WorldWideScience

Sample records for residues including heavy

  1. HDHPLUS/SHP : heavy residue hydroconversion technology

    Energy Technology Data Exchange (ETDEWEB)

    Morel, F. [Axens, Rueil Malmaison (France)

    2009-07-01

    This presentation described an integrated refinery process that achieves nearly full conversion of heavy and refractory residues into ultra high quality and ultra low sulphur transportation fuels with a yield great than 100 volume per cent. The Axens, IFP and Intevep/PDVSA Alliance combined the HDHPLUS vacuum residue slurry technology with Sequential Hydro Processing (SHP) of primary hydrocracked products. Both technologies have undergone extensive testing at a refinery in Puerto La Cruz (RPLC), Venezuela to begin production of 50,000 BPSD in 2012. The demonstration unit at Intevep has been used to investigate production of effluent for the downstream SHP processing. This paper also reviewed the SHP bench unit operations at IFP's Lyon research center in France and disclosed the final product yields and qualities. The test results have shown the expected RPLC deep conversion commercial unit performances and fully secure its design basis. tabs., figs.

  2. Heavy Metals Behavior During Thermal Plasma Vitrification Of Incineration Residues

    Science.gov (United States)

    Cerqueira, Nuno; Vandensteendam, Colette; Baronnet, Jean Marie

    2006-01-01

    Incineration of wastes, widely and increasingly used nowadays, produces residues, mainly bottom ash and filter fly ash. Fly ash is especially problematic because of its high content in heavy metals easily drawn out. Thermal processes, based mainly on electrical arc processes, are used to melt the residues at high temperature and convert them into a relatively inert glass. Consequently, to improve the process and get a glass satisfying regulation, control of heavy metals (lead, zinc, cadmium and chromium…) volatility during plasma fly ash melting and vitrification is needed and basic data concerning vaporization of these metals are required. According to the volatility of these compounds observed during vitrification of fly ash, a predictive model has been used to simulate the elimination of Pb, Zn and S from the melt as a function of time and temperature for a system including chlorides, oxides and sulfates. The objective of this work was the experimental study of heavy metals volatility using optical emission spectroscopy. A twin torch plasma system, mounted above a cold crucible with Ar (or Ar + O2) as plasma gas, has been used. The crucible was filled with synthetic glass in which known amounts of metallic salts were added to obtain the same chemical composition as used in the model. From spectral lines intensities of Ar, the plasma temperature profiles along the observation direction has been first established, before using ratios of spectral lines of Ar and metallic (Pb, Zn) or Cl vapors to reach the evolution of the elements concentrations above the melt. Off-gases have been analyzed by mass spectrometry. The influence of the atmosphere (Ar or Ar + O2) above the crucible has been studied and differences in elements behaviors have been pointed out. The results of the spectroscopic measurements have been compared to the ones issued of modeling, in order to validate our model of vaporization.

  3. AN ALTERNATIVE APPROACH TO THE USE OF HEAVY OIL RESIDUE

    Directory of Open Access Journals (Sweden)

    Eugene Dashut

    2013-01-01

    Full Text Available We consider an alternative approach to the existing oil refining, in which instead of a single priority that emerged in the traditional approach, we consider two: get the light component and a heavy residue used for the production of new construction materials.

  4. Evaluation of heavy metals in hazardous automobile shredder residue thermal residue and immobilization with novel nano-size calcium dispersed reagent.

    Science.gov (United States)

    Lee, Chi-Hyeon; Truc, Nguyen Thi Thanh; Lee, Byeong-Kyu; Mitoma, Yoshiharu; Mallampati, Srinivasa Reddy

    2015-10-15

    This study was conducted to synthesize and apply a nano-size calcium dispersed reagent as an immobilization material for heavy metal-contaminated automobile shredder residues (ASR) dust/thermal residues in dry condition. Simple mixing with a nanometallic Ca/CaO/PO4 dispersion mixture immobilized 95-100% of heavy metals in ASR dust/thermal residues (including bottom ash, cavity ash, boiler and bag filter ash). The quantity of heavy metals leached from thermal residues after treatment by nanometallic Ca/CaO/PO4 was lower than the Korean standard regulatory limit for hazardous waste landfills. The morphology and elemental composition of the nanometallic Ca/CaO-treated ASR residue were characterized by field emission scanning election microscopy combined with electron dispersive spectroscopy (FE-SEM/EDS). The results indicated that the amounts of heavy metals detectable on the ASR thermal residue surface decreased and the Ca/PO4 mass percent increased. X-ray diffraction (XRD) pattern analysis indicated that the main fraction of enclosed/bound materials on ASR residue included Ca/PO4- associated crystalline complexes, and that immobile Ca/PO4 salts remarkably inhibited the desorption of heavy metals from ASR residues. These results support the potential use of nanometallic Ca/CaO/PO4 as a simple, suitable and highly efficient material for the gentle immobilization of heavy metals in hazardous ASR thermal residue in dry condition. Copyright © 2015 Elsevier B.V. All rights reserved.

  5. Spatial variation in Heavy Metal residue in Corchorus olitorious ...

    African Journals Online (AJOL)

    Michael Horsfall

    soil and atmospheric contamination poses a threat to its quality and safety. Dietary intake of heavy metals ... atmosphere, the concentration of heavy metals in soil, the nature of soil and the degree of maturity of the plants at ..... include behavioral disturbances, learning and concentration difficulties and people who may have.

  6. Evaluation of heavy metals in hazardous automobile shredder residue thermal residue and immobilization with novel nano-size calcium dispersed reagent

    International Nuclear Information System (INIS)

    Lee, Chi-Hyeon; Truc, Nguyen Thi Thanh; Lee, Byeong-Kyu; Mitoma, Yoshiharu; Mallampati, Srinivasa Reddy

    2015-01-01

    Graphical abstract: Schematic representation of possible mechanisms determining the heavy metals immobilization efficiencyof ASR dust/thermal residues after treatment with nanometallic Ca/CaO/PO 4 . - Highlights: • Nanometallic Ca/CaO/PO 4 for heavy metals immobilization in ASR residue. • Heavy metals immobilization in dry condition attained about 95–100%. • Remaining heavy metals were lower than the Korean standard regulatory limit. • The amounts of heavy metals detectable on the ASR dust surface decreased. • Nanometallic Ca/CaO/PO 4 has a promising potential for heavy metal remediation. - Abstract: This study was conducted to synthesize and apply a nano-size calcium dispersed reagent as an immobilization material for heavy metal-contaminated automobile shredder residues (ASR) dust/thermal residues in dry condition. Simple mixing with a nanometallic Ca/CaO/PO 4 dispersion mixture immobilized 95–100% of heavy metals in ASR dust/thermal residues (including bottom ash, cavity ash, boiler and bag filter ash). The quantity of heavy metals leached from thermal residues after treatment by nanometallic Ca/CaO/PO 4 was lower than the Korean standard regulatory limit for hazardous waste landfills. The morphology and elemental composition of the nanometallic Ca/CaO-treated ASR residue were characterized by field emission scanning election microscopy combined with electron dispersive spectroscopy (FE-SEM/EDS). The results indicated that the amounts of heavy metals detectable on the ASR thermal residue surface decreased and the Ca/PO 4 mass percent increased. X-ray diffraction (XRD) pattern analysis indicated that the main fraction of enclosed/bound materials on ASR residue included Ca/PO 4 − associated crystalline complexes, and that immobile Ca/PO 4 salts remarkably inhibited the desorption of heavy metals from ASR residues. These results support the potential use of nanometallic Ca/CaO/PO 4 as a simple, suitable and highly efficient material for the gentle

  7. Heavy metals behavior during thermal plasma vitrification of incineration residues

    International Nuclear Information System (INIS)

    Cerqueira, N.; Vandensteendam, C.; Baronnet, J.M.

    2005-01-01

    In the developed world, incineration of wastes is widely and increasingly practiced. Worldwide, a total of approximately 100 millions of tons of municipal solid waste (MSW) material is incinerated annually. Incineration of one ton of MSW leads to the formation of 30 to 50 kg of fly ash, depending on the type of incinerator. The waste disposal of these dusts already causes great problems today; they are of low bulk density, they contain high concentrations of hazardous water-soluble heavy metal compounds, organohalogen compounds (dioxines, furanes), sulfur, and chlorinated compounds. Thermal processes, based mainly on electrical arc processes, show great promise: the residues are melted at high temperature and converted in a relatively inert glass. A few tens of plants, essentially in Japan and Taiwan, have been in industrial operation for a few years. To be authorized to be dumped in a common landfill, the glassy product has to satisfy the leaching test procedure to ensure long-term durability. But to satisfy the regulation to be reused, for example as a nonhazardous standard material in road building, the glassy product would probably include contents in some heavy metals lower than critical limits. So today, there are two alternatives: the first one is to improve the heavy toxic metals evaporation to get a 'light' glassy product and to recycle separately the said separated metals; the second is on the contrary to improve the incorporation of a maximum of heavy metals into the vitreous silicate matrix. Whatever, it is highly required to control, in situ and in real time, volatility of these metals during ash melting under electrical arc. The objective of this work was to reach basic data about metals volatility under the plasma column of an electrical arc transferred on the melt: an experiment has been designed to examine the effects of processing conditions, such as melt temperature, melt composition, and furnace atmosphere, upon volatilization and glassy slag

  8. Heavy residue properties in intermediate energy nuclear collisions with gold

    International Nuclear Information System (INIS)

    Aleklett, K.; Sihver, L.; Liljenzin, J.O.; Seaborg, G.T.

    1990-10-01

    We have measured the target fragment production cross sections and angular distributions for the interaction of 32, 44 and 93 MeV/nucleon argon, 35 and 43 MeV/nucleon krypton with gold. The fragment isobaric yield distributions, moving frame angular distributions and velocities have been deduced from these data. This fission cross section decreases with increasing projectile energy and the heavy residue cross section increases. The ratio v parallel /v cn increases approximately linearly with mass removed from the target. 21 refs., 8 figs

  9. Novel synthesis and applications of Thiomer solidification for heavy metals immobilization in hazardous ASR/ISW thermal residue.

    Science.gov (United States)

    Baek, Jin Woong; Mallampati, Srinivasa Reddy; Park, Hung Suck

    2016-03-01

    The present paper reports the novel synthesis and application of Thiomer solidification for heavy metal immobilization in hazardous automobile shredder residues and industrial solid waste (ASR/ISW) thermal residues. The word Thiomer is a combination of the prefix of a sulfur-containing compound "Thio" and the suffix of "Polymer" meaning a large molecule compound of many repeated subunits. To immobilize heavy metals, either ASR/ISW thermal residues (including bottom and fly ash) was mixed well with Thiomer and heated at 140°C. After Thiomer solidification, approximately 91-100% heavy metal immobilization was achieved. The morphology and mineral phases of the Thiomer-solidified ASR/ISW thermal residue were characterized by field emission-scanning electron microscopy, energy dispersive X-ray spectroscopy and X-ray diffraction (XRD), which indicated that the amounts of heavy metals detectable on the ASR/ISW thermal residue surface decreased and the sulfur mass percent increased. XRD indicated that the main fraction of the enclosed/bound materials on the ASR/ISW residue contained sulfur associated crystalline complexes. The Thiomer solidified process could convert the heavy metal compounds into highly insoluble metal sulfides and simultaneously encapsulate the ASR/ISW thermal residue. These results show that the proposed method can be applied to the immobilization of ASR/ISW hazardous ash involving heavy metals. Copyright © 2015 Elsevier Ltd. All rights reserved.

  10. Study on 'Tannix' an absorbent for heavy metals including uranium

    International Nuclear Information System (INIS)

    Nakamura, Yasuo

    1997-01-01

    To treat radioactive wastes including uranium and transuranic elements such as plutonium, americium etc., development of an absorbent which can be used to absorb and isolate these elements without producing secondary wastes after treatment was attempted. And an absorbent has been successfully developed by polymerizing tannin, a natural product. It is known that tannin binds heavy metals including uranium resulting to produce their precipitates. There are some reports suggesting its absorption ability for uranium. However, tannin has not been used to isolate a heavy metal from a solution because it is soluble in water. Here, insolubilization of tannin was attempted and a manufacturing method for a gelatinized insoluble tannin named as ''Tannix'' was established. Wattle tannin extracted from Mimosa pudica produced in Africa was dissolved in an alkaline solution and gelatinized by heating after the addition of formalin. Thus obtained insoluble tannin was used after crushing and sieving. This product, ''Tannix'' was able to absorb more than 99% of uranium in the waste. And the absorbed Tannin could be degraded by incineration even at a low temperature, leaving only uranium, but not producing any secondary product. (M.N.)

  11. Study on `Tannix` an absorbent for heavy metals including uranium

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, Yasuo [Mitsubishi Nuclear Fuel Co. Ltd., Tokyo (Japan)

    1997-09-01

    To treat radioactive wastes including uranium and transuranic elements such as plutonium, americium etc., development of an absorbent which can be used to absorb and isolate these elements without producing secondary wastes after treatment was attempted. And an absorbent has been successfully developed by polymerizing tannin, a natural product. It is known that tannin binds heavy metals including uranium resulting to produce their precipitates. There are some reports suggesting its absorption ability for uranium. However, tannin has not been used to isolate a heavy metal from a solution because it is soluble in water. Here, insolubilization of tannin was attempted and a manufacturing method for a gelatinized insoluble tannin named as ``Tannix`` was established. Wattle tannin extracted from Mimosa pudica produced in Africa was dissolved in an alkaline solution and gelatinized by heating after the addition of formalin. Thus obtained insoluble tannin was used after crushing and sieving. This product, ``Tannix`` was able to absorb more than 99% of uranium in the waste. And the absorbed Tannin could be degraded by incineration even at a low temperature, leaving only uranium, but not producing any secondary product. (M.N.)

  12. Reduction of heavy metals in residues from the dismantling of waste electrical and electronic equipment before incineration.

    Science.gov (United States)

    Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi; Hu, Li-Fang; Shen, Dong-Sheng

    2014-05-15

    Residues disposal from the dismantling of waste electrical and electronic equipment are challenging because of the large waste volumes, degradation-resistance, low density and high heavy metal content. Incineration is advantageous for treating these residues but high heavy metal contents may exist in incinerator input and output streams. We have developed and studied a specialized heavy metal reduction process, which includes sieving and washing for treating residues before incineration. The preferable screen aperture for sieving was found to be 2.36mm (8 meshes) in this study; using this screen aperture resulted in the removal of approximately 47.2% Cu, 65.9% Zn, 26.5% Pb, 55.4% Ni and 58.8% Cd from the residues. Subsequent washing further reduces the heavy metal content in the residues larger than 2.36mm, with preferable conditions being 400rpm rotation speed, 5min washing duration and liquid-to-solid ratio of 25:1. The highest cumulative removal efficiencies of Cu, Zn, Pb, Ni and Cd after sieving and washing reached 81.1%, 61.4%, 75.8%, 97.2% and 72.7%, respectively. The combined sieving and washing process is environmentally friendly, can be used for the removal of heavy metals from the residues and has benefits in terms of heavy metal recycling. Copyright © 2014 Elsevier B.V. All rights reserved.

  13. Heavy metal residues in beef carcasses in Beni-Suef abattoir, Egypt

    Directory of Open Access Journals (Sweden)

    Fathy A. Khalafalla

    2011-09-01

    Full Text Available A total of 300 samples were collected from cattle slaughtered in the Beni-Suef abattoir in Egypt. Samples included muscle, liver and kidney. Animals were randomly selected from the slaughter line. The age of the slaughtered cattle was less than three years (18-30 months. Samples were packed separately in plastic bags, identified and stored at -18°C until analysis which was performed at the Max Rubner Institute in Kulmbach, Germany, for the following heavy metals residues: lead, cadmium, mercury, arsenic, chromium and nickel in beef muscle, liver and kidney samples. The results revealed that the overall mean residual levels of lead were 8.77 µg/kg, 42.70 µg/kg and 109.42 µg/kg fresh weight in muscle, liver and kidney samples, respectively, while the mean residual levels of cadmium were 1.40 µg/kg, 14.16 µg/kg and 62.56 µg/kg fresh weight, respectively, and the mean arsenic residual levels were 5.06 µg/kg, 4.64 µg/kg and 14.92 µg/kg fresh weight, respectively. The mean residual levels of mercury were 3.91 µg/kg, 5.81 µg/kg and 10.14 µg/kg fresh weight, respectively, and the residual levels of chromium were 11.20 µg/kg, 21.85 µg/kg and 25.49 µg/kg fresh weight, respectively. Finally, the mean residual levels of nickel were 21.17 µg/kg, 14.59 µg/kg and 34.95 µg/kg fresh weight, respectively. The mean values of all heavy metals examined were low and did not exceed the permissible limits adopted by different organisations. Most heavy metals accumulated in higher concentrations in the kidney in comparison to the liver and muscle.

  14. Study of structure and residual stresses in cold rotary swaged tungsten heavy alloy

    Czech Academy of Sciences Publication Activity Database

    Kunčická, L.; Kocich, R.; Hervoches, Charles; Macháčková, A.

    2017-01-01

    Roč. 705, č. 9 (2017), s. 25-31 ISSN 0921-5093 R&D Projects: GA MŠk LM2015056 Institutional support: RVO:61389005 Keywords : Tungsten heavy alloy * residual stresses * neutron scattering * electron microscopy * work hardening Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) Impact factor: 3.094, year: 2016

  15. Residual activity induced by heavy ions and beam-loss criteria for heavy-ion accelerators

    Directory of Open Access Journals (Sweden)

    I. Strašík

    2010-07-01

    Full Text Available The paper presents results of FLUKA simulations of the residual activity induced by heavy ions in two target configurations representing: (1 a beam pipe of an accelerator and (2 a bulky accelerator structure like a magnet yoke or a coil. The target materials were stainless steel and copper representing the most common construction materials used for basic accelerator components. For these two materials, the inventory of the induced isotopes depends mainly on the target material and much less on the projectile species. Time evolution of the induced activity can be described by means of a generic curve that is independent from the projectile mass. Dependence of the induced residual activity on selected ion beam parameters was studied. The main goal of the study was establishing a scaling law expanding the existing proton beam-loss tolerance to heavy-ion beams. This scaling law enables specifying beam-loss criteria for projectile species from proton up to uranium at energies from 200  MeV/u up to 1  GeV/u.

  16. Extra heavy oil and refinery residues upgrading through Eni Slurry Technology : first EST commercial unit

    Energy Technology Data Exchange (ETDEWEB)

    Rispoli, G.; Sanfilippo, D.; Amoroso, A [Eni S.p.A., Rome (Italy)

    2009-07-01

    The production of heavy crude oils is projected to continue to grow in the upstream oil industry given that large reserves of unconventional extra heavy crude and bitumen exist in several geographic areas including Canada and Venezuela. As reserves of conventional crude oil continue to decline, these unconventional feedstocks are becoming an opportunity to pursue, but they require effective technologies for upgrading and meeting the growing demand for light and middle distillate fuels. This paper described the proprietary technology that offers a solution to upstream and downstream oil producers for bottom-of-the-barrel upgrading. En i Slurry Technology (EST) is constructing an industrial plant in its Sannazzaro refinery in Italy. The plant is designed to convert 23,000 BPSD of vacuum residue into high quality diesel and other valuable refinery streams such as liquefied petroleum gas, naphtha and jet fuel. EST is an H-addition process characterized by the use of a special homogeneous isothermal intrinsically safe reactor, and of a nano-dispersed non-ageing catalyst. EST converts more than 98 per cent of any type of residues to about 110 per cent volume of light products and distillates or extra heavy oils to high quality bottomless SCO. In typical performance, HDS is greater than 85 per cent, HDM greater than 99 per cent and HDCCR greater than 97 per cent. EST also achieves the target of zero fuel oil - zero coke. 12 refs., 4 tabs., 5 figs.

  17. Spatial variation in Heavy Metal residue in Corchorus olitorious ...

    African Journals Online (AJOL)

    distances of 10, 20 and 30m from the roadside and analyzed for Pb, Zn and Cd content by atomic absorption spectrophotometer. The mean concentration of heavy metals in the studied vegetable with effect to distance from the road was compared with the permissible values given by WHO/FAO. Mean concentration of heavy ...

  18. Pyrolysis and reutilization of plant residues after phytoremediation of heavy metals contaminated sediments: For heavy metals stabilization and dye adsorption.

    Science.gov (United States)

    Gong, Xiaomin; Huang, Danlian; Liu, Yunguo; Zeng, Guangming; Wang, Rongzhong; Wei, Jingjing; Huang, Chao; Xu, Piao; Wan, Jia; Zhang, Chen

    2018-04-01

    This study aimed to investigate the effect of pyrolysis on the stabilization of heavy metals in plant residues obtained after phytoremediation. Ramie residues, being collected after phytoremediation of metal contaminated sediments, were pyrolyzed at different temperatures (300-700 °C). Results indicated that pyrolysis was effective in the stabilization of Cd, Cr, Zn, Cu, and Pb in ramie residues by converting the acid-soluble fraction of metals into residual form and decreasing the TCLP-leachable metal contents. Meanwhile, the reutilization potential of using the pyrolysis products generated from ramie residues obtained after phytoremediation as sorbents was investigated. Adsorption experiments results revealed that the pyrolysis products presented excellent ability to adsorb methylene blue (MB) with a maximum adsorption capacity of 259.27 mg/g. This study demonstrated that pyrolysis could be used as an efficient alternative method for stabilizing heavy metals in plant residues obtained after phytoremediation, and their pyrolysis products could be reutilized for dye adsorption. Copyright © 2018 Elsevier Ltd. All rights reserved.

  19. Residue and heavy-oil conversion by thermal cracking: the TERVAHL processes

    Energy Technology Data Exchange (ETDEWEB)

    Billon, A.; Bousquet, J.

    1987-01-01

    This paper presents a report on the TERVAHL process for residue and heavy-oil conversion by thermal cracking. The principles of thermal cracking and the main characteristics of the TERVAHL processes are first examined, then the advantages for producers of extra-heavy crude and for refiners are presented. The TERVAHL T and TERVAHL H processes belong to the family of visbreaking processes characterized by a moderate conversion level below the threshold of the appearance of very viscous and unstable pitch. They improve viscosity at the production site for the producer of heavy crude and for the refiner, the visbreaking of residues by residues by using hydrogen pressure, and the preparation of feedstocks for deasphalting or hydroconversion.

  20. Impact of toxic heavy metals and pesticide residues in herbal products

    Directory of Open Access Journals (Sweden)

    Nema S. Shaban

    2016-03-01

    Full Text Available Medicinal plants have a long history of use in therapy throughout the world and still make an important part of traditional medicine. The World Health Organization (WHO estimates that 65%–80% of the world's populations depend on the herbal products as their primary form of health care. This review is conducted to provide a general idea about chemical contaminants such as heavy metals and pesticide residues as major common contaminants of the herbal medicine, which impose serious health risks to human health. Additionally, we aim to provide different analytical methods for analysis of heavy metals and pesticide residues in the herbal medicine.

  1. Heavy metal residues in tissues of marine turtles

    International Nuclear Information System (INIS)

    Storelli, M.M.; Marcotrigiano, G.O.

    2003-01-01

    Heavy metal concentrations in the tissues of marine turtles are presented. The most frequently monitored elements are mercury, cadmium and lead; and the tissues mainly analysed in nearly all the stranded individuals are muscle, liver and kidney. The highest mercury and cadmium levels were found in liver and kidney respectively; the majority of the lead burden existed in bones and carapace, while arsenic was present mainly in muscle tissue. Mercury occurred quite completely as methylmercury in muscle, whereas in liver the main form was the inorganic one. Arsenic was exclusively present in the metallorganic form either in muscle tissue or in liver. Metals in the eggs were mainly present in the yolk. Significantly higher concentration of mercury, copper, zinc and iron were found in yolk than albumen, while shell contained highest levels of manganese and copper. The load of trace metals in these animals strictly correlated with the species seems to depend on their different food behaviour

  2. CFD (Computational Fluid Dynamics) simulators and thermal cracking of heavy oil and ultraheavy residues using microreactor

    Energy Technology Data Exchange (ETDEWEB)

    Jardini, Andre L.; Bineli, Aulus R.R.; Viadana, Adriana M.; Maciel, Maria Regina Wolf; Maciel Filho, Rubens [State University of Campinas (UNICAMP), SP (Brazil). School of Chemical Engineering; Medina, Lilian C.; Gomes, Alexandre de O. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES); Barros, Ricardo S. [University Foundation Jose Bonifacio (FUJB), Rio de Janeiro, RJ (Brazil)

    2008-07-01

    In this paper, the design of microreactor with microfluidics channels has been carried out in Computer Aided Design Software (CAD) and constructed in rapid prototyping system to be used in chemical reaction processing of the heavy oil fractions. The flow pattern properties of microreactor (fluid dynamics, mixing behavior) have been considered through CFD (computational fluid dynamics) simulations. CFD calculations are also used to study the design and specification of new microreactor developments. The potential advantages of using a microreactor include better control of reaction conditions, improved safety and portability. A more detailed crude assay of the raw national oil, whose importance was evidenced by PETROBRAS/CENPES allows establishing the optimum strategies and processing conditions, aiming at a maximum utilization of the heavy oil fractions, towards valuable products. These residues are able to be processed in microreactor, in which conventional process like as hydrotreating, catalytic and thermal cracking may be carried out in a much more intensified fashion. The whole process development involves a prior thermal study to define the possible operating conditions for a particular task, the microreactor design through computational fluid dynamics and construction using rapid prototyping. This gives high flexibility for process development, shorter time, and costumer/task oriented process/product development. (author)

  3. Measurement of residual radioactivity in cooper exposed to high energy heavy ion beam

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Eunjoo; Nakamura, Takashi [Tohoku Univ., Sendai (Japan). Cyclotron and Radioisotope Center; Uwamino, Yoshitomo; Ito, Sachiko; Fukumura, Akifumi

    1999-03-01

    The residual radioactivities produced by high energy heavy ions have been measured using the heavy ion beams of the Heavy Ion Medical Accelerator (HIMAC) at National Institute of Radiological Sciences. The spatial distribution of residual radioactivities in 3.5 cm, 5.5 cm and 10 cm thick copper targets of 10 cm x 10 cm size bombarded by 290 MeV/u, 400 MeV/u-{sup 12}C ion beams and 400 MeV/u-{sup 20}Ne ion beam, respectively, were obtained by measuring the gamma-ray activities of 0.5 mm thick copper foil inserted in the target with a high purity Ge detector after about 1 hour to 6 hours irradiation. (author)

  4. Residual radioactivity guidelines for the heavy water components test reactor at the Savannah River Site

    International Nuclear Information System (INIS)

    Owen, M.B. Smith, R.; McNeil, J.

    1997-04-01

    Guidelines were developed for acceptable levels of residual radioactivity in the Heavy Water Components Test Reactor (HWCTR) facility at the conclusion of its decommissioning. Using source terms developed from data generated in a detailed characterization study, the RESRAD and RASRAD-BUILD computer codes were used to calculate derived concentration guideline levels (DCGLs) for the radionuclides that will remain in the facility. The calculated DCGLs, when compared to existing concentrations of radionuclides measured during a 1996 characterization program, indicate that no decontamination of concrete surfaces will be necessary. Also, based on the results of the calculations, activated concrete in the reactor biological shield does not have to be removed, and imbedded radioactive piping in the facility can remain in place. Viewed in another way, the results of the calculations showed that the present inventory of residual radioactivity in the facility (not including that associated with the reactor vessel and steam generators) would produce less than one millirem per year above background to a hypothetical individual on the property. The residual radioactivity is estimated to be approximately 0.04 percent of the total inventory in the facility as of March, 1997. According to the results, the only radionuclides that would produce greater than 0.0.1-millirem per year are Am-241 (0.013 mrem/yr at 300 years), C-14 (0.022 mrem/yr at 1000 years) and U-238 (0.034 mrem/yr at 6000 years). Human exposure would occur only through the groundwater pathways, that is, from water drawn from, a well on the property. The maximum exposure would be approximately one percent of the 4 millirem per year ground water exposure limit established by the U.S. Environmental Protection Agency. 11 refs., 13 figs., 15 tabs

  5. Uptake of Heavy Metal Residues from Sewerage Sludge in the Milk of Goat and Cattle during Summer Season

    Directory of Open Access Journals (Sweden)

    Bilal Aslam, Ijaz Javed*, Faqir Hussain Khan and Zia-ur-Rahman

    2011-01-01

    Full Text Available Uptake of different heavy metal residues including cadmium (Cd, chromium (Cr, nickel (Ni, led (Pb, arsenic (As, and mercury (Hg were determined in goat and cattle milk collected from two areas, each consisted of three sites. Area 1 was selected in the North-East and Area 2 in the North-West of Faisalabad city along the main sewerage drains. Levels of Cd, Cr, Ni, Pb, As and Hg in the milk of goat and cattle were higher than the most reported values in the literature. The levels of heavy metal residues in the milk of cattle from Area 1 were higher than those present in cattle milk from Area 2. However, in case of goat milk the residual values from Area 1 and Area 2 were non-significantly different. It was concluded that the levels of Cd, Cr, Ni, Pb, As and Hg in the milk of goat and cattle were higher than reported values in the literature.

  6. A tiered analytical protocol for the characterization of heavy oil residues at petroleum-contaminated hazardous waste sites

    International Nuclear Information System (INIS)

    Pollard, S.J.T.; Kenefick, S.L.; Hrudey, S.E.; Fuhr, B.J.; Holloway, L.R.; Rawluk, M.

    1994-01-01

    The analysis of hydrocarbon-contaminated soils from abandoned refinery sites in Alberta, Canada is used to illustrate a tiered analytical approach to the characterization of complex hydrocarbon wastes. Soil extracts isolated from heavy oil- and creosote-contaminated sites were characterized by thin layer chromatography with flame ionization detection (TLC-FID), ultraviolet fluorescence, simulated distillation (GC-SIMDIS) and chemical ionization GC-MS analysis. The combined screening and detailed analytical methods provided information essential to remedial technology selection including the extent of contamination, the class composition of soil extracts, the distillation profile of component classes and the distribution of individual class components within various waste fractions. Residual contamination was characteristic of heavy, degraded oils, consistent with documented site operations and length of hydrocarbon exposure at the soil surface

  7. In-situ burning of heavy oils and Orimulsion : analysis of soot and residue

    International Nuclear Information System (INIS)

    Fingas, M.F.; Wang, Z.; Fieldhouse, B.; Brown, C.E.; Yang, C.; Landriault, M.

    2005-01-01

    Oil spilled on water can be cleaned up by in-situ burning which can rapidly reduce the volume of spilled oil and eliminate the need to collect, store, transport and dispose of recovered oil. In-situ burning also shortens the response time to an oil spill, preventing the oil from reaching shorelines and thereby protecting the environment and aquatic biota. However, the concern over atmospheric emissions is the greatest barrier to the widespread use of in-situ burning. In this study, a series of bench-scale in-situ burning tests were conducted on Bunker C, Orimulsion and bitumen in order to analyze the residue and soot to gain insight into the chemistry of burning. The maximum burn efficiency was 70 per cent and the residue was mostly asphaltenes and resins which solidified when cooled. Soot was collected from glass-fibre filters on a sampling pump and the extracts were analyzed for polyaromatic hydrocarbons (PAHs). The analysis revealed that PAHs are enriched in pyrogenic PAHs and derive from the petrogenic PAHs in the starting oils. The PAH content is less than in many other environmental impacts. The solid residues were also analyzed for saturates of aromatics resins and asphaltenes (SARA). Their viscosity was also measured. The SARA analysis of the residue demonstrates that most of the heavy components such as the resins and asphaltenes are not burned by the fire, but are accumulated in the residue. 7 refs., 8 tabs., 6 figs

  8. Pesticide residues in grapes from vineyards included in integrated pest management in Slovenia.

    Science.gov (United States)

    Cesnik, H Basa; Gregorcic, A; Cus, F

    2008-04-01

    Although the list of pesticides used in integrated pest management (IPM) in grape growing and their annual application rates are limited, we are still confronted with the problem of pesticide residues in grapes. This paper presents the results of pesticide monitoring of 47 samples of wine grapes (Vitis vinifera L.) from the 2006 vintage from vineyards included in IPM. The grape samples were analysed for the presence of 67 pesticides. Among them 20 were allowed in IPM in 2006. Grapes were sampled at harvest. Two internal analytical methods were used for the determination of pesticides: gas chromatography-mass spectrometry (GC-MS) method for the determination of dithiocarbamates and a multi-residue GC-MS method. One grape sample (2.1%) contained no residues or they were below the limit of detection, 28 samples (59.6%) contained residues lower or equal than maximum residue levels (MRLs), and 18 samples (38.3%) exceeded national MRLs for cyprodinil (the concentration range was 0.03-0.40 mg kg(-1) of cyprodinil) and fludioxonil (concentration was 0.03 mg kg(-1) of fludioxonil). Multiple residues were found in 41 samples (87.2%). The highest number of pesticides detected per sample was seven. No violation of pesticides allowed in IPM was observed. Folpet (97.9%), cyprodinil (51.1%), dithiocarbamates (44.7%), chlorothalonil (23.4%), chlorpyriphos (19.1%) and pyrimethanil (14.9%) were the most frequently found pesticides in grapes. Risk assessment showed that the exceeded concentrations of cyprodinil and fludioxonil did not represent any risk for consumer's health (the national estimate of short-term intake as a percentage of the acceptable daily intake was below 100%).

  9. Characterization of Flame Cut Heavy Steel: Modeling of Temperature History and Residual Stress Formation

    Science.gov (United States)

    Jokiaho, T.; Laitinen, A.; Santa-aho, S.; Isakov, M.; Peura, P.; Saarinen, T.; Lehtovaara, A.; Vippola, M.

    2017-12-01

    Heavy steel plates are used in demanding applications that require both high strength and hardness. An important step in the production of such components is cutting the plates with a cost-effective thermal cutting method such as flame cutting. Flame cutting is performed with a controlled flame and oxygen jet, which burns the steel and forms a cutting edge. However, the thermal cutting of heavy steel plates causes several problems. A heat-affected zone (HAZ) is generated at the cut edge due to the steep temperature gradient. Consequently, volume changes, hardness variations, and microstructural changes occur in the HAZ. In addition, residual stresses are formed at the cut edge during the process. In the worst case, unsuitable flame cutting practices generate cracks at the cut edge. The flame cutting of thick steel plate was modeled using the commercial finite element software ABAQUS. The results of modeling were verified by X-ray diffraction-based residual stress measurements and microstructural analysis. The model provides several outcomes, such as obtaining more information related to the formation of residual stresses and the temperature history during the flame cutting process. In addition, an extensive series of flame cut samples was designed with the assistance of the model.

  10. Utilization of steel, pulp and paper industry solid residues in forest soil amendment: relevant physicochemical properties and heavy metal availability.

    Science.gov (United States)

    Mäkelä, Mikko; Watkins, Gary; Pöykiö, Risto; Nurmesniemi, Hannu; Dahl, Olli

    2012-03-15

    Industrial residue application to soil was investigated by integrating granulated blast furnace or converter steel slag with residues from the pulp and paper industry in various formulations. Specimen analysis included relevant physicochemical properties, total element concentrations (HCl+HNO3 digestion, USEPA 3051) and chemical speciation of chosen heavy metals (CH3COOH, NH2OH·HCl and H2O2+H2O2+CH3COONH4, the BCR method). Produced matrices showed liming effects comparable to commercial ground limestone and included significant quantities of soluble vital nutrients. The use of converter steel slag, however, led to significant increases in the total concentrations of Cr and V. Subsequently, total Cr was attested to occur as Cr(III) by Na2CO3+NaOH digestion followed by IC UV/VIS-PCR (USEPA 3060A). Additionally, 80.6% of the total concentration of Cr (370 mg kg(-1), d.w.) occurred in the residual fraction. However, 46.0% of the total concentration of V (2470 mg kg(-1), d.w.) occurred in the easily reduced fraction indicating potential bioavailability. Copyright © 2011 Elsevier B.V. All rights reserved.

  11. Transfer of heavy metals to biota after remediation of contaminated soils with calcareous residues.

    Science.gov (United States)

    Pérez-Sirvent, Carmen; Martínez-Sánchez, Maria Jose; Agudo, Ines; Gonzalez, Eva; Perez-Espinosa, Victor; Belen Martínez, Lucia; Hernández, Carmen; García-Fernandez, Antonio Juan; Bech, Jaime

    2013-04-01

    A study was carried out to evaluate the assimilation of heavy metals by three types of horticultural plants (broccoli, lettuce and leek), different parts of which are destined for human and farm animals consumption (leaves, roots, fruits). Five consecutive crops of each vegetable were obtained in greenhouse. In a second stage, experiments were carried out with rabbits fed with such vegetables. The plants were cultivated in four types of soil. The first one was contaminated by heavy metals (S1), the second was a uncontaminated soil (blank soil) (S2), the third was the material obtained by mixing S1 with residues coming from demolition and construction activities (S3); while the fourth was the result of remediating S1 with lime residues coming from quarries (S4). The total metal content (As, Pb, Cd and Zn) of the soil samples, rizosphere, leached water and vegetable samples, were measured, and both the translocation and bioconcentration factors (TF and BCF, respectively) were calculated. In the second stage, the effect caused in rabbits fed with the vegetables was monitorized using both external observation and the analysis of blood, urine, and the levels of metals in muscles, liver and kidney. The statistical analysis of the results obtained showed that there were no significant differences in the heavy metal levels for the vegetables cultivated in S2, S3 and S4. The results for soil sample S1 did not have a normal distribution since the growing of the vegetables were not homogeneous and also strongly dependent on the type of vegetal. As regards the effect caused in rabbits, significant differences were observed for the animals fed with plants cultivated in S1 compared with the others.

  12. Monitoring heavy metals, residual agricultural chemicals and sulfites in traditional herbal decoctions.

    Science.gov (United States)

    Yu, In-Sil; Lee, Jeong-Sook; Kim, Sung-Dan; Kim, Yun-Hee; Park, Hae-Won; Ryu, Hoe-Jin; Lee, Jib-Ho; Lee, Jeong-Mi; Jung, Kweon; Na, Cheol; Joung, Jin-Yong; Son, Chang-Gue

    2017-03-14

    Asian traditional herbal preparations are frequently considered for the contamination with undeclared toxic or hazardous substances. The aim of this study was to determine the toxic heavy metals, pesticides and sulfur dioxide in decoctions that is a common form of final utilization in Korea. A total of 155 decoctions composed of multi-ingredient traditional herbs were randomly sampled from Seoul in Korea between 2013 and 2014. For each decoction, the concentrations of four heavy metals (arsenic, cadmium, lead and mercury), 33 pesticides and sulfur dioxide were analyzed using inductively coupled plasma mass spectrometry (ICP-MS), mercury analyzer, gas chromatography/nitrogen phosphorous detector (GC/NPD), gas chromatography/micro electron capture detector (GC/μECD), and Monier-Williams method respectively. One hundred fifty-two of One hundred fifty-five decoctions (98.1%) contained one of three heavy metals (96.1% for As, 97.4% for Cd, and 90.3% for Pb, 0.0% for Hg). Their average concentrations (77.0 ± 79.7 ug/kg for As, 20.4 ± 23.7 ug/kg for Cd, and 68.8 ± 76.5 ug/kg for Pb) were approximately 20% of the maximum allowable limits of vegetable or ginseng beverage described in the Korean Food Standard Codex while their 95th percentile concentrations were below than the guideline for them. None of 33 pesticides was detected in 155 decoction samples, and only one sample showed over limit of detection for residual sulfites. This study support that the contained status of toxic heavy metals, pesticides and sulfur dioxide in herbal decoctions are currently within safe level in Korea, and provide a reference data for the further studies focused on the safety herbal preparations.

  13. Simulation of Weld Mechanical Behavior to Include Welding-Induced Residual Stress and Distortion: Coupling of SYSWELD and Abaqus Codes

    Science.gov (United States)

    2015-11-01

    Memorandum Simulation of Weld Mechanical Behavior to Include Welding-Induced Residual Stress and Distortion: Coupling of SYSWELD and Abaqus Codes...Weld Mechanical Behavior to Include Welding-Induced Residual Stress and Distortion: Coupling of SYSWELD and Abaqus Codes by Charles R. Fisher...Welding- Induced Residual Stress and Distortion: Coupling of SYSWELD and Abaqus Codes 5a. CONTRACT NUMBER N/A 5b. GRANT NUMBER N/A 5c

  14. Thermal Treatment of Iron Oxide Stabilized APC Residues from Waste Incineration and the Effect on Heavy Metal Binding

    DEFF Research Database (Denmark)

    Sørensen, Mette Abildgaard; Stackpoole, M.; Bender-Koch, C.

    2000-01-01

    Iron oxide stabilized APC residues from MSWI were heat treated at 600°C and 900°C. The thermal treatments resulted in a change in product stability by forcing a transformation in the mineralogical structures of the products. The treatments, moreover, simulated somewhat the natural aging processes...... that would take place in a stabilized residue. Consequent changes in crystalline structure and heavy metal binding were examined....

  15. Production of lightweight aggregates from mining residues, heavy metal sludge, and incinerator fly ash

    Energy Technology Data Exchange (ETDEWEB)

    Huang, S.-C. [Department of Atomic Science, National Tsing Hua University, 101, Sec. 2, Kuang Fu Road, Hsinchu 300, Taiwan (China); Chang, F.-C. [Research Center for Environmental Pollution Prevention and Control Technology, Graduate Institute of Environmental Engineering, National Taiwan University, 71 Chou-Shan Road, Taipei 106, Taiwan (China)]. E-mail: d90541003@ntu.edu.tw; Lo, S.-L. [Research Center for Environmental Pollution Prevention and Control Technology, Graduate Institute of Environmental Engineering, National Taiwan University, 71 Chou-Shan Road, Taipei 106, Taiwan (China); Lee, M.-Y. [Department of Civil Engineering, National Central University, 300 Jhongda Road, Jhongli 320, Taiwan (China); Wang, C.-F. [Department of Atomic Science, National Tsing Hua University, 101, Sec. 2, Kuang Fu Road, Hsinchu 300, Taiwan (China); Lin, J.-D. [Department of Civil Engineering, National Central University, 300 Jhongda Road, Jhongli 320, Taiwan (China)

    2007-06-01

    In this study, artificial lightweight aggregate (LWA) manufactured from recycled resources was investigated. Residues from mining, fly ash from an incinerator and heavy metal sludge from an electronic waste water plant were mixed into raw aggregate pellets and fed into a tunnel kiln to be sintered and finally cooled rapidly. Various feeding and sintering temperatures were employed to examine their impact on the extent of vitrification on the aggregate surface. Microstructural analysis and toxicity characteristic leaching procedure (TCLP) were also performed. The results show that the optimum condition of LWA fabrication is sintering at 1150 deg. C for 15 min with raw aggregate pellets fed at 750 deg. C. The rapidly vitrified surface envelops the gas produced with the increase in internal temperature and cooling by spraying water prevents the aggregates from binding together, thus forming LWA with specific gravity of 0.6. LWA produced by sintering in tunnel kiln shows good vitrified surface, low water absorption rate below 5%, and low cylindrical compressive strength of 4.3 MPa. In addition, only trace amounts of heavy metals were detected, making the LWA non-hazardous for construction use.

  16. Heavy-residue isoscaling as a probe of the symmetry energy of hot fragments

    International Nuclear Information System (INIS)

    Souliotis, G.A.; Shetty, D.V.; Keksis, A.; Bell, E.; Jandel, M.; Veselsky, M.; Yennello, S.J.

    2006-01-01

    The isoscaling properties of isotopically resolved projectile residues from peripheral collisions of 86 Kr (25 MeV/nucleon) 64 Ni (25 MeV/nucleon), and 136 Xe (20 MeV/nucleon) beams on various target pairs are employed to probe the symmetry energy coefficient of the nuclear binding energy. The present study focuses on heavy projectile fragments produced in peripheral and semiperipheral collisions near the onset of multifragment emission (E * /A=2-3 MeV). For these fragments, the measured average velocities are used to extract excitation energies. The excitation energies, in turn, are used to estimate the temperatures of the fragmenting quasiprojectiles in the framework the Fermi gas model. The isoscaling analysis of the fragment yields provided the isoscaling parameters α that, in combination with temperatures and isospin asymmetries provided the symmetry energy coefficient of the nuclear binding energy of the hot fragmenting quasiprojectiles. The extracted values of the symmetry energy coefficient at this excitation energy range (2-3 MeV/nucleon) are lower than the typical liquid-drop model value ∼25 MeV corresponding to ground-state nuclei and show a monotonic decrease with increasing excitation energy. This result is of importance in the formation of hot nuclei in heavy-ion reactions and in hot stellar environments such as supernova

  17. Hydrometallurgical recovery of heavy metals from low grade automobile shredder residue (ASR): An application of advanced Fenton process (AFP).

    Science.gov (United States)

    Singh, Jiwan; Lee, Byeong-Kyu

    2015-09-15

    To investigate the leaching and recovery of heavy metals from low-grade automobile shredder residue (ASR), the effects of nitric acid (HNO3) and hydrogen peroxide (H2O2) concentrations, liquid/solid (L/S) ratio, leaching temperature and ASR particle size fractions on the heavy metal leaching rate were determined. The heavy metals were recovered by fractional precipitation and advanced Fenton process (AFP) at different pHs. The toxicity characteristic leaching procedure (TCLP) test was also performed in the residue remaining after heavy metal leaching to evaluate the potential toxicity of ASR. The heavy metal leaching efficiency was increased with increasing HNO3 and H2O2 concentrations, L/S ratio and temperature. The heavy metal leaching efficiencies were maximized in the lowest ASR size fraction at 303 K and L/S ratio of 100 mL/g. The kinetic study showed that the metal leaching was best represented by a second-order reaction model, with a value of R(2) > 0.99 for all selected heavy metals. The determined activation energy (kJ/mol) was 21.61, 17.10, 12.15, 34.50, 13.07 and 11.45 for Zn, Fe, Ni, Pb, Cd and Cr, respectively. In the final residue, the concentrations of Cd, Cr and Pb were under their threshold limits in all ASR size fractions. Hydrometallurgical metal recovery was greatly increased by AFP up to 99.96% for Zn, 99.97% for Fe, 95.62% for Ni, 99.62% for Pb, 94.11% for Cd and 96.79% for Cr. AFP is highly recommended for the recovery of leached metals from solution even at low concentrations. Copyright © 2015 Elsevier Ltd. All rights reserved.

  18. Recycling of a fine, heavy fluff automobile shredder residue by density and differential fragmentation.

    Science.gov (United States)

    Gent, M R; Menéndez, M; Muñiz, H; Torno, S

    2015-09-01

    A compilation of the physical properties of materials which might typically occur in automobile shredder residue and an analysis of their suitability for the separation of materials in fine (<15mm) heavy fluff ASR (fhf-ASR) is presented. Differences in density and resistance to crushing of fhf-ASR materials were identified as potentially the most suitable low cost, technologically simple means for the separating this waste into its three principal components - metals, minerals (glass/stones) and organics (plastics). Results presented of laboratory scale tests demonstrate that fhf-ASR can in large part be separated into three principal components. Tests were conducted with 0.63-2.0mm and 2-10mm fractions. Recovery of plastics by density separations were conducted with water only jigs for the 2-10mm fraction and shaker tables for the 0.63-2mm fraction. Comparisons are presented of the separations of glass and stones from metals obtained by linear screening and vibratory screening of roller mill and impact mill crushing products of the high density 2-10mm fraction. Equipment used for these tests are of a laboratory or demonstrative scale. It is reasonable to anticipate that industrial scale processing would produce significantly better results. The 2-15mm fraction was found to constitute 91.6% of the fhf-ASR sampled. The metals content of the 2-10mm portion of this fraction was upgraded from 2.5% to 31% and 76.9% with recoveries varying inversely with grade from 91.9% to 40.1%. From 63.6% to 17.1% with a recovery of 93.5% of the organic materials. A residual product of fine sand of crushed glass/stones of 99.4% purity recovered 71.3% of these. Copyright © 2015 Elsevier Ltd. All rights reserved.

  19. Simulation of Weld Mechanical Behavior to Include Welding Induced Residual Stress and Distortion: Coupling of SYSWELD and Abaqus Codes

    Science.gov (United States)

    2015-11-01

    data .  scaleFactor: Scale factor to convert SYSWELD units to units in Abaqus analysis for field of interest. A help description can be obtained by...Memorandum Simulation of Weld Mechanical Behavior to Include Welding-Induced Residual Stress and Distortion: Coupling of SYSWELD and Abaqus Codes...Weld Mechanical Behavior to Include Welding-Induced Residual Stress and Distortion: Coupling of SYSWELD and Abaqus Codes by Charles R. Fisher

  20. Design of A District Heating System Including The Upgrading of Residual Industrial Waste Heat

    NARCIS (Netherlands)

    Falcao, P.W.; Mesbah, A.; Suherman, M.V.; Wennekes, S.

    2005-01-01

    This study was aimed to evaluate the feasibility of using a waste heat stream from DSM for a District Heating System. A conceptual design was carried out with emphasis on the unit for upgrading the residual waste heat. Having reviewed heat pump technology, mechanical heat pump was found to be the

  1. Economic values of production and functional traits, including residual feed intake, in Finnish milk production.

    Science.gov (United States)

    Hietala, P; Wolfová, M; Wolf, J; Kantanen, J; Juga, J

    2014-02-01

    Improving the feed efficiency of dairy cattle has a substantial effect on the economic efficiency and on the reduction of harmful environmental effects of dairy production through lower feeding costs and emissions from dairy farming. To assess the economic importance of feed efficiency in the breeding goal for dairy cattle, the economic values for the current breeding goal traits and the additional feed efficiency traits for Finnish Ayrshire cattle under production circumstances in 2011 were determined. The derivation of economic values was based on a bioeconomic model in which the profit of the production system was calculated, using the generated steady state herd structure. Considering beef production from dairy farms, 2 marketing strategies for surplus calves were investigated: (A) surplus calves were sold at a young age and (B) surplus calves were fattened on dairy farms. Both marketing strategies were unprofitable when subsidies were not included in the revenues. When subsidies were taken into account, a positive profitability was observed in both marketing strategies. The marginal economic values for residual feed intake (RFI) of breeding heifers and cows were -25.5 and -55.8 €/kg of dry matter per day per cow and year, respectively. The marginal economic value for RFI of animals in fattening was -29.5 €/kg of dry matter per day per cow and year. To compare the economic importance among traits, the standardized economic weight of each trait was calculated as the product of the marginal economic value and the genetic standard deviation; the standardized economic weight expressed as a percentage of the sum of all standardized economic weights was called relative economic weight. When not accounting for subsidies, the highest relative economic weight was found for 305-d milk yield (34% in strategy A and 29% in strategy B), which was followed by protein percentage (13% in strategy A and 11% in strategy B). The third most important traits were calving

  2. Simulation of Spread of African Swine Fever, Including the Effects of Residues from Dead Animals

    DEFF Research Database (Denmark)

    Hisham Beshara Halasa, Tariq; Boklund, Anette; Bøtner, Anette

    2016-01-01

    the subclinical stage and are fully infectious during the clinical stage. ASF virus (ASFV) infection through residues of dead animals in the slurries was also modeled in an exponentially fading-out pattern. Low and high transmission rates for ASFV were tested in the model. Robustness analysis was carried out......To study the spread of African swine fever (ASF) within a pig unit and the impact of unit size on ASF spread, a simulation model was created. In the model, an animal can be in one of the following stages: susceptible, latent, subclinical, clinical, or recovered. Animals can be infectious during...... in order to study the impact of uncertain parameters on model predictions. The results showed that the disease may fade out within the pig unit without a major outbreak. Furthermore, they showed that spread of ASFV is dependent on the infectiousness of subclinical animals and the residues of dead animals...

  3. A 1H NMR spectroscopic study on the tryptophan residues of lysozyme included by glucosyl-β-cyclodextrin

    Science.gov (United States)

    Yamamoto, Tatsuyuki; Kobayashi, Teruya; Yoshikiyo, Keisuke; Matsui, Yoshihisa; Takahashi, Tetsuya; Aso, Yuji

    2009-02-01

    A 1H NMR spectroscopic study showed that the side chains of Trp residues of chicken egg white lysozyme in an aqueous solution are included by Glucosyl-β-cyclodextrin (G1-β-CD). The 1H NMR signals due to Trp residues shifted with the addition of G1-β-CD. The addition of methyl α- D-glucopyranoside, which has no inclusion ability, gave different effect on the shift of 1H NMR signals. The 1H NMR signals due to Cys64 and Ile98 were also influenced to a considerable extent with the addition of G1-β-CD, suggesting that these hydrophobic amino acid residues are also included by the CD. The chemical shift values of 1H NMR signals, due to indole rings of tryptophan residues, changed more with the addition of G1-β-CD. The magnitudes of the chemical shift change were different depending on their locations in the protein. The chemical shift values of 1H NMR signals, due to those Trp residues in the active site of the lysozyme were smaller than those locating at relatively near the surface of the protein.

  4. Effects of rapeseed residue on lead and cadmium availability and uptake by rice plants in heavy metal contaminated paddy soil.

    Science.gov (United States)

    Ok, Yong Sik; Usman, Adel R A; Lee, Sang Soo; Abd El-Azeem, Samy A M; Choi, Bongsu; Hashimoto, Yohey; Yang, Jae E

    2011-10-01

    Rapeseed (Brassica napus L.) has been cultivated for biodiesel production worldwide. Winter rapeseed is commonly grown in the southern part of Korea under a rice-rapeseed double cropping system. In this study, a greenhouse pot experiment was conducted to assess the effects of rapeseed residue applied as a green manure alone or in combinations with mineral N fertilizer on Cd and Pb speciation in the contaminated paddy soil and their availability to rice plant (Oryza sativa L.). The changes in soil chemical and biological properties in response to the addition of rapeseed residue were also evaluated. Specifically, the following four treatments were evaluated: 100% mineral N fertilizer (N100) as a control, 70% mineral N fertilizer+rapeseed residue (N70+R), 30% mineral N fertilizer+rapeseed residue (N30+R) and rapeseed residue alone (R). The electrical conductivity and exchangeable cations of the rice paddy soil subjected to the R treatment or in combinations with mineral N fertilizer treatment, N70+R and N30+R, were higher than those in soils subjected to the N100 treatment. However, the soil pH value with the R treatment (pH 6.3) was lower than that with N100 treatment (pH 6.9). Use of rapeseed residue as a green manure led to an increase in soil organic matter (SOM) and enhanced the microbial populations in the soil. Sequential extraction also revealed that the addition of rapeseed residue decreased the easily accessible fraction of Cd by 5-14% and Pb by 30-39% through the transformation into less accessible fractions, thereby reducing metal availability to the rice plant. Overall, the incorporation of rapeseed residue into the metal contaminated rice paddy soils may sustain SOM, improve the soil chemical and biological properties, and decrease the heavy metal phytoavailability. Copyright © 2011 Elsevier Ltd. All rights reserved.

  5. Pesticide residues in grapes from integrated production of the Slovene origin The CORRECTED TITLE is: Pesticide residues in grapes from vineyards included in integrated pest management in Slovenia.

    OpenAIRE

    Baša Česnik , Helena; Gregorčič , Ana; Čuš , Franc

    2008-01-01

    Abstract Although the list of pesticides used in integrated pest management (IPM) in grape growing and their annual application rates are limited, we are still confronted with the problem of pesticide residues in grapes. The paper presents the results of pesticide monitoring in 47 samples of wine grapes (Vitis vinifera L.) of the 2006 vintage from the vineyards included in IPM. The grape samples were analysed for the presence of 67 pesticides. Among them, 20 were allowed in IPM in ...

  6. Evaluation of ground calcite/water heavy media cyclone suspensions for production of residual plastic concentrates.

    Science.gov (United States)

    Gent, Malcolm; Sierra, Héctor Muñiz; Menéndez, Mario; de Cos Juez, Francisco Javier

    2018-01-01

    Viable recycled residual plastic (RP) product(s) must be of sufficient quality to be reusable as a plastic or source of hydrocarbons or fuel. The varied composition and large volumes of such wastes usually requires a low cost, high through-put recycling method(s) to eliminate contaminants. Cyclone separation of plastics by density is proposed as a potential method of achieving separations of specific types of plastics. Three ground calcite separation medias of different grain size distributions were tested in a cylindrical cyclone to evaluate density separations at 1.09, 1.18 and 1.27 g/cm 3 . The differences in separation recoveries obtained with these medias by density offsets produced due to displacement of separation media solid particles within the cyclone caused by centrifugal settling is evaluated. The separation density at which 50% of the material of that density is recovered was found to increase from 0.010 to 0.026 g/cm 3 as the separation media density increased from 1.09 to 1.27 g/cm 3 . All separation medias were found to have significantly low Ep 95 values of 0.012-0.033 g/cm 3 . It is also demonstrated that the presence of an excess content of 75%) resulted in reduced separation efficiencies. It is shown that the optimum separations were achieved when the media density offset was 0.03-0.04 g/cm 3 . It is shown that effective heavy media cyclone separations of RP denser than 1.0 g/cm 3 can produce three sets of mixed plastics containing: PS and ABS/SAN at densities of >1.0-1.09 g/cm 3 ; PC, PMMA at a density of 1.09-1.18 g/cm 3 ; and PVC and PET at a density of >1.27 g/cm 3 . Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. Releasing characteristics and fate of heavy metals from phytoremediation crop residues during anaerobic digestion.

    Science.gov (United States)

    Lee, Jongkeun; Park, Ki Young; Cho, Jinwoo; Kim, Jae Young

    2018-01-01

    In this study, lab-scale batch tests were conducted to investigate releasing characteristics of heavy metals according to degradation of heavy metal containing biomass. The fate of heavy metals after released from biomass was also determined through adsorption tests and Visual MINTEQ simulation. According to the anaerobic batch test results as well as volatile solids and carbon balance analyses, maximum of 60% by wt. of biomass was degraded. During the anaerobic biodegradation, among Cd, Cu, Ni, Pb, and Zn, only Cu and Zn were observed in soluble form (approximately 40% by wt. of input mass). The discrepancy between degradation ratio of biomass and ratio of released heavy metals mass from biomass was observed. It seems that this discordance was caused by the fate (i.e., precipitated with sulfur/hydroxide or adsorbed onto sorbents) of each heavy metal types in solution after being released from biomass. Thus, releasing characteristics and fate of heavy metal should be considered carefully to predict stability of anaerobic digestion process for heavy metal-containing biomass. Copyright © 2017 Elsevier Ltd. All rights reserved.

  8. Application of multivariate heavy-tailed distributions to residuals in the estimation of genetic parameters of growth traits in beef cattle.

    Science.gov (United States)

    Peters, S O; Kizilkaya, K; Garrick, D J; Fernando, R L; Pollak, E J; De Donato, M; Hussain, T; Imumorin, I G

    2013-04-01

    Assumptions of normality in most animal breeding applications may make inferences vulnerable to the presence of outliers. Heavy-tail densities are viable alternatives to normal distributions and provide robustness against unusual or outlying observations when used to model the densities of residual effects. Our objective is to compare estimates of genetic parameters by fitting multivariate normal (MN) or heavy-tail distributions [multivariate Student's t (MSt) and multivariate slash (MS)] for residuals in data of body birth weight (BBW), weaning (WW), and yearling (YW) weight traits in beef cattle. A total of 17,019 weight records for BBW, WW, and YW from 1998 through 2010 from a large commercial cow/calf operation in the sand hills of Nebraska were analyzed. Models included fixed effects of contemporary group and sire breed whereas animal and maternal effects were random and the degrees of freedom (v) was treated as unknown for MSt and MS. Model comparisons using deviance information criteria (DIC) favored MSt over MS and MN models, respectively. The posterior means [and 95% posterior probability intervals (PPI)] of v for the MSt and MS models were 5.28 (4.80, 5.85) and 1.88 (1.76, 2.00), respectively. Smaller values of posterior densities of v for MSt and MS models confirm that the assumption of normally distributed residuals is not adequate for the analysis of BBW, WW, and YW datasets. Posterior mean (PM) and posterior median (PD) estimates of direct and maternal genetic variances were the same and posterior densities of these parameters were found to be symmetric. The 95% PPI estimates from MN and MSt models for BBW did not overlap, which indicates significant difference between PM estimates from MN or MSt models. The observed antagonistic relationship between additive direct and additive maternal effects indicated that genetic evaluation and selection strategies will be sensitive to the assumed model for residuals.

  9. Effects of thermal treatment on mineralogy and heavy metal behavior in iron oxide stabilized air pollution control residues

    DEFF Research Database (Denmark)

    Sørensen, Mette Abildgaard; Bender-Koch, C.; Starckpoole, M. M.

    2000-01-01

    Stabilization of air pollution control residues by coprecipitation with ferrous iron and subsequent thermal treatment (at 600 and 900 °C) has been examined as a means to reduce heavy metal leaching and to improve product stability. Changes in mineralogy and metal binding were analyzed using various...... volatilized or destabilized with respect to leaching. Pb, in particular, exhibited increased reactivity following the formation of an ordered iron oxide structure at 900 °C. The thermal treatment had a positive effect on Cr release, which was reduced significantly at 900 °C in the presence of organic matter...

  10. Thermal and catalytic ASVAHL processes under hydrogen pressure for converting heavy crudes and conventional residues

    Energy Technology Data Exchange (ETDEWEB)

    Peries, J.P.; Quignard, A.; Farjon, C.; Laborde, M.

    This article describes the comparative performances of thermal ASVAHL processes (TERVAHL T, TERVAHL H, TERVAHL HC) and catalytic ASVAHL processes (HYVAHL F, HYVAHL C) for two types of processing: (1) degasolined Boscan crude (basis of studies for transportation feasibility), and (2) Safaniya vacuum residue (basis of studies for residue refining). The results reveal the importance of the amount of fixed hydrogen, which affects the conversion obtained and the quality of the residues. The introduction of a TERVAHL HC soluble catalyst or one in catalytic suspension (catalytic hydrovisbreaking) or the use of a supported catalyst (HYVAHL hydrotreatment) enhances the activation of hydrogen. The combination of cracking, polycondensation and hydrogen reactions together with the operating conditions (temperatures, residence time and pressure) are what will define the conversion limits for a given stability of residues.

  11. Human major histocompatibility complex class I antigens: residues 61-83 of the HLA-B7 heavy chain specify an alloreactive site.

    OpenAIRE

    Walker, L E; Ketler, T A; Houghten, R A; Schulz, G; Chersi, A; Reisfeld, R A

    1985-01-01

    A chemically synthesized peptide (sequence in text) homologous to residues 61-83 of the HLA-B7 heavy chain, induced antibodies that specifically recognized the HLA heavy chain-beta 2-microglobulin complex and the free heavy chain of the HLA-B7 antigen. These antibodies specifically immunoprecipitated the HLA-B7 beta 2-microglobulin complex solubilized from human lymphoblastoid cells by nonionic detergents and reacted with free HLA-B7 heavy chains in blots on nitrocellulose. These observations...

  12. Dual mechanochemical immobilization of heavy metals and decomposition of halogenated compounds in automobile shredder residue using a nano-sized metallic calcium reagent.

