exchange resin waste glasses

    International Nuclear Information System (INIS)

    Kim, Cheon Woo; Park, Jong Kil; Lee, Kyung Ho; Lee, Myung Chan; Song, Myung Jae; BRUNELOT, Pierre

    2000-01-01

    An induction cold crucible melter (CCM) located in the NETEC-KEPCO has been used to vitrify simulated ion-exchange resin. During vitrification, the CCM operations were tightly constrained by glass viscosity as an important process parameter. Understanding the role of viscosity and quantifying viscosity is highly required in the determination of optimized feed formulations and in the selection of the processing temperature. Therefore, existing process models of glass viscosity based on a relationship between the glass composition, its structure polymerization, and the temperature were searched and adapted to our borosilicate glass systems. Calculated data using a viscosity model based on calculation of non-bridging oxygen (NBO) were in good agreement with the measured viscosity data of benchmark glasses

  15. Mechanisms of gas retention and release: Experimental results for Hanford single-shell waste tanks 241-A-101, 241-S-106, and 241-U-103

    International Nuclear Information System (INIS)

    Rassat, S.D.; Caley, S.M.; Bredt, P.R.; Gauglitz, P.A.; Rinehart, D.E.; Forbes, S.V.

    1998-09-01

    The 177 underground waste storage tanks at the Hanford Site contain millions of gallons of radioactive waste resulting from the purification of nuclear materials and related processes. Through various mechanisms, flammable gas mixtures of hydrogen, ammonia, methane, and nitrous oxide are generated and retained in significant quantities within the waste in many (∼25) of these tanks. The potential for large releases of retained gas from these wastes creates a flammability hazard. It is a critical component of the effort to understand the flammability hazard and a primary goal of this laboratory investigation to establish an understanding of the mechanisms of gas retention and release in these wastes. The results of bubble retention experimental studies using waste samples from several waste tanks and a variety of waste types support resolution of the Flammable Gas Safety Issue. Gas bubble retention information gained in the pursuit of safe storage will, in turn, benefit future waste operations including salt-well pumping, waste transfers, and sluicing/retrieval

  16. Surface chemistry of a viscose-based activated carbon cloth modified by treatment with ammonia and steam

    Energy Technology Data Exchange (ETDEWEB)

    Boudou, J.P. [University of Paris, Paris (France)

    2003-07-01

    The influence of ammonia treatment at 800{sup o}C on the catalytic activity of a viscose-based activated carbon cloth (ACC) was evaluated for the oxidative retention of H{sub 2}S or SO{sub 2} at room temperature. Change in the surface chemistry was observed by X-ray spectroscopy of nitrogen (N1s) and by temperature programmed desorption (TPD). Dynamic adsorption of H{sub 2}S or SO{sub 2} in moist air onto a packed bed of activated carbon cloth was monitored by measurement of the breakthrough curves at room temperature. ACC modified by ammonia showed noteworthy enhanced SO{sub 2} and H{sub 2}S loading relative to the untreated ACC. Improved SO{sub 2} retention rate could be replicated several times after regeneration by washing at room temperature, in contrast to the case with H{sub 2}S. The likely reasons for the behavior of H{sub 2}S and SO{sub 2} on the ammonia-treated ACC are discussed with reference to the recent literature.

  17. The micromechanics model analysis of the viscosity regulation of ultra-high strength concrete with low viscosity

    Science.gov (United States)

    Zhu, M.; Wang, F. G.; Wang, F. Z.; Liu, Y. P.

    2017-02-01

    The plastic viscosity of mortar and concrete with different binder content, sand ratio, water-binder ratio, microbead dosage and different class and dosage of fly ash were tested and calculated according tomicromechanics model proposed by A. Ghanbari and B.L. Karihaloo, The correlations between these parameters and fresh concrete workability were also investigated, which showed i. high consistence with the objective reality. When binder content, microbead dosage, fly ash dosage or the water-binder ratio was increased or sand ratio was reduced, the fresh concrete viscosity would decrease correspondingly. However their effects were not that same. The relationships between T50 a, V-funnel and inverted slump time with fresh concrete viscosity were established, respectively.

  18. Viscosity evolution of anaerobic granular sludge

    NARCIS (Netherlands)

    Pevere, A.; Guibaud, G.; Hullebusch, van E.D.; Lens, P.N.L.; Baudu, M.

    2006-01-01

    The evolution of the apparent viscosity at steady shear rate of sieved anaerobic granular sludge (20¿315 ¿m diameter) sampled from different full-scale anaerobic reactors was recorded using rotation tests. The ¿limit viscosity¿ of sieved anaerobic granular sludge was determined from the apparent

  19. Viscosity Meaurement Technique for Metal Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Ban, Heng [Utah State Univ., Logan, UT (United States). Mechanical and Aerospace Engineering; Kennedy, Rory [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-02-09

    Metallic fuels have exceptional transient behavior, excellent thermal conductivity, and a more straightforward reprocessing path, which does not separate out pure plutonium from the process stream. Fabrication of fuel containing minor actinides and rare earth (RE) elements for irradiation tests, for instance, U-20Pu-3Am-2Np-1.0RE-15Zr samples at the Idaho National Laboratory, is generally done by melt casting in an inert atmosphere. For the design of a casting system and further scale up development, computational modeling of the casting process is needed to provide information on melt flow and solidification for process optimization. Therefore, there is a need for melt viscosity data, the most important melt property that controls the melt flow. The goal of the project was to develop a measurement technique that uses fully sealed melt sample with no Americium vapor loss to determine the viscosity of metallic melts and at temperatures relevant to the casting process. The specific objectives of the project were to: develop mathematical models to establish the principle of the measurement method, design and build a viscosity measurement prototype system based on the established principle, and calibrate the system and quantify the uncertainty range. The result of the project indicates that the oscillation cup technique is applicable for melt viscosity measurement. Detailed mathematical models of innovative sample ampoule designs were developed to not only determine melt viscosity, but also melt density under certain designs. Measurement uncertainties were analyzed and quantified. The result of this project can be used as the initial step toward the eventual goal of establishing a viscosity measurement system for radioactive melts.

  20. Viscosity Meaurement Technique for Metal Fuels

    International Nuclear Information System (INIS)

    Ban, Heng

    2015-01-01

    Metallic fuels have exceptional transient behavior, excellent thermal conductivity, and a more straightforward reprocessing path, which does not separate out pure plutonium from the process stream. Fabrication of fuel containing minor actinides and rare earth (RE) elements for irradiation tests, for instance, U-20Pu-3Am-2Np-1.0RE-15Zr samples at the Idaho National Laboratory, is generally done by melt casting in an inert atmosphere. For the design of a casting system and further scale up development, computational modeling of the casting process is needed to provide information on melt flow and solidification for process optimization. Therefore, there is a need for melt viscosity data, the most important melt property that controls the melt flow. The goal of the project was to develop a measurement technique that uses fully sealed melt sample with no Americium vapor loss to determine the viscosity of metallic melts and at temperatures relevant to the casting process. The specific objectives of the project were to: develop mathematical models to establish the principle of the measurement method, design and build a viscosity measurement prototype system based on the established principle, and calibrate the system and quantify the uncertainty range. The result of the project indicates that the oscillation cup technique is applicable for melt viscosity measurement. Detailed mathematical models of innovative sample ampoule designs were developed to not only determine melt viscosity, but also melt density under certain designs. Measurement uncertainties were analyzed and quantified. The result of this project can be used as the initial step toward the eventual goal of establishing a viscosity measurement system for radioactive melts.

  1. Bulk viscosity of molecular fluids

    Science.gov (United States)

    Jaeger, Frederike; Matar, Omar K.; Müller, Erich A.

    2018-05-01

    The bulk viscosity of molecular models of gases and liquids is determined by molecular simulations as a combination of a dilute gas contribution, arising due to the relaxation of internal degrees of freedom, and a configurational contribution, due to the presence of intermolecular interactions. The dilute gas contribution is evaluated using experimental data for the relaxation times of vibrational and rotational degrees of freedom. The configurational part is calculated using Green-Kubo relations for the fluctuations of the pressure tensor obtained from equilibrium microcanonical molecular dynamics simulations. As a benchmark, the Lennard-Jones fluid is studied. Both atomistic and coarse-grained force fields for water, CO2, and n-decane are considered and tested for their accuracy, and where possible, compared to experimental data. The dilute gas contribution to the bulk viscosity is seen to be significant only in the cases when intramolecular relaxation times are in the μs range, and for low vibrational wave numbers (<1000 cm-1); This explains the abnormally high values of bulk viscosity reported for CO2. In all other cases studied, the dilute gas contribution is negligible and the configurational contribution dominates the overall behavior. In particular, the configurational term is responsible for the enhancement of the bulk viscosity near the critical point.

  2. Entropy viscosity method applied to Euler equations

    International Nuclear Information System (INIS)

    Delchini, M. O.; Ragusa, J. C.; Berry, R. A.

    2013-01-01

    The entropy viscosity method [4] has been successfully applied to hyperbolic systems of equations such as Burgers equation and Euler equations. The method consists in adding dissipative terms to the governing equations, where a viscosity coefficient modulates the amount of dissipation. The entropy viscosity method has been applied to the 1-D Euler equations with variable area using a continuous finite element discretization in the MOOSE framework and our results show that it has the ability to efficiently smooth out oscillations and accurately resolve shocks. Two equations of state are considered: Ideal Gas and Stiffened Gas Equations Of State. Results are provided for a second-order time implicit schemes (BDF2). Some typical Riemann problems are run with the entropy viscosity method to demonstrate some of its features. Then, a 1-D convergent-divergent nozzle is considered with open boundary conditions. The correct steady-state is reached for the liquid and gas phases with a time implicit scheme. The entropy viscosity method correctly behaves in every problem run. For each test problem, results are shown for both equations of state considered here. (authors)

  3. Universality of the high-temperature viscosity limit of silicate liquids

    DEFF Research Database (Denmark)

    Zheng, Qiuju; Mauro, John C.; Ellison, Adam J.

    2011-01-01

    We investigate the high-temperature limit of liquid viscosity by analyzing measured viscosity curves for 946 silicate liquids and 31 other liquids including metallic, molecular, and ionic systems. Our results show no systematic dependence of the high-temperature viscosity limit on chemical...... composition for the studied liquids. Based on theMauro-Yue-Ellison-Gupta-Allan (MYEGA) model of liquid viscosity, the high-temperature viscosity limit of silicate liquids is 10−2.93 Pa·s. Having established this value, there are only two independent parameters governing the viscosity-temperature relation...

  4. Learning and retention of quantum concepts with different teaching methods

    Science.gov (United States)

    Deslauriers, Louis; Wieman, Carl

    2011-06-01

    We measured mastery and retention of conceptual understanding of quantum mechanics in a modern physics course. This was studied for two equivalent cohorts of students taught with different pedagogical approaches using the Quantum Mechanics Conceptual Survey. We measured the impact of pedagogical approach both on the original conceptual learning and on long-term retention. The cohort of students who had a very highly rated traditional lecturer scored 19% lower than the equivalent cohort that was taught using interactive engagement methods. However, the amount of retention was very high for both cohorts, showing only a few percent decrease in scores when retested 6 and 18 months after completion of the course and with no exposure to the material in the interim period. This high level of retention is in striking contrast to the retention measured for more factual learning from university courses and argues for the value of emphasizing conceptual learning.

  5. Effects of xylanase and citric acid on the performance, nutrient retention, and characteristics of gastrointestinal tract of broilers fed low-phosphorus wheat-based diets

    NARCIS (Netherlands)

    Esmaeilipour, O.; Shivazad, M.; Moravej, H.; Aminzadeh, S.; Rezaian, M.; Krimpen, van M.M.

    2011-01-01

    An experiment was conducted to study the effects of xylanase and citric acid on the performance, nutrient retention, jejunal viscosity, and size and pH of the gastrointestinal tract of broilers fed a low-P wheat-based diet. The experiment was conducted as a 2 × 3 factorial arrangement with 2 levels

  6. Should you trust your heavy oil viscosity measurement?

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, L.; Miller, K.; Almond, R. [Petrovera Resources Ltd., Edmonton, AB (Canada)

    2003-07-01

    For the last 60 years, the heavy oil and bitumen reservoirs from western Canada have been exploited with varying degrees of success. There are many factors that may effect heavy oil and bitumen production rates. Primary production rates, which vary greatly from field to field, were found to improve with the addition of steam. Viscosity is the single most valued criteria in predicting cold production response from a new field. It is also the criteria used to determine whether thermal process are needed to reduce oil viscosity, or whether horizontal or vertical wells should be used. This study examined why production forecasts based on oil viscosity alone have been poor. It is based on an extensive data collection project in the Elk Point area reservoir which has lower than expected and erratic cold production rates. Viscosity values from the same wells were found to vary by a factor of four or more. One of the objectives of this study was to encourage commercial labs to develop an industry-wide standard method of heavy oil sample cleaning and viscosity measurement. It is generally understood that viscosity increases with an increase in the concentration of asphaltenes, but there is little information to quantify the relationship. Some studies suggest that viscosity increases logarithmically with increasing asphaltenes. It was concluded that the prediction of the viscosity of heavy oils and bitumens is very empirical, but there are ways to improve data comparisons and evaluation by applying available information from other scientific fields. 23 refs., 5 tabs., 6 figs.

  7. Shear viscosity enhancement in water–nanoparticle suspensions

    International Nuclear Information System (INIS)

    Balasubramanian, Ganesh; Sen, Swarnendu; Puri, Ishwar K.

    2012-01-01

    Equilibrium molecular dynamics simulations characterize the increase in the shear viscosity of water around a suspended silicon dioxide nanoparticle. Water layering on the solid surface decreases the fraction of adjacent fluid molecules that are more mobile and hence less viscous, thereby increasing the shear viscosity. The contribution of the nanoparticle surface area to this rheological behavior is identified and an empirical model that accounts for it is provided. The model successfully reproduces the shear viscosity predictions from previous experimental measurements as well as our simulations. -- Highlights: ► Layering of water on the solid surfaces increases the fraction of less mobile molecules adjacent to them. ► A nondimensional parameter predicts of viscosity enhancement due to particle shape, volume fraction. ► Model predictions agree with the results of atomistic simulations and experimental measurements.

  8. Viscosity of melts in the sodium borosilicate system

    International Nuclear Information System (INIS)

    Tait, J.C.; Mandolesi, D.L.; Rummens, H.E.C.

    1984-01-01

    The viscosities of a series of glasses in the sodium borosilicate system (5-35Na 2 O, 5-35B 2 O 3 , 45-80SiO 2 mol%) have been determined between 950 and 1500 deg C, using a rotating bob viscometer. A simplex lattice experimental design was used to define a series of compositions suitable for numerical analysis of the data. The viscosity data were fitted using the Fulcher equation for each composition. Nonlinear regression analysis of the viscosities at constant temperatures gave expressions for the variation in viscosity as a function of composition. The results are displayed as isoviscosity contours on the Na 2 O-B 2 O 3 -SiO 2 composition diagram. The viscosity behaviour as a function of composition is discussed in terms of structural bonding in the melt. (author)

  9. Jet collimation by turbulent viscosity. I

    International Nuclear Information System (INIS)

    Henriksen, R.N.

    1987-01-01

    In this paper it is assumed that the subscale turbulent eddies induced in an ambient medium by the emergence of a (already collimated) jet from a galactic nucleus (VLBI jet) are the source of the viscosity which causes material to be entrained into the large-scale (VLA) jet. New analytic solutions are derived by a generalization of the self-similar Ansatz used in the Landau-Squires solution to include variable density and viscosity. It is shown that such a process of viscous collimation of the VLA jets can account for the observed collimation-luminosity correlation, the magnetic flux, and the inferred mass flux of these jets. Order of magnitude comparisons of velocity and density fields with recently observed emission-line flow regions near radio jets are made. All of the viscosity-dependent observational checks imply roughly the same plausible value for the eddy viscosity. It is emphasized that storing the initial VLBI jet energy in the intermediate scales occupied by the turbulent eddies allows this energy to be largely undetected. 35 references

  10. Crustal Viscosity Structure Estimated from Multi-Phase Mixing Theory

    Science.gov (United States)

    Shinevar, W. J.; Behn, M. D.; Hirth, G.

    2014-12-01

    Estimates of lower crustal viscosity are typically constrained by analyses of isostatic rebound, post seismic creep, and laboratory-derived flow laws for crustal rocks and minerals. Here we follow a new approach for calculating the viscosity structure of the lower continental crust. We use Perple_X to calculate mineral assemblages for different crustal compositions. Effective viscosity is then calculated using the rheologic mixing model of Huet et al. (2014) incorporating flow laws for each mineral phase. Calculations are performed along geotherms appropriate for the Basin and Range, Tibetan Plateau, Colorado Plateau, and the San Andreas Fault. To assess the role of crustal composition on viscosity, we examined two compositional gradients extending from an upper crust with ~67 wt% SiO2 to a lower crust that is either: (i) basaltic with ~53 wt% SiO2 (Rudnick and Gao, 2003), or (ii) andesitic with ~64% SiO2 (Hacker et al., 2011). In all cases, the middle continental crust has a viscosity that is 2-3 orders of magnitude greater than that inferred for wet quartz, a common proxy for mid-crustal viscosities. An andesitic lower crust results in viscosities of 1020-1021 Pa-s and 1021-1022 Pa-s for hotter and colder crustal geotherms, respectively. A mafic lower crust predicts viscosities that are an order of magnitude higher for the same geotherm. In all cases, the viscosity calculated from the mixing model decreases less with depth compared to single-phase estimates. Lastly, for anhydrous conditions in which alpha quartz is stable, we find that there is a strong correlation between Vp/Vs and bulk viscosity; in contrast, little to no correlation exists for hydrous conditions.

  11. Viscosity of Ga-Li liquid alloys

    Science.gov (United States)

    Vidyaev, Dmitriy; Boretsky, Evgeny; Verkhorubov, Dmitriy

    2018-03-01

    The measurement of dynamic viscosity of Ga-Li liquid alloys has been performed using low-frequency vibrational viscometer at five temperatures in the range 313-353 K and four gallium-based dilute alloy compositions containing 0-1.15 at.% Li. It was found that the viscosity of the considered alloys increases with decreasing temperature and increasing lithium concentration in the above ranges. It was shown that dependence of the viscosity of Ga-Li alloys in the investigated temperature range has been described by Arrhenius equation. For this equation the activation energy of viscous flow and pre-exponential factor were calculated. This study helped to determine the conditions of the alkali metals separating process in gallam-exchange systems.

  12. Viscosity of glasses containing simulated Savannah River Plant waste

    International Nuclear Information System (INIS)

    Plodinec, M.J.

    1978-08-01

    The viscosity of glass melts containing four simulated sludge types and two frit candidates (Frits 18 and 21) was measured over the temperature range 750 to 1200 0 C. The viscosity of melts made with either frit was reduced by the addition of high iron sludge, unchanged by average sludge, and increased by composite and high aluminum sludge. High aluminium sludge greatly increased the viscosity. Frit 21 (containing 4 wt % Li 2 O substituted for 4 wt % Na 2 O in Frit 18) was clearly better than Frit 18 in terms of its low viscosity. However, further reductions in viscosity are desirable, especially for glasses containing high aluminum sludge. Changing any frit component by 1 wt % did not significantly affect the viscosity of the glasses. Therefore, variability of 1 wt % in any frit component can be tolerated

  13. On the optimal design of risk retention in securitisation

    Directory of Open Access Journals (Sweden)

    Metin Kaptan

    2011-09-01

    Full Text Available This paper examines the optimal design of retention in securitisation, in order to maximize welfare of screening per unit of retention, assuming that screening is costly and that the bank intends to securitise its loans. In contrast to the focus of previous literature on tranche retention, we deviate from the constitutional mechanisms of tranche retention to present a pareto-optimal method of tranche retention. Unlike the current ad-hoc-regulations, we derive the optimal design of retention from a utility maximization problem. We show that the level of retention per tranche should be dependent on the rate of credit default, i.e. the higher the rate of default, the higher the optimal rate of retention required to provide an incentive to screen carefully. From this approach, it follows that the rate of retention per tranche should be higher, the higher the position within the ranking order of subordination. Accordingly, the efficiency of tranche retention can be enhanced, reducing the level of retention required to maintain a given level of screening-effort. This retention design entails a recovery of the bank’s equity capital, thereby increasing liquidity and lending capacities.

  14. Peristaltic transport of a fractional Burgers' fluid with variable viscosity through an inclined tube

    Science.gov (United States)

    Rachid, Hassan

    2015-12-01

    In the present study,we investigate the unsteady peristaltic transport of a viscoelastic fluid with fractional Burgers' model in an inclined tube. We suppose that the viscosity is variable in the radial direction. This analysis has been carried out under low Reynolds number and long-wavelength approximations. An analytical solution to the problem is obtained using a fractional calculus approach. Figures are plotted to show the effects of angle of inclination, Reynolds number, Froude number, material constants, fractional parameters, parameter of viscosity and amplitude ratio on the pressure gradient, pressure rise, friction force, axial velocity and on the mechanical efficiency.

  15. The role of viscosity in TATB hot spot ignition

    Science.gov (United States)

    Fried, Laurence E.; Zepeda-Ruis, Luis; Howard, W. Michael; Najjar, Fady; Reaugh, John E.

    2012-03-01

    The role of dissipative effects, such as viscosity, in the ignition of high explosive pores is investigated using a coupled chemical, thermal, and hydrodynamic model. Chemical reactions are tracked with the Cheetah thermochemical code coupled to the ALE3D hydrodynamic code. We perform molecular dynamics simulations to determine the viscosity of liquid TATB. We also analyze shock wave experiments to obtain an estimate for the shock viscosity of TATB. Using the lower bound liquid-like viscosities, we find that the pore collapse is hydrodynamic in nature. Using the upper bound viscosity from shock wave experiments, we find that the pore collapse is closest to the viscous limit.

  16. Bulk-viscosity-driven asymmetric inflationary universe

    International Nuclear Information System (INIS)

    Waga, I.; Lima, J.A.S.; Portugal, R.

    1987-01-01

    A primordial net bosinic charge is introduced in the context of the bulk-viscosity-driven inflationary models. The analysis is carried through a macroscopic point of view in the framework of the causal thermodynamic theory. The conditions for having exponetial and generalized inflation are obtained. A phenomenological expression for the bulk viscosity coefficient is also derived. (author) [pt

  17. Hydro-mechanical paths within unsaturated compacted soil framed through water retention surfaces

    Directory of Open Access Journals (Sweden)

    Pelizzari Benjamin

    2016-01-01

    Full Text Available Compaction is a key issue of modern earthworks... From sustainable development, a need arise of using materials for compaction under given conditions that would normally be avoid due to unpredictable pathologies. The application of compaction on fine grained soils, without a change of gravimetric water content, lead to very important modifications of the void ratio and hence suction. Therefore the hydro-mechanical behaviour of fine grained soil need to be rendered around three variables: suction, void ratio, saturation degree or water content. The barring capacity of the soil is assessed through Penetrometers (In-situ manual penetrometer, CBR in order to assess gains through compaction. The three states variables are then assessed for in situ and frame through water retention surfaces, realized from Proctor tests, in which compaction effect and path could be described.

  18. Relaxation-based viscosity mapping for magnetic particle imaging

    Science.gov (United States)

    Utkur, M.; Muslu, Y.; Saritas, E. U.

    2017-05-01

    Magnetic particle imaging (MPI) has been shown to provide remarkable contrast for imaging applications such as angiography, stem cell tracking, and cancer imaging. Recently, there is growing interest in the functional imaging capabilities of MPI, where ‘color MPI’ techniques have explored separating different nanoparticles, which could potentially be used to distinguish nanoparticles in different states or environments. Viscosity mapping is a promising functional imaging application for MPI, as increased viscosity levels in vivo have been associated with numerous diseases such as hypertension, atherosclerosis, and cancer. In this work, we propose a viscosity mapping technique for MPI through the estimation of the relaxation time constant of the nanoparticles. Importantly, the proposed time constant estimation scheme does not require any prior information regarding the nanoparticles. We validate this method with extensive experiments in an in-house magnetic particle spectroscopy (MPS) setup at four different frequencies (between 250 Hz and 10.8 kHz) and at three different field strengths (between 5 mT and 15 mT) for viscosities ranging between 0.89 mPa · s-15.33 mPa · s. Our results demonstrate the viscosity mapping ability of MPI in the biologically relevant viscosity range.

  19. Intrinsic viscosity of a suspension of cubes

    KAUST Repository

    Mallavajula, Rajesh K.

    2013-11-06

    We report on the viscosity of a dilute suspension of cube-shaped particles. Irrespective of the particle size, size distribution, and surface chemistry, we find empirically that cubes manifest an intrinsic viscosity [η]=3.1±0.2, which is substantially higher than the well-known value for spheres, [η]=2.5. The orientation-dependent intrinsic viscosity of cubic particles is determined theoretically using a finite-element solution of the Stokes equations. For isotropically oriented cubes, these calculations show [η]=3.1, in excellent agreement with our experimental observations. © 2013 American Physical Society.

  20. Measurement of viscosity of slush at high shear rates

    OpenAIRE

    小林, 俊一; 川村, 公之; 津川, 圭一; 和泉, 薫; Kobayashi, Shun'ichi; Kawamura, Kimiyuki; Tugawa, Keiichi; Izumi, Kaoru

    1988-01-01

    Measurements of viscosity of slush were carried out using a method of flow along an inclined smooth surface in a 0℃cold room. The method was used to get the values of viscosity under high shear rates (25 and 75s^). From our experiments two important results were obtained: 1) the viscosity of slush decreases with increasing shear rates; 2) The fluid behavior is pseudoplastic that the values of non-Newtonian index of viscosity were less than unity.

  1. Rolling-Tooth Core Breakoff and Retention Mechanism

    Science.gov (United States)

    Badescu, Mircea; Bickler, Donald B.; Sherrit, Stewart; Bar-Cohen, Yoseph; Bao, Xiaoqi; Hudson, Nicolas H.

    2011-01-01

    Sampling cores requires the controlled breakoff of the core at a known location with respect to the drill end. An additional problem is designing a mechanism that can be implemented at a small scale that is robust and versatile enough to be used for a variety of core samples. This design consists of a set of tubes (a drill tube and an inner tube) and a rolling element (rolling tooth). An additional tube can be used as a sample tube. The drill tube and the inner tube have longitudinal holes with the axes offset from the axis of each tube. The two eccentricities are equal. The inner tube fits inside the drill tube, and the sample tube fits inside the inner tube. While drilling, the two tubes are positioned relative to each other such that the sample tube is aligned with the drill tube axis and core. The drill tube includes teeth and flutes for cuttings removal. The inner tube includes, at the base, the rolling element implemented as a wheel on a shaft in an eccentric slot. An additional slot in the inner tube and a pin in the drill tube limit the relative motion of the two tubes. While drilling, the drill assembly rotates relative to the core and forces the rolling tooth to stay hidden in the slot along the inner tube wall. When the drilling depth has been reached, the drill bit assembly is rotated in the opposite direction, and the rolling tooth is engaged and penetrates into the core. Depending on the strength of the created core, the rolling tooth can score, lock the inner tube relative to the core, start the eccentric motion of the inner tube, and break the core. The tooth and the relative position of the two tubes can act as a core catcher or core-retention mechanism as well. The design was made to fit the core and hole parameters produced by an existing bit; the parts were fabricated and a series of demonstration tests were performed. This invention is potentially applicable to sample return and in situ missions to planets such as Mars and Venus, to moons such

  2. Retention time variability as a mechanism for animal mediated long-distance dispersal.

    Directory of Open Access Journals (Sweden)

    Vishwesha Guttal

    Full Text Available Long-distance dispersal (LDD events, although rare for most plant species, can strongly influence population and community dynamics. Animals function as a key biotic vector of seeds and thus, a mechanistic and quantitative understanding of how individual animal behaviors scale to dispersal patterns at different spatial scales is a question of critical importance from both basic and applied perspectives. Using a diffusion-theory based analytical approach for a wide range of animal movement and seed transportation patterns, we show that the scale (a measure of local dispersal of the seed dispersal kernel increases with the organisms' rate of movement and mean seed retention time. We reveal that variations in seed retention time is a key determinant of various measures of LDD such as kurtosis (or shape of the kernel, thinkness of tails and the absolute number of seeds falling beyond a threshold distance. Using empirical data sets of frugivores, we illustrate the importance of variability in retention times for predicting the key disperser species that influence LDD. Our study makes testable predictions linking animal movement behaviors and gut retention times to dispersal patterns and, more generally, highlights the potential importance of animal behavioral variability for the LDD of seeds.

  3. The Viscosity of Organic Liquid Mixtures

    Science.gov (United States)

    Len, C. W.; Trusler, J. P. M.; Vesovic, V.; Wakeham, W. A.

    2006-01-01

    The paper reports measurements of the viscosity and density of two heavy hydrocarbon mixtures, Dutrex and Arab Light Flashed Distillate (ALFD), and of their mixtures with hydrogen. The measurements have been carried out with a vibrating-wire device over a range of temperatures from 399 to 547 K and at pressures up to 20 MPa. Measurements have also been carried out on systems in which hydrogen at different concentrations has been dissolved in the liquids. The measurements have an estimated uncertainty of ±5% for viscosity and ±2% for density and represent the first results on these prototypical heavy hydrocarbons. The results reveal that the addition of hydrogen reduces both the density and viscosity of the original hydrocarbon mixture at a particular temperature and pressure.

  4. Bulk viscosity and cosmological evolution

    International Nuclear Information System (INIS)

    Beesham, A.

    1996-01-01

    In a recent interesting paper, Pimentel and Diaz-Rivera (Nuovo Cimento B, 109(1994) 1317) have derived several solutions with bulk viscosity in homogeneous and isotropic cosmological models. They also discussed the properties of these solutions. In this paper the authors relate the solutions of Pimentel and Diaz-Rivera by simple transformations to previous solutions published in the literature, showing that all the solutions can be derived from the known existing ones. Drawbacks to these approaches of studying bulk viscosity are pointed out, and better approaches indicated

  5. In situ viscosity of oil sands using low field NMR

    International Nuclear Information System (INIS)

    Bryan, J.; Moon, D.; Kantzas, A.

    2005-01-01

    In heavy oil and bitumen reservoirs, oil viscosity is a vital piece of information that will have great bearing on the chosen EOR scheme and the recovery expected. Prediction of in situ viscosity with a logging tool would he very beneficial in reservoir characterization and exploitation design. Low field NMR is a technology that has shown great potential as a tool for characterizing hydrocarbon properties in heavy oil and bitumen reservoirs. An oil viscosity correlation has previously been developed that is capable of providing order of magnitude viscosity estimates for a wide range of oils taken from various fields in Alberta. This paper presents tuning procedures to improve the NMR predictions for different viscosity ranges, and extends the NMR viscosity model to in situ heavy oil in unconsolidated sands. The results of this work show that the NMR oil peak can be de-convoluted from the in situ signals of the oil and water, and the bulk viscosity correlation that was developed for bulk oils can he applied to predict the in situ oil viscosity. These results can be translated to an NMR logging tool algorithm, allowing for in situ measurements of oil viscosity at the proper reservoir conditions. (author)

  6. On the measurement of magnetic viscosity

    Energy Technology Data Exchange (ETDEWEB)

    Serletis, C. [Department of Physics, Aristotle University, Thessaloniki 54124 (Greece); Efthimiadis, K.G., E-mail: kge@auth.gr [Department of Physics, Aristotle University, Thessaloniki 54124 (Greece)

    2012-08-15

    This work is an investigation of the experimental method used for measuring the magnetic viscosity in a hard ferromagnetic material, i.e. the recording of the magnetization under constant applied field and temperature, after the material has been magnetically saturated. It investigates how the experimental results are affected by the initial conditions of the method (saturation field, field change rate and field oscillation prior to its stabilization), and by minor variations of field and temperature during the recording. Based on the arising conclusions and the use of a more complex fitting function of measurements, the accuracy and repeatability of experimental results is improved. - Highlights: Black-Right-Pointing-Pointer Magnetic viscosity is affected by initial measurement conditions. Black-Right-Pointing-Pointer Minor field deviations prior to its stabilization cause large changes in viscosity. Black-Right-Pointing-Pointer Viscosity is strongly dependent on the field change rate from saturation to the measurement field. Black-Right-Pointing-Pointer Small changes in field and temperature during the experiment can lead to false measurements. Black-Right-Pointing-Pointer Errors in measurements can be eliminated through the use of a proper fitting function.

  7. Utilizing the non-bridge oxygen model to predict the glass viscosity

    International Nuclear Information System (INIS)

    Choi, Kwansik; Sheng, Jiawei; Maeng, Sung Jun; Song, Myung Jae

    1998-01-01

    Viscosity is the most important process property of waste glass. Viscosity measurement is difficult and costs much. Non-bridging Oxygen (NBO) model which relates glass composition to viscosity had been developed for high level waste at the Savannah River Site (SRS). This research utilized this NBO model to predict the viscosity of KEPRI's 55 glasses. It was found that there was a linear relationship between the measured viscosity and the predicted viscosity. The NBO model could be used to predict glass viscosity in glass formulation development. However the precision of predicted viscosity is out of satisfaction because the composition ranges are very different between the SRS and KEPRI glasses. The modification of NBO calculation, which included modification of alkaline earth elements and TiO 2 , could not strikingly improve the precision of predicted values

  8. Subducted slabs and lateral viscosity variations: effects on the long-wavelength geoid

    Science.gov (United States)

    Tosi, Nicola; Čadek, Ondřej; Martinec, Zdeněk

    2009-11-01

    The characteristic broad local maxima exhibited by the long-wavelength geoid over subduction zones are investigated with a numerical model of mantle flow. In a spherical axisymmetric geometry, a synthetic model of buoyancy driven subduction is used to test the effects on the geoid caused by the depth of penetration of the lithosphere into the mantle, by the viscosity stratification and by lateral viscosity variations (LVV) in the lithosphere, upper and lower mantle. The presence of anomalous slab density in the lower mantle guarantees geoid amplitudes comparable with the observations, favouring the picture of slabs that penetrate the transition zone and sink into the deep mantle. The viscosity of the lower mantle controls the long-wavelength geoid to the first order, ensuring a clear positive signal when it is at least 30-times greater than the upper-mantle viscosity. The presence of LVV in the lithosphere, in the form of weak plate margins, helps to increase the contribution of the surface topography, causing a pronounced reduction of the geoid. Localized LVV associated with the cold slab play a secondary role if they are in the upper mantle. On the other hand, highly viscous slabs in the lower mantle exert a large influence on the geoid. They cause its amplitude to increase dramatically, way beyond the values typically observed over subduction zones. Long-wavelength flow becomes less vigorous as the slab viscosity increases. Deformation in the upper mantle becomes more localized and power is transferred to short wavelengths, causing the long-wavelength surface topography to diminish and the total geoid to increase. Slabs may be then weakened in the lower mantle or retain their high viscosity while other mechanisms act to lower the geoid. It is shown that a phase change from perovskite to post-perovskite above the core-mantle boundary can cause the geoid to reduce significantly, thereby helping to reconcile models and observations.

  9. Acute urinary retention due to benign inflammatory nervous diseases.

    Science.gov (United States)

    Sakakibara, Ryuji; Yamanishi, Tomonori; Uchiyama, Tomoyuki; Hattori, Takamichi

    2006-08-01

    Both neurologists and urologists might encounter patients with acute urinary retention due to benign inflammatory nervous diseases. Based on the mechanism of urinary retention, these disorders can be divided into two subgroups: disorders of the peripheral nervous system (e.g., sacral herpes) or the central nervous system (e.g., meningitis-retention syndrome [MRS]). Laboratory abnormalities include increased herpes virus titers in sacral herpes, and increased myelin basic protein in the cerebrospinal fluid (CSF) in some cases with MRS. Urodynamic abnormality in both conditions is detrusor areflexia; the putative mechanism of it is direct involvement of the pelvic nerves in sacral herpes; and acute spinal shock in MRS. There are few cases with CSF abnormality alone. Although these cases have a benign course, management of the acute urinary retention is necessary to avoid bladder injury due to overdistension. Clinical features of sacral herpes or MRS differ markedly from those of the original "Elsberg syndrome" cases.

  10. Negative viscosity can enhance learning of inertial dynamics.

    Science.gov (United States)

    Huang, Felix C; Patton, James L; Mussa-Ivaldi, Ferdinando A

    2009-06-01

    We investigated how learning of inertial load manipulation is influenced by movement amplification with negative viscosity. Using a force-feedback device, subjects trained on anisotropic loads (5 orientations) with free movements in one of three conditions (inertia only, negative viscosity only, or combined), prior to common evaluation conditions (prescribed circular pattern with inertia only). Training with Combined-Load resulted in lower error (6.89±3.25%) compared to Inertia-Only (8.40±4.32%) and Viscosity-Only (8.17±4.13%) according to radial deviation analysis (% of trial mean radius). Combined-Load and Inertia-Only groups exhibited similar unexpected no-load trials (8.38±4.31% versus 8.91±4.70% of trial mean radius), which suggests comparable low-impedance strategies. These findings are remarkable since negative viscosity, only available during training, evidently enhanced learning when combined with inertia. Modeling analysis suggests that a feedforward after-effect of negative viscosity cannot predict such performance gains. Instead, results from Combined-Load training are consistent with greater feedforward inertia compensation along with a small increase in impedance control. The capability of the nervous system to generalize learning from negative viscosity suggests an intriguing new method for enhancing sensorimotor adaptation.

  11. Viscosity of liquid sulfur under high pressure

    International Nuclear Information System (INIS)

    Terasaki, Hidenori; Kato, T; Funakoshi, K; Suzuki, A; Urakawa, S

    2004-01-01

    The viscosity of liquid sulfur up to 9.7 GPa and 1067 K was measured using the in situ x-ray radiography falling sphere method. The viscosity coefficients were found to range from 0.11 to 0.69 Pa s, and decreased continuously with increasing pressure under approximately constant homologous temperature conditions. The observed viscosity variation suggests that a gradual structural change occurs in liquid sulfur with pressure up to 10 GPa. The L-L' transition in liquid sulfur proposed by Brazhkin et al (1991 Phys. Lett. A 154 413) from thermobaric measurements has not been confirmed by the present viscometry

  12. Laboratory Tests for Dispersive Soil Viscosity Determining

    Science.gov (United States)

    Ter-Martirosyan, Z. G.; Ter-Martirosyan, A. Z.; Sobolev, E. S.

    2017-11-01

    There are several widespread methods for soil viscosity determining now. The standard shear test device and torsion test apparatus are the most commonly used installations to do that. However, the application of them has a number of disadvantages. Therefore, the specialists of Moscow State University of Civil Engineering proposed a new device to determine the disperse soil viscosity on the basis of a stabilometer with the B-type camera (viscosimeter). The paper considers the construction of a viscosimeter and the technique for determining soil viscosity inside this tool as well as some experimental verification results of its work.

  13. Viscosity effect in Landau's hydrodynamical model

    International Nuclear Information System (INIS)

    Hoang, T.F.; Phua, K.K.; Nanyang Univ., Singapore

    1979-01-01

    The Bose-Einstein distribution is used to investigate Landau's hydrodynamical model with viscosity. In case the viscosity dependence on the temperature is T 3 , the correction to the multiplicity behaves like I/E and is found to be negligible for the pp data. A discussion is presented on a possibility of reconciling E 1 / 2 and logE dependence of the multiplicity law. (orig.)

  14. Rapid quantification of imidazolium-based ionic liquids by hydrophilic interaction liquid chromatography: Methodology and an investigation of the retention mechanisms.

    Science.gov (United States)

    Hawkins, Cory A; Rud, Anna; Guthrie, Margaret L; Dietz, Mark L

    2015-06-26

    The separation of nine N,N'-dialkylimidazolium-based ionic liquids (ILs) by an isocratic hydrophilic interaction high-performance liquid chromatographic method using an unmodified silica column was investigated. The chosen analytical conditions using a 90:10 acetonitrile-ammonium formate buffer mobile phase on a high-purity, unmodified silica column were found to be efficient, robust, and sensitive for the determination of ILs in a variety of solutions. The retention window (k' = 2-11) was narrower than that of previous methods, resulting in a 7-min runtime for the nine IL homologues. The lower limit of quantification of the method, 2-3 μmol L(-1), was significantly lower than those reported previously for HPLC-UV methods. The effects of systematically modifying the IL cation alkyl chain length, column temperature, and mobile-phase water and buffer content on solute retention were examined. Cation exchange was identified as the dominant retention mechanism for most of the solutes, with a distinct (single methylene group) transition to a dominant partitioning mode at the highest solute polarity. Copyright © 2015 Elsevier B.V. All rights reserved.

  15. Vegetable oil and fat viscosity forecast models based on iodine number and saponification number

    International Nuclear Information System (INIS)

    Toscano, G.; Riva, G.; Foppa Pedretti, E.; Duca, D.

    2012-01-01

    Vegetable oil and fats can be considered as an important renewable source for the energy production. There are many applications where these biofuels are used directly in engines. However, the use of pure vegetable oils causes some problems as consequence of its chemical and physical characteristic. Viscosity is one of the most important parameters affecting several physical and mechanical processes of the operation of the engine. The determination of this parameter at different tis important to determine the behavior of the vegetable oil and fats. In this work we investigated the effects of two analytical chemical parameters (iodine number and saponification number) and forecasting models have been proposed. -- Highlights: ► Vegetable oil and fat viscosity is predicted by mathematical model based on saponification number and iodine number. ► Unsaturated vegetable oils with small size molecules of fatty acids have a lower viscosity values. ► The models proposed show an average error lower than 12%

  16. Viscosity of aluminum under shock-loading conditions

    International Nuclear Information System (INIS)

    Ma Xiao-Juan; Liu Fu-Sheng; Zhang Ming-Jian; Sun Yan-Yun

    2011-01-01

    A reliable data treatment method is critical for viscosity measurements using the disturbance amplitude damping method of shock waves. In this paper the finite difference method is used to obtain the numerical solutions for the disturbance amplitude damping behaviour of the sinusoidal shock front in a flyer-impact experiment. The disturbance amplitude damping curves are used to depict the numerical solutions of viscous flow. By fitting the experimental data to the numerical solutions of different viscosities, we find that the effective shear viscosity coefficients of shocked aluminum at pressures of 42, 78 and 101 GPa are (1500±100) Pa·s, (2800±100) Pa·s and (3500±100) Pa·s respectively. It is clear that the shear viscosity of aluminum increases with an increase in shock pressure, so aluminum does not melt below a shock pressure of 101 GPa. This conclusion is consistent with the sound velocity measurement. (interdisciplinary physics and related areas of science and technology)

  17. The evaporation of viscose process liquors: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Thornton, R

    1984-01-01

    A program of work aimed at producing designs for an energy efficient process for the evaporation of water from viscose process liquors has been completed. The process uses mechanical vapor recompression in conjunction with a thin plastic heat transfer surface. A bench laboratory evaporation rig was built to prove the technical viability of the process. This was followed by the construction of a research plant at a viscose production site. The capacity of this plant was 100 to 150 kg/h of water evaporated. The construction and operation of a plastic heat exchanger with thin walled plastic tubes was achieved with considerable success. The lining of the concrete containment vessel proved more difficult, and the technique employed may not be the best for commercial units. Heat transfer coefficients of up to 550 Wm/sup -2/ K/sup -1/ were measured on the research plant. These agreed well with results obtained from a mathematical model developed for the process. An optimum design for a commercial unit has been costed and the financial parameters determined. Courtaulds considers that the construction of a demonstration plant is justified. 3 refs., 8 figs.

  18. Determination of Viscosity Versus Pressure by Means of a Clearance Seal

    DEFF Research Database (Denmark)

    Christiansen, Peter; Schmidt Hansen, Niels; Lund, Martin Thomas Overdahl

    2018-01-01

    This paper describes the construction and testing of a simple, experimental tool setup that enables determination of the pressure–viscosity relationship for high viscosity oils. Comparing the determined pressure–viscosity relationship with a reference rheometer measuring the viscosity at ambient ...

  19. New instrument for on-line viscosity measurement of fermentation media.

    Science.gov (United States)

    Picque, D; Corrieu, G

    1988-01-01

    In an attempt to resolve the difficult problem of on-line determination of the viscosity of non-Newtonian fermentation media, the authors have used a vibrating rod sensor mounted on a bioreactor. The sensor signal decreases nonlinearly with increased apparent viscosity. Electronic filtering of the signal damps the interfering effect of aeration and mechanical agitation. Sensor drift is very low (0.03% of measured value per hour). On the rheological level the sensor is primarily an empirical tool that must be specifically calibrated for each fermentation process. Once this is accomplished, it becomes possible to establish linear or second-degree correlations between the electrical signal from the sensor and the essential parameters of the fermentation process in question (pH of a fermented milk during acidification, concentration of extra cellular polysaccharide). In addition, by applying the power law to describe the rheological behavior of fermentation media, we observe a second-order polynomial correlation between the sensor signal and the behavior index (n).

  20. Singularities and Entropy in Bulk Viscosity Dark Energy Model

    International Nuclear Information System (INIS)

    Meng Xinhe; Dou Xu

    2011-01-01

    In this paper bulk viscosity is introduced to describe the effects of cosmic non-perfect fluid on the cosmos evolution and to build the unified dark energy (DE) with (dark) matter models. Also we derive a general relation between the bulk viscosity form and Hubble parameter that can provide a procedure for the viscosity DE model building. Especially, a redshift dependent viscosity parameter ζ ∝ λ 0 + λ 1 (1 + z) n proposed in the previous work [X.H. Meng and X. Dou, Commun. Theor. Phys. 52 (2009) 377] is investigated extensively in this present work. Further more we use the recently released supernova dataset (the Constitution dataset) to constrain the model parameters. In order to differentiate the proposed concrete dark energy models from the well known ΛCDM model, statefinder diagnostic method is applied to this bulk viscosity model, as a complementary to the Om parameter diagnostic and the deceleration parameter analysis performed by us before. The DE model evolution behavior and tendency are shown in the plane of the statefinder diagnostic parameter pair {r, s} as axes where the fixed point represents the ΛCDM model. The possible singularity property in this bulk viscosity cosmology is also discussed to which we can conclude that in the different parameter regions chosen properly, this concrete viscosity DE model can have various late evolution behaviors and the late time singularity could be avoided. We also calculate the cosmic entropy in the bulk viscosity dark energy frame, and find that the total entropy in the viscosity DE model increases monotonously with respect to the scale factor evolution, thus this monotonous increasing property can indicate an arrow of time in the universe evolution, though the quantum version of the arrow of time is still very puzzling. (geophysics, astronomy, and astrophysics)

  1. The effect of viscosity, friction, and sonication on the morphology and metabolite production from Aspergillus terreus ATCC 20542.

    Science.gov (United States)

    Rahim, Muhamad Hafiz Abd; Hasan, Hanan; Harith, Hanis H; Abbas, Ali

    2017-12-01

    This study investigates the effects of viscosity, friction, and sonication on the morphology and the production of lovastatin, (+)-geodin, and sulochrin by Aspergillus terreus ATCC 20542. Sodium alginate and gelatine were used to protect the fungal pellet from mechanical force by increasing the media viscosity. Sodium alginate stimulated the production of lovastatin by up to 329.0% and sulochrin by 128.7%, with inhibitory effect on (+)-geodin production at all concentrations used. However, the use of gelatine to increase viscosity significantly suppressed lovastatin, (+)-geodin, and sulochrin's production (maximum reduction at day 9 of 42.7, 60.8, and 68.3%, respectively), which indicated that the types of chemical play a major role in metabolite production. Higher viscosity increased both pellet biomass and size in all conditions. Friction significantly increased (+)-geodin's titre by 1527.5%, lovastatin by 511.1%, and sulochrin by 784.4% while reducing pellet biomass and size. Conversely, sonication produced disperse filamentous morphology with significantly lower metabolites. Sodium alginate-induced lovastatin and sulochrin production suggest that these metabolites are not affected by viscosity; rather, their production is affected by the specific action of certain chemicals. In contrast, low viscosity adversely affected (+)-geodin's production, while pellet disintegration can cause a significant production of (+)-geodin.

  2. Rapid viscosity measurements of powdered thermosetting resins

    Science.gov (United States)

    Price, H. L.; Burks, H. D.; Dalal, S. K.

    1978-01-01

    A rapid and inexpensive method of obtaining processing-related data on powdered thermosetting resins has been investigated. The method involved viscosity measurements obtained with a small specimen (less than 100 mg) parallel plate plastometer. A data acquisition and reduction system was developed which provided a value of viscosity and strain rate about 12-13 second intervals during a test. The effects of specimen compaction pressure and reduction of adhesion between specimen and parallel plates were examined. The plastometer was used to measure some processing-related viscosity changes of an addition polyimide resin, including changes caused by pre-test heat treatment, test temperature, and strain rate.

  3. Elongational viscosity of multiarm (Pom-Pom) polystyrene

    DEFF Research Database (Denmark)

    Nielsen, Jens Kromann; Rasmussen, Henrik K.; Almdal, Kristoffer

    2006-01-01

    -Pom was estimated to have 2.5 arms on average, while the estimate is 3.3 for the asymmetric star. The molar mass of each arm is about 27 kg/mol. The melts were characterized in the linear viscoelastic regime and in non-linear elongational rheometry. The transient elongational viscosity for the Pom-Pom molecule...... it corresponds well with an estimate of the maximum stretchability of the backbone. Time-strain separability was not observed for the 'Asymmetric star' molecule at the elongation rates investigated. The transient elongational viscosity for the 'Pom-Pom' molecule went through a reproducible maximum...... in the viscosity at the highest elongational rate....

  4. Shear viscosity of liquid mixtures: Mass dependence

    International Nuclear Information System (INIS)

    Kaushal, Rohan; Tankeshwar, K.

    2002-06-01

    Expressions for zeroth, second, and fourth sum rules of transverse stress autocorrelation function of two component fluid have been derived. These sum rules and Mori's memory function formalism have been used to study shear viscosity of Ar-Kr and isotopic mixtures. It has been found that theoretical result is in good agreement with the computer simulation result for the Ar-Kr mixture. The mass dependence of shear viscosity for different mole fraction shows that deviation from ideal linear model comes even from mass difference in two species of fluid mixture. At higher mass ratio shear viscosity of mixture is not explained by any of the emperical model. (author)

  5. Shear viscosity of liquid mixtures Mass dependence

    CERN Document Server

    Kaushal, R

    2002-01-01

    Expressions for zeroth, second, and fourth sum rules of transverse stress autocorrelation function of two component fluid have been derived. These sum rules and Mori's memory function formalism have been used to study shear viscosity of Ar-Kr and isotopic mixtures. It has been found that theoretical result is in good agreement with the computer simulation result for the Ar-Kr mixture. The mass dependence of shear viscosity for different mole fraction shows that deviation from ideal linear model comes even from mass difference in two species of fluid mixture. At higher mass ratio shear viscosity of mixture is not explained by any of the emperical model.

