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Sample records for resistant elastomeric compositions

  1. Highly stretchable resistive pressure sensors using a conductive elastomeric composite on a micropyramid array.

    Science.gov (United States)

    Choong, Chwee-Lin; Shim, Mun-Bo; Lee, Byoung-Sun; Jeon, Sanghun; Ko, Dong-Su; Kang, Tae-Hyung; Bae, Jihyun; Lee, Sung Hoon; Byun, Kyung-Eun; Im, Jungkyun; Jeong, Yong Jin; Park, Chan Eon; Park, Jong-Jin; Chung, U-In

    2014-06-04

    A stretchable resistive pressure sensor is achieved by coating a compressible substrate with a highly stretchable electrode. The substrate contains an array of microscale pyramidal features, and the electrode comprises a polymer composite. When the pressure-induced geometrical change experienced by the electrode is maximized at 40% elongation, a sensitivity of 10.3 kPa(-1) is achieved. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Elastomeric composites with tuned electromagnetic characteristics

    International Nuclear Information System (INIS)

    Wheeland, Sara; Bayatpur, Farhad; Amirkhizi, Alireza V; Nemat-Nasser, Sia

    2013-01-01

    This paper presents a novel elastomeric composite that exhibits a deformation-induced change in chirality. Previous efforts primarily dealt with a coil array in air without chiral tuning. Here, a composite is created that consists of an array of parallel, metallic helices of the same handedness embedded in a polymer matrix. The chiral response of the composite depends on pitch, coil diameter, wire thickness and coil spacing; however, pitch has the greatest effect on electromagnetic performance. The present study explores this effect by using helical elements to construct a chiral medium that can be mechanically stretched to adjust pitch. This adjustment directly affects the overall chirality of the composite. A prototype sample of the composite, fabricated for operation between 5.5–12.5 GHz, demonstrates repeatable elastic deformation. Using a transmit/receive measurement setup, the composite scattering response is measured over the frequency interval. The results indicate substantial tuning of chirality through deformation. An increase in axial strain of up to 30% yields a ∼18% change in axial chirality. (paper)

  3. Mechanically programmed shape change in laminated elastomeric composites.

    Science.gov (United States)

    Robertson, Jaimee M; Torbati, Amir H; Rodriguez, Erika D; Mao, Yiqi; Baker, Richard M; Qi, H Jerry; Mather, Patrick T

    2015-07-28

    Soft, anisotropic materials, such as myocardium in the heart and the extracellular matrix surrounding cells, are commonly found in nature. This anisotropy leads to specialized responses and is imperative to material functionality, yet few soft materials exhibiting similar anisotropy have been developed. Our group introduced an anisotropic shape memory elastomeric composite (A-SMEC) composed of non-woven, aligned polymer fibers embedded in an elastomeric matrix. The composite exhibited shape memory (SM) behavior with significant anisotropy in room-temperature shape fixing. Here, we exploit this anisotropy by bonding together laminates with oblique anisotropy such that tensile deformation at room temperature - mechanical programming - results in coiling. This response is a breakthrough in mechanical programming, since non-affine shape change is achieved by simply stretching the layered A-SMECs at room temperature. We will show that pitch and curvature of curled geometries depend on fiber orientations and the degree of strain programmed into the material. To validate experimental results, a model was developed that captures the viscoplastic response of A-SMECs. Theoretical results correlated well with experimental data, supporting our conclusions and ensuring attainability of predictable curling geometries. We envision these smart, soft, shape changing materials will have aerospace and medical applications.

  4. Flexible Connection Elastomeric Rubber as a Pounding Resisting Element between Two Adjacent Buildings

    Directory of Open Access Journals (Sweden)

    Yuskar Lase

    2013-03-01

    Full Text Available To solve pounding problem of two adjacent buildings, structural designer usually employs a dilatation between the structures or make the two structures as a monolith structure. Other alternative is by using an elastomeric rubber as a pounding resisting element between the two structures. Effectiveness in applying elastomeric rubber component as flexible connection of two adjacent structures is the main focus of this paper. Various simulations such as structure models, earthquake excitations and openings in gap element are studied. Observation of maximum structural responses will be performed for structure model with elastomeric rubber in comparison with (1 monolith structure model and (2 structure model with rigid element (steel element. Simulation results show that application of elastomeric rubber component to prevent structures from pounding problem provides advantages especially in reducing internal forces in the shorter building. However, it slightly increases displacement of both structures.

  5. Static frictional resistance with the slide low-friction elastomeric ligature system.

    Science.gov (United States)

    Jones, Steven P; Ben Bihi, Saida

    2009-11-01

    This ex-vivo study compared the static frictional resistance of a low-friction ligation system against a conventional elastomeric module, and studied the effect of storage in a simulated oral environment on the static frictional resistance of both ligation systems. Eighty stainless steel brackets were tested by sliding along straight lengths of 0.018 inch round and 0.019 x 0.025 inch rectangular stainless steel wires ligated with either conventional elastomerics or the Slide system (Leone, Florence, Italy). During the tests the brackets and wires were lubricated with artificial saliva. A specially constructed jig assembly was used to hold the bracket and archwire securely. The jig was clamped in an Instron universal load testing machine. Crosshead speed was controlled via a microcomputer connected to the Instron machine. The static frictional forces at 0 degree bracket/wire angulation were measured for both systems, fresh from the pack and after storage in artificial saliva at 37 degrees C for 24 hours. The results of this investigation demonstrated that the Slide ligatures produced significantly lower static frictional resistance than conventional elastomeric modules in the fresh condition and after 24 hours of storage in a simulated oral environment (p static frictional resistance of conventional elastomeric modules and the Slide system (p = 0.525). The claim by the manufacturer that the Slide system produces lower frictional resistance than conventional elastomeric modules is upheld.

  6. Elastomeric Properties of Poly(glycerol sebacate) (PGS) Based Nanoparticle Composites

    Science.gov (United States)

    Chung, Hyun-Joong; Li, Xinda; Hong, Albert T.-L.

    2014-03-01

    Owing to the unique combination of biocompatible, biodegradable, and elastomeric properties, poly(glycerol sebacate) and their derivatives are an emerging class of biomaterials for soft tissue replacement, drug delivery, tissue adhesive, and hard tissue regeneration. The mechanical properties of the polyester have been tailored to match a wide range of target organs, ranging from cardiac muscle to bones, by manipulating the process parameters to modulate cross-linking density. In the present study, we applied nanoparticles and cross-linking agents to further optimize their elastomeric properties. Especially, the study aims to enhance the practically important, but less studied, property of tear resistance. Microscopic origin of the property enhancement is discussed.

  7. Radiation resistance of elastomeric O-rings in mixed neutron and gamma fields: Testing methodology and experimental results

    Science.gov (United States)

    Zenoni, A.; Bignotti, F.; Donzella, A.; Donzella, G.; Ferrari, M.; Pandini, S.; Andrighetto, A.; Ballan, M.; Corradetti, S.; Manzolaro, M.; Monetti, A.; Rossignoli, M.; Scarpa, D.; Alloni, D.; Prata, M.; Salvini, A.; Zelaschi, F.

    2017-11-01

    Materials and components employed in the presence of intense neutron and gamma fields are expected to absorb high dose levels that may induce deep modifications of their physical and mechanical properties, possibly causing loss of their function. A protocol for irradiating elastomeric materials in reactor mixed neutron and gamma fields and for testing the evolution of their main mechanical and physical properties with absorbed dose has been developed. Four elastomeric compounds used for vacuum O-rings, one fluoroelastomer polymer (FPM) based and three ethylene propylene diene monomer rubber (EPDM) based, presently available on the market have been selected for the test. One EPDM is rated as radiation resistant in gamma fields, while the other elastomers are general purpose products. Particular care has been devoted to dosimetry calculations, since absorbed dose in neutron fields, unlike pure gamma fields, is strongly dependent on the material composition and, in particular, on the hydrogen content. The products have been tested up to about 2 MGy absorbed dose. The FPM based elastomer, in spite of its lower dose absorption in fast neutron fields, features the largest variations of properties, with a dramatic increase in stiffness and brittleness. Out of the three EPDM based compounds, one shows large and rapid changes in the main mechanical properties, whereas the other two feature more stable behaviors. The performance of the EPDM rated as radiation resistant in pure gamma fields does not appear significantly better than that of the standard product. The predictive capability of the accelerated irradiation tests performed as well as the applicable concepts of threshold of radiation damage is discussed in view of the use of the examined products in the selective production of exotic species facility, now under construction at the Legnaro National Laboratories of the Italian Istituto Nazionale di Fisica Nucleare. It results that a careful account of dose rate effects

  8. Frictional resistance of orthodontic wires tied with 3 types of elastomeric ligatures

    Directory of Open Access Journals (Sweden)

    Amanda Carneiro da Cunha

    2011-12-01

    Full Text Available The aims of this study were to determine and compare frictional resistance obtained by low-friction and conventional elastomeric ligatures in the presence of artificial saliva, and observe whether this variable changed after 21 days. Super Slick® low-friction elastomeric ligatures and conventional ligatures of the brands TP conventional® and Unitek® were placed on standard edgewise maxillary central incisor metal brackets, slot .022" × .028" tying rectangular orthodontic wires .018" × .025". Three experimental groups were arranged according to the type of ligature and a control group in which no wires were used. The friction values obtained between the bracket/wire/ligature set were measured using a Universal Test Machine at a speed of 20 mm/minute, at two experimental time intervals: T0 - immediately after specimen fabrication; and T1 - 21 days after fabrication and immersion in artificial saliva at 37 ºC. Conventional Unitek ligatures and the low-friction ligature (Super Slick showed the lowest friction values at T0. After 21 days (T1, however, conventional Unitek ligatures presented the lowest value. All groups assessed from T0 to T1 showed a numerical reduction in friction values, suggesting that time, heat and humidity may cause elastic degradation, however this was not verified statistically (P > 0.05.

  9. Optimization of fractional composition of the excipient in the elastomeric covering for asphalt highways

    Directory of Open Access Journals (Sweden)

    E. M. Nurullaev

    2013-04-01

    Full Text Available The computational method of optimum fractional composition of a dispersible filler of polymeric composite on the basis of three-dimensionally linked elastomer is developed according to non-linear programming. The coefficient of dynamic viscosity of polymeric suspension or the initial module of a viscoelasticity of the join solidification low-molecular rubbers with the final functional groups, filled by many fractional dioxide of silicon are considered as criteria of optimization. Influence of the limiting volume filling on energy of mechanical destruction was investigated. The elastomeric material is offered for use as a covering of asphalt highways in the form of a frost-proof waterproofing layer, which allowing multiply to increase operating properties.

  10. Influence of particle arrangement on the permittivity of an elastomeric composite

    Directory of Open Access Journals (Sweden)

    Peiying J. Tsai

    2017-01-01

    Full Text Available Elastomers are used as dielectric layers contained between the parallel conductive plates of capacitors. The introduction of filler particles into an elastomer changes its permittivity ε. When particle organization in a composite is intentionally varied, this alters its capacitance. Using numerical simulations, we examine how conductive particle chains introduced into polydimethylsiloxane (PDMS alter ε. The effects of filler volume fraction ψ, interparticle d and interchain spacing a, zigzag angle θ between adjacent particles and overall chain orientation, particle size r, and clearance h between particles and the conductive plates are characterized. When filler particles are organized into chainlike structures rather than being just randomly distributed in the elastomer matrix, ε increases by as much as 85%. When particles are organized into chainlike forms, ε increases with increasing ψ and a, but decreases with increasing d and θ. A composite containing smaller particles has a higher ε when ψ<9% while larger particles provide greater enhancement when ψ is larger than that value. To enhance ε, adjacent particles must be interconnected and the overall chain direction should be oriented perpendicular to the conductive plates. These results are useful for additive manufacturing on electrical applications of elastomeric composites.

  11. Influence of particle arrangement on the permittivity of an elastomeric composite

    Science.gov (United States)

    Tsai, Peiying J.; Nayak, Suchitra; Ghosh, Suvojit; Puri, Ishwar K.

    2017-01-01

    Elastomers are used as dielectric layers contained between the parallel conductive plates of capacitors. The introduction of filler particles into an elastomer changes its permittivity ɛ. When particle organization in a composite is intentionally varied, this alters its capacitance. Using numerical simulations, we examine how conductive particle chains introduced into polydimethylsiloxane (PDMS) alter ɛ. The effects of filler volume fraction ψ, interparticle d and interchain spacing a, zigzag angle θ between adjacent particles and overall chain orientation, particle size r, and clearance h between particles and the conductive plates are characterized. When filler particles are organized into chainlike structures rather than being just randomly distributed in the elastomer matrix, ɛ increases by as much as 85%. When particles are organized into chainlike forms, ɛ increases with increasing ψ and a, but decreases with increasing d and θ. A composite containing smaller particles has a higher ɛ when ψ <9 % while larger particles provide greater enhancement when ψ is larger than that value. To enhance ɛ, adjacent particles must be interconnected and the overall chain direction should be oriented perpendicular to the conductive plates. These results are useful for additive manufacturing on electrical applications of elastomeric composites.

  12. Corrosion resistant composite materials

    International Nuclear Information System (INIS)

    Ul'yanin, E.A.

    1986-01-01

    Foundations for corrosion-resistant composite materials design are considered with account of components compatibility. Fibrous and lamellar composites with metal matrix, dispersion-hardened steels and alloys, refractory metal carbides-, borides-, nitrides-, silicides-based composites are described. Cermet compositions and fields of their application, such as protective coatings for operation in agressive media at high temperatures, are presented

  13. Comparison of frictional resistance between self-ligating and conventional brackets tied with elastomeric and metal ligature in orthodontic archwires.

    Science.gov (United States)

    Leite, Vanessa Vieira; Lopes, Murilo Baena; Gonini Júnior, Alcides; Almeida, Marcio Rodrigues de; Moura, Sandra Kiss; Almeida, Renato Rodrigues de

    2014-01-01

    To compare the frictional resistance between self-ligating and conventional brackets tied to different types of wire. Abzil Kirium Capelozza (Pattern I) and Easy Clip (Roth prescription) incisor brackets were used. An elastomeric ligature or a 0.10-in ligating wire was used to ligate the wire to the Abzil bracket. Three types of orthodontic archwire alloys were assessed: 0.016-in NiTi wire, 0.016 x 0.021-in NiTi wire and 0.019 x 0.025-in steel wire. Ten observations were carried out for each bracket-archwire angulation combination. Brackets were mounted in a special appliance, positioned at 90 degrees in relation to the wire and tested in two angulations. Frictional test was performed in a Universal Testing Machine at 5 mm/min and 10 mm of displacement. The means (MPa) were submitted to ANOVA and Tukey's test set at 5% of significance. The surfaces of wires and brackets were observed at SEM. Steel-tied brackets (16.48 ± 8.31) showed higher means of frictional resistance than elastomeric-tied brackets (4.29 ± 2.16 ) and self-ligating brackets (1.66 ± 1.57) (P 0.05). No statistical differences (P > 0.05) were found between zero (7.76 ± 8.46) and five-degree (7.19 ± 7.93) angulations. Friction was influenced not only by the type of bracket, but also by the ligating systems. Different morphological aspects were observed for the brackets and wires studied.

  14. Mechanical Properties and Chemical Resistance of New Composites for Oil Pump Impellers

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    Dilyus I. Chukov

    2018-05-01

    Full Text Available In this paper, a new class of high-performance composites and a method of their production based on the carbonization of an elastomeric matrix are proposed. The use of elastomeric matrix makes it possible to manufacture products with complex shapes, while the subsequent carbonization can significantly improve their properties by changing the chemical nature of the elastomeric matrix. Such an approach can reduce the products’ machining cost, especially for composites reinforced with super hard fillers such as silicon carbide at high filling degrees. Low-temperature carbonization makes it possible to obtain composites with mechanical behavior similar to that of ceramics. In contrast to classical elastomeric materials, the nitrile butadiene rubber (NBR-based compounds were highly filled (300 parts per hundred rubber-PHR with different carbon fillers and silicon carbide; then cured and carbonized at low-temperature 360 °C with the carbonization cycle of 12 h. The feasibility of the production method was validated through the manufacturing of products with complex shapes—impellers for electric centrifugal pumps. It was found that the carbonized composites have good chemical resistance and low water absorption. The composites have high Shore D hardnesses (93–96, ultimate tensile strengths (62–85 MPa, Young’s moduli (17–24 GPa, and compressive strengths (155–181 MPa.

  15. Modeling the electrical resistance of gold film conductors on uniaxially stretched elastomeric substrates

    Science.gov (United States)

    Cao, Wenzhe; Görrn, Patrick; Wagner, Sigurd

    2011-05-01

    The electrical resistance of gold film conductors on polydimethyl siloxane substrates at stages of uniaxial stretching is measured and modeled. The surface area of a gold conductor is assumed constant during stretching so that the exposed substrate takes up all strain. Sheet resistances are calculated from frames of scanning electron micrographs by numerically solving for the electrical potentials of all pixels in a frame. These sheet resistances agree sufficiently well with values measured on the same conductors to give credence to the model of a stretchable network of gold links defined by microcracks.

  16. Self-standing elastomeric composites based on lithium ferrites and their dielectric behavior

    Energy Technology Data Exchange (ETDEWEB)

    Soreto Teixeira, S.; Graça, M. P. F.; Costa, L. C. [I3N and Physics Department, University of Aveiro, 3810-193 Aveiro (Portugal); Dionisio, M. [REQUIMTE, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica (Portugal); Ilcíkova, M.; Mosnacek, J.; Spitalsky, Z. [Polymer Institute, Slovak Academy of Sciences, Dúbravská cesta 9, Bratislava (Slovakia); Krupa, I. [Polymer Institute, Slovak Academy of Sciences, Dúbravská cesta 9, Bratislava (Slovakia); Center for Advanced Materials, Qatar University, P.O. Box 2713, Doha (Qatar)

    2014-12-14

    Lithium ferrite (LiFe{sub 5}O{sub 8}) is an attractive material for technological applications due to its physical properties, which are significantly dependent on the preparation method and raw materials. In this work, LiFe{sub 5}O{sub 8} crystallites were obtained by controlled heat-treatment process at 1100 °C, of a homogeneous mixture of Li{sub 2}O-Fe{sub 2}O{sub 3} powders, prepared by wet ball-milling and using lithium and iron nitrates as raw materials. The main goal was the preparation of a flexible and self-standing tick composite film by embedding lithium ferrite particles in a polymeric matrix, taking advantage of the good mechanical properties of the polymer and of the electrical and dielectric properties of the ferrite. The selected polymer matrix was styrene-b-isoprene-b-styrene copolymer. To prepare the composites, the lithium ferrite particles were chemically modified in order to functionalize their surface. To analyse the influence of the particles surface modification, different composites were made, with modified and unmodified particles. The structure of the obtained composites was studied by FTIR, XRD, TGA, and DSC techniques. The dielectric properties were analysed, in the frequency range between 10 Hz and 1 MHz and in function of temperature in the range between −73 °C and 127 °C. These properties were related with the structure and concentration of the particles in the matrix network. The composites with the modified particles present higher dielectric constant, maintaining values of loss tangent sufficiently low (<10{sup −2}) that can be considered interesting for technological applications.

  17. Resistance to disinfection of a polymicrobial association contaminating the surface of elastomeric dental impressions.

    Science.gov (United States)

    Giammanco, Giovanni M; Melilli, Dario; Rallo, Antonio; Pecorella, Sonia; Mammina, Caterina; Pizzo, Giuseppe

    2009-04-01

    The aim of this study was to evaluate the ability to resist disinfection of a polymicrobial association contaminating the surface of dental impressions obtained with two different elastomers: a polyether (Impregum) and an addition-polymerized silicone (Elite). Impressions were contaminated with a mixture of three biofilm-forming microorganisms (Staphylococcus aureus, Pseudomonas aeruginosa and Candida albicans) and disinfected immediately after contamination, or after microbial layers were allowed to develop during a six-hour storage. Two commercial disinfectants were tested: MD 520 containing 0.5% glutaraldehyde and Sterigum Powder without glutaraldehyde. Residual contamination was recovered by mechanical rinsing immediately after disinfection and after a six-hour storage of disinfected impressions, and assessed by colony counting. Both disinfectants tested were shown to be effective in reducing the microbial presence on the impression materials, achieving at least a 102 reduction of microbial counts compared to water rinsing. However, Sterigum was generally less effective on the Elite elastomer and could not grant disinfection on six-hour aged P. aeruginosa and C. albicans microbial layers. The results of this study suggest that the materials used for the impressions influence the efficacy of disinfection. Disinfectants should be tested according to conditions encountered in everyday clinical practice and the need for immediate disinfection of impressions should be clearly indicated by manufacturers.

  18. Elastic Moduli of Nanoparticle-Polymer Composite Thin Films via Buckling on Elastomeric Substrates

    Science.gov (United States)

    Yuan, Hongyi; Karim, Alamgir; University of Akron Team

    2011-03-01

    Polymeric thin films find applications in diverse areas such as coatings, barriers and packaging. The dispersion of nanoparticles into the films was proven to be an effective method to generate tunable properties, particularly mechanical strength. However, there are very few methods for mechanical characterization of the composite thin films with high accuracy. In this study, nanometric polystyrene and polyvinyl alcohol films with uniformly dispersed cobalt and Cloisite nanoparticles at varying concentrations were synthesized via flow-coating and then transferred to crosslinked polydimethylsiloxane (PDMS) flexible substrates. The technique of Strain-Induced Elastic Buckling Instability for Mechanical Measurements (SIEBIMM) was employed to determine the elastic moduli of the films, which were calculated from the buckling patterns generated by applying compressive stresses. Results on moduli of films as a function of the concentrations of nanoparticles and the thicknesses of the composite films will be presented. *Corresponding author: alamgir@uakron.edu

  19. New approach to obtain elastomeric nano composites with clay from lattices

    International Nuclear Information System (INIS)

    Azeredo, Luciane K. de; Jacobi, Marly M.

    2009-01-01

    Rubber-Montmorillonite nanocomposites were prepared by Continuous Dynamic Latex Compounding (CDLC). This technique, recently developed in our laboratory, permits an intensive intercalation of the polymer at very small residence times in an elongational flow reactor. The processing conditions strongly affect the morphology of nanocomposites characterized by TEM and XRD. Clay-rubber nanocomposites were prepared from the mixture of NBR-, XNBR- and SBR-latex and aqueous suspensions of Na-montmorillonite. The polarity of rubbers influences the final properties of nanocomposites. The nanocomposites obtained by CDLC showed better reinforcement and permeation resistance at far less volume fractions than the obtained with carbon black or silica by conventional methods. (author)

  20. An elastomeric grating coupler

    NARCIS (Netherlands)

    Kocabas, A.; Ay, F.; Dana, A.; Aydinli, A.

    We report on a novel nondestructive and reversible method for coupling free space light to planar optical waveguides. In this method, an elastomeric grating is used to produce an effective refractive index modulation on the surface of the optical waveguide. The external elastomeric grating binds to

  1. Erosion-resistant composite material

    Science.gov (United States)

    Finch, C.B.; Tennery, V.J.; Curlee, R.M.

    A highly erosion-resistant composite material is formed of chemical vapor-deposited titanium diboride on a sintered titanium diboride-nickel substrate. This material may be suitable for use in cutting tools, coal liquefaction systems, etc.

  2. Unvulcanized elastomeric waterproofing materials for construction application

    Directory of Open Access Journals (Sweden)

    O. V. Karmanova

    2016-01-01

    Full Text Available In the construction was widespread elastomer profiles, which have the ability to swell in water. Such products should have a high capacity for swelling, elasticity, resistance to weathering. At the present time for these purposes are used materials, mostly of foreign origin. With the increasing pace of construction in Russia the problem of replacement of imported materials is particularly relevant. The work was dedicated to the creation of water-swellable elastomer materials using bentonite powders and study of their properties. Сomparative testing of imported and domestic hydrophilic sealants were held. Rationale and choice of components for the cords of bentonite was conducted. Polymer base is saturated ethylene-propylene rubber. Bentonite from different manufacturers used to increase the swelling of the samples. Filler added in an amount of 50–100 phr. The elastomeric compositions were prepared using laboratory roller at a temperature of 60 ± 5° C. Profiling was performed on a syringe-machine at a temperature of 120° C. Extrusion indicator of the mixtures were evaluated on a 10-point scale (German-Russian system. It is found that high swelling products provided using field Azerbaijan bentonite. It is noted that the dosage of bentonite than 150 w.p. deteriorates technological properties of bentonite cords. It has been shown that activation of the bentonite and sodium carbonate chloride can significantly improve product swelling, wherein the bentonite content of the composition was 150–200 w.p.

  3. High temperature resistant cermet and ceramic compositions

    Science.gov (United States)

    Phillips, W. M. (Inventor)

    1978-01-01

    Cermet compositions having high temperature oxidation resistance, high hardness and high abrasion and wear resistance, and particularly adapted for production of high temperature resistant cermet insulator bodies are presented. The compositions are comprised of a sintered body of particles of a high temperature resistant metal or metal alloy, preferably molybdenum or tungsten particles, dispersed in and bonded to a solid solution formed of aluminum oxide and silicon nitride, and particularly a ternary solid solution formed of a mixture of aluminum oxide, silicon nitride and aluminum nitride. Also disclosed are novel ceramic compositions comprising a sintered solid solution of aluminum oxide, silicon nitride and aluminum nitride.

  4. Reactive bonding mediated high mass loading of individualized single-walled carbon nanotubes in an elastomeric polymer

    Science.gov (United States)

    Zhao, Liping; Li, Yongjin; Qiu, Jishan; You, Jichun; Dong, Wenyong; Cao, Xiaojun

    2012-09-01

    A reactive chemical bonding strategy was developed for the incorporation of a high mass loading of individual single-wall carbon nanotubes (SWCNTs) into an elastomeric matrix using a reactive ionic liquid as a linker. This method simultaneously prevented the agglomeration of SWCNTs and caused strong interfacial bonding, while the electronic properties of the SWCNTs remained intact. As a result, the high conductivity of the carbon nanotubes (CNTs) and the flexibility of the elastomeric matrix were retained, producing optimum electrical and mechanical properties. A composite material with a loading of 20 wt% SWCNTs was fabricated with excellent mechanical properties and a high conductivity (9500 S m-1). The method could be used to form transparent thin conductive films that could tolerate over 800 bend cycles at a bending angle of 180° while maintaining a constant sheet resistance.A reactive chemical bonding strategy was developed for the incorporation of a high mass loading of individual single-wall carbon nanotubes (SWCNTs) into an elastomeric matrix using a reactive ionic liquid as a linker. This method simultaneously prevented the agglomeration of SWCNTs and caused strong interfacial bonding, while the electronic properties of the SWCNTs remained intact. As a result, the high conductivity of the carbon nanotubes (CNTs) and the flexibility of the elastomeric matrix were retained, producing optimum electrical and mechanical properties. A composite material with a loading of 20 wt% SWCNTs was fabricated with excellent mechanical properties and a high conductivity (9500 S m-1). The method could be used to form transparent thin conductive films that could tolerate over 800 bend cycles at a bending angle of 180° while maintaining a constant sheet resistance. Electronic supplementary information (ESI) available: Conductivity test of the SEBS-SWCNTs film, transmission spectra and sheet resistance for the spin-coated SEBS-SWCNTs thin films on PET slides. See DOI: 10

  5. The influence of modification of elastomer compositions in polyethylene oxides on their resistance to mineral oils

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    E. P. Uss

    2017-01-01

    Full Text Available The influence of modifying of elastomer compositions based on nitrile rubber in the medium of low molecular weight polyethylene oxide on resistance of rubbers to liquid aggressive mediawas studied. Standard hydrocarbon oils – oil ASTM №1 and ASTM №3, having a constant chemical composition and properties, were used as aggressive fluids. Resistance of elastomer compositions to standard oil was evaluated by change in weight, volume and relative compression set after keeping the samples in these oils at elevated temperatures. The influence of aggressive environment on the degree of swelling and the value of compression set of compositions modified in polyethylene oxides medium was established. It has been shown that the mass/volume of modified rubbers during aging in oil ASTM №1 reduced to a lesser degree compared to unmodified samples, which is probably due to the influence of low molecular weight polyethylene oxides for the formation of vulcanizates structure. At the same time exposure to oil ASTM №3 of elastomer compositions increases the degree of swelling of modified rubber more than unmodified, which can be due to destruction by the action of aggressive medium additional intermolecular bonds between macromolecules of polyethylene oxide and rubber, resulting in increased flexibility of the elastomeric matrix segments. It revealed that modification of rubbers in low molecular weightpolyethylene oxides facilitates preparation of rubber with low compression set after aging in standard oils at elevated temperatures.

  6. Asbestos free friction composition for brake linings

    Indian Academy of Sciences (India)

    An asbestos free friction material composite for brake linings is synthesized containing fibrous reinforcing constituents, friction imparting and controlling additives, elastomeric additives, fire retarding components and a thermosetting resin. The composite shows exemplary friction characteristics and has great resistance to ...

  7. High temperature oxidation resistant cermet compositions

    Science.gov (United States)

    Phillips, W. M. (Inventor)

    1976-01-01

    Cermet compositions are designed to provide high temperature resistant refractory coatings on stainless steel or molybdenum substrates. A ceramic mixture of chromium oxide and aluminum oxide form a coating of chromium oxide as an oxidation barrier around the metal particles, to provide oxidation resistance for the metal particles.

  8. Propriedades reométricas e mecânicas e morfologia de compósitos desenvolvidos com resíduos elastoméricos vulcanizados Cure characteristics, mechanical properties and morphology of composites developed with addition of elastomeric vulcanized ground scraps

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    Aline Zanchet

    2007-03-01

    Full Text Available Uma alternativa para as empresas geradoras de resíduos elastoméricos é a incorporação dos mesmos em suas formulações. Esse trabalho tem como objetivo preparar compósitos a partir da incorporação de resíduos industriais de SBR (copolímero de butadieno-estireno e de EPDM (terpolímero de etileno-propileno-dieno, em formulação ASTM específica para cada tipo de elastômero. Foram avaliadas as propriedades reométricas, mecânicas e morfológicas dos compósitos desenvolvidos. A incorporação do resíduo permitiu a obtenção de produtos que vulcanizam em menores tempos quando comparados a composições sem resíduo. A quantidade de resíduo, para o melhor resultado de resistência à tração foi de 37 e de 196 phr para os compósitos com SBR e EPDM, respectivamente. As micrografias de MEV corroboraram os resultados mecânicos dessas composições, indicando melhor homogeneidade do resíduo na respectiva matriz elastomérica.One alternative for elastomeric scraps generation is its incorporation in conventional formulations in the industry itself. In this work, compositions with incorporation of SBR (styrene butadiene rubber and EPDM (ethylene propylene diene rubber industrial scraps, in specific ASTM formulation for each elastomer, were prepared. Rheometric characteristics, mechanical properties and the morphology of the compounds developed were evaluated. With the ground scraps incorporation the vulcanization time decreases, comparing with compounds without ground scraps. The amount of scraps for the best tensile strength properties was 37 and 196 phr for SBR and EPDM compositions, respectively. Micrographs corroborated the mechanical results, indicating the best homogeneity of the scraps in the elastomeric matrix for these compositions.

  9. Thermal stability of the elastomeric anti-trauma pad

    Directory of Open Access Journals (Sweden)

    Olszewska Karolina

    2017-06-01

    Full Text Available The elastomeric anti-trauma pad (EA-TP based on shear thickening fluid (STF has been developed. Dynamic oscillatory shear experiment was conducted at constant strain amplitude of 5%. STF composed of 25% of volume fraction of 7 nm Fumed Silica, dispersed in polypropylene glycol with molar mass 400 gmol−1 shows elastic properties in entire investigated range of the frequency. Ballistic tests of EA-TP with 7.62 mm × 39 mm PS bullets were performed according to the PN-V-87000:2011 standard. The studies revealed about 60% reduction of the average backface signature depth (BSD for the EA-TP, when compared to the nowadays commonly used soft insert. The ATR-FTIR analysis confirmed slight impact of the elevated temperature and air (oxygen on the chemical degradation of the EA-TP surface. The UV-VIS spectroscopy has allowed to notice colour deviation of the aged samples towards green and yellow, as well as lack of dye resistance to accelerated aging process. Thermographic analysis has shown no visible changes of the EA-TP surface and sub-surface during accelerated aging process. The aforementioned small changes on the surface of EA-TP did not affect the ballistic properties of composite armour. EA-TP insert maintains ballistic properties after accelerated aging process which was simulating the period of 6 years according to ASTM F1980 – 07:2002 standard.

  10. Shock resistance of composite material pipes

    International Nuclear Information System (INIS)

    Pays, M.F.

    1995-01-01

    Composite materials have found a wide range of applications for EDF nuclear plants. Applications include fire pipework, demineralized water, service water, and emergency-supplied service water piping. Some of those pipework is classified nuclear safety, their integrity (resistance to water aging and earthquakes or accidental excess pressure (water hammer)) must be safeguarded. As composite materials generally suffer damage for low energy impacts (under 10 J), the pipes planned for the Civaux power plant have been studied for their resistance to a low speed shock (0 to 50 m/s) and of a 0 to 110 J energy level. For three representative diameters (20, 150, 600 mm), the minimum impact energy that leads to a leak has been determined to be respectively 18, 20 and 48 J. Then the leak rate versus impact energy was plotted; until roughly 90 J, the leak rate remains stable at less than 25 cm 3 /h and raises to higher values (300 cm 3 /h) afterwards. The level of leakage in the range of impact energy tested always stays within the limits set by the Safety Authorities for metallic pipes. These results have been linked to destructive examinations, to clarify the damage mechanisms. Other tests are still ongoing to follow the evolution of the damage and of the leak rate while the pipe is maintained under service pressure during one year

  11. Current voltage characteristics of composite superconductors with high contact resistance

    International Nuclear Information System (INIS)

    Akhmetov, A.A.; Baev, V.P.

    1984-01-01

    An experimental study has been made of current-voltage characteristics of composite superconductors with contact resistance between superconducting filaments and normal metal with high electrical conductivity. It is shown that stable resistive states exist in such conductors over a wide range of currents. The presence of resistive states is interpreted in terms of the resistive domain concept. The minimum and maximum currents of resistive states are found to be dependent on the electrical resistance of normal metal and magnetic field. (author)

  12. Chemical Stability of Telavancin in Elastomeric Pumps☆

    Science.gov (United States)

    Sand, Patrick; Aladeen, Traci; Kirkegaard, Paul; LaChance, Dennis; Slover, Christine

    2015-01-01

    Background VIBATIV is a once-daily, injectable lipoglycopeptide antibiotic approved in the U.S. for the treatment of hospital-acquired and ventilator-associated bacterial pneumonia (HABP/VABP) caused by susceptible isolates of Staphylococcus aureus when alternative treatments are not suitable. In addition, VIBATIV is approved in the U.S. for the treatment of adult patients with complicated skin & skin structure infections (cSSSI) caused by susceptible isolates of Gram-positive bacteria, including Staphylococcus aureus, both methicillin-susceptible (MSSA) and methicillin-resistant (MRSA) strains. Objective To evaluate the chemical stability of telavancin (Vibativ; Theravance Biopharma US, Inc, Northbrook, Illinois), a lipoglycopeptide antibiotic with activity against methicillin-resistant Staphylococcus aureus, in 2 types of elastomeric pumps, the Intermate Infusion System (Baxter International Inc) and the Homepump Eclipse (I-Flow Corporation). Methods Different sizes of the Baxter (Ontario, Canada) (105 mL and 275 mL) and I-Flow (Stoughton, Massachusetts) (100 mL and 250 mL) pumps were compared with glass controls. The telavancin drug product was reconstituted and diluted to concentrations of 0.6 mg/mL and 8.0 mg/mL using either 0.9% saline, 5% dextrose in water, or sterilized water for injection (0.6 mg/mL telavancin) or saline (8.0 mg/mL telavancin) followed by Ringer’s Lactate solution. Pumps were filled and stored at 2°C to 8°C, protected from light. Aliquots from both pump types and for all telavancin reconstitution/dilution schemes and concentrations were taken over a period of 8 days and analyzed for appearance, pH, telavancin concentration and purity, and degradation products. Results The pH of all pump solutions remained consistent throughout the 8-day analysis period, within a range of 4.6 to 5.7 for the 0.6 mg/mL and 4.4 to 4.9 for the 8.0 mg/mL telavancin solutions. There was no significant change in the chromatographic purity for any of the pump

  13. Chemical Stability of Telavancin in Elastomeric Pumps.

    Science.gov (United States)

    Sand, Patrick; Aladeen, Traci; Kirkegaard, Paul; LaChance, Dennis; Slover, Christine

    2015-12-01

    VIBATIV is a once-daily, injectable lipoglycopeptide antibiotic approved in the U.S. for the treatment of hospital-acquired and ventilator-associated bacterial pneumonia (HABP/VABP) caused by susceptible isolates of Staphylococcus aureus when alternative treatments are not suitable. In addition, VIBATIV is approved in the U.S. for the treatment of adult patients with complicated skin & skin structure infections (cSSSI) caused by susceptible isolates of Gram-positive bacteria, including Staphylococcus aureus, both methicillin-susceptible (MSSA) and methicillin-resistant (MRSA) strains. To evaluate the chemical stability of telavancin (Vibativ; Theravance Biopharma US, Inc, Northbrook, Illinois), a lipoglycopeptide antibiotic with activity against methicillin-resistant Staphylococcus aureus, in 2 types of elastomeric pumps, the Intermate Infusion System (Baxter International Inc) and the Homepump Eclipse (I-Flow Corporation). Different sizes of the Baxter (Ontario, Canada) (105 mL and 275 mL) and I-Flow (Stoughton, Massachusetts) (100 mL and 250 mL) pumps were compared with glass controls. The telavancin drug product was reconstituted and diluted to concentrations of 0.6 mg/mL and 8.0 mg/mL using either 0.9% saline, 5% dextrose in water, or sterilized water for injection (0.6 mg/mL telavancin) or saline (8.0 mg/mL telavancin) followed by Ringer's Lactate solution. Pumps were filled and stored at 2°C to 8°C, protected from light. Aliquots from both pump types and for all telavancin reconstitution/dilution schemes and concentrations were taken over a period of 8 days and analyzed for appearance, pH, telavancin concentration and purity, and degradation products. The pH of all pump solutions remained consistent throughout the 8-day analysis period, within a range of 4.6 to 5.7 for the 0.6 mg/mL and 4.4 to 4.9 for the 8.0 mg/mL telavancin solutions. There was no significant change in the chromatographic purity for any of the pump solutions examined. All decreases in

  14. New approach to obtain elastomeric nano composites with clay from lattices;Nova metodologia para obtencao de nanocompositos elastomericos a partir de laticas comerciais e argila

    Energy Technology Data Exchange (ETDEWEB)

    Azeredo, Luciane K. de; Jacobi, Marly M., E-mail: jacobi@iq.ufrgs.b [Universidade Federal do Rio Grande do Sul (IQ/UFRGS), Porto Alegre, RS (Brazil). Inst. de Quimica. Programa de Pos-Graduacao em Materiais; Schuster, Robert H. [Deutches Institut fuer Kautschuktechnologie (DIK), Hannover (Germany)

    2009-07-01

    Rubber-Montmorillonite nanocomposites were prepared by Continuous Dynamic Latex Compounding (CDLC). This technique, recently developed in our laboratory, permits an intensive intercalation of the polymer at very small residence times in an elongational flow reactor. The processing conditions strongly affect the morphology of nanocomposites characterized by TEM and XRD. Clay-rubber nanocomposites were prepared from the mixture of NBR-, XNBR- and SBR-latex and aqueous suspensions of Na-montmorillonite. The polarity of rubbers influences the final properties of nanocomposites. The nanocomposites obtained by CDLC showed better reinforcement and permeation resistance at far less volume fractions than the obtained with carbon black or silica by conventional methods. (author)

  15. Improving subcritical crack growth resistance for alumina glass dental composite

    NARCIS (Netherlands)

    Zhu, Q.; With, de G.

    2005-01-01

    The improvement of subcritical crack growth (SCG) resistance for alumina glass dental composites was explored in this study. The addition of nitrogen to the glass phases in the composite was found to increase the SCG resistance, where the SCG exponent n increases from 22 for the oxide glass

  16. Flame-Resistant Composite Materials For Structural Members

    Science.gov (United States)

    Spears, Richard K.

    1995-01-01

    Matrix-fiber composite materials developed for structural members occasionally exposed to hot, corrosive gases. Integral ceramic fabric surface layer essential for resistance to flames and chemicals. Endures high temperature, impedes flame from penetrating to interior, inhibits diffusion of oxygen to interior where it degrades matrix resin, resists attack by chemicals, helps resist erosion, and provides additional strength. In original intended application, composite members replace steel structural members of rocket-launching structures that deteriorate under combined influences of atmosphere, spilled propellants, and rocket exhaust. Composites also attractive for other applications in which corrosion- and fire-resistant structural members needed.

  17. Development of a flameproof elastic elastomeric fiber

    Science.gov (United States)

    Howarth, J. T.; Nilgrom, J.; Massucco, A.; Sheth, S. G.; Dawn, F. S.

    1971-01-01

    Various flexible polyurethane structures containing halogen were synthesized from polyesters derived from aliphatic or aromatic polyols and dibasic acids. Aliphatic halide structures could not be used because they are unstable at the required reaction temperatures, giving of hydrogen halide which hydrolyzes the ester linkages. In contract, halogen-containing aromatic polyols were stable and satisfactory products were made. The most promising composition, a brominated neopentyl glycol capped with toluene disocyanate, was used as a conventional diisocyanate, in conjunction with hydroxy-terminated polyethers or polyesters to form elastomeric urethanes containing about 10% bromine with weight. Products made in this manner will not burn in air, have an oxygen index value of about 25, and have tensile strength values of about 5,000 psi at 450% elongation. The most efficient additives for imparting flame retardancy to Spandex urethanes are aromatic halides and the most effective of these are the bromide compounds. Various levels of flame retardancy have been achieved depending on the levels of additives used.

  18. Development of radiation resistant organic composites for cryogenic use

    International Nuclear Information System (INIS)

    Nishijima, S.

    1997-01-01

    The mechanism of the radiation induced degradation of the mechanical properties in composite materials have been studied and based on the mechanism the radiation resistant organic composites for fusion magnet have been developing. It was found that the degradation was brought by the change of the fracture mode from tensile (or flexural) to shear failure. Consequently the intrinsic parameter which control the degradation was concluded to be the interlaminar shear strength. To develop the radiation resistant composites, therefore, means to develop the composites showing the radiation resistant interlaminar shear strength. The mechanism was confirmed using three dimensional fabric reinforced plastics which do not have the interlaminar area. The roles of matrix in the composites were also revealed. The effects of dose quality and irradiated temperature on the radiation induced degradation were also discussed and the selection standards of the components for radiation resistant composites were proposed

  19. Fabrication of elastomeric silk fibers.

    Science.gov (United States)

    Bradner, Sarah A; Partlow, Benjamin P; Cebe, Peggy; Omenetto, Fiorenzo G; Kaplan, David L

    2017-09-01

    Methods to generate fibers from hydrogels, with control over mechanical properties, fiber diameter, and crystallinity, while retaining cytocompatibility and degradability, would expand options for biomaterials. Here, we exploited features of silk fibroin protein for the formation of tunable silk hydrogel fibers. The biological, chemical, and morphological features inherent to silk were combined with elastomeric properties gained through enzymatic crosslinking of the protein. Postprocessing via methanol and autoclaving provided tunable control of fiber features. Mechanical, optical, and chemical analyses demonstrated control of fiber properties by exploiting the physical cross-links, and generating double network hydrogels consisting of chemical and physical cross-links. Structure and chemical analyses revealed crystallinity from 30 to 50%, modulus from 0.5 to 4 MPa, and ultimate strength 1-5 MPa depending on the processing method. Fabrication and postprocessing combined provided fibers with extensibility from 100 to 400% ultimate strain. Fibers strained to 100% exhibited fourth order birefringence, revealing macroscopic orientation driven by chain mobility. The physical cross-links were influenced in part by the drying rate of fabricated materials, where bound water, packing density, and microstructural homogeneity influenced cross-linking efficiency. The ability to generate robust and versatile hydrogel microfibers is desirable for bottom-up assembly of biological tissues and for broader biomaterial applications. © 2017 Wiley Periodicals, Inc.

  20. Magnetoactive elastomeric composites: Cure, tensile, electrical and ...

    Indian Academy of Sciences (India)

    M/s Godrej Soap Ltd, India. N-(1,3-dimethylbutyl)-N-phenyl-P-phenylenediamene M/s Bayer India. 1,2-Dihydro-2,2,4-trimethyl quinoline. M/s Bayer India. Carbon black, FEF N 550. M/s Philips Carbon Black Ltd, Kochi. Carbon black, HAF N 330. M/s Philips Carbon Black Ltd, Kochi. Lead oxide (red lead). M/s Glaxo, Mumbai.

  1. High temperature resistant cermet and ceramic compositions. [for thermal resistant insulators and refractory coatings

    Science.gov (United States)

    Phillips, W. M. (Inventor)

    1978-01-01

    High temperature oxidation resistance, high hardness and high abrasion and wear resistance are properties of cermet compositions particularly to provide high temperature resistant refractory coatings on metal substrates, for use as electrical insulation seals for thermionic converters. The compositions comprise a sintered body of particles of a high temperature resistant metal or metal alloy, preferably molybdenum or tungsten particles, dispersed in and bonded to a solid solution formed of aluminum oxide and silicon nitride, and particularly a ternary solid solution formed of a mixture of aluminum oxide, silicon nitride and aluminum nitride. Ceramic compositions comprising a sintered solid solution of aluminum oxide, silicon nitride and aluminum nitride are also described.

  2. Evaluation of Force Degradation Pattern of Elastomeric Ligatures and Elastomeric Separators in Active Tieback State

    Directory of Open Access Journals (Sweden)

    Amir Mohammadi

    2015-12-01

    Full Text Available Background and aims. The purpose of this study was to evaluate initial force and force decay of commercially available elastomeric ligatures and elastomeric separators in active tieback state in a simulated oral environment. Materials and methods. A total of 288 elastomeric ligatures and elastomeric separators from three manufacturers (Dentaurum, RMO, 3M Unitek were stretched to 100% and 150% of their original inner diameter. Force levels were measured initially and at 3-minute, 24-hour, and 1-, 2-, 3- and 4-week intervals. Data were analyzed by univariate analysis of variance and a post hoc Tukey test. Results. The means of initial forces of elastomeric ligatures and separators from three above-mentioned companies, when stretched to 100% of their inner diameters, were 199, 305 and 284 g, and 330, 416, 330 g; when they were stretched to 150% of their inner diameters the values were 286, 422 and 375 g, and 433, 540 and 504 g, respectively. In active tieback state, 11‒18% of the initial force of the specimens was lost within the first 3 minutes and 29‒63% of the force decay occurred in the first 24 hours; then force decay rate decreased. 62‒81% of the initial force was lost in 4 weeks. Although force decay pattern was identical in all the products, the initial force and force decay of Dentaurum elastomeric products were less than the similar products of other companies (P<0.05. Under the same conditions, the force of elastomeric separators was greater than elastomeric ligatures of the same company. Conclusion. Regarding the force pattern of elastomeric ligatures and separators and optimal force for tooth movement, many of these products can be selected for applying orthodontic forces in active tieback state.

  3. Study on the heat-resistant EB curing composites

    International Nuclear Information System (INIS)

    Bao Jianwen; Li Yang; Li Fengmei

    2000-01-01

    There are many advantages in the EB-curing process of composites. Heat-resistant EB-curing composites could substitute for polyimide composites used in aeronautical engine. The effects of catalyst and dose on the cured resin were investigated. The heat-resistance of the resin cured by EB was evaluated by dynamic mechanical thermal analysis (DMTA). The experiment result shows that the mechanical property of the composites cured by EB could meet the needs of the aeronautical engine in 250degC. (author)

  4. Is static friction affected by aging and amount of elastomeric ligatures in orthodontic sliding mechanics? An in-vitro investigation.

    Science.gov (United States)

    Lo Giudice, A; Portelli, M; Militi, A; Spinuzza, P; Bellocchio, A M; Nucera, R; Marcolina, M; Ghilardi, G; Manuelli, M; Lucchese, A

    2018-03-15

    In straight-wire mechanics, friction can significantly influence the forces expressed by wires. The aim of this study is to assess whether the aging and the sum of elastomeric ligatures affect the static friction during orthodontic space closure. A 0.017x 0.025-in SS was drawn throughout a 3-bracket experimental model and engaged with elastomeric ligatures. Before performing the test, the ligatures were soaked in artificial saliva for 48 hours (Group 1), 2 weeks (Group 2) and 4 weeks (Group 3); brand-new ligatures were also tested as control group (Group 4). The resistance to sliding (RS) was recorded at 3 different numerical configurations of ligatures using a customized testing machine and tests were repeated for ten times. Data of RS were statistically analysed by using two way analysis of variance (ANOVA) and Tukey’s multiple comparison tests. RS was found to increase systematically when more elastomeric ligatures were included in the wire engaging system. At two weeks of immersion in artificial saliva elastomeric ligatures showed the lowest values of RS while they became significantly more frictional after immersion for 4 weeks. The results of this study showed that in multi-bracket orthodontic therapy, the RS increases with the number of elastomeric ligatures involved for arch-wire engagement. Differently from the frictional behavior of elastomeric modules, the aging of these ligatures does not influence their incremental effect of frictional forces.

  5. Effect of composition on the polarization and ohmic resistances of ...

    Indian Academy of Sciences (India)

    2017-06-09

    Jun 9, 2017 ... Solid oxide fuel cell; composite cathodes; polarization resistance; ohmic resistance; ... of Oad on LSM, (iii) conversion of Oad into oxygen ion ... ions need to flow through the low temperature sintered ..... TPB's are present) suggest the formation of face-to-face con- ..... calculated using the following equation.

  6. Chemical Stability of Telavancin in Elastomeric Pumps

    Directory of Open Access Journals (Sweden)

    Patrick Sand, MSc

    2015-12-01

    Conclusions: The results of this study indicate that telavancin remains chemically stable when diluted in the Intermate Infusion System and the Homepump Eclipse elastomeric pumps and stored at 2°C to 8°C for up to 8 days protected from light at the concentration range and dilution schemes evaluated.

  7. Tribologically modified surfaces on elastomeric materials

    NARCIS (Netherlands)

    Rodriguez, N.V.; Masen, Marc Arthur; Schipper, Dirk J.

    2013-01-01

    As the result of tribological loading, the properties of the surface of elastomeric materials will alter. This effect has been observed using SEM and EDS analysis of the tread of a used car tyre, where differences in structure between the substrate and the area near the surface were found. To study

  8. Biodegradable elastomeric scaffolds for soft tissue engineering

    NARCIS (Netherlands)

    Pêgo, A.P.; Poot, Andreas A.; Grijpma, Dirk W.; Feijen, Jan

    2003-01-01

    Elastomeric copolymers of 1,3-trimethylene carbonate (TMC) and ε-caprolactone (CL) and copolymers of TMC and D,L-lactide (DLLA) have been evaluated as candidate materials for the preparation of biodegradable scaffolds for soft tissue engineering. TMC-DLLA copolymers are amorphous and degrade more

  9. Investigation on low velocity impact resistance of SMA composite material

    Science.gov (United States)

    Hu, Dianyin; Zhang, Long; Wang, Rongqiao; Zhang, Xiaoyong

    2016-04-01

    A method to improve low velocity impact resistance of aeroengine composite casing using shape memory alloy's properties of shape memory(SM) and super-elasticity(SE) is proposed in this study. Firstly, a numerical modeling of SMA reinforced composite laminate under low velocity impact load with impact velocity of 10 m/s is established based on its constitutive model implemented by the VUMAT subroutine of commercial software ABAQUS. Secondly, the responses of SMA composite laminate including stress and deflection distributions were achieved through transient analysis under low velocity impact load. Numerical results show that both peak stress and deflection values of SMA composite laminate are less than that without SMA, which proves that embedding SMA into the composite structure can effectively improve the low velocity impact performance of composite structure. Finally, the influence of SM and SE on low velocity impact resistance is quantitatively investigated. The values of peak stress and deflection of SMA composite based on SM property decrease by 18.28% and 9.43% respectively, compared with those without SMA, instead of 12.87% and 5.19% based on SE. In conclusion, this proposed model described the impact damage of SMA composite structure and turned to be a more beneficial method to enhance the impact resistance by utilizing SM effect.

  10. Influence of resistive matrices on the stability of superconducting composites

    International Nuclear Information System (INIS)

    Maccioni, P.

    1990-03-01

    Stability of superconducting composites is governed by limiting the temperature rise in conductors submitted to disturbances. Cooling exchange enhancement and reduction of the composite mean resistivity in the normal state, introducing a sufficient amount of copper, are the main ways to ensure stabilization. Nevertheless some losses occur in composites exposed to time varying fields because of induced currents between the filaments and circulating through the matrix. These currents have to be reduced to a convenient level by increasing the matrix resistivity by means of resistive barriers of greater resistivity than copper. It is necessary to study how the existence of these barriers affects the composite stability and whether an improved arrangement may lead to the fulfillment of the required conditions e.g: stability and low losses. The original theoretical approaches allow some existing models to be completed, to evaluate additional energy dissipation, inherent in current transfer through resistive barriers, and to compare the performance of two different conductor concepts from the cryostability point of view. Numerical simulations -performed by means of a finite element code- are in quite good agreement with theoretical predictions and link up with experimental results. The influence of resistive matrix and barriers on stability degradation is clearly demonstrated by the comparison between various kinds of conductors [fr

  11. Irradiatable polymer composition with improved oxidation resistance

    International Nuclear Information System (INIS)

    Lyons, B.J.

    1977-01-01

    A method is described for the incorporation of a substantially insoluble organic phosphite into a polymer composition such as polyolefin polymers or ethylene copolymers to prevent oxidation of the polymer at elevated temperatures after radiation-induced crosslinking. The crosslinking is readily achieved without affecting the antioxidant properties of the organic phosphite. Particularly suitable organic compounds are derivatives of pentaerythritol, dipentaerythritol, and tripentaerythritol in cooncentrations of 1 to 3% of the mixture to be irradiated

  12. Wear and impact resistance of HVOF sprayedceramic matrix composites coating

    Science.gov (United States)

    Prawara, B.; Martides, E.; Priyono, B.; Ardy, H.; Rikardo, N.

    2016-02-01

    Ceramic coating has the mechanical properties of high hardness and it is well known for application on wear resistance, but on the other hand the resistance to impact load is low. Therefore its use is limited to applications that have no impact loading. The aim of this research was to obtain ceramic-metallic composite coating which has improved impact resistance compared to conventional ceramic coating. The high impact resistance of ceramic-metallic composite coating is obtained from dispersed metallic alloy phase in ceramic matrix. Ceramic Matrix Composites (CMC) powder with chrome carbide (Cr3C2) base and ceramic-metal NiAl-Al2O3 with various particle sizes as reinforced particle was deposited on mild steel substrate with High Velocity Oxygen Fuel (HVOF) thermal spray coating. Repeated impact test showed that reinforced metallic phase size influenced impact resistance of CMC coating. The ability of CMC coating to absorb impact energy has improved eight times and ten times compared with original Cr3C2 and hard chrome plating respectively. On the other hand the high temperature corrosion resistance of CMC coating showed up to 31 cycles of heating at 800°C and water quenching cooling.

  13. Common bunt resistant wheat composite cross populations

    DEFF Research Database (Denmark)

    Steffan, Philipp Matthias; Borgen, A.; Backes, Gunter Martin

    stability. However, a number of challenges must be met before diverse wheat populations can be introduced into commercial wheat production: one of these is the development of breeding technologies based on mass selection which enable breeders and farmers to improve specific traits in populations...... and maintain diversity at the same time. BIOBREED is a project which commenced in Denmark in 2011 to meet these challenges for wheat population breeding. The project focuses on the development of tools and methods for mass selection of traits relevant for organic and low input production, where it is expected...... that the highest benefits of utilizing diverse populations can be achieved. BIOBREED focuses on three main aspects of wheat population breeding for organic and low input production systems: i) common bunt (caused by Tilletia caries) resistance, ii) selection for improved protein content and iii) the influence...

  14. Tensile properties of orthodontic elastomeric ligatures.

    Science.gov (United States)

    Ahrari, F; Jalaly, T; Zebarjad, M

    2010-01-01

    Tensile properties of elastomeric ligatures become important when efficiency of orthodontic appliances is considered. The aim of this study was to compare tensile strength, extension to tensile strength, toughness and modulus of elasticity of elastomeric ligatures in both the as--received condition and after 28 days of immersion in the simulated oral environment. Furthermore, the changes that occurred in tensile properties of each brand of ligatures after 28 days were evaluated. Experimental-laboratory based. Elastomeric ligatures were obtained from different companies and their tensile properties were measured using Zwick testing machine in both the as-received condition and after 28 days of immersion in the simulated oral environment. The data were analyzed using independent sample t-tests, analysis of variance and Tukey tests. After 28 days, all the ligatures experienced a significant decrease in tensile strength, extension to tensile strength and toughness ( P tensile properties of different brands of ligatures in both conditions ( P tensile properties of different brands of ligatures, which should be considered during selection of these products.

  15. Model for the resistive critical current transition in composite superconductors

    International Nuclear Information System (INIS)

    Warnes, W.H.

    1988-01-01

    Much of the research investigating technological type-II superconducting composites relies on the measurement of the resistive critical current transition. We have developed a model for the resistive transition which improves on older models by allowing for the very different nature of monofilamentary and multifilamentary composite structures. The monofilamentary model allows for axial current flow around critical current weak links in the superconducting filament. The multifilamentary model incorporates an additional radial current transfer between neighboring filaments. The development of both models is presented. It is shown that the models are useful for extracting more information from the experimental data than was formerly possible. Specific information obtainable from the experimental voltage-current characteristic includes the distribution of critical currents in the composite, the average critical current of the distribution, the range of critical currents in the composite, the field and temperature dependence of the distribution, and the fraction of the composite dissipating energy in flux flow at any current. This additional information about the distribution of critical currents may be helpful in leading toward a better understanding of flux pinning in technological superconductors. Comparison of the models with several experiments is given and shown to be in reasonable agreement. Implications of the models for the measurement of critical currents in technological composites is presented and discussed with reference to basic flux pinning studies in such composites

  16. Laboratory tests on fungal resistance of wood filled polyethylene composites

    Science.gov (United States)

    Craig M. Clemons; Rebecca E. Ibach

    2002-01-01

    A standard method for determining the durability of structural wood was modified for testing the fungal resistance of composites made from high density polyethylene filled with 50% wood flour. Moisture content, mechanical properties, and weight loss were measured over 12 weeks exposure to brown-and white-rot fungi. Mechanical properties were decreased, but irreversible...

  17. Radiation resistant organic composites for superconducting fusion magnets

    International Nuclear Information System (INIS)

    Nishijima, S.; Okada, T.

    1993-01-01

    Organic composite materials (usually reinforced by glas fibers: GFRP) are to be used in fusion superconducting magnets as insulating and/or structural materials. The fusion superconducting magnets are operated under radiation environments and hence the radiation induced degradation of magnet components is ought to be estimated. Among the components the organic composite materials were evaluated to be the most radiation sensitive. Consequently the development of radiation resistant organic composite materials is thought one of the 'key' technologies for fusion superconducting magnets. The mechanism of radiation-induced degradation was studied and the degradation of interlaminar shear strength (ILSS) was found to be the intrinsic phenomenon which controlled the overall degradation of organic composite materials. The degradation of ILSS was studied changing matrix resin, reinforcement and type of fabrics. The possible combination of the organic composites for the fusion superconducting magnet will be discussed. (orig.)

  18. Electrodeposition and Corrosion Resistance of Ni-Graphene Composite Coatings

    Science.gov (United States)

    Szeptycka, Benigna; Gajewska-Midzialek, Anna; Babul, Tomasz

    2016-08-01

    The research on the graphene application for the electrodeposition of nickel composite coatings was conducted. The study assessed an important role of graphene in an increased corrosion resistance of these coatings. Watts-type nickel plating bath with low concentration of nickel ions, organic addition agents, and graphene as dispersed particles were used for deposition of the composite coatings nickel-graphene. The results of investigations of composite coatings nickel-graphene deposited from the bath containing 0.33, 0.5, and 1 g/dm3 graphene and one surface-active substance were shown. The contents of particles in coatings, the surface morphology, the cross-sectional structures of the coated samples, and their thickness and the internal stresses were studied. Voltammetric method was used for examination of the corrosion resistance of samples of composite coatings in 0.5 M NaCl. The obtained results suggest that the content of incorporated graphene particles increases with an increasing amount of graphene in plating bath. The application of organic compounds was advantageous because it caused compressive stresses in the deposited coatings. All of the nickel-graphene composite layers had better corrosion resistance than the nickel coating.

  19. Wear resistance and fracture mechanics of WC-Co composites

    International Nuclear Information System (INIS)

    Kaytbay, Saleh; El-Hadek, Medhat

    2014-01-01

    Manufacturing of WC-Co composites using the electroless precipitation method at different sintering temperatures of 1 100, 1 250, 1 350 and 1 500 C was successfully achieved. The chemical composition of the investigated materials was 90 wt.% WC with 10 wt.% Co, and 80 wt.% WC with 20 wt.% Co. The specific density, densification, and Vickers microhardness measurements were found to increase with increased sintering temperature for both the WC-Co compositions. The composites of tungsten carbide with 10 wt.% Co had a higher specific density and Vickers microhardness measurements than those for the composites of tungsten carbide with 20 wt.% Co. Composites with WC-10 wt.% Co had better wear resistance. The stress-strain and transverse rupture strength increased monotonically with the increase in sintering temperatures, agreeing with the material hardness and wear resistance behavior. Fractographical scanning electron microscopy analysis of the fracture surface demonstrated a rough characteristic conical shape failure in the direction of the maximum shear stress. A proposed mechanism for the formation of the conical fracture surface under compression testing is presented. (orig.)

  20. Shape memory-based tunable resistivity of polymer composites

    Energy Technology Data Exchange (ETDEWEB)

    Luo, Hongsheng, E-mail: hongshengluo@163.com [Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006 (China); Zhou, Xingdong; Ma, Yuanyuan [Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006 (China); Yi, Guobin, E-mail: ygb116@163.com [Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006 (China); Cheng, Xiaoling [Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006 (China); Zhu, Yong [Shanghai Hiend Polyurethane Inc., No. 389, Jinshan District, Shanghai (China); Zu, Xihong; Zhang, Nanjun; Huang, Binghao; Yu, Lifang [Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006 (China)

    2016-02-15

    Graphical abstract: Hybrid nanofillers of the CNTs and AgNPs were embedded into a shape memory polyurethane. The composites exhibited tunable conduction, which could be facially tailored by the compositions and the thermal–mechanical programming. - Highlights: • Electrically conductive polymer composites in bi-layer structure were fabricated. • The CNTs/AgNPs layer had influence on the mechanics and thermal transitions. • The conductivity could be facially tailored via a thermo-mechanical programming. • The AgNPs contents enlarged the gauge factor of the resistivity–strain curves. • Tunneling theory was suitable for simulating the strain-dependent behaviors. - Abstract: A conductive composite in bi-layer structure was fabricated by embedding hybrid nanofillers, namely carbon nanotubes (CNTs) and silver nanoparticles (AgNPs), into a shape memory polyurethane (SMPU). The CNT/AgNP-SMPU composites exhibited a novel tunable conductivity which could be facially tailored in wide range via the compositions or a specifically designed thermo-mechanical shape memory programming. The morphologies of the conductive fillers and the composites were investigated by scanning electron microscope (SEM). The mechanical and thermal measurements were performed by tensile tests and differential scanning calorimetry (DSC). By virtue of a specifically explored shape memory programming, the composites were stretched and fixed into different temporary states. The electrical resistivity (R{sub s}) varied accordingly, which was able to be stabilized along with the shape fixing. Theoretical prediction based upon the tunneling model was performed. The R{sub s}–strain curves of the composites with different compositions were well fitted. Furthermore, the relative resistivity and the Gauge factor along with the elongation were calculated. The influence of the compositions on the strain-dependent R{sub s} was disclosed. The findings provided a new avenue to tailor the conductivity

  1. Thermal Oxidation Resistance of Rare Earth-Containing Composite Elastomer

    Institute of Scientific and Technical Information of China (English)

    邱关明; 张明; 周兰香; 中北里志; 井上真一; 冈本弘

    2001-01-01

    The rare earth-containing composite elastomer was obtained by the reaction of vinyl pyridine-SBR (PSBR) latex with rare earth alkoxides, and its thermal oxidation resistance was studied. After aging test, it is found that its retention rate of mechanical properties is far higher than that of the control sample. The results of thermogravimetric analysis show that its thermal-decomposing temperature rises largely. The analysis of oxidation mechanisms indicates that the main reasons for thermal oxidation resistance are that rare earth elements are of the utility to discontinue autoxidation chain reaction and that the formed complex structure has steric hindrance effect on oxidation.

  2. Oxidation resistance coating for niobium base structural composites

    International Nuclear Information System (INIS)

    Tabaru, T.; Shobu, K.; Kim, J.H.; Hirai, H.; Hanada, S.

    2003-01-01

    Oxidation behavior of Al-rich Mo(Si,Al) 2 base alloys, which is a candidate material for the oxidation resistance coating on Nb base structural composites, were investigated by thermogravimetry. The Mo(Si,Al) 2 base alloys containing Mo 5 (Si,Al) 3 up to about 10 vol% exhibits excellent oxidation resistance at temperatures ranging from 780 to 1580 K, particularly at 1580 K due to continuous Al 2 O 3 layer development. To evaluate the applicability of the Mo(Si,Al) 2 base coating, plasma spraying on Nb base composites were undertaken. However, interface reaction layer was found to form during the following heat treatment. Preparation of Mo(Si,Al) 2 /Al 2 O 3 /Nb layered structures via powder metallurgical process was attempted to preclude diffusion reaction between coating and substrate. (orig.)

  3. Hydrogen isotope permeation in elastomeric materials

    International Nuclear Information System (INIS)

    Steinmeyer, R.H.; Braun, J.D.

    1976-01-01

    The permeabilities of elastomeric and polymeric materials to hydrogen isotopes were measured at room temperature. The technique for measuring permeation rates is based on the following constant-volume method: a fixed pressure of gas is applied to one side of the specimen to be studied and the permeability constant is determined from the observed rate of pressure increase in an initially evacuated volume on the other side of the specimen. Permeability constants for hydrogen, deuterium, and tritium were measured for Mylar, Teflon, Kapton, Saran, Buna-N, and latex rubber. Results were compared with literature values for hydrogen and deuterium where available and showed excellent agreement

  4. Fissure sealant materials: Wear resistance of flowable composite resins.

    Science.gov (United States)

    Asefi, Sohrab; Eskandarion, Solmaz; Hamidiaval, Shadi

    2016-01-01

    Background. Wear resistance of pit and fissure sealant materials can influence their retention. Wear characteristics of sealant materials may determine scheduling of check-up visits. The aim of this study was to compare wear resistance of two flowable composite resins with that of posterior composite resin materials. Methods. Thirty-five disk-shaped specimens were prepared in 5 groups, including two flowable composite resins (Estelite Flow Quick and Estelite Flow Quick High Flow), Filtek P90 and Filtek P60 and Tetric N-Ceram. The disk-shaped samples were prepared in 25-mm diameter by packing them into a two-piece aluminum mold and then light-cured. All the specimens were polished for 1minute using 600-grit sand paper. The samples were stored in distilled water at room temperature for 1 week and then worn by two-body abrasion test using "pin-on-disk" method (with distilled water under a 15-Nload at 0.05 m/s, for a distance of 100 meter with Steatite ceramic balls antagonists). A Profilometer was used for evaluating the surface wear. Data were analyzed with the one-way ANOVA. Results. Estelite Flow Quick exhibited 2708.9 ± 578.1 μm(2) and Estelite Flow Quick High Flow exhibited 3206 ± 2445.1 μm(2)of wear but there were no significant differences between the groups. They demonstrated similar wear properties. Conclusion. Estelite flowable composite resins have wear resistance similar to nano- and micro-filled and micro-hybrid composite resins. Therefore, they can be recommended as pit and fissure sealant materials in the posterior region with appropriate mechanical characteristics.

  5. Wear resistance of polypropylene-SiC composite

    Science.gov (United States)

    Abenojar, J.; Enciso, B.; Martínez, MA; Velasco, F.

    2017-05-01

    In this work, the wear resistance of thermoplastic composites with a high amount of ceramic is evaluated. Composites made of polypropylene (PP) and silicon carbide (SiC) powder at 50 wt% were used with the final objective of manufacturing ablative materials. This is the first part of a project studying the wear resistance and the mechanical properties of those composites, to be used in applications like habitat industry. In theory, the exposure to high temperature of ablative materials involves the elimination of thermal energy by the sacrifice of surface polymer. In our case, PP will act as a heat sink, up to the reaction temperature (melting or sublimation), where endothermic chemical decomposition into charred material and gaseous products occurs. As the surface is eroded, it is formed a SiC like-foam with improved insulation performance. Composites were produced by extrusion and hot compression. The wear characterization was performed by pin-on-disk test. Wear test was carried out under standard ASTM G99. The parameters were 120 rpm speed, 15 N load, a alumina ball with 6 mm as pin and 1000 m sliding distance. The tracks were also observed by opto-digital microscope.

  6. Wear resistance of polypropylene-SiC composite

    International Nuclear Information System (INIS)

    Abenojar, J; Enciso, B; Martínez, MA; Velasco, F

    2017-01-01

    In this work, the wear resistance of thermoplastic composites with a high amount of ceramic is evaluated. Composites made of polypropylene (PP) and silicon carbide (SiC) powder at 50 wt% were used with the final objective of manufacturing ablative materials. This is the first part of a project studying the wear resistance and the mechanical properties of those composites, to be used in applications like habitat industry. In theory, the exposure to high temperature of ablative materials involves the elimination of thermal energy by the sacrifice of surface polymer. In our case, PP will act as a heat sink, up to the reaction temperature (melting or sublimation), where endothermic chemical decomposition into charred material and gaseous products occurs. As the surface is eroded, it is formed a SiC like-foam with improved insulation performance. Composites were produced by extrusion and hot compression. The wear characterization was performed by pin-on-disk test. Wear test was carried out under standard ASTM G99. The parameters were 120 rpm speed, 15 N load, a alumina ball with 6 mm as pin and 1000 m sliding distance. The tracks were also observed by opto-digital microscope. (paper)

  7. Fabrication of an Electrically-Resistive, Varistor-Polymer Composite

    Directory of Open Access Journals (Sweden)

    Sanaz A. Mohammadi

    2012-11-01

    Full Text Available This study focuses on the fabrication and electrical characterization of a polymer composite based on nano-sized varistor powder. The polymer composite was fabricated by the melt-blending method. The developed nano-composite was characterized by X-ray diffraction (XRD, transmission electron microscopy (TEM, field emission scanning electron microscopy (FeSEM, and energy-dispersive X-ray spectroscopy (EDAX. The XRD pattern revealed the crystallinity of the composite. The XRD study also showed the presence of secondary phases due to the substitution of zinc by other cations, such as bismuth and manganese. The TEM picture of the sample revealed the distribution of the spherical, nano-sized, filler particles throughout the matrix, which were in the 10–50 nm range with an average of approximately 11 nm. The presence of a bismuth-rich phase and a ZnO matrix phase in the ZnO-based varistor powder was confirmed by FeSEM images and EDX spectra. From the current-voltage curves, the non-linear coefficient of the varistor polymer composite with 70 wt% of nano filler was 3.57, and its electrical resistivity after the onset point was 861 KΩ. The non-linear coefficient was 1.11 in the sample with 100 wt% polymer content. Thus, it was concluded that the composites established a better electrical non-linearity at higher filler amounts due to the nano-metric structure and closer particle linkages.

  8. Evaluation of shear mounted elastomeric damper

    Science.gov (United States)

    Zorzi, E.; Walton, J.