    Science.gov (United States)

    Mallampati, Srinivasa Reddy; Lee, Byoung Ho; Mitoma, Yoshiharu; Simion, Cristian

    2016-11-01

    Simultaneous immobilization of heavy metals and decomposition of halogenated organic compounds in different fractions of automobile shredder residue (ASR) were achieved with a nano-sized metallic calcium through a 60-min ball milling treatment. Heavy metal (HM) immobilization and chlorinated/brominated compound (CBC) decomposition efficiencies both reached 90-100 %, after ball milling with nanometallic calcium/calcium oxide (Ca/CaO) dispersion, regardless of ASR particle size (1.0, 0.45-1.0, and 0.250 mm). Concentrations of leachable HMs substantially decreased to a level lower than the regulatory standard limits (Co and Cd 0.3 mg L -1 ; Cr 1.5 mg L -1 ; Fe, Pb, and Zn 3.0 mg L -1 ; Mn and Ni 1 mg L -1 ) proposed by the Korean hazardous waste elution standard regulatory threshold. Scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS) element maps/spectra showed that while the amounts of HMs and CBCs detectable in ASR significantly decreased, the calcium mass percentage increased. X-ray powder diffraction (XRD) patterns indicate that the main fraction of enclosed/bound materials on ASR includes Ca-associated crystalline complexes that remarkably inhibit HM desorption and simultaneously transform dangerous CBCs into harmless compounds. The use of a nanometallic Ca/CaO mixture in a mechanochemical process to treat hazardous ASR (dry conditions) is an innovative approach to remediate cross-contaminated residues with heavy metals and halogenated compounds.

  13. Evaluation of Spatial Resolution for Heavy Ion CT System Based on the Measurement of Residual Range Distribution With HIMAC

    Science.gov (United States)

    Muraishi, H.; Nishimura, K.; Abe, S.; Satoh, H.; Hara, S.; Hara, H.; Takahashi, Y.; Mogaki, T.; Kawai, R.; Yokoyama, K.; Yasuda, N.; Tomida, T.; Ohno, Y.; Kanai, T.

    2009-10-01

    We report experimental results from a heavy ion CT system based on the measurement of residual range distribution using an X-ray intensifying screen and a charged coupled device (CCD) camera system. This technique was first investigated by Zygmanski (2000) for proton beams, and they reported that the spatial resolution was significantly degraded by multiple Coulomb scattering (MCS) effects in the irradiated medium. Experiments were done on the spatial resolution phantom by using helium and carbon beams accelerated up to 120 MeV/u and 230 MeV/u by the Heavy Ion Medical Accelerator in Chiba (HIMAC), installed in the National Institute of Radiological Sciences (NIRS) in Japan, using a high performance intensified CCD (ICCD) camera. We show that the MCS blurring effect can be significantly reduced in the reconstructed image by using a carbon beam with this technique. Our results suggest that heavier particles such as carbon would be more useful if this technique is envisioned as a clinical tool to obtain data that would aid proton and/or heavy ion treatment planning.

  14. Heavy metal (lead, Cadmium) and antibiotic (Tetracycline and Chloramphenicol) residues in fresh and frozen fish types (Clarias gariepinus, Oreochromis niloticus) in Ibadan, Oyo State, Nigeria.

    Science.gov (United States)

    Olusola, Adetunji Victoria; Folashade, Popoola Amirah; Ayoade, Odetokun Ismail

    2012-09-15

    This study was carried out to assess the level of heavy metals (lead (Pb) and cadmium (Cd)) and antibiotics (tetracycline and chloramphenicol) residues in frozen and fresh fish types obtained from Eleyele river, Officer's mess, Alfa farm and a major frozen meat outlet in Ibadan, Oyo State Nigeria. The Atomic Absorption Spectrophotometer (AAS) and High Performance Liquid Chromatography (HPLC) were used to analyze the heavy metals and antibiotics residue levels in fresh and frozen fish, respectively. The results showed mean concentrations of antibiotics was higher (pmetal residue. The differences of mean residue levels in both antibiotics and heavy metals tested in the cranial and caudal parts of the fish samples were not significant (pmetals and tetraxycline residues were observed in Alfa's farm (Pb: 0.039+/-0.004 ppm; Cd: 0.020+/-0.006 ppm; tetraxycline: 2.185+/-0.412). Chloramphenicol was highest in Officers mess (0.837+/-0.165 ppm). The heavy metals (Pb and Cd) concentrations determined were below the maximum permissible limits set by both local and international safety agencies. Tetraxcycline exceeded international limits of 0.2 ppm while Chloramphenicol which has a zero tolerance level was also detected from all sources. This study accentuates the need for control of heavy metals and antibiotics in fish sold for human consumption in Ibadan, Nigeria. The need to ban chloramphenicol in treatment of fish and other animals is emphasised.

  15. Assessment of heavy metal residues in water, fish tissue and human ...

    African Journals Online (AJOL)

    MICHAEL HORSFALL

    ABSTRACT: Residual levels of lead, chromium, cadmium and zinc in water and fish tissue from. Ubeji River, Warri and blood samples from residents of Ubeji were analysed. Control water and fish samples were obtained from Eleyele River and blood from residents of Ibadan. All the samples collected were digested using a ...

  16. Gender differences in residual effect of prior drop jumps on oxygen uptake during heavy cycling exercise

    Directory of Open Access Journals (Sweden)

    Neringa Baranauskienė

    2017-12-01

    Conclusions: Prior eccentric–concentric exercise of thigh muscles (100 drop jumps accelerates VO2 kinetics at the start and increases VO2 during steady state of heavy cycling only in the male group. So, prior exercise of such type has a higher negative impact on cycling economy in men than in women and this might be related to greater muscle damage and fatigue in physically active male persons after plyometric exercise.

  17. Human major histocompatibility complex class I antigens: residues 61-83 of the HLA-B7 heavy chain specify an alloreactive site.

    Science.gov (United States)

    Walker, L E; Ketler, T A; Houghten, R A; Schulz, G; Chersi, A; Reisfeld, R A

    1985-01-01

    A chemically synthesized peptide (sequence in text) homologous to residues 61-83 of the HLA-B7 heavy chain, induced antibodies that specifically recognized the HLA heavy chain-beta 2-microglobulin complex and the free heavy chain of the HLA-B7 antigen. These antibodies specifically immunoprecipitated the HLA-B7 beta 2-microglobulin complex solubilized from human lymphoblastoid cells by nonionic detergents and reacted with free HLA-B7 heavy chains in blots on nitrocellulose. These observations suggest that the antigenic conformation of this region of the HLA-B7 molecule is independent of the presence of beta 2-microglobulin and that amino acid residues 61-83 mimic an alloreactive site expressed by the HLA-B7 antigen.

  18. Maximum conversion of heavy hydrocarbons. Product stability dictates thermal and catalytic conversion rates of residues

    Energy Technology Data Exchange (ETDEWEB)

    Hennico, A.; Peries, J.P. (Institut Francais du Petrole, 92 - Rueil Malmaison (France)); Laurent, J.; Espeillac, M.

    1992-01-01

    The maximum conversion achieved by thermal cracking is limited by the fuel stability. The same holds for catalytic hydrotreating. ASVAHL has studied for many years the relation between conversion and product stability in thermal and catalytic processes. Thermal Mode: Several solutions are proposed to increase the conversion of the TERVAHL T visbreaking process such as the use of hydrogen (TERVAHL H) and possibly the addition of a few ppm of a dispersed catalyst (TERVAHL C). Catalytic Mode: The conversion of the HYVAHL residue hydrotreating process may be increased either by adding a hydrovisbreaking furnace before the hydrotreating step (HYVAHL T) or by adding an existing visbreaking downstream the hydrotreating step. These various routes enable the ASVAHL processes to maximize the marketable light product quantities in function of the residue to be upgraded and the fuel qualities to be assured. (orig.).

  19. Production of petroleum bitumen by oxidation of heavy oil residue with sulfur

    Science.gov (United States)

    Tileuberdi, Ye.; Akkazyn, Ye. A.; Ongarbayev, Ye. K.; Imanbayev, Ye. I.; Mansurov, Z. A.

    2018-03-01

    In this paper production of bitumen adding elemental sulfur at oxidation of oil residue are investigated. The objects of research were distilled residue of Karazhanbas crude oil and elemental sulfur. These oil residue characterized by a low output of easy fractions and the high content of tar-asphaltene substances, therefore is the most comprehensible feedstock for producing bitumen. The sulfur is one of the oil product collected in oil extraction regions. Oxidation process of hydrocarbons carried out at temperatures from 180 up to 210 °С without addition of sulfur and with the addition of sulfur (5-10 wt. %) for 4 hours. At 200 °С oxidation of hydrocarbons with 5, 7 and 10 wt.% sulfur within 3-4 h allows receiving paving bitumen on the mark BND 200/300, BND 130/200, BN 90/130 and BN 70/30. Physical and mechanical characteristics of oxidation products with the addition of 5-7 wt. % sulfur corresponds to grade of paving bitumen BND 40/60. At the given temperature oxidized for 2.5-3 h, addition of 10 wt. % sulfur gave the products of oxidation describing on parameters of construction grades of bitumen (BN 90/10).

  20. Evaluation of remediation techniques in soils affected by residual contamination with heavy metals and arsenic.

    Science.gov (United States)

    García-Carmona, M; Romero-Freire, A; Sierra Aragón, M; Martínez Garzón, F J; Martín Peinado, F J

    2017-04-15

    Residual soil pollution from the Aznalcóllar mine spill is still a problem in some parts of the affected area, today converted in the Guadiamar Green Corridor. Dispersed spots of polluted soils, identified by the absence of vegetation, are characterized by soil acid pH and high concentrations of As, Pb, Cu and Zn. Ex situ remediation techniques were performed with unrecovered soil samples. Landfarming, Composting and Biopiles techniques were tested in order to immobilize pollutants, to improve soil properties and to promote vegetation recovery. The effectiveness of these techniques was assessed by toxicity bioassays: Lactuca sativa L. root elongation test, Vibrio fischeri bioluminescence reduction test, soil induced respiration test, and Eisenia andrei survival and metal bioaccumulation tests. Landfarming and Composting were not effective techniques, mainly due to the poor improvement of soil properties which maintained high soluble concentrations of Zn and Cu after treatments. Biopile technique, using adjacent recovered soils in the area, was the most effective action in the reduction of soil toxicity; the improvement of soil properties and the reduction in pollutants solubility were key to improve the response of the tested organisms. Therefore, the mixture of recovered soils with polluted soils in the areas affected by residual contamination is considered a more suitable technique to reduce the residual pollution and to promote the complete soil recovery in the Guadiamar Green Corridor. Copyright © 2016 Elsevier Ltd. All rights reserved.

  1. Stress and Fatigue Life Modeling of Cannon Breech Closures Including Effects of Material Strength and Residual Stress

    National Research Council Canada - National Science Library

    Underwood, John

    2000-01-01

    ...; overload residual stress. Modeling of applied and residual stresses at the location of the fatigue failure site is performed by elastic-plastic finite element analysis using ABAQUS and by solid...

  2. The long term release of heavy metals from combustion residues and slags

    Energy Technology Data Exchange (ETDEWEB)

    Crawford, J.N.

    1996-12-31

    This treatise details methodology which may be used to construct a model of the geochemical evolution in a waste repository and the changes in leachate composition over time. The pH and Eh of the leachant, as well as major complexing anions control the leaching of heavy metals over very long times due to solubility constraints. The pH and the Eh of the leachate changes when the buffering capacity of the waste has been exhausted. It is possible that the altered pH and Eh conditions in the leachate at later times may allow leaching of heavy metals at considerably higher concentrations than those present earlier during the leaching process. The model developed requires data which may be obtained from simple laboratory experiments in order to describe the reactive properties of the waste. Because of the complexity of the real system, the model uses `generalised` minerals which react with the inflowing oxygen and acidity to buffer the pH and Eh of the leachant. In this way, the chemistry of the leachant may be modelled without the need for a detailed geochemical description of the waste material. The model is intended to be simple and flexible enough that it may be adapted to different waste types with reasonable ease. The results obtained indicate that the redox and the pH-buffering characteristics of the waste are very important in determining the leaching of trace metals. The results also illustrate the strong influence that diffusional transport of CO{sub 2} and O{sub 2} may have upon the long term leaching behaviour. The model predictions have not, as yet, been reconciled with field leachate measurements. This will form a major part of the continued work with this project 38 refs, 63 figs, 11 tabs

  3. Electrodialytic removal of heavy metals and chloride from municipal solid waste incineration fly ash and air pollution control residue in suspension - test of a new two compartment experimental cell

    DEFF Research Database (Denmark)

    Kirkelund, Gunvor Marie; Magro, Cátia; Guedes, Paula

    2015-01-01

    Municipal solid waste incineration (MSWI) residues such as fly ash and air pollution control (APC) residues are classified as hazardous waste and disposed of, although they contain potential resources. The most problematic elements in MSWI residues are leachable heavy metals and salts. For reuse...... of MSWI residues in for instance concrete, the aim of remediation should be reduction of the heavy metal leaching, while at the same time keeping the alkaline pH, so the residue can replace cement. In this study a MSWI residues were subjected to electrodialytic remediation under various experimental...

  4. Analysis and characterization of heavy residues produced in 129Xe + natSn reactions between 8 and 25 AMeV

    International Nuclear Information System (INIS)

    Moisan, J.

    2008-06-01

    Studies with the INDRA multidetector of the 129 Xe + nat Sn reactions showed the unexpected existence of heavy fragments with a charge as large as Z=70. The charges of Xe and Sn are 54 and 50 respectively. Reactions between nuclei with a charge product greater than 2700 are dominated by deep inelastic collisions. For Xe + Sn the product is exactly 2700. After these observations, 129 Xe + nat Sn reactions at 8, 12, 15, 20 and 25 AMeV have been done. It will then be possible to clarify if the heavy residues are formed by an incomplete fusion, massive transfers occurring in deep inelastic collisions or a very asymmetric fission of a compound system. This work will present experimental results obtained by the analysis of these experiments. We will show that heavy residues are formed with a production cross-section of 10 -2 mb. Angular distributions show that the residues can be produced by an incomplete fusion of the projectile and the target. The study of the products in coincidence with the residues shows that a compound system was formed, followed by a fission producing the residue and a lighter fragment. The comparison with a phenomenological model, HIPSE, confirms that the model is valid at these energies

  5. Heavy metal leaching from aerobic and anaerobic landfill bioreactors of co-disposed municipal solid waste incineration bottom ash and shredded low-organic residues.

    Science.gov (United States)

    Inanc, Bulent; Inoue, Yuzo; Yamada, Masato; Ono, Yusaku; Nagamori, Masanao

    2007-03-22

    In this study, heavy metal leaching from aerobic and anaerobic landfill bioreactor test cells for co-disposed municipal solid waste incineration (MSWI) bottom ash and shredded low-organic residues has been investigated. Test cells were operated for 1 year. Heavy metals which were comparatively higher in leachate of aerobic cell were copper (Cu), lead (Pb), boron (B), zinc (Zn), manganese (Mn) and iron (Fe), and those apparently lower were aluminum (Al), arsenic (As), molybdenum (Mo), and vanadium (V). However, no significant release of heavy metals under aerobic conditions was observed compared to anaerobic and control cells. Furthermore, there was no meaningful correlation between oxidation-reduction potential (ORP) and heavy metal concentrations in the leachates although some researchers speculate that aeration may result in excessive heavy metal leaching. No meaningful correlation between dissolved organic carbon (DOC) and leaching of Cu and Pb was another interesting observation. The only heavy metal that exceeded the state discharge limits (10mg/l, to be enforced after April 2005) in the aerobic cell leachate samples was boron and there was no correlation between boron leaching and ORP. Higher B levels in aerobic cell should be due to comparatively lower pH values in this cell. However, it is anticipated that this slightly increased concentrations of B (maximum 25mg/l) will not create a risk for bioreactor operation; rather it should be beneficial for long-term stability of the landfill through faster washout. It was concluded that aerobization of landfills of heavy metal rich MSWI bottom ash and shredded residues is possible with no dramatic increase in heavy metals in the leachate.

  6. Landfilling of waste incineration residues

    DEFF Research Database (Denmark)

    Christensen, Thomas Højlund; Astrup, Thomas; Cai, Zuansi

    2002-01-01

    Residues from waste incineration are bottom ashes and air-pollution-control (APC) residues including fly ashes. The leaching of heavy metals and salts from the ashes is substantial and a wide spectrum of leaching tests and corresponding criteria have been introduced to regulate the landfilling...

  7. Quantitative analysis and reduction of the eco-toxicity risk of heavy metals for the fine fraction of automobile shredder residue (ASR) using H2O2.

    Science.gov (United States)

    Singh, Jiwan; Yang, Jae-Kyu; Chang, Yoon-Young

    2016-02-01

    Automobile shredder residue (ASR) fraction (size <0.25mm) can be considered as hazardous due to presence of high concentrations of heavy metals. Hydrogen peroxide combined with nitric acid has been used for the recovery of heavy metals (Zn, Cu, Mn, Fe, Ni, Pb, Cd and Cr) from the fine fraction of ASR. A sequential extraction procedure has also been used to determine the heavy metal speciation in the fine fraction of ASR before and after treatment. A risk analysis of the fine fraction of ASR before and after treatment was conducted to assess the bioavailability and eco-toxicity of heavy metals. These results showed that the recovery of heavy metals from ASR increased with an increase in the hydrogen peroxide concentration. A high concentration of heavy metals was found to be present in Cbio fractions (the sum of the exchangeable and carbonate fractions) in the fine fraction of ASR, indicating high toxicity risk. The Cbio rate of all selected heavy metals was found to range from 8.6% to 33.4% of the total metal content in the fine fraction of ASR. After treatment, Cbio was reduced to 0.3-3.3% of total metal upon a treatment with 2.0% hydrogen peroxide. On the basis of the risk assessment code (RAC), the environmental risk values for heavy metals in the fine fraction of ASR reflect high risk/medium risk. However, after treatment, the heavy metals would be categorized as low risk/no risk. The present study concludes that hydrogen peroxide combined with nitric acid is a promising treatment for the recovery and reduction of the eco-toxicity risk of heavy metals in ASR. Copyright © 2015 Elsevier Ltd. All rights reserved.

  8. Comparison of NAA XRF and ICP-OES Methods on Analysis of Heavy Metals in Coals and Combustion Residues

    Directory of Open Access Journals (Sweden)

    Agus Taftazani

    2017-07-01

    Full Text Available Heavy metals in the samples of coals and combustion residues (bottom ash and fly ash from Pacitan coal-fired power plant (CPP have been identified by using NAA, XRF, and ICP-OES methods. This research was aimed to understand the analysis results correlation coefficient (R and determine the enrichment ratio (ER value of the samples by using three analysis methods. The results showed 10 elements have been simultaneously detected in all samples. The correlation coefficient of analysis results of metals content in coals by using NAA-XRF, XRF-ICP OES and with ICPOES-NAA methods gives R2£1 respectively. The correlation coefficient of analysis results of metals content in bottom ash and fly ash by using the methods of NAA-XRF, XRF-ICPOES, and ICPOES-NAA gained R2»1 respectively. ICP-OES method was most satisfactory in this study. The value of ER for identified metals by using the three methods in the samples of bottom ash and fly ash yielded the value over one, and ER value of fly ash was greater in comparison to the bottom ash.

  9. Quantification of heavy metals from residual waste and ashes from the treatment plant of residual water Reciclagua and,effects for the health of those workers which manipulate those residuals

    International Nuclear Information System (INIS)

    Guerrero D, J.J.

    2004-01-01

    concentrations greater than 0.5% in weight, as long as the analysis of plasma emission spectroscopy very low concentrations are identified already that this method causes the destruction of the sample achieving the identification of all the present elements. With the obtained results we are able to compare the concentrations of the metals before and after the leaching and we calculate by this way the percentage of efficiency for each one of the variables that were managed in the development of the study, obtaining the extraction of those toxic, and valuable metals, present in the muds until of 100%. Based on the results we can mention that the workers are exposed to aerosols and powders of these toxic residuals which contain heavy metals. (Author)

  10. UN-ECE task force. Management on by-products/residues containing heavy metals and/or persistent organic pollutants. Status Report

    International Nuclear Information System (INIS)

    Hackl, A.E.; Sammer, G.; Winter, B.

    2001-01-01

    At its sixth session in July 1998, the United Nations Economic Commission for Europe (UN ECE) working group on abatement techniques recommended the establishment of a task force on the management of by-products and residues containing heavy metals and persistent organic pollutants (POPs). The aim of the task force was to support the parties, via the working group on abatement techniques, to comply with the requirements of the Aarhus protocols on heavy metals and POPs, and particularly those concerning the use and management of wastes containing these pollutants from different industrial sectors, including waste incineration. The task force built an earlier work conducted by the first task force an by-products utilization and waste management from fuel treatment and combustion (1986-91) and the second task force on by-product utilization from stationary installations (1991-96), and their respective status reports. Austria agreed to chair the task force, which held four meetings (Salzburg, Brussels, Ottawa and Zagreb) and one editorial conference (Frascati/Rome). Beside the lead country Belgium, Canada, Croatia, the Czech Republic, Denmark, Hungary, Italy, the Slovak Republic, Slovenia and the UN/ECE secretary were members of the task force. The work of the task force was also supported by EURELECTRIC, who hosted the meeting in Brussels and EUROCHLOR, who supported the writing of the Chlor-Alkali Chapter. The task force addressed the management of by-products and residues from the following industrial sectors: waste incineration; co-incineration; thermal electric power production; small-scale firing energy production; iron and steel production; aluminum production; copper, lead and zinc production; pulp and paper production; oil refineries; and chlor-alkali electrolysis. Information on these sectors was collected and reviewed. A questionnaire for most of the sectors was prepared and distributed to member states, requesting information an the management of the by

  11. Bioenergy from crops and biomass residues: a consequential life-cycle assessment including land-use changes

    DEFF Research Database (Denmark)

    Tonini, Davide; Astrup, Thomas Fruergaard

    demonstrated that algae represent an interesting alternative to terrestrial energy crops. This study provides GHG emission factors for a wide number of bioenergy scenarios. The aim is to inform decision/policy makers on the environmental consequences of producing biofuels from different sources...... generation biofuels produced from residual biomass promise important environmental savings. However, since these residues are today in-use for specific purposes (e.g., feeding), a detailed modelling of the consequences (e.g., on the feed-market) induced by their diversion to energy should be performed...... at identifying all the consequences associated with the establishment of bioenergy systems compared with the reference (current use of fossil and biomass resource). The modelling was facilitated with the LCA-model EASETECH. The functional unit was 1 unit-energy produced (i.e., 1 kWh electricity, 1 MJ heat or 1...

  12. Zoning of heavy metal concentrations including Cd, Pb and As in agricultural soils of Aghili plain, Khuzestan province, Iran

    Directory of Open Access Journals (Sweden)

    Mehdi Ahmadi

    2017-10-01

    Furthermore, based on the PLI, all stations were categorized as moderately to highly polluted sites (1heavy metal for human health, furture monitoring, some control measures and remedial actions should be undertaken in the study area.

  13. Persistent free radicals, heavy metals and PAHs generated in particulate soot emissions and residue ash from controlled combustion of common types of plastic

    International Nuclear Information System (INIS)

    Valavanidis, Athanasios; Iliopoulos, Nikiforos; Gotsis, George; Fiotakis, Konstantinos

    2008-01-01

    The production and use of polymeric materials worldwide has reached levels of 150 million tonnes per year, and the majority of plastic materials are discarded in waste landfills where are burned generating toxic emissions. In the present study we conducted laboratory experiments for batch combustion/burning of commercial polymeric materials, simulating conditions of open fire combustion, with the purpose to analyze their emissions for chemical characteristics of toxicological importance. We used common types of plastic materials: poly(vinyl chloride) (PVC), low and high density poly(ethylene) (LDPE, HDPE), poly(styrene) (PS), poly(propylene) (PP) and poly(ethylene terephthalate) (PET). Samples of particulate smoke (soot) collected on filters and residue solid ash produced by controlled burning conditions at 600-750 deg. C are used for analysis. Emissions of particulate matter, persistent free radicals embedded in the carbonaceous polymeric matrix, heavy metals, other elements and PAHs were determined in both types of samples. Results showed that all plastics burned easily generating charred residue solid ash and black airborne particulate smoke. Persistent carbon- and oxygen-centered radicals, known for their toxic effects in inhalable airborne particles, were detected in both particulate smoke emissions and residue solid ash. Concentrations of heavy metals and other elements (determined by Inductively Coupled Plasma Emission Spectrometry, ICP, method) were measured in the airborne soot and residue ash. Toxic heavy metals, such as Pb, Zn, Cr, Ni, and Cd were relatively at were found at low concentrations. High concentrations were found for some lithophilic elements, such as Na, Ca, Mg, Si and Al in particulate soot and residue solid ash. Measurements of PAHs showed that low molecular weight PAHs were at higher concentrations in the airborne particulate soot than in the residue solid ash for all types of plastic. Higher-ringed PAHs were detected at higher

  14. Persistent free radicals, heavy metals and PAHs generated in particulate soot emissions and residue ash from controlled combustion of common types of plastic.

    Science.gov (United States)

    Valavanidis, Athanasios; Iliopoulos, Nikiforos; Gotsis, George; Fiotakis, Konstantinos

    2008-08-15

    The production and use of polymeric materials worldwide has reached levels of 150 million tonnes per year, and the majority of plastic materials are discarded in waste landfills where are burned generating toxic emissions. In the present study we conducted laboratory experiments for batch combustion/burning of commercial polymeric materials, simulating conditions of open fire combustion, with the purpose to analyze their emissions for chemical characteristics of toxicological importance. We used common types of plastic materials: poly(vinyl chloride) (PVC), low and high density poly(ethylene) (LDPE, HDPE), poly(styrene) (PS), poly(propylene) (PP) and poly(ethylene terephthalate) (PET). Samples of particulate smoke (soot) collected on filters and residue solid ash produced by controlled burning conditions at 600-750 degrees C are used for analysis. Emissions of particulate matter, persistent free radicals embedded in the carbonaceous polymeric matrix, heavy metals, other elements and PAHs were determined in both types of samples. Results showed that all plastics burned easily generating charred residue solid ash and black airborne particulate smoke. Persistent carbon- and oxygen-centered radicals, known for their toxic effects in inhalable airborne particles, were detected in both particulate smoke emissions and residue solid ash. Concentrations of heavy metals and other elements (determined by Inductively Coupled Plasma Emission Spectrometry, ICP, method) were measured in the airborne soot and residue ash. Toxic heavy metals, such as Pb, Zn, Cr, Ni, and Cd were relatively at were found at low concentrations. High concentrations were found for some lithophilic elements, such as Na, Ca, Mg, Si and Al in particulate soot and residue solid ash. Measurements of PAHs showed that low molecular weight PAHs were at higher concentrations in the airborne particulate soot than in the residue solid ash for all types of plastic. Higher-ringed PAHs were detected at higher

  15. Ecological and health risks assessment and spatial distribution of residual heavy metals in the soil of an e-waste circular economy park in Tianjin, China.

    Science.gov (United States)

    Han, Wei; Gao, Guanghai; Geng, Jinyao; Li, Yao; Wang, Yingying

    2018-04-01

    Ziya Circular Economy Park is the biggest e-waste recycle park in North China before 2011, its function was then transformed in response to regulations and rules. In this paper, investigation was conducted to research the residual concentrations of 14 analytes (12 heavy metals and 2 non-metals) in the surface soil of Ziya Circular Economy Park and surrounding area. Both ecological and health assessments were evaluated using GI (geo-accumulation index) and NPI (Nemerow pollution index), and associated health risk was assessed by using USEPA model. According to the ecological risk assessment, Cu, Sb, Cd, Zn and Co were seriously enriched in the soil of the studied area. The health risk assessment proposed by USEPA indicated no significant health risks to the population. Soil properties, such as pH and organic matter, were found to correlate with the enrichment of heavy metals. Arsenic concentrations in the soil were found positively correlated to dead bacteria concentrations. Spatial distribution of heavy metals revealed that Ziya Circular Economy Park was the dominant pollution source in the studied area. Findings in this study suggest that enough attention should be payed to the heavy metal pollution in Ziya Circular Economy Park. Copyright © 2018 Elsevier Ltd. All rights reserved.

  16. Use of filler limestone and construction and demolition residues for remediating soils contaminated with heavy metals: an assessment by means of plant uptake.

    Science.gov (United States)

    Banegas, Ascension; Martinez-Sanchez, Maria Jose; Agudo, Ines; Perez-Sirvent, Carmen

    2010-05-01

    A greenhouse trial was carried out to evaluate the assimilation of heavy metals by three types of horticultural plants (lettuce, broccoli and alfalfa), different parts of which are destined for human and animal consumption (leaves, roots, fruits). The plants were cultivated in four types of soil, one uncontaminated (T1), one soil collected in the surrounding area of Sierra Minera (T2), the third being remediated with residues coming from demolition and construction activities (T3) and the four remediated with filler limestone (T4). To determine the metal content, soil samples were first ground to a fine powder using an agate ball mill. Fresh vegetable samples were separated into root and aboveground biomass and then lyophilized. The DTPA-extractable content was also determined to calculate the bioavailable amount of metal. Finally, the translocation factor (TF) and bioconcentration factor (BCF) were calculated. Arsenic levels were obtained by using atomic fluorescence spectrometry with an automated continuous flow hydride generation (HG-AFS) spectrometer and Cd, Pb and Zn was determined by electrothermal atomization atomic absorption spectrometry (ETAAS) or flame atomic absorption spectrometry (FAAS). Samples of the leached water were also obtained and analyzed. According to our results, the retention of the studied elements varies with the type of plant and is strongly decreased by the incorporation of filler limestone and/or construction and demolition residues to the soils. This practice represents a suitable way to reduce the risk posed to the biota by the presence of high levels of heavy metal in soil.

  17. Ab initio effective core potentials including relativistic effects and their application to the electronic structure calculations of heavy atoms and molecules

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Y.S.

    1977-11-01

    The effects of the 4f shell of electrons and the relativity of valence electrons are compared. The effect of 4f shell (lanthanide contraction) is estimated from the numerical Hartree-Fock (HF) calculations of pseudo-atoms corresponding to Hf, Re, Au, Hg, Tl, Pb and Bi without 4f electrons and with atomic numbers reduced by 14. The relativistic effect estimated from the numerical Dirac-Hartree-Fock (DHF) calculations of those atoms is comparable in the magnitude with that of the 4f shell of electrons. Both are larger for 6s than for 5d or 6p electrons. The various relativistic effects on valence electrons are discussed in detail to determine the proper level of the approximation for the valence electron calculations of systems with heavy elements. An effective core potential system has been developed for heavy atoms in which relativistic effects are included in the effective potentials.

  18. Heavy Metal Residues in Soil and Accumulation in Maize at Long-Term Wastewater Irrigation Area in Tongliao, China

    Directory of Open Access Journals (Sweden)

    Yintao Lu

    2015-01-01

    Full Text Available Soil and plant samples were collected from Tongliao, China, during the maize growth cycle between May and October 2010. Heavy metals, such as Cr, Pb, Ni, and Zn, were analyzed. The concentrations of Cr, Pb, Ni, and Zn in the wastewater-irrigated area were higher than those in the topsoil from the groundwater-irrigated area. The concentrations of metals in the maize increased as follows: Pb < Ni < Zn < Cr. In addition, Cr, Pb, and Ni mainly accumulated in the maize roots, and Zn mainly accumulated in the maize fruit. The results of translocation factors (TF and bioconcentration factors (BCF of maize for heavy metals revealed that maize is an excluder plant and a potential accumulator plant and can serve as an ideal slope remediation plant. In addition, the increasing heavy metal contents in soils that have been polluted by wastewater irrigation must result in the accumulation of Cr, Pb, Ni, and Zn in maize. Thus, the pollution level can be decreased by harvesting and disposing of and recovering the plant material.

  19. Characterisation and management of concrete grinding residuals.

    Science.gov (United States)

    Kluge, Matt; Gupta, Nautasha; Watts, Ben; Chadik, Paul A; Ferraro, Christopher; Townsend, Timothy G

    2018-02-01

    Concrete grinding residue is the waste product resulting from the grinding, cutting, and resurfacing of concrete pavement. Potential beneficial applications for concrete grinding residue include use as a soil amendment and as a construction material, including as an additive to Portland cement concrete. Concrete grinding residue exhibits a high pH, and though not hazardous, it is sufficiently elevated that precautions need to be taken around aquatic ecosystems. Best management practices and state regulations focus on reducing the impact on such aquatic environment. Heavy metals are present in concrete grinding residue, but concentrations are of the same magnitude as typically recycled concrete residuals. The chemical composition of concrete grinding residue makes it a useful product for some soil amendment purposes at appropriate land application rates. The presence of unreacted concrete in concrete grinding residue was examined for potential use as partial replacement of cement in new concrete. Testing of Florida concrete grinding residue revealed no dramatic reactivity or improvement in mortar strength.

  20. Environmental pre-disposition of Organisms to Contaminants with references to Heavy Metals Residues in the Brackish and Marines Gastropods

    OpenAIRE

    Ikpesu, T.O

    2017-01-01

    Environmental influences on organisms were studied on most common mollusks in the mangrove swamp and lower intertidal zone of Atlantic Ocean, Nigeria. Samples were collected between January and December, 2016. Five samples each of common whelk and Littorina littorea of relatively equal size and weight were collected at night from different stations and transported to the laboratory in a well ventilated container. Heavy metals in the tissues were digested with 5mL of HNO3 and 3mL of concentrat...

  1. A semi-exclusive study of heavy-residue production in the 40Ar+Ag reaction at 35 MeV/u incident energy

    International Nuclear Information System (INIS)

    Bizard, G.; Brou, R.

    1985-01-01

    Heavy residues created in the reaction Ar+Ag at 35 MeV/u have been detected at various forward angles. Their velocity spectra (quite different from the corresponding spectra measured at 27 MeV/u) show that these events result both from central and peripheral reactions and that the fusion component has dramatically decreased. Coincident light charged particles spectra have been obtained in a large solid angle forward hodoscope. The analysis of these spectra allows to differentiate peripheral and central collisions. The proton spectra are analysed in terms of emitting sources. There is no need for a participant zone in peripheral reactions. Instead protons are emitted either from the target-like or from the projectile-like fragments. However projectile sequential emission is not sufficient to explain all the high energy protons

  2. Determination of Leacheability of U, Th and Heavy Metals of Water Leached Purification (WLP) Residue and Soil from Bauxite Mining Area using Toxicity Characteristic Leaching Technique

    International Nuclear Information System (INIS)

    Siti Aminah Omar; Suhaimi Hamzah; Shamsiah Abdul Rahman

    2016-01-01

    The study was conducted to analyse the leachability of U, Th and heavy metals Cu, Cd, As, Pb, Mn, Zn, Ba, Se, Cr and Fe of water leached purification (WLP) residue gathered from Lynas Malaysia Sdn Bhd and soil from bauxite mining area, Kuantan. Their toxicity was assessed using the toxicity characteristic leaching procedure (TCLP) developed by the United States Environmental Protection Agency. The concentration of the elements studied was analysed using inductively coupled plasma mass spectrometry (ICP-MS). Results from the analysis indicated that the concentrations for all the elements studied in this project are well below than the TCLP regulatory limit. The concentrations of U and Th in leached solution were between 0.01 - 0.20 Bq/ kg. The concentrations of the multi elements were mostly between 0.02 - 1471 μg/ l, but certain elements such as Fe had concentration as high as 4707 μg/ l. Hence, it can be concluded that the WLP residue from Lynas and soil from bauxite mining area are very stable in the environment and does not pose any environmental problem. (author)

  3. DETERMINATION OF HEAVY METALS AND PESTICIDES IN GINSENG PRODUCTS

    Science.gov (United States)

    Medicinal plants may carry residuals of environmentally persistent pesticides or assimilate heavy metals in varying degrees. Several factors may influence contaminant accumulation, including species, level and duration of contaminant exposure, and topography. As part of a progra...

  4. Pesticide residues, heavy metals, and DNA damage in sentinel oysters Crassostrea gigas from Sinaloa and Sonora, Mexico.

    Science.gov (United States)

    Vázquez-Boucard, Celia; Anguiano-Vega, Gerardo; Mercier, Laurence; Rojas del Castillo, Emilio

    2014-01-01

    Pesticides and heavy metals were analyzed in sentinel Crassostrea gigas oysters placed in six aquaculture sites close to a contaminated agricultural region. Each site was sampled twice. Tests revealed the presence of organochlorine (OC) pesticides in the oysters at concentrations varying from 31.8 to 72.5 μg/kg for gamma-hexachlorocyclohexane (γ-HCH); from 1.2 to 3.1 μg/kg for dichlorodiphenyldichloroethylene (4,4-DDE); from 1.6 to 2.3 μg/kg for endosulfan I; and from 1.4 to 41.2 μg/kg for endosulfan II, as well as heavy metals in concentrations that exceeded Mexican tolerance levels (405.5 to 987.8 μg/g for zinc; 4.2 to 7.3 μg/g for cadmium; and 7.2 to 9.9 μg/g for lead). Significant levels of DNA damage in oyster hemocytes were also detected. There was a significant, positive correlation between genotoxic damage and concentration of nickel or the presence of endosulfan II. Cellular viability evaluated by cytotoxic analyses was found to be high at 80%. Marked inhibition in activity of acetylcholinesterase (AChE ) and induction of glutathione S-transferase (GST) activity was noted. Data demonstrated a significant relation between AChE activity inhibition and presence of endosulfan II, γ-HCH, copper, lead, and 4,4-DDE, as well as between AChE and GST activity at different sites.

  5. Heavy metal water pollution associated with the use of sewage sludge compost and limestone outcrop residue for soil restoration: effect of saline irrigation.

    Science.gov (United States)

    Pérez-Gimeno, Ana; Navarro-Pedreño, Jose; Gómez, Ignacio; Belén Almedro-Candel, María; Jordán, Manuel M.; Bech, Jaume

    2015-04-01

    The use of composted sewage sludge and limestone outcrop residue in soil restoration and technosol making can influence the mobility of heavy metals into groundwater. The use of compost from organic residues is a common practice in soil and land rehabilitation, technosol making, and quarry restoration (Jordán et al. 2008). Compost amendments may improve the physical, chemical, and biological properties of soils (Jordão et al. 2006; Iovieno et al. 2009). However, the use of compost and biosolids may have some negative effects on the environment (Karaca 2004; Navarro-Pedreño et al. 2004). This experiment analyzed the water pollution under an experimental design based on the use of columns (0-30 cm) formed by both wastes. Two waters of different quality (saline and non-saline) were used for irrigation. The presence of heavy metals (Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn) in the leachates was checked under controlled conditions inside a greenhouse (mean values: 20°±5°C and around 60% relative humidity). Sixteen 30-cm tall columns made of PVC pipe with internal diameters of 10.5 cm were prepared. The columns were filled with one of these materials: either sewage sludge compost (SW) or limestone outcrop residue (LR), fraction (<4 mm). The columns were irrigated with 2000 mL/week (230 mm) for twelve weeks (April to July). Half of them were irrigated with non-saline water (NS) and the others were so with saline water (S) from the beginning of the experiment. Four treatments combining the quality of the irrigation water (saline and non-saline) and wastes were studied: SW-NS, SW-S, LR-NS, and LR-S. After 24 hours of irrigation on the first day of each week, the leachates were taken and analyzed the heavy metal content (AAS-ES espectometer). The environmental risk due to the presence of heavy metals associated with the use of these materials was very low in general (under 0.1 mg/L). The use of sewage sludge favoured the presence of these metals in the lecheates and no effect

  6. A sensitive multi-residue method for the determination of 35 micropollutants including pharmaceuticals, iodinated contrast media and pesticides in water.

    Science.gov (United States)

    Valls-Cantenys, Carme; Scheurer, Marco; Iglesias, Mònica; Sacher, Frank; Brauch, Heinz-Jürgen; Salvadó, Victoria

    2016-09-01

    A sensitive, multi-residue method using solid-phase extraction followed by liquid chromatography-tandem mass spectrometry (LC-MS/MS) was developed to determine a representative group of 35 analytes, including corrosion inhibitors, pesticides and pharmaceuticals such as analgesic and anti-inflammatory drugs, five iodinated contrast media, β-blockers and some of their metabolites and transformation products in water samples. Few other methods are capable of determining such a broad range of contrast media together with other analytes. We studied the parameters affecting the extraction of the target analytes, including sorbent selection and extraction conditions, their chromatographic separation (mobile phase composition and column) and detection conditions using two ionisation sources: electrospray ionisation (ESI) and atmospheric pressure chemical ionisation (APCI). In order to correct matrix effects, a total of 20 surrogate/internal standards were used. ESI was found to have better sensitivity than APCI. Recoveries ranging from 79 to 134 % for tap water and 66 to 144 % for surface water were obtained. Intra-day precision, calculated as relative standard deviation, was below 34 % for tap water and below 21 % for surface water, groundwater and effluent wastewater. Method quantification limits (MQL) were in the low ng L(-1) range, except for the contrast agents iomeprol, amidotrizoic acid and iohexol (22, 25.5 and 17.9 ng L(-1), respectively). Finally, the method was applied to the analysis of 56 real water samples as part of the validation procedure. All of the compounds were detected in at least some of the water samples analysed. Graphical Abstract Multi-residue method for the determination of micropollutants including pharmaceuticals, iodinated contrast media and pesticides in waters by LC-MS/MS.

  7. A quantitative assessment of risks of heavy metal residues in laundered shop towels and their use by workers.

    Science.gov (United States)

    Connor, Kevin; Magee, Brian

    2014-10-01

    This paper presents a risk assessment of exposure to metal residues in laundered shop towels by workers. The concentrations of 27 metals measured in a synthetic sweat leachate were used to estimate the releasable quantity of metals which could be transferred to workers' skin. Worker exposure was evaluated quantitatively with an exposure model that focused on towel-to-hand transfer and subsequent hand-to-food or -mouth transfers. The exposure model was based on conservative, but reasonable assumptions regarding towel use and default exposure factor values from the published literature or regulatory guidance. Transfer coefficients were derived from studies representative of the exposures to towel users. Contact frequencies were based on assumed high-end use of shop towels, but constrained by a theoretical maximum dermal loading. The risk estimates for workers developed for all metals were below applicable regulatory risk benchmarks. The risk assessment for lead utilized the Adult Lead Model and concluded that predicted lead intakes do not constitute a significant health hazard based on potential worker exposures. Uncertainties are discussed in relation to the overall confidence in the exposure estimates developed for each exposure pathway and the likelihood that the exposure model is under- or overestimating worker exposures and risk. Copyright © 2014 Elsevier Inc. All rights reserved.

  8. Bioaccessibility and health risk of heavy metals in ash from the incineration of different e-waste residues.

    Science.gov (United States)

    Tao, Xiao-Qing; Shen, Dong-Sheng; Shentu, Jia-Li; Long, Yu-Yang; Feng, Yi-Jian; Shen, Chen-Chao

    2015-03-01

    Ash from incinerated e-waste dismantling residues (EDR) may cause significant health risks to people through ingestion, inhalation, and dermal contact exposure pathways. Ashes of four classified e-waste types generated by an incineration plant in Zhejiang, China were collected. Total contents and the bioaccessibilities of Cd, Cu, Ni, Pb, and Zn in ashes were measured to provide crucial information to evaluate the health risks for incinerator workers and children living in vicinity. Compared to raw e-waste in mixture, ash was metal-enriched by category incinerated. However, the physiologically based extraction test (PBET) indicates the bioaccessibilities of Ni, Pb, and Zn were less than 50 %. Obviously, bioaccessibilities need to be considered in noncancer risk estimate. Total and PBET-extractable contents of metal, except for Pb, were significantly correlated with the pH of the ash. Noncancer risks of ash from different incinerator parts decreased in the order bag filter ash (BFA) > cyclone separator ash (CFA) > bottom ash (BA). The hazard quotient for exposure to ash were decreased as ingestion > dermal contact > inhalation. Pb in ingested ash dominated (>80 %) noncancer risks, and children had high chronic risks from Pb (hazard index >10). Carcinogenic risks from exposure to ash were under the acceptable level (incinerated ash are made.

  9. Quantification of heavy metals from residual waste and ashes from the treatment plant of residual water Reciclagua and,effects for the health of those workers which manipulate those residuals; Cuantificacion de metales pesados de lodo residual y cenizas de la planta tratadora de aguas residuales Reciclagua y efectos a la salud de los trabajadores que manipulan los residuos

    Energy Technology Data Exchange (ETDEWEB)

    Guerrero D, J.J

    2004-07-01

    concentrations greater than 0.5% in weight, as long as the analysis of plasma emission spectroscopy very low concentrations are identified already that this method causes the destruction of the sample achieving the identification of all the present elements. With the obtained results we are able to compare the concentrations of the metals before and after the leaching and we calculate by this way the percentage of efficiency for each one of the variables that were managed in the development of the study, obtaining the extraction of those toxic, and valuable metals, present in the muds until of 100%. Based on the results we can mention that the workers are exposed to aerosols and powders of these toxic residuals which contain heavy metals. (Author)

  10. Technological alternatives for the handling of high viscosity heavy crude oil and of petroleum residuals; Alternativas tecnologicas para el manejo de crudos pesados de alta viscosidad y residuales de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez S, Ramon; Peralta M, Maria Vita; Gonzalez Santalo, Jose M.; Herrera V, J. Ramon; Arriola M, Alejandro M.; Manzanares P, Emilio; Romo M, Cesar A.; Palacios L, Elvia M. [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2006-07-01

    This work presents the technological capacity that, through the years, has been developed in emulsions of heavy oil in water preparations, as well as the potential application that this technology has in the electrical sector and the problem reduction during the extraction and handling of high viscosity heavy oils. Within this technological development it first appears the process for the formation of emulsions of residual petroleum within lots, followed by the preparation of emulsions in a continuous way within a laboratory model, and finally the production in greater scale in a pilot plant, including more and more adequate tense-actives for the formation of emulsions. Also experimental systems are presented to execute static stability and dynamic tests in different conditions, pumping tests for the handling of these emulsions and burning tests for their combustion. All of this with the purpose of consolidating the technology of residual petroleum emulsions as a profitable alternative that replaces the heavy fuel oil and to solve specific problems of the oil industry, among other benefits. [Spanish] Este trabajo exhibe la capacidad tecnologica que, a traves de los anos, se ha desarrollado en la preparacion de emulsiones de aceites pesados en agua; asi como el potencial de aplicacion que tiene dicha tecnologia en el sector electrico y la reduccion de problemas durante la extraccion y manejo de aceites pesados de alta viscosidad. Dentro de este desarrollo tecnologico figura primero el proceso para la formacion de emulsiones de residuales de petroleo dentro de lotes, seguido por la preparacion de emulsiones en continuo dentro de un laboratorio modelo, y finalmente la produccion a mayor escala en una planta piloto, incluyendo cada vez mas adecuados tenso-activos para la formacion de las emulsiones. Tambien se presentan sistemas experimentales para ejecutar pruebas de estabilidad estatica y dinamica en diferentes condiciones, pruebas de bombeo para el manejo de estas

  11. Evaluation of the vibration attenuation properties of an air-inflated cushion with two different heavy machinery seats in multi-axis vibration environments including jolts.

    Science.gov (United States)

    Ji, Xiaoxu; Eger, Tammy R; Dickey, James P

    2017-03-01

    Seats and cushions can attenuate whole-body vibration (WBV) exposures and minimize health risks for heavy machine operators. We successfully developed neural network (NN) algorithms to identify the vibration attenuation properties for four different seating conditions (seat/cushion combinations), and implemented each of the NN models to predict the equivalent daily exposure A(8) values for various vehicles in the forestry and mining environments. We also evaluated the performance of the new prototype No-Jolt™ air-inflated cushion and the original cushion of each seat with jolt exposures. We observed that the air cushion significantly improved the vibration attenuation properties of the seat that initially had good performance, but not for the seat that had relatively poor vibration attenuation properties. In addition, operator's anthropometrics and sex influenced the performance of the air-inflated cushion when the vibration environment included jolt exposures. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. Assessment of heavy metal contamination in raw milk for human ...

    African Journals Online (AJOL)

    The presence of heavy metals in various farm inputs, including feed, fertilizer, water and environment leads to excretion of the residues in animals' milk. Because consumption of milk contaminated with heavy metals poses serious threats to consumers' health, a study was conducted in 2012 – 2013 in Pakistan to evaluate ...

  13. Influence of partial replacement of soya bean meal by faba beans or peas in heavy pigs diet on meat quality, residual anti-nutritional factors and phytoestrogen content.

    Science.gov (United States)

    Gatta, Domenico; Russo, Claudia; Giuliotti, Lorella; Mannari, Claudio; Picciarelli, Piero; Lombardi, Lara; Giovannini, Luca; Ceccarelli, Nello; Mariotti, Lorenzo

    2013-06-01

    The study evaluated the partial substitution of soybean meal by faba beans (18%) or peas (20%) as additional protein sources in diets destined for typical Italian heavy pig production. It compared animal performances, meat quality, the presence of residual anti-nutritional factors (ANF) and phytoestrogens in plasma and meat and the possible effects on pig health, by evaluating oxidative, inflammatory and pro-atherogenic markers. The results showed that the productive performances, expressed as body weight and feed conversion ratio, of pigs fed with faba bean and pea diets were similar to those of pigs fed only the soybean meal. Meat quality of pigs fed with the three diets was similar in colour, water-holding capacity, tenderness and chemical composition. Despite the higher levels of phytoestrogen in the plasma of pigs fed only the soybean meal, phytoestrogen concentration in the muscle was equivalent to that of animals fed diets with faba beans, whereas pigs fed a diet with peas showed a lower concentration. Inflammation and pro-atherogenic parameters did not show significant differences among the three diets. Overall, the partial substitution of soybean meal by faba beans appears more interesting than with peas, particularly in relation to the higher amount of polyphenols in the diet and the highest concentration of phytoestrogens found in the plasma and muscle of animals, while the pyrimidine anti-nutritional compounds present in the diet did not appear to accumulate and had no effect on the growth performance of animals.

  14. High-resolution diffraction for residual stress determination in the NiCrMoV wheel of an axial compressor for a heavy-duty gas turbine

    Science.gov (United States)

    Rogante, M.; Török, G.; Ceschini, G. F.; Tognarelli, L.; Füzesy, I.; Rosta, L.

    2004-07-01

    The wheel of an axial compressor for a heavy-duty gas turbine has been investigated for residual stresses (RS) evaluation of the teeth-section where SANS measurements have previously been performed. Such a component can contain internal RS, either due to the manufacturing process, or to the operating cycles fatigue. The constitutive material is a NiCrMoV steel to ASTM A 471 (type 2) norms (equivalent to B50A420B10); this material is usually adopted in the manufacturing of forged components for gas turbines. Internal radial and hoop RS have been determined, whose values are under the limit of 200kPa. Hoop RS, in general, resulted in higher value than the radial ones. The present experiment represents a particularly important step in the RS determination for gas turbine components, since the measurements reveal that the fatigue of the wheel is also a lifetime limiting factor although, in the same technological field, the available data in the actual neutron techniques literature mainly concern turbine buckets.

  15. High-resolution diffraction for residual stress determination in the NiCrMoV wheel of an axial compressor for a heavy-duty gas turbine

    International Nuclear Information System (INIS)

    Rogante, M.; Toeroek, G.; Ceschini, G.F.; Tognarelli, L.; Fuezesy, I.; Rosta, L.

    2004-01-01

    The wheel of an axial compressor for a heavy-duty gas turbine has been investigated for residual stresses (RS) evaluation of the teeth-section where SANS measurements have previously been performed. Such a component can contain internal RS, either due to the manufacturing process, or to the operating cycles fatigue. The constitutive material is a NiCrMoV steel to ASTM A 471 (type 2) norms (equivalent to B50A420B10); this material is usually adopted in the manufacturing of forged components for gas turbines. Internal radial and hoop RS have been determined, whose values are under the limit of 200 kPa. Hoop RS, in general, resulted in higher value than the radial ones. The present experiment represents a particularly important step in the RS determination for gas turbine components, since the measurements reveal that the fatigue of the wheel is also a lifetime limiting factor although, in the same technological field, the available data in the actual neutron techniques literature mainly concern turbine buckets

  16. Field Measurements of Trace Gases and Aerosols Emitted by Undersampled Combustion Sources Including Wood and Dung Cooking Fires, Garbage and Crop Residue Burning, and Indonesian Peat Fires

    Science.gov (United States)

    Stockwell, C.; Jayarathne, T. S.; Goetz, D.; Simpson, I. J.; Selimovic, V.; Bhave, P.; Blake, D. R.; Cochrane, M. A.; Ryan, K. C.; Putra, E. I.; Saharjo, B.; Stone, E. A.; DeCarlo, P. F.; Yokelson, R. J.

    2017-12-01

    Field measurements were conducted in Nepal and in the Indonesian province of Central Kalimantan to improve characterization of trace gases and aerosols emitted by undersampled combustion sources. The sources targeted included cooking with a variety of stoves, garbage burning, crop residue burning, and authentic peat fires. Trace gas and aerosol emissions were studied using a land-based Fourier transform infrared spectrometer, whole air sampling, photoacoustic extinctiometers (405 and 870nm), and filter samples that were analyzed off-line. These measurements were used to calculate fuel-based emission factors (EFs) for up to 90 gases, PM2.5, and PM2.5 constituents. The aerosol optical data measured included EFs for the scattering and absorption coefficients, the single scattering albedo (at 870 and 405 nm), as well as the absorption Ångström exponent. The emissions varied significantly by source, although light absorption by both brown and black carbon (BrC and BC, respectively) was important for all non-peat sources. For authentic peat combustion, the emissions of BC were negligible and absorption was dominated by organic aerosol. The field results from peat burning were in reasonable agreement with recent lab measurements of smoldering Kalimantan peat and compare well to the limited data available from other field studies. The EFs can be used with estimates of fuel consumption to improve regional emissions inventories and assessments of the climate and health impacts of these undersampled sources.

  17. Optimization of biological and instrumental detection of explosives and ignitable liquid residues including canines, SPME/ITMS and GC/MSn

    Science.gov (United States)

    Furton, Kenneth G.; Harper, Ross J.; Perr, Jeannette M.; Almirall, Jose R.

    2003-09-01

    A comprehensive study and comparison is underway using biological detectors and instrumental methods for the rapid detection of ignitable liquid residues (ILR) and high explosives. Headspace solid phase microextraction (SPME) has been demonstrated to be an effective sampling method helping to identify active odor signature chemicals used by detector dogs to locate forensic specimens as well as a rapid pre-concentration technique prior to instrumental detection. Common ignitable liquids and common military and industrial explosives have been studied including trinitrotoluene, tetryl, RDX, HMX, EGDN, PETN and nitroglycerine. This study focuses on identifying volatile odor signature chemicals present, which can be used to enhance the level and reliability of detection of ILR and explosives by canines and instrumental methods. While most instrumental methods currently in use focus on particles and on parent organic compounds, which are often involatile, characteristic volatile organics are generally also present and can be exploited to enhance detection particularly for well-concealed devices. Specific examples include the volatile odor chemicals 2-ethyl-1-hexanol and cyclohexanone, which are readily available in the headspace of the high explosive composition C-4; whereas, the active chemical cyclo-1,3,5-trimethylene-2,4,6-trinitramine (RDX) is not. The analysis and identification of these headspace 'fingerprint' organics is followed by double-blind dog trials of the individual components using certified teams in an attempt to isolate and understand the target compounds to which dogs are sensitive. Studies to compare commonly used training aids with the actual target explosive have also been undertaken to determine their suitability and effectiveness. The optimization of solid phase microextraction (SPME) combined with ion trap mobility spectrometry (ITMS) and gas chromatography/mass spectrometry/mass spectrometry (GC/MSn) is detailed including interface development

  18. Heavy baryons

    International Nuclear Information System (INIS)

    Koerner, J.G.

    1994-06-01

    We review the experimental and theoretical status of baryons containing one heavy quark. The charm and bottom baryon states are classified and their mass spectra are listed. The appropriate theoretical framework for the description of heavy baryons is the Heavy Quark Effective Theory, whose general ideas and methods are introduced and illustrated in specific examples. We present simple covariant expressions for the spin wave functions of heavy baryons including p-wave baryons. The covariant spin wave functions are used to determine the Heavy Quark Symmetry structure of flavour-changing current-induced transitions between heavy baryons as well as one-pion and one-photon transitions between heavy baryons of the same flavour. We discuss 1/m Q corrections to the current-induced transitions as well as the structure of heavy to light baryon transitions. Whenever possible we attempt to present numbers to compare with experiment by making use of further model-dependent assumptions as e.g. the constituent picture for light quarks. We highlight recent advances in the theoretical understanding of the inclusive decays of hadrons containing one heavy quark including polarization. For exclusive semileptonic decays we discuss rates, angular decay distributions and polarization effects. We provide an update of the experimental and theoretical status of lifetimes of heavy baryons and of exclusive nonleptonic two body decays of charm baryons. (orig.)

  19. Residue processing

    Energy Technology Data Exchange (ETDEWEB)

    Gieg, W.; Rank, V.

    1942-10-15

    In the first stage of coal hydrogenation, the liquid phase, light and heavy oils were produced; the latter containing the nonliquefied parts of the coal, the coal ash, and the catalyst substances. It was the problem of residue processing to extract from these so-called let-down oils that which could be used as pasting oils for the coal. The object was to obtain a maximum oil extraction and a complete removal of the solids, because of the latter were returned to the process they would needlessly burden the reaction space. Separation of solids in residue processing could be accomplished by filtration, centrifugation, extraction, distillation, or low-temperature carbonization (L.T.C.). Filtration or centrifugation was most suitable since a maximum oil yield could be expected from it, since only a small portion of the let-down oil contained in the filtration or centrifugation residue had to be thermally treated. The most satisfactory centrifuge at this time was the Laval, which delivered liquid centrifuge residue and centrifuge oil continuously. By comparison, the semi-continuous centrifuges delivered plastic residues which were difficult to handle. Various apparatus such as the spiral screw kiln and the ball kiln were used for low-temperature carbonization of centrifuge residues. Both were based on the idea of carbonization in thin layers. Efforts were also being made to produce electrode carbon and briquette binder as by-products of the liquid coal phase.

  20. Heavy flavors

    International Nuclear Information System (INIS)

    Cox, B.; Gilman, F.J.; Gottschalk, T.D.

    1986-11-01

    A range of issues pertaining to heavy flavors at the SSC is examined including heavy flavor production by gluon-gluon fusion and by shower evolution of gluon jets, flavor tagging, reconstruction of Higgs and W bosons, and the study of rare decays and CP violation in the B meson system. A specific detector for doing heavy flavor physics and tuned to this latter study at the SSC, the TASTER, is described. 36 refs., 10 figs

  1. Diffusion-weighted MR imaging including bi-exponential fitting for the detection of recurrent or residual tumour after (chemo)radiotherapy for laryngeal and hypopharyngeal cancers

    Energy Technology Data Exchange (ETDEWEB)

    Tshering Vogel, Dechen W.; Vermathen, Peter; Thoeny, Harriet C. [University of Bern, Department of Diagnostic, Interventional and Paediatric Radiology, Inselspital, Bern (Switzerland); Zbaeren, Peter [University of Bern, Department of Oto-Rhino-Laryngology, Head and Neck Surgery, Inselspital, Bern (Switzerland); Geretschlaeger, Andreas [University of Bern, Department of Radiation Oncology, Inselspital, Bern (Switzerland); Keyzer, Frederik de [University Hospitals Leuven, Department of Radiology, Leuven (Belgium)

    2013-02-15

    To assess whether diffusion-weighted magnetic resonance imaging (DW-MRI) including bi-exponential fitting helps to detect residual/recurrent tumours after (chemo)radiotherapy of laryngeal and hypopharyngeal carcinoma. Forty-six patients with newly-developed/worsening symptoms after (chemo)radiotherapy for laryngeal/hypopharyngeal cancers were prospectively imaged using conventional MRI and axial DW-MRI. Qualitative (visual assessment) and quantitative analysis (mono-exponentially: total apparent diffusion coefficient [ADC{sub T}], and bi-exponentially: perfusion fraction [F{sub P}] and true diffusion coefficient [ADC{sub D}]) were performed. Diffusion parameters of tumour versus post-therapeutic changes were compared, with final diagnosis based on histopathology and follow-up. Mann-Whitney U test was used for statistical analysis. Qualitative DW-MRI combined with morphological images allowed the detection of tumour with a sensitivity of 94% and specificity 100%. ADC{sub T} and ADC{sub D} values were lower in tumour with values 120 {+-} 49 x 10{sup -5} mm{sup 2}/s and 113 {+-} 50 x 10{sup -5} mm{sup 2}/s, respectively, compared with post-therapeutic changes with values 182 {+-} 41 x 10{sup -5} mm{sup 2}/s (P < 0.0002) and 160 {+-} 47 x 10{sup -5} mm{sup 2}/s (P < 0.003), respectively. F{sub P} values were significantly lower in tumours than in non-tumours (13 {+-} 9% versus 31 {+-} 16%, P < 0.0002), with F{sub P} being the best quantitative parameter for differentiation between post-therapeutic changes and recurrence. DW-MRI in combination with conventional MRI substantially improves detection and exclusion of tumour in patients with laryngeal and hypopharyngeal cancers after treatment with (chemo)radiotherapy on both qualitative and quantitative analysis, with F{sub P} being the best quantitative parameter in this context. (orig.)

  2. On the magnetoresistance of heavy fermion compounds

    International Nuclear Information System (INIS)

    Lee Chengchung; Chen Chung

    1992-09-01

    Starting from two-conduction-band Anderson lattice model, the magneto-transport properties of heavy fermion systems are studied in the slave boson mean field theory. The residual magnetoresistivity induced by different kinds of impurities is calculated, and the experimentally detected positive maximum structure in the residual magnetoresistance of heavy fermion systems is reproduced. The transition of field-dependent resistivity from nonmonotonic to monotonic behaviour with increasing temperature can be explained naturally by including the charge fluctuation effect. The influence of applied pressure is also investigated. (author). 22 refs, 5 figs

  3. La conversion des résidus et huiles lourdes : au carrefour du thermique et du catalytique Conversion of Residues and Heavy Oils At the Crossroads of Thermal Cracking and Catalytic Reactions

    Directory of Open Access Journals (Sweden)

    Le Page J. F.

    2006-11-01

    Full Text Available Cet article passe en revue les diverses familles de procédés de conversion des résidus et huiles lourdes. Tous les résultats semblent converger pour accréditer l'idée que dans tous ces procédés, y compris les procédés dits catalytiques, l'essentiel de la conversion des espèces de poids moléculaire élevé, résines et asphaltènes, procède par mécanisme radicalaire : la clef de la conversion profonde, c'est paradoxalement la maîtrise de la condensation radicalaire de ces espèces. Hydrogène seul, hydrogène en présence de solvant donneur, d'additifs ou encore mieux de catalyseurs, sont les armes dont dispose tout raffineur pour affirmer cette maîtrise, dans la mesure où il ne tient pas à fabriquer du coke. Tous ces procédés de conversion des résidus donnent par ailleurs naissance à des produits craqués dont la nature et la distribution rappellent celles des produits de première distillation du pétrole brut dont est issu le résidu soumis au craquage. This article reviews the different families of conversion processes for residues and heavy oils. All the results seem to converge to support the idea that in all these processes, including so-called catalytic processes, most of the conversion of high-molecular-weight species (resins and asphaltenes operates by a radical mechanism. The key to in-depth conversion is, paradoxically, the mastery of the radical condensation of these species. Hydrogen alone, hydrogen in the presence of a donor solvent, of additives or, better yet, of catalysts, are the arms at the disposal of all refiners to assert this mastery, to the extent that they do not want to manufacture coke. All such conversion processes for residues also give rise to cracked products whose nature and distribution recall those of first-distillation products of crude oil, from which the residue comes that is subjected to cracking.