  6. Viscosity of Heterogeneous Silicate Melts: A Non-Newtonian Model

    Science.gov (United States)

    Liu, Zhuangzhuang; Blanpain, Bart; Guo, Muxing

    2017-12-01

    The recently published viscosity data of heterogeneous silicate melts with well-documented structure and experimental conditions are critically re-analyzed and tabulated. By using these data, a non-Newtonian viscosity model incorporating solid fraction, solid shape, and shear rate is proposed on the basis of the power-law equation. This model allows calculating the viscosity of the heterogeneous silicate melts with solid fraction up to 34 vol pct. The error between the calculated and measured data is evaluated to be 32 pct, which is acceptable considering the large error in viscosity measurement of the completely liquid silicate melt.

  7. Rotational and spin viscosities of water: Application to nanofluidics

    DEFF Research Database (Denmark)

    Hansen, Jesper Søndergaard; Bruus, Henrik; Todd, B.D.

    2010-01-01

    In this paper we evaluate the rotational viscosity and the two spin viscosities for liquid water using equilibrium molecular dynamics. Water is modeled via the flexible SPC/Fw model where the Coulomb interactions are calculated via the Wolf method which enables the long simulation times required....... We find that the rotational viscosity is independent of the temperature in the range from 284 to 319 K. The two spin viscosities, on the other hand, decrease with increasing temperature and are found to be two orders of magnitude larger than that estimated by Bonthuis et al. [Phys. Rev. Lett. 103...

  8. Viscosity Prediction of Natural Gas Using the Friction Theory

    DEFF Research Database (Denmark)

    Zeberg-Mikkelsen, Claus Kjær; Cisneros, Sergio; Stenby, Erling Halfdan

    2002-01-01

    Based on the concepts of the friction theory (f-theory) for viscosity modeling, a procedure is introduced for predicting the viscosity of hydrocarbon mixtures rich in one component, which is the case for natural gases. In this procedure, the mixture friction coefficients are estimated with mixing...... rules based on the values of the pure component friction coefficients. Since natural gases contain mainly methane, two f-theory models are combined, where the friction coefficients of methane are estimated by a seven-constant f-theory model directly fitted to methane viscosities, and the friction...... coefficients of the other components are estimated by the one-parameter general f-theory model. The viscosity predictions are performed with the SRK, the PR, and the PRSV equations of state, respectively. For recently measured viscosities of natural gases, the resultant AAD (0.5 to 0.8%) is in excellent...

  9. Evaluation of Relative Blood Viscosity During Menstruation in ...

    African Journals Online (AJOL)

    USER

    ABSTRACT. The changes in blood viscosity, plasma viscosity, haematocrit and erythrocyte sedimentation rate before ... higher (6.78±0.18mm/hr) during the menstrual phase than during the premenstrual phase ... MATERIALS AND METHODS.

  10. Acute urinary retention in a young man secondary to colonic irrigation: a case report

    Directory of Open Access Journals (Sweden)

    Raheem Omer A

    2009-06-01

    Full Text Available Abstract Introduction Autonomic innervation of the bladder is complex and regulated by a hierarchy of mechanisms of the central nervous system. Any dysfunction in these regulatory mechanisms can lead to acute urinary retention. Case presentation A 36-year-old Caucasian man presented with acute urinary retention following extensive bowel irrigation. His urinary bladder was decompressed and his normal voiding mechanism was restored thereafter. Conclusion We postulate that prolonged anorectal and sigmoid dilatation can stimulate the recto-vesicourethral reflex and lead to acute urinary retention via autonomic dysfunction.

  11. Viscosity kernel of molecular fluids

    DEFF Research Database (Denmark)

    Puscasu, Ruslan; Todd, Billy; Daivis, Peter

    2010-01-01

    , temperature, and chain length dependencies of the reciprocal and real-space viscosity kernels are presented. We find that the density has a major effect on the shape of the kernel. The temperature range and chain lengths considered here have by contrast less impact on the overall normalized shape. Functional...... forms that fit the wave-vector-dependent kernel data over a large density and wave-vector range have also been tested. Finally, a structural normalization of the kernels in physical space is considered. Overall, the real-space viscosity kernel has a width of roughly 3–6 atomic diameters, which means...

  12. Comparison and experimental validation of two potential resonant viscosity sensors in the kilohertz range

    International Nuclear Information System (INIS)

    Lemaire, Etienne; Caillard, Benjamin; Dufour, Isabelle; Heinisch, Martin; Jakoby, Bernhard

    2013-01-01

    Oscillating microstructures are well established and find application in many fields. These include force sensors, e.g. AFM micro-cantilevers or accelerometers based on resonant suspended plates. This contribution presents two vibrating mechanical structures acting as force sensors in liquid media in order to measure hydrodynamic interactions. Rectangular cross section microcantilevers as well as circular cross section wires are investigated. Each structure features specific benefits, which are discussed in detail. Furthermore, their mechanical parameters and their deflection in liquids are characterized. Finally, an inverse analytical model is applied to calculate the complex viscosity near the resonant frequency for both types of structures. With this approach it is possible to determine rheological parameters in the kilohertz range in situ within a few seconds. The monitoring of the complex viscosity of yogurt during the fermentation process is used as a proof of concept to qualify at least one of the two sensors in opaque mixtures. (paper)

  13. Comparison and experimental validation of two potential resonant viscosity sensors in the kilohertz range

    Energy Technology Data Exchange (ETDEWEB)

    Lemaire, Etienne; Caillard, Benjamin; Dufour, Isabelle [Univ. Bordeaux, IMS, UMR 5218, F-33400 Talence (France); Heinisch, Martin; Jakoby, Bernhard [Institute for Microelectronics and Microsensors, Johannes Kepler University, Linz (Austria)

    2013-08-15

    Oscillating microstructures are well established and find application in many fields. These include force sensors, e.g. AFM micro-cantilevers or accelerometers based on resonant suspended plates. This contribution presents two vibrating mechanical structures acting as force sensors in liquid media in order to measure hydrodynamic interactions. Rectangular cross section microcantilevers as well as circular cross section wires are investigated. Each structure features specific benefits, which are discussed in detail. Furthermore, their mechanical parameters and their deflection in liquids are characterized. Finally, an inverse analytical model is applied to calculate the complex viscosity near the resonant frequency for both types of structures. With this approach it is possible to determine rheological parameters in the kilohertz range in situ within a few seconds. The monitoring of the complex viscosity of yogurt during the fermentation process is used as a proof of concept to qualify at least one of the two sensors in opaque mixtures. (paper)

  14. Comparison and experimental validation of two potential resonant viscosity sensors in the kilohertz range

    Science.gov (United States)

    Lemaire, Etienne; Heinisch, Martin; Caillard, Benjamin; Jakoby, Bernhard; Dufour, Isabelle

    2013-08-01

    Oscillating microstructures are well established and find application in many fields. These include force sensors, e.g. AFM micro-cantilevers or accelerometers based on resonant suspended plates. This contribution presents two vibrating mechanical structures acting as force sensors in liquid media in order to measure hydrodynamic interactions. Rectangular cross section microcantilevers as well as circular cross section wires are investigated. Each structure features specific benefits, which are discussed in detail. Furthermore, their mechanical parameters and their deflection in liquids are characterized. Finally, an inverse analytical model is applied to calculate the complex viscosity near the resonant frequency for both types of structures. With this approach it is possible to determine rheological parameters in the kilohertz range in situ within a few seconds. The monitoring of the complex viscosity of yogurt during the fermentation process is used as a proof of concept to qualify at least one of the two sensors in opaque mixtures.

  15. The effect of compressive viscosity and thermal conduction on the longitudinal MHD waves

    Science.gov (United States)

    Bahari, K.; Shahhosaini, N.

    2018-05-01

    longitudinal Magnetohydrodynamic (MHD) oscillations have been studied in a slowly cooling coronal loop, in the presence of thermal conduction and compressive viscosity, in the linear MHD approximation. WKB method has been used to solve the governing equations. In the leading order approximation the dispersion relation has been obtained, and using the first order approximation the time dependent amplitude has been determined. Cooling causes the oscillations to amplify and damping mechanisms are more efficient in hot loops. In cool loops the oscillation amplitude increases with time but in hot loops the oscillation amplitude decreases with time. Our conclusion is that in hot loops the efficiency of the compressive viscosity in damping longitudinal waves is comparable to that of the thermal conduction.

  16. Viscosity of low-temperature substances at pressure

    International Nuclear Information System (INIS)

    Rudenko, N.S.; Slyusar', V.P.

    1976-01-01

    The review presents an analysis of data available on the viscosity coefficients of hydrogen, deuterohydrogen, deuterium, neon, argon, krypton, xenon, nitrogen and methane under pressure in the temperature range from triple points to 300 deg K. Averaged values of viscosity coefficients for all the substances listed above versus temperature, pressure and density are tabulated

  17. Plasma viscosity increase with progression of peripheral arterial atherosclerotic disease.

    Science.gov (United States)

    Poredos, P; Zizek, B

    1996-03-01

    Increased blood and plasma viscosity has been described in patients with coronary and peripheral arterial disease. However, the relation of viscosity to the extent of arterial wall deterioration--the most important determinant of clinical manifestation and prognosis of the disease--is not well known. Therefore, the authors studied plasma viscosity as one of the major determinants of blood viscosity in patients with different stages of arterial disease of lower limbs (according to Fontaine) and its relation to the presence of some risk factors of atherosclerosis. The study encompassed four groups of subjects: 19 healthy volunteers (group A), 18 patients with intermittent claudication up to 200 m (stage II; group B), 15 patients with critical ischemia of lower limbs (stage III and IV; group C), and 16 patients with recanalization procedures on peripheral arteries. Venous blood samples were collected from an antecubital vein without stasis for the determination of plasma viscosity (with a rotational capillary microviscometer, PAAR), fibrinogen, total cholesterol, alpha-2-macroglobulin, and glucose concentrations. In patients with recanalization procedure local plasma viscosity was also determined from blood samples taken from a vein on the dorsum of the foot. Plasma viscosity was most significantly elevated in the patients with critical ischemia (1.78 mPa.sec) and was significantly higher than in the claudicants (1.68 mPa.sec), and the claudicants also had significantly higher viscosity than the controls (1.58 mPa.sec). In patients in whom a recanalization procedure was performed, no differences in systemic and local plasma viscosity were detected, neither before nor after recanalization of the diseased artery. In all groups plasma viscosity was correlated with fibrinogen concentration (r=0.70, P < 0.01) and total cholesterol concentration (r=0.24, P < 0.05), but in group C (critical ischemia) plasma viscosity was most closely linked to the concentration of alpha-2

  18. Understanding the Viscosity of Liquids used in Infant Dysphagia Management.

    Science.gov (United States)

    Frazier, Jacqueline; Chestnut, Amanda H; Jackson, Arwen; Barbon, Carly E A; Steele, Catriona M; Pickler, Laura

    2016-10-01

    When assessing swallowing in infants, it is critical to have confidence that the liquids presented during the swallow study closely replicate the viscosity of liquids in the infant's typical diet. However, we lack research on rheological properties of frequently used infant formulas or breastmilk, and various forms of barium contrast media used in swallow studies. The aim of the current study was to provide objective viscosity measurements for typical infant liquid diet options and barium contrast media. A TA-Instruments AR2000 Advanced Rheometer was used to measure the viscosity of five standard infant formulas, three barium products, and two breastmilk samples. Additionally, this study measured the viscosity of infant formulas and breastmilk when mixed with powdered barium contrast in a 20 % weight-to-volume (w/v) concentration. The study findings determined that standard infant formulas and the two breastmilk samples had low viscosities, at the lower end of the National Dysphagia Diet (NDD) thin liquid range. Two specialty formulas tested had much thicker viscosities, close to the lower boundary of the NDD nectar-thick liquid range. The study showed differences in viscosity between 60 % w/v barium products (Liquid E-Z-Paque(®) and E-Z-Paque(®) powder); the powdered product had a much lower viscosity, despite identical barium concentration. When E-Z-Paque(®) powdered barium was mixed in a 20 % w/v concentration using water, standard infant formulas, or breastmilk, the resulting viscosities were at the lower end of the NDD thin range and only slightly thicker than the non-barium comparator liquids. When E-Z-Paque(®) powdered barium was mixed in a 20 % w/v concentration with the two thicker specialty formulas (Enfamil AR 20 and 24 kcal), unexpected alterations in their original viscosity occurred. These findings highlight the clinical importance of objective measures of viscosity as well as objective data on how infant formulas or breastmilk may change in

  19. Understanding the Viscosity of Liquids used in Infant Dysphagia Management

    Science.gov (United States)

    Frazier, Jackie; Chestnut, Amanda; Jackson, Arwen; Barbon, Carly E. A.; Steele, Catriona M.; Pickler, Laura

    2016-01-01

    When assessing swallowing in infants, it is critical to have confidence that the liquids presented during the swallow study closely replicate the viscosity of liquids in the infant's typical diet. However, we lack research on rheological properties of frequently used infant formulas or breastmilk, and various forms of barium contrast media used in swallow studies. The aim of the current study was to provide objective viscosity measurements for typical infant liquid diet options and barium contrast media. A TA-Instruments AR2000 Advanced Rheometer was used to measure the viscosity, five standard infant formulas, three barium products and two breastmilk samples. Additionally, this study measured the viscosity of infant formulas and breastmilk when mixed with powdered barium contrast in a 20% weight-to-volume (w/v) concentration. Study findings determined that standard infant formulas and the two breastmilk samples had low viscosities, at the lower end of the National Dysphagia Diet (NDD) thin liquid range. Two specialty formulas tested had much thicker viscosities, close to the NDD nectar-thick liquid range lower boundary. The study showed differences in viscosity between two 60% w/v barium products (Liquid E-Z-Paque® and E-Z-Paque® powder); the powdered product had a much lower viscosity, despite identical barium concentration. When E-Z-Paque® powdered barium was mixed in a 20% w/v concentration using water, standard infant formulas or breastmilk, the resulting viscosities were at the lower end of the NDD thin range, and only slightly thicker than the non-barium comparator liquids. When E-Z-Paque® powdered barium was mixed in a 20% w/v concentration with the two thicker specialty formulas (Enfamil AR 20kcal and 24 kcal), unexpected alterations in their original viscosity occurred. These findings highlight the clinical importance of objective measures of viscosity as well as objective data on how infant formulas or breastmilk may change in consistency when mixed

  20. Bulk viscosity in 2SC quark matter

    International Nuclear Information System (INIS)

    Alford, Mark G; Schmitt, Andreas

    2007-01-01

    The bulk viscosity of three-flavour colour-superconducting quark matter originating from the nonleptonic process u + s ↔ u + d is computed. It is assumed that up and down quarks form Cooper pairs while the strange quark remains unpaired (2SC phase). A general derivation of the rate of strangeness production is presented, involving contributions from a multitude of different subprocesses, including subprocesses that involve different numbers of gapped quarks as well as creation and annihilation of particles in the condensate. The rate is then used to compute the bulk viscosity as a function of the temperature, for an external oscillation frequency typical of a compact star r-mode. We find that, for temperatures far below the critical temperature T c for 2SC pairing, the bulk viscosity of colour-superconducting quark matter is suppressed relative to that of unpaired quark matter, but for T ∼> T c /30 the colour-superconducting quark matter has a higher bulk viscosity. This is potentially relevant for the suppression of r-mode instabilities early in the life of a compact star

  1. Stress relaxation and creep on living cells with the atomic force microscope: a means to calculate elastic moduli and viscosities of cell components

    International Nuclear Information System (INIS)

    Moreno-Flores, Susana; Toca-Herrera, Jose Luis; Benitez, Rafael; Vivanco, Maria dM

    2010-01-01

    In this work we present a unified method to study the mechanical properties of cells using the atomic force microscope. Stress relaxation and creep compliance measurements permitted us to determine, the relaxation times, the Young moduli and the viscosity of breast cancer cells (MCF-7). The results show that the mechanical behaviour of MCF-7 cells responds to a two-layered model of similar elasticity but differing viscosity. Treatment of MCF-7 cells with an actin-depolymerising agent results in an overall decrease in both cell elasticity and viscosity, however to a different extent for each layer. The layer that undergoes the smaller decrease (36-38%) is assigned to the cell membrane/cortex while the layer that experiences the larger decrease (70-80%) is attributed to the cell cytoplasm. The combination of the method presented in this work, together with the approach based on stress relaxation microscopy (Moreno-Flores et al 2010 J. Biomech. 43 349-54), constitutes a unique AFM-based experimental framework to study cell mechanics. This methodology can also be extended to study the mechanical properties of biomaterials in general.

  2. Effect of thrombus composition and viscosity on sonoreperfusion efficacy in a model of microvascular obstruction

    Science.gov (United States)

    Black, John J.; Yu, Francois T. H.; Schnatz, Rick G.; Flordeliza, Xucai Chen; Villanueva, S.; Pacella, John J.

    2016-01-01

    Distal embolization of microthrombi during stenting for myocardial infarction (MI) causes microvascular obstruction (MVO). We have previously shown that sonoreperfusion (SRP), a microbubble (MB)-mediated ultrasonic (US) therapy, resolves MVO from venous microthrombi in vitro in saline. However, blood is more viscous than saline and arterial thrombi that embolize during stenting are mechanically distinct from venous clot. Therefore, we tested the hypothesis that MVO created with arterial microthrombi are more resistant to SRP therapy compared with venous microthrombi and higher viscosity further increases the US requirement for effective SRP in an in vitro model of MVO. Lipid MB suspended in plasma with adjusted viscosity (1.1 or 4.0 cP) were passed through tubing bearing a mesh with 40 μm pores to simulate a microvascular cross-section; upstream pressure reflected thrombus burden. To simulate MVO, the mesh was occluded with either arterial or venous microthrombi to increase upstream pressure to 40±5 mmHg. Therapeutic long-tone-burst US was delivered to the occluded area for 20 min. MB activity was recorded with a passive cavitation detector (PCD). MVO caused by arterial microthrombi at either blood or plasma viscosity resulted in less effective SRP therapy, compared to venous thrombi. Higher viscosity further reduced the effectiveness of SRP therapy. PCD showed a decrease in inertial cavitation when viscosity was increased while stable cavitation was affected in a more complex manner. Overall, these data suggest that arterial thrombi may require higher acoustic pressure US than venous thrombi to achieve similar SRP efficacy, increased viscosity decreases SRP efficacy, and both inertial and stable cavitation are implicated in observed SRP efficacy. PMID:27207018

  3. An eddy viscosity model for flow in a tube bundle

    International Nuclear Information System (INIS)

    Soussan, D.; Grandotto, M.

    1998-01-01

    The work described in this paper is part of the development of GENEPI a 3-dimensional finite element code, designed for the thermalhydraulic analysis of steam generators. It focuses on the implementation of two-phase flow turbulence-induced viscosity in a tube bundle. The GENEPI code, as other industrial codes, uses the eddy viscosity concept introduced by Boussinesq for single phase flow. The concept assumes that the turbulent momentum transfer is similar to the viscous shear stresses. Eddy viscosity formulation is reasonably well known for single phase flows, especially in simple geometries (i.e., in smooth tube, around a single body, or behind a row of bars/tubes), but there exists very little information on it for two-phase flows. An analogy between single and two-phases is used to set up a model for eddy viscosity. The eddy viscosity model examined in this paper is used for a tube bundle geometry and, therefore, is extended to include anisotropy to the classic model. Each of the main flow directions (cross flow inline, cross flow staggered, and parallel flows) gives rise to a specific eddy viscosity formula. The results from a parametric study indicate that the eddy viscosity in the staggered flow is roughly 1.5 times as large as that for the inline cross flow, 60 times as large as that for the parallel flow, and 105 as large as that for the molecular viscosity. Then, the different terms are combined with each other to result in a global eddy viscosity model for a steam generator tube bundle flow. (author)

  4. The influence of magnetic fields on crude oils viscosity

    Energy Technology Data Exchange (ETDEWEB)

    Goncalves, Jose L.; Bombard, Antonio J. F. [Universidade Federal de Itajuba (UNIFEI), Itajuba, MG (Brazil). Instituto de Ciencias Exatas. Lab. de Reologia

    2009-07-01

    The crystallization of paraffin causes serious problems in the process of transportation of petroleum. This phenomenon increases the crude oil viscosity and implies an organic resin accumulation on pipeline wall, resulting in a reduced flux area or totally blocked pipes. One of the most challenging tasks for pipeline maintenance is solving this problem at low cost. Therefore, a method that inhibits the crystallization of paraffin and reduces the viscosity of crude oil could have many useful applications within the petroleum industry. Recent studies showed that magnetic fields reduce the Wax Appearance Temperature (WAT) and the viscosity of paraffin-based crude oil. For better understanding of this discovery, a series of tests was performed. This paper will show the influence of a DC magnetic field on rheological proprieties of three crude oils with different paraffin concentrations: a crude oil sample with 11 % p/p of paraffin concentration (sample 1); a crude oil sample with 6 % p/p of paraffin concentration (sample 2); a mixture of paraffin plus light crude oil with a total of 11 % p/p of paraffin concentration. These samples were placed in an electromagnet that generates a magnetic field of 1.3 Tesla. The samples' temperatures were conditioned around their Wax Appearance Temperature (WAT), and they were exposed to the field. As the viscosity of crude oil is very sensitive to the changes in temperature, it was ensured that the temperature has remained constant throughout the process. The sample 1 revealed a considerable reduction of viscosity: its original viscosity was 66 cP before magnetic field exposure, after that its viscosity was reduced to 39 cP. The other samples showed the same viscosity, before and after the magnetic field exposure. Since the samples 1 and 3 have the same paraffin concentrations, the viscosity reduction is not due only to the presence of paraffin; there must be other factors responsible for the interaction of sample 1 with the

  5. Shear viscosity of liquid argon and liquid rubidium

    International Nuclear Information System (INIS)

    Chiakwelu, O.

    1978-01-01

    A direct evaluation of the shear viscosity coefficient for models of liquid rubidium and liquid argon is presented by neglecting the cross-terms in the autocorrelation function of the transverse component of the momentum stress tensor. The time dependence of the shear viscosity for liquid argon is found to display a long decaying tail in qualitative agreement with a computer calculation of Levesque et al. However, the numerical values of the shear viscosity coefficients are smaller than the experimentally determined values of about 45% for liquid rubidium and 35% for liquid argon

  6. An empirical model for the melt viscosity of polymer blends

    International Nuclear Information System (INIS)

    Dobrescu, V.

    1981-01-01

    On the basis of experimental data for blends of polyethylene with different polymers an empirical equation is proposed to describe the dependence of melt viscosity of blends on component viscosities and composition. The model ensures the continuity of viscosity vs. composition curves throughout the whole composition range, the possibility of obtaining extremum values higher or lower than the viscosities of components, allows the calculation of flow curves of blends from the flow curves of components and their volume fractions. (orig.)

  7. Enhancing retention of partial dentures using elastomeric retention rings

    Directory of Open Access Journals (Sweden)

    Kakkirala Revathi

    2015-01-01

    Full Text Available This report presents an alternative method for the retention of partial dentures that relies on the engagement of tooth undercuts by a lining material. The lab procedures are also presented. A new maxillary and mandibular acrylic partial dentures were fabricated using elastomeric retention technique for a partially dentate patient. A partially dentate man reported difficulty in retaining his upper removable partial denture (RPD. The maxillary RPD was designed utilizing elastomeric retention technique. During follow-up, it was necessary to replace the retention rings due to wear. The replacement of the retention rings, in this case, was done through a chairside reline technique. Elastomeric retention technique provides exceptionally good retention can be indicated to stabilize, cushion, splint periodontally involved teeth, no enough undercut for clasps, eliminate extractions, single or isolated teeth.

  8. Modeling of Viscosity and Thermal Expansion of Bioactive Glasses

    OpenAIRE

    Farid, Saad B. H.

    2012-01-01

    The behaviors of viscosity and thermal expansion for different compositions of bioactive glasses have been studied. The effect of phosphorous pentoxide as a second glass former in addition to silica was investigated. Consequently, the nonlinear behaviors of viscosity and thermal expansion with respect to the oxide composition have been modeled. The modeling uses published data on bioactive glass compositions with viscosity and thermal expansion. -regression optimization technique has been uti...

  9. Communication: Simple liquids' high-density viscosity.

    Science.gov (United States)

    Costigliola, Lorenzo; Pedersen, Ulf R; Heyes, David M; Schrøder, Thomas B; Dyre, Jeppe C

    2018-02-28

    This paper argues that the viscosity of simple fluids at densities above that of the triple point is a specific function of temperature relative to the freezing temperature at the density in question. The proposed viscosity expression, which is arrived at in part by reference to the isomorph theory of systems with hidden scale invariance, describes computer simulations of the Lennard-Jones system as well as argon and methane experimental data and simulation results for an effective-pair-potential model of liquid sodium.

  10. Communication: Simple liquids' high-density viscosity

    Science.gov (United States)

    Costigliola, Lorenzo; Pedersen, Ulf R.; Heyes, David M.; Schrøder, Thomas B.; Dyre, Jeppe C.

    2018-02-01

    This paper argues that the viscosity of simple fluids at densities above that of the triple point is a specific function of temperature relative to the freezing temperature at the density in question. The proposed viscosity expression, which is arrived at in part by reference to the isomorph theory of systems with hidden scale invariance, describes computer simulations of the Lennard-Jones system as well as argon and methane experimental data and simulation results for an effective-pair-potential model of liquid sodium.

  11. On-line measurement of food viscosity during flow

    DEFF Research Database (Denmark)

    Mason, Sarah Louise; Friis, Alan

    2006-01-01

    Sarah L. Mason and Alan Friis discuss some of the principles and equipment used to monitor food viscosity in real time.......Sarah L. Mason and Alan Friis discuss some of the principles and equipment used to monitor food viscosity in real time....

  12. On the bulk viscosity of relativistic matter

    International Nuclear Information System (INIS)

    Canuto, V.; Hsieh, S.-H.

    1978-01-01

    An expression for the bulk viscosity coefficient in terms of the trace of the hydrodynamic energy-stress tensor is derived from the Kubo formula. This, along with a field-theoretic model of an interacting system of scalar particles, suggests that at high temperatures the bulk viscosity tends to zero, contrary to the often quoted resuls of Iso, Mori and Namiki. (author)

  13. Local viscosity distribution in bifurcating microfluidic blood flows

    Science.gov (United States)

    Kaliviotis, E.; Sherwood, J. M.; Balabani, S.

    2018-03-01

    The red blood cell (RBC) aggregation phenomenon is majorly responsible for the non-Newtonian nature of blood, influencing the blood flow characteristics in the microvasculature. Of considerable interest is the behaviour of the fluid at the bifurcating regions. In vitro experiments, using microchannels, have shown that RBC aggregation, at certain flow conditions, affects the bluntness and skewness of the velocity profile, the local RBC concentration, and the cell-depleted layer at the channel walls. In addition, the developed RBC aggregates appear unevenly distributed in the outlets of these channels depending on their spatial distribution in the feeding branch, and on the flow conditions in the outlet branches. In the present work, constitutive equations of blood viscosity, from earlier work of the authors, are applied to flows in a T-type bifurcating microchannel to examine the local viscosity characteristics. Viscosity maps are derived for various flow distributions in the outlet branches of the channel, and the location of maximum viscosity magnitude is obtained. The viscosity does not appear significantly elevated in the branches of lower flow rate as would be expected on the basis of the low shear therein, and the maximum magnitude appears in the vicinity of the junction, and towards the side of the outlet branch with the higher flow rate. The study demonstrates that in the branches of lower flow rate, the local viscosity is also low, helping us to explain why the effects of physiological red blood cell aggregation have no adverse effects in terms of in vivo vascular resistance.

  14. Plasma viscosity with mass transport in spherical inertial confinement fusion implosion simulations

    Energy Technology Data Exchange (ETDEWEB)

    Vold, E. L.; Molvig, K. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Joglekar, A. S. [University of Michigan, Ann Arbor, Michigan 48109 (United States); Ortega, M. I. [University of New Mexico, Albuquerque, New Mexico 87131 (United States); Moll, R. [University of California, Santa Cruz, California 95064 (United States); Fenn, D. [Florida State University, Tallahassee, Florida 32306 (United States)

    2015-11-15

    The effects of viscosity and small-scale atomic-level mixing on plasmas in inertial confinement fusion (ICF) currently represent challenges in ICF research. Many current ICF hydrodynamic codes ignore the effects of viscosity though recent research indicates viscosity and mixing by classical transport processes may have a substantial impact on implosion dynamics. We have implemented a Lagrangian hydrodynamic code in one-dimensional spherical geometry with plasma viscosity and mass transport and including a three temperature model for ions, electrons, and radiation treated in a gray radiation diffusion approximation. The code is used to study ICF implosion differences with and without plasma viscosity and to determine the impacts of viscosity on temperature histories and neutron yield. It was found that plasma viscosity has substantial impacts on ICF shock dynamics characterized by shock burn timing, maximum burn temperatures, convergence ratio, and time history of neutron production rates. Plasma viscosity reduces the need for artificial viscosity to maintain numerical stability in the Lagrangian formulation and also modifies the flux-limiting needed for electron thermal conduction.

  15. Applicability of viscosity measurement to the detection of irradiated peppers

    International Nuclear Information System (INIS)

    Hayashi, T.; Todoriki, S.; Kohyama, K.

    1996-01-01

    Starch is degraded by ionising radiation, resulting in a decrease in viscosity. The viscosities of black and white peppers which contain large amounts of starch are reduced by irradiation so, therefore, viscosity measurement has been proposed as a method to detect the irradiation treatment of these food products. Although detection of irradiated spices by thermoluminescence measurement has been established, it is useful to establish the viscosity measuring technique for detecting irradiated peppers, as this method is carried out widely in the laboratories of food controlling authorities and food processing companies. (author)

  16. Determination of viscosity in recirculating fluidized bed using radioactive tracer

    International Nuclear Information System (INIS)

    Silva, G.G. da.

    1986-01-01

    The use of radioactive tracer for measuring viscosity is proposed. The methodology relates the terminal velocity of a radioactive sphere in interior of fluid with the viscosity, which can be a fluidized bed or total flow of solids. The arrangement is composed by two γ detectors placed externally and along the bed. Both detectors are coupled by amplifier to electronic clock. The drop time of sphere between two detectors is measured. The bed viscosity two detectors is measured. The bed viscosity is calculated from mathematical correlations of terminal velocity of the sphere. (M.C.K.)

  17. Monetary and Non-monetary SWO Retention Bonuses: An Experimental Approach to the Combinatorial Retention Auction Mechanism (CRAM)

    Science.gov (United States)

    2009-12-01

    aircraft carrier would not function properly nor could a guided missile destroyer fulfill its missions. Retention of qualified and motivated ...19 Jason Blake Ellis, “Variability of Valuation of Non-Monetary Incentives: Motivating and...this illustration offer individual values that exceed the Navy’s cost to provide the incentive for most individuals. On the other hand, telecommuting

  18. Segment-based Eyring-Wilson viscosity model for polymer solutions

    International Nuclear Information System (INIS)

    Sadeghi, Rahmat

    2005-01-01

    A theory-based model is presented for correlating viscosity of polymer solutions and is based on the segment-based Eyring mixture viscosity model as well as the segment-based Wilson model for describing deviations from ideality. The model has been applied to several polymer solutions and the results show that it is reliable both for correlation and prediction of the viscosity of polymer solutions at different molar masses and temperature of the polymer

  19. Elongational viscosity of monodisperse and bidisperse polystyrene melts

    DEFF Research Database (Denmark)

    Nielsen, Jens Kromann; Rasmussen, Henrik K.; Hassager, Ole

    2006-01-01

    The start-up and steady uniaxial elongational viscosity have been measured for two monodisperse polystyrene melts with molecular weights of 52 and 103 kg/mole, and for three bidisperse polystyrene melts. The monodisperse melts show a maximum in the steady elongational viscosity vs. the elongational...

  20. Effect of ion viscosity on neoclassical tearing mode

    International Nuclear Information System (INIS)

    Yoshida, Shigeki; Itoh, Sanae-I.; Yagi, Masatoshi; Azumi, Masafumi

    2004-01-01

    Linear stability analysis of neoclassical tearing mode (NTM) is performed on the basis of four-field reduced magnetohydrodynamic (MHD) model which takes account of fluctuating ion parallel flow and ion neoclassical viscosity. The dependence of the growth rate on the kinetic effects is investigated. It is shown that the linear NTM is stabilized by ion neoclassical viscosity and that the stabilizing effect of ion parallel compressibility is weak in the banana-plateau regime. It is found that not only ion neoclassical viscosity but also both ion and electron diamagnetic effects are important for the stabilization of NTM. (author)

  1. Shear viscosities of photons in strongly coupled plasmas

    Directory of Open Access Journals (Sweden)

    Di-Lun Yang

    2016-09-01

    Full Text Available We investigate the shear viscosity of thermalized photons in the quark gluon plasma (QGP at weak coupling and N=4 super Yang–Mills plasma (SYMP at both strong and weak couplings. We find that the shear viscosity due to the photon–parton scattering up to the leading order of electromagnetic coupling is suppressed when the coupling of the QGP/SYMP is increased, which stems from the blue-shift of the thermal-photon spectrum at strong coupling. In addition, the shear viscosity rapidly increases near the deconfinement transition in a phenomenological model analogous to the QGP.

  2. Design of Oil Viscosity Sensor Based on Plastic Optical Fiber

    Science.gov (United States)

    Yunus, Muhammad; Arifin, A.

    2018-03-01

    A research of plastic optical fiber based sensors have been studied for measurement of oil viscosity. This sensor was made with straight configuration, U configuration, and gamma configuration have two types, there are optical fiber sensor with cladding and without cladding. Viscosity sensor was made, dipped into an oil sample with a concentration of viscosity percentage about 270 mPa.s - 350 mPa.s. The light from the LED propagated into the optical fiber, then it was received by the photodetector converted to output power. When plastic optical fiber dipped into an oil sample, viscosity of oil affect increase of refractive index on optical fiber resulting in a bigger loss of power so the light intensity will be smaller, consequences the measured output power will be smaller. Sensitivity and resolution viscosity sensor without cladding peel showed the best result rather than viscosity sensor with cladding peel. The best result in the measurement showed in gamma configuration with 3 cm length of cladding peel and the diameter of bending 0,25 cm is the range 103,090 nWatt, sensitivity 1,289 nWatt/mPa.s, and resolution 0,776 mPa.s. This method is effectively and efficiently used as an oil viscosity sensor with high sensitivity and resolution.

  3. Physiological Mechanisms in Herbivores for Retention and Utilization of Nitrogenous Compounds

    Energy Technology Data Exchange (ETDEWEB)

    Sperber, I. [Department of Animal Physiology, Agricultural College of Sweden, Uppsala 7 (Sweden)

    1968-07-01

    A short review is given of some aspects of nitrogen metabolism in herbivorous mammals. In the rumen the passage of urea into the rumen and of ammonia out of the rumen are of considerable importance. As yet no facts have been disclosed which definitely prove the existence of special mechanisms influencing these processes in a way favouring the use of endogenous urea in the rumen. The excretion of urea by the kidneys on the other hand is regulated in a manner which appears to be adapted for improved utilization of nitrogen when the nitrogen supply is low. It is further pointed out that efficient retention of microbial protein produced in the caecum must be of considerable importance to herbivores with a large caecum. Some preliminary results are given concerning the physiology of the colon in rabbits and the anatomy and physiology of the colon in lemmings. In the rabbit it appears probable that the passage of fluid and fine particles through the colon is considerably delayed compared with the passage of larger particles. In the lemming an anatomically complicated proximal part of the colon effects a very efficient separation of the microorganisms from the indigestible food residues when caecal contents pass through the colon. The microorganisms appear to be returned to the most proximal part of the colon or into the caecum. Mechanisms of this type seem to be of considerable value to herbivores, enabling them to utilize food with a low digestibility and a low protein content. (author)

  4. Diffusivities, viscosities, and conductivities of solvent-free ionically grafted nanoparticles

    KAUST Repository

    Hong, Bingbing; Panagiotopoulos, Athanassios Z.

    2013-01-01

    A new class of conductive composite materials, solvent-free ionically grafted nanoparticles, were modeled by coarse-grained molecular dynamics methods. The grafted oligomeric counterions were observed to migrate between different cores, contributing to the unique properties of the materials. We investigated the dynamics by analyzing the dependence on temperature and structural parameters of the transport properties (self-diffusion coefficients, viscosities and conductivities) and counterion migration kinetics. Temperature dependence of all properties follows the Arrhenius equation, but chain length and grafting density have distinct effects on different properties. In particular, structural effects on the diffusion coefficients are described by the Rouse model and the theory of nanoparticles diffusing in polymer solutions, viscosities are strongly influenced by clustering of cores, and conductivities are dominated by the motions of oligomeric counterions. We analyzed the migration kinetics of oligomeric counterions in a manner analogous to unimer exchange between micellar aggregates. The counterion migrations follow the "double-core" mechanism and are kinetically controlled by neighboring-core collisions. © 2013 The Royal Society of Chemistry.

  5. Bulk and shear viscosities of hot and dense hadron gas

    International Nuclear Information System (INIS)

    Kadam, Guru Prakash; Mishra, Hiranmaya

    2015-01-01

    We estimate the bulk and the shear viscosity at finite temperature and baryon densities of hadronic matter within a hadron resonance gas model which includes a Hagedorn spectrum. The parameters of the Hagedorn spectrum are adjusted to fit recent lattice QCD simulations at finite chemical potential. For the estimation of the bulk viscosity we use low energy theorems of QCD for the energy momentum tensor correlators. For the shear viscosity coefficient, we estimate the same using molecular kinetic theory to relate the shear viscosity coefficient to average momentum of the hadrons in the hot and dense hadron gas. The bulk viscosity to entropy ratio increases with chemical potential and is related to the reduction of velocity of sound at nonzero chemical potential. The shear viscosity to entropy ratio on the other hand, shows a nontrivial behavior with the ratio decreasing with chemical potential for small temperatures but increasing with chemical potential at high temperatures and is related to decrease of entropy density with chemical potential at high temperature due to finite volume of the hadrons

  6. Mechanisms of gas bubble retention and release: results for Hanford Waste Tanks 241-S-102 and 241-SY-103 and single-shell tank simulants

    Energy Technology Data Exchange (ETDEWEB)

    Gauglitz, P.A.; Rassat, S.D.; Bredt, P.R.; Konynenbelt, J.H.; Tingey, S.M.; Mendoza, D.P.

    1996-09-01

    Research at Pacific Northwest National Laboratory (PNNL) has probed the physical mechanisms and waste properties that contribute to the retention and release of flammable gases from radioactive waste stored in underground tanks at Hanford. This study was conducted for Westinghouse Hanford Company as part of the PNNL Flammable Gas Project. The wastes contained in the tanks are mixes of radioactive and chemical products, and some of these wastes are known to generate mixtures of flammable gases, including hydrogen, nitrous oxide, and ammonia. Because these gases are flammable, their retention and episodic release pose a number of safety concerns.

  7. Mechanisms of gas bubble retention and release: results for Hanford Waste Tanks 241-S-102 and 241-SY-103 and single-shell tank simulants

    International Nuclear Information System (INIS)

    Gauglitz, P.A.; Rassat, S.D.; Bredt, P.R.; Konynenbelt, J.H.; Tingey, S.M.; Mendoza, D.P.

    1996-09-01

    Research at Pacific Northwest National Laboratory (PNNL) has probed the physical mechanisms and waste properties that contribute to the retention and release of flammable gases from radioactive waste stored in underground tanks at Hanford. This study was conducted for Westinghouse Hanford Company as part of the PNNL Flammable Gas Project. The wastes contained in the tanks are mixes of radioactive and chemical products, and some of these wastes are known to generate mixtures of flammable gases, including hydrogen, nitrous oxide, and ammonia. Because these gases are flammable, their retention and episodic release pose a number of safety concerns

  8. Elongational viscosity of monodisperse and bidisperse polystyrene melts

    DEFF Research Database (Denmark)

    Nielsen, Jens Kromann; Rasmussen, Henrik Koblitz; Hassager, Ole

    2005-01-01

    The startup and steady uniaxial elongational viscosity have been measured for two monodisperse polystyrene melts with molecular weights of 52 kg/mole (PS52K) and 103 kg/mole (PS103K), and for three bidisperse polystyrene melts. The bidisperse melts consist of PS103K or PS52K and a monodisperse...... (closed loop proportional regulator) using the laser in such a way that the stretch rate at the neck is kept constant. The rheometer has been described in more detail in (A. Bach, H.K. Rasmussen and O. Hassager, Journal of Rheology, 47 (2003) 429). PS390K show a decrease in the steady viscosity as a power......-law function of the elongational rate (A. Bach, K. Almdal, H.K. Rasmussen and O. Hassager, Macromolecules 36 (2003) 5174). PS52K and PS103K show that the steady viscosity has a maximum that is respectively 100% and 50% above 3 times the zero-shear-rate viscosity. The bidisperse melts show a significant...

  9. Relating Fresh Concrete Viscosity Measurements from Different Rheometers.

    Science.gov (United States)

    Ferraris, Chiara F; Martys, Nicos S

    2003-01-01

    Concrete rheological properties need to be properly measured and predicted in order to characterize the workability of fresh concrete, including special concretes such as self-consolidating concrete (SCC). It was shown by a round-robin test held in 2000 [1,2] that different rheometer designs gave different values of viscosity for the same concrete. While empirical correlation between different rheometers was possible, for a procedure that is supposed to "scientifically" improve on the empirical slump tests, this situation is unsatisfactory. To remedy this situation, a new interpretation of the data was developed. In this paper, it is shown that all instruments tested could be directly and quantitatively compared in terms of relative plastic viscosity instead of the plastic viscosity alone. This should eventually allow the measurements from various rheometer designs to be directly calibrated against known standards of plastic viscosity, putting concrete rheometry and concrete workability on a sounder materials science basis.

  10. Various methods for determination of liquid viscosity with nuclear track membranes

    International Nuclear Information System (INIS)

    Guo Shilun

    1991-01-01

    A systematic study has been performed of the methods for determination of liquid viscosity with nuclear track membranes. Absolute and relative measurements have been suggested, the latter including relative measurements of absolute viscosity and kinematic viscosity. The study shows that the nuclear track membrane is a unique element for determination of liquid viscosity because it is small in volume, accurate in results and easy to manipulate in industries and laboratories

  11. THE FIRST DETERMINATION OF THE VISCOSITY PARAMETER IN THE CIRCUMSTELLAR DISK OF A Be STAR

    Energy Technology Data Exchange (ETDEWEB)

    Carciofi, Alex C.; Bjorkman, Jon E.; Haubois, Xavier [Instituto de Astronomia, Geofisica e Ciencias Atmosfericas, Universidade de Sao Paulo, Rua do Matao 1226, Cidade Universitaria, 05508-900, Sao Paulo, SP (Brazil); Otero, Sebastian A. [American Association of Variable Star Observers, 49 Bay State Road, Cambridge, MA 02138 (United States); Okazaki, Atsuo T. [Faculty of Engineering, Hokkai-Gakuen University, Toyohira-ku, Sapporo 062-8605 (Japan); Stefl, Stanislav; Rivinius, Thomas [European Organisation for Astronomical Research in the Southern Hemisphere, Casilla 19001, Santiago 19 (Chile); Baade, Dietrich, E-mail: carciofi@usp.br, E-mail: jon@physics.utoledo.edu [European Organisation for Astronomical Research in the Southern Hemisphere, Karl-Schwarzschild-Str. 2, 85748 Garching bei Muenchen (Germany)

    2012-01-15

    Be stars possess gaseous circumstellar decretion disks, which are well described using standard {alpha}-disk theory. The Be star 28 CMa recently underwent a long outburst followed by a long period of quiescence, during which the disk dissipated. Here we present the first time-dependent models of the dissipation of a viscous decretion disk. By modeling the rate of decline of the V-band excess, we determine that the viscosity parameter {alpha} = 1.0 {+-} 0.2, corresponding to a mass injection rate M-dot =(3.5{+-}1.3) Multiplication-Sign 10{sup -8} M{sub Sun} yr{sup -1}. Such a large value of {alpha} suggests that the origin of the turbulent viscosity is an instability in the disk whose growth is limited by shock dissipation. The mass injection rate is more than an order of magnitude larger than the wind mass-loss rate inferred from UV observations, implying that the mass injection mechanism most likely is not the stellar wind, but some other mechanism.

  12. Bulk viscosity, interaction and the viability of phantom solutions

    Energy Technology Data Exchange (ETDEWEB)

    Leyva, Yoelsy; Sepulveda, Mirko [Universidad de Tarapaca, Departamento de Fisica, Facultad de Ciencias, Arica (Chile)

    2017-06-15

    We study the dynamics of a bulk viscosity model in the Eckart approach for a spatially flat Friedmann-Robertson-Walker (FRW) Universe. We have included radiation and dark energy, assumed as perfect fluids, and dark matter treated as an imperfect fluid having bulk viscosity. We also introduce an interaction term between the dark matter and dark energy components. Considering that the bulk viscosity is proportional to the dark matter energy density and imposing a complete cosmological dynamics, we find bounds on the bulk viscosity in order to reproduce a matter-dominated era (MDE). This constraint is independent of the interaction term. Some late time phantom solutions are mathematically possible. However, the constraint imposed by a MDE restricts the interaction parameter, in the phantom solutions, to a region consistent with a null value, eliminating the possibility of late time stable solutions with w < -1. From the different cases that we study, the only possible scenario, with bulk viscosity and interaction term, belongs to the quintessence region. In the latter case, we find bounds on the interaction parameter compatible with latest observational data. (orig.)

  13. Direct observations of the viscosity of Earth's outer core and extrapolation of measurements of the viscosity of liquid iron

    International Nuclear Information System (INIS)

    Smylie, D E; Brazhkin, Vadim V; Palmer, Andrew

    2009-01-01

    Estimates vary widely as to the viscosity of Earth's outer fluid core. Directly observed viscosity is usually orders of magnitude higher than the values extrapolated from high-pressure high-temperature laboratory experiments, which are close to those for liquid iron at atmospheric pressure. It turned out that this discrepancy can be removed by extrapolating via the widely known Arrhenius activation model modified by lifting the commonly used assumption of pressure-independent activation volume (which is possible due to the discovery that at high pressures the activation volume increases strongly with pressure, resulting in 10 2 Pa s at the top of the fluid core, and in 10 11 Pa s at its bottom). There are of course many uncertainties affecting this extrapolation process. This paper reviews two viscosity determination methods, one for the top and the other for the bottom of the outer core, the former of which relies on the decay of free core nutations and yields 2371 ± 1530 Pa s, while the other relies on the reduction in the rotational splitting of the two equatorial translational modes of the solid inner core oscillations and yields an average of 1.247 ± 0.035 Pa s. Encouraged by the good performance of the Arrhenius extrapolation, a differential form of the Arrhenius activation model is used to interpolate along the melting temperature curve and to find the viscosity profile across the entire outer core. The viscosity variation is found to be nearly log-linear between the measured boundary values. (methodological notes)

  14. Dairy-Based Emulsions: Viscosity Affects Fat Difference Thresholds and Sweetness Perception.

    Science.gov (United States)

    Zahn, Susann; Hoppert, Karin; Ullrich, Franziska; Rohm, Harald

    2013-11-27

    In complex emulsions, viscosity or viscosity-associated sensory attributes such as creaminess are important for quality assessment and product differentiation. Two sets of emulsions with fat or locust bean gum content being varied at seven levels were developed; the two emulsions at each level had similar apparent viscosity. Additionally, sugar concentration was kept constant either with respect to total emulsion, or with respect to the aqueous phase. Series of two-alternative forced choice tests were performed with one constant stimulus, and just noticeable differences were calculated using probability regression. The results show that, when viscosity was not compensated, it was easy for the subjects to (a) distinguish emulsions with different fat content when the fat content was addressed in the question, and to (b) distinguish emulsions with different fat or locust bean gum content when creaminess was addressed. For the latter descriptor, it is of minor importance whether viscosity is altered by fat content or a thickener. Weber fractions that were calculated for viscosity were approximately 0.20. The quantitative effects of viscosity on sweetness, however, depend on how product rheology was modified.

  15. Effective Viscosity in Porous Media and Applicable Limitations for Polymer Flooding of an Associative Polymer

    Directory of Open Access Journals (Sweden)

    Zhang Peng

    2015-11-01

    Full Text Available Hydrophobically associating polyacrylamide (HAPAM is considered to be a promising candidate for polymer flooding because of its excellent apparent viscosifying capability. Compared with partially hydrolyzed polyacrylamide (HPAM, the resistance factor and residual resistance factor caused by HAPAM tend to be higher. However, the effective viscosity of HAPAM is lower than that of conventional polymer at a concentration of 2 000 mg/L. The dynamic retention capacity of HAPAM is about 2.3 times that of HPAM. The oil displacement efficiency of HAPAM is lower than that of conventional polymer at a concentration of 2 000 mg/L in the homogeneous sandpack model. The oil displacement efficiency of HAPAM is higher than that of HPAM only in the heterogeneous model (permeability ratio 2.8. Neither high nor low permeability ratios are good for the oil displacement efficiency of HAPAM.

  16. Temperature Dependence Viscosity and Density of Different Biodiesel Blends

    Directory of Open Access Journals (Sweden)

    Vojtěch Kumbár

    2015-01-01

    Full Text Available The main goal of this paper is to assess the effect of rapeseed oil methyl ester (RME concentration in diesel fuel on its viscosity and density behaviour. The density and dynamic viscosity were observed at various mixing ratios of RME and diesel fuel. All measurements were performed at constant temperature of 40 °C. Increasing ratio of RME in diesel fuel was reflected in increased density value and dynamic viscosity of the blend. In case of pure RME, pure diesel fuel, and a blend of both (B30, temperature dependence of dynamic viscosity and density was examined. Temperature range in the experiment was −10 °C to 80 °C. Considerable temperature dependence of dynamic viscosity and density was found and demonstrated for all three samples. This finding is in accordance with theoretical assumptions and reference data. Mathematical models were developed and tested. Temperature dependence of dynamic viscosity was modeled using a polynomial 3rd polynomial degree. Correlation coefficients R −0.796, −0.948, and −0.974 between measured and calculated values were found. Temperature dependence of density was modeled using a 2nd polynomial degree. Correlation coefficients R −0.994, −0.979, and −0.976 between measured and calculated values were acquired. The proposed models can be used for flow behaviour prediction of RME, diesel fuel, and their blends.

