WorldWideScience

Sample records for residential gas-fired sorption

  1. Residential gas-fired sorption heat pumps. Test and technology evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Naeslund, M.

    2008-12-15

    Heat pumps may be the next step in gas-fired residential space heating. Together with solar energy it is an option to combine natural gas and renewable energy. Heat pumps for residential space heating are likely to be based on the absorption or adsorption process, i.e. sorption heat pumps. Manufacturers claim that the efficiency could reach 140-160%. The annual efficiency will be lower but it is clear that gas-fired heat pumps can involve an efficiency and technology step equal to the transition from non-condensing gas boilers with atmospheric burners to condensing boilers. This report contains a review of the current sorption gas-fired heat pumps for residential space heating and also the visible development trends. A prototype heat pump has been laboratory tested. Field test results from Germany and the Netherlands are also used for a technology evaluation. The tested heat pump unit combines a small heat pump and a supplementary condensing gas boiler. Field tests show an average annual efficiency of 120% for this prototype design. The manufacturer abandoned the tested design during the project period and the current development concentrates on a heat pump design only comprising the heat pump, although larger. The heat pump development at three manufacturers in Germany indicates a commercial stage around 2010-2011. A fairly high electricity consumption compared to traditional condensing boilers was observed in the tested heat pump. Based on current prices for natural gas and electricity the cost savings were estimated to 12% and 27% for heat pumps with 120% and 150% annual efficiency respectively. There is currently no widespread performance testing procedure useful for annual efficiency calculations of gas-fired heat pumps. The situation seems to be clearer for electric compression heat pumps regarding proposed testing and calculation procedures. A German environmental label exists and gasfired sorption heat pumps are also slightly treated in the Eco-design work

  2. Development and Validation of a Gas-Fired Residential Heat Pump Water Heater - Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Michael Garrabrant; Roger Stout; Paul Glanville; Janice Fitzgerald; Chris Keinath

    2013-01-21

    For gas-fired residential water heating, the U.S. and Canada is predominantly supplied by minimum efficiency storage water heaters with Energy Factors (EF) in the range of 0.59 to 0.62. Higher efficiency and higher cost ($700 - $2,000) options serve about 15% of the market, but still have EFs below 1.0, ranging from 0.65 to 0.95. To develop a new class of water heating products that exceeds the traditional limit of thermal efficiency, the project team designed and demonstrated a packaged water heater driven by a gas-fired ammonia-water absorption heat pump. This gas-fired heat pump water heater can achieve EFs of 1.3 or higher, at a consumer cost of $2,000 or less. Led by Stone Mountain Technologies Inc. (SMTI), with support from A.O. Smith, the Gas Technology Institute (GTI), and Georgia Tech, the cross-functional team completed research and development tasks including cycle modeling, breadboard evaluation of two cycles and two heat exchanger classes, heat pump/storage tank integration, compact solution pump development, combustion system specification, and evaluation of packaged prototype GHPWHs. The heat pump system extracts low grade heat from the ambient air and produces high grade heat suitable for heating water in a storage tank for domestic use. Product features that include conventional installation practices, standard footprint and reasonable economic payback, position the technology to gain significant market penetration, resulting in a large reduction of energy use and greenhouse gas emissions from domestic hot water production.

  3. Preliminary experimental investigation of a natural gas-fired ORC-based micro-CHP system for residential buildings

    International Nuclear Information System (INIS)

    Farrokhi, M.; Noie, S.H.; Akbarzadeh, A.A.

    2014-01-01

    The continual increases in energy demand and greenhouse gas emissions, call for efficient use of energy resources. Decentralized combined heat and power (CHP) technology provides an alternative for the world to meet and solve energy-related problems including energy shortages, energy supply security, emission control and conservation of energy. This paper presents the preliminary results of an experimental investigation of a natural gas-fired micro-CHP system for residential buildings based on an organic Rankine cycle (ORC). Isopentane was used as the ORC working fluid in consideration of several criteria including its environmentally-friendly characteristics. Experiments were conducted to evaluate the performance of the developed system at different heat source temperatures of nominally 85, 80, 75, 70, and 65 °C. The maximum electrical power output of 77.4 W was generated at heating water entry temperature of 84.1 °C, corresponding to net cycle electrical efficiency of 1.66%. Further work will be done with a view to increasing the cycle electrical efficiency by using more efficient components, in particular the expander and generator. - Highlights: •A natural gas-fired ORC-based micro-scale CHP system has been developed and tested. •The good agreement between the mechanical and gross power validates the assumptions. •A vane expander suits a micro-CHP system based on an organic Rankine cycle. •A vane expander does not suit power generation by a Trilateral Flash Cycle (TFC). •Domestic gas-fired ORC systems may reduce reliance on central power stations

  4. Development and evaluation of a new depressurization spillage test for residential gas-fired combustion appliances : final report

    International Nuclear Information System (INIS)

    Edwards, P.

    2005-07-01

    This paper presented a newly developed combustion depressurization spillage test for residential combustion appliances. The test uses carbon dioxide (CO 2 ) that is produced in the fuel combustion process as a tracer gas. The test accurately measures the amount of combustion spillage from residential combustion appliances and their venting systems when they operate at certain levels of depressurization. Seven commonly used gas-fired appliances were used to evaluate the new test as well as the appliances. These included 2 power-vented storage-tank water heaters, 1 mid-efficiency furnace, 2 high-efficiency condensing furnaces, and 2 direct-vent gas fireplaces. Tests were performed for each unit with the test room initially depressurized by 50 Pa compared with the pressure outside the room. If the combustion spillage exceeded 2 per cent, the test was repeated with the room depressurized by 20 Pa, and then by 5 Pa. Each appliance was operated for 5 minutes of burner operation during which time the burner fuel consumption, the concentration of CO 2 and the exhaust fan flow rate were monitored. Measurements were taken for 2 minutes following burner shut off. The amount of CO 2 that was released into the test room from the appliance and its venting system was determined from the measurements and then compared with the amount of CO 2 that would be produced by combustion of the fuel that was consumed during the test. The ratio of the 2 provided a direct measure of the combustion spillage of the appliance and its venting system. The study revealed that 3 products had undetectable levels of combustion spillage, 3 products had low, but measurable combustion spillage, and 1 product had significant combustion spillage. refs., tabs., figs

  5. Size distribution and concentration of soot generated in oil and gas-fired residential boilers under different combustion conditions

    Science.gov (United States)

    Jiménez, Santiago; Barroso, Jorge; Pina, Antonio; Ballester, Javier

    2016-05-01

    In spite of the relevance of residential heating burners in the global emission of soot particles to the atmosphere, relatively little information on their properties (concentration, size distribution) is available in the literature, and even less regarding the dependence of those properties on the operating conditions. Instead, the usual procedure to characterize those emissions is to measure the smoke opacity by several methods, among which the blackening of a paper after filtering a fixed amount of gas (Bacharach test) is predominant. In this work, the size distributions of the particles generated in the combustion of a variety of gaseous and liquid fuels in a laboratory facility equipped with commercial burners have been measured with a size classifier coupled to a particle counter in a broad range of operating conditions (air excesses), with simultaneous determination of the Bacharach index. The shape and evolution of the distribution with progressively smaller oxygen concentrations depends essentially on the state of the fuel: whereas the combustion of the gases results in monomodal distributions that 'shift' towards larger diameters, in the case of the gas-oils an ultrafine mode is always observed, and a secondary mode of coarse particle grows in relevance. In both cases, there is a strong, exponential correlation between the total mass concentration and the Bacharach opacity index, quite similar for both groups of fuels. The empirical expressions proposed may allow other researchers to at least estimate the emissions of numerous combustion facilities routinely characterized by their smoke opacities.

  6. Sorption of organic gases in residential bedrooms andbathrooms

    Energy Technology Data Exchange (ETDEWEB)

    Singer, B.C.; Hodgson, A.T.; Hotchi, T.; Ming, K.Y.; Sextro,R.G.; Wood, E.E.; Brown, N.J.

    2005-01-05

    Experiments were conducted to characterize organic gas sorption in residential bedrooms (n=4), bathrooms (n=2), and a furnished test chamber. Rooms were studied ''as-is'' with material surfaces and furnishings unaltered. Surface materials were characterized and areas quantified. Experiments included rapid volatilization of a volatile organic compound (VOC) mixture with the room closed and sealed for a 5-h Adsorb phase, followed by 30-min Flush and 2-h closed-room Desorb phases. The mixture included n-alkanes, aromatics, glycol ethers, 2-ethyl-1-hexanol, dichlorobenzene, and organophosphorus compounds. Measured gas-phase concentrations were fit to three variations of a mathematical model that considers sorption occurring at one surface sink and one potential embedded sink. The 2-parameter sink model tracked measurements for most compounds, but improved fits were obtained for some VOCs with a 3-parameter sink-diffusion or a 4-parameter two-sink model. Sorptive partitioning and initial adsorption rates increased with decreasing vapor pressure within each chemical class.

  7. Gas fired heat pumps

    International Nuclear Information System (INIS)

    Seifert, M.

    2006-01-01

    The condensing gas boiler is now state of the art and there is no more room for improvement in performance, technically speaking. The next logical step to improve the overall efficiency is to exploit ambient heat in combination with the primary source of energy, natural gas. That means using natural-gas driven heat pumps and gas-fired heat pumps. Based on this, the Swiss Gas Industry decided to set up a practical test programme enjoying a high priority. The aim of the project 'Gas-fired heat pump practical test' is to assess by field tests the characteristics and performance of the foreign serial heat pumps currently on the market and to prepare and promote the introduction on the market place of this sustainable natural-gas technology. (author)

  8. Gas fired boilers and atmospheric pollution

    International Nuclear Information System (INIS)

    Chiaranello, J.M.

    1991-01-01

    A general analysis concerning atmospheric pollution is presented: chemical composition and vertical distribution of atmosphere and pollutants, chemical reactions, ozone destruction and production cycles, COx, NOx and SOx pollutions. The gas fired boiler number and repartition in France are presented and the associated pollution is analyzed (CO2, CO, NOx) and quantified. Various pollution control technics concerning gas fired boiler pollutants are described and a pollution criterion for clean gas fired generators is proposed

  9. Gas fired advanced turbine system

    Science.gov (United States)

    Lecren, R. T.; White, D. J.

    The basic concept thus derived from the Ericsson cycle is an intercooled, recuperated, and reheated gas turbine. Theoretical performance analyses, however, showed that reheat at high turbine rotor inlet temperatures (TRIT) did not provide significant efficiency gains and that the 50 percent efficiency goal could be met without reheat. Based upon these findings, the engine concept adopted as a starting point for the gas-fired advanced turbine system is an intercooled, recuperated (ICR) gas turbine. It was found that, at inlet temperatures greater than 2450 F, the thermal efficiency could be maintained above 50%, provided that the turbine cooling flows could be reduced to 7% of the main air flow or lower. This dual and conflicting requirement of increased temperatures and reduced cooling will probably force the abandonment of traditional air cooled turbine parts. Thus, the use of either ceramic materials or non-air cooling fluids has to be considered for the turbine nozzle guide vanes and turbine blades. The use of ceramic components for the proposed engine system is generally preferred because of the potential growth to higher temperatures that is available with such materials.

  10. Gas-fired electric power generating technologies

    International Nuclear Information System (INIS)

    1994-09-01

    The workshop that was held in Madrid 25-27 May 1994 included participation by experts from 16 countries. They represented such diverse fields and disciplines as technology, governmental regulation, economics, and environment. Thus, the participants provided an excellent cross section of key areas and a diversity of viewpoints. At the workshop, a broad range of topics regarding gas-fired electric power generation was discussed. These included political, regulatory and financial issues as well as more specific technical questions regarding the environment, energy efficiency, advanced generation technologies and the status of competitive developments. Important technological advances in gas-based power and CHP technologies have already been achieved including higher energy efficiency and lower emissions, with further improvements expected in the near future. Advanced technology trends include: (a) The use of gas technology to reduce emissions from existing coal-fired power plants. (b) The wide-spread application of combined-cycle gas turbines in new power plants and the growing use of aero-derivative gas turbines in CHP applications. (c) Phosphoric acid fuel cells that are being introduced commercially. Their market penetration will grow over the next 10 years. The next generation of fuel cells (solid oxide and molten carbonate) is expected to enter the market around the year 2000. (EG)

  11. An application of the gas-fired chilling and heating units to domestic houses

    Energy Technology Data Exchange (ETDEWEB)

    Choi, J.H.; Yang, Y.M.; Chae, J.M.; Bang, H.S.; Kwon, O.B.; Yoo, S.I.; Kim, T.H. [R and D Center, Korea Gas Co. (Korea); Lee, T.W.; Kim, T.H.; Kim, B.H.; Hwang, I.J.; Kim, J.Y.; Kim, C.D.; Park, S.J. [Korea Institute of Construction Technology (Korea)

    1999-10-01

    Following researches and considerations were performed in this study for an efficient application of gas-fired chilling and heating units to the residential buildings. (1) Status of domestic cooling and heating for residential building. (2) Various introduction schemes of outdoor unit. (3) Design exclusive area for the gas appliance and installation of it. (4) Ventilation of exhaust gas and heat. (5) Prepare the installation specifications or standards for gas-fired chilling and heating units. (6) Design technique of plumbing for cooling and heating. (7) Evaluation of unit's capacity considering the thermal load of domestic buildings. (8) Cooling and heating system with the unit. (9) Fundamental test for evaluation of applicability. (10) Actual design and construction of experimental house for an application and a demonstration of the developed gas units. (11) Field test for cooling and heating. (12) Evaluation of economic efficiency. (13) Establish a business potential. (14) Establishment of legal and systematic support, energy rate. (15) Troubleshooting in the course of development and application of the new gas appliance. 41 refs., 214 figs., 52 tabs.

  12. Gas-fired Power Generation in India: Challenges and opportunities

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    India's fast growing economy needs to add 100,000 MW power generating capacity between 2002-2012. Given limitations to the use of coal in terms of environmental considerations, quality and supply constraints, gas is expected to play an increasingly important role in India's power sector. This report briefs NMC Delegates on the potential for gas-fired power generation in India and describes the challenges India faces to translate the potential for gas-fired power generation into reality.

  13. Dynamics and control of a gas-fired furnace

    NARCIS (Netherlands)

    Roffel, B.; Rijnsdorp, J.E.

    1974-01-01

    A non-linear model has been developed for a gas-fired furnace in which oil is heated. The model is applicable from minimum to maximum heat load of the furnace. The dynamics of the model have been compared to experimental results, which were obtained for a pilot-scale furnace. They are in good

  14. Development of a cylindrical gas-fired furnace for reycling ...

    African Journals Online (AJOL)

    This study presents the development of a cylindrical gas-fired furnace, which could be used for recycling aluminum in small-scale foundries in Nigeria. The crucible, combustion chamber, suspension shaft and bearings were appropriately sized. The furnace chamber was 410 mm high and 510 mm diameter and had a ...

  15. Multi-Function Gas Fired Heat Pump

    Energy Technology Data Exchange (ETDEWEB)

    Mehdizadeh Momen, Ayyoub [ORNL; Abu-Heiba, Ahmad [ORNL; Vineyard, Edward Allan [ORNL

    2015-11-01

    The aim of this project was to design a residential fuel fired heat pump and further improve efficiency in collaboration with an industry partner – Southwest Gas, the developer of the Nextaire commercial rooftop fuel-fired heat pump. Work started in late 2010. After extensive search for suitable engines, one manufactured by Marathon was selected. Several prototypes were designed and built over the following four years. Design changes were focused on lowering the cost of components and the cost of manufacturing. The design evolved to a final one that yielded the lowest cost. The final design also incorporates noise and vibration reduction measures that were verified to be effective through a customer survey. ETL certification is currently (as of November 2015) underway. Southwest Gas is currently in talks with GTI to reach an agreement through which GTI will assess the commercial viability and potential of the heat pump. Southwest Gas is searching for investors to manufacture the heat pump and introduce it to the market.

  16. The potential for gas fired generation in Atlantic Canada

    International Nuclear Information System (INIS)

    MacDonald, T.

    2002-01-01

    The objective of this presentation was to stimulate discussion regarding the potential for Maritimes based gas fired power generation. It was noted that although the subject is complex, simplified assumptions are presented. The topics of discussion include the move to restructure the electric power industry in Nova Scotia and New Brunswick, the interest in gas fired generation in Atlantic Canada, the expected increase in natural gas consumption, and the issue of whether there is sufficient supply and adequate infrastructure to support demand. Other topics of discussion included the impact of regulations on the industry, and the future outlook of natural gas supply as it relates to power generation. The efforts of the natural gas industry to meet US natural gas generating requirements were also discussed. 3 tabs., 8 figs

  17. Gas-fired power. IEA ETSAP technology brief E02

    Energy Technology Data Exchange (ETDEWEB)

    Seebregts, A.J. [Energy research Centre of the Netherlands (Netherlands)], E-mail: seebregts@ecn.nl

    2010-04-15

    This technology brief on gas-fired power is part of a series produced by the IEA called the energy technology data source (E-Tech-DS). The E-Tech-DS series consists of a number of 5-10 page technology briefs similar to the IEA Energy Technology Essentials. Based on the data collected for the models that the Energy Technology Systems Analysis Programme (ETSAP) is known for, ETSAP also prepares technology briefs, called E-TechDS. The E-TechDS briefs are standardized presentations of basic information (process, status, performance, costs, potential, and barriers) for key energy technology clusters. Each brief includes an overview of the technology, charts and graphs, and a summary data table, and usually ending with some key references and further information. The E TechDS briefs are intended to offer essential, reliable and quantitative information to energy analysts, experts, policymakers, investors and media from both developed and developing countries. This specific brief focuses on the state of combined-cycle gas turbines (CCGT). CCGT's have become the technology of choice for new gas-fired power plants since the 1990's.