  4. Composition of carbonization residues

    Energy Technology Data Exchange (ETDEWEB)

    Hupfer; Leonhardt

    1943-11-30

    This report gave a record of the composition of several samples of residues from carbonization of various hydrogenation residue from processing some type of coal or tar in the Bergius process. These included Silesian bituminous coal processed at 600 atm. with iron catalyst, in one case to produce gasoline and middle oil and in another case to produce heavy oil excess, Scholven coal processed at 250 atm. with tin oxalate and chlorine catalyst, Bruex tar processed in a 10-liter oven using iron catalyst, and a pitch mixture from Welheim processed in a 10-liter over using iron catalyst. The values gathered were compared with a few corresponding values estimated for Boehlen tar and Gelsenberg coal based on several assumptions outlined in the report. The data recorded included percentage of ash in the dry residue and percentage of carbon, hydrogen, oxygen, nitrogen, chlorine, total sulfur, and volatile sulfur. The percentage of ash varied from 21.43% in the case of Bruex tar to 53.15% in the case of one of the Silesian coals. Percentage of carbon varied from 44.0% in the case of Scholven coal to 78.03% in the case of Bruex tar. Percentage of total sulfur varied from 2.28% for Bruex tar to a recorded 5.65% for one of the Silesian coals and an estimated 6% for Boehlen tar. 1 table.

  5. Collimator system for the stabilization of the dynamical residual-gas pressure in the heavy-ion synchrotron SIS18; Kollimatorsystem zur Stabilisierung des dynamischen Restgasdruckes im Schwerionensynchrotron SIS18

    Energy Technology Data Exchange (ETDEWEB)

    Omet, Carsten

    2009-01-15

    In order to achieve higher beam intensities of heavy ion beams in ring accelerators, low charge state ions can be used. By lowering the charge state, the space charge limit is shifted to higher particle numbers and stripping losses can be avoided. During test operation of the SIS18 at GSI with high intensity low charge state heavy ion beams, strong intensity dependent beam losses have been observed. It was found that these beam losses are originated to a large extent by the change of charge state of the circulating ions during collisions with residual gas atoms. The resulting deviation of m/q relative to the reference ion leads, in combination with dispersive elements in the ion optic lattice, to a modified trajectory, followed by the loss of the ion on the beam pipe. At the impact position, loosely bound residual gas molecules are released by ion stimulated desorption which increases the residual gas pressure locally. This pressure rise itself enhances the charge exchange rate, which can develop into a self amplifying process of pressure rise and subsequent beam loss. A method for the stabilization of the dynamic residual gas pressure is the use of special catcher systems, which minimize the production of desorption gases and remove them by strong pumping. Therefore, the pressure on the beam axis should remain as stable as possible. Other processes, e.g. Coulomb scattering of the beam ions by residual gas particles and unavoidable systematic beam losses can increase the gas pressure additionally. The pressure in the accelerator is further subjected to ionization of the residual gas atoms themselves, thermal out gassing of the beam pipes, insertions and pumps. In this work, a detailed numerical model of the interplay between the residual gas pressure dynamics in the accelerator, possible stabilization measures, e.g. by catchers and the resulting beam life time has been developed. The forecasted beam life times and pressures are verified by machine experiments, as

  6. Changing social norms: The impact of normative feedback included in motivational enhancement therapy on cannabis outcomes among heavy-using adolescents.

    Science.gov (United States)

    Blevins, Claire E; Walker, Denise D; Stephens, Robert S; Banes, Kelsey E; Roffman, Roger A

    2018-01-01

    Heavy cannabis use is a problematic behavior, particularly among some adolescents. Adolescents are particularly prone to social influence. As such, injunctive norms (perceptions of others' approval of cannabis use) and descriptive norms (perception of frequency of others' cannabis use) influence cannabis behavior. Given that norms are not always accurate, motivational enhancement therapy aims to reduce cannabis use through normative feedback and correction of normative misconceptions. The purpose of this study was to evaluate the relationships between perceived norms (descriptive and injunctive) and cannabis-related outcomes (use, cannabis-related problems, and cannabis use disorder symptoms) in a heavy cannabis-using adolescent population receiving motivational enhancement therapy. Heavy cannabis-using individuals (n=252, 68% male, mean age 13.38, 59% Caucasian) were recruited from six Seattle high schools for a motivational enhancement therapy-based intervention involving normative feedback. Participants perceived higher rates of cannabis use among close friends than other same age teens and reported a higher perception of approval for cannabis use from close friends as compared to perceived approval of other same aged peers. Personal approval and the perceived approval of other same age teens were reduced following the intervention but there was no evidence of change in normative perceptions for close friends following the normative feedback interventions. Changes in normative perceptions were related to decreases in cannabis use and -related outcomes. Results suggest the importance of normative feedback in changing behavior in adolescent cannabis users, but also highlight the ongoing influence of close friends. Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. The effects of Pantoea sp. strain Y4-4 on alfalfa in the remediation of heavy-metal-contaminated soil, and auxiliary impacts of plant residues on the remediation of saline-alkali soils.

    Science.gov (United States)

    Li, Shuhuan; Wang, Jie; Gao, Nanxiong; Liu, Lizhu; Chen, Yahua

    2017-04-01

    The plant-growth-promoting rhizobacterium (PGPR) Y4-4 was isolated from plant rhizosphere soil and identified as Pantoea sp. by 16S rRNA sequence analysis. The effects of strain Y4-4 on alfalfa grown in heavy-metals-contaminated soil was investigated using a pot experiment. In a Cu-rich environment, the shoot dry mass and total dry mass of plants inoculated with strain Y4-4 increased by 22.6% and 21%, and Cu accumulation increased by 15%. In a Pb-Zn-rich environment, the shoot dry mass and total dry mass of plants inoculated with strain Y4-4 increased by 23.4% and 22%, and Zn accumulation increased by 30.3%. In addition, the salt tolerance and biomass of wheat seedlings could be improved by applying strain Y4-4 mixed with plant residue as a result of the Cu-rich plant residues providing copper nutrition to wheat. This study offers an efficient PGPR with strong salt tolerance and a safe strategy for the post-treatment of plant residue.

  8. Modelling the residual stresses and microstructural evolution in Friction Stir Welding of AA2024-T3 including the Wagner-Kampmann precipitation model

    DEFF Research Database (Denmark)

    Sonne, Mads Rostgaard; Hattel, Jesper Henri

    In this work, a numerical finite element model for friction stir welding of 2024-T3 aluminum alloy, consisting of a heat transfer analysis and a sequentially coupled quasi-static stress analysis is proposed. Metallurgical softening of the material is properly considered and included...

  9. Salts, sodium and heavy metals, in residual waters not purified, used for the watering in the cultivation of the sugar cane

    International Nuclear Information System (INIS)

    Mendez Romero, Franky Jose; Gisbert-Banquert, Juan Manuel

    2003-01-01

    In a farm located in the Valencia Lake Basin at northeast of Guacara city (Venezuelan country) and cultivated with sugar cane crop was evaluated during the period of July of 1996 to June of 1997 the salinity, sodicity and heavy metals concentration In municipal wastewater using to gravity Irrigated the sugar cane crop. The salinity was determinate by EC direct measure In Irrigation water (standardized at 25 Celsius degrade, Sodium by flame photometer Calcium and Magnesium by titulation with EDTA Cd, Cu, Fe Mn, Ni and Zn, were determinate by AAS before water samples preserve with NO 3 H. The wastewater quality employ to Irrigated the sugar cane crop was evaluated by mean of the Venezuelan official water Laws (1995) and compare too with the directives mentioned by Pratt and Suarez (1990), Crook and Bastian (1992) and the Mexican official wastewater irrigation laws NOM-CAA-032-ECOL/93 (1993. The results showed than the wastewater using to Irrigated the sugar cane field crop could to bring light and strong problems by salinity and sodium so much the soil as the crop The concentration of Cd, Fe and Cu are outside Limits proposals the Venezuelan official water laws (1995) Also when comparing the results with the other directives all the heavy metal concentration are outside the proposed Limits In each one of them except the Zn. In any case, the continuous use of the wastewater treated in this research could generate potential contamination and toxicity problems by heavy metals, salts and sodium In the crop, soils, groundwater and the people

  10. Residual deposits (residual soil)

    International Nuclear Information System (INIS)

    Khasanov, A.Kh.

    1988-01-01

    Residual soil deposits is accumulation of new formate ore minerals on the earth surface, arise as a result of chemical decomposition of rocks. As is well known, at the hyper genes zone under the influence of different factors (water, carbonic acid, organic acids, oxygen, microorganism activity) passes chemical weathering of rocks. Residual soil deposits forming depends from complex of geologic and climatic factors and also from composition and physical and chemical properties of initial rocks

  11. Caractérisation des huiles lourdes et des résidus pétroliers. Symposium international, Lyon, 25-27 juin 1984 Characterization of Heavy Crude Oils and Petroleum Residues. International Symposium, 25-27 June 1984

    Directory of Open Access Journals (Sweden)

    Dorbon M.

    2006-11-01

    Full Text Available Ce symposium a permis aux chercheurs et ingénieurs qui étudient les bruts lourds et les résidus pétroliers de confronter les résultats de leurs travaux. II fut en particulier beaucoup question des asphaltènes et on a pu constater que de réels progrès avaient été réalisés en ce qui concerne la caractérisation de ces fractions. Furent également présentées les techniques d'analyse les plus aptes à fournir des informations sur ces produits ainsi que les manières spécifiques de les mettre en oeuvre. Enfin, on a vu comment l'analyse des produits lourds contribuait à la mise au point ou à l'optimisation des procédés de traitement de ces huiles. This symposium enabled research scientists and engineers working with heavy oils and petroleum residues to compare their findings. Much attention was paid to asphaltenes, and it could be seen that real progress had been made with regard to the characterization of such fractions. The analysis techniques best able to provide information were described along with the specific ways of implementing them. Then the topic of how the analysis of heavy products was contributing to the development or optimization of methods for processing such oils was discussed.

  12. Heavy metals, salts and organic residues in old solid urban waste landfills and surface waters in their discharge areas: determinants for restoring their impact.

    Science.gov (United States)

    Pastor, J; Hernández, A J

    2012-03-01

    This study was designed to determine the state of polluted soils in the main landfills of the Community of Madrid (central Spain), as part of a continuous assessment of the impacts of urban solid waste (USW) landfills that were capped with a layer of soil 20 years ago. Our analysis of this problem has been highly conditioned by the constant re-use of many of the USW landfills, since they have never been the target of any specific restoration plan. Our periodical analysis of cover soils and soils from discharge areas of the landfills indicates soil pollution has worsened over the years. Here, we examined heavy metal, salts, and organic compounds in soil and surface water samples taken from 15 landfills in the Madrid region. Impacts of the landfill soil covers on nematode and plant diversity were also evaluated. These analyses continue to reveal the presence of heavy metals (Zn, Cu, Cr, Ni, Pb, Cd) in soils, and salts (sulphates, chlorides and nitrates) in soils and surface waters. In addition, non-agricultural organic compounds, mainly aromatic and aliphatic hydrocarbons, often appeared in very high concentrations, and high levels of insecticides such as gamma-HCH (lindane) were also detected in soils. Around 50% of the water samples collected showed chemical demand of oxygen (CDO) values in excess of 150 mg/l. Traces of phenolic compounds were detected in some landfills, some of which exhibited high levels of 2-chlorophenol and pentachlorophenol. All these factors are conditioning both the revegetation of the landfill systems and the remediation of their slopes and terrestrial ecosystems arising in their discharge areas. This work updates the current situation and discusses risks for the health of the ecosystems, humans, domestic animals and wildlife living close to these landfills. Copyright © 2011 Elsevier Ltd. All rights reserved.

  13. Evaluation of some heavy metals residues in batteries and deep litter rearing systems in Japanese quail meat and offal in Egypt

    Directory of Open Access Journals (Sweden)

    Ali M. Ahmed

    2017-02-01

    Full Text Available Aim: The main objectives of this study were for comparing the effect of batteries and deep litter rearing systems of domesticated Japanese quail, Coturnix coturnix japonica, on the concentration levels of cadmium, copper, lead, and zinc from the quail meat and offal in Ismailia, Egypt. Materials and Methods: A total of 40 quail meat and their offal samples were randomly collected from two main quail rearing systems: Battery (Group I and deep litter system (Group II for determination of concentration levels of cadmium, copper, lead, and zinc. In addition, 80 water and feed samples were randomly collected from water and feeders of both systems in the Food Hygiene Laboratory, Faculty of Veterinary Medicine, Suez Canal University for heavy metals determination. Results: The mean concentration levels of cadmium, copper, lead, and zinc in Group I were 0.010, 0.027, 1.137, and 0.516 ppm and for Group II were 0.093, 0.832, 0.601, and 1.651 ppm, respectively. The mean concentration levels of cadmium, copper, lead, and zinc in quail feed in Group I were 1.114, 1.606, 5.822, and 35.11 ppm and for Group II were 3.010, 2.576, 5.852, and 23.616 ppm, respectively. The mean concentration levels of cadmium, copper, lead, and zinc in quail meat for Group I were 0.058, 5.902, 10.244, and 290 ppm and for Group II were 0.086, 6.092, 0.136, and 1.280 ppm, respectively. The mean concentration levels of cadmium, copper, lead, and zinc for liver samples in Group I were 0.15, 8.32, 1.05, and 3.41 ppm and for Group II were 0.13, 8.88, 0.95, and 4.21 ppm, respectively. The mean concentration levels of cadmium, copper, lead, and zinc in kidney samples for the Group I were 0.24, 4.21, 1.96, and 4.03 ppm and for Group II were 0.20, 5.00, 1.56, and 3.78 ppm, respectively. Kidney had the highest concentration levels of heavy metals followed by liver then muscles. The highest concentration levels of copper were observed in liver samples. The order of the levels of these trace

  14. Evaluation of some heavy metals residues in batteries and deep litter rearing systems in Japanese quail meat and offal in Egypt.

    Science.gov (United States)

    Ahmed, Ali M; Hamed, Dalia M; Elsharawy, Nagwa T

    2017-02-01

    The main objectives of this study were for comparing the effect of batteries and deep litter rearing systems of domesticated Japanese quail, Coturnix coturnix japonica , on the concentration levels of cadmium, copper, lead, and zinc from the quail meat and offal in Ismailia, Egypt. A total of 40 quail meat and their offal samples were randomly collected from two main quail rearing systems: Battery (Group I) and deep litter system (Group II) for determination of concentration levels of cadmium, copper, lead, and zinc. In addition, 80 water and feed samples were randomly collected from water and feeders of both systems in the Food Hygiene Laboratory, Faculty of Veterinary Medicine, Suez Canal University for heavy metals determination. The mean concentration levels of cadmium, copper, lead, and zinc in Group I were 0.010, 0.027, 1.137, and 0.516 ppm and for Group II were 0.093, 0.832, 0.601, and 1.651 ppm, respectively. The mean concentration levels of cadmium, copper, lead, and zinc in quail feed in Group I were 1.114, 1.606, 5.822, and 35.11 ppm and for Group II were 3.010, 2.576, 5.852, and 23.616 ppm, respectively. The mean concentration levels of cadmium, copper, lead, and zinc in quail meat for Group I were 0.058, 5.902, 10.244, and 290 ppm and for Group II were 0.086, 6.092, 0.136, and 1.280 ppm, respectively. The mean concentration levels of cadmium, copper, lead, and zinc for liver samples in Group I were 0.15, 8.32, 1.05, and 3.41 ppm and for Group II were 0.13, 8.88, 0.95, and 4.21 ppm, respectively. The mean concentration levels of cadmium, copper, lead, and zinc in kidney samples for the Group I were 0.24, 4.21, 1.96, and 4.03 ppm and for Group II were 0.20, 5.00, 1.56, and 3.78 ppm, respectively. Kidney had the highest concentration levels of heavy metals followed by liver then muscles. The highest concentration levels of copper were observed in liver samples. The order of the levels of these trace elements obtained from the four different quail organs

  15. Heavy water pumps

    International Nuclear Information System (INIS)

    Zecevic, V.; Nikolic, M.

    1963-12-01

    Continuous increase of radiation intensity was observed on all the elements in the heavy water system during first three years of RA reactor operation. The analysis of heavy water has shown the existence of radioactive cobalt. It was found that cobalt comes from stellite, cobalt based alloy which was used for coating of the heavy water pump discs in order to increase resistance to wearing. Cobalt was removed from the surfaces due to friction, and transferred by heavy water into the reactor where it has been irradiated for 29 876 MWh up to 8-15 Ci/g. Radioactive cobalt contaminated all the surfaces of aluminium and stainless steel parts. This report includes detailed description of heavy water pumps repair, exchange of stellite coated parts, decontamination of the heavy water system, distillation of heavy water [sr

  16. Fe(CO)5-catalyzed coprocessing of coal and heavy oil vacuum residue using syngas-water as a hydrogen source; Fe(CO)5 shokubai ni yoru gosei gas-mizu wo suisogen to suru sekitan-jushitsuyu no coprocessing

    Energy Technology Data Exchange (ETDEWEB)

    Hata, K.; Wada, K.; Mitsudo, T. [Kyoto University, Kyoto (Japan)

    1996-10-28

    Improvement in efficiency and profitability of hydrogenation reaction of heavy hydrocarbon resources is the most important matter to be done. In this study, coprocessing of coal and heavy oil vacuum residue was conducted using syngas-water as a hydrogen source. For the investigation of effect of the reaction temperature during the coprocessing of Wandoan coal and Arabian heavy vacuum residue using Fe(CO)5 as a catalyst, the conversion, 66.0% was obtained at 425{degree}C. For the investigation of effect of reaction time, the yield of light fractions further increased during the two stage reaction at 400{degree}C for 60 minutes and at 425{degree}C for 60 minutes. Finally, almost 100% of THF-soluble matter was obtained through the reaction using 2 mmol of Fe(CO)5 catalyst at 400{degree}C for 60 minutes, and hydrogenation of heavy oil was proceeded simultaneously. When comparing coprocessing reactions using three kinds of hydrogen sources, i.e., hydrogen, CO-water, and syngas-water, the conversion yield and oil yield obtained by using syngas-water were similar to those obtained by using hydrogen, which demonstrated the effectiveness of syngas-water. 2 refs., 2 figs., 2 tabs.

  17. Soil heavy metals

    Energy Technology Data Exchange (ETDEWEB)

    Sherameti, Irena [Jena Univ. (Germany). Inst. fuer Allgemeine Botanik und Pflanzenphysiologie; Varma, Ajit (eds.) [Amity Univ., Uttar Pradesh (India). Amity Inst. of Microbial Technology; Amity Science, Technology and Innovation Foundation, Noida, UP (India)

    2010-07-01

    Human activities have dramatically changed the composition and organisation of soils. Industrial and urban wastes, agricultural application and also mining activities resulted in an increased concentration of heavy metals in soils. How plants and soil microorganisms cope with this situation and the sophisticated techniques developed for survival in contaminated soils is discussed in this volume. The topics presented include: the general role of heavy metals in biological soil systems; the relation of inorganic and organic pollutions; heavy metal, salt tolerance and combined effects with salinity; effects on abuscular mycorrhizal and on saprophytic soil fungi; heavy metal resistance by streptomycetes; trace element determination of environmental samples; the use of microbiological communities as indicators; phytostabilization of lead polluted sites by native plants; effects of soil earthworms on removal of heavy metals and the remediation of heavy metal contaminated tropical land. (orig.)

  18. Residual effects of prolonged heavy cannabis use

    NARCIS (Netherlands)

    van Amsterdam JGC; van der Laan JW; Slangen JL; LGM

    1996-01-01

    Recente literatuur werd geraadpleegd om na te gaan of langdurig gebruik van van grote hoeveelheden cannabis (dagelijks gebruik gedurende minimaal 6 maanden) leidt tot aanhoudende cognitieve effecten en effecten op het immuunsysteem. Het resultaat van deze studie is weergegeven in het huidige

  19. Improved inventory for heavy metal emissions from stationary combustion plants

    DEFF Research Database (Denmark)

    Nielsen, Malene; Nielsen, Ole-Kenneth; Hoffmann, Leif

    -2009. The report also include methodology, references and an uncertainty estimate. In Denmark, stationary combustion plants are among the most important emission sources for heavy metals. Emissions of all heavy metals have decreased considerably (73 % - 92 %) since 1990. The main HM emission sources are coal...... combustion, waste incineration, residual oil combustion and in 2009 also combustion of biomass. The emission from waste incineration plants has decreased profoundly also in recent years due to installation and improved performance of flue gas cleaning devices. The emission from power plants have also...

  20. Heavy Chain Diseases

    Science.gov (United States)

    ... heavy chain produced: Alpha Gamma Mu Alpha Heavy Chain Disease Alpha heavy chain disease (IgA heavy chain ... disease or lead to a remission. Gamma Heavy Chain Disease Gamma heavy chain disease (IgG heavy chain ...

  1. Residuation theory

    CERN Document Server

    Blyth, T S; Sneddon, I N; Stark, M

    1972-01-01

    Residuation Theory aims to contribute to literature in the field of ordered algebraic structures, especially on the subject of residual mappings. The book is divided into three chapters. Chapter 1 focuses on ordered sets; directed sets; semilattices; lattices; and complete lattices. Chapter 2 tackles Baer rings; Baer semigroups; Foulis semigroups; residual mappings; the notion of involution; and Boolean algebras. Chapter 3 covers residuated groupoids and semigroups; group homomorphic and isotone homomorphic Boolean images of ordered semigroups; Dubreil-Jacotin and Brouwer semigroups; and loli

  2. Thermal Adsorption Processing Of Hydrocarbon Residues

    Directory of Open Access Journals (Sweden)

    Sudad H. Al.

    2017-04-01

    Full Text Available The raw materials of secondary catalytic processes must be pre-refined. Among these refining processes are the deasphalting and demetallization including their thermo adsorption or thermo-contact adsorption variety. In oil processing four main processes of thermo-adsorption refining of hydrocarbon residues are used ART Asphalt Residual Treating - residues deasphaltizing 3D Discriminatory Destructive Distillation developed in the US ACT Adsorption-Contact Treatment and ETCC Express Thermo-Contact Cracking developed in Russia. ART and ACT are processes with absorbers of lift type reactor while 3D and ETCC processes are with an adsorbing reactor having ultra-short contact time of the raw material with the adsorbent. In all these processes refining of hydrocarbon residues is achieved by partial Thermo-destructive transformations of hydrocarbons and hetero-atomic compounds with simultaneous adsorption of the formed on the surface of the adsorbents resins asphaltene and carboids as well as metal- sulphur - and nitro-organic compounds. Demetallized and deasphalted light and heavy gas oils or their mixtures are a quality raw material for secondary deepening refining processes catalytic and hydrogenation cracking etc. since they are characterized by low coking ability and low content of organometallic compounds that lead to irreversible deactivation of the catalysts of these deepening processes.

  3. Heavy element research

    International Nuclear Information System (INIS)

    Anon.

    1976-01-01

    Heavy element research activities in metallurgy and ceramics during 1976 at Lawrence Berkeley Laboratory are reviewed. Topics include: microstructure, properties and alloy design; ceramic alloy program; high resolution and high voltage electron microscopy; and powder metallurgy

  4. Topical and working papers on heavy water requirements and availability

    International Nuclear Information System (INIS)

    The documents included in this report are: Heavy water requirements and availability; technological infrastructure for heavy water plants; heavy water plant siting; hydrogen and methane availability; economics of heavy water production; monothermal, water fed heavy water process based on the ammonia/hydrogen isotopic exchange; production strategies to meet demand projections; hydrogen availability; deuterium sources; the independent UHDE heavy water process

  5. Heavy metal

    African Journals Online (AJOL)

    of spawning, resistance to diseases and social acceptability (Pillay, 1993). This study aimed at determining the carbohydrate reserves and heavy metal accumulation of the Nile tilapia, Oreochromis miloticus after treatment with heavy metals such as lead, copper and zinc. 2. Materials and Methods. Test organism: Nile tilapia ...

  6. Heavy-ion dosimetry

    International Nuclear Information System (INIS)

    Schimmerling, W.

    1980-03-01

    This lecture deals with some of the more important physical characteristics of relativistic heavy ions and their measurement, with beam delivery and beam monitoring, and with conventional radiation dosimetry as used in the operation of the BEVALAC biomedical facility for high energy heavy ions (Lyman and Howard, 1977; BEVALAC, 1977). Even so, many fundamental aspects of the interaction of relativistic heavy ions with matter, including important atomic physics and radiation chemical considerations, are not discussed beyond the reminder that such additional understanding is required before an adequte perspective of the problem can be attained

  7. BOTANICAL DIVERSITY AND HEAVY METAL CONTENT IN THE RESIDUE MATRIX AND PLANTS AT THE MORAVIA DUMP IN MEDELLÍN, COLOMBIA DIVERSIDAD BOTÁNICA Y CONTENIDO DE METALES PESADOS EN LA MATRIZ DE RESIDUOS Y LAS PLANTAS EN EL BASURERO DE MORAVIA EN MEDELLÍN, COLOMBIA

    OpenAIRE

    Maria Solange Sanchez Pinzón; Álvaro Cogollo Pacheco; Catalina Arroyave Quiceno; Rubén Darío Torrenegra Guerrero; Ángel Maria Giraldo Mejía; Rolando Barahona Rosales

    2010-01-01

    . Floristic characterization, plant tissue and residue matrix (RM) analysis were conducted to establish the extent of heavy metal (HM) pollution of the Moravia dump at Medellín, Colombia, a site that was inhabited by more than 17000 people since 1984. More than 65 plant species (28 families) were identified, most of which were herbaceous. Content of HM in the (RM) was determined in 14 different RM samples varied greatly among them, reaching 121 and 9600 mg/kg of Hg and Pb respectively. Mean c...

  8. Towards a rational approach for heavy-atom derivative screening in protein crystallography

    International Nuclear Information System (INIS)

    Agniswamy, Johnson; Joyce, M. Gordon; Hammer, Carl H.; Sun, Peter D.

    2008-01-01

    Heavy-atom derivatization is routinely used in protein structure determination and is thus of critical importance in structural biology. In order to replace the current trial-and-error heavy-atom derivative screening with a knowledge-based rational derivative-selection method, the reactivity of more than 40 heavy-atom compounds over a wide range of buffer and pH values was systematically examined using peptides which contained a single reactive amino-acid residue. Heavy-atom derivatization is routinely used in protein structure determination and is thus of critical importance in structural biology. In order to replace the current trial-and-error heavy-atom derivative screening with a knowledge-based rational derivative-selection method, the reactivity of more than 40 heavy-atom compounds over a wide range of buffer and pH values was systematically examined using peptides which contained a single reactive amino-acid residue. Met-, Cys- and His-containing peptides were derivatized against Hg, Au and Pt compounds, while Tyr-, Glu-, Asp-, Asn- and Gln-containing peptides were assessed against Pb compounds. A total of 1668 reactive conditions were examined using mass spectrometry and were compiled into heavy-atom reactivity tables. The results showed that heavy-atom derivatization reactions are highly linked to buffer and pH, with the most accommodating buffer being MES at pH 6. A group of 21 compounds were identified as most successful irrespective of ligand or buffer/pH conditions. To assess the applicability of the peptide heavy-atom reactivity to proteins, lysozyme crystals were derivatized with a list of peptide-reactive compounds that included both known and new compounds for lysozyme derivatization. The results showed highly consistent heavy-atom reactivities between the peptides and lysozyme

  9. Handling of Solid Residues

    International Nuclear Information System (INIS)

    Medina Bermudez, Clara Ines

    1999-01-01

    The topic of solid residues is specifically of great interest and concern for the authorities, institutions and community that identify in them a true threat against the human health and the atmosphere in the related with the aesthetic deterioration of the urban centers and of the natural landscape; in the proliferation of vectorial transmitters of illnesses and the effect on the biodiversity. Inside the wide spectrum of topics that they keep relationship with the environmental protection, the inadequate handling of solid residues and residues dangerous squatter an important line in the definition of political and practical environmentally sustainable. The industrial development and the population's growth have originated a continuous increase in the production of solid residues; of equal it forms, their composition day after day is more heterogeneous. The base for the good handling includes the appropriate intervention of the different stages of an integral administration of residues, which include the separation in the source, the gathering, the handling, the use, treatment, final disposition and the institutional organization of the administration. The topic of the dangerous residues generates more expectation. These residues understand from those of pathogen type that are generated in the establishments of health that of hospital attention, until those of combustible, inflammable type, explosive, radio-active, volatile, corrosive, reagent or toxic, associated to numerous industrial processes, common in our countries in development

  10. The heavy quark expansion of QCD

    Energy Technology Data Exchange (ETDEWEB)

    Falk, A.F. [Johns Hopkins Univ., Baltimore, MD (United States). Dept. of Physics and Astronomy

    1997-06-01

    These lectures contain an elementary introduction to heavy quark symmetry and the heavy quark expansion. Applications such as the expansion of heavy meson decay constants and the treatment of inclusive and exclusive semileptonic B decays are included. Heavy hadron production via nonperturbative fragmentation processes is also discussed. 54 refs., 7 figs.

  11. The heavy quark expansion of QCD

    International Nuclear Information System (INIS)

    Falk, A.F.

    1997-01-01

    These lectures contain an elementary introduction to heavy quark symmetry and the heavy quark expansion. Applications such as the expansion of heavy meson decay constants and the treatment of inclusive and exclusive semileptonic B decays are included. Heavy hadron production via nonperturbative fragmentation processes is also discussed. 54 refs., 7 figs

  12. Isotopic-tracer-aided studies on undesirable effects of heavy metals in the soil-plant system. Part of a coordinated programme on isotopic-tracer-aided studies of agrochemical residue - soil biota interactions

    International Nuclear Information System (INIS)

    Oberlaender, H.E.

    1982-07-01

    Uptake of isotopically labelled mercury (Hg-203), cadmium (Cd-115m) and zinc (Zn-65) from a calcareous chernozem and a podzolized brown earth by spring and winter varieties of wheat, rye and barley was investigated in pot experiments carried out until maturity of the plants. The labelled heavy metals, applied at concentrations innocuous to plant growth (0.5 ppm Hg or Cd, 50 ppm Zn) were determined radiometrically in the straw and in the grains of the harvested plants, as well as in the milling products (bran, semolina and flour) obtained by standard procedures of grain processing. Uptake of mercury was several hundred times smaller than the uptake of cadmium, if both metals were applied to the soil in equal amounts. Whereas the uptake of mercury from the acid soil was insignificant or not detectable, cadmium was taken up from this soil at a much higher rate than from the alkaline soil. Thus, not mercury, but cadmium imposes the greatest hazard on the food chain. Winter varieties of cereals took up more mercury and cadmium than did spring varieties. The content of heavy metals in the plants decreased considerably when plants approached maturity. During translocation through the plants the metals were gradually retained when passing from the stalks (''straw'') into the grains, and from the seed-cover (''bran'') into the endosperm (''flour''). The heavy metal contents of the grain fractions decreased in the order: bran > semolina > flour. Concentrations of heavy metals in flour were 3-8 times smaller than in straw, showing that flour is least affected by heavy metal pollution of cereals via the soil. The metal content of the various flour types was correlated with their percentage of bran and with their ash content. By adding an ion-exchanger to the soil the pattern of relative distribution of heavy metals in mature plants was not changed, but the cadmium content of all cereal products was considerably lowered

  13. Residual risk

    African Journals Online (AJOL)

    ing the residual risk of transmission of HIV by blood transfusion. An epidemiological approach assumed that all HIV infections detected serologically in first-time donors were pre-existing or prevalent infections, and that all infections detected in repeat blood donors were new or incident infections. During 1986 - 1987,0,012%.

  14. Migration and speciation of heavy metal in salinized mine tailings affected by iron mining.

    Science.gov (United States)

    Zhang, Xu; Yang, Huanhuan; Cui, Zhaojie

    2017-10-01

    The negative effects of heavy metals have aroused much attention due to their high toxicity to human beings. Migration and transformation trend of heavy metals have a close relationship with soil safety. Researching on migration and transformation of heavy metals in tailings can provide a reliable basis for pollution management and ecosystem restoration. Heavy metal speciation plays an important role in risk assessment. We chose Anshan tailings for our study, including field investigations and laboratory research. Four typical heavy metal elements of mine tailings {Fe (373.89 g/kg), Mn (2,303.80 mg/kg), Pb (40.99 mg/kg) and Cr (199.92 mg/kg)} were studied via Tessier test in vertical and horizontal direction. The main speciation of heavy metals in Anshan tailings was the residual. However, heavy metals have a strong ability for migration and transformation in vertical and horizontal directions. Its tendency to change from stable to unstable speciation results in increasing bioavailability and potential bioavailability. Fe, Mn, Pb and Cr showed different ability in the migration and transformation process (Mn > Pb > Fe > Cr) depending on the characteristics of heavy metals and physicochemical properties of the environment.

  15. Identification of hardly biodegradable residuals (sulfur- and nitrogen-containing substances) during waste water treatment, including the development of analytical methods; Identifizierung von schwer abbaubaren Reststoffen (stickstoff- und schwefelhaltigen Verbindungen) bei der Abwasserbehandlung, einschliesslich analytischer Methodenentwicklung

    Energy Technology Data Exchange (ETDEWEB)

    Moehle, E.; Huber, A.; Metzger, J.W.

    1999-07-01

    Organic residuals in sewage, which are not removed completely by waste water treatment may be relevant in environmental toxicology and may disturb drinking water treatment processes. The organic residuals must be identified before new techniques to eliminate these substances from waste water can be developed and steps can be taken to prevent them from polluting waste waters. In the research project sum parameters of sulfur- and nitrogen-containing substances in municipal waste water were determined. A new method was developed to determine the organic sulfur in compounds absorbed on activated carbon (AOS). The determination of dissolved organic nitrogen (DON) was calculated as the difference between total nitrogen and the sum of NH{sub 4}{sup +}-N, NO{sub 3}{sup -}-N and NO{sub 2}{sup -}N. The removal of organic substances from the inorganic matrix was only possible for standard solutions, but not for real samples. More than 60 substances contributing to the sum parameters could be identified with GC-MS and GC-AED, an most of them could be quantified. 30-70% of the sulfur-containing substances detected with GC-AED could be identified. With the GC-MS screening method 21 drugs or drug metabolites could be identified and partly quantified. Hydrophilic organic residuals were identified and quantified with high performance liquid chromatography coupled with UV- and fluorescence detectors and also with a mass detector (ESI-MS-MS). With the methods described only a small percentage of the sum of AOS and DON could be detected, although new materials for the solid phase enrichment and new analytical methods, such as HPLC-MS-MS were used. In order to get information about the degree of elimination (absorption or degradation) of different drugs in a municipal sewage plant, laboratory-scale tests under aerobic conditions were performed. A batch reactor containing drugs in environmentally relevant concentrations and a suspension of activated sludge was coupled online with HPLC

  16. Heavy metals, salts and organic residues in solid urban waste landfills and surface waters in their discharge areas: determinants for restoring their discharge areas: determinants for restoring their impact

    International Nuclear Information System (INIS)

    Hernandez, A. J.; Pastor, J.

    2009-01-01

    This report describes a continuous assessment of the impact of solid urban waste (SUW) landfills in the central Iberian Peninsula that were sealed with a layer of soil 20 years ago. cover soils and soils from discharge areas have been periodically analysed. Soil concentrations of salts and heavy metals affect the biotic components of these ecosystems. (Author)

  17. Heavy-heavy and heavy-light quarks interactions generated by QCD vacuum

    Directory of Open Access Journals (Sweden)

    Musakhanov Mirzayusuf

    2017-01-01

    Full Text Available The QCD vacuum is populated by instantons that correspond to the tunneling processes in the vacuum. This mechanism creates the strong vacuum gluon fields. As result, the QCD vacuum instantons induce very strong interactions between light quarks, initially almost massless. Such a strong interactions bring a large dynamical mass M of the light quarks and bound them to produce almost massless pions in accordance with the spontaneous breaking of the chiral symmetry (SBCS. On the other hand, the QCD vacuum instantons also interact with heavy quarks and responsible for the generation of the heavy-heavy and heavy-light quarks interactions, with a traces of the SBCS. If we take the average instanton size ρ¯=0.33$\\bar \\rho = 0.33$ fm, and the average inter-instanton distance R¯=1$\\bar R = 1$ fm we obtain the dynamical light quark mass to be M = 365 MeV and the instanton media contribution to the heavy quark mass ΔM=70 MeV. These factors define the coupling between heavy-light and heavy-heavy quarks induced by the QCD vacuum instantons. We consider first the instanton effects on the heavy-heavy quarks potential, including its spin-dependent part. We also discuss those effects on the masses of the charmonia and their hyperfine mass splittings. At the second part we discuss the interaction between a heavy and light quarks generated by instantons and it’s effects.

  18. Analysis of heavy oils: Method development and application to Cerro Negro heavy petroleum

    Energy Technology Data Exchange (ETDEWEB)

    Carbognani, L.; Hazos, M.; Sanchez, V. (INTEVEP, Filial de Petroleos de Venezuela, SA, Caracas (Venezuela)); Green, J.A.; Green, J.B.; Grigsby, R.D.; Pearson, C.D.; Reynolds, J.W.; Shay, J.Y.; Sturm, G.P. Jr.; Thomson, J.S.; Vogh, J.W.; Vrana, R.P.; Yu, S.K.T.; Diehl, B.H.; Grizzle, P.L.; Hirsch, D.E; Hornung, K.W.; Tang, S.Y.

    1989-12-01

    On March 6, 1980, the US Department of Energy (DOE) and the Ministry of Energy and Mines of Venezuela (MEMV) entered into a joint agreement which included analysis of heavy crude oils from the Venezuelan Orinoco oil belt.The purpose of this report is to present compositional data and describe new analytical methods obtained from work on the Cerro Negro Orinoco belt crude oil since 1980. Most of the chapters focus on the methods rather than the resulting data on Cerro Negro oil, and results from other oils obtained during the verification of the method are included. In addition, published work on analysis of heavy oils, tar sand bitumens, and like materials is reviewed, and the overall state of the art in analytical methodology for heavy fossil liquids is assessed. The various phases of the work included: distillation and determination of routine'' physical/chemical properties (Chapter 1); preliminary separation of >200{degree}C distillates and the residue into acid, base, neutral, saturated hydrocarbon and neutral-aromatic concentrates (Chapter 2); further separation of acid, base, and neutral concentrates into subtypes (Chapters 3-5); and determination of the distribution of metal-containing compounds in all fractions (Chapter 6).

  19. Assessment of heavy metals leaching from (biochar obtained from industrial sewage sludge

    Directory of Open Access Journals (Sweden)

    Julija Pečkytė

    2015-10-01

    Full Text Available Biochar can be produced from many various feedstock including biomass residues such as straw, branches, sawdust and other agricultural and forestry waste. One of the alternatives is to obtain biochar from industrial sewage sludge, however, the use of such a product could be limited due to high quantities of heavy metals in the biochar as a product. Total concentration of heavy metals provides only limited information on the behavior of heavy metals, therefore, batch leaching and up-flow percolation leaching tests were applied to study the leaching of heavy metals (Cd, Pb, Cr, Ni, Zn, Cu from (biochar produced from two types of sewage sludge: from paper mill and leather industries.

  20. Residual basins

    International Nuclear Information System (INIS)

    D'Elboux, C.V.; Paiva, I.B.

    1980-01-01

    Exploration for uranium carried out over a major portion of the Rio Grande do Sul Shield has revealed a number of small residual basins developed along glacially eroded channels of pre-Permian age. Mineralization of uranium occurs in two distinct sedimentary units. The lower unit consists of rhythmites overlain by a sequence of black shales, siltstones and coal seams, while the upper one is dominated by sandstones of probable fluvial origin. (Author) [pt

  1. Swift Heavy Ions in Matter

    International Nuclear Information System (INIS)

    1989-01-01

    The 1989 Symposium on Swift Heavy Ions in Matter is reported. The aim of the symposium is to evidence another aspect of heavy ions research at the interplay between atomic and solid state physics. The scope of the Symposium includes the fundamental aspects of heavy ion excitation, ionization, charge exchange, energy loss, energy dissipation and relaxation in solids, channeling and coherent effects in crystals and ion induced modifications of materials

  2. Monitoring the extraction of additives and additive degradation products from polymer packaging into solutions by multi-residue method including solid phase extraction and ultra-high performance liquid chromatography-tandem mass spectrometry analysis.

    Science.gov (United States)

    Pouech, Charlène; Lafay, Florent; Wiest, Laure; Baudot, Robert; Léonard, Didier; Cren-Olivé, Cécile

    2014-02-01

    The use of polymer materials in industry for product packaging is increasing. The presence of additives in the polymer matrix enables the modification or improvement of the properties and performance of the polymer, but these industries are concerned regarding the extractability of these additives. The quantification of these additives is particularly challenging because of the presence of these substances as contaminants in all the analytical equipment and the diversity of their physicochemical properties. In this context, a multi-residue analytical method was developed for the trace analysis of the twenty main additives (and their degradation products) authorized in plastic products such as pharmaceutical packaging (e.g., antioxidants, release agents, and light absorbers). This analytical method consisted of a solid phase extraction (SPE) followed by an analysis using ultra-high performance liquid chromatography coupled to a tandem mass spectrometer (UHPLC-MS/MS). A comparison of two ionization interfaces and the optimization of the extraction procedure were discussed. The influence of the quality of the solvent type (distilled versus not distilled) and the nature of the SPE cartridges (Polypropylene versus Teflon(®)) were demonstrated. The optimized method exhibited a quantification limit lower than 20 ng mL(-1) and recoveries between 70 % and 120 % for all compounds. Finally, the method was validated according to the ICH directive and was subsequently applied to the extraction of polymers under different pH conditions and storage temperatures. To the best of our knowledge, this study presents the first methodology allowing the simultaneous quantification of 24 additives at low ng mL(-1).

  3. Management of NORM Residues

    International Nuclear Information System (INIS)

    2013-06-01

    The IAEA attaches great importance to the dissemination of information that can assist Member States in the development, implementation, maintenance and continuous improvement of systems, programmes and activities that support the nuclear fuel cycle and nuclear applications, and that address the legacy of past practices and accidents. However, radioactive residues are found not only in nuclear fuel cycle activities, but also in a range of other industrial activities, including: - Mining and milling of metalliferous and non-metallic ores; - Production of non-nuclear fuels, including coal, oil and gas; - Extraction and purification of water (e.g. in the generation of geothermal energy, as drinking and industrial process water; in paper and pulp manufacturing processes); - Production of industrial minerals, including phosphate, clay and building materials; - Use of radionuclides, such as thorium, for properties other than their radioactivity. Naturally occurring radioactive material (NORM) may lead to exposures at some stage of these processes and in the use or reuse of products, residues or wastes. Several IAEA publications address NORM issues with a special focus on some of the more relevant industrial operations. This publication attempts to provide guidance on managing residues arising from different NORM type industries, and on pertinent residue management strategies and technologies, to help Member States gain perspectives on the management of NORM residues

  4. Alternatives to crop residues for soil amendment

    OpenAIRE

    Powell, J.M.; Unger, P.W.

    1997-01-01

    Metadata only record In semiarid agroecosystems, crop residues can provide important benefits of soil and water conservation, nutrient cycling, and improved subsequent crop yields. However, there are frequently multiple competing uses for residues, including animal forage, fuel, and construction material. This chapter discusses the various uses of crop residues and examines alternative soil amendments when crop residues cannot be left on the soil.

  5. Fracture mechanics evaluation of heavy welded structures

    International Nuclear Information System (INIS)

    Sprung, I.; Ericksson, C.W.; Zilberstein, V.A.

    1982-01-01

    This paper describes some applications of nondestructive examination (NDE) and engineering fracture mechanics to evaluation of flaws in heavy welded structures. The paper discusses not only widely recognized linear elastic fracture mechanics (LEFM) analysis, but also methods of the elastic-plastic fracture mechanics (EPFM), such as COD, J-integral, and Failure Assessment Diagram. Examples are given to highlight the importance of interaction between specialists providing input and the specialists performing the analysis. The paper points out that the critical parameters for as-welded structures when calculated by these methods are conservative since they are based on two pessimistic assumptions: that the magnitude of residual stress is always at the yield strength level, and that the residual stress always acts in the same direction as the applied (mechanical) stress. The suggestion is made that it would be prudent to use the COD or the FAD design curves for a conservative design. The appendix examines a J-design curve modified to include residual stresses

  6. PHENIX recent heavy flavor results

    Energy Technology Data Exchange (ETDEWEB)

    Lim, Sanghoon

    2014-06-15

    Cold nuclear matter (CNM) effects provide an important ingredient to interpret the results from heavy-ion collisions. Such effects include nuclear shadowing, intrinsic parton transverse momentum broadening, and initial patron energy loss. The measurement of heavy quark production is a good probe to study the CNM effects particularly on gluons, since heavy quarks are mainly produced via gluon fusions at RHIC energy. The PHENIX experiment has an ability to study the CNM effects by measuring leptons from heavy-flavor decay in a broad kinematic range. Comparisons of the results measured in different rapidity regions allow us to study modification of gluon density function in the Au nucleus depending on parton fractional momentum x. In addition, comparisons to the results from heavy-ion collisions (Au + Au and Cu + Cu) measured by PHENIX provide an insight into the role of CNM effects in such collisions. Recent PHENIX results on heavy quark production are discussed in this presentation.

  7. Hydrocracking of atmospheric distillable residue of Mongolian oil

    Directory of Open Access Journals (Sweden)

    Ts Tugsuu

    2014-09-01

    Full Text Available Many catalytic processes to refine heavy part of crude oil have attracted much interest due to declining reserves of light crude oils. This study focused on hydrocracking process of atmospheric distillable residue of Mongolian crude oil in the first time compared to those of other countries. Residue samples were hydrocracked with a commercial catalyst at 450°C, 460°C, 470°C for 2 h under hydrogen pressure of 10 MPa. The amount of residual fraction (350°Cresidue from Tamsagbulag crude oil. When the ME-AR was hydrocracked, the high consumption of hydrogen was related to the lowest H/C atomic ratio of feed atmospheric residue. The amount of liquid fractions (BP<350°C including gaseous products increased from 45.4wt% to 89.2wt%, when the reaction temperature increased from 450°C to 470°C. The highest yield of the middle fraction for each sample was observed at temperature of 460°C. On the other hand, the effect of temperature on the yield of middle fraction was not so high as compared with the yields of other fractions. The contents of n-paraffins on midlle and heavy fractions of TB-AR, DQ-AR were similar, but ME-AR’s was around 2 times lower than other after hydrocracking runs.DOI: http://dx.doi.org/10.5564/mjc.v12i0.166 Mongolian Journal of Chemistry Vol.12 2011: 24-28 

  8. Phenomenology of heavy leptons and heavy quarks

    International Nuclear Information System (INIS)

    Gilman, F.J.

    1978-11-01

    The review of the quark and lepton family includes properties of the tau, SU(2) x U(1) classification of the tau and its decays, heavier leptons, the spectroscopy of heavy hadrons composed of quarks, their strong and electromagnetic decays, the weak interaction properties of the c, b, and t quarks, and the decays of hadrons containing them expected within the context of the standard SU(2) x U(1) model. 76 references

  9. Heavy fermion and actinide materials

    International Nuclear Information System (INIS)

    1993-01-01

    During this period, 1/N expansions have been systematically applied to the calculation of the properties of highly correlated electron systems. These studies include examinations of (a) the class of materials known as heavy fermion semi-conductors, (b) the high energy spectra of heavy fermion systems, and (c) the doped oxide superconductors

  10. RESIDUAL RISK ASSESSMENTS - RESIDUAL RISK ...

    Science.gov (United States)

    This source category previously subjected to a technology-based standard will be examined to determine if health or ecological risks are significant enough to warrant further regulation for Coke Ovens. These assesments utilize existing models and data bases to examine the multi-media and multi-pollutant impacts of air toxics emissions on human health and the environment. Details on the assessment process and methodologies can be found in EPA's Residual Risk Report to Congress issued in March of 1999 (see web site). To assess the health risks imposed by air toxics emissions from Coke Ovens to determine if control technology standards previously established are adequately protecting public health.

  11. Electroremediation of air pollution control residues in a continuous reactor

    DEFF Research Database (Denmark)

    Jensen, Pernille Erland; Ferreira, Célia M. D.; Hansen, Henrik K.

    2010-01-01

    Air pollution control (APC) residue from municipal solid waste incineration is considered hazardous waste due to its alkalinity and high content of salts and mobile heavy metals. Various solutions for the handling of APC-residue exist, however most commercial solutions involve landfilling. A demand...... for environmental sustainable alternatives exists and electrodialysis could be such an alternative. The potential of electrodialysis for treating APC-residue is explored in this work by designing and testing a continuous-flow bench-scale reactor that can work with a high solids content feed solution. Experiments...... were made with raw residue, water-washed residue, acid washed residue and acid-treated residue with emphasis on reduction of heavy metal mobility. Main results indicate that the reactor successfully removes toxic elements lead, copper, cadmium and zinc from the feed stream, suggesting...

  12. Heavy ions

    CERN Multimedia

    CERN. Geneva. Audiovisual Unit

    2002-01-01

    Colliding two heavy nuclei at ultrarelativistic energies allows to create in the laboratory a bulk system with huge density, pressure and temperature and to study its properties. It is estimated that in Pb-Pb collisions at CERN-SPS we reach over an appreciable volume an energy density which exceeds by more than a factor 20 that of normal nuclear matter. At such densities, the hadrons are so closely packed that they interpenetrate; novel physics phenomena are expected to appear. QCD predicts that under such conditions a phase transition from a system composed of colourless hadrons to a Quark-Gluon Plasma (QGP) should occur. A rich ultrarelativistic heavy-ion physics programme is under way both at BNL-AGS and at CERN-SPS since 1986. The results obtained so far have led CERN to officially announce evidence for a new state of matter last year. A long-range programme of heavy-ion physics at higher energies is under way (BNL-RHIC) and in preparation (CERN-LHC). These lectures are meant as an introduction to the phy...

  13. Heavy ions

    CERN Multimedia

    CERN. Geneva; Antinori, Federico

    2001-01-01

    Colliding two heavy nuclei at ultrarelativistic energies allows to create in the laboratory a bulk system with huge density, pressure and temperature and to study its properties. It is estimated that in Pb-Pb collisions at CERN-SPS we reach over an appreciable volume an energy density which exceeds by more than a factor 20 that of normal nuclear matter. At such densities, the hadrons are so closely packed that they interpenetrate; novel physics phenomena are expected to appear. QCD predicts that under such conditions a phase transition from a system composed of colourless hadrons to a Quark-Gluon Plasma (QGP) should occur. A rich ultrarelativistic heavy-ion physics programme is under way both at BNL-AGS and at CERN-SPS since 1986. The results obtained so far have led CERN to officially announce evidence for a new state of matter last year. A long-range programme of heavy-ion physics at higher energies is under way (BNL-RHIC) and in preparation (CERN-LHC). These lectures are meant as an introduction to the phy...

  14. Chlorpyrifos residual behaviors in field crops and transfers during duck pellet feed processing.

    Science.gov (United States)

    Li, Rui; Wei, Wei; He, Liang; Hao, Lili; Ji, Xiaofeng; Zhou, Yu; Wang, Qiang

    2014-10-22

    Chlorpyrifos is a widely used organophosphorus pesticide in agricultural crops (including food) and animal feeds in China, resulting in heavy contamination. Many studies have focused on the food-processing effects on chlorpyrifos removal, but sufficient information is not observed for feed-processing steps. Here, chlorpyrifos residual behaviors in field crops and its transfers in duck pellet feed-processing steps were evaluated. In field trials, the highest residues for rice grain, shelled corn, and soybean seed were 12.0, 0.605, and 0.220 mg/kg, respectively. Residues of all rice grain and about half of shelled corn exceeded the maximum residue limits (MRLs) of China, and five soybean seeds exceeded the MRL of China. Chlorpyrifos residue was reduced 38.2% in brown rice after the raw rice grain was hulled. The residue in bran increased 71.2% after milling from brown rice. During the squashing step, the residue reduced 73.8% in soybean meal. The residues reduced significantly (23.7-36.8%) during the process of granulating for rice, maize, and soybean products. Comparatively, the grinding process showed only limited influence on chlorpyrifos removal (residues of duck pellet feeds produced from highly contaminated raw materials of this study were 1.01 mg/kg (maize-soybean feed) and 3.20 mg/kg (rice-soybean feed), which were much higher than the generally accepted value (>0.1 mg/kg) for animal feeding. Chlorpyrifos residues were removed significantly by processing steps of pellet feeds, but the residue of raw materials was the determining factor for the safety of duck feeding.

  15. Residual nilpotence and residual solubility of groups

    International Nuclear Information System (INIS)

    Mikhailov, R V

    2005-01-01

    The properties of the residual nilpotence and the residual solubility of groups are studied. The main objects under investigation are the class of residually nilpotent groups such that each central extension of these groups is also residually nilpotent and the class of residually soluble groups such that each Abelian extension of these groups is residually soluble. Various examples of groups not belonging to these classes are constructed by homological methods and methods of the theory of modules over group rings. Several applications of the theory under consideration are presented and problems concerning the residual nilpotence of one-relator groups are considered.

  16. Modélisation de la combustion de fuels lourds prenant en compte la dispersion des asphaltènes Modeling Heavy Fuel-Oil Combustion (While Considering Or Including Asphaltene Dispersion

    Directory of Open Access Journals (Sweden)

    Audibert F.

    2006-11-01

    difficultés relevant du mode d'exploration et de la non adéquation entre les structures asphalténiques et fractales. On a finalement opté pour une détermination visuelle s'appuyant sur les clichés sur lesquels les agglomérats d'asphaltènes sont clairement visualisés tels qu'ils sont dans le fuel. Ce mode d'exploration laborieux a cependant permis de déterminer un modèle construit sur une série de 25 fuels dont 10 ont été brûlés sur une chaudière de 2 MW, et 15 sur un four de 100 kW. Ce modèle fait intervenir les teneurs en carbone Conradson et en métaux, ainsi que le taux de dispersion des asphaltènes. Le perfectionnement des moyens d'exploration aidant, on peut s'attendre à ce que soient disponibles des techniques d'évaluation de la dispersion sur les clichés. Ce paramètre pourra alors être pris en considération pour une meilleure prédiction de résultats de combustion insuffisamment expliqués avec les paramètres classiques. Various models aiming to predict the amount of unburned particles (solids during heavy fuel-oil combustion have been developed. The parameters taken into consideration are generally asphaltenes precipitated by normal heptane or pentane and Conradson carbon as well as the metals content having a known catalytic effect on cenosphere combustion in the combustion chamber. The Exxon and Shell models can be mentioned, which were developed respectively in 1979 and 1981 (Chapter II. Other models also give consideration to the fuel-oil composition, the way it is atomized and diffused in the chamber and the combustion kinetics (research done by the MIT Energy Laboratory published in 1986. However, the above parameters are not the only ones involved. For some fuel oils, experience has shown that the state of dispersion of asphaltenes may also play an important role particularly for combustion installations with mechanical injection for which the dispersion of fuel-oil droplets is not very great and does not affect the structures built

  17. Experimental heavy quarkonium physics

    International Nuclear Information System (INIS)

    Bugge, L.

    1986-08-01

    Following some brief arguments on why heavy quarkonium spectroscopy is an important field of particle physics, some points on experimental techniques are discussed. Parts of the basic quarkonium phenomenology, including discussions of various items related to potensial models, are then presented. An up-to-date presentation is given of the state-of-the-art of experimental charmonium and bottomonium spectroscopy below open flavour threshold, including the confrontation of experimental results to representative theoretical predictions

  18. MICROBIAL REMOVAL OF HEAVY METALS FROM WASTEWATER

    Directory of Open Access Journals (Sweden)

    Justyna Koc-Jurczyk

    2014-10-01

    Full Text Available Industrialization and urbanization result in increase of heavy metals released into the environment (soil, lakes, rivers, seas, oceans, groundwater. Studies on biosorption of heavy metals are aimed to specify types of microorganisms which could efficiently bind metals. This approach has a very important significance for both slowing down metals exploitation by recovery, and also reduction of environmental pollution by decrease of their excessive concentration. Recent studies have reported about the capabilities of fungi, algae, yeasts, bacteria, waste and agricultural residues or materials containing chitosan derived from crustacean shells as a biosorbents. Biohydrometallurgy could be considered as a new “green” technology of heavy metals removal from wastewater.

  19. Statistical inference on residual life

    CERN Document Server

    Jeong, Jong-Hyeon

    2014-01-01

    This is a monograph on the concept of residual life, which is an alternative summary measure of time-to-event data, or survival data. The mean residual life has been used for many years under the name of life expectancy, so it is a natural concept for summarizing survival or reliability data. It is also more interpretable than the popular hazard function, especially for communications between patients and physicians regarding the efficacy of a new drug in the medical field. This book reviews existing statistical methods to infer the residual life distribution. The review and comparison includes existing inference methods for mean and median, or quantile, residual life analysis through medical data examples. The concept of the residual life is also extended to competing risks analysis. The targeted audience includes biostatisticians, graduate students, and PhD (bio)statisticians. Knowledge in survival analysis at an introductory graduate level is advisable prior to reading this book.

  20. Thermally induced transformations of iron oxide stabilised APC residues from waste incineration

    DEFF Research Database (Denmark)

    Sørensen, Mette Abildgaard; Koch, C.B.

    2001-01-01

    Air pollution control (APC) facilities at waste incinerator plants produce large quantities of solid residues rich in salts and heavy metals. Heavy metals are readily released to water from the residues and it has, therefore, been found suitable to apply a rapid co-precipitation/adsorption process...

  1. Composition of carbonization residues

    Energy Technology Data Exchange (ETDEWEB)

    Hupfer; Leonhardt

    1943-11-27

    This report compared the composition of samples from Wesseling and Leuna. In each case the sample was a residue from carbonization of the residues from hydrogenation of the brown coal processed at the plant. The composition was given in terms of volatile components, fixed carbon, ash, water, carbon, hydrogen, oxygen, nitrogen, volatile sulfur, and total sulfur. The result of carbonization was given in terms of (ash and) coke, tar, water, gas and losses, and bitumen. The composition of the ash was given in terms of silicon dioxide, ferric oxide, aluminum oxide, calcium oxide, magnesium oxide, potassium and sodium oxides, sulfur trioxide, phosphorus pentoxide, chlorine, and titanium oxide. The most important difference between the properties of the two samples was that the residue from Wesseling only contained 4% oil, whereas that from Leuna had about 26% oil. Taking into account the total amount of residue processed yearly, the report noted that better carbonization at Leuna could save 20,000 metric tons/year of oil. Some other comparisons of data included about 33% volatiles at Leuna vs. about 22% at Wesseling, about 5 1/2% sulfur at Leuna vs. about 6 1/2% at Leuna, but about 57% ash for both. Composition of the ash differed quite a bit between the two. 1 table.

  2. Residual stress analysis: a review

    International Nuclear Information System (INIS)

    Finlayson, T.R.

    1983-01-01

    The techniques which are or could be employed to measure residual stresses are outlined. They include X-ray and neutron diffraction. Comments are made on the reliability and accuracy to be expected from particular techniques

  3. Mercury and other heavy metal toxicity and mitocheondral dysfunction. Part of a coordinated programme of isotopic tracer-aided studies of the biological side-effects of foreign chemical residues in food and agriculture

    International Nuclear Information System (INIS)

    Nitisewojo, P.

    1977-12-01

    Mercury and other heavy metal toxicity and mitochondrial dysfunction: kidney mitochondria isolated from Hg-poisoned rats (4mgHg ++ /kgb.wt.,i.v.) exhibited a considerable loss of capacity for oxidative phosphorylation, apparently related to Mg ++ depletion and inhibition of ATP synthesis. Liver mitochondria remained unaffected. It is maintained that acute Hg poisoning is related to kidney failure. Selenium was found to provide protection as ascertained by partial restoration of the kidney mitochondrial oxidative phosphorylation and prolongation of time of death of the poisoned animals. In contrast to Hg, acute Cd-poisoning in rats (4mgCd ++ /kg,b.wt.,i.v.) is probably related to liver failure, where hepatic mitochondria loses its capacity for oxidative phosphorylation, through the same mechanism postulated for kiney mitochondria isolated from Hg-poisoned rats. Again, selenium provided a similar protective effect. That Hg and Cd have two different target organs may be ascribed to the relative distribution of both elements in the animal body. Preliminary data in the rabbit showed that Cd caused an increase of heart beat as well as an increased difference between systolic and diastolic pressures. Studies on Pb-poisoned rats, using 2,4-Dinitrophenol as uncoupling agent in mitochondria, suggested inhibition of the electron transport chain

  4. Study on Colloidal Model of Petroleum Residues through the Attraction Potential between Colloids

    Directory of Open Access Journals (Sweden)

    Long-li Zhang

    2016-01-01

    Full Text Available The samples of DaGang atmospheric residue (DG-AR, Middle East atmospheric residue (ME-AR, TaHe atmospheric residue (TH-AR, and their thermal reaction samples were chosen for study. All the samples were fractioned into six components separately, including saturates plus light aromatics, heavy aromatics, light resins, middle resins, heavy resins, and asphaltenes. The dielectric permittivity of the solutions of these components was measured, and the dielectric permittivity values of the components can be determined by extrapolation, which increased steadily from saturates plus light aromatics to asphaltenes. Moreover, the Hamaker constants of the components were calculated from their dielectric permittivity values. The Van der Waals attractive potential energy between colloids corresponding to various models could be calculated from the fractional composition and the Hamaker constants of every component. It was assumed that the cores of colloidal particles were formed by asphaltenes and heavy resins mainly; the other fractions acted as dispersion medium. For the three serials of thermal reaction samples, the Van der Waals attraction potential energy between colloids for this kind of model was calculated. For TH-AR thermal reaction samples, the Van der Waals attraction potential energy presented the maximum as thermal reaction is going on, which was near to the end of coke induction period.

  5. Gold processing residue from Jacobina Basin: chemical and physical properties

    OpenAIRE

    Lima, Luiz Rogério Pinho de Andrade; Bernardez, Letícia Alonso; Barbosa, Luís Alberto Dantas

    2007-01-01

    p. 848-852 Gold processing residues or tailings are found in several areas in the Itapicuru River region (Bahia, Brazil), and previous studies indicated significant heavy metals content in the river sediments. The present work focused on an artisanal gold processing residue found in a site from this region. Samples were taken from the processing residue heaps and used to perform a physical and chemical characterization study using X-ray diffraction, scanning electron microscopy, neutron...