  17. Blood viscosity during coagulation at different shear rates

    Science.gov (United States)

    Ranucci, Marco; Laddomada, Tommaso; Ranucci, Matteo; Baryshnikova, Ekaterina

    2014-01-01

    Abstract During the coagulation process, blood changes from a liquid to a solid gel phase. These changes are reflected by changes in blood viscosity; however, blood viscosity at different shear rates (SR) has not been previously explored during the coagulation process. In this study, we investigated the viscosity changes of whole blood in 10 subjects with a normal coagulation profile, using a cone‐on‐plate viscosimeter. For each subject, three consecutive measurements were performed, at a SR of 20, 40, 80 sec−1. On the basis of the time‐dependent changes in blood viscosity, we identified the gel point (GP), the time‐to‐gel point (TGP), the maximum clot viscosity (MCV), and the clot lysis half‐time (CLH). The TGP significantly (P = 0.0023) shortened for increasing SR, and was significantly associated with the activated partial thromboplastin time at a SR of 20 sec−1 (P = 0.038) and 80 sec−1 (P = 0.019). The MCV was significantly lower at a SR of 80 sec−1 versus 40 sec−1 (P = 0.027) and the CLH significantly (P = 0.048) increased for increasing SR. These results demonstrate that measurement of blood viscosity during the coagulation process offers a number of potentially useful parameters. In particular, the association between the TGP and the activated partial thromboplastin time is an expression of the clotting time (intrinsic and common pathway), and its shortening for increasing SR may be interpreted the well‐known activating effects of SR on platelet activation and thrombin generation. Further studies focused on the TGP under conditions of hypo‐ or hypercoagulability are required to confirm its role in the clinical practice. PMID:24994896

  18. Influence of processing conditions on apparent viscosity and system parameters during extrusion of distiller's dried grains-based snacks.

    Science.gov (United States)

    Singha, Poonam; Muthukumarappan, Kasiviswanathan; Krishnan, Padmanaban

    2018-01-01

    A combination of different levels of distillers dried grains processed for food application (FDDG), garbanzo flour and corn grits were chosen as a source of high-protein and high-fiber extruded snacks. A four-factor central composite rotatable design was adopted to study the effect of FDDG level, moisture content of blends, extrusion temperature, and screw speed on the apparent viscosity, mass flow rate or MFR, torque, and specific mechanical energy or SME during the extrusion process. With increase in the extrusion temperature from 100 to 140°C, apparent viscosity, specific mechanical energy, and torque value decreased. Increase in FDDG level resulted in increase in apparent viscosity, SME and torque. FDDG had no significant effect (p > .5) on mass flow rate. SME also increased with increase in the screw speed which could be due to the higher shear rates at higher screw speeds. Screw speed and moisture content had significant negative effect ( p  extruder and the system parameters were affected by the processing conditions. This study will be useful for control of extrusion process of blends containing these ingredients for the development of high-protein high-fiber extruded snacks.

  19. Viscosity, thermal diffusivity and Prandtl number of nanoparticle suspensions

    Institute of Scientific and Technical Information of China (English)

    WANG Buxuan; ZHOU Leping; PENG Xiaofeng

    2004-01-01

    Using our reported experimental data of effective thermal conductivity, specific heat capacity and viscosity for CuO nanoparticle suspensions, the corresponding thermal diffusivity and Prandtl number are calculated. With the hard sphere model and considering effects of particle clustering and surface adsorption, the increase of viscosity for nanoparticle suspension observed is explained. It is shown that the effective thermal conductivity will be strongly affected by the formation and correlated spatial distribution of nanoparticle clusters when compared to viscosity in hosting liquid.

  20. The influence of retention on the plate height in ion-exchange chromatography

    DEFF Research Database (Denmark)

    Hansen, Ernst; Mollerup, Jørgen

    2004-01-01

    The plate heights for the amino acid tyrosine (anion exchange) and the polypeptide aprotinin (cation exchange) were determined on a porous media (Resource 15) and a get filled media (HyperD 20) at salt concentrations ranging from weak to strong retention. At a constant velocity, measurements showed....... In this article, the rate of mass transfer in the particles is described by three different rate mechanisms, pore diffusion, solid diffusion, and parallel diffusion. The van Deemter equation was used to model the data to determine the mass-transfer properties. The development of the plate height with increasing...... retention revealed a characteristic behavior for each rate mechanism. In the pore diffusion model, the plate height increased toward a constant value at strong retention, while the plate height in the solid diffusion model decreased, approaching a constant value at strong retention. In the parallel...

  1. A microfluidic device for simultaneous measurement of viscosity and flow rate of blood in a complex fluidic network.

    Science.gov (United States)

    Jun Kang, Yang; Yeom, Eunseop; Lee, Sang-Joon

    2013-01-01

    Blood viscosity has been considered as one of important biophysical parameters for effectively monitoring variations in physiological and pathological conditions of circulatory disorders. Standard previous methods make it difficult to evaluate variations of blood viscosity under cardiopulmonary bypass procedures or hemodialysis. In this study, we proposed a unique microfluidic device for simultaneously measuring viscosity and flow rate of whole blood circulating in a complex fluidic network including a rat, a reservoir, a pinch valve, and a peristaltic pump. To demonstrate the proposed method, a twin-shaped microfluidic device, which is composed of two half-circular chambers, two side channels with multiple indicating channels, and one bridge channel, was carefully designed. Based on the microfluidic device, three sequential flow controls were applied to identify viscosity and flow rate of blood, with label-free and sensorless detection. The half-circular chamber was employed to achieve mechanical membrane compliance for flow stabilization in the microfluidic device. To quantify the effect of flow stabilization on flow fluctuations, a formula of pulsation index (PI) was analytically derived using a discrete fluidic circuit model. Using the PI formula, the time constant contributed by the half-circular chamber is estimated to be 8 s. Furthermore, flow fluctuations resulting from the peristaltic pumps are completely removed, especially under periodic flow conditions within short periods (T viscosity with respect to varying flow rate conditions [(a) known blood flow rate via a syringe pump, (b) unknown blood flow rate via a peristaltic pump]. As a result, the flow rate and viscosity of blood can be simultaneously measured with satisfactory accuracy. In addition, the proposed method was successfully applied to identify the viscosity of rat blood, which circulates in a complex fluidic network. These observations confirm that the proposed method can be used for

  2. Shear Elasticity and Shear Viscosity Imaging in Soft Tissue

    Science.gov (United States)

    Yang, Yiqun

    In this thesis, a new approach is introduced that provides estimates of shear elasticity and shear viscosity using time-domain measurements of shear waves in viscoelastic media. Simulations of shear wave particle displacements induced by an acoustic radiation force are accelerated significantly by a GPU. The acoustic radiation force is first calculated using the fast near field method (FNM) and the angular spectrum approach (ASA). The shear waves induced by the acoustic radiation force are then simulated in elastic and viscoelastic media using Green's functions. A parallel algorithm is developed to perform these calculations on a GPU, where the shear wave particle displacements at different observation points are calculated in parallel. The resulting speed increase enables rapid evaluation of shear waves at discrete points, in 2D planes, and for push beams with different spatial samplings and for different values of the f-number (f/#). The results of these simulations show that push beams with smaller f/# require a higher spatial sampling rate. The significant amount of acceleration achieved by this approach suggests that shear wave simulations with the Green's function approach are ideally suited for high-performance GPUs. Shear wave elasticity imaging determines the mechanical parameters of soft tissue by analyzing measured shear waves induced by an acoustic radiation force. To estimate the shear elasticity value, the widely used time-of-flight method calculates the correlation between shear wave particle velocities at adjacent lateral observation points. Although this method provides accurate estimates of the shear elasticity in purely elastic media, our experience suggests that the time-of-flight (TOF) method consistently overestimates the shear elasticity values in viscoelastic media because the combined effects of diffraction, attenuation, and dispersion are not considered. To address this problem, we have developed an approach that directly accounts for all

  3. Kinematic viscosity of liquid Al-Cu alloys

    International Nuclear Information System (INIS)

    Konstantinova, N Yu; Popel, P S

    2008-01-01

    Temperature dependences of kinematic viscosity n of liquid Al 100-x -Cu x alloys (x = 0.0, 10.0, 17.1, 25.0, 32.2, 40.0 and 50.0 at.%) were measured. A technique based on registration of the period and the decrement of damping of rotating oscillations of a cylindrical crucible with a melt was used. Viscosity was calculated in low viscous liquids approximation. Measurements were carried out in vacuum in crucibles of BeO with a temperature step of 30 deg. C and isothermal expositions of 10 to 15 minutes during both heating up to 1100-1250 deg. C and subsequent cooling. We have discovered branching of heating and cooling curves v(T) (hysteresis of viscosity) below temperatures depending on the copper content: 950 deg. C at 10 and 17.1 at.% Cu, 1050 deg. C at 25 and 40 at.% Cu, 850 deg. C at 32.2 at.% Cu. For samples with 10 and 17.1 at.% Cu the cooling curve 'returns' to the heating one near 700 deg. C. An abnormally high spreading of results at repeated decrement measurements was fixed at heating of the alloy containing 50 at.% Cu above 1000 deg. C. During subsequent cooling the effect disappeared. Isotherms of kinematic viscosity have been fitted for several temperatures

  4. Effect of Viscosity on Liquid Curtain Stability

    Science.gov (United States)

    Mohammad Karim, Alireza; Suszynski, Wieslaw; Francis, Lorraine; Carvalho, Marcio; Dow Chemical Company Collaboration; PUC Rio Collaboration; University of Minnesota, Twin Cities Collaboration

    2016-11-01

    The effect of viscosity on the stability of Newtonian liquid curtains was explored by high-speed visualization. Glycerol/water solutions with viscosity ranging from 19.1 to 210 mPa.s were used as coating liquids. The experimental set-up used a slide die delivery and steel tube edge guides. The velocity along curtain at different positions was measured by tracking small particles at different flow conditions. The measurements revealed that away from edge guides, velocity is well described by free fall effect. However, close to edge guides, liquid moves slower, revealing formation of a viscous boundary layer. The size of boundary layer and velocity near edge guides are strong function of viscosity. The critical condition was determined by examining flow rate below which curtain broke. Curtain failure was initiated by growth of a hole within liquid curtain, close to edge guides. Visualization results showed that the hole forms in a circular shape then becomes elliptical as it grows faster in vertical direction compared to horizontal direction. As viscosity rises, minimum flow rate for destabilization of curtain increased, indicating connection between interaction with edge guides and curtain stability. We would like to acknowledge the financial support from the Dow Chemical Company.

  5. Study on viscosity measurement using fiber Bragg grating micro-vibration

    International Nuclear Information System (INIS)

    Song, Le; Fang, Fengzhou; Zhao, Jibo

    2013-01-01

    It is now ascertained that traditional electric sensors are vulnerable to electromagnetic interference when measuring viscosity. Here, we propose a new viscosity-sensitive structure based on the fiber Bragg grating (FBG) sensing principle and a micro-vibration measurement method. The symmetric micro-vibration motivation method is also described, and a mathematical model for compensational voltage and fluid viscosity is established. The probe amplitude, which is produced by reciprocating stimulation, is accessible by means of an FBG sensor mounted on an equal-strength beam. Viscosity can be therefore calculated using a demodulation technique based on linear edge filtering with long period grating. After performing a group of verifying tests, the sensor has been subsequently calibrated with a series of standard fluids to determine uncertain parameters in the mathematical model. The results of the experiment show that the relative measurement error was less than 2% when the viscosity ranged from 200 to 500 mPa s. The proposed architecture utilizes the characteristics of anti-interference, fast response speed, high resolution and compact structure of FBG, thereby offering a novel modality to achieve an online viscosity measurement. (paper)

  6. Temperature dependence of bulk viscosity in water using acoustic spectroscopy

    International Nuclear Information System (INIS)

    Holmes, M J; Parker, N G; Povey, M J W

    2011-01-01

    Despite its fundamental role in the dynamics of compressible fluids, bulk viscosity has received little experimental attention and there remains a paucity of measured data. Acoustic spectroscopy provides a robust and accurate approach to measuring this parameter. Working from the Navier-Stokes model of a compressible fluid one can show that the bulk viscosity makes a significant and measurable contribution to the frequency-squared acoustic attenuation. Here we employ this methodology to determine the bulk viscosity of Millipore water over a temperature range of 7 to 50 0 C. The measured attenuation spectra are consistent with the theoretical predictions, while the bulk viscosity of water is found to be approximately three times larger than its shear counterpart, reinforcing its significance in acoustic propagation. Moreover, our results demonstrate that this technique can be readily and generally applied to fluids to accurately determine their temperature dependent bulk viscosities.

  7. Dairy-Based Emulsions: Viscosity Affects Fat Difference Thresholds and Sweetness Perception

    Directory of Open Access Journals (Sweden)

    Susann Zahn

    2013-11-01

    Full Text Available In complex emulsions, viscosity or viscosity-associated sensory attributes such as creaminess are important for quality assessment and product differentiation. Two sets of emulsions with fat or locust bean gum content being varied at seven levels were developed; the two emulsions at each level had similar apparent viscosity. Additionally, sugar concentration was kept constant either with respect to total emulsion, or with respect to the aqueous phase. Series of two-alternative forced choice tests were performed with one constant stimulus, and just noticeable differences were calculated using probability regression. The results show that, when viscosity was not compensated, it was easy for the subjects to (a distinguish emulsions with different fat content when the fat content was addressed in the question, and to (b distinguish emulsions with different fat or locust bean gum content when creaminess was addressed. For the latter descriptor, it is of minor importance whether viscosity is altered by fat content or a thickener. Weber fractions that were calculated for viscosity were approximately 0.20. The quantitative effects of viscosity on sweetness, however, depend on how product rheology was modified.

  8. A Riemann problem with small viscosity and dispersion

    Directory of Open Access Journals (Sweden)

    Kayyunnapara Thomas Joseph

    2006-09-01

    Full Text Available In this paper we prove existence of global solutions to a hyperbolic system in elastodynamics, with small viscosity and dispersion terms and derive estimates uniform in the viscosity-dispersion parameters. By passing to the limit, we prove the existence of solution the Riemann problem for the hyperbolic system with arbitrary Riemann data.

  9. Second viscosity effects in cosmology

    International Nuclear Information System (INIS)

    Potupa, A.S.

    1978-01-01

    The object of the investigation is to draw attention to two important aspects in the choice of a substance model, namely an allowance for the viscosity and behaviour of the metrics at the later stages of cosmological evolution. It is shown that in homogeneous cosmological models taking into account the viscosity there are solutions which realize interpolation between the Fridman and steady-state regimes. In a closed model a solution is obtained which corresponds to the ''curvature compensation'' regime with an unboundedly increasing radius. The problem of compensation of singularity at t → o is discussed as well as the choice of the equations of state for the early (hadron) stages of cosmological evolution in connection with the hydrodynamic theory of multiple hadron production

  10. Radionuclide Retention in Concrete Wasteforms

    Energy Technology Data Exchange (ETDEWEB)

    Wellman, Dawn M.; Jansik, Danielle P.; Golovich, Elizabeth C.; Cordova, Elsa A.

    2012-09-24

    Assessing long-term performance of Category 3 waste cement grouts for radionuclide encasement requires knowledge of the radionuclide-cement interactions and mechanisms of retention (i.e., sorption or precipitation); the mechanism of contaminant release; the significance of contaminant release pathways; how wasteform performance is affected by the full range of environmental conditions within the disposal facility; the process of wasteform aging under conditions that are representative of processes occurring in response to changing environmental conditions within the disposal facility; the effect of wasteform aging on chemical, physical, and radiological properties; and the associated impact on contaminant release. This knowledge will enable accurate prediction of radionuclide fate when the wasteforms come in contact with groundwater. Data collected throughout the course of this work will be used to quantify the efficacy of concrete wasteforms, similar to those used in the disposal of LLW and MLLW, for the immobilization of key radionuclides (i.e., uranium, technetium, and iodine). Data collected will also be used to quantify the physical and chemical properties of the concrete affecting radionuclide retention.

  11. VISCOSITY ANALYSIS OF EMPTY FRUIT BUNCH (EFB BIO-OIL

    Directory of Open Access Journals (Sweden)

    Z.S. Nazirah

    2013-12-01

    Full Text Available Empty fruit bunches (EFB are one of the solid wastes produced by the palm oil industry, which is increasing rapidly. The aim of this paper is to analyse the viscosity of empty fruit bunch (EFB bio-oil that can be extracted from all solid waste EFB as a sample, and a few processes were executed. The samples underwent two processes, which were pre-treatment and pyrolysis. The pre-treatment involved three processes, namely, cutting, shredding and sieving, which were necessary in order to prepare EFB into a particle size suitable for the reactor. After that, the samples were fed into the feedback reactor as feedstock for the pyrolysis process to produce bio-oil. Once the bio-oil was produced, its viscosity was tested using the Brookfield Viscometer in two conditions: before and after the chemical reaction. The bio-oil was treated by adding 10 ml and 20 ml of acetone respectively through the chemical reaction. The viscosity test was carried out at different temperatures, which were 25°C, 30°C, 35°C, 40°C, 45°C and 50°C respectively. The observed viscosity of the EFB bio-oil varied and was higher as the temperature decreased. In addition, the viscosity of the EFB bio-oil was higher when it reacted chemically with the acetone added. Therefore, the results showed that the chemical reaction with acetone has the potential to increase the viscosity of EFB bio-oil.

  12. Calculated viscosity-distance dependence for some actively flowing lavas

    International Nuclear Information System (INIS)

    Pieri, D.

    1987-01-01

    The importance of viscosity as a gauge of the various energy and momentum dissipation regimes of lava flows has been realized for a long time. Nevertheless, despite its central role in lava dynamics and kinematics, it remains among the most difficult of flow physical properties to measure in situ during an eruption. Attempts at reconstructing the actual emplacement viscosities of lava flows from their solidified topographic form are difficult. Where data are available on the position of an advancing flow front as a function of time, it is possible to calculate the effective viscosity of the front as a function of distance from the vent, under the assumptions of a steady state regime. As an application and test of an equation given, relevant parameters from five recent flows on Mauna Loa and Kilauea were utilized to infer the dynamic structure of their aggregate flow front viscosity as they advanced, up to cessation. The observed form of the viscosity-distance relation for the five active Hawaiian flows examined appears to be exponential, with a rapid increase just before the flows stopped as one would expect

  13. Investigation of viscosity of whole hydrolyze sweetened condensed milk

    Directory of Open Access Journals (Sweden)

    O. Kalinina

    2015-05-01

    Full Text Available Introduction. Рaper is aimed at developing of low-lactose (hydrolyzed sweetened condensed milk products technology for lactose intolerant people and for the whole population. Materials and methods: Rheological characteristics were determined on a Reotest device by the 2 nd method of viscometry Results and discussion. Reasonability of ß-galactosidase use for milk lactose hydrolyze during the production of canned products with sugar was proved in the previous works. This technology gives possibility to increase the quality of condensed canned foods, to reduce sugar concentration till 50 %, to increase dietary properties. Due to the reducing of saccharose mass part till 22 and 31 % the products had a liquid consistency that’s why was a necessity to increase the viscosity properties of condensed products. One of method to increase the product viscosity is inoculation of stabilization systems. Reasonability of the usage of stabilization system Bivicioc 1L was proved. The researches of viscosity determination in whole hydrolyzed sweetened condensed milk were shown in the work. Relations of viscosity of whole hydrolyzed condensed milk to the deformation rate were presented. Conclusions Viscosity indices of experimental samples in the fresh produced products and during storage are determined and justified.

  14. The Impact of Waste Loading on Viscosity in the Frit 418-SB3 System

    International Nuclear Information System (INIS)

    PEELER, DAVID

    2004-01-01

    In this report, data are provided to gain insight into the potential impact of a lower viscosity glass on melter stability (i.e., pressure spikes, cold cap behavior) and/or pour stream stability. High temperature viscosity data are generated for the Frit 418-SB3 system as a function of waste loading (from 30 to 45 percent) and compared to similar data from other systems that have been (or are currently being) processed through the Defense Waste Processing Facility (DWPF) melter. The data are presented in various formats to potentially align the viscosity data with physical observations at various points in the melter system or critical DWPF processing unit operations. The expectations is that the data will be provided adequate insight into the vitrification parameters which might evolve into working solutions as DWPF strives to maximize waste throughput. This report attempts to provide insight into a physical interpretation of the data from a DWPF perspective. The theories present ed are certainly not an all inclusive list and the order in which they are present does imply a ranking, probability, or likelihood that the proposed theory is even plausible. The intent of this discussion is to provide a forum in which the viscosity data can be discussed in relation to possible mechanisms which could potentially lead to a workable solution as discussed in relation to possible solution as higher overall attainment is striven for during processing of the current or future sludge batches

  15. A viscosity measurement during the high pressure phase transition in triolein

    International Nuclear Information System (INIS)

    Siegoczynski, R M; Rostocki, A J; Kielczynski, P; Szalewski, M

    2008-01-01

    The high-pressure properties of triolein, a subject of extensive research at the Faculty of Physics of Warsaw University of Technology (WUT) have been enhanced by the results of viscosity measurement within the pressure range up to 0.8 GPa. For the measurement the authors have adopted a new ultrasonic method based on Bleustein-Gulyaev waves, successfully developed earlier for the low pressures in the Section of Acoustoelectronics of the Institute of Fundamental Technological Research. The measurements have shown: 1. Exponential rise of viscosity with pressure up to 0.5 GPa. 2. Extraordinary increment of viscosity at constant pressure during phase transition. 3. Further exponential rise of viscosity with pressure of the high-pressure phase of triolein. 4. The pressure exponents of the viscosity of both phases were different (the high-pressure phase had much smaller exponent). 5. The decomposition of the high pressure phase due to the slow decompression have shown very large hysteresis of viscosity on pressure dependence

  16. Molecular dynamics calculation of shear viscosity for molten salt

    International Nuclear Information System (INIS)

    Okamoto, Yoshihiro; Yokokawa, Mitsuo; Ogawa, Toru

    1993-12-01

    A computer program of molecular dynamics simulation has been made to calculate shear viscosity of molten salt. Correlation function for an off-diagonal component of stress tensor can be obtained as the results of calculation. Shear viscosity is calculated by integration of the correlation function based on the Kubo-type formula. Shear viscosities for a molten KCl ranging in temperature from 1047K to 1273K were calculated using the program. Calculation of 10 5 steps (1 step corresponds to 5 x 10 -15 s) was performed for each temperature in the 216 ions system. The obtained results were in good agreement with the reported experimental values. The program has been vectorized to achieve a faster computation in supercomputer. It makes possible to calculate the viscosity using a large number of statistics amounting to several million MD steps. (author)

  17. Pulsatile flow of blood and heat transfer with variable viscosity under magnetic and vibration environment

    International Nuclear Information System (INIS)

    Shit, G.C.; Majee, Sreeparna

    2015-01-01

    Unsteady flow of blood and heat transfer characteristics in the neighborhood of an overlapping constricted artery have been investigated in the presence of magnetic field and whole body vibration. The laminar flow of blood is taken to be incompressible and Newtonian fluid with variable viscosity depending upon temperature with an aim to provide resemblance to the real situation in the physiological system. The unsteady flow mechanism in the constricted artery is subjected to a pulsatile pressure gradient arising from systematic functioning of the heart and from the periodic body acceleration. The numerical computation has been performed using finite difference method by developing Crank–Nicolson scheme. The results show that the volumetric flow rate, skin-friction and the rate of heat transfer at the wall are significantly altered in the downstream of the constricted region. The axial velocity profile, temperature and flow rate increases with increase in temperature dependent viscosity, while the opposite trend is observed in the case of skin-friction and flow impedance. - Highlights: • We have investigated the pulsatile MHD flow of blood and heat transfer in arteries. • The influence of periodic body acceleration has been taken into account. • The temperature dependent viscosity of blood is considered. • The variable viscosity has an increasing effect on blood flow and heat transfer. • The overall temperature distribution enhances in the presence of magnetic field

  18. Pulsatile flow of blood and heat transfer with variable viscosity under magnetic and vibration environment

    Energy Technology Data Exchange (ETDEWEB)

    Shit, G.C., E-mail: gopal_iitkgp@yahoo.co.in; Majee, Sreeparna

    2015-08-15

    Unsteady flow of blood and heat transfer characteristics in the neighborhood of an overlapping constricted artery have been investigated in the presence of magnetic field and whole body vibration. The laminar flow of blood is taken to be incompressible and Newtonian fluid with variable viscosity depending upon temperature with an aim to provide resemblance to the real situation in the physiological system. The unsteady flow mechanism in the constricted artery is subjected to a pulsatile pressure gradient arising from systematic functioning of the heart and from the periodic body acceleration. The numerical computation has been performed using finite difference method by developing Crank–Nicolson scheme. The results show that the volumetric flow rate, skin-friction and the rate of heat transfer at the wall are significantly altered in the downstream of the constricted region. The axial velocity profile, temperature and flow rate increases with increase in temperature dependent viscosity, while the opposite trend is observed in the case of skin-friction and flow impedance. - Highlights: • We have investigated the pulsatile MHD flow of blood and heat transfer in arteries. • The influence of periodic body acceleration has been taken into account. • The temperature dependent viscosity of blood is considered. • The variable viscosity has an increasing effect on blood flow and heat transfer. • The overall temperature distribution enhances in the presence of magnetic field.

  19. Viscosity of liquids theory, estimation, experiment, and data

    CERN Document Server

    Viswanath, Dabir S; Prasad, Dasika HL; Dutt, Nidamarty VK; Rani, Kalipatnapu Y

    2007-01-01

    Single comprehensive book on viscosity of liquids, as opposed to most of the books in this area which are data books, i.e., a compilation of viscosity data from the literature, where the information is scattered and the description and analysis of the experimental methods and governing theory are not readily available in a single place.

  20. The effect of gasses on the viscosity of dimethyl ether

    DEFF Research Database (Denmark)

    Sivebæk, Ion Marius; Jakobsen, Jørgen

    2008-01-01

    media, but their effect on DME viscosity is unknown. Argon (Ar), nitrogen (NA carbon dioxide (CO2), hydrogen (H-2) and propane (C3H8) have been investigated at pressure levels of 12-15 bar. A Cannon-Manning semi-micro capillary glass viscometer, size 25, enclosed in a cylindrical pressure container......, of glass, submerged completely in a constant temperature bath, has been used. A distinct reduction of efflux times was found only for the gas, CO2. The reduction in efflux time was about 9%. The kinematic viscosity of pure DME was determined to be: 0.188 +/- 0.001 cSt, 25 degrees C. A previously reported...... viscosity of pure DME has been corrected for the surface tension effect. Viscosity determination was initially based on a direct comparison of efflux times of DME with that of distilled water. The calculation gave a revised viscosity of 0.186 +/- 0.002 cSt, 25 degrees C, consistent with the above...

  1. Anomalous intrinsic viscosity of octadecylamine-functionalised carbon nanotubes in suspension.

    Science.gov (United States)

    Donovan, K J; Scott, K

    2013-06-28

    Single walled carbon nanotubes, SWCNTs, are used as a model cylinder of nanoscopic dimensions for testing rheological theories of how addition of cylindrical particles affects the viscosity of a suspension of such particles. Using the rate of growth of the accompanying induced linear dichroism following application of an applied electric field, the dynamics of carbon nanotube alignment is studied in suspensions of octadecylamine functionalised single walled carbon nanotubes, ODA-SWCNTs, in 1,2 dichloroethane. From such measurements the viscosity of the suspension is measured as the concentration of the suspension is varied. While working within the dilute limit the viscosity is found to increase linearly with concentration and the intrinsic viscosity of the suspension is found to be 8000. This anomalously high intrinsic viscosity is compared with the predictions of various models for a rigid cylinder and found to be incompatible with any of the current models. Some suggestions are made as to the way this ODA-SWCNT result may be eventually accommodated within other models.

  2. A note on the mixture viscosity using the Shannak definition

    International Nuclear Information System (INIS)

    Awad, M.M.

    2014-01-01

    Highlights: • A note on the mixture viscosity using the Shannak definition is presented. • The Shannak definition gives μ (2ph) > μ f at low x. • Attention must be taken when using the Shannak definition at low x. - Abstract: In this study, a note on the mixture viscosity using the Shannak definition is presented [Shannak, B. A., 2008. Frictional pressure drop of gas liquid two-phase flow in pipes. Nucl. Eng. Des. 238, 3277–3284]. From his definition of the two-phase Reynolds number (Re (2ph) ), an expression of the two-phase viscosity (μ (2ph) ) is obtained. This expression of the two-phase viscosity (μ (2ph) ) satisfies the following important limiting conditions: i. at x = 0, μ (2ph) = μ f , and at x = 1, μ (2ph) = μ g . This definition of the two-phase viscosity (μ (2ph) ) can be used to compute the two-phase frictional pressure gradient using the homogeneous modeling approach in circular pipes, minichannels and microchannels. By plotting μ (2ph) /μ f versus x for air–water system at atmospheric conditions using the Shannak definition as well as the other most commonly used formulas of the two-phase viscosity (μ (2ph) ) in gas–liquid two-phase flows such as McAdams et al. (1942), Cicchitti et al. (1960), and Awad and Muzychka (2008) (Definition 1, Definition 2, Definition 3, and Definition 4), it is clear that the Shannak definition of the two-phase viscosity gives μ (2ph) > μ f at low x. This is impossible because we must have μ g (2ph) f for 0 < x < 1. Therefore, attention must be taken when using the Shannak definition of the two-phase viscosity at low x

  3. Polymerization Behavior and Mechanical Properties of High-Viscosity Bulk Fill and Low Shrinkage Resin Composites.

    Science.gov (United States)

    Shibasaki, S; Takamizawa, T; Nojiri, K; Imai, A; Tsujimoto, A; Endo, H; Suzuki, S; Suda, S; Barkmeier, W W; Latta, M A; Miyazaki, M

    The present study determined the mechanical properties and volumetric polymerization shrinkage of different categories of resin composite. Three high viscosity bulk fill resin composites were tested: Tetric EvoCeram Bulk Fill (TB, Ivoclar Vivadent), Filtek Bulk Fill posterior restorative (FB, 3M ESPE), and Sonic Fill (SF, Kerr Corp). Two low-shrinkage resin composites, Kalore (KL, GC Corp) and Filtek LS Posterior (LS, 3M ESPE), were used. Three conventional resin composites, Herculite Ultra (HU, Kerr Corp), Estelite ∑ Quick (EQ, Tokuyama Dental), and Filtek Supreme Ultra (SU, 3M ESPE), were used as comparison materials. Following ISO Specification 4049, six specimens for each resin composite were used to determine flexural strength, elastic modulus, and resilience. Volumetric polymerization shrinkage was determined using a water-filled dilatometer. Data were evaluated using analysis of variance followed by Tukey's honestly significant difference test (α=0.05). The flexural strength of the resin composites ranged from 115.4 to 148.1 MPa, the elastic modulus ranged from 5.6 to 13.4 GPa, and the resilience ranged from 0.70 to 1.0 MJ/m 3 . There were significant differences in flexural properties between the materials but no clear outliers. Volumetric changes as a function of time over a duration of 180 seconds depended on the type of resin composite. However, for all the resin composites, apart from LS, volumetric shrinkage began soon after the start of light irradiation, and a rapid decrease in volume during light irradiation followed by a slower decrease was observed. The low shrinkage resin composites KL and LS showed significantly lower volumetric shrinkage than the other tested materials at the measuring point of 180 seconds. In contrast, the three bulk fill resin composites showed higher volumetric change than the other resin composites. The findings from this study provide clinicians with valuable information regarding the mechanical properties and

  4. Comparsion of maximum viscosity and viscometric method for identification of irradiated sweet potato starch

    International Nuclear Information System (INIS)

    Yi, Sang Duk; Yang, Jae Seung

    2000-01-01

    A study was carried out to compare viscosity and maximum viscosity methods for the detection of irradiated sweet potato starch. The viscosity of all samples decreased by increasing stirring speeds and irradiation doses. This trend was similar for maximum viscosity. Regression coefficients and expressions of viscosity and maximum viscosity with increasing irradiation dose were 0.9823 (y=335.02e -0. 3 366x ) at 120 rpm and 0.9939 (y =-42.544x+730.26). This trend in viscosity was similar for all stirring speeds. Parameter A, B and C values showed a dose dependent relation and were a better parameter for detecting irradiation treatment than maximum viscosity and the viscosity value it self. These results suggest that the detection of irradiated sweet potato starch is possible by both the viscometric and maximum visosity method. Therefore, the authors think that the maximum viscosity method can be proposed as one of the new methods to detect the irradiation treatment for sweet potato starch

  5. High-pressure viscosity measurements for the ethanol plus toluene binary system

    DEFF Research Database (Denmark)

    Zeberg-Mikkelsen, Claus Kjær; Baylaucq, A.; Watson, G.

    2005-01-01

    measured with a classical capillary viscometer (Ubbelohde) with an uncertainty of 1%. A total of 209 experimental measurements have been obtained for this binary system, which reveals a non-monotonic behavior of the viscosity as a function of the composition, with a minimum. The viscosity behavior...... interacting system showing a negative deviation from ideality. The viscosity of this binary system is represented by the Grunberg-Nissan and the Katti-Chaudhri mixing laws with an overall uncertainty of 12% and 8%, respectively. The viscosity of methanol (23 point) has also been measured in order to verify...

  6. Bulk viscosity of hot dense Quark matter in the PNJL model

    International Nuclear Information System (INIS)

    Xiao Shisong; Guo Panpan; Zhang Le; Hou Defu

    2014-01-01

    Starting from the Kubo formula and the QCD low energy theorem, we study the the bulk viscosity of hot dense quark matter in the PNJL model from the equation of state. We show that the bulk viscosity has a sharp peak near the chiral phase transition, and that the ratio of bulk viscosity over entropy rises dramatically in the vicinity of the phase transition. These results agree with those from the lattice and other model calculations. In addition, we show that the increase of chemical potential raises the bulk viscosity. (authors)

  7. Do dual-thread orthodontic mini-implants improve bone/tissue mechanical retention?

    Science.gov (United States)

    Lin, Yang-Sung; Chang, Yau-Zen; Yu, Jian-Hong; Lin, Chun-Li

    2014-12-01

    The aim of this study was to understand whether the pitch relationship between micro and macro thread designs with a parametrical relationship in a dual-thread mini-implant can improve primary stability. Three types of mini-implants consisting of single-thread (ST) (0.75 mm pitch in whole length), dual-thread A (DTA) with double-start 0.375 mm pitch, and dual-thread B (DTB) with single-start 0.2 mm pitch in upper 2-mm micro thread region for performing insertion and pull-out testing. Histomorphometric analysis was performed in these specimens in evaluating peri-implant bone defects using a non-contact vision measuring system. The maximum inserted torque (Tmax) in type DTA was found to be the smallest significantly, but corresponding values found no significant difference between ST and DTB. The largest pull-out strength (Fmax) in the DTA mini-implant was found significantly greater than that for the ST mini-implant regardless of implant insertion orientation. Mini-implant engaged the cortical bone well as observed in ST and DTA types. Dual-thread mini-implant with correct micro thread pitch (parametrical relationship with macro thread pitch) in the cortical bone region can improve primary stability and enhanced mechanical retention.

  8. Water retention behaviour of compacted bentonites: experimental observations and constitutive model

    Directory of Open Access Journals (Sweden)

    Dieudonne Anne-Catherine

    2016-01-01

    Full Text Available Bentonite-based materials are studied as potential barriers for the geological disposal of radioactive waste. In this context, the hydro-mechanical behaviour of the engineered barrier is first characterized by free swelling conditions followed by constant volume conditions. This paper presents an experimental study conducted in order to characterize the water retention behaviour of a compacted MX-80 bentonite/sand mixture. Then, based on observations of the material double structure and the water retention mechanisms in compacted bentonites, a new water retention model is proposed. The model considers adsorbed water in the microstructure and capillary water in the aggregate-porosity. The model is calibrated and validated against the experimental data. It is used for better understanding competing effects between volume change and water uptake observed during hydration under free swelling conditions.

  9. Retention behavior of flavonoids on immobilized artificial membrane chromatography and correlation with cell-based permeability.

    Science.gov (United States)

    Tsopelas, Fotios; Tsagkrasouli, Maria; Poursanidis, Pavlos; Pitsaki, Maria; Vasios, George; Danias, Panagiotis; Panderi, Irene; Tsantili-Kakoulidou, Anna; Giaginis, Constantinos

    2018-03-01

    The aim of the study was to investigate the immobilized artificial membrane (IAM) retention mechanism for a set of flavonoids and to evaluate the potential of IAM chromatography to model Caco-2 permeability. For this purpose, the retention behavior of 41 flavonoid analogs on two IAM stationary phases, IAM.PC.MG and IAM.PC.DD2, was investigated. Correlations between retention factors, logk w(IAM) and octanol-water partitioning (logP) were established and the role of hydroxyl groups of flavonoids to the underlying retention mechanism was explored. IAM retention and logP values were used to establish sound linear models with Caco-2 permeability (logP app ) taken from the literature. Both stepwise regression and multivariate analysis confirmed the contribution of hydrogen bond descriptors, as additional parameters in the either logk w(IAM) or logP models. Retention factors on both IAM stationary phases showed comparable performance with n-octanol-water partitioning towards Caco-2 permeability. Copyright © 2017 John Wiley & Sons, Ltd.

  10. The influence of tongue strength on oral viscosity discrimination acuity.

    Science.gov (United States)

    Steele, Catriona M

    2018-06-01

    The ability to generate tongue pressures is widely considered to be critical for liquid bolus propulsion in swallowing. It has been proposed that the application of tongue pressure may also serve the function of collecting sensory information regarding bolus viscosity (resistance to flow). In this study, we explored the impact of age-related reductions in tongue strength on oral viscosity discrimination acuity. The experiment employed a triangle test discrimination protocol with an array of xanthan-gum thickened liquids in the mildly to moderately thick consistency range. A sample of 346 healthy volunteers was recruited, with age ranging from 12 to 86 (164 men, 182 women). On average, participants were able to detect a 0.29-fold increase in xanthan-gum concentration, corresponding to a 0.5-fold increase in viscosity at 50/s. Despite having significantly reduced tongue strength on maximum isometric tongue-palate pressure tasks, and regardless of sex, older participants in this study showed no reductions in viscosity discrimination acuity. In this article, the relationship between tongue strength and the ability to discriminate small differences in liquid viscosity during oral processing is explored. Given that tongue strength declines with age in healthy adults and is also reduced in individuals with dysphagia, it is interesting to determine whether reduced tongue strength might contribute to difficulties in evaluating liquid viscosity during the oral stage of swallowing. Using an array of mildly to moderately thick xanthan-gum thickened liquids, this experiment failed to find any evidence that reductions in tongue strength influence oral viscosity discrimination acuity. © 2017 Wiley Periodicals, Inc.

  11. Prediction of the viscosity of lubricating oil blends at any temperature

    Energy Technology Data Exchange (ETDEWEB)

    Diaz, R.M.; Bernardo, M.I.; Fernandez, A.M.; Folgueras, M.B. [University of Oviedo, Oveido (Spain). Dept. of Energy

    1996-04-01

    This paper discusses a method of predicting the viscosity of multicomponent base lubricating oil mixtures based on Andrade`s equation. The kinematic viscosity of three types of base lubricating oils and their binary and ternary mixtures were measured at different temperatures and the parameters of Andrade`s equation were calculated. The results obtained indicate that the Andrade parameters vary linearly with the mixture composition. From these linear equations, generalized mixing equations are derived which confirm the experimental results. By application of the mixing equations, a simple method is obtained for prediction of the viscosity of oil blends at any temperature from viscosity-temperature data of the oil components. The calculated viscosities gave an average absolute deviation of 10% over the temperature range 20-100{degree}C. 8 refs., 3 figs., 4 tabs.

  12. Strong synergistic effects in PLA/PCL blends: Impact of PLA matrix viscosity.

    Science.gov (United States)

    Ostafinska, Aleksandra; Fortelný, Ivan; Hodan, Jiří; Krejčíková, Sabina; Nevoralová, Martina; Kredatusová, Jana; Kruliš, Zdeněk; Kotek, Jiří; Šlouf, Miroslav

    2017-05-01

    Blends of two biodegradable polymers, poly(lactic acid) (PLA) and poly(ϵ-caprolactone) (PCL), with strong synergistic improvement in mechanical performance were prepared by melt-mixing using the optimized composition (80/20) and the optimized preparation procedure (a melt-mixing followed by a compression molding) according to our previous study. Three different PLA polymers were employed, whose viscosity decreased in the following order: PLC ≈ PLA1 > PLA2 > PLA3. The blends with the highest viscosity matrix (PLA1/PCL) exhibited the smallest PCL particles (d∼0.6μm), an elastic-plastic stable fracture (as determined from instrumented impact testing) and the strongest synergistic improvement in toughness (>16× with respect to pure PLA, exceeding even the toughness of pure PCL). According to the available literature, this was the highest toughness improvement in non-compatiblized PLA/PCL blends ever achieved. The decrease in the matrix viscosity resulted in an increase in the average PCL particle size and a dramatic decrease in the overall toughness: the completely stable fracture (for PLA1/PCL) changed to the stable fracture followed by unstable crack propagation (for PLA2/PCL) and finally to the completely brittle fracture (for PLA3/PCL). The stiffness of all blends remained at well acceptable level, slightly above the theoretical predictions based on the equivalent box model. Despite several previous studies, the results confirmed that PLA and PCL could behave as compatible polymers, but the final PLA/PCL toughness is extremely sensitive to the PCL particle size distribution, which is influenced by both processing conditions and PLA viscosity. PLA/PCL blends with high stiffness (due to PLA) and toughness (due to PCL) are very promising materials for medical applications, namely for the bone tissue engineering. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Friction Reduction Tested for a Downsized Diesel Engine with Low-Viscosity Lubricants Including a Novel Polyalkylene Glycol

    Directory of Open Access Journals (Sweden)

    David E. Sander

    2017-04-01

    Full Text Available With the increasing pressure to reduce emissions, friction reduction is always an up-to-date topic in the automotive industry. Among the various possibilities to reduce mechanical friction, the usage of a low-viscosity lubricant in the engine is one of the most effective and most economic options. Therefore, lubricants of continuously lower viscosity are being developed and offered on the market that promise to reduce engine friction while avoiding deleterious mixed lubrication and wear. In this work, a 1.6 L downsized Diesel engine is used on a highly accurate engine friction test-rig to determine the potential for friction reduction using low viscosity lubricants under realistic operating conditions including high engine loads. In particular, two hydrocarbon-based lubricants, 0W30 and 0W20, are investigated as well as a novel experimental lubricant, which is based on a polyalkylene glycol base stock. Total engine friction is measured for all three lubricants, which show a general 5% advantage for the 0W20 in comparison to the 0W30 lubricant. The polyalkylene glycol-based lubricant, however, shows strongly reduced friction losses, which are about 25% smaller than for the 0W20 lubricant. As the 0W20 and the polyalkylene glycol-based lubricant have the same HTHS-viscosity , the findings contradict the common understanding that the HTHS-viscosity is the dominant driver related to the friction losses.

  14. Experimental viscosity measurements of biodiesels at high pressure

    Directory of Open Access Journals (Sweden)

    Schaschke C.J.

    2016-01-01

    Full Text Available The viscosity of biodiesels of soybean and rapeseed biodiesels blended with mineral diesel fuel were measured at pressures of up to 200 MPa. Using a falling sinker-type viscometer reproducible viscosity data were obtained based on the time taken for a sinker to descend a fixed distance down an enclosed tube under the influence of gravity. Measurements were taken using pressures which correspond to those of interest in automotive common rail diesel engines, and at temperatures of between 25ºC and 80ºC. In all cases, the viscosity of the biodiesel blends were found to increase exponentially for which the blends were noted as being more viscous than pure mineral fuels. A pressure-freezing effect was not observed for the blends.

  15. Temperature Dependence of the Viscosity of Isotropic Liquids

    Science.gov (United States)

    Jadzyn, J.; Czechowski, G.; Lech, T.

    1999-04-01

    Temperature dependence of the shear viscosity measured for isotropic liquids belonging to the three homologous series: 4-(trans-4'-n-alkylcyclohexyl) isothiocyanatobenzenes (Cn H2n+1 CyHx Ph NCS; nCHBT, n=0-12), n-alkylcyanobiphenyls (CnH2n+1 Ph Ph CN; nCB, n=2-12) and 1,n-alkanediols (HO(CH2)nOH; 1,nAD, n=2-10) were analysed with the use of Arrhenius equation and its two modifications: Vogel--Fulcher and proposed in this paper. The extrapolation of the isothermal viscosity of 1,n-alkanediols (n=2-10) to n=1 leads to an interesting conclusion concerning the expected viscosity of methanediol, HOCH2OH, the compound strongly unstable in a pure state.

  16. Nonlinear Eddy Viscosity Models applied to Wind Turbine Wakes

    DEFF Research Database (Denmark)

    Laan, van der, Paul Maarten; Sørensen, Niels N.; Réthoré, Pierre-Elouan

    2013-01-01

    The linear k−ε eddy viscosity model and modified versions of two existing nonlinear eddy viscosity models are applied to single wind turbine wake simulations using a Reynolds Averaged Navier-Stokes code. Results are compared with field wake measurements. The nonlinear models give better results...

  17. Viscosity of diluted suspensions of vegetal particles in water

    Directory of Open Access Journals (Sweden)

    Szydłowska Adriana

    2017-01-01

    Full Text Available Viscosity and rheological behaviour of sewage as well as sludge are essential while designing apparatuses and operations employed in the sewage treatment process and its processing. With reference to these substances, the bio-suspensions samples of three size fractions ((i 150÷212 μm, (ii 106÷150 μm and (iii below106 μm of dry grass in water with solid volume fraction 8%, 10% and 11% were prepared. After twenty four hours prior to their preparation time, the suspension samples underwent rheometeric measurements with the use of a rotational rheometer with coaxial cylinders. On the basis of the obtained results, flow curves were plotted and described with both the power model and Herschel-Bulkley model. Moreover, the viscosity of the studied substances was determined that allowed to conclude that the studied bio-suspensions display features of viscoelastic fluids. The experimentally established viscosity was compared to the calculated one according to Manley and Manson equation, recommended in the literature. It occurred that the measured viscosity values substantially exceed the calculation viscosity values, even by 105 times. The observations suggest that it stems from water imbibition of fibrous vegetal particles, which causes their swelling and decreases the amount of liquid phase in the suspension.

  18. Viscosity of confined two-dimensional Yukawa liquids: A nonequilibrium method

    International Nuclear Information System (INIS)

    Landmann, S.; Kählert, H.; Thomsen, H.; Bonitz, M.

    2015-01-01

    We present a nonequilibrium method that allows one to determine the viscosity of two-dimensional dust clusters in an isotropic confinement. By applying a tangential external force to the outer parts of the cluster (e.g., with lasers), a sheared velocity profile is created. The decay of the angular velocity towards the center of the confinement potential is determined by a balance between internal (viscosity) and external friction (neutral gas damping). The viscosity can then be calculated from a fit of the measured velocity profile to a solution of the Navier-Stokes equation. Langevin dynamics simulations are used to demonstrate the feasibility of the method. We find good agreement of the measured viscosity with previous results for macroscopic Yukawa plasmas

  19. Effect of soft mode on shear viscosity of quark matter

    International Nuclear Information System (INIS)

    Fukutome, Takahiko; Iwasaki, Masaharu

    2008-01-01

    We calculate the shear viscosity of quark matter at finite temperature and density. If we assume that the quark interacts with the soft mode, which is a collective mode of a quark-antiquark pair, the self-energy of the quark is calculated by quasi-particle random phase approximation. It is shown that its imaginary part is large and its mean free path is short. With the use of the Kubo formula, the shear viscosity of quark matter decreases. The Reynolds number of quark matter is estimated to be about 10. As temperature increases, shear viscosity increases gradually for T>200 MeV. Moreover it is shown that the shear viscosity also increases with the chemical potential for μ>200 MeV. (author)

  20. Time evolution of the eddy viscosity in two-dimensional navier-stokes flow

    Science.gov (United States)

    Chaves; Gama

    2000-02-01

    The time evolution of the eddy viscosity associated with an unforced two-dimensional incompressible Navier-Stokes flow is analyzed by direct numerical simulation. The initial condition is such that the eddy viscosity is isotropic and negative. It is shown by concrete examples that the Navier-Stokes dynamics stabilizes negative eddy viscosity effects. In other words, this dynamics moves monotonically the initial negative eddy viscosity to positive values before relaxation due to viscous term occurs.

  1. The assessment of nanofluid in a Von Karman flow with temperature relied viscosity

    Directory of Open Access Journals (Sweden)

    Anum Tanveer

    2018-06-01

    Full Text Available This work endeavor to study the heat and mass transfer viscous nanofluid features in a Von Karman flow invoking the variable viscosity mechanism. Moreover, we have extended our study in view of heat generation and uniform suction effects. The flow triggering non-linear partial differential equations are inscribed in the non-dimensional form by manipulating suitable transformations. The resulting non-linear ordinary differential equations are solved numerically via implicit finite difference scheme in conjecture with the Newton’s linearization scheme afterwards. The sought solutions are plotted graphically to present comparison between MATLAB routine bvp4c and implicit finite difference schemes. Impact of different parameters on the concentration/temperature/velocity profiles are highlighted. Further Nusselt number, skin friction and Sherwood number characteristics are discussed for better exposition. Keywords: Von Karman flow, Variable viscosity, Heat generation, Suction, Nanofluid, Implicit finite difference scheme, Bvp4c

  2. Measuring Shear Viscosity Using Transverse Momentum Correlations in Relativistic Nuclear Collisions

    International Nuclear Information System (INIS)

    Gavin, Sean; Abdel-Aziz, Mohamed

    2006-01-01

    Elliptic flow measurements at the Brookhaven National Laboratory Relativistic Heavy Ion Collider suggest that quark-gluon fluid flows with very little viscosity compared to weak-coupling expectations, challenging theorists to explain why this fluid is so nearly ''perfect.'' It is therefore vital to find quantitative experimental information on the viscosity of the fluid. We propose that measurements of transverse momentum fluctuations can be used to determine the shear viscosity. We use current data to estimate the viscosity-to-entropy ratio in the range from 0.08 to 0.3 and discuss how future measurements can reduce this uncertainty

  3. The viscosity window of the silicate glass foam production

    DEFF Research Database (Denmark)

    Petersen, Rasmus Rosenlund; König, Jakob; Yue, Yuanzheng

    2017-01-01

    which can offer a practical starting point for the optimisation procedure. The melt viscosity might be the most important parameter for controlling the foaming process and the glass foam density. In this work, we attempt to define a viscosity range in which foaming of different glasses results...... in a maximum of foam expansion. The expansion maximum is obtained for different glasses (labware, E-glass, CRT panel, soda-lime-silica) by foaming with CaCO3 at isokom temperature and from literature data. In general, the viscosity window was found to be within 104–106 Pa s when foaming with MnO2 or metal...... carbonates (CaCO3, Na2CO3, MgCO3, SrCO3, dolomite) whereas SiC requires higher temperatures and correspondingly lower viscosities (103.3–104.0 Pa s). These findings can help assessing the implementation of new resources in the glass foam production....

  4. Temperature dependent viscosity of cobalt ferrite / ethylene glycol ferrofluids

    Science.gov (United States)

    Kharat, Prashant B.; Somvanshi, Sandeep B.; Kounsalye, Jitendra S.; Deshmukh, Suraj S.; Khirade, Pankaj P.; Jadhav, K. M.