  18. An overview of the political, technical and economical aspects of gas-fired distributed energy system in China

    International Nuclear Information System (INIS)

    Chen, Qiaohui; Wang, Weilong; Lu, Jianfeng; Ding, Jing

    2013-01-01

    The interest in distributed energy system has been increasing in China in recent years due to the environmental and energy policy concerns. The distributed energy system generates power, heating and cooling to residential, commercial and industrial facilities. Due to cascade utilization of energy, it can make good use of energy to improve energy efficiency and to increase energy savings. Furthermore, it consumes less energy and reduces carbon emissions. This paper reviews existing and newly-built gas-fired distributed energy projects in China. The techno-economic assessment of the selected projects has also been discussed and reported. The results show that in Xiamen Jimei DE project, the primary energy ratio of the DES can be as high as 92.9%, and energy-saving rate is 35.5%. Moreover, exergy efficiency reaches 54.3%, and the system can reduce 0.52 million tons of CO 2 annually. -- Highlights: ► The political, technical and economical aspects of gas-fired DES are analyzed. ► The techno-economic assessment of two selected projects is conducted. ► Primary energy ratio can be as high as 92.9% and energy-saving rate is 35.5%. ► Exergy efficiency is 54.3% and the system can reduce a large amount of CO 2 emissions

  19. Gas supply planning for new gas-fired electricity generation facilities

    International Nuclear Information System (INIS)

    Slocum, J.C.

    1990-01-01

    This paper explores several key issues in gas supply planning for new gas fired electric generation facilities. This paper will have two main sections, as follows: developing the gas supply plan for a gas-fired electricity generation facility and exploring key gas supply contract pricing issues

  20. Gas-Fired Distributed Energy Resource Technology Characterizations

    Energy Technology Data Exchange (ETDEWEB)

    Goldstein, L.; Hedman, B.; Knowles, D.; Freedman, S. I.; Woods, R.; Schweizer, T.

    2003-11-01

    The U. S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) is directing substantial programs in the development and encouragement of new energy technologies. Among them are renewable energy and distributed energy resource technologies. As part of its ongoing effort to document the status and potential of these technologies, DOE EERE directed the National Renewable Energy Laboratory to lead an effort to develop and publish Distributed Energy Technology Characterizations (TCs) that would provide both the department and energy community with a consistent and objective set of cost and performance data in prospective electric-power generation applications in the United States. Toward that goal, DOE/EERE - joined by the Electric Power Research Institute (EPRI) - published the Renewable Energy Technology Characterizations in December 1997.As a follow-up, DOE EERE - joined by the Gas Research Institute - is now publishing this document, Gas-Fired Distributed Energy Resource Technology Characterizations.

  1. General conditions for gas-fired power plants in Europe

    International Nuclear Information System (INIS)

    Hugi, Ch.; Fuessler, J.; Sommerhalder, M.

    2006-11-01

    This comprehensive report for the Swiss Federal Office of Energy (SFOE) takes a look at the general conditions for the installation of gas-fired power plants in Europe. Combined cycle power stations are characterised and the associated power production costs are discussed. Also, the prices resulting from the internalisation of external costs are noted. The problems associated with carbon dioxide emissions are discussed and the trading of emission certificates is looked at. Also, nitrogen oxide emissions are examined and discussed. The use of waste heat from the combined cycle power stations is also examined. Further topics include subsidies and special credits for the gas industry in Europe and the granting of permission for the planning, construction, operation and dismantling of the power station facilities. The situation in various European countries is examined and the associated market distortion is commented on

  2. Carbon dioxide recovery from gas-fired power plants

    Energy Technology Data Exchange (ETDEWEB)

    Martins, Ricardo Salgado; Barbosa, Joao Roberto [Centro Tecnico Aeroespacial, Sao Jose dos Campos, SP (Brazil). Inst. Tecnologico de Aeronautica. Dept. de Energia]. E-mails: martinsr@epenergy.com; barbosa@mec.ita.br; Prado, Eduardo Lanari [Rice Univ., Houston, TX (United States). Jones Graduate School of Business]. E-mail: pradoe@epenergy.com; Vieira, Adriana de Moura [Instituto Brasileiro de Mercado de Capitais (IBMEC), Rio de Janeiro, RJ (Brazil). Dept. de Financas]. E-mail: vieiraa@epenergy.com

    2000-07-01

    Since 1996 the Brazilian electric sector has undergone a major restructuring. The aim of such change is to reduce the State's participation in the sector, and to induce the growth of private investments. In particular, this event created several opportunities for thermal power plant projects, leading to competition at the generation level. In this scenario of increased competition, the power plant efficiency becomes a key element for determining the feasibility and profitability of the project. Moreover, the utilization of the plant's own effluents as feedstock or as a source of additional revenue will impact positively in its economics. As an example, long term additional revenues could be created by the sale of CO{sub 2} extracted from the combustion products of thermal power plants. The production of CO{sub 2} also contributes to mitigate the environmental impacts of the power plant project by significantly reducing its airborne emissions. This paper shows how a gas-fired power plant can extract and utilize CO{sub 2} to generate additional revenue, contributing to a more competitive power plant. (author)

  3. Environmental optimisation of natural gas fired engines. Main report

    Energy Technology Data Exchange (ETDEWEB)

    Kvist, T. et al.

    2010-10-15

    The overall aim of the project has been to assess to which extent it is possible to reduce the emissions by adjusting the different engines examined and to determine the cost of the damage caused by emissions from natural gas combustion. However, only health and climate effects are included. The emissions of NO{sub x}, CO and UHC as well as the composition of the hydrocarbon emissions were measured for four different stationary lean-burn natural-gas fired engines installed at different combined heat and power (CHP) units in Denmark. The units were chosen to be representative of the natural gas fired engine-based power production in Denmark. The measurements showed that NO{sub x} emissions were relatively more sensitive to engine setting than UHC, CO and formaldehyde emissions. By reducing the NO{sub x} emissions to 40 % of the initial value (from 500 to 200 mg/m3(n) at 5 % O{sub 2}) the UHC emission was increased by 10 % to 50 % of the initial value. The electrical efficiency was reduced by 0.5 to 1.0 percentage point. Externalities in relation to power production are defined as the costs, which are not directly included in the price of the produced power. Health effects related to air pollution from power plants fall under this definition and usually dominate the results on external costs. For determination of these effects the exposure of the population, the impact of the exposure and the societal costs accompanying the impacts have been evaluated. As expected, it was found that when the engines are adjusted in order to reduce NO{sub x} emissions, the emission of UHC increases and vice versa. It was found that at high NO{sub x} emission levels (500 mg/m3{sub n} at 5 % O{sub 2}) the external costs related to the NO{sub x} emissions are 15 to 25 times the costs related to UHC emissions. At low NO{sub x} emission levels (200 mg/m3{sub n} at 5 % O{sub 2}) the costs related to NO{sub x} are 5 to 8 times the costs related to UHC emissions. Apparently, the harmfulness

  4. Fuel strategies for natural gas fired cogeneration and IPP projects

    International Nuclear Information System (INIS)

    Gottlieb, J.W.

    1992-01-01

    This paper as published is the outline of a presentation on managing the risk of varying fuel costs as part of a successful fuel strategy for natural gas fired cogeneration and Independent Power Producer (IPP) projects. So long as the fuel cost that electric utilities recover from their ratepayers differs from the fuel costs incurred by IPP and Qualifying Facility (QF) plant operators, the largest variable cost risk of any QF or IPP will continue to be the cost of fuel. Managing that risk is the mission of any successful fuel procurement strategy. Unfortunately, a quick review of the last 20 years in the oil and gas industry reveals dramatic and substantial changes in price and fuel availability that few, if any, industry experts could have predicted in 1971. Recognizing that the fuel cost risk to a QF or IPP investor also spans a 20 year period, the typical term of a QF or IPP power purchase contract, a successful fuel procurement strategy must consider and address the likelihood of future changes. Due to federal and state regulatory changes made from 1978 to 1989, the current structure of the oil and gas industry appears to provide end-users with the tools to improve the manageability of fuel cost risks. QF and IPP developers can choose the type of service they desire and can negotiate most of the contractual elements of that service. Until electric utilities are allowed to flow through their rates the fuel costs incurred by QFs and IPPs, a thorough analysis of the available fuel procurement options prior to development of a QF or IPP will continue to be absolutely necessary

  5. Holden gas-fired furnace baseline data. Revision 1

    International Nuclear Information System (INIS)

    Weatherspoon, K.A.

    1996-11-01

    The Holden gas-fired furnace is used in the enriched uranium recovery process to dry and combust small batches of combustibles. The ash is further processed. The furnace operates by allowing a short natural gas flame to burn over the face of a wall of porous fire brick on two sides of the furnace. Each firing wall uses two main burners and a pilot burner to heat the porous fire brick to a luminous glow. Regulators and orifice valves are used to provide a minimum gas pressure of 4 in. water column at a rate of approximately 1,450 scf/h to the burners. The gas flow rate was calculated by determining the gas flow appropriate for the instrumentation in the gas line. Observed flame length and vendor literature were used to calculate pilot burner gas consumption. Air for combustion, purging, and cooling is supplied by a single blower. Rough calculations of the air-flow distribution in piping entering the furnace show that air flow to the burners approximately agrees with the calculated natural gas flow. A simple on/off control loop is used to maintain a temperature of 1,000 F in the furnace chamber. Hoods and glove boxes provide contamination control during furnace loading and unloading and ash handling. Fan EF-120 exhausts the hoods, glove boxes, and furnace through filters to Stack 33. A review of the furnace safety shows that safety is ensured by design, interlocks, procedure, and a safety system. Recommendations for safety improvements include installation of both a timed ignition system and a combustible-gas monitor near the furnace. Contamination control in the area could be improved by redesigning the loading hood face and replacing worn gaskets throughout the system. 33 refs., 16 figs

  6. Gas to Power in China. Gas-fired Power in China. Clearing the policy bottleneck

    International Nuclear Information System (INIS)

    Chen, Xavier

    2005-12-01

    Policy for gas-fired power is the single most serious and common issue that needs urgent resolution for all China's current and future gas projects, including LNG projects. This was the main conclusion of a national seminar on gas industry development policy that was held in July 2004. At the time of writing this paper, such a policy is still missing. In order to reduce pollution, improve energy security and meet the needs of the ever-growing economy for high-quality energies, the Chinese government has declared its firm intention to develop a natural gas market. The official target is to develop a gas market of 200 bcm/a by 2020, five times of the current size of around 40 bcm/a. Domestic supply is expected to provide 120 bcm/a, with the rest (80 bcm/a) by gas imports either in the form of piped gas or LNG. Gas-fired power generation plays a critical role in developing a sizeable gas market, especially for large-scale pipeline and LNG projects. Similar to the Guangdong and Fujian LNG projects where gas-fired power accounts for approximately 60% and 70% respectively of the first phase gas volume, each of the proposed LNG projects has allocated a large portion of the gas off-take volume to the power sector. In addition to the first two commercial CCGT plants that were commissioned in 2005, there are over 20 projects totalling 18 GW of capacity under construction. By 2020, China's planners foresee a total gas-fired power capacity of 60 GW, accounting for around 6% of the total installed capacity in the country. Despite these impressive projections, gas-fired power faces significant uncertainties in China: (1) there is an ongoing debate on whether China should develop gas-fired power, given the relative scarcity and higher cost of gas; (2) high gas prices and imported equipment limit the competitiveness of gas-fired power relative to a coal-fired one; (3) it lacks policy support. For the moment, gas-fired power plants are required to participate in a yet

  7. Development of a gas fired Vuilleumier heat pump for residential heating

    DEFF Research Database (Denmark)

    Carlsen, Henrik

    1989-01-01

    A natural gas-driven heat pump based on the Vuilleumier principle has been developed for use in single-family houses. The pump has a heat output of 7.5 kW at a coefficient of performance of 1.62 based on the lower heat content of the gas fuel. The heat pump uses helium as working fluid at 20 MPa...... mean pressure, and it is designed as a semihermetic unit. A crank mechanism distinguished by very small loads on the piston rings was developed. The advantages and disadvantages of the Vuilleumier principle for heat-driven heat pumps are discussed. Results of the extensive experimental work...... are presented. A new 20 kW Vuilleumier heat pump is briefly described...

  8. Sorption mechanisms and sorption models

    International Nuclear Information System (INIS)

    Fedoroff, M.; Lefevre, G.; Duc, M.; Neskovic, C.; Milonjic, S.

    2004-01-01

    Sorption at the solid-liquid interfaces play a major role in many phenomena and technologies: chemical separations, catalysis, biological processes, transport of toxic and radioactive species in surface and underground waters. The long term safety of radioactive waste repositories is based on artificial and natural barriers, intended to sorb radionuclides after the moment when the storage matrixes and containers will be corroded. Predictions on the efficiency of sorption for more than 10 6 years have to be done in order to demonstrate the safety of such depositories, what is a goal never encountered in the history of sciences and technology. For all these purposes, and, especially for the long term prediction, acquiring of sorption data constitutes only a first step of studies. Modeling based on a very good knowledge of sorption mechanisms is needed. In this review, we shall examine the main approaches and models used to quantify sorption processes, including results taken from the literature and from our own studies. We shall compare sorption models and examine their adequacy with sorption mechanisms. The cited references are only a few examples of the numerous articles published in that field. (orig.)

  9. Dioxin and furan emissions from landfill gas-fired combustion units

    International Nuclear Information System (INIS)

    Caponi, F.R.; Wheless, E.; Frediani, D.

    1998-01-01

    The 1990 Federal Clean Air Act Amendments require the development of maximum achievable control technology standards (MACT) for sources of hazardous air pollutants, including landfill gas-fired combustion sources. The Industrial Combustion Coordinated Rulemaking (ICCR) Federal Advisory Committee is a group of stakeholders from the public and private sector whose charge is to develop recommendations for a unified set of federal toxic air emissions regulations. Specifically, the group will establish MACT standards for industrial-commercial-institutional combustion sources. The ICCR proceedings have given rise to considerable interest in potential dioxin and furan emissions from landfill gas-fired combustion units. In order to establish the potential of dioxin and furan emissions from this group of combustion sources, a world-wide literature search was conducted. A total of 22 references were evaluated. The references covered a wide range of test programs, testing methodologies and combustion equipment type. The most abundant data were for landfill gas-fired flares (shrouded and afterburners) and I.C. engines. Because of limitations in obtaining actual test reports with complete lab data and QA/QC results, and a lack of knowledge as to the exact types of waste received at the European landfills, the test data from these sources, for the purposes of this paper, are considered qualitative. The conclusion reached from review of the test data is that there is a potential for dioxin and furan emissions from landfill gas-fired combustion units, but at very low levels for well operated systems

  10. Application of gas-fired infra-red radiator to thermal disinfection of horticultural substrate

    International Nuclear Information System (INIS)

    Wawer, M.; Osiński, A.

    1998-01-01

    The studies were carried out on heating horticultural substrate (moor peat - bark, 1:1 by volume) with a gas-fired infra-red radiator to destroy the pests and pathogens. Minimum distance between radiator and substrate surface was determined considering assumed time of heating. Dynamics of substrate heating was determined depending on its layer thickness and kind of surface under substrate layer; black rubber, ground steel sheet and aluminium foil were used as the surface. Considerable decreasing of infra-red radiation penetrability through the substrate layer above 7 mm thick was found as well as an significant effect of the radiation reflected from the surface under substrate layer on the intensity of its heating. It was also stated that heating horticultural substrates with the gas-fired infra-red radiator enables to rise the temperature of thin substrate layer up to 70 degree of C within relatively short time [pl

  11. Selective catalytic reduction (SCR) NOx control for small natural gas-fired prime movers

    International Nuclear Information System (INIS)

    Shareef, G.S.; Stone, D.K.; Ferry, K.R.; Johnson, K.L.; Locke, K.S.

    1992-01-01

    The application of selective catalytic reduction (SCR) to small natural gas-fired prime movers at cogeneration facilities and compressor stations could possibly increase due to regulatory forces to limit NO x from such sources. The natural gas industry is presently without a current database with which to evaluate the cost and operating characteristics of SCR under the conditions anticipated for small prime movers. This paper presents the results from a two-phase study undertaken to document SCR applications with emphasis on SCR system performance and costs. The database of small natural gas-fired prime mover SCR experience, focusing on prime mover characterization, SCR system performance, and SCR system costs will be described. Result from analysis of performance and cost data will be discussed, including analytical tools developed to project SCR system performance and costs

  12. Economic potential of natural gas-fired cogeneration in Brazil: two case studies

    Energy Technology Data Exchange (ETDEWEB)

    Szklo, Alexandre Salem; Soares, Jeferson Borghetti; Tolmasquim, Mauricio Tiomno [Rio de Janeiro Federal Univ., Energy Planning Program (COPPE), Rio de Janeiro (Brazil); Cidade Univ., Ilha do Fundao, Rio de Janeiro (Brazil)

    2000-11-01

    Recent restructuring of Brazil's power sector, allied to the expected larger share of natural gas in the nation's grid and the cost reductions of gas-fired power generation technologies, has introduced a set of situations apparently favorable to the expansion of natural gas-fired cogeneration. However, electricity self-generation applications are restricted to specific cases in Brazil. In order to deal with this issue, the COGEN model was developed to assess the economic potential of cogeneration ventures from the standpoint of the investor and guide incentive public policies. This model has been applied to two cases in Brazil -- a chemical plant and a shopping mall -- showing that the highest economic potential for gas-fired cogeneration in Brazil is found in industrial plants faced with high values of loss of load. In the commercial sector, measures reshaping the load curve of enterprises -- such as cold storage --- might be much more interesting than fired cogeneration. (Author)

  13. Greenhouse gas emission measurement and economic analysis of Iran natural gas fired power plants

    International Nuclear Information System (INIS)

    Shahsavari Alavijeh, H.; Kiyoumarsioskouei, A.; Asheri, M.H.; Naemi, S.; Shahsavari Alavije, H.; Basirat Tabrizi, H.

