WorldWideScience

Sample records for resin based neutron

  1. Neutron shielding material based on colemanite and epoxy resin.

    Science.gov (United States)

    Okuno, Koichi

    2005-01-01

    In recent years, there has been a need for compact shielding design such as self-shielding of a PET cyclotron or upgradation of radiation machinery in existing facilities. In these cases, high performance shielding materials are needed. Concrete or polyethylene have been used for a neutron shield. However, for compact shielding, they fall short in terms of performance or durability. Therefore, a new type of neutron shielding material based on epoxy resin and colemanite has been developed. Slab attenuation experiments up to 40 cm for the new shielding material were carried out using a 252Cf neutron source. Measurement was carried out using a REM-counter, and compared with calculation. The results show that the shielding performance is better than concrete and polyethylene mixed with 10 wt% boron oxide. From the result, we confirmed that the performance of the new material is suitable for practical use.

  2. [Dimensional accuracy of microwave-cured denture base resin].

    Science.gov (United States)

    Uchida, K; Okamoto, F; Ogata, K; Sato, T

    1989-02-01

    Recently, microwave-cured denture base resin was developed, and the resin solved the problem of internal porosity which had been generated by curing the conventional denture base resins with microwave irradiation. In this study, the dimensional accuracy of microwave-cured denture base resin was compared with that of other denture base resins, such as pour-type resin, heat-cured resin and heat-shock resin. From the experiment, the following results were obtained. 1. Dimensional accuracy of microwave-cured denture base resin was better than that of heat-cured resin and heat-shock resin, and was similar to that of pour-type resin. 2. Dimensional accuracy of microwave-cured denture base resin by slow cooling method and rapid cooling method was almost the same. Those findings suggest that microwave-cured denture base resin is valuable in clinic.

  3. Reinforcement of Denture Base Resins

    Directory of Open Access Journals (Sweden)

    T Nejatiant

    2005-10-01

    Full Text Available Introduction: PMMA has been the most popular denture base material because of its advantages including good aesthetics, accurate fit, stability in the oral environment, easy laboratory and clinical manipulation and inexpensive equipments since the 1930’s. However, its fracture resistance is not satisfactory. Aim: The aim of this study is to improve the fracture resistance of denture bases made of PMMA by assessing the effect of resin type, packing and processing variables on biaxial flexural strength (BFS. Materials & methods: 930 discs, 12 mm diameter and 2 mm thick were prepared with the following variables: a. Veined (V and Plain (P PMMA. b. 5 different powder/liquid ratios by volume (1.5:1, 2:1, 2.5:1, 3:1, 3.5:1. c. Conventional (C and Injection packing methods (I. d. Dry heat (D Water bath (W; and e. different curing times. The discs were trimmed and stored in 37°C tap water for 50 hours before carrying out BFS test, according to BS EN ISO 1567: 2001. BFS test was carried out using a tensile-testing machine (Lloyd LRX, Lloyd instruments Ltd (Figure.1 b, with a x-head speed of 1mm/min. ONE-WAY ANOVA analysis and TUKEY’S comparison were carried out (MINITAB. The temperature within the curing baths and inside of curing resin was evaluated by using a thermocouple. Results: BFS of Powder/liquid ratio of 1.5:1 is significantly lower than the other four ratios. Among the last four ratios, 2.5:1 was the strongest one although the difference was not significant. BFS of the plain type of PMMA is significantly higher than the veined type.• BFS of conventionally packed PMMA discs was greater than the injectional packed ones and the difference is significant. Water bath cured resin showed a significant higher BFS compared with dry heat curing. • Changing the curing time in the dry heat bath from 7h @ 75º C and 2hrs @ 95º C to 5hrs @ 75º C and 3hrs @ 95º C and then 2hrs @ 95º C improves BFS of PMMA. In the water bath the trend is identical

  4. Novel silica-based ion exchange resin

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-11-01

    Eichrom`s highly successful Diphonixo resin resembles a conventional ion exchange resin in its use of sulfonic acid ligands on a styrene- divinylbenzene matrix. Diphonix resin exhibits rapid exchange kinetics that allow economical operation of ion exchange systems. Unlike conventional resins, Diphonix resin contains chelating ligands that are diphosphonic acid groups that recognize and remove the targeted metals and reject the more common elements such as sodium, calcium and magnesium. This latter property makes Diphonix ideal for many industrial scale applications, including those involving waste treatment. For treatment of low-level, transuranic (TRU) and high- level radioactive wastes, Diphonix`s polystyrene backbone hinders its application due to radiolytic stability of the carbon-hydrogen bonds and lack of compatibility with expected vitrification schemes. Polystyrene-based Diphonix is approximately 60% carbon- hydrogen. In response to an identified need within the Department of Energy for a resin with the positive attributes of Diphonix that also exhibits greater radiolytic stability and final waste form compatibility, Eichrom has successfully developed a new, silica-based resin version of Diphonix. Target application for this new resin is for use in environmental restoration and waste management situations involving the processing of low-level, transuranic and high-level radioactive wastes. The resin can also be used for processing liquid mixed waste (waste that contains low level radioactivity and hazardous constituents) including mixed wastes contaminated with organic compounds. Silica-based Diphonix is only 10% carbon-hydrogen, with the bulk of the matrix silica.

  5. Nuclear characteristics of epoxy resin as a space environment neutron shielding

    Energy Technology Data Exchange (ETDEWEB)

    Adeli, Ruhollah [Nuclear Science and Technology Research Institute, Yazd (Iran, Islamic Republic of). Central Iran Research Complex; Shirmardi, Seyed Pezhman [Nuclear Science and Technology Research Institute, Tehran (Iran, Islamic Republic of). Radiation Application Research School; Mazinani, Saideh [Amirkabir Nanotechnology Research Institute, Tehran (Iran, Islamic Republic of); Ahmadi, Seyed Javad [Nuclear Science and Technology Research Institute, Tehran (Iran, Islamic Republic of). Nuclear Fuel Cycle Research School

    2017-03-15

    In recent years many investigations have been done for choosing applicable light neutron shielding in space environmental applications. In this study, we have considered the neutron radiation-protective characteristics of neat epoxy resin, a thermoplastic polymer material and have compared it with various candidate materials in neutron radiation protection such as Al 6061 alloy and Polyethylene. The aim of this investigation is the effect of type of moderator for fast neutron, notwithstanding neutron absorbers fillers. The nuclear interactions and the effective dose at shields have been studied with the Monte Carlo N-Particle transport code (MCNP), using variance reductions to reduce the relative error. Among the candidates, polymer matrix showed a better performance in attenuating fast neutrons and caused a lower neutron and secondary photon effective dose.

  6. Novel silica-based ion exchange resin

    Energy Technology Data Exchange (ETDEWEB)

    Gula, M.; Harvey, J.

    1996-12-31

    Shortcomings of chelating resins have been addressed by a new class of ion exchange resins called dual mechanism bifunctional polymers (DMBPs). DMBPs use hydrophilic cation exchange ligands with rapid uptake kinetics and use chelating ligands for selectivity for one or more metals; result is a resin that quickly recognizes and removes targeted metals from waste, remediation, and process streams. Eichrom`s Diphonix {reg_sign} resin is the first DMBP to be widely released as a commercial product; it is polystyrene based. Objective of this work is to synthesize commercial quantities of a silica-based ion exchange resin with the same or better metal ion selectivity, metal uptake kinetics, and acid stability as Diphonix. Feasibility was determined, however the process needs to be optimized. Studies at Eichrom and ANL of the performance of Diphonix resin over a broad range of HNO3 and HCl conditions and inorganic salt loadings are discussed together with the proposed method of incorporating similar characteristics into a silica-based resin. The new, silica-based resin functionalized with diphosphonic acid ligands can be used in environmental restoration and waste management situations involving processing of low-level, transuranic, and high-level radioactive wastes; it can also be used for processing liquid mixed waste including wastes contaminated with organic compounds.

  7. Biocompatibility of Resin-based Dental Materials

    OpenAIRE

    Keyvan Moharamzadeh; Ian M. Brook; Richard van Noort

    2009-01-01

    Oral and mucosal adverse reactions to resin-based dental materials have been reported. Numerous studies have examined thebiocompatibility of restorative dental materials and their components, and a wide range of test systems for the evaluation of the biological effects of these materials have been developed. This article reviews the biological aspects of resin-based dental materials and discusses the conventional as well as the new techniques used for biocompatibility assessment of dental mat...

  8. Luminous Efficient Compositions Based on Epoxy Resin

    Directory of Open Access Journals (Sweden)

    R.S. Palaiah

    2006-07-01

    Full Text Available Magnesium/sodium nitrate illuminating compositions with epoxy resin - E 605 have beenstudied for luminosity and luminous efficiency by varying fuel oxidizer ratio and binder content.The compositions have been evaluated for impact and friction sensitivities, burn rate, thermalcharacteristics, and mechanical properties. Flame temperature and combustion products areevaluated theoretically by using REAL program. Experimental results show that, luminosity,burn rate, and calorimetric value are higher for polyester resin-based compositions. The highluminous efficiency composition is achieved with magnesium/sodium nitrate ratio of 70/30 with4 per cent epoxy resin.

  9. Visualization of in vitro evaluation of restored teeth with synthetic resins by neutron radiography

    Energy Technology Data Exchange (ETDEWEB)

    Barbosa, Andre Luis N., E-mail: abarbosa@ien.gov.br [Instituto de Engenharia Nuclear (IEN/CNEN-RJ), Rio de Janeiro, RJ (Brazil); Crispim, Verginia R., E-mail: vrcrispim@gmail.com [Coordenacao dos Programas de Pos-Graduacao em Engenharia (UFRJ/CT/COPPE), Rio de Janeiro, RJ (Brazil)

    2013-07-01

    The goal of the present study was to evaluate whether the technique of neutron radiography can provide information on strength and adherence in dental restoration with synthetic polymeric materials, particularly as a tool for the analysis of micro leakage and voids. Thus, tooth samples were drilled, producing cavities with similar dimensions in each tooth, and then carefully filled with eight types of resins that are the most commonly used by dentists. After exposing the tooth samples to a neutron beam, their radiographic images were analyzed. This technique gave good results showing that all the tooth samples were suitably restored. (author)

  10. FDI report on adverse reactions to resin-based materials.

    Science.gov (United States)

    Fan, P L; Meyer, D M

    2007-02-01

    Resin-based restorative materials are considered safe for the vast majority of dental patients. Although constituent chemicals such as monomers, accelerators and initiators can potentially leach out of cured resin-based materials after placement, adverse reactions to these chemicals are rare and reaction symptoms commonly subside after removal of the materials. Dentists should be aware of the rare possibility that patients could have adverse reactions to constituents of resin-based materials and be vigilant in observing any adverse reactions after restoration placement. Dentists should also be cognisant of patient complaints about adverse reactions that may result from components of resin-based materials. To minimise monomer leaching and any potential risk of dermatological reactions, resin-based materials should be adequately cured. Dental health care workers should avoid direct skin contact with uncured resin-based materials. Latex and vinyl gloves do not provide adequate barrier protection to the monomers in resin-based materials.

  11. Dental repair material: a resin-modified glass-ionomer bioactive ionic resin-based composite.

    Science.gov (United States)

    Croll, Theodore P; Berg, Joel H; Donly, Kevin J

    2015-01-01

    This report documents treatment and repair of three carious teeth that were restored with a new dental repair material that features the characteristics of both resin-modified glass-ionomer restorative cement (RMGI) and resin-based composite (RBC). The restorative products presented are reported by the manufacturer to be the first bioactive dental materials with an ionic resin matrix, a shock-absorbing resin component, and bioactive fillers that mimic the physical and chemical properties of natural teeth. The restorative material and base/liner, which feature three hardening mechanisms, could prove to be a notable advancement in the adhesive dentistry restorative materials continuum.

  12. Observation of Neutron Skyshine from an Accelerator Based Neutron Source

    Energy Technology Data Exchange (ETDEWEB)

    Franklyn, C. B. [Radiation Science Department, Necsa, PO Box 582, Pretoria 0001 (South Africa)

    2011-12-13

    A key feature of neutron based interrogation systems is the need for adequate provision of shielding around the facility. Accelerator facilities adapted for fast neutron generation are not necessarily suitably equipped to ensure complete containment of the vast quantity of neutrons generated, typically >10{sup 11} n{center_dot}s{sup -1}. Simulating the neutron leakage from a facility is not a simple exercise since the energy and directional distribution can only be approximated. Although adequate horizontal, planar shielding provision is made for a neutron generator facility, it is sometimes the case that vertical shielding is minimized, due to structural and economic constraints. It is further justified by assuming the atmosphere above a facility functions as an adequate radiation shield. It has become apparent that multiple neutron scattering within the atmosphere can result in a measurable dose of neutrons reaching ground level some distance from a facility, an effect commonly known as skyshine. This paper describes a neutron detection system developed to monitor neutrons detected several hundred metres from a neutron source due to the effect of skyshine.

  13. [Antibacterial actions of denture base resin on oral bacteria].

    Science.gov (United States)

    Yamauchi, M; Nigauri, A; Yamamoto, K; Nakazato, G; Kawano, J; Kimura, K

    1989-06-01

    Antibacterial action of various denture base resins on thirteen species of bacteria were studied in vitro. Antibacterial effect of 5% tannin-fluoride preparation, 5% tannic acid and 5% chlorhexidine added to resins on these thirteen bacterial species were also investigated using heat-curing denture base resins. Fresh microwave-curing resin and pour-type resin each showed an antibacterial action on one bacterial strain. Fresh self-curing resins had antibacterial actions on several bacterial strains. However, after storage in water at 37 degrees C for one week, antibacterial action of microwave-curing and pour-type resin were diminished and self-curing resins partially lost their antibacterial actions. Denture base resin containing tannin-fluoride preparation or tannic acid showed an antibacterial effect on one bacterial strain. On the other hand, denture base resin containing chlorhexidine had an antibacterial action on eleven bacterial strains. However, color and mechanical properties of the drug-containing resins were not satisfactory.

  14. Synthesis and Characterizations of Melamine-Based Epoxy Resins

    Directory of Open Access Journals (Sweden)

    Raffaele Cioffi

    2013-09-01

    Full Text Available A new, easy and cost-effective synthetic procedure for the preparation of thermosetting melamine-based epoxy resins is reported. By this innovative synthetic method, different kinds of resins can be obtained just by mixing the reagents in the presence of a catalyst without solvent and with mild curing conditions. Two types of resins were synthesized using melamine and a glycidyl derivative (resins I or by adding a silane derivative (resin II. The resins were characterized by means of chemical-physical and thermal techniques. Experimental results show that all the prepared resins have a good thermal stability, but differ for their mechanical properties: resin I exhibits remarkable stiffness with a storage modulus value up to 830 MPa at room temperature, while lower storage moduli were found for resin II, indicating that the presence of silane groups could enhance the flexibility of these materials. The resins show a pot life higher than 30 min, which makes these resins good candidates for practical applications. The functionalization with silane terminations can be exploited in the formulation of hybrid organic-inorganic composite materials.

  15. Synthesis and characterizations of melamine-based epoxy resins.

    Science.gov (United States)

    Ricciotti, Laura; Roviello, Giuseppina; Tarallo, Oreste; Borbone, Fabio; Ferone, Claudio; Colangelo, Francesco; Catauro, Michelina; Cioffi, Raffaele

    2013-09-05

    A new, easy and cost-effective synthetic procedure for the preparation of thermosetting melamine-based epoxy resins is reported. By this innovative synthetic method, different kinds of resins can be obtained just by mixing the reagents in the presence of a catalyst without solvent and with mild curing conditions. Two types of resins were synthesized using melamine and a glycidyl derivative (resins I) or by adding a silane derivative (resin II). The resins were characterized by means of chemical-physical and thermal techniques. Experimental results show that all the prepared resins have a good thermal stability, but differ for their mechanical properties: resin I exhibits remarkable stiffness with a storage modulus value up to 830 MPa at room temperature, while lower storage moduli were found for resin II, indicating that the presence of silane groups could enhance the flexibility of these materials. The resins show a pot life higher than 30 min, which makes these resins good candidates for practical applications. The functionalization with silane terminations can be exploited in the formulation of hybrid organic-inorganic composite materials.

  16. Biphenyl liquid crystalline epoxy resin as a low-shrinkage resin-based dental restorative nanocomposite.

    Science.gov (United States)

    Hsu, Sheng-Hao; Chen, Rung-Shu; Chang, Yuan-Ling; Chen, Min-Huey; Cheng, Kuo-Chung; Su, Wei-Fang

    2012-11-01

    Low-shrinkage resin-based photocurable liquid crystalline epoxy nanocomposite has been investigated with regard to its application as a dental restoration material. The nanocomposite consists of an organic matrix and an inorganic reinforcing filler. The organic matrix is made of liquid crystalline biphenyl epoxy resin (BP), an epoxy resin consisting of cyclohexylmethyl-3,4-epoxycyclohexanecarboxylate (ECH), the photoinitiator 4-octylphenyl phenyliodonium hexafluoroantimonate and the photosensitizer champhorquinone. The inorganic filler is silica nanoparticles (∼70-100 nm). The nanoparticles were modified by an epoxy silane of γ-glycidoxypropyltrimethoxysilane to be compatible with the organic matrix and to chemically bond with the organic matrix after photo curing. By incorporating the BP liquid crystalline (LC) epoxy resin into conventional ECH epoxy resin, the nanocomposite has improved hardness, flexural modulus, water absorption and coefficient of thermal expansion. Although the incorporation of silica filler may dilute the reinforcing effect of crystalline BP, a high silica filler content (∼42 vol.%) was found to increase the physical and chemical properties of the nanocomposite due to the formation of unique microstructures. The microstructure of nanoparticle embedded layers was observed in the nanocomposite using scanning and transmission electron microscopy. This unique microstructure indicates that the crystalline BP and nanoparticles support each other and result in outstanding mechanical properties. The crystalline BP in the LC epoxy resin-based nanocomposite was partially melted during exothermic photopolymerization, and the resin expanded via an order-to-disorder transition. Thus, the post-gelation shrinkage of the LC epoxy resin-based nanocomposite is greatly reduced, ∼50.6% less than in commercialized methacrylate resin-based composites. This LC epoxy nanocomposite demonstrates good physical and chemical properties and good biocompatibility

  17. Has resin-based composite replaced amalgam?

    Science.gov (United States)

    Christensen, Gordon J; Child, Paul L

    2010-02-01

    The major health organizations in the world continue to accept amalgam use, but the "amalgam war" of the 1800s is still going on. The end is not in sight. There is little disagreement that amalgam serves well and, although controversial, it appears to have minimal to no health hazards. There is a wide variation in the relative amount of amalgam placed in developed countries, and many dentists in North America do not use it. However, amalgam is still being used at least some of the time by the majority of practitioners in North America, and most of those practitioners also place resin-based composite in Class II locations. The evolution from amalgam to tooth-colored restorations has been a slow and tumultuous journey. The acceptability of resin-based composite in Class II locations continues to be a question for some dentists, while others have concluded that amalgam is "dead." It would be highly desirable if some of dentists using the alleged poisonous properties of amalgam as a "practice building" ploy would find more legitimate methods to increase their practice activity.

  18. The creep behavior of acrylic denture base resins.

    Science.gov (United States)

    Sadiku, E R; Biotidara, F O

    1996-01-01

    The creep behavior of acrylic dental base resins, at room temperature and at different loading conditions, has been examined. The behaviors of these resins are similar to that of "commercial perspex" at room temperature over a period of 1000 seconds. The pseudo-elastic moduli of the blends of PMMA VC show a significant increase compared with PMMA alone. The addition of the PVC powder to the heat-cured acrylic resin increased the time-dependent elastic modulus. This increase in elastic modulus is advantageous in the production of denture based resins of improv mechanical properties.

  19. Sorption kinetics of ethanol/water solution by dimethacrylate-based dental resins and resin composites.

    Science.gov (United States)

    Sideridou, Irini D; Achilias, Dimitris S; Karabela, Maria M

    2007-04-01

    In the present investigation the sorption-desorption kinetics of 75 vol % ethanol/water solution by dimethacrylate-based dental resins and resin composites was studied in detail. The resins examined were made by light-curing of bisphenol A glycol dimethacrylate (Bis-GMA), triethylene glycol dimethacrylate (TEGDMA), urethane dimethacrylate (UDMA), bisphenol A ethoxylated dimethacrylate (Bis-EMA), and mixtures of these monomers. The resin composites were prepared from two commercial light-cured restorative materials (Z100 MP and Filtek Z250), the resin matrix of which is based on copolymers of the above-mentioned monomers. Ethanol/water sorption/desorption was examined in both equilibrium and dynamic conditions in two adjacent sorption-desorption cycles. For all the materials studied, it was found that the amount of ethanol/water sorbed or desorbed was always larger than the corresponding one reported in literature in case of water immersion. It was also observed that the chemical structure of the monomers used for the preparation of the resins directly affects the amount of solvent sorbed or desorbed, as well as sorption kinetics, while desorption rate was nearly unaffected. In the case of composites studied, it seems that the sorption/desorption process is not influenced much by the presence of filler. Furthermore, diffusion coefficients calculated for the resins were larger than those of the composites and were always higher during desorption than during sorption. Finally, an interesting finding concerning the rate of ethanol/water sorption was that all resins and composites followed Fickian diffusion kinetics during almost the whole sorption curve; however, during desorption the experimental data were overestimated by the theoretical model. Instead, it was found that a dual diffusion-relaxation model was able to accurately predict experimental data during the whole desorption curve. Kinetic relaxation parameters, together with diffusion coefficients, are reported

  20. Acrylic Resin Cytotoxicity for Denture Base--Literature Review.

    Science.gov (United States)

    Goiato, Marcelo C; Freitas, Emily; dos Santos, Daniela; de Medeiros, Rodrigo; Sonego, Mariana

    2015-01-01

    Acrylic resin is a widely used material in clinical practice, and a satisfactory biocompatibility is essential. When the resin polymerization reaction is incomplete, residual monomers are released into the oral cavity. The aim of this study was to evaluate, through a literature review, the cytotoxicity caused by the denture base acrylic resin used, and its components. The selection of published studies was performed on the Pubmed database from January 2008 to July 2013. The keywords used were: "cytotoxicity and acrylic resins", "cytotoxicity and denture base resins" and "cytotoxicity and oral prosthesis". Inclusion criteria were: in vitro studies and literature reviews published in English that evaluated the acrylic resin cytotoxicity for denture base and its components. Studies with no reference to the search strategy were excluded. A total of 182 articles were found. Among these, only 13 were included for writing this review. The MTT test is the most common test used to evaluate acrylic resin cytotoxicity. Auto-polymerized resin is more cytotoxic than heat-polymerized resin because of its higher quantity of residual monomers which cause cell and tissue changes in the oral mucosa. However, more studies are necessary for the development of biocompatible materials.

  1. Curing depth of a resin-modified glass ionomer and two resin-based luting agents.

    Science.gov (United States)

    Sigemori, Ricardo Massao; Reis, André Figueiredo; Giannini, Marcelo; Paulillo, Luís Alexandre M S

    2005-01-01

    The degree of conversion of resin-based luting agents used for retention of prefabricated posts has been questioned due to the difficulty of light penetration into the resin-filled root canal. This study evaluated the depth of cure of a resin-modified glass ionomer cement (Rely X--3M ESPE) and two resin-based luting agents (Rely X ARC--3M ESPE and Enforce-Dentsply). Twenty-four 14x2x2mm3 specimens were prepared in a Teflon split mold with the three luting agents (n=8). After preparation, the specimens were stored at 37 degrees C in a dark box for 24 hours prior to microhardness testing. Measurements of Knoop hardness were performed at three different depths: superficial, medium and deep thirds. The results (KHN) were statistically analyzed by repeated measures ANOVA and Tukey test (0.05), which showed that resin-based luting agents presented the highest Knoop hardness values within the superficial third. Within the medium third, there were no significant differences among luting materials. However, within the deep third, Rely X presented the highest values. KHN values of resin-based luting agents decreased remarkably as depth increased.

  2. Posterior resin-based composite: review of the literature.

    Science.gov (United States)

    Burgess, J O; Walker, Richard; Davidson, J M

    2002-01-01

    The use of direct posterior resin-based composite has increased primarily due to patient esthetic desires and product improvements. Other factors (substantiated or not) contributing to increased use of resin-based composite are environmental and health concerns with dental amalgam. New visible light cured resin-based composite products are introduced yearly, as manufacturers continue to improve this tooth-colored restorative material. This paper will characterize current posterior resin-based composite materials (hybrid, microfill, flowable, and packable), review recent in vitro and clinical research, and recommend indications for these materials. In addition, the literature on compomers will be reviewed and recommendation made for their use. The data indicates that composite resin is a technique sensitive restorative material that can be used in large preparations if proper manipulation and isolation can be maintained. Compomers may also be used as an esthetic posterior restorative if proper isolation is provided.

  3. Attribute based selection of thermoplastic resin for vacuum infusion process

    DEFF Research Database (Denmark)

    Prabhakaran, R.T. Durai; Lystrup, Aage; Løgstrup Andersen, Tom

    2011-01-01

    The composite industry looks toward a new material system (resins) based on thermoplastic polymers for the vacuum infusion process, similar to the infusion process using thermosetting polymers. A large number of thermoplastics are available in the market with a variety of properties suitable...... for different engineering applications, and few of those are available in a not yet polymerised form suitable for resin infusion. The proper selection of a new resin system among these thermoplastic polymers is a concern for manufactures in the current scenario and a special mathematical tool would...... be beneficial. In this paper, the authors introduce a new decision making tool for resin selection based on significant attributes. This article provides a broad overview of suitable thermoplastic material systems for vacuum infusion process available in today’s market. An illustrative example—resin selection...

  4. Contribution To Degradation Study, Behavior Of Unsaturated Polyester Resin Under Neutron Irradiation

    Science.gov (United States)

    Abellache, D.; Lounis, A.; Taïbi, K.

    2010-01-01

    Applications of unsaturated polyester thermosetting resins are numerous in construction sector, in transport, electric spare parts manufactures, consumer goods, and anticorrosive materials. This survey reports the effect of thermosetting polymer degradation (unsaturated polyester): degradation by neutrons irradiation. In order to evaluate the deterioration of our material, some comparative characterizations have been done between standard samples and damaged ones. Scanning electron microscopy (SEM), ultrasonic scanning, hardness test (Shore D) are the techniques which have been used. The exposure to a neutrons flux is carried out in the column of the nuclear research reactor of Draria (Algiers-Algeria). The energetic profile of the incidental fluxes is constituted of fast neutrons (ΦR = 3.1012n.cm-2.s-1, E = 2 Mev) of thermal neutrons (ΦTH = 1013n.cm-2.s-1; E = 0.025 ev) and epithermal neutrons (Φepi = 7.1011 n.cm-2.s-1; E>4,9 ev). The received dose flow is 0,4 Kgy. We notice only a few scientific investigations can be found in this field. In comparison with the standard sample (no exposed) it is shown that the damage degree is an increasing process with the exposure. Concerning the description of irradiation effects on polymers, we can advance that several reactions are in competition : reticulation, chain break, and oxidation by radical mechanism. In our case the incidental particle of high energy fast neutrons whose energy is greater or equal to 2 Mev, is braked by the target with a nuclear shock during which the incidental particle transmits a part of its energy to an atom. If the energy transfer is sufficient, the nuclear shock permits to drive out an atom of its site the latter will return positioning interstitially, the energy that we used oversteps probably the energy threshold (displacement energy). This fast neutrons collision with target cores proceeds to an indirect ionization by the preliminary creation of excited secondary species that will

  5. Cyclotron-based neutron source for BNCT

    Science.gov (United States)

    Mitsumoto, T.; Yajima, S.; Tsutsui, H.; Ogasawara, T.; Fujita, K.; Tanaka, H.; Sakurai, Y.; Maruhashi, A.

    2013-04-01

    Kyoto University Research Reactor Institute (KURRI) and Sumitomo Heavy Industries, Ltd. (SHI) have developed a cyclotron-based neutron source for Boron Neutron Capture Therapy (BNCT). It was installed at KURRI in Osaka prefecture. The neutron source consists of a proton cyclotron named HM-30, a beam transport system and an irradiation & treatment system. In the cyclotron, H- ions are accelerated and extracted as 30 MeV proton beams of 1 mA. The proton beams is transported to the neutron production target made by a beryllium plate. Emitted neutrons are moderated by lead, iron, aluminum and calcium fluoride. The aperture diameter of neutron collimator is in the range from 100 mm to 250 mm. The peak neutron flux in the water phantom is 1.8×109 neutrons/cm2/sec at 20 mm from the surface at 1 mA proton beam. The neutron source have been stably operated for 3 years with 30 kW proton beam. Various pre-clinical tests including animal tests have been done by using the cyclotron-based neutron source with 10B-p-Borono-phenylalanine. Clinical trials of malignant brain tumors will be started in this year.

  6. Cyclotron-based neutron source for BNCT

    Energy Technology Data Exchange (ETDEWEB)

    Mitsumoto, T.; Yajima, S.; Tsutsui, H.; Ogasawara, T.; Fujita, K. [Sumitomo Heavy Industries, Ltd (Japan); Tanaka, H.; Sakurai, Y.; Maruhashi, A. [Kyoto University Research Reactor Institute (Japan)

    2013-04-19

    Kyoto University Research Reactor Institute (KURRI) and Sumitomo Heavy Industries, Ltd. (SHI) have developed a cyclotron-based neutron source for Boron Neutron Capture Therapy (BNCT). It was installed at KURRI in Osaka prefecture. The neutron source consists of a proton cyclotron named HM-30, a beam transport system and an irradiation and treatment system. In the cyclotron, H- ions are accelerated and extracted as 30 MeV proton beams of 1 mA. The proton beams is transported to the neutron production target made by a beryllium plate. Emitted neutrons are moderated by lead, iron, aluminum and calcium fluoride. The aperture diameter of neutron collimator is in the range from 100 mm to 250 mm. The peak neutron flux in the water phantom is 1.8 Multiplication-Sign 109 neutrons/cm{sup 2}/sec at 20 mm from the surface at 1 mA proton beam. The neutron source have been stably operated for 3 years with 30 kW proton beam. Various pre-clinical tests including animal tests have been done by using the cyclotron-based neutron source with {sup 10}B-p-Borono-phenylalanine. Clinical trials of malignant brain tumors will be started in this year.

  7. Repair of dental resin-based composites.

    Science.gov (United States)

    Baur, Veronika; Ilie, Nicoleta

    2013-03-01

    The study analyzed the reparability and compatibility of light-curing resin-based composites (RBCs) of the categories "microhybrid," "nanohybrid," and "packable." Six RBCs with different matrix and filler formulation--purely methacrylate-based composites (MBCs), ormocer-based composites (OBCs), and silorane-based composites (SBCs)--were used for the specimens. Every material was combined with itself and with the other five RBCs, resulting in a total of 36 combination groups (n = 20). The specimens were polymerized, aged for 8 weeks in distilled water at 37 °C, and then repaired by means of a repair kit. Shear bond strength and fracture mode were measured after aging of the specimens, undergoing storage for 24 h in distilled water at 37 °C followed by thermocycling (5,000 cycles, 5-55 °C) and an additional 4-week storage in distilled water at 37 °C. Data were statistically analyzed using ANOVA with TUKEY HSD post hoc test (α = 0.05). On average, the OBC Admira reached the highest value as a substrate material (30.41 MPa), and the SBC Filtek Silorane reached the lowest value (8.14 MPa). Filtek Silorane was identified as the repair material with the highest bond strength value (28.70 MPa), while a packable composite reached the lowest bond strength value (15.55 MPa). The analysis of the break modes showed that adhesive breaks are typical when strength is at its lowest (6.27 MPa). A large number of cohesive fractures are conspicuous when identical materials are used for repair, except Filtek Silorane (2 % cohesive fractures). The study demonstrated that the effect of the different materials on bond strength varies strongly, depending on whether the material is used as filling or as repair material. It is generally advisable but not compulsory to combine identical RBCs.

  8. Cytotoxicity evaluation of methacrylate- and silorane-based composite resins

    Directory of Open Access Journals (Sweden)

    Gulsah Goktolga Akin

    2012-10-01

    Full Text Available

    Objectives: The objective of this study was to investigate and compare the cytotoxic effects of four composite resin materials with different content.

    Material and Methods: Two traditional methacrylate-based (Clearfil AP-X, RefleXions, as well as a self-adhering methacrylate-based (Vertise Flow and a silorane-based (Filtek Silorane composite resin were tested in the experiment. Ten cylindrical specimens were made of each material, using a mould (2mm. thick and 8 mm. in diameter. An agar diffusion method was employed, and cytotoxicity rankings were determined using lysis index scores. For statistical analysis, Kruskal-Wallis and Mann-Whitney U-tests were used.

    Results: Amongst the composite resins, the silorane-based composite was found to be less cytotoxic than the methacrylate-based composite resins, which all had the same cytotoxicity ranking.

    Conclusions: The silorane-based composite resin was considered more biocompatible than the methacrylate-based composite resins.

  9. Polymerization shrinkage of flowable resin-based restorative materials

    OpenAIRE

    Stavridakis, Minos M; Dietschi, Didier; Krejci, Ivo

    2005-01-01

    This study measured the linear polymerization displacement and polymerization forces induced by polymerization shrinkage of a series of flowable resin-based restorative materials. The materials tested were 22 flowable resin-based restorative materials (Admira Flow, Aelite Flow, Aeliteflow LV, Aria, Crystal Essence, Definite Flow, Dyract Flow, Filtek Flow, FloRestore, Flow-it, Flow-Line, Freedom, Glacier, OmegaFlo, PermaFlo, Photo SC, Revolution 2, Star Flow, Synergy Flow, Tetric Flow, Ultrase...

  10. Resin-based composites and compomers in primary molars.

    Science.gov (United States)

    García-Godoy, F

    2000-07-01

    Resin-based composite resins and polyacid-modified resin-based composites (compomers) have become popular for the restoration of primary anterior and posterior teeth. In some European countries, resin-based composites or glass-ionomers are the materials of choice for primary teeth because of the controversy over dental amalgam and its alleged adverse health effects resulting from the release of mercury, although a clear correlation between amalgam restorations and health has not been determined. Another reason for the worldwide increased use of resin-based composites and glass-ionomers in pediatric dentistry could be attributed to the growing demand from parents to provide esthetic restorations to their children. More conservative preparations can be performed maintaining more tooth structure because of the adhesive properties of the composites and compomers. The most conservative treatment planning and meticulous care in the placement of the resin-based composites and compomers would produce long-term satisfactory results. These restorations should be placed in patients with low-to-moderate caries risk, and after placement the restorations should be monitored carefully to avoid complications mainly produced by recurrent caries and wear.

  11. Neutron matter, neutron pairing, and neutron drops based on chiral effective field theory interactions

    Energy Technology Data Exchange (ETDEWEB)

    Krueger, Thomas

    2016-10-19

    calculate the pairing gaps in neutron matter and provide uncertainty estimates. The formation of heavy elements in the early universe proceeds through the rapid neutron-capture process. This process requires precise knowledge of the properties of very neutron-rich nuclei, which are unstable and at present not accessible in experiments. Thus, one can explore their properties only with theoretical calculations. Currently the only approach to the properties of all nuclei are energy-density functionals (EDFs). All EDFs used today are based on phenomenological models and fits to stable nuclei, which makes their predictive power for unknown (neutron-rich) nuclei unclear. Deriving an ab initio EDF directly from the nuclear forces is an important goal of nuclear theory. A promising approach is the optimised effective potential (OEP) method. We take a step into that direction and calculate neutron drops within the OEP formalism. In addition to the exact-exchange approximation we study for the first time the effect of second-order contributions and compare to quantum Monte Carlo and other results.

  12. The effect of resin thickness on polymerization characteristics of silorane-based composite resin

    Directory of Open Access Journals (Sweden)

    Sung-Ae Son

    2014-11-01

    Full Text Available Objectives This study examined the influence of the resin thickness on the polymerization of silorane- and methacrylate-based composites. Materials and Methods One silorane-based (Filtek P90, 3M ESPE and two methacrylate-based (Filtek Z250 and Z350, 3M ESPE composite resins were used. The number of photons were detected using a photodiode detector at the different thicknesses (thickness, 1, 2 and 3 mm specimens. The microhardness of the top and bottom surfaces was measured (n = 15 using a Vickers hardness with 200 gf load and 15 sec dwell time conditions. The degree of conversion (DC of the specimens was determined using Fourier transform infrared spectroscopy (FTIR. Scratched powder of each top and bottom surface of the specimen dissolved in ethanol for transmission FTIR spectroscopy. The refractive index was measured using a Abbe-type refractometer. To measure the polymerization shrinkage, a linometer was used. The results were analyzed using two-way ANOVA and Tukey's test at p < 0.05 level. Results The silorane-based resin composite showed the lowest filler content and light attenuation among the specimens. P90 showed the highest values in the DC and the lowest microhardness at all depth. In the polymerization shrinkage, P90 showed a significantly lower shrinkage than the rest two resin products (p < 0.05. P90 showed a significantly lower refractive index than the remaining two resin products (p < 0.05. Conclusions DC, microhardness, polymerization rate and refractive index linearly decreased as specimen thickness linearly increased. P90 showed much less polymerization shrinkage compared to other specimens. P90, even though achieved the highest DC, showed the lowest microhardness and refractive index.

  13. Ion chamber based neutron detectors

    Science.gov (United States)

    Derzon, Mark S; Galambos, Paul C; Renzi, Ronald F

    2014-12-16

    A neutron detector with monolithically integrated readout circuitry, including: a bonded semiconductor die; an ion chamber formed in the bonded semiconductor die; a first electrode and a second electrode formed in the ion chamber; a neutron absorbing material filling the ion chamber; and the readout circuitry which is electrically coupled to the first and second electrodes. The bonded semiconductor die includes an etched semiconductor substrate bonded to an active semiconductor substrate. The readout circuitry is formed in a portion of the active semiconductor substrate. The ion chamber has a substantially planar first surface on which the first electrode is formed and a substantially planar second surface, parallel to the first surface, on which the second electrode is formed. The distance between the first electrode and the second electrode may be equal to or less than the 50% attenuation length for neutrons in the neutron absorbing material filling the ion chamber.

  14. A comparison of shear bond strength of ceramic and resin denture teeth on different acrylic resin bases.

    Science.gov (United States)

    Corsalini, Massimo; Di Venere, Daniela; Pettini, Francesco; Stefanachi, Gianluca; Catapano, Santo; Boccaccio, Antonio; Lamberti, Luciano; Pappalettere, Carmine; Carossa, Stefano

    2014-01-01

    The purpose of this study is to compare the shear bond strength of different resin bases and artificial teeth made of ceramic or acrylic resin materials and whether tooth-base interface may be treated with aluminium oxide sandblasting. Experimental measurements were carried on 80 specimens consisting of a cylinder of acrylic resin into which a single tooth is inserted. An ad hoc metallic frame was realized to measure the shear bond strength at the tooth-base interface. A complete factorial plan was designed and a three-way ANalysis Of VAriance (ANOVA) was carried out to investigate if shear bond strength is affected by the following factors: (i) tooth material (ceramic or resin); (ii) base material (self-curing or thermal-curing resin); (iii) presence or absence of aluminium oxide sandblasting treatment at the tooth-base interface. Tukey post hoc test was also conducted to evaluate any statistically significant difference between shear strength values measured for the dif-ferently prepared samples. It was found from ANOVA that the above mentioned factors all affect shear strength. Furthermore, post hoc analysis indi-cated that there are statistically significant differences (p-value=0.000) between measured shear strength values for: (i) teeth made of ceramic material vs. teeth made of acrylic resin material; (ii) bases made of self-curing resin vs. thermal-curing resin; (iii) specimens treated with aluminium oxide sandblasting vs. untreated specimens. Shear strength values measured for acryl-ic resin teeth were on average 70% higher than those measured for ceramic teeth. The shear bond strength was maximized by preparing samples with thermal-curing resin bases and resin teeth submitted to aluminium oxide sandblasting.

  15. Dimensional accuracy of acrylic resin maxillary denture base polymerized by a new injection pressing method.

    Science.gov (United States)

    Ono, Takahiro; Kita, Seiichi; Nokubi, Takashi

    2004-09-01

    The purpose of this study was to confirm the dimensional accuracy of a newly developed injection pressing method for resin polymerization by making use of the internal electric resistance of resin to determine the optimal timing for resin injection. A new injection pressing polymerization pot with a built-in system to measure the internal electric resistance of resin was used for resin polymerization. Fluid-type resin was injected into the mold of a maxillary complete denture base under nine different conditions: three different timings for resin injection according to the electric resistance of resin dough (early stage: 11 Mohms; intermediate stage: 16 Mohms; final stage: 21 Mohms) and three different motor powers for resin injection (2000 N, 4000 N, and 6000 N). In the best polymerization condition (injected during the early stage of resin dough under a motor power of 6000 N), the adaptation of the denture base showed a statistically significant improvement compared with the conventional pouring method.

  16. Accelerator Based Neutron Beams for Neutron Capture Therapy

    Energy Technology Data Exchange (ETDEWEB)

    Yanch, Jacquelyn C.

    2003-04-11

    The DOE-funded accelerator BNCT program at the Massachusetts Institute of Technology has resulted in the only operating accelerator-based epithermal neutron beam facility capable of generating significant dose rates in the world. With five separate beamlines and two different epithermal neutron beam assemblies installed, we are currently capable of treating patients with rheumatoid arthritis in less than 15 minutes (knee joints) or 4 minutes (finger joints) or irradiating patients with shallow brain tumors to a healthy tissue dose of 12.6 Gy in 3.6 hours. The accelerator, designed by Newton scientific Incorporated, is located in dedicated laboratory space that MIT renovated specifically for this project. The Laboratory for Accelerator Beam Applications consists of an accelerator room, a control room, a shielded radiation vault, and additional laboratory space nearby. In addition to the design, construction and characterization of the tandem electrostatic accelerator, this program also resulted in other significant accomplishments. Assemblies for generating epithermal neutron beams were designed, constructed and experimentally evaluated using mixed-field dosimetry techniques. Strategies for target construction and target cooling were implemented and tested. We demonstrated that the method of submerged jet impingement using water as the coolant is capable of handling power densities of up to 6 x 10(sup 7) W/m(sup 2) with heat transfer coefficients of 10(sup 6)W/m(sup 2)-K. Experiments with the liquid metal gallium demonstrated its superiority compared with water with little effect on the neutronic properties of the epithermal beam. Monoenergetic proton beams generated using the accelerator were used to evaluate proton RBE as a function of LET and demonstrated a maximum RBE at approximately 30-40 keV/um, a finding consistent with results published by other researchers. We also developed an experimental approach to biological intercomparison of epithermal beams and

  17. Development of optical devices based on neutron refractive optics

    Energy Technology Data Exchange (ETDEWEB)

    Oku, T.; Morita, S.; Moriyasu, S. [Institute of Physical and Chemical Research, Wako, Saitama (JP)] [and others

    2001-03-01

    We have been developing neutron optical devices based on neutron refractive optics, such as a neutron lens and prism to improve neutron scattering methods. Prototypes of a compound Fresnel lens, a magnetic lens and prism for neutrons have been developed. The functions of each devices were verified by experimental and numerical simulation studies, and their improvement and applications are still being investigated. The recent progress in our work is reviewed and perspective of their application to neutron scattering experiments is described. (author)

  18. Neutron collimator design of neutron radiography based on the BNCT facility

    Science.gov (United States)

    Yang, Xiao-Peng; Yu, Bo-Xiang; Li, Yi-Guo; Peng, Dan; Lu, Jin; Zhang, Gao-Long; Zhao, Hang; Zhang, Ai-Wu; Li, Chun-Yang; Liu, Wan-Jin; Hu, Tao; Lü, Jun-Guang

    2014-02-01

    For the research of CCD neutron radiography, a neutron collimator was designed based on the exit of thermal neutron of the Boron Neutron Capture Therapy (BNCT) reactor. Based on the Geant4 simulations, the preliminary choice of the size of the collimator was determined. The materials were selected according to the literature data. Then, a collimator was constructed and tested on site. The results of experiment and simulation show that the thermal neutron flux at the end of the neutron collimator is greater than 1.0×106 n/cm2/s, the maximum collimation ratio (L/D) is 58, the Cd-ratio(Mn) is 160 and the diameter of collimator end is 10 cm. This neutron collimator is considered to be applicable for neutron radiography.

  19. Development of fast neutron radiography system based on portable neutron generator

    Energy Technology Data Exchange (ETDEWEB)

    Yi, Chia Jia, E-mail: gei-i-kani@hotmail.com; Nilsuwankosit, Sunchai, E-mail: sunchai.n@chula.ac.th [Department of Nuclear Engineering, Faculty of Engineering, Chulalongkorn University, Phayathai Rd., Patumwan, Bangkok, THAILAND 10330 (Thailand)

    2016-01-22

    Due to the high installation cost, the safety concern and the immobility of the research reactors, the neutron radiography system based on portable neutron generator is proposed. Since the neutrons generated from a portable neutron generator are mostly the fast neutrons, the system is emphasized on using the fast neutrons for the purpose of conducting the radiography. In order to suppress the influence of X-ray produced by the neutron generator, a combination of a shielding material sandwiched between two identical imaging plates is used. A binary XOR operation is then applied for combining the information from the imaging plates. The raw images obtained confirm that the X-ray really has a large effect and that XOR operation can help enhance the effect of the neutrons.

  20. Development of fast neutron radiography system based on portable neutron generator

    Science.gov (United States)

    Yi, Chia Jia; Nilsuwankosit, Sunchai

    2016-01-01

    Due to the high installation cost, the safety concern and the immobility of the research reactors, the neutron radiography system based on portable neutron generator is proposed. Since the neutrons generated from a portable neutron generator are mostly the fast neutrons, the system is emphasized on using the fast neutrons for the purpose of conducting the radiography. In order to suppress the influence of X-ray produced by the neutron generator, a combination of a shielding material sandwiched between two identical imaging plates is used. A binary XOR operation is then applied for combining the information from the imaging plates. The raw images obtained confirm that the X-ray really has a large effect and that XOR operation can help enhance the effect of the neutrons.

  1. A polyethylene-B4C based concrete for enhanced neutron shielding at neutron research facilities

    Science.gov (United States)

    DiJulio, D. D.; Cooper-Jensen, C. P.; Perrey, H.; Fissum, K.; Rofors, E.; Scherzinger, J.; Bentley, P. M.

    2017-07-01

    We present the development of a specialized concrete for neutron shielding at neutron research facilities, based on the addition of hydrogen atoms in the form of polyethylene and also B4C for enhancing the neutron capture properties of the concrete. We show information on the mechanical properties of the concrete and the neutronics, in particular its relevance to modern spallation neutron sources, such as the European Spallation Source (ESS), currently under construction in Lund, Sweden. The new concrete exhibits a 15% lower mass density, a compressible strength of 50% relative to a standard concrete and a significant increase in performance of shielding against MeV neutrons and lower energies. The concrete could find application at the ESS in for example common shielding components, individual beamline shielding and instrument caves. Initial neutronic tests of the concrete, carried out at Lund University, have also verified the performance in the MeV neutron energy range and the results are presented.

  2. Resin-based composite as a direct esthetic restorative material.

    Science.gov (United States)

    Malhotra, Neeraj; Mala, Kundabala; Acharya, Shashirashmi

    2011-06-01

    The search for an ideal esthetic material for tooth restoration has resulted in significant improvements in both materials and the techniques for using them. Various resin-based composite (RBC) materials have recently been introduced into the market that offer improved esthetic and physical properties. This article reviews RBCs, including their compositions, advantages, and disadvantages, that are contemporary to today's clinical practice as well as those that are under research consideration and/ or in clinical trial phase.

  3. SYNTHESIS AND CHARACTERIZATION OF KRAFT LIGNIN-BASED EPOXY RESINS

    Directory of Open Access Journals (Sweden)

    Nour Eddine El Mansouri

    2011-05-01

    Full Text Available Epoxidization is an interesting way to develop a new application of lignin and therefore to improve its application potential. In this work, kraft lignin-based epoxy resins were obtained by the epoxidization reaction, using the kraft lignin recovered directly from pulping liquor and modified by a methylolation reaction. The methylolated lignins were obtained by the reaction of original kraft lignin with formaldehyde and glyoxal, which is a less volatile and less toxic aldehyde. 1H-NMR spectroscopy showed that methylolated kraft lignin has more hydroxymethyl groups than glyoxalated kraft lignin. For the epoxidization reaction we studied the influence of the lignin:NaOH (w/w ratio, temperature, and time of the reaction on the properties of the prepared epoxidized lignins. The structures of lignin-based epoxy resins were followed by epoxy index test and FTIR spectroscopy. Optimal conditions were obtained for lignin-based epoxy resin produced at lignin/NaOH = 1/3 at 70 ºC for 3h. Thermogravimetry analysis (TGA revealed that the epoxidization enhances the thermal stability of lignins and may allow a wider temperature range for applications with lignin epoxy-PF blends.

  4. Synchrotron based spallation neutron source concepts

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Y.

    1998-07-01

    During the past 20 years, rapid-cycling synchrotrons (RCS) have been used very productively to generate short-pulse thermal neutron beams for neutron scattering research by materials science communities in Japan (KENS), the UK (ISIS) and the US (IPNS). The most powerful source in existence, ISIS in the UK, delivers a 160-kW proton beam to a neutron-generating target. Several recently proposed facilities require proton beams in the MW range to produce intense short-pulse neutron beams. In some proposals, a linear accelerator provides the beam power and an accumulator ring compresses the pulse length to the required {approx} 1 {micro}s. In others, RCS technology provides the bulk of the beam power and compresses the pulse length. Some synchrotron-based proposals achieve the desired beam power by combining two or more synchrotrons of the same energy, and others propose a combination of lower and higher energy synchrotrons. This paper presents the rationale for using RCS technology, and a discussion of the advantages and disadvantages of synchrotron-based spallation sources.

  5. Preparation of liquefied wood-based resins and their application in molding material

    Institute of Scientific and Technical Information of China (English)

    Zhang Qiu-hui; Zhao Guang-jie; Yu Li-li; Jie Shu-jun

    2007-01-01

    To investigate value in use of liquefied wood-based resin applications in molding material, Chinese fir (Cunninghamia lanceolata) and poplar (Populus tomentosa) wood meal were liquefied in phenol. The reactant was co-condensed with formaldehyde to obtain liquefied wood-based resin. For this paper, we investigated the characterization of the resin and its application in molding material. The result shows that the basic properties of liquefied wood-based resin were satisfactory; the bonding strength of plywood prepared with liquefied Chinese fir and liquefied poplar resin can reach 1.54 and 1.00 MPa, respectively. The compression strengths of the molding material prepared with two kinds of liquefied wood resin were 73.01 and 73.58 MPa, almost the same as that of PF resin molding material. The limiting volume swelling of molding material made with liquefied Chinese resin and liquefied poplar resin were 8.5% and 8.3%, thickness swelling rates of water absorption were 3.3% and 4.2%, and the maximum weight ratios of water absorption were 25.9% and 26.2%, respectively. The soil burial test result shows that the weight loss rate of the molding materials made with liquefied Chinese resin and liquefied poplar resin were 8.3% and 9.1% and that of the PF resin molding material was 7.9%. After the soil internment test, the reduction ratio of compression strength of the two kinds of molding material achieved 16.9%and 17.7%, while that of the PF resin molding material was 15.4%. The test results of wood fungi inoculation on the three surfaces of the molding material indicate the breeding rate of molding material prepared with liquefied Chinese resin and liquefied poplar resin were at level 4 and that of PF resin molding material was at level 1 of the ISO standard.

  6. Analysis of tissue reactions to methacrylate resin-based, epoxy resin-based, and zinc oxide-eugenol endodontic sealers.

    Science.gov (United States)

    Scarparo, Roberta Kochenborger; Grecca, Fabiana Soares; Fachin, Elaine Vianna Freitas

    2009-02-01

    The purpose of this study was to investigate the reaction of the subcutaneous connective tissue of rats to methacrylate resin-based sealer (EndoREZ), epoxy resin-based sealer (AH Plus), and zinc oxide-eugenol sealer (EndoFill). Polyethylene tubes containing the test materials were implanted in 18 rats. After 7, 30, and 60 days, tissues were collected for biopsy and fixed and processed for histologic evaluation. Observations were made of the cellular inflammatory component, the fibrous condensation, and the abscess formation. Comparisons between groups and times were made with the Friedman and Kruskall-Wallis tests. EndoREZ and EndoFill sealers showed a more intense and longer-lasting inflammation. With AH Plus, the inflammatory reaction showed a tendency to diminish over time. The only group to show a statistically significant reduction in inflammation during the 60-day period was the control group. None of the materials tested proved to have ideal characteristics for biocompatibility.

  7. Neutron collimator design of neutron radiography based on the BNCT facility

    CERN Document Server

    Yang, XP; Li, YG; Peng, D; Lu, J; Zhang, GL; Zhao, H; Zhang, AW; Li, CY; Liu, WJ; Hu, T; Lv, JG

    2013-01-01

    For the research of CCD neutron radiography, a neutron collimator was designed based on the exit of thermal neutron of the Boron Neutron Capture Therapy (BNCT) reactor. Based on the Geant4 simulations, the preliminary choice of the size of the collimator was determined. The materials were selected according to the literature data. Then, a collimator was constructed and tested on site. The results of experiment and simulation show that the thermal neutron flux at the end of theneutron collimator is greater than 10^6 n/cm^2/s, the maximum collimation ratio (L/D) is 58, the Cd-ratio(Mn) is 160 and the diameter of collimator end is 10 cm. This neutron collimator is considered to be applicable for neutron radiography.

  8. Bulk-filled posterior resin restorations based on stress-decreasing resin technology

    DEFF Research Database (Denmark)

    van Dijken, Jan W.V.; Pallesen, Ulla

    2017-01-01

    This randomized study evaluated a flowable resin composite bulk-fill technique in posterior restorations and compared it intraindividually with a conventional 2-mm resin composite layering technique over a 6-yr follow-up period. Thirty-eight pairs of Class II restorations and 15 pairs of Class I...... restorations were placed in 38 adults. In all cavities a single-step self-etch adhesive (Xeno V) was applied. In the first cavity of each pair, the flowable resin composite (SDR) was placed, in bulk increments of up to 4 mm. The occlusal part was completed with a layer of nanohybrid resin composite (Ceram X...... mono). In the second cavity of each pair, the hybrid resin composite was placed in 2-mm increments. The restorations were evaluated using slightly modified US Public Health Service (USPHS) criteria at baseline and then annually for a time period of 6 yr. After 6 yr, 72 Class II restorations and 26...

  9. Selecting the Best Materials Compositions of Resin Based Bioasphalt

    Science.gov (United States)

    Setyawan, Ary; Widiharjo, Budi; Djumari

    2017-07-01

    Damar asphalt is one type of bioaspal which is a mixture with the main ingredient is a resin as a binder and cooking oil as a solvent. One major drawback of this damar asphalt is the low ductility. To improve the ductility values, then use the added material Filler. Filler serves as a divider between the impurities with damar asphalt, increases ductility and increase the ability of cohesion or bonding between the particles of material damar asphalt. The purpose of this study was to determine damar asphalt modifications to the properties in accordance with the properties of damar asphalt test specifications based on the value of penetration. This method uses some variant on material such as powder bricks and fly ash as a binder. Solvent in constituent used oil and used cooking oil. It also added the polymer latex up to 10% at intervals of 2%. The best composition of damar asphalt materials were obtained with gum rosin, Fly Ash, Oil and Latex. Damar asphalt modification damar asphalt optimum mix of resin (100g pure resin or resin chunk + 350g powder), Fly Ash powder (150g), cooking oil (205g), and latex 4%, ductility increased from 63.5 cm to 119.5 cm, the value of the flash point was originally at temperature of 240 °C to 260 °C, damar asphalt penetration of 68.2 dmm to 43 dmm, and the value of density decreases from 1.01 g / cm3 to 0.99 g / cm3. Damar asphalt at these modifications meet the specifications in terms of solubility in trichlore ethylene is equal to 99.5%, and also meet the affinity of damar asphalt at 99%. With the optimum value, damar asphalt could be categorized as bitumen 40/60 penetration.

  10. Immediate and delayed allergy from epoxy resins based on diglycidyl ether of bisphenol A.

    Science.gov (United States)

    Kanerva, L; Jolanki, R; Tupasela, O; Halmepuro, L; Keskinen, H; Estlander, T; Sysilampi, M L

    1991-06-01

    This case report presents two patients with immediate and delayed allergy to epoxy resins based on diglycidyl ether of bisphenol A (DGEBA). In patch testing, the epoxy resin (DGEBA-based) of the standard series gave allergic reactions. Both patients had a prick test reaction of histamine size or larger to the human serum albumin (HSA) conjugate of DGEBA-based epoxy resins. One had been occupationally exposed to methyl tetrahydrophthalic anhydride (MTHPA) and had a histamine-size prick test reaction to the HSA conjugate of MTHPA; the other did not react to the conjugate. Determinations of specific immunoglobulin E were carried out with HSA-DGEBA conjugates, two DGEBA-based epoxy resins, and phthalic anhydrides. The first patient had positive tests to DGEBA, the DGEBA-based epoxy resins, and two phthalic anhydrides, and the second to DGEBA and the DGEBA-based epoxy resins, but not to the phthalic anhydrides.

  11. Neutron transport study of a beam port based dynamic neutron radiography facility

    Science.gov (United States)

    Khaial, Anas M.

    Neutron radiography has the ability to differentiate between gas and liquid in two-phase flow due both to the density difference and the high neutron scattering probability of hydrogen. Previous studies have used dynamic neutron radiography -- in both real-time and high-speed -- for air-water, steam-water and gas-liquid metal two-phase flow measurements. Radiography with thermal neutrons is straightforward and efficient as thermal neutrons are easier to detect with relatively higher efficiency and can be easily extracted from nuclear reactor beam ports. The quality of images obtained using neutron radiography and the imaging speed depend on the neutron beam intensity at the imaging plane. A high quality neutron beam, with thermal neutron intensity greater than 3.0x 10 6 n/cm2-s and a collimation ratio greater than 100 at the imaging plane, is required for effective dynamic neutron radiography up to 2000 frames per second. The primary objectives of this work are: (1) to optimize a neutron radiography facility for dynamic neutron radiography applications and (2) to investigate a new technique for three-dimensional neutron radiography using information obtained from neutron scattering. In this work, neutron transport analysis and experimental validation of a dynamic neutron radiography facility is studied with consideration of real-time and high-speed neutron radiography requirements. A beam port based dynamic neutron radiography facility, for a target thermal neutron flux of 1.0x107 n/cm2-s, has been analyzed, constructed and experimentally verified at the McMaster Nuclear Reactor. The neutron source strength at the beam tube entrance is evaluated experimentally by measuring the thermal and fast neutron fluxes using copper activation flux-mapping technique. The development of different facility components, such as beam tube liner, gamma ray filter, beam shutter and biological shield, is achieved analytically using neutron attenuation and divergence theories. Monte

  12. Conceptual design of an RFQ accelerator-based neutron source for boron neutron-capture therapy

    Energy Technology Data Exchange (ETDEWEB)

    Wangler, T.P.; Stovall, J.E.; Bhatia, T.S.; Wang, C.K.; Blue, T.E.; Gahbauer, R.A.

    1989-01-01

    We present a conceptual design of a low-energy neutron generator for treatment of brain tumors by boron neutron capture theory (BNCT). The concept is based on a 2.5-MeV proton beam from a radio-frequency quadrupole (RFQ) linac, and the neutrons are produced by the /sup 7/Li(p,n)/sup 7/Be reaction. A liquid lithium target and modulator assembly are designed to provide a high flux of epithermal neutrons. The patient is administered a tumor-specific /sup 10/Be-enriched compound and is irradiated by the neutrons to create a highly localized dose from the reaction /sup 10/B(n,..cap alpha..)/sup 7/Li. An RFQ accelerator-based neutron source for BNCT is compact, which makes it practical to site the facility within a hospital. 11 refs., 5 figs., 1 tab.

  13. Scattered Neutron Tomography Based on A Neutron Transport Inverse Problem

    Energy Technology Data Exchange (ETDEWEB)

    William Charlton

    2007-07-01

    Neutron radiography and computed tomography are commonly used techniques to non-destructively examine materials. Tomography refers to the cross-sectional imaging of an object from either transmission or reflection data collected by illuminating the object from many different directions.

  14. Grazing-Incidence Neutron Optics based on Wolter Geometries

    Science.gov (United States)

    Gubarev, M. V.; Ramsey, B. D.; Mildner, D. F. R.

    2008-01-01

    The feasibility of grazing-incidence neutron imaging optics based on the Wolter geometries have been successfully demonstrated. Biological microscopy, neutron radiography, medical imaging, neutron crystallography and boron neutron capture therapy would benefit from high resolution focusing neutron optics. Two bounce optics can also be used to focus neutrons in SANS experiments. Here, the use of the optics would result in lower values of obtainable scattering angles. The high efficiency of the optics permits a decrease in the minimum scattering vector without lowering the neutron intensity on sample. In this application, a significant advantage of the reflective optics over refractive optics is that the focus is independent of wavelength, so that the technique can be applied to polychromatic beams at pulsed neutron sources.

  15. Experimental Study on Neutron Radiography Device Based on Reactor

    Institute of Scientific and Technical Information of China (English)

    LU; Jin; PENG; Dan; HAO; Qian; YU; Bo-xiang; LI; Yi-guo

    2012-01-01

    <正>Neutron radiography is a non-destructive testing developing fast recently, which requires stable and proper neutron source with low γ background. Neutrons from In-hospital Neutron Irradiator (IHNI) could meet this requirement. Based on the neutron beams of IHNI, a collimator is designed and built for neutron radiography. The experiment results show that in the case of IHNI working at normal rated power, the neutron flux at the end of the collimator is 1.43×106 cm-2·s-1; The max collimation ratio (L/D) is 58; the γ dose rate is 6.3×106 mSv/s. In a word, the collimator could be used for neutron radiography.

  16. Dimensional accuracy and stability of acrylic resin denture bases.

    Science.gov (United States)

    Huggett, R; Zissis, A; Harrison, A; Dennis, A

    1992-10-01

    Proponents of injection molding systems have claimed a number of benefits over conventional press-pack dough molding systems. The aim of this study was to evaluate a recently developed injection (dry heat) procedure of processing compared with press-pack dough molding utilizing three curing cycles. The dimensional accuracy and stability of acrylic resin bases produced by the two molding procedures were compared. Dimensional changes were assessed over a period of 4 months using an optical comparator. The results demonstrate that baseplates produced by the injection molding procedure exhibit less shrinkage than those produced by the conventional press-pack procedures.

  17. Design of a mobile neutron radiography installation based on a compact sealed tube neutron generator

    Institute of Scientific and Technical Information of China (English)

    MaWei-Chao; YaoAn-Ju; 等

    1997-01-01

    A series of optimum conditions are taken into account in the construction of neutron radiography(NR) installation based on a sealed tube neutron generator capable of gnerating 1010 n/s with 14MeV.The characteristics of NNU screens,a kind of self-made 6LiF.ZnS(Ag)scintillation intensifying screen are presented.Finally,some neutron radiographies taken by this NR installation and NNU screens are given.

  18. Effects of Chairside Polishing and Brushing on Surface Roughness of Acrylic Denture Base Resins

    Institute of Scientific and Technical Information of China (English)

    Seung-Kyun Kim; Ju-Mi Park; Min-Ho Lee; Jae-Youn Jung; Shipu Li; Xinyu Wang

    2009-01-01

    The effects of 3 chairside polishing kits and mechanical brushing on the surface roughness of 3 different acrylic denture base resins were compared. Acrylic denture base resins (auto-polymerizing, heat-polymerizing, injected heat-polymerizing resins) were examined after a tungsten carbide bur, and after chairside polishing using 3 polishing kits and pumice. The specimens were subjected to mechanical brushing using a wear tester to simulate 30 000 strokes of brushing. The surface roughness of the acrylic denture base resin specimens was measured using a contact pro-filometer. After the test, the random polished acrylic resins were evaluated by scanning electron mi-croscopy (SEM) and atomic force microscopy (AFM). Acrylic denture base resins polished using the 3 types of polishing kits had a smoother surface than those finished with the tungsten carbide bur (p <0.05). The surface of the resin polished by a TC cutter exceeded the Ra of 0.2 μm (p<0.05). The auto-polymerizing resin showed a significantly higher surface roughness than the heat-polymerizing resin and injected heat-polymerizing resin (p>0.05). In the case of polishing step wise, there was almost no change in surface roughness after brushing (p>0.05).

  19. D301 resin as a solid base for phosphine-free Heck reactions with heteroaryl halides

    Institute of Scientific and Technical Information of China (English)

    Wen Pei; Xiang Mei Wu

    2008-01-01

    A new and practical method of the D301 resin,a weak basic anion exchange resin with secondary amine functionality (Grade Matrix Structure:Styrene-DVB D301R),used as base to Heck reactions catalyzed by palladium reagent without phosphine compound as ligand is described.It was found that the D301 resin used as base is an efficient and reusable base and can be regenerated and recycled in the reaction.The olefination of heteroaryl halides prepared the corresponding products in good yields using D301 resin as base.

  20. Shear bond strength evaluation of resin composite to resin-modified glass-ionomer cement using three different resin adhesives vs. glass-ionomer based adhesive

    Directory of Open Access Journals (Sweden)

    Mostafa Sadeghi

    2015-12-01

    Full Text Available Background: The clinical success of sandwich technique depends on the strength of resin-modified glass ionomer cement (RMGIC bonding to both dentin and resin composite. Therefore, the shear bond strength (SBS of resin composite bonded to RMGIC utilizing different resin adhesives versus a GIC-based adhesive was compared. Materials and methods: In this in vitro study, 84 holes (5×2 mm were prepared in acrylic blocks, randomly divided into seven groups (n=12 and filled with RMGIC (Light-Cured Universal Restorative, GC. In the Group I; no adhesive was applied on the RMGIC. In the Group II, non-etched and Group III was etched with phosphoric acid. In groups II and III, after rinsing, etch-and-rinse adhesive (OptiBond Solo Plus; in the Group IV; a two-step self-etch adhesive (OptiBond XTR and in Group V; a one-step self-etch (OptiBond All-in-One were applied on the cement surfaces. Group VI; a GIC-based adhesive (Fuji Bond LC was painted over the cement surface and cured. Group VII; the GIC-based adhesive was brushed over RMGIC followed by the placement of resin composite and co-cured. Afterward; resin composite (Point 4 cylinders were placed on the treated cement surfaces. The specimens were placed in 100% humidity at 37 ± 1°C and thermo cycled. The shear bond test was performed at a cross-head speed of 1 mm/min and calculated in MPa; the specimens were examined to determine mode of failure. The results were analyzed using one-way ANOVA and Tukey test. Results: The maximum (24.62±3.70 MPa and minimum (18.15±3.38 MPa SBS mean values were recorded for OptiBond XTR adhesive and the control group, respectively. The pairwise comparisons showed no significant differences between the groups that bonded with different adhesives. The adhesive failure was the most common failure mode observed. Conclusion: This study suggests that GIC-based adhesive could be applied over RMGIC as co-cure technique for sandwich restorations in lieu of employing the resin

  1. The influence of urea formaldehyde resins on pyrolysis characteristics and products of wood-based panels

    Directory of Open Access Journals (Sweden)

    Yongshun Feng

    2012-11-01

    Full Text Available In China each year, large amounts of wood-based panels are consumed and abandoned. These are huge resources for energy recovery and materials reuse. In order to study the influence of urea formaldehyde resin (UF resin on waste wood-based panels during pyrolysis, thermobalance experiments together with the evolution of main gaseous products of wood, wood-based panels, and UF resins were carried out and analyzed by TG-FTIR. Elementary and GC-MS analyses were also done to study the characteristics of solid and liquid products. Results from TG and DTG analyses indicated that UF resin used in wood-based panels accelerated the degradation rate of wood-based panels at lower temperature; however the resin inhibited the degradation of wood-based panels over the later stage at higher temperatures. Compared with solid wood, the higher intensity and earlier releasing time of HNCO and NH3 in wood board revealed that the release of nitric gases is mainly due to the presence of UF resin, especially between 180 °C and 320 °C. Mass loss of hydrogen is significantly inhibited by UF resin, and nitrogen is quite stable in the char. The influence of UF resin on pyrolysis liquids of wood-based panels is mainly on nitrogen compounds and ketones rather than aldehydes and esters, which is probably due to the chemical reactions of UF resin with lignin constituent in wood.

  2. Color difference threshold determination for acrylic denture base resins.

    Science.gov (United States)

    Ren, Jiabao; Lin, Hong; Huang, Qingmei; Liang, Qifan; Zheng, Gang

    2015-01-01

    This study aimed to set evaluation indicators, i.e., perceptibility and acceptability color difference thresholds, of color stability for acrylic denture base resins for a spectrophotometric assessing method, which offered an alternative to the visual method described in ISO 20795-1:2013. A total of 291 disk specimens 50±1 mm in diameter and 0.5±0.1 mm thick were prepared (ISO 20795-1:2013) and processed through radiation tests in an accelerated aging chamber (ISO 7491:2000) for increasing times of 0 to 42 hours. Color alterations were measured with a spectrophotometer and evaluated using the CIE L*a*b* colorimetric system. Color differences were calculated through the CIEDE2000 color difference formula. Thirty-two dental professionals without color vision deficiencies completed perceptibility and acceptability assessments under controlled conditions in vitro. An S-curve fitting procedure was used to analyze the 50:50% perceptibility and acceptability thresholds. Furthermore, perceptibility and acceptability against the differences of the three color attributes, lightness, chroma, and hue, were also investigated. According to the S-curve fitting procedure, the 50:50% perceptibility threshold was 1.71ΔE00 (r(2)=0.88) and the 50:50% acceptability threshold was 4.00 ΔE00 (r(2)=0.89). Within the limitations of this study, 1.71/4.00 ΔE00 could be used as perceptibility/acceptability thresholds for acrylic denture base resins.

  3. Surface and line-edge roughness in acid-breakable resin-based positive resist

    Science.gov (United States)

    Sakamizu, Toshio; Shiraishi, Hiroshi

    2003-06-01

    A positive chemical amplification resist based on acid-catalyzed fragmentation of acetal groups in its main-chain has been developed as a means for reducing line-edge roughness. The resist consists of an acid-generator, an acid-diffusion controller and an acid-breakable (AB) resin that is synthesized through a co-condensation reaction between polyphenol and aromatic multi-functional vinylether compound. The effects of the fractionation of AB resins on resin properties and line-edge roughness (LER) are evaluated. Although AB resins have wide molecular-weight distributions, the density of acetal groups in this AB resin is found to be almost constant except in the lower molecular-weight components. The resist with a fractionated resin from which such components removed provides the high resolution of 60-nm line-and-space (L/S) patterns with fairly low LER. AFM analysis shows the surface roughness (SR) for the resist with the fractionated resin is smaller than that for a resist using non-fractionated AB resin, and that the SR value is not altered throughout the range of exposure doses up to just below the beginning of dissolution. By using the fractionated AB resin, the AB resin-based resist (ABR) is capable of forming sub-100 nm L/S patterns with less than 5 nm of LER (3σ).

  4. Neutron Detection Using Gadolinium-Based Diodes

    Science.gov (United States)

    2011-03-01

    U Uranium UNL The University of Nebraska, Lincoln XRD X-Ray Diffraction 1 NEUTRON DETECTION USING GADOLINIUM-BASED DIODES I...detector volume of approximately 3.46x10-6 cm3. 6 4 2 0 2 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Applied BiasV De ple tio nW idt hm  Si SiC 22...Layer deposition on the SiC substrate was confirmed by x-ray diffraction ( XRD ), however, no ellipsometry or other characterization measurements were

  5. Incorporation of antimicrobial macromolecules in acrylic denture base resins: a research composition and update.

    Science.gov (United States)

    Sivakumar, Indumathi; Arunachalam, Kuthalingam Subbiah; Sajjan, Suresh; Ramaraju, Alluri Venkata; Rao, Bheemalingeshwara; Kamaraj, Bindu

    2014-06-01

    Contemporary research in acrylic denture base materials focuses on the development of a novel poly(methyl methacrylate) (PMMA) resin with antimicrobial properties. Although PMMA resin has fulfilled all the requirements of an ideal denture base material, its susceptibility to microbial colonization in the oral environment is a formidable concern to clinicians. Many mechanisms including the absence of ionic charge in the methyl methacrylate resins, hydrophobic interactions, electrostatic interactions, and mechanical attachment have been found to contribute to the formation of biofilm. The present article outlines the basic categories of potential antimicrobial polymer (polymeric biocides) formulations (modified PMMA resins) and considers their applicability, biological status, and usage potential over the coming years.

  6. Anion-exchange resin-based desulfurization process. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Sheth, A C; Dharmapurikar, R; Strevel, S D

    1994-01-01

    The following investigations were performed: (1) batch mode screening of eleven(11) commercially available resins and selection of three candidate resins for further evaluation in a fixed-bed setup. (2) Process variables study using three candidate resins in the fixed-bed setup and selection of the ``best`` resin for process economics development. (3) Exhaustion efficiency and solution concentration were found to be inversely related necessitating a trade-off between the resin cost versus the cost of evaporation/concentration of ensuing effluents. (4) Higher concentration of the HCO{sub 3}{sup {minus}} form of active sites over less active CO{sub 3}{sup 2{minus}} form of sites in the resin was believed to be the main reason for the observed increase in the equilibrium capacity of the resin at an elevated static CO{sub 2}-pressure. This Increase in capacity was found to level off around 80--120 psig range. The increase in CO{sub 2}-pressure, however, did not appear to affect the overall ion-exchange kinetics. (5) In the fixed-bed mode, the solution concentration was found to affect the equilibrium capacity of candidate resins. Their relationship was well satisfied by the Langmuir type non-linear equilibrium isotherm. Alternatively, the effect of solution concentration on overall ion-exchange kinetics varied from resin to resin. (6) Product inhibition effect on the resin was observed as an initial increase followed by a significant decrease in the resin`s equilibrium capacity for SO{sub 4}{sup 2{minus}} as the HCO{sub 3}{sup {minus}}/SO{sub 4}{sup 2{minus}} molar ratio in the solution was increased from 0 to 1.0. This ratio, however, did not affect the overall ion-exchange kinetics.