    1982-01-01

    Viton-70 elastomeric shear mounted damper was built and tested on a T-55 power turbine spool in the rotor's high speed balancing rig. This application of a shear mounted elastomeric damper demonstrated for the first time, the feasibility of using elastomers as the primary rotor damping source in production turbine engine hardware. The shear damper design was selected because it was compatible with actual gas turbine engine radial space constraints, could accommodate both the radial and axial thrust loads present in gas turbine engines, and was capable of controlled axial preload. The shear damper was interchangeable with the production T-55 power turbine roller bearing support so that a direct comparison between the shear damper and the production support structure could be made. Test results show that the Viton-70 elastomer damper operated successfully and provided excellent control of both synchronous and nonsynchronous vibrations through all phases of testing up to the maximum rotor speed of 16,000 rpm. Excellent correlation between the predicted and experienced critical speeds, mode shapes and log decrements for the power turbine rotor and elastomer damper assembly was also achieved.

  9. Investigation of the recycling of tires to elastomeric requirements by techniques of thermal compression

    Science.gov (United States)

    Nadal Gisbert, Antonio V.

    In this work is investigated the recycling of tires to elastomeric requirements by thermal compression. The production of recycled products is carried out starting from the powder, of elastomeric nature, coming from the grinding of used tires denominated GTR (Ground Tire Rubber) of different grain size, although the fundamental objective is the recycling of powder of 0,2mm grain size. The process of forming used for obtaining the recycled product is thermal compression, due to its simplicity and low cost. The composition of the powder has been analyzed and also the influence, on the elastomeric characteristics of the recycled product, of different parameters: Grain size, compact pressure, temperature, time, thickness of the recycled product and combination of sizes. At last we give an hypothesis that justifies the mechanism that gives cohesion to the powder GTR and allows their recycling. We also have carried out an analysis of the investigation lines, at the present, on the recycling of tires in general and an economic study of the viability of the recycled product in front of present products in the market, agglomerated with polyurethane, that have their application in using it in different types of floors.

  10. Metal-nanotube composites as radiation resistant materials

    Energy Technology Data Exchange (ETDEWEB)

    González, Rafael I.; Valencia, Felipe; Mella, José; Kiwi, Miguel, E-mail: m.kiwi.t@gmail.com [Departamento de Física, Facultad de Ciencias, CEDENNA, Universidad de Chile, Casilla 653, Santiago 7800024 (Chile); Duin, Adri C. T. van [Department of Mechanical and Nuclear Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802 (United States); So, Kang Pyo; Li, Ju [Department of Nuclear Science and Engineering and Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Bringa, Eduardo M. [CONICET and Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Cuyo, Mendoza 5500 (Argentina)

    2016-07-18

    The improvement of radiation resistance in nanocomposite materials is investigated by means of classical reactive molecular dynamics simulations. In particular, we study the influence of carbon nanotubes (CNTs) in an Ni matrix on the trapping and possible outgassing of He. When CNTs are defect-free, He atoms diffuse alongside CNT walls and, although there is He accumulation at the metal-CNT interface, no He trespassing of the CNT wall is observed, which is consistent with the lack of permeability of a perfect graphene sheet. However, when vacancies are introduced to mimic radiation-induced defects, He atoms penetrate CNTs, which play the role of nano-chimneys, allowing He atoms to escape the damaged zone and reduce bubble formation in the matrix. Consequently, composites made of CNTs inside metals are likely to display improved radiation resistance, particularly when radiation damage is related to swelling and He-induced embrittlement.

  11. Metal-nanotube composites as radiation resistant materials

    International Nuclear Information System (INIS)

    González, Rafael I.; Valencia, Felipe; Mella, José; Kiwi, Miguel; Duin, Adri C. T. van; So, Kang Pyo; Li, Ju; Bringa, Eduardo M.

    2016-01-01

    The improvement of radiation resistance in nanocomposite materials is investigated by means of classical reactive molecular dynamics simulations. In particular, we study the influence of carbon nanotubes (CNTs) in an Ni matrix on the trapping and possible outgassing of He. When CNTs are defect-free, He atoms diffuse alongside CNT walls and, although there is He accumulation at the metal-CNT interface, no He trespassing of the CNT wall is observed, which is consistent with the lack of permeability of a perfect graphene sheet. However, when vacancies are introduced to mimic radiation-induced defects, He atoms penetrate CNTs, which play the role of nano-chimneys, allowing He atoms to escape the damaged zone and reduce bubble formation in the matrix. Consequently, composites made of CNTs inside metals are likely to display improved radiation resistance, particularly when radiation damage is related to swelling and He-induced embrittlement.

  12. Method of making sulfur-resistant composite metal membranes

    Science.gov (United States)

    Way, J Douglas [Boulder, CO; Lusk, Mark [Golden, CO; Thoen, Paul [Littleton, CO

    2012-01-24

    The invention provides thin, hydrogen-permeable, sulfur-resistant membranes formed from palladium or palladium-alloy coatings on porous, ceramic or metal supports. Also disclosed are methods of making these membranes via sequential electroless plating techniques, wherein the method of making the membrane includes decomposing any organic ligands present on the substrate, reducing the palladium crystallites on the substrate to reduced palladium crystallites, depositing a film of palladium metal on the substrate and then depositing a second, gold film on the palladium film. These two metal films are then annealed at a temperature between about 200.degree. C. and about 1200.degree. C. to form a sulfur-resistant, composite PdAu alloy membrane.

  13. Maleimido substituted cyclotriphosphazene resins for fire and heat resistant composites

    Science.gov (United States)

    Kumar, D.; Fohlen, G. M.; Parker, J. A.

    1983-01-01

    A new class of fire- and heat-resistant matrix resins have been synthesized by the thermal polymerization of maleimido substituted phenoxycyclotriphosphazenes. The resins have exhibited a char yield of 82 percent at 800 C in nitrogen and 81 percent at 700 C in air. Graphite-fabric laminates based on a resin of this class have shown a limiting oxygen index of 100 percent even at 300 C. Details of the fabrication of the resins and the composites and testing procedures are discussed.

  14. Fracture resistance of teeth restored with packable and hybrid composites

    Directory of Open Access Journals (Sweden)

    Ghavam M

    2006-06-01

    Full Text Available Background and Aim: With recent introduction of packable composites, it is claimed that they apply less stress on tooth structure because of reduced polymerization shrinkage, and similarity of coefficient of thermal expansion to tooth structure. However, the high viscosity may in turn cause less adaptation, so it is not clearly known whether these materials strengthen tooth structure or not. The aim of this study was to evaluate fracture resistance of maxillary premolars, receiving hybrid or packable composite restorations with different methods of application and curing. Materials and Methods: In this experimental study, seventy five intact premolars were randomly assigned to five groups of 15 teeth each. One group was maintained intact as the control group. Similar MOD cavities were prepared in the other teeth. The teeth in group two were restored with Spectrum in incremental layers and light cured with 500 mw/cm2 intensity. The third group were filled with Surefil and cured with light intensity of 500 mw/cm2. The groups four and five were restored with Surefil in bulk technique with two different modes: 500 mw/cm2 intensity and a ramp mode (100-900 mw/cm2 respectively. After thermocycling, force to fracture was assessed and degree of conversion (DC at the bottom of cavities was evaluated for different modes and methods. The curing and placement methods in groups tested for DC (A to D were the same as fracture resistance groups (2 to 5. Data were analyzed using one way ANOVA and Tukey HSD tests with p<0.05 as the limit of significance. Results: All the restored groups showed significantly less fracture resistance than the control group, but had no significant difference among themselves. DC of Spectrum was higher than Surefil. Bulk method with 500 mw/cm2 light intensity, significantly decreased DC. DC in bulk method with high light intensity was not significantly different from incremental method with 500 mw/cm2 light intensity. Conclusion

  15. Laser cladding of wear resistant metal matrix composite coatings

    International Nuclear Information System (INIS)

    Yakovlev, A.; Bertrand, Ph.; Smurov, I.

    2004-01-01

    A number of coatings with wear-resistant properties as well as with a low friction coefficient are produced by laser cladding. The structure of these coatings is determined by required performance and realized as metal matrix composite (MMC), where solid lubricant serves as a ductile matrix (e.g. CuSn), reinforced by appropriate ceramic phase (e.g. WC/Co). One of the engineered coating with functionally graded material (FGM) structure has a dry friction coefficient 0.12. Coatings were produced by coaxial injection of powder blend into the zone of laser beam action. Metallographic and tribological examinations were carried out confirming the advanced performance of engineered coatings

  16. Contact angle of unset elastomeric impression materials.

    Science.gov (United States)

    Menees, Timothy S; Radhakrishnan, Rashmi; Ramp, Lance C; Burgess, John O; Lawson, Nathaniel C

    2015-10-01

    Some elastomeric impression materials are hydrophobic, and it is often necessary to take definitive impressions of teeth coated with some saliva. New hydrophilic materials have been developed. The purpose of this in vitro study was to compare contact angles of water and saliva on 7 unset elastomeric impression materials at 5 time points from the start of mixing. Two traditional polyvinyl siloxane (PVS) (Aquasil, Take 1), 2 modified PVS (Imprint 4, Panasil), a polyether (Impregum), and 2 hybrid (Identium, EXA'lence) materials were compared. Each material was flattened to 2 mm and a 5 μL drop of distilled water or saliva was dropped on the surface at 25 seconds (t0) after the start of mix. Contact angle measurements were made with a digital microscope at initial contact (t0), t1=2 seconds, t2=5 seconds, t3=50% working time, and t4=95% working time. Data were analyzed with a generalized linear mixed model analysis, and individual 1-way ANOVA and Tukey HSD post hoc tests (α=.05). For water, materials grouped into 3 categories at all time-points: the modified PVS and one hybrid material (Identium) produced the lowest contact angles, the polyether material was intermediate, and the traditional PVS materials and the other hybrid (EXA'lence) produced the highest contact angles. For saliva, Identium, Impregum, and Imprint 4 were in the group with the lowest contact angle at most time points. Modified PVS materials and one of the hybrid materials are more hydrophilic than traditional PVS materials when measured with water. Saliva behaves differently than water in contact angle measurement on unset impression material and produces a lower contact angle on polyether based materials. Copyright © 2015 Editorial Council for the Journal of Prosthetic Dentistry. Published by Elsevier Inc. All rights reserved.

  17. Kinetic analysis of elastomeric lag damper for helicopter rotors

    Science.gov (United States)

    Liu, Yafang; Wang, Jidong; Tong, Yan

    2018-02-01

    The elastomeric lag dampers suppress the ground resonance and air resonance that play a significant role in the stability of the helicopter. In this paper, elastomeric lag damper which is made from silicone rubber is built. And a series of experiments are conducted on this elastomeric lag damper. The stress-strain curves of elastomeric lag dampers employed shear forces at different frequency are obtained. And a finite element model is established based on Burgers model. The result of simulation and tests shows that the simple, linear model will yield good predictions of damper energy dissipation and it is adequate for predicting the stress-strain hysteresis loop within the operating frequency and a small-amplitude oscillation.

  18. Aligned composite structures for mitigation of impact damage and resistance to wear in dynamic environments

    Science.gov (United States)

    Mulligan, Anthony C.; Rigali, Mark J.; Sutaria, Manish P.; Popovich, Dragan; Halloran, Joseph P.; Fulcher, Michael L.; Cook, Randy C.

    2009-04-14

    Fibrous monolith composites having architectures that provide increased flaw insensitivity, improved hardness, wear resistance and damage tolerance and methods of manufacture thereof are provided for use in dynamic environments to mitigate impact damage and increase wear resistance.

  19. Optical Manipulation of Shape-Morphing Elastomeric Liquid Crystal Microparticles Doped with Gold Nanocrystals

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Y. R.; Evans, J. S.; Lee, T.; Senyuk, B.; Keller, P.; He, S. L.; Smalyukh, I. I.

    2012-06-11

    We demonstrate facile optical manipulation of shape of birefringent colloidal microparticles made from liquid crystal elastomers. Using soft lithography and polymerization, we fabricate elastomeric microcylinders with weakly undulating director oriented on average along their long axes. These particles are infiltrated with gold nanospheres acting as heat transducers that allow for an efficient localized transfer of heat from a focused infrared laser beam to a submicrometer region within a microparticle. Photothermal control of ordering in the liquid crystal elastomer using scanned beams allows for a robust control of colloidal particles, enabling both reversible and irreversible changes of shape. Possible applications include optomechanics, microfluidics, and reconfigurable colloidal composites with shape-dependent self-assembly.

  20. Oxidation resistant coatings for ceramic matrix composite components

    Energy Technology Data Exchange (ETDEWEB)

    Vaubert, V.M.; Stinton, D.P. [Oak Ridge National Lab., TN (United States); Hirschfeld, D.A. [New Mexico Inst. of Mining and Technology, Socorro, NM (United States). Dept. of Materials and Metallurgical Engineering

    1998-11-01

    Corrosion resistant Ca{sub 0.6}Mg{sub 0.4}Zr{sub 4}(PO{sub 4}){sub 6} (CMZP) and Ca{sub 0.5}Sr{sub 0.5}Zr{sub 4}(PO{sub 4}){sub 6} (CS-50) coatings for fiber-reinforced SiC-matrix composite heat exchanger tubes have been developed. Aqueous slurries of both oxides were prepared with high solids loading. One coating process consisted of dipping the samples in a slip. A tape casting process has also been created that produced relatively thin and dense coatings covering a large area. A processing technique was developed, utilizing a pre-sintering step, which produced coatings with minimal cracking.

  1. Residual stress effects on the impact resistance and strength of fiber composites

    Science.gov (United States)

    Chamis, C. C.

    1973-01-01

    Equations have been derived to predict degradation effects of microresidual stresses on impact resistance of unidirectional fiber composites. Equations also predict lamination residual stresses in multilayered angle ply composites.

  2. Baxter elastomeric pumps: Feasibility of weight estimates.

    Science.gov (United States)

    Chambers, Carole R; Pabia, Mica; Sawyer, Michael; Tang, Patricia A

    2017-09-01

    Purpose Elastomeric pumps are used to infuse a 46-h fluorouracil protocol and patients are asked to visually inspect the pump daily. The pump has a variability of ±10% and there are additional patient variables that can increase this. The feasibility of weighing the pump rather than a visual inspection along with the secondary objective to confirm the pump's variability in real world conditions was undertaken. Methods Empty pumps were weighed using both pharmacy and kitchen scales. Pumps upon completion of the 46-h infusion were also weighed using both pharmacy and kitchen scales. Results The kitchen scale was as accurate as the pharmacy grade scale. Disconnected pumps showed the expected variability from using these infusor pumps along with a few showing greater variability likely due to patient variables. Conclusion Weighing pumps appears to be feasible both at the pharmacy and home level. Next steps would be to weigh pumps during the infusion to validate an alternate method to simple visual inspection for patients to confirm proper infusing of the pump at their home.

  3. Sterilizing elastomeric chains without losing mechanical properties. Is it possible?

    Directory of Open Access Journals (Sweden)

    Matheus Melo Pithon

    2015-06-01

    Full Text Available OBJECTIVE: To investigate the effects of different sterilization/disinfection methods on the mechanical properties of orthodontic elastomeric chains. METHODS: Segments of elastomeric chains with 5 links each were sent for sterilization by cobalt 60 (Co60 (20 KGy gamma ray technology. After the procedure, the elastomeric chains were contaminated with clinical samples of Streptococcus mutans. Subsequently, the elastomeric chains were submitted to sterilization/disinfection tests carried out by means of different methods, forming six study groups, as follows: Group 1 (control - without contamination, Group 2 (70°GL alcohol, Group 3 (autoclave, Group 4 (ultraviolet, Group 5 (peracetic acid and Group 6 (glutaraldehyde. After sterilization/disinfection, the effectiveness of these methods, by Colony forming units per mL (CFU/mL, and the mechanical properties of the material were assessed. Student's t-test was used to assess the number of CFUs while ANOVA and Tukey's test were used to assess elastic strength. RESULTS: Ultraviolet treatment was not completely effective for sterilization. No loss of mechanical properties occurred with the use of the different sterilization methods (p > 0.05. CONCLUSION: Biological control of elastomeric chains does not affect their mechanical properties.

  4. 40 CFR 427.40 - Applicability; description of the asbestos paper (elastomeric binder) subcategory.

    Science.gov (United States)

    2010-07-01

    ... asbestos paper (elastomeric binder) subcategory. 427.40 Section 427.40 Protection of Environment... SOURCE CATEGORY Asbestos Paper (Elastomeric Binder) Subcategory § 427.40 Applicability; description of the asbestos paper (elastomeric binder) subcategory. The provisions of this subpart are applicable to...

  5. Radiation crosslinked block copolymer blends with improved impact resistance

    International Nuclear Information System (INIS)

    Saunders, F.L.; Pelletier, R.R.

    1976-01-01

    Polymer blends having high impact resistance after mechanical working are produced by blending together a non-elastomeric monovinylidene aromatic polymer such as polystyrene with an elastomeric copolymer, such as a block copolymer of styrene and butadiene, in the form of crosslinked, colloidal size particles

  6. Enhancing retention of partial dentures using elastomeric retention rings

    Directory of Open Access Journals (Sweden)

    Kakkirala Revathi

    2015-01-01

    Full Text Available This report presents an alternative method for the retention of partial dentures that relies on the engagement of tooth undercuts by a lining material. The lab procedures are also presented. A new maxillary and mandibular acrylic partial dentures were fabricated using elastomeric retention technique for a partially dentate patient. A partially dentate man reported difficulty in retaining his upper removable partial denture (RPD. The maxillary RPD was designed utilizing elastomeric retention technique. During follow-up, it was necessary to replace the retention rings due to wear. The replacement of the retention rings, in this case, was done through a chairside reline technique. Elastomeric retention technique provides exceptionally good retention can be indicated to stabilize, cushion, splint periodontally involved teeth, no enough undercut for clasps, eliminate extractions, single or isolated teeth.

  7. Elastomeric Cellular Structure Enhanced by Compressible Liquid Filler

    Science.gov (United States)

    Sun, Yueting; Xu, Xiaoqing; Xu, Chengliang; Qiao, Yu; Li, Yibing

    2016-05-01

    Elastomeric cellular structures provide a promising solution for energy absorption. Their flexible and resilient nature is particularly relevant to protection of human bodies. Herein we develop an elastomeric cellular structure filled with nanoporous material functionalized (NMF) liquid. Due to the nanoscale infiltration in NMF liquid and its interaction with cell walls, the cellular structure has a much enhanced mechanical performance, in terms of loading capacity and energy absorption density. Moreover, it is validated that the structure is highly compressible and self-restoring. Its hyper-viscoelastic characteristics are elucidated.

  8. Effects of processing method and moisture history on laboratory fungal resistance of wood-HDPE composites.

    Science.gov (United States)

    Craig M. Clemons; Rebecca E. Ibach

    2004-01-01

    The purpose of this study was to clarify the effects of composite processing and moisture sorption on laboratory fungal resistance of wood-plastic composites. A 2-week water soaking or cyclic boiling-drying procedure was used to infuse moisture into composites made from high-density polyethylene filled with 50 percent wood flour and processed by extrusion, compression...

  9. Continuous monitoring of the composition of liquid Pb-17Li eutectic using electrical resistivity methods

    International Nuclear Information System (INIS)

    Hubberstey, P.; Sample, T.; Barker, M.G.

    1991-01-01

    The composition of liquid Pb-17Li alloys has been continously determined, using an electrical resistivity monitor, during their interaction with nitrogen, oxygen, hydrogen and water vapour. The operation of the monitor depends on the fact that the resistivity of liquid Pb-Li alloys is dependent on their composition. Accurate resistivity-composition isotherms have been derived from resistivity-temperature data for 15 Pb-Li alloys (0 Li -8 Ω m (mol% Li) -1 at 725 K) is such that a change of 0.05 mol% Li in the alloy composition can be measured. The addition of oxygen and water vapour resulted in a decrease in the resistivity of the liquid alloy. Neither nitrogen nor hydrogen had any effect. The observed changes were shown to be consistent with Li 2 O formation. (orig.)

  10. Elastomeric neutron shielding material and process of production

    International Nuclear Information System (INIS)

    John, G.; Knorr, W.

    1987-01-01

    Elastomeric neutron shielding material made of plastic with high hydrogen content, characterized in that the shielding material is a polymeric reaction product of a reaction between (a) polyol on the base of polybutadiene which compares with polyethylene with regard to hydrogen content, and (b) aliphatic diisocyanate, and in that the hydrogen content is higher than 8 weight per cent. (orig.) [de

  11. Composite-Material Tanks with Chemically Resistant Liners

    Science.gov (United States)

    DeLay, Thomas K.

    2004-01-01

    Lightweight composite-material tanks with chemically resistant liners have been developed for storage of chemically reactive and/or unstable fluids . especially hydrogen peroxide. These tanks are similar, in some respects, to the ones described in gLightweight Composite-Material Tanks for Cryogenic Liquids h (MFS-31379), NASA Tech Briefs, Vol. 25, No. 1 (January, 2001), page 58; however, the present tanks are fabricated by a different procedure and they do not incorporate insulation that would be needed to prevent boil-off of cryogenic fluids. The manufacture of a tank of this type begins with the fabrication of a reusable multisegmented aluminum mandrel in the shape and size of the desired interior volume. One or more segments of the mandrel can be aluminum bosses that will be incorporated into the tank as end fittings. The mandrel is coated with a mold-release material. The mandrel is then heated to a temperature of about 400 F (approximately equal to 200 C) and coated with a thermoplastic liner material to the desired thickness [typically approxiamtely equal to 15 mils (approximately equal to 0.38 mm)] by thermal spraying. In the thermal-spraying process, the liner material in powder form is sprayed and heated to the melting temperature by a propane torch and the molten particles land on the mandrel. The sprayed liner and mandrel are allowed to cool, then the outer surface of the liner is chemically and/or mechanically etched to enhance bonding of a composite overwrap. The etched liner is wrapped with multiple layers of an epoxy resin reinforced with graphite fibers; the wrapping can be done either by manual application of epoxy-impregnated graphite cloth or by winding of epoxy-impregnated filaments. The entire assembly is heated in an autoclave to cure the epoxy. After the curing process, the multisegmented mandrel is disassembled and removed from inside, leaving the finished tank. If the tank is to be used for storing hydrogen peroxide, then the liner material

  12. Properties of Natural Rubber-Based Composites Containing Fullerene

    Directory of Open Access Journals (Sweden)

    Omar A. Al-Hartomy

    2012-01-01

    Full Text Available In this study the influence of fullerenes in concentrations from 0.5 to 1.5 phr on both the vulcanization characteristics of the compounds and physicomechanical, dynamic, and dielectric properties and thermal aging resistance of nanocomposites on the basis of natural rubber has been investigated. The effect of the filler dispersion in the elastomeric matrix has been also investigated. Neat fullerene and the composites comprising it have been studied and characterized by scanning electron microscopy (SEM and transmission electron microscopy (TEM.

  13. Long-Term Chemical Resistance of Ecological Epoxy Polymer Composites

    Directory of Open Access Journals (Sweden)

    Bernardeta Debska

    2018-03-01

    Full Text Available Resin concretes belong to a small group of building materials which, besides high strength parameters, also have a very good chemical resistance. This is confirmed by the studies carried out by various research institutions around the world. However, there is little data on the behaviour of composite resin exposed to corrosive solutions for an extended period of time. This article presents the results of the research on weight changes in samples of epoxy mortar modified with poly(ethylene terephthalate glycolysates, immersed for 5 years in four different aggressive media i.e. 10% aqueous solutions of sulphuric and nitric acids, sodium hydroxide, and sodium chloride. The actual average weight changes obtained were compared with the data calculated on the basis of the regression functions fitted to the data recorded after 3.5 years of exposure. This allowed verification of the model selection correctness and evaluation of the effectiveness of the fitted regression curve. In the case of aqueous sodium hydroxide and sodium chloride solutions, it can be assumed that the logarithmic model describes weight changes well. It was observed that the weight of the samples exposed to NaCl solutions and NaOH stabilizes over prolonged monitoring time and reaches a plateau. However, the weight changes in mortar samples immersed for 5 years in aqueous solution of sulphuric and nitric acids quite significantly differ from the data calculated on the basis of the trend line fitted to the results of the tests carried out after 3.5 years of exposure. It seems that the better solution in this case is the selection of an exponential model. In addition, placing the logarithmic trendlines for all corrosive media together on a chart allows to note which of the solutions is the most aggressive. It was found that after 5 years of immersion in aqueous solutions of acids, mortar samples became brittle, and the observation of their fractures confirmed the weakness of the

  14. Low-Cost Repairable Oxidation Resistant Coatings for Carbon-Carbon Composites via CCVD

    National Research Council Canada - National Science Library

    Hendrick, Michelle

    2000-01-01

    ...) thin film process to yield oxidation resistant coatings on carbon-carbon (C-C) composites. Work was on simple coatings at this preliminary stage of investigation, including silicon dioxide, platinum and aluminum oxide...

  15. Fiber Finishes for Improving Galvanic Resistance of Imide-Based Composites

    National Research Council Canada - National Science Library

    Allred, R. E

    1998-01-01

    The objective of this program is the development and demonstration of galvanic corrosion resistant carbon/ BMI composites through the use of reactive finishes to form coatings that isolate the carbon...

  16. Towards mechanisms-guided resistivity-based monitoring of damage evolution in laminated composites

    KAUST Repository

    Lubineau, Gilles; Nouri, Hedi; Selvakumaran, Lakshmi

    2013-01-01

    A convenient health monitoring technique for detecting degradation in laminated composite is to monitor the change of electrical resistance along multiple conduction paths within the structure. Yet, the relations between the global modification

  17. Mechanical Properties and Thermal Shock Resistance Analysis of BNNT/Si3N4 Composites

    Science.gov (United States)

    Wang, Shouren; Wang, Gaoqi; Wen, Daosheng; Yang, Xuefeng; Yang, Liying; Guo, Peiquan

    2018-04-01

    BNNT/Si3N4 ceramic composites with different weight amount of BNNT fabricated by hot isostatic pressing were introduced. The mechanical properties and thermal shock resistance of the composites were investigated. The results showed that BNNT-added ceramic composites have a finer and more uniform microstructure than that of BNNT-free Si3N4 ceramic because of the retarding effect of BNNT on Si3N4 grain growth. The addition of 1.5 wt.% BNNT results in simultaneous increase in flexural strength, fracture toughness, and thermal shock resistance. The analysis of the results indicates that BNNT brings many thermal transport channels in the microstructure, increasing the efficiency of thermal transport, therefore results in increase of thermal shock resistance. In addition, BNNT improves the residual flexural strength of composites by crack deflection, bridging, branching and pinning, which increase the crack propagation resistance.

  18. Mode I and Mode II Interlaminar Crack Growth Resistances of Ceramic Matrix Composites at Ambient Temperature

    National Research Council Canada - National Science Library

    Choi, Sung R; Kowalik, Robert W; Alexander, Donald J

    2007-01-01

    ...) including three gas-turbine grade melt-infiltrated SiC/SiC composites. Modes I and II crack growth resistances, GI and GII, were evaluated at ambient temperature using double cantilever beam and end notched flexure methods, respectively...

  19. Stab Resistance of Shear Thickening Fluid (STF)-Kevlar Composites for Body Armor Applications

    National Research Council Canada - National Science Library

    Egres Jr., R. G; Decker, M. J; Halbach, C. J; Lee, Y. S; Kirkwood, J. E; Kirwood, K. M; Wagner, N. J; Wetzel, E. D

    2004-01-01

    The stab resistance of shear thickening fluid (STF)-Kevlar and STF-Nylon fabric composites are investigated and found to exhibit significant improvements over neat fabric targets of equivalent areal density...

  20. Wireless Damage Monitoring of Laminated CFRP Composites using Electrical Resistance Change

    National Research Council Canada - National Science Library

    Todoroki, Akira

    2007-01-01

    .... In this system, a tiny oscillation circuit is attached to the composite component. When delimitation of the component occurs, electrical resistance changes, which causes a change in the oscillating frequency of the circuit...

  1. Resistance Welding of Thermoplastic Composites : Process and Performance

    NARCIS (Netherlands)

    Shi, H.

    2014-01-01

    Compared to thermoset composites, thermoplastic composites are drawing more and more attention by aircraft industries not only due to their excellent material properties but also due to their potentials to reduce cycle time and structure cost by using low-cost manufacturing technologies such as

  2. Fatigue resistance of CAD/CAM resin composite molar crowns.

    NARCIS (Netherlands)

    Shembish, F.A.; Tong, H.; Kaizer, M.; Janal, M.N.; Thompson, V.P.; Opdam, N.J.M.; Zhang, Y.

    2016-01-01

    OBJECTIVE: To demonstrate the fatigue behavior of CAD/CAM resin composite molar crowns using a mouth-motion step-stress fatigue test. Monolithic leucite-reinforced glass-ceramic crowns were used as a reference. METHODS: Fully anatomically shaped monolithic resin composite molar crowns (Lava

  3. Pressure and temperature induced electrical resistance change in nano-carbon/epoxy composites

    NARCIS (Netherlands)

    Shen, J. T.; Buschhorn, S. T.; De Hosson, J. Th. M.; Schulte, K.; Fiedler, B.

    2015-01-01

    In this study, we investigate the changes of electrical resistance of the carbon black (CB) and carbon nanotube (CNT) filled epoxy composites upon compression, swelling and temperature variation. For all samples we observe a decrease of electrical resistance under compression, while an increase of

  4. Increased corrosion resistance of basalt reinforced cement compositions with nanosilica

    Directory of Open Access Journals (Sweden)

    URKHANOVA Larisa Alekseevna

    2014-08-01

    Full Text Available Disperse fiber reinforcement is used to improve deformation and shrinkage characteristics, flexural strength of concrete. Basalt roving and thin staple fiber are often used as mineral fibers. The paper considers the problems of using thin basalt fiber produced by centrifugal-blow method. Evaluation of the corrosion resistance of basalt fiber as part of the cement matrix was performed. Nanodispersed silica produced by electron beam accelerator was used to increase corrosion resistance of basalt fiber.

  5. Increased corrosion resistance of basalt reinforced cement compositions with nanosilica

    OpenAIRE

    URKHANOVA Larisa Alekseevna; LKHASARANOV Solbon Aleksandrovich; ROZINA Victoria Yevgenievna; BUYANTUEV Sergey Lubsanovich; BARDAKHANOV Sergey Prokopievich

    2014-01-01

    Disperse fiber reinforcement is used to improve deformation and shrinkage characteristics, flexural strength of concrete. Basalt roving and thin staple fiber are often used as mineral fibers. The paper considers the problems of using thin basalt fiber produced by centrifugal-blow method. Evaluation of the corrosion resistance of basalt fiber as part of the cement matrix was performed. Nanodispersed silica produced by electron beam accelerator was used to increase corrosion resistance of ba...

  6. Fracture strength and fatigue resistance of dental resin-based composites

    NARCIS (Netherlands)

    Keulemans, F.; Palav, P.; Aboushelib, M.M.N.; van Dalen, A.; Kleverlaan, C.J.; Feilzer, A.J.

    2009-01-01

    Objectives: The aim of this study was to evaluate in vitro the influence of fiber-reinforcement on the fracture strength and fatigue resistance of resin-based composites. Methods: One hundred rectangular bar-shaped specimens (2 mm × 2 mm × 25 mm) made of resin-based composite were prepared in a

  7. Effect of magnesium aluminum silicate glass on the thermal shock resistance of BN matrix composite ceramics

    NARCIS (Netherlands)

    Cai, Delong; Jia, Dechang; Yang, Zhihua; Zhu, Qishuai; Ocelik, Vaclav; Vainchtein, Ilia D.; De Hosson, Jeff Th M.; Zhou, Yu

    The effects of magnesium aluminum silicate (MAS) glass on the thermal shock resistance and the oxidation behavior of h-BN matrix composites were systematically investigated at temperature differences from 600 degrees C up to 1400 degrees C. The retained strength rate of the composites rose with the

  8. Fracture resistance of reattached incisor fragments with mini fibre-reinforced composite anchors.

    NARCIS (Netherlands)

    Fennis, W.M.M.; Kreulen, C.M.; Wolke, J.G.C.; Fokkinga, W.A.; Machado, C.; Creugers, N.H.J.

    2009-01-01

    OBJECTIVES: Fractured coronal fragments of incisors can be adhered to the remaining tooth with resin composite, but are prone to failure. This study explores whether mini fibre-reinforced composite (FRC) anchors increase fracture resistance of reattached fragments. METHODS: Forty-five extracted

  9. Effects of oxygen plasma treatment power on Aramid fiber III/BMI composite humidity resistance properties

    Science.gov (United States)

    Wang, Jing; Shi, Chen; Feng, Jiayue; Long, Xi; Meng, Lingzhi; Ren, Hang

    2018-01-01

    The effects of oxygen plasma treatment power on Aramid Fiber III chemical structure and its reinforced bismaleimides (BMI) composite humidity resistance properties were investigated in this work. The aramid fiber III chemical structure under different plasma treatment power were measured by FTIR. The composite bending strength and interlinear shear strength with different plasma treatment power before and after absorption water were tested respectively. The composite rupture morphology was observed by SEM. The FTIR results showed that oxygen plasma treatment do not change the fiber bulk chemical structure. The composite humidity resistance of bending strength and interlinear shear strength are similar for untreated and plasma treated samples. The retention rate of composite bending strength and interlinear shear strength are about 75% and 94%, respectively. The composite rupture mode turns to be the fiber failure after water absorption.

  10. Hybrid carbon/glass fiber composites: Micromechanical analysis of structure–damage resistance relationships

    DEFF Research Database (Denmark)

    Mishnaevsky, Leon; Dai, Gaoming

    2014-01-01

    A computational study of the effect of microstructure of hybrid carbon/glass fiber composites on their strength is presented. Unit cells with hundreds of randomly located and misaligned fibers of various properties and arrangements are subject to tensile and compression loading, and the evolution...... strength than pure composites, while the strength of hybrid composites under inform force loading increases steadily with increasing the volume content of carbon fibers....... of fiber damages is analyzed in numerical experiments. The effects of fiber clustering, matrix properties, nanoreinforcement, load sharing rules on the strength and damage resistance of composites are studied. It was observed that hybrid composites under uniform displacement loading might have lower...

  11. Random walks in nanotube composites: Improved algorithms and the role of thermal boundary resistance

    International Nuclear Information System (INIS)

    Duong, Hai M.; Papavassiliou, Dimitrios V.; Lee, Lloyd L.; Mullen, Kieran J.

    2005-01-01

    Random walk simulations of thermal walkers are used to study the effect of interfacial resistance on heat flow in randomly dispersed carbon nanotube composites. The adopted algorithm effectively makes the thermal conductivity of the nanotubes themselves infinite. The probability that a walker colliding with a matrix-nanotube interface reflects back into the matrix phase or crosses into the carbon nanotube phase is determined by the thermal boundary (Kapitza) resistance. The use of 'cold' and 'hot' walkers produces a steady state temperature profile that allows accurate determination of the thermal conductivity. The effects of the carbon nanotube orientation, aspect ratio, volume fraction, and Kapitza resistance on the composite effective conductivity are quantified

  12. Radiolucent Composites Providing High Resistance against Sterilization Decomposition

    Czech Academy of Sciences Publication Activity Database

    Suchý, Tomáš; Balík, Karel; Sedláček, R.; Sucharda, Zbyněk; Sochor, M.; Prokop, J.; Beneš, J.; Křena, J.

    2011-01-01

    Roč. 55, č. 4 (2011), s. 401-409 ISSN 0862-5468 R&D Projects: GA ČR(CZ) GAP108/10/1457 Institutional research plan: CEZ:AV0Z30460519 Keywords : composite material * polymer matrix * radiolucency Subject RIV: JI - Composite Materials Impact factor: 0.382, year: 2011 http://www.ceramics-silikaty.cz/2011/2011_04_401.htm

  13. Fabrication and testing of fire resistant graphite composite panels

    Science.gov (United States)

    Roper, W. D.

    1986-01-01

    Eight different graphite composite panels were fabricated using four different resin matrices. The resin matrices included Hercules 71775, a blend of vinylpolystyrpyridine and bismaleimide, H795, a bismaleimide, Cycom 6162, a phenolic, and PSP 6022m, a polystyrylpyridine. Graphite panels were fabricated using fabric or unidirectional tape. Described are the processes for preparing these panels and some of their mechanical, thermal and flammability properties. Panel properties are compared with state-of-the-art epoxy fiberglass composite panels.

  14. Fracture resistance curves and toughening mechanisms in polymer based dental composites

    DEFF Research Database (Denmark)

    De Souza, J.A.; Goutianos, Stergios; Skovgaard, M.

    2011-01-01

    The fracture resistance (R-curve behaviour) of two commercial dental composites (Filtek Z350® and Concept Advanced®) were studied using Double Cantilever Beam sandwich specimens loaded with pure bending moments to obtain stable crack growth. The experiments were conducted in an environmental...... significantly higher fracture resistance than the composite with the coarser microstructure. The fracture properties were related to the flexural strength of the dental composites. The method, thus, can provide useful insight into how the microstructure enhances toughness, which is necessary for the future...

  15. Influence of Heat Treatment on Abrasive Wear Resistance of Silumin Matrix Composite Castings

    Directory of Open Access Journals (Sweden)

    Gawdzińska K.

    2016-03-01

    Full Text Available The authors attempted at examining the effect of heat treatment on abrasive wear resistance of metal composite castings. Metal matrix composites were made by infiltrating preforms created from unordered short fibers (graphite or silumin with liquid aluminium alloy AlSi12(b. Thus prepared composites were subject to solution heat treatment at a temperature of 520°C for four hours, then aging at a temperature of 220°C for four hours. Abrasion resistance of the material was tested before and after thermal treatment.

  16. Enhanced oxidation resistance of carbon fiber reinforced lithium aluminosilicate composites by boron doping

    International Nuclear Information System (INIS)

    Xia, Long; Jin, Feng; Zhang, Tao; Hu, Xueting; Wu, Songsong; Wen, Guangwu

    2015-01-01

    Highlights: • C f /LAS composites exhibit enhanced oxidation resistance by boron doping. • Boron doping is beneficial to the improvement of graphitization degree of carbon fibers. • Graphitization of carbon fibers together with the decrease of viscosity of LAS matrix is responsible to the enhancement of oxidation resistance of C f /LAS composites. - Abstract: Carbon fiber reinforced lithium aluminosilicate matrix composites (C f /LAS) modified with boron doping were fabricated and oxidized for 1 h in static air. Weight loss, residual strength and microstructure were analyzed. The results indicate that boron doping has a remarkable effect on improving the oxidation resistance for C f /LAS. The synergism of low viscosity of LAS matrix at high temperature and formation of graphite crystals on the surface of carbon fibers, is responsible for excellent oxidation resistance of the boron doped C f /LAS.

  17. Preparation of novel functional Mg/O/PCL/ZnO composite biomaterials and their corrosion resistance

    International Nuclear Information System (INIS)

    Xi, Zhongxian; Tan, Cui; Xu, Lan; Yang, Na; Li, Qing

    2015-01-01

    Highlights: • Novel functional Mg/O/PCL/ZnO composite biomaterials were prepared. • The biomaterials were prepared by anodization treatment and dip-coating technique. • The composite biomaterials were smooth and with low porosity. • The prepared biomaterials have good corrosion resistance in SBF. • The composite biomaterials can release zinc ion to promote bone formation. - Abstract: In this study, novel and functional Mg/O/PCL/ZnO (magnesium/anodic film/poly(ε-caprolactone)/zinc oxide) composite biomaterials for enhancing the bioactivity and biocompatibility of the implant was prepared by using anodization treatment and dip-coating technique. The surface morphology, microstructure, adhesion strength and corrosion resistance of the composite biomaterials were investigated using scanning electron microscopy (SEM), adhesion measurements, electrochemical tests and immersion tests respectively. In addition, the biocompatible properties of Mg (magnesium), Mg/PCL (magnesium/poly(ε-caprolactone)) and Mg/O/PCL (magnesium/anodic film/poly(ε-caprolactone)) samples were also investigated. The results show that the Mg/O/PCL/ZnO composite biomaterials were with low porosity and with the ZnO powders dispersed in PCL uniformly. The adhesion tests suggested that Mg/O/PCL/ZnO composite biomaterials had better adhesion strength than that of Mg/PCL composite biomaterials obviously. Besides, an in vitro test for corrosion demonstrated that the Mg/O/PCL/ZnO composite biomaterials had good corrosion resistance and zinc ion was released obviously in SBF

  18. Fundamental studies of low velocity impact resistance of graphite fiber reinforced polymer matrix composites

    International Nuclear Information System (INIS)

    Bowles, K.J.

    1985-01-01

    A study was conducted to relate the impact resistance of graphite fiber reinforced composites with matrix properties through gaining an understanding of the basic mechanics involved in the deformation and fracture process, and the effect of the polymer matrix structure on these mechanisms. It was found that the resin matrix structure influences the composite impact resistance in at least two ways. The integration of flexibilizers into the polymer chain structure tends to reduce the T/sub G/ and the mechanical properties of the polymer. The reduction in the mechanical properties of the matrix does not enhance the composite impact resistance because it allows matrix controlled failure to initiate impact damage. Linear polymers, which contain no active groups for cross-linking, do not toughen composites because the fiber-matrix interfacial bond is not of sufficient strength to prevent interfacial failure from occurring. Toughness must be built into the basic polymer backbone and cross-linking structure

  19. Radiation-resistant composite for biological shield of personnel

    Science.gov (United States)

    Barabash, D. E.; Barabash, A. D.; Potapov, Yu B.; Panfilov, D. V.; Perekalskiy, O. E.

    2017-10-01

    This article presents the results of theoretical and practical justification for the use of polymer concrete based on nonisocyanate polyurethanes in biological shield structures. We have identified the impact of ratio: polymer - radiation-resistant filling compound on the durability and protection properties of polymer concrete. The article expounds regression dependence of the change of basic properties of the aforementioned polymer concrete on the absorbed radiation dose rate. Synergy effect in attenuation of radioactivity release in case of conjoint use of hydrogenous polymer base and radiation-resistant powder is also addressed herein.

  20. Active shape-morphing elastomeric colloids in short-pitch cholesteric liquid crystals.

    Science.gov (United States)

    Evans, Julian S; Sun, Yaoran; Senyuk, Bohdan; Keller, Patrick; Pergamenshchik, Victor M; Lee, Taewoo; Smalyukh, Ivan I

    2013-05-03

    Active elastomeric liquid crystal particles with initial cylindrical shapes are obtained by means of soft lithography and polymerization in a strong magnetic field. Gold nanocrystals infiltrated into these particles mediate energy transfer from laser light to heat, so that the inherent coupling between the temperature-dependent order and shape allows for dynamic morphing of these particles and well-controlled stable shapes. Continuous changes of particle shapes are followed by their spontaneous realignment and transformations of director structures in the surrounding cholesteric host, as well as locomotion in the case of a nonreciprocal shape morphing. These findings bridge the fields of liquid crystal solids and active colloids, may enable shape-controlled self-assembly of adaptive composites and light-driven micromachines, and can be understood by employing simple symmetry considerations along with electrostatic analogies.

  1. Erosion resistance and adhesion of composite metal/ceramic coatings produced by plasma spraying

    International Nuclear Information System (INIS)

    Ramm, D.A.J.; Hutchings, I.M.; Clyne, T.W.

    1993-01-01

    Ceramic coatings can exhibit greater erosion resistance than most metallic coatings. Such coatings are conveniently produced by thermal spraying. Unfortunately, thermally sprayed ceramic coatings often exhibit poor adhesion, partly as a consequence of the development of residual stresses during spraying and subsequent cooling. Composite coatings have been studied using aluminium/alumina deposits on steel substrates. The incorporation of ceramics within a ductile matrix has potential for sharply reducing the erosive wear at high erodent impact angles, whilst retaining the good erosion resistance of ceramics at low angles. It is shown that the proportion of metal and ceramic at the free surface can be specified so as to optimise the erosion resistance. Experiments have also been carried out on the resistance of the coatings to debonding during four-point bending of the coated substrate. Progress is being made towards the tailoring of composition profiles in graded coatings so as to optimise the combination of erosion resistance and adhesion. (orig.)

  2. Impact resistance of uncoated SiC/SiC composites

    International Nuclear Information System (INIS)

    Bhatt, Ramakrishna T.; Choi, Sung R.; Cosgriff, Laura M.; Fox, Dennis S.; Lee, Kang N.

    2008-01-01

    Two-dimensional woven SiC/SiC composites fabricated by melt infiltration method were impact tested at room temperature and at 1316 deg. C in air using 1.59-mm diameter steel-ball projectiles at velocities ranging from 115 to 400 m/s. The extent of substrate damage with increasing projectile velocity was imaged and analyzed using optical and scanning electron microscopy, and non-destructive evaluation (NDE) methods such as pulsed thermography, and computed tomography. The impacted specimens were tensile tested at room temperature to determine their residual mechanical properties. Results indicate that at 115 m/s projectile velocity, the composite showed no noticeable surface or internal damage and retained its as-fabricated mechanical properties. As the projectile velocity increased above this value, the internal damage increased and mechanical properties degraded. At velocities >300 m/s, the projectile penetrated through the composite, but the composite retained ∼50% of the ultimate tensile strength of the as-fabricated composite and exhibited non-brittle failure. Predominant internal damages are delamination of fiber plies, fiber fracture and matrix shearing

  3. Fracture resistance of premolar teeth restored with silorane-based or dimethacrylate-based composite resins.

    Science.gov (United States)

    Akbarian, Golsa; Ameri, Hamideh; Chasteen, Joseph E; Ghavamnasiri, Marjaneh

    2014-01-01

    To restore posterior teeth using low-shrinkage composite to minimize microleakage. To compare the fracture resistance of mesio-occlusal-distal (MOD) cavity preparations restored with either low-shrinkage composite or with dimethacrylate-based composite in conjunction with cavity liners and without them. The null hypothesis of the study is that there are no differences in either fracture resistance or fracture mode between the silorane group and dimethacrylate groups with and without the use of cavity liners. Sixty maxillary premolars were divided into six groups of 10. MOD cavities were prepared in four groups: F: posterior composite (Filtek P60); GF: 0.5-mm Glass Ionomer (Fuji LC) + posterior composite; FF: 0.5-mm flowable composite (Filtek Supreme XT) + posterior composite; and S: low-shrinkage composite (Filtek P90). Negative (N) and positive (P) control groups consisted of unrestored and sound teeth, respectively. The specimens were thermocycled and loaded. Data were analyzed using analysis of variance, Tukey, and chi-square tests (α = 0.05). Groups FF (1643.09 ± 187/80 N) and GF (1596.80 ± 163/93 N) (p = 0.06 > 0.05) were statistically identical, although less than group P (1742/33 ± 110/08 N), but still demonstrated greater fracture resistance than the other groups. The fracture resistance of group S (1434/69 ± 107/62 N) was identical to GF and FF (p = 0.06 > 0.05). The fracture resistance of F (1353/19 ± 233/90 N) was less than GF and FF, and statistically identical to S (p = 0.87 > 0.05). Silorane-based composite showed a resistance to fracture similar to methacrylate-based composite restorations regardless of whether cavity liners were used. The findings of this study support the selection of silorane-based composite for the restoration of maxillary premolars with standardized Class II cavity preparations in order to strengthen the resistance to fracture to the same extent as do dimethacrylate

  4. Effect of different glass and zeolite A compositions on the leach resistance of ceramic waste forms

    International Nuclear Information System (INIS)

    Lewis, M.A.; Hash, M.; Glandorf, D.

    1996-01-01

    A ceramic waste form is being developed for waste generated during electrometallurgical treatment of spent nuclear fuel. The waste is generated when fission products are removed from the electrolyte, LiCl-KCl eutectic. The waste form is a composite fabricated by hot isostatic pressing a mixture of glass frit and zeolite occluded with fission products and salt. Normalized release rate is less than 1 g/m 2 d for all elements in MCC-1 leach test run for 28 days in deionized water at 90 C. This leach resistance is comparable to that of early Savannah River glasses. We are investigating how leach resistance is affected by changes in cationic form of zeolite and in glass composition. Composites were made with 3 forms of zeolite A and 6 glasses. We used 3-day ASTM C1220-92 (formerly MCC-1) leach tests to screen samples for development purposes only. The leach test results show that the glass composites of zeolites 5A and 4A retain fission products equally well. Loss of Cs is small (0.1-0.5 wt%), while the loss of divalent and trivalent fission products is one or more orders of magnitude smaller. Composites of 5A retain chloride ion better in these short-term screens than 4A and 3A. The more leach resistant composites were made with durable glasses rich in silica and poor in alkaline earth oxides. XRD show that a salt phase was absent in the leach resistant composites of 5A and the better glasses but was present in the other composites with poorer leach performance. Thus, absence of salt phase corresponds to improved leach resistance. Interactions between zeolite and glass depend on composition of both

  5. Equivalent network for resistance and temperature coefficient of resistance versus temperature and composition of thick resistive films

    International Nuclear Information System (INIS)

    Kusy, A.

    1987-01-01

    Two types of elementary resistances in thick resistive films have been considered: (i) constriction resistance R/sub C/ determined by the bulk properties of conducting material and by the geometry of constriction, and (ii) barrier resistance R/sub B/ determined by the parameters of a thermally activated type of tunneling process and by the geometry of the metal-insulator-metal unit. On this basis a resistance network composed of a large number of the two types of resistances has been defined. The network has been considered as being equivalent to thick resistive film (TRF) from the point of view of the resistance and temperature coefficient of resistance (TCR). The parameters of this network have been evaluated by the computer-aided approximation of the experimental data found for RuO 2 -based TRFs. On the basis of the equations derived for the network as well as the results of the approximation process, it can be concluded that the small values of the network TCR result from the superposition of the TCR of the conducting component β/sub C/ and of the temperature coefficient of barrier resistance α/sub B/. In this superposition β/sub C/ is attenuated (by 1--2 orders of magnitude), while α/sub B/ is attenuated by only few percentages. The network has been found to be strongly barrier dominated

  6. Development of in-situ ZrC reinforced iron based composites for wear resistance applications

    International Nuclear Information System (INIS)

    Bandyopadhyay, T.K.; Das, K.

    2002-01-01

    A common objective behind the processing of iron-based composites is to improve the wear resistance of steels by incorporating some reinforcing phases, e.g., carbides and oxides. In the present investigation, iron-based zirconium carbide reinforced composite is produced by the aluminothermic reduction of zircon sand (ZrSiO 4 ) and blue dust (Fe 2 O 3 ) in the presence of carbon. Aluminothermic reduction of blue dust and zircon sand, being highly exothermic in nature, essentially leads to a self-propagating high-temperature synthesis (SHS) of the Fe-ZrC composite. The as-cast composite is characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The mechanical properties of the composite and the effect of heat treatment on the microstructure are evaluated. The composite possess sufficient hardness and promising abrasive wear resistance property. The abrasive wear resistance property of the Fe-ZrC composite is compared with that of a M2 grade tool material and it is found to be better than the tool material. The composite also possess good high temperature stability. (author)

  7. An electrical resistivity monitor for the detection of composition changes in Pb-17Li

    International Nuclear Information System (INIS)

    Hubberstey, P.; Barker, M.G.; Sample, T.

    1991-01-01

    An electrical resistivity monitor for the detection of composition changes in the lithium-lead eutectic alloy, Pb-17Li, has been developed. A miniature electromagnetic pump is used to sample alloy continuously from a pool or loop system and force it through a capillary section, within which the necessary resistance measurements are made, prior to its return to the bulk source. To calibrate the monitor, detailed resistivity-temperature and resistivity-composition data have been determined for Pb-Li alloys at temperatures from 600 to 800K and compositions from 0 to 20.5 at% Li. The resistivity increases with both temperature and composition; for Pb-17li at 723 K, dρ/dT=0.054x10 -8 ΩmK -1 , and dρ/d[Li]=1.27x10 -8 Ωm(at% Li) -1 . The sensitivity of the monitor is such that changes in composition of as little as ±0.05 at% Li can be detected and its response time is limited soley by the rate of sampling. (orig.)

  8. Specific features in the behavior of electrical resistivity of the pine biocarbon preform/copper composite

    Science.gov (United States)

    Burkov, A. T.; Orlova, T. S.; Smirnov, B. I.; Smirnov, I. A.; Misiorek, H.; Jezowski, A.

    2010-11-01

    The electrical resistivity ρ( T) of the novel type of composites prepared by infiltrating melted copper in vacuum in empty sap channels of white pine high-porosity biocarbon preforms has been measured in the temperature range 5-300 K. Biocarbon preforms have been prepared by pyrolysis of tree wood in an argon flow at two carbonization temperatures, 1000 and 2400°C. The electrical resistivity of the composites has been found to vary relatively weakly with temperature and to pass through a characteristic minimum near 40-50 K, which can be ascribed to iron and manganese impurities penetrating into copper from the carbon preform when liquid copper is infiltrated into it. It has been shown that the electrical resistivity ρ( T) of the composites is governed primarily by the specific microstructure of the preform, which is made up of parallel channels with an average diameter of about 50 μm interrupted by systems of thin capillaries. The small cross section of the copper-filled capillaries accounts for these regions providing the major contribution to the electrical resistivity of the composites. An increase in the wood carbonization temperature brings about a noticeable increase in the effective capillary cross section and a decrease in the electrical resistivity ρ( T) of the composite.

  9. Role of certain cellular composition in radio-resistant fungi

    International Nuclear Information System (INIS)

    Shahin, A.A.M.; Hammad, A.A.I.; Hazaa, M.M.; Swelim, M.A.; Mohamed, Y.A.

    2007-01-01

    Fifty three fungal isolates of genera Curvularia, Alternaria and Fusarium were isolated from different sources included crops, vegetables, fruits in addition to bread, chicken feed soil and air. Five isolates were selected from each genus according to the difference in the morphological characters and its source. The fifteen isolates were exposed to increasing doses of gamma rays from 0.5 to 10.0 I 10 values when irradiated in saline solution were found to be 1.92,1.25, 1.47,0.47,1.31 and 0.70 respectively while their D 10 values were 2.25, 1.56, 1.70, 1.30, 1.83 and 1.23 as the irradiation process was done in their natural sources. The values of total protein, total lipids and total nucleic acids either RNA or DNA were relatively higher in radio-resistant strains than sensitive ones. Amino acids containing sulfur (cysteine, methionine) or double bonds (histidine) and the percentage of unsaturated fatty acids were also higher in resistant strains than the sensitive ones. Exposing the six selected strains to dose level 4 kGy obviously decreased each of total protein, total amino acids and total nucleic acids especially DNA and the values of decreases were found to be higher in sensitive than the resistant strains. Dose level 12.5 kGy was quiet enough to eliminate the radioresistant fungi from the contaminated food whatever the level of contamination is

  10. Strain-dependent electrical resistance of multi-walled carbon nanotube/polymer composite films

    International Nuclear Information System (INIS)

    Park, Myounggu; Kim, Hyonny; Youngblood, Jeffrey P

    2008-01-01

    The strain-dependent electrical resistance characteristics of multi-walled carbon nanotube (MWCNT)/polymer composite films were investigated. In this research, polyethylene oxide (PEO) is used as the polymer matrix. Two representative volume fractions of MWCNT/PEO composite films were selected: 0.56 vol% (near the percolation threshold) and 1.44 vol% (away from the percolation threshold) of MWCNT. An experimental setup which can measure electrical resistance and strain simultaneously and continuously has been developed. Unique and repeatable relationships in resistance versus strain were obtained for multiple specimens with different volume fractions of MWCNT. The overall pattern of electrical resistance change versus strain for the specimens tested consists of linear and nonlinear regions. A resistance change model to describe the combination of linear and nonlinear modes of electrical resistance change as a function of strain is suggested. The unique characteristics in electrical resistance change for different volume fractions imply that MWCNT/PEO composite films can be used as tunable strain sensors and for application into embedded sensor systems in structures

  11. UV resistibility of a nano-ZnO/glass fibre reinforced epoxy composite

    International Nuclear Information System (INIS)

    Wong, Tsz-ting; Lau, Kin-tak; Tam, Wai-yin; Leng, Jinsong; Etches, Julie A.

    2014-01-01

    Highlights: • A GFRE composite with UV resistibility is introduced. • The bonding behaviour and UV resistibility of the composite were studied upon the addition of nano-ZnO particles. • The solvent effect in the dispersion of nano-ZnO particles was also studied. • The nano-ZnO/GFRE composite shows effective UV absorption with enhanced bonding behaviour. - Abstract: The harmfulness of ultraviolet (UV) radiation (UVR) to human health and polymer degradation has been the focus recently in all engineering industries. A polymer-based composite filled with nano-ZnO particles can enhance its UV resistibility. It has been found that the use of appropriate amount of nano-ZnO/Isopropyl alcohol solvent to prepare a UV resistant nano-ZnO/glass fibre reinforced epoxy (ZGFRE) composite can effectively block the UV transmission with negligible influence on the crystal structure of its resin system. This paper aims at investigating the interfacial bonding behaviour and UV resistibility of a ZGFRE composite. The solvent effect in relation to the dispersion properties of ZnO in the composite is also discussed. XRD results indicated that 20 wt% Isopropyl alcohol was an effective solvent for filling nano-ZnO particles into an epoxy. SEM examination also showed that the bonding behaviour between glass fibre and matrix was enhanced after filling 20 wt% nano-ZnO particles with 20 wt% Isopropyl alcohol into the composite. Samples filled with 20 wt% nano-ZnO/Isopropyl alcohol and 40 wt% nano-ZnO/Isopropyl alcohol has full absorption of UVA (315–400 nm), UVB (280–315 nm) and a part of UVC (190–280 nm)

  12. Fracture Resistance Evaluation of Fibre Reinforced Brittle Matrix Composites

    Czech Academy of Sciences Publication Activity Database

    Dlouhý, Ivo; Chlup, Zdeněk

    2005-01-01

    Roč. 290, - (2005), s. 167-174 ISSN 1013-9826. [Fractography of Advanced Ceramic s /2./. Stará Lesná, 03.10.2004-06.10.2004] R&D Projects: GA AV ČR(CZ) IAA2041003; GA ČR(CZ) GA101/02/0683 Keywords : fibre-reinforced ceramic s * glass matrix composites * chevron notch Subject RIV: JL - Materials Fatigue, Friction Mechanics Impact factor: 0.224, year: 2005

  13. Fracture resistance of endodontically treated teeth restored with a bulkfill flowable material and a resin composite.

    Science.gov (United States)

    Isufi, Almira; Plotino, Gianluca; Grande, Nicola Maria; Ioppolo, Pietro; Testarelli, Luca; Bedini, Rossella; Al-Sudani, Dina; Gambarini, Gianluca

    2016-01-01

    To determine and compare the fracture resistance of endodontically treated teeth restored with a bulk fill flowable material (SDR) and a traditional resin composite. Thirty maxillary and 30 mandibular first molars were selected based on similar dimensions. After cleaning, shaping and filling of the root canals and adhesive procedures, specimens were assigned to 3 subgroups for each tooth type (n=10): Group A: control group, including intact teeth; Group B: access cavities were restored with a traditional resin composite (EsthetX; Dentsply-Italy, Rome, Italy); Group C: access cavities were restored with a bulk fill flowable composite (SDR; Dentsply-Italy), except 1.5 mm layer of the occlusal surface that was restored with the same resin composite as Group B. The specimens were subjected to compressive force in a material static-testing machine until fracture occurred, the maximum fracture load of the specimens was measured (N) and the type of fracture was recorded as favorable or unfavorable. Data were statistically analyzed with one-way analysis of variance (ANOVA) and Bonferroni tests (Pcomposite and with a bulk fill flowable composite (SDR) was similar in both maxillary and mandibular molars and showed no significant decrease in fracture resistance compared to intact specimens. No significant difference was observed in the mechanical fracture resistance of endodontically treated molars restored with traditional resin composite restorations compared to bulk fill flowable composite restorations.

  14. Thickness effect on electric resistivity on polystyrene and carbon black- based composites

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez-Lopez, S; Vigueras-Santiago, E [Laboratorio de Investigacion y Desarrollo de Materiales Avanzados (LIDMA) Facultad de Quimica, Paseo Colon Esquina con Paseo Tollocan, s/n, CP 50000, Toluca (Mexico); Mayorga-Rojas, M; Reyes-Contreras, D, E-mail: eviguerass@uaemex.m [Facultad de Ciencias, Universidad Autonoma del Estado de Mexico. Av. Instituto Literario 100 Ote. C. P. 50000, Toluca (Mexico)

    2009-05-01

    Changes on electrical resistivity were experimentally studied for polystyrene and carbon black-based composites respect to the temperature. 22% w/w carbon black composite films at 30{mu}m, 2mm y 1cm thick were submitted to thermal heating-cooling cycles from room temperature to 100 deg. C, slightly up to T{sub g} of the composite. For each cycle changes on electrical resistivity constituent a hysteresis loop that depends on the sample thickness. The changes during the heating stage could be explained as a consequence of the thermal expansion and mobility of the polymer chains at T{sub g}, producing a disconnecting of the electrical contacts among carbon black particles and an important increasing (200%) of the electrical resistivity. For each cycle, the hysteresis loop was observed in thicker samples, whereas for 30 mu m thickness sample the hysteresis loop was lost after four cycles.

  15. Delamination Detection in Carbon Fibre Reinforced Composites Using Electrical Resistance Measurement

    International Nuclear Information System (INIS)

    Kovalovs, A; Rucevskis, S; Kulakov, V; Aniskevich, A

    2016-01-01

    In the present study 2-D numerical analysis of strip-type laminated composite specimens with and without damage is considered and numerical investigation is carried out by using a finite element method. The surface and oblique resistances are numerically calculated according to the two-probe and four-probe methods. The electrical conductivity of the composite laminate in the longitudinal direction is constant, while the electrical conductivity in the through-thickness direction is used as a variable in the parametric study. The resistance change due to delamination for each case is estimated by comparing the obtained resistance with the corresponding resistance of the specimen without delamination. Applicability and effectiveness of the proposed method are investigated by using various lengths of a delaminated crack in the specimen. (paper)

  16. High-Temperature Ceramic Matrix Composite with High Corrosion Resistance

    Science.gov (United States)

    2010-06-02

    description of high temperature oxidation processes of composite ceramic materials of ZrB2 - SiC and ZrB2-SiC-Zr(Mo)Si2 systems up to high (~1300 °C...analysis was applied using MІN-7 mineralogical microscope and a set of standard immersion liquids with the known values of refraction coefficients...2.0 V) corresponds to the simultaneous formation of ZrO2 zirconium dioxide of monoclinic modification and Zr(OH)4 zirconium hydroxide which is

  17. FIRE-RESISTANCE PROPERTIES RESEARCH OF “WATER GLASS - GRAPHITE MICROPARTICLES” COMPOSITE MATERIAL

    Directory of Open Access Journals (Sweden)

    E. A. Pitukhin

    2016-03-01

    Full Text Available Subject of Research. Research results of the fire-resistance for “water glass - graphite microparticles” composite material (CM are given. The method for fire-resistance test of the micro composition is suggested in order to determine the limit state of the experimental samples under hightemperature action. Method. Test-benchequipment being used for research includes metering devices of temperature and time, as well as laboratory electric furnace PL20 with a maximum temperature in the chamber up to 1250ºC. Fire-resistance limit for the test samples of composite material is determined by the loss of insulating ability (I. For that purpose, the time is obtained from the test beginning with the standard temperature mode up to a limiting condition. Main Results. In accordance with the requirements of regulatory documents fire-resistance limit I15 has been obtained equal to 15 minutes. The qualitative and quantitative phase analysis of the CM structure has been done. By the study of samples by X-ray diffraction and electron microscopy we have determined that the material retains the same chemical structure with a monotonic heating above 700° C. Practical Relevance. The composite material with obtained characteristics can be used as a protective coating for building constructions with the aim of fire-resistance enhancement and fuel hazard reduction.

  18. Preparation of electrodes on cfrp composites with low contact resistance comprising laser-based surface pre-treatment

    KAUST Repository

    Almuhammadi, Khaled Hamdan; Lubineau, Gilles; Alfano, Marco Francesco; Buttner, Ulrich

    2016-01-01

    Various examples are provided related to the preparation of electrodes on carbon fiber reinforced polymer (CFRP) composites with low contact resistance. Laser-based surface preparation can be used for bonding to CFRP composites. In one example, a

  19. Performance testing of elastomeric seal materials under low and high temperature conditions: Final report

    Energy Technology Data Exchange (ETDEWEB)

    BRONOWSKI,DAVID R.

    2000-06-01

    The US Department of Energy Offices of Defense Programs and Civilian Radioactive Waste Management jointly sponsored a program to evaluate elastomeric O-ring seal materials for radioactive material shipping containers. The report presents the results of low- and high-temperature tests conducted on 27 common elastomeric compounds.

  20. Preparation of electrodes on cfrp composites with low contact resistance comprising laser-based surface pre-treatment

    KAUST Repository

    Almuhammadi, Khaled Hamdan

    2016-12-29

    Various examples are provided related to the preparation of electrodes on carbon fiber reinforced polymer (CFRP) composites with low contact resistance. Laser-based surface preparation can be used for bonding to CFRP composites. In one example, a method includes preparing a pretreated target area on a CFRP composite surface using laser pulsed irradiation and bonding an electrode to exposed fibers in the pretreated target area. The surface preparation can allow the electrode to have a low contact resistance with the CFRP composite.

  1. Microstructure and wear resistance of in situ porous TiO/Cu composites

    Science.gov (United States)

    Qin, Qingdong; Huang, Bowei; Li, Wei

    2016-07-01

    An in situ porous TiO/Cu composite is successfully prepared using powder metallurgy by the reaction of Ti2CO and Cu powder. Morphological examination of the composite shows that the porosity of composites lies in the range between 10.2% and 35.2%. Dry sliding un-lubricated wear tests show that the wear resistance of the composite is higher than that of the Cu-Al alloy ingot. The coefficient of friction test shows that, as the volume fraction of the reinforced phase increases, the coefficient of friction decreases. The wear rate variation trend of the oil-lubricated wear test results is similar to that of the un-lubricated wear test results. The coefficient of friction for oil lubrication is similar for different volume fractions of the reinforced phase. The wear resistance of the composite at a sliding velocity of 200 rpm is slightly larger than that at 50 rpm. The porosity of the composites enhances the high-velocity oil-lubricated sliding wear resistance.

  2. The fibre orientation influence in cementitious composite against extreme load resistance

    Science.gov (United States)

    Lovichova, R.; Fornusek, J.; Mara, M.; Kocova, M.; Rihova, Z.

    2018-02-01

    This paper is focused on resistance of steel fibre-reinforced cement composite against impact of the deformable projectile shot from the 7.62 × 39 caliber. Different values of resistance against impact of the projectile are caused by different orientation of the fibres. The influence of formwork position, which is the main cause of the different orientation of the fibres, is investigated. The resistance was examined on thirty slabs made of ultra-high performance fibre-reinforced concrete (UHPFRC). Fifteen specimens with vertical orientation of formwork and fifteen with horizontal orientation of formwork was made. The resistance is classified according to the visual evaluation and local damage measurement on the front side and the rear side of the examined specimens. The experiment shown positive influence of vertically oriented formwork on the slabs according to their resistance against impact of the projectile.

  3. Effect of aggregate graining compositions on skid resistance of Exposed Aggregate Concrete pavement

    Science.gov (United States)

    Wasilewska, Marta; Gardziejczyk, Wladysław; Gierasimiuk, Pawel

    2018-05-01

    The paper presents the evaluation of skid resistance of EAC (Exposed Aggregate Concrete) pavements which differ in aggregate graining compositions. The tests were carried out on concrete mixes with a maximum aggregate size of 8 mm. Three types of coarse aggregates were selected depending on their resistance to polishing which was determined on the basis of the PSV (Polished Stone Value). Basalt (PSV 48), gabbro (PSV 50) and trachybasalt (PSV 52) aggregates were chosen. For each type of aggregate three graining compositions were designed, which differed in the content of coarse aggregate > 4mm. Their content for each series was as follows: A - 38%, B - 50% and C - 68%. Evaluation of the skid resistance has been performed using the FAP (Friction After Polishing) test equipment also known as the Wehner/Schulze machine. Laboratory method enables to compare the skid resistance of different types of wearing course under specified conditions simulating polishing processes. In addition, macrotexture measurements were made on the surface of each specimen using the Elatexure laser profile. Analysis of variance showed that at significance level α = 0.05, aggregate graining compositions as well as the PSV have a significant influence on the obtained values of the friction coefficient μm of the tested EAC pavements. The highest values of the μm have been obtained for EAC with the lowest amount of coarse aggregates (compositions A). In these cases the resistance to polishing of the aggregate does not significantly affect the friction coefficients. This is related to the large areas of cement mortar between the exposed coarse grains. Based on the analysis of microscope images, it was observed that the coarse aggregates were not sufficiently exposed. It has been proved that PSV significantly affected the coefficient of friction in the case of compositions B and C. This is caused by large areas of exposed coarse aggregate. The best parameters were achieved for the EAC pavements

  4. Determining the fracture resistance of advanced SiC fiber reinforced SiC matrix composites

    International Nuclear Information System (INIS)

    Nozawa, T.; Katoh, Y.; Kishimoto, H.

    2007-01-01

    Full text of publication follows: One of the perceived advantages for highly-crystalline and stoichiometric silicon carbide (SiC) and SiC composites, e.g., advanced SiC fiber reinforced chemically-vapor-infiltrated (CVI) SiC matrix composites, is the retention of fast fracture properties after neutron irradiation at high-temperatures (∼1000 deg. C) to intermediate-doses (∼15 dpa). Accordingly, it has been clarified that the maximum allowable stress (or strain) limit seems unaffected in certain irradiation conditions. Meanwhile, understanding the mechanism of crack propagation from flaws, as potential weakest link to cause composite failure, is somehow lacking, despite that determining the strength criterion based on the fracture mechanics will eventually become important considering the nature of composites' fracture. This study aims to evaluate crack propagation behaviors of advanced SiC/SiC and to provide fundamentals on fracture resistance of the composites to define the strength limit for the practical component design. For those purposes, the effects of irreversible energies related to interfacial de-bonding, fiber bridging, and microcrack forming on the fracture resistance were evaluated. Two-dimensional SiC/SiC composites were fabricated by CVI or nano-infiltration and transient-eutectic-phase (NITE ) methods. Hi-Nicalon TM Type-S or Tyranno TM -SA fibers were used as reinforcements. In-plane mode-I fracture resistance was evaluated by the single edge notched bend technique. The key finding is the continuous Load increase with the crack growth for any types of advanced composites, while many studies specified the gradual load decrease for the conventional composites once the crack initiates. This high quasi-ductility appeared due primarily to high friction (>100 MPa) at the fiber/matrix interface using rough SiC fibers. The preliminary analysis based on the linear elastic fracture mechanics, which does not consider the effects of irreversible energy

  5. Interaction of Reinforced Elastomeric Bearings in Bridge Construction

    Directory of Open Access Journals (Sweden)

    Nittmannová Ľubica

    2016-03-01

    Full Text Available The aim of this paper is to demonstrate the behavior of reinforced elastomeric bearings under various loads. They are made of special types of bearings. The experimental verification of these special bearings has been tested on various types of loading. The results of the experimental measurements are compared with the results of the numerical modeling and calculations according to the standard assumptions in STN EN 1337-3. In the conclusion, the results are summarized for the selected types of bearings.

  6. The effect of nylon nanofibers on the dynamic behaviour and the delamination resistance of GFRP composites

    Directory of Open Access Journals (Sweden)

    Garcia Cristobal

    2018-01-01

    Full Text Available Vibrations are responsible for a considerable number of accidents in aircrafts, bridges and other civil engineering structures. Therefore, there is a need to reduce the vibrations on structures made of composite materials. Delamination is a particularly dangerous failure mode for composite materials because delaminated composites can lose up to 60% of their strength and stiffness and still remain unchanged. One of the methods to suppress vibrations and preventing delamination is to incorporate nanofibers into the composite laminates. The aim of the present work is to investigate how nylon nanofibers affect the dynamic behaviour and delamination resistance of glass fibre reinforced polymer (GFRP composites. Experiments and numerical simulations using finite element modelling (FEM analysis are used to estimate the natural frequencies, the damping ratio and inter-laminar strength in GFRP composites with and without nylon nanofibers. It is found that the natural frequencies of the nylon nano-modified composites do not change significantly as compared to the traditional composites. However, nano-modified composites demonstrated a considerable increase in damping ratio and inter-laminar shear strength due to the incorporation of nylon nanofibers. This work contributes to the knowledge about the mechanical and dynamic properties of glass fibre reinforced polymer (GFRP composites with nylon nanofibers.