    2018-04-01

    In the present work, cobalt ferrite / ethylene glycol ferrofluid is prepared in 0 to 1 (in the step of 0.2) volume fraction of cobalt ferrite nanoparticles synthesized by co-precipitation method. The XRD results confirmed the formation of single phase spinel structure. The Raman spectra have been deconvoluted into individual Lorentzian peaks. Cobalt ferrite has cubic spinel structure with Fd3m space group. FT-IR spectra consist of two major absorption bands, first at about 586 cm-1 (υ1) and second at about 392 cm-1 (υ2). These absorption bands confirm the formation of spinel-structured cobalt ferrite. Brookfield DV-III viscometer and programmable temperature-controlled bath was used to study the relationship between viscosity and temperature. Viscosity behavior with respect to temperature has been studied and it is revealed that the viscosity of cobalt ferrite / ethylene glycol ferrofluids increases with an increase in volume fraction of cobalt ferrite. The viscosity of the present ferrofluid was found to decrease with increase in temperature.

  5. Viscosity of komatiite liquid at high pressure and temperature

    Science.gov (United States)

    O Dwyer, L.; Lesher, C. E.; Wang, Y.

    2006-12-01

    The viscosities of komatiite liquids at high pressures and temperatures are being investigated by the in-situ falling sphere technique, using the T-25 multianvil apparatus at the GSECARS 13 ID-D beamline at the Advanced Photon Source, ANL. The refractory and fluid nature of komatiite and other ultramafic liquids relevant to the Earth's deep interior, presents unique challenges for this approach. To reach superliquidus temperatures we use a double reservoir configuration, where marker spheres are placed at the top of both a main melt reservoir and an overlying reservoir containing a more refractory composition. Using this approach, we have successfully measured the viscosity of a komatiite from Gorgona Island (GOR-94-29; MgO - 17.8 wt.%; NBO/T = 1.6) up to 6 GPa and 1900 K. Under isothermal conditions, viscosity increases with pressure, consistent with the depolymerized nature of the komatiite. At 1900 K, viscosity increases from 1.5 (+- 0.3) Pa s at 3.5 GPa to 3.4 (+- 0.3) Pa s at 6 GPa, corresponding to an activation volume of 2.2 cm3/mol. At high pressures, the viscosities of Gorgona Island komatiite melt are an order of magnitude higher than those measured by Liebske et al. (2005, EPSL, v. 240) for peridotite melt (MgO 37.1 wt.%; NBO/T = 2.5), and similar in magnitude to molten diopside (NBO/T = 2) (Reid et al. 2003, PEPI, v. 139). The positive pressure dependence is consistent with the reduction in interatomic space diminishing the free volume of the liquid as it is compressed. Above 6 GPa the free volume reduction may become less important with the production of high-coordinated network formers, as attributed to the reversal of the pressure dependence of viscosity for peridotite melt at ~8.5 GPa and diopside melt at ~10 GPa. Experiments at higher pressures are underway to determine if a similar viscosity maximum occurs for komatiite melt and whether its pressure is greater than 10 GPa, as suggested by the data for peridotite and diopside melts.

  6. Vanishing Shear Viscosity Limit in the Magnetohydrodynamic Equations

    Science.gov (United States)

    Fan, Jishan; Jiang, Song; Nakamura, Gen

    2007-03-01

    We study an initial boundary value problem for the equations of plane magnetohydrodynamic compressible flows, and prove that as the shear viscosity goes to zero, global weak solutions converge to a solution of the original equations with zero shear viscosity. As a by-product, this paper improves the related results obtained by Frid and Shelukhin for the case when the magnetic effect is neglected.

  7. Temperature dependent kinematic viscosity of different types of engine oils

    Directory of Open Access Journals (Sweden)

    Libor Severa

    2009-01-01

    Full Text Available The objective of this study is to measure how the viscosity of engine oil changes with temperature. Six different commercially distributed engine oils (primarily intended for motorcycle engines of 10W–40 viscosity grade have been evaluated. Four of the oils were of synthetic type, two of semi–synthetic type. All oils have been assumed to be Newtonian fluids, thus flow curves have not been determined. Oils have been cooled to below zero temperatures and under controlled temperature regulation, kinematic viscosity (mm2 / s have been measured in the range of −5 °C and +115 °C. Anton Paar digital viscometer with concentric cylinders geometry has been used. In accordance with expected behavior, kinematic viscosity of all oils was decreasing with increasing temperature. Viscosity was found to be independent on oil’s density. Temperature dependence has been modeled using se­ve­ral mathematical models – Vogel equation, Arrhenius equation, polynomial, and Gaussian equation. The best match between experimental and computed data has been achieved for Gaussian equation (R2 = 0.9993. Knowledge of viscosity behavior of an engine oil as a function of its temperature is of great importance, especially when considering running efficiency and performance of combustion engines. Proposed models can be used for description and prediction of rheological behavior of engine oils.

  8. Gravimetric capillary method for kinematic viscosity measurements

    Science.gov (United States)

    Rosenberger, Franz; Iwan, J.; Alexander, D.; Jin, Wei-Qing

    1992-01-01

    A novel version of the capillary method for viscosity measurements of liquids is presented. Viscosity data can be deduced in a straightforward way from mass transfer data obtained by differential weighing during the gravity-induced flow of the liquid between two cylindrical chambers. Tests of this technique with water, carbon tetrachloride, and ethanol suggest that this arrangement provides an accuracy of about +/- 1 percent. The technique facilitates operation under sealed, isothermal conditions and, thus can readily be applied to reactive and/or high vapor pressure liquids.

  9. Extensive Management Promotes Plant and Microbial Nitrogen Retention in Temperate Grassland

    Science.gov (United States)

    de Vries, Franciska T.; Bloem, Jaap; Quirk, Helen; Stevens, Carly J.; Bol, Roland; Bardgett, Richard D.

    2012-01-01

    Leaching losses of nitrogen (N) from soil and atmospheric N deposition have led to widespread changes in plant community and microbial community composition, but our knowledge of the factors that determine ecosystem N retention is limited. A common feature of extensively managed, species-rich grasslands is that they have fungal-dominated microbial communities, which might reduce soil N losses and increase ecosystem N retention, which is pivotal for pollution mitigation and sustainable food production. However, the mechanisms that underpin improved N retention in extensively managed, species-rich grasslands are unclear. We combined a landscape-scale field study and glasshouse experiment to test how grassland management affects plant and soil N retention. Specifically, we hypothesised that extensively managed, species-rich grasslands of high conservation value would have lower N loss and greater N retention than intensively managed, species-poor grasslands, and that this would be due to a greater immobilisation of N by a more fungal-dominated microbial community. In the field study, we found that extensively managed, species-rich grasslands had lower N leaching losses. Soil inorganic N availability decreased with increasing abundance of fungi relative to bacteria, although the best predictor of soil N leaching was the C/N ratio of aboveground plant biomass. In the associated glasshouse experiment we found that retention of added 15N was greater in extensively than in intensively managed grasslands, which was attributed to a combination of greater root uptake and microbial immobilisation of 15N in the former, and that microbial immobilisation increased with increasing biomass and abundance of fungi. These findings show that grassland management affects mechanisms of N retention in soil through changes in root and microbial uptake of N. Moreover, they support the notion that microbial communities might be the key to improved N retention through tightening linkages

  10. Use of the McQuarrie equation for the computation of shear viscosity via equilibrium molecular dynamics

    International Nuclear Information System (INIS)

    Chialvo, A.A.; Debenedetti, P.G.

    1991-01-01

    To date, the calculation of shear viscosity for soft-core fluids via equilibrium molecular dynamics has been done almost exclusively using the Green-Kubo formalism. The alternative mean-squared displacement approach has not been used, except for hard-sphere fluids, in which case the expression proposed by Helfand [Phys. Rev. 119, 1 (1960)] has invariably been selected. When written in the form given by McQuarrie [Statistical Mechanics (Harper ampersand Row, New York, 1976), Chap. 21], however, the mean-squared displacement approach offers significant computational advantages over both its Green-Kubo and Helfand counterparts. In order to achieve comparable statistical significance, the number of experiments needed when using the Green-Kubo or Helfand formalisms is more than an order of magnitude higher than for the McQuarrie expression. For pairwise-additive systems with zero linear momentum, the McQuarrie method yields frame-independent shear viscosities. The hitherto unexplored McQuarrie implementation of the mean-squared displacement approach to shear-viscosity calculation thus appears superior to alternative methods currently in use

  11. Fluctuation expressions for fast thermal transport processes: Vortex viscosity

    International Nuclear Information System (INIS)

    Evans, D.J.; Hanley, H.J.M.

    1982-01-01

    The vortex viscosity of a model diatomic fluid is calculated using both equilibrium and nonequilibrium molecular dynamics. The two calculations agree within statistical uncertainties. The results show that vortex viscosity does not have a conventional Kubo-Green relation. An argument as to why this is so is presented

  12. Effect of viscosity on seismic response of waste storage tanks

    International Nuclear Information System (INIS)

    Tang, Yu; Uras, R.A.; Chang, Yao-Wen.

    1992-06-01

    The dynamic response of liquid-storage tanks subjected to harmonic excitations and earthquake ground motions has been studied. A rigid tank of negligible mass, rigidly supported at the base having a diameter of 50 ft. and fluid height of 20.4 ft. was used in the computer analysis. The liquid is assumed to have a density of 1.5 g/ml. Viscosity values, μ = 60, 200, 100, and 10,000 cP, were used in the numerical analyses to study the effects of viscosity on sloshing wave height, impulsive and convective pressure on the tank wall, base shear and base moments. Harmonic excitations as well as earthquake ground motions were used as input motions. The harmonic excitations used in the analyses covers a wide range of frequencies, including both the resonant and non-resonant frequencies. Two earthquake motions were used. One matches the Newmark-Hall median response spectrum and is anchored at 0.24 g for a rock site with a damping of 2% and a time duration of 10 s. The other is the 1978 Tabas earthquake which had a peak ZPA of 0.81 g and a time duration of 29 s. A small tank, about 1/15 the size of the typical waste storage tank, was used in the harmonic excitation study to investigate the effect of viscosity on the response of liquid-storage tanks and how the viscosity effect is affected by the size of the storage tank. The results of this study show that for the typical waste storage tank subjected to earthquake motions, the effect of viscosity on sloshing wave height and impulsive and convective pressures is very small and can be neglected. For viscosity effect to become noticeable in the response of the typical waste storage tank, the waste viscosity must be greater than 10,000 cP. This value is far greater than the estimated viscosity value of the high level wastes, which may range from 60 to 200 cP for some tanks

  13. Towards adjoint-based inversion of time-dependent mantle convection with nonlinear viscosity

    Science.gov (United States)

    Li, Dunzhu; Gurnis, Michael; Stadler, Georg

    2017-04-01

    We develop and study an adjoint-based inversion method for the simultaneous recovery of initial temperature conditions and viscosity parameters in time-dependent mantle convection from the current mantle temperature and historic plate motion. Based on a realistic rheological model with temperature-dependent and strain-rate-dependent viscosity, we formulate the inversion as a PDE-constrained optimization problem. The objective functional includes the misfit of surface velocity (plate motion) history, the misfit of the current mantle temperature, and a regularization for the uncertain initial condition. The gradient of this functional with respect to the initial temperature and the uncertain viscosity parameters is computed by solving the adjoint of the mantle convection equations. This gradient is used in a pre-conditioned quasi-Newton minimization algorithm. We study the prospects and limitations of the inversion, as well as the computational performance of the method using two synthetic problems, a sinking cylinder and a realistic subduction model. The subduction model is characterized by the migration of a ridge toward a trench whereby both plate motions and subduction evolve. The results demonstrate: (1) for known viscosity parameters, the initial temperature can be well recovered, as in previous initial condition-only inversions where the effective viscosity was given; (2) for known initial temperature, viscosity parameters can be recovered accurately, despite the existence of trade-offs due to ill-conditioning; (3) for the joint inversion of initial condition and viscosity parameters, initial condition and effective viscosity can be reasonably recovered, but the high dimension of the parameter space and the resulting ill-posedness may limit recovery of viscosity parameters.

  14. Coherent oscillatory networks supporting short-term memory retention.

    Science.gov (United States)

    Payne, Lisa; Kounios, John

    2009-01-09

    Accumulating evidence suggests that top-down processes, reflected by frontal-midline theta-band (4-8 Hz) electroencephalogram (EEG) oscillations, strengthen the activation of a memory set during short-term memory (STM) retention. In addition, the amplitude of posterior alpha-band (8-13 Hz) oscillations during STM retention is thought to reflect a mechanism that protects fragile STM activations from interference by gating bottom-up sensory inputs. The present study addressed two important questions about these phenomena. First, why have previous studies not consistently found memory set-size effects on frontal-midline theta? Second, how does posterior alpha participate in STM retention? To answer these questions, large-scale network connectivity during STM retention was examined by computing EEG wavelet coherence during the retention period of a modified Sternberg task using visually-presented letters as stimuli. The results showed (a) increasing theta-band coherence between frontal-midline and left temporal-parietal sites with increasing memory load, and (b) increasing alpha-band coherence between midline parietal and left temporal/parietal sites with increasing memory load. These findings support the view that theta-band coherence, rather than amplitude, is the key factor in selective top-down strengthening of the memory set and demonstrate that posterior alpha-band oscillations associated with sensory gating are involved in STM retention by participating in the STM network.

  15. Competing retention pathways of uranium upon reaction with Fe(II)

    Science.gov (United States)

    Massey, Michael S.; Lezama-Pacheco, Juan S.; Jones, Morris E.; Ilton, Eugene S.; Cerrato, José M.; Bargar, John R.; Fendorf, Scott

    2014-10-01

    Biogeochemical retention processes, including adsorption, reductive precipitation, and incorporation into host minerals, are important in contaminant transport, remediation, and geologic deposition of uranium. Recent work has shown that U can become incorporated into iron (hydr)oxide minerals, with a key pathway arising from Fe(II)-induced transformation of ferrihydrite, (Fe(OH)3·nH2O) to goethite (α-FeO(OH)); this is a possible U retention mechanism in soils and sediments. Several key questions, however, remain unanswered regarding U incorporation into iron (hydr)oxides and this pathway's contribution to U retention, including: (i) the competitiveness of U incorporation versus reduction to U(IV) and subsequent precipitation of UO2; (ii) the oxidation state of incorporated U; (iii) the effects of uranyl aqueous speciation on U incorporation; and, (iv) the mechanism of U incorporation. Here we use a series of batch reactions conducted at pH ∼7, [U(VI)] from 1 to 170 μM, [Fe(II)] from 0 to 3 mM, and [Ca] at 0 or 4 mM coupled with spectroscopic examination of reaction products of Fe(II)-induced ferrihydrite transformation to address these outstanding questions. Uranium retention pathways were identified and quantified using extended X-ray absorption fine structure (EXAFS) spectroscopy, X-ray powder diffraction, X-ray photoelectron spectroscopy, and transmission electron microscopy. Analysis of EXAFS spectra showed that 14-89% of total U was incorporated into goethite, upon reaction with Fe(II) and ferrihydrite. Uranium incorporation was a particularly dominant retention pathway at U concentrations ⩽50 μM when either uranyl-carbonato or calcium-uranyl-carbonato complexes were dominant, accounting for 64-89% of total U. With increasing U(VI) and Fe(II) concentrations, U(VI) reduction to U(IV) became more prevalent, but U incorporation remained a functioning retention pathway. These findings highlight the potential importance of U(V) incorporation within iron

  16. PVT characterization and viscosity modeling and prediction of crude oils

    DEFF Research Database (Denmark)

    Cisneros, Eduardo Salvador P.; Dalberg, Anders; Stenby, Erling Halfdan

    2004-01-01

    In previous works, the general, one-parameter friction theory (f-theory), models have been applied to the accurate viscosity modeling of reservoir fluids. As a base, the f-theory approach requires a compositional characterization procedure for the application of an equation of state (EOS), in most...... pressure, is also presented. The combination of the mass characterization scheme presented in this work and the f-theory, can also deliver accurate viscosity modeling results. Additionally, depending on how extensive the compositional characterization is, the approach,presented in this work may also...... deliver accurate viscosity predictions. The modeling approach presented in this work can deliver accurate viscosity and density modeling and prediction results over wide ranges of reservoir conditions, including the compositional changes induced by recovery processes such as gas injection....

  17. Measurement of viscosity as a means to identify irradiated food

    International Nuclear Information System (INIS)

    Nuernberger, E.; Heide, L.; Boegl, K.W.

    1990-01-01

    The measurement of viscosity is a simple method to identify previous irradiation of some kinds of spices and foods, at least in combination with other methods. A possible change of the soaking capacity was examined up to a storage period of 18 months after irradiation of black pepper, white pepper, cinnamon, ginger and onion powder with a radiation dose of 10 kGy each. After irradiation, either increased or decreased viscosity values were measured; the results showed, also after the 18-months-storage period, considerable differences of the viscosity behaviour in non-irradiated and irradiated samples. The time of storage had no effect to the individual viscosity values, so that this method could also be applied to the examined spices after a longer storage period. (orig.) With 51 figs., 25 tabs [de

  18. Giant Viscosity Enhancement in a Spin-Polarized Fermi Liquid

    International Nuclear Information System (INIS)

    Akimoto, H.; Xia, J. S.; Adams, E. D.; Sullivan, N. S.; Candela, D.; Mullin, W. J.

    2007-01-01

    The viscosity is measured for a Fermi liquid, a dilute 3 He- 4 He mixture, under extremely high magnetic field/temperature conditions (B≤14.8 T, T≥1.5 mK). The spin-splitting energy μB is substantially greater than the Fermi energy k B T F ; as a consequence the polarization tends to unity and s-wave quasiparticle scattering is suppressed for T F . Using a novel composite vibrating-wire viscometer an enhancement of the viscosity is observed by a factor of more than 500 over its low-field value. Good agreement is found between the measured viscosity and theoretical predictions based upon a t-matrix formalism

  19. Effect of Thrombus Composition and Viscosity on Sonoreperfusion Efficacy in a Model of Micro-Vascular Obstruction.

    Science.gov (United States)

    Black, John J; Yu, Francois T H; Schnatz, Rick G; Chen, Xucai; Villanueva, Flordeliza S; Pacella, John J

    2016-09-01

    Distal embolization of micro-thrombi during stenting for myocardial infarction causes micro-vascular obstruction (MVO). We have previously shown that sonoreperfusion (SRP), a microbubble (MB)-mediated ultrasound (US) therapy, resolves MVO from venous micro-thrombi in vitro in saline. However, blood is more viscous than saline, and arterial thrombi that embolize during stenting are mechanically distinct from venous clot. Therefore, we tested the hypothesis that MVO created with arterial micro-thrombi are more resistant to SRP therapy compared with venous micro-thrombi, and higher viscosity further increases the US requirement for effective SRP in an in vitro model of MVO. Lipid MBs suspended in plasma with adjusted viscosity (1.1 cP or 4.0 cP) were passed through tubing bearing a mesh with 40-μm pores to simulate a micro-vascular cross-section; upstream pressure reflected thrombus burden. To simulate MVO, the mesh was occluded with either arterial or venous micro-thrombi to increase upstream pressure to 40 mmHg ± 5 mmHg. Therapeutic long-tone-burst US was delivered to the occluded area for 20 min. MB activity was recorded with a passive cavitation detector. MVO caused by arterial micro-thrombi at either blood or plasma viscosity resulted in less effective SRP therapy compared to venous thrombi. Higher viscosity further reduced the effectiveness of SRP therapy. The passive cavitation detector showed a decrease in inertial cavitation when viscosity was increased, while stable cavitation was affected in a more complex manner. Overall, these data suggest that arterial thrombi may require higher acoustic pressure US than venous thrombi to achieve similar SRP efficacy; increased viscosity decreases SRP efficacy; and both inertial and stable cavitation are implicated in observed SRP efficacy. Copyright © 2016 World Federation for Ultrasound in Medicine & Biology. Published by Elsevier Inc. All rights reserved.

  20. High pressure changes of the castor oil viscosity by ultrasonic method

    International Nuclear Information System (INIS)

    Rostocki, A J; Siegoczynski, R M; Kielczynski, P; Szalewski, M

    2008-01-01

    The pressure change of viscosity of castor oil have been measured by ultrasonic method within the range of pressure up to 0.9 GPa. For the measurement, the authors have applied a new ultrasonic method based on Bleustein-Gulyaev (B-G) waves. For the lower pressures (up to 0.3 GPa) the results have been compared with earlier results obtained by falling body method, whereas for the higher pressure range results were compared with those obtained by the flow type viscometer. The measurements have shown: 1. Exponential rise of viscosity with pressure up to 0.4 GPa according to the Barus formula. 2. Extraordinary increment of viscosity at constant pressure during phase transition. 3. The decomposition of the high pressure phase during the decompression process have shown very large hysteresis of viscosity on pressure. 4. After the decompression process the viscosity lasts higher then a initial value for several hours

  1. Hall viscosity of a chiral two-orbital superconductor at finite temperatures

    Science.gov (United States)

    Yazdani-Hamid, Meghdad; Shahzamanian, Mohammad Ali

    2018-06-01

    The Hall viscosity known as the anti-symmetric part of the viscosity fourth-rank tensor. Such dissipationless response which appears for systems with broken time reversal symmetry. We calculate this non-dissipative quantity for a chiral two-orbital superconductor placed in a viscoelastic magnetic field using the linear response theory and apply our calculations to the putative multiband chiral superconductor Sr2RuO4. The chirality origin of a multiband superconductor arises from the interorbital coupling of the superconducting state. This feature leads to the robustness of the Hall viscosity against temperature and impurity effects. We study the temperature effect on the Hall viscosity at the one-loop approximation.

  2. Measuring Viscosities of Gases at Atmospheric Pressure

    Science.gov (United States)

    Singh, Jag J.; Mall, Gerald H.; Hoshang, Chegini

    1987-01-01

    Variant of general capillary method for measuring viscosities of unknown gases based on use of thermal mass-flowmeter section for direct measurement of pressure drops. In technique, flowmeter serves dual role, providing data for determining volume flow rates and serving as well-characterized capillary-tube section for measurement of differential pressures across it. New method simple, sensitive, and adaptable for absolute or relative viscosity measurements of low-pressure gases. Suited for very complex hydrocarbon mixtures where limitations of classical theory and compositional errors make theoretical calculations less reliable.

  3. Faster in-plane switching and reduced rotational viscosity characteristics in a graphene-nematic suspension

    Science.gov (United States)

    Basu, Rajratan; Kinnamon, Daniel; Skaggs, Nicole; Womack, James

    2016-05-01

    The in-plane switching (IPS) for a nematic liquid crystal (LC) was found to be considerably faster when the LC was doped with dilute concentrations of monolayer graphene flakes. Additional studies revealed that the presence of graphene reduced the rotational viscosity of the LC, permitting the nematic director to respond quicker in IPS mode on turning the electric field on. The studies were carried out with several graphene concentrations in the LC, and the experimental results coherently suggest that there exists an optimal concentration of graphene, allowing a reduction in the IPS response time and rotational viscosity in the LC. Above this optimal graphene concentration, the rotational viscosity was found to increase, and consequently, the LC no longer switched faster in IPS mode. The presence of graphene suspension was also found to decrease the LC's pretilt angle significantly due to the π-π electron stacking between the LC molecules and graphene flakes. To understand the π-π stacking interaction, the anchoring mechanism of the LC on a CVD grown monolayer graphene film on copper substrate was studied by reflected crossed polarized microscopy. Optical microphotographs revealed that the LC alignment direction depended on monolayer graphene's hexagonal crystal structure and its orientation.

  4. Faster in-plane switching and reduced rotational viscosity characteristics in a graphene-nematic suspension

    International Nuclear Information System (INIS)

    Basu, Rajratan; Kinnamon, Daniel; Skaggs, Nicole; Womack, James

    2016-01-01

    The in-plane switching (IPS) for a nematic liquid crystal (LC) was found to be considerably faster when the LC was doped with dilute concentrations of monolayer graphene flakes. Additional studies revealed that the presence of graphene reduced the rotational viscosity of the LC, permitting the nematic director to respond quicker in IPS mode on turning the electric field on. The studies were carried out with several graphene concentrations in the LC, and the experimental results coherently suggest that there exists an optimal concentration of graphene, allowing a reduction in the IPS response time and rotational viscosity in the LC. Above this optimal graphene concentration, the rotational viscosity was found to increase, and consequently, the LC no longer switched faster in IPS mode. The presence of graphene suspension was also found to decrease the LC's pretilt angle significantly due to the π-π electron stacking between the LC molecules and graphene flakes. To understand the π-π stacking interaction, the anchoring mechanism of the LC on a CVD grown monolayer graphene film on copper substrate was studied by reflected crossed polarized microscopy. Optical microphotographs revealed that the LC alignment direction depended on monolayer graphene's hexagonal crystal structure and its orientation.

  5. Faster in-plane switching and reduced rotational viscosity characteristics in a graphene-nematic suspension

    Energy Technology Data Exchange (ETDEWEB)

    Basu, Rajratan, E-mail: basu@usna.edu; Kinnamon, Daniel; Skaggs, Nicole; Womack, James [Soft Matter and Nanomaterials Laboratory, Department of Physics, The United States Naval Academy, Annapolis, Maryland 21402 (United States)

    2016-05-14

    The in-plane switching (IPS) for a nematic liquid crystal (LC) was found to be considerably faster when the LC was doped with dilute concentrations of monolayer graphene flakes. Additional studies revealed that the presence of graphene reduced the rotational viscosity of the LC, permitting the nematic director to respond quicker in IPS mode on turning the electric field on. The studies were carried out with several graphene concentrations in the LC, and the experimental results coherently suggest that there exists an optimal concentration of graphene, allowing a reduction in the IPS response time and rotational viscosity in the LC. Above this optimal graphene concentration, the rotational viscosity was found to increase, and consequently, the LC no longer switched faster in IPS mode. The presence of graphene suspension was also found to decrease the LC's pretilt angle significantly due to the π-π electron stacking between the LC molecules and graphene flakes. To understand the π-π stacking interaction, the anchoring mechanism of the LC on a CVD grown monolayer graphene film on copper substrate was studied by reflected crossed polarized microscopy. Optical microphotographs revealed that the LC alignment direction depended on monolayer graphene's hexagonal crystal structure and its orientation.

  6. A new model for the accurate calculation of natural gas viscosity

    Directory of Open Access Journals (Sweden)

    Xiaohong Yang

    2017-03-01

    Full Text Available Viscosity of natural gas is a basic and important parameter, of theoretical and practical significance in the domain of natural gas recovery, transmission and processing. In order to obtain the accurate viscosity data efficiently at a low cost, a new model and its corresponding functional relation are derived on the basis of the relationship among viscosity, temperature and density derived from the kinetic theory of gases. After the model parameters were optimized using a lot of experimental data, the diagram showing the variation of viscosity along with temperature and density is prepared, showing that: ① the gas viscosity increases with the increase of density as well as the increase of temperature in the low density region; ② the gas viscosity increases with the decrease of temperature in high density region. With this new model, the viscosity of 9 natural gas samples was calculated precisely. The average relative deviation between these calculated values and 1539 experimental data measured at 250–450 K and 0.10–140.0 MPa is less than 1.9%. Compared with the 793 experimental data with a measurement error less than 0.5%, the maximum relative deviation is less than 0.98%. It is concluded that this new model is more advantageous than the previous 8 models in terms of simplicity, accuracy, fast calculation, and direct applicability to the CO2 bearing gas samples.

  7. Effects of plasma viscosity modulation on cardiac function during moderate hemodilution

    Directory of Open Access Journals (Sweden)

    Chatpun Surapong

    2010-01-01

    Full Text Available Background : Previous studies have found that increasing plasma viscosity as whole blood viscosity decrease has beneficial effects in microvascular hemodynamics. As the heart couples with systemic vascular network, changes in plasma and blood viscosity during hemodilution determine vascular pressure drop and flow rate, which influence cardiac function. This study aimed to investigate how changes in plasma viscosity affect on cardiac function during acute isovolemic hemodilution. Materials and Methods: Plasma viscosity was modulated by hemodilution of 40% of blood volume with three different plasma expanders (PEs. Dextran 2000 kDa (Dx2M, 6.3 cP and dextran 70 kDa (Dx70, 3.0 cP were used as high and moderate viscogenic PEs, respectively. Polyethylene glycol conjugated with human serum albumin (PEG-HSA, 2.2 cP was used as low viscogenic PE. The cardiac function was assessed using a miniaturized pressure-volume conductance catheter. Results: After hemodilution, pressure dropped to 84%, 79%, and 78% of baseline for Dx2M, Dx70 and PEG-HSA, respectively. Cardiac output markedly increased for Dx2M and PEG-HSA. Dx2M significantly produced higher stroke work relative to baseline and compared to Dx70. Conclusion: Acute hemodilution with PEG-HSA without increasing plasma viscosity provided beneficial effects on cardiac function compared to Dx70, and similar to those measured with Dx2M. Potentially negative effects of increasing peripheral vascular resistance due to the increase in plasma viscosity were prevented.

  8. ARRHENIUS MODEL FOR HIGH-TEMPERATURE GLASS VISCOSITY WITH A CONSTANT PRE-EXPONENTIAL FACTOR

    International Nuclear Information System (INIS)

    Hrma, Pavel R.

    2008-01-01

    A simplified form of the Arrhenius equation, ln η = A + B(x)/T, where η is the viscosity, T the temperature, x the composition vector, and A and B the Arrhenius coefficients, was fitted to glass-viscosity data for the processing temperature range (the range at which the viscosity is within 1 to 103 Pa.s) while setting A = constant and treating B(x) as a linear function of mass fractions of major components. Fitting the Arrhenius equation to over 550 viscosity data of commercial glasses and approximately 1000 viscosity data of glasses for nuclear-waste glasses resulted in the A values of -11.35 and -11.48, respectively. The R2 value ranged from 0.92 to 0.99 for commercial glasses and was 0.98 for waste glasses. The Arrhenius models estimate viscosities for melts of commercial glasses containing 42 to 84 mass% SiO2 within the temperature range of 1100 to 1550 C and viscosity range of 5 to 400 Pa.s and for waste glasses containing 32 to 60 mass% SiO2 within the temperature range of 850 to 1450 C and viscosity range of 0.4 to 250 Pa.s

  9. Turbulent viscosity optimized by data assimilation

    Directory of Open Access Journals (Sweden)

    Y. Leredde

    Full Text Available As an alternative approach to classical turbulence modelling using a first or second order closure, the data assimilation method of optimal control is applied to estimate a time and space-dependent turbulent viscosity in a three-dimensional oceanic circulation model. The optimal control method, described for a 3-D primitive equation model, involves the minimization of a cost function that quantifies the discrepancies between the simulations and the observations. An iterative algorithm is obtained via the adjoint model resolution. In a first experiment, a k + L model is used to simulate the one-dimensional development of inertial oscillations resulting from a wind stress at the sea surface and with the presence of a halocline. These results are used as synthetic observations to be assimilated. The turbulent viscosity is then recovered without the k + L closure, even with sparse and noisy observations. The problems of controllability and of the dimensions of the control are then discussed. A second experiment consists of a two-dimensional schematic simulation. A 2-D turbulent viscosity field is estimated from data on the initial and final states of a coastal upwelling event.

    Key words. Oceanography: general (numerical modelling · Oceanography: physical (turbulence · diffusion · and mixing processes

  10. Estimation of the viscosities of liquid binary alloys

    Science.gov (United States)

    Wu, Min; Su, Xiang-Yu

    2018-01-01

    As one of the most important physical and chemical properties, viscosity plays a critical role in physics and materials as a key parameter to quantitatively understanding the fluid transport process and reaction kinetics in metallurgical process design. Experimental and theoretical studies on liquid metals are problematic. Today, there are many empirical and semi-empirical models available with which to evaluate the viscosity of liquid metals and alloys. However, the parameter of mixed energy in these models is not easily determined, and most predictive models have been poorly applied. In the present study, a new thermodynamic parameter Δ G is proposed to predict liquid alloy viscosity. The prediction equation depends on basic physical and thermodynamic parameters, namely density, melting temperature, absolute atomic mass, electro-negativity, electron density, molar volume, Pauling radius, and mixing enthalpy. Our results show that the liquid alloy viscosity predicted using the proposed model is closely in line with the experimental values. In addition, if the component radius difference is greater than 0.03 nm at a certain temperature, the atomic size factor has a significant effect on the interaction of the binary liquid metal atoms. The proposed thermodynamic parameter Δ G also facilitates the study of other physical properties of liquid metals.

  11. A viscosity and density meter with a magnetically suspended rotor

    International Nuclear Information System (INIS)

    Bano, Mikulas; Strharsky, Igor; Hrmo, Igor

    2003-01-01

    A device for measuring the viscosity and density of liquids is presented. It is a Couette-type viscometer that uses a submerged rotor to measure the viscosity without errors originating in the contact of the rotor with the sample/air boundary. The inner cylinder is a glass rotor suspended in the liquid, and the outer cylinder is also made of glass. The rotor is stabilized on the axis of the outer cylinder by an electromagnetic force controlled by feedback from the rotor's vertical position. In the lower part of the rotor is an aluminum cylinder located in a magnetic field generated by rotating permanent magnets. The interaction of this rotating magnetic field with eddy currents generated in the aluminum cylinder causes rotation of the rotor. This rotation is optically detected, and viscosity is calculated from the measured angular velocity of rotor. The density of the liquid is calculated from the applied vertical equilibrating force. A computer controls the whole measurement. The device works at constant temperature or while scanning temperature. The sample volume is 1.6 ml, and the accuracy of measurement of both viscosity and density is ∼0.1%. The range of measured densities is (0.7-1.4) g/ml, and viscosity can be measured in the range (3x10 -4 -0.3) Pa s. The shear rate of the viscosity measurement varies in the range (20-300) s-1. The accuracy of the temperature measurement is 0.02 K

  12. Reliable Viscosity Calculation from Equilibrium Molecular Dynamics Simulations: A Time Decomposition Method.

    Science.gov (United States)

    Zhang, Yong; Otani, Akihito; Maginn, Edward J

    2015-08-11

    Equilibrium molecular dynamics is often used in conjunction with a Green-Kubo integral of the pressure tensor autocorrelation function to compute the shear viscosity of fluids. This approach is computationally expensive and is subject to a large amount of variability because the plateau region of the Green-Kubo integral is difficult to identify unambiguously. Here, we propose a time decomposition approach for computing the shear viscosity using the Green-Kubo formalism. Instead of one long trajectory, multiple independent trajectories are run and the Green-Kubo relation is applied to each trajectory. The averaged running integral as a function of time is fit to a double-exponential function with a weighting function derived from the standard deviation of the running integrals. Such a weighting function minimizes the uncertainty of the estimated shear viscosity and provides an objective means of estimating the viscosity. While the formal Green-Kubo integral requires an integration to infinite time, we suggest an integration cutoff time tcut, which can be determined by the relative values of the running integral and the corresponding standard deviation. This approach for computing the shear viscosity can be easily automated and used in computational screening studies where human judgment and intervention in the data analysis are impractical. The method has been applied to the calculation of the shear viscosity of a relatively low-viscosity liquid, ethanol, and relatively high-viscosity ionic liquid, 1-n-butyl-3-methylimidazolium bis(trifluoromethane-sulfonyl)imide ([BMIM][Tf2N]), over a range of temperatures. These test cases show that the method is robust and yields reproducible and reliable shear viscosity values.

  13. Drop splashing: the role of surface wettability and liquid viscosity

    Science.gov (United States)

    Almohammadi, Hamed; Amirfazli, Alidad; -Team

    2017-11-01

    There are seemingly contradictory results in the literature about the role of surface wettability and drop viscosity for the splashing behavior of a drop impacting onto a surface. Motivated by such issues, we conducted a systematic experimental study where splashing behavior for a wide range of the liquid viscosity (1-100 cSt) and surface wettability (hydrophilic to hydrophobic) are examined. The experiments were performed for the liquids with both low and high surface tensions ( 20 and 72 mN/m). We found that the wettability affects the splashing threshold at high or low contact angle values. At the same drop velocity, an increase of the viscosity (up to 4 cSt) promotes the splashing; while, beyond such value, any increase in viscosity shows the opposite effect. It is also found that at a particular combination of liquid surface tension and viscosity (e.g. silicone oil, 10 cSt), an increase in the drop velocity changes the splashing to spreading. We relate such behaviors to the thickness, shape, and the velocity of the drop's lamella. Finally, to predict the splashing, we developed an empirical correlation which covers all of the previous reported data, hence clarifying the ostensible existing contradictions.

  14. The thermo magnetic instability in hot viscose plasmas

    Science.gov (United States)

    Haghani, A.; Khosravi, A.; Khesali, A.

    2017-10-01

    Magnetic Rotational Instability (MRI) can not performed well in accretion disks with strong magnetic field. Studies have indicated a new type of instability called thermomagnetic instability (TMI) in systems where Nernst coefficient and gradient temperature were considered. Nernst coefficient would appear if Boltzman equation could be expanded through ω_{Be} (cyclotron frequency). However, the growth rate of this instability was two magnitude orders below MRI growth (Ωk), which could not act the same as MRI. Therefor, a higher growth rate of unstable modes was needed. In this paper, rotating viscid hot plasma with strong magnetic filed was studied. Firstly, a constant alpha viscosity was studied and then a temperature sensitive viscosity. The results showed that the temperature sensitive viscosity would be able to increase the growth rate of TMI modes significantly, hence capable of acting similar to MRI.

  15. Temperature-dependent viscosities of eutectic Al-Si alloys modified with Sr and P

    Energy Technology Data Exchange (ETDEWEB)

    Song Xigui [Key Laboratory of Liquid Structure and Heredity of Materials, Ministry of Education, Shandong University, Jinan, 250061 (China)], E-mail: sxglm@126.com; Bian Xiufang; Zhang Jingxiang; Zhang Jie [Key Laboratory of Liquid Structure and Heredity of Materials, Ministry of Education, Shandong University, Jinan, 250061 (China)

    2009-06-24

    The viscosities of eutectic Al-12 wt.%Si alloy and those modified with Sr and P were investigated using high-temperature torsional oscillation viscometer. Strontium decreased melt's viscosity, while phosphorus increased viscosity. Both additional level and means of addition affected the variation of viscosity. The activation energy of viscous flow was strengthened after modification, but the influence of modification on the molar volume was perplexing.

  16. Density, viscosity, and saturated vapor pressure of ethyl trifluoroacetate

    International Nuclear Information System (INIS)

    Huang, Zhixian; Jiang, Haiming; Li, Ling; Wang, Hongxing; Qiu, Ting

    2015-01-01

    Highlights: • Density of ethyl trifluoroacetate was measured and its thermal expansion coefficient was determined. • Viscosity of ethyl trifluoroacetate was measured and fitted to the Andrade equation. • Saturated vapor pressure of ethyl trifluoroacetate was reported. • The Clausius–Clapeyron equation was used to calculate the molar evaporation enthalpy of ethyl trifluoroacetate. - Abstract: The properties of ethyl trifluoroacetate (CF 3 COOCH 2 CH 3 ) were measured as a function of temperature: density (278.08 to 322.50) K, viscosity (293.45 to 334.32) K, saturated vapor pressure (293.35 to 335.65) K. The density data were fitted to a quadratic polynomial equation, and the viscosity data were regressed to the Andrade equation. The correlation coefficient (R 2 ) of equations for density and viscosity are 0.9997 and 0.9999, respectively. The correlation between saturated vapor pressures and temperatures was achieved with a maximum absolute relative deviation of 0.142%. In addition, the molar evaporation enthalpy in the range of T = (293.35 to 335.65) K was estimated by the Clausius–Clapeyron equation

  17. Measurement of viscosity of gaseous mixtures at atmospheric pressure

    Science.gov (United States)

    Singh, J. J.; Mall, G. H.; Chegini, H.

    1986-01-01

    Coefficients of viscosity of various types of gas mixtures, including simulated natural-gas samples, have been measured at atmospheric pressure and room temperature using a modified capillary tube method. Pressure drops across the straight capillary tube section of a thermal mass flowmeter were measured for small, well-defined, volume flow rates for the test gases and for standard air. In this configuration, the flowmeter provides the volumetric flow rates as well as a well-characterized capillary section for differential pressure measurements across it. The coefficients of viscosity of the test gases were calculated using the reported value of 185.6 micro P for the viscosity of air. The coefficients of viscosity for the test mixtures were also calculated using Wilke's approximation of the Chapman-Enskog (C-E) theory. The experimental and calculated values for binary mixtures are in agreement within the reported accuracy of Wilke's approximation of the C-E theory. However, the agreement for multicomponent mixtures is less satisfactory, possible because of the limitations of Wilkes's approximation of the classical dilute-gas state model.

  18. Predicting specific gravity and viscosity of biodiesel fuels

    OpenAIRE

    Tesfa, Belachew; Mishra, Rakesh; Gu, Fengshou; Ball, Andrew

    2009-01-01

    Biodiesel is a promising non-toxic and biodegradable alternative fuel in transport sector. Of all the biodiesel properties, specific gravity and viscosity are the most significant for the effects they have on the utilization of biodiesel fuels in unmodified engines. This paper presents models, which have been derived from experimental data, for predicting the specific gravity and dynamic viscosity of biodiesel at various temperatures and fractions. In addition a model has also been developed ...

  19. Radionuclide Retention in Concrete Waste Forms

    Energy Technology Data Exchange (ETDEWEB)

    Mattigod, Shas V.; Bovaird, Chase C.; Wellman, Dawn M.; Wood, Marcus I.

    2010-09-30

    Assessing long-term performance of Category 3 waste cement grouts for radionuclide encasement requires knowledge of the radionuclide-cement interactions and mechanisms of retention (i.e., sorption or precipitation); the mechanism of contaminant release; the significance of contaminant release pathways; how waste form performance is affected by the full range of environmental conditions within the disposal facility; the process of waste form aging under conditions that are representative of processes occurring in response to changing environmental conditions within the disposal facility; the effect of waste form aging on chemical, physical, and radiological properties; and the associated impact on contaminant release. This knowledge will enable accurate prediction of radionuclide fate when the waste forms come in contact with groundwater. The information presented in the report provides data that 1) quantify radionuclide retention within concrete waste form materials similar to those used to encapsulate waste in the Low-Level Waste Burial Grounds (LLBG); 2) measure the effect of concrete waste form properties likely to influence radionuclide migration; and 3) quantify the stability of uranium-bearing solid phases of limited solubility in concrete.

  20. Chebyshev super spectral viscosity method for water hammer analysis

    Directory of Open Access Journals (Sweden)

    Hongyu Chen

    2013-09-01

    Full Text Available In this paper, a new fast and efficient algorithm, Chebyshev super spectral viscosity (SSV method, is introduced to solve the water hammer equations. Compared with standard spectral method, the method's advantage essentially consists in adding a super spectral viscosity to the equations for the high wave numbers of the numerical solution. It can stabilize the numerical oscillation (Gibbs phenomenon and improve the computational efficiency while discontinuities appear in the solution. Results obtained from the Chebyshev super spectral viscosity method exhibit greater consistency with conventional water hammer calculations. It shows that this new numerical method offers an alternative way to investigate the behavior of the water hammer in propellant pipelines.

  1. Improved Intranasal Retentivity and Transnasal Absorption Enhancement by PEGylated Poly-l-ornithine

    Directory of Open Access Journals (Sweden)

    Yusuke Kamiya

    2018-01-01

    Full Text Available We reported that the introduction of polyethylene glycol (PEG to poly-l-ornithine (PLO, which is an homopolymeric basic amino acid having absorption-enhancement ability, prolonged retention time in an in vitro inclined plate test, probably due to an increase in viscosity caused by PEGylation. The aim of the present study is to investigate whether the introduction of PEG chains to PLO improves intranasal retention and transnasal absorption in vivo. We performed intranasal administration experiments using PLO and PEG-PLO with a model drug, fluorescein isothiocyanate dextran (FD-4, in rats under closed and open systems. In the open system, transition of plasma FD-4 concentration after co-administration with unmodified PLO was low, and the area under the plasma concentration-time curve (AUC decreased to about 60% of that in the closed system. In contrast, the AUC after co-administration with PEG-PLO in the open system was about 90% of that in the closed system, and the transition of plasma FD-4 concentration and FD-4 absorption profile were similar to those of the closed system. These findings indicate that introducing PEG chains to homopolymeric basic amino acids (HPBAAs is a very useful method for developing a functional absorption enhancer that can exhibit an efficient in vivo absorption-enhancing effect.

  2. On viscosity measurements of nanofluids in micro and mini tube flow

    International Nuclear Information System (INIS)

    Egan, V M; Walsh, P A; Walsh, E J

    2009-01-01

    This study presents measurements on the relative viscosity of Al 2 O 3 nanofluids, obtained using capillary and rotational viscometers. Suspension volume concentrations between 0.3% and 6.3% were considered and all exhibited Newtonian behaviour. This paper questions previously published data (Jang et al 2007 Appl. Phys. Lett. 91 243112) which show effective viscosity measurements of nanofluids to be strongly dependent on the tube dimension used in a microscale capillary viscometer. Hence, tubes of diameter 337 μm and 1017 μm were employed but no effect on relative viscosity was observed as all measurements compared favourably. Additionally, all viscosity measurements were found to correlate well using classical models when aggregate size was considered in calculating volume concentration.

  3. Variability of Moisture Retention and Hydrophobicity Among Biochars

    Science.gov (United States)

    This research identifies factors and mechanisms that control changes in moisture retention when biochars produced from different feedstocks and under different heat treatment temperatures are mixed with fine sand. While substantial experimental research has been conducted on the ...

  4. Large-scale fabrication of linear low density polyethylene/layered double hydroxides composite films with enhanced heat retention, thermal, mechanical, optical and water vapor barrier properties

    Energy Technology Data Exchange (ETDEWEB)

    Xie, Jiazhuo; Zhang, Kun; Zhao, Qinghua [College of Chemistry and Material Science, Shandong Agricultural University, 61 Daizong Street, Tai' an 271018 (China); Wang, Qingguo, E-mail: wqgyyy@126.com [College of Food Science and Engineering, Shandong Agricultural University, 61 Daizong Street, Tai' an 271018 (China); Xu, Jing, E-mail: jiaxu@sdau.edu.cn [College of Chemistry and Material Science, Shandong Agricultural University, 61 Daizong Street, Tai' an 271018 (China)

    2016-11-15

    Novel LDH intercalated with organic aliphatic long-chain anion was large-scale synthesized innovatively by high-energy ball milling in one pot. The linear low density polyethylene (LLDPE)/layered double hydroxides (LDH) composite films with enhanced heat retention, thermal, mechanical, optical and water vapor barrier properties were fabricated by melt blending and blowing process. FT IR, XRD, SEM results show that LDH particles were dispersed uniformly in the LLDPE composite films. Particularly, LLDPE composite film with 1% LDH exhibited the optimal performance among all the composite films with a 60.36% enhancement in the water vapor barrier property and a 45.73 °C increase in the temperature of maximum mass loss rate compared with pure LLDPE film. Furthermore, the improved infrared absorbance (1180–914 cm{sup −1}) of LLDPE/LDH films revealed the significant enhancement of heat retention. Therefore, this study prompts the application of LLDPE/LDH films as agricultural films with superior heat retention. - Graphical abstract: The fabrication process of LLDPE/LDH composite films. - Highlights: • LDH with basal spacing of 4.07 nm was synthesized by high-energy ball milling. • LLDPE composite films with homogeneous LDH dispersion were fabricated. • The properties of LLDPE/LDH composite films were improved. • LLDPE/LDH composite films show superior heat retention property.

  5. Large-scale fabrication of linear low density polyethylene/layered double hydroxides composite films with enhanced heat retention, thermal, mechanical, optical and water vapor barrier properties

    International Nuclear Information System (INIS)

    Xie, Jiazhuo; Zhang, Kun; Zhao, Qinghua; Wang, Qingguo; Xu, Jing

    2016-01-01

    Novel LDH intercalated with organic aliphatic long-chain anion was large-scale synthesized innovatively by high-energy ball milling in one pot. The linear low density polyethylene (LLDPE)/layered double hydroxides (LDH) composite films with enhanced heat retention, thermal, mechanical, optical and water vapor barrier properties were fabricated by melt blending and blowing process. FT IR, XRD, SEM results show that LDH particles were dispersed uniformly in the LLDPE composite films. Particularly, LLDPE composite film with 1% LDH exhibited the optimal performance among all the composite films with a 60.36% enhancement in the water vapor barrier property and a 45.73 °C increase in the temperature of maximum mass loss rate compared with pure LLDPE film. Furthermore, the improved infrared absorbance (1180–914 cm −1 ) of LLDPE/LDH films revealed the significant enhancement of heat retention. Therefore, this study prompts the application of LLDPE/LDH films as agricultural films with superior heat retention. - Graphical abstract: The fabrication process of LLDPE/LDH composite films. - Highlights: • LDH with basal spacing of 4.07 nm was synthesized by high-energy ball milling. • LLDPE composite films with homogeneous LDH dispersion were fabricated. • The properties of LLDPE/LDH composite films were improved. • LLDPE/LDH composite films show superior heat retention property.

  6. Effect of structure and viscosity of the components on some properties of starch-rich hybrid blends.

    Science.gov (United States)

    Ferreira, Willian H; Carmo, Marwin M I B; Silva, Ana Lúcia N; Andrade, Cristina T

    2015-03-06

    Glycerol-plasticized cornstarch and poly(lactic acid) (PLA) were melt-blended alone and at a constant 70:30 (m/m) composition, in the present of an organoclay. The effect of increasing contents of the organoclay on extruded and compression-molded samples was evaluated by X-ray diffraction (XRD), capillary rheometry, thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and tensile tests. XRD and shear viscosity results obtained for the hybrid components (TPS/organoclay and PLA/organoclay) were correlated with the hybrid blends properties. XRD and TGA results suggested that the organoclay was similarly dispersed within both phases. SEM images revealed improved adhesion between the phases. Shear viscosities results indicated improved compatibilization as the organoclay content was increased. Some of the extruded materials were also submitted to injection molding, and characterized by SEM and by tensile tests. For the extruded and compression-molded samples, improved mechanical properties were obtained for the samples with higher contents of the organoclay. For the injection-molded samples, the mechanical properties seemed to be dependent on the organoclay dispersion. Copyright © 2014 Elsevier Ltd. All rights reserved.

  7. Separate density and viscosity measurements of unknown liquid using quartz crystal microbalance

    Directory of Open Access Journals (Sweden)

    Feng Tan

    2016-09-01

    Full Text Available Aqueous liquids have a wide range of applications in many fields. Basic physical properties like the density and the viscosity have great impacts on the functionalities of a given ionic liquid. For the millions kinds of existing liquids, only a few have been systematically measured with the density and the viscosity using traditional methods. However, these methods are limited to measure the density and the viscosity of an ionic liquid simultaneously especially in processing micro sample volumes. To meet this challenge, we present a new theoretical model and a novel method to separate density and viscosity measurements with single quartz crystal microbalance (QCM in this work. The agreement of experimental results and theocratical calculations shows that the QCM is capable to measure the density and the viscosity of ionic liquids.