  6. Stabilization of heavy metals in fired clay brick incorporated with wastewater treatment plant sludge: Leaching analysis

    Science.gov (United States)

    Kadir, A. A.; Hassan, M. I. H.; Salim, N. S. A.; Sarani, N. A.; Ahmad, S.; Rahmat, N. A. I.

    2018-04-01

    Wastewater treatment sludge or known as sewage sludge is regarded as the residue and produced by the sedimentation of the suspended solid during treatment at the wastewater treatment plant. As such, this sludge was gained from the separation process of the liquids and solids. This sludge wastes has becomes national issues in recent years due to the increasing amount caused by population and industrialization growth in Malaysia. This research was conducted to fully utilize the sludge that rich in dangerous heavy metals and at the same time act as low cost alternative materials in brick manufacturing. The investigation includes determination of heavy metal concentration and chemical composition of the sludge, physical and mechanical properties. Wastewater treatment sludge samples were collected from wastewater treatment plant located in Johor, Malaysia. X-Ray Fluorescence was conducted to determine the heavy metals concentration of wastewater treatment sludge. Different percentage of sludges which are 0%, 1%, 5%, 10%, and 20%, has been incorporated into fired clay brick. The leachability of heavy metals in fired clay brick that incorporated with sludge were determined by using Toxicity Characteristic Leaching Procedure (TCLP) and Synthetic Precipitation Leachability Procedure (SPLP) that has been analyzed by using Inductively Coupled Plasma Mass Spectrometry (ICP-MS). The results show a possibility to stabilize the heavy metals in fired clay brick incorporated with wastewater treatment sludge. 20% of the sludge incorporated into the brick is the most suitable for building materials as it leached less heavy metals concentration and complying with USEPA standard.

  7. Neutrinos: Heavy water detector

    International Nuclear Information System (INIS)

    Anon.

    1990-01-01

    The proponents of the Sudbury Neutrino Observatory (SNO) received a welcome Christmas present when William Winegard, Canadian Minister for Science and Technology announced the final details of the funding for this project, totalling 48 million Canadian dollars and including contributions from the US and the UK. The SNO experiment will extend significantly the study of solar neutrinos, using some 1,000 tonnes of heavy water to be installed more than two kilometres below ground in a nickel mine at Sudbury, Ontario

  8. THERMAL STABILITY OF SYNTHETIC PEPTIDES MIMICKING THE SEQUENCE OF THE REGION CONTAINING THE SKIP RESIDUES IN SQUID MYOSIN ROD

    Directory of Open Access Journals (Sweden)

    Yoshihiro Ochiai

    2017-08-01

    Full Text Available Myosin is the major protein in skeletal muscles including those of fish and shellfish. The characteristics of this protein are closely related to the biological function and the quality and physical properties of musclefood. In the myosin rod (the coiled-coil region of myosin, several amino acid residues, known as skip residues, seem to destabilize the ordered structure (heptad repeat. These residues might be responsible for reducing thermal stability. Attempts were thus made to examine the role of these residues in the rod of squid myosin, based on the thermodynamic properties of synthetic peptides which have been designed to mimic the partial sequence of myosin heavy chain from the squid Todarodes pacificus mantle muscle. Five peptides, namely, with the sequence of Trp1343 -Ala1372  having the skip residue Glu1357 at the center (Peptide WT, without the skip residue (Peptide Δ, with the replacements of the skip residue (Glu by Ile, Gln and Pro (Peptides E/I, E/Q, and E/P, respectively to modify the helix forming propensity, were synthesized. The results obtained showed that the stability of the peptides as measured by circular dichroism spectrometry was in the order of Peptide Δ > Peptide WT > Peptide E/Q > Peptide E/P > Peptide E/I. It is suggested that the presence of the skip residues dexterously tunes the stability or flexibility of the coiled-coil structure, thus possibly regulating thick filament formation and further gel formation ability of myosin.

  9. Drying of heavy water system and works of charging heavy water in Fugen

    International Nuclear Information System (INIS)

    Matsushita, Tadashi; Iijima, Setsuo

    1980-01-01

    The advanced thermal reactor ''Fugen'' is the first heavy water-moderated, boiling light water-cooled nuclear reactor for power generation in Japan. It is a large heavy water reactor having about 130 m 3 of heavy water inventory and about 300 m 3 of helium space as the cover gas of the heavy water system. The heavy water required was purchased from FRG, which had been used for the power output test in the KKN, and the quality was 99.82 mol % mean heavy water concentration. The concentration of heavy water for Fugen used for the nuclear design is 99.70 mol%, and it was investigated how heavy water can be charged without lowering the concentration. The matters of investigation include the method of bringing the heavy water and helium system to perfect dryness after washing and light water test, the method of confirming the sufficient dryness to prevent the deterioration, and the method of charging heavy water safely from its containers. On the basis of the results of investigation, the actual works were started. The works of drying the heavy water and helium system by vacuum drying, the works of sampling heavy water and the result of the degree of deterioration, and the works of charging heavy water and the measures to the heavy water remaing in the containers are described. All the works were completed safely and smoothly. (J.P.N.)

  10. Heavy Flavor in heavy ion collisions

    International Nuclear Information System (INIS)

    Ruan, L.J.

    2010-01-01

    The recent results on heavy flavor at the Relativistic Heavy Ion Collider will be reviewed. The results on charm cross section, heavy flavor collectivity and energy loss, color screening effect and quarkonia production mechanism will be highlighted. Precise measurements with future detector upgrades will be discussed.

  11. Phenomenology of heavy quark systems

    International Nuclear Information System (INIS)

    Gilman, F.J.

    1987-03-01

    The spectroscopy of heavy quark systems is examined with regards to spin independent and spin dependent potentials. It is shown that a qualitative picture exists of the spin-independent forces, and that a semi-quantitative understanding exists for the spin-dependent effects. A brief review is then given of the subject of the decays of hadrons containing heavy quarks, including weak decays at the quark level, and describing corrections to the spectator model

  12. Heavy quark physics at HERA

    International Nuclear Information System (INIS)

    Ali, A.

    1992-06-01

    A brief overview of the anticipated heavy quark physics at HERA is given. The topics discussed include heavy quark photo- and leptoproduction cross sections at HERA calculated in the context of perturbative QCD, various mechanisms of J/ψ-leptoproduction and their rates, determination of the gluon density of the proton using open and bound charmed hadrons, and rare D 0 -meson decays. Some selected aspects of B-Physics at HERA are also discussed. (orig.)

  13. Heavy Metal Pollution, Fractionation, and Potential Ecological Risks in Sediments from Lake Chaohu (Eastern China) and the Surrounding Rivers.

    Science.gov (United States)

    Zhang, Lei; Liao, Qianjiahua; Shao, Shiguang; Zhang, Nan; Shen, Qiushi; Liu, Cheng

    2015-11-06

    Heavy metal (Cr, Ni, Cu, Zn, Cd, and Pb) pollution, fractionation, and ecological risks in the sediments of Lake Chaohu (Eastern China), its eleven inflowing rivers and its only outflowing river were studied. An improved BCR (proposed by the European Community Bureau of Reference) sequential extraction procedure was applied to fractionate heavy metals within sediments, a geoaccumulation index was used to assess the extent of heavy metal pollution, and a risk assessment code was applied to evaluate potential ecological risks. Heavy metals in the Shuangqiao and Nanfei Rivers were generally higher than the other studied sites. Of the three Lake Chaohu sites, the highest concentrations were identified in western Chaohu. Heavy metal pollution and ecological risks in the lake's only outflowing river were similar to those in the eastern region of the lake, to which the river is connected. Heavy metal concentrations occurred in the following order: Cd > Zn > Cu > Pb ≈ Ni ≈ Cr. Cr, Ni, and Cu made up the largest proportion of the residual fraction, while Cd was the most prominent metal in the exchangeable and carbonate-included fraction. Cd posed the greatest potential ecological risk; the heavy metals generally posed risks in the following order: Cd > Zn > Cu > Ni > Pb > Cr.

  14. Continuous coking of heavy feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, Douglas W. [Lidcon, Inc (United States)

    2011-07-01

    A new process for continuous coking and decoking has been developed by Lidcon Inc. This process uses bitumen, vacuum tower residues, or a heavy CCR stock. The Lidcon process produces a higher liquid yield and lowers solid coke production. It also reduces the effects on the environment by lowering the amount of utilities that are needed to power the unit, while improving fire and worker safety. The reactor also produces coke continuously. The theoretical advantage of such a reactor configuration is that it has a short high temperature residence time for volatiles while improving the mass transfer of volatiles through the residue. The dimensions of the reactor are approximately 28' long with a 7' diameter. The weight of the unit is 20,000lbs. The Lidcon process can deliver a higher level of efficiency while reducing the amount of coke that is produced.

  15. Heavy metal jako subkultura

    OpenAIRE

    KOUTNÁ, Daniela

    2016-01-01

    This bachelor thesis deals with heavy metal subculture. Its aim is to introduce the most important branches and to show broadness of heavy metal. This bachelor thesis describes development and history, briefly shows Czech heavy metal history alongside with the biggest and most popular Czech heavy metal festivals. It shows the most dressing concerns of society against this style.

  16. Utah Heavy Oil Program

    Energy Technology Data Exchange (ETDEWEB)

    J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

    2009-10-20

    The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

  17. Electrodialytic remediation of air pollution control residues in bench scale

    DEFF Research Database (Denmark)

    Jensen, Pernille Erland; Ferreira, Celia; Hansen, Henrik K.

    2008-01-01

    Air pollution control (APC) residue from municipal solid waste incineration (MSWI) is considered a hazardous waste due to its alkalinity and high content of salts and mobile heavy metals. Various solutions for the handling of APC-residue exist in different regions; however, most commercial...... solutions are concerned with deposition. A demand for more environmentally friendly alternatives exists. Electrodialysis could be such an alternative, and the potential is being explored. This work presents a bench scale study of the feasibility of treating APC-residue from a dry system by electrodialysis....... A system resembling conventional electrodialysis was designed and adjusted to fit the high solids content feed solution (10% APC residue, 90% water). Experiments were made in bench scale with raw residue (natural pH > 12), water pre-residue (natural pH > 12), acid pre-washed residue (pH 10), and acid...

  18. Remediation of deltamethrin contaminated cotton fields: residual and adsorption assessment

    Directory of Open Access Journals (Sweden)

    Rafique Uzaira

    2016-01-01

    Full Text Available Pakistan occupies a significant global position in the growing of high quality cotton. The extensive application of pesticides on agricultural products leads to environmental risk due to toxic residues in air, water and soil. This study examined the chemodynamic effect of Deltamethrin on cotton fields. Samples were collected from the cotton fields of D.G. Khan, Pakistan and analyzed for heavy metal speciation patterns. Batch experiments were administered in order to study the adsorption of Deltamethrin in cotton fields. The effect of different factors including pH, adsorbate dose, and adsorbent mass on adsorption were studied. It was observed that in general, adsorption increased with increases in the mass of adsorbate, although the trends were irregular. Residual fractions of deltamethrin in the soil and water of cotton fields were analyzed to assess concentrations of xenobiotics bound to soil particles. Results indicated that such residues are significantly higher in soil samples due to high Koc in comparison to water, indicating the former is an efficient degradation agent. Results from the batch experiment resulted in 95% removal with alkaline pH and an adsorbent-adsorbate ratio of 250:1. These results may be used to environment friendly resource management policies.

  19. Coreflood assay using extremophile microorganisms for recovery of heavy oil in Mexican oil fields.

    Science.gov (United States)

    Castorena-Cortés, Gladys; Roldán-Carrillo, Teresa; Reyes-Avila, Jesús; Zapata-Peñasco, Icoquih; Mayol-Castillo, Martha; Olguín-Lora, Patricia

    2012-10-01

    A considerable portion of oil reserves in Mexico corresponds to heavy oils. This feature makes it more difficult to recover the remaining oil in the reservoir after extraction with conventional techniques. Microbial enhanced oil recovery (MEOR) has been considered as a promising technique to further increase oil recovery, but its application has been developed mainly with light oils; therefore, more research is required for heavy oil. In this study, the recovery of Mexican heavy oil (11.1°API and viscosity 32,906 mPa s) in a coreflood experiment was evaluated using the extremophile mixed culture A7, which was isolated from a Mexican oil field. Culture A7 includes fermentative, thermophilic, and anaerobic microorganisms. The experiments included waterflooding and MEOR stages, and were carried out under reservoir conditions (70°C and 9.65 MPa). MEOR consisted of injections of nutrients and microorganisms followed by confinement periods. In the MEOR stages, the mixed culture A7 produced surface-active agents (surface tension reduction 27 mN m⁻¹), solvents (ethanol, 1738 mg L⁻¹), acids (693 mg L⁻¹), and gases, and also degraded heavy hydrocarbon fractions in an extreme environment. The interactions of these metabolites with the oil, as well as the bioconversion of heavy oil fractions to lighter fractions (increased alkanes in the C₈-C₃₀ range), were the mechanisms responsible for the mobility and recovery of heavy oil from the porous media. Oil recovery by MEOR was 19.48% of the residual oil in the core after waterflooding. These results show that MEOR is a potential alternative to heavy oil recovery in Mexican oil fields. Copyright © 2012 The Society for Biotechnology, Japan. Published by Elsevier B.V. All rights reserved.

  20. Influence of inoculating white-rot fungi on organic matter transformations and mobility of heavy metals in sewage sludge based composting.

    Science.gov (United States)

    Zhang, Chaosheng; Xu, Ying; Zhao, Meihua; Rong, Hongwei; Zhang, Kefang

    2018-02-15

    White-rot fungi, Phanerochaete chrysosporium was inoculated to sewage sludge composting. Its effect on transformation of organic matter and mobility of heavy metals (Zn, Pb, Cu, and Ni) was studied. Detailed sampling was performed to measure C contents in humic extracts (HE), humic acids (HAs), fulvic acids (FAs), humin and distribution of heavy metals, including acid exchangeable fraction (AE), reducible fraction (RED), oxidization fraction (OXI) and residual fraction (RES). In our study, it is evident that the HE, HAs increased obviously and hydrolyzed humin decreased markedly in inoculation. The stabilization rate ((OXI+RES)/(AE+RED)) of Zn, Pb, Cu, and Ni was 20.31%, 7%, 14.3% and 19.79% higher in inoculating reactor. Additionally, the changes of heavy metals fractions could be explained by the organic variables. The results of this study demonstrated that Phanerochaete chrysosporium passivates the heavy metal by provoking the formation of humus. Copyright © 2017 Elsevier B.V. All rights reserved.

  1. Searches for heavy neutrinos and heavy leptons

    CERN Document Server

    Kim, Jae Sung

    2017-01-01

    The discovery of non-zero neutrino masses has opened a new window for heavy neutrinos at TeV scale. The CMS experiment has performed many searches for heavy neutrinos at the LHC. We present an overview of these heavy neutrino (Majorana type) searches in events with two leptons and two jets or three leptons, using proton-proton collision data recorded by the CMS experiment.

  2. Heavy particle effects

    International Nuclear Information System (INIS)

    Yao, Y.P.

    1981-01-01

    There are two problems discussed, both of which have to do with dissimilar magnitudes in mass. Theoretically, we can devise the large difference in mass as observed by decreeing some vev, v/sub i/ to be much bigger than the other; or, we can assume that some couplings g/sub i/ are much stronger. These two different assumptions give rise to entirely different patterns of interaction in the resulting theory. The first way to generate a mass hierarchy can be called the soft way, because in the zeroth order, the large mass scale leaves its foot print merely in a few effective parameters of the residual theory. The effective theory is renormalizable, sans anomaly. In this limit, the heavy particles decouple. The second assumption (g/sub j/ much greater than g/sub j'/) to create mass hierarchy does a lot of violence to a theory. Effects of the large mass scale will be felt by the system left behind in many ways. An infinite number of parameters are needed to summarize the effects in this limit. This is called the hard limit. It follows that the resulting effective Lagrangian, if in fact it makes sense to construct one at all, will be non-polynomial and apparently non-renormalizable

  3. Children with health impairments by heavy metals in an e-waste recycling area.

    Science.gov (United States)

    Zeng, Xiang; Xu, Xijin; Boezen, H Marike; Huo, Xia

    2016-04-01

    E-waste recycling has become a global environmental health issue. Pernicious chemicals escape into the environment due to informal and nonstandard e-waste recycling activities involving manual dismantling, open burning to recover heavy metals and open dumping of residual fractions. Heavy metals derived from electronic waste (e-waste), such as, lead (Pb), cadmium (Cd), chromium (Cr), manganese (Mn), nickel (Ni), mercury (Hg), arsenic (As), copper (Cu), zinc (Zn), aluminum (Al) and cobalt (Co), differ in their chemical composition, reaction properties, distribution, metabolism, excretion and biological transmission. Our previous studies showed that heavy metal exposure have adverse effects on children's health including lower birth weight, lower anogenital distance, lower Apgar scores, lower current weight, lower lung function, lower hepatitis B surface antibody levels, higher prevalence of attention-deficit/hyperactivity disorder, and higher DNA and chromosome damage. Heavy metals influence a number of diverse systems and organs, resulting in both acute and chronic effects on children's health, ranging from minor upper respiratory irritation to chronic respiratory, cardiovascular, nervous, urinary and reproductive disease, as well as aggravation of pre-existing symptoms and disease. These effects of heavy metals on children's health are briefly discussed. Copyright © 2016 Elsevier Ltd. All rights reserved.

  4. Gill ATPase activity in Procambarus clarkii as an indicator of heavy metal pollution

    Energy Technology Data Exchange (ETDEWEB)

    Torreblanca, A.; Del Ramo, J.; Diaz-Mayans, J. (Univ. of Valencia (Spain))

    1989-06-01

    Lake Albufera and the surrounding rice field waters are subjected to very heavy loads of sewage and toxic industrial residues, including heavy metals, from the many urban and waste waters of this area. The American red crayfish, Procambarus clarkii have a high resistance to toxic effects of heavy metals. The sublethal effects of heavy metals on gills of fish and aquatic invertebrates have been extensively studied. Some metabolic disturbances and histologic damages have been reported, as well as osmoregulation alterations. However, little work has been done about the effect of heavy metals on Na,K and Mg-ATPases of freshwater invertebrate gills. Na,K-ATPase is the prime mediator of ion transport across cellular membranes and plays a central role in whole body ion regulation in marine and estuarine animals. Na,K-ATPase has been reviewed and assessed as a potentially useful indicator of pollution stress in aquatic animals. The purpose of this study is look for the relation, if any, between crayfish gill ATP-ase activity changes and metal exposure in laboratory. This find would allow the authors to assay this potential indicator in the field.

  5. International cooperation in heavy-ion research

    International Nuclear Information System (INIS)

    Tobias, C.A.

    1980-01-01

    The rapidly growing research applications of heavy ions in basic biology and medicine have stimulated interest in this field in many countries. LBL, with its unique facilities and its scientific programs, is the focal point of interest. Plans are underway in several countries, including France, Japan, West Germany, and Canada, to build heavy-ion facilities, and to collaborate with our staff at LBL in heavy-ion research in physics, biology, and medicine

  6. Heavy Quarkonium Physics

    CERN Document Server

    CERN. Geneva; Krämer, Michael; Mussa, Roberto; Vairo, Antonio; Bali, G S; Bodwin, G T; Braaten, E; Eichten, E; Eidelman, S; Godfrey, S; Hoang, A; Jamin, M; Kharzeev, Dima E; Lombardo, M P; Lourenço, C; Meyer, A B; Papadimitriou, V; Patrignani, C; Rosati, M; Sanchis-Lozano, M A; Satz, Helmut; Soto, J; Besson, D Z; Bettoni, D; Böhrer, A; Boogert, S; Chang, C H; Cooper, P; Crochet, Philippe; Datta, S; Davies, C; Deandrea, A; Faustov, R; Ferguson, T; Galik, R; Harris, F; Iouchtchenko, O; Kaczmarek, O; Karsch, Frithjof; Kienzle, M; Kiselev, V V; Klein, S R; Kroll, P; Kronfeld, A S; Kuang Yu Ping; Laporta, V; Lee, J; Leibovich, A K; Ma, J P; MacKenzie, P; Maiani, Luciano; Mangano, Michelangelo L; Meyer, A; Mo, X H; Morningstar, C; Nairz, A; Napolitano, J; Olsen, S; Penin, A A; Petreczky, P; Piccinini, F; Pineda, A; Polosa, Antonio; Ramello, L; Rapp, R; Richard, J M; Riquer, V; Ricciardi, S; Robutti, E; Schneider, O; Scomparin, E; Simone, J; Skwarnicki, T; Stancari, G; Stewart, I W; Sumino, Y; Teubner, T; Tseng, J; Vogt, R; Wang, P; Yabsley, B D; Yuan, C Z; Zantow, F; Zhao, Z G; Zieminski, A

    2005-01-01

    This report is the result of the collaboration and research effort of the Quarkonium Working Group over the last three years. It provides a comprehensive overview of the state of the art in heavy-quarkonium theory and experiment, covering quarkonium spectroscopy, decay, and production, the determination of QCD parameters from quarkonium observables, quarkonia in media, and the effects on quarkonia of physics beyond the Standard Model. An introduction to common theoretical and experimental tools is included. Future opportunities for research in quarkonium physics are also discussed.

  7. Heavy Metal.

    Science.gov (United States)

    Black, Susan

    2001-01-01

    The Centers for Disease Control and Prevention (CDC) estimate that more than 1 million children ages 5 and under are afflicted with unsafe amounts of lead. Schools can be a source of lead poisoning. Other sources include playgrounds near freeways, playground equipment, contaminated soil, and technology rooms with lead-bearing supplies. Sidebars…

  8. Effective mutagenesis of Arabidopsis by heavy ion beam-irradiation

    International Nuclear Information System (INIS)

    Yamamoto, Y.Y.; Saito, H.; Ryuto, H.; Fukunishi, N.; Yoshida, S.; Abe, T.

    2005-01-01

    Full text: Arabidopsis researches frequently include the genetic approach, so efficient, convenient, and safe methods for mutagenesis are required. Currently, the most popular method for in house mutagenesis is application of EMS. Although this method is very effective, its base substitution-type mutations often gives leaky mutants with residual gene functions, leading some difficulty in understanding the corresponding gene functions. Heavy ion beam generated by accelerators gives highest energy transfer rates among known radiation-based mutagenesis methods including X ray, gamma ray, fast neutron, electron and proton irradiation. This feature is thought to give high frequency of the double strand break of genomic DNA and resultant short deletions, resulting frame shift-type mutations. At RIKEN Accelerator Research Facility (RARF, http://www.rarf.riken.go.jp/index-e.html), we have optimized conditions for effective mutagenesis of Arabidopsis regarding to ion species and irradiation dose, and achieved comparable mutation rates to the method with EMS. (author)

  9. Electron impact ionization of heavy ions: some surprises

    International Nuclear Information System (INIS)

    Younger, S.M.

    1986-01-01

    This paper reports the results of calculations of electron impact ionization cross sections for a variety of heavy ions using a distorted wave Born-exchange approximation. The target is described by a Hartree-Fock wavefunction. The scattering matrix element is represented by a triple partial wave expansion over incident, scattered, and ejected (originally bound) continuum states. These partial waves are computed in the potentials associated with the initial target (incident and scattered waves) and the residual ion (ejected waves). A Gauss integration was performed over the distribution of energy between the two final state continuum electrons. For ionization of closed d- and f-subshells, the ejected f-waves were computed in frozen-core term-dependent Hartree-Fock potentials, which include the strong repulsive contribution in singlet terms which arises from the interaction of an excited orbital with an almost closed shell. Ground state correlation was included in some calculations of ionization of d 10 subshells

  10. Oxygen uptake by excised gills of Procambarus clarkii (Girard) from Albufera Lake of Valencia, Spain, under heavy metal treatments

    Energy Technology Data Exchange (ETDEWEB)

    Diaz-Mayans, J.; Torreblanca, A.; Del Ramo, J.; Nunez, A.

    1986-06-01

    The American red crayfish Procambarus clarkii, originally from Louisiana (USA) was introduced in Spain in the 70's in the Guadalquivir River swamps. It appeared first randomly and in a more regular basis afterwards since 1978 in the Albufera Lake south of Valencia and in the surrounding rice fields. Albufera lake and surrounding rice fields waters are being subject since the last three decades to very heavy load of sewage, toxic industrial residues including heavy metals and pesticides from the many urban and industrial settlements in the zone. In the present study, the authors have investigated the effect that heavy metals (Chromium, Cadmium and Mercury) have on the oxygen uptake by excised bills of Procambarus clarkii (Girard) coming from the Albufera Lake (Valencia).

  11. A heavy load for heavy ions

    CERN Multimedia

    2003-01-01

    On 25 September, the two large coils for the dipole magnet of ALICE, the LHC experiment dedicated to heavy ions, arrived at Point 2 on two heavy load trucks after a 1200 km journey from their assembly in Vannes, France.

  12. Leaching Behavior of Circulating Fluidised Bed MSWI Air Pollution Control Residue in Washing Process

    Directory of Open Access Journals (Sweden)

    Zhiliang Chen

    2016-09-01

    Full Text Available In this study, air pollution control (APC residue is conducted with water washing process to reduce its chloride content. A novel electrical conductivily (EC measurement method is proposed to monitor the dynamic change of chloride concentrations in leachate as well as the chloride content of the residue. The method equally applies to various washing processes with different washing time, liquid/solid ratio and washing frequency. The results show that washing effectively extracts chloride salts from APC residues, including those from circulating fluidized bed (CFB municipal solid waste incineration (MSWI. The most appropriate liquid/solid ratio and washing time in the first washing are found to be around 4 L water per kg of APC residue and 30 min, respectively, and washing twice is required to obtain maximum dissolution. The pH value is the major controlling factor of the heavy metals speciation in leachate, while chloride concentration also affects the speciation of Cd. Water washing causes no perceptible transfer of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs from the APC residue to leachate. The chloride concentration is strongly related with electrical conductivity (EC, as well as with the concentrations of calcium, sodium and potassium of washing water. Their regression analyses specify that soluble chloride salts and EC could act as an indirect indicator to monitor the change of chloride concentration and remaining chloride content, thus, contributing to the selection of the optimal washing conditions.

  13. Heavy metal decontamination of sludges and soils. Pt. 2

    International Nuclear Information System (INIS)

    Niemann, J.

    1993-06-01

    This research project deals with decontamination technology for contaminated soil and sediments. A pilot plant for the decontamination of soil contaminated with heavy metals has been erected and is operated. The process is arranged in two steps: - heavy metal contaminated solid is decontaminted with acidic extraction. - the heavy metals are separated in a recyclable formation from the process solution you gain in the first process step. Heavy metal contaminated soil, heavy metal contaminated sediments (habour sediments) as well as residue from a soil regeneration plant have been successfully decontaminated in the pilot plan. An adaption of the process is necessary for various materials. High rates of mobilisation of heavy metals (e.g. lead, cadmium, chromium, copper, nickel, zinc) were obtained, especially with soil which contains less organic matter. (orig.). 54 figs., 30 tabs., 45 refs [de

  14. Heavy Water Quality Management in HANARO

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Ho Chul; Lee, Mun; Kim, Hi Gon; Park, Chan Young; Choi, Ho Young; Hur, Soon Ock; Ahn, Guk Hoon

    2008-12-15

    Heavy water quality management in the reflector tank is a very important element to maintain the good thermal neutron flux and to ensure the performance of reflector cooling system. This report is written to provide a guidance for the future by describing the history of the heavy water quality management during HANARO operation. The heavy water quality in the reflector tank has been managed by measuring the electrical conductivity at the inlet and outlet of the ion exchanger and by measuring pH of the heavy water. In this report, the heavy water quality management activities performed in HANARO from 1996 to 2007 ere described including a basic theory of the heavy water quality management, exchanging history of used resin in the reflector cooling system, measurement data of the pH and the electrical conductivity, and operation history of the reflector cooling system.

  15. Heavy oil in Saskatchewan: Building on strengths

    International Nuclear Information System (INIS)

    1994-02-01

    Saskatchewan has reserves of 17.6 billion bbl of heavy oil located in the west-central part of the province. The first oil well was drilled in 1945 and production of heavy oil has increased gradually, reaching 79,000 bbl/d in 1992. In recent years, the production pattern has not matched trends in investment; since 1982/83, the relative proportion of heavy oil drilling has declined significantly. A study is presented which analyzes trends in heavy oil investment, production, economics, and markets, with a focus on determining the causes for lack of investment in the heavy oil sector and evaluating the opportunities and constraints for long-term sustainability of this industry. Industry background is provided, with presentation of the key resource characteristics, reserve potential, and production and investment trends. Markets both in Canada and the USA are analyzed in detail, possible future trends are suggested. The effect of development of refinery capacity on heavy oil developments is examined. The logistics of shipping heavy oil to markets are detailed. The economics of Saskatchewan heavy oil production are established, taking into account all relevant cost components including taxes, royalties, and netbacks to producers. Issues of relevance affecting the heavy oil industry are discussed, including the need for environmental safeguards. 25 figs., 24 tabs

  16. Life cycle assessment of disposal of residues from municipal solid waste incineration

    DEFF Research Database (Denmark)

    Birgisdottir, Harpa; Bhander, Gurbakhash Singh; Hauschild, Michael Zwicky

    2007-01-01

    Two disposal methods for MSWI bottom ash were assessed in a new life cycle assessment (LCA) model for road construction and disposal of residues. The two scenarios evaluated in the model were: (i) landfilling of bottom ash in a coastal landfill in Denmark and (ii) recycling of bottom ash as subbase...... layer in an asphalted secondary road. The LCA included resource and energy consumption, and emissions associated with upgrading of bottom ash, transport, landfilling processes, incorporation of bottom ash in road, substitution of natural gravel as road construction material and leaching of heavy metals...

  17. Experimental approaches to heavy ion fusion

    International Nuclear Information System (INIS)

    Obayashi, H.; Fujii-e, Y.; Yamaki, T.

    1986-01-01

    As a feasibility study on heavy-ion-beam induced inertial fusion (HIF) approach, a conceptual plant design called HIBLIC-I has been worked out since 1982. The characteristic features of this design are summarized. To experimentally confirm them and prove them at least in principle, considerations are made on possible experimental programs to give substantial information on these critical phenomena. In HIBLIC-I, an accelerator complex is adopted as driver system to provide 6 beams of 208 Pb +1 ions at 15 GeV, which will be simultaneously focussed on a single shell, three layered target. The target is designed to give an energy gain of 100, so that the total beam energy of 4 MJ with 160 TW power may release 400 MJ fusion energy. A reactor chamber is cylindrical with double-walled structure made of HT-9. There are three layers of liquid Li flow inside the reactor. The innermost layer forms a Li curtain which is effective to recover the residual cavity pressure. A thick upward flow serves as coolant and tritium breeder. Tritium will be recovered by yttrium gettering system. A driver system is operated at the repetition rate of 10 Hz and supplies beams for 10 reactor chambers. Then the plant yield of fusion power becomes 4000 MWt, corresponding a net electric output of 1.5 GW. Experimental programs related to HIBLIC-I is described and discussed, including those for heavy-ion-beam experiments and proposals for lithium curtain by electron beam to clarify the key phenomena in HIBLIC-I cavity. (Nogami, K.)

  18. Heavy Flavour results from CMS

    CERN Document Server

    Chen, Kai-Feng

    2016-01-01

    The available statistics of heavy flavoured particles collected in pp collisions at the LHC provides an excellent opportunity to test the standard model and probe for new physics effects. A review of selected recent studies on heavy flavours, including the angular analysis in B$^0$ $\\to$ K$^{*0}$$\\mu^+\\mu^-$, the measurements of B$^+$ hadron production cross section, as well as the quarkonium production cross sections, by the CMS experiment based on datasets collected during LHC Run I and Run II is presented.

  19. Solidification process for sludge residue

    International Nuclear Information System (INIS)

    Pearce, K.L.

    1998-01-01

    This report investigates the solidification process used at 100-N Basin to solidify the N Basin sediment and assesses the N Basin process for application to the K Basin sludge residue material. This report also includes a discussion of a solidification process for stabilizing filters. The solidified matrix must be compatible with the Environmental Remediation Disposal Facility acceptance criteria

  20. The development of heavy-ion nuclear physics

    International Nuclear Information System (INIS)

    Bromley, D.A.

    1984-01-01

    This paper presents a brief historical overview of heavy-ion science. Topics considered include the early work at Berkeley, developments at Los Alamos and Yale, nuclear chemistry at Berkeley, European heavy-ion studies, 14 N+ 14 N studies at Oak Ridge, heavy-ion studies in the USSR, heavy-ion linear accelerator projects at Yale and Berkeley, research at the HILAC and HIA, the first tandem accelerator, heavy-ion research at Dubna, large electrostatic accelerators, the Brookhaven Double MP accelerator, the SUPERHILAC at Berkeley, the UNILAC complex at Darmstadt, the 1975 renaissance in precision heavy-ion nuclear physics, postaccelerator systems for heavy ions, the Berkeley Bevalac, ultrarelativistic interactions, heavy-ion nuclear theory, and applications of heavy-ion nuclear physics

  1. Heavy ion beam probing

    Energy Technology Data Exchange (ETDEWEB)

    Hickok, R L

    1980-07-01

    This report consists of the notes distributed to the participants at the IEEE Mini-Course on Modern Plasma Diagnostics that was held in Madison, Wisconsin in May 1980. It presents an overview of Heavy Ion Beam Probing that briefly describes the principles and discuss the types of measurements that can be made. The problems associated with implementing beam probes are noted, possible variations are described, estimated costs of present day systems, and the scaling requirements for large plasma devices are presented. The final chapter illustrates typical results that have been obtained on a variety of plasma devices. No detailed calculations are included in the report, but a list of references that will provide more detailed information is included.

  2. Heavy ion beam probing

    International Nuclear Information System (INIS)

    Hickok, R.L.

    1980-07-01

    This report consists of the notes distributed to the participants at the IEEE Mini-Course on Modern Plasma Diagnostics that was held in Madison, Wisconsin in May 1980. It presents an overview of Heavy Ion Beam Probing that briefly describes the principles and discuss the types of measurements that can be made. The problems associated with implementing beam probes are noted, possible variations are described, estimated costs of present day systems, and the scaling requirements for large plasma devices are presented. The final chapter illustrates typical results that have been obtained on a variety of plasma devices. No detailed calculations are included in the report, but a list of references that will provide more detailed information is included

  3. Mortality and cancer morbidity after heavy occupational fluoride exposure

    DEFF Research Database (Denmark)

    Grandjean, P; Juel, K; Jensen, Ole Møller

    1985-01-01

    A cohort of 431 male cryolite workers employed for at least six months between 1924 and 1961 was identified from personnel records at the Copenhagen cryolite factory. During this period, heavy fluoride exposure resulted in at least 74 cases of skeletal fluorosis. All workmen in the cohort were......, a possible residual effect of fluoride cannot be excluded. However, any major carcinogenic effect of heavy fluoride exposure would be very unlikely....

  4. Mortality and cancer morbidity after heavy occupational fluoride exposure

    DEFF Research Database (Denmark)

    Grandjean, P; Juel, K; Jensen, Ole Møller

    1985-01-01

    A cohort of 431 male cryolite workers employed for at least six months between 1924 and 1961 was identified from personnel records at the Copenhagen cryolite factory. During this period, heavy fluoride exposure resulted in at least 74 cases of skeletal fluorosis. All workmen in the cohort were fo......, a possible residual effect of fluoride cannot be excluded. However, any major carcinogenic effect of heavy fluoride exposure would be very unlikely....

  5. Symmetry-dictated trucation: Solutions of the spherical shell model for heavy nuclei

    International Nuclear Information System (INIS)

    Guidry, M.W.

    1992-01-01

    Principles of dynamical symmetry are used to simplify the spherical shell model. The resulting symmetry-dictated truncation leads to dynamical symmetry solutions that are often in quantitative agreement with a variety of observables. Numerical calculations, including terms that break the dynamical symmetries, are shown that correspond to shell model calculations for heavy deformed nuclei. The effective residual interaction is simple, well-behaved, and can be determined from basic observables. With this approach, we intend to apply the shell model in systematic fashion to all nuclei. The implications for nuclear structure far from stability and for nuclear masses and other quantities of interest in astrophysics are discussed

  6. Vacuum Distillation Residue Upgrading by an Indigenous Bacillus Cereus

    Directory of Open Access Journals (Sweden)

    Mitra Sadat Tabatabaee

    2013-07-01

    Full Text Available Background:Biological processing of heavy fractions of crude oils offers less severe process conditions and higher selectivity for refining. Biochemical Processes are expected to be low demand energy processes and certainly ecofriendly.Results:A strain of biosurfactant producing bacterium was isolated from an oil contaminated soil at Tehran refinery distillation unit. Based on selected phenotypic and genotypic characteristic including morphology, biochemical proprety, and 16 SrRNA sequencing identified as a novel strain of Bacillus cereus (JQ178332. This bacterium endures a wide range of pH, salinity and temperature. This specific strain utilizes both paraffin and anthracene as samples of aliphatic and polycyclic aromatic hydrocarbons. The ability of this bacterium to acquire all its energy and chemical requirements from Vacuum Distillation Residue (VR, as a net sample of problematic hydrocarbons in refineries, was studied. SARA test ASTM D4124-01 revealed 65.5% decrease in asphaltenic, 22.1% in aliphatics and 30.3% in Aromatics content of the VR in MSM medium. Further results with 0.9% saline showed 55% decrease in asphaltene content and 2.1% Aromatics respectively.Conclusion:Remarkable abilities of this microorganism propose its application in an ecofriendly technology to upgrade heavy crude oils.

  7. Residual gas analysis

    International Nuclear Information System (INIS)

    Berecz, I.

    1982-01-01

    Determination of the residual gas composition in vacuum systems by a special mass spectrometric method was presented. The quadrupole mass spectrometer (QMS) and its application in thin film technology was discussed. Results, partial pressure versus time curves as well as the line spectra of the residual gases in case of the vaporization of a Ti-Pd-Au alloy were demonstrated together with the possible construction schemes of QMS residual gas analysers. (Sz.J.)

  8. Semantic Tagging with Deep Residual Networks

    NARCIS (Netherlands)

    Bjerva, Johannes; Plank, Barbara; Bos, Johan

    2016-01-01

    We propose a novel semantic tagging task, semtagging, tailored for the purpose of multilingual semantic parsing, and present the first tagger using deep residual networks (ResNets). Our tagger uses both word and character representations and includes a novel residual bypass architecture. We evaluate

  9. Rare Earth Element Phases in Bauxite Residue

    Directory of Open Access Journals (Sweden)

    Johannes Vind

    2018-02-01

    Full Text Available The purpose of present work was to provide mineralogical insight into the rare earth element (REE phases in bauxite residue to improve REE recovering technologies. Experimental work was performed by electron probe microanalysis with energy dispersive as well as wavelength dispersive spectroscopy and transmission electron microscopy. REEs are found as discrete mineral particles in bauxite residue. Their sizes range from <1 μm to about 40 μm. In bauxite residue, the most abundant REE bearing phases are light REE (LREE ferrotitanates that form a solid solution between the phases with major compositions (REE,Ca,Na(Ti,FeO3 and (Ca,Na(Ti,FeO3. These are secondary phases formed during the Bayer process by an in-situ transformation of the precursor bauxite LREE phases. Compared to natural systems, the indicated solid solution resembles loparite-perovskite series. LREE particles often have a calcium ferrotitanate shell surrounding them that probably hinders their solubility. Minor amount of LREE carbonate and phosphate minerals as well as manganese-associated LREE phases are also present in bauxite residue. Heavy REEs occur in the same form as in bauxites, namely as yttrium phosphates. These results show that the Bayer process has an impact on the initial REE mineralogy contained in bauxite. Bauxite residue as well as selected bauxites are potentially good sources of REEs.

  10. Bioaccumulation and toxic effects of some heavy metals in ...

    African Journals Online (AJOL)

    The contamination of the aquatic systems with heavy metals from natural anthropogenic sources has become a global problem which poses threats to ecosystems and natural communities. Hence this study reviews the effects of heavy metals in freshwater fishes. Fishes bioaccumulate heavy metals (including cadmium, zinc ...

  11. Heavy metals content in the stem bark of Detarium microcarpum ...

    African Journals Online (AJOL)

    The heavy metal analysis was carried out on the stem bark of D. microcarpum using an atomic absorption spectrophotometer (AAS). The heavy metals screened for include: lead, chromium, manganese, zinc and iron. The levels of manganese, zinc and iron were 13.91, 4.89 and 21.89 mg/L respectively. These heavy metals ...

  12. Transfer of heavy metals through terrestrial food webs: a review.

    Science.gov (United States)

    Gall, Jillian E; Boyd, Robert S; Rajakaruna, Nishanta

    2015-04-01

    Heavy metals are released into the environment by both anthropogenic and natural sources. Highly reactive and often toxic at low concentrations, they may enter soils and groundwater, bioaccumulate in food webs, and adversely affect biota. Heavy metals also may remain in the environment for years, posing long-term risks to life well after point sources of heavy metal pollution have been removed. In this review, we compile studies of the community-level effects of heavy metal pollution, including heavy metal transfer from soils to plants, microbes, invertebrates, and to both small and large mammals (including humans). Many factors contribute to heavy metal accumulation in animals including behavior, physiology, and diet. Biotic effects of heavy metals are often quite different for essential and non-essential heavy metals, and vary depending on the specific metal involved. They also differ for adapted organisms, including metallophyte plants and heavy metal-tolerant insects, which occur in naturally high-metal habitats (such as serpentine soils) and have adaptations that allow them to tolerate exposure to relatively high concentrations of some heavy metals. Some metallophyte plants are hyperaccumulators of certain heavy metals and new technologies using them to clean metal-contaminated soil (phytoextraction) may offer economically attractive solutions to some metal pollution challenges. These new technologies provide incentive to catalog and protect the unique biodiversity of habitats that have naturally high levels of heavy metals.

  13. BOTANICAL DIVERSITY AND HEAVY METAL CONTENT IN THE RESIDUE MATRIX AND PLANTS AT THE MORAVIA DUMP IN MEDELLÍN, COLOMBIA DIVERSIDAD BOTÁNICA Y CONTENIDO DE METALES PESADOS EN LA MATRIZ DE RESIDUOS Y LAS PLANTAS EN EL BASURERO DE MORAVIA EN MEDELLÍN, COLOMBIA

    Directory of Open Access Journals (Sweden)

    Maria Solange Sanchez Pinzón

    2010-06-01

    Full Text Available . Floristic characterization, plant tissue and residue matrix (RM analysis were conducted to establish the extent of heavy metal (HM pollution of the Moravia dump at Medellín, Colombia, a site that was inhabited by more than 17000 people since 1984. More than 65 plant species (28 families were identified, most of which were herbaceous. Content of HM in the (RM was determined in 14 different RM samples varied greatly among them, reaching 121 and 9600 mg/kg of Hg and Pb respectively. Mean content of HM (mg/kg in the RM had the following pattern: Pb > Ni > Cr > Hg > Cd. Uptake of HM from the RM to plants was evident in most sampled species, with concentrations of Pb, Cr, and Hg reaching maximum values of 1.0, 123.7, 263.7 mg/kg of Hg, Pb and Cr respectively. However, Lepidium virginicum excluded, estimated bioconcentration factors were not greater than 1.0. Given their adaptation, Bidens pilosa, Urochloa maxima and L. virginicum, appear to be suitable for the revegetation of Moravia. Twenty-four years after its closure, HM content in Moravia continue to be high and the local flora actively takes up HM. Since other studies have shown that in Moravia there is still production of lixiviates and that there is an active heavy metal transference to the local Moravia fauna, it is imperative to implement adequate control measures in order to control HM contamination at this site.Con el fin de establecer el nivel de contaminación por metales pesados (MP, se llevó a cabo una caracterización florística y análisis de la matriz de residuos (MR y muestras de tejidos vegetales en el morro de basuras de Moravia en Medellín, un antiguo botadero de basuras habitado desde 1984 por más de 17.000 personas. Se identificaron más de 65 especies vegetales, la mayoría de ellas herbáceas, agrupadas en 28 familias. El contenido de MP en 14 diferentes muestras de MR varió considerablemente, yendo de 121 y 9.600 mg/kg de Hg y Pb, respectivamente. El contenido

  14. Three- and two-point one-loop integrals in heavy particle effective theories

    International Nuclear Information System (INIS)

    Bouzas, A.O.

    2000-01-01

    We give a complete analytical computation of three- and two-point loop integrals occurring in heavy particle theories, involving a velocity change, for arbitrary real values of the external masses and residual momenta. (orig.)

  15. Historical aspects of heavy ion radiotherapy

    International Nuclear Information System (INIS)

    Raju, M.R.

    1995-01-01

    This paper presents historical developments of heavy-ion radiotherapy including discussion of HILAC and HIMAC and discussion of cooperation between Japan and the United States, along with personal reflections

  16. Heavy quark masses

    Science.gov (United States)

    Testa, Massimo

    1990-01-01

    In the large quark mass limit, an argument which identifies the mass of the heavy-light pseudoscalar or scalar bound state with the renormalized mass of the heavy quark is given. The following equation is discussed: m(sub Q) = m(sub B), where m(sub Q) and m(sub B) are respectively the mass of the heavy quark and the mass of the pseudoscalar bound state.

  17. Heavy mineral placers

    Digital Repository Service at National Institute of Oceanography (India)

    Gujar, A.R.

    ], which contains economic quantities of valuable minerals such as gold, tin and platinum etc. Placer deposit can also be defined as a “mineral deposit formed by the process of mechanical concentration of mineral particles from weathered debris... Content-Type text/plain; charset=UTF-8 32 Heavy mineral placers A. R. Gujar National Institute of Oceanography, Dona-Paula, Goa-403004 agujar@nio.org Heavy mineral placers Heavy mineral placer deposit is defined as “Alluvial...

  18. 40 CFR Appendix Xii to Part 86 - Tables for Production Compliance Auditing of Heavy-Duty Engines and Heavy-Duty Vehicles...

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 19 2010-07-01 2010-07-01 false Tables for Production Compliance Auditing of Heavy-Duty Engines and Heavy-Duty Vehicles, Including Light-Duty Trucks XII Appendix XII to... Appendix XII to Part 86—Tables for Production Compliance Auditing of Heavy-Duty Engines and Heavy-Duty...

  19. Agricultural pesticide residues

    International Nuclear Information System (INIS)

    Fuehr, F.

    1984-01-01

    The utilization of tracer techniques in the study of agricultural pesticide residues is reviewed under the following headings: lysimeter experiments, micro-ecosystems, translocation in soil, degradation of pesticides in soil, biological availability of soil-applied substances, bound residues in the soil, use of macro- and microautography, double and triple labelling, use of tracer labelling in animal experiments. (U.K.)

  20. Spin dependent fragmentation functions for heavy flavor baryons and single heavy hyperon polarization

    CERN Document Server

    Goldstein, G R

    2001-01-01

    Spin dependent fragmentation functions for heavy flavor quarks to fragment into heavy baryons are calculated in a quark-diquark model. The production of intermediate spin 1/2 and 3/2 excited states is explicity included. $\\Lambda_b$ , $\\Lambda_c$ and $\\Xi_c$ production rate and polarization at LEP energies are calculated and, where possible, compared with experiment. A different approach, also relying on a heavy quark-diquark model, is proposed for the small momentum transfer inclusive production of polarized heavy flavor hyperons. The predicted $\\Lambda_c$ polarization is roughly in agreement with experiment.

  1. The heavy oil refiners needs in the future

    International Nuclear Information System (INIS)

    Sauer, J.W.

    1991-01-01

    In the 1970s oil crisis, the high price differential that developed between heavy and light crude led to an expansion in heavy crude processing geared to producing light oil products. The subsequent collapse in prices meant that heavy crudes with low netbacks were shut in, heavy crude refining capacity exceeded the restrained production of heavy crudes, and refineries were operating at losses. However, the low prices for oil rekindled demand and spare production capacity has been absorbed. The crude oil price is forecast to rise to ca $27/bbl by the late 1990s, which is favorable for heavy crude oil production. Nevertheless, investments in heavy crude production are exposed to a high degree of risk. A strategy for dealing with this risk is to integrate into downstream, which makes more sense for heavy crude producers than for conventional producers. On the other hand, such integration is capital-intensive, and light oils will likely be favored in crude oil production developments for the next several years. Low prices for natural gas will make it hard to find markets for residual fuel made from heavy crudes. 8 figs

  2. An Additive-Multiplicative Restricted Mean Residual Life Model

    DEFF Research Database (Denmark)

    Mansourvar, Zahra; Martinussen, Torben; Scheike, Thomas H.

    2016-01-01

    The mean residual life measures the expected remaining life of a subject who has survived up to a particular time. When survival time distribution is highly skewed or heavy tailed, the restricted mean residual life must be considered. In this paper, we propose an additive-multiplicative restricted...... mean residual life model to study the association between the restricted mean residual life function and potential regression covariates in the presence of right censoring. This model extends the proportional mean residual life model using an additive model as its covariate dependent baseline....... For the suggested model, some covariate effects are allowed to be time-varying. To estimate the model parameters, martingale estimating equations are developed, and the large sample properties of the resulting estimators are established. In addition, to assess the adequacy of the model, we investigate a goodness...

  3. Production of heavy water

    Energy Technology Data Exchange (ETDEWEB)

    Spencer, Larry S.; Brown, Sam W.; Phillips, Michael R.

    2017-06-06

    Disclosed are methods and apparatuses for producing heavy water. In one embodiment, a catalyst is treated with high purity air or a mixture of gaseous nitrogen and oxygen with gaseous deuterium all together flowing over the catalyst to produce the heavy water. In an alternate embodiment, the deuterium is combusted to form the heavy water. In an alternate embodiment, gaseous deuterium and gaseous oxygen is flowed into a fuel cell to produce the heavy water. In various embodiments, the deuterium may be produced by a thermal decomposition and distillation process that involves heating solid lithium deuteride to form liquid lithium deuteride and then extracting the gaseous deuterium from the liquid lithium deuteride.

  4. The effect of different solvent polarity on the precipitation of heavy ...

    African Journals Online (AJOL)

    The precipitation of heavy organics (Saturates, Aromatics, Resins and Asphaltenes) from the Niger delta (Atan crude oil residue) was studied. Two C4 organic polar solvents (ethyl acetate and butanone) were used to investigate the effect of polarity of the precipitating solvents. The heavy organics precipitated from Antan ...

  5. Children with health impairments by heavy metals in an e-waste recycling area

    NARCIS (Netherlands)

    Zeng, Xiang; Xu, Xijin; Boezen, H. Marike; Huo, Xia

    E-waste recycling has become a global environmental health issue. Pernicious chemicals escape into the environment due to informal and nonstandard e-waste recycling activities involving manual dismantling, open burning to recover heavy metals and open dumping of residual fractions. Heavy metals

  6. Heavy-Quark Production

    CERN Document Server

    Frixione, Stefano; Nason, Paolo; Ridolfi, Giovanni

    1997-01-01

    We review the present theoretical and experimental status of heavy quark production in high-energy collisions. In particular, we cover hadro- and photoproduction at fixed target experiments, at HERA and at the hadron colliders, as well as aspects of heavy quark production in e+e- collisions at the Z0 peak.

  7. Accelerators for heavy ions

    International Nuclear Information System (INIS)

    Martin, J.A.

    1975-01-01

    The use of heavy ion accelerators in nuclear physics, nuclear chemistry, atomic physics, and in material sciences studies is rapidly increasing. A review is given of the present and developing scene in heavy ion accelerator concepts and technology. The area of applicability of various methods, likely avenues of future development, and the trends of future requirements are discussed. (auth)

  8. Heavy-quark physics in quantum chromodynamics

    International Nuclear Information System (INIS)

    Brodsky, S.J.

    1991-04-01

    Heavy quarks can expose new symmetries and novel phenomena in QCD not apparent in ordinary hadronic systems. In these lectures I discuss the use of effective-Lagrangian and light-cone Fock methods to analyze exclusive heavy hadron decays such as Υ → p bar p and B → ππ, and also to derive effective Schroedinger and Dirac equations for heavy quark systems. Two contributions to the heavy quark structure functions of the proton and other light hadrons are identified: an ''extrinsic'' contribution associated with leading twist QCD evolution of the gluon distribution, and a higher twist ''intrinsic'' contribution due to the hardness of high-mass fluctuations of multi-gluon correlations in hadronic wavefunctions. A non-perturbative calculation of the heavy quark distribution of a meson in QCD in one space and one time is presented. The intrinsic higher twist contributions to the pion and proton structure functions can dominate the hadronic production of heavy quark systems at large longitudinal momentum fraction x F and give anomalous contributions to the quark structure functions of ordinary hadrons at large x bj . I also discuss a number of ways in which heavy quark production in nuclear targets can test fundamental QCD phenomena and provide constraints on hadronic wavefunctions. The topics include color transparency, finite formation time, and predictions for charm production at threshold, including nuclear-bound quarkonium. I also discuss a number of QCD mechanisms for the suppression of J/ψ and Υ production in nuclear collisions, including gluon shadowing, the peripheral excitation of intrinsic heavy quark components at large x F , and the coalescence of heavy quarks with co-moving spectators at low x F

  9. Effects of temperature on the acute toxicity of heavy metals (Cr, Cd, and Hg) to the freshwater crayfish, Procambarus clarkii (Girard)

    Energy Technology Data Exchange (ETDEWEB)

    Del Ramo, J.; Diaz-Mayans, J.; Torreblanca, A.; Nunez, A.

    1987-05-01

    Chromium, an essential trace element for humans and animals is involved in normal carbohydrate metabolism; however, it is toxic at high concentrations. There is no evidence that cadmium and mercury are biologically essential but their toxicity for organisms is well known. Both cause toxic effects at low concentrations to most organisms, especially in combination with other environmental variables such as temperature. Lake Albufera and the surrounding rice field waters are subjected to very heavy loads of sewage and toxic industrial residues (including heavy metals) from the many urban and waste waters in this area. In 1978, the American red crayfish Procambarus clarkii appeared in lake Albufera and in the surrounding rice fields. Without adequate sanitary control, the crayfish is presently being fished commercially for human consumption. The purpose of the present study is to evaluate the degree of toxicity of various heavy metals (chromium, cadmium and mercury) to freshwater crayfish Procambarus clarkii at various temperatures.

  10. Proficiency test for heavy metals in compound feed

    NARCIS (Netherlands)

    Pereboom, D.P.K.H.; Elbers, I.J.W.; Jong, de J.; Lee, van der M.K.; Nijs, de W.C.M.

    2016-01-01

    The here described proficiency test for heavy metals in compound feed was organised by RIKILT, Wageningen UR in accordance with ISO 17043. RIKILT Wageningen UR has an ISO/IEC 17043 accreditation for proficiency tests of residues in products of animal origin. However, this specific test is not part

  11. Concentrations of heavy metals in untreated produced water from a ...

    African Journals Online (AJOL)

    product, residue or waste. One of such is an effluent from the mining of crude oil and gas, known as produced water, which contains varying quantities of hydrocarbons and heavy metals, thereby making it to require proper treatment in order to ...

  12. Assessment of heavy metals in vegetables irrigated with Awash ...

    African Journals Online (AJOL)

    GIRMAYE

    urgent step is taken by relevant agencies to address this issue. Key words: Awash River, contamination, trace ... investment capacity worldwide for construction and operation of adequate treatment facilities which ... compounds and active residues of personal care products. Moreover, the excessive accumulation of heavy.

  13. Chemical Speciation and Mobility of Some Heavy Metals in Soils ...

    African Journals Online (AJOL)

    The mobility of some heavy metals (Fe, Co, Ni and Mn) in soils around automobile waste dumpsites in Northern part of Niger Delta was assessed using Tessier et al. five syteps sequential chemical extraction procedure. The results showed that majority of iron and manganese were associated with the residual fraction with ...

  14. Environmental assessment of ground water pollution by heavy ...

    African Journals Online (AJOL)

    use

    2011-11-14

    Nov 14, 2011 ... permissible metal limits of drinking water (WHO,. 1980, 1984). For this reason, the residual quantities of mercury, which were the most abundant heavy metals in the analyzed wells water samples were estimated in different chicken tissues to find the bioaccumulation of this toxic metal in the tissues and ...

  15. Recovery of silver residues from dental amalgam.

    Science.gov (United States)

    Pereira, Heloísa Aparecida Barbosa da Silva; Iano, Flávia Godoy; da Silva, Thelma Lopes; de Oliveira, Rodrigo Cardoso; de Menezes, Manoel Lima; Buzalaf, Marília Afonso Rabelo

    2010-01-01

    Dental amalgam residues are probably the most important chemical residues generated from clinical dental practice because of the presence of heavy metals among its constituents, mainly mercury and silver. The purpose of this study was to develop an alternative method for the recovery of silver residues from dental amalgam. The residue generated after vacuum distillation of dental amalgam for the separation of mercury was initially diluted with 32.5% HNO3, followed by precipitation with 20% NaCl. Sequentially, under constant heating and agitation with NaOH and sucrose, the sample was reduced to metallic silver. However, the processing time was too long, which turned this procedure not viable. In another sequence of experiments, the dilution was accomplished with concentrated HNO3 at 90 degrees C, followed by precipitation with 20% NaCl. After washing, the pellet was diluted with concentrated NH4OH, water and more NaCl in order to facilitate the reaction with the reducer. Ascorbic acid was efficiently used as reducer, allowing a fast reduction, thus making the procedure viable. The proposed methodology is of easy application and does not require sophisticated equipment or expensive reagents.

  16. Recovery of silver residues from dental amalgam

    Directory of Open Access Journals (Sweden)

    Heloísa Aparecida Barbosa da Silva Pereira

    2010-04-01

    Full Text Available Dental amalgam residues are probably the most important chemical residues generated from clinical dental practice because of the presence of heavy metals among its constituents, mainly mercury and silver. OBJECTIVE: The purpose of this study was to develop an alternative method for the recovery of silver residues from dental amalgam. MATERIAL AND METHODS: The residue generated after vacuum distillation of dental amalgam for the separation of mercury was initially diluted with 32.5% HNO3, followed by precipitation with 20% NaCl. Sequentially, under constant heating and agitation with NaOH and sucrose, the sample was reduced to metallic silver. However, the processing time was too long, which turned this procedure not viable. In another sequence of experiments, the dilution was accomplished with concentrated HNO3 at 90ºC, followed by precipitation with 20% NaCl. After washing, the pellet was diluted with concentrated NH4OH, water and more NaCl in order to facilitate the reaction with the reducer. RESULTS: Ascorbic acid was efficiently used as reducer, allowing a fast reduction, thus making the procedure viable. CONCLUSIONS: The proposed methodology is of easy application and does not require sophisticated equipment or expensive reagents.

  17. [Residual neuromuscular blockade].

    Science.gov (United States)

    Fuchs-Buder, T; Schmartz, D

    2017-06-01

    Even small degrees of residual neuromuscular blockade, i. e. a train-of-four (TOF) ratio >0.6, may lead to clinically relevant consequences for the patient. Especially upper airway integrity and the ability to swallow may still be markedly impaired. Moreover, increasing evidence suggests that residual neuromuscular blockade may affect postoperative outcome of patients. The incidence of these small degrees of residual blockade is relatively high and may persist for more than 90 min after a single intubating dose of an intermediately acting neuromuscular blocking agent, such as rocuronium and atracurium. Both neuromuscular monitoring and pharmacological reversal are key elements for the prevention of postoperative residual blockade.

  18. TENORM: Wastewater Treatment Residuals

    Science.gov (United States)

    Water and wastes which have been discharged into municipal sewers are treated at wastewater treatment plants. These may contain trace amounts of both man-made and naturally occurring radionuclides which can accumulate in the treatment plant and residuals.

  19. Residuation in orthomodular lattices

    Directory of Open Access Journals (Sweden)

    Chajda Ivan

    2017-04-01

    Full Text Available We show that every idempotent weakly divisible residuated lattice satisfying the double negation law can be transformed into an orthomodular lattice. The converse holds if adjointness is replaced by conditional adjointness. Moreover, we show that every positive right residuated lattice satisfying the double negation law and two further simple identities can be converted into an orthomodular lattice. In this case, also the converse statement is true and the corresponence is nearly one-to-one.

  20. Heavy water physical verification in power plants

    International Nuclear Information System (INIS)

    Morsy, S.; Schuricht, V.; Beetle, T.; Szabo, E.

    1986-01-01

    This paper is a report on the Agency experience in verifying heavy water inventories in power plants. The safeguards objectives and goals for such activities are defined in the paper. The heavy water is stratified according to the flow within the power plant, including upgraders. A safeguards scheme based on a combination of records auditing, comparing records and reports, and physical verification has been developed. This scheme has elevated the status of heavy water safeguards to a level comparable to nuclear material safeguards in bulk facilities. It leads to attribute and variable verification of the heavy water inventory in the different system components and in the store. The verification methods include volume and weight determination, sampling and analysis, non-destructive assay (NDA), and criticality check. The analysis of the different measurement methods and their limits of accuracy are discussed in the paper

  1. Characterization of Hospital Residuals

    International Nuclear Information System (INIS)

    Blanco Meza, A.; Bonilla Jimenez, S.

    1997-01-01

    The main objective of this investigation is the characterization of the solid residuals. A description of the handling of the liquid and gassy waste generated in hospitals is also given, identifying the source where they originate. To achieve the proposed objective the work was divided in three stages: The first one was the planning and the coordination with each hospital center, in this way, to determine the schedule of gathering of the waste can be possible. In the second stage a fieldwork was made; it consisted in gathering the quantitative and qualitative information of the general state of the handling of residuals. In the third and last stage, the information previously obtained was organized to express the results as the production rate per day by bed, generation of solid residuals for sampled services, type of solid residuals and density of the same ones. With the obtained results, approaches are settled down to either determine design parameters for final disposition whether for incineration, trituration, sanitary filler or recycling of some materials, and storage politics of the solid residuals that allow to determine the gathering frequency. The study concludes that it is necessary to improve the conditions of the residuals handling in some aspects, to provide the cleaning personnel of the equipment for gathering disposition and of security, minimum to carry out this work efficiently, and to maintain a control of all the dangerous waste, like sharp or polluted materials. In this way, an appreciable reduction is guaranteed in the impact on the atmosphere. (Author) [es

  2. Heavy Stars Thrive among Heavy Elements

    Science.gov (United States)

    2002-08-01

    VLT Observes Wolf-Rayet Stars in Virgo Cluster Galaxies [1] Summary Do very massive stars form in metal-rich regions of the Universe and in the nuclei of galaxies ? Or does "heavy element poisoning" stop stellar growth at an early stage, before young stars reach the "heavyweight class"? What may at the first glance appear as a question for specialists actually has profound implications for our understanding of the evolution of galaxies, those systems of billions of stars - the main building blocks of the Universe. With an enormous output of electromagnetic radiation and energetic elementary particles, massive stars exert a decisive influence on the surrounding (interstellar) gas and dust clouds . They also eject large amounts of processed elements, thereby participating in the gradual build-up of the many elements we see today. Thus the presence or absence of such stars at the centres of galaxies can significantly change the overall development of those regions and hence, presumably, that of the entire galaxy. A team of European astronomers [2] has now directly observed the presence of so-called Wolf-Rayet stars (born with masses of 60 - 90 times that of the Sun or more) within metal-rich regions in some galaxies in the Virgo cluster, some 50 million light-years away. This is the first unambiguous detection of such massive stellar objects in metal-rich regions . PR Photo 20a/02 : H II regions in the Virgo cluster galaxy NGC 4254 . PR Photo 20b/02 : Multi-object-slit observation of galaxy NGC 4303 . PR Photo 20c/02 : Spectrum of H II region in NGC 4254 with Wolf-Rayet signatures. Production of heavy elements in the Universe Most scientists agree that the Universe in which we live underwent a dramatic event, known as the Big Bang , approximately 15,000 million years ago. During the early moments, elementary particles were formed which after some time united into more complex nuclei and in turn resulted in the production of hydrogen and helium atoms and their isotopes

  3. Assessment of long-term pH developments in leachate from waste incineration residues

    DEFF Research Database (Denmark)

    Astrup, Thomas; Jakobsen, Rasmus; Christensen, Thomas Højlund

    2006-01-01

    influenced by changes in pH over time. The paper presents an approach for assessing pH changes in leachate from municipal solid waste incineration (MSWI) air-pollution-control (APC) residues. Residue samples were subjected to a stepwise batch extraction method in order to obtain residue samples at a range......Environmental assessment of residue disposal needs to account for long-term changes in leaching conditions. Leaching of heavy metals from incineration residues are highly affected by the leachate pH; the overall environmental consequences of disposing of these residues are therefore greatly...... range, for example, at pH 9. The paper offers a thorough basis for further modelling of incineration residue leaching and for modelling the environmental consequences of landfilling and utilization of these residues....