  7. Anion-exchange resin-based desulfurization process. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Sheth, A C; Dharmapurikar, R; Strevel, S D

    1994-01-01

    The following investigations were performed: (1) batch mode screening of eleven(11) commercially available resins and selection of three candidate resins for further evaluation in a fixed-bed setup. (2) Process variables study using three candidate resins in the fixed-bed setup and selection of the ``best`` resin for process economics development. (3) Exhaustion efficiency and solution concentration were found to be inversely related necessitating a trade-off between the resin cost versus the cost of evaporation/concentration of ensuing effluents. (4) Higher concentration of the HCO{sub 3}{sup {minus}} form of active sites over less active CO{sub 3}{sup 2{minus}} form of sites in the resin was believed to be the main reason for the observed increase in the equilibrium capacity of the resin at an elevated static CO{sub 2}-pressure. This Increase in capacity was found to level off around 80--120 psig range. The increase in CO{sub 2}-pressure, however, did not appear to affect the overall ion-exchange kinetics. (5) In the fixed-bed mode, the solution concentration was found to affect the equilibrium capacity of candidate resins. Their relationship was well satisfied by the Langmuir type non-linear equilibrium isotherm. Alternatively, the effect of solution concentration on overall ion-exchange kinetics varied from resin to resin. (6) Product inhibition effect on the resin was observed as an initial increase followed by a significant decrease in the resin`s equilibrium capacity for SO{sub 4}{sup 2{minus}} as the HCO{sub 3}{sup {minus}}/SO{sub 4}{sup 2{minus}} molar ratio in the solution was increased from 0 to 1.0. This ratio, however, did not affect the overall ion-exchange kinetics.

  8. Improved Fission Neutron Data Base for Active Interrogation of Actinides

    Energy Technology Data Exchange (ETDEWEB)

    Pozzi, Sara; Czirr, J. Bart; Haight, Robert; Kovash, Michael; Tsvetkov, Pavel

    2013-11-06

    This project will develop an innovative neutron detection system for active interrogation measurements. Many active interrogation methods to detect fissionable material are based on the detection of neutrons from fission induced by fast neutrons or high-energy gamma rays. The energy spectrum of the fission neutrons provides data to identify the fissionable isotopes and materials such as shielding between the fissionable material and the detector. The proposed path for the project is as follows. First, the team will develop new neutron detection systems and algorithms by Monte Carlo simulations and bench-top experiments. Next, They will characterize and calibrate detection systems both with monoenergetic and white neutron sources. Finally, high-fidelity measurements of neutron emission from fissions induced by fast neutrons will be performed. Several existing fission chambers containing U-235, Pu-239, U-238, or Th-232 will be used to measure the neutron-induced fission neutron emission spectra. The challenge for making confident measurements is the detection of neutrons in the energy ranges of 0.01 – 1 MeV and above 8 MeV, regions where the basic data on the neutron energy spectrum emitted from fission is least well known. In addition, improvements in the specificity of neutron detectors are required throughout the complete energy range: they must be able to clearly distinguish neutrons from other radiations, in particular gamma rays and cosmic rays. The team believes that all of these challenges can be addressed successfully with emerging technologies under development by this collaboration. In particular, the collaboration will address the area of fission neutron emission spectra for isotopes of interest in the advanced fuel cycle initiative (AFCI).

  9. Fracture strength and fatigue resistance of dental resin-based composites

    NARCIS (Netherlands)

    F. Keulemans; P. Palav; M.M.N. Aboushelib; A. van Dalen; C.J. Kleverlaan; A.J. Feilzer

    2009-01-01

    Objectives: The aim of this study was to evaluate in vitro the influence of fiber-reinforcement on the fracture strength and fatigue resistance of resin-based composites. Methods: One hundred rectangular bar-shaped specimens (2 mm × 2 mm × 25 mm) made of resin-based composite were prepared in a stai

  10. Lithium neutron producing target for BINP accelerator-based neutron source.

    Science.gov (United States)

    Bayanov, B; Belov, V; Kindyuk, V; Oparin, E; Taskaev, S

    2004-11-01

    Pilot innovative accelerator-based neutron source for neutron capture therapy is under construction now at the Budker Institute of Nuclear Physics, Novosibirsk, Russia. One of the main elements of the facility is lithium target, that produces neutrons via threshold (7)Li(p,n)(7)Be reaction at 25 kW proton beam with energies 1.915 or 2.5 MeV. In the present report, the results of experiments on neutron producing target prototype are presented, the results of calculations of hydraulic resistance for heat carrier flow and lithium layer temperature are shown. Calculation showed that the lithium target could run up to 10 mA proton beam before melting. Choice of target variant is substantiated. Program of immediate necessary experiments is described. Target design for neutron source constructed at BINP is presented. Manufacturing the neutron producing target up to the end of 2004 and obtaining a neutron beam on BINP accelerator-based neutron source are planned during 2005.

  11. Lithium neutron producing target for BINP accelerator-based neutron source

    Energy Technology Data Exchange (ETDEWEB)

    Bayanov, B.; Belov, V.; Kindyuk, V.; Oparin, E.; Taskaev, S. E-mail: taskaev@inp.nsk.su

    2004-11-01

    Pilot innovative accelerator-based neutron source for neutron capture therapy is under construction now at the Budker Institute of Nuclear Physics, Novosibirsk, Russia. One of the main elements of the facility is lithium target, that produces neutrons via threshold {sup 7}Li(p,n){sup 7}Be reaction at 25 kW proton beam with energies 1.915 or 2.5 MeV. In the present report, the results of experiments on neutron producing target prototype are presented, the results of calculations of hydraulic resistance for heat carrier flow and lithium layer temperature are shown. Calculation showed that the lithium target could run up to 10 mA proton beam before melting. Choice of target variant is substantiated. Program of immediate necessary experiments is described. Target design for neutron source constructed at BINP is presented. Manufacturing the neutron producing target up to the end of 2004 and obtaining a neutron beam on BINP accelerator-based neutron source are planned during 2005.

  12. APPLICATION OF DIRECT CONTACT TEST IN EVALUATION OF CYTOTOXICITY OF ACRYLIC DENTURE BASE RESINS

    Directory of Open Access Journals (Sweden)

    Milena Kostić

    2012-03-01

    Full Text Available The use of acrylic denture base resins is widely spread in dental practice. They belong to the group of biomaterials due to their role of morphological and functional substituent in the mouth. However, clinical practice has shown that some toxic ingredients of these materials may lead to adverse local and even systemic changes. The aim of the study was to evaluate cytotoxic effect of various denture base resins on cell culture using direct contact test. The effect of four different acrylic materials on HeLa cell structure was evaluated. Upon light microscopy analysis, MTT test was performed without previous removal of material samples. The obtained values of MTT indicate that cell proliferation is dependant on the type of acrylic denture base resins. Cold polymerization denture base resins showed mild inhibitory effect on the cell culture growth. The signs of toxicity were not observed in heat polymerization denture base resins.

  13. Prospect for application of compact accelerator-based neutron source to neutron engineering diffraction

    Science.gov (United States)

    Ikeda, Yoshimasa; Taketani, Atsushi; Takamura, Masato; Sunaga, Hideyuki; Kumagai, Masayoshi; Oba, Yojiro; Otake, Yoshie; Suzuki, Hiroshi

    2016-10-01

    A compact accelerator-based neutron source has been lately discussed on engineering applications such as transmission imaging and small angle scattering as well as reflectometry. However, nobody considers using it for neutron diffraction experiment because of its low neutron flux. In this study, therefore, the neutron diffraction experiments are carried out using Riken Accelerator-driven Compact Neutron Source (RANS), to clarify the capability of the compact neutron source for neutron engineering diffraction. The diffraction pattern from a ferritic steel was successfully measured by suitable arrangement of the optical system to reduce the background noise, and it was confirmed that the recognizable diffraction pattern can be measured by a large sampling volume with 10 mm in cubic for an acceptable measurement time, i.e. 10 min. The minimum resolution of the 110 reflection for RANS is approximately 2.5% at 8 μs of the proton pulse width, which is insufficient to perform the strain measurement by neutron diffraction. The moderation time width at the wavelength corresponding to the 110 reflection is estimated to be approximately 30 μs, which is the most dominant factor to determine the resolution. Therefore, refinements of the moderator system to decrease the moderation time by decreasing a thickness of the moderator or by applying the decoupler system or application of the angular dispersive neutron diffraction technique are important to improve the resolution of the diffraction experiment using the compact neutron source. In contrast, the texture evolution due to plastic deformation was successfully observed by measuring a change in the diffraction peak intensity by RANS. Furthermore, the volume fraction of the austenitic phase in the dual phase mock specimen was also successfully evaluated by fitting the diffraction pattern using a Rietveld code. Consequently, RANS has been proved to be capable for neutron engineering diffraction aiming for the easy access

  14. Simulation of the Resin Film Infusion Process Based on the Finite Element Method

    Institute of Scientific and Technical Information of China (English)

    YANG Mei; YAN Shilin; TAN Hua

    2006-01-01

    A physically accurate and computationally effective pure finite element method (FEM) was developed to simulate the isothermal resin infusing process. The FEM was based on conservation of resin mass at any instant of time and was objective of resin film infusion (RFI) fiber impregnation and mold filling. The developed computer code was able to simulate the resin infusing visually. A numerical example presented here demonstrated that compared with traditional finite element/ control-volume (FE/CV), and FEM was physically accurate and computationally efficient.

  15. Effect of an Extra Hydrophobic Resin Layer on Repair Shear Bond Strength of a Silorane-Based Composite Resin.

    Science.gov (United States)

    Mohammadi, Narmin; Bahari, Mahmoud; Kimyai, Soodabeh; Rahbani Nobar, Behnam

    2015-12-01

    Composite repair is a minimally invasive and conservative approach. This study aimed to evaluate the effect of an additional hydrophobic resin layer on the repair shear bond strength of a silorane-based composite repaired with silorane or methacrylate-based composite. Sixty bar-shaped composite blocks were fabricated and stored in saline for 72 hours. The surface of the samples were roughened by diamond burs and etched with phosphoric acid; then, they were randomly divided into three groups according to the repairing process: Group 1: Silorane composite-silorane bonding agent-silorane composite; group 2: Silorane composite-silorane bonding agent-hydrophobic resin-silorane composite, and group 3: Silorane composite-silorane bonding agent-hydrophobic resin methacrylate-based composite. Repairing composite blocks measured 2.5×2.5×5mm. After repairing, the samples were stored in saline for 24 hours and thermocycled for 1500 cycles. The repair bond strength was measured at a strain rate of 1mm/min. Twenty additional cylindrical composite blocks (diameter: 2.5mm, height: 6mm) were also fabricated for measuring the cohesive strength of silorane-based composite. The data were analyzed using One-way ANOVA and the post hoc Tukey's test (α=0.05). Cohesive bond strength of silorane composite was significantly higher than the repair bond strengths in other groups (Presin layer for repair of silorane-based composite with a methacrylate-based composite enhanced the repair shear bond strength.

  16. Accelerator-based epithermal neutron sources for boron neutron capture therapy of brain tumors.

    Science.gov (United States)

    Blue, Thomas E; Yanch, Jacquelyn C

    2003-01-01

    This paper reviews the development of low-energy light ion accelerator-based neutron sources (ABNSs) for the treatment of brain tumors through an intact scalp and skull using boron neutron capture therapy (BNCT). A major advantage of an ABNS for BNCT over reactor-based neutron sources is the potential for siting within a hospital. Consequently, light-ion accelerators that are injectors to larger machines in high-energy physics facilities are not considered. An ABNS for BNCT is composed of: (1) the accelerator hardware for producing a high current charged particle beam, (2) an appropriate neutron-producing target and target heat removal system (HRS), and (3) a moderator/reflector assembly to render the flux energy spectrum of neutrons produced in the target suitable for patient irradiation. As a consequence of the efforts of researchers throughout the world, progress has been made on the design, manufacture, and testing of these three major components. Although an ABNS facility has not yet been built that has optimally assembled these three components, the feasibility of clinically useful ABNSs has been clearly established. Both electrostatic and radio frequency linear accelerators of reasonable cost (approximately 1.5 M dollars) appear to be capable of producing charged particle beams, with combinations of accelerated particle energy (a few MeV) and beam currents (approximately 10 mA) that are suitable for a hospital-based ABNS for BNCT. The specific accelerator performance requirements depend upon the charged particle reaction by which neutrons are produced in the target and the clinical requirements for neutron field quality and intensity. The accelerator performance requirements are more demanding for beryllium than for lithium as a target. However, beryllium targets are more easily cooled. The accelerator performance requirements are also more demanding for greater neutron field quality and intensity. Target HRSs that are based on submerged-jet impingement and

  17. Neutron flux assessment of a neutron irradiation facility based on inertial electrostatic confinement fusion.

    Science.gov (United States)

    Sztejnberg Gonçalves-Carralves, M L; Miller, M E

    2015-12-01

    Neutron generators based on inertial electrostatic confinement fusion were considered for the design of a neutron irradiation facility for explanted organ Boron Neutron Capture Therapy (BNCT) that could be installed in a health care center as well as in research areas. The chosen facility configuration is "irradiation chamber", a ~20×20×40 cm(3) cavity near or in the center of the facility geometry where samples to be irradiated can be placed. Neutron flux calculations were performed to study different manners for improving scattering processes and, consequently, optimize neutron flux in the irradiation position. Flux distributions were assessed through numerical simulations of several models implemented in MCNP5 particle transport code. Simulation results provided a wide spectrum of combinations of net fluxes and energy spectrum distributions. Among them one can find a group that can provide thermal neutron fluxes per unit of production rate in a range from 4.1·10(-4) cm(-2) to 1.6·10(-3) cm(-2) with epithermal-to-thermal ratios between 0.3% and 13% and fast-to-thermal ratios between 0.01% to 8%. Neutron generators could be built to provide more than 10(10) n s(-1) and, consequently, with an arrangement of several generators appropriate enough neutron fluxes could be obtained that would be useful for several BNCT-related irradiations and, eventually, for clinical practice.

  18. Synthesis and Characterization of Bio-Oil Phenol Formaldehyde Resin Used to Fabricate Phenolic Based Materials.

    Science.gov (United States)

    Cui, Yong; Hou, Xiaopeng; Wang, Wenliang; Chang, Jianmin

    2017-06-18

    In this study, bio-oil from the fast pyrolysis of renewable biomass was used as the raw material to synthesize bio-oil phenol formaldehyde (BPF) resin-a desirable resin for fabricating phenolic-based material. During the synthesis process, paraformaldehyde was used to achieve the requirement of high solid content and low viscosity. The properties of BPF resins were tested. Results indicated that BPF resin with the bio-oil addition of 20% had good performance on oxygen index and bending strength, indicating that adding bio-oil could modify the fire resistance and brittleness of PF resin. The thermal curing behavior and heat resistance of BPF resins were investigated by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). Results showed that adding bio-oil had an impact on curing characteristics and thermal degradation process of PF resin, but the influence was insignificant when the addition was relatively low. The chemical structure and surface characteristics of BPF resins were determined by Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). The analysis demonstrated that adding bio-oil in the amount of 20% was able to improve the crosslinking degree and form more hydrocarbon chains in PF resin.

  19. Neutron Sources for Standard-Based Testing

    Energy Technology Data Exchange (ETDEWEB)

    Radev, Radoslav [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); McLean, Thomas [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2014-11-10

    The DHS TC Standards and the consensus ANSI Standards use 252Cf as the neutron source for performance testing because its energy spectrum is similar to the 235U and 239Pu fission sources used in nuclear weapons. An emission rate of 20,000 ± 20% neutrons per second is used for testing of the radiological requirements both in the ANSI standards and the TCS. Determination of the accurate neutron emission rate of the test source is important for maintaining consistency and agreement between testing results obtained at different testing facilities. Several characteristics in the manufacture and the decay of the source need to be understood and accounted for in order to make an accurate measurement of the performance of the neutron detection instrument. Additionally, neutron response characteristics of the particular instrument need to be known and taken into account as well as neutron scattering in the testing environment.

  20. Effect of denture base-resin with prereacted glass-ionomer filler on dentin demineralization

    NARCIS (Netherlands)

    Y. Mukai; K. Kamijo; F. Fujino; T. Teranaka; J.M. ten Cate

    2009-01-01

    The demineralization of dentin was studied when placed adjacent to one of four experimental denture base-resins. These experimental resins contained polymethylmethacrylate (PMMA) and 0, 5, 10, 20 or 30 wt% surface reaction-type prereacted glass-ionomer (S-PRG) filler, respectively. A dentin thin-sec

  1. Neutron-based sterilization of anthrax contamination.

    Science.gov (United States)

    Liu, Bin; Wang, Qingfei

    2006-05-01

    With the anthrax threat becoming a reality, it is very important to have an effective way to sterilize areas contaminated by anthrax. Anthrax spores are the dormant form of the anthrax bacteria. They can germinate in tissues, producing new bacteria that release lethal toxins. Neutrons can be a powerful tool in our defense against anthrax contamination. Neutrons are elementary particles that have no charge, which allows them to be very penetrating, killing the anthrax spores on the surface and inside the containers. So neutrons have an advantage over other forms of radiation if deep penetration is required to kill biological organisms. A Cf neutron source allows for a low cost method of decontamination. It emits most neutrons in the 100 keV to 2 MeV energy regions, and a neutron in this energy region is 20 times more deadly than electrons or gamma rays in killing anthrax spores. If we just consider the first neutron collision with anthrax spores and that all the anthrax spores will not survive at the dose level above 2.0 x 10 Gy, our calculations show that a 0.5-g Cf neutron source within 20 min can generate 1.11 x 10 m fluence neutrons, which is good enough to kill the anthrax spores on the sample. An experimental confirmation of the above results may prove that to achieve 1.11 x 10 m fluence neutrons on the anthrax spore sample, the neutron irradiation time may be reduced dramatically or the Cf neutron source reduced to 0.1 g level or even less. The aim of this paper is to evaluate a feasible way to sterilize the anthrax contamination by using a Cf neutron source. Presently, we are mainly concentrating on the theoretical estimation of neutron fluence to see if the Cf neutron source can deliver enough neutron irradiation dose to kill the anthrax spores. Our future work will focus on experimental confirmation and Monte Carlo simulation by using Geant4 or MCNP codes. At that time, we will consider the effects of the real experimental setup, the shielding materials

  2. Study of a gold-foil-based multisphere neutron spectrometer.

    Science.gov (United States)

    Wang, Z; Hutchinson, J D; Hertel, N E; Burgett, E; Howell, R M

    2008-01-01

    Multisphere neutron spectrometers with active thermal neutron detectors cannot be used in high-intensity radiation fields due to pulse pile-up and dead-time effects. Thus, a multisphere spectrometer using a passive detection system, specifically gold foils, has been investigated in this work. The responses of a gold-foil-based Bonner sphere neutron spectrometer were studied for two different gold-foil holder designs; an aluminium-polyethylene holder and a polyethylene holder. The responses of the two designs were calculated for four incident neutron beam directions, namely, parallel, perpendicular and at +/-45 degrees relative to the flat surface of the foil. It was found that the use of polyethylene holder resulted in a more isotropic response to neutrons for the four incident directions considered. The computed responses were verified by measuring the neutron spectrum of a 252Cf source with known strength.

  3. Spectrum shaping of accelerator-based neutron beams for BNCT

    CERN Document Server

    Montagnini, B; Esposito, J; Giusti, V; Mattioda, F; Varone, R

    2002-01-01

    We describe Monte Carlo simulations of three facilities for the production of epithermal neutrons for Boron Neutron Capture Therapy (BNCT) and examine general aspects and problems of designing the spectrum-shaping assemblies to be used with these neutron sources. The first facility is based on an accelerator-driven low-power subcritical reactor, operating as a neutron amplifier. The other two facilities have no amplifier and rely entirely on their primary sources, a D-T fusion reaction device and a conventional 2.5 MeV proton accelerator with a Li target, respectively.

  4. Attribute Based Selection of Thermoplastic Resin for Vacuum Infusion Process: A Decision Making Methodology

    DEFF Research Database (Denmark)

    Raghavalu Thirumalai, Durai Prabhakaran; Lystrup, Aage; Løgstrup Andersen, Tom

    2012-01-01

    The composite industry looks toward a new material system (resins) based on thermoplastic polymers for the vacuum infusion process, similar to the infusion process using thermosetting polymers. A large number of thermoplastics are available in the market with a variety of properties suitable...... for different engineering applications, and few of those are available in a not yet polymerised form suitable for resin infusion. The proper selection of a new resin system among these thermoplastic polymers is a concern for manufactures in the current scenario and a special mathematical tool would...... be beneficial. In this paper, the authors introduce a new decision making tool for resin selection based on significant attributes. This article provides a broad overview of suitable thermoplastic material systems for vacuum infusion process available in today’s market. An illustrative example—resin selection...

  5. [Current status and further prospects of dental resin-based materials with antibacterial properties].

    Science.gov (United States)

    Shi, X; Lu, H B; Mao, J; Gong, S Q

    2016-09-01

    The mode of dental antibacterial resin-based materials can be divided into two types, namely, single and combined antibacterial mode. With regard to single antibacterial mode, only one kind of antibacterial agent is added into the resin, which can be released or act as contacting antibacterial agent. The single mode resin has limitation in sterilization methods and effect. As for combined antibacterial mode, it is a combination of different types of biocides and thus maximizes the sterilizing effect, including the releasing antibacterial agent incorporated with the contacting antibacterial agent or antibacterial agents combined with calcium compound possessing biological mineralization function. In this paper, current status and further prospects of dental resin-based materials with antibacterial properties are reviewed from the perspectives of single and combined antibacterial modes to provide guidance for dental antibacterial resin material research.

  6. Factors affecting the bond strength of denture base and reline acrylic resins to base metal materials

    Directory of Open Access Journals (Sweden)

    Naomi Tanoue

    2013-07-01

    Full Text Available OBJECTIVE: The shear bond strengths of two hard chairside reline resin materials and an auto-polymerizing denture base resin material to cast Ti and a Co-Cr alloy treated using four conditioning methods were investigated. MATERIAL AND METHODS: Disk specimens (diameter 10 mm and thickness 2.5 mm were cast from pure Ti and Co-Cr alloy. The specimens were wet-ground to a final surface finish of 600 grit, air-dried, and treated with the following bonding systems: 1 air-abraded with 50-70-µm grain alumina (CON; 2 1 + conditioned with a primer, including an acidic phosphonoacetate monomer (MHPA; 3 1 + conditioned with a primer including a diphosphate monomer (MDP; 4 treated with a tribochemical system. Three resin materials were applied to each metal specimen. Shear bond strengths were determined before and after 10,000 thermocycles. RESULTS: The strengths decreased after thermocycling for all combinations. Among the resin materials assessed, the denture base material showed significantly (p<0.05 greater shear bond strengths than the two reline materials, except for the CON condition. After 10,000 thermocycles, the bond strengths of two reline materials decreased to less than 10 MPa for both metals. The bond strengths of the denture base material with MDP were sufficient: 34.56 MPa for cast Ti and 38.30 for Co-Cr alloy. CONCLUSION: Bonding of reline resin materials to metals assessed was clinically insufficient, regardless of metal type, surface treatment, and resin composition. For the relining of metal denture frameworks, a denture base material should be used.

  7. Thermal Neutron Imaging Using A New Pad-Based Position Sensitive Neutron Detector

    Energy Technology Data Exchange (ETDEWEB)

    Dioszegi I.; Vanier P.E.; Salwen C.; Chichester D.L.; Watson S.M.

    2016-10-29

    Thermal neutrons (with mean energy of 25 meV) have a scattering mean free path of about 20 m in air. Therefore it is feasible to find localized thermal neutron sources up to ~30 m standoff distance using thermal neutron imaging. Coded aperture thermal neutron imaging was developed in our laboratory in the nineties, using He-3 filled wire chambers. Recently a new generation of coded-aperture neutron imagers has been developed. In the new design the ionization chamber has anode and cathode planes, where the anode is composed of an array of individual pads. The charge is collected on each of the individual 5x5 mm2 anode pads, (48x48 in total, corresponding to 24x24 cm2 sensitive area) and read out by application specific integrated circuits (ASICs). The high sensitivity of the ASICs allows unity gain operation mode. The new design has several advantages for field deployable imaging applications, compared to the previous generation of wire-grid based neutron detectors. Among these are the rugged design, lighter weight and use of non-flammable stopping gas. For standoff localization of thermalized neutron sources a low resolution (11x11 pixel) coded aperture mask has been fabricated. Using the new larger area detector and the coarse resolution mask we performed several standoff experiments using moderated californium and plutonium sources at Idaho National Laboratory. In this paper we will report on the development and performance of the new pad-based neutron camera, and present long range coded-aperture images of various thermalized neutron sources.

  8. Improved Neutron Scintillators Based on Nanomaterials

    Energy Technology Data Exchange (ETDEWEB)

    Dennis Friesel, PhD

    2008-06-30

    The development work conducted in this SBIR has so far not supported the premise that using nano-particles in LiFZnS:Ag foils improves their transparency to 420 (or other frequency) light. This conclusion is based solely on the light absorption properties of LiFZnS foils fabricated from nano- and from micro-particles. Furthermore, even for the case of the Gd{sub 2}O{sub 3} foils, the transmission of 420 nm light gained by using nano-particles all but disappears as the foil thickness is increased beyond about 0.2 mm, a practical scintillator thickness. This was not immediately apparent from the preliminary study since no foils thicker than about 0.04 mm were produced. Initially it was believed that the failure to see an improvement by using nano-particles for the LiFZnS foils was caused by the clumping of the particles in Toluene due to the polarity of the ZnS particles. However, we found, much to our surprise, that nano-particle ZnS alone in polystyrene, and in Epoxy, had worse light transmission properties than the micro-particle foils for equivalent thickness and density foils. The neutron detection measurements, while disappointing, are attributable to our inability to procure or fabricate Bulk Doped ZnS nanoparticles. The cause for the failure of nano-particles to improve the scintillation light, and hence improved neutron detection efficiency, is a fundamental one of light scattering within the scintillator. A consequence of PartTec's documentation of this is that several concepts for the fabrication of improved {sup 6}LiFZnS scintillators were formulated that will be the subject of a future SBIR submission.

  9. Evaluation of Cellular Toxicity of Three Denture Base Acrylic Resins

    OpenAIRE

    Ebrahimi Saravi, M.; M. Vojdani; Bahrani, F

    2012-01-01

    Objective This study aimed to evaluate the cellular toxicity of two newly-released acrylic resins (Futura Gen and GC Reline Hard) in comparison with the conventional heat-cure resin (Meliodent). Materials and Methods: Sample discs from each acrylic resin were placed in 24-well culture plates along with L929 mouse fibroblast cell line. A mixture of the RPMI 1640 medium, antibiotics and 10% FBS was added to the plates and the specimens were incubated in a CO2 incubator. The amount of light abso...

  10. Development of melamine modified urea formaldehyde resins based o nstrong acidic pH catalyzed urea formaldehyde polymer

    Science.gov (United States)

    Chung-Yun Hse

    2009-01-01

    To upgrade the performance of urea-formaldehyde (UF) resin bonded particleboards, melamine modified urea-formaldehyde (MUF) resins based on strong acidic pH catalyzed UF polymers were investigated. The study was conducted in a series of two experiments: 1) formulation of MUF resins based on a UF polymer catalyzed with strong acidic pH and 2) determination of the...

  11. Evaluation of Shear Bond Strength of Methacrylate- and Silorane-based Composite Resin Bonded to Resin-Modified Glass-ionomer Containing Micro- and Nano-hydroxyapatite.

    Science.gov (United States)

    Sharafeddin, Farahnaz; Moradian, Marzie; Motamedi, Mehran

    2016-06-01

    The adhesion of resin-modified glass-ionomer (RMGI) to composite resin has a very important role in the durability of sandwich restorations. Hydroxyapatite is an excellent candidate as a filler material for improving the mechanical properties of glass ionomer cement. The aim of this study was to assess the effect of adding micro- and nano-hydroxyapatite (HA) powder to RMGI on the shear bond strength (SBS) of nanofilled and silorane-based composite resins bonded to RMGI containing micro- and nano-HA. Sixty cylindrical acrylic blocks containing a hole of 5.5×2.5 mm (diameter × height) were prepared and randomly divided into 6 groups as Group 1 with RMGI (Fuji II LC) plus Adper Single Bond/Z350 composite resin (5.5×3.5 mm diameter × height); Group 2 with RMGI containing 25 wt% of micro-HA plus Adper Single Bond/Z350 composite resin; Group3 with RMGI containing 25 wt% of nano-HA plus Adper Single Bond/Z350 composite resin; Group 4 with RMGI plus P90 System Adhesive/P90 Filtek composite resin (5.5×3.5 mm diameter × height); Group 5 with RMGI containing 25 wt% of micro-HA plus P90 System Adhesive/P90Filtek composite resin; and Group 6 with RMGI containing 25 wt% of nano-HA plus P90 System Adhesive/P90 Filtek composite resin. The specimens were stored in water (37° C, 1 week) and subjected to 1000 thermal cycles (5°C/55°C). SBS test was performed by using a universal testing machine at a crosshead speed of 1 mm/min. Data were analyzed by two-way ANOVA and Tukey test (pcomposite resins. Meanwhile, RMGI without HA has the best bond strength to silorane-based composite resins.

  12. Optimization of an accelerator-based epithermal neutron source for neutron capture therapy

    Energy Technology Data Exchange (ETDEWEB)

    Kononov, O.E.; Kononov, V.N.; Bokhovko, M.V.; Korobeynikov, V.V.; Soloviev, A.N.; Chu, W.T.

    2004-02-20

    A modeling investigation was performed to choose moderator material and size for creating optimal epithermal neutron beams for BNCT based on a proton accelerator and the 7Li(p,n)7Be reaction as a neutrons source. An optimal configuration is suggested for the beam shaping assembly made from polytetrafluoroethylene and magnesium fluorine. Results of calculation were experimentally tested and are in good agreement with measurements.

  13. On the limit of neutron fluxes in the fission-based pulsed neutron sources

    Science.gov (United States)

    Aksenov, V. L.; Ananiev, V. D.; Komyshev, G. G.; Rogov, A. D.; Shabalin, E. P.

    2017-09-01

    The upper limit of the density of the thermal neutron flux from pulsed sources based on the fission reaction is established. Three types of sources for research on ejected beams are considered: a multiplying target of the proton accelerator (a booster), a booster with the reactivity modulation (a superbooster), and a pulsing reactor. Comparison with other high-flux sources is carried out. The investigation has been performed at the Frank Laboratory of Neutron Physics of JINR.

  14. Is the bond between acrylic resin denture teeth and denture base resin stronger if they are both made by the same manufacturer?

    Science.gov (United States)

    Patil, Reshma; Juszczyk, Andrzej S; Radford, David R; Clark, Robert K F

    2010-03-01

    A previous study suggested that a stronger bond may be achieved between acrylic resin denture base material and acrylic denture teeth when both are made by the same manufacturer. Three denture base acrylic resins from three different manufacturers were bonded to three different acrylic resin denture teeth, one of which was manufactured by each of the manufacturers of the base material. In each group there was a trend that the bond strength achieved between the teeth and base material from the same manufacturer was higher than the unmatched pairs but statistical significance was not achieved.

  15. Evaluation of thermal neutron irradiation field using a cyclotron-based neutron source for alpha autoradiography.

    Science.gov (United States)

    Tanaka, H; Sakurai, Y; Suzuki, M; Masunaga, S; Mitsumoto, T; Kinashi, Y; Kondo, N; Narabayashi, M; Nakagawa, Y; Watanabe, T; Fujimoto, N; Maruhashi, A; Ono, K

    2014-06-01

    It is important to measure the microdistribution of (10)B in a cell to predict the cell-killing effect of new boron compounds in the field of boron neutron capture therapy. Alpha autoradiography has generally been used to detect the microdistribution of (10)B in a cell. Although it has been performed using a reactor-based neutron source, the realization of an accelerator-based thermal neutron irradiation field is anticipated because of its easy installation at any location and stable operation. Therefore, we propose a method using a cyclotron-based epithermal neutron source in combination with a water phantom to produce a thermal neutron irradiation field for alpha autoradiography. This system can supply a uniform thermal neutron field with an intensity of 1.7×10(9) (cm(-2)s(-1)) and an area of 40mm in diameter. In this paper, we give an overview of our proposed system and describe a demonstration test using a mouse liver sample injected with 500mg/kg of boronophenyl-alanine.

  16. Characterisation of Rapeseed Oil Based Resins Using Infrared and ...

    African Journals Online (AJOL)

    Rapeseed oil which is a triglyceride had undergone chemical modification ... methylene-pphenyl diisocyanate to produce a thermoset rapeseed oil resin. ... The applications of more than one analytical method offer a complement of the results.

  17. Modification Bituminous Binders Petroleum Resin (Based on C9 Fraction

    Directory of Open Access Journals (Sweden)

    Elena A. Chigorina

    2015-12-01

    Full Text Available The goal of the present study is to measure the basic parameters of a bituminous binder obtained by modification of the BND 60/90 binder with petroleum resin, for both dynamic and static modification modes.

  18. Furfural resin-based bio-nanocomposites reinforced by reactive nanocrystalline cellulose

    Science.gov (United States)

    Wang, C.; Sun, S.; Zhao, G.; He, B.; Xiao, H.

    2009-07-01

    The work presented herein has been focused on reinforcing the furfural resins (FA) by reactive-modified nanocrystalline cellulose (NCC) in an attempt to create a bio-nanocomposite completely based on natural resources. FA prepolymers were synthesized with an acid catalyst, and NCC was rendered reactive via the grafting of maleic anhydride (MAH). The resulting NCC and nanocomposites were characterized using TEM, SEM and FT-IR. It was found that NCC appeared to be spherical in shape with diameters under 100 nm. FT-IR confirmed that there were hydrogen and esterification bonding between MAH and NCC or FA prepolymer. After solidified with paratoluenesulfonic acid, NCC-reinforced FA resin composites showed granular cross-section while FA resin with layered structures. Mechanical property tests indicated that NCC-reinforced FA resin composites possessed the improved tensile and flexural strengths, in comparison with FA resin.

  19. Novel Epoxy Resin/SiO2 Nanocomposites Preparation Method Based on Diminutive Bubbles Explosion

    Institute of Scientific and Technical Information of China (English)

    NIE Peng; ZHAO Xue-zeng; CHEN Fang; WANG Wei-jie; BAI Yong-ping

    2006-01-01

    To obtain suspended dispersion of nano-particles in liquid without any dispersant, a novel epoxy resin/SiO2 nanocomposites preparation method based on diminutive bubbles explosion is presented. And, corresponding nanocomposites preparation system was designed. The preparation system applies compressed gas as transmission medium to carry nanomaterials into epoxy resin solution. The compressed gas with nanomaterials turns into diminutive bubbles distributing in epoxy resin/SiO2. The great pressure difference between inner and outer-bubbles led to bubbles inflation and explosion. During the bubble inflation, bubble oscillation may generate. The stretching rate may reach 106 s-1, which favors more homogeneous dispersion of nanoparticles. During the bubbles explosion the released energy and the explosion shock waves disperse the nanoparticles into epoxy resin solution. By using the preparation system, epoxy resin/SiO2 nanocomposites were prepared. The SiO2 dispersed into epoxy as the configuration of 15 nm - 30 nm particles.

  20. Phenol resin-based supports of inclined workings

    Energy Technology Data Exchange (ETDEWEB)

    Boldin, V.M.; Krivoshchekova, N.P.; Fedorova, G.G.

    1980-10-01

    This article evaluates experimental tubing supports produced in the Kuzbass. The tubings are formed from coal and phenol-formaldehyde resins. Benzene sulfonic acid is used as hardening agent. Coal with grains up to 10 mm is used as filling agent. Five phenol-formaldehyde resins (SFZh-3032U, SF-142, SF-40K0, SFZh-3032NV, SFZh-3032) are evaluated as the basis for support production. The results are given in a table. Experiments show that SFZh-3032 resin is superior to other resins as a means of improving strength and mechanical parameters of the coal body in which workings are driven. It is noted that until now 10 km of resin reinforced coal tubing support have been constructed. Capacity of equipment producing the supports is 2.5 km/year. Resin reinforced tubing is economical: it need not be removed, can be mined together with coal seam, it reduces hazard of wall or floor swelling, increases haulage capacity of workings used for underground haulage 3 to 4 times, and improves safety of work for miners. (In Russian)

  1. Neutron counter based on beryllium activation

    Energy Technology Data Exchange (ETDEWEB)

    Bienkowska, B.; Prokopowicz, R.; Kaczmarczyk, J.; Paducha, M. [Institute of Plasma Physics and Laser Microfusion (IPPLM), Hery 23, 01-497 Warsaw (Poland); Scholz, M.; Igielski, A. [Institute of Nuclear Physics PAS (IFJPAN), Radzikowskiego 152, 31-342 Krakow (Poland); Karpinski, L. [Faculty of Electrical Engineering, Rzeszow University of Technology, Pola 2, 35-959 Rzeszow (Poland); Pytel, K. [National Centre for Nuclear Research (NCBJ), Soltana 7, 05-400 Otwock - Swierk (Poland)

    2014-08-21

    The fusion reaction occurring in DD plasma is followed by emission of 2.45 MeV neutrons, which carry out information about fusion reaction rate and plasma parameters and properties as well. Neutron activation of beryllium has been chosen for detection of DD fusion neutrons. The cross-section for reaction {sup 9}Be(n, α){sup 6}He has a useful threshold near 1 MeV, which means that undesirable multiple-scattered neutrons do not undergo that reaction and therefore are not recorded. The product of the reaction, {sup 6}He, decays with half-life T{sub 1/2} = 0.807 s emitting β{sup −} particles which are easy to detect. Large area gas sealed proportional detector has been chosen as a counter of β–particles leaving activated beryllium plate. The plate with optimized dimensions adjoins the proportional counter entrance window. Such set-up is also equipped with appropriate electronic components and forms beryllium neutron activation counter. The neutron flux density on beryllium plate can be determined from the number of counts. The proper calibration procedure needs to be performed, therefore, to establish such relation. The measurements with the use of known β–source have been done. In order to determine the detector response function such experiment have been modeled by means of MCNP5–the Monte Carlo transport code. It allowed proper application of the results of transport calculations of β{sup −} particles emitted from radioactive {sup 6}He and reaching proportional detector active volume. In order to test the counter system and measuring procedure a number of experiments have been performed on PF devices. The experimental conditions have been simulated by means of MCNP5. The correctness of simulation outcome have been proved by measurements with known radioactive neutron source. The results of the DD fusion neutron measurements have been compared with other neutron diagnostics.

  2. Neutron counter based on beryllium activation

    Science.gov (United States)

    Bienkowska, B.; Prokopowicz, R.; Scholz, M.; Kaczmarczyk, J.; Igielski, A.; Karpinski, L.; Paducha, M.; Pytel, K.

    2014-08-01

    The fusion reaction occurring in DD plasma is followed by emission of 2.45 MeV neutrons, which carry out information about fusion reaction rate and plasma parameters and properties as well. Neutron activation of beryllium has been chosen for detection of DD fusion neutrons. The cross-section for reaction 9Be(n, α)6He has a useful threshold near 1 MeV, which means that undesirable multiple-scattered neutrons do not undergo that reaction and therefore are not recorded. The product of the reaction, 6He, decays with half-life T1/2 = 0.807 s emitting β- particles which are easy to detect. Large area gas sealed proportional detector has been chosen as a counter of β-particles leaving activated beryllium plate. The plate with optimized dimensions adjoins the proportional counter entrance window. Such set-up is also equipped with appropriate electronic components and forms beryllium neutron activation counter. The neutron flux density on beryllium plate can be determined from the number of counts. The proper calibration procedure needs to be performed, therefore, to establish such relation. The measurements with the use of known β-source have been done. In order to determine the detector response function such experiment have been modeled by means of MCNP5-the Monte Carlo transport code. It allowed proper application of the results of transport calculations of β- particles emitted from radioactive 6He and reaching proportional detector active volume. In order to test the counter system and measuring procedure a number of experiments have been performed on PF devices. The experimental conditions have been simulated by means of MCNP5. The correctness of simulation outcome have been proved by measurements with known radioactive neutron source. The results of the DD fusion neutron measurements have been compared with other neutron diagnostics.

  3. Design for an accelerator-based orthogonal epithermal neutron beam for boron neutron capture therapy.

    Science.gov (United States)

    Allen, D A; Beynon, T D; Green, S

    1999-01-01

    This paper is concerned with the proposed Birmingham accelerator-based epithermal neutron beam for boron neutron capture therapy (BNCT). In particular, the option of producing a therapy beam at an orthogonal direction to the incoming protons is considered. Monte Carlo radiation transport simulations, both with and without a head phantom, have shown that an orthogonal beam geometry is not only acceptable but is indeed beneficial, in terms of a lower mean neutron energy and an enhanced therapeutic ratio for the same useful neutron fluence in the therapy beam. Typical treatment times for various beam options have been calculated, and range from 20 to 48 min with a 5 mA beam of 2.8 MeV protons, if the maximum photon-equivalent dose delivered to healthy tissue is to be 12.6 Gy Eq. The effects of proton beam diameter upon the therapy beam parameters have also been considered.

  4. On accelerator-based neutron sources and neutron field characterization with low energy neutron spectrometer based on position sensitive 3He counter.

    Science.gov (United States)

    Murata, I; Miyamaru, H; Kato, I; Mori, Y

    2009-07-01

    The development of new neutron sources for BNCT applications, based on particle accelerators is currently underway all over the world. Though nuclear reactors were used for a long time as the only neutron source available having the requested flux levels, the accelerator-based ones have recently been investigated on the other hand due to its easy-to-use and acceptable performances. However, when using an accelerator, various secondary particles would be emitted which forms a troublesome background. Moreover, the neutrons produced have usually an energy spectrum somewhat different from the requested one and thus should be largely moderated. An additional issue to be taken into account is the patient positioning, which should be close to the neutron source, in order to take advantage of a neutron flux level high enough to limit the BNCT treatment time within 1h. This implies that, inside a relatively narrow space, neutrons should be moderated, while unnecessary secondary particles should be shielded. Considering that a background-free neutron field from an accelerator-driven neutron source dedicated to BNCT application is generally difficult to be provided, the characterization of such a neutron field will have to be clearly assessed. In the present study, a low energy neutron spectrometer has been thus designed and is now being developed to measure the accelerator-based neutron source performance. The presently proposed spectrometer is based on a (3)He proportional counter, which is 50 cm long and 5 cm in diameter, with a gas pressure of 0.5 MPa. It is quite unique that the spectrometer is set up in parallel with the incident neutron beam and a reaction depth distribution is measured by it as a position sensitive detector. Recently, a prototype detector has been developed and the signal test is now underway. In this paper, the feature of the accelerator-based neutron sources is outlined and importance of neutron field characterization is discussed. And the developed

  5. Feasibility study on epithermal neutron field for cyclotron-based boron neutron capture therapy.

    Science.gov (United States)

    Yonai, Shunsuke; Aoki, Takao; Nakamura, Takashi; Yashima, Hiroshi; Baba, Mamoru; Yokobori, Hitoshi; Tahara, Yoshihisa

    2003-08-01

    To realize the accelerator-based boron neutron capture therapy (BNCT) at the Cyclotron and Radioisotope Center of Tohoku University, the feasibility of a cyclotron-based BNCT was evaluated. This study focuses on optimizing the epithermal neutron field with an energy spectrum and intensity suitable for BNCT for various combinations of neutron-producing reactions and moderator materials. Neutrons emitted at 90 degrees from a thick (stopping-length) Ta target, bombarded by 50 MeV protons of 300 microA beam current, were selected as a neutron source, based on the measurement of angular distributions and neutron energy spectra. As assembly composed of iron, AlF3/Al/6LiF, and lead was chosen as moderators, based on the simulation trials using the MCNPX code. The depth dose distributions in a cylindrical phantom, calculated with the MCNPX code, showed that, within 1 h of therapeutic time, the best moderator assembly, which is 30-cm-thick iron, 39-cm-thick AlF3/Al/6LiF, and 1-cm-thick lead, provides an epithermal neutron flux of 0.7 x 10(9) [n cm(-2) s(-1)]. This results in a tumor dose of 20.9 Gy-eq at a depth of 8 cm in the phantom, which is 6.4 Gy-eq higher than that of the Brookhaven Medical Research Reactor at the equivalent condition of maximum normal tissue tolerance. The beam power of the cyclotron is 15 kW, which is much lower than other accelerator-based BNCT proposals.

  6. Elastic modulus and flexural strength comparisons of high-impact and traditional denture base acrylic resins

    Directory of Open Access Journals (Sweden)

    Nour M. Ajaj-ALKordy

    2014-01-01

    Conclusion: Within the limitations of this study, it can be concluded that the high-impact acrylic resin is a suitable denture base material for patients with clinical fracture of the acrylic denture.

  7. Dose monitoring for boron neutron capture therapy using a reactor-based epithermal neutron beam

    Science.gov (United States)

    Raaijmakers, C. P. J.; Nottelman, E. L.; Konijnenberg, M. W.; Mijnheer, B. J.

    1996-12-01

    The aims of this study were (i) to determine the variation with time of the relevant beam parameters of a clinical reactor-based epithermal neutron beam for boron neutron capture therapy (BNCT) and (ii) to test a monitoring system for its applicability to monitor the dose delivered to the dose specification point in a patient treated with BNCT. For this purpose two fission chambers covered with Cd and two GM counters were positioned in the beam-shaping collimator assembly of the epithermal neutron beam. The monitor count rates were compared with in-phantom reference measurements of the thermal neutron fluence rate, the gamma-ray dose rate and the fast neutron dose rate, at a constant reactor power, over a period of 2 years. Differences in beam output, defined as the thermal neutron fluence rate at 2 cm depth in a phantom, of up to 15% were observed between various reactor cycles. A decrease in beam output of about 5% was observed in each reactor cycle. An unacceptable decrease of 50% in beam output due to malfunctioning of the beam filter assembly was detected. For safe and accurate treatment of patients, on-line monitoring of the beam is essential. Using the calibrated monitor system, the standard uncertainty in the total dose at depth due to variations with time of the beam output parameters has been reduced to a clinically acceptable value of 1% (one standard deviation).

  8. An overview of an accelerator-based neutron spallation source

    Energy Technology Data Exchange (ETDEWEB)

    Lessner, E.S.

    1996-06-01

    An overview of the feasibility study of a 1-MW pulsed spallation source is presented. The machine delivers 1 MW of proton beam power to spallation targets where slow neutrons are produced. The slow neutrons can be used for isotope production, materials irradiation, and neutron scattering research. The neutron source facility is based on a rapid cycling synchrotron (RCS) and consists of a 400-MeV linac, a 30-Hz RCS that accelerates the 400-MeV beam to 2 GeV, and two neutron-generating target stations. The RCS accelerates an average proton beam current of 0.5 mA, corresponding to 1.04 x 10{sup 14} protons per pulse. This intensity is about two times higher than that of existing machines. A key feature of this accelerator system design is that beam losses are minimized from injection to extraction, reducing activation to levels consistent with hands-on maintenance.

  9. New neutron-based isotopic analytical methods; An explorative study of resonance capture and incoherent scattering

    NARCIS (Netherlands)

    Perego, R.C.

    2004-01-01

    Two novel neutron-based analytical techniques have been treated in this thesis, Neutron Resonance Capture Analysis (NRCA), employing a pulsed neutron source, and Neutron Incoherent Scattering (NIS), making use of a cold neutron source. With the NRCA method isotopes are identified by the isotopic-spe

  10. New neutron-based isotopic analytical methods; An explorative study of resonance capture and incoherent scattering

    NARCIS (Netherlands)

    Perego, R.C.

    2004-01-01

    Two novel neutron-based analytical techniques have been treated in this thesis, Neutron Resonance Capture Analysis (NRCA), employing a pulsed neutron source, and Neutron Incoherent Scattering (NIS), making use of a cold neutron source. With the NRCA method isotopes are identified by the

  11. Investigations on landmine detection by neutron-based techniques.

    Science.gov (United States)

    Csikai, J; Dóczi, R; Király, B

    2004-07-01

    Principles and techniques of some neutron-based methods used to identify the antipersonnel landmines (APMs) are discussed. New results have been achieved in the field of neutron reflection, transmission, scattering and reaction techniques. Some conclusions are as follows: The neutron hand-held detector is suitable for the observation of anomaly caused by a DLM2-like sample in different soils with a scanning speed of 1m(2)/1.5 min; the reflection cross section of thermal neutrons rendered the determination of equivalent thickness of different soil components possible; a simple method was developed for the determination of the thermal neutron flux perturbation factor needed for multi-elemental analysis of bulky samples; unfolded spectra of elastically backscattered neutrons using broad-spectrum sources render the identification of APMs possible; the knowledge of leakage spectra of different source neutrons is indispensable for the determination of the differential and integrated reaction rates and through it the dimension of the interrogated volume; the precise determination of the C/O atom fraction requires the investigations on the angular distribution of the 6.13MeV gamma-ray emitted in the (16)O(n,n'gamma) reaction. These results, in addition to the identification of landmines, render the improvement of the non-intrusive neutron methods possible.

  12. Investigations on landmine detection by neutron-based techniques

    Energy Technology Data Exchange (ETDEWEB)

    Csikai, J. E-mail: csikai@delfin.klte.hu; Doczi, R.; Kiraly, B

    2004-07-01

    Principles and techniques of some neutron-based methods used to identify the antipersonnel landmines (APMs) are discussed. New results have been achieved in the field of neutron reflection, transmission, scattering and reaction techniques. Some conclusions are as follows: The neutron hand-held detector is suitable for the observation of anomaly caused by a DLM2-like sample in different soils with a scanning speed of 1 m{sup 2}/1.5 min; the reflection cross section of thermal neutrons rendered the determination of equivalent thickness of different soil components possible; a simple method was developed for the determination of the thermal neutron flux perturbation factor needed for multi-elemental analysis of bulky samples; unfolded spectra of elastically backscattered neutrons using broad-spectrum sources render the identification of APMs possible; the knowledge of leakage spectra of different source neutrons is indispensable for the determination of the differential and integrated reaction rates and through it the dimension of the interrogated volume; the precise determination of the C/O atom fraction requires the investigations on the angular distribution of the 6.13 MeV gamma-ray emitted in the {sup 16}O(n,n'{gamma}) reaction. These results, in addition to the identification of landmines, render the improvement of the non-intrusive neutron methods possible.

  13. Alkyd-amino resins based on waste PET for coating applications.

    Science.gov (United States)

    Torlakoğlu, A; Güçlü, G

    2009-01-01

    Waste polyethylene terephthalate (PET) flakes were depolymerized by using propylene glycol (PG) in the presence of zinc acetate as catalyst. Glycolysis reaction products of waste PET obtained by using PET/glycol molar ratio 1/2. Two short oil alkyd resins of high acid values (30-40mgKOH/g) were prepared from phthalic anhydride (PA), glycerin (G), coconut oil fatty acids (COFA) and glycolyzed products of waste PET (PET-based alkyd resins) or glycols (PG) (reference alkyd resins). These alkyd resins were blended with 30%, 40%, and 50% of a commercial urea-formaldehyde, melamine-formaldehyde and urea-formaldehyde/melamine-formaldehyde mixture (1/1 weight ratio) and heated at 140 degrees C. The physical and chemical properties such as drying time, hardness, abrasion resistance, adhesion strength, water resistance, alkaline resistance, acid resistance, gelation time, and thermal oxidative degradation resistance (with thermogravimetric analysis, TGA) of these alkyd-amino resins were investigated. The properties of the waste PET-based resins were found to be compatible with the properties of the reference resins.

  14. Effect of post-polymerization heat treatments on the cytotoxicity of two denture base acrylic resins

    OpenAIRE

    Janaina Habib Jorge; Eunice Teresinha Giampaolo; Carlos Eduardo Vergani; Ana Lúcia Machado; Ana Cláudia Pavarina; Iracilda Zeppone Carlos

    2006-01-01

    INTRODUCTION: Most denture base acrylic resins have polymethylmethacrylate in their composition. Several authors have discussed the polymerization process involved in converting monomer into polymer because adequate polymerization is a crucial factor in optimizing the physical properties and biocompatibility of denture base acrylic resins. To ensure the safety of these materials, in vitro cytotoxicity assays have been developed as preliminary screening tests to evaluate material biocompatibil...

  15. Synthesis, Characterization and Thermal Analysis of Resins from Different Cardanol Based Dyes

    Directory of Open Access Journals (Sweden)

    Tapan K. Das

    2014-06-01

    Full Text Available Cardanol(Cashew phenol is subjected to diazotisation with Aniline and m-Toluidine to get monomers like Cardanol based dye from Aniline (CBDFA and Cardanol based dye from m-Toludine (CBDFT. Such monomers have been condensed with formaldehyde in presence of acid catalyst to form resins. The resins have been characterized by FTIR spectra and their thermal behaviour have been studied.

  16. APPLICATION OF DIRECT CONTACT TEST IN EVALUATION OF CYTOTOXICITY OF ACRYLIC DENTURE BASE RESINS

    OpenAIRE

    Milena Kostić; Stevo Najman; Jelena Najdanović; Nebojša Krunić; Ivan Kostić

    2012-01-01

    The use of acrylic denture base resins is widely spread in dental practice. They belong to the group of biomaterials due to their role of morphological and functional substituent in the mouth. However, clinical practice has shown that some toxic ingredients of these materials may lead to adverse local and even systemic changes. The aim of the study was to evaluate cytotoxic effect of various denture base resins on cell culture using direct contact test. The effect of four different acrylic...

  17. In vitro mechanical properties comparsion of four room temperature curing denture base resin:

    Institute of Scientific and Technical Information of China (English)

    LI Zhian; XIA Xuetong; Xiao Qun

    2001-01-01

    @@ The room temperature curing denture base resin has low mechanical properties,so it was limited in clinical application. It had previously disscused that reinfored maehinical properties with metal fiber, glass fiber,plastic fiber and by adding the fracture resistance substances in powderThe aim of this study was to determined the mechanical properities of four roomtemperature curing denture base resin which had been modified performance withhigh boil point methacrylate.

  18. A neutron spectrum unfolding code based on iterative procedures

    Energy Technology Data Exchange (ETDEWEB)

    Ortiz R, J. M.; Vega C, H. R., E-mail: morvymm@yahoo.com.mx [Universidad Autonoma de Zacatecas, Unidad Academica de Ingenieria Electrica, Apdo. Postal 336, 98000 Zacatecas (Mexico)

    2012-10-15

    In this work, the version 3.0 of the neutron spectrum unfolding code called Neutron Spectrometry and Dosimetry from Universidad Autonoma de Zacatecas (NSDUAZ), is presented. This code was designed in a graphical interface under the LabVIEW programming environment and it is based on the iterative SPUNIT iterative algorithm, using as entrance data, only the rate counts obtained with 7 Bonner spheres based on a {sup 6}Lil(Eu) neutron detector. The main features of the code are: it is intuitive and friendly to the user; it has a programming routine which automatically selects the initial guess spectrum by using a set of neutron spectra compiled by the International Atomic Energy Agency. Besides the neutron spectrum, this code calculates the total flux, the mean energy, H(10), h(10), 15 dosimetric quantities for radiation protection porpoises and 7 survey meter responses, in four energy grids, based on the International Atomic Energy Agency compilation. This code generates a full report in html format with all relevant information. In this work, the neutron spectrum of a {sup 241}AmBe neutron source on air, located at 150 cm from detector, is unfolded. (Author)

  19. Effect of different housing retaining materials on the flexural strength of an acrylic resin overdenture base.

    Science.gov (United States)

    Ozkir, Serhat Emre; Yilmaz, Burak

    2017-04-03

    An attachment housing inside an overdenture may weaken the acrylic resin base. The type of housing retaining material may affect the strength of the housing retaining material-acrylic resin base assembly. The effect of different housing retaining materials on the strength of acrylic resin base is unknown. The purpose of this in vitro study was to evaluate the effects of different materials used to retain the housing on the flexural strength of a poly(methyl methacrylate) (PMMA) resin base. Sixty PMMA specimens (64×10×4 mm) were prepared with a clearance inside to allow the insertion of overdenture housings. Five different materials were used for housing orientation: an autopolymerizing composite resin, an acrylic resin reline material, a heat-polymerized PMMA, an autopolymerizing PMMA (n=10), and a control group (n=10) were prepared without any preparation or housing. The specimens were thermocycled 5000 times between 5°C and 55°C. The flexural strength data were analyzed by an analysis of variance using the maximum likelihood estimation method to eliminate the needs for normality within the groups and for equality of variances between the groups. If statistically significant, resolution of the significance factor was obtained by pairwise comparisons using the Tukey adjustment (α=.05). The fracture values were statistically significantly higher (Pmaterial (26.78 ±6.72 MPa), the acrylic resin reline material (16.94 ±4.38 MPa), the Ufigel (16.07 ±3.40 MPa), and the autopolymerizing composite resin (19.37 ±3.13 MPa). Heat- and autopolymerizing PMMA groups were significantly different from acrylic resin-based hard reline materials (Pmaterial except for one of the hard reline groups, which separated from the PMMA. The tested retaining materials significantly reduced the flexural strength of PMMA denture base. The flexural strength of the resin base with housing was significantly higher when PMMA-based retaining materials were used than when acrylic resin-based

  20. Boron removal from water and wastewater using new polystyrene-based resin grafted with glycidol

    OpenAIRE

    2015-01-01

    A divinylbenzene cross-linked polystyrene resin with amine functional groups (Purolite A170) was grafted with glycidol and characterized as a novel sorbent, GLY-resin, for the oxoborate removal from model solutions and post-crystallization lye. The sorption behavior of GLY-resin was investigated using a batch system. The results showed that the sorption was maximal at pH=9.5. The equilibrium was achieved after 24 h. Calculations based on Langmuir model show the monolayer sorption capacity qm=...

  1. The Electrical Properties for Phenolic Isocyanate-Modified Bisphenol-Based Epoxy Resins Comprising Benzoate Group.

    Science.gov (United States)

    Lee, Eun Yong; Chae, Il Seok; Park, Dongkyung; Suh, Hongsuk; Kang, Sang Wook

    2016-03-01

    Epoxy resin has been required to have a low dielectric constant (D(k)), low dissipation factor (Df), low coefficient of thermal expansion (CTE), low water absorption, high mechanical, and high adhesion properties for various applications. A series of novel phenolic isocyanate-modified bisphenol-based epoxy resins comprising benzoate group were prepared for practical electronic packaging applications. The developed epoxy resins showed highly reduced dielectric constants (D(k)-3.00 at 1 GHz) and low dissipation values (Df-0.014 at 1 GHz) as well as enhanced thermal properties.

  2. Viscoelastic properties of graphene-based epoxy resins

    Science.gov (United States)

    Nobile, Maria Rossella; Fierro, Annalisa; Rosolia, Salvatore; Raimondo, Marialuigia; Lafdi, Khalid; Guadagno, Liberata

    2015-12-01

    In this paper the viscoelastic properties of an epoxy resin filled with graphene-based nanoparticles have been investigated in the liquid state, before curing, by means of a rotational rheometer equipped with a parallel plate geometry. Exfoliated graphite was prepared using traditional acid intercalation followed by a sudden treatment at high temperature (900°C). The percentage of exfoliated graphite was found to be 56%. The epoxy matrix was prepared by mixing a tetrafunctional precursor with a reactive diluent which produces a significant decrease in the viscosity of the epoxy precursor so that the dispersion step of nanofillers in the matrix can easily occur. The hardener agent, the 4,4-diaminodiphenyl sulfone (DDS), was added at a stoichiometric concentration with respect to all the epoxy rings. The inclusion of the partially exfoliated graphite (pEG) in the formulated epoxy mixture significantly modifies the rheological behaviour of the mixture itself. The epoxy mixture, indeed, shows a Newtonian behaviour while, at 3 wt % pEG content, the complex viscosity of the nanocomposite clearly shows a shear thinning behaviour with η* values much higher at the lower frequencies. The increase in complex viscosity with the increasing of the partially exfoliated graphite content was mostly caused by a dramatic increase in the storage modulus. All the graphene-based epoxy mixtures were cured by a two-stage curing cycles: a first isothermal stage was carried out at the lower temperature of 125°C for 1 hour while the second isothermal stage was performed at the higher temperature of 200°C for 3 hours. The mechanical properties of the cured nanocomposites show high values in the storage modulus and glass transition temperature.

  3. Development of Refined Natural Resin based Cashew Nut Shell Oil Liquid (CNSL) for Brake Pads Composite

    Science.gov (United States)

    Wahyuningsih, S.; Ramelan, A. H.; Rahmawati, P.; Tamtama, B. P. N.; Sari, P. P.; Sari, P. L.; Ichsan, S.; Kristiawan, Y. R.; Aini, F. N.

    2017-02-01

    Brake is one of the most important components in the vehicle. One type of brake that widely used is brake-based composites. One of the manufacture of composite material is resin. Cashew Nut Shell Liquid (CNSL) is a natural material which has chemical structure similar to synthetic phenol so it can be an alternative as a resin. Brake pads manufacture using CNSL as resin composites made to obtain the brake which is strong, wear-resistant, and environmentally friendly. The composite made using powder metallurgy techniques by mixing ingredients such as rubber, fibre glass, carbon, mineral sands and phenolic resin. Two formulas were composed by varying the resin and iron mineral sands in 5 grams. Composites were tested using Universal Testing Machine (UTM). The tensile strength result of those formulas are 600 N and 900 N and the elongations are 1.98 mm and 2.59 mm respectively. Formula 2 has a better tensile strength due to the addition of more resin is 15%. Since the better properties, formula 2 was derivated to 4 extended formulas and showed excellent pressure strength reached 20.000 N. It indicates that the addition of the resin can improve the mechanical properties of a composite.

  4. Fabrication of Glass Fiber Reinforced Composites Based on Bio-Oil Phenol Formaldehyde Resin

    Directory of Open Access Journals (Sweden)

    Yong Cui

    2016-11-01

    Full Text Available In this study, bio-oil from fast pyrolysis of renewable biomass was added by the mass of phenol to synthesize bio-oil phenol formaldehyde (BPF resins, which were used to fabricate glass fiber (GF reinforced BPF resin (GF/BPF composites. The properties of the BPF resin and the GF/BPF composites prepared were tested. The functional groups and thermal property of BPF resin were thoroughly investigated by Fourier transform infrared (FTIR spectra and dynamic thermomechanical analysis (DMA. Results indicated that the addition of 20% bio-oil exhibited favorable adaptability for enhancing the stiffness and heat resistance of phenol formaldehyde (PF resin. Besides, high-performance GF/BPF composites could be successfully prepared with the BPF resin based on hand lay-up process. The interface characteristics of GF/BPF composites were determined by the analysis of dynamic wettability (DW and scanning electron microscopy (SEM. It exhibited that GF could be well wetted and embedded in the BPF resin with the bio-oil addition of 20%.

  5. Principles and status of neutron-based inspection technologies

    Science.gov (United States)

    Gozani, Tsahi

    2011-06-01

    Nuclear based explosive inspection techniques can detect a wide range of substances of importance for a wide range of objectives. For national and international security it is mainly the detection of nuclear materials, explosives and narcotic threats. For Customs Services it is also cargo characterization for shipment control and customs duties. For the military and other law enforcement agencies it could be the detection and/or validation of the presence of explosive mines, improvised explosive devices (IED) and unexploded ordnances (UXO). The inspection is generally based on the nuclear interactions of the neutrons (or high energy photons) with the various nuclides present and the detection of resultant characteristic emissions. These can be discrete gamma lines resulting from the thermal neutron capture process (n,γ) or inelastic neutron scattering (n,n'γ) occurring with fast neutrons. The two types of reactions are generally complementary. The capture process provides energetic and highly penetrating gamma rays in most inorganic substances and in hydrogen, while fast neutron inelastic scattering provides relatively strong gamma-ray signatures in light elements such as carbon and oxygen. In some specific important cases unique signatures are provided by the neutron capture process in light elements such as nitrogen, where unusually high-energy gamma ray is produced. This forms the basis for key explosive detection techniques. In some cases the elastically scattered source (of mono-energetic) neutrons may provide information on the atomic weight of the scattering elements. The detection of nuclear materials, both fissionable (e.g., 238U) and fissile (e.g., 235U), are generally based on the fissions induced by the probing neutrons (or photons) and detecting one or more of the unique signatures of the fission process. These include prompt and delayed neutrons and gamma rays. These signatures are not discrete in energy (typically they are continua) but temporally

  6. Novel high glass temperature sugar-based epoxy resins: Characterization and comparison to mineral oil-based aliphatic and aromatic resins

    Directory of Open Access Journals (Sweden)

    P. Niedermann

    2015-02-01

    Full Text Available Curing and rheological behaviour, glass transition temperature, mechanical and thermal properties of two newly synthesized glucopyranoside- (GPTE and glucofuranoside- (GFTE based renewable epoxy resin (EP components were investigated and compared to aromatic and aliphatic EPs. The glucose-based EPs can be successfully cured with amine and anhydride type curing agents, their gel times are suitable for processing and can be well-adopted to the needs of the common composite preparation methods. GPTE showed the highest glass transition temperature (Tg among all investigated resins, followed by GFTE and DGEBA. Below the Tg there was no significant difference between the storage modulus values of the EP systems. The glucose-based EPs had lower tensile and bending strength, but their tensile modulus values are not significantly different from the mineral oil based EPs. The thermal stability of the synthesized GPTE and GFTE is between DGEBA and the aliphatic resins. In applications where bending stresses are dominant over the tensile ones, and outstanding Tg is required, these glucose-based resins offer a feasible renewable option.

  7. Event-based processing of neutron scattering data

    Science.gov (United States)

    Peterson, Peter F.; Campbell, Stuart I.; Reuter, Michael A.; Taylor, Russell J.; Zikovsky, Janik

    2015-12-01

    Many of the world's time-of-flight spallation neutrons sources are migrating to recording individual neutron events. This provides for new opportunities in data processing, the least of which is to filter the events based on correlating them with logs of sample environment and other ancillary equipment. This paper will describe techniques for processing neutron scattering data acquired in event mode which preserve event information all the way to a final spectrum, including any necessary corrections or normalizations. This results in smaller final uncertainties compared to traditional methods, while significantly reducing processing time and memory requirements in typical experiments. Results with traditional histogramming techniques will be shown for comparison.

  8. Accelerator-based epithermal neutron beam design for neutron capture therapy.

    Science.gov (United States)

    Yanch, J C; Zhou, X L; Shefer, R E; Klinkowstein, R E

    1992-01-01

    Recent interest in the production of epithermal neutrons for use in boron neutron capture therapy (BNCT) has promoted an investigation into the feasibility of generating such neutrons with a high current proton accelerator. Energetic protons (2.5 MeV) on a 7Li target produce a spectrum of neutrons with maximum energy of roughly 800 keV. A number of combinations of D2O moderator, lead reflector, 6Li thermal neutron filtration, and D2O/6Li shielding will result in a useful epithermal flux of 1.6 x 10(8) n/s at the patient position. The neutron beam is capable of delivering 3000 RBE-cGy to a tumor at a depth of 7.5 cm in a total treatment time of 60-93 min (depending on RBE values used and based on a 24-cm diameter x 19-cm length D2O moderator). Treatment of deeper tumors with therapeutic advantage would also be possible. Maximum advantage depths (RBE weighted) of 8.2-9.2 (again depending on RBE values and precise moderator configuration) are obtained in a right-circular cylindrical phantom composed of brain-equivalent material with an advantage ratio of 4.7-6.3. A tandem cascade accelerator (TCA), designed and constructed at Science Research Laboratory (SRL) in Somerville MA, can provide the required proton beam parameters for BNCT of deep-seated tumors. An optimized configuration of materials required to shift the accelerator neutron spectrum down to therapeutically useful energies has been designed using Monte Carlo simulation in the Whitaker College Biomedical Imaging and Computation Laboratory at MIT. Actual construction of the moderator/reflector assembly is currently underway.

  9. Neutron based evaluation in support of NEAMS

    Energy Technology Data Exchange (ETDEWEB)

    Vogel, Sven C. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Bourke, Mark Andrew [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Losko, Adrian Simon [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-06-07

    The primary objective of the Advanced Non-Destructive fuel Examination (ANDE) work package is to develop capability that has the potential to accelerate insight and development of ceramic and metallic fuels. Establishing unique validation opportunities for new models is a key component of this effort. To explore opportunities a series of interactions were held with NEAMS modelers at LANL. The focus was to identify experiments that draw on the unique capabilities of neutron scattering and imaging for studies of nuclear fuel particularly in areas where experimental data can be valuable for of models validation. The neutron characterization techniques applied in the ANDE program span length scales from millimeter to micrometer to angstroms. Spatial heterogeneities of interest include cracks, pores and inclusions, crystal structure, phase composition, stoichiometry texture, chemistry and atomic thermal motion. Neutrons offer characterization opportunities that are distinct from other probes such as X-rays, electrons or protons. This report describes a variety of opportunities whereby neutron data can be related to models and lists some opportunities.

  10. Designing accelerator-based epithermal neutron beams for boron neutron capture therapy.

    Science.gov (United States)

    Bleuel, D L; Donahue, R J; Ludewigt, B A; Vujic, J

    1998-09-01

    The 7Li(p,n)7Be reaction has been investigated as an accelerator-driven neutron source for proton energies between 2.1 and 2.6 MeV. Epithermal neutron beams shaped by three moderator materials, Al/AlF3, 7LiF, and D2O, have been analyzed and their usefulness for boron neutron capture therapy (BNCT) treatments evaluated. Radiation transport through the moderator assembly has been simulated with the Monte Carlo N-particle code (MCNP). Fluence and dose distributions in a head phantom were calculated using BNCT treatment planning software. Depth-dose distributions and treatment times were studied as a function of proton beam energy and moderator thickness. It was found that an accelerator-based neutron source with Al/AlF3 or 7LiF as moderator material can produce depth-dose distributions superior to those calculated for a previously published neutron beam design for the Brookhaven Medical Research Reactor, achieving up to approximately 50% higher doses near the midline of the brain. For a single beam treatment, a proton beam current of 20 mA, and a 7LiF moderator, the treatment time was estimated to be about 40 min. The tumor dose deposited at a depth of 8 cm was calculated to be about 21 Gy-Eq.

  11. Thin film CdTe based neutron detectors with high thermal neutron efficiency and gamma rejection for security applications

    Science.gov (United States)

    Smith, L.; Murphy, J. W.; Kim, J.; Rozhdestvenskyy, S.; Mejia, I.; Park, H.; Allee, D. R.; Quevedo-Lopez, M.; Gnade, B.

    2016-12-01

    Solid-state neutron detectors offer an alternative to 3He based detectors, but suffer from limited neutron efficiencies that make their use in security applications impractical. Solid-state neutron detectors based on single crystal silicon also have relatively high gamma-ray efficiencies that lead to false positives. Thin film polycrystalline CdTe based detectors require less complex processing with significantly lower gamma-ray efficiencies. Advanced geometries can also be implemented to achieve high thermal neutron efficiencies competitive with silicon based technology. This study evaluates these strategies by simulation and experimentation and demonstrates an approach to achieve >10% intrinsic efficiency with <10-6 gamma-ray efficiency.

  12. Retention of a Flowable Composite Resin in Comparison to a Conventional Resin-Based Sealant: One-year Follow-up

    OpenAIRE

    N. Tadayon; B. Malekafzali; M.Jafarzadeh; Fallahi, S.

    2010-01-01

    Objective: Long-term retention of pit and fissure sealants is crucial for their success. This clinical study evaluated the retention rate of a flowable composite resin (Filtek Supreme XT Flowable Restorative) compared to a conventional resin-based sealant (Concise Light Cure White Sealant) over 12 months. Materials and Methods: Forty subjects aged 6 to 9 years were included in the study. Using a half-mouth design, a total of 80 first permanent molars were sealed with conventional fissure seal...

  13. Proposal of thermal neutron flux monitors based on vibrating wire

    CERN Document Server

    Arutunian, S G; Chung, M; Harutyunyan, G S; Lazareva, E G

    2015-01-01

    Two types of neutron monitors with fine spatial resolution are proposed based on vibrating wire. In the first type, neutrons interact with the vibrating wire, heat it, and lead to the change of natural frequency, which can be precisely measured. To increase the heat deposition during the neutron scattering, use of gadolinium layer which has the highest thermal neutron capture cross section among all elements is proposed. The second type of the monitor uses vibrating wire as a resonant target. Besides the measurement of beam profile according to the average signal, the differential signal synchronized with the wire oscillations defines the gradient of beam profile. Spatial resolution of the monitor is defined by the diameter of the wire.

  14. Experimental characterization of semiconductor-based thermal neutron detectors

    Energy Technology Data Exchange (ETDEWEB)

    Bedogni, R., E-mail: roberto.bedogni@lnf.infn.it [IFNF—LNF, via E. Fermi n. 40, 00044 Frascati, Roma (Italy); Bortot, D.; Pola, A.; Introini, M.V.; Lorenzoli, M. [Politecnico di Milano, Dipartimento di Energia, via La Masa 34, 20156 Milano (Italy); INFN—Milano, Via Celoria 16, 20133 Milano (Italy); Gómez-Ros, J.M. [IFNF—LNF, via E. Fermi n. 40, 00044 Frascati, Roma (Italy); CIEMAT, Av. Complutense 40, 28040 Madrid (Spain); Sacco, D. [IFNF—LNF, via E. Fermi n. 40, 00044 Frascati, Roma (Italy); INAIL—DIT, Via di Fontana Candida 1, 00040 Monteporzio Catone (Italy); Esposito, A.; Gentile, A.; Buonomo, B. [IFNF—LNF, via E. Fermi n. 40, 00044 Frascati, Roma (Italy); Palomba, M.; Grossi, A. [ENEA Triga RC-1C.R. Casaccia, via Anguillarese 301, 00060 S. Maria di Galeria, Roma (Italy)

    2015-04-21

    In the framework of NESCOFI@BTF and NEURAPID projects, active thermal neutron detectors were manufactured by depositing appropriate thickness of {sup 6}LiF on commercially available windowless p–i–n diodes. Detectors with different radiator thickness, ranging from 5 to 62 μm, were manufactured by evaporation-based deposition technique and exposed to known values of thermal neutron fluence in two thermal neutron facilities exhibiting different irradiation geometries. The following properties of the detector response were investigated and presented in this work: thickness dependence, impact of parasitic effects (photons and epithermal neutrons), linearity, isotropy, and radiation damage following exposure to large fluence (in the order of 10{sup 12} cm{sup −2})

  15. Nanoparticles-based phenol-formaldehyde hybrid resins.

    Science.gov (United States)

    Hernández-Padrón, Genoveva; García-Garduño, Margarita; Canseco, Miguel A; Castaño, Victor M

    2008-06-01

    The synthesis, characterization and corrosion properties of a novel material, produced by the reaction of silica nanoparticles with a functionalized Phenol-Formaldehyde Resin (PFR), are presented. Carboxylic groups were attached in situ to the PFR skeleton to produce a functionalized resin (PFR-SA), which is then reacted with sol-gel-prepared silica nanoparticles, yielding a novel hybrid (organic/inorganic) material (PFR-SA-nanoSiO2). This hybrid material was characterized by FT-IR, FT-Raman, TGA, DSC, SEM and corrosion tests, whose results showed significant improvement of the thermal properties in comparison with the PFR coating. In addition, the new material was efficient and durable against corrosion of metals, with the anticorrosive performance of PFR-SA and PFR-SA/nanoSiO2 coating films being superior to those of the original PFR coating.

