Establishment of in situ TEM-implanter/accelerator interface facility at Wuhan University

International Nuclear Information System (INIS)

Guo, L.P.; Liu, C.S.; Li, M.; Song, B.; Ye, M.S.; Fu, D.J.; Fan, X.J.

2008-01-01

In order to perform in situ investigations on the evolution of microstructures during ion irradiation for the evaluation of irradiation-resistance performance of advanced materials, we have established a transmission electron microscope (TEM)-implanter/accelerator interface facility at Wuhan University, the first of its kind in China. A Hitachi H800 TEM was linked to a 200 kV ion implanter and a 2x1.7 MV tandem accelerator through the interface system designed on the basis of ion beam transportation calculations. Effective steps were taken to isolate the TEM from mechanical vibration transmitted from the ion beam lines, and no significant degradation of microscope resolution was observed when the TEM operated under high zoom modes during the ion implantation. In the test experiments, ion beams of N + , He + , Ar + , and H + were successfully transported from the implanter into the TEM chamber through the interface system, and the ion currents measured at the entrance of the TEM column were between 20 and 80 nA. The amorphisation process of Si crystal irradiated by N + ion beams was successfully observed in the preliminary experiments, demonstrating that this interface facility is capable of in situ study of ion irradiated samples

In Situ Environmental TEM in Imaging Gas and Liquid Phase Chemical Reactions for Materials Research.

Science.gov (United States)

Wu, Jianbo; Shan, Hao; Chen, Wenlong; Gu, Xin; Tao, Peng; Song, Chengyi; Shang, Wen; Deng, Tao

2016-11-01

Gas and liquid phase chemical reactions cover a broad range of research areas in materials science and engineering, including the synthesis of nanomaterials and application of nanomaterials, for example, in the areas of sensing, energy storage and conversion, catalysis, and bio-related applications. Environmental transmission electron microscopy (ETEM) provides a unique opportunity for monitoring gas and liquid phase reactions because it enables the observation of those reactions at the ultra-high spatial resolution, which is not achievable through other techniques. Here, the fundamental science and technology developments of gas and liquid phase TEM that facilitate the mechanistic study of the gas and liquid phase chemical reactions are discussed. Combined with other characterization tools integrated in TEM, unprecedented material behaviors and reaction mechanisms are observed through the use of the in situ gas and liquid phase TEM. These observations and also the recent applications in this emerging area are described. The current challenges in the imaging process are also discussed, including the imaging speed, imaging resolution, and data management. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Performance of a field emission gun TEM/STEM

International Nuclear Information System (INIS)

Carpenter, R.W.; Bentley, J.

1979-01-01

First experimental results on a Phillips EM 400 TEM/STEM fitted with a field-emission electron gun and objective twin lens are given here. Operation of the FEG is reliable up to maximum design voltage (120 kV). Highest resolution achieved in TEM was 1.9 A fringe. A wide variety of diffraction modes were demonstrated, ranging from CBDP from a small area (approx. 10 A dia) in STEM mode to SAD with angular resolution of 8 μrad in TEM mode. The EDS sensitivity is very high. STEM imaging performance to the highest magnifications examined (200 kx) is good. Work is in progress to evaluate the limits of STEM performance

Interpretation of interfacial structures in X-ray multilayers by TEM Fresnel fringe effects

OpenAIRE

Nguyen, Tai D.; O'Keefe, Michael A.; Kilaas, Roar; Gronsky, Ronald; Kortright, Jeffrey B.

1991-01-01

Assessment of interfacial structures from high-resolution TEM images of cross-sectional specimens is difficult due to Fresnel fringe effects producing different apparent structures in the images. The effects of these fringes have been commonly over-looked in efforts of making quantitative interpretation of interfacial profiles. In this report, we present the observations of the Fresnel fringes in nanometer period Mo/Si, W/C, and WC/C multilayers in through-focus-series TEM images. Calculation...

An Ultrahigh Resolution Structure of TEM-1 β-Lactamase Suggests a Role for Glu166 as the General Base in Acylation

International Nuclear Information System (INIS)

Minasov, George; Wang, Xiaojun; Shoichet, Brian K.

2002-01-01

Although TEM-1 β-lactamase is among the best studied enzymes, its acylation mechanism remains controversial. To investigate this problem, the structure of TEM-1 in complex with an acylation transition-state analogue was determined at ultrahigh resolution (0.85 (angstrom)) by X-ray crystallography. The quality of the data was such as to allow for refinement to an R-factor of 9.1% and an R free of 11.2%. In the resulting structure, the electron density features were clear enough to differentiate between single and double bonds in carboxylate groups, to identify multiple conformations that are occupied by residues and loops, and to assign 70% of the protons in the protein. Unexpectedly, even at pH 8.0 where the protein was crystallized, the active site residue Glu166 is clearly protonated. This supports the hypothesis that Glu166 is the general base in the acylation half of the reaction cycle. This structure suggests that Glu166 acts through the catalytic water to activate Ser70 for nucleophilic attack on the β-lactam ring of the substrate. The hydrolytic mechanism of class A β-lactamases, such as TEM-1, appears to be symmetrical, as are the serine proteases. Apart from its mechanistic implications, this atomic resolution structure affords an unusually detailed view of the structure, dynamics, and hydrogen-bonding networks of TEM-1, which may be useful for the design of inhibitors against this key antibiotic resistance target.

Fast FIB-milled Electron-transparent Microchips for in situ TEM Investigations

DEFF Research Database (Denmark)

Lei, Anders; Petersen, Dirch Hjorth; Kallesøe, Christian

In this work we present a fast approach to 50 nm resolution structures defined in a generic TEM-chip template in few minutes. While creating complex electrical and NEMS circuits for a specific insitu TEM experiment can be a cumbersome process, microchips with 100 nm thin flakes of single crystall......In this work we present a fast approach to 50 nm resolution structures defined in a generic TEM-chip template in few minutes. While creating complex electrical and NEMS circuits for a specific insitu TEM experiment can be a cumbersome process, microchips with 100 nm thin flakes of single...

Optimum aberration coefficients for recording high-resolution off-axis holograms in a Cs-corrected TEM

Energy Technology Data Exchange (ETDEWEB)

Linck, Martin, E-mail: linck@ceos-gmbh.de [CEOS GmbH, Englerstr. 28, D-69126 Heidelberg (Germany)

2013-01-15

Amongst the impressive improvements in high-resolution electron microscopy, the Cs-corrector also has significantly enhanced the capabilities of off-axis electron holography. Recently, it has been shown that the signal above noise in the reconstructable phase can be significantly improved by combining holography and hardware aberration correction. Additionally, with a spherical aberration close to zero, the traditional optimum focus for recording high-resolution holograms ('Lichte's defocus') has become less stringent and both, defocus and spherical aberration, can be selected freely within a certain range. This new degree of freedom can be used to improve the signal resolution in the holographically reconstructed object wave locally, e.g. at the atomic positions. A brute force simulation study for an aberration corrected 200 kV TEM is performed to determine optimum values for defocus and spherical aberration for best possible signal to noise in the reconstructed atomic phase signals. Compared to the optimum aberrations for conventional phase contrast imaging (NCSI), which produce 'bright atoms' in the image intensity, the resulting optimum values of defocus and spherical aberration for off-axis holography enable 'black atom contrast' in the hologram. However, they can significantly enhance the local signal resolution at the atomic positions. At the same time, the benefits of hardware aberration correction for high-resolution off-axis holography are preserved. It turns out that the optimum is depending on the object and its thickness and therefore not universal. -- Highlights: Black-Right-Pointing-Pointer Optimized aberration parameters for high-resolution off-axis holography. Black-Right-Pointing-Pointer Simulation and analysis of noise in high-resolution off-axis holograms. Black-Right-Pointing-Pointer Improving signal resolution in the holographically reconstructed phase shift. Black-Right-Pointing-Pointer Comparison of &apos

Optimum aberration coefficients for recording high-resolution off-axis holograms in a Cs-corrected TEM

International Nuclear Information System (INIS)

Linck, Martin

2013-01-01

Amongst the impressive improvements in high-resolution electron microscopy, the Cs-corrector also has significantly enhanced the capabilities of off-axis electron holography. Recently, it has been shown that the signal above noise in the reconstructable phase can be significantly improved by combining holography and hardware aberration correction. Additionally, with a spherical aberration close to zero, the traditional optimum focus for recording high-resolution holograms (“Lichte's defocus”) has become less stringent and both, defocus and spherical aberration, can be selected freely within a certain range. This new degree of freedom can be used to improve the signal resolution in the holographically reconstructed object wave locally, e.g. at the atomic positions. A brute force simulation study for an aberration corrected 200 kV TEM is performed to determine optimum values for defocus and spherical aberration for best possible signal to noise in the reconstructed atomic phase signals. Compared to the optimum aberrations for conventional phase contrast imaging (NCSI), which produce “bright atoms” in the image intensity, the resulting optimum values of defocus and spherical aberration for off-axis holography enable “black atom contrast” in the hologram. However, they can significantly enhance the local signal resolution at the atomic positions. At the same time, the benefits of hardware aberration correction for high-resolution off-axis holography are preserved. It turns out that the optimum is depending on the object and its thickness and therefore not universal. -- Highlights: ► Optimized aberration parameters for high-resolution off-axis holography. ► Simulation and analysis of noise in high-resolution off-axis holograms. ► Improving signal resolution in the holographically reconstructed phase shift. ► Comparison of “black” and “white” atom contrast in off-axis holograms.

A Structural Study of Escherichia coli Cells Using an In Situ Liquid Chamber TEM Technology

Directory of Open Access Journals (Sweden)

Yibing Wang

2015-01-01

Full Text Available Studying cell microstructures and their behaviors under living conditions has been a challenging subject in microbiology. In this work, in situ liquid chamber TEM was used to study structures of Escherichia coli cells in aqueous solutions at a nanometer-scale resolution. Most of the cells remained intact under electron beam irradiation, and nanoscale structures were observed during the TEM imaging. The analysis revealed structures of pili surrounding the E. coli cells; the movements of the pili in the liquid were also observed during the in situ tests. This technology also allowed the observation of features of the nucleoid in the E. coli cells. Overall, in situ TEM can be applied as a valuable tool to study real-time microscopic structures and processes in microbial cells residing in native aqueous solutions.

Novel sample preparation for operando TEM of catalysts

International Nuclear Information System (INIS)

Miller, Benjamin K.; Barker, Trevor M.; Crozier, Peter A.

2015-01-01

A new TEM sample preparation method is developed to facilitate operando TEM of gas phase catalysis. A porous Pyrex-fiber pellet TEM sample was produced, allowing a comparatively large amount of catalyst to be loaded into a standard Gatan furnace-type tantalum heating holder. The increased amount of catalyst present inside the environmental TEM allows quantitative determination of the gas phase products of a catalytic reaction performed in-situ at elevated temperatures. The product gas concentration was monitored using both electron energy loss spectroscopy (EELS) and residual gas analysis (RGA). Imaging of catalyst particles dispersed over the pellet at atomic resolution is challenging, due to charging of the insulating glass fibers. To overcome this limitation, a metal grid is placed into the holder in addition to the pellet, allowing catalyst particles dispersed over the grid to be imaged, while particles in the pellet, which are assumed to experience identical conditions, contribute to the overall catalytic conversion inside the environmental TEM cell. The gas within the cell is determined to be well-mixed, making this assumption reasonable. - Highlights: • High in-situ conversion of CO to CO 2 achieved by a novel TEM sample preparation method. • A 3 mm fiber pellet increases the TEM sample surface area by 50×. • Operando atomic resolution is maintained by also including a 3 mm grid in the sample. • Evidence for a well-mixed gas composition inside the ETEM cell is given

SAXS and TEM Investigation of Bentonite Structure

International Nuclear Information System (INIS)

Matusewicz, Michal; Liljestroem, Ville; Muurinen, Arto; Serimaa, Ritva

2013-01-01

A preliminary investigation of bentonite structure using Small-Angle X-ray Scattering (SAXS) and Transmission Electron Microscopy (TEM) is presented. Three types of clay were used: unchanged MX-80 bentonite and purified clays with sodium or calcium ions. Quantitative information in nano-scale - basal spacing, mean crystallite size - was obtained from SAXS, which was complemented by TEM to give qualitative information from micron to nanometre scale. SAXS seems to be a more reliable source of quantitative data than TEM. SAXS gives the averaged information about basal spacing. TEM in this study gives more qualitative information, but in a greater resolution range. The presented work is a starting point to combine more methods to obtain a better idea of bentonite structure. (authors)

In-Situ TEM-STM Observations of SWCNT Ropes/Tubular Transformations

Science.gov (United States)

Sola, F.; Lebron-Colon, M.; Ferreira, P. J.; Fonseca, L. F.; Meador, M. A.; Marin, C.

2010-01-01

Single-walled carbon nanotubes (SWCNTs) prepared by the HiPco process were purified using a modified gas phase purification technique. A TEM-STM holder was used to study the morphological changes of SWCNT ropes as a function of applied voltage. Kink formation, buckling behavior, tubular transformation and eventual breakdown of the system were observed. The tubular formation was attributed to a transformation from SWCNT ropes to multi-walled carbon nanotube (MWCNT) structures. It is likely mediated by the patching and tearing mechanism which is promoted primarily by the mobile vacancies generated due to current-induced heating and, to some extent, by electron irradiation.

Structural characterizaiton and gas reactions of small metal particles by high-resolution, in-situ TEM and TED

Science.gov (United States)

1984-01-01

The existing in-situ transmission electron microscopy (TEM) facility was improved by adding a separately pumped mini-specimen chamber. The chamber contains wire-evaporation sources for three metals and a specimen heater for moderate substrate temperatures. A sample introduction device was constructed, installed, and tested, facilitating rapid introduction of a specimen into the mini-chamber while maintaining the background pressure in that chamber in the 10(-9) millibar range. Small particles and clusters of Pd, grown by deposition from the vapor phase in an in-situ TEM facility on amorphous and crystalline support films of alumina and on ultra-thin carbon films, were analyzed by conventional high-resolution TEM and image analysis in terms of detectability, number density, and size distribution. The smallest particles that could be detected and counted contained no more than 6 atoms; size determinations could be made for particles 1 nm in diameter. The influence of various oxygen plasma treatments, annealing treatments, and of increasing the substrate temperature during deposition was investigated. The TEM technique was employed to demonstrate that under otherwise identica l conditions the lattice parameter of Pd particles in the 1 to 2 nm size range and supported in random orientation on ex-situ prepared mica films is expanded by some 3% when compared to 5 nm size particles. It is believed that this expansion is neither a small-particle diffraction effect nor due to pseudomorphism, but that it is due to a annealing-induced transformation of the small as-deposited particles with predominantly composite crystal structures into larger particles with true f.c.c. structure and thus inherently smaller lattice parameter.

In situ TEM observations of reverse dislocation motion upon unloading in tensile-deformed UFG aluminium

International Nuclear Information System (INIS)

Mompiou, Frédéric; Caillard, Daniel; Legros, Marc; Mughrabi, Haël

2012-01-01

Loading–unloading cycles have been performed on ultrafine-grained (UFG) aluminium inside a transmission electron microscope (TEM). The interaction of dislocations with grain boundaries, which is supposed to be at the origin of the inelastic behaviour of this class of materials, differs according to the main character of the dislocation segments involved in pile-ups. Pile-ups are formed by spiral sources and lead to the incorporation of dislocations into grain boundaries (GBs) during loading. Upon unloading, partial re-emission of dislocations from GBs can be observed. Stress and strain measurements performed during these in situ TEM loading–unloading experiments are in agreement with the rather large inelastic reverse strains observed during unloading in loading–unloading tests on bulk macroscopic UFG aluminium specimens.

A nonlinear filtering algorithm for denoising HR(S)TEM micrographs

International Nuclear Information System (INIS)

Du, Hongchu

2015-01-01

Noise reduction of micrographs is often an essential task in high resolution (scanning) transmission electron microscopy (HR(S)TEM) either for a higher visual quality or for a more accurate quantification. Since HR(S)TEM studies are often aimed at resolving periodic atomistic columns and their non-periodic deviation at defects, it is important to develop a noise reduction algorithm that can simultaneously handle both periodic and non-periodic features properly. In this work, a nonlinear filtering algorithm is developed based on widely used techniques of low-pass filter and Wiener filter, which can efficiently reduce noise without noticeable artifacts even in HR(S)TEM micrographs with contrast of variation of background and defects. The developed nonlinear filtering algorithm is particularly suitable for quantitative electron microscopy, and is also of great interest for beam sensitive samples, in situ analyses, and atomic resolution EFTEM. - Highlights: • A nonlinear filtering algorithm for denoising HR(S)TEM images is developed. • It can simultaneously handle both periodic and non-periodic features properly. • It is particularly suitable for quantitative electron microscopy. • It is of great interest for beam sensitive samples, in situ analyses, and atomic resolution EFTEM

Accelerator-TEM interface facility and application

International Nuclear Information System (INIS)

Liu Chuansheng; Li Ming; He Jun; Yang Zheng; Zhou Lin; Wang Zesong; Guo Liping; Jiang Changzhong; Yang Shibo; Fu Dejun; Fan Xiangjun; Liu Jiarui; Lee J C

2010-01-01

An accelerator-TEM interface facility has been established at Wuhan University in 2008. The system consists of an H800 TEM linked to a 200 kV ion implanter and a 2 x 1.7 MV tandem accelerator. Nitrogen ions at 115 keV were successfully transported from the implanter into the TEM chamber through the interface system, and the ion currents measured at the entrance of the TEM column were between 20 and 180 nA. Structural evolution caused by ion irradiation in Si, GaAs, nanocrystal Ag was observed in situ. The in situ observation showed that the critical implantation dose for amorphization of Si is 10 14 cm -2 . The nuclear material C276 samples implanted with 115 keV Ar + was also studied, and dislocation loops sized at 3-12 nm were clearly observed after implantation to doses of over 1 x 10 15 cm -2 . The density of the loops increased with the dose. Evolution to polycrystalline and amorphous structures were observed at 5 x l0 15 cm -2 and 3 x 10 16 cm -2 , respectively. An in situ RBS/C chamber was installed on the transport line of the accelerator-TEM interface system. This enables in situ measurement of composition and location of the implanted species in lattice of the samples. In addition, a 50 kV low-energy gaseous ion generator was installed close to the TEM chamber, which facilitates in situ TEM observation of helium bubbles formed in helium-implanted materials. (authors)

Moessbauer effect and TEM in mineralogy

International Nuclear Information System (INIS)

Ferrow, E.A.

1994-01-01

Moessbauer effect (ME) provides useful information on oxidation state, co-ordination number, co-ordination state, site occupancies, and magnetic properties of Fe-bearing phases. The information gained by ME together with the information provided by other conventional techniques is used to extract temperature, pressure, and kinetics of rock-forming processes. Nevertheless, ME requires that the phases studied are homogeneous over an extremely large volume and that Fe is a major component of the system. Transmission electron microscopy (TEM), on the other hand, provides similar information over a very small volume for a system of any component. However, present TEM spectrometers do not provide sufficient resolution to detect the mixed oxidation state. A complete characterisation of phases in rocks requires, therefore, that conventional techniques be combined with TEM. (orig.)

High resolution solar observations

International Nuclear Information System (INIS)

Title, A.

1985-01-01

Currently there is a world-wide effort to develop optical technology required for large diffraction limited telescopes that must operate with high optical fluxes. These developments can be used to significantly improve high resolution solar telescopes both on the ground and in space. When looking at the problem of high resolution observations it is essential to keep in mind that a diffraction limited telescope is an interferometer. Even a 30 cm aperture telescope, which is small for high resolution observations, is a big interferometer. Meter class and above diffraction limited telescopes can be expected to be very unforgiving of inattention to details. Unfortunately, even when an earth based telescope has perfect optics there are still problems with the quality of its optical path. The optical path includes not only the interior of the telescope, but also the immediate interface between the telescope and the atmosphere, and finally the atmosphere itself

Aberration-corrected STEM/TEM imaging at 15 kV

International Nuclear Information System (INIS)

Sasaki, Takeo; Sawada, Hidetaka; Hosokawa, Fumio; Sato, Yuta; Suenaga, Kazu

2014-01-01

The performance of aberration-corrected (scanning) transmission electron microscopy (S/TEM) at an accelerating voltage of 15 kV was evaluated in a low-voltage microscope equipped with a cold-field emission gun and a higher-order aberration corrector. Aberrations up to the fifth order were corrected by the aberration measurement and auto-correction system using the diffractogram tableau method in TEM and Ronchigram analysis in STEM. TEM observation of nanometer-sized particles demonstrated that aberrations up to an angle of 50 mrad were compensated. A TEM image of Si[110] exhibited lattice fringes with a spacing of 0.192 nm, and the power spectrum of the image showed spots corresponding to distances of 0.111 nm. An annular dark-field STEM image of Si[110] showed lattice fringes of (111) and (22¯0) planes corresponding to lattice distances of 0.314 nm and 0.192 nm, respectively. At an accelerating voltage of 15 kV, the developed low-voltage microscope achieved atomic-resolution imaging with a small chromatic aberration and a large uniform phase. - Highlights: • Aberration-corrected STEM/TEM imaging at 15 kV demonstrated lattice fringes of Si[110] single crystal with a spacing of 0.192 nm. • To achieve this performance at a lower accelerating voltage, uniform phase area over 50 mrad is mandatory in Ronchigram and Diffractogram tableau. • This means a higher-order aberration of six-fold astigmatism should be compensated. • In addition, decreasing the effect of chromatic aberration plays an important role for improving the performance of linear scattering component at 15 kV TEM

TEM investigation of discommensurations in a Bi-Sr-Ca-Cu-O superconductor

International Nuclear Information System (INIS)

El boussiri, K.; Rais, T.; Schneck, J.; Toledano, J.C.; Morin, D.

1997-01-01

We were able to observe, by transmission electron microscopy (TEM), a certain type ot defects in the superconducting bismuth cuprates. High-resolution evidence for the translation slip across a wall is obtained in this material. A consistent relationship is established between the observed characteristics of the walls in this family: number of walls merging at a node, average distance between discommensurations, value of the modulation wavenumber. We show that a wide range of ''latent'' commensurate periods ''4b'', determine the characteristics of the walls. (orig.)

In situ TEM observation of the growth and decomposition of monoclinic W18O49 nanowires

International Nuclear Information System (INIS)

Chen, C L; Mori, H

2009-01-01

The growth of monoclinic W 18 O 49 nanowires by heat treatment of a tungsten filament at ∼873 K and the decomposition of these nanowires under 200 keV electron irradiation at ∼1023 K have been investigated using in situ transmission electron microscopy (TEM). In situ TEM observation of the growth confirmed the vapor-solid growth mechanism of the monoclinic W 18 O 49 nanowires. In situ irradiation experiments revealed the formation of metallic bcc tungsten from monoclinic W 18 O 49 nanowires under 200 keV electron irradiation.

In-situ TEM observation of nano-void formation in UO2 under irradiation

Science.gov (United States)

Sabathier, C.; Martin, G.; Michel, A.; Carlot, G.; Maillard, S.; Bachelet, C.; Fortuna, F.; Kaitasov, O.; Oliviero, E.; Garcia, P.

2014-05-01

Transmission electron microscopy (TEM) observations of UO2 polycrystals irradiated in situ with 4 MeV Au ions were performed at room temperature (RT) to better understand the mechanisms of cavity and ultimately fission products nucleation in UO2. Experiments were carried out at the JANNuS Orsay facility that enables in situ ion irradiations inside the microscope to be carried out. The majority of 4 MeV gold ions were transmitted through the thin foil, and the induced radiation defects were investigated by TEM. Observations showed that nano-void formation occurs at ambient temperature in UO2 thin foils irradiated with energetic heavy ions under an essentially nuclear energy loss regime. The diameter and density of nano-objects were measured as a function of the gold irradiation dose at RT. A previous paper has also revealed a similar nano-object population after a Xe implantation performed at 390 keV at 870 K. The nano-object density was modelled using simple concepts derived from Classical Molecular Dynamics simulations. The results are in good agreement, which suggests a mechanism of heterogeneous nucleation induced by energetic cascade overlaps. This indicates that nano-void formation mechanism is controlled by radiation damage. Such nanovoids are likely to act as sinks for mobile fission products during reactor operation.

Accelerator-based single-shot ultrafast transmission electron microscope with picosecond temporal resolution and nanometer spatial resolution

Science.gov (United States)

Xiang, D.; Fu, F.; Zhang, J.; Huang, X.; Wang, L.; Wang, X.; Wan, W.

2014-09-01

We present feasibility study of an accelerator-based ultrafast transmission electron microscope (u-TEM) capable of producing a full field image in a single-shot with simultaneous picosecond temporal resolution and nanometer spatial resolution. We study key physics related to performance of u-TEMs and discuss major challenges as well as possible solutions for practical realization of u-TEMs. The feasibility of u-TEMs is confirmed through simulations using realistic electron beam parameters. We anticipate that u-TEMs with a product of temporal and spatial resolution beyond 10-19 ms will open up new opportunities in probing matter at ultrafast temporal and ultrasmall spatial scales.

Characterising ambient and vacuum performance of a miniaturised TEM nanoindenter for in-situ material deformation

Energy Technology Data Exchange (ETDEWEB)

Wang, J J; Lockwood, A J; Gay, R; Inkson, B J [Department of Engineering Materials, University of Sheffield, Sheffield SI 3JD (United Kingdom)], E-mail: beverley.inkson@Sheffield.ac.uk

2008-08-15

A miniaturised nanomanipulation and nanoindentation system has been designed and manufactured to perform sub-micron localised in-situ deformation studies in a high resolution transmission electron microscope (HRTEM). The nanomanipulation drive comprises two independent mechanisms for both coarse and fine positioning of sharp indenter tips. Small slip-stick inertial sliders are used to coarsely position a tip which fits inside a bespoke hollowed specimen holder for a JEOL (Japan) 2010/3010 series microscope. The coarse drive comprises three fully independent sliders which are set mutually perpendicular to one another (x, y and z) with a range > 1 mm and resolution {approx} 100 nm. Fine positioning is achieved with a quartered piezoelectric tube with range {approx} 2 {mu}m and resolution < 1 A. Optical displacement sensors have been used to characterise the nanomanipulation drive performance including total displacement rate and step size in ambient conditions. These are compared to the operation of the drive within a TEM under vacuum conditions. TEM observations at high magnification enable optimisation of the fine and coarse motion and overall drive stiffness.

Size Determination of Au Aerosol Nanoparticles by Off-Line TEM/STEM Observations

Science.gov (United States)

Karlsson, Lisa S.; Deppert, Knut; Malm, Jan-Olle

2006-12-01

Determination of particle size distributions of Au aerosol nanoparticles has been performed by a TEM/STEM investigation. The particles are generated by an evaporation/condensation method and are size-selected by differential mobility analyzers (DMA) based on their electrical mobility. Off-line TEM measurements resulted in equivalent projected area diameters assuming that the particles are spherical in shape. In this paper critical factors such as magnification calibration, sampling, image analysis, beam exposure and, particle shape are treated. The study shows that the measures of central tendency; mean, median and mode, are equal as expected from a narrow size distribution. Moreover, the correlation between TEM/STEM and DMA are good, in practice 1:1. Also, STEM has the advantage over TEM due to enhanced contrast and is proposed as an alternative route for determination of particle size distributions of nanoparticles with lower contrast.

Size Determination of Au Aerosol Nanoparticles by Off-Line TEM/STEM Observations

International Nuclear Information System (INIS)

Karlsson, Lisa S.; Deppert, Knut; Malm, Jan-Olle

2006-01-01

Determination of particle size distributions of Au aerosol nanoparticles has been performed by a TEM/STEM investigation. The particles are generated by an evaporation/condensation method and are size-selected by differential mobility analyzers (DMA) based on their electrical mobility. Off-line TEM measurements resulted in equivalent projected area diameters assuming that the particles are spherical in shape. In this paper critical factors such as magnification calibration, sampling, image analysis, beam exposure and, particle shape are treated. The study shows that the measures of central tendency; mean, median and mode, are equal as expected from a narrow size distribution. Moreover, the correlation between TEM/STEM and DMA are good, in practice 1:1. Also, STEM has the advantage over TEM due to enhanced contrast and is proposed as an alternative route for determination of particle size distributions of nanoparticles with lower contrast

Stereoscopic methods in TEM

International Nuclear Information System (INIS)

Thomas, L.E.

1975-07-01

Stereoscopic methods used in TEM are reviewed. The use of stereoscopy to characterize three-dimensional structures observed by TEM has become widespread since the introduction of instruments operating at 1 MV. In its emphasis on whole structures and thick specimens this approach differs significantly from conventional methods of microstructural analysis based on three-dimensional image reconstruction from a number of thin-section views. The great advantage of stereo derives from the ability to directly perceive and measure structures in three-dimensions by capitalizing on the unsurpassed human ability for stereoscopic matching of corresponding details on picture pairs showing the same features from different viewpoints. At this time, stereo methods are aimed mainly at structural understanding at the level of dislocations, precipitates, and irradiation-induced point-defect clusters in crystal and on the cellular irradiation-induced point-defect clusters in crystal and on the cellular level of biological specimens. 3-d reconstruction methods have concentrated on the molecular level where image resolution requirements dictate the use of very thin specimens. One recent application of three-dimensional coordinate measurements is a system developed for analyzing depth variations in the numbers, sizes and total volumes of voids produced near the surfaces of metal specimens during energetic ion bombardment. This system was used to correlate the void volumes at each depth along the ion range with the number of atomic displacements produced at that depth, thereby unfolding the entire swelling versus dose relationship from a single stereo view. A later version of this system incorporating computer-controlled stereo display capabilities is now being built

In situ EELS and TEM observation of Al implanted with nitrogen ions

International Nuclear Information System (INIS)

Hojou, K.; Furuno, S.; Kushita, K.N.; Otsu, H.; Izui, K.

1995-01-01

Formation processes of Aluminum nitride (AIN) in Aluminum (AI) implanted with nitrogen were examined by in situ EELS and TEM observations during nitrogen ion implantation in an electron microscope at room temperature and 400 deg C. AIN phase was identified both by EDP and EELS after nitrogen ion implantation to 6 x 10 20 (N + )/m 2 . The observed peak (20.8 eV) in EELS spectra was identified as plasmon loss peak of AIN formed in AI. The binding energy of N ls in AI was found to shift by about 4 eV to the lower side with increasing nitrogen-ion fluence. Unreacted AI was also found to remain in the AIN films after high fluence implantation both at room temperature and 400 deg C. (authors). 11 refs., 5 figs., 2 tabs

Accelerator-based Single-shot Ultrafast Transmission Electron Microscope with Picosecond Temporal Resolution and Nanometer Spatial Resolution

OpenAIRE

Xiang, D.; Fu, F.; Zhang, J.; Huang, X.; Wang, L.; Wang, X.; Wan, W.

2014-01-01

We present feasibility study of an accelerator-based ultrafast transmission electron microscope (u-TEM) capable of producing a full field image in a single-shot with simultaneous picosecond temporal resolution and nanometer spatial resolution. We study key physics related to performance of u-TEMs, and discuss major challenges as well as possible solutions for practical realization of u-TEMs. The feasibility of u-TEMs is confirmed through simulations using realistic electron beam parameters. W...

Direct observation of shear–induced nanocrystal attachment and coalescence in CuZr-based metallic glasses: TEM investigation

International Nuclear Information System (INIS)

Hajlaoui, K.; Alrasheedi, Nashmi H.; Yavari, A.R.

2016-01-01

In-situ tensile straining tests were performed in a transmission electron microscope (TEM) to analyse the deformation processes in CuZr-based metallic glasses and to directly observe the phase transformation occurrence. We report evidence of shear induced coalescence of nanocrystals in the vicinity of deformed regions. Nanocrystals grow in shear bands, come into contact, being attached and progressively coalesce under applied shear stress. - Highlights: • In-situ tensile straining test in TEM was investigated on CuZr-Based metallic glass. • Strain induces nanocrystallization and subsequent attachment and coalescence of nanocrystals. • The coalescence of nanocrystals compensates strain softening in metallic glasses.

TEM sample preparation by femtosecond laser machining and ion milling for high-rate TEM straining experiments

Energy Technology Data Exchange (ETDEWEB)

Voisin, Thomas; Grapes, Michael D. [Dept. of Materials Science and Engineering, Johns Hopkins University, Baltimore, MD 21218 (United States); Zhang, Yong [Dept. of Mechanical Engineering, Johns Hopkins University, Baltimore, MD 21218 (United States); Lorenzo, Nicholas; Ligda, Jonathan; Schuster, Brian [US Army Research Laboratory, Aberdeen Proving Ground, Aberdeen, MD 21005 (United States); Weihs, Timothy P. [Dept. of Materials Science and Engineering, Johns Hopkins University, Baltimore, MD 21218 (United States)

2017-04-15

To model mechanical properties of metals at high strain rates, it is important to visualize and understand their deformation at the nanoscale. Unlike post mortem Transmission Electron Microscopy (TEM), which allows one to analyze defects within samples before or after deformation, in situ TEM is a powerful tool that enables imaging and recording of deformation and the associated defect motion during mechanical loading. Unfortunately, all current in situ TEM mechanical testing techniques are limited to quasi-static strain rates. In this context, we are developing a new test technique that utilizes a rapid straining stage and the Dynamic TEM (DTEM) at the Lawrence Livermore National Laboratory (LLNL). The new straining stage can load samples in tension at strain rates as high as 4×10{sup 3}/s using two piezoelectric actuators operating in bending while the DTEM at LLNL can image in movie mode with a time resolution as short as 70 ns. Given the piezoelectric actuators are limited in force, speed, and displacement, we have developed a method for fabricating TEM samples with small cross-sectional areas to increase the applied stresses and short gage lengths to raise the applied strain rates and to limit the areas of deformation. In this paper, we present our effort to fabricate such samples from bulk materials. The new sample preparation procedure combines femtosecond laser machining and ion milling to obtain 300 µm wide samples with control of both the size and location of the electron transparent area, as well as the gage cross-section and length. - Highlights: • Tensile straining TEM specimens made by femtosecond laser machining and ion milling. • Accurate positioning of the electron transparent area within a controlled gauge region. • Optimization of femtosecond laser and ion milling parameters. • Fast production of numerous samples with a highly repeatable geometry.

Novel sample preparation for operando TEM of catalysts.

Science.gov (United States)

Miller, Benjamin K; Barker, Trevor M; Crozier, Peter A

2015-09-01

A new TEM sample preparation method is developed to facilitate operando TEM of gas phase catalysis. A porous Pyrex-fiber pellet TEM sample was produced, allowing a comparatively large amount of catalyst to be loaded into a standard Gatan furnace-type tantalum heating holder. The increased amount of catalyst present inside the environmental TEM allows quantitative determination of the gas phase products of a catalytic reaction performed in-situ at elevated temperatures. The product gas concentration was monitored using both electron energy loss spectroscopy (EELS) and residual gas analysis (RGA). Imaging of catalyst particles dispersed over the pellet at atomic resolution is challenging, due to charging of the insulating glass fibers. To overcome this limitation, a metal grid is placed into the holder in addition to the pellet, allowing catalyst particles dispersed over the grid to be imaged, while particles in the pellet, which are assumed to experience identical conditions, contribute to the overall catalytic conversion inside the environmental TEM cell. The gas within the cell is determined to be well-mixed, making this assumption reasonable. Copyright © 2015 Elsevier B.V. All rights reserved.

Application of TEM to highly reactive metals

International Nuclear Information System (INIS)

Sherry, W.M.; Prinz, F.

1982-01-01

In the following a method for the preparation and observation of sodium TEM specimens and the first TEM micrograph ever to be published on the dislocation microstructure of sodium are reported. (orig./IHOE) [de

In situ TEM observation of microcrack nucleation and propagation in pure tin solder

International Nuclear Information System (INIS)

Ding Ying; Wang Chunqing; Li, Mingyu; Wang Weiqiang

2006-01-01

Microcrack nucleation and propagation behavior in pure tin solder was investigated by using transmission electron microscopy (TEM) through in situ tensile test. Observation results showed that fracture process was completed in this visco-plastic material by connecting discontinuous cracks or voids. Depending on remarkable vacancy diffusion ability, microvoids were nucleated and developed in the dislocation free zone (DFZ) or super thinned area ahead of crack tip under local high stress concentration. The cracks were linked with each other by mutual dislocation emission which expedites the propagation of crack tips effectively

Challenges in quantitative crystallographic characterization of 3D thin films by ACOM-TEM.

Science.gov (United States)

Kobler, A; Kübel, C

2017-02-01

Automated crystal orientation mapping for transmission electron microscopy (ACOM-TEM) has become an easy to use method for the investigation of crystalline materials and complements other TEM methods by adding local crystallographic information over large areas. It fills the gap between high resolution electron microscopy and electron back scatter diffraction in terms of spatial resolution. Recent investigations showed that spot diffraction ACOM-TEM is a quantitative method with respect to sample parameters like grain size, twin density, orientation density and others. It can even be used in combination with in-situ tensile or thermal testing. However, there are limitations of the current method. In this paper we discuss some of the challenges and discuss solutions, e.g. we present an ambiguity filter that reduces the number of pixels with a '180° ambiguity problem'. For that an ACOM-TEM tilt series of nanocrystalline Pd thin films with overlapping crystallites was acquired and analyzed. Copyright © 2017. Published by Elsevier B.V.

Apparatus for observing a sample with a particle beam and an optical microscope

NARCIS (Netherlands)

2010-01-01

An apparatus for observing a sample (1) with a TEM column and an optical high resolution scanning microscope (10). The sample position when observing the sample with the TEM column differs from the sample position when observing the sample with the optical microscope in that in the latter case the

cisTEM, user-friendly software for single-particle image processing

Science.gov (United States)

2018-01-01

We have developed new open-source software called cisTEM (computational imaging system for transmission electron microscopy) for the processing of data for high-resolution electron cryo-microscopy and single-particle averaging. cisTEM features a graphical user interface that is used to submit jobs, monitor their progress, and display results. It implements a full processing pipeline including movie processing, image defocus determination, automatic particle picking, 2D classification, ab-initio 3D map generation from random parameters, 3D classification, and high-resolution refinement and reconstruction. Some of these steps implement newly-developed algorithms; others were adapted from previously published algorithms. The software is optimized to enable processing of typical datasets (2000 micrographs, 200 k – 300 k particles) on a high-end, CPU-based workstation in half a day or less, comparable to GPU-accelerated processing. Jobs can also be scheduled on large computer clusters using flexible run profiles that can be adapted for most computing environments. cisTEM is available for download from cistem.org. PMID:29513216

cisTEM, user-friendly software for single-particle image processing.

Science.gov (United States)

Grant, Timothy; Rohou, Alexis; Grigorieff, Nikolaus

2018-03-07

We have developed new open-source software called cis TEM (computational imaging system for transmission electron microscopy) for the processing of data for high-resolution electron cryo-microscopy and single-particle averaging. cis TEM features a graphical user interface that is used to submit jobs, monitor their progress, and display results. It implements a full processing pipeline including movie processing, image defocus determination, automatic particle picking, 2D classification, ab-initio 3D map generation from random parameters, 3D classification, and high-resolution refinement and reconstruction. Some of these steps implement newly-developed algorithms; others were adapted from previously published algorithms. The software is optimized to enable processing of typical datasets (2000 micrographs, 200 k - 300 k particles) on a high-end, CPU-based workstation in half a day or less, comparable to GPU-accelerated processing. Jobs can also be scheduled on large computer clusters using flexible run profiles that can be adapted for most computing environments. cis TEM is available for download from cistem.org. © 2018, Grant et al.

Challenges in quantitative crystallographic characterization of 3D thin films by ACOM-TEM

Energy Technology Data Exchange (ETDEWEB)

Kobler, A. [Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen (Germany); Karlsruhe Nano Micro Facility (KNMF), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen (Germany); Kübel, C., E-mail: christian.kuebel@kit.edu [Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen (Germany); Karlsruhe Nano Micro Facility (KNMF), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen (Germany)

2017-02-15

Automated crystal orientation mapping for transmission electron microscopy (ACOM-TEM) has become an easy to use method for the investigation of crystalline materials and complements other TEM methods by adding local crystallographic information over large areas. It fills the gap between high resolution electron microscopy and electron back scatter diffraction in terms of spatial resolution. Recent investigations showed that spot diffraction ACOM-TEM is a quantitative method with respect to sample parameters like grain size, twin density, orientation density and others. It can even be used in combination with in-situ tensile or thermal testing. However, there are limitations of the current method. In this paper we discuss some of the challenges and discuss solutions, e.g. we present an ambiguity filter that reduces the number of pixels with a ‘180° ambiguity problem’. For that an ACOM-TEM tilt series of nanocrystalline Pd thin films with overlapping crystallites was acquired and analyzed. - Highlights: • Tilt series of nanocrystalline Pd thin films. • Quantitative ACOM-TEM data processing, including a rotation map of crystallites. • Noise filter for orientation data: Ambiguity Filter and min. distance filter.

Optimized pre-thinning procedures of ion-beam thinning for TEM sample preparation by magnetorheological polishing.

Science.gov (United States)

Luo, Hu; Yin, Shaohui; Zhang, Guanhua; Liu, Chunhui; Tang, Qingchun; Guo, Meijian

2017-10-01

Ion-beam-thinning is a well-established sample preparation technique for transmission electron microscopy (TEM), but tedious procedures and labor consuming pre-thinning could seriously reduce its efficiency. In this work, we present a simple pre-thinning technique by using magnetorheological (MR) polishing to replace manual lapping and dimpling, and demonstrate the successful preparation of electron-transparent single crystal silicon samples after MR polishing and single-sided ion milling. Dimples pre-thinned to less than 30 microns and with little mechanical surface damage were repeatedly produced under optimized MR polishing conditions. Samples pre-thinned by both MR polishing and traditional technique were ion-beam thinned from the rear side until perforation, and then observed by optical microscopy and TEM. The results show that the specimen pre-thinned by MR technique was free from dimpling related defects, which were still residual in sample pre-thinned by conventional technique. Nice high-resolution TEM images could be acquired after MR polishing and one side ion-thinning. MR polishing promises to be an adaptable and efficient method for pre-thinning in preparation of TEM specimens, especially for brittle ceramics. Copyright © 2017 Elsevier B.V. All rights reserved.

Atomic-resolution environmental TEM for quantitative in-situ microscopy in materials science.

Science.gov (United States)

Takeda, Seiji; Yoshida, Hideto

2013-02-01

We have compiled our recent in-situ quantitative environmental transmission electron microscopy (ETEM) studies on typical gold nanoparticulate catalysts for the low-temperature oxidation of CO to describe the issues surrounding the application of ETEM, with a special regard to catalyst chemistry. Thanks to the recent development of high-resolution environmental transmission electron microscopes that can work robustly to accumulate observation data in controlled environments, we can deal with the electron irradiation effects and heterogeneity of real catalysts. We established a structural evolution diagram that summarizes the structure of catalysts under electron irradiation as a function of the electron current density ϕ and the electron dose, D. By extrapolating to ϕ = 0, D = 0, we could deduce the intrinsic catalysis structure (without electron irradiation) in various environments, including reaction environments. By numerically and statistically analyzing a substantial number of ETEM images of gold nanoparticles, we established a morphology phase diagram that summarizes how the majority of gold nanoparticles change their morphology systematically as a function of the partial pressures of CO and O(2). Similar diagrams will be helpful in elucidating the phenomena that directly correlate with the catalytic activity determined from ETEM observations. Using these quantitative analyses, we could analyze Cs-corrected ETEM images of the catalysts. The surfaces of gold nanoparticles were structurally reconstructed under reaction conditions, via interactions with CO molecules. CO molecules were observed on the surfaces of catalysts under reaction conditions using high-resolution ETEM. Finally, we discuss the potential of environmental transmission electron microscopy for quantitative in-situ microscopy at the atomic scale.

Preparation and Loading Process of Single Crystalline Samples into a Gas Environmental Cell Holder for In Situ Atomic Resolution Scanning Transmission Electron Microscopic Observation.

Science.gov (United States)

Straubinger, Rainer; Beyer, Andreas; Volz, Kerstin

2016-06-01

A reproducible way to transfer a single crystalline sample into a gas environmental cell holder for in situ transmission electron microscopic (TEM) analysis is shown in this study. As in situ holders have only single-tilt capability, it is necessary to prepare the sample precisely along a specific zone axis. This can be achieved by a very accurate focused ion beam lift-out preparation. We show a step-by-step procedure to prepare the sample and transfer it into the gas environmental cell. The sample material is a GaP/Ga(NAsP)/GaP multi-quantum well structure on Si. Scanning TEM observations prove that it is possible to achieve atomic resolution at very high temperatures in a nitrogen environment of 100,000 Pa.

In situ TEM observations of unusual nanocrystallization in a Ti-based bulk metallic glass

International Nuclear Information System (INIS)

Yan, M.; Wang, D.J.; Shen, J.; Qian, M.

2011-01-01

In situ transmission electron microscopy (TEM) has been used to witness the nanocrystallization of amorphous Ti 42.5 Cu 40 Zr 10 Ni 5 Sn 2.5 . A crystallization front exists to separate the TEM sample into two parts with different thermal stabilities. The number density of the crystallization products varies significantly, with the precipitate sizes ranging from a few nanometres to ∼100 nm. Detailed TEM analysis suggests that oxygen is the most likely reason for realizing the unusual nanocrystallization. External thermal analysis also indicates that oxygen affects the crystallization.

Investigation of C3 S hydration mechanism by transmission electron microscope (TEM) with integrated Super-XTM EDS system.

Science.gov (United States)

Sakalli, Y; Trettin, R

2017-07-01

Tricalciumsilicate (C 3 S, Alite) is the major component of the Portland cement clinker. Hydration of Alite is decisive in influencing the properties of the resulting material. This is due to its high content in cement. The mechanism of the hydration of C 3 S is very complicated and not yet fully understood. There are different models describing the hydration of C 3 S in various ways. In this work for a better understanding of hydration mechanism, the hydrated C 3 S was investigated by using the transmission electron microscope (TEM) and for the first time, the samples for the investigations were prepared by using of focused ion beam from sintered pellets of C 3 S. Also, an FEI Talos F200x with an integrated Super-X EDS system was used for the investigations. FEI Talos F200X combines outstanding high-resolution S/TEM and TEM imaging with energy dispersive X-ray spectroscopy signal detection, and 3D chemical characterization with compositional mapping. TEM is a very powerful tool for material science. A high energy beam of electrons passes through a very thin sample, and the interactions between the electrons and the atoms can be used to observe the structure of the material and other features in the structure. TEM can be used to study the growth of layers and their composition. TEM produces high-resolution, two-dimensional images and will be used for a wide range of educational, science and industry applications. Chemical analysis can also be performed. The purpose of these investigations was to get the information about the composition of the C-S-H phases and some details of the nanostructure of the C-S-H phases. © 2017 The Authors Journal of Microscopy © 2017 Royal Microscopical Society.

High-resolution TEM characterization of ZnO core-shell nanowires for dye-sensitized solar cells

Energy Technology Data Exchange (ETDEWEB)

Divitini, G; Ducati, C [Department of Materials Science, Pembroke Street, Cambridge, CB2 3QZ (United Kingdom); Plank, N O V; Welland, M E [Nanoscience Centre, Department of Engineering, University of Cambridge, CB3 0FF (United Kingdom); Snaith, H J, E-mail: gd322@cam.ac.u [Clarendon Laboratory, Department of Physics, University of Oxford, OX1 3PU (United Kingdom)

2010-07-01

Recently ZnO nanowire films have been used in very promising and inexpensive dye-sensitized solar cells (DSSC). It was found that the performance of the devices can be enhanced by functionalising the nanowires with a thin metal oxide coating. This nm-scale shell is believed to tailor the electronic structure of the nanowire, and help the absorption of the dye. Core-shell ZnO nanowire structures are synthesised at low temperature (below 120{sup 0}C) by consecutive hydrothermal growth steps. Different materials are investigated for the coating, including Mg, Al, Cs and Zr oxides. High resolution TEM is used to characterise the quality of both the nanowire core and the shell, and to monitor the thickness and the degree of crystallisation of the oxide coating. The interface between the nanowire core and the outer shell is investigated in order to understand the adhesion of the coating, and give valuable feedback for the synthesis process. Nanowire films are packaged into dye-sensitised solar cell prototypes; samples coated with ZrO{sub 2} and MgO show the largest enhancement in the photocurrent and open-circuit voltage and look very promising for further improvement.

Comparison of ultramicrotomy and focused-ion-beam for the preparation of TEM and STEM cross section of organic solar cells

DEFF Research Database (Denmark)

Corazza, Michael; Simonsen, Søren Bredmose; Gnaegi, Helmut

2016-01-01

The challenge of preparing cross sections of organic photovoltaics (OPV) suitable for transmission electron microscopy (TEM) and scanning TEM (STEM) is addressed. The samples were polymer solar cells fabricated using roll-to-roll (R2R) processing methods on a flexible polyethylene terephthalate...... resolution, enabling further studies of phase separation of P3HT:PCBM by means of energy filtered TEM (EFTEM). The sample prepared by FIB shows good structure preservation, but reduced resolution due to non-optimal thicknesses achieved after treatment. Degradation studies of samples prepared...

In situ TEM electromechanical testing of nanowires and nanotubes.

Science.gov (United States)

Espinosa, Horacio D; Bernal, Rodrigo A; Filleter, Tobin

2012-11-05

The emergence of one-dimensional nanostructures as fundamental constituents of advanced materials and next-generation electronic and electromechanical devices has increased the need for their atomic-scale characterization. Given its spatial and temporal resolution, coupled with analytical capabilities, transmission electron microscopy (TEM) has been the technique of choice in performing atomic structure and defect characterization. A number of approaches have been recently developed to combine these capabilities with in-situ mechanical deformation and electrical characterization in the emerging field of in-situ TEM electromechanical testing. This has enabled researchers to establish unambiguous synthesis-structure-property relations for one-dimensional nanostructures. In this article, the development and latest advances of several in-situ TEM techniques to carry out mechanical and electromechanical testing of nanowires and nanotubes are reviewed. Through discussion of specific examples, it is shown how the merging of several microsystems and TEM has led to significant insights into the behavior of nanowires and nanotubes, underscoring the significant role in-situ techniques play in the development of novel nanoscale systems and materials. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Soft nanomaterials analysed by in situ liquid TEM: Towards high resolution characterisation of nanoparticles in motion

Directory of Open Access Journals (Sweden)

Joseph P. Patterson

2015-12-01

Full Text Available In this article we present in situ transmission electron microscopy (TEM of soft, synthetic nanoparticles with a comparative analysis using conventional TEM methods. This comparison is made with the simple aim of describing what is an unprecedented example of in situ imaging by TEM. However, we contend the technique will quickly become essential in the characterisation of analogous systems, especially where dynamics are of interest in the solvated state. In this case, particles were studied which were obtained from the direct polymerisation of an oxaliplatin analogue, designed for an ongoing programme in novel chemotherapeutic delivery systems. The resulting nanoparticles provided sufficient contrast for facile imaging in situ, and point towards key design parameters that enable this new characterisation approach for organic nanomaterials. We describe the preparation of the synthetic nanoparticles together with their characterisation in liquid water. Finally, we provide a future perspective of this technique for the analysis of soft and dynamic nanomaterials and discussion the progress which needs to be made in order to bring in situ liquid TEM to its full potential.

TEM investigations of laser ablated particles

International Nuclear Information System (INIS)

Fliegel, D.; Dundas, S.; Kosler, J.; Klementova, M.

2009-01-01

Full text: Laser ablation inductively coupled plasma mass spectrometry suffers from fractionation effects hindering a non matrix matched calibration strategy. Different reasons for elemental fractionation that are related to the laser ablation, the transport and the vaporization in the plasma are discussed. One major question to be addressed linked to the vaporization yield in the ICP is in which of mineralogical phase the different ablated particle sizes enter the plasma. This contribution will investigate particles generated by a 213 nm laser from different samples such as minerals and alloys with respect to their chemical and phase compositions using high resolution TEM. (author)

Multi-component and multi-array TEM detection in karst tunnels

International Nuclear Information System (INIS)

Sun, Huaifeng; Li, Shucai; Su, Maoxin; Xue, Yiguo; Li, Xiu; Qi, Zhipeng

2012-01-01

Emerging applications of transient electromagnetic methods (TEM) in tunnelling require higher resolution on the distributions and shapes of low resistivity bodies, such as karst water and karst pipes, using multi-component and multi-array receivers. However, there are no apparent resistivity definitions for both vertical and horizontal components with offsets inside the loop. Although the raw field can show the differences of the earth electric structure, it is not straightforward. Apparent resistivity is very convenient and easy for engineers. We have developed a method for multi-component and multi-array TEM which can be applied in tunnelling and defined the expressions of apparent resistivity. This method takes advantage of the difference in resolution among components. A homogeneous half-space model and four typical three-layered models are used to test the effectiveness of the new definition. A field case history is carried out and analysed to demonstrate the viability of this technique. The results suggest that it is feasible to use the technique in tunnelling, especially for identifying the spatial distribution of karst water and karst pipes. (paper)

High spectral resolution X-ray observations of AGN

NARCIS (Netherlands)

Kaastra, J.S.

2008-01-01

brief overview of some highlights of high spectral resolution X-ray observations of AGN is given, mainly obtained with the RGS of XMM-Newton. Future prospects for such observations with XMM-Newton are given.

A sub-50meV spectrometer and energy filter for use in combination with 200kV monochromated (S)TEMs.

Science.gov (United States)

Brink, H A; Barfels, M M G; Burgner, R P; Edwards, B N

2003-09-01

A high-energy resolution post-column spectrometer for the purpose of electron energy loss spectroscopy (EELS) and energy-filtered TEM in combination with a monochromated (S)TEM is presented. The prism aberrations were corrected up to fourth order using multipole elements improving the electron optical energy resolution and increasing the acceptance of the spectrometer for a combination of object area and collection angles. Electronics supplying the prism, drift tube, high-tension reference and critical lenses have been newly designed such that, in combination with the new electron optics, a sub-50 meV energy resolution has been realized, a 10-fold improvement over past post-column spectrometer designs. The first system has been installed on a 200 kV monochromated TEM at the Delft University of Technology. Total system energy resolution of sub-100 meV has been demonstrated. For a 1s exposure the resolution degraded to 110 meV as a result of noise. No further degradation in energy resolution was measured for exposures up to 1 min at 120 kV. Spectral resolution measurements, performed on the pi* peak of the BN K-edge, demonstrated a 350 meV (FWHM) peak width at 200 kV. This measure is predominantly determined by the natural line width of the BN K-edge.

On the way to high resolution TEM characterization of dual ion beam irradiated ODS steels

International Nuclear Information System (INIS)

Hsiung, L.; Tumey, S.; Fluss, M. J.; King, W.; Marian, J.; Kuntz, J.; Dasher, B. El; Serruys, Y.; Willaime, F.; Kimura, A.

2009-01-01

Fission and fusion energy application of ODS steels while appearing promising requires that many key science issues be resolved. Among these issues are our incomplete understanding of the effect of irradiation on low-temperature fracture properties, the role of fusion relevant helium and hydrogen transmutation gases on the deformation and fracture of irradiated material at low and high temperatures, radiation-induced solute segregation and phase stability, mechanisms of swelling suppression in ODS steels, and the effects of radiation damage on localized deformation. While planning to focus on all these issues we are particularly interested in the atomic scale mechanism by which helium is mitigated by the nano scale particles. In order to obtain insight we are performing analytical transmission electron microscopy (AEM), high resolution electron microscopy (HRTEM) to investigate micro-structural and micro-compositional changes and property alterations of Fe-Cr ferritic/martensitic and ODS steels driven by temperature and ion-beam irradiation with Fe, H, and He. As a beginning to a collaboration between LLNL and CEA-Saclay, we have carried out an irradiation of four specimens, Fe, Fe14%Cr, and two ODS steels (14% Cr and 16% Cr) using the dual beam facility at CEA-Saclay (JANNuS). An Fe 8+ beam was implanted at 24 MeV and helium was implanted through a degrader wheel with energies between 1.7 MeV and 1.3 MeV. The nominal radiation parameters were 40 to 25 DPA, 10 to 25 appm He/DPA ratio, and specimen temperatures of ∼425 deg. C. Our goal is to compare the evolved microstructure with respect to the accumulation of helium at or near the particle matrix interface. Preparatory to this first study we have made many hi-resolution analyses of the nano-particles in the two ODS steels which serve as a base line for comparison with the TEM post irradiation examination reported here. These base line studies are reported separately at this conference. (author)

High resolution TEM study of Ni4Ti3 precipitates in austenitic Ni51Ti49

International Nuclear Information System (INIS)

Tirry, Wim; Schryvers, Dominique

2003-01-01

Binary NiTi with a composition of 51 at.% Ni was heat treated to form lens-shaped Ni 4 Ti 3 precipitates that are coherent or semi-coherent with the B2 matrix. High resolution transmission electron microscopy (HRTEM) was used to study the internal structure of the precipitates, precipitate-precipitate and matrix-precipitate interfaces and the deformation of the B2 matrix near a precipitate. Observations were made in the B2 and B2 zones and compared with computer simulated high resolution images. The B2 observations made it possible to study the [0 0 1] H zone orientation of Ni 4 Ti 3 (direction defined according to the hexagonal unit cell of Ni 4 Ti 3 ) which corresponds to the normal of the central plane of the discs. In these images the superperiodicity of the 4:3 ordering is clearly visible confirming the known atomic structure. Close to the precipitate the B2 matrix is deformed, as determined by measuring the interplanar spacing from the HRTEM images. The observed deformations are compared with theoretical models for the stress field

Behaviour of TEM metal grids during in-situ heating experiments.

Science.gov (United States)

Zhang, Zaoli; Su, Dangsheng

2009-05-01

The stability of Ni, Cu, Mo and Au transmission electron microscope (TEM) grids coated with ultra-thin amorphous carbon (alpha-C) or silicon monoxide film is examined by in-situ heating up to a temperature in the range 500-850 degrees C in a transmission electron microscope. It is demonstrated that some grids can generate nano-particles either due to the surface diffusion of metal atoms on amorphous film or due to the metal evaporation/redeposition. The emergence of nano-particles can complicate experimental observations, particularly in in-situ heating studies of dynamic behaviours of nano-materials in TEM. The most widely used Cu grid covered with amorphous carbon is unstable, and numerous Cu nano-particles start to form once the heating temperature reaches 600 degrees C. In the case of Ni grid covered with alpha-C film, a large number of Ni nano-crystals occur immediately when the temperature approaches 600 degrees C, accompanied by the graphitization of amorphous carbon. In contrast, both Mo and Au grids covered with alpha-C film exhibit good stability at elevated temperature, for instance, up to 680 and 850 degrees C for Mo and Au, respectively, and any other metal nano-particles are detected. Cu grid covered Si monoxide thin film is stable up to 550 degrees C, but Si nano-crystals appear under intensive electron beam. The generated nano-particles are well characterized by spectroscopic techniques (EDXS/EELS) and high-resolution TEM. The mechanism of nano-particle formation is addressed based on the interactions between the metal grid and the amorphous carbon film and on the sublimation of metal.

Quantitative in situ TEM tensile testing of an individual nickel nanowire

International Nuclear Information System (INIS)

Lu Yang; Peng Cheng; Ganesan, Yogeeswaran; Lou Jun; Huang Jianyu

2011-01-01

In this paper, we have demonstrated the usage of a novel micro-mechanical device (MMD) to perform quantitative in situ tensile tests on individual metallic nanowires inside a transmission electron microscope (TEM). Our preliminary experiment on a 360 nm diameter nickel nanowire showed that the sample fractured at an engineering stress of ∼ 1.2 GPa and an engineering strain of ∼ 4%, which is consistent with earlier experiments performed inside a scanning electron microscope (SEM). With in situ high resolution TEM imaging and diffraction capabilities, this novel experimental set-up could provide unique opportunities to reveal the underlying deformation and damage mechanisms for metals at the nanoscale.

TEM characterization of UO2-Gd2O3 nuclear fuels synthesized by coprecipitation method

International Nuclear Information System (INIS)

Soldati, A.; Gana Watkins, I.; Menghini, J.; Prado, M.

2013-01-01

We present a micro and nano structural characterization of 4% weight doped Gd 2 O 3 -UO 2 pellet using Transmission Electron Microscopy (TEM). Agglomerate morphology and crystallite sizes were determined using light/dark field and high resolution (HR-TEM) images. Convergent beam Energy Dispersive Spectroscopy (EDS) and Electron Diffraction (ED) were used to evaluate sample composition and homogeneity, even at the nanometer scale. We obtained an average crystallite size of 90±20 nm. Moreover, from TEM-EDS analyses we determined the presence of Gadolinium in all the analyzed crystallites but with 25% variation among their concentrations. These results show the capability of TEM analysis to characterize a nuclear fuel pellet with burnable poisons nano structure and homogeneity.(author)

Optimization of Monochromated TEM for Ultimate Resolution Imaging and Ultrahigh Resolution Electron Energy Loss Spectroscopy

KAUST Repository

Lopatin, Sergei; Cheng, Bin; Liu, Wei-Ting; Tsai, Meng-Lin; He, Jr-Hau; Chuvilin, Andrey

2017-01-01

The performance of a monochromated transmission electron microscope with Wien type monochromator is optimized to achieve an extremely narrow energy spread of electron beam and an ultrahigh energy resolution with spectroscopy. The energy spread in the beam is improved by almost an order of magnitude as compared to specified values. The optimization involves both the monochromator and the electron energy loss detection system. We demonstrate boosted capability of optimized systems with respect to ultra-low loss EELS and sub-angstrom resolution imaging (in a combination with spherical aberration correction).

Optimization of Monochromated TEM for Ultimate Resolution Imaging and Ultrahigh Resolution Electron Energy Loss Spectroscopy

KAUST Repository

Lopatin, Sergei

2017-09-01

The performance of a monochromated transmission electron microscope with Wien type monochromator is optimized to achieve an extremely narrow energy spread of electron beam and an ultrahigh energy resolution with spectroscopy. The energy spread in the beam is improved by almost an order of magnitude as compared to specified values. The optimization involves both the monochromator and the electron energy loss detection system. We demonstrate boosted capability of optimized systems with respect to ultra-low loss EELS and sub-angstrom resolution imaging (in a combination with spherical aberration correction).

Comparison between measured and predicted turbulence frequency spectra in ITG and TEM regimes

Science.gov (United States)

Citrin, J.; Arnichand, H.; Bernardo, J.; Bourdelle, C.; Garbet, X.; Jenko, F.; Hacquin, S.; Pueschel, M. J.; Sabot, R.

2017-06-01

The observation of distinct peaks in tokamak core reflectometry measurements—named quasi-coherent-modes (QCMs)—are identified as a signature of trapped-electron-mode (TEM) turbulence (Arnichand et al 2016 Plasma Phys. Control. Fusion 58 014037). This phenomenon is investigated with detailed linear and nonlinear gyrokinetic simulations using the Gene code. A Tore-Supra density scan is studied, which traverses through a linear (LOC) to saturated (SOC) ohmic confinement transition. The LOC and SOC phases are both simulated separately. In the LOC phase, where QCMs are observed, TEMs are robustly predicted unstable in linear studies. In the later SOC phase, where QCMs are no longer observed, ion-temperature-gradient (ITG) modes are identified. In nonlinear simulations, in the ITG (SOC) phase, a broadband spectrum is seen. In the TEM (LOC) phase, a clear emergence of a peak at the TEM frequencies is seen. This is due to reduced nonlinear frequency broadening of the underlying linear modes in the TEM regime compared with the ITG regime. A synthetic diagnostic of the nonlinearly simulated frequency spectra reproduces the features observed in the reflectometry measurements. These results support the identification of core QCMs as an experimental marker for TEM turbulence.

Graphene-based sample supports for in situ high-resolution TEM electrical investigations

International Nuclear Information System (INIS)

Westenfelder, B; Scholz, F; Meyer, J C; Biskupek, J; Algara-Siller, G; Lechner, L G; Kaiser, U; Kusterer, J; Kohn, E; Krill, C E III

2011-01-01

Specially designed transmission electron microscopy (TEM) sample carriers have been developed to enable atomically resolved studies of the heat-induced evolution of adsorbates on graphene and their influence on electrical conductivity. Here, we present a strategy for graphene-based carrier realization, evaluating its design with respect to fabrication effort and applications potential. We demonstrate that electrical current can lead to very high temperatures in suspended graphene membranes, and we determine that current-induced cleaning of graphene results from Joule heating.

Processing grounded-wire TEM signal in time-frequency-pseudo-seismic domain: A new paradigm

Science.gov (United States)

Khan, M. Y.; Xue, G. Q.; Chen, W.; Huasen, Z.

2017-12-01

Grounded-wire TEM has received great attention in mineral, hydrocarbon and hydrogeological investigations for the last several years. Conventionally, TEM soundings have been presented as apparent resistivity curves as function of time. With development of sophisticated computational algorithms, it became possible to extract more realistic geoelectric information by applying inversion programs to 1-D & 3-D problems. Here, we analyze grounded-wire TEM data by carrying out analysis in time, frequency and pseudo-seismic domain supported by borehole information. At first, H, K, A & Q type geoelectric models are processed using a proven inversion program (1-D Occam inversion). Second, time-to-frequency transformation is conducted from TEM ρa(t) curves to magneto telluric MT ρa(f) curves for the same models based on all-time apparent resistivity curves. Third, 1-D Bostick's algorithm was applied to the transformed resistivity. Finally, EM diffusion field is transformed into propagating wave field obeying the standard wave equation using wavelet transformation technique and constructed pseudo-seismic section. The transformed seismic-like wave indicates that some reflection and refraction phenomena appear when the EM wave field interacts with geoelectric interface at different depth intervals due to contrast in resistivity. The resolution of the transformed TEM data is significantly improved in comparison to apparent resistivity plots. A case study illustrates the successful hydrogeophysical application of proposed approach in recovering water-filled mined-out area in a coal field located in Ye county, Henan province, China. The results support the introduction of pseudo-seismic imaging technology in short-offset version of TEM which can also be an useful aid if integrated with seismic reflection technique to explore possibilities for high resolution EM imaging in future.