  4. 40 CFR 180.586 - Clothianidin; tolerances for residues.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 23 2010-07-01 2010-07-01 false Clothianidin; tolerances for residues... § 180.586 Clothianidin; tolerances for residues. (a) General. Tolerances are established for residues of the insecticide clothianidin, including its metabolites and degradates. Compliance with the tolerance...

  5. Logging residues under different stand and harvesting conditions, Rocky Mountains

    Science.gov (United States)

    Robert E. Benson; Cameron M. Johnston

    1976-01-01

    Volume and characteristics of logging residues from 34 harvest areas are presented. Clearcuts and partial cuts logged to conventional utilization levels and to close utilization levels are included. Residue volumes ranged from almost 3, 600 ft3 /acre of wood 3-inches-plus down to about 550 ft3 /acre, depending on treatment. More than 60 percent of the residues were...

  6. Heavy metals anthropogenic pollutants in Austria

    International Nuclear Information System (INIS)

    Anderl, M.; Gager, M.; Gugele, B.; Huttunen, K.; Kurzweil, A.; Poupa, S.; Ritter, M.; Wappel, D.; Wieser, M.

    2004-01-01

    Several heavy metals from anthropogenic sources are emitted in the atmosphere damaging the air quality and the human health, besides they accumulate on the soil and lately are transmitted into the human food chain. Therefore at international level there is a concern to reduce them. Austrian heavy metals emissions (cadmium, mercury and lead) during 1990-2002 are given including an analysis of causes and sources. Lead is the main pollutant and the main sector responsible is the industry. 5 figs. (nevyjel)

  7. Heavy metal removal and recovery using microorganisms

    Energy Technology Data Exchange (ETDEWEB)

    Wilde, E.W. (Westinghouse Savannah River Co., Aiken, SC (United States)); Benemann, J.R. (Benemann (J.R.), Pinole, CA (United States))

    1991-02-01

    Microorganisms -- bacteria, fungi, and microalgae -- can accumulate relatively large amounts of toxic heavy metals and radionuclides from the environment. These organisms often exhibit specificity for particular metals. The metal content of microbial biomass can be a substantial fraction of total dry weight with concentration factors (metal in dry biomass to metal in solution) exceeding one million in some cases. Both living and inert (dead) microbial biomass can be used to reduce heavy metal concentrations in contaminated waters to very low levels -- parts per billion and even lower. In many respects (e.g. specificity, residual metal concentrations, accumulation factors, and economics) microbial bioremoval processes can be superior to conventional processes, such as ion exchange and caustic (lime or hydroxide) precipitation for heavy metals removal from waste and contaminated waters. Thus, bioremoval could be developed to contribute to the clean-up of wastes at the Savannah River Site (SRS) and other DOE facilities. However, the potential advantages of bioremoval processes must still be developed into practical operating systems. A detailed review of the literature suggests that appropriate bioremoval processes could be developed for the SRS. There is great variability from one biomass source to another in bioremoval capabilities. Bioremoval is affected by pH, other ions, temperature, and many other factors. The biological (living vs. dead) and physical (immobilized vs. dispersed) characteristics of the biomass also greatly affect metal binding. Even subtle differences in the microbial biomass, such as the conditions under which it was cultivated, can have major effects on heavy metal binding.

  8. HEAVY AND THERMAL OIL RECOVERY PRODUCTION MECHANISMS

    Energy Technology Data Exchange (ETDEWEB)

    Anthony R. Kovscek

    2002-07-01

    This technical progress report describes work performed from April 1 through June 30, 2002, for the project ''Heavy and Thermal Oil Recovery Production Mechanisms.'' We investigate a broad spectrum of topics related to thermal and heavy-oil recovery. Significant results were obtained in the areas of multiphase flow and rock properties, hot-fluid injection, improved primary heavy oil recovery, and reservoir definition. The research tools and techniques used are varied and span from pore-level imaging of multiphase fluid flow to definition of reservoir-scale features through streamline-based history-matching techniques. Briefly, experiments were conducted to image at the pore level matrix-to-fracture production of oil from a fractured porous medium. This project is ongoing. A simulation studied was completed in the area of recovery processes during steam injection into fractured porous media. We continued to study experimentally heavy-oil production mechanisms from relatively low permeability rocks under conditions of high pressure and high temperature. High temperature significantly increased oil recovery rate and decreased residual oil saturation. Also in the area of imaging production processes in laboratory-scale cores, we use CT to study the process of gas-phase formation during solution gas drive in viscous oils. Results from recent experiments are reported here. Finally, a project was completed that uses the producing water-oil ratio to define reservoir heterogeneity and integrate production history into a reservoir model using streamline properties.

  9. Heavy metal removal and recovery using microorganisms

    International Nuclear Information System (INIS)

    Wilde, E.W.; Benemann, J.R.

    1991-02-01

    Microorganisms -- bacteria, fungi, and microalgae -- can accumulate relatively large amounts of toxic heavy metals and radionuclides from the environment. These organisms often exhibit specificity for particular metals. The metal content of microbial biomass can be a substantial fraction of total dry weight with concentration factors (metal in dry biomass to metal in solution) exceeding one million in some cases. Both living and inert (dead) microbial biomass can be used to reduce heavy metal concentrations in contaminated waters to very low levels -- parts per billion and even lower. In many respects (e.g. specificity, residual metal concentrations, accumulation factors, and economics) microbial bioremoval processes can be superior to conventional processes, such as ion exchange and caustic (lime or hydroxide) precipitation for heavy metals removal from waste and contaminated waters. Thus, bioremoval could be developed to contribute to the clean-up of wastes at the Savannah River Site (SRS) and other DOE facilities. However, the potential advantages of bioremoval processes must still be developed into practical operating systems. A detailed review of the literature suggests that appropriate bioremoval processes could be developed for the SRS. There is great variability from one biomass source to another in bioremoval capabilities. Bioremoval is affected by pH, other ions, temperature, and many other factors. The biological (living vs. dead) and physical (immobilized vs. dispersed) characteristics of the biomass also greatly affect metal binding. Even subtle differences in the microbial biomass, such as the conditions under which it was cultivated, can have major effects on heavy metal binding

  10. Heavy metal fate in pilot-scale sludge drying reed beds under various design and operation conditions.

    Science.gov (United States)

    Stefanakis, Alexandros I; Tsihrintzis, Vassilios A

    2012-04-30

    Thirteen pilot-scale sludge drying reed bed (SDRB) units have been constructed and operated under various settings. The beds included a cobbles lower layer, where perforated PVC aeration tubes were placed, and two gravel layers on top. The setup included planted beds with common reeds and control units. Three sludge loading rates (SLR) were examined: 30, 60 and 75 kg dm/m(2)/yr. Heavy metal (HM) accumulation in the residual sludge layer was negligible or low, and was found to increase with sludge layer depth. Plant uptake was low; the belowground biomass accumulated significantly more HMs compared to the aboveground biomass. Less than 16% of the influent HM left the bed through drainage. HM accumulation in the gravel layer was the major metal sink in the mass balance. On the whole, the HM content of the residual sludge was below the legal limits proposed by the EU for land application. Copyright © 2012 Elsevier B.V. All rights reserved.

  11. Heavy Metal Pumps in Plants

    Energy Technology Data Exchange (ETDEWEB)

    Harper, J.F.

    2000-10-01

    The long term goal of the funded research is to understand how heavy metals are taken up from the soil and translocated throughout the plant. The potential application of this research is to create plants with better heavy metal uptake systems and thereby improve the ability of these plants to help clean up toxic metals from soils. A rate limiting step is using plant for bioremediation is the normally poor capacity of plants to concentrate toxic metals. Our interest in metal ion transport systems includes those for essential mineral nutrients such as molybdenum, copper, iron, manganese, as well as toxic metals such as cerium, mercury, cesium, cadmium, arsenic and selenium. Understanding the pathways by which toxic metals accumulate in plants will enable the engineering of plants to exclude toxic metals and create healthier food sources, or to extract toxic metals from the soil as a strategy to clean up polluted lands and water.

  12. RHIC heavy ion operations performance

    CERN Document Server

    Satogata, T; Ferrone, R; Pilat, F

    2006-01-01

    The Relativistic Heavy Ion Collider (RHIC) completed its fifth year of operation in 2005, colliding copper ion beams with ps=200 GeV/u and 62.4 GeV/u[1]. Previous heavy ion runs have collided gold ions at ps=130 GeV/u, 200 GeV/u, and 62.4 GeV/u[2], and deuterons and gold ions at ps=200 GeV/u[3]. This paper discusses operational performance statistics of this facility, including Cu- Cu delivered luminosity, availability, calendar time spent in physics stores, and time between physics stores. We summarize the major factors affecting operations efficiency, and characterize machine activities between physics stores.

  13. Semiholography for heavy ion collisions

    CERN Document Server

    Mukhopadhyay, Ayan

    2017-01-01

    The formation of QGP in heavy ion collisions gives us a great opportunity for learning about nonperturbative dynamics of QCD. Semiholography provides a new consistent framework to combine perturbative and non-perturbative effects in a coherent way and can be applied to obtain an effective description for heavy ion collisions. In particular, it allows us to include nonperturbative effects in existing glasma effective theory and QCD kinetic theory for the weakly coupled saturated degrees of freedom liberated by the collisions in the initial stages in a consistent manner. We argue why the full framework should be able to confront experiments with only a few phenomenological parameters and present feasibility tests for the necessary numerical computations. Furthermore, we discuss that semiholography leads to a new description of collective flow in the form of a generalised non-Newtonian fluid. We discuss some open questions which we hope to answer in the near future.

  14. Properties of residuals for spatial point processes

    DEFF Research Database (Denmark)

    Baddeley, A.; Møller, Jesper; Pakes, A. G.

    2008-01-01

    For any point process in Rd that has a Papangelou conditional intensity λ, we define a random measure of ‘innovations' which has mean zero. When the point process model parameters are estimated from data, there is an analogous random measure of ‘residuals'. We analyse properties of the innovation...... and residuals, including first and second moments, conditional independence, a martingale property, and lack of correlation. Some large sample asymptotics are studied. We derive the marginal distribution of smoothed residuals by solving a distributional equivalence....

  15. Heavy metals in municipal solid waste deposits

    Energy Technology Data Exchange (ETDEWEB)

    Flyhammar, P.

    1997-12-01

    Extensive use of heavy metals in modern society influences routes followed by fluxes on the surface of the Earth. The changed flow paths may be harmful for the balance of biological systems at different levels, micro-organisms, human beings and whole ecosystems, since the toxicity of heavy metals is determined by their concentrations and chemical forms. Despite the low mobility of heavy metals (Zn, Cu, Pb, Cr, Ni and Cd) in municipal landfills, it was found that extensive transformations of the binding forms of heavy metal take place within the waste mass during the degradation of the waste. These changes appear to be closely related to the development of early diagenetic solid phases, i.e. new secondary solid phases formed in the waste. The heavy metals often constitute a minor part of these phases and the bindings include several forms such as adsorption, complexation, coprecipitation, precipitation, etc. It was also found that the associations between heavy metals and solid phases are dominated by several binding forms to one specific substrate rather than bindings to various solid phases. The mobility of iron and manganese seems to increase during the processes involved in waste degradation due to the solution of oxide/hydroxide phases, while the heavy metals appear to become less mobile due to their binding to organic compounds and sulphides. However, one exception in this case may be nickel. Another aspect of the transformation of heavy metals is the accumulation of pools of heavy metals which can become susceptible to environmental changes, such as oxidation or acidification. However, the risk of increased mobilization caused by lower pH values seem to be limited since municipal solid waste has a large buffer capacity. 66 refs, 9 figs, 3 tabs 66 refs, 9 figs, 3 tabs

  16. Heavy Flavour Production

    CERN Document Server

    Nason, Paolo; Ridolfi, Giovanni

    1995-01-01

    We review the status of heavy flavour production in QCD. Comparison of experimental and theoretical results for top and bottom production are given. Selected topics in charm production are also discussed.

  17. Kawasaki Heavy Industries, Ltd

    International Nuclear Information System (INIS)

    Kobayashi, T.

    1990-01-01

    This paper reports how Kawasaki Heavy Industries (KHI) has performed research in fusion nuclear technology, especially in the areas of breeding blankets, plasma facing components, tritium handling, and remote maintenance

  18. Atmospheric Heavy Metal Pollution

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 6; Issue 4. Atmospheric Heavy Metal Pollution - Development of Chronological Records and Geochemical Monitoring. Rohit Shrivastav. General Article Volume 6 Issue 4 April 2001 pp 62-68 ...

  19. Search for heavy neutrinos

    International Nuclear Information System (INIS)

    Abela, R.; Daum, M.; Eaton, G.H.; Frosch, R.; Jost, B.; Kettle, P.-R.; Steiner, E.

    1982-01-01

    The authors have measured the energy spectrum of muons from the decay of pions at rest in a scintillator. The existence of a heavy neutrino would result in an additional line in this spectrum. From the data, no evidence is found for the existence of a heavy neutrino in the mass range between 4 MeV/c 2 and 30 MeV/c 2 . (Auth.)

  20. Development of a low-temperature two-stage fluidized bed incinerator for controlling heavy-metal emission in flue gases

    International Nuclear Information System (INIS)

    Peng, Tzu-Huan; Lin, Chiou-Liang; Wey, Ming-Yen

    2014-01-01

    This study develops a low-temperature two-stage fluidized bed system for treating municipal solid waste. This new system can decrease the emission of heavy metals, has low construction costs, and can save energy owing to its lower operating temperature. To confirm the treatment efficiency of this system, the combustion efficiency and heavy-metal emission were determined. An artificial waste containing heavy metals (chromium, lead, and cadmium) was used in this study. The tested parameters included first-stage temperature and system gas velocity. Results obtained using a thermogravimetric analyzer with a differential scanning calorimeter indicated that the first-stage temperature should be controlled to at least 400 °C. Although, a large amount of carbon monoxide was emitted after the first stage, it was efficiently consumed in the second. Loss of the ignition values of ash residues were between 0.005% and 0.166%, and they exhibited a negative correlation with temperature and gas velocity. Furthermore, the emission concentration of heavy metals in the two-stage system was lower than that of the traditional one-stage fluidized bed system. The heavy-metal emissions can be decreased by between 16% and 82% using the low-temperature operating process, silica sand adsorption, and the filtration of the secondary stage. -- Graphical abstract: Heavy-metal emission concentrations in flue gases under different temperatures and gas velocities (dashed line: average of the heavy-metal emission in flue gases in the one-stage fluidized-bed incinerator). Highlights: • Low temperature two-stage system is developed to control heavy metal. • The different first-stage temperatures affect the combustion efficiency. • Surplus CO was destroyed efficiently by the secondary fluidized bed combustor. • Metal emission in two-stage system is lower than in the traditional system. • Temperature, bed adsorption, and filtration are the main control mechanisms

  1. Electrodialytically treated MSWI APC residue as substitute for cement in mortar

    DEFF Research Database (Denmark)

    Kirkelund, Gunvor Marie; Geiker, Mette Rica; Jensen, Pernille Erland

    2014-01-01

    Air pollution control (APC) residues from municipal solid waste incineration (MSWI) are considered hazardous waste and need pretreatment prior to possible reuse. Here, two MSWI APC residues, from which the most mobile fraction of heavy metals and salts has been removed by carbonation and/or elect......Air pollution control (APC) residues from municipal solid waste incineration (MSWI) are considered hazardous waste and need pretreatment prior to possible reuse. Here, two MSWI APC residues, from which the most mobile fraction of heavy metals and salts has been removed by carbonation and...... and comparable to both the reference mortar and mortar with coal fly ash. These results indicate that electrodialytic remediation could be used a pre-treatment method for MSWI APC residues prior to reuse in mortar....

  2. Residual-stress measurements

    Energy Technology Data Exchange (ETDEWEB)

    Ezeilo, A.N.; Webster, G.A. [Imperial College, London (United Kingdom); Webster, P.J. [Salford Univ. (United Kingdom)

    1997-04-01

    Because neutrons can penetrate distances of up to 50 mm in most engineering materials, this makes them unique for establishing residual-stress distributions non-destructively. D1A is particularly suited for through-surface measurements as it does not suffer from instrumental surface aberrations commonly found on multidetector instruments, while D20 is best for fast internal-strain scanning. Two examples for residual-stress measurements in a shot-peened material, and in a weld are presented to demonstrate the attractive features of both instruments. (author).

  3. Pump apparatus including deconsolidator

    Energy Technology Data Exchange (ETDEWEB)

    Sonwane, Chandrashekhar; Saunders, Timothy; Fitzsimmons, Mark Andrew

    2014-10-07

    A pump apparatus includes a particulate pump that defines a passage that extends from an inlet to an outlet. A duct is in flow communication with the outlet. The duct includes a deconsolidator configured to fragment particle agglomerates received from the passage.

  4. Fractionation characterization and speciation of heavy metals in composts and compost and compost-amended soils

    International Nuclear Information System (INIS)

    Lwegbue, C. M.A.; Emuh, F.N.; Isirimah, N.O.; Egun, A.C.

    2007-01-01

    Speciation of heavy metals in soils determines the availability for metals for plant uptake and potential for contamination of groundwater following application of composts to agricultural lands. Methods used to characterize heavy metals in solid phase of composts and compost amended soils include physical fractionation and chemical extraction. Chemical extraction schemes are most frequently used approach to fractionate trace metals in soils, sewage sludge and composts. Several variations exist in the sequential extraction procedures. These variations include reagent types, strength, volume and extraction time. A main drawback shared by all sequential extraction schemes is that the procedures themselves are complex and time consuming. This setback has been overcome by the use of ultrasound accelerated extraction which reduce the extraction time for the entire extraction steps to about 90 minutes allowing composting process to be monitored more frequently which help to provide detailed understanding of the partitioning behaviour of heavy metals. Inspite of the variability the sequential extraction schemes, they all aimed at correlating each fraction with the mobility and plant availability of each metal. Several studies have shown that phase association of heavy metal in composts include water-soluble, exchangeable, precipitated as discrete phases, co-precipitate in metal oxides and adsorbed or complexed by organic ligands and residual forms. The phase association and solubility of metals changes over composting time thereby altering metal availability. It is apparent that the positive effects of resulting from compost application far outweigh the negative effect, but more research is needed on a wide range of municipal solid waste compost with more precise determination of the fate of municipal solid waste compost applied trace metals in the environment. (author)

  5. Optical modulator including grapene

    Science.gov (United States)

    Liu, Ming; Yin, Xiaobo; Zhang, Xiang

    2016-06-07

    The present invention provides for a one or more layer graphene optical modulator. In a first exemplary embodiment the optical modulator includes an optical waveguide, a nanoscale oxide spacer adjacent to a working region of the waveguide, and a monolayer graphene sheet adjacent to the spacer. In a second exemplary embodiment, the optical modulator includes at least one pair of active media, where the pair includes an oxide spacer, a first monolayer graphene sheet adjacent to a first side of the spacer, and a second monolayer graphene sheet adjacent to a second side of the spacer, and at least one optical waveguide adjacent to the pair.

  6. Designing with residual materials

    NARCIS (Netherlands)

    Walhout, W.; Wever, R.; Blom, E.; Addink-Dölle, L.; Tempelman, E.

    2013-01-01

    Many entrepreneurial businesses have attempted to create value based on the residual material streams of third parties. Based on ‘waste’ materials they designed products, around which they built their company. Such activities have the potential to yield sustainable products. Many of such companies

  7. Detection of Gunshot Residues Using Mass Spectrometry

    Directory of Open Access Journals (Sweden)

    Regina Verena Taudte

    2014-01-01

    Full Text Available In recent years, forensic scientists have become increasingly interested in the detection and interpretation of organic gunshot residues (OGSR due to the increasing use of lead- and heavy metal-free ammunition. This has also been prompted by the identification of gunshot residue- (GSR- like particles in environmental and occupational samples. Various techniques have been investigated for their ability to detect OGSR. Mass spectrometry (MS coupled to a chromatographic system is a powerful tool due to its high selectivity and sensitivity. Further, modern MS instruments can detect and identify a number of explosives and additives which may require different ionization techniques. Finally, MS has been applied to the analysis of both OGSR and inorganic gunshot residue (IGSR, although the “gold standard” for analysis is scanning electron microscopy with energy dispersive X-ray microscopy (SEM-EDX. This review presents an overview of the technical attributes of currently available MS and ionization techniques and their reported applications to GSR analysis.

  8. Chromopolarizabilities of a heavy quark at weak coupling

    Science.gov (United States)

    Moreno, Daniel; Pineda, Antonio

    2018-01-01

    We obtain the renormalization group improved expressions of the Wilson coefficients of the heavy quark effective theory Lagrangian with leading logarithmic approximation to O (1 /m3) for the spin-independent sector, which includes the heavy quark chromopolarizabilities. Our analysis includes the effects induced by spectator quarks. We observe that the numerical impact of these logarithms is very large in most cases.

  9. Stabilization of APC residues from waste incineration with ferrous sulfate on a semi-industrial scale

    DEFF Research Database (Denmark)

    Lundtorp, Kasper; Jensen, Dorthe Lærke; Christensen, Thomas Højlund

    2002-01-01

    A stabilization method for air pollution control (APC) residues from municipal solid waste incineration (MSWI) involving mixing of the residue with water and FeSO4 has been demonstrated on a semi-industrial scale on three types of APC residues: a semidy (SD) APC residue, a fly ash (FA), and an FA...... mixed with sludge (FAS) from a wet flue gas cleaning system. The process was performed in batches of 165-175 kg residue. It generates a wastewater that is highly saline but has a low content of heavy metals such as Cd, Cr, and Pb. The stabilized and raw residues have been subject to a range of leaching...... tests: the batch leacing test, the pH-static leaching test, the availability test, and the column test. These tests showed that the stabilized residues have remarkably improved leaching properties, especially with respect to Pb but also with respect to Cd, Cu, and Zn. The release of Pb was reduced...

  10. Validation of welded joint residual stress simulation

    International Nuclear Information System (INIS)

    Computational mechanics is being increasingly applied to predict the state of residual stress in welded joints for nuclear power plant applications. Motives for undertaking such calculations include optimising the design of welded joints and weld procedures, assessing the effectiveness of mitigation processes, providing more realistic inputs to structural integrity assessments and underwriting safety cases for operating nuclear power plant. Fusion welding processes involve intense localised heating to melt the surfaces to be joined and introduction of molten weld filler metal. A complex residual stress field develops at the weld through solidification, differential thermal contraction, cyclic thermal plasticity, phase transformation and chemical diffusion processes. The calculation of weld residual stress involves detailed non-linear analyses where many assumptions and approximations have to be made. In consequence, the accuracy and reliability of solutions can be highly variable. This paper illustrates the degree of variability that can arise in weld residual stress simulation results and summarises the new R6 guidelines which aim to improve the reliability and accuracy of computational predictions. The requirements for validating weld simulations are reviewed where residual stresses are to be used in fracture mechanics analysis. This includes a discussion of how to obtain and interpret measurements from mock-ups, benchmark weldments and published data. Benchmark weldments are described that illustrate some of the issues and show how validation of numerical prediction of weld residual stress can be achieved. Finally, plans for developing the weld modelling guidelines and associated benchmarks are outlined

  11. Antibiotic Residues - A Global Health Hazard

    Directory of Open Access Journals (Sweden)

    Nisha A.R.

    Full Text Available Use of Antibiotic that might result in deposition of residues in meat, milk and eggs must not be permitted in food intended for human consumption. If use of antibiotics is necessary as in prevention and treatment of animal diseases, a withholding period must be observed until the residues are negligible or no longer detected. The use of antibiotics to bring about improved performance in growth and feed efficiency, to synchronize or control of reproductive cycle and breeding performance also often lead to harmful residual effects. Concern over antibiotic residues in food of animal origin occurs in two times; one which produces potential threat to direct toxicity in human, second is whether the low levels of antibiotic exposure would result in alteration of microflora, cause disease and the possible development of resistant strains which cause failure of antibiotic therapy in clinical situations. A withdrawal period is established to safeguard human from exposure of antibiotic added food. The withdrawal time is the time required for the residue of toxicological concern to reach safe concentration as defined by tolerance. It is the interval from the time an animal is removed from medication until permitted time of slaughter. Heavy responsibility is placed on the veterinarian and livestock producer to observe the period for a withdrawal of a drug prior to slaughter to assure that illegal concentration of drug residue in meat, milk and egg do not occur. Use of food additives may improve feed efficiency 17% in beef cattle, 10% in lambs, 15% in poultry and 15% in swine. But their indiscriminate use will produce toxicity in consumers. WHO and FAO establish tolerances for a drug, pesticide or other chemical in the relevant tissues of food producing animals. The tolerance is the tissue concentration below, which a marker residue for the drug or chemical must fall in the target tissue before that animal edible tissues are considered safe for human

  12. Phytochemicals Mediated Remediation of Neurotoxicity Induced by Heavy Metals

    OpenAIRE

    Gupta, Vivek Kumar; Singh, Shweta; Agrawal, Anju; Siddiqi, Nikhat Jamal; Sharma, Bechan

    2015-01-01

    Almost all the environmental components including both the abiotic and biotic factors have been consistently threatened by excessive contamination of heavy metals continuously released from various sources. Different heavy metals have been reported to generate adverse effects in many ways. Heavy metals induced neurotoxicity and impairment in signalling cascade leading to cell death (apoptosis) has been indicated by several workers. On one hand, these metals are required by the cellular system...

  13. Very heavy dark Skyrmions

    International Nuclear Information System (INIS)

    Dick, Rainer

    2017-01-01

    A dark sector with a solitonic component provides a means to circumvent the problem of generically low annihilation cross sections of very heavy dark matter particles. At the same time, enhanced annihilation cross sections are necessary for indirect detection of very heavy dark matter components beyond 100 TeV. Non-thermally produced dark matter in this mass range could therefore contribute to the cosmic γ-ray and neutrino flux above 100 TeV, and massive Skyrmions provide an interesting framework for the discussion of these scenarios. Therefore a Higgs portal and a neutrino portal for very heavy Skyrmion dark matter are discussed. The Higgs portal model demonstrates a dark mediator bottleneck, where limitations on particle annihilation cross sections will prevent a signal from the potentially large soliton annihilation cross sections. This problem can be avoided in models where the dark mediator decays. This is illustrated by the neutrino portal for Skyrmion dark matter. (orig.)

  14. Heavy-ion radiography

    International Nuclear Information System (INIS)

    Fabrikant, J.I.; Tobias, C.A.; Holley, W.R.; Benton, E.V.

    1981-01-01

    Heavy-particle radiography has clinical potential as a newly developed noninvasive low-dose imaging procedure that provides increased resolution of minute density differences in soft tissues of the body. The method utilizes accelerated high-energy ions, primarily carbon and neon, at the Bevalac accelerator at the Lawrence Berkeley Laboratory. The research program for medicine utilizes heavy-ion radiography for low-dose mammography, for treatment planning for cancer patients, and for imaging and accurate densitometry of skeletal structures, brain and spinal neoplasms, and the heart. The potential of heavy-ion imaging, and particularly reconstruction tomography, is now proving to be an adjunct to existing diagnostic imaging procedures in medicine, both for applications to the diagnosis, management and treatment of clinical cancer in man, and for the early detection of small soft-tissue tumors at low radiation dose

  15. Heavy-Load Lifting

    DEFF Research Database (Denmark)

    Bloomquist, Kira; Oturai, Peter; Steele, Megan L

    2018-01-01

    PURPOSE: Despite a paucity of evidence, prevention guidelines typically advise avoidance of heavy lifting in an effort to protect against breast cancer-related lymphedema. This study compared acute responses in arm swelling and related symptoms after low- and heavy-load resistance exercise among...... women at risk of lymphedema while receiving adjuvant taxane-based chemotherapy. METHODS: This is a randomized, cross-over equivalence trial. Women receiving adjuvant taxane-based chemotherapy for breast cancer who had undergone axillary lymph node dissection (n=21) participated in low- (60-65% 1...... repetition maximum (RM), two sets of 15-20 repetitions) and heavy-load (85-90% 1RM, three sets of 5-8 repetition) upper-extremity resistance exercise separated by a one-week wash-out period. Swelling was determined by bioimpedance spectroscopy and dual energy x-ray absorptiometry, with breast cancer...

  16. Effect of hydrothermal carbonization on migration and environmental risk of heavy metals in sewage sludge during pyrolysis.

    Science.gov (United States)

    Liu, Tingting; Liu, Zhengang; Zheng, Qingfu; Lang, Qianqian; Xia, Yu; Peng, Nana; Gai, Chao

    2018-01-01

    The heavy metals distribution during hydrothermal carbonization (HTC) of sewage sludge, and pyrolysis of the resultant hydrochar was investigated and compared with raw sludge pyrolysis. The results showed that HTC reduced exchangeable/acid-soluble and reducible fraction of heavy metals and lowered the potential risk of heavy metals in sewage sludge. The pyrolysis favored the transformation of extracted/mobile fraction of heavy metals to residual form especially at high temperature, immobilizing heavy metals in the chars. Compared to the chars from raw sludge pyrolysis, the chars derived from hydrochar pyrolysis was more alkaline and had lower risk and less leachable heavy metals, indicating that pyrolysis imposed more positive effect on immobilization of heavy metals for the hydrochar than for sewage sludge. The present study demonstrated that HTC is a promising pretreatment prior to pyrolysis from the perspective of immobilization of heavy metals in sewage sludge. Copyright © 2017 Elsevier Ltd. All rights reserved.

  17. Heavy metal input to agricultural soils from irrigation with treated wastewater: Insight from Pb isotopes

    Science.gov (United States)

    Kloppmann, Wolfram; Cary, Lise; Psarras, Georgios; Surdyk, Nicolas; Chartzoulakis, Kostas; Pettenati, Marie; Maton, Laure

    2010-05-01

    A major objective of the EU FP6 project SAFIR was to overcome certain drawbacks of wastewater reuse through the development of a new irrigation technology combining small-scale modular water treatment plants on farm level and improved irrigation hardware, in the aim to lower the risks related to low quality water and to increase water use efficiency. This innovative technology was tested in several hydro-climatic contexts (Crete, Italy, Serbia, China) on experimental irrigated tomato and potato fields. Here we present the heavy metal variations in soil after medium-term (3 irrigation seasons from 2006-2008) use of treated municipal wastewater with a special focus on lead and lead isotope signatures. The experimental site is located in Chania, Crete. A matrix of plots were irrigated, combining different water qualities (secondary, primary treated wastewater, tap water, partially spiked with heavy metals, going through newly developed tertiary treatment systems) with different irrigation strategies (surface and subsurface drip irrigation combined with full irrigation and partial root drying). In order to assess small scale heavy metal distribution around a drip emitter, Pb isotope tracing was used, combined with selective extraction. The sampling for Pb isotope fingerprinting was performed after the 3rd season of ww-irrigation on a lateral profile from a drip irrigator (half distance between drip lines, i.e. 50cm) and three depth intervals (0-10, 10-20, 20-40 cm). These samples were lixiviated through a 3 step selective extraction procedure giving rise to the bio-accessible, mobile and residual fraction: CaCl2/NaNO3 (bio-accessible fraction), DPTA (mobile fraction), total acid attack (residual fraction). Those samples were analysed for trace elements (including heavy metals) and major inorganic compounds by ICP-MS. The extracted fractions were then analysed by Thermal Ionisation Mass Spectrometry (TIMS) for their lead isotope fingerprints (204Pb, 206Pb, 207Pb, 208Pb

  18. Residual N effects from livestock manure inputs to soils

    DEFF Research Database (Denmark)

    Schröder, Jaap; Bechini, Luca; Bittman, Shabtai

    Organic inputs including livestock manures provide nitrogen (N) to crops beyond the year of their application. This so-called residual N effect should be taken into account when making decisions on N rates for individual fields, but also when interpreting N response trials in preparation...... of recommendations. This paper addresses general principles of residual N effects, gives literature-based estimates of them, and reviews to which extent residual N effects are included in ecommendations and regulations in selected countries....

  19. Residual stresses in material processing

    Science.gov (United States)

    Kozaczek, K. J.; Watkins, T. R.; Hubbard, C. R.; Wang, Xun-Li; Spooner, S.

    Material manufacturing processes often introduce residual stresses into the product. The residual stresses affect the properties of the material and often are detrimental. Therefore, the distribution and magnitude of residual stresses in the final product are usually an important factor in manufacturing process optimization or component life prediction. The present paper briefly discusses the causes of residual stresses. It then addresses the direct, nondestructive methods of residual stress measurement by X ray and neutron diffraction. Examples are presented to demonstrate the importance of residual stress measurement in machining and joining operations.

  20. SRC Residual fuel oils

    Science.gov (United States)

    Tewari, Krishna C.; Foster, Edward P.

    1985-01-01

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  1. Chromosome Aberrations by Heavy Ions

    Science.gov (United States)

    Ballarini, Francesca; Ottolenghi, Andrea

    It is well known that mammalian cells exposed to ionizing radiation can show different types of chromosome aberrations (CAs) including dicentrics, translocations, rings, deletions and complex exchanges. Chromosome aberrations are a particularly relevant endpoint in radiobiology, because they play a fundamental role in the pathways leading either to cell death, or to cell conversion to malignancy. In particular, reciprocal translocations involving pairs of specific genes are strongly correlated (and probably also causally-related) with specific tumour types; a typical example is the BCR-ABL translocation for Chronic Myeloid Leukaemia. Furthermore, aberrations can be used for applications in biodosimetry and more generally as biomarkers of exposure and risk, that is the case for cancer patients monitored during Carbon-ion therapy and astronauts exposed to space radiation. Indeed hadron therapy and astronauts' exposure to space radiation represent two of the few scenarios where human beings can be exposed to heavy ions. After a brief introduction on the main general features of chromosome aberrations, in this work we will address key aspects of the current knowledge on chromosome aberration induction, both from an experimental and from a theoretical point of view. More specifically, in vitro data will be summarized and discussed, outlining important issues such as the role of interphase death/mitotic delay and that of complex-exchange scoring. Some available in vivo data on cancer patients and astronauts will be also reported, together with possible interpretation problems. Finally, two of the few available models of chromosome aberration induction by ionizing radiation (including heavy ions) will be described and compared, focusing on the different assumptions adopted by the authors and on how these models can deal with heavy ions.

  2. Protein structure based prediction of catalytic residues

    Science.gov (United States)

    2013-01-01

    Background Worldwide structural genomics projects continue to release new protein structures at an unprecedented pace, so far nearly 6000, but only about 60% of these proteins have any sort of functional annotation. Results We explored a range of features that can be used for the prediction of functional residues given a known three-dimensional structure. These features include various centrality measures of nodes in graphs of interacting residues: closeness, betweenness and page-rank centrality. We also analyzed the distance of functional amino acids to the general center of mass (GCM) of the structure, relative solvent accessibility (RSA), and the use of relative entropy as a measure of sequence conservation. From the selected features, neural networks were trained to identify catalytic residues. We found that using distance to the GCM together with amino acid type provide a good discriminant function, when combined independently with sequence conservation. Using an independent test set of 29 annotated protein structures, the method returned 411 of the initial 9262 residues as the most likely to be involved in function. The output 411 residues contain 70 of the annotated 111 catalytic residues. This represents an approximately 14-fold enrichment of catalytic residues on the entire input set (corresponding to a sensitivity of 63% and a precision of 17%), a performance competitive with that of other state-of-the-art methods. Conclusions We found that several of the graph based measures utilize the same underlying feature of protein structures, which can be simply and more effectively captured with the distance to GCM definition. This also has the added the advantage of simplicity and easy implementation. Meanwhile sequence conservation remains by far the most influential feature in identifying functional residues. We also found that due the rapid changes in size and composition of sequence databases, conservation calculations must be recalibrated for specific

  3. Antifibrinolytics for heavy menstrual bleeding.

    Science.gov (United States)

    Lethaby, A; Farquhar, C; Cooke, I

    2000-01-01

    heavy menstrual bleeding were excluded. Fifteen eligible trials were assessed by three reviewers and eight of these did not meet with the inclusion criteria. Of the seven remaining trials, four of these could be included within the meta-analysis. The remaining three trials had a crossover design and despite contacting the authors and appropriate companies, we were unable to extract the results in a format suitable to include these within the meta-analysis. However the results are included within the text of the review for discussion. Antifibrinolytic therapy compared to placebo showed a significant reduction in mean blood loss (WMD -94.0 [-151.4, -36.5]) and significant change in mean reduction of blood loss (WMD -110.2 [-146.5, -73.8]). This objective improvement was not mirrored by a patient perceived improvement in monthly menstrual blood loss (RR 2.5 [0.9, 7.3]) in the one study which recorded this outcome (~~ Edlund 1995~~). Antifibrinolytic agents were compared to only three other medical (non-surgical) therapies: mefenamic acid, norethisterone administered in the luteal phase and ethamsylate. In all instances, there was a significant reduction in mean blood loss (WMD -73.0 [-123.4, -22.6], WMD -111.0 [-178.5, -43.5] and (WMD -100 [-143.9, -56.1] respectively) and a strong, although non-significant trend in favour of tranexamic acid in the participants' perception of an improvement in menstrual blood loss. There were no significant differences in the frequency of reported side effects with tranexamic acid when compared to oral luteal phase progestogens (RR 0.4 [0.1, 1.2]) or withdrawal from treatment because of adverse events when compared with NSAIDs and ethamsylate when these treatments were used for heavy menstrual bleeding. Change in the quality of life measures, flooding and leakage and sex life, were significantly improved in the tranexamic acid group when compared to the oral progestagen group. These findings are based in most cases on

  4. Atmospheric Heavy Metal Pollution

    Indian Academy of Sciences (India)

    within and below cloud scavenging, whereby the wet aerosol particles are collected by falling raindrops. In occult deposition, wetted particles (fog and mist) are deposited by impaction or turbulent transfer [3]. A high proportion of atmospheric heavy metals entering aquatic systems is in small particulate « IJlm) or soluble ...

  5. Heavy liquid bubble chamber

    CERN Multimedia

    CERN PhotoLab

    1965-01-01

    The CERN Heavy liquid bubble chamber being installed in the north experimental hall at the PS. On the left, the 1180 litre body; in the centre the magnet, which can produce a field of 26 800 gauss; on the right the expansion mechanism.

  6. Heavy quarks photoproduction

    International Nuclear Information System (INIS)

    Cacciari, M.

    1996-08-01

    The state of the art of the theoretical calculations for heavy quarks photoproduction is reviewed. The full next-to-leading order calculation and two possible resummations, the high energy one for total cross sections and the large p T one for differential cross sections, are described. (orig.)

  7. Heavy-ion radiography and heavy-ion computed tomography

    International Nuclear Information System (INIS)

    Fabrikant, J.I.; Holley, W.R.; McFarland, E.W.; Tobias, C.a.

    1982-02-01

    Heavy-ion projection and CT radiography is being developed into a safe, low-dose, noninvasive radiological procedure that can quantitate and image small density differences in human tissues. The applications to heavy-ion mammography and heavy-ion CT imaging of the brain in clinical patients suggest their potential value in cancer diagnosis

  8. Heavy-ion radiography and heavy-ion computed tomography

    Energy Technology Data Exchange (ETDEWEB)

    Fabrikant, J.I.; Holley, W.R.; McFarland, E.W.; Tobias, C.a.

    1982-02-01

    Heavy-ion projection and CT radiography is being developed into a safe, low-dose, noninvasive radiological procedure that can quantitate and image small density differences in human tissues. The applications to heavy-ion mammography and heavy-ion CT imaging of the brain in clinical patients suggest their potential value in cancer diagnosis.

  9. Measurement of volatiles, semi-volatiles and heavy metals in an oil burn test

    International Nuclear Information System (INIS)

    Li, K.; Caron, T.; Landriault, M.; Pare, J.R.J.; Fingas, M.

    1992-01-01

    Tests involving meso-scale burning of Louisiana crude oil were conducted, and during each burn, extensive samples were taken from the oil, residue, and the smoke plume. The detailed analytical work employed to obtain and analyze the burn samples is outlined and discussed. The analytical parameters included volatiles and semi-volatiles of environmental interests as well as heavy metals typically contained in the starting crude oil. Because the smoke plume did not always impinge on the samplers, the ground samplers did not collect sufficient samples for a definitive analysis. Crude/residue analyses showed the burn resulted in a significant reduction of polycyclic aromatic hydrocarbons (PAH) in the original oil. Most of the reduction was thought to be simply evaporation or destruction from combustion. The residue did not have the degree of enrichment of the higher molecular weight PAHs as was the case in bench-scale burn experiments. Volatile organic compound and dioxin/furan measurements likewise did not show high levels of contamination from the burn itself. Most of the elevated levels of contaminants could probably be due to evaporation of the oil itself. Insufficient sampling was conducted to investigate the background levels from the weathering process. A novel means of sampling using a small remote controlled helicopter was attempted and sufficiently interesting results were obtained to indicate the potential of this passive sampling device for future work. 5 refs., 4 figs

  10. Atmospheric heavy metal deposition in Europe estimated by moss analysis

    Energy Technology Data Exchange (ETDEWEB)

    Ruehling, Aa. [Swedish Environmental Research Inst., Lund (Sweden). Dept. of Ecology

    1995-12-31

    Atmospheric heavy metal deposition in Europe including 21 countries was monitored in 1990-1992 by the moss technique. This technique is based on the fact that the concentrations of heavy metals in moss are closely correlated to atmospheric deposition. This was the first attempt to map heavy metal deposition in this large area. The objectives of the project were to characterise qualitatively and quantitatively the regional atmospheric deposition pattern of heavy metals in background areas in Europe, to indicate the location of important heavy metal pollution sources and to allow retrospective comparisons with similar studies. The present survey is a follow-up of a joint Danish and Swedish project in 1980 and an extended survey in 1985 within the framework of the Nordic Council of Ministers. In Sweden, heavy-metal deposition was first mapped on a nation-wide scale in 1968-1971 and 1975. (author)

  11. Heavy metal ions are potent inhibitors of protein folding.

    Science.gov (United States)

    Sharma, Sandeep K; Goloubinoff, Pierre; Christen, Philipp

    2008-07-25

    Environmental and occupational exposure to heavy metals such as cadmium, mercury and lead results in severe health hazards including prenatal and developmental defects. The deleterious effects of heavy metal ions have hitherto been attributed to their interactions with specific, particularly susceptible native proteins. Here, we report an as yet undescribed mode of heavy metal toxicity. Cd2+, Hg2+ and Pb2+ proved to inhibit very efficiently the spontaneous refolding of chemically denatured proteins by forming high-affinity multidentate complexes with thiol and other functional groups (IC(50) in the nanomolar range). With similar efficacy, the heavy metal ions inhibited the chaperone-assisted refolding of chemically denatured and heat-denatured proteins. Thus, the toxic effects of heavy metal ions may result as well from their interaction with the more readily accessible functional groups of proteins in nascent and other non-native form. The toxic scope of heavy metals seems to be substantially larger than assumed so far.

  12. Adsorption of heavy metal in freeway by asphalt block

    Science.gov (United States)

    Zheng, Chaocheng

    2017-08-01

    Heavy metals are toxic, persistent, and carcinogenic in freeway. Various techniques are available for the removal of heavy metals from waste water among soils during freeway including ion-exchange, membrane filtration, electrolysis, coagulation, flotation, and adsorption. Among them, bio-sorption processes are widely used for heavy metal and other pollutant removal due to its sustainable, rapid and economic. In this paper, heavy metal removal facilitated by adsorption in plants during freeway was illustrated to provide concise information on exploring the adsorption efficiency.

  13. Residues and contaminants in tea and tea infusions: a review.

    Science.gov (United States)

    Abd El-Aty, A M; Choi, Jeong-Heui; Rahman, Md Musfiqur; Kim, Sung-Woo; Tosun, Alev; Shim, Jae-Han

    2014-01-01

    Consumers are very aware of contaminants that could pose potential health hazards. Most people drink tea as an infusion (adding hot water); however, in some countries, including India, China and Egypt, tea is drunk as a decoction (tea and water are boiled together). An infusion usually brings the soluble ingredients into solution, whereas a decoction brings all soluble and non-soluble constituents together. Therefore, a cup of tea may contain various kinds of contaminants. This review focuses on green and black tea because they are most commonly consumed. The target was to examine the transfer rate of contaminants - pesticides, environmental pollutants, mycotoxins, microorganisms, toxic heavy metals, radioactive isotopes (radionuclides) and plant growth regulators - from tea to infusion/brewing, factors contributing to the transfer potential and contaminants degradation, and residues in or on the spent leaves. It is concluded that most contaminants leaching into tea infusion are not detected or are detected at a level lower than the regulatory limits. However, the traditional practice of over-boiling tea leaves should be discouraged as there may be a chance for more transfer of contaminants from the tea to the brew.

  14. Heavy Ion Physics at CMS

    CERN Document Server

    Veres, Gabor

    2017-01-01

    In the present proceedings recent heavy ion results from the Compact Muon Solenoid collaboration at the LHC are presented. These contain comparisons between small and large collision systems, as well as studies of energy evolution, thus include data collected in proton-proton collisions at 13 TeV (2015 and 2016), proton-proton and lead-lead collisions at 5 TeV (2015), and proton-lead collisions at 5 TeV and 8 TeV (2016) center-of-mass energy per nucleon pair. They provide new insights into the properties of the extremely high density and high temperature matter created in heavy ion collisions, while pointing out similarities and differences in comparison to smaller collision systems. These include gluon distribution functions in the lead nucleus; the azimuthal anisotropy of final state particle distributions in all the three different collision systems; charge separation signals from proton-lead collisions and consequences for the Chiral Magnetic Effect; new studies of parton energy loss and its dependence on...

  15. Quadratic residues and non-residues selected topics

    CERN Document Server

    Wright, Steve

    2016-01-01

    This book offers an account of the classical theory of quadratic residues and non-residues with the goal of using that theory as a lens through which to view the development of some of the fundamental methods employed in modern elementary, algebraic, and analytic number theory. The first three chapters present some basic facts and the history of quadratic residues and non-residues and discuss various proofs of the Law of Quadratic Reciprosity in depth, with an emphasis on the six proofs that Gauss published. The remaining seven chapters explore some interesting applications of the Law of Quadratic Reciprocity, prove some results concerning the distribution and arithmetic structure of quadratic residues and non-residues, provide a detailed proof of Dirichlet’s Class-Number Formula, and discuss the question of whether quadratic residues are randomly distributed. The text is a valuable resource for graduate and advanced undergraduate students as well as for mathematicians interested in number theory.

  16. Reactivity of Athabasca residue and of its SARA fractions during residue hydroconversion

    Energy Technology Data Exchange (ETDEWEB)

    Verstraete, J.; Danial-Fortain, P.; Gauthier, T.; Merdrignac, I. [IFP-Lyon, Vermaison (France); Budzinski, H. [Bordeaux Univ. (France). ISM-LPTC, UMR CNRS

    2009-07-01

    Residue conversion processes are becoming increasingly important because of the declining market for residual fuel oil and a greater demand for middle distillates. Ebullated-bed hydroconversion is a commercially proven technology for converting heavy feedstocks with high amounts of impurities. The process enables the conversion of atmospheric or vacuum residues at temperatures up to 440 degrees C, and at liquid hourly space velocity (LHSV) conditions in the range of 0.15 to 0.5 per hour. A 540 degrees C conversion of up to 80 weight per cent can be achieved under these conditions. This paper reported on a research study conducted at IFP Lyon in which the residue hydroconversion in a large-scale ebullated bed bench unit was investigated to determine the impact of operating conditions and feed properties on yield and product qualities. Hydrogen was added to the feed in the bench units to keep a high hydrogen partial pressure and favour the catalytic hydroconversion reactions. In a typical test, the reactor was fed with 50 g of feedstock and 0.45 g of crushed equilibrium industrial NiMo catalyst, pressurized hydrogen and quickly heated at the reaction temperature. This paper also discussed the conversion of Athabasca bitumen residue in the large-scale pilot plant and also in the small scale batch reactor. The effect of operating temperature and space velocity was examined. The reactivity of the saturates, aromatics, resins and asphaltenes (SARA) fractions of the bitumen was studied separately in order to better understand the conversion mechanisms and reactivities. The Athabasca bitumen feed and SARA fractions were also analyzed in terms of standard petroleum analysis, SARA fractionation, elemental analysis, size exclusion chromatography (SEC) and 13C NMR. Hydroconversion experiments were conducted in the batch unit at different reaction temperatures and reaction times. A comparison of small-scale batch results with those obtained with the continuous large-scale bench

  17. Heavy Metal Uptake by Novel Miscanthus Seed-Based Hybrids Cultivated in Heavy Metal Contaminated Soil

    Directory of Open Access Journals (Sweden)

    Krzyżak Jacek

    2017-09-01

    Full Text Available When heavy metal contaminated soils are excluded from food production, biomass crops offer an alternative commercial opportunity. Perennial crops have potential for phytoremediation. Whilst the conditions at heavy metal contaminated sites are challenging, successful phytoremediation would bring significant economic and social benefits. Seed-based Miscanthus hybrids were tested alongside the commercial clone Miscanthus × giganteus on arable land, contaminated with Pb, Cd and Zn near Katowice. Before the randomized experimental plots were established (25m2 plots with plant density 2/m2 ‘time-zero’ soil samples were taken to determine initial levels of total (aqua regia and bioavailable (CaCl2 extraction concentration of Pb, Cd and Zn. After the growing season plant material was sampled during autumn (October, green harvest and winter (March, brown harvest to determine differences in heavy metal uptake. Results after the first growing season are presented, including the plot establishment success, biomass yield and heavy metal uptake.

  18. Heavy Metal Uptake by Novel Miscanthus Seed-Based Hybrids Cultivated in Heavy Metal Contaminated Soil

    Science.gov (United States)

    Krzyżak, Jacek; Pogrzeba, Marta; Rusinowski, Szymon; Clifton-Brown, John; McCalmont, Jon Paul; Kiesel, Andreas; Mangold, Anja; Mos, Michal

    2017-09-01

    When heavy metal contaminated soils are excluded from food production, biomass crops offer an alternative commercial opportunity. Perennial crops have potential for phytoremediation. Whilst the conditions at heavy metal contaminated sites are challenging, successful phytoremediation would bring significant economic and social benefits. Seed-based Miscanthus hybrids were tested alongside the commercial clone Miscanthus × giganteus on arable land, contaminated with Pb, Cd and Zn near Katowice. Before the randomized experimental plots were established (25m2 plots with plant density 2/m2) `time-zero' soil samples were taken to determine initial levels of total (aqua regia) and bioavailable (CaCl2 extraction) concentration of Pb, Cd and Zn. After the growing season plant material was sampled during autumn (October, green harvest) and winter (March, brown harvest) to determine differences in heavy metal uptake. Results after the first growing season are presented, including the plot establishment success, biomass yield and heavy metal uptake.

  19. Heavy metal contamination in bats in Britain

    International Nuclear Information System (INIS)

    Walker, L.A.; Simpson, V.R.; Rockett, L.; Wienburg, C.L.; Shore, R.F.

    2007-01-01

    Toxic metals are bioaccumulated by insectivorous mammals but few studies (none from Britain) have quantified residues in bats. We measured renal mercury (Hg), lead (Pb) and cadmium (Cd) concentrations in bats from south-west England to determine how they varied with species, sex, age, and over time, and if they were likely to cause adverse effects. Residues were generally highest in whiskered bats (Myotis mystacinus). Compared with other species, pipistrelle (Pipistrellus spp) and Natterer's bats (Myotis nattereri) had significantly lower kidney Hg and Pb concentrations, respectively. Renal Hg increased over time in pipistrelles but the contributory sources are unknown. Kidney Pb did not decrease over time despite concurrent declines in atmospheric Pb. Overall, median renal metal concentrations were similar to those in bats from mainland Europe and 6- to 10-fold below those associated with clinical effect, although 5% of pipistrelles had kidney Pb residues diagnostic of acute lead poisoning. - Heavy metal contamination has been quantified in bats from Britain for the first time and indicates increased accumulation of Hg and no reduction in Pb

  20. Water issues associated with heavy oil production.

    Energy Technology Data Exchange (ETDEWEB)

    Veil, J. A.; Quinn, J. J.; Environmental Science Division

    2008-11-28

    Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.

  1. Study of Correlation Between Heavy Metal Concentration, Street ...

    African Journals Online (AJOL)

    This study was aimed at evaluating heavy metal contents in street dust of five major roads within the trunk of Kano metropolis. The dust were collected from heavy traffic roads of the city which include Zaria road (ZR), Maiduguri road (MR), Katsina road (KR), Hadejia road (HR) and Bayero University Kano road (BR).

  2. Proceedings of the Budapest workshop on relativistic heavy ion collisions

    International Nuclear Information System (INIS)

    Csoergoe, T.; Hegyi, S.; Levai, P.

    1993-04-01

    This volume is the Proceedings of the Budapest workshop on relativistic heavy ion collisions held in Budapest, 10-13 Aug, 1992. The topics include experimental heavy ion physics, Bose-Einstein correlations, intermittency, relativistic transport theory, Quark-Gluon Plasma rehadronization, astronuclear physics and cosmology. All contributions were indexed and abstracted. (author)

  3. Fractionation, characterization and speciation of heavy metals in ...

    African Journals Online (AJOL)

    Speciation of heavy metals in soils determines the availability for metals for plant uptake and potential for contamination of groundwater following application of composts to agricultural lands. Methods used to characterize heavy metals in solid phase of composts and compost amended soils include physical fractionation ...

  4. Extra Z neutral bosons, families and heavy fermions

    International Nuclear Information System (INIS)

    Li Tiezhong

    1989-08-01

    The minimal Grand Unified Theories with three-family should include two extra Z neufral bosons which belong to the different broken scales. Georgi's argument on heavy Dirac fermions has been realized. These fermions should not be bizarre. The extra Z and Dirac fermions are not too heavy. The difficulty of the proton decay may be resolved

  5. Evaluation of heavy metal uptake and translocation by Acacia ...

    African Journals Online (AJOL)

    Many organic and inorganic pollutants, including heavy metals are being transported and mixed with the cultivated soils and water. Heavy metals are the most dangerous pollutants as they are nondegradable and accumulate and become toxic to plants and animals. An experiment was conducted in the glasshouse to ...

  6. Comparative Studies on Mosses for Heavy Metals Pollution ...

    African Journals Online (AJOL)

    The sources of these heavy metals were discovered to include: vehicular emission and incineration of domestic wastes and the heavy metals from these sources were discovered to pose severe toxicological risks to the environment and human health. Samples of mosses were collected at eight different locations in each ...

  7. Sharing Residual Liability

    DEFF Research Database (Denmark)

    Carbonara, Emanuela; Guerra, Alice; Parisi, Francesco

    2016-01-01

    Economic models of tort law evaluate the efficiency of liability rules in terms of care and activity levels. A liability regime is optimal when it creates incentives to maximize the value of risky activities net of accident and precaution costs. The allocation of primary and residual liability...... the virtues and limits of loss-sharing rules in generating optimal (second-best) incentives and allocations of risk. We find that loss sharing may be optimal in the presence of countervailing policy objectives, homogeneous risk avoiders, and subadditive risk, which potentially offers a valuable tool...

  8. Survival-mediated capture and fusion cross sections for heavy-element synthesis

    Science.gov (United States)

    Yao, L.; Loveland, W.

    2018-01-01

    The cross section for producing a heavy evaporation residue σEVR in a fusion reaction can be written as a product of three nonseparable factors, i.e., the capture cross section, the fusion probability PCN, and the survival probability Wsur. Each of these factors is dependent on the spin. However, one must remember that the Wsur term is zero or very small for higher spin values, thus effectively limiting the capture and fusion terms. For a series of ˜287 reactions leading to heavy evaporation residues with ZCN≤110 , we point out the implications of this fact for capture cross sections for heavy element formation reactions. From a comparison of calculated and measured evaporation residue cross sections we deduce values of the fusion probability PCN for some of these reactions.

  9. Some theoretical issues in heavy flavour physics

    Indian Academy of Sciences (India)

    Some of the recent developments in heavy flavour physics will be reviewed. This will include an update on some of the Standard Model predictions, and a summary of recent measurements that may indicate the presence of new physics (NP). The focus will be on selected models of NP that are indicated by the anomalies in ...

  10. Accelerator development for heavy ion fusion

    International Nuclear Information System (INIS)

    Talbert, W.L. Jr.; Sawyer, G.A.

    1980-01-01

    Accelerator technology development is presented for heavy ion drivers used in inertial confinement fusion. The program includes construction of low-velocity ''test bed'' accelerator facilities, development of analytical and experimental techniques to characterize ion beam behavior, and the study of ion beam energy deposition

  11. Detectors for relativistic heavy-ion experiments

    International Nuclear Information System (INIS)

    Braun-Munzinger, P.; Cleland, W.; Young, G.R.

    1989-04-01

    We present in some detail an overview of the detectors currently used in relativistic heavy-ion research at the BNL AGS and the CERN SPS. Following that, a detailed list of RandD projects is given, including specific areas of work which need to be addressed in preparation for further experiments at the AGS and SPS for the upcoming experiments at RHIC

  12. Non-perturbative Heavy Quark Effective Theory

    DEFF Research Database (Denmark)

    Della Morte, Michele; Heitger, Jochen; Simma, Hubert

    2015-01-01

    We review a lattice strategy how to non-perturbatively determine the coefficients in the HQET expansion of all components of the heavy-light axial and vector currents, including 1/m_h-corrections. We also discuss recent preliminary results on the form factors parameterizing semi-leptonic B-decays...

  13. Pions from and about heavy ions

    Energy Technology Data Exchange (ETDEWEB)

    Rasmussen, J.O.

    1982-09-01

    A review is presented of the possibilities of pion production with heavy ion reactions. Major headings include: pion thermometry; hills and valleys in pion spectra; pionic orbits of nuclear size; pion confinement in the fireball; anomalons; and Schroedinger equation solutions for pionic atoms. 47 references, 9 figures. (GHT)

  14. The Electronic Structure of Heavy Element Complexes

    Energy Technology Data Exchange (ETDEWEB)

    Bursten, Bruce E.

    2000-07-25

    The area of study is the bonding in heavy element complexes, and the application of more sophisticated electronic structure theories. Progress is recounted in several areas: (a) technological advances and current methodologies - Relativistic effects are extremely important in gaining an understanding of the electronic structure of compounds of the actinides, transactinides, and other heavy elements. Therefore, a major part of the continual benchmarking was the proper inclusion of the appropriate relativistic effects for the properties under study. (b) specific applications - These include organoactinide sandwich complexes, CO activation by actinide atoms, and theoretical studies of molecules of the transactinide elements. Finally, specific directions in proposed research are described.

  15. Heavy ion induced mutation in arabidopsis

    Energy Technology Data Exchange (ETDEWEB)

    Tano, Shigemitsu [Japan Atomic Energy Research Inst., Takasaki, Gunma (Japan). Takasaki Radiation Chemistry Research Establishment

    1997-03-01

    Heavy ions, He, C, Ar and Ne were irradiated to the seeds of Arabidopsis thaliana for inducing the new mutants. In the irradiated generation (M{sub 1}), germination and survival rate were observed to estimate the relative biological effectiveness in relation to the LET including the inactivation cross section. Mutation frequencies were compared by using three kinds of genetic loci after irradiation with C ions and electrons. Several interesting new mutants were selected in the selfed progenies of heavy ion irradiated seeds. (author)

  16. Heavy Flavour Production and Decay at ATLAS

    CERN Document Server

    Jones, RWL; The ATLAS collaboration

    2013-01-01

    ATLAS is taking advantage of its large integrated luminosity band sophisticated muon and dimuon triggers to make competitive measurements of heavy flavour production and decay. Inclusive production and heavy flavour jet production is discussed before turning to charm and onium production. The production and decay of individual B hadron species is then addressed, including the current best measurement of the Λb lifetime. A much improved analysis of CP related quantities in Bs decays is presented, before turning to recent results and prospects for rare B decays.

  17. Heavy-ion driver design and scaling

    International Nuclear Information System (INIS)

    Bieri, R.; Monsler, M.; Meier, W.; Stewart, L.

    1992-01-01

    Parametric models for scaling heavy-ion driver designs are described. Scaling of target performance and driver cost is done for driver parameters including driver energy, number of beams, type of superconductor used in focusing magnets, maximum magnetic field allowed at the superconducting windings, linear quadrupole array packing fraction mass, and ion charge state. The cumulative accelerator voltage and beam currents are determined from the Maschke limits on beam current for each choice of driver energy and post-acceleration pulse duration. The heavy-ion driver is optimized over the large available driver parameter space. Parametric studies and the choice of a base driver model are described in a companion paper

  18. Heavy mineral potential of Athabasca oil sands

    Energy Technology Data Exchange (ETDEWEB)

    Coward, J.; Oxenford, J. [Syncrude Canada Ltd., Edmonton, AB (Canada)

    1997-11-01

    There are three large scale production operations in the Athabasca oil sands: (1) Syncrude, a surface mining plant that has been operating since 1978 at a current synthetic oil production rate of over 205,000 barrels per day, (2) the Suncor operation, also a surface mining plant, in operation since 1967 and producing about 80,000 barrels per day of synthetic oil and (3) Esso`s Cold Lake operation, an in-situ operation that extracts the oil from the deposits in the ground and produces about 95,000 barrels per day of bitumen. The presence of heavy metals in the Athabasca oil sands was discussed, emphasizing current trends in the heavy mineral industry and various conditions and options for the development of this resource. The typical heavy minerals include magnetite, ilmenite, leucoxene, rutile, zircon, monazite, sillimanite, kyanite, and garnet. Several potentially attractive investment options exist to develop this byproduct of oil sands mining. The potential impact on the heavy mineral industry that may result from the development of heavy minerals from oil sands was also explored. 23 refs., 10 tabs., 5 figs.