    2013-01-01

    This study attempts to examine the natural gas fired power plants in Iran. The required data from natural gas fired power plants were gathered during 2008. The characteristics of thirty two gas turbine power plants and twenty steam power plants have been measured. Their emission factor values were then compared with the standards of Energy Protection Agency, Euro Union and World Bank. Emission factors of gas turbine and steam power plants show that gas turbine power plants have a better performance than steam power plants. For economic analysis, fuel consumption and environmental damages caused by the emitted pollutants are considered as cost functions; and electricity sales revenue are taken as benefit functions. All of these functions have been obtained according to the capacity factor. Total revenue functions show that gas turbine and steam power plants are economically efficient at 98.15% and 90.89% of capacity factor, respectively; this indicates that long operating years of power plants leads to reduction of optimum capacity factor. The stated method could be implemented to assess the economic status of a country’s power plants where as efficient capacity factor close to one means that power plant works in much better condition. - Highlights: • CO 2 and NO x emissions of Iran natural gas fired power plants have been studied. • CO 2 and NO x emission factors are compared with EPA, EU and World Bank standards. • Costs and benefit as economic functions are obtained according to capacity factor. • Maximum economic profit is obtained for gas turbine and steam power plants. • Investment in CO 2 reduction is recommended instead of investment in NO x reduction

  14. Comparative funding consequences of large versus small gas-fired power generation units

    International Nuclear Information System (INIS)

    Johnson, N.G.

    1995-01-01

    Gas producers are increasingly looking to privately-owned gas-fired power generation as a major growth market to support the development of new fields being discovered across Australia. Gas-fired generating technology is more environmentally friendly than coal-fired power stations, has lower unit capital costs and has higher efficiency levels. With the recent downward trends in gas prices for power generation (especially in Western Australia) it is likely that gas will indeed be the consistently preferred fuel for generation in Australia. Gas producers should be sensitive to the different financial and risk characteristics of the potential market represented by large versus small gas-fired private power stations. These differences are exaggerated by the much sharper focus given by the private sector to quantify risk and to its allocation to the parties best able to manage it. The significant commercial differences between classes of generation projects result in gas producers themselves being exposed to diverging risk profiles through their gas supply contracts with generating companies. Selling gas to larger generation units results in gas suppliers accepting proportionately (i.e. not just prorata to the larger installed capacity) higher levels of financial risk. Risk arises from the higher probability of a project not being completed, from the increased size of penalty payments associated with non-delivery of gas and from the rising level of competition between gas suppliers. Gas producers must fully understand the economics and risks of their potential electricity customers and full financial analysis will materially help the gas supplier in subsequent commercial gas contract negotiations. (author). 1 photo

  15. Development and optimization of operational parameters of a gas-fired baking oven

    OpenAIRE

    Afolabi Tunde MORAKINYO; Babatunde OMIDIJI; Hakeem OWOLABI

    2017-01-01

    This study presented the development and optimization of operational parameters of an indigenous gas-fired bread-baking oven for small-scale entrepreneur. It is an insulated rectangular box-like chamber, made of galvanized-steel sheets and having a total dimension of 920mm×650mm×600mm. This oven consists of two baking compartments and three combustion chambers. The oven characteristics were evaluated in terms of the baking capacity, baking efficiency and weight loss of the baked bread. The ph...

  16. Seasonal performance and energy costs of oil or gas-fired boilers and furnaces

    Energy Technology Data Exchange (ETDEWEB)

    Berlad, A.L.; Lin, H.C.; Batey, J.; Salzano, F.J.; Yu, W.S.; Hoppe, R.J.; Allen, T.

    1977-03-01

    The seasonal operating cost of a small oil or gas-fired boiler or furnace depends upon the intrinsic merits of the device itself, the appropriateness of its capacity and cycle characteristics to the imposed load conditions, the weather characteristics and heat loss characteristics of the building being heated, and the control philosophy employed. The current study provides the bases for comparing quantitatively the seasonal operating costs of various specific space heating and/or domestic hot water systems, as influenced by the device specifics and device interaction with the space conditioned system that it serves. The resulting formalism is applied to various space-heating systems. Quantitative cost comparisons are presented.

  17. Capacity payment impact on gas-fired generation investments under rising renewable feed-in — A real options analysis

    International Nuclear Information System (INIS)

    Hach, Daniel; Spinler, Stefan

    2016-01-01

    We assess the effect of capacity payments on investments in gas-fired power plants in the presence of different degrees of renewable energy technology (RET) penetration. Low variable cost renewables increasingly make investments in gas-fired generation unprofitable. At the same time, growing feed-in from intermittent RETs amplifies fluctuations in power generation, thus entailing the need for flexible buffer capacity—currently mostly gas-fired power plants. A real options approach is applied to evaluate investment decisions and timing of a single investor in gas-fired power generation. We investigate the necessity and effectiveness of capacity payments. Our model incorporates multiple uncertainties and assesses the effect of capacity payments under different degrees of RET penetration. In a numerical study, we implement stochastic processes for peak-load electricity prices and natural gas prices. We find that capacity payments are an effective measure to promote new gas-fired generation projects. Especially in times of high renewable feed-in, capacity payments are required to incentivize peak-load investments. - Highlights: • We assess capacity payments under the specific focus of the influence of different degrees of renewable feed-in. • We use a real options approach to analyze investment decision and timing. • Our model reflects stochastic gas prices and stochastic electricity prices. • The case study shows the value of capacity payments to investors especially under high renewable feed-in.

  18. Economic potential of natural gas-fired cogeneration--analysis of Brazil's chemical industry

    International Nuclear Information System (INIS)

    Szklo, A.S.; Soares, J.B.; Tolmasquim, M.T.

    2004-01-01

    This paper attempts to estimate the technical and economic potential for natural gas-fired cogeneration (NGCHP) in Brazil's chemical industry as well as also analyses the impacts of specific incentive policies on the economic feasibility of this potential. Currently, the NGCHP installed capacity at Brazil's chemical industry is still quite a low figure, although the chemical plants are under heavy pressures to: (1) cut costs; and (2) show a rising awareness of the importance of power service quality, underscored even more heavily by Brazil's recent power crisis. According this study, a natural gas-fired remaining technical potential of 1.4 GW is noted in the Brazilian chemical industry. Financing policies showed to be the stand-alone policy that would be most successful for ensuring the economic feasibility of this technical potential. Nevertheless, this policy proved to be affected by the economic scenario under consideration, which includes world oil prices, electricity tariff and foreign exchange ratio possible paths. Consequently, the key issue is related to the ability to assess which economic scenario is rated as more probable by possible future investors in NGCHP, and then selecting the most appropriate incentive policy

  19. Development and optimization of operational parameters of a gas-fired baking oven

    Directory of Open Access Journals (Sweden)

    Afolabi Tunde MORAKINYO

    2017-12-01

    Full Text Available This study presented the development and optimization of operational parameters of an indigenous gas-fired bread-baking oven for small-scale entrepreneur. It is an insulated rectangular box-like chamber, made of galvanized-steel sheets and having a total dimension of 920mm×650mm×600mm. This oven consists of two baking compartments and three combustion chambers. The oven characteristics were evaluated in terms of the baking capacity, baking efficiency and weight loss of the baked bread. The physical properties of the baked breads were measured and analyzed using Duncan multiple range test of one way ANOVA at significant level of p<0.05. These properties were optimized to determine the optimum baking temperature using 3D surface response plot of Statistical Release 7. The baking capacity, baking efficiency, weight loss and optimum baking temperature were: 12.5 kg/hr, 87.8%, 12.5 g, 200-220oC, respectively. The physical properties of baked bread dough were found to correspond with the imported product (control sample. These results showed that, the developed gas-fired baking oven can be adopted for baking of bread at domestic and commercial levels.

  20. Comparison of inhalation risks : oil- versus gas-fired urban power plants

    International Nuclear Information System (INIS)

    Levin, L.

    2000-01-01

    The risks due to inhalation of emitted trace substances from natural gas-fired power plants tend to be significantly lower than those from oil- or coal-fired plants. A 1994 study suggested that the median inhalation life-time cancer risk from gas-fired plants was about 4 in one billion. This is an acceptable risk range according to the United States Environmental Protection Agency (US EPA) classification of risks. In the same study, median oil plant risks were 8 in one billion. coal plant median risks ranged from 2 to 3 in one billion depending on the grade of coal being burned. The US EPA classifies risks from 1 to one million to one to 10,000 as being in an acceptable risk range. In some cases, gas plants were shown to exhibit higher inhalation risks than oil plants due to terrain, air circulation patterns, enhanced stack or building downwash or mechanical turbulence. Higher concentrations of very potent trace substances could also result in high inhalation risks. An examination of several power plants in an urban area showed that initial judgements about risk can often be incorrect

  1. Using Probability of Exceedance to Compare the Resource Risk of Renewable and Gas-Fired Generation

    Energy Technology Data Exchange (ETDEWEB)

    Bolinger, Mark [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2017-08-01

    Of the myriad risks surrounding long-term investments in power plants, resource risk is one of the most difficult to mitigate, and is also perhaps the risk that most-clearly distinguishes renewable generation from natural gas-fired generation. For renewable generators like wind and solar projects, resource risk manifests as a quantity risk—i.e., the risk that the quantity of wind and insolation will be less than expected.i For gas-fired generators (i.e., a combined-cycle gas turbine or “CCGT”), resource risk manifests primarily as a price risk—i.e., the risk that natural gas will cost more than expected. Most often, resource risk—and natural gas price risk in particular—falls disproportionately on utility ratepayers, who are typically not well-equipped to manage this risk. As such, it is incumbent upon utilities, regulators, and policymakers to ensure that resource risk is taken into consideration when making or approving resource decisions, or enacting policies that influence the development of the electricity sector more broadly.

  2. Thermodynamic performance analysis of gas-fired air-cooled adiabatic absorption refrigeration systems

    International Nuclear Information System (INIS)

    Wang, L.; Chen, G.M.; Wang, Q.; Zhong, M.

    2007-01-01

    In China, the application of small size gas-fired air-cooled absorption refrigeration systems as an alternative for electric compression air conditioning systems has shown broad prospects due to occurrence of electricity peak demand in Chinese big cities and lack of water resources. However, for conventional air-cooled absorption refrigeration systems, it is difficult to enhance the heat and mass transfer process in the falling film absorber, and may cause problems, for example, remarkable increase of pressure, temperature and concentration in the generators, risk of crystallization, acceleration of corrosion, degradation of performance, and so on. This paper presents a gas-fired air-cooled adiabatic absorption refrigeration system using lithium bromide-water solutions as its working fluid, which is designed with a cooling capacity of 16 kW under standard conditions. The system has two new features of waste heat recovery of condensed water from generator and an adiabatic absorber with an air cooler. Performance simulation and characteristic analysis are crucial for the optimal control and reliability of operation in extremely hot climates. A methodology is presented to simulate thermodynamic performance of the system. The influences of outdoor air temperature on operation performances of the system are investigated

  3. Emission characteristics and axial flame temperature distribution of producer gas fired premixed burner

    Energy Technology Data Exchange (ETDEWEB)

    Bhoi, P.R. [Department of Mechanical Engineering, L and T-Sargent and Lundy Limited, L and T Energy Centre, Near Chhani Jakat Naka, Baroda 390 002 (India); Channiwala, S.A. [Department of Mechanical Engineering, Sardar Vallabhbhai National Institute of Technology, Deemed University, Ichchhanath, Surat 395 007, Gujarat (India)

    2009-03-15

    This paper presents the emission characteristics and axial flame temperature distribution of producer gas fired premixed burner. The producer gas fired premixed burner of 150 kW capacity was tested on open core throat less down draft gasifier system in the present study. A stable and uniform flame was observed with this burner. An instrumented test set up was developed to evaluate the performance of the burner. The conventional bluff body having blockage ratio of 0.65 was used for flame stabilization. With respect to maximum flame temperature, minimum pressure drop and minimum emissions, a swirl angle of 60 seems to be optimal. The experimental results also showed that the NO{sub x} emissions are inversely proportional to swirl angle and CO emissions are independent of swirl angle. The minimum emission levels of CO and NO{sub x} are observed to be 0.167% and 384 ppm respectively at the swirl angle of 45-60 . The experimental results showed that the maximum axial flame temperature distribution was achieved at A/F ratio of 1.0. The adiabatic flame temperature of 1653 C was calculated theoretically at A/F ratio of 1.0. Experimental results are in tune with theoretical results. It was also concluded that the CO and UHC emissions decreases with increasing A/F ratio while NO{sub x} emissions decreases on either side of A/F ratio of 1.0. (author)

  4. Historical and future emission of hazardous air pollutants (HAPs) from gas-fired combustion in Beijing, China.

    Science.gov (United States)

    Xue, Yifeng; Nie, Lei; Zhou, Zhen; Tian, Hezhong; Yan, Jing; Wu, Xiaoqing; Cheng, Linglong

    2017-07-01

    The consumption of natural gas in Beijing has increased in the past decade due to energy structure adjustments and air pollution abatement. In this study, an integrated emission inventory of hazardous air pollutants (HAPs) emitted from gas-fired combustion in Beijing was developed for the period from 2000 to 2014 using a technology-based approach. Future emission trends were projected through 2030 based on current energy-related and emission control policies. We found that emissions of primary HAPs exhibited an increasing trend with the rapid increase in natural gas consumption. Our estimates indicated that the total emissions of NO X , particulate matter (PM) 10 , PM 2.5 , CO, VOCs, SO 2 , black carbon, Pb, Cd, Hg, As, Cr, Cu, Ni, Zn, polychlorinated dibenzo-p-dioxins and dibenzofurans, and benzo[a]pyrene from gas-fired combustion in Beijing were approximately 22,422 t, 1042 t, 781 t, 19,097 t, 653 t, 82 t, 19 t, 0.6 kg, 0.1 kg, 43 kg, 52 kg, 0.3 kg, 0.03 kg, 4.3 kg, 0.6 kg, 216 μg, and 242 g, respectively, in 2014. To mitigate the associated air pollution and health risks caused by gas-fired combustion, stricter emission standards must be established. Additionally, combustion optimization and flue gas purification system could be used for lowering NO X emissions from gas-fired combustion, and gas-fired facilities should be continuously monitored based on emission limits. Graphical abstract Spatial distribution and typical live photos of gas-fired boiler in Beijing.

  5. Laboratory and gas-fired furnace performance tests of epoxy primers for intumescent coatings

    DEFF Research Database (Denmark)

    Nørgaard, Kristian Petersen; Dam-Johansen, Kim; Catala, Pere

    2014-01-01

    , either to ensure adhesion of the intumescent coating to the steel or to provide corrosion resistance. It is essential to document the performance of the intumescent coating together with the primer to ensure the overall quality of coating system. In the present work, two epoxy primers were used...... to a gas-fired furnace following the ISO834 fire curve (a so-called cellulosic fire), one of the primers selected performed well and the other poorly. From tests in the electrically heated oven, it was found that both primers were sensitive to the film thickness employed and the presence of oxygen....... At oxygen-rich conditions, higher primer thicknesses gave weaker performance. In addition, a color change from red to black was observed in nitrogen, while the color remained red in the oxygen-nitrogen mixture. In summary, the results suggest that an adequate choice of primer, primer thickness...

  6. Control systems for condensing flue-gas coolers related to natural-gas-fired heating plants

    International Nuclear Information System (INIS)

    Krighaar, M.; Paulsen, O.

    1992-01-01

    A theoretical study is made of the enthalpy-efficiency for a water-cooled heat exchanger added to a natural gas-fired boiler. Under varying conditions of both water flow and temperature and flue-gas flow and temperature, both in condensing and non-condensing mode, the efficiency seems to be constant. The result is very useful for comparison between two different working conditions. The efficiency is used to calculate the savings achieved for a district heating plant by using a heat exchanger. The energy economic calculations are also helpful for estimating the most appropriate size of heat exchanger. The annual savings are calculated by means of data regarding heat production, flue gas temperature and water return temperature. The savings achieved by using different connection principles such as bypass, reheating and controlled water temperature are also calculated. (author)

  7. DEVELOPMENT OF FINE PARTICULATE EMISSION FACTORS AND SPECIATION PROFILES FOR OIL AND GAS FIRED COMBUSTION SYSTEMS

    Energy Technology Data Exchange (ETDEWEB)

    Glenn England; Oliver Chang; Stephanie Wien

    2002-02-14

    This report provides results from the second year of this three-year project to develop dilution measurement technology for characterizing PM2.5 (particles with aerodynamic diameter smaller than 2.5 micrometers) and precursor emissions from stationary combustion sources used in oil, gas and power generation operation. Detailed emission rate and chemical speciation tests results for a gas turbine, a process heater, and a commercial oil/gas fired boiler are presented. Tests were performed using a research dilution sampling apparatus and traditional EPA methods. A series of pilot tests were conducted to identify the constraints to reduce the size of current research dilution sampler for future stack emission tests. Based on the test results, a bench prototype compact dilution sampler developed and characterized in GE EER in August 2002.

  8. Air quality impacts of projections of natural gas-fired distributed generation

    Science.gov (United States)

    Horne, Jeremy R.; Carreras-Sospedra, Marc; Dabdub, Donald; Lemar, Paul; Nopmongcol, Uarporn; Shah, Tejas; Yarwood, Greg; Young, David; Shaw, Stephanie L.; Knipping, Eladio M.

    2017-11-01

    This study assesses the potential impacts on emissions and air quality from the increased adoption of natural gas-fired distributed generation of electricity (DG), including displacement of power from central power generation, in the contiguous United States. The study includes four major tasks: (1) modeling of distributed generation market penetration; (2) modeling of central power generation systems; (3) modeling of spatially and temporally resolved emissions; and (4) photochemical grid modeling to evaluate the potential air quality impacts of increased DG penetration, which includes both power-only DG and combined heat and power (CHP) units, for 2030. Low and high DG penetration scenarios estimate the largest penetration of future DG units in three regions - New England, New York, and California. Projections of DG penetration in the contiguous United States estimate 6.3 GW and 24 GW of market adoption in 2030 for the low DG penetration and high DG penetration scenarios, respectively. High DG penetration (all of which is natural gas-fired) serves to offset 8 GW of new natural gas combined cycle (NGCC) units, and 19 GW of solar photovoltaic (PV) installations by 2030. In all scenarios, air quality in the central United States and the northwest remains unaffected as there is little to no DG penetration in those states. California and several states in the northeast are the most impacted by emissions from DG units. Peak increases in maximum daily 8-h average ozone concentrations exceed 5 ppb, which may impede attainment of ambient air quality standards. Overall, air quality impacts from DG vary greatly based on meteorological conditions, proximity to emissions sources, the number and type of DG installations, and the emissions factors used for DG units.