  7. Fatigue Resistant Bioinspired Composite from Synergistic Two-Dimensional Nanocomponents.

    Science.gov (United States)

    Wan, Sijie; Zhang, Qi; Zhou, Xiaohang; Li, Dechang; Ji, Baohua; Jiang, Lei; Cheng, Qunfeng

    2017-07-25

    Portable and wearable electronics require much more flexible graphene-based electrode with high fatigue life, which could repeatedly bend, fold, or stretch without sacrificing its mechanical properties and electrical conductivity. Herein, a kind of ultrahigh fatigue resistant graphene-based nanocomposite via tungsten disulfide (WS 2 ) nanosheets is synthesized by introducing a synergistic effect with covalently cross-linking inspired by the orderly layered structure and abundant interfacial interactions of nacre. The fatigue life of resultant graphene-based nanocomposites is more than one million times at the stress level of 270 MPa, and the electrical conductivity can be kept as high as 197.1 S/cm after 1.0 × 10 5 tensile testing cycles. These outstanding properties are attributed to the synergistic effect from lubrication of WS 2 nanosheets for deflecting crack propagation, and covalent bonding between adjacent GO nanosheets for bridging crack, which is verified by the molecular dynamics (MD) simulations. The WS 2 induced synergistic effect with covalent bonding offers a guidance for constructing graphene-based nanocomposites with high fatigue life, which have great potential for applications in flexible and wearable electronic devices, etc.

  8. Wear Resistance of TiC Reinforced Cast Steel Matrix Composite

    Directory of Open Access Journals (Sweden)

    Sobula S.

    2017-03-01

    Full Text Available Wear resistance of TiC-cast steel metal matrix composite has been investigated. Composites were obtained with SHSB method known as SHS synthesis during casting. It has been shown the differences in wear between composite and base cast steel. The Miller slurry machine test were used to determine wear loss of the specimens. The slurry was composed of SiC and water. The worn surface of specimens after test, were studied by SEM. Experimental observation has shown that surface of composite zone is not homogenous and consist the matrix lakes. Microscopic observations revealed the long grooves with SiC particles indented in the base alloy area, and spalling pits in the composite area. Due to the presence of TiC carbides on composite layer, specimens with TiC reinforced cast steel exhibited higher abrasion resistance. The wear of TiC reinforced cast steel mechanism was initially by wearing of soft matrix and in second stage by polishing and spalling of TiC. Summary weight loss after 16hr test was 0,14÷0,23 g for composite specimens and 0,90 g for base steel.

  9. Diffusion barrier coatings for high temperature corrosion resistance of advanced carbon/carbon composites

    International Nuclear Information System (INIS)

    Singh Raman, K.S.

    2000-01-01

    Carbon possesses an excellent combination of mechanical and thermal properties, viz., excellent creep resistance at temperatures up to 2400 deg C in non-oxidizing environment and a low thermal expansion coefficient. These properties make carbon a potential material for very high temperature applications. However, the use of carbon materials at high temperatures is considerably restricted due to their extremely poor oxidation resistance at temperatures above 400 deg C. The obvious choice for improving high temperature oxidation resistance of such materials is a suitable diffusion barrier coating. This paper presents an overview of recent developments in advanced diffusion- and thermal-barrier coatings for ceramic composites, with particular reference to C/C composites. The paper discusses the development of multiphase and multi-component ceramic coatings, and recent investigations on the oxidation resistance of the coated C/C composites. The paper also discusses the cases of innovative engineering solutions for traditional problems with the ceramic coatings, and the scope of intelligent processing in developing coatings for the C/C composites. Copyright (2000) AD-TECH - International Foundation for the Advancement of Technology Ltd

  10. Fatigue resistance of teeth restored with cuspal-coverage composite restorations.

    NARCIS (Netherlands)

    Fennis, W.M.M.; Kuijs, R.H.; Kreulen, C.M.; Verdonschot, N.J.J.; Creugers, N.H.J.

    2004-01-01

    PURPOSE: This study assessed the influence of palatal cuspal coverage on the in vitro fatigue resistance and failure mode of Class II resin composite restorations including replacement of the buccal cusp in premolars. MATERIALS AND METHODS: A master model was made of a maxillary premolar with an MOD

  11. Study of the relation between hydrated portland cement composition and leaching resistance

    NARCIS (Netherlands)

    Eijk, van R.J.; Brouwers, H.J.H.

    1998-01-01

    The present paper addresses cement compositions that have an optimal resistance against acid attack and hence, low leaching rates and optimal waste containment. To this end a shrinking core leaching model is used that describes the leaching of metals from a cement sample. This process is directly

  12. Study of hydrated Portland cement composition in regard to leaching resistance

    NARCIS (Netherlands)

    Eijk, van R.J.; Brouwers, H.J.H.

    1997-01-01

    The present paper addresses cement compositions that have an optimal resistance against acid attack and hence, low leaching rates and optimal waste containment. To this end a shrinking core leaching model is used that describes the leaching of metals from a cement sample. This process is directly

  13. In vitro fracture resistance of fiber reinforced cusp-replacing composite restorations.

    NARCIS (Netherlands)

    Fennis, W.M.M.; Tezvergil, A.; Kuijs, R.H.; Lassila, L.V.; Kreulen, C.M.; Creugers, N.H.J.; Vallittu, P.K.

    2005-01-01

    OBJECTIVES: To assess the fracture resistance and failure mode of fiber reinforced composite (FRC) cusp-replacing restorations in premolars. METHODS: Forty-five extracted sound upper premolars were randomly divided into three groups. Identical MOD cavities with simulated buccal cusp fracture and

  14. Decay resistance of wood-plastic composites reinforced with extracted or delignified wood flour

    Science.gov (United States)

    Rebecca E. Ibach; Yao Chen; Nicole M. Stark; Mandla A. Tshabalala; Yongming Fan; Jianmin Gao

    2014-01-01

    The moisture and decay resistance of wood-plastic composites (WPCs) reinforced with extracted or delignified wood flour (WF) was investigated. Three different extractions were preformed: toluene/ethanol (TE), acetone/water (AW), and hot water (HW). Delignification (DL) was performed using a sodium chlorite/acetic acid solution. All WPCs specimens were made with 50% by...

  15. Characterization of fatigue resistance in photochromic composite materials for 3D rewritable optical memory applications

    International Nuclear Information System (INIS)

    Samoylova, Elena; Dallari, William; Allione, Marco; Pignatelli, Francesca; Marini, Lara; Cingolani, Roberto; Diaspro, Alberto; Athanassiou, Athanassia

    2013-01-01

    Highlights: • Fatigue resistance of diarylethene–polymer composites was tested with optical absorption and fluorescence methods upon repetitive UV–VIS irradiation. • Significant differences in fatigue were found in different polymeric matrices and in one-photon and two-photon excitation experiments. • Several explanations for fatigue resistance of the composites are proposed based on the physico-chemical properties of the diarylethenes and polymeric matrices. -- Abstract: Fatigue resistance of the photochromic diarylethene molecules 1,2-bis[2-methylbenzo[b]thyophen-3-yl] -3,3,4,4,5,5-hexafluoro-1-cyclopentene embedded in three different acrylic polymers is studied upon multiple coloration–decoloration cycles. The resistance to photofatigue is found to be different in the three polymeric materials when one-photon excitation was used for the reversible photoconversion experiment. In particular, the photochromic molecules lose their photoisomerization ability faster if they are embedded in poly(methyl methacrylate) (PMMA) with respect to poly(ethyl methacrylate-co-methyl acrylate) (PEMMA) and poly(ethyl methacrylate) (PEMA). We propose several explanations based on the physico-chemical properties of the matrix and of the photochromic molecules. In the case of two-photon excitation, which is necessary for 3D optical writing, the fatigue resistance is found to be poorer than in the one-photon case. The accelerated photodegradation can be assigned to the non-linear nature of interaction between the polymeric composite material and light

  16. Characterization of fatigue resistance in photochromic composite materials for 3D rewritable optical memory applications

    Energy Technology Data Exchange (ETDEWEB)

    Samoylova, Elena, E-mail: Elena.Samoylova@physik.uni-muenchen.de [Nanophysics, Istituto Italiano di Tecnologia, via Morego 30, 16163 Genova (Italy); Dallari, William; Allione, Marco; Pignatelli, Francesca; Marini, Lara; Cingolani, Roberto; Diaspro, Alberto [Nanophysics, Istituto Italiano di Tecnologia, via Morego 30, 16163 Genova (Italy); Athanassiou, Athanassia, E-mail: athanassia.athanassiou@iit.it [Nanophysics, Istituto Italiano di Tecnologia, via Morego 30, 16163 Genova (Italy); Center for Biomolecular Nanotechnologies-Unile, Istituto Italiano di Tecnologia, via Barsanti, 73010 Arnesano, Lecce (Italy)

    2013-06-01

    Highlights: • Fatigue resistance of diarylethene–polymer composites was tested with optical absorption and fluorescence methods upon repetitive UV–VIS irradiation. • Significant differences in fatigue were found in different polymeric matrices and in one-photon and two-photon excitation experiments. • Several explanations for fatigue resistance of the composites are proposed based on the physico-chemical properties of the diarylethenes and polymeric matrices. -- Abstract: Fatigue resistance of the photochromic diarylethene molecules 1,2-bis[2-methylbenzo[b]thyophen-3-yl] -3,3,4,4,5,5-hexafluoro-1-cyclopentene embedded in three different acrylic polymers is studied upon multiple coloration–decoloration cycles. The resistance to photofatigue is found to be different in the three polymeric materials when one-photon excitation was used for the reversible photoconversion experiment. In particular, the photochromic molecules lose their photoisomerization ability faster if they are embedded in poly(methyl methacrylate) (PMMA) with respect to poly(ethyl methacrylate-co-methyl acrylate) (PEMMA) and poly(ethyl methacrylate) (PEMA). We propose several explanations based on the physico-chemical properties of the matrix and of the photochromic molecules. In the case of two-photon excitation, which is necessary for 3D optical writing, the fatigue resistance is found to be poorer than in the one-photon case. The accelerated photodegradation can be assigned to the non-linear nature of interaction between the polymeric composite material and light.

  17. "A New Class of Creep Resistant Oxide/Oxide Ceramic Matrix Composites"

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Mohit Jain, Dr. Ganesh Skandan, Prof. Roger Cannon, Rutgers University

    2007-03-30

    Despite recent progress in the development of SiC-SiC ceramic matrix composites (CMCs), their application in industrial gas turbines for distributed energy (DE) systems has been limited. The poor oxidation resistance of the non-oxide ceramics warrants the use of envrionmental barrier coatings (EBCs), which in turn lead to issues pertaining to life expectancy of the coatings. On the other hand, oxide/oxide CMCs are potential replacements, but their use has been limited until now due to the poor creep resistance at high temperatures, particularly above 1200 oC: the lack of a creep resistant matrix has been a major limiting factor. Using yttrium aluminum garnet (YAG) as the matrix material system, we have advanced the state-of-the-art in oxide/oxide CMCs by introducing innovations in both the structure and composition of the matrix material, thereby leading to high temperature matrix creep properties not achieved until now. An array of YAG-based powders with a unique set of particle characteristics were produced in-house and sintered to full density and compressive creep data was obtained. Aided in part by the composition and the microstructure, the creep rates were found to be two orders of magnitude smaller than the most creep resistant oxide fiber available commercially. Even after accounting for porosity and a smaller matrix grain size in a practical CMC component, the YAG-based matrix material was found to creep slower than the most creep resistant oxide fiber available commercially.

  18. Evaluation of the Impact Resistance of Various Composite Sandwich Beams by Vibration Tests

    Directory of Open Access Journals (Sweden)

    Amir Shahdin

    2011-01-01

    Full Text Available Impact resistance of different types of composite sandwich beams is evaluated by studying vibration response changes (natural frequency and damping ratio. This experimental works will help aerospace structural engineer in assess structural integrity using classification of impact resistance of various composite sandwich beams (entangled carbon and glass fibers, honeycomb and foam cores. Low velocity impacts are done below the barely visible impact damage (BVID limit in order to detect damage by vibration testing that is hardly visible on the surface. Experimental tests are done using both burst random and sine dwell testing in order to have a better confidence level on the extracted modal parameters. Results show that the entangled sandwich beams have a better resistance against impact as compared to classical core materials.

  19. Environment-friendly wood fibre composite with high bonding strength and water resistance

    Science.gov (United States)

    Ji, Xiaodi; Dong, Yue; Nguyen, Tat Thang; Chen, Xueqi; Guo, Minghui

    2018-04-01

    With the growing depletion of wood-based materials and concerns over emissions of formaldehyde from traditional wood fibre composites, there is a desire for environment-friendly binders. Herein, we report a green wood fibre composite with specific bonding strength and water resistance that is superior to a commercial system by using wood fibres and chitosan-based adhesives. When the mass ratio of solid content in the adhesive and absolute dry wood fibres was 3%, the bonding strength and water resistance of the wood fibre composite reached the optimal level, which was significantly improved over that of wood fibre composites without adhesive and completely met the requirements of the Chinese national standard GB/T 11718-2009. Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) characterizations revealed that the excellent performance of the binder might partly be due to the amide linkages and hydrogen bonding between wood fibres and the chitosan-based adhesive. We believe that this strategy could open new insights into the design of environment-friendly wood fibre composites with high bonding strength and water resistance for multifunctional applications.

  20. Resistance of Bonded Composite Restorations on Fractures of Endodontically Treated Teeth

    Directory of Open Access Journals (Sweden)

    AR Daneshkazemi

    2005-01-01

    Full Text Available Introduction: This study was performed to evaluate the effect of dentine bonding agents and Glass Ionomer cement beneath composite restorations and its resistance on fractures of endodontically treated teeth. Material and Methods: Forty sound maxillary teeth were selected; ten of them for positive control, and on the rest, RCT and MOD cavity preparations were done with standard methods. Then, the teeth were divided to four groups: 1-Sound teeth for positive control. 2-Prepared without any restoration for negative control. 3-Prepared and restored with Vitrabond(3M, USA, Single bond(3M, USA and Z100(3M, USA resin composite. 4-Prepared and restored by Single bond and Z100 resin composite. Specimens were subjected to compressive load by Instron 8502 until fracture occurred. Results: Group 1 showed the highest resistance to compressive forces followed by group 4,3&2 respectively. ANOVA, t test and Chi-square tests indicated significant difference between all the groups. Conclusion: Use of dentine bonding agents and resin composite increases resistance of endodontically treated teeth to fractures more than teeth restored with sandwich of glass ionomer cements, dentine bonding agents and resin composite.

  1. High compressive resistance drainage geo composites; Geocompuestos de drenaje de alta resistencia a compresion

    Energy Technology Data Exchange (ETDEWEB)

    Castelo Nolla, J.; Gutierrez Cuevas, J.

    2014-02-01

    There are several typologies of drainage geo composites available in the market which can be classified according to their structures as: cus pated, mono filaments, geo nets and those products formed by the combination of a draining blanket with a series of mini-pipes. Each one of them has its own range of compressive resistances. There are applications, such as are the new cells of landfills or mines and roads or railways over large embankments, where the pressure exerted on the geo composite exceeds the compressive resistance of the majority of these typologies. For all this applications, besides providing and adequate flow capacity, it must be ensured that the chosen typology is able to withstand the required loading without collapsing and guaranteeing an adequate factor of safety. This article will expose that, currently, the only typology of drainage geo composites that can bear these loadings while maintaining its drainage properties is the tri-planar geo net. (Author)

  2. Self-Diagnosis of Damage in Carbon Fiber Reinforced Composites Using Electrical Residual Resistance Measurement

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Ji Ho [KAERI, Daejeon (Korea, Republic of)

    2009-08-15

    The objective of this research was to develop a practical integrated approach using extracted features from electrical resistance measurements and coupled electromechanical models of damage, for in-situ damage detection and sensing in carbon fiber reinforced plastic(CFRP) composites. To achieve this objective, we introduced specific known damage (in terms of type, size, and location) into CFRP laminates and established quantitative relationships with the electrical resistance measurements. For processing of numerous measurement data, an autonomous data acquisition system was devised. We also established a specimen preparation procedure and a method for electrode setup. Coupon and panel CFRP laminate specimens with several known damage were tested. Coupon specimens with various sizes of artificial delaminations obtained by inserting Teflon film were manufactured and the resistance was measured. The measurement results showed that increase of delamination size led to increase of resistance implying that it is possible to sense the existence and size of delamination. A quasi-isotropic panel was manufactured and electrical resistance was measured. Then three different sizes of holes were drilled at a chosen location. The panel was prepared using the established procedures with six electrode connections on each side making a total of twenty-four electrodes. Vertical, horizontal, and diagonal pairs of electrodes were chosen and the resistance was measured. The measurement results showed the possibility of the established measurement system for an in-situ damage detection method for CFRP composite structures.

  3. The Impact of Morphology and Composition on the Resistivity and Oxidation Resistance of Metal Nanostructure Films

    Science.gov (United States)

    Stewart, Ian Edward

    Printed electronics, including transparent conductors, currently rely on expensive materials to generate high conductivity devices. Conductive inks for thick film applications utilizing inkjet, aerosol, and screen printing technologies are often comprised of expensive and rare silver particles. Thin film applications such as organic light emitting diodes (OLEDs) and organic photovoltaics (OPVs) predominantly employ indium tin oxide (ITO) as the transparent conductive layer which requires expensive and wasteful vapor deposition techniques. Thus an alternative to silver and ITO with similar performance in printed electronics warrants considerable attention. Copper nanomaterials, being orders of magnitude cheaper and more abundant than silver or indium, solution-coatable, and exhibiting a bulk conductivity only 6 % less than silver, have emerged as a promising candidate for incorporation in printed electronics. First, we examine the effect of nanomaterial shape on the conductivity of thick films. The inks used in such films often require annealing at elevated temperature in order to sinter the silver nanoparticles together and obtain low resistivities. We explore the change in morphology and resistivity that occurs upon heating thick films of silver nanowires (of two different lengths, Ag NWs), nanoparticles (Ag NPs), and microflakes (Ag MFs) deposited from water at temperatures between 70 and 400 °C. At the lowest temperatures, longer Ag NWs exhibited the lowest resistivity (1.8 x 10-5 O cm), suggesting that the resistivity of thick films of silver nanostructures is dominated by the contact resistance between particles. This result supported previous research showing that junction resistance between Ag NWs in thin film conductors also dominates optoelectronic performance. Since the goal is to replace silver with copper, we perform a similar analysis by using a pseudo-2D rod network modeling approach that has been modified to include lognormal distributions in length

  4. Elastically stretchable thin film conductors on an elastomeric substrate

    Science.gov (United States)

    Jones Harris, Joyelle Elizabeth

    Imagine a large, flat screen television that can be rolled into a small cylinder after purchase in the store and then unrolled and mounted onto the wall of a home. The electronic devices within the television must be able to withstand large deformation and tensile strain. Consider a robot that is covered with an electronic skin that simulates human skin. The skin would enable the machine to lift an elderly person with care and sensitivity. The skin will endure repeated deformation with the highest tensile strains being experienced at the robot's joints. These applications and many others will benefit from stretchable electronic circuitry. While several different methods have been employed to create stretchable electronics, all methods use a common tool -- stretchable conductors. Therefore, the goal of this thesis work was to fabricate elastically stretchable conductors that can be used in stretchable electronics. We deposited Au thin films on an elastomeric substrate, and the resulting conductors remained electrically continuous when stretched by 30% and more. We developed photolithographic processes that can be used to pattern elastically stretchable conductors with a 10 mum resolution. We fabricated bi-level stretchable conductors that are separated by an elastomeric insulator and are electrically connected through via holes in the insulator. We applied our bi-level conductors to create a stretchable resistor-inductor-capacitor (RLC) circuit with a tunable resonant frequency. We also used stretchable conductors to measure action potentials in biological samples. This thesis describes the fabrication and application of our elastically stretchable conductors.

  5. Adjustment of Part Properties for an Elastomeric Laser Sintering Material

    Science.gov (United States)

    Wegner, A.; Ünlü, T.

    2018-03-01

    Laser sintering of polymers is gaining more and more importance within the field of small series productions. Polyamide 12 is predominantly used, although a variety of other materials are also available for the laser sintering process. For example, elastomeric, rubberlike materials offer very different part property profiles. Those make the production of flexible parts like, e.g., sealings, flexible tubes or shoe soles possible because they offer high part ductility and low hardness. At the chair for manufacturing technology, a new elastomeric laser sintering material has been developed and then commercialized by a spin-off from university. The aim of the presented study was the analysis of the new material's properties. Proof was found that Shore hardness can be modified by varying the parameter settings. Therefore, the correlation between process parameters, energy input, Shore hardness and other part properties like mechanical properties were analyzed. Based on these results, suitable parameter settings were established which lead to the possibility of producing parts with different Shore hardnesses.

  6. Recycled Aluminium Cans/Eggshell Composites: Evaluation of Mechanical and Wear Resistance Properties

    Directory of Open Access Journals (Sweden)

    J.O. Agunsoye

    2015-03-01

    Full Text Available Aluminium based metal matrix composites have been produced from recycled aluminium cans and 150µm sized eggshell particles using a stir cast process. The mechanical properties of the control and aluminium can/eggshell composites produced have been investigated. The microstructures of the aluminium can/eggshell composites were examined with the aids of Scanning Electron Microscope (SEM after the sample surfaces have been carefully prepared and etched with aqueous solution of 0.5 cm3 nitric acid. Micrographs revealed that there was a homogenous distribution of eggshell particles within the aluminium can matrix. An indication of effective stirring action during the melting process. The wear resistance was also investigated under different applied loads (6 to 14 N on an abrasive surface emery paper of grade 220. The results revealed an increase in Young’s modulus of elasticity and yield stress from 1,206.45 and 50.23 Mpa respectively of the cast aluminium can with 0 % eggshell particle to the maximum of 3,258.87and 73.2 MPa of aluminium can/12 % eggshell composites. The hardness values increased from 66.23 to 75.13 VN. There was a gradual increase in wear rate of the tested samples as the applied load increased. However, the wear resistance of the aluminium can/6 % eggshell and aluminium can/12 % eggshell composites increased significantly. Hence, recycling of aluminium cans and eggshells can be harnessed into development of useful engineering metal matrix composite materials.

  7. Piezoelectric and mechanical properties of fatigue resistant, self-healing PZT–ionomer composites

    International Nuclear Information System (INIS)

    James, N K; Lafont, U; Van der Zwaag, S; Groen, W A

    2014-01-01

    Piezoelectric ceramic–polymer composites with 0–3 connectivity were fabricated using lead zirconium titanate (PZT) powder dispersed in an ionomer (Zn ionomer) and its reference ethylene methacrylic acid copolymer (EMAA) polymer matrix. The PZT–Zn ionomer and PZT–EMAA composites were prepared by melt extrusion followed by hot pressing. The effects of poling conditions such as temperature, time and electric field on the piezoelectric properties of the composites were investigated. The experimentally observed piezoelectric charge coefficient and dielectric constant of the composites were compared with theoretical models. The results show that PZT–Zn ionomer composites have better piezoelectric properties compared to PZT–EMAA composites. The static and fatigue properties of the composites were investigated. The PZT–Zn ionomer composites were found to have excellent fatigue resistance even at strain levels of 4%. Due to the self-healing capabilities of the ionomer matrix, the loss of piezoelectric properties after high strain tensile cyclic loading could be partially recovered by thermal healing. (paper)

  8. Piezoelectric and mechanical properties of fatigue resistant, self-healing PZT-ionomer composites

    Science.gov (United States)

    James, N. K.; Lafont, U.; van der Zwaag, S.; Groen, W. A.

    2014-05-01

    Piezoelectric ceramic-polymer composites with 0-3 connectivity were fabricated using lead zirconium titanate (PZT) powder dispersed in an ionomer (Zn ionomer) and its reference ethylene methacrylic acid copolymer (EMAA) polymer matrix. The PZT-Zn ionomer and PZT-EMAA composites were prepared by melt extrusion followed by hot pressing. The effects of poling conditions such as temperature, time and electric field on the piezoelectric properties of the composites were investigated. The experimentally observed piezoelectric charge coefficient and dielectric constant of the composites were compared with theoretical models. The results show that PZT-Zn ionomer composites have better piezoelectric properties compared to PZT-EMAA composites. The static and fatigue properties of the composites were investigated. The PZT-Zn ionomer composites were found to have excellent fatigue resistance even at strain levels of 4%. Due to the self-healing capabilities of the ionomer matrix, the loss of piezoelectric properties after high strain tensile cyclic loading could be partially recovered by thermal healing.

  9. Fracture Resistance of Premolars Restored by Various Types and Placement Techniques of Resin Composites

    Directory of Open Access Journals (Sweden)

    Horieh Moosavi

    2012-01-01

    Full Text Available To verify the fracture resistance of premolars with mesioocclusodistal preparations restored by different resin composites and placement techniques. Sixty premolars were randomly divided into two groups based on type of composite resin: Filtek P60 or Nulite F, and then each group was separated into three subgroups: bulk, centripetal, and fiber insert according to the type of placement method (n=10. Single-bond adhesive system was used as composite bonding according to the manufacturer's instructions. Specimens were restored in Groups 1, 2, and 3 with Filtek P60 and in Groups 4, 5, and 6 with Nulite F. After being stored 24 hours at 37∘C, a 4 mm diameter steel sphere in a universal testing machine was applied on tooth buccal and lingual cusps at a cross-head speed of 5 mm/min until fracture occurred. Groups 3 and 6 showed higher fracture resistance than Groups 1, 2, 4, and 5. Among the placement techniques, the fiber insert method had a significant effect, but the type of composite was ineffective. The insertion technique in contrast to the type of material had a significant influence on the fracture resistance of premolar teeth.

  10. Insulin resistance, body composition, and fat distribution in obese children with nonalcoholic fatty liver disease.

    Science.gov (United States)

    Yang, Hye Ran; Chang, Eun Jae

    2016-01-01

    The aim of this study was to evaluate the influence of body composition, especially distribution of body fat, and insulin resistance on nonalcoholic fatty liver disease (NAFLD) in obese children. One hundred obese children (66 boys, 34 girls) with (n=60) and without NAFLD (n=40) were assessed. Anthropometry, laboratory tests, abdominal ultrasonography, and dual energy x-ray absorption metry (DXA) were evaluated in all subjects. Subject age and measurements of liver enzymes, γ- glutamyl transpeptidase (γGT), uric acid, high-density lipoprotein cholesterol, and insulin resistance were significantly different between the non-NAFLD group and NAFLD group. Body fat and trunk fat percentage were significantly different between the two groups (pfat percentage was not (p=0.683). Insulin resistance correlated significantly with body fat and trunk fat percentages, age, liver enzymes, γGT, and uric acid in obese children. Multiple logistic regression analysis indicated that insulin resistance and trunk fat percentage significantly affected the development of NAFLD in obese children. Body fat, especially abdominal fat, influences the development of insulin resistance and subsequent NAFLD in obese children. Therefore, body composition measurement using DXA, in conjunction with biochemical tests, may be beneficial in evaluating obese children with NAFLD.

  11. Effect of composition on corrosion resistance of high-alloy austenitic stainless steel weld metals

    International Nuclear Information System (INIS)

    Marshall, P.I.; Gooch, T.G.

    1993-01-01

    The corrosion resistance of stainless steel weld metal in the ranges of 17 to 28% chromium (Cr), 6 to 60% nickel (Ni), 0 to 9% molybdenum (Mo), and 0.0 to 0.37% nitrogen (N) was examined. Critical pitting temperatures were determined in ferric chloride (FeCl 3 ). Passive film breakdown potentials were assessed from potentiodynamic scans in 3% sodium chloride (NaCl) at 50 C. Potentiodynamic and potentiostatic tests were carried out in 30% sulfuric acid (H 2 SO 4 ) ar 25 C, which was representative of chloride-free acid media of low redox potential. Metallographic examination and microanalysis were conducted on the test welds. Because of segregation of alloying elements, weld metal pitting resistance always was lower than that of matching composition base steel. The difference increased with higher Cr, Mo, and N contents. Segregation also reduced resistance to general corrosion in H 2 SO 4 , but the effect relative to the base steel was less marked than with chloride pitting. Segregation of Cr, Mo, and N in fully austenitic deposits decreased as the Ni' eq- Cr' eq ratio increased. Over the compositional range studied, weld metal pitting resistance was dependent mainly on Mo content and segregation. N had less effect than in wrought alloys. Both Mo and N enhanced weld metal corrosion resistance in H 2 SO 4

  12. Co nanoparticles induced resistive switching and magnetism for the electrochemically deposited polypyrrole composite films.

    Science.gov (United States)

    Xu, Zedong; Gao, Min; Yu, Lina; Lu, Liying; Xu, Xiaoguang; Jiang, Yong

    2014-10-22

    The resistive switching behavior of Co-nanoparticle-dispersed polypyrrole (PPy) composite films is studied. A novel design method for resistive random access memory (ReRAM) is proposed. The conducting polymer films with metal nanocrystal (NC)-dispersed carbon chains induce the spontaneous oxidization of the conducting polymer at the surface. The resistive switching behavior is achieved by an electric field controlling the oxygen ion mobility between the metal electrode and the conducting polymer film to realize the mutual transition between intrinsic conduction (low resistive state) and oxidized layer conduction (high resistive state). Furthermore, the formation process of intrinsic conductive paths can be effectively controlled in the conducting polymer ReRAM using metal NCs in films because the inner metal NCs induce electric field lines converging around them and the intensity of the electric field at the tip of NCs can greatly exceed that of the other region. Metal NCs can also bring new characteristics for ReRAM, such as magnetism by dispersing magnetic metal NCs in polymer, to obtain multifunctional electronic devices or meet some special purpose in future applications. Our works will enrich the application fields of the electromagnetic PPy composite films and present a novel material for ReRAM devices.

  13. A guide to the suitability of elastomeric seal materials for use in radioactive material transport packages

    International Nuclear Information System (INIS)

    Vince, D.J.

    2004-01-01

    Elastomeric seals are a frequently favoured method of sealing Radioactive Material Transport (RMT) packages. The sealing technology has been proven for many years in a wide range of industrial applications. The requirements of the RMT package applications, however, are significantly different from those commonly found in other industries. This guide outlines the Regulatory performance requirements placed on an RMT package sealing system by TS-R-1, and then summarises the material, environment and geometry characteristics of elastomeric seals relevant to RMT applications. Tables in the guide list typical material properties for a range of elastomeric materials commonly used in RMT packages

  14. Study of Thermal Fatigue Resistance of a Composite Coating Made by a Vacuum Fusion Sintering Method

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    Thermal fatigue behavior of a Ni-base alloy chromium carbide composite coating made by a vacuum fusion sintering method are discussed. Results show that thermal fatigue behavior is associated with cyclic upper temperature and coating thickness. As the thickness of the coating decreases, the thermal fatigue resistance increases. The thermal fatigue resistance cuts down with the thermal cyclic upper temperature rising. The crack growth rate decreases with the increase in cyclic number until crack arrests. Thermal fatigue failure was not found along the interface of the coating/matrix. The tract of thermal fatigue crack cracks along the interfaces of phases.

  15. Utilization of composite fecal samples for detection of anthelmintic resistance in gastrointestinal nematodes of cattle.

    Science.gov (United States)

    George, Melissa M; Paras, Kelsey L; Howell, Sue B; Kaplan, Ray M

    2017-06-15

    Recent reports indicate that anthelmintic resistance in gastrointestinal nematodes of cattle is becoming increasingly prevalent worldwide. Presently, the fecal egg count reduction test (FECRT) is the only means available for detection of resistance to anthelmintics in cattle herds at the farm level. However, the FECRT is labor and cost intensive, and consequently is only rarely performed on cattle farms unless for research purposes. If costs could be reduced, cattle producers might be more likely to pursue drug resistance testing on their farms. One approach to reducing the cost of the FECRT, is the use of composite fecal samples for performing fecal egg counts (FEC), rather than conducting FEC on fecal samples from 15 to 20 individual animals. In this study FECRT were performed on 14 groups of cattle using both individual and composite FEC methods To measure how well the results of composite sampling reproduce those of individual sampling, Lin's Concordance Correlation Coefficient was utilized to describe both the linear relationship between methods and the slope and y-intercept of the line relating the data sets. There was little difference between the approaches with 98% agreement in mean FEC found between methods Mean FEC based on individual counts ranged between 0 and 670.6 eggs per gram of feces, indicating that the results of this study are applicable to a wide range of FEC levels. Standard error of the mean FEC and range of FEC are reported for each group prior to and following treatment to describe the variability of the data set. There was greater than 95% agreement in drug efficacy between individual and composite sampling methods, demonstrating composite sampling is appropriate to evaluate drug efficacy. Notably, for all groups tested the efficacy calculated by composite sampling was within the 95% confidence interval for efficacy calculated using individual sampling. The use of composite samples was shown to reduce the number of FEC required by 79

  16. Wettability and interface considerations in advanced heat-resistant Ni-base composites

    International Nuclear Information System (INIS)

    Asthana, R.; Mileiko, S.T.; Sobczak, N.

    2006-01-01

    Oxide fiber-reinforced Ni-base composites have long been considered as attractive heat-resistant materials. After several decades of active research, however, interest in these materials began to decline around mid-1990's due chiefly to 1) a lack of manufacturing technology to grow inexpensive single-crystal oxide fibers to be used in structural composites, and 2) fiber strength loss during processing due to chemical interactions with reactive solutes in the matrix. The cost disadvantage has been mitigated to a large extent by the development of innovative fiber fabrication processes such as the Internal Crystallization Method (ICM) that produces monocrystalline oxide fibers in a cost-effective manner. Fiber strength loss has been an equally restrictive issue but recent work has shown that it may be possible to design creep-resistant composites even when fiber surface reconstruction from chemical interactions has degraded the strength of extracted fibers tested outside the matrix. The key issue is the optimization of the composite- and interface structure. Reaction-formed defects may be healed by the matrix (or a suitable coating material) so that the fiber residing in the matrix may exhibit diminished sensitivity to flaws as compared to fibers extracted from the matrix and tested in isolation of the matrix. Generally, the Ni-base/Al 2 O 3 composites exhibit acceptable levels of wettability and interface strength (further improved with the aid of reactive solutes), which are required for elevated-temperature creep-resistance. In order to harness the full potential of these composites, the quality of the interface as manifested in the fiber/matrix wettability, interface composition, interphase morphology, and interface strength must be designed. We identify key issues related to the measurement of contact angle, interface strength, and chemical and structural properties at the fiber/matrix interface in the Ni/alumina composites, and present the current state-of the

  17. Wear resistance and electrical properties of functionally graded epoxy-resin/silica composites

    International Nuclear Information System (INIS)

    Rihan, Y. A.; Abd El-Bary, B.

    2012-12-01

    In this paper graded Silica/Epoxy composite fabricated by controlled mold filling to obtain a stepwise graded structure. The generated graded structure was controlled by the w 1% content of silica particulates of size range from (45 μm-250 μm). Microstructural characterization was conducted using Scanning Electron Microscope (SEM). Electrical properties were conducted in High Voltage-Lab using Sphere-Plate Electrode System and Insulating resistance equipment s. Wear characteristics were studied using Block-on-Ring wear testing machine for the different layers of the graded silica/epoxy composites, The prepared materials are used as coating materials for the floors of chemical laboratories. (Author)

  18. Dependence of Seebeck coefficient on a load resistance and energy conversion efficiency in a thermoelectric composite

    International Nuclear Information System (INIS)

    Yamashita, Osamu; Odahara, Hirotaka; Ochi, Takahiro; Satou, Kouji

    2007-01-01

    The thermo-emf ΔV and current ΔI generated by imposing the alternating temperature gradients (ATG) at a period of T and the steady temperature gradient (STG) on a thermoelectric (TE) composite were measured as a function of t, where t is the lapsed time and T was varied from 60 to or ∞ s. The STG and ATG were produced by imposing steadily and alternatively a source voltage V in the range from 1.0 to 4.0 V on two Peltier modules sandwiching a composite. ΔT, ΔV, ΔI and V P oscillate at a period T and their waveforms vary significantly with a change of T, where ΔV and V P are the voltage drops in a load resistance R L and in resistance R P of two modules. The resultant Seebeck coefficient |α| = |ΔV|/ΔT of a composite under the STG was found to be expressed as |α| = |α 0 |(1 - R comp /R T ), where R T is the total resistance of a circuit for measuring the output signals and R comp is the resistance of a composite. The effective generating power ΔW eff has a local maximum at T = 960 s for the p-type composite and at T = 480 s for the n-type one. The maximum energy conversion efficiency η of the p- and n-type composites under the ATG produced by imposing a voltage of 4.0 V at an optimum period were 0.22 and 0.23% at ΔT eff = 50 K, respectively, which are 42 and 43% higher than those at ΔT = 42 K under the STG. These maximum η for a TE composite sandwiched between two Peltier modules, were found to be expressed theoretically in terms of R P , R T , R L , α P and α, where α P and α are the resultant Seebeck coefficients of Peltier modules and a TE composite

  19. Muscle function and body composition profile in adolescents with restrictive anorexia nervosa: Does resistance training help?

    OpenAIRE

    Fernández del Valle, María; Larumbe Zabala, Eneko; Morandé Lavín, Gonzalo; Pérez Ruiz, Margarita

    2016-01-01

    The aim of this study was to analyze the effects of short-term resistance training on the body composition profile and muscle function in a group of Anorexia Nervosa restricting type (AN-R) patients. The sample consisted of AN-R female adolescents (12.8 ± 0.6 years) allocated into the control and intervention groups (n¼18 each). Body composition and relative strength were assessed at baseline, after 8 weeks and 4 weeks following the intervention. Body mass index (BMI) increased throughout...

  20. Thermal shock resistances of a bonding material of C/C composite and copper

    International Nuclear Information System (INIS)

    Kurumada, Akira; Oku, Tatsuo; Kawamata, Kiyohiro; Motojima, Osamu; Noda, Nobuaki; McEnaney, B.

    1997-01-01

    The purpose of this study is to contribute to the development and the safety design of plasma facing components for fusion reactor devices. We evaluated the thermal shock resistance and the thermal shock fracture toughness of a bonding material which was jointed a carbon-fiber-reinforced carbon composite (C/C composite) to oxygen-free copper. We also examined the microstructures of the bonding layers using a scanning electron microscope before and after thermal shock tests. The bonding material did not fracture during thermal shock tests. However, thermal cracks and delamination cracks were observed in the bonding layers. (author)

  1. Insulin resistance, exercise capacity and body composition in subjects with two hypertensive parents

    DEFF Research Database (Denmark)

    Andersen, U B; Dige-Petersen, H; Ibsen, H

    1999-01-01

    OBJECTIVE: To study insulin resistance in subjects with strong genetic predisposition to essential hypertension, compared with non-disposed subjects. SUBJECTS: Thirty normotensive subjects aged 18-35 years whose parents both had essential hypertension, and 30 age- and sex matched subjects whose...... correlated to abdominal fat mass but not to insulin sensitivity. CONCLUSION: Subjects with a strong genetic predisposition to essential hypertension had increased diastolic blood pressure compared with subjects with normotensive parents, but they were not insulin resistant. This may be due to the subjects...... for the difference between the means; -0.5; -7.9), but the insulin sensitivity index was similar: 312 versus 362 I(2) min(-1) pmol(-1) kg(-1) (28; -129). The two groups were similar in terms of body composition, exercise capacity and composition of usual diet. Resting and 24-h diastolic blood pressures were...

  2. Effect of Processing Conditions on Fracture Resistance and Cohesive Laws of Binderfree All-Cellulose Composites

    DEFF Research Database (Denmark)

    Goutianos, Stergios; Arévalo, R.; Sørensen, Bent F.

    2014-01-01

    molecules during the drying process. Defibrilation of the raw cellulose material is done in wet medium in a paper-like process. Panels with different refining time were tested and it was found than an increase in fibre fibrillation results in a lower fracture resistance. © 2014 Springer Science......The fracture properties of all-cellulose composites without matrix were studied using Double Cantilever Beam (DCB) sandwich specimens loaded with pure monotonically increasing bending moments, which give stable crack growth. The experiments were conducted in an environmental scanning electron...... microscope to a) perform accurate measurements of both the fracture energy for crack initiation and the fracture resistance and b) observe the microscale failure mechanisms especially in the the wake of the crack tip. Since the mechanical behaviour of the all-cellulose composites was non-linear, a general...

  3. Study of the effect of composition and construction of material on sub-bandage pressure during dynamic loading of a limb in vitro.

    Science.gov (United States)

    Kumar, Bipin; Das, Apurba; Alagirusamy, R

    2013-01-01

    Internal stress in a compression bandage wrapped over a limb in vitro is expected to reduce over time because of fatigue which may occur due to repetitive and prolonged variations in the extension of the bandage during posture change and exercise. This phenomenon may cause significant variation in the sub-bandage pressure over time. To examine the effect of composition and construction of material on the sub-bandage pressure variation over time in the dynamic state of a limb in the laboratory. Yarns comprising fibers of polyester, viscose, cotton and elastomeric yarn were used to prepare different knitted bandage samples having varying thread densities in the structure. A leg-segment prototype was used for the measurement of the interface pressure over a mannequin limb to analyse different bandages under similar dynamic conditions. The pressure drop in the dynamic state of the mannequin limb was greater than that in the static state. The mean pressure drop in 2 h in the dynamic state was greater by >30% for bandages made of pure cotton or viscose yarns than for bandages having elastomeric yarns in their structure. At the same applied tension, increasing the number of yarns per unit length in the bandage structure resulted in a smaller drop in pressure in the dynamic mode. Elastomeric yarn improves the elasticity and fatigue resistance of the bandage. Therefore, these yarns should be used in bandages to obtain sustained compression effects under dynamic conditions.

  4. The correlation of grain boundary composition in irradiated stainless steel with IASCC resistance

    International Nuclear Information System (INIS)

    Jacobs, A.J.; Wozadlo, G.P.; Nakata, K.; Kasahara, S.; Okada, T.; Kawano, S.; Suzuki, S.

    1993-01-01

    Scanning transmission electron microscopy (STEMP) analysis were conducted on a group of irradiated Type-316 stainless steels (SS), in an continuing effort to correlate grain boundary composition with IASCC resistance. The latter property was measured by either one of two means: an in-reactor (boiling water reactor) swelling-mandrel-type test or a laboratory constant extension rate tensile (CERT) test. Possibly because of their basically different nature, the two types of test yielded different correlations with the STEM results. The in-reactor results showed two regimes, one in which IASCC resistance remained essentially unchanged with increasing radiation-induced segregation/depletion (RIS), and another in which IASCC resistance increased with decreasing RIS. The CERT test results, on the other hand, showed a monotonic increase in IASCC resistance with decreasing RIS, with a transition range of RIS in which IASCC resistance was very high or very low. It appeared from the two sets of results that in the reactor environment, a low degree of RIS was necessary but not sufficient for high IASCC resistance, and in the laboratory environment, a low degree of RIS was necessary and sufficient

  5. Erosion resistance and adhesion of composite metal/ceramic coatings produced by plasma spraying

    OpenAIRE

    Ramm , D.; Hutchings , I.; Clyne , T.

    1993-01-01

    Ceramic coatings can exhibit greater erosion resistance than most metallic coatings. Such coatings are conveniently produced by thermal spraying. Unfortunately, thermally sprayed ceramic coatings often exhibit poor adhesion, partly as a consequence of the development of residual stresses during spraying and subsequent cooling. Composite coatings have been studied using aluminium/alumina deposits on steel substrates. The incorporation of ceramics within a ductile matrix has potential for sharp...

  6. Rhodium and Hafnium Influence on the Microstructure, Phase Composition, and Oxidation Resistance of Aluminide Coatings

    OpenAIRE

    Maryana Zagula-Yavorska; Małgorzata Wierzbińska; Jan Sieniawski

    2017-01-01

    A 0.5 μm thick layer of rhodium was deposited on the CMSX 4 superalloy by the electroplating method. The rhodium-coated superalloy was hafnized and aluminized or only aluminized using the Chemical vapour deposition method. A comparison was made of the microstructure, phase composition, and oxidation resistance of three aluminide coatings: nonmodified (a), rhodium-modified (b), and rhodium- and hafnium-modified (c). All three coatings consisted of two layers: the additive layer and the interdi...

  7. Elastomeric polymer resonant waveguide grating based pressure sensor

    International Nuclear Information System (INIS)

    Song, Fuchuan; Xie, Antonio Jou; Seo, Sang-Woo

    2014-01-01

    In this paper, we demonstrate an elastomeric polymer resonant waveguide grating structure to be used as a pressure sensor. The applied pressure is measured by optical resonance spectrum peak shift. The sensitivity—as high as 86.74 pm psi −1 or 12.58 pm kPa −1 —has been experimentally obtained from a fabricated sensor. Potentially, the sensitivity of the demonstrated sensor can be tuned to different pressure ranges by the choices of elastic properties and layer thicknesses of the waveguide and cladding layers. The simulation results agree well with experimental results and indicate that the dominant effect on the sensor is the change of grating period when external pressure is applied. Based on the two-dimensional planar structure, the demonstrated sensor can be used to measure applied surface pressure optically, which has potential applications for optical ultrasound imaging and pressure wave detection/mapping

  8. Seismic isolation of nuclear power plants using elastomeric bearings

    Science.gov (United States)

    Kumar, Manish

    Seismic isolation using low damping rubber (LDR) and lead-rubber (LR) bearings is a viable strategy for mitigating the effects of extreme earthquake shaking on safety-related nuclear structures. Although seismic isolation has been deployed in nuclear structures in France and South Africa, it has not seen widespread use because of limited new build nuclear construction in the past 30 years and a lack of guidelines, codes and standards for the analysis, design and construction of isolation systems specific to nuclear structures. The nuclear accident at Fukushima Daiichi in March 2011 has led the nuclear community to consider seismic isolation for new large light water and small modular reactors to withstand the effects of extreme earthquakes. The mechanical properties of LDR and LR bearings are not expected to change substantially in design basis shaking. However, under shaking more intense than design basis, the properties of the lead cores in lead-rubber bearings may degrade due to heating associated with energy dissipation, some bearings in an isolation system may experience net tension, and the compression and tension stiffness may be affected by the horizontal displacement of the isolation system. The effects of intra-earthquake changes in mechanical properties on the response of base-isolated nuclear power plants (NPPs) were investigated using an advanced numerical model of a lead-rubber bearing that has been verified and validated, and implemented in OpenSees and ABAQUS. A series of experiments were conducted at University at Buffalo to characterize the behavior of elastomeric bearings in tension. The test data was used to validate a phenomenological model of an elastomeric bearing in tension. The value of three times the shear modulus of rubber in elastomeric bearing was found to be a reasonable estimate of the cavitation stress of a bearing. The sequence of loading did not change the behavior of an elastomeric bearing under cyclic tension, and there was no

  9. Design of a new bottom antireflective coating composition for KrF resist

    Science.gov (United States)

    Mizutani, Kazuyoshi; Momota, Makoto; Aoai, Toshiaki; Yagihara, Morio

    1999-06-01

    A study for a new organic bottom antireflective coating (BARC) composition is described. A structural design of a light-absorbing dye was most important because dye structure not only plays a role in eliminating reflection from a substrate but also shows influence on dry etch rate of BARC material to a considerable extent. For example, an anthracene moiety with large absorption at 248 nm had undesirable dry etch resistance. 3-Hydroxy-2-naphthoic acid moiety was found to be one of suitable dyes for KrF BARC compositions, and the polymer bearing the dye showed enough absorbance and good erodability in dry etch. The BARC polymer was eroded as one and a half times faster than a novolak resin, and a little faster than an anthracene incorporated polymer. The result was discussed from the concepts of Ohnishi parameter and the ring parameter for dry etch durability of resist materials. BARC polymer should be thermoset by hard bake to eliminate intermixing with resist compositions. The BARC polymer bearing hydroxy group which is useful for a crosslinking reaction was thermoset in the presence of melamine-formaldehyde crosslinker and an acid catalyst after baking over 200 degrees C.

  10. Fracture resistance of class IV fiber-reinforced composite resin restorations: An in vitro study

    Directory of Open Access Journals (Sweden)

    P S Praveen Kumar

    2017-01-01

    Full Text Available Objectives: The aim of this study was to evaluate fracture resistance of incisal edge fractures (Class IV restored with a Glass Fiber-reinforced Composite (FRC. Materials and Methods: Twenty-four extracted sound maxillary central incisors were randomly divided into two groups. Group I (control contained untreated teeth. Samples in experimental groups II were prepared by cutting the incisal (one-third part of the crown horizontally and was subjected to enamel preparations, then restored with a Glass FRC. Fracture resistance was evaluated as Newton's for samples tested in a Hounsfield universal testing machine. Failure modes were examined microscopically. Results: Mean peak failure load (Newton's observed in Glass Fiber-reinforced Nanocomposite was 863.50 ± 76.12. The experimental group showed similar types of failure modes with the majority occurring as cohesive and mixed type. 58% of the teeth in Glass FRC group fractured below the cementoenamel junction. Conclusion: Using Fiber reinforced composite substructure under conventional composites in Class IV restorations, the fracture resistance of the restored incisal edge could be increased.

  11. A Damage Resistance Comparison Between Candidate Polymer Matrix Composite Feedline Materials

    Science.gov (United States)

    Nettles, A. T

    2000-01-01

    As part of NASAs focused technology programs for future reusable launch vehicles, a task is underway to study the feasibility of using the polymer matrix composite feedlines instead of metal ones on propulsion systems. This is desirable to reduce weight and manufacturing costs. The task consists of comparing several prototype composite feedlines made by various methods. These methods are electron-beam curing, standard hand lay-up and autoclave cure, solvent assisted resin transfer molding, and thermoplastic tape laying. One of the critical technology drivers for composite components is resistance to foreign objects damage. This paper presents results of an experimental study of the damage resistance of the candidate materials that the prototype feedlines are manufactured from. The materials examined all have a 5-harness weave of IM7 as the fiber constituent (except for the thermoplastic, which is unidirectional tape laid up in a bidirectional configuration). The resin tested were 977-6, PR 520, SE-SA-1, RS-E3 (e-beam curable), Cycom 823 and PEEK. The results showed that the 977-6 and PEEK were the most damage resistant in all tested cases.

  12. Towards mechanisms-guided resistivity-based monitoring of damage evolution in laminated composites

    KAUST Repository

    Lubineau, Gilles

    2013-04-05

    A convenient health monitoring technique for detecting degradation in laminated composite is to monitor the change of electrical resistance along multiple conduction paths within the structure. Yet, the relations between the global modification of resistivity and the exact underlying damage map is still unclear that makes diffcult to interpret these nondestructive-testing results. The challenge is then to be able to reconstruct from these global observation the underlying damage map. This is even more diffcult due to the numerous underlying damage mechanisms that can take place either at the inter laminar of intra laminar level. This paper intends to provide some preliminary insights about strategies to recover the damage state based only on global measurements. We focus here on transverse cracking detection. We introduce the homogenization process that defines at the meso scale an equivalent homogeneous ply that is energetically equivalent to the cracked one. This can be used as a first tool to reconstruct damage maps based on global resistivity measurements.

  13. Linear dimensional stability of elastomeric impression materials over time.

    Science.gov (United States)

    Garrofé, Analía B; Ferrari, Beatriz A; Picca, Mariana; Kaplan, Andrea E

    2011-01-01

    The purpose of this study was to evaluate the linear dimensional stability of different elastomeric impression materials over time. A metal mold was designed with its custom trays, which were made of thermoplastic sheets (Sabilex sheets 0.125 mm thick). Three impressions were taken of it with each of the following: the polyvinylsiloxane Examix-GC-(AdEx), Aquasil-Dentsply-(AdAq) and Panasil-Kettenbach-(AdPa), and the polydimethylsiloxane Densell-Dental Medrano-(CoDe), Speedex-Coltene-(CoSp) and Lastic-Kettenbach-(CoLa). All impressions were taken with putty and light-body materials using a one-step technique. Standardized digital photographs were taken at different time intervals (0, 15, 30, 60, 120 minutes; 24 hours; 7 and 14 days), using an "ad-hoc" device, and analyzed using software (Image Tool) by measuring the distance between lines previously made at the top of the mold. The results were analyzed by ANOVA for repeated measures. The initial and final values for mean and SD were: AdEx: 1.32 (0.01) and 1.31 (0.00); AdAq: 1.32 (0.00) and 1.32 (0.00), AdPa: 1.327 (0.006) and 1.31 (0.00); CoDe: 1.32 (0.00) and 1.32 (0.01); CoSp: 1.327 (0.006) and 1.31 (0.00), CoLa: 1.327 (0.006) and 1.303 (0.006). Statistical evaluation showed that both material and time have significant effects. Under the conditions in this study we conclude that time would significantly affect the lineal dimensional stability of elastomeric impression materials.

  14. Fatigue resistance and microleakage of CAD/CAM ceramic and composite molar crowns.

    Science.gov (United States)

    Kassem, Amr S; Atta, Osama; El-Mowafy, Omar

    2012-01-01

    The aim of this study was to determine effect of compressive cyclic loading on fatigue resistance and microleakage of monolithic CAD/CAM molar ceramic and composite crowns. Thirty-two extracted molars were prepared to receive CEREC crowns according to manufacturer's guidelines using a special paralleling device (Parallel-A-Prep). Sixteen feldspathic ceramic crowns (VITABLOCS Mark II) (VMII) and 16 resin-composite crowns (Paradigm-MZ100 blocks) (PMZ) were milled using a CEREC-3D machine. Eight crowns of each group were cemented to their respective teeth using self-etching resin cement (Panavia-F-2.0) (PAN), and eight were cemented using self-adhesive resin cement (RelyX-Unicem-Clicker) (RXU). Following storage for 1 week in water, specimens were subjected to uniaxial compressive cyclic loading in an Instron testing machine at 12 Hz for 1,000,000 cycles. Load was applied at the central fossa, and the cycle range was 60-600 N. Specimens were then subjected to microleakage testing. Data were statistically analyzed using factorial ANOVA and Post Hoc (Tukey HSD) tests. All composite crowns survived compressive cyclic loading without fracture, while three ceramic crowns from the subgroup cemented with RXU developed surface cracks at the center of occlusal surfaces, extending laterally. Microleakage scores of ceramic crowns cemented with PAN were significantly lower than those of the other three subgroups (p < 0.05). After 1,000,000 cycles of compressive cyclic loading, PMZ composite molar crowns were more fatigue-resistant than VMII ceramic crowns. Cement type had a significant effect on fatigue resistance of the ceramic crowns but not the composite ones. Microleakage scores of ceramic crowns cemented with PAN were significantly lower than those of the other subgroups (p < 0.05). © 2011 by The American College of Prosthodontists.

  15. Engineered elastomeric proteins with dual elasticity can be controlled by a molecular regulator.

    Science.gov (United States)

    Cao, Yi; Li, Hongbin

    2008-08-01

    Elastomeric proteins are molecular springs that confer excellent mechanical properties to many biological tissues and biomaterials. Depending on the role performed by the tissue or biomaterial, elastomeric proteins can behave as molecular springs or shock absorbers. Here we combine single-molecule atomic force microscopy and protein engineering techniques to create elastomeric proteins that can switch between two distinct types of mechanical behaviour in response to the binding of a molecular regulator. The proteins are mechanically labile by design and behave as entropic springs with an elasticity that is governed by their configurational entropy. However, when a molecular regulator binds to the protein, it switches into a mechanically stable state and can act as a shock absorber. These engineered proteins effectively mimic and combine the two extreme forms of elastic behaviour found in natural elastomeric proteins, and thus represent a new type of smart nanomaterial that will find potential applications in nanomechanics and material sciences.

  16. Correlation between in vitro Elastomeric Force Degradation and Glass Transition Temperature determined by Dynamic Mechanical Analysis

    Directory of Open Access Journals (Sweden)

    Manu Krishnan

    2012-01-01

    Conclusion: Tg can be considered as a dependable parameter in envisaging the force properties of an elastomeric chain. Clinically, it suggested that a polymer with higher Tg can give higher or optimum levels of force for tooth movement.

  17. Electrical Resistance Based Damage Modeling of Multifunctional Carbon Fiber Reinforced Polymer Matrix Composites

    Science.gov (United States)

    Hart, Robert James

    In the current thesis, the 4-probe electrical resistance of carbon fiber-reinforced polymer (CFRP) composites is utilized as a metric for sensing low-velocity impact damage. A robust method has been developed for recovering the directionally dependent electrical resistivities using an experimental line-type 4-probe resistance method. Next, the concept of effective conducting thickness was uniquely applied in the development of a brand new point-type 4-probe method for applications with electrically anisotropic materials. An extensive experimental study was completed to characterize the 4-probe electrical resistance of CFRP specimens using both the traditional line-type and new point-type methods. Leveraging the concept of effective conducting thickness, a novel method was developed for building 4-probe electrical finite element (FE) models in COMSOL. The electrical models were validated against experimental resistance measurements and the FE models demonstrated predictive capabilities when applied to CFRP specimens with varying thickness and layup. These new models demonstrated a significant improvement in accuracy compared to previous literature and could provide a framework for future advancements in FE modeling of electrically anisotropic materials. FE models were then developed in ABAQUS for evaluating the influence of prescribed localized damage on the 4-probe resistance. Experimental data was compiled on the impact response of various CFRP laminates, and was used in the development of quasi- static FE models for predicting presence of impact-induced delamination. The simulation-based delamination predictions were then integrated into the electrical FE models for the purpose of studying the influence of realistic damage patterns on electrical resistance. When the size of the delamination damage was moderate compared to the electrode spacing, the electrical resistance increased by less than 1% due to the delamination damage. However, for a specimen with large

  18. Chemical resistance, void content and tensile properties of oil palm/jute fibre reinforced polymer hybrid composites

    International Nuclear Information System (INIS)

    Jawaid, M.; Khalil, H.P.S. Abdul; Bakar, A. Abu; Khanam, P. Noorunnisa

    2011-01-01

    Tri layer hybrid composites of oil palm empty fruit bunches (EFB) and jute fibres was prepared by keeping oil palm EFB as skin material and jute as the core material and vice versa. The chemical resistance, void content and tensile properties of oil palm EFB/Jute composites was investigated with reference to the relative weight of oil palm EFB/Jute, i.e. 4:1, the fibre loading was optimized and different layering pattern were investigated. It is found from the chemical resistance test that all the composites are resistant to various chemicals. It was observed that marked reduction in void content of hybrid composites in different layering pattern. From the different layering pattern, the tensile properties were slightly higher for the composite having jute as skin and oil palm EFB as core material. Scanning electron microscopy (SEM) was used to study tensile fracture surfaces of different composites.

  19. Erosion resistance of composite materials on titanium, zirconium and aluminium nitride base under the electron beam effect

    International Nuclear Information System (INIS)

    Verkhoturov, A.D.; Kuzenkova, M.A.; Slutskin, M.G.; Kravchuk, L.A.

    1977-01-01

    Erosion resistance of composites based on nitrides of titanium, zirconium and aluminium to spark and electron beam processing has been studied. The erosion resistance in spark processing is shown to depend on specific electric resistance of the alloys. TiN-AlN and ZrN-AlN alloys containing more than 70% AlN (with specific electric resistance more than 10 6 -10 7 ohm/cm) caot be processed by spark method. It is shown that erosion of the composites by an electron beam depends primarily on the rate of evaporation of the components

  20. Evaluation of the cytotoxicity of elastomeric ligatures after sterilisation with 0.25% peracetic acid.

    Science.gov (United States)

    Pithon, Matheus Melo; dos Santos, Rogerio Lacerda; Judice, Renata Lima Pasini; de Assuncao, Paulo Sergio; Restle, Luciana

    2013-11-01

    Sterilisation using peracetic acid (PAA) has been advocated for orthodontic elastic bands. However, cane-loaded elastomeric ligatures can also become contaminated during processing, packaging, and manipulation before placement in the oral cavity and are therefore susceptible, and possible causes, of cross-contamination. To test the hypothesis that 0.25% peracetic acid (PAA), following the sterilisation of elastomers, influences the cytotoxicity of elastomeric ligatures on L929 cell lines. Four hundred and eighty silver elastomeric ligatures were divided into 4 groups of 120 ligatures to produce, Group TP (latex natural, bulk pack, TP Orthodontics), Group M1 (Polyurethane, bulk pack, Morelli), Group M2 (Polyurethane, cane-loaded, Morelli) and Group U (Polyurethane, cane-loaded, Uniden). Of the 120 ligatures in each group, 100 were sterilised in 0.25% PAA at time intervals (N = 20) of 1 hour, 2 hours, 3 hours, 4 hours and 5 hours. The 20 remaining elastomeric ligatures in each group were not sterilised and served as controls. Cytotoxicity was assessed using L929 cell lines and a dye-uptake method. Analysis of variance (ANOVA), followed by the Tukey post hoc test (p < 0.05) determined statistical relevance. There was a significant difference between TP, Morelli and Uniden elastomerics (p < 0.05), but no difference between the two types of Morelli elastomerics at the 1 hour time interval. In addition, there was a significant difference between Group CC and the other groups assessed, except between Groups CC and TP at the 1 hour time interval. The non-sterilised elastomeric ligatures showed similar cell viability to that observed after 1 hour of standard sterilisation. PAA did not significantly influence the cytotoxicity of elastomeric ligatures after a sterilisation time of 1 hour and is therefore recommended for clinical use.

  1. Multilayer oxidation resistant coating for SiC coated carbon/carbon composites at high temperature

    International Nuclear Information System (INIS)

    Li Hejun; Jiao Gengsheng; Li Kezhi; Wang Chuang

    2008-01-01

    To prevent carbon/carbon (C/C) composites from oxidation, a multilayer coating based on molybdenum disilicide and titanium disilicide was formed using a two-step pack cementation technique in argon atmosphere. XRD and SEM analysis showed that the internal coating was a bond SiC layer that acts as a buffer layer, and that the external multilayer coating formed in the two-step pack cementation was composed of two MoSi 2 -TiSi 2 -SiC layers. This coating, which is characterized by excellent thermal shock resistance, could effectively protect the composites from exposure to an oxidizing atmosphere at 1773 K for 79 h. The oxidation of the coated C/C composites was primarily due to the reaction of C/C matrix and oxygen diffusing through the penetrable cracks in the coating

  2. Radiation-resistant composite scintillators based on GSO and GPS grains

    Energy Technology Data Exchange (ETDEWEB)

    Boyarintsev, A.Yu. [Institute for Scintillation Materials, National Academy of Sciences of Ukraine, 60 Nauki Avenue, 61001 Kharkiv (Ukraine); Galunov, N.Z. [Institute for Scintillation Materials, National Academy of Sciences of Ukraine, 60 Nauki Avenue, 61001 Kharkiv (Ukraine); V.N. Karasin Kharkov National University, 4 Svobody Sq., 61022 Kharkiv (Ukraine); Gerasymov, Ia.V.; Karavaeva, N.L. [Institute for Scintillation Materials, National Academy of Sciences of Ukraine, 60 Nauki Avenue, 61001 Kharkiv (Ukraine); Krech, A.V., E-mail: AntonKrech@gmail.com [Institute for Scintillation Materials, National Academy of Sciences of Ukraine, 60 Nauki Avenue, 61001 Kharkiv (Ukraine); Levchuk, L.G.; Popov, V.F. [National Science Center, Kharkov Institute of Physics and Technology, 1 Akademicheskaya Str., 61108 Kharkiv (Ukraine); Sidletskiy, O.Ts. [Institute for Scintillation Materials, National Academy of Sciences of Ukraine, 60 Nauki Avenue, 61001 Kharkiv (Ukraine); Sorokin, P.V. [National Science Center, Kharkov Institute of Physics and Technology, 1 Akademicheskaya Str., 61108 Kharkiv (Ukraine); Tarasenko, O.A. [Institute for Scintillation Materials, National Academy of Sciences of Ukraine, 60 Nauki Avenue, 61001 Kharkiv (Ukraine)

    2017-01-01

    The effect of irradiation on the scintillation light output, optical transmittance, and luminescent spectra of composite scintillators based on grains of single crystals Gd{sub 2}SiO{sub 5}:Ce (GSO) and Gd{sub 2}Si{sub 2}O{sub 7}:Ce (GPS) is studied. The dielectric gel Sylgard-184 is the base and the binder for the grains inside the composite scintillator. The paper presents and analyzes the results obtained for the scintillators exposed by 10 MeV electrons from the linear electron accelerator at room temperature. The exposure doses D≤250 Mrad. The dose rate is 0.2 or 1500 Mrad/h. The study has shown that the composite scintillators based on the grains of GSO and GPS are radiation-resistant over the range of the irradiation.

  3. Wear Resistance Properties Reinforcement Using Nano-Al/Cu Composite Coating in Sliding Bearing Maintenance.

    Science.gov (United States)

    Liu, Hongtao; Li, Zhixiong; Wang, Jianmei; Sheng, Chenxing; Liu, Wanli

    2018-03-01

    Sliding bearing maintenance is crucial for reducing the cost and extending the service life. An efficient and practical solution is to coat a restorative agent onto the worn/damaged bearings. Traditional pure-copper (Cu) coating results in a soft surface and poor abrasion resistance. To address this issue, this paper presents a nano-composite repairing coating method. A series of nano-Al/Cu coatings were prepared on the surface of 45 steel by composite electro-brush plating (EBP). Their micro-hardness was examined by a MHV-2000 Vickers hardness tester, and tribological properties by a UMT-2M Micro-friction tester, 3D profiler and SEM. Then, the influence of processing parameters such as nano-particle concentration and coating thickness on the micro-hardness of nano-Al/Cu coating was analyzed. The experimental analysis results demonstrate that, when the nano-Al particle concentration in electrolyte was 10 g/L, the micro-hardness of the composite coating was 1.1 times as much as that of pure-Cu coating. When the Al nano-particle concentration in electrolyte was 20 g/L, the micro-hardness of the composite coating reached its maximum value (i.e., 231.6 HV). Compared with the pure-Cu coating, the hardness and wear resistance of the nano-composite coating were increased, and the friction coefficient and wear volume were decreased, because of the grain strengthening and dispersion strengthening. The development in this work may provide a feasible and effective nano-composite EBP method for sliding bearing repair.

  4. Static characterization of a soft elastomeric capacitor for non destructive evaluation applications

    International Nuclear Information System (INIS)

    Saleem, Hussam; Laflamme, Simon; Zhang, Huanhuan; Geiger, Randall; Kessler, Michael; Rajan, Krishna

    2014-01-01

    A large and flexible strain transducer consisting of a soft elastomeric capacitor (SEC) has been proposed by the authors. Arranged in a network setup, the sensing strategy offers tremendous potential at conducting non-destructive evaluation of large-scale surfaces. In prior work, the authors have demonstrated the performance of the sensor at tracking strain history, localizing cracks, and detecting vibration signatures. In this paper, we characterize the static performance of the proposed SEC. The characterization includes sensitivity of the signal, and temperature and humidity dependences. Tests are conducted on a simply supported aluminum beam subjected to bending as well as on a free standing sensor. The performance of the SEC is compared against off-the-shelf resistance-based strain gauges with resolution of 1 με. A sensitivity of 1190 pF/ε is obtained experimentally, in agreement with theory. Results also show the sensor linearity over the given level of strain, showing the promise of the SEC at monitoring of surface strain

  5. Static characterization of a soft elastomeric capacitor for non destructive evaluation applications

    Science.gov (United States)

    Saleem, Hussam; Laflamme, Simon; Zhang, Huanhuan; Geiger, Randall; Kessler, Michael; Rajan, Krishna

    2014-02-01

    A large and flexible strain transducer consisting of a soft elastomeric capacitor (SEC) has been proposed by the authors. Arranged in a network setup, the sensing strategy offers tremendous potential at conducting non-destructive evaluation of large-scale surfaces. In prior work, the authors have demonstrated the performance of the sensor at tracking strain history, localizing cracks, and detecting vibration signatures. In this paper, we characterize the static performance of the proposed SEC. The characterization includes sensitivity of the signal, and temperature and humidity dependences. Tests are conducted on a simply supported aluminum beam subjected to bending as well as on a free standing sensor. The performance of the SEC is compared against off-the-shelf resistance-based strain gauges with resolution of 1 μɛ. A sensitivity of 1190 pF/ɛ is obtained experimentally, in agreement with theory. Results also show the sensor linearity over the given level of strain, showing the promise of the SEC at monitoring of surface strain.

  6. Analysis of the Influence of Food Colorings in Esthetic Orthodontic Elastomeric Ligatures.

    Science.gov (United States)

    Dias da Silva, Vanessa; de Lima, Eduardo Martinelli S; Dias, Caroline; Osório, Leandro Berni

    2016-01-01

    The purpose of this study was to evaluate in vitro the color changes of esthetic orthodontic elastomeric ligatures of different shades when exposed to four food colorings commonly found in the diet of patients. The sample consisted of esthetic orthodontic elastomeric ligatures in the colors pearl, pearl blue, pearl white and colorless, which were immersed for 72 hours in five different solutions: distilled water (control group), coffee, tea, Coca-Cola ® and wine. The color changes of the esthetic orthodontic elastomeric ligatures were measured with the aid of a spectrophotometer, at T1 - as provided by the manufacturer; and T2 - after colorings process. The results indicated that the esthetic orthodontic elastomeric ligatures of all initial hues are susceptible to pigmentation. Among the evaluated colors, all changed the finished look and the color of the samples tested. In ascending order, the color of the samples was as follows: distilled water, Coca-Cola ® , black tea, wine and coffee. The substances that have a greater potential for pigmentation in esthetic orthodontic elastomeric ligatures were black tea, wine and coffee, respectively. All shades of esthetic orthodontic elastomeric ligatures are susceptible to color change.

  7. The correlation of low-velocity impact resistance of graphite-fiber-reinforced composites with matrix properties

    Science.gov (United States)

    Bowles, Kenneth J.

    1988-01-01

    Summarized are basic studies that were conducted to correlate the impact resistance of graphite-fiber-reinforced composites with polymer matrix properties. Three crosslinked epoxy resins and a linear polysulfone were selected as composite matrices. As a group, these resins possess a significantly large range of mechanical properties. The mechanical properties of the resins and their respective composites were measured. Neat resin specimens and unidirectional and crossply composite specimens were impact tested with an instrumented dropweight tester. Impact resistances of the specimens were assesseed on the basis of loading capability, energy absorption, and extent of damage.

  8. Optimal Electrode Selection for Electrical Resistance Tomography in Carbon Fiber Reinforced Polymer Composites

    Science.gov (United States)

    Escalona Galvis, Luis Waldo; Diaz-Montiel, Paulina; Venkataraman, Satchi

    2017-01-01

    Electrical Resistance Tomography (ERT) offers a non-destructive evaluation (NDE) technique that takes advantage of the inherent electrical properties in carbon fiber reinforced polymer (CFRP) composites for internal damage characterization. This paper investigates a method of optimum selection of sensing configurations for delamination detection in thick cross-ply laminates using ERT. Reduction in the number of sensing locations and measurements is necessary to minimize hardware and computational effort. The present work explores the use of an effective independence (EI) measure originally proposed for sensor location optimization in experimental vibration modal analysis. The EI measure is used for selecting the minimum set of resistance measurements among all possible combinations resulting from selecting sensing electrode pairs. Singular Value Decomposition (SVD) is applied to obtain a spectral representation of the resistance measurements in the laminate for subsequent EI based reduction to take place. The electrical potential field in a CFRP laminate is calculated using finite element analysis (FEA) applied on models for two different laminate layouts considering a set of specified delamination sizes and locations with two different sensing arrangements. The effectiveness of the EI measure in eliminating redundant electrode pairs is demonstrated by performing inverse identification of damage using the full set and the reduced set of resistance measurements. This investigation shows that the EI measure is effective for optimally selecting the electrode pairs needed for resistance measurements in ERT based damage detection. PMID:28772485

  9. Static resistance function for steel-plate composite (SC) walls subject to impactive loading

    Energy Technology Data Exchange (ETDEWEB)

    Bruhl, Jakob C., E-mail: jbruhl@purdue.edu; Varma, Amit H., E-mail: ahvarma@purdue.edu; Kim, Joo Min, E-mail: kim1493@purdue.edu

    2015-12-15

    Highlights: • An idealized static resistance function for SC walls is proposed. • The influence of design parameters on static resistance is explained. • SDOF models can accurately estimate global response of SC walls to missile impact. - Abstract: Steel-plate composite (SC) walls consist of a plain concrete core reinforced with two steel faceplates on the surfaces. Modules (consisting of steel faceplates, shear connectors and tie-bars) can be shop-fabricated and shipped to the site for erection and concrete casting, which expedites construction schedule and thus economy. SC structures have recently been used in nuclear power plant designs and are being considered for the next generation of small modular reactors. Design for impactive and impulsive loading is an important consideration for SC walls in safety-related nuclear facilities. The authors have previously developed design methods to prevent local failure (perforation) of SC walls due to missile impact. This paper presents the development of static resistance functions for use in single-degree-of-freedom (SDOF) analyses to predict the maximum displacement response of SC walls subjected to missile impact and designed to resist local failure (perforation). The static resistance function for SC walls is developed using results of numerical analyses and parametric studies conducted using benchmarked 3D finite element (FE) models. The influence of various design parameters are discussed and used to develop idealized bilinear resistance functions for SC walls with fixed edges and simply supported edges. Results from dynamic non-linear FE analysis of SC panels subjected to rigid missile impact are compared with the maximum displacements predicted by SDOF analyses using the bilinear resistance function.