Transmission Electron Microscopy (TEM) Sample Preparation of Si(1-x)Gex in c-Plane Sapphire Substrate

Science.gov (United States)

Kim, Hyun Jung; Choi, Sang H.; Bae, Hyung-Bin; Lee, Tae Woo

2012-01-01

The National Aeronautics and Space Administration-invented X-ray diffraction (XRD) methods, including the total defect density measurement method and the spatial wafer mapping method, have confirmed super hetero epitaxy growth for rhombohedral single crystalline silicon germanium (Si1-xGex) on a c-plane sapphire substrate. However, the XRD method cannot observe the surface morphology or roughness because of the method s limited resolution. Therefore the authors used transmission electron microscopy (TEM) with samples prepared in two ways, the focused ion beam (FIB) method and the tripod method to study the structure between Si1-xGex and sapphire substrate and Si1?xGex itself. The sample preparation for TEM should be as fast as possible so that the sample should contain few or no artifacts induced by the preparation. The standard sample preparation method of mechanical polishing often requires a relatively long ion milling time (several hours), which increases the probability of inducing defects into the sample. The TEM sampling of the Si1-xGex on sapphire is also difficult because of the sapphire s high hardness and mechanical instability. The FIB method and the tripod method eliminate both problems when performing a cross-section TEM sampling of Si1-xGex on c-plane sapphire, which shows the surface morphology, the interface between film and substrate, and the crystal structure of the film. This paper explains the FIB sampling method and the tripod sampling method, and why sampling Si1-xGex, on a sapphire substrate with TEM, is necessary.

Nonlinear entropy transfer in ETG-TEM turbulence via TEM driven zonal flows

International Nuclear Information System (INIS)

Asahi, Yuuichi; Tsutsui, Hiroaki; Tsuji-Iio, Shunji; Ishizawa, Akihiro; Sugama, Hideo; Watanabe, Tomohiko

2015-01-01

Nonlinear interplay of the electron temperature gradient (ETG) modes and the trapped electron modes (TEMs) was investigated by means of gyrokinetic simulation. Focusing on the situation where both TEMs and ETG modes are linearly unstable, the effects of TEM-driven zonal flows on ETG turbulence were examined by means of entropy transfer analysis. In a statistically steady turbulence where the TEM driven zonal flows are dominant, it turned out that the zonal flows meditate the entropy transfer of the ETG modes from the low to high radial wavenumber regions. The successive entropy transfer broadens the potential fluctuation spectrum in the radial wavenumber direction. In contrast, in the situation where ETG modes are unstable but TEMs are stable, the pure ETG turbulence does not produce strong zonal flows, leading to a rather narrow spectrum in the radial wavenumber space and a higher transport level. (author)

Electron beam fabrication and characterization of high-resolution magnetic force microscopy tips

Science.gov (United States)

Rührig, M.; Porthun, S.; Lodder, J. C.; McVitie, S.; Heyderman, L. J.; Johnston, A. B.; Chapman, J. N.

1996-03-01

The stray field, magnetic microstructure, and switching behavior of high-resolution electron beam fabricated thin film tips for magnetic force microscopy (MFM) are investigated with different imaging modes in a transmission electron microscope (TEM). As the tiny smooth carbon needles covered with a thermally evaporated magnetic thin film are transparent to the electron energies used in these TEMs it is possible to observe both the external stray field emanating from the tips as well as their internal domain structure. The experiments confirm the basic features of electron beam fabricated thin film tips concluded from various MFM observations using these tips. Only a weak but highly concentrated stray field is observed emanating from the immediate apex region of the tip, consistent with their capability for high resolution. It also supports the negligible perturbation of the magnetization sample due to the tip stray field observed in MFM experiments. Investigation of the magnetization distributions within the tips, as well as preliminary magnetizing experiments, confirm a preferred single domain state of the high aspect ratio tips. To exclude artefacts of the observation techniques both nonmagnetic tips and those supporting different magnetization states are used for comparison.

Preparation and observation of an artifact-free Ge2Sb2Te5 TEM specimen by the small angle cleavage technique

International Nuclear Information System (INIS)

Kim, M.S.; Kim, H.G.

2006-01-01

The amorphous Ge 2 Sb 2 Te 5 thin film for the application to the non-volatile memory device was prepared by the pulsed laser deposition on a SiO2/Si substrate. The amorphous Ge 2 Sb 2 Te 5 which has the T C around 150 deg. C is readily crystallized when exposed to a comparable heat such as the Ar beam irradiation during the conventional ion milling process. Retaining its amorphous initial phase is important in order to precisely observe and understand the crystallization behaviour whether it be the sample for a pure materialistic research or applied into the device. To avoid such deterioration of the film's amorphous nature, the complete mechanical TEM specimen preparation which is called the small angle cleavage technique (SACT) was adopted to show thermally undisturbed, an artifact-free amorphous Ge 2 Sb 2 Te 5 TEM specimen. The two distinctive amorphous and crystalline phases has been observed by the HRTEM study

TEM Imaging of Mass-selected Polymer Molecules

International Nuclear Information System (INIS)

Nasibulin, Albert G.; Kauppinen, Esko I.; Thomson, Bruce A.; Fernandez de la Mora, J.

2002-01-01

Polyethylene glycol (PEG) molecules with masses below 1300 amu are electrosprayed (ES) from solution, mobility-selected at high resolution in a differential mobility analyzer (DMA), collected on a grid and imaged by transmission electron microscopy (ES-DMA-TEM). The DMA resolves individual n-mers, and selects only one out of the many present in the original sample. Ion identity is established from parallel mass spectra (ES-MS). The images reveal spherical particles 1.46 nm in diameter, in good agreement with the known ion mass and bulk density. The DMA-selection technique opens new paths for the study of very small particles

Exploration of shallow subsurface resistivity structure using a portable TEM system: TEM-FAST prosystem; Kan`igata TEM ho sochi TEM-FAST prosystem ni yoru senbu hiteiko chosa

Energy Technology Data Exchange (ETDEWEB)

Miura, Y; Kumekawa, Y; Takasugi, S [GERD Geothermal Energy Research and Development Co. Ltd., Tokyo (Japan)

1997-05-27

Discussions were given on effectiveness of the TEM-FAST ProSystem which is a portable TEM system developed recently for use in exploration of shallow subsurface resistivity. The system consists of a loop type antenna, the TEM-FAST as the main equipment, and a host computer, the host computer controlling the entire system. The system acquires transient response data in secondary induced magnetic fields lasting 4 {mu} sec to 1 m sec. The number of data is 5490 stacks in one measurement, and the data acquisition time is about three minutes. Measurements were carried out by using the TEM-FAST in the vicinity of a well, whose results were compared with those of electric logging, and discussions were given on them. Although the electric logging results had no data available for depths shallower than 35 m, the measurement results from the TEM-FAST were found highly harmonious with those of the electric logging. In addition, there were transmission and telephone lines in locations about 10 m away from the well during the measurement, but extremely high data quality was discovered. 6 refs., 7 figs., 1 tab.

Cassette-based in-situ TEM sample inspection in the dual-beam FIB

International Nuclear Information System (INIS)

Kendrick, A B; Moore, T M; Zaykova-Feldman, L; Amador, G; Hammer, M

2008-01-01

A novel method is presented, combining site-specific TEM sample preparation and in-situ STEM analysis in a dual-beam microscope (FIB/SEM) fitted with a chamber mounted nano-manipulator. TEM samples are prepared using a modified in-situ, lift-out method, whereby the samples are thinned and oriented for immediate in-situ STEM analysis using the tilt, translation, and rotation capabilities of a FIB/SEM sample stage, a nano-manipulator, and a novel cassette. This cassette can provide a second tilt axis, orthogonal to the stage tilt axis, so that the STEM image contrast can be optimized to reveal the structural features of the sample (true STEM imaging in the FIB/SEM). The angles necessary for stage rotation and probe shaft rotation are calculated based on the position of the nano-manipulator relative to the stage and door and the stage tilt angle. A FIB/SEM instrument, equipped with a high resolution scanning electron column, can provide sufficiently high image resolution to enable many failure analysis and process control applications to be successfully carried out without requiring the use of a separate dedicated TEM/STEM instrument. The benefits of this novel approach are increased throughput and reduced cost per sample. Comparative analysis of different sample preparation methods is provided, and the STEM images obtained are shown.

Quantitative TEM analysis of Al/Cu multilayer systems prepared by pulsed laser deposition

DEFF Research Database (Denmark)

Liu, Haihua; Pryds, Nini; Schou, Jørgen

2010-01-01

Thin films composed of alternating Al/Cu/Al layers were deposited on a (111) Si substrate using pulsed laser deposition (PLD). The thicknesses of the film and the individual layers, and the detailed internal structure within the layers were characterized by means of transmission electron microscopy...... for the formation of the first layer of nano-sized Al grains. The results demonstrate that the PLD technique is a powerful tool to produce nano-scale multilayered metal films with controllable thickness and grain sizes....... (TEM), high-resolution TEM (HRTEM), and energy-filtered TEM (EFTEM). Each Al or Cu layer consists of a single layer of nano-sized grains of different orientations. EFTEM results revealed a layer of oxide about 2 nm thick on the surface of the Si substrate, which is considered to be the reason...

Correlating TEM images of damage in irradiated materials to molecular dynamics simulations

International Nuclear Information System (INIS)

Schaeublin, R.; Caturla, M.-J.; Wall, M.; Felter, T.; Fluss, M.; Wirth, B.D.; Diaz de la Rubia, T.; Victoria, M.

2002-01-01

TEM image simulations are used to couple the results from molecular dynamics (MD) simulations to experimental TEM images. In particular we apply this methodology to the study of defects produced during irradiation. MD simulations have shown that irradiation of FCC metals results in a population of vacancies and interstitials forming clusters. The limitation of these simulations is the short time scales available, on the order of 100 s of picoseconds. Extrapolation of the results from these short times to the time scales of the laboratory has been difficult. We address this problem by two methods: we perform TEM image simulations of MD simulations of cascades with an improved technique, to relate defects produced at short time scales with those observed experimentally at much longer time scales. On the other hand we perform in situ TEM experiments of Au irradiated at liquid-nitrogen temperatures, and study the evolution of the produced damage as the temperature is increased to room temperature. We find that some of the defects observed in the MD simulations at short time scales using the TEM image simulation technique have features that resemble those observed in laboratory TEM images of irradiated samples. In situ TEM shows that stacking fault tetrahedra are present at the lowest temperatures and are stable during annealing up to room temperature, while other defect clusters migrate one dimensionally above -100 deg. C. Results are presented here

Detecting single-electron events in TEM using low-cost electronics and a silicon strip sensor.

Science.gov (United States)

Gontard, Lionel C; Moldovan, Grigore; Carmona-Galán, Ricardo; Lin, Chao; Kirkland, Angus I

2014-04-01

There is great interest in developing novel position-sensitive direct detectors for transmission electron microscopy (TEM) that do not rely in the conversion of electrons into photons. Direct imaging improves contrast and efficiency and allows the operation of the microscope at lower energies and at lower doses without loss in resolution, which is especially important for studying soft materials and biological samples. We investigate the feasibility of employing a silicon strip detector as an imaging detector for TEM. This device, routinely used in high-energy particle physics, can detect small variations in electric current associated with the impact of a single charged particle. The main advantages of using this type of sensor for direct imaging in TEM are its intrinsic radiation hardness and large detection area. Here, we detail design, simulation, fabrication and tests in a TEM of the front-end electronics developed using low-cost discrete components and discuss the limitations and applications of this technology for TEM.

FIB and TEM studies of damage mechanisms in DLC coatings sliding against aluminum

International Nuclear Information System (INIS)

Meng-Burany, X.; Alpas, A.T.

2007-01-01

Material transfer and adhesion phenomena during sliding contact of non-hydrogenated diamond like carbon (DLC) coatings against an aluminum-silicon (319 Al) counterface tested in vacuum were studied using TEM investigations of the cross-sectional microstructures of the wear tracks. Site-specific focused ion beam (FIB) lift-out method was used to prepare the sections at the precise locations where aluminum pieces were adhered to the DLC surface. The dense amorphous structure of DLC coatings with nanocrystalline graphite platelets is confirmed by the high-resolution transmission electron microscopy. The focused ion channeling contrast images obtained from the cross-sections of the wear track indicated that in some sections of DLC coatings considerable wear was inflicted by aluminum, reducing the coating thickness. The aluminum that was transferred on the DLC coatings' contact surfaces consisted of nanocrystalline grains of less than 100 nm. TEM examination of the contact surface of the 319 Al pin has revealed that the initial aluminum grain size was also reduced to the nanocrystalline scale and this was accompanied with a hardness increase. These observations revealed that local severe plastic deformation accompanied the aluminum adhesion process to DLC coating surfaces

High resolution solar observations from first principles to applications

Science.gov (United States)

Verdoni, Angelo P.

2009-10-01

The expression "high-resolution observations" in Solar Physics refers to the spatial, temporal and spectral domains in their entirety. High-resolution observations of solar fine structure are a necessity to answer many of the intriguing questions related to solar activity. However, a researcher building instruments for high-resolution observations has to cope with the fact that these three domains often have diametrically opposed boundary conditions. Many factors have to be considered in the design of a successful instrument. Modern post-focus instruments are more closely linked with the solar telescopes that they serve than in past. In principle, the quest for high-resolution observations already starts with the selection of the observatory site. The site survey of the Advanced Technology Solar Telescope (ATST) under the stewardship of the National Solar Observatory (NSO) has identified Big Bear Solar Observatory (BBSO) as one of the best sites for solar observations. In a first step, the seeing characteristics at BBSO based on the data collected for the ATST site survey are described. The analysis will aid in the scheduling of high-resolution observations at BBSO as well as provide useful information concerning the design and implementation of a thermal control system for the New Solar Telescope (NST). NST is an off-axis open-structure Gregorian-style telescope with a 1.6 m aperture. NST will be housed in a newly constructed 5/8-sphere ventilated dome. With optics exposed to the surrounding air, NST's open-structure design makes it particularly vulnerable to the effects of enclosure-related seeing. In an effort to mitigate these effects, the initial design of a thermal control system for the NST dome is presented. The goal is to remediate thermal related seeing effects present within the dome interior. The THermal Control System (THCS) is an essential component for the open-telescope design of NST to work. Following these tasks, a calibration routine for the

Is the TEM obsolescent?

International Nuclear Information System (INIS)

Williams, D.B.

2002-01-01

Full text: The TEM has undergone many revolutions since its invention 70 years ago, but is now a very mature instrument. The major functions of imaging, diffraction and analysis were invented decades ago. Much of the instrument development in the last 20 years has come in peripheral improvements such as ease of operation and computer control which, nevertheless, have made no substantial differences to basic operational methods. The TEM remains a predominantly manual instrument, still providing analog viewing and recording, well into the digital age. Indeed any operator of a Siemens Elmiskop 1 TEM from the 1950s would be more than skilled enough to operate a modern FEG TEM, with little more than a few minutes of training. It is arguable that no other cutting-edge scientific instrument is so basically unchanged in its method of operation over the last five decades, as the TEM. This state of affairs is a recipe for obsolescence. Students today are not interested in mastering the complexities of balancing potentiometers (which are still necessary for good centered dark-field operation) or manipulating sets of tilt controls to move from to , while fighting to maintain eucentricity and a recognizable image on the screen at 200 kX. Students are already masters of the mouse, keyboard or joystick and expect information to be generated, stored, processed and analyzed rapidly and efficiently under full computer control. We need to provide today's students with an instrument to challenge their skills, not those of their parents. There is nothing preventing the creation of a TEM that is under full computer control, except perhaps the notion that the TEM is an instrument worthy of mastery per se, rather than being simply a tool for the characterization of materials. In contrast, the SEM has never been seen as a 'real' electron microscope and consequently has found its way into many more research, education and commercial operations than the TEM. The SEM has also evolved

High Resolution Active Optics Observations from the Kepler Follow-up Observation Program

Science.gov (United States)

Gautier, Thomas N.; Ciardi, D. R.; Marcy, G. W.; Hirsch, L.

2014-01-01

The ground based follow-up observation program for candidate exoplanets discovered with the Kepler observatory has supported a major effort for high resolution imaging of candidate host stars using adaptive optics wave-front correction (AO), speckle imaging and lucky imaging. These images allow examination of the sky as close as a few tenths of an arcsecond from the host stars to detect background objects that might be the source of the Kepler transit signal instead of the host star. This poster reports on the imaging done with AO cameras on the Keck, Palomar 5m and Shane 3m (Lick Observatory) which have been used to obtain high resolution images of over 500 Kepler Object of Interest (KOI) exoplanet candidate host stars. All observations were made at near infrared wavelengths in the J, H and K bands, mostly using the host target star as the AO guide star. Details of the sensitivity to background objects actually attained by these observations and the number of background objects discovered are presented. Implications to the false positive rate of the Kepler candidates are discussed.

HUMAN CAPSULE EPITHELIAL-CELL DEGENERATION A LM, SEM AND TEM INVESTIGATION

NARCIS (Netherlands)

JONGEBLOED, WL; KALICHARAN, D; WORST, JGF

1993-01-01

The degeneration of the capsule epithelium of cataractous lenses has been studied with LM, SEM on TEM with emphases on TEM. The observed degeneration of the epithelial cells can be described as follows: The cell nucleus becomes picnotic and desintegrates as result of change of the chromatin.

Oxidation in ceria infiltrated metal supported SOFCs – A TEM investigation

DEFF Research Database (Denmark)

Knibbe, Ruth; Wang, Hsiang-Jen; Blennow Tullmar, Peter

2013-01-01

electron microscopy (TEM) techniques including energy-dispersive X-ray spectroscopy and electron energy-loss spectroscopy of focus ion beamed TEM samples. The infiltrated CGO is predominately converted into CeFeO3 after high temperature processing, protecting the alloy. A thin layer of Cr-oxide is observed...

Complete Tem-Tomography: 3D Structure of Gems Cluster

Science.gov (United States)

Matsuno, J.; Miyake, A.; Tsuchiyama, A.; Messenger, S.; Nakamura-Messenger, K.

2015-01-01

GEMS (glass with embedded metal and sulfide) grains in interplanetary dust particles (IDPs) are considered to be one of the ubiquitous and fundamental building blocks of solids in the Solar System. They have been considered to be interstellar silicate dust that survived various metamorphism or alteration processes in the protoplanetary disk but the elemental and isotopic composition measurements suggest that most of them have been formed in the protoplanetary disk as condensates from high temperature gas. This formation model is also supported by the formation of GEMS-like grains with respect to the size, mineral assemblage, texture and infrared spectrum by condensation experiments from mean GEMS composition materials. Previous GEMS studies were performed only with 2D observation by transmission electron microscopy (TEM) or scanning TEM (STEM). However, the 3D shape and structure of GEMS grains and the spatial distribution of Fe/FeS's has critical information about their formation and origin. Recently, the 3D structure of GEMS grains in ultrathin sections of cluster IDPs was revealed by electron tomography using a TEM/STEM (JEM-2100F, JEOL). However, CT images of thin sections mounted on Cu grids acquired by conventional TEM-tomography are limited to low tilt angles (e. g., less than absolute value of 75 deg. In fact, previous 3D TEM observations of GEMS were affected by some artifacts related to the limited tilt range in the TEM used. Complete tomographic images should be acquired by rotating the sample tilt angle over a range of more than absolute value of 80 deg otherwise the CT images lose their correct structures. In order to constrain the origin and formation process of GEMS grains more clearly, we performed complete electron tomography for GEMS grains. Here we report the sample preparation method we have developed for this study, and the preliminary results.

Distortion of DNA Origami on Graphene Imaged with Advanced TEM Techniques.

Science.gov (United States)

Kabiri, Yoones; Ananth, Adithya N; van der Torre, Jaco; Katan, Allard; Hong, Jin-Yong; Malladi, Sairam; Kong, Jing; Zandbergen, Henny; Dekker, Cees

2017-08-01

While graphene may appear to be the ultimate support membrane for transmission electron microscopy (TEM) imaging of DNA nanostructures, very little is known if it poses an advantage over conventional carbon supports in terms of resolution and contrast. Microscopic investigations are carried out on DNA origami nanoplates that are supported onto freestanding graphene, using advanced TEM techniques, including a new dark-field technique that is recently developed in our lab. TEM images of stained and unstained DNA origami are presented with high contrast on both graphene and amorphous carbon membranes. On graphene, the images of the origami plates show severe unwanted distortions, where the rectangular shape of the nanoplates is significantly distorted. From a number of comparative control experiments, it is demonstrated that neither staining agents, nor screening ions, nor the level of electron-beam irradiation cause this distortion. Instead, it is suggested that origami nanoplates are distorted due to hydrophobic interaction of the DNA bases with graphene upon adsorption of the DNA origami nanoplates. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

High-Resolution Characterization of UMo Alloy Microstructure

Energy Technology Data Exchange (ETDEWEB)

Devaraj, Arun [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Kovarik, Libor [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Joshi, Vineet V. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Jana, Saumyadeep [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Manandhar, Sandeep [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Arey, Bruce W. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lavender, Curt A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

2016-11-30

This report highlights the capabilities and procedure for high-resolution characterization of UMo fuels in PNNL. Uranium-molybdenum (UMo) fuel processing steps, from casting to forming final fuel, directly affect the microstructure of the fuel, which in turn dictates the in-reactor performance of the fuel under irradiation. In order to understand the influence of processing on UMo microstructure, microstructure characterization techniques are necessary. Higher-resolution characterization techniques like transmission electron microscopy (TEM) and atom probe tomography (APT) are needed to interrogate the details of the microstructure. The findings from TEM and APT are also directly beneficial for developing predictive multiscale modeling tools that can predict the microstructure as a function of process parameters. This report provides background on focused-ion-beam–based TEM and APT sample preparation, TEM and APT analysis procedures, and the unique information achievable through such advanced characterization capabilities for UMo fuels, from a fuel fabrication capability viewpoint.

Direct Observations of Oxygen-induced Platinum Nanoparticle Ripening Studied by In Situ TEM

DEFF Research Database (Denmark)

Simonsen, Søren Bredmose; Chorkendorff, Ib; Dahl, Søren

2010-01-01

This study addresses the sintering mechanism of Pt nanoparticles dispersed on a planar, amorphous Al2O3 support as a model system for a catalyst for automotive exhaust abatement. By means of in situ transmission electron microscopy (TEM), the model catalyst was monitored during the exposure to 10...

TEM characterization of plate-shaped L12-(Al,Ag)3Ti precipitates in a Ag-modified TiAl based intermetallics

International Nuclear Information System (INIS)

Yuan, Y.; Liu, H.W.; Zhao, X.N.; Meng, X.K.; Liu, Z.G.

2006-01-01

L1 2 -(Al,Ag) 3 Ti phase in a L1 0 -TiAl(Ag) intermetallic compound with a nominal composition of Ti-54 at.% Al-4 at.% Ag has been studied by transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM) and energy dispersive X-ray (EDX). TEM observations revealed that the alloy aged at 1273 K consists of L1 0 phase and L1 2 phase. The compositions of L1 2 phase and the matrix have been determined. The habit plane of L1 2 phase was analyzed by trace line method. It was revealed that the habit plane changed to one of {1 1 2) planes compared with our previous result. The semi-coherent interface was formed between L1 0 phase and L1 2 phase. HRTEM characterized the interface structure directly. The dislocation loops and ledges at the interphase boundary were observed. The results were discussed in terms of the competition between elastic strain and interfacial energy, ledge mechanism of phase transformation caused by long-range diffusion of the atoms

In Situ TEM Electrical Measurements

DEFF Research Database (Denmark)

Canepa, Silvia; Alam, Sardar Bilal; Ngo, Duc-The

2016-01-01

understanding of complex physical and chemical interactions in the pursuit to optimize nanostructure function and device performance. Recent developments of sample holder technology for TEM have enabled a new field of research in the study of functional nanomaterials and devices via electrical stimulation...... influence the sample by external stimuli, e.g. through electrical connections, the TEM becomes a powerful laboratory for performing quantitative real time in situ experiments. Such TEM setups enable the characterization of nanostructures and nanodevices under working conditions, thereby providing a deeper...... and measurement of the specimen. Recognizing the benefits of electrical measurements for in situ TEM, many research groups have focused their effort in this field and some of these methods have transferred to ETEM. This chapter will describe recent advances in the in situ TEM investigation of nanostructured...

In situ mechanical TEM: seeing and measuring under stress with electrons

International Nuclear Information System (INIS)

Legros, M.

2014-01-01

From the first observation of moving dislocations in 1956 to the latest developments of piezo-actuated sample holders and direct electron sensing cameras in modern transmission electron microscopes (TEM), in situ mechanical testing has brought an unequaled view of the involved mechanisms during the plastic deformation of materials. Although MEMS-based or load-cell equipped holders provide an almost direct measure of these quantities, deriving stress and strain from in situ TEM experiments has an extensive history. Nowadays, the realization of a complete mechanical test while observing the evolution of a dislocation structure is possible, and it constitutes the perfect combination to explore size effects in plasticity. New cameras, data acquisition rates and intrinsic image-related techniques, such as holography, should extend the efficiency and capabilities of in situ deformation inside a TEM. (author)

Strain study of gold nanomaterials as HR-TEM calibration standard.

Science.gov (United States)

Peng, X Y; Zhou, L Q; Li, X; Tao, X F; Ren, L L; Cao, W H; Xu, G F

2015-12-01

This work presents the use of high resolution electron microscopy (HREM) and geometric phase analysis (GPA) to measure the interplanar spacing and strain distribution of three gold nanomaterials, respectively. The results showed that the {111} strain was smaller than the {002} strain for any kind of gold materials at the condition of same measuring method. The 0.65% of {111} strain in gold film measured by HREM (0.26% measured by GPA) was smaller than the {111} strains in two gold particles. The presence of lattice strain was interpreted according to the growth mechanism of metallic thin film. It is deduced that the {111} interplanar spacing of the gold thin film is suitable for high magnification calibration of transmission electron microscopy (TEM) and the gold film is potential to be a new calibration standard of TEM. Copyright © 2015 Elsevier Ltd. All rights reserved.

TEM specimen preparation of semiconductor-PMMA-metal interfaces

International Nuclear Information System (INIS)

Thangadurai, P.; Lumelsky, Yulia; Silverstein, Michael S.; Kaplan, Wayne D.

2008-01-01

Transmission electron microscopy (TEM) cross-section specimens of PMMA in contact with gold and Si were prepared by focused ion beam (FIB) and compared with plan-view PMMA specimens prepared by a dip-coating technique. The specimens were characterized by TEM and electron energy loss spectroscopy (EELS). In the cross-section specimens, the thin films of PMMA were located in a Si-PMMA-Au multilayer. Different thicknesses of PMMA films were spin-coated on the Si substrates. The thickness of the TEM specimens prepared by FIB was estimated using EELS to be 0.65 of the plasmon mean-free-path. Along the PMMA-Au interface, Au particle diffusion into the PMMA was observed, and the size of the Au particles was in the range of 2-4 nm. Dip-coating of PMMA directly on Cu TEM grids resulted in thin specimens with a granular morphology, with a thickness of 0.58 of the plasmon mean-free-path. The dip-coated specimens were free from ion milling induced artifacts, and thus serve as control specimens for comparison with the cross-sectioned specimens prepared by FIB

Delayed formation of chromosome aberrations in mouse pachytebne spermatocytes treated with triethylenemelamine (TEM)

International Nuclear Information System (INIS)

Generoso, W.M.; Krishna, M.; Sotomayor, R.E.; Cacheiro, N.L.A.

1977-01-01

Induction of chromosome aberrations in pachytene spermatocytes of mice by 2 mg/kg TEM was compared with induction by 400 R x rays. These doses induced comparably high dominant lethal effects in pachytene spermatocytes of mice. Cytological analysis at diakinesis-metaphase I stage showed that whereas 76.4% of the cells treated with x rays at pachytene stage had aberrations, the frequencies observed in two TEM experiments were only 0.8 and 2.2%. On the other hand, 5% of the progeny from TEM-treated pachytene spermatocytes were found to be translocation heterozygotes. This is the first report on the recovery of heritable translocations from treated spermatocytes of mice. The aberration frequencies observed for TEM in diakinesis-metaphase I were much too low to account for all the lethal mutations and heritable translocations. Thus, the formation of the bulk of aberrations induced by TEM in pachytene spermatocytes was delayed--a marked contrast to the more immediate formation of x-ray-induced aberrations. It is postulated that the formation of the bulk of TEM-induced aberrations in pachytene spermatocytes and in certain postmeiotic stages occurs sometime during spermiogenesis, and not through the operation of postfertilization pronuclear DNA synthesis

Speciation of uranium in minerals by Sem, Tem, μ-PIXE, XPS and XAFS

International Nuclear Information System (INIS)

Toshihiko Ohnuki; Hiroshi Isobe; Tomihiro Kamiya; Takuro Sakai; Takashi Murakami

2001-01-01

Many kinds of electromagnetic waves and particle beams are used as analytical probes for the investigation of uranium-mineralogy and speciation. The representatives of the probes are SEM, TEM, μ-PIRE, XPS and XAFS. Each of these analytical probes has its own advantages and disadvantages. We have performed studies to compare the advantages and disadvantages on the basis of the analysis of the distribution and speciation of U containing rock samples collected at the Koongarra uranium deposit, Australia. The spatial resolutions of the probes are in the order of TEM>SEM, μ-PIXE>XFAS, XPS. The lower detection limits of the probes are in the order of μ-PIXE< TEM, SEM< XFAS, XPS. Oxidation state of U was determined by XFAS and XPS. These results indicate that combination of the above probes can give us sufficient data on U speciation not only in natural rock samples but in solid samples obtained in the laboratory. (authors)

SOFC anode reduction studied by in situ TEM

DEFF Research Database (Denmark)

Simonsen, Søren Bredmose; Wagner, Jakob Birkedal; Hansen, Thomas Willum

The Solid Oxide Fuel Cell (SOFC) is a promising part of future energy approaches due to a relatively high energy conversion efficiency and low environmental pollution. SOFCs are typically composed of ceramic materials which are highly complex at the nanoscale. TEM is routinely applied ex situ...... for studying these nanoscale structures, but only few SOFC studies have applied in situ TEM to observe the ceramic nanostructures in a reactive gas environment at elevated temperatures. The present contribution focuses on the reduction of an SOFC anode which is a necessary process to form the catalytically...... active Ni surface before operating the fuel cells. The reduction process was followed in the TEM while exposing a NiO/YSZ (YSZ = Y2O3-stabilized ZrO2) model anode to H2 at T = 250-1000⁰C. Pure NiO was used in reference experiments. Previous studies have shown that the reduction of pure Ni...

Quantitative evaluation of temporal partial coherence using 3D Fourier transforms of through-focus TEM images

International Nuclear Information System (INIS)

Kimoto, Koji; Sawada, Hidetaka; Sasaki, Takeo; Sato, Yuta; Nagai, Takuro; Ohwada, Megumi; Suenaga, Kazu; Ishizuka, Kazuo

2013-01-01

We evaluate the temporal partial coherence of transmission electron microscopy (TEM) using the three-dimensional (3D) Fourier transform (FT) of through-focus images. Young's fringe method often indicates the unexpected high-frequency information due to non-linear imaging terms. We have already used the 3D FT of axial (non-tilted) through-focus images to reduce the effect of non-linear terms on the linear imaging term, and demonstrated the improvement of monochromated lower-voltage TEM performance [Kimoto et al., Ultramicroscopy 121 (2012) 31–39]. Here we apply the 3D FT method with intentionally tilted incidence to normalize various factors associated with a TEM specimen and an imaging device. The temporal partial coherence of two microscopes operated at 30, 60 and 80 kV is evaluated. Our method is applicable to such cases where the non-linear terms become more significant in lower acceleration voltage or aberration-corrected high spatial resolution TEM. - Highlights: • We assess the temporal partial coherence of TEM using a 3-dimensional (3D) Fourier transform (FT) of through-focus images. • We apply the 3D FT method with intentionally tilted incidence to normalize various factors associated with a TEM specimen and an imaging device. • The spatial frequency at which information transfer decreases to 1/e 2 (13.5%) is determined for two lower-voltage TEM systems

XRD and TEM analysis of microstructure in the welding zone of 9Cr ...

Indian Academy of Sciences (India)

Unknown

XRD and TEM analysis of microstructure in the welding zone of. 9Cr–1Mo–V–Nb ... steel, which has highest Cr content in the heat-resisting. Cr–Mo ... This research provides essential ... film samples were observed under TEM and select elec-.

High-resolution electron microscopy

CERN Document Server

Spence, John C H

2013-01-01

This new fourth edition of the standard text on atomic-resolution transmission electron microscopy (TEM) retains previous material on the fundamentals of electron optics and aberration correction, linear imaging theory (including wave aberrations to fifth order) with partial coherence, and multiple-scattering theory. Also preserved are updated earlier sections on practical methods, with detailed step-by-step accounts of the procedures needed to obtain the highest quality images of atoms and molecules using a modern TEM or STEM electron microscope. Applications sections have been updated - these include the semiconductor industry, superconductor research, solid state chemistry and nanoscience, and metallurgy, mineralogy, condensed matter physics, materials science and material on cryo-electron microscopy for structural biology. New or expanded sections have been added on electron holography, aberration correction, field-emission guns, imaging filters, super-resolution methods, Ptychography, Ronchigrams, tomogr...

OSCE vs. TEM: Different approaches to assess clinical skills of nursing students

Directory of Open Access Journals (Sweden)

Prasuna Jelly

2017-01-01

Full Text Available Introduction: Nurses are trained with specific clinical skills, and objective structured clinical examination (OSCE could be a better approach to assess clinical skills of nursing students. Materials and Methods: A comparative study was conducted by observational checklist regarding antenatal care and opinionnaire on the usefulness of OSCE and tradition evaluation method (TEM was used to assess the clinical skills and to get opinion. Results: The mean score of OSCE was more than TEM and the difference was statistically significant (P < 0.001. The opinion of students regarding the usefulness of OSCE was higher than TEM. Conclusions: The study concluded that implementing OSCE will overweigh the advantages of the TEM.

Minimum depth of investigation for grounded-wire TEM due to self-transients

Science.gov (United States)

Zhou, Nannan; Xue, Guoqiang

2018-05-01

The grounded-wire transient electromagnetic method (TEM) has been widely used for near-surface metalliferous prospecting, oil and gas exploration, and hydrogeological surveying in the subsurface. However, it is commonly observed that such TEM signal is contaminated by the self-transient process occurred at the early stage of data acquisition. Correspondingly, there exists a minimum depth of investigation, above which the observed signal is not applicable for reliable data processing and interpretation. Therefore, for achieving a more comprehensive understanding of the TEM method, it is necessary to perform research on the self-transient process and moreover develop an approach for quantifying the minimum detection depth. In this paper, we first analyze the temporal procedure of the equivalent circuit of the TEM method and present a theoretical equation for estimating the self-induction voltage based on the inductor of the transmitting wire. Then, numerical modeling is applied for building the relationship between the minimum depth of investigation and various properties, including resistivity of the earth, offset, and source length. It is guide for the design of survey parameters when the grounded-wire TEM is applied to the shallow detection. Finally, it is verified through applications to a coal field in China.

Copper implantation defects in MgO observed by positron beam analysis, RBS and X-TEM

International Nuclear Information System (INIS)

Huis, M.A. van; Fedorov, A.V.; Veen, A. van; Smulders, P.J.M.; Kooi, B.J.; Hosson, J.Th.M. de

2000-01-01

In this work, effects of copper ion implantation in MgO were studied. (1 0 0) MgO samples were implanted with 50 keV Cu ions and thermally annealed stepwise in air for 30 minutes at 550, 750, 1000, 1250 and 1350 K. After ion implantation and after each annealing step, the samples were analysed with positron beam analysis (PBA). Use was also made of Rutherford backscattering spectrometry/channeling (RBS-C) and cross-sectional transmission electron microscopy (X-TEM). The combination of these techniques enabled to monitor the depth resolved evolution of both created defects and the copper atom depth distribution. PBA results show that copper implantation at a dose of 10 15 ions cm -2 yields a single layer of vacancy type defects after annealing. However a copper implantation at a dose of 10 16 ions cm -2 clearly yields two layers of defects in the material after annealing, separated by an intermediate layer. In both layers nanocavities have been identified. RBS experimental results show that the implanted copper atoms diffuse into the bulk material during annealing. X-TEM and channeling results show that after annealing, the lattice of the copper nanoprecipitates is epitaxial to the MgO host lattice. Under some circumstances, copper precipitates and small voids can co-exist. Furthermore, X-TEM measurements show that the nanocavities have rectangular shapes

Quantitative TEM study of the precipitation microstructure in aluminium alloy Al(MgSiCu) 6056 T6

International Nuclear Information System (INIS)

Delmas, F.; Casanove, M.J.; Lours, P.; Couret, A.; Coujou, A.

2004-01-01

The precipitate microstructure in the last-generation aluminium alloy 6056 T6 [AlMgSiCu] is investigated using three complementary techniques of transmission electron microscopy (TEM) with a special focus on the density and volume fraction of strengthening particles. High-resolution TEM allows the identification of the precipitates and the measurement of the precipitate sizes to be performed. Conventional TEM is used to evaluate the number of precipitates in the investigated area as well as their distribution in the matrix. In situ TEM straining, via the analysis of the dislocation slip traces, permits to determine precisely the thickness and the volume of the foil in the region where the precipitates are analysed. Taking into account the shape and the dimensions of precipitates with respect to the foil thickness, a novel methodology for measuring the volume density and the volume fraction of precipitates is proposed

Preparation of TEM specimen by cross-section technique

International Nuclear Information System (INIS)

Hamada, Shozo

1986-01-01

Transmission electron microscopy (TEM) is applied to the direct observation of the depth dependent damage structure in ion-irradiated stainless steel by using the cross-section technique; obtaining the TEM specimen from a slice of the irradiated stainless steel with thick Ni plating. Here has been developed the specimen preparation method of cross-section technique without heat treatment, which was necessary in the conventional method to strengthen the bonding between Ni and stainless steel. Nickel plating with good bonding to stainless steel is enabled by the following manner. First, the irradiated stainless steel is immersed in the Wood's nickel solution at room temperature for 60s to activate the surface, followed by the stricking for 300s at a current density of 300 A/m 2 in the solution to make fine and homogeneous nucleation of Ni on the stainless steel. Then, the sample is plated with Ni in the Watt's nickel plating solution at 333 K with current density of 900 ∼ 1,000 A/m 2 . The TEM disc is obtained by mechanical slicing from the specimen with Ni plating of more than 3 mm thickness. Electropolishing is accomplished by using both Ballmann method and jet electropolishing to perforate the disc accurately at the aimed point for the observation of the damage structure. (author)

Global gyrokinetic simulations of TEM microturbulence

Science.gov (United States)

Vernay, T.; Brunner, S.; Villard, L.; McMillan, B. F.; Jolliet, S.; Bottino, A.; Görler, T.; Jenko, F.

2013-07-01

Global gyrokinetic simulations of electrostatic temperature-gradient-driven trapped-electron-mode (TEM) turbulence using the δf particle-in-cell code ORB5 are presented. The electron response is either fully kinetic or hybrid, i.e. considering kinetic trapped and adiabatic passing electrons. A linear benchmark in the TEM regime against the Eulerian-based code GENE is presented. Two different methods for controlling the numerical noise, based, respectively, on a Krook operator and a so-called coarse-graining approach, are discussed and successfully compared. Both linear and non-linear studies are carried out for addressing the issue of finite-ρ*-effects and finite electron collisionality on TEM turbulence. Electron collisions are found to damp TEMs through the detrapping process, while finite-ρ*-effects turn out to be important in the non-linear regime but very small in the linear regime. Finally, the effects of zonal flows on TEM turbulence are briefly considered as well and shown to be unimportant in the temperature-gradient-driven TEM regime. Consistently, basically no difference is found between linear and non-linear critical electron temperature gradients in the TEM regime.

eV-TEM: Transmission electron microscopy in a low energy cathode lens instrument

Energy Technology Data Exchange (ETDEWEB)

Geelen, Daniël, E-mail: geelen@physics.leidenuniv.nl [Huygens-Kamerlingh Onnes Laboratory, Leiden Institute of Physics, Leiden University, P.O. Box 9504, 2300 RA Leiden (Netherlands); Thete, Aniket [Huygens-Kamerlingh Onnes Laboratory, Leiden Institute of Physics, Leiden University, P.O. Box 9504, 2300 RA Leiden (Netherlands); Schaff, Oliver; Kaiser, Alexander [SPECS GmbH, Voltastrasse 5, D-13355 Berlin (Germany); Molen, Sense Jan van der [Huygens-Kamerlingh Onnes Laboratory, Leiden Institute of Physics, Leiden University, P.O. Box 9504, 2300 RA Leiden (Netherlands); Tromp, Rudolf [IBM T.J. Watson Research Center, 1101 Kitchawan Road, P.O. Box 218, Yorktown Heights, NY 10598 (United States)

2015-12-15

We are developing a transmission electron microscope that operates at extremely low electron energies, 0–40 eV. We call this technique eV-TEM. Its feasibility is based on the fact that at very low electron energies the number of energy loss pathways decreases. Hence, the electron inelastic mean free path increases dramatically. eV-TEM will enable us to study elastic and inelastic interactions of electrons with thin samples. With the recent development of aberration correction in cathode lens instruments, a spatial resolution of a few nm appears within range, even for these very low electron energies. Such resolution will be highly relevant to study biological samples such as proteins and cell membranes. The low electron energies minimize adverse effects due to radiation damage. - Highlights: • We present a new way of performing low energy transmission electron microscopy in an aberration corrected LEEM/PEEM instrument. • We show a proof of principle where we measure transmitted electrons through a suspended graphene monolayer with a preliminary setup. • We present an improved setup design that provides better control of the incident electron beam.

In situ TEM-tandem/implanter interface facility in Wuhan University for investigation of radiation effects

International Nuclear Information System (INIS)

Guo Liping; Li Ming; Liu Chuansheng; Song Bo; Ye Mingsheng; Fan Xiangjun; Fu Dejun

2007-01-01

Transmission electron microscope (TEM) interfaced to one or more ion implanters and/or accelerators, i.e. in situ TEM, provides effective tools to observe microstructural changes of studied samples during the ion irradiation. Evolution of both radiation damages and irradiation-induced nano-sized microstructures can be investigated with this technique, much more convenient than conventional ex situ techniques. In situ TEM technique has been widely applied in various fields, especially in the study of radiation damages of structural materials of fission and fusion nuclear reactors, and in evaluation and qualification of radioactive waste forms. Nowadays there are more than a dozen such facilities located in Japan, France, and the United States. Recently, we have constructed the first TEM-Tandem/Implanter interface facility of China in Wuhan University. A modified Hitachi H800 TEM was interfaced to a 200 kV ion implanter and a 2 x 1.7 MV tandem accelerator. Effective steps were taken to isolate the TEM from mechanical vibration from the ion beam line, and no obvious wobbling of the TEM image was observed during the ion implantation. The amorphization process of Si crystal irradiated by 115 keV N + ion beam was observed in the primary experiments, demonstrating that this interface facility is capable of in situ study of radiation effects. An online low energy gaseous ion source which may provide 1-20 keV H + and He + is under construction. (authors)

In situ TEM experiments of electrochemical lithiation and delithiation of individual nanostructures

Energy Technology Data Exchange (ETDEWEB)

Liu, Xiao Hua; Liu, Yang; Huang, Jian Yu [Center for Integrated Nanotechnologies (CINT), Sandia National Laboratories, Albuquerque, New Mexico (United States); Kushima, Akihiro; Li, Ju [Department of Nuclear Science and Engineering and Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts (United States); Zhang, Sulin [Department of Engineering Science and Mechanics, Pennsylvania State University, University Park, Pennsylvania (United States); Zhu, Ting [Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia (United States)

2012-07-15

Understanding the microscopic mechanisms of electrochemical reaction and material degradation is crucial for the rational design of high-performance lithium ion batteries (LIBs). A novel nanobattery assembly and testing platform inside a transmission electron microscope (TEM) has been designed, which allows a direct study of the structural evolution of individual nanowire or nanoparticle electrodes with near-atomic resolution in real time. In this review, recent progresses in the study of several important anode materials are summarized. The consistency between in situ and ex situ results is shown, thereby validating the new in situ testing paradigm. Comparisons between a variety of nanostructures lead to the conclusion that electrochemical reaction and mechanical degradation are material specific, size dependent, and geometrically and compositionally sensitive. For example, a highly anisotropic lithiation in Si is observed, in contrast to the nearly isotropic response in Ge. The Ge nanowires can develop a spongy network, a unique mechanism for mitigating the large volume changes during cycling. The Si nanoparticles show a critical size of {proportional_to}150 nm below which fracture is averted during lithiation, and above which surface cracking, rather than central cracking, is observed. In carbonaceous nanomaterials, the lithiated multi-walled carbon nanotubes (MWCNTs) are drastically embrittled, while few-layer graphene nanoribbons remain mechanically robust after lithiation. This distinct contrast manifests a strong 'geometrical embrittlement' effect as compared to a relatively weak 'chemical embrittlement' effect. In oxide nanowires, discrete cracks in ZnO nanowires are generated near the lithiation reaction front, leading to leapfrog cracking, while a mobile dislocation cloud at the reaction front is observed in SnO{sub 2} nanowires. This contrast is corroborated by ab initio calculations that indicate a strong chemical embrittlement of Zn

TEM studies of nanostructure in melt-spun Mg-Ni-La alloy manifesting enhanced hydrogen desorbing kinetics

International Nuclear Information System (INIS)

Tanaka, K.; Miwa, T.; Sasaki, K.; Kuroda, K.

2009-01-01

The hydrogen storage properties of a magnesium-rich Mg-Ni-La alloy prepared by melt-spinning are significantly improved by nanostructure formation during crystallization and activation. It can absorb and desorb ∼5 wt% hydrogen at temperatures as low as 200 deg. C in moderate time periods. Transmission electron microscopic (TEM) studies on this alloy indicate that the nanostructure, consisting of LaH 3 and Mg 2 NiH 4 nano-particles dispersed homogeneously in MgH 2 matrices after hydrogenation, is rather stable at temperatures below 300 deg. C but undergoes coarsening and segregation of these particles and matrices above ∼400 deg. C. These structural changes have been confirmed by electron energy-loss spectroscopic (EELS) imaging as well as high-resolution TEM techniques. A new EELS peak associated with a plasmon excitation in the MgH 2 phase (H-plasmon) is found for the first time in this study. By imaging the H-plasmon peak, the hydrogen distribution in the alloy has been clearly visualized. We have succeeded in observing the hydrogen desorption process at ∼400 deg. C in-situ in the microscope using this EELS imaging technique.

Imaging Lithium Atoms at Sub-Angstrom Resolution

Energy Technology Data Exchange (ETDEWEB)

O' Keefe, Michael A.; Shao-Horn, Yang

2005-01-03

John Cowley and his group at ASU were pioneers in the use of transmission electron microscopy (TEM) for high-resolution imaging. Three decades ago they achieved images showing the crystal unit cell content at better than 4A resolution. Over the years, this achievement has inspired improvements in resolution that have enabled researchers to pinpoint the positions of heavy atom columns within the cell. More recently, this ability has been extended to light atoms as resolution has improved. Sub-Angstrom resolution has enabled researchers to image the columns of light atoms (carbon, oxygen and nitrogen) that are present in many complex structures. By using sub-Angstrom focal-series reconstruction of the specimen exit surface wave to image columns of cobalt, oxygen, and lithium atoms in a transition metal oxide structure commonly used as positive electrodes in lithium rechargeable batteries, we show that the range of detectable light atoms extends to lithium. HRTEM at sub-Angstrom resolution will provide the essential role of experimental verification for the emergent nanotech revolution. Our results foreshadow those to be expected from next-generation TEMs with CS-corrected lenses and monochromated electron beams.

TEM turbulence optimisation in stellarators

Science.gov (United States)

Proll, J. H. E.; Mynick, H. E.; Xanthopoulos, P.; Lazerson, S. A.; Faber, B. J.

2016-01-01

With the advent of neoclassically optimised stellarators, optimising stellarators for turbulent transport is an important next step. The reduction of ion-temperature-gradient-driven turbulence has been achieved via shaping of the magnetic field, and the reduction of trapped-electron mode (TEM) turbulence is addressed in the present paper. Recent analytical and numerical findings suggest TEMs are stabilised when a large fraction of trapped particles experiences favourable bounce-averaged curvature. This is the case for example in Wendelstein 7-X (Beidler et al 1990 Fusion Technol. 17 148) and other Helias-type stellarators. Using this knowledge, a proxy function was designed to estimate the TEM dynamics, allowing optimal configurations for TEM stability to be determined with the STELLOPT (Spong et al 2001 Nucl. Fusion 41 711) code without extensive turbulence simulations. A first proof-of-principle optimised equilibrium stemming from the TEM-dominated stellarator experiment HSX (Anderson et al 1995 Fusion Technol. 27 273) is presented for which a reduction of the linear growth rates is achieved over a broad range of the operational parameter space. As an important consequence of this property, the turbulent heat flux levels are reduced compared with the initial configuration.

Environmental TEM in an Aberration Corrected Microscope

DEFF Research Database (Denmark)

Hansen, Thomas Willum; Wagner, Jakob Birkedal

‐resolution imaging. A gaseous atmosphere in the pole‐piece gap of the objective lens of the microscope alters both the incoming electron wave prior to interaction with the sample and the outgoing wave below the sample. Whereas conventional TEM samples are usually thin (below 10‐20 nm), the gas in the environmental...... the microscope column. The effects of gas on the electron wave in the objective lens are not well understood and needs further attention. Imaging samples with a simple geometry, such as gold particles on a flat graphene substrate and analyzing the variations in contrast, provides a means for understanding...... results from imaging in various elemental as well as di‐molecular gases and their effect on imaging and spectroscopy in the environmental transmission electron microscope....

In situ targeting TEM8 via immune response and polypeptide recognition by wavelength-modulated surface plasmon resonance biosensor

Science.gov (United States)

Wang, Yimin; Luo, Zewei; Liu, Kunping; Wang, Jie; Duan, Yixiang

2016-01-01

There is an increasing interest in real-time and in situ monitoring of living cell activities in life science and medicine. This paper reports a whole cell sensing protocol over the interface of Au film coupled in a wavelength-modulated surface plasmon resonance (WMSPR) biosensor. With dual parabolic mirrors integrated in the sensor, the compact and miniaturized instrument shows satisfactory refractive index sensitivity (2220 nm/RIU) and a high resolution of resonance wavelength shift of 0.3 nm to liquid samples. The affinity interactions between the biomarker of human tumor endothelial marker 8 (TEM8) and antibody (Ab) or specific polypeptide (PEP) were firstly introduced to WMSPR biosensor analysis. Both the interaction events of Ab-cell and PEP-cell over the Au film interface can be recognized by the sensor and the balance time of interactions is about 20 min. The concentration range of Ab for quantitative monitoring of the TEM8 expression on human colon carcinoma SW620 cells was investigated. The present low-cost and time-saving method provides a time resolution of binding specificity between Ab/PEP and TEM8 for real-time analysis of antigen on living tumor cell surface. PMID:26822761

Electron energy-loss spectrometry at the frontier of spatial and energy resolution

International Nuclear Information System (INIS)

Hofer, F.; Grogger, W.; Kothleitner, G.

2004-01-01

Full text: Electron energy-loss spectroscopy (EELS) in the transmission electron microscope (TEM) is now used routinely as a means of measuring chemical and structural properties of very small regions of a thin specimen. The power of this technique depends significantly on two parameters: its spatial resolution and the energy resolution available in the spectrum and in the energy-filtered TEM (EFTEM) image. The cold field emission source and the Schottky emitter have made an energy resolution below 1 eV possible and it is now feasible to obtain data with a spatial resolution close to atomic dimensions, given the right instrumentation and specimen. EFTEM allows to record elemental maps at sub-nanometre resolution, being mainly limited by chromatic and spherical aberration of the objective lens and by delocalization of inelastic scattering. Recently the possibility of correcting spherical and even chromatic aberrations of electron lenses has become a practical reality thus improving the point resolution of the TEM to below 0.1 nm. The other limiting factor for EFTEM resolution is delocalization. However, recent measurements show that resolution values in the range of 1 nm and below can be achieved, even for energy-losses of only a few eV. In terms of energy-resolution, EELS and EFTEM compare less favourably with other spectroscopies. For common TEMs, the overall energy-resolution is mainly determined by the energy width of the electron source, typically between 0.5 and 1.5 eV. For comparison, synchrotron x-ray sources and beam line spectrometers, provide a resolution well below 0.1 eV for absorption spectroscopy. During the early sixties, the energy spread of an electron beam could be reduced by incorporating an energy-filter into the illumination system, but the system lacked spatial resolution. Later developments combined high energy resolution in the range of 0.1 eV with improved spatial resolution. Recently, FEI introduced a new high resolution EELS system based

Recent advances in FIB-TEM specimen preparation techniques

International Nuclear Information System (INIS)

Li Jian; Malis, T.; Dionne, S.

2006-01-01

Preparing high-quality transmission electron microscopy (TEM) specimens is of paramount importance in TEM studies. The development of the focused ion beam (FIB) microscope has greatly enhanced TEM specimen preparation capabilities. In recent years, various FIB-TEM foil preparation techniques have been developed. However, the currently available techniques fail to produce TEM specimens from fragile and ultra-fine specimens such as fine fibers. In this paper, the conventional FIB-TEM specimen preparation techniques are reviewed, and their advantages and shortcomings are compared. In addition, a new technique suitable to prepare TEM samples from ultra-fine specimens is demonstrated

Practical considerations for high spatial and temporal resolution dynamic transmission electron microscopy

Energy Technology Data Exchange (ETDEWEB)

Armstrong, Michael R. [Materials Science and Technology Division, Chemistry and Materials Science Directorate, Lawrence Livermore National Laboratory, P.O. Box 808, L-356, Livermore, CA 94550 (United States)], E-mail: armstrong30@llnl.gov; Boyden, Ken [Materials Science and Technology Division, Chemistry and Materials Science Directorate, Lawrence Livermore National Laboratory, P.O. Box 808, L-356, Livermore, CA 94550 (United States); Browning, Nigel D. [Materials Science and Technology Division, Chemistry and Materials Science Directorate, Lawrence Livermore National Laboratory, P.O. Box 808, L-356, Livermore, CA 94550 (United States); Department of Chemical Engineering and Materials Science, University of California-Davis, One Shields Avenue, Davis, CA 95616 (United States); Campbell, Geoffrey H.; Colvin, Jeffrey D.; De Hope, William J.; Frank, Alan M. [Materials Science and Technology Division, Chemistry and Materials Science Directorate, Lawrence Livermore National Laboratory, P.O. Box 808, L-356, Livermore, CA 94550 (United States); Gibson, David J.; Hartemann, Fred [N Division, Physics and Advanced Technologies Directorate, Lawrence Livermore National Laboratory, P.O. Box 808, L-280, Livermore, CA 94550 (United States); Kim, Judy S. [Materials Science and Technology Division, Chemistry and Materials Science Directorate, Lawrence Livermore National Laboratory, P.O. Box 808, L-356, Livermore, CA 94550 (United States); Department of Chemical Engineering and Materials Science, University of California-Davis, One Shields Avenue, Davis, CA 95616 (United States); King, Wayne E.; La Grange, Thomas B.; Pyke, Ben J.; Reed, Bryan W.; Shuttlesworth, Richard M.; Stuart, Brent C.; Torralva, Ben R. [Materials Science and Technology Division, Chemistry and Materials Science Directorate, Lawrence Livermore National Laboratory, P.O. Box 808, L-356, Livermore, CA 94550 (United States)

2007-04-15

Although recent years have seen significant advances in the spatial resolution possible in the transmission electron microscope (TEM), the temporal resolution of most microscopes is limited to video rate at best. This lack of temporal resolution means that our understanding of dynamic processes in materials is extremely limited. High temporal resolution in the TEM can be achieved, however, by replacing the normal thermionic or field emission source with a photoemission source. In this case the temporal resolution is limited only by the ability to create a short pulse of photoexcited electrons in the source, and this can be as short as a few femtoseconds. The operation of the photo-emission source and the control of the subsequent pulse of electrons (containing as many as 5x10{sup 7} electrons) create significant challenges for a standard microscope column that is designed to operate with a single electron in the column at any one time. In this paper, the generation and control of electron pulses in the TEM to obtain a temporal resolution <10{sup -6} s will be described and the effect of the pulse duration and current density on the spatial resolution of the instrument will be examined. The potential of these levels of temporal and spatial resolution for the study of dynamic materials processes will also be discussed.

Practical considerations for high spatial and temporal resolution dynamic transmission electron microscopy

International Nuclear Information System (INIS)

Armstrong, Michael R.; Boyden, Ken; Browning, Nigel D.; Campbell, Geoffrey H.; Colvin, Jeffrey D.; De Hope, William J.; Frank, Alan M.; Gibson, David J.; Hartemann, Fred; Kim, Judy S.; King, Wayne E.; La Grange, Thomas B.; Pyke, Ben J.; Reed, Bryan W.; Shuttlesworth, Richard M.; Stuart, Brent C.; Torralva, Ben R.

2007-01-01

Although recent years have seen significant advances in the spatial resolution possible in the transmission electron microscope (TEM), the temporal resolution of most microscopes is limited to video rate at best. This lack of temporal resolution means that our understanding of dynamic processes in materials is extremely limited. High temporal resolution in the TEM can be achieved, however, by replacing the normal thermionic or field emission source with a photoemission source. In this case the temporal resolution is limited only by the ability to create a short pulse of photoexcited electrons in the source, and this can be as short as a few femtoseconds. The operation of the photo-emission source and the control of the subsequent pulse of electrons (containing as many as 5x10 7 electrons) create significant challenges for a standard microscope column that is designed to operate with a single electron in the column at any one time. In this paper, the generation and control of electron pulses in the TEM to obtain a temporal resolution -6 s will be described and the effect of the pulse duration and current density on the spatial resolution of the instrument will be examined. The potential of these levels of temporal and spatial resolution for the study of dynamic materials processes will also be discussed

High resolution ultrastructure imaging of fractures in human dental tissues

Directory of Open Access Journals (Sweden)

Tan Sui

2014-01-01

Full Text Available Human dental hard tissues are dentine, cementum, and enamel. These are hydrated mineralised composite tissues with a hierarchical structure and versatile thermo-mechanical properties. The hierarchical structure of dentine and enamel was imaged by transmission electron microscopy (TEM of samples prepared by focused ion beam (FIB milling. High resolution TEM was carried out in the vicinity of a crack tip in dentine. An intricate “random weave” pattern of hydroxyapatile crystallites was observed and this provided a possible explanation for toughening of the mineralized dentine tissue at the nano-scale. The results reported here provide the basis for improved understanding of the relationship between the multi-scale nature and the mechanical properties of hierarchically structured biomaterials, and will also be useful for the development of better prosthetic and dental restorative materials.

TEMS: results of a specialist centre.

Science.gov (United States)

Flexer, S M; Durham-Hall, A C; Steward, M A; Robinson, J M

2014-06-01

Transanal endoscopic microsurgery (TEMS) is becoming more widespread due to the increasing body of evidence to support its role. Previous published data has reported recurrence rates in excess of 10% for benign polyps after TEMS. Bradford Royal Infirmary is a tertiary referral centre for TEMS and early rectal cancer in the UK. Data for all TEMS operations were entered into a prospective database over a 7-year period. Demographic data, complications and recurrence rates were recorded. Both benign adenomas and malignant lesions were included. A total of 164 patients (65% male), with a mean age of 68 years were included; 114 (70%) of the lesions resected were benign adenomas, and 50 (30%) were malignant lesions. Median polyp size was 4 (range 0.6-14.5) cm. Mean length of operation was 55 (range 10-120) min. There were no recurrences in any patients with a benign adenoma resected; two patients with malignant lesions developed recurrences. Three intra-operative complications were recorded, two rectal perforations (repaired primarily, one requiring defunctioning stoma), and a further patient suffered a blood loss of >300 ml requiring transfusion. Six patients developed strictures requiring dilation either endoscopically or under anaesthetic in the post-operative period. We have demonstrated that TEMS procedures performed in a specialist centre provide low rates of both recurrence and complication. Within a specialist centre, TEMS surgery should be offered to all patients for rectal lesions, both benign and malignant, that are amenable to TEMS.

Tie2-expressing monocytes (TEMs): novel targets and vehicles of anticancer therapy?

Science.gov (United States)

De Palma, Michele; Naldini, Luigi

2009-08-01

There is a growing interest in understanding the complex interactions between bone marrow-derived myeloid-lineage cells and angiogenesis in tumors. Such interest has been revived recently by the observation that tumor-infiltrating myeloid cells convey proangiogenic programs that can counteract the activity of antiangiogenic drugs in mouse tumor models. Among myeloid cells, Tie2-expressing monocytes (TEMs) appear to have nonredundant function in promoting tumor angiogenesis and growth in mouse models. The identification and functional characterization of TEMs in mice and humans may provide novel molecular targets for anticancer therapy. Moreover, TEMs may be exploited to deliver antitumor drugs specifically to the tumor microenvironment.

Using Process Observation to Teach Alternative Dispute Resolution: Alternatives to Simulation.

Science.gov (United States)

Bush, Robert A. Barush

1987-01-01

A method of teaching alternative dispute resolution (ADR) involves sending students to observe actual ADR sessions, by agreement with the agencies conducting them, and then analyzing the students' observations in focused discussions to improve student insight and understanding of the processes involved. (MSE)

Super resolution for astronomical observations

Science.gov (United States)

Li, Zhan; Peng, Qingyu; Bhanu, Bir; Zhang, Qingfeng; He, Haifeng

2018-05-01

In order to obtain detailed information from multiple telescope observations a general blind super-resolution (SR) reconstruction approach for astronomical images is proposed in this paper. A pixel-reliability-based SR reconstruction algorithm is described and implemented, where the developed process incorporates flat field correction, automatic star searching and centering, iterative star matching, and sub-pixel image registration. Images captured by the 1-m telescope at Yunnan Observatory are used to test the proposed technique. The results of these experiments indicate that, following SR reconstruction, faint stars are more distinct, bright stars have sharper profiles, and the backgrounds have higher details; thus these results benefit from the high-precision star centering and image registration provided by the developed method. Application of the proposed approach not only provides more opportunities for new discoveries from astronomical image sequences, but will also contribute to enhancing the capabilities of most spatial or ground-based telescopes.

Joint TEM and MT aquifer study in the Atacama Desert, North Chile

Science.gov (United States)

Ruthsatz, Alexander D.; Sarmiento Flores, Alvaro; Diaz, Daniel; Reinoso, Pablo Salazar; Herrera, Cristian; Brasse, Heinrich

2018-06-01

The Atacama Desert represents one of the driest regions on earth, and despite the absence of sustainable clean water reserves the demand has increased drastically since 1970 as a result of growing population and expanding mining activities. Magnetotelluric (MT) and Transient Electromagnetic (TEM) measurements were carried out for groundwater exploration in late 2015 in the area of the Profeta Basin at the western margin of the Chilean Precordillera. Both methods complement each other: While MT in general attains larger penetration depths, TEM allows better resolution of near surface layers; furthermore TEM is free from galvanic distortion. Data were collected along three profiles, enabling a continuous resistivity image from the surface to at least several hundred meters depth. TEM data were inverted in a 1-D manner, consistently yielding a poorly conductive near-surface layer with a thickness of approximately 30 m and below a well-conducting layer which we interpret as the aquifer with resistivities around 10 Ωm. At marginal sites of the main SW-NE-profile the resistive basement was found in 150 m. These depths are confirmed by interpretation of the MT soundings. Those were firstly inverted with a 2-D approach and then by 3-D inversion as clear indications of three-dimensionality exist. Several modeling runs were performed with different combinations of transfer functions and smoothing parameters. Generally, MT and TEM results agree reasonably well and an overall image of the resistivity structures in the Profeta Basin could be achieved. The aquifer reaches depths of more than 500 m in parts and, by applying Archie's law, resistivities of 1 Ωm can be assumed, indicating highly saline fluids from the source region of the surrounding high Andes under persisting arid conditions.

Study of InGaN/GaN quantum dot systems by TEM techniques and photoluminescence spectroscopy

International Nuclear Information System (INIS)

Kashtiban, R J; Bangert, U; Harvey, A J; Sherliker, B; Halsall, M P

2010-01-01

InGaN/GaN multilayer quantum dot structures produced by MOCVD techniques on c-plane sapphire were studied by transmission electron microscopy (TEM) and photoluminescence (PL) techniques. Indium fluctuations ranging from 1-4 nm were observed with both energy filtered TEM (EFTEM) and high angle annular dark field (HAADF) scanning TEM. The existence of V-shaped defects with nucleation centres at the termination of threading dislocation were observed in HAADF images. There was also evidence of the formation of large quantum dots at low densities from lattice HRTEM images. This was further confirmed by PL measurements through the observation of a single sharp line at low power with the typical saturation behaviour at higher power excitation.

Identification of proangiogenic TIE2-expressing monocytes (TEMs) in human peripheral blood and cancer.

Science.gov (United States)

Venneri, Mary Anna; De Palma, Michele; Ponzoni, Maurilio; Pucci, Ferdinando; Scielzo, Cristina; Zonari, Erika; Mazzieri, Roberta; Doglioni, Claudio; Naldini, Luigi

2007-06-15

Tumor-infiltrating myeloid cells, including tumor-associated macrophages (TAMs), have been implicated in tumor progression. We recently described a lineage of mouse monocytes characterized by expression of the Tie2 angiopoietin receptor and required for the vascularization and growth of several tumor models. Here, we report that TIE2 expression in human blood identifies a subset of monocytes distinct from classical inflammatory monocytes and comprised within the less abundant "resident" population. These TIE2-expressing monocytes (TEMs) accounted for 2% to 7% of blood mononuclear cells in healthy donors and were distinct from rare circulating endothelial cells and progenitors. In human cancer patients, TEMs were observed in the blood and, intriguingly, within the tumors, where they represented the main monocyte population distinct from TAMs. Conversely, TEMs were hardly detected in nonneoplastic tissues. In vitro, TEMs migrated toward angiopoietin-2, a TIE2 ligand released by activated endothelial cells and angiogenic vessels, suggesting a homing mechanism for TEMs to tumors. Purified human TEMs, but not TEM-depleted monocytes, markedly promoted angiogenesis in xenotransplanted human tumors, suggesting a potentially critical role of TEMs in human cancer progression. Human TEMs may provide a novel, biologically relevant marker of angiogenesis and represent a previously unrecognized target of cancer therapy.