  8. Dynamic viscosity study of barley malt and chicory concentrates

    Directory of Open Access Journals (Sweden)

    G. O. Magomedov

    2016-01-01

    Full Text Available The purpose of research is to find optimal conditions for dispersing and subsequent dehydration of liquid food environments in the nozzle spray drying chamber through the study of dynamic changes in viscosity according to temperature, velocities gradients and dry residue content. The objects of study were roasted chicory and malt barley concentrates with dry residue content of 20, 40, 60 and 80%. Research of dynamic viscosity were carried out at the measuring complex based on the rotational viscometer Rheotest II, analog-to-digital converter, module Laurent and a personal computer with a unique software that allows to record in real time (not only on a tape recorder, but also in the form of graphic files the behavior of the viscosity characteristics of concentrates. Registration of changes of dynamic viscosity was carried out at a shear rate gradient from 1,0 с -1 to 27,0 с -1 and the products temperature thermostating : 35, 55, 75˚ C. The research results are presented in the form of graphic dependences of effective viscosity on shear rate and flow curves (dependencies of shear stresses on the velocity gradient, which defined flow regimes, the optimal modes of dispersion concentrates into spray dryer chambers in obtaining of powdered semi-finished products and instanting were found: dry residue content - 40 %, concentrate temperature - 75 ˚C, velocity gradient in the air channel of the nozzle at least 20 c-1

  9. Microfluidic method for measuring viscosity using images from smartphone

    Science.gov (United States)

    Kim, Sooyeong; Kim, Kyung Chun; Yeom, Eunseop

    2018-05-01

    The viscosity of a fluid is the most important characteristic in fluid rheology. Many microfluidic devices have been proposed for easily measuring the fluid viscosity of small samples. A hybrid system consisting of a smartphone and microfluidic device can offer a mobile laboratory for performing a wide range of detection and analysis functions related to healthcare. In this study, a new mobile sensing method based on a microfluidic device was proposed for fluid viscosity measurements. By separately delivering sample and reference fluids into the two inlets of a Y-shaped microfluidic device, an interfacial line is induced at downstream of the device. Because the interfacial width (W) between the sample and reference fluid flows was determined by their pressure ratio, the viscosity (μ) of the sample could be estimated by measuring the interfacial width. To distinguish the interfacial width of a sample, optical images of the flows at downstream of the Y-shaped microfluidic device were acquired using a smartphone. To check the measurement accuracy of the proposed method, the viscosities of glycerol mixtures were compared with those measured by a conventional viscometer. The proposed technique was applied to monitor the variations in blood and oil samples depending on storage or rancidity. We expect that this mobile sensing method based on a microfluidic device could be utilized as a viscometer with significant advantages in terms of mobility, ease-of-operation, and data management.

  10. Modelling of long term nitrogen retention in surface waters

    Science.gov (United States)

    Halbfaß, S.; Gebel, M.; Bürger, S.

    2010-12-01

    In order to derive measures to reduce nutrient loadings into waters in Saxony, we calculated nitrogen inputs with the model STOFFBILANZ on the regional scale. Thereby we have to compare our modelling results to measured loadings at the river basin outlets, considering long term nutrient retention in surface waters. The most important mechanism of nitrogen retention is the denitrification in the contact zone of water and sediment, being controlled by hydraulic and micro-biological processes. Retention capacity is derived on the basis of the nutrient spiralling concept, using water residence time (hydraulic aspect) and time-specific N-uptake by microorganisms (biological aspect). Short time related processes of mobilization and immobilization are neglected, because they are of minor importance for the derivation of measures on the regional scale.

  11. Effective viscosity of dispersions approached by a statistical continuum method

    NARCIS (Netherlands)

    Mellema, J.; Willemse, M.W.M.

    1983-01-01

    The problem of the determination of the effective viscosity of disperse systems (emulsions, suspensions) is considered. On the basis of the formal solution of the equations governing creeping flow in a statistically homogeneous dispersion, the effective viscosity is expressed in a series expansion

  12. Field dependence of magnetic viscosity of CoCrTa in-plane media

    NARCIS (Netherlands)

    Phan le kim, P.L.K.; Lodder, J.C.; Popma, T.J.A.

    1999-01-01

    In this paper we will present a study of magnetic viscosity as a function of applied field of CoCrTa/Cr in-plane media. The viscosity versus applied field curves (viscosity curves) of the samples exhibit a sharp peak at remanence coercivity (Hcr). Their activation volume was found to be close to the

  13. NVP melt/magma viscosity: insight on Mercury lava flows

    Science.gov (United States)

    Rossi, Stefano; Morgavi, Daniele; Namur, Olivier; Vetere, Francesco; Perugini, Diego; Mancinelli, Paolo; Pauselli, Cristina

    2016-04-01

    After more than four years of orbiting Mercury, NASA's MESSENGER spacecraft came to an end in late April 2015. MESSENGER has provided many new and surprising results. This session will again highlight the latest results on Mercury based on MESSENGER observations or updated modelling. The session will further address instrument calibration and science performance both retrospective on MESSENGER and on the ESA/JAXA BepiColombo mission. Papers covering additional themes related to Mercury are also welcomed. Please be aware that this session will be held as a PICO session. This will allow an intensive exchange of expertise and experience between the individual instruments and mission. NVP melt/magma viscosity: insight on Mercury lava flows S. Rossi1, D. Morgavi1, O. Namur2, D. Perugini1, F.Vetere1, P. Mancinelli1 and C. Pauselli1 1 Dipartimento di Fisica e Geologia, Università di Perugia, piazza Università 1, 06123 Perugia, Italy 2 Uni Hannover Institut für Mineralogie, Leibniz Universität Hannover, Callinstraβe 3, 30167 Hannover, Germany In this contribution we report new measurements of viscosity of synthetic komatitic melts, used the behaviour of silicate melts erupted at the surface of Mercury. Composition of Mercurian surface magmas was calculated using the most recent maps produced from MESSENGER XRS data (Weider et al., 2015). We focused on the northern hemisphere (Northern Volcanic Province, NVP, the largest lava flow on Mercury and possibly in the Solar System) for which the spatial resolution of MESSENGER measurements is high and individual maps of Mg/Si, Ca/Si, Al/Si and S/Si were combined. The experimental starting material contains high Na2O content (≈7 wt.%) that strongly influences viscosity. High temperature viscosity measurements were carried out at 1 atm using a concentric cylinder apparatus equipped with an Anton Paar RheolabQC viscometer head at the Department of Physics and Geology (PVRG_lab) at the University of Perugia (Perugia, Italy

  14. Dynamic viscosity versus probe-reported microviscosity of aqueous mixtures of poly(ethylene glycol)

    International Nuclear Information System (INIS)

    Bhanot, Chhavi; Trivedi, Shruti; Gupta, Arti; Pandey, Shubha; Pandey, Siddharth

    2012-01-01

    Highlights: ► Aqueous polymer mixtures, non-toxic media of huge industrial importance, are investigated. ► Bulk viscosity of aqueous. PEG mixtures is shown to vary widely with composition and temperature. ► T-dependent viscosity follows Arrhenius behavior suggesting aqueous PEGs to be Newtonian fluids. ► Microviscosity sensed by a fluorescence ratiometric probe is estimated and correlated with viscosity. ► Microviscosity correlates well with bulk viscosity at higher PEG concentrations. - Abstract: Correlation between the dynamic viscosity (η) and the microviscosity of a hybrid green medium constituted of water and poly(ethylene glycol) (PEG) of average molar mass (200, 400, and 600) g · mol −1 , respectively, is explored over the temperatures range (10 to 90) °C across the complete composition regime. The microviscosity is obtained using a fluorescence probe 1,3-bis-(1-pyrenyl)propane (BPP), which is manifested through the ratio of the monomer-to-intramolecular excimer intensities (I M /I E ). Aqueous PEG mixtures are observed to behave similar to Newtonian fluids as the temperature dependence of dynamic viscosity follows Arrhenius-type behavior. Surprisingly, a simple and convenient linear dependence of ln η with wt% PEG of the mixture is established. The BPP I M /I E is observed, in general, to increase with the bulk dynamic viscosity of the mixture having >10 wt% PEG suggesting a good correlation between the bulk dynamic viscosity and BPP-reported microviscosity when the viscosity of the aqueous PEG mixture is relatively high.

  15. Viscosity estimation utilizing flow velocity field measurements in a rotating magnetized plasma

    International Nuclear Information System (INIS)

    Yoshimura, Shinji; Tanaka, Masayoshi Y.

    2008-01-01

    The importance of viscosity in determining plasma flow structures has been widely recognized. In laboratory plasmas, however, viscosity measurements have been seldom performed so far. In this paper we present and discuss an estimation method of effective plasma kinematic viscosity utilizing flow velocity field measurements. Imposing steady and axisymmetric conditions, we derive the expression for radial flow velocity from the azimuthal component of the ion fluid equation. The expression contains kinematic viscosity, vorticity of azimuthal rotation and its derivative, collision frequency, azimuthal flow velocity and ion cyclotron frequency. Therefore all quantities except the viscosity are given provided that the flow field can be measured. We applied this method to a rotating magnetized argon plasma produced by the Hyper-I device. The flow velocity field measurements were carried out using a directional Langmuir probe installed in a tilting motor drive unit. The inward ion flow in radial direction, which is not driven in collisionless inviscid plasmas, was clearly observed. As a result, we found the anomalous viscosity, the value of which is two orders of magnitude larger than the classical one. (author)

  16. Uni-axial Elongational Viscosity of Linear and Branched polymer melts

    DEFF Research Database (Denmark)

    Hassager, Ole; Nielsen, Jens Kromann; Rasmussen, Henrik Koblitz

    2005-01-01

    About 40 years ago interest in the measurement of elongational viscosity of polymer melts started to grow. Here we present measurements of transient (and steady) uni-axial elongational viscosity, using the FSR, of the following melts: Four narrow MMD polystyrene (PS) samples with weight......-average molar mass Mw in the range of 50k to 390k. Three different bi-disperse samples, mixed from the narrow MMD PS. Two low-density polyethylene (LDPE) melts (Lupolen 1840D and 3020D). A steady-state viscosity was kept for 1-2.5 Hencky strain units in all measurements.The measurements on the bi-disperse PS...... melts have demonstrated that both the transient and steady elongational viscosity is quite sensitive to polydispersity. Bi-disperse PS resembles the behaviour of mono-disperse melts only at elongational rates larger then the inverse of maximal time constant of the smallest molecule. As observed in Boger...

  17. Viscosity-Induced Crossing of the Phantom Barrier

    Directory of Open Access Journals (Sweden)

    Iver Brevik

    2015-09-01

    Full Text Available We show explicitly, by using astrophysical data plus reasonable assumptions for the bulk viscosity in the cosmic fluid, how the magnitude of this viscosity may be high enough to drive the fluid from its position in the quintessence region at present time t = 0 across the barrier w = −1 into the phantom region in the late universe. The phantom barrier is accordingly not a sharp mathematical divide, but rather a fuzzy concept. We also calculate the limiting forms of various thermodynamical quantities, including the rate of entropy production, for a dark energy fluid near the future Big Rip singularity.

  18. Entropy viscosity method for nonlinear conservation laws

    KAUST Repository

    Guermond, Jean-Luc

    2011-05-01

    A new class of high-order numerical methods for approximating nonlinear conservation laws is described (entropy viscosity method). The novelty is that a nonlinear viscosity based on the local size of an entropy production is added to the numerical discretization at hand. This new approach does not use any flux or slope limiters, applies to equations or systems supplemented with one or more entropy inequalities and does not depend on the mesh type and polynomial approximation. Various benchmark problems are solved with finite elements, spectral elements and Fourier series to illustrate the capability of the proposed method. © 2010 Elsevier Inc.

  19. Entropy viscosity method for nonlinear conservation laws

    KAUST Repository

    Guermond, Jean-Luc; Pasquetti, Richard; Popov, Bojan

    2011-01-01

    A new class of high-order numerical methods for approximating nonlinear conservation laws is described (entropy viscosity method). The novelty is that a nonlinear viscosity based on the local size of an entropy production is added to the numerical discretization at hand. This new approach does not use any flux or slope limiters, applies to equations or systems supplemented with one or more entropy inequalities and does not depend on the mesh type and polynomial approximation. Various benchmark problems are solved with finite elements, spectral elements and Fourier series to illustrate the capability of the proposed method. © 2010 Elsevier Inc.

  20. Effects of SOC-dependent electrolyte viscosity on performance of vanadium redox flow batteries

    International Nuclear Information System (INIS)

    Xu, Q.; Zhao, T.S.; Zhang, C.

    2014-01-01

    Highlights: • The correlations of electrolyte viscosity and SOC are obtained. • Effect of SOC-dependent electrolyte viscosity is considered in this model. • This model enables a more realistic simulation of variable distributions. • It provides accurate estimations of pumping work and system efficiency. - Abstract: The viscosity of the electrolyte in vanadium redox flow batteries (VRFBs) varies during charge and discharge as the concentrations of acid and vanadium ions in the electrolyte continuously change with the state of charge (SOC). In previous VRFB models, however, the electrolyte has been treated as a constant-viscosity solution. In this work, a mass-transport and electrochemical model taking account of the effect of SOC-dependent electrolyte viscosity is developed. The comparison between the present model and the model with the constant-viscosity simplification indicates that the consideration of the SOC-dependent electrolyte viscosity enables (i) a more realistic simulation of the distributions of overpotential and current density in the electrodes, and (ii) more accurate estimations of pumping work and the system efficiency of VRFBs

  1. Separation of gold nanorods by viscosity gradient centrifugation

    International Nuclear Information System (INIS)

    Dong, Suli; Wang, Yawei; Li, Xiaogang; Zhang, Qingquan; Liu, Xiaojun; Tu, Yang; Liang, Aiye

    2016-01-01

    Size-uniform gold nanorods (Au-NRs) are used in biosensing, bioimaging, photothermal therapy, drug and gene delivery, and controlled release. Monodisperse Au-NRs are usually obtained by separation steps following their synthesis, and centrifugation is widely used because of the ease of operation, high recovery, and the good availability of equipment. So far, the effect of viscosity on the separation of Au-NRs has not been investigated. We have developed a method for separation of monodisperse Au-NRs that is based on centrifugation in a viscosity gradient. Monodisperse Au-NRs obtained from gold nanoparticles were obtained by centrifugation in viscosity gradient adjusted with poly(2-ethyl-2-oxazoline). Au-NRs in sizes ranging from 25.6 to 26.1 nm in effective radius can be separated 5500 g within 5 min, which appears to be the fastest method for separation of Au-NRs. (author)

  2. Viscosity and attenuation of sound wave in high density deuterium

    International Nuclear Information System (INIS)

    Inoue, Kazuko; Ariyasu, Tomio

    1985-01-01

    The penetration of low frequency sound wave into the fuel deuterium is discussed as for laser fusion. The sound velocity and the attenuation constant due to viscosity are calculated for high density (n = 10 24 -- 10 27 cm -3 , T = 10 -1 -- 10 4 eV) deuterium. The shear viscosity of free electron gas and the bulk viscosity due to ion-ion interaction mainly contribute to the attenuation of sound wave. The sound wave of the frequency below 10 10 Hz can easily penetrate through the compressed fuel deuterium of diameter 1 -- 10 3 μm. (author)

  3. Viscosity calculated in simulations of strongly coupled dusty plasmas with gas friction

    International Nuclear Information System (INIS)

    Feng Yan; Goree, J.; Liu Bin

    2011-01-01

    A two-dimensional strongly coupled dusty plasma is modeled using Langevin and frictionless molecular dynamical simulations. The static viscosity η and the wave-number-dependent viscosity η(k) are calculated from the microscopic shear in the random motion of particles. A recently developed method of calculating the wave-number-dependent viscosity η(k) is validated by comparing the results of η(k) from the two simulations. It is also verified that the Green-Kubo relation can still yield an accurate measure of the static viscosity η in the presence of a modest level of friction as in dusty plasma experiments.

  4. A new model for the accurate calculation of natural gas viscosity

    OpenAIRE

    Xiaohong Yang; Shunxi Zhang; Weiling Zhu

    2017-01-01

    Viscosity of natural gas is a basic and important parameter, of theoretical and practical significance in the domain of natural gas recovery, transmission and processing. In order to obtain the accurate viscosity data efficiently at a low cost, a new model and its corresponding functional relation are derived on the basis of the relationship among viscosity, temperature and density derived from the kinetic theory of gases. After the model parameters were optimized using a lot of experimental ...

  5. Sequence-Specific Model for Peptide Retention Time Prediction in Strong Cation Exchange Chromatography.

    Science.gov (United States)

    Gussakovsky, Daniel; Neustaeter, Haley; Spicer, Victor; Krokhin, Oleg V

    2017-11-07

    The development of a peptide retention prediction model for strong cation exchange (SCX) separation on a Polysulfoethyl A column is reported. Off-line 2D LC-MS/MS analysis (SCX-RPLC) of S. cerevisiae whole cell lysate was used to generate a retention dataset of ∼30 000 peptides, sufficient for identifying the major sequence-specific features of peptide retention mechanisms in SCX. In contrast to RPLC/hydrophilic interaction liquid chromatography (HILIC) separation modes, where retention is driven by hydrophobic/hydrophilic contributions of all individual residues, SCX interactions depend mainly on peptide charge (number of basic residues at acidic pH) and size. An additive model (incorporating the contributions of all 20 residues into the peptide retention) combined with a peptide length correction produces a 0.976 R 2 value prediction accuracy, significantly higher than the additive models for either HILIC or RPLC. Position-dependent effects on peptide retention for different residues were driven by the spatial orientation of tryptic peptides upon interaction with the negatively charged surface functional groups. The positively charged N-termini serve as a primary point of interaction. For example, basic residues (Arg, His, Lys) increase peptide retention when located closer to the N-terminus. We also found that hydrophobic interactions, which could lead to a mixed-mode separation mechanism, are largely suppressed at 20-30% of acetonitrile in the eluent. The accuracy of the final Sequence-Specific Retention Calculator (SSRCalc) SCX model (∼0.99 R 2 value) exceeds all previously reported predictors for peptide LC separations. This also provides a solid platform for method development in 2D LC-MS protocols in proteomics and peptide retention prediction filtering of false positive identifications.

  6. A Comparison of the Viscosities of Thickened Liquids for Pediatric Dysphagia.

    Science.gov (United States)

    Wijesinghe, Ranjith; Clifton, Mekale; Tarlton, Morgan; Heinsohn, Erica; Ewing, Mary

    It has been reported that Speech Language Pathologists in different facilities across the nation use a variety of thickening agents and recipes as therapeutic measures for infants and children diagnosed with dysphagia. Limited research has been completed in this area. Viscosity was tested to determine the thickness of each thickening agent mixed with infant formula. The values were then compared to the National Dysphagia Diet liquid levels to determine which thickening agent resulted in the desired viscosity levels. The thickeners were mixed with common infant formulas and soy formulas to determine if the type of formula impacted the viscosity. The main goal was to determine if the assumed thickness level (viscosity) of prescribed thickened liquids was actually being met. This topic is of high concern because of its impact on the safety and well-being of clients with dysphagia. A viscometer was used to collect the viscosity levels. Commercially available formulas selected for this study. The final results of our investigation will be presented during the APS meeting. This work is supported by a Ball State University Immersive Learning Grant.

  7. Viscosity Prediction of Hydrocarbon Mixtures Based on the Friction Theory

    DEFF Research Database (Denmark)

    Zeberg-Mikkelsen, Claus Kjær; Cisneros, Sergio; Stenby, Erling Halfdan

    2001-01-01

    The application and capability of the friction theory (f-theory) for viscosity predictions of hydrocarbon fluids is further illustrated by predicting the viscosity of binary and ternary liquid mixtures composed of n-alkanes ranging from n-pentane to n-decane for wide ranges of temperature and from...

  8. Viscosity and density models for copper electrorefining electrolytes

    OpenAIRE

    Kalliomäki Taina; Aji Arif T.; Aromaa Jari; Lundström Mari

    2016-01-01

    Viscosity and density are highly important physicochemical properties of copper electrolyte since they affect the purity of cathode copper and energy consumption [1, 2] affecting the mass and heat transfer conditions in the cell [3]. Increasing viscosity and density decreases the rate in which the anode slime falls to the bottom of the cell [4, 5] and lowers the diffusion coefficient of cupric ion (DCu2+) [6]. Decreasing the falling rate of anode slime increases movement of the slime to other...

  9. Sensitivity of viscosity Arrhenius parameters to polarity of liquids

    Science.gov (United States)

    Kacem, R. B. H.; Alzamel, N. O.; Ouerfelli, N.

    2017-09-01

    Several empirical and semi-empirical equations have been proposed in the literature to estimate the liquid viscosity upon temperature. In this context, this paper aims to study the effect of polarity of liquids on the modeling of the viscosity-temperature dependence, considering particularly the Arrhenius type equations. To achieve this purpose, the solvents are classified into three groups: nonpolar, borderline polar and polar solvents. Based on adequate statistical tests, we found that there is strong evidence that the polarity of solvents affects significantly the distribution of the Arrhenius-type equation parameters and consequently the modeling of the viscosity-temperature dependence. Thus, specific estimated values of parameters for each group of liquids are proposed in this paper. In addition, the comparison of the accuracy of approximation with and without classification of liquids, using the Wilcoxon signed-rank test, shows a significant discrepancy of the borderline polar solvents. For that, we suggested in this paper new specific coefficient values of the simplified Arrhenius-type equation for better estimation accuracy. This result is important given that the accuracy in the estimation of the viscosity-temperature dependence may affect considerably the design and the optimization of several industrial processes.

  10. On the measurement of the relative viscosity of suspensions

    International Nuclear Information System (INIS)

    Acrivos, A.; Fan, X.; Mauri, R.

    1994-01-01

    The relative viscosity of a suspension of rigid, noncolloidal particles immersed in a Newtonian fluid was measured in a Couette device and was found to be shear thinning even for values of the solids fraction as low as 20%. Although such behavior was reported previously, no satisfactory explanation appears to have been given thus far. It shall be shown presently, however, that, at least for our systems, this shear-thinning effect was due to a slight mismatch in the densities of the two phases. Moreover, the apparent relative viscosities measured in our apparatus were found to be in excellent agreement with those predicted theoretically using a model, originally proposed by Leighton and Acrivos [Chem. Eng. Sci. 41, 1377--1384 (1986)], to describe viscous resuspension, according to which the measured relative viscosity should depend on the bulk particle concentration and on the dimensionless Shields number A, and should attain its correct value for a well-mixed suspension only as A→∞. The predictions of this model are also in excellent agreement with the measured transient response of the apparent relative viscosity due to a sudden change in the shear rate

  11. Microcantilever based disposable viscosity sensor for serum and blood plasma measurements.

    Science.gov (United States)

    Cakmak, Onur; Elbuken, Caglar; Ermek, Erhan; Mostafazadeh, Aref; Baris, Ibrahim; Erdem Alaca, B; Kavakli, Ibrahim Halil; Urey, Hakan

    2013-10-01

    This paper proposes a novel method for measuring blood plasma and serum viscosity with a microcantilever-based MEMS sensor. MEMS cantilevers are made of electroplated nickel and actuated remotely with magnetic field using an electro-coil. Real-time monitoring of cantilever resonant frequency is performed remotely using diffraction gratings fabricated at the tip of the dynamic cantilevers. Only few nanometer cantilever deflection is sufficient due to interferometric sensitivity of the readout. The resonant frequency of the cantilever is tracked with a phase lock loop (PLL) control circuit. The viscosities of liquid samples are obtained through the measurement of the cantilever's frequency change with respect to a reference measurement taken within a liquid of known viscosity. We performed measurements with glycerol solutions at different temperatures and validated the repeatability of the system by comparing with a reference commercial viscometer. Experimental results are compared with the theoretical predictions based on Sader's theory and agreed reasonably well. Afterwards viscosities of different Fetal Bovine Serum and Bovine Serum Albumin mixtures are measured both at 23°C and 37°C, body temperature. Finally the viscosities of human blood plasma samples taken from healthy donors are measured. The proposed method is capable of measuring viscosities from 0.86 cP to 3.02 cP, which covers human blood plasma viscosity range, with a resolution better than 0.04 cP. The sample volume requirement is less than 150 μl and can be reduced significantly with optimized cartridge design. Both the actuation and sensing are carried out remotely, which allows for disposable sensor cartridges. Copyright © 2013. Published by Elsevier Inc.

  12. Modified free volume theory of self-diffusion and molecular theory of shear viscosity of liquid carbon dioxide.

    Science.gov (United States)

    Nasrabad, Afshin Eskandari; Laghaei, Rozita; Eu, Byung Chan

    2005-04-28

    In previous work on the density fluctuation theory of transport coefficients of liquids, it was necessary to use empirical self-diffusion coefficients to calculate the transport coefficients (e.g., shear viscosity of carbon dioxide). In this work, the necessity of empirical input of the self-diffusion coefficients in the calculation of shear viscosity is removed, and the theory is thus made a self-contained molecular theory of transport coefficients of liquids, albeit it contains an empirical parameter in the subcritical regime. The required self-diffusion coefficients of liquid carbon dioxide are calculated by using the modified free volume theory for which the generic van der Waals equation of state and Monte Carlo simulations are combined to accurately compute the mean free volume by means of statistical mechanics. They have been computed as a function of density along four different isotherms and isobars. A Lennard-Jones site-site interaction potential was used to model the molecular carbon dioxide interaction. The density and temperature dependence of the theoretical self-diffusion coefficients are shown to be in excellent agreement with experimental data when the minimum critical free volume is identified with the molecular volume. The self-diffusion coefficients thus computed are then used to compute the density and temperature dependence of the shear viscosity of liquid carbon dioxide by employing the density fluctuation theory formula for shear viscosity as reported in an earlier paper (J. Chem. Phys. 2000, 112, 7118). The theoretical shear viscosity is shown to be robust and yields excellent density and temperature dependence for carbon dioxide. The pair correlation function appearing in the theory has been computed by Monte Carlo simulations.

  13. Glucocorticoid receptors and extinction retention deficits in the single prolonged stress model.

    Science.gov (United States)

    Knox, D; Nault, T; Henderson, C; Liberzon, I

    2012-10-25

    Single prolonged stress (SPS) is a rodent model of post traumatic stress disorder that is comprised of serial application of restraint (r), forced swim (fs), and ether (eth) followed by a 7-day quiescent period. SPS induces extinction retention deficits and it is believed that these deficits are caused by the combined stressful effect of serial exposure to r, fs, and eth. However, this hypothesis remains untested. Neurobiological mechanisms by which SPS induces extinction retention deficits are unknown, but SPS enhances glucocorticoid receptor (GR) expression in the hippocampus, which is critical for contextual modulation of extinction retrieval. Upregulation of GRs in extinction circuits may be a mechanism by which SPS induces extinction retention deficits, but this hypothesis has not been examined. In this study, we systematically altered the stressors that constitute SPS (i.e. r, fs, eth), generating a number of partial SPS (p-SPS) groups, and observed the effects SPS and p-SPSs had on extinction retention and GR levels in the hippocampus and prefrontal cortex (PFC). PFC GRs were assayed, because regions of the PFC are critical for maintaining extinction. We predicted that only exposure to full SPS would result in extinction retention deficits and enhance hippocampal and PFC GR levels. Only exposure to full SPS induced extinction retention deficits. Hippocampal and PFC GR expression was enhanced by SPS and most p-SPSs, however hippocampal GR expression was significantly larger following the full SPS exposure than all other conditions. Our findings suggest that the combined stressful effect of serial exposure to r, fs, and eth results in extinction retention deficits. The results also suggest that simple enhancements in GR expression in the hippocampus and PFC are insufficient to result in extinction retention deficits, but raise the possibility that a threshold-enhancement in hippocampal GR expression contributes to SPS-induced extinction retention deficits

  14. Pressure Dependence of Komatiite Liquid Viscosity and Implications for Magma Ocean Rheology

    Science.gov (United States)

    O'Dwyer Brown, L.; Lesher, C. E.; Terasaki, H. G.; Yamada, A.; Sakamaki, T.; Shibazaki, Y.; Ohtani, E.

    2009-12-01

    The viscosities of komatiite liquids at high pressures and temperatures were investigated using the in-situ falling sphere technique at BL04B1, SPring-8. Komatiites are naturally occurring magmas, rich in network modifying cations. Despite the refractory and fluid nature of komatiite, we successfully measured the viscosity of molten komatiites from Gorgona Island, Colombia (MgO = 17.8 wt.%; NBO/T = 1.5) between 11 and 13 GPa at 2000 C, and from Belingwe, Zimbabwe (MgO = 28.14 wt.%; NBO/T = 2.1) from 12 to 14 GPa at 2000 C. Under isothermal conditions, the viscosity of Gorgona Island komatiite melt increased with pressure, consistent with our previous measurements at lower pressures for this composition. We interpreted this positive pressure dependence as the result of reductions in interatomic space diminishing the free volume of the liquid when compressed. The viscosity of molten komatiite from Belingwe also increased up to 12 GPa, however between 12 and 14 GPa the viscosity is nearly constant. In previous studies of depolymerized silicate liquids, the pressure dependence of viscosity has been shown to reverse from positive to negative between 8 and 10 GPa with corresponding changes in activation volume [1] [2]. In contrast, the activation volume for Belingwe liquid decreases to near zero, but does not become negative above 11 GPa. Similarly, the activation volume for Gorgona Island komatiite remains positive throughout the pressure range investigated. Molecular dynamics simulations of simple MgO-SiO2 liquids with NBO/T > 2 also show a positive pressure dependence, reflecting the dominant control of free-volume reduction on the viscosity of depolymerized melts. However, the more rapid reduction in activation volume with pressure in komatiite liquids may be related to the presence of Al, Ti and other cations that interact and undergo coordination changes unavailable in simple silicate liquids. Along Hadean and post-Hadean mantle adiabats the net effect of

  15. The influence of magma viscosity on convection within a magma chamber

    Science.gov (United States)

    Schubert, M.; Driesner, T.; Ulmer, P.

    2012-12-01

    Magmatic-hydrothermal ore deposits are the most important sources of metals like Cu, Mo, W and Sn and a major resource for Au. It is well accepted that they are formed by the release of magmatic fluids from a batholith-sized magma body. Traditionally, it has been assumed that crystallization-induced volatile saturation (called "second boiling") is the main mechanism for fluid release, typically operating over thousands to tens of thousands of years (Candela, 1991). From an analysis of alteration halo geometries caused by magmatic fluids, Cathles and Shannon (2007) suggested much shorter timescales in the order of hundreds of years. Such rapid release of fluids cannot be explained by second boiling as the rate of solidification scales with the slow conduction of heat away from the system. However, rapid fluid release is possible if convection is assumed within the magma chamber. The magma would degas in the upper part of the magma chamber and volatile poor magma would sink down again. Such, the rates of degassing can be much higher than due to cooling only. We developed a convection model using Navier-Stokes equations provided by the computational fluid dynamics platform OpenFOAM that gives the possibility to use externally derived meshes with complex (natural) geometries. We implemented a temperature, pressure, composition and crystal fraction dependent viscosity (Ardia et al., 2008; Giordano et al., 2008; Moore et al., 1998) and a temperature, pressure, composition dependent density (Lange1994). We found that the new viscosity and density models strongly affect convection within the magma chamber. The dependence of viscosity on crystal fraction has a particularly strong effect as the steep viscosity increase at the critical crystal fraction leads to steep decrease of convection velocity. As the magma chamber is cooling from outside to inside a purely conductive layer is developing along the edges of the magma chamber. Convection continues in the inner part of the

  16. Viscosity of egg white from hens of different strains fed with commercial and natural additives

    Directory of Open Access Journals (Sweden)

    Fernanda Papa Spada

    2012-03-01

    Full Text Available Yolk color and egg white (albumen cleanliness and viscosity are important parameters by which consumers judge the quality of eggs. This study aimed to investigate changes in albumen viscosity during storage of eggs for up to 36 days from two different commercial laying hen strains (Carijo Barbada and Isa Brown fed a diet containing annatto (1.5 and 2.0% or a synthetic additive without synthetic colorants (control. Analyses of humidity, albumen height, pH, viscosity, foam formation, and stability were carried out on eggs. Carijo Barbada strain had smaller albumen, lower humidity and higher egg white viscosity than Isa Brown strain; however, with storage, viscosity lowered significantly on both strains. Initially, the addition of 2.0% of annatto or a synthetic additive increased viscosity in both strains, but with storage only the control maintained longer viscosity. Lower viscosity did not change foam density and stability.

  17. Variation of velocity profile according to blood viscosity in a microfluidic channel

    Science.gov (United States)

    Yeom, Eunseop; Kang, Yang Jun; Lee, Sang-Joon

    2014-11-01

    The shear-thinning effect of blood flows is known to change blood viscosity. Since blood viscosity and motion of red blood cells (RBCs) are closely related, hemorheological variations have a strong influence on hemodynamic characteristics. Therefore, understanding on the relationship between the hemorheological and hemodynamic properties is importance for getting more detailed information on blood circulation in microvessels. In this study, the blood viscosity and velocity profiles in a microfluidic channel were systematically investigated. Rat blood was delivered in the microfluidic device which can measure blood viscosity by monitoring the flow-switching phenomenon. Velocity profiles of blood flows in the microchannel were measured by using a micro-particle image velocimetry (PIV) technique. Shape of velocity profiles measured at different flow rates was quantified by using a curve-fitting equation. It was observed that the shape of velocity profiles is highly correlated with blood viscosity. The study on the relation between blood viscosity and velocity profile would be helpful to understand the roles of hemorheological and hemodynamic properties in cardiovascular diseases. This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea Government (MSIP) (No. 2008-0061991).

  18. Proceedings of the Workshop on in-vessel core debris retention and coolability

    International Nuclear Information System (INIS)

    1999-01-01

    This conference on in-vessel core debris retention and coolability is composed of 37 papers grouped in three sessions: session 1 (Keynote papers: Key phenomena of late phase core melt progression, accident management strategies and status quo of severe fuel damage codes, In-vessel retention as a severe accident management scheme, GAREC analyses in support of in-vessel retention concept, Latest findings of RASPLAV project); session 2 - Experiments and model development with five sub-sessions: sub-session 1 (Debris bed heat transfer: Debris and Pool Formation/Heat Transfer in FARO-LWR: Experiments and Analyses, Evaporation and Flow of Coolant at the Bottom of a Particle-Bed modelling Relocated Debris, Investigations on the Coolability of Debris in the Lower Head with WABE-2D and MESOCO-2D, Uncertainty and Sensitivity Analysis of the Heat Transfer Mechanisms in the Lower Head, Simulation of the Arrival and Evolution of Debris in a PWR Lower Head with the SFD ICARE2 code), sub-session 2 (Corium properties, molten pool natural convection, and crust formation: Physico-chemistry and corium properties for in-vessel retention, Experimental data on heat flux distribution from volumetrically heated pool with frozen boundaries, Thermal hydraulic phenomena in corium pools - numerical simulation with TOLBIAC and experimental validation with BALI, TOLBIAC code simulations of some molten salt RASPLAV experiments, SIMECO experiments on in-vessel melt pool formation and heat transfer with and without a metallic layer, Numerical investigation of turbulent natural convection heat transfer in an internally-heated melt pool and metallic layer, Current status and validation of CON2D and 3D code, Free convection of heat-generating fluid in a constrained during experimental simulation of heat transfer in slice geometry), sub-session 3 (Gap formation and gap cooling: Quench of molten aluminum oxide associated with in-vessel debris retention by RPV internal water, Experimental investigations

  19. Sweetness and other sensory properties of model fruit drinks: Does viscosity have an impact?

    Science.gov (United States)

    Brandenstein, Cai V S; Busch-Stockfisch, Mechthild; Fischer, Markus

    2015-03-15

    The impact of thickening agents and viscosity levels on sensory perception was studied in model fruit drinks. Four formulations were prepared that varied in the sweetener blend (erythritol, maltitol and/or steviol glycosides). Locust bean gum and its blends with either xanthan or carrageenan were used to adjust viscosity levels (20, 40, and 70 mPa s). The ranges of viscosity and sweetness level were selected to represent a typical concentration range in commercially available beverages. An increase in viscosity resulted in significant increases in pulpiness, sliminess and perceived viscosity (P-values ≤ 0.001), which were not dependent on sweeteners or hydrocolloid type. Taste perception remained largely unchanged irrespective of the hydrocolloid used. The impact of viscosity on sweetness and taste perception was much smaller in the concentrations used than has been generally reported. The effect of the type of hydrocolloid on the perception of taste attributes was greater than that of viscosity. © 2014 Society of Chemical Industry.

  20. Shear viscosity, cavitation and hydrodynamics at LHC

    International Nuclear Information System (INIS)

    Bhatt, Jitesh R.; Mishra, Hiranmaya; Sreekanth, V.

    2011-01-01

    We study evolution of quark-gluon matter in the ultrarelativistic heavy-ion collisions within the frame work of relativistic second-order viscous hydrodynamics. In particular, by using the various prescriptions of a temperature-dependent shear viscosity to the entropy ratio, we show that the hydrodynamic description of the relativistic fluid becomes invalid due to the phenomenon of cavitation. For most of the initial conditions relevant for LHC, the cavitation sets in very early stage. The cavitation in this case is entirely driven by the large values of shear viscosity. Moreover we also demonstrate that the conformal terms used in equations of the relativistic dissipative hydrodynamic can influence the cavitation time.

  1. Viscosity, ion mobility, and the lambda transition

    International Nuclear Information System (INIS)

    Goodstein, D.L.

    1977-01-01

    A model is presented of the lambda transition in superfluid helium in which fluctuations near the transition are approximated by distinct regions of normal fluid and superfluid. The macroscopic viscosity of such a medium is computed. The ion mobility is also computed, taking into account a region of normal fluid around the ion induced by electrostriction. The results are, for the viscosity, eta/sub lambda/ - eta approx. t/sup 0.67/ and for the mobility μ - μ/sub lambda/ approx. t/sup 0.92/, both in excellent agreement with recent experiments. The model suggests that the lambda transition itself is the point at which superfluid regions become macroscopically connected

  2. Viscosity, granular-temperature, and stress calculations for shearing assemblies of inelastic, frictional disks

    International Nuclear Information System (INIS)

    Walton, O.R.; Braun, R.L.

    1986-01-01

    Employing nonequilibrium molecular-dynamics methods the effects of two energy loss mechanisms on viscosity, stress, and granular-temperature in assemblies of nearly rigid, inelastic frictional disks undergoing steady-state shearing are calculated. Energy introduced into the system through forced shearing is dissipated by inelastic normal forces or through frictional sliding during collisions resulting in a natural steady-state kinetic energy density (granular-temperature) that depends on the density and shear rate of the assembly and on the friction and inelasticity properties of the disks. The calculations show that both the mean deviatoric particle velocity and the effective viscosity of a system of particles with fixed friction and restitution coefficients increase almost linearly with strain rate. Particles with a velocity-dependent coefficient of restitution show a less rapid increase in both deviatoric velocity and viscosity as strain rate increases. Particles with highly dissipative interactions result in anisotropic pressure and velocity distributions in the assembly, particularly at low densities. At very high densities the pressure also becomes anisotropic due to high contact forces perpendicular to the shearing direction. The mean rotational velocity of the frictional disks is nearly equal to one-half the shear rate. The calculated ratio of shear stress to normal stress varies significantly with density while the ratio of shear stress to total pressure shows much less variation. The inclusion of surface friction (and thus particle rotation) decreases shear stress at low density but increases shear stress under steady shearing at higher densities

  3. Mechanisms of hydrogen retention in metallic beryllium and beryllium oxide and properties of ion-induced beryllium nitride

    International Nuclear Information System (INIS)

    Oberkofler, Martin

    2011-01-01

    In the framework of this thesis laboratory experiments on atomically clean beryllium surfaces were performed. They aim at a basic understanding of the mechanisms occurring upon interaction of a fusion plasma with a beryllium first wall. The retention and the temperature dependent release of implanted deuterium ions are investigated. An atomistic description is developed through simulations and through the comparison with calculations based on density functional theory. The results of these investigations are compared to the behaviour of hydrogen upon implantation into thermally grown beryllium oxide layers. Furthermore, beryllium nitride is produced by implantation of nitrogen into metallic beryllium and its properties are investigated. The results are interpreted with regard to the use of beryllium in a fusion reactor. (orig.)

  4. Experimental study on viscosity of spinel-type manganese ferrite nanofluid in attendance of magnetic field

    Energy Technology Data Exchange (ETDEWEB)

    Amani, Mohammad, E-mail: m_amani@sbu.ac.ir [Mechanical and Energy Engineering Department, Shahid Beheshti University, Tehran (Iran, Islamic Republic of); Amani, Pouria, E-mail: pouria.amani@ut.ac.ir [Department of Chemical Engineering, Faculty of Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Kasaeian, Alibakhsh, E-mail: akasa@ut.ac.ir [Department of Renewable Energies, Faculty of New Science & Technologies, University of Tehran, Tehran (Iran, Islamic Republic of); Mahian, Omid, E-mail: omid.mahian@mshdiau.ac.ir [Young Researchers and Elite Club, Mashhad Branch, Islamic Azad University, Mashhad (Iran, Islamic Republic of); Kasaeian, Fazel, E-mail: f.kasa92@student.sharif.edu [Faculty of Material Science and Engineering, Sharif University of Technology, Tehran (Iran, Islamic Republic of); Wongwises, Somchai, E-mail: somchai.won@kmutt.ac.th [Fluid Mechanics, Thermal Engineering and Multiphase Flow Research Lab (FUTURE), Department of Mechanical Engineering, Faculty of Engineering, King Mongkut' s University of Technology Thonburi (KMUTT), Bangmod, Bangkok (Thailand)

    2017-04-15

    In this paper, an experimental evaluation on the viscosity of water-based manganese ferrite nanofluid with and without magnetic field with 100, 200, 300, and 400 G intensities has been conducted. The Brookfield DV-I PRIME viscometer is implemented to measure the MnFe{sub 2}O{sub 4}/water nanofluid viscosity and to evaluate the influence of different volume concentrations (from 0.25% to 3%) and various temperatures (from 20 to 60 °C) on the viscosity. According to the measurements, viscosity incrementally increases with the augmentation of nanoparticles concentration while it remarkably decreases at higher temperatures under absence and attendance of magnetic field. The maximum viscosity ratio of 1.14 is achieved at 3 vol% of nanoparticles and 20 °C under no magnetic field, whereas it increments to maximum viscosity ratio of 1.75 at 3 vol% of nanoparticles and 40 °C under 400 G magnetic field. Furthermore, new correlation is proposed for determination of viscosity of MnFe{sub 2}O{sub 4}/water nanofluids in terms of magnetic field intensity, volume concentration and temperature. - Highlights: • Viscosity of spinel-type manganese ferrite nanofluids is measured. • Effect of a constant magnetic field on the viscosity is investigated. • A novel correlation is proposed for estimation of the measured viscosity.

  5. Experimental study on viscosity of spinel-type manganese ferrite nanofluid in attendance of magnetic field

    International Nuclear Information System (INIS)

    Amani, Mohammad; Amani, Pouria; Kasaeian, Alibakhsh; Mahian, Omid; Kasaeian, Fazel; Wongwises, Somchai

    2017-01-01

    In this paper, an experimental evaluation on the viscosity of water-based manganese ferrite nanofluid with and without magnetic field with 100, 200, 300, and 400 G intensities has been conducted. The Brookfield DV-I PRIME viscometer is implemented to measure the MnFe 2 O 4 /water nanofluid viscosity and to evaluate the influence of different volume concentrations (from 0.25% to 3%) and various temperatures (from 20 to 60 °C) on the viscosity. According to the measurements, viscosity incrementally increases with the augmentation of nanoparticles concentration while it remarkably decreases at higher temperatures under absence and attendance of magnetic field. The maximum viscosity ratio of 1.14 is achieved at 3 vol% of nanoparticles and 20 °C under no magnetic field, whereas it increments to maximum viscosity ratio of 1.75 at 3 vol% of nanoparticles and 40 °C under 400 G magnetic field. Furthermore, new correlation is proposed for determination of viscosity of MnFe 2 O 4 /water nanofluids in terms of magnetic field intensity, volume concentration and temperature. - Highlights: • Viscosity of spinel-type manganese ferrite nanofluids is measured. • Effect of a constant magnetic field on the viscosity is investigated. • A novel correlation is proposed for estimation of the measured viscosity.

  6. Numerical investigation on lateral migration and lift force of single bubble in simple shear flow in low viscosity fluid using volume of fluid method

    International Nuclear Information System (INIS)

    Zhongchun, Li; Xiaoming, Song; Shengyao, Jiang; Jiyang, Yu

    2014-01-01

    Highlights: • A VOF simulation of bubble in low viscosity fluid was conducted. • Lift force in different viscosity fluid had different lateral migration characteristics. • Bubble with different size migrated to different direction. • Shear stress triggered the bubble deformation process and the bubble deformation came along with the oscillation behaviors. - Abstract: Two phase flow systems have been widely used in industrial engineering. Phase distribution characteristics are vital to the safety operation and optimization design of two phase flow systems. Lift force has been known as perpendicular to the bubbles’ moving direction, which is one of the mechanisms of interfacial momentum transfer. While most widely used lift force correlations, such as the correlation of Tomiyama et al. (2002), were obtained by experimentally tracking single bubble trajectories in high viscosity glycerol–water mixture, the applicability of these models into low viscosity fluid, such as water in nuclear engineering system, needs to be further evaluated. In the present paper, bubble in low viscosity fluid in shear flow was investigated in a full 3D numerical simulation and the volume of fluid (VOF) method was applied to capture the interface. The fluid parameter: fluid viscosity, bubble parameter: diameter and external flow parameters: shear stress magnitude and liquid velocity were examined. Comparing with bubble in high viscosity shear flow and bubble in low viscosity still flow, relative large bubble in low viscosity shear flow keep an oscillation way towards the moving wall and experienced a shape deformation process. The oscillation amplitude increased as the viscosity of fluid decreased. Small bubble migrated to the static wall in a line with larger migration velocity than that in high viscosity fluid and no deformation occurred. The shear stress triggered the oscillation behaviors while it had no direct influence with the behavior. The liquid velocity had no effect on

  7. Heritability and Seasonal Changes in Viscosity of Slash Pine Oleoresin

    Science.gov (United States)

    Robert D. McReynolds

    1971-01-01

    Oleoresin viscosity was measured in slash pine (Pinus elliottii var. elliottii) trees of known genetic origin over a 1-year period. A strong broad-sense heritability of this trait was found. Seasonal variation followed a definite pattern, with the highest viscosities occurring in early spring and a gradual decline occurring in...

  8. Excess molar volumes and viscosities of binary mixtures of 1,2

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Chemical Sciences; Volume 113; Issue 3. Excess molar volumes and viscosities of binary mixtures of 1,2-diethoxyethane with chloroalkanes ... The Bloomfield and Dewan model has been used to calculate viscosity ...

  9. Effective viscosity of confined hydrocarbons

    DEFF Research Database (Denmark)

    Sivebæk, Ion Marius; Samoilov, V.N.; Persson, B.N.J.

    2012-01-01

    We present molecular dynamics friction calculations for confined hydrocarbon films with molecular lengths from 20 to 1400 carbon atoms. We find that the logarithm of the effective viscosity ηeff for nanometer-thin films depends linearly on the logarithm of the shear rate: log ηeff=C-nlog γ̇, where...

  10. Using Of Viscosity Property For Identification Of Irradiated Black Pepper And Cumin

    International Nuclear Information System (INIS)

    ALI, H.G.M.

    2009-01-01

    In the present investigation, the viscosity measurement was used for detecting irradiated black pepper and cumin during storage period. All samples under investigation were packed in polyethylene bags then irradiated at 3, 5, 7 and 10 kGy and stored for 12 months at room temperature then viscosity were measured under extremely alkaline condition (ph 13.8). The results indicated that irradiation treatment caused significant decrease in apparent viscosity values, where it decreased from 67.3 in control sample to 49.7, 42.3, 38.7 and 32.7 mpa.s in black pepper, while the viscosity of cumin was decreased from 74 mpa.s for control to 64.9, 41.7, 25.3 and 11.3 mpa.s for samples. The viscosity of black pepper and cumin were decreased significantly with increasing the radiation dose and during storage period. It was decreased from 67.3 for control to 67.0, 47.7, 32.3 and 17.7 mpa.s after 3, 6, 9 and 12 months, respectively, in black pepper while the viscosity of cumin samples was decreased significantly from 74 for control to 50.3, 17.1, 9.5 and 7.2 mpa.s after the same months. The data also showed that the moisture and carbohydrate contents were decreased by increasing the radiation dose. It could be concluded that the viscosity parameter can be used to identify of black pepper and cumin samples after irradiation and during 12 months of storage at ambient temperature.

  11. Cooking utensil with improved heat retention

    Science.gov (United States)

    Potter, T.F.; Benson, D.K.; Burch, S.D.

    1997-07-01

    A cooking utensil with improved heat retention includes an inner pot received within an outer pot and separated in a closely spaced-apart relationship to form a volume or chamber there between. The chamber is evacuated and sealed with foil leaves at the upper edges of the inner and outer pot. The vacuum created between the inner and outer pot, along with the minimum of thermal contact between the inner and outer pot, and the reduced radiative heat transfer due to low emissivity coatings on the inner and outer pot, provide for a highly insulated cooking utensil. Any combination of a plurality of mechanisms for selectively disabling and re-enabling the insulating properties of the pot are provided within the chamber. These mechanisms may include: a hydrogen gas producing and reabsorbing device such as a metal hydride, a plurality of metal contacts which can be adjusted to bridge the gap between the inner and outer pot, and a plurality of bimetallic switches which can selectively bridge the gap between the inner and outer pot. In addition, phase change materials with superior heat retention characteristics may be provided within the cooking utensil. Further, automatic and programmable control of the cooking utensil can be provided through a microprocessor and associated hardware for controlling the vacuum disable/enable mechanisms to automatically cook and save food. 26 figs.

  12. Cooking utensil with improved heat retention

    Science.gov (United States)

    Potter, Thomas F.; Benson, David K.; Burch, Steven D.

    1997-01-01

    A cooking utensil with improved heat retention includes an inner pot received within an outer pot and separated in a closely spaced-apart relationship to form a volume or chamber therebetween. The chamber is evacuated and sealed with foil leaves at the upper edges of the inner and outer pot. The vacuum created between the inner and outer pot, along with the minimum of thermal contact between the inner and outer pot, and the reduced radiative heat transfer due to low emissivity coatings on the inner and outer pot, provide for a highly insulated cooking utensil. Any combination of a plurality of mechanisms for selectively disabling and re-enabling the insulating properties of the pot are provided within the chamber. These mechanisms may include: a hydrogen gas producing and reabsorbing device such as a metal hydride, a plurality of metal contacts which can be adjusted to bridge the gap between the inner and outer pot, and a plurality of bimetallic switches which can selectively bridge the gap between the inner and outer pot. In addition, phase change materials with superior heat retention characteristics may be provided within the cooking utensil. Further, automatic and programmable control of the cooking utensil can be provided through a microprocessor and associated hardware for controlling the vacuum disable/enable mechanisms to automatically cook and save food.