  9. Final Report: Laboratory Development of a High Capacity Gas-Fired Paper Dryer

    Energy Technology Data Exchange (ETDEWEB)

    Yaroslav Chudnovsky; Aleksandr Kozlov; Lester Sherrow

    2005-09-30

    Paper drying is the most energy-intensive and temperature-critical aspect of papermaking. It is estimated that about 67% of the total energy required in papermaking is used to dry paper. The conventional drying method uses a series of steam-heated metal cylinders that are required to meet ASME codes for pressure vessels, which limits the steam pressure to about 160 psig. Consequently, the shell temperature and the drying capacity are also limited. Gas Technology Institute together with Boise Paper Solutions, Groupe Laperrier and Verreault (GL&V) USA Inc., Flynn Burner Corporation and with funding support from the U.S. Department of Energy, U.S. natural gas industry, and Gas Research Institute is developing a high efficiency gas-fired paper dryer based on a combination of a ribbon burner and advanced heat transfer enhancement technique. The Gas-Fired Paper Dryer (GFPD) is a high-efficiency alternative to conventional steam-heated drying drums that typically operate at surface temperatures in the 300 deg F range. The new approach was evaluated in laboratory and pilot-scale testing at the Western Michigan University Paper Pilot Plant. Drum surface temperatures of more than 400 deg F were reached with linerboard (basis weight 126 lb/3000 ft2) production and resulted in a 4-5 times increase in drying rate over a conventional steam-heated drying drum. Successful GFPD development and commercialization will provide large energy savings to the paper industry and increase paper production rates from dryer-limited (space- or steam-limited) paper machines by an estimated 10 to 20%, resulting in significant capital costs savings for both retrofits and new capacity.

  10. Laboratory Development of A High Capacity Gas-Fired paper Dryer

    Energy Technology Data Exchange (ETDEWEB)

    Chudnovsky, Yaroslav [Gas Technology Institute, Des Plaines, IL (United States); Kozlov, Aleksandr [Gas Technology Institute, Des Plaines, IL (United States); Sherrow, Lester [Gas Technology Institute, Des Plaines, IL (United States)

    2005-09-30

    Paper drying is the most energy-intensive and temperature-critical aspect of papermaking. It is estimated that about 67% of the total energy required in papermaking is used to dry paper. The conventional drying method uses a series of steam-heated metal cylinders that are required to meet ASME codes for pressure vessels, which limits the steam pressure to about 160 psig. Consequently, the shell temperature and the drying capacity are also limited. Gas Technology Institute together with Boise Paper Solutions, Groupe Laparrier and Verreault (GL&V) USA Inc., Flynn Burner Corporation and with funding support from the U.S. Department of Energy, U.S. natural gas industry, and Gas Research Institute is developing a high efficiency gas-fired paper dryer based on a combination of a ribbon burner and advanced heat transfer enhancement technique. The Gas-Fired Paper Dryer (GFPD) is a high-efficiency alternative to conventional steam-heated drying drums that typically operate at surface temperatures in the 300ºF range. The new approach was evaluated in laboratory and pilot-scale testing at the Western Michigan University Paper Pilot Plant. Drum surface temperatures of more than 400ºF were reached with linerboard (basis weight 126 lb/3000 ft2) production and resulted in a 4-5 times increase in drying rate over a conventional steam-heated drying drum. Successful GFPD development and commercialization will provide large energy savings to the paper industry and increase paper production rates from dryer-limited (space- or steam-limited) paper machines by an estimated 10 to 20%, resulting in significant capital costs savings for both retrofits and new capacity.

  11. Natural gas-fired kitchen of a caterer in Veghel, Netherlands; Cateraar in Veghel gebruikt fonkelnieuwe grootkeuken op aardgas

    Energy Technology Data Exchange (ETDEWEB)

    Havinga, J. [ed.

    1995-06-01

    A new kitchen for a catering firm in Veghel, Netherlands, has been build. The gas utility Obragas, Gasunie and the engineering office Van Heugten advised the catering company on the choice for new kitchen equipment. The cooperation resulted in a head kitchen, laundry and a washing-up kitchen, mainly gas-fired. 6 ills.

  12. Hazardous air pollutant emissions from gas-fired combustion sources: emissions and the effects of design and fuel type

    Energy Technology Data Exchange (ETDEWEB)

    England, G.C.; McGrath, T.P. [GE-Energy and Environmental Research Corp., Irvine, CA (United States); Gilmer, L. [Equilon Enterprises, Bellaire, TX (United States); Seebold, J.G. [Chevron Research and Technology Co., Richmond, CA (United States); Lev-On, M. [ARCO, Los Angeles, CA (United States); Hunt, T. [American Petroleum Institute, Washington, DC (United States)

    2001-07-01

    Air emissions from gas-fired combustion devices such as boilers, process heaters, gas turbines and stationary reciprocating engines contain hazardous air pollutants (HAPs) subjected to consideration under the federal clean air act (CAA). This work presents a recently completed major research project to develop an understanding of HAP emissions from gas-fired boilers and process heaters and new HAP emission factors based on field emission tests of gas-fired external combustion devices used in the petroleum industry. The effect of combustion system design and operating parameters on HAP emissions determined by both field and research tests are discussed. Data from field tests of gas-fired petroleum industry boilers and heaters generally show very low emission levels of organic HAPs. A comparison of the emission data for boilers and process heaters, including units with and without various forms of NO{sub x} emission controls, showed no significant difference in organic HAP emission characteristics due to process or burner design. This conclusion is also supported by the results of research tests with different burner designs. Based on field tests of units fired with natural gas and various petroleum industry process gases and research tests in which gas composition was intentionally varied, organic HAP emissions were not determined to be significantly affected by the gas composition. Research data indicate that elevated organic HAP emission levels are found only under extreme operating conditions (starved air or high excess air combustion) associated with poor combustion. (author)

  13. Accounting for fuel price risk when comparing renewable to gas-fired generation: the role of forward natural gas prices

    International Nuclear Information System (INIS)

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2006-01-01

    Unlike natural gas-fired generation, renewable generation (e.g., from wind, solar, and geothermal power) is largely immune to fuel price risk. If ratepayers are rational and value long-term price stability, then-contrary to common practice-any comparison of the levelized cost of renewable to gas-fired generation should be based on a hedged gas price input, rather than an uncertain gas price forecast. This paper compares natural gas prices that can be locked in through futures, swaps, and physical supply contracts to contemporaneous long-term forecasts of spot gas prices. We find that from 2000 to 2003, forward gas prices for terms of 2-10 years have been considerably higher than most contemporaneous long-term gas price forecasts. This difference is striking, and implies that comparisons between renewable and gas-fired generation based on these forecasts over this period have arguably yielded results that are biased in favor of gas-fired generation

  14. Hazardous air pollutant emissions from gas-fired combustion sources: emissions and the effects of design and fuel type

    International Nuclear Information System (INIS)

    England, G.C.; McGrath, T.P.; Gilmer, L.; Seebold, J.G.; Lev-On, M.; Hunt, T.

    2001-01-01

    Air emissions from gas-fired combustion devices such as boilers, process heaters, gas turbines and stationary reciprocating engines contain hazardous air pollutants (HAPs) subjected to consideration under the federal clean air act (CAA). This work presents a recently completed major research project to develop an understanding of HAP emissions from gas-fired boilers and process heaters and new HAP emission factors based on field emission tests of gas-fired external combustion devices used in the petroleum industry. The effect of combustion system design and operating parameters on HAP emissions determined by both field and research tests are discussed. Data from field tests of gas-fired petroleum industry boilers and heaters generally show very low emission levels of organic HAPs. A comparison of the emission data for boilers and process heaters, including units with and without various forms of NO x emission controls, showed no significant difference in organic HAP emission characteristics due to process or burner design. This conclusion is also supported by the results of research tests with different burner designs. Based on field tests of units fired with natural gas and various petroleum industry process gases and research tests in which gas composition was intentionally varied, organic HAP emissions were not determined to be significantly affected by the gas composition. Research data indicate that elevated organic HAP emission levels are found only under extreme operating conditions (starved air or high excess air combustion) associated with poor combustion. (author)

  15. Environmental optimisation of natural gas fired engines - calculation of health externalities

    Energy Technology Data Exchange (ETDEWEB)

    Frohn, L.M.; Becker, T.; Christensen, Jesper; Hertel, O.; Silver, J.D.; Villadsen, H. (Aarhus Univ., National Environmental Research Institute, Dept. of Atmospheric Environment, Roskilde (Denmark)); Soees Hansen, M. (Aarhus Univ., National Environmental Research Institute, Dept. of Policy Analysis, Roskilde (Denmark)); Skou Andersen, M. (European Environment Agency, Copenhagen (Denmark))

    2010-07-01

    The measured emissions of WP1 of the project has been applied as input for model calculations with the EVA model system. The DEHM model which calculates the regional scale delta-concentrations has been further developed to handle the low signal to noise ratio of the delta-concentrations related to the small sources that the gas fired engines constitute. All combinations of engine settings and locations have been run as scenarios with the EVA system, however the results have been grouped into themes to investigate changes related to location as well as changes related to engine settings. New exposure-response relations have been implemented in the system related to the chemical components nitrogen dioxide, formaldehyde, ethene and propene. The choice of high-exposure location in the calculations has unfortunately turned out to be less optimal. The location at Store Valby has previously been applied in studies with the EVA system as a high-exposure site, however in previous applications, the emission sources have been large power plants with stack heights of around 150 meters. The height of the stack of the gas fired engines is only around 30 meters, and the consequence is that the emitted components reach the surface closer to the stack, thereby giving high exposure in an area located further to the southwest, where the population density is not as high as in central Copenhagen. In general the marginal health costs (in Euro pr kg) of carbon monoxide and formaldehyde emissions are very small. The emissions of formaldehyde are also small and the resulting costs for this component is therefore very small. The emission of carbon monoxide is much larger, however the small marginal cost makes the contribution to the total costs small, also for this component. The marginal health costs of nitrogen oxides and ethene emissions show little variation with engine scenario. However the general picture is that as the NO{sub x} emissions increase (either by increasing ignition

  16. Apples with apples: accounting for fuel price risk in comparisons of gas-fired and renewable generation

    Energy Technology Data Exchange (ETDEWEB)

    Bolinger, Mark; Wiser, Ryan

    2003-12-18

    For better or worse, natural gas has become the fuel of choice for new power plants being built across the United States. According to the US Energy Information Administration (EIA), natural gas combined-cycle and combustion turbine power plants accounted for 96% of the total generating capacity added in the US between 1999 and 2002--138 GW out of a total of 144 GW. Looking ahead, the EIA expects that gas-fired technology will account for 61% of the 355 GW new generating capacity projected to come on-line in the US up to 2025, increasing the nationwide market share of gas-fired generation from 18% in 2002 to 22% in 2025. While the data are specific to the US, natural gas-fired generation is making similar advances in other countries as well. Regardless of the explanation for (or interpretation of) the empirical findings, however, the basic implications remain the same: one should not blindly rely on gas price forecasts when comparing fixed-price renewable with variable-price gas-fired generation contracts. If there is a cost to hedging, gas price forecasts do not capture and account for it. Alternatively, if the forecasts are at risk of being biased or out of tune with the market, then one certainly would not want to use them as the basis for resource comparisons or investment decisions if a more certain source of data (forwards) existed. Accordingly, assuming that long-term price stability is valued, the most appropriate way to compare the levelized cost of these resources in both cases would be to use forward natural gas price data--i.e. prices that can be locked in to create price certainty--as opposed to uncertain natural gas price forecasts. This article suggests that had utilities and analysts in the US done so over the sample period from November 2000 to November 2003, they would have found gas-fired generation to be at least 0.3-0.6 cents/kWh more expensive (on a levelized cost basis) than otherwise thought. With some renewable resources, in particular wind

  17. PM1 particles at coal- and gas-fired power plant work areas.

    Science.gov (United States)

    Hicks, Jeffrey B; McCarthy, Sheila A; Mezei, Gabor; Sayes, Christie M

    2012-03-01

    With the increased interest in the possible adverse health effects attributed to inhalation of fine particle matter, this study was conducted to gather preliminary information about workplace exposures at coal- and gas-fired power plants to fine particles (PM(1); i.e. <1 μm) and ultrafine particles (i.e. <0.1 μm). Combustion of fossil fuel is known to produce fine particles, and due to their proximity and durations of exposure, power plant workers could be a group of individuals who experience high chronic exposures to these types of particles. The results of a series of real-time instrument measurements showed that concentrations of PM(1) were elevated in some locations in power plants. The highest concentrations were in locations near combustion sources, indicating that combustion materials were leaking from conventional fossil fuel-fired boilers or it was associated with emission plume downwash. Concentrations were the lowest inside air-conditioned control rooms where PM(1) were present at levels similar to or lower than upwind concentrations. Microscopic examinations indicate that PM(1) at the coal-fired plants are dominated by vitrified spheres, although there were also unusual elongated particles. Most of the PM(1) were attached to larger coal fly ash particles that may affect where and how they could be deposited in the lung.

  18. NORM emissions from heavy oil and natural gas fired power plants in Syria

    International Nuclear Information System (INIS)

    Al-Masri, M.S.; Haddad, Kh.

    2012-01-01

    Naturally occurring radioactive materials (NORM) have been determined in fly and bottom ash collected from four major Syrian power plants fired by heavy oil and natural gas. 210 Pb and 210 Po were the main NORM radionuclides detected in the fly and bottom ash. 210 Pb activity concentrations have reached 3393 ± 10 Bq kg −1 and 4023 ± 7 Bq kg −1 in fly ash and bottom ash, respectively; lower values of 210 Po were observed due to its high volatility. In addition, 210 Po and 210 Pb annual emissions in bottom ash from mixed (heavy oil and natural gas) fired power plants varied between 2.7 × 10 9 –7.95 × 10 9 Bq and 3.5 × 10 9 –10 10 Bq, respectively; higher emissions of 210 Po and 210 Pb from gas power plants being observed. However, the present study showed that 210 Po and 210 Pb emissions from thermal power plants fired by natural gas are much higher than the coal power plants operated in the World. - Highlights: ► NORM have been determined in fly and bottom ash collected from Syrian power plants fired by heavy oil and natural gas. ► 210 Pb and 210 Po were the main NORM radionuclides detected in the fly and bottom ash. ► 210 Po and 210 Pb annual emissions from these power plants were estimated.

  19. Analysis of directional radiative behavior and heating efficiency for a gas-fired radiant burner

    International Nuclear Information System (INIS)

    Li, B.X.; Lu, Y.P.; Liu, L.H.; Kudo, K.; Tan, H.P.

    2005-01-01

    For the purpose of energy conservation and uniform heating of object surface, a gas-fired porous radiant burner with a bundle of reflecting tubes is developed. A physical model is developed to simulate the directional radiative behavior of this heating device, in which the Monte Carlo method based on the concept of radiation distribution factor is used to compute the directional radiative behavior. The effects of relating parameters on the directional behavior of radiative heating and the heating efficiency are analyzed. With the increase of the length-to-radius ratio of tube, the radiation heating efficiency decreases, but the radiation energy incident on the object surface is more collimated. The radiation heating efficiency increases with the specular reflectivity. With the increase in length of tube segment with specular reflective surface, the radiation heating efficiency increases, but the extent of concentration and collimation of radiative energy decreases. For real design of the heating device, some trade-offs are needed to balance the radiation heating efficiency and the uniformity of radiative heating of object surface

  20. Simultaneous reduction of NO2 and CO in a domestic unvented gas-fired convective heater

    International Nuclear Information System (INIS)

    Arai, N.; Kasugai, N. A.; Hasatani, M.; Ishibashi, N.

    1989-01-01

    A programme of industrial and university research has been carried out to develop a domestic, unvented gas-fired space-heater capable of the simultaneous reduction of NO 2 and CO. To this end, lean-burning convective heaters of two types have been devised, and their performance has been characterised on methane-air mixtures. One burner contains a vertical cylinder of stainless-steel wire mesh (Type A), and the other incorporates a heat-recirculating matrix and a horizontal plate of stainless-steel wire mesh (Type B). The results obtained under a wide range of equivalence ratios show that: - the emission characteristics for NO x and NO 2 in Type A were excellent over the entire equivalence ratio of 0.5 - 1.0, but the concentration of CO was always higher than the current informal guideline in Japan, in which CO/CO 2 -3 . - Type B displayed an optimum range of equivalence ratios to satisfy simultaneously every guideline for NO x ( 2 ( 2 . However, since the optimum range of equivalence ratio was limited to between 0.45 and 0.55, further effort should be devoted to the extension of this optimum range. (Author)

  1. Gas-fired cogeneration and cooling: new study identifies major benefits

    International Nuclear Information System (INIS)

    Watt, G.

    2001-01-01

    A research paper- 'Gas Fired Cogeneration and Cooling: Markets, Technologies and Greenhouse Gas Savings'- launched at last month's Australian Gas Association 2001 Convention, reveals that gas cooling could replace 25 PJ of electricity summer demand, and reduce greenhouse gas emissions by 58 percent compared with electrical technologies. Commissioned by the AGA's Gas Cooling Task Force and supported by the Sustainable Energy Authority of Victoria and the Sustainable Energy Development Authority of NSW, the study examined market opportunities and environmental outcomes for the combined gas cogeneration and cooling technologies. It shows that the penetration of gas into the distributed cooling and power generation market is being driven by the following developments: the uncertainty and volatility of electricity costs, particularly during summer, electricity market structural changes which encourage distributed generation, high and uncertain world oil prices, the relative stability of Australian gas prices, the encouragement of demand and energy management strategies by regulators, greenhouse gas emission reduction policies, indoor air quality issues, product and productivity improvements in industry and CFC phase-out opportunities

  2. The development of an ultra-low-emission gas-fired cyclonic combustor

    International Nuclear Information System (INIS)

    Xiong, Tian-yu; Khinkis, M.J.; Coppin, W.P.