  16. Chemical analysis of monomers in epoxy resins based on bisphenols F and A.

    Science.gov (United States)

    Pontén, A; Zimerson, E; Sörensen, O; Bruze, M

    2004-05-01

    Diglycidyl ether of bisphenol A (DGEBA) is the monomer and most important contact allergen in epoxy resin(s) based on bisphenol A (DGEBA-R). Both thin-layer chromatography (TLC) and high-pressure liquid chromatography (HPLC) methods are available for the analysis of products containing DGEBA-R. With respect to detection and quantification, epoxy resins of the bisphenol F-type, i.e. epoxy resins containing the isomers of diglycidyl ethers of bisphenol F (DGEBF), are not as well investigated as DGEBA-R. The isomers of DGEBF are p,p'-DGEBF, o,p'-DGEBF and o,o'-DGEBF. Both p,p'-DGEBF and o,p'-DGEBF have been shown to be contact allergens in humans, and all 3 isomers are sensitizers in the guinea pig maximization test. We aimed (i). to develop HPLC methods for separation and purification of the individual DGEBF isomers, (ii). to detect and quantify the DGEBF isomers in epoxy resins of the bisphenol F-type and (iii). to evaluate and develop the TLC as a method for the detection of the DGEBF monomers. We found the total content of the DGEBF isomers in the investigated epoxy resins of the bisphenol F-type to vary from 17.0 to 81.7% w/w. Some of them also contained 0.1-2.4% w/w DGEBA. The HPLC method showed a sensitivity that was 2000-20 000x higher than that obtained with the TLC method for the DGEBF monomers. We concluded that the range of the DGEBF isomer content in epoxy resins of the bisphenol F-type is approximately the same as the monomer content in liquid compared to solid DGEBA-R. The relevance of contact allergy to DGEBA-R can remain unrecognized if the suspected product is an epoxy resin of the bisphenol F-type, which is analysed with the TLC method.

  17. Resin Catalyst Hybrids

    Institute of Scientific and Technical Information of China (English)

    S. Asaoka

    2005-01-01

    @@ 1Introduction: What are resin catalyst hybrids? There are typically two types of resin catalyst. One is acidic resin which representative is polystyrene sulfonic acid. The other is basic resin which is availed as metal complex support. The objective items of this study on resin catalyst are consisting of pellet hybrid, equilibrium hybrid and function hybrid of acid and base,as shown in Fig. 1[1-5].

  18. Novel Boron Based Multilayer Thermal Neutron Detector

    CERN Document Server

    SCHIEBER, M

    2010-01-01

    The detector contains four or more layers of natural Boron absorbing thermal neutrons. Thickness of a layer is 0.4 - 1.2 mg/cm2. The layers are deposited on one or on both sides of a metal surface used as contacts. Between the absorbing layers there are gas-filled gaps 3 - 6 mm thick. Electric field of 100 - 200 V/cm is applied to the gas-filled gaps. Natural Boron contains almost 20% of 10B isotope. When atoms of 10B capture a thermal neutron, nuclear reaction occurs, as a result of which two heavy particles - alpha particle and ion 7Li - from the thin absorber layer are emitted in opposing sides. One of the two particles penetrates into gas-filled gap between Boron layers and ionizes the gas. An impulse of electric current is created in the gas-filled gap actuated by the applied electric field. The impulse is registered by an electronic circuit. We have made and tested detectors containing from two to sixteen layers of natural Boron with an efficiency of thermal neutron registration from 2.9% to 12.5% accor...

  19. Variations in survival time for amalgam and resin composite restorations: a population based cohort analysis.

    Science.gov (United States)

    Birch, S; Price, R; Andreou, P; Jones, G; Portolesi, A

    2016-09-01

    To estimate the association between the restorative material used and time to further treatment across population cohorts with universal coverage for dental treatment. Cohort study of variation in survival time for tooth restorations over time and by restoration material used based on an Accelerated Failure Time model. Primary dental care clinics. Members of Canada's First Nations and Inuit population covered by the Non-Insured Health Benefits program of Health Canada for the period April 1, 1999 to March 31, 2012. Tooth restorations using resin composite or amalgam material. Survival time of restoration to further treatment. Median survival time for resin composite was 51 days longer than amalgam, for restorations placed in 1999-2000. This difference was not statistically significant (p⟩0.05). Median survival times were lower for females, older subjects. Those visiting the dentist annually, and decreased monotonically over time from 11.2 and 11.3 years for resin composite and amalgam restorations respectively placed in 1999-2000 to 6.9 and 7.0 years for those placed in 2009-10. Resin composite restorations performed no better than amalgams over the study period, but cost considerably more. With the combination of the overall decrease in survival times for both resin composite and amalgam restorations and the increase in use of resin composite, the costs of serving Health Canada's Non-Insured Health Benefits population will rise considerably, even without any increase in the incidence of caries.

  20. Safety assessment for hair-spray resins: risk assessment based on rodent inhalation studies.

    Science.gov (United States)

    Carthew, Philip; Griffiths, Heather; Keech, Stephen; Hartop, Peter

    2002-04-01

    The methods involved in the safety assessment of resins used in hair-spray products have received little peer review, or debate in the published literature, despite their widespread use, in both hairdressing salons and the home. The safety assessment for these resins currently involves determining the type of lung pathology that can be caused in animal inhalation exposure studies, and establishing the no-observable-effect level (NOEL) for these pathologies. The likely human consumer exposure is determined by techniques that model the simulated exposure under "in use" conditions. From these values it is then possible to derive the likely safety factors for human exposure. An important part of this process would be to recognize the intrinsic differences between rodents and humans in terms of the respiratory doses that each species experiences during inhalation exposures, for the purpose of the safety assessment. Interspecies scaling factors become necessary when comparing the exposure doses experienced by rats, compared to humans, because of basic differences between species in lung clearance rates and the alveolar area in the lungs. The rodent inhalation data and modeled human exposure to Resin 6965, a resin polymer that is based on vinyl acetate, has been used to calculate the safety factor for human consumer exposure to this resin, under a range of "in use" exposure conditions. The use of this safety assessment process clearly demonstrates that Resin 6965 is acceptable for human consumer exposure under the conditions considered in this risk assessment.

  1. Bond of acrylic teeth to different denture base resins after various surface-conditioning methods.

    Science.gov (United States)

    Lang, Reinhold; Kolbeck, Carola; Bergmann, Rainer; Handel, Gerhard; Rosentritt, Martin

    2012-02-01

    The study examined the bond between different denture base resins and highly cross-linked acrylic denture teeth with different base surface-conditioning methods. One hundred fifty highly cross-linked resin denture teeth (SR-Antaris, No. 11, Ivoclar-Vivadent, FL) were divided into five groups with different surface-conditioning methods of the base surfaces of the teeth (C = control, no surface conditioning, MM = application of methyl methacrylate monomer, SB = sand blasting, SBB = sand blasting + bonding agent, TSS = tribochemical silica coating + silanization). Teeth were bonded to either a cold-cured denture base resin (ProBase Cold, Ivoclar-Vivadent, FL) or heat-cured denture base resins (SR Ivocap Plus, Ivoclar-Vivadent, FL and Lucitone 199, Dentsply, USA). After 24 h of storage in distilled water, compressive load was applied at 90° on the palatal surface of each tooth until fracture. Median failure load ranged between 103 and 257 N for Probase Cold groups, 91 to 261 N for Lucitone 199, and 149 to 320 N for SR Ivocap Plus. For Probase Cold, significant highest failure loads resulted when teeth were treated with SB, SBB, or TSS. For Lucitone 199, significant highest failure loads has been found with MM and TSS treatment. For SR Ivocap Plus, highest failure loads resulted using SBB and TSS. Conditioning of the base surfaces of the teeth prior to denture base processing is highly recommended. Tooth bond is significantly affected by the surface-conditioning method and applied denture base resin. Tribochemical silica coating + silanization method can be recommended for pre-treatment of teeth applying either heat-cured or cold-cured denture base resin.

  2. Novel high glass temperature sugar-based epoxy resins: Characterization and comparison to mineral oil-based aliphatic and aromatic resins

    OpenAIRE

    Niedermann, P.; G. Szebenyi; A. Toldy

    2015-01-01

    Curing and rheological behaviour, glass transition temperature, mechanical and thermal properties of two newly synthesized glucopyranoside- (GPTE) and glucofuranoside- (GFTE) based renewable epoxy resin (EP) components were investigated and compared to aromatic and aliphatic EPs. The glucose-based EPs can be successfully cured with amine and anhydride type curing agents, their gel times are suitable for processing and can be well-adopted to the needs of the common composite preparation method...

  3. Effects of different cavity disinfectants on shear bond strength of a silorane-based resin composite.

    Science.gov (United States)

    Arslan, Soley; Yazici, A Ruya; Gorucu, Jale; Ertan, Atilla; Pala, Kansad; Ustun, Yakup; Antonson, Sibel A; Antonson, Donald E

    2011-07-01

    This in vitro study evaluated the effect of different cavity disinfection agents on bond strength of a silorane-based resin composite. Thirty-six caries-free human third mandibular molars sectioned in mesio-distal direction were mounted in acrylic resin with their flat dentin surfaces exposed. After the dentin surfaces were wet ground with # 600 silicon carbide paper, the teeth were randomly divided into 6 groups of 12 each according to the cavity disinfection agents; chlorhexidine (CHX); sodium hypochlorite (NaOCl), propolis, ozone, Er,Cr:YSGG laser and no treatment (control). After treatment of dentin surfaces with one of these cavity disinfection agents, Filtek Silorane adhesive system was applied. The silorane-based resin composite, Filtek Silorane was condensed into a mold and polymerized. After storage at 37°C for 24 hours, the specimens were tested in shear mode at a crosshead speed of 1.0 mm/minute. The results were analyzed by one-way ANOVA. No statistically significant difference was observed between the groups (p>0.05). The use of the tested cavity disinfection agents, chlorhexidine, sodium hypochlorite, propolis, ozone and Er,Cr:YSGG laser did not significantly affect the dentin bond strength of a silorane-based resin composite, filtek supreme. Cavity disinfectant applications did not affect the dentin bond strength of a silorane-based resin composite.

  4. Design of a californium-based epithermal neutron beam for neutron capture therapy.

    Science.gov (United States)

    Yanch, J C; Kim, J K; Wilson, M J

    1993-08-01

    The potential of the spontaneously fissioning isotope, 252Cf, to provide epithermal neutrons for use in boron neutron capture therapy (BNCT) has been investigated using Monte Carlo simulation. The Monte Carlo code MCNP was used to design an assembly composed of a 26 cm long, 11 cm radius cylindrical D2O moderator followed by a 64 cm long Al filter. Lithium filters are placed between the moderator and the filter and between the Al and the patient. A reflector surrounding the moderator/filter assembly is required in order to maintain adequate therapy flux at the patient position. An ellipsoidal phantom composed of skull- and brain-equivalent material was used to determine the dosimetric effect of this beam. It was found that both advantage depths and advantage ratios compare very favourably with reactor and accelerator epithermal neutron sources. The dose rate obtainable, on the other hand, is 4.1 RBE cGy min-1, based on a very large (1.0 g) source of 252Cf. This dose rate is two to five times lower than those provided by existing reactor beams and can be viewed as a drawback of using 252Cf as a neutron source. Radioisotope sources, however, do offer the advantage of in-hospital installation.

  5. Atmospheric Neutron Measurements using a Small Scintillator Based Detector

    Science.gov (United States)

    Kole, Merlin; Pearce, Mark; Fukazawa, Yasushi; Fukuda, Kentaro; Ishizu, Sumito; Jackson, Miranda; Kamae, Tune; Kawaguchi, Noriaki; Kawano, Takafumi; Kiss, Mozsi; Moretti, Elena; Yanagida, Takayuki; Chauvin, Maxime; Mikhalev, Victor; Rydstrom, Stefan; Takahashi, Hiromitsu

    PoGOLino is a standalone scintillator-based neutron detector designed for balloon-borne missions. Its main purpose is to provide data of the neutron flux in 2 different energy ranges in the high altitude / high latitude region where the highest neutron flux in the atmosphere is found. Furthermore the influence of the Solar activity upon the neutron environment in this region is relatively strong. As a result both short and long term time fluctuations are strongest in this region. At high altitudes neutrons can form a source of background for balloon-borne scientific measurements. They can furthermore form a major source for single event upsets in electronics. A good understanding of the high altitude / high latitude neutron environment is therefore important. Measurements of the neutron environment in this region are however lacking. PoGOLino contains two 5 mm thick Lithium Calcium Aluminium Fluoride (LiCAF) scintillators used for neutron detection. The LiCAF crystals are sandwiched between 2 Bismuth Germanium Oxide (BGO) scintillating crystals, which serve to veto signals produced by gamma-rays and charged particles. The veto system makes measurements of the neutron flux possible even in high radiation environments. One LiCAF detector is shielded with polyethylene while the second remains unshielded, making the detectors sensitive in different energy ranges. The choice of a scintillator crystals as the detection material ensures a high detection efficiency while keeping the instrument small, robust and light weight. The full standalone cylindrical instrument has a radius of 120 mm, a height of 670 mm and a total mass of 13 kg, making it suitable as a piggy back mission. PoGOLino was successfully launched on March 20th 2013 from the Esrange Space Center in Northern Sweden to an altitude of 30.9 km. A detailed description of the detector design is presented, along with results of of the flight. The neutron flux measured during flight is compared to predictions based

  6. Absolute Calibration of Proportional Counter Based Fast Pulsed Neutron Detectors with Resolution Below 105 neutron/pulse

    Science.gov (United States)

    Tarifeño-Saldivia, A.; Mayer, R. E.; Pavez, C.; Soto, L.

    2014-05-01

    A method for absolute calibration of proportional counters for pulsed fast neutrons is presented. The method is based on the use of an isotopic standard source and development of a model for counting detected events from area of a signal compounded by single piled up neutron pulses. Effects of detection counting statistics and electrical background noise are also considered. The method is applied in detectors used for D-D neutron yield measurements in low emission plasma focus devices.

  7. Unfolding code for neutron spectrometry based on neural nets technology

    Energy Technology Data Exchange (ETDEWEB)

    Ortiz R, J. M.; Vega C, H. R., E-mail: morvymm@yahoo.com.mx [Universidad Autonoma de Zacatecas, Unidad Academica de Ingenieria Electrica, Apdo. Postal 336, 98000 Zacatecas (Mexico)

    2012-10-15

    The most delicate part of neutron spectrometry, is the unfolding process. The derivation of the spectral information is not simple because the unknown is not given directly as a result of the measurements. The drawbacks associated with traditional unfolding procedures have motivated the need of complementary approaches. Novel methods based on Artificial Neural Networks have been widely investigated. In this work, a neutron spectrum unfolding code based on neural nets technology is presented. This unfolding code called Neutron Spectrometry and Dosimetry by means of Artificial Neural Networks was designed in a graphical interface under LabVIEW programming environment. The core of the code is an embedded neural network architecture, previously optimized by the {sup R}obust Design of Artificial Neural Networks Methodology{sup .} The main features of the code are: is easy to use, friendly and intuitive to the user. This code was designed for a Bonner Sphere System based on a {sup 6}Lil(Eu) neutron detector and a response matrix expressed in 60 energy bins taken from an International Atomic Energy Agency compilation. The main feature of the code is that as entrance data, only seven rate counts measurement with a Bonner spheres spectrometer are required for simultaneously unfold the 60 energy bins of the neutron spectrum and to calculate 15 dosimetric quantities, for radiation protection porpoises. This code generates a full report in html format with all relevant information. (Author)

  8. Acid-Breakable Resin-Based Chemical Amplification Positive Resist for Electron-Beam Mastering: Design and Lithographic Performance

    Science.gov (United States)

    Sakamizu, Toshio; Shiraishi, Hiroshi

    2004-07-01

    A positive chemical amplification resist based on acid-catalyzed fragmentation of acetal groups in its main chain has been developed as a means of reducing line-edge roughness. The resist consists of an acid generator, an acid-diffusion controller and an acid-breakable (AB) resin that is synthesized through a co-condensation reaction between polyphenol and aromatic multifunctional vinylether compound. The effects of the fractionation of AB resins on resin properties and line-edge roughness (LER) are evaluated. Although AB resins have wide molecular weight distributions, the density of acetal groups in this AB resin is found to be almost constant except in the lower molecular weight components. The resist with a fractionated resin from which such components are removed provides high-resolution patterns (70-nm-wide pit) with fairly low LER. AFM analysis shows that the surface roughness (SR) of the resist with the fractionated resin is smaller than that of a resist using nonfractionated AB resin, and that the SR value is not altered throughout the range of exposure doses up to just below the start of dissolution. By using the fractionated AB resin, the AB resin-based resist (ABR) is capable of forming sub-100 nm L/S patterns with less than 5 nm of LER (3σ).

  9. Chitosan whiskers from shrimp shells incorporated into dimethacrylate-based dental resin sealant.

    Science.gov (United States)

    Mahapoka, Ekamon; Arirachakaran, Pratanporn; Watthanaphanit, Anyarat; Rujiravanit, Ratana; Poolthong, Suchit

    2012-01-01

    A resin-based sealant containing chitosan whiskers was developed for use as a pit and fissure sealer. Chitosan whiskers were synthesized and then characterized using Fourier transform infrared spectrometry and transmission electron microscopy. The whiskers were next incorporated into dimethacrylate monomer at various ratios by weight and subsequently analyzed for their antimicrobial and physical properties. The dimethacrylate-based sealant containing chitosan whiskers had a greater antimicrobial activity than control sealant and they were comparable with antimicrobial commercial resin sealants. The inclusion of the whiskers did not reduce the curing depth or degree of double bond conversion and the reduction in hardness was minimal. In conclusion, a resin-based sealant containing chitosan whiskers can be considered an effective antimicrobial pit and fissure sealant.

  10. Extraction of Carbon Dioxide From Seawater by Ion Exchange Resin. Part 2. Using Strong Base Anion Exchange Resin

    Science.gov (United States)

    2009-09-29

    Figure 1. Table 2 - Resin Properties of Static Experiments Using Amberjet 4400 in OH Form (150 minute contact time). Sample Concentration (Molar...0.271 1 36 17.9 0.0075 150 0.267 134 19.0 Table 4 - Resin Properties of Static Experiments Using Amberjet 4400 in Cl Form (150 minute contact time

  11. Reducing composite restoration polymerization shrinkage stress through resin modified glass-ionomer based adhesives.

    Science.gov (United States)

    Naoum, S J; Mutzelburg, P R; Shumack, T G; Thode, Djg; Martin, F E; Ellakwa, A E

    2015-12-01

    The aim of this study was to determine whether employing resin modified glass-ionomer based adhesives can reduce polymerization contraction stress generated at the interface of restorative composite adhesive systems. Five resin based adhesives (G Bond, Optibond-All-in-One, Optibond-Solo, Optibond-XTR and Scotchbond-Universal) and two resin modified glass-ionomer based adhesives (Riva Bond-LC, Fuji Bond-LC) were analysed. Each adhesive was applied to bond restorative composite Filtek-Z250 to opposing acrylic rods secured within a universal testing machine. Stress developed at the interface of each adhesive-restorative composite system (n = 5) was calculated at 5-minute intervals over 6 hours. The resin based adhesive-restorative composite systems (RBA-RCS) demonstrated similar interface stress profiles over 6 hours; initial rapid contraction stress development (0-300 seconds) followed by continued contraction stress development ≤0.02MPa/s (300 seconds - 6 hours). The interface stress profile of the resin modified glass-ionomer based adhesive-restorative composite systems (RMGIBA-RCS) differed substantially to the RBA-RCS in several ways. Firstly, during 0-300 seconds the rate of contraction stress development at the interface of the RMGIBA-RCS was significantly (p resin modified glass-ionomer based adhesives can significantly reduce the magnitude and rate of polymerization contraction stress developed at the interface of adhesive-restorative composite systems. © 2015 Australian Dental Association.

  12. Introduction to Neutron Coincidence Counter Design Based on Boron-10

    Energy Technology Data Exchange (ETDEWEB)

    Kouzes, Richard T.; Ely, James H.; Lintereur, Azaree T.; Siciliano, Edward R.

    2012-01-22

    The Department of Energy Office of Nonproliferation Policy (NA-241) is supporting the project 'Coincidence Counting With Boron-Based Alternative Neutron Detection Technology' at Pacific Northwest National Laboratory (PNNL) for development of an alternative neutron coincidence counter. The goal of this project is ultimately to design, build and demonstrate a boron-lined proportional tube based alternative system in the configuration of a coincidence counter. This report, providing background information for this project, is the deliverable under Task 1 of the project.

  13. Epoxy Resin Based Composites, Mechanical and Tribological Properties: A Review

    Directory of Open Access Journals (Sweden)

    S.A. Bello

    2015-12-01

    Full Text Available High fuel consumption by automobile and aerospace vehicles built from legacy alloys has been a great challenge to global design and material engineers. This has called for researches into material development for the production of lighter materials of the same or even superior mechanical properties to the existing materials in this area of applications. This forms a part of efforts to achieve the global vision 2025 i.e to reduce the fuel consumption by automobile and aerospace vehicles by at least 75 %. Many researchers have identified advanced composites as suitable materials in this regard. Among the common matrices used for the development of advanced composites, epoxy resin has attained a dominance among its counterparts because of its excellent properties including chemical, thermal and electrical resistance properties, mechanical properties and dimensional stability. This review is a reflection of the extensive study on the currently ongoing research aimed at development of epoxy resin hybrid nanocomposites for engineering applications. In this paper, brief explanation has been given to different terms related to the research work and also, some previous works (in accordance with materials within authors’ reach in the area of the ongoing research have been reported.

  14. Bonding of acrylic denture teeth to resin denture bases.

    Science.gov (United States)

    Geerts, G A V M; Stuhlinger, M E

    2012-07-01

    Anterior teeth debonding from dentures is a common problem. This study tested the bond strength of denture teeth to two types of denture resin, with and without grooving the ridge-lap surface. Bond strength and fracture type of three different groups were compared: 1. Teeth bonded to heat-cured polymethyl methacrylate (PMMA); 2. Teeth bonded to pour-type PMMA; 3. Grooved teeth bonded to pour-type PMMA. Specimens were manufactured following ISO standard 22112. Force values at failure were analysed using one-way analysis of variance, using the mixed procedure with confidence interval of 95%. Types of failure were identified as adhesive, cohesive or combination. In descending order, mean failure forces were 418.55N (Group One), 367.55N (Group Two) and 290.05N (Group Three). There was no significant difference between the means of groups 1 and 2 (p = 0.0627). Group Three differed from both other groups (p denture teeth (83% and 72% respectively); group Three showed predominantly cohesive fractures within the denture PMMA (75%). Without ridge-lap modification, the bond strengths of denture teeth to pour-type and heat-cured denture resin were similar. Failures were predominantly of cohesive nature within the teeth themselves. Grooving the ridge-lap reduced fracture resistance and led to breakages predominantly in denture PMMA.

  15. A 24-month evaluation of amalgam and resin-based composite restorations

    DEFF Research Database (Denmark)

    McCracken, Michael S; Gordan, Valeria V; Litaker, Mark S

    2013-01-01

    Knowing which factors influence restoration longevity can help clinicians make sound treatment decisions. The authors analyzed data from The National Dental Practice-Based Research Network to identify predictors of early failures of amalgam and resin-based composite (RBC) restorations....

  16. Characterization of a GEM-based fast neutron detector

    Energy Technology Data Exchange (ETDEWEB)

    Esposito, B., E-mail: basilio.esposito@enea.it [Associazione Euratom-ENEA sulla Fusione, Via E. Fermi, 45, I-00044 Frascati, Roma (Italy); Marocco, D.; Villari, R. [Associazione Euratom-ENEA sulla Fusione, Via E. Fermi, 45, I-00044 Frascati, Roma (Italy); Murtas, F. [Laboratori Nazionali di Frascati, Istituto Nazionale di Fisica Nucleare, Via E. Fermi, 40, I-00044 Frascati, Roma (Italy); Rodionov, R. [SRC RF TRINITI Troitsk, Moscow (Russian Federation)

    2014-03-21

    The neutron efficiency of a Gas Electron Multiplier (GEM)-based detector designed for fast neutron measurements in fusion devices was determined through the combined use of Monte Carlo (MCNPX) calculations and analysis of deuterium–deuterium and deuterium–tritium neutron irradiation experiments. The detector, characterized by a triple GEM structure flushed with a Ar/CO{sub 2}/CF{sub 4} – 45/15/40 gas mixture, features a digital read-out system and has two sub-units for the detection of 2.5+14 MeV neutrons and 14 MeV neutrons (U{sub DD} and U{sub DT}, respectively). The pulse height spectra (PHS) determined from the curves of experimental efficiency as a function of the detector's high voltage (HV) and the MCNPX-simulated PHS were compared using a fitting routine that finds the best match between the experimental and simulated PHS by assuming a parametric model for the relation between HV (that determines the detector's gain) and the energy deposited in the gas. This led to express the experimental neutron efficiency as a function of the discrimination level set on the deposited energy (energy threshold). The detector sensitivity to γ-rays was also analyzed and the operational range in which the γ-ray contribution to the signal is not negligible was determined. It is found that this detector can reach a maximum neutron efficiency of ∼1×10{sup −3} counts/n at 2.5 MeV (U{sub DD} sub-unit) and of ∼4×10{sup −3} counts/n at 14 MeV (U{sub DT} and U{sub DD} sub-units)

  17. A Project of Boron Neutron Capture Therapy System based on a Proton Linac Neutron Source

    Science.gov (United States)

    Kiyanagi, Yoshikai; Asano, Kenji; Arakawa, Akihiro; Fukuchi, Shin; Hiraga, Fujio; Kimura, Kenju; Kobayashi, Hitoshi; Kubota, Michio; Kumada, Hiroaki; Matsumoto, Hiroshi; Matsumoto, Akira; Sakae, Takeji; Saitoh, Kimiaki; Shibata, Tokushi; Yoshioka, Masakazu

    At present, the clinical trials of Boron Neutron Capture Therapy (BNCT) are being performed at research reactor facilities. However, an accelerator based BNCT has a merit that it can be built in a hospital. So, we just launched a development project for the BNCT based on an accelerator in order to establish and to spread the BNCT as an effective therapy in the near future. In the project, a compact proton linac installed in a hospital will be applied as a neutron source, and energy of the proton beam is planned to be less than about 10 MeV to reduce the radioactivity. The BNCT requires epithermal neutron beam with an intensity of around 1x109 (n/cm2/sec) to deliver the therapeutic dose to a deeper region in a body and to complete the irradiation within an hour. From this condition, the current of the proton beam required is estimated to be a few mA on average. Enormous heat deposition in the target is a big issue. We are aiming at total optimization of the accelerator based BNCT from the linac to the irradiation position. Here, the outline of the project is introduced and the moderator design is presented.

  18. DETERMINATION OF ION EXCHANGE EQUILIBRIUM CONSTANTS FOR THE WEAK ACID CATION AND THE WEAK BASE ANION EXCHANGE RESINS

    Institute of Scientific and Technical Information of China (English)

    TAOZuyi; WANGChangshou

    1992-01-01

    The general procedure based on the potentiometric titration has developed.According to the procedure,the rational equilibrium constants of the ion exchange reactions RH/Na,RH/Ca,RH/Sr,RH/Ba for the weak acid cation exchange resin D725 and ROH/Cl for the weak base anion exchange resin D705 have been determined.

  19. Boron removal from water and wastewater using new polystyrene-based resin grafted with glycidol

    Directory of Open Access Journals (Sweden)

    Joanna Kluczka

    2015-09-01

    Full Text Available A divinylbenzene cross-linked polystyrene resin with amine functional groups (Purolite A170 was grafted with glycidol and characterized as a novel sorbent, GLY-resin, for the oxoborate removal from model solutions and post-crystallization lye. The sorption behavior of GLY-resin was investigated using a batch system. The results showed that the sorption was maximal at pH=9.5. The equilibrium was achieved after 24 h. Calculations based on Langmuir model show the monolayer sorption capacity qm=1.3 mg/g and the fitted experimental data chemisorption as a dominating mechanism of boron sorption on GLY-resin. Boron removal from the solution containing 5 mg B/L and post-crystallization lye having a 9.1 mg B/L was 99% and 80% respectively. The thermodynamic calculations indicated the spontaneous and endothermic nature of the sorption process. The pseudo-second-order model adequately described the boron sorption on GLY-resin. Sorption−desorption efficiency was 100%, which means the boron sorption at next cycle did not decrease.

  20. Epoxy Resin Composite Based on Functional Hybrid Fillers

    Directory of Open Access Journals (Sweden)

    Mariusz Oleksy

    2014-08-01

    Full Text Available A study was carried out involving the filling of epoxy resin (EP with bentonites and silica modified with polyhedral oligomeric silsesquioxane (POSS. The method of homogenization and the type of filler affect the functional and canceling properties of the composites was determined. The filler content ranged from 1.5% to 4.5% by mass. The basic mechanical properties of the hybrid composites were found to improve, and, in particular, there was an increase in tensile strength by 44%, and in Charpy impact strength by 93%. The developed hybrid composites had characteristics typical of polymer nanocomposites modified by clays, with a fine plate morphology of brittle fractures observed by SEM, absence of a plate separation peak in Wide Angles X-ray Scattering (WAXS curves, and an exfoliated structure observed by TEM.

  1. Epoxy Resin Composite Based on Functional Hybrid Fillers

    Science.gov (United States)

    Oleksy, Mariusz; Szwarc-Rzepka, Karolina; Heneczkowski, Maciej; Oliwa, Rafał; Jesionowski, Teofil

    2014-01-01

    A study was carried out involving the filling of epoxy resin (EP) with bentonites and silica modified with polyhedral oligomeric silsesquioxane (POSS). The method of homogenization and the type of filler affect the functional and canceling properties of the composites was determined. The filler content ranged from 1.5% to 4.5% by mass. The basic mechanical properties of the hybrid composites were found to improve, and, in particular, there was an increase in tensile strength by 44%, and in Charpy impact strength by 93%. The developed hybrid composites had characteristics typical of polymer nanocomposites modified by clays, with a fine plate morphology of brittle fractures observed by SEM, absence of a plate separation peak in Wide Angles X-ray Scattering (WAXS) curves, and an exfoliated structure observed by TEM. PMID:28788177

  2. Effect of dentinal tubules and resin-based endodontic sealers on fracture properties of root dentin.

    Science.gov (United States)

    Jainaen, Angsana; Palamara, Joseph E A; Messer, Harold H

    2009-10-01

    To investigate the role of dentinal tubules in the fracture properties of human root dentin and whether resin-filled dentinal tubules can enhance fracture resistance. Crack propagation in human root dentin was investigated in 200 microm thick longitudinal samples and examined by light and scanning electron microscopy. 30 maxillary premolar teeth were prepared for work of fracture (Wf) test at different tubule orientations, one perpendicular and two parallel to dentinal tubules. Another 40 single canal premolars were randomly divided into four groups of 10 each: intact dentin, prepared but unobturated canal, canal obturated with epoxy rein (AH Plus/gutta percha), or with UDMA resin sealer (Resilon/RealSeal. The samples were prepared for Wf test parallel to dentinal tubules. Wf was compared under ANOVA with statistical significance set at pcanal preparation nor obturation using epoxy- or UDMA-based resins as sealer cements substantially influenced fracture properties of root dentin, despite extensive infiltration of dentinal tubules by both sealer cements.

  3. Influence of a peracetic acid-based immersion on indirect composite resin.

    Science.gov (United States)

    Samuel, Susana Maria Werner; Fracaro, Gisele Baggio; Collares, Fabrício Mezzomo; Leitune, Vicente Castelo Branco; Campregher, Ulisses Bastos

    2011-06-01

    The aim of this study was to evaluate the influence of immersion in a 0.2% peracetic acid-based disinfectant on the three-point flexural strength, water sorption and water solubility of an indirect composite resin. Specimens were produced according to ISO 4049:2000 specifications and were divided in two groups: Control group, with no disinfection and Disinfected group, with three 10 min immersions in the peracetic acid intercalated with 10 min immersions in sterile distilled water. All evaluations were conducted in compliance with ISO specifications. Three-point flexural strength, water sorption and solubility of indirect composite resin before and after immersion showed no statistical significant differences (p > 0.05) and met ISO standard requirements. Immersion in peracetic acid solution showed no influence in indirect composite resin tested properties.

  4. Adsorption characteristics of thorium on silica-based anion exchange resins

    Institute of Scientific and Technical Information of China (English)

    陈彦良; 赵龙; 韦悦周; 何林锋; 唐方东

    2015-01-01

    To isolate and separate thorium from nitric acid solutions, three silica-based anion exchange resins were synthesized. Batch experiments were carried out to investigate adsorption behavior of thorium in nitric acid solutions. Adsorption at different concentrations of nitric acid and thorium, influence of contact time and coex-isting metal ions, and effect of NO–3 were investigated in detail. It was found that at high HNO3 concentrations, the resins exhibited higher adsorption capacity and better affinity towards thorium. The adsorption kinetics could be described by the pseudo-second order model equation, while the adsorption isotherms were well cor-related by the Langmuir model. The maximum capacity towards thorium species on SiPyR-N4 was evaluated at 27–28 mg/g-resin. The thermodynamic parameters indicated the adsorption was an exothermic reaction. The presence of NO–3 was found to promote the retention of the thorium species.

  5. Synthesis of Antistatic Composite Based on Reaction Flame Retarding Unsaturated Polyester Resin

    Institute of Scientific and Technical Information of China (English)

    WANG Shui-ping; GONG Wen-hua; ZENG Jia

    2002-01-01

    The synthesis of reaction flame retarding unsaturated polyester resin and the flame retarding mechanism are investigated. By taking the synthesis flame retarding unsaturated polyester resin as a base material,glass fibers as reinforced material, under the condition of adding graphite or carbon black respectively, the composites were manufactured. The flame retarding and antistatic properties are also studied. In the experiment, bromidebearing flame retarding resin decomposed under a high temperature. Compound HBr was set out and retarded or stopped the flame. High concentration of HBr gas wall was formed between gas and solid phrases, which decreased flame. The results show that antistatic property of carbon black is higher than that of graphite. Adding a threshed value of 1% carbon black into composite, the antistatic property is at its highest value.

  6. Laminated composite based on polyester geotextile fibers and polyurethane resin for coating wood structures

    Directory of Open Access Journals (Sweden)

    Yuri Andrey Olivato Assagra

    2013-01-01

    Full Text Available New environmental laws have restricted the use of hardwood trees in overhead power lines structures, such as, poles and cross-arms, leading companies to seek alternative materials. Reforested wood coated with polymeric resin has been proposed as an environmental friendly solution, with improved electrical properties and protection against external agents, e.g. moisture, ultraviolet radiation and fungi. However, the single thin layer of resin, normally applied on such structures reveal to be inefficient, due to be easily damage during handling. In this paper, we present a composite coating, based on geotextile fibers and polyurethane resin that is suitable for wooden structures. Results obtained from two different tree species (from managed and reforested areas coated with the composite reveal that the additional layer not only provided a stronger adhesion between wood and ccoating layer but also a further improvement in the electrical properties and better protection against abrasion and moisture.

  7. Nanostructured composites based on carbon nanotubes and epoxy resin for use as radar absorbing materials

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Valdirene Aparecida [Instituto Tecnologico de Aeronautica (ITA), Sao Jose dos Campos, SP (Brazil); Folgueras, Luiza de Castro; Candido, Geraldo Mauricio; Paula, Adriano Luiz de; Rezende, Mirabel Cerqueira, E-mail: mirabelmcr@iae.cta.br [Instituto de Aeronautica e Espaco (IAE), Sao Jose dos Campos, SP (Brazil). Div. de Materiais; Costa, Michelle Leali [Universidade Estadual Paulista Julio de Mesquita Filho (DMT/UNESP), Guaratingueta, SP (Brazil). Dept. de Materiais e Tecnologia

    2013-07-01

    Nanostructured polymer composites have opened up new perspectives for multifunctional materials. In particular, carbon nanotubes (CNTs) present potential applications in order to improve mechanical and electrical performance in composites with aerospace application. The combination of epoxy resin with multi walled carbon nanotubes results in a new functional material with enhanced electromagnetic properties. The objective of this work was the processing of radar absorbing materials based on formulations containing different quantities of carbon nanotubes in an epoxy resin matrix. To reach this objective the adequate concentration of CNTs in the resin matrix was determined. The processed structures were characterized by scanning electron microscopy, rheology, thermal and reflectivity in the frequency range of 8.2 to 12.4 GHz analyses. The microwave attenuation was up to 99.7%, using only 0.5% (w/w) of CNT, showing that these materials present advantages in performance associated with low additive concentrations (author)

  8. Removal of dissolved oxygen from water using a Pd-resin based catalytic reactor

    Institute of Scientific and Technical Information of China (English)

    Wenxin SHI; Chongwei CUI; Liye ZHAO; Shuili YU; Xia YUN

    2009-01-01

    The removal of dissolved oxygen (DO) from water was studied experimentally in a Pd-resin base catalyst reactor using purified hydrogen gas as a reducing agent. The effects of various operating conditions, such as hydrogen and water flow rates, height of the catalytic resin bed, temperature, pH value and nan time, on the removal of DO, had been studied extensively. The results shows that DO could be removed by the reactor from ppm to ppb levels at ambient temperature. Increases of temperature, H2gas rate and the height of the catalytic resin were helpful to improve the DO removal rate. The change of pH value fom 4 to 12 resulted in no effect on DO removal. Reaction time was the key factor to control the DO removal efficiency. Only when the reaction time was longer than 2.3 minutes under the experimental conditions, could a very low DO level be achieved.

  9. Thermal neutron detectors based on hexagonal boron nitride epilayers

    Science.gov (United States)

    Doan, T. C.; Marty, A.; Li, J.; Lin, J. Y.; Jiang, H. X.

    2016-09-01

    Solid-state neutron detectors with high performances are urgently sought after for the detection of fissile materials. Until now, direct-conversion neutron detectors based on semiconductors with a measureable efficiency have not been realized. We have successfully synthesized hexagonal boron nitride (h-BN) epilayers with varying thicknesses (0.3 μm - 50 μm) by metal organic chemical vapor deposition (MOCVD) on sapphire substrates. In this paper, we present the detailed characterization of thermal neutron detectors fabricated from h-BN epilayers with a thickness up to 5 m to obtain insights into the h-BN epilayer thickness dependence of the device performance. The results revealed that the charge collection efficiency is almost independent of the h-BN epilayer thickness. By minimizing h-BN material removal by dry etching, it was shown that detectors incorporating an isotopically 10B-enriched h-BN epilayer of 2.7 μm in thickness exhibited an overall detection efficiency for thermal neutrons of 4% and a charge collection efficiency as high as 83%. By doing away altogether with dry etching, we have successfully realized a simple vertical 43 μm thick h-10BN detector which delivers a detection efficiency of 51.4% for thermal neutrons, which is the highest reported efficiency for any semiconductor-based neutron detector The h-BN detectors possess all the advantages of semiconductor devices including low cost, high efficiency and sensitivity, wafer-scale processing, compact size, light weight, and ability to integrate with other functional devices.

  10. Development and construction of a neutron beam line for accelerator-based boron neutron capture synovectomy.

    Science.gov (United States)

    Gierga, D P; Yanch, J C; Shefer, R E

    2000-01-01

    A potential application of the 10B(n, alpha)7Li nuclear reaction for the treatment of rheumatoid arthritis, termed Boron Neutron Capture Synovectomy (BNCS), is under investigation. In an arthritic joint, the synovial lining becomes inflamed and is a source of great pain and discomfort for the afflicted patient. The goal of BNCS is to ablate the synovium, thereby eliminating the symptoms of the arthritis. A BNCS treatment would consist of an intra-articular injection of boron followed by neutron irradiation of the joint. Monte Carlo radiation transport calculations have been used to develop an accelerator-based epithermal neutron beam line for BNCS treatments. The model includes a moderator/reflector assembly, neutron producing target, target cooling system, and arthritic joint phantom. Single and parallel opposed beam irradiations have been modeled for the human knee, human finger, and rabbit knee joints. Additional reflectors, placed to the side and back of the joint, have been added to the model and have been shown to improve treatment times and skin doses by about a factor of 2. Several neutron-producing charged particle reactions have been examined for BNCS, including the 9Be(p,n) reaction at proton energies of 4 and 3.7 MeV, the 9Be(d,n) reaction at deuteron energies of 1.5 and 2.6 MeV, and the 7Li(p,n) reaction at a proton energy of 2.5 MeV. For an accelerator beam current of 1 mA and synovial boron uptake of 1000 ppm, the time to deliver a therapy dose of 10,000 RBEcGy ranges from 3 to 48 min, depending on the treated joint and the neutron producing charged particle reaction. The whole-body effective dose that a human would incur during a knee treatment has been estimated to be 3.6 rem or 0.75 rem, for 1000 ppm or 19,000 ppm synovial boron uptake, respectively, although the shielding configuration has not yet been optimized. The Monte Carlo design process culminated in the construction, installation, and testing of a dedicated BNCS beam line on the high

  11. 18-year survival of posterior composite resin restorations with and without glass ionomer cement as base.

    NARCIS (Netherlands)

    Sande, F.H. van de; Rosa Rodolpho, P.A. Da; Basso, G.R.; Patias, R.; Rosa, Q.F. da; Demarco, F.F.; Opdam, N.J.M.; Cenci, M.S.

    2015-01-01

    OBJECTIVE: Advantages and disadvantages of using intermediate layers underneath resin-composite restorations have been presented under different perspectives. Yet, few long-term clinical studies evaluated the effect of glass-ionomer bases on restoration survival. The present study investigated the i

  12. Long-term performance of resin based fissure sealants placed in a general dental practice.

    NARCIS (Netherlands)

    Hevinga, M.; Opdam, N.J.M.; Bronkhorst, E.M.; Truin, G.J.; Huysmans, M.C.D.N.J.M.

    2010-01-01

    OBJECTIVES: The aim of the present retrospective study was to evaluate the long-term performance of resin based fissure sealants applied in a general dental practice. METHODS: Regularly attending patients visiting the practice between July 2006 until November 2007 and who had received sealants befor

  13. Assessment of the impact strength of the denture base resin polymerized by various processing techniques

    Directory of Open Access Journals (Sweden)

    Rajashree Jadhav

    2013-01-01

    Full Text Available Aim : To measure the impact strength of denture base resins polymerized using short and long curing cycles by water bath, pressure cooker and microwave techniques. Materials and Methods: For impact strength testing, 60 samples were made. The sample dimensions were 60 mm × 12 mm × 3 mm, as standardized by the American Standards for Testing and Materials (ASTM. A digital caliper was used to locate the midpoint of sample. The impact strength was measured in IZOD type of impact tester using CEAST Impact tester. The pendulum struck the sample and it broke. The energy required to break the sample was measured in Joules. Data were analyzed using Student′s " t" test. Results: There was statistically significant difference in the impact strength of denture base resins polymerized by long curing cycle and short curing cycle in each technique, with the long curing processing being the best. Conclusion: The polymerization technique plays an important role in the influence of impact strength in the denture base resin. This research demonstrates that the denture base resin polymerized by microwave processing technique possessed the highest impact strength.

  14. Fracture strength of root filled premolar teeth restored with silorane and methacrylate-based resin composite.

    Science.gov (United States)

    Taha, N A; Maghaireh, G A; Bagheri, R; Abu Holy, A

    2015-06-01

    To compare fracture characteristics of root-filled teeth with variable cavity design restored with a low shrinkage silorane and methacrylate-based resin composite. 77 extracted maxillary premolars were divided randomly into seven groups: (Group 1) intact teeth; (Groups 2-4) MOD plus endodontic access with the buccopalatal width of the occlusal isthmus equals one third of the intercuspal width; (Groups 5-7) MOD plus endodontic access with the buccopalatal width of the occlusal isthmus equals one half of the intercuspal width. Groups 2 and 5 were left unrestored, Groups 3 and 6 were restored with a silorane-based resin composite (Filtek P90) and Groups 4 and 7 with a methacrylate-based resin composite (Z250). Teeth were loaded in a universal testing machine; load and fracture patterns were recorded and compared statistically using 2-way ANOVA and t-test for pairwise comparisons and 1-way ANOVA with Dunnett test for multiple comparisons. Unrestored teeth became progressively weaker with more extensive preparations, Group 5 (unfilled ½) showed the lowest fracture load among the groups (71±22N, Presin composite have no superior strengthening effect over the conventional methacrylate-based resin composite in restoration of root filled teeth. Both materials showed similar fracture patterns. Root filled teeth are considerably weakened via restorative and endodontic procedures. A direct adhesive restoration will aid in preserving tooth structure as far as it provides enough strength. Copyright © 2015 Elsevier Ltd. All rights reserved.

  15. Azido--meconine-`high ortho’ Novolak resin-based negative photoresists for deep UV lithography

    Indian Academy of Sciences (India)

    Maneesh Sharma; Anant A Naik; Manoj Gaur; P Raghunathan; S V Eswaran

    2009-07-01

    Photoactive chemicals blended with polymers, solvents and certain other additives serve as photoresists. A new photoactive compound (PAC), azido--meconine absorbing in the deep UV region has been blended with `alternating’ and `semi-alternating’ and `high ortho’ alternating novolak resins, based on /-cresol. The new photoresists have been evaluated as a negative tone deep UV photoresist for mircolithography.

  16. Characteristics comparison between a cyclotron-based neutron source and KUR-HWNIF for boron neutron capture therapy

    Science.gov (United States)

    Tanaka, H.; Sakurai, Y.; Suzuki, M.; Masunaga, S.; Kinashi, Y.; Kashino, G.; Liu, Y.; Mitsumoto, T.; Yajima, S.; Tsutsui, H.; Maruhashi, A.; Ono, K.

    2009-06-01

    At Kyoto University Research Reactor Institute (KURRI), 275 clinical trials of boron neutron capture therapy (BNCT) have been performed as of March 2006, and the effectiveness of BNCT has been revealed. In order to further develop BNCT, it is desirable to supply accelerator-based epithermal-neutron sources that can be installed near the hospital. We proposed the method of filtering and moderating fast neutrons, which are emitted from the reaction between a beryllium target and 30-MeV protons accelerated by a cyclotron accelerator, using an optimum moderator system composed of iron, lead, aluminum and calcium fluoride. At present, an epithermal-neutron source is under construction from June 2008. This system consists of a cyclotron accelerator, beam transport system, neutron-yielding target, filter, moderator and irradiation bed. In this article, an overview of this system and the properties of the treatment neutron beam optimized by the MCNPX Monte Carlo neutron transport code are presented. The distribution of biological effect weighted dose in a head phantom compared with that of Kyoto University Research Reactor (KUR) is shown. It is confirmed that for the accelerator, the biological effect weighted dose for a deeply situated tumor in the phantom is 18% larger than that for KUR, when the limit dose of the normal brain is 10 Gy-eq. The therapeutic time of the cyclotron-based neutron sources are nearly one-quarter of that of KUR. The cyclotron-based epithermal-neutron source is a promising alternative to reactor-based neutron sources for treatments by BNCT.

  17. Physicochemical Properties of Epoxy Resin-Based and Bioceramic-Based Root Canal Sealers

    Science.gov (United States)

    Lee, Ju Kyung; Kwak, Sang Won; Ha, Jung-Hong; Lee, WooCheol

    2017-01-01

    Three bioceramic sealers (EndoSequence BC sealer, EndoSeal MTA, and MTA Fillapex) and three epoxy resin-based sealers (AH-Plus, AD Seal, and Radic-Sealer) were tested to evaluate the physicochemical properties: flow, final setting time, radiopacity, dimensional stability, and pH change. The one-way ANOVA and Tukey's post hoc test were used to analyze the data (P = 0.05). The MTA Fillapex sealer had a highest flow and the BC Sealer presented a flow significantly lower than the others (P MTA Fillapex samples were not set in humid incubator condition even after one month. EndoSeal MTA had the longest setting time among the measurable materials and Radic-Sealer and AD Seal showed shorter setting time than the AH-Plus (P MTA showed statistically higher values and MTA Fillapex showed statistically lower radiopacity (P MTA presented a significant increase of pH over experimental time for 4 weeks. In conclusion, the bioceramic sealer and epoxy resin-based sealers showed clinical acceptable physicochemical properties, but BC Sealer and MTA Fillapex were not set completely. PMID:28210204

  18. Effect of high-pressure polymerization on mechanical properties of PMMA denture base resin.

    Science.gov (United States)

    Murakami, Natsuko; Wakabayashi, Noriyuki; Matsushima, Rie; Kishida, Akio; Igarashi, Yoshimasa

    2013-04-01

    The aim of this study was to assess the effect of high-pressure polymerization on mechanical properties of denture base resin. A heat-curing denture base resin and an experimental PMMA were polymerized under 500MPa of pressure by means of an isostatic pressurization machine at 70°C for 24h to make rectangular specimens whose dimensions were 30mm×2mm×2mm. Each specimen was deflected on a three-point flexural test until either fracture occurred or the sample was loaded up to 8mm in deflection. The molecular weight of the PMMA without filler was analyzed using the high-speed liquid chromatography system. Increased ductility without fracture was shown in the specimens subjected to high pressure, while most of the control specimens (ambient pressure) fractured. The mean toughness of the PMMA specimens polymerized under the high pressure was significantly higher than the same material polymerized under ambient pressure (ppressure groups of the denture resin and the PMMA revealed a significantly lower mean 0.2% yield stress, flexural strength, and elastic modulus than control groups (ppressure specimens than were present in the controls. The increased toughness shown in the PMMA polymerized under the high pressure was presumably attributed to the higher molecular weight produced by the pressure. The result suggests a potential application of the high-pressure polymerization to the development of PMMA-based denture resin with improved fracture resistance.

  19. Multicenter Patch Testing With a Resol Resin Based on Phenol and Formaldehyde Within the International Contact Dermatitis Research Group

    DEFF Research Database (Denmark)

    Isaksson, M.; Ale, I.; Andersen, Klaus Ejner

    2015-01-01

    Background Contact allergy to phenol-formaldehyde resins (PFRs) based on phenol and formaldehyde is not detected by a p-tertiary-butylphenol-formaldehyde resin included in most baseline patch test series. Objective The aims of this study were to investigate the contact allergy rate to PFR-2...

  20. Progress on the realization of a new GEM based neutron diagnostic concept for high flux neutron beams

    Science.gov (United States)

    Croci, G.; Rebai, M.; Cazzaniga, C.; Palma, M. Dalla; Grosso, G.; Muraro, A.; Murtas, F.; Claps, G.; Pasqualotto, R.; Cippo, E. Perelli; Tardocchi, M.; Tollin, M.; Cavenago, M.; Gorini, G.

    2014-08-01

    Fusion reactors will need high flux neutron detectors to diagnose the deuterium-deuterium and deuterium-tritium. A candidate detection technique is the Gas Electron Multiplier (GEM). New GEM based detectors are being developed for application to a neutral deuterium beam test facility. The proposed detection system is called Close-contact Neutron Emission Surface Mapping (CNESM). The diagnostic aims at providing the map of the neutron emission due to interaction of the deuterium beam with the deuterons implanted in the beam dump surface. This is done by placing a detector in close contact, right behind the dump. CNESM uses nGEM detectors, i.e. GEM detectors equipped with a cathode that also serves as neutron-proton converter foil. After the realization and test of several small area prototypes, a full size prototype has been realized and tested with laboratory sources. Test on neutron beams are foreseen for the next months.

  1. Progress on the realization of a new GEM based neutron diagnostic concept for high flux neutron beams

    Energy Technology Data Exchange (ETDEWEB)

    Croci, G.; Tardocchi, M. [Istituto di Fisica del Plasma, Associazione EURATOM-ENEA-CNR, Milano, Italy and INFN, Sez. di Milano-Bicocca, Milano (Italy); Rebai, M.; Cippo, E. Perelli; Gorini, G. [Dipartimento di Fisica, Università degli Studi di Milano-Bicocca, Milano, Italy and INFN, Sez. di Milano-Bicocca, Milano (Italy); Cazzaniga, C. [Dipartimento di Fisica, Università degli Studi di Milano-Bicocca, Milano (Italy); Palma, M. Dalla; Pasqualotto, R.; Tollin, M. [Consorzio RFX - Associazione Euratom-Enea sulla Fusione, Padova (Italy); Grosso, G.; Muraro, A. [Istituto di Fisica del Plasma, Associazione EURATOM-ENEA-CNR, Milano (Italy); Murtas, F.; Claps, G. [INFN, Laboratori Nazionali di Frascati, Frascati (Roma) (Italy); Cavenago, M. [INFN, Laboratori Nazionali di Legnaro, Legnaro (Padova) (Italy)

    2014-08-21

    Fusion reactors will need high flux neutron detectors to diagnose the deuterium-deuterium and deuterium-tritium. A candidate detection technique is the Gas Electron Multiplier (GEM). New GEM based detectors are being developed for application to a neutral deuterium beam test facility. The proposed detection system is called Close-contact Neutron Emission Surface Mapping (CNESM). The diagnostic aims at providing the map of the neutron emission due to interaction of the deuterium beam with the deuterons implanted in the beam dump surface. This is done by placing a detector in close contact, right behind the dump. CNESM uses nGEM detectors, i.e. GEM detectors equipped with a cathode that also serves as neutron-proton converter foil. After the realization and test of several small area prototypes, a full size prototype has been realized and tested with laboratory sources. Test on neutron beams are foreseen for the next months.

  2. The teaching of posterior resin composites: planning for the future based on 25 years of research.

    Science.gov (United States)

    Wilson, Nairn H F; Lynch, Christopher D

    2014-05-01

    The restoration of posterior teeth affected by caries, trauma or wear remains one of the commonest procedures in the practice of dentistry. Over the past 20 years the first author and latterly the second author have led a series of surveys around the world to capture information on the teaching of posterior resin composites. The aim of this paper is to identify trends, reflect on the findings and make recommendations for the further development of this important aspect of the curriculum for primary dental qualifications. Surveys on the teaching of posterior resin composites were completed in 1986, 1997-99, 2004-05 and 2007-2009. The findings from these surveys were reviewed and drawn together to allow historical and contemporary international trends to be identified. Recommendations for further developments in the teaching of posterior resin composites were formulated from the cumulated data and trends identified. Information was available from a total of 679 survey returns. Increased teaching of posterior resin composites has been observed over the period of the surveys: while 90% of dental school curricula did not include any didactic teaching of posterior resin composites in the mid-1980s, this dropped to 4% or less in the late 1990s, and to 0% in the early 2000s. In the late 2000s, however, 21% of dental schools still did not teach the placement of resin composites in three-surface cavities in permanent molar teeth. Areas of confusion were reported in the teaching of certain aspects of cavity design, notably the use of bevels, and in the protection of operatively exposed dentine. While there has been steady growth in, and trends towards evidence-based teaching of posterior resin composites in dental schools around the world over the last 20-25 years, there is a need for further developments and harmonisation in this important aspect of curricula for primary dental qualifications. This need is now pressing, subsequent to the signing of the Minamata Convention

  3. Mechanical properties of four methylmethacrylate-based resins for provisional fixed restorations.

    Science.gov (United States)

    Hernandez, E P; Oshida, Y; Platt, J A; Andres, C J; Barco, M T; Brown, D T

    2004-01-01

    The use of a provisional restoration is an important phase in the treatment of the dental prosthetic patient. A good provisional restoration should satisfy the following requirements: pulpal protection, positional stability, ease in cleaning, accurate margins, wear resistance, dimensional stability, and serve as a diagnostic aid in treatment assessment and esthetics. There is a tendency for discoloration, occlusal wear, and fracture that eventually leads to unnecessary repair. Heat-processed and reinforced methacrylate-based resins have been used to improve the mechanical and physical properties of provisional restorations. Among various improvements, the interpenetrating network crosslinked PMMA (IPN) has been shown to have superior mechanical properties if manufactured through a dough compression molding process at 130 degrees C. However, there have been no published data that relate with the use of this material for fixed provisional restorations. The objective of this study was to compare four methyl methacrylate-based resins for provisional crowns and bridges with varying processing cycles, including JET [self-cure], ACRALON [heat-cured], titanium dioxide filled PMMA [heat-cured], and IPN [heat-cured denture tooth resin]. Properties studied included transverse strength, toughness, rigidity, and hardness. From the results of this study the following conclusions can be made: the IPN group may have had a lower degree of conversion as demonstrated by decreased strength, toughness, and hardness data as compared with Acralon. Increasing the polymerization cycle of unmodified Acralon resin causes a significant increase in strength.

  4. The Influence of Chicken Egg Shell as Fillers on Biocomposite Acrylic Resin for Denture Based

    Science.gov (United States)

    Lubis, M.; Ginting, M. H. S.; Dalimunthe, N. F.; Hasibuan, D. M. T.; Sastrodihardjo, S.

    2017-03-01

    This research was conducted to discover the influence of the addition of chicken egg shells microparticle as filler on the mechanical properties such as modulus of elasticity, modulus of rapture and particle size analysis on biocomposite acrylic resin for denture based. The raw materials used in this research were acrylic resin, egg shell, cold mold seals, gypsum, Vaseline and wax. The process of making biocomposite acrylic resin for denture based with mix the acrylic resin in ratio 2:1 (w/w). Then added the microparticle filler 0,10,20,30 (%w) to mold and boil in 75°C for 90 minutes and increase the temperature to 90 °C for 30 minutes. Took the sample and let it dried. The results of research showed the increase of modulus elasticity and modulus of rapture. The modulus of elasticity showed a very significant increase by adding fillers 10% of 2.123 GPa, which was only 1.932 GPa without adding the filler of chicken egg shells. For modulus of rapture showed the increase by adding fillers 20% of 48,311MPa, which was only 46,865 GPa without adding the filler of chicken egg shells

  5. Hardness of resin cement cured under different thickness of lithium disilicate-based ceramic

    Institute of Scientific and Technical Information of China (English)

    ZHANG Xuan; WANG Fu

    2011-01-01

    Background The lithium disilicate-based ceramic is a newly developed all-ceramic material,which is lithium disilicate-based and could be used for fabricating almost all kinds of restorations.The extent of light attenuation by ceramic material was material-dependent.Ceramic materials with different crystal composition or crystalline content would exhibit distinct light-absorbing characteristics.The aim of this study was to analyze the influence of ceramic thickness and light-curing time on the polymerization of a dual-curing resin luting material with a lithium disilicate-based ceramic.Methods A lithium disilicate-based ceramic was used in this study.The light attenuation caused by ceramic with different thickness was determined using a spectral radiometer.The commercial dual-cured resin cement was light-cured directly or through ceramic discs with different thickness (1,2 and 3 mm,respectively) for different times (10,20,30,40,50 and 60 seconds,respectively).The polymerization efficiency of resin cement was expressed in terms as Vickers hardness (VHN) measured after 24 hours storage.Two-way analysis of variance (ANOVA) and Tukey's HSD tests were used to determine differences.Results Intensity of polymerizing light transmitted through ceramic discs was reduced from 584 mW/cm2 to about 216 mW/cm2,80 mW/cm2 and 52 mW/cm2 at thicknesses of 1 mm,2 mm and 3 mm,respectively.Resin cement specimens self-cured alone showed significantly lower hardness values.When resin cement was light-cured through ceramic discs with a thickness of 1 mm,2 mm and 3 mm,no further increasing in hardness values was observed when light-curing time was more than 30 seconds,40 seconds and 60 seconds,respectively.Conclusions Within the limitation of the present study,ceramic thickness and light-curing time had remarkable influence on the polymerization of dual-cured resin cement.When resin cement is light-cured beneath a lithium disilicate ceramic with different thickness,prolonging light

  6. Characterization of a boron carbide-based polymer neutron sensor

    Science.gov (United States)

    Tan, Chuting; James, Robinson; Dong, Bin; Driver, M. Sky; Kelber, Jeffry A.; Downing, Greg; Cao, Lei R.

    2015-12-01

    Boron is used widely in thin-film solid-state devices for neutron detection. The film thickness and boron concentration are important parameters that relate to a device's detection efficiency and capacitance. Neutron depth profiling was used to determine the film thicknesses and boron-concentration profiles of boron carbide-based polymers grown by plasma enhanced chemical vapor deposition (PECVD) of ortho-carborane (1,2-B10C2H12), resulting in a pure boron carbide film, or of meta-carborane (1,7-B10C2H12) and pyridine (C5H5N), resulting in a pyridine composite film, or of pyrimidine (C4H4N2) resulting in a pure pyrimidine film. The pure boron carbide film had a uniform surface appearance and a constant thickness of 250 nm, whereas the thickness of the composite film was 250-350 nm, measured at three different locations. In the meta-carborane and pyridine composite film the boron concentration was found to increase with depth, which correlated with X-ray photoelectron spectroscopy (XPS)-derived atomic ratios. A proton peak from 14N (n,p)14C reaction was observed in the pure pyrimidine film, indicating an additional neutron sensitivity to nonthermal neutrons from the N atoms in the pyrimidine.

  7. Properties of silorane-based dental resins and composites containing a stress-reducing monomer.

    Science.gov (United States)

    Eick, J David; Kotha, Shiva P; Chappelow, Cecil C; Kilway, Kathleen V; Giese, Gregory J; Glaros, Alan G; Pinzino, Charles S

    2007-08-01

    To evaluate properties of silorane-based resins and composites containing a stress reducing monomer. Resin mixtures and composites were formulated containing (a) a developmental stress reducing monomer [TOSU; Midwest Research Institute]; (b) Sil-Mix (3M-ESPE); (c) photo cationic initiator system. Standard BISGMA/TEGDMA resin (B/T) and composite (Filtek Z250) were used as controls. Polymerization volume change was measured using a NIST mercury dilatometer and polymerization stress using an Enduratec mechanical testing machine. Three point bend tests determined flexural elastic modulus, work of fracture, and ultimate strength (ADA 27; ISO 4049). Fracture toughness was measured using ASTM E399-90. Four groups of resins and composites were tested: Sil-Mix, methacrylate standard, and Sil-Mix with two addition levels of TOSU. An ANOVA was used and significant differences ranked using Student-Newman-Keuls test (alpha=0.05). Polymerization stress values for resins containing TOSU were significantly less than the other materials. Polymerization shrinkage values for Sil-Mix formulations were significantly less than for B/T, but were not different from each other. TOSU-containing formulations generally had somewhat lower mechanical properties values than Sil-Mix or B/T. Polymerization stress values for Sil-Mix-based composites were significantly less as compared to Z250. The 1wt.% TOSU composite had the lowest stress. No difference between composite groups was noted for fracture toughness or work of fracture. For ultimate strength, the 5wt.% TOSU formulation differed significantly from Z250. All Sil-Mix formulations had elastic modulus values significantly different from Z250. The ability of TOSU to reduce polymerization stress without a proportional reduction in mechanical properties provides a basis for improvement of silorane-based composites.

  8. Scintillation neutron detectors based on solid-state photomultipliers and lightguides

    Energy Technology Data Exchange (ETDEWEB)

    Litvin, V. S., E-mail: vlitvin@inr.ru; Marin, V. N.; Karaevsky, S. K.; Trunov, D. N.; Axenov, S. N.; Stolyarov, A. A.; Sadykov, R. A. [Russian Academy of Sciences, Institute for Nuclear Research (Russian Federation)

    2016-01-15

    Neutron detectors based on scintillation screens ZnS(Ag)/LiF and solid-state photomultipliers have been developed. Lightguides are used to collect light. The application of a coincidence scheme provides a low dark count and a neutron detection efficiency as high as 70%. A scheme of x-y neutron detector based on wavelength shifting fibers is also proposed. Tests of the proposed versions of detectors in a neutron beam have shown their efficiency.

  9. Cytotoxicity and cytokine expression induced by silorane and methacrylate-based composite resins

    Science.gov (United States)

    LONGO, Daniele Lucca; PAULA-SILVA, Francisco Wanderley Garcia; FACCIOLI, Lucia Helena; GATÓN-HERNÁNDEZ, Patrícia Maria; de QUEIROZ, Alexandra Mussolino; da SILVA, Léa Assed Bezerra

    2016-01-01

    ABSTRACT The successful use of composite resins in Dentistry depends on physicochemical properties, but also on the biological compatibility of resins, because of the close association between pulp and dentin. Objective The aim of this study was to evaluate cytotoxicity and cytokine production induced by light-cured or non-light-cured methacrylate-based and silorane composite resins in RAW 264.7 macrophages. Material and Methods Cells were stimulated with the extracts from light-cured or non-light-cured composite resins. After incubation for 24 h, cytotoxicity was assessed with the lactate dehydrogenase (LDH) and methyl thiazolyl tetrazolium (MTT) assays, and total protein was quantified using the Lowry method. TNF-α detection was examined with an enzyme-linked immunosorbent assay (ELISA) conducted with cell supernatants after cell stimulation for 6, 12, and 24 h. Data were analyzed using one-way analysis of variance (ANOVA) and Tukey’s post hoc test (α=0.05). Results KaloreTM and FiltekTM Silorane were cytotoxic with or without light curing (p0.05). However, after 24 h FiltekTM Silorane inhibited the production of TNF-α (p<0.05). Conclusions KaloreTM and FiltekTM Silorane were cytotoxic regardless of light curing. The extract obtained from KaloreTM after 15 days of incubation stimulated the production of TNF-α, unlike that obtained from FiltekTM Silorane. PMID:27556204

  10. Work of adhesion of resin on treated lithia disilicate-based ceramic.

    Science.gov (United States)

    Della Bona, Alvaro; Shen, Chiayi; Anusavice, Kenneth J

    2004-05-01

    This study is to test the hypothesis that chemical etching and silane coating of a ceramic surface will influence the work of adhesion (WA) of adhesive resin to dental ceramic. A hot-pressed lithia disilicate-based ceramic was used as a model material to investigate the influence of probing media and surface treatments on WA using a dynamic contact angle analyzer. Eighty ceramic specimens were randomly divided into eight experimental groups and treated as follows: (1 and 3) as polished; (2 and 4) etched with 9.5% hydrofluoric acid (HF) for 1 min; (5) etched with 4% acidulated phosphate fluoride (APF) for 2 min; (6) silane coated; (7) etched with HF for 1 min and silane coated; (8) etched with APF for 2 min and silane coated. Advancing and receding contact angles (theta(a) and theta(r)) were measured using high purity water (gamma = 72.6 mN/m) for groups 1 and 2, and a liquid resin (gamma = 39.7) for groups 3-8 as probing liquids. The liquid resin medium yielded a lower WA than water. Silanization produced a significantly lower WA (p < 0.001) than non-silanated surfaces. Etching alone consistently yielded a greater WA for all surface treatments (p < 0.001). The silanated ceramic surface exhibited a lower surface energy and did not enhance bonding to the liquid resin by work of adhesion.

  11. CR-39 detector based thermal neutron flux measurements, in the photo neutron project

    Energy Technology Data Exchange (ETDEWEB)

    Mameli, A.; Greco, F.; Fidanzio, A. [U.O. di Fisica Sanitaria Policlinico A. Gemelli, Universita Cattolica S. Cuore, Roma (Italy); Fusco, V. [U.O. di Radioterapia, Centro di Riferimento Oncologico della Basilicata, CROB Rionero Pz (Italy); Cilla, S.; D' Onofrio, G.; Grimaldi, L.; Augelli, B.G. [U.O. di Fisica Sanitaria, Centro di Ricerca e Formazione ad Alta Tecnologia nelle Scienze Biomediche dell' Universita Cattolica S. Cuore, Campobasso (Italy); Giannini, G.; Bevilacqua, R.; Totaro, P. [Dipartimento di Fisica-Universita di Trieste e INFN Sez Trieste, Padriciano, Trieste (Italy); Tommasino, L. [Consultant, Via Cassia 1727, 00123 Roma (Italy); Azario, L. [Istituto di Fisica, Universita Cattolica del S. Cuore, Roma (Italy); Piermattei, A. [Istituto di Fisica, Universita Cattolica del S. Cuore, Roma (Italy)], E-mail: a.piermattei@rm.unicatt.it

    2008-08-15

    PhoNeS (photo neutron source) is a project aimed at the production and moderation of neutrons by exploiting high energy linear accelerators, currently used in radiotherapy. A feasibility study has been carried out with the scope in mind to use the high energy photon beams from these accelerators for the production of neutrons suitable for boron neutron capture therapy (BNCT). Within these investigations, it was necessary to carry out preliminary measurements of the thermal neutron component of neutron spectra, produced by the photo-conversion of X-ray radiotherapy beams supplied by three LinAcs: 15 MV, 18 MV and 23 MV. To this end, a simple passive thermal neutron detector has been used which consists of a CR-39 track detector facing a new type of boron-loaded radiator. Once calibrated, this passive detector has been used for the measurement of both the thermal neutron component and the cadmium ratio of different neutron spectra. In addition, bubble detectors with a response highly sensitive to thermal neutrons have also been used. Both thermal neutron detectors are simple to use, very compact and totally insensitive to low-ionizing radiation such as electrons and X-rays. The resultant thermal neutron flux was above 10{sup 6} n/cm{sup 2}s and the cadmium ratio was no greater than 15 for the first attempt of photo-conversion of X-ray radiotherapy beams.

  12. Staining susceptibility of methacrylate and silorane-based materials: influence of resin type and storage time

    Directory of Open Access Journals (Sweden)

    Leonardo Fernandes da Cunha

    2013-06-01

    Full Text Available Introduction: The color stability of composite resins is a fundamental factor in their clinical behavior. Objective: To evaluate the color stability of composite resins of different colors exposed to a cola-based soft drink after different storage periods. Additionally, three methacrylate-based materials and one silorane-based material were evaluated. Material and methods: Specimens of three methacrylate-based materials (Opallis EA3, DA3 and T-Neutral; Filtek Supreme XT A3E, A3D and CT; 4 Seasons A3 Enamel, A3 Dentin and High Value and one silorane-based material (Filtek P90 A3 were prepared, light-cured for 40 s, and manually polished with Sof-Lex discs. Samples were stored for 1 h, 24 h or 7 days. The color was evaluated by CIE-Lab system before and after immersion for 10 min in a cola-based soft drink. Color variation (∆E was calculated from individual values of L*, a* and b*, being considered imperceptible when < 1, clinically acceptable when ≤ 3.3, and clinically inacceptable when higher than 3.3. Data were evaluated by two-way Anova and Dunnett’s T3 tests (α = 0.05. Results: There were differences among the resins (p < 0.001, with an interaction effect being also observed (p < 0.001. Storage time was not significant (p = 0.246. P90 showed a ∆E smaller than one unit at all studied times. Supreme XT CT and 4 Seasons High Value showed higher ∆E, but not above the critical value of 3.3. The only material that showed ∆E higher than 3.3 was Opallis DA3 after 1 h of storage. Conclusion: The silorane-based composite resin showed smaller ∆E at the times studied.

  13. Allergic effects of the residual monomer used in denture base acrylic resins

    Science.gov (United States)

    Rashid, Haroon; Sheikh, Zeeshan; Vohra, Fahim

    2015-01-01

    Denture base resins are extensively used in dentistry for a variety of purposes. These materials can be classified as chemical, heat, light, and microwave polymerization materials depending upon the factor which starts the polymerization reaction. Their applications include use during denture base construction, relining existing dentures, and for fabrication of orthodontic removable appliances. There have been increased concerns regarding the safe clinical application of these materials as their biodegradation in the oral environment leads to harmful effects. Along with local side effects, the materials have certain occupational hazards, and numerous studies can be found in the literature mentioning those. The purpose of this article is to outline the cytotoxic consequences of denture base acrylic resins and clinical recommendations for their use. PMID:26929705

  14. Effect of different solutions on color stability of acrylic resin-based dentures

    Directory of Open Access Journals (Sweden)

    Marcelo Coelho Goiato

    2014-01-01

    Full Text Available The aim of this study was to evaluate the effect of thermocycling and immersion in mouthwash or beverage solutions on the color stability of four different acrylic resin-based dentures (Onda Cryl, OC; QC20, QC; Classico, CL; and Lucitone, LU. The factors evaluated were type of acrylic resin, immersion time, and solution (mouthwash or beverage. A total of 224 denture samples were fabricated. For each type of resin, eight samples were immersed in mouthwashes (Plax-Colgate, PC; Listerine, LI; and Oral-B, OB, beverages (coffee, CP; cola, C; and wine, W, and artificial saliva (AS; control. The color change (DE was evaluated before (baseline and after thermocycling (T1, and after immersion in solution for 1 h (T2, 3 h (T3, 24 h (T4, 48 h (T5, and 96 h (T6. The CIE Lab system was used to determine the color changes. The thermocycling test was performed for 5000 cycles. Data were submitted to three-way repeated-measures analysis of variance and Tukey's test (p < 0.05. When the samples were immersed in each mouthwash, all assessed factors, associated or not, significantly influenced the color change values, except there was no association between the mouthwash and acrylic resin. Similarly, when the samples were immersed in each beverage, all studied factors influenced the color change values. In general, regardless of the solution, LU exhibited the greatest DE values in the period from T1 to T5; and QC presented the greatest DE values at T6. Thus, thermocycling and immersion in the various solutions influenced the color stability of acrylic resins and QC showed the greatest color alteration.