  13. Transport and Retention of Carboxymethylcellulose-Modified Carbon Nanotube-Magnetite Nanohybrids in Water-Saturated Porous Media

    Science.gov (United States)

    Wang, D.; Su, C.

    2017-12-01

    Carbon-metal oxide nanohybrids (NHs) are increasingly recognized as the next-generation, promising group of nanomaterials for solving emerging environmental issues and challenges. This research, for the first time, systematically explored the transport and retention of the multifunctional carbon nanotube-magnetite (CNT-Fe3O4) NHs in water-saturated porous media under environmentally relevant physicochemical conditions. An environment-benign macromolecule, carboxymethylcellulose (CMC), was employed to stabilize the NHs. Classical Derjaguin-Landau-Verwey-Overbeek (DLVO) theory and colloid transport model were used to describe the transport and retention of the NHs. Our results showed that transport of the magnetic CNT-Fe3O4 NHs was lower than that of the parent CNT due to greater aggregation (induced by magnetic attraction) during transport. The DLVO theory well-interpreted the NHs' transport; and secondary minimum played dominant roles in NHs' retention. A novel transport feature, an initial low and following sharp peaks occurred frequently in the NHs' breakthrough curves; and the magnitude and location of both transport peaks varied with different experimental conditions due to the interplay between variability of the fluid viscosity and aggregation-dispersion nature of the NHs. Very promisingly, the estimated maximum transport distance of NHs using the Tufenkji-Elimelech equation ranged between 0.38-46 m, supporting the feasibility of employing the magnetically recyclable CNT-Fe3O4 NHs for in-situ nanoremediation of contaminated soils, sediment aquifers, and groundwater.

  14. [Relations between plasma-erythrocyte viscosity factors and ESR].

    Science.gov (United States)

    Cortinovis, A; Crippa, A; Crippa, M; Bosoni, T; Moratti, R

    1992-09-01

    The ESR is usually put in relationship: to the real density of the RBCs (erythrocytes) (difference between the RBC specific gravity and the plasma one), and to the resistance that the RBCs meet moving in a medium, which is due to the plasma viscosity and to the total external RBC surface. When the RBCs take shape of aggregates, their external surface is decreased and ESR increases. The most important plasma factor causing changes in ESR is the fibrinogen level followed by the plasma globulins and by the products arising from the tissue damage. The resistance that the RBCs meet moving in the plasma is well expressed by the measurement of the plasma-RBC viscosity considering that is inclusive of both factors that are the plasma viscosity and the external RBC surface. The plasma-RBC viscosity is the resultant of several factors: Fa = Fb - Fe - Fs - Fm, were: Fa is the resultant, Fb the attracting forces due to the proteic macromolecules, Fe the repulsing forces due the negative charges. Fs the repulsing forces due to the shear-stress, Fm the force which opposes itself against the surface tension of the aggregation; it depends on the RBC morphology and on the RBC rigidity. The ESR has been recently used like an index of the RBC aggregation. The Authors study the relationship between several hemorheological parameters and the ESR in infective and inflammatory processes.(ABSTRACT TRUNCATED AT 250 WORDS)

  15. Online shear viscosity measurement of starchy melts enriched in wheat bran.

    Science.gov (United States)

    Robin, Frédéric; Bovet, Nicolas; Pineau, Nicolas; Schuchmann, Heike P; Palzer, Stefan

    2011-01-01

    Addition of wheat bran to flours modifies their expansion properties after cooking extrusion. This can be attributed to changes in the melt shear viscosity at the die. The effect of wheat bran concentration added to achieve 2 levels of dietary fibers of 12. 6% and 24.4%, and process conditions on the shear viscosity of wheat flour was therefore assessed using an online twin-slit rheometer. The shear viscosity measured at 30 s⁻¹ ranged from 9.5 × 10³ to 53.4 × 10³ Pa s. Regardless of the process conditions and bran concentration, the extruded melts showed a pseudoplastic behavior with a power law index n ranging from 0.05 to 0.27. Increasing the barrel temperature of the extruder from 120 to 180 °C, the water content from 18% to 22% or the screw speed from 400 to 800 rpm significantly decreased the melt shear viscosity at the extruder exit. The addition of bran significantly increased the melt shear viscosity only at the highest bran concentration. The effect was process condition dependant. Mathematical interpretations, based upon observations, of the experimental data were carried out. They can be used to predict the effect of the process conditions on the melt shear viscosity at the die of extruded wheat flour with increasing bran concentration. The viscosity data will be applied in future works to study the expansion properties of extruded wheat flour supplemented with bran. Incorporation of wheat bran, a readily available and low cost by-product, in extruded puffed foods is constrained due to its negative effect on the product texture. Understanding the effect of wheat bran on rheological properties of extruded melts, driving the final product properties, is essential to provide solutions to the food industry and enhance its use. © 2011 Institute of Food Technologists®

  16. Titin-Actin Interaction: PEVK-Actin-Based Viscosity in a Large Animal

    Directory of Open Access Journals (Sweden)

    Charles S. Chung

    2011-01-01

    Full Text Available Titin exhibits an interaction between its PEVK segment and the actin filament resulting in viscosity, a speed dependent resistive force, which significantly influences diastolic filling in mice. While diastolic disease is clinically pervasive, humans express a more compliant titin (N2BA:N2B ratio ~0.5–1.0 than mice (N2BA:N2B ratio ~0.2. To examine PEVK-actin based viscosity in compliant titin-tissues, we used pig cardiac tissue that expresses titin isoforms similar to that in humans. Stretch-hold experiments were performed at speeds from 0.1 to 10 lengths/s from slack sarcomere lengths (SL to SL of 2.15 μm. Viscosity was calculated from the slope of stress-relaxation vs stretch speed. Recombinant PEVK was added to compete off native interactions and this found to reduce the slope by 35%, suggesting that PEVK-actin interactions are a strong contributor of viscosity. Frequency sweeps were performed at frequencies of 0.1–400 Hz and recombinant protein reduced viscous moduli by 40% at 2.15 μm and by 50% at 2.25 μm, suggesting a SL-dependent nature of viscosity that might prevent SL ``overshoot’’ at long diastolic SLs. This study is the first to show that viscosity is present at physiologic speeds in the pig and supports the physiologic relevance of PEVK-actin interactions in humans in both health and disease.

  17. Determination of the density and the viscosities of biodiesel-diesel fuel blends

    Energy Technology Data Exchange (ETDEWEB)

    Alptekin, Ertan; Canakci, Mustafa [Department of Mechanical Education, Kocaeli University, 41380 Kocaeli (Turkey); Alternative Fuels R and D Center, Kocaeli University, 41040 Kocaeli (Turkey)

    2008-12-15

    In this study, commercially available two different diesel fuels were blended with the biodiesels produced from six different vegetable oils (sunflower, canola, soybean, cottonseed, corn oils and waste palm oil). The blends (B2, B5, B10, B20, B50 and B75) were prepared on a volume basis. The key fuel properties such as density and viscosities of the blends were measured by following ASTM test methods. Generalized equations for predicting the density and viscosities for the blends were given and a mixing equation, originally proposed by Arrhenius and described by Grunberg and Nissan, was used to predict the viscosities of the blends. For all blends, it was found that there is an excellent agreement between the measured and estimated values of the density and viscosities. According to the results, the density and viscosities of the blends increased with the increase of biodiesel concentration in the fuel blend. (author)

  18. Searching for perfect fluids: quantum viscosity in a universal Fermi gas

    International Nuclear Information System (INIS)

    Cao, C; Elliott, E; Wu, H; Thomas, J E

    2011-01-01

    We measure the shear viscosity in a two-component Fermi gas of atoms, tuned to a broad s-wave collisional (Feshbach) resonance. At resonance, the atoms strongly interact and exhibit universal behavior, where the equilibrium thermodynamic properties and transport coefficients are universal functions of density n and temperature T. We present a new calibration of the temperature as a function of global energy, which is directly measured from the cloud profiles. Using the calibration, the trap-averaged shear viscosity in units of ℎn is determined as a function of the reduced temperature at the trap center, from nearly the ground state to the unitary two-body regime. Low-temperature data are obtained from the damping rate of the radial breathing mode, whereas high-temperature data are obtained from hydrodynamic expansion measurements. We also show that the best fit to the high-temperature expansion data is obtained for a vanishing bulk viscosity. The measured trap-averaged entropy per particle and shear viscosity are used to estimate the ratio of shear viscosity to entropy density, which is compared with that conjectured for a perfect fluid.

  19. Effect of β-cyclodextrin on Rheological Properties of some Viscosity Modifiers.

    Science.gov (United States)

    Rao, G Chandra Sekhara; Ramadevi, K; Sirisha, K

    2014-01-01

    Cyclodextrins are a group of novel excipients, extensively used in the present pharmaceutical industry. Sometimes they show significant interactions with other conventional additives used in the formulation of dosage forms. The effect of β-cyclodextrin on the rheological properties of aqueous solutions of some selected viscosity modifiers was studied in the present work. β-cyclodextrin showed two different types of effects on the rheology of the selected polymers. In case of natural polymers like xanthan gum and guar gum, enhanced apparent viscosity was found and in case of semi-synthetic polymers like sodium carboxymethyl cellulose and methyl cellulose, reduction in apparent viscosity was found. β-cyclodextrin was included at 0.5, 1 and 2% w/v concentrations into the polymeric solutions. These findings are useful in the adjustment of concentrations of viscosity modifiers during the formulation of physically stable disperse systems.

  20. Experimental study of electric conductivity, density and viscosity of Wood's alloy

    International Nuclear Information System (INIS)

    Kazandzhan, B.I.; Matveev, V.M.; Savich, T.B.; Umarov, A.M.

    1989-01-01

    Electric conductivity, density and kinematic viscosity of commercially pure Wood's alloy are obtained in a wide temperature range. Electric conductivity and density are investigated from the room temperature to 1000 K. Measurements of kinematic viscosity are carried out from 372 to 1000 K by means of torsional vibrations method using informatiom computer system permitting to automate data acquisition and processing and to increase the measurement accuracy. On the basis of analysis the character of electric conductivity and kinematic viscosity polyterms Wood's alloy liquidus and solidus temperatures are estimated

  1. Approximate Solution of Dam-break Flow of Low Viscosity Bingham Fluid

    Science.gov (United States)

    Puay, How Tion; Hosoda, Takashi

    In this study, we investigate the characteristics of dam-break flow of low viscosity Bingham fluid by deriving an approximate solution for the time development of the front position and depth at the origin of the flow. The asymptotic solutions representing the characteristic of Bingham fluid in the limit of low plastic viscosity are verified with a depth-averaged numerical model. Numerical simulations showed that with the decrease of plastic viscosity, the time development of the front position and depth at the origin approach to the theoretical asymptotic solution.

  2. Evaluation of Removal Mechanisms in a Graphene Oxide-Coated Ceramic Ultrafiltration Membrane for Retention of Natural Organic Matter, Pharmaceuticals, and Inorganic Salts.

    Science.gov (United States)

    Chu, Kyoung Hoon; Fathizadeh, Mahdi; Yu, Miao; Flora, Joseph R V; Jang, Am; Jang, Min; Park, Chang Min; Yoo, Sung Soo; Her, Namguk; Yoon, Yeomin

    2017-11-22

    Functionalized graphene oxide (GO), derived from pure graphite via the modified Hummer method, was used to modify commercially available ceramic ultrafiltration membranes using the vacuum method. The modified ceramic membrane functionalized with GO (ceramic GO ) was characterized using a variety of analysis techniques and exhibited higher hydrophilicity and increased negative charge compared with the pristine ceramic membrane. Although the pure water permeability of the ceramic GO membrane (14.4-58.6 L/m 2 h/bar) was slightly lower than that of the pristine membrane (25.1-62.7 L/m 2 h/bar), the removal efficiencies associated with hydrophobic attraction and charge effects were improved significantly after GO coating. Additionally, solute transport in the GO nanosheets of the ceramic GO membrane played a vital role in the retention of target compounds: natural organic matter (NOM; humic acid and tannic acid), pharmaceuticals (ibuprofen and sulfamethoxazole), and inorganic salts (NaCl, Na 2 SO 4 , CaCl 2 , and CaSO 4 ). While the retention efficiencies of NOM, pharmaceuticals, and inorganic salts in the pristine membrane were 74.6%, 15.3%, and 2.9%, respectively, these increased to 93.5%, 51.0%, and 31.4% for the ceramic GO membrane. Consequently, the improved removal mechanisms of the membrane modified with functionalized GO nanosheets can provide efficient retention for water treatment under suboptimal environmental conditions of pH and ionic strength.

  3. Time Dependent and Steady Uni-axial Elongational Viscosity

    DEFF Research Database (Denmark)

    Nielsen, Jens K.; Rasmussen, Henrik Koblitz; Hassager, Ole

    2005-01-01

    Here we present measurements of transient and steady uni-axial elongational viscosity, using the Filament Stretching Rheometer1 or FSR1 (see Fig. 1) of the following melts: Four narrow MMD polystyrene (PS) samples with weight-average molar mass Mw in the range of 50k to 390k. Three different bi......-disperse samples, mixed from the narrow MMD PS. Two low-density polyethylene (LDPE) melts (Lupolen 1840D and 3020D). A steady-state viscosity was kept for 1-2.5 Hencky strain units in all measurements....

  4. Principles of application of mechanical design measures to control severe accident phenomena, applied to the melt retention concept of the EPR

    International Nuclear Information System (INIS)

    Bittermann, D.

    2000-01-01

    To retain and stabilize a core melt within the containment, the phenomena which principally have to be dealt with are related to melt discharge, spreading, retention and cooling, plus specific phenomena like melt dispersal and ex-vessel melt water interaction. For the elaboration of mechanical design measures provided to stabilize a melt within the containment, boundary conditions may occur which could pose extremely high thermal and mechanical loads on the structures. This file describes an approach characterized by the idea to influence the course of severe accident scenarios as much as possible in order to generate boundary conditions for mitigation means ''by design'', which enables the development of a mitigation concept with maximum confidence in the effectiveness of the measures provided. (orig.)

  5. Viscosity Measurement: A Virtual Experiment - Abstract of Issues 9907W

    Science.gov (United States)

    Papadopoulos, N.; Pitta, A. T.; Markopoulos, N.; Limniou, M.; Lemos, M. A. N. D. A.; Lemos, F.; Freire, F. G.

    1999-11-01

    Viscosity Measurement: A Virtual Experiment simulates a series of viscosity experiments. Viscosity is an important subject in chemistry and chemical engineering. It is important when dealing with intermolecular forces in liquids and gases and it has enormous relevance in all technological aspects of equipment dealing with liquids or gases. Most university-level chemistry courses include viscosity to some extent. Viscosity Measurement includes three virtual experiments: an Ostwald viscometer simulator, a falling-ball viscometer simulator, and a balance simulator for a simple determination of the density of a liquid. The Ostwald viscometer simulator and the balance simulator allow the student to find out how composition and temperature influence the density and viscosity of an ethanol-water mixture. The falling-ball viscometer simulator allows the student to determine experimentally the size and density of the ball required to measure viscosity of various liquids. Each virtual experiment includes a corresponding theoretical section. Support from the program is sufficient to enable the students to carry out a virtual experiment sensibly and on their own. Preparation is not essential. Students can use the program unsupervised, thus saving staff time and allowing flexibility in students' time. The design of the program interface plays a key role in the success of a simulated experiment. Direct manipulation has greater intuitive appeal than alternative interface forms such as menus and has been observed to provide performance and learning advantages (1). We tried to design an interface that is visually attractive, is user friendly with simple and intuitive navigation, and provides appropriate schematic animations to clarify the principles of the laboratory procedures. The opening screen presents the virtual experiments that can be selected. Clicking an icon takes the student to the appropriate section. Viscosity Measurement allows the student to concentrate on the

  6. Viscosity measurements of molten refractory metals using an electrostatic levitator

    International Nuclear Information System (INIS)

    Ishikawa, Takehiko; Paradis, Paul-François; Okada, Junpei T; Watanabe, Yuki

    2012-01-01

    Viscosities of several refractory metals (titanium, nickel, zirconium, niobium, ruthenium, rhodium, hafnium, iridium and platinum) and terbium have been measured by the oscillation drop method with an improved procedure. The measured data were less scattered than our previous measurements. Viscosities at their melting temperatures showed good agreement with literature values and some predicted values. (paper)

  7. The adhesive strength and initial viscosity of denture adhesives.

    Science.gov (United States)

    Han, Jian-Min; Hong, Guang; Dilinuer, Maimaitishawuti; Lin, Hong; Zheng, Gang; Wang, Xin-Zhi; Sasaki, Keiichi

    2014-11-01

    To examine the initial viscosity and adhesive strength of modern denture adhesives in vitro. Three cream-type denture adhesives (Poligrip S, Corect Cream, Liodent Cream; PGS, CRC, LDC) and three powder-type denture adhesives (Poligrip Powder, New Faston, Zanfton; PGP, FSN, ZFN) were used in this study. The initial viscosity was measured using a controlled-stress rheometer. The adhesive strength was measured according to ISO-10873 recommended procedures. All data were analyzed independently by one-way analysis of variance combined with a Student-Newman-Keuls multiple comparison test at a 5% level of significance. The initial viscosity of all the cream-type denture adhesives was lower than the powder-type adhesives. Before immersion in water, all the powder-type adhesives exhibited higher adhesive strength than the cream-type adhesives. However, the adhesive strength of cream-type denture adhesives increased significantly and exceeded the powder-type denture adhesives after immersion in water. For powder-type adhesives, the adhesive strength significantly decreased after immersion in water for 60 min, while the adhesive strength of the cream-type adhesives significantly decreased after immersion in water for 180 min. Cream-type denture adhesives have lower initial viscosity and higher adhesive strength than powder type adhesives, which may offer better manipulation properties and greater efficacy during application.

  8. Effects of Nattokinase on Whole Blood Viscosity and Mortality

    Directory of Open Access Journals (Sweden)

    Melike Cengiz

    2011-12-01

    Full Text Available Objective: Nattokinase is a serin protease having potent fibrinolytic effect derived from fermentation of boiled soy bean by the use of Basillus Subtilis Natto. The aim of this experimental study is to investigate the effects of intragastric Nattokinase (6 mg/day administration for 7 days prior to formation of sepsis on plasma fibrinogen levels, whole blood viscosity and mortality in rats. Materials and Methods: Intraabdominal sepsis were performed by cecal ligation and puncture in rats supplemented with nattokinase or olive oil for 7 days prior to sepsis formation. Plasma fibrinogen, whole blood viscosity analysis and survival analysis was performed after intraabdominal sepsis formation. Results: Mean blood viscosity of rats was lower in Nattokinase and cecal ligation group at lowest shear rate (p<0.05. However, the differences between groups were not significant at higher shear rates. No difference was found in survival rates and survival times of Nattokinase and cecal ligation and cecal ligation and puncture groups. Conclusion: Our results were unable to show the effects of intragastric nattokinase supplementation prior to sepsis on plasma fibrinogen levels or whole blood viscosity, except low shear rate. Nattokinase did not altered survival in septic rats. (Journal of the Turkish Society Intensive Care 2011; 9: 85-9

  9. Mechanistic investigation of food effect on disintegration and dissolution of BCS class III compound solid formulations: the importance of viscosity.

    Science.gov (United States)

    Radwan, Asma; Amidon, Gordon L; Langguth, Peter

    2012-10-01

    A negative food effect, i.e. a decrease in bioavailability upon the co-administration of compounds together with food, has been attributed particularly with high solubility/low permeability compounds (BCS class III). Different mechanisms have been proposed including intestinal dilution leading to a lower concentration gradient across the intestinal wall as well as binding of the active pharmaceutical ingredient to food components in the intestine and thereby decreasing the fraction of the dose available for absorption. These mechanisms refer primarily to the compound and not to the dosage form. An increase in viscosity of the dissolution fluid will in particular affect the absorption of BCS type III compounds with preferential absorption in the upper small intestine if the API release is delayed from the dosage form. The present study demonstrated that the increase in viscosity of the dissolution medium, following ingestion of a solid meal, may drastically reduce disintegration and dissolution. For that purpose the viscosity of the standard FDA meal was determined and simulated by solutions of HPMC in buffer. As model formulations, three commercially available tablets containing trospium chloride, a BCS class III m-cholinoreceptor antagonist was used. Trospium chloride drug products have been described to undergo a negative food effect of more than 80% following ingestion with food. The tablets showed prolonged disintegration times and reduced dissolution rates in viscous media, which could be attributed to changes in the liquid penetration rates. The effect was particularly significant for film-coated tablets relative to uncoated dosage forms. The results show the necessity of considering media viscosity when designing in vitro models of drug release for BCS type III drug formulations. Copyright © 2012 John Wiley & Sons, Ltd.

  10. Experimental density and viscosity measurements of di(2ethylhexyl)sebacate at high pressure

    International Nuclear Information System (INIS)

    Paredes, Xavier; Fandino, Olivia; Pensado, Alfonso S.; Comunas, Maria J.P.; Fernandez, Josefa

    2012-01-01

    Highlights: → We measure viscosities for di(2-ethylhexyl)sebacate from (298.15 to 398.15) K and up to 60 MPa. → We measure densities for DEHS from (298.15 to 373.15) K and from (0.1 to 60) MPa. → The reported and lit. data were used in a viscosity correlation from (273 to 491) K and up to 1.1 GPa. → This correlation could be used in industrial equipment that operate at high pressures. - Abstract: Experimental densities and dynamic viscosities of di(2-ethylhexyl)sebacate (DEHS) are the object of study in this work. DEHS could be a useful industrial reference fluid for moderately high viscosity at high pressures as it is often used as a pressure transmitting fluid. At atmospheric pressure the density and viscosity measurements have been performed in a rotational SVM 3000 Stabinger viscometer from (273.15 to 373.15) K, whereas from (0.1 to 60) MPa and from (298.15 to 398.15) K an automated Anton Paar DMA HPM vibrating-tube densimeter, and a high-pressure rolling-ball viscometer were used. Several Vogel-Fulcher-Tammann type equations were used to fit the experimental values of viscosity to the pressure and temperature. The measured viscosity data have been used together with previous data found in the literature to establish a correlation of the viscosity surface η(T, p) of DEHS, covering a temperature range from (273 to 491) K and pressure up to 1.1 GPa. This correlation could be used in industrial equipment like viscometers and other devices that operate at high pressures. Our viscosity data have also been fitted as a function of temperature and volume to the thermodynamic scaling model of Roland et al. [C.M. Roland, S. Bair, R. Casalini, J. Chem. Phys. 125 (2006) 124508].

  11. Radionuclide Retention in Concrete Wasteforms - FY13

    Energy Technology Data Exchange (ETDEWEB)

    Snyder, Michelle MV; Golovich, Elizabeth C.; Wellman, Dawn M.; Crum, Jarrod V.; Lapierre, Robert; Dage, Denomy C.; Parker, Kent E.; Cordova, Elsa A.

    2013-10-15

    Assessing long-term performance of Category 3 waste cement grouts for radionuclide encasement requires knowledge of the radionuclide-cement interactions and mechanisms of retention (i.e., sorption or precipitation); the mechanism of contaminant release; the significance of contaminant release pathways; how wasteform performance is affected by the full range of environmental conditions within the disposal facility; the process of wasteform aging under conditions that are representative of processes occurring in response to changing environmental conditions within the disposal facility; the effect of wasteform aging on chemical, physical, and radiological properties; and the associated impact on contaminant release. This knowledge will enable accurate prediction of radionuclide fate when the wasteforms come in contact with groundwater. Data collected throughout the course of this work will be used to quantify the efficacy of concrete wasteforms, similar to those used in the disposal of low-level waste and mixed low-level waste, for the immobilization of key radionuclides (i.e., uranium, technetium, and iodine). Data collected will also be used to quantify the physical and chemical properties of the concrete affecting radionuclide retention.

  12. Decreased hematocrit-to-viscosity ratio and increased lactate dehydrogenase level in patients with sickle cell anemia and recurrent leg ulcers.

    Directory of Open Access Journals (Sweden)

    Philippe Connes

    Full Text Available Leg ulcer is a disabling complication in patients with sickle cell anemia (SCA but the exact pathophysiological mechanisms are unknown. The aim of this study was to identify the hematological and hemorheological alterations associated with recurrent leg ulcers. Sixty-two SCA patients who never experienced leg ulcers (ULC- and 13 SCA patients with a positive history of recurrent leg ulcers (ULC+--with no leg ulcers at the time of the study--were recruited. All patients were in steady state condition. Blood was sampled to perform hematological, biochemical (hemolytic markers and hemorheological analyses (blood viscosity, red blood cell deformability and aggregation properties. The hematocrit-to-viscosity ratio (HVR, which reflects the red blood cell oxygen transport efficiency, was calculated for each subject. Patients from the ULC+ group were older than patients from the ULC- group. Anemia (red blood cell count, hematocrit and hemoglobin levels was more pronounced in the ULC+ group. Lactate dehydrogenase level was higher in the ULC+ group than in the ULC- group. Neither blood viscosity, nor RBC aggregation properties differed between the two groups. HVR was lower and RBC deformability tended to be reduced in the ULC+ group. Our study confirmed increased hemolytic rate and anemia in SCA patients with leg ulcers recurrence. Furthermore, our data suggest that although systemic blood viscosity is not a major factor involved in the pathophysiology of this complication, decreased red blood cell oxygen transport efficiency (i.e., low hematocrit/viscosity ratio may play a role.

  13. Fission hindrance and nuclear viscosity

    Indian Academy of Sciences (India)

    is in exact conformity with all the previous measurements [7,10–13]. The CASCADE calculations (solid lines in figure 1) used in this first level of analysis do not include any viscosity or temperature-dependent nuclear level density parameter a. The γ and particle decay are calculated using the standard prescriptions as ...

  14. Mantle viscosity structure constrained by joint inversions of seismic velocities and density

    Science.gov (United States)

    Rudolph, M. L.; Moulik, P.; Lekic, V.

    2017-12-01

    The viscosity structure of Earth's deep mantle affects the thermal evolution of Earth, the ascent of mantle upwellings, sinking of subducted oceanic lithosphere, and the mixing of compositional heterogeneities in the mantle. Modeling the long-wavelength dynamic geoid allows us to constrain the radial viscosity profile of the mantle. Typically, in inversions for the mantle viscosity structure, wavespeed variations are mapped into density variations using a constant- or depth-dependent scaling factor. Here, we use a newly developed joint model of anisotropic Vs, Vp, density and transition zone topographies to generate a suite of solutions for the mantle viscosity structure directly from the seismologically constrained density structure. The density structure used to drive our forward models includes contributions from both thermal and compositional variations, including important contributions from compositionally dense material in the Large Low Velocity Provinces at the base of the mantle. These compositional variations have been neglected in the forward models used in most previous inversions and have the potential to significantly affect large-scale flow and thus the inferred viscosity structure. We use a transdimensional, hierarchical, Bayesian approach to solve the inverse problem, and our solutions for viscosity structure include an increase in viscosity below the base of the transition zone, in the shallow lower mantle. Using geoid dynamic response functions and an analysis of the correlation between the observed geoid and mantle structure, we demonstrate the underlying reason for this inference. Finally, we present a new family of solutions in which the data uncertainty is accounted for using covariance matrices associated with the mantle structure models.

  15. Experimental determination of viscosity of water based magnetite nanofluid for application in heating and cooling systems

    International Nuclear Information System (INIS)

    Toghraie, Davood; Alempour, Seyed Mohammadbagher; Afrand, Masoud

    2016-01-01

    In this paper, experimental determination of dynamic viscosity of water based magnetite nanofluid (Fe 3 O 4 /water) was performed. The viscosity was measured in the temperature range of 20–55 °C for various samples with solid volume fractions of 0.1%, 0.2%, 0.4%, 1%, 2% and 3%. The results showed that the viscosity considerably decreases with increasing temperature. Moreover, the viscosity enhances with an increase in the solid volume fraction, remarkably. The calculated viscosity ratios showed that the maximum viscosity enhancement was 129.7%. Using experimental data, a new correlation has been proposed to predict the viscosity of magnetite nanofluid (Fe 3 O 4 /water). A comparison between the experimental results and the correlation outputs showed that the proposed model has a suitable accuracy. - Highlights: • Preparing Magnetite nanofluids with solid volume fractions up to 3%. • Measuring viscosity in temperature range of 20–55 °C using Brookfield Viscometer. • Maximum viscosity enhancement occurred at volume fraction of 3% and was 129.7%. • Proposing new correlation to predict the viscosity of Fe3O4/water nanofluid.

  16. A model for the viscosity of dilute smectite gels

    International Nuclear Information System (INIS)

    Liu, Di; Liu, Longcheng

    2010-01-01

    Document available in extended abstract form only. A simple yet accurate model describing the viscosity of dilute suspensions of sodium montmorillonite in low ionic strength waters is presented. Taking the clay particle and the surrounding clouds of ions as whole as an uncharged but soft particle, the Huggins' equation is extended in the model to account for both the primary and the secondary electro-viscous effects, by use of the notion of an effective volume fraction. In the model, however, we do not represent the clay particle as a sphere surrounded by immobile water layer with thickness of a Debye length, as did by Adachi et al. (1998) who used the co-volume fraction to approximate the effective volume fraction. We visualize the effective geometry of the particle and the associated ionic atmosphere as an ellipsoid. This representation is more practical and more plausible, because in the limit of large ionic strength, the electrolyte ions have been screened to a significant extent so that the charged particle behaves just like an uncharged one. As a result, the application of the Simha's equation of intrinsic viscosity for ellipsoidal particle following with random Brownian motion enables us to obtain an analytical expression for the primary electro-viscous effect. More importantly, the available models for hard plate-like particles can be used to aid in the quantification of the secondary electro-viscous effect. The development of the model is based firmly on precise measurements of the viscosity of sufficiently dilute suspensions of sodium montmorillonite in low concentration NaCl solutions (at room temperature) using Ostwald capillary viscometers. The obtained data clearly demonstrate the primary and the secondary electro-viscous effects. That is, with an decrease of ionic strength, the intrinsic viscosity which is the intercept of the extrapolation of the plot at zero volume fraction will increase, and the slope of the linear part which appears in

  17. Effect of electron beam irradiation on the viscosity of carboxymethylcellulose solution

    International Nuclear Information System (INIS)

    Choi, Jong-il; Lee, Hee-Sub; Kim, Jae-Hun; Lee, Kwang-Won; Chung, Young-Jin; Byun, Myung-Woo; Lee, Ju-Woon

    2008-01-01

    In this study, the effects of an electron beam irradiation on the viscosity of a carboxymethylcellulose (CMC) solution were investigated. The viscosity of the CMC solution was decreased with an increase in the irradiation dose. Interestingly, the extent of the degradation of the CMC was found to decrease with an increase of the CMC concentration in the solution. The change of the average molar mass confirmed the decrease in the viscosity due to the degradation of the polymer. The energy of the electron beam also affected the degradation of the CMC. Lower degradation of the CMC was obtained with a decreasing electron beam energy due to its lower penetration. Addition of vitamin C as a radical scavenger to the solution and an irradiation at -70 deg. C were shown to be moderately effective in preventing a decrease in the viscosity of the solution by irradiation.

  18. Effect of electron beam irradiation on the viscosity of carboxymethylcellulose solution

    Science.gov (United States)

    Choi, Jong-il; Lee, Hee-Sub; Kim, Jae-Hun; Lee, Kwang-Won; Chung, Young-Jin; Byun, Myung-Woo; Lee, Ju-Woon

    2008-12-01

    In this study, the effects of an electron beam irradiation on the viscosity of a carboxymethylcellulose (CMC) solution were investigated. The viscosity of the CMC solution was decreased with an increase in the irradiation dose. Interestingly, the extent of the degradation of the CMC was found to decrease with an increase of the CMC concentration in the solution. The change of the average molar mass confirmed the decrease in the viscosity due to the degradation of the polymer. The energy of the electron beam also affected the degradation of the CMC. Lower degradation of the CMC was obtained with a decreasing electron beam energy due to its lower penetration. Addition of vitamin C as a radical scavenger to the solution and an irradiation at -70 °C were shown to be moderately effective in preventing a decrease in the viscosity of the solution by irradiation.

  19. Effect of electron beam irradiation on the viscosity of carboxymethylcellulose solution

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Jong-il [Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute, 1266 Sinjeong-dong, Jeongeup 580-185 (Korea, Republic of); Lee, Hee-Sub [Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute, 1266 Sinjeong-dong, Jeongeup 580-185 (Korea, Republic of); Department of Food and Nutrition, Chungnam National University, Daejeon 305-764 (Korea, Republic of); Kim, Jae-Hun [Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute, 1266 Sinjeong-dong, Jeongeup 580-185 (Korea, Republic of); Lee, Kwang-Won [Department of Orthopaedic Surgery, Eulji University School of Medicine, Daejeon 302-799 (Korea, Republic of); Chung, Young-Jin [Department of Food and Nutrition, Chungnam National University, Daejeon 305-764 (Korea, Republic of); Byun, Myung-Woo [Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute, 1266 Sinjeong-dong, Jeongeup 580-185 (Korea, Republic of); Lee, Ju-Woon [Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute, 1266 Sinjeong-dong, Jeongeup 580-185 (Korea, Republic of)], E-mail: sjwlee@kaeri.re.kr

    2008-12-15

    In this study, the effects of an electron beam irradiation on the viscosity of a carboxymethylcellulose (CMC) solution were investigated. The viscosity of the CMC solution was decreased with an increase in the irradiation dose. Interestingly, the extent of the degradation of the CMC was found to decrease with an increase of the CMC concentration in the solution. The change of the average molar mass confirmed the decrease in the viscosity due to the degradation of the polymer. The energy of the electron beam also affected the degradation of the CMC. Lower degradation of the CMC was obtained with a decreasing electron beam energy due to its lower penetration. Addition of vitamin C as a radical scavenger to the solution and an irradiation at -70 deg. C were shown to be moderately effective in preventing a decrease in the viscosity of the solution by irradiation.

  20. Gluon gas viscosity in nonperturbative region

    International Nuclear Information System (INIS)

    Il'in, S.V.; Mogilevskij, O.A.; Smolyanskij, S.A.; Zinov'ev, G.M.

    1992-01-01

    Using the Green-Kubo-type formulae and the cutoff model motivated by Monte Carlo lattice gluodynamics simulations we find the temperature behaviour of shear viscosity of gluon gas in the region of deconfinement phase transition. 22 refs.; 1 fig. (author)

  1. Resin Viscosity Influence on Fiber Compaction in Tapered Resin Injection Pultrusion Manufacturing

    Science.gov (United States)

    Masuram, N. B.; Roux, J. A.; Jeswani, A. L.

    2018-06-01

    Viscosity of the liquid resin effects the chemical and mechanical properties of the pultruded composite. In resin injection pultrusion manufacturing the liquid resin is injected into a specially designed tapered injection chamber through the injection slots present on top and bottom of the chamber. The resin is injected at a pressure so as to completely wetout the fiber reinforcements inside the tapered injection chamber. As the resin penetrates through the fibers, the resin also pushes the fibers away from the wall towards the center of chamber causing compaction of the fiber reinforcements. The fibers are squeezed together due to compaction, making resin penetration more difficult; thus higher resin injection pressures are required to efficaciously penetrate through the compacted fibers and achieve complete wetout. The impact of resin viscosity on resin flow, fiber compaction, wetout and on the final product is further discussed. Injection chamber design predominantly effects the resin flow inside the chamber and the minimum injection pressure required to completely wet the fibers. Therefore, a desirable injection chamber design is such that wetout occurs at lower injection pressures and at low internal pressures inside the injection chamber.

  2. A Deoxyuridine-Based Far-Red Emitting Viscosity Sensor.

    Science.gov (United States)

    Wang, Mengyuan; Zhang, Yuanwei; Yue, Xiling; Yao, Sheng; Bondar, Mykhailo V; Belfield, Kevin D

    2016-05-30

    A novel deoxyuridine (dU) benzothiazolium (BZ) derivative, referred to as dU-BZ, is reported that was synthesized via Sonogashira coupling reaction methodology. The deoxyuridine building block was introduced to enhance hydrophilicity, while an alkynylated benzothiazolium dye was incorporated for long wavelength absorption to reduce potential phototoxicity that is characteristic of using UV light to excite common fluorphores, better discriminate from native autofluorescence, and potentially facilitate deep tissue imaging. An impressive 30-fold enhancement of fluorescence intensity of dU-BZ was achieved upon increasing viscosity. Fluorescence quantum yields in 99% glycerol/1% methanol (v/v) solution as a function of temperature (293-343 K), together with viscosity-dependent fluorescence lifetimes and radiative and non-radiative rate constants in glycerol/methanol solutions (ranging from 4.8 to 950 cP) were determined. Both fluorescence quantum yields and lifetimes increased with increased viscosity, consistent with results predicted by theory. This suggests that the newly-designed compound, dU-BZ, is capable of functioning as a probe of local microviscosity, an aspect examined by in vitro bioimaging experiments.

  3. A Deoxyuridine-Based Far-Red Emitting Viscosity Sensor

    Directory of Open Access Journals (Sweden)

    Mengyuan Wang

    2016-05-01

    Full Text Available A novel deoxyuridine (dU benzothiazolium (BZ derivative, referred to as dU-BZ, is reported that was synthesized via Sonogashira coupling reaction methodology. The deoxyuridine building block was introduced to enhance hydrophilicity, while an alkynylated benzothiazolium dye was incorporated for long wavelength absorption to reduce potential phototoxicity that is characteristic of using UV light to excite common fluorphores, better discriminate from native autofluorescence, and potentially facilitate deep tissue imaging. An impressive 30-fold enhancement of fluorescence intensity of dU-BZ was achieved upon increasing viscosity. Fluorescence quantum yields in 99% glycerol/1% methanol (v/v solution as a function of temperature (293–343 K, together with viscosity-dependent fluorescence lifetimes and radiative and non-radiative rate constants in glycerol/methanol solutions (ranging from 4.8 to 950 cP were determined. Both fluorescence quantum yields and lifetimes increased with increased viscosity, consistent with results predicted by theory. This suggests that the newly-designed compound, dU-BZ, is capable of functioning as a probe of local microviscosity, an aspect examined by in vitro bioimaging experiments.

  4. Structural and molecular basis of starch viscosity in hexaploid wheat.

    Science.gov (United States)

    Ral, J-P; Cavanagh, C R; Larroque, O; Regina, A; Morell, M K

    2008-06-11

    Wheat starch is considered to have a low paste viscosity relative to other starches. Consequently, wheat starch is not preferred for many applications as compared to other high paste viscosity starches. Increasing the viscosity of wheat starch is expected to increase the functionality of a range of wheat flour-based products in which the texture is an important aspect of consumer acceptance (e.g., pasta, and instant and yellow alkaline noodles). To understand the molecular basis of starch viscosity, we have undertaken a comprehensive structural and rheological analysis of starches from a genetically diverse set of wheat genotypes, which revealed significant variation in starch traits including starch granule protein content, starch-associated lipid content and composition, phosphate content, and the structures of the amylose and amylopectin fractions. Statistical analysis highlighted the association between amylopectin chains of 18-25 glucose residues and starch pasting properties. Principal component analysis also identified an association between monoesterified phosphate and starch pasting properties in wheat despite the low starch-phosphate level in wheat as compared to tuber starches. We also found a strong negative correlation between the phosphate ester content and the starch content in flour. Previously observed associations between internal starch granule fatty acids and the swelling peak time and pasting temperature have been confirmed. This study has highlighted a range of parameters associated with increased starch viscosity that could be used in prebreeding/breeding programs to modify wheat starch pasting properties.

  5. Green-Kubo relations for the viscosity of biaxial nematic liquid crystals

    Science.gov (United States)

    Sarman, Sten

    1996-09-01

    We derive Green-Kubo relations for the viscosities of a biaxial nematic liquid crystal. In this system there are seven shear viscosities, three twist viscosities, and three cross coupling coefficients between the antisymmetric strain rate and the symmetric traceless pressure tensor. According to the Onsager reciprocity relations these couplings are equal to the cross couplings between the symmetric traceless strain rate and the antisymmetric pressure. Our method is based on a comparison of the microscopic linear response generated by the SLLOD equations of motion for planar Couette flow (so named because of their close connection to the Doll's tensor Hamiltonian) and the macroscopic linear phenomenological relations between the pressure tensor and the strain rate. In order to obtain simple Green-Kubo relations we employ an equilibrium ensemble where the angular velocities of the directors are identically zero. This is achieved by adding constraint torques to the equations for the molecular angular accelerations. One finds that all the viscosity coefficients can be expressed as linear combinations of time correlation function integrals (TCFIs). This is much simpler compared to the expressions in the conventional canonical ensemble, where the viscosities are complicated rational functions of the TCFIs. The reason for this is, that in the constrained angular velocity ensemble, the thermodynamic forces are given external parameters whereas the thermodynamic fluxes are ensemble averages of phase functions. This is not the case in the canonical ensemble. The simplest way of obtaining numerical estimates of viscosity coefficients of a particular molecular model system is to evaluate these fluctuation relations by equilibrium molecular dynamics simulations.

  6. Detection of irradiated peppers by viscosity measurement at extremely high pH

    International Nuclear Information System (INIS)

    Hayashi, Toru; Todoriki, Setsuko

    1996-01-01

    The viscosities of aqueous suspensions of irradiated peppers determined after heat gelatinization were influenced by the pH of the suspension to a greater degree than those of unirradiated ones. Viscosity measurement under an extremely alkaline condition (pH 13.8) resulted in a significant different between irradiated peppers and unirradiated ones, irrespective of the planting locality and storage period. All of the pepper samples irradiated at 5 kGy showed viscosity values significantly lower than unirradiated ones. (Author)

  7. Boundary layers and the vanishing viscosity limit for incompressible 2D flow

    OpenAIRE

    Filho, Milton C. Lopes

    2007-01-01

    This manuscript is a survey on results related to boundary layers and the vanishing viscosity limit for incompressible flow. It is the lecture notes for a 10 hour minicourse given at the Morningside Center, Academia Sinica, Beijing, PRC from 11/28 to 12/07, 2007. The main topics covered are: a derivation of Prandtl's boundary layer equation; an outline of the rigorous theory of Prandtl's equation, without proofs; Kato's criterion for the vanishing viscosity limit; the vanishing viscosity limi...

  8. Measuring the density and viscosity of H2S-loaded aqueous methyldiethanolamine solution

    International Nuclear Information System (INIS)

    Shokouhi, Mohammad; Ahmadi, Reza

    2016-01-01

    Highlights: • Measurement solubility of H 2 S in 46.78 mass% MDEA aqueous solutions. • Measurement density of H 2 S loaded of MDEA aqueous solution. • Measurement viscosity of H 2 S loaded of MDEA aqueous solution. • Correlation of the density and viscosity of H 2 S loaded of MDEA aqueous solution using modified setchenow equation. - Abstract: The density and viscosity of H 2 S-loaded aqueous 46.78 mass% methyldiethanolamine solution were experimentally measured accompanied with the solubility of H 2 S at temperatures (313.15, 328.15 and 343.15) K, pressures from vapor pressure of fresh solution up to 1.0 MPa and loadings up to 1.00 mol of H 2 S per 1 mol of amine. All experimental trials have been carried out using the new setup developed in our laboratory. It was observed that both density and viscosity of mixtures decrease by increasing temperature and density increase by increasing acid gas solubility (loading) by about 4.7%, whereas viscosity has a complicated behavior with H 2 S solubility. Viscosity decreases by increasing acid gas solubility (loading) at 313.15 K by about 20.6% and at 328.15 K by about 15.0%, but it is comparable at 343.15 K in terms of H 2 S solubility. Finally, the experimental density and viscosity data correlated using Modified Setchenow equation.

  9. Effects of the positioning force of electrostatic levitators on viscosity measurements

    International Nuclear Information System (INIS)

    Ishikawa, Takehiko; Paradis, Paul-Francois; Koike, Noriyuki; Watanabe, Yuki

    2009-01-01

    Electrostatic levitators use strong electric fields to levitate and accurately position a sample against gravity. In this study, the effects of the electric field are investigated with regard to viscosity measurements conducted with the oscillating drop method. The effects of the external field on viscosity measurements are experimentally confirmed by changing the sample size. Moreover, a numerical simulation based on a simple mass-spring-damper system can reproduce the experimental observations. Based on the above results, measurement procedures are improved. These help to minimize the effect of the positioning force and to increase the accuracy of the viscosity measurements.

  10. Deep and wide gaps by super Earths in low-viscosity discs

    Science.gov (United States)

    Ginzburg, Sivan; Sari, Re'em

    2018-06-01

    Planets can open cavities (gaps) in the protoplanetary gaseous discs in which they are born by exerting gravitational torques. Viscosity counters these torques and limits the depletion of the gaps. We present a simple one-dimensional scheme to calculate the gas density profile inside gaps by balancing the gravitational and viscous torques. By generalizing the results of Goodman & Rafikov (2001), our scheme properly accounts for the propagation of angular momentum by density waves. This method allows us to easily study low-viscosity discs, which are challenging for full hydrodynamical simulations. We complement our numerical integration by analytical equations for the gap's steady-state depth and width as a function of the planet's to star's mass ratio μ, the gas disc's aspect ratio h, and its Shakura & Sunyaev viscosity parameter α. Specifically, we focus on low-mass planets (μ < μth ≡ h3) and identify a new low-viscosity regime, α < h(μ/μth)5, in which the classical analytical scaling relations are invalid. Equivalently, this low-viscosity regime applies to every gap that is depleted by more than a factor of (μth/μ)3 relative to the unperturbed density. We show that such gaps are significantly deeper and wider than previously thought, and consequently take a longer time to reach equilibrium.

  11. Viscosity measurement - probably a means for detecting radiation treatment of spices?

    International Nuclear Information System (INIS)

    Heide, L.; Albrich, S.; Boegl, K.W.

    1987-12-01

    The viscosity of 13 different spices and dried vegetables in total was measured. Optimal conditions were first determined for each product, i.e. concentration, pH-value, temperature, particle size and soaking time. For method evaluation, examinations were primarily performed to study the effect of storage, the reproducibility and the influence of the different varieties of the same spice. In supplement, for pepper, the viscosity was measured as a function of radiation dose. In summation, significant changes in the gel forming capability after irradiation could be observed after preliminary experiments in 8 dried spices (ginger, carrots, leek, cloves, pepper, celery, cinnamon and onions). With 3 spices (ginger, pepper and cinnamon) could the results from examining all different varieties of the same spice be substantiated. An additional influence of storage time on viscosity could not be proved during the investigative period of 8 months. Generally seen, there is no possibility of being able to identify an irradiated spice on the basis of viscosity measurements alone, since the difference between the varieties of one and the same spice is considerably great. However, radiation treatment can be reliably excluded with ginger, pepper and cinnamon, if the viscosities are high (10-20 Pa x s). (orig./MG) [de

  12. Effect of Polyvinyl Siloxane Viscosity on Accuracy of Dental Implant Impressions

    Directory of Open Access Journals (Sweden)

    Ahmad Ghahremanloo

    2017-02-01

    Full Text Available Objectives: The aim of this study was to compare the accuracy of dental implant impressions obtained by a combination of different impression techniques and viscosities of polyvinyl siloxane (PVS.Materials and Methods: Four parallel fixtures were placed between mental foramina in a master model of lower dental arch. Three different viscosities (putty/light body, medium body/light body, and monophase: heavy body and direct and indirect techniques (six groups were used, and seven impressions were obtained from each group (n=42. To measure the accuracy of impressions, drift, horizontal, and vertical angles of the implants, as well as the hex rotation of the implants in casts were evaluated using a digitizer device (1μm accuracy, in comparison with master arch. Data were analyzed using five-factor two-way ANOVA and Tukey’s post-hoc test.Results: The accuracy of impressions was assessed and the results showed that direct technique was not significantly different from indirect technique (P>0.05. Also, there were no significant differences between the mentioned viscosities except for the horizontal angle (P=0.006.Conclusions: Viscosity of impression materials is of high significance for the accuracy of dental impressions.Keywords: Dental Materials; Dental Implants; Dental Impression Technique; Viscosity; Vinyl Polysiloxane; Dimensional Measurement Accuracy

  13. Assessing Potential Additional PFAS Retention Processes in the Subsurface

    Science.gov (United States)

    Brusseau, M. L.

    2017-12-01

    Understanding the transport and fate of per- and poly-fluorinated alkyl substances (PFASs) in the subsurface is critical for accurate risk assessments and design of effective remedial actions. Current conceptual and mathematical models are based on an assumption that solid-phase adsorption is the sole source of retention for PFASs. However, additional retention processes may be relevant for PFAS compounds in vadose-zone systems and in source zones that contain trapped immiscible organic liquids. These include adsorption at the air-water interface, partitioning to the soil atmosphere, adsorption at the NAPL-water interface, and absorption by NAPL. A multi-process retention model is proposed to account for these potential additional sources of PFAS retardation. An initial assessment of the relative magnitudes and significance of these retention processes was conducted for three representative PFASs, perfluorooctanoic acid (PFOA), perfluorooctane sulfonate (PFOS), and 8:2 fluorotelomer alcohol (FTOH). Data collected from the literature were used to determine measured or estimated values for the relevant distribution coefficients, which were in turn used to calculate retardation factors for a representative porous medium. Adsorption at the air-water interface was shown to be a primary source of retention for PFOA and PFOS, contributing approximately 80% of total retardation. Adsorption to NAPL-water interfaces and absorption by bulk NAPL were also shown to be significant sources of retention for PFOS and PFOA. The latter process was the predominant source of retention for 8:2 FTOH, contributing 98% of total retardation. These results indicate that we may anticipate significant retention of PFASs by these additional processes. In such cases, retardation of PFASs in source areas may be significantly greater than what is typically estimated based on the standard assumption of solid-phase adsorption as the sole retention mechanism. This has significant ramifications for

  14. Retention measurements of nanofiltration membranes with electrolyte solutions

    NARCIS (Netherlands)

    Peeters, J.M.M.; Peeters, J.M.M.; Boom, J.P.; Boom, J.P.; Mulder, M.H.V.; Strathmann, H.

    1998-01-01

    Retention measurements with single salt solutions of CaCl2, NaCl and Na2SO4 revealed that the rejection mechanism of commercial polymeric nanofiltration membranes investigated in this study may be divided into two categories: 1. Membranes for which Donnan exclusion seems to play an important role.