    1991-01-01

    A gas-fired cyclonic combustor has been developed for relatively low-temperature direct-air heating applications that require ultra-low pollutant emissions. High-lean premixed combustion with a flame stabilizer is adopted to achieve ultra-low emissions and high turndown operation. On the basis of analytical studies and cold modeling, a 350-kW test combustor was designed and successfully tested. Experimental results obtained using natural gas and ambient air demonstrated that the test combustor can operate steadily at high excess air up to 80% to 100% over a large turndown range up to 40:1. At design operating conditions, NO x emissions as low as 0.6 vppm and CO and total hydrocarbon (THC) emissions below 3 vppm were achieved. Over the full operating range, NO x emissions from 0.3 to 1.0 vppm and CO and THC emissions below 4 vppm were demonstrated. In all tests, concentrations of NO 2 were less than 40% of the total NO x emissions -- lower than the level of NO 2 emissions from combustion processes required for good indoor air quality (0.5 vppm). This paper presents the concept of high-lean premixed ultra-low-emission cyclonic combustion, design specifications for the combustion system, and the major experimental results, including flame stability, emissions, and turndown performance. 13 refs., 12 figs., 1 tab

  3. Evaluation of retrofitting gas-fired cooling and heating systems into BCHP using design optimization

    International Nuclear Information System (INIS)

    Cao Jiacong

    2009-01-01

    The influence of energy prices on the feasibility of a retrofit is investigated. The retrofit describes the conversion of a system from HVAC to BCHP for energy-saving. This includes two optimal retrofit design models, of which the exergetic efficiency and annual costs (AC) are the separate objective functions. The retrofit scheme is planned to insert gas engines as prime movers into the original system, which have adopted gas-fired absorption chillers. The solutions of the optimizations show that such a retrofit can result in a remarkable rise in exergetic efficiency but is not viable with current energy prices. The contradictory solutions reveal a gap between the current energy prices system of the country and the present energy situation. Further investigation gives the critical lines of which each divides the coordinate plane of natural gas-electric prices into two parts of benefit and deficit. If the electric price rises to a certain extent, the retrofit will be advantageous both in benefit and energy-saving. So it is really an urgent task to reform the energy prices system in China. Conclusions may be helpful for other similar retrofit projects, and for legislators and the government which are responsible for improving the energy market in China.

  4. Environmental optimisation of natural gas fired engines. Measurement on four different engines. Project report

    Energy Technology Data Exchange (ETDEWEB)

    Kvist, T.

    2010-10-15

    The emissions of NO{sub x}, CO and UHC as well as the composition of the hydrocarbon emissions were measured for four different stationary lean burn natural gas fired engines installed at different combined heat and power (CHP) units in Denmark. The units have been chosen to be representative for the natural gas engine based on power production in Denmark. The NO{sub x} emissions were varied from around 200 to 500 mg/m3(n) by varying the ignition timing and the excess of air. For each of the examined engines measurements were conducted at different combinations of ignition timing and excess of air. The measurements showed the NO{sub x} emissions were relatively more sensitive to engine setting than UHC, CO and formaldehyde emissions. By reducing the NO{sub x} emissions to 40 % of the initial value (from 500 to 200 mg/m3(n)) the UHC emission were increased by 10 % to 50 % of the initial value. The electrical efficiency was reduced by 0,5 to 1,0 % point. (Author)

  5. Gas-fired power plants: Investment timing, operating flexibility and CO2 capture

    International Nuclear Information System (INIS)

    Fleten, Stein-Erik; Naesaekkaelae, Erkka

    2010-01-01

    We analyze investments in gas-fired power plants based on stochastic electricity and natural gas prices. A simple but realistic two-factor model is used for price processes, enabling analysis of the value of operating flexibility, the opportunity to abandon the capital equipment, as well as finding thresholds for energy prices for which it is optimal to enter into the investment. We develop a method to compute upper and lower bounds on plant values and investment threshold levels. Our case study uses representative power plant investment and operations data, and historical forward prices from well-functioning energy markets. We find that when the decision to build is considered, the abandonment option does not have significant value, whereas the operating flexibility and time-to-build option have significant effect on the building threshold. Furthermore, the joint value of the operating flexibility and the abandonment option is much smaller than the sum of their separate values, because both are options to shut down. The effects of emission costs on the value of installing CO 2 capture technology are also analyzed.

  6. Failure Analysis and Magnetic Evaluation of Tertiary Superheater Tube Used in Gas-Fired Boiler

    Science.gov (United States)

    Mohapatra, J. N.; Patil, Sujay; Sah, Rameshwar; Krishna, P. C.; Eswarappa, B.

    2018-02-01

    Failure analysis was carried out on a prematurely failed tertiary superheater tube used in gas-fired boiler. The analysis includes a comparative study of visual examination, chemical composition, hardness and microstructure at failed region, adjacent and far to failure as well as on fresh tube. The chemistry was found matching to the standard specification, whereas the hardness was low in failed tube compared to the fish mouth opening region and the fresh tube. Microscopic examination of failed sample revealed the presence of spheroidal carbides of Cr and Mo predominantly along the grain boundaries. The primary cause of failure is found to be localized heating. Magnetic hysteresis loop (MHL) measurements were carried out to correlate the magnetic parameters with microstructure and mechanical properties to establish a possible non-destructive evaluation (NDE) for health monitoring of the tubes. The coercivity of the MHL showed a very good correlation with microstructure and mechanical properties deterioration enabling a possible NDE technique for the health monitoring of the tubes.

  7. Gas fired combined cycle plant in Singapore: energy use, GWP and cost-a life cycle approach

    International Nuclear Information System (INIS)

    Kannan, R.; Leong, K.C.; Osman, Ramli; Ho, H.K.; Tso, C.P.

    2005-01-01

    A life cycle assessment was performed to quantify the non-renewable (fossil) energy use and global warming potential (GWP) in electricity generation from a typical gas fired combined cycle power plant in Singapore. The cost of electricity generation was estimated using a life cycle cost analysis (LCCA) tool. The life cycle assessment (LCA) of a 367.5 MW gas fired combined cycle power plant operating in Singapore revealed that hidden processes consume about 8% additional energy in addition to the fuel embedded energy, and the hidden GWP is about 18%. The natural gas consumed during the operational phase accounted for 82% of the life cycle cost of electricity generation. An empirical relation between plant efficiency and life cycle energy use and GWP in addition to a scenario for electricity cost with varying gas prices and plant efficiency have been established

  8. Element composition of solid airborne particles deposited in snow in the vicinity of gas-fired heating plant

    OpenAIRE

    Talovskaya, Anna Valerievna; Yazikov, Yegor (Egor) Grigoryevich; Filimonenko, Ekaterina Anatolievna; Samokhina, Nataljya Pavlovna; Shakhova, Tatiana Sergeevna; Parygina, Irina Alekseevna

    2016-01-01

    Local heating plants are the main pollution source of rural areas. Currently, there are few studies on the composition of local heating plants emissions. The article deals with the research results of air pollution level with solid airborne particles in the vicinity of local gas-fired heating plants of some districts of Tomsk region. The snow sampling was conducted for the purpose of solid airborne particles extraction from snow cover. The content of 28 chemical elements (heavy metals, rare e...

  9. Emission Characteristics of Gas-Fired Boilers based on Category-Specific Emission Factor from Field Measurements in Beijing, China

    Science.gov (United States)

    Itahashi, S.; Yan, X.; Song, G.; Yan, J.; Xue, Y.

    2017-12-01

    Gas-fired boilers will become the main stationary sources of NOx in Beijing. However, the knowledge of gas-fired boilers in Beijing is limited. In the present study, the emission characteristics of NOx, SO2, and CO from gas-fired boilers in Beijing were established using category-specific emission factors (EFs) from field measurements. In order to obtain category-specific EFs, boilers were classified through influence analysis. Factors such as combustion mode, boiler type, and installed capacity were considered critical for establishing EFs because they play significant roles in pollutant formation. The EFs for NOx, CO, and SO2 ranged from 1.42-6.86 g m-3, 0.05-0.67 g m-3 and 0.03-0.48 g m-3. The emissions of NOx, SO2, and CO for gas-fired boilers in Beijing were 11121 t, 468 t, and 222 t in 2014, respectively. The emissions were spatially allocated into grid cells with a resolution of 1 km × 1 km, and the results indicated that top emitters were in central Beijing. The uncertainties were quantified using a Monte Carlo simulation. The results indicated high uncertainties in CO (-157% to 154%) and SO2 (-127% to 182%) emissions, and relatively low uncertainties (-34% to 34%) in NOx emission. Furthermore, approximately 61.2% and 96.8% of the monitored chamber combustion boilers (CCBs) met the standard limits for NOx and SO2, respectively. Concerning NOx, low-NOx burners and NOx emission control measures are urgently needed for implementing of stricter standards. Adopting terminal control measures is unnecessary for SO2, although its concentration occasionally exceeds standard limits, because reduction of its concentration can be achieved thorough control of the sulfur content of natural gas at a stable low level. Furthermore, the atmospheric combustion boilers (ACBs) should be substituted with CCBs, because ACBs have a higher emission despite lower gross installed capacity. The results of this study will enable in understanding and controlling emissions from gas-fired

  10. A policy study examining the use of imported LNG for gas-fired power generation on the southeast coast of China

    International Nuclear Information System (INIS)

    Li Yajun; Bai Fangfang

    2010-01-01

    Since China's energy demand is growing quickly, speeding up the development of natural gas is an important substitute and supplement for coal and oil. The development of the natural gas market in many developing countries has demonstrated that the success of the whole project hinges upon the success of gas-fired power generation. However, under the current energy pricing system in China, the advantages of gas-fired power plants, such as low investment costs and high efficiency, have not been able to offset the low price of coal. The gas-fired power plants, both at downstream of the Liquefied Natural Gas (LNG) industry and upstream of the power sector, are faced with a dilemma. In order to solve the problems facing gas-fired power projects while providing policy guidance for the future development of gas-fired power projects, the policy of gas-fired power generation using imported LNG on the southeastern coast of China was examined. This study aims to identify the position of the national energy strategy that China should import some LNG from the other countries, to guide the development of energy policy in this region, and to formulate some clear policy measures.

  11. Comparison of different testing methods for gas fired domestic boiler efficiency determination

    International Nuclear Information System (INIS)

    De Paepe, M.; T'Joen, C.; Huisseune, H.; Van Belleghem, M.; Kessen, V.

    2013-01-01

    As the Energy Performance of Buildings Directive is being implemented throughout the European Union, a clear need for certification of boiler and domestic heating devices has arisen. Several ‘Notified Bodies’ exist, spread around the different member states. They are acting as the notified body of that member state and focus on local certification. A boiler manufacturer has its equipment tested according to the ‘Boiler Efficiency directive 92/42/EC’. Recently, tests done by several notified bodies in sequence on an identical unit of a manufacturer showed that results could differ depending on which notified body performed the test. In cooperation with ‘Technigas’ (Notified Body in Belgium) a detailed study was done of the measurement setup and devices for determining boiler efficiencies. Several aspects were studied: measurement devices (absolute or differential types), their location within the test setup (focussing on accuracy and their overall impact on the result) and the measurement strategy (measuring on the primary or the secondary water side). The study was performed for both full load and part load scenarios of a gas fired domestic boiler (smaller than 70 kW [4]). The results clearly indicate that temperature measurements arecritical for assessing boiler efficiency. Secondly the test setup using secondary circuit measurements should be preferred. Tests were performed at ‘Technigas’ on different setups in order to validate the findings. - Highlights: ► Labelling of boiler is now obliged by European standards. ► Error propagation is analysed for different methods of boiler performance testing. ► Secondary water side measurement with separate calibration of has highest quality. ► A sensitivity analysis showed that the water temperatures are important factors.

  12. Research and development of a high efficiency gas-fired water heater. Volume 2. Task reports

    Energy Technology Data Exchange (ETDEWEB)

    Vasilakis, A.D.; Pearson, J.F.; Gerstmann, J.

    1980-01-01

    Design and development of a cost-effective high efficiency gas-fired water heater to attain a service efficiency of 70% (including the effect of exfiltration) and a service efficiency of 78% (excluding exfiltration) for a 75 GPD draw at a 90/sup 0/F temperature rise, with a stored water to conditioned air temperature difference of 80/sup 0/F, are described in detail. Based on concept evaluation, a non-powered natural draft water heater was chosen as the most cost-effective design to develop. The projected installed cost is $374 compared to $200 for a conventional unit. When the project water heater is compared to a conventional unit, it has a payback of 3.7 years and life cycle savings of $350 to the consumer. A prototype water heater was designed, constructed, and tested. When operated with sealed combustion, the unit has a service efficiency of 66.4% (including the effect of exfiltration) below a burner input of 32,000 Btu/h. In the open combustion configuration, the unit operated at a measured efficiency of 66.4% Btu/h (excluding exfiltration). This compares with a service efficiency of 51.3% for a conventional water heater and 61% for a conventional high efficiency unit capable of meeting ASHRAE 90-75. Operational tests showed the unit performed well with no evidence of stacking or hot spots. It met or exceeded all capacity or usage tests specified in the program test plan and met all emission goals. Future work will concentrate on designing, building, and testing pre-production units. It is anticipated that both sealed combustion and open draft models will be pursued.

  13. Performance of casting aluminum-silicon alloy condensing heating exchanger for gas-fired boiler

    Science.gov (United States)

    Cao, Weixue; Liu, Fengguo; You, Xue-yi

    2018-01-01

    Condensing gas boilers are widely used due to their high heat efficiency, which comes from their ability to use the recoverable sensible heat and latent heat in flue gas. The condensed water of the boiler exhaust has strong corrosion effect on the heat exchanger, which restricts the further application of the condensing gas boiler. In recent years, a casting aluminum-silicon alloy (CASA), which boasts good anti-corrosion properties, has been introduced to condensing hot water boilers. In this paper, the heat transfer performance, CO and NOx emission concentrations and CASA corrosion resistance of a heat exchanger are studied by an efficiency bench test of the gas-fired boiler. The experimental results are compared with heat exchangers produced by Honeywell and Beka. The results show that the excess air coefficient has a significant effect on the heat efficiency and CO and NOx emission of the CASA water heater. When the excess air coefficient of the CASA gas boiler is 1.3, the CO and NOx emission concentration of the flue gas satisfies the design requirements, and the heat efficiency of water heater is 90.8%. In addition, with the increase of heat load rate, the heat transfer coefficient of the heat exchanger and the heat efficiency of the water heater are increased. However, when the heat load rate is at 90%, the NOx emission in the exhaust gas is the highest. Furthermore, when the temperature of flue gas is below 57 °C, the condensation of water vapor occurs, and the pH of condensed water is in the 2.5 5.5 range. The study shows that CASA water heater has good corrosion resistance and a high heat efficiency of 88%. Compared with the heat exchangers produced by Honeywell and Beka, there is still much work to do in optimizing and improving the water heater.

  14. Combustion measurements in an industrial gas-fired flat-glass furnace

    Energy Technology Data Exchange (ETDEWEB)

    Newbold, J; Webb, B W; McQuay, M Q [Brigham Young Univ., Provo, UT (United States). Mechanical Engineering Dept.; Huber, A M [Ford Motor Co., Glass Div., Dearborn, MI (United States)

    1997-06-01

    Profiles of velocity, species concentration (O{sub 2}, CO and CO{sub 2}), wall incident radiative heat flux and temperature are reported in the combustion space of a regenerative, side-port, 550t/day, gas-fired flat-glass furnace. A region exists of fast-moving gases near the glass, with axial velocity components exceeding 20 m s{sup -1}, and a large recirculation zone near the crown. Temperatures as high as 1985 K in the flame and as low as 1750 K in the recirculation zone are reported. A region of intense reaction is observed near the glass, with large concentration gradients and incomplete combustion even in the tail of the flame. Local incident radiant fluxes on the crown were nearly uniform spatially at a level of 680 kW m{sup -2}. In the portnecks, flat inlet velocity profiles were measured with a magnitude of approximately 11 m s{sup -1}. Significant variations were observed in the exhaust profiles of most measured variables. Large errors in exhaust mass balance suggest a complex, three-dimensional flow with recirculation zones along the side walls of the portnecks. A nominal preheat air temperature of 1420 k and a variation of exhaust temperatures between 1630 K and 1835 K were noted. O{sub 2} concentrations as high as 8.4% were measured at the exit, suggesting a bypass of oxygen-rich flow around the flame. CO{sub 2} concentrations were the highest near the batch, where the glass reactions are the most intense. (Author)

  15. An experimental and theoretical study of decentralized gas fired liquid heating

    Energy Technology Data Exchange (ETDEWEB)

    Christensen, Rolf

    1996-12-01

    The effects on the energy situation in industry when gas fired liquid heaters replace steam have been determined by energy surveys performed in a brewery and a slaughterhouse, measurements of the performance and emissions from liquid heaters installed in these industries, and theoretical analyses of the potential energy. The theoretical study in the first part of the project provides information that allows assessment of the effects on the energy situation, of a part or complete conversion to decentralized heating, under the conditions prevailing in the industries concerned. The second part of the project focused on increasing the liquid heater efficiency and reducing emissions of carbon monoxide and hydrocarbons. Heat transfer and pressure drop for a corrugated tube was investigated experimentally. Empirical correlations for heat transfer and pressure drop for a corrugated tube were developed. These correlations were used in the design model that was developed within this project. The design model was validated against experimental data and data from an industrial application, where a section of the smooth heat exchanger tube was replaced with a corrugated tube. The results show that the design model predicts the outlet flue gas temperature and the heater efficiency quite accurately. The wall temperature at the first corrugation is also predicted with reasonable accuracy. These results make it possible to calculate the location where a corrugated tube can be inserted without causing subcooled boiling or severe fouling. It is shown that emissions of carbon monoxide and hydrocarbons can be held at low levels, even when conventional industrial burners are used. The use of nozzles that produce long soft flames increase the risk for large emissions of hydrocarbons and carbon monoxide. 125 refs, 89 figs, 16 tabs

  16. Residential Care

    Science.gov (United States)

    ... Kids For Teens For Parents & Teachers Resolving Family Conflicts The Holidays and Alzheimer's Glossary Virtual Library Online ... longer an option Costs Choosing a care setting Types of residential care A good long-term care ...