  19. Diagnostics of heavy impurities at GOL-3 facility

    Science.gov (United States)

    Sorokina, N.; Burdakov, A.; Ivanov, I.; Kuklin, K.; Polosatkin, S.; Popov, S.; Postupaev, V.; Rovenskikh, A.; Shoshin, A.; Schudlo, I.

    2010-11-01

    Multimirror approach to plasma confinement for fusion is studied at GOL-3 facility in the Budker Institute of Nuclear Physics (Novosibirsk, Russia). The presented work is devoted to diagnostics of heavy impurities in plasma of this facility. The main purpose is quantitative measurement of density, degree of ionization of the main heavy impurities in plasma and their contribution to an effective charge of plasma at the GOL-3 facility. Density of interested elements was measured by optical spectroscopy and mass-spectroscopy of residual vacuum. A number of spectroscopic diagnostics has been developed for this purpose. Experimental data were compared with results of numerical calculations of impurities dynamics. As a result it is revealed that the contribution of heavy impurities to effective charge of plasma does not exceed 20%; thus the presence of impurities in plasma of the GOL-3 facility does not influence essentially the plasma confinement at the multimirror trap.

  20. Diagnostics of heavy impurities at GOL-3 facility

    International Nuclear Information System (INIS)

    Sorokina, N.; Burdakov, A.; Ivanov, I.; Kuklin, K.; Polosatkin, S.; Popov, S.; Postupaev, V.; Rovenskikh, A.; Shoshin, A.; Schudlo, I.

    2010-01-01

    Multimirror approach to plasma confinement for fusion is studied at GOL-3 facility in the Budker Institute of Nuclear Physics (Novosibirsk, Russia). The presented work is devoted to diagnostics of heavy impurities in plasma of this facility. The main purpose is quantitative measurement of density, degree of ionization of the main heavy impurities in plasma and their contribution to an effective charge of plasma at the GOL-3 facility. Density of interested elements was measured by optical spectroscopy and mass-spectroscopy of residual vacuum. A number of spectroscopic diagnostics has been developed for this purpose. Experimental data were compared with results of numerical calculations of impurities dynamics. As a result it is revealed that the contribution of heavy impurities to effective charge of plasma does not exceed 20%; thus the presence of impurities in plasma of the GOL-3 facility does not influence essentially the plasma confinement at the multimirror trap.

  1. Bioenergy from sisal residues

    Energy Technology Data Exchange (ETDEWEB)

    Jungersen, G. [Dansk Teknologisk Inst. (Denmark); Kivaisi, A.; Rubindamayugi, M. [Univ. of Dar es Salaam (Tanzania, United Republic of)

    1998-05-01

    The main objectives of this report are: To analyse the bioenergy potential of the Tanzanian agro-industries, with special emphasis on the Sisal industry, the largest producer of agro-industrial residues in Tanzania; and to upgrade the human capacity and research potential of the Applied Microbiology Unit at the University of Dar es Salaam, in order to ensure a scientific and technological support for future operation and implementation of biogas facilities and anaerobic water treatment systems. The experimental work on sisal residues contains the following issues: Optimal reactor set-up and performance; Pre-treatment methods for treatment of fibre fraction in order to increase the methane yield; Evaluation of the requirement for nutrient addition; Evaluation of the potential for bioethanol production from sisal bulbs. The processing of sisal leaves into dry fibres (decortication) has traditionally been done by the wet processing method, which consumes considerable quantities of water and produces large quantities of waste water. The Tanzania Sisal Authority (TSA) is now developing a dry decortication method, which consumes less water and produces a waste product with 12-15% TS, which is feasible for treatment in CSTR systems (Continously Stirred Tank Reactors). (EG)

  2. Remediating sites contaminated with heavy metals

    International Nuclear Information System (INIS)

    Swartzbaugh, J.; Sturgill, J.; Cormier, B.; Williams, H.D.

    1992-01-01

    This article is intended to serve as a reference for decision makers who must choose an approach to remediate sites contaminated with heavy metals. Its purpose is to explain pertinent chemical and physical characteristics of heavy metals, how to use these characteristics to select remedial technologies, and how to interpret and use data from field investigations. Different metal species are typically associated with different industrial processes. The contaminant species behave differently in various media (i.e., groundwater, soils, air), and require different technologies for containment and treatment. We focus on the metals that are used in industries that generate regulated waste. These include steelmaking, paint and pigment manufacturing, metal finishing, leather tanning, papermaking, aluminum anodizing, and battery manufacturing. Heavy metals are also present in refinery wastes as well as in smelting wastes and drilling muds

  3. Studies of heavy flavored jets with CMS

    CERN Document Server

    Jung, Kurt

    2017-01-01

    The energy loss of jets in heavy-ion collisions is expected to depend on the mass and flavor of the initiating parton. Thus, measurements of jet quenching with identified partons place powerful constraints on the thermodynamic and transport properties of the hot and dense medium. We present recent results of heavy flavor jet spectra and nuclear modification factors of jets associated to charm and bottom quarks in both pPb and PbPb collisions. New measurements to be presented include the dijet asymmetry of pairs of b-jets in PbPb collisions and a finalized c-jet measurement in pPb collisions based on new data collected during the 2015 heavy-ion run period at the LHC.

  4. Heavy Oil Detection (Prototypes)

    Science.gov (United States)

    2009-06-01

    marine life in addition to causing closure of water intakes at water treatment facilities and power plants . Regardless of whether the heavy oil is near...especially useful for municipalities and power plants that use the water for cooling. The use of this equipment by a Federal On-scene Coordinator (FOSC) is...28. CodaOctopus sample results. (a) shaded mosaic showing bathymetry (color palette wraps around so red to red spans 20 cm elevation); (b) raw data

  5. Heavy ion fusion III

    International Nuclear Information System (INIS)

    Hammer, D.; Max, C.; Perkins, F.; Rosenbluth, M.

    1987-03-01

    This report updates Heavy Ion Fusion, JSR-82-302, dated January, 1983. During the last four years, program management and direction has been changed and the overall Inertial Confinement Program has been reviewed. This report therefore concentrates on accelerator physics issues, how the program has addressed those issues during the last four years, and how it will be addressing them in the future. 8 refs., 3 figs

  6. New heavy plastic scintillators

    International Nuclear Information System (INIS)

    Britvich, G.I.; Vasil'chenko, V.G.; Lapshin, V.G.; Solov'ev, A.S.

    2000-01-01

    The possibility of manufacturing through the quenching method new transparent heavy scintillators on the basis of polystyrene with the light yield of approximately 32% from anthracene by general concentration of metalloorganic additions of approximately 17% by weight is shown. Doping of plastic scintillators through a set of various metalloorganic additives makes it possible to achieve more efficient and homogeneous by energy absorption of soft γ-quanta therein [ru

  7. Relativistic heavy ion reactions

    International Nuclear Information System (INIS)

    Brink, D.M.

    1989-08-01

    The theory of quantum chromodynamics predicts that if nuclear matter is heated to a sufficiently high temperature then quarks might become deconfined and a quark-gluon plasma could be produced. One of the aims of relativistic heavy ion experiments is to search for this new state of matter. These lectures survey some of the new experimental results and give an introduction to the theories used to interpret them. 48 refs., 4 tabs., 11 figs

  8. Canadian heavy water production

    International Nuclear Information System (INIS)

    Dahlinger, A.; Lockerby, W.E.; Rae, H.K.

    1977-01-01

    The paper reviews Canadian experience in the production of heavy water, presents a long-term supply projection, relates this projection to the anticipated long-term electrical energy demand, and highlights principal areas for further improvement that form the bulk of the Canadian R and D programme on heavy water processes. Six Canadian heavy water plants with a total design capacity of 4000Mg/a are in operation or under construction. All use the Girdler-Sulphide (GS) process, which is based on deuterium exchange between water and hydrogen sulphide. Early operating problems have been overcome and the plants have demonstrated annual capacity factors in excess of 70%, with short-term production rates equal to design rates. Areas for further improvement are: to increase production rates by optimizing the control of foaming to give both higher sieve tray efficiency and higher flow rates, to reduce the incapacity due to deposition of pyrite (FeS 2 ) and sulphur (between 5% and 10%), and to improve process control and optimization of operating conditions by the application of mathematical simulations of the detailed deuterium profile throughout each plant. Other processes being studied, which look potentially attractive are the hydrogen-water exchange and the hydrogen-amine exchange. Even if they become successful competitors to the GS process, the latter is likely to remain the dominant production method for the next 10-20 years. This programme, when related to the long-term electricity demand, indicates that heavy water supply and demand are in reasonable balance and that the Candu programme will not be inhibited because of shortages of this commodity. (author)

  9. Sustainable System for Residual Hazards Management

    International Nuclear Information System (INIS)

    Kevin M. Kostelnik; James H. Clarke; Jerry L. Harbour

    2004-01-01

    Hazardous, radioactive and other toxic substances have routinely been generated and subsequently disposed of in the shallow subsurface throughout the world. Many of today's waste management techniques do not eliminate the problem, but rather only concentrate or contain the hazardous contaminants. Residual hazards result from the presence of hazardous and/or contaminated material that remains on-site following active operations or the completion of remedial actions. Residual hazards pose continued risk to humans and the environment and represent a significant and chronic problem that require continuous long-term management (i.e. >1000 years). To protect human health and safeguard the natural environment, a sustainable system is required for the proper management of residual hazards. A sustainable system for the management of residual hazards will require the integration of engineered, institutional and land-use controls to isolate residual contaminants and thus minimize the associated hazards. Engineered controls are physical modifications to the natural setting and ecosystem, including the site, facility, and/or the residual materials themselves, in order to reduce or eliminate the potential for exposure to contaminants of concern (COCs). Institutional controls are processes, instruments, and mechanisms designed to influence human behavior and activity. System failure can involve hazardous material escaping from the confinement because of system degradation (i.e., chronic or acute degradation) or by external intrusion of the biosphere into the contaminated material because of the loss of institutional control. An ongoing analysis of contemporary and historic sites suggests that the significance of the loss of institutional controls is a critical pathway because decisions made during the operations/remedial action phase, as well as decisions made throughout the residual hazards management period, are key to the long-term success of the prescribed system. In fact

  10. A rational approach to heavy-atom derivative screening

    International Nuclear Information System (INIS)

    Joyce, M. Gordon; Radaev, Sergei; Sun, Peter D.

    2010-01-01

    In order to overcome the difficulties associated with the ‘classical’ heavy-atom derivatization procedure, an attempt has been made to develop a rational crystal-free heavy-atom-derivative screening method and a quick-soak derivatization procedure which allows heavy-atom compound identification. Despite the development in recent times of a range of techniques for phasing macromolecules, the conventional heavy-atom derivatization method still plays a significant role in protein structure determination. However, this method has become less popular in modern high-throughput oriented crystallography, mostly owing to its trial-and-error nature, which often results in lengthy empirical searches requiring large numbers of well diffracting crystals. In addition, the phasing power of heavy-atom derivatives is often compromised by lack of isomorphism or even loss of diffraction. In order to overcome the difficulties associated with the ‘classical’ heavy-atom derivatization procedure, an attempt has been made to develop a rational crystal-free heavy-atom derivative-screening method and a quick-soak derivatization procedure which allows heavy-atom compound identification. The method includes three basic steps: (i) the selection of likely reactive compounds for a given protein and specific crystallization conditions based on pre-defined heavy-atom compound reactivity profiles, (ii) screening of the chosen heavy-atom compounds for their ability to form protein adducts using mass spectrometry and (iii) derivatization of crystals with selected heavy-metal compounds using the quick-soak method to maximize diffraction quality and minimize non-isomorphism. Overall, this system streamlines the process of heavy-atom compound identification and minimizes the problem of non-isomorphism in phasing

  11. Outlook for Saskatchewan heavy oil

    International Nuclear Information System (INIS)

    Youzwa, P.

    1993-01-01

    Some of the opportunities and challenges currently facing the heavy oil industry in Saskatchewan are discussed from a government perspective. By the end of September 1993, 220 heavy oil wells were drilled in the province, and 26% of the land sales in 1993 were in heavy oil areas. About 41% of the wells drilled in heavy oil areas were horizontal oil wells. Of the total horizontal wells drilled in Saskatchewan, 48% are for heavy oil, and horizontal well production averages 85 bbl/d. Initial trends suggest that horizontal wells both accelerate production and contribute to ultimate recovery. Total heavy oil production in 1992 reached 28.9 million bbl and recoverable reserves in 1991 were 262.3 million bbl, or 1.5% of total oil in place. The low recovery is not only due to technical factors such as high viscosity but also to low investment in the heavy oil sector due to poor economics. It is hoped that lower interest and exchange rates, the success of horizontal wells and the provincial royalty structure will maintain the recent increase in heavy oil activity. The provincial government recently launched a comprehensive energy strategy in which development of a heavy oil strategy is an important component. Total heavy oil reserves exceed those of light and medium oil and have significant development potential. The Saskatchewan government wishes to adopt a cooperative and partnership approach in its dealings with the heavy oil industry to help realize this potential. 9 figs

  12. Heavy Flavour results from Tevatron

    Energy Technology Data Exchange (ETDEWEB)

    Borissov, G.; /Lancaster U.

    2012-06-01

    The CDF and D0 experiments finalize the analysis of their full statistics collected in the p{bar p} collisions at a center-of-mass energy of {radical}s = 1.96 TeV at the Fermilab Tevatron collider. This paper presents several new results on the properties of hadrons containing heavy b- and c-quarks obtained by both collaborations. These results include the search for the rare decays B{sup 0}, B{sub s}{sup 0} {yields} {mu}{sup +}{mu}{sup -} (CDF), the study of CP asymmetry in B{sub s} {yields} J{psi}{phi} decay (CDF, D0), the measurement of the like-sign dimuon charge asymmetry (D0), the measurement of CP asymmetry in D{sup 0} {yields} K{sup +}K{sup -} and D{sup 0} {yields} {pi}{sup +}{pi}{sup -} decays (CDF), and the new measurement of the B{sub s} {yields} D{sub s}{sup (*)+} D{sub s}{sup (*)-} branching fraction (CDF). Both experiments still expect to produce more results on the properties of heavy flavours.

  13. Heavy flavor spectroscopy

    International Nuclear Information System (INIS)

    Rosen, J.; Marques, J.; Spiegel, L.

    1993-01-01

    As a useful by-product of the unfolding searches for mixing and CP-violation effects in the beauty sector there will accrue very large data samples for the study of heavy flavor spectroscopy. (I) Hidden flavor states, i.e. c bar c and b bar b onium states. (II) Open flavor states (a) the D, D s , B, B s , and B c meson systems; (b) Charm and beauty flavored baryons. In this brief note the authors emphasize that there are many missing (undiscovered) states in both categories - states which are not readily produced exclusively due to quantum number preferences or states which are not readily observed inclusively due to experimentally difficult decay channels. As recorded luminosities increase it may be possible to fill in some of the holes in the present listings of heavy flavor states. Of particular interest to the authors would be the identification of heavy flavor mesons which are not easily explained in terms of a q bar q paradigm but rather may be evidence for hadro-molecular status. At Snowmass 1993 the topic of self-tagging schemes in B meson production was very much in vogue. Whether or not excited B-meson flavor-tagging will prove to be competitive with traditional methods based on the partner B decay remains to be seen. The authors suggest however that the richness of the excited B-system may undetermine the efficacy of self-tagging schemes

  14. Heavy ion fusion

    International Nuclear Information System (INIS)

    Hofmann, Ingo

    1993-01-01

    With controlled thermonuclear fusion holding out the possibility of a prolific and clean new source of energy, the goal remains elusive after many years of continual effort. While the conventional Tokamak route with magnetic confinement continues to hit the headlines, other alternatives are now becoming competitive. One possible solution is to confine the thermonuclear fuel pellet by high power beams. Current research and perspectives for future work in such inertial confinement was the subject of the 'Prospects for Heavy Ion Fusion' European Research Conference held in Aghia Pelaghia, Crete, last year. Its main focus was on the potential of heavy ion accelerators as well as recent advances in target physics with high power lasers and light ion beams. Carlo Rubbia declared that high energy accelerators, with their high efficiency, are the most promising approach to economical fusion energy production. However the need for cost saving in the driver accelerator requires new ideas in target design tailored to the particularities of heavy ion beams, which need to be pushed to the limits of high current and phase space density at the same time

  15. Heavy oil markets and investments

    Energy Technology Data Exchange (ETDEWEB)

    Forrest, Jackie [CERA North America (United States)

    2011-07-01

    With the depletion of traditional energy resources and the rising demand for energy, the exploitation of heavy oil resources is increasing. The aim of this paper is to present the heavy oil sector and to show which are the factors influencing heavy oil growth and production. A large part of heavy oil reserves lies in the Americas, with about 45% of the world's reserves in Latin America and over 35% in North America. The development of the heavy oil sector is dependent on economic, technological and environmental factors; greenhouse gas policies have important impacts on the development of the heavy oil industry as well as downstream market access. This presentation highlighted the great potential that North and South America have in terms of heavy oil but that the development of this sector will depend on several factors.

  16. Turbine Fuels from Tar Sands Bitumen and Heavy Oil. Phase I. Preliminary Process Analysis.

    Science.gov (United States)

    1985-04-09

    JP-4, upgrading, refining, tar sands, bitumen, 21 04 05 heavy crude oil, hydrotreating , hydrocracking, hydrovisbreak 07 01 03 ina. delayed coking...significant reserves of coal , shale, heavy crudes, and tar sands. Coal , because it is more hydrogen deficient than either shale oil or bitumen, is more...Bitumen from Santa Rosa tar sands was processed in a single case study (Zi) of high severity two-stage residual oil hydrotreating . Low ash and low metals

  17. Mineralogical characterization of municipal solid waste incineration bottom ash with an emphasis on heavy metal-bearing phases.

    Science.gov (United States)

    Wei, Yunmei; Shimaoka, Takayuki; Saffarzadeh, Amirhomayoun; Takahashi, Fumitake

    2011-03-15

    Municipal solid waste incineration (MSWI) bottom ash contains a considerable amount of heavy metals. The occurrence and uneven distribution of these heavy metals in bottom ash can increase the complexity of such residues in terms of long-term behavior upon landfilling or recycling. Bottom ashes sampled from three stoker-type incinerators in Japan were analyzed in this paper. This study presents detailed information on the mineralogical characterization of bottom ash constituents and the weathering behavior of these constituents by means of optical microscopy and scanning electron microscopy. It was revealed that bottom ash mainly consists of assorted silicate-based glass phases (48-54 wt% of ash) and mineral phases including melilites, pseudowollastonite, spinels, and metallic inclusions (Fe-P, Fe-S, Fe-Cu, Cu-Sn, Cu-Zn, Cu-S, and Cu-Pb dominated phases), as melt products formed during the incineration process. The compounds embedded in the glass matrix, e.g. spinels and metallic inclusions, played the most important role in concentration of heavy metals (Pb, Zn, Cu, Cr, Mn, Ni, etc.). Other phases such as refractory minerals and ceramics, frequently found in ash, were of less significance in terms of their influence on the involvement of heavy metals. Analysis of lab-scale artificially weathered and 10-year landfilled bottom ash samples revealed that secondary mineralization/alteration of the bottom ash constituents principally carbonation and glass evolution substantially decreased the potential risk of the heavy metals to the surrounding environment. Copyright © 2011 Elsevier B.V. All rights reserved.

  18. 51st North American Chemical Residue Workshop.

    Science.gov (United States)

    Yang, Paul; Martos, Perry; Barrett, Brad

    2015-06-03

    Manuscripts collected in this 51st North American Chemical Residue Workshop (NACRW) Symposium issue of the Journal of Agricultural and Food Chemistry (JAFC) were originally presented at the 51st NACRW meeting. The 2014 NACRW JAFC symposium collects 14 publications representing the broad range of topics in chemical analyses presented at the 2014 meeting. These include the analysis of chemical residues and contaminants in food, environment, feed, botanical, and bee samples as well as the application of quality control/quality assurance protocols in routine and method development.

  19. Leaching from municipal solid waste incineration residues

    Energy Technology Data Exchange (ETDEWEB)

    Hyks, J.

    2008-02-15

    range of elements was adequately predicted over a liquid-to-solid ratio of 250 L kg-1 corresponding to more than 10,000 years in a typical landfill. Overall, only a minor fraction of many potential pollutants (e.g. heavy metals) present in MSWI residues have been shown leachable even during long-term percolation experiments; typically, less than 1% of initially present As, Cr, Sb, Cu, Cd, and Pb has leached. (ln)

  20. Treatment of Arsenazo III contaminated heavy water stored at Darlington

    International Nuclear Information System (INIS)

    Suryanarayan, S.; Husain, A.; Williams, D.

    2010-01-01

    Darlington Nuclear Generating Station (DNGS) has accumulated over 48 drums of chemistry laboratory waste arising from analysis of heavy water (D 2 O). Several organic, including Arsenazo III, and inorganic contaminants present in these drums results in high total organic carbon (TOC) and conductivity. These drums have not been processed due to uncertainties related to clean-up of Arsenazo III contaminated heavy water. This paper provides details of chemical characterization as well as bench scale studies performed to demonstrate the feasibility of treating the downgraded D 2 O to the stringent target specifications of <1 ppm TOC and <0.1mS/m conductivity, required for feed to the Station Upgrading Plant (SUP). Both ionic organic species such as glycolate, acetate and formate as well as neutral organics such as acetone, methanol and ethylene glycol were detected in all the samples. Morpholine and propylene glycol were detected in one sample. Arsenazo III was determined to be not a major contaminant (maximum 8.4 ppm) in these waste drums, compared to the other organic contaminants present. Various unit processes such as pH adjustment, granular activated carbon (GAC), ion exchange resin (IX), UV-peroxide oxidation (UV-H 2 O 2 ) treatments, nanofiltration (NF) as well as reverse osmosis (RO) were tested on a bench scale both singly as well as in various combinations to evaluate their ability to achieve the stringent target conductivity and TOC specifications. Among the various bench scale tests evaluated, the successive processing train used at DNGS and consisting of GAC+IX+UV/H 2 O 2 +IX (polishing) unit operations was found to meet target specifications for both conductivity and TOC. Unit processes comprising (GAC+IX) and (RO-double pass + GAC+IX) met conductivity targets but failed to meet TOC specifications. The results of GAC+IX tests clearly emphasize the importance of using low flow rates for successful reduction in both conductivity as well as TOC. Detailed

  1. Characterization of bound residues in plants

    International Nuclear Information System (INIS)

    Stratton, G.D. Jr.; Wheeler, W.B.

    1986-01-01

    The characterization of unextractable (or 'bound') pesticide residues in plants can be difficult owing to the insoluble nature of the pesticide-plant complex. An unextractable residue can be defined as material derived from the applied pesticide which remains in the plant matrix after exhaustive organic solvent extraction. Experiments with a variety of pesticide classes in plants indicate that the level of unextractable residue varies with the plant species, the pesticide and the exposure time of the plant to the pesticide. Methods used in attempts to release 'bound' residues from solvent-extracted plant tissues include acid hydrolyses, enzymatic treatments and techniques of high-temperature distillation. These methods solubilize or release varying amounts of unextractable material; the amounts depend on the pesticide and on the extent to which the plant fibre is degraded. In experiments using radiolabelled dieldrin (1, 2, 3, 4, 10, 10-hexachloro-6, 7-epoxy-1, 4, 4a, 5, 6, 7, 8, 8a-octahydro-exo-1, 4-endo-5,6-dimethanonaphthalene), carbofuran (2,3-dihydro-2, 2-dimethylbenzofuran-7-yl methylcarbamate) and permethrin ([3-phenoxybenzyl(+-)-3-(2, 2-dichlorovinyl)-2, 2-dimethylcyclopropanecarboxylate]) in radishes, portions of the unextractable material solubilized by the above methods were identified as parent compound and/or closely related metabolites. The bioavailability and toxicological significance of unextractable pesticide residues need to be evaluated. (author)

  2. Geostatistical methods applied to field model residuals

    DEFF Research Database (Denmark)

    Maule, Fox; Mosegaard, K.; Olsen, Nils

    consists of measurement errors and unmodelled signal), and is typically assumed to be uncorrelated and Gaussian distributed. We have applied geostatistical methods to analyse the residuals of the Oersted(09d/04) field model [http://www.dsri.dk/Oersted/Field_models/IGRF_2005_candidates/], which is based......The geomagnetic field varies on a variety of time- and length scales, which are only rudimentary considered in most present field models. The part of the observed field that can not be explained by a given model, the model residuals, is often considered as an estimate of the data uncertainty (which...... on 5 years of Ørsted and CHAMP data, and includes secular variation and acceleration, as well as low-degree external (magnetospheric) and induced fields. The analysis is done in order to find the statistical behaviour of the space-time structure of the residuals, as a proxy for the data covariances...

  3. Chelating agents to solubilize heavy metals from Oxisols contaminated by the addition of organic and inorganic residues Uso de quelantes na solubilização de metais pesados de Latossolos contaminados pela adição de resíduos orgânico e inorgânico

    Directory of Open Access Journals (Sweden)

    Aline Renée Coscione

    2009-02-01

    Full Text Available Phytoremediation is an attractive technique for soils contaminated with heavy metals, especially in conjunction with chelating agents to assist metal phytoextraction. Nevertheless, their studies in Brazil are rare. Thus, the objective of the present work was to evaluate the efficiency of the chelating agents EDDS and EDTA for the solubilization of heavy metals from two Oxisols contaminated by organic sources in Jaguariúna (LVJ and inorganic sources in Paulínia (LVP, São Paulo State, Southeastern Brazil. First, the soil samples were fractionated and the DTPA method was used to quantify heavy metals available forms. The results indicated that the metals were highly available in the soil fractions and could be solubilized by the chelating agents. The soil was suspended for 24 h in a chelating agent solution (EDTA or EDDS at rates of 0, 250, 500 and 750 mg kg-1 of soil. The concentration of solubilized heavy metals was determined in the resulting solution. The extent of metal solubilization varied according to soil type, the chelating agent added and the specific metal. The amount of iron solubilized, as compared to the total iron (LVJ was 11% (EDTA and 19% (EDDS. EDDS solubilized more Cu than EDTA in both soils but more Ni in LVJ, while EDTA solubilized more Zn in both soils but more Cd in LVP. Both EDTA and EDDS may be useful for phytoextraction from soils, although the iron content is an important factor regarding the phytoextraction of heavy metals with chelating agents in Oxisols.A fitoextração tem sido uma opção atrativa para remediar solos contaminados com metais pesados, principalmente quando associada à aplicação de quelantes ao solo, embora no Brasil seus estudos sejam muito incipientes. Portanto, o objetivo deste trabalho foi avaliar a eficiência dos quelantes EDTA e EDDS na solubilização de metais pesados em Latossolos contaminados por Cu, Zn, Cd e Ni, cujas fontes de contaminação foram: orgânica em Jaguariúna (LVJ e

  4. AMBIENT CARBONATION of MINING RESIDUES: Understanding the Mechanisms and Optimization of Direct Carbon Dioxide Mineral Sequestration

    Science.gov (United States)

    Assima, G. P.; Larachi, F.; Molson, J. W.; Beaudoin, G.

    2013-12-01

    The huge amounts (GTs) of ultramafic mining residues (UMRs) produced by mining activities around the world and accumulated in multi-square-kilometer stockpiles are stimulating a vivid interest regarding their possible use as a stable and permanent sink for CO2. Virtually costless and often found crushed and / or ground, UMRs are being considered as ideal candidates for atmospheric CO2 mitigation. The present work, therefore, explores the potential of several UMRs available in Quebec (Thetford Mines, Asbestos, Nunavik, Amos, Otish Mountains), for carbonation under ambient conditions, as a cost-effective alternative to remove low-concentration CO2 from the atmosphere and alleviate global warming. Several experimental reactors have been built to specifically simulate various climatic changes at the laboratory scale. The impact of various environmental conditions to which the residues are subjected to in their storage location, including temperature variations, precipitation, flooding, drought, changing water saturation, oxygen gradient and CO2 diffusion have been thoroughly studied. Dry and heavy-rain periods are unsuitable for efficient CO2 sequestration. Low liquid saturation within UMRs pores favors carbonation by combining fast percolation of gaseous CO2, rapid dissemination of CO2 dissolved species and creation of highly reactive sites throughout the mining residue pile. Partly saturated samples were also found to exhibit lower gaseous CO2 breakthrough times across the mining residues. Warm periods significantly accelerate the rate of CO2 uptake as compared to cold periods, which, in contrast are characterized by heat generation levels that could possibly be exploited by low temperature geothermal systems. A temperature rise from 10 to 40 °C was accompanied by a ten-fold increase in initial reaction rate. The carbonation reaction caused a rise in UMRs temperature up to 4.9°C during experiments at a 10°C. The presence of oxygen in the reaction medium induces

  5. Contamination and chemical fractionation of heavy metals in street dust from the metropolitan area of Monterrey, Mexico.

    Science.gov (United States)

    Valdez Cerda, Enrique; Hinojosa Reyes, Laura; Alfaro Barbosa, Juan Manuel; Elizondo-Martinez, Perla; Acuña-Askar, Karim

    2011-07-01

    The prevalence of heavy metal pollution and mobility of both Pb and Cd was investigated in street dust samples from the Metropolitan Area of Monterrey (MAM) in northern Mexico. Street dust samples from 30 selected sites were analysed for their content of Zn, Cd, Pb, Cr and Ni after digestion according to U.S. EPA Method 3051. Multivariate analysis including correlation coefficient analysis, Principal Component Analysis and Cluster Analysis was used to analyse the data and identify possible sources of these heavy metals. Compared with background values, elevated concentrations of Pb (300 mg kg(-1)), Cd (7.6 mg kg(-1)) and Cr (78 mg kg(-1)) were observed in street dust of MAM. Based on multivariate statistical approaches, the studied elements were classified in three main sources: (1) Cr, Ni and Zn mainly derived from industrial activities; (2) Cd originating from traffic-related activities; and (3) Pb associated with vehicular emissions. A sequential extraction procedure using the Tessier method was applied to evaluate the mobility of Pb and Cd in street dust. The majority of Pb was associated with the residual fraction followed by the carbonate fraction. The majority of Cd was associated with the residual fraction. These results indicated that the mobility was higher in Pb (26%) compared with Cd (11%), posing a potential risk to the environment.

  6. Antibody Heavy Chain Variable Domains of Different Germline Gene Origins Diversify through Different Paths

    Directory of Open Access Journals (Sweden)

    Ufuk Kirik

    2017-11-01

    Full Text Available B cells produce antibodies, key effector molecules in health and disease. They mature their properties, including their affinity for antigen, through hypermutation events; processes that involve, e.g., base substitution, codon insertion and deletion, often in association with an isotype switch. Investigations of antibody evolution define modes whereby particular antibody responses are able to form, and such studies provide insight important for instance for development of efficient vaccines. Antibody evolution is also used in vitro for the design of antibodies with improved properties. To better understand the basic concepts of antibody evolution, we analyzed the mutational paths, both in terms of amino acid substitution and insertions and deletions, taken by antibodies of the IgG isotype. The analysis focused on the evolution of the heavy chain variable domain of sets of antibodies, each with an origin in 1 of 11 different germline genes representing six human heavy chain germline gene subgroups. Investigated genes were isolated from cells of human bone marrow, a major site of antibody production, and characterized by next-generation sequencing and an in-house bioinformatics pipeline. Apart from substitutions within the complementarity determining regions, multiple framework residues including those in protein cores were targets of extensive diversification. Diversity, both in terms of substitutions, and insertions and deletions, in antibodies is focused to different positions in the sequence in a germline gene-unique manner. Altogether, our findings create a framework for understanding patterns of evolution of antibodies from defined germline genes.

  7. Les procédés ASVAHL thermiques et catalytiques sous pression d'hydrogène pour la conversion des bruts lourds et des résidus de bruts classiques Thermal and Catalytic Asvahl Processes under Hydrogen Pressure for Converting Heavy Crudes and Conventional Residues

    Directory of Open Access Journals (Sweden)

    Peries J. P.

    2006-11-01

    Full Text Available Cet article décrit les performances comparées des procédés ASVAHL thermiques (TERVAHL T, TERVAHL H, TERVAHL HC et catalytiques (HYVAHL F, HYVAHL C dans deux cas de traitement: - brut désessencié Boscan (base des études objectif Transport; - résidu sous vide Safaniya (base des études Raffinage de résidu. A travers ces résultats, l'importance de la quantité d'hydrogène fixée est mise en évidence. Elle joue sur la conversion obtenue et sur la qualité des résidus. L'introduction de catalyseur soluble ou en suspension catalytique TERVAHL HC (hydroviscoréduction catalytique ou l'utilisation d'un catalyseur supporté (hydrotraiternent HYVAHL favorisent l'activation de l'hydrogène. C'est la combinaison des réactions de craquage, de polycondensation et d'hydrogénation, et les conditions opératoires (températures, temps de séjour et pression qui définiront les limites de la conversion pour une stabilité donnée des résidus. This article describes the comparative performances of thermal ASVAHL processes (TERVAHL T, TERVAHL H, TERVAHL HQ and catalytic ASVAHL processes (HYVAHL F, HYVAHL C for two types of processing: (1 degasolined Boscan crude (basis of studies for transportation feasibility, and (2 Safaniya vacuum residue (basis of studies for residue refining. The results reveal the importance of the amount of fixed hydrogen, which affects the conversion obtained and the quality of the residues. The introduction of a TERVAHL HC soluble catalyst or one in catalytic suspension (catalytic hydrovisbreaking or the use of a supported catalyst (HYVAHL hydrotreatment enhances the activation of hydrogen. The combination of cracking, polycondensation and hydrogen reactions together with the operating conditions (temperatures, residence time and pressure are what will define the conversion limits for a given stability of residues.

  8. Remaining or residual first ribs are the cause of recurrent thoracic outlet syndrome.

    Science.gov (United States)

    Likes, Kendall; Dapash, Thadeus; Rochlin, Danielle H; Freischlag, Julie A

    2014-05-01

    Surgical intervention for neurogenic thoracic outlet syndrome (NTOS) is not always successful. Treatment plans can be difficult in patients presenting with recurrent symptoms. The purpose of this study was to evaluate outcomes of this patient subset, who underwent operative intervention to remove a remaining or residual first rib because of recurrent thoracic outlet syndrome (TOS)-related symptoms. Data on 15 patients who presented with previous scalenectomy, brachial plexus lysis, or first rib resection and scalenectomy (FRRS) with residual rib present on chest radiograph from 2004 to 2012 were retrospectively reviewed from a prospectively maintained database, with approval from the Institutional Review Board of Johns Hopkins Hospital. Patients were classified as having a remaining first rib if they presented with recurrent NTOS symptoms, had previously undergone scalenectomy and/or brachial plexus lysis alone to decompress the thoracic outlet, and exhibited an intact first rib on chest X-ray, whereas patients were classified as having a remnant rib if they presented with recurrent symptoms of NTOS, had previously undergone a first rib resection at another institution, and exhibited an anterior or posterior first rib on chest X-ray. Demographic and clinical characteristics along with postoperative outcomes were evaluated. Different precipitating events reaggravated symptoms in 12 patients. Events included car accidents (n = 4), work-related repetitive movements (n = 5), lifting heavy objects (n = 2), and repetitive injury (n = 1). Group 1: Previous scalenectomy (n = 2), brachial plexus lysis alone (n = 2), or both (n = 3). Seven patients (2 men and 5 women; mean age 34 [25-53]) presented with NTOS symptoms due to a remaining first rib at an average of 24 months (range: 2-68) after their initial operation at another institution. All underwent transaxillary first rib resection, residual scalene resection, and lysis of scar tissue. Perioperative complications

  9. Characteristics of residual organics in municipal solid waste incinerator bottom ash.

    Science.gov (United States)

    Lin, Yen-Ching; Yen, Jui-Hung; Lateef, Shaik Khaja; Hong, Pui-Kwan Andy; Lin, Cheng-Fang

    2010-10-15

    Although heavy metals in bottom ash have been a primary issue in resource recovery of municipal solid waste incinerator residues in past decades, less studied are potentially toxic and odorous organic fractions that exist as they have not been completely oxidized during the mass burn process. Using supercritical fluid extraction (SFE) and soxtec extraction (SE) techniques, this study investigated the characteristics of un-oxidized organic residues contained in bottom ash from three municipal solid waste incinerators in Taiwan during 2008-2009. All together 99 organics were identified in bottom ash samples using gas chromatography-mass spectrometry (GC-MS). Among the identified organics, aromatic compounds were most frequently detected. No polycyclic aromatic hydrocarbons were extracted by SFE or SE. Several phthalates (e.g., phthalic acid isobutyl tridec-2-yn-1-yl ester, dibutyl phthalate and 2-butoxyethyl butyl benzene-1,2-dicarboxylate), organic phosphates (e.g., octicizer and phosphoric acid isodecyl diphenyl ester), and aromatics and amines including pyridine, quinoline derivatives, chloro- and cyano-organics were successfully extracted. Aromatic amines (e.g., 1-nitro-9,10-dioxo-9,10-dihydro-anthracene-2-carboxylic acid diethylamide and 3-bromo-N-(4-bromo-2-chlorophenyl)-propanamide) and aromatic compounds (other than amines) (e.g., 7-chloro-4-methoxy-3-methylquinoline and 2,3-dihydro-N-hydroxy-4-methoxy-3,3-dimethyl indole-2-one) are probably the major odorous compounds in bottom ash. This work identifies organic pollutants in incinerated bottom ash that have received far less attention than their heavy metals counterpart. 2010 Elsevier B.V. All rights reserved.

  10. Marine Tar Residues: a Review

    OpenAIRE

    Warnock, April M.; Hagen, Scott C.; Passeri, Davina L.

    2015-01-01

    Marine tar residues originate from natural and anthropogenic oil releases into the ocean environment and are formed after liquid petroleum is transformed by weathering, sedimentation, and other processes. Tar balls, tar mats, and tar patties are common examples of marine tar residues and can range in size from millimeters in diameter (tar balls) to several meters in length and width (tar mats). These residues can remain in the ocean environment indefinitely, decomposing or becoming buried in ...

  11. Residue Management: A Computer Program About Conservation Tillage Decisions.

    Science.gov (United States)

    Thien, Steve J.

    1986-01-01

    Describes a computer program, Residue Management, which is designed to supplement discussions on the Universal Soil Loss Equation and the impact of tillage on soil properties for introductory soil courses. The program advances the user through three stages of residue management. Information on obtaining the program is also included. (ML)

  12. Crop residues for advanced biofuels workshop: A synposis

    Science.gov (United States)

    Crop residues are being harvested for a variety of purposes including their use as livestock feed and to produce advanced biofuels. Crop residue harvesting, by definition, reduces the potential annual carbon input to the soil from aboveground biomass but does not affect input from plant roots. The m...

  13. A review on heavy metal contamination in the soil worldwide: Situation, impact and remediation techniques

    OpenAIRE

    Chao Su; LiQin Jiang; WenJun Zhang

    2014-01-01

    Heavy metals in the soil refers to some significant heavy metals of biological toxicity, including mercury (Hg), cadmium (Cd), lead (Pb), chromium (Cr), and arsenic (As), etc. With the development of the global economy, both type and content of heavy metals in the soil caused by human activities have gradually increased in recent years, which have resulted in serious environment deterioration. In present study we compared and analyzed soil contamination of heavy metals in various cities/count...

  14. Bioremediation of Heavy Metals in Liquid Media Through Fungi Isolated from Contaminated Sources

    OpenAIRE

    Joshi, P. K.; Swarup, Anand; Maheshwari, Sonu; Kumar, Raman; Singh, Namita

    2011-01-01

    Wastewater particularly from electroplating, paint, leather, metal and tanning industries contain enormous amount of heavy metals. Microorganisms including fungi have been reported to exclude heavy metals from wastewater through bioaccumulation and biosorption at low cost and in eco-friendly way. An attempt was, therefore, made to isolate fungi from sites contaminated with heavy metals for higher tolerance and removal of heavy metals from wastewater. Seventy-six fungal isolates tolerant to he...

  15. Medical heavy ion accelerator proposals

    International Nuclear Information System (INIS)

    Gough, R.A.

    1985-05-01

    For several decades, accelerators designed primarily for research in nuclear and high energy physics have been adapted for biomedical research including radiotherapeutic treatment of human diseases such as pituitary disorders, cancer, and more recently, arteriovascular malformations. The particles used in these treatments include pions, protons and heavier ions such as carbon, neon, silicon and argon. Maximum beam energies must be available to penetrate into an equivalent of about 30 cm of water, requiring treatment beams of 250 to 1000 MeV/nucleon. Certain special treatments of superficial melanoma, however, require that beam energies as low as 70 MeV/nucleon also be available. Intensities must be adequate to complete a 100 rad treatment fraction in about 1 minute. For most heavy ion treatments, this corresponds to 10 7 -10 9 ions/second at the patient. Because this research is best conducted in a dedicated, hospital-based facility, and because of the clinical need for ultra-high reliability, the construction of new and dedicated facilities has been proposed. Heavy ion accelerators can provide a variety of ions and energies, permitting treatment plans that exploit the properties of the ion best suited to each individual treatment, and that employ radioactive beams (such as 11 C and 19 Ne) to precisely confirm the dose localization. The favored technical approach in these proposals utilizes a conventional, strong-focusing synchrotron capable of fast switching between ions and energies, and servicing multiple treatment rooms. Specialized techniques for shaping the dose to conform to irregularly-shaped target volumes, while simultaneously sparing surrounding, healthy tissue and critical structures, are employed in each treatment room, together with the sophisticated dosimetry necessary for verification, monitoring, and patient safety. 3 refs., 8 figs

  16. Heavy crude oil and synthetic crude market outlook

    International Nuclear Information System (INIS)

    Crandall, G.R.

    1997-01-01

    This presentation included an outline of the international heavy crude supply and demand versus Canadian heavy crude supply and disposition, and pricing outlook for synthetic crudes. Differences among crude oils such as light sweet, light sour, heavy and bitumen were described and illustrated with respect to their gravity, API, percentage of sulphur, metals and nitrogen. Internationally, heavy and sour crude supplies are forecast to increase significantly over the next four years. Discoveries of light sour crude in offshore Gulf of Mexico will provide a major new source of sour crude to U.S. Gulf Coast refineries. Venezuela's supplies of heavy and sour crude are also expected to increase over the next few years. Mexico and Canada have plans to increase their heavy crude production. All of the crudes will be aimed at the U.S. Gulf Coast and Midwest markets. Pentanes and condensates are also expected to increase based on the growing Canadian natural gas production. Diluent demand will also grow to match Canadian heavy crude/bitumen production. U.S. midwest refiners are proposing expansions to allow them to process more Canadian heavy crude oil. At present, only a few refineries are equipped to process significant amounts of synthetic crude. It was suggested that to absorb available heavy and synthetic production, increased penetration into both Canadian and U.S. markets will be required. Some refineries may have to be modified to process heavy and synthetic oil supplies. Heavy oil and synthetic producers may need to develop relationships with refiners such as joint ventures and term supply agreements to secure markets. 2 tabs., 12 figs

  17. eμ signal as heavy lepton signature at PEP

    International Nuclear Information System (INIS)

    Smith, J.

    1978-01-01

    A planned experiment to detect heavy leptons is described including the signature, cross sections, cuts to reduce the two-photon background to a tolerable level, and the computer program. The expected luminosity is also noted

  18. Co-sintering of treated APC-residues with bottom ash

    DEFF Research Database (Denmark)

    Jensen, Dorthe Lærke; Bergfeldt, Britta; Vehlow, Jürgen

    2001-01-01

    Air pollution control residues stabilised by means of the Ferrox process can be sager disposed of due to lower contents of soluble salts and lesssoluble heavy metals stabilised in iron oxides. Co-combustion tests in the Karlsruhe test incinerator TAMARA were carried out in order to investigate...

  19. Co-sintering of treated APC-residues with bottom ash

    DEFF Research Database (Denmark)

    Bergfeldt, B.; Jensen, Dorthe Lærke; Vehlow, J.

    2001-01-01

    Air pollution control residues stabilised by means of the Ferrox process can be sager disposed of due to lower contents of soluble salts and lesssoluble heavy metals stabilised in iron oxides. Co-combustion tests in the Karlsruhe test incinerator TAMARA were carried out in order to investigate th...

  20. Evaluation of residue-residue contact predictions in CASP9

    KAUST Repository

    Monastyrskyy, Bohdan

    2011-01-01

    This work presents the results of the assessment of the intramolecular residue-residue contact predictions submitted to CASP9. The methodology for the assessment does not differ from that used in previous CASPs, with two basic evaluation measures being the precision in recognizing contacts and the difference between the distribution of distances in the subset of predicted contact pairs versus all pairs of residues in the structure. The emphasis is placed on the prediction of long-range contacts (i.e., contacts between residues separated by at least 24 residues along sequence) in target proteins that cannot be easily modeled by homology. Although there is considerable activity in the field, the current analysis reports no discernable progress since CASP8.

  1. Lixiviation of heavy metals of hazardous industrial wastes by means of thermostatized columns and design of a pilot plant

    International Nuclear Information System (INIS)

    Vite T, J.; Leon, C.C. de; Vite T, M.; Soto T, J.L.

    2006-01-01

    The purpose of this work was to evaluate the efficiency of lixiviation of heavy metals, using thermostatized columns and hazardous industrial residual wastes: those by the volume with which are generated and its high toxicity, its represent a great problem for it treatment and disposition, in this work a diagram of a pilot plant for extraction of heavy metals is included. The process and equipment were patented in United States and in Mexico. For the development of this study four thermostated columns were used that were coupled. The waste were finely milled and suspended in an aqueous pulp adding of 10 - 40gL -1 of mineral acid or sodium hydroxide until reaching an interval of pH of 2,5,7 and 10. Its were used of 4-10 gL -1 of a reducer agent and of 0.3-1.5 g of a surfactant agent. In some cases with this method was possible to remove until 100% of heavy metals. It was used Plasma Emission Spectroscopy to determine the concentrations of the cations in the lixiviation liquors. For studying the metallic alloys the X-ray diffraction technique was used. (Author)

  2. Heavy ion therapy: Bevalac epoch

    International Nuclear Information System (INIS)

    Castro, J.R.

    1993-10-01

    An overview of heavy ion therapy at the Bevelac complex (SuperHILac linear accelerator + Bevatron) is given. Treatment planning, clinical results with helium ions on the skull base and uveal melanoma, clinical results with high-LET charged particles, neon radiotherapy of prostate cancer, heavy charged particle irradiation for unfavorable soft tissue sarcoma, preliminary results in heavy charged particle irradiation of bone sarcoma, and irradiation of bile duct carcinoma with charged particles and-or photons are all covered

  3. Heavy quark production and spectroscopy

    International Nuclear Information System (INIS)

    Appel, J.A.

    1993-11-01

    This review covers many new experimental results on heavy flavor production and spectroscopy. It also shows some of the increasingly improved theoretical understanding of results in light of basic perturbative QCD and heavy quark symmetry. At the same time, there are some remaining discrepancies among experiments as well as significant missing information on some of the anticipated lowest lying heavy quark states. Most interesting, perhaps, are some clearly measured production effects awaiting full explanation

  4. Actinides and heavy fermions

    International Nuclear Information System (INIS)

    Smith, J.L.; Fisk, Z.; Ott, H.R.

    1987-01-01

    The actinide series of elements begins with f-shell electrons forming energy bands, contributing to the bonding, and possessing no magnetic moments. At americium the series switches over to localized f electrons with magnetic moments. In metallic compounds this crossover of behavior can be modified and studied. In this continuum of behavior a few compounds on the very edge of localized f-electron behavior exhibit enormous electronic heat capacities at low temperatures. This is associated with an enhanced thermal mass of the conduction electrons, which is well over a hundred times the free electron mass, and is what led to the label heavy fermion for such compounds. A few of these become superconducting at even lower temperatures. The excitement in this field comes from attempting to understand how this heaviness arises and from the likelihood that the superconductivity is different from that of previously known superconductors. The effects of thorium impurities in UBe 13 were studied as a representative system for studying the nature of the superconductivity

  5. Ultrarelativistic heavy ions

    International Nuclear Information System (INIS)

    Pugh, H.G.

    1980-12-01

    Studies with ultrarelativistic heavy ions combine aspects of cosmic ray physics, particle physics, nuclear physics, astrophysics and cosmogenesis. The leading theoretical concerns are the behavior of matter at very high-energy density and flux, the general behavior of space time in collisions, relativistic nuclear theory, and quantum chromodynamics. The field has developed over a period of more than thirty years, since the first observation of heavy nuclei in cosmic rays and the major developments of understanding of high-energy collisions made by Fermi and Landau in the early fifties. In the late sixties the discovery of the parton content of nucleons was rapidly followed by a great extension of high-energy collision phenomenology at the CERN ISR and subsequent confirmation of the QCD theory. In parallel the study of p-nucleus and nucleus-nucleus collisions at very high energies, especially at the CERN PS, Fermilab and the Bevalac, and in cosmic rays demonstrated that studies involving the nucleus opened up a new dimension in studies of the hadronic interaction. It is now at a high level of interest on an international scale, with major new accelerators being proposed to dedicate to this kind of study

  6. Heavy quark spectroscopy

    International Nuclear Information System (INIS)

    Rosner, J.L.

    1985-10-01

    New experimental and theoretical developments in heavy quark spectroscopy are reviewed. From studies of J/psi decays, the eta' is found to have some ''glue'' or other inert component, while the iota (a glueball candidate) probably contains some quarks as well. The xi(2.2) persists in new Mark III data, but is not seen by the DM2 collaboration. The production of charmonium states by anti pp reactions is reviewed. First evidence for a P- wave charmed meson, D(2420), has been presented by the ARGUS group. Radiative UPSILON decay studies fail to confirm the zeta(8.3) and begin to place useful limits on Higgs bosons. First results from an experiment at Fermilab on low-background hadronic production of UPSILON states are shown. Accurate measurements of chi/sub b/(1P) masses by the ARGUS collaboration are noted, and interpreted as favoring scalar quark confinement. Studies of t and other heavy quarks will probe the q anti q interaction below 0.05 fm, are likely to be strongly affected by t anti t-Z interference, and can provide varied information on Higgs bosons. 144 refs., 21 figs

  7. Heavy Metals Accumulation Characteristics of Vegetables in Hangzhou City, China

    Directory of Open Access Journals (Sweden)

    GU Yan-qing

    2015-08-01

    Full Text Available A field survey of heavy metal concentrations in soils and vegetables grown in 30 vegetable farmlands of Hangzhou City were carried out. Through calculating the bioconcentration factor(BCFand transfer factor(TFfor different heavy metals(Cu, Zn, Cd, Cr and Pbin 27 kinds of different vegetables which belong to leafy vegetables, root vegetables or eggplant fruit vegetables, assessing their accumulation characteristics of heavy metals according to the differences of the bio-concentration factor, the reasonable proposals were put forward to optimize the planting structure of vegetables in mild and middle-level heavy metal contamination soils. The experimental results were as follows: In soils with mild and middle-level heavy metal contamination, leafy vegetables, such as crown daisy, cabbage, celery and Chinese long cabbage, had relatively low enrichment ability of heavy metals, so as the root and fruit vegetables like white radish, carrot, tomatoes, hence these vegetables could be planted preferentially. In contrast, some kinds of vegetables, including white amaranth, red amaranth, tatsoi, broccoli, gynura, brassica juncea and lettuce of leafy vegetables, lactuca sativa, taro, red radish and cherry radish of rhizome vegetables and sweet pepper of fruit vegetables, had relatively high accumulation ability of heavy metal, which should be avoided to be planted in soils with mild and middle-level heavy metal contamination.

  8. Dissecting and analyzing key residues in protein-DNA complexes.

    Science.gov (United States)

    Kulandaisamy, A; Srivastava, Ambuj; Nagarajan, R; Gromiha, M Michael

    2018-04-01

    Protein-DNA interactions are involved in various fundamental biological processes such as replication, transcription, DNA repair, and gene regulation. To understand the interaction in protein-DNA complexes, the integrative study of binding and stabilizing residues is important. In the present study, we have identified key residues that play a dual role in both binding and stability from a nonredundant dataset of 319 protein-DNA complexes. We observed that key residues are identified in very less number of complexes (29%) and only about 4% of stabilizing/binding residues are identified as key residues. Specifically, stabilizing residues have higher preference to be key residues than binding residues. These key residues include polar, nonpolar, aliphatic, aromatic, and charged amino acids. Moreover, we have analyzed and discussed the key residues in different protein-DNA complexes, which are classified based on protein structural class, function, DNA strand, and their conformations. Especially, Ser, Thr, Tyr, Arg, and Lys residues are commonly found in most of the subclasses of protein-DNA complexes. Further, we analyzed atomic contacts, which show that polar-nonpolar is more enriched than other types of contacts. In addition, the charged contacts are highly preferred in protein-DNA complexes compared with protein-protein and protein-RNA complexes. Finally, we have discussed the sequence and structural features of key residues such as conservation score, surrounding hydrophobicity, solvent accessibility, secondary structure, and long-range order. This study will be helpful to understand the recognition mechanism and structural and functional aspects of protein-DNA complexes. Copyright © 2017 John Wiley & Sons, Ltd.

  9. Laboratory studies of the properties of in-situ burn residues: chemical composition of residues

    International Nuclear Information System (INIS)

    Trudel, B.K.; Buist, I.A.; Schatzke, D.; Aurand, D.

    1996-01-01

    The chemical composition of the residue from small-scale burns of thick oil slicks was studied. The objective was to describe the changes in chemical composition in oils burning on water and to determine how these changes were influenced by the condition of the burn. Small-scale test burns involved burning 40-cm diameter pools of oil on water. A range of eight oil types including seven crude oils and an automotive diesel were burned. For each oil, slicks of fresh oil of three different thicknesses were tested. Two of the oils were tested before and after weathering. Results showed that the composition of the residue differed greatly from the parent oil. Asphaltenes, high-boiling-point aromatics and resins remained concentrated in the burn residue. The burning of slicks appeared to remove most of the lower-molecular weight aromatic hydrocarbons which included the more toxic and more bioavailable components of the crude oils. 11 refs., 6 tabs

  10. Automatic prediction of catalytic residues by modeling residue structural neighborhood

    Directory of Open Access Journals (Sweden)

    Passerini Andrea

    2010-03-01

    Full Text Available Abstract Background Prediction of catalytic residues is a major step in characterizing the function of enzymes. In its simpler formulation, the problem can be cast into a binary classification task at the residue level, by predicting whether the residue is directly involved in the catalytic process. The task is quite hard also when structural information is available, due to the rather wide range of roles a functional residue can play and to the large imbalance between the number of catalytic and non-catalytic residues. Results We developed an effective representation of structural information by modeling spherical regions around candidate residues, and extracting statistics on the properties of their content such as physico-chemical properties, atomic density, flexibility, presence of water molecules. We trained an SVM classifier combining our features with sequence-based information and previously developed 3D features, and compared its performance with the most recent state-of-the-art approaches on different benchmark datasets. We further analyzed the discriminant power of the information provided by the presence of heterogens in the residue neighborhood. Conclusions Our structure-based method achieves consistent improvements on all tested datasets over both sequence-based and structure-based state-of-the-art approaches. Structural neighborhood information is shown to be responsible for such results, and predicting the presence of nearby heterogens seems to be a promising direction for further improvements.

  11. Heavy and standard silicone oil: intraocular inflammation.

    Science.gov (United States)

    Russo, Andrea; Morescalchi, Francesco; Donati, Simone; Gambicorti, Elena; Azzolini, Claudio; Costagliola, Ciro; Semeraro, Francesco

    2017-03-13

    Proliferative vitreoretinopathy in the inferior retina remains clinically challenging. Heavier-than-water intraocular tamponades have been developed to improve inferior tamponading properties, and their chemical compositions have been substantially improved over the years, in parallel with developments in vitrectomy instrumentation and surgical techniques. Herein we present an updated review of the clinical use of standard formulations and HSO, focusing on analysis of the intraocular inflammation associated with endotamponade agents, and comparison of the adverse effects of these agents on the physical and biological properties of the eye. A detailed literature search was conducted on PubMed, EMBASE, Cochrane Library, and Google Scholar using the key words. Fifty-eight articles matched our inclusion criteria that were included in this systematic review. Perfluorocarbon liquids and partially fluorinated alkanes are associated with tamponade emulsification, intraocular inflammation, and rises in intraocular pressure, but these associations are not as strong when these substances are mixed with a heavy silicone oil (HSO). Two recently approved heavy silicone oil tamponades, Oxane HD and Densiron 68, are now available for use in clinical practice. While the complication spectrum of the new generation of these HSOs seems to be similar to that of conventional silicone oil tamponades, they provide better support for the inferior retina and the posterior pole. Both regular and heavy silicone oils usually yield good success rates in cases of complicated retinal detachment. Decisions as to whether to utilize heavy or regular silicone oil should be made on a case-by-case basis.

  12. Biological effects of heavy particles

    International Nuclear Information System (INIS)

    Sabatier, L.; Martins, B.; Dutrillaux, B.

    1991-01-01

    The usual definitions of biological dose and biological dosimetry do not fit in case of particles with high linear energy transfer (LET). The dose corresponds to an average value which is not representative of the highly localized energy transfer due to heavy ions. Fortunately, up to now, a biological dosimetry following an exposure to high LET particles is necessary only for cosmonauts. In radiotherapy applications, one exactly knows the nature and energy of incident particle beams. The quality requirements for a good biodosimeter include reliable relation between dose and effect, weak sensitivity to individual variations, reliability and stability of acquired informations against the time delay between exposure and measurements. Nothing is better than the human lymphocyte to be used for measurements that fulfil these requirements. In the case of a manned spaceship, the irradiation dose corresponds to a wide range of radiation (protons, neutrons, heavy ions), and making a dosimetry as well as defining it are of current concern. As yet, there exist two possible definitions, which reduce the dose either to a proton or to a neutron equivalent one. However, such an approximation is not a faithful representation of the irradiation effects and in particular, the long-term effects may be quite different. In the future, it is reasonable to expect an evolution towards technics that enable identifying irradiated cells and quantifying precisely their radiation damage in order to reconstruct the spectrum of particles received by a given cosmonaut in a given time. Let us emphasize that the radiation hazards due to a short stay in space are quite minor, but in the case of a travel to Mars, they cannot be neglected [fr

  13. Assessment of heavy metal contamination of dustfall in northern China from integrated chemical and magnetic investigation

    Science.gov (United States)

    Qiao, Qingqing; Huang, Baochun; Zhang, Chunxia; Piper, John D. A.; Pan, Yuepeng; Sun, Ying

    2013-08-01

    Magnetic phases are a common component of dustfall samples and mineral magnetic studies have been increasingly exploited for air quality studies in recent years to assess the source and spatial-temporal distribution of anthropogenic magnetic particulates and associated heavy metals. Here we report a comparative study of magnetic and chemical properties of atmospheric particulate deposits from rural areas of Inner Mongolia and urban regions of Hebei and Beijing. The sample sets were collected at 13 monitoring stations by the gravimetric method between April 2009 and March 2010. At the rural sites paramagnetic clays, complemented by hematite and goethite recognized by Isothermal Remanent Magnetism (IRM) and Diffuse Reflectance Spectra (DRS) investigations, accompany fine grained magnetite as an important fraction. Although present as a residual phase in samples from the urban regions, coarse-grained magnetite of anthropogenic origin dominants the magnetic signatures in these latter environments. Systematic variations with local anthropogenic activity including traffic, the mining of ores and a range of industrial emissions are identified, together with a seasonal signature in the Beijing area. We use correlations between magnetic concentration-related parameters, notably magnetic susceptibility, and the Pollution Load Index to demonstrate how magnetic parameters can be used as a practical tool for mapping degrees of heavy metal pollution and tracing the sources of pollutants in dustfall samples.

  14. Iron and aluminium oxides containing industrial wastes as adsorbents of heavy metals: Application possibilities and limitations.

    Science.gov (United States)

    Jacukowicz-Sobala, Irena; Ociński, Daniel; Kociołek-Balawejder, Elżbieta

    2015-07-01

    Industrial wastes with a high iron or aluminium oxide content are produced in huge quantities as by-products of water treatment (water treatment residuals), bauxite processing (red mud) and hard and brown coal burning in power plants (fly ash). Although they vary in their composition, the wastes have one thing in common--a high content of amorphous iron and/or aluminium oxides with a large specific surface area, whereby this group of wastes shows very good adsorbability towards heavy metals, arsenates, selenates, etc. But their physical form makes their utilisation quite difficult, since it is not easy to separate the spent sorbent from the solution and high bed hydraulic resistances occur in dynamic regime processes. Nevertheless, because of the potential benefits of utilising the wastes in industrial effluent treatment, this issue attracts much attention today. This study describes in detail the waste generation processes, the chemical structure of the wastes, their physicochemical properties, and the mechanisms of fixing heavy metals and semimetals on the surface of iron and aluminium oxides. Typical compositions of wastes generated in selected industrial plants are given. A detailed survey of the literature on the adsorption applications of the wastes, including methods of their thermal and chemical activation, as well as regeneration of the spent sorbents, is presented. The existing and potential ways of modifying the physical form of the discussed group of wastes, making it possible to overcome the basic limitation on their practical use, are discussed. © The Author(s) 2015.

  15. Intraoperative neuromuscular monitoring site and residual paralysis.

    Science.gov (United States)

    Thilen, Stephan R; Hansen, Bradley E; Ramaiah, Ramesh; Kent, Christopher D; Treggiari, Miriam M; Bhananker, Sanjay M

    2012-11-01

    Residual paralysis is common after general anesthesia involving administration of neuromuscular blocking drugs (NMBDs). Management of NMBDs and reversal is frequently guided by train-of-four (TOF) monitoring. We hypothesized that monitoring of eye muscles is associated with more frequent residual paralysis than monitoring at the adductor pollicis. This prospective cohort study enrolled 180 patients scheduled for elective surgery with anticipated use of NMBDs. Collected variables included monitoring site, age, gender, weight, body mass index, American Society of Anesthesiologists physical status class, type and duration of surgery, type of NMBDs, last and total dose administered, TOF count at time of reversal, dose of neostigmine, and time interval between last dose of NMBDs to quantitative measurement. Upon postanesthesia care unit admission, we measured TOF ratios by acceleromyography at the adductor pollicis. Residual paralysis was defined as a TOF ratio less than 90%. Multivariable logistic regression was used to account for unbalances between the two groups and to adjust for covariates. 150 patients received NMBDs and were included in the analysis. Patients with intraoperative TOF monitoring of eye muscles had significantly greater incidence of residual paralysis than patients monitored at the adductor pollicis (P paralysis was observed in 51/99 (52%) and 11/51 (22%) of patients, respectively. The crude odds ratio was 3.9 (95% CI: 1.8-8.4), and the adjusted odds ratio was 5.5 (95% CI: 2.1-14.5). Patients having qualitative TOF monitoring of eye muscles had a greater than 5-fold higher risk of postoperative residual paralysis than those monitored at the adductor pollicis.