  15. The effect of low molecular weight multifunctional additives on heavy oil viscosity

    Energy Technology Data Exchange (ETDEWEB)

    Oldenburg, T.B.P.; Yarranton, H.W.; Larter, S.R. [Calgary Univ., AB (Canada)

    2010-07-01

    Crude oils contain many small multifunctional low molecular weight components that act as linking molecules between larger functionalized species. The linkage molecules have a significant impact on the flow properties of hydrocarbon systems. This study investigated the use of a low molecular weight multiheteroatom species (LMWMH) as a molecular Velcro linking high molecular weight components together. LMWMH species were added to Albertan bitumens and heavy oil, and their impact on viscosity was investigated. Results of the experimental studies were then compared with the effects of hydrocarbon solvents on similar samples. The LMWMH species included bifunctional species and analogous alkyl and aryl monoamines that acted as blocking molecules to hinder the association of larger petroleum species. Density and viscosity measurements were conducted. A correlation method was used to predict the viscosity of the solvent-diluted heavy oil and bitumen samples. The study showed that of the tested additives, only aniline demonstrated an additional viscosity-reducing effect. The aniline inhibited asphaltene association and is a promising candidate for enhanced in-situ bitumen viscosity reduction. 23 refs., 4 tabs.

  16. Shear viscosity of the quark-gluon plasma in a kinetic theory approach

    International Nuclear Information System (INIS)

    Puglisi, A.; Plumari, S.; Scardina, F.; Greco, V.

    2014-01-01

    One of the main results of heavy ions collision (HIC) at relativistic energy experiments is the very small shear viscosity to entropy density ratio of the Quark-Gluon Plasma, close to the conjectured lower bound η/s=1/4π for systems in the infinite coupling limit. Transport coefficients like shear viscosity are responsible of non-equilibrium properties of a system: Green-Kubo relations give us an exact expression to compute these coefficients. We compute shear viscosity numerically using Green-Kubo relation in the framework of Kinetic Theory solving the relativistic transport Boltzmann equation in a finite box with periodic boundary conditions. We investigate a system of particles interacting via anisotropic and energy dependent cross-section in the range of temperature of interest for HIC. Green-Kubo results are in agreement with Chapman-Enskog approximation while Relaxation Time approximation can underestimates the viscosity of a factor 2. The correct analytic formula for shear viscosity can be used to develop a transport theory with a fixed η/s and have a comparison with physical observables like elliptic flow

  17. Magnetic viscosity study in FePt/C granular films

    International Nuclear Information System (INIS)

    Huang, Y.; Butler, W.; Zhang, Y.; Hadjipanayis, G.C.; Weller, D.

    2004-01-01

    The magnetic viscosity of FePt/C granular thin films was studied in the temperature range from 2 to 300 K in order to examine the thermal stability of the nanoparticles. The magnetic viscosity coefficient (S max ) was found to decrease with temperature because of decreased thermal activation. At low temperatures, S max showed an almost linear dependence on temperature. However, S max does not extrapolate to zero but seems to have a finite value at cryogenic temperatures

  18. Coefficients of viscosity for heavy impurity element in tokamak

    Energy Technology Data Exchange (ETDEWEB)

    El-Sharif, R N; Bekhit, A M [Plasma Physics dept., NRC, Atomic energy Authority, Cairo, (Egypt)

    1997-12-31

    The transport of heavy impurity element in to tokamak was studied theoretically. The viscosity coefficients of chromium impurities has been calculated in 13 and 21 moment approximation, in the limit of strong fields where is the gyrofrequency of species it was found that the off diagonal coefficient approximately tends to zero. This means that the friction force in the off-diagonal direction is very small, for the perpendicular viscosity coefficient the two approximation coincide to each other. 3 figs.

  19. Effect of gamma irradiation on viscosity of aqueous solutions of some natural polymers

    International Nuclear Information System (INIS)

    Nguyen Tan Man; Truong Thi Hanh; Le Quang Luan; Le Hai; Nguyen Quoc Hien

    2000-01-01

    Effect of gamma irradiation on viscosity of aqueous solution of alginate and carbon xylmethyl cellulose (CMC) irradiated in solid state has been carried out. the viscosity of aqueous solution of alginate and CMC decreased remarkably with increasing dose and the viscosity of 2% solution of above polymers irradiated at 50 kGy was about 100 times lower than the original one. (author)

  20. Pipeline flow of heavy oil with temperature-dependent viscosity

    Energy Technology Data Exchange (ETDEWEB)

    Maza Quinones, Danmer; Carvalho, Marcio da Silveira [Pontifical Catholic University of Rio de Janeiro (PUC-Rio), RJ (Brazil). Dept. of Mechanical Engineering], E-mail: msc@puc-rio.br

    2010-07-01

    The heavy oil produced offshore needs to be transported through pipelines between different facilities. The pipelines are usually laid down on the seabed and are submitted to low temperatures. Although heavy oils usually present Newtonian behavior, its viscosity is a strong function of temperature. Therefore, the prediction of pressure drops along the pipelines should include the solution of the energy equation and the dependence of viscosity to temperature. In this work, an asymptotic model is developed to study this problem. The flow is considered laminar and the viscosity varies exponentially with temperature. The model includes one-dimensional equations for the temperature and pressure distribution along the pipeline at a prescribed flow rate. The solution of the coupled differential equation is obtained by second-order finite difference. Results show a nonlinear behavior as a result of coupled interaction between the velocity, temperature, and temperature dependent material properties. (author)

  1. Estimation of shear viscosity based on transverse momentum correlations

    International Nuclear Information System (INIS)

    Sharma, Monika

    2009-01-01

    Event anisotropy measurements at RHIC suggest the strongly interacting matter created in heavy ion collisions flows with very little shear viscosity. Precise determination of 'shear viscosity-to-entropy' ratio is currently a subject of extensive study [S. Gavin and M. Abdel-Aziz, Phys. Rev. Lett. 97 (2006) 162302]. We present preliminary results of measurements of the evolution of transverse momentum correlation function with collision centrality of Au+Au interactions at √(s NN )=200 GeV. We compare two differential correlation functions, namely inclusive [J. Adams et al. (STAR Collaboration), Phys. Rev. C 72 (2005) 044902] and a differential version of the correlation measure C introduced by Gavin et al. [S. Gavin and M. Abdel-Aziz, Phys. Rev. Lett. 97 (2006) 162302; M. Sharma and C. A. Pruneau, Phys. Rev. C 79 (2009) 024905.]. These observables can be used for the experimental study of the shear viscosity per unit entropy.

  2. Estimation of shear viscosity based on transverse momentum correlations

    Science.gov (United States)

    STAR Collaboration; Sharma, Monika; STAR Collaboration

    2009-11-01

    Event anisotropy measurements at RHIC suggest the strongly interacting matter created in heavy ion collisions flows with very little shear viscosity. Precise determination of “shear viscosity-to-entropy” ratio is currently a subject of extensive study [S. Gavin and M. Abdel-Aziz, Phys. Rev. Lett. 97 (2006) 162302]. We present preliminary results of measurements of the evolution of transverse momentum correlation function with collision centrality of Au+Au interactions at s=200 GeV. We compare two differential correlation functions, namely inclusive [J. Adams et al. (STAR Collaboration), Phys. Rev. C 72 (2005) 044902] and a differential version of the correlation measure C˜ introduced by Gavin et al. [S. Gavin and M. Abdel-Aziz, Phys. Rev. Lett. 97 (2006) 162302; M. Sharma and C. A. Pruneau, Phys. Rev. C 79 (2009) 024905.]. These observables can be used for the experimental study of the shear viscosity per unit entropy.

  3. Dependence of Helium II viscosity properties on oscillation frequency

    International Nuclear Information System (INIS)

    Nadirashvili, Z.S.; Tsakadze, J.S.

    1979-01-01

    The causes of a discrepancy in the results of measurements of He II viscosity below Tapprox. =1.6 K obtained with different measurement methods are investigated. It is shown that to obtain correct results in oscillation experiments, the condition delta>>lambda/sub ph/ should obtain, where delta is the depth of viscous wave penetration and lambda/sub ph/ is the phonon free path length. Results of viscosity measurements at different ratios delta/lambda/sub ph/ (by a wire viscometer) are presented. It is shown that for the condition delta>>lambda/sub ph/, the results obtained are in good agreement with the results of Andronikashvili (in which delta/lambda/sub ph/>100). If the mentioned relation is not satisfied, then as the value of the ratio delta/lambda/sub ph/ is decreased, the value measured for the viscosity is increasingly lower than the results of Andronikashvili

  4. Influence of fluid viscosity on vortex cavitation at a suction pipe inlet

    International Nuclear Information System (INIS)

    Ezure, Toshiki; Ito, Kei; Kamide, Hideki; Kameyama, Yuri; Kunugi, Tomoaki

    2016-01-01

    Cavitation is a highly important issue in various fluid machineries. In the design of an advanced loop-type sodium-cooled fast reactor in Japan, vortex cavitation is also a significant issue for the integrity of the reactor structure. Thus, an evaluation method for vortex cavitation is required. In this study, vortex cavitation at a single suction pipe inlet was studied under several different viscosity conditions including its transient behavior. The intermittent occurrence behaviors of vortex cavitation were grasped by visualization measurements. The experimental results showed that the influence of the kinematic viscosity was obvious under a high kinematic viscosity. However, the influence became smaller with decreasing kinematic viscosity. From these results, the non-dimensional circulation, which was defined as the ratio of the local circulation to the kinematic viscosity, was deduced as an evaluation parameter to estimate the influence of the kinematic viscosity. Cavitation factors at transition points from continuous occurrence to intermittent occurrences were also evaluated as representative points where vortex cavitation occurs. Then, the occurrences of vortex cavitation were expressed as a relation between the cavitation factor at transition points and the non-dimensional circulation. As a result, it was clarified that the cavitation factor at transition points increased linearly in relatively small non-dimensional circulation, while it was nearly constant in relatively large non-dimensional circulation. (author)

  5. Electron-processing technology: A promising application for the viscose industry

    Science.gov (United States)

    Stepanik, T. M.; Rajagopal, S.; Ewing, D.; Whitehouse, R.

    1998-06-01

    In marketing its IMPELA ® line of high power, high-throughput industrial accelerators, Atomic Energy of Canada Limited (AECL) is working with viscose (rayon) companies world-wide to integrate electron-processing technology as part of the viscose manufacturing process. The viscose industry converts cellulose wood pulp into products such as staple fiber, filament, cord, film, packaging, and non-edible sausage casings. This multibillion dollar industry is currently suffering from high production costs, and is facing increasingly stringent environmental regulations. The use of electron-treated pulp can significantly lower production costs and can provide equally significant environmental benefits. This paper describes our current understanding of the benefits of using electron-treated pulp in this process, and AECL's efforts in developing this technology.

  6. Fission product retention during faults involving steam generator tube rupture

    International Nuclear Information System (INIS)

    Rodliffe, R.S.

    1983-08-01

    In some PWR fault conditions, such as stuck open safety relief valve in the secondary circuit or main steam line break, the release of fission products to the atmosphere may be increased by the leakage of primary coolant into the secondary circuit following steam generator tube rupture. The release may be reduced by retention either within the primary circuit or within the affected steam generator unit (SGU). The mechanisms leading to retention are reviewed and quantified where possible. The parameters on which any analysis will be most critically dependent are identified. Fission product iodine and caesium may be retained in the secondary side of a SGU either by partition to retained water or by droplet deposition on surfaces and subsequent evaporation to dryness. Two extreme simplifications are considered: SGU 'dry', i.e. the secondary side is steam filled, and SGU 'wet', i.e. the tube bundle is covered with water. Consideration is given to: the distribution of fission products between gaseous and aerosol forms; mechanisms for droplet formation, deposition and resuspension; fission product retention during droplet or film evaporation primary coolant mixing and droplet scrubbing in a wet SGU; and the performance of moisture separators and steam driers. (author)

  7. Excess Molar Volumes and Viscosities of Binary Mixture of Diethyl Carbonate+Ethanol at Different Temperatures

    Institute of Scientific and Technical Information of China (English)

    MA Peisheng; LI Nannan

    2005-01-01

    The purpose of this work was to report excess molar volumes and dynamic viscosities of the binary mixture of diethyl carbonate (DEC)+ethanol. Densities and viscosities of the binary mixture of DEC+ethanol at temperatures 293.15 K-343.15 K and atmospheric pressure were determined over the entire composition range. Densities of the binary mixture of DEC+ethanol were measured by using a vibrating U-shaped sample tube densimeter. Viscosities were determined by using Ubbelohde suspended-level viscometer. Densities are accurate to 1.0×10-5 g·cm-3, and viscosities are reproducible within ±0.003 mPa·s. From these data, excess molar volumes and deviations in viscosity were calculated. Positive excess molar volumes and negative deviations in viscosity for DEC+ethanol system are due to the strong specific interactions.All excess molar vo-lumes and deviations in viscosity fit to the Redlich-Kister polynomial equation.The fitting parameters were presented,and the average deviations and standard deviations were also calculated.The errors of correlation are very small.It proves that it is valuable for estimating densities and viscosities of the binary mixture by the correlated equation.

  8. Recombinant human DNase I reduces the viscosity of cystic fibrosis sputum.

    Science.gov (United States)

    Shak, S; Capon, D J; Hellmiss, R; Marsters, S A; Baker, C L

    1990-12-01

    Respiratory distress and progressive lung destruction in cystic fibrosis can be attributed to bacterial persistence and the accumulation of viscous purulent secretions in the airways. More than 30 yr ago it was suggested that the large amounts of DNA in purulent secretions contribute to its viscosity and that bovine pancreatic DNase I could reduce the viscosity. To evaluate the potential clinical utility of recombinant human DNase I (rhDNase) in the treatment of cystic fibrosis, we have cloned, sequenced, and expressed rhDNase. Catalytic amounts of rhDNase greatly reduce the viscosity of purulent cystic fibrosis sputum, transforming it within minutes from a nonflowing viscous gel to a flowing liquid. The reduction in viscosity is associated with a decrease in size of DNA in the sputum. Inhalation of a rhDNase aerosol may be a simple direct approach that will help individuals with cystic fibrosis and other patients with pneumonia or bronchitis to clear their airways of purulent secretions.

  9. Viscosity and Analytical Differences between Raw Milk and UHT Milk of Czech Cows

    Directory of Open Access Journals (Sweden)

    Kumbár V.

    2015-06-01

    Full Text Available Viscosity and analytical differences in four milk samples from Czech cows were described. Three samples of UHT milk (0.5%, 1.5%, and 3.5% fat and one sample of raw milk from a Czech bio-farm were analyzed. The following analytical properties were observed: titratable acidity, fat content, dry matter content, and protein content. Titratable acidity and dry matter content decreased in dependence upon the increasing milk fat content. The protein content ranged 3.51-3.57 g per 100 g milk. The milk flow behaviour represented by density, dynamic and kinematic viscosity, as well as the dependence of the milk flow behaviour on temperature were investigated. These properties were measured using a digital densitometer and a rotary viscometer. Milk density was studied at temperatures ranging 0-60 °C and dynamic viscosity at 0-100 °C. With increasing temperature, the density and dynamic viscosity of the studied milk samples decreased. The temperature dependence of dynamic viscosity was manifested in all samples. Kinematic viscosity was calculated from experimental data. Furthermore, mathematical models using Power law and Gaussian fitting were constructed. Determination coefficients achieved high values (0.843-0.997.

  10. Effect of Qingnao tablet on blood viscosity of rat model of blood stasis induced by epinephrine

    Science.gov (United States)

    Xie, Guoqi; Hao, Shaojun; Ma, Zhenzhen; Liu, Xiaobin; Li, Jun; Li, Wenjun; Zhang, Zhengchen

    2018-04-01

    To establish a rat model of blood stasis with adrenaline (Adr) subcutaneous injection and ice bath stimulation. The effects of different doses on the blood viscosity of blood stasis model rats were observed. The rats were randomly divided into 6 groups: blank control group (no model), model group, positive control group, high, middle and low dose group. The whole blood viscosity and plasma viscosity were detected by blood viscosity instrument. Compared with the blank group, model group, high shear, low shear whole blood viscosity and plasma viscosity were significantly increased, TT PT significantly shortened, APTT was significantly prolonged, FIB increased significantly, indicating that the model was successful. Compared with the model group, can significantly reduce the Naoluotong group (cut, low cut). Qingnaopian high dose group (low cut), middle dose group (cut, low shear blood viscosity) (Pgroup, high dose group (Pgroup (Pblood rheology of blood stasis mice abnormal index, decrease the blood viscosity, blood stasis has certain hemostatic effect.

  11. The effectivity of bentonites in cesium retention of cemented waste products; Efetividade das bentonitas na retencao de cesio em produtos de rejeitos cimentados

    Energy Technology Data Exchange (ETDEWEB)

    Tello, Cledola Cassia Oliveira de

    2001-01-15

    The nuclear energy has been used for the human development in different areas, as in the medicine, in the agriculture, in the industry and in the environmental protection, besides the electricity generation. As in other activities, in the use of nuclear energy, residues are also generated. They are considered radioactive wastes when the contaminant content can bring a potential negative impact in the human health and in the environment. In this case they should be properly managed and should not be released without treatment. In general the waste processing consists in a volume reduction followed by solidification and/or conditioning. A number of materials can be considered as immobilisation matrices for the wastes, with the objective of maintain the radioactive material physical and chemically stable. The cement is extensively used because it is easy to obtain, there is large. experience in its use and the processing is done at room temperature. Many materials have been studied to improve the fixation characteristics of the radionuclides in the cemented product. The aim of this study was to search, among Brazilian natural materials, those that could be effective in the contaminant retention without jeopardising the process and other characteristics of the waste product. Four types of bentonite were selected to the process and product evaluation tests. Many mixtures were prepared with simulated waste, cement and bentonite in different proportions. The viscosity, set time, compressive strength and leaching were evaluated. In addition it was verified if the products were monolithic and without free water. Inactive caesium was used as tracer. The leaching resistance is the most important parameter in the product evaluation, because it indicates the retention capacity of the matrix for radionuclides when the product is in contact with the water. In 1985 leaching tests were begun and they have been continued till now and from their results it was proved that the

  12. Reduced viscosity for flagella moving in a solution of long polymer chains

    Science.gov (United States)

    Zhang, Yuchen; Li, Gaojin; Ardekani, Arezoo M.

    2018-02-01

    The bacterial flagellum thickness is smaller than the radius of gyration of long polymer chain molecules. The flow velocity gradient over the length of polymer chains can be nonuniform and continuum models of polymeric liquids break in this limit. In this work, we use Brownian dynamics simulations to study a rotating helical flagellum in a polymer solution and overcome this limitation. As the polymer size increases, the viscosity experienced by the flagellum asymptotically reduces to the solvent viscosity. The contribution of polymer molecules to the local viscosity in a solution of long polymer chains decreases with the inverse of polymer size to the power 1/2. The difference in viscosity experienced by the bacterial cell body and flagella can predict the nonmonotonic swimming speed of bacteria in polymer solutions.

  13. Fluid friction and wall viscosity of the 1D blood flow model.

    Science.gov (United States)

    Wang, Xiao-Fei; Nishi, Shohei; Matsukawa, Mami; Ghigo, Arthur; Lagrée, Pierre-Yves; Fullana, Jose-Maria

    2016-02-29

    We study the behavior of the pulse waves of water into a flexible tube for application to blood flow simulations. In pulse waves both fluid friction and wall viscosity are damping factors, and difficult to evaluate separately. In this paper, the coefficients of fluid friction and wall viscosity are estimated by fitting a nonlinear 1D flow model to experimental data. In the experimental setup, a distensible tube is connected to a piston pump at one end and closed at another end. The pressure and wall displacements are measured simultaneously. A good agreement between model predictions and experiments was achieved. For amplitude decrease, the effect of wall viscosity on the pulse wave has been shown as important as that of fluid viscosity. Copyright © 2016 Elsevier Ltd. All rights reserved.

  14. Viscosity and Liquid Density of Asymmetric n-Alkane Mixtures: Measurement and Modelling

    DEFF Research Database (Denmark)

    Queimada, António J.; Marrucho, Isabel M.; Coutinho, João A.P.

    2005-01-01

    Viscosity and liquid density Measurements were performed, at atmospheric pressure. in pure and mixed n-decane. n-eicosane, n-docosane, and n-tetracosane from 293.15 K (or above the melting point) up to 343.15 K. The viscosity was determined with a rolling ball viscometer and liquid densities...... with a vibrating U-tube densimeter. Pure component results agreed, oil average, with literature values within 0.2% for liquid density and 3% for viscosity. The measured data were used to evaluate the performance of two models for their predictions: the friction theory coupled with the Peng-Robinson equation...... of state and a corresponding states model recently proposed for surface tension, viscosity, vapor pressure, and liquid densities of the series of n-alkanes. Advantages and shortcoming of these models are discussed....

  15. Modeling of asphalt-rubber rotational viscosity by statistical analysis and neural networks

    Directory of Open Access Journals (Sweden)

    Luciano Pivoto Specht

    2007-03-01

    Full Text Available It is of a great importance to know binders' viscosity in order to perform handling, mixing, application processes and asphalt mixes compaction in highway surfacing. This paper presents the results of viscosity measurement in asphalt-rubber binders prepared in laboratory. The binders were prepared varying the rubber content, rubber particle size, duration and temperature of mixture, all following a statistical design plan. The statistical analysis and artificial neural networks were used to create mathematical models for prediction of the binders viscosity. The comparison between experimental data and simulated results with the generated models showed best performance of the neural networks analysis in contrast to the statistic models. The results indicated that the rubber content and duration of mixture have major influence on the observed viscosity for the considered interval of parameters variation.

  16. Measuring in-stream retention of copper by means of constant-rate additions.

    Science.gov (United States)

    Serra, A; Guasch, H; Martí, E; Geiszinger, A

    2009-06-01

    Human practices entail inputs of nutrients and toxicants such as heavy metals to the fluvial ecosystems. While nutrient dynamics in fluvial ecosystems have been widely studied for over three decades, dynamics of toxicants still remain unclear. In this investigation, the nutrient spiraling concept and associated methodologies to quantify nutrient retention in streams were applied to study copper (Cu) dynamics in streams. The present study aimed to quantify total dissolved Cu retention using a simplified system of indoor channels colonized with fluvial biofilms. Cu retention was studied at sub-toxic concentrations to avoid negative/lethal effects on biota. In addition, Cu retention was compared with retention estimates of a macronutrient, phosphate (PO(4)(3-)), which has been widely studied within the context of the nutrient spiraling concept. The methodology used allowed a successful quantification of Cu and PO(4)(3-) retention. The results showed higher retention efficiency for PO(4)(3-) than for Cu. The biofilm played a key role in retaining both solutes. Although retention efficiency for both solutes was higher in the experiments with colonized substrata compared to uncolonized substrata, we found a positive relationship between uptake rate and chlorophyll-a only for PO(4)(3-). Finally, retention efficiency for both solutes was influenced by water discharge, showing lower retention efficiencies under higher flow conditions. These results suggest that the fate and toxic effects of copper on stream biota may be strongly influenced by the prevailing environmental conditions. Our results indicate that the experimental approach considered can provide new insights into the investigation of retention of toxic compounds in fluvial systems and their controlling mechanisms.

  17. Magnetite effect in radionuclide retention : cesium, strontium, molybdenum and selenium

    International Nuclear Information System (INIS)

    Rovira, M.; Casas, I.; Gimenez, J.; Clarens, F.; Pablo, J. de

    2004-01-01

    In this work we have investigated the interaction of magnetite with cesium, strontium, molybdenum and selenium, in the frame of radionuclide retention by canister corrosion products. For each radionuclide, the retention on magnetite has been studied as a function of pH and the mass/ volume ratio. The experimental results have been modeled by means of Surface Complexation Models (SCM), that constitute a tool that allows an approach to sorption mechanisms in a wide range of experimental conditions taking into account electrostatic interactions at the mineral-water interface.(Author)

  18. Viscosities in the Gluon-Plasma within a Quasiparticle Model

    CERN Document Server

    Bluhm, M; Redlich, K

    2009-01-01

    A phenomenological quasiparticle model, featuring dynamically generated self-energies of excitation modes, successfully describes lattice QCD results relevant for the QCD equation of state and related quantities both at zero and non-zero net baryon density. Here, this model is extended to study bulk and shear viscosities of the gluon-plasma within an effective kinetic theory approach. In this way, the compatibility of the employed quasiparticle ansatz with the apparent low viscosities of the strongly coupled deconfined gluonic medium is shown.

  19. A mechanistic study explaining the synergistic viscosity increase obtained from polyethylene oxide (PEO) and {beta}-naphthalene sulfonate (BNS) in shotcrete

    Energy Technology Data Exchange (ETDEWEB)

    Pickelmann, J.; Plank, J., E-mail: sekretariat@bauchemie.ch.tum.de

    2012-11-15

    In shotcrete, a combination of polyethylene oxide (PEO) and {beta}-naphthalene sulfonate (BNS) is commonly applied to reduce rebound. Here, the mechanism for the synergistic viscosity increase resulting from this admixture combination was investigated via x-ray diffraction (XRD), infrared and nuclear magnetic resonance (NMR) spectroscopy. It was found that the electron-rich aromatic rings present in BNS donate electrons to the alkyl protons of PEO and thus increase the electron density there. This rare interaction is known as CH-{pi} interaction and leads to the formation of a supramolecular structure whereby PEO chains bind weakly to BNS molecules. Through this mechanism a polymer network exhibiting exceptionally high molecular weight and thus viscosity is formed. Among polycondensates, sulfanilic acid-phenol-formaldehyde (SPF) provides even higher synergy with PEO than BNS while melamine (PMS), acetone (AFS) or polycarboxylate (PCE) based superplasticizers do not work at all. Effectiveness of lignosulfonates is dependent on their degree of sulfonation.

  20. An investigation of the leaf retention capacity, efficiency and mechanism for atmospheric particulate matter of five greening tree species in Beijing, China.

    Science.gov (United States)

    Liu, Jinqiang; Cao, Zhiguo; Zou, Songyan; Liu, Huanhuan; Hai, Xiao; Wang, Shihua; Duan, Jie; Xi, Benye; Yan, Guangxuan; Zhang, Shaowei; Jia, Zhongkui

    2018-03-01

    Urban trees have the potential to reduce air pollution, but the retention capacity and efficiency of different tree species for atmospheric particulate matter (PM) accumulation and the underlying mechanism hasn't been well understood. To select tree species with high air purification abilities, the supplementing ultrasonic cleaning (UC) procedure was first introduced into the conventional leaf cleaning methods [single water cleaning (WC) or plus brush cleaning (BC)] for eluting the leaf-retained PM. Further updates to the methodology were applied to investigate the retention capacity, efficiency, and mechanism for PM of five typical greening tree species in Beijing, China. Meanwhile, the particle size distribution of PM on the leaves, the PM retention efficiencies of easily removable (ERP), difficult-to-remove (DRP) and totally removable (TRP) particles on the leaf (AE leaf ), and the individual tree scales were estimated. The experimental leaf samples were collected from trees with similar sizes 4 (SDR) and 14days (LDR) after rainfall. When the leaves were cleaned by WC+BC, there was, on average, 29%-46% of the PM remaining on the leaves of different species, which could be removed almost completely if UC was supplemented. From SDR to LDR, the mass of the leaf-retained PM increased greatly, and the particle size distribution changed markedly for all species except for Sophorajaponica. Pinus tabuliformis retains particles with the largest average diameter (34.2μm), followed by Ginkgo biloba (20.5μm), Sabina chinensis (16.4μm), Salix babylonica (16.0μm), and S. japonica (13.1μm). S. japonica and S. chinensis had the highest AE leaf to retain the TRP and ERP of both PM 1 and PM 1-2.5 , respectively. Conversely, S. babylonica and P. tabuliformis could retain both TRP and ERP of PM 2.5-5 and PM 5-10 , and PM >10 and TSP with the highest AE leaf , respectively. In conclusion, our results could be useful in selecting greening tree species with high air purification

  1. Experimental study on the viscosity and adhesive performance of exogenous liquid fibrin glue.

    Science.gov (United States)

    Hayashi, Takuro; Hasegawa, Mitsuhiro; Inamasu, Joji; Adachi, Kazuhide; Nagahisa, Shinya; Hirose, Yuichi

    2014-01-01

    Exogenous fibrin glue (FG) is highly suitable for neurosurgical procedures, because of its viscosity and adhesive properties. Several FGs are commercially available, but only few reports detail their differences. In the present study, we investigated the viscosity and adhesive performance of two types of FG: one is derived from blood donated in Europe and the United States (CSL Behring's Beriplast(®), BP) and the other is derived from blood donated in Japan (the Chemo-Sero-Therapeutic Research Institute's Bolheal(®), BH). The viscosity test that measured fibrinogen viscosity revealed that BP had significantly higher viscosity than BH. Similarly, the dripping test showed that BP traveled a significantly shorter drip distance in the vertical direction than BH, although the transverse diameter of the coagulated FG did not differ statistically significantly. In the tensile strength test, BP showed superior adhesion performance over BH. The histological study of the hematoxylin-eosin-stained specimens in both groups showed favorable adhesion. Although further studies are required on its manufacturing and usage methods, FG shows differences in viscosity and adhesive performance according to the blood from which it is derived. We conclude that it is desirable to select the type and usage method of FG according to the characteristics of the surgical operation in question. Our findings suggest that FG produced from the blood donated in Europe and the United States might be more suitable for use in surgical procedures that demand an especially high degree of viscosity and rapid adhesive performance.

  2. Refractive index and viscosity: dual sensing with plastic fibre gratings

    Science.gov (United States)

    Ferreira, Ricardo; Bilro, Lúcia; Marques, Carlos; Oliveira, Ricardo; Nogueira, Rogério

    2014-05-01

    A refractive index and viscosity sensor based on FBGs in mPOF is reported for the first time. The refractive index was measured with a sensitivity of -10:98nm=RIU and a resolution of 1 - 10-4RIU. Viscosity measurements were performed with acousto-optic modulation, obtaining a sensitivity of -94:42%=mPa • s and a resolution of 0:06mPa • s.

  3. Derivation of a new kinetic equation. Application to the determination of viscosity coefficients

    International Nuclear Information System (INIS)

    Frey, Jean-Jacques

    1970-01-01

    By introducing a new hypothesis concerning the closure in the B.B.G.K.Y. equation system, an approximate expression for f 12 is obtained. By inserting this expression in the first B.B.G.K.Y. equation, a new kinetic equation results. It is verified that this equation does in fact give the fluid mechanics equations, and new expressions for the shear and expansion viscosity coefficients are obtained. The numerical calculations which have been carried out show that very satisfactory agreement exists with experimental results. (author) [fr

  4. Effect of tellurium on viscosity and liquid structure of GaSb melts

    Energy Technology Data Exchange (ETDEWEB)

    Ji Leilei [School of Material Science and Engineering, Jinan University, Jinan 250022 (China); Geng Haoran [School of Material Science and Engineering, Jinan University, Jinan 250022 (China)], E-mail: mse_genghr@ujn.edu.cn; Sun Chunjing [Key Laboratory of Liquid Structure and Heredity of Materials, Ministry of Education, Shandong University, Jinan 250061 (China); Teng Xinying; Liu Yamei [School of Material Science and Engineering, Jinan University, Jinan 250022 (China)

    2008-04-03

    The behavior of GaSb melt with tellurium addition was investigated using viscometer and differential scanning calorimetry (DSC). Normally, the viscosity of all melts measured decreased with the increasing temperature. However, anomalous transition points were observed in the temperature dependence of viscosity for Ga-Sb-Te system. Corresponded with the abnormal points on the viscosity-temperature curves, there were thermal effect peaks on the DSC curves. Furthermore, viscous activation energy and flow units of these melts and their structural features were discussed in this paper.

  5. Study of thermal and chemical effects on cellulase enzymes: Viscosity measurements

    International Nuclear Information System (INIS)

    Ghaouar, N.; Aschi, A.; Belbahri, L.; Trabelsi, S.; Gharbi, A.

    2009-01-01

    The behaviour of cellulase enzymes in phosphate saline buffer has been studied over a wide range of temperatures and enzyme concentrations by using viscosity measurements. To characterize the conformation change of cellulase versus temperature and chemical denaturants, such as guanidinium chloride (GdmCl) and urea, the information about the intrinsic viscosity and the hydrodynamic radius are necessary. The dependence of the intrinsic viscosity and the hydrodynamic radius in its random coil conformation on temperature and denaturant concentration were studied. Our results and discussions are limited to the dilute regime of concentration because of abnormalities in conformation observed in the very dilute regime due to the presence of capillary absorption effects.

  6. Study of thermal and chemical effects on cellulase enzymes: Viscosity measurements

    Energy Technology Data Exchange (ETDEWEB)

    Ghaouar, N., E-mail: naoufel-ghaouar@lycos.co [Laboratoire de Physique de la Matiere Molle, Faculte des Sciences de Tunis, Campus Universitaire, 2092 (Tunisia); Institut National des Sciences Appliquees et de Technologie, INSAT, Centre Urbain Nord, BP. 676, Tunis (Tunisia); Aschi, A. [Laboratoire de Physique de la Matiere Molle, Faculte des Sciences de Tunis, Campus Universitaire, 2092 (Tunisia); Belbahri, L. [Agronomy Department, School of Engineering of Lullier, University of Applied Sciences of Western Switzerland, 150, Route de Presinge, 1254 Jussy (Switzerland); Trabelsi, S.; Gharbi, A. [Laboratoire de Physique de la Matiere Molle, Faculte des Sciences de Tunis, Campus Universitaire, 2092 (Tunisia)

    2009-11-15

    The behaviour of cellulase enzymes in phosphate saline buffer has been studied over a wide range of temperatures and enzyme concentrations by using viscosity measurements. To characterize the conformation change of cellulase versus temperature and chemical denaturants, such as guanidinium chloride (GdmCl) and urea, the information about the intrinsic viscosity and the hydrodynamic radius are necessary. The dependence of the intrinsic viscosity and the hydrodynamic radius in its random coil conformation on temperature and denaturant concentration were studied. Our results and discussions are limited to the dilute regime of concentration because of abnormalities in conformation observed in the very dilute regime due to the presence of capillary absorption effects.

  7. Near-surface viscosity measurements with a love acoustic wave device

    International Nuclear Information System (INIS)

    Collings, A.F.; Cooper, B.J.; Lappas, S.; Sor, J.A.

    1999-01-01

    Full text: In the last decade, considerable research effort has been directed towards interfacing piezoelectric transducers with biological detection systems to produce efficient and highly selective biosensors. Several types of piezoelectric or, more specifically, acoustic wave transducers have been investigated. Our group has developed Love wave (guided surface skimming wave) devices which are made by attaching a thin overlayer with the appropriate acoustic properties to the surface of a conventional surface horizontal mode device. An optimised layer concentrates most of the propagating wave energy in the guiding layer and can improve the device sensitivity in detecting gas-phase mass loading on the surface some 20- to 40-fold. Love wave devices used in liquid phase sensing will also respond to viscous, as well as mass, loading on the device surface. We have studied the propagation of viscous waves into liquid sitting on a Love wave device both theoretically and experimentally. Modelling of the effect of a viscous liquid layer on a Love wave propagating in a layered medium predicts the velocity profile in the solid substrate and in the adjoining liquid. This is a function of the thickness of the guiding layer, the elastic properties of the guiding layer and the piezoelectric substrate, and of the viscosity and density of the liquid layer. We report here on measurements of the viscosity of aqueous glycerine solutions made with a quartz Love wave device with a 5.5 μm SiO 2 guiding layer. The linear relationship between the decrease in the device frequency and the square root of the viscosity density product is accurately observed at Newtonian viscosities. At higher viscosities, there is an increase in damping, the insertion loss of the device saturates, Δf is no longer proportional to (ηp) l/2 and reaches a maximum. We also show results for the determination of the gelation time in protein and inorganic aqueous gels and for the rate of change of viscosity with

  8. Effect of viscosity on appetite and gastro-intestinal hormones

    DEFF Research Database (Denmark)

    Zijlstra, Nicolien; Mars, Monica; de Wijk, René A

    2009-01-01

    In previous studies we showed that higher viscosity resulted in lower ad libitum intake and that eating rate is an important factor. In this study we aimed to explore the effect of viscosity on the gastro-intestinal hormones ghrelin, CCK-8 and GLP-1. Thirty-two subjects (22+/-2 y, BMI 21.9+/-2.2 kg....../m(2)) participated in this cross-over study. Subjects received a fixed amount of a chocolate flavored milk-based liquid or semi-solid product similar in energy density and macronutrient composition. Before intake and 15, 30, 60 and 90 min thereafter, appetite was rated and blood was drawn to determine...... than the liquid. There was a significant product effect for fullness (p 0.03), desire to eat (p 0.04), appetite something sweet (p 0.002) and prospective consumption (p 0.0009). We observed no clear effect of viscosity on gastro-intestinal hormones. Only for desacyl ghrelin there was a significant...

  9. Diffusivities and Viscosities of Poly(ethylene oxide) Oligomers †

    KAUST Repository

    Hong, Bingbing

    2010-10-14

    Diffusivities and viscosities of poly(ethylene oxide) (PEO) oligomer melts with 1 to 12 repeat units have been obtained from equilibrium molecular dynamics simulations using the TraPPE-UA force field. The simulations generated diffusion coefficients with high accuracy for all of the molar masses studied, but the statistical uncertainties in the viscosity calculations were significantly larger for longer chains. There is good agreement of the calculated viscosities and densities with available experimental data, and thus, the simulations can be used to bridge gaps in the data and for extrapolations with respect to chain length, temperature, and pressure. We explored the convergence characteristics of the Green-Kubo formulas for different chain lengths and propose minimal production times required for convergence of the transport properties. The chain-length dependence of the transport properties suggests that neither Rouse nor reptation models are applicable in the short-chain regime investigated. © 2010 American Chemical Society.

  10. Hall viscosity of hierarchical quantum Hall states

    Science.gov (United States)

    Fremling, M.; Hansson, T. H.; Suorsa, J.

    2014-03-01

    Using methods based on conformal field theory, we construct model wave functions on a torus with arbitrary flat metric for all chiral states in the abelian quantum Hall hierarchy. These functions have no variational parameters, and they transform under the modular group in the same way as the multicomponent generalizations of the Laughlin wave functions. Assuming the absence of Berry phases upon adiabatic variations of the modular parameter τ, we calculate the quantum Hall viscosity and find it to be in agreement with the formula, given by Read, which relates the viscosity to the average orbital spin of the electrons. For the filling factor ν =2/5 Jain state, which is at the second level in the hierarchy, we compare our model wave function with the numerically obtained ground state of the Coulomb interaction Hamiltonian in the lowest Landau level, and find very good agreement in a large region of the complex τ plane. For the same example, we also numerically compute the Hall viscosity and find good agreement with the analytical result for both the model wave function and the numerically obtained Coulomb wave function. We argue that this supports the notion of a generalized plasma analogy that would ensure that wave functions obtained using the conformal field theory methods do not acquire Berry phases upon adiabatic evolution.

  11. RELAP-7 Numerical Stabilization: Entropy Viscosity Method

    Energy Technology Data Exchange (ETDEWEB)

    R. A. Berry; M. O. Delchini; J. Ragusa

    2014-06-01

    The RELAP-7 code is the next generation nuclear reactor system safety analysis code being developed at the Idaho National Laboratory (INL). The code is based on the INL's modern scientific software development framework, MOOSE (Multi-Physics Object Oriented Simulation Environment). The overall design goal of RELAP-7 is to take advantage of the previous thirty years of advancements in computer architecture, software design, numerical integration methods, and physical models. The end result will be a reactor systems analysis capability that retains and improves upon RELAP5's capability and extends the analysis capability for all reactor system simulation scenarios. RELAP-7 utilizes a single phase and a novel seven-equation two-phase flow models as described in the RELAP-7 Theory Manual (INL/EXT-14-31366). The basic equation systems are hyperbolic, which generally require some type of stabilization (or artificial viscosity) to capture nonlinear discontinuities and to suppress advection-caused oscillations. This report documents one of the available options for this stabilization in RELAP-7 -- a new and novel approach known as the entropy viscosity method. Because the code is an ongoing development effort in which the physical sub models, numerics, and coding are evolving, so too must the specific details of the entropy viscosity stabilization method. Here the fundamentals of the method in their current state are presented.

  12. Dietary fibres in the regulation of appetite and food intake. Importance of viscosity.

    Science.gov (United States)

    Kristensen, Mette; Jensen, Morten Georg

    2011-02-01

    Dietary fibres have many functions in the diet, one of which may be to promote control of energy intake and reduce the risk of developing obesity. This is linked to the unique physico-chemical properties of dietary fibres which aid early signalling of satiation and prolonged or enhanced sensation of satiety. Particularly the ability of some dietary fibres to increase viscosity of intestinal contents offers numerous opportunities to affect appetite regulation. Few papers on the satiating effect of dietary fibres include information on the physico-chemical characteristics of the dietary fibres being tested, including molecular weight and viscosity. For viscosity to serve as a proxy for soluble dietary fibres it is essential to have an understanding of individual dietary fibre viscosity characteristics. The goal of this paper is to provide a brief overview on the role of dietary fibres in appetite regulation highlighting the importance of viscosity. Copyright © 2010 Elsevier Ltd. All rights reserved.

  13. Lack of association between systolic blood pressure and blood viscosity in normotensive healthy subjects.

    Science.gov (United States)

    Irace, Concetta; Carallo, Claudio; Scavelli, Faustina; Loprete, Antonio; Merante, Valentina; Gnasso, Agostino

    2012-01-01

    A direct relationship between blood pressure and viscosity has frequently been reported, although clear data are not available. To better understand the relationship between these two variables, we evaluated blood viscosity and blood pressure in a group of healthy subjects without cardiovascular risk factors. Healthy subjects were selected from participants in a campaign of prevention of cardiovascular disease (n = 103). They underwent blood sampling for measurement of plasma and blood viscosity, haematocrit, blood lipids and glucose. The quantity and distribution of body fat was assessed by body mass index and waist/hip ratio, respectively. Systolic blood pressure (SBP) correlated significantly with age (r = 0.222) and waist/hip ratio (r = 0.374). Diastolic blood pressure (DBP) correlated significantly with waist/hip ratio (r = 0.216), haematocrit (r = 0.333) and blood viscosity (r = 0.258). Multiple linear regression analyses demonstrated that the only variable significantly associated with SBP was age, while haematocrit was the only variable significantly associated with DBP. Blood viscosity was closely related to waist/hip ratio. These findings show that SBP, in healthy subjects, is not influenced by haematocrit and blood viscosity. In contrast, DBP is related to the values of haematocrit. Among classical cardiovascular risk factors, waist/hip ratio is closely related to blood viscosity.

  14. Adequacy of human milk viscosity to respond to infants with dysphagia: experimental study

    Directory of Open Access Journals (Sweden)

    Mariangela Bartha de Mattos de Almeida

    2011-12-01

    Full Text Available Neonatal nutrition is an important subject in health in the short, medium and long term. In preterm newborns, nutrition assumes a predominant role for the child's overall development. Babies with uncoordinated swallowing or respiration may not have the necessary oral abilities to suck the mother's breast and will need to implement different feeding practices; one of them is changing the consistency of the milk offered. Objectives: Determine viscosity variations of untreated human and pasteurized milk without and with thickening to adapt the diet to the needs of dysphagic infants hospitalized in the Neonatal Intensive Cara Unit (NICU. Material and Methods: The authors altered the viscosity of natural infant powdered milk and, after thickening, determined and adopted a thickening standard for human milk. Untreated human and pasteurized milk was thickened in concentrations of 2%, 3%, 5% and 7% and the viscosity were determined every 20 minutes for a period of 60 minutes at a temperature of 37ºC. Results: The infant lactose formula thickened at concentrations of 2% and 3% produced viscosities of 8.97cP and 27.73 cP, respectively. The increases were significantly different after 1 hour. Inversely, untreated human milk at 2%, 3%, 5% and 7% produced diminished viscosity over time; the changes were more accentuated in the first 20 minutes. In pasteurized human milk, the 2% concentration had no variation in viscosity, but with the 3%, 5% and 7% concentrations, there was a significant decrease in the first 20 minutes with stability observed in the subsequent times. Conclusion: In powdered milk, the viscosity increases over time; the viscosity in human milk diminishes. The results point out the importance not only of considering the concentration of the thickener but also the time being administered after its addition to effectively treat dysphagic infants.

  15. Thermodynamic parameters of bonds in glassy materials from viscosity-temperature relationships

    International Nuclear Information System (INIS)

    Ojovan, Michael I; Travis, Karl P; Hand, Russell J

    2007-01-01

    Doremus's model of viscosity assumes that viscous flow in amorphous materials is mediated by broken bonds (configurons). The resulting equation contains four coefficients, which are directly related to the entropies and enthalpies of formation and motion of the configurons. Thus by fitting this viscosity equation to experimental viscosity data these enthalpy and entropy terms can be obtained. The non-linear nature of the equation obtained means that the fitting process is non-trivial. A genetic algorithm based approach has been developed to fit the equation to experimental viscosity data for a number of glassy materials, including SiO 2 , GeO 2 , B 2 O 3 , anorthite, diopside, xNa 2 O-(1-x)SiO 2 , xPbO-(1-x)SiO 2 , soda-lime-silica glasses, salol, and α-phenyl-o-cresol. Excellent fits of the equation to the viscosity data were obtained over the entire temperature range. The fitting parameters were used to quantitatively determine the enthalpies and entropies of formation and motion of configurons in the analysed systems and the activation energies for flow at high and low temperatures as well as fragility ratios using the Doremus criterion for fragility. A direct anti-correlation between fragility ratio and configuron percolation threshold, which determines the glass transition temperature in the analysed materials, was found

  16. The tribological behaviour of different clearance MOM hip joints with lubricants of physiological viscosities.

    Science.gov (United States)

    Hu, X Q; Wood, R J K; Taylor, A; Tuke, M A

    2011-11-01

    Clearance is one of the most influential parameters on the tribological performance of metal-on-metal (MOM) hip joints and its selection is a subject of considerable debate. The objective of this paper is to study the lubrication behaviour of different clearances for MOM hip joints within the range of human physiological and pathological fluid viscosities. The frictional torques developed by MOM hip joints with a 50 mm diameter were measured for both virgin surfaces and during a wear simulator test. Joints were manufactured with three different diametral clearances: 20, 100, and 200 microm. The fluid used for the friction measurements which contained different ratios of 25 percent newborn calf serum and carboxymethyl cellulose (CMC) with the obtained viscosities values ranging from 0.001 to 0.71 Pa s. The obtained results indicate that the frictional torque for the 20 microm clearance joint remains high over the whole range of the viscosity values. The frictional torque of the 100 microm clearance joint was low for the very low viscosity (0.001 Pa s) lubricant, but increased with increasing viscosity value. The frictional torque of the 200 microm clearance joint was high at very low viscosity levels, however, it reduced with increasing viscosity. It is concluded that a smaller clearance level can enhance the formation of an elastohydrodynamic lubrication (EHL) film, but this is at the cost of preventing fluid recovery between the bearing surfaces during the unloaded phase of walking. Larger clearance bearings allow a better recovery of lubricant during the unloaded phase, which is necessary for higher viscosity lubricants. The selection of the clearance value should therefore consider both the formation of the EHL film and the fluid recovery as a function of the physiological viscosity in order to get an optimal tribological performance for MOM hip joints. The application of either 25 per cent bovine serum or water in existing in vitro tribological study should

  17. Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition

    Science.gov (United States)

    Wong DeRieux, Wing-Sy; Li, Ying; Lin, Peng; Laskin, Julia; Laskin, Alexander; Bertram, Allan K.; Nizkorodov, Sergey A.; Shiraiwa, Manabu

    2018-05-01

    Secondary organic aerosol (SOA) accounts for a large fraction of submicron particles in the atmosphere. SOA can occur in amorphous solid or semi-solid phase states depending on chemical composition, relative humidity (RH), and temperature. The phase transition between amorphous solid and semi-solid states occurs at the glass transition temperature (Tg). We have recently developed a method to estimate Tg of pure compounds containing carbon, hydrogen, and oxygen atoms (CHO compounds) with molar mass less than 450 g mol-1 based on their molar mass and atomic O : C ratio. In this study, we refine and extend this method for CH and CHO compounds with molar mass up to ˜ 1100 g mol-1 using the number of carbon, hydrogen, and oxygen atoms. We predict viscosity from the Tg-scaled Arrhenius plot of fragility (viscosity vs. Tg/T) as a function of the fragility parameter D. We compiled D values of organic compounds from the literature and found that D approaches a lower limit of ˜ 10 (±1.7) as the molar mass increases. We estimated the viscosity of α-pinene and isoprene SOA as a function of RH by accounting for the hygroscopic growth of SOA and applying the Gordon-Taylor mixing rule, reproducing previously published experimental measurements very well. Sensitivity studies were conducted to evaluate impacts of Tg, D, the hygroscopicity parameter (κ), and the Gordon-Taylor constant on viscosity predictions. The viscosity of toluene SOA was predicted using the elemental composition obtained by high-resolution mass spectrometry (HRMS), resulting in a good agreement with the measured viscosity. We also estimated the viscosity of biomass burning particles using the chemical composition measured by HRMS with two different ionization techniques: electrospray ionization (ESI) and atmospheric pressure photoionization (APPI). Due to differences in detected organic compounds and signal intensity, predicted viscosities at low RH based on ESI and APPI measurements differ by 2-5 orders

  18. Viscosity of HI-I2-H2O solution at atmospheric pressure

    International Nuclear Information System (INIS)

    Chen, Songzhe; Zhang, Ping; Wang, Laijun; Xu, Jingming; Gao, Mengxue

    2014-01-01

    Iodine-Sulfur thermochemical cycle (IS-cycle) is one of the most promising massive hydrogen production methods. Basic properties data of the HI-I 2 -H 2 O solution involved in the HI decomposition section of IS-cycle are found to be very important. HI, I 2 , and H 2 O make up a highly non-ideal solution system. Viscosity and its variation with the composition/temperature are very essential for the flowsheet work and HI-H 2 O-I 2 solution’s fluid simulation, especially in the distillation and electro-electrodialysis processes. In this paper, viscosity values of HI-H 2 O-I 2 solutions were measured at atmospheric pressure and varying temperatures (from 20 to 125 ºC). As for the composition, the HI/H2O molar ratio of the samples ranged from 1:5.36 to 1:12.00, while the HI/I 2 molar ratio from 1.0 to 1.4.0. Both temperature and composition have dramatic influence on the viscosity. Increasing temperature or H 2 O/HI molar ratio will lead to the reduction of viscosity; while increasing of I 2 /HI molar ratio results in the increase of viscosity. It was also found that I 2 content has a larger and more complex influence on the viscosity of the HI-H 2 O-I 2 solution than H 2 O content does, especially at low temperature (<50 °C). (author)

  19. An Investigation of Viscosities, Calorific Values and Densities of Binary Biofuel Blends

    Directory of Open Access Journals (Sweden)

    Che Mat Sharzali

    2017-01-01

    Full Text Available Straight vegetable oil (SVO biofuel is a promising alternative to petroleum diesel fuel primarily due to its comparable physical properties to that of petroleum diesel fuel. However, the relatively higher viscosity of SVO limits its direct application in diesel engine. To resolve this issue, binary biofuel blends was introduced in this study to reduce the viscosity of SVO. In this work, a novel biofuel namely Melaleuca Cajuputi oil (MCO was used and blended with refined palm oil (RPO. A total of four blends with the mixing ratios of 20%, 40%, 50% and 60% of MCO were prepared. Various key properties of dynamic viscosity, calorific value and density of the blends were measured and benchmarked against the biodiesel standards based on ASTM D6751. It was found that viscosity and density of the blends decreased with the increase of MCO fraction. Meanwhile, the calorific value of the blends increased linearly as the MCO fraction increased. The blend of 40RPO60MCO was found to have comparable key properties of viscosity, calorific value and density to those of petroleum diesel fuel and ASTM D6751 standard.