Studying the interface between cyanobacteria and biotite mineral surfaces using FIB and TEM

International Nuclear Information System (INIS)

Ward, M B; Brown, A P

2014-01-01

Recent analysis of the bioweathering of minerals has highlighted the challenges for investigating the interface between fungi or bacteria and the surface of the mineral that they live on. Transmission electron microscopy (TEM) with its ability to gather imaging information and collect elemental data at high spatial resolution is the ideal technique to analyse such interfaces. Further to this, a dual beam scanning electron and focused ion beam (FIB) microscope is an ideal instrument to prepare specimens for TEM because of its ability to simultaneously cut through hard and soft materials from specific sites of interest. There are however precautions that must be taken when analysing such mineral systems. The electron beam sensitive nature of most sheet silicate minerals means that consideration has to be made as to whether the structure and/or chemistry of the material is being altered during (S)TEM analysis. Here, results from a study of cyanobacteria grown on the surface of biotite are discussed. Particular reference is given to the methods used to determine an electron beam intensity threshold, below which STEM-EDX analysis could be performed without detrimental alteration to the mineral

TEM and EELS studies of microwave-irradiation synthesis of bimetallic platinum nanocatalysts

International Nuclear Information System (INIS)

Mathe, N R; Scriba, M R; Coville, N J; Olivier, J E

2014-01-01

Microwave-irradiation (MW) synthesis of nanostructured materials provides for the synthesis of metal nanoparticles, using fast and uniform heating rates. This procedure affords better control of the shape and size of the nanoparticles when compared to conventional methods. In this work, microwave-irradiation was used to produce platinum-cobalt (Pt-Co) and platinum-nickel (Pt-Ni) nanoparticles for use as electrocatalysts in the methanol oxidation reaction. High resolution TEM imaging and EELS studies revealed that these bimetallic nanoparticles form islands or hetero-structures

Comparison of ultramicrotomy and focused-ion-beam for the preparation of TEM and STEM cross section of organic solar cells

Energy Technology Data Exchange (ETDEWEB)

Corazza, Michael, E-mail: michael.corazza@gmail.com [Department of Energy Conversion and Storage, Technical University of Denmark, Frederiksborgvej 399, 4000 Roskilde (Denmark); Simonsen, Søren B. [Department of Energy Conversion and Storage, Technical University of Denmark, Frederiksborgvej 399, 4000 Roskilde (Denmark); Gnaegi, Helmut [Diatome Ltd., Biel-Bienne (Switzerland); Thydén, Karl T.S.; Krebs, Frederik C.; Gevorgyan, Suren A. [Department of Energy Conversion and Storage, Technical University of Denmark, Frederiksborgvej 399, 4000 Roskilde (Denmark)

2016-12-15

Highlights: • Comparison of flexible solar cell sections prepared by ultramicrotomy and by FIB. • Energy filtered TEM analysis of phase separation in the P3HT:PCBM active layer. • Imaging of aging effects on solar cell cross section prepared by ultramicrotomy. • Ultramicrotomy provides great details while FIB better preserves the structure. - Abstract: The challenge of preparing cross sections of organic photovoltaics (OPV) suitable for transmission electron microscopy (TEM) and scanning TEM (STEM) is addressed. The samples were polymer solar cells fabricated using roll-to-roll (R2R) processing methods on a flexible polyethylene terephthalate (PET) substrate. Focused ion beam (FIB) and ultramicrotomy were used to prepare the cross sections. The differences between the samples prepared by ultramicrotomy and FIB are addressed, focusing on the advantages and disadvantages of each technique. The sample prepared by ultramicrotomy yielded good resolution, enabling further studies of phase separation of P3HT:PCBM by means of energy filtered TEM (EFTEM). The sample prepared by FIB shows good structure preservation, but reduced resolution due to non-optimal thicknesses achieved after treatment. Degradation studies of samples prepared by ultramicrotomy are further discussed, which reveal particular effects of the ISOS-L-3 aging test (85 °C, 50% R.H., 0.7 Sun) onto the sample, especially pronounced in the silver layer.

High-resolution TEM and the application of direct and indirect aberration correction

DEFF Research Database (Denmark)

Hetherington, Crispin J.D.; Chang, Lan-Yun Shery; Haigh, Sarah

2008-01-01

Aberration correction leads to a substantial improvement in the directly interpretable resolution of transmission electron microscopes. Correction of the aberrations has been achieved electron-optically through a hexapole-based corrector and also indirectly by computational analysis of a focal or...

Time-resolved High Spectral Resolution Observation of 2MASSW J0746425+200032AB

Energy Technology Data Exchange (ETDEWEB)

Wang, Ji; Mawet, Dimitri [Department of Astronomy, California Institute of Technology, MC 249-17, 1200 E. California Boulevard, Pasadena, CA 91106 (United States); Prato, Lisa, E-mail: ji.wang@caltech.edu [Lowell Observatory, 1400 West Mars Hill Road, Flagstaff, AZ 86001 (United States)

2017-03-20

Many brown dwarfs (BDs) exhibit photometric variability at levels from tenths to tens of percents. The photometric variability is related to magnetic activity or patchy cloud coverage, characteristic of BDs near the L–T transition. Time-resolved spectral monitoring of BDs provides diagnostics of cloud distribution and condensate properties. However, current time-resolved spectral studies of BDs are limited to low spectral resolution ( R ∼ 100) with the exception of the study of Luhman 16 AB at a resolution of 100,000 using the VLT+CRIRES. This work yielded the first map of BD surface inhomogeneity, highlighting the importance and unique contribution of high spectral resolution observations. Here, we report on the time-resolved high spectral resolution observations of a nearby BD binary, 2MASSW J0746425+200032AB. We find no coherent spectral variability that is modulated with rotation. Based on simulations, we conclude that the coverage of a single spot on 2MASSW J0746425+200032AB is smaller than 1% or 6.25% if spot contrast is 50% or 80% of its surrounding flux, respectively. Future high spectral resolution observations aided by adaptive optics systems can put tighter constraints on the spectral variability of 2MASSW J0746425+200032AB and other nearby BDs.

TEM investigation of the microstructural evolution in nickel during MeV helium implantation

International Nuclear Information System (INIS)

Gadalla, A.A.; Jaeger, W.; Ehrhart, P.

1986-01-01

In a recent TEM investigation of high energy He-implanted copper the low average helium density could be understood by the observation of the coexistence of two types of vacancy agglomerates i.e. relaxed vacancy agglomerates in the form of stacking fault tetrahedra (SFT) and small bubbles. In order to arrive at a more systematic understanding of the evolution of the microstructure during high energy helium implantation we extended these TEM investigations to nickel. Of particular interest was also the minimum implantation dose necessary to precipitate bubbles that are large enough to be visible in the TEM. (orig./RK)

High resolution transmission electron microscopy and microdiffraction for radiation damage analysis

International Nuclear Information System (INIS)

Sinclair, R.

1982-01-01

High resolution TEM techniques have developed to quite a sophisticated level over the past few years. In addition TEM instruments with a scanning capability have become available commercially which permit in particular the formation of a small electron probe at the specimen. Thus direct resolution and microdiffraction investigations of thin specimens are now possible, neither of which have been employed to any great extent in the analysis of radiation damage. Some recent advances which are thought to be relevant to this specific area of research are highlighted

Role of light satellites in the high-resolution Earth observation domain

Science.gov (United States)

Fishman, Moshe

1999-12-01

Current 'classic' applications using and exploring space based earth imagery are exclusive, narrow niche tailored, expensive and hardly accessible. On the other side new, inexpensive and widely used 'consumable' applications will be only developed concurrently to the availability of appropriate imagery allowing that process. A part of these applications can be imagined today, like WWW based 'virtual tourism' or news media, but the history of technological, cultural and entertainment evolution teaches us that most of future applications are unpredictable -- they emerge together with the platforms enabling their appearance. The only thing, which can be ultimately stated, is that the definitive condition for such applications is the availability of the proper imagery platform providing low cost, high resolution, large area, quick response, simple accessibility and quick dissemination of the raw picture. This platform is a constellation of Earth Observation satellites. Up to 1995 the Space Based High Resolution Earth Observation Domain was dominated by heavy, super-expensive and very inflexible birds. The launch of Israeli OFEQ-3 Satellite by MBT Division of Israel Aircraft Industries (IAI) marked the entrance to new era of light, smart and cheap Low Earth Orbited Imaging satellites. The Earth Resource Observation System (EROS) initiated by West Indian Space, is based on OFEQ class Satellites design and it is capable to gather visual data of Earth Surface both at high resolution and large image capacity. The main attributes, derived from its compact design, low weight and sophisticated logic and which convert the EROS Satellite to valuable and productive system, are discussed. The major advantages of Light Satellites in High Resolution Earth Observation Domain are presented and WIS guidelines featuring the next generation of LEO Imaging Systems are included.

EBSD and FIB/TEM examination of shape memory effect deformation structures in U-14 at.% Nb

Energy Technology Data Exchange (ETDEWEB)

Clarke, A.J. [Materials Science and Technology Division, Mail Stop G770, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)], E-mail: aclarke@lanl.gov; Field, R.D.; McCabe, R.J.; Cady, C.M.; Hackenberg, R.E.; Thoma, D.J. [Materials Science and Technology Division, Mail Stop G770, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

2008-06-15

Detailed examinations of shape memory effect (SME) deformation structures in martensite of U-14 at.% Nb were performed with electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM). An accommodation strain analysis, which has been previously used to predict SME deformation structures and texture evolution in polycrystalline material, was also performed. Martensite variants and twin relationships observed with EBSD after compressive or tensile deformation were determined to be consistent with those expected from calculated accommodation strains. Focused ion beam (FIB) was used to select twinned regions identified with EBSD for more detailed TEM analysis to verify the presence of these specific twins. The observed SME twinning systems in the martensite agree with previous TEM observations and the predicted {l_brace}1-bar76{r_brace} twinning system was observed experimentally for the first time in U-14 at.% Nb using these complementary techniques.

Double aberration-corrected TEM/STEM of tungstated zirconia nanocatalysts for the synthesis of paracetamol

International Nuclear Information System (INIS)

Yoshida, K; Boyes, E D; Gai, P L; Shiju, N R; Brown, D R

2010-01-01

We report highly active tungstated zirconia nanocatalysts for the synthesis of paracetamol by Beckmann rearrangement of 4-hydroxyacetophenone oxime. Double aberration-corrected (2AC)-TEM/STEM studies were performed in a JEOL 2200FS FEG TEM/STEM at the 1 Angstrom (1 A = 0.1 nanometer) level. Observations at close to zero defocus were carried out using the AC-TEM as well as AC-STEM including high angle annular dark field (HAADF) imaging, from the same areas of the catalyst crystallites. The studies from the same areas have revealed the location and the nanostructure of the polytungstate species (clusters) and the nanograins of zirconia. The AC (S)TEM was crucial to observe the nanostructure and location of polytungstate clusters on the zirconia grains. Polytungstate clusters as small as 0.5 nm have been identified using the HAADF-STEM. The nanostructures of the catalyst and the W surface density have been correlated with paracetamol reaction studies. The results demonstrate the nature of active sites and high activity of the tungstated zirconia nanocatalyst, which is an environmentally clean alternative to the current homogeneous process.

Double aberration-corrected TEM/STEM of tungstated zirconia nanocatalysts for the synthesis of paracetamol

Energy Technology Data Exchange (ETDEWEB)

Yoshida, K; Boyes, E D; Gai, P L [York JEOL Nanocentre (United Kingdom); Shiju, N R; Brown, D R, E-mail: pgb500@york.ac.u [Department of Chemical and Biological Sciences, University of Huddersfield, Huddersfield, HD1 3DH (United Kingdom)

2010-07-01

We report highly active tungstated zirconia nanocatalysts for the synthesis of paracetamol by Beckmann rearrangement of 4-hydroxyacetophenone oxime. Double aberration-corrected (2AC)-TEM/STEM studies were performed in a JEOL 2200FS FEG TEM/STEM at the 1 Angstrom (1 A = 0.1 nanometer) level. Observations at close to zero defocus were carried out using the AC-TEM as well as AC-STEM including high angle annular dark field (HAADF) imaging, from the same areas of the catalyst crystallites. The studies from the same areas have revealed the location and the nanostructure of the polytungstate species (clusters) and the nanograins of zirconia. The AC (S)TEM was crucial to observe the nanostructure and location of polytungstate clusters on the zirconia grains. Polytungstate clusters as small as 0.5 nm have been identified using the HAADF-STEM. The nanostructures of the catalyst and the W surface density have been correlated with paracetamol reaction studies. The results demonstrate the nature of active sites and high activity of the tungstated zirconia nanocatalyst, which is an environmentally clean alternative to the current homogeneous process.

In-situ TEM investigations of graphic-epitaxy and small particles

Science.gov (United States)

Heinemann, K.

1983-01-01

Palladium was deposited inside a controlled-vacuum specimen chamber of a transmission electron microscope (TEM) onto MgO and alpha-alumina substrate surfaces. Annealing and various effects of gas exposure of the particulate Pd deposits were studied in-situ by high resolution TEM and electron diffraction. Whereas substrate temperatures of 500 C or annealing of room temperature (RT) deposits to 500 C were needed to obtain epitaxy on sapphire, RT deposits on MgO were perfectly epitaxial. For Pd/MgO a lattice expansion of 2 to 4% was noted; the highest values of expansion were found for the smallest particles. The lattice expansion of small Pd particles on alumina substrates was less than 1%. Long-time RT exposure of Pd/MgO in a vacuum yielded some moblity and coalescence events, but notably fewer than for Pd on sapphire. Exposure to air or oxygen greatly enhanced the particle mobility and coalescence and also resulted in the flattening of Pd particles on MgO substrates. Electron-beam irradiation further enhanced this effect. Exposure to air for several tens of hours of Pd/MgO led to strong coalescence.

In situ TEM investigation on the precipitation behavior of μ phase in Ni-base single crystal superalloys

International Nuclear Information System (INIS)

Gao, Shuang; Liu, Zhi-Quan; Li, Cai-Fu; Zhou, Yizhou; Jin, Tao

2016-01-01

The precipitation behavior of μ phase in Ni-base single crystal superalloys was investigated by in situ transmission electron microscopy (TEM). A layer-by-layer growth process with a ledge propagation mechanism was first observed during in situ precipitation. Three types of μ phase with different morphologies were found, which grow along [001] μ with (001) μ planar defects, [-111] μ with (1–12) μ planar defects, as well as both directions with mixed planar defects. High-resolution TEM image and established atomic models reveal a basic growth mechanism of μ phase by stacking on (001) μ plane and randomly forming coherent planar defects, while the nucleation of incoherent (1–12) μ planar defects at the early stage of precipitation plays an important role in affecting the basic growth mechanism. The frequent faults during the stacking process of the sub-unit layers within μ lattice should be responsible for the defect formation. -- Graphical abstract: In situ transmission electron microscopy (TEM) investigations reveal the layer-by-layer growth mechanism of μ phase precipitated in Ni-base single crystal superalloys. Three types of μ phase with different morphologies were formed at 1050 °C, which grows along [001] μ with (001) μ planar defects, [-111] μ with (1–12) μ planar defects, as well as both directions with mixed planar defects respectively. Formation of (001) μ micro-twin and stacking fault is the essential feature for precipitated μ phase, while nucleation of incoherent (1–12) μ planar defects plays an important role in changing growth method. Display Omitted

Towards high resolution mapping of 3-D mesoscale dynamics from observations

Directory of Open Access Journals (Sweden)

B. Buongiorno Nardelli

2012-10-01

Full Text Available The MyOcean R&D project MESCLA (MEsoSCaLe dynamical Analysis through combined model, satellite and in situ data was devoted to the high resolution 3-D retrieval of tracer and velocity fields in the oceans, based on the combination of in situ and satellite observations and quasi-geostrophic dynamical models. The retrieval techniques were also tested and compared with the output of a primitive equation model, with particular attention to the accuracy of the vertical velocity field as estimated through the Q vector formulation of the omega equation. The project focused on a test case, covering the region where the Gulf Stream separates from the US East Coast. This work demonstrated that innovative methods for the high resolution mapping of 3-D mesoscale dynamics from observations can be used to build the next generations of operational observation-based products.

TEM and SEM observation of uranium induced renal necrosis and the result of chelates treatment on rats

International Nuclear Information System (INIS)

Sun Shiquan; Li Baoxing; Lai Chixiang; You Zhanyun

1987-01-01

The TEM (transmission electron microscope) and SEM (scanning electron microscope) observation of uranium induced renal necrosis and the result of chelates treatment on rats are reported. Ultrastructural changes in kidney related with the impairment of intracellular fluid transportation can be found after acute uranium intoxication in rats, such as: condensation and swelling of mitochondria, matrix edema, dilatation of intercellular space, disappearance of basal folds, thickening of basal web, intensification of basal lamina of the proximal convoluted tubule epithelium cells, and foot processes swelling, diminishing of endothelium fenestrae of the renal glomerulus. Heavy metal chelates DTPA and H-73-10 treatment may result in intracellular fluid accumulation and condensed grannule formation in lysosome. Treatment with these chelates in the critical stage of uranium intoxication may accelerate the necrosis instead of diminishing. This may be related to the augment of the load of lysosome and intracellular system of fluid transportation

Theoretical analysis and modeling of Thickness-Expansion Mode (TEM) sensors for fluid characterization.

Science.gov (United States)

Elvira, Luis; Resa, Pablo; Castro, Pedro

2013-03-01

In this paper, the principles of Thickness-Expansion Mode (TEM) resonators for the characterization of fluids are described. From the measurement of the resonance parameters of a TEM piezoelectric transducer, the compressional acoustic impedance of gases and liquids can be determined. Since the propagation of mechanical waves into the fluid is not necessary, information in a wide range of frequencies can be obtained. Alternatively, these sensors can be driven in combination with other ultrasonic techniques to simultaneously determine the density, speed of sound and viscosity of samples. Some potential applications include the probe monitoring of processes and the characterization of fluids under harsh conditions. The main experimental criteria for the design and construction of high-resolution impedance meters (such as piezoelectric material, protective coating or thermal response) have been studied using equivalent electrical circuit modeling and finite element analysis. Copyright © 2012 Elsevier B.V. All rights reserved.

HIGH SPATIAL RESOLUTION OBSERVATIONS OF LOOPS IN THE SOLAR CORONA

Energy Technology Data Exchange (ETDEWEB)

Brooks, David H.; Ugarte-Urra, Ignacio [College of Science, George Mason University, 4400 University Drive, Fairfax, VA 22030 (United States); Warren, Harry P. [Space Science Division, Naval Research Laboratory, Washington, DC 20375 (United States); Winebarger, Amy R. [NASA Marshall Space Flight Center, ZP 13, Huntsville, AL 35812 (United States)

2013-08-01

Understanding how the solar corona is structured is of fundamental importance to determine how the Sun's upper atmosphere is heated to high temperatures. Recent spectroscopic studies have suggested that an instrument with a spatial resolution of 200 km or better is necessary to resolve coronal loops. The High Resolution Coronal Imager (Hi-C) achieved this performance on a rocket flight in 2012 July. We use Hi-C data to measure the Gaussian widths of 91 loops observed in the solar corona and find a distribution that peaks at about 270 km. We also use Atmospheric Imaging Assembly data for a subset of these loops and find temperature distributions that are generally very narrow. These observations provide further evidence that loops in the solar corona are often structured at a scale of several hundred kilometers, well above the spatial scale of many proposed physical mechanisms.

Qualidade de vida do paciente submetido à Microcirurgia Endoscópica Transanal (TEM Quality of life after Transanal Endoscopic Microsurgery (TEM

Directory of Open Access Journals (Sweden)

Roberto da Silveira Moraes

2007-03-01

qualidade de vida com a TEM.BACKGROUND: Transanal Endoscopic Microsurgery (TEM is a minimal invasive procedure for the treatment of rectal tumors. Nowadays there has been an increasing medical interest regarding quantitative measurements pertaining quality of life. AIM: To evaluate life quality of patients submitted to TEM at Hospital de Clínicas of the Federal University of Paraná in the Department of Surgery of the Digestive Tract. METHODS: A prospective observational cohort study was done to evaluate the quality of life after TEM. Thirty-four patients answered a questionnaire composed of 14 questions concerning postoperative and labor issues. Questions concerned primarily about: informed consent; pain felt after surgery; patients capacity to walk during the postoperative state; period of return to normal activities; satisfaction regarding the absence of postoperative scars; postoperative incontinence, as well as the recommendation of this surgery to family members or friends. RESULTS: All thirty-four patients claimed to be adequately informed about the procedure. The absence of postoperative pain was observed in 82.5 %, and all demonstrated the capacity to walk in the first postoperative day. In average, returning to normal activities began after the seventh day of surgery. Only five patients (14.70% experimented transitory fecal incontinence, enduring no longer than a week. Three patients (8.82% were later readmitted to the hospital: two with residual tumors and the other for tumor recurrence. Two patients (5.88% complained about temporary modification in his/her sexual life after the surgery, and 97.05% would indicate TEM for his/her family members or friends. The average time period of admission was of three days. CONCLUSION: Patients presented a good evolution, with little postoperative pain, and a low complication index, demonstrating satisfactory and adequate quality of life after TEM.

XRD, TEM, and thermal analysis of Arizona Ca-montmorillonites modified with didodecyldimethylammonium bromide.

Science.gov (United States)

Sun, Zhiming; Park, Yuri; Zheng, Shuilin; Ayoko, Godwin A; Frost, Ray L

2013-10-15

An Arizona SAz-2 calcium montmorillonite was modified by a typical dialkyl cationic surfactant (didodecyldimethylammonium bromide, abbreviated to DDDMA) through direct ion exchange. The obtained organoclays were characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HR-TEM), high-resolution thermogravimetric analysis (HR-TG), and infrared emission spectroscopy (IES). The intercalation of surfactants greatly increased the basal spacing of the interlayers and the conformation arrangement of the loaded surfactant were assessed based on the XRD and TEM measurements. This work shows that the dialkyl surfactant can be directly intercalated into the montmorillonite without first undergoing Na(+) exchange. Moreover, the thermal stability of organoclays and the different arrangements of the surfactant molecules intercalated in the SAz-2 Ca-montmorillonite were determined by a combination of TG and IES techniques. The detailed conformational ordering of different intercalated surfactants under different conditions was also studied. The surfactant molecule DDDMA has proved to be thermally stable even at 400°C which indicates that the prepared organoclay is stable to significantly high temperatures. This study offers new insights into the structure and thermal stabilities of SAz-2 Ca-montmorillonite modified with DDDMA. The experimental results also confirm the potential applications of organic SAz-2 Ca-montmorillonites as adsorbents and polymer-clay nanocomposites. Copyright © 2013 Elsevier Inc. All rights reserved.

High resolution TEM of chondritic carbonaceous matter: Metamorphic evolution and heterogeneity

Science.gov (United States)

Le Guillou, Corentin; Rouzaud, Jean-Noël.; Bonal, Lydie; Quirico, Eric; Derenne, Sylvie; Remusat, Laurent

2012-03-01

The insoluble carbonaceous matter from 12 chondrites (CI, CM, CO, CV, EH, and UOC), was characterized by high resolution transmission electron microscopy (HRTEM). Besides ubiquitous nanoglobules, the insoluble organic matter from petrologic type 1 and 2 chondrites and Semarkona (LL 3.0) is composed of a highly disordered polyaromatic component. No structural differences were observed between these IOMs, in agreement with the limited thermal metamorphism they all experienced. In chondrites of petrologic type >3.0, the evolution of the IOM is controlled by the extent of thermal metamorphism. The polyaromatic layers, shorter than 1 nm in petrologic type ≤3.0 chondrites, grow up to sizes between 5 and 10 nm in petrologic type >3.6 chondrites, contributing to the increase of the degree of structural order. In addition, we find rare, but ubiquitous onion-like carbons, which may be the product of nanodiamond graphitization. The insoluble carbonaceous matter of the enstatite chondrite Sahara 97096 (EH 3) is different from the other meteorites studied here. It is more heterogeneous and displays a high abundance of graphitized particles. This may be the result of a mixture between (1) the disordered carbon located in the matrix, and (2) catalytic graphitized phases associated with metal, potentially originating from partial melting events. The structural and nanostructural evolution are similar in all IOMs. This suggests that the structure of the accreted precursors and the parent body conditions of their secondary thermal modifications (temperature, duration, and pressure) were similar. The limited degree of organization of the most metamorphosed IOMs compared with terrestrial rocks submitted to similar temperature suggests that the conditions are not favorable to graphitization processes, due to the chemical nature of the precursor or the lack of confinement pressure.

TEM1 expression in cancer-associated fibroblasts is correlated with a poor prognosis in patients with gastric cancer

International Nuclear Information System (INIS)

Fujii, Satoshi; Fujihara, Ayano; Natori, Kei; Abe, Anna; Kuboki, Yasutoshi; Higuchi, Youichi; Aizawa, Masaki; Kuwata, Takeshi; Kinoshita, Takahiro; Yasui, Wataru; Ochiai, Atsushi

2015-01-01

The cancer stroma, including cancer-associated fibroblasts (CAFs), is known to contribute to cancer cell progression and metastasis, suggesting that functional proteins expressed specifically in CAFs might be candidate molecular targets for cancer treatment. The purpose of the present study was to explore the possibility of using TEM1 (tumor endothelial marker 1), which is known to be expressed in several types of mesenchymal cells, as a molecular target by examining the impact of TEM1 expression on clinicopathological factors in gastric cancer patients. A total of 945 consecutive patients with gastric cancer who underwent surgery at the National Cancer Center Hospital East between January 2003 and July 2007 were examined using a tissue microarray approach. TEM1 expression in CAFs or vessel-associated cells was determined using immunohistochemical staining. Three items (CAF-TEM1-positivity, CAF-TEM1-intensity, and vessel-TEM1-intensity) were then examined to determine the correlations between the TEM1 expression status and the recurrence-free survival (RFS), overall survival (OS), cancer-related survival (COS), and other clinicopathological factors. Significant correlations between CAF-TEM1-positivity or CAF-TEM1-intensity and RFS, OS, or COS were observed (P < 0.001, Kaplan–Meier curves); however, no significant correlation between vessel-TEM1-intensity and RFS, OS, or COS was observed. A univariate analysis showed that CAF-TEM1-positivity and CAF-TEM1-intensity were each correlated with a scirrhous subtype, tumor depth, nodal status, distant metastasis, serosal invasion, lymphatic or venous vessel infiltrations, and pTMN stage. This study suggests that the inhibition of TEM1 expression specifically in the CAFs of gastric carcinoma might represent a new strategy for the treatment of gastric cancer

Substrate-HTcS thin film interaction studies by (S)TEM

NARCIS (Netherlands)

Ramaekers, P.P.J.; Klepper, D.; Kitazawa, K.; Ishiguro, T.

1989-01-01

This paper concerns with compatibility aspects beween HTcS thin film either their substrates. The influence of substrate-thin film interaction and thin film microstructure on the superconducting properties is discussed. In this respect, data based on (S)TEM observations are presented. It is

Feasibility of Observing and Characterizing Single Ion Strikes in Microelectronic Components

International Nuclear Information System (INIS)

Dingreville, Remi Philippe Michel; Hattar, Khalid Mikhiel; Bufford, Daniel Charles

2015-01-01

The transient degradation of semiconductor device performance under irradiation has long been an issue of concern. A single high-energy charged particle can degrade or permanently destroy the microelectronic component, potentially altering the course or function of the systems. Disruption of the the crystalline structure through the introduction of quasi-stable defect structures can change properties from semiconductor to conductor. Typically, the initial defect formation phase is followed by a recovery phase in which defect-defect or defect-dopant interactions modify the characteristics of the damaged structure. In this LDRD Express, in-situ ion irradiation transmission microscopy (TEM) in-situ TEM experiments combined with atomistic simulations have been conducted to determine the feasibility of imaging and characterizing the defect structure resulting from a single cascade in silicon. In-situ TEM experiments have been conducted to demonstrate that a single ion strike can be observed in Si thin films with nanometer resolution in real time using the in-situ ion irradiation transmission electron microscope (I 3 TEM). Parallel to this experimental effort, ion implantation has been numerically simulated using Molecular Dynamics (MD). This numerical framework provides detailed predictions of the damage and follow the evolution of the damage during the first nanoseconds. The experimental results demonstrate that single ion strike can be observed in prototypical semiconductors.

New constraints on deformation processes in serpentinite from sub-micron Raman Spectroscopy and TEM

Science.gov (United States)

Smith, S. A. F.; Tarling, M.; Rooney, J. S.; Gordon, K. C.; Viti, C.

2017-12-01

Extensive work has been performed to characterize the mineralogical and mechanical properties of the various serpentine minerals (i.e. antigorite, lizardite, chrysotile, polyhedral and polygonal serpentine). However, correct identification of serpentine minerals is often difficult or impossible using conventional analytical techniques such as optical- and SEM-based microscopy, X-ray diffraction and infrared spectroscopy. Transmission Electron Microscopy (TEM) is the best analytical technique to identify the serpentine minerals, but TEM requires complex sample preparation and typically results in very small analysis areas. Sub-micron confocal Raman spectroscopy mapping of polished thin sections provides a quick and relatively inexpensive way of unambiguously distinguishing the main serpentine minerals within their in-situ microstructural context. The combination of high spatial resolution (with a diffraction-limited system, 366 nm), large-area coverage (up to hundreds of microns in each dimension) and ability to map directly on thin sections allows intricate fault rock textures to be imaged at a sample-scale, which can then form the target of more focused TEM work. The potential of sub-micron Raman Spectroscopy + TEM is illustrated by examining sub-micron-scale mineral intergrowths and deformation textures in scaly serpentinites (e.g. dissolution seams, mineral growth in pressure shadows), serpentinite crack-seal veins and polished fault slip surfaces from a serpentinite-bearing mélange in New Zealand. The microstructural information provided by these techniques has yielded new insights into coseismic dehydration and amorphization processes and the interplay between creep and localised rupture in serpentinite shear zones.

Characterization of some biological specimens using TEM and SEM

Science.gov (United States)

Ghosh, Nabarun; Smith, Don W.

2009-05-01

The advent of novel techniques using the Transmission and Scanning Electron Microscopes improved observation on various biological specimens to characterize them. We studied some biological specimens using Transmission and Scanning Electron Microscopes. We followed negative staining technique with Phosphotungstic acid using bacterial culture of Bacillus subtilis. Negative staining is very convenient technique to view the structural morphology of different samples including bacteria, phage viruses and filaments in a cell. We could observe the bacterial cell wall and flagellum very well when trapped the negative stained biofilm from bacterial culture on a TEM grid. We cut ultra thin sections from the fixed root tips of Pisum sativum (Garden pea). Root tips were pre fixed with osmium tetroxide and post fixed with uranium acetate and placed in the BEEM capsule for block making. The ultrathin sections on the grid under TEM showed the granular chromatin in the nucleus. The protein bodies and large vacuoles with the storage materials were conspicuous. We followed fixation, critical point drying and sputter coating with gold to view the tissues with SEM after placing on stubs. SEM view of the leaf surface of a dangerous weed Tragia hispida showed the surface trichomes. These trichomes when break on touching releases poisonous content causing skin irritation. The cultured tissue from in vitro culture of Albizia lebbeck, a tree revealed the regenerative structures including leaf buds and stomata on the tissue surface. SEM and TEM allow investigating the minute details characteristic morphological features that can be used for classroom teaching.

Atomistic observations and analyses of lattice defects in transmission electron microscopes

CERN Document Server

Abe, H

2003-01-01

The transmission electron microscope (TEM) -accelerators was developed. TEM-Accelerator made possible to observe in situ experiments of ion irradiation and implantation. The main results are the experimental proof of new lattice defects by irradiation, the formation process and synthesized conditions of carbon onion by ion implantation, the microstructure and phase transformation conditions of graphite by ion irradiated phase transformation, the irradiation damage formation process by simultaneous irradiation of electron and ion and behavior of fullerene whisker under irradiation. The microstructural evolution of defect clusters in copper irradiated with 240-keV Cu sup + ions and a high resolution electron micrograph of carbon onions synthesized by ion implantation are explained as the examples of recent researches. (S.Y.)

TEM characterization of corrosion products formed on a SS-15ZR alloy

International Nuclear Information System (INIS)

Luo, J. S.; Abraham, D. P.

2000-01-01

The corrosion products formed on a stainless steel-15Zr (SS-15Zr) alloy have been characterized by transmission electron microscopy (TEM) and energy dispersive x-ray spectroscopy (EDS). Examination of alloy particles that were immersed in 90 C deionized water for two years revealed that different corrosion products were formed on the stainless steel and intermetallic phases. Two corrosion products were identified on an austenite particle: trevorite (NiFe 2 O 4 ) in the layer close to the metal and maghemite (Fe 2 O 3 ) in the outer layer. The corrosion layer formed on the intermetallic was uniform, adherent, and amorphous. The EDS analysis indicated that the layer was enriched in zirconium when compared with the intermetallic composition. High-resolution TEM images of the intermetallic-corrosion layer interface show an interlocking metal-oxide interface which may explain the relatively strong adherence of the corrosion layer to the intermetallic surface. These results will be used to evaluate corrosion mechanisms and predict long-term corrosion behavior of the alloy waste form

SIZE OF BOEHMITE NANOPARTICLES BY TEM IMAGES ANALYSIS

Directory of Open Access Journals (Sweden)

Maxime Moreaud

2011-05-01

Full Text Available Transition aluminas, and especially the gamma type, are largely used as catalyst supports in refining and petrochemicals. Most studies focus on properties resulting from material texture and casting (specific surface, porous volume, pore shape and diameter. However, surface properties of alumina should be considered as well, as the catalytic activity is tightly related to the structure of exposed crystalline faces. As γ alumina results from controlled thermal treatment of boehmite γ-AlOOH by a topotactic transformation, the nature of exposed crystalline planes is related to the starting material. Therefore, the synthesis of the oxihydroxide γ-AlOOH, and especially size and shape of these particles, is critical in determining the relevant surface properties. Unlike often aggregated alumina, boehmite nanoparticles can be observed by TEM. Analysis of these TEM images can be performed to estimate the size of the boehmite nanoparticles. Information about morphology of the nanoparticles is obtained by the analysis of the covariance, modeling micrographs by a dilution model.

Does resolution of flow field observation influence apparent habitat use and energy expenditure in juvenile coho salmon?

Science.gov (United States)

Tullos, D. D.; Walter, C.; Dunham, J.

2016-12-01

This study investigated how the resolution of observation influences interpretation of how fish, juvenile Coho Salmon (Oncorhynchus kisutch), exploit the hydraulic environment in streams. Our objectives were to evaluate how spatial resolution of the flow field observation influenced: 1) the velocities considered to be representative of habitat units; 2) patterns of use of the hydraulic environment by fish; and 3) estimates of energy expenditure. We addressed these objectives using observations within a 1:1 scale physical model of a full-channel log jam in an outdoor experimental stream. Velocities were measured with Acoustic Doppler Velocimetry at a 10 cm grid spacing, whereas fish locations and tailbeat frequencies were documented over time using underwater videogrammetry. Results highlighted that resolution of observation did impact perceived habitat use and energy expenditure, as did the location of measurement within habitat units and the use of averaging to summarize velocities within a habitat unit. In this experiment, the range of velocities and energy expenditure estimates increased with coarsening resolution, reducing the likelihood of measuring the velocities locally experienced by fish. In addition, the coarser resolutions contributed to fish appearing to select velocities that were higher than what was measured at finer resolutions. These findings indicate the need for careful attention to and communication of resolution of observation in investigating the hydraulic environment and in determining the habitat needs and bioenergetics of aquatic biota.

High spectral resolution infrared observations of V1057 Cygni

International Nuclear Information System (INIS)

Hartmann, L.; Kenyon, S.J.

1987-01-01

High-resolution near-infrared spectra of V1057 Cygni obtained in 1986 with the KPNO 4-m Fourier transform spectrometer provide support for a previously proposed accretion disk model. The model predicts that the observed rotational broadening of spectral lines should be smaller in the infrared than in the optical. The present observations show that V1057 Cyg rotates more slowly at 2.3 microns than at 6000 A by an amount quantitatively consistent with the simple disk models. The absence of any radial velocity variations in either the infrared or optical spectral regions supports the suggestion that the accreted material arises from a remnant disk of protostellar material. 19 references

Atomic-resolution transmission electron microscopy of electron beam–sensitive crystalline materials

Science.gov (United States)

Zhang, Daliang; Zhu, Yihan; Liu, Lingmei; Ying, Xiangrong; Hsiung, Chia-En; Sougrat, Rachid; Li, Kun; Han, Yu

2018-02-01

High-resolution imaging of electron beam–sensitive materials is one of the most difficult applications of transmission electron microscopy (TEM). The challenges are manifold, including the acquisition of images with extremely low beam doses, the time-constrained search for crystal zone axes, the precise image alignment, and the accurate determination of the defocus value. We develop a suite of methods to fulfill these requirements and acquire atomic-resolution TEM images of several metal organic frameworks that are generally recognized as highly sensitive to electron beams. The high image resolution allows us to identify individual metal atomic columns, various types of surface termination, and benzene rings in the organic linkers. We also apply our methods to other electron beam–sensitive materials, including the organic-inorganic hybrid perovskite CH3NH3PbBr3.

Atomic-resolution transmission electron microscopy of electron beam–sensitive crystalline materials

KAUST Repository

Zhang, Daliang

2018-01-18

High-resolution imaging of electron beam-sensitive materials is one of the most difficult applications of transmission electron microscopy (TEM). The challenges are manifold, including the acquisition of images with extremely low beam doses, the time-constrained search for crystal zone axes, the precise image alignment, and the accurate determination of the defocus value. We develop a suite of methods to fulfill these requirements and acquire atomic-resolution TEM images of several metal organic frameworks that are generally recognized as highly sensitive to electron beams. The high image resolution allows us to identify individual metal atomic columns, various types of surface termination, and benzene rings in the organic linkers. We also apply our methods to other electron beam–sensitive materials, including the organic-inorganic hybrid perovskite CH3NH3PbBr3.

Mechanical Conversion for High-Throughput TEM Sample Preparation

International Nuclear Information System (INIS)

Kendrick, Anthony B; Moore, Thomas M; Zaykova-Feldman, Lyudmila

2006-01-01

This paper presents a novel method of direct mechanical conversion from lift-out sample to TEM sample holder. The lift-out sample is prepared in the FIB using the in-situ liftout Total Release TM method. The mechanical conversion is conducted using a mechanical press and one of a variety of TEM coupons, including coupons for both top-side and back-side thinning. The press joins a probe tip point with attached TEM sample to the sample coupon and separates the complete assembly as a 3mm diameter TEM grid, compatible with commercially available TEM sample holder rods. This mechanical conversion process lends itself well to the high through-put requirements of in-line process control and to materials characterization labs where instrument utilization and sample security are critically important

Cross section TEM characterization of high-energy-Xe-irradiated U-Mo

Energy Technology Data Exchange (ETDEWEB)

Ye, B., E-mail: bye@anl.gov [Nuclear Engineering Division, Argonne National Laboratory, 9700 S. Cass Ave. Lemont, IL 60439 (United States); Jamison, L.; Miao, Y. [Nuclear Engineering Division, Argonne National Laboratory, 9700 S. Cass Ave. Lemont, IL 60439 (United States); Bhattacharya, S. [Department of Materials Science and Engineering, Northwestern University, 2220 Campus Dr. Evanston, IL 60208 (United States); Hofman, G.L.; Yacout, A.M. [Nuclear Engineering Division, Argonne National Laboratory, 9700 S. Cass Ave. Lemont, IL 60439 (United States)

2017-05-15

U-Mo alloys irradiated with 84 MeV Xe ions to various doses were characterized with transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM) techniques. The TEM thin foils were prepared perpendicular to the irradiated surface to allow a direct observation of the entire region modified by ions. Therefore, depth-selective microstructural information was revealed. Varied irradiation-induced phenomena such as gas bubble formation, phase reversal, and recrystallization were observed at different ion penetration depths in U-Mo. - Highlights: •Three distinct zones were observed along the ion traveling direction in U-7Mo irradiated with 84 MeV Xe ions at 350 °C. •The α-U particles within the Xe-implanted region were reverted to γ-U phase by irradiation. •High-density random intra-granular bubbles in a size of 4–5 nm were found in the irradiated region, coexisting with large inter-granular bubbles. •The high lattice stresses built up during the irradiation-induced phase reversal is probably the driving force for the small grain formation at cell boundaries.

Study of the phase transformation of single particles of Ga2O3 by UV-Raman spectroscopy and high-resolution TEM.

Science.gov (United States)

Wang, Xiang; Xu, Qian; Fan, Fengtao; Wang, Xiuli; Li, Mingrun; Feng, Zhaochi; Li, Can

2013-09-01

By taking advantage of UV-Raman spectroscopy and high-resolution TEM (HRTEM), combined with the focused ion beam (FIB) technique, the transformation from GaOOH into α-Ga2O3 and then into β-Ga2O3 was followed. We found that the stepwise transformations took place from the surface region before developing into the bulk of single particles without particle agglomeration and growth. During the transformation from GaOOH into α-Ga2O3, the elimination of water vapor through the dehydroxylation of GaOOH resulted in the formation of micropores in the single particles, whilst maintaining their particle size. For the phase transformation from α-Ga2O3 into β-Ga2O3, the nucleation of β-Ga2O3 was found to occur at the surface defects and this process could be retarded by occupying these defects with a small amount of La2O3. By finely controlling the process of the phase transformation, the β-Ga2O3 domains gradually developed from the surface into the bulk of the single particles without particle agglomeration. Therefore, the surface structure of the α-Ga2O3 single particles can be easily tuned and a particle with an α@β core-shell phase structure has been obtained. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Two-dimensional dopant profiling for shallow junctions by TEM and AFM

International Nuclear Information System (INIS)

Yoo, K.

2000-01-01

The present work concerns the development of the Etch/TEM and Etch/AFM methods to obtain quantitative 2-D dopant profiles for the ultra shallow p-n junctions of the next generation of metal-oxide-semiconductor field effect transistors (MOSFETs). For these methods, thin foil (TEM) or bulk (AFM) cross-sectional specimens were etched using a dopant selective chemical so that local areas of the dopant implanted source/drain (S/D) regions were etched to different depths. The surface topography of the S/D regions was determined from the thickness fringes for the TEM method and by the direct measurement for the AFM method. The local etched depths were converted to etch rates, and these were then converted to corresponding 1-D and 2-D dopant profiles by the experimentally independent etch rate calibration curves. Shallow junction MOSFET samples were designed and fabricated with junction depths 60nm (n + /p), 80nm (n + /p) and 120nm (p + /n) using 0.25μm process technology. A new method using SOG (Spin-on-Glass) contributed to the high quality XTEM thin foil specimens. Controlled stirring of the etchant increased the dopant concentration selectivity and etching consistency. Computer modelling simulated the isotropic etching behaviours, which can introduce the significant error in dopant profiling for shallow and abrupt junction samples. Comprehensive quantitative results enabled the optimum etching time to be determined for the first time. Etch/TEM method gave 1-D dopant profiles that showed good agreement with 1-D Spreading Resistance Probe (SRP) dopant profiles for determining junction depths. 2-D dopant profiles gave L eff , i.e. the shortest lateral distance between the S/D junctions, of major importance for MOSFET performance. Values for L eff of 161, 159 and 123nm were determined from 60, 80 and 120nm junction depth samples respectively, compared with the 215nm MOSFET gate length. The resolution and accuracy of the Etch/TEM method are estimated as 2 and 10nm

Static shift correction of MT data in Tohoku district using TEM soundings; TEM ho data wo mochiita Tohoku chiho MT ho data no statistic shift hosei

Energy Technology Data Exchange (ETDEWEB)

Kawakami, N; Kumekawa, Y; Miura, Y; Takasugi, S [GERD Geothermal Energy Research and Development Co. Ltd., Tokyo (Japan); Fujinawa, Y [National Research Institute for Disaster Prevention, Tsukuba (Japan)

1997-05-27

There is a possibility that the wide-band MT observation data obtained in the central part of Tohoku district include the static shift effect. To grasp the static shift effect in the MT data, the TEM soundings were conducted at all the site where the MT data were measured. The TEM sounding system was developed for the shallow survey depth ranging from 5 m to 150 m. When showing the measured results on the histogram, it was found that the static shifts were concentrated in the vicinity of zero. About 70% of the data was below 0.2 decade. Only a slight static shift effect was observed. This means that the results obtained by the two-dimensional analysis are plausible. Especially, the static shift around plain was small. Therefore, the current results around the plain were trustful. On the other hand, the static shift in the mountainous area was rather large. Accordingly, the results around the mountainous area should be carefully treated. 7 refs., 10 figs.

HR-TEM and FT-Raman dataset of the caffeine interacted Phe–Phe peptide nanotube for possible sensing applications

Directory of Open Access Journals (Sweden)

A. Lakshmi Narayanan

2018-02-01

Full Text Available Sensing ability of caffeine interaction with Phe-Phe annotates (PNTs, is presented (Govindhan et al., 2017; Karthikeyan et al., 2014; Tavagnacco et al., 2013; Kennedy et al., 2011; Wang et al., 2017 [1–5] in this data set. Investigation of synthesized caffeine carrying peptide nanotubes are carried out by FT-Raman spectral analysis and high resolution transmission electron microscopy (HR-TEM. Particle size of the caffeine loaded PNTs is < 40 nm. The FT-Raman spectrum signals are enhanced in the region of 400–1700 cm−1. These data are ideal tool for the applications like biosensing and drug delivery research (DDS. Keywords: Caffeine, PNTs, Sensing, HR-TEM, FT-Raman data

Does resolution of flow field observation influence apparent habitat use and energy expenditure in juvenile coho salmon?

Science.gov (United States)

Tullos, Desiree D.; Walter, Cara; Dunham, Jason B.

2016-01-01

This study investigated how the resolution of observation influences interpretation of how fish, juvenile Coho Salmon (Oncorhynchus kisutch), exploit the hydraulic environment in streams. Our objectives were to evaluate how spatial resolution of the flow field observation influenced: (1) the velocities considered to be representative of habitat units; (2) patterns of use of the hydraulic environment by fish; and (3) estimates of energy expenditure. We addressed these objectives using observations within a 1:1 scale physical model of a full-channel log jam in an outdoor experimental stream. Velocities were measured with Acoustic Doppler Velocimetry at a 10 cm grid spacing, whereas fish locations and tailbeat frequencies were documented over time using underwater videogrammetry. Results highlighted that resolution of observation did impact perceived habitat use and energy expenditure, as did the location of measurement within habitat units and the use of averaging to summarize velocities within a habitat unit. In this experiment, the range of velocities and energy expenditure estimates increased with coarsening resolution (grid spacing from 10 to 100 cm), reducing the likelihood of measuring the velocities locally experienced by fish. In addition, the coarser resolutions contributed to fish appearing to select velocities that were higher than what was measured at finer resolutions. These findings indicate the need for careful attention to and communication of resolution of observation in investigating the hydraulic environment and in determining the habitat needs and bioenergetics of aquatic biota.

TEM-145 and TEM-146 β-lactamases produced by Escherichia coli ...

African Journals Online (AJOL)

GREGO

2007-03-05

Mar 5, 2007 ... Key words: Escherichia coli, plasmid-mediated, TEM β-lactamase. ... Enterobacteriaceae, the most prevalent mechanism of resistance to ... the production of a relatively inhibitor-resistant OXA-type β-lactamase .... and 8.6 as transcripts of the E. coli chromosomal AmpC .... Mode of action and mechanisms of.

High-resolution far-infrared observations of the galactic center

International Nuclear Information System (INIS)

Harvey, P.M.; Campbell, M.F.; Hoffmann, W.F.

1976-01-01

A map at 53 μ with 17'' resolution and three-color observations at 53 μ, 100 μ, and 175 μ with approx.30'' beams of Sgr A are presented. Sagittarius A is resolved into two main sources, one associated with the cluster of strong 10 μ sources and another approx.45'' to the southwest coincident with a weak 10 μ source. The dust temperature peaks near the strong 10 μ sources, but the 100 μ and 175 μ fluxes and the far-infrared optical depth are greatest near the southwest source. The amount of dust required to explain the far-infrared emission is comparable to that observed in absorption in the near-infrared

TEM and EELS study of deuterated carbon: application to the fuel retention in tokamaks

International Nuclear Information System (INIS)

Bernier, N.

2007-12-01

We developed a methodology, based on the combination of TEM and EELS techniques, for a structural and chemical characterization, at a high spatial resolution, of a wide range of carbon materials. We i) optimized, in the framework of theoretical models, the sp2 fraction quantification from pure carbons by EELS ii) transferred this quantification to deuterated amorphous carbon layers iii) showed, from graphitized carbons, how the TEM-EELS combination allows to detect low concentrations of implanted D. Due to the accomplishment of these developments, we applied our approach to the study of D retention in composites C/C, which are the plasma-facing materials in TS. We showed that specific localized retention sites correspond to relatively large (∼ 3 mm.) cracks between fibres and matrix; such cracks offer a simple and direct path for deuterated amorphous carbon. The particle balance performed in TS is discussed in the light of this trapping mechanism. (author)

LTE modeling of inhomogeneous chromospheric structure using high-resolution limb observations

Science.gov (United States)

Lindsey, C.

1987-01-01

The paper discusses considerations relevant to LTE modeling of rough atmospheres. Particular attention is given to the application of recent high-resolution observations of the solar limb in the far-infrared and radio continuum to the modeling of chromospheric spicules. It is explained how the continuum limb observations can be combined with morphological knowledge of spicule structure to model the physical conditions in chromospheric spicules. This discussion forms the basis for a chromospheric model presented in a parallel publication based on observations ranging from 100 microns to 2.6 mm.

A short note on how to convert a conventional analytical TEM into an analytical Low Voltage TEM

International Nuclear Information System (INIS)

Stöger-Pollach, M.

2014-01-01

The present work is a short note on the performance of a conventional transmission electron microscope (TEM) being operated at very low beam energies (below 20 keV). We discuss the high tension stability and resolving power of this uncorrected TEM. We find out that the theoretical lens performance can nearly be achieved in practice. We also demonstrate that electron energy loss spectra can be recorded at these low beam energies with standard equipment. The signal-to-noise ratio is sufficiently good for further data treatment like multiple scattering deconvolution and Kramers–Kronig analysis. - Highlights: • TEM operation at very low beam energies (below 20 keV). • Testing of hardware performance at low beam energies. • EELS spectra recorded with 10 keV electrons

Observations of silicon carbide by high resolution transmission electron microscopy

International Nuclear Information System (INIS)

Smith, D.J.; Jepps, N.W.; Page, T.F.

1978-01-01

High resolution transmission electron microscopy techniques, principally involving direct lattice imaging, have been used as part of a study of the crystallography and phase transformation mechanics of silicon carbide polytypes. In particular, the 3C (cubic) and 6H (hexagonal) polytypes have been examined together with partially transformed structural mixtures. Although direct observation of two-dimensional atomic structures was not possible at an operating voltage of 100 kV, considerable microstructural information has been obtained by careful choice of the experimental conditions. In particular, tilted beam observations of the 0.25 nm lattice fringes have been made in the 3C polytype for two different brace 111 brace plane arrays in order to study the dimensions and coherency of finely-twinned regions together with brace 0006 brace and brace 1 0 bar1 2 brace lattice images in the 6H polytype which allow the detailed stacking operations to be resolved. Lower resolution lattice images formed with axial illumination have also been used to study the nature of the 3C → 6H transformation and results are presented showing that the transformation interface may originate with fine twinning of the 3C structure followed by growth of the resultant 6H regions. Observations have been made of the detailed stepped structure of this interface together with the stacking fault distribution in the resultant 6H material. (author)

The impact of clustering and angular resolution on far-infrared and millimeter continuum observations

Science.gov (United States)

Béthermin, Matthieu; Wu, Hao-Yi; Lagache, Guilaine; Davidzon, Iary; Ponthieu, Nicolas; Cousin, Morgane; Wang, Lingyu; Doré, Olivier; Daddi, Emanuele; Lapi, Andrea

2017-11-01

Follow-up observations at high-angular resolution of bright submillimeter galaxies selected from deep extragalactic surveys have shown that the single-dish sources are comprised of a blend of several galaxies. Consequently, number counts derived from low- and high-angular-resolution observations are in tension. This demonstrates the importance of resolution effects at these wavelengths and the need for realistic simulations to explore them. We built a new 2 deg2 simulation of the extragalactic sky from the far-infrared to the submillimeter. It is based on an updated version of the 2SFM (two star-formation modes) galaxy evolution model. Using global galaxy properties generated by this model, we used an abundance-matching technique to populate a dark-matter lightcone and thus simulate the clustering. We produced maps from this simulation and extracted the sources, and we show that the limited angular resolution of single-dish instruments has a strong impact on (sub)millimeter continuum observations. Taking into account these resolution effects, we are reproducing a large set of observables, as number counts and their evolution with redshift and cosmic infrared background power spectra. Our simulation consistently describes the number counts from single-dish telescopes and interferometers. In particular, at 350 and 500 μm, we find that the number counts measured by Herschel between 5 and 50 mJy are biased towards high values by a factor 2, and that the redshift distributions are biased towards low redshifts. We also show that the clustering has an important impact on the Herschel pixel histogram used to derive number counts from P(D) analysis. We find that the brightest galaxy in the beam of a 500 μm Herschel source contributes on average to only 60% of the Herschel flux density, but that this number will rise to 95% for future millimeter surveys on 30 m-class telescopes (e.g., NIKA2 at IRAM). Finally, we show that the large number density of red Herschel sources

In-situ heating TEM observation of microscopic structural changes of size-controlled metallic copper/gelatin composite.

Science.gov (United States)

Narushima, Takashi; Hyono, Atsushi; Nishida, Naoki; Yonezawa, Tetsu

2012-10-01

Copper/gelatin composite particles with controlled sizes were prepared at room temperature from cupric sulfate pentahydrate in the presence of gelatin as a protective reagent by using hydrazine monohydrate as a reducing agent. The formed particles with the size between 190-940 nm were secondary aggregated particles which were composed of smaller nanosized particles ("particle-in-particle"), the presence of which was established by XRD patterns and a cross-sectional TEM image. The sintering behavior of these copper/gelatin composite particles was demonstrated by in-situ heating TEM under a high vacuum (approximately 10(-5) Pa) and separately with the oxygen partial pressure controlled at the 10(-4) Pa level. It was established that the particles began to sinter at about 330 degrees C with the oxygen and that they sublimate above 450 degrees C both in the vacuum and oxygen conditions. This result shows that the introduction of an adequate amount of oxygen was effective to remove the gelatin surrounding the particles. It can also be concluded that the sintering of the copper/gelatin composite particles occurred even in the absence of a reducing agent such as hydrogen gas.

Report on the Installation and Preparedness of a Protochips Fusion in-situ Heating Holder for TEM

Energy Technology Data Exchange (ETDEWEB)

Edmondson, Philip D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

2017-03-01

This brief report documents the procurement and installation of a Protochips Fusion (formerly Aduro) high-temperature, high stability transmission electron microscopy (TEM) specimen holder that allows for the high spatial resolution characterization of material specimens at high temperature in situ of an electron microscope. This specimen holder was specifically procured for use with The FEI Talos F200X Scanning/Transmission Electron Microscope (STEM) in Oak Ridge National Laboratory’s (ORNL’s) Low Activation Materials Development and Analysis (LAMDA) Laboratory. The Protochips Fusion holder will enable high-resolution structural and chemical analysis of irradiated materials at high temperature, becoming a unique capability worldwide, and would encourage high-quality in situ experiments to be conducted on irradiated materials.

Atomic-Resolution Transmission Electron Microscopic Movies for Study of Organic Molecules, Assemblies, and Reactions: The First 10 Years of Development.

Science.gov (United States)

Nakamura, Eiichi

2017-06-20

A molecule is a quantum mechanical entity. "Watching motions and reactions of a molecule with our eyes" has therefore been a dream of chemists for a century. This dream has come true with the aid of the movies of atomic-resolution transmission electron microscopic (AR-TEM) molecular images through real-time observation of dynamic motions of single organic molecules (denoted hereafter as single-molecule atomic-resolution real-time (SMART) TEM imaging). Since 2007, we have reported movies of a variety of single organic molecules, organometallic molecules, and their assemblies, which are rotating, stretching, and reacting. Like movies in the theater, the atomic-resolution molecular movies provide us information on the 3-D structures of the molecules and also their time evolution. The success of the SMART-TEM imaging crucially depends on the development of "chemical fishhooks" with which fish (organic molecules) in solution can be captured on a single-walled carbon nanotube (CNT, serving as a "fishing rod"). The captured molecules are connected to a slowly vibrating CNT, and their motions are displayed on a monitor in real time. A "fishing line" connecting the fish and the rod may be a σ-bond, a van der Waals force, or other weak connections. Here, the molecule/CNT system behaves as a coupled oscillator, where the low-frequency anisotropic vibration of the CNT is transmitted to the molecules via the weak chemical connections that act as an energy filter. Interpretation of the observed motions of the molecules at atomic resolution needs us to consider the quantum mechanical nature of electrons as well as bond rotation, letting us deviate from the conventional statistical world of chemistry. What new horizons can we explore? We have so far carried out conformational studies of individual molecules, assigning anti or gauche conformations to each C-C bond in conformers that we saw. We can also determine the structures of van der Waals assemblies of organic molecules

High-resolution observation of phase contrast at 1MeV. Amorphous or crystalline objects

International Nuclear Information System (INIS)

Bourret, A.; Desseaux, J.

1975-01-01

Many authors have stressed the possibilities of high voltage to improve resolution, but owing to numerous experimental difficulties the resolution limit at 1MeV, which lies around 1A for conventional lenses, has so far been unattainable. Thus the phase contrast at 1MeV has not been studied on evaporated objects. On the other hand the fringes of crystal planes have been observed at 1MeV. the CEN-G microscope having been considerably modified it has been possible to observe the phase contrast of amorphous or crystalline objects [fr

TEM sample preparation by FIB for carbon nanotube interconnects

International Nuclear Information System (INIS)

Ke, Xiaoxing; Bals, Sara; Romo Negreira, Ainhoa; Hantschel, Thomas; Bender, Hugo; Van Tendeloo, Gustaaf

2009-01-01

A powerful method to study carbon nanotubes (CNTs) grown in patterned substrates for potential interconnects applications is transmission electron microscopy (TEM). However, high-quality TEM samples are necessary for such a study. Here, TEM specimen preparation by focused ion beam (FIB) has been used to obtain lamellae of patterned samples containing CNTs grown inside contact holes. A dual-cap Pt protection layer and an extensive 5 kV cleaning procedure are applied in order to preserve the CNTs and avoid deterioration during milling. TEM results show that the inner shell structure of the carbon nanotubes has been preserved, which proves that focused ion beam is a useful technique to prepare TEM samples of CNT interconnects.

TEM sample preparation by FIB for carbon nanotube interconnects

Energy Technology Data Exchange (ETDEWEB)

Ke, Xiaoxing, E-mail: xiaoxing.ke@ua.ac.be [EMAT, University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp (Belgium); Bals, Sara [EMAT, University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp (Belgium); Romo Negreira, Ainhoa [IMEC, Kapeldreef 75, B-3001 Leuven (Belgium); Metallurgy and Materials Engineering Department, KU Leuven, Kasteelpark Arenberg 44, Leuven B-3001 (Belgium); Hantschel, Thomas; Bender, Hugo [IMEC, Kapeldreef 75, B-3001 Leuven (Belgium); Van Tendeloo, Gustaaf [EMAT, University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp (Belgium)

2009-10-15

A powerful method to study carbon nanotubes (CNTs) grown in patterned substrates for potential interconnects applications is transmission electron microscopy (TEM). However, high-quality TEM samples are necessary for such a study. Here, TEM specimen preparation by focused ion beam (FIB) has been used to obtain lamellae of patterned samples containing CNTs grown inside contact holes. A dual-cap Pt protection layer and an extensive 5 kV cleaning procedure are applied in order to preserve the CNTs and avoid deterioration during milling. TEM results show that the inner shell structure of the carbon nanotubes has been preserved, which proves that focused ion beam is a useful technique to prepare TEM samples of CNT interconnects.

Dynamics of electrochemical lithiation/delithiation of graphene-encapsulated silicon nanoparticles studied by in-situ TEM.

Science.gov (United States)

Luo, Langli; Wu, Jinsong; Luo, Jiayan; Huang, Jiaxing; Dravid, Vinayak P

2014-01-24

The incorporation of nanostructured carbon has been recently reported as an effective approach to improve the cycling stability when Si is used as high-capacity anodes for the next generation Li-ion battery. However, the mechanism of such notable improvement remains unclear. Herein, we report in-situ transmission electron microscopy (TEM) studies to directly observe the dynamic electrochemical lithiation/delithiation processes of crumpled graphene-encapsulated Si nanoparticles to understand their physical and chemical transformations. Unexpectedly, in the first lithiation process, crystalline Si nanoparticles undergo an isotropic to anisotropic transition, which is not observed in pure crystalline and amorphous Si nanoparticles. Such a surprising phenomenon arises from the uniformly distributed localized voltage around the Si nanoparticles due to the highly conductive graphene sheets. It is observed that the intimate contact between graphene and Si is maintained during volume expansion/contraction. Electrochemical sintering process where small Si nanoparticles react and merge together to form large agglomerates following spikes in localized electric current is another problem for batteries. In-situ TEM shows that graphene sheets help maintain the capacity even in the course of electrochemical sintering. Such in-situ TEM observations provide valuable phenomenological insights into electrochemical phenomena, which may help optimize the configuration for further improved performance.

In-situ TEM characterization of nanomaterials and devices

KAUST Repository

Kim, Moon; Park, Seongyong; Cha, Dong Kyu; Kim, Jiyoung; Floresca, Herman Carlo; Lu, Ning; Wang, Jinguo

2011-01-01

Electrical properties of nano size devices were directly measured by TEM. Real time observation of phase transition behavior in PRAM revealed that the volume of the crystalline phase is the main factor in determining cell resistance. In the transistor device, we have identified the doping type and area by measuring the I-V curve at the individual nano contact on the specimen. The evolution of the graphene edge structure was controlled and monitored at and up to 1200°C in-situ. © 2011 IEEE.

In-situ TEM characterization of nanomaterials and devices

KAUST Repository

Kim, Moon

2011-10-01

Electrical properties of nano size devices were directly measured by TEM. Real time observation of phase transition behavior in PRAM revealed that the volume of the crystalline phase is the main factor in determining cell resistance. In the transistor device, we have identified the doping type and area by measuring the I-V curve at the individual nano contact on the specimen. The evolution of the graphene edge structure was controlled and monitored at and up to 1200°C in-situ. © 2011 IEEE.

Characterization of TEM1/endosialin in human and murine brain tumors

International Nuclear Information System (INIS)

Carson-Walter, Eleanor B; Walter, Kevin A; Winans, Bethany N; Whiteman, Melissa C; Liu, Yang; Jarvela, Sally; Haapasalo, Hannu; Tyler, Betty M; Huso, David L; Johnson, Mahlon D

2009-01-01

TEM1/endosialin is an emerging microvascular marker of tumor angiogenesis. We characterized the expression pattern of TEM1/endosialin in astrocytic and metastatic brain tumors and investigated its role as a therapeutic target in human endothelial cells and mouse xenograft models. In situ hybridization (ISH), immunohistochemistry (IH) and immunofluorescence (IF) were used to localize TEM1/endosialin expression in grade II-IV astrocytomas and metastatic brain tumors on tissue microarrays. Changes in TEM1/endosialin expression in response to pro-angiogenic conditions were assessed in human endothelial cells grown in vitro. Intracranial U87MG glioblastoma (GBM) xenografts were analyzed in nude TEM1/endosialin knockout (KO) and wildtype (WT) mice. TEM1/endosialin was upregulated in primary and metastatic human brain tumors, where it localized primarily to the tumor vasculature and a subset of tumor stromal cells. Analysis of 275 arrayed grade II-IV astrocytomas demonstrated TEM1/endosialin expression in 79% of tumors. Robust TEM1/endosialin expression occurred in 31% of glioblastomas (grade IV astroctyomas). TEM1/endosialin expression was inversely correlated with patient age. TEM1/endosialin showed limited co-localization with CD31, αSMA and fibronectin in clinical specimens. In vitro, TEM1/endosialin was upregulated in human endothelial cells cultured in matrigel. Vascular Tem1/endosialin was induced in intracranial U87MG GBM xenografts grown in mice. Tem1/endosialin KO vs WT mice demonstrated equivalent survival and tumor growth when implanted with intracranial GBM xenografts, although Tem1/endosialin KO tumors were significantly more vascular than the WT counterparts. TEM1/endosialin was induced in the vasculature of high-grade brain tumors where its expression was inversely correlated with patient age. Although lack of TEM1/endosialin did not suppress growth of intracranial GBM xenografts, it did increase tumor vascularity. The cellular localization of TEM1

In situ TEM observation of stress-induced martensitictransformations and twinning processes in CuAlNi single crystals

Czech Academy of Sciences Publication Activity Database

Zárubová, Niva; Gemperlová, Juliana; Gemperle, Antonín; Dlabáček, Zdeněk; Šittner, Petr; Novák, Václav

2010-01-01

Roč. 58, č. 15 (2010), s. 5109-5119 ISSN 1359-6454 R&D Projects: GA AV ČR(CZ) IAA200100627 Institutional research plan: CEZ:AV0Z10100520 Keywords : CuAlNi shape memory alloy * martensitic transformation * in situ TEM straining Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.781, year: 2010

Objective function analysis for electric soundings (VES), transient electromagnetic soundings (TEM) and joint inversion VES/TEM

Science.gov (United States)

Bortolozo, Cassiano Antonio; Bokhonok, Oleg; Porsani, Jorge Luís; Monteiro dos Santos, Fernando Acácio; Diogo, Liliana Alcazar; Slob, Evert

2017-11-01

Ambiguities in geophysical inversion results are always present. How these ambiguities appear in most cases open to interpretation. It is interesting to investigate ambiguities with regard to the parameters of the models under study. Residual Function Dispersion Map (RFDM) can be used to differentiate between global ambiguities and local minima in the objective function. We apply RFDM to Vertical Electrical Sounding (VES) and TEM Sounding inversion results. Through topographic analysis of the objective function we evaluate the advantages and limitations of electrical sounding data compared with TEM sounding data, and the benefits of joint inversion in comparison with the individual methods. The RFDM analysis proved to be a very interesting tool for understanding the joint inversion method of VES/TEM. Also the advantage of the applicability of the RFDM analyses in real data is explored in this paper to demonstrate not only how the objective function of real data behaves but the applicability of the RFDM approach in real cases. With the analysis of the results, it is possible to understand how the joint inversion can reduce the ambiguity of the methods.

A-10/TF34 Turbine Engine Monitoring System (TEMS)

Science.gov (United States)

Christopher, R. G.

1981-01-01

The hardware and software development of the A-10/TF34 turbine engine monitoring system (TEMS) is described. The operation and interfaces of the A-10/TF34 TEMS hardware are discussed with particular emphasis on function, capabilities, and limitations. The TEMS data types are defined and the various data acquisition modes are explained. Potential data products are also discussed.