  16. Probability-scale residuals for continuous, discrete, and censored data.

    Science.gov (United States)

    Shepherd, Bryan E; Li, Chun; Liu, Qi

    2016-12-01

    We describe a new residual for general regression models, defined as pr ( Y * y ), where y is the observed outcome and Y * is a random variable from the fitted distribution. This probability-scale residual can be written as E {sign( y , Y * )} whereas the popular observed-minus-expected residual can be thought of as E ( y - Y * ). Therefore, the probability-scale residual is useful in settings where differences are not meaningful or where the expectation of the fitted distribution cannot be calculated. We present several desirable properties of the probability-scale residual that make it useful for diagnostics and measuring residual correlation, especially across different outcome types. We demonstrate its utility for continuous, ordered discrete, and censored outcomes, including current status data, and with various models including Cox regression, quantile regression, and ordinal cumulative probability models, for which fully specified distributions are not desirable or needed, and in some cases suitable residuals are not available. The residual is illustrated with simulated data and real datasets from HIV-infected patients on therapy in the southeastern United States and Latin America.

  17. Recent advances in residual stress measurement

    International Nuclear Information System (INIS)

    Withers, P.J.; Turski, M.; Edwards, L.; Bouchard, P.J.; Buttle, D.J.

    2008-01-01

    Until recently residual stresses have been included in structural integrity assessments of nuclear pressure vessels and piping in a very primitive manner due to the lack of reliable residual stress measurement or prediction tools. This situation is changing the capabilities of newly emerging destructive (i.e. the contour method) and non-destructive (i.e. magnetic and high-energy synchrotron X-ray strain mapping) residual stress measurement techniques for evaluating ferritic and austenitic pressure vessel components are contrasted against more well-established methods. These new approaches offer the potential for obtaining area maps of residual stress or strain in welded plants, mock-up components or generic test-pieces. The mapped field may be used directly in structural integrity calculations, or indirectly to validate finite element process/structural models on which safety cases for pressurised nuclear systems are founded. These measurement methods are complementary in terms of application to actual plant, cost effectiveness and measurements in thick sections. In each case an exemplar case study is used to illustrate the method and to highlight its particular capabilities

  18. Heavy ion inertial fusion

    International Nuclear Information System (INIS)

    Keefe, D.; Sessler, A.M.

    1980-01-01

    Inertial fusion has not yet been as well explored as magnetic fusion but can offer certain advantages as an alternative source of electric energy for the future. Present experiments use high-power beams from lasers and light-ion diodes to compress the deuterium-tritium (D-T) pellets but these will probably be unsuitable for a power plant. A more promising method is to use intense heavy-ion beams from accelerator systems similar to those used for nuclear and high-energy physics; the present paper addresses itself to this alternative. As will be demonstrated the very high beam power needed poses new design questions, from the ion-source through the accelerating system, the beam transport system, to the final focus. These problems will require extensive study, both theoretically and experimentally, over the next several years before an optimum design for an inertial fusion driver can be arrived at. (Auth.)

  19. LEXUS heavy ion collisions

    CERN Document Server

    Sang Yong Jeon

    1997-01-01

    We use a Glauber-like approach to describe very energetic nucleus- nucleus collisions as a sequence of binary nucleon-nucleon collisions. No free parameters are needed: all the information comes from simple parametrizations of nucleon-nucleon collision data. Produced mesons are assumed not to interact with each other or with the original baryons. Comparisons are made to published experimental measurements of baryon rapidity and transverse momentum distributions, negative hadron rapidity and transverse momentum distributions, average multiplicities of pions, kaons, hyperons, and antihyperons, and zero degree energy distributions for sulfur-sulfur collisions at 200 GeV/c per nucleon and for lead-lead collisions at 158 GeV/c per nucleon. Good agreement is found except that the number of strange particles produced, especially antihyperons, is too small compared with experiment. We call this model LEXUS: Linear EXtrapolation of Ultrarelativistic nucleon-nucleon Scattering to heavy ion collisions. (11 refs).

  20. Relativistic heavy ion physics

    International Nuclear Information System (INIS)

    Hill, J.C.; Wohn, F.K.

    1993-01-01

    This is a progress report for the period May 1992 through April 1993. The first section, entitled ''Purpose and Trends, gives background on the recent trends in the research program and its evolution from an emphasis on nuclear structure physics to its present emphasis on relativistic heavy ion and RHIC physics. The next section, entitled ''Physics Research Progress'', is divided into four parts: participation in the program to develop a large detector named PHENIX for the RHIC accelerator; joining E864 at the AGS accelerator and the role in that experiment; progress made in the study of electromagnetic dissociation highlight of this endeavor is an experiment carried out with the 197 Au beam from the AGS accelerator in April 1992; progress in completion of the nuclear structure studies. In the final section a list of publications, invited talks, and contributed talks is given

  1. Heavy meson spectroscopy

    International Nuclear Information System (INIS)

    Chakrabarty, S.

    1989-08-01

    In this article we give a review of certain aspects of the present understanding of spectroscopy of heavy mesons and constituent quark masses in the light of non-relativistic potential model approach motivated by quantum chromodynamics. We find that the one gluon exchange at short distance and colour-confining interaction at large distance which is pure scalar (or scalar-vector admixture with dominant scalar interaction) under the Lorentz transformation, can explain only partially the present data on 1P states of cc-bar and bb-bar states. The S-wave data, that are available at present, however can be understood with both scalar confinement or scalar-vector admixture with scalar-dominant interaction. (author). 44 refs, 13 tabs

  2. Heavy flavor results from CMS

    CERN Document Server

    Ronchese, Paolo

    2017-01-01

    Heavy flavor particles produced in LHC $pp$ collisions at $7, 8,$ and $13~\\mathrm{TeV}$ constitute an excellent opportunity to test the standard model and probe for new physics effects. Recent results by the CMS Collaboration on heavy flavor production and decays are presented.

  3. Heavy-ion superconducting linacs

    International Nuclear Information System (INIS)

    Delayen, J.R.

    1989-01-01

    This paper reviews the status of the superconducting heavy-ion accelerators. Most of them are linacs used as boosters for tandem electrostatic accelerators, although the technology is being extended to very low velocity to eliminate the need for an injector. The characteristics and features of the various superconducting heavy-ion accelerators are discussed. 45 refs

  4. in heavy-ion collisions

    Indian Academy of Sciences (India)

    2015-05-06

    May 6, 2015 ... the 'Big Bang', and has now been (re-)created as the hottest matter ever in laboratory by heavy-ion collisions ('Little Bang') at the Relativistic Heavy Ion Collider (RHIC) as well as at the Large Hadron Collider (LHC). To experimentally measure and theoretically understand the various properties of the QGP ...

  5. Esterase resistant to inactivation by heavy metals

    KAUST Repository

    El, Dorry Hamza

    2014-09-25

    EstATII is an esterase that a halotolerant, thermophilic and resistant to a spectrum of heavy metals including toxic concentration of metals. It was isolated from the lowest convective layer of the Atlantis II Red Sea brine pool. The Atlantis II brine pool is an extreme environment that possesses multiple harsh conditions such as; high temperature, salinity, pH and high concentration of metals, including toxic heavy metals. A fosmid metagenomic library using DNA isolated from the lowest convective layer this pool was used to identify EstATII. Polynucleotides encoding EstATII and similar esterases are disclosed and can be used to make EstATII. EstATII or compositions or apparatuses that contain it may be used in various processes employing lipases/esterases especially when these processes are performed under harsh conditions that inactivate other kinds of lipases or esterases.

  6. Residual stress by repair welds

    International Nuclear Information System (INIS)

    Mochizuki, Masahito; Toyoda, Masao

    2003-01-01

    Residual stress by repair welds is computed using the thermal elastic-plastic analysis with phase-transformation effect. Coupling phenomena of temperature, microstructure, and stress-strain fields are simulated in the finite-element analysis. Weld bond of a plate butt-welded joint is gouged and then deposited by weld metal in repair process. Heat source is synchronously moved with the deposition of the finite-element as the weld deposition. Microstructure is considered by using CCT diagram and the transformation behavior in the repair weld is also simulated. The effects of initial stress, heat input, and weld length on residual stress distribution are studied from the organic results of numerical analysis. Initial residual stress before repair weld has no influence on the residual stress after repair treatment near weld metal, because the initial stress near weld metal releases due to high temperature of repair weld and then stress by repair weld regenerates. Heat input has an effect for residual stress distribution, for not its magnitude but distribution zone. Weld length should be considered reducing the magnitude of residual stress in the edge of weld bead; short bead induces high tensile residual stress. (author)

  7. Selected heavy metals speciation in chemically stabilised sewage sludge

    Science.gov (United States)

    Wiśniowska, Ewa; Włodarczyk-Makuła, Marła

    2017-11-01

    Selected heavy metals (Pb, Ni, Cd) were analysed in soil, digested sewage sludge as well as in the sludge stabilised with CaO or Fenton's reagent. The dose of Fenton's reagent was as follows: Fe2+ = 1g.L-1, Fe2+/H2O2=1:100; stabilisation lasted for 2 h. Dose of CaO was equal to 1 g CaO.g d.m.-1 Total concentration of all metals in the digested sewage sludge was higher than in the soil. Chemical stabilisation of sludge with Fenton's reagent increased total metal content in the sludge as a result of total solids removal. Opposite effect was stated when the sludge was mixed with CaO. Also chemical fractions of heavy metals were identified (exchangeable, carbonate bound, iron oxides bound, organic and residual). The results indicate that stabilisation of the sludge with Fenton's reagent increased mobility of heavy metals compared to the digested sludge. Amendment of CaO increased percent share of examined metals in residual fraction, thus immobilised them and decreased their bioavailability.

  8. Results of heavy ion radiotherapy

    International Nuclear Information System (INIS)

    Castro, J.R.

    1994-04-01

    The potential of heavy ion therapy for clinical use in cancer therapy stems from the biological parameters of heavy charged particles, and their precise dose localization. Biologically, carbon, neon and other heavy ion beams (up to about silicon) are clinically useful in overcoming the radioresistance of hypoxic tumors, thus increasing biological effectiveness relative to low-LET x-ray or electron beams. Cells irradiated by heavy ions show less variation in cell-cycle related radiosensitivity and decreased repair of radiation injury. The physical parameters of these heavy charged particles allow precise delivery of high radiation doses to tumors while minimizing irradiation of normal tissues. Clinical use requires close interaction between radiation oncologists, medical physicists, accelerator physicists, engineers, computer scientists and radiation biologists

  9. Heavy metal sorption by microalgae

    Energy Technology Data Exchange (ETDEWEB)

    Sandau, E. [IGV - Inst. fuer Getreideverarbeitung GmbH, Bergholz-Rehbruecke (Germany); Sandau, P. [IGV - Inst. fuer Getreideverarbeitung GmbH, Bergholz-Rehbruecke (Germany); Pulz, O. [IGV - Inst. fuer Getreideverarbeitung GmbH, Bergholz-Rehbruecke (Germany)

    1996-12-31

    Viable microalgae are known to be able to accumulate heavy metals (bioaccumulation). Against a background of the increasing environmental risks caused by heavy metals, the microalgae Chlorella vulgaris and Spirulina platensis and their potential for the biological removal of heavy metals from aqueous solutions were taken as an example for investigation. Small-scale cultivation tests (50 l) with Cd-resistant cells of Chlorella vulgaris have shown that approx. 40% of the added 10 mg Cd/l was removed from the solution within seven days. At this heavy metal concentration sensitive cells died. Non-viable microalgae are able to eliminate heavy metal ions in a short time by biosorption in uncomplicated systems, without any toxicity problems. Compared with original biomasses, the sorption capacity of microalgal by-products changes only insignificantly. Their low price makes them economical. (orig.)

  10. Improvement of the focal-plane detector system for medium heavy ions

    International Nuclear Information System (INIS)

    Wan Yude; Li Zhongzhen

    1992-01-01

    An improved medium heavy ion focal-plane detector system (500 mm long) was tested with beam and has been used in nuclear physics experiment. The measured results at tandem accelerator with 66 MeV 12 C beam are: the energy resolution of the residual energy E detector is about 7%. The experiment of particle discrimination has been performed

  11. Review of Phosphate in soils: Interaction with micronutrients, radionuclides, and heavy metals

    Science.gov (United States)

    Phosphate-phosphorus present in the vadose zone of soil as native, added, or residual fertilizer influences the retention, transport, and bioavailability of heavy metals, metalloids, or metallic radionuclides to aboveground vegetation, soil microorganisms, and fauna that browse that vegetation, or d...

  12. Heavy flavour production and spectroscopy at LHCb

    CERN Document Server

    INSPIRE-00258787

    2012-01-01

    At the Moriond QCD conference LHCb has presented results on heavy flavour production and spectroscopy. Here the latest results are discussed, which include the first observation and measurement of the branching fraction of the hadronic decay $B^+_e \\to J/\\psi\\pi^+ \\pi^- \\pi^+$, the mass measurement of the excited B mesons and the mass measurement of the $\\Xi_b$ and $\\Omega_b$ baryons.

  13. ATLAS Heavy Flavor productions and decay properties

    CERN Document Server

    Smirnova, Lidia; The ATLAS collaboration

    2015-01-01

    First measurements of non-prompt J/psi fraction in pp collisions at √s = 13 TeV and new results from RUN 1 data analysis are presented for heavy flavor production and decays. RUN 1 results include observation and measurement of Z + J/Ψ associated production, fs/fd measurements and the branching ratio measurement for Λb decays to Ψ(2S) + Λ and J/Ψ + Λ.

  14. RESIDUAL RISK ASSESSMENT: ETHYLENE OXIDE ...

    Science.gov (United States)

    This document describes the residual risk assessment for the Ethylene Oxide Commercial Sterilization source category. For stationary sources, section 112 (f) of the Clean Air Act requires EPA to assess risks to human health and the environment following implementation of technology-based control standards. If these technology-based control standards do not provide an ample margin of safety, then EPA is required to promulgate addtional standards. This document describes the methodology and results of the residual risk assessment performed for the Ethylene Oxide Commercial Sterilization source category. The results of this analyiss will assist EPA in determining whether a residual risk rule for this source category is appropriate.

  15. Properties of residuals for spatial point processes

    DEFF Research Database (Denmark)

    Baddeley, A.; Møller, Jesper; Pakes, A.G.

    For any point process in $R^d$ that has a Papangelou conditional intensity $lambda$, we define a random measure of ‘innovations’ which has mean zero. When the point process model parameters are estimated from data, there is an analogous random measure of ‘residuals’. We analyse properties of the ...... of the innovations and residuals, including first and second moments, conditional independence, a martingale property, lack of correlation, and marginal distributions....

  16. Fate of heavy metals during municipal solid waste incineration in Shanghai.

    Science.gov (United States)

    Zhang, Hua; He, Pin-Jing; Shao, Li-Ming

    2008-08-15

    The transfer behavior of heavy metals during municipal solid waste (MSW) incineration was investigated based on 2-year field measurements in two large-scale incinerators in Shanghai. Great temporal and spatial diversification was observed. Most of Hg and Cd were evaporated and then removed by air pollution control (APC) system through condensation and adsorption processes, thus being enriched in the fine APC residues particles. Cr, Cu, and Ni were transferred into the APC residues mainly by entrainment, and distributed uniformly in the two residues flows, as well as in the ash particles with different sizes. Pb and Zn in the APC residues were from both entrainment and evaporation, resulting in the higher concentrations (two to four times) compared with the bottom ash. Arsenic was transported into the flue gas mainly by evaporation, however, its transfer coefficient was lower. Though the heavy metals contents in the APC residues were higher than that in bottom ash, more than 80% of As, Cr, Cu, and Ni, 74-94% of Zn, as well as 46-79% of Pb remained in the bottom ash, due to its high mass ratio (85-93%) in the residues. While 47-73% of Cd and 60-100% of Hg were transferred into the APC residues, respectively.

  17. A systematic workflow process for heavy oil characterization : experimental techniques and challenges

    Energy Technology Data Exchange (ETDEWEB)

    Memon, A.I.; Gao, J.; Taylor, S.D.; Davies, T.L.; Jia, N. [Schlumberger, Edmonton, AB (Canada)

    2010-07-01

    Fluid characterization of heavy oil and bitumen is necessary when choosing the best extraction, production, and processing methods. High viscosity, low API, low saturation pressure, and low gas to oil ratios impose challenges in measuring fluid properties of heavy oil. This paper summarized the heavy oil fluid characterization technique that includes fluid sample handling, PVT analysis, fluid viscosity, emulsion and rheology, slow kinetics of gas evolution during constant composition expansion (CCE) experiments, solvent solubility, steam stripping, and high temperature vapor-liquid equilibrium of oil-solvent-steam systems. The paper also proposed a heavy oil characterization workflow to address a broad range of heavy oil production scenarios, including cold depletion, steam flow and heavy oil flow assurance. The workflow was based on various experimental techniques and challenges facing heavy oil sample preparation. Fluid property measurement requirements for each production technique were also compiled. 16 refs., 13 figs.

  18. An Evaluation of the Delayed-Coking Product Yield of Heavy Feedstocks Using Asphaltene Content and Carbon Residue Évaluation du rendement en produit de cokéfaction différée de pétrole lourd à l'aide de la teneur an asphaltènes et du résidu de coke

    Directory of Open Access Journals (Sweden)

    Schabron J. F.

    2006-11-01

    Full Text Available Six residua from different crude oils were evaluated for composition and carbon residue forming tendencies. The whole residua were evaluated for elemental composition, trace metals content, carbon residue, and specific gravity. Each residuum was deasphaltened in heptane, and the heptane-soluble materials were separated into saturate, aromatic, and polar fractions on activated silica gel. The asphaltenes were evaluated for elemental composition, trace metals content, molecular weight, and carbon residue. The relationship between carbon residues and features of the asphaltenes was studied, and a correlation of contributing features was developed. The asphaltenes were further separated into four fractions according to apparent molecular size by preparative size exclusion chromatography (SEC. The preparative size exclusion chromatographic fractions from the asphaltenes were evaluated for sulfur content, molecular weight, and trace metals content. Material balances showed that the data obtained on the fractions account for the data obtained on the original material. This indicates that the contributions of the properties of the fractions can be studied and related to properties of the whole material. La composition et le résidu de coke de six résidus de raffinage de différents pétroles lourds ont été évalués afin de déterminer des tendances. La composition élémentaire, la teneur en métaux-traces, le résidu de coke et la densité spécifique ont été déterminés sur le résidu complet. Chaque résidu a été désasphalténé dans l'heptane et les produits solubles dans l'heptane ont été séparés en fractions saturée, aromatique et polaire sur du gel de silice activée. La composition élémentaire, la teneur en métaux-traces, la masse moléculaire et le résidu de coke ont été déterminés sur les asphaltènes. La relation entre les résidus de coke et les caractéristiques des asphaltènes a été étudiée, ce qui a permis d

  19. Evaluation of pesticide residues in fruits and vegetables from Algeria.

    Science.gov (United States)

    Mebdoua, Samira; Lazali, Mohamed; Ounane, Sidi Mohamed; Tellah, Sihem; Nabi, Fahima; Ounane, Ghania

    2017-06-01

    A total of 160 samples of 13 types of fresh fruits and vegetables from domestic production and import were analysed to detect the presence of pesticide residues. Analysis was performed by multi-residual extraction followed by gas chromatography-mass spectrometry. In 42.5% of the tested samples, no residues were found and 12.5% of samples contained pesticide residues above maximum residue limits. Risk assessment for long-term exposure was done for all pesticides detected in this study. Except chlorpyrifos and lambda-cyhalothrin, exposure to pesticides from vegetables and fruits was below 1% of the acceptable daily intake. Short-term exposure assessment revealed that in seven pesticide/commodity combinations, including three pesticides (chlorpyrifos, deltamethrin and lambda-cyhalothrin), the acute reference dose had been exceeded.

  20. Agrochemical residues in rivers sediments, Poas, Costa Rica

    International Nuclear Information System (INIS)

    Masis, Federico; Valdez, Juan; Leon, Sandra; Coto, Tatiana

    2008-01-01

    The organophosphorus and organochlorine agrochemical residues distribution in sediments of 3 rivers located in an ornamental plant production area were analyzed in Poas canton, Alajuela, Costa Rica. The study comprised 8 months in order to assure 3 seasonal episodes: dry, transitional, and rainy seasons. Sediments were taken in 10 sampling stations along the rivers and characterized by a determination of their organic matter and texture. In 7 out of 10 sampling stations pesticide residues were detected in at least 1 of 4 samplings, but quantified only in 4 stations. Agrochemical residues evaluated included 21 organophosphorus and organochlorine pesticides; however, we found residues of only 3 organochlorine pesticides, due their high persistence in the sediment. Residues corresponded to PCNB (80-800 μg.kg -1 ), Endosulfan-β (40-50 μg.kg -1 ), and Endosulfan-α (90 μg.kg -1 ). Chlorothalonil was detected in only one sample. (author) [es

  1. Residual stress studies of austenitic and ferritic steels

    International Nuclear Information System (INIS)

    Chrenko, R.M.

    1978-01-01

    Residual studies have been made on austenitic and ferritic steels of the types used as structural materials. The residual stress results presented here will include residual stress measurements in the heat-affected zone on butt welded Type 304 stainless steel pipes, and the stresses induced in Type 304 austenitic stainless steel and Type A508 ferritic steel by several surface preparations. Such surface preparation procedures as machining and grinding can induce large directionality effects in the residual stresses determined by X-ray techniques and some typical data will be presented. A brief description is given of the mobile X-ray residual stress apparatus used to obtain most of the data in these studies. (author)

  2. Migration and transformation rule of heavy metals in sludge during hydrolysis for protein extraction.

    Science.gov (United States)

    Li, Yulong; Xue, Fei; Li, Jiebing; Xu, Shi Hong; Li, Dengxin

    2016-03-01

    The content and speciation of heavy metals can fundamentally affect the hydrolysis of sludge. This research study investigates the migration and transformation rule of heavy metals during the hydrolysis process by measuring the content of exchangeables (F1), bound to carbonates (F2), bound to Fe-Mn oxides (F3), bound to organic matter (F4), and residuals (F5) under different periods of time undergoing hydrolysis. The results show that the hydrolysis process generally stabilized Cu, Zn, Mn, Ni, Pb, Cr, and As by transforming the unstable states into structurally stable states. Such transformations and stabilization were primarily caused by the changes in local metal ion environment and bonding structure, oxidation of sulfides, pyrolyzation of organic matter, and evaporation of resulting volatile materials. An X-ray diffractometry (XRD) of the residuals conducted after hydrolysis indicated that hydrolysis did have a significant influence on the transportation and transformation of heavy metals.

  3. A review on heavy metal contamination in the soil worldwide: Situation, impact and remediation techniques

    Directory of Open Access Journals (Sweden)

    Chao Su

    2014-06-01

    Full Text Available Heavy metals in the soil refers to some significant heavy metals of biological toxicity, including mercury (Hg, cadmium (Cd, lead (Pb, chromium (Cr, and arsenic (As, etc. With the development of the global economy, both type and content of heavy metals in the soil caused by human activities have gradually increased in recent years, which have resulted in serious environment deterioration. In present study we compared and analyzed soil contamination of heavy metals in various cities/countries, and reviewed background, impact and remediation methods of soil heavy metal contamination worldwide.

  4. Accumulation of Heavy Metals in Soil and Kiwifruit of Planting Base in Western Hunan Province, China

    Directory of Open Access Journals (Sweden)

    WANG Ren-cai

    2017-05-01

    Full Text Available The heavy metals accumulation in soil and kiwi fruit plant in Western Hunan Province main kiwifruit planting base were analyzed, such as As, Pb, Hg, Cd, Cr. The results showed that the accumulation of heavy metals in soil of 6 kiwifruit planting areas were not obvious. The contents of heavy metals in most of areas of Western Hunan Province were below the national standard, except one area where the soil contents of cadmium (4.900 mg·kg-1, mercury (0.634 mg·kg-1were exceeded. At the same time, the comprehensive pollution index of heavy metals was less than 0.7 in these areas. There were 5 bases with no pollution of heavy metal, all which the kiwifruit could be safely produced in line with the requirements of the green kiwifruit planting base soil standards. At these areas, the contents of various heavy metals(except cadmium and mercurywere small in the branches and leaves of kiwifruit; kiwifruit had a very well capacity to absorb the cadmium when the cadmium content of its branches reached 12.73%. The heavy metal contents of the kiwifruit in the 6 regions, which belonging to the pollutionfree green fruits, were below or far lower than the national standard. According to the comprehensive analysis, the soil condition of the main cultivated land in Western Hunan Province was good, and the fruit had no heavy metal residues.

  5. Integrated assessment of soil quality after application of the biogas fermentation residues - a laboratory experiment

    Science.gov (United States)

    Telesiński, Arkadiusz; Cybulska, Krystyna; Płatkowski, Maciej; Stręk, Michał; Jarnuszewski, Grzegorz; Wrońska, Ilona; Mularewicz, Piotr; Kajdan, Tomasz; Biczak, Robert; Kołosowski, Paweł

    2017-11-01

    The aim of study was to determine the impact of three different biogas fermentation residues on some chemical and biochemical characteristics in sandy soil. The laboratory experiment was carried out on loamy sand. Residues were added to soil samples in the forms of pulp, drought, and granulate at dosages of 10, 50, and 100 g·kg-1. The reference was the soil sample without residues. On day 28, the content of macroelements and heavy metals was determined. In addition, on days 1, 7, 14, 28, and 56, the content of biomass and the activities of some hydrolases and oxidoreductases were assayed. Results showed that the application of all fermentation residues caused an increase in most of the chemical parameters. The highest impact on pH and the content of Ctot, Ntot, Stot, K, and P was observed in the soil treated with granulate, whereas the increase in the content of heavy metals was the highest after the drought application. The effect of biogas fermentation residues on all hydrolases and o-diphenol oxidase activities was mostly significant, but depended on the kind of residues and the day of experiment. Biomass content and the activity of dehydrogenase were increased in the whole experiment.

  6. Nitrogen availability of biogas residues

    Energy Technology Data Exchange (ETDEWEB)

    El-Sayed Fouda, Sara

    2011-09-07

    The objectives of this study were to characterize biogas residues either unseparated or separated into a liquid and a solid phase from the fermentation of different substrates with respect to their N and C content. In addition, short and long term effects of the application of these biogas residues on the N availability and N utilization by ryegrass was investigated. It is concluded that unseparated or liquid separated biogas residues provide N at least corresponding to their ammonium content and that after the first fertilizer application the C{sub org}:N{sub org} ratio of the biogas residues was a crucial factor for the N availability. After long term application, the organic N accumulated in the soil leads to an increased release of N.

  7. OECD Maximum Residue Limit Calculator

    Science.gov (United States)

    With the goal of harmonizing the calculation of maximum residue limits (MRLs) across the Organisation for Economic Cooperation and Development, the OECD has developed an MRL Calculator. View the calculator.

  8. Fractionation, transfer, and ecological risks of heavy metals in riparian and ditch wetlands across a 100-year chronosequence of reclamation in an estuary of China

    International Nuclear Information System (INIS)

    Xiao, Rong; Bai, Junhong; Lu, Qiongqiong; Zhao, Qingqing; Gao, Zhaoqin; Wen, Xiaojun; Liu, Xinhui

    2015-01-01

    The effect of reclamation on heavy metal concentrations and the ecological risks in ditch wetlands (DWs) and riparian wetlands (RWs) across a 100-year chronosequence in the Pearl River Estuary of China was investigated. Concentrations of 4 heavy metals (Cd, Cu, Pb, and Zn) in soil and plant samples, and sequential extracts of soil samples were determined, using inductively coupled plasma atomic absorption spectrometry. Results showed that heavy metal concentrations were higher in older DW soils than in the younger ones, and that the younger RW soils contained higher heavy metal concentrations compared to the older ones. Although the increasing tendency of heavy metal concentrations in soil was obvious after wetland reclamation, the metals Cu, Pb, and Zn exhibited low or no risks to the environment based on the risk assessment code (RAC). Cd, on the other hand, posed a medium or high risk. Cd, Pb, and Zn were mainly bound to Fe–Mn oxide, whereas most of Cu remained in the residual phase in both ditch and riparian wetland soils, and the residual proportions generally increased with depth. Bioconcentration and translocation factors for most of these four heavy metals significantly decreased in the DWs with older age (p < 0.05), whereas they increased in the RWs with younger age (p < 0.05). The DW soils contained higher concentrations of heavy metals in the organic fractions, whereas there were more carbonate and residual fractions in the RW soils. The non-bioavailable fractions of Cu and Zn, and the organic-bound Cd and Pb significantly inhibited plant growth. - Highlights: • Heavy metals in ditch wetland accumulated with increasing reclamation history. • Heavy metals exist in the Fe–Mn oxides and residual fractions in both wetlands. • Cd posed a medium to high environmental risk while low risk for other metals. • Long reclamation history caused lower BCFs and TFs in DWs and higher levels in RWs. • RW soils contained more heavy metals in the carbonate

  9. Toxicity of heavy metals in the environment

    National Research Council Canada - National Science Library

    Oehme, F.W

    1978-01-01

    ... as the fundamental mechanisms of toxicity resulting from heavy metal chemicals. The more common toxic heavy metals, along with their biochemistry and associated clinical syndromes, are then described...

  10. Pesticide residues in brain tissues of dairy cattle in Lembang

    Directory of Open Access Journals (Sweden)

    Indraningsih

    2006-03-01

    Full Text Available The use of pesticides to control plant diseases may cause residual formation in crops, its byproduct and environmental. Furthermore, the use of agriculture byproduct as animal feed may cause poisoning or residual formation in animal products. The purpose of this study is to investigate of pesticide residues in brain tissues of dairy cattle in relation to animal feed as a contamination source. Samples consisted of animal feeds (19 samples of fodder and 6 samples of feed, 31 samples of sera and 25 samples of brain tissues of dairy cattle collected from Lembang, West Java. Feeds and fodders were collected from dairy farms located in Lembang. Sera were directly collected from 31 heads of Frisien Holstein (FH cattle from the same location, while brain tissues of FH cattle were collected from a local animal slaughtering house. Pesticide residues were analysed using gas chromatography (GC. Both residues of organochlorines and organophosphates were detected from brain tissues with average residue concentration OP was 22.7 ppb and OC was 5.1 ppb and a total residue was 27.8 ppb. The pesticide residues in brain tissues are new information that should be taken into consideration since the Indonesian consumed this tissues as an oval. Although pesticides residue concentration was low, pathological changes were noted microscopically from the brain tissues including extracellular vacuolisation, focal necrosis, haemorrhages, dilatation of basement membrane without cellular infiltration. Both pesticide residues were also detected in sera, where OP (9.0 ppb was higher than OC (4.9 ppb. These pesticides were also detected in animal feeds consisting fodders and feeds. Residues of OP (12.0 ppb were higher than OC (1.8 ppb in feeds, but residues of OP (16.8 ppb were lower than OC (18.7 ppb in fodders. Although, pesticide residues in sera and brain tissues were below the maximum residue limits (MRL of fat, the presence of pesticides in brain tissues should be taken

  11. Vesícula residual

    Directory of Open Access Journals (Sweden)

    Júlio C. U. Coelho

    Full Text Available Our objective is to report three patients with recurrent severe upper abdominal pain secondary to residual gallbladder. All patients had been subjected to cholecystectomy from 1 to 20 years before. The diagnosis was established after several episodes of severe upper abdominal pain by imaging exams: ultrasonography, tomography, or endoscopic retrograde cholangiography. Removal of the residual gallbladder led to complete resolution of symptoms. Partial removal of the gallbladder is a very rare cause of postcholecystectomy symptoms.

  12. A unified model for nucleosynthesis of heavy elements in stars

    OpenAIRE

    Kiss, Miklós; Trócsányi, Zoltán

    2017-01-01

    We propose a unified model for the nucleosynthesis of heavy (A > 57) elements in stars. The neutron flux can be set to describe neutron capture in arbitrary neutron flux. Our approach solves the coupled differential equations, that describe the neutron capture and decays of 2696 nuclei, numerically without truncating those to include only either capture or decay as traditionally assumed in weak neutron flux (s process). As a result the synthesis of heavy nuclei always evolves along a wide ban...

  13. Relativistic heavy-atom effects on heavy-atom nuclear shieldings

    Science.gov (United States)

    Lantto, Perttu; Romero, Rodolfo H.; Gómez, Sergio S.; Aucar, Gustavo A.; Vaara, Juha

    2006-11-01

    The principal relativistic heavy-atom effects on the nuclear magnetic resonance (NMR) shielding tensor of the heavy atom itself (HAHA effects) are calculated using ab initio methods at the level of the Breit-Pauli Hamiltonian. This is the first systematic study of the main HAHA effects on nuclear shielding and chemical shift by perturbational relativistic approach. The dependence of the HAHA effects on the chemical environment of the heavy atom is investigated for the closed-shell X2+, X4+, XH2, and XH3- (X =Si-Pb) as well as X3+, XH3, and XF3 (X =P-Bi) systems. Fully relativistic Dirac-Hartree-Fock calculations are carried out for comparison. It is necessary in the Breit-Pauli approach to include the second-order magnetic-field-dependent spin-orbit (SO) shielding contribution as it is the larger SO term in XH3-, XH3, and XF3, and is equally large in XH2 as the conventional, third-order field-independent spin-orbit contribution. Considering the chemical shift, the third-order SO mechanism contributes two-thirds of the difference of ˜1500ppm between BiH3 and BiF3. The second-order SO mechanism and the numerically largest relativistic effect, which arises from the cross-term contribution of the Fermi contact hyperfine interaction and the relativistically modified spin-Zeeman interaction (FC/SZ-KE), are isotropic and practically independent of electron correlation effects as well as the chemical environment of the heavy atom. The third-order SO terms depend on these factors and contribute both to heavy-atom shielding anisotropy and NMR chemical shifts. While a qualitative picture of heavy-atom chemical shifts is already obtained at the nonrelativistic level of theory, reliable shifts may be expected after including the third-order SO contributions only, especially when calculations are carried out at correlated level. The FC/SZ-KE contribution to shielding is almost completely produced in the s orbitals of the heavy atom, with values diminishing with the principal

  14. Marine Tar Residues: a Review.

    Science.gov (United States)

    Warnock, April M; Hagen, Scott C; Passeri, Davina L

    Marine tar residues originate from natural and anthropogenic oil releases into the ocean environment and are formed after liquid petroleum is transformed by weathering, sedimentation, and other processes. Tar balls, tar mats, and tar patties are common examples of marine tar residues and can range in size from millimeters in diameter (tar balls) to several meters in length and width (tar mats). These residues can remain in the ocean environment indefinitely, decomposing or becoming buried in the sea floor. However, in many cases, they are transported ashore via currents and waves where they pose a concern to coastal recreation activities, the seafood industry and may have negative effects on wildlife. This review summarizes the current state of knowledge on marine tar residue formation, transport, degradation, and distribution. Methods of detection and removal of marine tar residues and their possible ecological effects are discussed, in addition to topics of marine tar research that warrant further investigation. Emphasis is placed on benthic tar residues, with a focus on the remnants of the Deepwater Horizon oil spill in particular, which are still affecting the northern Gulf of Mexico shores years after the leaking submarine well was capped.

  15. Examining factors associated with heavy episodic drinking among college undergraduates

    Directory of Open Access Journals (Sweden)

    Kristen Scholly

    2014-08-01

    Full Text Available Heavy episodic drinking among college students is a serious health concern. The purpose of this study was to identify factors associated with heavy episodic drinking behaviors amongst a predominately Asian undergraduate college student population in the United States. A survey measuring alcohol use behaviors was completed by a random sample of 18-24 year old undergraduates during April, 2011. A multivariate logistic regression analysis was conducted to determine factors associated with students’ heavy episodic drinking behavior. Independent factors associated with heavy episodic drinking included living on campus, ethnicity, perceived drinking behavior among peers, and a belief that alcohol is a central part of one’s social life. Heavy episodic drinking was also associated with poor academic performance. Campus-wide educational strategies to reduce heavy episodic drinking among college undergraduates should incorporate accurate information regarding alcohol use norms to correct students’ perceived over estimation of their peers alcohol consumption rates and the under estimation of students protective alcohol use behaviors. These efforts should focus in on-campus residence halls where a higher occurrence of heavy episodic drinking is often found.

  16. From heavy nuclei to super-heavy nuclei

    International Nuclear Information System (INIS)

    Theisen, Ch.

    2003-01-01

    The existence of super-heavy nuclei has been predicted nearly fifty years ago. Due to the strong coulomb repulsion, the stabilisation of these nuclei is possible only through shell effects. The reasons for this fragile stability, as well as the theoretical predictions concerning the position of the island of stability are presented in the first part of this lecture. In the second part, experiments and experimental techniques which have been used to synthesize or search for super-heavy elements are described. Spectroscopic studies performed in very heavy elements are presented in the following section. We close this lecture with techniques that are currently being developed in order to reach the superheavy island and to study the structure of very-heavy nuclei. (author)

  17. Lithic Residue Survival and Characterisation at Star Carr: a burial experiment

    Directory of Open Access Journals (Sweden)

    Shannon Croft

    2016-09-01

    Full Text Available A modern burial experiment was devised to test microscopic residue survival in acidic peat and slightly acidic clay soils at the Early Mesolithic site of Star Carr (North Yorkshire, UK, and at nearby control location. The experiment addresses concerns regarding the applicability of residue analysis in varied burial environments, and particularly in highly acidic archaeological conditions. Flint flakes (n= 78, including blank controls were used on twelve plant, animal, and mineral materials to create residues and then buried. The residues were examined 1 month and 11 months after burial. An unburied reference collection containing the same twelve residue types in a fresh state was compared to the buried residues to assess diagenesis. The residue types that survived across all burial conditions and time intervals were: softwood tissue, tree resin, bird feathers, squirrel hair, and red ochre. During microscopic analysis, it became clear that many residues lack diagnostic traits, and thus an assessment of the extent to which each residue can be identified was conducted. The degree to which residues were able to be identified was further investigated with a variable pressure scanning electron microscope (SEM. SEM images of the reference residues were compared to the reflected VLM micrographs of the same residues, which improved characterisation in some cases. Residues were grouped into three categories (diagnostic, distinctive, and non-distinctive within a visual characterisation guide. Our in situ microscopic analyses indicated that few residue types have diagnostic traits that allow them to be identified unambiguously, and thus further characterisation techniques are often required.

  18. Lignin biochemistry and soil N determine crop residue decomposition and soil priming

    Science.gov (United States)

    Cropping history can affect soil properties, including available N, but little is known about the interactive effects of residue biochemistry, temperature and cropping history on residue decomposition. A laboratory incubation examined the role of residue biochemistry and temperature on the decomposi...

  19. Electron cloud studies for heavy-ion and proton machines

    CERN Document Server

    Petrov, F; Weiland, Th

    2013-01-01

    Electron cloud effects are a known problem in various accelerator facilities around the world. Electron clouds cause instabilities and emittance growth in positron and proton beams as well as in heavy ion beams. Most of the hadron machines experience the build-up of EC due to the multipacting. In LHC and in positron machines production of electrons due to the synchrotron radiation becomes as important as the build-up due to the secondary emission. The main source of seed electrons in heavy ion machines is the residual gas ionization. FAIR facility in Darmstadt will operate with heavy-ion and proton beams. However, the beam parameters are such that the multipacting will start to play a role only for the unconditioned wall with the secondary emission yieldmore than 1.8. In this paperwe study the electron cloud build-up and its effect on the beam stability for FAIR heavy-ion coasting beams. These beams will be used during slow extraction. Electron scattering on the beam ions and its effect on the final neutraliz...

  20. Heavy metal characterization of circulating fluidized bed derived biomass ash.

    Science.gov (United States)

    Li, Lianming; Yu, Chunjiang; Bai, Jisong; Wang, Qinhui; Luo, Zhongyang

    2012-09-30

    Although the direct combustion of biomass for energy that applies circulating fluidized bed (CFB) technology is steadily expanding worldwide, only few studies have conducted an environmental assessment of biomass ash thus far. Therefore, this study aims to integrate information on the environmental effects of biomass ash. We investigated the concentration of heavy metal in biomass ash samples (bottom ash, cyclone ash, and filter ash) derived from a CFB boiler that combusted agricultural and forest residues at a biomass power plant (2×12 MW) in China. Ash samples were gathered for the digestion and leaching test. The heavy metal content in the solution and the leachate was studied via an inductively coupled plasma-mass spectrometer and a Malvern Mastersizer 2000 mercury analyzer. Measurements for the chemical composition, particle size distribution, and the surface morphology were carried out. Most of the metals in cyclone ash particles were enriched, whereas Ti and Hg were enriched in filter ash. Residence time contributed most to heavy metal enrichment. Under HJ/T 300 conditions, the heavy metals showed serious leaching characteristics. Under EN 12457-2 conditions, leaching behavior was hardly detected. Copyright © 2012 Elsevier B.V. All rights reserved.

  1. Test of electrodialytic upgrading of MSWI APC residue in pilot scale: focus on reduced metal and salt leaching

    DEFF Research Database (Denmark)

    Kirkelund, Gunvor Marie; Jensen, Pernille Erland; Villumsen, Arne

    2010-01-01

    In this study a pilot plant for electrodialytic treatment of municipal solid waste incineration (MSWI) air pollution control (APC) residue was tested and proposed as a treatment method which can lead to reuse of this otherwise hazardous waste. The pilot plant was developed based on a design...... that is adapted from conventional electrodialysis, e.g. used in desalination of solutions. The APC residue was treated in a suspension (8 kg APC residue and 80 L tap water) and circulated through an electrodialytic (ED) stack consisting of 50 cell pairs separated by ion exchange membranes. A direct current...... was applied to the ED stack for removal of heavy metals (As, Ba, Cd, Cr, Cu, Mn, Ni, Pb, Zn) and salts (Cl, Na, SO4) from the APC residue suspension. Different tank designs for mixing the APC residue suspension were tested as well as changing experimental conditions. A part of the raw experimental APC residue...

  2. Microwave-assisted digestion using nitric acid for heavy metals and sulfated ash testing in active pharmaceutical ingredients.

    Science.gov (United States)

    Pluhácek, T; Hanzal, J; Hendrych, J; Milde, D

    2016-04-01

    The monitoring of inorganic impurities in active pharmaceutical ingredients plays a crucial role in the quality control of the pharmaceutical production. The heavy metals and residue on ignition/sulfated ash methods employing microwave-assisted digestion with concentrated nitric acid have been demonstrated as alternatives to inappropriate compendial methods recommended in United States Pharmacopoeia (USP) and European Pharmacopoeia (Ph. Eur.). The recoveries using the heavy metals method ranged between 89% and 122% for nearly all USP and Ph. Eur. restricted elements as well as the recoveries of sodium sulfate spikes were around 100% in all tested matrices. The proposed microwave-assisted digestion method allowed simultaneous decomposition of 15 different active pharmaceutical ingredients with sample weigh up to 1 g. The heavy metals and sulfated ash procedures were successfully applied to the determination of heavy metals and residue on ignition/sulfated ash content in mycophenolate mofetil, nicergoline and silymarin.

  3. Heavy fields and gravity

    Energy Technology Data Exchange (ETDEWEB)

    Goon, Garrett [Institute of Physics, Universiteit van Amsterdam,Science Park 904, Amsterdam, 1090 GL (Netherlands)

    2017-01-11

    We study the effects of heavy fields on 4D spacetimes with flat, de Sitter and anti-de Sitter asymptotics. At low energies, matter generates specific, calculable higher derivative corrections to the GR action which perturbatively alter the Schwarzschild-(A)dS family of solutions. The effects of massive scalars, Dirac spinors and gauge fields are each considered. The six-derivative operators they produce, such as ∼R{sup 3} terms, generate the leading corrections. The induced changes to horizon radii, Hawking temperatures and entropies are found. Modifications to the energy of large AdS black holes are derived by imposing the first law. An explicit demonstration of the replica trick is provided, as it is used to derive black hole and cosmological horizon entropies. Considering entropy bounds, it’s found that scalars and fermions increase the entropy one can store inside a region bounded by a sphere of fixed size, but vectors lead to a decrease, oddly. We also demonstrate, however, that many of the corrections fall below the resolving power of the effective field theory and are therefore untrustworthy. Defining properties of black holes, such as the horizon area and Hawking temperature, prove to be remarkably robust against higher derivative gravitational corrections.

  4. Heavy ion elastic scatterings

    International Nuclear Information System (INIS)

    Mermaz, M.C.

    1984-01-01

    Diffraction and refraction play an important role in particle elastic scattering. The optical model treats correctly and simultaneously both phenomena but without disentangling them. Semi-classical discussions in terms of trajectories emphasize the refractive aspect due to the real part of the optical potential. The separation due to to R.C. Fuller of the quantal cross section into two components coming from opposite side of the target nucleus allows to understand better the refractive phenomenon and the origin of the observed oscillations in the elastic scattering angular distributions. We shall see that the real part of the potential is responsible of a Coulomb and a nuclear rainbow which allows to determine better the nuclear potential in the interior region near the nuclear surface since the volume absorption eliminates any effect of the real part of the potential for the internal partial scattering waves. Resonance phenomena seen in heavy ion scattering will be discussed in terms of optical model potential and Regge pole analysis. Compound nucleus resonances or quasi-molecular states can be indeed the more correct and fundamental alternative

  5. Heavy-element nucleosynthesis

    International Nuclear Information System (INIS)

    Mathews, G.J.

    1990-01-01

    New measurements and theoretical studies of nuclear properties, together with new astronomical data on the growth of heavy-element abundances during the early history of the Galaxy, now provide a clearer picture of where in nature the elements heavier than iron are produced by rapid (r-process) and show (s-process) neutron capture reactions. The nuclear data suggest that the r-process involves a high-neutron-density beta-flow equilibrium environment and that the s-process may have occurred at a temperature and neutron density consistent with a 13 C(α,n) 16 0 neutron source. The astronomical data, when compared with simple galactic chemical evolution modes, suggests that the r-process is associated with type II supernovae and that the neutron source must be manufactured by the star. Low-mass type II supernovae are proposed as the most important contributors to the r-process. A 13 C neutron source in intermediate-mass stars is proposed for the s-process. 64 refs., 7 figs

  6. Heavy-element nucleosynthesis

    Energy Technology Data Exchange (ETDEWEB)

    Mathews, G.J.

    1990-10-30

    New measurements and theoretical studies of nuclear properties, together with new astronomical data on the growth of heavy-element abundances during the early history of the Galaxy, now provide a clearer picture of where in nature the elements heavier than iron are produced by rapid (r-process) and show (s-process) neutron capture reactions. The nuclear data suggest that the r-process involves a high-neutron-density beta-flow equilibrium environment and that the s-process may have occurred at a temperature and neutron density consistent with a {sup 13}C({alpha},n){sup 16}0 neutron source. The astronomical data, when compared with simple galactic chemical evolution modes, suggests that the r-process is associated with type II supernovae and that the neutron source must be manufactured by the star. Low-mass type II supernovae are proposed as the most important contributors to the r-process. A {sup 13}C neutron source in intermediate-mass stars is proposed for the s-process. 64 refs., 7 figs.

  7. Relativistic heavy ion research

    International Nuclear Information System (INIS)

    1992-01-01

    Experimental work is reported on the following topics: transverse energy production in 10.7-GeV/c/u Au on Au collisions; first results on delta ray production and charged particle multiplicities with the Au beam at 10.7 GeV/c/A; preliminary studies on the feasibility of flow measurement with the E814 participant calorimeter; preliminary results from the E877 telescope; and low-p t baryon distribution in Si+Al, Pb collisions at the AGS. Then the status of the Hadronic Calorimeter project of AGS Experiment E864 (ECOS--Exotic Composite Object Spectrometer) is reviewed. Next, the same is done for work of the STAR RHIC collaboration (Silicon Vertex Tracker (SVT) project evolution and development in FY92, SVT software results from 1992, SVT instrumentation, FY93 SVT pion test beam). The instrumentation section deals with the design and installation of a target rapidity telescope for BNL experiment 814/877 and a repair scheme for the E814/E877 participant calorimeter. Finally, the theory part addresses bosonic kinetics: thermalization of mesons and the pion p perpendicular spectrum in ultrarelativistic heavy-ion collisions and non-equilibrium properties of hadronic mixtures

  8. Glenn T. Seaborg and heavy ion nuclear science

    International Nuclear Information System (INIS)

    Loveland, W.

    1992-04-01

    Radiochemistry has played a limited but important role in the study of nucleus-nucleus collisions. Many of the important radiochemical studies have taken place in Seaborg's laboratory or in the laboratories of others who have spent time in Berkeley working with Glenn T. Seaborg. I will discuss studies of low energy deep inelastic reactions with special emphasis on charge equilibration, studies of the properties of heavy residues in intermediate energy nuclear collisions and studies of target fragmentation in relativistic and ultrarelativistic reactions. The emphasis will be on the unique information afforded by radiochemistry and the physical insight derived from radiochemical studies. Future roles of radiochemistry in heavy ion nuclear science also will be discussed

  9. Glenn T. Seaborg and heavy ion nuclear science

    Energy Technology Data Exchange (ETDEWEB)

    Loveland, W. (Oregon State Univ., Corvallis, OR (United States). Dept. of Chemistry Lawrence Berkeley Lab., CA (United States))

    1992-04-01

    Radiochemistry has played a limited but important role in the study of nucleus-nucleus collisions. Many of the important radiochemical studies have taken place in Seaborg's laboratory or in the laboratories of others who have spent time in Berkeley working with Glenn T. Seaborg. I will discuss studies of low energy deep inelastic reactions with special emphasis on charge equilibration, studies of the properties of heavy residues in intermediate energy nuclear collisions and studies of target fragmentation in relativistic and ultrarelativistic reactions. The emphasis will be on the unique information afforded by radiochemistry and the physical insight derived from radiochemical studies. Future roles of radiochemistry in heavy ion nuclear science also will be discussed.

  10. Glenn T. Seaborg and heavy ion nuclear science

    Energy Technology Data Exchange (ETDEWEB)

    Loveland, W. [Oregon State Univ., Corvallis, OR (United States). Dept. of Chemistry]|[Lawrence Berkeley Lab., CA (United States)

    1992-04-01

    Radiochemistry has played a limited but important role in the study of nucleus-nucleus collisions. Many of the important radiochemical studies have taken place in Seaborg`s laboratory or in the laboratories of others who have spent time in Berkeley working with Glenn T. Seaborg. I will discuss studies of low energy deep inelastic reactions with special emphasis on charge equilibration, studies of the properties of heavy residues in intermediate energy nuclear collisions and studies of target fragmentation in relativistic and ultrarelativistic reactions. The emphasis will be on the unique information afforded by radiochemistry and the physical insight derived from radiochemical studies. Future roles of radiochemistry in heavy ion nuclear science also will be discussed.

  11. Heavy Flavor Production in Heavy Ion Collisions at CMS

    CERN Document Server

    Sun, Jian

    2016-01-01

    Studies of Heavy flavor production are of great interest in heavy ion collisions. In the produced medium, the binding potential between a quark and antiquark in quarkonium is screened by surrounding light quarks and antiquarks. Thus, the various quarkonium states are expected to be melt at different temperatures depending on their binding energies, which allows us to characterize the QCD phase transition. In addition, open heavy flavor production are relevant for flavor-dependence of the in-medium parton energy loss. In QCD, gluons are expected to lose more energy compared to quarks when passing through the QGP due to the larger color charge. Compared to light quarks, heavy quarks are expected to lose less radiative energy because gluon radiation is suppressed at angles smaller than the ratio of the quark mass to its energy. This dead cone effect (and its disappearance at high transverse momentum) can be studied using open heavy flavor mesons and heavy flavor tagged jets. With CMS detector, quarkonia, open he...

  12. Removal of gadolinium nitrate from heavy water

    Energy Technology Data Exchange (ETDEWEB)

    Wilde, E.W.

    2000-03-22

    Work was conducted to develop a cost-effective process to purify 181 55-gallon drums containing spent heavy water moderator (D2O) contaminated with high concentrations of gadolinium nitrate, a chemical used as a neutron poison during former nuclear reactor operations at the Savannah River Site (SRS). These drums also contain low level radioactive contamination, including tritium, which complicates treatment options. Presently, the drums of degraded moderator are being stored on site. It was suggested that a process utilizing biological mechanisms could potentially lower the total cost of heavy water purification by allowing the use of smaller equipment with less product loss and a reduction in the quantity of secondary waste materials produced by the current baseline process (ion exchange).

  13. Residual Stresses and Other Properties of Teardrops

    Energy Technology Data Exchange (ETDEWEB)

    Stroud, Mary Ann [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Veirs, Douglas Kirk [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Berg, John M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Hill, Mary Ann [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Rios, Daniel [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Duque, Juan [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-07-26

    The Department of Energy’s 3013 Standard for packaging plutonium-bearing materials for storage up to fifty years specifies a minimum of two individually welded, nested containers herein referred to as the 3013 outer and the 3013 inner.1 Stress corrosion cracking (SCC) is a potential failure mechanism for 3013 inner containers.2,3 The bagless transfer container (BTC), a 3013 inner container used by Hanford and Savanna River Site (SRS) made from 304L stainless steel (SS), poses the greatest concern for SCC.4,5 The Surveillance and Monitoring Program (SMP) use stressed metal samples known as teardrops as screening tools in SCC studies to evaluate factors that could result in cracks in the 3013 containers.6,7 This report provides background information on the teardrops used in the Los Alamos National Laboratory (LANL) SMP studies including method of construction, composition and variability. In addition, the report discusses measurements of residual stresses in teardrops and compares the results with residual stresses in BTCs reported previously.4 Factors affecting residual stresses, including teardrop dimensions and surface finish, are also discussed.

  14. Evaluation of residue-residue contact prediction in CASP10

    KAUST Repository

    Monastyrskyy, Bohdan

    2013-08-31

    We present the results of the assessment of the intramolecular residue-residue contact predictions from 26 prediction groups participating in the 10th round of the CASP experiment. The most recently developed direct coupling analysis methods did not take part in the experiment likely because they require a very deep sequence alignment not available for any of the 114 CASP10 targets. The performance of contact prediction methods was evaluated with the measures used in previous CASPs (i.e., prediction accuracy and the difference between the distribution of the predicted contacts and that of all pairs of residues in the target protein), as well as new measures, such as the Matthews correlation coefficient, the area under the precision-recall curve and the ranks of the first correctly and incorrectly predicted contact. We also evaluated the ability to detect interdomain contacts and tested whether the difficulty of predicting contacts depends upon the protein length and the depth of the family sequence alignment. The analyses were carried out on the target domains for which structural homologs did not exist or were difficult to identify. The evaluation was performed for all types of contacts (short, medium, and long-range), with emphasis placed on long-range contacts, i.e. those involving residues separated by at least 24 residues along the sequence. The assessment suggests that the best CASP10 contact prediction methods perform at approximately the same level, and comparably to those participating in CASP9.

  15. Manual of Standard Operating Procedures for Veterinary Drug Residue Analysis

    International Nuclear Information System (INIS)

    2016-01-01

    Laboratories are crucial to national veterinary drug residue monitoring programmes. However, one of the main challenges laboratories encounter is obtaining access to relevant methods of analysis. Thus, in addition to training, providing technical advice and transferring technology, the Joint FAO/IAEA Division of Nuclear Techniques in Food and Agriculture has resolved to develop clear and practical manuals to support Member State laboratories. The Coordinated Research Project (CRP) on Development of Radiometric and Allied Analytical Methods to Strengthen Residue Control Programs for Antibiotic and Anthelmintic Veterinary Drug Residues has developed a number of analytical methods as standard operating procedures (SOPs), which are now compiled here. This publication contains SOPs on chromatographic and spectrometric techniques, as well as radioimmunoassay and associated screening techniques, for various anthelmintic and antimicrobial veterinary drug residue analysis. Some analytical method validation protocols are also included. The publication is primarily aimed at food and environmental safety laboratories involved in testing veterinary drug residues, including under organized national residue monitoring programmes. It is expected to enhance laboratory capacity building and competence through the use of radiometric and complementary tools and techniques. The publication is also relevant for applied research on residues of veterinary drugs in food and environmental samples

  16. Lifecycle-analysis for heavy vehicles

    International Nuclear Information System (INIS)

    Gaines, L.

    1998-01-01

    Various alternative fuels and improved engine and vehicle systems have been proposed in order to reduce emissions and energy use associated with heavy vehicles (predominantly trucks). For example, oil companies have proposed improved methods for converting natural gas to zero-aromatics, zero-sulfur diesel fuel via the Fischer-Tropsch process. Major heavy-duty diesel engine companies are working on ways to simultaneously reduce particulate-matter and NOX emissions. The trend in heavy vehicles is toward use of lightweight materials, tires with lower rolling resistance, and treatments to reduce aerodynamic drag. In this paper, we compare the Mecycle energy use and emissions from trucks using selected alternatives, such as Fisher-Tropsch diesel fuel and advanced fuel-efficient engines. We consider heavy-duty, Class 8 tractor-semitrailer combinations for this analysis. The total life cycle includes production and recycling of the vehicle itself, extraction, processing, and transportation of the fuel itself, and vehicle operation and maintenance. Energy use is considered in toto, as well as those portions that are imported, domestic, and renewable. Emissions of interest include greenhouse gases and criteria pollutants. Angonne's Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model is used to generate per-vehicle fuel cycle impacts. Energy use and emissions for materials manufacturing and vehicle disposal are estimated by means of materials information from Argonne studies. We conclude that there are trade-offs among impacts. For example, the lowest fossil energy use does not necessarily result in lowest total energy use, and lower tailpipe emissions may not necessarily result in lower lifecycle emissions of all criteria pollutants

  17. Searches for leptoquarks and heavy leptons with the ATLAS detector at the LHC

    CERN Document Server

    Grancagnolo, Sergio; The ATLAS collaboration

    2015-01-01

    Leptoquarks are hypothetical particles predicted by extensions of the Standard Model, providing an explanation for the similarity between the quark and lepton sectors. Pair-produced scalar leptoquarks have been searched for using final states including leptons and jets. Similar final states are predicted in decays of heavy leptons/neutrinos including Type III neutral/charged leptons as well as heavy Majorana neutrinos produced in decays of heavy right-handed W or SM W boson. In this talk, recent ATLAS results on searches for Leptoquarks and heavy leptons with similar signatures using LHC Run 1 data are presented. First LHC Run-2 results will be included if available.

  18. Heavy ion event generator HYDJET++ (HYDrodynamics plus JETs)

    Science.gov (United States)

    Lokhtin, I. P.; Malinina, L. V.; Petrushanko, S. V.; Snigirev, A. M.; Arsene, I.; Tywoniuk, K.

    2009-05-01

    process in NN collisions with the minimum transverse momentum transfer pTmin. In order to take into account the effect of nuclear shadowing on parton distribution functions, the impact parameter dependent parameterization obtained in the framework of Glauber-Gribov theory [16] is used. The soft part of HYDJET++ event is the "thermal" hadronic state generated on the chemical and thermal freeze-out hypersurfaces obtained from the parameterization of relativistic hydrodynamics with preset freeze-out conditions (the adapted C++ code FAST MC [17,18]). Hadron multiplicities are calculated using the effective thermal volume approximation and Poisson multiplicity distribution around its mean value, which is supposed to be proportional to the number of participating nucleons at a given impact parameter of AA collision. The fast soft hadron simulation procedure includes generation of the 4-momentum of a hadron in the rest frame of a liquid element in accordance with the equilibrium distribution function; generation of the spatial position of a liquid element and its local 4-velocity in accordance with phase space and the character of motion of the fluid; the standard von Neumann rejection/acceptance procedure to account for the difference between the true and generated probabilities; boost of the hadron 4-momentum in the center mass frame of the event; the two- and three-body decays of resonances with branching ratios taken from the SHARE particle decay table [19]. The high generation speed in HYDJET++ is achieved due to almost 100% generation efficiency of the "soft" part because of the nearly uniform residual invariant weights which appear in the freeze-out momentum and coordinate simulation. Although HYDJET++ is optimized for very high energies of RHIC and LHC colliders (c.m.s. energies of heavy ion beams √{s}=200 and 5500 GeV per nucleon pair, respectively), in practice it can also be used for studying the particle production in a wider energy range down to √{s}˜10 GeV per

  19. Heavy quark spectroscopy and decay

    Energy Technology Data Exchange (ETDEWEB)

    Schindler, R.H.

    1987-01-01

    The understanding of q anti q systems containing heavy, charmed, and bottom quarks has progressed rapidly in recent years, through steady improvements in experimental techniques for production and detection of their decays. These lectures are meant to be an experimentalist's review of the subject. In the first of two lectures, the existing data on the spectroscopy of the bound c anti c and b anti b systems will be discussed. Emphasis is placed on comparisons with the theoretical models. The second lecture covers the rapidly changing subject of the decays of heavy mesons (c anti q and b anti q), and their excited states. In combination, the spectroscopy and decays of heavy quarks are shown to provide interesting insights into both the strong and electroweak interactions of the heavy quarks. 103 refs., 39 figs.

  20. The Canadian heavy water situation

    International Nuclear Information System (INIS)

    Dahlinger, A.

    The Canadian heavy water industry is analyzed. Supply and demand are predicted through 1985. Pricing is broken down into components. Backup R and D contributes greatly to process improvements. (E.C.B.)

  1. Pollution control and metal resource recovery for low grade automobile shredder residue: a mechanism, bioavailability and risk assessment.

    Science.gov (United States)

    Singh, Jiwan; Lee, Byeong-Kyu

    2015-04-01

    Automobile shredder residue (ASR) is considered as hazardous waste in Japan and European countries due to presence of heavy metals. This study was carried on the extraction characteristics of heavy metals (Mn, Fe, Ni, and Cr) from automobile shredder residue (ASR). The effects of pH, temperature, particle size, and liquid/solid ratio (L/S) on the extraction of heavy metals were investigated. The recovery rate of Mn, Fe, Ni, and Cr increased with increasing extraction temperature and L/S ratio. The lowest pH 2, the highest L/S ratio, and the smallest particle size showed the highest recovery of heavy metals from ASR. The highest recovery rates were in the following order: Mn > Ni > Cr > Fe. Reduction of mobility factor for the heavy metals was observed in all the size fractions after the recovery. The results of the kinetic analysis for various experimental conditions supported that the reaction rate of the recovery process followed a second order reaction model (R(2) ⩾ 0.95). The high availability of water-soluble fractions of Mn, Fe, Ni, and Cr from the low grade ASR could be potential hazards to the environment. Bioavailability and toxicity risk of heavy metals reduced significantly with pH 2 of distilled water. However, water is a cost-effective extracting agent for the recovery of heavy metals and it could be useful for reducing the toxicity of ASR. Copyright © 2015 Elsevier Ltd. All rights reserved.

  2. Heavy metals in Antarctic organisms

    Energy Technology Data Exchange (ETDEWEB)

    Moreno, J.E.A. de; Moreno, V.J. [Universidad Nacional de Mar del Plata (Argentina); Gerpe, M.S.; Vodopivez, C. [Instituto Antartico Argentino, Buenos Aires (Argentina)

    1997-02-01

    To evaluate levels of essential (zinc and copper) and non-essential (mercury and cadmium) heavy metals, 34 species of organisms from different areas close to the Antarctic Peninsula were analysed. These included algae, filter-feeders, omnivorous invertebrates and vertebrates. Mercury was not detected, while cadmium was found in the majority of organisms analysed (detection limit was 0.05 ppm for both metals). The highest cadmium concentration was observed in the starfish Odontaster validus. Anthozoans, sipunculids and nudibranchs showed maximum levels of zinc, while the highest copper level was found in the gastropod Trophon brevispira. Mercury and cadmium levels in fishes were below the detection limit. Concentrations of essential and non-essential metals in birds were highest in liver followed by muscle and eggs. Cadmium and mercury levels in muscle of southern elephant seals were above the detection limit, whereas in Antarctic fur seals they were below it. The objective of the study was to gather baseline information for metals in Antarctic Ocean biota that may be needed to detect, measure and monitor future environmental changes. 46 refs., 7 figs., 8 tabs.