  20. "Coulombic Viscosity" In Granular Materials: Planetary and Astrophysical Implications

    Science.gov (United States)

    Marshall, J. R.

    1999-01-01

    The term "Coulombic viscosity" is introduced here to define an empirically observed phenomenon from experiments conducted in both microgravity, and in ground-based 1-g conditions. In the latter case, a sand attrition device was employed to test the longevity of aeolian materials by creating two intersecting grain-circulation paths or cells that would lead to most of the grain energy being expended on grain-to-grain collisions (simulating dune systems). In the areas in the device where gravitationally-driven grain-slurries recycled the sand, the slurries moved with a boundary-layer impeded motion down the chamber walls. Excessive electrostatic charging of the grains during these experiments was prevented by the use of an a.c. corona (created by a Tesla coil) through which the grains passed on every cycle. This created both positive and negative ions which neutralized the triboelectrically-generated grain charges. When the corona was switched on, the velocity of the wall-attached slurries increased by a factor of two as approximately determined by direct observation. What appeared to be a freely-flowing slurry of grains impeded only by intergranular mechanical friction, had obviously been significantly retarded in its motion by electrostatic forces between the grains; with the charging reduced, the grains were able to move past one another without a flow "viscosity" imposed by the Coulombic intergranular forces. A similar phenomenon was observed during microgravity experiments aboard Space Shuttle in USML-1 & USML-2 spacelabs where freely-suspended clouds of sand were being investigated for their potential to for-m aggregates. In this environment, the grains were also charged electrostatically (by natural processes prior to flight), but were free from the intervention of gravity in their interactions. The grains were dispersed into dense clouds by bursts of air turbulence and allowed to form aggregates as the ballistic and turbulent motions damped out. During this

  1. "Coulombic Viscosity" In Granular Materials: Planetary and Astrophysical Implications

    Science.gov (United States)

    Marshall, J. R.

    1999-09-01

    The term "Coulombic viscosity" is introduced here to define an empirically observed phenomenon from experiments conducted in both microgravity, and in ground-based 1-g conditions. In the latter case, a sand attrition device was employed to test the longevity of aeolian materials by creating two intersecting grain-circulation paths or cells that would lead to most of the grain energy being expended on grain-to-grain collisions (simulating dune systems). In the areas in the device where gravitationally-driven grain-slurries recycled the sand, the slurries moved with a boundary-layer impeded motion down the chamber walls. Excessive electrostatic charging of the grains during these experiments was prevented by the use of an a.c. corona (created by a Tesla coil) through which the grains passed on every cycle. This created both positive and negative ions which neutralized the triboelectrically-generated grain charges. When the corona was switched on, the velocity of the wall-attached slurries increased by a factor of two as approximately determined by direct observation. What appeared to be a freely-flowing slurry of grains impeded only by intergranular mechanical friction, had obviously been significantly retarded in its motion by electrostatic forces between the grains; with the charging reduced, the grains were able to move past one another without a flow "viscosity" imposed by the Coulombic intergranular forces. A similar phenomenon was observed during microgravity experiments aboard Space Shuttle in USML-1 & USML-2 spacelabs where freely-suspended clouds of sand were being investigated for their potential to for-m aggregates. In this environment, the grains were also charged electrostatically (by natural processes prior to flight), but were free from the intervention of gravity in their interactions. The grains were dispersed into dense clouds by bursts of air turbulence and allowed to form aggregates as the ballistic and turbulent motions damped out. During this

  2. Bulk and shear viscosities of the gluon plasma in a quasiparticle description

    CERN Document Server

    Bluhm, M; Redlich, K

    2011-01-01

    Bulk and shear viscosities of deconfined gluonic matter are investigated within an effective kinetic theory by describing the strongly interacting medium phenomenologically in terms of quasiparticle excitations with medium-dependent self-energies. In this approach, local conservation of energy and momentum follows from a Boltzmann-Vlasov type kinetic equation and guarantees thermodynamic self-consistency. We show that the resulting transport coefficients reproduce the parametric dependencies on temperature and coupling obtained in perturbative QCD at large temperatures and small running coupling. The extrapolation into the non-perturbative regime results in a decreasing specific shear viscosity with decreasing temperature, exhibiting a minimum in the vicinity of the deconfinement transition temperature, while the specific bulk viscosity is sizeable in this region falling off rapidly with increasing temperature. The temperature dependence of specific bulk and shear viscosities found within this quasiparticle d...

  3. Electro-optical properties of low viscosity driven holographic polymer dispersed liquid crystals

    Science.gov (United States)

    Moon, K. R.; Bae, S. Y.; Kim, B. K.

    2015-04-01

    Relative diffraction efficiency (RDE), operating voltage, and response times are most important performance characteristics of holographic polymer dispersed liquid crystals (HPDLC). Two types of triallyl isocyanurate (TI) having different structures were incorporated into the conventional transmission grating of HPDLC. Premix viscosity decreased by 13-18% with up to 3% TI, beyond which it increased. TI eliminated induction period and augmented initial grating formation rate at all contents. Saturation RDE increased over 200% while threshold voltage and rise time decreased to about half and 2/3, respectively up to 3% TI, beyond which the tendencies were reversed. Among the two TIs, low viscosity monomer (TA) showed high RDE, while high miscibility monomer (TE) low characteristic voltages and short response times. It is concluded that grating formation is largely favored by low viscosity, while interface tensions and electro-optical performances by miscibility at similar viscosities.

  4. VARIATION IN MEAT COMPOSITION VISCOSITY DURING THE MIXING PROCESS

    Directory of Open Access Journals (Sweden)

    DANIELA IANIłCHI

    2008-10-01

    Full Text Available Animal raw material processing is directly influenced by the physical and chemical characteristics of the materials which also influence their water holding capacity. The various combinations and status of the raw materials used in the food industry determine specific behaviours that may influence the processing equipment performance and construction. The study on meat composition viscosity depending upon the added components, temperature and mixing time length, has shown that viscosity is increasing with lower added water percentage, lower mixing temperature and higher mixing time length.

  5. Shear viscosity and thermal conductivity of nuclear 'pasta'

    International Nuclear Information System (INIS)

    Horowitz, C. J.; Berry, D. K.

    2008-01-01

    We calculate the shear viscosity η and thermal conductivity κ of a nuclear pasta phase in neutron star crusts. This involves complex nonspherical shapes. We use semiclassical molecular dynamics simulations involving 40, 000 to 100, 000 nucleons. The viscosity η can be simply expressed in terms of the height Z* and width Δq of the peak in the static structure factor S p (q). We find that η increases somewhat, compared to a lower density phase involving spherical nuclei, because Z* decreases from form factor and ion screening effects. However, we do not find a dramatic increase in η from nonspherical shapes, as may occur in conventional complex fluids

  6. Effect of electron beam irradiation on viscosity/temperature characteristics of cellulose derivatives

    International Nuclear Information System (INIS)

    Mastro, N.L. del; Villavicencio, A.L.C.; Yamasaki, M.C.R.

    1991-11-01

    The direct relationship between intrinsic viscosity and molecular weight of polymers allowed to attend the aggregation, cross-linking and degradation processes induced by electron beam irradiation on carboxymethylcellulose and hydroxiethylcellulose in aqueous solutions. The changes in viscosity were related to irradiation doses from 2.5x10 4 Gy to 25x10 4 Gy at 5 0 C, 25 0 C, 50 0 C and 75 0 C measured at different intervals after irradiation. The results showed the viscosity decrease characteristics as a function of those parameters for each one of the polymers. (author)

  7. Continuous dependence estimates for viscosity solutions of fully nonlinear degenerate elliptic equations

    Directory of Open Access Journals (Sweden)

    Espen R. Jakobsen

    2002-05-01

    Full Text Available Using the maximum principle for semicontinuous functions [3,4], we prove a general ``continuous dependence on the nonlinearities'' estimate for bounded Holder continuous viscosity solutions of fully nonlinear degenerate elliptic equations. Furthermore, we provide existence, uniqueness, and Holder continuity results for bounded viscosity solutions of such equations. Our results are general enough to encompass Hamilton-Jacobi-Bellman-Isaacs's equations of zero-sum, two-player stochastic differential games. An immediate consequence of the results obtained herein is a rate of convergence for the vanishing viscosity method for fully nonlinear degenerate elliptic equations.

  8. Study on viscosity modification of human and formula milk for infants with dysphagia

    Directory of Open Access Journals (Sweden)

    Mariangela Bartha de Mattos Almeida

    Full Text Available ABSTRACT Purpose: to analyze the modification of the viscosity of human milk and infant formula. Methods: three studies were performed to assess the viscosity and effect of time on infant formula with a thickener, at concentrations of 2, 3, and 5%, as well as raw and pasteurized human milk at concentrations of 2, 3, 5, and 7% at 37ºC, for 60 minutes. Rice cereal was used as a thickening agent. The viscosity was evaluated using a Ford Cup-type viscometer, and the samples were analyzed at 20-minute intervals. Significant differences were assessed using the ANOVA test. Results: no significant differences in viscosity were observed over time in concentrations of 2, 3, and 5%. There was a difference in the viscosity between human milk and infant formula, in concentrations of 2% and 5%, 2% and 7%, 3% and 5%, and 3% and 7%, independently of the time intervals evaluated. Conclusion: the findings of this study demonstrate the need for different concentrations of the thickening agent for human milk and infant formula. Rice cereal is a suitable therapeutic option for newborns presented with dysphagia in concentrations of 2, 3, 5, and 7%, due to its effect on the viscosity and flow reduction, provided that the feeding time is considered.

  9. Viscosity Measurements of "FeO"-SiO2 Slag in Equilibrium with Metallic Fe

    Science.gov (United States)

    Chen, Mao; Raghunath, Sreekanth; Zhao, Baojun

    2013-06-01

    The current study delivered the measurements of viscosities in the system "FeO"-SiO2 in equilibrium with metallic Fe in the composition range between 15 and 40 wt pct SiO2. The experiments were carried out in the temperature range of 1473 K to 1773 K (1200 °C to 1500 °C) using a rotational spindle technique. An analysis of the quenched sample by electron probe X-ray microanalysis (EPMA) after the viscosity measurement enables the composition and microstructure of the slag to be directly linked with the viscosity. The current results are compared with available literature data. The significant discrepancies of the viscosity measurements in this system have been clarified. The possible reasons affecting the accuracy of the viscosity measurement have been discussed. The activation energies derived from the experimental data have a sharp increase at about 33 wt pct SiO2, which corresponds to the composition of fayalite (Fe2SiO4). The modified quasi-chemical model was constructed in the system "FeO"-SiO2 to describe the current viscosity data.

  10. Convergence of a residual based artificial viscosity finite element method

    KAUST Repository

    Nazarov, Murtazo

    2013-02-01

    We present a residual based artificial viscosity finite element method to solve conservation laws. The Galerkin approximation is stabilized by only residual based artificial viscosity, without any least-squares, SUPG, or streamline diffusion terms. We prove convergence of the method, applied to a scalar conservation law in two space dimensions, toward an unique entropy solution for implicit time stepping schemes. © 2012 Elsevier B.V. All rights reserved.

  11. A Low Viscosity Lunar Magma Ocean Forms a Stratified Anorthitic Flotation Crust With Mafic Poor and Rich Units: Lunar Magma Ocean Viscosity

    Energy Technology Data Exchange (ETDEWEB)

    Dygert, Nick [Department of Geological Sciences, Jackson School of Geosciences, University of Texas at Austin, Austin TX USA; Planetary Geosciences Institute, Department of Earth and Planetary Sciences, University of Tennessee, Knoxville, Knoxville TN USA; Lin, Jung-Fu [Department of Geological Sciences, Jackson School of Geosciences, University of Texas at Austin, Austin TX USA; Marshall, Edward W. [Department of Geological Sciences, Jackson School of Geosciences, University of Texas at Austin, Austin TX USA; Kono, Yoshio [HPCAT, Geophysical Laboratory, Carnegie Institution of Washington, Argonne IL USA; Gardner, James E. [Department of Geological Sciences, Jackson School of Geosciences, University of Texas at Austin, Austin TX USA

    2017-11-21

    Much of the lunar crust is monomineralic, comprising >98% plagioclase. The prevailing model argues the crust accumulated as plagioclase floated to the surface of a solidifying lunar magma ocean (LMO). Whether >98% pure anorthosites can form in a flotation scenario is debated. An important determinant of the efficiency of plagioclase fractionation is the viscosity of the LMO liquid, which was unconstrained. Here we present results from new experiments conducted on a late LMO-relevant ferrobasaltic melt. The liquid has an exceptionally low viscosity of 0.22 $+0.11\\atop{-0.19}$to 1.45 $+0.46\\atop{-0.82}$ Pa s at experimental conditions (1,300–1,600°C; 0.1–4.4 GPa) and can be modeled by an Arrhenius relation. Extrapolating to LMO-relevant temperatures, our analysis suggests a low viscosity LMO would form a stratified flotation crust, with the oldest units containing a mafic component and with very pure younger units. Old, impure crust may have been buried by lower crustal diapirs of pure anorthosite in a serial magmatism scenario.

  12. Role of viscosity in nonlinear effects

    Energy Technology Data Exchange (ETDEWEB)

    Petrov, G V; Peshkin, M A; Polyakov, Ye Ye

    1980-01-01

    Data are presented on laboratory experiments for filtering of gases of liquids in clay, slightly permeable core samples. A method is proposed for processing the results of experiments which makes it possible to isolate the effect of viscosity of the fluid on the defined quantity of maximum pressure differential.

  13. Viscosity bound violation in holographic solids and the viscoelastic response

    Energy Technology Data Exchange (ETDEWEB)

    Alberte, Lasma [Abdus Salam International Centre for Theoretical Physics (ICTP),Strada Costiera 11, 34151, Trieste (Italy); Baggioli, Matteo [Institut de Física d’Altes Energies (IFAE),The Barcelona Institute of Science and Technology (BIST),Campus UAB, 08193 Bellaterra, Barcelona (Spain); Department of Physics, Institute for Condensed Matter Theory, University of Illinois,1110 W. Green Street, Urbana, IL 61801 (United States); Pujolàs, Oriol [Institut de Física d’Altes Energies (IFAE),The Barcelona Institute of Science and Technology (BIST),Campus UAB, 08193 Bellaterra, Barcelona (Spain)

    2016-07-14

    We argue that the Kovtun-Son-Starinets (KSS) lower bound on the viscosity to entropy density ratio holds in fluid systems but is violated in solid materials with a non-zero shear elastic modulus. We construct explicit examples of this by applying the standard gauge/gravity duality methods to massive gravity and show that the KSS bound is clearly violated in black brane solutions whenever the massive gravity theories are of solid type. We argue that the physical reason for the bound violation relies on the viscoelastic nature of the mechanical response in these materials. We speculate on whether any real-world materials can violate the bound and discuss a possible generalization of the bound that involves the ratio of the shear elastic modulus to the pressure.

  14. Viscosity bound violation in holographic solids and the viscoelastic response

    International Nuclear Information System (INIS)

    Alberte, Lasma; Baggioli, Matteo; Pujolàs, Oriol

    2016-01-01

    We argue that the Kovtun-Son-Starinets (KSS) lower bound on the viscosity to entropy density ratio holds in fluid systems but is violated in solid materials with a non-zero shear elastic modulus. We construct explicit examples of this by applying the standard gauge/gravity duality methods to massive gravity and show that the KSS bound is clearly violated in black brane solutions whenever the massive gravity theories are of solid type. We argue that the physical reason for the bound violation relies on the viscoelastic nature of the mechanical response in these materials. We speculate on whether any real-world materials can violate the bound and discuss a possible generalization of the bound that involves the ratio of the shear elastic modulus to the pressure.

  15. Shear and bulk viscosity of high-temperature gluon plasma

    Science.gov (United States)

    Zhang, Le; Hou, De-Fu

    2018-05-01

    We calculate the shear viscosity (η) and bulk viscosity (ζ) to entropy density (s) ratios η/s and ζ/s of a gluon plasma system in kinetic theory, including both the elastic {gg}≤ftrightarrow {gg} forward scattering and the inelastic soft gluon bremsstrahlung {gg}≤ftrightarrow {ggg} processes. Due to the suppressed contribution to η and ζ in the {gg}≤ftrightarrow {gg} forward scattering and the effective g≤ftrightarrow {gg} gluon splitting, Arnold, Moore and Yaffe (AMY) and Arnold, Dogan and Moore (ADM) have got the leading order computations for η and ζ in high-temperature QCD matter. In this paper, we calculate the correction to η and ζ in the soft gluon bremsstrahlung {gg}≤ftrightarrow {ggg} process with an analytic method. We find that the contribution of the collision term from the {gg}≤ftrightarrow {ggg} soft gluon bremsstrahlung process is just a small perturbation to the {gg}≤ftrightarrow {gg} scattering process and that the correction is at ∼5% level. Then, we obtain the bulk viscosity of the gluon plasma for the number-changing process. Furthermore, our leading-order result for bulk viscosity is the formula \\zeta \\propto \\tfrac{{α }s2{T}3}{ln}{α }s-1} in high-temperature gluon plasma. Supported by Ministry of Science and Technology of China (MSTC) under the “973” Project (2015CB856904(4)) and National Natural Science Foundation of China (11735007, 11521064)

  16. Transient extensional viscosity of polymer melts in the filament stretching rheometer

    DEFF Research Database (Denmark)

    Rasmussen, Henrik Koblitz; Bach, Anders; Bastian, Heike

    2002-01-01

    In many polymer processing operations, the polymer molecules becomes highly elongated and the extensional viscosity becomes an inportant parameter in estimating properties during and after the process.......In many polymer processing operations, the polymer molecules becomes highly elongated and the extensional viscosity becomes an inportant parameter in estimating properties during and after the process....

  17. Urinary retention in women.

    Science.gov (United States)

    Juma, Saad

    2014-07-01

    This review is a summary of the most pertinent published studies in the literature in the last 18 months that address cause, diagnosis, and management of urinary retention in women. Symptoms, uroflow, and pressure-flow studies have a low predictive value for and do not correlate with elevated postvoid residual urine (PVR). Anterior and posterior colporrhaphy do not cause de-novo bladder outlet obstruction in the majority of patients with elevated PVR, and the cause of elevated PVR may be other factors such as pain or anxiety causing abnormal relaxation of the pelvic floor and contributing to voiding difficulty. The risk of urinary retention in a future pregnancy after mid-urethral sling (MUS) is small. The risk of urinary tract infection and urinary retention after chemodenervation of the bladder with onabotulinumtoxin-A (100 IU) in patients with non-neurogenic urge incontinence is 33 and 5%, respectively. There is a lack of consensus among experts on the timing of sling takedown in the management of acute urinary retention following MUS procedures. There has been a significant progress in the understanding of the causation of urinary retention. Important areas that need further research (basic and clinical) are post-MUS and pelvic organ prolapse repair urinary retention and obstruction, and urinary retention owing to detrusor underactivity.

  18. Temperature and particle-size dependent viscosity data for water-based nanofluids - Hysteresis phenomenon

    International Nuclear Information System (INIS)

    Nguyen, C.T.; Desgranges, F.; Roy, G.; Galanis, N.; Mare, T.; Boucher, S.; Angue Mintsa, H.

    2007-01-01

    In the present paper, we have investigated experimentally the influence of both the temperature and the particle size on the dynamic viscosities of two particular water-based nanofluids, namely water-Al 2 O 3 and water-CuO mixtures. The measurement of nanofluid dynamic viscosities was accomplished using a 'piston-type' calibrated viscometer based on the Couette flow inside a cylindrical measurement chamber. Data were collected for temperatures ranging from ambient to 75 deg. C, for water-Al 2 O 3 mixtures with two different particle diameters, 36 nm and 47 nm, as well as for water-CuO nanofluid with 29 nm particle size. The results show that for particle volume fractions lower than 4%, viscosities corresponding to 36 nm and 47 nm particle-size alumina-water nanofluids are approximately identical. For higher particle fractions, viscosities of 47 nm particle-size are clearly higher than those of 36 nm size. Viscosities corresponding to water-oxide copper are the highest among the nanofluids tested. The temperature effect has been investigated thoroughly. A more complete viscosity data base is presented for the three nanofluids considered, with several experimental correlations proposed for low particle volume fractions. It has been found that the application of Einstein's formula and those derived from the linear fluid theory seems not to be appropriate for nanofluids. The hysteresis phenomenon on viscosity measurement, which is believed to be the first observed for nanofluids, has raised serious concerns regarding the use of nanofluids for heat transfer enhancement purposes

  19. Mechanistic Insights into Dye-Decolorizing Peroxidase Revealed by Solvent Isotope and Viscosity Effects

    Energy Technology Data Exchange (ETDEWEB)

    Shrestha, Ruben [Department; Huang, Gaochao [Department; Meekins, David A. [Department; Geisbrecht, Brian V. [Department; Li, Ping [Department

    2017-08-18

    Dye-decolorizing peroxidases (DyPs) are a family of H2O2-dependent heme peroxidases that have shown potential applications in lignin degradation and valorization. However, the DyP kinetic mechanism remains underexplored. Using structural biology and solvent isotope (sKIE) and viscosity effects, many mechanistic characteristics have been determined for the B-class ElDyP from Enterobacter lignolyticus. Its structure revealed that a water molecule acts as the sixth axial ligand and two channels at diameters of ~3.0 and 8.0 Å lead to the heme center. A conformational change of ERS* to ERS, which have identical spectral characteristics, was proposed as the final step in DyPs’ bisubstrate Ping-Pong mechanism. This step is also the rate-determining step in ABTS oxidation. The normal KIE of wild-type ElDyP with D2O2 at pD 3.5 suggested that compound 0 deprotonation by the distal aspartate is rate-limiting in the formation of compound I, which is more reactive under acidic pH than under neutral or alkaline pH. The viscosity effects and other biochemical methods implied that the reducing substrate binds with compound I instead of the free enzyme. The significant inverse sKIEs of kcat/KM and kERS* suggested that the aquo release in ElDyP is mechanistically important and may explain the enzyme’s adoption of two-electron reduction for compound I. The distal aspartate is catalytically more important than the distal arginine and plays key roles in determining ElDyP’s optimum acidic pH. The kinetic mechanism of D143H-ElDyP was also briefly studied. The results obtained will pave the way for future protein engineering to improve DyPs’ lignolytic activity.

  20. Short time-scale wind forced variability in the Río de la Plata Estuary and its role on ichthyoplankton retention

    Science.gov (United States)

    Simionato, C. G.; Berasategui, A.; Meccia, V. L.; Acha, M.; Mianzan, H.

    2008-01-01

    The Río de la Plata Estuary presents a strong bottom salinity front located over a submerged shoal. Apparently favored by retention processes, it is a spawning ground for several coastal fishes. This estuary is very shallow and essentially wind driven and, moreover, in time scales relevant to biota, estuarine circulation is wind dominated and highly variable. Two intriguing questions are, therefore, how this system can favor retention and what the involved mechanisms are. This paper qualitatively explores mechanisms involved in the estuary where retention is favored applying numerical simulations in which neutral particles - simulating fish eggs and early larvae - are released along the bottom frontal zone and tracked for different wind conditions. Results suggest that retentive features can be a consequence of estuarine response to natural wind variability acting over bathymetric features. For winds from most directions, particles either remain trapped near their launching position or move northeastward to southwestward along the shoal. As alternation of winds that favor along-shoal motion is the dominant feature of wind variability in the region, a retentive scenario results from prevailing wind variability. Additionally, winds that tend to export particles with a poor chance of being restored to the front are neither frequent nor persistent. Results show, therefore, that physical forcing alone might generate a retentive scenario at the inner part of this estuary. The physical retention mechanism is more effective for bottom than for surface launched particles. Wind statistics indicate that the proposed mechanism has different implications for retention along the seasons. Spring is the most favorable season, followed by summer, when particles would have a larger propensity to reach the southern area of the estuary (Samborombón Bay). Fall and winter are increasingly less favorable. All these features are consistent with patterns observed in the region in

  1. Study of specific loss power of magnetic fluids with various viscosities

    Energy Technology Data Exchange (ETDEWEB)

    Phong, P.T., E-mail: phamthanhphong@tdt.edu.vn [Department for Management of Science and Technology Development, Ton Duc Thang University, Ho Chi Minh City (Viet Nam); Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City (Viet Nam); Nguyen, L.H., E-mail: luuhuunguyen@ukh.edu.vn [Institute of Materials Science, Vietnam Academy of Science and Technology,18- Hoang Quoc Viet Street, Cau Giay District, Ha Noi City (Viet Nam); Khanh Hoa University, 1- Nguyen Chanh Street, Nha Trang City, Khanh Hoa Province (Viet Nam); Phong, L.T.H., E-mail: lthp52a@gmail.com [Institute of Materials Science, Vietnam Academy of Science and Technology,18- Hoang Quoc Viet Street, Cau Giay District, Ha Noi City (Viet Nam); Nam, P.H., E-mail: namph.ims@gmail.com [Institute of Materials Science, Vietnam Academy of Science and Technology,18- Hoang Quoc Viet Street, Cau Giay District, Ha Noi City (Viet Nam); Manh, D.H., E-mail: manhdh.ims@gmail.com [Institute of Materials Science, Vietnam Academy of Science and Technology,18- Hoang Quoc Viet Street, Cau Giay District, Ha Noi City (Viet Nam); Lee, I.J., E-mail: lij@dongguk.ac.kr [Department of Advanced Materials Chemistry, Dongguk University-Gyeongju, Dongdae-roDongdae-ro 123, Gyeongju-Si, Gyeongbuk 38066 (Korea, Republic of); Phuc, N.X., E-mail: phucnx1949@gmail.com [Institute of Materials Science, Vietnam Academy of Science and Technology,18- Hoang Quoc Viet Street, Cau Giay District, Ha Noi City (Viet Nam)

    2017-04-15

    Abstracts: Using hydrothermal method, CoFe{sub 2}O{sub 4} (hard ferrite) and MnFe{sub 2}O{sub 4} (soft ferrite) nanoparticles of size up to 20 nm were synthesized and the viscosities were controlled using various concentrations of agar. The hydrodynamic diameter of these particles was measured and fitted to a lognormal distribution and the results showed their polydispersity is very narrow. From the calorimetric measurements of the particles stabilized in agar solutions, we have demonstrated that at a given frequency, the dependence of the specific loss power of magnetic fluids on the viscosity is in good agreement with the theoretical predictions made in the earlier studies. - Highlights: • CoFe{sub 2}O{sub 4} (hard ferrite) and MnFe{sub 2}O{sub 4} (soft ferrite) nanoparticles size up to 20 nm were synthesized. • The relaxation loss depends on both the particle's intrinsic properties and the viscosity of the environment. • The SLP of hard nanoparticles strongly decreases with increasing the viscosity whereas that of soft nanoparticles remains almost unchanged.

  2. Measurement of changes in viscosity in polymers with gamma-ray dose using a differential viscometer

    International Nuclear Information System (INIS)

    Santra, L.; Bhaumik, D.; Roy, S.C.

    1988-01-01

    Although some works on changes in viscosity of liquids with gamma-ray dose have been made near the ''gel point'', very little works have been done bellow this point. Changes in viscosities of different-grade silicone fluids below gel point have been measured using a differential viscometer developed in our laboratory, capable of measuring change in viscosities of two liquids directly. Preliminary results on viscosity changes when irradiated with energetic alpha particles will also be reported [pt

  3. Measurement of changes in viscosity in polymers with gamma-ray dose using a differential viscometer

    International Nuclear Information System (INIS)

    Santra, L.; Bhaumik, D.; Roy, S.C.

    1989-01-01

    Although some works on changes in viscosity of liquids with gamma-ray dose have been made near the 'gel point', very little works have been done below this point. Changes in viscosities of different-grade silicone fluids below gel point have been measured using a differential viscometer developed in our laboratory, capable of measuring change in viscosities of two liquids directly. Preliminary results on viscosity changes when irradiated with energetic alpha particles will also be reported. (orig.)

  4. Retention of copper originating from different fungicides in contrasting soil types.

    Science.gov (United States)

    Komárek, Michael; Vanek, Ales; Chrastný, Vladislav; Száková, Jirina; Kubová, Karolina; Drahota, Petr; Balík, Jirí

    2009-07-30

    This work described the retention of Cu from two different commonly used pesticides, the Bordeaux mixture (CuSO(4)+Ca(OH)(2)) and Cu-oxychloride (3Cu(OH)(2).CuCl(2)), and from Cu(NO(3))(2) in contrasting soil types (Leptosol, Chernozem, Cambisol). Thermodynamic modeling showed that Cu speciation was similar in all fungicide solutions. However, the retention of Cu differed with the fungicide used (maximum retention from the Bordeaux mixture) which indicates that different retention processes occurred in the studied soils. The suggested mechanisms include: specific and non-specific adsorption (especially on soil organic matter), precipitation of newly formed phases, such as CuO, Cu(OH)(2), Cu(2)(OH)(3)NO(3), CuCO(3)/Cu(2)(OH)(2)CO(3) and in the case of the Bordeaux mixture, precipitation of various Cu-hydroxysulfates. These phases were identified by the speciation model. The retention of fungicide-derived Cu in the studied soil types followed well the Freundlich isotherm and was directly controlled by the chemical form of Cu. This fact should be taken into account for both environmental and practical applications.

  5. Retention of copper originating from different fungicides in contrasting soil types

    Energy Technology Data Exchange (ETDEWEB)

    Komarek, Michael, E-mail: komarek@af.czu.cz [Department of Agro-Environmental Chemistry and Plant Nutrition, Czech University of Life Sciences Prague, Kamycka 129, 165 21, Prague 6 (Czech Republic); Vanek, Ales [Department of Soil Science and Soil Protection, Czech University of Life Sciences Prague, Kamycka 129, 165 21, Prague 6 (Czech Republic); Chrastny, Vladislav [Department of Applied Chemistry, University of South Bohemia, Studentska 13, 370 05, Ceske Budejovice (Czech Republic); Szakova, Jirina; Kubova, Karolina [Department of Agro-Environmental Chemistry and Plant Nutrition, Czech University of Life Sciences Prague, Kamycka 129, 165 21, Prague 6 (Czech Republic); Drahota, Petr [Institute of Geochemistry, Mineralogy and Mineral Resources, Charles University Prague, Albertov 6, 128 43, Prague 2 (Czech Republic); Balik, Jiri [Department of Agro-Environmental Chemistry and Plant Nutrition, Czech University of Life Sciences Prague, Kamycka 129, 165 21, Prague 6 (Czech Republic)

    2009-07-30

    This work described the retention of Cu from two different commonly used pesticides, the Bordeaux mixture (CuSO{sub 4} + Ca(OH){sub 2}) and Cu-oxychloride (3Cu(OH){sub 2}.CuCl{sub 2}), and from Cu(NO{sub 3}){sub 2} in contrasting soil types (Leptosol, Chernozem, Cambisol). Thermodynamic modeling showed that Cu speciation was similar in all fungicide solutions. However, the retention of Cu differed with the fungicide used (maximum retention from the Bordeaux mixture) which indicates that different retention processes occurred in the studied soils. The suggested mechanisms include: specific and non-specific adsorption (especially on soil organic matter), precipitation of newly formed phases, such as CuO, Cu(OH){sub 2}, Cu{sub 2}(OH){sub 3}NO{sub 3}, CuCO{sub 3}/Cu{sub 2}(OH){sub 2}CO{sub 3} and in the case of the Bordeaux mixture, precipitation of various Cu-hydroxysulfates. These phases were identified by the speciation model. The retention of fungicide-derived Cu in the studied soil types followed well the Freundlich isotherm and was directly controlled by the chemical form of Cu. This fact should be taken into account for both environmental and practical applications.

  6. Retention of copper originating from different fungicides in contrasting soil types

    International Nuclear Information System (INIS)

    Komarek, Michael; Vanek, Ales; Chrastny, Vladislav; Szakova, Jirina; Kubova, Karolina; Drahota, Petr; Balik, Jiri

    2009-01-01

    This work described the retention of Cu from two different commonly used pesticides, the Bordeaux mixture (CuSO 4 + Ca(OH) 2 ) and Cu-oxychloride (3Cu(OH) 2 .CuCl 2 ), and from Cu(NO 3 ) 2 in contrasting soil types (Leptosol, Chernozem, Cambisol). Thermodynamic modeling showed that Cu speciation was similar in all fungicide solutions. However, the retention of Cu differed with the fungicide used (maximum retention from the Bordeaux mixture) which indicates that different retention processes occurred in the studied soils. The suggested mechanisms include: specific and non-specific adsorption (especially on soil organic matter), precipitation of newly formed phases, such as CuO, Cu(OH) 2 , Cu 2 (OH) 3 NO 3 , CuCO 3 /Cu 2 (OH) 2 CO 3 and in the case of the Bordeaux mixture, precipitation of various Cu-hydroxysulfates. These phases were identified by the speciation model. The retention of fungicide-derived Cu in the studied soil types followed well the Freundlich isotherm and was directly controlled by the chemical form of Cu. This fact should be taken into account for both environmental and practical applications.

  7. Skyrmions and Hall viscosity

    Science.gov (United States)

    Kim, Bom Soo

    2018-05-01

    We discuss the contribution of magnetic Skyrmions to the Hall viscosity and propose a simple way to identify it in experiments. The topological Skyrmion charge density has a distinct signature in the electric Hall conductivity that is identified in existing experimental data. In an electrically neutral system, the Skyrmion charge density is directly related to the thermal Hall conductivity. These results are direct consequences of the field theory Ward identities, which relate various physical quantities based on symmetries and have been previously applied to quantum Hall systems.

  8. Viscosity and diffusivity in melts: from unary to multicomponent systems

    Science.gov (United States)

    Chen, Weimin; Zhang, Lijun; Du, Yong; Huang, Baiyun

    2014-05-01

    Viscosity and diffusivity, two important transport coefficients, are systematically investigated from unary melt to binary to multicomponent melts in the present work. By coupling with Kaptay's viscosity equation of pure liquid metals and effective radii of diffusion species, the Sutherland equation is modified by taking the size effect into account, and further derived into an Arrhenius formula for the convenient usage. Its reliability for predicting self-diffusivity and impurity diffusivity in unary liquids is then validated by comparing the calculated self-diffusivities and impurity diffusivities in liquid Al- and Fe-based alloys with the experimental and the assessed data. Moreover, the Kozlov model was chosen among various viscosity models as the most reliable one to reproduce the experimental viscosities in binary and multicomponent melts. Based on the reliable viscosities calculated from the Kozlov model, the modified Sutherland equation is utilized to predict the tracer diffusivities in binary and multicomponent melts, and validated in Al-Cu, Al-Ni and Al-Ce-Ni melts. Comprehensive comparisons between the calculated results and the literature data indicate that the experimental tracer diffusivities and the theoretical ones can be well reproduced by the present calculations. In addition, the vacancy-wind factor in binary liquid Al-Ni alloys with the increasing temperature is also discussed. What's more, the calculated inter-diffusivities in liquid Al-Cu, Al-Ni and Al-Ag-Cu alloys are also in excellent agreement with the measured and theoretical data. Comparisons between the simulated concentration profiles and the measured ones in Al-Cu, Al-Ce-Ni and Al-Ag-Cu melts are further used to validate the present calculation method.

  9. Microfluidics for simultaneous quantification of platelet adhesion and blood viscosity

    Science.gov (United States)

    Yeom, Eunseop; Park, Jun Hong; Kang, Yang Jun; Lee, Sang Joon

    2016-01-01

    Platelet functions, including adhesion, activation, and aggregation have an influence on thrombosis and the progression of atherosclerosis. In the present study, a new microfluidic-based method is proposed to estimate platelet adhesion and blood viscosity simultaneously. Blood sample flows into an H-shaped microfluidic device with a peristaltic pump. Since platelet aggregation may be initiated by the compression of rotors inside the peristaltic pump, platelet aggregates may adhere to the H-shaped channel. Through correlation mapping, which visualizes decorrelation of the streaming blood flow, the area of adhered platelets (APlatelet) can be estimated without labeling platelets. The platelet function is estimated by determining the representative index IA·T based on APlatelet and contact time. Blood viscosity is measured by monitoring the flow conditions in the one side channel of the H-shaped device. Based on the relation between interfacial width (W) and pressure ratio of sample flows to the reference, blood sample viscosity (μ) can be estimated by measuring W. Biophysical parameters (IA·T, μ) are compared for normal and diabetic rats using an ex vivo extracorporeal model. This microfluidic-based method can be used for evaluating variations in the platelet adhesion and blood viscosity of animal models with cardiovascular diseases under ex vivo conditions. PMID:27118101

  10. Glass viscosity calculation based on a global statistical modelling approach

    Energy Technology Data Exchange (ETDEWEB)

    Fluegel, Alex

    2007-02-01

    A global statistical glass viscosity model was developed for predicting the complete viscosity curve, based on more than 2200 composition-property data of silicate glasses from the scientific literature, including soda-lime-silica container and float glasses, TV panel glasses, borosilicate fiber wool and E type glasses, low expansion borosilicate glasses, glasses for nuclear waste vitrification, lead crystal glasses, binary alkali silicates, and various further compositions from over half a century. It is shown that within a measurement series from a specific laboratory the reported viscosity values are often over-estimated at higher temperatures due to alkali and boron oxide evaporation during the measurement and glass preparation, including data by Lakatos et al. (1972) and the recently published High temperature glass melt property database for process modeling by Seward et al. (2005). Similarly, in the glass transition range many experimental data of borosilicate glasses are reported too high due to phase separation effects. The developed global model corrects those errors. The model standard error was 9-17°C, with R^2 = 0.985-0.989. The prediction 95% confidence interval for glass in mass production largely depends on the glass composition of interest, the composition uncertainty, and the viscosity level. New insights in the mixed-alkali effect are provided.

  11. Mechanism underlying the inner membrane retention of Escherichia coli lipoproteins caused by Lol avoidance signals.

    Science.gov (United States)

    Hara, Takashi; Matsuyama, Shin-ichi; Tokuda, Hajime

    2003-10-10

    Escherichia coli lipoproteins are localized to either the inner or outer membrane depending on the residue at position 2. The inner membrane retention signal, Asp at position 2 in combination with certain residues at position 3, functions as a Lol avoidance signal, i.e. the signal inhibits the recognition of lipoproteins by LolCDE that releases lipoproteins from the inner membrane. To understand the role of the residue at position 2, outer membrane-specific lipoproteins with Cys at position 2 were subjected to chemical modification followed by the release reaction in reconstituted proteoliposomes. Sulfhydryl-specific introduction of nonprotein molecules or a negative charge to Cys did not inhibit the LolCDE-dependent release. In contrast, oxidation of Cys to cysteic acid resulted in generation of the Lol avoidance signal, indicating that the Lol avoidance signal requires a critical length of negative charge at the second residue. Furthermore, not only modification of the carboxylic acid of Asp at position 2 but also that of the amine of phosphatidylethanolamine abolished the Lol avoidance function. Based on these results, the Lol avoidance mechanism is discussed.

  12. Development of an ex vivo retention model simulating bioadhesion in the oral cavity using human saliva and physiologically relevant irrigation media.

    Science.gov (United States)

    Madsen, Katrine D; Sander, Camilla; Baldursdottir, Stefania; Pedersen, Anne Marie L; Jacobsen, Jette

    2013-05-20

    In recent years, there has been a particular interest in bioadhesive formulations for oromucosal drug delivery as this may promote prolonged local therapy and enhanced systemic effect. Saliva plays a vital role in oromucosal drug absorption by dissolving the drug and presenting it to the mucosal surface. However, the rheological, chemical, and interfacial properties of this complex biological fluid may strongly affect the adhesion of bioadhesive formulations. There is a need for well characterized in vitro models to assess the bioadhesive properties of oral dosage forms for administration in the oral cavity. Thus we aimed at developing an advanced ex vivo buccal retention model, with focus on choosing a physiologically relevant irrigation media closely resembling human saliva. Spray dried chitosan microparticles containing metformin hydrochloride as an example of a small hydrophilic drug, were employed as bioadhesive formulations. Chewing-stimulated human whole saliva was collected and characterized for use in retention studies in comparison with four artificial irrigation media; phosphate buffer, Saliva Orthana(®), porcine gastric mucin base media (PGM3), and xanthan gum based media (XG2). Retention of metformin, applied as spray dried microparticles on porcine buccal mucosa, greatly depended on the characteristics of the irrigation media. When rheology of the irrigation media was examined, changes in retention profiles could be interpreted, as irrigation media containing mucin and xanthan gum possessed a higher viscosity than phosphate buffer, which led to longer retention of the drug due to better hydration of the mucosa and the spray dried microparticles. Metformin retention profiles were comparable when human saliva, Saliva Orthana(®), or PGM3 were used as irrigation media. Moreover, PGM3 displayed physico-chemical properties closest to those of human saliva with regard to pH, protein content and surface tension. Saliva Orthana(®) and PGM3 are therefore

  13. Applying Magneto-rheology to Reduce Blood Viscosity and Suppress Turbulence to Prevent Heart Attacks

    Science.gov (United States)

    Tao, R.

    Heart attacks are the leading causes of death in USA. Research indicates one common thread, high blood viscosity, linking all cardiovascular diseases. Turbulence in blood circulation makes different regions of the vasculature vulnerable to development of atherosclerotic plaque. Turbulence is also responsible for systolic ejection murmurs and places heavier workload on heart, a possible trigger of heart attacks. Presently, neither medicine nor method is available to suppress turbulence. The only method to reduce the blood viscosity is to take medicine, such as aspirin. However, using medicine to reduce the blood viscosity does not help suppressing turbulence. In fact, the turbulence gets worse as the Reynolds number goes up with the viscosity reduction by the medicine. Here we report our new discovery: application of a strong magnetic field to blood along its flow direction, red blood cells are polarized in the magnetic field and aggregated into short chains along the flow direction. The blood viscosity becomes anisotropic: Along the flow direction the viscosity is significantly reduced, but in the directions perpendicular to the flow the viscosity is considerably increased. In this way, the blood flow becomes laminar, turbulence is suppressed, the blood circulation is greatly improved, and the risk for heart attacks is reduced. While these effects are not permanent, they last for about 24 hours after one magnetic therapy treatment.

  14. Correlation of shear and dielectric ion viscosity of dental resins - Influence of composition, temperature and filler content.

    Science.gov (United States)

    Steinhaus, Johannes; Hausnerova, Berenika; Haenel, Thomas; Selig, Daniela; Duvenbeck, Fabian; Moeginger, Bernhard

    2016-07-01

    Shear viscosity and ion viscosity of uncured visible light-curing (VLC) resins and resin based composites (RBC) are correlated with respect to the resin composition, temperature and filler content to check where Dielectric Analysis (DEA) investigations of VLC RBC generate similar results as viscosity measurements. Mixtures of bisphenol A glycidyl methacrylate (Bis-GMA) and triethylene glycol dimethacrylate (TEGDMA) as well as the pure resins were investigated and compared with two commercial VLC dental resins and RBCs (VOCO, Arabesk Top and Grandio). Shear viscosity data was obtained using a Haake Mars III, Thermo Scientific. Ion viscosity measurements performed by a dielectric cure analyzer (DEA 231/1 Epsilon with Mini IDEX-Sensor, Netzsch-Gerätebau). Shear viscosity depends reciprocally on the mobility of molecules, whereas the ion viscosity also depends on the ion concentration as it is affected by both ion concentration and mixture viscosity. Except of pure TEGDMA, shear and ion viscosities depend on the resin composition qualitatively in a similar manner. Furthermore, shear and ion viscosities of the commercial VLC dental resins and composites exhibited the same temperature dependency regardless of filler content. Application of typical rheological models (Kitano and Quemada) revealed that ion viscosity measurements can be described with respect to filler contents of up to 30vol.%. Rheological behavior of a VLC RBC can be characterized by DEA under the condition that the ion concentration is kept constant. Both methods address the same physical phenomenon - motion of molecules. The proposed relations allows for calculating the viscosity of any Bis-GMA-TEGDMA mixture on the base of the viscosities of the pure components. This study demonstrated the applicability of DEA investigations of VLC RBCs with respect to quality assurance purposes. Copyright © 2016 The Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

  15. Viscosity Measurements of SiO2-"FeO"-MgO System in Equilibrium with Metallic Fe

    Science.gov (United States)

    Chen, Mao; Raghunath, Sreekanth; Zhao, Baojun

    2014-01-01

    The present study delivers the measurements of viscosities in the SiO2-"FeO"-MgO system in equilibrium with metallic Fe. The rotational spindle technique was used for the measurements at the temperature range of 1523 K to 1773 K (1250 °C to 1500 °C). Molybdenum crucibles and spindles were employed in all measurements. The viscosity measurements were carried out at 31 to 47 mol pct SiO2 and up to 18.8 mol pct MgO. Analysis of the quenched sample by Electron probe X-ray microanalysis after the viscosity measurement enables the composition and microstructure of the slag to be directly linked with the viscosity. The replacement of "FeO" by MgO was found to increase viscosity and activation energy of the SiO2-"FeO"-MgO slags. The modified Quasi-chemical Viscosity Model was further optimized in this system based on the current viscosity measurements.

  16. Use of Intrinsic Viscosity for evaluation of polymer-solvent affinity

    DEFF Research Database (Denmark)

    Marani, Debora; Hjelm, Johan; Wandel, Marie

    2013-01-01

    The objective of the current paper was to define a rheological method for the study of the solvent/binder affinity. The adopted strategy involves the study of the intrinsic viscosity [η] of polymer solutions. [η] was estimated via an extrapolation procedure using the Huggins and Kramer equations....... The intrinsic viscosity and the Mark-Houwink shape parameter were estimated for the three polymers and used as criteria for estimating the polymer/solvent affinity....

  17. Effects of powdered versus liquid barium on the viscosity of fluids used in modified swallow studies

    International Nuclear Information System (INIS)

    Baron, J.; Alexander, T.

    2003-01-01

    To determine if the viscosity of thickened juice mixtures used in modified barium swallow studies significantly changes with the addition of powdered barium. We also describe a test formulation created using liquid barium, which has a negligible effect on juice viscosity. The viscosities of water and standardized honey- and nectar-consistency juices mixed with different amounts of powdered barium were measured by timing the laminar flow of a given initial hydrostatic head of fluid under gravity though an orifice of fixed diameter. Standardized juices were then mixed with a liquid formulation of barium and with measured quantities of water to produce viscosities that more closely equated with those of the standardized juices. With the addition of powdered barium, viscosity increased in all fluids, most markedly with the nectar-consistency juice. Liquid barium formulations maintained the viscosities of the original thickened juices. Rendering juices radio-opaque with barium powder results in dramatic increases in the viscosity of the resulting mixture and compromises diagnostic accuracy. Liquid barium preparations have the advantage that they can be rapidly and accurately dispensed by syringe, and their use does not significantly increase the viscosity of the preparation. (author)

  18. Effects of powdered versus liquid barium on the viscosity of fluids used in modified swallow studies

    Energy Technology Data Exchange (ETDEWEB)

    Baron, J.; Alexander, T. [Univ. of Alberta, Dept. of Radiology, Edmonton, Alberta (Canada)

    2003-06-01

    To determine if the viscosity of thickened juice mixtures used in modified barium swallow studies significantly changes with the addition of powdered barium. We also describe a test formulation created using liquid barium, which has a negligible effect on juice viscosity. The viscosities of water and standardized honey- and nectar-consistency juices mixed with different amounts of powdered barium were measured by timing the laminar flow of a given initial hydrostatic head of fluid under gravity though an orifice of fixed diameter. Standardized juices were then mixed with a liquid formulation of barium and with measured quantities of water to produce viscosities that more closely equated with those of the standardized juices. With the addition of powdered barium, viscosity increased in all fluids, most markedly with the nectar-consistency juice. Liquid barium formulations maintained the viscosities of the original thickened juices. Rendering juices radio-opaque with barium powder results in dramatic increases in the viscosity of the resulting mixture and compromises diagnostic accuracy. Liquid barium preparations have the advantage that they can be rapidly and accurately dispensed by syringe, and their use does not significantly increase the viscosity of the preparation. (author)

  19. Tomato juices and tomato juice concentrates : a study of factors contributing to their gross viscosity

    NARCIS (Netherlands)

    Heutink, R.

    1986-01-01

    The gross viscosity of tomato juice and tomato juice concentrates was found to be determined primarily by the water insoluble solids (WIS) content. The serum viscosity did not contribute to gross viscosity. The WIS consisted of whole tomato cells, vascular bundles and skin fragments. In general the

  20. Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition

    Directory of Open Access Journals (Sweden)

    W.-S. W. DeRieux

    2018-05-01

    Full Text Available Secondary organic aerosol (SOA accounts for a large fraction of submicron particles in the atmosphere. SOA can occur in amorphous solid or semi-solid phase states depending on chemical composition, relative humidity (RH, and temperature. The phase transition between amorphous solid and semi-solid states occurs at the glass transition temperature (Tg. We have recently developed a method to estimate Tg of pure compounds containing carbon, hydrogen, and oxygen atoms (CHO compounds with molar mass less than 450 g mol−1 based on their molar mass and atomic O : C ratio. In this study, we refine and extend this method for CH and CHO compounds with molar mass up to ∼ 1100 g mol−1 using the number of carbon, hydrogen, and oxygen atoms. We predict viscosity from the Tg-scaled Arrhenius plot of fragility (viscosity vs. Tg∕T as a function of the fragility parameter D. We compiled D values of organic compounds from the literature and found that D approaches a lower limit of ∼ 10 (±1.7 as the molar mass increases. We estimated the viscosity of α-pinene and isoprene SOA as a function of RH by accounting for the hygroscopic growth of SOA and applying the Gordon–Taylor mixing rule, reproducing previously published experimental measurements very well. Sensitivity studies were conducted to evaluate impacts of Tg, D, the hygroscopicity parameter (κ, and the Gordon–Taylor constant on viscosity predictions. The viscosity of toluene SOA was predicted using the elemental composition obtained by high-resolution mass spectrometry (HRMS, resulting in a good agreement with the measured viscosity. We also estimated the viscosity of biomass burning particles using the chemical composition measured by HRMS with two different ionization techniques: electrospray ionization (ESI and atmospheric pressure photoionization (APPI. Due to differences in detected organic compounds and signal intensity, predicted viscosities at low RH based on ESI and