  15. Concomitant contact allergy to the resins, reactive diluents and hardener of a bisphenol A/F-based epoxy resin in subway construction workers.

    Science.gov (United States)

    Chu, Chia-Yu; Pontén, Ann; Sun, Chee-Ching; Jee, Shiou-Hwa

    2006-03-01

    An outbreak of suspected contact dermatitis among subway construction workers was suspected to be due to a new bisphenol A/F-based epoxy resin system (ERS). The construction workers used ERSs during the insertion of iron bars into concrete walls. The objective of the study was to determine the components (if any) of the ERS responsible for the contact allergy. Patch testing was performed on 20 of the 22 construction workers who had had contact with the ERS, and to the various subcomponents of component A on 5 of the 7 who reacted to this component. 9 patients (9/22, 40.9%) had clinical symptoms and signs of suspected contact dermatitis at presentation. 7 of these 9, but none of the 11 asymptomatic individuals, were positive to component A, while all were negative to component B. Of the 5 cases receiving further patch testing, all reacted to m-xylylene diamine, 4 to 1,6-hexanediol diglycidyl ether, 3 to epoxy resins of the bisphenol F-type and trimethylolpropane triglycidyl ether 0.25% petrolatum, and only 1 to epoxy resins of the bisphenol A-type. Contact allergy to ERSs may involve hardeners and diluents as well as resins, and patch testing for reaction to all components should be performed.

  16. Improving water resistance of wheat straw-based medium density fiberboards bonded with aminoplastic and phenolic resins

    Directory of Open Access Journals (Sweden)

    Laborie, M.-P. G.

    2007-05-01

    Full Text Available A long standing problem in the manufacture of wheat-straw based composites with cost-effective formaldehyde-based resins is their poor water resistance as demonstrated by their large water thickness swell. In this study, wheat straw based medium density fiberboards were manufactured using 3 resin/wax systems: a melamine-urea-formalde-hyde resin with either low or high wax content, and a phenol-formal-dehyde resin with low wax content. The flexural properties, internal bond strength, and thickness swell of the resulting composites were evaluated and compared according to ASTM methods. The three MDF compos-ites passed the requirements for MDF in interior application, except for the MDF manufactured with the aminoplastic resin and low wax content that failed to provide acceptable thickness swell. Using the phenolic resin in combination with low wax content resulted in a higher grade MDF composite, grade 120, than with the aminoplastic and high wax content. This study demonstrates that wheat straw based MDF manu-factured with cost-effective aminoplastic and phenolic resins can have flexural properties, internal bond strength and thickness swell perfor-mance above the requirements from the American National Standards Institute.

  17. Reinforcement of Aluminum Oxide Filler on the Flexural Strength of Different Types of Denture Base Resins: An In vitro Study.

    Science.gov (United States)

    Dhole, Rohit I; Srivatsa, G; Shetty, Rohit; Huddar, Dayanand; Sankeshwari, Banashree; Chopade, Swapnil

    2017-04-01

    Acrylic resins have been used extensively for the fabrication of denture bases because of their aesthetic qualities, ease of manipulation and repairability. Flexural fatigue of the denture base has been shown to be a factor in the clinical failure of polymethyl methacrylate resin dentures. Also, the fracture can result from impact, fatigue or degradation of the base material. Hence, there is a need to increase the strength of denture base resins. To evaluate the effect of reinforcing alumina oxide filler on the flexural strength of different acrylic resins. A total of 180 acrylic specimens were fabricated, which were divided into three groups self cure acrylic resin (SC), conventional heat cure resin (HC) and high strength heat cure resin (HI). Each group was divided into four subgroups i.e., control group and the specimens of the remaining three groups were reinforced with aluminum oxide (Al2O3) powder by 5%, 10% and 15% by weight. Specimens were stored in distilled water for one week; flexural strength was tested by universal testing machine. Results were analysed by one-way analysis of variance and post-hoc Tukey paired group comparison tests. Flexural strength of SC increased by 9%, 13% and 19%, Flexural strength of HC increased by 8%, 15% and 19% and that of HI increased by 21%, 26% and 29% compared to control group by adding 5%,10% and 15% of alumina filler (p-value lead to more clinical success.

  18. {sup 4}H-SiC neutron sensors based on ion implanted {sup 10}B neutron converter layer

    Energy Technology Data Exchange (ETDEWEB)

    Issa, F.; Ottaviani, L.; Vervisch, V.; Ferone, R.; Palais, O. [Universite Aix-Marseille, Marseille 13397, (France); Szalkai, D.; Klix, A. [Karlsruhe Institute of Technology, Institute of Neutron Physics and Reactor Technology, Karlsruhe 76344, (Germany); Vermeeren, L. [SCK-CEN, B-2400 Mol, (Belgium); Lyoussi, A. [Laboratoire Dosimetrie Capteurs Instrumentation, CEA, Cadarache 13108, (France); Kuznetsov, A. [University of Oslo, NO-0316 Oslo, (Norway); Lazar, M. [AMPERE, UMR 500, INSA de Lyon, 69621 Villeurbanne, (France); Hallen, A. [KTH, Electrum 229, 16440 Kista, (Sweden)

    2015-07-01

    In the framework of the I{sub S}MART project the main aim is to develop an innovative complete radiation detection system based on silicon carbide technology in view to detect neutrons (thermal and fast) and photons for harsh environments. In the present work two geometries have been realized based on ion implantation of boron. In the first geometry, {sup 10}B ions have been implanted into the Al metallic contact to create the neutron converter layer. In the second geometry one single process has been used to realize both the p+-layer and the neutron converter layer. The technological processes followed to fabricate these detectors, with a study of their electrical behavior and their responses under thermal neutron irradiations are addressed in this paper. (authors)

  19. Development of a thermal neutron detector based on scintillating fibers and silicon photomultipliers.

    Science.gov (United States)

    Barbagallo, Massimo; Cosentino, Luigi; Greco, Giuseppe; Montereali, Rosa Maria; Pappalardo, Alfio; Scirè, Carlotta; Scirè, Sergio; Vincenti, Maria Aurora; Finocchiaro, Paolo

    2010-09-01

    We propose a technique for thermal neutron detection, based on a (6)Li converter placed in front of scintillating fibers readout by means of silicon photomultipliers. Such a technique allows building cheap and compact detectors and dosimeters, thus possibly opening new perspectives in terms of granular monitoring of neutron fluxes as well as space-resolved neutron detection.

  20. Tomsk Polytechnic University cyclotron as a source for neutron based cancer treatment

    Energy Technology Data Exchange (ETDEWEB)

    Lisin, V. A. [Cancer Research Institute, 5 Kooperativny St., Tomsk 634050 (Russian Federation); Tomsk Polytechnic University, 30 Lenina av., Tomsk 634050 (Russian Federation); Bogdanov, A. V.; Golovkov, V. M.; Sukhikh, L. G.; Verigin, D. A., E-mail: verigin@tpu.ru [Tomsk Polytechnic University, 30 Lenina av., Tomsk 634050 (Russian Federation); Musabaeva, L. I. [Cancer Research Institute, 5 Kooperativny St., Tomsk 634050 (Russian Federation)

    2014-02-15

    In this paper we present our cyclotron based neutron source with average energy 6.3 MeV generated during the 13.6 MeV deuterons interactions with beryllium target, neutron field dosimetry, and dosimetry of attendant gamma fields. We also present application of our neutron source for cancer treatment.

  1. Treatment Planning for Accelerator-Based Boron Neutron Capture Therapy

    Science.gov (United States)

    Herrera, María S.; González, Sara J.; Minsky, Daniel M.; Kreiner, Andrés J.

    2010-08-01

    Glioblastoma multiforme and metastatic melanoma are frequent brain tumors in adults and presently still incurable diseases. Boron Neutron Capture Therapy (BNCT) is a promising alternative for this kind of pathologies. Accelerators have been proposed for BNCT as a way to circumvent the problem of siting reactors in hospitals and for their relative simplicity and lower cost among other advantages. Considerable effort is going into the development of accelerator-based BNCT neutron sources in Argentina. Epithermal neutron beams will be produced through appropriate proton-induced nuclear reactions and optimized beam shaping assemblies. Using these sources, computational dose distributions were evaluated in a real patient with diagnosed glioblastoma treated with BNCT. The simulated irradiation was delivered in order to optimize dose to the tumors within the normal tissue constraints. Using Monte Carlo radiation transport calculations, dose distributions were generated for brain, skin and tumor. Also, the dosimetry was studied by computing cumulative dose-volume histograms for volumes of interest. The results suggest acceptable skin average dose and a significant dose delivered to tumor with low average whole brain dose for irradiation times less than 60 minutes, indicating a good performance of an accelerator-based BNCT treatment.

  2. Effect of aggressive beverage on the color stability of different nano-hybrid resin based composite

    Directory of Open Access Journals (Sweden)

    Hicham Oday Nuaimi

    2014-01-01

    Full Text Available Background: The purpose of this study was to evaluate the color stability of different types of nano-hybrid resin based composite restorative materials upon exposure to aggressive staining solutions (coffee and tea over time. The color of all specimens before and after storage in the solutions were measured by a spectrophotometer based on CIE Lab system that is recommended by the American Dental Association and the color differences thereby is calculated. Materials and Methods: The color differences of three nano-hybrid composites after immersion for 30 days in tea and coffee as aggressive beverage solutions. Results: Within the limitations of the study, Venus Diamond was found the most color stable in tea, while Ceram X was shown the most color stable in coffee. There were statistically significant differences between Filtek 350 XT in tea and coffee storage (P 0.005. Conclusion: Staining solutions are significant factors that affect color stability of composite resins.

  3. Staining of resin-based veneering materials with coffee and tea.

    Science.gov (United States)

    Um, C M; Ruyter, I E

    1991-05-01

    Two light-activated, and three heat-polymerized, resin-based veneering materials were exposed to boiled coffee, filtered coffee, or tea at 50 degrees C and evaluated for color stability. Specimens immersed in distilled water in the dark at 37 degrees C for 4 months were also assessed. One of the light-activated, resin-based veneering materials underwent intrinsic discoloration during the long-term immersion both in distilled water and in the staining solutions. The discoloration of the other materials by tea was mainly due to surface adsorption of the colorants. Discoloration by coffee was due to adsorption, and also to absorption of colorants by two of the materials investigated. This absorption and penetration of colorants into the organic phase of the veneering materials were probably due to compatibility of the polymer phase with the yellow colorants of coffee.

  4. Production and characterization of MDF using eucalyptus fibers and castor oil-based polyurethane resin

    Directory of Open Access Journals (Sweden)

    Campos Cristiane Inácio de

    2004-01-01

    Full Text Available The growing popularity of wooden panels renders this market segment increasingly competitive. MDF (Medium Density Fiberboard, in particular, is widely employed for a variety of applications, including civil construction, furniture, and packaging. This paper discusses a study of MDF produced from alternative raw materials, i.e., Eucalyptus fibers and castor-oil-based polyurethane resin. Physical and mechanical tests were performed to determine the MDF's modulus of elasticity and modulus of rupture in static bending tests, its swelling, water absorption, moisture and density. The results of the physical and mechanical characterization of this laboratory-produced MDF are discussed and compared with the Euro MDF Board standard. MDF produced with eucalyptus fiber and castor-oil-based polyurethane resin presents results very satisfactory.

  5. The biocompatibility evaluation of epoxy resin-based root canal sealers in vitro.

    Science.gov (United States)

    Huang, Tsui-Hsien; Yang, Jaw-Ji; Li, Huei; Kao, Chia-Tze

    2002-01-01

    The cytotoxic and mutagenic effects of epoxy resin-based root canal sealer AH26 and AH-Plus were determined in vitro. Root canal sealers were eluted for 24 h in dimethyl sulfoxide (DMSO) and diluted in culture medium. Cytotoxic effects were assessed using the MTT [tetrazolium dye, 3-(4.5-dimethylthiazol-2-yl)-2.5-diphenyltetrazolium bromide, C18H16N5SBr] assay for mitochondrial enzyme activity and also the cell viability. Genotoxicity assays were assessed using the alkaline single cell gel electrophoresis assay (comet assay) for DNA damage measurement. Result indicated that both the AH26 and AH-Plus sealers exhibited a dose-dependent increase in astrocyte toxic effects. Additionally, dose-dependent astrocyte DNA damage was also noted for both sealers. Therefore, these epoxy resin-based sealers, AH26 and AH-Plus demonstrated both cytotoxicity and genotoxicity in vitro.

  6. Evaluation of chitosan quaternary ammonium salt-modified resin denture base material.

    Science.gov (United States)

    Song, Rong; Zhong, Zhaohua; Lin, Lexun

    2016-04-01

    Chitosan quaternary ammonium salt displays good antioxidant and antibacterial characteristics and it shows appreciable solubility in water. When added to the traditional denture material to form a resin base, it could promote good oral health by improving the oral environment. In this study, chitosan quaternary ammonium salt was added to the denture material following two different methods. After three months of immersion in artificial saliva, the specimens were tested for tensile strength and were scanned by electron microscope. The murine fibroblast cytotoxicity and antibacterial properties were also tested. The result showed no significant differences in the tensile strength and in the proliferation of murine L929 fibroblast cells. The two structures of chitosan quaternary ammonium salt-modified denture material had different degrees of corrosion resistance and antimicrobial properties. These results indicate that chitosan quaternary ammonium salt-modified resin denture base material has the potential to become a new generation oral denture composite material.

  7. Isothermal curing of polymer layered silicate nanocomposites based upon epoxy resin by means of anionic homopolymerisation

    OpenAIRE

    Román Concha, Frida Rosario; Calventus Solé, Yolanda; Colomer Vilanova, Pere; Hutchinson, John M.

    2013-01-01

    The use of an initiator, 4-(dimethylamino) pyridine (DMAP), to promote an anionic homopolymerisation reaction for the isothermal cure of polymer layered silicate (PLS) nanocomposites based on an epoxy resin, as well as the effect of the nanoclay content, have been studied by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), dielectric relaxation spectroscopy (DRS) and transmission electron microscopy (TEM). The vitrification phenomenon was observed during the isotherm...

  8. Phenol-Formaldehyde Resin-Based Carbons for CO2 Separation at Sub-Atmospheric Pressures

    OpenAIRE

    2016-01-01

    The challenge of developing effective separation and purification technologies that leave much smaller energy footprints is greater for carbon dioxide (CO2) than for other gases. In addition to its involvement in climate change, CO2 is present as an impurity in biogas and bio-hydrogen (biological production by dark fermentation), in post-combustion processes (flue gas, CO2-N2) and many other gas streams. Selected phenol-formaldehyde resin-based activated carbons prepared in our laboratory hav...

  9. The mechanical properties of nanofilled resin-based composites: characterizing discrete filler particles and agglomerates using a micromanipulation technique.

    LENUS (Irish Health Repository)

    Curtis, Andrew R

    2009-02-01

    To assess the mechanical properties of discrete filler particles representative of several inorganic fillers in modern dental resin-based composites (RBCs) and to assess the validity of a novel micromanipulation technique.

  10. Comparison of Shear Bond Strengths of three resin systems for a Base Metal Alloy bonded to

    Directory of Open Access Journals (Sweden)

    Jlali H

    1999-12-01

    Full Text Available Resin-bonded fixed partial dentures (F.P.D can be used for conservative treatment of partially edentulous"npatients. There are numerous studies regarding the strength of resin composite bond to base meta! alloys. Shear bond"nstrength of three resin systems were invistigated. In this study these systems consisted of: Panavia Ex, Mirage FLC and"nMarathon V. Thirty base metal specimens were prepared from rexillium III alloy and divided into three groups. Then each"ngroup was bonded to enamel of human extracted molar teeth with these systems. All of specimens were stored in water at"n37ac for 48 hours. A shear force was applied to each specimen by the instron universal testing machine. A statistical"nevaluation of the data using one-way analysis of variance showed that there was highly significant difference (P<0.01"nbetween the bond strengths of these three groups."nThe base metal specimens bonded with panavia Ex luting agent, exhibited the highest mean bond strength. Shear bond"nstrength of the specimens bonded to enamel with Mirage F1C showed lower bond strenght than panavia EX. However, the"nlowest bond strength was obtained by the specimens bonded with Marathon V.

  11. Effect of different bleaching strategies on microhardness of a silorane-based composite resin

    Science.gov (United States)

    Bahari, Mahmoud; Savadi Oskoee, Siavash; Mohammadi, Narmin; Ebrahimi Chaharom, Mohammad Esmaeel; Godrati, Mostafa; Savadi Oskoee, Ayda

    2016-01-01

    Background. Dentists’ awareness of the effects of bleaching agents on the surface and mechanical properties of restorative materials is of utmost importance. Therefore, this in vitro study was undertaken to investigate the effects of different bleaching strategies on the microhardness of a silorane-based composite resin. Methods. Eighty samples of a silorane-based composite resin (measuring 4 mm in diameter and 2 mm in thickness) were prepared within acrylic molds. The samples were polished and randomly assigned to 4 groups (n=20). Group 1 (controls) were stored in distilled water for 2 weeks. The samples in group 2 underwent a bleaching procedure with 15% carbamide peroxide for two weeks two hours daily. The samples in group 3 were bleached with 35% hydrogen peroxide twice 5 days apart for 30 minutes each time. The samples in group 4 underwent a bleaching procedure with light-activated 35% hydrogen peroxide under LED light once for 40 minutes. Then the microhardness of the samples was determined using Vickers method. Data were analyzed with one-way ANOVA and post hoc Tukey tests (P 0.05). Conclusion. Bleaching agents decreased microhardness of silorane-based composite resin restorations, the magnitude of which depending on the bleaching strategy used. PMID:28096946

  12. Sensitivity studies of beam directionality, beam size, and neutron spectrum for a fission converter-based epithermal neutron beam for boron neutron capture therapy.

    Science.gov (United States)

    Sakamoto, S; Kiger, W S; Harling, O K

    1999-09-01

    Sensitivity studies of epithermal neutron beam performance in boron neutron capture therapy are presented for realistic neutron beams with varying filter/moderator and collimator/delimiter designs to examine the relative importance of neutron beam spectrum, directionality, and size. Figures of merit for in-air and in-phantom beam performance are calculated via the Monte Carlo technique for different well-optimized designs of a fission converter-based epithermal neutron beam with head phantoms as the irradiation target. It is shown that increasing J/phi, a measure of beam directionality, does not always lead to corresponding monotonic improvements in beam performance. Due to the relatively low significance, for most configurations, of its effect on in-phantom performance and the large intensity losses required to produce beams with very high J/phi, beam directionality should not be considered an important figure of merit in epithermal neutron beam design except in terms of its consequences on patient positioning and collateral dose. Hardening the epithermal beam spectrum, while maintaining the specific fast neutron dose well below the inherent hydrogen capture dose, improves beam penetration and advantage depth and, as a desirable by-product, significantly increases beam intensity. Beam figures of merit are shown to be strongly dependent on beam size relative to target size. Beam designs with J/phi approximately 0.65-0.7, specific fast neutron doses of 2-2.6x10(-13) Gy cm2/n and beam sizes equal to or larger than the size of the head target produced the deepest useful penetration, highest therapeutic ratios, and highest intensities.

  13. Properties evaluation of silorane, low-shrinkage, non-flowable and flowable resin-based composites in dentistry

    OpenAIRE

    Maia, Rodrigo R.; Reis, Rodrigo S.; Moro, André F.V.; Perez, Cesar R.; Bárbara M. Pessôa; Dias, Katia R.H.C.

    2015-01-01

    Purpose. This study tested the null hypothesis that different classes of direct restorative dental materials: silorane-based resin, low-shrinkage and conventional (non-flowable and flowable) resin-based composite (RBC) do not differ from each other with regard to polymerization shrinkage, depth of cure or microhardness. Methods. 140 RBC samples were fabricated and tested by one calibrated operator. Polymerization shrinkage was measured using a gas pycnometer both before and immediately after ...

  14. Lithium target for accelerator based BNCT neutron source: Influence by the proton irradiation on lithium

    Science.gov (United States)

    Fujii, R.; Imahori, Y.; Nakakmura, M.; Takada, M.; Kamada, S.; Hamano, T.; Hoshi, M.; Sato, H.; Itami, J.; Abe, Y.; Fuse, M.

    2012-12-01

    The neutron source for Boron Neutron Capture Therapy (BNCT) is in the transition stage from nuclear reactor to accelerator based neutron source. Generation of low energy neutron can be achieved by 7Li (p, n) 7Be reaction using accelerator based neutron source. Development of small-scale and safe neutron source is within reach. The melting point of lithium that is used for the target is low, and durability is questioned for an extended use at a high current proton beam. In order to test its durability, we have irradiated lithium with proton beam at the same level as the actual current density, and found no deterioration after 3 hours of continuous irradiation. As a result, it is suggested that lithium target can withstand proton irradiation at high current, confirming suitability as accelerator based neutron source for BNCT.

  15. Properties of unidirectional GFRPs based on an epoxy resin modified with polysulphone or an epoxyurethane oligomer

    Science.gov (United States)

    Solodilov, V. I.; Gorbatkina, Yu. A.

    2006-11-01

    The mechanical properties of unidirectional GFRPs based on an ED-22 epoxy resin were investigated. The resin was modified with a PSK-1 polysulphone or a PEF-3a epoxyurethane oligomer. Triethanolaminotitanate or diaminodiphenilsulphone was used as a hardener. The modification did not improve the mechanical properties of GFRPs in quasi-static loading; but in a low-speed impact loading, the shear strength of epoxypolysulphone GFRPs with 20 wt.% PSK-1 increased by 20-25%. For all the GFRPs investigated, the shear strength grew linearly with the logarithm of loading rate. The introduction of the modifiers increased the fracture toughness considerably: by 100 and 70% for GFRPs modified with 20 wt.% PSK-1 and 50 wt.% PEF-3a, respectively.

  16. A Statistics-Based Cracking Criterion of Resin-Bonded Silica Sand for Casting Process Simulation

    Science.gov (United States)

    Wang, Huimin; Lu, Yan; Ripplinger, Keith; Detwiler, Duane; Luo, Alan A.

    2017-02-01

    Cracking of sand molds/cores can result in many casting defects such as veining. A robust cracking criterion is needed in casting process simulation for predicting/controlling such defects. A cracking probability map, relating to fracture stress and effective volume, was proposed for resin-bonded silica sand based on Weibull statistics. Three-point bending test results of sand samples were used to generate the cracking map and set up a safety line for cracking criterion. Tensile test results confirmed the accuracy of the safety line for cracking prediction. A laboratory casting experiment was designed and carried out to predict cracking of a cup mold during aluminum casting. The stress-strain behavior and the effective volume of the cup molds were calculated using a finite element analysis code ProCAST®. Furthermore, an energy dispersive spectroscopy fractographic examination of the sand samples confirmed the binder cracking in resin-bonded silica sand.

  17. Genotoxicity and cytotoxicity of the epoxy resin-based root canal sealer AH plus.

    Science.gov (United States)

    Leyhausen, G; Heil, J; Reifferscheid, G; Waldmann, P; Geurtsen, W

    1999-02-01

    Previous studies with four rapid in vitro and in vivo test systems have shown that the epoxy resin-based root canal sealer AH26 may be genotoxic and cytotoxic (9). The purpose of this study was to determine the cytotoxic and genotoxic effects of the new resinous root canal sealer AH Plus by means of the growth inhibition test with primary human periodontal ligament fibroblasts and permanent 3T3 monolayers, the procaryotic umu test, the eucaryotic DNA synthesis inhibition test, and the in vivo alkaline filter elution test. In addition, Ames tests were performed with extracts from AH Plus. AH Plus caused only slight or no cellular injuries. Furthermore, no genotoxicity and mutagenicity were revealed by AH Plus. These data should be taken into consideration when deciding about a root canal sealer.

  18. Time-related surface modification of denture base acrylic resin treated by atmospheric pressure cold plasma.

    Science.gov (United States)

    Qian, Kun; Pan, Hong; Li, Yinglong; Wang, Guomin; Zhang, Jue; Pan, Jie

    2016-01-01

    The changes of denture base acrylic resin surface properties under cold plasma and the relationships with time were investigated. Cold plasma treated the specimens for 30 s, 60 s, 90 s, and 120 s, respectively. Water contact angles were measured immediately after the treatment, 48 h, 15 days and 30 days later. Surface roughness was measured with 3-D laser scanning microscope. Candida albicans adherence was evaluated by CFU counting. Chemical composition was monitored by X-ray photoelectron spectroscopy analysis. Water contact angle reduced after treated for 30 s. No changes were observed with time prolonged, except the durability. There were no differences in roughness among all groups. However, treatment groups showed significantly lower C. albicans adherence. XPS demonstrated a decrease in C/O, and this reduction was affected by treatment time. Cold plasma was an effective means of increasing hydrophilicity of acrylic resin and reducing C. albicans adherence without affecting physical properties.

  19. Water sorption of CH3- and CF3-Bis-GMA based resins with additives

    Directory of Open Access Journals (Sweden)

    Anuradha Prakki

    2012-08-01

    Full Text Available OBJECTIVES: To evaluate the effect of additives on the water sorption characteristics of Bis-GMA based copolymers and composites containing TEGDMA, CH3Bis-GMA or CF3Bis-GMA. MATERIAL AND METHODS: Fifteen experimental copolymers and corresponding composites were prepared combining Bis-GMA and TEGDMA, CH3Bis-GMA or CF3Bis-GMA, with aldehyde or diketone (24 and 32 mol% totaling 30 groups. For composites, barium aluminosilicate glass and pyrogenic silica was added to comonomer mixtures. Photopolymerization was effected by 0.2 wt% each of camphorquinone and N,N-dimethyl-p-toluidine. Specimen densities in dry and water saturated conditions were obtained by Archimedes' method. Water sorption and desorption were evaluated in a desorption-sorption-desorption cycle. Water uptake (%WU, water desorption (%WD, equilibrium solubility (ES; µg/mm³, swelling (f and volume increase (%V were calculated using appropriate equations. RESULTS: All resins with additives had increased %WU and ES. TEGDMA-containing systems presented higher %WU, %WD, ES, f and %V values, followed by resins based on CH3Bis-GMA and CF3Bis-GMA. CONCLUSIONS: Aldehyde and diketone led to increases in the water sorption characteristics of experimental resins.

  20. Dimensional changes of acrylic resin denture bases: conventional versus injection-molding technique.

    Directory of Open Access Journals (Sweden)

    Jafar Gharechahi

    2014-08-01

    Full Text Available Acrylic resin denture bases undergo dimensional changes during polymerization. Injection molding techniques are reported to reduce these changes and thereby improve physical properties of denture bases. The aim of this study was to compare dimensional changes of specimens processed by conventional and injection-molding techniques.SR-Ivocap Triplex Hot resin was used for conventional pressure-packed and SR-Ivocap High Impact was used for injection-molding techniques. After processing, all the specimens were stored in distilled water at room temperature until measured. For dimensional accuracy evaluation, measurements were recorded at 24-hour, 48-hour and 12-day intervals using a digital caliper with an accuracy of 0.01 mm. Statistical analysis was carried out by SPSS (SPSS Inc., Chicago, IL, USA using t-test and repeated-measures ANOVA. Statistical significance was defined at P<0.05.After each water storage period, the acrylic specimens produced by injection exhibited less dimensional changes compared to those produced by the conventional technique. Curing shrinkage was compensated by water sorption with an increase in water storage time decreasing dimensional changes.Within the limitations of this study, dimensional changes of acrylic resin specimens were influenced by the molding technique used and SR-Ivocap injection procedure exhibited higher dimensional accuracy compared to conventional molding.

  1. SORPTION AND SOLUBILITY OF LOW-SHRINKAGE RESIN-BASED DENTAL COMPOSITES

    Directory of Open Access Journals (Sweden)

    Sevda Yantcheva

    2016-04-01

    Full Text Available Background: Resin-based composites are well-established restorative materials. However, these materials may absorb significant amounts of water when exposed to aqueous environments. Sorption and solubility are affecting composite restorations by two different mechanisms; the first is the up taking of water producing an increased weight and the second is the dissolution of materials in water, leading to a weight reduction of the final conditioned samples. Objective: To measure the water sorption and solubility of different low-shrinkage resin-based composites. Six materials were selected: Filtek P60, Filtek Ultimate, SonicFill, Filtek Silorane, Kalore and Venus Diamond. Materials and methods: Five disc specimens were prepared of each material and polymerized with diode light-curing unit. Water sorption and solubility of the different materials were were calculated by means of weighting the samples before and after water immersion and desiccation. Data were statistically analyzed using Shapiro-Wilk One Way Analysis of Variance followed by the Holm-Sidak comparison test . Results: There were significant differences (p<=0.001 between materials regarding sorption and solubility. Regarding sorption F. Silorane showed lowest values, followed by SonicFill, without significant difference between them. Statistical significant differences exist between F. Silorane and F.P60, F. Ultimate, Kalore. Significant differences exist between SonicFill and F. Ultimate. F.Silorane (-0.018 and Kalore (-0.010 showed lowest values of solubility but there were marginal difference among all composites investigated. Conclusions: 1.The material with lowest values of sorption and solubility was F.Silorane. 2. The attained sorption and solubility values for composites are influenced by the differences in resin matrix composition and filler contend. 3. Modifications of dimethacrylate matrix did not minimize significantly sorption and solubility of composites. 4. Besides water

  2. Silorane- and high filled-based"low-shrinkage" resin composites: shrinkage, flexural strength and modulus

    Directory of Open Access Journals (Sweden)

    Cesar Augusto Galvão Arrais

    2013-04-01

    Full Text Available This study compared the volumetric shrinkage (VS, flexural strength (FS and flexural modulus (FM properties of the low-shrinkage resin composite Aelite LS (Bisco to those of Filtek LS (3M ESPE and two regular dimethacrylate-based resin composites, the microfilled Heliomolar (Ivoclar Vivadent and the microhybrid Aelite Universal (Bisco. The composites (n = 5 were placed on the Teflon pedestal of a video-imaging device, and VS was recorded every minute for 5 min after 40 s of light exposure. For the FS and FM tests, resin discs (0.6 mm in thickness and 6.0 mm in diameter were obtained (n = 12 and submitted to a piston-ring biaxial test in a universal testing machine. VS, FS, and FM data were submitted to two-way repeated measures and one-way ANOVA, respectively, followed by Tukey's post-hoc test (a = 5%. Filtek LS showed lower VS than did Aelite LS, which in turn showed lower shrinkage than did the other composites. Aelite Universal and Filtek LS exhibited higher FS than did Heliomolar and Aelite LS, both of which exhibited the highest FM. No significant difference in FM was noted between Filtek LS and Aelite Universal, while Heliomolar exhibited the lowest values. Aelite LS was not as effective as Filtek LS regarding shrinkage, although both low-shrinkage composites showed lower VS than did the other composites. Only Filtek LS exhibited FS and FM comparable to those of the regular microhybrid dimethacrylate-based resin composite.

  3. Effect of Energy Drinks on Discoloration of Silorane- and Dimethacrylate-Based Composite Resins

    Directory of Open Access Journals (Sweden)

    Ghazaleh Ahmadizenouz

    2016-11-01

    Full Text Available Objectives: This study aimed to assess the effects of two energy drinks on color change (∆E of two methacrylate-based and a silorane-based composite resin after one week and one month.Materials and Methods: Thirty cubic samples were fabricated from Filtek P90, Filtek Z250 and Filtek Z350XT composite resins. All the specimens were stored in distilled water at 37°C for 24 hours. Baseline color values (L*a*b* of each specimen were measured using a spectrophotometer according to the CIEL*a*b* color system. Ten randomly selected specimens from each composite were then immersed in the two energy drinks (Hype, Red Bull and artificial saliva (control for one week and one month. Color was re-assessed after each storage period and ∆E values were calculated. The data were analyzed using the Kruskal Wallis and Mann–Whitney U tests.Results: Filtek Z250 composite showed the highest ∆E irrespective of the solutions at both time points. After seven days and one month, the lowest ∆E values were observed in Filtek Z350XT and Filtek P90 composites immersed in artificial saliva, respectively. The ∆E values of Filtek Z250 and Z350XT composites induced by Red Bull and Hype energy drinks were not significantly different. Discoloration of Filtek P90 was higher in Red Bull energy drink at both time points.Conclusions: Prolonged immersion time in all three solutions increased ∆E values of all composites. However, the ∆E values were within the clinically acceptable range (<3.3 at both time points.Keywords: Color; Composite Resins; Energy Drinks; Silorane Composite Resin; Spectrophotometry

  4. Sensitivity of catalyst/base ratio on curing of resin luting agents: polymerization exotherm analysis.

    Science.gov (United States)

    Griggs, J A; Shen, C; Anusavice, K J

    1994-09-01

    Currently, the proposed test of the International Standardization Organization (ISO) for measuring working and setting times of resin luting agents is based on measurement of times to reach specified stages on the polymerization exotherm. The objective of this study was to use this test to investigate the influence of variations in the mass ratios of catalyst paste to base paste on the working and setting times of three dual-cured dental resin luting agents. The materials used were Dicor Light Activated Cement (Dentsply International Inc.), Palfique Inlay Resin Cement (Tokuyama Soda Co.), and Vivadent Dual Cement (Vivadent). Fifteen specimens of each material were tested for working time by spatulating mass ratios from 0.7 to 1.3 for 30s at 23 degrees C and recording the time from beginning of spatulation to the time at which a temperature increase occurs. Ten specimens of each material were tested for setting time by spatulating in a similar manner at 37 degrees C and recording the time at which the temperature reaches a maximum value. The data were fitted to the relation, In t = In A + Bm, where t is the time in seconds, m is the mass ratio, and A and B are regression coefficients. The results suggest that working and setting times of the specimens were independent of variations in mass ratio. A comparison among the materials was made by using a multiple linear regression with the relation, In t = In C + Dm + E gamma + Fm gamma, where gamma is a dummy variable to help distinguish between materials, and C, D, E, and F are regression coefficients. The results suggest that differences in materials influence the working time but not the setting time. These results infer that variations in mass ratio (+/- 20%) often observed in the clinical setting should not have a significant influence on the working and setting times of resin luting agents.

  5. L(+-Lactic acid recovery from cassava bagasse based fermented medium using anion exchange resins

    Directory of Open Access Journals (Sweden)

    Rojan P. John

    2008-12-01

    Full Text Available The properties of the ion exchange resins, Amberlite IRA 402, a strong anion exchange resin and IRA 67, a weak anion exchange resin were determined to evaluate their comparative suitability for lactic acid recovery from fermented cassava bagasse. Data on binding capacities and recovery proved that weak base resin in chloride form was the most favourable ones for lactic acid recovery from aqueous solutions and fermentation media. Fermented media obtained through simultaneous saccharification and fermentation of cassava bagasse starch hydrolysate based medium were used for lactic acid recovery study using weak base resin column. Amberlite IRA 67 had much more efficiency than Amberlite IRA 402 to recover lactic acid. Like in other reports, due to the presence of nutrients and ions other than lactate, the binding capacity was slightly lesser while using fermented media (~93% instead of aqueous lactic acid solutions (~98%.As propriedades das resinas de troca iônica, da Amberlite IRA 402, uma resina de troca aniônica forte, e da IRA 67, uma resina de troca aniônica fraca, foram determinadas para se avaliar a adequabilidade comparativa delas à obtenção de ácido lático de bagaço de mandioca fermentado. Dados sobre a capacidade de ligação e sobre a obtenção provaram que a resina de base fraca na forma de cloreto era a mais adequada para a obtenção de ácido lático em soluções aquosas e meios de fermentação. Os meios de fermentação obtidos da sacarificação e da fermentação simultâneas de meios baseados hidrolisados de fécula de bagaço de mandioca foram usados para o estudo da obtenção de ácido lático usando uma coluna de resina de base fraca. A Amberlite IRA 67 mostrou-se muito mais eficaz do que a Amberlite IRA 402 para a obtenção de ácido lático. Como em outros relatórios, devido à presença de nutrientes e íons que não lactatos, a capacidade de ligação foi ligeiramente inferior enquanto se utilizavam meios

  6. Analytical methods for the measurement of polymerization kinetics and stresses of dental resin-based composites: A review

    Science.gov (United States)

    Ghavami-Lahiji, Mehrsima; Hooshmand, Tabassom

    2017-01-01

    Resin-based composites are commonly used restorative materials in dentistry. Such tooth-colored restorations can adhere to the dental tissues. One drawback is that the polymerization shrinkage and induced stresses during the curing procedure is an inherent property of resin composite materials that might impair their performance. This review focuses on the significant developments of laboratory tools in the measurement of polymerization shrinkage and stresses of dental resin-based materials during polymerization. An electronic search of publications from January 1977 to July 2016 was made using ScienceDirect, PubMed, Medline, and Google Scholar databases. The search included only English-language articles. Only studies that performed laboratory methods to evaluate the amount of the polymerization shrinkage and/or stresses of dental resin-based materials during polymerization were selected. The results indicated that various techniques have been introduced with different mechanical/physical bases. Besides, there are factors that may contribute the differences between the various methods in measuring the amount of shrinkages and stresses of resin composites. The search for an ideal and standard apparatus for measuring shrinkage stress and volumetric polymerization shrinkage of resin-based materials in dentistry is still required. Researchers and clinicians must be aware of differences between analytical methods to make proper interpretation and indications of each technique relevant to a clinical situation. PMID:28928776

  7. EFFECT OF FLUORIDE-CONTAINING DESENSITIZING AGENTS ON THE BOND STRENGTH OF RESIN-BASED CEMENTS TO DENTIN

    Science.gov (United States)

    Saraç, Duygu; Külünk, Safak; Saraç, Y. Sinasi; Karakas, Özlem

    2009-01-01

    Objective: The objective of this study was to evaluate the effect of desensitizing agents containing different amounts of fluoride on the shear bond strength of a dual polymerized resin cement and a resin-modified glass ionomer cement (RMGIC) to dentin. Material and Methods: One hundred human molars were mounted in acrylic resin blocks and prepared until the dentin surface was exposed. The specimens were treated with one of four desensitizing agents: Bifluorid 12, Fluoridin, Thermoline and PrepEze. The remaining 20 specimens served as untreated controls. All groups were further divided into 2 subgroups in which a dual polymerized resin cement (Bifix QM) or a resin-modified glass ionomer cement (AVANTO) was used. The shear bond strength (MPa) was measured using a universal testing machine at a 0.5 mm/min crosshead speed. The data were analyzed statistically with a 2-way ANOVA, Tukey HSD test and regression analysis (α=0.05). The effect of the desensitizing agents on the dentin surface was examined by scanning electron microscopy. Results: The fluoride-containing desensitizing agents affected the bond strength of the resin-based cements to dentin (p<0.001). PrepEze showed the highest bond strength values in all groups (p<0.001). Conclusion: Regression analysis showed a reverse relation between bond strength values of resin cements to dentin and the amount of fluoride in the desensitizing agent (p<0.05). PMID:19936532

  8. Effect of resin infiltration on the thermal and mechanical properties of nano-sized silica-based thermal insulation.

    Science.gov (United States)

    Lee, Jae Chun; Kim, Yun-Il; Lee, Dong-Hun; Kim, Won-Jun; Park, Sung; Lee, Dong Bok

    2011-08-01

    Several kinds of nano-sized silica-based thermal insulation were prepared by dry processing of mixtures consisting of fumed silica, ceramic fiber, and a SiC opacifier. Infiltration of phenolic resin solution into the insulation, followed by hot-pressing, was attempted to improve the mechanical strength of the insulation. More than 22% resin content was necessary to increase the strength of the insulation by a factor of two or more. The structural integrity of the resin-infiltrated samples could be maintained, even after resin burn-out, presumably due to reinforcement from ceramic fibers. For all temperature ranges and similar sample bulk density values, the thermal conductivities of the samples after resin burn-out were consistently higher than those of the samples obtained from the dry process. Mercury intrusion curves indicated that the median size of the nanopores formed by primary silica aggregates in the samples after resin burn-out is consistently larger than that of the sample without resin infiltration.

  9. Effect of surface treatments on shear bond strength of denture teeth to denture base resins

    Directory of Open Access Journals (Sweden)

    Farideh Bahrani

    2014-01-01

    Full Text Available Background: Debonding of denture teeth from denture bases is the most common failure in removable dentures. The purpose of this study was to evaluate the effect of surface treatments on shear bond strength of denture teeth to heat-polymerized and autopolymerized denture base resins. Materials and Methods: In this experimental in vitro study, 60 maxillary central incisor acrylic teeth were divided into two groups. Group M was polymerized with heat-polymerized acrylic resin (Meliodent by compression molding technique and group F was processed by autopolymerized acrylic resin (Futura Gen by injection molding technique. Within each group, specimens were divided into three subgroups according to the teeth surface treatments (n = 10: (1 ground surface as the control group (M 1 and F 1 , (2 ground surface combined with monomer application (M 2 and F 2 , and (3 airborne particle abrasion by 50 μm Al 2 O 3 (M 3 and F 3 . The shear bond strengths of the specimens were tested by universal testing machine with crosshead speed of 5 mm/min. Data were analyzed by two-way analysis of variance (ANOVA and Tukey′s honestly significant difference (HSD tests (P < 0.05. Results: The mean shear bond strengths of the studied groups were 96.40 ± 14.01, 124.70 ± 15.64, and 118 ± 16.38 N for M 1 , M 2 , and M 3 and 87.90 ± 13.48, 117 ± 13.88, and 109.70 ± 13.78 N for F 1 , F 2 , and F 3 , respectively. The surface treatment of the denture teeth significantly affected their shear bond strengths to the both the denture base resins (P < 0.001. However, there were no significant differences between the groups treated by monomer or airborne particle abrasion (P = 0.29. The highest percentage of failure mode was mixed in Meliodent and adhesive in Futura Gen. Conclusion: Monomer application and airborne particle abrasion of the ridge lap area of the denture teeth improved their shear bond strengths to the denture base resins regardless of the type of polymerization.

  10. Effect of base monomer's refractive index on curing depth and polymerization conversion of photo-cured resin composites.

    Science.gov (United States)

    Fujita, Kou; Nishiyama, Norihiro; Nemoto, Kimiya; Okada, Tamami; Ikemi, Takuji

    2005-09-01

    In this study, we examined the effect of the transmitted amount of visible light through a resin composite on the curing depth and polymerization conversion. Transmitted amount of visible light was strongly dependent on the magnitude of refractive index difference that existed between the resin and silica filler. More specifically, the differences arose from the type of base monomer used. The transmitted amount of visible light exhibited a good correlation with the curing depth and Knoop hardness ratio of the bottom surface against the top surface of the resin composite. To improve the polymerization conversion of the cavity floor, it is important to reduce the refractive index difference that exists between the base resin and silica filler.

  11. Synthesis, properties and applications of interacting blends of acrylated novalac epoxy resin based poly(ester-amides and vinyl ester

    Directory of Open Access Journals (Sweden)

    Pragnesh N. Dave

    2016-09-01

    Full Text Available Epoxy resin based unsaturated poly(ester-amide resins (UPEAs were prepared by the reported method. These UPEAs were then treated with acryloyl chloride to afford acrylated UPEAs resin (i.e. AUPEAs. Interacting blends of equal proportional AUPEAs and vinyl ester epoxy (VE resin were prepared. APEAs and AUPEAs were characterized by elemental analysis, molecular weight determined by vapor pressure osmometer and by IR spectral study and by thermogravimetry. The curing of interacting blends was monitored on differential scanning calorimeter (DSC. Based on DSC data in situ glass reinforced composites of the resultant blends have been prepared and characterized for mechanical, electrical and chemical properties. Unreinforced blends were characterized by thermogravimetry (TGA.

  12. Selective concentration of aromatic bases from water with a resin adsorbent

    Science.gov (United States)

    Stuber, H.A.; Leenheer, J.A.

    1983-01-01

    Aromatic bases are concentrated from water on columns of a resin adsorbent and recovered by aqueous-acid elution. The degree of concentration attainable depends on the ratio of the capacity factor (k) of the neutral form of the amine to that of the ionized form. Capacity factors of ionic forms of amines on XAD-8 resin (a methylacrylic ester polymer) are greater than zero, ranging from 20 to 250 times lower than those of their neutral forms; they increase with increasing hydrophobicity of the amine. Thus, desorption by acid is an edition (k during desorption >0) rather than a displacement (k during desorption = 0) process. The degree of concentration attainable on XAD-8 resin varies with the hydrophobicity of the amine, being limited for hydrophilic solutes (for example, pyridine) by small neutral-form k's, reaching a maximum for amines of intermediate hydrophobicity (for example, quinoline), and decreasing for more hydrophobc solutes (for example, acridine) because of their large ionic-form k's.

  13. Pilot scale production, characterization, and optimization of epoxidized vegetable oil-based resins

    Science.gov (United States)

    Monono, Ewumbua Menyoli

    Novel epoxidized sucrose soyate (ESS) resins perform much better than other vegetable oil-based resins; thus, they are of current interest for commercial scale production and for a wide range of applications in coatings and polymeric materials. However, no work has been published that successfully scaled-up the reaction above a 1 kg batch size. To achieve this goal, canola oil was first epoxidized at a 300 g scale to study the epoxidation rate and thermal profile at different hydrogen peroxide (H2O2) addition rates, bath temperatures, and reaction times. At least 83% conversion of double bonds to oxirane was achieved by 2.5 h, and the reaction temperature was 8-15 °C higher than the water bath temperature within the first 30-40 min of epoxidation. A 38 L stainless steel kettle was modified as a reactor to produce 10 kg of ESS. Twenty 7-10 kg batches of ESS were produced with an overall 87.5% resin yield and > 98% conversion after batch three. The conversion and resin quality were consistent across the batches due to the modifications on the reaction that improved mixing and reaction temperature control within 55-65 oC. The total production time was reduced from 8 to 4 days due to the fabrication of a 40 L separatory funnel for both washing and filtration. A math model was developed to optimize the epoxidation process. This was done by using the Box-Behnken design to model the conversion at various acetic acid, H2O2, and Amberlite ratios and at various reaction temperatures and times. The model had an adjusted R2 of 97.6% and predicted R2 of 96.8%. The model showed that reagent amounts and time can be reduced by 18% without compromising the desired conversion value and quality.

  14. Highly active, recyclable catalyst for the manufacture of viscous, low molecular weight, CO–ethene–propene-based polyketone, base component for a new class of resins

    NARCIS (Netherlands)

    Broekhuis, Antonius A.; Dirkzwager, Hendrik; Mul, Wilhelmus P.; Heeres, Hero J.; Linden, Adrianus J. van der; Orpen, A. Guy

    2002-01-01

    A highly active, recyclable homogeneous palladium(II) catalyst is described for the manufacture of viscous, low molecular weight CO–ethene–propene-based polyketone (Carilite Oligomer), used for the manufacture of a new class of resins (Carilite Resins). The catalyst is composed of palladium acetate,

  15. Fusion Based Neutron Sources for Security Applications: Energy Optimisation

    OpenAIRE

    Albright, S.; Seviour, Rebecca

    2014-01-01

    There is a growing interest in the use of neutrons for na- tional security. The majority of work on security focuses on the use of either sealed tube DT fusors or fission sources, e.g. Cf-252. Fusion reactions enable the energy of the neu- tron beam to be chosen to suit the application, rather than the application being chosen based on the available neu- tron beam energy. In this paper we discuss simulations of fusion reactions demonstrating the broad range of energies available and methods f...

  16. Novel bio-based thermoset resins based on epoxidized vegetable oils for structural adhesives

    Science.gov (United States)

    Sivasubramanian, Shivshankar

    Conventional engineered wood composites are bonded for the most part through formaldehyde-based structural adhesives such as urea formaldehyde (UF), melamine formaldehyde (MF), phenol formaldehyde (PF) and resorcinol formaldehyde (RF). Formaldehyde is a known human carcinogen; the occupational exposure and emission after manufacturing of these binders is raising more and more concern. With increasing emphasis on environmental issues, there is clear incentive to replace these hazardous conventional formaldehyde-based binders with cco-friendly resins having similar properties but derived from renewable sources, bearing in mind the economics of the structural wood composite industry. In this thesis, the curing reaction of bio-derived epoxy thermosets with inexpensive, low-toxicity precursors, including polyimines and amino acids was investigated. Epoxidized linseed oil (ELO) and epoxidized soybean oil (ESO) were successfully crosslinked with both branched polyethyleneimine (PEI) and triethylenetetramine (fETA). Epoxidized castor oil (ECO) was crosslinked with polyethyleneimine (PEI), having different molecular weights. Curing conditions were optimized through solvent uptake and soluble fraction analysis. Finally, the mechanical properties of the optimized compositions of rigid bioepoxies were evaluated using dynamic mechanical rheological testing (DMRT). While not as stiff as conventional materials, optimized materials have sufficient room temperature moduli to show promise for coatings and as binders in engineered wood products.

  17. The Use of Commercial Non-Hazardous Air Pollutant Monomers to Optimize the Properties of Fatty Acid-Based Resins

    Science.gov (United States)

    2009-05-01

    Reviewing all of the data, it was found that the di-functional monomers produced resins with lower viscosities, higher modulus, and higher Tg than the...to storage modulus Tg Glass transition temperature of polymer TGA Thermogravimetric analysis UPE Unsaturated polyester VE Vinyl ester...The Use of Commercial Non-Hazardous Air Pollutant Monomers to Optimize the Properties of Fatty Acid-Based Resins by John J. La Scala, Priya

  18. The effect of repeated preheating of dimethacrylate and silorane-based composite resins on marginal gap of class V restorations

    Directory of Open Access Journals (Sweden)

    Parnian Alizadeh Oskoee

    2017-03-01

    Full Text Available Background. One of the problems with composite resin restorations is gap formation at resin‒tooth interface. The present study evaluated the effect of preheating cycles of silorane- and dimethacrylate-based composite resins on gap formation at the gingival margins of Class V restorations. Methods. In this in vitro study, standard Class V cavities were prepared on the buccal surfaces of 48 bovine incisors. For restorative procedure, the samples were randomly divided into 2 groups based on the type of composite resin (group 1: di-methacrylate composite [Filtek Z250]; group 2: silorane composite [Filtek P90] and each group was randomly divided into 2 subgroups based on the composite temperature (A: room temperature; B: after 40 preheating cycles up to 55°C. Marginal gaps were measured using a stereomicroscope at ×40 and analyzed with two-way ANOVA. Inter- and intra-group comparisons were analyzed with post-hoc Tukey tests. Significance level was defined at P < 0.05. Results. The maximum and minimum gaps were detected in groups 1-A and 2-B, respectively. The effects of composite resin type, preheating and interactive effect of these variables on gap formation were significant (P<0.001. Post-hoc Tukey tests showed greater gap in dimethacrylate compared to silorane composite resins (P< 0.001. In each group, gap values were greater in composite resins at room temperature compared to composite resins after 40 preheating cycles (P<0.001. Conclusion. Gap formation at the gingival margins of Class V cavities decreased due to preheating of both composite re-sins. Preheating of silorane-based composites can result in the best marginal adaptation.

  19. A dosimetry study of deuterium-deuterium neutron generator-based in vivo neutron activation analysis

    Science.gov (United States)

    Sowers, Daniel A.

    A neutron irradiation cavity for in vivo Neutron Activation Analysis (IVNAA) to detect manganese, aluminum, and other potentially toxic elements in human hand bone has been designed and its dosimetric specifications measured. The neutron source is a customized deuterium-deuterium neutron generator which produces neutrons at 2.45 MeV by the fusion reaction 2H(d, n)3He at a calculated flux of 7 x 108 +/-30% s-1. A moderator/reflector/shielding (5 cm high density polyethylene (HDPE), 5.3 cm graphite & 5.7 cm borated HDPE) assembly has been designed and built to maximize the thermal neutron flux inside the hand irradiation cavity and to reduce the extremity dose and effective dose to the human subject. Lead sheets are used to attenuate bremsstrahlung x rays and activation gammas. A Monte Carlo simulation (MCNP6) was used to model the system and calculate extremity dose. The extremity dose was measured with neutron and photon sensitive film badges and Fuji electronic pocket dosimeter (EPD). The neutron ambient dose outside the shielding was measured by Fuji NSN3, and photon dose by a Bicron MicroREM scintillator. Neutron extremity dose was calculated to be 32.3 mSv using MCNP6 simulations given a 10 min IVNAA measurement of manganese. Measurements by EPD and film badge indicate hand dose to be 31.7 +/- 0.8 mSv for neutron and 4.2 +/- 0.2 mSv for photon for 10 mins; whole body effective dose was calculated conservatively to be 0.052 mSv. Experimental values closely match values obtained from MCNP6 simulations. These are acceptable doses to apply the technology for a manganese toxicity study in a human population.

  20. Neutron irradiation tests on B4C/epoxy composite for neutron shielding application and the parameters assay

    Science.gov (United States)

    Adeli, Ruhollah; Shirmardi, Seyed Pezhman; Ahmadi, Seyed Javad

    2016-10-01

    In this investigation, epoxy resin with a low viscosity amine-based curing agent was chosen as matrix and additives were added to epoxy resin using low speed stirring with ultrasonic waves approach. The chemical stability of resin during fabrication of composites was studied with Fourier transform infrared spectroscopy (FTIR). The effect of B4C particle size (20 and 150 μm) on neutron shielding was investigated. Besides, in order to develop the high performance composites, the effect of ATH (flame retardant) and WO3 powders (for shielding from against gamma rays) on neutron shielding property is considered. The neutron experiments were based on foil activation analysis in thermal column of Tehran Research Reactor (TRR). According to experimental data, required shield thickness (B4C, 150 μm, 3 wt%) for 80% absorption of neutron fluence was calculated about 9.8 mm. Consequently, data show thermal neutron absorption is dependent also on the size of the boron compound filler and show a significant enhancement in shielding performance when using smaller particle size of B4C filler. Furthermore, data obviously show that the neutron attenuation coefficient of reinforced composites increases to 0.345 cm-1 for B4C (20 μm, 5 wt%)/ Epoxy composite shield. As clearly data indicate, adding WO3 and ATH additive had a significant influence on the thermal neutron attenuation property and hybrid shield shows an enhancement of more than 60% in shielding performance.

  1. Protein-based green resins and nanocomposites from waste residues

    Science.gov (United States)

    Rahman, Muhammad Maksudur

    The main goal of the present research is to design and fabricate 'green' nanocomposites using eco-friendly and biodegradable polymers, an effort driven towards an alternative of conventional petroleum-derived polymers in structural applications considering environmental and economic concerns. The behavior of structure, composition and property relationships between the novel combinations of these materials has been analyzed and discussed. The materials used in this study, many of them from non-edible sources, are obtained, derived and/or synthesized using various wastes from agricultural and food industries, as much as possible, so as to utilize wastes that are discarded at present. At the same time, the use of waste sources reduces the dependency of edible source-based biopolymers in various structural applications and thus, reduces the cost of materials significantly. Overall, this study opens up new avenues in the fabrication of low-cost 'green' nanocomposite with facile and 'green' methodology using various agricultural and food wastes.

  2. Separation of thorium and uranium in nitric acid solution using silica based anion exchange resin.

    Science.gov (United States)

    Chen, Yanliang; Wei, Yuezhou; He, Linfeng; Tang, Fangdong

    2016-09-30

    To separate thorium and uranium in nitric acid solution using anion exchange process, a strong base silica-based anion exchange resin (SiPyR-N4) was synthesized. Batch experiments were conducted and the separation factor of thorium and uranium in 9M nitric acid was about 10. Ion exchange chromatography was applied to separate thorium and uranium in different ratios. Uranium could be eluted by 9M nitric acid and thorium was eluted by 0.1M nitric acid. It was proved that thorium and uranium can be separated and recovered successfully by this method.

  3. Selective separation of mercury(II) using magnetic chitosan resin modified with Schiff's base derived from thiourea and glutaraldehyde.

    Science.gov (United States)

    Donia, Ahmed M; Atia, Asem A; Elwakeel, Khalid Z

    2008-03-01

    Magnetic chitosan resin was chemically modified by a Schiff's base cross-linker. The interaction of the resin obtained with Hg(II) was studied and uptake value of 2.8 mmol/g was reported. The kinetic and thermodynamic parameters of the adsorption process were estimated. These data indicated that the adsorption process is exothermic and follow the pseudo-second-order kinetics. The selectivity of Hg(II) from other different metal ions in solutions using the studied resin was also reported. Breakthrough curves for the recovery of Hg(II) were studied. The critical bed height was found to be 2.05 cm. The adsorbed Hg(II) was eluted from the resin effectively using 0.1 M potassium iodide.

  4. Development of a Fresnel lens for cold neutrons based on neutron refractive optics

    CERN Document Server

    Oku, T; Moriyasu, S; Yamagata, Y; Ohmori, H; Takizawa, Y; Shimizu, H M; Hirota, T; Kiyanagi, Y; Ino, T; Furusaka, M; Suzuki, J

    2001-01-01

    We have developed compound refractive lenses (CRLs) for cold neutrons, which are made of vitreous silica and have an effective potential of (90.1-2.7x10 sup - sup 4 i) neV. In the case of compound refractive optics, neutron absorption by the material deteriorates lens performance. Thus, to prevent an increase in neutron absorption with increasing beam size, we have developed Fresnel lenses using the electrolytic in-process dressing grinding technique. The lens characteristics were carefully investigated with experimental and numerical simulation studies. The lenses functioned as a neutron focusing lens, and the focal length of 14 m was obtained with a 44-element series of the Fresnel lenses for 10 A neutrons. Moreover, good neutron transmission of 0.65 for 15 A neutrons was obtained due to the shape effect. According to comprehensive analysis of the obtained results, it is possible to realize a CRL for practical use by choosing a suitable lens shape and material.

  5. Effect of surface treatment methods on the shear bond strength of auto-polymerized resin to thermoplastic denture base polymer.

    Science.gov (United States)

    Koodaryan, Roodabeh; Hafezeqoran, Ali

    2016-12-01

    Polyamide polymers do not provide sufficient bond strength to auto-polymerized resins for repairing fractured denture or replacing dislodged denture teeth. Limited treatment methods have been developed to improve the bond strength between auto-polymerized reline resins and polyamide denture base materials. The objective of the present study was to evaluate the effect of surface modification by acetic acid on surface characteristics and bond strength of reline resin to polyamide denture base. 84 polyamide specimens were divided into three surface treatment groups (n=28): control (N), silica-coated (S), and acid-treated (A). Two different auto-polymerized reline resins GC and Triplex resins were bonded to the samples (subgroups T and G, respectively, n=14). The specimens were subjected to shear bond strength test after they were stored in distilled water for 1 week and thermo-cycled for 5000 cycles. Data were analyzed with independent t-test, two-way analysis of variance (ANOVA), and Tukey's post hoc multiple comparison test (α=.05). The bond strength values of A and S were significantly higher than those of N (Pauto-polymerized reline resin.

  6. Effect of Antimicrobial Denture Base Resin on Multi-Species Biofilm Formation.

    Science.gov (United States)

    Zhang, Keke; Ren, Biao; Zhou, Xuedong; Xu, Hockin H K; Chen, Yu; Han, Qi; Li, Bolei; Weir, Michael D; Li, Mingyun; Feng, Mingye; Cheng, Lei

    2016-06-29

    Our aims of the research were to study the antimicrobial effect of dimethylaminododecyl methacrylate (DMADDM) modified denture base resin on multi-species biofilms and the biocompatibility of this modified dental material. Candida albicans (C. albicans), Streptococcus mutans (S. mutans), Streptococcus sanguinis (S. sanguinis), as well as Actinomyces naeslundii (A. naeslundii) were used for biofilm formation on denture base resin. Colony forming unit (CFU) counts, microbial viability staining, and 2,3-bis(2-methoxy-4-nitro-5-sulfophenyl)-2H-tetrazolium-5-carboxanilide (XTT) array were used to evaluate the antimicrobial effect of DMADDM. C. albicans staining and Real-time PCR were used to analyze the morphology and expression of virulence genes of C. albicans in biofilm. Lactate dehydrogenase (LDH) array and Real-time PCR were conducted to examine the results after biofilm co-cultured with epithelial cell. Hematoxylin and eosin (HE) staining followed by histological evaluation were used to study the biocompatibility of this modified material. We found that DMADDM containing groups reduced both biomass and metabolic activity of the biofilm significantly. DMADDM can also inhibit the virulence of C. albicans by means of inhibiting the hyphal development and downregulation of two virulence related genes. DMADDM significantly reduced the cell damage caused by multi-species biofilm according to the LDH activity and reduced the expression of IL-18 gene of the cells simultaneously. The in vivo histological evaluation proved that the addition of DMADDM less than 6.6% in denture material did not increase the inflammatory response (p > 0.05). Therefore, we proposed that the novel denture base resin containing DMADDM may be considered as a new promising therapeutic system against problems caused by microbes on denture base such as denture stomatitis.

  7. Effect of Antimicrobial Denture Base Resin on Multi-Species Biofilm Formation

    Directory of Open Access Journals (Sweden)

    Keke Zhang

    2016-06-01

    Full Text Available Our aims of the research were to study the antimicrobial effect of dimethylaminododecyl methacrylate (DMADDM modified denture base resin on multi-species biofilms and the biocompatibility of this modified dental material. Candida albicans (C. albicans, Streptococcus mutans (S. mutans, Streptococcus sanguinis (S. sanguinis, as well as Actinomyces naeslundii (A. naeslundii were used for biofilm formation on denture base resin. Colony forming unit (CFU counts, microbial viability staining, and 2,3-bis(2-methoxy-4-nitro-5-sulfophenyl-2H-tetrazolium-5-carboxanilide (XTT array were used to evaluate the antimicrobial effect of DMADDM. C. albicans staining and Real-time PCR were used to analyze the morphology and expression of virulence genes of C. albicans in biofilm. Lactate dehydrogenase (LDH array and Real-time PCR were conducted to examine the results after biofilm co-cultured with epithelial cell. Hematoxylin and eosin (HE staining followed by histological evaluation were used to study the biocompatibility of this modified material. We found that DMADDM containing groups reduced both biomass and metabolic activity of the biofilm significantly. DMADDM can also inhibit the virulence of C. albicans by means of inhibiting the hyphal development and downregulation of two virulence related genes. DMADDM significantly reduced the cell damage caused by multi-species biofilm according to the LDH activity and reduced the expression of IL-18 gene of the cells simultaneously. The in vivo histological evaluation proved that the addition of DMADDM less than 6.6% in denture material did not increase the inflammatory response (p > 0.05. Therefore, we proposed that the novel denture base resin containing DMADDM may be considered as a new promising therapeutic system against problems caused by microbes on denture base such as denture stomatitis.

  8. Characterisation of an accelerator-based neutron source for BNCT versus beam energy

    Science.gov (United States)

    Agosteo, S.; Curzio, G.; d'Errico, F.; Nath, R.; Tinti, R.

    2002-01-01

    Neutron capture in 10B produces energetic alpha particles that have a high linear energy transfer in tissue. This results in higher cell killing and a higher relative biological effectiveness compared to photons. Using suitably designed boron compounds which preferentially localize in cancerous cells instead of healthy tissues, boron neutron capture therapy (BNCT) has the potential of providing a higher tumor cure rate within minimal toxicity to normal tissues. This clinical approach requires a thermal neutron source, generally a nuclear reactor, with a fluence rate sufficient to deliver tumorcidal doses within a reasonable treatment time (minutes). Thermal neutrons do not penetrate deeply in tissue, therefore BNCT is limited to lesions which are either superficial or otherwise accessible. In this work, we investigate the feasibility of an accelerator-based thermal neutron source for the BNCT of skin melanomas. The source was designed via MCNP Monte Carlo simulations of the thermalization of a fast neutron beam, generated by 7 MeV deuterons impinging on a thick target of beryllium. The neutron field was characterized at several deuteron energies (3.0-6.5 MeV) in an experimental structure installed at the Van De Graaff accelerator of the Laboratori Nazionali di Legnaro, in Italy. Thermal and epithermal neutron fluences were measured with activation techniques and fast neutron spectra were determined with superheated drop detectors (SDD). These neutron spectrometry and dosimetry studies indicated that the fast neutron dose is unacceptably high in the current design. Modifications to the current design to overcome this problem are presented.

  9. Three new nondestructive evaluation tools based on high flux neutron sources

    Energy Technology Data Exchange (ETDEWEB)

    Hubbard, C.R.; Raine, D.; Peascoe, R.; Wright, M. [and others

    1997-03-01

    Nondestructive evaluation methods and systems based on specific attributes of neutron interactions with materials are being developed. The special attributes of neutrons are low attenuation in most engineering materials, strong interaction with low Z elements, and epithermal neutron absorption resonances. The three methods under development at ORNL include neutron based tomography and radiography; through thickness, nondestructive texture mapping; and internal, noninvasive temperature measurement. All three techniques require high flux sources such as the High Flux Isotope Reactor, a steady state source, or the Oak Ridge Electron Linear Accelerator, a pulsed neutron source. Neutrons are quite penetrating in most engineering materials and thus can be useful to detect internal flaws and features. Hydrogen atoms, such as in a hydrocarbon fuel, lubricant, or a metal hydride, are relatively opaque to neutron transmission and thus neutron based tomography/radiography is ideal to image their presence. Texture, the nonrandom orientation of crystalline grains within materials, can be mapped nondestructively using neutron diffraction methods. Epithermal neutron resonance absorption is being studied as a noncontacting temperature sensor. This paper highlights the underlying physics of the methods, progress in development, and the potential benefits for science and industry of the three facilities.

  10. Irradiation facility for boron neutron capture therapy application based on a rf-driven D-T neutron source and a new beam shaping assembly (abstract)

    Science.gov (United States)

    Cerullo, N.; Esposito, J.; Leung, K. N.

    2002-02-01

    Selecting the best neutron source for boron neutron capture therapy (BNCT) requires optimizing neutron beam parameters. This involves solving many complex problems. Safety issues related to the use of nuclear reactor in hospital environments, as well as lower costs have led to interest in the development of accelerator-driven neutron sources. The BNCT research programs at the Nuclear Departments of Pisa and Genova Universities (DIMNP and DITEC) focus on studies of new concepts for accelerator-based DT neutron sources. Simple and compact accelerator designs using relatively low deuteron beam energy, ˜100 keV, have been developed which, in turn, can generate high neutron yields. New studies have been started for optimization of moderator materials for the 14.1 MeV DT neutrons. Our aim is to obtain an epithermal neutron beam for therapeutic application at the exit end, with minimal beam intensity losses, the specific goal is to achieve an epithermal neutron flux of at least of 1×109 n/cm2 s at the beam port, with low gamma and fast neutron dose contamination. According to the most recent neutron BNCT beam parameters some moderating and spectrum shifter materials and geometrical configurations have thus far been tested, and neutron and gamma beam data at beam port have been computed. A possible beam shaping assembly model has been designed. This research demonstrates that a DT neutron source could be successfully implemented for BNCT application, with performance surpassing the minimum requirements stated above, using DT neutron sources with yields in the range 1013-1014 n/s. The latest Monte Carlo simulation results of an accelerator based facility which relies on a rf-driven DT fusion neutron generator will be presented.

  11. Polishing of denture base acrylic resin with chairside polishing kits: an SEM and surface roughness study.

    Science.gov (United States)

    Chatzivasileiou, Konstantinos; Emmanouil, Ioannis; Kotsiomiti, Eleni; Pissiotis, Argirios

    2013-01-01

    Heat-cured acrylic resin specimens were polished using either conventional laboratory polishing, sandpaper, or three commercial chairside kits. The surface roughness of the polished specimens was measured with a contact profilometer. Scanning electron microscopy was used to obtain microphotographs of the polished surfaces. Laboratory polishing produced the smoothest surfaces in all cases, while sandpaper application produced the roughest. Use of the chairside polishing kits resulted in significantly rougher surfaces compared to those produced by laboratory polishing. Nonetheless, polishing of trimmed denture bases using chairside polishing kits is an effective alternative procedure for cases in which the laboratory procedure is not applicable.

  12. Dynamic measurement of local displacements within curing resin-based dental composite using optical coherence elastography

    Science.gov (United States)

    Tomlins, Peter H.; Rahman, Mohammed Wahidur; Donnan, Robert S.

    2016-04-01

    This study aimed to determine the feasibility of using optical coherence elastography to measure internal displacements during the curing phase of a light-activated, resin-based composite material. Displacement vectors were spatially mapped over time within a commercial dental composite. Measurements revealed that the orientation of cure-induced displacement vectors varied spatially in a complex manner; however, each vector showed a systematic evolution with time. Precision of individual displacements was estimated to be ˜1 to 2 μm, enabling submicrometer time-varying displacements to be detected.

  13. Polymerization contraction and conversion of light-curing BisGMA-based methacrylate resins.

    Science.gov (United States)

    Venhoven, B A; de Gee, A J; Davidson, C L

    1993-09-01

    The aim of this study was to investigate the polymerization contraction and the conversion of light-curing methacrylate resins based on bisphenol-A bis(2-hydroxypropyl)methacrylate (BisGMA) diluted with triethylene glycol dimethyacrylate (TEGDMA), methyl methacrylate (MMA), hydroxypropyl methacrylate (HPMA) or (+/-)-2-ethylhexyl methacrylate (EHMA). The contraction measurements were carried out with a linometer, a simple device to determine true linear polymerization contraction of liquid monomers at ambient temperature. The contraction increased with the amount of diluting monomer. The estimated conversion of the BisGMA-TEGDMA, calculated using the contraction, is consistent with literature values. The BisGMA-HPMA mixtures showed high conversions at moderate contraction.

  14. Effect of 4-MET- and 10-MDP-based primers on resin bonding to titanium.

    Science.gov (United States)

    Tsuchimoto, Youhei; Yoshida, Yasuhiro; Mine, Atsushi; Nakamura, Mariko; Nishiyama, Norihiro; Van Meerbeek, Bart; Suzuki, Kazuomi; Kuboki, Takuo

    2006-03-01

    The purpose of this study was to investigate the effect of a 4-MET- and 10-MDP-based primer on the bond strength of two resin cements (SuperBond C&B, Sun Medical; Panavia Fluoro Cement, Kuraray) to titanium (Ti). Ti plates were treated with six experimental primers consisting of, respectively, 10-MDP and 4-MET in concentrations of 0.1, 1 and 10wt%, or were kept untreated (control). The highest tensile bond strength of Panavia Fluoro Cement to Ti was obtained when the Ti surface was pre-treated with 10wt% 10-MDP and was significantly higher than that when a lower concentrated 10-MDP-based primer or any 4-MET-based primer was used. On the contrary, no significant difference in tensile bond strength of SuperBond C&B was found for the untreated and six pre-treated Ti surfaces, although pre-treatment with each 10-MDP-based primer resulted in a higher tensile bond strength as compared to any 4-MET pre-treatment. Altogether, the data obtained strongly suggest that 10-MDP is effective to improve the adhesive performance of resin to titanium.

  15. Treatment of Perchlorate-Contaminated Groundwater Using Highly-Selective, Regenerable Anion-Exchange Resins at Edwards Air Force Base

    Energy Technology Data Exchange (ETDEWEB)

    Gu, B.

    2003-05-30

    Selective ion exchange is one of the most effective treatment technologies for removing low levels of perchlorate (ClO{sub 4}{sup -}) from contaminated water because of its high efficiency without adverse impacts on the water quality caused by adding or removing any chemicals or nutrients. This report summarizes both the laboratory and a field pilot-scale studies to determine the ability and efficiency of the bifunctional synthetic resins to remove ClO{sub 4}{sup -} from the contaminated groundwater at the Edwards Air Force Base in California. Regeneration of the resins after groundwater treatment was also evaluated using the FeCl{sub 3}-HCl regeneration technique recently developed at Oak Ridge National Laboratory. On the basis of this study, the bifunctional resin, D-3696 was found to be highly selective toward ClO{sub 4}{sup -} and performed much better than one of the best commercial nitrate-selective resins (Purolite A-520E) and more than an order of magnitude better than the Purolite A-500 resin (with a relatively low selectivity). At an influent concentration of {approx} 450 {micro}g/L ClO{sub 4}{sup -} in groundwater, the bifunctional resin bed treated {approx} 40,000 empty bed volumes of groundwater before a significant breakthrough of ClO{sub 4}{sup -} occurred. The presence of relatively high concentrations of chloride and sulfate in site groundwater did not appear to affect the ability of the bifunctional resin to remove ClO{sub 4}{sup -}. However, the presence of high iron or iron oxyhydroxides and/or biomass in groundwater caused a significant fouling of the resin beds and greatly influenced the effectiveness in regenerating the resins sorbed with ClO{sub 4}{sup -}. Under such circumstances, a prefilter ({approx} 0.5-1 {micro}m) was found to be necessary to remove these particulates and to reduce the risk of fouling of the resin beds. Without significant fouling, the resin bed could be effectively regenerated by the FeCl{sub 3} displacement technique

  16. Biocompatibility of composite resins

    OpenAIRE

    Sayed Mostafa Mousavinasab

    2011-01-01

    Dental materials that are used in dentistry should be harmless to oral tissues, so they should not contain any leachable toxic and diffusible substances that can cause some side effects. Reports about probable biologic hazards, in relation to dental resins, have increased interest to this topic in dentists. The present paper reviews the articles published about biocompatibility of resin-restorative materials specially resin composites and monomers which are mainly based on Bis-GMA and concern...

  17. First platinum moderated positron beam based on neutron capture

    CERN Document Server

    Hugenschmidt, C; Repper, R; Schreckenbach, K; Sperr, P; Triftshaeuser, W

    2002-01-01

    A positron beam based on absorption of high energy prompt gamma-rays from thermal neutron capture in sup 1 sup 1 sup 3 Cd was installed at a neutron guide of the high flux reactor at the ILL in Grenoble. Measurements were performed for various source geometries, dependent on converter mass, moderator surface and extraction voltages. The results lead to an optimised design of the in-pile positron source which will be implemented at the Munich research reactor FRM-II. The positron source consists of platinum foils acting as gamma-e sup + e sup - -converter and positron moderator. Due to the negative positron work function moderation in heated platinum leads to emission of monoenergetic positrons. The positron work function of polycrystalline platinum was determined to 1.95(5) eV. After acceleration to several keV by four electrical lenses the beam was magnetically guided in a solenoid field of 7.5 mT leading to a NaI-detector in order to detect the 511 keV gamma-radiation of the annihilating positrons. The posi...