Customizable in situ TEM devices fabricated in freestanding membranes by focused ion beam milling

International Nuclear Information System (INIS)

Lei, Anders; Petersen, Dirch Hjorth; Booth, Timothy John; Homann, Lasse Vinther; Kallesoe, Christian; Sukas, Ozlem Sardan; Molhave, Kristian; Boggild, Peter; Gyrsting, Yvonne

2010-01-01

Nano- and microelectromechanical structures for in situ operation in a transmission electron microscope (TEM) were fabricated with a turnaround time of 20 min and a resolution better than 100 nm. The structures are defined by focused ion beam (FIB) milling in 135 nm thin membranes of single crystalline silicon extending over the edge of a pre-fabricated silicon microchip. Four-terminal resistance measurements of FIB-defined nanowires showed at least two orders of magnitude increase in resistivity compared to bulk. We show that the initial high resistance is due to amorphization of silicon, and that current annealing recrystallizes the structure, causing the electrical properties to partly recover to the pristine bulk resistivity. In situ imaging of the annealing process revealed both continuous and abrupt changes in the crystal structure, accompanied by instant changes of the electrical conductivity. The membrane structures provide a simple way to design electron-transparent nanodevices with high local temperature gradients within the field of view of the TEM, allowing detailed studies of surface diffusion processes. We show two examples of heat-induced coarsening of gold on a narrow freestanding bridge, where local temperature gradients are controlled via the electrical current paths. The separation of device processing into a one-time batch-level fabrication of identical, generic membrane templates, and subsequent device-specific customization by FIB milling, provides unparalleled freedom in device layout combined with very short effective fabrication time. This approach significantly speeds up prototyping of nanodevices such as resonators, actuators, sensors and scanning probes with state-of-art resolution.

Customizable in situ TEM devices fabricated in freestanding membranes by focused ion beam milling

Energy Technology Data Exchange (ETDEWEB)

Lei, Anders; Petersen, Dirch Hjorth; Booth, Timothy John; Homann, Lasse Vinther; Kallesoe, Christian; Sukas, Ozlem Sardan; Molhave, Kristian; Boggild, Peter [DTU Nanotech, Department of Nano- and Microtechnology, Technical University of Denmark, DK-2800 Kongens Lyngby (Denmark); Gyrsting, Yvonne, E-mail: Anders.Lei@nanotech.dtu.dk [DTU Danchip, National Center for Micro- and Nanofabrication, Technical University of Denmark, DK-2800 Kongens Lyngby (Denmark)

2010-10-08

Nano- and microelectromechanical structures for in situ operation in a transmission electron microscope (TEM) were fabricated with a turnaround time of 20 min and a resolution better than 100 nm. The structures are defined by focused ion beam (FIB) milling in 135 nm thin membranes of single crystalline silicon extending over the edge of a pre-fabricated silicon microchip. Four-terminal resistance measurements of FIB-defined nanowires showed at least two orders of magnitude increase in resistivity compared to bulk. We show that the initial high resistance is due to amorphization of silicon, and that current annealing recrystallizes the structure, causing the electrical properties to partly recover to the pristine bulk resistivity. In situ imaging of the annealing process revealed both continuous and abrupt changes in the crystal structure, accompanied by instant changes of the electrical conductivity. The membrane structures provide a simple way to design electron-transparent nanodevices with high local temperature gradients within the field of view of the TEM, allowing detailed studies of surface diffusion processes. We show two examples of heat-induced coarsening of gold on a narrow freestanding bridge, where local temperature gradients are controlled via the electrical current paths. The separation of device processing into a one-time batch-level fabrication of identical, generic membrane templates, and subsequent device-specific customization by FIB milling, provides unparalleled freedom in device layout combined with very short effective fabrication time. This approach significantly speeds up prototyping of nanodevices such as resonators, actuators, sensors and scanning probes with state-of-art resolution.

Destructive interference of TEM and ITG turbulence

International Nuclear Information System (INIS)

Merz, F.; Jenko, F.

2009-01-01

Full text: Turbulence driven by ion temperature gradient (ITG) modes and trapped electron modes (TEMs) is generally considered the key mechanism for anomalous transport in fusion devices on ion scales. But while pure ITG and, to a lesser extent, also pure TEM turbulence have been studied in detail over the last years, not much is presently known about nonlinear interactions between ITG modes and TEMs, which are often present simultaneously in experimentally relevant situations. This important issue is addressed by means of linear and nonlinear gyrokinetic simulations with the GENE code. To examine the properties of the (linear) TEM and ITG instabilities in the (realistic) transitional regime, the GENE code is run as eigenvalue solver, which allows for a systematic study of dominant and subdominant modes. Corresponding nonlinear initial value computations show that the particle transport of the turbulent system can be completely suppressed if the two driving instabilities are active simultaneously. The direct comparison of the linear modes and the corresponding turbulent system reveals a coexistence of the two microinstabilities in a transitional regime even at the same wave number. The consequences of this dual turbulence drive for transport modeling is discussed. (author)

TEM-turbulence in stellarators and its optimization

Science.gov (United States)

Proll, Josefine H. E.; Helander, Per; Lazerson, Samuel; Mynick, Harry; Xanthopoulos, Pavlos

2014-10-01

Quasi-isodynamic stellarators, which are especially optimized for neoclassical transport, have been shown to be resilient towards trapped-electrons modes (TEMs) in large regions of parameter space. In these configurations, all particles have average ``good curvature.'' It was shown analytically that, thanks to this property, particles that bounce faster than the mode in question draw energy from it near marginal stability, so that the ordinary density-gradient-driven TEM has to be stable in the electrostatic and collisionless limit.This has been confirmed in linear flux-tube simulations that were performed with the GENE code. Several magnetic field configurations were compared and it was found that the growth rates of the TEMs drop with increasing degree of quasi-isodynamicity. These findings can be used to optimize stellarators with respect to TEM turbulence by reducing the fraction of trapped particles with bounce averaged ``bad curvature.'' An appropriate proxy function has therefore been designed to be implemented in STELLOPT, a stellarator optimization tool that can now be used to further explore the configuration space of neoclassically optimized stellarators with the aim to extract designs with improved turbulent transport. This work was facilitated by the Max-Planck/Princeton Center for Plasma Physics.

In-situ TEM Studies : Heat-treatment and Corrosion

NARCIS (Netherlands)

Malladi, S.R.K.

2014-01-01

Transmission electron microscopy (TEM) has been well known as a powerful characterisation tool to understand the structure and composition of various materials down to the atomic level. Over the years, several TEM studies have been carried out to understand the compositional, structural and

Indications and techniques of transanal endoscopic microsurgery (TEMS).

Science.gov (United States)

Qi, Yanjie; Stoddard, David; Monson, John R T

2011-08-01

Transanal endoscopic microsurgery (TEMS) has recently reemerged as a valuable technique for the management of rectal neoplasms - both benign and malignant. Since the original description of this technique in the early 1980s, TEMS has emerged as the approach of choice for most benign rectal tumors because of the excellent views provided and superior dissection techniques possible when compared to traditional transanal excision. Many published reports demonstrate that the lowest rates of recurrence are associated with TEMS probably because of full-thickness excision with negative margins. Increasingly, TEMS is being applied to primary rectal cancer when used alone as a full-thickness excision alone or in combination with additional therapies, depending on tumor stage. There is now a significant evidence base to suggest that this approach should be considered as part of a multidisciplinary approach to rectal cancer. This paper describes indications and techniques for this technology.

TEM characterization of catalyst- and mask-free grown GaN nanorods

International Nuclear Information System (INIS)

Schowalter, M; Aschenbrenner, T; Kruse, C; Hommel, D; Rosenauer, A

2010-01-01

Catalyst- and mask-free grown GaN nanorods have been investigated using transmission electron microscopy (TEM), scanning transmission electron microscopy (STEM) and energy filtered transmission electron microscopy (EFTEM). The nanorods were grown on nitridated r-plane sapphire substrates in a molecular beam epitaxy reactor. We investigated samples directly after the nitridation and after the overgrowth of the structure with GaN. High resolution transmission electron microscopy (HRTEM) and EFTEM revealed that AlN islands have formed due to nitridation. After overgrowth, the AlN islands could not be observed any more, neither by EFTEM nor by Z-contrast imaging. Instead, a smooth layer consisting of AlGaN was found. The investigation of the overgrown sample revealed that an a-plane GaN layer and GaN nanorods on top of the a-plane GaN have formed. The nanorods reduced from top of the a-plane GaN towards the a-plane GaN/sapphire interface suggesting that the nanorods originate at the AlN islands found after nitridation. However, this could not be shown unambiguously. The number of threading dislocations in the nanorods was very low. The analysis of the epitaxial relationship to the a-plane GaN showed that the nanorods grew along the [000-1] direction, and the [1-100] direction of the rods was parallel to the [0001] direction of the a-plane GaN.

Automated transmission-mode scanning electron microscopy (tSEM for large volume analysis at nanoscale resolution.

Directory of Open Access Journals (Sweden)

Masaaki Kuwajima

Full Text Available Transmission-mode scanning electron microscopy (tSEM on a field emission SEM platform was developed for efficient and cost-effective imaging of circuit-scale volumes from brain at nanoscale resolution. Image area was maximized while optimizing the resolution and dynamic range necessary for discriminating key subcellular structures, such as small axonal, dendritic and glial processes, synapses, smooth endoplasmic reticulum, vesicles, microtubules, polyribosomes, and endosomes which are critical for neuronal function. Individual image fields from the tSEM system were up to 4,295 µm(2 (65.54 µm per side at 2 nm pixel size, contrasting with image fields from a modern transmission electron microscope (TEM system, which were only 66.59 µm(2 (8.160 µm per side at the same pixel size. The tSEM produced outstanding images and had reduced distortion and drift relative to TEM. Automated stage and scan control in tSEM easily provided unattended serial section imaging and montaging. Lens and scan properties on both TEM and SEM platforms revealed no significant nonlinear distortions within a central field of ∼100 µm(2 and produced near-perfect image registration across serial sections using the computational elastic alignment tool in Fiji/TrakEM2 software, and reliable geometric measurements from RECONSTRUCT™ or Fiji/TrakEM2 software. Axial resolution limits the analysis of small structures contained within a section (∼45 nm. Since this new tSEM is non-destructive, objects within a section can be explored at finer axial resolution in TEM tomography with current methods. Future development of tSEM tomography promises thinner axial resolution producing nearly isotropic voxels and should provide within-section analyses of structures without changing platforms. Brain was the test system given our interest in synaptic connectivity and plasticity; however, the new tSEM system is readily applicable to other biological systems.

A high-resolution and observationally constrained OMI NO2 satellite retrieval

International Nuclear Information System (INIS)

Goldberg, Daniel L.; Lamsal, Lok N.; Loughner, Christopher P.

2017-01-01

Here, this work presents a new high-resolution NO 2 dataset derived from the NASA Ozone Monitoring Instrument (OMI) NO 2 version 3.0 retrieval that can be used to estimate surface-level concentrations. The standard NASA product uses NO 2 vertical profile shape factors from a 1.25° × 1° (~110 km × 110 km) resolution Global Model Initiative (GMI) model simulation to calculate air mass factors, a critical value used to determine observed tropospheric NO 2 vertical columns. To better estimate vertical profile shape factors, we use a high-resolution (1.33 km × 1.33 km) Community Multi-scale Air Quality (CMAQ) model simulation constrained by in situ aircraft observations to recalculate tropospheric air mass factors and tropospheric NO 2 vertical columns during summertime in the eastern US. In this new product, OMI NO 2 tropospheric columns increase by up to 160% in city centers and decrease by 20–50 % in the rural areas outside of urban areas when compared to the operational NASA product. Our new product shows much better agreement with the Pandora NO 2 and Airborne Compact Atmospheric Mapper (ACAM) NO 2 spectrometer measurements acquired during the DISCOVER-AQ Maryland field campaign. Furthermore, the correlation between our satellite product and EPA NO 2 monitors in urban areas has improved dramatically: r 2 = 0.60 in the new product vs. r 2 = 0.39 in the operational product, signifying that this new product is a better indicator of surface concentrations than the operational product. Our work emphasizes the need to use both high-resolution and high-fidelity models in order to recalculate satellite data in areas with large spatial heterogeneities in NO x emissions. Although the current work is focused on the eastern US, the methodology developed in this work can be applied to other world regions to produce high-quality region-specific NO 2 satellite retrievals.

Preparation of carbon-free TEM microgrids by metal sputtering

International Nuclear Information System (INIS)

Janbroers, S.; Kruijff, T.R. de; Xu, Q.; Kooyman, P.J.; Zandbergen, H.W.

2009-01-01

A new method for preparing carbon-free, temperature-stable Transmission Electron Microscope (TEM) grids is presented. An 80% Au/20% Pd metal film is deposited onto a 'holey' microgrid carbon supported on standard mixed-mesh Au TEM grids. Subsequently, the carbon film is selectively removed using plasma cleaning. In this way, an all-metal TEM film is made containing the 'same' microgrid as the original carbon film. Although electron transparency of the foil is reduced significantly, the open areas for TEM inspection of material over these areas are maintained. The metal foil can be prepared with various thicknesses and ensures good electrical conductivity. The new Au/Pd grids are stable to at least 775 K under vacuum conditions.

Preparation of carbon-free TEM microgrids by metal sputtering.

Science.gov (United States)

Janbroers, S; de Kruijff, T R; Xu, Q; Kooyman, P J; Zandbergen, H W

2009-08-01

A new method for preparing carbon-free, temperature-stable Transmission Electron Microscope (TEM) grids is presented. An 80% Au/20% Pd metal film is deposited onto a 'holey' microgrid carbon supported on standard mixed-mesh Au TEM grids. Subsequently, the carbon film is selectively removed using plasma cleaning. In this way, an all-metal TEM film is made containing the 'same' microgrid as the original carbon film. Although electron transparency of the foil is reduced significantly, the open areas for TEM inspection of material over these areas are maintained. The metal foil can be prepared with various thicknesses and ensures good electrical conductivity. The new Au/Pd grids are stable to at least 775K under vacuum conditions.

ToTem: a tool for variant calling pipeline optimization.

Science.gov (United States)

Tom, Nikola; Tom, Ondrej; Malcikova, Jitka; Pavlova, Sarka; Kubesova, Blanka; Rausch, Tobias; Kolarik, Miroslav; Benes, Vladimir; Bystry, Vojtech; Pospisilova, Sarka

2018-06-26

High-throughput bioinformatics analyses of next generation sequencing (NGS) data often require challenging pipeline optimization. The key problem is choosing appropriate tools and selecting the best parameters for optimal precision and recall. Here we introduce ToTem, a tool for automated pipeline optimization. ToTem is a stand-alone web application with a comprehensive graphical user interface (GUI). ToTem is written in Java and PHP with an underlying connection to a MySQL database. Its primary role is to automatically generate, execute and benchmark different variant calling pipeline settings. Our tool allows an analysis to be started from any level of the process and with the possibility of plugging almost any tool or code. To prevent an over-fitting of pipeline parameters, ToTem ensures the reproducibility of these by using cross validation techniques that penalize the final precision, recall and F-measure. The results are interpreted as interactive graphs and tables allowing an optimal pipeline to be selected, based on the user's priorities. Using ToTem, we were able to optimize somatic variant calling from ultra-deep targeted gene sequencing (TGS) data and germline variant detection in whole genome sequencing (WGS) data. ToTem is a tool for automated pipeline optimization which is freely available as a web application at  https://totem.software .

EELS signal enhancement by means of beam precession in the TEM

International Nuclear Information System (INIS)

Estradé, Sonia; Portillo, Joaquim; Yedra, Lluís; Rebled, José Manuel; Peiró, Francesca

2012-01-01

EELS is nowadays a most relevant characterization tool as it provides chemical and electronic information with an extraordinary spatial resolution. When a crystal is viewed in zone axis in the TEM, there is channelling of the electrons along the atom columns, which strongly reduce the EELS signal, so that it is generally advised to work slightly off the zone axis to collect EELS data, which may not always be possible or advantageous. In the present work, we demonstrate the use of precession to compensate for the reduction of EELS signal when in the zone axis. -- Highlights: ► Channelling compromises EELS signal in zone axis. ► Precession can be used to get rid of channelling effects. ► Use of precession to enhance EELS signal in the zone axis is demonstrated.

Comparison between measured and predicted turbulence frequency spectra in ITG and TEM regimes

NARCIS (Netherlands)

Citrin, J.; Arnichand, H.; Bernardo, J.; Bourdelle, C.; Garbet, X.; Jenko, F.; Hacquin, S.; Puschel, M. J.; Sabot, R.

2017-01-01

The observation of distinct peaks in tokamak core reflectometry measurements—named quasi-coherent-modes (QCMs)—are identified as a signature of trapped-electron-mode (TEM) turbulence (Arnichand et al 2016 Plasma Phys. Control. Fusion 58 014037). This phenomenon is investigated with detailed linear

In Situ High-Resolution Transmission Electron Microscopy (TEM) Observation of Sn Nanoparticles on SnO2 Nanotubes Under Lithiation.

Science.gov (United States)

Cheong, Jun Young; Chang, Joon Ha; Kim, Sung Joo; Kim, Chanhoon; Seo, Hyeon Kook; Shin, Jae Won; Yuk, Jong Min; Lee, Jeong Yong; Kim, Il-Doo

2017-12-01

We trace Sn nanoparticles (NPs) produced from SnO2 nanotubes (NTs) during lithiation initialized by high energy e-beam irradiation. The growth dynamics of Sn NPs is visualized in liquid electrolytes by graphene liquid cell transmission electron microscopy. The observation reveals that Sn NPs grow on the surface of SnO2 NTs via coalescence and the final shape of agglomerated NPs is governed by surface energy of the Sn NPs and the interfacial energy between Sn NPs and SnO2 NTs. Our result will likely benefit more rational material design of the ideal interface for facile ion insertion.

Preparation of carbon-free TEM microgrids by metal sputtering

Energy Technology Data Exchange (ETDEWEB)

Janbroers, S., E-mail: stephan.janbroers@albemarle.com [Albemarle Catalysts B.V., Nieuwendammerkade 1-3, 1030 BE, Amsterdam (Netherlands); Kavli Institute of Nanoscience, Delft University of Technology, Lorentzweg 1, 2628 CJ Delft (Netherlands); Kruijff, T.R. de; Xu, Q. [Kavli Institute of Nanoscience, Delft University of Technology, Lorentzweg 1, 2628 CJ Delft (Netherlands); Kooyman, P.J. [DelftChemTech, Delft University of Technology, Julianalaan 136, 2628 BL, Delft (Netherlands); Kavli Institute of Nanoscience, Delft University of Technology, Lorentzweg 1, 2628 CJ Delft (Netherlands); Zandbergen, H.W. [Kavli Institute of Nanoscience, Delft University of Technology, Lorentzweg 1, 2628 CJ Delft (Netherlands)

2009-08-15

A new method for preparing carbon-free, temperature-stable Transmission Electron Microscope (TEM) grids is presented. An 80% Au/20% Pd metal film is deposited onto a 'holey' microgrid carbon supported on standard mixed-mesh Au TEM grids. Subsequently, the carbon film is selectively removed using plasma cleaning. In this way, an all-metal TEM film is made containing the 'same' microgrid as the original carbon film. Although electron transparency of the foil is reduced significantly, the open areas for TEM inspection of material over these areas are maintained. The metal foil can be prepared with various thicknesses and ensures good electrical conductivity. The new Au/Pd grids are stable to at least 775 K under vacuum conditions.

Regulation of ETG turbulence by TEM driven zonal flows

Science.gov (United States)

Asahi, Yuuichi; Ishizawa, Akihiro; Watanabe, Tomohiko; Tsutsui, Hiroaki; Tsuji-Iio, Shunji

2013-10-01

Anomalous heat transport driven by electron temperature gradient (ETG) turbulence is investigated by means of gyrokinetic simulations. It is found that the ETG turbulence can be suppressed by zonal flows driven by trapped electron modes (TEMs). The TEMs appear in a statistically steady state of ETG turbulence and generate zonal flows, while its growth rate is much smaller than those of ETGs. The TEM-driven zonal flows with lower radial wave numbers are more strongly generated than those driven by ETG modes, because of the higher zonal flow response to a density source term. An ExB shearing rate of the TEM-driven zonal flows is strong enough to suppress the long-wavelength ETG modes which make the main contribution to the turbulent transport.

3D TEM reconstruction and segmentation process of laminar bio-nanocomposites

International Nuclear Information System (INIS)

Iturrondobeitia, M.; Okariz, A.; Fernandez-Martinez, R.; Jimbert, P.; Guraya, T.; Ibarretxe, J.

2015-01-01

The microstructure of laminar bio-nanocomposites (Poly (lactic acid)(PLA)/clay) depends on the amount of clay platelet opening after integration with the polymer matrix and determines the final properties of the material. Transmission electron microscopy (TEM) technique is the only one that can provide a direct observation of the layer dispersion and the degree of exfoliation. However, the orientation of the clay platelets, which affects the final properties, is practically immeasurable from a single 2D TEM image. This issue can be overcome using transmission electron tomography (ET), a technique that allows the complete 3D characterization of the structure, including the measurement of the orientation of clay platelets, their morphology and their 3D distribution. ET involves a 3D reconstruction of the study volume and a subsequent segmentation of the study object. Currently, accurate segmentation is performed manually, which is inefficient and tedious. The aim of this work is to propose an objective/automated segmentation methodology process of a 3D TEM tomography reconstruction. In this method the segmentation threshold is optimized by minimizing the variation of the dimensions of the segmented objects and matching the segmented V clay (%) and the actual one. The method is first validated using a fictitious set of objects, and then applied on a nanocomposite

Megapixel Longwave Infrared SLS FPAs for High Spatial Resolution Earth Observing Missions, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — Earth observing missions like NASA's LANDSAT Data Continuity Mission - Thermal Infrared Sensor (LDCM-TIRS) require greater spatial resolution of the earth than the ~...

Megapixel Longwave Infrared SLS FPAs for High Spatial Resolution Earth Observing Missions, Phase II

Data.gov (United States)

National Aeronautics and Space Administration — Earth observing missions like NASA's LANDSAT Data Continuity Mission - Thermal Infrared Sensor (LDCM-TIRS) require greater spatial resolution of the earth than the ~...

Retrofit implementation of Zernike phase plate imaging for cryo-TEM.

Science.gov (United States)

Marko, Michael; Leith, Ardean; Hsieh, Chyongere; Danev, Radostin

2011-05-01

In-focus phase-plate imaging is particularly beneficial for cryo-TEM because it offers a substantial overall increase in image contrast, without an electron dose penalty, and it simplifies image interpretation. We show how phase-plate cryo-TEM can be implemented with an appropriate existing TEM, and provide a basic practical introduction to use of thin-film (carbon) phase plates. We point out potential pitfalls of phase-plate operation, and discuss solutions. We provide information on evaluating a particular TEM for its suitability. Copyright © 2011 Elsevier Inc. All rights reserved.

Experimental study on propagation properties of large size TEM antennas

International Nuclear Information System (INIS)

Zhang Guowei; Wang Haiyang; Chen Weiqing; Wang Wei; Zhu Xiangqin; Xie Linshen

2014-01-01

The propagation properties of large size TEM antennas were studied by experiment. The size of the TEM antennas is 60 m × 20 m × 10 m and the character Impedance is 120 Ω. A kind of dielectric foil switch is designed compactly with TEM antennas which can generate double exponential waveform with altitude of 10 kV and rise time of l.2 ns. The radiated field distribution was measured. The relationship between rise time/altitude and distance were provided, and the propagation properties of large size TEM antennas were summarized. (authors)

Accurate Mass Measurements for Planetary Microlensing Events Using High Angular Resolution Observations

Directory of Open Access Journals (Sweden)

Jean-Philippe Beaulieu

2018-04-01

Full Text Available The microlensing technique is a unique method to hunt for cold planets over a range of mass and separation, orbiting all varieties of host stars in the disk of our galaxy. It provides precise mass-ratio and projected separations in units of the Einstein ring radius. In order to obtain the physical parameters (mass, distance, orbital separation of the system, it is necessary to combine the result of light curve modeling with lens mass-distance relations and/or perform a Bayesian analysis with a galactic model. A first mass-distance relation could be obtained from a constraint on the Einstein ring radius if the crossing time of the source over the caustic is measured. It could then be supplemented by secondary constraints such as parallax measurements, ideally by using coinciding ground and space-born observations. These are still subject to degeneracies, like the orbital motion of the lens. A third mass-distance relation can be obtained thanks to constraints on the lens luminosity using high angular resolution observations with 8 m class telescopes or the Hubble Space Telescope. The latter route, although quite inexpensive in telescope time is very effective. If we have to rely heavily on Bayesian analysis and limited constraints on mass-distance relations, the physical parameters are determined to 30–40% typically. In a handful of cases, ground-space parallax is a powerful route to get stronger constraint on masses. High angular resolution observations will be able to constrain the luminosity of the lenses in the majority of the cases, and in favorable circumstances it is possible to derive physical parameters to 10% or better. Moreover, these constraints will be obtained in most of the planets to be discovered by the Euclid and WFIRST satellites. We describe here the state-of-the-art approaches to measure lens masses and distances with an emphasis on high angular resolution observations. We will discuss the challenges, recent results and

Design of the high resolution optical instrument for the Pleiades HR Earth observation satellites

Science.gov (United States)

Lamard, Jean-Luc; Gaudin-Delrieu, Catherine; Valentini, David; Renard, Christophe; Tournier, Thierry; Laherrere, Jean-Marc

2017-11-01

As part of its contribution to Earth observation from space, ALCATEL SPACE designed, built and tested the High Resolution cameras for the European intelligence satellites HELIOS I and II. Through these programmes, ALCATEL SPACE enjoys an international reputation. Its capability and experience in High Resolution instrumentation is recognised by the most customers. Coming after the SPOT program, it was decided to go ahead with the PLEIADES HR program. PLEIADES HR is the optical high resolution component of a larger optical and radar multi-sensors system : ORFEO, which is developed in cooperation between France and Italy for dual Civilian and Defense use. ALCATEL SPACE has been entrusted by CNES with the development of the high resolution camera of the Earth observation satellites PLEIADES HR. The first optical satellite of the PLEIADES HR constellation will be launched in mid-2008, the second will follow in 2009. To minimize the development costs, a mini satellite approach has been selected, leading to a compact concept for the camera design. The paper describes the design and performance budgets of this novel high resolution and large field of view optical instrument with emphasis on the technological features. This new generation of camera represents a breakthrough in comparison with the previous SPOT cameras owing to a significant step in on-ground resolution, which approaches the capabilities of aerial photography. Recent advances in detector technology, optical fabrication and electronics make it possible for the PLEIADES HR camera to achieve their image quality performance goals while staying within weight and size restrictions normally considered suitable only for much lower performance systems. This camera design delivers superior performance using an innovative low power, low mass, scalable architecture, which provides a versatile approach for a variety of imaging requirements and allows for a wide number of possibilities of accommodation with a mini

A hard x-ray spectrometer for high angular resolution observations of cosmic sources

International Nuclear Information System (INIS)

Hailey, C.J.; Ziock, K.P.; Harrison, F.; Kahn, S.M.; Liedahl, D.; Lubin, P.M.; Seiffert, M.

1988-01-01

LAXRIS (large area x-ray imaging spectrometer) is an experimental, balloon-borne, hard x-ray telescope that consists of a coaligned array of x-ray imaging spectrometer modules capable of obtaining high angular resolution (1--3 arcminutes) with moderate energy resolution in the 20- to 300-keV region. Each spectrometer module consists of a CsI(Na) crystal coupled to a position-sensitive phototube with a crossed-wire, resistive readout. Imaging is provided by a coded aperture mask with a 4-m focal length. The high angular resolution is coupled with rather large area (/approximately/800 cm 2 ) to provide good sensitivity. Results are presented on performance and overall design. Sensitivity estimates are derived from a Monte-Carlo code developed to model the LAXRIS response to background encountered at balloon altitudes. We discuss a variety of observations made feasible by high angular resolution. For instance, spatially resolving the nonthermal x-ray emission from clusters of galaxies is suggested as an ideal program for LAXRIS. 15 refs., 5 figs

High resolution microstructure characterization of the interface between cold sprayed Al coating and Mg alloy substrate

International Nuclear Information System (INIS)

Wang, Qiang; Qiu, Dong; Xiong, Yuming; Birbilis, Nick; Zhang, Ming-Xing

2014-01-01

High-resolution transmission electron microscopy (HR-TEM) has validated the intimate metallurgical (atomic) bond formed along the interface of a cold-sprayed Al coating upon an Mg-alloy (AZ91) substrate. The compressive impact led to the formation of nanostructured layers of about 300–500 nm into the substrate. A highly distorted lattice structure with the inclusion of small amorphous zones was observed at the periphery of the particle/substrate interface, as a result of adiabatic shear plastic deformation at a high strain rate.

TEM in situ micropillar compression tests of ion irradiated oxide dispersion strengthened alloy

Energy Technology Data Exchange (ETDEWEB)

Yano, K.H., E-mail: kaylayano@u.boisestate.edu [Boise State University, 1910 University Drive, Boise, ID, 83725 (United States); Swenson, M.J. [Boise State University, 1910 University Drive, Boise, ID, 83725 (United States); Wu, Y. [Boise State University, 1910 University Drive, Boise, ID, 83725 (United States); Center for Advanced Energy Studies, 995 University Blvd, Idaho Falls, ID, 83401 (United States); Wharry, J.P. [Boise State University, 1910 University Drive, Boise, ID, 83725 (United States); Purdue University, 400 Central Drive, West Lafayette, IN 47907 (United States)

2017-01-15

The growing role of charged particle irradiation in the evaluation of nuclear reactor candidate materials requires the development of novel methods to assess mechanical properties in near-surface irradiation damage layers just a few micrometers thick. In situ transmission electron microscopic (TEM) mechanical testing is one such promising method. In this work, microcompression pillars are fabricated from a Fe{sup 2+} ion irradiated bulk specimen of a model Fe-9%Cr oxide dispersion strengthened (ODS) alloy. Yield strengths measured directly from TEM in situ compression tests are within expected values, and are consistent with predictions based on the irradiated microstructure. Measured elastic modulus values, once adjusted for the amount of deformation and deflection in the base material, are also within the expected range. A pillar size effect is only observed in samples with minimum dimension ≤100 nm due to the low inter-obstacle spacing in the as received and irradiated material. TEM in situ micropillar compression tests hold great promise for quantitatively determining mechanical properties of shallow ion-irradiated layers.

High resolution radio observations of nuclear and circumnuclear regions of luminous infrared galaxies (LIRGs)

Energy Technology Data Exchange (ETDEWEB)

Alberdi, A; Perez-Torres, M A [Instituto de Astrofisica de Andalucia (IAA, CSIC), PO Box 3004, 18080-Granada (Spain); Colina, L [Instituto de Estructura de la Materia - IEM, CSIC, C, Serrano 115, 28005 Madrid (Spain); Torrelles, J M [Instituto de Ciencias del Espacio (ICE, CSIC) and IEEC, Gran Capita 2-4, 08034 Barcelona (Spain)], E-mail: antxon@iaa.es, E-mail: torres@iaa.es, E-mail: colina@damir.iem.csic.es, E-mail: torrelle@ieec.fcr.es

2008-10-15

High-resolution radio observations of the nuclear region of Luminous and Ultraluminous Infrared Galaxies (ULIRGs) have shown that its radio structure consists of a compact high surface-brightness central radio source immersed in a diffuse low brightness circumnuclear halo. While the central component could be associated with an AGN or compact star-forming regions where radio supernovae are exploding, it is well known that the circumnuclear regions host bursts of star-formation. The studies of radio supernovae can provide essential information about stellar evolution and CSM/ISM properties in regions hidden by dust at optical and IR wavelengths. In this contribution, we show results from radio interferometric observations from NGC 7469, IRAS 18293-3413 and IRAS 17138-1017 where three extremely bright radio supernovae have been found. High-resolution radio observations of these and other LIRGs would allow us to determine the core-collapse supernova rate in them as well as their star-formation rate.

Microstructural studies of 35 degrees C copper Ni-Ti orthodontic wire and TEM confirmation of low-temperature martensite transformation.

Science.gov (United States)

Brantley, William A; Guo, Wenhua; Clark, William A T; Iijima, Masahiro

2008-02-01

Previous temperature-modulated differential scanning calorimetry (TMDSC) study of nickel-titanium orthodontic wires revealed a large exothermic low-temperature peak that was attributed to transformation within martensitic NiTi. The purpose of this study was to use transmission electron microscopy (TEM) to verify this phase transformation in a clinically popular nickel-titanium wire, identify its mechanism and confirm other phase transformations found by TMDSC, and to provide detailed information about the microstructure of this wire. The 35 degrees C Copper nickel-titanium wire (Ormco) with cross-section dimensions of 0.016 in. x 0.022 in. used in the earlier TMDSC investigation was selected. Foils were prepared for TEM analyses by mechanical grinding, polishing, dimpling, ion milling and plasma cleaning. Standard bright-field and dark-field TEM images were obtained, along with convergent-beam electron diffraction patterns. A cryo-stage with the electron microscope (Phillips CM 200) permitted the specimen to be observed at -187, -45, and 50 degrees C, as well as at room temperature. Microstructures were also observed with an optical microscope and a scanning electron microscope. Room temperature microstructures had randomly oriented, elongated grains that were twinned. Electron diffraction patterns confirmed that phase transformations took place over temperature ranges previously found by TMDSC. TEM observations revealed a high dislocation density and fine-scale oxide particles, and that twinning is the mechanism for the low-temperature transformation in martensitic NiTi. TEM confirmed the low-temperature peak and other phase transformations observed by TMDSC, and revealed that twinning in martensite is the mechanism for the low-temperature peak. The high dislocation density and fine-scale oxide particles in the microstructure are the result of the wire manufacturing process.

HIGH ANGULAR RESOLUTION OBSERVATIONS OF FOUR CANDIDATE BLAST HIGH-MASS STARLESS CORES

International Nuclear Information System (INIS)

Olmi, Luca; Poventud, Carlos M.; Araya, Esteban D.; Chapin, Edward L.; Gibb, Andrew; Hofner, Peter; Martin, Peter G.

2010-01-01

We discuss high angular resolution observations of ammonia toward four candidate high-mass starless cores (HMSCs). The cores were identified by the Balloon-borne Large Aperture Submillimeter Telescope (BLAST) during its 2005 survey of the Vulpecula region where 60 compact sources were detected simultaneously at 250, 350, and 500 μm. Four of these cores, with no IRAS-PSC or MSX counterparts, were mapped with the NRAO Very Large Array and observed with the Effelsberg 100 m telescope in the NH 3 (1,1) and (2,2) spectral lines. Our observations indicate that the four cores are cold (T k -1 . The four BLAST cores appear to be colder and more quiescent than other previously observed HMSC candidates, suggesting an earlier stage of evolution.

A detailed TEM and SEM study of Ni-base alloys oxide scales formed in primary conditions of pressurized water reactor

International Nuclear Information System (INIS)

Sennour, Mohamed; Marchetti, Loic; Martin, Frantz; Perrin, Stephane; Molins, Regine; Pijolat, Michele

2010-01-01

The oxide film formed on nickel-based alloys in pressurized water reactors (PWR) primary coolant conditions (325 o C, aqueous media) is very thin, in the range of 1-100 nm thick, depending on the surface state and on the corrosion test duration. The nature and the structure of this scale have been investigated by Transmission Electron Microscopy (TEM) and Scanning Electron Microscopy (SEM). TEM observations revealed an oxide layer divided in two parts. The internal layer was mainly composed of a continuous spinel layer, identified as a mixed iron and nickel chromite (Ni (1-x) Fe x Cr 2 O 4 ). Moreover, nodules of Cr 2 O 3 , with a size about 5 nm, were present at the interface between this spinel and the alloy. No chromium depletion was observed in the alloy, at the alloy/oxide interface. The external layer is composed of large crystallites corresponding to a spinel structure rich in iron (Ni (1-z) Fe (2+z) O 4 ) resulting from precipitation phenomena. SEM and TEM observations showed a link between the nucleation and/or the growth of crystallites of nickel ferrite and the crystallographic orientation of the substrate. A link between the presence of surface defects and the nucleation of the crystallites was also underlined by SEM observations. Partially hydrated nickel hydroxide, was also observed by TEM in the external scale. Based on these results, some considerations about the mechanism of formation of this oxide layer are discussed.

Structure and chemistry of epitaxial ceria thin films on yttria-stabilized zirconia substrates, studied by high resolution electron microscopy

Energy Technology Data Exchange (ETDEWEB)

Sinclair, Robert, E-mail: bobsinc@stanford.edu [Department of Materials Science and Engineering, Stanford University, Stanford, CA 94305 (United States); Lee, Sang Chul, E-mail: sclee99@stanford.edu [Department of Materials Science and Engineering, Stanford University, Stanford, CA 94305 (United States); Shi, Yezhou; Chueh, William C. [Department of Materials Science and Engineering, Stanford University, Stanford, CA 94305 (United States); Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, CA 94025 (United States); Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, Menlo Park, CA 94025 (United States)

2017-05-15

We have applied aberration-corrected transmission electron microscopy (TEM) imaging and electron energy loss spectroscopy (EELS) to study the structure and chemistry of epitaxial ceria thin films, grown by pulsed laser deposition onto (001) yttria-stabilized zirconia (YSZ) substrates. There are few observable defects apart from the expected mismatch interfacial dislocations and so the films would be expected to have good potential for applications. Under high electron beam dose rate (above about 6000 e{sup -}/Å{sup 2}s) domains of an ordered structure appear and these are interpreted as being created by oxygen vacancy ordering. The ordered structure does not appear at lower lose rates (ca. 2600 e{sup -}/Å{sup 2}s) and can be removed by imaging under 1 mbar oxygen gas in an environmental TEM. EELS confirms that there is both oxygen deficiency and the associated increase in Ce{sup 3+} versus Ce{sup 4+} cations in the ordered domains. In situ high resolution TEM recordings show the formation of the ordered domains as well as atomic migration along the ceria thin film (001) surface. - Highlights: • The local structure and chemistry of ceria can be studied by TEM combined with EELS. • At lower electron, there are no observable changes in the ceria thin films. • At higher dose rates, an ordered phase is created due to oxygen vacancy ordering. • In situ HRTEM shows the oxygen vacancy ordering and the movement of surface atoms.

On the structural affinity of macromolecules with different biological properties: Molecular dynamics simulations of a series of TEM-1 mutants

Energy Technology Data Exchange (ETDEWEB)

Giampaolo, Alessia Di [Dipartimento di Scienze Fisiche e Chimiche, Universita’ degli Studi di l’Aquila, Via Vetoio snc, 67100 Coppito (AQ) (Italy); Mazza, Fernando [Department of Health Sciences, Univ. of L’Aquila, 67010 L’Aquila (Italy); Daidone, Isabella [Dipartimento di Scienze Fisiche e Chimiche, Universita’ degli Studi di l’Aquila, Via Vetoio snc, 67100 Coppito (AQ) (Italy); Amicosante, Gianfranco; Perilli, Mariagrazia [Dipartimento di Scienze Cliniche Applicate e Biotecnologiche, Università degli Studi di l’Aquila, Via Vetoio snc, 67100 Coppito (AQ) (Italy); Aschi, Massimiliano, E-mail: massimiliano.aschi@univaq.it [Dipartimento di Scienze Fisiche e Chimiche, Universita’ degli Studi di l’Aquila, Via Vetoio snc, 67100 Coppito (AQ) (Italy)

2013-07-12

Highlights: •We have performed molecular dynamics simulations of TEM-1 mutants. •Mutations effects on the mechanical properties are considered. •Mutants do not significantly alter the average enzymes structure. •Mutants produce sharp alterations in enzyme conformational repertoire. •Mutants also produce changes in the active site volume. -- Abstract: Molecular Dynamics simulations have been carried out in order to provide a molecular rationalization of the biological and thermodynamic differences observed for a class of TEM β-lactamases. In particular we have considered the TEM-1(wt), the single point mutants TEM-40 and TEM-19 representative of IRT and ESBL classes respectively, and TEM-1 mutant M182T, TEM-32 and TEM-20 which differ from the first three for the additional of M182T mutation. Results indicate that most of the thermodynamic, and probably biological behaviour of these systems arise from subtle effects which, starting from the alterations of the local interactions, produce drastic modifications of the conformational space spanned by the enzymes. The present study suggests that systems showing essentially the same secondary and tertiary structure may differentiate their chemical–biological activity essentially (and probably exclusively) on the basis of the thermal fluctuations occurring in their physiological environment.

On the structural affinity of macromolecules with different biological properties: Molecular dynamics simulations of a series of TEM-1 mutants

International Nuclear Information System (INIS)

Giampaolo, Alessia Di; Mazza, Fernando; Daidone, Isabella; Amicosante, Gianfranco; Perilli, Mariagrazia; Aschi, Massimiliano

2013-01-01

Highlights: •We have performed molecular dynamics simulations of TEM-1 mutants. •Mutations effects on the mechanical properties are considered. •Mutants do not significantly alter the average enzymes structure. •Mutants produce sharp alterations in enzyme conformational repertoire. •Mutants also produce changes in the active site volume. -- Abstract: Molecular Dynamics simulations have been carried out in order to provide a molecular rationalization of the biological and thermodynamic differences observed for a class of TEM β-lactamases. In particular we have considered the TEM-1(wt), the single point mutants TEM-40 and TEM-19 representative of IRT and ESBL classes respectively, and TEM-1 mutant M182T, TEM-32 and TEM-20 which differ from the first three for the additional of M182T mutation. Results indicate that most of the thermodynamic, and probably biological behaviour of these systems arise from subtle effects which, starting from the alterations of the local interactions, produce drastic modifications of the conformational space spanned by the enzymes. The present study suggests that systems showing essentially the same secondary and tertiary structure may differentiate their chemical–biological activity essentially (and probably exclusively) on the basis of the thermal fluctuations occurring in their physiological environment

HR-TEM and FT-Raman dataset of the caffeine interacted Phe–Phe peptide nanotube for possible sensing applications

OpenAIRE

Narayanan, A. Lakshmi; Dhamodaran, M.; Solomon, J. Samu; Karthikeyan, B.; Govindhan, R.

2017-01-01

Sensing ability of caffeine interaction with Phe-Phe annotates (PNTs), is presented (Govindhan et al., 2017; Karthikeyan et al., 2014; Tavagnacco et al., 2013; Kennedy et al., 2011; Wang et al., 2017) [1–5] in this data set. Investigation of synthesized caffeine carrying peptide nanotubes are carried out by FT-Raman spectral analysis and high resolution transmission electron microscopy (HR-TEM). Particle size of the caffeine loaded PNTs is < 40 nm. The FT-Raman spectrum signals are enhanced i...

The structure of the ISM in the Zone of Avoidance by high-resolution multi-wavelength observations

Science.gov (United States)

Tóth, L. V.; Doi, Y.; Pinter, S.; Kovács, T.; Zahorecz, S.; Bagoly, Z.; Balázs, L. G.; Horvath, I.; Racz, I. I.; Onishi, T.

2018-05-01

We estimate the column density of the Galactic foreground interstellar medium (GFISM) in the direction of extragalactic sources. All-sky AKARI FIS infrared sky survey data might be used to trace the GFISM with a resolution of 2 arcminutes. The AKARI based GFISM hydrogen column density estimates are compared with similar quantities based on HI 21cm measurements of various resolution and of Planck results. High spatial resolution observations of the GFISM may be important recalculating the physical parameters of gamma-ray burst (GRB) host galaxies using the updated foreground parameters.

Estimating Vegetation Rainfall Interception Using Remote Sensing Observations at Very High Resolution

Science.gov (United States)

Cui, Y.; Zhao, P.; Hong, Y.; Fan, W.; Yan, B.; Xie, H.

2017-12-01

Abstract: As an important compont of evapotranspiration, vegetation rainfall interception is the proportion of gross rainfall that is intercepted, stored and subsequently evaporated from all parts of vegetation during or following rainfall. Accurately quantifying the vegetation rainfall interception at a high resolution is critical for rainfall-runoff modeling and flood forecasting, and is also essential for understanding its further impact on local, regional, and even global water cycle dynamics. In this study, the Remote Sensing-based Gash model (RS-Gash model) is developed based on a modified Gash model for interception loss estimation using remote sensing observations at the regional scale, and has been applied and validated in the upper reach of the Heihe River Basin of China for different types of vegetation. To eliminate the scale error and the effect of mixed pixels, the RS-Gash model is applied at a fine scale of 30 m with the high resolution vegetation area index retrieved by using the unified model of bidirectional reflectance distribution function (BRDF-U) for the vegetation canopy. Field validation shows that the RMSE and R2 of the interception ratio are 3.7% and 0.9, respectively, indicating the model's strong stability and reliability at fine scale. The temporal variation of vegetation rainfall interception loss and its relationship with precipitation are further investigated. In summary, the RS-Gash model has demonstrated its effectiveness and reliability in estimating vegetation rainfall interception. When compared to the coarse resolution results, the application of this model at 30-m fine resolution is necessary to resolve the scaling issues as shown in this study. Keywords: rainfall interception; remote sensing; RS-Gash analytical model; high resolution

Extensive FE-SEM/EDS, HR-TEM/EDS and ToF-SIMS studies of micron- to nano-particles in anthracite fly ash

Energy Technology Data Exchange (ETDEWEB)

Ribeiro, Joana [Centro de Geologia, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); DaBoit, Kátia [Institute of Environmental Research and Human Development, IPADHC, Capivari de Baixo, Santa Catarina (Brazil); Flores, Deolinda [Centro de Geologia, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Departamento de Geociências, Ambiente e Ordenamento do Território, Faculdade de Ciências, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Kronbauer, Marcio A. [Laboratory of Environmental Researches and Nanotechnology Development, Centro Universitário La Salle, Victor Barreto, 2288 Centro 92010-000, Canoas, RS (Brazil); Silva, Luis F.O., E-mail: felipeqma@hotmail.com [Laboratory of Environmental Researches and Nanotechnology Development, Centro Universitário La Salle, Victor Barreto, 2288 Centro 92010-000, Canoas, RS (Brazil); Environmental Science and Nanotechnology Department, Catarinense Institute of Environmental Research and Human Development, IPADHC, Capivari de Baixo, Santa Catarina (Brazil)

2013-05-01

The generation of anthropogenic carbonaceous matter and mixed crystalline/amorphous mineral ultrafine/nano-particles in the 1 to 100 nm size range by worldwide coal power plants represents serious environmental problems due to their potential hazards. Coal fly ash (CFA) that resulted from anthracite combustion in a Portuguese thermal power plant was studied in this work. The physico-chemical characterization of ultrafine/nano-particles present in the CFA samples and their interaction with environment are the aim of this study. The methodologies applied for this work were field emission scanning electron microscopy (FE-SEM) with energy dispersive X-ray spectroscopy (EDS), high-resolution transmission electron microscopy with energy dispersive X-ray spectroscopy (HR-TEM/EDS) and time of flight secondary ion mass spectrometry (ToF-SIMS). Some hazardous volatile elements, C, N, S and Hg contents were also determined in the studied samples. Generally, the CFA samples comprise carbonaceous, glassy and metallic solid spheres with some containing mixed amorphous/crystalline phases. The EDS analysis coupled with the FE-SEM and HR-TEM observations of the fly ash particles with 100 to 0.1 nm demonstrates that these materials contain a small but significant proportion of encapsulated HVEs. In addition, the presence of abundant multi-walled carbon nanotubes (MWCNTs) and amorphous carbon particles, both containing hazardous volatile elements (HVEs), was also evidenced by the FE-SEM/EDS and HR-TEM/EDS analysis. A wide range of organic and inorganic compounds was determined by chemical maps obtained in ToF-SIMS analysis. - Highlights: ► We examine changes in the level of ultrafine and nanoparticles of coal mining. ► Increasing geochemical information will increase human health information in this area. ► Electron bean and Tof-SIMS increase area information.

Sensitivity to grid resolution in the ability of a chemical transport model to simulate observed oxidant chemistry under high-isoprene conditions

Directory of Open Access Journals (Sweden)

K. Yu

2016-04-01

Full Text Available Formation of ozone and organic aerosol in continental atmospheres depends on whether isoprene emitted by vegetation is oxidized by the high-NOx pathway (where peroxy radicals react with NO or by low-NOx pathways (where peroxy radicals react by alternate channels, mostly with HO2. We used mixed layer observations from the SEAC4RS aircraft campaign over the Southeast US to test the ability of the GEOS-Chem chemical transport model at different grid resolutions (0.25°  ×  0.3125°, 2°  ×  2.5°, 4°  ×  5° to simulate this chemistry under high-isoprene, variable-NOx conditions. Observations of isoprene and NOx over the Southeast US show a negative correlation, reflecting the spatial segregation of emissions; this negative correlation is captured in the model at 0.25°  ×  0.3125° resolution but not at coarser resolutions. As a result, less isoprene oxidation takes place by the high-NOx pathway in the model at 0.25°  ×  0.3125° resolution (54 % than at coarser resolution (59 %. The cumulative probability distribution functions (CDFs of NOx, isoprene, and ozone concentrations show little difference across model resolutions and good agreement with observations, while formaldehyde is overestimated at coarse resolution because excessive isoprene oxidation takes place by the high-NOx pathway with high formaldehyde yield. The good agreement of simulated and observed concentration variances implies that smaller-scale non-linearities (urban and power plant plumes are not important on the regional scale. Correlations of simulated vs. observed concentrations do not improve with grid resolution because finer modes of variability are intrinsically more difficult to capture. Higher model resolution leads to decreased conversion of NOx to organic nitrates and increased conversion to nitric acid, with total reactive nitrogen oxides (NOy changing little across model resolutions. Model concentrations in the

Investigation of diversity of plasmids carrying the blaTEM-52 gene

DEFF Research Database (Denmark)

Bielak, Eliza Maria; Bergenholtz, Rikke D.; Jørgensen, Mikael Skaanning

2011-01-01

OBJECTIVES: To investigate the diversity of plasmids that carry blaTEM-52 genes among Escherichia coli and Salmonella enterica originating from animals, meat products and humans. METHODS: A collection of 22 blaTEM-52-encoding plasmids was characterized by restriction fragment length polymorphism...... of self-transfer to a plasmid-free E. coli recipient. CONCLUSIONS: The blaTEM-52 gene found in humans could have been transmitted on transferable plasmids originating from animal sources. Some of the blaTEM-52 plasmids carry replicons that differ from the classical ones. Two novel replicons were detected...

Radiation budget studies using collocated observations from advanced Very High Resolution Radiometer, High-Resolution Infrared Sounder/2, and Earth Radiation Budget Experiment instruments

Science.gov (United States)

Ackerman, Steven A.; Frey, Richard A.; Smith, William L.

1992-01-01

Collocated observations from the Advanced Very High Resolution Radiometer (AVHRR), High-Resolution Infrared Sounder/2 (HIRS/2), and Earth Radiation Budget Experiment (ERBE) instruments onboard the NOAA 9 satellite are combined to describe the broadband and spectral radiative properties of the earth-atmosphere system. Broadband radiative properties are determined from the ERBE observations, while spectral properties are determined from the HIRS/2 and AVHRR observations. The presence of clouds, their areal coverage, and cloud top pressure are determined from a combination of the HIRS/2 and the AVHRR observations. The CO2 slicing method is applied to the HIRS/2 to determine the presence of upper level clouds and their effective emissivity. The AVHRR data collocated within the HIRS/2 field of view are utilized to determine the uniformity of the scene and retrieve sea surface temperature. Changes in the top of the atmosphere longwave and shortwave radiative energy budgets, and the spectral distribution of longwave radiation are presented as a function of cloud amount and cloud top pressure. The radiative characteristics of clear sky conditions over oceans are presented as a function of sea surface temperature and atmospheric water vapor structure.

A Fast Algorithm for Image Super-Resolution from Blurred Observations

Directory of Open Access Journals (Sweden)

Ng Michael K

2006-01-01

Full Text Available We study the problem of reconstruction of a high-resolution image from several blurred low-resolution image frames. The image frames consist of blurred, decimated, and noisy versions of a high-resolution image. The high-resolution image is modeled as a Markov random field (MRF, and a maximum a posteriori (MAP estimation technique is used for the restoration. We show that with the periodic boundary condition, a high-resolution image can be restored efficiently by using fast Fourier transforms. We also apply the preconditioned conjugate gradient method to restore high-resolution images in the aperiodic boundary condition. Computer simulations are given to illustrate the effectiveness of the proposed approach.

TEM and HRTEM of Soot-in-oil particles and agglomerates from internal combustion engines

International Nuclear Information System (INIS)

Fay, M W; Rocca, A La; Shayler, P J

2014-01-01

Over time, the performance of lubricating oil in a diesel engine is affected by the build-up of carbon soot produced by the combustion process. TEM and HRTEM are commonly used to investigate the characteristics of individual and agglomerated particles from diesel exhaust, to understand the structure and distribution of the carbon sheets in the primary particles and the nanostructure morphology. However, high resolution imaging of soot-in-oil is more challenging, as mineral oil is a contaminant for the electron microscope and leads to instability under the electron beam. In this work we compare solvent extraction and centrifugation techniques for removing the mineral oil contaminant, and the effect on particle size distribution

Tem holder for sample transfer under reaction conditions

DEFF Research Database (Denmark)

Damsgaard, Christian Danvad; Zandbergen, Henny W.; Wagner, Jakob Birkedal

Environmental transmission electron microscopy (ETEM) studies are usually performed using conventional sample holders in a dedicated ETEM [1] or in a traditional TEM by use of a dedicated high-pressure cell sample holder [2]. In both cases, the setup defines the conditions regarding gas, pressure......]. Furthermore, dedicated transfer holders have been used to transfer catalyst samples between reactor set-ups and TEM at room temperature in inert atmosphere [5]. To take the full advantage of complementary in situ techniques, transfer under reactions conditions is essential. This study introduces the in situ...... transfer concept by use of a dedicated TEM transfer holder capable of enclosing the sample in a gaseous environment at temperatures up to approx. 900C. By oxidation and reduction experiments of Cu nanoparticles it is shown possible to keep the reaction conditions during transfer outside the microscope...

Molecular identification of TEM-116 beta-lactamase gene in isolates ...

African Journals Online (AJOL)

Keywords: P. aeruginosa, Clinical isolates, Sequencing, TEM-116, Antibiotic susceptibility. Tropical Journal of ... organisms produce a wide range of beta ... TEM-1 is the most commonly encountered beta-lactamase in Gram-negative bacteria.

Coarsening of Pd nanoparticles in an oxidizing atmosphere studied by in situ TEM

DEFF Research Database (Denmark)

Simonsen, Søren Bredmose; Chorkendorff, Ib; Dahl, Søren

2016-01-01

The coarsening of supported palladium nanoparticles in an oxidizing atmosphere was studied in situ by means of transmission electron microscopy (TEM). Specifically, the Pd nanoparticles were dispersed on a planar and amorphous Al2O3 support and were observed during the exposure to 10 mbar technical...... for the Ostwald ripening process indicates that the observed change in the particle size distribution can be accounted for by wetting of the Al2O3 support by the larger Pd nanoparticles....

Report on the progress of various ongoing projects on out JEOL 3000f 300 kV FEG TEM

International Nuclear Information System (INIS)

Bulcock, S.R.; Zou, J.; Cai, D.; Ringer, S.P.

2002-01-01

Full text: The Electron Microscope Unit (EMU) at the University of Sydney has recently installed a new JEOL 3000F Field Emission Gun TEM. With a point resolution of 1.95 Angstroms, it is the ideal tool for high resolution imaging. The microscope also has an Oxford INCA EDS system and GATAN GIF attached, and with an incident probe of diameter ≥0.5nm. As such, it is an excellent tool for microanalysis and in conjunction with a VGSTEM, these facilities are ideal for a large variety of materials microscopy and microanalysis at high resolution. These facilities are also central to the outreach work of the EMU'S Key Centre and add important capability to the Nanostructural Analysis Network Organisation (NANO) the new Australian Major National Research Facility in characterisation. In this poster we will be presenting results from a number of ongoing projects which demonstrate some of the capabilities of both microscopes, including high resolution imaging, phase analysis in Al alloys, compositional gradients in novel glass optical fibres, alternative mechanisms for the formation of misfit dislocation in quantum dots and compositional analysis in quantum well structures. Copyright (2002) Australian Society for Electron Microscopy Inc

High-resolution observations in the western Mediterranean Sea: the REP14-MED experiment

Science.gov (United States)

Onken, Reiner; Fiekas, Heinz-Volker; Beguery, Laurent; Borrione, Ines; Funk, Andreas; Hemming, Michael; Hernandez-Lasheras, Jaime; Heywood, Karen J.; Kaiser, Jan; Knoll, Michaela; Mourre, Baptiste; Oddo, Paolo; Poulain, Pierre-Marie; Queste, Bastien Y.; Russo, Aniello; Shitashima, Kiminori; Siderius, Martin; Thorp Küsel, Elizabeth

2018-04-01

The observational part of the REP14-MED experiment was conducted in June 2014 in the Sardo-Balearic Basin west of Sardinia (western Mediterranean Sea). Two research vessels collected high-resolution oceanographic data by means of hydrographic casts, towed systems, and underway measurements. In addition, a vast amount of data was provided by a fleet of 11 ocean gliders, time series were available from moored instruments, and information on Lagrangian flow patterns was obtained from surface drifters and one profiling float. The spatial resolution of the observations encompasses a spectrum over 4 orders of magnitude from 𝒪(101 m) to 𝒪(105 m), and the time series from the moored instruments cover a spectral range of 5 orders from 𝒪(101 s) to 𝒪(106 s). The objective of this article is to provide an overview of the huge data set which has been utilised by various studies, focusing on (i) water masses and circulation, (ii) operational forecasting, (iii) data assimilation, (iv) variability of the ocean, and (v) new payloads for gliders.

ERDA, RBS, TEM and SEM characterization of microstructural evolution in helium-implanted Hastelloy N alloy

Energy Technology Data Exchange (ETDEWEB)

Gao, Jie [Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100049 (China); Bao, Liangman [Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); Huang, Hefei, E-mail: huanghefei@sinap.ac.cn [Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); Li, Yan, E-mail: liyan@sinap.ac.cn [Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); Lei, Qiantao [Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); Institute of Modern Physics, Fudan University, Shanghai 200433 (China); Deng, Qi [Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); Liu, Zhe; Yang, Guo [Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100049 (China); Shi, Liqun [Institute of Modern Physics, Fudan University, Shanghai 200433 (China)

2017-05-15

Hastelloy N alloy was implanted with 30 keV, 5 × 10{sup 16} ions/cm{sup 2} helium ions at room temperature, and subsequent annealed at 600 °C for 1 h and further annealed at 850 °C for 5 h in vacuum. Using elastic recoil detection analysis (ERDA) and transmission electron microscopy (TEM), the depth profiles of helium concentration and helium bubbles in helium-implanted Hastelloy N alloy were investigated, respectively. The diffusion of helium and molybdenum elements to surface occurred during the vacuum annealing at 850 °C (5 h). It was also observed that bubbles in molybdenum-enriched region were much larger in size than those in deeper region. In addition, it is worth noting that plenty of nano-holes can be observed on the surface of helium-implanted sample after high temperature annealing by scanning electron microscope (SEM). This observation provides the evidence for the occurrence of helium release, which can be also inferred from the results of ERDA and TEM analysis.

Earth System Modeling 2.0: A Blueprint for Models That Learn From Observations and Targeted High-Resolution Simulations

Science.gov (United States)

Schneider, Tapio; Lan, Shiwei; Stuart, Andrew; Teixeira, João.

2017-12-01

Climate projections continue to be marred by large uncertainties, which originate in processes that need to be parameterized, such as clouds, convection, and ecosystems. But rapid progress is now within reach. New computational tools and methods from data assimilation and machine learning make it possible to integrate global observations and local high-resolution simulations in an Earth system model (ESM) that systematically learns from both and quantifies uncertainties. Here we propose a blueprint for such an ESM. We outline how parameterization schemes can learn from global observations and targeted high-resolution simulations, for example, of clouds and convection, through matching low-order statistics between ESMs, observations, and high-resolution simulations. We illustrate learning algorithms for ESMs with a simple dynamical system that shares characteristics of the climate system; and we discuss the opportunities the proposed framework presents and the challenges that remain to realize it.

2D Inversion of Transient Electromagnetic Method (TEM)

Science.gov (United States)

Bortolozo, Cassiano Antonio; Luís Porsani, Jorge; Acácio Monteiro dos Santos, Fernando

2017-04-01

A new methodology was developed for 2D inversion of Transient Electromagnetic Method (TEM). The methodology consists in the elaboration of a set of routines in Matlab code for modeling and inversion of TEM data and the determination of the most efficient field array for the problem. In this research, the 2D TEM modeling uses the finite differences discretization. To solve the inversion problem, were applied an algorithm based on Marquardt technique, also known as Ridge Regression. The algorithm is stable and efficient and it is widely used in geoelectrical inversion problems. The main advantage of 1D survey is the rapid data acquisition in a large area, but in regions with two-dimensional structures or that need more details, is essential to use two-dimensional interpretation methodologies. For an efficient field acquisition we used in an innovative form the fixed-loop array, with a square transmitter loop (200m x 200m) and 25m spacing between the sounding points. The TEM surveys were conducted only inside the transmitter loop, in order to not deal with negative apparent resistivity values. Although it is possible to model the negative values, it makes the inversion convergence more difficult. Therefore the methodology described above has been developed in order to achieve maximum optimization of data acquisition. Since it is necessary only one transmitter loop disposition in the surface for each series of soundings inside the loop. The algorithms were tested with synthetic data and the results were essential to the interpretation of the results with real data and will be useful in future situations. With the inversion of the real data acquired over the Paraná Sedimentary Basin (PSB) was successful realized a 2D TEM inversion. The results indicate a robust geoelectrical characterization for the sedimentary and crystalline aquifers in the PSB. Therefore, using a new and relevant approach for 2D TEM inversion, this research effectively contributed to map the most

High-resolution observations of the near-surface wind field over an isolated mountain and in a steep river canyon

Science.gov (United States)

B. W. Butler; N. S. Wagenbrenner; J. M. Forthofer; B. K. Lamb; K. S. Shannon; D. Finn; R. M. Eckman; K. Clawson; L. Bradshaw; P. Sopko; S. Beard; D. Jimenez; C. Wold; M. Vosburgh

2015-01-01

A number of numerical wind flow models have been developed for simulating wind flow at relatively fine spatial resolutions (e.g., 100 m); however, there are very limited observational data available for evaluating these high-resolution models. This study presents high-resolution surface wind data sets collected from an isolated mountain and a steep river canyon. The...

In situ TEM observation of the Boudouard reaction: Multi-layered graphene formation from CO on cobalt nanoparticles at atmospheric pressure

NARCIS (Netherlands)

Bremmer, G.M.; Zacharaki, E.; Sjåstad, A.O.; Navarro, V.; Frenken, J.W.M.; Kooyman, P.J.

2017-01-01

Using a MEMS nanoreactor in combination with a specially designed in situ Transmission Electron Microscope (TEM) holder and gas supply system, we imaged the formation of multiple layers of graphene encapsulating a cobalt nanoparticle, at 1 bar CO:N2 (1:1) and 500 °C. The cobalt nanoparticle was

The adhesion behavior of carbon coating studied by re-indentation during in situ TEM nanoindentation

Energy Technology Data Exchange (ETDEWEB)

Fan, Xue; Diao, Dongfeng, E-mail: dfdiao@szu.edu.cn

2016-01-30

Graphical abstract: Nanoscale adhesion induced response in terms of re-indentation was directly observed. During unloading (start from B), the re-indentation phenomenon with the displacement sudden drop and the external loading force change from tension (C) to compression (D) within 0.1 s was captured by in situ TEM nanoindentation. - Highlights: • In situ TEM nanoindentation was performed on carbon coating. • Adhesion induced nano-response of re-indentation was directly observed. • Adhesive forces were measured from the load–displacement curves. • Adhesion energies released for re-indentation were quantitatively analyzed. • Carbon coating reduced the impact of adhesion for silicon substrate. - Abstract: We report a nanoscale adhesion induced nano-response in terms of re-indentation during in situ transmission electron microscope (TEM) nanoindentation on the carbon coating with silicon substrate. The adhesive force generated with nanoindentation was measured, and re-indentation phenomenon during unloading with displacement sudden drop and external loading force change from tension to compression was found. The occurrence of re-indentation during unloading was ascribed to the adhesive force of the contact interface between the indenter and the coating surface. Adhesion energies released for re-indentation processes were quantitatively analyzed from the re-indentation load–displacement curves, and carbon coating reduced the impact of adhesion for silicon substrate. The adhesion induced nano-response of contact surfaces would affect the reliability and performance of nano devices.

TEM microstructural analysis of creep deformed CM186LC single crystal Ni-base superalloy

Energy Technology Data Exchange (ETDEWEB)

Dubiel, B.; Czyrska-Filemonowicz, A. [AGH Univ. of Science and Technology, Krakow (Poland); Blackler, M. [Howmet Ltd., Exeter (United Kingdom); Barnard, P.M. [ALSTOM Power Turbo-Systems Technology Centre, Rugby (United Kingdom)

2006-07-01

The nickel based single crystal superalloy CM186LC was extensively investigated as a potential low cost material for industrial gas turbine vanes within the COST522 programme. The alloy exhibits inhomogeneous structure consisting of dendritic regions and eutectic colonies. In the present work attention is focused on microstructural changes observed in single crystal CM186LC following creep deformation at 750 C. Creep tests were conducted at 750 C with an applied stress of 560 or 675 MPa for up to 11440 hours. The microstructure o ruptured and terminated specimens was investigated by scanning (SEM) and transmission (TEM) electron microscopy. TEM analysis revealed the microstructural changes in the CM186LC at primary and secondary creep as well as after creep rupture. (orig.)

Electron beam fabrication and characterization of high- resolution magnetic force microscopy tips

NARCIS (Netherlands)

Ruhrig, M.; Rührig, M.; Porthun, S.; Porthun, S.; Lodder, J.C.; Mc vitie, S.; Heyderman, L.J.; Johnston, A.B.; Chapman, J.N.