  10. Static resistance function for steel-plate composite (SC) walls subject to impactive loading

    International Nuclear Information System (INIS)

    Bruhl, Jakob C.; Varma, Amit H.; Kim, Joo Min

    2015-01-01

    Highlights: • An idealized static resistance function for SC walls is proposed. • The influence of design parameters on static resistance is explained. • SDOF models can accurately estimate global response of SC walls to missile impact. - Abstract: Steel-plate composite (SC) walls consist of a plain concrete core reinforced with two steel faceplates on the surfaces. Modules (consisting of steel faceplates, shear connectors and tie-bars) can be shop-fabricated and shipped to the site for erection and concrete casting, which expedites construction schedule and thus economy. SC structures have recently been used in nuclear power plant designs and are being considered for the next generation of small modular reactors. Design for impactive and impulsive loading is an important consideration for SC walls in safety-related nuclear facilities. The authors have previously developed design methods to prevent local failure (perforation) of SC walls due to missile impact. This paper presents the development of static resistance functions for use in single-degree-of-freedom (SDOF) analyses to predict the maximum displacement response of SC walls subjected to missile impact and designed to resist local failure (perforation). The static resistance function for SC walls is developed using results of numerical analyses and parametric studies conducted using benchmarked 3D finite element (FE) models. The influence of various design parameters are discussed and used to develop idealized bilinear resistance functions for SC walls with fixed edges and simply supported edges. Results from dynamic non-linear FE analysis of SC panels subjected to rigid missile impact are compared with the maximum displacements predicted by SDOF analyses using the bilinear resistance function.

  11. Highly Magneto-Responsive Elastomeric Films Created by a Two-Step Fabrication Process

    KAUST Repository

    Marchi, Sophie

    2015-08-24

    An innovative method for the preparation of elastomeric magnetic films with increased magneto-responsivity is presented. Polymeric films containing aligned magnetic microchains throughout their thickness are formed upon the magnetophoretic transport and assembly of microparticles during polymer curing. The obtained films are subsequently magnetized at a high magnetic field of 3 T directed parallel to the orientation of the microchains. We prove that the combination of both alignment of the particles along a favorable direction during curing and the subsequent magnetization of the solid films induces an impressive increase of the films’ deflection. Specifically, the displacements reach few millimeters, up to 85 times higher than those of the nontreated films with the same particle concentration. Such a process can improve the performance of the magnetic films without increasing the amount of magnetic fillers and, thus, without compromising the mechanical properties of the resulting composites. The proposed method can be used for the fabrication of magnetic films suitable as components in systems in which large displacements at relatively low magnetic fields are required, such as sensors and drug delivery or microfluidic systems, especially where remote control of valves is requested to achieve appropriate flow and mixing of liquids.

  12. Highly Magneto-Responsive Elastomeric Films Created by a Two-Step Fabrication Process

    KAUST Repository

    Marchi, Sophie; Casu, Alberto; Bertora, Franco; Athanassiou, Athanassia; Fragouli, Despina

    2015-01-01

    An innovative method for the preparation of elastomeric magnetic films with increased magneto-responsivity is presented. Polymeric films containing aligned magnetic microchains throughout their thickness are formed upon the magnetophoretic transport and assembly of microparticles during polymer curing. The obtained films are subsequently magnetized at a high magnetic field of 3 T directed parallel to the orientation of the microchains. We prove that the combination of both alignment of the particles along a favorable direction during curing and the subsequent magnetization of the solid films induces an impressive increase of the films’ deflection. Specifically, the displacements reach few millimeters, up to 85 times higher than those of the nontreated films with the same particle concentration. Such a process can improve the performance of the magnetic films without increasing the amount of magnetic fillers and, thus, without compromising the mechanical properties of the resulting composites. The proposed method can be used for the fabrication of magnetic films suitable as components in systems in which large displacements at relatively low magnetic fields are required, such as sensors and drug delivery or microfluidic systems, especially where remote control of valves is requested to achieve appropriate flow and mixing of liquids.

  13. Fatigue resistance and stiffness of glass fiber-reinforced urethane dimethacrylate composite.

    Science.gov (United States)

    Narva, Katja K; Lassila, Lippo V J; Vallittu, Pekka K

    2004-02-01

    Retentive properties of cast metal clasps decrease over time because of metal fatigue. Novel fiber-reinforced composite materials are purported to have increased fatigue resistance compared with metals and may offer a solution to the problem of metal fatigue. The aim of this study was to investigate the fatigue resistance and stiffness of E-glass fiber-reinforced composite. Twelve cylindrical fiber-reinforced composite test cylinders (2 mm in diameter and 60 mm in length) were made from light-polymerized urethane dimethacrylate monomer with unidirectional, single-stranded, polymer preimpregnated E-glass fiber reinforcement. Six cylinders were stored in dry conditions and 6 in distilled water for 30 days before testing. Fatigue resistance was measured by a constant-deflection fatigue test with 1 mm of deflection across a specimen span of 11 mm for a maximum of 150,000 loading cycles. The resistance of the cylinder against deflection was measured (N) and the mean values of the force were compared by 1-way analysis of variance (alpha = .05). The flexural modulus (GPa) was calculated for the dry and water-stored cylinders for the first loading cycle. Scanning electron microscopy was used to assess the distribution of the fibers, and the volume percent of fibers and polymer were assessed by combustion analysis. The test cylinders did not fracture due to fatigue following 150,000 loading cycles. Flexural modulus at the first loading cycle was 18.9 (+/- 2.9) GPa and 17.5 (+/- 1.7) GPa for the dry and water-stored cylinders, respectively. The mean force required to cause the first 1-mm deflection was 33.5 (+/- 5.2) N and 37.7 (+/- 3.6) N for the dry and water stored cylinders, respectively; however, the differences were not significant. After 150,000 cycles the mean force to cause 1-mm deflection was significantly reduced to 23.4 (+/- 8.5) N and 13.1 (+/- 3.5) N, respectively (P fiber- and polymer-rich areas within the specimens and indicated that individual fibers were

  14. Highly sensitive piezo-resistive graphite nanoplatelet-carbon nanotube hybrids/polydimethylsilicone composites with improved conductive network construction.

    Science.gov (United States)

    Zhao, Hang; Bai, Jinbo

    2015-05-13

    The constructions of internal conductive network are dependent on microstructures of conductive fillers, determining various electrical performances of composites. Here, we present the advanced graphite nanoplatelet-carbon nanotube hybrids/polydimethylsilicone (GCHs/PDMS) composites with high piezo-resistive performance. GCH particles were synthesized by the catalyst chemical vapor deposition approach. The synthesized GCHs can be well dispersed in the matrix through the mechanical blending process. Due to the exfoliated GNP and aligned CNTs coupling structure, the flexible composite shows an ultralow percolation threshold (0.64 vol %) and high piezo-resistive sensitivity (gauge factor ∼ 10(3) and pressure sensitivity ∼ 0.6 kPa(-1)). Slight motions of finger can be detected and distinguished accurately using the composite film as a typical wearable sensor. These results indicate that designing the internal conductive network could be a reasonable strategy to improve the piezo-resistive performance of composites.

  15. EFFECT OF SURFACE SEALING ON STAIN RESISTANCE OF A NANO-HYBRID RESIN COMPOSITE*

    Directory of Open Access Journals (Sweden)

    Günçe SAYGI

    2015-04-01

    Full Text Available Purpose: This study investigated the influence of sealant application on stain resistance of a nanohybrid resin composite compared to the efficacy of a bonding agent used as a surface sealant on prolonging color stability of the resin composite. Materials and Methods: 28 disc-shaped materials were prepared from a nano-hybrid resin composite Filtek Z550 and assigned to four groups: G1K: nonsealed; G2:Adper Single Bond; G3: Fortify ; G4: Biscover LV. After 24 h storage in distilled water at 37˚C, all specimens were subjected to thermocycling and immersed into coffee solution. Color measurements were performed using spectrophotometer (VITA Easyshade; Vident according to CIEL*a*b* system. Results: Color change values were significantly different among the groups in each evaluation period except for after thermocycling (p<0.05. For 7 days evaluation period, the difference between G3 and G4 group was statistically significant while G4 exhibited statistically significant differences (p<0.05 and p<0.0001 respectively compared to control (G1 in 14 day whereas no significant difference was found between GI and GII in 28-day evaluation period. However, ΔE values of sealed specimens (GIII, GIV differed significantly from non-sealed (GI specimens after 28 days of immersion in coffee solution (p<0.05 and p<0.0001 respectively. Conclusion: It may be concluded that using a bonding agent as a surface sealant does not increase stain resistance of resin composites of the sealants evaluated. Biscover LV showed the highest efficacy to prolong color stability of the resin composite.

  16. Electrical resistivity and thermal properties of compatibilized multi-walled carbon nanotube/polypropylene composites

    Directory of Open Access Journals (Sweden)

    A. Szentes

    2012-06-01

    Full Text Available The electrical resistivity and thermal properties of multi-walled carbon nanotube/polypropylene (MWCNT/PP composites have been investigated in the presence of coupling agents applied for improving the compatibility between the nanotubes and the polymer. A novel olefin-maleic-anhydride copolymer and an olefin-maleic-anhydride copolymer based derivative have been used as compatibilizers to achieve better dispersion of MWCNTs in the polymer matrix. The composites have been produced by extrusion followed by injection moulding. They contained different amounts of MWCNTs (0.5, 2, 3 and 5 wt% and coupling agent to enhance the interactions between the carbon nanotubes and the polymer. The electrical resistivity of the composites has been investigated by impedance spectroscopy, whereas their thermal properties have been determined using a thermal analyzer operating on the basis of the periodic thermal perturbation method. Rheological properties, BET-area and adsorption-desorption isotherms have been determined. Dispersion of MWCNTs in the polymer has been studied by scanning electron microscopy (SEM.

  17. Effect of Fiber Layers on the Fracture Resistance of Fiber Reinforced Composite Bridges

    Directory of Open Access Journals (Sweden)

    A Fazel

    2011-08-01

    Full Text Available Introduction: The purpose of this in vitro study was to introduce the fiber reinforced composite bridges and evaluate the most suitable site and position for placement of fibers in order to get maximum strength. Methods: The study included 20 second premolars and 20 second molars selected for fabricating twenty fiber reinforced composite bridges. Twenty specimens were selected for one fiber layer and the remaining teeth for two fiber layers. In the first group, fibers were placed in the inferior third and in the second group, fibers were placed in both the middle and inferior third region. After tooth preparation, the restorations were fabricated, thermocycled and then loaded with universal testing machine in the middle of the pontics with crosshead speed of 1mm/min. Data was analyzed by Kolmogorov-Smirnov test, Independent sample t test and Kaplan-Meier test. Mode of failure was evaluated using stereomicroscope. Results: Mean fracture resistance for the first and second groups was 1416±467N and 1349±397N, respectively. No significant differences were observed between the groups (P>0.05.In the first group, 5 specimens had delamintation and 5 specimens had detachment between fibers and resin composite. In the second group, there were 4 and 6 delaminations and detachments, respectively. There was no fracture within the fiber. Conclusion: In the fiber reinforced fixed partial dentures, fibers reinforce the tensile side of the connectors but placement of additional fibers at other sites does not increase the fracture resistance of the restoration.

  18. Metal Matrix Composite Coatings of Cupronickel Embedded with Nanoplatelets for Improved Corrosion Resistant Properties

    Directory of Open Access Journals (Sweden)

    Casey R. Thurber

    2018-01-01

    Full Text Available The deterioration of metals under the influence of corrosion is a costly problem faced by many industries. Therefore, particle-reinforced composite coatings are being developed in different technological fields with high demands for corrosion resistance. This work studies the effects of nanoplatelet reinforcement on the durability, corrosion resistance, and mechanical properties of copper-nickel coatings. A 90 : 10 Cu-Ni alloy was coelectrodeposited with nanoplatelets of montmorillonite (Mt embedded into the metallic matrix from electrolytic baths containing 0.05, 0.10, and 0.15% Mt. X-ray diffraction of the coatings indicated no disruption of the crystal structure with addition of the nanoplatelets into the alloy. The mechanical properties of the coatings improved with a 17% increase in hardness and an 85% increase in shear adhesion strength with nanoplatelet incorporation. The measured polarization resistance increased from 11.77 kΩ·cm2 for pure Cu-Ni to 33.28 kΩ·cm2 for the Cu-Ni-0.15% Mt coating after soaking in a simulated seawater environment for 30 days. The incorporation of montmorillonite also stabilized the corrosion potential during the immersion study and increased resistance to corrosion.

  19. Chemical composition and antibacterial activity of Lavandula coronopifolia essential oil against antibiotic-resistant bacteria.

    Science.gov (United States)

    Ait Said, L; Zahlane, K; Ghalbane, I; El Messoussi, S; Romane, A; Cavaleiro, C; Salgueiro, L

    2015-01-01

    The aim of this study was to analyse the composition of the essential oil (EO) of Lavandula coronopifolia from Morocco and to evaluate its in vitro antibacterial activity against antibiotic-resistant bacteria isolated from clinical infections. The antimicrobial activity was assessed by a broth micro-well dilution method using multiresistant clinical isolates of 11 pathogenic bacteria: Klebsiella pneumoniae subsp. pneumoniae, Klebsiella ornithinolytica, Escherichia coli, Enterobacter cloacae, Enterobacter aerogenes, Providencia rettgeri, Citrobacter freundii, Hafnia alvei, Salmonella spp., Acinetobacter baumannii and methicillin-resistant Staphylococcus aureus. The main compounds of the oil were carvacrol (48.9%), E-caryophyllene (10.8%) and caryophyllene oxide (7.7%). The oil showed activity against all tested strains with minimal inhibitory concentration (MIC) values ranging between 1% and 4%. For most of the strains, the MIC value was equivalent to the minimal bactericidal concentration value, indicating a clear bactericidal effect of L. coronopifolia EO.

  20. Influence of electropolishing and anodic oxidation on morphology, chemical composition and corrosion resistance of niobium

    Energy Technology Data Exchange (ETDEWEB)

    Sowa, Maciej; Greń, Katarzyna [Faculty of Chemistry, Silesian University of Technology, B. Krzywoustego Street 6, 44-100 Gliwice (Poland); Kukharenko, Andrey I. [Institute of Metal Physics, Russian Academy of Sciences-Ural Division, S. Kovalevskoi Street 18, 620990 Yekaterinburg (Russian Federation); Ural Federal University, Mira Street 19, 620002 Yekaterinburg, Mira str. 19 (Russian Federation); Korotin, Danila M. [Institute of Metal Physics, Russian Academy of Sciences-Ural Division, S. Kovalevskoi Street 18, 620990 Yekaterinburg (Russian Federation); Michalska, Joanna [Faculty of Materials Engineering and Metallurgy, Silesian University of Technology, Krasińskiego Street 8, 40-019 Katowice (Poland); Szyk-Warszyńska, Lilianna; Mosiałek, Michał [Jerzy Haber Institute of Catalysis and Surface Chemistry PAS, Niezapominajek Street 8, 30-239 Kraków (Poland); Żak, Jerzy [Faculty of Chemistry, Silesian University of Technology, B. Krzywoustego Street 6, 44-100 Gliwice (Poland); Pamuła, Elżbieta [AGH University of Science and Technology, Faculty of Materials Science and Ceramics, Mickiewicza Avenue 30, 30-059 Kraków (Poland); Kurmaev, Ernst Z. [Institute of Metal Physics, Russian Academy of Sciences-Ural Division, S. Kovalevskoi Street 18, 620990 Yekaterinburg (Russian Federation); Cholakh, Seif O. [Ural Federal University, Mira Street 19, 620002 Yekaterinburg, Mira str. 19 (Russian Federation); Simka, Wojciech, E-mail: wojciech.simka@polsl.pl [Faculty of Chemistry, Silesian University of Technology, B. Krzywoustego Street 6, 44-100 Gliwice (Poland)

    2014-09-01

    The work presents results of the studies performed on electropolishing of pure niobium in a bath that contained: sulphuric acid, hydrofluoric acid, ethylene glycol and acetanilide. After the electropolishing, the specimens were subjected to anodic passivation in a 1 mol dm{sup −3} phosphoric acid solution at various voltages. The surface morphology, thickness, roughness and chemical composition of the resulting oxide layers were analysed. Thusly prepared niobium samples were additionally investigated in terms of their corrosion resistance in Ringer's solution. The electropolished niobium surface was determined to be smooth and lustrous. The anodisation led to the growth of barrier-like oxide layers, which were enriched in phosphorus species. - Highlights: • Pure niobium was electropolished and subsequently anodised in a H{sub 3}PO{sub 4} solution. • Phosphorus was successfully introduced into the oxide layers after the treatment. • Corrosion resistance of niobium in Ringer's solution was improved after anodising.

  1. Mechanical properties of flexible knitted composites

    NARCIS (Netherlands)

    Haan, de J.; Peijs, A.A.J.M.

    1996-01-01

    This study investigates the influence of the matrix material and the degree of prestretch of a knitted fibre structure on the mechanical properties of knitted composites with low fibre volume fractions. By embedding a flexible textile structure in an elastomeric matrix, composite materials are

  2. Metagenomic profiling of microbial composition and antibiotic resistance determinants in Puget Sound.

    Science.gov (United States)

    Port, Jesse A; Wallace, James C; Griffith, William C; Faustman, Elaine M

    2012-01-01

    Human-health relevant impacts on marine ecosystems are increasing on both spatial and temporal scales. Traditional indicators for environmental health monitoring and microbial risk assessment have relied primarily on single species analyses and have provided only limited spatial and temporal information. More high-throughput, broad-scale approaches to evaluate these impacts are therefore needed to provide a platform for informing public health. This study uses shotgun metagenomics to survey the taxonomic composition and antibiotic resistance determinant content of surface water bacterial communities in the Puget Sound estuary. Metagenomic DNA was collected at six sites in Puget Sound in addition to one wastewater treatment plant (WWTP) that discharges into the Sound and pyrosequenced. A total of ~550 Mbp (1.4 million reads) were obtained, 22 Mbp of which could be assembled into contigs. While the taxonomic and resistance determinant profiles across the open Sound samples were similar, unique signatures were identified when comparing these profiles across the open Sound, a nearshore marina and WWTP effluent. The open Sound was dominated by α-Proteobacteria (in particular Rhodobacterales sp.), γ-Proteobacteria and Bacteroidetes while the marina and effluent had increased abundances of Actinobacteria, β-Proteobacteria and Firmicutes. There was a significant increase in the antibiotic resistance gene signal from the open Sound to marina to WWTP effluent, suggestive of a potential link to human impacts. Mobile genetic elements associated with environmental and pathogenic bacteria were also differentially abundant across the samples. This study is the first comparative metagenomic survey of Puget Sound and provides baseline data for further assessments of community composition and antibiotic resistance determinants in the environment using next generation sequencing technologies. In addition, these genomic signals of potential human impact can be used to guide initial

  3. Metagenomic profiling of microbial composition and antibiotic resistance determinants in Puget Sound.

    Directory of Open Access Journals (Sweden)

    Jesse A Port

    Full Text Available Human-health relevant impacts on marine ecosystems are increasing on both spatial and temporal scales. Traditional indicators for environmental health monitoring and microbial risk assessment have relied primarily on single species analyses and have provided only limited spatial and temporal information. More high-throughput, broad-scale approaches to evaluate these impacts are therefore needed to provide a platform for informing public health. This study uses shotgun metagenomics to survey the taxonomic composition and antibiotic resistance determinant content of surface water bacterial communities in the Puget Sound estuary. Metagenomic DNA was collected at six sites in Puget Sound in addition to one wastewater treatment plant (WWTP that discharges into the Sound and pyrosequenced. A total of ~550 Mbp (1.4 million reads were obtained, 22 Mbp of which could be assembled into contigs. While the taxonomic and resistance determinant profiles across the open Sound samples were similar, unique signatures were identified when comparing these profiles across the open Sound, a nearshore marina and WWTP effluent. The open Sound was dominated by α-Proteobacteria (in particular Rhodobacterales sp., γ-Proteobacteria and Bacteroidetes while the marina and effluent had increased abundances of Actinobacteria, β-Proteobacteria and Firmicutes. There was a significant increase in the antibiotic resistance gene signal from the open Sound to marina to WWTP effluent, suggestive of a potential link to human impacts. Mobile genetic elements associated with environmental and pathogenic bacteria were also differentially abundant across the samples. This study is the first comparative metagenomic survey of Puget Sound and provides baseline data for further assessments of community composition and antibiotic resistance determinants in the environment using next generation sequencing technologies. In addition, these genomic signals of potential human impact can be used

  4. Correlation of chemical compositions of cassava varieties to their resistance to Prostephanus truncatus Horn (Coleoptera: Bostrichidae).

    Science.gov (United States)

    Osipitan, Adebola A; Sangowusi, Victoria T; Lawal, Omoniyi I; Popoola, Kehinde O

    2015-01-01

    The preference of cassava as a major host by Prostephanus truncatus Horn is a major constraint to ample production of cassava, Manihot esculenta Crantz and storage. This study analyzed the nutritional and secondary metabolite compositions in 15 cassava varieties, evaluated levels of damage and reproduction by P. truncatus, and assessed their resistance to attack. One hundred grams of dried cassava chips in 250-ml Kilner jars were infested with 10 adult larger grain borerof 0-10 days old and held for 3 months. The nutritional and secondary metabolites compositions of the dry cassava chips were determined using the method of Association of Analytical Chemists . Chip perforation rates in the cassava varieties ranged from 17.7 to 71.6%. The weight of cassava powder varied by about threefold. The final number of larger grain borer in the cassava varieties varied by about sixfold with 63 in 01/0040 and 379 in 01/1368. Hydrocyanic acid content content varied by over 10-fold and correlated negatively with number of larger grain borer. Flavonoid content varied by ∼10%. Tannins and saponin content of the cassava negatively correlated with number of adult P. truncatus. The cassava varieties 95/0166, 92/0326, 01/0040, 05/0024, and 34 91934 had selection index 0.8 were classified as susceptible. The resistance to high damage in the resistant varieties was conferred by secondary metabolites such as tannins, saponins, alkaloids, and hydrocyanic acid content. The genetic variation in cassava varieties could be explored to breed resistant cassava varieties for use in larger grain borer-endemic areas. © The Author 2015. Published by Oxford University Press on behalf of the Entomological Society of America.

  5. Enhancement of the oxidation resistance of carbon fibres in C/C composites via surface treatments

    Energy Technology Data Exchange (ETDEWEB)

    Labruquere, S.; Pailler, R.; Naslain, R. [Bordeaux Univ., Pessac (France). Lab. des Composites Thermostructuraux; Desbat, B. [Lab. de Spectroscopie Moleculaire et Cristalline, Univ. of Bordeaux, Talence (France)

    1997-12-31

    Carbon-carbon (C/C) composites are commonly used in rockets and braking systems. However, the carbon reacts with oxygen, burning away rapidly at temperatures as low as 450 C. This work deals with the protection of carbon fibres from oxidation between 600 and 1000 C. Two kinds of methods were investigated to protect carbon fibres: (i) surface treatment with aqueous solutions (e.g. of H3PO4) and (ii) chemical vapour deposition (CVD) of SiC coatings. Oxidation resistance of the as treated preforms was studied under dry air atmosphere. (orig.) 2 refs.

  6. REM effect on nonmetallic inclusion composition and heat resistance in an austenitic steel

    International Nuclear Information System (INIS)

    Farafonov, V.K.; Shtejnberg, M.M.; Kikhtin, M.V.; Cheremnykh, V.P.; Vojnov, V.V.

    1979-01-01

    Studies were made to elucidate the effect of rare earths (lanthanum, neodymium, praseodymium, cerium) on the composition of non-metallic inclusions and heat resistance of an austenitic chromium-nickel steel. Common sulfide and oxide inclusions are shown to be substituted by rare earth sulfide and oxide inclusions at RE metal content in the steel up to 0.1%. Further increase of RE metal content results in increasing non-metallic inclusions containing RE metals, phosphorus and non-ferrous impurities. Creep rate changes insignificantly at RE metal content up to 0.1%, and then it sharply grows with the quantity of non-metallic inclusions in the steel

  7. A Numerical Analysis of the Resistance and Stiffness of the Timber and Concrete Composite Beam

    Science.gov (United States)

    Szumigała, Ewa; Szumigała, Maciej; Polus, Łukasz

    2015-03-01

    The article presents the results of a numerical analysis of the load capacity and stiffness of the composite timber and concrete beam. Timber and concrete structures are relatively new, they have not been thoroughly tested and they are rarely used because of technological constraints. One of the obstacles to using them is difficulty with finding a method which would allow successful cooperation between concrete and timber, which has been proposed by the authors of the present article. The modern idea of sustainable construction design requires the use of new more environmentally-friendly solutions. Wood as an ecological material is easily accessible, less energy-consuming, and under certain conditions more corrosion-resistant than steel. The analysis presented in the article showed that cooperation between a wooden beam and a concrete slab on profiled steel sheeting is possible. The analysed composite beam has a greater load capacity and stiffness than the wooden beam.

  8. Radiation resistance of the carbon fiber reinforced composite material with PEEK as the matrix resin

    International Nuclear Information System (INIS)

    Sasuga, Tsuneo; Seguchi, Tadao; Sakai, Hideo; Nakakura, Toshiyuki; Masutani, Masahiro.

    1987-01-01

    In the fast breeder reactor etc. the structural materials are exposed to various environment, i.e., repeated high and low temperature, stress, etc. Irradiation effect (electron radiation) in the mechanical characteristic at low and high temperature has been studied in the PEEK-CF, polyarylether · ether · ketone - carbon fiber composite. Following are the results. (1) Radiation resistance of PEEK-CF is higher than that of PEEK-PES-CF, PEEK - polyethersulfone surface treated CF composite. In PEEK-PES-CF, PES is deteriorated by irradiation so the adhesive power lowers. (2) In the unirradiated PEEK-CF, its mechanical characteristic decreases beyond 140 deg C. With increase of the radiation dose, however, the characteristic rises. (3) Mechanical characteristic of PEEK-CF thus little drops by the heat treatment after the irradiation. (Mori, K.)

  9. Wear resistance analysis of the aluminum 7075 alloy and the nanostructured aluminum 7075 - silver nanoparticles composites

    Directory of Open Access Journals (Sweden)

    Estrada-Ruiz R.H.

    2016-01-01

    Full Text Available Nanostructured composites of the aluminum 7075 alloy and carbon-coated silver nanoparticles were synthetized by the mechanical milling technique using a high-energy mill SPEX 8000M; the powders generated were compacted, sintered and hot-extruded to produce 1 cm-diameter bars. The composites were then subjected to a wear test using a pin-on-disc device to validate the hypothesis that second phase-ductile nanometric particles homogenously distributed throughout the metalmatrix improve the wear resistance of the material. It was found that silver nanoparticles prevent the wear of the material by acting as an obstacle to dislocations movement during the plastic deformation of the contact surface, as well as a solid lubricant when these are separated from the metal-matrix.

  10. A Numerical Analysis of the Resistance and Stiffness of the Timber and Concrete Composite Beam

    Directory of Open Access Journals (Sweden)

    Szumigała Ewa

    2015-03-01

    Full Text Available The article presents the results of a numerical analysis of the load capacity and stiffness of the composite timber and concrete beam. Timber and concrete structures are relatively new, they have not been thoroughly tested and they are rarely used because of technological constraints. One of the obstacles to using them is difficulty with finding a method which would allow successful cooperation between concrete and timber, which has been proposed by the authors of the present article. The modern idea of sustainable construction design requires the use of new more environmentally-friendly solutions. Wood as an ecological material is easily accessible, less energy-consuming, and under certain conditions more corrosion-resistant than steel. The analysis presented in the article showed that cooperation between a wooden beam and a concrete slab on profiled steel sheeting is possible. The analysed composite beam has a greater load capacity and stiffness than the wooden beam.

  11. Body composition using deuterated water, index of insulin resistance and cortisol levels in Costa Rican school in the metropolitan area

    International Nuclear Information System (INIS)

    Valverde Vindas, Allan Ignacio

    2014-01-01

    Body composition in the Costa Rican child population is evaluated and analyzed to determine the relationship with the index of insulin resistance and serum cortisol levels. 113 children in the metropolitan area were studied using deuterium isotope techniques as reference method for overweight and obesity. Morning cortisol levels were determined by immunoassay techniques (ELISA). The insulin resistance index of 113 Costa Rican boys and girls is obtained by the homeostatic method and the relationship between body composition with index of insulin resistance or levels of cortisol [es

  12. Effect of different composite core materials on fracture resistance of endodontically treated teeth restored with FRC posts

    OpenAIRE

    PANITIWAT, Prapaporn; SALIMEE, Prarom

    2017-01-01

    Abstract Objective This study evaluated the fracture resistance of endodontically treated teeth restored with fiber reinforced composite posts, using three resin composite core build-up materials, (Clearfil Photo Core (CPC), MultiCore Flow (MCF), and LuxaCore Z-Dual (LCZ)), and a nanohybrid composite, (Tetric N-Ceram (TNC)). Material and Methods Forty endodontically treated lower first premolars were restored with quartz fiber posts (D.T. Light-Post) cemented with resin cement (Panavia F2...

  13. Wear resistance of laser-deposited boride reinforced Ti-Nb-Zr-Ta alloy composites for orthopedic implants

    International Nuclear Information System (INIS)

    Samuel, Sonia; Nag, Soumya; Scharf, Thomas W.; Banerjee, Rajarshi

    2008-01-01

    The inherently poor wear resistance of titanium alloys limits their application as femoral heads in femoral (hip) implants. Reinforcing the soft matrix of titanium alloys (including new generation β-Ti alloys) with hard ceramic precipitates such as borides offers the possibility of substantially enhancing the wear resistance of these composites. The present study discusses the microstructure and wear resistance of laser-deposited boride reinforced composites based on Ti-Nb-Zr-Ta alloys. These composites have been deposited using the LENS TM process from a blend of elemental Ti, Nb, Zr, Ta, and boron powders and consist of complex borides dispersed in a matrix of β-Ti. The wear resistance of these composites has been compared with that of Ti-6Al-4V ELI, the current material of choice for orthopedic femoral implants, against two types of counterfaces, hard Si 3 N 4 and softer SS440C stainless steel. Results suggest a substantial improvement in the wear resistance of the boride reinforced Ti-Nb-Zr-Ta alloys as compared with Ti-6Al-4V ELI against the softer counterface of SS440. The presence of an oxide layer on the surface of these alloys and composites also appears to have a substantial effect in terms of enhanced wear resistance

  14. Diffusion of nanoparticles in solution through elastomeric membrane

    Science.gov (United States)

    Zemzem, Mohamed; Vinches, Ludwig; Hallé, Stéphane

    2017-04-01

    Diffusion phenomena encountered in mass transfer of liquids play an important role in many technological processes of polymer manufacturing and use. In addition and alongside the notable growth of nanoparticles use, particularly when in suspension in liquid solutions, it has become important to pay some attention to their interactions with polymeric structures. The aim of this work is to evaluate some diffusion parameters of gold nanoparticle solutions as well as of their liquid carrier (water) through elastomeric membranes. Gravimetric method was chosen as the main technique to quantify swelling phenomena and to assess kinetic properties. The dynamic liquid uptake measurements were conducted on gold nanoparticles (5 nm and 50 nm in diameter) in aqueous solutions when brought into contact with two types of nitrile material samples. Results showed that diffusion mechanism of the liquids lies between Fickian and sub-Fickian modes. Slight deviations were noticed with the gold nanoparticle solutions. A growth in liquid interaction with the rubbery structure in presence of the nanoparticles was also observed from comparison of K factor (characteristic of the elastomer-liquid interaction). Difference between the characteristics of the two membranes was also reported using this parameter. Besides, diffusion coefficients testified the impact of the membrane thickness on the penetration process, while no significant effect of the nature of the nanoparticle solution can be seen on this coefficient.

  15. Diffusion of nanoparticles in solution through elastomeric membrane

    International Nuclear Information System (INIS)

    Zemzem, Mohamed; Vinches, Ludwig; Hallé, Stéphane

    2017-01-01

    Diffusion phenomena encountered in mass transfer of liquids play an important role in many technological processes of polymer manufacturing and use. In addition and alongside the notable growth of nanoparticles use, particularly when in suspension in liquid solutions, it has become important to pay some attention to their interactions with polymeric structures. The aim of this work is to evaluate some diffusion parameters of gold nanoparticle solutions as well as of their liquid carrier (water) through elastomeric membranes. Gravimetric method was chosen as the main technique to quantify swelling phenomena and to assess kinetic properties. The dynamic liquid uptake measurements were conducted on gold nanoparticles (5 nm and 50 nm in diameter) in aqueous solutions when brought into contact with two types of nitrile material samples. Results showed that diffusion mechanism of the liquids lies between Fickian and sub-Fickian modes. Slight deviations were noticed with the gold nanoparticle solutions. A growth in liquid interaction with the rubbery structure in presence of the nanoparticles was also observed from comparison of K factor (characteristic of the elastomer-liquid interaction). Difference between the characteristics of the two membranes was also reported using this parameter. Besides, diffusion coefficients testified the impact of the membrane thickness on the penetration process, while no significant effect of the nature of the nanoparticle solution can be seen on this coefficient. (paper)

  16. Strain-dependent dynamic compressive properties of magnetorheological elastomeric foams

    Science.gov (United States)

    Wereley, Norman M.; Perez, Colette; Choi, Young T.

    2018-05-01

    This paper addresses the strain-dependent dynamic compressive properties (i.e., so-called Payne effect) of magnetorheological elastomeric foams (MREFs). Isotropic MREF samples (i.e., no oriented particle chain structures), fabricated in flat square shapes (nominal size of 26.5 mm x 26.5 mm x 9.5 mm) were synthesized by randomly dispersing micron-sized iron oxide particles (Fe3O4) into a liquid silicone foam in the absence of magnetic field. Five different Fe3O4 particle concentrations of 0, 2.5, 5.0, 7.5, and 10 percent by volume fraction (hereinafter denoted as vol%) were used to investigate the effect of particle concentration on the dynamic compressive properties of the MREFs. The MREFs were sandwiched between two multi-pole flexible plate magnets in order to activate the magnetorheological (MR) strengthening effect. Under two different pre-compression conditions (i.e., 35% and 50%), the dynamic compressive stresses of the MREFs with respect to dynamic strain amplitudes (i.e., 1%-10%) were measured by using a servo-hydraulic testing machine. The complex modulus (i.e., storage modulus and loss modulus) and loss factors of the MREFs with respect to dynamic strain amplitudes were presented as performance indices to evaluate their strain-dependent dynamic compressive behavior.

  17. Strain-dependent dynamic compressive properties of magnetorheological elastomeric foams

    Directory of Open Access Journals (Sweden)

    Norman M. Wereley

    2018-05-01

    Full Text Available This paper addresses the strain-dependent dynamic compressive properties (i.e., so-called Payne effect of magnetorheological elastomeric foams (MREFs. Isotropic MREF samples (i.e., no oriented particle chain structures, fabricated in flat square shapes (nominal size of 26.5 mm x 26.5 mm x 9.5 mm were synthesized by randomly dispersing micron-sized iron oxide particles (Fe3O4 into a liquid silicone foam in the absence of magnetic field. Five different Fe3O4 particle concentrations of 0, 2.5, 5.0, 7.5, and 10 percent by volume fraction (hereinafter denoted as vol% were used to investigate the effect of particle concentration on the dynamic compressive properties of the MREFs. The MREFs were sandwiched between two multi-pole flexible plate magnets in order to activate the magnetorheological (MR strengthening effect. Under two different pre-compression conditions (i.e., 35% and 50%, the dynamic compressive stresses of the MREFs with respect to dynamic strain amplitudes (i.e., 1%-10% were measured by using a servo-hydraulic testing machine. The complex modulus (i.e., storage modulus and loss modulus and loss factors of the MREFs with respect to dynamic strain amplitudes were presented as performance indices to evaluate their strain-dependent dynamic compressive behavior.

  18. Unification of reactor elastomeric sealing based on material

    International Nuclear Information System (INIS)

    Sinha, N.K.; Raj, Baldev

    2012-01-01

    The unification of elastomeric sealing applications of Indian nuclear reactors based on a few qualified fluoroelastomer/perfluoroelastomer compounds and standardized approaches for finite element analysis (FEA) based design, manufacturing process and antifriction coatings is discussed. It is shown that the advance polymer architecture based Viton ® formulation developed for inflatable seals of 500 MWe Prototype Fast Breeder Reactor (PFBR) and its four basic variations can encompass other sealing applications of PFBR with minimum additional efforts on development and validation. Changing the blend ratio of Viton ® GBL 200S and 600S in inflatable seal formulation could extend its use to Pressurized Heavy Water Reactors (PHWRs). The higher operating temperature of Advanced Heavy Water Reactor (AHWR) seals expands the choice to perfluoroelastomers. FEA based on plane-strain/axisymmetric modeling (with Mooney–Rivlin as the basic constitutive model), seal manufacture by cold feed extrusion and injection molding as well as plasma Teflon-like coating belonging to two variations obtained from the development of inflatable seals provide the necessary standardization for unification. The gains in simplification of design, development and operation of seals along with the enhancements of safety and reliability are expected to be substantial.

  19. The inaccuracy of conventional one-dimensional parallel thermal resistance circuit model for two-dimensional composite walls

    International Nuclear Information System (INIS)

    Wong, K.-L.; Hsien, T.-L.; Hsiao, M.-C.; Chen, W.-L.; Lin, K.-C.

    2008-01-01

    This investigation is to show that two-dimensional steady state heat transfer problems of composite walls should not be solved by the conventionally one-dimensional parallel thermal resistance circuits (PTRC) model because the interface temperatures are not unique. Thus PTRC model cannot be used like its conventional recognized analogy, parallel electrical resistance circuits (PERC) model which has the unique node electric voltage. Two typical composite wall examples, solved by CFD software, are used to demonstrate the incorrectness. The numerical results are compared with those obtained by PTRC model, and very large differences are observed between their results. This proves that the application of conventional heat transfer PTRC model to two-dimensional composite walls, introduced in most heat transfer text book, is totally incorrect. An alternative one-dimensional separately series thermal resistance circuit (SSTRC) model is proposed and applied to the two-dimensional composite walls with isothermal boundaries. Results with acceptable accuracy can be obtained by the new model

  20. Incorrectness of conventional one-dimensional parallel thermal resistance circuit model for two-dimensional circular composite pipes

    International Nuclear Information System (INIS)

    Wong, K.-L.; Hsien, T.-L.; Chen, W.-L.; Yu, S.-J.

    2008-01-01

    This study is to prove that two-dimensional steady state heat transfer problems of composite circular pipes cannot be appropriately solved by the conventional one-dimensional parallel thermal resistance circuits (PTRC) model because its interface temperatures are not unique. Thus, the PTRC model is definitely different from its conventional recognized analogy, parallel electrical resistance circuits (PERC) model, which has unique node electric voltages. Two typical composite circular pipe examples are solved by CFD software, and the numerical results are compared with those obtained by the PTRC model. This shows that the PTRC model generates large error. Thus, this conventional model, introduced in most heat transfer text books, cannot be applied to two-dimensional composite circular pipes. On the contrary, an alternative one-dimensional separately series thermal resistance circuit (SSTRC) model is proposed and applied to a two-dimensional composite circular pipe with isothermal boundaries, and acceptable results are returned

  1. Tribological properties and morphology of bimodal elastomeric nitrile butadiene rubber networks

    International Nuclear Information System (INIS)

    Guo, Yin; Wang, Jiaxu; Li, Kang; Ding, Xingwu

    2013-01-01

    Highlights: • Bimodal elastomeric NBR as a new material was developed. • The structure of bimodal elastomeric NBR networks was determined. • The relationship between structure and mechanical properties was investigated. • The tribological properties and mechanisms of bimodal NBR were analyzed. • The benefits of bimodal NBR in the field of tribology were discussed. - Abstract: Bimodal nitrile butadiene rubber (NBR) was examined in this study. The molecular structure was determined by dynamic mechanical analysis and transmission electron microscopy. The relationship between the structure and the mechanical properties related to elastomeric tribological properties was investigated. The properties and the mechanisms of friction and wear of bimodal elastomeric NBR networks were also analyzed. The lubricating characteristics of bimodal NBR networks were revealed based on the mechanisms of friction and wear. Results show that bimodal NBR networks are similar to bimodal polydimethylsiloxane networks. The form and density of the network structure can be controlled from elastomeric networks to thermosetting resin networks. The mechanical properties of bimodal NBR networks, such as elasticity, elongation at break, fatigue characteristic, tensile strength, elastic modulus, and thermal stability can be precisely controlled following the variation in network structure. The friction, wear, and lubrication of bimodal NBR networks can be clearly described according to the principles of tribology. Common elastomers cannot simultaneously reduce friction and wear because of the different mechanisms of friction and wear; however, bimodal elastomer networks can efficiently address this problem

  2. The role of elastomeric pumps in postoperative analgesia in orthopaedics and factors affecting their flow rate.

    Science.gov (United States)

    Theodorides, Anthony Andreas

    2017-12-01

    Elastomeric pumps are mechanical devices composed of an elastomeric balloon reservoir into which the drug to be infused is stored, a protective casing (used by some manufacturers), a flow controller and a wound catheter. In orthopaedics they are used to provide continuous local infiltration analgesia. In this way patients rely less on other routes of analgesia and thus avoid their systemic side effects. Studies have shown good response to analgesia with these pumps for the first 24 hours but their benefit is not as clear at 48 and 72 hours. There are numerous factors that affect the flow rate of elastomeric pumps. Some are inherent to all elastomeric pumps such as: the pressure exerted by the elastomeric balloon, catheter size, the vertical height of the pump in relation to the wound, viscosity and partial filling. There are also other factors which vary according to the manufacturer such as: the optimal temperature to obtain the desired flow rate as this directly affects viscosity, the dialysate that the analgesic drug is mixed with (ie normal saline or 5% dextrose), and the storage conditions of the fluid to be infused. It is thus essential to follow the clinical guidelines provided by the manufacturer in order to obtain the desired flow rate. Copyright the Association for Perioperative Practice.

  3. Force decay of elastomeric chains - a mechanical design and product comparison study.

    Science.gov (United States)

    Balhoff, David A; Shuldberg, Matthew; Hagan, Joseph L; Ballard, Richard W; Armbruster, Paul C

    2011-03-01

    To evaluate the percentage force decay of elastomeric chain products utilizing three different design mechanisms simulating canine retraction; and to evaluate the percentage force decay of elastomeric chain products from four different companies. In vitro, laboratory study. LSUHSC Dental School, New Orleans, LA, USA. Closed (non-spaced), grey elastomeric chains from four companies were selected for the study. Three acrylic resin jigs were constructed to provide a framework for three simulated space closure mechanisms. The 6-5-3, the chain loop, and the 6-3 were the configuration mechanisms used in the study. An electronic force gauge was used to measure the percentage force decay associated with each elastomeric chain over 28 days at preselected times. There was a significant difference in the mean percentage force decay for the three different mechanisms (P < 0·001). For all four companies, the 6-3 mechanical design had the smallest mean percentage force decay. There was a significant difference in the mean percentage force decay for the different companies (P < 0·001). For all three mechanisms, Ormco had the smallest percentage force decay while Unitek had the highest percentage force decay. The significant difference in the mean percentage force decay for the different mechanisms suggests that the 6-3 design is a more efficient means of closing extraction spaces utilizing elastomeric chains.

  4. TiO2-TiO2 composite resistive humidity sensor: ethanol crosssensitivity

    International Nuclear Information System (INIS)

    Ghalamboran, Milad; Saedi, Yasin

    2016-01-01

    The fabrication method and characterization results of a TiO 2 -TiO 2 composite bead used for humidity sensing along with its negative cross-sensitivity to ethanol vapor are reported. The bead shaped resistive sample sensors are fabricated by the drop-casting of a TiO 2 slurry on two Pt wire segments. The dried bead is pre-fired at 750°C and subsequently impregnated with a Ti-based sol. The sample is ready for characterization after a thermal annealing at 600°C in air. Structurally, the bead is a composite of the micron-sized TiO 2 crystallites embedded in a matrix of nanometric TiO 2 particle aggregates. The performance of the beads as resistive humidity sensors is recorded at room temperature in standard humidity level chambers. Results evince the wide dynamic range of the sensors fabricated in the low relative humidity range. While the sensor conductance is not sensitive to ethanol vapor in dry air, in humid air, sensor's responses are negatively affected by the contaminant. (paper)

  5. Muscle function and body composition profile in adolescents with restrictive anorexia nervosa: does resistance training help?

    Science.gov (United States)

    Fernández-del-Valle, Maria; Larumbe-Zabala, Eneko; Morande-Lavin, Gonzalo; Perez Ruiz, Margarita

    2016-01-01

    The aim of this study was to analyze the effects of short-term resistance training on the body composition profile and muscle function in a group of Anorexia Nervosa restricting type (AN-R) patients. The sample consisted of AN-R female adolescents (12.8 ± 0.6 years) allocated into the control and intervention groups (n = 18 each). Body composition and relative strength were assessed at baseline, after 8 weeks and 4 weeks following the intervention. Body mass index (BMI) increased throughout the study (p = 0.011). Significant skeletal muscle mass (SMM) gains were found in the intervention group (p = 0.045, d = 0.6) that correlated to the change in BMI (r = 0.51, p  0.60) with change in BMI in both the groups. Significant relative strength increases (p Anorexia Nervosa Restricting Type (AN-R) AN-R is a psychiatric disorder that has a major impact on muscle mass content and function. However, little or no attention has been paid to muscle recovery. High intensity resistance training is safe for AN-R after hospitalization and enhances the force generating capacity as well as muscle mass gains. Skeletal muscle mass content and muscular function improvements are partially maintained for a short period of time when the exercise program ceases.

  6. N-stearoylethanolamine restores pancreas lipid composition in obesity-induced insulin resistant rats.

    Science.gov (United States)

    Onopchenko, Oleksandra V; Kosiakova, Galina V; Oz, Murat; Klimashevsky, Vitaliy M; Gula, Nadiya M

    2015-01-01

    This study investigates the protective effect of N-stearoylethanolamine (NSE), a bioactive N-acylethanolamine , on the lipid profile distribution in the pancreas of obesity-induced insulin resistant (IR) rats fed with prolonged high fat diet (58% of fat for 6 months). The phospholipid composition was determined using 2D thin-layer chromatography. The level of individual phospholipids was estimated by measuring inorganic phosphorus content. The fatty acid (FA) composition and cholesterol level were investigated by gas-liquid chromatography. Compared to controls, plasma levels of triglycerides and insulin were significantly increased in IR rats. The pancreas lipid composition indicated a significant reduction of the free cholesterol level and some phospholipids such as phosphatidylcholine (PtdCho), phosphatidylethanolamine (PtdEtn), phosphatidylinositol (PtdIns), phosphatidylserine (PtdSer) compared to controls. Moreover, the FA composition of pancreas showed a significant redistribution of the main FA (18:1n-9, 18:2n-6, 18:3n-6 and 20:4n-6) levels between phospholipid, free FA, triglyceride fractions under IR conditions that was accompanied by a change in the estimated activities of Δ9-, Δ6-, Δ5-desaturase. Administration of N-stearoylethanolamine (NSE, 50 mg/kg daily per os for 2 weeks) IR rats triggered an increase in the content of free cholesterol, PtdCho and normalization of PtdEtn, PtdSer level. Furthermore, the NSE modulated the activity of desaturases, thus influenced FA composition and restored the FA ratios in the lipid fractions. These NSE-induced changes were associated with a normalization of plasma triglyceride content, considerable decrease of insulin and index HOMA-IR level in rats under IR conditions.

  7. Effect of combined aerobic and resistance training in body composition of obese postmenopausal women

    Directory of Open Access Journals (Sweden)

    Fabrício E. Rossi

    2015-03-01

    Full Text Available The aim of this study was to investigate the effects of a 16-week program of combined aerobic and resistance training on the body composition of postmenopausal women who are obese. The participants were divided into two groups: training group (TG, n = 37 and non-trained control group (CG, n = 18. The trunk fat, fat mass, percentage of fat mass and fat-free mass were estimated using DXA. Three nonconsecutive 24-hour dietary recalls were conducted. The training protocol consisted of 50 minutes of resistance training followed by 30 minutes of aerobic training. After the 16-week training program, differences were observed in trunk fat (CG= 0.064 x TG= -0.571 Kg; p-value = .020, fat mass (CG= -0.088 x TG= -1.037 Kg; p-value = .020 and fat-free mass (CG= -0.388 x TG= 1.049 Kg; p = .001. Therefore, a 16-week program of systematic combined aerobic and resistance training in obese postmenopausal women was effective in improving fat-free mass and decreasing both whole and abdominal adiposity.

  8. Hazardous industrial gases identified using a novel polymer/MWNT composite resistance sensor array

    International Nuclear Information System (INIS)

    Yuana, C.L.; Chang, C.P.; Song, Y.

    2011-01-01

    Highlights: → In this work, a silicon wafer microelectrode substrate for a resistance sensor was fabricated using the semiconductor manufacturing process. → This work developed polymer-functionalized MWNT sensor plat forms for the detection of vapors from chemical agents at different temperatures. → Applied PCA to determine the performance of as-fabricated films for exposure to three chemical agents. - Abstract: Hazardous industrial chemical gases pose a significant threat to the environment and human life. Therefore, there is an urgent need to develop a reliable sensor for identifying these hazardous gases. In this work, a silicon wafer microelectrode substrate for a resistance sensor was fabricated using the semiconductor manufacturing process. Conductive carbon nanotubes were then mixed with six different polymers with different chemical adsorption properties to produce a composite thin film for the fabrication of a chemical sensor array. This array was then utilized to identify three hazardous gases at different temperatures. Experimental results for six polymers for chemical gases, such as tetrahydrofuran (THF), chloroform (CHCl 3 ) and methanol (MeOH) at different temperatures, indicate that the variation in sensitivity resistance increased when the sensing temperature increased. The poly(ethylene adipate)/MWNT sensing film had high sensitivity, excellent selectivity, and good reproducibility in detecting all chemical agent vapors. Additionally, this study utilized a bar chart and statistical methods in principal component analysis to identify gases with the polymer/MWNT sensor.

  9. Effect of Different Liners on Fracture Resistance of Premolars Restored with Conventional and Short Fiber-Reinforced Composite Resins.

    Science.gov (United States)

    Shafiei, Fereshteh; Doozandeh, Maryam; Ghaffaripour, Dordaneh

    2018-01-11

    To see whether applying four different liners under short fiber-reinforced composite (SFRC), everX Posterior, compared to conventional composite resin, Z250, affected their strengthening property in premolar MOD cavities. Mesio-occluso-distal (MOD) cavities were prepared in 120 sound maxillary premolars divided into 10 groups (n = 12) in terms of two composite resin types and 4 liners or no liner. For each composite resin, in 5 groups no liner, resin-modified glass ionomer (RMGI), conventional flowable composite (COFL), self-adhesive flowable composite resin (SAFL), and self-adhesive resin cement (SARC) were applied prior to restoring incrementally. After water storage and thermocycling, static fracture resistance was tested. Data (in Newtons) were analyzed using two-way ANOVA (α = 0.05). Fracture resistance was significantly affected by composite resin type (p = 0.02), but not by the liner (p > 0.05). The interaction of the two factors was not statistically significant (p > 0.05). SFRC exhibited higher fracture strength (1470 ± 200 N) compared to conventional composite resin (1350 ± 290), irrespective of the application of liners. Application of SARC and SAFL liners led to a higher number of restorable fractures for both composite resins. The four liners can be used without interfering with the higher efficacy of SFRC, compared to conventional composite resins, to improve the fracture strength of premolar MOD cavities. © 2018 by the American College of Prosthodontists.

  10. High corrosion resistance of electroless composite plating coatings on AZ91D magnesium alloys

    International Nuclear Information System (INIS)

    Song, Y.W.; Shan, D.Y.; Han, E.H.

    2008-01-01

    The process of electroless plating Ni-P on AZ91D magnesium alloys was improved. The Ni-P-ZrO 2 composite coatings and multilayer coatings were investigated based on the new electroless plating process. The coatings surface and cross-section morphologies were observed with scanning electron microscopy (SEM). The chemical compositions were analyzed by EDXS. The corrosion behaviors were evaluated by immersion, salt spray and electrochemical tests. The experimental results indicated that the Ni-P-ZrO 2 composite coatings suffered attack in NaCl solution but displayed passivation characteristics in NaOH and Na 2 SO 4 solutions. The corrosion resistance of Ni-P-ZrO 2 coatings was superior to Ni-P coatings due to the effect of ZrO 2 nano-particle. The multilayer coatings consisting of Ni-P-ZrO 2 /electroplating nickel/Ni-P (from substrate to surface) can protect magnesium alloys from corroding more than 1000 h for the salt spray test

  11. The Formation Mechanism and Corrosion Resistance of a Composite Phosphate Conversion Film on AM60 Alloy

    Science.gov (United States)

    Lan, Xiangna; Wang, Chao; Zhang, Qinyong

    2018-01-01

    Magnesium alloy AM60 has high duc and toughness, which is expected to increase in demand for automotive applications. However, it is too active, and coatings have been extensively studied to prevent corrosion. In this work, a Ba-containing composite phosphate film has been prepared on the surface of AM60. The composition and formation mechanism of the film have been investigated using a scanning electronic microscope equipped with energy dispersive X-ray spectroscopy, Fourier transform infrared, X-ray photoelectron spectroscopy, and X-ray diffractometry tests. The corrosion resistance of the film has been measured by electrochemical and immersion tests. The results show that the deposition film has fully covered the substrate but there are some micro-cracks. The structure of the film is complex, and consists of MgHPO4·3H2O, MnHPO4·2.25H2O, BaHPO4·3H2O, BaMg2(PO4)2, Mg3(PO4)2·22H2O, Ca3(PO4)2·xH2O, and some amorphous phases. The composite phosphate film has better anticorrosion performance than the AM60 and can protect the bare alloy from corrosion for more than 12 h in 0.6 M NaCl. PMID:29518038

  12. Effect of the fatty acid composition of acclimated oenological Lactobacillus plantarum on the resistance to ethanol.

    Science.gov (United States)

    Bravo-Ferrada, B M; Gómez-Zavaglia, A; Semorile, L; Tymczyszyn, E E

    2015-02-01

    The aim of this work was to evaluate the changes due to acclimation to ethanol on the fatty acid composition of three oenological Lactobacillus plantarum strains and their effect on the resistance to ethanol and malic acid consumption (MAC). Lactobacillus plantarum UNQLp 133, UNQLp 65.3 and UNQLp 155 were acclimated in the presence of 6 or 10% v/v ethanol, for 48 h at 28°C. Lipids were extracted to obtain fatty acid methyl esters and analysed by gas chromatography interfaced with mass spectroscopy. The influence of change in fatty acid composition on the viability and MAC in synthetic wine was analysed by determining the Pearson correlation coefficient. Acclimated strains showed a significant change in the fatty composition with regard to the nonacclimated strains. Adaptation to ethanol led to a decrease in the unsaturated/saturated ratio, mainly resulting from an increase in the contribution of short-length fatty acid C12:0 and a decrease of C18:1. The content of C12:0 was related to a higher viability after inoculation of synthetic wine. The MAC increased at higher contents in saturated fatty acid, but its efficiency was strain dependent. © 2014 The Society for Applied Microbiology.

  13. The Formation Mechanism and Corrosion Resistance of a Composite Phosphate Conversion Film on AM60 Alloy.

    Science.gov (United States)

    Chen, Jun; Lan, Xiangna; Wang, Chao; Zhang, Qinyong

    2018-03-08

    Magnesium alloy AM60 has high duc and toughness, which is expected to increase in demand for automotive applications. However, it is too active, and coatings have been extensively studied to prevent corrosion. In this work, a Ba-containing composite phosphate film has been prepared on the surface of AM60. The composition and formation mechanism of the film have been investigated using a scanning electronic microscope equipped with energy dispersive X-ray spectroscopy, Fourier transform infrared, X-ray photoelectron spectroscopy, and X-ray diffractometry tests. The corrosion resistance of the film has been measured by electrochemical and immersion tests. The results show that the deposition film has fully covered the substrate but there are some micro-cracks. The structure of the film is complex, and consists of MgHPO₄·3H₂O, MnHPO₄·2.25H₂O, BaHPO₄·3H₂O, BaMg₂(PO₄)₂, Mg₃(PO₄)₂·22H₂O, Ca₃(PO₄)₂·xH₂O, and some amorphous phases. The composite phosphate film has better anticorrosion performance than the AM60 and can protect the bare alloy from corrosion for more than 12 h in 0.6 M NaCl.

  14. Incremental dynamic analysis of concrete moment resisting frames reinforced with shape memory composite bars

    International Nuclear Information System (INIS)

    Zafar, Adeel; Andrawes, Bassem

    2012-01-01

    Fiber reinforced polymer (FRP) reinforcing bars have been used in concrete structures as an alternative to conventional steel reinforcement, in order to overcome corrosion problems. However, due to the linear behavior of the commonly used reinforcing fibers, they are not considered in structures which require ductility and damping characteristics. The use of superelastic shape memory alloy (SMA) fibers with their nonlinear elastic behavior as reinforcement in the composite could potentially provide a solution for this problem. Small diameter SMA wires are coupled with polymer matrix to produce SMA–FRP composite, which is sought in this research as reinforcing bars. SMA–FRP bars are sought in this study to enhance the seismic performance of reinforced concrete (RC) moment resisting frames (MRFs) in terms of reducing their residual inter-story drifts while still maintaining the elastic characteristics associated with conventional FRP. Three story one bay and six story two bay RC MRF prototype structures are designed with steel, SMA–FRP and glass–FRP reinforcement. The incremental dynamic analysis technique is used to investigate the behaviors of the two frames with the three different reinforcement types under a suite of ground motion records. It is found that the frames with SMA–FRP composite reinforcement exhibit higher performance levels including lower residual inter-story drifts, high energy dissipation and thus lower damage, which are important for structures in highly seismic zones. (paper)

  15. Corrosion resistance of Ni-Cr-Mo alloys. Chemical composition and metallurgical condition's effects

    International Nuclear Information System (INIS)

    Zadorozne, N.S.; Rebak, Raul B.

    2009-01-01

    P, may form if Ni-Cr-Mo alloys are exposed for tens of hours in the range of 600 C degrees to 1100 C degrees. These phases could have a detrimental effect upon corrosion resistance and cause a loss of mechanical ductility. The precipitation of TCP phases starts at grain boundaries and for long aging times it progresses to twins boundaries and then the grain bodies. TCP phases are rich in Mo and Cr. Zones in the matrix adjacent to the TCP precipitates may be depleted of Cr and Mo, and the alloy becomes sensitized.The aim of the present work was to compare the general corrosion rate and the crevice corrosion susceptibility of alloys C-22, C-22HS and HYBRID-BC1 in different metallurgical conditions when exposed to hot chloride solutions. The effects of the alloy composition and different heat treatments were assessed. (author)

  16. Renewable and superior thermal-resistant cellulose-based composite nonwoven as lithium-ion battery separator.

    Science.gov (United States)

    Zhang, Jianjun; Liu, Zhihong; Kong, Qingshan; Zhang, Chuanjian; Pang, Shuping; Yue, Liping; Wang, Xuejiang; Yao, Jianhua; Cui, Guanglei

    2013-01-01

    A renewable and superior thermal-resistant cellulose-based composite nonwoven was explored as lithium-ion battery separator via an electrospinning technique followed by a dip-coating process. It was demonstrated that such nanofibrous composite nonwoven possessed good electrolyte wettability, excellent heat tolerance, and high ionic conductivity. The cells using the composite separator displayed better rate capability and enhanced capacity retention, when compared to those of commercialized polypropylene separator under the same conditions. These fascinating characteristics would endow this renewable composite nonwoven a promising separator for high-power lithium-ion battery.

  17. Fracture Resistance of Endodontically Treated Teeth Restored with 2 Different Fiber-reinforced Composite and 2 Conventional Composite Resin Core Buildup Materials: An In Vitro Study.

    Science.gov (United States)

    Eapen, Ashly Mary; Amirtharaj, L Vijay; Sanjeev, Kavitha; Mahalaxmi, Sekar

    2017-09-01

    The purpose of this in vitro study was to comparatively evaluate the fracture resistance of endodontically treated teeth restored with 2 fiber-reinforced composite resins and 2 conventional composite resin core buildup materials. Sixty noncarious unrestored human maxillary premolars were collected, endodontically treated (except group 1, negative control), and randomly divided into 5 groups (n = 10). Group 2 was the positive control. The remaining 40 prepared teeth were restored with various direct core buildup materials as follows: group 3 teeth were restored with dual-cure composite resin, group 4 with posterior composite resin, group 5 with fiber-reinforced composite resin, and group 6 with short fiber-reinforced composite resin. Fracture strength testing was performed using a universal testing machine. The results were statistically analyzed by 1-way analysis of variance and the post hoc Tukey test. Fracture patterns for each sample were also examined under a light microscope to determine the level of fractures. The mean fracture resistance values (in newtons) were obtained as group 1 > group 6 > group 4 > group 3 > group 5 > group 2. Group 6 showed the highest mean fracture resistance value, which was significantly higher than the other experimental groups, and all the fractures occurred at the level of enamel. Within the limitations of this study, a short fiber-reinforced composite can be used as a direct core buildup material that can effectively resist heavy occlusal forces against fracture and may reinforce the remaining tooth structure in endodontically treated teeth. Copyright © 2017 American Association of Endodontists. Published by Elsevier Inc. All rights reserved.

  18. Adequate plasma drug concentrations suggest that amoxicillin can be administered by continuous infusion using elastomeric pumps.

    Science.gov (United States)

    Arensdorff, Lyne; Boillat-Blanco, Noémie; Decosterd, Laurent; Buclin, Thierry; de Vallière, Serge

    2017-09-01

    Elastomeric pumps can be useful for the administration of antibiotics in the outpatient setting. To determine amoxicillin degradation in elastomeric pumps, as well as the effectiveness of amoxicillin treatment administered by elastomeric pumps. Antibiotic degradation was measured in elastomeric pumps filled with 6 g of amoxicillin in 240 mL of NaCl 0.9% by drawing samples at 12 h intervals when stored in the fridge for 48 h and when worn around the waist for 24 h. Subsequently nine patients were treated with continuous infusions of 8 or 12 g of amoxicillin per day. Plasma amoxicillin concentrations were measured on each visit to the outpatient parenteral antibiotic therapy unit. Clinical outcome was verified 3 months after the end of treatment. Amoxicillin degradation in elastomeric pumps reached 10% after 48 h in the fridge and an additional 30% when worn around the waist for 24 h. Mean plasma drug concentrations achieved with 12 g of amoxicillin per day were 18.5 mg/L (95% CI 13.5-23.5), which is largely above the MIC of amoxicillin-susceptible bacteria. Nine patients treated for various complicated infections were cured and had no unexpected adverse effects. Adequate plasma drug concentrations and favourable clinical outcomes suggest that amoxicillin can be administered by continuous infusion using elastomeric pumps. This treatment modality does not fulfil formal requirements regarding pharmaceutical stability, but the resulting safety impact in patients is probably limited. Therapeutic drug monitoring and a close clinical follow-up are recommended if this route of administration is chosen. © The Author 2017. Published by Oxford University Press on behalf of the British Society for Antimicrobial Chemotherapy. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  19. Baxter elastomeric pumps: Weighing as an alternative to visual inspection.

    Science.gov (United States)

    Cusano, Ellen L; Ali, Raafi; Sawyer, Michael B; Chambers, Carole R; Tang, Patricia A

    2018-04-01

    Purpose Elastomeric pumps are used to administer 46-hour infusions of 5-fluorouracil (5FU). Baxter suggests patients visually monitor their pumps to ensure that infusions are proceeding correctly. This can be confusing and lead to concerns about under- or over-dosing. Baxter has not considered weighing pumps as a validated method for monitoring. This study aims to validate weighing as a more accurate method for patients and healthcare professionals, and describe real life Baxter Infusor™ variability. Methods Patients who had been started on a 46-hour 5FU infusion returned to the clinic approximately 24 h after starting treatment. The pump was weighed on a StarFrit kitchen scale, and date, time, and weights recorded. Patients were asked if they had a preference for weighing or visually inspecting their pump. Results Pumps ( n = 103) were weighed between 17.25 and 27.5 h after connection. The average weight of a pump was 189 g. Of 103 pumps weighed, 99 weighed less than expected, corresponding to average flow rates of 5.69 mL/h over the elapsed time. The expected flow rate is 5 mL/h with 10% variability. Average flow rates within the 17.25- to 27.5-hour window were 4.561 mL/h, which is 8.78% slower than expected, but within the 10% known variability. Forty-seven percent of patients didn't have a preference for either method, but for those who did have a preference, more than twice as many preferred weighing. Conclusion With proper education, weighing Baxter Infusors at home with kitchen scales can be an accepted and objective alternative to the current recommendation of visual inspection.

  20. Effect of storage period on the accuracy of elastomeric impressions

    Directory of Open Access Journals (Sweden)

    Eduardo Batista Franco

    2007-06-01

    Full Text Available AIMS: To investigate the effect of the storage period on the accuracy of recently developed elastomeric materials. METHODS: Simultaneous impressions of a steel die were taken using a polyether (I: Impregum Soft Heavy and Light body, 3M ESPE and vinyl polysiloxane (P: Perfectim Blue Velvet and Flexi-Velvet, J.Morita. The trays were loaded with the heavy-bodied impression materials while the light-bodied impression materials were simultaneously spread on the steel die. The impressions were poured after 2 hours, 24 hours, and 7 days. Impressions were stored at approximately 55% relative humidity and room temperature. Ten replicas were produced for each experimental condition (n=60. Accuracy of the stone dies was assessed with a depth-measuring microscope. The difference in height between the surface of the stone die and a standard metallic ring was recorded in micrometers at four demarcated points, by two independent examiners. Data were submitted to two-way ANOVA and Tukey test (a = 0.05. RESULTS: Significant differences were found among the groups. Smaller discrepancies were observed when pouring was performed up to 24 hours (I-2h= 65.0 ± 15.68 µm; I-24h= 81.6 ± 11.13 µm for the polyether, and up to 7 days for the vinyl polysiloxane (P-2h= 79.1 ± 13.82 µm; P-24h= 96.8 ± 6.02 µm; P-7d= 81.4 ± 4.3 µm. Significant dimensional discrepancies, however, were observed when polyether was stored for 7 days (I-7d= 295.3 ± 17.4 µm. CONCLUSION: Storage may significantly affect the dimensional accuracy of impressions and, thus, a maximum period and storage condition should be specified for the recently developed materials.

  1. Resistivity and Its Anisotropy Characterization of 3D-Printed Acrylonitrile Butadiene Styrene Copolymer (ABS/Carbon Black (CB Composites

    Directory of Open Access Journals (Sweden)

    Jie Zhang

    2017-01-01

    Full Text Available The rapid printing of 3D parts with desired electrical properties enables numerous applications. Fused deposition modeling (FDM using conductive thermoplastic composites has been a valuable approach for such fabrication. The parts produced by FDM possess various controllable structural features, but the effects of the structural features on the electrical properties remain to be determined. This study investigated the effects of these features on the electrical resistivity and resistivity anisotropy of 3D-printed ABS/CB composites. The effects of the process parameters of FDM, including the layer thickness, raster width, and air gap, on the resistivity in both the vertical and horizontal directions for cubic samples were studied because the internal structure of the printed parts depended on those process parameters. The resistivities of printed parts in different parameter combinations were measured by an impedance analyzer and finite element models were created to investigate the relationship between the resistivity and the internal structure. The results indicated that the parameters remarkably affected the resistivity due to the influence of voids and the bonding condition between adjacent fibers. The resistivity in the vertical direction ranged from 70.40 ± 2.88 Ω·m to 180.33 ± 8.21 Ω·m, and the resistivity in the horizontal direction ranged from 41.91 ± 2.29 Ω·m to 58.35 ± 0.61 Ω·m at the frequency of 1 kHz. Moreover, by adjusting the resistivities in different directions, the resistivity anisotropy of the printed parts can be manipulated from 1.01 to 3.59. This research may serve as a reference to fabricate parts with sophisticated geometry with desired electrical resistivity and resistivity anisotropy.

  2. THE INFLUENCE OF THE FILLER GRAIN COMPOSITION ON THE PROPERTIES OF THE HEAT-RESISTANT BASALTIC CONCRETE

    Directory of Open Access Journals (Sweden)

    A. M. Gadzhiev

    2017-01-01

    Full Text Available Objectives. The optimal granulometric composition of filler compound ensures the production of concrete having improved  physical and mechanical characteristics, as well as minimal binder  consumption. The properties of heat-resistant concrete largely  depend on the type and the ratio of its components. Taking this into  account, the aim of the study is to determine the optimal grain composition of heat-resistant concrete.Methods. Methods for optimising the properties of heatresistant basaltic concrete with a composite binder and  mechanochemical activation of the filler grains were used during the  course of the research.A simplex-centroid experiment design is  applied for this purpose. The composite binder was subjected to  mechanochemical activation. Samples were made by vibration-pressing from a concrete mix with a cone draught of 2 cm.Results. The grain composition of heat-resistant concrete is proved  to be the most important variable factor, regulating which the  properties of concrete can be varied. The compositions of heat- resistant basaltic concrete with activated composite binder having a  maximum application temperature of 700 ºС are developed. The  influence of the grain composition of the basaltic filler on the  properties of basaltic concrete using mathematical experiment planning methods is determined. The regression equations for the ultimate tensile strength and bending stress of basaltic concrete are  obtained for heating temperature of 700ºC.Conclusion. The granulometric composition of heat-resistant basaltic concrete based on the activated binder is optimised for basic physical and technical properties. The optimal granulometric  design of the composition of heat-resistant concrete indicates that as the coarse fraction (particles greater than 0.63 mm in the filler  composition increases, the ultimate tensile strength and bending  stress of heatresistant basaltic concrete is increased

  3. Ballistic Impact Resistance of Plain Woven Kenaf/Aramid Reinforced Polyvinyl Butyral Laminated Hybrid Composite

    Directory of Open Access Journals (Sweden)

    Suhad D. Salman

    2016-07-01

    Full Text Available Traditionally, the helmet shell has been used to provide protection against head injuries and fatalities caused by ballistic threats. In this study, because of the high cost of aramid fibres and the necessity for environmentally friendly alternatives, a portion of aramid was replaced with plain woven kenaf fibre, with different arrangements and thicknesses, without jeopardising the requirements demanded by U.S. Army helmet specifications. Furthermore, novel helmets were produced and tested to reduce the dependency on the ballistic resistance components. Their use could lead to helmets that are less costly and more easily available than conventional helmet armour. The hybrid materials subjected to ballistic tests were composed of 19 layers and were fabricated by the hot press technique using different numbers and configurations of plain woven kenaf and aramid layers. In the case of ballistic performance tests, a positive effect was found for the hybridisation of kenaf and aramid laminated composites.

  4. Grain boundary composition and irradiation-assisted stress corrosion cracking resistance in Type 348 stainless steel

    International Nuclear Information System (INIS)

    Jacobs, A.J.; Wozadlo, G.P.; Nakata, K.