  18. Neutron detector based on lithiated sol-gel glass

    CERN Document Server

    Wallace, S; Miller, L F; Dai, S

    2002-01-01

    A neutron detector technology is demonstrated based on sup 6 Li/ sup 1 sup 0 B doped sol-gel glass. The detector is a sol-gel glass film coated silicon surface barrier detector (SBD). The ionized charged particles from (n, alpha) reactions in the sol-gel film enter the SBD and are counted. Data showing that gamma-ray pulse amplitudes interfere with identifying charged particles that exit the film layer with energies below the gamma-ray energy is presented. Experiments were performed showing the effect of sup 1 sup 3 sup 7 Cs and sup 6 sup 0 Co gamma rays on the SBD detector. The reaction product energies of the triton and alpha particles from sup 6 Li are significantly greater than the energies of the Compton electrons from high-energy gamma rays, allowing the measurement of neutrons in a high gamma background. The sol-gel radiation detection technology may be applicable to the characterization of transuranic waste, spent nuclear fuel and to the monitoring of stored plutonium.

  19. Transparent plastic scintillators for neutron detection based on lithium salicylate

    Energy Technology Data Exchange (ETDEWEB)

    Mabe, Andrew N.; Glenn, Andrew M.; Carman, M. Leslie; Zaitseva, Natalia P.; Payne, Stephen A.

    2016-01-01

    Transparent plastic scintillators with pulse shape discrimination containing 6Li salicylate have been synthesized by bulk polymerization with a maximum 6Li loading of 0.40 wt%. Photoluminescence and scintillation responses to gamma-rays and neutrons are reported herein. Plastics containing 6Li salicylate exhibit higher light yields and permit a higher loading of 6Li as compared to previously reported plastics based on lithium 3-phenylsalicylate. However, pulse shape discrimination performance is reduced in lithium salicylate plastics due to the requirement of adding more nonaromatic monomers to the polymer matrix as compared to those based on lithium 3-phenylsalicylate. Reduction in light yield and pulse shape discrimination performance in lithium-loaded plastics as compared to pulse shape discrimination plastics without lithium is interpreted in terms of energy transfer interference by the aromatic lithium salts.

  20. Effect of denture cleaning on abrasion resistance and surface topography of polymerized CAD CAM acrylic resin denture base.

    Science.gov (United States)

    Shinawi, Lana Ahmed

    2017-05-01

    The application of computer-aided design computer-aided manufacturing (CAD CAM) technology in the fabrication of complete dentures, offers numerous advantages as it provides optimum fit and eliminates polymerization shrinkage of the acrylic base. Additionally, the porosity and surface roughness of CAD CAM resins is less compared to conventionally processed resins which leads to a decrease in the adhesion of bacteria on the denture base, which is associated with many conditions including halitosis and aspiration pneumonia in elderly denture wearers. To evaluate the influence of tooth brushing with dentifrices on CAD CAM resin blocks in terms of abrasion resistance, surface roughness and scanning electron photomicrography. This experimental study was carried out at the Faculty of Dentistry of King Abdulaziz University during 2016. A total of 40 rectangular shaped polymerized CAD CAM resin samples were subjected to 40.000 and 60.000 brushing strokes under a 200-gram vertical load simulating three years of tooth brushing strokes using commercially available denture cleaning dentifrice. Data were analyzed by SPSS version 20, using descriptive statistics and ANOVA. ANOVA test revealed a statistical significant weight loss of CAD CAM acrylic resin denture base specimens following 40.000 and 60.000 brushing strokes as well as a statistical significant change (p=0.0.5) in the surface roughness following brushing. The CAD CAM resin samples SEM baseline imaging revealed a relatively smooth homogenous surface, but following 40,000 and 60,000 brushing strokes, imaging displayed the presence of small scratches on the surface. CAD CAM resin displayed a homogenous surface initially with low surface roughness that was significantly affected following simulating three years of manual brushing, but despite the significant weight loss, the findings are within the clinically acceptable limits.

  1. Bond strength of acrylic teeth to denture base resin after various surface conditioning methods before and after thermocycling

    NARCIS (Netherlands)

    Saavedra, Guilherme; Valandro, Luz Felipe; Leite, Fabiola Pessoa; Amaral, Regina; Oezcan, Mutlu; Bottino, Marco A.; Kimpara, Estevao T.

    2007-01-01

    This study aimed to evaluate the durability of adhesion between acrylic teeth and denture base acrylic resin. The base surfaces of 24 acrylic teeth were flatted and submitted to 4 surface treatment methods: SM1 (control): No SM; SM2: application of a methyl methacrylate-based bonding agent (Vitacol)

  2. Removal of dyes from water using crosslinked aminomethane sulfonic acid based resin.

    Science.gov (United States)

    Kaner, Damla; Saraç, Ayfer; Senkal, Bahire Filiz

    2010-08-01

    A new polymeric resin with amino sulfonic acid pendant functions has been prepared for the extraction of acidic and basic dyes from water. Beaded polymer supports were prepared by suspension polymerization of vinyl benzyl chloride (0.9 mol) and ethylene glycol dimethacrylate (0.1 mol). The resulting copolymer beads were modified with amino methane sulfonic acid. The dye adsorption capacity of the resin was found as 0.16 g dye/g resin for ramazol black and 0.15 g dye/g resin for crystal violet. The pH depending measurements and dye sorption kinetics of the resin were also investigated.

  3. Characterization methods for an accelerator based fast-neutron facility

    Science.gov (United States)

    Franklyn, C.; Daniels, G. C.

    2012-02-01

    A fast neutron facility provides a number of complexities in both detection and shielding, the latter arising not only due to uncertainty in the behaviour of the scattered radiation (neutron and gamma-rays) from a fast neutron source, but also on shielding requirements that have to take into account internal and external factors, such as dose limitations, space availability for implementing bulky shielding and secondary interactions of the radiation with materials. This has possible influence on experimental measurements with a low signal to noise ratio. This paper reports on some of the investigations performed at a RFQ accelerator facility generating > 1011 neutrons per second with energies up to 14 MeV, which are used to perform fast neutron radiography studies. Areas highlighted are the neutron cross section libraries, where important data needs to be reviewed or updated.

  4. Development of a composite resin disclosing agent based on the understanding of tooth staining mechanisms.

    Science.gov (United States)

    Abdallah, Mohamed-Nur; Light, Nathan; Amin, Wala M; Retrouvey, Jean-Marc; Cerruti, Marta; Tamimi, Faleh

    2014-06-01

    To characterize the surface composition of dental enamel and composite resin, assess the ability of dyes with different affinities to stain these surfaces, and use this information to develop a disclosing agent that stains composite resin more than dental enamel. One hundred and ten sound extracted teeth were collected and 60 discs of composite resin, 9 mm diameter and 3 mm thick, were prepared. X-ray photoelectron spectroscopy (XPS) was employed to determine the elemental composition on the different surfaces. A tooth shade spectrophotometer was used to assess the change in shade after staining the surfaces with different dyes. XPS analysis revealed that surfaces of both outer dental enamel and composite resin contained relatively high amounts of carbon, specifically hydrocarbons. Both dental enamel and composite surfaces were stainable with the hydrophobic dye (pcomposite resin was stained more than the dental enamel (pcomposite resin might explain their high affinity to be stained by food and beverages containing hydrophobic molecules. The composite resin is more stainable by hydrophobic dyes than dental enamel. We used this information to develop an agent for disclosing composite resins that could be used to visualize composite resins that need to be removed. Removal of composite resin can be problematic, time consuming and stressful to the dental practitioner. A composite disclosing agent would help the dental practitioner identify the composite resin and facilitate its removal without damaging the adjacent healthy tooth tissues. Copyright © 2014 Elsevier Ltd. All rights reserved.

  5. Advantages and drawbacks of Thiol-ene based resins for 3D-printing

    Science.gov (United States)

    Leonards, Holger; Engelhardt, Sascha; Hoffmann, Andreas; Pongratz, Ludwig; Schriever, Sascha; Bläsius, Jana; Wehner, Martin; Gillner, Arnold

    2015-03-01

    The technology of 3D printing is conquering the world and awakens the interest of many users in the most varying of applications. New formulation approaches for photo-sensitive thiol-ene resins in combination with various printing technologies, like stereolithography (SLA), projection based printing/digital light processing (DLP) or two-photon polymerization (TPP) are presented. Thiol-ene polymerizations are known for its fast and quantitative reaction and to form highly homogeneous polymer networks. As the resins are locally and temporally photo-curable the polymerization type is very promising for 3D-printing. By using suitable wavelengths, photoinitiator-free fabrication is feasible for single- and two photon induced polymerization. In this paper divinyl ethers of polyethylene glycols in combination with star-shaped tetrathiols were used to design a simple test-system for photo-curable thiol-ene resins. In order to control and improve curing depth and lateral resolution in 3D-polymerization processes, either additives in chemical formulation or process parameters can be changed. The achieved curing depth and resolution limits depend on the applied fabrication method. While two-/multiphoton induced lithography offers the possibility of micron- to sub-micron resolution it lacks in built-up speed. Hence single-photon polymerization is a fast alternative with optimization potential in sub-10-micron resolution. Absorber- and initiator free compositions were developed in order to avoid aging, yellowing and toxicity of resulting products. They can be cured with UV-laser radiation below 300 nm. The development at Fraunhofer ILT is focusing on new applications in the field of medical products and implants, technical products with respect to mechanical properties or optical properties of 3D-printed objects. Recent process results with model system (polyethylene glycol divinylether/ Pentaerithrytol tetrakis (3-mercaptopropionat), Raman measurements of polymer conversion

  6. Phenol-Formaldehyde Resin-Based Carbons for CO2 Separation at Sub-Atmospheric Pressures

    Directory of Open Access Journals (Sweden)

    Noelia Álvarez-Gutiérrez

    2016-03-01

    Full Text Available The challenge of developing effective separation and purification technologies that leave much smaller energy footprints is greater for carbon dioxide (CO2 than for other gases. In addition to its involvement in climate change, CO2 is present as an impurity in biogas and bio-hydrogen (biological production by dark fermentation, in post-combustion processes (flue gas, CO2-N2 and many other gas streams. Selected phenol-formaldehyde resin-based activated carbons prepared in our laboratory have been evaluated under static conditions (adsorption isotherms as potential adsorbents for CO2 separation at sub-atmospheric pressures, i.e., in post-combustion processes or from biogas and bio-hydrogen streams. CO2, H2, N2, and CH4 adsorption isotherms at 25 °C and up to 100 kPa were obtained using a volumetric equipment and were correlated by applying the Sips model. Adsorption equilibrium was then predicted for multicomponent gas mixtures by extending the multicomponent Sips model and the Ideal Adsorbed Solution Theory (IAST in conjunction with the Sips model. The CO2 uptakes of the resin-derived carbons from CO2-CH4, CO2-H2, and CO2-N2 at atmospheric pressure were greater than those of the reference commercial carbon (Calgon BPL. The performance of the resin-derived carbons in terms of equilibrium of adsorption seems therefore relevant to CO2 separation in post-combustion (flue gas, CO2-N2 and in hydrogen fermentation (CO2-H2, CO2-CH4.

  7. Experimental research on the THGEM-based thermal neutron detector

    CERN Document Server

    Lei, Yang; Zhi-Jia, Sun; Ying, Zhang; Chao-Qiang, Huang; Guang-Ai, Sun; Yan-Feng, Wang; Gui-An, Yang; Hong, Xu; Yu-Guang, Xie; Yuan-Bo, Chen

    2014-01-01

    A new thermal neutron detector with the domestically produced THGEM (THick Gas Electron Multiplier) was developed as an alternative to 3He to meet the needs of the next generation of neutron facilities. One type of Au-coated THGEM was designed specifically for the neutron detection. A detector prototype had been developed and the preliminary experimental tests were presented, including the performance of the Au-coated THGEM working in the Ar/CO2 gas mixtures and the neutron imaging test with 252CF source, which would provide the reference of experimental data for the research in future.

  8. CMOS-Based Neutron Spectroscopic Dosimeter (CNSD) Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Monitoring space radiation and the dose received by astronauts is important, especially for future long-duration missions. Neutrons contribute a significant...

  9. Bulk Density Adjustment of Resin-Based Equivalent Material for Geomechanical Model Test

    Directory of Open Access Journals (Sweden)

    Pengxian Fan

    2015-01-01

    Full Text Available An equivalent material is of significance to the simulation of prototype rock in geomechanical model test. Researchers attempt to ensure that the bulk density of equivalent material is equal to that of prototype rock. In this work, barite sand was used to increase the bulk density of a resin-based equivalent material. The variation law of the bulk density was revealed in the simulation of a prototype rock of a different bulk density. Over 300 specimens were made for uniaxial compression test. Test results indicated that the substitution of quartz sand by barite sand had no apparent influence on the uniaxial compressive strength and elastic modulus of the specimens but can increase the bulk density, according to the proportional coarse aggregate content. An ideal linearity was found in the relationship between the barite sand substitution ratio and the bulk density. The relationship between the bulk density and the usage of coarse aggregate and barite sand was also presented. The test results provided an insight into the bulk density adjustment of resin-based equivalent materials.

  10. Water sorption and solubility of methacrylate resin-based root canal sealers.

    Science.gov (United States)

    Donnelly, Adam; Sword, Jeremy; Nishitani, Yoshihiro; Yoshiyama, Masahiro; Agee, Kelli; Tay, Franklin R; Pashley, David H

    2007-08-01

    The water sorption and solubility characteristics of three contemporary methacrylate resin-based endodontic sealers, EndoREZ, Epiphany, and InnoEndo, were compared with those obtained from Kerr EWT, Ketac-Endo (positive control), GuttaFlow, and AH Plus (both negative controls). Ten disks of each material were dehydrated in Drierite for 24 h and weighed to constant dry mass. They were placed in water and weighed periodically until maximum water sorption was obtained. The disks were dehydrated again to determine their mass loss (solubility) at equilibrium. Epiphany exhibited the highest apparent water sorption (8%) followed by Ketac-Endo (6.2%), InnoEndo (3.4%), EndoREZ (3.0%), AH Plus (1.1%), GuttaFlow (0.4%), and Kerr EWT (0.3%). Significantly higher solubility (3.5-4%) were observed for all three methacrylate resin-based sealers and Kerr EWT (3.95%), compared with Ketac-Endo (1.6%), AH Plus (0.16%), and GuttaFlow (0.13%). American Dental Association specifications require<3% solubility for endodontic sealers. Only Ketac-Endo, AH Plus, and GuttaFlow met that criterion.

  11. Evaluation of sealing ability of two temporary resin-based cements used in Endodontics

    Directory of Open Access Journals (Sweden)

    Paloma Mariana Ramos Bitencourt

    2010-07-01

    Full Text Available Introduction: The outcome of endodontic treatment is related to the sealing ability of temporary dental restoration, which aims to prevent bacterial infiltration and recontamination of the root canal system.Objective: The purpose of this study was to evaluate the sealing ability of two temporary resin-based cements: Fill Magic Tempo and Bioplic.Material and methods: Twenty-four third molars were used, and twenty-two of them were opened to the pulp chamber (resulting in a class I cavity and randomly divided: group 1 was restored using Fill Magic Tempo (n = 10 and group 2 was restored using Bioplic (n = 10.The negative control group was not opened (n = 2, and the positive control group was opened but not restored (n = 2. Then the root and apex of the teeth were varnished to become impermeable. All samples were immersed in 2% methylene blue and kept at 37°C for 72h.After longitudinal sectioning, the linear leakage was measured in mm.In sequence, the statistical analysis was performed using Mann-Whitney test with a level of significance of 5%. Results: Most part of the samples showed leakage of 1 mm, and only the negative control group showed total leakage. There was no significant difference between the tested materials. Conclusion: It is possible to conclude that both resin-based cements showed satisfactory results on sealing ability during endodontic treatment.

  12. Penetration of resin-based materials into initial erosion lesion: A confocal microscopic study.

    Science.gov (United States)

    Ionta, Franciny Querobim; Boteon, Ana Paula; Moretto, Marcelo Juliano; Júnior, Odair Bim; Honório, Heitor Marques; Silva, Thiago Cruvinel; Wang, Linda; Rios, Daniela

    2016-02-01

    The application of resin-based materials is an alternative of treatment for eroded lesions. Nevertheless, there are no studies about the penetration of these materials into eroded lesion, which might affect its adhesion. Therefore, this study evaluated the penetration of four resin-based materials, with and without enamel etching. By using an in vitro protocol, types of treatment were studied at five levels (AdheSE(®) , Tetric N-Bond(®) , Single Bond 2(®) , Helioseal Clear(®) , Icon(®) ) and types of enamel etching in two levels (with and without). Materials were stained with 0.02 mg/mL ethanolic solution of tetramethylrhodamine isothiocyanate. Bovine enamel samples (4 × 4 mm) were immersed in 0.01 M HCl, pH 2.3, for 30 seconds to produce initial eroded lesions. Afterward, the materials were applied on half of sample enamel surface following the manufacturer's instructions. On the other half of sample, the materials were applied without etching the enamel. Materials penetration into the enamel was assessed by Confocal Laser Scanning Microscopy on reflection and fluorescence modes. The penetration depth (PD) was measured using ImageJ software. Data were analyzed by two-way ANOVA and Tukey test (P material, etched enamel resulted in higher PD than non-etched (P  0.05). It can be concluded that prior enamel etching increased the materials penetration into eroded enamel and the Icon(®) -infiltrant presented highest penetration.

  13. Effect of silanization of hydroxyapatite fillers on physical and mechanical properties of a bis-GMA based resin composite.

    Science.gov (United States)

    Lung, Christie Ying Kei; Sarfraz, Zenab; Habib, Amir; Khan, Abdul Samad; Matinlinna, Jukka Pekka

    2016-02-01

    To evaluate the physical and mechanical properties of an experimental bis-GMA-based resin composite incorporated with non-silanized and silanized nano-hydroxyapatite (nHAP) fillers. Experimental bis-GMA based resin composites samples which were reinforced with nHAP fillers were prepared. Filler particles were surface treated with a silane coupling agent. Five test groups were prepared: 1. Unfilled, 2. Reinforced with 10wt% and 30wt% non-silanized nHAP fillers, and 3. Reinforced with 10wt% and 30wt% silanized nHAP fillers. The samples were subjected to tests in dry condition and in deionized water, aged at 37°C for 30 days. Prepared silanized and non-silanized nHAP were analyzed with Fourier Transform Infrared (FTIR) Spectroscopy and X-ray Photoelectron Spectroscopy (XPS). The micro-hardness and water sorption were evaluated. Data were analyzed by one-way ANOVA (psilane treated fillers was superior to unfilled and untreated fillers resins. The resin matrix loaded with 30wt% silanized-nHAP fillers would improve the physical and mechanical properties of a bis-GMA based resin.

  14. 18-year survival of posterior composite resin restorations with and without glass ionomer cement as base.

    Science.gov (United States)

    van de Sande, Françoise H; Rodolpho, Paulo A Da Rosa; Basso, Gabriela R; Patias, Rômulo; da Rosa, Quéren F; Demarco, Flávio F; Opdam, Niek J; Cenci, Maximiliano S

    2015-06-01

    Advantages and disadvantages of using intermediate layers underneath resin-composite restorations have been presented under different perspectives. Yet, few long-term clinical studies evaluated the effect of glass-ionomer bases on restoration survival. The present study investigated the influence of glass-ionomer-cement base in survival of posterior composite restorations, compared to restorations without base. Original datasets of one dental practice were used to retrieve data retrospectively. The presence or absence of an intermediate layer of glass-ionomer-cement was the main factor under analysis, considering survival, annual failure rate and types of failure as outcomes. Other investigated factors were: patient gender, jaw, tooth, number of restored surfaces and composite. Statistical analysis was performed using Fisher's exact test, Kaplan-Meier method and multivariate Cox-regression. In total 632 restorations in 97 patients were investigated. Annual failure rates percentages up to 18-years were 1.9% and 2.1% for restorations with and without base, respectively. In restorations with glass-ionomer-cement base, fracture was the predominant reason for failure, corresponding to 57.8% of total failures. Failure type distribution was different (p=0.007) comparing restorations with and without base, but no effect in the overall survival of restorations was found (p=0.313). The presence of a glass-ionomer-cement base did not affect the survival of resin-composite restorations in the investigated sample. Acceptable annual failure rates after 18-years can be achieved with both techniques, leading to the perspective that an intermediate layer, placed during an interim treatment, may be maintained without clinical detriment, but no improvement in survival should be expected based on such measure. Copyright © 2015 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

  15. The $\\mu$TPC Method: Improving the Position Resolution of Neutron Detectors Based on MPGDs

    CERN Document Server

    Pfeiffer, Dorothea; Birch, Jens; Hall-Wilton, Richard; Höglund, Carina; Hultman, Lars; Iakovidis, George; Oliveri, Eraldo; Oksanen, Esko; Ropelewski, Leszek; Thuiner, Patrik

    2015-01-01

    Due to the Helium-3 crisis, alternatives to the standard neutron detection techniques are becoming urgent. In addition, the instruments of the European Spallation Source (ESS) require advances in the state of the art of neutron detection. The instruments need detectors with excellent neutron detection efficiency, high-rate capabilities and unprecedented spatial resolution. The Macromolecular Crystallography instrument (NMX) requires a position resolution in the order of 200 um over a wide angular range of incoming neutrons. Solid converters in combination with Micro Pattern Gaseous Detectors (MPGDs) are proposed to meet the new requirements. Charged particles rising from the neutron capture have usually ranges larger than several millimetres in gas. This is apparently in contrast with the requirements for the position resolution. In this paper, we present an analysis technique, new in the field of neutron detection, based on the Time Projection Chamber (TPC) concept. Using a standard Single-GEM with the catho...

  16. Neutron imaging detector based on the muPIC micro-pixel chamber

    CERN Document Server

    Parker, J D; Fujioka, H; Harada, M; Iwaki, S; Kabuki, S; Kishimoto, Y; Kubo, H; Kurosawa, S; Miuchi, K; Nagae, T; Nishimura, H; Oku, T; Sawano, T; Shinohara, T; Suzuki, J; Takada, A; Tanimori, T; Ueno, K

    2012-01-01

    We have developed a prototype time-resolved neutron imaging detector employing the micro-pixel chamber (muPIC), a micro-pattern gaseous detector, coupled with a field programmable gate array-based data acquisition system for applications in neutron radiography at high-intensity neutron sources. The prototype system, with an active area of 10cm x 10cm and operated at a gas pressure of 2 atm, measures both the energy deposition (via time-over-threshold) and 3-dimensional track of each neutron-induced event, allowing the reconstruction of the neutron interaction point with improved accuracy. Using a simple position reconstruction algorithm, a spatial resolution of 349 +/- 36 microns was achieved, with further improvement expected. The detailed tracking allows strong rejection of background gamma-rays, resulting in an effective gamma sensitivity of 10^-12 or less, coupled with stable, robust neutron identification. The detector also features a time resolution of 0.6 microseconds.

  17. Dental cavity liners for Class I and Class II resin-based composite restorations.

    Science.gov (United States)

    Schenkel, Andrew B; Peltz, Ivy; Veitz-Keenan, Analia

    2016-10-25

    Resin-based composite (RBC) is currently accepted as a viable material for the restoration of caries for posterior permanent teeth requiring surgical treatment. Despite the fact that the thermal conductivity of the RBC restorative material closely approximates that of natural tooth structure, postoperative hypersensitivity is sometimes still an issue. Dental cavity liners have historically been used to protect the pulp from the toxic effects of some dental restorative materials and to prevent the pain of thermal conductivity by placing an insulating layer between restorative material and the remaining tooth structure. The objective of this review was to assess the effects of using dental cavity liners in the placement of Class I and Class II resin-based composite posterior restorations in permanent teeth in children and adults. Cochrane Oral Health's Information Specialist searched the following databases: Cochrane Oral Health's Trials Register (to 25 May 2016), the Cochrane Central Register of Controlled Trials (CENTRAL; 2016, Issue 4) in the Cochrane Library (searched 25 May 2016), MEDLINE Ovid (1946 to 25 May 2016), Embase Ovid (1980 to 25 May 2016) and LILACS BIREME Virtual Health Library (Latin American and Caribbean Health Science Information database; 1982 to 25 May 2016). We searched ClinicalTrials.gov and the World Health Organization International Clinical Trials Registry Platform for ongoing trials. No restrictions were placed on the language or date of publication when searching the electronic databases. We included randomized controlled trials assessing the effects of the use of liners under Class I and Class II posterior resin-based composite restorations in permanent teeth (in both adults and children). We included both parallel and split-mouth designs. We utilized standard methodological procedures prescribed by Cochrane for data collection and analysis. Two review authors screened the search results and assessed the eligibility of studies for

  18. Commercial Applications at FRM II Based on Neutron Irradiations

    Energy Technology Data Exchange (ETDEWEB)

    Gerstenberg, H.; Draack, A.; Kastenmuller, A. [Technische Universitaet Muenchen, Munchen (Germany)

    2013-07-01

    Due to its design as a heavy water moderated reactor with a very compact core FRM II, Germany's most modern and most powerful research reactor, offers excellent conditions for basic research using beam tubes. On the other hand it is equipped with various irradiation facilities to be used mainly for industrial purposes. From the very beginning of reactor operation a dedicated department had been implemented in order to provide a neutron irradiation service to interested parties on a commercial basis. As of today the most widely used application is Si doping. The semiautomatic doping facility accepts ingots with diameters between 125 mm and 200 mm and a maximum height of 500 mm. The irradiation channel is located deep in the heavy water tank and exhibits a ratio of thermal/fast neutron flux density of > 1000. This value allows the doping of Si to a target resistivity as high as 1100 Ωcm within the tight limits regarding accuracy and homogeneity specified by the customer. Typically the throughput of Si doped in FRM II sums up to about 15 t/year. Another topic of growing importance is the use of FRM II aiming the production of radioisotopes mainly for the radiopharmaceutical industry. The maybe most challenging example is the production of Lu-177 n. c. a. based on the irradiation of Yb{sub 2}O{sub 3} to a high fluence of thermal neutrons of typically 1.5E20 cm{sup -2}. The Lu-177 activity delivered to the customer is in the range of 750 GBq. With respect to further processing it turned out to be a highly advantageous to have the laboratories of ITG, the company extracting the Lu-177 from the freshly irradiated Yb{sub 2}O{sub 3} on site FRM II. Further irradiation facilities are available at FRM II in order to allow the activation of samples for analytical purposes or to irradiate samples for geochronological investigations using the fission track technique. Finally a project on the future installation of a facility dedicated to the irradiation of U-targets for

  19. Effect of Mechanical Surface Treatment on the Repair Bond Strength of the Silorane-based Composite Resin

    Directory of Open Access Journals (Sweden)

    Parnian Alizadeh Oskoee

    2014-06-01

    Full Text Available Background and aims. A proper bond must be created between the existing composite resin and the new one for successful repair. The aim of this study was to compare the effect of three mechanical surface treatments, using diamond bur, air abrasion, and Er,Cr:YSGG laser, on the repair bond strength of the silorane-based composite resin. Materials and methods. Sixty cylindrical composite resin specimens (Filtek Silorane were fabricated and randomly divided into four groups according to surface treatment: group 1 (control group without any mechanical surface treatment, groups 24 were treated with air abrasion, Er,Cr:YSGG laser, and diamond bur, respectively. In addition, a positive control group was assigned in order to measure the cohesive strength. Silorane bonding agent was used in groups 14 before adding the new composite resin. Then, the specimens were subjected to a shear bond strength test and data was analyzed using one-way ANOVA and post hoc Tukey tests at a significance level of P < 0.05. The topographical effects of surface treatments were characterized under a scanning electron microscope. Results. There were statistically significant differences in the repair bond strength values between groups 1 and 2 and groups 3 and 4 (P < 0.001. There were no significant differences between groups 1 and 2 (P = 0.98 and groups 3 and 4 (P = 0.97. Conclusion. Surface treatment using Er,Cr:YSGG laser and diamond bur were effective in silorane-based composite resin repair.

  20. Properties of experimental resins based on synthesized propoxylated bis-GMA with different propionaldehyde ratios

    Directory of Open Access Journals (Sweden)

    Aline Bassi Denis

    2012-06-01

    Full Text Available The effect of different propionaldehyde ratios on the properties of bis-GMA-based comonomers and copolymers diluted with propoxylated bis-GMA (CH3bis-GMA was evaluated. Five experimental comonomers were prepared combining bis-GMA with CH3bis-GMA and propionaldehyde at 0, 2, 8, 16, 24 mol%. Light polymerization was effected with the use of 0.2 wt. (% each of camphorquinone and N,N-dimethyl-p-toluidine. Resin degrees of conversion (%DC were evaluated by FT-IR spectrophotometry and Tg by Differential Scanning Calorimeter. Complex viscosity (η*, the effect of temperature on η*, and Microhardness (H for dry and wet samples were also determined. Data were analyzed by Student's t-test, one-way ANOVA and Tukey-Kramer test (α = 0.05. The group with 24 mol% additive had a significant increase in %DC and H, and the lowest comonomer Tg and η*. No remarkable variation was noted in copolymers Tg s. All resins presented Newtonian behavior of viscosity, which linearly decreased with increased temperature. The η* decreased sigmoidally as the additive ratio increased.

  1. Isothermal curing of polymer layered silicate nanocomposites based upon epoxy resin by means of anionic homopolymerisation

    Energy Technology Data Exchange (ETDEWEB)

    Román, Frida, E-mail: roman@mmt.upc.edu; Calventus, Yolanda, E-mail: calventus@mmt.upc.edu; Colomer, Pere, E-mail: colomer@mmt.upc.edu; Hutchinson, John M., E-mail: hutchinson@mmt.upc.edu

    2013-12-20

    Highlights: • The nanocomposite with low content of clay displayed improved thermal properties. • The vitrification was observed in the isothermal curing. • Dielectric relaxations outside and inside of the clay galleries were detected. - Abstract: The use of an initiator, 4-(dimethylamino) pyridine (DMAP), to promote an anionic homopolymerisation reaction for the isothermal cure of polymer layered silicate (PLS) nanocomposites based on an epoxy resin, as well as the effect of the nanoclay content, have been studied by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), dielectric relaxation spectroscopy (DRS) and transmission electron microscopy (TEM). The vitrification phenomenon was observed during the isothermal cure process, and it was found that the nanocomposite with a low clay content (2 wt%), denoted EDM2, shows improved thermal properties with respect to the unreinforced resin (denoted ED), while the nanocomposite with a higher clay content (5 wt%), denoted EDM5, displayed inferior properties. The cure kinetics were analysed by different methods, and it was observed that the activation energy and kinetic parameters of EDM2 were lower compared to the other two systems. Examination of the nanostructure of the cured EDM2 nanocomposite showed partial exfoliation, while the EDM5 system retains an intercalated nanostructure. In the DRS studies of the curing process of the EDM2 system, two dielectric relaxations were detected, which are associated with the molecular mobility in the curing reaction which takes place both outside and inside the clay galleries.

  2. Optical techniques for determination of the state of cure of epoxy resin based systems

    Science.gov (United States)

    Michie, W. C.; Thursby, G.; Johnstone, W.; Culshaw, B.

    1993-03-01

    Determination of the state of cure of epoxy resin based systems is of considerable interest to manufacturers of large carbon fiber reinforced plastic and glass reinforced plastic structures. Optical methods designed to indicate the cure state have been developed using a loss mechanism which is a function of the refractive index of the curing system. Such techniques are however subject to corruption from losses arising from other influences and consequently are limited in their measurement resolution. In this paper, two techniques which are able to provide a high degree of accuracy of measurement of refractive index are investigated as a means of performing cure measurements. The methods investigated involve the interaction of the evanescent field of a side polished optical fiber with an overlay waveguide or a surface plasmon. Coupling between the fiber and the overlay waveguide (or plasmon) is strongly influenced by the refractive index of the bulk superstrate above the overlay (in this case the curing resin system). Both sensing schemes are self referencing and are not influenced by loss.

  3. Cation exchange resin nanocomposites based on multi-walled carbon nanotubes

    Science.gov (United States)

    Fathy, Mahmoud; Abdel Moghny, Th.; Awad Allah, Ahmed Elsayed; Alblehy, AbdElhamid

    2014-01-01

    Carbon nanotubes (CNTs) are of great interest due to their potential applications in different fields such as water treatment and desalination. The increasing exploitation of multi-walled carbon nanotubes (MWCNTs) into many industrial processes has raised considerable concerns for environmental applications. The interactions of soluble salt with MWNCTs influence in the total salt content in saline water. In this work, we synthesized two cation exchange resins nano composites from polystyrene divinylbenzene copolymer (PSDVB) and pristine MWNCTs. The prepared compounds were characterized using infra red spectroscopy, thermal stability, X-ray diffraction, and electro scan microscope. Also, the ion capacities of prepared cation exchange resins were determined by titration. Based on the experimental results, it was found that the thermal stability of prepared nanocomposites in the presence of MWNCTs increased up to 617 °C. The X-ray of PSDVB and its sulfonated form exhibits amorphous pattern texture structure, whereas the nano composite exhibits amorphous structure with indication peak at 20° and 26° for the PSDVB and MWCNTs, respectively. The ion-exchange capacity increased from 225.6 meq/100 g to 466 mg/100 g for sulfonated PSDVB and sulfonated PSDVB MWNCTs-pristine, respectively.

  4. Development of dental resin luting agents based on Bis-EMA4: bond strength evaluation

    Directory of Open Access Journals (Sweden)

    2008-02-01

    Full Text Available The aim of this study was to investigate the influence of incorporating Bis-EMA4 monomer into experimental Bis-GMA/TEGDMA-based resin luting agents on the bond strength to dentin. Seven mixtures were prepared with the following ratios (wt% of Bis-GMA/TEGDMA/Bis-EMA4: 50/50/0, 50/30/20, 50/10/40, 50/0/50, 30/10/60, 10/10/80 and 0/0/100. Camphorquinone (0.4 wt%, N,N-dimethyl-p-toluidine (0.8 wt% and hydroquinone (0.2 wt% were dissolved in each mixture, which was loaded with silanated strontium glass fillers to a constant content of 60 wt%. Bond strength was evaluated by microshear testing (n = 10 on bovine dentin. Data were submitted to Analysis of Variance (p<0.05. Modes of failure were classified under magnification (200×. Bond strength means (MPa, respective to each agent, were: 19.4, 19.8, 20.0, 19.1, 16.8, 18.7 and 17.8. No significant differences were detected among groups. Mixed failures were generally predominant for all materials. In conclusion, the addition of Bis-EMA4 presented no significant influence on the bond strength of the experimental resin luting agents to dentin.

  5. Correlation between the degree of conversion and the elution of leachable components from dental resin-based cements

    Directory of Open Access Journals (Sweden)

    KOSOVKA OBRADOVIĆ-DJURIČIĆ

    2011-09-01

    Full Text Available This study examined the possible correlation between the degree of conversion (DC and the amount of substances eluted from three commercial cured resin-based cements. The DC of the various resin-based cements was measured by Raman spectroscopy, while the quantity of unreacted monomers released from the cement matrix (triethylene glycol dimethacrylate, TEGDMA, urethane dimethacrylate, UDMA, 2-hydroxyethyl methacrylate, HEMA and bisphenol A was determined by high pressure liquid chromatography (HPLC. The obtained results, after multiple statistical evaluation (one way ANOVA, LSD post hoc test, showed no significant differences in the DC values between the resin cements. On the contrary, the results of the HPLC analysis depicted statistically significant differences between the three materials with respect to the amount of leached monomers. In addition, no correlation between the DC and the amount of eluted substances from the tested cured composite cements was found.

  6. Fission, spallation or fusion-based neutron sources

    Indian Academy of Sciences (India)

    Kurt N Clausen

    2008-10-01

    In this paper the most promising technology for high power neutron sources is briefly discussed. The conclusion is that the route to high power neutron sources in the foreseeable future is spallation – short or long pulse or even CW – all of these sources will have areas in which they excel.

  7. Neutron beam monitor based on a boron-coated GEM

    Institute of Scientific and Technical Information of China (English)

    周健荣; 李仪; 孙志嘉; 刘贲; 王艳凤; 杨桂安; 周良; 许虹; 董静; 杨雷

    2011-01-01

    A new thermal neutron beam monitor with a Gas Electron Multiplier (GEM) is developed to meet the needs of the next generation of neutron facilities. A prototype chamber has been constructed with two 100 mm×100 mm GEM foils. Enriched boron-10 is coated on

  8. Restored viability and function of dental pulp cells on poly-methylmethacrylate (PMMA)-based dental resin supplemented with N-acetyl cysteine (NAC).

    Science.gov (United States)

    Kojima, N; Yamada, M; Paranjpe, A; Tsukimura, N; Kubo, K; Jewett, A; Ogawa, T

    2008-12-01

    This study examines cytotoxicity of poly-methylmethacrylate (PMMA)-based dental temporary filling resin to dental pulp cells, and the potential amelioration of the toxicity with an anti-oxidant amino-acid, N-acetyl cysteine (NAC). Dental pulp cells extracted from rat maxillary incisors were cultured on the resin material with or without NAC incorporation, or on the polystyrene. The cultures were supplied with osteoblastic media, containing dexamethasone. Forty five percent of cells on the PMMA dental resin were necrotic at 24h after seeding. However, this percentage was reduced to 27% by incorporating NAC in the resin, which was the level equivalent to that in the culture on polystyrene. The culture on the untreated resin was found to be negative for alkaline phosphate (ALP) activity at days 5 and 10 or von Kossa mineralized nodule formation at day 20. In contrast, some areas of the cultures on NAC-incorporated resin substrates were ALP and von Kossa positive. Collagen I and dentin sialoprotein genes were barely expressed in day 7 culture on the untreated resin. However, those genes were expressed in the culture on the resin with NAC. These results suggest that the decreased cell viability and the nearly completely suppressed odontoblast-like cell phenotype of dental pulp cells cultured on PMMA dental resin can be salvaged to a biologically significant degree by the incorporation of NAC in the resin.

  9. Neutron shielding material design based on Monte Carlo simulation%基于蒙特卡罗方法的中子屏蔽材料设计

    Institute of Scientific and Technical Information of China (English)

    陈飞达; 汤晓斌; 王鹏; 陈达

    2012-01-01

    基于蒙特卡罗粒子输运程序MCNP,设计了一种强度高、密度低、具有优异中子屏蔽性能的新型玻璃纤维/B4C/环氧树脂复合材料,模拟计算了镅-铍(Am-Be)中子源产生中子对该材料的透射率;研究了该材料的中子屏蔽性能与传统屏蔽材料的差异以及不同B4C质量分数对该材料的屏蔽性能影响;根据模拟结果分析了该材料对不同能区中子(慢中子、中能中子、快中子)具有的不同屏蔽性能.研究发现:B4C质量分数为10%的该种新型玻璃纤维/B4C/环氧树脂复合材料的中子屏蔽性能,尤其是慢中子屏蔽性能较传统的含硼聚乙烯和Al-B4C合金材料更为优异;但随着B4C质量分数的增大,屏蔽性能提升不明显.结果验证了蒙特卡罗方法用于中子屏蔽材料优化设计的可行性.%Based on the Monte Carlo particle transport program MCNP, a noveL glass fiber/B4 C/epoxy resin composite for neutron shielding with high strength and low density was developed. Its neutron transmissivity was calculated under the Am-Be neutron source condition to study the difference of neutron shielding performance between the glass fiber/B4 C/epoxy resin composite and traditional shielding materials. Furthermore, effects of B4 C mass fraction of the composite on the shielding performance for neutrons with different energy(slow neutron, intermediate neutron, fast neutron) were analyzed. The results show the composites with 10% B4C mass contents have more advantages on the neutron shielding performance , especially the slow neutron shielding performance in comparison with polyethylene/boron containing composites and Al-B4 C alloy. With the further increasing of the B4C contents, no remarkable increase is observed. Monte Carlo method is demonstrated feasible in optimization design of neutron shielding materials and the results provide a theoretical basis for design and preparation of a new neutron shielding composite.

  10. Neutron irradiation effects on gallium nitride-based Schottky diodes

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Chung-Han; Katz, Evan J.; Zhang, Zhichun [Department of Electrical and Computer Engineering, The Ohio State University, Columbus Ohio 43210 (United States); Qiu, Jie; Cao, Lei [Nuclear Engineering Program, Department of Mechanical and Aerospace Engineering, The Ohio State University, Columbus, Ohio 43210 (United States); Mishra, Umesh K. [Departments of Electrical and Computer Engineering and Materials Science and Engineering, University of California, Santa Barbara, California 93106 (United States); Brillson, Leonard J. [Department of Electrical and Computer Engineering, The Ohio State University, Columbus Ohio 43210 (United States); Department of Physics and Center for Materials Research, The Ohio State University, Columbus, Ohio 43210 (United States)

    2013-10-14

    Depth-resolved cathodoluminescence spectroscopy (DRCLS), time-resolved surface photovoltage spectroscopy, X-ray photoemission spectroscopy (XPS), and current-voltage measurements together show that fast versus thermal neutrons differ strongly in their electronic and morphological effects on metal-GaN Schottky diodes. Fast and thermal neutrons introduce GaN displacement damage and native point defects, while thermal neutrons also drive metallurgical reactions at metal/GaN interfaces. Defect densities exhibit a threshold neutron fluence below which thermal neutrons preferentially heal versus create new native point defects. Scanning XPS and DRCLS reveal strong fluence- and metal-dependent electronic and chemical changes near the free surface and metal interfaces that impact diode properties.

  11. A transportable neutron radiography system based on a SbBe neutron source

    Science.gov (United States)

    Fantidis, J. G.; Nicolaou, G. E.; Tsagas, N. F.

    2009-07-01

    A transportable neutron radiography system, incorporating a SbBe neutron source, has been simulated using the MCNPX code. Design provisions have allowed two radiography systems to be utilised using the same SbBe neutron source. In this respect, neutron radiographies can be carried out using the photoneutrons produced when the 124Sb is surrounded by the Be target. Alternatively, γ-radiography can be utilised with the photons from the 124Sb with the target removed. Appropriate collimators were simulated for each of the radiography modes. Apart from Be, the materials considered were compatible with the European Union Directive on 'Restriction of Hazardous Substances' (RoHS) 2002/95/EC, hence excluding the use of cadmium and lead. Bismuth was chosen as the material for γ-radiation shielding and the proposed system allowed a maximum activity of the 124Sb up to 1.85×1013 Bq. The system simulated allows different object sizes to be studied with a wide range of radiography parameters.

  12. A D-D/D-T fusion reaction based neutron generator system for liver tumor BNCT

    Energy Technology Data Exchange (ETDEWEB)

    Koivunoro, H.; Lou, T.P.; Leung, K. N.; Reijonen, J.

    2003-04-02

    Boron-neutron capture therapy (BNCT) is an experimental radiation treatment modality used for highly malignant tumor treatments. Prior to irradiation with low energetic neutrons, a 10B compound is located selectively in the tumor cells. The effect of the treatment is based on the high LET radiation released in the {sup 10}B(n,{alpha}){sup 7}Li reaction with thermal neutrons. BNCT has been used experimentally for brain tumor and melanoma treatments. Lately applications of other severe tumor type treatments have been introduced. Results have shown that liver tumors can also be treated by BNCT. At Lawrence Berkeley National Laboratory, various compact neutron generators based on D-D or D-T fusion reactions are being developed. The earlier theoretical studies of the D-D or D-T fusion reaction based neutron generators have shown that the optimal moderator and reflector configuration for brain tumor BNCT can be created. In this work, the applicability of 2.5 MeV neutrons for liver tumor BNCT application was studied. The optimal neutron energy for external liver treatments is not known. Neutron beams of different energies (1eV < E < 100 keV) were simulated and the dose distribution in the liver was calculated with the MCNP simulation code. In order to obtain the optimal neutron energy spectrum with the D-D neutrons, various moderator designs were performed using MCNP simulations. In this article the neutron spectrum and the optimized beam shaping assembly for liver tumor treatments is presented.

  13. In vitro comparison of autoclave polymerization on the transverse strength of denture base resins.

    Science.gov (United States)

    Durkan, Rukiye; Ozel, Mehmet Birol; Bağiş, Bora; Usanmaz, Ali

    2008-07-01

    The aim of this study was to determine the effect of autoclave polymerization on the transverse strength of denture base polymers. To this end, 30 rectangular test specimens were fabricated of two heat-polymerized denture base polymers. The test groups were: (I) control, i.e., conventional water bath to polymerize resins by heat at 100 degrees C for 30 minutes; (II) autoclave polymerization at 60 degrees C for 30 minutes followed by 130 degrees C for 10 minutes; and (III) autoclave polymerization at 60 degrees C for 30 minutes followed by 130 degrees C for 20 minutes. The specimens were tested with three-point bending test at a crosshead speed of 5 mm/min. It was revealed that the transverse strength of specimens increased with statistical significance when the autoclave was used for polymerization.

  14. Resin-assisted enrichment of thiols as a general strategy for proteomic profiling of cysteine-based reversible modifications

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Jia [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Gaffrey, Matthew J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Su, Dian [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Genentech Inc., South San Francisco, CA (United States); Liu, Tao [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Camp, David G. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Smith, Richard D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Qian, Weijun [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2013-12-12

    Reversible modifications on cysteine thiols play a significant role in redox signaling and regulation. A number of reversible redox modifications, including disulfide formation, S-nitrosylation, and S-glutathionylation, have been recognized for their significance in various physiological and pathological processes. Here we describe in detail a resin-assisted thiol-affinity enrichment protocol for both biochemical and proteomics applications. This protocol serves as a general approach for specific isolation of thiol-containing proteins or peptides derived from reversible redox-modified proteins. This approach utilizes thiol-affinity resins to directly capture thiol-containing proteins or peptides through a disulfide exchange reaction followed by on-resin protein digestion and on-resin multiplexed isobaric labeling to facilitate LC-MS/MS based quantitative site-specific analysis of redox modifications. The overall approach requires a much simpler workflow with increased specificity compared to the commonly used biotin switch technique. By coupling different selective reduction strategies, the resin-assisted approach provides the researcher with a useful tool capable of enriching different types of reversible modifications on protein thiols. Procedures for selective enrichment and analyses of S-nitrosylation and total reversible cysteine oxidation are presented to demonstrate the utility of this general strategy.

  15. Mechanical properties of composites based on unsaturated polyester resins obtained by chemical recycling of poly(ethylene terephthalate

    Directory of Open Access Journals (Sweden)

    Marinković Aleksandar D.

    2013-01-01

    Full Text Available Composites based on unsaturated polyester (UPe resins and fumed silica AEROSIL® RY 50, NY 50, RX 50 and NAX 50, as well as graphite, TiO2 or organically modified clay CLOISITE 30B were prepared in order to investigate the influence of reinforcing agents on the mechanical properties of composites. Unsaturated polyester resins were synthesized from maleic anhydride and products of glycolysis, obtained by depolymerization of poly(ethylene terephthalate with dipropylene glycol (UPe1 resin and triethylene glycol (UPe2 resin in the presence of tetrabutyl titanate catalyst. The obtained unsaturated polyesters were characterized by FTIR spectroscopy, acid and hydroxyl values, and their mechanical properties were also examined. Significant increase of the tensile modulus, tensile strength and decrease of the elongation at break was observed for composites prepared after addition of 10 wt.% of graphite or 10 wt.% of TiO2 to the UPe resins, indicating strong interaction between matrix and filler particles. On the other hand, nanocomposites prepared using UPe2 and hydrophobically modified silica nanoparticles showed lower tensile strength and tensile modulus than polymer matrix. The presence of CLOISITE 30B had no significant influence on the mechanical properties of UPe1, while tensile strength and tensile modulus of UPe2 increased after adding 10 wt.% of clay. [Projekat Ministarstva nauke Republike Srbije, br. 172013

  16. Influence of acrylamide monomer addition to the acrylic denture-base resins on mechanical and physical properties.

    Science.gov (United States)

    Aydogan Ayaz, Elif; Durkan, Rukiye

    2013-12-01

    The aim of the study was to evaluate the effect of adding acrylamide monomer (AAm) on the characterization, flexural strength, flexural modulus and thermal degradation temperature of poly(methyl methacrylate) (PMMA) denture-base resins. Specimens (n=10) were fabricated from a conventional heat-activated QC-20 (Qc-) and a microwave heat-activated Acron MC (Ac-) PMMA resins. Powder/liquid ratio followed the manufacturer's instructions for the control groups (Qc-c and Ac-c) and for the copolymer groups, the resins were prepared with 5% (-5), 10% (-10), 15% (-15) and 20% (-20) acrylamide contents, according to the molecular weight ratio, respectively. The flexural strength and flexural modulus were measured by a three-point bending test. The data obtained were statistically analyzed by Kruskal-Wallis test (α=0.05) to determine significant differences between the groups. The chemical structures of the resins were characterized by the nuclear magnetic resonance spectroscopy. Thermal stabilities were determined by thermogravimetric analysis (TGA) with a heating rate of 10 °C⋅min(-1) from 35 °C to 600 °C. Control groups from both acrylic resins showed the lowest flexural strength values. Qc-15 showed significant increase in the flexural strength when compared to Qc-c (PPMMA is increased by the insertion of AAm.

  17. An accelerator-based epithermal photoneutron source for boron neutron capture therapy

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, H.E.

    1996-04-01

    Boron neutron capture therapy is an experimental binary cancer radiotherapy modality in which a boronated pharmaceutical that preferentially accumulates in malignant tissue is first administered, followed by exposing the tissue in the treatment volume to a thermal neutron field. Current usable beams are reactor-based but a viable alternative is the production of an epithermal neutron beam from an accelerator. Current literature cites various proposed accelerator-based designs, most of which are based on proton beams with beryllium or lithium targets. This dissertation examines the efficacy of a novel approach to BNCT treatments that incorporates an electron linear accelerator in the production of a photoneutron source. This source may help to resolve some of the present concerns associated with accelerator sources, including that of target cooling. The photoneutron production process is discussed as a possible alternate source of neutrons for eventual BNCT treatments for cancer. A conceptual design to produce epithermal photoneutrons by high photons (due to bremsstrahlung) impinging on deuterium targets is presented along with computational and experimental neutron production data. A clinically acceptable filtered epithermal neutron flux on the order of 10{sup 7} neutrons per second per milliampere of electron current is shown to be obtainable. Additionally, the neutron beam is modified and characterized for BNCT applications by employing two unique moderating materials (an Al/AlF{sub 3} composite and a stacked Al/Teflon design) at various incident electron energies.

  18. An accelerator-based epithermal photoneutron source for boron neutron capture therapy

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, Hannah E. [Georgia Inst. of Technology, Atlanta, GA (United States)

    1996-04-01

    Boron neutron capture therapy is an experimental binary cancer radiotherapy modality in which a boronated pharmaceutical that preferentially accumulates in malignant tissue is first administered, followed by exposing the tissue in the treatment volume to a thermal neutron field. Current usable beams are reactor-based but a viable alternative is the production of an epithermal neutron beam from an accelerator. Current literature cites various proposed accelerator-based designs, most of which are based on proton beams with beryllium or lithium targets. This dissertation examines the efficacy of a novel approach to BNCT treatments that incorporates an electron linear accelerator in the production of a photoneutron source. This source may help to resolve some of the present concerns associated with accelerator sources, including that of target cooling. The photoneutron production process is discussed as a possible alternate source of neutrons for eventual BNCT treatments for cancer. A conceptual design to produce epithermal photoneutrons by high photons (due to bremsstrahlung) impinging on deuterium targets is presented along with computational and experimental neutron production data. A clinically acceptable filtered epithermal neutron flux on the order of 107 neutrons per second per milliampere of electron current is shown to be obtainable. Additionally, the neutron beam is modified and characterized for BNCT applications by employing two unique moderating materials (an Al/AlF3 composite and a stacked Al/Teflon design) at various incident electron energies.

  19. Effect of surface treatment methods on the shear bond strength of auto-polymerized resin to thermoplastic denture base polymer

    Science.gov (United States)

    Koodaryan, Roodabeh

    2016-01-01

    PURPOSE Polyamide polymers do not provide sufficient bond strength to auto-polymerized resins for repairing fractured denture or replacing dislodged denture teeth. Limited treatment methods have been developed to improve the bond strength between auto-polymerized reline resins and polyamide denture base materials. The objective of the present study was to evaluate the effect of surface modification by acetic acid on surface characteristics and bond strength of reline resin to polyamide denture base. MATERIALS AND METHODS 84 polyamide specimens were divided into three surface treatment groups (n=28): control (N), silica-coated (S), and acid-treated (A). Two different auto-polymerized reline resins GC and Triplex resins were bonded to the samples (subgroups T and G, respectively, n=14). The specimens were subjected to shear bond strength test after they were stored in distilled water for 1 week and thermo-cycled for 5000 cycles. Data were analyzed with independent t-test, two-way analysis of variance (ANOVA), and Tukey's post hoc multiple comparison test (α=.05). RESULTS The bond strength values of A and S were significantly higher than those of N (P<.001 for both). However, statistically significant difference was not observed between group A and group S. According to the independent Student's t-test, the shear bond strength values of AT were significantly higher than those of AG (P<.001). CONCLUSION The surface treatment of polyamide denture base materials with acetic acid may be an efficient and cost-effective method for increasing the shear bond strength to auto-polymerized reline resin. PMID:28018569

  20. Distortion behavior of heat-activated acrylic denture-base resin in conventional and long, low-temperature processing methods.

    Science.gov (United States)

    Kawara, M; Komiyama, O; Kimoto, S; Kobayashi, N; Kobayashi, K; Nemoto, K

    1998-06-01

    There have been many reports on fatal distortion of heat-activated acrylic denture-base resin which is still widely used in the field of removable prosthodontics. However, these reports have failed to report quantitatively on polymerization and thermal shrinkage factors. In the present study, we attempted to verify that the shrinkage of heat-activated acrylic denture-base resin was caused mainly by thermal contraction after processing. Furthermore, we examined the degree of distortion resulting from long, low-temperature processing, and compared the results with that of the conventional method. The strain gauge and thermo-couple were embedded in a specimen at the time of resin packing. The measurement started from the beginning of processing and continued until the specimen was bench-cooled and immediately before and after it was de-flasked, as well as during seven-day immersion in water at 37 degrees C. The resin expanded when processed by the conventional method. Meanwhile, mild shrinkage, possibly polymerization shrinkage, was observed when the resin was processed by the low-temperature method. This suggested that polymerization shrinkage was compensated for by thermal expansion during processing by the conventional method. Moreover, the shrinkage strains in the period from the completion of processing to immediately after de-flasking, in both the conventional and low-temperature methods, were identical to the theoretical value of thermal shrinkage which we obtained by multiplying the linear coefficients of thermal expansion by temperature differences. The shrinkage strain in the specimen processed by the low-temperature method, measured from the end of processing to immediately after de-flasking, averaged 64% of that in the specimen processed by the conventional method. The results revealed quantitatively that the shrinkage of heat-activated acrylic denture-base resin was mainly thermal shrinkage, and demonstrated the advantage of the low-temperature method in

  1. Retention of a Flowable Composite Resin in Comparison to a Conventional Resin-Based Sealant: One-year Follow-up

    Directory of Open Access Journals (Sweden)

    N. Tadayon

    2010-03-01

    Full Text Available Objective: Long-term retention of pit and fissure sealants is crucial for their success. This clinical study evaluated the retention rate of a flowable composite resin (Filtek SupremeXT Flowable Restorative compared to a conventional resin-based sealant (Concise Light Cure White Sealant over 12 months.Materials and Methods: Forty subjects aged 6 to 9 years were included in the study. Using a half-mouth design, a total of 80 first permanent molars were sealed with conventional fissure sealant on one side of the mouth and flowable composite on the contralateralside. Clinical evaluation was performed at 3, 6, and 12 months by a single blind examiner and the retention was classified as complete retention, partial loss, or total loss.Results: For both materials, there was no total loss of sealants over 12 months. Partial loss of both materials was observed in one sealant after 3 months. After 6 months, 36 teeth sealed with conventional fissure sealant were intact compared with 37 sealed with a flowable composite, and after 12 months, 33 teeth sealed with conventional fissure sealant were intact compared with 35 that were sealed with a flowable composite. There were no statistically significant difference (P>0.05 between the two materials regarding the retention rate at each follow-up period.Conclusion: As flowable composite resulted in comparable sealant retention rates, this material could be a good choice for fissure sealant.

  2. Effect of surface roughness and adhesive system on repair potential of silorane-based resin composite

    Directory of Open Access Journals (Sweden)

    Enas H. Mobarak

    2012-07-01

    Full Text Available This study was performed to evaluate the influence of surface roughness and adhesive system on the repair strength of silorane-based resin composite. Twenty-four substrate discs from silorane-based FiltekP90 were made and stored for 24 h. Half of the discs were roughened against 320 grit SiC paper while the other half was polished against 4000 grit SiC paper. All discs were etched with phosphoric acid. Repair resin composite, FiltekP90 or FiltekZ250, was bonded to the treated surfaces using their corresponding adhesive; P90 System Adhesive (SA or Adper Scotchbond Multipurpose (SBMP ending up with four repair groups. The groups were as follows: G1: Smooth + SA + FiltekP90; G2: Roughened + SA + FiltekP90; G3: Smooth + SBMP + FiltekZ250; G4: Roughened + SBMP + FiltekZ250. Additional six unrepaired discs from each resin composite (G5 and G6 were prepared to test the cohesive strength. After 24 h, discs (n = 6/group were serially sectioned to obtain sticks (n = 30/group for microtensile bond strength (μTBS testing. Scanning electron microscopic (SEM evaluation of substrates that received different treatments as well as representative substrate-repair sticks from each group were performed. Modes of failure were also determined. Two-way ANOVA with Repeated-Measures revealed that surface treatment and repair material had no significant effect on repair bond strength of silorane-based composite material. Paired t-test showed that all repair strength values were significantly lower than the cohesive strength of FiltekP90. Adhesive failure was the predominant mode of failure which was confirmed by SEM. Surface treated FiltekP90 composite showed different textures under SEM whereas phosphoric acid did not produce clear changes. An interaction layer between SBMP adhesive and FiltekZ250 repairing composite was detected. Repair of the silorane composite was successful irrespective of the surface roughness and chemistry of the repair

  3. Evaluation of the responses of MHC class II molecule-expressing cells and macrophages to epoxy resin-based and 4-META-containing, methacrylate resin-based root canal sealers in rat subcutaneous tissue.

    Science.gov (United States)

    Yamanaka, Yusuke; Shigetani, Yoshimi; Yoshiba, Kunihiko; Kaneko, Tomoatsu; Yoshiba, Nagako; Okiji, Takashi

    2013-01-01

    Major histocompatibility complex (MHC) class II molecule-expressing cells and macrophages play a pivotal role in mediating the host tissue response to biomaterials. This study investigated the responses of these cells to epoxy resin-based and 4-META-containing, methacrylate resin-based endodontic sealers (AH Plus and MetaSEAL respectively) in rat connective tissue. Silicone tubes loaded with one of the sealers or solid silicone rods (control) were subcutaneously implanted in male Wistar rats for three time periods of 7, 14, or 28 days. Tissue specimens were immunoperoxidase-stained for MHC class II molecules and CD68 (a general macrophage marker). Results showed that AH Plus-implanted tissue displayed significantly more MHC class II-positive cells than the control at 14 and 28 days, whereas MetaSEAL-implanted tissue showed significantly more CD68-positive cells than both AH Plus-implanted tissue and the control at all time periods. It was concluded that the epoxy resin-based sealer induced the infiltration of MHC class II molecule-expressing cells, whereas 4-META-containing, methacrylate resin-based sealer elicited macrophage infiltration.

  4. A novel sustained release drug-resin complex-based microbeads of ciprofloxacin HCl.

    Science.gov (United States)

    Jain, Sunil K; Prajapati, Neeraj; Rajpoot, Kuldeep; Kumar, Amrish

    2016-12-01

    Objective A novel multiparticulate system for the gastro-mucoadhesive delivery of ciprofloxacin HCl (CFN) was developed with the help of ion-exchange resin to deal with urinary tract (UT) infections effectively. Materials and methods An optimized complex (resinate) of CFN with sodium polystyrene sulfonate USP resin was prepared and entrapped within microbeads of sodium alginate and pectin. The developed systems were evaluated for drug entrapment efficiency, percentage of mucoadhesion and in vitro release patterns in simulated gastric fluid (pH 1.2). Results and discussion The interaction of the resin complex and polycation via alginate was consequently supported the formation of polyelectrolyte complex membrane. The in vitro drug release studies demonstrate that formulation without drug-resin complex (NRB) released the drug more swiftly than formulation containing drug-resin complex (DRC). This controlled release pattern of drug, resin complex containing microbeads was owed to complexation between drug and resin. Conclusion Preliminary results from the study suggested that this drug-resin complex-entrapped microbeads can be used to incorporate other antibiotic drugs and could be effective against UT infection. Such developed formulation could be subjected to in vivo studies in future in order to prove their efficacy for such type of infections.

  5. Neutron detectors based on CMOS solid state photomultipliers

    Science.gov (United States)

    Sia, Radia; Christian, James F.; Stapels, Christopher J.; Prettyman, Thomas; Squillante, Michael R.

    2008-08-01

    CMOS solid-state photomultipliers (CMOS-SSPM) are new, potentially very inexpensive, photodetectors that have the promise of supplanting photomultiplier tubes and standard photodiodes for many nuclear radiation detection measurements using scintillator crystals. The compact size and very high gain make SSPMs attractive for use in applications where photomultiplier tubes cannot be used and standard photodiodes have insufficient sensitivity. In this effort, the use of SSPMs was investigated for the detection of neutrons with the goal of designing a detector for portable systems that has the capability of discriminating neutrons from gamma rays. The neutron scintillation signatures were measured using boron-loaded plastic scintillators. Our detector concept design incorporates a dual-scintillator design with both a neutrons sensitive organic scintillator (a boron-loaded gel) and a gamma ray sensitive inorganic scintillator (LYSO). Using this design, the gamma ray signal is suppressed and the neutron events are clearly resolved. The design was modeled to optimize the detection efficiency for both thermal and energetic neutrons. In addition, the detection of thermal neutrons in the presence of gamma rays was examined using the SSPM coupled to Cs2LiYCl6:Ce scintillator (CLYC).

  6. Shielding properties of composite materials based on epoxy resin with graphene nanoplates in the microwave frequency range

    Science.gov (United States)

    Volynets, N. I.; Bychenok, D. S.; Lyubimov, A. G.; Kuzhir, P. P.; Maksimenko, S. A.; Baturkin, S. A.; Klochkov, A. Ya.; Mastrucci, M.; Micciulla, F.; Bellucci, S.

    2016-12-01

    Analysis of the electromagnetic properties of composite materials based on epoxy resin with the addition of 0.5 wt % graphene nanoplates in the frequency range of 26-37 GHz is performed. The influence of types of epoxy resin with different viscosities and the type of solvent used (ethanol, acetone) on the electromagnetic response in this frequency range are determined. It is established that the least viscous epoxy resin, Epikote 828, and solvent ethanol are most effective for creation of a shielding covering in the microwave range. Composite materials with optimal composition provide attenuation of the electromagnetic signal at a level at least 10 dB in power for a film thickness of 1.1 mm.

  7. The STING imaging system based on using neutrons and gammas

    Energy Technology Data Exchange (ETDEWEB)

    Barker, H.B. [SubAtomic Technologies, Inc., 4929 Hidden Meadow Way, Antelope, CA 95843 (United States); Maier, M.R. [SubAtomic Technologies, Inc., 4929 Hidden Meadow Way, Antelope, CA 95843 (United States)]. E-mail: mmaier@SubatomicInc.com

    2005-04-21

    We present a novel method for three-dimensional imaging of contrast agents in different specimens using neutrons. The contrast agent is an element with a high neutron capture cross section-e.g. B{sup 10}. This element emits a {gamma}-ray-478keV in the case of B{sup 10}-upon capturing a neutron. The {gamma}-rays are then imaged with suitable tomographic imaging methods. We present a method of using a shadow mask technique for imaging which needs only one exposure and can yield depth information in addition to the two-dimensional projection.

  8. The STING imaging system based on using neutrons and gammas

    Science.gov (United States)

    Barker, H. B.; Maier, M. R.

    2005-04-01

    We present a novel method for three-dimensional imaging of contrast agents in different specimens using neutrons. The contrast agent is an element with a high neutron capture cross section—e.g. B 10. This element emits a γ-ray—478 keV in the case of B 10—upon capturing a neutron. The γ-rays are then imaged with suitable tomographic imaging methods. We present a method of using a shadow mask technique for imaging which needs only one exposure and can yield depth information in addition to the two-dimensional projection.

  9. Transparent plastic scintillators for neutron detection based on lithium salicylate

    Energy Technology Data Exchange (ETDEWEB)

    Mabe, Andrew N., E-mail: mabe2@llnl.gov; Glenn, Andrew M.; Carman, M. Leslie; Zaitseva, Natalia P.; Payne, Stephen A.

    2016-01-11

    Transparent plastic scintillators with pulse shape discrimination containing {sup 6}Li salicylate have been synthesized by bulk polymerization with a maximum {sup 6}Li loading of 0.40 wt%. Photoluminescence and scintillation responses to gamma-rays and neutrons are reported herein. Plastics containing {sup 6}Li salicylate exhibit higher light yields and permit a higher loading of {sup 6}Li as compared to previously reported plastics based on lithium 3-phenylsalicylate. However, pulse shape discrimination performance is reduced in lithium salicylate plastics due to the requirement of adding more nonaromatic monomers to the polymer matrix as compared to those based on lithium 3-phenylsalicylate. Reduction in light yield and pulse shape discrimination performance in lithium-loaded plastics as compared to pulse shape discrimination plastics without lithium is interpreted in terms of energy transfer interference by the aromatic lithium salts. - Highlights: • Plastic scintillator with 0.4% {sup 6}Li loading is reported using lithium salicylate. • Influence of lithium salts on the scintillation mechanism is explored. • New lithium-loaded scintillator provides improved light yield and reduced cost.

  10. Cumulative effect of disinfection procedures on microhardness and tridimensional stability of a poly(methyl methacrylate) denture base resin.

    Science.gov (United States)

    Sartori, Evandro Afonso; Schmidt, Caroline Bom; Mota, Eduardo Gonçalves; Hirakata, Luciana Mayumi; Shinkai, Rosemary Sadami Arai

    2008-08-01

    Microwave irradiation has been used for disinfection of dentures instead of chemical solutions; yet, its effect on resin properties after repeated procedures still is unclear. This study evaluated the cumulative effect of two disinfection methods on Knoop microhardness and tridimensional stability of a poly(methyl methacrylate) denture base resin. For the microhardness measurement, 24-resin discs received mechanical polishing and were submitted to the following treatments: (1) control (no disinfection), (2) chemical disinfection (immersion in 100ppm chloride solution for 24h), or (3) microwave disinfection (irradiation at 690 W for 6 min). Disinfection procedures were performed twice (T1, T2) with a 7-day interval. Knoop microhardness was recorded after polishing (T0) and after T1 and T2. For the dimensional stability test (measured by the adaptation of the denture bases), 36-maxillary denture bases were obtained from type III dental stone casts duplicated from a metallic master model and submitted to the disinfection treatment. Adaptation of denture bases was measured at baseline (T0) and after T1 and T2 by weighing a vinyl polysiloxane film reproducing the gap between resin base and master model. Data were analyzed by ANOVA GLM for repeated measures and Bonferroni's test, alpha = 0.05. Knoop microhardness was not modified by any disinfection procedure but decreased over time. Denture resin bases submitted to microwave disinfection had gradual increase of distortion over time, while bases immersed in chloride solution did not differ from the control group and remained dimensionally stable from T1 to T2.

  11. Thermal and Mechanical Characteristics of Polymer Composites Based on Epoxy Resin, Aluminium Nanopowders and Boric Acid

    Science.gov (United States)

    Nazarenko, O. B.; Melnikova, T. V.; Visakh, P. M.

    2016-01-01

    The epoxy polymers are characterized by low thermal stability and high flammability. Nanoparticles are considered to be effective fillers of polymer composites for improving their thermal and functional properties. In this work, the epoxy composites were prepared using epoxy resin ED-20, polyethylene polyamine as a hardener, aluminum nanopowder and boric acid fine powder as flame-retardant filler. The thermal characteristics of the obtained samples were studied using thermogravimetric analysis and differential scanning calorimetry. The mechanical characteristics of epoxy composites were also studied. It was found that an addition of all fillers enhances the thermal stability and mechanical characteristics of the epoxy composites. The best thermal stability showed the epoxy composite filled with boric acid. The highest flexural properties showed the epoxy composite based on the combination of boric acid and aluminum nanopowder.

  12. Chaos Analysis of Discharge Current Based on Tracking Test of Phenolic Resin

    Institute of Scientific and Technical Information of China (English)

    DU Boxue; ZHENG Xiaolei; DONG Dianshuai

    2009-01-01

    In tracking test,discharge is a complicated process and comparative tracking index(CTI)has wide variation.To evaluate tracking resistance,the chaos analysis of discharge current is presented based on the tracking test ofphenolic resin in accordance with IEC601 12.According to the characteristics of statistical self-similarity and complexity of discharge current,the largest Lyapunov exponent is calculated,and the 2-dimensional attractor ofdischarge current is reconstructed.Moreover,the attractors of discharge current and recurrence plots of different discharge states are reconstructed.The results indicate that the chaos attractors have different characteristics in evolutionary tracks,the topological structure and grain direction of recurrence plots show significant differences.The chaos attractor can describe the tracking process,the recurrence plot can identify the tracking state clearly,while its arithmetic is simple.

  13. New Flexible Flame Retardant Coatings Based on Siloxane Resin and Ethylene-Vinyl Chloride Copolymer

    Directory of Open Access Journals (Sweden)

    Dorota Wesolek

    2016-12-01

    Full Text Available This work presents the effectiveness of a phosphorus-containing flame retardant based on siloxane resin and ethylene-vinyl chloride copolymer as a back-coating of fabrics. The possibility of improving flame retardant efficiency of this composition by introducing fumed silica, montmorillonite, carbon nanotubes, and graphite was evaluated. The effect of each additive on the efficiency of the composition was examined separately. Flammability tests of flame retardant-coated fabrics (natural and synthetic were carried out using pyrolysis combustion flow calorimetry (PCFC, cone calorimetry, and limiting oxygen index determination. An assessment of the ignitability of upholstered furniture containing flame retardant fabric, resistance to washing, antifungal activity, and some of the utility properties of the final newly-developed flame-retardant coating was conducted.

  14. Influence of halogen irradiance on short- and long-term wear resistance of resin-based composite materials.

    LENUS (Irish Health Repository)

    Bhamra, Gurcharn S

    2009-02-01

    The Oregon Health Science University (OHSU) four-chamber oral wear simulator was used to examine the impact of halogen irradiance on the short- and long-term wear behavior of four-methacrylate resin-based composites (RBCs). The hypothesis proposed was that exacerbated wear would occur following the long-term wear of RBCs irradiated under non-optimized irradiance conditions.

  15. Designed biodegradable hydrogel structures prepared by stereolithography using poly(ethylene glycol)/poly(D,L-lactide)-based resins

    NARCIS (Netherlands)

    Seck, Tetsu M.; Melchels, Ferry P. W.; Feijen, Jan; Grijpma, Dirk W.

    2010-01-01

    Designed three-dimensional biodegradable poly(ethylene glycol)/poly(D,L-lactide) hydrogel structures were prepared for the first time by stereolithography at high resolutions. A photo-polymerisable aqueous resin comprising PDLLA-PEG-PDLLA-based macromer, visible light photo-initiator, dye and inhibi

  16. Uranium target for electron accelerator based neutron source for BNCT

    Science.gov (United States)

    Tonchev, A. P.; Harmon, F.; Collens, T. J.; Kennedy, K.; Sabourov, A.; Harker, Y. D.; Nigg, D. W.; Jones, J. L.

    2001-07-01

    Calculations of the epithermal-neutron yield of photoneutrons from a uranium-beryllium converter using a 27 MeV electron linear accelerator have been investigated. In this concept, relativistic electron beams from a 30 MeV LINAC impinge upon a small uranium sphere surrounded by a cylindrical tank of circulating heavy water (D2O) nested in a beryllium cube. The photo-fission neutron spectrum from the uranium sphere is thermalized in deuterium and beryllium, filtered and moderated in special material (AlF3/Al/LiF), and directed to the patient. The results of these calculations demonstrate that photoneutron devices could offer a promising alternative to nuclear reactors for the production of epithermal neutrons for Neutron Capture Therapy. The predicted parameter for the epithermal flux is more than 108n.cm-2.mA-1.

  17. Influence of aging solutions on wear resistance and hardness of selected resin-based dental composites.

    Science.gov (United States)

    Chladek, Grzegorz; Basa, Katarzyna; Żmudzki, Jarosław; Malara, Piotr; Nowak, Agnieszka J; Kasperski, Jacek

    2016-01-01

    The purpose of this study was to investigate the effect of different plasticizing aging solutions on wear resistance and hardness of selected universal resin-based dental composites. Three light cured (one nanofilled, two microhybride) and one hybride chemical cured composites were aged at 37 °C for 48 h in distillated water, ethyl alcohol solution or Listerine mouthwash. After aging the microhardness tests were carried out and then tribological tests were performed in the presence of aging solution at 37 °C. During wear testing coefficients of friction were determined. The maximal vertical loss in micrometers was determined with profilometer. Aging in all liquids resulted in a significant decrease in hardness of the test materials, with the largest values obtained successively in ethanol solution, mouthwash and water. The effect of the liquid was dependent on the particular material, but not the type of material (interpreted as the size of filler used). Introduction of mouthwash instead of water or ethanol solution resulted in a significant reduction in the coefficient of friction. The lowest wear resistance was registered after aging in ethanol and for the chemical cured hybrid composite, but the vertical loss was strongly material dependent. The effect of different aging solution, including commercial mouthrinse, on hardness and wear was material dependent, and cannot be deduced from their category or filler loading. There is no simple correlation between hardness of resin-based dental composites and their wear resistance, but softening of particular composites materials during aging leads to the reduction of its wear resistance.