  17. Sorption by cation exchange

    International Nuclear Information System (INIS)

    Bradbury, M.H.; Baeyens, B.

    1994-04-01

    A procedure for introducing exchange into geochemical/surface complexation codes is described. Beginning with selectivity coefficients, K c , defined in terms of equivalent fractional ion occupancies, a general expression for the molar based exchange code input parameters, K ex , is derived. In natural systems the uptake of nuclides onto complex sorbents often occurs by more than one mechanism. The incorporation of cation exchange and surface complexation into a geochemical code therefore enables sorption by both mechanisms to be calculated simultaneously. The code and model concepts are tested against sets of experimental data from widely different sorption studies. A proposal is made to set up a data base of selectivity coefficients. Such a data base would form part of a more general one consisting of sorption mechanism specific parameters to be used in conjunction with geochemical/sorption codes to model and predict sorption. (author) 6 figs., 6 tabs., 26 refs

  18. Assessing the Greenhouse Gas Emissions from Natural Gas Fired Power Plants

    Science.gov (United States)

    Hajny, K. D.; Shepson, P. B.; Rudek, J.; Stirm, B. H.; Kaeser, R.; Stuff, A. A.

    2017-12-01

    Natural gas is often discussed as a "bridge fuel" to transition to renewable energy as it only produces 51% the amount of CO2 per unit energy as coal. This, coupled with rapid increases in production fueled by technological advances, has led to a near tripling of natural gas used for electricity generation since 2005. One concern with this idea of a "bridge fuel" is that methane, the primary component of natural gas, is itself a potent greenhouse gas with 28 and 84 times the global warming potential of CO2 based on mass over a 100 and 20 year period, respectively. Studies have estimated that leaks from the point of extraction to end use of 3.2% would offset the climate benefits of natural gas. Previous work from our group saw that 3 combined cycle power plants emitted unburned CH4 from the stacks and leaked additional CH4 from equipment on site, but total loss rates were still less than 2.2%. Using Purdue's Airborne Laboratory for Atmospheric Research (ALAR) we completed additional aircraft based mass balance experiments combined with passes directly over power plant stacks to expand on the previous study. In this work, we have measured at 12 additional natural gas fired power plants including a mix of operation types (baseload, peaking, intermediate) and firing methods (combined cycle, simple thermal, combustion turbine). We have also returned to the 3 plants previously sampled to reinvestigate emissions for each of those, to assess reproducibility of the results. Here we report the comparison of reported continuous emissions monitoring systems (CEMS) data for CO2 to our emission rates calculated from mass balance experiments, as well as a comparison of calculated CH4 emission rates to estimated emission rates based on the EPA emission factor of 1 g CH4/mmbtu natural gas and CEMS reported heat input. We will also discuss emissions from a coal-fired plant which has been sampled by the group in the past and has since converted to natural gas. Lastly, we discuss the

  19. Optical properties of wet paper and simulation of the effect of autoprofiling on gas-fired IR drying

    Energy Technology Data Exchange (ETDEWEB)

    Ojala, K T; Lampinen, M J [Helsinki University of Technology (FI)

    1991-12-01

    Mathematical models are developed to determine the radiative heat transfer of gas-fired infrared dryers. These models are based on the calculation of radiation energy balance between the main surfaces and layers in the dryer section. The energy efficiency can be calculated, when the temperatures of the radiator and the optical properties of all parts of the dryer are known. A computer program is used for studying the autoprofiling effect in gas-fired infrared drying. Optical properties of paper samples of different moisture contents as a function of wavelength are systematically measured by using FT-IR spectrometer and integrating sphere techniques. These measurements covered the moisture content range of 6-150%. The total measured wavelength range is 1.0-20.0 {mu}m. The moisture content of paper increases the absorptivity mainly in two wavelength ranges, i.e. 1.4-2.6 {mu}m and 3.75-6.0 {mu}m. In these ranges, the difference between the absorptivity of two sheets (dry weight 41.1 g/m{sup 2}, moisture contents 6.0% and 20.8%) is 5-10%. Outside these ranges, the difference is less than 5%. The radiation properties of component surfaces of the IR dryer were measured or taken from literature. The dryer efficiency as a function of the moisture content of paper is calculated. The extent of the autoprofilling effect in gas-fired IR drying is hereby achieved for light weight coated paper web. In one simulation, before the dryer, the moisture difference between two sheets was 5.0% (=20% - 15%). After the dryer, the moisture difference was reduced to 4.5%. If the variation in moisture contents is high, the autoprofilling effect takes place and reduces the moisture variaton. (AB).

  20. Optical properties of wet paper and simulation of the effect of autoprofiling on gas-fired IR drying

    Energy Technology Data Exchange (ETDEWEB)

    Ojala, K T; Lampinen, M J

    1991-01-01

    We have developed new models to determine the radiative heat transfer of gas-fired infrared dryers. A computer program based on the mathematical models is developed further. This program is used for studying the autoprofiling effect in gas-fired infrared drying. Optical properties of paper samples of different moisture contents as a function of wavelength are systematically measured by using FT-lR specrometer and integraing sphere techniques. These measurements covered the moisture content range of 6- 150 %. A new wavelength range (1.2- 1.9 mm), not properly covered by our earlier measurements, is measured by using a liquid nitrogen cooled detector. The total measured wavelength range is 1.0-20.0 mm. The moisture dependence of the optical properties of coating are calculated by using a theoretical model developed in State Research Centre of Finland, Laboratory of Optoelectronics. The radiation properties of component surfaces of the IR dryer were either measured or taken from literature. The mathematical models are based on the calculation of radiation energy balance between the main surfaces and layers in the dryer section. The energy efficiency can be calculated, when the temperatures of the radiator and the optical properties of all parts of the dryer are known. A computer program based on the models is developed further. The dryer efficiency as a function of the moisture content of paper is calculated. The extent of the autoprofiling effect in gas-fired IR drying is hereby achieved for light weight coated paper web. If the variation in moisture contents is high, the autoprofiling effect takes place and reduces the moisture variation. However, if the moisture variation is low, it is not a very significant phenomenon. The simulation results are compared to a pilot coater trial made in Cenre Technique du Papier, Grenoble.

  1. Sorption data bases and mechanistic sorption studies

    International Nuclear Information System (INIS)

    Bradbury, M.H.

    2000-01-01

    In common with many other countries with a nuclear programme, the Swiss concept for the disposal of radioactive waste is focused on deep burial in specially constructed repositories in geologically stable host rocks. Under such conditions, the most likely means whereby radionuclides might return to the biosphere involves their transport in slowly moving groundwater. The sorption of radionuclides by solid phases in the engineered barriers within the repository, and in the surrounding geological media, limits their release and retards their movement. Performance assessment studies for disposal concepts are carried out by Nagra, the National Cooperative for the Disposal of Radioactive Waste, in which various release scenarios are examined, and 'doses to man' calculated. The uptake of radionuclides by immobile phases is one of the pillars upon which the safety case rests. Hence, sorption databases are very important data sets for performance assessments. The methodology lying behind the construction of sorption databases, and some aspects of the supporting experimental work, are briefly described in this report. Flexible, long-term, focused research programmes are required to properly understand the radionuclide/rock/groundwater system, and this is an essential pre-requisite for producing robust state-of-the-art sorption databases. (author)

  2. Sorption data bases and mechanistic sorption studies

    Energy Technology Data Exchange (ETDEWEB)

    Bradbury, M.H

    2000-07-01

    In common with many other countries with a nuclear programme, the Swiss concept for the disposal of radioactive waste is focused on deep burial in specially constructed repositories in geologically stable host rocks. Under such conditions, the most likely means whereby radionuclides might return to the biosphere involves their transport in slowly moving groundwater. The sorption of radionuclides by solid phases in the engineered barriers within the repository, and in the surrounding geological media, limits their release and retards their movement. Performance assessment studies for disposal concepts are carried out by Nagra, the National Cooperative for the Disposal of Radioactive Waste, in which various release scenarios are examined, and 'doses to man' calculated. The uptake of radionuclides by immobile phases is one of the pillars upon which the safety case rests. Hence, sorption databases are very important data sets for performance assessments. The methodology lying behind the construction of sorption databases, and some aspects of the supporting experimental work, are briefly described in this report. Flexible, long-term, focused research programmes are required to properly understand the radionuclide/rock/groundwater system, and this is an essential pre-requisite for producing robust state-of-the-art sorption databases. (author)

  3. Residential Waste

    DEFF Research Database (Denmark)

    Christensen, Thomas Højlund; Fruergaard, Thilde; Matsufuji, Y.

    2011-01-01

    are discussed in this chapter. Characterizing residential waste is faced with the problem that many residences already divert some waste away from the official collection systems, for example performing home composting of vegetable waste and garden waste, having their bundled newspaper picked up by the scouts...... twice a year or bringing their used furniture to the flea markets organized by charity clubs. Thus, much of the data available on residential waste represents collected waste and not necessarily all generated waste. The latter can only be characterized by careful studies directly at the source......, but such studies are very expensive if fair representation of both spatial and temporal variations should be obtained. In addition, onsite studies may affect the waste generation in the residence because of the increased focus on the issue. Residential waste is defined in different ways in different countries...

  4. Life-cycle comparison of greenhouse gas emissions and water consumption for coal and shale gas fired power generation in China

    International Nuclear Information System (INIS)

    Chang, Yuan; Huang, Runze; Ries, Robert J.; Masanet, Eric

    2015-01-01

    China has the world's largest shale gas reserves, which might enable it to pursue a new pathway for electricity generation. This study employed hybrid LCI (life cycle inventory) models to quantify the ETW (extraction-to-wire) GHG (greenhouse gas) emissions and water consumption per kWh of coal- and shale gas-fired electricity in China. Results suggest that a coal-to-shale gas shift and upgrading coal-fired power generation technologies could provide pathways to less GHG and water intensive power in China. Compared to different coal-fired generation technologies, the ETW GHG emissions intensity of gas-fired CC (combined cycle) technology is 530 g CO 2 e/kWh, which is 38–45% less than China's present coal-fired electricity. Gas-fired CT (combustion turbine) technology has the lowest ETW water consumption intensity at 960 g/kWh, which is 34–60% lower than China's present coal-fired electricity. The GHG-water tradeoff of the two gas-fired power generation technologies suggests that gas-fired power generation technologies should be selected based on regional-specific water resource availabilities and electricity demand fluctuations in China. However, the low price of coal-fired electricity, high cost of shale gas production, insufficient pipeline infrastructures, and multiple consumers of shale gas resources may serve as barriers to a coal-to-shale gas shift in China's power sector in the near term. - Highlights: • The GHG and water footprints of coal- and shale gas-fired electricity are estimated. • A coal-to-shale gas shift can enable less GHG and water intensive power in China. • The GHG emissions of shale gas-fired combined cycle technology is 530 g CO 2 e/kWh. • The water consumption of shale gas-fired combustion turbine technology is 960 g/kWh. • Shale gas-fired power generation technologies selection should be regional-specific

  5. Sorption properties of wool

    Directory of Open Access Journals (Sweden)

    Radetić Maja M.

    2004-01-01

    Full Text Available Strict ecological legislation, especially in highly developed countries, imposed requirements for the purification of industrial effluents and the need for efficient oil clean up after sea and inland water spills. Although numerous processes have been developed, the application of sorbents is still one of the most efficient methods to remove heavy metal ions, dyes and crude oil from water. Recently, special attention was paid to sorbents based on natural fibres. A review of studies concerning the sorption properties of wool is presented in this paper. The presence of various functional groups on the wool fibre surface contributes to the efficient sorption of heavy metal ions and dyes. A hydrophobic, scaly surface and fibre crimp strongly influence the high sorption capacity of wool for oil. Wool has great sorption potential even as a recycled material. Accordingly, it can be used as a viable substitute to commercially available synthetic sorbents that show poor biodegradab ility.

  6. Metal sorption on kaolinite

    International Nuclear Information System (INIS)

    Westrich, H.R.; Brady, P.V.; Cygan, R.T.; Nagy, K.L.; Anderson, H.L.

    1997-01-01

    A key issue in performance assessment of low-level radioactive waste sites is predicting the transport and retardation of radionuclides through local soils under a variety of hydrologic and geochemical conditions. Improved transport codes should include a mechanistic model of radionuclide retardation. The authors have been investigating metal sorption (Cs + , Sr 2+ , and Ba 2+ ) on a simple clay mineral (kaolinite) to better understand the geochemical interactions of common soil minerals with contaminated groundwaters. These studies include detailed characterizations of kaolinite surfaces, experimental adsorption measurements, surface complexation modeling, and theoretical simulations of cation sorption. The aluminol edge (010) site has been identified as the most likely site for metal sorption on kaolinite in natural solutions. Relative metal binding strengths decrease from Ba 2+ to Sr 2+ to Cs + , with some portion sorbed on both kaolinite edges and basal surfaces. Some Cs + also appears to be irreversibly sorbed on both sites. Molecular dynamics simulations suggest that Cs + is sorbed at aluminol (010) edge sites as an inner-sphere complex and weakly sorbed as an outer-sphere complex on (001) basal surfaces. These results provide the basis to understand and predict metal sorption onto kaolinite, and a framework to characterize sorption processes on more complex clay minerals

  7. Ensuring Reliable Natural Gas-Fired Generation with Fuel Contracts and Storage - DOE/NETL-2017/1816

    Energy Technology Data Exchange (ETDEWEB)

    Myles, Paul T. [National Energy Technology Lab. (NETL), Albany, OR (United States); Labarbara, Kirk A. [National Energy Technology Lab. (NETL), Albany, OR (United States); Logan, Cecilia Elise [National Energy Technology Lab. (NETL), Albany, OR (United States)

    2017-11-17

    This report finds that natural gas-fired power plants purchase fuel both on the spot market and through firm supply contracts; there do not appear to be clear drivers propelling power plants toward one or the other type. Most natural gas-fired power generators are located near major natural gas transmission pipelines, and most natural gas contracts are currently procured on the spot market. Although there is some regional variation in the type of contract used, a strong regional pattern does not emerge. Whether gas prices are higher with spot or firm contracts varies by both region and year. Natural gas prices that push the generators higher in the supply curve would make them less likely to dispatch. Most of the natural gas generators discussed in this report would be unlikely to enter firm contracts if the agreed price would decrease their dispatch frequency. The price points at which these generators would be unlikely to enter a firm contract depends upon the region that the generator is in, and how dependent that region is on natural gas. The Electric Reliability Council of Texas (ERCOT) is more dependent on natural gas than either Eastern Interconnection or Western Interconnection. This report shows that above-ground storage is prohibitively expensive with respect to providing storage for an extended operational fuel reserve comparable to the amount of on-site fuel storage used for coal-fired plants. Further, both pressurized and atmospheric tanks require a significant amount of land for storage, even to support one day’s operation at full output. Underground storage offers the only viable option for 30-day operational storage of natural gas, and that is limited by the location of suitable geologic formations and depleted fields.

  8. Development and demonstration of a gas-fired recuperative confined radiant burner (deliverable 42/43). Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-06-01

    The objective of the project was to develop and demonstrate an innovative, efficient, low-pollutant, recuperative gas-fired IR-system (infrared radiation) for industrial processes (hereafter referred to as the CONRAD-system). The CONRAD-system is confined, so flue gases from the combustion can be kept separated from the product. The gas/air mixture to the burner is preheated by means of the flue gas, which increases the radiant efficiency of the CONRAD-system significantly over traditional gas-fired IR burners. During the first phase of the project, the CONRAD-system was designed and developed. The conducted work included a survey on suitable burner materials, modelling of the burner system, basic design of burner construction, control etc., experimental characterisation of several preprototypes and detailed design of the internal heat exchanger in the burner. The result is a cost effective burner system with a documented radiant efficiency up to 66% and low emissions (NO{sub x} and CO) all in accordance with the criteria of success set up at the start of the project. In the second phase of the project, the burner system was established and tested in laboratory and in four selected industrial applications: 1) Drying of coatings on sand cores in the automotive industry. 2) Baking of bread/cake. 3) General purpose painting/powder curing process 4. Curing of powder paint on wood components. The results from the preliminary tests Overe used to optimise the CONRAD-system, before it was applied in the industrial processes and demonstrated. However, the optimised burners manufactured for demonstration suffered from different 'infant failures', which made the installation in an industrial environment very cumbersome, and even impossible in the food industry and the automotive industry. In the latter cases realistic laboratory tests Overe carried out and the established know how reported for use when the burner problems are overcome.(au)

  9. Residential greenhouse

    Energy Technology Data Exchange (ETDEWEB)

    1985-02-01

    The following report examines the technical and economic viability of residential greenhouse additions in Whitehorse, Yukon. The greenhouse was constructed using the south facing wall of an existing residence as a common wall. Total construction costs were $18,000, including labour. Annual fuel demand for the residence has been reduced by about 10 per cent for an annual saving of $425. In addition, produce to the value of $1,000 is grown annually in the greenhouse for domestic consumption and commercial resale. Typically the greenhouse operates for nine months each year. There is a net thermal loss during the months of November, December and January as a result of the large area of glazing. As well as supplementing the heating supply solar greenhouses can provide additional cash crops which can be used to offset the cost of construction. Humidity problems are minimal and can be dealt with by exhausting high humidity air. One system which has been considered for the greenhouse is to use a standard residential heat pump to remove excess moisture and to pump heat into the house. This would have a secondary benefit of excluding the need to circulate greenhouse air through the house. Thus any allergenic reactions to the greenhouse air would be prevented. 8 refs., 3 figs, 2 tabs.