    1994-01-01

    Scanning transmission electron microscopy (STEM) analyses, in-reactor swelling mandrel tests, and laboratory constant extension rate tensile (CERT) tests were conducted on nine custom type 348 (UNS S34800) stainless steel (SS) alloys in an attempt to correlate grain boundary composition with irradiation-assisted stress corrosion cracking (IASCC) resistance. Phosphorus (P) enrichment showed the best correlation with in-reactor test results, and chromium (Cr) depletion showed the best correlation with laboratory results. Silicon (Si) and P enrichment were found to depend quantitatively on the bulk concentrations of these elements. The amount of Cr depletion seemed dependent at least partially on the amounts of Si and/or P enrichment. Si and P enrichment and Cr depletion were suppressed by higher carbon (C) contents, such as that present in commercial-purity type 348 SS

  5. Contribution to the study of the influence of zinc bath composition on corrosion resistance of coatings obtained by galvanization

    International Nuclear Information System (INIS)

    Cabrillac, Claude

    1969-01-01

    This research thesis deals with the influence of zinc purity on the corrosion resistance of a coating obtained by galvanization, and on its effect on cathodic protection. This study therefore addresses methods and tests processes (notably salt spray test) aiming at assessing the efficiency of steel protection by hot galvanization, and aims at highlighting the influence of galvanization bath purity or composition on corrosion resistance of galvanized layers

  6. Improved Corrosion and Abrasion Resistance of Organic-Inorganic Composite Coated Electro-galvanized Steels for Digital TV Panels

    Energy Technology Data Exchange (ETDEWEB)

    Jo, Du-Hwan; Noh, Sang-Geol; Park, Jong-Tae; Kang, Choon-Ho [POSCO Technical Research Laboratories, Pohang (Korea, Republic of)

    2015-10-15

    Recently, household electronic industries require environmentally-friendly and highly functional steels in order to enhance the quality of human life. Customers especially require both excellent corrosion and abrasion resistant anti-fingerprint steels for digital TV panels. Thus POSCO has developed new functional electro-galvanized steels, which have double coated layers with organic-inorganic composites on the zinc surface of the steel for usage as the bottom chassis panel of TVs. The inorganic solution for the bottom layer consists of inorganic phosphate, magnesium, and zirconium compounds with a small amount of epoxy binder, and affords both improved adhesion properties by chemical conversion reactions and corrosion resistance due to a self-healing effect. The composite solution for the top layer was prepared by fine dispersion of organic-inorganic ingredients that consist of a urethane modified polyacrylate polymer, hardener, silica sol and a titanium complex inhibitor in aqueous media. Both composite solutions were coated on the steel surface by using a roll coater and then cured through an induction furnace in the electro-galvanizing line. New anti-fingerprint steel was evaluated for quality performance through such procedures as the salt spray test for corrosion resistance, tribological test for abrasion resistance, and conductivity test for surface electric conductance regarding to both types of polymer resin and coating weight of composite solution. New composite coated anti-fingerprint steels afford both better corrosion resistance and abrasion properties compared to conventional anti-fingerprint steel that mainly consists of acrylate polymers. Detailed discussions of both composite solutions and experimental results suggest that urethane modifications of acrylate polymers of composite solutions play a key role in enhanced quality performances.

  7. Microstructure and wear resistance of a laser clad TiC reinforced nickel aluminides matrix composite coating

    International Nuclear Information System (INIS)

    Chen, Y.; Wang, H.M.

    2004-01-01

    Wear resistant TiC/(NiAl-Ni 3 Al) composite coating was fabricated on a substrate of electrolyzed nickel by laser cladding using Ni-Al-Ti-C alloy powders. The laser clad coating is metallurgically bonded to the substrate and has a homogenous fine microstructure consisting of the flower-like equiaxed TiC dendrite and the dual phase matrix of NiAl and Ni 3 Al. The intermetallic matrix composite coating exhibits excellent wear resistance under both room- and high-temperature sliding wear test conditions due to the high hardness of TiC coupled with the strong atomic bonds of intermetallic matrix

  8. Data on post irradiation experiments of heat resistant ceramic composite materials. PIE for 97M-13A

    Energy Technology Data Exchange (ETDEWEB)

    Baba, Shin-ichi; Ishihara, Masahiro; Souzawa, Shizuo [Japan Atomic Energy Research Inst., Oarai, Ibaraki (Japan). Oarai Research Establishment; Sekino, Hajime [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    2003-03-01

    The research on the radiation damage mechanism of heat resistant ceramic composite materials is one of the research subjects of the innovative basic research in the field of high temperature engineering, using the High Temperature engineering Test Reactor (HTTR). Three series of irradiation tests on the heat resistant ceramic composite materials, first to third irradiation test program, were carried out using the Japan Material Testing Reactor (JMTR). This is a summary report on the first irradiation test program; irradiation induced dimensional change, thermal expansion coefficient, X-ray diffraction and {gamma}-ray spectrum are reported. (author)

  9. Superior high creep resistance of in situ nano-sized TiCx/Al-Cu-Mg composite.

    Science.gov (United States)

    Wang, Lei; Qiu, Feng; Zhao, Qinglong; Zha, Min; Jiang, Qichuan

    2017-07-03

    The tensile creep behavior of Al-Cu-Mg alloy and its composite containing in situ nano-sized TiC x were explored at temperatures of 493 K, 533 K and 573 K with the applied stresses in the range of 40 to 100 MPa. The composite reinforced by nano-sized TiC x particles exhibited excellent creep resistance ability, which was about 4-15 times higher than those of the unreinforced matrix alloy. The stress exponent of 5 was noticed for both Al-Cu-Mg alloy and its composite, which suggested that their creep behavior was related to dislocation climb mechanism. During deformation at elevated temperatures, the enhanced creep resistance of the composite was mainly attributed to two aspects: (a) Orowan strengthening and grain boundary (GB) strengthening induced by nano-sized TiC x particles, (b) θ' and S' precipitates strengthening.

  10. Triclosan-immobilized polyamide thin film composite membranes with enhanced biofouling resistance

    Science.gov (United States)

    Park, Sang-Hee; Hwang, Seon Oh; Kim, Taek-Seung; Cho, Arah; Kwon, Soon Jin; Kim, Kyoung Taek; Park, Hee-Deung; Lee, Jung-Hyun

    2018-06-01

    We report on a strategy to improve biofouling resistance of a polyamide (PA) thin-film composite (TFC) reverse osmosis (RO) membrane via chemically immobilizing triclosan (TC), known as a common organic biocide, on its surface. To facilitate covalent attachment of TC on the membrane surface, TC was functionalized with amine moiety to prepare aminopropyl TC. Then, the TC-immobilized TFC (TFC-TC) membranes were fabricated through a one-step amide formation reaction between amine groups of aminopropyl TC and acyl chloride groups present on the PA membrane surface, which was confirmed by high-resolution XPS. Strong stability of the immobilized TC was also confirmed by a hydraulic washing test. Although the TFC-TC membrane showed slightly reduced separation performance compared to the pristine control, it still maintained a satisfactory RO performance level. Importantly, the TFC-TC membrane exhibited excellent antibacterial activity against both gram negative (E. coli and P. aeruginosa) and gram positive (S. aureus) bacteria along with greatly enhanced resistance to biofilm formation. Our immobilization approach offers a robust and relatively benign strategy to control biofouling of functional surfaces, films and membranes.

  11. Role of polymeric binders on mechanical behavior and cracking resistance of silicon composite electrodes during electrochemical cycling

    Science.gov (United States)

    Li, Dawei; Wang, Yikai; Hu, Jiazhi; Lu, Bo; Dang, Dingying; Zhang, Junqian; Cheng, Yang-Tse

    2018-05-01

    This work focuses on understanding the role of various binders, including sodium alginate (SA), Nafion, and polyvinylidene fluoride (PVDF), on the mechanical behavior and cracking resistance of silicon composite electrodes during electrochemical cycling. In situ curvature measurement of bilayer electrodes, consisting of a silicon-binder-carbon black composite layer on a copper foil, is used to determine the effects of binders on bending deformation, elastic modulus, and stress on the composite electrodes. It is found that the lithiation induced curvature and the modulus of the silicon/SA electrodes are larger than those of electrodes with Nafion and PVDF as binders. Although the modulus of Nafion is smaller than that of PVDF, the curvature and the modulus of silicon/Nafion composite are larger than those of silicon/PVDF electrodes. The moduli of all three composites decrease not only during lithiation but also during delithiation. Based on the measured stress and scanning electron microscopy observations of cracking in the composite electrodes, we conclude that the stress required to crack the composite electrodes with SA and Nafion binders is considerably higher than that of the silicon/PVDF electrode during electrochemical cycling. Thus, the cracking resistance of silicon/SA and silicon/Nafion composite electrodes is higher than that of silicon/PVDF electrodes.

  12. Materials, Manufacturing, and Test Development of a Composite Fan Blade Leading Edge Subcomponent for Improved Impact Resistance

    Science.gov (United States)

    Miller, Sandi G.; Handschuh, Katherine; Sinnott, Matthew J.; Kohlman, Lee W.; Roberts, Gary D.; Martin, Richard E.; Ruggeri, Charles R.; Pereira, J. Michael

    2015-01-01

    Application of polymer matrix composite materials for jet engine fan blades is becoming attractive as an alternative to metallic blades; particularly for large engines where significant weight savings are recognized on moving to a composite structure. However, the weight benefit of the composite is offset by a reduction of aerodynamic efficiency resulting from a necessary increase in blade thickness; relative to the titanium blades. Blade dimensions are largely driven by resistance to damage on bird strike. Further development of the composite material is necessary to allow composite blade designs to approximate the dimensions of a metallic fan blade. The reduction in thickness over the state of the art composite blades is expected to translate into structural weight reduction, improved aerodynamic efficiency, and therefore reduced fuel consumption. This paper presents test article design, subcomponent blade leading edge fabrication, test method development, and initial results from ballistic impact of a gelatin projectile on the leading edge of composite fan blades. The simplified test article geometry was developed to realistically simulate a blade leading edge while decreasing fabrication complexity. Impact data is presented on baseline composite blades and toughened blades; where a considerable improvement to impact resistance was recorded.

  13. Analysis of impact resistance of composite fan blade. Fukugozai fan blade no taishogekisei no kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Miyachi, T; Okumura, H; Otake, K; Sofue, Y [Japan Society for Aeronautical and Space Sciences, Tokyo (Japan)

    1992-01-05

    Numerical analysis of impact response was carried out when a bird strike was simulated to study the applicability of fiber reinforced composite material to fan blades for turbo-fan engines. The validity of the numerical analysis was verified by comparing the analyzed results with impact tested results of a fan-blade model of Ti-alloy. The impact resistance was studied by applying this method to fan blades of composite materials such as carbon fiber, epoxy resin and carbon-silicate fiber reinforced Ti-alloy. The finite element method was used for the analysis by dividing the model into triangular flat elements. The relation between the impact load, the deformation of blade and the strain, the natural frequency characteristics, the elastic modulus and hetrogeneity of blade were considered to analyze the impact response. The impact load by the strike of 1.5 lbs bird is very severe to the fan blades for turbo-fan engines having the thrust of 5 ton class. 23 refs., 23 figs., 3 tabs.

  14. Evaluating the thermal damage resistance of graphene/carbon nanotube hybrid composite coatings

    Science.gov (United States)

    David, L.; Feldman, A.; Mansfield, E.; Lehman, J.; Singh, G.

    2014-03-01

    We study laser irradiation behavior of multiwalled carbon nanotubes (MWCNT) and chemically modified graphene (rGO)-composite spray coatings for use as a thermal absorber material for high-power laser calorimeters. Spray coatings on aluminum test coupon were exposed to increasing laser irradiance for extended exposure times to quantify their damage threshold and optical absorbance. The coatings, prepared at varying mass % of MWCNTs in rGO, demonstrated significantly higher damage threshold values at 2.5 kW laser power at 10.6 μm wavelength than carbon paint or MWCNTs alone. Electron microscopy and Raman spectroscopy of irradiated specimens show that the coating prepared at 50% CNT loading endure at least 2 kW.cm-2 for 10 seconds without significant damage. The improved damage resistance is attributed to the unique structure of the composite in which the MWCNTs act as an efficient absorber of laser light while the much larger rGO sheets surrounding them, dissipate the heat over a wider area.

  15. The effect of N-stearoylethanolamine on plasma lipid composition in rats with experimental insulin resistance

    Directory of Open Access Journals (Sweden)

    O. V. Onopchenko

    2015-02-01

    Full Text Available A model of insulin resistance (IR, induced by prolonged high fat diet with high content of saturated fats was used to investigate the effect of N-stearoylethanolamine (NSE on the composition of free fatty acids (FFA, plasma lipoprotein spectrum and content of proinflammatory cytokine TNFα in rats. The results of this work showed a rise in the content of monounsaturated fatty acids (18:1 n-9 and a reduction in the level of polyunsaturated fatty acids (20:4 n-6 in plasma of rats with experimental IR. These findings are accompanied by the increased TNFα production and significant changes in plasma lipoprotein profile of rats with the fat overload. Particularly, a decreased high-density lipoprotein (HDL cholesterol level and increased low-density (LDL and very low-density lipoprotein (VLDL cholesterol level were detected. The NSE administration to obese rats with IR restored the content of mono- and polyunsaturated FFA, increased HDL cholesterol content and reduced LDL cholesterol level. In addition, the IR rats treated with NSE showed normalization in the serum TNFα level. Our results showed the restoration of plasma lipid profile under NSE administration in rats with obesity-induced IR. Considering the fact that plasma lipid composition displays the lipid metabolism in general, the NSE actions may play a significant role in the prevention of IR-associated complications.

  16. Physics-Based Simulation and Experiment on Blast Protection of Infill Walls and Sandwich Composites Using New Generation of Nano Particle Reinforced Materials

    Science.gov (United States)

    Irshidat, Mohammad

    A critical issue for the development of nanotechnology is our ability to understand, model, and simulate the behavior of small structures and to make the connection between nano structure properties and their macroscopic functions. Material modeling and simulation helps to understand the process, to set the objectives that could guide laboratory efforts, and to control material structures, properties, and processes at physical implementation. These capabilities are vital to engineering design at the component and systems level. In this research, experimental-computational-analytical program was employed to investigate the performance of the new generation of polymeric nano-composite materials, like nano-particle reinforced elastomeric materials (NPREM), for the protection of masonry structures against blast loads. New design tools for using these kinds of materials to protect Infill Walls (e.g. masonry walls) against blast loading were established. These tools were also extended to cover other type of panels like sandwich composites. This investigation revealed that polymeric nano composite materials are strain rate sensitive and have large amount of voids distributed randomly inside the materials. Results from blast experiments showed increase in ultimate flexural resistance achieved by both unreinforced and nano reinforced polyurea retrofit systems applied to infill masonry walls. It was also observed that a thin elastomeric coating on the interior face of the walls could be effective at minimizing the fragmentation resulting from blast. More conclusions are provided with recommended future research.

  17. The effect of dietary pigmentation on the esthetic appearance of clear orthodontic elastomeric modules

    Directory of Open Access Journals (Sweden)

    Nabeel F Talic

    2016-01-01

    Conclusions: Coffee and tea are strong staining media that should be avoided by patients who opted to have esthetic appliances for their orthodontic treatment. Elastomeric modules manufactured by AU showed higher staining optical properties as compared to the other two companies, which could be related to the manufacturing processing of these modules.

  18. Physical and Chemical Stability of Urapidil in 0.9% Sodium Chloride in Elastomeric Infusion Pump.

    Science.gov (United States)

    Tomasello, Cristina; Leggieri, Anna; Rabbia, Franco; Veglio, Franco; Baietto, Lorena; Fulcheri, Chiara; De Nicolò, Amedeo; De Perri, Giovanni; D'Avolio, Antonio

    2016-01-01

    Urapidil is an antihypertensive agent, usually administered through intravenous bolus injection, slow-intravenous infusion, or continuous-drug infusion by perfusor. Since to date no evidences are available on drug stability in elastomeric pumps, patients have to be hospitalized. The purpose of this study was to validate an ultra-performance liquid chromatographic method to evaluate urapidil stability in an elastomeric infusion pump, in order to allow continuous infusion as home-care treatment. Analyses were conducted by diluting urapidil in an elastomeric pump. Two concentrations were evaluated: 1.6 mg/mL and 3.3 mg/mL. For the analyses, a reverse-phase ultra-performance liquid chromatographic- photodiode array detection instrument was used. Stressed degradation, pH changes, and visual clarity were used as stability indicators up to 10 days after urapidil solution preparation. The drug showed no more than 5% degradation during the test period at room temperature. No pH changes and no evidences of incompatibility were observed. Stress tests resulted in appreciable observation of degradation products. Considering the observed mean values, urapidil hydrochloride in sodium chloride 0.9% in elastomeric infusion pumps is stable for at least 10 days. These results indicate that this treatment could be administered at home for a prolonged duration (at least 7 days) with a satisfactory response. Copyright© by International Journal of Pharmaceutical Compounding, Inc.

  19. Modified resistivity-strain behavior through the incorporation of metallic particles in conductive polymer composite fibers containing carbon nanotubes

    NARCIS (Netherlands)

    Lin, L.; Deng, H.; Gao, X.; Zhang, S.M.; Bilotti, E.; Peijs, A.A.J.M.; Fu, Q.

    2013-01-01

    Eutectic metal particles and carbon nanotubes are incorporated into a thermoplastic polyurethane matrix through a simple but efficient method, melt compounding, to tune the resistivity-strain behavior of conductive polymer composite (CPC) fibers. Such a combination of conductive fillers is rarely

  20. Altered skeletal muscle fiber composition and size precede whole-body insulin resistance in young men with low birth weight

    DEFF Research Database (Denmark)

    Jensen, Christine B; Storgaard, Heidi; Madsbad, Sten

    2007-01-01

    CONTEXT: Low birth weight (LBW), a surrogate marker of an adverse fetal milieu, is linked to muscle insulin resistance, impaired insulin-stimulated glycolysis, and future risk of type 2 diabetes. Skeletal muscle mass, fiber composition, and capillary density are important determinants of muscle...

  1. Ex vivo fracture resistance of direct resin composite complete crowns with and without posts on maxillary premolars.

    NARCIS (Netherlands)

    Fokkinga, W.A.; Bell, A.M. Le; Kreulen, C.M.; Lassila, L.V.; Vallittu, P.K.; Creugers, N.H.J.

    2005-01-01

    AIM: To investigate ex vivo the fracture resistance and failure mode of direct resin composite complete crowns with and without various root canal posts made on maxillary premolars. METHODOLOGY: The clinical crowns of 40 human extracted single-rooted maxillary premolars were sectioned at the

  2. In vitro antibacterial activity of porous TiO2-Ag composite layers against methicillin-resistant Staphylococcus aureus

    NARCIS (Netherlands)

    Necula, Bogdan S.; Fratila-Apachitei, Lidy E.; Zaat, Sebastian A. J.; Apachitei, Iulian; Duszczyk, Jurek

    2009-01-01

    The aim of this study was the synthesis of a porous TiO(2)-Ag composite coating and assessment of its in vitro bactericidal activity against methicillin-resistant Staphylococcus aureus. The coating was produced by plasma electrolytic oxidation of Ti-6Al-7Nb medical alloy in a calcium acetate/calcium

  3. Biological degradation of wood-plastic composites (WPC) and strategies for improving the resistance of WPC against biological decay

    Science.gov (United States)

    Anke Schirp; Rebecca E. Ibach; David E. Pendleton; Michael P. Wolcott

    2008-01-01

    Much of the research on wood-plastic composites (WPC) has focused on formulation development and processing while high biological durability of the material was assumed. The gap between assumption and knowledge in biodeterioration of WPC needs to be reduced. Although some information on the short-term resistance of WPC against biological degradation is available, long-...

  4. Oxygen plasma treatment and deposition of CNx on a fluorinated polymer matrix composite for improved erosion resistance

    International Nuclear Information System (INIS)

    Muratore, C.; Korenyi-Both, A.; Bultman, J. E.; Waite, A. R.; Jones, J. G.; Storage, T. M.; Voevodin, A. A.

    2007-01-01

    The use of polymer matrix composites in aerospace propulsion applications is currently limited by insufficient resistance to erosion by abrasive media. Erosion resistant coatings may provide necessary protection; however, adhesion to many high temperature polymer matrix composite (PMC) materials is poor. A low pressure oxygen plasma treatment process was developed to improve adhesion of CN x coatings to a carbon reinforced, fluorinated polymer matrix composite. Fullerene-like CN x was selected as an erosion resistant coating for its high hardness-to-elastic modulus ratio and elastic resilience which were expected to reduce erosion from media incident at different angles (normal or glancing) relative to the surface. In situ x-ray photoelectron spectroscopy was used to evaluate the effect of the plasma treatment on surface chemistry, and electron microscopy was used to identify changes in the surface morphology of the PMC substrate after plasma exposure. The fluorine concentration at the surface was significantly reduced and the carbon fibers were exposed after plasma treatment. CN x coatings were then deposited on oxygen treated PMC substrates. Qualitative tests demonstrated that plasma treatment improved coating adhesion resulting in an erosion resistance improvement of a factor of 2 compared to untreated coated composite substrates. The combination of PMC pretreatment and coating with CN x reduced the erosion rate by an order of magnitude for normally incident particles

  5. Analysis of the Effect of Surface Modification on Polyimide Composites Coated with Erosion Resistant Materials

    Science.gov (United States)

    Ndalama, Tchinga; Hirschfeld, Deidre; Sutter, James K. (Technical Monitor)

    2003-01-01

    The aim of this research is to enhance performance of composite coatings through modification of graphite-reinforced polyimide composite surfaces prior to metal bond coat/ hard topcoat application for use in the erosive and/or oxidative environments of advanced engines. Graphite reinforced polyimide composites, PMR-15 and PMR-II-50, formed by sheet molding and pre-pregging will be surface treated, overlaid with a bond coat and then coated with WC-Co. The surface treatment will include cleaning, RF plasma or ultraviolet light- ozone etching, and deposition of SiO(x) groups. These surface treatments will be studied in order to investigate and improve adhesion and oxidation resistance. The following panels were provided by NASA-Glenn Research Center(NASA-GRC): Eight compression molded PMR-II-50; 6 x 6 x 0.125 in. Two vacuum-bagged PMR-II-50; 12 x 12 x 0.125 in. Eight compression molded PMR-15; 6 x 6 x 0.125 in. One vacuum-bagged PMR-15; 12 x 12 x 0.125 in. All panels were made using a 12 x 12 in. T650-35 8HS (3K-tow) graphite fabric. A diamond-wafering blade, with deionized water as a cutting fluid, was used to cut PMR-II-50 and PMR-15 panels into 1 x 1 in. pieces for surface tests. The panel edges exhibiting delamination were used for the preliminary surface preparation tests as these would be unsuitable for strength and erosion testing. PMR-15 neat resin samples were also provided by NASA GRC. Surface profiles of the as-received samples were determined using a Dektak III Surface profile measuring system. Two samples of compression molded PMR-II-50 and PMR-15, vacuum-bagged PMR-II-50 and PMR-15 were randomly chosen for surface profile measurement according to ANSI/ASME B46.1. Prior to each measurement, the samples were blasted with compressed air to remove any artifacts. Five 10 mm-long scans were made on each sample. The short and long wavelength cutoff filter values were set at 100 and 1000 m, diamond stylus radius was 12.5 microns. Table 1 is a summary of the

  6. Effect of Commonly Used Beverage, Soft Drink, and Mouthwash on Force Delivered by Elastomeric Chain: A Comparative In Vitro Study

    OpenAIRE

    Kumar, Kiran; Shetty, Sharath; Krithika, M J; Cyriac, Bobby

    2014-01-01

    Background: The objective was to evaluate and compare the effect of Coca-Cola®, tea, Listerine® mouthwash on the force delivered by elastomeric chain in vitro. Materials and Methods: Four specimen groups (distilled water, Coca-Cola®, tea, Listerine® mouthwash) with a total sample size of 480 specimens. A specimen is described as a four link grey close elastomeric chain. Jigs, each with a series of pins set 25 mm apart, was used to hold stretched elastomeric chains at a...

  7. Ablation resistance and mechanical/conductive properties of ZrB{sub 2} reinforced carbon based composites

    Energy Technology Data Exchange (ETDEWEB)

    Li, X.T.; Shi, J.L.; Zhang, H.; Zhang, G.B.; Guo, Q.G.; Liu, L. [Chinese Academy of Sciences, Taiyuan (China)

    2007-02-15

    Zirconium diboride reinforced carbon (ZrB{sub 2}/C) particulate composites are prepared from petroleum coke, coal tar pitch, and ZrB{sub 2} powder by hot-pressing. The ablation, mechanical, thermal, and electrical properties of the composites are studied. Results show that the composites have excellent flexural strength and thermal conductivity, with highest values reaching 131 MPa and 161 W/mK for a 10% ZrB{sub 2} addition in raw materials. The electrical resistivity reduces rapidly with increasing amount of ZrB{sub 2}. The values of mass and linear ablation rates are lower in the composites than those measured for pure carbon, decreasing with increasing ZrB{sub 2} content, confirming that these materials are promising for ultrahigh temperature materials. Correlations between properties and microstructure of the composites are also discussed.

  8. The flow Rate Accuracy of Elastomeric Infusion Pumps After Repeated Filling.

    Science.gov (United States)

    Mohseni, Masood; Ebneshahidi, Amin

    2014-05-01

    One of the frequent applications of elastomeric infusion pumps is postoperative pain management. In daily practice, the disposable pumps get refilled with modified medication combinations in the successive days; although, the accuracy of infusion rates is unknown to clinicians. Our aim was to evaluate the effect of repeated filling on the delivery rate accuracy of an elastomeric pump available in our market. We examined 10 elastomeric infusion pumps (BOT-802, Nanchang Biotek Medical Device Company, China) with 100 mL capacity and nominal flow of 5 mL/h. Each pump was filled for three times, accounting for 30 series of experiments. A microset scaled in mL was used to measure the pump deliveries. Flow profile and reliability of infusion rate were analyzed after repeated use. The mean flow rate in the three series of measurements showed a gradual increase; however, the difference was not statistically significant (5.01 ± 0.07 vs. 5.03 ± 0.06 vs. 5.06 ± 0.08 mL/h; P = 0.81). The percentage of the flow rate error (deviation from 5 mL/h ± 15%) was 100% in the first and second hours of infusion, 96% in the third hour, 60% in the 20th hour and zero percent in the rest of the infusion time. This study indicated that the delivery rate accuracy of elastomeric infusion pumps is preserved after repeated usage. These laboratory findings suggested that elastomeric pumps could be safely refilled in the successive days to provide postoperative analgesia.

  9. Beta-lactam resistance in the gram negatives: increasing complexity of conditional, composite and multiply resistant phenotypes.

    Science.gov (United States)

    Iredell, Jon; Thomas, Lee; Espedido, Björn

    2006-12-01

    The greatest impact of microbiology data on clinical care is in the critically ill. Unfortunately, this is also the area in which microbiology laboratories are most often non-contributive. Attempts to move to rapid, culture-independent diagnostics are driven by the need to expedite urgent results. This is difficult in Gram-negative infection because of the complexity of the antibiotic resistance phenotype. Here, we discuss resistance to modern beta-lactams as a case in point. Recent outbreaks of transmissible carbapenem resistance among Gram-negative enteric pathogens in Sydney and Melbourne serve to illustrate the pitfalls of traditional phenotypical approaches. A better understanding of the epidemiology and mosaic nature of antibiotic resistance elements in the microflora is needed for us to move forward.

  10. Changes in muscle size and MHC composition in response to resistance exercise with heavy and light loading intensity

    DEFF Research Database (Denmark)

    Holm, Lars; Reitelseder, Søren; Pedersen, T.G.

    2008-01-01

    Muscle mass accretion is accomplished by heavy-load resistance training. The effect of light-load resistance exercise has been far more sparsely investigated with regard to potential effect on muscle size and contractile strength. We applied a resistance exercise protocol in which the same indivi...... in healthy young men. However, LL resistance training was inferior to HL training in evoking adaptive changes in muscle size and contractile strength and was insufficient to induce changes in MHC composition.......Muscle mass accretion is accomplished by heavy-load resistance training. The effect of light-load resistance exercise has been far more sparsely investigated with regard to potential effect on muscle size and contractile strength. We applied a resistance exercise protocol in which the same.......05) in HL but remained unchanged in LL (4 +/- 5%, not significant). Finally, MHC IIX protein expression was decreased with HL but not LL, despite identical total workload in HL and LL. Our main finding was that LL resistance training was sufficient to induce a small but significant muscle hypertrophy...

  11. Electro-thermo-mechanical coupling analysis of deep drawing with resistance heating for aluminum matrix composites sheet

    Science.gov (United States)

    Zhang, Kaifeng; Zhang, Tuoda; Wang, Bo

    2013-05-01

    Recently, electro-plastic forming to be a focus of attention in materials hot processing research area, because it is a sort of energy-saving, high efficient and green manufacturing technology. An electro-thermo-mechanical model can be adopted to carry out the sequence simulation of aluminum matrix composites sheet deep drawing via electro-thermal coupling and thermal-mechanical coupling method. The first step of process is resistance heating of sheet, then turn off the power, and the second step is deep drawing. Temperature distribution of SiCp/2024Al composite sheet by resistance heating and sheet deep drawing deformation were analyzed. During the simulation, effect of contact resistances, temperature coefficient of resistance for electrode material and SiCp/2024Al composite on temperature distribution were integrally considered. The simulation results demonstrate that Sicp/2024Al composite sheet can be rapidly heated to 400° in 30s using resistances heating and the sheet temperature can be controlled by adjusting the current density. Physical properties of the electrode materials can significantly affect the composite sheet temperature distribution. The temperature difference between the center and the side of the sheet is proportional to the thermal conductivity of the electrode, the principal cause of which is that the heat transfers from the sheet to the electrode. SiCp/2024Al thin-wall part can be intactly manufactured at strain rate of 0.08s-1 and the sheet thickness thinning rate is limited within 20%, which corresponds well to the experimental result.

  12. Correlation of gut microbiota composition with resistance to experimental autoimmune encephalomyelitis in rats

    Directory of Open Access Journals (Sweden)

    Suzana Stanisavljevic

    2016-12-01

    Full Text Available Multiple sclerosis is a chronic inflammatory disease of the central nervous system (CNS. It is widely accepted that autoimmune response against the antigens of the CNS is the essential pathogenic force in the disease. It has recently become increasingly appreciated that activated encephalitogenic cells tend to migrate towards gut associated lymphoid tissues (GALT and that interrupted balance between regulatory and inflammatory immunity within the GALT might have decisive role in the initiation and propagation of the CNS autoimmunity. Gut microbiota composition and function has the major impact on the balance in the GALT. Thus, our aim was to perform analyses of gut microbiota in experimental autoimmune encephalomyelitis (EAE, an animal model of multiple sclerosis. Albino Oxford (AO rats that are highly resistant to EAE induction and Dark Agouti (DA rats that develop EAE after mild immunization were compared for gut microbiota composition in different phases after EAE induction. Microbial analyses of the genus Lactobacillus and related lactic acid bacteria showed higher diversity of Lactobacillus spp. in EAE-resistant AO rats, while some members of Firmicutes and Proteobacteria (Undibacterium oligocarboniphilum were detected only in faeces of DA rats at the peak of the disease (between 13 and 16 days after induction. Interestingly, Turicibacter sp. that was found exclusively in non-immunized AO, but not in DA rats in our previous study was detected in DA rats that remained healthy 16 days after induction. Similar observation was obtained for the members of Lachnospiraceae. As dominant presence of the members of Lachnospiraceae family in gut microbial community has been linked with mild symptoms of various diseases, it is tempting to assume that Turicibacter sp. and Lachnospiraceae contribute to the prevention of EAE development and the alleviation of the disease symptoms. Further, production of a typical regulatory cytokine interleukin-10 was

  13. Composite piping: basic materials, manufacturing methods, hydrolysis resistance. Bibliographical data and state of the art

    International Nuclear Information System (INIS)

    Pays, M.F.

    1997-01-01

    EDF has decided to replace traditional materials by glass reinforced plastic for the manufacture of certain PWR water piping. However, these are liable to in-service degradation through the hydrolysis of the operating conditions which can involve mechanical stresses or specific temperature and humidity conditions. These resins have been the subject of bibliographical surveys and laboratory experiments providing the following main results: the water diffusion in the selected thermoset resins (polyester, vinyl-ester, epoxy) can reach one percent in weight, according to the relative humidity and temperature; the water absorption is a reversible phenomenon, at the beginning and is followed by hydrolysis, an irreversible deterioration affecting the chemical functions of the polymeric chain. Thermally activated, the reaction limits the temperature for the use of these resins; polyester resins are made of a large number of ester bonds and are highly sensitive to hydrolysis. These resins can be classified on the basis of the alcohol and acid which they come acid. A possible hydrolytic degradation does not prevent from using these resins in humid environments. The cooling towers in Belleville, Nogent ad Chooz are equipped with water collecting channels made of polyester laminates which have behaved satisfactorily since their installation in 1982. In acid environments, even concentrated, resins have a better behavior than in a neutral medium. However, they can be liable to stress corrosion. Polyester resins ar not suitable for use in concentrated base media. Vinyl-ester resins are more appropriate for this purpose, although their resistance will be lower than in a neutral environment. When resins are used as a matrix for composites, the presence of glass fibers modifies their behavior. The physico-chemical protection of the fiber/matrix interfaces and of the surface of the glass itself through the sizing of the fibers plays key role in the durability of the composites, which

  14. Electrostatic Assembly Preparation of High-Toughness Zirconium Diboride-Based Ceramic Composites with Enhanced Thermal Shock Resistance Performance.

    Science.gov (United States)

    Zhang, Baoxi; Zhang, Xinghong; Hong, Changqing; Qiu, Yunfeng; Zhang, Jia; Han, Jiecai; Hu, PingAn

    2016-05-11

    The central problem of using ceramic as a structural material is its brittleness, which associated with rigid covalent or ionic bonds. Whiskers or fibers of strong ceramics such as silicon carbide (SiC) or silicon nitride (Si3N4) are widely embedded in a ceramic matrix to improve the strength and toughness. The incorporation of these insulating fillers can impede the thermal flow in ceramic matrix, thus decrease its thermal shock resistance that is required in some practical applications. Here we demonstrate that the toughness and thermal shock resistance of zirconium diboride (ZrB2)/SiC composites can be improved simultaneously by introducing graphene into composites via electrostatic assembly and subsequent sintering treatment. The incorporated graphene creates weak interfaces of grain boundaries (GBs) and optimal thermal conductance paths inside composites. In comparison to pristine ZrB2-SiC composites, the toughness of (2.0%) ZrB2-SiC/graphene composites exhibited a 61% increasing (from 4.3 to 6.93 MPa·m(1/2)) after spark plasma sintering (SPS); the retained strength after thermal shock increased as high as 74.8% at 400 °C and 304.4% at 500 °C. Present work presents an important guideline for producing high-toughness ceramic-based composites with enhanced thermal shock properties.

  15. Microstructure Characterization and Wear-Resistant Properties Evaluation of an Intermetallic Composite in Ni–Mo–Si System

    Directory of Open Access Journals (Sweden)

    Boyuan Huang

    2017-02-01

    Full Text Available Intermetallic compounds have been studied for their potential application as structural wear materials or coatings on engineering steels. In the present work, a newly designed intermetallic composite in a Ni–Mo–Si system was fabricated by arc-melting process with commercially pure metal powders as starting materials. The chemical composition of this intermetallic composite is 45Ni–40Mo–15Si (at %, selected according to the ternary alloy diagram. The microstructure was characterized using optical microscopy (OM, scanning electron microscopy (SEM, X-ray diffraction (XRD, and energy dispersive spectroscopy (EDS, and the wear-resistant properties at room temperature were evaluated under different wear test conditions. Microstructure characterization showed that the composite has a dense and uniform microstructure. XRD results showed that the intermetallic composite is constituted by a binary intermetallic compound NiMo and a ternary Mo2Ni3Si metal silicide phase. Wear test results indicated that the intermetallic composite has an excellent wear-resistance at room-temperature, which is attributed to the high hardness and strong atomic bonding of constituent phases NiMo and Mo2Ni3Si.

  16. Temperature Dependence of Electrical Resistance of Woven Melt-Infiltrated SiCf/SiC Ceramic Matrix Composites

    Science.gov (United States)

    Appleby, Matthew P.; Morscher, Gregory N.; Zhu, Dongming

    2016-01-01

    Recent studies have successfully shown the use of electrical resistance (ER)measurements to monitor room temperature damage accumulation in SiC fiber reinforced SiC matrix composites (SiCf/SiC) Ceramic Matrix Composites (CMCs). In order to determine the feasibility of resistance monitoring at elevated temperatures, the present work investigates the temperature dependent electrical response of various MI (Melt Infiltrated)-CVI (Chemical Vapor Infiltrated) SiC/SiC composites containing Hi-Nicalon Type S, Tyranno ZMI and SA reinforcing fibers. Test were conducted using a commercially available isothermal testing apparatus as well as a novel, laser-based heating approach developed to more accurately simulate thermomechanical testing of CMCs. Secondly, a post-test inspection technique is demonstrated to show the effect of high-temperature exposure on electrical properties. Analysis was performed to determine the respective contribution of the fiber and matrix to the overall composite conductivity at elevated temperatures. It was concluded that because the silicon-rich matrix material dominates the electrical response at high temperature, ER monitoring would continue to be a feasible method for monitoring stress dependent matrix cracking of melt-infiltrated SiC/SiC composites under high temperature mechanical testing conditions. Finally, the effect of thermal gradients generated during localized heating of tensile coupons on overall electrical response of the composite is determined.

  17. A Resistive Humidity Sensor Based on Nanostructured WO3-ZnO Composites

    Directory of Open Access Journals (Sweden)

    Karunesh Tiwari

    2011-11-01

    Full Text Available Paper reports morphological and humidity sensing studies of WO3 and WO3-ZnO composite pellets prepared in the weight % ratio of 10:1, 4:1 and 2:1 by solid-state reaction route. The pellets have been annealed at temperatures of 300-500 °C. XRD pattern shows peaks of ZnWO4 formed due to solid state reaction between WO3 and ZnO. SEM micrographs show that the sensing elements manifest porous structure. Granulation and tendency to agglomerate seen in the SEM micrograph are due to the presence of zinc ions in ZnWO4. Nanoparticles are having their sizes in the range 37-182 nm. The average Kelvin radius at 20˚C room temperature is 27 Ả. Humidity sensing application of the pellets has been studied in a humidity control cabinet. It is observed that as relative humidity increases, there is decrease in the resistance of pellets in the range 10-85 % RH. Sensing element of WO3-ZnO in 2:1 weight % ratio shows best results in 10-85 % relative humidity range. The average sensitivity of this sample is 1.25 MΩ/%RH. This sensing element shows good reproducibility, low hysteresis and less effect of aging.

  18. Biodegradation Resistance and Bioactivity of Hydroxyapatite Enhanced Mg-Zn Composites via Selective Laser Melting

    Directory of Open Access Journals (Sweden)

    Cijun Shuai

    2017-03-01

    Full Text Available Mg-Zn alloys have attracted great attention as implant biomaterials due to their biodegradability and biomechanical compatibility. However, their clinical application was limited due to the too rapid degradation. In the study, hydroxyapatite (HA was incorporated into Mg-Zn alloy via selective laser melting. Results showed that the degradation rate slowed down due to the decrease of grain size and the formation of protective layer of bone-like apatite. Moreover, the grain size continually decreased with increasing HA content, which was attributed to the heterogeneous nucleation and increased number of nucleation particles in the process of solidification. At the same time, the amount of bone-like apatite increased because HA could provide favorable areas for apatite nucleation. Besides, HA also enhanced the hardness due to the fine grain strengthening and second phase strengthening. However, some pores occurred owing to the agglomerate of HA when its content was excessive, which decreased the biodegradation resistance. These results demonstrated that the Mg-Zn/HA composites were potential implant biomaterials.

  19. Biodegradation Resistance and Bioactivity of Hydroxyapatite Enhanced Mg-Zn Composites via Selective Laser Melting.

    Science.gov (United States)

    Shuai, Cijun; Zhou, Yuanzhuo; Yang, Youwen; Feng, Pei; Liu, Long; He, Chongxian; Zhao, Mingchun; Yang, Sheng; Gao, Chengde; Wu, Ping

    2017-03-17

    Mg-Zn alloys have attracted great attention as implant biomaterials due to their biodegradability and biomechanical compatibility. However, their clinical application was limited due to the too rapid degradation. In the study, hydroxyapatite (HA) was incorporated into Mg-Zn alloy via selective laser melting. Results showed that the degradation rate slowed down due to the decrease of grain size and the formation of protective layer of bone-like apatite. Moreover, the grain size continually decreased with increasing HA content, which was attributed to the heterogeneous nucleation and increased number of nucleation particles in the process of solidification. At the same time, the amount of bone-like apatite increased because HA could provide favorable areas for apatite nucleation. Besides, HA also enhanced the hardness due to the fine grain strengthening and second phase strengthening. However, some pores occurred owing to the agglomerate of HA when its content was excessive, which decreased the biodegradation resistance. These results demonstrated that the Mg-Zn/HA composites were potential implant biomaterials.

  20. Dendrimeric Thin-Film Composite Membranes: Free Volume, Roughness, and Fouling Resistance

    KAUST Repository

    Phuoc, Duong

    2017-11-10

    Copolyamide films with a thickness from 50 to 780 nm were fabricated by interfacial polymerization between mixtures of m-phenylene diamine and primary amine-terminated polyamidoamine dendrimers (PAMAM) in the aqueous phase and trimesoyl chloride (TMC) in the organic phase. Different PAMAM generations (G0, d = 15 Å, Z = 4; G3, d = 36 Å, Z = 32; and G5, d = 54, Z = 128, where d is the measured diameter and Z is the number of terminal groups) and concentrations were used to obtain copolyamide films with different crosslinked structures. The influences of the concentration and degree of branching (PAMAM generation) on free volume were analysed via positon annihilation spectroscopy (PAS) and correlated with the separation properties of copolyamide films. Besides, surface and intrinsic properties of copolyamide films under different conditions were compared. The high hydrophilicity of PAMAM in the copolyamide network leads to the formation of a hydration layer on the copolyamide surface, which minimizes fouling. The separation performance of copolyamide membranes with various PAMAM networks was investigated in forward osmosis (FO) experiments. Understanding the correlation between the PAMAM structure/concentration, free volume, thickness, and surface intrinsic properties leads to the design of suitable fouling resistant thin-film composite membranes in a single interfacial polymerization process.

  1. An experimental estimation of the resistance against a high-temperature gas corrosion of C/C composite materials with protective plasma coating

    International Nuclear Information System (INIS)

    Babin, S.V.; Khripakov, E.V.

    2007-01-01

    Materials with well-defined structure has been proposed as corrosion- and erosion-resistant coating from the carbon-carbon composite. Experiments on heat and erosion resistance of plasma coatings at carbon-carbon composite materials demonstrate availability of multilayer with upper erosion resistant layer on the basis of aluminium oxide, intermediate layer on the basis of boron-containing components with aluminium additions and damping layer of silicon carbide. Multilayer protective coats offer demand service characteristics of details [ru

  2. Composite plasma electrolytic oxidation to improve the thermal radiation performance and corrosion resistance on an Al substrate

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Donghyun [Department of Materials Science and Engineering, Pusan National University, Busan 46241 (Korea, Republic of); Sung, Dahye [Department of Materials Science and Engineering, Pusan National University, Busan 46241 (Korea, Republic of); Korea Institute of Industrial Technology (KITECH), Busan 46742 (Korea, Republic of); Lee, Junghoon [Department of Mechanical Engineering, Stevens Institute of Technology, Hoboken, NJ 07030 (United States); Kim, Yonghwan [Korea Institute of Industrial Technology (KITECH), Busan 46742 (Korea, Republic of); Chung, Wonsub, E-mail: wschung1@pusan.ac.kr [Department of Materials Science and Engineering, Pusan National University, Busan 46241 (Korea, Republic of)

    2015-12-01

    Highlights: • Composite plasma electrolytic oxidation was performed using dispersed CuO particles in convectional PEO electrolyte. • Thermal radiation performance and corrosion resistance were examined by FT-IR spectroscopy and electrochemical methods, respectively. • Deposited copper oxide on the surface of the Al substrate was enhanced the corrosion resistance and the emissivity compared with the conventional PEO. - Abstract: A composite plasma electrolytic oxidation (PEO) was performed for enhancing the thermal radiation performance and corrosion resistance on an Al alloy by dispersing cupric oxide (CuO) particles in a conventional PEO electrolyte. Cu-based oxides (CuO and Cu{sub 2}O) formed by composite PEO increased the emissivity of the substrate to 0.892, and made the surface being dark color, similar to a black body, i.e., an ideal radiator. In addition, the corrosion resistance was analyzed using potentio-dynamic polarization and electrochemical impedance spectroscopy tests in 3.5 wt.% NaCl aqueous solution. An optimum condition of 10 ampere per square decimeter (ASD) current density and 30 min processing time produced appropriate surface morphologies and coating thicknesses, as well as dense Cu- and Al-based oxides that constituted the coating layers.

  3. Effect of length and diameter of fiber reinforced composite post (FRC on fracture resistance of remaining tooth structure

    Directory of Open Access Journals (Sweden)

    Mahdiyeh seifi

    2013-03-01

    Full Text Available Introduction: Post and core has been considered for endodontically treated tooth, especially in cases with severe damage crowns. Recently fiber reinforced composite posts (FRC post have been used in the treatment of endodontically treated teeth. Because the length and diameter of posts are effective in stress distribution, the purpose of this study is to evaluate the effect of length and diameter of FRC post on fracture resistance. Methods: In this experimental study, 36 glass fiber posts with combination of 7mm, 9mm, and 12mm length and 1.1mm, 1.3mm and 1.5mm diameter were divided into 9 groups of 4. These posts were cemented in root canals by Panavia. Samples were tested with 45° compressive forces for the evaluation of fracture resistance. Datas were analyzed using SPSS soft ware and One- way and Two-way ANOVA analyses. Results: Fracture resistance did not increase significantly with the effect of length and diameter simultaneously (P=0.85. Samples with 12mm length and 1.5mm diameter had the greatest fracture resistance (1023/33N±239/22. The minimum fracture resistance had occurred in post with 7mm length and 1.5mm diameter (503/13N ±69/18. Fracture resistance increased significantly by increasing the length and the same diameter. Conclusion: It can be concluded that fracture resistance is affected by the length and not the diameter of FRC post.

  4. Effect of different composite core materials on fracture resistance of endodontically treated teeth restored with FRC posts.

    Science.gov (United States)

    Panitiwat, Prapaporn; Salimee, Prarom

    2017-01-01

    This study evaluated the fracture resistance of endodontically treated teeth restored with fiber reinforced composite posts, using three resin composite core build-up materials, (Clearfil Photo Core (CPC), MultiCore Flow (MCF), and LuxaCore Z-Dual (LCZ)), and a nanohybrid composite, (Tetric N-Ceram (TNC)). Forty endodontically treated lower first premolars were restored with quartz fiber posts (D.T. Light-Post) cemented with resin cement (Panavia F2.0). Samples were randomly divided into four groups (n=10). Each group was built-up with one of the four core materials following its manufacturers' instructions. The teeth were embedded in acrylic resin blocks. Nickel-Chromium crowns were fixed on the specimens with resin cement. The fracture resistance was determined using a universal testing machine with a crosshead speed of 1 mm/min at 1350 to the tooth axis until failure occurred. All core materials used in the study were subjected to test for the flexural modulus according to ISO 4049:2009. One-way ANOVA and Bonferroni multiple comparisons test indicated that the fracture resistance was higher in the groups with CPC and MCF, which presented no statistically significant difference (p>0.05), but was significantly higher than in those with LCZ and TNC (paligned with the same tendency of fracture loads. Among the cores used in this study, the composite core with high filler content tended to enhance fracture thresholds of teeth restored with fiber posts more than others.

  5. The impact of a 12-week resistance training program on strength, body composition, and self-concept of Hispanic adolescents.

    Science.gov (United States)

    Velez, Amelia; Golem, Devon L; Arent, Shawn M

    2010-04-01

    Current evidence suggests that a resistance training program may be physically and psychologically beneficial for adolescents. The purpose of this study was to examine the effects of a structured resistance training program on strength, body composition, and self-concept in normal and overweight Hispanic adolescents. Male and female participants (n = 28; 16.1 +/- 0.2 y; 164.5 +/- 1.4 cm; 63.3 +/- 2.5 kg; 20.0 +/- 1.7% body fat [BF]) were recruited from a predominantly Hispanic high school. Prior to the 12-week program, strength, body composition, and self-concept were assessed. Subjects were randomly assigned to a control group (CON; n = 15) or to a resistance training group (RT; n = 13) that participated in supervised strength training 3 days/week. All measures were repeated at the end of the 12-week program. RT had significantly greater strength increases for bench press (p increased %BF. RT had an increase in condition/stamina competence (p = 0.008), attractive body adequacy (p = 0.017), and global self-worth (p = 0.013) from pretest to posttest, whereas no change was observed for CON. In conclusion, resistance training resulted in significant physiological and psychological improvements in Hispanic adolescents compared to typical school-based activities. These findings indicate that resistance training can be incorporated into the activities of Hispanic adolescents to promote improved health and fitness.

  6. Fracture Resistance of Ceramic Laminate Veneers Bonded to Teeth with Class V Composite Fillings after Cyclic Loading

    Directory of Open Access Journals (Sweden)

    Leyla Sadighpour

    2018-01-01

    Full Text Available Purpose. Porcelain laminate veneers (PLVs are sometimes required to be used for teeth with composite fillings. This study examined the fracture strength of PLVs bonded to the teeth restored with different sizes of class V composite fillings. Materials and Methods. Thirty-six maxillary central incisors were divided into three groups (n=12: intact teeth (control and teeth with class V composite fillings of one-third or two-thirds of the crown height (small or large group, resp.. PLVs were made by using IPS e.max and bonded with a resin cement (RelyX Unicem. Fracture resistance (N was measured after cyclic loading (1 × 106 cycles, 1.2 Hz. For statistical analyses, one-way ANOVA and Tukey test were used (α=0.05. Results. There was a significant difference between the mean failure loads of the test groups (P=0.004, with the Tukey-HSD test showing lower failure loads in the large-composite group compared to the control (P=0.02 or small group (P=0.05. The control and small-composite groups achieved comparable results (P>0.05. Conclusions. Failure loads of PLVs bonded to intact teeth and to teeth with small class V composite fillings were not significantly different. However, extensive composite fillings could compromise the bonding of PLVs.

  7. Towards the improvement of the oxidation resistance of Nb-silicides in situ composites: A solid state diffusion approach

    International Nuclear Information System (INIS)

    Mathieu, S.; Knittel, S.; François, M.; Portebois, L.; Mathieu, S.; Vilasi, M.

    2014-01-01

    Highlights: •Local equilibrium is attained during oxidation at phase boundaries (steady state conditions). •A solid state diffusion model explains the oxidation mechanism of Nb-silicides composites. •The Nb ss fraction is not the only parameters governing the oxidation rate of Nb-silicides. •Aluminium increases the thermodynamic activity of Si in the Nb-silicides composites. •The results indicate the need to develop a Nb–Ti–Hf–Al–Cr–Si thermodynamic database. -- Abstract: The present study focuses on the oxidation mechanism of Nb-silicide composites and on the effect of the composition on the oxidation rate at 1100 °C. A theoretical approach is proposed based on experimental results and used to optimise the oxidation resistance. The growth model based on multiphase diffusion was experimentally tested and confirmed by manufacturing seven composites with different compositions. It was also found that the effect of the composition has to be evaluated at 1100 °C within a short time duration (50 h), where the oxide scale and the internal oxidation zone both grow according to parabolic kinetics

  8. Effect of domain size and interface characteristics on the impact resistance of selected polymer composites

    Science.gov (United States)

    Viratyaporn, Wantinee

    Nanocomposite technology has advanced considerably in recent years and excellent engineering properties have been achieved in numerous systems. In multiphase materials the enhancement of properties relies heavily on the nature at the interphase region between polymer domains and nanoparticle reinforcements. Strong adhesion between the phases provides excellent load-transfer and good mechanical elastic modulus and strength, whereas weak interaction contributes to crack deflection mechanisms and toughness. Polymer molecules are large and the presence of comparably sized filler particles affects chain gyration, which in turn influences the conformation of the polymer and the properties of the composite. Nanoparticles were incorporated into a poly(methyl methacrylate) matrix by means of in situ free radical (bulk) polymerization. Aluminum oxide and zinc oxide nanoparticles were added to study the effects of particle chemistry and shape on selected mechanical properties such as impact resistance, which showed significant improvement at a certain loading of zinc oxide. The elongated shape of zinc oxide particles appears to promote crack deflection processes and to introduce a pull-out mechanism similar to that observed in fiber composite systems. Moreover, the thermal stability of PMMA was improved with the addition of nanoparticles, apparently by steric hindrance of polymer chain motion and a second mechanism related to the dipole inducing effect of the oxide particles. The sensitivity of infrared spectroscopy to changes in molecular dipoles was used to study the nature of the polymer/particle interface. The results revealed some interesting aspects of the secondary bonds between polymers and oxides. Raman spectroscopy was used to investigate the extent of polymerization and changes in polymer conformation. A degree of polymerization of 93% was achieved in neat PMMA, and even when 5.0 v/o of PGMEA was introduced into the system no monomer was detected. However, when

  9. Effect of Volume Fraction of Particle on Wear Resistance of Al2O3/Steel Composites at Elevated Temperature

    Institute of Scientific and Technical Information of China (English)

    BAO Chong-gao; WANG En-ze; GAO Yi-min; XING Jian-dong

    2005-01-01

    Based on previous work,abrasive wear resistance of Al2 O3/steel composites with different Al2 O3 parti cle volume fraction (VOF) at 900 C was investigated.The experimental results showed that a suitable particle VOF is important to protect the metal matrix from wear at elevated temperature.Both too high and too low particle VOF lead to a poor abrasive wear because a bulk matrix is easily worn off by grits when it exceeds the suitable VOF and also because when VOF is low,the Al2O3 particles are easily dug out by grits during wearing as well.When the particle VOF is 39%,the wear resistance of tested composites is excellent.

  10. High Kinetic Energy Penetrator Shielding and High Wear Resistance Materials Fabricated with Boron Nitride Nanotubes (BNNTS) and BNNT Polymer Composites

    Science.gov (United States)

    Kang, Jin Ho (Inventor); Sauti, Godfrey (Inventor); Smith, Michael W. (Inventor); Jordan, Kevin C. (Inventor); Park, Cheol (Inventor); Bryant, Robert George (Inventor); Lowther, Sharon E. (Inventor)

    2015-01-01

    Boron nitride nanotubes (BNNTs), boron nitride nanoparticles (BNNPs), carbon nanotubes (CNTs), graphites, or combinations, are incorporated into matrices of polymer, ceramic or metals. Fibers, yarns, and woven or nonwoven mats of BNNTs are used as toughening layers in penetration resistant materials to maximize energy absorption and/or high hardness layers to rebound or deform penetrators. They can be also used as reinforcing inclusions combining with other polymer matrices to create composite layers like typical reinforcing fibers such as Kevlar.RTM., Spectra.RTM., ceramics and metals. Enhanced wear resistance and usage time are achieved by adding boron nitride nanomaterials, increasing hardness and toughness. Such materials can be used in high temperature environments since the oxidation temperature of BNNTs exceeds 800.degree. C. in air. Boron nitride based composites are useful as strong structural materials for anti-micrometeorite layers for spacecraft and space suits, ultra strong tethers, protective gear, vehicles, helmets, shields and safety suits/helmets for industry.

  11. Effect of chemical composition on corrosion resistance of Zircaloy fuel cladding tube for BWR

    International Nuclear Information System (INIS)

    Inagaki, Masahisa; Akahori, Kimihiko; Kuniya, Jirou; Masaoka, Isao; Suwa, Masateru; Maru, Akira; Yasuda, Teturou; Maki, Hideo.

    1990-01-01

    Effects of Fe and Ni contents on nodular corrosion susceptibility and hydrogen pick-up of Zircaloy were investigated. Total number of 31 Zr alloys having different chemical compositions; five Zr-Sn-Fe-Cr alloys, eight Zr-Sn-Fe-Ni alloys and eighteen Zr-Sn-Fe-Ni-Cr alloys, were melted and processed to thin plates for the corrosion tests in the environments of a high temperature (510degC) steam and a high temperature (288degC) water. In addition, four 450 kg ingots of Zr-Sn-Fe-Ni-Cr alloys were industrially melted and BWR fuel cladding tubes were manufactured through a current material processing sequence to study their producibility, tensile properties and corrosion resistance. Nodular corrosion susceptibility decreased with increasing Fe and Ni contents of Zircaloys. It was seen that the improved Zircaloys having Fe and Ni contents in the range of 0.30 [Ni]+0.15[Fe]≥0.045 (w%) showed no susceptibility to nodular corrosion. An increase of Fe content resulted in a decrease of hydrogen pick-up fraction in both steam and water environments. An increase of Fe and Ni content of Zircaloys in the range of Fe≤0.25 w% and Ni≤0.1 w% did not cause the changes in tensile properties and fabricabilities of fuel cladding tube. The fuel cladding tube of improved Zircaloy, containing more amount of Fe and Ni than the upper limit of Zircaloy-2 specification showed no susceptibility to nodular corrosion even in the 530degC steam test. (author)

  12. Sensitivity improvement of a fibre Bragg grating pH sensor with elastomeric coating

    Science.gov (United States)

    Yulianti, Ian; Supa'at, A. S. M.; Idrus, Sevia M.; Kurdi, Ojo; Anwar, M. R. S.

    2012-01-01

    A new optical pH sensor based on fibre Bragg grating (FBG) is demonstrated. The sensor consists of a FBG coated with pH sensitive hydrogel. The sensing was performed through the detection of wavelength shifts resulting from the induced strain on the FBG due to mechanical expansion of the hydrogel. An elastomeric coating was applied before the hydrogel coating to improve the sensitivity. The sensor performance was investigated by simulating the hydrogel swelling and the strain induced on the FBG. The swelling of hydrogel due to pH change was modelled using a free-energy function and was solved using the finite element method. With silicone rubber as the elastomer material, the results show that the sensitivity was improved by up to 66% compared to that of the FBG pH sensor without elastomeric coating.

  13. Sensitivity improvement of a fibre Bragg grating pH sensor with elastomeric coating

    International Nuclear Information System (INIS)

    Yulianti, Ian; Supa'at, A S M; Idrus, Sevia M; Anwar, M R S; Kurdi, Ojo

    2012-01-01

    A new optical pH sensor based on fibre Bragg grating (FBG) is demonstrated. The sensor consists of a FBG coated with pH sensitive hydrogel. The sensing was performed through the detection of wavelength shifts resulting from the induced strain on the FBG due to mechanical expansion of the hydrogel. An elastomeric coating was applied before the hydrogel coating to improve the sensitivity. The sensor performance was investigated by simulating the hydrogel swelling and the strain induced on the FBG. The swelling of hydrogel due to pH change was modelled using a free-energy function and was solved using the finite element method. With silicone rubber as the elastomer material, the results show that the sensitivity was improved by up to 66% compared to that of the FBG pH sensor without elastomeric coating

  14. Determining the fracture resistance of fibre-reinforced glass matrix composites by means of the chevron-notch flexural technique

    Czech Academy of Sciences Publication Activity Database

    Boccaccini, A. R.; Kern, H.; Dlouhý, Ivo

    2001-01-01

    Roč. 308, 1/2 (2001), s. 111-117 ISSN 0921-5093 R&D Projects: GA ČR GV101/96/K264 Institutional research plan: CEZ:AV0Z2041904 Keywords : glass matrix composites * fracture toughness * chevron notch test Subject RIV: JH - Ceramics, Fire-Resistant Materials and Glass Impact factor: 0.978, year: 2001

  15. Changes in body composition in heart failure patients after a resistance exercise program and branched chain amino acid supplementation.

    Science.gov (United States)

    Pineda-Juárez, Juan Antonio; Sánchez-Ortiz, Néstor Alonso; Castillo-Martínez, Lilia; Orea-Tejeda, Arturo; Cervantes-Gaytán, Rocío; Keirns-Davis, Candace; Pérez-Ocampo, Carlos; Quiroz-Bautista, Karla; Tenorio-Dupont, Mónica; Ronquillo-Martínez, Alberto

    2016-02-01

    Heart Failure (HF) is a complex syndrome, which can include the physiological, neural hormonal and metabolic complications known as "Cardiac Cachexia" (CC). In the development of CC there is a release of catabolic cytokines (Tumor Necrosis Factor-α, interleukins 1 and 6) that cause a decrease of fat free mass and fat mass. These changes in body composition might be reversed with a therapeutic combination of resistance exercise and branched chain amino acid supplementation (BCAA). Evaluate changes in body composition after a resistance exercise program and BCAA supplementation in patients with HF. In a randomized clinical trial with 3 month of follow-up anthropometric body composition analysis and stress tests were evaluated at the beginning and in the end of the study. Patients were divided into two groups; the experimental group performed the resistance exercise program and received 10 g/day BCAA supplementation, and the control group only performed the resistance exercise program. Both groups were provided with individualized diets and conventional medical treatment. Changes were found in hip circumference between the groups (p = 0.02), and muscle strength was increased in the experimental group (8%) and the control group (11.4%) with no difference between them. METS and VO2Max also increased in experimental and control groups (16.6% and 50.1% respectively). Regarding changes in symptoms, improvements in fatigue (45.4%), decubitus intolerance (21.8%) and dyspnea (25.4%) were observed in the overall sample. Improvements in physical and functional capacities are attributed to resistance exercise program but not to the BCAA supplementation. NCT02240511. Copyright © 2015 Elsevier Ltd and European Society for Clinical Nutrition and Metabolism. All rights reserved.

  16. Permeation of "Hydromer" Film: An Elastomeric Hydrogen-Capturing Biopolymer.

    Energy Technology Data Exchange (ETDEWEB)

    Karnesky, Richard A. [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Friddle, Raymond William [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Whaley, Josh A. [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Smith, Geoffrey [New Mexico State Univ., Las Cruces, NM (United States)

    2015-12-01

    This report analyzes the permeation resistance of a novel and proprietary polymer coating for hydrogen isotope resistance that was developed by New Mexico State University. Thermal gravimetric analysis and thermal desoprtion spectroscopy show the polymer is stable thermally to approximately 250 deg C. Deuterium gas-driven permeation experiments were conducted at Sandia to explore early evidence (obtained using Brunauer - Emmett - Teller) of the polymer's strong resistance to hydrogen. With a relatively small amount of the polymer in solution (0.15%), a decrease in diffusion by a factor of 2 is observed at 100 and 150 deg C. While there was very little reduction in permeability, the preliminary findings reported here are meant to demonstrate the sensitivity of Sandia's permeation measurements and are intended to motivate the future exploration of thicker barriers with greater polymer coverage.

  17. Effects of atmospheric pressure conditions on flow rate of an elastomeric infusion pump.

    Science.gov (United States)

    Wang, Jong; Moeller, Anna; Ding, Yuanpang Samuel

    2012-04-01

    The effects of pressure conditions, both hyperbaric and hypobaric, on the flow rate of an elastomeric infusion pump were investigated. The altered pressure conditions were tested with the restrictor outlet at two different conditions: (1) at the same pressure condition as the Infusor elastomeric balloon and (2) with the outlet exposed to ambient conditions. Five different pressure conditions were tested. These included ambient pressure (98-101 kilopascals [kPa]) and test pressures controlled to be 10 or 20 kPa below or 75 or 150 kPa above the ambient pressure. A theoretical calculation based on the principles of fluid mechanics was also used to predict the pump's flow rate at various ambient conditions. The conditions in which the Infusor elastomeric pump and restrictor outlet were at the same pressure gave rise to average flow rates within the ±10% tolerance of the calculated target flow rate of 11 mL/hr. The flow rate of the Infusor pump decreased when the pressure conditions changed from hypobaric to ambient. The flow rate increased when the pressure conditions changed from hyperbaric to ambient. The flow rate of the Infusor elastomeric pump was not affected when the balloon reservoir and restrictor outlet were at the same pressure. The flow rate varied from 58.54% to 377.04% of the labeled flow rate when the pressure applied to the reservoir varied from 20 kPa below to 150 kPa above the pressure applied to the restrictor outlet, respectively. The maximum difference between observed flow rates and those calculated by applying fluid mechanics was 4.9%.

  18. Hybrid magnetorheological fluid–elastomeric lag dampers for helicopter stability augmentation

    International Nuclear Information System (INIS)

    Hu Wei; Wereley, Norman M

    2008-01-01

    A laboratory demonstration of a hybrid magnetorheological fluid–elastomeric (MRFE) damper is investigated for adjustable or programmable lag mode damping in helicopters, so that damping requirements can be varied as a function of different flight conditions. The laboratory demonstration of this hybrid MRFE lag damper consists of a double lap shear elastomeric damper in parallel with two magnetorheological (MR) flow mode dampers. This is compared to a damper where only elastomeric materials are implemented, i.e., a double lap shear specimen. The relationship between the output force and the quasi-steady harmonic displacement input to a flow mode MR damper is exploited, where the output force can be adjusted as a function of applied magnetic field. Equivalent viscous damping is used to compare the damping characteristics of the hybrid damper to a conventional elastomeric damper under steady-state sinusoidal displacement excitation. To demonstrate feasibility, a hybrid MRFE damper test setup is designed, and single frequency (lag frequency or rotor in-plane bending frequency) and dual frequency (lag frequency and rotor frequency) tests are conducted under different magnetic fields. The hybrid MRFE damper exhibits amplitude-dependent damping behavior. However, with application of a magnetic field, the damping level is controlled to a specific damping level objective as a function of displacement amplitude. Similarly, under dual frequency conditions, damping degradation at the lag frequency, because of lag motion at the rotor frequency, can also be recovered by increasing magnetic field. A time-domain analysis is developed to study the nonlinear dynamic behavior of the hybrid MRFE damper. Using rate-dependent elasto-slides, the amplitude-dependent behavior of the hybrid MRFE damper is accurately reconstructed using both constant and current-dependent (i.e. controllable) parameters. The analysis is physically motivated and can be applied to the elastomer and MR fluid

  19. Antibiotic stability related to temperature variations in elastomeric pumps used for outpatient parenteral antimicrobial therapy (OPAT).

    Science.gov (United States)

    Voumard, Rachel; Van Neyghem, Niklas; Cochet, Camille; Gardiol, Céline; Decosterd, Laurent; Buclin, Thierry; de Valliere, Serge

    2017-05-01

    Elastomeric pumps can be used for the continuous administration of antimicrobials in the outpatient setting. A potentially limiting factor in their use is the stability of antimicrobials. To investigate under real-life conditions the temperature variations of antibiotic solutions contained in elastomeric pumps, and to examine under such conditions the stability of five antibiotics. Healthy volunteers carried the elastomeric pumps in carry pouches during their daily activities. A thermologger measured the temperatures every 15 min over 24 h. Antibiotic concentrations were measured by HPLC coupled to tandem MS. During daytime, the temperature of solutions in the pumps increased steadily, warming to >30°C. During the night, when the pumps were kept attached to the waist, the temperatures reached up to 33°C. The use of white carry pouches avoided excessive temperature increases. Over seven experiments, cefazolin, cefepime, piperacillin and tazobactam were found to be stable over 24 h. Flucloxacillin showed a mean decrease in concentration of 11% ( P  = 0.001). Real-life situations can cause significant temperature rises in elastomeric pumps, thereby potentially increasing the risk of antibiotic degradation. Patients should be instructed to avoid situations causing excessive temperature increases. Despite these temperature variations, cefazolin, cefepime, piperacillin and tazobactam were found to be stable over 24 h. A moderate degradation was noticed for flucloxacillin, albeit most probably not to an extent that might impair anti-infective efficacy. © The Author 2017. Published by Oxford University Press on behalf of the British Society for Antimicrobial Chemotherapy. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  20. Friction produced by types of elastomeric ligatures in treatment mechanics with the preadjusted appliance.

    Science.gov (United States)

    Baccetti, Tiziano; Franchi, Lorenzo

    2006-03-01

    The objective was to compare the frictional forces generated by new nonconventional passive elastomeric ligatures (NCL) and conventional elastomeric ligatures (CL) under dry conditions. An experimental model reproducing the right buccal segment of the upper arch and consisting of five stainless steel 0.022-inch preadjusted brackets (from the second premolar through the central incisor) was used to assess both static and kinetic frictional forces produced by NCL and CL. The frictional forces generated by the 0.019 x 0.025-inch stainless steel wire with the two types of elastomeric ligatures were recorded by sliding the wire into the aligned brackets. The friction produced by the 0.014-inch superelastic nickel titanium wire was evaluated both in the presence of aligned brackets and of three-mm misaligned canine bracket. The amount of both static and kinetic frictions were minimal (<10 g) in the NCL group in the presence of aligned brackets with both types of wires, whereas it ranged from a minimum of 95.6 g for the 0.014-inch superelastic nickel titanium wire to a maximum of 590.7 g for the 0.019 x 0.025-inch stainless steel wire when using CL. The amount of both static and kinetic frictions in the presence of a misaligned canine bracket in the NCL group were less than half of that shown by the CL group. A recently developed passive ligature system is able to produce significantly lower levels of frictional forces in vitro when compared with conventional elastomeric modules.

  1. Wear Resistant Thermal Sprayed Composite Coatings Based on Iron Self-Fluxing Alloy and Recycled Cermet Powders

    Directory of Open Access Journals (Sweden)

    Heikki SARJAS

    2012-03-01

    Full Text Available Thermal spray and WC-Co based coatings are widely used in areas subjected to abrasive wear. Commercial  cermet thermal spray powders for HVOF are relatively expensive. Therefore applying these powders in cost-sensitive areas like mining and agriculture are hindered. Nowadays, the use of cheap iron based self-fluxing alloy powders for thermal spray is limited. The aim of this research was to study properties of composite powders based on self-fluxing alloys and recycled cermets and to examine the properties of thermally sprayed (HVOF coatings from composite powders based on iron self-fluxing alloy and recycled cermet powders (Cr3C2-Ni and WC-Co. To estimate the properties of  recycled cermet powders, the sieving analysis, laser granulometry and morphology were conducted. For deposition of coatings High Velocity Oxy-Fuel spray was used. The structure and composition of powders and coatings were estimated by SEM and XRD methods. Abrasive wear performance of coatings was determined and compared with wear resistance of coatings from commercial powders. The wear resistance of thermal sprayed coatings from self-fluxing alloy and recycled cermet powders at abrasion is comparable with wear resistance of coatings from commercial expensive spray powders and may be an alternative in tribological applications in cost-sensitive areas.DOI: http://dx.doi.org/10.5755/j01.ms.18.1.1338

  2. Changes in muscle size and MHC composition in response to resistance exercise with heavy and light loading intensity

    DEFF Research Database (Denmark)

    Holm, L.; Reitelseder, S.; Pedersen, T.G.

    2008-01-01

    resonance imaging, muscle biopsies were obtained bilaterally from vastus lateralis for determination of myosin heavy chain (MHC) composition, and maximal muscle strength was assessed by 1RM testing and in an isokinetic dynamometer at 60 degrees /s. Quadriceps muscle cross-sectional area increased (P ...Muscle mass accretion is accomplished by heavy-load resistance training. The effect of light-load resistance exercise has been far more sparsely investigated with regard to potential effect on muscle size and contractile strength. We applied a resistance exercise protocol in which the same...... individual trained one leg at 70% of one-repetition maximum (1RM) (heavy load, HL) while training the other leg at 15.5% 1RM (light load, LL). Eleven sedentary men (age 25 +/- 1 yr) trained for 12 wk at three times/week. Before and after the intervention muscle hypertrophy was determined by magnetic...

  3. Electrical resistivity of carbon black-filled high-density polyethylene (HDPE) composite containing radiation crosslinked HDPE particles

    International Nuclear Information System (INIS)

    Lee, M.-G.; Nho, Y.C.