1996-01-01

The stray field, magnetic microstructure, and switching behavior of high‐resolution electron beam fabricated thin film tips for magnetic force microscopy (MFM) are investigated with different imaging modes in a transmission electron microscope (TEM). As the tiny smooth carbon needles covered with a

The high resolution optical instruments for the Pleiades HR Earth observation satellites

Science.gov (United States)

Gaudin-Delrieu, Catherine; Lamard, Jean-Luc; Cheroutre, Philippe; Bailly, Bruno; Dhuicq, Pierre; Puig, Olivier

2017-11-01

Coming after the SPOT satellites series, PLEIADESHR is a CNES optical high resolution satellite dedicated to Earth observation, part of a larger optical and radar multi-sensors system, ORFEO, which is developed in cooperation between France and Italy for dual Civilian and Defense use. The development of the two PLEIADES-HR cameras was entrusted by CNES to Thales Alenia Space. This new generation of instrument represents a breakthrough in comparison with the previous SPOT instruments owing to a significant step in on-ground resolution, which approaches the capabilities of aerial photography. The PLEIADES-HR instrument program benefits from Thales Alenia Space long and successful heritage in Earth observation from space. The proposed solution benefits from an extensive use of existing products, Cannes Space Optics Centre facilities, unique in Europe, dedicated to High Resolution instruments. The optical camera provides wide field panchromatic images supplemented by 4 multispectral channels with narrow spectral bands. The optical concept is based on a four mirrors Korsch telescope. Crucial improvements in detector technology, optical fabrication and electronics make it possible for the PLEIADES-HR instrument to achieve the image quality requirements while respecting the drastic limitations of mass and volume imposed by the satellite agility needs and small launchers compatibility. The two flight telescopes were integrated, aligned and tested. After the integration phase, the alignment, mainly based on interferometric measurements in vacuum chamber, was successfully achieved within high accuracy requirements. The wave front measurements show outstanding performances, confirmed, after the integration of the PFM Detection Unit, by MTF measurements on the Proto-Flight Model Instrument. Delivery of the proto flight model occurred mi-2008. The FM2 Instrument delivery is planned Q2-2009. The first optical satellite launch of the PLEIADES-HR constellation is foreseen

Spontaneous Resolution of Chronic Subdural Hematoma : Close Observation as a Treatment Strategy

Science.gov (United States)

Kim, Hyung Chan; Yoo, Dong Soo; Lee, Sang-Koo

2016-01-01

Objective Chronic subdural hematoma (cSDH) is common condition in neurosurgical field. It is difficult to select the treatment modality between the surgical method and the conservative method when patients have no or mild symptoms. The purpose of this study is to provide a suggestion that the patients could be cured with conservative treatment modality. Methods We enrolled 16 patients who had received conservative treatment for cSDH without special medications which could affect hematoma resolution such as mannitol, steroids, tranexamic acid and angiotensin converting enzyme inhibitors. The patients were classified according to the Markwalder's Grading Scale. Results Among these 16 patients, 13 (81.3%) patients showed spontaneously resolved cSDH and 3 (18.7%) patients received surgery due to symptom aggravation and growing hematoma. They were categorized into two groups based on whether they were cured with conservative treatment or not. The first group was the spontaneous resolution group. The second group was the progression-surgery group. The mean hematoma volume in the spontaneous resolution group was 43.1 mL. The mean degree of midline shift in the spontaneous resolution group was 5.3 mm. The mean hematoma volume in the progression-surgery group was 62.0 mL. The mean degree of midline shift in the second group was 6 mm. Conclusion We suggest that the treatment modality should be determined according to the patient's symptoms and clinical condition and close observation could be performed in patients who do not have any symptoms or in patients who have mild to moderate headache without neurological deterioration. PMID:27847578

Molecular identification of TEM-116 beta-lactamase gene in isolates ...

African Journals Online (AJOL)

Purpose: Purpose: To determine TEM-116 beta-lactamase gene prevalence in drug-resistant Pseudomonas aeruginosa isolates from Pakistan. Methods: Sequence analysis of TEM beta-lactamase isolates and their antibiotic susceptibility patterns were carried out. Quantitative bacteriostatic concentrations for commonly ...

Exploring image data assimilation in the prospect of high-resolution satellite oceanic observations

Science.gov (United States)

Durán Moro, Marina; Brankart, Jean-Michel; Brasseur, Pierre; Verron, Jacques

2017-07-01

Satellite sensors increasingly provide high-resolution (HR) observations of the ocean. They supply observations of sea surface height (SSH) and of tracers of the dynamics such as sea surface salinity (SSS) and sea surface temperature (SST). In particular, the Surface Water Ocean Topography (SWOT) mission will provide measurements of the surface ocean topography at very high-resolution (HR) delivering unprecedented information on the meso-scale and submeso-scale dynamics. This study investigates the feasibility to use these measurements to reconstruct meso-scale features simulated by numerical models, in particular on the vertical dimension. A methodology to reconstruct three-dimensional (3D) multivariate meso-scale scenes is developed by using a HR numerical model of the Solomon Sea region. An inverse problem is defined in the framework of a twin experiment where synthetic observations are used. A true state is chosen among the 3D multivariate states which is considered as a reference state. In order to correct a first guess of this true state, a two-step analysis is carried out. A probability distribution of the first guess is defined and updated at each step of the analysis: (i) the first step applies the analysis scheme of a reduced-order Kalman filter to update the first guess probability distribution using SSH observation; (ii) the second step minimizes a cost function using observations of HR image structure and a new probability distribution is estimated. The analysis is extended to the vertical dimension using 3D multivariate empirical orthogonal functions (EOFs) and the probabilistic approach allows the update of the probability distribution through the two-step analysis. Experiments show that the proposed technique succeeds in correcting a multivariate state using meso-scale and submeso-scale information contained in HR SSH and image structure observations. It also demonstrates how the surface information can be used to reconstruct the ocean state below

Estudo das propriedades psicométricas do Teste de Memória de Reconhecimento – TEM-R

Directory of Open Access Journals (Sweden)

Fabián Javier Marín Rueda

2012-06-01

Full Text Available The purpose was to verify the psychometric qualities of the Memory Test of Recognition (TEM-R. In a first moment an initial version of the TEM-R was applied at 137 college students. It was found that from the 64 initial items, 15 did not show any frequency response. Based on this it was proceeded a reconfiguration of the instrument, fixing the number of 49 items. It was accomplished a new enforcement where participated 531 college students. The results of the internal structure showed an adequacy to the Rasch model, a absence of bias in the items through the analysis of differential items functioning, and an appropriate factor structure. We observed satisfactory reability indexes. Thus, the TEM-R presented adequate psychometric properties for use in the Brazilian reality.   Keywords: memory; psychological tests; psychometry; validity; reability.

Track Etch Membranes (TEMS) for separation sciences from BARC-TIFR Pelletron accelerator

International Nuclear Information System (INIS)

Nair, J.P.; Surendran, P.; Sparrow, Hillary; Gupta, A.K.; Kailas, S.; Bhagwat, P.V.

2014-01-01

TEMs are very much in need for the separation of desirable/undesirable metals from industrial effluents and radioactive wastes as well as in the field of biology and gas separation. It is necessary to optimize pore size and pore density for a specific application. TEMs available in market are imported and are used for laboratory scale activity. To carry the success of these activities on industrial scale large scale production of TEMs is needed. The availability of heavy ion accelerator made possible the production of TEMs in wide range of sizes. Many countries have set up facilities for continuous production of TEMs. BARC-TIFR Pelletron Accelerator at Mumbai delivers MeV energies of heavy ions for research in basic as well as applied sciences. Heavy ions of various species and energies from BARC-TIFR Pelletron Accelerator were used to make TEMs using polyethylene terephthalate (PET/Mylar) films of 25 micron thickness. The films used were procured from reputed manufactures in India

HRTEM Imaging of Atoms at Sub-Angstrom Resolution

Energy Technology Data Exchange (ETDEWEB)

O' Keefe, Michael A.; Allard, Lawrence F.; Blom, Douglas A.

2005-04-06

John Cowley and his group at Arizona State University pioneered the use of transmission electron microscopy (TEM) for high-resolution imaging. Images were achieved three decades ago showing the crystal unit cell content at better than 4 Angstrom resolution. This achievement enabled researchers to pinpoint the positions of heavy atom columns within the unit cell. Lighter atoms appear as resolution is improved to sub-Angstrom levels. Currently, advanced microscopes can image the columns of the light atoms (carbon, oxygen, nitrogen) that are present in many complex structures, and even the lithium atoms present in some battery materials. Sub-Angstrom imaging, initially achieved by focal-series reconstruction of the specimen exit surface wave, will become common place for next-generation electron microscopes with CS-corrected lenses and monochromated electron beams. Resolution can be quantified in terms of peak separation and inter-peak minimum, but the limits imposed on the attainable resolution by the properties of the micro-scope specimen need to be considered. At extreme resolution the ''size'' of atoms can mean that they will not be resolved even when spaced farther apart than the resolution of the microscope.

Measurement and correlation of optical and TEM twins in Y/sub 1/Ba/sub 2/Cu/sub 3/O/sub 7-δ/

International Nuclear Information System (INIS)

Chumbley, L.S.; Verhoeven, J.D.; Kim, M.R.; Cornelius, A.L.; Kramer, M.J.

1989-01-01

The spacing of the twins present in Y/sub 1/Ba/sub 2/Cu/sub 3/O/sub 7-δ/ has been investigated using optical and Transmission Electron Microscopy (TEM). Studies have reported that the value of the average twin spacing obtained by optical measurements is much larger than that measured in thin foils prepared for TEM observation, and controversy exists as to the exact nature of the optical twins. Experiments have been conducted which show that the twins observed optically correspond to those seen using TEM and are not produced by an optical interference effect. Using electron channeling, equations have been formulated which allow optical determination of the true spacing of twins present in a selected grain as well as the orientation of that grain. The average twin spacing measured in TEM has been found to vary with sample preparation method, being smaller for crushed chip samples than for bulk samples prepared by ion milling or jet-polishing. A variation of the twin spacing with grain size has also been noted

How TEM Projection Artifacts Distort Microstructure Measurements: A Case Study in a 9 pct Cr-Mo-V Steel

Science.gov (United States)

Monsegue, Niven; Reynolds, William T.; Hawk, Jeffrey A.; Murayama, Mitsuhiro

2014-08-01

Morphological data obtained from two-dimensional (2D) and three-dimensional (3D) transmission electron microscopy (TEM) observations were compared to assess the effects of TEM projection errors for submicron-size precipitates. The microstructure consisted of M23C6 carbides in a 9 pct Cr-Mo-V heat resistant steel before and after exposure to creep conditions. Measurements obtained from about 800 carbides demonstrate that particle size and spacing estimates made from 2D observations overestimate the more accurate values obtained from 3D reconstructions. The 3D analysis also revealed the M23C6 precipitates lengthen anisotropically along lath boundary planes, suggesting that coarsening during the early stage of creep in this alloy system is governed by grain boundary diffusion.

Developments in TEM Nanotomography of Calcium Silicate Hydrate

KAUST Repository

Taylor, Rae; Sakdinawat, Anne E.; Chae, Sejung R.; Wenk, Haz Rudolf; Levitz, Pierre E.; Sougrat, Rachid; Monteiro, Paulo José Meleragno

2015-01-01

This investigation was designed to explore the possibility of using transmission electron microscope (TEM) tomography on cement-based systems gain a greater understanding of their nanostructure and pore network. The preliminary results show a clearly a well-defined pore network at the nanoscale, with pore size approximately 1.7-2.4 nm in diameter and spaced around 5-8 nm apart. A comparison of small angle X-ray scattering data with 2-D TEM images analyzed with the Fourier slice theorem documents an excellent structural correlation. © 2015 The American Ceramic Society.

Developments in TEM Nanotomography of Calcium Silicate Hydrate

KAUST Repository

Taylor, Rae

2015-04-01

This investigation was designed to explore the possibility of using transmission electron microscope (TEM) tomography on cement-based systems gain a greater understanding of their nanostructure and pore network. The preliminary results show a clearly a well-defined pore network at the nanoscale, with pore size approximately 1.7-2.4 nm in diameter and spaced around 5-8 nm apart. A comparison of small angle X-ray scattering data with 2-D TEM images analyzed with the Fourier slice theorem documents an excellent structural correlation. © 2015 The American Ceramic Society.

Direct observation of atomic-level nucleation and growth processes from an ultrathin metallic glass films

Energy Technology Data Exchange (ETDEWEB)

Huang, K. Q.; Cao, C. R.; Sun, Y. T.; Li, J.; Bai, H. Y.; Zheng, D. N., E-mail: l.gu@iphy.ac.cn, E-mail: dzheng@iphy.ac.cn, E-mail: whw@iphy.ac.cn; Wang, W. H., E-mail: l.gu@iphy.ac.cn, E-mail: dzheng@iphy.ac.cn, E-mail: whw@iphy.ac.cn [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Gu, L., E-mail: l.gu@iphy.ac.cn, E-mail: dzheng@iphy.ac.cn, E-mail: whw@iphy.ac.cn [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Collaborative Innovation Center of Quantum Matter, Beijing 100190 (China)

2016-01-07

Till date, there have been no direct atomic-level experimental observations of the earliest stages of the nucleation and growth processes of nanocrystals formed by thermally induced crystallization in ultrathin metallic glasses (MGs). Here, we present a study of the crystallization process in atomically thin and highly stable MG films using double spherical aberration-corrected scanning transmission electron microscopy (Cs-TEM). Taking advantage of the stability of MG films with a slow crystallization process and the atomic-level high resolution of Cs-TEM, we observe the formation of the nucleus precursor of nanocrystals formed by atom aggregation followed by concomitant coalescence and stepwise evolution of the shape of the nanocrystals with a monodispersed and separated bimodal size distribution. Molecular dynamics simulation of the atomic motion in the glass film on a rigid amorphous substrate confirms the stepwise evolution processes of atom aggregation, cluster formation, cluster movement on the substrate, and cluster coalescence into larger crystalline particles. Our results might provide a better fundamental understanding of the nucleation and growth processes of nanocrystals in thin MG films.

Sub-surface microstructure of single and polycrystalline tungsten after high flux plasma exposure studied by TEM

Energy Technology Data Exchange (ETDEWEB)

Dubinko, A., E-mail: adubinko@sckcen.be [Institute for Nuclear Material Sciences, SCK-CEN, 2400 Mol (Belgium); Department of Applied Physics, Ghent University, 9000 Ghent (Belgium); Terentyev, D. [Institute for Nuclear Material Sciences, SCK-CEN, 2400 Mol (Belgium); Bakaeva, A. [Institute for Nuclear Material Sciences, SCK-CEN, 2400 Mol (Belgium); Department of Applied Physics, Ghent University, 9000 Ghent (Belgium); Hernández-Mayoral, M. [Division of Materials, CIEMAT, 28040 Madrid (Spain); De Temmerman, G. [ITER Organization, Route de Vinon-sur-Verdon, CS 90 046, 13067 St Paul-lez-Durance Cedex (France); Buzi, L. [Forschungszentrum Julich, Inst. Energie & Klimaforsch Plasmaphys, D-52425 Julich (Germany); Noterdaeme, J.-M. [Department of Applied Physics, Ghent University, 9000 Ghent (Belgium); Unterberg, B. [Forschungszentrum Julich, Inst. Energie & Klimaforsch Plasmaphys, D-52425 Julich (Germany)

2017-01-30

Highlights: • Plasma exposure induces dislocation-dominated microstructure as indicated by TEM. • Plasma exposure increases surface dislocation density by an order of magnitude in the polycrystalline tungsten. • Intensive dislocation-grain boundary interaction observed in polycrystalline tungsten. • Dislocation loops are observed in both polycrystalline and single crystal tungsten. - Abstract: We have performed high flux plasma exposure of tungsten and subsequent microstructural characterization using transmission electron microscopy (TEM) techniques. The aim was to reveal the nanometric features in the sub-surface region as well as to compare the microstructural evolution in tungsten single crystal and ITER-relevant specification. In both types of samples, TEM examination revealed the formation of a dense dislocation network and dislocation tangles. The estimated dislocation density in the sub-surface region was of the order of 10{sup 14} m{sup −2} and it gradually decreased with a depth position of the examined sample. Besides individual dislocation lines, networks and tangles, the interstitial dislocation loops have been observed in all examined samples only after the exposure. Contrary to that, examination of the pristine single crystal W and backside of the plasma-exposed samples did not reveal the presence of dislocation loops and tangles. This clearly proves that high flux plasma exposure induces severe plastic deformation in the sub-surface region irrespective of the presence of initial dislocations and sub-grains, and the formation of dislocation tangles, networks and interstitial loops is a co-product of thermal stress and intensive plasma particles uptake.

Inter-observer agreement for diagnostic classification of esophageal motility disorders defined in high-resolution manometry

NARCIS (Netherlands)

Fox, M. R.; Pandolfino, J. E.; Sweis, R.; Sauter, M.; Abreu Y Abreu, A. T.; Anggiansah, A.; Bogte, A.; Bredenoord, A. J.; Dengler, W.; Elvevi, A.; Fruehauf, H.; Gellersen, S.; Ghosh, S.; Gyawali, C. P.; Heinrich, H.; Hemmink, M.; Jafari, J.; Kaufman, E.; Kessing, K.; Kwiatek, M.; Lubomyr, B.; Banasiuk, M.; Mion, F.; Pérez-de-la-Serna, J.; Remes-Troche, J. M.; Rohof, W.; Roman, S.; Ruiz-de-León, A.; Tutuian, R.; Uscinowicz, M.; Valdovinos, M. A.; Vardar, R.; Velosa, M.; Waśko-Czopnik, D.; Weijenborg, P.; Wilshire, C.; Wright, J.; Zerbib, F.; Menne, D.

2015-01-01

High-resolution esophageal manometry (HRM) is a recent development used in the evaluation of esophageal function. Our aim was to assess the inter-observer agreement for diagnosis of esophageal motility disorders using this technology. Practitioners registered on the HRM Working Group website were

Investigation of the nanoscale two-component ZnS-ZnO heterostructures by means of HR-TEM and X-ray based analysis

Science.gov (United States)

Pankin, I. A.; Polozhentsev, O. E.; Soldatov, M. A.; Bugaev, A. L.; Tsaturyan, A.; Lomachenko, K. A.; Guda, A. A.; Budnyk, A. P.; Lamberti, C.; Soldatov, A. V.

2018-06-01

This article is devoted to the spectroscopic characterization of ZnS-ZnO nanoscale heterostructures synthesized by the microwave-assisted solvothermal method. The synthesized samples were investigated by means of X-ray powder diffraction (XRPD), high energy resolution fluorescence detected X-ray absorption near-edge-structure (HERFD-XANES) spectroscopy, valence-to-core X-ray emission spectroscopy (VtC-XES) and high resolution transmission electron microscopy (HR-TEM) as well as energy dispersive X-ray spectroscopy (EDX). The average crystallite size estimated by the broadening of XRPD peaks increases from 2.7 nm to 3.7 nm in the temperature range from 100 °C to 150 °C. HR-TEM images show that nanoparticles are arranged in aggregates with the 60-200 nm size. Theoretical estimation shows that the systems synthesized at higher temperatures more prone to the agglomeration. The full profile Reitveld analysis of XRPD data reveals the formation of hexagonal zinc sulfide structure, whereas electron diffraction data reveal also the formation of cubic zinc sulfide and claim the polymorphous character of the system. High energy resolution Zn K-edge XANES data unambiguously demonstrate the presence of a certain amount of the zinc oxide which is likely to have an amorphous structure and could not be detected by XRPD. Qualitative analysis of XANES data allows deriving ZnS/ZnO ratio as a function of synthesis temperature. EDX analysis depicts homogeneous distribution of ZnS and amorphous ZnO phases across the conglomerates. A complementary element-selective valence to core X-ray emission spectroscopy evidences formation of two-component system and confirms estimations of ZnS/ZnO fractions obtained by linear combination fit of XANES data.

SMA OBSERVATIONS OF CLASS 0 PROTOSTARS: A HIGH ANGULAR RESOLUTION SURVEY OF PROTOSTELLAR BINARY SYSTEMS

Energy Technology Data Exchange (ETDEWEB)

Chen Xuepeng [Purple Mountain Observatory, Chinese Academy of Sciences, 2 West Beijing Road, Nanjing 210008 (China); Arce, Hector G.; Dunham, Michael M. [Department of Astronomy, Yale University, Box 208101, New Haven, CT 06520-8101 (United States); Zhang Qizhou; Bourke, Tyler L. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Launhardt, Ralf; Henning, Thomas [Max Planck Institute for Astronomy, Koenigstuhl 17, D-69117 Heidelberg (Germany); Jorgensen, Jes K. [Niels Bohr Institute and Centre for Star and Planet Formation, Copenhagen University, Juliane Maries Vej 30, DK-2100 Copenhagen O (Denmark); Lee, Chin-Fei [Academia Sinica Institute of Astronomy and Astrophysics, P.O. Box 23-141, Taipei 106, Taiwan (China); Foster, Jonathan B. [Institute for Astrophysical Research, Boston University, Boston, MA 02215 (United States); Pineda, Jaime E., E-mail: xpchen@pmo.ac.cn, E-mail: xuepeng.chen@yale.edu [ESO, Karl Schwarzschild Str. 2, D-85748 Garching bei Munchen (Germany)

2013-05-10

We present high angular resolution 1.3 mm and 850 {mu}m dust continuum data obtained with the Submillimeter Array toward 33 Class 0 protostars in nearby clouds (distance < 500 pc), which represents so far the largest survey toward protostellar binary/multiple systems. The median angular resolution in the survey is 2.''5, while the median linear resolution is approximately 600 AU. Compact dust continuum emission is observed from all sources in the sample. Twenty-one sources in the sample show signatures of binarity/multiplicity, with separations ranging from 50 AU to 5000 AU. The numbers of singles, binaries, triples, and quadruples in the sample are 12, 14, 5, and 2, respectively. The derived multiplicity frequency (MF) and companion star fraction (CSF) for Class 0 protostars are 0.64 {+-} 0.08 and 0.91 {+-} 0.05, respectively, with no correction for completeness. The derived MF and CSF in this survey are approximately two times higher than the values found in the binary surveys toward Class I young stellar objects, and approximately three (for MF) and four (for CSF) times larger than the values found among main-sequence stars, with a similar range of separations. Furthermore, the observed fraction of high-order multiple systems to binary systems in Class 0 protostars (0.50 {+-} 0.09) is also larger than the fractions found in Class I young stellar objects (0.31 {+-} 0.07) and main-sequence stars ({<=}0.2). These results suggest that binary properties evolve as protostars evolve, as predicted by numerical simulations. The distribution of separations for Class 0 protostellar binary/multiple systems shows a general trend in which CSF increases with decreasing companion separation. We find that 67% {+-} 8% of the protobinary systems have circumstellar mass ratios below 0.5, implying that unequal-mass systems are preferred in the process of binary star formation. We suggest an empirical sequential fragmentation picture for binary star formation, based on this

Neutron, x-ray scattering and TEM studies of Ni-Ti multilayers

International Nuclear Information System (INIS)

Keem, J.E.; Wood, J.; Grupido, N.; Hart, K.; Nutt, S.; Reichel, D.G.; Yelon, W.B.

1988-01-01

The authors present an analysis of Ni-Ti multilayer neutron reflectors and supermirrors undertaken to identify the causes of the lower than expected observed scattering power and critical angle enhancement of Ni-Ti supermirrors. Results of these investigations focus attention on cusp formation in the Ni-Ti bilayers as probable cause for the reduced neutron scattering power. Grazing angle x-ray and neutron scattering, wide angle neutron diffraction and analytical cross sectional TEM have been used. The multilayers were produced by magnetron sputtering and ion-beam deposition on float glass substrates and silicon wafers

Razvijmo sebe, druge in s tem svoj kraj

Directory of Open Access Journals (Sweden)

Dušana Findeisen

1997-12-01

Full Text Available Dušana Findeisen v tem prispevku obravnava vprašanje, kako spodbuditi ljudi k soodgovornosti za lasten razvoj in razvoj kraja. Preučuje tudi, kako naj prebivalci postanejo soodgovorni za zadostitev lastnih potreb in potreb njihovega kraja. V zvezi s tem se dotakne vloge izobraževalca odraslih - animatorja lokalnih projektov. Poudarja tudi pomen navezovanja novih odnosov in razmerij med lokalnimi skupnostmi in državo ter uvajanje “strukturalne politike”, kot jo imenuje avtorica, za sistemsko pomoč razvoju lokalnih projektov. Nazadnje pa obravnava vlogo lokalnih projektov z vidika razvoja kraja.

HR-TEM and FT-Raman dataset of the caffeine interacted Phe-Phe peptide nanotube for possible sensing applications.

Science.gov (United States)

Narayanan, A Lakshmi; Dhamodaran, M; Solomon, J Samu; Karthikeyan, B; Govindhan, R

2018-02-01

Sensing ability of caffeine interaction with Phe-Phe annotates (PNTs), is presented (Govindhan et al., 2017; Karthikeyan et al., 2014; Tavagnacco et al., 2013; Kennedy et al., 2011; Wang et al., 2017) [1-5] in this data set. Investigation of synthesized caffeine carrying peptide nanotubes are carried out by FT-Raman spectral analysis and high resolution transmission electron microscopy (HR-TEM). Particle size of the caffeine loaded PNTs is < 40 nm. The FT-Raman spectrum signals are enhanced in the region of 400-1700 cm -1 . These data are ideal tool for the applications like biosensing and drug delivery research (DDS).

Quantitative phase imaging and differential interference contrast imaging for biological TEM

International Nuclear Information System (INIS)

Allman, B.E.; McMahon, P.J.; Barone-Nugent, E.D.; Nugent, E.D.

2002-01-01

Full text: Phase microscopy is a central technique in science. An experienced microscopist uses this effect to visualise (edge) structure within transparent samples by slightly defocusing the microscope. Although widespread in optical microscopy, phase contrast transmission electron microscopy (TEM) has not been widely adopted. TEM for biological specimens has largely relied on staining techniques to yield sufficient contrast. We show here a simple method for quantitative TEM phase microscopy that quantifies this phase contrast effect. Starting with conventional, digital, bright field images of the sample, our algorithm provides quantitative phase information independent of the sample's bright field intensity image. We present TEM phase images of a range of stained and unstained, biological and material science specimens. This independent phase and intensity information is then used to emulate a range of phase visualisation images familiar to optical microscopy, e.g. differential interference contrast. The phase images contain features not visible with the other imaging modalities. Further, if the TEM samples have been prepared on a microtome to a uniform thickness, the phase information can be converted into refractive index structure of the specimen. Copyright (2002) Australian Society for Electron Microscopy Inc

In-situ TEM investigations of graphic-epitaxy and small particles. Final Report, 1 January-31 December 1982

International Nuclear Information System (INIS)

Heinemann, K.

1983-01-01

Palladium was deposited inside a controlled-vacuum specimen chamber of a transmission electron microscope (TEM) onto MgO and alpha-alumina substrate surfaces. Annealing and various effects of gas exposure of the particulate Pd deposits were studied in-situ by high resolution TEM and electron diffraction. Whereas substrate temperatures of 500 C or annealing of room temperature (RT) deposits to 500 C were needed to obtain epitaxy on sapphire, RT deposits on MgO were perfectly epitaxial. For Pd/MgO a lattice expansion of 2 to 4% was noted the highest values of expansion were found for the smallest particles. The lattice expansion of small Pd particles on alumina substrates was less than 1%. Long-time RT exposure of Pd/MgO in a vacuum yielded some moblity and coalescence events, but notably fewer than for Pd on sapphire. Exposure to air or oxygen greatly enhanced the particle mobility and coalescence and also resulted in the flattening of Pd particles on MgO substrates. Electron-beam irradiation further enhanced this effect. Exposure to air for several tens of hours of Pd/MgO led to strong coalescence

TEM investigation of irradiation damage in single crystal CeO2

International Nuclear Information System (INIS)

Ye Bei; Kirk, Mark A.; Chen, Weiying; Oaks, Aaron; Rest, Jeffery; Yacout, Abdellatif; Stubbins, James F.

2011-01-01

In order to understand the evolution of radiation damage in oxide nuclear fuel, 150-1000 keV Kr ions were implanted into single crystal CeO 2 , as a simulation of fluorite ceramic UO 2 , while in situ transmission electron microscopy (TEM) observations were carried out. Two characteristic defect structures were investigated: dislocation/dislocation loops and nano-size gas bubbles. The growth behavior of defect clusters induced by 1 MeV Kr ions up to doses of 5 x 10 15 ions/cm 2 were followed at 600 deg. C and 800 deg. C. TEM micrographs clearly show the development of defect structures: nucleation of dislocation loops, transformation to extended dislocation lines, and the formation of tangled dislocation networks. The difference in dislocation growth rates at 600 deg. C and 800 deg. C revealed the important role which Ce-vacancies play in the loop formation process. Bubble formation, studied through 150 keV Kr implantations at room temperature and 600 deg. C, might be influenced by either the mobility of metal-vacancies correlated with at threshold temperature or the limitation of gas solubility as a function of temperature.

Benchmarking of a novel contactless characterisation method for micro thermoelectric modules (μTEMs)

International Nuclear Information System (INIS)

Hickey, S; Punch, J; Jeffers, N

2014-01-01

Significant challenges exist in the thermal control of Photonics Integrated Circuits (PICs) for use in optical communications. Increasing component density coupled with greater functionality is leading to higher device-level heat fluxes, stretching the capabilities of conventional cooling methods using thermoelectric modules (TEMs). A tailored thermal control solution incorporating micro thermoelectric modules (μTEMs) to individually address hotspots within PICs could provide an energy efficient alternative to existing control methods. Performance characterisation is required to establish the suitability of commercially-available μTEMs for the operating conditions in current and next generation PICs. The objective of this paper is to outline a novel method for the characterisation of thermoelectric modules (TEMs), which utilises infra-red (IR) heat transfer and temperature measurement to obviate the need for mechanical stress on the upper surface of low compression tolerance (∼0.5N) μTEMs. The method is benchmarked using a commercially-available macro scale TEM, comparing experimental data to the manufacturer's performance data sheet.

Benchmarking of a novel contactless characterisation method for micro thermoelectric modules (μTEMs)

Science.gov (United States)

Hickey, S.; Punch, J.; Jeffers, N.

2014-07-01

Significant challenges exist in the thermal control of Photonics Integrated Circuits (PICs) for use in optical communications. Increasing component density coupled with greater functionality is leading to higher device-level heat fluxes, stretching the capabilities of conventional cooling methods using thermoelectric modules (TEMs). A tailored thermal control solution incorporating micro thermoelectric modules (μTEMs) to individually address hotspots within PICs could provide an energy efficient alternative to existing control methods. Performance characterisation is required to establish the suitability of commercially-available μTEMs for the operating conditions in current and next generation PICs. The objective of this paper is to outline a novel method for the characterisation of thermoelectric modules (TEMs), which utilises infra-red (IR) heat transfer and temperature measurement to obviate the need for mechanical stress on the upper surface of low compression tolerance (~0.5N) μTEMs. The method is benchmarked using a commercially-available macro scale TEM, comparing experimental data to the manufacturer's performance data sheet.

Super-resolution

DEFF Research Database (Denmark)

Nasrollahi, Kamal; Moeslund, Thomas B.

2014-01-01

Super-resolution, the process of obtaining one or more high-resolution images from one or more low-resolution observations, has been a very attractive research topic over the last two decades. It has found practical applications in many real world problems in different fields, from satellite...

TEM Study of High-Temperature Precipitation of Delta Phase in Inconel 718 Alloy

Directory of Open Access Journals (Sweden)

Moukrane Dehmas

2011-01-01

Full Text Available Inconel 718 is widely used because of its ability to retain strength at up to 650∘C for long periods of time through coherent metastable  Ni3Nb precipitation associated with a smaller volume fraction of  Ni3Al precipitates. At very long ageing times at service temperature,  decomposes to the stable Ni3Nb phase. This latter phase is also present above the  solvus and is used for grain control during forging of alloy 718. While most works available on precipitation have been performed at temperatures below the  solvus, it appeared of interest to also investigate the case where phase precipitates directly from the fcc matrix free of  precipitates. This was studied by X-ray diffraction and transmission electron microscopy (TEM. TEM observations confirmed the presence of rotation-ordered domains in plates, and some unexpected contrast could be explained by double diffraction due to overlapping phases.

The Development of an In-Situ TEM Technique for Studying Corrosion Behavior as Applied to Zirconium-Based Alloys

Science.gov (United States)

Harlow, Wayne

Zirconium-based alloys are a commonly used material for nuclear fuel rod cladding, due to its low neutron cross section and good corrosion properties. However, corrosion is still a limiting factor in fuel rod lifespan, which restricts burn up levels, and thus efficiency, that can be achieved. While long-term corrosion behavior has been studied through both reactor and autoclave samples, the oxide nucleation and growth behavior has not been extensively studied. This work develops a new technique to study the initial stages of corrosion in zirconium-based alloys and the microstructural effects on this process by developing an environmental cell system for the TEM. Nanoscale oxidation parameters are developed, as is a new FIB technique to support this method. Precession diffraction is used in conjunction with in-situ TEM to observe the initial stages of corrosion in these alloys, and oxide thickness is estimated using low-loss EELS. In addition, the stress stabilization of tetragonal ZrO 2 is explored in the context of sample preparation for TEM. It was found that in-situ environmental TEM using an environmental cell replicates the oxidation behavior observed in autoclaved samples in both oxide structure and phases. Utilizing this technique, it was shown that cracking of the oxide layer in zirconium-based alloys is related to oxide relaxation, and not thermal changes. The effect of secondary phase particles on oxidation behavior did not present significant results, however a new method for studying initial oxidation rates using low-loss EELS was developed.

In Situ TEM Multi-Beam Ion Irradiation as a Technique for Elucidating Synergistic Radiation Effects

Energy Technology Data Exchange (ETDEWEB)

Taylor, Caitlin; Bufford, Daniel; Muntifering, Brittany; Senor, David; Steckbeck, Mackenzie; Davis, Justin; Doyle, Barney; Buller, Daniel; Hattar, Khalid

2017-09-29

Materials designed for nuclear reactors undergo microstructural changes resulting from a combination of several environmental factors, including neutron irradiation damage, gas accumulation and elevated temperatures. Typical ion beam irradiation experiments designed for simulating a neutron irradiation environment involve irradiating the sample with a single ion beam and subsequent characterization of the resulting microstructure, often by transmission electron microscopy (TEM). This method does not allow for examination of microstructural effects due to simultaneous gas accumulation and displacement cascade damage, which occurs in a reactor. Sandia’s in situ ion irradiation TEM (I3TEM) offers the unique ability to observe microstructural changes due to irradiation damage caused by concurrent multi-beam ion irradiation in real time. This allows for time-dependent microstructure analysis. A plethora of additional in situ stages can be coupled with these experiments, e.g., for more accurately simulating defect kinetics at elevated reactor temperatures. This work outlines experiments showing synergistic effects in Au using in situ ion irradiation with various combinations of helium, deuterium and Au ions, as well as some initial work on materials utilized in tritium-producing burnable absorber rods (TPBARs): zirconium alloys and LiAlO2.

In Situ TEM Multi-Beam Ion Irradiation as a Technique for Elucidating Synergistic Radiation Effects

Directory of Open Access Journals (Sweden)

Caitlin Anne Taylor

2017-09-01

Full Text Available Materials designed for nuclear reactors undergo microstructural changes resulting from a combination of several environmental factors, including neutron irradiation damage, gas accumulation and elevated temperatures. Typical ion beam irradiation experiments designed for simulating a neutron irradiation environment involve irradiating the sample with a single ion beam and subsequent characterization of the resulting microstructure, often by transmission electron microscopy (TEM. This method does not allow for examination of microstructural effects due to simultaneous gas accumulation and displacement cascade damage, which occurs in a reactor. Sandia’s in situ ion irradiation TEM (I3TEM offers the unique ability to observe microstructural changes due to irradiation damage caused by concurrent multi-beam ion irradiation in real time. This allows for time-dependent microstructure analysis. A plethora of additional in situ stages can be coupled with these experiments, e.g., for more accurately simulating defect kinetics at elevated reactor temperatures. This work outlines experiments showing synergistic effects in Au using in situ ion irradiation with various combinations of helium, deuterium and Au ions, as well as some initial work on materials utilized in tritium-producing burnable absorber rods (TPBARs: zirconium alloys and LiAlO2.

High-resolution TEM microscopy study of the creep behaviour of carbon-based cathode materials

Energy Technology Data Exchange (ETDEWEB)

Wang, Wei, E-mail: wwlyzwkj@126.com [College of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023 (China); Collaborative Innovation Center of Nonferrous Metals Henan Province, Luoyang 471023 (China); Chen, Weijie [College of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023 (China); Collaborative Innovation Center of Nonferrous Metals Henan Province, Luoyang 471023 (China); Gu, Wanduo [Collaborative Innovation Center of Nonferrous Metals Henan Province, Luoyang 471023 (China)

2017-02-27

Creep is in close relationship with the materials deterioration and deformation of the cathodes in aluminum reduction cells. The purpose of this work is to obtain the creep mechanism of the carbon cathode for aluminum electrolysis. A modified Rapoport equipment was used for measuring the creep strain of the semi-graphitic cathodes during aluminum electrolysis with CR=2.5 and at temperature of 945 ℃. The arrangement of carbon atom has been studied after hexagonal graphite converting into rhombohedral graphite during aluminum electrolysis by XRD and high-resolution transmission electron microscopy (HRTEM). The creep deformation of the carbon cathode has a close relationship with the mobile dislocation walls. These results will be helpful in controlling the cathode quality and its performance in aluminum reduction cells.

Aerosol midlatitude cyclone indirect effects in observations and high-resolution simulations

Directory of Open Access Journals (Sweden)

D. T. McCoy

2018-04-01

Full Text Available Aerosol–cloud interactions are a major source of uncertainty in inferring the climate sensitivity from the observational record of temperature. The adjustment of clouds to aerosol is a poorly constrained aspect of these aerosol–cloud interactions. Here, we examine the response of midlatitude cyclone cloud properties to a change in cloud droplet number concentration (CDNC. Idealized experiments in high-resolution, convection-permitting global aquaplanet simulations with constant CDNC are compared to 13 years of remote-sensing observations. Observations and idealized aquaplanet simulations agree that increased warm conveyor belt (WCB moisture flux into cyclones is consistent with higher cyclone liquid water path (CLWP. When CDNC is increased a larger LWP is needed to give the same rain rate. The LWP adjusts to allow the rain rate to be equal to the moisture flux into the cyclone along the WCB. This results in an increased CLWP for higher CDNC at a fixed WCB moisture flux in both observations and simulations. If observed cyclones in the top and bottom tercile of CDNC are contrasted it is found that they have not only higher CLWP but also cloud cover and albedo. The difference in cyclone albedo between the cyclones in the top and bottom third of CDNC is observed by CERES to be between 0.018 and 0.032, which is consistent with a 4.6–8.3 Wm−2 in-cyclone enhancement in upwelling shortwave when scaled by annual-mean insolation. Based on a regression model to observed cyclone properties, roughly 60 % of the observed variability in CLWP can be explained by CDNC and WCB moisture flux.

Comet Shoemaker-Levy 9/Jupiter collision observed with a high resolution speckle imaging system

Energy Technology Data Exchange (ETDEWEB)

Gravel, D. [Lawrence Livermore National Lab., CA (United States)

1994-11-15

During the week of July 16, 1994, comet Shoemaker-Levy 9, broken into 20 plus pieces by tidal forces on its last orbit, smashed into the planet Jupiter, releasing the explosive energy of 500 thousand megatons. A team of observers from LLNL used the LLNL Speckle Imaging Camera mounted on the University of California`s Lick Observatory 3 Meter Telescope to capture continuous sequences of planet images during the comet encounter. Post processing with the bispectral phase reconstruction algorithm improves the resolution by removing much of the blurring due to atmospheric turbulence. High resolution images of the planet surface showing the aftermath of the impact are probably the best that were obtained from any ground-based telescope. We have been looking at the regions of the fragment impacts to try to discern any dynamic behavior of the spots left on Jupiter`s cloud tops. Such information can lead to conclusions about the nature of the comet and of Jupiter`s atmosphere. So far, the Hubble Space Telescope has observed expanding waves from the G impact whose mechanism is enigmatic since they appear to be too slow to be sound waves and too fast to be gravity waves, given the present knowledge of Jupiter`s atmosphere. Some of our data on the G and L impact region complements the Hubble observations but, so far, is inconclusive about spot dynamics.

From Nanoparticles to Process An Aberration Corrected TEM Study of Fischer Tropsch Catalysts at Various Steps of the Process

International Nuclear Information System (INIS)

Braidy, N.; Blanchard, J.; Abatzoglou, N.; Andrei, C.

2011-01-01

χThe nanostructure of Fischer-Tropsch (FT) Fe carbides are investigated using aberration-corrected high-resolution transmission electron microscopy (TEM). The plasma-generated Fe carbides are analyzed just after synthesis, following reduction via a H2 treatment step and once used as FT catalyst and deactivated. The as-produced nanoparticles (NPs) are seen to be abundantly covered with graphitic and amorphous carbon. Using the extended information limit from the spherical aberration-corrected TEM, the NPs could be indexed as a mixture of NPs in the θ-Fe 3 C and χ-Fe 5 C 2 phases. The reduction treatment exposed the NPs by removing most of the carbonaceous speSubscript textcies while retaining the χ-Fe 5 C 2 . Fe-carbides NPs submitted to conditions typical to FT synthesis develop a Fe3O4 shell which eventually consumes the NPs up to a point where 3-4 nm residual carbide is left at the center of the particle. Subscript textVarious mechanisms explaining the formation of such a microstructure are discussed. (author)

SIMS and TEM study on oxide characteristics of Zircaloy

International Nuclear Information System (INIS)

Jung, Y. H.; Baek, J. H.; Kim, S. J.; Kim, K. H.; Choi, B. K.; Jung, Y. H.

1998-01-01

Long-term corrosion test, SIMS analysis, and TEM study were carried out to investigate the corrosion characteristics and corrosion mechanism of Zircaloy-4 in LiOH solution. The corrosion tests were performed in alkali solutions at 350 deg C for 500days. SIMS analysis was performed for the specimens prepared to have an equal oxide thickness to measure the cation content. TEM studies on the samples formed in various alkali solutions were also conducted. Based on the corrosion test, SIMS analysis, and TEM study, the cation is considered to control the corrosion in LiOH solution and its effect is dependent on the concentration of alkali and the oxide thickness. The slight acceleration of corrosion rate at a low concentration is thought to be caused by the cation incorporation into oxide while the significant acceleration at a high concentration is due to the transformation of oxide microstructure that would be induced by the cation incorporation

Inverse transformation algorithm of transient electromagnetic field and its high-resolution continuous imaging interpretation method

International Nuclear Information System (INIS)

Qi, Zhipeng; Li, Xiu; Lu, Xushan; Zhang, Yingying; Yao, Weihua

2015-01-01

We introduce a new and potentially useful method for wave field inverse transformation and its application in transient electromagnetic method (TEM) 3D interpretation. The diffusive EM field is known to have a unique integral representation in terms of a fictitious wave field that satisfies a wave equation. The continuous imaging of TEM can be accomplished using the imaging methods in seismic interpretation after the diffusion equation is transformed into a fictitious wave equation. The interpretation method based on the imaging of a fictitious wave field could be used as a fast 3D inversion method. Moreover, the fictitious wave field possesses some wave field features making it possible for the application of a wave field interpretation method in TEM to improve the prospecting resolution.Wave field transformation is a key issue in the migration imaging of a fictitious wave field. The equation in the wave field transformation belongs to the first class Fredholm integration equation, which is a typical ill-posed equation. Additionally, TEM has a large dynamic time range, which also facilitates the weakness of this ill-posed problem. The wave field transformation is implemented by using pre-conditioned regularized conjugate gradient method. The continuous imaging of a fictitious wave field is implemented by using Kirchhoff integration. A synthetic aperture and deconvolution algorithm is also introduced to improve the interpretation resolution. We interpreted field data by the method proposed in this paper, and obtained a satisfying interpretation result. (paper)

High resolution, high speed ultrahigh vacuum microscopy

International Nuclear Information System (INIS)

Poppa, Helmut

2004-01-01

The history and future of transmission electron microscopy (TEM) is discussed as it refers to the eventual development of instruments and techniques applicable to the real time in situ investigation of surface processes with high resolution. To reach this objective, it was necessary to transform conventional high resolution instruments so that an ultrahigh vacuum (UHV) environment at the sample site was created, that access to the sample by various in situ sample modification procedures was provided, and that in situ sample exchanges with other integrated surface analytical systems became possible. Furthermore, high resolution image acquisition systems had to be developed to take advantage of the high speed imaging capabilities of projection imaging microscopes. These changes to conventional electron microscopy and its uses were slowly realized in a few international laboratories over a period of almost 40 years by a relatively small number of researchers crucially interested in advancing the state of the art of electron microscopy and its applications to diverse areas of interest; often concentrating on the nucleation, growth, and properties of thin films on well defined material surfaces. A part of this review is dedicated to the recognition of the major contributions to surface and thin film science by these pioneers. Finally, some of the important current developments in aberration corrected electron optics and eventual adaptations to in situ UHV microscopy are discussed. As a result of all the path breaking developments that have led to today's highly sophisticated UHV-TEM systems, integrated fundamental studies are now possible that combine many traditional surface science approaches. Combined investigations to date have involved in situ and ex situ surface microscopies such as scanning tunneling microscopy/atomic force microscopy, scanning Auger microscopy, and photoemission electron microscopy, and area-integrating techniques such as x-ray photoelectron

3D Observation of GEMS by Electron Tomography

Science.gov (United States)

Matsuno, Junya; Miyake, Akira; Tsuchiyama, Akira; Nakamura-Messenger, Keiko; Messenger, Scott

2014-01-01

Amorphous silicates in chondritic porous interplanetary dust particles (CP-IDPs) coming from comets are dominated by glass with embedded metal and sulfides (GEMS). GEMS grains are submicron-sized rounded objects (typically 100-500) nm in diameter) with anaometer-sized (10-50 nm) Fe-Ni metal and sulfide grains embedded in an amorphous silicate matrix. Several formation processes for GEMS grains have been proposed so far, but these models are still being debated [2-5]. Bradley et al. proposed that GEMS grains are interstellar silicate dust that survived various metamorphism or alteration processes in the protoplanetary disk and that they are amorphiation products of crystalline silicates in the interstellar medium by sputter-deposition of cosmic ray irradiation, similar to space weathering [2,4]. This consideration is based on the observation of nano-sized crystals (approximately 10 nm) called relict grains in GEMS grains and their shapes are pseudomorphs to the host GEMS grains. On the other hand, Keller and Messenger proposed that most GEMS formed in the protoplanetary disk as condensates from high temperature gas [3,5]. This model is based on the fact that most GEMS grains have solar isotopic compositions and have extremely heterogeneous and non-solar elemental compositions. Keller and Messenger (2011) also reported that amorphous silicates in GEMS grains are surrounded by sulfide grains, which formed as sulfidization of metallic iron grains located on the GEMS surface. The previous studies were performed with 2D observation by using transmission electron microscopy (TEM) or scanning TEM (STEM). In order to understand the structure of GEMS grains described above more clearly, we observed 3D structure of GEMS grains by electron tomography using a TEM/STEM (JEM-2100F, JEOL) at Kyoto University. Electron tomography gives not only 3D structures but also gives higher spatial resolution (approximately a few nm) than that in conventional 2D image, which is restricted by

Prospects for realizing a sub-A sub-eV resolution EFTEM

International Nuclear Information System (INIS)

Rose, H.

1999-01-01

The arrangement of a sub-Angstrom and sub-eV resolution energy filtering transmission electron microscope (EFTEM) is outlined. This ideal future analytical microscope is a combination of a scanning transmission (STEM) and a corrected fixed-beam transmission electron microscope (TEM) and operates at voltages between 150 and 300 kV. The ultra resolution EFTEM will consist of a field emission gun followed by a monochromator yielding an energy width below 0.2 eV. The condenser system provides Koehler illumination for the TEM mode and a spot size of about 0.2 nm for the STEM mode. The spherically corrected aplanatic objective lens consists of a coma-free round lens and an integrated hexapole corrector. The formation of the energy loss spectrum is performed by the ultradispersive aberration-free MANDOLINE filter. The filtered intermediate image or the energy loss spectrum, respectively, are imaged onto a Charged-Coupled Device (CCD) array with variable magnification by means of a distortion-free projector system consisting of several quadrupoles and octupoles. For obtaining sub-Angstrom resolution the parasitic mechanical and electromagnetic instabilities must be reduced to such an extent that the information limit is pushed below 0.06 nm. All requirements can be met at the present state of technology. (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)

Generation of a microelectron beam by an intense short pulse laser in the TEM(1, 0) + TEM(0, 1) mode in vacuum

International Nuclear Information System (INIS)

Miyazaki, Shuji; Kawata, Shigeo; Kong, Qing; Miyauchi, Koichi; Sakai, Kei; Hasumi, Shotaro; Sonobe, Ryo; Kikuchi, Takashi

2005-01-01

The generation of a high energy microelectron bunch in vacuum by an intense short pulse laser in the TEM(1, 0) + TEM(0, 1) mode is investigated in this paper numerically and analytically. A focused short pulse laser in the TEM(1, 0) + TEM(0, 1) mode has a confinement effect on electrons in the transverse direction due to the transverse ponderomotive force, and at the same time the electrons are accelerated and compressed longitudinally by a longitudinal electric field. In our three-dimensional particle simulations, the maximum kinetic energy of electrons reaches 455 MeV, the maximum density is 3.87 x 10 10 cm -3 , and the normalized transverse and longitudinal rms emittances of accelerated electrons are of the order of 10 -6 m rad at the following parameter values: a 0 = eE 0 /(m e ω c) = 10 (where a 0 is the dimensionless parameter of the laser amplitude, e and m e are the electron charge and rest mass, respectively, E 0 is the laser amplitude, ω the angular frequency of the laser and c the speed of light in vacuum), a laser wavelength λ = 0.8 μm, laser spot size 20λ, laser pulse length 5λ and initial electron velocity 0.99c. Moreover, the transverse and longitudinal sizes of the compressed electron bunch are about 600λ and 10λ, respectively. In this paper, we also present a scaling law of the maximum electron energy. The estimated results of the maximum electron energy coincide well with the simulation results

Mistic winds, a microsatellite constellation approach to high-resolution observations of the atmosphere using infrared sounding and 3d winds measurements

Science.gov (United States)

Maschhoff, K. R.; Polizotti, J. J.; Aumann, H. H.; Susskind, J.

2016-10-01

MISTiC Winds is an approach to improve short-term weather forecasting based on a miniature high resolution, wide field, thermal emission spectrometry instrument that will provide global tropospheric vertical profiles of atmospheric temperature and humidity at high (3-4 km) horizontal and vertical ( 1 km) spatial resolution. MISTiC's extraordinarily small size, payload mass of less than 15 kg, and minimal cooling requirements can be accommodated aboard a 27U-class CubeSat or an ESPA-Class micro-satellite. Low fabrication and launch costs enable a LEO sunsynchronous sounding constellation that would collectively provide frequent IR vertical profiles and vertically resolved atmospheric motion vector wind observations in the troposphere. These observations are highly complementary to present and emerging environmental observing systems, and would provide a combination of high vertical and horizontal resolution not provided by any other environmental observing system currently in operation. The spectral measurements that would be provided by MISTiC Winds are similar to those of NASA's AIRS that was built by BAE Systems and operates aboard the AQUA satellite. These new observations, when assimilated into high resolution numerical weather models, would revolutionize short-term and severe weather forecasting, save lives, and support key economic decisions in the energy, air transport, and agriculture arenas-at much lower cost than providing these observations from geostationary orbit. In addition, this observation capability would be a critical tool for the study of transport processes for water vapor, clouds, pollution, and aerosols. Key remaining technical risks are being reduced through laboratory and airborne testing under NASA's Instrument Incubator Program.

A TEM Study on the Ti-Alloyed Grey Iron

DEFF Research Database (Denmark)

Moumeni, Elham; Tiedje, Niels Skat; Grumsen, Flemming Bjerg

2014-01-01

The microstructure of graphite flakes in titanium alloyed cast iron is studied using electron microscopy techniques. Dual beam SEM/FIB has been used for TEM sample preparation. A TEM study has been carried out on graphite flakes in grey cast iron using selected area electron diffraction. Based...... and that there is a high proportion of twins in the fine grained graphite. It appears that twinning and stacking faults are involved in the fine grained structure of the graphite. It is discussed how Ti addition affect crystal growth and may lead to formation of superfine graphite....

Practical aspects of the use of the X(2) holder for HRTEM-quality TEM sample preparation by FIB.

Science.gov (United States)

van Mierlo, Willem; Geiger, Dorin; Robins, Alan; Stumpf, Matthias; Ray, Mary Louise; Fischione, Paul; Kaiser, Ute

2014-12-01

The X(2) holder enables the effective production of thin, electron transparent samples for high-resolution transmission electron microscopy (HRTEM). Improvements to the X(2) holder for high-quality transmission electron microscopy (TEM) sample preparation are presented in this paper. We discuss the influence of backscattered electrons (BSE) from the sample holder in determining the lamella thickness in situ and demonstrate that a significant improvement in thickness determination can be achieved by comparatively simple means using the relative BSE intensity. We show (using Monte Carlo simulations) that by taking into account the finite collection angle of the electron backscatter detector, an approximately 20% underestimation of the lamella thickness in a silicon sample can be avoided. However, a correct thickness determination for light-element lamellas still remains a problem with the backscatter method; we introduce a more accurate method using the energy dispersive X-ray spectroscopy (EDX) signal for in situ thickness determination. Finally, we demonstrate how to produce a thin lamella with a nearly damage-free surface using the X(2) holder in combination with sub-kV polishing in the Fischione Instruments׳ NanoMill(®) TEM specimen preparation system. Copyright © 2014 Elsevier B.V. All rights reserved.

A vision for an ultra-high resolution integrated water cycle observation and prediction system

Science.gov (United States)

Houser, P. R.

2013-05-01

Society's welfare, progress, and sustainable economic growth—and life itself—depend on the abundance and vigorous cycling and replenishing of water throughout the global environment. The water cycle operates on a continuum of time and space scales and exchanges large amounts of energy as water undergoes phase changes and is moved from one part of the Earth system to another. We must move toward an integrated observation and prediction paradigm that addresses broad local-to-global science and application issues by realizing synergies associated with multiple, coordinated observations and prediction systems. A central challenge of a future water and energy cycle observation strategy is to progress from single variable water-cycle instruments to multivariable integrated instruments in electromagnetic-band families. The microwave range in the electromagnetic spectrum is ideally suited for sensing the state and abundance of water because of water's dielectric properties. Eventually, a dedicated high-resolution water-cycle microwave-based satellite mission may be possible based on large-aperture antenna technology that can harvest the synergy that would be afforded by simultaneous multichannel active and passive microwave measurements. A partial demonstration of these ideas can even be realized with existing microwave satellite observations to support advanced multivariate retrieval methods that can exploit the totality of the microwave spectral information. The simultaneous multichannel active and passive microwave retrieval would allow improved-accuracy retrievals that are not possible with isolated measurements. Furthermore, the simultaneous monitoring of several of the land, atmospheric, oceanic, and cryospheric states brings synergies that will substantially enhance understanding of the global water and energy cycle as a system. The multichannel approach also affords advantages to some constituent retrievals—for instance, simultaneous retrieval of vegetation

High Spectral Resolution Observation of the Soft Diffuse X-ray Background in the Direction of the Galactic Anti-Center

Science.gov (United States)

Wulf, Dallas; Eckart, Mega E.; Galeazzi, Massimiliano; Jaeckel, Felix; Kelley, Richard L.; Kilbourne, Caroline A.; McCammon, Dan; Morgan, Kelsey M.; Porter, Frederick S.; Szymkowiak, Andrew E.

2018-01-01

High spectral resolution observations in the soft x-rays are necessary for understanding and modelling the hot component of the interstellar medium and its contribution to the Soft X-ray Background (SXRB). This extended source emission cannot be resolved with most wavelength dispersive spectrometers, making energy dispersive microcalorimeters the ideal choice for these observations. We present here the analysis of the most recent sounding rocket flight of the University of Wisconsin-Madison/Goddard Space Flight Center X-ray Quantum Calorimeter (XQC), a large area silicon thermistor microcalorimeter. This 111 second observation integrates a nearly 1 steradian field of view in the direction of the galactic anti-center (l, b = 165°, -5°) and features ~5 eV spectral resolution below 1 keV. Direct comparison will also be made to the previous, high-latitude observations.

The High Visible Resolution (HVR) instrument of the spot ground observation satellite

Science.gov (United States)

Otrio, G.

1980-01-01

Two identical high resolution cameras, capable of attaining a track width of 116 km in an almost vertical line of sight from the two 60 km images of each instrument, will be carried on the initial mission of the space observation of Earth satellite (SPOT). Specifications for the instrument, including the telescope and CCD devices are summarized. The present status of development is described including the optical characteristics, structure and thermal control, detector assembly, electronic equipment, and calibration. SPOT mission objectives include the developments relating to soil use, the exploration of EART Earth resources, the discrimination of plant species, and cartography.

Constraints on Circumstellar Dust Grain Sizes from High Spatial Resolution Observations in the Thermal Infrared

Science.gov (United States)

Bloemhof, E. E.; Danen, R. M.; Gwinn, C. R.

1996-01-01

We describe how high spatial resolution imaging of circumstellar dust at a wavelength of about 10 micron, combined with knowledge of the source spectral energy distribution, can yield useful information about the sizes of the individual dust grains responsible for the infrared emission. Much can be learned even when only upper limits to source size are available. In parallel with high-resolution single-telescope imaging that may resolve the more extended mid-infrared sources, we plan to apply these less direct techniques to interpretation of future observations from two-element optical interferometers, where quite general arguments may be made despite only crude imaging capability. Results to date indicate a tendency for circumstellar grain sizes to be rather large compared to the Mathis-Rumpl-Nordsieck size distribution traditionally thought to characterize dust in the general interstellar medium. This may mean that processing of grains after their initial formation and ejection from circumstellar atmospheres adjusts their size distribution to the ISM curve; further mid-infrared observations of grains in various environments would help to confirm this conjecture.

In Situ TEM Creation of Nanowire Devices

DEFF Research Database (Denmark)

Alam, Sardar Bilal

Integration of silicon nanowires (SiNWs) as active components in devices requires that desired mechanical, thermal and electrical interfaces can be established between the nanoscale geometry of the SiNW and the microscale architecture of the device. In situ transmission electron microscopy (TEM),...

TEM characterization of nanodiamond thin films.

Energy Technology Data Exchange (ETDEWEB)

Qin, L.-C.; Zhou, D.; Krauss, A. R.; Gruen, D. M.; Chemistry

1998-05-01

The microstructure of thin films grown by microwave plasma-enhanced chemical vapor deposition (MPCVD) from fullerene C{sub 60} precursors has been characterized by scanning electron microscopy (SEM), selected-area electron diffraction (SAED), bright-field electron microscopy, high-resolution electron microscopy (HREM), and parallel electron energy loss spectroscopy (PEELS). The films are composed of nanosize crystallites of diamond, and no graphitic or amorphous phases were observed. The diamond crystallite size measured from lattice images shows that most grains range between 3-5 nm, reflecting a gamma distribution. SAED gave no evidence of either sp2-bonded glassy carbon or sp3-bonded diamondlike amorphous carbon. The sp2-bonded configuration found in PEELS was attributed to grain boundary carbon atoms, which constitute 5-10% of the total. Occasionally observed larger diamond grains tend to be highly faulted.

Effect of interparticle interactions on size determination of zirconia and silica based systems – A comparison of SAXS, DLS, BET, XRD and TEM

Science.gov (United States)

Pabisch, Silvia; Feichtenschlager, Bernhard; Kickelbick, Guido; Peterlik, Herwig

2012-01-01

The aim of this work is a systematic comparison of size characterisation methods for two completely different model systems of oxide nanoparticles, i.e. amorphous spherical silica and anisotropic facet-shaped crystalline zirconia. Size and/or size distribution were determined in a wide range from 5 to 70 nm using small-angle X-ray scattering (SAXS), dynamic light scattering (DLS), nitrogen sorption (BET), X-ray diffraction (XRD) and transmission electron microscopy (TEM). A nearly perfect coincidence was observed only for SAXS and TEM for both types of particles. For zirconia nanoparticles considerable differences between different measurement methods were observed. PMID:22347721

TEM study of internal oxidation in an ODS-Eurofer alloy

International Nuclear Information System (INIS)

Klimenkov, M.; Lindau, R.; Moeslang, A.

2009-01-01

Analytical TEM investigations of samples from an oxide dispersion-strengthened Eurofer batch show the formation of new type of precipitates of Fe-Cr-V-O composition and a size of 40-250 nm. Structural HRTEM analysis reveals that the precipitates consist of (Mn,Fe)(Cr,V) 2 O 4 manganese chromium oxide of spinel structure. In some cases, the inclusions order along lines that can reach more than ten micrometers in length. Such lines of large particles might have a negative influence on the mechanical properties of the steel, as was observed. It is assumed that they form by internal oxidation during hot isostatic pressing due to the high oxygen content of the mechanically alloyed powder.

Geoelectrical characterization by joint inversion of VES/TEM in Paraná basin, Brazil

Science.gov (United States)

Bortolozo, C. A.; Couto, M. A.; Almeida, E. R.; Porsani, J. L.; Santos, F. M.

2012-12-01

For many years electrical (DC) and transient electromagnetic (TEM) soundings have been used in a great number of environmental, hydrological and mining exploration studies. The data of both methods are interpreted usually by individual 1D models resulting in many cases in ambiguous models. This can be explained by how the two different methodologies sample the subsurface. The vertical electrical sounding (VES) is good on marking very resistive structures, while the transient electromagnetic sounding (TEM) is very sensitive to map conductive structures. Another characteristic is that VES is more sensitive to shallow structures, while TEM soundings can reach deeper structures. A Matlab program for joint inversion of VES and TEM soundings, by using CRS algorithm was developed aiming explore the best of the both methods. Initially, the algorithm was tested with synthetic data and after it was used to invert experimental data from Paraná sedimentary basin. We present the results of a re-interpretation of 46 VES/TEM soundings data set acquired in Bebedouro region in São Paulo State - Brazil. The previous interpretation was based in geoelectrical models obtained by single inversion of the VES and TEM soundings. In this work we present the results with single inversion of VES and TEM sounding inverted by the Curupira Program and a new interpretation based in the joint inversion of both methodologies. The goal is increase the accuracy in determining the underground structures. As a result a new geoelectrical model of the region is obtained.

High Resolution Transmission Electron Microscope Observation of Zero-Strain Deformation Twinning Mechanisms in Ag

Science.gov (United States)

Liu, L.; Wang, J.; Gong, S. K.; Mao, S. X.

2011-04-01

We have observed a new deformation-twinning mechanism using the high resolution transmission electron microscope in polycrystalline Ag films, zero-strain twinning via nucleation, and the migration of a Σ3{112} incoherent twin boundary (ITB). This twinning mechanism produces a near zero macroscopic strain because the net Burgers vectors either equal zero or are equivalent to a Shockley partial dislocation. This observation provides new insight into the understanding of deformation twinning and confirms a previous hypothesis: detwinning could be accomplished via the nucleation and migration of Σ3{112} ITBs. The zero-strain twinning mechanism may be unique to low staking fault energy metals with implications for their deformation behavior.

Characterization of mineral particles in winter fog of Beijing analyzed by TEM and SEM.

Science.gov (United States)

Li, Weijun; Shao, Longyi

2010-02-01

Aerosol samples were collected during winter fog and nonfog episodes in Beijing. Transmission electron microscopy (TEM) and scanning electron microscopy (SEM) were applied to study morphologies, sizes, and compositions of aerosol particles. TEM observation indicates that most mineral particles collected in fog episode are scavenged in fog droplets. Number-size distributions of mineral particles collected in fog and nonfog episodes show two main peaks at the ranges of 0.1-0.3 and 1-2.5 microm, respectively. Based on their major compositions, mineral particles mainly include Si-rich, Ca-rich, and S-rich. Average S/Ca ratio of mineral particles collected in fog episode is 6.11, being eight times higher than that in nonfog episodes. Development mechanism of individual mineral particles in fog droplets is proposed. It is suggested that mineral particles with abundant alkaline components (e.g., "Ca-rich" particles) occurred in air should alleviate acidic degree of fog and contribute to complexity of fog droplets in Beijing.

Determination of the activation energy in a cast aluminium alloy by TEM and DSC

International Nuclear Information System (INIS)

Ovono Ovono, D.; Guillot, I.; Massinon, D.

2007-01-01

The precipitation behaviour and microstructure development of the A319 alloy during ageing were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM and STEM). During T5 treatment, θ' precipitates with an average size of about 18 nm were observed by TEM. The precipitate sizes increased with ageing temperature and attained an average size of 107 nm. In addition, there was a linear relationship between precipitate growth temperature and the cube of the precipitate size. This indicates that precipitate growth of the A319 alloy belongs to a thermal activated process of the Arrhenius type. The activation energy for the precipitate growth was calculated to be 140.4 ± 13.3 kJ/mol. However, under continuous heating conditions, the activation energy for the precipitate growth obtained by Kissinger plot was determined to be 119.5 ± 8.3 kJ/mol. Allowing for experimental error, both values are comparable and are related to the diffusion of Cu and/or Si in Al

APFIM and TEM investigations of precipitation in rapidly solidified 316 stainless steel

International Nuclear Information System (INIS)

Wisutmethangoon, S.; Kelly, T.F.; Flinn, J.E.; Camus, P.P.

1998-01-01

316 stainless steel has been rapid solidification-processed (RSP) by gas atomization and hot extrusion of the powder with the intent of improving the mechanical properties through fine-scale precipitation. Vanadium, nitrogen and oxygen have been introduced intentionally as alloying elements for this purpose. The yield strength after solution heat treatment of the RSP alloy is 450 MPa. By ageing at 600 C for 1000 h, the yield strength increases to 615 MPa with little loss of ductility (53% reduction of area). The ultimate tensile strength after cold work and ageing is 922 MPa. The morphology and composition of the precipitates in this steel have been investigated using APFIM and TEM techniques in order understand the origin of the high strength. A high numbered density (∼2 x 10 21 m -3 ) of 25 nm plate-like precipitates was observed with TEM in an aged specimen. The composition of these precipitates was analyzed using APFIM techniques, and was found to be a complex nitride of Cr, V, Fe, Ni and Mo. This nitride precipitate was not found in an unaged specimen of this alloy. These precipitates are responsible for improving mechanical properties by dispersion strengthening. (orig.)