  10. Sorption of organic gases in a furnished room

    Energy Technology Data Exchange (ETDEWEB)

    Singer, Brett C.; Revzan, Kenneth L.; Hotchi, Toshifumi; Hodgson, Alfred T.; Brown, Nancy J.

    2003-11-30

    We present experimental data and semi-empirical models describing the sorption of organic gases in a simulated indoor residential environment. Two replicate experiments were conducted with 20 volatile organic compounds (VOCs) in a 50-m{sup 3} room finished with painted wallboard, carpet and cushion, draperies and furnishings. The VOCs span a wide volatility range and include ten Hazardous Air Pollutants. VOCs were introduced to the static chamber as a pulse and their gas-phase concentrations were measured during a net adsorption period and a subsequent net desorption period. Three sorption models were fit to the measured concentrations for each compound to determine the simplest formulation needed to adequately describe the observed behavior. Sorption parameter values were determined by fitting the models to adsorption period data then checked by comparing measured and predicted behavior during desorption. The adequacy of each model was evaluated using a goodness of fit parameter calculated for each period. Results indicate that sorption usually does not greatly affect indoor concentrations of methyl-tert-butyl ether, 2-butanone, isoprene and benzene. In contrast, sorption appears to be a relevant indoor process for many of the VOCs studied, including C{sub 8}-C{sub 10} aromatic hydrocarbons (HC), terpenes, and pyridine. These compounds sorbed at rates close to typical residential air change rates and exhibited substantial sorptive partitioning at equilibrium. Polycyclic aromatic HCs, aromatic alcohols, ethenylpyridine and nicotine initially adsorbed to surfaces at rates of 1.5 to >6 h{sup -1} and partitioned 95 to >99% in the sorbed phase at equilibrium.

  11. Technetium Sorption Media Review

    International Nuclear Information System (INIS)

    Duncan, J.B.; Kelly, S.E.; Robbins, R.A.; Adams, R.D.; Thorson, M.A.; Haass, C.C.

    2011-01-01

    This report presents information and references to aid in the selection of 99Tc sorption media for feasibility studies regarding the removal of 99Tc from Hanford's low activity waste. The report contains literature search material for sorption media (including ion exchange media) for the most tested media to date, including SuperLig 639, Reillex HPQ, TAM (Kruion), Purolite A520E and A530E, and Dowex 1X8. The U.S. Department of Energy (DOE), Office of River Protection (ORP) is responsible for management and completion of the River Protection Project (RPP) mission, which comprises both the Hanford Site tank farms and the Waste Treatment and Immobilization Plant (WTP). The RPP mission is to store, retrieve and treat Hanford's tank waste; store and dispose of treated wastes; and close the tank farm waste management areas and treatment facilities in a safe, environmentally compliant, cost-effective and energy-effective manner.

  12. TECHNETIUM SORPTION MEDIA REVIEW

    Energy Technology Data Exchange (ETDEWEB)

    DUNCAN JB; KELLY SE; ROBBINS RA; ADAMS RD; THORSON MA; HAASS CC

    2011-08-25

    This report presents information and references to aid in the selection of 99Tc sorption media for feasibility studies regarding the removal of 99Tc from Hanford's low activity waste. The report contains literature search material for sorption media (including ion exchange media) for the most tested media to date, including SuperLig 639, Reillex HPQ, TAM (Kruion), Purolite A520E and A530E, and Dowex 1X8. The U.S. Department of Energy (DOE), Office of River Protection (ORP) is responsible for management and completion of the River Protection Project (RPP) mission, which comprises both the Hanford Site tank farms and the Waste Treatment and Immobilization Plant (WTP). The RPP mission is to store, retrieve and treat Hanford's tank waste; store and dispose of treated wastes; and close the tank farm waste management areas and treatment facilities in a safe, environmentally compliant, cost-effective and energy-effective manner.

  13. Operational experiences of (in)direct co-combustion in coal and gas fired power plants in Europe

    International Nuclear Information System (INIS)

    Van Ree, R.; Korbee, R.; Meijer, R.; Konings, T.; Van Aart, F.

    2001-02-01

    The operational experiences of direct and indirect co-combustion of biomass/waste in European coal and natural gas fired power plants are addressed. The operational experiences of mainly Dutch direct co-combustion activities in coal fired power plants are discussed; whereas an overview of European indirect co-combustion activities is presented. The technical, environmental, and economic feasibility of different indirect co-combustion concepts (i.e. upstream gasification, pyrolysis, combustion with steam-side integration) is investigated, and the results are compared with the economic preferable concept of direct co-combustion. Main technical constraints that limit the co-combustion capacity of biomass/waste in conventional coal fired power plants are: the grindability of the biomass/coal blend, the capacity of available unit components, and the danger of severe slagging, fouling, corrosion and erosion. The main environmental constraints that have to be taken into account are the quality of produced solid waste streams (fly ash, bottom ash, gypsum) and the applicable air emission regulations. 6 refs

  14. Advanced turbine systems program conceptual design and product development task 5 -- market study of the gas fired ATS. Topical report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-05-01

    Solar Turbines Incorporated (Solar), in partnership with the Department of Energy, will develop a family of advanced gas turbine-based power systems (ATS) for widespread commercialization within the domestic and international industrial marketplace, and to the rapidly changing electric power generation industry. The objective of the jointly-funded Program is to introduce an ATS with high efficiency, and markedly reduced emissions levels, in high numbers as rapidly as possible following introduction. This Topical Report is submitted in response to the requirements outlined in Task 5 of the Department of Energy METC Contract on Advanced Combustion Systems, Contract No, DE AC21-93MC30246 (Contract), for a Market Study of the Gas Fired Advanced Turbine System. It presents a market study for the ATS proposed by Solar, and will examine both the economic and siting constraints of the ATS compared with competing systems in the various candidate markets. Also contained within this report is an examination and analysis of Solar`s ATS and its ability to compete in future utility and industrial markets, as well as factors affecting the marketability of the ATS.

  15. Modern technical solutions of gas-fired heating devices of household and communal use and analysis of their testing

    Energy Technology Data Exchange (ETDEWEB)

    Bodzon, L.; Radwan, W. [Oil Mining and Gas Engineering Institute, Cracow (Poland)

    1995-12-31

    A review of technical solutions for gas-fired heating devices for household and communal use in Poland is presented. Based upon the analysis it is stated that the power output of Polish and foreign boilers ranges between 9 and 35 kW. The carbon monoxide content in flue gases reaches (on average) 0.005 vol.%, i.e., it is much lower than the maximum permissible level. Temperature of flue gases (excluding condensation boilers and those with air-tight combustion chamber) ranges between 150 and 200{degrees}C and their heating efficiency reaches 87-93%. The best parameters are given for condensation boilers, however they are still not widespread in Poland for the high cost of the equipment and assembling works. Among the heaters, the most safe are convection devices with closed combustion chamber; their efficiency is also the highest. Thus, it is concluded that a wide spectrum of high efficiency heating devices with good combustion parameters are available. The range of output is sufficient to meet household and communal requirement. They are however - predominantly - units manufactured abroad. It is difficult to formulate the program aimed at the improvement of the technique of heating devices made in Poland, and its implementation is uncertain because the production process is broken up into small handicraft workshops.

  16. Optimizing Hydronic System Performance in Residential Applications

    Energy Technology Data Exchange (ETDEWEB)

    Arena, L.; Faakye, O.

    2013-10-01

    Even though new homes constructed with hydronic heat comprise only 3% of the market (US Census Bureau 2009), of the 115 million existing homes in the United States, almost 14 million of those homes (11%) are heated with steam or hot water systems according to 2009 US Census data. Therefore, improvements in hydronic system performance could result in significant energy savings in the US. When operating properly, the combination of a gas-fired condensing boiler with baseboard convectors and an indirect water heater is a viable option for high-efficiency residential space heating in cold climates. Based on previous research efforts, however, it is apparent that these types of systems are typically not designed and installed to achieve maximum efficiency. Furthermore, guidance on proper design and commissioning for heating contractors and energy consultants is hard to find and is not comprehensive. Through modeling and monitoring, CARB sought to determine the optimal combination(s) of components - pumps, high efficiency heat sources, plumbing configurations and controls - that result in the highest overall efficiency for a hydronic system when baseboard convectors are used as the heat emitter. The impact of variable-speed pumps on energy use and system performance was also investigated along with the effects of various control strategies and the introduction of thermal mass.

  17. Valuing a gas-fired power plant: A comparison of ordinary linear models, regime-switching approaches, and models with stochastic volatility

    International Nuclear Information System (INIS)

    Heydari, Somayeh; Siddiqui, Afzal

    2010-01-01

    Energy prices are often highly volatile with unexpected spikes. Capturing these sudden spikes may lead to more informed decision-making in energy investments, such as valuing gas-fired power plants, than ignoring them. In this paper, non-linear regime-switching models and models with mean-reverting stochastic volatility are compared with ordinary linear models. The study is performed using UK electricity and natural gas daily spot prices and suggests that with the aim of valuing a gas-fired power plant with and without operational flexibility, non-linear models with stochastic volatility, specifically for logarithms of electricity prices, provide better out-of-sample forecasts than both linear models and regime-switching models.

  18. Sorption of actinides onto nanodiamonds

    Energy Technology Data Exchange (ETDEWEB)

    Buchatskaya, Yulia; Romanchuk, Anna; Yakovlev, Ruslan; Kulakova, Inna [Lomonosov Moscow State Univ., Moscow (Russian Federation). Dept. of Chemistry; Shiryaev, Andrei [Russian Academy of Sciences, Moscow (Russian Federation). Frumkin Institute of Physical Chemistry and Electrochemistry; Russian Academy of Sciences, Moscow (Russian Federation). Inst. of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry; Kalmykov, Stepan [Lomonosov Moscow State Univ., Moscow (Russian Federation). Dept. of Chemistry; Russian Academy of Sciences, Moscow (Russian Federation). Frumkin Institute of Physical Chemistry and Electrochemistry; Russian Academy of Sciences, Moscow (Russian Federation). Vernadsky Institute of Geochemistry and Analytical Chemistry

    2015-06-01

    Detonation nanodiamonds (ND) present a significant part of nanocarbons group, which could be produced on commercial scale by detonation of explosives in a closed chamber. Their unique properties of high surface area, low weight and radiation resistance make ND a prospective candidate for applications in sorption processes in radiochemistry. To study the influence of surface chemistry on sorption properties, apristine sample of ND was treated with acids and hydrogen. The surface chemistry of the samples was characterised by infrared spectroscopy, X-ray photoelectron spectroscopy and Boehm titration. The sorption properties of ND were tested fordifferent radionuclides. The sorption capacity of ND was shown to be higher than those of commonly used radionuclide sorbents like activated carbon and compariable to other members of nanocarbon group like graphene oxide and carbon nanotubes. The sorption properties were shown to be influenced by the presence of oxygen-containing groups on the surface of ND. This represents an opportunity to increase the sorption capacity of ND.

  19. Sorption of actinides onto nanodiamonds

    International Nuclear Information System (INIS)

    Buchatskaya, Yulia; Romanchuk, Anna; Yakovlev, Ruslan; Kulakova, Inna; Shiryaev, Andrei; Russian Academy of Sciences, Moscow; Kalmykov, Stepan; Russian Academy of Sciences, Moscow; Russian Academy of Sciences, Moscow

    2015-01-01

    Detonation nanodiamonds (ND) present a significant part of nanocarbons group, which could be produced on commercial scale by detonation of explosives in a closed chamber. Their unique properties of high surface area, low weight and radiation resistance make ND a prospective candidate for applications in sorption processes in radiochemistry. To study the influence of surface chemistry on sorption properties, apristine sample of ND was treated with acids and hydrogen. The surface chemistry of the samples was characterised by infrared spectroscopy, X-ray photoelectron spectroscopy and Boehm titration. The sorption properties of ND were tested fordifferent radionuclides. The sorption capacity of ND was shown to be higher than those of commonly used radionuclide sorbents like activated carbon and compariable to other members of nanocarbon group like graphene oxide and carbon nanotubes. The sorption properties were shown to be influenced by the presence of oxygen-containing groups on the surface of ND. This represents an opportunity to increase the sorption capacity of ND.

  20. Analysis of an effective solution to excessive heat supply in a city primary heating network using gas-fired boilers for peak-load compensation

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Hai-Chao; Jiao, Wen-Ling; Zou, Ping-Hua; Liu, Jing-Cheng [School of Municipal and Environmental Engineering, Harbin Institute of Technology, mail box 2645, 202 Haihe Road, Nangang District, Harbin 150090 (China)

    2010-11-15

    Through investigation of the Dengfeng heating network in the city of Daqing, China, for the 2007-2008 heating season, we found serious problems of excessive heat supply in the primary heating network. Therefore, we propose the application of gas-fired boilers in underperforming heating substations as peak-load heat sources to effectively adapt to the regulation demands of seasonal heat-load fluctuations and reduce the excessive heat supply. First, we calculated the excessive heat supply rates (EHSRs) of five substations using detailed investigative data. We then discussed the feasibility of the proposed scheme providing energy savings from both energetic and exergetic points of view. The results showed that the average EHSR of the five substations between January and March was 20.57% of the gross heat production but consequently reduced to 6.24% with the installation of the gas-fired boilers. Therefore, the combined heating scheme with coal as the basic heat-source and gas-fired boilers as peak-load heat sources is energy-efficient to some extent, although requires the use of natural gas. Meanwhile, the exergy decreased by 10.97%, which indicates that the combined heating scheme effectively reduces the primary energy consumption and pollutant emission of the heating systems. (author)

  1. Mathematical models and qualities of shredded Thai-style instant rice under a combined gas-fired infrared and air convection drying

    Science.gov (United States)

    Nachaisin, Mali; Teeta, Suminya; Deejing, Konlayut; Pharanat, Wanida

    2017-09-01

    Instant food is a product produced for convenience for consumer. Qualities are an important attribute of food materials reflecting consumer acceptance. The most problem of instant rice is casehardening during drying process resulted in the longer rehydration time. The objective of this research was to study the qualities of shredded Thai-style instant rice under a combined gas-fired infrared and air convection drying. Additionally, the mathematical models for gas-fired infrared assisted thin-layer drying of shredded Thai-style rice for traditional was investigated. The thin-layer drying of shredded Thai-style rice was carried out under gas-fired infrared intensities of 1000W/m2, air temperatures of 70°C and air velocities of 1 m/s. The drying occurred in the falling rate of drying period. The Page model was found to satisfactorily describe the drying behavior of shredded Thai-style rice, providing the highest R2 (0.997) and the lowest MBE and RMSE (0.01 and 0.18) respectively. A 9 point hedonic test showed in softness and color, but odor and overall acceptance were very similar.

  2. Fossil fuel-fired power generation. Case studies of recently constructed coal- and gas-fired plants

    Energy Technology Data Exchange (ETDEWEB)

    Henderson, C. [IEA Clean Coal Centre, London (United Kingdom)

    2007-10-23

    To meet future energy demand growth and replace older or inefficient units, a large number of fossil fuel-fired plants will be required to be built worldwide in the next decade. Yet CO{sub 2} emissions from fossil-fired power generation are a major contributor to climate change. As a result, new plants must be designed and operated at highest efficiency both to reduce CO{sub 2} emissions and to facilitate deployment of CO{sub 2} capture and storage in the future. The series of case studies in this report, which respond to a request to the IEA from the G8 Summit in July 2005, were conducted to illustrate what efficiency is achieved now in modern plants in different parts of the world using different grades of fossil fuels. The plants were selected from different geographical areas, because local factors influence attainable efficiency. The case studies include pulverized coal combustion (PCC) with both subcritical and supercritical (very high pressure and temperature) steam turbine cycles, a review of current and future applications of coal-fuelled integrated gasification combined cycle plants (IGCC), and a case study of a natural gas fired combined cycle plant to facilitate comparisons. The results of these analyses show that the technologies for high efficiency (low CO{sub 2} emission) and very low conventional pollutant emissions (particulates, SO{sub 2}, NOx) from fossil fuel-fired power generation are available now through PCC, IGCC or NGCC at commercially acceptable cost. This report contains comprehensive technical and indicative cost information for modern fossil fuel-fired plants that was previously unavailable. It serves as a valuable sourcebook for policy makers and technical decision makers contemplating decisions to build new fossil fuel-fired power generation plants.

  3. Accounting for fuel price risk: Using forward natural gas prices instead of gas price forecasts to compare renewable to natural gas-fired generation

    Energy Technology Data Exchange (ETDEWEB)

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2003-08-13

    Against the backdrop of increasingly volatile natural gas prices, renewable energy resources, which by their nature are immune to natural gas fuel price risk, provide a real economic benefit. Unlike many contracts for natural gas-fired generation, renewable generation is typically sold under fixed-price contracts. Assuming that electricity consumers value long-term price stability, a utility or other retail electricity supplier that is looking to expand its resource portfolio (or a policymaker interested in evaluating different resource options) should therefore compare the cost of fixed-price renewable generation to the hedged or guaranteed cost of new natural gas-fired generation, rather than to projected costs based on uncertain gas price forecasts. To do otherwise would be to compare apples to oranges: by their nature, renewable resources carry no natural gas fuel price risk, and if the market values that attribute, then the most appropriate comparison is to the hedged cost of natural gas-fired generation. Nonetheless, utilities and others often compare the costs of renewable to gas-fired generation using as their fuel price input long-term gas price forecasts that are inherently uncertain, rather than long-term natural gas forward prices that can actually be locked in. This practice raises the critical question of how these two price streams compare. If they are similar, then one might conclude that forecast-based modeling and planning exercises are in fact approximating an apples-to-apples comparison, and no further consideration is necessary. If, however, natural gas forward prices systematically differ from price forecasts, then the use of such forecasts in planning and modeling exercises will yield results that are biased in favor of either renewable (if forwards < forecasts) or natural gas-fired generation (if forwards > forecasts). In this report we compare the cost of hedging natural gas price risk through traditional gas-based hedging instruments (e

  4. Sorption properties of carbon nanostructures

    International Nuclear Information System (INIS)

    Eletskii, Aleksandr V

    2004-01-01

    The current status of research in sorption properties of carbon nanotubes (CNTs) is reviewed. The structural peculiarities of CNTs, determining their sorption characteristics, are considered. The mechanisms of sorption of gaseous and condensed substances by such structures are analyzed. Special attention is paid to the problem of using CNTs for storing hydrogen and other gaseous substances. Methods for filling CNTs with liquid materials, based on capillary phenomena and wetting the graphite surface of the CNT with liquids of various nature, are considered. Properties of 'peapods' formed as a result of filling single-walled CNTs with fullerene molecules are reviewed. Also considered are perspectives on the applied usage of the sorption properties of CNTs in electrochemical and fuel cells, and material storage devices, as well as for producing superminiature metallic conductors. (reviews of topical problems)

  5. Evaluation of sorption distribution coefficient of Cs onto granite using sorption data collected in sorption database and sorption model

    International Nuclear Information System (INIS)

    Nagasaki, S.