    2001-01-01

    The room-temperature volume resistivity of high-density polyethylene (HDPE)-carbon black (CB) blends containing previously radiation crosslinked HDPE powder was studied. The results showed that the room-temperature volume resistivity decreases with increasing concentration of crosslinked HDPE powder. It is considered that the crosslinked HDPE particles act as a filler that increases the CB volume fraction in the HDPE matrix. The results of an optical microscope observation indicated that the crosslinked polymer particles are dispersed in the HDPE/CB composite. This effect of the crosslinked particles is attributed to the fact that the crosslinked mesh size of the HDPE particles is so small that the CB particles cannot go inside them. The effect of 60 Co γ-ray and electron beam (EB) irradiation on the positive temperature coefficient, negative temperature coefficient and electrical resistivity behavior of the blends were studied

  4. The electrical resistivity and percolation threshold of MWCNTs/polymer composites filled with a few aligned carbonyl iron particles

    Science.gov (United States)

    Dong, Shuai; Wang, Xiaojie

    2018-03-01

    Conductive polymer composites (CPCs) consist of multi-walled carbon nanotubes (MWCNTs), a few carbonyl iron particles (CIPs) and polydimethylsiloxane (PDMS) are fabricated under a moderate magnetic field. The alignment of CIPs will change the structure of MWCNT network, and consequently the electrical properties of CPCs. The volume fraction of CIPs is fixed at 0.08 vol% at which CIPs will not directly participate in electric conduction. The electrical resistivity of CPCs and the changes of resistance versus strain are evaluated at various MWCNT volume fractions. The testing results show that a percolation threshold as low as 0.19 vol% is obtained due to the effect of aligned CIPs, comparing with 0.39 vol% of isotropic MWCNT/CIP/PDMS (prepared without magnetic field). Meanwhile, the anisotropic structure reduces the electrical resistivity by more than 80% when the MWCNT volume fractions is over the percolation threshold.

  5. Nonequilibrium Alloying of Aluminum for Improving the Corrosion Resistance of Graphite-Reinforced Metal Matrix Composites

    National Research Council Canada - National Science Library

    Shaw, Barbara

    1994-01-01

    .... Unfortunately, MMCs, especially Gr reinforced composites, are extremely susceptible to corrosion with severe attack in chloride-containing environments occurring in as little time as several weeks for Gr/Al composites...

  6. In silico simulation and in vitro evaluation of an elastomeric scaffold using ultrasonic shear wave imaging

    Science.gov (United States)

    Yu, Jiao; Nie, Erwei; Zhu, Yanying; Hong, Yi

    2018-03-01

    Biodegradable elastomeric scaffolds for soft tissue repair represent a growing area of biomaterials research. Mechanical strength is one of the key factors to consider in the evaluation of candidate materials and the designs for tissue scaffolds. It is desirable to develop non-invasive evaluation methods of the mechanical property of scaffolds which would provide options for monitoring temporal mechanical property changes in situ. In this paper, we conduct in silico simulation and in vitro evaluation of an elastomeric scaffold using a novel ultrasonic shear wave imaging (USWI). The scaffold is fabricated from a biodegradable elastomer, poly(carbonate urethane) urea using salt leaching method. A numerical simulation is performed to test the robustness of the developed inversion algorithm for the elasticity map reconstruction which will be implemented in the phantom experiment. The generation and propagation of shear waves in a homogeneous tissue-mimicking medium with a circular scaffold inclusion is simulated and the elasticity map is well reconstructed. A PVA phantom experiment is performed to test the ability of USWI combined with the inversion algorithm to non-invasively characterize the mechanical property of a porous, biodegradable elastomeric scaffold. The elastic properties of the tested scaffold can be easily differentiated from the surrounding medium in the reconstructed image. The ability of the developed method to identify the edge of the scaffold and characterize the elasticity distribution is demonstrated. Preliminary results in this pilot study support the idea of applying the USWI based method for non-invasive elasticity characterization of tissue scaffolds.

  7. Puncture mechanics of soft elastomeric membrane with large deformation by rigid cylindrical indenter

    Science.gov (United States)

    Liu, Junjie; Chen, Zhe; Liang, Xueya; Huang, Xiaoqiang; Mao, Guoyong; Hong, Wei; Yu, Honghui; Qu, Shaoxing

    2018-03-01

    Soft elastomeric membrane structures are widely used and commonly found in engineering and biological applications. Puncture is one of the primary failure modes of soft elastomeric membrane at large deformation when indented by rigid objects. In order to investigate the puncture failure mechanism of soft elastomeric membrane with large deformation, we study the deformation and puncture failure of silicone rubber membrane that results from the continuous axisymmetric indentation by cylindrical steel indenters experimentally and analytically. In the experiment, effects of indenter size and the friction between the indenter and the membrane on the deformation and puncture failure of the membrane are investigated. In the analytical study, a model within the framework of nonlinear field theory is developed to describe the large local deformation around the punctured area, as well as to predict the puncture failure of the membrane. The deformed membrane is divided into three parts and the friction contact between the membrane and indenter is modeled by Coulomb friction law. The first invariant of the right Cauchy-Green deformation tensor I1 is adopted to predict the puncture failure of the membrane. The experimental and analytical results agree well. This work provides a guideline in designing reliable soft devices featured with membrane structures, which are present in a wide variety of applications.

  8. Preliminary SEM Observations on the Surface of Elastomeric Impression Materials after Immersion or Ozone Disinfection

    Science.gov (United States)

    Prombonas, Anthony; Yannikakis, Stavros; Karampotsos, Thanasis; Katsarou, Martha-Spyridoula; Drakoulis, Nikolaos

    2016-01-01

    Introduction Surface integrity of dental elastomeric impression materials that are subjected to disinfection is of major importance for the quality of the final prosthetic restorations. Aim The aim of this qualitative Scanning Electronic Microscopy (SEM) study was to reveal the effects of immersion or ozone disinfection on the surface of four dental elastomeric impression materials. Materials and Methods Four dental elastomeric impression material brands were used (two vinyl polysiloxane silicones, one polyether, and one vinyl polyether silicone). Total of 32 specimens were fabricated, eight from each impression material. Specimens were immersion (0.525% sodium hypochlorite solution or 0.3% benzalkonium chloride solution) or ozone disinfected or served as controls and examined with SEM. Results Surface degradation was observed on several speci-mens disinfected with 0.525% sodium hypochlorite solution. Similar wavy-wrinkling surface structures were observed in almost all specimens, when treated either with 0.3% benzalkonium chloride solution or ozone. Conclusion The SEM images obtained from this study revealed that both immersion disinfectants and ozone show similar impression material surface alterations. Ozone seems to be non-inferior as compared to immersion disinfectants, but superior as to environmental protection. PMID:28208993

  9. Initial Tensile and Residual Forces of Pigmented Elastomeric Ligatures from Various Brands

    Science.gov (United States)

    Wichai, Wassana; Anuwongnukroh, Niwat; Dechkunakorn, Surachai; Kaypetch, Rattiporn; Tua-ngam, Peerapong

    2017-11-01

    This study aimed to investigate the initial tensile and residual forces of pigmented elastomeric ligatures (clear, pink, and metallic) from three commercial brands - Brand 1 (USA), Brand 2 (USA), and Brand 3(China). Twelve elastomeric ligatures of each brand and color were evaluated for initial tensile and residual forces after stretching for 28 days at 37°C by a Universal Testing Machine. The results showed that the highest initial tensile force was 14.78 N, 20.71 N, and 15.1 N for the metallic color of Brand-1, pink color of Brand -2, and metallic color of Brand -3, respectively. There were significant (ptensile force of each brand, except clear and metallic color of Brand-1 & 3 and pink color of Brand-2 & 3. Similarly, among the pigmented ligatures from each brand, significant (ptensile force, except metallic color of Brand-1 & 3. Brand-3 had the highest residual force after 28 days, whereas the loss of force was 80-90% in Brand-1 & 2 and 20-30% in Brand-3. There were also significant (ptensile and residual forces among the three pigmented elastomeric ligatures of the three commercial brands.

  10. Forces released during alignment with a preadjusted appliance with different types of elastomeric ligatures.

    Science.gov (United States)

    Franchi, Lorenzo; Baccetti, Tiziano

    2006-05-01

    The purpose of this in-vitro study was to compare the forces generated by new nonconventional elastomeric ligatures (NCEL) and conventional elastomeric ligatures (CEL) during leveling and aligning phases. The testing model consisted of 5 stainless steel 0.022-in preadjusted brackets for second premolar, first premolar, canine, lateral incisor, and central incisor. The canine bracket was welded to a sliding bar that allowed for different vertical positions. The forces generated by 3 sizes of wires (0.012-, 0.014-, and 0.016-in superelastic nickel-titanium) with the 2 types of elastomeric ligatures at different amounts of upward canine misalignment (1.5, 3, 4.5, and 6 mm) were recorded. Significant differences between CEL and NCEL were found for all tested variables (P <.01) with the exception of the 0.014- and 0.016-in wires at canine misalignment of 1.5 mm. A noticeable amount of force was generated with the NCEL at all 4 canine positions with all 3 wire sizes (from about 50 to about 150 g). With 4.5 mm of canine misalignment or more, the average amount of released force with the CEL was approximately zero.

  11. Study of rheological, viscoelastic and vulcanization behavior of sponge EPDM/NR blended nano- composites

    International Nuclear Information System (INIS)

    Bashir, M Arshad; Shahid, M; Ahmed, Riaz; Yahya, A G

    2014-01-01

    In this research paper the effect of blending ratio of natural rubber (NR) with Ethylene Propylene Diene Monomer (EPDM) were investigated. Different samples of EPDM/NR ratio were prepared to study the variation of NR in EPDM on rheology, curing characteristics, tangent δ, and viscosity variation during vulcanization of sponge nano composites.The main aim of present research is to develop elastomeric based sponge composites with the blending ratio of base elastomers along with the carbon nano particles for high energy absorbing and damping applications. The curing characteristics, rheology and viscoelastic nature of the composite is remarkably influenced with the progressive blending ratio of the base elastomeric matrix

  12. Study of rheological, viscoelastic and vulcanization behavior of sponge EPDM/NR blended nano-composites

    International Nuclear Information System (INIS)

    Bashir, M. A.; Shahid, M.; Ahmed, R.; Yahya, A. G.

    2013-01-01

    In this research paper the effect of blending ratio of natural rubber (NR) with Ethylene Propylene Diene Monomer (EPDM) were investigated. Different samples of EPDM/NR ratio were prepared to study the variation of NR in EPDM on rheology, curing characteristics, tangent d, and viscosity variation during vulcanization of sponge nano composites. The main aim of present research is to develop elastomeric based sponge composites with the blending ratio of base elastomers along with the carbon nano particles for high energy absorbing and damping applications. The curing characteristics, rheology and viscoelastic nature of the composite is remarkably influenced with the progressive blending ratio of the base elastomeric matrix. (author)

  13. Direct patterning of highly-conductive graphene@copper composites using copper naphthenate as a resist for graphene device applications.

    Science.gov (United States)

    Bi, Kaixi; Xiang, Quan; Chen, Yiqin; Shi, Huimin; Li, Zhiqin; Lin, Jun; Zhang, Yongzhe; Wan, Qiang; Zhang, Guanhua; Qin, Shiqiao; Zhang, Xueao; Duan, Huigao

    2017-11-09

    We report an electron-beam lithography process to directly fabricate graphene@copper composite patterns without involving metal deposition, lift-off and etching processes using copper naphthenate as a high-resolution negative-tone resist. As a commonly used industrial painting product, copper naphthenate is extremely cheap with a long shelf time but demonstrates an unexpected patterning resolution better than 10 nm. With appropriate annealing under a hydrogen atmosphere, the produced graphene@copper composite patterns show high conductivity of ∼400 S cm -1 . X-ray diffraction, conformal Raman spectroscopy and X-ray photoelectron spectroscopy were used to analyze the chemical composition of the final patterns. With the properties of high resolution and high conductivity, the patterned graphene@copper composites could be used as conductive pads and interconnects for graphene electronic devices with ohmic contacts. Compared to common fabrication processes involving metal evaporation and lift-off steps, this pattern-transfer-free fabrication process using copper naphthenate resist is direct and simple but allows comparable device performance in practical device applications.

  14. Improving the corrosion wear resistance of AISI 316L stainless steel by particulate reinforced Ni matrix composite alloying layer

    Science.gov (United States)

    Xu, Jiang; Zhuo, Chengzhi; Tao, Jie; Jiang, Shuyun; Liu, Linlin

    2009-01-01

    In order to overcome the problem of corrosion wear of AISI 316L stainless steel (SS), two kinds of composite alloying layers were prepared by a duplex treatment, consisting of Ni/nano-SiC and Ni/nano-SiO2 predeposited by brush plating, respectively, and subsequent surface alloying with Ni-Cr-Mo-Cu by a double glow process. The microstructure of the two kinds of nanoparticle reinforced Ni-based composite alloying layers was investigated by means of SEM and TEM. The electrochemical corrosion behaviour of composite alloying layers compared with the Ni-based alloying layer and 316L SS under different conditions was characterized by potentiodynamic polarization test and electrochemical impedance spectroscopy. Results showed that under alloying temperature (1000 °C) conditions, amorphous nano-SiO2 particles still retained the amorphous structure, whereas nano-SiC particles were decomposed and Ni, Cr reacted with SiC to form Cr6.5Ni2.5Si and Cr23C6. In static acidic solution, the corrosion resistance of the composite alloying layer with the brush plating Ni/nano-SiO2 particles interlayer is lower than that of the Ni-based alloying layer. However, the corrosion resistance of the composite alloying layer with the brush plating Ni/nano-SiO2 particles interlayer is prominently superior to that of the Ni-based alloying layer under acidic flow medium condition and acidic slurry flow condition. The corrosion resistance of the composite alloying layer with the brush plating Ni/nano-SiC particles interlayer is evidently lower than that of the Ni-based alloying layer, but higher than that of 316L SS under all test conditions. The results show that the highly dispersive nano-SiO2 particles are helpful in improving the corrosion wear resistance of the Ni-based alloying layer, whereas carbides and silicide phase are deleterious to that of the Ni-based alloying layer due to the fact that the preferential removal of the matrix around the precipitated phase takes place by the chemical

  15. The effect of pioglitazone and resistance training on body composition in older men and women undergoing hypocaloric weight loss.

    Science.gov (United States)

    Shea, M Kyla; Nicklas, Barbara J; Marsh, Anthony P; Houston, Denise K; Miller, Gary D; Isom, Scott; Miller, Michael E; Carr, J Jeffrey; Lyles, Mary F; Harris, Tamara B; Kritchevsky, Stephen B

    2011-08-01

    Age-related increases in ectopic fat accumulation are associated with greater risk for metabolic and cardiovascular diseases, and physical disability. Reducing skeletal muscle fat and preserving lean tissue are associated with improved physical function in older adults. PPARγ-agonist treatment decreases abdominal visceral adipose tissue (VAT) and resistance training preserves lean tissue, but their effect on ectopic fat depots in nondiabetic overweight adults is unclear. We examined the influence of pioglitazone and resistance training on body composition in older (65-79 years) nondiabetic overweight/obese men (n = 48, BMI = 32.3 ± 3.8 kg/m(2)) and women (n = 40, BMI = 33.3 ± 4.9 kg/m(2)) during weight loss. All participants underwent a 16-week hypocaloric weight-loss program and were randomized to receive pioglitazone (30 mg/day) or no pioglitazone with or without resistance training, following a 2 × 2 factorial design. Regional body composition was measured at baseline and follow-up using computed tomography (CT). Lean mass was measured using dual X-ray absorptiometry. Men lost 6.6% and women lost 6.5% of initial body mass. The percent of fat loss varied across individual compartments. Men who were given pioglitazone lost more visceral abdominal fat than men who were not given pioglitazone (-1,160 vs. -647 cm(3), P = 0.007). Women who were given pioglitazone lost less thigh subcutaneous fat (-104 vs. -298 cm(3), P = 0.002). Pioglitazone did not affect any other outcomes. Resistance training diminished thigh muscle loss in men and women (resistance training vs. no resistance training men: -43 vs. -88 cm(3), P = 0.005; women: -34 vs. -59 cm(3), P = 0.04). In overweight/obese older men undergoing weight loss, pioglitazone increased visceral fat loss and resistance training reduced skeletal muscle loss. Additional studies are needed to clarify the observed gender differences and evaluate how these changes in body composition influence functional status.

  16. Surface composition, microstructure and corrosion resistance of AZ31 magnesium alloy irradiated by high-intensity pulsed ion beam

    International Nuclear Information System (INIS)

    Li, P.; Lei, M.K.; Zhu, X.P.

    2011-01-01

    High-intensity pulsed ion beam (HIPIB) irradiation of AZ31 magnesium alloy is performed and electrochemical corrosion experiment of irradiated samples is carried out by using potentiodynamic polarization technology in order to explore the effect of HIPIB irradiation on corrosion resistance of magnesium alloy. The surface composition, cross-sectional morphology and microstructure are characterized by using electron probe microanalyzer, optical microscope and transmission electron microscope, respectively. The results indicated that HIPIB irradiation leads to a significant improvement in corrosion resistance of magnesium alloy, in terms of the considerable increase in both corrosion potential and pitting breakdown potential. The microstructural refinement and surface purification induced by HIPIB irradiation are responsible for the improved corrosion resistance. - Research Highlights: → A modified layer about 30 μm thick is obtained by HIPIB irradiation. → Selective ablation of element/impurity phase having lower melting point is observed. → More importantly, microstructural refinement occurred on the irradiated surface. → The modified layer exhibited a significantly improved corrosion resistance. → Improved corrosion resistance is ascribed to the combined effect induced by HIPIB.

  17. Preparation and corrosion resistance of magnesium phytic acid/hydroxyapatite composite coatings on biodegradable AZ31 magnesium alloy.

    Science.gov (United States)

    Zhang, Min; Cai, Shu; Zhang, Feiyang; Xu, Guohua; Wang, Fengwu; Yu, Nian; Wu, Xiaodong

    2017-06-01

    In this work, a magnesium phytic acid/hydroxyapatite composite coating was successfully prepared on AZ31 magnesium alloy substrate by chemical conversion deposition technology with the aim of improving its corrosion resistance and bioactivity. The influence of hydroxyapatite (HA) content on the microstructure and corrosion resistance of the coatings was investigated. The results showed that with the increase of HA content in phytic acid solution, the cracks on the surface of the coatings gradually reduced, which subsequently improved the corrosion resistance of these coated magnesium alloy. Electrochemical measurements in simulated body fluid (SBF) revealed that the composite coating with 45 wt.% HA addition exhibited superior surface integrity and significantly improved corrosion resistance compared with the single phytic acid conversion coating. The results of the immersion test in SBF showed that the composite coating could provide more effective protection for magnesium alloy substrate than that of the single phytic acid coating and showed good bioactivity. Magnesium phytic acid/hydroxyapatite composite, with the desired bioactivity, can be synthesized through chemical conversion deposition technology as protective coatings for surface modification of the biodegradable magnesium alloy implants. The design idea of the new type of biomaterial is belong to the concept of "third generation biomaterial". Corrosion behavior and bioactivity of coated magnesium alloy are the key issues during implantation. In this study, preparation and corrosion behavior of magnesium phytic acid/hydroxyapatite composite coatings on magnesium alloy were studied. The basic findings and significance of this paper are as follows: 1. A novel environmentally friendly, homogenous and crack-free magnesium phytic acid/hydroxyapatite composite coating was fabricated on AZ31 magnesium alloy via chemical conversion deposition technology with the aim of enhancing its corrosion resistance and

  18. Fracture resistance of metal-free composite crowns-effects of fiber reinforcement, thermal cycling, and cementation technique.

    Science.gov (United States)

    Lehmann, Franziska; Eickemeyer, Grit; Rammelsberg, Peter

    2004-09-01

    The improved mechanical properties of contemporary composites have resulted in their extensive use for the restoration of posterior teeth. However, the influence of fiber reinforcement, cementation technique, and physical stress on the fracture resistance of metal-free crowns is unknown. This in vitro study evaluated the effect of fiber reinforcement, physical stress, and cementation methods on the fracture resistance of posterior metal-free Sinfony crowns. Ninety-six extracted human third molars received a standardized tooth preparation: 0.5-mm chamfer preparation and occlusal reduction of 1.3 to 1.5 mm. Sinfony (nonreinforced crowns, n=48) and Sinfony-Vectris (reinforced crowns, n=48) crowns restoring original tooth contour were prepared. Twenty-four specimens of each crown type were cemented, using either glass ionomer cement (GIC) or resin cement. Thirty-two crowns (one third) were stored in humidity for 48 hours. Another third was exposed to 10,000 thermal cycles (TC) between 5 degrees C and 55 degrees C. The remaining third was treated with thermal cycling and mechanical loading (TCML), consisting of 1.2 million axial loads of 50 N. The artificial crowns were then vertically loaded with a steel sphere until failure occurred. Significant differences in fracture resistance (N) between experimental groups were assessed by nonparametric Mann-Whitney U-test (alpha=.05). Fifty percent of the Sinfony and Sinfony-Vectris crowns cemented with glass ionomer cement loosened after thermal cycling. Thermal cycling resulted in a significant reduction in the mean fracture resistance for Sinfony crowns cemented with GIC, from 2037 N to 1282 N (P=.004). Additional fatigue produced no further effects. Fiber reinforcement significantly increased fracture resistance, from 1555 N to 2326 N (P=.001). The minimal fracture resistance was above 600 N for all combinations of material, cement and loading. Fracture resistance of metal-free Sinfony crowns was significantly increased by

  19. Effect of different composite core materials on fracture resistance of endodontically treated teeth restored with FRC posts

    Directory of Open Access Journals (Sweden)

    Prapaporn PANITIWAT

    Full Text Available Abstract Objective This study evaluated the fracture resistance of endodontically treated teeth restored with fiber reinforced composite posts, using three resin composite core build-up materials, (Clearfil Photo Core (CPC, MultiCore Flow (MCF, and LuxaCore Z-Dual (LCZ, and a nanohybrid composite, (Tetric N-Ceram (TNC. Material and Methods Forty endodontically treated lower first premolars were restored with quartz fiber posts (D.T. Light-Post cemented with resin cement (Panavia F2.0. Samples were randomly divided into four groups (n=10. Each group was built-up with one of the four core materials following its manufacturers’ instructions. The teeth were embedded in acrylic resin blocks. Nickel-Chromium crowns were fixed on the specimens with resin cement. The fracture resistance was determined using a universal testing machine with a crosshead speed of 1 mm/min at 1350 to the tooth axis until failure occurred. All core materials used in the study were subjected to test for the flexural modulus according to ISO 4049:2009. Results One-way ANOVA and Bonferroni multiple comparisons test indicated that the fracture resistance was higher in the groups with CPC and MCF, which presented no statistically significant difference (p>0.05, but was significantly higher than in those with LCZ and TNC (p<0.05. In terms of the flexural modulus, the ranking from the highest values of the materials was aligned with the same tendency of fracture loads. Conclusion Among the cores used in this study, the composite core with high filler content tended to enhance fracture thresholds of teeth restored with fiber posts more than others.

  20. Composites

    International Nuclear Information System (INIS)

    Kasen, M.B.

    1983-01-01

    This chapter discusses the roles of composite laminates and aggregates in cryogenic technology. Filamentary-reinforced composites are emphasized because they are the most widely used composite materials. Topics considered include composite systems and terminology, design and fabrication, composite failure, high-pressure reinforced plastic laminates, low-pressure reinforced plastics, reinforced metals, selectively reinforced structures, the effect of cryogenic temperatures, woven-fabric and random-mat composites, uniaxial fiber-reinforced composites, composite joints in cryogenic structures, joining techniques at room temperature, radiation effects, testing laminates at cryogenic temperatures, static and cyclic tensile testing, static and cyclic compression testing, interlaminar shear testing, secondary property tests, and concrete aggregates. It is suggested that cryogenic composite technology would benefit from the development of a fracture mechanics model for predicting the fitness-for-purpose of polymer-matrix composite structures

  1. SCIENTIFIC-METHODICAL PREREQUISITES FOR DEVELOPMENT OF THE STEEL COMPOSITIONS FOR INCREASE OF RESISTANCE OF HIGH-LOADED STAMPS OF COLD DEFORMATION

    Directory of Open Access Journals (Sweden)

    V. N. Fedulov

    2005-01-01

    Full Text Available The basis of perfecting of the known steels composition with the purpose of using for solving of concrete production problem, in particular increase of instrument resistance, are examined in the article.

  2. Wear Resistance Analysis of A359/SiC/20p Advanced Composite Joints Welded by Friction Stir Welding

    Directory of Open Access Journals (Sweden)

    O. Cuevas Mata

    Full Text Available Abstract Advancement in automotive part development demands new cost-effective materials with higher mechanical properties and improved wear resistance as compared to existing materials. For instance, Aluminum Matrix Composites (AMC shows improved mechanical properties as wear and abrasion resistance, high strength, chemical and dimensional stability. Automotive industry has focused in AMC for a variety of applications in automotive parts in order to improve the fuel economy, minimize vehicle emissions, improve design options, and increase the performance. Wear resistance is one of the most important factors in useful life of the automotive components, overall in those components submitted to mechanical systems like automotive brakes and suspensions. Friction Stir Welding (FSW rises as the most capable process to joining AMC, principally for the capacity to weld without compromising their ceramic reinforcement. The aim of this study is focused on the analysis of wear characteristics of the friction-stir welded joint of aluminum matrix reinforced with 20 percent in weight silicon carbide composite (A359/SiC/20p. The experimental procedure consisted in cut samples into small plates and perform three welds on these with a FSW machine using a tool with 20 mm shoulder diameter and 8 mm pin diameter. The wear features of the three welded joints and parent metal were analyzed at constant load applying 5 N and a rotational speed of 100 rpm employing a Pin-on - Disk wear testing apparatus, using a sapphire steel ball with 6 mm diameter. The experimental results indicate that the three welded joints had low friction coefficient compared with the parent metal. The results determine that the FSW process parameters affect the wear resistance of the welded joints owing to different microstructural modifications during welding that causes a low wear resistance on the welded zone.

  3. Oxidation-resistant interface coatings for SiC/SiC composites

    Energy Technology Data Exchange (ETDEWEB)

    Stinton, D.P.; Kupp, E.R.; Hurley, J.W.; Lowden, R.A. [Oak Ridge National Lab., TN (United States)] [and others

    1996-08-01

    The characteristics of the fiber-matrix interfaces in ceramic matrix composites control the mechanical behavior of these composites. Finite element modeling (FEM) was performed to examine the effect of interface coating modulus and coefficient of thermal expansion on composite behavior. Oxide interface coatings (mullite and alumina-titania) produced by a sol-gel method were chosen for study as a result of the FEM results. Amorphous silicon carbide deposited by chemical vapor deposition (CVD) is also being investigated for interface coatings in SiC-matrix composites. Processing routes for depositing coatings of these materials were developed. Composites with these interfaces were produced and tested in flexure both as-processed and after oxidation to examine the suitability of these materials as interface coatings for SiC/SiC composites in fossil energy applications.

  4. Surfactant-free electrodeposition of reduced graphene oxide/copper composite coatings with enhanced wear resistance

    Science.gov (United States)

    Mai, Y. J.; Zhou, M. P.; Ling, H. J.; Chen, F. X.; Lian, W. Q.; Jie, X. H.

    2018-03-01

    How to uniformly disperse graphene sheets into the electrolyte is one of the main challenges to synthesize graphene enhanced nanocomposites by electrodeposition. A surfactant-free colloidal solution comprised of copper (II)-ethylene diamine tetra acetic acid ([CuIIEDTA]2-) complexes and graphene oxide (GO) sheets is proposed to electrodeposit reduced graphene oxide/copper (RGO/Cu) composite coatings. Anionic [CuIIEDTA]2- complexes stably coexist with negatively charged GO sheets due to the electrostatic repulsion between them, facilitating the electrochemical reduction and uniform dispersion of GO sheets into the copper matrix. The RGO/Cu composite coatings are well characterized by XRD, Raman, SEM and XPS. Their tribological behavior as a function of RGO content in composite coatings and normal loads are investigated. Also the chemical composition and topography of the wear tracks for the composite coatings are analyzed to deduce the lubricating and anti-wear mechanism of RGO/Cu composite coatings.

  5. Compact, Isolating Elastomeric Suspension for Vehicle Acoustic Vector Sensor

    Science.gov (United States)

    2007-09-30

    well as underwater acoustics. His Master’s thesis, funded by NUSC, was a study of near-body acoustic signal behavior entitled “Some Characteristics of ...in non-polymer based composites, including cermets . He has formulated a very wide range of materials for an equally wide range of applications, and...with a moving vehicle of an instrument responsive to particle accelerations in the surrounding medium. The overall goal of this project is to develop

  6. The effect of morphology and surface composition on radiation resistance of heterogeneous material CdS-PbS

    Energy Technology Data Exchange (ETDEWEB)

    Malyar, I. V., E-mail: imalyar@yandex.ru; Stetsyura, S. V., E-mail: stetsyurasv@info.sgu.ru [Chernyshevsky Saratov State University (Russian Federation)

    2011-07-15

    As a result of a complex study of the heterophase photosensitive material CdS-PbS by the methods of scanning electron microscopy and Auger spectrometry, it has been found that the radiation resistance of this material depends on the morphology and phase composition at its surface. It is shown that, as the temperature of annealing is increased, aggregations with predominant content of PbS grow; simultaneously, the composition of these aggregations varies as a consequence of the reaction of substitution of sulfur atoms with oxygen atoms. The latter of the aforementioned processes brings about a decrease in the radiation resistance of the heterophase photosensitive material CdS-PbS, which is accounted for by a decrease in the gettering due to appearance of an intermediate oxidized layer between PbS and CdS. An increase in the sizes and number of spherical aggregations at the surface, which consist of crystallites with predominant content of PbS, brings about an increase in the radiation resistance.

  7. An Evaluation of the Effect of Various Gloves on Polymerization Inhibition of Elastomeric Impression Materials: An In vitro Study.

    Science.gov (United States)

    Hiremath, Vinuta; Vinayakumar, G; Ragher, Mallikarjuna; Rayannavar, Sounyala; Bembalagi, Mahantesh; Ashwini, B L

    2017-11-01

    Latex protective barriers such as gloves and rubber dam material have been used widely in restorative procedures for crown and bridge. However, the chemical used during latex glove fabrication is thought to inhibit the polymerization of elastomeric impression materials used for impression making which has a detrimental effect on the dimensional accuracy and surface definition of resultant casts used for restorative procedures. The objectives of the study were to examine the surface of different elastomeric impressions on contact with various gloves. This clinical study included a total of eighty specimens of two types of the putty elastomeric impression material were hand manipulated by wearing three different gloves materials and is placed on a marked area of a clean and alcohol-treated glass slab at room temperature. The specimens examined for any signs of polymerization inhibition. The specimen will be rated as being "inhibited" if any residue remains on the glass slab and absence of the above will result as "no inhibition." The results showed no interference with the polymerization inhibition of the selected elastomers followed by the nitrile glove. The latex gloves showed inhibited set of the elastomeric impression material but set after sometime confirming time-dependent inhibition of the impression material. This study shows that the use of latex and sometime nitrile gloves during crown and bridge procedures should be contraindicated and the use of vinyl gloves should be stressed when working with elastomeric impression materials.

  8. An evaluation of the effect of various gloves on polymerization inhibition of elastomeric impression materials: An In vitro study

    Directory of Open Access Journals (Sweden)

    Vinuta Hiremath

    2017-01-01

    Full Text Available Background: Latex protective barriers such as gloves and rubber dam material have been used widely in restorative procedures for crown and bridge. However, the chemical used during latex glove fabrication is thought to inhibit the polymerization of elastomeric impression materials used for impression making which has a detrimental effect on the dimensional accuracy and surface definition of resultant casts used for restorative procedures. The objectives of the study were to examine the surface of different elastomeric impressions on contact with various gloves. Materials and Methods: This clinical study included a total of eighty specimens of two types of the putty elastomeric impression material were hand manipulated by wearing three different gloves materials and is placed on a marked area of a clean and alcohol-treated glass slab at room temperature. The specimens examined for any signs of polymerization inhibition. The specimen will be rated as being “inhibited” if any residue remains on the glass slab and absence of the above will result as “no inhibition.” Results: The results showed no interference with the polymerization inhibition of the selected elastomers followed by the nitrile glove. The latex gloves showed inhibited set of the elastomeric impression material but set after sometime confirming time-dependent inhibition of the impression material. Conclusion: This study shows that the use of latex and sometime nitrile gloves during crown and bridge procedures should be contraindicated and the use of vinyl gloves should be stressed when working with elastomeric impression materials.

  9. Effect of Si3N4 Addition on Oxidation Resistance of ZrB2-SiC Composites

    Directory of Open Access Journals (Sweden)

    Manab Mallik

    2017-06-01

    Full Text Available The oxidation behavior of ZrB2-20 vol % SiC and ZrB2-20 vol % SiC-5 vol % Si3N4 composites prepared by hot-pressing and subjected to isothermal exposure at 1200 or 1300 °C for durations of 24 or 100 h in air, as well as cyclic exposure at 1300 °C for 24 h, have been investigated. The oxidation resistance of the ZrB2-20 vol % SiC composite has been found to improve by around 20%–25% with addition of 5 vol % Si3N4 during isothermal or cyclic exposures at 1200 or 1300 °C. This improvement in oxidation resistance has been attributed to the formation of higher amounts of SiO2 and Si2N2O, as well as a greater amount of continuity in the oxide scale, because these phases assist in closing the pores and lower the severity of cracking by exhibiting self-healing type behavior. For both the composites, the mass changes are found to be higher during cyclic exposure at 1300 °C by about 2 times compared to that under isothermal conditions.

  10. Effects of resistance training and dietary changes on physical function and body composition in overweight and obese older adults.

    Science.gov (United States)

    Straight, Chad R; Dorfman, Leah R; Cottell, Kathryn E; Krol, Julie M; Lofgren, Ingrid E; Delmonico, Matthew J

    2012-08-01

    Community-based interventions that incorporate resistance training (RT) and dietary changes have not been extensively studied in overweight and obese older adults. The purpose of this investigation was to determine the effects of a community-based RT and dietary intervention on physical function and body composition in overweight and obese older adults. Ninety-five overweight and obese (BMI=33.4±4.0 kg/m2) older adults aged 55-80 years completed an 8-week RT and dietary intervention at 4 Rhode Island senior centers. Participants performed RT twice-weekly using resistance tubing, dumbbells, and ankle weights. Participants also attended 1 weekly dietary counseling session on a modified Dietary Approaches to Stop Hypertension diet. Outcome measurements included anthropometrics, body composition, and physical function. There were small changes in body mass (-1.0±1.8 kg, Pfoot up-and-go test time (-0.56±0.89 s, P<.001). Community-based RT and dietary modifications can improve body composition, muscle strength, and physical function in overweight and obese older adults. Future investigations should determine if this intervention is effective for long-term changes.

  11. Prevalence of antibiotic resistance genes and bacterial community composition in a river influenced by a wastewater treatment plant.

    Directory of Open Access Journals (Sweden)

    Elisabet Marti

    Full Text Available Antibiotic resistance represents a global health problem, requiring better understanding of the ecology of antibiotic resistance genes (ARGs, their selection and their spread in the environment. Antibiotics are constantly released to the environment through wastewater treatment plant (WWTP effluents. We investigated, therefore, the effect of these discharges on the prevalence of ARGs and bacterial community composition in biofilm and sediment samples of a receiving river. We used culture-independent approaches such as quantitative PCR to determine the prevalence of eleven ARGs and 16S rRNA gene-based pyrosequencing to examine the composition of bacterial communities. Concentration of antibiotics in WWTP influent and effluent were also determined. ARGs such as qnrS, bla TEM, bla CTX-M, bla SHV, erm(B, sul(I, sul(II, tet(O and tet(W were detected in all biofilm and sediment samples analyzed. Moreover, we observed a significant increase in the relative abundance of ARGs in biofilm samples collected downstream of the WWTP discharge. We also found significant differences with respect to community structure and composition between upstream and downstream samples. Therefore, our results indicate that WWTP discharges may contribute to the spread of ARGs into the environment and may also impact on the bacterial communities of the receiving river.

  12. Effect of impact energy on damage resistance and mechanical property of C/SiC composites under low velocity impact

    Energy Technology Data Exchange (ETDEWEB)

    Mei, Hui, E-mail: phdhuimei@yahoo.com; Yu, Changkui; Xu, Yawei; Han, Daoyang; Cheng, Laifei

    2017-02-27

    The present study investigated the damage resistance of two dimensional carbon fiber reinforced silicon carbide (C/SiCs) composites subjected to low velocity impact (LVI). Damage microstructures of specimens under different impact energies (E{sub i}) were characterized by infrared thermography, X-ray computed tomography and scanning electron microscopy. The real damage radii of specimens were found to change slightly with E{sub i}, whereas apparent damage radii where much larger. Overall, the fabricated 2D C/SiC composites exhibited good damage resistance to LVI with nominal post-impact tensile strengths remaining at 89.4%, 83.35%, 76.97%, and 74.84% of their pre-impacted counterpart of 158 MPa, for impact energies of 3, 4, 5, and 6 J, respectively. Compared with the as-received one, after LVI real tensile strengths of the C/SiC composite specimens increased by 5.84% for the E{sub i} of 3 J, 9.27% for 4 J, −1.83% for 5 J, −3.16% for 6 J.

  13. [Cellular composition of lymphoid nodules in the trachea wall in rats with different resistance to emotional stress in a model of hemorrhagic stroke].

    Science.gov (United States)

    Klyueva, L A

    2017-01-01

    To reveal regularities of changes in cellular composition of lymphoid nodules in the tracheal wall in male Wistar rats resistant and not resistant to emotional stress in a model of hemorrhagic stroke. Lymphoid formations of the tracheal wall (an area near the bifurcation of the organ) were investigated in 98 male Wistar rats using histological methods. Significant changes in the cellular composition of lymphoid nodules were found. The pattern of changes depends on the stress resistance of rats and the period of the experiment. The active cell destruction in lymphoid nodules was noted both in stress resistant and stress susceptible animals. The changes in the structure of lymphoid nodules found in the experimental hemorrhagic stroke suggest a decrease in the local immune resistance, which is most pronounced in rats not resistant to stress, that may contribute to the development of severe inflammatory complications of stroke such as pneumonia.

  14. Piezoelectric and mechanical properties of fatigue resistant, self-healing PZT-ionomer composites

    NARCIS (Netherlands)

    James, N.K.; Lafont, U.; Zwaag, S. van der; Groen, W.A.

    2014-01-01

    Piezoelectric ceramic-polymer composites with 0-3 connectivity were fabricated using lead zirconium titanate (PZT) powder dispersed in an ionomer (Zn ionomer) and its reference ethylene methacrylic acid copolymer (EMAA) polymer matrix. The PZT-Zn ionomer and PZT-EMAA composites were prepared by melt

  15. Development and optimization of manufacture process for heat resistant fibre reinforced ceramic matrix composites

    Czech Academy of Sciences Publication Activity Database

    Glogar, Petr; Hron, P.; Burian, M.; Balík, Karel; Černý, Martin; Sucharda, Zbyněk; Vymazalová, Z.; Červencl, J.; Pivoňka, M.

    -, č. 14 (2005), 25-32 ISSN 1214-9691 R&D Projects: GA ČR(CZ) GA106/02/0177 Institutional research plan: CEZ:AV0Z30460519 Keywords : polysiloxane resin * pyrolysis * ceramic matrix composite Subject RIV: JI - Composite Materials

  16. Characterization of Antibiotic Resistance Gene Abundance and Microbiota Composition in Feces of Organic and Conventional Pigs from Four EU Countries.

    Science.gov (United States)

    Gerzova, Lenka; Babak, Vladimir; Sedlar, Karel; Faldynova, Marcela; Videnska, Petra; Cejkova, Darina; Jensen, Annette Nygaard; Denis, Martine; Kerouanton, Annaelle; Ricci, Antonia; Cibin, Veronica; Österberg, Julia; Rychlik, Ivan

    2015-01-01

    One of the recent trends in animal production is the revival of interest in organic farming. The increased consumer interest in organic animal farming is mainly due to concerns about animal welfare and the use of antibiotics in conventional farming. On the other hand, providing animals with a more natural lifestyle implies their increased exposure to environmental sources of different microorganisms including pathogens. To address these concerns, we determined the abundance of antibiotic resistance and diversity within fecal microbiota in pigs kept under conventional and organic farming systems in Sweden, Denmark, France and Italy. The abundance of sul1, sul2, strA, tet(A), tet(B) and cat antibiotic resistance genes was determined in 468 samples by real-time PCR and the fecal microbiota diversity was characterized in 48 selected samples by pyrosequencing of V3/V4 regions of 16S rRNA. Contrary to our expectations, there were no extensive differences between the abundance of tested antibiotic resistance genes in microbiota originating from organic or conventionally housed pigs within individual countries. There were also no differences in the microbiota composition of organic and conventional pigs. The only significant difference was the difference in the abundance of antibiotic resistance genes in the samples from different countries. Fecal microbiota in the samples originating from southern European countries (Italy, France) exhibited significantly higher antibiotic resistance gene abundance than those from northern parts of Europe (Denmark, Sweden). Therefore, the geographical location of the herd influenced the antibiotic resistance in the fecal microbiota more than farm's status as organic or conventional.

  17. Modelling the influence of steel fibres on the electrical resistivity of cementitious composites

    DEFF Research Database (Denmark)

    Solgaard, Anders Ole Stubbe; Michel, Alexander; Stang, Henrik

    2009-01-01

    One of the governing factors on the corrosion of embedded reinforcement is the electrical resistivity of the concrete. The combination of steel fibres and conventional reinforcement bars has been used in a number of structures. However, the addition of electrical con-ductive fibres might influence...... of steel fibre reinforced concrete (SFRC). The parameters investigated in the following are the fibre geometry, the fibre volume and the transitional resistance. On basis of the experimental results, a model, taking the resistivity of the fibres and the concrete matrix into account is proposed....... the overall resistivity of the material and thereby the corrosion rate of the embedded reinforcement. To the knowledge of the authors, only preliminary studies have been made on the influence of corrosion of the reinforcement bars from the addition of the electrical conductive steel fibres. Thus the present...

  18. Evaluation of contact resistance between carbon fiber/epoxy composite laminate and printed silver electrode for damage monitoring

    International Nuclear Information System (INIS)

    Jeon, Eun Beom; Kim, Hak Sung; Takahashi, Kosuke

    2014-01-01

    An addressable conducting network (ACN) makes it possible to monitor the condition of a structure using the electrical resistance between electrodes on the surface of a carbon fiber reinforced plastics (CFRP) structure. To improve the damage detection reliability of the ACN, the contact resistances between the electrodes and CFRP laminates needs to be minimized. In this study, silver nanoparticle electrodes were fabricated via printed electronics techniques on a CFRP composite. The contact resistance between the silver electrodes and CFRP were measured with respect to various fabrication conditions such as the sintering temperature of the silver nano-ink and the surface roughness of the CFRP laminates. The interfaces between the silver electrode and carbon fibers were observed using a scanning electron microscope (SEM). Based on this study, it was found that the lowest contact resistance of 0.3664Ω could be achieved when the sintering temperature of the silver nano-ink and surface roughness were 120 degree C and 0.230 a, respectively.

  19. Fabrication and characterization of a micromachined swirl-shaped ionic polymer metal composite actuator with electrodes exhibiting asymmetric resistance.

    Science.gov (United States)

    Feng, Guo-Hua; Liu, Kim-Min

    2014-05-12

    This paper presents a swirl-shaped microfeatured ionic polymer-metal composite (IPMC) actuator. A novel micromachining process was developed to fabricate an array of IPMC actuators on a glass substrate and to ensure that no shortcircuits occur between the electrodes of the actuator. We demonstrated a microfluidic scheme in which surface tension was used to construct swirl-shaped planar IPMC devices of microfeature size and investigated the flow velocity of Nafion solutions, which formed the backbone polymer of the actuator, within the microchannel. The unique fabrication process yielded top and bottom electrodes that exhibited asymmetric surface resistance. A tool for measuring surface resistance was developed and used to characterize the resistances of the electrodes for the fabricated IPMC device. The actuator, which featured asymmetric electrode resistance, caused a nonzero-bias current when the device was driven using a zero-bias square wave, and we propose a circuit model to describe this phenomenon. Moreover, we discovered and characterized a bending and rotating motion when the IPMC actuator was driven using a square wave. We observed a strain rate of 14.6% and a displacement of 700 μm in the direction perpendicular to the electrode surfaces during 4.5-V actuation.

  20. The Composition and Spatial Patterns of Bacterial Virulence Factors and Antibiotic Resistance Genes in 19 Wastewater Treatment Plants.

    Directory of Open Access Journals (Sweden)

    Bing Zhang

    Full Text Available Bacterial pathogenicity and antibiotic resistance are of concern for environmental safety and public health. Accumulating evidence suggests that wastewater treatment plants (WWTPs are as an important sink and source of pathogens and antibiotic resistance genes (ARGs. Virulence genes (encoding virulence factors are good indicators for bacterial pathogenic potentials. To achieve a comprehensive understanding of bacterial pathogenic potentials and antibiotic resistance in WWTPs, bacterial virulence genes and ARGs in 19 WWTPs covering a majority of latitudinal zones of China were surveyed by using GeoChip 4.2. A total of 1610 genes covering 13 virulence factors and 1903 genes belonging to 11 ARG families were detected respectively. The bacterial virulence genes exhibited significant spatial distribution patterns of a latitudinal biodiversity gradient and a distance-decay relationship across China. Moreover, virulence genes tended to coexist with ARGs as shown by their strongly positive associations. In addition, key environmental factors shaping the overall virulence gene structure were identified. This study profiles the occurrence, composition and distribution of virulence genes and ARGs in current WWTPs in China, and uncovers spatial patterns and important environmental variables shaping their structure, which may provide the basis for further studies of bacterial virulence factors and antibiotic resistance in WWTPs.

  1. Thermal Shock Resistance of Stabilized Zirconia/Metal Coat on Polymer Matrix Composites by Thermal Spraying Process

    Science.gov (United States)

    Zhu, Ling; Huang, Wenzhi; Cheng, Haifeng; Cao, Xueqiang

    2014-12-01

    Stabilized zirconia/metal coating systems were deposited on the polymer matrix composites by a combined thermal spray process. Effects of the thicknesses of metal layers and ceramic layer on thermal shock resistance of the coating systems were investigated. According to the results of thermal shock lifetime, the coating system consisting of 20 μm Zn and 125 μm 8YSZ exhibited the best thermal shock resistance. Based on microstructure evolution, failure modes and failure mechanism of the coating systems were proposed. The main failure modes were the formation of vertical cracks and delamination in the outlayer of substrate, and the appearance of coating spallation. The residual stress, thermal stress and oxidation of substrate near the substrate/metal layer interface were responsible for coating failure, while the oxidation of substrate near the substrate/coating interface was the dominant one.

  2. Effect of fed- versus fasted state resistance training during Ramadan on body composition and selected metabolic parameters in bodybuilders.

    Science.gov (United States)

    Trabelsi, Khaled; Stannard, Stephen R; Ghlissi, Zohra; Maughan, Ronald J; Kallel, Choumous; Jamoussi, Kamel; Zeghal, Khaled M; Hakim, Ahmed

    2013-04-25

    Muslim bodybuilders often continue training during Ramadan. However, the effect of resistance training in a fasted versus a fed state during Ramadan on body composition and metabolic parameters in bodybuilders is not well known. The aim of this study was to evaluate the effects of resistance training in a fasted versus a fed state during Ramadan on body composition and metabolic parameters in bodybuilders. Sixteen men were allocated to two groups: Eight practicing resistance training in the late afternoon in a fasted state (FAST), and eight training in the late evening in an acutely fed state (FED) during Ramadan. All visited the laboratory in the morning two days before the start of Ramadan (Bef-R) and on the 29th day of Ramadan (End-R) for anthropometric measurement, completion of a dietary questionnaire, and provision of fasting blood and urine samples. Body mass and body fat percentage remained unchanged in FAST and FED during the whole period of the investigation. Both FAST and FED experienced an increase in the following parameters from Bef-R to End-R: urine specific gravity (1%; p = 0.028, p = 0.004 respectively), serum concentrations of urea (4%, p = 0.006; 7%, p = 0.004 respectively), creatinine (5%, p = 0.015; 6%, p = 0.04 respectively), uric acid (17%; p Ramadan does not affect body mass and body composition of bodybuilders. Additionally, Ramadan fasting induced changes in urinary and some biochemical parameters, but these changes were not different according to when the training occurred.

  3. Composition

    DEFF Research Database (Denmark)

    Bergstrøm-Nielsen, Carl

    2011-01-01

    Strategies are open compositions to be realised by improvising musicians. See more about my composition practise in the entry "Composition - General Introduction". Caution: streaming the sound files will in some cases only provide a few minutes' sample. Please DOWNLOAD them to hear them in full...

  4. Composition

    DEFF Research Database (Denmark)

    2014-01-01

    Memory Pieces are open compositions to be realised solo by an improvising musicians. See more about my composition practise in the entry "Composition - General Introduction". Caution: streaming the sound files will in some cases only provide a few minutes' sample. Please DOWNLOAD them to hear them...

  5. Mechanisms of charge transport and resistive switching in composite films of semiconducting polymers with nanoparticles of graphene and graphene oxide

    Science.gov (United States)

    Berestennikov, A. S.; Aleshin, A. N.

    2017-11-01

    We have investigated the effect of the resistive switching in the composite films based on polyfunctional polymers - PVK, PFD and PVC mixed with particles of Gr and GO with the concentration of ˜ 1 - 3 wt.%. We have developed the solution processed hybrid memory structures based on PVK and GO particles composite films. The effect of the resistive switching in Al/PVK(PFD; PVC):Gr(GO)/ITO/PET structures manifests itself as a sharp change of the electrical resistance from a low-conducting state to a relatively high-conducting state when applying a bias to Al-ITO electrodes of ˜ 0.2-0.4 V. It has been established that a sharp conductivity jump characterized by S-shaped current-voltage curves and the presence of their hysteresis occurs upon applying a voltage pulse to the Au/PVK(PFD; PVC):Gr(GO)/ITO/PET structures, with the switching time in the range from 1 to 30 μs. The mechanism of resistive switching associated with the processes of capture and accumulation of charge carriers by Gr(GO) particles introduced into the matrixes of the PVK polymer due to the reduction/oxidation processes. The possible mechanisms of energy transfer between organic and inorganic components in PVK(PFD; PVC):GO(Gr) films causes increase mobility are discussed. Incorporating of Gr (GO) particles into the polymer matrix is a promising route to enhance the performance of hybrid memory structures, as well as it is an effective medium for memory cells.

  6. Insulin resistance, exercise capacity and body composition in subjects with two hypertensive parents

    DEFF Research Database (Denmark)

    Andersen, U B; Dige-Petersen, H; Ibsen, H

    1999-01-01

    -ray absorptiometry; (4) an exercise test with gas exchange analysis; and (5) investigation of composition of usual diet by diet registration for 5 days. RESULTS: The 24-h diastolic blood pressure was higher in subjects predisposed to hypertension compared with the controls: 78.1 versus 74.0 mmHg (confidence interval...... for the difference between the means; -0.5; -7.9), but the insulin sensitivity index was similar: 312 versus 362 I(2) min(-1) pmol(-1) kg(-1) (28; -129). The two groups were similar in terms of body composition, exercise capacity and composition of usual diet. Resting and 24-h diastolic blood pressures were...

  7. Oxidation-resistant interface coatings for Nicalon/SiC composites

    Energy Technology Data Exchange (ETDEWEB)

    Stinton, D.P.; Besmann, T.M.; Lowden, R.A. [Oak Ridge National Lab., TN (United States); Liaw, P.K.; Shanmugham, S. [Univ. of Tennessee, Knoxville, TN (United States)

    1997-12-01

    Nicalon/SiC composites with thin C and C/oxide/C interfaces were fabricated. The oxide layers, mullite and Al{sub 2}O{sub 3}-TiO{sub 2}, were deposited by a sol-gel process, while the C layer was deposited by a chemical vapor infiltration method. The fabricated composites were flexure tested in both as-processed and oxidized conditions. Composites with C and C/oxide/C interfaces retained graceful failure even after 500 h oxidation at 1000 C, but with reduced flexural strengths.

  8. Epoxy-borax-coal tar composition for a radiation protective, burn resistant drum liner and centrifugal casting method

    International Nuclear Information System (INIS)

    Boyer, N.W.; Taylor, R.S.

    1980-01-01

    A boron containing burn resistant, low level radiation protection material useful, for example, as a liner for radioactive waste disposal and storage, a component for neutron absorber, and a shield for a neutron source. The material is basically composed of borax in the range of 25-50%, coal tar in the range of 25-37.5%, with the remainder being an epoxy resin mix. A preferred composition is 50% borax, 25% coal tar and 25% epoxy resin. The material is not susceptible to burning and is about 1/5 the cost of existing radiation protection material utilized in similar applications

  9. High-performance flexible resistive memory devices based on Al2O3:GeOx composite

    Science.gov (United States)

    Behera, Bhagaban; Maity, Sarmistha; Katiyar, Ajit K.; Das, Samaresh

    2018-05-01

    In this study a resistive switching random access memory device using Al2O3:GeOx composite thin films on flexible substrate is presented. A bipolar switching characteristic was observed for the co-sputter deposited Al2O3:GeOx composite thin films. Al/Al2O3:GeOx/ITO/PET memory device shows excellent ON/OFF ratio (∼104) and endurance (>500 cycles). GeOx nanocrystals embedded in the Al2O3 matrix have been found to play a significant role in enhancing the switching characteristics by facilitating oxygen vacancy formation. Mechanical endurance was retained even after several bending. The conduction mechanism of the device was qualitatively discussed by considering Ohmic and SCLC conduction. This flexible device is a potential candidate for next-generation electronics device.

  10. Hexagonal Boron Nitride Impregnated Silane Composite Coating for Corrosion Resistance of Magnesium Alloys for Temporary Bioimplant Applications

    Directory of Open Access Journals (Sweden)

    Saad Al-Saadi

    2017-11-01

    Full Text Available Magnesium and its alloys are attractive potential materials for construction of biodegradable temporary implant devices. However, their rapid degradation in human body fluid before the desired service life is reached necessitate the application of suitable coatings. To this end, WZ21 magnesium alloy surface was modified by hexagonal boron nitride (hBN-impregnated silane coating. The coating was chemically characterised by Raman spectroscopy. Potentiodynamic polarisation and electrochemical impedance spectroscopy (EIS of the coated alloy in Hanks’ solution showed a five-fold improvement in the corrosion resistance of the alloy due to the composite coating. Post-corrosion analyses corroborated the electrochemical data and provided a mechanistic insight of the improvement provided by the composite coating.

  11. Investigation on low room-temperature resistivity Cr/(Ba0.85Pb0.15)TiO3 positive temperature coefficient composites

    DEFF Research Database (Denmark)

    He, Zeming; Ma, J.; Qu, Yuanfang

    2009-01-01

    discussed. Using these special processes, the prepared composite with 20 wt% Cr possessed low room-temperature resistivity (2.96 Ω cm at 25 °C) and exhibited PTC effect (resistivity jump of 10), which is considered as a promising candidate for over-current protector when working at low voltage. The grain......Low room-temperature resistivity positive temperature coefficient (PTC) Cr/(Ba0.85Pb0.15)TiO3 composites were produced via a reducing sintering and a subsequent oxidation treatment. The effects of metallic content and processing conditions on materials resistivity–temperature properties were...

  12. Eight Weeks of Phosphatidic Acid Supplementation in Conjunction with Resistance Training Does Not Differentially Affect Body Composition and Muscle Strength in Resistance-Trained Men

    Directory of Open Access Journals (Sweden)

    Thomas L. Andre, Joshua J. Gann, Sarah K. McKinley-Barnard, Joon J. Song, Darryn S. Willoughby

    2016-09-01

    Full Text Available This study attempted to determine the effects of eight weeks of resistance training (RT combined with phosphatidic acid (PA supplementation at a dose of either 250 mg or 375 mg on body composition and muscle size and strength. Twenty-eight resistance-trained men were randomly assigned to ingest 375 mg [PA375 (n = 9] or 250 mg [PA250 (n = 9] of PA or 375 mg of placebo [PLC (n = 10] daily for eight weeks with RT. Supplements were ingested 60 minutes prior to RT and in the morning on non-RT days. Participants’ body composition, muscle size, and lower-body muscle strength were determined before and after training/supplementation. Separate group x time ANOVAs for each criterion variable were used employing an alpha level of ≤ 0.05. Magnitude- based inferences were utilized to determine the likely or unlikely impact of PA on each criterion variable. A significant main effect for time was observed for improvements in total body mass (p = 0.003, lean mass (p = 0.008, rectus femoris cross-sectional area [RF CSA (p = 0.011], and lower-body strength (p 0.05. Collectively, magnitude-based inferences determined both doses of PA to have a likely impact of increasing body mass (74.2%, lean mass (71.3%, RF CSA (92.2%, and very likely impact on increasing lower-body strength (98.1% beneficial. When combined with RT, it appears that PA has a more than likely impact on improving lower-body strength, whereas a likely impact exists for increasing muscle size and lean mass.

  13. Fracture Resistance of Endodontically Treated Teeth Restored with Biodentine, Resin Modified GIC and Hybrid Composite Resin as a Core Material.

    Science.gov (United States)

    Subash, Dayalan; Shoba, Krishnamma; Aman, Shibu; Bharkavi, Srinivasan Kumar Indu; Nimmi, Vijayan; Abhilash, Radhakrishnan

    2017-09-01

    The restoration of a severely damaged tooth usually needs a post and core as a part of treatment procedure to provide a corono - radicular stabilization. Biodentine is a class of dental material which possess high mechanical properties with excellent biocompatibility and bioactive behaviour. The sealing ability coupled with optimum physical properties could make Biodentine an excellent option as a core material. The aim of the study was to determine the fracture resistance of Biodentine as a core material in comparison with resin modified glass ionomer and composite resin. Freshly extracted 30 human permanent maxillary central incisors were selected. After endodontic treatment followed by post space preparation and luting of Glass fibre post (Reforpost, Angelus), the samples were divided in to three groups based on the type of core material. The core build-up used in Group I was Biodentine (Septodont, France), Group II was Resin-Modified Glass Ionomer Cement (GC, Japan) and Group III was Hybrid Composite Resin (TeEconom plus, Ivoclar vivadent). The specimens were subjected to fracture toughness using Universal testing machine (1474, Zwick/Roell, Germany) and results were compared using One-way analysis of variance with Tukey's Post hoc test. The results showed that there was significant difference between groups in terms of fracture load. Also, composite resin exhibited highest mean fracture load (1039.9 N), whereas teeth restored with Biodentine demonstrated the lowest mean fracture load (176.66 N). Resin modified glass ionomer exhibited intermediate fracture load (612.07 N). The primary mode of failure in Group I and Group II was favourable (100%) while unfavourable fracture was seen in Group III (30%). Biodentine, does not satisfy the requirements to be used as an ideal core material. The uses of RMGIC's as a core build-up material should be limited to non-stress bearing areas. Composite resin is still the best core build-up material owing to its high fracture

  14. Fracture resistance of endodontically treated teeth restored with Zirconia filler containing composite core material and fiber posts.

    Science.gov (United States)

    Jeaidi, Zaid Al

    2016-01-01

    To assess the fracture resistance of endodontically treated teeth with a novel Zirconia (Zr) nano-particle filler containing bulk fill resin composite. Forty-five freshly extracted maxillary central incisors were endodontically treated using conventional step back preparation and warm lateral condensation filling. Post space preparation was performed using drills compatible for fiber posts (Rely X Fiber Post) on all teeth (n=45), and posts were cemented using self etch resin cement (Rely X Unicem). Samples were equally divided into three groups (n=15) based on the type of core materials, ZirconCore (ZC) MulticCore Flow (MC) and Luxacore Dual (LC). All specimens were mounted in acrylic resin and loads were applied (Universal testing machine) at 130° to the long axis of teeth, at a crosshead speed of 0.5 mm/min until failure. The loads and the site at which the failures occurred were recorded. Data obtained was tabulated and analyzed using a statistical program. The means and standard deviations were compared using ANOVA and Multiple comparisons test. The lowest and highest failure loads were shown by groups LC (18.741±3.02) and MC (25.16±3.30) respectively. Group LC (18.741±3.02) showed significantly lower failure loads compared to groups ZC (23.02±4.21) and MC (25.16±3.30) (pcomposite cores was comparable to teeth restored with conventional Zr free bulk fill composites. Zr filled bulk fill composites are recommended for restoration of endodontically treated teeth as they show comparable fracture resistance to conventional composite materials with less catastrophic failures.

  15. Development of an oxidation resistant glass-ceramic composite coating on Ti-47Al-2Cr-2Nb alloy

    Science.gov (United States)

    Li, Wenbo; Zhu, Shenglong; Chen, Minghui; Wang, Cheng; Wang, Fuhui

    2014-02-01

    Three glass-ceramic composite coatings were prepared on Ti-47Al-2Cr-2Nb alloy by air spraying technique and subsequent firing. The aim of this work is to study the reactions between glass matrix and inclusions and their effects on the oxidation resistance of the glass-ceramic composite coating. The powders of alumina, quartz, or both were added into the aqueous solution of potassium silicate (ASPS) to form slurries used as the starting materials for the composite coatings. The coating formed from an ASPS-alumina slurry was porous, because the reaction between alumina and potassium silicate glass resulted in the formation of leucite (KAlSi2O6), consuming substantive glass phase and hindering the densification of the composite coating. Cracks were observed in the coating prepared from an ASPS-quartz slurry due to the larger volume shrinkage of the coating than that of the alloy. In contrast, an intact and dense SiO2-Al2O3-glass coating was successfully prepared from an ASPS-alumina-silica slurry. The oxidation behavior of the SiO2-Al2O3-glass composite coating on Ti-47Al-2Cr-2Nb alloy was studied at 900 °C. The SiO2-Al2O3-glass composite coating acted as an oxygen diffusion barrier, and prevented the inward diffusion of the oxygen from the air to the coating/alloy interface, therefore, decreasing the oxidation rate of the Ti-47Al-2Cr-2Nb alloy significantly.

  16. Accelerated Fatigue Resistance of Thick CAD/CAM Composite Resin Overlays Bonded with Light- and Dual-polymerizing Luting Resins.

    Science.gov (United States)

    Goldberg, Jack; Güth, Jan-Frederik; Magne, Pascal

    To evaluate the accelerated fatigue resistance of thick CAD/CAM composite resin overlays luted with three different bonding methods. Forty-five sound human second mandibular molars were organized and distributed into three experimental groups. All teeth were restored with a 5-mm-thick CAD/CAM composite resin overlay. Group A: immediate dentin sealing (IDS) with Optibond FL and luted with light-polymerizing composite (Herculite XRV). Group B: IDS with Optibond FL and luted with dual-polymerizing composite (Nexus 3). Group C: direct luting with Optibond FL and dual-polymerizing composite (Nexus 3). Masticatory forces at a frequency of 5 Hz were simulated using closed-loop servo-hydraulics and forces starting with a load of 200 N for 5000 cycles, followed by steps of 400, 600, 800, 1000, 1200 and 1400 N for a maximum of 30,000 cycles. Each step was applied through a flat steel cylinder at a 45-degree angle under submerged conditions. The fatigue test generated one failure in group A, three failures in group B, and no failures in group C. The survival table analysis for the fatigue test did not demonstrate any significant difference between the groups (p = 0.154). The specimens that survived the fatigue test were set up for the load-to-failure test with a limit of 4600 N. The survival table analysis for the load-to-failure test demonstrates an average failure load of 3495.20 N with survival of four specimens in group A, an average failure load of 4103.60 N with survival of six specimens in group B, and an average failure load of 4075.33 N with survival of nine specimens in group C. Pairwise comparisons revealed no significant differences (p composites in combination with IDS are not contraindicated with thick restorations.

  17. Toughened and corrosion- and wear-resistant composite structures and fabrication methods thereof

    Science.gov (United States)

    Seals, Roland D.; Ripley, Edward B.; Hallman, Russell L.

    2017-06-20

    Composite structures having a reinforced material interjoined with a substrate, wherein the reinforced material comprises a compound selected from the group consisting of titanium monoboride, titanium diboride, and combinations thereof.

  18. Multiply fully recyclable carbon fibre reinforced heat-resistant covalent thermosetting advanced composites.

    Science.gov (United States)

    Yuan, Yanchao; Sun, Yanxiao; Yan, Shijing; Zhao, Jianqing; Liu, Shumei; Zhang, Mingqiu; Zheng, Xiaoxing; Jia, Lei

    2017-03-02

    Nondestructive retrieval of expensive carbon fibres (CFs) from CF-reinforced thermosetting advanced composites widely applied in high-tech fields has remained inaccessible as the harsh conditions required to recycle high-performance resin matrices unavoidably damage the structure and properties of CFs. Degradable thermosetting resins with stable covalent structures offer a potential solution to this conflict. Here we design a new synthesis scheme and prepare a recyclable CF-reinforced poly(hexahydrotriazine) resin matrix advanced composite. The multiple recycling experiments and characterization data establish that this composite demonstrates performance comparable to those of its commercial counterparts, and more importantly, it realizes multiple intact recoveries of CFs and near-total recycling of the principal raw materials through gentle depolymerization in certain dilute acid solution. To our best knowledge, this study demonstrates for the first time a feasible and environment-friendly preparation-recycle-regeneration strategy for multiple CF-recycling from CF-reinforced advanced composites.

  19. Novel Nonporous Fouling-Resistant Enzymatic Composite Membranes for Waste Water Treatment

    National Research Council Canada - National Science Library

    Freeman, Benny D

    2005-01-01

    .... Permeation properties of thin-films made of these gels is also reported. Approximately 20 m2 of chitosan composite membrane were prepared at our industrial partner, Membrane Technology and Research (MTR...

  20. [The effect of N-stearoylethanolamine on liver phospholipid composition of rats with insulin resistance caused by alimentary obesity].

    Science.gov (United States)

    Onopchenko, O V; Kosiakova, H V; Horid'ko, T M; Klimashevskyĭ, V M; Hula, N M

    2014-01-01

    We used alimentary obesity-induced insulin resistance (IR) model in rats to investigate the influence of N-stearoylethanolamine on the content of phospholipids and their fatty acid composition. Our results show that prolonged high-fat diet triggers considerable aberrations in the composition of main phospholipids in the liver and can be one of the causes of IR in rats. In particular, the increase of phosphatidylcholine, phosphatidylethanolamine and significant decrease of other phospholipids: lysophosphatidylcholine, lysophosphatidylethanolamine, sphingomyelin, phosphatidylinositol, phosphatidylserine and diphosphaglicerol were observed. The levels of monounsaturated (erucic, nervonic, oleic) and polyunsaturated (eicosatrienoic, docosatrienoic, arachidonic) fatty acids were increased; meanwhile the content of diunsaturated acids was decreased. The NSE administration (50 mg/kg of body weight) caused restoration of the phospholipids content in the liver of rats with diet-induced IR that highly correlated with the decrease in plasma insulin level and the improvement of insulin sensitivity. Moreover, the effect of NSE was accompanied by the normalization of fatty acids composition of phospholipids that could be related to modulating influence of NSE on the activity of the main fatty acid desaturases. It is known that the imbalance in phospholipid composition of the rat liver causes substantial metabolic alterations that are associated with the development of IR. Accordingly, the compensations of the imbalance by NSE can help to restore insulin sensitivity, inhibit the development of obesity, IR and type 2 diabetes.

  1. Compressive fracture resistance of the marginal ridge in large Class II tunnels restored with cermet and composite resin.

    Science.gov (United States)

    Ehrnford, L E; Fransson, H

    1994-01-01

    Compressive fracture resistance of the marginal ridge was studied in large tunnel preparations, before and after restoration with cermet (Ketac Silver, ESPE), a universal hybrid composite (Superlux, DMG) and an experimental composite. Each group was represented by six tunnels in extracted upper premolars. The tunnels were prepared by the use of round burs up to size #6. Remaining ridge width was 1.5 mm and ridge height 1.7 mm in the contact area. The ridge was loaded to fracture by a rod placed perpendicular to the ridge. Generally this resulted in a shear fracture of the restoration. There was no significant reinforcement of the ridge by the cermet whereas the composites both reinforced by the same magnitude, averaging 62%. It was concluded that the ridge could be considered a "megafiller" where contact need to be preserved and contour protected against proximal and occlusal wear of the restoration. Clinically there would therefore be good reasons to save even ridge areas with very low inherent strength. Based on the present study composite resin might therefore be the filling material of choice for such tunnel preparations.

  2. Preparation and Wear Resistance of Aluminum Composites Reinforced with In Situ Formed TiO/Al2O3

    Science.gov (United States)

    Qin, Q. D.; Huang, B. W.; Li, W.; Zeng, Z. Y.

    2016-05-01

    An in situ TiO/Al2O3-reinforced Al composite is successfully prepared using a powder metallurgy route by the reaction of Ti2CO and Al powder. The Ti2CO powder is produced by carrying out a carbothermic reduction of titanium dioxide at 1000 °C. XRD results show that the final product is composed of Al, TiO, Al2O3, and Al3Ti. Morphology examination of the composite reveals the presence of bigger blocks of TiO and fine particles of Al2O3 and the volume fraction of reinforcement is found to range between 18 and 55%. As the volume fraction of the reinforced materials approaches 50%, the particles start to agglomerate. Dry sliding wear tests conducted using a conventional pin-on-disk testing machine show that the wear resistance of the composite is higher than that of the pure aluminum ingot. The wear rate of the composite increases almost linearly with the increase in the wear distance. The sliding wear test shows that as the volume fraction of the reinforced phase increases, the coefficient of friction decreases. The wear mechanism is also discussed.

  3. The effect of N-stearoylethanolamine on liver phospholipid composition of rats with insulin resistance caused by alimentary obesity

    Directory of Open Access Journals (Sweden)

    O. V. Onopchenko

    2014-02-01

    Full Text Available We used alimentary obesity-induced insulin resistance (IR model in rats to investigate the influence of N-stearoylethanolamine on the content of phospholipids and their fatty acid composition. Our results show that prolonged high-fat diet triggers considerable aberrations in the composition of main phospholipids in the liver and can be one of the causes of IR in rats. In particular, the increase of phosphatidylcholine, phosphatidylethanolamine and significant decrease of other phospholipids: lysophosphatidylcholine, lysophosphatidylethanolamine, sphingomyelin, phosphatidylinositol, phosphatidylserine and diphosphaglicerol were observed. The levels of monounsaturated (erucic, nervonic, oleic and polyunsaturated (eicosatrienoic, docosatrienoic, arachidonic fatty acids were increased; meanwhile the content of diunsaturated acids was decreased. The NSE administration (50 mg/kg of body weight caused restoration of the phospholipids content in the liver of rats with diet-induced IR that highly correlated with the decrease in plasma insulin level and the improvement of insulin sensitivity. Moreover, the effect of NSE was accompanied by the normalization of fatty acids composition of phospholipids that could be related to modulating influen­ce of NSE on the activity of the main fatty acid desaturases. It is known that the imbalance in phospholipid composition of the rat liver causes substantial metabolic alterations that are associated with the development of IR. Accordingly, the compensations of the imbalance by NSE can help to restore insulin sensitivity, inhibit the development of obesity, IR and type 2 diabetes.

  4. Quasi-Static Behavior of Palm-Based Elastomeric Polyurethane: For Strengthening Application of Structures under Impulsive Loadings

    Directory of Open Access Journals (Sweden)

    H. M. Chandima Chathuranga Somarathna

    2016-05-01

    Full Text Available In recent years, attention has been focused on elastomeric polymers as a potential retrofitting material considering their capability in contributing towards the impact resistance of various structural elements. A comprehensive understanding of the behavior and the morphology of this material are essential to propose an effective and feasible alternative to existing structural strengthening and retrofitting materials. This article presents the findings obtained from a series of experimental investigations to characterize the physical, mechanical, chemical and thermal behavior of eight types of palm-based polyurethane (PU elastomers, which were synthesized from the reaction between palm kernel oil-based monoester polyol (PKO-p and 4,4-diphenylmethane diisocyanate (MDI with polyethylene glycol (PEG as the plasticizer via pre-polymerization. Fourier transform infrared (FT-IR spectroscopy analysis was conducted to examine the functional groups in PU systems. Mechanical and physical behavior was studied with focus on elongation, stresses, modulus, energy absorption and dissipation, and load dispersion capacities by conducting hardness, tensile, flexural, Izod impact, and differential scanning calorimetry tests. Experimental results suggest that the palm-based PU has positive effects as a strengthening and retrofitting material against dynamic impulsive loadings both in terms of energy absorption and dissipation, and load dispersion. In addition, among all PUs with different plasticizer contents, PU2 to PU8 (which contain 2% to 8% (w/w PEG with respect to PKO-p content show the best correlation with mechanical response under quasi-static conditions focusing on energy absorption and dissipation and load dispersion characteristics.