Sub-Angstrom Atomic-Resolution Imaging of Heavy Atoms to Light Atoms

Energy Technology Data Exchange (ETDEWEB)

O' Keefe, Michael A.; Shao-Horn, Yang

2003-05-23

Three decades ago John Cowley and his group at ASU achieved high-resolution electron microscope images showing the crystal unit cell contents at better than 4Angstrom resolution. Over the years, this achievement has inspired improvements in resolution that have enabled researchers to pinpoint the positions of heavy atom columns within the cell. More recently, this ability has been extended to light atoms as resolution has improved. Sub-Angstrom resolution has enabled researchers to image the columns of light atoms (carbon, oxygen and nitrogen) that are present in many complex structures. By using sub-Angstrom focal-series reconstruction of the specimen exit surface wave to image columns of cobalt, oxygen, and lithium atoms in a transition metal oxide structure commonly used as positive electrodes in lithium rechargeable batteries, we show that the range of detectable light atoms extends to lithium. HRTEM at sub-Angstrom resolution will provide the essential role of experimental verification for the emergent nanotech revolution. Our results foreshadow those to be expected from next-generation TEMs with Cs-corrected lenses and monochromated electron beams.

Recent advances in cryo-TEM imaging of soft lipid nanoparticles

DEFF Research Database (Denmark)

Helvig, Shen Yu; Mat Azmi, Intan Diana Binti; Moghimi, Seyed Moien

2015-01-01

Cryo-transmission electron microscopy (Cryo-TEM), and its technological variations thereof, have become a powerful tool for detailed morphological characterization and 3D tomography of soft lipid and polymeric nanoparticles as well as biological materials such as viruses and DNA without chemical...... fixation. Here, we review and discuss recent advances in Cryo-TEM analysis of lipid-based drug nanocarriers with particular emphasis on morphological and internal nanostructure characterization of lyotropic liquid crystalline nanoparticles such as cubosomes and hexosomes....

Specific, sensitive, high-resolution detection of protein molecules in eukaryotic cells using metal-tagging transmission electron microscopy

Science.gov (United States)

Risco, Cristina; Sanmartín-Conesa, Eva; Tzeng, Wen-Pin; Frey, Teryl K.; Seybold, Volker; de Groot, Raoul J.

2012-01-01

Summary More than any other methodology, transmission electron microscopy (TEM) has contributed to our understanding of the architecture and organization of cells. With current detection limits approaching atomic resolution, it will ultimately become possible to ultrastructurally image intracellular macromolecular assemblies in situ. Presently, however, methods to unambiguously identify proteins within the crowded environment of the cell’s interior are lagging behind. We describe a novel approach, metal-tagging TEM (METTEM) that allows detection of intracellular proteins in mammalian cells with high specificity, exceptional sensitivity and at molecular scale resolution. In live cells treated with gold salts, proteins bearing a small metal-binding tag will form 1-nm gold nanoclusters, readily detectable in electron micrographs. The applicability and strength of METTEM is demonstrated by a study of Rubella virus replicase and capsid proteins, which revealed virus-induced cell structures not seen before. PMID:22579245

ANALISIS PARAMETER JARINGAN HSDPA KONDISI INDOOR DENGAN TEMS INVESTIGATION DAN G-NETTRACK PRO

Directory of Open Access Journals (Sweden)

Dewa Made Mahendra Yudha

2016-03-01

Full Text Available Penggunaan teknologi dalam sistem komunikasi bergerak sudah berkembang cukup pesat. Salah satu contohnya ada teknologi HSDPA. Pihak provider biasanya melakukan metode walk test untuk mengecek kekuatan sinyal dengan menggunakan software TEMS Investigtions. Dengan kemajuannya Teknologi walk test dapat diterapkan dengan lebih mudah yaitu menggunakan perangkat android yang sudah terinstal aplikasi G-Net track Pro. Pada penelitian ini, akan menggunakan tahapan sesuai alur yang ada pada metode penelitian yaitu dimulai dengan melakukan pengukuran berdasarkan jarak dengan membandingkan software TEMS Investigations dan G-NET TRACK PRO dengan parameter RSCP dan Ec/No. Setelah dilakukan pengukuran kemudian akan dilanjutkan dengan menganalisa antara hubungan parameter RSCP dan Ec/No menggunakan TEMS Investigations dan G-Net Pro. kemudian dilanjutkan menggunakan perhitungan teoritis parameter RSCP. Dari hasil pengukuran diproleh pada lantai I antena 1-1 pada titik jarak 5 meter parameter RSCP dengan TEMS Investigation memiliki nilai -75 dBm sedangkan dari G-Net Track Pro memiliki nilai -83 dBm. Pada parameter Ec/No dengan TEMS Investigation memiliki nilai -6 dB dan G_Net Track memiliki nilai -5 dB. Dapat disimpulkan bahwa aplikasi G-NetTrack Pro mampu menampilkan parameter yang dibutuhkan akan tetapi tidak sedetail TEMS investigation sehingga untuk proses pembelajaran dan pengenalan walk test aplikasi G-Net track Pro dapat digunakan.

High-Resolution Infrared Spectroscopic Observations of the Upper Scorpius Eclipsing Binary EPIC 203868608

Science.gov (United States)

Johnson, Marshall C.; Mace, Gregory N.; Kim, Hwihyun; Kaplan, Kyle; McLane, Jacob; Sokal, Kimberly R.

2017-06-01

EPIC 203868608 is a source in the ~10 Myr old Upper Scorpius OB association. Using K2 photometry and ground-based follow-up observations, David et al. (2016) found that it consists of two brown dwarfs with a tertiary object at a projected separation of ~20 AU; the former objects appear to be a double-lined eclipsing binary with a period of 4.5 days. This is one of only two known eclipsing SB2s where both components are below the hydrogen-burning limit. We present additional follow-up observations of this system from the IGRINS high-resolution near-infrared spectrograph at McDonald Observatory. Our measured radial velocities do not follow the orbital solution presented by David et al. (2016). Instead, our combined IGRINS plus literature radial velocity dataset appears to indicate a period significantly different than that of the eclipsing binary obvious from the K2 light curve. We will discuss possible scenarios to account for the conflicting observations of this system.

Characterization of TEM Moiré Patterns Originating from Two Monolayer Graphenes Grown on the Front and Back Sides of a Copper Substrate by CVD Method

Science.gov (United States)

Yamazaki, Kenji; Maehara, Yosuke; Gohara, Kazutoshi

2018-06-01

The number of layers affects the electronic properties of graphene owing to its unique band structure, called the Dirac corn. Raman spectroscopy is a key diagnostic tool for identifying the number of graphene layers and for determining their physical properties. Here, we observed moiré structures in transmission electron microscopy (TEM) observations; these are signature patterns in multilayer, although Raman spectra showed the typical intensity of the 2D/G peak in the monolayer. We also performed a multi-slice TEM image simulation to compare the 3D atomic structures of the two graphene membranes with experimental TEM images. We found that the experimental moiré image was constructed with a 9-12 Å interlayer distance between graphene membranes. This structure was constructed by transferring CVD-grown graphene films that formed on both sides of the Cu substrate at once.

New high-sensitivity, milliarcsecond resolution results from routine observations of lunar occultations at the ESO VLT

Science.gov (United States)

Richichi, A.; Fors, O.; Chen, W.-P.; Mason, E.

2010-11-01

Context. Lunar occultations (LO) are a very efficient and powerful technique that achieves the best combination of high angular resolution and sensitivity possible today at near-infrared wavelengths. Given that the events are fixed in time, that the sources are occulted randomly, and that the telescope use is minimal, the technique is very well suited for service mode observations. Aims: We have established a program of routine LO observations at the VLT observatory, especially designed to take advantage of short breaks available in-between other programs. We have used the ISAAC instrument in burst mode, capable of producing continuous read-outs at millisecond rates on a suitable subwindow. Given the random nature of the source selection, our aim has been primarily the investigation of a large number of stellar sources at the highest angular resolution in order to detect new binaries. Serendipitous results such as resolved sources and detection of circumstellar components were also anticipated. Methods: We have recorded the signal from background stars for a few seconds, around the predicted time of occultation by the Moon's dark limb. At millisecond time resolution, a characteristic diffraction pattern can be observed. Patterns for two or more sources superimpose linearly, and this property is used for the detection of binary stars. The detailed analysis of the diffraction fringes can be used to measure specific properties such as the stellar angular size and the presence of extended light sources such as a circumstellar shell. Results: We present a list of 191 stars for which LO data could be recorded and analyzed. Results include the detection of 16 binary and 2 triple stars, all but one of which were previously unknown. The projected angular separations are as small as 4 milliarcsec and magnitude differences as high as Δ K = 5.8 mag. Additionally we derive accurate angular diameters for 2 stars and resolve circumstellar emission around another one, also all

Application of High Resolution Air-Borne Remote Sensing Observations for Monitoring NOx Emissions

Science.gov (United States)

Souri, A.; Choi, Y.; Pan, S.; Curci, G.; Janz, S. J.; Kowalewski, M. G.; Liu, J.; Herman, J. R.; Weinheimer, A. J.

2017-12-01

Nitrogen oxides (NOx=NO+NO2) are one of the air pollutants, responsible for the formation of tropospheric ozone, acid rain and particulate nitrate. The anthropogenic NOx emissions are commonly estimated based on bottom-up inventories which are complicated by many potential sources of error. One way to improve the emission inventories is to use relevant observations to constrain them. Fortunately, Nitrogen dioxide (NO2) is one of the most successful detected species from remote sensing. Although many studies have shown the capability of using space-borne remote sensing observations for monitoring emissions, the insufficient sample number and footprint of current measurements have introduced a burden to constrain emissions at fine scales. Promisingly, there are several air-borne sensors collected for NASA's campaigns providing high spatial resolution of NO2 columns. Here, we use the well-characterized NO2 columns from the Airborne Compact Atmospheric Mapper (ACAM) onboard NASA's B200 aircraft into a 1×1 km regional model to constrain anthropogenic NOx emissions in the Houston-Galveston-Brazoria area. Firstly, in order to incorporate the data, we convert the NO2 slant column densities to vertical ones using a joint of a radiative transfer model and the 1x1 km regional model constrained by P3-B aircraft measurements. After conducting an inverse modeling method using the Kalman filter, we find the ACAM observations are resourceful at mitigating the overprediction of model in reproducing NO2 on regular days. Moreover, the ACAM provides a unique opportunity to detect an anomaly in emissions leading to strong air quality degradation that is lacking in previous works. Our study provides convincing evidence that future geostationary satellites with high spatial and temporal resolutions will give us insights into uncertainties associated with the emissions at regional scales.

TEM-EELS: A personal perspective

International Nuclear Information System (INIS)

Egerton, R.F.

2012-01-01

The development of electron energy-loss spectroscopy in a transmission electron microscope (TEM-EELS) is illustrated through personal anecdote, highlighting some of the basic principles, instrumentation and personalities involved. The current state of the art is reviewed, together with some challenges for the future. -- Highlights: ► The history of EELS instrumentation is reviewed in a lighthearted manner. ► The current state of the art is summarized, together with some future possibilities. ► A couple of related mathematical puzzles are offered as a challenge to the reader.

Conservation through payments for an ecosys- tem service?

African Journals Online (AJOL)

tem service? In his Spotlights ... functions” and “ecosystem services” are being ridiculed by the developments in ... high price as legal marketing would avoid various middlemen. ... Diagnostic participatif de la gestion des ressources naturelles.

High-resolution observation by double-biprism electron holography

International Nuclear Information System (INIS)

Harada, Ken; Tonomura, Akira; Matsuda, Tsuyoshi; Akashi, Tetsuya; Togawa, Yoshihiko

2004-01-01

High-resolution electron holography has been achieved by using a double-biprism interferometer implemented on a 1 MV field emission electron microscope. The interferometer was installed behind the first magnifying lens to narrow carrier fringes and thus enabled complete separation of sideband Fourier spectrum from center band in reconstruction process. Holograms of Au fine particles and single-crystalline thin films with the finest fringe spacing of 4.2 pm were recorded and reconstructed. The overall holography system including the reconstruction process performed well for holograms in which carrier fringes had a spacing of around 10 pm. High-resolution lattice images of the amplitude and phase were clearly reconstructed without mixing of the center band and sideband information. Additionally, entire holograms were recorded without Fresnel fringes normally generated by the filament electrode of the biprism, and the holograms were thus reconstructed without the artifacts caused by Fresnel fringes

Test for English Majors (TEM) in China

Science.gov (United States)

Jin, Yan; Fan, Jinsong

2011-01-01

The purpose of the Test for English Majors (TEM) is to measure the English proficiency of Chinese university undergraduates majoring in English Language and Literature and to examine whether these students meet the required levels of English language abilities as specified in the National College English Teaching Syllabus for English Majors…

Automated SEM and TEM sample preparation applied to copper/low k materials

Science.gov (United States)

Reyes, R.; Shaapur, F.; Griffiths, D.; Diebold, A. C.; Foran, B.; Raz, E.

2001-01-01

We describe the use of automated microcleaving for preparation of both SEM and TEM samples as done by SELA's new MC500 and TEMstation tools. The MC500 is an automated microcleaving tool that is capable of producing cleaves with 0.25 μm accuracy resulting in SEM-ready samples. The TEMstation is capable of taking a sample output from the MC500 (or from SELA's earlier MC200 tool) and producing a FIB ready slice of 25±5 μm, mounted on a TEM-washer and ready for FIB thinning to electron transparency for TEM analysis. The materials selected for the tool set evaluation mainly included the Cu/TaN/HOSP low-k system. The paper is divided into three sections, experimental approach, SEM preparation and analysis of HOSP low-k, and TEM preparation and analysis of Cu/TaN/HOSP low-k samples. For the samples discussed, data is presented to show the quality of preparation provided by these new automated tools.

TEM in situ cube-corner indentation analysis using ViBe motion detection algorithm

Science.gov (United States)

Yano, K. H.; Thomas, S.; Swenson, M. J.; Lu, Y.; Wharry, J. P.

2018-04-01

Transmission electron microscopic (TEM) in situ mechanical testing is a promising method for understanding plasticity in shallow ion irradiated layers and other volume-limited materials. One of the simplest TEM in situ experiments is cube-corner indentation of a lamella, but the subsequent analysis and interpretation of the experiment is challenging, especially in engineering materials with complex microstructures. In this work, we: (a) develop MicroViBE, a motion detection and background subtraction-based post-processing approach, and (b) demonstrate the ability of MicroViBe, in combination with post-mortem TEM imaging, to carry out an unbiased qualitative interpretation of TEM indentation videos. We focus this work around a Fe-9%Cr oxide dispersion strengthened (ODS) alloy, irradiated with Fe2+ ions to 3 dpa at 500 °C. MicroViBe identifies changes in Laue contrast that are induced by the indentation; these changes accumulate throughout the mechanical loading to generate a "heatmap" of features in the original TEM video that change the most during the loading. Dislocation loops with b = ½ identified by post-mortem scanning TEM (STEM) imaging correspond to hotspots on the heatmap, whereas positions of dislocation loops with b = do not correspond to hotspots. Further, MicroViBe enables consistent, objective quantitative approximation of the b = ½ dislocation loop number density.

Studying the TEM response of a 3-D conductor at a geological contact using the FDTD method

Energy Technology Data Exchange (ETDEWEB)

Wang, T.; Tripp, A.C.; Hohmann, G.W. [Univ. of Utah, Salt Lake City, UT (United States). Dept. of Geology and Geophysics

1995-07-01

Many mineral targets are located near contact zones. Since the change of resistivity across the contact can distort or obscure the transient electromagnetic (TEM) response of the target, it is important to understand the possible effects. Previous investigators have examined similar problems using scale models. For example, Spies and Parker (1984) studied the TEM responses of fixed-loop and moving-loop configurations to geological contacts with lateral resistivity variations. More recently, Wilt (1991) systematically studied TEM soundings near a geological contact and observed that different survey systems respond to the contact in different ways. This paper will illustrate the use of the finite-difference, time-domain (FDTD) algorithm of Wang and Hohmann (1993) for calculating the TEM response of a 3-D conductive body at a geological contact. The algorithm is based on the Yee staggered grid FDTD method for solving the transient electrical nonmagnetic field responses of a 3-D model. On a suitable computer, a wide range of model responses can be readily calculated, a versatility that scale modeling does not share. This study uses a fixed transmitter loop, roving-receiver configuration. Many other configurations can be regarded as special cases of this survey. It is commonly employed, for instance, by the Newmont EMP (Body and Wiles, 1984), UTEM (West et al., 1984), and Geonics EM37 systems. The configuration also facilitates finite-difference, time-domain modeling because it does not require frequent movement of the source.

Atomic-resolution studies of In2O3-ZnO compounds on aberration-corrected electron microscopes

International Nuclear Information System (INIS)

Yu, Wentao

2009-01-01

In this work, the characteristic inversion domain microstructures of In 2 O 3 (ZnO) m (m=30) compounds were investigated by TEM methods. At bright-atom contrast condition, atomically resolved HR-TEM images of In 2 O 3 (ZnO) 30 were successfully acquired in [1 anti 100] zone axis of ZnO, with projected metal columns of ∝1.6 A well resolved. From contrast maxima in the TEM images, local lattice distortions at the pyramidal inversion domain boundaries were observed for the first time. Lattice displacements and the strain field in two-dimensions were visualized and measured using the 'DALI' algorithm. Atomically resolved single shot and focal series images of In 2 O 3 (ZnO) 30 were achieved in both zone axes of ZnO, [1 anti 100] and [2 anti 1 anti 10], respectively. The electron waves at the exit-plane were successfully reconstructed using the software package 'TrueImage'. Finally, a three dimensional atomic structure model for the pyramidal IDB was proposed, with an In distribution of 10%, 20%, 40%, 20% and 10% of In contents over 5 atom columns along basal planes, respectively. Through a detailed structural study of In 2 O 3 (ZnO) m compounds by using phase-contrast and Z-contrast imaging at atomic resolution, In 3+ atoms are determined with trigonal bi-pyramidal co-ordination and are distributed at the pyramidal IDBs. (orig.)

Reference resolution in multi-modal interaction: Preliminary observations

NARCIS (Netherlands)

González González, G.R.; Nijholt, Antinus

2002-01-01

In this paper we present our research on multimodal interaction in and with virtual environments. The aim of this presentation is to emphasize the necessity to spend more research on reference resolution in multimodal contexts. In multi-modal interaction the human conversational partner can apply

High resolution geomagnetic field observations at Terra Nova bay, Antarctica

Directory of Open Access Journals (Sweden)

P. Palangio

1996-06-01

Full Text Available he preliminary results obtained from the analysis in the micropulsation frequency range of high time resolution magnetic field data recorded at the Antarctic Italian geomagnetic observatory at Terra Nova Bay for 11 consecutive days in February 1994 are reported. The spectral index over the whole Pcl-Pc5 frequency range is of the order of 3.5 and its value significantly increases beyond about 50 mHz. Spectral peaks in the Pc3 frequency range are common, especially during the daytime hours, and are probably due to the direct penetration of upstream waves in the cusp region. From the local time distribution of the micro pulsation power, a signifi - cant activity enhancement around the local magnetic noon emerges, in agreement with previous observations. The analysis of the signal polarisation characteristics in the horizontal plane shows a predominant CW polarisation in the Pcl-Pc3 frequency ranges with the major axis of the polarisation ellipse in the first quadrant.

Pilot production of track etch membranes (TEMS) using heavy ion beam scanner

International Nuclear Information System (INIS)

Nair, J.P.; Surendran, P.; Sparrow, Hillary; Ninawe, N.G.; Bhagwat, P.V.; Acharya, N.; Kulshreshta, V.; Rajesh Kumar; Vijay, Y.K.; Kurup, M.B.

2005-01-01

Various methods for making TEMs were conducted at Pelletron Accelerator Facility. The technique for production using ion beam scattering was also established. This is an effort to make TEMs on pilot basis at BARC- TIFR Pelletron Accelerator using Heavy Ion Beam Scanner till large rolling mechanism is implemented

HIGH-RESOLUTION HELIOSEISMIC IMAGING OF SUBSURFACE STRUCTURES AND FLOWS OF A SOLAR ACTIVE REGION OBSERVED BY HINODE

International Nuclear Information System (INIS)

Zhao Junwei; Kosovichev, Alexander G.; Sekii, Takashi

2010-01-01

We analyze a solar active region observed by the Hinode Ca II H line using the time-distance helioseismology technique, and infer wave-speed perturbation structures and flow fields beneath the active region with a high spatial resolution. The general subsurface wave-speed structure is similar to the previous results obtained from Solar and Heliospheric Observatory/Michelson Doppler Imager observations. The general subsurface flow structure is also similar, and the downward flows beneath the sunspot and the mass circulations around the sunspot are clearly resolved. Below the sunspot, some organized divergent flow cells are observed, and these structures may indicate the existence of mesoscale convective motions. Near the light bridge inside the sunspot, hotter plasma is found beneath, and flows divergent from this area are observed. The Hinode data also allow us to investigate potential uncertainties caused by the use of phase-speed filter for short travel distances. Comparing the measurements with and without the phase-speed filtering, we find out that inside the sunspot, mean acoustic travel times are in basic agreement, but the values are underestimated by a factor of 20%-40% inside the sunspot umbra for measurements with the filtering. The initial acoustic tomography results from Hinode show a great potential of using high-resolution observations for probing the internal structure and dynamics of sunspots.

Backthinned TDI CCD image sensor design and performance for the Pleiades high resolution Earth observation satellites

Science.gov (United States)

Materne, A.; Bardoux, A.; Geoffray, H.; Tournier, T.; Kubik, P.; Morris, D.; Wallace, I.; Renard, C.

2017-11-01

The PLEIADES-HR Earth observing satellites, under CNES development, combine a 0.7m resolution panchromatic channel, and a multispectral channel allowing a 2.8 m resolution, in 4 spectral bands. The 2 satellites will be placed on a sun-synchronous orbit at an altitude of 695 km. The camera operates in push broom mode, providing images across a 20 km swath. This paper focuses on the specifications, design and performance of the TDI detectors developed by e2v technologies under CNES contract for the panchromatic channel. Design drivers, derived from the mission and satellite requirements, architecture of the sensor and measurement results for key performances of the first prototypes are presented.

Cosmic non-TEM radiation and synthetic feed array sensor system in ASIC mixed signal technology

Science.gov (United States)

Centureli, F.; Scotti, G.; Tommasino, P.; Trifiletti, A.; Romano, F.; Cimmino, R.; Saitto, A.

2014-08-01

The paper deals with the opportunity to introduce "Not strictly TEM waves" Synthetic detection Method (NTSM), consisting in a Three Axis Digital Beam Processing (3ADBP), to enhance the performances of radio telescope and sensor systems. Current Radio Telescopes generally use the classic 3D "TEM waves" approximation Detection Method, which consists in a linear tomography process (Single or Dual axis beam forming processing) neglecting the small z component. The Synthetic FEED ARRAY three axis Sensor SYSTEM is an innovative technique using a synthetic detection of the generic "NOT strictly TEM Waves radiation coming from the Cosmo, which processes longitudinal component of Angular Momentum too. Than the simultaneous extraction from radiation of both the linear and quadratic information component, may reduce the complexity to reconstruct the Early Universe in the different requested scales. This next order approximation detection of the observed cosmologic processes, may improve the efficacy of the statistical numerical model used to elaborate the same information acquired. The present work focuses on detection of such waves at carrier frequencies in the bands ranging from LF to MMW. The work shows in further detail the new generation of on line programmable and reconfigurable Mixed Signal ASIC technology that made possible the innovative Synthetic Sensor. Furthermore the paper shows the ability of such technique to increase the Radio Telescope Array Antenna performances.

An efficient and reproducible process for transmission electron microscopy (TEM) of rare cell populations

Science.gov (United States)

Kumar, Sachin; Ciraolo, Georgianne; Hinge, Ashwini; Filippi, Marie-Dominique

2014-01-01

Transmission electron microscopy (TEM) provides ultra-structural details of cells at the sub-organelle level. However, details of the cellular ultrastructure, and the cellular organization and content of various organelles in rare populations, particularly in the suspension, like hematopoietic stem cells (HSCs) remained elusive. This is mainly due to the requirement of millions of cells for TEM studies. Thus, there is a vital requirement of a method that will allow TEM studies with low cell numbers of such rare populations. We describe an alternative and novel approach for TEM studies for rare cell populations. Here we performed TEM study from 10,000 HSC cells with quite ease. In particular, tiny cell pellets were identified by Evans blue staining after PFA-GA fixation. The cell pellet was pre-embedded in agarose in a small microcentrifuge tube and processed for dehydration, infiltration and embedding. Semi-thin and ultra-thin sections identified clusters of numerous cells per sections with well preserved morphology and ultrastructural details of golgi complex and mitochondria. Together, this method provides an efficient, easy and reproducible process to perform qualitative and quantitative TEM analysis from limited biological samples including cells in suspension. PMID:24291346

Dynamics of Transformation from Platinum Icosahedral Nanoparticles to Larger FCC Crystal at Millisecond Time Resolution

Energy Technology Data Exchange (ETDEWEB)

Gao, Wenpei [Univ. of Illinois at Urbana-Champaign, IL (United States). Dept. of Materials Science and Engineering and Fredrick Seitz Materials Research Lab.; Wu, Jianbo [Univ. of Illinois at Urbana-Champaign, IL (United States). Dept. of Materials Science and Engineering, Fredrick Seitz Materials Research Lab. and Dept. of Chemical and Biomolecular Engineering; Shanghai Jiao Tong Univ. (China). School of Materials Science and Engineering; Yoon, Aram [Univ. of Illinois at Urbana-Champaign, IL (United States). Dept. of Materials Science and Engineering and Fredrick Seitz Materials Research Lab.; Lu, Ping [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Qi, Liang [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Materials Science and Engineering; Wen, Jianguo [Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials and Electron Microscopy Center; Miller, Dean J. [Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials and Electron Microscopy Center; Mabon, James C. [Univ. of Illinois at Urbana-Champaign, IL (United States). Fredrick Seitz Materials Research Lab.; Wilson, William L. [Univ. of Illinois at Urbana-Champaign, IL (United States). Dept. of Materials Science and Engineering and Fredrick Seitz Materials Research Lab.; Yang, Hong [Univ. of Illinois at Urbana-Champaign, IL (United States). Dept. of Chemical and Biomolecular Engineering; Zuo, Jian-Min [Univ. of Illinois at Urbana-Champaign, IL (United States). Dept. of Materials Science and Engineering and Fredrick Seitz Materials Research Lab.

2017-12-08

Atomic motion at grain boundaries is essential to microstructure development, growth and stability of catalysts and other nanostructured materials. However, boundary atomic motion is often too fast to observe in a conventional transmission electron microscope (TEM) and too slow for ultrafast electron microscopy. We report on the entire transformation process of strained Pt icosahedral nanoparticles (ICNPs) into larger FCC crystals, captured at 2.5 ms time resolution using a fast electron camera. Results show slow diffusive dislocation motion at nm/s inside ICNPs and fast surface transformation at μm/s. By characterizing nanoparticle strain, we show that the fast transformation is driven by inhomogeneous surface stress. And interaction with pre-existing defects led to the slowdown of the transformation front inside the nanoparticles. Particle coalescence, assisted by oxygen-induced surface migration at T ≥ 300°C, also played a critical role. Thus by studying transformation in the Pt ICNPs at high time and spatial resolution, we obtain critical insights into the transformation mechanisms in strained Pt nanoparticles.

Direct observation of cation distributions of ideal inverse spinel CoFe2O4 nanofibres and correlated magnetic properties

KAUST Repository

Zeng, Xue

2017-04-25

Low-dimensional spinel ferrites have recently attracted increasing attention because their tunable magnetic properties make them attractive candidates as spin-filtering tunnel barriers in spintronic devices and as magnetic components in artificial multiferroic heterostructures. Although we know that the distribution of cations (Fe3+ and Co2+) in a spinel structure governs its magnetic properties, their distribution in the so-called ideal inverse spinel structure of a ferrite, CoFe2O4, has not yet been imaged with sub-ångstrom resolution. In this work, we fill this gap in evidence by reporting a direct observation of the distribution of cations in an ideal inverse spinel structure of CoFe2O4 nanofibres using aberration-corrected transmission electron microscopy (TEM). The ordering of Co2+ and Fe3+ at the octahedral sites imaged along either [001], [011] or [-112] orientation was identified as 1 : 1, in accordance with the ideal inverse spinel structure. The saturation magnetisation calculated based on the crystal structure as determined from the TEM image is in good agreement with that measured experimentally on the spinel CoFe2O4 nanofibres, further confirming results from TEM.

VES/TEM 1D joint inversion by using Controlled Random Search (CRS) algorithm

Science.gov (United States)

Bortolozo, Cassiano Antonio; Porsani, Jorge Luís; Santos, Fernando Acácio Monteiro dos; Almeida, Emerson Rodrigo

2015-01-01

Electrical (DC) and Transient Electromagnetic (TEM) soundings are used in a great number of environmental, hydrological, and mining exploration studies. Usually, data interpretation is accomplished by individual 1D models resulting often in ambiguous models. This fact can be explained by the way as the two different methodologies sample the medium beneath surface. Vertical Electrical Sounding (VES) is good in marking resistive structures, while Transient Electromagnetic sounding (TEM) is very sensitive to conductive structures. Another difference is VES is better to detect shallow structures, while TEM soundings can reach deeper layers. A Matlab program for 1D joint inversion of VES and TEM soundings was developed aiming at exploring the best of both methods. The program uses CRS - Controlled Random Search - algorithm for both single and 1D joint inversions. Usually inversion programs use Marquadt type algorithms but for electrical and electromagnetic methods, these algorithms may find a local minimum or not converge. Initially, the algorithm was tested with synthetic data, and then it was used to invert experimental data from two places in Paraná sedimentary basin (Bebedouro and Pirassununga cities), both located in São Paulo State, Brazil. Geoelectric model obtained from VES and TEM data 1D joint inversion is similar to the real geological condition, and ambiguities were minimized. Results with synthetic and real data show that 1D VES/TEM joint inversion better recovers simulated models and shows a great potential in geological studies, especially in hydrogeological studies.

Photoluminescence and TEM evaluations of defects generated during SiGe-on-insulator virtual substrate fabrication: Temperature ramping process

International Nuclear Information System (INIS)

Wang, D.; Ii, S.; Ikeda, K.; Nakashima, H.; Matsumoto, K.; Nakamae, M.; Nakashima, H.

2006-01-01

Crystal qualities were evaluated by photoluminescence (PL) and transmission electron microscopy (TEM) for cap-Si/SiGe/Si-on-insulater (SOI) structure, which is the typical structure for SiGe-on-insulator virtual substrate fabrication using the Ge condensation by dry oxidation. The thicknesses of cap-Si, SOI and BOX layers are 10, 70, and 140 nm, respectively. We have three kinds of wafers with SiGe thicknesses of 74, 154 and 234 nm. All of the wafers were heated from 200 deg.C to a target temperature (T t ) in the range of 820-1200 deg. C with a ramping rate of 5 deg. C/min, and maintained at T t for 10 min. The air in the furnace was a mixture of O 2 and N 2 . The PL measurements were carried out using a 325 nm UV line of a continuous-wave HeCd laser. Free exciton peaks were clearly observed for the as-grown wafers and decreased with an increase in the annealing temperature. For the selected wafers, cross-sectional and plan-view TEM measurements show clear generation and variation of dislocations at the interface of SiGe/SOI according to the T t . Defect-related PL signals were observed at around 0.82, 0.88, 0.95 and 1.0 eV, which also varied according to the T t and the SiGe thickness. They were identified to dislocation-related and stacking-fault-related defects by TEM

HIGH SPATIAL-RESOLUTION IMAGING OF TE INCLUSIONS IN CZT MATERIAL

International Nuclear Information System (INIS)

CAMARDA, G.S.; BOLOTNIKOV, A.E.; CARINI, G.A.; CUI, Y.; KOHMAN, K.T.; LI, L.; JAMES, R.B.

2006-01-01

We present new results from our studies of defects in current single-crystal CdZnTe material. Our previous measurements, carried out on thin (∼1 mm) and long (>12 mm) CZT detectors, indicated that small (1-20 (micro)m) Te inclusions can significantly degrade the device's energy resolution and detection efficiency. We are conducting detailed studies of the effects of Te inclusions by employing different characterization techniques with better spatial resolution, such as quantitative fluorescence mapping, X-ray micro-diffraction, and TEM. Also, IR microscopy and gamma-mapping with pulse-shape analysis with higher spatial resolution generated more accurate results in the areas surrounding the micro-defects (Te inclusions). Our results reveal how the performance of CdZnTe detectors is influenced by Te inclusions, such as their spatial distribution, concentration, and size. We also discuss a model of charge transport through areas populated with Te inclusions

High-cadence, High-resolution Spectroscopic Observations of Herbig Stars HD 98922 and V1295 Aquila

Energy Technology Data Exchange (ETDEWEB)

Aarnio, Alicia N.; Monnier, John D.; Calvet, Nuria; Che, Xiao [Department of Astronomy, University of Michigan, 311 West Hall, 1085 S. University Avenue, Ann Arbor, MI 48109 (United States); Harries, Tim J.; Kraus, Stefan; Acreman, David [Department of Physics and Astronomy, University of Exeter, Stocker Road, Exeter EX4 4QL (United Kingdom)

2017-10-10

Recent observational work has indicated that mechanisms for accretion and outflow in Herbig Ae/Be star–disk systems may differ from magnetospheric accretion (MA) as it is thought to occur in T Tauri star–disk systems. In this work, we assess the temporal evolution of spectral lines probing accretion and mass loss in Herbig Ae/Be systems and test for consistency with the MA paradigm. For two Herbig Ae/Be stars, HD 98922 (B9e) and V1295 Aql (A2e), we have gathered multi-epoch (∼years) and high-cadence (∼minutes) high-resolution optical spectra to probe a wide range of kinematic processes. Employing a line equivalent width evolution correlation metric introduced here, we identify species co-evolving (indicative of common line origin) via novel visualization. We interferometrically constrain often problematically degenerate parameters, inclination and inner-disk radius, allowing us to focus on the structure of the wind, magnetosphere, and inner gaseous disk in radiative transfer models. Over all timescales sampled, the strongest variability occurs within the blueshifted absorption components of the Balmer series lines; the strength of variability increases with the cadence of the observations. Finally, high-resolution spectra allow us to probe substructure within the Balmer series’ blueshifted absorption components: we observe static, low-velocity features and time-evolving features at higher velocities. Overall, we find the observed line morphologies and variability are inconsistent with a scaled-up T Tauri MA scenario. We suggest that as magnetic field structure and strength change dramatically with increasing stellar mass from T Tauri to Herbig Ae/Be stars, so too may accretion and outflow processes.

High-cadence, High-resolution Spectroscopic Observations of Herbig Stars HD 98922 and V1295 Aquila

International Nuclear Information System (INIS)

Aarnio, Alicia N.; Monnier, John D.; Calvet, Nuria; Che, Xiao; Harries, Tim J.; Kraus, Stefan; Acreman, David

2017-01-01

Recent observational work has indicated that mechanisms for accretion and outflow in Herbig Ae/Be star–disk systems may differ from magnetospheric accretion (MA) as it is thought to occur in T Tauri star–disk systems. In this work, we assess the temporal evolution of spectral lines probing accretion and mass loss in Herbig Ae/Be systems and test for consistency with the MA paradigm. For two Herbig Ae/Be stars, HD 98922 (B9e) and V1295 Aql (A2e), we have gathered multi-epoch (∼years) and high-cadence (∼minutes) high-resolution optical spectra to probe a wide range of kinematic processes. Employing a line equivalent width evolution correlation metric introduced here, we identify species co-evolving (indicative of common line origin) via novel visualization. We interferometrically constrain often problematically degenerate parameters, inclination and inner-disk radius, allowing us to focus on the structure of the wind, magnetosphere, and inner gaseous disk in radiative transfer models. Over all timescales sampled, the strongest variability occurs within the blueshifted absorption components of the Balmer series lines; the strength of variability increases with the cadence of the observations. Finally, high-resolution spectra allow us to probe substructure within the Balmer series’ blueshifted absorption components: we observe static, low-velocity features and time-evolving features at higher velocities. Overall, we find the observed line morphologies and variability are inconsistent with a scaled-up T Tauri MA scenario. We suggest that as magnetic field structure and strength change dramatically with increasing stellar mass from T Tauri to Herbig Ae/Be stars, so too may accretion and outflow processes.

"One-sample concept" micro-combinatory for high throughput TEM of binary films.

Science.gov (United States)

Sáfrán, György

2018-04-01

Phases of thin films may remarkably differ from that of bulk. Unlike to the comprehensive data files of Binary Phase Diagrams [1] available for bulk, complete phase maps for thin binary layers do not exist. This is due to both the diverse metastable, non-equilibrium or instable phases feasible in thin films and the required volume of characterization work with analytical techniques like TEM, SAED and EDS. The aim of the present work was to develop a method that remarkably facilitates the TEM study of the diverse binary phases of thin films, or the creation of phase maps. A micro-combinatorial method was worked out that enables both preparation and study of a gradient two-component film within a single TEM specimen. For a demonstration of the technique thin Mn x Al 1- x binary samples with evolving concentration from x = 0 to x = 1 have been prepared so that the transition from pure Mn to pure Al covers a 1.5 mm long track within the 3 mm diameter TEM grid. The proposed method enables the preparation and study of thin combinatorial samples including all feasible phases as a function of composition or other deposition parameters. Contrary to known "combinatorial chemistry", in which a series of different samples are deposited in one run, and investigated, one at a time, the present micro-combinatorial method produces a single specimen condensing a complete library of a binary system that can be studied, efficiently, within a single TEM session. That provides extremely high throughput for TEM characterization of composition-dependent phases, exploration of new materials, or the construction of phase diagrams of binary films. Copyright © 2018 Elsevier B.V. All rights reserved.

A preliminary study of CdS for solar cells using combined TEM and cathodoluminescence

International Nuclear Information System (INIS)

Mam, K.; Durose, K.; Halliday, D.P.; Szczerbakow, A.

2005-01-01

A study of the suitability of a combined transmission electron microscope (TEM)/cathodoluminescence (CL) imaging and spectroscopy apparatus for investigations of CdS is presented. Photoluminescence (PL) was used to evaluate the effect of the Ar + and I + ion beam thinning used in TEM specimen preparation of CdS: a minor increase in yellow emission (594 nm) resulted. However, excitation of luminescence spectra in the TEM had a quenching effect on red luminescence (734 nm), this being considered due to the high excitation density compared to that in PL. Significant electron beam damage to the CdS could be avoided by using scanning transmission electron microscope (STEM) illumination in preference to the conventional TEM mode, which generally uses higher beam current density. Dislocation images were correlated with contrast in the STEM-CL imaging mode. The potential of the apparatus to make further direct correlations of CL images with diffraction contrast TEM imaging was assessed using the Rose visibility criterion

Development of a versatile TEM specimen holder for the characterization of photocatalytic materials

DEFF Research Database (Denmark)

Cavalca, Filippo; Langhammer, C.; Hansen, Thomas Willum

2011-01-01

conventional TEM analysis on photocatalysts with several in situ TEM techniques including environmental TEM (ETEM), in situ photo activation and localized surface plasmon resonance (LSPR) spectroscopy [3-4]. These experiments are facilitated by the construction of a specimen holder capable of illuminating....../on nanomaterials and thin films. We present results from combined ETEM-LSPR studies of thermally-induced catalytic phenomena and on metal nanoparticle sintering, an important process in catalysis, which we study in situ in both real and model systems by means of indirect nanoplasmonic sensing and ETEM....

Coupling physics and biogeochemistry thanks to high-resolution observations of the phytoplankton community structure in the northwestern Mediterranean Sea

Science.gov (United States)

Marrec, Pierre; Grégori, Gérald; Doglioli, Andrea M.; Dugenne, Mathilde; Della Penna, Alice; Bhairy, Nagib; Cariou, Thierry; Hélias Nunige, Sandra; Lahbib, Soumaya; Rougier, Gilles; Wagener, Thibaut; Thyssen, Melilotus

2018-03-01

Fine-scale physical structures and ocean dynamics strongly influence and regulate biogeochemical and ecological processes. These processes are particularly challenging to describe and understand because of their ephemeral nature. The OSCAHR (Observing Submesoscale Coupling At High Resolution) campaign was conducted in fall 2015 in which a fine-scale structure (1-10 km/1-10 days) in the northwestern Mediterranean Ligurian subbasin was pre-identified using both satellite and numerical modeling data. Along the ship track, various variables were measured at the surface (temperature, salinity, chlorophyll a and nutrient concentrations) with ADCP current velocity. We also deployed a new model of the CytoSense automated flow cytometer (AFCM) optimized for small and dim cells, for near real-time characterization of the surface phytoplankton community structure of surface waters with a spatial resolution of a few kilometers and an hourly temporal resolution. For the first time with this optimized version of the AFCM, we were able to fully resolve Prochlorococcus picocyanobacteria in addition to the easily distinguishable Synechococcus. The vertical physical dynamics and biogeochemical properties of the studied area were investigated by continuous high-resolution CTD profiles thanks to a moving vessel profiler (MVP) during the vessel underway associated with a high-resolution pumping system deployed during fixed stations allowing sampling of the water column at a fine resolution (below 1 m). The observed fine-scale feature presented a cyclonic structure with a relatively cold core surrounded by warmer waters. Surface waters were totally depleted in nitrate and phosphate. In addition to the doming of the isopycnals by the cyclonic circulation, an intense wind event induced Ekman pumping. The upwelled subsurface cold nutrient-rich water fertilized surface waters and was marked by an increase in Chl a concentration. Prochlorococcus and pico- and nano-eukaryotes were more

MISTiC Winds, a Micro-Satellite Constellation Approach to High Resolution Observations of the Atmosphere Using Infrared Sounding and 3D Winds Measurements

Science.gov (United States)

Maschhoff, K. R.; Polizotti, J. J.; Aumann, H. H.; Susskind, J.

2016-01-01

MISTiC(TM) Winds is an approach to improve short-term weather forecasting based on a miniature high resolution, wide field, thermal emission spectrometry instrument that will provide global tropospheric vertical profiles of atmospheric temperature and humidity at high (3-4 km) horizontal and vertical ( 1 km) spatial resolution. MISTiCs extraordinarily small size, payload mass of less than 15 kg, and minimal cooling requirements can be accommodated aboard a 27U-class CubeSat or an ESPA-Class micro-satellite. Low fabrication and launch costs enable a LEO sunsynchronous sounding constellation that would collectively provide frequent IR vertical profiles and vertically resolved atmospheric motion vector wind observations in the troposphere. These observations are highly complementary to present and emerging environmental observing systems, and would provide a combination of high vertical and horizontal resolution not provided by any other environmental observing system currently in operation. The spectral measurements that would be provided by MISTiC Winds are similar to those of NASA's AIRS that was built by BAE Systems and operates aboard the AQUA satellite. These new observations, when assimilated into high resolution numerical weather models, would revolutionize short-term and severe weather forecasting, save lives, and support key economic decisions in the energy, air transport, and agriculture arenasat much lower cost than providing these observations from geostationary orbit. In addition, this observation capability would be a critical tool for the study of transport processes for water vapor, clouds, pollution, and aerosols. Key remaining technical risks are being reduced through laboratory and airborne testing under NASA's Instrument Incubator Program.

MISTiC Winds: A micro-satellite constellation approach to high resolution observations of the atmosphere using infrared sounding and 3D winds measurements

Science.gov (United States)

Maschhoff, K. R.; Polizotti, J. J.; Aumann, H. H.; Susskind, J.

2016-09-01

MISTiCTM Winds is an approach to improve short-term weather forecasting based on a miniature high resolution, wide field, thermal emission spectrometry instrument that will provide global tropospheric vertical profiles of atmospheric temperature and humidity at high (3-4 km) horizontal and vertical ( 1 km) spatial resolution. MISTiC's extraordinarily small size, payload mass of less than 15 kg, and minimal cooling requirements can be accommodated aboard a 27U-class CubeSat or an ESPA-Class micro-satellite. Low fabrication and launch costs enable a LEO sunsynchronous sounding constellation that would collectively provide frequent IR vertical profiles and vertically resolved atmospheric motion vector wind observations in the troposphere. These observations are highly complementary to present and emerging environmental observing systems, and would provide a combination of high vertical and horizontal resolution not provided by any other environmental observing system currently in operation. The spectral measurements that would be provided by MISTiC Winds are similar to those of NASA's AIRS that was built by BAE Systems and operates aboard the AQUA satellite. These new observations, when assimilated into high resolution numerical weather models, would revolutionize short-term and severe weather forecasting, save lives, and support key economic decisions in the energy, air transport, and agriculture arenas-at much lower cost than providing these observations from geostationary orbit. In addition, this observation capability would be a critical tool for the study of transport processes for water vapor, clouds, pollution, and aerosols. Key remaining technical risks are being reduced through laboratory and airborne testing under NASA's Instrument Incubator Program.

LAMOST OBSERVATIONS IN THE KEPLER FIELD. I. DATABASE OF LOW-RESOLUTION SPECTRA

Energy Technology Data Exchange (ETDEWEB)

Cat, P. De; Ren, A. B.; Yang, X. H. [Royal observatory of Belgium, Ringlaan 3, B-1180 Brussel (Belgium); Fu, J. N. [Department of Astronomy, Beijing Normal University, 19 Avenue Xinjiekouwai, Beijing 100875 (China); Shi, J. R.; Luo, A. L.; Yang, M.; Wang, J. L.; Zhang, H. T.; Shi, H. M.; Zhang, W. [Key Lab for Optical Astronomy, National Astronomical Observatories, Chinese Academy of Sciences, Beijing 100012 (China); Dong, Subo [Kavli Institute for Astronomy and Astrophysics, Peking University, Yi He Yuan Road 5, Hai Dian District, Beijing, 100871 (China); Catanzaro, G.; Frasca, A. [INAF—Osservatorio Astrofisico di Catania, Via S. Sofia 78, I-95123 Catania (Italy); Corbally, C. J. [Vatican Observatory Research Group, Steward Observatory, Tucson, AZ 85721-0065 (United States); Gray, R. O. [Department of Physics and Astronomy, Appalachian State University, Boone, NC 28608 (United States); Żakowicz, J. Molenda- [Astronomical Institute of the University of Wrocław, ul. Kopernika 11, 51-622 Wrocław (Poland); Uytterhoeven, K. [Instituto de Astrofísica de Canarias (IAC), E-38200 La Laguna, Tenerife (Spain); Briquet, M. [Institut d’Astrophysique et de Géophysique, Université de Liège, Allée du 6 Août 19C, B-4000 Liège (Belgium); Bruntt, H., E-mail: Peter.DeCat@oma.be [Stellar Astrophysics Center, Department of Physics and Astronomy, Aarhus University, Ny Munkegade 120, DK-8000 Aarhus C (Denmark); and others

2015-09-15

The nearly continuous light curves with micromagnitude precision provided by the space mission Kepler are revolutionizing our view of pulsating stars. They have revealed a vast sea of low-amplitude pulsation modes that were undetectable from Earth. The long time base of Kepler light curves allows for the accurate determination of the frequencies and amplitudes of pulsation modes needed for in-depth asteroseismic modeling. However, for an asteroseismic study to be successful, the first estimates of stellar parameters need to be known and they cannot be derived from the Kepler photometry itself. The Kepler Input Catalog provides values for the effective temperature, surface gravity, and metallicity, but not always with sufficient accuracy. Moreover, information on the chemical composition and rotation rate is lacking. We are collecting low-resolution spectra for objects in the Kepler field of view with the Large Sky Area Multi-Object Fiber Spectroscopic Telescope (lamost, Xinglong observatory, China). All of the requested fields have now been observed at least once. In this paper, we describe those observations and provide a useful database for the whole astronomical community.

Determination of the Projected Atomic Potential by Deconvolution of the Auto-Correlation Function of TEM Electron Nano-Diffraction Patterns

Directory of Open Access Journals (Sweden)

Liberato De Caro

2016-11-01

Full Text Available We present a novel method to determine the projected atomic potential of a specimen directly from transmission electron microscopy coherent electron nano-diffraction patterns, overcoming common limitations encountered so far due to the dynamical nature of electron-matter interaction. The projected potential is obtained by deconvolution of the inverse Fourier transform of experimental diffraction patterns rescaled in intensity by using theoretical values of the kinematical atomic scattering factors. This novelty enables the compensation of dynamical effects typical of transmission electron microscopy (TEM experiments on standard specimens with thicknesses up to a few tens of nm. The projected atomic potentials so obtained are averaged on sample regions illuminated by nano-sized electron probes and are in good quantitative agreement with theoretical expectations. Contrary to lens-based microscopy, here the spatial resolution in the retrieved projected atomic potential profiles is related to the finer lattice spacing measured in the electron diffraction pattern. The method has been successfully applied to experimental nano-diffraction data of crystalline centrosymmetric and non-centrosymmetric specimens achieving a resolution of 65 pm.

A simple algorithm for measuring particle size distributions on an uneven background from TEM images

DEFF Research Database (Denmark)

Gontard, Lionel Cervera; Ozkaya, Dogan; Dunin-Borkowski, Rafal E.

2011-01-01

Nanoparticles have a wide range of applications in science and technology. Their sizes are often measured using transmission electron microscopy (TEM) or X-ray diffraction. Here, we describe a simple computer algorithm for measuring particle size distributions from TEM images in the presence of a...... application to images of heterogeneous catalysts is presented.......Nanoparticles have a wide range of applications in science and technology. Their sizes are often measured using transmission electron microscopy (TEM) or X-ray diffraction. Here, we describe a simple computer algorithm for measuring particle size distributions from TEM images in the presence...

Observation of Eye Pattern on Super-Resolution Near-Field Structure Disk with Write-Strategy Technique

Science.gov (United States)

Fuji, Hiroshi; Kikukawa, Takashi; Tominaga, Junji

2004-07-01

Pit-edge recording at a density of 150 nm pits and spaces is carried out on a super-resolution near-field structure (super-RENS) disk with a platinum oxide layer. Pits are recorded and read using a 635-nm-wavelength laser and an objective lens with a 0.6 numerical aperture. We arrange laser pulses to correctly record the pits on the disk by a write-strategy technique. The laser-pulse figure includes a unit time of 0.25 T and intensities of Pw1, Pw2 and Pw3. After recording pits of various lengths, the observation of an eye pattern is achieved despite a pit smaller than the resolution limit. Furthermore, the eye pattern maintains its shape even though other pits fill the adjacent tracks at a track density of 600 nm. The disk can be used as a pit-edge recording system through a write-strategy technique.

High-resolution monitoring of marine protists based on an observation strategy integrating automated on-board filtration and molecular analyses

Science.gov (United States)

Metfies, Katja; Schroeder, Friedhelm; Hessel, Johanna; Wollschläger, Jochen; Micheller, Sebastian; Wolf, Christian; Kilias, Estelle; Sprong, Pim; Neuhaus, Stefan; Frickenhaus, Stephan; Petersen, Wilhelm

2016-11-01

Information on recent biomass distribution and biogeography of photosynthetic marine protists with adequate temporal and spatial resolution is urgently needed to better understand the consequences of environmental change for marine ecosystems. Here we introduce and review a molecular-based observation strategy for high-resolution assessment of these protists in space and time. It is the result of extensive technology developments, adaptations and evaluations which are documented in a number of different publications, and the results of the recently completed field testing which are introduced in this paper. The observation strategy is organized at four different levels. At level 1, samples are collected at high spatiotemporal resolution using the remotely controlled automated filtration system AUTOFIM. Resulting samples can either be preserved for later laboratory analyses, or directly subjected to molecular surveillance of key species aboard the ship via an automated biosensor system or quantitative polymerase chain reaction (level 2). Preserved samples are analyzed at the next observational levels in the laboratory (levels 3 and 4). At level 3 this involves molecular fingerprinting methods for a quick and reliable overview of differences in protist community composition. Finally, selected samples can be used to generate a detailed analysis of taxonomic protist composition via the latest next generation sequencing technology (NGS) at level 4. An overall integrated dataset of the results based on the different analyses provides comprehensive information on the diversity and biogeography of protists, including all related size classes. At the same time the cost of the observation is optimized with respect to analysis effort and time.

Generation of real-time mode high-resolution water vapor fields from GPS observations

Science.gov (United States)

Yu, Chen; Penna, Nigel T.; Li, Zhenhong

2017-02-01

Pointwise GPS measurements of tropospheric zenith total delay can be interpolated to provide high-resolution water vapor maps which may be used for correcting synthetic aperture radar images, for numeral weather prediction, and for correcting Network Real-time Kinematic GPS observations. Several previous studies have addressed the importance of the elevation dependency of water vapor, but it is often a challenge to separate elevation-dependent tropospheric delays from turbulent components. In this paper, we present an iterative tropospheric decomposition interpolation model that decouples the elevation and turbulent tropospheric delay components. For a 150 km × 150 km California study region, we estimate real-time mode zenith total delays at 41 GPS stations over 1 year by using the precise point positioning technique and demonstrate that the decoupled interpolation model generates improved high-resolution tropospheric delay maps compared with previous tropospheric turbulence- and elevation-dependent models. Cross validation of the GPS zenith total delays yields an RMS error of 4.6 mm with the decoupled interpolation model, compared with 8.4 mm with the previous model. On converting the GPS zenith wet delays to precipitable water vapor and interpolating to 1 km grid cells across the region, validations with the Moderate Resolution Imaging Spectroradiometer near-IR water vapor product show 1.7 mm RMS differences by using the decoupled model, compared with 2.0 mm for the previous interpolation model. Such results are obtained without differencing the tropospheric delays or water vapor estimates in time or space, while the errors are similar over flat and mountainous terrains, as well as for both inland and coastal areas.

MORPHOLOGICAL ASPECTS OF HUMAN LENS CAPSULES - A COMPARATIVE LM, SEM AND TEM EXAMINATION

NARCIS (Netherlands)

JONGEBLOED, WL; KALICHARAN, D; LOS, LI; VANDERVEEN, G; WORST, JGF

1991-01-01

Lens capsules of patients of advanced age, obtained after extracapsular cataract surgery, were carefully prepared for a combined LM, TEM and SEM investigation, after preliminary washing and mounting onto a holder in a buffer solution. After pre-fixation with GA, samples were postfixed for LM/TEM and

Energy resolution of scintillation detectors

Energy Technology Data Exchange (ETDEWEB)

Moszyński, M., E-mail: M.Moszynski@ncbj.gov.pl; Syntfeld-Każuch, A.; Swiderski, L.; Grodzicka, M.; Iwanowska, J.; Sibczyński, P.; Szczęśniak, T.

2016-01-01

According to current knowledge, the non-proportionality of the light yield of scintillators appears to be a fundamental limitation of energy resolution. A good energy resolution is of great importance for most applications of scintillation detectors. Thus, its limitations are discussed below; which arise from the non-proportional response of scintillators to gamma rays and electrons, being of crucial importance to the intrinsic energy resolution of crystals. The important influence of Landau fluctuations and the scattering of secondary electrons (δ-rays) on intrinsic resolution is pointed out here. The study on undoped NaI and CsI at liquid nitrogen temperature with a light readout by avalanche photodiodes strongly suggests that the non-proportionality of many crystals is not their intrinsic property and may be improved by selective co-doping. Finally, several observations that have been collected in the last 15 years on the influence of the slow components of light pulses on energy resolution suggest that more complex processes are taking place in the scintillators. This was observed with CsI(Tl), CsI(Na), ZnSe(Te), and undoped NaI at liquid nitrogen temperature and, finally, for NaI(Tl) at temperatures reduced below 0 °C. A common conclusion of these observations is that the highest energy resolution, and particularly intrinsic resolution measured with the scintillators, characterized by two or more components of the light pulse decay, is obtainable when the spectrometry equipment integrates the whole light of the components. In contrast, the slow components observed in many other crystals degrade the intrinsic resolution. In the limiting case, afterglow could also be considered as a very slow component that spoils the energy resolution. The aim of this work is to summarize all of the above observations by looking for their origin.

Integrated model for providing tactical emergency medicine support (TEMS): analysis of 120 tactical situations.

Science.gov (United States)

Vainionpää, T; Peräjoki, K; Hiltunen, T; Porthan, K; Taskinen, A; Boyd, J; Kuisma, M

2012-02-01

Various models for organising tactical emergency medicine support (TEMS) in law enforcement operations exist. In Helsinki, TEMS is organised as an integral part of emergency medical service (EMS) and applied in hostage, siege, bomb threat and crowd control situations and in other tactical situations after police request. Our aim was to analyse TEMS operations, patient profile, and the level of on-site care provided. We conducted a retrospective cohort study of TEMS operations in Helsinki from 2004 to 2009. Data were retrieved from EMS, hospital and dispatching centre files and from TEMS reports. One hundred twenty TEMS operations were analysed. Median time from dispatching to arrival on scene was 10 min [Interquartile Range (IQR) 7-14]. Median duration of operations was 41 min (IQR 19-63). Standby was the only activity in 72 operations, four patients were dead on arrival, 16 requests were called off en route and patient examination or care was needed in 28 operations. Twenty-eight patients (records retrieved) were alive on arrival and were classified as trauma (n = 12) or medical (n = 16). Of traumas, two sustained a gunshot wound, one sustained a penetrating abdominal wound, three sustained medium severity injuries and nine sustained minor injuries. There was neither on-scene nor in-hospital mortality among patients who were alive on arrival. The level of on-site care performed was basic life support in all cases. The results showed that TEMS integrated to daily EMS services including safe zone working only was a feasible, rapid and efficient way to provide medical support to law enforcement operations. © 2011 The Authors Acta Anaesthesiologica Scandinavica © 2011 The Acta Anaesthesiologica Scandinavica Foundation.

Coupling physics and biogeochemistry thanks to high-resolution observations of the phytoplankton community structure in the northwestern Mediterranean Sea

Directory of Open Access Journals (Sweden)

P. Marrec

2018-03-01

Full Text Available Fine-scale physical structures and ocean dynamics strongly influence and regulate biogeochemical and ecological processes. These processes are particularly challenging to describe and understand because of their ephemeral nature. The OSCAHR (Observing Submesoscale Coupling At High Resolution campaign was conducted in fall 2015 in which a fine-scale structure (1–10 km∕1–10 days in the northwestern Mediterranean Ligurian subbasin was pre-identified using both satellite and numerical modeling data. Along the ship track, various variables were measured at the surface (temperature, salinity, chlorophyll a and nutrient concentrations with ADCP current velocity. We also deployed a new model of the CytoSense automated flow cytometer (AFCM optimized for small and dim cells, for near real-time characterization of the surface phytoplankton community structure of surface waters with a spatial resolution of a few kilometers and an hourly temporal resolution. For the first time with this optimized version of the AFCM, we were able to fully resolve Prochlorococcus picocyanobacteria in addition to the easily distinguishable Synechococcus. The vertical physical dynamics and biogeochemical properties of the studied area were investigated by continuous high-resolution CTD profiles thanks to a moving vessel profiler (MVP during the vessel underway associated with a high-resolution pumping system deployed during fixed stations allowing sampling of the water column at a fine resolution (below 1 m. The observed fine-scale feature presented a cyclonic structure with a relatively cold core surrounded by warmer waters. Surface waters were totally depleted in nitrate and phosphate. In addition to the doming of the isopycnals by the cyclonic circulation, an intense wind event induced Ekman pumping. The upwelled subsurface cold nutrient-rich water fertilized surface waters and was marked by an increase in Chl a concentration. Prochlorococcus and pico

NPP Multi-Biome: TEM Calibration Data, 1992, R1

Data.gov (United States)

National Aeronautics and Space Administration — ABSTRACT: This data set contains one data file (.csv format) that is known as the Terrestrial Ecosystem Model (TEM) data set. The data provide pool sizes and fluxes...

Investigations of oxide particles in unirradiated ODS-Eurofer by TEM and 3D atom probe methods

International Nuclear Information System (INIS)

Aleev, A.A.; Iskandarov, N.A.; Nikitin, A.A.; Rogizhkin, S.V.; Zaluzhny, A.G.; Klimenkov, M.; Lindau, R.; Moeslang, A.; Vladimirov, P.

2009-01-01

Oxide dispersion strengthened steels possess better high-temperature creep and radiation resistance than conventionally produced ferritic/martensitic steels. This behavior is mainly caused by the presence of highly dispersed and extremely stable oxide particles with sizes of few nanometers. One of the promising oxides used for dispersion strengthening was yttria (Y 2 O 3 ), which was introduced into EUROFER by mechanical alloying followed by the hot isostatic pressing at temperature around 1000-1200 dg. C and pressure ∼100 MPa. It was found that mechanical properties were strongly depended on size and spatial distribution of the precipitates. Therefore considerable efforts are focused on the investigation of the chemical composition and orientation of precipitates with respect to the steel matrix. Recent studies of Eurofer ODS steel (9%-CrWVTa) by SANS revealed the presence of high number density structural features with a size of approximately one nanometer. At the same time, previous studies by TEM identified only high number of small (6-40 nm) Y 2 O 3 particles. In this work we tried to get a deeper inside into the nanostructure of this material by means of tomographic atom probe and to correlate the results with the picture obtained by TEM. The present investigations revealed fine (∼2 nm) enrichments containing not only yttrium and oxygen but also vanadium and nitrogen. Concentration of vanadium was found to be approximately at the same level as yttrium. Some of the enrichments contained only three or even two elements mentioned above. Estimated number density of enrichments is about (1/5) x 10 23 m -3 . We suppose that these enriched zones might be precursors of the larger precipitates observed by TEM. The thesis seems to be supported by the similarities of the chemical composition and spatial distribution of elements inside enriched zones and nano precipitates studied by atomic probe and analytical TEM methods. (author)

Location specific in situ TEM straining specimens made using FIB

International Nuclear Information System (INIS)

Field, R.D.; Papin, P.A.

2004-01-01

A method has been devised and demonstrated for producing in situ straining specimens for the transmission electron microscope (TEM) from specific locations in a sample using a dual-beam focused ion beam (FIB) instrument. The specimen is removed from a polished surface in the FIB using normal methods and then attached to a pre-fabricated substrate in the form of a modified TEM tensile specimen. In this manner, specific features of the microstructure of a polished optical mount can be selected for in situ tensile straining. With the use of electron backscattered diffraction (EBSD), this technique could be extended to select specific orientations of the specimen as well

High-temperature in-situ TEM straining of the interaction with dislocations and particles for Cu-added ferritic stainless steel.

Science.gov (United States)

Kobayashi, Shuhei; Kaneko, Kenji; Yamada, Kazuhiro; Kikuchi, Masao; Kanno, Norihiro; Hamada, Junichi

2014-11-01

IntroductionCu is always present in the matrix when ferritic steels were prepared from ferrous scrap. When the ferritic steels are aged thermally, Cu precipitates start appear and disperse finely and homogeneously [1], which may make the steels strengthened by precipitation hardening. In this study, the interaction between Cu precipitates and dislocations was exmined via high-temperature in-situ TEM straining. ExperimentalCu-added ferritic stainless steel (Fe-18.4%Cr-1.5%Cu) was used in the present study. Specimen was aged at1073 K for 360 ks. Samples for TEM observation were prepared by focused ion beam (FIB; Quanta 3D 200i) method. Microstructure of specimen was analyzed by JEM-3200FSK and high-temperature in-situ TEM straining was conducted using JEM-1300NEF. Results and discussionInteraction between Cu precipitates and dislocation is seen from consecutive TEM images acquired by in-situ TEM straining at 1073 K, as shown in Fig.1. The size of Cu precipitates was about 70 nm and several dislocations were present within the field of view. In particular, progressing dislocations contacted with the Cu precipitate at right angle, as indicated by arrows in Fig.1 (b) to (d). This result implies that there is an attractive interaction between dislocations and the Cu precipitate. This is attributed to the fact that Stress field of dislocations was easily relaxed in interface between the Cu precipitate and matrix because of lattice and interface diffusion as well as slip in the interface [2,3]. Furthermore, dislocations pass through the particle after contacting it, so that the interaction with dislocations and particles should be explained by Srolovitz mechanism [4].jmicro;63/suppl_1/i28/DFU083F1F1DFU083F1Fig. 1.TEM images foucused on interaction with dislocations and partticles. © The Author 2014. Published by Oxford University Press on behalf of The Japanese Society of Microscopy. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

Statistical Analyses of High-Resolution Aircraft and Satellite Observations of Sea Ice: Applications for Improving Model Simulations

Science.gov (United States)

Farrell, S. L.; Kurtz, N. T.; Richter-Menge, J.; Harbeck, J. P.; Onana, V.

2012-12-01

Satellite-derived estimates of ice thickness and observations of ice extent over the last decade point to a downward trend in the basin-scale ice volume of the Arctic Ocean. This loss has broad-ranging impacts on the regional climate and ecosystems, as well as implications for regional infrastructure, marine navigation, national security, and resource exploration. New observational datasets at small spatial and temporal scales are now required to improve our understanding of physical processes occurring within the ice pack and advance parameterizations in the next generation of numerical sea-ice models. High-resolution airborne and satellite observations of the sea ice are now available at meter-scale resolution or better that provide new details on the properties and morphology of the ice pack across basin scales. For example the NASA IceBridge airborne campaign routinely surveys the sea ice of the Arctic and Southern Oceans with an advanced sensor suite including laser and radar altimeters and digital cameras that together provide high-resolution measurements of sea ice freeboard, thickness, snow depth and lead distribution. Here we present statistical analyses of the ice pack primarily derived from the following IceBridge instruments: the Digital Mapping System (DMS), a nadir-looking, high-resolution digital camera; the Airborne Topographic Mapper, a scanning lidar; and the University of Kansas snow radar, a novel instrument designed to estimate snow depth on sea ice. Together these instruments provide data from which a wide range of sea ice properties may be derived. We provide statistics on lead distribution and spacing, lead width and area, floe size and distance between floes, as well as ridge height, frequency and distribution. The goals of this study are to (i) identify unique statistics that can be used to describe the characteristics of specific ice regions, for example first-year/multi-year ice, diffuse ice edge/consolidated ice pack, and convergent

NPP Multi-Biome: TEM Calibration Data, 1992, R1

Data.gov (United States)

National Aeronautics and Space Administration — This data set contains one data file (.csv format) that is known as the Terrestrial Ecosystem Model (TEM) data set. The data provide pool sizes and fluxes of carbon...