  3. Various light particles emissions accompaning light heavy ion collisions

    International Nuclear Information System (INIS)

    Billerey, R.

    1981-01-01

    In this work we have investigated light particles emission accompanying heavy-ion induced reactions. The experiments were performed at the isochronous cyclotron of the I.S.N. de Grenoble and we got in and out of plane correlations between solid state and gazeous detectors. In 14 N (100 MeV) + 27 Al we have chosen, light particles emitted in coincidence with deep inelastic fragments or evaporation residues have been measured. Likewise we observed the correlations between fragments and fragments. The particularities we found between protons and alpha emissions are to be assigned to differences in separation energies, but their relative energies and angular momenta have also a significant part [fr

  4. Building on comparative experience : the Venezuelan extra-heavy crude oil projects

    International Nuclear Information System (INIS)

    Valentine, T.E.

    2004-01-01

    This paper reviewed legal considerations regarding heavy and extra heavy oil production in both Canada and Venezuela. The paper focused on Venezuela's extra heavy oil projects in the Orinoco Oil Belt, one of the world's largest accumulation of bitumen with an estimated reserve of 1.2 trillion barrels. The paper described the following four projects: the Petrozuata, Cerro Negro, SINCOR, and Hamaca heavy oil projects which are all congressionally approved joint ventures for extra-heavy crudes in the Orinoco Belt. It also described the legal regime which governs heavy oil projects in Venezuela, including the Organic Gaseous Hydrocarbon Law and the Organic Hydrocarbon Law. Twenty congressional conditions which have been imposed were also outlined along with the legal considerations and lessons learned regarding new extra-heavy crude projects under the two legal regimes. 1 fig

  5. Economic potential of the heavy minerals of the beaches between Baruva and Bavanapadu, Andhra Pradesh

    International Nuclear Information System (INIS)

    Rajasekhara Reddy, D.; Prasad, V.S.S.; Malathi, V.; Reddy, K.S.N.; Varma, D.D.

    2001-01-01

    The economic potentiality of the heavy minerals in the beaches between Baruva and Bavanapadu extending for about 45 km was examined. In the sub-surface sediments, the heavy minerals were studied at an interval of 1 m up to a maximum depth of 5.8m. In general the concentration of heavy minerals is high in dunes followed by backshore and foreshore regions. Heavy mineral content increases from surface to sub-surface in dunes, decreases in foreshore and does not vary much in backshore. The heavy minerals include mainly ilmenite, garnet, sillimanite and ortho-pyroxenes with minor amounts of amphiboles, zircon, monazite, rutile etc. Majority of the heavies such as ilmenite, monazite, zircon etc. are concentrated in finer fractions while some of the heavies like garnet and sillimanite are concentrated in coarser fractions. The inferred reserves estimated for the area indicate its economical potential. (author)

  6. Are pesticide residues in honey related to oilseed rape treatments?

    Science.gov (United States)

    Karise, Reet; Raimets, Risto; Bartkevics, Vadims; Pugajeva, Iveta; Pihlik, Priit; Keres, Indrek; Williams, Ingrid H; Viinalass, Haldja; Mänd, Marika

    2017-12-01

    Pesticide treatments before and during the flowering of honey bee forage crops may lead to residues in honey. In northern regions oilseed rape belongs to the main forage crops that is mostly cultivated by means of intensive agriculture, including several pesticide treatments. However, in addition to the focal forage crops, pesticides from non-forage crops can spread to wild flowers around fields, and thus the residues in honey would reflect the whole range of pesticides used in the agricultural landscape. The aim of our study was to clarify which currently used pesticides are present in honey gathered from heterogeneous agricultural landscapes after the end of flowering of oilseed crops. Honey samples (N = 33) were collected from beehives of Estonia during 2013 and 2014, and analysed for residues of 47 currently used agricultural pesticides using the multiresidue method with HPLC-MS/MS and GC-MS and a single residue method for glyphosate, aminopyralid and clopyralid. Residues of eight different active ingredients with representatives from all three basic pesticide classes were determined. Although no correlation was detected between the cumulative amount of pesticide residues and percent of oilseed crops in the foraging territory, most of the residues are those allowed for oilseed rape treatments. Among all pesticides, herbicide residues prevailed in 2013 but not in 2014. Despite the relatively small agricultural impact of Estonia, the detected levels of pesticide residues sometimes exceeded maximum residue level; however, these concentrations do not pose a health risk to consumers, also acute toxicity to honey bees would be very unlikely. Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. Status of Heavy Neutrino Experiments

    CERN Document Server

    Wynne, Benjamin; The ATLAS collaboration

    2017-01-01

    The observation of neutrino oscillations raises the possibility that there exist additional, undiscovered high-mass neutrinos, giving mass to Standard Model neutrinos via the seesaw mechanism. By pushing the collider energy frontier at the LHC, the possibility arises that these heavy neutrinos may be produced and identified. We summarise the latest LHC results of searches for heavy neutrinos in a variety of final states.

  8. Exotic heavy baryons at LHC

    International Nuclear Information System (INIS)

    Biro, T.S.; Zimanyi, J.

    1993-06-01

    A heavy bottom-charm six-quark baryon is considered. A semiclassical and a Gaussian estimate show that the octet-octet bbb-ccc configuration can be favoured energetically rather than the singlet-singlet one. This result suggests that a confined bbb-ccc six-quark state may exist. Such objects may be produced in suitable amounts by heavy-ion collisions at Large Hadronic Collider energies. (R.P.) 8 refs. 1 fig

  9. The Canadian heavy water situation

    International Nuclear Information System (INIS)

    Dahlinger, A.

    1975-08-01

    Existing heavy water plants in Canada are producing at a satisfactory rate and currently planned capacity is in balance with projected needs. By 1980, we shall have Girdler-Sulphide plants installed with a design capacity of almost 600 kg/h. Effort is required to minimize production costs for heavy water and to ensure that costs do not increase faster than the current inflationary trend. (Author)

  10. BNL heavy ion fusion program

    International Nuclear Information System (INIS)

    Maschke, A.W.

    1978-01-01

    A principal attraction of heavy ion fusion is that existing accelerator technology and theory are sufficiently advanced to allow one to commence the design of a machine capable of igniting thermonuclear explosions. There are, however, a number of features which are not found in existing accelerators built for other purposes. The main thrust of the BNL Heavy Ion Fusion program has been to explore these features. Longitudinal beam bunching, very low velocity acceleration, and space charge neutralization are briefly discussed

  11. Aging of iron (hydr)oxides by heat treatment and effects on heavy metal binding

    DEFF Research Database (Denmark)

    Sørensen, Mette Abildgaard; Starckpoole, M. M.; Frenkel, A. I.

    2000-01-01

    Amorphous iron (hydr)oxides are used to remove heavy metals from wastewater and in the treatment of air pollution control residues generated in waste incineration. In this study, iron oxides containing heavy metals (e.g., Pb, Hg, Cr, and Cd) were treated at 50, 600, and 900 °C to simulate...... oxides were transformed to hematite, which had a greater thermodynamic stability but less surface area than the initial products. Heat treatment also caused some volatilization of heavy metals (most notably, Hg). Leaching with water at pH 9 (L/S 10, 24 h) and weak acid extraction showed that heat...... of iron oxides may be advantageous to improve the thermodynamic stability of the product but that thermal treatment at both 600 and 900 °C significantly reduced the binding capacity for heavy metals....

  12. Stopping of relativistic heavy ions in various media

    Science.gov (United States)

    Waddington, C. J.; Fixsen, D. J.; Crawford, H. J.; Lindstrom, P. J.; Heckman, H. H.

    1986-01-01

    The residual ranges of (900 + or - 3)-MeV/amu gold nuclei accelerated at the Lawrence Berkeley Laboratory Bevalac have been measured in several different media. The energy of the beam of nuclei was measured directly using a new time-of-flight system. The ranges were measured by absorption in linear wedges of polyethylene, carbon, aluminum, copper, tin, and lead and in circular wedges of polystyrene, aluminum, and gold, and by total absorption in nuclear emulsion. The measured ranges were significantly different from those calculated from the best available theoretical estimates of the energy loss of highly charged nuclei. It is concluded that at present energy losses and residual ranges of relativistic heavy ions in an arbitrary medium cannot be predicted with better than an approximately 2 percent accuracy.

  13. Heavy metal contamination of soil and water in the vicinity of an abandoned e-waste recycling site: implications for dissemination of heavy metals.

    Science.gov (United States)

    Wu, Qihang; Leung, Jonathan Y S; Geng, Xinhua; Chen, Shejun; Huang, Xuexia; Li, Haiyan; Huang, Zhuying; Zhu, Libin; Chen, Jiahao; Lu, Yayin

    2015-02-15

    Illegal e-waste recycling activity has caused heavy metal pollution in many developing countries, including China. In recent years, the Chinese government has strengthened enforcement to impede such activity; however, the heavy metals remaining in the abandoned e-waste recycling site can still pose ecological risk. The present study aimed to investigate the concentrations of heavy metals in soil and water in the vicinity of an abandoned e-waste recycling site in Longtang, South China. Results showed that the surface soil of the former burning and acid-leaching sites was still heavily contaminated with Cd (>0.39 mg kg(-1)) and Cu (>1981 mg kg(-1)), which exceeded their respective guideline levels. The concentration of heavy metals generally decreased with depth in both burning site and paddy field, which is related to the elevated pH and reduced TOM along the depth gradient. The pond water was seriously acidified and contaminated with heavy metals, while the well water was slightly contaminated since heavy metals were mostly retained in the surface soil. The use of pond water for irrigation resulted in considerable heavy metal contamination in the paddy soil. Compared with previous studies, the reduced heavy metal concentrations in the surface soil imply that heavy metals were transported to the other areas, such as pond. Therefore, immediate remediation of the contaminated soil and water is necessary to prevent dissemination of heavy metals and potential ecological disaster. Copyright © 2014 Elsevier B.V. All rights reserved.

  14. Production and spectroscopy in heavy flavour

    CERN Document Server

    Maevskiy, Artem; The ATLAS collaboration

    2017-01-01

    A wide programme of studies of heavy flavour production at the LHC is performed with the ATLAS detector, which includes charm and beauty hadrons, quarkonia production in both sectors, and associated production J/psi + W, J/psi + Z and J/psi + J/psi. This talk will cover recent results, including the differential production cross-section measurement of di-Jpsi and effective cross-section from double parton scattering. Studies on the production of exotic states are also presented.

  15. Recent heavy flavor measurements from PHENIX at RHIC

    International Nuclear Information System (INIS)

    Haseler, T O S

    2016-01-01

    Heavy flavor quarks are an important probe of the initial state of the Quark Gluon Plasma formed in heavy-ion collisions. Bottom and charm quarks are primarily produced through hard interactions, early in the collision and experience the full time evolution of the medium. Measuring their production in p + p collisions can also give a baseline reference to study larger collision systems, including asymmetric systems and can directly test pQCD calculations. At PHENIX open heavy flavor states can be measured through leptonic decay channels. Some measurements have utilized silicon vertex detectors to determine meson decay lengths in order to separate D mesons from B mesons. Recent measurements have been made at √s NN = 200 and 500 GeV, with a variety of collision species, in both forward/backward and central rapidities.A review of the recent heavy flavor measurements from PHENIX will be presented in this proceeding. (paper)

  16. Residual stresses around Vickers indents

    International Nuclear Information System (INIS)

    Pajares, A.; Guiberteau, F.; Steinbrech, R.W.

    1995-01-01

    The residual stresses generated by Vickers indentation in brittle materials and their changes due to annealing and surface removal were studied in 4 mol% yttria partially stabilized zirconia (4Y-PSZ). Three experimental methods to gain information about the residual stress field were applied: (i) crack profile measurements based on serial sectioning, (ii) controlled crack propagation in post indentation bending tests and (iii) double indentation tests with smaller secondary indents located around a larger primary impression. Three zones of different residual stress behavior are deduced from the experiments. Beneath the impression a crack free spherical zone of high hydrostatic stresses exists. This core zone is followed by a transition regime where indentation cracks develop but still experience hydrostatic stresses. Finally, in an outward third zone, the crack contour is entirely governed by the tensile residual stress intensity (elastically deformed region). Annealing and surface removal reduce this crack driving stress intensity. The specific changes of the residual stresses due to the post indentation treatments are described and discussed in detail for the three zones

  17. Residual complaints after neuralgic amyotrophy.

    Science.gov (United States)

    Cup, Edith H; Ijspeert, Jos; Janssen, Renske J; Bussemaker-Beumer, Chaska; Jacobs, Joost; Pieterse, Allan J; van der Linde, Harmen; van Alfen, Nens

    2013-01-01

    To develop recommendations regarding outcome measures and topics to be addressed in rehabilitation for persons with neuralgic amyotrophy (NA), this study explored which functions and activities are related to persisting pain in NA and which questionnaires best capture these factors. A questionnaire-based survey from 2 cross-sectional cohorts, one of patients visiting the neurology outpatient clinic and a cohort seen at a multidisciplinary plexus clinic. Two tertiary referral clinics based in the Department of Neurology and Rehabilitation from a university medical center provided the data. A referred sample of patients (N=248) with either idiopathic or hereditary NA who fulfilled the criteria for this disorder, in whom the last episode of NA had been at least 6 months ago and included brachial plexus involvement. Not applicable. Two custom clinical screening questionnaires were used as well as the Shoulder Rating Questionnaire-Dutch Language Version, the Shoulder Pain and Disability Index (SPADI), the Shoulder Disability Questionnaire (SDQ), and Overall Disability Sum Score. The survey confirms the high prevalence of persisting pain and impairments. More than half of the patients were restricted by pain, while in those without pain 60% experienced residual paresis. Correlations show an intimate relation between pain, scapular instability, problems with overhead activities, and increased fatigability. A standard physical therapy approach was ineffective or aggravated symptoms in more than 50%. Pain and fatigue are strongly correlated to persisting scapular instability and increased fatigability of the affected muscles in NA. Our results suggest that an integrated rehabilitation approach is needed in which all of these factors are addressed. We further recommend using the SPADI and SDQ in future studies to evaluate the natural course and treatment effects in NA. Copyright © 2013 American Congress of Rehabilitation Medicine. Published by Elsevier Inc. All rights

  18. Structural and functional effects of heavy metals on the nervous system, including sense organs, of fish

    DEFF Research Database (Denmark)

    Baatrup, E

    1991-01-01

    1. Today, fish in the environment are inevitably exposed to chemical pollution. Although most hazardous substances are present at concentrations far below the lethal level, they may still cause serious damage to the life processes of these animals. 2. Fish depend on an intact nervous system, incl...

  19. Heavy oil : PetroChina's perspective

    Energy Technology Data Exchange (ETDEWEB)

    He, C. [PetroChina Co., Ltd., Beijing (China)

    2010-07-01

    This keynote presentation discussed China's future in relation to heavy oil refining. An overview of PetroChina's overseas operations was also presented. China currently has six 200,000 bpd refineries as well as an additional 12 refineries with a 100,000 bpd capacity that are able to process lower quality feedstocks with a high acid and sulphur content. Seven new 200,000 bpd refineries will be built by 2020. Poor and heavy crude oil from global heavy oil reserves will form a significant percentages of China's refinery feedstocks, and Canada is expected to provide a significant portion of its heavy oil and bitumen resources for further refining in China. China's existing refineries are being reconfigured and optimized for the processing of heavy crude oils. Additional hydrotreating and hydrocracking technologies have been added, and resid fluid catalytic cracking technologies have been retrofitted. China envisages a future with steady increases in oil consumption, high oil prices, and an increased reliance on heavy and poor quality crude oils. China's strong economic growth will increase demand for petrochemical feedstocks. Various research organizations and institutions have been established to accelerate innovation and technology development for ensuring that clean fuels standards are met. New refineries in China will include resid upgrading and new generation catalyst technologies. Details of various technologies were included. tabs., figs.

  20. [Speciation and Risk Assessment of Heavy Metals in Surface Sediments from the Heavily Polluted Area of Xiaoqing River].

    Science.gov (United States)

    Huang, Ying; Li, Yong-xia; Gao, Fu-wei; Xu, Min-min; Sun, Bo; Wang, Ning; Yang, Jian

    2015-06-01

    Th concentrations of Cu, As, Pb, Zn, Cr, Cd, Ni in interstitial water were analyzed by ICP-MS from the heavily polluted area of Xiaoqing River. A modified BCR's sequential extraction procedure was used to investigate the fraction of the heavy metals in the surface sediments. The aquatic toxicity of heavy metals in interstitial water was assessed by US Water Quality Criteria (CCC, CMC). Based on the speciation of the metals in the surface sediments, the ecological risk of heavy metals was assessed with methods of risk assessment code (RAC) and potential ecological risk index. The results showed that: The tested heavy metals would not pose chronic toxicity for aquatic ecosystem. The contents of heavy metals (Cu, Pb, Zn, Cr, Cd, Ni) in the surface sediments were higher than the background values of the local soils, indicating enrichment of heavy metals. Cu, As and Ni were mainly composed with residual fractions, Pb and Cr were mainly constituted of residual and oxidizable fractions, and mass fractions of Zn and Cd existed mainly in acid soluble and reducible factions. The contents of bio-available fractions of Cd, Zn, Cr and Pb in the sediments were higher those of residual fractions, indicating high potential for secondary release. Based on calculation of RAC method, Cu, Pb, Cr and As posed extremely low to low risk to the environment. Accordingly, Ni was of low to medium risk, Cd was of medium to high risk, and Zn was of medium to extremely high risk to the environment. The potential ecological risk of heavy metals in the sediments was in the descending order of Cd > Zn > Ni > As > Cu > Cr > Pb. Cd had high to very high potential ecological risk comparing with the other heavy metals. The potential ecological risk indexes (RI) of the heavy metals in the sediments were in the range of 136.83-264.83, and posed medium to high potential ecological risks for Xiaoqing River.

  1. Heavy metals in drinking water: Occurrences, implications, and future needs in developing countries

    Energy Technology Data Exchange (ETDEWEB)

    Chowdhury, Shakhawat, E-mail: Schowdhury@kfupm.edu.sa [Department of Civil and Environmental Engineering, King Fahd University of Petroleum and Minerals, Dhahran 31261 (Saudi Arabia); Mazumder, M.A. Jafar [Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261 (Saudi Arabia); Al-Attas, Omar [Department of Civil and Environmental Engineering, King Fahd University of Petroleum and Minerals, Dhahran 31261 (Saudi Arabia); Husain, Tahir [Faculty of Engineering and Applied Science, Memorial University of Newfoundland, St. John’s, NL (Canada)

    2016-11-01

    Heavy metals in drinking water pose a threat to human health. Populations are exposed to heavy metals primarily through water consumption, but few heavy metals can bioaccumulate in the human body (e.g., in lipids and the gastrointestinal system) and may induce cancer and other risks. To date, few thousand publications have reported various aspects of heavy metals in drinking water, including the types and quantities of metals in drinking water, their sources, factors affecting their concentrations at exposure points, human exposure, potential risks, and their removal from drinking water. Many developing countries are faced with the challenge of reducing human exposure to heavy metals, mainly due to their limited economic capacities to use advanced technologies for heavy metal removal. This paper aims to review the state of research on heavy metals in drinking water in developing countries; understand their types and variability, sources, exposure, possible health effects, and removal; and analyze the factors contributing to heavy metals in drinking water. This study identifies the current challenges in developing countries, and future research needs to reduce the levels of heavy metals in drinking water. - Highlights: • Co-exposure to multiple heavy metals in drinking water needs better understanding • Low-cost technologies for arsenic removal needs urgent attention • Protonated alginate needs further research for drinking water applications • Community level and PoU devices need improvement and cost reduction • Developing countries are most affected by heavy metals in drinking water.

  2. Heavy metals in drinking water: Occurrences, implications, and future needs in developing countries

    International Nuclear Information System (INIS)

    Chowdhury, Shakhawat; Mazumder, M.A. Jafar; Al-Attas, Omar; Husain, Tahir

    2016-01-01

    Heavy metals in drinking water pose a threat to human health. Populations are exposed to heavy metals primarily through water consumption, but few heavy metals can bioaccumulate in the human body (e.g., in lipids and the gastrointestinal system) and may induce cancer and other risks. To date, few thousand publications have reported various aspects of heavy metals in drinking water, including the types and quantities of metals in drinking water, their sources, factors affecting their concentrations at exposure points, human exposure, potential risks, and their removal from drinking water. Many developing countries are faced with the challenge of reducing human exposure to heavy metals, mainly due to their limited economic capacities to use advanced technologies for heavy metal removal. This paper aims to review the state of research on heavy metals in drinking water in developing countries; understand their types and variability, sources, exposure, possible health effects, and removal; and analyze the factors contributing to heavy metals in drinking water. This study identifies the current challenges in developing countries, and future research needs to reduce the levels of heavy metals in drinking water. - Highlights: • Co-exposure to multiple heavy metals in drinking water needs better understanding • Low-cost technologies for arsenic removal needs urgent attention • Protonated alginate needs further research for drinking water applications • Community level and PoU devices need improvement and cost reduction • Developing countries are most affected by heavy metals in drinking water

  3. Actinide recovery from pyrochemical residues

    International Nuclear Information System (INIS)

    Avens, L.R.; Clifton, D.G.; Vigil, A.R.

    1984-01-01

    A new process for recovery of plutonium and americium from pyrochemical waste has been demonstrated. It is based on chloride solution anion exchange at low acidity, which eliminates corrosive HCl fumes. Developmental experiments of the process flowsheet concentrated on molten salt extraction (MSE) residues and gave >95% plutonium and >90% americium recovery. The recovered plutonium contained 6 = from high chloride-low acid solution. Americium and other metals are washed from the ion exchange column with 1N HNO 3 -4.8M NaCl. The plutonium is recovered, after elution, via hydroxide precipitation, while the americium is recovered via NaHCO 3 precipitation. All filtrates from the process are discardable as low-level contaminated waste. Production-scale experiments are now in progress for MSE residues. Flow sheets for actinide recovery from electrorefining and direct oxide reduction residues are presented and discussed

  4. Actinide recovery from pyrochemical residues

    International Nuclear Information System (INIS)

    Avens, L.R.; Clifton, D.G.; Vigil, A.R.

    1985-05-01

    We demonstrated a new process for recovering plutonium and americium from pyrochemical waste. The method is based on chloride solution anion exchange at low acidity, or acidity that eliminates corrosive HCl fumes. Developmental experiments of the process flow chart concentrated on molten salt extraction (MSE) residues and gave >95% plutonium and >90% americium recovery. The recovered plutonium contained 6 2- from high-chloride low-acid solution. Americium and other metals are washed from the ion exchange column with lN HNO 3 -4.8M NaCl. After elution, plutonium is recovered by hydroxide precipitation, and americium is recovered by NaHCO 3 precipitation. All filtrates from the process can be discardable as low-level contaminated waste. Production-scale experiments are in progress for MSE residues. Flow charts for actinide recovery from electro-refining and direct oxide reduction residues are presented and discussed

  5. Observations of Heavy Ions in the Magnetosphere

    Science.gov (United States)

    Kistler, L. M.

    2017-12-01

    There are two sources for the hot ions in the magnetosphere: the solar wind and the ionosphere. The solar wind is predominantly protons, with about 4% He++ and less than 1% other high charge state heavy ions. The ionospheric outflow is also predominantly H+, but can contain a significant fraction of heavy ions including O+, N+, He+, O++, and molecular ions (NO+, N2+, O2+). The ionospheric outflow composition varies significantly both with geomagnetic activity and with solar EUV. The variability in the contribution of the two sources, the variability in the ionospheric source itself, and the transport paths of the different species are all important in determining the ion composition at a given location in the magnetosphere. In addition to the source variations, loss processes within the magnetosphere can be mass dependent, changing the composition. In particular, charge exchange is strongly species dependent, and can lead to heavy ion dominance at some energies in the inner magnetosphere. In this talk we will review the current state of our understanding of the composition of the magnetosphere and the processes that determine it.

  6. Heavy quarkonium suppression in a fireball

    Science.gov (United States)

    Brambilla, Nora; Escobedo, Miguel A.; Soto, Joan; Vairo, Antonio

    2018-04-01

    We perform a comprehensive study of the time evolution of heavy-quarkonium states in an expanding hot QCD medium by implementing effective field theory techniques in the framework of open quantum systems. The formalism incorporates quarkonium production and its subsequent evolution in the fireball including quarkonium dissociation and recombination. We consider a fireball with a local temperature that is much smaller than the inverse size of the quarkonium and much larger than its binding energy. The calculation is performed at an accuracy that is leading order in the heavy-quark density expansion and next-to-leading order in the multipole expansion. Within this accuracy, for a smooth variation of the temperature and large times, the evolution equation can be written as a Lindblad equation. We solve the Lindblad equation numerically both for a weakly coupled quark-gluon plasma and a strongly coupled medium. As an application, we compute the nuclear modification factor for the ϒ (1 S ) and ϒ (2 S ) states. We also consider the case of static quarks, which can be solved analytically. Our study fulfills three essential conditions: it conserves the total number of heavy quarks, it accounts for the non-Abelian nature of QCD, and it avoids classical approximations.

  7. Overview of US heavy ion fusion research

    International Nuclear Information System (INIS)

    Logan, G.; Bieniosek, F.; Celata, C.; Henestroza, E.; Kwan, J.; Lee, E.P.; Leitner, M.; Prost, L.; Roy, P.; Seidl, P.A.; Eylon, S.; Vay, J.-L.; Waldron, W.; Yu, S.; Barnard, J.; Callahan, D.; Cohen, R.; Friedman, A.; Grote, D.; Kireeff Covo, M.; Meier, W.R.; Molvik, A.; Lund, S.; Davidson, R.; Efthimion, P.; Gilson, E.; Grisham, L.; Kaganovich, I.; Qin, H.; Startsev, E.; Rose, D.; Welch, D.; Olson, C.; Kishek, R.; O'Shea, P.; Haber, I.

    2005-01-01

    Significant experimental and theoretical progress has been made in the U.S. heavy ion fusion program on high-current sources, injectors, transport, final focusing, chambers and targets for high energy density physics (HEDP) and inertial fusion energy (IFE) driven by induction linac accelerators. One focus of present research is the beam physics associated with quadrupole focusing of intense, space-charge dominated heavy-ion beams, including gas and electron cloud effects at high currents, and the study of long-distance-propagation effects such as emittance growth due to field errors in scaled experiments. A second area of emphasis in present research is the introduction of background plasma to neutralize the space charge of intense heavy ion beams and assist in focusing the beams to a small spot size. In the near future, research will continue in the above areas, and a new area of emphasis will be to explore the physics of neutralized beam compression and focusing to high intensities required to heat targets to high energy density conditions as well as for inertial fusion energy. (author)

  8. Medical treatment for heavy menstrual bleeding

    Directory of Open Access Journals (Sweden)

    Yi-Jen Chen

    2015-10-01

    Full Text Available Heavy menstrual bleeding, or menorrhagia, is subjectively defined as a “complaint of a large amount of bleeding during menstrual cycles that occurs over several consecutive cycles” and is objectively defined as menstrual blood loss of more than 80 mL per cycle that is associated with an anemia status (defined as a hemoglobin level of <10 g/dL. During their reproductive age, more than 30% of women will complain of or experience a heavy amount of bleeding, which leads to a debilitating health outcome, including significantly reduced health-related quality of life, and a considerable economic burden on the health care system. Although surgical treatment might be the most important definite treatment, especially hysterectomy for those women who have finished bearing children, the uterus is still regarded as the regulator and controller of important physiological functions, a sexual organ, a source of energy and vitality, and a maintainer of youth and attractiveness. This has resulted in a modern trend in which women may reconsider the possibility of organ preservation. For women who wish to retain the uterus, medical treatment may be one of the best alternatives. In this review, recent trends in the management of women with heavy menstrual bleeding are discussed.

  9. Postintervention Effects of "Click City®: Alcohol" on Changing Etiological Mechanisms Related to the Onset of Heavy Drinking

    Science.gov (United States)

    Gordon, Judith S.; Andrews, Judy A.; Hampson, Sarah H.; Gunn, Barbara; Christiansen, Steven M.; Jacobs, Thomas

    2017-01-01

    Introduction: Alcohol consumption, including heavy drinking, is the fourth leading preventable cause of death in the United States. Youth who engage in heavy drinking are likely to experience a number of problems associated with their use. In 2015, U.S. prevalence of heavy drinking was 17% among 12th graders. These data suggest a clear need for…

  10. Cost analysis for heavy equipment in earthfill work - An optimization of heavy equipment fleet (Case study: Jabung ring dike project)

    Science.gov (United States)

    Arifin, Muhammad Faizal Ardhiansyah

    2017-03-01

    Earth fill work with large volumes of soil deposits will involve a lot of heavy equipment with a variety of functions and with different objectives. Where each machine will have different productivity anyway. So that in this paper discusses the calculation of the cost required to do the compacted earthfill work for embankment in accordance with the volume of work, the target date for implementation, and the number of heavy equipment needs. As the cost calculations used heavy equipment rental price per hour. In the cost analysis calculations use heavy equipment here there are several factors that we included in the calculation, are: 1.)Hauling distance; 2.)Effective hour a day; 3.)Change factor of Soil Volume; 4.)Effective Speed; 5.)Equipment efficiency factor; 6.)Equipment coefficient; 7.)Cycle Time.

  11. Advanced new technologies for residue upgrading

    International Nuclear Information System (INIS)

    Gillis, D.

    1997-01-01

    Viewgraphs summarizing UOP technologies for residue are provided. The upgrading technologies include: (1) Aquaconversion, (2) the Discriminatory Destructive Distillation process (3D), and (3) the RCD uniflex process. The Aquaconversion process is based on catalytic hydrovisbreaking. It makes use of a homogeneous (liquid phase) catalyst. The hydrogen is derived from water. The advantages of this process are improved residue stability and quality at higher conversion levels, high synthetic crude yields, low operational complexity, reduced transportation costs. The 3D process is a unique carbon rejection contaminant removal process which can process whole crudes through viscous residues. FCC type equipment is used. Performance characteristics and advantages of the process were highlighted. The RCD uniflex process makes use of proven fixed bed and ebullated bed technologies in a new process configuration in which the fixed bed system is located upstream of the ebullated bed system. In this process, the catalyst volume increases exponentially with increasing processing severity. Performance characteristics, design features, benefits and development progress to date are described. 1 tab., 21 figs

  12. Medium energy heavy ion operations at RHIC

    International Nuclear Information System (INIS)

    Drees, K.A.; Ahrens, L.; Bai, M.; Beebe-Wang, J.; Blackler, I.M.C.; Blaskiewicz, M.; Brown, K.A.; Brennan, M.; Bruno, D.; Butler, J.; Carlson, C.; Connolly, R.; D'Ottavio, T.; Fischer, W.; Fu, W.; Gassner, D.; Harvey, M.; Hayes, T.; Huang, H.; Hulsart, R.; Ingrassia, P.; Kling, N.; Lafky, M.; Laster, J.; Lee, R.C.; Litvinenko, V.; Luo, Y.; MacKay, W.W.; Marr, G.; Mapes, M.; Marusic, A.; Mernick, K.; Michnoff, R.; Minty, M.; Montag, C.; Morris, J.; Naylor, C.; Nemesure, S.; Pilat, F.; Ptitsyn, V.; Robert-Demolaize, G.; Roser, T.; Sampson, P.; Satogata, T.; Schoefer, V.; Schultheiss, C.; Severino, F.; Shrey, T.; Smith, K.S.; Tepikian, S.; Thieberger, P.; Trbojevic, D.; Tsoupas, N.; Tuozzolo, J.; van Kuik, B.; Wilinski, M.; Zaltsman, A.; Zeno, K.; Zhang, S.Y.

    2011-01-01

    As part of the search for a phase transition or critical point on the QCD phase diagram, an energy scan including 5 different energy settings was performed during the 2010 RHIC heavy ion run. While the top beam energy for heavy ions is at 100 GeV/n and the lowest achieved energy setpoint was significantly below RHICs injection energy of approximately 10 GeV/n, we also provided beams for data taking in a medium energy range above injection energy and below top beam energy. This paper reviews RHIC experience and challenges for RHIC medium energy operations that produced full experimental data sets at beam energies of 31.2 GeV/n and 19.5 GeV/n. The medium energy AuAu run covered two beam energies, both above the RHIC injection energy of 9.8 GeV but well below the standard store energy of 100 GeV (see table 1). The low energy and full energy runs with heavy ions in FY10 are summarized in (1) and (2). Stochastic Cooling ((3)) was only used for 100 GeV beams and not used in the medium energy run. The efficiency of the transition from 100 GeV operation to 31.2 GeV and then to 19.5 GeV was remarkable. Setup took 32 h and 19 h respectively for the two energy settings. The time in store, defined to be the percentage of time RHIC provides beams in physics conditions versus calendar time, was approximately 52% for the entire FY10 heavy ion run. In both medium energy runs it was well above this average, 68% for 31.5 GeV and 82% for 19.5 GeV. For both energies RHIC was filled with 111 bunches with 1.2 10 9 and 1.3 10 9 ions per bunch respectively.

  13. Medium energy heavy ion operations at RHIC

    Energy Technology Data Exchange (ETDEWEB)

    Drees, K.A.; Ahrens, L.; Bai, M.; Beebe-Wang, J.; Blackler, I.M.C.; Blaskiewicz, M.; Brown, K.A.; Brennan, M.; Bruno, D.; Butler, J.; Carlson, C.; Connolly, R.; D' Ottavio, T.; Fischer, W.; Fu, W.; Gassner, D.; Harvey, M.; Hayes, T.; Huang, H.; Hulsart, R.; Ingrassia, P.; Kling, N.; Lafky, M.; Laster, J.; Lee, R.C.; Litvinenko, V.; Luo, Y.; MacKay, W.W.; Marr, G.; Mapes. M.; Marusic, A.; Mernick, K.; Michnoff, R.; Minty, M.; Montag, C.; Morris, J.; Naylor, C.; Nemesure, S.; Pilat, F.; Ptitsyn, V.; Robert-Demolaize, G.; Roser, T.; Sampson, P.; Satogata, T.; Schoefer, V.; Schultheiss, C.; Severino, F.; Shrey, T.; Smith, K.S.; Tepikian, S.; Thieberger, P.; Trbojevic, D.; Tsoupas, N.; Tuozzolo, J.; van Kuik, B.; Wilinski, M.; Zaltsman, A.; Zeno, K.; Zhang, S.Y.

    2011-03-28

    As part of the search for a phase transition or critical point on the QCD phase diagram, an energy scan including 5 different energy settings was performed during the 2010 RHIC heavy ion run. While the top beam energy for heavy ions is at 100 GeV/n and the lowest achieved energy setpoint was significantly below RHICs injection energy of approximately 10 GeV/n, we also provided beams for data taking in a medium energy range above injection energy and below top beam energy. This paper reviews RHIC experience and challenges for RHIC medium energy operations that produced full experimental data sets at beam energies of 31.2 GeV/n and 19.5 GeV/n. The medium energy AuAu run covered two beam energies, both above the RHIC injection energy of 9.8 GeV but well below the standard store energy of 100 GeV (see table 1). The low energy and full energy runs with heavy ions in FY10 are summarized in [1] and [2]. Stochastic Cooling ([3]) was only used for 100 GeV beams and not used in the medium energy run. The efficiency of the transition from 100 GeV operation to 31.2 GeV and then to 19.5 GeV was remarkable. Setup took 32 h and 19 h respectively for the two energy settings. The time in store, defined to be the percentage of time RHIC provides beams in physics conditions versus calendar time, was approximately 52% for the entire FY10 heavy ion run. In both medium energy runs it was well above this average, 68% for 31.5 GeV and 82% for 19.5 GeV. For both energies RHIC was filled with 111 bunches with 1.2 10{sup 9} and 1.3 10{sup 9} ions per bunch respectively.

  14. Leaching From Biomass Gasification Residues

    DEFF Research Database (Denmark)

    Allegrini, Elisa; Boldrin, Alessio; Polletini, A.

    2011-01-01

    The aim of the present work is to attain an overall characterization of solid residues from biomass gasification. Besides the determination of chemical and physical properties, the work was focused on the study of leaching behaviour. Compliance and pH-dependence leaching tests coupled with geoche......The aim of the present work is to attain an overall characterization of solid residues from biomass gasification. Besides the determination of chemical and physical properties, the work was focused on the study of leaching behaviour. Compliance and pH-dependence leaching tests coupled...

  15. Carbaryl residues in maize products

    International Nuclear Information System (INIS)

    Zayed, S.M.A.D.; Mansour, S.A.; Mostafa, I.Y.; Hassan, A.

    1976-01-01

    The 14 C-labelled insecticide carbaryl was synthesized from [1- 14 C]-1-naphthol at a specific activity of 3.18mCig -1 . Maize plants were treated with the labelled insecticide under simulated conditions of agricultural practice. Mature plants were harvested and studied for distribution of total residues in untreated grains as popularly roasted and consumed, and in the corn oil and corn germ products. Total residues found under these conditions in the respective products were 0.2, 0.1, 0.45 and 0.16ppm. (author)

  16. Combinatorial construction of toric residues

    OpenAIRE

    Khetan, Amit; Soprounov, Ivan

    2004-01-01

    The toric residue is a map depending on n+1 semi-ample divisors on a complete toric variety of dimension n. It appears in a variety of contexts such as sparse polynomial systems, mirror symmetry, and GKZ hypergeometric functions. In this paper we investigate the problem of finding an explicit element whose toric residue is equal to one. Such an element is shown to exist if and only if the associated polytopes are essential. We reduce the problem to finding a collection of partitions of the la...

  17. Decontamination of soils polluted with heavy metals using plants as determined by nuclear technique

    International Nuclear Information System (INIS)

    Lotfy, S.M

    2010-01-01

    The objectives of this work were three folds. First, to study the mobility and fate of heavy metals in two polluted sites (Mostorud soil, irrigated with contaminated water for more than 30 years and El-Gabal EL-Asfar soil, subjected to sewage effluent irrigation for more than 50 years) utilizing a modified tessier's sequential extraction procedure to evaluate the effect of total metal concentrations on metal partitioning into different fractions. Second, to evaluate the efficiency of some plant species (sunflower, cotton, penakium, Napier grass, and Squash) to extract heavy metals out of polluted soils. Third, to enhance the phyto-extraction of heavy metals by sunflower plant using some chemical chelators (citric acids, EDTA, and Ammonium nitrate) in order to improve the remediation of pollutants as well as to protect soil quality.It was observed that the distribution of heavy metals in various chemical fractions depends on the total heavy metals content. The distribution of heavy metals forms in the studied soils was in the following decreasing order: residual > Fe-Mn oxides > carbonates > organic > exchangeable > water soluble.Either higher metal accumulation in shoots or enhanced metal accumulation in roots was mainly due to improved phyto-extraction or rhizo-filtration efficiency, respectively. Heavy metals accumulation in shoots and roots of the investigated plant species was as follow: sunflower > cotton > penakium > Napier grass > Squash with a lower order of magnitude. Sunflower showed superiority for heavy metals extraction.Application of chemical chelators (soil amendments) enhanced the phyto-extraction efficiency of heavy metals by sunflower in both Mostorud and El-Gabal El-Asfar soils. Citric acid enhanced metals accumulation in shoots and roots more than EDTA and ammonium nitrate. Citric acid with rate of 20 m mole/kg soil was the best chelators to enhance phyto- extraction of heavy metals by sunflower.

  18. The third Qinshan nuclear power plant, risks and countermeasures of the fuelling machine head heavy water degradation

    International Nuclear Information System (INIS)

    Huang Yan

    2012-01-01

    The residual light-water brings severe stress on long-term safety and economic operation of units during fuelling machine head maintenance and test. The article tries to analyze how to provides practical countermeasures to reduce the residual light-water during fuelling machine head maintenance and test. By using these countermeasures, the risks of the fuelling machine head heavy water degradation will be reduced to a minimum and we have achieved good results. (author)

  19. Perioperative functional residual capacity.

    Science.gov (United States)

    Wahba, R W

    1991-04-01

    The literature dealing with the magnitude, mechanism and effects of reduced FRC in the perioperative period is reviewed. During general anaesthesia FRC is reduced by approximately 20%. The reduction is greater in the obese and in patients with COPD. The most likely mechanism is the loss of inspiratory muscle tone of the muscles acting on the rib cage. Gas trapping is an additional mechanism. Lung compliance decreases and airways resistance increases, in large part, due to decreased FRC. The larynx is displaced anteriorly and elongated, making laryngoscopy and intubation more difficult. The change in FRC creates or increases intrapulmonary shunt and areas of low ventilation to perfusion. This is due to the occurrence of compression atelectasis, and to regional changes in mechanics and airway closure which tend to reduce ventilation to dependent lung zones which are still well perfused. Abdominal and thoracic operations tend to increase shunting further. Large tidal volume but not PEEP will improve oxygenation, although both increase FRC. Both FRC and vital capacity are reduced following abdominal and thoracic surgery in a predictable pattern. The mechanism is the combined effect of incisional pain and reflex dysfunction of the diaphragm. Additional effects of thoracic surgery include pleural effusion, cooling of the phrenic nerve and mediastinal widening. Postoperative hypoxaemia is a function of reduced FRC and airway closure. There is no real difference among the various methods of active lung expansion in terms of the speed of restoration of lung function, or in preventing postoperative atelectasis/pneumonia. Epidural analgesia does not influence the rate of recovery of lung function, nor does it prevent atelectasis/pneumonia.

  20. Mobility of heavy metals within freshwater sediments affected by motorway stormwater

    Energy Technology Data Exchange (ETDEWEB)

    Stead-Dexter, K.; Ward, N.I

    2004-12-01

    The assessment of the mobility and bioavailability of heavy metals in sediment samples requires the use of sequential extraction procedures. Results for sediments taken from an unmanaged motorway detention pond showed heavy metals to be associated with the carbonate and residual fractions. In particular, nickel and cadmium showed a high percentage association, compared with other geochemical fractions, such as carbonates and residual fractions. Copper and zinc were shown to be associated with carbonates and iron-manganese oxides, whereas lead showed the strongest association (72%) with the Fe-Mn oxides. When compared to a groundwater-fed lake on the same site, all heavy metals contained within this sediment were found to be at much lower concentrations and strongly associated with the residual fraction (>50%) and are therefore strongly bound within the sediment. Following discharge via a wet detention pond, stormwater then flows through a series of interconnecting lake systems. Heavy metal fractionation of these interconnecting lakes is discussed and shows changes in fractionation through the lake system for copper, nickel, lead and zinc. The main concern in these lakes is the continued use of calcium carbonate to maintain freshwater pH for coarse fishing. This practice, used until 1999, may present an enhanced risk to the freshwater environment, causing greater mobility of these metals.

  1. Heavy metal extraction from PCB wastewater treatment sludge by sulfuric acid.

    Science.gov (United States)

    Kuan, Yu-Chung; Lee, I-Hsien; Chern, Jia-Ming

    2010-05-15

    Heavy metals contaminated wastewater sludge is classified as hazardous solid waste and needs to be properly treated to prevent releasing heavy metals to the environment. In this study, the wastewater treatment sludge from a printed circuit board manufacturing plant was treated in a batch reactor by sulfuric acid to remove the contained heavy metals. The effects of sulfuric acid concentration and solid to liquid ratio on the heavy metal removal efficiencies were investigated. The experimental results showed that the total and individual heavy metal removal efficiencies increased with increasing sulfuric acid concentration, but decreased with increasing solid to liquid ratio. A mathematical model was developed to predict the residual sludge weights at varying sulfuric concentrations and solid to liquid ratios. The trivalent heavy metal ions, iron and chromium were more difficult to be removed than the divalent ions, copper, zinc, nickel, and cadmium. For 5 g/L solid to liquid ratio, more than 99.9% of heavy metals can be removed from the sludge by treating with 0.5M sulfuric acid in 2h. Copyright (c) 2010 Elsevier B.V. All rights reserved.

  2. Sequential extraction of heavy metals during composting of sewage sludge.

    Science.gov (United States)

    Amir, Soumia; Hafidi, Mohamed; Merlina, Georges; Revel, Jean-Claude

    2005-05-01

    The major limitation of soil application of sewage sludge compost is the total heavy metal contents and their bioavailability to the soil-plant system. This study was conducted to determine the heavy metal speciation and the influence of changing the physico-chemical properties of the medium in the course of composting on the concentrations, bioavailability or chemical forms of Cu, Zn, Pb and Ni in sewage sludge. Principal physical and chemical properties and FTIR spectroscopical characterization of sludge compost during treatment show the stability and maturity of end product. The total metal contents in the final compost were much lower than the limit values of composts to be used as good soil fertilizer. Furthermore, it was observed by using a sequential extraction procedure in sludge compost at different steps of treatment, that a large proportion of the heavy metals were associated to the residual fraction (70-80%) and more resistant fractions to extraction X-NaOH, X-EDTA, X-HNO3 (12-29%). Less than 2% of metals bound to bioavailable fractions X-(KNO3+H2O). Heavy metal distribution and bioavailability show some changes during composting depending on the metal itself and the physico-chemical properties of the medium. Bioavailable fractions of all elements tend to decrease except Ni-H2O. Zn and mainly Cu present more affinity to organic and carbonate fractions. In contrast, Pb is usually preferentially bound to sulfide forms X-HNO3. Nickel shows a significant decrease of organic form. Significant degrees of correlation were found between heavy metal fractions and changes of some selected variables (e.g. pH, ash, organic matter, humic substance) during the course of composting. Mobile fractions of metals are poorly predictable from the total content. The R2 value was significantly increased by the inclusion of other variables such as the amount of organic matter (OM) and pH.

  3. Heavy metals in some termite species and their nests in Ojo, Lagos ...

    African Journals Online (AJOL)

    Termites feed on decaying organic matter including plant parts and wood, concentrating heavy metals in the process. The main campus of Lagos State University was surveyed for termite species and their heavy metal contents. Nests including mounds, wooden structures and discarded wood products were observed for ...

  4. Evaluation of Crops Sensitivity to Atrazine Soil Residual

    Directory of Open Access Journals (Sweden)

    E Izadi

    2012-02-01

    Full Text Available Abstract In order to study the sensitivity of 9 crops to atrazine soil residual, two separate experiments were conducted in field and greenhouse conditions. First experiment was conducted in a field with treated soil by atrazine based on split plot and the results evaluated in greenhouse conditions. Treatments in the field experiment included two organic manure application rates (0 and 50 t/ha as main plots and 2 atrazine application rates (2 and 4 kg/ha atrazine a.i. as sob plots. After corn harvesting soil was sampled at 0-15 cm surface layer in each plots in 15 points, after mixing the samples. Wheat, barley, sugar beet, pea, lens and colza planted in pots at greenhouse. Second experiment conducted in greenhouse conditions for evaluation of atrazine soil residual in completely randomized design. Treatments included atrazine soil residual concentrations (0, 0.2, 0.5, 1, 5, 10 and 15 mg/kg soil and crops included wheat, barley, sugar beet, pea, lens, rape, bean and tomato. Results showed that atrazine residue had no effect on crops growth in field experiment treated with atrazine. It seems that atrazine residue in filed soil is lower that its damage threshold for crops or maybe for its fast removal in field than in control conditions. But in bioassay experiment (greenhouse experiment crops response to atrazine residues were different. Results showed that onion and pea were most susceptible ant tolerant crops between studied species and based of ED50 parameter the other crops tolerance to total residue ranked as: pea< bean< lentil< sugar beet< tomato< barley< wheat< rape< onion. Keywords: Atrazine residue, Pea, Bean, Lentil, Sugar beet, Barley, Wheat, Rape, Tomato

  5. Weld Residual Stress in Corner Boxing Joints

    OpenAIRE

    Kazuyoshi, Matsuoka; Tokuharu, Yoshii; Ship Research Institute, Ministry of Transport; Ship Research Institute, Ministry of Transport

    1998-01-01

    Fatigue damage often occurs in corner boxing welded joints because of stress concentration and residual stress. The hot spot stress approach is applicable to stress concentration. However, the number of suitable methods for estimating residual stress in welded joints is limited. The purpose of this paper is to clarify the residual stress in corner boxing joints. The method of estimating residual stresses based on the inherent stress technique is presented. Residual stress measurements are per...

  6. Monitoring of ground water quality and heavy metals in soil during large scale bioremediation of petroleum hydrocarbon contaminated waste in India: case studies

    Directory of Open Access Journals (Sweden)

    Ajoy Kumar Mandal

    2014-10-01

    Full Text Available Bioremediation using microbes has been well accepted as an environmentally friendly and economical treatment method for disposal of hazardous petroleum hydrocarbon contaminated waste (oily waste and this type of bioremediation has been successfully conducted in laboratory and on a pilot scale in various countries, including India. Presently there are no federal regulatory guidelines available in India for carrying out field-scale bioremediation of oily waste using microbes. The results of the present study describe the analysis of ground water quality as well as selected heavy metals in oily waste in some of the large-scale field case studies on bioremediation of oily waste (solid waste carried out at various oil installations in India. The results show that there was no contribution of oil and grease and selected heavy metals to the ground water in the nearby area due to adoption of this bioremediation process. The results further reveal that there were no changes in pH and EC of the groundwater due to bioremediation. In almost all cases the selected heavy metals in residual oily waste were within the permissible limits as per Schedule – II of Hazardous Waste Management, Handling and Transboundary Movement Act, Amendment 2008, (HWM Act 2008, by the Ministry of Environment and Forests (MoEF, Government of India (GoI.

  7. Intense negative heavy ion sources

    Science.gov (United States)

    Mori, Yoshiharu; Takagi, Akira; Ikegami, Kiyoshi; Ueno, Akira; Fukumoto, Sadayoshi

    1990-08-01

    Negative ion sources based on plasma-surface interactions (BLAKE ion source) have been developed at KEK for producing negative heavy ions. The first negative heavy ion source (BLAKE-II) was developed by modifying the ordinary negative hydrogen ion source with converter (BLAKE-I) placed into the plasma. It generates various species of negative heavy ions with intense beam currents. For example, a more than 10 mA Au- ion beam was obtained from the ion source. Recently, the large scaled negative heavy ion source (BLAKE-III) has been developed and in the preliminary test experiment, more than 100 mA Cu- ion beam has been stably obtained with a 10% duty factor in pulsed operation. The BLAKE-II ion source was attached to the BNL 15 MV and Tsukuba University TANDEM accelerators and large current negative heavy ion beams were successfully accelerated in pulsed mode operation. Also, it was found that the space charge effect should be carefully considered for such a large current acceleration in a tandem accelerator, especially at the injection beam line and low energy end. In order to examine the negative ion formation process fundamentally, negative ion production probability related on sputtered particle velocity was measured and the results showed exponential dependence of the production probability on particle velocity as Norskov and Lindquist's theory predicted.

  8. Machine Arithmetic in Residual Classes,

    Science.gov (United States)

    1981-04-03

    rsmainder/residue, as this ascape /-nsues from thp determination of system. It can be. zaalizpd ;n the presence of th- arithmetic urit, which wor~s in thz sys...modules Nj. Page 417. Proof. Proof ascaps /ensues directly from the theorem of Gauss. Actually/really, since according to condition (py, qj)-=-. then

  9. Residual stress in polyethylene pipes

    Czech Academy of Sciences Publication Activity Database

    Poduška, Jan; Hutař, Pavel; Kučera, J.; Frank, A.; Sadílek, J.; Pinter, G.; Náhlík, Luboš

    2016-01-01

    Roč. 54, SEP (2016), s. 288-295 ISSN 0142-9418 R&D Projects: GA MŠk LM2015069; GA MŠk(CZ) LQ1601 Institutional support: RVO:68081723 Keywords : polyethylene pipe * residual stress * ring slitting method * lifetime estimation Subject RIV: JL - Materials Fatigue, Friction Mechanics Impact factor: 2.464, year: 2016

  10. Managing woodwaste: Yield from residue

    Energy Technology Data Exchange (ETDEWEB)

    Nielson, E. [LNS Services, Inc., North Vancouver, British Columbia (Canada); Rayner, S. [Pacific Waste Energy Inc., Burnaby, British Columbia (Canada)

    1993-12-31

    Historically, the majority of sawmill waste has been burned or buried for the sole purpose of disposal. In most jurisdictions, environmental legislation will prohibit, or render uneconomic, these practices. Many reports have been prepared to describe the forest industry`s residue and its environmental effect; although these help those looking for industry-wide or regional solutions, such as electricity generation, they have limited value for the mill manager, who has the on-hands responsibility for generation and disposal of the waste. If the mill manager can evaluate waste streams and break them down into their usable components, he can find niche market solutions for portions of the plant residue and redirect waste to poor/no-return, rather than disposal-cost, end uses. In the modern mill, residue is collected at the individual machine centre by waste conveyors that combine and mix sawdust, shavings, bark, etc. and send the result to the hog-fuel pile. The mill waste system should be analyzed to determine the measures that can improve the quality of residues and determine the volumes of any particular category before the mixing, mentioned above, occurs. After this analysis, the mill may find a niche market for a portion of its woodwaste.

  11. Leptogenesis and residual CP symmetry

    International Nuclear Information System (INIS)

    Chen, Peng; Ding, Gui-Jun; King, Stephen F.

    2016-01-01

    We discuss flavour dependent leptogenesis in the framework of lepton flavour models based on discrete flavour and CP symmetries applied to the type-I seesaw model. Working in the flavour basis, we analyse the case of two general residual CP symmetries in the neutrino sector, which corresponds to all possible semi-direct models based on a preserved Z 2 in the neutrino sector, together with a CP symmetry, which constrains the PMNS matrix up to a single free parameter which may be fixed by the reactor angle. We systematically study and classify this case for all possible residual CP symmetries, and show that the R-matrix is tightly constrained up to a single free parameter, with only certain forms being consistent with successful leptogenesis, leading to possible connections between leptogenesis and PMNS parameters. The formalism is completely general in the sense that the two residual CP symmetries could result from any high energy discrete flavour theory which respects any CP symmetry. As a simple example, we apply the formalism to a high energy S 4 flavour symmetry with a generalized CP symmetry, broken to two residual CP symmetries in the neutrino sector, recovering familiar results for PMNS predictions, together with new results for flavour dependent leptogenesis.

  12. Solow Residuals Without Capital Stocks

    DEFF Research Database (Denmark)

    Burda, Michael C.; Severgnini, Battista

    2014-01-01

    We use synthetic data generated by a prototypical stochastic growth model to assess the accuracy of the Solow residual (Solow, 1957) as a measure of total factor productivity (TFP) growth when the capital stock in use is measured with error. We propose two alternative measurements based on current...

  13. Residual Gas Fluorescence for Profile Measurements at the GSI UNILAC

    CERN Document Server

    Forck, P

    2002-01-01

    The high beam currents, delivered at the LINAC at GSI (UNILAC) can destroy intercepting diagnostics within one macro-pulse. As an alternative for a non-destructive profile measurement the methode for residual-gas-fluorescence is investigated. The fluorescence light is emitted by the N2 molecules of the residual gas at the blue wavelength range and can be monitored with a modern CCD-camera. The images are transferred via digital bus (IEEE 1394 'FireWire') and the profiles are generated by analysis of the images with a modern software tool (National Instruments 'LabView'). Due to the short beam pulses (about 0.2 ms) the light intensities emitted by the residual gas are low and require a high amplification (gain >106) which is realized with an image intensifier with double MCP (multi channel plate), connected with a fiber taper to the CCD-chip. The design parameters of the optics and electronics are discussed as well as the advantages of the digital data transmission. Measurements with heavy ion beams of several...

  14. Heavy metals and epigenetic alterations in brain tumors.

    Science.gov (United States)

    Caffo, Maria; Caruso, Gerardo; Fata, Giuseppe La; Barresi, Valeria; Visalli, Maria; Venza, Mario; Venza, Isabella

    2014-12-01

    Heavy metals and their derivatives can cause various diseases. Numerous studies have evaluated the possible link between exposure to heavy metals and various cancers. Recent data show a correlation between heavy metals and aberration of genetic and epigenetic patterns. From a literature search we noticed few experimental and epidemiological studies that evaluate a possible correlation between heavy metals and brain tumors. Gliomas arise due to genetic and epigenetic alterations of glial cells. Changes in gene expression result in the alteration of the cellular division process. Epigenetic alterations in brain tumors include the hypermethylation of CpG group, hypomethylation of specific genes, aberrant activation of genes, and changes in the position of various histones. Heavy metals are capable of generating reactive oxygen assumes that key functions in various pathological mechanisms. Alteration of homeostasis of metals could cause the overproduction of reactive oxygen species and induce DNA damage, lipid peroxidation, and alteration of proteins. In this study we summarize the possible correlation between heavy metals, epigenetic alterations and brain tumors. We report, moreover, the review of relevant literature.

  15. Probing the nuclear symmetry energy with heavy ion collisions

    Science.gov (United States)

    Coupland, Daniel David Schechtman

    There are two distinct components involved in using heavy ion collisions to constrain the density dependence of the symmetry energy. On one hand, observables sensitive to the symmetry energy must be identified and measured with enough precision to provide meaningful constraints. On the other hand, nuclear reaction simulations are used to predict those observables for different possible forms of the symmetry energy. Examination of both components and the interface between them is important to improve the constraints. This thesis contributes to both the experimental and theoretical parts of this endeavor. First, we examine the uncertainties in the simulation of the isospin diffusion observable by varying the input physics within the pBUU transport code. In addition to the symmetry energy, several other uncertain parts of the calculation affect isospin diffusion, most notably the in-medium nucleon-nucleon cross sections and light cluster production. There is also a difference in the calculated isospin transport ratios depending on whether they are computed using the isospin asymmetry of the heavy residue or of all forward-moving fragments. We suggest that measurements comparing these two quantities would help place constraints on the input physics, including the density dependence of the symmetry energy. Second, we present a measurement of the neutron and proton kinetic energy spectra emitted from central collisions of 124Sn + 124Sn and 112Sn + 112Sn at beam energies of 50 MeV per nucleon and 120 MeV per nucleon. Previous transport simulations indicate that ratios of these spectra are sensitive to the density dependence of the symmetry energy and to the isovector momentum dependence of the mean field. Protons were detected in the Large Area Silicon Strip Array (LASSA) and neutrons were detected in the MSU Neutron Walls. The multiplicity of charged particles detected in the MSU Miniball was used to determine the impact parameter of the collisions. Several thin

  16. Residual supersymmetry of compactified d = 10 supergravity

    International Nuclear Information System (INIS)

    Wit, B. de; Smit, D.J.; Hari Dass, N.D.

    1986-05-01

    The conditions for residual supersymmetry in compactified ten-dimensional supergravity theories are investigated, including the effect of a non-constant 'warp factor'. The analysis is based on on-shell transformation laws which implies that certain linear combinations of classical field equations must be satisfied. The conditions for superysymmetry are, in general, not very restrictive. When, in addition, one assumes the validity of Bianchi identities, two independent contractions of the Einstein equation are implied. These equations exclude d=4 de Sitter space; for compactifications to d=4 Minkowski space they only allow purely metric Ricci-flat field configurations with constant warp factor. (Auth.)

  17. Biochemical suitability of crop residues for cellulosic ethanol: disincentives to nitrogen fertilization in corn agriculture.

    Science.gov (United States)

    Gallagher, Morgan E; Hockaday, William C; Masiello, Caroline A; Snapp, Sieglinde; McSwiney, Claire P; Baldock, Jeffrey A

    2011-03-01

    Concerns about energy security and climate change have increased biofuel demand, particularly ethanol produced from cellulosic feedstocks (e.g., food crop residues). A central challenge to cropping for cellulosic ethanol is the potential environmental damage from increased fertilizer use. Previous analyses have assumed that cropping for carbohydrate in residue will require the same amount of fertilizer as cropping for grain. Using (13)C nuclear magnetic resonance, we show that increases in biomass in response to fertilization are not uniform across biochemical classes (carbohydrate, protein, lipid, lignin) or tissues (leaf and stem, grain, reproductive support). Although corn grain responds vigorously and nonlinearly, corn residue shows only modest increases in carbohydrate yields in response to high levels of fertilization (25% increase with 202 kg N ha(-1)). Lignin yields in the residue increased almost twice as much as carbohydrate yields in response to nitrogen, implying that residue feedstock quality declines as more fertilizer is applied. Fertilization also increases the decomposability of corn residue, implying that soil carbon sequestration becomes less efficient with increased fertilizer. Our results suggest that even when corn is grown for grain, benefits of fertilization decline rapidly after the ecosystem's N demands are met. Heavy application of fertilizer yields minimal grain benefits and almost no benefits in residue carbohydrates, while degrading the cellulosic ethanol feedstock quality and soil carbon sequestration capacity.

  18. Menorrhagia (Heavy Menstrual Bleeding)

    Science.gov (United States)

    ... red blood cells to carry oxygen to tissues. Iron deficiency anemia occurs as your body attempts to make up ... iron levels enough to increase the risk of iron deficiency anemia. Signs and symptoms include pale skin, weakness and ...

  19. Technology management for heavy oil

    International Nuclear Information System (INIS)

    Kerr, R.

    1994-01-01

    The framework for investment in research and development (R ampersand D) at a medium-sized Canadian petroleum company is described. The importance of R ampersand D is illustrated by a graph showing the strong positive correlation between R ampersand D intensity and sales for companies in the mainstream oil and gas sector in the USA. Strong R ampersand D efforts also help to maintain market share and enhance corporate ability to transfer technology into its operations. Three ways of structuring, developing, and transferring technology are outlined: using in-house R ampersand D facilities, which is too costly for medium-sized firms; having a central group responsible for funding third-party R ampersand D, transferring technology into the company, and being aware of technology activities within and outside the company; and complete decentralizing of R ampersand D, in which operations decides how, when, and what to spend on R ampersand D. For the medium-sized company, the second option is considered the best choice. Essential R ampersand D administration practices for such a company are reviewed, including corporate support, an updated technology strategy, central funding with a separate budget from operations, a portfolio of R ampersand D projects and ideas, collaboration with other organizations, and effective communication of R ampersand D activity and results to the company. At the company studied, Wascana Energy, R ampersand D is being focused on three priority areas: production technology, enhanced recovery, and heavy oil upgrading. It is estimated that the monetary benefits of R ampersand D in these three areas could be as much as $100 million. The evaluation of R ampersand D performance is then discussed and critical factors for R ampersand D success are listed. 3 figs., 1 tab

  20. Development of cost-effective sensor for the in-situ monitoring of heavy metals

    OpenAIRE

    Lacour, Gareth; McCaul, Margaret; Donohoe, Andrew; Diamond, Dermot

    2017-01-01

    Heavy Metals are of environmental interest due to persistence in both fresh and marine water environments 1. Heavy metals in seawater come from both natural process and anthropogenic activities. 2. The main sources of anthropogenic pollution by heavy metals in the coastal regions include industrial wastes, liquid effluents and paint degradation of ships 3. Metal ions such as copper, zinc and cadmium at low concentrations are necessary micronutrients, however at higher concentration t...