  5. Multiple refraction switches realized by stretching elastomeric scatterers in sonic crystals

    Directory of Open Access Journals (Sweden)

    Y. Huang

    2015-02-01

    Full Text Available The effect of out-of-plane pre-stretch on the 2D sonic crystal with stretchable elastomeric scatterers is explored. The hyperelastic scatterers are characterized by a compressible neo-Hookean model. The Dirichlet-to-Neumann (DtN map is adopted to obtain the band structure and equi-frequency contours. We focus on the first passband and find that a variety of switching functionalities for refraction behaviors can be realized in selected frequencies under a specific pre-stretch range. These refraction switches enable an active control of wave propagation and are applicable in advanced technologies where switchable and multifunctional sonic crystals are required.

  6. Evaluation of Blast Resistance of Fiber Reinforced Composite Specimens under Contact Blast Load

    Science.gov (United States)

    Janota, O.; Foglar, M.

    2017-09-01

    This paper presents results of experimental programme which took place in 2014, 2015 and 2016. Experiments were focused on the resistance of full scale concrete panels subjected to contact blast loading. Specimens were loaded by contact blast by plastic explosive. All specimens were reinforced concrete slabs made of fiber concrete. Basalt mesh and textile sheets were added to some of the experiments for creating more heterogeneous material to achieve better resistance of the specimens. Evaluation of experiments was mainly focused on the damaged area on the contact side and soffit of the specimens. Dependency of the final damage of concrete panels on the weight of explosive and concrete strength was assessed.

  7. In vitro fracture resistance of molar teeth restored with a short fibre-reinforced composite material.

    Science.gov (United States)

    Fráter, Márk; Forster, András; Keresztúri, Márk; Braunitzer, Gábor; Nagy, Katalin

    2014-09-01

    The purpose of this in vitro study was to evaluate the efficiency of a short fibre-reinforced composite (SFRC) material compared to conventional composites when restoring class II. MOD cavities in molar teeth with different layering techniques. One hundred and thirty mandibular third molars were divided into 5 groups (n=26). Except for the control group (intact teeth), in all other groups MOD cavities were prepared. The cavities were restored by either conventional composite with horizontal and oblique layering or by SFRC with horizontal and oblique layering. The specimens were submitted to static fracture toughness test. Fracture thresholds and fracture patterns were evaluated. In general, no statistically significant difference was found in fracture toughness between the study groups, except for horizontally layered conventional composite restorations, which turned out to be significantly weaker than controls. However, SFRC yielded noticeably higher fracture thresholds and only obliquely applied SFRC restorations exhibited favourable fracture patterns above chance level. The application of SFRC did not lead to a statistically significant improvement of the fracture toughness of molar teeth with MOD cavities. Still, SFRC applied in oblique increments measurably reduces the chance of unrestorable fractures of molar teeth with class II MOD cavities. The restoration of severely weakened molar teeth with the use of SFRC combined with composite might have advantages over conventional composites alone. It was observed from the statistical data, that the application of SFRC with an oblique layering technique yielded not significantly but better fracture thresholds and more favourable fracture patterns than any other studied material/technique combination. Thus further investigations need to be carried out, to investigate the possible positive mechanical effects of SFRC. The application of the horizontal layering technique with conventional composite materials is inferior

  8. Elastomeric thermal interface materials with high through-plane thermal conductivity from carbon fiber fillers vertically aligned by electrostatic flocking.

    Science.gov (United States)

    Uetani, Kojiro; Ata, Seisuke; Tomonoh, Shigeki; Yamada, Takeo; Yumura, Motoo; Hata, Kenji

    2014-09-03

    Electrostatic flocking is applied to create an array of aligned carbon fibers from which an elastomeric thermal interface material (TIM) can be fabricated with a high through-plane thermal conductivity of 23.3 W/mK. A high thermal conductivity can be achieved with a significantly low filler level (13.2 wt%). As a result, this material retains the intrinsic properties of the matrix, i.e., elastomeric behavior. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Corrosion resistance of Zn-Al layered double hydroxide/poly(lactic acid) composite coating on magnesium alloy AZ31

    Science.gov (United States)

    Zeng, Rong-Chang; Li, Xiao-Ting; Liu, Zhen-Guo; Zhang, Fen; Li, Shuo-Qi; Cui, Hong-Zhi

    2015-12-01

    A Zn-Al layered double hydroxide (ZnAl-LDH) coating consisted of uniform hexagonal nano-plates was firstly synthesized by co-precipitation and hydrothermal treatment on the AZ31 alloy, and then a poly(lactic acid) (PLA) coating was sealed on the top layer of the ZnAl-LDH coating using vacuum freeze-drying. The characteristics of the ZnAl-LDH/PLA composite coatings were investigated by means of XRD, SEM, FTIR and EDS. The corrosion resistance of the coatings was assessed by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The results showed that the ZnAl-LDH coating contained a compact inner layer and a porous outer layer, and the PLA coating with a strong adhesion to the porous outer layer can prolong the service life of the ZnAl-LDH coating. The excellent corrosion resistance of this composite coating can be attributable to its barrier function, ion-exchange and self-healing ability.

  10. The Variations of Thermal Contact Resistance and Heat Transfer Rate of the AlN Film Compositing with PCM

    Directory of Open Access Journals (Sweden)

    Huann-Ming Chou

    2015-01-01

    Full Text Available The electrical industries have been fast developing over the past decades. Moreover, the trend of microelements and packed division multiplex is obviously for the electrical industry. Hence, the high heat dissipative and the electrical insulating device have been popular and necessary. The thermal conduct coefficient of aluminum nitride (i.e., AlN is many times larger than the other materials. Moreover, the green technology of composite with phase change materials (i.e., PCMs is worked as a constant temperature cooler. Therefore, PCMs have been used frequently for saving energy and the green environment. Based on the above statements, it does show great potential in heat dissipative for the AlN film compositing with PCM. Therefore, this paper is focused on the research of thermal contact resistance and heat transfer between the AlN/PCM pairs. According to the experimental results, the heat transfer decreases and the thermal contact resistance increases under the melting process of PCM. However, the suitable parameters such as contact pressures can be used to improve the above defects.

  11. Influence of high sintering pressure on the microhardness and wear resistance of diamond powder and silicon carbide-based composites

    Directory of Open Access Journals (Sweden)

    Osipov Oleksandr Sergueevitch

    2004-01-01

    Full Text Available The work reported on here involved the development of several samples of "diamond-SiC" composite produced under sintering pressures of up to 9.0 GPa at temperatures of up to 1973 7K. The average size of the diamond micropowder crystals used was 40/28 µm. The sintering process was carried out in a 2500-ton hydraulic press equipped with an anvil-type high-pressure device having a toroidal work surface and a central concavity diameter of 20 mm. The microhardness and wear resistance of the samples were found to be dependent on the sintering pressure. The experimental results indicated that the maximum microhardness and minimum wear resistance coefficients of each compact were attained when the pressure applied during sintering exceeded 6.5 GPa. Based on the established values of pressure, this study served to identify the types of devices applicable for the manufacture of composite material inserts for a variety of rock drilling applications.

  12. Experimental investigation of copper matrix longitudinal resistance in a composite Nb-Ti wire

    International Nuclear Information System (INIS)

    Gubkin, I.N.; Kozlenkova, N.I.; Nikulin, A.D.; Polikarpova, M.V.; Filkin, V.Ya.

    1994-01-01

    The longitudinal resistance of multifilamentary superconducting wires is among the major parameters used in design and optimization of superconducting magnetic systems. To enhance the conductivity of the copper matrix, it is made of pipes and rods of enhanced quality copper produced by electron beam melting (resistance ratio between two temperatures, 295 K and 4.2 K, R 295 /R 4.2 > 200). Yet for readily obtainable conductors this parameter is much lower. The reduction of the copper-matrix electrical conductivity may be attributed to wire-production technology involving processes such as extrusion, drawing and intermediate thermal processing, as well as to the size effect. Copper-matrix longitudinal resistance was studied as a function of wire diameter on specimens of multifilamentary Nb-Ti wire with filaments coated by a Nb layer. Experimental results are compared with the Sondheimer calculations for a monofilament conductor as well as with the Gavalloni calculations for an ideal wire with hexagonally located filaments. It has been shown that the best fit with the experiment is provided by the Sondheimer approximation. Comparison of the results of this work with other authors' data obtained for the specimens with no niobium barrier, allows the authors to single out the influence of a pure size effect and diffusion of Ti on the resistivity

  13. Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same

    Science.gov (United States)

    Way, J. Douglas; Hatlevik, Oyvind

    2014-07-15

    The invention relates to thin, hydrogen-permeable, sulfur-resistant membranes formed from multi-layers of palladium or palladium-alloy coatings on porous, ceramic or metal supports, methods of making these membranes, methods of repairing layers of these membranes and devices that incorporate these membranes.

  14. Diversity and community composition of tributyltin-resistant bacteria under different conditions

    International Nuclear Information System (INIS)

    Lee, Y. H.; Park, S.; Park, H.; Choi, Y

    2009-01-01

    Tributyltin (TBT) is an organometallic compound used as anti fouling agent in marine paints. this compound is toxic not only for eukaryotes, but also for bacteria. Based on the literature review, a few researchers have reported evidence for the presence of TBT-resistant bacteria in natural seawater and marine sediment. (Author)

  15. Diversity and community composition of tributyltin-resistant bacteria under different conditions

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Y. H.; Park, S.; Park, H.; Choi, Y

    2009-07-01

    Tributyltin (TBT) is an organometallic compound used as anti fouling agent in marine paints. this compound is toxic not only for eukaryotes, but also for bacteria. Based on the literature review, a few researchers have reported evidence for the presence of TBT-resistant bacteria in natural seawater and marine sediment. (Author)

  16. Carbon and nitrogen molecular composition of soil organic matter fractions resistant to oxidation

    Science.gov (United States)

    Katherine Heckman; Dorisel Torres; Christopher Swanston; Johannes Lehmann

    2017-01-01

    The methods used to isolate and characterise pyrogenic organic carbon (PyC) from soils vary widely, and there is little agreement in the literature as to which method truly isolates the most chemically recalcitrant (inferred from oxidative resistance) and persistent (inferred from radiocarbon abundance) fraction of soil organic matter. In addition, the roles of fire,...

  17. Body composition influenced by progressive elastic band resistance exercise of sarcopenic obesity elderly women: a pilot randomized controlled trial.

    Science.gov (United States)

    Huang, Shih-Wei; Ku, Jan-Wen; Lin, Li-Fong; Liao, Chun-De; Chou, Lin-Chuan; Liou, Tsan-Hon

    2017-08-01

    Sarcopenia involves age-related decreases in muscle strength and muscle mass, leading to frailty and disability in elderly people. When combined with obesity, it is defined as sarcopenic obesity (SO), which can result in more functional limitations and metabolic disorders than either disorder alone. The aim of this study was to investigate body composition changes after elastic band resistance training in elderly women with SO. Randomized single-blinded (assessor blinded) controlled pilot trial. Academic medical center. Thirty-five elderly (>60 years old) women with SO. This pilot randomized controlled trial focused on elderly women with SO. The study group underwent progressive elastic band resistance training for 12 weeks (3 times per week). The control group received only a 40-minute lesson about the exercise concept. Dual-energy X-ray absorptiometry was performed before and after intervention to evaluate body composition. Mann-Whitney U and Wilcoxon signed rank tests were used to analyze the differences within and between these groups. In total, 35 elderly women with SO were enrolled and divided into study (N.=18) and control groups (N.=17). No difference was observed in age, biochemical parameters, or Body Mass Index between both groups. After the intervention, the fat proportion of body composition in the right upper extremity (P=0.03), left upper extremity (P=0.04), total fat (P=0.035), and fat percentage (P=0.012) had decreased, and bone mineral density (BMD) (P=0.026), T-score (P=0.028), and Z-score (P=0.021) had increased in the study group. Besides, statistical difference was observed in outcome measurements of right upper extremity (P=0.013), total fat (P=0.023), and fat percentage (P=0.012) between the groups. Our study demonstrated that progressive elastic band resistance exercise can reduce fat mass and increase BMD in elderly women with SO, and that this exercise program is feasible for this demographic. Additional studies with larger sample sizes

  18. Neuroendocrine Responses and Body Composition Changes Following Resistance Training Under Normobaric Hypoxia

    Directory of Open Access Journals (Sweden)

    Chycki Jakub

    2016-12-01

    Full Text Available The aim of the present study was to evaluate the effects of a 6 week resistance training protocol under hypoxic conditions (FiO2 = 12.9%, 4000 m on muscle hypertrophy. The project included 12 resistance trained male subjects, randomly divided into two experimental groups. Group 1 (n = 6; age 21 ± 2.4 years; body height [BH] 178.8 ± 7.3 cm; body mass [BM] 80.6 ± 12.3 kg and group 2 (n = 6; age 22 ± 1.5 years; BH 177.8 ± 3.7cm; BM 81.1 ± 7.5 kg. Each group performed resistance exercises alternately under normoxic and hypoxic conditions (4000 m for 6 weeks. All subjects followed a training protocol that comprised two training sessions per week at an exercise intensity of 70% of 1RM; each training session consisted of eight sets of 10 repetitions of the bench press and barbell squat, with 3 min rest periods. The results indicated that strength training in normobaric hypoxia caused a significant increase in BM (p < 0.01 and fat free mass (FFM (p < 0.05 in both groups. Additionally, a significant increase (p < 0.05 was observed in IGF-1 concentrations at rest after 6 weeks of hypoxic resistance training in both groups. The results of this study allow to conclude that resistance training (6 weeks under normobaric hypoxic conditions induces greater muscle hypertrophy compared to training in normoxic conditions.

  19. Protein adsorption resistant surface on polymer composite based on 2D- and 3D-controlled grafting of phospholipid moieties

    International Nuclear Information System (INIS)

    Hoshi, Toru; Matsuno, Ryosuke; Sawaguchi, Takashi; Konno, Tomohiro; Takai, Madoka; Ishihara, Kazuhiko

    2008-01-01

    To prepare the biocompatible surface, a phosphorylcholine (PC) group was introduced on this hydroxyl group generated by surface hydrolysis on the polymer composite composed of polyethylene (PE) and poly (vinyl acetate) (PVAc) prepared by supercritical carbon dioxide. Two different procedures such as two-dimensional (2D) modification and three-dimensional (3D) modification were applied to obtain the steady biocompatible surface. 2D modification was that PC groups were directly anchored on the surface of the polymer composite. 3D modification was that phospholipid polymer was grafted from the surface of the polymer composite by surface-initiated atom transfer radical polymerization (SI-ATRP) of 2-methacryloyloxyethyl phosphorylcholine (MPC). The surfaces were characterized by X-ray photoelectron spectroscopy, dynamic water contact angle measurements, and atomic force microscope. The effects of the poly(MPC) chain length on the protein adsorption resistivity were investigated. The protein adsorption on the polymer composite surface with PC groups modified by 2D or 3D modification was significantly reduced as compared with that on the unmodified PE. Further, the amount of protein adsorbed on the 3D modified surface that is poly(MPC)-grafted surface decreased with an increase in the chain length of the poly(MPC). The surface with an arbitrary structure and the characteristic can be constructed by using 2D and 3D modification. We conclude that the polymer composites of PE/PVAc with PC groups on the surface are useful for fabricating biomedical devices due to their good mechanical and surface properties

  20. Compositions of corrosion-resistant Fe-based amorphous metals suitable for producing thermal spray coatings

    Science.gov (United States)

    Farmer, Joseph C; Wong, Frank M.G.; Haslam, Jeffery J; Ji, Xiaoyan; Day, Sumner D; Blue, Craig A; Rivard, John D.K.; Aprigliano, Louis F; Kohler, Leslie K; Bayles, Robert; Lemieux, Edward J; Yang, Nancy; Perepezko, John H; Kaufman, Larry; Heuer, Arthur; Lavernia, Enrique J

    2013-09-03

    A method of coating a surface comprising providing a source of amorphous metal that contains manganese (1 to 3 atomic %), yttrium (0.1 to 10 atomic %), and silicon (0.3 to 3.1 atomic %) in the range of composition given in parentheses; and that contains the following elements in the specified range of composition given in parentheses: chromium (15 to 20 atomic %), molybdenum (2 to 15 atomic %), tungsten (1 to 3 atomic %), boron (5 to 16 atomic %), carbon (3 to 16 atomic %), and the balance iron; and applying said amorphous metal to the surface by a spray.

  1. Testing of Composite Fan Vanes With Erosion-Resistant Coating Accelerated

    Science.gov (United States)

    Bowman, Cheryl L.; Sutter, James K.; Otten, Kim D.; Samorezov, Sergey; Perusek, Gail P.

    2004-01-01

    The high-cycle fatigue of composite stator vanes provided an accelerated life-state prior to insertion in a test stand engine. The accelerated testing was performed in the Structural Dynamics Laboratory at the NASA Glenn Research Center under the guidance of Structural Mechanics and Dynamics Branch personnel. Previous research on fixturing and test procedures developed at Glenn determined that engine vibratory conditions could be simulated for polymer matrix composite vanes by using the excitation of a combined slip table and electrodynamic shaker in Glenn's Structural Dynamics Laboratory. Bench-top testing gave researchers the confidence to test the coated vanes in a full-scale engine test.

  2. Chemical composition and modulation of bacterial drug resistance of the essential oil from leaves of Croton grewioides.

    Science.gov (United States)

    de Medeiros, Vivianne Marcelino; do Nascimento, Yuri Mangueira; Souto, Augusto Lopes; Madeiro, Sara Alves Lucena; Costa, Vicente Carlos de Oliveira; Silva, Suellen Maria P M; Falcão Silva, Vivyanne Dos Santos; Agra, Maria de Fátima; de Siqueira-Júnior, José Pinto; Tavares, Josean Fechine

    2017-10-01

    The essential oil from leaves of Croton grewioides Baill was obtained by hydrodistillation using Clevenger apparatus, and its chemical composition was analyzed by GC-MS, where 18 compounds were identified, mostly as monoterpenes (55.56%) and sesquiterpenes (44.44%), in which the major constituent was the α-pinene (47.43%). The essential oil of Croton grewioides (EOCg) and its major compound (α-pinene) were evaluated as modulators of antibiotic resistance in strain SA-1199B and IS-58 of Staphylococcus aureus that overexpresses efflux protein. The minimum inhibitory concentrations (MICs) of the antibiotics were determined by the microdilution assay in the absence and in the presence of sub-inhibitory concentration of EOCg and α-pinene. Although the EOCg and α-pinene did not indicate relevant antibacterial activity in vitro, they acted as antibiotic resistance modulators, i.e., EOCg in combination with norfloxacin, reducted its MIC, by 64× whereas in combination with tetracycline it was observed a reduction of 4×. Additionally, it was observed a MIC reduction of tetracycline by 32×, when combined with α-pinene. The results suggest that EOCg and α-pinene modulate or even reverse bacterial resistance as a putative efflux pump inhibitor. Copyright © 2017 Elsevier Ltd. All rights reserved.

  3. The fabrication, nano/micro-structure, heat- and wear-resistance of the superhydrophobic PPS/PTFE composite coatings.

    Science.gov (United States)

    Wang, Huaiyuan; Zhao, Jingyan; Zhu, Youzhuang; Meng, Yang; Zhu, Yanji

    2013-07-15

    A simple engineering method was used to fabricate stability and wear-resistance of superhydrophobic PPS-based PPS/PTFE surfaces through nano/micro-structure design and modification of the lowest surface energy groups (-CF2-), which was inspired by the biomimic lotus leaves. The hydrophobic properties and wear-resistance of the coatings were measured by a contact angle meter and evaluated on a pin-on-disk friction and wear tester, respectively. Moreover, the surfaces of the PPS/PTFE composite coatings were investigated by means of scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD), and thermogravimetry (TG) analysis. Results showed that the highest contact angle of the PPS/PTFE surface, with papillae-like randomly distributed double-scale structure, could reach up to 162°. When 1 wt.% PDMS was added, the highest contact angle could hold is 172°. The coatings also retained superhydrophobicity, even under high temperature environment. The investigation also indicated that the coatings were not only superhydrophobic but also oleophobic behavior at room temperature, such as the crude oil, glycerol, and oil-water mixture. The PPS/45%PTFE coatings had more stable friction coefficient and excellent wear-resistance (331,407 cycles) compared with those with less than 45% of PTFE. Copyright © 2012 Elsevier Inc. All rights reserved.

  4. Formation of structure, phase composition and properties of electro explosion resistant coatings using electron-beam processing

    International Nuclear Information System (INIS)

    Romanov, Denis A.; Sosnin, Kirill V.; Budovskikh, Evgenij A.; Gromov, Viktor E.; Semin, Alexander P.

    2014-01-01

    For the first time, the high intensity electron beam modification of electroexplosion composite coatings of MoCu, MoCCu, WCu, WCCu and TiB 2 Cu systems was done. The studies of phase and elemental composition, defective structure conditions of these coatings were carried out. The regimes of electron-beam processing making possible to form the dense, specular luster surface layers having a submicrocrystalline structure were revealed. It was established that electron-beam processing of elecroexplosion spraying of layer of elecroexplosion spraying carried out in the regime of melting results in the formation of structurally and contrationally homogeneous surface layer. Investigation of the effect of electron-beam processing of electroexplosion electroerosion resistant coatings on their tribological properties (wear resistanse and coefficient of friction) and electroerosion resistance was done. It was shown that all the examined costings demonstrate the increase of electroerosion resistance in spark erosion up to 10 times

  5. Formation of structure, phase composition and properties of electro explosion resistant coatings using electron-beam processing

    Energy Technology Data Exchange (ETDEWEB)

    Romanov, Denis A., E-mail: romanov-da@physics.sibsiu.ru, E-mail: kos2906@mail.ru, E-mail: budovskih-ea@physics.sibsiu.ru, E-mail: gromov@physics.sibsiu.ru, E-mail: da-rom@live.ru; Sosnin, Kirill V., E-mail: romanov-da@physics.sibsiu.ru, E-mail: kos2906@mail.ru, E-mail: budovskih-ea@physics.sibsiu.ru, E-mail: gromov@physics.sibsiu.ru, E-mail: da-rom@live.ru; Budovskikh, Evgenij A., E-mail: romanov-da@physics.sibsiu.ru, E-mail: kos2906@mail.ru, E-mail: budovskih-ea@physics.sibsiu.ru, E-mail: gromov@physics.sibsiu.ru, E-mail: da-rom@live.ru; Gromov, Viktor E., E-mail: romanov-da@physics.sibsiu.ru, E-mail: kos2906@mail.ru, E-mail: budovskih-ea@physics.sibsiu.ru, E-mail: gromov@physics.sibsiu.ru, E-mail: da-rom@live.ru; Semin, Alexander P., E-mail: romanov-da@physics.sibsiu.ru, E-mail: kos2906@mail.ru, E-mail: budovskih-ea@physics.sibsiu.ru, E-mail: gromov@physics.sibsiu.ru, E-mail: da-rom@live.ru [Siberian State Industrial University, Novokuznetsk, 654007 (Russian Federation)

    2014-11-14

    For the first time, the high intensity electron beam modification of electroexplosion composite coatings of MoCu, MoCCu, WCu, WCCu and TiB{sub 2}Cu systems was done. The studies of phase and elemental composition, defective structure conditions of these coatings were carried out. The regimes of electron-beam processing making possible to form the dense, specular luster surface layers having a submicrocrystalline structure were revealed. It was established that electron-beam processing of elecroexplosion spraying of layer of elecroexplosion spraying carried out in the regime of melting results in the formation of structurally and contrationally homogeneous surface layer. Investigation of the effect of electron-beam processing of electroexplosion electroerosion resistant coatings on their tribological properties (wear resistanse and coefficient of friction) and electroerosion resistance was done. It was shown that all the examined costings demonstrate the increase of electroerosion resistance in spark erosion up to 10 times.

  6. In vitro evaluation of fracture resistance of Fiber-Reinforced Composite inlay bridges in upper anterior and lower posterior teeth

    Directory of Open Access Journals (Sweden)

    Jalalian E.

    2007-07-01

    Full Text Available Background and Aim: Considering flexural strength of fiber-reinforced composites (FRC and also the role of conservative cavities in protecting sound tissue of abutments, the aim of this study was to evaluate the fracture resistance of these bridges by handmade samples in vitro.Materials and Methods: In this experimental in vitro study, 44 sound newly extracted teeth were used to make 22 fixed inlay bridges including 11 three unit anterior upper inlay bridges substituting clinical model of upper central and 11 three unit posterior lower inlay bridges substituting clinical model of lower first molar. Specimens were prepared with FRC and mounted with artificial PDL in acryl. Cases were exposed to final load by using Universal Testing Machine (Instron 1195 with the speed of 1 mm/min. Statistical analysis was performed by Kolmogorov- Smirnov, independent sample T and Kaplan-Meier tests with p<0.05 as the level of significance.Results: Based on the statistical tests, the 95% confidence interval of mean was 450-562 N in anterior and  1473- 1761 N in posterior area. Fracture strength was high in the studied groups. Fractures in both groups occurred on composite facing, and the framework remained intact. The highest percentage of fracture in posterior teeth was in the middle of pontic towards the distal connector and in the anterior teeth in the lateral connector, between central pontic and lateral abutment. Using the independent sample T  test a significant statistical difference was observed between two groups (P<0.001. The fracture resistance of anterior samples was lower than the posterior ones.Conclusion: Based on the results of this study regarding the high fracture resistance in both areas FRC inlay bridges could be recommended for upper anterior and lower posterior teeth in clinical dentistry certainly more studies are needed to ascertain this treatment option.

  7. Effect of fed- versus fasted state resistance training during Ramadan on body composition and selected metabolic parameters in bodybuilders

    Science.gov (United States)

    2013-01-01

    Background Muslim bodybuilders often continue training during Ramadan. However, the effect of resistance training in a fasted versus a fed state during Ramadan on body composition and metabolic parameters in bodybuilders is not well known. The aim of this study was to evaluate the effects of resistance training in a fasted versus a fed state during Ramadan on body composition and metabolic parameters in bodybuilders. Methods Sixteen men were allocated to two groups: Eight practicing resistance training in the late afternoon in a fasted state (FAST), and eight training in the late evening in an acutely fed state (FED) during Ramadan. All visited the laboratory in the morning two days before the start of Ramadan (Bef-R) and on the 29th day of Ramadan (End-R) for anthropometric measurement, completion of a dietary questionnaire, and provision of fasting blood and urine samples. Results Body mass and body fat percentage remained unchanged in FAST and FED during the whole period of the investigation. Both FAST and FED experienced an increase in the following parameters from Bef-R to End-R: urine specific gravity (1%; p = 0.028, p = 0.004 respectively), serum concentrations of urea (4%, p = 0.006; 7%, p = 0.004 respectively), creatinine (5%, p = 0.015; 6%, p = 0.04 respectively), uric acid (17%; p bodybuilders. Additionally, Ramadan fasting induced changes in urinary and some biochemical parameters, but these changes were not different according to when the training occurred. PMID:23617897

  8. Fatigue resistance and crack propensity of large MOD composite resin restorations: direct versus CAD/CAM inlays.

    Science.gov (United States)

    Batalha-Silva, Silvana; de Andrada, Mauro Amaral Caldeira; Maia, Hamilton Pires; Magne, Pascal

    2013-03-01

    To assess the influence of material/technique selection (direct vs. CAD/CAM inlays) for large MOD composite adhesive restorations and its effect on the crack propensity and in vitro accelerated fatigue resistance. A standardized MOD slot-type tooth preparation was applied to 32 extracted maxillary molars (5mm depth and 5mm bucco-palatal width) including immediately sealed dentin for the inlay group. Fifteen teeth were restored with direct composite resin restoration (Miris2) and 17 teeth received milled inlays using Paradigm MZ100 block in the CEREC machine. All inlays were adhesively luted with a light curing composite resin (Filtek Z100). Enamel shrinkage-induced cracks were tracked with photography and transillumination. Cyclic isometric chewing (5 Hz) was simulated, starting with a load of 200 N (5000 cycles), followed by stages of 400, 600, 800, 1000, 1200 and 1400 N at a maximum of 30,000 cycles each. Samples were loaded until fracture or to a maximum of 185,000 cycles. Teeth restored with the direct technique fractured at an average load of 1213 N and two of them withstood all loading cycles (survival=13%); with inlays, the survival rate was 100%. Most failures with Miris2 occurred above the CEJ and were re-restorable (67%), but generated more shrinkage-induced cracks (47% of the specimen vs. 7% for inlays). CAD/CAM MZ100 inlays increased the accelerated fatigue resistance and decreased the crack propensity of large MOD restorations when compared to direct restorations. While both restorative techniques yielded excellent fatigue results at physiological masticatory loads, CAD/CAM inlays seem more indicated for high-load patients. Copyright © 2012 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

  9. Sliding wear resistance of metal matrix composite layers prepared by high power laser

    NARCIS (Netherlands)

    Ocelik, Vaclav; Matthews, D; de Hosson, Jeff

    2005-01-01

    Two laser surface engineering techniques, Laser Cladding and Laser Melt Injection (LMI), were used to prepare three different metal matrix composite layers with a thickness of about 1 mm and approximately 25-30% volume fraction of ceramic particles. SiC/Al-8Si, WC/Ti-6Al-4V and TiB2/Ti-6Al-4V layers

  10. Biological resistance of polyethylene composites made with chemically modified fiber or flour

    Science.gov (United States)

    Rebecca E. Ibach; Craig M. Clemons

    2002-01-01

    The role of moisture in the biological decay of wood-plastic composites was investigated. Southern pine wood fiber and ponderosa pine wood flour were chemically modified using either acetic anhydride (AA), butylene oxide (BO), or propylene oxide (PO). A 50:50 mixture of high density polyethylene and either chemically modified fiber or flour, or untreated fiber or flour...

  11. Characterization of nano-composite PVD coatings for wear-resistant applications

    NARCIS (Netherlands)

    Galvan, D.; Pei, Y.T.; de Hosson, J.T.M.; DeHosson, JTM; Brebbia, CA; Nishida, SI

    2005-01-01

    Various methodologies for the characterization of nano-composite coatings are discussed, which consist TiC nano-particles distributed in an amorphous hydrocarbon (a-C:H) matrix. Complications that arise from the influence of coating roughness and underlying substrate on the properties are evaluated

  12. The Impact Resistance of Fiber-Reinforced Polymer Composites: A Review

    Directory of Open Access Journals (Sweden)

    Mahmood Mehrdad Shokrieh

    2012-12-01

    Full Text Available Fiber reinforced composites are widely used instead of traditional materials in various technological applications. Therefore, by considering the extensive applications of these materials, a proper knowledge of their impact behavior (from low- to high-velocity as well as their static behavior is necessary. In order to study the effects of strain rates on the behavior of these materials, special testing machines are needed. Most of the research efforts in this feld are focused on application of real loading and gripping boundary conditions on the testing specimens. In this paper, a detailed review of different types of impact testing techniques and the strain rate dependence of mechanical and strength properties of polymer composite materials  are presented. In this respect, an attempt is made to present and summarize the methods of impact tests and the strain rate effects on the tensile, compressive, shear and bending properties of the fber-reinforced polymer composite materials. Moreover, a classifcation of the state-of-the-art of the testing techniques to characterize composite material properties in a wide range of strain rates are also given.

  13. Resistance pressure sensor based on Ag/Cu/sub 2/O-PEPC-NiPc/Al composite

    International Nuclear Information System (INIS)

    Khan, A.; Karimov, K.S.; Shah, M.

    2011-01-01

    This work reports on the fabrication and investigation of pressure sensor based on Ag/Cu/sub 2/O-PEPC-NiPc/Al composite. The active layer of the composite was deposited by drop-casting of the blend Cu/sub 2/O-PEPC-NiPc on flexible substrate. The thin film of the blend consist of cuprous oxide (Cu/sub 2/O) micropowder, (5 wt. %), poly-N-epoxypropyl carbazole (PEPC), (2 wt. %) and nickel phthalocyanine (NiPc) micropowder, (3 wt. %) in benzol (1 ml). The film thickness of the composite is in the range of 20-30 mu m. It is found that the fabricated sensor is sensitive to pressure and showed good repeatability. The decrease in resistance of the sensor is observed 10 times by increasing the external uniaxial pressure up to 11.7 kNm/sup -2/. The experimentally obtained results are compared with the simulated results and showed reasonable agreement with each other. (author)

  14. A constrained maximization formulation to analyze deformation of fiber reinforced elastomeric actuators

    Science.gov (United States)

    Singh, Gaurav; Krishnan, Girish

    2017-06-01

    Fiber reinforced elastomeric enclosures (FREEs) are soft and smart pneumatic actuators that deform in a predetermined fashion upon inflation. This paper analyzes the deformation behavior of FREEs by formulating a simple calculus of variations problem that involves constrained maximization of the enclosed volume. The model accurately captures the deformed shape for FREEs with any general fiber angle orientation, and its relation with actuation pressure, material properties and applied load. First, the accuracy of the model is verified with existing literature and experiments for the popular McKibben pneumatic artificial muscle actuator with two equal and opposite families of helically wrapped fibers. Then, the model is used to predict and experimentally validate the deformation behavior of novel rotating-contracting FREEs, for which no prior literature exist. The generality of the model enables conceptualization of novel FREEs whose fiber orientations vary arbitrarily along the geometry. Furthermore, the model is deemed to be useful in the design synthesis of fiber reinforced elastomeric actuators for general axisymmetric desired motion and output force requirement.

  15. Sulcus reproduction with elastomeric impression materials: a new in vitro testing method.

    Science.gov (United States)

    Finger, Werner J; Kurokawa, Rie; Takahashi, Hidekazu; Komatsu, Masashi

    2008-12-01

    Aim of this study was to investigate the depth reproduction of differently wide sulci with elastomeric impression materials by single- and double-mix techniques using a tooth and sulcus model, simulating clinical conditions. Impressions with one vinyl polysiloxane (VPS; FLE), two polyethers (PE; IMP and P2), and one hybrid VPS/PE elastomer (FUS) were taken from a truncated steel cone with a circumferential 2 mm deep sulcus, 50, 100 or 200 microm wide. The "root surface" was in steel and the "periodontal tissue" in reversible hydrocolloid. Single-mix impressions were taken with light-body (L) or monophase (M) pastes, double-mix impressions with L as syringe and M or heavy-body (H) as tray materials (n=8). Sulcus reproduction was determined by 3D laser topography of impressions at eight locations, 45 degrees apart. Statistical data analysis by ANOVA and multiple comparison tests (pimpression materials only: FLE=IMP>FUS=P2. At 50 and 100 microm width, significant differences were found between materials (IMP>FUS=FLE>P2) and techniques (L+H=L+M>M>L). The sulcus model is considered useful for screening evaluation of elastomeric impression materials ability to reproduce narrow sulci. All tested materials and techniques reproduced 200 microm wide sulci to almost nominal depth. Irrespective of the impression technique used, IMP showed the best penetration ability in 50 and 100 microm sulci. Double-mix techniques are more suitable to reproduce narrow sulci than single-mix techniques.

  16. Power turbine dynamics - An evaluation of a shear-mounted elastomeric damper

    Science.gov (United States)

    Zorzi, E. S.; Walton, J.; Cunningham, R.

    1983-01-01

    As an alternative to the more conventional squeeze-film bearing damper designs, a Viton-70 shear-mounted, elastomeric damper was built and tested in a T-55 power turbine high-speed balancing rig. This application demonstrated, for the first time, the feasibility of using elastomers as the primary rotor damping source in production turbine engine hardware. The shear-mounted damper design was selected because of its compatibility with actual gas turbine engine radial space constraints, its accommodation of both the radial and axial thrust loads present in gas turbine engines, and its capability of controlled axial preload. Test results showed that the Viton-70 elastomeric damper operated successfully and provided excellent control of both synchronous and nonsynchronous vibrations through all phases of testing to the maximum rotor speed of 1676 rad/s (16,000 rpm). Excellent correlation between the predicted and experienced critical speeds, mode shapes, and log decrements for the power turbine rotor and elastomer damper assembly was also achieved.

  17. Experiment-Based Sensitivity Analysis of Scaled Carbon-Fiber-Reinforced Elastomeric Isolators in Bonded Applications

    Directory of Open Access Journals (Sweden)

    Farshad Hedayati Dezfuli

    2016-01-01

    Full Text Available Fiber-reinforced elastomeric isolators (FREIs are a new type of elastomeric base isolation systems. Producing FREIs in the form of long laminated pads and cutting them to the required size significantly reduces the time and cost of the manufacturing process. Due to the lack of adequate information on the performance of FREIs in bonded applications, the goal of this study is to assess the performance sensitivity of 1/4-scale carbon-FREIs based on the experimental tests. The scaled carbon-FREIs are manufactured using a fast cold-vulcanization process. The effect of several factors including the vertical pressure, the lateral cyclic rate, the number of rubber layers, and the thickness of carbon fiber-reinforced layers are explored on the cyclic behavior of rubber bearings. Results show that the effect of vertical pressure on the lateral response of base isolators is negligible. However, decreasing the cyclic loading rate increases the lateral flexibility and the damping capacity. Additionally, carbon fiber-reinforced layers can be considered as a minor source of energy dissipation.

  18. A new UV-curing elastomeric substrate for rapid prototyping of microfluidic devices

    Science.gov (United States)

    Alvankarian, Jafar; Yeop Majlis, Burhanuddin

    2012-03-01

    Rapid prototyping in the design cycle of new microfluidic devices is very important for shortening time-to-market. Researchers are facing the challenge to explore new and suitable substrates with simple and efficient microfabrication techniques. In this paper, we introduce and characterize a UV-curing elastomeric polyurethane methacrylate (PUMA) for rapid prototyping of microfluidic devices. The swelling and solubility of PUMA in different chemicals is determined. Time-dependent measurements of water contact angle show that the native PUMA is hydrophilic without surface treatment. The current monitoring method is used for measurement of the electroosmotic flow mobility in the microchannels made from PUMA. The optical, physical, thermal and mechanical properties of PUMA are evaluated. The UV-lithography and molding process is used for making micropillars and deep channel microfluidic structures integrated to the supporting base layer. Spin coating is characterized for producing different layer thicknesses of PUMA resin. A device is fabricated and tested for examining the strength of different bonding techniques such as conformal, corona treating and semi-curing of two PUMA layers in microfluidic application and the results show that the bonding strengths are comparable to that of PDMS. We also report fabrication and testing of a three-layer multi inlet/outlet microfluidic device including a very effective fluidic interconnect for application demonstration of PUMA as a promising new substrate. A simple micro-device is developed and employed for observing the pressure deflection of membrane made from PUMA as a very effective elastomeric valve in microfluidic devices.

  19. METHOD FOR PROVIDING SHAPED BIODEGRADABLE AND ELASTOMERIC STRUCTURES OF (CO) POLYMERS OF 1,3-TRIMETHYLENE CARBONATE (TMC), SHAPED BIODEGRADABLE AND ELASTOMERIC STRUCTURES, AND THE USE OF THESE STRUCTURES

    NARCIS (Netherlands)

    Grijpma, D.W.; Pêgo, A.P.; Feijen, Jan

    2004-01-01

    The present invention relates to methods for providing shaped biodegradable and elastomeric structures of (co)polymers of 1,3­trimethylene carbonate (TMC) with improved (mechanical) properties which can be used for tissue or tissue component support, generation or regeneration. Such shaped

  20. Research of the Fire Resistance оf Translucent and Composite Facade System

    Directory of Open Access Journals (Sweden)

    Nedryshkin Oleg

    2016-01-01

    Full Text Available The paper aims at researching fire resistance of a prototype facade system “Technocom” (type Alucobond A2. Experimental and theoretical research of fire hazard facade system is carried out. The objectives of the study are to determine compliance with the applicable front of special technical requirements. The status of problem reducing fire hazard facade system is reviewed. The method developed by compensatory measures is applied.

  1. Blast-Resistant Improvement of Sandwich Armor Structure with Aluminum Foam Composite

    OpenAIRE

    Yang, Shu; Qi, Chang

    2013-01-01

    Sandwich armor structures with aluminum foam can be utilized to protect a military vehicle from harmful blast load such as a landmine explosion. In this paper, a system-level dynamic finite element model is developed to simulate the blast event and to evaluate the blast-resistant performance of the sandwich armor structure. It is found that a sandwich armor structure with only aluminum foam is capable of mitigating crew injuries under a moderate blast load. However, a severe blast load causes...

  2. Chemical composition and antibacterial activities of Illicium verum against antibiotic-resistant pathogens.

    Science.gov (United States)

    Yang, Jyh-Ferng; Yang, Cheng-Hong; Chang, Hsueh-Wei; Yang, Cheng-San; Wang, Shao-Ming; Hsieh, Ming-Che; Chuang, Li-Yeh

    2010-10-01

    In recent years, human pathogenic microorganisms have developed multiple drug resistance and caused serious nosocomial infections. In this study, we identified four new antimicrobial compounds from the Chinese herbal medicine Illicium verum and assessed their antibacterial efficacies. The supercritical CO₂ and ethanol extracts of Illicium verum showed substantial antibacterial activity against 67 clinical drug-resistant isolates, including 27 Acinetobacter baumannii, 20 Pseudomonas aeruginosa, and 20 methicillin-resistant Staphylococcus aureus. The diethyl ether (EE) fraction obtained from partition extraction and supercritical CO₂ extracts revealed an antibacterial activity with a minimum inhibitory concentration value of 0.15-0.70 mg/mL and 0.11 mg/mL, respectively. The EE fraction of I. verum showed synergetic effects with some commercial antibiotics. The antimicrobial mechanism was investigated with killing curves and scanning electron microscopy observation. The chemical components of the extracts were analyzed by spectrophotometry; (E)-anethole, anisyl acetone, anisyl alcohol, and anisyl aldehyde exhibited antibacterial activity against different clinical isolates. These extracts from I. verum can be further developed into antibiotic medicines due to their proven antibacterial activity.

  3. Toward advanced gamma rays radiation resistance and shielding efficiency with phthalonitrile resins and composites

    Science.gov (United States)

    Derradji, Mehdi; Zegaoui, Abdeldjalil; Xu, Yi-Le; Wang, An-ran; Dayo, Abdul Qadeer; Wang, Jun; Liu, Wen-bin; Liu, Yu-Guang; Khiari, Karim

    2018-04-01

    The phthalonitrile resins have claimed the leading place in the field of high performance polymers thanks to their combination of outstanding properties. The present work explores for the first time the gamma rays radiation resistance and shielding efficiency of the phthalonitrile resins and its related tungsten-reinforced nanocomposites. The primary goal of this research is to define the basic behavior of the phthalonitrile resins under highly ionizing gamma rays. The obtained results confirmed that the neat phthalonitrile resins can resist absorbed doses as high as 200 kGy. Meanwhile, the remarkable shielding efficiency of the phthalonitrile polymers was confirmed to be easily improved by preparing lead-free nanocomposites. In fact, the gamma rays screening ratio reached the exceptional value of 42% for the nanocomposites of 50 wt% of nano-tungsten loading. Thus, this study confirms that the remarkable performances of the phthalonitrile resins are not limited to the thermal and mechanical properties and can be extended to the gamma rays radiation and shielding resistances.

  4. The Effect of 10 Weeks of Resistance Training on Serum Myostatin and Body Composition Levels in Obese Adolescents

    Directory of Open Access Journals (Sweden)

    Mohammad ebrahim Bahram

    2017-06-01

    Full Text Available Background and Objectives: Studies are indicative of negative regulatory role of myostatin in skeletal muscle growth. In the present study, the effect of 10 weeks of resistance training was investigated on serum level of myostatin and body composition in obese adolescents. Methods: In this quasi-experimental study, 16 students of Mohammad Naraghi Technical and Vocational Institute of Kashan with body mass index of 30-35, were purposefully selected and randomly divided into two groups of experimental and control. Resistance training program included 3 sets of 8-10 reps with 50-90% 1RM for 3 days a week. Before starting the training program and 48 h after the last training session, blood samples were taken from all participants. Before and after the training, plasma level of myostatin were measured. Data were analyzed using Kolmogorov-Smirnov, dependent t-, and independent t-tests at significance level of p<0.05. Results: In this study, 10 weeks of resistance training resulted in a significant decrease in serum level of myostatin (p=0.0001, weight (p=0.015, body mass index (p=0.02, and fat percentage (p=0.0001 in the experimental group as compared to the control group (p<0.05. Conclusion: According to the findings of the current study, it can be concluded that resistance training-induced changes reduce myostatin level and some anthropometric parameters related to obesity and overweight, which may be effective in the prevention of muscle atrophy and loss of muscle mass, and can play a role as an autocrine mechanism for guiding mechanical load stimuli in response to the growth of skeletal muscle.

  5. Thermal shock resistance of ceramic fibre composites characterized by non-destructive methods

    Directory of Open Access Journals (Sweden)

    M. Dimitrijević

    2008-12-01

    Full Text Available Alumina based ceramic fibres and alumina based ceramic were used to produce composite material. Behaviour of composite ceramics after thermal shock treatments was investigated. Thermal shock of the samples was evaluated using water quench test. Surface deterioration level of samples was monitored by image analysis before and after a number of quenching cycles. Ultrasonic measurements were done on samples after quench tests. Dynamic Young modulus of elasticity and strength degradation were calculated using measured values of ultrasonic velocities. Strengths deterioration was calculated using the non-destructive measurements and correlated to degradation of surface area and number of quenches. The addition of small amount of ceramic fibres improves the strengths and diminishes the loss of mechanical properties of samples during thermal shock experiments.

  6. Surge-Resistant Nanocomposite Enameled Wire Using Silica Nanoparticles with Binary Chemical Compositions on the Surface

    Directory of Open Access Journals (Sweden)

    Jeseung Yoo

    2015-01-01

    Full Text Available We developed polyesterimide (PEI nanocomposite enameled wires using surface-modified silica nanoparticles with binary chemical compositions on the surface. The modification was done using silanes assisted by ultrasound, which facilitated high density modification. Two different trimethoxysilanes were chosen for the modification on the basis of resemblance of chemical compositions on the silica surface to PEI varnish. The surface-modified silica was well dispersed in PEI varnish, which was confirmed by optical observation and viscosity measurement. The glass transition temperature of the silica-PEI nanocomposite increased with the silica content. The silica-dispersed PEI varnish was then used for enameled wire fabrication. The silica-PEI nanocomposite enameled wire exhibited a much longer lifetime compared to that of neat PEI enameled wire in partial discharge conditions.

  7. The role of microcracking on the crack growth resistance of brittle solids and composites

    International Nuclear Information System (INIS)

    Biner, S.B.

    1994-01-01

    A set of numerical analyses of crack growth was preformed to elucidate the influence of microcracking on the fracture behavior of microcracking brittle solids and composites. The random nucleation, orientation and size effects of discrete nucleating microcracks and resulting interactions are fully accounted for in a hybrid finite element model. The results obtained from the finite element analysis are compared with the continuum description of the microcracking. Although continuum description can provide a reasonable estimation of shielding, it fails to resolve the details of micromechanism of toughening resulting from microcracking, since not every shielding event during the course of crack extension corresponds to an increase in the R-curve. Moreover, as seen in the composite cases, the local events leading to toughening behavior may not be associated with the microcracking even in the presence of a large population of microcracks

  8. Composition

    DEFF Research Database (Denmark)

    Bergstrøm-Nielsen, Carl

    2014-01-01

    Cue Rondo is an open composition to be realised by improvising musicians. See more about my composition practise in the entry "Composition - General Introduction". Caution: streaming the sound/video files will in some cases only provide a few minutes' sample, or the visuals will not appear at all....... Please DOWNLOAD them to see/hear them in full length! This work is licensed under a Creative Commons "by-nc" License. You may for non-commercial purposes use and distribute it, performance instructions as well as specially designated recordings, as long as the author is mentioned. Please see http...

  9. Composition and adaptation of human myotendinous junction and neighboring muscle fibers to heavy resistance training

    DEFF Research Database (Denmark)

    Jakobsen, Jens R.; Mackey, A L; Knudsen, A B

    2017-01-01

    The myotendinous junction (MTJ) is a common site of strain injury and yet understanding of its composition and ability to adapt to loading is poor. The main aims of this study were to determine the profile of selected collagens and macrophage density in human MTJ and adjoining muscle fibers...... 4 weeks of training may reflect a training-induced protection against strain injuries in this region....

  10. Wear resistant composite structure of vitreous carbon containing convoluted fibers. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Burton, R.G.; Burton, R.A.

    1996-05-28

    Energy Related Inventions Program Number 613 was a two year program to commercialize a unique new wear material, Metal Reinforced Carbon Composite, MRCC. The program was designed to manufacture sample components of MRCC for evaluation by potential users and manufacturers. As a result of the program Burton Technologies Inc. and Rotary Power International are forming a joint company to manufacture, market and license MRCC materials to a wide range of industries.

  11. The Impact Resistance of Fiber-Reinforced Polymer Composites: A Review

    OpenAIRE

    Mahmood Mehrdad Shokrieh; Majid Jamal Omidi

    2012-01-01

    Fiber reinforced composites are widely used instead of traditional materials in various technological applications. Therefore, by considering the extensive applications of these materials, a proper knowledge of their impact behavior (from low- to high-velocity) as well as their static behavior is necessary. In order to study the effects of strain rates on the behavior of these materials, special testing machines are needed. Most of the research efforts in this feld are focused on application ...

  12. A New Design of In Situ Ti(C,N) Reinforced Composite Coatings and Their Microstructures, Interfaces, and Wear Resistances.

    Science.gov (United States)

    Wang, Mingliang; Cui, Hongzhi; Wei, Na; Ding, Lei; Zhang, Xinjie; Zhao, Yong; Wang, Canming; Song, Qiang

    2018-01-31

    Here, a unique combination of a novel carbon-nitrogen source (g-C 3 N 4 ) with different mole ratios of Ti/g-C 3 N 4 has been utilized to fabricate iron matrix composite coatings by a synchronized powder feeding plasma transferred arc (PTA) cladding technology. The results show that submicron Ti(C,N) particles are successfully fabricated in situ on a Q235 low carbon steel substrate to reinforce the iron matrix composite coatings and exhibit dense microstructures and good metallurgical bonding between the coating and the substrate. The microstructure of the coating consists of an α-Fe matrix and Ti(C,N) particles when the mole ratio of Ti/g-C 3 N 4 is no more than 5:1. The microhardness and wear resistance of the coating gradually improve with increasing abundance of the in-situ-synthesized Ti(C,N) particles. Interestingly, for a Ti/g-C 3 N 4 mole ratio of 6:1, a fine lamellar eutectic Laves phase (Fe 2 Ti) appears, and this phase further improves the microhardness and wear resistance of the coating. The microhardness of the coating is 3.5 times greater than that of the Q235 substrate, and the wear resistance is enhanced 7.66 times over that of the substrate. The Ti(C,N)/Fe 2 Ti and Fe 2 Ti/α-Fe interfaces are very clean, and the crystallographic orientation relationships between the phases are analyzed by high-resolution transmission electron microscopy (HRTEM) and an edge-to-edge matching model. The theoretical predictions and the experimental results are in good agreement. Furthermore, based on the present study, for the solidification process near equilibrium, smaller interatomic spacing misfits and interplanar spacing d-value mismatches contribute to the formation of crystallographic orientation relationships between phases during the PTA cladding process. The existence of orientation relationships is beneficial for improving the properties of the coatings. This work not only expands the application fields of g-C 3 N 4 but also provides a new idea for the

  13. Biomimetic elastomeric, conductive and biodegradable polycitrate-based nanocomposites for guiding myogenic differentiation and skeletal muscle regeneration.

    Science.gov (United States)

    Du, Yuzhang; Ge, Juan; Li, Yannan; Ma, Peter X; Lei, Bo

    2018-03-01

    Artificial muscle-like biomaterials have gained tremendous interests owing to their broad applications in regenerative medicine, wearable devices, bioelectronics and artificial intelligence. Unfortunately, key challenges are still existed for current materials, including biomimetic viscoelasticity, biocompatibility and biodegradation, multifunctionality. Herein, for the first time, we develop highly elastomeric, conductive and biodegradable poly (citric acid-octanediol-polyethylene glycol)(PCE)-graphene (PCEG) nanocomposites, and demonstrate their applications in myogenic differentiation and guiding skeletal muscle tissue regeneration. In PCEG nanocomposites, PCE provides the biomimetic elastomeric behavior, and the addition of reduced graphene oxide (RGO) endows the enhanced mechanical strength and conductivity. The highly elastomeric behavior, significantly enhanced modulus (400%-800%), strength (200%-300%) of PCEG nanocomposites with controlled biodegradability and electrochemical conductivity were achieved. The myoblasts proliferation and myogenic differentiation were significantly improved by PCEG nanocomposite. Significantly high in vivo biocompatibility of PCEG nanocomposites was observed when implanted in the subcutaneous tissue for 4 weeks in rats. PCEG nanocomposites could significantly enhance the muscle fibers and blood vessels formation in vivo in a skeletal muscle lesion model of rat. This study may provide a novel strategy to develop multifunctional elastomeric nanocomposites with high biocompatibility for potential soft tissue regeneration and stretchable bioelectronic devices. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. Glass interface effect on high-strain-rate tensile response of a soft polyurethane elastomeric polymer material

    NARCIS (Netherlands)

    Fan, J.T.; Weerheijm, J.; Sluys, L.J.

    2015-01-01

    The glass interface effect on dynamic tensile response of a soft polyurethane elastomeric polymer material has been investigated by subjecting a glass-polymer system of this polymer material matrix embedded a single 3 mm-diameter glass particle to impact loading in a split Hopkinson tension bar

  15. Fabrication, characterization, and biocompatibility assessment of a novel elastomeric nanofibrous scaffold: A potential scaffold for soft tissue engineering

    DEFF Research Database (Denmark)

    Shamirzaei Jeshvaghani, Elham; Ghasemi-Mobarakeh, Laleh; Mansurnezhad, Reza

    2017-01-01

    With regard to flexibility and strength properties requirements of soft biological tissue, elastomeric materials could be more beneficial in soft tissue engineering applications. The present work investigates the use of an elastic polymer, (polycaprolactone fumarate [PCLF]), for fabricating...... experiments and its application for engineering of soft tissues subjected to in vivo cyclic mechanical stresses....

  16. Effects of coal composition and flotation reagents on the water resistance of binderless briquettes

    Energy Technology Data Exchange (ETDEWEB)

    Motaung, S.R.; Mangena, S.J.; de Korte, G.J. [Syngas & Coal Technology, Sasolburg (South Africa)

    2007-10-15

    The difference in the physical properties, particularly the water resistance or wet strength, of the binderless coal briquettes produced from flotation feed and concentrate was investigated using six bituminous coals from two collieries in the Witbank Coalfield. The coal samples were analyzed for their proximate, petrographic, and mineralogical properties. The presence, in the flotation concentrates, of the reagents used during the froth flotation process was also investigated using gas chromatography. Pillow-shaped binderless briquettes were produced from coal samples at various moisture contents and a pressure of approximately 17 MPA using a Komarek B-100A double-roll press. The briquettes were tested for some physical properties (i.e., dry- and wet-compressive strengths), which were thereafter compared with the properties determined for the coal samples. The binderless briquettes produced from the flotation concentrates were more water-resistant than those produced from the flotation feed. The flotation feed and concentrates of the coals tested were found to have similar petrographic properties. As expected, the ash and kaolinite contents were found to be lower in the flotation concentrates than in the flotation feed. Flotation reagents were detected in the flotation concentrates from both collieries. From the results obtained it is concluded that the increased water resistance of the binderless briquettes produced from flotation concentrates of the coals tested is due to a combination of the fineness of the coal particles, assisted by the amount of reactive macerals (most particularly vitrinite) with the lower ash and kaolinite contents, together with the presence of the flotation reagents, particularly the collector, in the flotation concentrate.

  17. Bistable resistive memory behavior in gelatin-CdTe quantum dot composite film

    Science.gov (United States)

    Vallabhapurapu, Sreedevi; Rohom, Ashwini; Chaure, N. B.; Du, Shengzhi; Srinivasan, Ananthakrishnan

    2018-05-01

    Bistable memory behavior has been observed for the first time in gelatin type A thin film dispersed with functionalized CdTe quantum dots. The two terminal device with the polymer nanocomposite layer sandwiched between an indium tin oxide coated glass plate and an aluminium top electrode performs as a bistable resistive random access memory module. Butterfly shaped (O-shaped with a hysteresis in forward and reverse sweeps) current-voltage response is observed in this device. The conduction mechanism leading to the bistable electrical switching has been deduced to be a combination of ohmic and electron hopping.

  18. Effect of commonly used beverage, soft drink, and mouthwash on force delivered by elastomeric chain: a comparative in vitro study.

    Science.gov (United States)

    Kumar, Kiran; Shetty, Sharath; Krithika, M J; Cyriac, Bobby

    2014-06-01

    The objective was to evaluate and compare the effect of Coca-Cola®, tea, Listerine® mouthwash on the force delivered by elastomeric chain in vitro. Four specimen groups (distilled water, Coca-Cola®, tea, Listerine® mouthwash) with a total sample size of 480 specimens. A specimen is described as a four link grey close elastomeric chain. Jigs, each with a series of pins set 25 mm apart, was used to hold stretched elastomeric chains at a constant length. These jigs allowed for complete submersion of the elastomeric chain in a water bath throughout the test period, as well as the dipping of elastomeric chains in respective control and test solutions. For 60 s, twice a day, groups were exposed to the respective solutions, the two daily exposure was separated by 9 h and force measurements were taken at six time points during the experiment, that is, 1 h, 24 h, 7 days, 14 days, 21 days, and 28 days. Force measurements were made by Instron machine by a single blinded examiner with the help of a second examiner. It was found out that there was highly significant difference between groups control, Coca-Cola®, Listerine®, and tea as well as there was highly significant (p Coca-Cola® and the Listerine® group reached a plateau between 7 and 21 days then decrease between 21 and 28 days. The tea group showed plateau phase between 7 and 28 days. After 28 days in the control group, 25% force decay occurred while the test groups force decay of 30-50% occurred. Coca-Cola®, Listerine® mouthwash, and tea cause an increase in force decay of elastomeric chains over time. Tea caused highest force decay followed by Listerine® and Coca-Cola® when compared to control group. How to cite the article: Kumar K, Shetty S, Krithika MJ, Cyriac B. Effect of commonly used beverage, soft drink, and mouthwash on force delivered by elastomeric chain: A comparative in vitro study. J Int Oral Health 2014;6(3):7-10.

  19. Alteration in lipid composition of plasma membranes of sensitive and resistant Guerin carcinoma cells due to the action of free and liposomal form of cisplatin.

    Science.gov (United States)

    Naleskina, L A; Todor, I N; Nosko, M M; Lukianova, N Y; Pivnyuk, V M; Chekhun, V F

    2013-09-01

    To study in vivo changes of lipid composition of plasma membranes of sensitive and resistant to cisplatin Guerin carcinoma cells under influence of free and liposomal cisplatin forms. The isolation of plasma membranes from parental (sensitive) and resistant to cisplatin Guerin carcinoma cells was by differential ultracentrifugation in sucrose density gradient. Lipids were detected by method of thin-layer chromatography. It was determined that more effective action of cisplatin liposomal form on resistant cells is associated with essential abnormalities of conformation of plasma membrane due to change of lipid components and architectonics of rafts. It results in the increase of membrane fluidity. Reconstructions in lipid composition of plasma membranes of cisplatin-resistant Guerin carcinoma cells provide more intensive delivery of drug into the cells, increase of its concentration and more effective interaction with cellular structural elements.

  20. Development of high temperature resistant ceramic matrix composites based on SiC- and novel SiBNC-fibres

    International Nuclear Information System (INIS)

    Daenicke, Enrico

    2014-01-01

    Novel ceramic fibres in the quaternary system Si-B-C-N exhibit excellent high temperature stability and creep resistance. In th is work it was investigated, to what extent these outstanding properties of SiBNC-fibres can be transferred into ceramic matrix composites (CMC) in comparison to commercial silicon carbide (SiC) fibres. For the CMC development the liquid silicon infiltration (LSI) as well as the polymer infiltration and pyrolysis process (PIP) was applied. Extensive correlations between fibre properties, fibre coating (without, pyrolytic carbon, lanthanum phosphate), process parameters of the CMC manufacturing method and the mechanical and microstructural properties of the CMC before and after exposure to air could be established. Hence, the potential of novel CMCs can be assessed and application fields can be derived.

  1. A new discrete-element approach for the assessment of the seismic resistance of composite reinforced concrete-masonry buildings

    International Nuclear Information System (INIS)

    Calio, I.; Cannizzaro, F.; Marletta, M.; Panto, B.; D'Amore, E.

    2008-01-01

    In the present study a new discrete-element approach for the evaluation of the seismic resistance of composite reinforced concrete-masonry structures is presented. In the proposed model, unreinforced masonry panels are modelled by means of two-dimensional discrete-elements, conceived by the authors for modelling masonry structures, whereas the reinforced concrete elements are modelled by lumped plasticity elements interacting with the masonry panels through nonlinear interface elements. The proposed procedure was adopted for the assessment of the seismic response of a case study confined-masonry building which was conceived to be a typical representative of a wide class of residential buildings designed to the requirements of the 1909 issue of the Italian seismic code and widely adopted in the aftermath of the 1908 earthquake for the reconstruction of the cities of Messina and Reggio Calabria

  2. Thioridazine Induces Major Changes in Global Gene Expression and Cell Wall Composition in Methicillin-Resistant Staphylococcus aureus USA300

    DEFF Research Database (Denmark)

    Thorsing, Mette; Klitgaard, Janne Kudsk; Atilano, Magda L.

    2013-01-01

    and the transcriptomic response of S. aureus to known inhibitors of cell wall synthesis suggests that TDZ disturbs PGN biosynthesis at a stage that precedes transpeptidation by penicillin-binding proteins (PBPs). In support of this notion, dramatic changes in the muropeptide profile of USA300 were observed following....... In the present study, we have examined the effect of a subinhibitory concentration of TDZ on antimicrobial resistance, the global transcriptome, and the cell wall composition of MRSA USA300. We show that TDZ is able to sensitize the bacteria to several classes of antimicrobials targeting the late stages...... a major impact on the cell wall biosynthesis pathway in S. aureus and provides new insights into how MRSA may be sensitized towards β-lactam antibiotics....

  3. Creep behavior and wear resistance of Al 5083 based hybrid composites reinforced with carbon nanotubes (CNTs) and boron carbide (B{sub 4}C)

    Energy Technology Data Exchange (ETDEWEB)

    Alizadeh, Ali [Faculty of Materials & Manufacturing Processes, Malek-e-Ashtar University of Technology, Tehran (Iran, Islamic Republic of); Abdollahi, Alireza, E-mail: alirezaabdollahi1366@gmail.com [Faculty of Materials & Manufacturing Processes, Malek-e-Ashtar University of Technology, Tehran (Iran, Islamic Republic of); Biukani, Hootan [Faculty of Engineering, South Tehran Branch, Islamic Azad University, Tehran (Iran, Islamic Republic of)

    2015-11-25

    In the current research, aluminum based hybrid composite reinforced with boron carbide (B{sub 4}C) and carbon nanotubes (CNTs) was produced by powder metallurgy method. creep behavior, wear resistance, surface roughness, and hardness of the samples were investigated. To prepare the samples, Al 5083 powder was milled with boron carbide particles and carbon nanotubes using planetary ball mill under argon atmosphere with ball-to-powder weight ratio of 10:1 for 5 h. Afterwards, the milled powders were formed by hot press process at 380{sup °}C and then were sintered at 585{sup °}C under argon atmosphere for 2 h. There was shown to be an increase in hardness values of composite with an increase in B{sub 4}C content. The micrograph of worn surfaces indicate a delamination mechanism due to the presence of CNTs and abrasion mechanism in composite containing 10 vol.%B{sub 4}C. Moreover, it was shown that increasing B{sub 4}C content increases the wear resistance by 3 times under a load of 20 N and 10 times under a load of 10 N compared to CNTs-reinforced composite. surface roughness of the composite containing 5 vol.%CNT has shown to be more than other samples. The results of creep test showed that adding carbon nanotubes increases creep rate of Al 5083 alloy; however, adding B{sub 4}C decreases its creep rate. - Highlights: • Al 5083/(CNTs + B{sub 4}C) hybrid composite was produced by powder metallurgy method. • Creep behavior, wear resistance, surface roughness, and Hardness of samples were investigated. • Addition of CNTs to Al 5083 matrix reduces alloy hardness, wear resistance and creep strength. • By addition of B{sub 4}C and composite hybridization, creep strength and wear resistance increased. • Surface roughness of Al-5 vol.%CNT has shown to be more than other samples.

  4. Silk Composite with a Fluoropolymer as a Water-Resistant Protein-Based Material

    Directory of Open Access Journals (Sweden)

    Keiji Numata

    2018-04-01

    Full Text Available Silk-based materials are water-sensitive and show different physical properties at different humidities and under wet/dry conditions. To overcome the water sensitivity of silk-based materials, we developed a silk composite material with a fluoropolymer. Blending and coating the silk protein-based materials, such as films and textiles, with the fluoropolymer enhanced the surface hydrophobicity, water vapor barrier properties, and size stability during shrinkage tests. This material design with a protein biopolymer and a fluoropolymer is expected to broaden the applicability of protein-based materials.

  5. Molecular modeling of the elastomeric properties of repeating units and building blocks of resilin, a disordered elastic protein.

    Science.gov (United States)

    Khandaker, Md Shahriar K; Dudek, Daniel M; Beers, Eric P; Dillard, David A; Bevan, David R

    2016-08-01

    The mechanisms responsible for the properties of disordered elastomeric proteins are not well known. To better understand the relationship between elastomeric behavior and amino acid sequence, we investigated resilin, a disordered rubber-like protein, found in specialized regions of the cuticle of insects. Resilin of Drosophila melanogaster contains Gly-rich repetitive motifs comprised of the amino acids, PSSSYGAPGGGNGGR, which confer elastic properties to resilin. The repetitive motifs of insect resilin can be divided into smaller partially conserved building blocks: PSS, SYGAP, GGGN and GGR. Using molecular dynamics (MD) simulations, we studied the relative roles of SYGAP, and its less common variants SYSAP and TYGAP, on the elastomeric properties of resilin. Results showed that SYGAP adopts a bent structure that is one-half to one-third the end-to-end length of the other motifs having an equal number of amino acids but containing SYSAP or TYGAP substituted for SYGAP. The bent structure of SYGAP forms due to conformational freedom of glycine, and hydrogen bonding within the motif apparently plays a role in maintaining this conformation. These structural features of SYGAP result in higher extensibility compared to other motifs, which may contribute to elastic properties at the macroscopic level. Overall, the results are consistent with a role for the SYGAP building block in the elastomeric properties of these disordered proteins. What we learned from simulating the repetitive motifs of resilin may be applicable to the biology and mechanics of other elastomeric biomaterials, and may provide us the deeper understanding of their unique properties. Copyright © 2016 Elsevier Ltd. All rights reserved.

  6. Effect of inclusion of SiC particulates on the mechanical resistance behaviour of stir-cast AA6063/SiC composites

    International Nuclear Information System (INIS)

    Balasubramanian, I.; Maheswaran, R.

    2015-01-01

    Highlights: • AA6063/SiC composites with different weight percent are stir cast. • Resistance properties against indentation, stretching force and sliding force are studied. • Increase in initiation of cleavage facets and reduces the tensile strength for 15% SiC. • Transition from micro ploughing to micro cutting wear mechanism is less due to SiC inclusion. - Abstract: This study investigates the mechanical resistance behaviour of AA6063 particulate composites with the inclusion of micron-sized silicon carbide (SiC) particles with different weight percentages in an AA6063 aluminium matrix. AA6063/SiC particulate composites containing 0, 5, 10, and 15 weight percent of SiC particles were produced by stir casting. Standard mechanical tests were conducted on the composite plates, and the mechanical resistance to indentation, tensile force and sliding force are evaluated. It has been observed that upon addition of SiC particles, the resistance against indentation is increased and the resistance against tensile force is initially increased and then decreased. Furthermore, using scanning electron microscopy (SEM), the fracture appearance of the broken specimen subjected to tensile force and morphological changes in the surface subjected to sliding force are analysed. The SEM images reveal that the addition of SiC particles in the AA6063 aluminium matrix initiates more cleavage facets. This leads to brittle fracture in the specimen subjected to tensile forces and less transition from material displacement to material removal in the specimen subjected to sliding forces

  7. Nesfatin-1 in childhood and adolescent obesity and its association with food intake, body composition and insulin resistance.

    Science.gov (United States)

    Anwar, Ghada M; Yamamah, Gamal; Ibrahim, Amani; El-Lebedy, Dalia; Farid, Tarek M; Mahmoud, Rasha

    2014-01-10

    Nesfatin-1 is an anorexigenic peptide that controls feeding behavior and glucose homeostasis. However, there is little data that exists regarding nesfatin-1 secretion in obese children and young adolescents. The aim of this study is to investigate serum nesfatin-1 in childhood and adolescent obesity and to study potential correlations with food intake, anthropometric indices, body composition and insulin resistance. Forty obese children and adolescents and 40 healthy control subjects were studied. Anthropometric measurements were assessed, dietary food intake was evaluated based on 3-days food record and body composition indices were evaluated using bioelectrical impedance analysis. Lipid profile, fasting blood sugar, fasting insulin and HOMA-IR were measured. Fasting serum nesfatin-1 was quantitatively assayed by ELISA. Serum nesfatin-1 was significantly higher in obese group (2.49±1.96 ng/ml) than in control group (0.70±0.81 ng/ml), P=0.001. Positive correlations with serum insulin (P=0.001), HOMA-IR (P=0.000), BMI-SDS (P=0.04), body fat % (P=0.000), fat mass (P=0.000), fat free mass (P=0.03), CHO % (P=0.000), and saturated fat % (P=0.01) were found. While significant negative correlation with protein % (P=0.000) was observed. In conclusion, our results denote that nesfatin-1 might have an important role in regulation of food intake and pathogenesis of insulin resistance in obese children and young adolescents. Copyright © 2014 Elsevier B.V. All rights reserved.

  8. Improved corrosion resistant and mechanical behavior of distinct composite coatings (silica/titania/zirconia on Ti–6Al–4V deposited by EPD

    Directory of Open Access Journals (Sweden)

    M. Chellappa

    2017-09-01

    Full Text Available Synthesized composite powders (ZrO2/TiO2, SiO2/TiO2, and SiO2/ZrO2 were successfully deposited on Ti–6Al–4V by electrophoretic deposition method (EPD to improve its electrochemical characteristics for better biomedical applications. In the present investigation, the three composite powders were prepared by sol–gel synthesis and its phase purity was analyzed by Powder X-ray diffraction (XRD method. Further, the performance of the deposited coatings was assessed by scanning electron microscopy (SEM coupled with energy dispersive X-ray analysis (EDAX, scratch resistance test. The electrochemical properties of the composite coatings were analyzed by Potentiodynamic (Tafel polarization and electrochemical impedance spectroscopy (EIS studies. From the results, we observed that the corrosion resistance behavior of the different composite coated metallic substrate exhibited divergent corrosion resistance nature than blank Ti–6Al–4V. Of all these coatings on Ti–6Al–4V, the composite made up of, ZrO2/TiO2 has pronounced corrosion resistance behavior in Ringer’s solution when compared to others. This behavior is due to the presence of strong adherent coating owing to the existence of uniform deposition on Ti–6Al–4V.

  9. Electrical Resistivity Correlation to Vadose Zone Sediment and Pore-Water Composition for the BC Cribs and Trenches Area

    International Nuclear Information System (INIS)

    Serne, R. Jeffrey; Ward, Anderson L.; Um, Wooyong; Bjornstad, Bruce N.; Rucker, Dale F.; Lanigan, David C.; Benecke, Mark W.