  18. Effect of Energy Drinks on Discoloration of Silorane and Dimethacrylate-Based Composite Resins.

    Science.gov (United States)

    Ahmadizenouz, Ghazaleh; Esmaeili, Behnaz; Ahangari, Zohreh; Khafri, Soraya; Rahmani, Aghil

    2016-08-01

    This study aimed to assess the effects of two energy drinks on color change (ΔE) of two methacrylate-based and a silorane-based composite resin after one week and one month. Thirty cubic samples were fabricated from Filtek P90, Filtek Z250 and Filtek Z350XT composite resins. All the specimens were stored in distilled water at 37°C for 24 hours. Baseline color values (L*a*b*) of each specimen were measured using a spectrophotometer according to the CIEL*a*b* color system. Ten randomly selected specimens from each composite were then immersed in the two energy drinks (Hype, Red Bull) and artificial saliva (control) for one week and one month. Color was re-assessed after each storage period and ΔE values were calculated. The data were analyzed using the Kruskal Wallis and Mann-Whitney U tests. Filtek Z250 composite showed the highest ΔE irrespective of the solutions at both time points. After seven days and one month, the lowest ΔE values were observed in Filtek Z350XT and Filtek P90 composites immersed in artificial saliva, respectively. The ΔE values of Filtek Z250 and Z350XT composites induced by Red Bull and Hype energy drinks were not significantly different. Discoloration of Filtek P90 was higher in Red Bull energy drink at both time points. Prolonged immersion time in all three solutions increased ΔE values of all composites. However, the ΔE values were within the clinically acceptable range (<3.3) at both time points.

  19. Bio-Based Resin Reinforced with Flax Fiber as Thermorheologically Complex Materials

    Directory of Open Access Journals (Sweden)

    Ali Amiri

    2016-04-01

    Full Text Available With the increase in structural applications of bio-based composites, the study of long-term creep behavior of these materials turns into a significant issue. Because of their bond type and structure, natural fibers and thermoset resins exhibit nonlinear viscoelastic behavior. Time-temperature superposition (TTS provides a useful tool to overcome the challenge of the long time required to perform the tests. The TTS principle assumes that the effect of temperature and time are equivalent when considering the creep behavior, therefore creep tests performed at elevated temperatures may be converted to tests performed at longer times. In this study, flax fiber composites were processed with a novel liquid molding methacrylated epoxidized sucrose soyate (MESS resin. Frequency scans of flax/MESS composites were obtained at different temperatures and storage modulus and loss modulus were recorded and the application of horizontal and vertical shift factors to these viscoelastic functions were studied. In addition, short-term strain creep at different temperatures was measured and curves were shifted with solely horizontal, and with both horizontal and vertical shift factors. The resulting master curves were compared with a 24-h creep test and two extrapolated creep models. The findings revealed that use of both horizontal and vertical shift factors will result in a smoother master curves for loss modulus and storage modulus, while use of only horizontal shift factors for creep data provides acceptable creep strain master curves. Based on the findings of this study, flax/MESS composites can be considered as thermorheologically complex materials.

  20. Determination of surface roughness and topography of dental resin-based nanocomposites using AFM analysis.

    Science.gov (United States)

    Lainović, Tijana; Vilotić, Marko; Blažić, Larisa; Kakaš, Damir; Marković, Dubravka; Ivanišević, Aljoša

    2013-02-01

    The aim of this study was to determine surface roughness and topography of polished dental resin-based nanocomposites. Four representative dental resin-based nanocomposites were tested in the study: two nanohybrids (Filtek Z550 and Tetric EvoCeram) and two nanofilled (Filtek Ultimate Body and Filtek Ultimate Translucent); and two reference materials: one microfilled (Gradia Direct) and one microhybrid (Filtek Z250). Polymerized cylindrical specimens (4 mm x 2 mm) were polished with multi-step polishing system- Super Snap. Immediately after the polishing, topography of each specimen was examined by Veeco di CP-II Atomic Force Microscope. Specimen's surface has been scanned in 6 points in contact mode with CONT20A-CP tips. 1 Hz scan rate and 256 × 256 resolution were used to obtain topography on a 90 µm × 90 µm scanning area. Measured topography data were processed by Image Processing and Data Analysis v2.1.15 software. Following parameters were compared among specimens: average roughness and maximum peak-to-valley distance. All of the tested materials had similar average surface roughness after finishing and polishing procedure. The lowest values occurred in the material Filtek Ultimate Body, and the highest in the Filtek Z550. When interpreting maximum peak-to-valley distance the larger differences in values (up to 100%) occurred in Filtek Z550, Filtek Z250 and Filtek Ultimate Body, which is a result of the deep polishing channels and tracks. Type, size, distribution of fillers and filler loading in tested materials, didn't influence average roughness values, but had an impact on maximum peak-to-valley distance values.

  1. The influence of monomeric resin and filler characteristics on the performance of experimental resin-based composites (RBCs) derived from a commercial formulation.

    LENUS (Irish Health Repository)

    Hahnel, Sebastian

    2012-04-01

    To explore experimental RBCs derived from a successful commercially available RBC (Grandio) to investigate resin monomer blend and filler parameters (volume fraction, density and diameter) on RBC performance.

  2. Characterisation of an accelerator-based neutron source for BNCT versus beam energy

    Energy Technology Data Exchange (ETDEWEB)

    Agosteo, S. E-mail: stefano.agosteo@polimi.it; Curzio, G.; D' Errico, F.; Nath, R.; Tinti, R

    2002-01-01

    Neutron capture in {sup 10}B produces energetic alpha particles that have a high linear energy transfer in tissue. This results in higher cell killing and a higher relative biological effectiveness compared to photons. Using suitably designed boron compounds which preferentially localize in cancerous cells instead of healthy tissues, boron neutron capture therapy (BNCT) has the potential of providing a higher tumor cure rate within minimal toxicity to normal tissues. This clinical approach requires a thermal neutron source, generally a nuclear reactor, with a fluence rate sufficient to deliver tumorcidal doses within a reasonable treatment time (minutes). Thermal neutrons do not penetrate deeply in tissue, therefore BNCT is limited to lesions which are either superficial or otherwise accessible. In this work, we investigate the feasibility of an accelerator-based thermal neutron source for the BNCT of skin melanomas. The source was designed via MCNP Monte Carlo simulations of the thermalization of a fast neutron beam, generated by 7 MeV deuterons impinging on a thick target of beryllium. The neutron field was characterized at several deuteron energies (3.0-6.5 MeV) in an experimental structure installed at the Van De Graaff accelerator of the Laboratori Nazionali di Legnaro, in Italy. Thermal and epithermal neutron fluences were measured with activation techniques and fast neutron spectra were determined with superheated drop detectors (SDD). These neutron spectrometry and dosimetry studies indicated that the fast neutron dose is unacceptably high in the current design. Modifications to the current design to overcome this problem are presented.

  3. Hospital based superconducting cyclotron for neutron therapy: Medical physics perspective

    Science.gov (United States)

    Yudelev, M.; Burmeister, J.; Blosser, E.; Maughan, R. L.; Kota, C.

    2001-12-01

    The neutron therapy facility at the Gershenson Radiation Oncology Center, Harper University Hospital in Detroit has been operational since September 1991. The d(48.5)+Be beam is produced in a gantry mounted superconducting cyclotron designed and built at the National Superconducting Cyclotron Laboratory (NSCL). Measurements were performed in order to obtain the physical characteristics of the neutron beam and to collect the data necessary for treatment planning. This included profiles of the dose distribution in a water phantom, relative output factors and the design of various beam modifiers, i.e., wedges and tissue compensators. The beam was calibrated in accordance with international protocol for fast neutron dosimetry. Dosimetry and radiobiology intercomparions with three neutron therapy facilities were performed prior to clinical use. The radiation safety program was established in order to monitor and reduce the exposure levels of the personnel. The activation products were identified and the exposure in the treatment room was mapped. A comprehensive quality assurance (QA) program was developed to sustain safe and reliable operation of the unit at treatment standards comparable to those for conventional photon radiation. The program can be divided into three major parts: maintenance of the cyclotron and related hardware; QA of the neutron beam dosimetry and treatment delivery; safety and radiation protection. In addition the neutron beam is used in various non-clinical applications. Among these are the microdosimetric characterization of the beam, the effects of tissue heterogeneity on dose distribution, the development of boron neutron capture enhanced fast neutron therapy and variety of radiobiology experiments.

  4. Neutron-based techniques for detection of explosives and drugs

    CERN Document Server

    Kiraly, B; Csikai, J

    2001-01-01

    Systematic measurements were carried out on the possible use of elastically backscattered Pu-Be neutrons combined with the thermal neutron reflection method for the identification of land mines and illicit drugs via he detection of H, C, N, and O elements as their major constituents. While ur present results show that these methods are capable of indicating the anomalies in bulky materials and observation of the major elements, e termination of the exact atom fractions needs further investigation.

  5. Variety of neutron sensors based on scintillating glass waveguides

    Science.gov (United States)

    Bliss, Mary; Craig, Richard A.

    1995-04-01

    Pacific Northwest Laboratory (PNL) has fabricated cerium-activated lithium silicate glass scintillating fiber waveguide neutron sensors via a hot-downdraw process. These fibers typically have a transmission length (e-1 length) of greater than 2 meters. The underlying physics of, the properties of, and selected devices incorporating these fibers are described. These fibers constitute an enabling technology for a wide variety of neutron sensors.

  6. Pulsed neutron source based on accelerator-subcritical-assembly

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, Makoto; Noda, Akira; Iwashita, Yoshihisa; Okamoto, Hiromi; Shirai, Toshiyuki [Kyoto Univ., Uji (Japan). Inst. for Chemical Research

    1997-03-01

    A new pulsed neutron source which consists of a 300MeV proton linac and a nuclear fuel subcritical assembly is proposed. The proton linac produces pulsed spallation neutrons, which are multipied by the subcritical assembly. A prototype proton linac that accelerates protons up to 7MeV has been developed and a high energy section of a DAW structure is studied with a power model. Halo formations in high intensity beam are also being studied. (author)

  7. Si-based thin film coating on Y-TZP: Influence of deposition parameters on adhesion of resin cement

    Energy Technology Data Exchange (ETDEWEB)

    Queiroz, José Renato Cavalcanti, E-mail: joserenatocq@hotmail.com [Potiguar University, Department of Biotechnology, Natal (Brazil); Nogueira Junior, Lafayette [São Paulo State University, Department of Prosthodontics and Dental Materials, São José dos Campos (Brazil); Massi, Marcos [Federal University of São Paulo, Institute of Science and Technology, São José dos Campos (Brazil); Silva, Alecssandro de Moura; Bottino, Marco Antonio [São Paulo State University, Department of Prosthodontics and Dental Materials, São José dos Campos (Brazil); Sobrinho, Argemiro Soares da Silva [Technological Institute of Aeronautics, Department of Physics, São José dos Campos (Brazil); Özcan, Mutlu [University of Zurich, Dental Materials Unit, Center for Dental and Oral Medicine, Clinic for Fixed and Removable Prosthodontics and Dental Materials Science, Zurich (Switzerland)

    2013-10-01

    This study evaluated the influence of deposition parameters for Si-based thin films using magnetron sputtering for coating zirconia and subsequent adhesion of resin cement. Zirconia ceramic blocks were randomly divided into 8 groups and specimens were either ground finished and polished or conditioned using air-abrasion with alumina particles coated with silica. In the remaining groups, the polished specimens were coated with Si-based film coating with argon/oxygen magnetron discharge at 8:1 or 20:1 flux. In one group, Si-based film coating was performed on air-abraded surfaces. After application of bonding agent, resin cement was bonded. Profilometry, goniometry, Energy Dispersive X-ray Spectroscopy and Rutherford Backscattering Spectroscopy analysis were performed on the conditioned zirconia surfaces. Adhesion of resin cement to zirconia was tested using shear bond test and debonded surfaces were examined using Scanning Electron Microscopy. Si-based film coating applied on air-abraded rough zirconia surfaces increased the adhesion of the resin cement (22.78 ± 5.2 MPa) compared to those of other methods (0–14.62 MPa) (p = 0.05). Mixed type of failures were more frequent in Si film coated groups on either polished or air-abraded groups. Si-based thin films increased wettability compared to the control group but did not change the roughness, considering the parameters evaluated. Deposition parameters of Si-based thin film and after application of air-abrasion influenced the initial adhesion of resin cement to zirconia.

  8. Neutron spectral fluence measurements using a Bonner sphere spectrometer in the development of the iBNCT accelerator-based neutron source.

    Science.gov (United States)

    Masuda, Akihiko; Matsumoto, Tetsuro; Takada, Kenta; Onishi, Takahiro; Kotaki, Kohei; Sugimoto, Hidenori; Kumada, Hiroaki; Harano, Hideki; Sakae, Takeji

    2017-09-01

    The neutron spectral fluence of an accelerator-based neutron source facility for boron neutron capture therapy (BNCT) based on a proton linac and a beryllium target was evaluated by the unfolding method using a Bonner sphere spectrometer (BSS). A (3)He-proportional-counter-based BSS was used with weak beam during the development of the facility. The measured epithermal neutron spectra were consistent with calculations. The epithermal neutron intensity at the beam port was estimated and the results gave a numerical target for the enhancement of the proton beam intensity and will be used as reference data for measurements performed after the completion of the facility. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Do Red-cockaded Woodpeckers Select Cavity Trees Based on Chemical Composition of Pine Resin?

    Science.gov (United States)

    Richard N. Conner; Robert H. Johnson; D. Craig Rudolph; Daniel Saenz

    2003-01-01

    We examined resin chemistry of loblolly (Pinus taeda) and shortleaf (P. echinata) pines selected as cavity trees by Red-cockaded Woodpeckers (Picoides borealis) in eastern Texas. We sampled resin from (1) pines selected by Red-cockaded Woodpeckers that contained naturally excavated active cavities, (2) pines...

  10. Influence of matrix and filler fraction on biofilm formation on the surface of experimental resin-based composites.

    Science.gov (United States)

    Ionescu, Andrei; Brambilla, Eugenio; Wastl, Daniel S; Giessibl, Franz J; Cazzaniga, Gloria; Schneider-Feyrer, Sibylle; Hahnel, Sebastian

    2015-01-01

    The aim of this study was to investigate the impact of resin matrix chemistry and filler fraction on biofilm formation on the surface of experimental resin-based composites (RBCs). Specimens were prepared from eight experimental RBC formulations differing in resin matrix blend (BisGMA/TEGDMA in a 7:3 wt% ratio or UDMA/aliphatic dimethacrylate in a 1:1 wt% ratio) and filler fraction (no fillers; 65 wt% dental glass with an average diameter of 7 or 0.7 µm or 65 wt% SiO2 with an average diameter of 20 nm). Surface roughness, surface free energy, and chemical surface composition were determined; surface topography was visualized using atomic force microscopy. Biofilm formation was simulated under continuous flow conditions for a 48 h period using a monospecies Streptococcus mutans and a multispecies biofilm model. In the monospecies biofilm model, the impact of the filler fraction overruled the influence of the resin matrix, indicating lowest biofilm formation on RBCs with nano-scaled filler particles and those manufactured from the neat resin blends. The multispecies model suggested a more pronounced effect of the resin matrix blend, as significantly higher biofilm formation was identified on RBCs with a UDMA/dimethacrylate matrix blend than on those including a BisGMA/TEGDMA matrix blend but analogous filler fractions. Although significant differences in surface properties between the various materials were identified, correlations between the surface properties and biofilm formation were poor, which highlights the relevance of surface topography and chemistry. These results may help to tailor novel RBC formulations which feature reduced biofilm formation on their surface.

  11. Water sorption characteristics of light-cured dental resins and composites based on Bis-EMA/PCDMA.

    Science.gov (United States)

    Sideridou, Irini; Achilias, Dimitris S; Spyroudi, Chrysa; Karabela, Maria

    2004-01-01

    The water uptake characteristics of resins and composites based on an ethoxylated bisphenol A glycol dimethacrylate (Bis-EMA) and a polycarbonate dimethacrylate (PCDMA) were studied in detail. Polydimethacrylate resins were prepared by photopolymerization of the neat monomers and mixtures of them with various weight ratios, using the camphoroquinone/N,N-dimethylaminoethyl methacrylate system as initiator, while the composites were prepared from the light-curing of commercial samples (Sculpt-It and Alert). Water sorption/desorption was examined both in equilibrium and dynamic conditions in two adjacent sorption-desorption cycles. The equilibrium water uptake from all resins was very small with a trend to increase as the amount of PCDMA was increased. The inverse effect was observed in the solubility values. The composites studied exhibited also very low water uptake values in comparison to other composite materials reported in the literature. It was also observed that the equilibrium uptake decreased with increasing filler loading. Slightly larger equilibrium water uptake and much smaller solubility values were obtained during the second sorption-desorption cycle in comparison to the first one. Concerning the sorption rate data, it was observed that the resin materials followed Fickian diffusion during almost the whole sorption or desorption curve, while the composites showed this behavior until only M(t)/M( infinity ) congruent with 0.5. The diffusion coefficients calculated for the resins were larger than those of the composites and always higher during desorption compared to sorption. The values of the diffusion coefficients for both resins and composites were in the same order of magnitude with the values of the corresponding materials reported in the literature.

  12. Block-Based Compressed Sensing for Neutron Radiation Image Using WDFB

    Directory of Open Access Journals (Sweden)

    Wei Jin

    2015-01-01

    Full Text Available An ideal compression method for neutron radiation image should have high compression ratio while keeping more details of the original image. Compressed sensing (CS, which can break through the restrictions of sampling theorem, is likely to offer an efficient compression scheme for the neutron radiation image. Combining wavelet transform with directional filter banks, a novel nonredundant multiscale geometry analysis transform named Wavelet Directional Filter Banks (WDFB is constructed and applied to represent neutron radiation image sparsely. Then, the block-based CS technique is introduced and a high performance CS scheme for neutron radiation image is proposed. By performing two-step iterative shrinkage algorithm the problem of L1 norm minimization is solved to reconstruct neutron radiation image from random measurements. The experiment results demonstrate that the scheme not only improves the quality of reconstructed image obviously but also retains more details of original image.

  13. Characterisation of an accelerator-based neutron source for BNCT versus beam energy

    CERN Document Server

    Agosteo, S; D'Errico, F; Nath, R; Tinti, R

    2002-01-01

    Neutron capture in sup 1 sup 0 B produces energetic alpha particles that have a high linear energy transfer in tissue. This results in higher cell killing and a higher relative biological effectiveness compared to photons. Using suitably designed boron compounds which preferentially localize in cancerous cells instead of healthy tissues, boron neutron capture therapy (BNCT) has the potential of providing a higher tumor cure rate within minimal toxicity to normal tissues. This clinical approach requires a thermal neutron source, generally a nuclear reactor, with a fluence rate sufficient to deliver tumorcidal doses within a reasonable treatment time (minutes). Thermal neutrons do not penetrate deeply in tissue, therefore BNCT is limited to lesions which are either superficial or otherwise accessible. In this work, we investigate the feasibility of an accelerator-based thermal neutron source for the BNCT of skin melanomas. The source was designed via MCNP Monte Carlo simulations of the thermalization of a fast ...

  14. A research plan based on high intensity proton accelerator Neutron Science Research Center

    Energy Technology Data Exchange (ETDEWEB)

    Mizumoto, Motoharu [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    1997-03-01

    A plan called Neutron Science Research Center (NSRC) has been proposed in JAERI. The center is a complex composed of research facilities based on a proton linac with an energy of 1.5GeV and an average current of 10mA. The research facilities will consist of Thermal/Cold Neutron Facility, Neutron Irradiation Facility, Neutron Physics Facility, OMEGA/Nuclear Energy Facility, Spallation RI Beam Facility, Meson/Muon Facility and Medium Energy Experiment Facility, where high intensity proton beam and secondary particle beams such as neutron, pion, muon and unstable radio isotope (RI) beams generated from the proton beam will be utilized for innovative researches in the fields on nuclear engineering and basic sciences. (author)

  15. Design and characterization of an SRAM-based neutron detector for particle therapy

    Energy Technology Data Exchange (ETDEWEB)

    Ytre-Hauge, Kristian S., E-mail: kristian.ytre-hauge@uib.no [Department of Physics and Technology, University of Bergen, Allegaten 55, 5007 Bergen (Norway); Velure, Arild; Larsen, Eivind F. [Department of Physics and Technology, University of Bergen, Allegaten 55, 5007 Bergen (Norway); Stokkevåg, Camilla H. [Department of Medical Physics and Oncology, Haukeland University Hospital, 5021 Bergen (Norway); Röhrich, Dieter [Department of Physics and Technology, University of Bergen, Allegaten 55, 5007 Bergen (Norway); Brekke, Njål; Odland, Odd Harald [Department of Medical Physics and Oncology, Haukeland University Hospital, 5021 Bergen (Norway)

    2015-12-21

    A neutron detector based on registration of radiation effects in Static Random Access Memories (SRAMs) has been developed at the University of Bergen for applications in particle therapy. Nine different SRAMs were tested and a 16 Mibit SRAM from Cypress was chosen for the final detector. The SRAMs were irradiated in beam lines at PTB Braunschweig, the Oslo Cyclotron Laboratory, The Svedberg Laboratory, The Institute for Energy Technology (IFE, Kjeller) and the CERN-EU high-energy reference field. The results from the measurements demonstrate the feasibility of using the selected SRAMs for neutron detection. The results indicate low or no sensitivity to thermal neutrons while the cross section for fast neutrons increases with neutron energy before reaching a more stable level at energies of several tenths of MeV.

  16. A neutron spectrometer based on temperature variations in superheated drop compositions

    CERN Document Server

    Apfel, R E

    2002-01-01

    The response of superheated drop detectors (SDDs) to neutron radiation varies in a self-consistent manner with variations in temperature and pressure, making such compositions suitable for neutron spectrometry. The advantage of this approach is that the response functions of candidate materials versus energy as the temperature or pressure is varied are nested and have distinct thresholds, with no thermal neutron response. These characteristics permit unfolding without the uncertainties associated with other spectrometry techniques, where multiple solutions are possible, thus requiring an initial guess of the spectrum. A spectrometer was developed based on the well-established technology for acoustic sensing of bubble events interfaced with a proportional-integral-derivative temperature controller. The active monitor for neutrons, called REMbrandt sup T sup M , was used as the platform for controlling temperature on a SDD probe and for data acquisition, thereby automating the process of measuring the neutron e...

  17. Multipurpose applications of the accelerator-based neutron source[1pt] GENEPI2

    Science.gov (United States)

    Villa, F.; Baylac, M.; Billebaud, A.; Boge, P.; Cabanel, T.; Labussière, E.; Méplan, O.; Rey, S.

    2016-11-01

    GENEPI2 (GEnérateur de NEutrons Pulsé Intense) is an accelerator-based neutron source operating at LPSC laboratory in Grenoble (France). The neutrons are produced at 2.5MeV or 14.2MeV trough fusion reactions. GENEPI2 specifications allow performing efficiently accelerated irradiation tests of integrated circuits. This facility can also be operated to test and calibrate different types of detectors. This paper will describe the facility and its performances. Then, measurements of the neutron production will be presented as well as different types of experiments and irradiations. Finally, we describe upgrades undertaken to increase the neutron flux and optimize the facility for multiple applications.

  18. Application of neutron activation techniques and x-ray energy dispersion spectrometry, in analysis of metallic traces adsorbed by chelex-100 resin; Ativacao das tecnicas de ativacao neutronica e espectrometria por dispersao de onda e de energia de raios X, na analise de tracos metalicos adsorvidos pela resina chelex-100

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes, Jair C.; Amaral, Angela M.; Magalhaes, Jesus C.; Pereira, Jose S.J.; Silva, Juliana B. da; Auler, Lucia M.L.A. [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN), Belo Horizonte, MG (Brazil)]. E-mail: jcf@urano.cdtn.br

    2000-07-01

    In this work, the authors have investigated optimal conditions of adsorption for several ion metallic groups (cations of heavy metals and transition metals, oxyanions metallics and metalloids and cations of rare earths), as traces (ppb), withdrawn and in mixture of groups, by chelex-100 resin. The experiments have been developed by bath techniques in ammonium acetate tamponade solution 40 mM pH 5,52 content 0,5 g of chelex-100 resin. After magnetic agitation for two hours, resins were dried and submitted to X-ray energy dispersion spectrometry, x-ray fluorescence spectrometry and neutron activation analysis. The results have demonstrated that chelex-100 resin adsorb quantitatively transition element groups and rare earth groups in two cases (withdrawn and simultaneously adsorption)

  19. Fracture resistance of computer-aided design/computer-aided manufacturing-generated composite resin-based molar crowns.

    Science.gov (United States)

    Harada, Akio; Nakamura, Keisuke; Kanno, Taro; Inagaki, Ryoichi; Örtengren, Ulf; Niwano, Yoshimi; Sasaki, Keiichi; Egusa, Hiroshi

    2015-04-01

    The aim of this study was to investigate whether different fabrication processes, such as the computer-aided design/computer-aided manufacturing (CAD/CAM) system or the manual build-up technique, affect the fracture resistance of composite resin-based crowns. Lava Ultimate (LU), Estenia C&B (EC&B), and lithium disilicate glass-ceramic IPS e.max press (EMP) were used. Four types of molar crowns were fabricated: CAD/CAM-generated composite resin-based crowns (LU crowns); manually built-up monolayer composite resin-based crowns (EC&B-monolayer crowns); manually built-up layered composite resin-based crowns (EC&B-layered crowns); and EMP crowns. Each type of crown was cemented to dies and the fracture resistance was tested. EC&B-layered crowns showed significantly lower fracture resistance compared with LU and EMP crowns, although there was no significant difference in flexural strength or fracture toughness between LU and EC&B materials. Micro-computed tomography and fractographic analysis showed that decreased strength probably resulted from internal voids in the EC&B-layered crowns introduced by the layering process. There was no significant difference in fracture resistance among LU, EC&B-monolayer, and EMP crowns. Both types of composite resin-based crowns showed fracture loads of >2000 N, which is higher than the molar bite force. Therefore, CAD/CAM-generated crowns, without internal defects, may be applied to molar regions with sufficient fracture resistance. © 2015 Eur J Oral Sci.

  20. Degree of conversion and leached monomers of urethane dimethacrylate-hydroxypropyl methacrylate-based dental resin systems.

    Science.gov (United States)

    Zhang, Meng; Puska, Mervi A; Botelho, Michael G; Säilynoja, Eija S; Matinlinna, Jukka P

    2016-01-01

    The degree of conversion (DC) and monomer leaching of three experimental urethane dimethacrylate (UEDMA)-hydroxypropyl methacrylate (HPMA)-based resin systems were studied. Three experimental resins (E1: 70.6 wt% UEDMA + 27.4 wt% HPMA, E2: 80.6 wt% UEDMA + 17.4 wt% HPMA, E3: 90.6 wt% UEDMA + 7.4 wt% HPMA) and one control resin [C: 70.6 wt% bis-phenol A glycidyl methacrylate (bis-GMA) + 27.4 wt% methyl methacrylate (MMA)] were prepared. For the DC test, cylindrical specimens [1.5 mm (h) × 6 mm (d)] were scanned with an ATR-FTIR instrument before and after light-curing (n = 5). For the monomer leaching test, block-shaped specimens [5.67 mm (l) × 2.00 mm (w) × 2.00 mm (h)] were light-cured (n = 6), stored in a 75% ethanol:water solution for 3 days, and then analyzed with HPLC. The UEDMA-HPMA-based experimental groups showed higher DC (62-78%) than the bis-GMA-MMA-based control group (58-66%), and the DC decreased as the UEDMA content increased (P < 0.05). Amongst the four groups, E3 exhibited the lowest leaching of both mono methacrylate (0.1% HPMA) and dimethacrylate (<0.043% UEDMA) monomers after 30 or 40 s of curing. The UEDMA-HPMA-based resins, therefore, exhibited higher DC and less monomer leaching compared to the bis-GMA-MMA-based resin. (J Oral Sci 58, 15-22, 2016).

  1. ETHERNES: A new design of radionuclide source-based thermal neutron facility with large homogeneity area.

    Science.gov (United States)

    Bedogni, R; Sacco, D; Gómez-Ros, J M; Lorenzoli, M; Gentile, A; Buonomo, B; Pola, A; Introini, M V; Bortot, D; Domingo, C

    2016-01-01

    A new thermal neutron irradiation facility based on an (241)Am-Be source embedded in a polyethylene moderator has been designed, and is called ETHERNES (Extended THERmal NEutron Source). The facility shows a large irradiation cavity (45 cm × 45 cm square section, 63 cm in height), which is separated from the source by means of a polyethylene sphere acting as shadowing object. Taking advantage of multiple scattering of neutrons with the walls of this cavity, the moderation process is especially effective and allows obtaining useful thermal fluence rates from 550 to 800 cm(-2) s(-1) with a source having nominal emission rate 5.7×10(6) s(-1). Irradiation planes parallel to the cavity bottom have been identified. The fluence rate across a given plane is as uniform as 3% (or better) in a disk with 30 cm (or higher) diameter. In practice, the value of thermal fluence rate simply depends on the height from the cavity bottom. The thermal neutron spectral fraction ranges from 77% up to 89%, depending on the irradiation plane. The angular distribution of thermal neutrons is roughly isotropic, with a slight prevalence of directions from bottom to top of the cavity. The mentioned characteristics are expected to be attractive for the scientific community involved in neutron metrology, neutron dosimetry and neutron detector testing.

  2. A design study for an accelerator-based epithermal neutron beam for BNCT.

    Science.gov (United States)

    Allen, D A; Beynon, T D

    1995-05-01

    An achievable design concept for a boron neutron capture therapy (BNCT) facility, based on a high-current, low-energy proton accelerator, is described. Neutrons are produced within a thick natural lithium target, under bombardment from protons with an initial energy between 2.5 and 3.0 MeV. The proton current will be up to 10 mA. After gamma-ray filtering, the neutrons are partially moderated to epithermal energies within a heavy-water moderator, poisoned with 6Li to remove thermal neutrons. Monte Carlo modelling has been used to predict system performance in terms of neutron fluence rate and neutron and gamma-ray dose at the patient position. The relationship between the system performance and key parameters, such as proton energy, moderator depth and 6Li concentration, has been investigated. With a proton current of 10 mA, the facility is capable of providing a therapy beam with a useful neutron fluence rate of 10(9) cm-2 s-1 and a neutron dose per unit fluence of less than 6 x 10(-13) Gy cm2, with a gamma-ray contamination of the therapy beam of about 10(-13) Gy cm2.

  3. Resin-Dipped Boron Coating——Production Method for Sensitive Layer of Neutron Detectors%浸酯涂硼——中子探测器灵敏层制作方法

    Institute of Scientific and Technical Information of China (English)

    陈国云; 魏志勇; 黄福成; 辛勇; 朱立

    2013-01-01

    Two economic and practical resin-dipped boron coating methods for neutron detectors were presented, whose names are dip coated boron deposition (DCBD) and hand painted boron deposition (HPBD). Several experiments on stainless steel sheet show that the minimum of the resin-boron ratio A in DCBD is 5. 0, while the best value of A in HPBD is 0. 2. The better method is that the mixture drops on the coated surface firstly, and then the boron powder is scattered by hand. Finally, a cylindrical boron-lined proportional counter made by using this method was irradiated by a standard Am-Be neutron source, and the output pulses were measured. After the proportional counter was wrapped by PE tubes with different thickness, the neutron spectra of the Am-Be source were measured. By analyzing the parameters of the neutron spectra, it is found that these two manufacture crafts have a simple and feasible process, which would provide the coworkers with meaningful reference.%介绍了两种价廉、实用的中子探测器浸酯涂硼方法——浸没涂硼和手工刷涂,并给出涂抹细节.对不锈钢片的多次实验表明:浸没涂硼时脂硼比λ的最小值为5.0;手工刷涂时λ的最佳值为0.2,最佳方法是先在待涂面上滴混合液,再撒上硼粉刷涂.采用该方法研制一圆柱形硼衬正比计数管,用标准Am-Be中子源辐照测得了其输出脉冲;用不同厚度聚乙烯管包裹后测得了Am-Be源的中子谱.对中子谱参数的分析表明,两种硼膜制作过程简单、方法可行,为业内人员提供了很有意义的参考.

  4. A wide dynamics neutron monitor with BF3 and logarithmic amplifier based front-end electronics

    OpenAIRE

    2010-01-01

    In this paper a wide dynamics neutron monitor based on BF3 neutron detector is described. The detector is used in current mode, and a front-end electronics based on a logarithmic amplifier is used in order to have a measurement capability ranging over many decades. The system has been calibrated at Polytechnic of Milan, CESNEF, with an AmBe neutron source, and has been tested in a pulsed field at the PUNITA facility at JRC, Ispra. The detector has achieved a dynamics ranging ov...

  5. Influence of ionizing radiation on the mechanical properties of BisGMA/TEGDMA based experimental resin

    Science.gov (United States)

    LMP, Campos; Boaro, LC; LKG, Santos; Parra, DF; Lugão, AB

    2015-10-01

    Dental restorative composites are activated by visible light and the polymerization process, known as direct technique, is initiated by absorbing light in a specific wavelength range (450-500 nm). However this technique presented some disadvantages. If light is not inserted correctly, layers uncured can cause countless damage to restoration, especially with regard to mechanical properties. A clinical alternative used to reduce the shortcomings of direct application is the use of composite resins for indirect application. These composites are adaptations of resins prepared for direct use, with differences mainly in the healing process. Besides the traditional photoactivation, indirect application composites may be submitted to particular curing conditions, such as a slow curing rate, heating, vacuum, and inert-gas pressure leading to an oxygen-free environment. However few studies have been conducted on the process of post-curing by ionizing radiation at low doses. On this sense the purpose of this study was to evaluate possible interactions of ionizing radiation in the post-curing process of the experimental composites based on BisGMA/TEGDMA filled with silica Aerosil OX-50 silanized. Characterization of the experimental composites was performed by thermogravimetry analysis, infrared spectroscopy, elastic modulus and flexural strength. Statistical analysis of results was calculated by one-way ANOVA/Tukey's test. Cross-linking of the polymeric matrix caused by ionizing radiation, influenced the thermal stability of irradiated specimens. FTIR analysis showed that the ionizing radiation induced a post-cure reaction in the specimens. The irradiation dose influenced directly the mechanical properties that showed a strong positive correlation between flexural strength and irradiation and between modulus strength and irradiation.

  6. Novel bioactive polyester scaffolds prepared from unsaturated resins based on isosorbide and succinic acid

    Energy Technology Data Exchange (ETDEWEB)

    Śmiga-Matuszowicz, Monika, E-mail: monika.smiga-matuszowicz@polsl.pl [Silesian University of Technology, Department of Physical Chemistry and Technology of Polymers, M. Strzody Street 9, 44-100 Gliwice (Poland); Janicki, Bartosz; Jaszcz, Katarzyna; Łukaszczyk, Jan [Silesian University of Technology, Department of Physical Chemistry and Technology of Polymers, M. Strzody Street 9, 44-100 Gliwice (Poland); Kaczmarek, Marcin [Silesian University of Technology, Department of Biomaterials and Medical Devices Engineering, de Gaulle' a Street 66, 41-800 Zabrze (Poland); Lesiak, Marta; Sieroń, Aleksander L. [Medical University of Silesia, Department of General and Molecular Biology and Genetics, Medyków Street 18, 40-752 Katowice (Poland); Simka, Wojciech [Silesian University of Technology, Department of Chemistry, Inorganic Technology and Fuels, B. Krzywoustego Street 6, 44-100 Gliwice (Poland); Mierzwiński, Maciej; Kusz, Damian [Medical University of Silesia, Department of Orthopedics and Traumatology, Ziołowa Street 45, 40-635 Katowice (Poland)

    2014-12-01

    In this study new biodegradable materials obtained by crosslinking poly(3-allyloxy-1,2-propylene succinate) (PSAGE) with oligo(isosorbide maleate) (OMIS) and small amount of methyl methacrylate were investigated. The porous scaffolds were obtained in the presence of a foaming system consisted of calcium carbonate/carboxylic acid mixture, creating in situ porous structure during crosslinking of liquid formulations. The maximum crosslinking temperature and setting time, the cured porous materials morphology as well as the effect of their porosity on mechanical properties and hydrolytic degradation process were evaluated. It was found that the kind of carboxylic acid used in the foaming system influenced compressive strength and compressive modulus of porous scaffolds. The MTS cytotoxicity assay was carried out for OMIS using hFOB1.19 cell line. OMIS resin was found to be non-toxic in wide range of concentrations. On the ground of scanning electron microscopy (SEM) observations and energy X-ray dispersive analysis (EDX) it was found that hydroxyapatite (HA) formation at the scaffolds surfaces within short period of soaking in phosphate buffer solution occurs. After 3 h immersion a compact layer of HA was observed at the surface of the samples. The obtained results suggest potential applicability of resulted new porous crosslinked polymeric materials as temporary bone void fillers. - Highlights: • Isosorbide-based resin was used as a component of biodegradable scaffolds. • CAC/carboxylic acid system was proven as facile method to obtain porous scaffolds. • Porous scaffolds displayed the formation of hydroxyapatite at their surfaces.

  7. High yield neutron generator based on a high-current gasdynamic electron cyclotron resonance ion source

    Energy Technology Data Exchange (ETDEWEB)

    Skalyga, V.; Sidorov, A. [Institute of Applied Physics of Russian Academy of Sciences, 46 Ulyanova St., Nizhny Novgorod (Russian Federation); Lobachevsky State University of Nizhny Novgorod (UNN), 23 Gagarina St., Nizhny Novgorod (Russian Federation); Izotov, I.; Golubev, S.; Razin, S. [Institute of Applied Physics of Russian Academy of Sciences, 46 Ulyanova St., Nizhny Novgorod (Russian Federation); Strelkov, A. [Joint Institute for Nuclear Research, Joliot-Curie 6, 141980 Dubna, Moscow Region (Russian Federation); Tarvainen, O.; Koivisto, H.; Kalvas, T. [Department of Physics, University of Jyväskylä, Jyväskylä (Finland)

    2015-09-07

    In present paper, an approach for high yield compact D-D neutron generator based on a high current gasdynamic electron cyclotron resonance ion source is suggested. Results on dense pulsed deuteron beam production with current up to 500 mA and current density up to 750 mA/cm{sup 2} are demonstrated. Neutron yield from D{sub 2}O and TiD{sub 2} targets was measured in case of its bombardment by pulsed 300 mA D{sup +} beam with 45 keV energy. Neutron yield density at target surface of 10{sup 9} s{sup −1} cm{sup −2} was detected with a system of two {sup 3}He proportional counters. Estimations based on obtained experimental results show that neutron yield from a high quality TiD{sub 2} target bombarded by D{sup +} beam demonstrated in present work accelerated to 100 keV could reach 6 × 10{sup 10} s{sup −1} cm{sup −2}. It is discussed that compact neutron generator with such characteristics could be perspective for a number of applications like boron neutron capture therapy, security systems based on neutron scanning, and neutronography.

  8. New detectors of neutron, gamma- and X-radiations

    CERN Document Server

    Lobanov, N S

    2002-01-01

    Paper presents new detectors to record absorbed doses of neutron, gamma- and X-ray radiations within 0-1500 Mrad range. DBF dosimeter is based on dibutyl phthalate. EDS dosimeter is based on epoxy (epoxide) resin, while SD 5-40 detector is based on a mixture of dibutyl phthalate and epoxy resin. Paper describes experimental techniques to calibrate and interprets the measurement results of absorbed doses for all detectors. All three detectors cover 0-30000 Mrad measured does range. The accuracy of measurements is +- 10% independent (practically) of irradiation dose rates within 20-2000 rad/s limits under 20-80 deg C temperature

  9. Mechanical properties and fire retardancy of bidirectional reinforced composite based on biodegradable starch resin and basalt fibres

    Directory of Open Access Journals (Sweden)

    2008-11-01

    Full Text Available Environmental problems caused by extensive use of polymeric materials arise mainly due to lack of landfill space and depletion of finite natural resources of fossil raw materials, such as petroleum or natural gas. The substitution of synthetic petroleum-based resins with natural biodegradable resins appears to be one appropriate measure to remedy the above-mentioned situation. This study presents the development of a composite that uses environmentally degradable starch-based resin as matrix and basalt fibre plain fabric as reinforcement. Prepreg sheets were manufactured by means of a modified doctor blade system and a hot power press. The sheets were used to manufacture bidirectional-reinforced specimens with fibre volume contents ranging from 33 to 61%. Specimens were tested for tensile and flexural strength, and exhibited values of up to 373 and 122 MPa, respectively. Through application of silane coupling agents to the reinforcement fibres, the flexural composite properties were subsequently improved by as much as 38%. Finally, in order to enhance the fire retardancy and hence the applicability of the composite, fire retardants were applied to the resin, and their effectiveness was tested by means of flame rating (according to UL 94 and thermogravimetric analysis (TGA, respectively.

  10. Microscale characterisation of stochastically reconstructed carbon fiber-based Gas Diffusion Layers; effects of anisotropy and resin content

    Science.gov (United States)

    Yiotis, Andreas G.; Kainourgiakis, Michael E.; Charalambopoulou, Georgia C.; Stubos, Athanassios K.

    2016-07-01

    A novel process-based methodology is proposed for the stochastic reconstruction and accurate characterisation of Carbon fiber-based matrices, which are commonly used as Gas Diffusion Layers in Proton Exchange Membrane Fuel Cells. The modeling approach is efficiently complementing standard methods used for the description of the anisotropic deposition of carbon fibers, with a rigorous model simulating the spatial distribution of the graphitized resin that is typically used to enhance the structural properties and thermal/electrical conductivities of the composite Gas Diffusion Layer materials. The model uses as input typical pore and continuum scale properties (average porosity, fiber diameter, resin content and anisotropy) of such composites, which are obtained from X-ray computed microtomography measurements on commercially available carbon papers. This information is then used for the digital reconstruction of realistic composite fibrous matrices. By solving the corresponding conservation equations at the microscale in the obtained digital domains, their effective transport properties, such as Darcy permeabilities, effective diffusivities, thermal/electrical conductivities and void tortuosity, are determined focusing primarily on the effects of medium anisotropy and resin content. The calculated properties are matching very well with those of Toray carbon papers for reasonable values of the model parameters that control the anisotropy of the fibrous skeleton and the materials resin content.

  11. Neutron Source Facility Training Simulator Based on EPICS

    Energy Technology Data Exchange (ETDEWEB)

    Park, Young Soo; Wei, Thomas Y.; Vilim, Richard B.; Grelle, Austin L.; Dworzanski, Pawel L.; Gohar, Yousry

    2015-01-01

    A plant operator training simulator is developed for training the plant operators as well as for design verification of plant control system (PCS) and plant protection system (PPS) for the Kharkov Institute of Physics and Technology Neutron Source Facility. The simulator provides the operator interface for the whole plant including the sub-critical assembly coolant loop, target coolant loop, secondary coolant loop, and other facility systems. The operator interface is implemented based on Experimental Physics and Industrial Control System (EPICS), which is a comprehensive software development platform for distributed control systems. Since its development at Argonne National Laboratory, it has been widely adopted in the experimental physics community, e.g. for control of accelerator facilities. This work is the first implementation for a nuclear facility. The main parts of the operator interface are the plant control panel and plant protection panel. The development involved implementation of process variable database, sequence logic, and graphical user interface (GUI) for the PCS and PPS utilizing EPICS and related software tools, e.g. sequencer for sequence logic, and control system studio (CSS-BOY) for graphical use interface. For functional verification of the PCS and PPS, a plant model is interfaced, which is a physics-based model of the facility coolant loops implemented as a numerical computer code. The training simulator is tested and demonstrated its effectiveness in various plant operation sequences, e.g. start-up, shut-down, maintenance, and refueling. It was also tested for verification of the plant protection system under various trip conditions.

  12. Preliminary energy-filtering neutron imaging with time-of-flight method on PKUNIFTY: A compact accelerator based neutron imaging facility at Peking University

    Science.gov (United States)

    Wang, Hu; Zou, Yubin; Wen, Weiwei; Lu, Yuanrong; Guo, Zhiyu

    2016-07-01

    Peking University Neutron Imaging Facility (PKUNIFTY) works on an accelerator-based neutron source with a repetition period of 10 ms and pulse duration of 0.4 ms, which has a rather low Cd ratio. To improve the effective Cd ratio and thus improve the detection capability of the facility, energy-filtering neutron imaging was realized with the intensified CCD camera and time-of-flight (TOF) method. Time structure of the pulsed neutron source was firstly simulated with Geant4, and the simulation result was evaluated with experiment. Both simulation and experiment results indicated that fast neutrons and epithermal neutrons were concentrated in the first 0.8 ms of each pulse period; meanwhile in the period of 0.8-2.0 ms only thermal neutrons existed. Based on this result, neutron images with and without energy filtering were acquired respectively, and it showed that detection capability of PKUNIFTY was improved with setting the exposure interval as 0.8-2.0 ms, especially for materials with strong moderating capability.

  13. Preliminary energy-filtering neutron imaging with time-of-flight method on PKUNIFTY: A compact accelerator based neutron imaging facility at Peking University

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Hu; Zou, Yubin, E-mail: zouyubin@pku.edu.cn; Wen, Weiwei; Lu, Yuanrong; Guo, Zhiyu

    2016-07-01

    Peking University Neutron Imaging Facility (PKUNIFTY) works on an accelerator–based neutron source with a repetition period of 10 ms and pulse duration of 0.4 ms, which has a rather low Cd ratio. To improve the effective Cd ratio and thus improve the detection capability of the facility, energy-filtering neutron imaging was realized with the intensified CCD camera and time-of-flight (TOF) method. Time structure of the pulsed neutron source was firstly simulated with Geant4, and the simulation result was evaluated with experiment. Both simulation and experiment results indicated that fast neutrons and epithermal neutrons were concentrated in the first 0.8 ms of each pulse period; meanwhile in the period of 0.8–2.0 ms only thermal neutrons existed. Based on this result, neutron images with and without energy filtering were acquired respectively, and it showed that detection capability of PKUNIFTY was improved with setting the exposure interval as 0.8–2.0 ms, especially for materials with strong moderating capability.

  14. Retention and penetration of a conventional resin-based sealant and a photochromatic flowable composite resin placed on occlusal pits and fissures

    Directory of Open Access Journals (Sweden)

    Aguilar F

    2007-01-01

    Full Text Available This study compares the retention and penetration of a conventional resin-based sealant (Fluroshield and a photochromatic flowable composite resin (Tetric Flow Chroma placed on occlusal pits and fissures and submitted to thermal or chemical cycling regimens. Penetration assessment - ten premolars were sealed with each material, isolated (except for the sealed surface and immersed in 0.2% Rhodamine B. The teeth were serially sectioned in a mesiodistal direction. The images of the sections were digitized and analyzed (ImageLab. The distance between the most superficial and the deepest points on the occlusal central groove was calculated to determine the groove′s total depth. The length of the central groove filled with the sealant was divided by its total depth to obtain the percentage of sealing of the occlusal groove. Retention assessment - 30 premolars were sealed, their occlusal surfaces were photographed and the area occupied by the sealing materials was demarcated (ImageLab. The teeth were submitted to different treatments: thermocycled, stored in artificial saliva and immersed in acetic acid and saliva (10 cycles/day protocol for 30 days. New photographs were taken to assess the final area occupied by the materials. The difference between the final and initial area was calculated to obtain the material loss. The data was analyzed (two-way anova and Tukey′s test P < 0.05. Both materials presented similar penetration of the occlusal central groove. After thermal and chemical cycling, the materials did not differ with respect to retention, except for immersion in acetic acid. In this case, Tetric Flow Chroma presented greater retention than Fluoroshield.

  15. Recent advances in polarized 3 He based neutron spin filter development

    Science.gov (United States)

    Chen, Wangchun; Gentile, Thomas; Erwin, Ross; Watson, Shannon; Krycka, Kathryn; Ye, Qiang; NCNR NIST Team; University of Maryland Team

    2015-04-01

    Polarized 3 He neutron spin filters (NSFs) are based on the strong spin-dependence of the neutron absorption cross section by 3 He. NSFs can polarize large area, widely divergent, and broadband neutron beams effectively and allow for combining a neutron polarizer and a spin flipper into a single polarizing device. The last capability utilizes 3 He spin inversion based on the adiabatic fast passage (AFP) nuclear magnetic resonance technique. Polarized 3 He NSFs are significantly expanding the polarized neutron measurement capabilities at the NIST Center for Neutron Research (NCNR). Here we present an overview of 3 He NSF applications to small-angle neutron scattering, thermal triple axis spectrometry, and wide-angle polarization analysis. We discuss a recent upgrade of our spin-exchange optical pumping (SEOP) systems that utilize chirped volume holographic gratings for spectral narrowing. The new capability allows us to polarize rubidium/potassium hybrid SEOP cells over a liter in volume within a day, with 3 He polarizations up to 88%, Finally we discuss how we can achieve nearly lossless 3 He polarization inversion with AFP.

  16. Event-based simulation of neutron interferometry experiments

    CERN Document Server

    De Raedt, Hans; Michielsen, Kristel

    2012-01-01

    A discrete-event approach, which has already been shown to give a cause-and-effect explanation of many quantum optics experiments, is applied to single-neutron interferometry experiments. The simulation algorithm yields a logically consistent description in terms of individual neutrons and does not require the knowledge of the solution of a wave equation. It is shown that the simulation method reproduces the results of several single-neutron interferometry experiments, including experiments which, in quantum theoretical language, involve entanglement. Our results demonstrate that classical (non-Hamiltonian) systems can exhibit correlations which in quantum theory are associated with interference and entanglement, also when all particles emitted by the source are accounted for.

  17. A dense plasma focus-based neutron source for a single-shot detection of illicit materials and explosives by a nanosecond neutron pulse

    Energy Technology Data Exchange (ETDEWEB)

    Gribkov, V A; Latyshev, S V [Institute of Theoretical and Experimental Physics, Moscow (Russian Federation); Miklaszewski, R A; Chernyshova, M [Institute of Plasma Physics and Laser Microfusion, Warsaw (Poland); Drozdowicz, K; Wiacek, U [Institute of Nuclear Physics, Krakow (Poland); Tomaszewski, K [ACS Ltd, Warsaw (Poland); Lemeshko, B D [N L Dukhov All-Russian Institute of Automation, Moscow (Russian Federation)], E-mail: gribkovv@yahoo.com

    2010-03-15

    Recent progress in a single-pulse Nanosecond Impulse Neutron Investigation System (NINIS) intended for interrogation of hidden objects by means of measuring elastically scattered neutrons is presented in this paper. The method uses very bright neutron pulses having duration of the order of 10 ns only, which are generated by dense plasma focus (DPF) devices filled with pure deuterium or DT mixture as a working gas. The small size occupied by the neutron bunch in space, number of neutrons per pulse and mono-chromaticity ({delta}E/E{approx}1%) of the neutron spectrum provides the opportunity to use a time-of-flight (TOF) technique with flying bases of about a few metres. In our researches we used DPF devices having bank energy in the range 2-7 kJ. The devices generate a neutron yield of the level of 10{sup 8}-10{sup 9} 2.45 MeV and 10{sup 10}-10{sup 11} 14 MeV neutrons per pulse with pulse duration {approx}10-20 ns. TOF base in the tests was 2.2-18.5 m. We have demonstrated the possibility of registering of neutrons scattered by the substances under investigation-1 litre bottles with methanol (CH{sub 3}OH), phosphoric (H{sub 2}PO{sub 4}) and nitric (HNO{sub 3}) acids as well as a long object-a 1 m gas tank filled with deuterium at high pressure. It is shown that the above mentioned short TOF bases and relatively low neutron yields are enough to distinguish different elements' nuclei composing the substance under interrogation and to characterize the geometry of lengthy objects in some cases. The wavelet technique was employed to 'clean' the experimental data registered. The advantages and restrictions of the proposed and tested NINIS technique in comparison with other methods are discussed.

  18. A dense plasma focus-based neutron source for a single-shot detection of illicit materials and explosives by a nanosecond neutron pulse

    Science.gov (United States)

    Gribkov, V. A.; Latyshev, S. V.; Miklaszewski, R. A.; Chernyshova, M.; Drozdowicz, K.; Wiącek, U.; Tomaszewski, K.; Lemeshko, B. D.

    2010-03-01

    Recent progress in a single-pulse Nanosecond Impulse Neutron Investigation System (NINIS) intended for interrogation of hidden objects by means of measuring elastically scattered neutrons is presented in this paper. The method uses very bright neutron pulses having duration of the order of 10 ns only, which are generated by dense plasma focus (DPF) devices filled with pure deuterium or DT mixture as a working gas. The small size occupied by the neutron bunch in space, number of neutrons per pulse and mono-chromaticity (ΔE/E~1%) of the neutron spectrum provides the opportunity to use a time-of-flight (TOF) technique with flying bases of about a few metres. In our researches we used DPF devices having bank energy in the range 2-7 kJ. The devices generate a neutron yield of the level of 108-109 2.45 MeV and 1010-1011 14 MeV neutrons per pulse with pulse duration ~10-20 ns. TOF base in the tests was 2.2-18.5 m. We have demonstrated the possibility of registering of neutrons scattered by the substances under investigation—1 litre bottles with methanol (CH3OH), phosphoric (H2PO4) and nitric (HNO3) acids as well as a long object—a 1 m gas tank filled with deuterium at high pressure. It is shown that the above mentioned short TOF bases and relatively low neutron yields are enough to distinguish different elements' nuclei composing the substance under interrogation and to characterize the geometry of lengthy objects in some cases. The wavelet technique was employed to 'clean' the experimental data registered. The advantages and restrictions of the proposed and tested NINIS technique in comparison with other methods are discussed.

  19. Shielding design studies for a neutron irradiator system based on a 252Cf source.

    Science.gov (United States)

    da Silva, A X; Crispim, V R

    2001-01-01

    This study aims to investigate a shielding design against neutrons and gamma rays from a source of 252Cf, using Monte Carlo simulation. The shielding materials studied were borated polyethylene, borated-lead polyethylene and stainless steel. The Monte Carlo code MCNP4B was used to design shielding for 252Cf based neutron irradiator systems. By normalising the dose equivalent rate values presented to the neutron production rate of the source, the resulting calculations are independent of the intensity of the actual 252Cf source. The results show that the total dose equivalent rates were reduced significantly by the shielding system optimisation.

  20. A simulation-based study of the neutron backgrounds for NaI dark matter experiments

    CERN Document Server

    Jeon, Eunju

    2015-01-01

    Among the direct search experiments for weakly interacting massive particle (WIMP) dark matter, the DAMA experiment observed an annual modulation signal interpreted as WIMP interactions with a significance of 9.2$\\sigma$. Recently, Jonathan Davis claimed that the DAMA modulation may be interpreted on the basis of the neutron scattering events induced by the muons and neutrinos together. We tried to simulate the neutron backgrounds at the Gran Sasso and Yangyang laboratory with and without the polyethylene shielding to quantify the effects of the ambient neutrons on the direct detection experiments based on the crystals.

  1. Syntheses of silsesquioxane (POSS)-based inorganic/organic hybrid and the application in reinforcement for an epoxy resin.

    Science.gov (United States)

    Ni, Caihua; Ni, Guifeng; Zhang, Liping; Mi, Jiaquan; Yao, Bolong; Zhu, Changping

    2011-10-01

    A new inorganic/organic hybrid material containing silsesquioxane was prepared by the reaction of caged octa (aminopropyl silsesquioxane) (POSS-NH(2)) with n-butyl glycidyl ether (nBGE) and 1,4-butanediol diglycidyl ether (BDGE). The copolymers of POSS, nBGE, and BDGE could be obtained with varied feed ratio of POSS-NH(2), nBGE, and BDGE in the preparation. The hybrid material was added into an epoxy resin (E51) for enhancing the toughening and thermal properties of the epoxy resin. The results showed that the toughening and the thermal properties of the cured epoxy resin were greatly improved by the addition of the hybrid. The enhancement was ascribed to nano-scale effect of the POSS structure and the formation of anchor structure in the cured network. The investigation of kinetics for the curing process of the hybrid-modified epoxy resin revealed that two kinds of curing reactions occurred in different temperature ranges. They were attributed to the reactions between amino groups of the curing agent with epoxy groups of E51 and with residue epoxy groups in the hybrid. The reacting activation energies were calculated based on Kissinger's and Flynn-Wall-Ozawa's methods, respectively.

  2. Modelling of the interaction between chemical and mechanical behaviour of ion exchange resins incorporated into a cement-based matrix

    Directory of Open Access Journals (Sweden)

    Le Bescop P.

    2013-07-01

    Full Text Available In this paper, we present a predictive model, based on experimental data, to determine the macroscopic mechanical behavior of a material made up of ion exchange resins solidified into a CEM III cement paste. Some observations have shown that in some cases, a significant macroscopic expansion of this composite material may be expected, due to internal pressures generated in the resin. To build the model, we made the choice to break down the problem in two scale’s studies. The first deals with the mechanical behavior of the different heterogeneities of the composite, i.e. the resin and the cement paste. The second upscales the information from the heterogeneities to the Representative Elementary Volume (REV of the composite. The heterogeneities effects are taken into account in the REV by applying a homogenization method derived from the Eshelby theory combined with an interaction coefficient drawn from the poroelasticity theory. At the first scale, from the second thermodynamic law, a formulation is developed to estimate the resin microscopic swelling. The model response is illustrated on a simple example showing the impact of the calculated internal pressure, on the macroscopic strain.

  3. Effect of incorporation of 2-tert-butylaminoethyl methacrylate on flexural strength of a denture base acrylic resin

    Directory of Open Access Journals (Sweden)

    André Gustavo Paleari

    2011-06-01

    Full Text Available Polymethyl methacrylate (PMMA resins have commonly been used as a denture base material. However, denture bases may act as a reservoir for microorganisms and contribute to oral diseases in denture wearers. It is hypothesized that the 2-tert-butylaminoethyl methacrylate (TBAEMA incorporated to acrylic resins should have antimicrobial activity related to the presence of amino groups on acrylic resin surface. OBJECTIVES: The objectives of this study were to evaluate the presence of amino groups on acrylic resin surface and the influence on flexural strength after incorporation of TBAEMA. MATERIAL AND METHODS: Six groups were divided according to the concentration of TBAEMA incorporated to acrylic resin (Lucitone 550: 0, 0.5, 1.0, 1.5, 1.75 and 2%. Specimens surface were evaluated by Electron Spectroscopy for Chemical Analysis (ESCA to detect the presence of amino groups, represented by nitrogen ratios. Flexural strength of the specimens was tested and results were analyzed by ANOVA and Tukey's test (α=0.05. RESULTS: Different nitrogen ratios were observed on specimen surfaces: 0, 0.13, 0.74, 0.66, 0.92 and 0.33% for groups 0, 0.5, 1.0, 1.5, 1.75, and 2%, respectively. Significant differences were found for flexural strength (p<0.001. The mean flexural strength values were 98.3±3.9, 93.3±3.2, 83.9±2.1, 82.8±5.2, 71.2±5.1 and 17.3±3.2 MPa for groups 0, 0.5, 1.0, 1.5, 1.75, and 2%, respectively. CONCLUSION: Within the limitations of this study, the incorporation of TBAEMA results in the presence of the potentially antimicrobial amino groups on specimen surfaces, but affect the flexural strength, depending on the concentration of TBAEMA.

  4. Phenolic resin-based porous carbons for adsorption and energy storage applications

    Science.gov (United States)

    Wickramaratne, Nilantha P.

    The main objective of this dissertation research is to develop phenolic resin based carbon materials for range of applications by soft-templating and Stober-like synthesis strategies. Applications Studied in this dissertation are adsorption of CO2, bio-molecular and heavy metal ions, and energy storage devices. Based on that, our goal is to design carbon materials with desired pore structure, high surface area, graphitic domains, incorporated metal nanoparticles, and specific organic groups and heteroatoms. In this dissertation the organic-organic self-assembly of phenolic resins and triblock copolymers under acidic conditions will be used to obtain mesoporous carbons/carbon composites and Stober-like synthesis involving phenolic resins under basic condition will be used to prepare polymer/carbon particles and their composites. The structure of this dissertation consists of an introductory chapter (Chapter 1) discussing the general synthesis of carbon materials, particularly the soft-templating strategy and Stober-like carbon synthesis. Also, Chapter 1 includes a brief outline of applications namely adsorption of CO2, biomolecule and heavy metal ions, and supercapacitors. Chapter 2 discusses the techniques used for characterization of the carbon materials studied. This chapter starts with nitrogen adsorption analysis, which is used to measure the specific surface area, pore volume, distribution of pore sizes, and pore width. In addition to nitrogen adsorption, powder X-ray diffraction (XRD), transmission electron microscopy (TEM), high resolution thermogravimetric analysis (HR-TGA), cyclic voltammetry (CV) and CHNS elemental analysis (EA) are mentioned too. Chapter 3 is focused on carbon materials for CO2 adsorption. There are different types of porous solid materials such as silicate, MOFs, carbons, and zeolites studied for CO2 adsorption. However, the carbon based materials are considered to be the best candidates for CO 2 adsorption to the industrial point of

  5. Biocompatibility of composite resins

    Directory of Open Access Journals (Sweden)

    Sayed Mostafa Mousavinasab

    2011-01-01

    Full Text Available Dental materials that are used in dentistry should be harmless to oral tissues, so they should not contain any leachable toxic and diffusible substances that can cause some side effects. Reports about probable biologic hazards, in relation to dental resins, have increased interest to this topic in dentists. The present paper reviews the articles published about biocompatibility of resin-restorative materials specially resin composites and monomers which are mainly based on Bis-GMA and concerns about their degradation and substances which may be segregated into oral cavity.

  6. Properties of powdered ion-exchange resins based on petroleum asphaltites

    Energy Technology Data Exchange (ETDEWEB)

    Pokonova, Y.V.; Mitrofanova, L.M.; Proskuryakov, V.A.

    1977-02-01

    The following properties of the resins were studied: physical-mechanical properties, total effective exchange capacity, particle size distribution, dissociation constants, and dynamic and static exchange capacities. 6 tables. (DLC)

  7. Particle Filter-Based Recursive Data Fusion With Sensor Indexing for Large Core Neutron Flux Estimation

    Science.gov (United States)

    Tamboli, Prakash Kumar; Duttagupta, Siddhartha P.; Roy, Kallol

    2017-06-01

    We introduce a sequential importance sampling particle filter (PF)-based multisensor multivariate nonlinear estimator for estimating the in-core neutron flux distribution for pressurized heavy water reactor core. Many critical applications such as reactor protection and control rely upon neutron flux information, and thus their reliability is of utmost importance. The point kinetic model based on neutron transport conveniently explains the dynamics of nuclear reactor. The neutron flux in the large core loosely coupled reactor is sensed by multiple sensors measuring point fluxes located at various locations inside the reactor core. The flux values are coupled to each other through diffusion equation. The coupling facilitates redundancy in the information. It is shown that multiple independent data about the localized flux can be fused together to enhance the estimation accuracy to a great extent. We also propose the sensor anomaly handling feature in multisensor PF to maintain the estimation process even when the sensor is faulty or generates data anomaly.

  8. Proton recoil telescope based on diamond detectors for measurement of fusion neutrons

    CERN Document Server

    Caiffi, B; Ripani, M; Pillon, M; Taiuti, M

    2015-01-01

    Diamonds are very promising candidates for the neutron diagnostics in harsh environments such as fusion reactor. In the first place this is because of their radiation hardness, exceeding that of Silicon by an order of magnitude. Also, in comparison to the standard on-line neutron diagnostics (fission chambers, silicon based detectors, scintillators), diamonds are less sensitive to $\\gamma$ rays, which represent a huge background in fusion devices. Finally, their low leakage current at high temperature suppresses the detector intrinsic noise. In this talk a CVD diamond based detector has been proposed for the measurement of the 14 MeV neutrons from D-T fusion reaction. The detector was arranged in a proton recoil telescope configuration, featuring a plastic converter in front of the sensitive volume in order to induce the (n,p) reaction. The segmentation of the sensitive volume, achieved by using two crystals, allowed to perform measurements in coincidence, which suppressed the neutron elastic scattering backg...

  9. Calibration of a neutron detector based on single event upset of SRAM memories

    Energy Technology Data Exchange (ETDEWEB)

    Domingo, C., E-mail: carles.domingo@uab.ca [Departament de Fisica, Univ. Autonoma de Barcelona, E-08193 Bellaterra (Spain); Gomez, F. [Dpto. de Particulas, Univ. de Santiago, 15782 Santiago de Compostela (Spain); Sanchez-Doblado, F. [Dpto. de Fisiologia Medica y Biofisica, Univ. de Sevilla, 41009 Sevilla (Spain); Servicio de Radiofisica, Hospital Univ. Virgen Macarena, 41009 Sevilla (Spain); Hartmann, G.H. [DKFZ E0400, Im Neuenheimer Feld 280, 69120 Heidelberg (Germany); Amgarou, K.; Garcia-Fuste, M.J. [Departament de Fisica, Univ. Autonoma de Barcelona, E-08193 Bellaterra (Spain); Romero, M.T. [Dpto. de Fisiologia Medica y Biofisica, Univ. de Sevilla, 41009 Sevilla (Spain); Boettger, R.; Nolte, R.; Wissmann, F.; Zimbal, A.; Schuhmacher, H. [PTB, Bundesallee 100, 38116 Braunschweig (Germany)

    2010-12-15

    One of the challenges of measuring neutron fluences around medical linacs is the fact that the scattered photon fluence is important and higher than the surrounding neutron leakage fluence. Additionally most electron accelerators are pulsed, with repetition rates of the order of hundreds of Hertz, while the pulse duration is in the microsecond range. For this reason, neutron fluence around RT linacs is usually measured through passive methods, with the inconvenience of their time consuming analysis. A new neutron detector, based on the relation between Single Event Upsets (SEU) in digital SRAM memories and the existing thermal neutron fluence, has been developed. This work reports the calibration results of prototypes of this detector, obtained from exposures to the Physikalisch-Technische Bundesanstalt in Braunschweig (PTB) moderated {sup 252}Cf source, to PTB quasi-monoenergetic neutron beams of 0.565 MeV, 1.2 MeV, 5 MeV, 8 MeV and 14.8 MeV, and to the GKSS thermal neutron beam.

  10. Application of XAD-resin based passive air samplers to assess local (roadside) and regional patterns of persistent organic pollutants.

    Science.gov (United States)

    Barthel, Paul; Thuens, Sabine; Shunthirasingham, Chubashini; Westgate, John N; Wania, Frank; Radke, Michael

    2012-07-01

    We used XAD-resin based passive air samplers (PAS) to measure atmospheric levels of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) at five ombrotrophic bogs in Eastern Canada. The aims of our study were to investigate the influence of local roads on contaminant levels in the bogs, to derive the regional pattern of atmospheric concentrations, and to assess the uncertainties of the method. Expanded uncertainties based on the duplicate PAS deployed at 24 sites were good for the PAHs, while the deployment period of approx. 100 days was too short to yield acceptable uncertainties for PCBs. The regional PAH distribution was in good agreement with the calculated source proximity of the sampled bogs. We conclude that XAD-resin based PAS deployed for comparatively short periods are well suited for measuring atmospheric concentrations of volatile PAHs, while in remote regions longer deployment is necessary for less volatile PAHs and for PCBs.

  11. Modification of epoxy resins with thermoplastic segmented polycarbonate-based polyurethanes

    OpenAIRE

    Pavličević Jelena; Jovičić Mirjana; Simendić Vesna; Bera Oskar; Radičević Radmila; Špírková Milena

    2014-01-01

    In this work, epoxy hybrid materials were synthesized by addition of thermoplastic segmented aliphatic polyurethanes with good elastic properties. The modified epoxy samples were obtained by curing of previously homogenized mixture of prepared polyurethane melts, epoxy resin and crosslinking agent Jeffamine D-2000. The influence of different weight content of polyurethanes (5, 10 and 15 wt. % compared to pure epoxy resin) as well the influence of different ...

  12. Differences in physico-mechanical behaviors of resol(e) and novolac type phenolic resin based composite bipolar plate for proton exchange membrane (PEM) fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Kakati, Biraj Kumar [Department of Chemical Engineering, Indian Institute of Technology Guwahati, North Guwahati, PIN 781 039, Dist. Kamrup (Assam) (India); Deka, Dhanapati [Department of Energy, Tezpur University, Tezpur 784 028, Dist. Sonitpur (Assam) (India)

    2007-09-15

    Composite bipolar plates for Proton Exchange Membrane Fuel Cell (PEMFC) are prepared by compression molding technique using polymer as binder and graphite as electric filler material with some other reinforcements. Study on the effect of resole and novolac type phenolic resin on the properties of composite bipolar plate, such as bulk density, porosity, bulk conductivity, hardness, flexural strength, etc. shows that both of the resin shows different physico-mechanical properties. Moreover, single cell performance analysis also shows variation for resole and novolac based composites. A novel concept of triple continuous structure to provide graphite polymer blends with high electrical conductivity, high shore hardness, high flexural strength, less porosity and low density has been proposed and study on the effect of different types of phenolic resin on the properties and performance of bipolar plate reveals that novolac type powdered phenolic resin gives better mechanical properties than resole type phenolic resin. However, resole type phenolic resin compound has slightly higher electrical conductivity due to more number of polar -OH group presents on its cured form. But due to the less porosity and higher mechanical strength, bipolar plates with novolac type phenolic resin gives better performance in I-V analysis than bipolar plates with resole type phenolic resin. (author)

  13. Neutron-based land mine detection system development

    Energy Technology Data Exchange (ETDEWEB)

    Davis, H.A.; McDonald, T.E. Jr.; Nebel, R.A.; Pickrell, M.M.

    1997-10-01

    This is the final report of a one-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The goal of this project was to examine the feasibility of developing a land mine detection system that can detect nonmetallic (plastic) mines using the detection and analysis of prompt gamma neutron activation analysis (PGNAA). The authors approached this study by first carrying out a review of other nonmetallic land mine detection methods for comparison with the PGNAA concept. They reviewed issues associated with detecting and recording the return gamma signal resulting from neutrons interacting with high explosive in mines and they examined two neutron source technologies that have been under development at Los Alamos for the past several years for possible application to a PGNAA system. A major advantage of the PGNAA approach is it`s ability to discriminate detection speed and need for close proximity. The authors identified approaches to solving these problems through development of improved neutron sources and detection sensors.

  14. Novel Boron-10-based detectors for Neutron Scattering Science

    CERN Document Server

    Piscitelli, Francesco

    2015-01-01

    Nowadays neutron scattering science is increasing its instrumental power. Most of the neutron sources in the world are pushing the development of their technologies to be more performing. The neutron scattering development is also pushed by the European Spallation Source (ESS) in Sweden, a neutron facility which has just started construction. Concerning small area detectors (1m^2), the 3He technology, which is today cutting edge, is reaching fundamental limits in its development. Counting rate capability, spatial resolution and cost-e?ectiveness, are only a few examples of the features that must be improved to ful?fill the new requirements. On the other hand, 3He technology could still satisfy the detector requirements for large area applications (50m^2), however, because of the present 3He shortage that the world is experiencing, this is not practical anymore. The recent detector advances (the Multi-Grid and the Multi-Blade prototypes) developed in the framework of the collaboration between the Institut Laue...

  15. Recent neutron scattering results from Gd-based pyrochlore oxides

    Science.gov (United States)

    Gardner, Jason

    2009-03-01

    In my presentation I will present recent results that have determined the spin-spin correlations in the geometrically frustrated magnets Gd2Sn2O7 and Gd2Ti2O7. This will include polarised neutron diffraction, inelastic neutron scattering and neutron spin echo data. One sample of particular interest is Gd2Sn2O7 which is believed to be a good approximation to a Heisenberg antiferromagnet on a pyrochlore lattice with exchange and dipole-dipole interactions. Theoretically such a system is expected to enter long range ordered ground state known as the ``Palmer Chalker'' state [1]. We show conclusively, through neutron scattering data, that the system indeed enters an ordered state with the Palmer-Chalker spin configuration below Tc = 1 K [2-3]. Within this state we have also observed long range collective spin dynamics, spin waves. This work has been performed in collaboration with many research groups including G. Ehlers (SNS), R. Stewart (ISIS). [0pt] [1] S. E. Palmer and J. T. Chalker, Phys. Rev. B 62, 488 (2000). [0pt] [2] J. R. Stewart, G. Ehlers, A. S. Wills, S. T. Bramwell, and J. S. Gardner, J. Phys.: Condens. Matter 16, L321 (2004). [0pt] [3] J R Stewart, J S Gardner, Y. Qiu and G Ehlers, Phys. Rev. B. 78, 132410 (2008)

  16. Modification of epoxy resins with thermoplastic segmented polycarbonate-based polyurethanes

    Directory of Open Access Journals (Sweden)

    Pavličević Jelena

    2014-01-01

    Full Text Available In this work, epoxy hybrid materials were synthesized by addition of thermoplastic segmented aliphatic polyurethanes with good elastic properties. The modified epoxy samples were obtained by curing of previously homogenized mixture of prepared polyurethane melts, epoxy resin and crosslinking agent Jeffamine D-2000. The influence of different weight content of polyurethanes (5, 10 and 15 wt. % compared to pure epoxy resin as well the influence of different hard segments of elastomers (20, 25 and 30 wt. % on the curing of modified epoxy systems was studied. The curing was followed by differential scanning calorimetry (DSC, in dynamic regime from 30 to 300°C, at three heating rates (5, 10 and 20°C/min. With the increase of hard segments content of polyurethanes added in higher concentration (10 and 15 wt. % into epoxy matrix, the temperature of maximum ratio of curing was shifted to lower values (from 205 to 179°C. Obtained DSC data were analyzed using two integral methods (Ozawa-Flynn-Wall and Kissinger-Akahira-Sunose and one differential kinetic model (Friedman. The significant differences were observed in the second part of the epoxy curing (for the reaction degrees higher than 60 %, where the values of activation energies remarkably increase. The addition of polyurethane elastomers retarded the curing process due to decreased mobility of reactant molecules caused by higher viscosity of reaction mixture. By detailed analysis of determined kinetic parameters, it is concluded that the influence of slow diffusion is more pronounced in the presence of thermoplastic polycarbonate-based polyurethanes, which confirmed their effect on the mechanism of epoxy curing. The highest tensile strength and hardness showed the DGEBA modified with the polyurethane with highest hard segment content. Increasing the hard segment content of polyurethane and its concentration in matrix, the tensile strength of modified epoxy was increased. The elongation at break of

  17. Electron spectroscopy of rubber and resin-based composites containing 2D carbon

    Energy Technology Data Exchange (ETDEWEB)

    Kaciulis, S., E-mail: saulius.kaciulis@ismn.cnr.it [Institute for the Study of Nanostructured Materials, ISMN-CNR, P.O. Box 10, Monterotondo Stazione, 00015 Roma (Italy); Mezzi, A.; Balijepalli, S.K. [Institute for the Study of Nanostructured Materials, ISMN-CNR, P.O. Box 10, Monterotondo Stazione, 00015 Roma (Italy); Lavorgna, M. [Institute of Polymers, Composites and Biomaterials, IPCB-CNR, P.le Fermi, 80055 Napoli (Italy); Xia, H.S. [State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu, 610065 Sichuan (China)

    2015-04-30

    Composite materials with 2D carbon (graphene and/or single wall carbon nanotubes) are very promising due to their extraordinary electrical and mechanical properties. Graphene and natural rubber composites, which may be used for the gaskets or sealants, were prepared by ultrasonically assisted latex-mixing exfoliation and in-situ reduction process, with two vulcanization approaches: roll-mixing and hot-pressing. Also the resin-based composites, filled with micro-particles of Ag and graphene or carbon nanotubes, have been studied. The standards for the compositional characterization of these materials still are not established. In addition to the mostly used techniques, such as Raman spectroscopy and electron microscopy, also Auger electron spectroscopy can be employed for the identification of graphene. In this study, the shape of C KVV peak, excited by electron beam and X-ray photons, has been investigated in different composite materials containing graphene and carbon nanotubes. A spectroscopic method for 2D carbon recognition, based on the D{sub x} parameter which is determined from C KVV signal excited by X-ray photons, was proposed and verified. Even a small content of graphene in different types of composites was sufficient for this recognition due to the dominating presence of graphene on the surface of composites. - Highlights: • Chemical composition of the rubber composites was determined by XPS. • Auger spectrum of carbon was used for graphene identification in composites. • Small content of graphene was sufficient for its recognition from the D parameter.