High resolution solar observations in the context of space weather prediction

Science.gov (United States)

Yang, Guo

Space weather has a great impact on the Earth and human life. It is important to study and monitor active regions on the solar surface and ultimately to predict space weather based on the Sun's activity. In this study, a system that uses the full power of speckle masking imaging by parallel processing to obtain high-spatial resolution images of the solar surface in near real-time has been developed and built. The application of this system greatly improves the ability to monitor the evolution of solar active regions and to predict the adverse effects of space weather. The data obtained by this system have also been used to study fine structures on the solar surface and their effects on the upper solar atmosphere. A solar active region has been studied using high resolution data obtained by speckle masking imaging. Evolution of a pore in an active region presented. Formation of a rudimentary penumbra is studied. The effects of the change of the magnetic fields on the upper level atmosphere is discussed. Coronal Mass Ejections (CMEs) have a great impact on space weather. To study the relationship between CMEs and filament disappearance, a list of 431 filament and prominence disappearance events has been compiled. Comparison of this list with CME data obtained by satellite has shown that most filament disappearances seem to have no corresponding CME events. Even for the limb events, only thirty percent of filament disappearances are associated with CMEs. A CME event that was observed on March 20, 2000 has been studied in detail. This event did not show the three-parts structure of typical CMEs. The kinematical and morphological properties of this event were examined.

Solar Ion Processing of Major Element Surface Compositions of Mature Mare Soils: Insights from Combined XPS and Analytical TEM Observations

Science.gov (United States)

Christoffersen, R.; Dukes, C.; Keller, L. P.; Baragiola, R.

2012-01-01

Solar wind ions are capable of altering the sur-face chemistry of the lunar regolith by a number of mechanisms including preferential sputtering, radiation-enhanced diffusion and sputter erosion of space weathered surfaces containing pre-existing compositional profiles. We have previously reported in-situ ion irradiation experiments supported by X-ray photoelectron spectroscopy (XPS) and analytical TEM that show how solar ions potentially drive Fe and Ti reduction at the monolayer scale as well as the 10-100 nm depth scale in lunar soils [1]. Here we report experimental data on the effect of ion irradiation on the major element surface composition in a mature mare soil.

Conception d'instrument pour une mission d'observation haute resolution et grand champ

Science.gov (United States)

Fayret, Jean-Philippe; Gaudin-Delrieu, Catherine; Lamard, Jean-Luc; Devilliers, Christophe; Costes, Vincent

2017-11-01

The future Earth observation missions aim at delivering images with a high resolution and a large field of view. The PLEIADES mission, coming after the SPOT satellites, lead to enhance the resolution to submetric values with a swath over 20km. Panchromatic and multispectral images will be proposed. Starting with the mission requirements elaborated by the CNES, Alcatel Space Industries has conducted a study to identify the instrument concepts most suited to comply with these performance. In addition, to minimise the development costs, a mini satellite approach has been selected, leading to a compact concept for the instrument design. During the study, various detection techniques and the associated detectors have been investigated from classical pushbroom to supermode acquisition modes. For each of these options, different optical lay-outs were proposed and evaluated with respect to performance as well as interfaces requirements. Optical performance, mechanical design constraints and manufacturing processes were taken into account to assess the performances of the various solutions. Eventually the most promising concept was selected and a preliminary design study performed. This concept, based on a Korsch optical scheme associated with TDI detectors, complies with the mission requirements and allows for a wide number of possibilities of accommodation with a minisatellite class platform.

Potential for added value in precipitation simulated by high-resolution nested Regional Climate Models and observations

Energy Technology Data Exchange (ETDEWEB)

Di Luca, Alejandro; Laprise, Rene [Universite du Quebec a Montreal (UQAM), Centre ESCER (Etude et Simulation du Climat a l' Echelle Regionale), Departement des Sciences de la Terre et de l' Atmosphere, PK-6530, Succ. Centre-ville, B.P. 8888, Montreal, QC (Canada); De Elia, Ramon [Universite du Quebec a Montreal, Ouranos Consortium, Centre ESCER (Etude et Simulation du Climat a l' Echelle Regionale), Montreal (Canada)

2012-03-15

Regional Climate Models (RCMs) constitute the most often used method to perform affordable high-resolution regional climate simulations. The key issue in the evaluation of nested regional models is to determine whether RCM simulations improve the representation of climatic statistics compared to the driving data, that is, whether RCMs add value. In this study we examine a necessary condition that some climate statistics derived from the precipitation field must satisfy in order that the RCM technique can generate some added value: we focus on whether the climate statistics of interest contain some fine spatial-scale variability that would be absent on a coarser grid. The presence and magnitude of fine-scale precipitation variance required to adequately describe a given climate statistics will then be used to quantify the potential added value (PAV) of RCMs. Our results show that the PAV of RCMs is much higher for short temporal scales (e.g., 3-hourly data) than for long temporal scales (16-day average data) due to the filtering resulting from the time-averaging process. PAV is higher in warm season compared to cold season due to the higher proportion of precipitation falling from small-scale weather systems in the warm season. In regions of complex topography, the orographic forcing induces an extra component of PAV, no matter the season or the temporal scale considered. The PAV is also estimated using high-resolution datasets based on observations allowing the evaluation of the sensitivity of changing resolution in the real climate system. The results show that RCMs tend to reproduce relatively well the PAV compared to observations although showing an overestimation of the PAV in warm season and mountainous regions. (orig.)

Structure and Output Characteristics of a TEM Array Fitted to a Fin Heat Exchanger

Science.gov (United States)

Zhang, Z.; Chen, L. N.; Chen, Z. J.; Xiao, G. Q.; Liu, Z. J.

2015-06-01

In the design of a thermoelectric generator, both the heat transfer area and the number of thermoelectric modules (TEMs) should be increased accordingly as the generator power increases; crucially, both aspects need to be coordinated. A kilowatt thermoelectric generator with a fin heat exchanger is proposed for use in a constant-speed diesel generator unit. Interior fins enhance convective heat transfer, whereas an exterior fin segment increases the heat transfer area. The heat transfer surface is double that of a plane heat exchanger, and the temperature field over the exterior fins is constrained to a one-dimensional distribution. Between adjoining exterior fins, there is a cooling water channel with trapezoid cross-section, enabling compact TEMs and cooling them. Hence, more TEMs are built as a series-parallel array of TEMs with lower resistance and more stable output current. Under nonuniform conditions, to prevent circulation and energy loss, bypass diodes and antidiodes are added. Experiments and numerical calculations show that, with matching and optimization of the heat exchanger and TEM array, a stable maximum output power is obtainable from the interior of the thermoelectric generator system, which can be connected to an external maximum power point tracking system.

ISED: Constructing a high-resolution elevation road dataset from massive, low-quality in-situ observations derived from geosocial fitness tracking data.

Directory of Open Access Journals (Sweden)

Grant McKenzie

Full Text Available Gaining access to inexpensive, high-resolution, up-to-date, three-dimensional road network data is a top priority beyond research, as such data would fuel applications in industry, governments, and the broader public alike. Road network data are openly available via user-generated content such as OpenStreetMap (OSM but lack the resolution required for many tasks, e.g., emergency management. More importantly, however, few publicly available data offer information on elevation and slope. For most parts of the world, up-to-date digital elevation products with a resolution of less than 10 meters are a distant dream and, if available, those datasets have to be matched to the road network through an error-prone process. In this paper we present a radically different approach by deriving road network elevation data from massive amounts of in-situ observations extracted from user-contributed data from an online social fitness tracking application. While each individual observation may be of low-quality in terms of resolution and accuracy, taken together they form an accurate, high-resolution, up-to-date, three-dimensional road network that excels where other technologies such as LiDAR fail, e.g., in case of overpasses, overhangs, and so forth. In fact, the 1m spatial resolution dataset created in this research based on 350 million individual 3D location fixes has an RMSE of approximately 3.11m compared to a LiDAR-based ground-truth and can be used to enhance existing road network datasets where individual elevation fixes differ by up to 60m. In contrast, using interpolated data from the National Elevation Dataset (NED results in 4.75m RMSE compared to the base line. We utilize Linked Data technologies to integrate the proposed high-resolution dataset with OpenStreetMap road geometries without requiring any changes to the OSM data model.

ISED: Constructing a high-resolution elevation road dataset from massive, low-quality in-situ observations derived from geosocial fitness tracking data.

Science.gov (United States)

McKenzie, Grant; Janowicz, Krzysztof

2017-01-01

Gaining access to inexpensive, high-resolution, up-to-date, three-dimensional road network data is a top priority beyond research, as such data would fuel applications in industry, governments, and the broader public alike. Road network data are openly available via user-generated content such as OpenStreetMap (OSM) but lack the resolution required for many tasks, e.g., emergency management. More importantly, however, few publicly available data offer information on elevation and slope. For most parts of the world, up-to-date digital elevation products with a resolution of less than 10 meters are a distant dream and, if available, those datasets have to be matched to the road network through an error-prone process. In this paper we present a radically different approach by deriving road network elevation data from massive amounts of in-situ observations extracted from user-contributed data from an online social fitness tracking application. While each individual observation may be of low-quality in terms of resolution and accuracy, taken together they form an accurate, high-resolution, up-to-date, three-dimensional road network that excels where other technologies such as LiDAR fail, e.g., in case of overpasses, overhangs, and so forth. In fact, the 1m spatial resolution dataset created in this research based on 350 million individual 3D location fixes has an RMSE of approximately 3.11m compared to a LiDAR-based ground-truth and can be used to enhance existing road network datasets where individual elevation fixes differ by up to 60m. In contrast, using interpolated data from the National Elevation Dataset (NED) results in 4.75m RMSE compared to the base line. We utilize Linked Data technologies to integrate the proposed high-resolution dataset with OpenStreetMap road geometries without requiring any changes to the OSM data model.

Comprehensive analysis of TEM methods for LiFePO4/FePO4 phase mapping: spectroscopic techniques (EFTEM, STEM-EELS) and STEM diffraction techniques (ACOM-TEM).

Science.gov (United States)

Mu, X; Kobler, A; Wang, D; Chakravadhanula, V S K; Schlabach, S; Szabó, D V; Norby, P; Kübel, C

2016-11-01

Transmission electron microscopy (TEM) has been used intensively in investigating battery materials, e.g. to obtain phase maps of partially (dis)charged (lithium) iron phosphate (LFP/FP), which is one of the most promising cathode material for next generation lithium ion (Li-ion) batteries. Due to the weak interaction between Li atoms and fast electrons, mapping of the Li distribution is not straightforward. In this work, we revisited the issue of TEM measurements of Li distribution maps for LFP/FP. Different TEM techniques, including spectroscopic techniques (energy filtered (EF)TEM in the energy range from low-loss to core-loss) and a STEM diffraction technique (automated crystal orientation mapping (ACOM)), were applied to map the lithiation of the same location in the same sample. This enabled a direct comparison of the results. The maps obtained by all methods showed excellent agreement with each other. Because of the strong difference in the imaging mechanisms, it proves the reliability of both the spectroscopic and STEM diffraction phase mapping. A comprehensive comparison of all methods is given in terms of information content, dose level, acquisition time and signal quality. The latter three are crucial for the design of in-situ experiments with beam sensitive Li-ion battery materials. Furthermore, we demonstrated the power of STEM diffraction (ACOM-STEM) providing additional crystallographic information, which can be analyzed to gain a deeper understanding of the LFP/FP interface properties such as statistical information on phase boundary orientation and misorientation between domains. Copyright © 2016 Elsevier B.V. All rights reserved.

MISTiC Winds, a Micro-Satellite Constellation Approach to High Resolution Observations of the Atmosphere using Infrared Sounding and 3D Winds Measurements

Science.gov (United States)

Maschhoff, K. R.; Polizotti, J. J.; Aumann, H. H.; Susskind, J.

2017-12-01

MISTiCTM Winds is an approach to improve short-term weather forecasting based on a miniature high resolution, wide field, thermal emission spectrometry instrument that will provide global tropospheric vertical profiles of atmospheric temperature and humidity at high (3-4 km) horizontal and vertical ( 1 km) spatial resolution. MISTiC's extraordinarily small size, payload mass of less than 15 kg, and minimal cooling requirements can be accommodated aboard a ESPA-Class (50 kg) micro-satellite. Low fabrication and launch costs enable a LEO sun-synchronous sounding constellation that would provide frequent IR vertical profiles and vertically resolved atmospheric motion vector wind observations in the troposphere. These observations are highly complementary to present and emerging environmental observing systems, and would provide a combination of high vertical and horizontal resolution not provided by any other environmental observing system currently in operation. The spectral measurements that would be provided by MISTiC Winds are similar to those of NASA's Atmospheric Infrared Sounder. These new observations, when assimilated into high resolution numerical weather models, would revolutionize short-term and severe weather forecasting, save lives, and support key economic decisions in the energy, air transport, and agriculture arenas-at much lower cost than providing these observations from geostationary orbit. In addition, this observation capability would be a critical tool for the study of transport processes for water vapor, clouds, pollution, and aerosols. In this third year of a NASA Instrument incubator program, the compact infrared spectrometer has been integrated into an airborne version of the instrument for high-altitude flights on a NASA ER2. The purpose of these airborne tests is to examine the potential for improved capabilities for tracking atmospheric motion-vector wind tracer features, and determining their height using hyper-spectral sounding and

Opto-mechano-electrical tripling in ZnO nanowires probed by photocurrent spectroscopy in a high-resolution transmission electron microscope

Energy Technology Data Exchange (ETDEWEB)

Zhang, C.; Golberg, D., E-mail: xuzhi@iphy.ac.cn, E-mail: golberg.dmitri@nims.go.jp [International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki 3050044 (Japan); Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1, Tsukuba, Ibaraki 3058577 (Japan); Xu, Z., E-mail: xuzhi@iphy.ac.cn, E-mail: golberg.dmitri@nims.go.jp [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Kvashnin, D. G. [National University of Science and Technology, MISIS, Leninskiy Prospect 4, Moscow 119049 (Russian Federation); Tang, D.-M.; Xue, Y. M.; Bando, Y. [International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki 3050044 (Japan); Sorokin, P. B. [National University of Science and Technology, MISIS, Leninskiy Prospect 4, Moscow 119049 (Russian Federation); Moscow Institute of Physics and Technology, Institutsky Lane 9, Dolgoprudny 141700 (Russian Federation)

2015-08-31

Photocurrent spectroscopy of individual free-standing ZnO nanowires inside a high-resolution transmission electron microscope (TEM) is reported. By using specially designed optical in situ TEM system capable of scanning tunneling microscopy probing paired with light illumination, opto-mechano-electrical tripling phenomenon in ZnO nanowires is demonstrated. Splitting of photocurrent spectra at around 3.3 eV under in situ TEM bending of ZnO nanowires directly corresponds to nanowire deformation and appearance of expanded and compressed nanowire sides. Theoretical simulation of a bent ZnO nanowire has an excellent agreement with the experimental data. The splitting effect could be explained by a change in the valence band structure of ZnO nanowires due to a lattice strain. The strain-induced splitting provides important clues for future flexible piezo-phototronics.

Determination of crystallographic and macroscopic orientation of planar structures in TEM

DEFF Research Database (Denmark)

Huang, X.; Liu, Q.

1998-01-01

With the aid of a double-tilt holder in a transmission electron microscope (TEM), simple methods are described for determination of the crystallographic orientation of a planar structure and for calculation of the macroscopic orientation of the planar structure. The correlation between a planar...... structure and a crystallographic plane can be found by comparing the differences in their trace directions on the projection plane and inclination angles with respect to that plane. The angles between the traces of planar structures and the sample axis measured from the TEM micrographs, which have been...

High resolution earth observation from geostationary orbit by optical aperture synthesys

Science.gov (United States)

Mesrine, M.; Thomas, E.; Garin, S.; Blanc, P.; Alis, C.; Cassaing, F.; Laubier, D.

2017-11-01

In this paper, we describe Optical Aperture Synthesis (OAS) imaging instrument concepts studied by Alcatel Alenia Space under a CNES R&T contract in term of technical feasibility. First, the methodology to select the aperture configuration is proposed, based on the definition and quantification of image quality criteria adapted to an OAS instrument for direct imaging of extended objects. The following section presents, for each interferometer type (Michelson and Fizeau), the corresponding optical configurations compatible with a large field of view from GEO orbit. These optical concepts take into account the constraints imposed by the foreseen resolution and the implementation of the co-phasing functions. The fourth section is dedicated to the analysis of the co-phasing methodologies, from the configuration deployment to the fine stabilization during observation. Finally, we present a trade-off analysis allowing to select the concept wrt mission specification and constraints related to instrument accommodation under launcher shroud and in-orbit deployment.

Directrices para la construcción de un repositorio temático

Directory of Open Access Journals (Sweden)

Doria, María Vanesa

2013-04-01

Full Text Available La creación de repositorios de información institucionales y/o temáticos, en nuestros días es la clave para el acceso a producción científica de manera libre y abierta. Por lo tanto, el acceso a la información a través de repositorios de información se ve favorecido por las iniciativas que propone el Acceso Abierto (AA. Para la creación de un repositorio de información en el marco de la filosofía de AA es importante contar con directrices, éstas pretenden ser una guía general de aspectos básicos dónde se detallan los pasos necesarios para la creación de un repositorio. El presente trabajo recoge las directrices para la construcción de repositorios temáticos a partir de los siguientes puntos de referencia: finalidad, funciones, políticas y actividades. Aunque existe un consenso sobre que los repositorios temáticos fueron los primeros en aparecer, existe poca información sobre desarrollo y gestión de repositorios temáticos comparado con la amplitud de información alcanzada por repositorios institucionales

TEMS: an alternative method for the repair of benign recto-vaginal fistulae.

Science.gov (United States)

Darwood, R J; Borley, N R

2008-07-01

The repair of high recto-vaginal fistula can be challenging since access may be limited via the endo-anal approach yet the alternative trans-abdominal route carries significant morbidity. We report the use of TEMS to repair a recto-vaginal fistula following anterior resection and pelvic radiotherapy. The patient was placed prone and a 25 cm rectoscope was inserted. A proximally based mucosal advancement flap was raised to repair the fistula. The patient was discharged 2 days later and a contrast study confirmed closure of the fistula. COMPARISON WITH OTHER TECHNIQUES: TEMS allows excellent visualisation of a rectovaginal fistula compared to standard endo-anal or trans-vaginal techniques. The morbidity is lower than the trans-abdominal route. TEMS is a useful technique for the repair of benign recto-vaginal fistula and has distinct advantages over conventional techniques.

Smoke Dispersion Modeling Over Complex Terrain Using High-Resolution Meteorological Data and Satellite Observations: The FireHub Platform

Science.gov (United States)

Solomos, S.; Amiridis, V.; Zanis, P.; Gerasopoulos, E.; Sofiou, F. I.; Herekakis, T.; Brioude, J.; Stohl, A.; Kahn, R. A.; Kontoes, C.

2015-01-01

A total number of 20,212 fire hot spots were recorded by the Moderate Resolution Imaging Spectroradiometer (MODIS) satellite instrument over Greece during the period 2002e2013. The Fire Radiative Power (FRP) of these events ranged from 10 up to 6000 MW at 1 km resolution, and many of these fire episodes resulted in long-range transport of smoke over distances up to several hundred kilometers. Three different smoke episodes over Greece are analyzed here using real time hot-spot observations from the Spinning Enhanced Visible and Infrared Imager (SEVIRI) satellite instrument as well as from MODIS hot-spots. Simulations of smoke dispersion are performed with the FLEXPART-WRF model and particulate matter emissions are calculated directly from the observed FRP. The modeled smoke plumes are compared with smoke stereo-heights from the Multiangle Imaging Spectroradiometer (MISR) instrument and the sensitivities to atmospheric and modeling parameters are examined. Driving the simulations with high resolution meteorology (4 4 km) and using geostationary satellite data to identify the hot spots allows the description of local scale features that govern smoke dispersion. The long-range transport of smoke is found to be favored over the complex coastline environment of Greece due to the abrupt changes between land and marine planetary boundary layers (PBL) and the decoupling of smoke layers from the surface.

Maredata: red temática sobre datos de investigación en abierto

OpenAIRE

Abadal Falgueras, Ernest; Aleixandre, Rafael; Canals, Agustí; Ferrer, Antonia; Garrigós, Irene; Hernández, Tony; López-Borrull, Alexandre; Mazón, José N.; Melero Melero, Remedios; Méndez Rodríguez, Eva María; Ollé, Eva; Peset Mancebo, María Fernanda

2017-01-01

[ES]El objetivo central de la red temática MAREDATA es aglutinar y consolidar la colaboración entre grupos de investigación españoles centrados en el estudio de los datos científicos y también establecer relación con aquellos sectores y disciplinas interesados en esta temática.

High spectral resolution observations of the H2 2.12 micron line in Herbig-Haro objects

International Nuclear Information System (INIS)

Zinnecker, H.; Mundt, R.; Geballe, T.R.; Zealey, W.J.

1989-01-01

High-spectral-resolution Fabry-Perot observations of the H 2 2.12-micron line emissions of several Herbig-Haro (HH) objects are discussed. It is shown that H 2 emission by the shock heating of external molecular gas in the wings of the bow shock associated with the working surface of a high-velocity jet may occur for HH objects associated with the jet's end. The shock heating of external molecular gas entrained in the flow by internal shocks occurring in the jet itself and/or in its boundary layer may be the H 2 emission mechanism for HH objects observed along the flow axis. 59 refs

Marine Boundary Layer Cloud Property Retrievals from High-Resolution ASTER Observations: Case Studies and Comparison with Terra MODIS

Science.gov (United States)

Werner, Frank; Wind, Galina; Zhang, Zhibo; Platnick, Steven; Di Girolamo, Larry; Zhao, Guangyu; Amarasinghe, Nandana; Meyer, Kerry

2016-01-01

A research-level retrieval algorithm for cloud optical and microphysical properties is developed for the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) aboard the Terra satellite. It is based on the operational MODIS algorithm. This paper documents the technical details of this algorithm and evaluates the retrievals for selected marine boundary layer cloud scenes through comparisons with the operational MODIS Data Collection 6 (C6) cloud product. The newly developed, ASTERspecific cloud masking algorithm is evaluated through comparison with an independent algorithm reported in Zhao and Di Girolamo (2006). To validate and evaluate the cloud optical thickness (tau) and cloud effective radius (r(sub eff)) from ASTER, the high-spatial-resolution ASTER observations are first aggregated to the same 1000m resolution as MODIS. Subsequently, tau(sub aA) and r(sub eff, aA) retrieved from the aggregated ASTER radiances are compared with the collocated MODIS retrievals. For overcast pixels, the two data sets agree very well with Pearson's product-moment correlation coefficients of R greater than 0.970. However, for partially cloudy pixels there are significant differences between r(sub eff, aA) and the MODIS results which can exceed 10 micrometers. Moreover, it is shown that the numerous delicate cloud structures in the example marine boundary layer scenes, resolved by the high-resolution ASTER retrievals, are smoothed by the MODIS observations. The overall good agreement between the research-level ASTER results and the operational MODIS C6 products proves the feasibility of MODIS-like retrievals from ASTER reflectance measurements and provides the basis for future studies concerning the scale dependency of satellite observations and three-dimensional radiative effects.

The principle of electron microscopy; SEM and TEM

International Nuclear Information System (INIS)

Fauzi, S.H.

1992-01-01

The article reviews the principle of electron microscopy which is used in scanning electron microscope (SEM) and transmission electron microscope (TEM). These instruments are important for the examination and analysis of the microstructural properties of solid objects. Relevance physical concept lies behind the devices are given. The main components of each device are also discussed

GISAXS modelling of helium-induced nano-bubble formation in tungsten and comparison with TEM

International Nuclear Information System (INIS)

Thompson, Matt; Sakamoto, Ryuichi; Bernard, Elodie; Kirby, Nigel; Kluth, Patrick; Riley, Daniel; Corr, Cormac

2016-01-01

Grazing-incidence small angle x-ray scattering (GISAXS) is a powerful non-destructive technique for the measurement of nano-bubble formation in tungsten under helium plasma exposure. Here, we present a comparative study between transmission electron microscopy (TEM) and GISAXS measurements of nano-bubble formation in tungsten exposed to helium plasma in the Large Helical Device (LHD) fusion experiment. Both techniques are in excellent agreement, suggesting that nano-bubbles range from spheroidal to ellipsoidal, displaying exponential diameter distributions with mean diameters μ=0.68 ± 0.04 nm and μ=0.6 ± 0.1 nm measured by TEM and GISAXS respectively. Depth distributions were also computed, with calculated exponential depth distributions with mean depths of 8.4 ± 0.5 nm and 9.1 ± 0.4 nm for TEM and GISAXS. In GISAXS modelling, spheroidal particles were fitted with an aspect ratio ε=0.7 ± 0.1. The GISAXS model used is described in detail. - Highlights: • GISAXS and TEM were used to measure nano-bubble formation in W exposed to He plasma in the large helical device. • Nano-bubbles had an exponential diameter distributions with averages 0.6 ± 0.1 nm and 0.68 ± 0.04 nm measured by GISAXS and TEM. • Nano-bubbles had an exponential depth distributions with average depths of 9.1 ± 0.4 nm and 8.4 ± 0.5 nm for GISAXS and TEM. • The GISAXS model used to analyse diffraction patterns is explained in detail.

GISAXS modelling of helium-induced nano-bubble formation in tungsten and comparison with TEM

Energy Technology Data Exchange (ETDEWEB)

Thompson, Matt, E-mail: matt.a.thompson@anu.edu.au [Research School of Physics and Engineering, Australian National University, Mills Road, Acton, ACT 2601 (Australia); Sakamoto, Ryuichi [National Institute for Fusion Science, Toki, Gifu 509-5292 (Japan); Bernard, Elodie [Aix-Marseille University, Marseille 13288 (France); Kirby, Nigel [SAXS/WAXS Beamline, Australian Synchrotron, 800 Blackburn Rd, Clayton, VIC, 3168 (Australia); Kluth, Patrick [Research School of Physics and Engineering, Australian National University, Mills Road, Acton, ACT 2601 (Australia); Riley, Daniel [Australian Nuclear Science and Technology Organisation, Locked Bag 2001, Kirrawee DC, NSW, 2232 (Australia); Corr, Cormac [Research School of Physics and Engineering, Australian National University, Mills Road, Acton, ACT 2601 (Australia)

2016-05-15

Grazing-incidence small angle x-ray scattering (GISAXS) is a powerful non-destructive technique for the measurement of nano-bubble formation in tungsten under helium plasma exposure. Here, we present a comparative study between transmission electron microscopy (TEM) and GISAXS measurements of nano-bubble formation in tungsten exposed to helium plasma in the Large Helical Device (LHD) fusion experiment. Both techniques are in excellent agreement, suggesting that nano-bubbles range from spheroidal to ellipsoidal, displaying exponential diameter distributions with mean diameters μ=0.68 ± 0.04 nm and μ=0.6 ± 0.1 nm measured by TEM and GISAXS respectively. Depth distributions were also computed, with calculated exponential depth distributions with mean depths of 8.4 ± 0.5 nm and 9.1 ± 0.4 nm for TEM and GISAXS. In GISAXS modelling, spheroidal particles were fitted with an aspect ratio ε=0.7 ± 0.1. The GISAXS model used is described in detail. - Highlights: • GISAXS and TEM were used to measure nano-bubble formation in W exposed to He plasma in the large helical device. • Nano-bubbles had an exponential diameter distributions with averages 0.6 ± 0.1 nm and 0.68 ± 0.04 nm measured by GISAXS and TEM. • Nano-bubbles had an exponential depth distributions with average depths of 9.1 ± 0.4 nm and 8.4 ± 0.5 nm for GISAXS and TEM. • The GISAXS model used to analyse diffraction patterns is explained in detail.

Analysis of arsenic speciation in mine contaminated lacustrine sediment using selective sequential extraction, HR-ICPMS and TEM

International Nuclear Information System (INIS)

Haus, Kelly L.; Hooper, Robert L.; Strumness, Laura A.; Mahoney, J. Brian

2008-01-01

In order to determine how As speciation in lacustrine sediment changes as a function of local conditions, sediment cores were taken from three lakes with differing hydrologic regimes and subjected to extensive chemical and TEM analysis. The lakes (Killarney, Thompson and Swan Lakes) are located within the Coeur d' Alene River system (northern Idaho, USA), which has been contaminated with trace metals and As, from over 100 a of sulfide mining. Previous analyses of these lakebed sediments have shown an extensive amount of contaminant metals and As associated with sub-μm grains, making them extremely difficult to analyze using standard methods (scanning electron microscopy, X-ray diffraction). Transmission electron microscopy offers great advantages in spatial resolution and can be invaluable in determining As speciation when combined with other techniques. Data indicate that because of differences in local redox conditions, As speciation and stability is dramatically different in these lakes. Killarney and Thompson Lakes experience seasonal water-level fluctuations due to drawdown on a downstream dam, causing changes in O 2 content in sediment exposed during drawdown. Swan Lake has relatively constant water levels as its only inlet is dammed. Consequently, Killarney and Thompson Lakes show an increase in labile As-bearing phases with depth, while Swan Lake data indicate stable As hosts throughout the sediment profile. Based on these observations it can be stated that As in lakebed sediments is much less mobile, and therefore less bioavailable, when water is kept at a constant level

In-situ TEM study of dislocation patterning during deformation in single crystal aluminum

International Nuclear Information System (INIS)

Landau, P; Shneck, R Z; Makov, G; Venkert, A

2010-01-01

The evolution of dislocation patterns in single crystal aluminum was examined using transmission electron microscopy (TEM). In-situ tensile tests of single crystals were carried out in a manner that activated double slip. Cross slip of dislocations, which is prominent in all stages of work hardening, plays an important role in dislocation motion and microstructural evolution. In spite of the limitations of in-situ straining to represent bulk phenomena, due to surface effects and the thickness of the samples, it is shown that experiments on prestrained samples can represent the early stages of deformation. Transition between stage I and stage II of work hardening and evolution during stage III were observed.

In-situ TEM on (de)hydrogenation of Pd at 0.5–4.5 bar hydrogen pressure and 20–400°C

International Nuclear Information System (INIS)

Yokosawa, Tadahiro; Alan, Tuncay; Pandraud, Gregory; Dam, Bernard; Zandbergen, Henny

2012-01-01

We have developed a nanoreactor, sample holder and gas system for in-situ transmission electron microscopy (TEM) of hydrogen storage materials up to at least 4.5 bar. The MEMS-based nanoreactor has a microheater, two electron-transparent windows and a gas inlet and outlet. The holder contains various O-rings to have leak-tight connections with the nanoreactor. The system was tested with the (de)hydrogenation of Pd at pressures up to 4.5 bar. The Pd film consisted of islands being 15 nm thick and 50–500 nm wide. In electron diffraction mode we observed reproducibly a crystal lattice expansion and shrinkage owing to hydrogenation and dehydrogenation, respectively. In selected-area electron diffraction and bright/dark-field modes the (de)hydrogenation of individual Pd particles was followed. Some Pd islands are consistently hydrogenated faster than others. When thermally cycled, thermal hysteresis of about 10–16 °C between hydrogen absorption and desorption was observed for hydrogen pressures of 0.5–4.5 bar. Experiments at 0.8 bar and 3.2 bar showed that the (de)hydrogenation temperature is not affected by the electron beam. This result shows that this is a fast method to investigate hydrogen storage materials with information at the nanometer scale. -- Highlights: ► In-situ TEM experiments up to 4.5 bar. ► In-situ TEM on a hydrogen storage material at pressures used in practice. ► No electron beam effect on (de)hydrogenation. ► In-situ TEM allows for fast screening of hydrogen storage materials.

Nonlinear interplay of TEM and ITG turbulence and its effect on transport

Science.gov (United States)

Merz, F.; Jenko, F.

2010-05-01

The dominant source of anomalous transport in fusion plasmas on ion scales is turbulence driven by trapped electron modes (TEMs) and ion temperature gradient (ITG) modes. While the individual properties of each of these two instabilities and the corresponding microturbulence have been examined in detail in the past, the effects of a coexistence of the two modes and the phenomena of transitions between the TEM and ITG dominated regimes are not well studied. In many experimental situations, the temperature and density gradients support both microinstabilities simultaneously, so that transitional regimes are important for a detailed understanding of fusion plasmas. In this paper, this issue is addressed, using the gyrokinetic code GENE for a detailed investigation of the dominant and subdominant linear instabilities and the corresponding nonlinear system. A simple quasilinear model based on eigenvalue computations is presented which is shown to reproduce important features of the nonlinear TEM-ITG transition.

Observation of human embryonic behavior in vitro by high-resolution time-lapse cinematography.

Science.gov (United States)

Iwata, Kyoko; Mio, Yasuyuki

2016-07-01

Assisted reproductive technology (ART) has yielded vast amounts of information and knowledge on human embryonic development in vitro; however, still images provide limited data on dynamic changes in the developing embryos. Using our high-resolution time-lapse cinematography (hR-TLC) system, we were able to describe normal human embryonic development continuously from the fertilization process to the hatched blastocyst stage in detail. Our hR-TLC observation also showed the embryonic abnormality of a third polar body (PB)-like substance likely containing a small pronucleus being extruded and resulting in single-pronucleus (1PN) formation, while our molecular biological investigations suggested the possibility that some 1PN embryos could be diploid, carrying both maternal and paternal genomes. Furthermore, in some embryos the extruded third PB-like substance was eventually re-absorbed into the ooplasm resulting in the formation of an uneven-sized, two-PN zygote. In addition, other hR-TLC observations showed that cytokinetic failure was correlated with equal-sized, multi-nucleated blastomeres that were also observed in the embryo showing early initiation of compaction. Assessment combining our hR-TLC with molecular biological techniques enables a better understanding of embryonic development and potential improvements in ART outcomes.

High Temporal Resolution Tropospheric Wind Profile Observations at NASA Kennedy Space Center During Hurricane Irma

Science.gov (United States)

Decker, Ryan K.; Barbre, Robert E., Jr.; Huddleston, Lisa; Brauer, Thomas; Wilfong, Timothy

2018-01-01

The NASA Kennedy Space Center (KSC) operates a 48-MHz Tropospheric/Stratospheric Doppler Radar Wind Profiler (TDRWP) on a continual basis generating wind profiles between 2-19 km in the support of space launch vehicle operations. A benefit of the continual operability of the system is the ability to provide unique observations of severe weather events such as hurricanes. Over the past two Atlantic Hurricane seasons the TDRWP has made high temporal resolution wind profile observations of Hurricane Irma in 2017 and Hurricane Matthew in 2016. Hurricane Irma was responsible for power outages to approximately 2/3 of Florida's population during its movement over the state(Stein,2017). An overview of the TDRWP system configuration, brief summary of Hurricanes Irma and Matthew storm track in proximity to KSC, characteristics of the tropospheric wind observations from the TDRWP during both events, and discussion of the dissemination of TDRWP data during the event will be presented.

TEM and ellipsometry studies of nanolaminate oxide films prepared using atomic layer deposition

Energy Technology Data Exchange (ETDEWEB)

Mitchell, D.R.G. [Materials and Engineering Science, ANSTO, PMB 1, Menai, NSW 2234 (Australia)]. E-mail: drm@ansto.gov.au; Attard, D.J. [Materials and Engineering Science, ANSTO, PMB 1, Menai, NSW 2234 (Australia); Finnie, K.S. [Materials and Engineering Science, ANSTO, PMB 1, Menai, NSW 2234 (Australia); Triani, G. [Materials and Engineering Science, ANSTO, PMB 1, Menai, NSW 2234 (Australia); Barbe, C.J. [Materials and Engineering Science, ANSTO, PMB 1, Menai, NSW 2234 (Australia); Depagne, C. [Materials and Engineering Science, ANSTO, PMB 1, Menai, NSW 2234 (Australia); Bartlett, J.R. [Materials and Engineering Science, ANSTO, PMB 1, Menai, NSW 2234 (Australia)

2005-04-30

Nanolaminate oxide layers consisting of TiO{sub 2} and Al{sub 2}O{sub 3} have been deposited on silicon using atomic layer deposition (ALD). Characterisation of these films has been achieved by use of a range of modern transmission electron microscopy (TEM)-based techniques, including plasmon loss imaging, energy filtered imaging and scanning TEM (STEM) X-ray line profiling. These have shown that the target thickness of the individual layers in the nanolaminate structures (20 nm) has been met with a high degree of accuracy, that the layers are extremely flat and parallel and that the interfaces between the layers are compositionally abrupt. Localised crystallisation within the stacks, and responses to electron beam irradiation point to the presence of a stress gradient within the layers. The performance of ellipsometry in characterising multilayer stacks has been benchmarked against the TEM measurements. Errors in determination of individual layer thicknesses were found to increase with growing stack size, as expected given the increasing number of interfaces incorporated in each model. The most sophisticated model gave maximum deviations of {+-}4 nm from the TEM determined values for the 5- and 10-layer stacks.

High-Resolution Assimilation of GRACE Terrestrial Water Storage Observations to Represent Local-Scale Water Table Depths

Science.gov (United States)

Stampoulis, D.; Reager, J. T., II; David, C. H.; Famiglietti, J. S.; Andreadis, K.

2017-12-01

Despite the numerous advances in hydrologic modeling and improvements in Land Surface Models, an accurate representation of the water table depth (WTD) still does not exist. Data assimilation of observations of the joint NASA and DLR mission, Gravity Recovery and Climate Experiment (GRACE) leads to statistically significant improvements in the accuracy of hydrologic models, ultimately resulting in more reliable estimates of water storage. However, the usually shallow groundwater compartment of the models presents a problem with GRACE assimilation techniques, as these satellite observations account for much deeper aquifers. To improve the accuracy of groundwater estimates and allow the representation of the WTD at fine spatial scales we implemented a novel approach that enables a large-scale data integration system to assimilate GRACE data. This was achieved by augmenting the Variable Infiltration Capacity (VIC) hydrologic model, which is the core component of the Regional Hydrologic Extremes Assessment System (RHEAS), a high-resolution modeling framework developed at the Jet Propulsion Laboratory (JPL) for hydrologic modeling and data assimilation. The model has insufficient subsurface characterization and therefore, to reproduce groundwater variability not only in shallow depths but also in deep aquifers, as well as to allow GRACE assimilation, a fourth soil layer of varying depth ( 1000 meters) was added in VIC as the bottom layer. To initialize a water table in the model we used gridded global WTD data at 1 km resolution which were spatially aggregated to match the model's resolution. Simulations were then performed to test the augmented model's ability to capture seasonal and inter-annual trends of groundwater. The 4-layer version of VIC was run with and without assimilating GRACE Total Water Storage anomalies (TWSA) over the Central Valley in California. This is the first-ever assimilation of GRACE TWSA for the determination of realistic water table depths, at

Sensitivity of Global Methane Bayesian Inversion to Surface Observation Data Sets and Chemical-Transport Model Resolution

Science.gov (United States)

Lew, E. J.; Butenhoff, C. L.; Karmakar, S.; Rice, A. L.; Khalil, A. K.

2017-12-01

Methane is the second most important greenhouse gas after carbon dioxide. In efforts to control emissions, a careful examination of the methane budget and source strengths is required. To determine methane surface fluxes, Bayesian methods are often used to provide top-down constraints. Inverse modeling derives unknown fluxes using observed methane concentrations, a chemical transport model (CTM) and prior information. The Bayesian inversion reduces prior flux uncertainties by exploiting information content in the data. While the Bayesian formalism produces internal error estimates of source fluxes, systematic or external errors that arise from user choices in the inversion scheme are often much larger. Here we examine model sensitivity and uncertainty of our inversion under different observation data sets and CTM grid resolution. We compare posterior surface fluxes using the data product GLOBALVIEW-CH4 against the event-level molar mixing ratio data available from NOAA. GLOBALVIEW-CH4 is a collection of CH4 concentration estimates from 221 sites, collected by 12 laboratories, that have been interpolated and extracted to provide weekly records from 1984-2008. Differently, the event-level NOAA data records methane mixing ratios field measurements from 102 sites, containing sampling frequency irregularities and gaps in time. Furthermore, the sampling platform types used by the data sets may influence the posterior flux estimates, namely fixed surface, tower, ship and aircraft sites. To explore the sensitivity of the posterior surface fluxes to the observation network geometry, inversions composed of all sites, only aircraft, only ship, only tower and only fixed surface sites, are performed and compared. Also, we investigate the sensitivity of the error reduction associated with the resolution of the GEOS-Chem simulation (4°×5° vs 2°×2.5°) used to calculate the response matrix. Using a higher resolution grid decreased the model-data error at most sites, thereby

Atomic-resolution studies of In{sub 2}O{sub 3}-ZnO compounds on aberration-corrected electron microscopes

Energy Technology Data Exchange (ETDEWEB)

Yu, Wentao

2009-10-23

In this work, the characteristic inversion domain microstructures of In{sub 2}O{sub 3}(ZnO){sub m} (m=30) compounds were investigated by TEM methods. At bright-atom contrast condition, atomically resolved HR-TEM images of In{sub 2}O{sub 3}(ZnO){sub 30} were successfully acquired in [1 anti 100] zone axis of ZnO, with projected metal columns of {proportional_to}1.6 A well resolved. From contrast maxima in the TEM images, local lattice distortions at the pyramidal inversion domain boundaries were observed for the first time. Lattice displacements and the strain field in two-dimensions were visualized and measured using the 'DALI' algorithm. Atomically resolved single shot and focal series images of In{sub 2}O{sub 3}(ZnO){sub 30} were achieved in both zone axes of ZnO, [1 anti 100] and [2 anti 1 anti 10], respectively. The electron waves at the exit-plane were successfully reconstructed using the software package 'TrueImage'. Finally, a three dimensional atomic structure model for the pyramidal IDB was proposed, with an In distribution of 10%, 20%, 40%, 20% and 10% of In contents over 5 atom columns along basal planes, respectively. Through a detailed structural study of In{sub 2}O{sub 3}(ZnO){sub m} compounds by using phase-contrast and Z-contrast imaging at atomic resolution, In{sup 3+} atoms are determined with trigonal bi-pyramidal co-ordination and are distributed at the pyramidal IDBs. (orig.)

Characterization of crystallite morphology for doped strontium fluoride nanophosphors by TEM and XRD

Energy Technology Data Exchange (ETDEWEB)

O' Connell, J.H. [Centre for HRTEM, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth ZA6031 (South Africa); Lee, M.E., E-mail: Michael.lee@nmmu.ac.za [Centre for HRTEM, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth ZA6031 (South Africa); Yagoub, M.Y.A.; Swart, H.C.; Coetsee, E. [Department of Physics, University of the Free State, PO Box 339, Bloemfontein ZA9300 (South Africa)

2016-01-01

Crystallite morphology for Eu-doped and undoped SrF{sub 2} nanophosphors have been determined by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The values for average crystallite size obtained by the application of the Scherrer equation and the full width at half maximum (FWHM) values for XRD peaks are compared to the results obtained using the hollow cone dark field (HCDF) TEM imaging technique. In the case of the TEM analysis, a bimodal crystallite size distribution was revealed with one of the distributions having a measured range of crystallite sizes which was in good agreement with the XRD data. HCDF in combination with FIB specimen preparation was found to be a promising technique for the determination of crystallite size distributions in nanophosphors which might facilitate a better understanding of their scintillation properties.

Characterization of crystallite morphology for doped strontium fluoride nanophosphors by TEM and XRD

International Nuclear Information System (INIS)

O'Connell, J.H.; Lee, M.E.; Yagoub, M.Y.A.; Swart, H.C.; Coetsee, E.

2016-01-01

Crystallite morphology for Eu-doped and undoped SrF_2 nanophosphors have been determined by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The values for average crystallite size obtained by the application of the Scherrer equation and the full width at half maximum (FWHM) values for XRD peaks are compared to the results obtained using the hollow cone dark field (HCDF) TEM imaging technique. In the case of the TEM analysis, a bimodal crystallite size distribution was revealed with one of the distributions having a measured range of crystallite sizes which was in good agreement with the XRD data. HCDF in combination with FIB specimen preparation was found to be a promising technique for the determination of crystallite size distributions in nanophosphors which might facilitate a better understanding of their scintillation properties.

FE-SEM, FIB and TEM Study of Surface Deposits of Apollo 15 Green Glass Volcanic Spherules

Science.gov (United States)

Ross, Daniel K.; Thomas-Keprta, K. L.; Rahman, Z.; Wentworth, S. J.; McKay, D. S.

2011-01-01

Surface deposits on lunar pyroclastic green (Apollo 15) and orange (Apollo 17) glass spherules have been attributed to condensation from the gas clouds that accompanied fire-fountain eruptions. The fire fountains cast molten lava high above the lunar surface and the silicate melt droplets quenched before landing producing the glass beads. Early investigations showed that these deposits are rich in sulfur and zinc. The deposits are extremely fine-grained and thin, so that it was never possible to determine their chemical compositions cleanly by SEM/EDX or electron probe x-ray analysis because most of the excited volume was in the under-lying silicate glass. We are investigating the surface deposits by TEM, using focused ion beam (FIB) microscopy to extract and thin the surface deposits. Here we report on chemical mapping of a FIB section of surface deposits of an Apollo green glass bead 15401using the ultra-high resolution JEOL 2500 STEM located at NASA Johnson Space Center.

Mapping High-Resolution Soil Moisture over Heterogeneous Cropland Using Multi-Resource Remote Sensing and Ground Observations

Directory of Open Access Journals (Sweden)

Lei Fan

2015-10-01

Full Text Available High spatial resolution soil moisture (SM data are crucial in agricultural applications, river-basin management, and understanding hydrological processes. Merging multi-resource observations is one of the ways to improve the accuracy of high spatial resolution SM data in the heterogeneous cropland. In this paper, the Bayesian Maximum Entropy (BME methodology is implemented to merge the following four types of observed data to obtain the spatial distribution of SM at 100 m scale: soil moisture observed by wireless sensor network (WSN, Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER-derived soil evaporative efficiency (SEE, irrigation statistics, and Polarimetric L-band Multi-beam Radiometer (PLMR-derived SM products (~700 m. From the poor BME predictions obtained by merging only WSN and SEE data, we observed that the SM heterogeneity caused by irrigation and the attenuating sensitivity of the SEE data to SM caused by the canopies result in BME prediction errors. By adding irrigation statistics to the merged datasets, the overall RMSD of the BME predictions during the low-vegetated periods can be successively reduced from 0.052 m3·m−3 to 0.033 m3·m−3. The coefficient of determination (R2 and slope between the predicted and in situ measured SM data increased from 0.32 to 0.64 and from 0.38 to 0.82, respectively, but large estimation errors occurred during the moderately vegetated periods (RMSD = 0.041 m3·m−3, R = 0.43 and the slope = 0.41. Further adding the downscaled SM information from PLMR SM products to the merged datasets, the predictions were satisfactorily accurate with an RMSD of 0.034 m3·m−3, R2 of 0.4 and a slope of 0.69 during moderately vegetated periods. Overall, the results demonstrated that merging multi-resource observations into SM estimations can yield improved accuracy in heterogeneous cropland.

TEM and Moessbauer Study of Nano Sized Fe2MnAl Flakes

International Nuclear Information System (INIS)

Vinesh, A.; Sudheesh, V. D.; Lakshmi, N.; Venugopalan, K.

2011-01-01

Magnetic and structural properties of L21 ordered Fe 2 MnAl Heusler alloy have been studied by X-ray diffraction, Transmission electron microscopy (TEM), Moessbauer spectroscopy and DC magnetization. Structural texturing induced by ball milling is destroyed on heating while Moessbauer and DC magnetization studies show magnetic texturing persists after thermal treatment. TEM shows large distribution in particle size with an average size of 27 nm. Thermal annealing of ball milled sample results L2 1 ordering and the needle shaped particle contributes spin texturing.

Phase analysis of nano-phase materials using selected area electron diffraction in the TEM

International Nuclear Information System (INIS)

Labar, J. L.

2002-01-01

In analogy to X-ray power diffraction (XRD), we are developing a method to help phase identification when examining a large number of grains simultaneously by electron diffraction. Although XRD is well established, it can not be used for small quantities of materials (volumes below 1 mm 3 ). Examining a usual TEM sample with thickness of 100 nm and using a selected area of 1 mm in diameter, the selected area electron diffraction pattern (SAED) carries information about several thousands of grains from a material with an average grain size of about 10 nm. The accuracy of XRD can not be attained by electron diffraction (ED). However, simultaneous visual observation of the nanostructure is an additional benefit of TEM (beside the small amount of needed material). The first step of the development project was the development of a computer program ('ProcessDiffraction') that processes digital versions of SAED patterns and presents them in an XRD-like form (intensity vs. scattering vector). In the present version (V2.0.3) phase identification is carried out by comparing the measured distribution to 'Markers', i.e. data of known phases. XRD data cards are used if the detailed structure of a phase is not known. Kinematic electron diffraction intensities are calculated for phases with known atomic positions (Author)

The measurement and calculation of the X-ray spatial resolution obtained in the analytical electron microscope

International Nuclear Information System (INIS)

Michael, J.R.; Williams, D.B.

1990-01-01

The X-ray microanalytical spatial resolution is determined experimentally in various analytical electron microscopes by measuring the degradation of an atomically discrete composition profile across an interphase interface in a thin-foil of Ni-Cr-Fe. The experimental spatial resolutions are then compared with calculated values. The calculated spatial resolutions are obtained by the mathematical convolution of the electron probe size with an assumed beam-broadening distribution and the single-scattering model of beam broadening. The probe size is measured directly from an image of the probe in a TEM/SETEM and indirectly from dark-field signal changes resulting from scanning the probe across the edge of an MgO crystal in a dedicated STEM. This study demonstrates the applicability of the convolution technique to the calculation of the microanalytical spatial resolution obtained in the analytical electron microscope. It is demonstrated that, contrary to popular opinion, the electron probe size has a major impact on the measured spatial resolution in foils < 150 nm thick. (author)

Transanal endoscopic microsurgery with 3-D (TEM) or high-definition 2-D transanal endoscopic operation (TEO) for rectal tumors. A prospective, randomized clinical trial.

Science.gov (United States)

Serra-Aracil, Xavier; Mora-Lopez, Laura; Alcantara-Moral, Manel; Caro-Tarrago, Aleidis; Navarro-Soto, Salvador

2014-05-01

Transanal endoscopic microsurgery (TEM) is a three-dimensional viewing endoscopic system procedure which provides access to rectal tumors through a rectoscope. Two-dimensional transanal endoscopic operation (TEO), with the introduction of high-definition vision, achieves results that are comparable to those of the classical TEM. The main aim of the study was to compare the effectiveness of TEO and TEM systems in a prospective, randomized clinical trial. patients meeting inclusion criteria for diagnosis of rectal tumors with curative intent. Sample size, 36 patients. Patients were randomized to receive one of the two procedures. Study variables recorded were the following: preoperative data (time taken to assemble equipment, surgical time, quality of pneumorectum), postoperative morbidity and mortality, pathology study of the tumors, and economic analysis. Thirty-six patients were analyzed according to intention to treat. Two patients were excluded. The final per-protocol analysis was 34 patients. There were no significant differences in the preoperative or operative variables, quality of pneumorectum, postoperative variables, or pathology results. A trend toward benefit was observed in favor of TEO in time required for assembly, surgical suture time, and total surgical time though the differences were not statistically significant. Statistically significant differences were found in terms of the total cost of the procedure, with mean costs of 2,031  ± 440 for TEO and 2,603  ± 507 for TEM (95% CI 218.15-926.486 , p = 0.003). No technical or clinical differences were observed between the results obtained with the two systems except lower cost with TEO.

Analysis and design of a coupled coaxial line TEM resonator for magnetic resonance imaging

International Nuclear Information System (INIS)

Benahmed, Nasreddine; Feham, Mohammed; Khelif, M'Hamed

2006-01-01

In this paper, we have successfully realized a numerical tool to analyse and to design an n-element unloaded coaxial line transverse electromagnetic (TEM) resonator. This numerical tool allows the determination of the primary parameters, matrices [L], [C] and [R], and simulates the frequency response of S 11 at the RF port of the designed TEM resonator. The frequency response permits evaluation of the unloaded quality factor Q 0 . As an application, we present the analysis and the design of an eight-element unloaded TEM resonator for animal studies at 4.7 T. The simulated performance has a -62.81 dB minimum reflection and a quality factor of 260 around 200 MHz

Deformation Mechanisms and Fracture of Ni-Based Metallic Glasses

Directory of Open Access Journals (Sweden)

Lesz S.

2016-06-01

Full Text Available The cracking of materials and fracture surface is of great practical and academic importance. Over the last few years the development of the fractography of crystalline alloys resulted in a useful tool for the prediction or failure analysis. Many attempts have been made to observe cracks using optical microscopy, X-ray topography and transmission electron microscopy (TEM. Of these techniques, the resolution of optical microscopy and X-ray topography is too poor. By contrast, the resolution of TEM is high enough for detailed information to be obtained. However, in order to apply TEM observations, a thin foil specimen must be prepared, and it is usually extremely difficult to prepare such a specimen from a pre-selected region containing a crack.

A flexible multi-stimuli in situ (S)TEM: Concept, optical performance, and outlook

International Nuclear Information System (INIS)

Börrnert, Felix; Müller, Heiko; Riedel, Thomas; Linck, Martin; Kirkland, Angus I.; Haider, Max.; Büchner, Bernd; Lichte, Hannes

2015-01-01

The progress in (scanning) transmission electron microscopy development had led to an unprecedented knowledge of the microscopic structure of functional materials at the atomic level. Additionally, although not widely used yet, electron holography is capable to map the electric and magnetic potential distributions at the sub-nanometer scale. Nevertheless, in situ studies inside a (scanning) transmission electron microscope ((S)TEM) are extremely challenging because of the much restricted size and accessibility of the sample space. Here, we introduce a concept for a dedicated in situ (S)TEM with a large sample chamber for flexible multi-stimuli experimental setups and report about the electron optical performance of the instrument. We demonstrate a maximum resolving power of about 1 nm in conventional imaging mode and substantially better than 5 nm in scanning mode while providing an effectively usable “pole piece gap” of 70 mm. - Highlights: • A concept for a (S)TEM with a large sample chamber is outlined. • An actual microscope is modified and has now a 70 mm high sample space. • The resolving power is about 1 nm in TEM and better than 5 nm in STEM mode. • Possible dedicated in situ microscopes with present technology are discussed

A flexible multi-stimuli in situ (S)TEM: Concept, optical performance, and outlook

Energy Technology Data Exchange (ETDEWEB)

Börrnert, Felix, E-mail: felix.boerrnert@triebenberg.de [Speziallabor Triebenberg, Technische Universität Dresden, 01062 Dresden (Germany); IFW Dresden, PF 27 01 16, 01171 Dresden (Germany); Department of Materials, University of Oxford, Parks Road, Oxford OX1 3PH (United Kingdom); Müller, Heiko; Riedel, Thomas; Linck, Martin [CEOS GmbH, Englerstraße 28, 69126 Heidelberg (Germany); Kirkland, Angus I. [Department of Materials, University of Oxford, Parks Road, Oxford OX1 3PH (United Kingdom); Haider, Max. [CEOS GmbH, Englerstraße 28, 69126 Heidelberg (Germany); Büchner, Bernd [IFW Dresden, PF 27 01 16, 01171 Dresden (Germany); Lichte, Hannes [Speziallabor Triebenberg, Technische Universität Dresden, 01062 Dresden (Germany)

2015-04-15

The progress in (scanning) transmission electron microscopy development had led to an unprecedented knowledge of the microscopic structure of functional materials at the atomic level. Additionally, although not widely used yet, electron holography is capable to map the electric and magnetic potential distributions at the sub-nanometer scale. Nevertheless, in situ studies inside a (scanning) transmission electron microscope ((S)TEM) are extremely challenging because of the much restricted size and accessibility of the sample space. Here, we introduce a concept for a dedicated in situ (S)TEM with a large sample chamber for flexible multi-stimuli experimental setups and report about the electron optical performance of the instrument. We demonstrate a maximum resolving power of about 1 nm in conventional imaging mode and substantially better than 5 nm in scanning mode while providing an effectively usable “pole piece gap” of 70 mm. - Highlights: • A concept for a (S)TEM with a large sample chamber is outlined. • An actual microscope is modified and has now a 70 mm high sample space. • The resolving power is about 1 nm in TEM and better than 5 nm in STEM mode. • Possible dedicated in situ microscopes with present technology are discussed.

Determination of Size Distributions in Nanocrystalline Powders by TEM, XRD and SAXS

DEFF Research Database (Denmark)

Jensen, Henrik; Pedersen, Jørgen Houe; Jørgensen, Jens Erik

2006-01-01

Crystallite size distributions and particle size distributions were determined by TEM, XRD, and SAXS for three commercially available TiO2 samples and one homemade. The theoretical Guinier Model was fitted to the experimental data and compared to analytical expressions. Modeling of the XRD spectra...... the size distribution obtained from the XRD experiments; however, a good agreement was obtained between the two techniques. Electron microscopy, SEM and TEM, confirmed the primary particle sizes, the size distributions, and the shapes obtained by XRD and SAXS. The SSEC78 powder and the commercially...

SEM and TEM Observation of the Surfaces of the Fine-Grained Particles Retrieved from the Muses-C Regio on the Asteroid 25413 Itokawa

Science.gov (United States)

Noguchi, T.; Nakamura, T.; Zolensky, Michael E.; Tanaka, M.; Hashimoto, T.; Konno, M.; Nakato, A.; Ogami, T.; Fujimura, A.; Abe, M.;

In-Situ TEM Study of a Nanoporous Ni–Co Catalyst Used for the Dry Reforming of Methane

Directory of Open Access Journals (Sweden)

Takeshi Fujita

2017-10-01

Full Text Available We performed in-situ transmission electron microscopy (TEM on a dealloyed nanoporous NiCo catalyst used for the dry reforming of methane (DRM to investigate the origin of the catalytic activity and structural durability. The in-situ observations and local chemical analysis indicated that the DRM induced chemical demixing of Ni and Co accompanied by grain refinement, implying possible “synergic effects” in a general bimetallic NiCo catalyst when used for the DRM.

Dynamics of Saturn’s 2010 Great White Spot from high-resolution Cassini ISS observations

Science.gov (United States)

Hueso, Ricardo; Sánchez-Lavega, A.; del Río-Gaztelurrutia, T.

2012-10-01

On December 5th 2010 a storm erupted in Saturn’s North Temperate latitudes which were experiencing early spring season. The storm quickly developed to a planet-wide disturbance of the Great White Spot type. The ISS instrument onboard Cassini acquired its first images of the storm on 23th December 2010 and performed repeated observations with a variety of spatial resolutions over the nearly 10 months period the storm continued active. Here we present an analysis of two of the image sequences with better spatial resolution of the mature storm when it was fully developed and very active. We used an image correlation algorithm to measure the cloud motions obtained from images separated 20 minutes and obtained 16,000 wind tracers in a domain of 60 degrees longitude per 20 degrees in latitude. Intense zonal and meridional motions accompanied the storm and reached values of 120 m/s in particular regions of the active storm. The storm released a chain of anticyclonic and cyclonic vortices at planetocentric latitudes of 36° and 32° respectively. The short time difference between the images results in estimated wind uncertainties of 15 m/s that did not allow to perform a complete analysis of the turbulence and kinetic spectrum of the motions. We identify locations of the updrafts and link those with the morphology in different observing filters. The global behaviour of the storm was examined in images separated by 10 hours confirming the intensity of the winds and the global behaviour of the vortices. Acknowledgments: This work was supported by the Spanish MICIIN project AYA2009-10701 with FEDER funds, by Grupos Gobierno Vasco IT-464-07 and by Universidad País Vasco UPV/EHU through program UFI11/55.

Coordinated Isotopic and TEM Studies of Presolar Graphites from Murchison

Science.gov (United States)

Croat, T. K.; Stadermann, F. J.; Zinner, E.; Bernatowicz, T. J.

2004-03-01

TEM and NanoSIMS investigations of the same presolar Murchison KFC graphites revealed high Zr, Mo, and Ru content in refractory carbides within the graphites. Along with isotopically light carbon, these suggest a low-metallicity AGB source.

A Spatio-Temporal Enhancement Method for medium resolution LAI (STEM-LAI), International Journal of Applied Earth Observation and Geoinformation

KAUST Repository

Houborg, Rasmus

2015-12-12

Satellite remote sensing has been used successfully to map leaf area index (LAI) across landscapes, but advances are still needed to exploit multi-scale data streams for producing LAI at both high spatial and temporal resolution. A multi-scale Spatio-Temporal Enhancement Method for medium resolution LAI (STEM-LAI) has been developed to generate 4-day time-series of Landsat-scale LAI from existing medium resolution LAI products. STEM-LAI has been designed to meet the demands of applications requiring frequent and spatially explicit information, such as effectively resolving rapidly evolving vegetation dynamics at sub-field (30 m) scales. In this study, STEM-LAI is applied to Moderate Resolution Imaging Spectroradiometer (MODIS) based LAI data and utilizes a reference-based regression tree approach for producing MODIS-consistent, but Landsat-based, LAI. The Spatial and Temporal Adaptive Reflectance Fusion Model (STARFM) is used to interpolate the downscaled LAI between Landsat acquisition dates, providing a high spatial and temporal resolution improvement over existing LAI products. STARFM predicts high resolution LAI by blending MODIS and Landsat based information from a common acquisition date, with MODIS data from a prediction date. To demonstrate its capacity to reproduce fine-scale spatial features observed in actual Landsat LAI, the STEM-LAI approach is tested over an agricultural region in Nebraska. The implementation of a 250 m resolution LAI product, derived from MODIS 1 km data and using a scale consistent approach based on the Normalized Difference Vegetation Index (NDVI), is found to significantly improve accuracies of spatial pattern prediction, with the coefficient of efficiency (E) ranging from 0.77–0.94 compared to 0.01–0.85 when using 1 km LAI inputs alone. Comparisons against an 11-year record of in-situ measured LAI over maize and soybean highlight the utility of STEM-LAI in reproducing observed LAI dynamics (both characterized by r2 = 0

A TEM method for analyzing local strain fields in irradiated materials

International Nuclear Information System (INIS)

Bennetch, J.I.; Jesser, W.A.

1983-01-01

Of great interest to the field of fracture mechanics is the strain field in front of a crack tip. In irradiated materials, cavities which naturally form as a result of radiation provide convenient internal markers. If a miniaturized irradiated tensile sample is pulled in situ in a transmission electron microscope (TEM), both the relative displacement of these cavities and their distortion in shape provide information on localized strain on a microscopic level. In addition, the TEM method allows direct correlation of active slip systems with crack propagation characteristics. To illustrate this method a strain field map was constructed about a crack propagating in a helium irradiated type 316 stainless steel sample containing large cavities. (orig.)

High-resolution Mapping of Permafrost and Soil Freeze/thaw Dynamics in the Tibetan Plateau Based on Multi-sensor Satellite Observations

Science.gov (United States)

Zhang, W.; Yi, Y.; Yang, K.; Kimball, J. S.

2016-12-01

The Tibetan Plateau (TP) is underlain by the world's largest extent of alpine permafrost ( 2.5×106 km2), dominated by sporadic and discontinuous permafrost with strong sensitivity to climate warming. Detailed permafrost distributions and patterns in most of the TP region are still unknown due to extremely sparse in-situ observations in this region characterized by heterogeneous land cover and large temporal dynamics in surface soil moisture conditions. Therefore, satellite-based temperature and moisture observations are essential for high-resolution mapping of permafrost distribution and soil active layer changes in the TP region. In this study, we quantify the TP regional permafrost distribution at 1-km resolution using a detailed satellite data-driven soil thermal process model (GIPL2). The soil thermal model is calibrated and validated using in-situ soil temperature/moisture observations from the CAMP/Tibet field campaign (9 sites: 0-300 cm soil depth sampling from 1997-2007), a multi-scale soil moisture and temperature monitoring network in the central TP (CTP-SMTMN, 57 sites: 5-40 cm, 2010-2014) and across the whole plateau (China Meteorology Administration, 98 sites: 0-320 cm, 2000-2015). Our preliminary results using the CAMP/Tibet and CTP-SMTMN network observations indicate strong controls of surface thermal and soil moisture conditions on soil freeze/thaw dynamics, which vary greatly with underlying topography, soil texture and vegetation cover. For regional mapping of soil freeze/thaw and permafrost dynamics, we use the most recent soil moisture retrievals from the NASA SMAP (Soil Moisture Active Passive) sensor to account for the effects of temporal soil moisture dynamics on soil thermal heat transfer, with surface thermal conditions defined by MODIS (Moderate Resolution Imaging Spectroradiometer) land surface temperature records. Our study provides the first 1-km map of spatial patterns and recent changes of permafrost conditions in the TP.

High resolution and high voltage electron microscopy at the University of California, Berkeley

International Nuclear Information System (INIS)

Thomas, G.; Westmacott, K.H.

1978-01-01

Recent applications of high-resolution and high-voltage techniques at Berkely are described, using 100-kV TEMs and a standard 650-keV HVEM: grain boundary precipitation in Al--Zn, lattice imaging of grain boundaries in ceramics, steels, phase transitions and magnetic properties of ferrites, lattice defects, precipitation in Al--Si and behavior of interstitial dislocations under electron irradiation, effect of oxide films on loop formation in Al--Mg, and polytypism in magnesium Sialon. 13 refs. 12 figs

Micromechanical and in situ shear testing of Al–SiC nanolaminate composites in a transmission electron microscope (TEM)

Energy Technology Data Exchange (ETDEWEB)

Mayer, C. [Materials Science and Engineering, Arizona State University, Tempe, AZ 85287-6106 (United States); Li, N.; Mara, N. [Center for Integrated Nanotechnologies, Los Alamos National Laboratory, Albuquerque, NM (United States); Chawla, N., E-mail: nchawla@asu.edu [Materials Science and Engineering, Arizona State University, Tempe, AZ 85287-6106 (United States)

2015-01-05

Nanolaminate composites show promise as high strength and toughness materials. However, due to the limited volume of these materials, micron scale mechanical testing methods must be used to determine the properties of these films. To this end, a novel approach combining a double notch shear testing geometry and compression with a flat punch in a nanoindenter was developed to determine the mechanical properties of these films under shear loading. To further elucidate the failure mechanisms under shear loading, in situ TEM experiments were performed using a double notch geometry cut into the TEM foil. Aluminum layer thicknesses of 50 nm and 100 nm were used to show the effect of constraint on the deformation. Higher shear strength was observed in the 50 nm sample (690±54 MPa) compared to the 100 nm sample (423±28.7 MPa). Additionally, failure occurred close to the Al–SiC interface in the 50 nm sample as opposed to failure within the Al layer in the 100 nm sample.

In Vivo Inflammatory Effects of Ceria Nanoparticles on CD-1 Mouse: Evaluation by Hematological, Histological, and TEM Analysis

Directory of Open Access Journals (Sweden)

Anna Poma

2014-01-01

Full Text Available The attention on CeO2-NPs environmental and in vivo effects is due to their presence in diesel exhaust and in diesel filters that release a more water-soluble form of ceria NPs, as well as to their use for medical applications. In this work, acute and subacute in vivo toxicity assays demonstrate no lethal effect of these NPs. Anyhow, performing in vivo evaluations on CD-1 mouse systems, we demonstrate that it is even not correct to assert that ceria NPs are harmless for living systems as they can induce status of inflammation, revealed by hematological-chemical-clinical assays as well as histological and TEM microscope observations. TEM analysis showed the presence of NPs in alveolar macrophages. Histological evaluation demonstrated the NPs presence in lungs tissues and this can be explained by assuming their ability to go into the blood stream and lately into the organs (generating inflammation.