    2009-01-01

    This technical report documents the results of geochemical and soil resistivity characterization of sediment obtained from four boreholes drilled in the BC Cribs and Trench area. Vadose zone sediment samples were obtained at a frequency of about every 2.5 ft from approximately 5 ft bgs to borehole total depth. In total, 505 grab samples and 39 six-inch long cores were obtained for characterization. The pore-water chemical composition data, laboratory-scale soil resistivity and other ancillary physical and hydrologic measurements and analyses described in this report are designed to provide a crucial link between direct measurements on sediments and the surface-based electrical-resistivity information obtained via field surveys. A second goal of the sediment characterization was to measure the total and water-leachable concentrations of key contaminants of concern as a function of depth and distance from the footprints of inactive disposal facilities. The total and water-leachable concentrations of key contaminants will be used to update contaminant distribution conceptual models and to provide more data for improving base-line risk predictions and remedial alternative selections. The ERC 'ground truthing' exercise for the individual boreholes showed mixed results. In general, the high concentrations of dissolved salts in the pore waters of sediments from C5923, C5924 and C4191 produced a low resistivity 'target' in the processed resistivity field surveys, and variability could be seen in the resistivity data that could relate to the variability in pore- water concentrations but the correlations (regression R2 were mediocre ranging from 0.2 to 0.7 at best; where perfect correlation is 1.0). The field-based geophysical data also seemed to suffer from a sort of vertigo, where looking down from the ground surface, the target (e.g., maximum pore-water salt concentration) depth was difficult to resolve. The best correlations between the field electrical resistivity

  10. Electrical Resistivity Correlation to Vadose Zone Sediment and Pore-Water Composition for the BC Cribs and Trenches Area

    Energy Technology Data Exchange (ETDEWEB)

    Serne, R. Jeffrey; Ward, Anderson L.; Um, Wooyong; Bjornstad, Bruce N.; Rucker, Dale F.; Lanigan, David C.; Benecke, Mark W.

    2009-06-01

    This technical report documents the results of geochemical and soil resistivity characterization of sediment obtained from four boreholes drilled in the BC Cribs and Trench area. Vadose zone sediment samples were obtained at a frequency of about every 2.5 ft from approximately 5 ft bgs to borehole total depth. In total, 505 grab samples and 39 six-inch long cores were obtained for characterization. The pore-water chemical composition data, laboratory-scale soil resistivity and other ancillary physical and hydrologic measurements and analyses described in this report are designed to provide a crucial link between direct measurements on sediments and the surface-based electrical-resistivity information obtained via field surveys. A second goal of the sediment characterization was to measure the total and water-leachable concentrations of key contaminants of concern as a function of depth and distance from the footprints of inactive disposal facilities. The total and water-leachable concentrations of key contaminants will be used to update contaminant distribution conceptual models and to provide more data for improving base-line risk predictions and remedial alternative selections. The ERC “ground truthing” exercise for the individual boreholes showed mixed results. In general, the high concentrations of dissolved salts in the pore waters of sediments from C5923, C5924 and C4191 produced a low resistivity “target” in the processed resistivity field surveys, and variability could be seen in the resistivity data that could relate to the variability in pore- water concentrations but the correlations (regression R2 were mediocre ranging from 0.2 to 0.7 at best; where perfect correlation is 1.0). The field-based geophysical data also seemed to suffer from a sort of vertigo, where looking down from the ground surface, the target (e.g., maximum pore-water salt concentration) depth was difficult to resolve. The best correlations between the field electrical

  11. Melting of corrosion-resistant steel of martensite class with given phase composition

    International Nuclear Information System (INIS)

    Grashchenkov, P.M.; Kachanov, E.B.; Stetsenko, N.V.; Moshkevich, E.I.; Bunina, T.I.

    1979-01-01

    Introduced is a melting procedure for the EhP410U (vacuum arc remelted) and VNC-2M (electroslag remelted) stainless steels with carbon (carbon ferrochrome) and nickel additions to ensure a present phase composition. Magnetizability of cold specimens of the EhP410U steel should be within the limits 17.0-19.5 mV by a special device. During melting of the second steel controlled are not only cold specimens magnetizability of which should be not less than 16 mV, but hot as well (at 25O-400 deg C) by the level of magnetizability not higher than 0.5 mV. During vacuum arc remelting nitrogen content reduces in general by 0.014% and manganese content - by 0.23%; correspondingly the magnetizability of specimens insceases approximately by 1 mV. During electroslag remelting chemical and phase composition practically are not changed. Total and diffusible hydrogen contents in the vacuum remelted steel is rather low (1-5 and 0.03-0.35 cm 3 /100 gs), which provides increased reliability of the articles

  12. Phenolic composition, antioxidant capacity of Salvia verticcilata and effect on multidrug resistant bacteria by flow-cytometry.

    Science.gov (United States)

    Tekeli, Yener; Karpuz, Esra; Danahaliloglu, Hatice; Bucak, Serbay; Guzel, Yelda; Erdmann, Helmuth

    2014-01-01

    Antioxidants are of great importance for preventing oxidative stress that may cause several degenerative diseases. Studies have indicated phytochemicals have high free-radical scavenging activity, which helps to reduce the risk of chronic diseases. The aim of the present study is the determination of antioxidant properties, polyphenolic content and multidrug resistant bacteria of Salvia verticcilata L. Methanol was used as the extraction solvent. The total phenolic content was calculated using Folin-Ciocalteau method and phenolic composition was determined by HPLC. The radical scavenging activity of plant was evaluated in vitro based on the reduction of the stable DPPH free radical. The reducing capacity was identified by using the FRAP method. The ability of Salvia verticcilata L. to increase the permeability of multidrug resistant bacterial cells was conducted by flow cytometric assay on Listeria innocua and E-coli. The amount of total phenolics was found to be 347.5 mg GA/g extract. The IC50 value and FRAP assay are 0.61, and 0.944 respectively, Free radical scavenging effect and FRAP values are less than synthetic antioxidant compounds (BHA and BHT). Eight phenolic compounds were found in Salvia verticcilata L. Intense concentration of S. verticcilata L. has destroyed 97 % of living cells for Listeria innocua and 94.86% for E-coli. This study shows that methanolic extracts of Salvia verticcilata L. is a potential source of natural antioxidants and antimicrobial agent and can form the basis for pharmacological studies.

  13. Diets high in resistent starch and arabinoxylan modulate digestion processes and SCFA pool size in the large intestine and faecal microbial composition in pigs

    DEFF Research Database (Denmark)

    Nielsen, Tina Skau; Lærke, Helle Nygaard; Theil, Peter Kappel

    2014-01-01

    The effects of a high level of dietary fibre (DF) either as arabinoxylan (AX) or resistant starch (RS) on digestion processes, SCFA concentration and pool size in various intestinal segments and on the microbial composition in the faeces were studied in a model experiment with pigs. A total...... resulted in a 3- to 5-fold higher pool size of butyrate compared with WSD feeding, with the RSD being intermediate (P microbial composition towards butyrogenic...

  14. In vitro comparative analysis of resistance to compression of laboratory resin composites and a ceramic system

    Directory of Open Access Journals (Sweden)

    Montenegro Alexandre

    2010-01-01

    Full Text Available Background: Restorative materials must be capable not only of restoring the patient′s masticatory function, but also to rescue the self-esteem of those maculated by a disharmonious smile. Among the esthetic materials available on the market, the choice frequently lies between ceramic or indirect laboratory resin restorations. Aim: This study assessed the resistance to compression of two laboratory resins found on the market, namely Artglass ® and Targis ® , considering Omega 900 ® ceramic from Vita as control. Materials and Methods: With the aid of stainless steel matrices, with internal dimensions of 8.0 mm diameter at the base, 9.0 mm in the top portion and 4.0 mm height, 15 test specimens were made, being 5 of each material to be tested. The test specimens were kept in distilled water for 72 hours and submitted to an axial load by the action of a point with a rounded tip 2 mm in diameter, adapted to an EMIC 500 universal test machine. The compression speed was 0.5 mm/min, with a load cell capacity of 200 Kgf. Results: The means of the results were calculated in kilogram-force (Kgf. The results found were treated by analysis of variance (ANOVA and the differences found among the groups were identified by the Tukey test (5%. Conclusion: It was observed that the material Omega 900 ® offered significantly greater resistance to compression than the other two materials, which did not present statistically significant difference between them.

  15. The effect of fibre layering pattern in resisting bending loads of natural fibre-based hybrid composite materials

    Directory of Open Access Journals (Sweden)

    Jusoh Muhamad Shahirul Mat

    2016-01-01

    Full Text Available The effect of fibre layering pattern and hybridization on the flexural properties of composite hybrid laminates between natural fibres of basalt, jute and flax with synthetic fibre of E-glass reinforced epoxy have been investigated experimentally. Results showed that the effect fibre layering pattern was highly significant on the flexural strength and modulus, which were strongly dependent on the hybrid configuration between sandwich-like (SL and intercalation (IC sequence of fibre layers. In addition, specific modulus based on the variation densities of the hybrid laminates was used to discover the best combination either basalt, jute or flax with E-glass exhibits superior properties concerning on the strength to weight-ratio. Generally, SL sequence of glass/basalt exhibited superior strength and stiffness compared with glass/jute and glass/flax in resisting bending loads. In terms of hybridization effect, glass/jute was found to be the best combination with E-glass compared to the rest of natural fibres investigated in the present study. Hence, the proper stacking sequences and material selection are among predominant factors that influence on mechanical properties and very crucial in designing composite hybrid system to meet the desired requirements.

  16. Corrosion resistance enhancement of Ni-P-nano SiO{sub 2} composite coatings on aluminum

    Energy Technology Data Exchange (ETDEWEB)

    Sadreddini, Sina, E-mail: sina.sadreddini1986@gmail.com [Department of Materials Science and Engineering, Science and Research Branch, Islamic Azad University, Tehran (Iran, Islamic Republic of); Afshar, Abdollah [Department of Materials Science and Engineering, Sharif university of Technology, Tehran (Iran, Islamic Republic of)

    2014-06-01

    In this study, the influences of different concentrations of SiO{sub 2} nano sized particles in the bath on deposition rate, surface morphology and corrosion behavior of Ni-P-SiO{sub 2} Composite coatings were investigated. The deposition rate of coating was influenced by incorporation of SiO{sub 2} particles. The microstructure was investigated with field emission scanning electron microscopy (FESEM). The amount of SiO{sub 2} was examined by Energy Dispersive Analysis of X-Ray (EDX) and amount of SiO{sub 2} nanoparticles co-deposited reached a maximum value at 4.5 %wt. Corrosion behavior of coated aluminum was evaluated by electrochemical impedance spectroscopy (EIS) and polarization techniques. The results illustrated that the corrosion rate decreases (6.5–0.6 μA/cm{sup 2}) and the corrosion potential increases (−0.64 to −0.3) with increasing the quantity of the SiO{sub 2} nanoparticles in the bath. Moreover, Ni-p-SiO{sub 2} nano-composite coating possesses less porosity than that in Ni-P coating, resulting in improving corrosion resistance.

  17. Magnetocaloric effect and corrosion resistance of La(Fe, Si)13 composite plates bonded by different fraction of phenolic resin

    Science.gov (United States)

    Zhang, K. S.; Xue, J. N.; Wang, Y. X.; Sun, H.; Long, Y.

    2018-04-01

    La(Fe, Si)13-based composite plates were successfully fabricated using different amount of phenolic resin. The introduction of phenolic resin as binder increased the corrosion resistance and maintained giant magnetocaloric effect for La(Fe, Si)13-based composite plates. It was found that corroded spots were firstly observed on the boundaries between resin and La(Fe, Si)13 particles, rather than in La(Fe, Si)13-based particles, after being immersed in static distilled water. The corrosion rate decreased significantly with the increase of resin content. And the increase of the content of phenolic resin leads to the reduction of corrosion current density. Meanwhile, the volumetric magnetic entropy change ΔSM decreases slightly as the content of phenolic resin increases. The ΔSM of the plates with 3 wt.%, 5 wt.% and 8 wt.% resin are 63.1, 61.2 and 59.8 mJ/cm3 K under a low magnetic field change of 1 T, respectively.

  18. Preparation of the CNC/Ag/beeswax composites for enhancing antibacterial and water resistance properties of paper.

    Science.gov (United States)

    Liu, Kai; Liang, Hunan; Nasrallah, Joseph; Chen, Lihui; Huang, Liulian; Ni, Yonghao

    2016-05-20

    An effective method of preparing composites containing inorganic (Ag) and organic (beeswax) particles was established in this study. Ag nanoparticles were first immobilized on the cellulose nanocrystals (CNC) during the reduction of AgNO3 in the presence of CNC, then mixed with beeswax by high speed stirring. Scanning transmission electron microscopy (STEM) images indicated that Ag and beeswax particles were uniformly dispersed and stable in the network structure formed by CNC. Upon coating on a paper surface, a layer of beeswax film was evident based on scanning electron microscopy (SEM) images. The dynamic contact angle and antibacterial activity tests indicated that the contact angle of coated paper reached 113.06° and the growth inhibition of Escherichia coli increased to 99.96%, respectively, at a coating amount of 21.53 g/m(2). When applied onto paper surface by coating, the CNC/Ag/beeswax composites can impact paper with antibacterial property and improved water resistance. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Effects of exercise on insulin resistance and body composition in overweight and obese women with and without polycystic ovary syndrome.

    Science.gov (United States)

    Hutchison, Samantha K; Stepto, Nigel K; Harrison, Cheryce L; Moran, Lisa J; Strauss, Boyd J; Teede, Helena J

    2011-01-01

    Polycystic ovary syndrome (PCOS) is an insulin-resistant (IR) state. Visceral fat (VF) is independently associated with IR. The objectives of the study were to explore mechanisms underpinning IR by assessing the effect of exercise training on IR and body composition in overweight PCOS and non-PCOS women. This was a prospective exercise intervention study. The study was conducted at an academic medical center. Participants included 20 overweight PCOS and 14 overweight non-PCOS women. The intervention included 12 wk of intensified aerobic exercise (3 h/wk). IR on euglycemic hyperinsulinemic clamp, body composition including abdominal visceral and sc fat distribution by computer tomography and lipids was measured. PCOS subjects were more IR (P = 0.02) and had more VF (P = 0.04 age adjusted) than non-PCOS women. In PCOS women, IR correlated with VF (r = -0.78, P cardiometabolic risk factors including IR, triglycerides, and VF in PCOS were observed without significant weight loss and if confirmed in future controlled trials, suggest weight loss should not be the sole focus of exercise programs.

  20. Development of a new composite system: fire resistant and highly structural

    Directory of Open Access Journals (Sweden)

    González, J.

    2010-06-01

    Full Text Available Infrastructure and rail sectors share two singularities in terms of materials: highly structural performance and strict fire requirements. Moreover, there is a common growing interest in both sectors: the use of organic matrix composite materials due to their high performance, lightweight and in-service behavior. Traditionally, fire fillers have been added to the matrix, decreasing its mechanical performance in a critical way. A study about composite materials formed by three different matrices and four different carbon fibers will be presented in this paper. A number of laminates have been manufactured by using these composite materials in order to analyze both the resin processing and the compatibility of the different matrices and fibers. This study is a need due to the fact that these matrices are fire-related and therefore further problems may arise in comparison with standard matrices.

    Los sectores de la construcción y del ferrocarril tienen dos aspectos en común en el ámbito de los materiales: la utilización de materiales altamente estructurales y la aplicación de estrictos requerimientos de fuego. Asimismo, en ambos sectores existe un interés creciente en el uso de materiales compuestos de matriz orgánica por sus excelentes prestaciones, ligereza y comportamiento en servicio. Tradicionalmente, se han aplicado cargas anti-fuego a la matriz orgánica, disminuyendo sus propiedades mecánicas de forma importante. En este artículo se presentará un estudio de materiales compuestos formados por tres matrices orgánicas diferentes y cuatro tipos de fibras de carbono. Con estos constituyentes se han fabricado diferentes laminados para analizar, por un lado, la procesabilidad de estas resinas, y, por otro, la compatibilidad de estas resinas con las fibras de refuerzo utilizadas. Este estudio es necesario debido a que al tratarse de resinas formuladas con características frente a fuego y humos, su fabricabilidad puede

  1. Unidirectional fibers and polyurethane elastomer matrix based composites synthesis and properties. Ph.D. Thesis

    Science.gov (United States)

    Chakar, A.

    1984-01-01

    A study of the properties and manufacturing techniques for long-fiber reinforced elastomeric composites for flexible and damping structural materials is presented. Attention is given to the usage of polyurethane in the matrix to obtain plastic elastomeric matrices and vitreous transition temperatures which vary from -80 C to 10 C, as well as assure good fiber adhesion. Various polyurethane formulations synthesized from diisocyanate prepolymers are examined in terms of mechanical and thermal properties. The principal reinforcing fiber selected is a unidirectional glass cloth.

  2. Resistance scaling for composite fermions in the presence of a density gradient

    International Nuclear Information System (INIS)

    Stormer, H. L.; Tsui, Daniel Chee; Pan, Wei; West, Ken W.; Baldwin, K. W.; Pfeiffer, Loren N.

    2006-01-01

    The magnetoresistance, R xx , at even-denominator fractional fillings, of an ultra high quality two-dimensional electron system at T ∼ 35 mK is observed to be strictly linear in magnetic field, B. While at 35 mK R xx is dominated by the integer and fractional quantum Hall states, at T ≅ 1.2 K an almost perfect linear relationship between R xx and B emerges over the whole magnetic field range except for spikes at the integer quantum Hall states. This linear R xx cannot be understood within the Composite Fermion model, but can be explained through the existence of a density gradient in our sample

  3. High-temperature Corrosion Resistance of Composite Coating Prepared by Micro-arc Oxidation Combined with Pack Cementation Aluminizing

    Directory of Open Access Journals (Sweden)

    HUANG Zu-jiang

    2018-01-01

    Full Text Available Al2O3 ceramic film was obtained by micro-arc oxidation (MAO process on Al/C103 specimen, which was prepared by pack cementation aluminizing technology on C103 niobium alloy. With the aid of XRD and SEM equipped with EDS, chemical compositions and microstructures of the composite coatings before and after high-temperature corrosion were analyzed. The behavior and mechanism of the composite coatings in high-temperature oxidation and hot corrosion were also investigated. The results indicate that oxidation mass gain at 1000℃ for 10h of the Al/C103 specimen is 6.98mg/cm2, and it is 2.89mg/cm2 of the MAO/Al/C103 specimen. However, the mass gain of MAO/Al/C103 specimen (57.52mg/cm2 is higher than that of Al/C103 specimen (28.08mg/cm2 after oxidation 20h. After hot corrosion in 75%Na2SO4 and 25%NaCl at 900℃ for 50h, the mass gain of Al/C103 and MAO/Al/C103 specimens are 70.54mg/cm2 and 55.71mg/cm2 respectively, Al2O3 and perovskite NaNbO3 phases are formed on the surface; the diffusion of molten salt is suppressed, due to part of NaNbO3 accumulated in the MAO micropores. Therefore, MAO/Al/C103 specimen exhibits better hot corrosion resistance.

  4. Mechanics of nanowire/nanotube in-surface buckling on elastomeric substrates

    Energy Technology Data Exchange (ETDEWEB)

    Xiao, J; Huang, Y [Department of Mechanical Engineering, Northwestern University, Evanston, IL 60208 (United States); Ryu, S Y; Paik, U [Division of Materials Science and Engineering, Hanyang University, 17 Hangdang-dong, Sungdong-gu, Seoul 133-791 (Korea, Republic of); Hwang, K-C [Department of Engineering Mechanics, Tsinghua University, Beijing 100084 (China); Rogers, J A, E-mail: y-huang@northwestern.edu, E-mail: jrogers@uiuc.edu [Department of Materials Science and Engineering, Frederick-Seitz Materials Research Laboratory and Beckman Institute, University of Illinois at Urbana-Champaign, Illinois 61801 (United States)

    2010-02-26

    A continuum mechanics theory is established for the in-surface buckling of one-dimensional nanomaterials on compliant substrates, such as silicon nanowires on elastomeric substrates observed in experiments. Simple analytical expressions are obtained for the buckling wavelength, amplitude and critical buckling strain in terms of the bending and tension stiffness of the nanomaterial and the substrate elastic properties. The analysis is applied to silicon nanowires, single-walled carbon nanotubes, multi-walled carbon nanotubes, and carbon nanotube bundles. For silicon nanowires, the measured buckling wavelength gives Young's modulus to be 140 GPa, which agrees well with the prior experimental studies. It is shown that the energy for in-surface buckling is lower than that for normal (out-of-surface) buckling, and is therefore energetically favorable.

  5. Mechanics of nanowire/nanotube in-surface buckling on elastomeric substrates

    International Nuclear Information System (INIS)

    Xiao, J; Huang, Y; Ryu, S Y; Paik, U; Hwang, K-C; Rogers, J A

    2010-01-01

    A continuum mechanics theory is established for the in-surface buckling of one-dimensional nanomaterials on compliant substrates, such as silicon nanowires on elastomeric substrates observed in experiments. Simple analytical expressions are obtained for the buckling wavelength, amplitude and critical buckling strain in terms of the bending and tension stiffness of the nanomaterial and the substrate elastic properties. The analysis is applied to silicon nanowires, single-walled carbon nanotubes, multi-walled carbon nanotubes, and carbon nanotube bundles. For silicon nanowires, the measured buckling wavelength gives Young's modulus to be 140 GPa, which agrees well with the prior experimental studies. It is shown that the energy for in-surface buckling is lower than that for normal (out-of-surface) buckling, and is therefore energetically favorable.

  6. Silicon micro-masonry using elastomeric stamps for three-dimensional microfabrication

    International Nuclear Information System (INIS)

    Keum, Hohyun; Eisenhaure, Jeffrey D; Kim, Seok; Carlson, Andrew; Ning, Hailong; Mihi, Agustin; Braun, Paul V; Rogers, John A

    2012-01-01

    We present a micromanufacturing method for constructing microsystems, which we term ‘micro-masonry’ based on individual manipulation, influenced by strategies for deterministic materials assembly using advanced forms of transfer printing. Analogous to masonry in construction sites, micro-masonry consists of the preparation, manipulation, and binding of microscale units to assemble microcomponents and microsystems. In this paper, for the purpose of demonstration, we used microtipped elastomeric stamps as manipulators and built three dimensional silicon microstructures. Silicon units of varied shapes were fabricated in a suspended format on donors, retrieved, delivered, and placed on a target location on a receiver using microtipped stamps. Annealing of the assembled silicon units permanently bound them and completed the micro-masonry procedure. (paper)

  7. The effect of rinsing time periods on wettability of elastomeric impression materials: in vitro study

    Directory of Open Access Journals (Sweden)

    Özlem Acar

    2016-01-01

    Full Text Available OBJECTIVE: The aim of this study was to determine whether different rinsing time periods affected the wettability of polymerized elastomeric impression materials. MATERIALS AND METHOD: Panasil Contact Plus (PCP, Panasil Contact Non-Surfactant (PCNS, Panasil Initial Contact (PIC, Express (EXP and Impregum (IMP impression materials were tested. Standardized samples were rinsed with water for 10 s, 15 s or 20 s, and the wettability was determined by contact angle measurement through an evaluation period of 60 seconds (n=7. Non-rinsed groups were used as control. Measurements were made at 5 time points (at 0, 6, 15, 30 and 60 seconds. Kruskal Wallis test and Conover’s multiple comparison tests were used for all multiple comparisons. Bonferroni adjustment was applied for controlling Type I error (p0.002. CONCLUSION: Rinsing the surfactant-containing polyvinylsiloxane impression materials decreased their wettability, whereas no such effect was seen for the surfactant free polyvinylsiloxane and polyether impression materials.

  8. Tribaloy intermetallic alloy compositions: new materials or additives for wear resistant applications

    International Nuclear Information System (INIS)

    Cameron, C.B.; Hoffman, R.A.; Poskitt, R.W.

    1975-01-01

    Properties and uses of TRIBALOY alloys in powder metallurgy fabrication are discussed. Powders of TRIBALOY can be blended with essentially any powder processed by powder metallurgy. Green strength of the blended powder parts is reduced as the amount of TRIBALOY is increased. The concentration of TRIBALOY, however, is usually 15 to 20 volume percent, a compromise between green strength and effectiveness as a wear resistant part. Blended powders are sintered at the temperature normally used for the base metal with special consideration given to a low dew point in the atmosphere. The sintered parts can be coined, carburized, machined, or impregnated in any of the well-known ways. TRIBALOY as a powder blending agent has extended the useful life of P/M parts by factors of 5 and more. A variety of industries are presently using P/M parts at higher temperatures, heavier loads, in poorer or non-lubricated conditions or at higher speeds because of the addition of TRIBALOY. More important, however, is that TRIBALOY can be incorporated in parts to be made by powder metallurgy which until now had not been feasible. The overall effect has been considerable savings for the customer by switching to the powder metal method of manufacturing and increased activity for the fabricator

  9. Resistência adesiva de resinas compostas à dentina Adhesive strength between composite resin and dentin substract

    Directory of Open Access Journals (Sweden)

    Joel BIANCHI

    1999-01-01

    Full Text Available As pesquisas relacionadas com adesão à dentina, em virtude da ampla aplicabilidade, são de grande interesse para a Odontologia. O objetivo deste estudo foi avaliar, através de ensaios de tração, a resistência adesiva ao substrato dentinário, em função de dois sistemas adesivos (3M e Kerr, dois níveis de rugosidade do substrato dentinário (lixas 220 e 600, duas áreas de colagem (3,14 mm2 - 12,56 mm2, e duas condições de armazenagem (inicial e final. A análise dos resultados evidenciou que: 1 houve diferença estatisticamente significativa entre os dois sistemas adesivos, sendo que o da Kerr apresentou os valores mais elevados de resistência adesiva; 2 diferenças significativas não ficaram evidentes na resistência da adesão entre os dois níveis de rugosidade dentinária; 3 as colagens em áreas menores apresentaram, em nível altamente significativo, maior resistência adesiva; 4 a condição de armazenagem influiu nos resultados dependendo da área e do sistema adesivo.There is a wealthy literature on bonding strength of composites to dentine. One of the reasons for the large number of studies is the continuous introduction of new bonding agents in combination with accumulated knowledge about the dentine substrate conditions. The aim of the present study was to compare the "in vitro" tensile bond strengths of two dentine bonding systems (3M and Kerr applied to different dentine roughness (220 and 600 gritand two sizes of bonding areas (3,14 mm2 and 12,56 mm2. Different storage conditions (initial and final were also considered. One hundred and sixty human teeth were randomly allocated in 4 groups. The Kerr system groups and the smallest bonding area groups showed the highest tensile strengths. The storage condition and the substrate roughness did not display a significant influence on bond strengths.

  10. Utilizing stretch-tunable thermochromic elastomeric opal films as novel reversible switchable photonic materials.

    Science.gov (United States)

    Schäfer, Christian G; Lederle, Christina; Zentel, Kristina; Stühn, Bernd; Gallei, Markus

    2014-11-01

    In this work, the preparation of highly thermoresponsive and fully reversible stretch-tunable elastomeric opal films featuring switchable structural colors is reported. Novel particle architectures based on poly(diethylene glycol methylether methacrylate-co-ethyl acrylate) (PDEGMEMA-co-PEA) as shell polymer are synthesized via seeded and stepwise emulsion polymerization protocols. The use of DEGMEMA as comonomer and herein established synthetic strategies leads to monodisperse soft shell particles, which can be directly processed to opal films by using the feasible melt-shear organization technique. Subsequent UV crosslinking strategies open access to mechanically stable and homogeneous elastomeric opal films. The structural colors of the opal films feature mechano- and thermoresponsiveness, which is found to be fully reversible. Optical characterization shows that the combination of both stimuli provokes a photonic bandgap shift of more than 50 nm from 560 nm in the stretched state to 611 nm in the fully swollen state. In addition, versatile colorful patterns onto the colloidal crystal structure are produced by spatial UV-induced crosslinking by using a photomask. This facile approach enables the generation of spatially cross-linked switchable opal films with fascinating optical properties. Herein described strategies for the preparation of PDEGMEMA-containing colloidal architectures, application of the melt-shear ordering technique, and patterned crosslinking of the final opal films open access to novel stimuli-responsive colloidal crystal films, which are expected to be promising materials in the field of security and sensing applications. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Three-Dimensional Elastomeric Scaffolds Designed with Cardiac-Mimetic Structural and Mechanical Features

    Science.gov (United States)

    Neal, Rebekah A.; Jean, Aurélie; Park, Hyoungshin; Wu, Patrick B.; Hsiao, James; Engelmayr, George C.; Langer, Robert

    2013-01-01

    Tissue-engineered constructs, at the interface of material science, biology, engineering, and medicine, have the capacity to improve outcomes for cardiac patients by providing living cells and degradable biomaterials that can regenerate the native myocardium. With an ultimate goal of both delivering cells and providing mechanical support to the healing heart, we designed three-dimensional (3D) elastomeric scaffolds with (1) stiffnesses and anisotropy mimicking explanted myocardial specimens as predicted by finite-element (FE) modeling, (2) systematically varied combinations of rectangular pore pattern, pore aspect ratio, and strut width, and (3) structural features approaching tissue scale. Based on predicted mechanical properties, three scaffold designs were selected from eight candidates for fabrication from poly(glycerol sebacate) by micromolding from silicon wafers. Large 20×20 mm scaffolds with high aspect ratio features (5:1 strut height:strut width) were reproducibly cast, cured, and demolded at a relatively high throughput. Empirically measured mechanical properties demonstrated that scaffolds were cardiac mimetic and validated FE model predictions. Two-layered scaffolds providing fully interconnected pore networks were fabricated by layer-by-layer assembly. C2C12 myoblasts cultured on one-layered scaffolds exhibited specific patterns of cell elongation and interconnectivity that appeared to be guided by the scaffold pore pattern. Neonatal rat heart cells cultured on two-layered scaffolds for 1 week were contractile, both spontaneously and in response to electrical stimulation, and expressed sarcomeric α-actinin, a cardiac biomarker. This work not only demonstrated several scaffold designs that promoted functional assembly of rat heart cells, but also provided the foundation for further computational and empirical investigations of 3D elastomeric scaffolds for cardiac tissue engineering. PMID:23190320

  12. Wear-resistant EBW coatings based on a TiB{sub 2}-Fe SHS composite with a high-alloy matrix

    Energy Technology Data Exchange (ETDEWEB)

    Galchenko, Nina K.; Kolesnikova, Ksenia A.; Belyuk, Sergei I. [Institute of Strength Physics and Materials Science SB RAS, Tomsk (Russian Federation); Semenov, Grigoriy V., E-mail: Kolesnikova_KsAl@mail.ru [Tomsky Instrument Manufacturing Company, Tomsk (Russian Federation)

    2011-07-01

    In the work, we studied the structure and properties of “titanium diboride – high-chromium cast iron binder” coatings obtained by electron beam welding. It is demonstrated that the phase and structure formation of the composite coatings depends on the content of high-chromium cast iron in the deposited mixture. Varying the volume fraction of the hardening compounds and the chemical composition of the metal binder makes possible wear-resistant coatings with specified operating characteristics. Key words: electron beam technology, composite coatings.

  13. Fracture resistance of endodontically treated teeth restored with short fiber composite used as a core material-An in vitro study.

    Science.gov (United States)

    Garlapati, Tejesh Gupta; Krithikadatta, Jogikalmat; Natanasabapathy, Velmurugan

    2017-10-01

    This in-vitro study tested the fracture resistance of endodontically treated molars with Mesial-Occluso-Distal (MOD) cavities restored with fibre reinforced composite material everX posterior in comparision with hybrid composite and ribbond fiber composite. Fifty intact freshly extracted human mandibular first molars were collected and were randomly divided into five groups (n=10). Group 1: positive control (PC) intact teeth without any endodontic preparation. In groups 2 through 6 after endodontic procedure standard MOD cavities were prepared and restored with their respective core materials as follows: group 2, negative control (NC) left unrestored or temporary flling was applied. Group 3, Hybrid composite (HC) as a core material (Te-Econom Plus Ivoclar Vivadent Asia) group 4, Ribbond (Ribbond; Seattle, WA, USA)+conventional composite resin (RCR) group 5, everX posterior (everX Posterior GC EUROPE)+conventional composite resin (EXP) after thermocycling fracture resistance for the samples were tested using universal testing machine. The results were analysed using ANOVA and Tukey's HSD post hoc tests. Mean fracture resistance (in Newton, N) was group 1: 1568.4±221.71N, group 2: 891.0±50.107N, group 3: 1418.3±168.71N, group 4:1716.7±199.51N and group 5: 1994.8±254.195N. Among the materials tested, endodontically treated teeth restored with everX posterior fiber reinforced composite showed superior fracture resistance. Copyright © 2017 Japan Prosthodontic Society. Published by Elsevier Ltd. All rights reserved.

  14. D-aspartic acid supplementation combined with 28 days of heavy resistance training has no effect on body composition, muscle strength, and serum hormones associated with the hypothalamo-pituitary-gonadal axis in resistance-trained men.

    Science.gov (United States)

    Willoughby, Darryn S; Leutholtz, Brian

    2013-10-01

    It was hypothesized that D-aspartic acid (D-ASP) supplementation would not increase endogenous testosterone levels or improve muscular performance associated with resistance training. Therefore, body composition, muscle strength, and serum hormone levels associated with the hypothalamo-pituitary-gonadal axis were studied after 28 days of resistance training and D-ASP supplementation. Resistance-trained men resistance trained 4 times/wk for 28 days while orally ingesting either 3 g of placebo or 3 g of D-ASP. Data were analyzed with 2 × 2 analysis of variance (P aspartate oxidase (DDO) were determined. Body composition and muscle strength were significantly increased in both groups in response to resistance training (P .05). Total and free testosterone, luteinizing hormone, gonadotropin-releasing hormone, and estradiol were unchanged with resistance training and D-ASP supplementation (P > .05). For serum D-ASP and DDO, D-ASP resulted in a slight increase compared with baseline levels (P > .05). For the D-ASP group, the levels of serum DDO were significantly increased compared with placebo (P < .05). The gonadal hormones were unaffected by 28 days of D-ASP supplementation and not associated with the observed increases in muscle strength and mass. Therefore, at the dose provided, D-ASP supplementation is ineffective in up-regulating the activity of the hypothalamo-pituitary-gonadal axis and has no anabolic or ergogenic effects in skeletal muscle. © 2013 Elsevier Inc. All rights reserved.

  15. Redox Control of Aphid Resistance through Altered Cell Wall Composition and Nutritional Quality.

    Science.gov (United States)

    Rasool, Brwa; McGowan, Jack; Pastok, Daria; Marcus, Sue E; Morris, Jenny A; Verrall, Susan R; Hedley, Peter E; Hancock, Robert D; Foyer, Christine H

    2017-09-01

    The mechanisms underpinning plant perception of phloem-feeding insects, particularly aphids, remain poorly characterized. Therefore, the role of apoplastic redox state in controlling aphid infestation was explored using transgenic tobacco ( Nicotiana tabacum ) plants that have either high (PAO) or low (TAO) ascorbate oxidase (AO) activities relative to the wild type. Only a small number of leaf transcripts and metabolites were changed in response to genotype, and cell wall composition was largely unaffected. Aphid fecundity was decreased significantly in TAO plants compared with other lines. Leaf sugar levels were increased and maximum extractable AO activities were decreased in response to aphids in all genotypes. Transcripts encoding the Respiratory Burst Oxidase Homolog F, signaling components involved in ethylene and other hormone-mediated pathways, photosynthetic electron transport components, sugar, amino acid, and cell wall metabolism, were increased significantly in the TAO plants in response to aphid perception relative to other lines. The levels of galactosylated xyloglucan were decreased significantly in response to aphid feeding in all the lines, the effect being the least in the TAO plants. Similarly, all lines exhibited increases in tightly bound (1→4)-β-galactan. Taken together, these findings identify AO-dependent mechanisms that limit aphid infestation. © 2017 American Society of Plant Biologists. All Rights Reserved.

  16. Pressure resistance of copper benzene-1,3,5-tricarboxylate - carbon aerogel composites

    Science.gov (United States)

    Domán, Andrea; Nagy, Balázs; Nichele, Laura P.; Srankó, Dávid; Madarász, János; László, Krisztina

    2018-03-01

    The protective effect of a resorcinol - formaldehyde based carbon aerogel (CA) support was compared in two different forms of the hybrid made of copper benzene-1,3,5-tricarboxilate (HKUST-1) and CA. HKUST-1:CA with identical mass ratio (1:1). HKUST-1+CAis a physical mixture while in HKUST-1@CA the metal organic framework (MOF) crystals were grown on CA under solvothermal conditions. The effect of water vapour and the external pressure (25-200 bar) was investigated. TG/DTG data show that the prehistory of the samples has a strong influence on their thermal behaviour and nitrogen data suggest that part of the MOF grows in the wider pores of the HKUST-1@CA sample. Although there are no dramatic differences in the water adsorption isotherms, the physical mixture is slightly more proficient. In dry samples under compression the crystalline structure of the free HKUST-1 is well conserved. The nanoscale structure of the hybrids is sensitive to applied pressure and formation of mesopores of wide size distribution occurs. No significant difference was found between the corresponding CH4 adsorption isotherms of the composite samples, either in the as-prepared samples or after compression at 100 bar. After being exposed to high external pressure the CH4 uptake seems to be governed by the MOF.

  17. Fatigue resistance, debonding force, and failure type of fiber-reinforced composite, polyethylene ribbon-reinforced, and braided stainless steel wire lingual retainers in vitro

    NARCIS (Netherlands)

    Foek, Dave Lie Sam; Yetkiner, Enver; Ozcan, Mutlu

    Objective: To analyze the fatigue resistance, debonding force, and failure type of fiber-reinforced composite, polyethylene ribbon-reinforced, and braided stainless steel wire lingual retainers in vitro. Methods: Roots of human mandibular central incisors were covered with silicone, mimicking the

  18. Mechanical property characterization and impact resistance of selected graphite/PEEK composite materials

    Science.gov (United States)

    Baker, Donald J.

    1994-01-01

    To use graphite polyetheretherketone (PEEK) material on highly curved surfaces requires that the material be drapable and easily conformable to the surface. This paper presents the mechanical property characterization and impact resistance results for laminates made from two types of graphite/PEEK materials that will conform to a curved surface. These laminates were made from two different material forms. These forms are: (1) a fabric where each yarn is a co-mingled Celion G30-500 3K graphite fiber and PEEK thermoplastic fiber; and (2) an interleaved material of Celion G30-500 3K graphite fabric interleaved with PEEK thermoplastic film. The experimental results from the fabric laminates are compared with results for laminates made from AS4/PEEK unidirectional tape. The results indicate that the tension and compression moduli for quasi-isotropic and orthotropic laminates made from fabric materials are at least 79 percent of the modulus of equivalent laminates made from tape material. The strength of fabric material laminates is at least 80 percent of laminates made from tape material. The evaluation of fabric material for shear stiffness indicates that a tape material laminate could be replaced by a fabric material laminate and still maintain 89 percent of the shear stiffness of the tape material laminate. The notched quasi-isotropic compression panel failure strength is 42 to 46 percent of the unnotched quasi-isotropic laminate strength. Damage area after impact with 20 ft-lbs of impact energy is larger for the co-mingled panels than for the interleaved panels. The inerleaved panels have less damage than panels made from tape material. Residual compression strength of quasi-isotropic panels after impact of 20 ft-lbs of energy varies between 33 percent of the undamaged quasi-isotropic material strength for the tape material and 38 percent of the undamaged quasi-isotropic material strength for the co-mingled fabric material.

  19. Composite piping: basic materials, manufacturing methods, hydrolysis resistance. Bibliographical data and state of the art; Tuyauteries composites: materiaux de base, methodes de fabrication, resistance a l`hydrolyse. Donnees bibliographiques et etat de l`art

    Energy Technology Data Exchange (ETDEWEB)

    Pays, M.F.

    1997-10-01

    EDF has decided to replace traditional materials by glass reinforced plastic for the manufacture of certain PWR water piping. However, these are liable to in-service degradation through the hydrolysis of the operating conditions which can involve mechanical stresses or specific temperature and humidity conditions. These resins have been the subject of bibliographical surveys and laboratory experiments providing the following main results: the water diffusion in the selected thermoset resins (polyester, vinyl-ester, epoxy) can reach one percent in weight, according to the relative humidity and temperature; the water absorption is a reversible phenomenon, at the beginning and is followed by hydrolysis, an irreversible deterioration affecting the chemical functions of the polymeric chain. Thermally activated, the reaction limits the temperature for the use of these resins; polyester resins are made of a large number of ester bonds and are highly sensitive to hydrolysis. These resins can be classified on the basis of the alcohol and acid which they come acid. A possible hydrolytic degradation does not prevent from using these resins in humid environments. The cooling towers in Belleville, Nogent ad Chooz are equipped with water collecting channels made of polyester laminates which have behaved satisfactorily since their installation in 1982. In acid environments, even concentrated, resins have a better behavior than in a neutral medium. However, they can be liable to stress corrosion. Polyester resins ar not suitable for use in concentrated base media. Vinyl-ester resins are more appropriate for this purpose, although their resistance will be lower than in a neutral environment. When resins are used as a matrix for composites, the presence of glass fibers modifies their behavior. The physico-chemical protection of the fiber/matrix interfaces and of the surface of the glass itself through the sizing of the fibers plays key role in the durability of the composites, which

  20. Development of the composition of chocolate mass that resistant to bloom

    Directory of Open Access Journals (Sweden)

    M. E. Tkeshelashvili

    2017-01-01

    Full Text Available Chocolate or used as a coating on the surface of the sweets chocolate mass when exposed to a temperature drop and/or a drop in the humidity of the environment, change color, lose gloss and acquire an unwanted grayish-white surface. The loss of the appearance of chocolate – the effect of bloom is the reason for the return of products from the trading network causing highly tangible the economic damage to the producers. In this connection, experimental researches devoted to the problem of preventing bloom and developing consist of chocolate masses preclusion to bloom appear to be an urgent task. The purpose of the research is develop consist of chocolate and covering chocolate resistant to bloom. The work is performed at the Scientific research institute of «Applied research of innovative technologies and food quality» of Plekhanov Russian University of Economics. For an investigation, samples of chocolate and covering chocolate based on cocoa butter were made in the formulation of which an additive including milk fat/isomalt/polydextrose. The control samples were dark chocolate and covering chocolate prepared according to a unified formula. For the formation of blooming, the samples were exposed to temperature fluctuations and relative humidity. The measurement of the color of chocolate is implementation by an instrumental method based on the analysis of the optical characteristics of the product. The coefficients of reflection spectra of samples of chocolate were converted into color coordinates of space CIEL ? a ? b* 1976. The emergence of a bloom of chocolate by changing the parameter lightness L ? (CIEL ? a ? b* was diagnosed. The effect of introducing an additive, including milk fat/isomalt/polydextrose on fat and sugar bloom, was determined in the formulation of chocolate masses. Based on research the consist of the chocolate mass has been developed which practically does not change the taste of the finished chocolate products

  1. High-temperature fracture and fatigue resistance of a ductile β-TiNb reinforced γ-TiAl intermetallic composite

    International Nuclear Information System (INIS)

    Rao, K.T.V.; Ritchie, R.O.

    1998-01-01

    The high-temperature fatigue-crack propagation and fracture resistance of a model γ-TiAl intermetallic composite reinforced with 20 vol. % ductile β-TiNb particles is examined at elevated temperatures of 650 and 800 C and compared with behavior at room temperature. TiNb reinforcements are found to enhance the fracture toughness of γ-TiAl, even at high temperatures, from about 123 to ∼40 MPa m 1/2 , although their effectiveness is lower compared to room temperature due to the reduction in strength of TiNb particles. Under monotonic loading, crack-growth response in the composite is characterized by resistance-curve behavior arising from crack trapping, renucleation and resultant crack bridging effects attributable to the presence of TiNb particles. In addition, crack-tip blunting associated with plasticity increases the crack-initiation (matrix) toughness of the composite, particularly at 800 C, above the ductile-to-brittle transition temperature (DBTT) for γ-TiAl. High-temperature fatigue-crack growth resistance, however, is marginally degraded by the addition of TiNb particles in the C-R (edge) orientation, similar to observations made at room temperature; premature fatigue failure of TiNb ligaments in the crack wake diminishes the role of bridging under cyclic loading. Both fatigue and fracture resistance of the composite are slightly lower at 650 C (just below the DBTT for TiAl) compared to the behavior at ambient and 800 C. Overall, the beneficial effect of adding ductile TiNb reinforcements to enhance the room-temperature fracture and fatigue resistance of γ-TiAl alloys is retained up to 800 C, in air environments. There is concern, however, regarding the long-term environmental stability of these composite microstructures in unprotected atmospheres

  2. Associations of Low-Intensity Resistance Training with Body Composition and Lipid Profile in Obese Patients with Type 2 Diabetes.

    Science.gov (United States)

    Hamasaki, Hidetaka; Kawashima, Yu; Tamada, Yoshiki; Furuta, Masashi; Katsuyama, Hisayuki; Sako, Akahito; Yanai, Hidekatsu

    2015-01-01

    Resistance training to increase muscle mass and functional capacity is an integral part of diet and exercise programs for the management of obesity and type 2 diabetes. Low-intensity resistance training with slow movement and tonic force generation (LST) may be a practical and safe regimen for elderly obese individuals but the health benefits are uncertain. This study investigated the effects of LST on body composition and metabolic parameters in obese patients with type 2 diabetes. Twenty-six obese patients with type 2 diabetes engaged in LST training during hospitalization and were advised to maintain this regimen for 12 weeks after discharge. We compared lipid profile, arterial stiffness, and body composition before and after LST training. After 12 weeks of LST training, the ratio of lower extremity muscle mass to body weight increased significantly (0.176 ± 0.028 to 0.184 ± 0.023, mean ± SD), while body fat mass and body fat percentage decreased significantly (36.2 ± 10.9 kg to 34.3 ± 9.4 kg and 41.2 ± 8.6% to 40.1 ± 7.7%, respectively). Moreover, high-density lipoprotein cholesterol was significantly increased (42.2 ± 14 mg/dl to 46.3 ± 12.4 mg/dl) and both free fatty acids and lipoprotein(a) were decreased (665.2 ± 212.1 μEq/l to 525.4 ± 231.3 μEq/l and 15.4 ± 18 mg/dl to 13.8 ± 18 mg/dl, respectively). No significant change was observed in arterial stiffness. Although this study was a non-controlled investigation and some confounding factors including dietary intake, medication and compliance with training might affect the study result, a brief (12-week) LST training program may be a safe and effective strategy for the management of obesity and type 2 diabetes.

  3. Associations of Low-Intensity Resistance Training with Body Composition and Lipid Profile in Obese Patients with Type 2 Diabetes.

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    Hidetaka Hamasaki

    Full Text Available Resistance training to increase muscle mass and functional capacity is an integral part of diet and exercise programs for the management of obesity and type 2 diabetes. Low-intensity resistance training with slow movement and tonic force generation (LST may be a practical and safe regimen for elderly obese individuals but the health benefits are uncertain. This study investigated the effects of LST on body composition and metabolic parameters in obese patients with type 2 diabetes. Twenty-six obese patients with type 2 diabetes engaged in LST training during hospitalization and were advised to maintain this regimen for 12 weeks after discharge. We compared lipid profile, arterial stiffness, and body composition before and after LST training. After 12 weeks of LST training, the ratio of lower extremity muscle mass to body weight increased significantly (0.176 ± 0.028 to 0.184 ± 0.023, mean ± SD, while body fat mass and body fat percentage decreased significantly (36.2 ± 10.9 kg to 34.3 ± 9.4 kg and 41.2 ± 8.6% to 40.1 ± 7.7%, respectively. Moreover, high-density lipoprotein cholesterol was significantly increased (42.2 ± 14 mg/dl to 46.3 ± 12.4 mg/dl and both free fatty acids and lipoprotein(a were decreased (665.2 ± 212.1 μEq/l to 525.4 ± 231.3 μEq/l and 15.4 ± 18 mg/dl to 13.8 ± 18 mg/dl, respectively. No significant change was observed in arterial stiffness. Although this study was a non-controlled investigation and some confounding factors including dietary intake, medication and compliance with training might affect the study result, a brief (12-week LST training program may be a safe and effective strategy for the management of obesity and type 2 diabetes.

  4. The effect of 8 weeks of Circuit Resistance Training on metabolic syndrome risk factors and body composition in women over age 50 with diabetes mellitus type 2

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    Seyede Amene Azarmehr

    2017-10-01

    Full Text Available Abstract Introduction: The prevalence of type 2 diabetes mellitus (T2DM increased significantly in the last three decades, and effective strategies to manage and prevent this disease are urgently needed. Physical activity and exercise training is an effective way for metabolic syndrome risk factors in type 2 diabetes mellitus (T2DM patients. However, the effects of Circuit Resistance Training (CRT program on patients T2DM are unknown. The purpose of this study is to investigation the effect of 8 weeks of Circuit resistance training (CRT on metabolic syndrome and body composition in women over age 50 with T2DM. Methods: Twenty women over 50 years old with diabetes Referred to diabetes Center of 17 Shahrivar hospital in Amol and they were divided randomly into two groups; Circuit resistance (n=10 and Control (n=10. Resistance training consisted of 10 stations for 8 weeks and 3 sessions per week (Intensity 60-80% 1RM. Levels of Lipid profile and body composition before and after eight weeks training in both groups were measured. Statistical analysis of the data was carried out by SPSS (v. 22. Results Fasting Blood Sugar (FBS levels (P=0.021, Triglycerides (0.010, high-density lipoprotein cholesterol (0.042, significant decreased in CRT. Also after 8 weeks circuit resistance training, BMI (P= 0.003, WHR (P=0.004 and body fat present (0.019 significant decreased in CRT. Conclusion: According to our results, CRT was an effective approach to improve the Anthropometrics, FBS, lipid profile in women over age 50 with diabetes mellitus type 2. Moreover, CRT did have influence on LDL level.  Keywords: Circuit resistance training, insulin resistance, metabolic syndrome, body composition

  5. Influence of temperature and composition in the mechanical resistance and porosity of ceramic pieces

    Directory of Open Access Journals (Sweden)

    Jordán Vidal, M. M.

    2001-03-01

    Full Text Available We have tried to establish a relationship between the raw material and the mechanical properties of ceramic pieces subjected to different firing processes, so under the determinant of the thermal process we have done a follow up on the petrogenetic process that the manufacture of ceramics represents. This is evaluated in terms of the mechanical behaviour of the ceramic tile bodies, which have been normalised and submitted to tests for flexion. The principal objective is to be able to indicate what the optimum firing temperature for each sample is, and to determine what it is in the ceramic body which offers the greatest resistance when a specific force is applied. The study of the texture of the ceramic body will be considered mainly in relation to the existent porosity, as well as its distribution, which conditions its characteristics and specifications. The relation between porosity and the parameters that describe the porous texture of the ceramic tile pieces studied is complicated because of the fact that these have many pores with a complex and irregular spatial disposition, with a broad distribution of forms and sizes, and as such they do not fit into established empirical equations.

    Se ha tratado de establecer la relación entre materia prima y propiedades mecánicas de piezas cerámicas sometidas a procesos de cocción diversos. Bajo el condicionante del proceso térmico se realiza un seguimiento del proceso petrogenético que representa la fabricación cerámica y se evalúa a través del comportamiento mecánico de probetas cerámicas normalizadas y sometidas a ensayos de flexión. El objetivo principal es poder indicar cuál es la temperatura óptima de cocción para cada muestra y determinar cuál es aquélla en que la probeta cerámica ofrece una mayor resistencia al aplicarle una determinada carga. El estudio de la textura de la matriz cerámica es de gran interés en relación con la porosidad, asi como su distribuci

  6. Influence of elastomeric seal plate surface chemistry on interface integrity in biofouling-prone systems: Evaluation of a hydrophobic "easy-release" silicone-epoxy coating for maintaining water seal integrity of a sliding neoprene/steel interface

    Science.gov (United States)

    Andolina, Vincent L.

    The scientific hypothesis of this work is that modulation of the properties of hard materials to exhibit abrasion-reducing and low-energy surfaces will extend the functional lifetimes of elastomeric seals pressed against them in abrasive underwater systems. The initial motivation of this work was to correct a problem noted in the leaking of seals at major hydropower generating facilities subject to fouling by abrasive zebra mussel shells and extensive corrosion. Similar biofouling-influenced problems can develop at seals in medical devices and appliances from regulators in anesthetic machines and SCUBA diving oxygen supply units to autoclave door seals, injection syringe gaskets, medical pumps, drug delivery components, and feeding devices, as well as in food handling equipment like pasteurizers and transfer lines. Maritime and many other heavy industrial seal interfaces could also benefit from this coating system. Little prior work has been done to elucidate the relationship of seal plate surface properties to the friction and wear of elastomeric seals during sliding contacts of these articulating materials, or to examine the secondary influence of mineralized debris within the contacting interfaces. This investigation utilized the seal materials relevant to the hydropower application---neoprene elastomer against carbon steel---with and without the application of a silicone-epoxy coating (WearlonRTM 2020.98) selected for its wear-resistance, hydrophobicity, and "easy-release" capabilities against biological fouling debris present in actual field use. Analytical techniques applied to these materials before and after wear-producing processes included comprehensive Contact Angle measurements for Critical Surface Tension (CA-CST) determination, Scanning Electron Microscopic inspections, together with Energy Dispersive X-ray Spectroscopy (SEM-EDS) and X-Ray Fluorescence (XRF) measurements for determination of surface texture and inorganic composition, Multiple

  7. Utilization of the UV laser with picosecond pulses for the formation of surface microstructures on elastomeric plastics

    Science.gov (United States)

    Antoszewski, B.; Tofil, S.; Scendo, M.; Tarelnik, W.

    2017-08-01

    Elastomeric plastics belong to a wide range of polymeric materials with special properties. They are used as construction material for seals and other components in many branches of industry and, in particular, in the biomedical industry, mechatronics, electronics and chemical equipment. The micromachining of surfaces of these materials can be used to build micro-flow, insulating, dispensing systems and chemical and biological reactors. The paper presents results of research on the effects of micro-machining of selected elastomeric plastics using a UV laser emitting picosecond pulses. The authors see the prospective application of the developed technology in the sealing technique in particular to shaping the sealing pieces co-operating with the surface of the element. The result of the study is meant to show parameters of the UV laser’s performance when producing typical components such as grooves, recesses for optimum ablation in terms of quality and productivity.

  8. The effect of a lidocaine/prilocaine topical anesthetic on pain and discomfort associated with orthodontic elastomeric separator placement

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    M. Abu Al-Melh

    2017-01-01

    Full Text Available Abstract Background The initial placement of orthodontic elastomeric separators can be uncomfortable and painful. Therefore, it is important to relieve this disturbing sensation to create a discomfort or pain-free orthodontic visit. The purpose of this study was to investigate the effect of a lidocaine/prilocaine topical anesthetic on pain and discomfort associated with the placement of orthodontic elastomeric separators. Methods Fifty subjects aging between 20–35 years were included in this study. In the maxillary arch, a lidocaine/prilocaine topical anesthetic was placed around the ginigval margins of the premolar and molar on side. On the other side, a placebo agent was placed around the ginigval margins of the premolar and molar. After two minutes, an elastomeric separator was placed between the premolar and molar on both sides. The subjects were then asked to report their findings on a Verbal Scale and a Visual Analogue Scale every second minute for a period of 10 min. The subjects were also given a questionnaire to evaluate the overall impression on the topical anesthetic use. Results The overall mean discomfort/pain score was found to be significantly lower (p < 0.001 with the topical anesthetic than with the placebo. Repeated measures ANOVA with a Greenhouse-Geisser correction determined that mean pain scores were statistically significantly low with the 10-min time duration (F (1.54,42.2 = 40.7, p = 0.001, with an estimated grand mean (8.37, 95% CI 6.75–9.98. The questionnaire responses revealed that 87% of the subjects reported an overall satisfaction and agreement with the topical anesthetic than with the placebo or no difference (13% after the initial separator placement. Conclusions The discomfort and pain resulting from the initial placement of orthodontic elastomeric separators can be significantly reduced with the lidocaine/prilocaine topical anesthetic.

  9. Metagenomic analysis of bacterial community composition and antibiotic resistance genes in a wastewater treatment plant and its receiving surface water.

    Science.gov (United States)

    Tang, Junying; Bu, Yuanqing; Zhang, Xu-Xiang; Huang, Kailong; He, Xiwei; Ye, Lin; Shan, Zhengjun; Ren, Hongqiang

    2016-10-01

    The presence of pathogenic bacteria and the dissemination of antibiotic resistance genes (ARGs) may pose big risks to the rivers that receive the effluent from municipal wastewater treatment plants (WWTPs). In this study, we investigated the changes of bacterial community and ARGs along treatment processes of one WWTP, and examined the effects of the effluent discharge on the bacterial community and ARGs in the receiving river. Pyrosequencing was applied to reveal bacterial community composition including potential bacterial pathogen, and Illumina high-throughput sequencing was used for profiling ARGs. The results showed that the WWTP had good removal efficiency on potential pathogenic bacteria (especially Arcobacter butzleri) and ARGs. Moreover, the bacterial communities of downstream and upstream of the river showed no significant difference. However, the increase in the abundance of potential pathogens and ARGs at effluent outfall was observed, indicating that WWTP effluent might contribute to the dissemination of potential pathogenic bacteria and ARGs in the receiving river. Copyright © 2016 Elsevier Inc. All rights reserved.

  10. Microstructure and Wear Resistance of Composite Coating by Laser Cladding Al/TiN on the Ti-6Al-4V Substrate

    Science.gov (United States)

    Zhang, H. X.; Yu, H. J.; Chen, C. Z.

    2015-05-01

    The composite coatings were fabricated by laser cladding Al/TiN pre-placed powders on Ti-6Al-4V substrate for enhancing wear resistance and hardness of the substrate. The composite coatings were analyzed by means of X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive spectrometer (EDS). The sliding wear tests were performed by MM200 wear test machine. The hardness of the coatings was tested by HV-1000 hardness tester. After laser cladding, it was found that there was a good metallurgical bond between the coating and the substrate. The composite coatings were mainly composed of the matrix of β-Ti (Al) and the reinforcements of titanium nitride (TiN), Ti3Al, TiAl and Al3Ti. The hardness and wear resistance of the coatings on four samples were greatly improved, among which sample 4 exhibited the highest hardness and best wear resistance. The hardness of the coating on sample 4 was approximately 2.5 times of the Ti-6Al-4V substrate. And the wear resistance of sample 4 was four times of the substrate.

  11. Ductile-reinforcement toughening in γ-TiAl intermetallic-matrix composites: Effects on fracture toughness and fatigue-crack propagation resistance

    International Nuclear Information System (INIS)

    Venkateswara Rao, K.T.; Ritchie, R.O.; Odette, G.R.

    1994-01-01

    The influence of the type, volume fraction, thickness and orientation of ductile phase reinforcements on the room temperature fatigue and fracture resistance of γ-TiAl intermetallic alloys is investigated. Large improvements in toughness compared to monolithic γ-TiAl are observed in both the TiNb- and Nb-reinforced composites under monotonic loading. Toughness increases with increasing ductile phase content, reinforcement thickness and strength; orientation effect are minimal. Crack-growth behavior is characterized by steep resistance curves primarily due to crack trapping/renucleation and extensive crack bridging by the ductile-phase particles. In contrast, under cyclic loading the influence of ductile phases on fatigue resistance is strongly dependent upon reinforcement orientation. Compared to monolithic γ-TiAl, improvements in fatigue-crack growth resistance are observed in TiNb-reinforced composites only in the face (C-L) orientation; crack-growth rates for the edge (C-R) orientation are actually faster in the composite. In comparison, Nb-particle reinforcements offer less toughening under monotonic loading but enhance the fatigue properties compared to TiNb reinforcements under cyclic loading

  12. Can resistance training change the strength, body composition and self-concept of overweight and obese adolescent males? A randomised controlled trial.

    Science.gov (United States)

    Schranz, Natasha; Tomkinson, Grant; Parletta, Natalie; Petkov, John; Olds, Tim

    2014-10-01

    Resistance training is an exercise modality at which overweight and obese adolescents can excel and which can therefore positively affect their psychological well-being. The aim of this study was to determine the effect of a 6-month resistance training intervention on the self-concept strength and body composition of overweight and obese adolescent males. 56 overweight and obese males aged 13-17 years were randomly allocated to an Intervention (n=30) or Control (n=26) group. Primary (psychological) and secondary (strength and body composition) outcomes were assessed at baseline as well as at 3 (halfway through the intervention), 6 (immediately postintervention) and 12 months follow-up. Random effects mixed modelling was used to determine the effects of the intervention. Statistically significant differences between the Intervention and Control groups were observed at 3-month and 6-month assessments for exercise self-efficacy, resistance training confidence and self-esteem. Large increases in strength for the Intervention group, relative to Controls, were also observed with no substantial changes in body composition shown for either group. Values for all variables returned to baseline following completion of the programme. A 6-month resistance training intervention can positively affect the self-concept and strength of overweight and obese adolescent boys. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://group.bmj.com/group/rights-licensing/permissions.

  13. Characterization of the radiation resistance of ITER-relevant and innovative fiber composites for the ITER magnet system

    International Nuclear Information System (INIS)

    Bittner-Rohrhofer, K.

    2003-06-01

    The application of glass-fiber reinforced composites for the insulation of the superconducting magnet coils of the ITER (International Thermonuclear Experimental Reactor ) fusion device requires high material performance. The mechanical integrity of the insulation is influenced by the neutron- and g-environment and by the high mechanical stresses of the magnet system over the entire plant lifetime of 20 years. Materials suggested as insulation have to be investigated in extensive test programs with respect to the present ITER design criteria. In particular, the ultimate tensile strength as well as the interlaminar shear behavior will change under static and dynamic load (tension-tension fatigue) at 77 K after irradiation to the ITER design fluence level of 1x1022 m-2 (E620.1 MeV). Therefore, a frequency of 10 Hz and a ratio of 0.1 were chosen, in order to simulate the pulsed TOKAMAK-operation as closely as possible. Furthermore, the fatigue behavior of the material is investigated over more than 3x104 cycles, which is the ITER- relevant design fatigue limit. Basically, these insulation systems are based on combined glass-fiber/Kapton tapes, which are impregnated with di-functional DGEBA epoxy resins. Several mechanical investigations showed that the radiation resistance of these organic resins is dramatically affected by radiation at a neutron fluence of 1x1022 m-2 (E620.1 MeV). Moreover, the material strength after irradiation is strongly influenced by these factors: the winding direction of the tapes, the quality of fabrication and the drastic delamination process of the whole compound. Furthermore, the radiation induced damage of adhesives applied for supporting the interfacial bonding between the glass-fiber tape and Kapton has an adverse effect on the material performance. In addition, the poor interlaminar shear behavior does not fulfil the requirements of ITER. These test-results motivated for the development of innovative resin systems with higher stability

  14. High performance corrosion and wear resistant composite titanium nitride layers produced on the AZ91D magnesium alloy by a hybrid method

    Directory of Open Access Journals (Sweden)

    Michał Tacikowski

    2014-09-01

    Full Text Available Composite, diffusive titanium nitride layers formed on a titanium and aluminum sub-layer were produced on the AZ91D magnesium alloy. The layers were obtained using a hybrid method which combined the PVD processes with the final sealing by a hydrothermal treatment. The microstructure, resistance to corrosion, mechanical damage, and frictional wear of the layers were examined. The properties of the AZ91D alloy covered with these layers were compared with those of the untreated alloy and of some engineering materials such as 316L stainless steel, 100Cr6 bearing steel, and the AZ91D alloy subjected to commercial anodizing. It has been found that the composite diffusive nitride layer produced on the AZ91D alloy and then sealed by the hydrothermal treatment ensures the corrosion resistance comparable with that of 316L stainless steel. The layers are characterized by higher electrochemical durability which is due to the surface being overbuilt with the titanium oxides formed, as shown by the XPS examinations, from titanium nitride during the hydrothermal treatment. The composite titanium nitride layers exhibit high resistance to mechanical damage and wear, including frictional wear which is comparable with that of 100Cr6 bearing steel. The performance properties of the AZ91D magnesium alloy covered with the composite titanium nitride coating are substantially superior to those of the alloy subjected to commercial anodizing which is the dominant technique employed in industrial practice.

  15. A Comparative Study of the Microstructure, Mechanical Properties and Corrosion Resistance of Ni- or Fe- Based Composite Coatings by Laser Cladding

    Science.gov (United States)

    Wan, M. Q.; Shi, J.; Lei, L.; Cui, Z. Y.; Wang, H. L.; Wang, X.

    2018-04-01

    Ni- and Fe-based composite coatings were laser cladded on 40Cr steel to improve the surface mechanical property and corrosion resistance, respectively. The microstructure and phase composition were analyzed by x-ray diffraction (XRD) and field emission scanning electron microscope (FESEM) equipped with an energy-dispersive spectrometer (EDS). The micro-hardness, tribological properties and electrochemical corrosion behavior of the coatings were evaluated. The results show that the thickness of both the coatings is around 0.7 mm, the Ni-based coating is mainly composed of γ-(Ni, Fe), FeNi3, Ni31Si12, Ni3B, CrB and Cr7C3, and the Fe-based coating is mainly composed of austenite and (Fe, Cr)7C3. Micro-hardness of the Ni-based composite coating is about 960 HV0.3, much higher than that of Fe-based coating (357.4 HV0.3) and the 40Cr substrate (251 HV0.3). Meanwhile, the Ni-based composite coating possesses better wear resistance than the Fe-based coating validated by the worn appearance and the wear loss. Electrochemical results suggested that Ni-based coating exhibited better corrosion resistance than the Fe-based coating. The 40Cr substrate could be well protected by the Ni-based coating.

  16. Anisotropy of the thermal conductivity and electrical resistivity of the SiC/Si biomorphic composite based on a white-eucalyptus biocarbon template

    Science.gov (United States)

    Parfen'eva, L. S.; Orlova, T. S.; Smirnov, B. I.; Smirnov, I. A.; Misiorek, H.; Mucha, J.; Jezowski, A.; de Arellano-Lopez, A. R.; Martinez-Fernandez, J.; Varela-Feria, F. M.

    2006-12-01

    The thermal conductivity κ and electrical resistivity ρ of a cellular ecoceramic, namely, the SiC/Si biomorphic composite, are measured in the temperature range 5 300 K. The SiC/Si biomorphic composite is fabricated using a cellular biocarbon template prepared from white eucalyptus wood by pyrolysis in an argon atmosphere with subsequent infiltration of molten silicon into empty through cellular channels of the template. The temperature dependences κ(T) and ρ(T) of the 3C-SiC/Si biomorphic composite at a silicon content of ˜30 vol % are measured for samples cut out parallel and perpendicular to the direction of tree growth. Data on the anisotropy of the thermal conductivity κ are presented. The behavior of the dependences κ(T) and ρ(T) of the SiC/Si biomorphic composite at different silicon contents is discussed in terms of the results obtained and data available in the literature.

  17. Effect of aerobic training and resistance training on circulating irisin level and their association with change of body composition in overweight/obese adults: a pilot study.

    Science.gov (United States)

    Kim, H-J; Lee, H-J; So, B; Son, J S; Yoon, D; Song, W

    2016-06-20

    The novel myokine irisin has been reported as a therapeutic target for metabolic disease. The objective of this study is to reveal the effects of aerobic training (AT) and resistance training (RT) on circulating irisin levels and their associations with change of body composition in overweight/obese adults. Twenty eight overweight/obese adults (BMI>23 kg/m(2)) were included in this study and compared before and after 8 weeks of exercise program (60 min/day, 5 times in a week). The subjects, in both aerobic and resistance training, showed significant improvement in anthropometric parameters and exercise capacities including maximal oxygen uptake and muscle strength. Interestingly, the circulating irisin was significantly increased in resistance training group (p=0.002) but not in aerobic training (p=0.426) compared to control group. In addition, we found the positive correlation between change of the circulating irisin and muscle mass (r=0.432, p=0.022) and the negative correlation between change of the circulating irisin and fat mass (r=-0.407, p=0.031). In the present pilot study, we found that circulating irisin level was increased by 8 weeks of resistance training in overweight/obese adults, suggesting that resistance training could be the efficient exercise type in overweight/obese considering positive change of body composition concomitant with increase of irisin levels.

  18. Comparisons of low-intensity versus moderate-intensity combined aerobic and resistance training on body composition, muscle strength, and functional performance in older women.

    Science.gov (United States)

    Shiotsu, Yoko; Yanagita, Masahiko

    2018-06-01

    This study aimed to examine the effects of exercise order of combined aerobic and low- or moderate-intensity resistance training into the same session on body composition, functional performance, and muscle strength in healthy older women. Furthermore, this study compared the effects of different (low- vs moderate-) intensity combined training. A total of 60 healthy older women (age 61-81 y) were randomly assigned to five groups that performed aerobic exercise before low-intensity resistance training (AR-L, n = 12) or after resistance training (RA-L, n = 12), performed aerobic exercise before moderate-intensity resistance training (AR-M, n = 12) or after resistance training (RA-M, n = 12), or nonintervention control conditions (CON, n = 12). Body composition, functional performance, and muscle strength were evaluated before and after the 10-week training. No effects of exercise order of combined aerobic and low- or moderate-intensity resistance training (AR-L vs RA-L, AR-M vs RA-M) were observed in body composition, functional performance, or muscle strength, whereas the effects of training intensity of combined training (AR-L vs AR-M, RA-L vs RA-M) were observed on functional performance. All combined trainings significantly increased muscle strength and gait ability (P Functional reach test significantly increased in the AR-M and RA-M groups (P training increases muscle strength and improves gait ability, regardless of the exercise order. Also, greater improvement in dynamic balance capacity, a risk factor associated with falling, is observed in moderate-intensity combined training.

  19. Heavy Resistance Training and Supplementation With the Alleged Testosterone Booster Nmda has No Effect on Body Composition, Muscle Performance, and Serum Hormones Associated With the Hypothalamo-Pituitary-Gonadal Axis in Resistance-Trained Males

    Directory of Open Access Journals (Sweden)

    Darryn S. Willoughby

    2014-03-01

    Full Text Available The effects of 28 days of heavy resistance training while ingesting the alleged testosterone-boosting supplement, NMDA, were determined on body composition, muscle strength, serum cortisol, prolactin, and hormones associated with the hypothalamo-pituitary- gonadal (HPG axis. Twenty resistance-trained males engaged in 28 days of resistance training 4 times/wk while orally ingesting daily either 1.78 g of placebo (PLAC or NMDA. Data were analyzed with separate 2 x 2 ANOVA (p 0.05 or supplementation (p > 0.05. In regard to total body mass and fat-free mass, however, each was significantly increased in both groups in response to resistance training (p 0.05. In both groups, lower-body muscle strength was significantly increased in response to resistance training (p 0.05. All serum hormones (total and free testosterone, LH, GnRH, estradiol, cortisol, prolactin were unaffected by resistance training (p > 0.05 or supplementation (p > 0.05. The gonadal hormones and cortisol and prolactin were unaffected by 28 days of NMDA supplementation and not associated with the observed increases in muscle strength and mass. At the dose provided, NMDA had no effect on HPG axis activity or ergogenic effects in skeletal muscle.

  20. Influence of load and sliding velocity on wear resistance of solid-lubricant composites of ultra-high molecular weight polyethylene

    Science.gov (United States)

    Panin, S. V.; Kornienko, L. A.; Buslovich, D. G.; Alexenko, V. O.; Ivanova, L. R.

    2017-12-01

    To determine the limits of the operation loading intervals appropriate for the use of solid lubricant UHMWPE composites in tribounits for mechanical engineering and medicine, the tribotechnical properties of UHMWPE blends with the optimum solid lubricant filler content (polytetrafluoroethylene, calcium stearate, molybdenum disulfide, colloidal graphite, boron nitride) are studied under dry sliding friction at different velocities (V = 0.3 and 0.5 m/s) and loads (P = 60 and 140 N). It is shown that the wear resistance of solid lubricant UHMWPE composites at moderate sliding velocities (V = 0.3 m/s) and loads (P = 60 N) increases 2-3 times in comparison with pure UHMWPE, while at high load P = 140 N wear resistance of both neat UHMWPE and its composites is reduced almost twice. At high sliding velocities and loads (up to P = 140 N), multiple increasing of the wear of pure UHMWPE and its composites takes place (by the factor of 5 to 10). The operational conditions of UHMWPE composites in tribounits in engineering and medicine are discussed.