  18. Simultaneous measurement of refractive index and temperature using an epoxy resin-based interferometer.

    Science.gov (United States)

    Wang, Jian; Wu, Shengli; Ren, Wenyi

    2014-11-20

    A fiber-optics reflection probe based on fiber Fabry-Perot interference (FFPI) is proposed and experimentally demonstrated. The sensing structure comprises an epoxy resin (ER)-based cap on the end-face of the single-mode fiber. A well-defined interference spectrum is obtained by the reflective beams of two surfaces of the ER cap. The simultaneous measurements, including fringe contrast-referenced for the surrounding refractive index (SRI) and wavelength-referenced for temperature, have been achieved via selective interference dips monitoring. Experimental results indicate that the proposed FFPI presents an SRI sensitivity of 57.69 dB/RIU in the measurement range of 1.33-1.40 RIU and a temperature sensitivity of 0.98  pm·μm-1·°C-1 with per unit cavity length in the range of 30°C-70°C. The proposed sensor has advantages of being compact and robust, making it an alternative candidate as a smart sensor in chemical and biological applications.

  19. Mechanical and electrical properties of a polyester resin reinforced with clay-based fillers

    Energy Technology Data Exchange (ETDEWEB)

    Buncianu, Dorel; Jadaneant, Mihai [UPT Timisoara, Timisoara (Romania); Tessier-Doyen, Nicolas; Absi, Joseph [Centre Européen de la Céramique, Limoges Cedex (France); Courreges, Fabien [Laboratoire XLIM, 123, Limoges Cedex (France)

    2017-03-15

    In this study, composite polymer-based materials were fabricated, in which a significant proportion of polyester resin was substituted by low-cost and environmentally-friendly clay-based raw materials. The main objective is to improve mechanical properties while maintaining a reasonable electrical insulating behavior. A homogenized distribution of fillers within the matrix compatible with the processing parameters was obtained up to a maximum added fraction of 20 vol%. Mechanical characterization using uniaxial traction tests and Charpy impact pendulum machine showed that stress-to-rupture can be enhanced of approximately 25 %. In addition, fracture energy was doubled for the best formulation. Dielectric constant was decreased and loss factor was slightly increased when electrical resistivity remained almost constant. In general, the composite materials with metakaolin fillers exhibited higher mechanical properties and greater electrical insulating behavior. Microstructural observation showed the presence of decohesive agglomerates of particles at the interface with the matrix. The mechanical properties were found to be more sensitive than electrical properties to the homogeneity of filler dispersion in the matrix.

  20. Influence of acrylamide monomer addition to the acrylic denture-base resins on mechanical and physical properties

    Institute of Scientific and Technical Information of China (English)

    Elif Aydogan Ayaz; Rukiye Durkan

    2013-01-01

    The aim of the study was to evaluate the effect of adding acrylamide monomer (AAm) on the characterization, flexural strength, flexural modulus and thermal degradation temperature of poly(methyl methacrylate) (PMMA) denture-base resins. Specimens (n510) were fabricated from a conventional heat-activated QC-20 (Qc-) and a microwave heat-activated Acron MC (Ac-) PMMA resins. Powder/liquid ratio followed the manufacturer’s instructions for the control groups (Qc-c and Ac-c) and for the copolymer groups, the resins were prepared with 5%(25), 10%(210), 15%(215) and 20%(220) acrylamide contents, according to the molecular weight ratio, respectively. The flexural strength and flexural modulus were measured by a three-point bending test. The data obtained were statistically analyzed by Kruskal-Wallis test (a50.05) to determine significant differences between the groups. The chemical structures of the resins were characterized by the nuclear magnetic resonance spectroscopy. Thermal stabilities were determined by thermogravimetric analysis (TGA) with a heating rate of 10 6C?min21 from 35 6C to 600 6C. Control groups from both acrylic resins showed the lowest flexural strength values. Qc-15 showed significant increase in the flexural strength when compared to Qc-c (P,0.01). Ac-10 and Ac-15 showed significance when compared to Ac-c (P,0.01). Acrylamide incorporation increased the elastic modulus in Qc-10, Qc-15 and Qc-20 when compared to Qc-c (P,0.01). Also significant increase was observed in Ac-10, Ac-15 and Ac-20 copolymer groups when compared to Ac-c (P,0.01). According to the 1H-nuclear magnetic resonance (NMR) results, acrylamide copolymerization was confirmed in the experimental groups. TGA results showed that the thermal stability of PMMA is increased by the insertion of AAm.

  1. [Effect of surface pretreatment with chemical etchants on bond strength between a silicone-based resilient liner and denture base resin].

    Science.gov (United States)

    Zhang, Ying; Zhang, Huai-qin; Ma, Jun-chi; Jin, Si-yuan

    2011-12-01

    To evaluate the effect of denture base resin surface pretreatment with chemical etchants on microleakage and bond strength between silicone-based resilient liner and denture base resin. The initial bending strength of denture base resin after surface pretreatment was also examined. Thirty-six polymethyl methacrylate (PMMA) denture base resin blocks (30 mm × 30 mm × 2 mm) were prepared and divided into three groups: group acetone, group methyl methy acrylate (MMA) and group control. Subsequently, a 2 mm silicone-based resilient liner was applied between every two blocks. After 5000 cycles in the thermal cycler (5 and 55°C), they were immersed in the (131) I solution for 24 hours and γ-ray counts were measured. Another 36 PMMA resin blocks (30 mm × 10 mm × 7.5 mm) were prepared. The blocks were divided into three groups and treated as mentioned above. A 3 mm silicone-based resilient liner was applied between every two blocks. After 5000 thermal cycles, tensile bond strength of the sample was measured in a universal testing machine. Another 18 PMMA resin blocks (65 mm × 10 mm × 3.3 mm) were prepared. They were divided into 3 groups and treated in the same way. After an adhesive was applied, the bending strength was measured with three-piont bending test. Two experimental groups showed lower microleakage (520.0 ± 562.2 and 493.5 ± 447.9) and higher tensile bond strength [(1.5 ± 0.4) and (1.4 ± 0.5) MPa] than the group control [microleakage: (1369.5 ± 590.2); tensile bond strength: (0.9 ± 0.2) MPa, P 0.05). There was no statistically significant difference in bending strength among the three groups (P > 0.05). Treating the denture base resin surface with acetone and MMA decreased the microleakage, increased the tensile bond strength between the two materials and did not make the initial bending strength of denture base resin decline.

  2. Analysis of accelerator based neutron spectra for BNCT using proton recoil spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Wielopolski, L.; Ludewig, H.; Powell, J.R.; Raparia, D.; Alessi, J.G.; Lowenstein, D.I.

    1999-03-01

    Boron Neutron Capture Therapy (BNCT) is a promising binary treatment modality for high-grade primary brain tumors (glioblastoma multiforme, GM) and other cancers. BNCT employs a boron-10 containing compound that preferentially accumulates in the cancer cells in the brain. Upon neutron capture by {sup 10}B energetic alpha particles and triton released at the absorption site kill the cancer cell. In order to gain penetration depth in the brain Fairchild proposed, for this purpose, the use of energetic epithermal neutrons at about 10 keV. Phase 1/2 clinical trials of BNCT for GM are underway at the Brookhaven Medical Research Reactor (BMRR) and at the MIT Reactor, using these nuclear reactors as the source for epithermal neutrons. In light of the limitations of new reactor installations, e.g. cost, safety and licensing, and limited capability for modulating the reactor based neutron beam energy spectra, alternative neutron sources are being contemplated for wider implementation of this modality in a hospital environment. For example, accelerator based neutron sources offer the possibility of tailoring the neutron beams, in terms of improved depth-dose distributions, to the individual and offer, with relative ease, the capability of modifying the neutron beam energy and port size. In previous work new concepts for compact accelerator/target configuration were published. In this work, using the Van de Graaff accelerator the authors have explored different materials for filtering and reflecting neutron beams produced by irradiating a thick Li target with 1.8 to 2.5 MeV proton beams. However, since the yield and the maximum neutron energy emerging from the Li-7(p,n)Be-7 reaction increase with increase in the proton beam energy, there is a need for optimization of the proton energy versus filter and shielding requirements to obtain the desired epithermal neutron beam. The MCNP-4A computer code was used for the initial design studies that were verified with benchmark

  3. ANALYSIS OF ACCELERATOR BASED NEUTRON SPECTRA FOR BNCT USING PROTON RECOIL SPECTROSCOPY

    Energy Technology Data Exchange (ETDEWEB)

    WIELOPOLSKI,L.; LUDEWIG,H.; POWELL,J.R.; RAPARIA,D.; ALESSI,J.G.; LOWENSTEIN,D.I.

    1998-11-06

    Boron Neutron Capture Therapy (BNCT) is a promising binary treatment modality for high-grade primary brain tumors (glioblastoma multiforme, GM) and other cancers. BNCT employs a boron-10 containing compound that preferentially accumulates in the cancer cells in the brain. Upon neutron capture by {sup 10}B energetic alpha particles and triton released at the absorption site kill the cancer cell. In order to gain penetration depth in the brain Fairchild proposed, for this purpose, the use of energetic epithermal neutrons at about 10 keV. Phase I/II clinical trials of BNCT for GM are underway at the Brookhaven Medical Research Reactor (BMRR) and at the MIT Reactor, using these nuclear reactors as the source for epithermal neutrons. In light of the limitations of new reactor installations, e.g. cost, safety and licensing, and limited capability for modulating the reactor based neutron beam energy spectra alternative neutron sources are being contemplated for wider implementation of this modality in a hospital environment. For example, accelerator based neutron sources offer the possibility of tailoring the neutron beams, in terms of improved depth-dose distributions, to the individual and offer, with relative ease, the capability of modifying the neutron beam energy and port size. In previous work new concepts for compact accelerator/target configuration were published. In this work, using the Van de Graaff accelerator the authors have explored different materials for filtering and reflecting neutron beams produced by irradiating a thick Li target with 1.8 to 2.5 MeV proton beams. However, since the yield and the maximum neutron energy emerging from the Li-7(p,n)Be-7 reaction increase with increase in the proton beam energy, there is a need for optimization of the proton energy versus filter and shielding requirements to obtain the desired epithermal neutron beam. The MCNP-4A computer code was used for the initial design studies that were verified with benchmark

  4. Novel acrylic resin denture base with enhanced mechanical properties by the incorporation of PMMA-modified hydroxyapatite

    Institute of Scientific and Technical Information of China (English)

    Yingying Pan; Fengwei Liu; Dan Xu; Xiaoze Jiang; Hao Yu; Meifang Zhu

    2013-01-01

    A kind of novel acrylic resin denture base enhanced by PMMA-modified hydroxyapatite (M-HAP) was prepared and the modification effect of HAP on the mechanical properties of denture base material was investigated in the present study. HAP whiskers were prepared by hydrothermal homogeneous precipitation process and were silanized by the coupling agent, 3-methacryloxy propyl trimethoxyl silane (g-MPS), to induce the vinyl groups onto its surface. Methyl methacrylate (MMA) were then modified outside the vinyl functionalized HAP via polymerization to build a similar chemical structure with the acrylic matrix. A novel acrylic resin denture base was obtained through self-curing process with the incorporation of this PMMA-modified HAP, and the content of which ranged from 0 wt% to 0.8 wt%. Thermal gravimetric analysis (TGA), fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), and universal testing apparatus were used to characterize M-HAP and corresponding denture base. The results showed that PMMA were successfully grafted onto the surface of HAP whiskers with up to 15 wt% and the modification turned out to be useful for the dispersion and compatibility of whiskers in the acrylic resin matrix. The mechanical properties of the prepared denture base samples were enhanced greatly after incorporating with M-HAP fillers. The optimal incorporated content of M-HAP was also investigated.

  5. Performance characteristics of the MIT fission converter based epithermal neutron beam.

    Science.gov (United States)

    Riley, K J; Binns, P J; Harling, O K

    2003-04-07

    A pre-clinical characterization of the first fission converter based epithermal neutron beam (FCB) designed for boron neutron capture therapy (BNCT) has been performed. Calculated design parameters describing the physical performance of the aluminium and Teflon filtered beam were confirmed from neutron fluence and absorbed dose rate measurements performed with activation foils and paired ionization chambers. The facility currently provides an epithermal neutron flux of 4.6 x 10(9) n cm(-2) s(-1) in-air at the patient position that makes it the most intense BNCT source in the world. This epithermal neutron flux is accompanied by very low specific photon and fast neutron absorbed doses of 3.5 +/- 0.5 and 1.4 +/- 0.2 x 10(-13) Gy cm2, respectively. A therapeutic dose rate of 1.7 RBE Gy min(-1) is achievable at the advantage depth of 97 mm when boronated phenylalanine (BPA) is used as the delivery agent, giving an average therapeutic ratio of 5.7. In clinical trials of normal tissue tolerance when using the FCB, the effective prescribed dose is due principally to neutron interactions with the nonselectively absorbed BPA present in brain. If an advanced compound is considered, the dose to brain would instead be predominately from the photon kerma induced by thermal neutron capture in hydrogen and advantage parameters of 0.88 Gy min(-1), 121 mm and 10.8 would be realized for the therapeutic dose rate, advantage depth and therapeutic ratio, respectively. This study confirms the success of a new approach to producing a high intensity, high purity epithermal neutron source that attains near optimal physical performance and which is well suited to exploit the next generation of boron delivery agents.

  6. New method of a "point-like" neutron source creation based on sharp focusing of high-current deuteron beam onto deuterium-saturated target for neutron tomography

    Science.gov (United States)

    Golubev, S.; Skalyga, V.; Izotov, I.; Sidorov, A.

    2017-02-01

    A possibility of a compact powerful point-like neutron source creation is discussed. Neutron yield of the source based on deuterium-deuterium (D-D) reaction is estimated at the level of 1011 s‑1 (1013 s‑1 for deuterium-tritium reaction). The fusion takes place due to bombardment of deuterium- (or tritium) loaded target by high-current focused deuterium ion beam with energy of 100 keV. The ion beam is formed by means of high-current quasi-gasdynamic ion source of a new generation based on an electron cyclotron resonance (ECR) discharge in an open magnetic trap sustained by powerful microwave radiation. The prospects of proposed generator for neutron tomography are discussed. Suggested method is compared to the point-like neutron sources based on a spark produced by powerful femtosecond laser pulses.

  7. Advanced Neutron Source Cross Section Libraries (ANSL-V): ENDF/B-V based multigroup cross-section libraries for advanced neutron source (ANS) reactor studies

    Energy Technology Data Exchange (ETDEWEB)

    Ford, W.E. III; Arwood, J.W.; Greene, N.M.; Moses, D.L.; Petrie, L.M.; Primm, R.T. III; Slater, C.O.; Westfall, R.M.; Wright, R.Q.

    1990-09-01

    Pseudo-problem-independent, multigroup cross-section libraries were generated to support Advanced Neutron Source (ANS) Reactor design studies. The ANS is a proposed reactor which would be fueled with highly enriched uranium and cooled with heavy water. The libraries, designated ANSL-V (Advanced Neutron Source Cross Section Libraries based on ENDF/B-V), are data bases in AMPX master format for subsequent generation of problem-dependent cross-sections for use with codes such as KENO, ANISN, XSDRNPM, VENTURE, DOT, DORT, TORT, and MORSE. Included in ANSL-V are 99-group and 39-group neutron, 39-neutron-group 44-gamma-ray-group secondary gamma-ray production (SGRP), 44-group gamma-ray interaction (GRI), and coupled, 39-neutron group 44-gamma-ray group (CNG) cross-section libraries. The neutron and SGRP libraries were generated primarily from ENDF/B-V data; the GRI library was generated from DLC-99/HUGO data, which is recognized as the ENDF/B-V photon interaction data. Modules from the AMPX and NJOY systems were used to process the multigroup data. Validity of selected data from the fine- and broad-group neutron libraries was satisfactorily tested in performance parameter calculations.

  8. Cell death effects of resin-based dental material compounds and mercurials in human gingival fibroblasts

    Energy Technology Data Exchange (ETDEWEB)

    Reichl, Franz-Xaver [Walther-Straub-Institute of Pharmacology and Toxicology, Munich (Germany); Ludwig-Maximilians-University, Department of Operative Dentistry and Periodontology, Munich (Germany); Esters, Magali; Simon, Sabine; Seiss, Mario [Walther-Straub-Institute of Pharmacology and Toxicology, Munich (Germany); Kehe, Kai [Bundeswehr Institute of Pharmacology and Toxicology, Munich (Germany); Kleinsasser, Norbert [University of Regensburg, Head and Neck Surgery, Department of Otolaryngology, Regensburg (Germany); Folwaczny, Matthias; Glas, Juergen; Hickel, Reinhard [Ludwig-Maximilians-University, Department of Operative Dentistry and Periodontology, Munich (Germany)

    2006-06-15

    In order to test the hypothesis that released dental restorative materials can reach toxic levels in human oral tissues, the cytotoxicities of the resin-based dental (co)monomers hydroxyethylmethacrylate (HEMA), triethyleneglycoldimethacrylate (TEGDMA), urethanedimethacrylate (UDMA), and bisglycidylmethacrylate (BisGMA) compared with methyl mercury chloride (MeHgCl) and the amalgam component mercuric chloride (HgCl{sub 2}) were investigated on human gingival fibroblasts (HGF) using two different test systems: (1) the modified XTT-test and (2) the modified H 33342 staining assay. The HGF were exposed to various concentrations of the test-substances in all test systems for 24 h. All tested (co)monomers and mercury compounds significantly (P<0.05) decreased the formazan formation in the XTT-test. EC{sub 50} values in the XTT assay were obtained as half-maximum-effect concentrations from fitted curves. Following EC{sub 50} values were found (mean [mmol/l]; s.e.m. in parentheses; n=12; * significantly different to HEMA): HEMA 11.530 (0.600); TEGDMA* 3.460 (0.200); UDMA* 0.106 (0.005); BisGMA* 0.087 (0.001); HgCl{sub 2}* 0.013 (0.001); MeHgCl* 0.005 (0.001). Following relative toxicities were found: HEMA 1; TEGDMA 3; UDMA 109; BisGMA 133; HgCl{sub 2} 887; MeHgCl 2306. A significant (P<0.05) increase of the toxicity of (co)monomers and mercurials was found in the XTT-test in the following order: HEMA < TEGDMA < UDMA < BisGMA < HgCl{sub 2} < MeHgCl. TEGDMA and MeHgCl induced mainly apoptotic cell death. HEMA, UDMA, BisGMA, and HgCl{sub 2} induced mainly necrotic cell death. The results of this study indicate that resin composite components have a lower toxicity than mercury from amalgam in HGF. HEMA, BisGMA, UDMA, and HgCl{sub 2} induced mainly necrosis, but it is rather unlikely that eluted substances (solely) can reach concentrations, which might induce necrotic cell death in the human physiological situation, indicating that other (additional) factors may be involved in

  9. Thin and thick layers of resin-based sealer cement bonded to root dentine compared: Adhesive behaviour.

    Science.gov (United States)

    Pane, Epita S; Palamara, Joseph E A; Messer, Harold H

    2015-12-01

    This study aims to evaluate tensile and shear bond strengths of one epoxy (AH) and two methacrylate resin-based sealers (EZ and RS) in thin and thick layers bonded to root dentine. An alignment device was prepared for accurate positioning of 20 root dentine cylinders in a predefined gap of 0.1 or 1 mm. Sealer was placed in the interface. Bond strength tests were conducted. Mode of failures and representative surfaces were evaluated. Data were analysed using anova and post-hoc tests, with P layer of sealer produced higher bond strength, except for the shear bond strength of EZ. Significant differences between thin and thick layers were found only in tensile bond strengths of AH and RS. Mixed type of failure was constantly found with all sealers. Bond strengths of thick layers of resin-based sealers to root dentine tended to be higher than with thin layers.

  10. Bonding of a mica-based castable ceramic material with a tri-n-butylborane-initiated adhesive resin.

    Science.gov (United States)

    Morikawa, T; Matsumura, H; Atsuta, M

    1996-07-01

    Adhesive bonding of a mica-based castable ceramic material (Olympus Castable Ceramics, OCC) was evaluated in vitro with the use of a silane primer in conjunction with an adhesive luting material. The primer contained a silane coupler and 4-methacryloxyethyl trimellitate anhydride (4-META), while the methyl methacrylate (MMA)-based luting agent was initiated with a tri-n-butylborane derivative (TBB) and contained 4-META (4-META/MMA-TBB resin). Ceramic specimens were sanded with No. 600 silicon carbide paper followed by blasting with alumina and/or etching with ammonium bifluoride. The specimens were bonded with various combinations and shear bond strengths were determined. Both priming and alumina blasting enhanced the bond between 4-META resin and OCC. Although etching with ammonium bifluoride roughened the ceramic surface, this procedure did not improve the bond strength. Electron probe microanalysis of the ceramic surface revealed a decrease in silicon and aluminium elements after etching with ammonium bifluoride.

  11. Selective degradation of organic dyes by a resin modified Fe-based metal-organic framework under visible light irradiation

    Science.gov (United States)

    Araya, Tirusew; Chen, Chun-cheng; Jia, Man-ke; Johnson, David; Li, Ruiping; Huang, Ying-ping

    2017-02-01

    Metal organic frameworks (MOFs), a new class of porous crystalline materials have attracted attention because of potential applications in environmental remediation. In this work, an Fe-based MOF, FeBTC (BTC = 1,3,5-tricarboxylic acid), was successfully modified with Amberlite IRA-200 resin to yield a novel heterogeneous photocatalyst, A@FeBTC. The modification resulted in higher photocatalytic activity than FeBTC under the same conditions. After 60 min of visible light illumination (λ ≥ 420 nm) 99% of rhodamine B was degraded. The modification lowers the zeta potential, enhancing charge-based selective adsorption and subsequent photocatalytic degradation of cationic dye pollutants. The composite also improved catalyst stability and recyclability by significantly reducing loss of iron leaching. Photoluminescence studies show that introduction of the resin reduces the recombination rate of photogenerated charge carriers thereby improving the photocatalytic activity of the composite. Finally, a plausible photocatalytic reaction mechanism is proposed.

  12. Characteristics of low polymerization shrinkage flowable resin composites in newly-developed cavity base materials for bulk filling technique.

    Science.gov (United States)

    Nitta, Keiko; Nomoto, Rie; Tsubota, Yuji; Tsuchikawa, Masuji; Hayakawa, Tohru

    2017-06-23

    The purpose of this study was to evaluate polymerization shrinkage and other physical properties of newly-developed cavity base materials for bulk filling technique, with the brand name BULK BASE (BBS). Polymerization shrinkage was measured according to ISO/FDIS 17304. BBS showed the significantly lowest polymerization shrinkage and significantly higher depth of cure than conventional flowable resin composites (p<0.05). The Knoop hardness, flexural strength and elastic modulus of that were significantly lower than conventional flowable resin composites (p<0.05). BBS had the significantly greatest filler content (p<0.05). SEM images of the surface showed failure of fillers. The lowest polymerization shrinkage was due to the incorporation of a new type of low shrinkage monomer, which has urethane moieties. There were no clear correlations between inorganic filler contents and polymerization shrinkage, flexural strength and elastic modulus. In conclusion, the low polymerization shrinkage of BBS will be useful for cavity treatment in dental clinics.

  13. In vitro tensile bond strength of denture repair acrylic resins to primed base metal alloys using two different processing techniques.

    Science.gov (United States)

    Banerjee, Sarmistha; Engelmeier, Robert L; O'Keefe, Kathy L; Powers, John M

    2009-12-01

    Approximately 38% of removable partial denture (RPD) failures involve fracture at the alloy/acrylic interface. Autopolymerizing resin is commonly used to repair RPDs. Poor chemical bonding of repair acrylic to base metal alloys can lead to microleakage and failure of the bond. Therefore, ideal repair techniques should provide a strong, adhesive bond. This investigation compared the tensile bond strength between cobalt-chromium (Super Cast, Pentron Laboratory Technologies, Llc., Wallingford, CT) and nickel-chromium (Rexalloy, Pentron Laboratory Technologies, Llc.) alloys and autopolymerized acrylic resin (Dentsply Repair Material, Dentsply Int, Inc, York, Pa) using three primers containing different functional monomers [UBar (UB), Sun Medical Co., Ltd., Shiga, Japan: Alloy Primer (AP) Kuraray Medical Inc., Okayama, Japan; and MR Bond (MRB) Tokyuyama Dental Corp., Tokyo, Japan] and two processing techniques (bench cure and pressure-pot cure). One hundred and twenty eight base metal alloy ingots were polished, air abraded, and ultrasonically cleaned. The control group was not primed. Specimens in the test groups were primed with one of the three metal primers. Autopolymerized acrylic resin material was bonded to the metal surfaces. Half the specimens were bench cured, and the other half were cured in a pressure pot. All specimens were stored in distilled water for 24 hours at 37 degrees C. The specimens were debonded under tension at a crosshead speed of 0.05 cm/min. The forces at which the bond failed were noted. Data were analyzed using ANOVA. Fisher's PLSD post hoc test was used to determine significant differences (p effect on bond strength of all specimens except Co-Cr alloy primed with UB. The highest bond strength was observed for both Co-Cr and Ni-Cr alloys that were sandblasted, primed with MRB, and pressure-pot cured. Co-Cr alloys primed with UB had the lowest bond strength whether bench cured or pressure-pot cured. Primed specimens generally experienced

  14. Demonstrating a directional detector based on neon for characterizing high energy neutrons

    CERN Document Server

    Hexley, A; Spitz, J; Conrad, J M

    2015-01-01

    MITPC is a gas-based time projection chamber used for detecting fast, MeV-scale neutrons. The standard version of the detector relies on a mixture of 600~torr gas composed of 87.5% $^4$He and 12.5% CF$_4$ for precisely measuring the energy and direction of neutron-induced nuclear recoils. We describe studies performed with a prototype detector investigating the use of Ne, as a replacement for $^4$He, in the gas mixture. Our discussion focuses on the advantages of Ne as the fast neutron target for high energy neutron events ($\\lesssim$100 MeV) and a demonstration that the mixture will be effective for this event class. We find that the achievable gain and transverse diffusion of drifting electrons in the Ne mixture are acceptable and that the detector uptime lost due to voltage breakdowns in the amplification plane is negligible, compared to $\\sim$ 20% with the $^4$He mixture.

  15. Demonstrating a directional detector based on neon for characterizing high energy neutrons

    Science.gov (United States)

    Hexley, Allie

    2016-03-01

    MITPC is a gas-based time projection chamber used for detecting fast, MeV-scale neutrons. The standard version of the detector relies on a mixture of 600 torr gas composed of 87.5% helium-4 and 12.5% tetrafluoromethane for precisely measuring the energy and direction of neutron-induced nuclear recoils. I describe studies performed with a prototype detector investigating the use of neon, as a replacement for helium-4, in the gas mixture. My discussion focuses on the advantages of neon as the fast neutron target for high energy neutron events (100 MeV) and a demonstration that the mixture will be effective for this event class. I show that the achievable gain and transverse diffusion of drifting electrons in the neon mixture are acceptable and that the detector uptime lost due to voltage breakdowns in the amplification plane is negligible, compared to 20% with the helium-4 mixture.

  16. Characterisation of an accelerator-based neutron source for BNCT of explanted livers

    Energy Technology Data Exchange (ETDEWEB)

    Agosteo, S. [Politecnico di Milano (Italy). Dipartimento di Ingeneria Nucleare; Colautti, P. [INFN, Padova (Italy). Laboratori Nazionali di Legnaro; Corrado, M.G. [Universita degli Studi di Milano (Italy). Dipartimento di Fisica; d`Errico, F. [Pisa Univ. (Italy). Dipt. di Costruzioni Meccaniche e Nucleari; Matzke, M. [Physikalisch-Technische Bundesanstalt, Braunschweig (Germany); Monti, S.; Tinti, R. [ENEA-ERG-FIRE, Bologna (Italy); Silari, M. [Consiglio Nazionale delle Ricerche, Milan (Italy)

    1997-09-01

    An accelerator-based thermal neutron source for BNCT of the explanted liver was designed using the MCNP code. Neutrons are generated via (d,n) reactions by 7 MeV deuterons bombarding a beryllium target. The therapy constraints were approached by simulating an irradiation cavity placed inside a graphite reflector parallelepiped containing a heavy-water moderator in turn enclosing the beryllium target. The experimental verification was performed at the Laboratori Nazionali di Legnaro (Italy). The thermal and epithermal neutron flux was measured at various positions in the irradiation cavity by means of activation techniques employing bare and cadmium covered indium foils. Further measurements were performed with BF{sub 3} detectors. The fast neutron component of the dose equivalent and the energy spectrum above 100keV were assessed by means of a recently developed technique employing variable threshold superheated drop detectors. The prompt gamma ray dose was measured with {sup 7}LiF TLDs. (author).

  17. Influence of surface preparation on fracture load of resin composite-based repairs

    Science.gov (United States)

    Mateos-Palacios, Rocío; Román-Rodríguez, Juan-Luis; Solá-Ruíz, María-Fernanda; Fons-Font, Antonio

    2015-01-01

    The purpose of the present study is to evaluate the fracture load of composite-based repairs to fractured zirconium oxide (Z) crowns and to ceramic-fused-to-metal (CM) crowns, comparing different mechanical surface preparation methods. A total of 75 crowns were repaired; samples then underwent dynamic loading and thermocycling. Final fracture load values for failure of the repaired crowns were measured and the type of fracture registered. Group I: CM: Surface preparation with a diamond bur + 9.5% Hydrofluoric Acid (HF) etching; Group II): CM: air-particle (Al2O3) + 9.5% HF; Group III: CM: Silica coating (SiO2); Group IV): Z: air-particle (Al2O3) + HF 9.5%; Group V) Z: Silica coating (SiO2). Of the three CM groups, Group I (CM-diamond bur) showed the highest mean failure value, with significant difference in comparison with Group III (CM-silica coating). For the zirconia groups, the highest value was obtained by Group V (silica coating). Key words:Crown, ceramic-fused-to-metal, zirconia, resin-composite, ceramic covering. PMID:25810848

  18. Synthesis and characterization of a novel bio-based resin from maleated soybean oil polyols

    Science.gov (United States)

    Li, Y. T.; Yang, L. T.; Zhang, H.

    2017-02-01

    In this paper, a novel bio-based resin was prepared by the radical copolymerization of maleated soybean oil polyols (MSBOP) and styrene (ST). Structure of the product was studied by Fourier transformation infrared spectrometer (FT-IR), and the result was found to be consistent with that of theoretical structure. Swelling experiments indicated that the crosslinking degree increased with the increase of hydroxyl value. Thermal analysis by differential scanning calorimetry (DSC) and thermo-gravimetric analysis (TG) revealed that glass transition temperature (Tg) of the polymer increased with increasing hydroxyl values, and that its thermal stability showed a good correlation with the hydroxyl value. The tensile strength and impact strength were significantly affected by the hydroxyl value of soybean oil polyols. With increasing hydroxyl value, the tensile strength presented an increasing trend, while the impact strength showed a decreasing one. Moreover, the property of the polymer from elastomer to plastic character also depended on the functionality of the hydroxyl value of soybean oil polyols.

  19. Influence of surface preparation on fracture load of resin composite-based repairs.

    Science.gov (United States)

    Agustín-Panadero, Rubén; Mateos-Palacios, Rocío; Román-Rodríguez, Juan-Luis; Solá-Ruíz, María-Fernanda; Fons-Font, Antonio

    2015-02-01

    The purpose of the present study is to evaluate the fracture load of composite-based repairs to fractured zirconium oxide (Z) crowns and to ceramic-fused-to-metal (CM) crowns, comparing different mechanical surface preparation methods. A total of 75 crowns were repaired; samples then underwent dynamic loading and thermocycling. Final fracture load values for failure of the repaired crowns were measured and the type of fracture registered. Group I: CM: Surface preparation with a diamond bur + 9.5% Hydrofluoric Acid (HF) etching; Group II): CM: air-particle (Al2O3) + 9.5% HF; Group III: CM: Silica coating (SiO2); Group IV): Z: air-particle (Al2O3) + HF 9.5%; Group V) Z: Silica coating (SiO2). Of the three CM groups, Group I (CM-diamond bur) showed the highest mean failure value, with significant difference in comparison with Group III (CM-silica coating). For the zirconia groups, the highest value was obtained by Group V (silica coating). Key words:Crown, ceramic-fused-to-metal, zirconia, resin-composite, ceramic covering.

  20. Influence of fluoride- or triclosan-based desensitizing agents on adhesion of resin cements to dentin.

    Science.gov (United States)

    Dündar, Mine; Cal, Ebru; Gökçe, Bülent; Türkün, Murat; Ozcan, Mutlu

    2010-10-01

    Effect of desensitizers on the bond strength of resin cements to dentin was evaluated. Intact premolars (N = 90) were embedded in polymethyl methacrylate; dentin surfaces were exposed, and they were randomly divided into two main groups of cements (Duolink (D), Variolink II (V); n = 45 per group) and then into three desensitizer subgroups (n = 15 per subgroup). Teeth in controls (C) were treated according to cements' adhesion protocols; the other two groups received either fluoride- [Aqua-Prep F (F)] or triclosan-based [Seal&Protect (T)] desensitizers. Ceramic disks (Empress 2) were adhered; specimens were thermocycled (×5,000 cycles, 5-55 ± 1°C, dwell time 30 s) and subjected to shear bond strength test (MPa ± SD) in a universal testing machine (crosshead speed 1 mm/min). Failure types were classified using scanning electron microscope. For V, application of both desensitizers (29.6 ± 7.8 and 22.8 ± 2.8 for F and T, respectively) did not present significantly different results than that of the VC (21.2 ± 2.3; p > 0.05, one-way ANOVA). In D, F (20.6 ± 2.4) showed significantly higher results (p types.

  1. Neutron imaging detector with 2 μm spatial resolution based on event reconstruction of neutron capture in gadolinium oxysulfide scintillators

    Science.gov (United States)

    Hussey, Daniel S.; LaManna, Jacob M.; Baltic, Elias; Jacobson, David L.

    2017-09-01

    We report on efforts to improve the achievable spatial resolution in neutron imaging by centroiding the scintillation light from gadolinium oxysulfide scintillators. The current state-of-the-art neutron imaging spatial resolution is about 10 μm, and many applications of neutron imaging would benefit from at least an order of magnitude improvement in the spatial resolution. The detector scheme that we have developed magnifies the scintillation light from a gadolinium oxysulfide scintillator, calculates the center of mass of the scintillation event, resulting in an event-based imaging detector with spatial resolution of about 2 μm.

  2. Influence of zirconium hydrophosphate nanoparticles on porous structure and sorption capacity of the composites based on ion exchange resin

    OpenAIRE

    Dzyazko, Yuliya; Ponomarova, Ludmila; Volfkovich, Yurii; Tsirina, Valentina; Sosenkin, Valentin; Nikolska, Nadiya; Belyakov, Volodimir

    2016-01-01

    Evolution of swelling of gel-like strongly acidic resin and organic-inorganic composites based on this ionexchanger was investigated. Non-aggregated nanoparticles of zirconium hydrophosphate were found to provide size invariability of the polymer pores, which contain functional groups (up to 20 nm), the nanoparticle aggregates squeeze these pores (down to 3 nm). Owing to this, the nanocomposite shows higher break-through capacity during removal of Ni2+ from water, than the sample modified onl...

  3. A new approach to influence contact angle and surface free energy of resin-based dental restorative materials.

    Science.gov (United States)

    Rüttermann, Stefan; Trellenkamp, Taina; Bergmann, Nora; Raab, Wolfgang H-M; Ritter, Helmut; Janda, Ralf

    2011-03-01

    The purpose of the present study was to identify novel delivery systems and active agents which increase the water contact angle and reduce the surface free energy when added to resin-based dental restorative materials. Two delivery systems based on zeolite or novel polymeric hollow beads (Poly-Pore), loaded with two low surface tension active agents (hydroxy functional polydimethylsiloxane and polydimethylsiloxane) or a polymerizable active agent (silicone polyether acrylate) were used to modify commonly formulated experimental dental resin composites. The non-modified resin was used as a standard (ST). Flexural strength, flexural modulus, water sorption, solubility, polymerization shrinkage, surface roughness Ra, contact angle θ, total surface free energy γS, and the apolar γSLW, polar γSAB, Lewis acid γS+ and base γS- components, and the active agents surface tensions γL were determined (Pmaterials had significantly higher θ but significantly lower γS, γSAB and γS- than the ST. A Poly-Pore/polydimethyl siloxane delivery system yielded the highest θ (110.9±3.5°) acceptable physical properties and the lowest values for γSLW and γS-. Among the modified materials the polymerizable materials containing active agents had the lowest γAB and the highest γS+ and γS-. Although not significant, both of the zeolite delivery systems yielded higher γSLW, γS+ and γS- but lower γSAB than the Poly-Pore delivery systems. Poly-Pore based delivery systems highly loaded with low surface tension active agents were found not to influence the physical properties but to significantly increase the water contact angle and thus reduce surface free energy of dental resin composites.

  4. Detection and quantification of monomers in unstimulated whole saliva after treatment with resin-based composite fillings in vivo.

    Science.gov (United States)

    Michelsen, Vibeke B; Kopperud, Hilde B M; Lygre, Gunvor B; Björkman, Lars; Jensen, Einar; Kleven, Inger S; Svahn, Johanna; Lygre, Henning

    2012-02-01

    Resin-based dental restorative materials contain allergenic methacrylate monomers, which may be released into saliva after restorative treatment. Monomers from resin-based composite materials have been demonstrated in saliva in vitro; however, studies analyzing saliva after restorative therapy are scarce. The aim of this study was to quantify methacrylate monomers in saliva after treatment with a resin-based composite filling material. Saliva was collected from 10 patients at four start points--before treatment, and 10 min, 24 h, and 7 d after treatment--and analysed by combined chromatography/mass spectrometry. The monomers bisphenol-A diglycidyl methacrylate (Bis-GMA), 2-hydroxyethyl methacrylate (HEMA), and urethane dimethacrylate (UDMA) were detected and quantified in the samples collected shortly (10 min) after treatment. The amounts detected ranged from 0.028 to 9.65 μg ml(-1) for Bis-GMA, from 0.015 to 0.19 μg ml(-1) for HEMA, and from 0.004 to 1.2 μg ml(-1) for UDMA. Triethyleneglycol dimethacrylate (TEGDMA) was detected in four of the samples. Ethoxylated bisphenol-A dimethacrylate (Bis-EMA) was not detected. Monomers were not detected in saliva samples collected before treatment, or 24 h or 7 d after treatment, with the exception of one sample, 24 h after treatment, in which HEMA was detected. In conclusion, monomers from the investigated resin-based composite and adhesive system were present in saliva shortly after treatment. One week after treatment, no monomers could be detected in patients' saliva samples.

  5. Efficacy and tolerability of a polysaccharide-resin-honey based cough syrup as compared to carbocysteine syrup for children with colds: a randomized, single-blinded, multicenter study

    National Research Council Canada - National Science Library

    Cohen, Herman Avner; Hoshen, Moshe; Gur, Shmuel; Bahir, Arie; Laks, Yoseph; Blau, Hannah

    2017-01-01

    .... The objective of this trial is to compare the effects of a polysaccharide-resin-honey based cough syrup, and carbocysteine syrups on nocturnal and daytime cough associated with childhood upper...

  6. Effect of artificial saliva and pH on shear bond strength of resin cements to zirconia-based ceramic.

    Science.gov (United States)

    Geramipanah, F; Majidpour, M; Sadighpour, L; Fard, M J Kharazi

    2013-03-01

    The aim of the present study was to evaluate the effect of media with different pH on shear and strength of resin cements to zirconia-based ceramics. Sixty rectangularly shaped specimens made of a zirconia based ceramic (Cercon, Dentsply) were prepared, air-blasted with 110 microm aluminum oxide particles (Al203) and randomly assigned into three groups (n = 30). A universal resin composite (Filtek Z250, 3M/ESPE) was bonded to each specimen using one of the following three cements: Calibra (Dentsply), Panavia F2 (kurary) and Unicem (3M/ESPE). Specimens were thermal cycled and stored in one of the following three media for two weeks: water at pH = 7, saliva at pH = 7 and saliva at pH = 3.5. The mean shear bond strength of each group was analyzed using the Kruskal-Wallis test (alpha = 0.05). The modes of failure were recorded using a streomicroscope. All specimens in the Calibra groups showed premature debonding. No significant difference was found between the two other cements or different media. The failure modes in the two latter cements were predominantly adhesive. Despite the adverse effect of acidic media on the properties of restorative materials, the media did not significantly influence the bond strength of MDP-containing resin cement and a self-adhesive cement to a zirconia- based ceramic.

  7. Bacterial Leakage Assessment for Different Types of Resin-Based Dental Restorations Applied Using Various Placement Methods

    Directory of Open Access Journals (Sweden)

    Horieh Moosavi

    2014-09-01

    Full Text Available Introduction: Although composite resins have improved greatly since their introduction, microleakage is one of the most frequently encountered problems. This study compared the effects of different monomer systems and layering techniques on the bacterial leakage of Cl I composite resin restorations. Methods: Eighty-two sound human third molars were used. The teeth were randomly divided into six groups of 12 teeth each and two positive and negative control groups of five teeth. Class I cavities, measuring 4×4×2 mm, were prepared. The first three groups were filled with a silorane-based composite (Filtek P90 using three different methods of filling (bulk, incremental and snowplow and the remaining three groups were filled with a methacrylate-based composite (Clearfil AP-X using the same techniques. The specimens were stored for 24 hours at 37°C and then thermocycled up to 1000 cycles. The bacterial leakage of the specimens was assessed in a microbiological laboratory and statistical analyses of data were performed by Fisher’s exact and chi-squared tests (P0.05. Conclusion: Leakage occurred similarly in both silorane- and methacrylate-based composite resins and three filling techniques.  

  8. Influence of radiopaque fillers on physicochemical properties of a model epoxy resin-based root canal sealer

    Directory of Open Access Journals (Sweden)

    Fabricio Mezzomo COLLARES

    2013-12-01

    Full Text Available Objective: To verify the influence of radiopaque fillers on an epoxy resin-based sealer. Material and Methods: Experimental sealers were formulated by adding 20%, 40%, 60%, 80%, 100% and 120% of calcium tungstate, ytterbium trifluoride or barium sulphate by weight to an epoxy-resin-base. Setting time, flow, film thickness, radiopacity, sorption, solubility, pH and push-out bond strength were evaluated. Results: The setting time ranged from 373 to 612.66 min, the flow varied from 13.81±0.49 to 22.49±0.37 mm, and the film thickness ranged from 16.67±5.77 to 33.33±11.54 µm. The lowest pH was 5.47±0.53, and the highest was 6.99±0.03. Radiopacity varied from 0.38±0.04 to 2.57±0.21 mmAl and increased with the amount of filler. Calcium tungstate sealers had a higher sorption and solubility than other sealers. There was no significant difference in the push-out bond strength among the fillers at the 120% concentration. CONCLUSION: The inorganic fillers evaluated and their concentrations affect the physicochemical properties of an epoxy resin-based root canal sealer.

  9. Development of a microstrip-based neutron detector

    Indian Academy of Sciences (India)

    S S Desai; A M Shaikh; V Radhakrishna; K Rajanna

    2004-08-01

    A gas-filled microstrip detector for thermal neutrons has been built and successfully tested in our laboratory. The detector has an active area of 20 mm × 15 mm and consists of alternate anodes and cathodes of widths 12 m and 300 m respectively. The anode to cathode gap is 150 m and the pitch is 612 m. A high resistance, meandering type horizontal strip connects the anodes at one end and aids in position sensing by charge division method. The detector is tested with gas mixtures 3He+Kr (1 : 2) and 3He+CF4 (2 : 1) at pressure of 3 atmospheres and using a Pu-Be neutron source. The pulse height spectrum shows energy resolution of ∼ 8% (FWHM) for the 764 keV peak at anode voltage of 525 V for 3He+Kr and ∼ 15% at anode voltage of 800 V for 3He+CF4. Gas gains up to 6.3 × 103 and 3.6 × 103 are obtained respectively with these gas mixtures. The overall efficiency of the detector along the sensitive length is tested by exposing the active area to neutrons and recording the position spectrum. The detector shows fairly uniform efficiency (∼ 45\\%) over the active length.

  10. SWELLING AND WETTABILITY OF LIGHT-CURED METHACRYLATE-BASED DENTAL RESINS PREPARED FROM CHOLIC ACID

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    2 '-methacryloxy-3α, 7α 12α- trimethacryloyl cholic acid ethyl ester (CAGE4MA) has been prepared from cholic acid. Photo-polymeric resins were prepared from CAGE4MA. 2,2-bis[4-(2-hydroxy-3-methacrylyloxypropoxy)phenyl]propane (bis-GMA) was used for comparison, triethyleneglycol dimethacrylate (TEGDMA) was used as diluent. The polymerization was initiated by camphoroquinone (CQ)/N, N-dimethylaminoethyl methacrylate (DMAEMA) system. The conversion of CAGE4MA was 39% when the reaction time is 60s, which is lower than bis-GMA and TEGDMA.The swelling value of CAGE4MA resin was 0.41% in distilled water, which is much lower than those of bis-GMA resin (2.04%) and TEGDMA resin (4.77%) under the same conditions. Copolymers from CAGE4MA and TEGDMA have been prepared. With the increase of TEGDMA in mixture, the degree of conversion of CA GE4MA and swelling value increased. The swelling values of photocured resins in 0. 1mol/L HCl were also measured.

  11. Effect of root canal filling techniques on the bond strength of epoxy resin-based sealers.

    Science.gov (United States)

    Rached-Júnior, Fuad Jacob Abi; Souza, Angélica Moreira; Macedo, Luciana Martins Domingues; Raucci-Neto, Walter; Baratto-Filho, Flares; Silva, Bruno Marques; Silva-Sousa, Yara Teresinha Corrêa

    2016-01-01

    The aim of this study was to evaluate the effects of different root canal filling techniques on the bond strength of epoxy resin-based sealers. Sixty single-rooted canines were prepared using ProTaper (F5) and divided into the following groups based on the root filling technique: Lateral Compaction (LC), Single Cone (SC), and Tagger Hybrid Technique (THT). The following subgroups (n = 10) were also created based on sealer material used: AH Plus and Sealer 26. Two-millimeter-thick slices were cut from all the root thirds and subjected to push-out test. Data (MPa) was analyzed using ANOVA and Tukey's test (α = 0.05). The push-out values were significantly affected by the sealer, filling technique, and root third (p < 0.05). AH Plus (1.37 ± 1.04) exhibited higher values than Sealer 26 (0.92 ± 0.51), while LC (1.80 ± 0.98) showed greater bond strength than THT (1.16 ± 0.50) and SC (0.92 ± 0.25). The cervical (1.45 ± 1.14) third exhibited higher bond strength, followed by the middle (1.20 ± 0.72) and apical (0.78 ± 0.33) thirds. AH Plus/LC (2.26 ± 1.15) exhibited the highest bond strength values, followed by AH Plus/THT (1.32 ± 0.61), Sealer 26/LC (1.34 ± 0.42), and Sealer 26/THT (1.00 ± 0.27). The lowest values were obtained with AH Plus/SC and Sealer 26/SC. Thus, it can be concluded that the filling technique affects the bond strength of sealers. LC was associated with higher bond strength between the material and intra-radicular dentine than THT and SC techniques.

  12. Removal of gadolinium, a neutron poison from the moderator system of nuclear reactors.

    Science.gov (United States)

    Rufus, A L; Kumar, Padma S; Jeena, K; Velmurugan, S

    2017-08-03

    Gadolinium as gadolinium nitrate is used as neutron poison in the moderator system for regulating and controlling the power generation of Pressurized Heavy Water Reactors (PHWR) and proposed to be used in Advanced Heavy Water Reactors (AHWR) owing to its high neutron absorption cross section. Removal of the added gadolinium nitrate (Gd(3+) and NO3(-)) from the system after its intended use is done using ion exchange resins. In the present investigation, attempts have been made to optimize the ion exchange process for generation of low radioactive waste and maximize utilization of the ion exchange resins by employing different types of resins and different modes of operation. The investigations revealed that use of mixed bed (MB) resin column consisting of Strong Acid Cation (SAC) resin and Strong Base Anion (SBA) resin followed by SAC resin column is efficient in removing the Gd(3+) and NO3(-) from the system besides maintaining the pH of the moderator system in the desirable regime, where gadolinium does not get precipitated as its hydroxide. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. RADIATION PERFORMANCE OF GAN AND INAS/GAAS QUANTUM DOT BASED DEVICES SUBJECTED TO NEUTRON RADIATION

    Directory of Open Access Journals (Sweden)

    Dhiyauddin Ahmad Fauzi

    2017-05-01

    Full Text Available In addition to their useful optoelectronics functions, gallium nitride (GaN and quantum dots (QDs based structures are also known for their radiation hardness properties. With demands on such semiconductor material structures, it is important to investigate the differences in reliability and radiation hardness properties of these two devices. For this purpose, three sets of GaN light-emitting diode (LED and InAs/GaAs dot-in-a well (DWELL samples were irradiated with thermal neutron of fluence ranging from 3×1013 to 6×1014 neutron/cm2 in PUSPATI TRIGA research reactor. The radiation performances for each device were evaluated based on the current-voltage (I-V and capacitance-voltage (C-V electrical characterisation method. Results suggested that the GaN based sample is less susceptible to electrical changes due to the thermal neutron radiation effects compared to the QD based sample.

  14. Streptococcus mutans counts in plaque adjacent to orthodontic brackets bonded with resin-modified glass ionomer cement or resin-based composite

    Directory of Open Access Journals (Sweden)

    Solange Machado Mota

    2008-03-01

    Full Text Available This study investigated the number of Streptococcus mutans CFU (colony forming units in the saliva and plaque adjacent to orthodontic brackets bonded with a glass ionomer cement - GIC (Fuji Ortho or a resin-based composite - RC (Concise. Twenty male and female patients, aged 12 to 20 years, participated in the study. Saliva was collected before and after placement of appliances. Plaque was collected from areas adjacent to brackets and saliva was again collected on the 15th, 30th, and 45th day after placement. On the 30th day, 0.4% stannous fluoride gel was applied for 4 minutes. No significant modification in the number of Streptococcus mutans CFU in saliva was observed after placement of the fixed orthodontic appliances. On the 15th day, the percentage of Streptococcus mutans CFU in plaque was statistically lower in sites adjacent to GIC-bonded brackets (mean = 0.365 than in those adjacent to RC-bonded brackets (mean = 0.935. No evidence was found of a contribution of GIC to the reduction of CFU in plaque after the 15th day. Topical application of stannous fluoride gel on the 30th day reduced the number of CFU in saliva, but not in plaque. This study suggests that the antimicrobial activity of GIC occurs only in the initial phase and is not responsible for a long-term anticariogenic property.

  15. Monitoring of polycyclic aromatic hydrocarbons (PAHs) in the atmosphere of southern Luxembourg using XAD-2 resin-based passive samplers.

    Science.gov (United States)

    Schummer, Claude; Appenzeller, Brice M; Millet, Maurice

    2014-02-01

    XAD-2 resin-based passive samplers (PAS) with dimensions adapted to 100 mL accelerated solvent extraction cells were used to study the temporal and spatial variations of 17 PAHs on five sites in the atmosphere of southern Luxembourg. This new design allowed extracting the PAS without emptying the resin from the shelter. PAH analyses were done with gas chromatography-tandem mass spectrometry. PAS were deployed for 1 year with varying sampling periodicities, and 16 PAHs were detected with concentrations ranging from 1 ng/PAS for chrysene to 9,727 ng/PAS for naphthalene. The PAS were found adapted to the monitoring of temporal and spatial variations for lightweight PAHs (up to four aromatic rings) though not for heavy PAHs with five aromatic rings or more, as these compounds are preferably in the particle phase of the atmosphere and the amount of these PAHs trapped on the PAS will be too low.

  16. Neutron generator for BNCT based on high current ECR ion source with gyrotron plasma heating.

    Science.gov (United States)

    Skalyga, V; Izotov, I; Golubev, S; Razin, S; Sidorov, A; Maslennikova, A; Volovecky, A; Kalvas, T; Koivisto, H; Tarvainen, O

    2015-12-01

    BNCT development nowadays is constrained by a progress in neutron sources design. Creation of a cheap and compact intense neutron source would significantly simplify trial treatments avoiding use of expensive and complicated nuclear reactors and accelerators. D-D or D-T neutron generator is one of alternative types of such sources for. A so-called high current quasi-gasdynamic ECR ion source with plasma heating by millimeter wave gyrotron radiation is suggested to be used in a scheme of D-D neutron generator in the present work. Ion source of that type was developed in the Institute of Applied Physics of Russian Academy of Sciences (Nizhny Novgorod, Russia). It can produce deuteron ion beams with current density up to 700-800 mA/cm(2). Generation of the neutron flux with density at the level of 7-8·10(10) s(-1) cm(-2) at the target surface could be obtained in case of TiD2 target bombardment with deuteron beam accelerated to 100 keV. Estimations show that it is enough for formation of epithermal neutron flux with density higher than 10(9) s(-1) cm(-2) suitable for BNCT. Important advantage of described approach is absence of Tritium in the scheme. First experiments performed in pulsed regime with 300 mA, 45 kV deuteron beam directed to D2O target demonstrated 10(9) s(-1) neutron flux. This value corresponds to theoretical estimations and proofs prospects of neutron generator development based on high current quasi-gasdynamic ECR ion source.

  17. Neutron imaging detector based on the {mu}PIC micro-pixel chamber

    Energy Technology Data Exchange (ETDEWEB)

    Parker, J.D., E-mail: jparker@cr.scphys.kyoto-u.ac.jp [Department of Physics, Graduate School of Science, Kyoto University, Kitashirakawa-oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan); Hattori, K.; Fujioka, H. [Department of Physics, Graduate School of Science, Kyoto University, Kitashirakawa-oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan); Harada, M. [Materials and Life Science Facility Division, Japan Atomic Energy Agency (JAEA), Tokai, Ibaraki 319-1195 (Japan); Iwaki, S.; Kabuki, S.; Kishimoto, Y.; Kubo, H.; Kurosawa, S.; Miuchi, K.; Nagae, T.; Nishimura, H. [Department of Physics, Graduate School of Science, Kyoto University, Kitashirakawa-oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan); Oku, T. [Materials and Life Science Facility Division, Japan Atomic Energy Agency (JAEA), Tokai, Ibaraki 319-1195 (Japan); Sawano, T. [Department of Physics, Graduate School of Science, Kyoto University, Kitashirakawa-oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan); Shinohara, T.; Suzuki, J. [Materials and Life Science Facility Division, Japan Atomic Energy Agency (JAEA), Tokai, Ibaraki 319-1195 (Japan); Takada, A.; Tanimori, T.; Ueno, K. [Department of Physics, Graduate School of Science, Kyoto University, Kitashirakawa-oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan)

    2013-01-01

    We have developed a prototype time-resolved neutron imaging detector employing the micro-pixel chamber ({mu}PIC), a micro-pattern gaseous detector, coupled with a field programmable gate array-based data acquisition system for applications in neutron radiography at high-intensity neutron sources. The prototype system, with an active area of 10 Multiplication-Sign 10 cm{sup 2} and operated at a gas pressure of 2 atm, measures both the energy deposition (via time-over-threshold) and three-dimensional track of each neutron-induced event, allowing the reconstruction of the neutron interaction point with improved accuracy. Using a simple position reconstruction algorithm, a spatial resolution of 349{+-}36{mu}m was achieved, with further improvement expected. The detailed tracking allows strong rejection of background gamma-rays, resulting in an effective gamma sensitivity of 10{sup -12} or less, coupled with stable, robust neutron identification. The detector also features a time resolution of 0.6{mu}s.

  18. Industrial resin inspection for display production using automated fluid-inspection based on multimodal optical detection techniques

    Science.gov (United States)

    Wijesinghe, Ruchire Eranga; Park, Kibeom; Jung, Yeongri; Kim, Pilun; Jeon, Mansik; Kim, Jeehyun

    2017-09-01

    The large-scale liquid-crystal display (LCD) industry requires an accurate inspection system for identifying defects, as the LCD quality can be drastically degraded because of defects. In particular, the refractive index of LCD panels can be changed by internal micrometer-range substances, which form as a result of defectiveness and the insufficient solidification of industrial liquid resins. Intrinsically, the defect inspection of the raw materials must be performed prior to the LCD manufacturing process. Thus, optical coherence tomography (OCT) based automated fluid-inspection (AFI) methodology was introduced to demarcate and enumerate the defects in industrial liquid resins and the final product (LCD smartphone). The accuracy of the method was enhanced by implementing an intensity-detection algorithm. Subsequently, the optimal solidification rates of liquid resins were investigated using a fluorescence sensor-based ultraviolet hardening method to prevent the formation of defects between the internal layers of the LCD panel. Therefore, AFI can be implemented as an effective and cost-saving method in the smartphone industry for improving the quality of the final product.

  19. An accelerator-based epithermal neutron beam design for BNCT and dosimetric evaluation using a voxel head phantom.

    Science.gov (United States)

    Lee, Deok-jae; Han, Chi Young; Park, Sung Ho; Kim, Jong Kyung

    2004-01-01

    The beam shaping assembly design has been investigated in order to improve the epithermal neutron beam for accelerator-based boron neutron capture therapy in intensity and quality, and dosimetric evaluation for the beams has been performed using both mathematical and voxel head phantoms with MCNP runs. The neutron source was assumed to be produced from a conventional 2.5 MeV proton accelerator with a thick (7)Li target. The results indicate that it is possible to enhance epithermal neutron flux remarkably as well as to embody a good spectrum shaping to epithermal neutrons only with the proper combination of moderator and reflector. It is also found that a larger number of thermal neutrons can reach deeply into the brain and, therefore, can reduce considerably the treatment time for brain tumours. Consequently, the epithermal neutron beams designed in this study can treat more effectively deep-seated brain tumours.

  20. Effect of LED-LCU light irradiance distribution on mechanical properties of resin based materials

    Energy Technology Data Exchange (ETDEWEB)

    Magalhães Filho, T.R.; Weig, K.M. [Faculdade de Odontologia, Universidade Federal Fluminense, Rua São Paulo 28, CEP 24020-150 Niterói (Brazil); Engenharia Metalúrgica e de Materiais (COPPE), Universidade Federal do Rio de Janeiro, CP 68505, CEP: 21941-972 Rio de Janeiro (Brazil); Costa, M.F. [Engenharia Metalúrgica e de Materiais (COPPE), Universidade Federal do Rio de Janeiro, CP 68505, CEP: 21941-972 Rio de Janeiro (Brazil); Werneck, M.M. [Engenharia Elétrica (COPPE), Universidade Federal do Rio de Janeiro, CP 68504, CEP: 21941-972 Rio de Janeiro (Brazil); Barthem, R.B. [Instituto de Física, Universidade Federal do Rio de Janeiro, CP 68528, CEP: 21941-972 Rio de Janeiro (Brazil); Costa Neto, C.A., E-mail: celio@metalmat.ufrj.br [Engenharia Metalúrgica e de Materiais (COPPE), Universidade Federal do Rio de Janeiro, CP 68505, CEP: 21941-972 Rio de Janeiro (Brazil)

    2016-06-01

    The objective of this study is to analyze the light power distribution along the tip end of the light guide of three LED-LCUs (Light Curing Units) and to evaluate its effect on the mechanical properties of a polymer based dental composite. Firstly, the light power distribution over the whole area of LED-LCU light guide surface was analyzed by three methods: visual projection observation, spectral measurement and optical spectral analysis (OSA). The light power distribution and the total irradiance were different for the three LEDs used, but the wavelength was within the camphorquinone absorption spectrum. The use of a blank sheet was quite on hand to make a qualitative analysis of a beam, and it is costless. Secondly, specimens of a hybrid composite with approximately 8 mm diameter and 2 mm thickness were produced and polymerized by 20 s exposition time to each LED-LCU. Thirdly, the elastic modulus (E) and hardness (HV) were measured throughout the irradiated area by instrumented micro-indentation test (IIT), allowing to correlate localized power and mechanical properties. Both E and HV showed to be very sensitive to local power and wavelength dependent, but they followed the beam power profile. It was also shown that the mechanical properties could be directly correlated to the curing process. Very steep differences in mechanical properties over very short distances may impair the material performance, since residual stresses can easily be built over it. - Highlights: • A resin based composite (RBC) was polymerized by three different Light Emitting Diodes. • Each LED had its beam profile visually, wavelength and power analyzed. • The effective polymerization power (EPP) varied from 28% to 52% of the total beam power. • Wavelength seems to be as relevant as power in the light curing process. • Mechanical properties depend on the simultaneous effect of wavelength and power.

  1. Development of a 6LiF/ZnS-based Neutron Multiplicity Counter

    Energy Technology Data Exchange (ETDEWEB)

    Stave, Sean C.; Behling, Richard S.; Bernacki, Bruce E.; Bliss, Mary; Cowles, Christian C.; Kouzes, Richard T.; Lintereur, Azaree; Robinson, Sean M.; Siciliano, Edward R.

    2016-10-06

    Abstract–Neutron multiplicity counters are used in safeguards to provide rapid assay of samples which contain an unknown amount of plutonium in a potentially unknown configuration. A project at PNNL is using regular and nickel-quenched 6LiF/ZnS neutron-scintillator sheets and wavelength shifting plastic for light pipes in place of 3He. A combination of laboratory and modeling work predicts a LiF/ZnS-based system to be able to match or exceed the performance of the best 3He-based systems available. Also, the Ni-quenched material is expected to allow for improved neutron/gamma-ray discrimination at twice the event rate relative to the non-Ni-quenched LiF/ZnS. A new system based on the LiF/ZnS material is under construction and components are being used to optimize the detection efficiency and neutron/gamma-ray discrimination properties. Components of the new system are partially constructed and undergoing performance testing utilizing high-speed digitizers with field programmable gate arrays to perform the neutron/gamma-ray discrimination. The expected performance of the full-scale system is expected to be nearly the same as for 3He-based systems and is due for completion in 2016.

  2. Effect of resin content and substrate on the emission of BTEX and carbonyls from low-VOC water-based wall paint.

    Science.gov (United States)

    Zhao, Ping; Cheng, Yu-Hsiang; Lin, Chi-Chi; Cheng, Yu-Lin

    2016-02-01

    The primary aim of this work is to explore the effect of resin content and the effect of substrate on the emission of benzene, toluene, ethylbenzene, and xylene (BTEX) and carbonyls from low-VOC water-based wall paint. Four low-volatile organic compound (VOC) paints include paints A (20% acrylic), B (30% acrylic), C (20% polyvinyl acetate), and D (30% polyvinyl acetate) were painted on stainless steel specimen for the study of resin effect. Green calcium silicate, green cement, and stainless steel were painted with paints A and C for the study of substrate effect. Concentrations of the VOCs in the chamber decreased with the elapsed time. Both resin type and resin quantity in paint had effects on VOC emissions. Paints with acrylic resin emitted less BTEX and carbonyls than paints with polyvinyl acetate resin. However, the effects of resin quantity varied with VOCs. Porous substrates were observed to interact more strongly with paints than inert substrates. Both green calcium silicate and green cement substrates have strong power of adsorption of VOCs from wall paints, namely toluene, formaldehyde, acetaldehyde, 2-butanone, methacrolein, butyraldehyde, and benzaldehyde. Some compounds like toluene, formaldehyde, and butyaldehyde were desorbed very slowly from green calcium silicate and green cement substrates.

  3. Monte Carlo simulation of moderator and reflector in coal analyzer based on a D-T neutron generator.

    Science.gov (United States)

    Shan, Qing; Chu, Shengnan; Jia, Wenbao

    2015-11-01

    Coal is one of the most popular fuels in the world. The use of coal not only produces carbon dioxide, but also contributes to the environmental pollution by heavy metals. In prompt gamma-ray neutron activation analysis (PGNAA)-based coal analyzer, the characteristic gamma rays of C and O are mainly induced by fast neutrons, whereas thermal neutrons can be used to induce the characteristic gamma rays of H, Si, and heavy metals. Therefore, appropriate thermal and fast neutrons are beneficial in improving the measurement accuracy of heavy metals, and ensure that the measurement accuracy of main elements meets the requirements of the industry. Once the required yield of the deuterium-tritium (d-T) neutron generator is determined, appropriate thermal and fast neutrons can be obtained by optimizing the neutron source term. In this article, the Monte Carlo N-Particle (MCNP) Transport Code and Evaluated Nuclear Data File (ENDF) database are used to optimize the neutron source term in PGNAA-based coal analyzer, including the material and shape of the moderator and neutron reflector. The optimized targets include two points: (1) the ratio of the thermal to fast neutron is 1:1 and (2) the total neutron flux from the optimized neutron source in the sample increases at least 100% when compared with the initial one. The simulation results show that, the total neutron flux in the sample increases 102%, 102%, 85%, 72%, and 62% with Pb, Bi, Nb, W, and Be reflectors, respectively. Maximum optimization of the targets is achieved when the moderator is a 3-cm-thick lead layer coupled with a 3-cm-thick high-density polyethylene (HDPE) layer, and the neutron reflector is a 27-cm-thick hemispherical lead layer.

  4. Neutron dosimetry; Dosimetria de neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Fratin, Luciano

    1993-12-31

    A neutron irradiation facility was designed and built in order to establish a procedure for calibrating neutron monitors and dosemeters. A 185 GBq {sup 241} Am Be source of known is used as a reference source. The irradiation facility using this source in the air provides neutron dose rates between 9 nSv s{sup -1} and 0,5 {sup {mu}}Sv s{sup -1}. A calibrated 50 nSv s{sup -1} thermal neutron field is obtained by using a specially designed paraffin block in conjunction with the {sup 241} Am Be source. A Bonner multisphere spectrometer was calibrated, using a procedure based on three methods proposed by international standards. The unfold {sup 241} Am Be neutron spectrum was determined from the Bonner spheres data and resulted in a good agreement with expected values for fluence rate, dose rate and mean energy. A dosimetric system based on the electrochemical etching of CR-39 was developed for personal dosimetry. The dosemeter badge using a (n,{alpha}) converter, the etching chamber and high frequency power supply were designed and built specially for this project. The electrochemical etching (ECE) parameters used were: a 6N KOH solution, 59 deg C, 20 kV{sub pp} cm{sup -1}, 2,0 kHz, 3 hours of ECE for thermal and intermediate neutrons and 6 hours for fast neutrons. The calibration factors for thermal, intermediate and fast neutrons were determined for this personal dosemeter. The sensitivities determined for the developed dosimetric system were (1,46{+-} 0,09) 10{sup 4} tracks cm{sup -2} mSv{sup -1} for thermal neutrons, (9{+-}3) 10{sup 2} tracks cm{sup -2} mSV{sup -1} for intermediate neutrons and (26{+-}4) tracks cm{sup -2} mSv{sup -1} for fast neutrons. The lower and upper limits of detection were respectively 0,002 mSv and 0,6 mSv for thermal neutrons, 0,04 mSv and 8 mSv for intermediate neutrons and 1 mSv and 12 mSv for fast neutrons. In view of the 1990`s ICRP recommendations, it is possible to conclude that the personal dosemeter described in this work is

  5. A neutron spectrum unfolding code based on generalized regression artificial neural networks

    Energy Technology Data Exchange (ETDEWEB)

    Ortiz R, J. M.; Martinez B, M. R.; Castaneda M, R.; Solis S, L. O. [Universidad Autonoma de Zacatecas, Unidad Academica de Ingenieria Electrica, Av. Ramon Lopez Velarde 801, Col. Centro, 98000 Zacatecas, Zac. (Mexico); Vega C, H. R., E-mail: morvymm@yahoo.com.mx [Universidad Autonoma de Zacatecas, Unidad Academica de Estudios Nucleares, Cipres No. 10, Fracc. La Penuela, 98068 Zacatecas, Zac. (Mexico)

    2015-10-15

    The most delicate part of neutron spectrometry, is the unfolding process. Then derivation of the spectral information is not simple because the unknown is not given directly as result of the measurements. Novel methods based on Artificial Neural Networks have been widely investigated. In prior works, back propagation neural networks (BPNN) have been used to solve the neutron spectrometry problem, however, some drawbacks still exist using this kind of neural nets, as the optimum selection of the network topology and the long training time. Compared to BPNN, is usually much faster to train a generalized regression neural network (GRNN). That is mainly because spread constant is the only parameter used in GRNN. Another feature is that the network will converge to a global minimum. In addition, often are more accurate than BPNN in prediction. These characteristics make GRNN be of great interest in the neutron spectrometry domain. In this work is presented a computational tool based on GRNN, capable to solve the neutron spectrometry problem. This computational code, automates the pre-processing, training and testing stages, the statistical analysis and the post-processing of the information, using 7 Bonner spheres rate counts as only entrance data. The code was designed for a Bonner Spheres System based on a {sup 6}LiI(Eu) neutron detector and a response matrix expressed in 60 energy bins taken from an International Atomic Energy Agency compilation. (Author)

  6. Epoxy resins.

    Science.gov (United States)

    Bray, P G

    1999-01-01

    Epoxy resins have an extraordinarily broad range of commercial applications, especially as protective surface coatings and adhesives. Epoxy resin systems include combinations of epoxy monomers, hardeners, reactive diluents, and/or a vast array of other additives. As a result, an epoxy resin system may have a number of chemical ingredients with the potential for attendant health hazards. Most, but not all, of these health hazards arise in the occupational setting. The most frequent adverse effects are irritation or allergic mechanisms involving the dermal and respiratory systems. Sensitization usually is caused by low molecular weight or short-chain compounds. This review discusses the diagnosis, treatment, and prevention of epoxy resin-related adverse health effects.

  7. Demonstration of a high-intensity neutron source based on a liquid-lithium target for Accelerator based Boron Neutron Capture Therapy.

    Science.gov (United States)

    Halfon, S; Arenshtam, A; Kijel, D; Paul, M; Weissman, L; Berkovits, D; Eliyahu, I; Feinberg, G; Kreisel, A; Mardor, I; Shimel, G; Shor, A; Silverman, I; Tessler, M

    2015-12-01

    A free surface liquid-lithium jet target is operating routinely at Soreq Applied Research Accelerator Facility (SARAF), bombarded with a ~1.91 MeV, ~1.2 mA continuous-wave narrow proton beam. The experiments demonstrate the liquid lithium target (LiLiT) capability to constitute an intense source of epithermal neutrons, for Accelerator based Boron Neutron Capture Therapy (BNCT). The target dissipates extremely high ion beam power densities (>3 kW/cm(2), >0.5 MW/cm(3)) for long periods of time, while maintaining stable conditions and localized residual activity. LiLiT generates ~3×10(10) n/s, which is more than one order of magnitude larger than conventional (7)Li(p,n)-based near threshold neutron sources. A shield and moderator assembly for BNCT, with LiLiT irradiated with protons at 1.91 MeV, was designed based on Monte Carlo (MCNP) simulations of BNCT-doses produced in a phantom. According to these simulations it was found that a ~15 mA near threshold proton current will apply the therapeutic doses in ~1h treatment duration. According to our present results, such high current beams can be dissipated in a liquid-lithium target, hence the target design is readily applicable for accelerator-based BNCT.