Application effect of TEM sounding survey on prospecting and target area selection of sandstone-type uranium deposits

International Nuclear Information System (INIS)

He Jianguo; Liang Shanming; Zhao Cuiping

2006-01-01

Based on the results of transient electromagnetic (TEM) sounding survey during recent years regional geological reconnaissance with drilling (1:250000), the application effect of TEM sounding survey during regional reconnaissance is summarized in this paper. It is suggested that the data of TEM sounding are useful in judging hydrodynamic conditions of groundwater and determining favorable areas for uranium ore-formation; TEM sounding in large areas may be proper for prospecting in gobi-desert areas and be beneficial for regional reconnaissance and target area selection, and may reduce the target area and provide basis for further drilling program. It is of popularized significance in the prospecting for sandstone-type uranium deposits. (authors)

New perspectives on Natal Pulses from satellite observations

CSIR Research Space (South Africa)

Rouault, MJ

2011-07-01

Full Text Available that on their journey from the Natal Bight to Port Elizabeth, Natal Pulses systematically interact with the coastal topography to generate upstream perturbations. These upstream offshore meanders occur when the trailing edge of the original Natal Figure 2. SST daily... SST which have a relatively low tem- poral resolution (daily) can also prove difficult due to the extensive and persistent cloud coverage above the Agulhas Current [Rouault et al., 2000]. [5] High�frequency data acquisitions from the geostation...

ANALISIS JARINGAN UMTS PADA MENARA ROOFTOP DENGAN MENGGUNAKAN SOFTWARE TEMS INVESTIGATION DAN G-NETTRACK PRO

Directory of Open Access Journals (Sweden)

Pande Putu Wahyu Pramanda

2016-03-01

Full Text Available Berkembangnya dunia teknologi telekomunikasi dan informasi sejalan dengan kebutuhan akan kecepatan dan kestabilan akses internet teknologi UMTS. Metode drive test adalah metode yang biasanya digunakan untuk pengukuran kualitas sebuah site. Pihak provider umumnya menggunakan software TEMS Investigation dalam melakukan drive test. Melakukan drive test dengan TEMS Investigation sangatlah tidak praktis dan memerlukan biaya yang besar. Berkembangnya teknologi smartphone membuat drive test dapat dilakukan dengan menggunakan handphone yaitu dengan G-NetTrack Pro. Namun G-NetTrack Pro tidak memiliki kemampuan yang sama dengan TEMS Investigation. Software G-NetTrack Pro dapat digunakan sebagai bahan pembelajaran yaitu untuk pengenalan drivetest namun belum cocok digunakan secara profesional. G-NetTrack Pro dapat menampilkan data yang dibutuhkan dalam drive test namun tidak sedetail TEMS Investigation, sehingga dalam proses pembelajaran dapat digunakan untuk pengenalan karena efisien dan dapat di install pada handphone mahasiswa namun tidak dapat digunakan melakukan drive test misalnya dalam dunia kerja atau secara professional.

In situ high-resolution transmission electron microscopy synthesis observation of nanostructured carbon coated LiFePO 4

Science.gov (United States)

Trudeau, M. L.; Laul, D.; Veillette, R.; Serventi, A. M.; Mauger, A.; Julien, C. M.; Zaghib, K.

In situ high-resolution transmission electron microscopy (HRTEM) studies of the structural transformations that occur during the synthesis of carbon-coated LiFePO 4 (C-LiFePO 4) and heat treatment to elevated temperatures were conducted in two different electron microscopes. Both microscopes have sample holders that are capable of heating up to 1500 °C, with one working under high vacuum and the other capable of operating with the sample surrounded by a low gaseous environment. The C-LiFePO 4 samples were prepared using three different compositions of precursor materials with Fe(0), Fe(II) or Fe(III), a Li-containing salt and a polyethylene- block-poly(ethylene glycol)-50% ethylene oxide or lactose. The in situ TEM studies suggest that low-cost Fe(0) and a low-cost carbon-containing compound such as lactose are very attractive precursors for mass production of C-LiFePO 4, and that 700 °C is the optimum synthesis temperature. At temperatures higher than 800 °C, LiFePO 4 has a tendency to decompose. The same in situ measurements have been made on particles without carbon coat. The results show that the homogeneous deposit of the carbon deposit at 700 °C is the result of the annealing that cures the disorder of the surface layer of bare LiFePO 4. Electrochemical tests supported the conclusion that the C-LiFePO 4 derived from Fe(0) is the most attractive for mass production.

Helicopter TEM parameters analysis and system optimization based on time constant

Science.gov (United States)

Xiao, Pan; Wu, Xin; Shi, Zongyang; Li, Jutao; Liu, Lihua; Fang, Guangyou

2018-03-01

Helicopter transient electromagnetic (TEM) method is a kind of common geophysical prospecting method, widely used in mineral detection, underground water exploration and environment investigation. In order to develop an efficient helicopter TEM system, it is necessary to analyze and optimize the system parameters. In this paper, a simple and quantitative method is proposed to analyze the system parameters, such as waveform, power, base frequency, measured field and sampling time. A wire loop model is used to define a comprehensive 'time constant domain' that shows a range of time constant, analogous to a range of conductance, after which the characteristics of the system parameters in this domain is obtained. It is found that the distortion caused by the transmitting base frequency is less than 5% when the ratio of the transmitting period to the target time constant is greater than 6. When the sampling time window is less than the target time constant, the distortion caused by the sampling time window is less than 5%. According to this method, a helicopter TEM system, called CASHTEM, is designed, and flight test has been carried out in the known mining area. The test results show that the system has good detection performance, verifying the effectiveness of the method.

High-resolution Observations of Downflows at One End of a Pre-eruption Filament

Energy Technology Data Exchange (ETDEWEB)

Li, Qin; Deng, Na; Jing, Ju; Wang, Haimin, E-mail: ql47@njit.edu [Space Weather Research Laboratory, New Jersey Institute of Technology, University Heights, Newark, NJ 07102-1982 (United States)

2017-06-01

Studying the dynamics of filaments at the pre-eruption phase can shed light on the precursor of eruptive events. Such high-resolution studies (of the order of 0.″1) are highly desirable yet very rare. In this work, we present a detailed observation of a pre-eruption evolution of a filament obtained by the 1.6 m New Solar Telescope (NST) at the Big Bear Solar Observatory (BBSO). One end of the filament is anchored at the sunspot in the NOAA active region (AR) 11515, which is well observed by NST H α off-bands from four hours before to one hour after the filament eruption. A M1.6 flare is associated with the eruption. We observed persistent downflowing materials along the H α multi-threaded component of the loop toward the AR end during the pre-eruption phase. We traced the trajectories of plasma blobs along the H α threads and obtained a plane-of-sky velocity of 45 km s{sup −1} on average. Furthermore, we estimated the real velocities of the downflows and the altitude of the filament by matching the observed H α threads with magnetic field lines extrapolated from a nonlinear force-free field model. Observations of chromospheric brightenings at the footpoints of the falling plasma blobs are also presented. The lower limit of the kinetic energy per second of the downflows through the brightenings is found to be ∼10{sup 21} erg. Larger FOV observations from BBSO full-disk H α images show that the AR end of the filament started ascending four hours before the flare. We attribute the observed downflows at the AR end of the filament to the draining effect of the filament rising prior to its eruption. During the slow-rise phase, the downflows continuously drained away ∼10{sup 15}g mass from the filament over a few hours, which is believed to be essential for the instability, and could be an important precursor of eruptive events.

Non Invasive 3D Characterization of Materials at Multi scale Resolution in Correlative and 4D microscopy

International Nuclear Information System (INIS)

Lau, S.H.

2011-01-01

We describe a suite of novel lab-based X-ray computed tomography (CT) systems for high contrast 3D characterization of hard to soft materials with resolution across length scales. The system has similar resolution and contrast range obtained from x-ray micro and nano tomography systems in synchrotron radiation facilities, except it makes use of conventional lab sources. Samples with dimensions from several cm to several microns may be imaged non invasively at varying resolution from tens of microns to 20 nm voxel. The novel multi scale CT helps bridge the resolution, scaling and 3D visualization gap in the traditional destructive 2D imaging modalities such as optical microscopes, AFM, SEM, SEM-FIB and TEM. It provides a direct non-invasive volumetric imaging technique at the macro to nano scale, making it ideal for accurate prediction and modeling of whole systems and components. For example, using 3D visualization, segmentation and computational analysis tools, pore networks, FEA, fluid, thermal and ionic transport in various systems and materials from ceramics, geo materials, composites, metals, and coatings may be characterized and modeled. The high resolution and unique phase contrast features of the novel CTs also lend themselves very well to characterize inherently low contrast soft materials such as polymers; membranes and biological tissue or to differentiate small differences in material and mineral phases in geo material and composites. Tomography of samples may be acquired at different volume vs resolution using local tomography technique, often without sample destruction. In the emerging field of 3D correlative microscopy, these larger CT volumetric data sets can be correlated at the different length scales with conventional 2D imaging modalities. For example, after a CT scan, specimen may undergo destructive sample sectioning at specific region of interest, to obtain the corresponding 2D slices with SEM and TEM or with X-ray microanalysis derive its

TEMs but not DKK1 could serve as complementary biomarkers for AFP in diagnosing AFP-negative hepatocellular carcinoma.

Science.gov (United States)

Mao, Liping; Wang, Yueguo; Wang, Delin; Han, Gang; Fu, Shouzhong; Wang, Jianxin

2017-01-01

Hepatitis B virus (HBV)-related hepatocellular carcinoma (HCC) is prevalent worldwide. Despite its limitations, serum alpha-fetoprotein (AFP) remains the most widely-used biomarker for the diagnosis of HCC. This study aimed to assess whether measurement of peripheral plasma Dickkopf-1 (DKK1) and Tie2-expressing monocytes (TEMs) could overcome the limitations of AFP and improve the diagnostic accuracy of HCC. Plasma DKK1 level and the percentage of TEMs in peripheral CD14+CD16+ monocytes from HCC patients (n = 82), HBV-related liver cirrhosis (LC) patients (n = 29), chronic hepatitis B (CHB) infected patients (n = 28) and healthy volunteers (n = 31) were analyzed by ELISA and flow cytometry. Receiver operating characteristic (ROC) curves were used to analyze a single biomarker, or a combination of two or three biomarkers. Univariate and multivariate analyses were performed to assess the significance of each marker in prediction of HCC and AFP-negative HCC from LC patients. The percentage of TEMs in peripheral CD14+CD16+ monocytes and plasma level of DKK1 in HCC group were significantly higher than those in LC, CHB and healthy control groups (all P-values TEMs alone was also significantly higher in AFP-negative HCC group than that in LC, CHB and healthy control groups (all P-values TEMs. There was no significant difference in AUC of DKK1, TEMs and AFP in HCC diagnosis between the four groups (all P>0.05). A combination of DKK1, TEMs and AFP measurements increased the AUC for HCC diagnosis as compared with either marker alone (0.833; 95%CI 0.768-0.886). The AUC for TEMs was 0.692 (95% CI 0.564-0.819) in differentiating AFP-negative HCC from LC, with a sensitivity of 80.0% and a specificity of 65.52%. Only TEMs prevailed as a significant predictor for AFP-negative HCC differentiating from LC patients in univariate and multivariate analyses (P = 0.016, P = 0.023). TEMs and DKK1 may prove to be potential complementary biomarkers for AFP in the diagnosis of HCC. TEMs

Analysis of arsenic speciation in mine contaminated lacustrine sediment using selective sequential extraction, HR-ICPMS and TEM

Energy Technology Data Exchange (ETDEWEB)

Haus, Kelly L. [Department of Geology, Phillips 157, University of Wisconsin - Eau Claire, Eau Claire, WI 54702-4004 (United States)], E-mail: khaus@vt.edu; Hooper, Robert L.; Strumness, Laura A.; Mahoney, J. Brian [Department of Geology, Phillips 157, University of Wisconsin - Eau Claire, Eau Claire, WI 54702-4004 (United States)

2008-04-15

In order to determine how As speciation in lacustrine sediment changes as a function of local conditions, sediment cores were taken from three lakes with differing hydrologic regimes and subjected to extensive chemical and TEM analysis. The lakes (Killarney, Thompson and Swan Lakes) are located within the Coeur d' Alene River system (northern Idaho, USA), which has been contaminated with trace metals and As, from over 100 a of sulfide mining. Previous analyses of these lakebed sediments have shown an extensive amount of contaminant metals and As associated with sub-{mu}m grains, making them extremely difficult to analyze using standard methods (scanning electron microscopy, X-ray diffraction). Transmission electron microscopy offers great advantages in spatial resolution and can be invaluable in determining As speciation when combined with other techniques. Data indicate that because of differences in local redox conditions, As speciation and stability is dramatically different in these lakes. Killarney and Thompson Lakes experience seasonal water-level fluctuations due to drawdown on a downstream dam, causing changes in O{sub 2} content in sediment exposed during drawdown. Swan Lake has relatively constant water levels as its only inlet is dammed. Consequently, Killarney and Thompson Lakes show an increase in labile As-bearing phases with depth, while Swan Lake data indicate stable As hosts throughout the sediment profile. Based on these observations it can be stated that As in lakebed sediments is much less mobile, and therefore less bioavailable, when water is kept at a constant level.

Novel carbon nanosheets as support for ultrahigh-resolution structural analysis of nanoparticles

International Nuclear Information System (INIS)

Nottbohm, Christoph T.; Beyer, Andre; Sologubenko, Alla S.; Ennen, Inga; Huetten, Andreas; Roesner, Harald; Eck, Wolfgang; Mayer, Joachim; Goelzhaeuser, Armin

2008-01-01

The resolution in transmission electron microscopy (TEM) has reached values as low as 0.08 nm. However, these values are not accessible for very small objects in the size range of a few nanometers or lower, as they have to be placed on some support, which contributes to the overall electron-scattering signal, thereby blurring the contrast. Here, we report on the use of nanosheets made from cross-linked aromatic self-assembled monolayers as TEM sample supports. When transferred onto a copper grid, a single 1.6-nm-thick nanosheet can cover the grid and is free standing within the micron-sized openings. Despite its thinness, the sheet is stable under the impact of the electron beam. Micrographs taken from nanoclusters onto these nanosheets show highly increased contrast in comparison to the images taken from amorphous carbon supports. In scanning transmission electron microscopy with nanosheet support, a size analysis of sub-nanometer Au clusters was performed and single Au atoms were resolved

2.5D Modeling of TEM Data Applied to Hidrogeological Studies in PARANÁ Basin, Brazil

Science.gov (United States)

Bortolozo, C. A.; Porsani, J. L.; Santos, F. M.

2013-12-01

The transient electromagnetic method (TEM) is used all over the world and has shown great potential in hydrological, hazardous waste site characterization, mineral exploration, general geological mapping, and geophysical reconnaissance. However, the behavior of TEM fields are very complex and is not yet fully understood. Forward modeling is one of the most common and effective methods to understand the physical behavior and significance of the electromagnetics responses of a TEM sounding. Until now, there are a limited number of solutions for the 2D forward problem for TEM. More rare are the descriptions of a three-component response of a 3D source over 2D earth, which is the so-called 2.5D. The 2.5D approach is more realistic than the conventional 2D source previous used, once normally the source cannot be realistic represented for a 2D approximation (normally source are square loops). At present the 2.5D model represents the only way of interpreting TEM data in terms of a complex earth, due to the prohibitive amount of computer time and storage required for a full 3D model. In this work we developed a TEM modeling program for understanding the different responses and how the magnetic and electric fields, produced by loop sources at air-earth interface, behave in different geoelectrical distributions. The models used in the examples are proposed focusing hydrogeological studies, once the main objective of this work is for detecting different kinds of aquifers in Paraná sedimentary basin, in São Paulo State - Brazil. The program was developed in MATLAB, a widespread language very common in the scientific community.

Crosstalk between TEMs and endothelial cells modulates angiogenesis and metastasis via IGF1-IGF1R signalling in epithelial ovarian cancer.

Science.gov (United States)

Wang, Xinjing; Zhu, Qinyi; Lin, Yingying; Wu, Li; Wu, Xiaoli; Wang, Kai; He, Qizhi; Xu, Congjian; Wan, Xiaoping; Wang, Xipeng

2017-10-24

Epithelial ovarian cancer (EOC) is the leading cause of death from gynaecologic malignancies and has a poor prognosis due to metastasis. Drugs targeting the angiogenesis pathway significantly improve patient outcome. However, the key factors linking angiogenesis and metastasis have not been elucidated. In this study, we found Tie2 expressing monocytes (CD14 + Tie2 + , TEMs) as key contributors to angiogenesis and metastasis of EOC. Tissue slides were evaluated by immunofluorescence for the presence of total tissue macrophages and TEMs. The correlation between microvascular density (MVD) values and the TEMs number or ratio was calculated in both ovarian cancer tissues and peritoneum. The rate of TEMs in monocytes was evaluated in the peripheral blood of female healthy donors, benign cysts patients, and EOC patients using flow cytometry. The TEMs rate in ascites from EOC patients was also evaluated by flow cytometry. The concentration of Ang2, as the ligand of Tie2, was examined by ELISA in serum samples of EOC patients, benign cysts patients, and ascites samples of EOC patients. The effects of Ang2 on the migration and the cytokine expression of TEMs were further examined. The pro- angiogenesis activity of TEMs via IGF1 was performed in both in vivo and in vitro. And the IGF1 blocking test was performed using neutralising antibody. TEMs were significantly higher in tumour foci, peripheral blood and ascites in EOC patients. The proportion of TEMs among total tissue macrophages was positively correlated with tumour MVD. In vivo animal results showed that TEMs promoted EOC angiogenesis and metastasis. Further functional and mechanisms studies revealed that concentration of angiopoietin 2 (Ang2), a ligand of Tie2, was elevated in EOC ascites which further recruit TEMs in a dose-dependent manner as a powerful chemokine to TEMs. Recruited TEMs promoted endothelial cell function through IGF1-activated downstream signalling. Blocking secreted IGF1 using inhibiting antibody

Multi-scale characterization by FIB-SEM/TEM/3DAP.

Science.gov (United States)

Ohkubo, T; Sepehri-Amin, H; Sasaki, T T; Hono, K

2014-11-01

In order to improve properties of functional materials, it is important to understand the relation between the structure and the properties since the structure has large effect to the properties. This can be done by using multi-scale microstructure analysis from macro-scale to nano and atomic scale. Scanning electron microscope (SEM) equipped with focused ion beam (FIB), transmission electron microscope (TEM) and 3D atom probe (3DAP) are complementary analysis tools making it possible to know the structure and the chemistry from micron to atomic resolution. SEM gives us overall microstructural and chemical information by various kinds of detectors such as secondary electron, backscattered electron, EDS and EBSD detectors. Also, it is possible to analyze 3D structure and chemistry via FIB serial sectioning. In addition, using TEM we can focus on desired region to get more complementary information from HRTEM/STEM/Lorentz images, SAED/NBD patterns and EDS/EELS to see the detail micro or nano-structure and chemistry. Especially, combination of probe Cs corrector and split EDS detectors with large detector size enable us to analyze the atomic scale elemental distribution. Furthermore, if the specimen has a complicated 3D nanostructure, or we need to analyze light elements such as hydrogen, lithium or boron, 3DAP can be used as the only technique which can visualize and analyze distribution of all constituent atoms of our materials within a few hundreds nm area. Hence, site-specific sample preparation using FIB/SEM is necessary to get desired information from region of interest. Therefore, this complementary analysis combination works very well to understand the detail of materials.In this presentation, we will show the analysis results obtained from some of functional materials by Carl Zeiss CrossBeam 1540EsB FIB/SEM, FEI Tecnai G(2) F30, Titan G2 80-200 TEMs and locally build laser assisted 3DAP. As the one of the example, result of multi-scale characterization for

Investigation of InN layers grown by MOCVD using analytical and high resolution TEM: The structure, band gap, role of the buffer layers

International Nuclear Information System (INIS)

Ruterana, P.; Abouzaid, M.; Gloux, F.; Maciej, W.; Doualan, J.L.; Drago, M.; Schmidtling, T.; Pohl, U.W.; Richter, W.

2006-01-01

In this work we investigate the microstructure of InN layers grown by MOCVD on different buffer layers using TEM (InN, GaN). The large mismatch between the various lattices (InN, sapphire or GaN) leads to particular interface structures. Our local analysis allows to show that at atomic scale, the material has the InN lattice parameters and that no metallic In precipitates are present, meaning that the PL emission below 0.8 eV is a genuine property of the InN semiconductor. It is also shown that the N polar layers, which exhibit a 2D growth, have poorer PL emission than In polar layers. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Super-resolution biomolecular crystallography with low-resolution data.

Science.gov (United States)

Schröder, Gunnar F; Levitt, Michael; Brunger, Axel T

2010-04-22

X-ray diffraction plays a pivotal role in the understanding of biological systems by revealing atomic structures of proteins, nucleic acids and their complexes, with much recent interest in very large assemblies like the ribosome. As crystals of such large assemblies often diffract weakly (resolution worse than 4 A), we need methods that work at such low resolution. In macromolecular assemblies, some of the components may be known at high resolution, whereas others are unknown: current refinement methods fail as they require a high-resolution starting structure for the entire complex. Determining the structure of such complexes, which are often of key biological importance, should be possible in principle as the number of independent diffraction intensities at a resolution better than 5 A generally exceeds the number of degrees of freedom. Here we introduce a method that adds specific information from known homologous structures but allows global and local deformations of these homology models. Our approach uses the observation that local protein structure tends to be conserved as sequence and function evolve. Cross-validation with R(free) (the free R-factor) determines the optimum deformation and influence of the homology model. For test cases at 3.5-5 A resolution with known structures at high resolution, our method gives significant improvements over conventional refinement in the model as monitored by coordinate accuracy, the definition of secondary structure and the quality of electron density maps. For re-refinements of a representative set of 19 low-resolution crystal structures from the Protein Data Bank, we find similar improvements. Thus, a structure derived from low-resolution diffraction data can have quality similar to a high-resolution structure. Our method is applicable to the study of weakly diffracting crystals using X-ray micro-diffraction as well as data from new X-ray light sources. Use of homology information is not restricted to X

Use of the TEM Cell for Compliance Testing of Emissions and Immunity, an IEC Perspective

DEFF Research Database (Denmark)

Bentz, Sigurd

1996-01-01

The current work of the IEC on preparing a standard for the use of TEM cells for compliance testing of emissions and immunity is reviewed. The requirements of TEM cells are related to the established procedures: “open area test site” and “shielded enclosure with area of uniform field”, respective...

Analytical TEM investigations of nanoscale magnetic materials

International Nuclear Information System (INIS)

Meingast, A.

2015-01-01

Analytical transmission electron microscopy has been applied within this thesis to investigate several novel approaches to design and fabricate nanoscale magnetic materials. As the size of the features of interest rank in the sub-nanometer range, it is necessary to employ techniques with a resolution – both spatial and analytical – well below this magnitude. Only at this performance level it is possible to examine material properties, necessary for the further tailoring of materials. Within this work two key aspects have been covered: First, analytical TEM (transmission electron microscopy) investigations were carried out to get insight into novel magnetic materials with high detail. Second, new analytical and imaging possibilities enabled with the commissioning of the new ASTEM (Austrian scanning transmission electron microscope) were explored. The aberration corrected TITAN® microscope (© FEI Company) allows resolving features in scanning transmission mode (STEM) with 70 pm distance. Thereby, direct imaging of light elements in STEM mode by using the annular bright field method becomes possible. Facilitated through high beam currents within the electron probe, an increased acquisition speed of analytical signals is possible. For energy dispersive X-ray spectroscopy (EDXS) a new four detector disc geometry around the specimen was implemented, which increases the accessible collection angle. With the integration of the latest generation of image filter and electron spectrometer (GIF QuantumERS), electron energy loss spectroscopy (EELS) is boosted through the high acquisition speed and the dual spectroscopy mode. The high acquisition speed allows to record up to 1000 spectra per second and the possibility to record atomically resolved EELS maps is at hand. Hereby it is important to avoid beam damage and alteration of the material during imaging and analysis. With the simultaneous acquisition of the low and the high loss spectral region, an extended range for

High Resolution Mapping of Drought Impacts on Small Waterbodies using Sentinel 1 SAR and Landsat Observations

Science.gov (United States)

Slinski, K.; Hogue, T. S.; McCray, J. E.

2017-12-01

Drought in semi-arid areas can have substantial impact on ephemeral and small water bodies, which provide critical ecological habitat and have important socio-economic value. This is particularly true in the pastoral areas of East Africa, where these ecosystems provide local communities with water for human and animal consumption and pasture for livestock. However, monitoring the impact of drought on ephemeral and small water bodies in East Africa is challenging because of sparse in situ observational systems. Satellite remote sensing observations have been shown to be a viable option for monitoring surface water change in data-poor regions. Landsat data is widely used to detect open water, but the use of Landsat data in small waterbody studies is limited by its 30-meter spatial resolution. New remote sensing-based tools are necessary to better understand the vulnerability of ephemeral and small waterbodies in semi-arid areas to drought and to monitor drought impacts. This study combines Landsat and Sentinel 1 SAR observations to create a series of monthly waterbody maps over the Awash River basin in Ethiopia depicting the change in surface water from October 2014 to March 2017. The study time period corresponds with a major drought event in the area. Waterbody maps were generated using a 10-meter resolution and utilized to monitor drought impacts on ephemeral and small waterbodies in the Awash River basin over the course of the drought event. Initial results show that surface waterbodies in the lower catchments of the Awash basin were more severely impacted by the drought event than the upper catchments. It is anticipated that the new information provided by this tool will inform decisions affecting the water, energy, agriculture and other sectors in East Africa reliant on water resources, enabling water authorities to better manage future drought events.

TEM studies of P+ implanted and subsequently laser annealed Si

International Nuclear Information System (INIS)

Sadana, D.K.; Wilson, M.C.; Booker, G.R.; Washburn, J.

1979-05-01

The present investigation is concerned with laser annealing of P + implanted Si. The aim of the work was to study the crystallization behavior of damage structure occurring due to high dose rate implantation using transmission electron microscopy (TEM) as the method of examination

Recombination-related properties of a-screw dislocations in GaN: A combined CL, EBIC, TEM study

Energy Technology Data Exchange (ETDEWEB)

Medvedev, O. S., E-mail: o.s.medvedev@spbu.ru; Mikhailovskii, V. Yu. [V.A. Fok Institute of Physics, St. Petersburg State University (Russian Federation); IRC for Nanotechnology, Research Park, St.-Petersburg State University (Russian Federation); Vyvenko, O. F.; Bondarenko, A. S.; Ubyivovk, E. V. [V.A. Fok Institute of Physics, St. Petersburg State University (Russian Federation); Peretzki, P.; Seibt, M. [IV. Physikalisches Institut Georg-August Universität Göttingen (Germany)

2016-06-17

Cathodoluminescence (CL), electron beam current (EBIC) and transmission electron microscopy (TEM) techniques have been applied to investigate recombination properties and structure of freshly introduced dislocations in low-ohmic GaN crystals. It was confirmed that the only a-screw dislocations exhibited an intense characteristic dislocation-related luminescence (DRL) which persisted up to room temperature and was red-shifted by about 0.3 eV with respect to the band gap energy not only in HVPE but also in MOCVD grown samples. EBIC contrast of the dislocations was found to be temperature independent indicating that the dislocation-related recombination level is situated below 200 meV with respect of conduction band minimum. With the increasing of the magnification of the dislocation TEM cross-sectional images they were found to disappear, probably, due to the recombination enhanced dislocation glide (REDG) under electron beam exposure which was immediately observed in CL investigations on a large scale. The stacking fault ribbon in the core of dissociated a-screw dislocation which form a quantum well for electrons was proposed to play an important role both in DRL spectrum formation and in REDG.

High-Resolution Spectroscopic Observations of Potassium Emissions in the Lunar Exosphere

Science.gov (United States)

Robertson, Sarena D.; Oliversen, Ronald J.; Mierkiewicz, Edwin J.; Kuruppuaratchi, Dona Chathuni P.; Derr, Nicholas James; Gallant, Margaret A.; McFarland, Christina G.; Sarantos, Menelaos

2018-01-01

We investigate lunar exospheric potassium D1 emissions (7698.9646 Å) using high-resolution (R = 180,000 or 1.7 km/s) spectroscopy with our dual-etalon Fabry-Perot instrument to measure line widths and radial velocities. The Field of View (FOV) is 2 arcmins (~224 km at the mean lunar distance of 384,400 km) positioned tangent to the sunlit limb. The FOV placements are at cardinal directions from a variety of reference craters. All observations are collected at the National Solar Observatory McMath-Pierce Telescope in Kitt Peak, Arizona. The data are from several observations from 2014 through 2017 at various times of the year. Results are produced via a newly created automated data reduction using Python. Python was chosen as an open-source alternative to the previously used IDL and MATLAB scripts to decrease the cost of software licenses and maintenance. The potassium spectral line profiles provide a direct method to track exospheric effective temperatures and velocities. By monitoring the state of the potassium emissions over different lunar phases, solar activity, and the influx of meteor streams, we can constrain physical processes of sources and sinks at the lunar surface. Mechanisms that create the exosphere include photon-stimulated desorption, thermal evaporation, meteoroid impact vaporization, and ion sputtering via solar wind. In contrast, the exosphere is diminished due to the low lunar escape velocity, solar radiation pressure, and neutral gas being ionized and swept away by the interplanetary and terrestrial magnetic field. Preliminary analysis of 2017 data (January through June, excluding February) indicates an average potassium temperature of 1140 K but varying over the range of 550 K to 2000 K. Preliminary results from 2014 data depict a similar range of temperatures to that of 2017. Further analysis is expected for additional data from 2014 to later observations in 2017 that were not included in the initial set of models.

Merging Radar Quantitative Precipitation Estimates (QPEs) from the High-resolution NEXRAD Reanalysis over CONUS with Rain-gauge Observations

Science.gov (United States)

Prat, O. P.; Nelson, B. R.; Stevens, S. E.; Nickl, E.; Seo, D. J.; Kim, B.; Zhang, J.; Qi, Y.

2015-12-01

The processing of radar-only precipitation via the reanalysis from the National Mosaic and Multi-Sensor Quantitative (NMQ/Q2) based on the WSR-88D Next-generation Radar (Nexrad) network over the Continental United States (CONUS) is completed for the period covering from 2002 to 2011. While this constitutes a unique opportunity to study precipitation processes at higher resolution than conventionally possible (1-km, 5-min), the long-term radar-only product needs to be merged with in-situ information in order to be suitable for hydrological, meteorological and climatological applications. The radar-gauge merging is performed by using rain gauge information at daily (Global Historical Climatology Network-Daily: GHCN-D), hourly (Hydrometeorological Automated Data System: HADS), and 5-min (Automated Surface Observing Systems: ASOS; Climate Reference Network: CRN) resolution. The challenges related to incorporating differing resolution and quality networks to generate long-term large-scale gridded estimates of precipitation are enormous. In that perspective, we are implementing techniques for merging the rain gauge datasets and the radar-only estimates such as Inverse Distance Weighting (IDW), Simple Kriging (SK), Ordinary Kriging (OK), and Conditional Bias-Penalized Kriging (CBPK). An evaluation of the different radar-gauge merging techniques is presented and we provide an estimate of uncertainty for the gridded estimates. In addition, comparisons with a suite of lower resolution QPEs derived from ground based radar measurements (Stage IV) are provided in order to give a detailed picture of the improvements and remaining challenges.

Microscopic studies on Y2Ba4Cu7O15-δ by use of TEM and NQR techniques

International Nuclear Information System (INIS)

Kato, Masaki; Nakanishi, Makoto; Yoshimura, Kazuyoshi; Kosuge, Koji; Miyano, Toshio; Kakihana, Masato

1998-01-01

Y 2 Ba 4 Cu 7 O 15-δ compounds were characterized by microscopic investigation using TEM and NQR techniques. The authors synthesized Y247 compounds by two kinds of preparation methods: the conventional solid-state reaction (sample A) and the polymerized-complex method (sample B). The value of T c for sample A was found o be 65 K and that for sample B as 93 K by ac-χ measurements. As a result of TEM experiments, stacking faults along the c axis were observed more frequently in sample B than in sample A. These stacking faults resulted in microdomains containing pure Y123 or Y124 thin blocks of several unit cells. NQR experiments revealed that the microscopic environment of Cu(2) sites in sample A differed from either of those in the Y123 and Y124 compounds. NQR frequency values (ν Q ) of Cu(2) sites agreed well with those calculated by the point charge model applied for the Y247 structure. The spectra of Cu(2) sites in sample B could be regarded, however, as a combination of those of pure Y123, Y124, and also Y247 compounds. This fact was coincident with the result of TEM experiments. The authors concluded that the superconductivity of Y247 with higher T c originates from the thin block of Y123

High-resolution sensing for precision agriculture: from Earth-observing satellites to unmanned aerial vehicles

Science.gov (United States)

McCabe, Matthew F.; Houborg, Rasmus; Lucieer, Arko

2016-10-01

With global population projected to approach 9 billion by 2050, it has been estimated that a 40% increase in cereal production will be required to satisfy the worlds growing nutritional demands. Any such increases in agricultural productivity are likely to occur within a system that has limited room for growth and in a world with a climate that is different from that of today. Fundamental to achieving food and water security, is the capacity to monitor the health and condition of agricultural systems. While space-agency based satellites have provided the backbone for earth observation over the last few decades, many developments in the field of high-resolution earth observation have been advanced by the commercial sector. These advances relate not just to technological developments in the use of unmanned aerial vehicles (UAVs), but also the advent of nano-satellite constellations that offer a radical shift in the way earth observations are now being retrieved. Such technologies present opportunities for improving our description of the water, energy and carbon cycles. Efforts towards developing new observational techniques and interpretative frameworks are required to provide the tools and information needed to improve the management and security of agricultural and related sectors. These developments are one of the surest ways to better manage, protect and preserve national food and water resources. Here we review the capabilities of recently deployed satellite systems and UAVs and examine their potential for application in precision agriculture.

High-resolution sensing for precision agriculture: from Earth-observing satellites to unmanned aerial vehicles

KAUST Repository

McCabe, Matthew

2016-10-25

With global population projected to approach 9 billion by 2050, it has been estimated that a 40% increase in cereal production will be required to satisfy the worlds growing nutritional demands. Any such increases in agricultural productivity are likely to occur within a system that has limited room for growth and in a world with a climate that is different from that of today. Fundamental to achieving food and water security, is the capacity to monitor the health and condition of agricultural systems. While space-Agency based satellites have provided the backbone for earth observation over the last few decades, many developments in the field of high-resolution earth observation have been advanced by the commercial sector. These advances relate not just to technological developments in the use of unmanned aerial vehicles (UAVs), but also the advent of nano-satellite constellations that offer a radical shift in the way earth observations are now being retrieved. Such technologies present opportunities for improving our description of the water, energy and carbon cycles. Efforts towards developing new observational techniques and interpretative frameworks are required to provide the tools and information needed to improve the management and security of agricultural and related sectors. These developments are one of the surest ways to better manage, protect and preserve national food and water resources. Here we review the capabilities of recently deployed satellite systems and UAVs and examine their potential for application in precision agriculture.

Novel Transrotational Solid State Order Discovered by TEM in Crystallizing Amorphous Films

Science.gov (United States)

Kolosov, Vladimir

Exotic thin crystals with unexpected transrotational microstructures have been discovered by transmission electron microscopy (TEM) for crystal growth in thin (10-100 nm) amorphous films of different chemical nature (oxides, chalcogenides, metals and alloys) prepared by various methods. Primarily we use our TEM bend contour technique. The unusual phenomenon can be traced in situ in TEM column: dislocation independent regular internal bending of crystal lattice planes in a growing crystal. Such transrotation (unit cell trans lation is complicated by small rotationrealized round an axis lying in the film plane) can result in strong regular lattice orientation gradients (up to 300 degrees per micrometer) of different geometries: cylindrical, ellipsoidal, toroidal, saddle, etc. Transrotation is increasing as the film gets thinner. Transrotational crystal resembles ideal single crystal enclosed in a curved space. Transrotational micro crystals have been eventually recognized by other authors in some vital thin film materials, i.e. PCMs for memory, silicides, SrTiO3. Atomic model and possible mechanisms of the phenomenon are discussed. New transrotational nanocrystalline model of amorphous state is also proposed Support of RF Ministry of Education and Science is acknowledged.

In-situ TEM imaging of the anisotropic etching of graphene by metal nanoparticles.

Science.gov (United States)

Wei, Jiake; Xu, Zhi; Wang, Hao; Tian, Xuezeng; Yang, Shize; Wang, Lifen; Wang, Wenlong; Bai, Xuedong

2014-11-21

Few-layer graphene was successfully tailored with smooth edges along crystallographic directions by Joule heating-driven tungsten nanoparticles inside a transmission electron microscope. The dynamic process was monitored in real time at the atomic resolution level. These high-resolution in-situ observations show that the neighboring graphene layers joined together to form closed edges, which is in contrast to the supposed open edges formed with hydrogen passivation. The tungsten nanoparticles transformed to W₂C in the intermediate stage of etching and to WC after etching, suggesting that carbon dissolution helped the continuous action of the metal nanoparticles in the catalytic anisotropic etching reaction.

Scalable pumping approach for extracting the maximum TEM(00) solar laser power.

Science.gov (United States)

Liang, Dawei; Almeida, Joana; Vistas, Cláudia R

2014-10-20

A scalable TEM(00) solar laser pumping approach is composed of four pairs of first-stage Fresnel lens-folding mirror collectors, four fused-silica secondary concentrators with light guides of rectangular cross-section for radiation homogenization, four hollow two-dimensional compound parabolic concentrators for further concentration of uniform radiations from the light guides to a 3 mm diameter, 76 mm length Nd:YAG rod within four V-shaped pumping cavities. An asymmetric resonator ensures an efficient large-mode matching between pump light and oscillating laser light. Laser power of 59.1 W TEM(00) is calculated by ZEMAX and LASCAD numerical analysis, revealing 20 times improvement in brightness figure of merit.

Simultaneous observations of structure function parameter of refractive index using a high-resolution radar and the DataHawk small airborne measurement system

Science.gov (United States)

Scipión, Danny E.; Lawrence, Dale A.; Milla, Marco A.; Woodman, Ronald F.; Lume, Diego A.; Balsley, Ben B.

2016-09-01

The SOUSY (SOUnding SYstem) radar was relocated to the Jicamarca Radio Observatory (JRO) near Lima, Peru, in 2000, where the radar controller and acquisition system were upgraded with state-of-the-art parts to take full advantage of its potential for high-resolution atmospheric sounding. Due to its broad bandwidth (4 MHz), it is able to characterize clear-air backscattering with high range resolution (37.5 m). A campaign conducted at JRO in July 2014 aimed to characterize the lower troposphere with a high temporal resolution (8.1 Hz) using the DataHawk (DH) small unmanned aircraft system, which provides in situ atmospheric measurements at scales as small as 1 m in the lower troposphere and can be GPS-guided to obtain measurements within the beam of the radar. This was a unique opportunity to make coincident observations by both systems and to directly compare their in situ and remotely sensed parameters. Because SOUSY only points vertically, it is only possible to retrieve vertical radar profiles caused by changes in the refractive index within the resolution volume. Turbulent variations due to scattering are described by the structure function parameter of refractive index Cn2. Profiles of Cn2 from the DH are obtained by combining pressure, temperature, and relative humidity measurements along the helical trajectory and integrated at the same scale as the radar range resolution. Excellent agreement is observed between the Cn2 estimates obtained from the DH and SOUSY in the overlapping measurement regime from 1200 m up to 4200 m above sea level, and this correspondence provides the first accurate calibration of the SOUSY radar for measuring Cn2.

TEM Study of the Orientation Relationship Between Cementite and Ferrite in a Bainitic Low Carbon High Strength Low Alloy Steel

OpenAIRE

Illescas Fernandez, Silvia; Brown, A.P.; He, K.; Fernández, Javier; Guilemany Casadamon, Josep Maria

2005-01-01

Two different bainitic structures are observed in a steel depending on the sample heat treatment. The different types of bainitic structures exhibit different orientation relationships between cementite and the ferrite matrix. Upper bainite presents a Pitsch orientation relationship and lower bainite presents a Bagaryatski orientation relationship. Different heat treatments of low carbon HSLA steel samples have been studied using TEM in order to find the orientation relationshi...

Advancements in medium and high resolution Earth observation for land-surface imaging: Evolutions, future trends and contributions to sustainable development

Science.gov (United States)

Ouma, Yashon O.

2016-01-01

Technologies for imaging the surface of the Earth, through satellite based Earth observations (EO) have enormously evolved over the past 50 years. The trends are likely to evolve further as the user community increases and their awareness and demands for EO data also increases. In this review paper, a development trend on EO imaging systems is presented with the objective of deriving the evolving patterns for the EO user community. From the review and analysis of medium-to-high resolution EO-based land-surface sensor missions, it is observed that there is a predictive pattern in the EO evolution trends such that every 10-15 years, more sophisticated EO imaging systems with application specific capabilities are seen to emerge. Such new systems, as determined in this review, are likely to comprise of agile and small payload-mass EO land surface imaging satellites with the ability for high velocity data transmission and huge volumes of spatial, spectral, temporal and radiometric resolution data. This availability of data will magnify the phenomenon of ;Big Data; in Earth observation. Because of the ;Big Data; issue, new computing and processing platforms such as telegeoprocessing and grid-computing are expected to be incorporated in EO data processing and distribution networks. In general, it is observed that the demand for EO is growing exponentially as the application and cost-benefits are being recognized in support of resource management.

TEM and EELS study of deuterated carbon: application to the fuel retention in tokamaks; Etude couplee MET-EELS du carbone deutere: application a la retention du combustible dans les tokamaks

Energy Technology Data Exchange (ETDEWEB)

Bernier, N

2007-12-15

We developed a methodology, based on the combination of TEM and EELS techniques, for a structural and chemical characterization, at a high spatial resolution, of a wide range of carbon materials. We i) optimized, in the framework of theoretical models, the sp2 fraction quantification from pure carbons by EELS ii) transferred this quantification to deuterated amorphous carbon layers iii) showed, from graphitized carbons, how the TEM-EELS combination allows to detect low concentrations of implanted D. Due to the accomplishment of these developments, we applied our approach to the study of D retention in composites C/C, which are the plasma-facing materials in TS. We showed that specific localized retention sites correspond to relatively large ({approx} 3 mm.) cracks between fibres and matrix; such cracks offer a simple and direct path for deuterated amorphous carbon. The particle balance performed in TS is discussed in the light of this trapping mechanism. (author)

TEM study of radiation induced defects in baffle-former-barrel assembly from decommissioned NPP Greifswald

International Nuclear Information System (INIS)

Srba, O.; Michalicka, J.; Keilova, E.; Kocik, K.

2013-06-01

A complex transmission electron microscopy (TEM) study of reactor vessel internal (RVI) materials from the baffle-former-barrel assembly from NPP Greifswald (VVER 440), Unit 1 decommissioned after 15 service cycles has been undertaken. All parts of the baffle-former-barrel assembly are made from Ti-stabilized austenitic stainless steel 08Ch18N10T. The materials were exposed to different dose of neutron radiation (2.4 - 11.4 dpa) at temperatures 267 - 398 deg. C depending on position in the core. Three types of radiation induced defects were identified and quantified, namely: dislocations, cavities (voids) and fine-scaled precipitated particles of Ni-Si rich phases. Black-dot type defects were observed too. Operation conditions are around ≅ 300 deg. C that is why we have observed defect typical for both low and high regions of irradiation temperatures. (authors)

Observations of a Cold Front at High Spatiotemporal Resolution Using an X-Band Phased Array Imaging Radar

Directory of Open Access Journals (Sweden)

Andrew Mahre

2017-02-01

Full Text Available While the vertical structure of cold fronts has been studied using various methods, previous research has shown that traditional methods of observing meteorological phenomena (such as pencil-beam radars in PPI/volumetric mode are not well-suited for resolving small-scale cold front phenomena, due to relatively low spatiotemporal resolution. Additionally, non-simultaneous elevation sampling within a vertical cross-section can lead to errors in analysis, as differential vertical advection cannot be distinguished from temporal evolution. In this study, a cold front from 19 September 2015 is analyzed using the Atmospheric Imaging Radar (AIR. The AIR transmits a 20-degree fan beam in elevation, and digital beamforming is used on receive to generate simultaneous receive beams. This mobile, X-band, phased-array radar offers temporal sampling on the order of 1 s (while in RHI mode, range sampling of 30 m (37.5 m native resolution, and continuous, arbitrarily oversampled data in the vertical dimension. Here, 0.5-degree sampling is used in elevation (1-degree native resolution. This study is the first in which a cold front has been studied via imaging radar. The ability of the AIR to obtain simultaneous RHIs at high temporal sampling rates without mechanical steering allows for analysis of features such as Kelvin-Helmholtz instabilities and feeder flow.

Real-time transmission electron microscope observation of gold nanoclusters diffusing into silicon at room temperature

International Nuclear Information System (INIS)

Ishida, Tadashi; Nakajima, Yuuki; Fujita, Hiroyuki; Endo, Junji; Collard, Dominique

2009-01-01

Gold diffusion into silicon at room temperature was observed in real time with atomic resolution. Gold nanoclusters were formed on a silicon surface by an electrical discharge between a silicon tip and a gold coated tip inside an ultrahigh-vacuum transmission electron microscope (TEM) specimen chamber. At the moment of the gold nanocluster deposition, the gold nanoclusters had a crystalline structure. The crystalline structure gradually disappeared due to the interdiffusion between silicon and gold as observed after the deposition of gold nanoclusters. The shape of the nanocluster gradually changed due to the gold diffusion into the damaged silicon. The diffusion front between silicon and gold moved toward the silicon side. From the observations of the diffusion front, the gold diffusivity at room temperature was extracted. The extracted activation energy, 0.21 eV, matched the activation energy in bulk diffusion between damaged silicon and gold. This information is useful for optimizing the hybridization between solid-state and biological nanodevices in which gold is used as an adhesive layer between the two devices.

The Track of Brain Activity during the Observation of TV Commercials with the High-Resolution EEG Technology

Directory of Open Access Journals (Sweden)

Laura Astolfi

2009-01-01

Full Text Available We estimate cortical activity in normal subjects during the observation of TV commercials inserted within a movie by using high-resolution EEG techniques. The brain activity was evaluated in both time and frequency domains by solving the associate inverse problem of EEG with the use of realistic head models. In particular, we recover statistically significant information about cortical areas engaged by particular scenes inserted within the TV commercial proposed with respect to the brain activity estimated while watching a documentary. Results obtained in the population investigated suggest that the statistically significant brain activity during the observation of the TV commercial was mainly concentrated in frontoparietal cortical areas, roughly coincident with the Brodmann areas 8, 9, and 7, in the analyzed population.

SOUTHERN MASSIVE STARS AT HIGH ANGULAR RESOLUTION: OBSERVATIONAL CAMPAIGN AND COMPANION DETECTION

Energy Technology Data Exchange (ETDEWEB)

Sana, H. [European Space Agency/Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Le Bouquin, J.-B.; Duvert, G.; Zins, G. [Université Grenoble Alpes, IPAG, F-38000 Grenoble (France); Lacour, S.; Gauchet, L.; Pickel, D. [LESIA, Observatoire de Paris, CNRS, UPMC, Université Paris-Diderot, Paris Sciences et Lettres, 5 Place Jules Janssen, F-92195 Meudon (France); Berger, J.-P. [European Southern Observatory, Schwarzschild-Str. 2, D-85748 Garching bei München (Germany); Norris, B. [Sydney Institute for Astronomy, School of Physics, University of Sydney, NSW 2006 (Australia); Olofsson, J. [Max-Planck-Institut für Astronomie, Koenigstuhl 17, D-69117 Heidelberg (Germany); Absil, O. [Département d' Astrophysique, Géophysique et Océanographie, Université de Liège, 17 Allée du Six Août, B-4000 Liège (Belgium); De Koter, A. [Astrophysical Institute Anton Pannekoek, Universiteit van Amsterdam, Science Park 904, 1098XH Amsterdam (Netherlands); Kratter, K. [JILA, 440 UCB, University of Colorado, Boulder, CO 80309-0440 (United States); Schnurr, O. [Leibniz-Institut für Astrophysik Potsdam, An der Sternwarte 16, D-14482 Potsdam (Germany); Zinnecker, H., E-mail: hsana@stsci.edu [Deutsches SOFIA Instituut, SOFIA Science Center, NASA Ames Research Center, Mail Stop N232-12, Moffett Field, CA 94035 (United States)

2014-11-01

Multiplicity is one of the most fundamental observable properties of massive O-type stars and offers a promising way to discriminate between massive star formation theories. Nevertheless, companions at separations between 1 and 100 milliarcsec (mas) remain mostly unknown due to intrinsic observational limitations. At a typical distance of 2 kpc, this corresponds to projected physical separations of 2-200 AU. The Southern MAssive Stars at High angular resolution survey (SMaSH+) was designed to fill this gap by providing the first systematic interferometric survey of Galactic massive stars. We observed 117 O-type stars with VLTI/PIONIER and 162 O-type stars with NACO/Sparse Aperture Masking (SAM), probing the separation ranges 1-45 and 30-250 mas and brightness contrasts of ΔH < 4 and ΔH < 5, respectively. Taking advantage of NACO's field of view, we further uniformly searched for visual companions in an 8'' radius down to ΔH = 8. This paper describes observations and data analysis, reports the discovery of almost 200 new companions in the separation range from 1 mas to 8'' and presents a catalog of detections, including the first resolved measurements of over a dozen known long-period spectroscopic binaries. Excluding known runaway stars for which no companions are detected, 96 objects in our main sample (δ < 0°; H < 7.5) were observed both with PIONIER and NACO/SAM. The fraction of these stars with at least one resolved companion within 200 mas is 0.53. Accounting for known but unresolved spectroscopic or eclipsing companions, the multiplicity fraction at separation ρ < 8'' increases to f {sub m} = 0.91 ± 0.03. The fraction of luminosity class V stars that have a bound companion reaches 100% at 30 mas while their average number of physically connected companions within 8'' is f {sub c} = 2.2 ± 0.3. This demonstrates that massive stars form nearly exclusively in multiple systems. The nine non-thermal radio

Nucleation and Nanometric Inhomogeneity in Niobiogermanate Glass: In-Situ Inelastic Light Scattering and TEM Studies

International Nuclear Information System (INIS)

Takahashi, Y; Ihara, R; Fujiwara, T; Osada, M; Masai, H

2011-01-01

We performed in-situ inelastic light scattering measurement in KNbGeO 5 glass with a high nucleation ability during heating in order to elucidate nanocrystallization dynamics. The results of the in-situ measurement and TEM observation revealed that nanometric heterogeneous region (∼1-2 nm) consisting of the Nb-richer phase develops, i.e., K 3 Nb 7 O 19 , at the temperature, in which glassy-supercooled-liquid (SCL) phase-transition occurs, i.e., precursive stage of nanocrystallization. This strongly suggests that evolution of the nanometric Nb-richer phase in the SCL phase corresponds to nucleation in the KNbGeO 5 glass.

ANALISIS KUAT SINYAL DAN KUALITAS PANGGILAN JARINGAN GSM INDOOR DENGAN TEMS INVESTIGATION DAN G-NETTRACK PRO

Directory of Open Access Journals (Sweden)

Ida Bagus Ari Budiarta

2016-03-01

Full Text Available Kebutuhan akan teknologi GSM merupakan tantangan bagi provider untuk memberikan pelayanan terbaik bagi pengguna layanannya. Dalam proses layanan tersebut kemungkinan besar terdapat masalah yang terjadi. Pihak provider biasanya melakukan walk test untuk mengecek kekuatan sinyal yang dipancarkan oleh antena pemancar di dalam ruangan. Kebanyakan pihak provider menggunakan TEMS Investigation dalam melakukan walk test. Biaya walk test dengan TEMS Investigation bisa dikatakan cukup mahal. Namun dengan berkembangnya teknologi, walk test juga bisa dilakukan menggunakan smartphone Android dengan menggunakan G-NetTrack Pro. Dalam penelitian ini dibandingkan kualitas hasil pengukuran parameter kuat sinyal yaitu RSL dan parameter kualitas panggilan yaitu RxQual, CSSR, dan DCR antara software TEMS Investigation dengan G-NetTrack Pro berdasarkan metode walk test pada jaringan GSM indoor 1800 MHz di Matahari Duta Plaza. Secara keseluruhan, G-NetTrack Pro mampu menampilkan data yang dibutuhkan pada penelitian tetapi tidak sedetail TEMS Investigation, sehingga untuk pengenalan awal walk test, software G-NetTrack Pro bisa digunakan sebagai bahan pembelajaran.

Thin dielectric film thickness determination by advanced transmission electron microscopy

Energy Technology Data Exchange (ETDEWEB)

Diebold, A.C.; Foran, B.; Kisielowski, C.; Muller, D.; Pennycook, S.; Principe, E.; Stemmer, S.

2003-09-01

High Resolution Transmission Electron Microscopy (HR-TEM) has been used as the ultimate method of thickness measurement for thin films. The appearance of phase contrast interference patterns in HR-TEM images has long been confused as the appearance of a crystal lattice by non-specialists. Relatively easy to interpret crystal lattice images are now directly observed with the introduction of annular dark field detectors for scanning TEM (STEM). With the recent development of reliable lattice image processing software that creates crystal structure images from phase contrast data, HR-TEM can also provide crystal lattice images. The resolution of both methods was steadily improved reaching now into the sub Angstrom region. Improvements in electron lens and image analysis software are increasing the spatial resolution of both methods. Optimum resolution for STEM requires that the probe beam be highly localized. In STEM, beam localization is enhanced by selection of the correct aperture. When STEM measurement is done using a highly localized probe beam, HR-TEM and STEM measurement of the thickness of silicon oxynitride films agree within experimental error. In this paper, the optimum conditions for HR-TEM and STEM measurement are discussed along with a method for repeatable film thickness determination. The impact of sample thickness is also discussed. The key result in this paper is the proposal of a reproducible method for film thickness determination.

ANALISIS JARINGAN UMTS PADA MENARA ROOFTOP DENGAN MENGGUNAKAN SOFTWARE TEMS INVESTIGATION DAN G-NETTRACK PRO

OpenAIRE

Pande Putu Wahyu Pramanda; Pande Ketut Sudiarta; Ngurah Indra ER.

2016-01-01

Berkembangnya dunia teknologi telekomunikasi dan informasi sejalan dengan kebutuhan akan kecepatan dan kestabilan akses internet teknologi UMTS. Metode drive test adalah metode yang biasanya digunakan untuk pengukuran kualitas sebuah site. Pihak provider umumnya menggunakan software TEMS Investigation dalam melakukan drive test. Melakukan drive test dengan TEMS Investigation sangatlah tidak praktis dan memerlukan biaya yang besar. Berkembangnya teknologi smartphone membuat drive test dapat di...

Development and ITER relevant application of a user friendly interface (TEM) for use with the TMAP4 code

International Nuclear Information System (INIS)

Tanaka, M.R.; Fong, C.; Kalyanam, K.M.; Sood, S.K.; Delisle, M.; Natalizio, A.

1995-01-01

The Tritium Enclosure Model (TEM) has been developed as a user friendly interface to facilitate the application of the previously validated, verified and ITER approved TMAP4 Code. TEM (and TMAP4) dynamically analyzes the movement of tritium through structures, between structures and adjoining enclosures. Credible ITER relevant accident scenarios were developed and analyzed. The analyses considered the scenario with the cleanup system active or inactive, with and without the surface interactions. For surface interaction cases, the epoxy characteristics reported in the TMAP4 User Manual were used. Typical applications for TEM are the estimation of time-dependent tritium inventories in enclosures, as well as emissions to the environment following an accidental spill into any set of enclosures connected to cleanup systems. This paper outlines the various features of TEM and reports on the application of TEM to determine environmental source terms for the ITER Fuel Cycle and Cooling Systems, under chronic and accidental tritium releases. 3 refs., 2 figs., 1 tab

TEM Characterization of High Burn-up Microstructure of U-7Mo Alloy

Energy Technology Data Exchange (ETDEWEB)

Jian Gan; Brandon Miller; Dennis Keiser; Adam Robinson; James Madden; Pavel Medvedev; Daniel Wachs

2014-04-01

As an essential part of global nuclear non-proliferation effort, the RERTR program is developing low enriched U-Mo fuels (< 20% U-235) for use in research and test reactors that currently employ highly enriched uranium fuels. One type of fuel being developed is a dispersion fuel plate comprised of U-7Mo particles dispersed in Al alloy matrix. Recent TEM characterizations of the ATR irradiated U-7Mo dispersion fuel plates include the samples with a local fission densities of 4.5, 5.2, 5.6 and 6.3 E+21 fissions/cm3 and irradiation temperatures of 101-136?C. The development of the irradiated microstructure of the U-7Mo fuel particles consists of fission gas bubble superlattice, large gas bubbles, solid fission product precipitates and their association to the large gas bubbles, grain subdivision to tens or hundreds of nanometer size, collapse of bubble superlattice, and amorphisation. This presentation will describe the observed microstructures specifically focusing on the U-7Mo fuel particles. The impact of the observed microstructure on the fuel performance and the comparison of the relevant features with that of the high burn-up UO2 fuels will be discussed.

16S rRNA gene metabarcoding and TEM reveals different ecological strategies within the genus Neogloboquadrina (planktonic foraminifer.

Directory of Open Access Journals (Sweden)

Clare Bird

Full Text Available Uncovering the complexities of trophic and metabolic interactions among microorganisms is essential for the understanding of marine biogeochemical cycling and modelling climate-driven ecosystem shifts. High-throughput DNA sequencing methods provide valuable tools for examining these complex interactions, although this remains challenging, as many microorganisms are difficult to isolate, identify and culture. We use two species of planktonic foraminifera from the climatically susceptible, palaeoceanographically important genus Neogloboquadrina, as ideal test microorganisms for the application of 16S rRNA gene metabarcoding. Neogloboquadrina dutertrei and Neogloboquadrina incompta were collected from the California Current and subjected to either 16S rRNA gene metabarcoding, fluorescence microscopy, or transmission electron microscopy (TEM to investigate their species-specific trophic interactions and potential symbiotic associations. 53-99% of 16S rRNA gene sequences recovered from two specimens of N. dutertrei were assigned to a single operational taxonomic unit (OTU from a chloroplast of the phylum Stramenopile. TEM observations confirmed the presence of numerous intact coccoid algae within the host cell, consistent with algal symbionts. Based on sequence data and observed ultrastructure, we taxonomically assign the putative algal symbionts to Pelagophyceae and not Chrysophyceae, as previously reported in this species. In addition, our data shows that N. dutertrei feeds on protists within particulate organic matter (POM, but not on bacteria as a major food source. In total contrast, of OTUs recovered from three N. incompta specimens, 83-95% were assigned to bacterial classes Alteromonadales and Vibrionales of the order Gammaproteobacteria. TEM demonstrates that these bacteria are a food source, not putative symbionts. Contrary to the current view that non-spinose foraminifera are predominantly herbivorous, neither N. dutertrei nor N. incompta

Multi-wavelength high-resolution observations of a small-scale emerging magnetic flux event and the chromospheric and coronal response

Energy Technology Data Exchange (ETDEWEB)

Vargas Domínguez, Santiago; Kosovichev, Alexander; Yurchyshyn, Vasyl, E-mail: svargas@bbso.njit.edu [Big Bear Solar Observatory, NJIT, 40386 North Shore Lane, Big Bear City, CA 92314-9672 (United States)

2014-10-20

State-of-the-art solar instrumentation is now revealing magnetic activity of the Sun with unprecedented temporal and spatial resolutions. Observations with the 1.6 m aperture New Solar Telescope (NST) of the Big Bear Solar Observatory are making next steps in our understanding of the solar surface structure. Granular-scale magnetic flux emergence and the response of the solar atmosphere are among the key research topics of high-resolution solar physics. As part of a joint observing program with NASA's Interface Region Imaging Spectrograph (IRIS) mission on 2013 August 7, the NST observed active region NOAA 11,810 in the photospheric TiO 7057 Å band with a resolution of pixel size of 0.''034 and chromospheric He I 10830 Å and Hα 6563 Å wavelengths. Complementary data are provided by the Solar Dynamics Observatory (SDO) and Hinode space-based telescopes. The region displayed a group of solar pores, in the vicinity of which we detect a small-scale buoyant horizontal magnetic flux tube causing granular alignments and interacting with the preexisting ambient field in the upper atmospheric layers. Following the expansion of distorted granules at the emergence site, we observed a sudden appearance of an extended surge in the He I 10830 Å data (bandpass of 0.05 Å). The IRIS transition region imaging caught ejection of a hot plasma jet associated with the He I surge. The SDO/HMI data used to study the evolution of the magnetic and Doppler velocity fields reveal emerging magnetic loop-like structures. Hinode/Ca II H and IRIS filtergrams detail the connectivities of the newly emerged magnetic field in the lower solar chromosphere. From these data, we find that the orientation of the emerging magnetic field lines from a twisted flux tube formed an angle of ∼45° with the overlying ambient field. Nevertheless, the interaction of emerging magnetic field lines with the pre-existing overlying field generates high-temperature emission regions and boosts the

Nano features of Al/Au ultrasonic bond interface observed by high resolution transmission electron microscopy

International Nuclear Information System (INIS)

Ji Hongjun; Li Mingyu; Kim, Jong-Myung; Kim, Dae-Won; Wang Chunqing

2008-01-01

Nano-scale interfacial details of ultrasonic AlSi1 wire wedge bonding to a Au/Ni/Cu pad were investigated using high resolution transmission electron microscopy (HRTEM). The intermetallic phase Au 8 Al 3 formed locally due to diffusion and reaction activated by ultrasound at the Al/Au bond interface. Multilayer sub-interfaces roughly parallel to the wire/pad interface were observed among this phase, and interdiffusional features near the Au pad resembled interference patterns, alternately dark and bright bars. Solid-state diffusion theory cannot be used to explain why such a thick compound formed within milliseconds at room temperature. The major formation of metallurgical bonds was attributed to ultrasonic cyclic vibration

Pro-angiogenic TIE-2-expressing monocytes/TEMs as a biomarker of the effect of sorafenib in patients with advanced hepatocellular carcinoma.

Science.gov (United States)

Shoji, Hirotaka; Yoshio, Sachiyo; Mano, Yohei; Doi, Hiroyoshi; Sugiyama, Masaya; Osawa, Yosuke; Kimura, Kiminori; Arai, Taeang; Itokawa, Norio; Atsukawa, Masanori; Aoki, Yoshihiko; Fukai, Moto; Taketomi, Akinobu; Mizokami, Masashi; Kanto, Tatsuya

2017-09-01

Sorafenib, a multi-kinase inhibitor, inhibits tumor angiogenesis and is the first-line systemic therapy for patients with advanced hepatocellular carcinoma (HCC). However, due to its limited effects and frequent occurrence of side effects, biomarkers are needed to predict the effects of sorafenib. We considered the possibility of using TIE-2-expressing monocytes (TEMs) to predict the response in sorafenib-treated patients with advanced HCC. TEMs serve as a diagnostic marker of HCC and are related to angiogenesis. We analyzed 25 advanced HCC patients and prospectively evaluated TEMs before (Pre TEMs) and at 1 month after initial therapy (T1m TEMs). The radiologic response was evaluated by modified Response Evaluation Criteria in Solid Tumors (mRECIST). Median survival time (MST) was significantly longer in the partial response/stable disease (PR/SD) group (21.8 months) than in the PD group (8.7 months). ΔTEMs (changes of T1m TEMs compared to Pre TEMs) were significantly lower in the PR/SD group than in the PD group. MST of the ΔTEMs low group (14.2 months) was significantly longer than that of the high group (8.7 months). Univariate and multivariate Cox regression analyses showed that ΔTEMs [hazard ratio (HR) = 8.53, 95% confidence interval (CI) = 1.51-48.16, p = 0.015] and Child-Pugh class (HR = 5.59, 95% CI = 1.06-29.63, p = 0.043) were independently associated with overall survival. Our results suggest that ΔTEMs could serve as a biomarker for predicting radiologic response and overall survival in sorafenib-treated patients with advanced HCC. © 2017 UICC.

Scattering of a TEM wave from a time varying surface

Science.gov (United States)

Elcrat, Alan R.; Harder, T. Mark; Stonebraker, John T.

1990-03-01

A solution is given for reflection of a plane wave with TEM polarization from a planar surface with time varying properties. These properties are given in terms of the currents on the surface. The solution is obtained by numerically solving a system of differential-delay equations in the time domain.

Simultaneous observations of structure function parameter of refractive index using a high-resolution radar and the DataHawk small airborne measurement system

Directory of Open Access Journals (Sweden)

D. E. Scipión

2016-09-01

Full Text Available The SOUSY (SOUnding SYstem radar was relocated to the Jicamarca Radio Observatory (JRO near Lima, Peru, in 2000, where the radar controller and acquisition system were upgraded with state-of-the-art parts to take full advantage of its potential for high-resolution atmospheric sounding. Due to its broad bandwidth (4 MHz, it is able to characterize clear-air backscattering with high range resolution (37.5 m. A campaign conducted at JRO in July 2014 aimed to characterize the lower troposphere with a high temporal resolution (8.1 Hz using the DataHawk (DH small unmanned aircraft system, which provides in situ atmospheric measurements at scales as small as 1 m in the lower troposphere and can be GPS-guided to obtain measurements within the beam of the radar. This was a unique opportunity to make coincident observations by both systems and to directly compare their in situ and remotely sensed parameters. Because SOUSY only points vertically, it is only possible to retrieve vertical radar profiles caused by changes in the refractive index within the resolution volume. Turbulent variations due to scattering are described by the structure function parameter of refractive index Cn2. Profiles of Cn2 from the DH are obtained by combining pressure, temperature, and relative humidity measurements along the helical trajectory and integrated at the same scale as the radar range resolution. Excellent agreement is observed between the Cn2 estimates obtained from the DH and SOUSY in the overlapping measurement regime from 1200 m up to 4200 m above sea level, and this correspondence provides the first accurate calibration of the SOUSY radar for measuring Cn2.