  8. Sifat fisik hidroksiapatit sintesis kalsit sebagai bahan pengisi pada sealer saluran akar resin epoxy (Physical properties of calcite synthesized hydroxyapatite as the filler of epoxy-resin-based root canal sealer

    Directory of Open Access Journals (Sweden)

    Ema Mulyawati

    2013-12-01

    Full Text Available Background: The filler addition to resin based sealers will enhance the physical properties of the polymer. Because of its biological properties, the synthetic hydroxyapatite (HA has been proposed as filler for dental material such as composite resin. The calcite synthesized HA is the HA produced of calcite minerals that came from many Indonesian mining. Purpose: The aim of study was to determine the effect of different concentration of calcite synthesized HA as the filler of the epoxy-resin-based root canal sealer on the physical properties such as its contact angle, the film thickness and the microhardness. Methods: The crystal of the calcite synthesized hydroxyapatite with the size between 77.721-88.710 nm and the ratio of Ca/P 1.6886 were synthesized at Ceramic Laboratory, Mechanical Engineering, using wet method of hydrothermal microwave. The powders of the epoxy- resin were prepared by added the synthesized hydroxyapatite crystal in 5 different weight ratios (e.g.: HA-10%, HA-20%, HA-30%, HA-40% and HA-50%. Each of these was mixed with the paste of 3:1 ratio using spatula on a glass plate until homogen and then measuring the contact angle and the film thickness. Microhardness test was conducted after the mixture of experimental sealer was stored for 24 hrs at 37 oC to reach perfect polymerization. Results: All of contact angles were <90o and were not significantly different to each other (p= 0.510. All groups had a film thickness in accordance with ISO 6876 (<50 um and with no statistical difference (p= 0.858. In the HA of 10%, 20%, 30% seen that the microhardness were increased, while in the HA-50% was decreased and in the HA-40% has the same microhardness to the control groups (HA-0%. Conclusion: Calcite synthesized HA as the filler did not affect contact angle and film thickness of the sealer. Microhardness of the epoxy-resin based sealer could be increased using maximum 30% of the calcite synthesized HA as the filler.Latar belakang

  9. Influence of Coating with Some Natural Based Materials on the Erosion Wear Behavior of Glass Fiber Reinforced Epoxy Resin

    Directory of Open Access Journals (Sweden)

    Aseel Basim Abdul Hussein

    2015-06-01

    Full Text Available In the present study, composites were prepared by Hand lay-up molding. The composites constituents were epoxy resin as a matrix, 6% volume fractions of glass fibers (G.F as reinforcement and 3%, 6% volume fractions of preparation natural material (Rice Husk Ash, Carrot Powder, and Sawdust as filler. Studied the erosion wear behavior and coating by natural wastes (Rice Husk Ash with epoxy resin after erosion. The results showed the non – reinforced epoxy have lower resistance erosion than natural based material composites and the specimen (Epoxy+6%glass fiber+6%RHA has higher resistance erosion than composites reinforced with carrot powder and sawdust at 30cm , angle 60°, grin size of sand 425µm , temperature 30Ċ , 300 gm salt content in 2liter of water and 15 hour. Coating specimen with mixed epoxy resin -RHA with particles size in the range (1.4-4.2 µm improves erosion wear resistance characteristics of the coated specimen, coating thickness was (16 ± 1 μm and after erosion at (15 hour the thickness was (10 μm .

  10. Influence of light-curing mode on the cytotoxicity of resin-based surface sealants

    Science.gov (United States)

    2014-01-01

    Background Surface sealants have been successfully used in the prevention of erosive tooth wear. However, when multiple tooth surfaces should be sealed, the light-curing procedure is very time-consuming. Therefore, the aim of this study was to investigate whether reduced light-curing time (while maintaining similar energy density) has an influence on resin-based surface sealant cytotoxicity. Methods Bovine dentine discs were treated as follows: group 1: untreated, groups 2–5: Seal&Protect and groups 6–9: experimental sealer. Groups 2 and 6 were light-cured (VALO LED light-curing device) for 40 s (1000 mW/cm2), groups 3 and 7 for 10 s (1000 mW/cm2), groups 4 and 8 for 7 s (1400 mW/cm2) and groups 5 and 9 for 3 s (3200 mW/cm2). Later, materials were extracted in culture medium for 24 h, and released lactate dehydrogenase (LDH) activity as a measure of cytotoxicity was determined photometrically after cells (dental pulp cells and gingival fibroblasts) were exposed to the extracts for 24 h. Three independent experiments, for both sample preparation and cytotoxicity testing, were performed. Results Overall, lowest cytotoxicity was observed for the unsealed control group. No significant influence of light-curing settings on the cytotoxicity was observed (p = 0.537 and 0.838 for pulp cells and gingival fibroblasts, respectively). No significant difference in the cytotoxicity of the two sealants was observed after light-curing with same light-curing settings (group 2 vs. 6, 3 vs. 7, 4 vs. 8 and 5 vs. 9: p > 0.05, respectively). Conclusions Shortening the light-curing time, while maintaining constant energy density, resulted in no higher cytotoxicity of the investigated sealants. PMID:24885810

  11. Comparison of cytotoxicity test models for evaluating resin-based composites.

    Science.gov (United States)

    Lim, S M; Yap, Auj; Loo, Csl; Ng, J; Goh, C Y; Hong, Chl; Toh, W S

    2017-04-01

    This study compared different cytotoxicity test models for evaluating resin-based composites (RBCs) and assessed the biocompatibility of standard and bulk-fill RBCs. A standard (spectrum TPH) and a bulk-fill (smart dentin replacement (SDR)) RBC were selected. Disc-shaped specimens (7 mm diameter) of 2 and 4 mm thickness were polymerized for 20 s with a LED curing light of 700 mW/cm(2) irradiance. The specimens ( n = 5) were subjected to micro-hardness testing and three cytotoxicity test models (direct contact, indirect contact and extract tests) with the established L-929 cell line. Hardness ratios of top and bottom surfaces of specimens were computed to assess the effectiveness of cure. For the direct and indirect contact tests, the cells were stained and zones of inhibition were analyzed after material contact for 24 h. For the extract test, cells were exposed to extracts for 24 h, and cell viability was measured. Data was analyzed using analysis of variance/Scheffe's post hoc test and Pearson's correlation ( p cytotoxicity were observed for TPH at 4 mm. At 4-mm thickness, SDR was found to be biocompatible with all three models. Correlations between hardness ratio and cell viability ranged from r = 0.89-0.96 for the various tests. A significant correlation ( r = 0.97) was also observed between the three test models. Our data indicated consistency between direct contact, indirect contact and extract test models for cytotoxicity testing of RBCs. Bulk placement and curing at 4 mm for the bulk-fill RBC evaluated did not result in undue cytotoxicity.

  12. Development of palm oil-based UV-curable epoxy acrylate and urethane acrylate resins for wood coating application

    Energy Technology Data Exchange (ETDEWEB)

    Tajau, Rida; Mahmood, Mohd Hilmi; Salleh, Mek Zah; Salleh, Nik Ghazali Nik [Radiation Processing Technology Division, Malaysian Nuclear Agency (Nuclear Malaysia), Bangi, 43000 Kajang, Selangor (Malaysia); Ibrahim, Mohammad Izzat [Faculty of Science, University of Malaya (UM), 50603 Kuala Lumpur (Malaysia); Yunus, Nurulhuda Mohd [Faculty of Science and Technology, National University Malaysia (UKM), 43600 Bangi, Selangor (Malaysia)

    2014-02-12

    The trend of using renewable sources such as palm oil as raw material in radiation curing is growing due to the demand from the market to produce a more environmental friendly product. In this study, the radiation curable process was done using epoxy acrylate and urethane acrylate resins which are known as epoxidised palm olein acrylate (EPOLA) and palm oil based urethane acrylate (POBUA), respectively. The purpose of the study was to investigate curing properties and the application of this UV-curable palm oil resins for wood coating. Furthermore, the properties of palm oil based coatings are compared with the petrochemical-based compound such as ebecryl (EB) i.e. EB264 and EB830. From the experiment done, the resins from petrochemical-based compounds resulted higher degree of crosslinking (up to 80%) than the palm oil based compounds (up to 70%), where the different is around 10-15%. The hardness property from this two type coatings can reached until 50% at the lower percentage of the oligomer. However, the coatings from petrochemical-based have a high scratch resistance as it can withstand at least up to 3.0 Newtons (N) compared to the palm oil-based compounds which are difficult to withstand the load up to 1.0 N. Finally, the test on the rubber wood substrate showed that the coatings containing benzophenone photoinitiator give higher adhesion property and their also showed a higher glosiness property on the glass substrate compared to the coatings containing irgacure-819 photoinitiator. This study showed that the palm oil coatings can be a suitable for the replacement of petrochemicals compound for wood coating. The palm oil coatings can be more competitive in the market if the problems of using high percentage palm oil oligomer can be overcome as the palm oil price is cheap enough.

  13. Development of palm oil-based UV-curable epoxy acrylate and urethane acrylate resins for wood coating application

    Science.gov (United States)

    Tajau, Rida; Ibrahim, Mohammad Izzat; Yunus, Nurulhuda Mohd; Mahmood, Mohd Hilmi; Salleh, Mek Zah; Salleh, Nik Ghazali Nik

    2014-02-01

    The trend of using renewable sources such as palm oil as raw material in radiation curing is growing due to the demand from the market to produce a more environmental friendly product. In this study, the radiation curable process was done using epoxy acrylate and urethane acrylate resins which are known as epoxidised palm olein acrylate (EPOLA) and palm oil based urethane acrylate (POBUA), respectively. The purpose of the study was to investigate curing properties and the application of this UV-curable palm oil resins for wood coating. Furthermore, the properties of palm oil based coatings are compared with the petrochemical-based compound such as ebecryl (EB) i.e. EB264 and EB830. From the experiment done, the resins from petrochemical-based compounds resulted higher degree of crosslinking (up to 80%) than the palm oil based compounds (up to 70%), where the different is around 10-15%. The hardness property from this two type coatings can reached until 50% at the lower percentage of the oligomer. However, the coatings from petrochemical-based have a high scratch resistance as it can withstand at least up to 3.0 Newtons (N) compared to the palm oil-based compounds which are difficult to withstand the load up to 1.0 N. Finally, the test on the rubber wood substrate showed that the coatings containing benzophenone photoinitiator give higher adhesion property and their also showed a higher glosiness property on the glass substrate compared to the coatings containing irgacure-819 photoinitiator. This study showed that the palm oil coatings can be a suitable for the replacement of petrochemicals compound for wood coating. The palm oil coatings can be more competitive in the market if the problems of using high percentage palm oil oligomer can be overcome as the palm oil price is cheap enough.

  14. Secondary Neutron Production from Space Radiation Interactions: Advances in Model and Experimental Data Base Development

    Science.gov (United States)

    Heilbronn, Lawrence H.; Townsend, Lawrence W.; Braley, G. Scott; Iwata, Yoshiyuki; Iwase, Hiroshi; Nakamura, Takashi; Ronningen, Reginald M.; Cucinotta, Francis A.

    2003-01-01

    For humans engaged in long-duration missions in deep space or near-Earth orbit, the risk from exposure to galactic and solar cosmic rays is an important factor in the design of spacecraft, spacesuits, and planetary bases. As cosmic rays are transported through shielding materials and human tissue components, a secondary radiation field is produced. Neutrons are an important component of that secondary field, especially in thickly-shielded environments. Calculations predict that 50% of the dose-equivalent in a lunar or Martian base comes from neutrons, and a recent workshop held at the Johnson Space Center concluded that as much as 30% of the dose in the International Space Station may come from secondary neutrons. Accelerator facilities provide a means for measuring the effectiveness of various materials in their ability to limit neutron production, using beams and energies that are present in cosmic radiation. The nearly limitless range of beams, energies, and target materials that are present in space, however, means that accelerator-based experiments will not provide a complete database of cross sections and thick-target yields that are necessary to plan and design long-duration missions. As such, accurate nuclear models of neutron production are needed, as well as data sets that can be used to compare with, and verify, the predictions from such models. Improvements in a model of secondary neutron production from heavy-ion interactions are presented here, along with the results from recent accelerator-based measurements of neutron-production cross sections. An analytical knockout-ablation model capable of predicting neutron production from high-energy hadron-hadron interactions (both nucleon-nucleus and nucleus-nucleus collisions) has been previously developed. In the knockout stage, the collision between two nuclei result in the emission of one or more nucleons from the projectile and/or target. The resulting projectile and target remnants, referred to as

  15. Secondary Neutron Production from Space Radiation Interactions: Advances in Model and Experimental Data Base Development

    Science.gov (United States)

    Heilbronn, Lawrence H.; Townsend, Lawrence W.; Braley, G. Scott; Iwata, Yoshiyuki; Iwase, Hiroshi; Nakamura, Takashi; Ronningen, Reginald M.; Cucinotta, Francis A.

    2003-01-01

    For humans engaged in long-duration missions in deep space or near-Earth orbit, the risk from exposure to galactic and solar cosmic rays is an important factor in the design of spacecraft, spacesuits, and planetary bases. As cosmic rays are transported through shielding materials and human tissue components, a secondary radiation field is produced. Neutrons are an important component of that secondary field, especially in thickly-shielded environments. Calculations predict that 50% of the dose-equivalent in a lunar or Martian base comes from neutrons, and a recent workshop held at the Johnson Space Center concluded that as much as 30% of the dose in the International Space Station may come from secondary neutrons. Accelerator facilities provide a means for measuring the effectiveness of various materials in their ability to limit neutron production, using beams and energies that are present in cosmic radiation. The nearly limitless range of beams, energies, and target materials that are present in space, however, means that accelerator-based experiments will not provide a complete database of cross sections and thick-target yields that are necessary to plan and design long-duration missions. As such, accurate nuclear models of neutron production are needed, as well as data sets that can be used to compare with, and verify, the predictions from such models. Improvements in a model of secondary neutron production from heavy-ion interactions are presented here, along with the results from recent accelerator-based measurements of neutron-production cross sections. An analytical knockout-ablation model capable of predicting neutron production from high-energy hadron-hadron interactions (both nucleon-nucleus and nucleus-nucleus collisions) has been previously developed. In the knockout stage, the collision between two nuclei result in the emission of one or more nucleons from the projectile and/or target. The resulting projectile and target remnants, referred to as

  16. Perubahan warna lempeng resin akrilik yang direndam dalam larutan desinfektan sodium hipoklorit dan klorhexidin (The color changes of acrylic resins denture base material which are immersed in Sodium hypochlorite and chlorhexidine

    Directory of Open Access Journals (Sweden)

    David David

    2006-03-01

    Full Text Available One of the acrylic resins properties is the water absorption including color fluids and chemically fluids that affect on the color changes of the acrylic resins. This laboratory experiments studied sodium hypochlorite and chlorhexidine effect on the color changes of acrylic denture base resins material. The study was conducted by immersing heat cured acrylic plate samples of 26 mm of diameter and 0.4 mm of thickness in sodium hypochlorite for 10; 70 and 140 minutes and chlorhexidine for 15; 105 and 210 minutes. Seven samples were used for each experiment. An optical spectrometer BPX-47 type photo cell and a digital microvoltage were used for the color changes observation. The statistical test used were t-test, One-way ANOVA and LSD with 0.05 significance degree level. The results of the studied showed that the color of acrylic resins denture base plate changed after immersion in sodium hypochlorite for 70 and 140 minutes and chlorhexidine for 105 and 210 minute of immersion.

  17. A novel polishing technology for epoxy resin based on 355 nm UV laser

    Science.gov (United States)

    Meng, Xinling; Tao, Luqi; Liu, Zhaolin; Yang, Yi; Ren, Tianling

    2017-06-01

    The electromagnetic shielding film has drawn much attention due to its wide applications in the integrated circuit package, which demands a high surface quality of epoxy resin. However, gaseous Cu will splash and adhere to epoxy resin surface when the Cu layer in PCB receives enough energy in the process of laser cutting, which has a negative effect on the quality of the shielding film. Laser polishing technology can solve this problem and it can effectively improve the quality of epoxy resin surface. The paper studies the mechanism of Cu powder spraying on the compound surface by 355 nm ultraviolet (UV) laser, including the parameters of laser polishing process and the remains of Cu content on compound surface. The results show that minimal Cu content can be realized with a scanning speed of 700 mm/s, a laser frequency of 50 kHz and the distance between laser focus and product top surface of -1.3 mm. This result is important to obtain an epoxy resin surface with high quality. Project supported by the National Natural Science Foundation of China (Nos. 61574083, 61434001), the National Basic Research Program (No. 2015CB352100), the National Key Project of Science and Technology (No. 2011ZX02403-002), the Special Fund for Agroscientic Research in the Public Interest of China (No 201303107), the support of the Independent Research Program of Tsinghua University (No. 2014Z01006), and Advanced Sensor and Integrated System Lab of Tsinghua University Graduate School at Shenzhen (No. ZDSYS20140509172959969).

  18. Fluorinated Epoxy Resins-based Sorbent Coating Materials for Quartz Piezoelectric Crystal Detector

    Directory of Open Access Journals (Sweden)

    D. C Gupta

    2004-04-01

    Full Text Available Fluorinated epoxy resins were synthesised and evaluated as sorbent coating materials for the detection of organophosphorus compounds using quartz piezoelectric crystal detector. These resins were prepared by reacting excess of epichlorohydrin with each of or in combination of fluorinated diols, ie, a, a, a', a' tetrakis (trifluoromethyl 1,3 benzene dimethanol (TTFMBD, 4,4'bis-2-hydroxy hexafluoro isopropyl biphenyl (BHHFIBP, 4,4'dihydroxyocta fluorodiphenyl (DHOFDP and 2,2,3,3,4,4 hexafluoro 1,5 pentanediol (HFPD in the presence of sodium hydroxide at reflux temperature. These polymers were extracted in organic solvents and dried. Each of these fluoroepoxy resins were coated over quartz piezoelectric crystal by solution-casting method and tested using dimethylmethyl phosphonate (DMMP as model compound. Change in the  frequency (AF of quartz piezoelectric crystal oscillator was recorded. Sensitive and potential fluorinated epoxy resins, ie, diglycidylethers (DGE of HFPD-TTFMBD (in the molar ratio 6:4 and DGE (HFPD-BHHFIBP in the molar ratio 4:6 were characterised by viscosity, number average molecular weight (Mn, epoxy equivalent, infrared spectroscopy, and thermal stability.

  19. Resins and additives for powder coatings and alkyd paints, based on renewable resources

    NARCIS (Netherlands)

    Haveren, van J.; Oostveen, E.A.; Micciche, F.; Noordover, B.A.J.; Koning, C.E.; Benthem, van R.A.T.M.; Frissen, A.E.; Weijnen, J.G.J.

    2007-01-01

    Due to limited fossil resources and an increased need for environmentally friendly, sustainable technologies, the importance of using renewable feedstocks in the paint and coatings area will increase in the decades to come. This paper highlights some of the perspectives in this area. Alkyd resins

  20. Fatty Acid-Based Monomers as Styrene Replacements for Liquid Molding Resins

    Science.gov (United States)

    2005-05-01

    methacrylation of diglycidyl ether of bisphenol A ( DGEBA ) [8] (Fig. 1) catalyzed using AMC-2 (Aerojet Chemicals, Rancho Cordova, CA), which is a... DGEBA , and its methacrylated analog is dubbed VE 828. The effect of VE molecular weight on the properties of VE/FA resins was not tested, but will be

  1. Resins and additives for powder coatings and alkyd paints, based on renewable resources

    NARCIS (Netherlands)

    Haveren, van J.; Oostveen, E.A.; Micciche, F.; Noordover, B.A.J.; Koning, C.E.; Benthem, van R.A.T.M.; Frissen, A.E.; Weijnen, J.G.J.

    2007-01-01

    Due to limited fossil resources and an increased need for environmentally friendly, sustainable technologies, the importance of using renewable feedstocks in the paint and coatings area will increase in the decades to come. This paper highlights some of the perspectives in this area. Alkyd resins fo

  2. Novel Ag nanocrystals based dental resin composites with enhanced mechanical and antibacterial properties

    Institute of Scientific and Technical Information of China (English)

    Fengwei Liu; Ruili Wang; Yuyuan Shi; Xiaoze Jiang; Bin Sun; Meifang Zhu

    2013-01-01

    The aim of this work was to investigate the effect of trace addition of oleic acid coated Ag nanocrystals (Ag NCs) on mechanical and antibacterial properties of dental resin composites. Composites (70 wt%of silica loading) with 25 ppm, 50 ppm, 75 ppm and 100 ppm (wt) Ag NCs were prepared and the composite without Ag NCs served as a control. The experimental results showed that the addition of Ag NCs significantly improved the strength and modulus of the resin composite without compromising the shade. For the composite with 50 ppm Ag NCs, flexural strength (140.3 MPa), modulus (13.2 GPa) and compressive strength (347.2 MPa) were increased by 4.1%, 22.2%, 13.3%, respectively, compared with the control. The antibacterial test demonstrated that trace Ag NCs provided the resin composites with an antibacterial effect. Such strong and antibacterial dental resin composites might be advantageous to prevent secondary caries and be potential for future clinical applications.

  3. Mechanistic aspects of fracture and fatigue in resin based dental restorative composites

    Science.gov (United States)

    Shah, Minalben B.

    For resin based dental restorative composites, one of the major challenges is to optimize the balance between mechanical and optical properties. Although fracture is the second leading cause of dental restorative failures, very limited mechanistic understanding exists on a microscopic level. In the present study, the fracture properties and mechanisms of two commercial dental resin composites with different microstructures are examined using double notched four point beam bending and pre-cracked compact-tension, C(T), specimens. Four point bend flexural strength was also measured using un-notched beam samples. The first material is a microhybrid composite that combines a range of nano and micro scale filler particles to give an average particle size of 0.6 mum, while the second is a nanofill composite reinforced entirely with nano particles and their agglomerates. The influences of 60 days water hydration and a post-cure heat treatment were also examined. Fracture resistance curve (R-curve) experiments have demonstrated the microhybrid composite to be more fracture resistant than the nanofill composite in both as-processed and hydrated conditions. Rising fracture resistance with crack extension was observed in all specimens, independent of the environmental conditions. Compared to the as-processed condition, a significant reduction in the peak toughness was observed for the nanofill composite after 60 days of water aging. Hydration lowered flexural strength of both composites which was attributed to hydrolytic matrix degradation with additional interfacial debonding causing larger strength decrease in the nanofill. Optical and SEM observations revealed an interparticle matrix crack path promoting crack deflection as a toughening mechanism in all cases except the hydrated nanofill which showed particle-matrix debonding. Crack bridging was another observed extrinsic toughening mechanism that was believed to be responsible for the rising fracture resistance curve (R

  4. Test of a prototype neutron spectrometer based on diamond detectors in a fast reactor

    CERN Document Server

    Osipenko, M; Ripani, M; Pillon, M; Ricco, G; Caiffi, B; Cardarelli, R; Verona-Rinati, G; Argiro, S

    2015-01-01

    A prototype of neutron spectrometer based on diamond detectors has been developed. This prototype consists of a $^6$Li neutron converter sandwiched between two CVD diamond crystals. The radiation hardness of the diamond crystals makes it suitable for applications in low power research reactors, while a low sensitivity to gamma rays and low leakage current of the detector permit to reach good energy resolution. A fast coincidence between two crystals is used to reject background. The detector was read out using two different electronic chains connected to it by a few meters of cable. The first chain was based on conventional charge-sensitive amplifiers, the other used a custom fast charge amplifier developed for this purpose. The prototype has been tested at various neutron sources and showed its practicability. In particular, the detector was calibrated in a TRIGA thermal reactor (LENA laboratory, University of Pavia) with neutron fluxes of $10^8$ n/cm$^2$s and at the 3 MeV D-D monochromatic neutron source na...

  5. An optimized neutron-beam shaping assembly for accelerator-based BNCT.

    Science.gov (United States)

    Burlon, A A; Kreiner, A J; Valda, A A; Minsky, D M

    2004-11-01

    Different materials and proton beam energies have been studied in order to search for an optimized neutron production target and beam shaping assembly for accelerator-based BNCT. The solution proposed in this work consists of successive stacks of Al, polytetrafluoroethylene, commercially known as Teflon, and LiF as moderator and neutron absorber, and Pb as reflector. This assembly is easy to build and its cost is relatively low. An exhaustive Monte Carlo simulation study has been performed evaluating the doses delivered to a Snyder model head phantom by a neutron production Li-metal target based on the (7)Li(p,n)(7)Be reaction for proton bombarding energies of 1.92, 2.0, 2.3 and 2.5 MeV. Three moderator thicknesses have been studied and the figures of merit show the advantage of irradiating with near-resonance-energy protons (2.3 MeV) because of the relatively high neutron yield at this energy, which at the same time keeps the fast neutron healthy tissue dose limited and leads to the lowest treatment times. A moderator of 34 cm length has shown the best performance among the studied cases.

  6. An optimized neutron-beam shaping assembly for accelerator-based BNCT

    Energy Technology Data Exchange (ETDEWEB)

    Burlon, A.A. E-mail: burlon@tandar.cnea.gov.ar; Kreiner, A.J.; Valda, A.A.; Minsky, D.M

    2004-11-01

    Different materials and proton beam energies have been studied in order to search for an optimized neutron production target and beam shaping assembly for accelerator-based BNCT. The solution proposed in this work consists of successive stacks of Al, polytetrafluoroethylene, commercially known as Teflon[reg ], and LiF as moderator and neutron absorber, and Pb as reflector. This assembly is easy to build and its cost is relatively low. An exhaustive Monte Carlo simulation study has been performed evaluating the doses delivered to a Snyder model head phantom by a neutron production Li-metal target based on the {sup 7}Li(p,n){sup 7}Be reaction for proton bombarding energies of 1.92, 2.0, 2.3 and 2.5 MeV. Three moderator thicknesses have been studied and the figures of merit show the advantage of irradiating with near-resonance-energy protons (2.3 MeV) because of the relatively high neutron yield at this energy, which at the same time keeps the fast neutron healthy tissue dose limited and leads to the lowest treatment times. A moderator of 34 cm length has shown the best performance among the studied cases.

  7. Resin-based preparation of HTGR fuels: operation of an engineering-scale uranium loading system

    Energy Technology Data Exchange (ETDEWEB)

    Haas, P.A.

    1977-10-01

    The fuel particles for recycle of /sup 233/U to High-Temperature Gas-Cooled Reactors are prepared from uranium-loaded carboxylic acid ion exchange resins which are subsequently carbonized, converted, and refabricated. The development and operation of individual items of equipment and of an integrated system are described for the resin-loading part of the process. This engineering-scale system was full scale with respect to a hot demonstration facility, but was operated with natural uranium. The feed uranium, which consisted of uranyl nitrate solution containing excess nitric acid, was loaded by exchange with resin in the hydrogen form. In order to obtain high loadings, the uranyl nitrate must be acid deficient; therefore, nitric acid was extracted by a liquid organic amine which was regenerated to discharge a NaNO/sub 3/ or NH/sub 4/NO/sub 3/ solution waste. Water was removed from the uranyl nitrate solution by an evaporator that yielded condensate containing less than 0.5 ppM of uranium. The uranium-loaded resin was washed with condensate and dried to a controlled water content via microwave heating. The loading process was controlled via in-line measurements of the pH and density of the uranyl nitrate. The demonstrated capacity was 1 kg of uranium per hour for either batch loading contractors or a continuous column as the resin loading contractor. Fifty-four batch loading runs were made without a single failure of the process outlined in the chemical flowsheet or any evidence of inability to control the conditions dictated by the flowsheet.

  8. A neutron production target for ESS based upon the Canned-rods concept

    Energy Technology Data Exchange (ETDEWEB)

    Ghiglino, A., E-mail: angeloglinovoa@gmail.com [ESS-BILBAO, Parque Tecnológico Bizkaia, Laida Bidea, Edificio 207 B Planta Baja, 48160 Derio (Spain); Instituto de Fusión Nuclear - UPM, ETS Ingenieros Industriales, C/José Gutiérrez Abascal, 2, 28006 Madrid (Spain); Terrón, S. [ESS-BILBAO, Parque Tecnológico Bizkaia, Laida Bidea, Edificio 207 B Planta Baja, 48160 Derio (Spain); Instituto de Fusión Nuclear - UPM, ETS Ingenieros Industriales, C/José Gutiérrez Abascal, 2, 28006 Madrid (Spain); Thomsen, K. [Paul Scherrer Institut, 5232 Villigen PSI (Switzerland); Wolters, J. [Forschungszentrum Juelich GmbH, 52425 Juelich (Germany); Magán, M.; Martínez, F.; Vicente, P.J. de; Vivanco, R.; Sordo, F. [ESS-BILBAO, Parque Tecnológico Bizkaia, Laida Bidea, Edificio 207 B Planta Baja, 48160 Derio (Spain); Instituto de Fusión Nuclear - UPM, ETS Ingenieros Industriales, C/José Gutiérrez Abascal, 2, 28006 Madrid (Spain); Butzek, M. [Forschungszentrum Juelich GmbH, 52425 Juelich (Germany); Perlado, J.M. [Instituto de Fusión Nuclear - UPM, ETS Ingenieros Industriales, C/José Gutiérrez Abascal, 2, 28006 Madrid (Spain); Bermejo, F.J. [Instituto de Estructura de la Materia, IEM-CSIC, Consejo Superior de Investigaciones Científicas, Serrano 123, 28006 Madrid (Spain)

    2014-08-21

    The neutron production targets operating within the present day spallation neutron sources in the MW power range are either based on water-cooled solid state devices such as that implemented at the SINQ source at PSI or liquid metal loops such as those installed at SNS and MLSF. Here we describe a water-cooled rotating solid target as an option for the 5 MW ESS project as an alternative to the current design based upon a helium-cooled solid rotating target. Implementation of the proposed option would provide comparable neutronic performance to that of the gas-cooled concept and furthermore, it would involve a relatively straightforward adaptation of the current ESS baseline geometry.

  9. A 200 cm x 50 cm large multigap resistive plate chamber based neutron detector

    Energy Technology Data Exchange (ETDEWEB)

    Yakorev, Dmitry; Elekes, Zoltan; Bemmerer, Daniel; Kempe, Mathias; Sobiella, Manfred; Stach, Daniel; Wagner, Andreas [Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Dresden (Germany); Roeder, Marko; Zuber, Kai [TU Dresden (Germany); Cowan, Thomas [Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Dresden (Germany); TU Dresden (Germany)

    2012-07-01

    A prototype for a multigap resistive plate chamber (MRPC) based detector of 200 cm x 50 cm size for 1 GeV neutrons has been developed, built and tested. The principle of operation is the conversion of the high-energy neutron to a charged particle in an iron converter, and the detection of the charged particle in the MRPC. Experiments using the single-electron mode of operation of the ELBE 40 MeV electron accelerator showed that a time resolution of {sigma}{sub t}<100 ps was reached for minimum-ionizing particles, at nearly full efficiency. Extensive simulations show that it is feasible to construct a time-of-flight detector for GeV neutrons based on such a principle.

  10. Nitrogen Detection in Bulk Samples Using a D-D Reaction-Based Portable Neutron Generator

    Directory of Open Access Journals (Sweden)

    A. A. Naqvi

    2013-01-01

    Full Text Available Nitrogen concentration was measured via 2.52 MeV nitrogen gamma ray from melamine, caffeine, urea, and disperse orange bulk samples using a newly designed D-D portable neutron generator-based prompt gamma ray setup. Inspite of low flux of thermal neutrons produced by D-D reaction-based portable neutron generator and interference of 2.52 MeV gamma rays from nitrogen in bulk samples with 2.50 MeV gamma ray from bismuth in BGO detector material, an excellent agreement between the experimental and calculated yields of nitrogen gamma rays indicates satisfactory performance of the setup for detection of nitrogen in bulk samples.

  11. Gadolinium-doped water cerenkov-based neutron and high energy gamma-ray detector and radiation portal monitoring system

    Science.gov (United States)

    Dazeley, Steven A; Svoboda, Robert C; Bernstein, Adam; Bowden, Nathaniel

    2013-02-12

    A water Cerenkov-based neutron and high energy gamma ray detector and radiation portal monitoring system using water doped with a Gadolinium (Gd)-based compound as the Cerenkov radiator. An optically opaque enclosure is provided surrounding a detection chamber filled with the Cerenkov radiator, and photomultipliers are optically connected to the detect Cerenkov radiation generated by the Cerenkov radiator from incident high energy gamma rays or gamma rays induced by neutron capture on the Gd of incident neutrons from a fission source. The PMT signals are then used to determine time correlations indicative of neutron multiplicity events characteristic of a fission source.

  12. Spatial resolution of a μPIC-based neutron imaging detector

    Energy Technology Data Exchange (ETDEWEB)

    Parker, J.D., E-mail: jparker@cr.scphys.kyoto-u.ac.jp [Department of Physics, Graduate School of Science, Kyoto University, Kitashirakawa-oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan); Harada, M. [Materials and Life Science Facility Division, Japan Atomic Energy Agency (JAEA), Tokai, Ibaraki 319-1195 (Japan); Hattori, K.; Iwaki, S.; Kabuki, S.; Kishimoto, Y.; Kubo, H.; Kurosawa, S.; Matsuoka, Y.; Miuchi, K.; Mizumoto, T.; Nishimura, H. [Department of Physics, Graduate School of Science, Kyoto University, Kitashirakawa-oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan); Oku, T. [Materials and Life Science Facility Division, Japan Atomic Energy Agency (JAEA), Tokai, Ibaraki 319-1195 (Japan); Sawano, T. [Department of Physics, Graduate School of Science, Kyoto University, Kitashirakawa-oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan); Shinohara, T.; Suzuki, J. [Materials and Life Science Facility Division, Japan Atomic Energy Agency (JAEA), Tokai, Ibaraki 319-1195 (Japan); Takada, A.; Tanimori, T.; Ueno, K. [Department of Physics, Graduate School of Science, Kyoto University, Kitashirakawa-oiwakecho, Sakyo-ku, Kyoto 606-8502 (Japan)

    2013-10-21

    We present a detailed study of the spatial resolution of our time-resolved neutron imaging detector utilizing a new neutron position reconstruction method that improves both spatial resolution and event reconstruction efficiency. Our prototype detector system, employing a micro-pattern gaseous detector known as the micro-pixel chamber (μPIC) coupled with a field-programmable-gate-array-based data acquisition system, combines 100μm-level spatial and sub-μs time resolutions with excellent gamma rejection and high data rates, making it well suited for applications in neutron radiography at high-intensity, pulsed neutron sources. From data taken at the Materials and Life Science Experimental Facility within the Japan Proton Accelerator Research Complex (J-PARC), the spatial resolution was found to be approximately Gaussian with a sigma of 103.48±0.77μm (after correcting for beam divergence). This is a significant improvement over that achievable with our previous reconstruction method (334±13μm), and compares well with conventional neutron imaging detectors and with other high-rate detectors currently under development. Further, a detector simulation indicates that a spatial resolution of less than 60μm may be possible with optimization of the gas characteristics and μPIC structure. We also present an example of imaging combined with neutron resonance absorption spectroscopy. -- Highlights: • Neutron imaging detector with micro-pattern gaseous detector and {sup 3}He was developed. • Detector combines imaging with energy by time-of-flight and high-rate capability. • Detector features 18% efficiency, 0.6μs time resolution, and γ sensitivity <10{sup −12}. • New analysis method with template fit achieves spatial resolution of nearly 100μm. • Simulation study indicates improvement to ∼60μm after optimization.

  13. Effect of silica coating combined to a MDP-based primer on the resin bond to Y-TZP ceramic.

    Science.gov (United States)

    May, Liliana Gressler; Passos, Sheila Pestana; Capelli, Diana Barca; Ozcan, Mutlu; Bottino, Marco Antonio; Valandro, Luiz Felipe

    2010-10-01

    The aim of this study was to evaluate the influence of silica coating and 10-methacryloyloxydecyl dihydrogen phosphate (MDP)-based primer applications upon the bonding durability of a MDP-based resin cement to a yttrium stabilized tetragonal zirconia (Y-TZP) ceramic. Ninety-six Y-TZP tabs were embedded in an acrylic resin (free surface for adhesion: 5 × 5 mm(2)), ground finished and randomly divided into four groups (N = 24) according to the ceramic surface conditioning: (1) cleaning with isopropanol (ALC); (2) ALC + phosphoric acid etching + MDP-based primer application (MDP-primer); (3) silica coating + 3-methacryloyloxypropyl trimethoxysilane (MPS)-based coupling agent application (SiO2 + MPS-Sil); and (4) SiO2 + MDP-primer. The MDP-based resin cement was applied on the treated surface using a cylindrical mold (diameter= 3 mm). Half of the specimens from each surface conditioning were stored in distilled water (37 °C, 24 h) before testing. Another half of the specimens were stored (90 days) and thermo-cycled (12,000 x) during this period (90 d/TC) before testing. A shear bond strength (SBS) test was performed at a crosshead speed of 0.5 mm/min. Two factors composed the experimental design: ceramic conditioning strategy (in four levels) and storage condition (in two levels), totaling eight groups. After 90 d/TC (Tukey; p MDP-primer (24.40 MPa) promoted the highest SBS. The ALC and MDP-primer groups debonded spontaneously during 90 d/TC. Bonding values were higher and more stable in the SiO2 groups. The use of MDP-primer after silica coating increased the bond strength.

  14. Boron neutron capture therapy design calculation of a 3H(p,n) reaction based BSA for brain cancer setup

    OpenAIRE

    Bassem Elshahat; Akhtar Naqvi; Nabil Maalej

    2015-01-01

    Purpose: Boron neutron capture therapy (BNCT) is a promising technique for the treatment of malignant disease targeting organs of the human body. Monte Carlo simulations were carried out to calculate optimum design parameters of an accelerator based beam shaping assembly (BSA) for BNCT of brain cancer setup.Methods: Epithermal beam of neutrons were obtained through moderation of fast neutrons from 3H(p,n) reaction in a high density polyethylene moderator and a graphite reflector. The dimensio...

  15. Instrumentation for PSD-based neutron diffractometers at Dhruva reactor

    Indian Academy of Sciences (India)

    S S Pande; S P Borkar; S Prafulla; V D Srivastava; A Behare; P K Mukhopadhyay; M D Ghodgaonkar; S K Kataria

    2004-08-01

    Linear position sensitive detectors (PSDs) are widely used to configure neutron diffractometers and other instruments. Necessary front-end electronics and a data acquisition system [1] is developed to cater to such instruments built around the Dhruva research reactor in BARC. These include three diffractometers with multiple PSDs and four with single PSD. The front-end electronics consists of high voltage units, preamplifiers [2], shaping amplifiers, ratio ADCs (RDC) [3]. The data acquisition system consists of an interface card and software. Commercially available hardware like temperature controller or stepper motor controller connected over GPIB or RS232 are also integrated in the data acquisition system. The data acquisition is automated so that it can continue unattended for control parameter like temperature, thus enabling optimum utilization of available beam time. The instrumentation is scalable and can be easily configured for various instrumental requirements. The front-end electronics and the data acquisition system are described here.

  16. Materials-based process tolerances for neutron generator encapsulation.

    Energy Technology Data Exchange (ETDEWEB)

    Berry, Ryan S.; Adolf, Douglas Brian; Stavig, Mark Edwin

    2007-10-01

    Variations in the neutron generator encapsulation process can affect functionality. However, instead of following the historical path in which the effects of process variations are assessed directly through functional tests, this study examines how material properties key to generator functionality correlate with process variations. The results of this type of investigation will be applicable to all generators and can provide insight on the most profitable paths to process and material improvements. Surprisingly, the results at this point imply that the process is quite robust, and many of the current process tolerances are perhaps overly restrictive. The good news lies in the fact that our current process ensures reproducible material properties. The bad new lies in the fact that it would be difficult to solve functional problems by changes in the process.

  17. A review of nanostructured based radiation sensors for neutron

    Energy Technology Data Exchange (ETDEWEB)

    Ahmad, Pervaiz; Mohamed, Norani Muti; Burhanudin, Zainal Arif [Center of Excellence in Nanotechnology Department of Fundamental and Applied Sciences, Department of Electrical and Electronic Engineering Universiti Teknologi PETRONAS (Malaysia)

    2012-09-26

    Currently radiation sensors with various mechanisms such as radio thermo luminescence, radiographic and radiochromic film, semiconductor and ionization have been used for the detection of nuclear radiation. Sensitivity, handling procedure, heating condition, energy response, nonlinearity, polarization, non-uniform electric field, high bias voltage and spatial resolution due to large physical size are some of the key issues faced by these sensors. Due to the excellent electrical and mechanical properties, nanostructured materials such as carbon nanotubes (CNTs) have been researched as sensing elements in the sensors to overcome the mentioned problems. However CNTs are found to pose different problems, arising from the uncontrolled helicity and small cross-sectional area. Therefore, alternative sensing elements are still been sought after and the possibility of using boron nitride nanotubes for sensing neutron is considered in this review.

  18. The influence of resin flexural modulus on the magnitude of ceramic strengthening.

    LENUS (Irish Health Repository)

    Fleming, Garry J P

    2012-07-01

    The aim was to determine the magnitude of ceramic resin-strengthening with resin-based materials with varying flexural moduli using a regression technique to assess the theoretical strengthening at a \\'zero\\' resin-coating thickness. The hypothesis tested was that experimentally, increasing resin flexural modulus results in increased resin-strengthening observed at a theoretical \\'zero\\' resin-coating thickness.

  19. Properties evaluation of silorane, low-shrinkage, non-flowable and flowable resin-based composites in dentistry

    Directory of Open Access Journals (Sweden)

    Rodrigo R. Maia

    2015-06-01

    Full Text Available Purpose. This study tested the null hypothesis that different classes of direct restorative dental materials: silorane-based resin, low-shrinkage and conventional (non-flowable and flowable resin-based composite (RBC do not differ from each other with regard to polymerization shrinkage, depth of cure or microhardness.Methods. 140 RBC samples were fabricated and tested by one calibrated operator. Polymerization shrinkage was measured using a gas pycnometer both before and immediately after curing with 36 J/cm2 light energy density. Depth of cure was determined, using a penetrometer and the Knoop microhardness was tested from the top surface to a depth of 5 mm.Results. Considering polymerization shrinkage, the authors found significant differences (p < 0.05 between different materials: non-flowable RBCs showed lower values compared to flowable RBCs, with the silorane-based resin presenting the smallest shrinkage. The low shrinkage flowable composite performed similarly to non-flowable with significant statistical differences compared to the two other flowable RBCs. Regarding to depth of cure, low-shrinkage flowable RBC, were most effective compared to other groups. Microhardness was generally higher for the non-flowable vs. flowable RBCs (p < 0.05. However, the values for low-shrinkage flowable did not differ significantly from those of non-flowable, but were significantly higher than those of the other flowable RBCs.Clinical Significance. RBCs have undergone many modifications as they have evolved and represent the most relevant restorative materials in today’s dental practice. This study of low-shrinkage RBCs, conventional RBCs (non-flowable and flowable and silorane-based composite—by in vitro evaluation of volumetric shrinkage, depth of cure and microhardness—reveals that although filler content is an important determinant of polymerization shrinkage, it is not the only variable that affects properties of materials that were tested in

  20. Properties evaluation of silorane, low-shrinkage, non-flowable and flowable resin-based composites in dentistry.

    Science.gov (United States)

    Maia, Rodrigo R; Reis, Rodrigo S; Moro, André F V; Perez, Cesar R; Pessôa, Bárbara M; Dias, Katia R H C

    2015-01-01

    Purpose. This study tested the null hypothesis that different classes of direct restorative dental materials: silorane-based resin, low-shrinkage and conventional (non-flowable and flowable) resin-based composite (RBC) do not differ from each other with regard to polymerization shrinkage, depth of cure or microhardness. Methods. 140 RBC samples were fabricated and tested by one calibrated operator. Polymerization shrinkage was measured using a gas pycnometer both before and immediately after curing with 36 J/cm(2) light energy density. Depth of cure was determined, using a penetrometer and the Knoop microhardness was tested from the top surface to a depth of 5 mm. Results. Considering polymerization shrinkage, the authors found significant differences (p flowable RBCs showed lower values compared to flowable RBCs, with the silorane-based resin presenting the smallest shrinkage. The low shrinkage flowable composite performed similarly to non-flowable with significant statistical differences compared to the two other flowable RBCs. Regarding to depth of cure, low-shrinkage flowable RBC, were most effective compared to other groups. Microhardness was generally higher for the non-flowable vs. flowable RBCs (p flowable did not differ significantly from those of non-flowable, but were significantly higher than those of the other flowable RBCs. Clinical Significance. RBCs have undergone many modifications as they have evolved and represent the most relevant restorative materials in today's dental practice. This study of low-shrinkage RBCs, conventional RBCs (non-flowable and flowable) and silorane-based composite-by in vitro evaluation of volumetric shrinkage, depth of cure and microhardness-reveals that although filler content is an important determinant of polymerization shrinkage, it is not the only variable that affects properties of materials that were tested in this study.

  1. A position-sensitive neutron spectrometer/dosimeter based on pressurized superheated drop (bubble) detectors

    Science.gov (United States)

    d'Errico, F.; Nath, R.; Holland, S. K.; Lamba, M.; Patz, S.; Rivard, M. J.

    2002-01-01

    A position-sensitive, superheated emulsion chamber (SEC) is introduced for three-dimensional (3D) spectrometry and dosimetry of fast neutrons. The detector is based on a fine suspension of octafluorocyclobutane droplets emulsified in a tissue-equivalent gel. This gel is highly viscous and immobilizes the bubbles at the location of their formation. At an operating temperature of 35°C, the droplets are moderately superheated and their evaporation is nucleated by the densely ionizing products of fast neutron interactions, with no response to sparsely ionizing radiations. Thus, when a neutron emitter such as a 252Cf brachytherapy source is inserted in the SEC, a bubble distribution forms around the source and makes the neutron field visible. The SEC is operated at different externally applied pressures that correspond to different response thresholds. These responses form a virtually orthogonal matrix which is suitable for spectrometry and allows the use of effective few channel unfolding procedures, yielding the spatial dependence of absorbed dose and neutron energy spectra in-tissue. Bubble spatial distributions in the chamber can be determined through optical tomography or magnetic resonance imaging (MRI). A 3D, steady-state MRI method has proven particularly effective for this purpose. After the imaging, the SEC can be pressurized above the halocarbon vapor tension in order to recondense the bubbles to the liquid phase. Within a few minutes, the device is annealed and ready to be used again for repeated measurements improving the bubble counting statistics.

  2. Neutron Imager and Flux Monitor Based on Micro Channel Plates (MCP) in Electrostatic Mirror Configuration

    Science.gov (United States)

    Variale, V.

    In this paper, a new high transparency device based on MCP for the monitoring the flux and spatial profile of a neutron beam will be described. The assembly consists of a carbon foil with a 6Li deposit, placed in the beam, and a MCP equipped with a phosphor screen readout viewed by a CCD camera, placed outside the beam. Secondary emitted electrons (SEE) produced in the carbon foil by the alpha-particles and tritons from the 6Li+n reaction, are deflected to the MCP detector by means of an electrostatic mirror, suitably designed to preserve the spatial resolution. The conductive layer on the phosphor can be used for neutron counting, and to obtain time-of-flight information. A peculiar feature of this device is that the use of an electrostatic mirror minimizes the perturbation of the neutron beam, i.e. absorption and scattering. It can be used at existing time-of-flight (TOF) facilities, in particular at the n_TOF facility at CERN, for monitoring the flux and special profile of the neutron beam in the thermal and epithermal region. In this work, the device principle and design will be presented, together with the main features in terms of resolution and neutron detection efficiency.

  3. High-flux neutron source based on a liquid-lithium target

    Science.gov (United States)

    Halfon, S.; Feinberg, G.; Paul, M.; Arenshtam, A.; Berkovits, D.; Kijel, D.; Nagler, A.; Eliyahu, I.; Silverman, I.

    2013-04-01

    A prototype compact Liquid Lithium Target (LiLiT), able to constitute an accelerator-based intense neutron source, was built. The neutron source is intended for nuclear astrophysical research, boron neutron capture therapy (BNCT) in hospitals and material studies for fusion reactors. The LiLiT setup is presently being commissioned at Soreq Nuclear research Center (SNRC). The lithium target will produce neutrons through the 7Li(p,n)7Be reaction and it will overcome the major problem of removing the thermal power generated by a high-intensity proton beam, necessary for intense neutron flux for the above applications. The liquid-lithium loop of LiLiT is designed to generate a stable lithium jet at high velocity on a concave supporting wall with free surface toward the incident proton beam (up to 10 kW). During off-line tests, liquid lithium was flown through the loop and generated a stable jet at velocity higher than 5 m/s on the concave supporting wall. The target is now under extensive test program using a high-power electron-gun. Up to 2 kW electron beam was applied on the lithium flow at velocity of 4 m/s without any flow instabilities or excessive evaporation. High-intensity proton beam irradiation will take place at SARAF (Soreq Applied Research Accelerator Facility) superconducting linear accelerator currently in commissioning at SNRC.

  4. A neutron spectrometer based on temperature variations in superheated drop compositions

    Energy Technology Data Exchange (ETDEWEB)

    Apfel, Robert E. E-mail: robert.apfel@yale.edu; D' Errico, Francesco

    2002-01-01

    The response of superheated drop detectors (SDDs) to neutron radiation varies in a self-consistent manner with variations in temperature and pressure, making such compositions suitable for neutron spectrometry. The advantage of this approach is that the response functions of candidate materials versus energy as the temperature or pressure is varied are nested and have distinct thresholds, with no thermal neutron response. These characteristics permit unfolding without the uncertainties associated with other spectrometry techniques, where multiple solutions are possible, thus requiring an initial guess of the spectrum. A spectrometer was developed based on the well-established technology for acoustic sensing of bubble events interfaced with a proportional-integral-derivative temperature controller. The active monitor for neutrons, called REMbrandt{sup TM}, was used as the platform for controlling temperature on a SDD probe and for data acquisition, thereby automating the process of measuring the neutron energy spectrum. The new instrument, called REM-SPEC{sup TM}, implements and automates the original BINS approach: it adjusts the temperature of the SDD vial in increasing steps and measures the bubble event rate at each step. By using two distinct SDD materials with overlapping responses, the 0.1-20 MeV range of energies relevant to practical spectrometry is readily covered. Initial experiments with an Am-Be source validate the operational protocols of this device.

  5. Characteristics of SiC neutron sensor spectrum unfolding process based on Bayesian inference

    Energy Technology Data Exchange (ETDEWEB)

    Cetnar, Jerzy; Krolikowski, Igor [Faculty of Energy and Fuels AGH - University of Science and Technology, Al. Mickiewicza 30, 30-059 Krakow (Poland); Ottaviani, L. [IM2NP, UMR CNRS 7334, Aix-Marseille University, Case 231 -13397 Marseille Cedex 20 (France); Lyoussi, A. [CEA, DEN, DER, Instrumentation Sensors and Dosimetry Laboratory, Cadarache, F-13108 St-Paul-Lez-Durance (France)

    2015-07-01

    This paper deals with SiC detector signal interpretation in neutron radiation measurements in mixed neutron gamma radiation fields, which is called the detector inverse problem or the spectrum unfolding, and it aims in finding a representation of the primary radiation, based on the measured detector signals. In our novel methodology we resort to Bayesian inference approach. In the developed procedure the resultant spectra is unfolded form detector channels reading, where the estimated neutron fluence in a group structure is obtained with its statistical characteristic comprising of standard deviation and correlation matrix. In the paper we present results of unfolding process for case of D-T neutron source in neutron moderating environment. Discussions of statistical properties of obtained results are presented as well as of the physical meaning of obtained correlation matrix of estimated group fluence. The presented works has been carried out within the I-SMART project, which is part of the KIC InnoEnergy R and D program. (authors)

  6. High-power liquid-lithium target prototype for accelerator-based boron neutron capture therapy.

    Science.gov (United States)

    Halfon, S; Paul, M; Arenshtam, A; Berkovits, D; Bisyakoev, M; Eliyahu, I; Feinberg, G; Hazenshprung, N; Kijel, D; Nagler, A; Silverman, I

    2011-12-01

    A prototype of a compact Liquid-Lithium Target (LiLiT), which will possibly constitute an accelerator-based intense neutron source for Boron Neutron Capture Therapy (BNCT) in hospitals, was built. The LiLiT setup is presently being commissioned at Soreq Nuclear Research Center (SNRC). The liquid-lithium target will produce neutrons through the (7)Li(p,n)(7)Be reaction and it will overcome the major problem of removing the thermal power generated using a high-intensity proton beam (>10 kW), necessary for sufficient neutron flux. In off-line circulation tests, the liquid-lithium loop generated a stable lithium jet at high velocity, on a concave supporting wall; the concept will first be tested using a high-power electron beam impinging on the lithium jet. High intensity proton beam irradiation (1.91-2.5 MeV, 2-4 mA) will take place at Soreq Applied Research Accelerator Facility (SARAF) superconducting linear accelerator currently in construction at SNRC. Radiological risks due to the (7)Be produced in the reaction were studied and will be handled through a proper design, including a cold trap and appropriate shielding. A moderator/reflector assembly is planned according to a Monte Carlo simulation, to create a neutron spectrum and intensity maximally effective to the treatment and to reduce prompt gamma radiation dose risks.

  7. A position-sensitive neutron spectrometer/dosimeter based on pressurized superheated drop (bubble) detectors

    Energy Technology Data Exchange (ETDEWEB)

    D' Errico, F. E-mail: francesco.derrico@yale.edu; Nath, R.; Holland, S.K.; Lamba, M.; Patz, S.; Rivard, M.J

    2002-01-01

    A position-sensitive, superheated emulsion chamber (SEC) is introduced for three-dimensional (3D) spectrometry and dosimetry of fast neutrons. The detector is based on a fine suspension of octafluorocyclobutane droplets emulsified in a tissue-equivalent gel. This gel is highly viscous and immobilizes the bubbles at the location of their formation. At an operating temperature of 35 deg.C, the droplets are moderately superheated and their evaporation is nucleated by the densely ionizing products of fast neutron interactions, with no response to sparsely ionizing radiations. Thus, when a neutron emitter such as a {sup 252}Cf brachytherapy source is inserted in the SEC, a bubble distribution forms around the source and makes the neutron field visible. The SEC is operated at different externally applied pressures that correspond to different response thresholds. These responses form a virtually orthogonal matrix which is suitable for spectrometry and allows the use of effective few channel unfolding procedures, yielding the spatial dependence of absorbed dose and neutron energy spectra in-tissue. Bubble spatial distributions in the chamber can be determined through optical tomography or magnetic resonance imaging (MRI). A 3D, steady-state MRI method has proven particularly effective for this purpose. After the imaging, the SEC can be pressurized above the halocarbon vapor tension in order to recondense the bubbles to the liquid phase. Within a few minutes, the device is annealed and ready to be used again for repeated measurements improving the bubble counting statistics.

  8. A conceptual design of a beam-shaping assembly for boron neutron capture therapy based on deuterium-tritium neutron generators.

    Science.gov (United States)

    Martín, Guido; Abrahantes, Arian

    2004-05-01

    A conceptual design of a beam-shaping assembly for boron neutron capture therapy using deuterium-tritium accelerator based neutrons source is developed. Calculations based on a simple geometry model for the radiation transport are initially performed to estimate the assembly materials and their linear dimensions. Afterward, the assembly geometry is produced, optimized and verified. In order to perform these calculations the general-purpose MCNP code is used. Irradiation time and therapeutic gain are utilized as beam assessment parameters. Metallic uranium and manganese are successfully tested for fast-to-epithermal neutron moderation. In the present beam-shaping assembly proposal, the therapeutic gain is improved by 23% and the accelerator current required for a fixed irradiation period is reduced by six times compared to previous proposals based on the same D-T reaction.

  9. Neutron-gamma discrimination based on bipolar trapezoidal pulse shaping using FPGAs in NE213

    Energy Technology Data Exchange (ETDEWEB)

    Esmaeili-sani, Vahid, E-mail: vaheed_esmaeely80@yahoo.com [Department of Nuclear Engineering and Physics, Amirkabir University of Technology, P.O. Box 4155-4494, Tehran (Iran, Islamic Republic of); Moussavi-zarandi, Ali; Akbar-ashrafi, Nafiseh; Boghrati, Behzad; Afarideh, Hossein [Department of Nuclear Engineering and Physics, Amirkabir University of Technology, P.O. Box 4155-4494, Tehran (Iran, Islamic Republic of)

    2012-12-01

    A technique employing neutron-gamma pulse shape discrimination (PSD) system that overcomes pile up limitations of previous methods to distinguish neutrons from gammas in scintillation detectors is described. The output signals of detectors were digitized and processed with a data acquisition system based on bipolar trapezoidal pulse shaping using Field programmable gate arrays (FPGA). FPGAs are capable of doing complex discrete signal processing algorithms with clock rates above 100 MHz. Their low cost, ease of use and selected dedicated hardware make them an ideal option for spectrometer systems.

  10. Discrimination of neutrons and {\\gamma}-rays in liquid scintillator based on Elman neural network

    CERN Document Server

    Zhang, Cai-Xun; Zhao, Jian-Ling; Wang, Li; Yu, Xun-Zhen; Zhu, Jing-Jun; Xing, Hao-Yang

    2015-01-01

    A new neutron and {\\gamma} (n/{\\gamma}) discrimination method based on Elman Neural Network (ENN) was put forward to improve the n/{\\gamma} discrimination performance of liquid scintillator (LS). In this study, neutron and {\\gamma} data acquired from EJ-335 which was exposed in Am-Be radiation field was discriminated using ENN. The difference of n/{\\gamma} discrimination performance between using ENN and Back Propagation Neural Network (BPNN) is that ENN gave a improvement over BPNN in n/{\\gamma} discrimination with the increasing increasing of the Figure of Merit (FOM) from 0.907 to 0.953.

  11. PoGOLino: a scintillator-based balloon-borne neutron detector

    CERN Document Server

    Kole, Merlin; Fukazawa, Yasushi; Fukuda, Kentaro; Ishizu, Sumito; Jackson, Miranda; Kamae, Tune; Kawaguchi, Noriaki; Kawano, Takafumi; Kiss, Mozsi; Moretti, Elena; Pearce, Mark; Rydström, Stefan; Takahashi, Hiromitsu; Yanagida, Takayuki

    2014-01-01

    PoGOLino is a balloon-borne scintillator-based experiment developed to study the largely unexplored high altitude neutron environment at high geomagnetic latitudes. The instrument comprises two detectors that make use of LiCAF, a novel neutron sensitive scintillator, sandwiched by BGO crystals for background reduction. The experiment was launched on March 20th 2013 from the Esrange Space Centre, Northern Sweden (geomagnetic latitude of $65^\\circ$), for a three hour flight during which the instrument took data up to an altitude of 30.9 km. The detector design and ground calibration results are presented together with the measurement results from the balloon flight.

  12. Spherical harmonics method for neutron transport equation based on unstructured-meshes

    Institute of Scientific and Technical Information of China (English)

    CAO Liang-Zhi; WU Hong-Chun

    2004-01-01

    Based on a new second-order neutron transport equation, self-adjoint angular flux (SAAF) equation, the spherical harmonics (PN) method for neutron transport equation on unstructured-meshes is derived. The spherical harmonics function is used to expand the angular flux. A set of differential equations about the spatial variable, which are coupled with each other, can be obtained. They are solved iteratively by using the finite element method on unstructured-meshes. A two-dimension transport calculation program is coded according to the model. The numerical results of some benchmark problems demonstrate that this method can give high precision results and avoid the ray effect very well.

  13. Temperature changes under demineralized dentin during polymerization of three resin-based restorative materials using QTH and LED units

    Directory of Open Access Journals (Sweden)

    Sayed-Mostafa Mousavinasab

    2014-08-01

    Full Text Available Objectives Light-curing of resin-based materials (RBMs increases the pulp chamber temperature, with detrimental effects on the vital pulp. This in vitro study compared the temperature rise under demineralized human tooth dentin during light-curing and the degrees of conversion (DCs of three different RBMs using quartz tungsten halogen (QTH and light-emitting diode (LED units (LCUs. Materials and Methods Demineralized and non-demineralized dentin disks were prepared from 120 extracted human mandibular molars. The temperature rise under the dentin disks (n = 12 during the light-curing of three RBMs, i.e. an Ormocer-based composite resin (Ceram. X, Dentsply DeTrey, a low-shrinkage silorane-based composite (Filtek P90, 3M ESPE, and a giomer (Beautifil II, Shofu GmbH, was measured with a K-type thermocouple wire. The DCs of the materials were investigated using Fourier transform infrared spectroscopy. Results The temperature rise under the demineralized dentin disks was higher than that under the non-demineralized dentin disks during the polymerization of all restorative materials (p 0.05. Conclusions Although there were no significant differences in the DCs, the temperature rise under demineralized dentin disks for the silorane-based composite was higher than that for dimethacrylate-based restorative materials, particularly with QTH LCU.

  14. An algorithm for 252Cf-Source-Driven neutron signal denoising based on Compressive Sensing

    Institute of Scientific and Technical Information of China (English)

    李鹏程; 魏彪; 冯鹏; 何鹏; 米德伶

    2015-01-01

    As photoelectrically detected 252Cf-source-driven neutron signals always contain noise, a denoising algorithm is proposed based on compressive sensing for the noised neutron signal. In the algorithm, Empirical Mode Decomposition (EMD) is applied to decompose the noised neutron signal and then find out the noised Intrinsic Mode Function (IMF) automatically. Thus, we only need to use the basis pursuit denoising (BPDN) algorithm to denoise these IMFs. For this reason, the proposed algorithm can be called EMDCSDN (Empirical Mode Decomposition Compressive Sensing Denoising). In addition, five indicators are employed to evaluate the denoising effect. The results show that the EMDCSDN algorithm is more effective than the other denoising algorithms including BPDN. This study provides a new approach for signal denoising at the front-end.

  15. Discrete ordinates method for three-dimensional neutron transport equation based on unstructured-meshes

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    A discrete ordinates method for a threedimensional first-order neutron transport equation based on unstructured-meshes that avoids the singularity of the second-order neutron transport equation in void regions was derived.The finite element variation equation was obtained using the least-squares method.A three-dimensional transport calculation code was developed.Both the triangular-z and the tetrahedron elements were included.The numerical results of some benchmark problems demonstrated that this method can solve neutron transport problems in unstructuredmeshes very well.For most problems,the error of the eigenvalue and the angular flux is less than 0.3% and 3.0% respectively.

  16. Tensile bond strength of silicone-based soft denture liner to two chemically different denture base resins after various surface treatments.

    Science.gov (United States)

    Akin, Hakan; Tugut, Faik; Guney, Umit; Kirmali, Omer; Akar, Turker

    2013-01-01

    This study evaluated the effect of various surface treatments on the tensile bond strength of a silicone-based soft denture liner to two chemically different denture base resins, heat-cured polymethyl methacrylate (PMMA), and light-activated urethane dimethacrylate or Eclipse denture base resin. PMMA test specimens were fabricated and relined with a silicone-based soft denture liner (group AC). Eclipse test specimens were prepared according to the manufacturer's recommendation. Before they were relined with a silicone-based soft denture liner, each received one of three surface treatments: untreated (control, group EC), Eclipse bonding agent applied (group EB), and laser-irradiated (group EL). Tensile bond strength tests (crosshead speed = 5 mm/min) were performed for all specimens, and the results were analyzed using the analysis of variance followed by Tukey's test (p = 0.05). Eclipse denture base and PMMA resins presented similar bond strengths to the silicone-based soft denture liner. The highest mean force was observed in group EL specimens, and the tensile bond strengths in group EL were significantly different (p < 0.05) from those in the other groups.

  17. [Acrylic resin removable partial dentures

    NARCIS (Netherlands)

    Baat, C. de; Witter, D.J.; Creugers, N.H.J.

    2011-01-01

    An acrylic resin removable partial denture is distinguished from other types of removable partial dentures by an all-acrylic resin base which is, in principle, solely supported by the edentulous regions of the tooth arch and in the maxilla also by the hard palate. When compared to the other types of

  18. Flexural Strength of Acrylic Resin Denture Bases Processed by Two Different Methods

    Directory of Open Access Journals (Sweden)

    Jafar Gharechahi

    2014-09-01

    Full Text Available Background and aims. The aim of this study was to compare flexural strength of specimens processed by conventional and injection-molding techniques. Materials and methods. Conventional pressure-packed PMMA was used for conventional pressure-packed and injection-molded PMMA was used for injection-molding techniques. After processing, 15 specimens were stored in distilled water at room temperature until measured. Three-point flexural strength test was carried out. Statistical analysis was carried out by SPSS using t-test. Statistical significance was defined at P<0.05. Results. Flexural strength of injection-polymerized acrylic resin specimens was higher than that of theconventional method (P=0.006. This difference was statistically significant (P=0.006. Conclusion. Within the limitations of this study, flexural strength of acrylic resin specimens was influenced by the mold-ing technique.

  19. Flexural strength of acrylic resin denture bases processed by two different methods.

    Science.gov (United States)

    Gharechahi, Jafar; Asadzadeh, Nafiseh; Shahabian, Foad; Gharechahi, Maryam

    2014-01-01

    Background and aims. The aim of this study was to compare flexural strength of specimens processed by conventional and injection-molding techniques. Materials and methods. Conventional pressure-packed PMMA was used for conventional pressure-packed and injection-molded PMMA was used for injection-molding techniques. After processing, 15 specimens were stored in distilled water at room temperature until measured. Three-point flexural strength test was carried out. Statistical analysis was carried out by SPSS using t-test. Statistical significance was defined at P<0.05. Results. Flexural strength of injection-polymerized acrylic resin specimens was higher than that of the conventional method (P=0.006). This difference was statistically significant (P=0.006). Conclusion. Within the limitations of this study, flexural strength of acrylic resin specimens was influenced by the molding technique.

  20. Optical waveguide BTX gas sensor based on polyacrylate resin thin film.

    Science.gov (United States)

    Kadir, Razak; Yimit, Abliz; Ablat, Hayrensa; Mahmut, Mamtimin; Itoh, Kiminori

    2009-07-01

    An optical sensor sensitive to BTX has been developed by spin coating a thin film of polyacrylate resin onto a tin- diffused glass optical waveguide. A pair of prism coupler was employed for optical coupling matched with diiodomethane (CH2l2). The guided wave transmits in waveguide layer and passes through the film as an evanescent wave. Polyacrylate film has a strong capacity of absorbing oil gases. The film is stable in N2 but benzene exposure at room temperature can result in rapid and reversible changes of transmittance (7) and refractive index (n1) of this film. It has been demonstrated that the sensor containing a 10 mm boardand about a hundred nanometers thick resin film can detect lower than 8 ppm BTX.

  1. PHOTOCURING STUDY OF NEW DENTAL RESINS BASED ON MULTIFUNCTIONAL ACRYLIC ISOCYANURATE BY PHOTOCALORIMETRY

    Institute of Scientific and Technical Information of China (English)

    Jun Nie; Wen-hui Zhou; Miao-zhen Li; Er-jian Wang; L.A. Linden; J.F. Rabek

    1999-01-01

    Photocuring of new dental resins composed of tri(2-hydroxyethyl) isocyanurate triacrylate (THITA)alone and its mixtures with trimethylolpropane triacrylate (TMPTA) or pentaerythritol triacrylate (PETA) initiated by camphorquinone/amine system was studied by photocalorimetry. Among several different amines as coinitiators, 2-ethyl-4-dimethylaminobenzoate (AM-3), N,N-dimethylbenzylamine (AM-5) and 2,4,6-[tri(dimethylaminomethyl)]phenol (AM-6) are most effective. Upon irradiation, photopolymerization can occur immediately and no induction period appears in N2 nor in air. Comparing the THITA/TMPTA and THITA/PETA mixtures, the parameters of photopolymerization and hardness of photocured samples show a small difference and only change slightly with varying molar ratios of mixture. In the presence of inorganic filler, the hardness of photocuring resins is almost the same as that for commercial products.

  2. Compact Short-Pulsed Electron Linac Based Neutron Sources for Precise Nuclear Material Analysis

    Science.gov (United States)

    Uesaka, M.; Tagi, K.; Matsuyama, D.; Fujiwara, T.; Dobashi, K.; Yamamoto, M.; Harada, H.

    2015-10-01

    An X-band (11.424GHz) electron linac as a neutron source for nuclear data study for the melted fuel debris analysis and nuclear security in Fukushima is under development. Originally we developed the linac for Compton scattering X-ray source. Quantitative material analysis and forensics for nuclear security will start several years later after the safe settlement of the accident is established. For the purpose, we should now accumulate more precise nuclear data of U, Pu, etc., especially in epithermal (0.1-10 eV) neutrons. Therefore, we have decided to modify and install the linac in the core space of the experimental nuclear reactor "Yayoi" which is now under the decommission procedure. Due to the compactness of the X-band linac, an electron gun, accelerating tube and other components can be installed in a small space in the core. First we plan to perform the time-of-flight (TOF) transmission measurement for study of total cross sections of the nuclei for 0.1-10 eV energy neutrons. Therefore, if we adopt a TOF line of less than 10m, the o-pulse length of generated neutrons should be shorter than 100 ns. Electronenergy, o-pulse length, power, and neutron yield are ~30 MeV, 100 ns - 1 micros, ~0.4 kW, and ~1011 n/s (~103 n/cm2/s at samples), respectively. Optimization of the design of a neutron target (Ta, W, 238U), TOF line and neutron detector (Ce:LiCAF) of high sensitivity and fast response is underway. We are upgrading the electron gun and a buncher to realize higher current and beam power with a reasonable beam size in order to avoid damage of the neutron target. Although the neutron flux is limited in case of the X-band electron linac based source, we take advantage of its short pulse aspect and availability for nuclear data measurement with a short TOF system. First, we form a tentative configuration in the current experimental room for Compton scattering in 2014. Then, after the decommissioning has been finished, we move it to the "Yayoi" room and perform

  3. Shear bond strength of a denture base acrylic resin and gingiva-colored indirect composite material to zirconia ceramics.

    Science.gov (United States)

    Kubochi, Kei; Komine, Futoshi; Fushiki, Ryosuke; Yagawa, Shogo; Mori, Serina; Matsumura, Hideo

    2017-04-01

    To evaluate the shear bond strengths of two gingiva-colored materials (an indirect composite material and a denture base acrylic resin) to zirconia ceramics and determine the effects of surface treatment with various priming agents. A gingiva-colored indirect composite material (CER) or denture base acrylic resin (PAL) was bonded to zirconia disks with unpriming (UP) or one of seven priming agents (n=11 each), namely, Alloy Primer (ALP), Clearfil Photo Bond (CPB), Clearfil Photo Bond with Clearfil Porcelain Bond Activator (CPB+Act), Metal Link (MEL), Meta Fast Bonding Liner (MFB), MR. bond (MRB), and V-Primer (VPR). Shear bond strength was determined before and after 5000 thermocycles. The data were analyzed with the Kruskal-Wallis test and Steel-Dwass test. The mean pre-/post-thermalcycling bond strengths were 1.0-14.1MPa/0.1-12.1MPa for the CER specimen and 0.9-30.2MPa/0.1-11.1MPa for the PAL specimen. For the CER specimen, the ALP, CPB, and CPB+Act groups had significantly higher bond strengths among the eight groups, at both 0 and 5000 thermocycles. For the PAL specimen, shear bond strength was significantly lower after thermalcycling in all groups tested. After 5000 thermocycles, bond strengths were significantly higher in the CPB and CPB+Act groups than in the other groups. For the PAL specimens, bond strengths were significantly lower after thermalcycling in all groups tested. The MDP functional monomer improved bonding of a gingiva-colored indirect composite material and denture base acrylic resin to zirconia ceramics. Copyright © 2016 Japan Prosthodontic Society. Published by Elsevier Ltd. All rights reserved.

  4. A small-angle neutron scattering study of cholic acid-based organogel systems

    NARCIS (Netherlands)

    Willemen, H.M.; Marcelis, A.T.M.; Sudhölter, E.J.R.; Bouwman, W.G.; Deme, B.; Terech, P.

    2004-01-01

    Small-angle neutron scattering measurements were performed on some cholic acid-based gel systems in order to gain detailed information about the network structure. The presence of thin fibers with a radius of about 10-20 Å was found for various gelators. Two types of interaction between different so

  5. Research progress in bio-based epoxy resins%生物基环氧树脂的研究进展

    Institute of Scientific and Technical Information of China (English)

    马松琪; 刘小青; 朱锦

    2014-01-01

    In oder to solve the unsustainability and toxicity problems of the traditional bisphenol A type epoxy resins,one of the best solutions is synthesizing the epoxy resins with the bio-based raw materials.Our researchers in the bio-based polymer material research group of Ningbo Institute of Materials Technology&Engineering (Chinese Academy of Science) have done a lot of work in preparation of the bio-based epoxy resins.Based on the progress in home and abroad,this paper introduced the research work in preparing the bio-based epoxy resins with rosin, itaconic acid and gallic acid as the raw materials,and presented the raises prospect of future development in the bio-based epoxy resins.%以生物基原料合成环氧树脂是目前解决双酚A环氧树脂原料不可持续性和毒性问题最切实可行的方案。在综述国内外生物基环氧树脂研究进展的基础上,对最近几年我们基于松香、衣康酸、没食子酸合成生物基环氧树脂方面的研究进展进行了介绍,在此基础上进行了总结和展望。

  6. High Performance Fatty Acid-Based Vinyl Ester Resin for Liquid Molding

    Science.gov (United States)

    2007-07-01

    novolac epoxy, and Epon 828, a diglycidyl ether of bisphenol A ( DGEBA ), were purchased from Hexion Specialty Chemicals and was used to synthesize vinyl... DGEBA vinyl ester resins with n~0.1 and containing no styrene, CN 151 and RDX 26936, were obtained from Sartomer and Cytec Surface Specialties Inc...Diglycidyl ether of bisphenol-A ( DGEBA ) Methacrylic Acid Figure 1: The reaction of DGEBA and methacrylic acid to produce the vinyl ester 2.3

  7. Neutron time-of-flight spectrometer based on HIRFL for studies of spallation reactions related to ADS project

    Institute of Scientific and Technical Information of China (English)

    张苏雅拉吐; 罗飞; 陈志强; 韩瑞; 刘星泉; 林炜平; 刘建立; 石福栋; 任培培; 田国玉

    2015-01-01

    A Neutron Time-of-Flight (NTOF) spectrometer, based at the Heavy Ion Research Facility in Lanzhou (HIRFL) was developed for studies of neutron production of proton induced spallation reactions related to the ADS project. After the presentation of comparisons between calculated spallation neutron production double-differential cross sections and the available experimental data, a detailed description of the NTOF spectrometer is given. Test beam results show that the spectrometer works well and data analysis procedures are established. The comparisons of the test beam neutron spectra with those of GEANT4 simulations are presented.

  8. The 10B based Jalousie neutron detector - An alternative for 3He filled position sensitive counter tubes

    Science.gov (United States)

    Henske, M.; Klein, M.; Köhli, M.; Lennert, P.; Modzel, G.; Schmidt, C. J.; Schmidt, U.

    2012-09-01

    Over the last decades 3He filled proportional counter tubes were the working horse employed to serve as neutron counters especially in cases where large area coverage was required. Today the lack of 3He demands the development of an alternative technology. Here we present a prototype neutron detector that is <