    2013-01-01

    Based on the sorption distribution coefficients (K d ) of Cs onto granite collected from the JAERI Sorption Database (SDB), the parameters for a two-site model without the triple-layer structure were optimized. Comparing the experimentally measured K d values of Cs onto Mizunami granite carried out by JAEA with the K d values predicted by the model, the effect of the ionic strength on the K d values of Cs onto granite was evaluated. It was found that K d values could be determined using the content of biotite in granite at a sodium concentration ([Na]) of 1 x 10 -2 to 5 x 10 -1 mol/dm 3 . It was suggested that in high ionic strength solutions, the sorption of Cs onto other minerals such as microcline should also be taken into account. (author)

  6. Evaluation of sorption distribution coefficient of Cs onto granite using sorption data collected in sorption database and sorption model

    Energy Technology Data Exchange (ETDEWEB)

    Nagasaki, S., E-mail: nagasas@mcmaster.ca [McMaster Univ., Hamilton, Ontario (Canada)

    2013-07-01

    Based on the sorption distribution coefficients (K{sub d}) of Cs onto granite collected from the JAERI Sorption Database (SDB), the parameters for a two-site model without the triple-layer structure were optimized. Comparing the experimentally measured K{sub d} values of Cs onto Mizunami granite carried out by JAEA with the K{sub d} values predicted by the model, the effect of the ionic strength on the K{sub d} values of Cs onto granite was evaluated. It was found that K{sub d} values could be determined using the content of biotite in granite at a sodium concentration ([Na]) of 1 x 10{sup -2} to 5 x 10{sup -1} mol/dm{sup 3} . It was suggested that in high ionic strength solutions, the sorption of Cs onto other minerals such as microcline should also be taken into account. (author)

  7. 77 FR 28519 - Test Procedure Guidance for Room Air Conditioners, Residential Dishwashers, and Residential...

    Science.gov (United States)

    2012-05-15

    ... Guidance for Room Air Conditioners, Residential Dishwashers, and Residential Clothes Washers: Public... procedures for room air conditioners, residential dishwashers, and residential clothes washers. DATES: DOE...'s existing test procedures for residential room air conditioners, residential dishwashers, and...

  8. Sorption isotherms, GAB parameters and isosteric heat of sorption

    NARCIS (Netherlands)

    Quirijns, E.J.; Boxtel, van A.J.B.; Loon, van W.K.P.; Straten, van G.

    2005-01-01

    The diffusion-sorption drying model has been developed as a physics-based way to model the decreasing drying rate at low moisture contents. This new model is founded on the existence of different classes of water: free and bound water. The transition between these classes and the corresponding

  9. Not locked-in? The overlooked impact of new gas-fired generation investment on long-term decarbonisation in the UK

    International Nuclear Information System (INIS)

    Chignell, Simon; Gross, Robert J.K.

    2013-01-01

    This paper contrasts the potential increase in gas-fired power generation in the UK in the period to 2020 with the ambitious decarbonisation goals set forth for this sector. An increase in Combined Cycle Gas Turbine (CCGT) capacity, in particular, only represents a threat to long-term decarbonisation if some ‘lock-in’ exists. It is against this background, and in the interest of challenging the perception of no significant lock-in to gas-fired generation, that this paper identifies investment lock-in as phenomenon of relevance to policy-makers. The paper determines both direct and indirect ways in which investment in significant new CCGT capacity could negatively impact on the likelihood of meeting decarbonisation goals through ‘locking-in’ the existing technological system. It also identifies that the technical lifetime, and not just the capital repayment period, of CCGT assets is relevant in understanding the strength of the lock-in. Finally, a regulatory structure that aligns with the long-term targets in place is identified as providing a clear signal for investors and asset owners that may reduce the risk of ‘investment lock-in’. - Highlights: ► The potential conflict between new CCGT and decarbonisation targets is examined. ► A form of ‘hysteretic lock-in’ associated with CCGT investment is identified. ► Potential effects of ‘lock-in’ from new CCGT investment in the UK are highlighted. ► The paper argues for a clear long-term regulatory structure for new CCGT generation.

  10. Sorption on inactive repository components

    International Nuclear Information System (INIS)

    Gardiner, M.P.; Smith, A.J.; Williams, S.J.

    1990-11-01

    The near-field of an intermediate level/low level radioactive waste repository will contain significant quantities of iron and steel, Magnox and Zircaloy. Their corrosion products may possess significant sorption capacity for radioelements. The sorption of americium and plutonium onto magnesium hydroxide, zirconium hydroxide, colloidal magnetite and colloidal haematite has been studied under conditions typical of the porewater of a cementitious near-field. R D values ≥ 10 5 m g -1 were measured for both actinides on the oxides and hydroxides. These values are at least as great as those measured on crushed 3:1 Blast Furnace Slag/Ordinary Portland cement. Competitive sorption experiments have shown that sorption onto the corrosion products does not take place in preference to that on the cement or the converse. Magnetite and haematite colloids are positively charged in cement-equilibrated water whilst zirconium hydroxide is negatively charged. Crushed cement was found to be positively charged. Simple experiments show that only a small proportion of haematite colloids is potentially mobile through a column of crushed cement. (author)

  11. Sorption on inactive repository components

    International Nuclear Information System (INIS)

    Gardiner, M.P.; Smith, A.J.; Williams, S.J.

    1990-07-01

    The near-field of an intermediate level/low level radioactive waste repository will contain significant quantities of iron and steel, Magnox and Zircaloy. Their corrosion products may possess significant sorption capacity for radioelements. The sorption of americium and plutonium onto magnesium hydroxide, zirconium hydroxide, colloidal magnetite and colloidal haematite has been studied under conditions typical of the porewater of a cementitious near-field. R D values ≥ 10 5 ml g -1 were measured for both actinides on the oxides and hydroxides. These values are at least as great at those measured on crushed 3:1 Blast Furnace Slag/Ordinary Portland Cement. Competitive sorption experiments have shown that sorption onto the corrosion products does not take place in preference to that on the cement or the converse. Magnetite and haematite colloids are positively charged in cement-equilibrated water whilst zirconium hydroxide is negatively charged. Crushed cement was found to be positively charged. Simple experiments show that only a small proportion of haematite colloids is potentially mobile through a column of crushed cement. (author)

  12. Sorption Energy Maps of Clay Mineral Surfaces

    International Nuclear Information System (INIS)

    Cygan, Randall T.; Kirkpatrick, R. James

    1999-01-01

    A molecular-level understanding of mineral-water interactions is critical for the evaluation and prediction of the sorption properties of clay minerals that may be used in various chemical and radioactive waste disposal methods. Molecular models of metal sorption incorporate empirical energy force fields, based on molecular orbital calculations and spectroscopic data, that account for Coulombic, van der Waals attractive, and short-range repulsive energies. The summation of the non-bonded energy terms at equally-spaced grid points surrounding a mineral substrate provides a three dimensional potential energy grid. The energy map can be used to determine the optimal sorption sites of metal ions on the exposed surfaces of the mineral. By using this approach, we have evaluated the crystallographic and compositional control of metal sorption on the surfaces of kaolinite and illite. Estimates of the relative sorption energy and most stable sorption sites are derived based on a rigid ion approximation

  13. Applicability of microautoradiography to sorption studies

    International Nuclear Information System (INIS)

    Thompson, J.L.; Wolfsberg, K.

    1979-01-01

    The technique of microautoradiography was applied to the study of the sorption of uranium and americium on five rock types which exist at the Nevada Test Site. It was found that autoradiograms could be prepared in a few days which would allow the specific minerals responsible for sorption to be identified. Furthermore, the state of aggregation of the sorbed species was clearly indicated. It was concluded that microautoradiography was a useful adjunct to currently used methods for studying sorption of certain radionuclides

  14. Strontium sorption on Savannah River Plant soils

    International Nuclear Information System (INIS)

    Hoeffner, S.L.

    1984-12-01

    A laboratory study of strontium-85 sorption was conducted using Savannah River Plant soil and groundwater from the low-level waste burial ground. Systematic variation of soil and water composition indicates that strontium sorption is most strongly a function of pH. Changes in clay content and in K + , Ca 2+ , or Mg 2+ concentrations influence strontium sorption indirectly through the slight pH changes which result. The ions Na + , Cl - , and NO 3 - have no effect. Ferrous ion, added to groundwater to simulate the conditions of water at the bottom of waste trenches, did not account for low strontium sorption observed with some trench waters

  15. Technical, economic and environmental potential of co-firing of biomass in coal and natural gas fired power plants in the Netherlands

    International Nuclear Information System (INIS)

    Van Ree, R.; Korbee, R.; Eenkhoorn, S.; De Lange, T.; Groenendaal, B.

    2000-01-01

    In this paper the technical, economic, and environmental potential of co-firing of biomass in existing Dutch coal and natural gas fired power plants, and industrial combined-cycles (CC), is addressed. Main criteria that are considered are: the availability and contractibility of biomass for energy purposes; the (technical) operation of the conventional fossil fuel based processes may not be disturbed; the gaseous and liquid plant emissions have to comply to those applicable for power plants/CCs, the commercial applicability of the solid residues may not be negatively influenced; applicable additional biomass conversion technologies must be commercially available; the necessary additional investment costs must be acceptable from an economic point of view, and the co-firing option must result in a substantial CO 2 -emission reduction. The main result of the study described in the paper is the presentation of a clear and founded indication of the total co-firing potential of biomass in existing power plants and industrial CCs in the Netherlands. This potential is determined by considering both technical, economic, and environmental criteria. In spite of the fact that the co-firing potential for the specific Dutch situation is presented, the results of the criteria considered are more generally applicable, and therefore are also very interesting for potential co-firing initiatives outside of the Netherlands

  16. A Techno-Economic Assessment of Hybrid Cooling Systems for Coal- and Natural-Gas-Fired Power Plants with and without Carbon Capture and Storage.

    Science.gov (United States)

    Zhai, Haibo; Rubin, Edward S

    2016-04-05

    Advanced cooling systems can be deployed to enhance the resilience of thermoelectric power generation systems. This study developed and applied a new power plant modeling option for a hybrid cooling system at coal- or natural-gas-fired power plants with and without amine-based carbon capture and storage (CCS) systems. The results of the plant-level analyses show that the performance and cost of hybrid cooling systems are affected by a range of environmental, technical, and economic parameters. In general, when hot periods last the entire summer, the wet unit of a hybrid cooling system needs to share about 30% of the total plant cooling load in order to minimize the overall system cost. CCS deployment can lead to a significant increase in the water use of hybrid cooling systems, depending on the level of CO2 capture. Compared to wet cooling systems, widespread applications of hybrid cooling systems can substantially reduce water use in the electric power sector with only a moderate increase in the plant-level cost of electricity generation.

  17. Family ties and residential locations

    NARCIS (Netherlands)

    Mulder, C.H.; Cooke, T.J.

    2009-01-01

    In this paper, and in the Special Issue it introduces, the focus is on the role of family ties in residential location choice and, conversely, the role of residential locations in maintaining family ties. Not only do events in the nuclear family trigger residential relocations, but nearby family

  18. Feasibility study of a hybrid renewable energy system with geothermal and solar heat sources for residential buildings in South Korea

    International Nuclear Information System (INIS)

    Kim, Young Ju; Woo, Nam Sub; Jang, Sung Cheol; Choi, Jeong Ju

    2013-01-01

    This study investigates the economic feasibility of a hybrid renewable energy system (HRES) that uses geothermal and solar heat sources for water heating, space heating, and space cooling in a residential building in Korea. A small-scale HRES consists of a geothermal heat pump for heating and cooling, solar collectors for hot water, a gas-fired backup boiler, and incidental facilities. To determine whether the Hares will produce any economic benefits for homeowners, an economic analysis is conducted to compare the Hares with conventional methods of space heating and cooling in Korea. The payback period of a small-scale Hares is predicted as a maximum of 9 yrs by life cycle costing based on a performance index compared with conventional systems. However, the payback period of large-scale HRES above 400 RT is 6 yrs to 7 yrs.

  19. Feasibility study of a hybrid renewable energy system with geothermal and solar heat sources for residential buildings in South Korea

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Young Ju; Woo, Nam Sub [Korea Institute of Geoscience and Mineral Resources, Daejeon (Korea, Republic of); Jang, Sung Cheol [Mechatronics Department of the Korea Aviation Polytechnic College, Sacheon (Korea, Republic of); Choi, Jeong Ju [Dong-A University, Busan (Korea, Republic of)

    2013-08-15

    This study investigates the economic feasibility of a hybrid renewable energy system (HRES) that uses geothermal and solar heat sources for water heating, space heating, and space cooling in a residential building in Korea. A small-scale HRES consists of a geothermal heat pump for heating and cooling, solar collectors for hot water, a gas-fired backup boiler, and incidental facilities. To determine whether the Hares will produce any economic benefits for homeowners, an economic analysis is conducted to compare the Hares with conventional methods of space heating and cooling in Korea. The payback period of a small-scale Hares is predicted as a maximum of 9 yrs by life cycle costing based on a performance index compared with conventional systems. However, the payback period of large-scale HRES above 400 RT is 6 yrs to 7 yrs.

  20. GREEN RETROFITTING RESIDENTIAL BUILDINGS

    Science.gov (United States)

    When compared with the rest of the world, the United States consumes a disproportionately large amount of energy and is a major source of greenhouse gases from fossil fuel combustion. As much as two thirds of U.S. electricity production is consumed by residential and commerci...

  1. Residential Mechanical Precooling

    Energy Technology Data Exchange (ETDEWEB)

    German, a. [Alliance for Residential Building Innovation (ARBI), Davis, CA (United States); Hoeschele, M. [Alliance for Residential Building Innovation (ARBI), Davis, CA (United States)

    2014-12-01

    This research conducted by the Alliance for Residential Building Innovation team evaluated mechanical air conditioner pre-cooling strategies in homes throughout the United States. EnergyPlus modeling evaluated two homes with different performance characteristics in seven climates. Results are applicable to new construction homes and most existing homes built in the last 10 years, as well as fairly efficient retrofitted homes.

  2. Models for the location decision for a combined cycle power plant : basic principles for solving the decision problem of the choice of location for a feasibility study of gas-fired power plants

    OpenAIRE

    Krüger, Jan

    2015-01-01

    The present thesis deals with the foundations for solving the decision problem of site selection for a feasibility study of gas-fired power plants, based on realistic and practical statements, under a business approach. The analysis of different theories and the investigation of site-relevant decision criteria has illustrated the broad range of site-specific factors and criteria that are to be taken into account. On the basis of existing projects, in which site theories were analysed for vari...

  3. Sorption of radionuclides on inorganic sorbents

    International Nuclear Information System (INIS)

    Rajec, P.; Matel, L.

    1995-01-01

    The sorption of cesium, strontium, plutonium and americium from water solution on natural zeolite, clay minerals, synthetic zeolites and ferrocyanides in silica gel matrix was studied. The same experiments but with synthetic zeolites irradiated by the dose 100 kGy proved no change in sorption properties. 1 tab., 4 refs

  4. Nitrate Sorption in an Agricultural Soil Profile

    Directory of Open Access Journals (Sweden)

    Wissem Hamdi

    2013-01-01

    Full Text Available Increasing concentrations of in surface water and groundwater can cause ecological and public health effects and has come under increased scrutiny by both environmental scientists and regulatory agencies. For many regions though, including the Sahel of Tunisia, little is known about the sorption capacity of soils. In this project we measured sorption by a profile of an iso-humic soil from Chott Meriem, Tunisia. Soil samples were collected from four soil depths (0–25, 25–60, 60–90, and 90–120 cm on 1 June 2011, and their sorption capacity was determined using batch experiments under laboratory conditions. The effects of contact time, the initial concentration, and the soil-solution ratio on sorption were investigated. In general, the results suggested that was weakly retained by the Chott Meriem soil profile. The quantity of sorption increased with depth, contact time, initial concentration, and soil-solution ratios. To evaluate the sorption capacities of the soil samples at concentrations ranging between 25 and 150 mg L−1 experimental data were fitted to both Freundlich and Langmuir isotherm sorption models. The results indicated that Freundlich model was better for describing sorption in this soil profile.

  5. Sorption of mercury on chemically synthesized polyaniline

    International Nuclear Information System (INIS)

    Remya Devi, P.S.; Verma, R.; Sudersanan, M.

    2006-01-01

    Sorption of inorganic mercury (Hg 2+ ) and methyl mercury, on chemically synthesized polyaniline, in 0.1-10N HCl solutions has been studied. Hg 2+ is strongly sorbed at low acidities and the extent of sorption decreases with increase in acidity. The sorption of methyl mercury is very low in the HCl concentration range studied. Sorption of Hg 2+ on polyaniline in 0.1-10N LiCl and H 2 SO 4 solutions has also been studied. The analysis of the data indicates that the sorption of Hg 2+ depends on the degree of protonation of polyaniline and the nature of mercury(II) chloride complexes in solution. X-ray photoelectron spectroscopy analysis (XPS) of polyaniline sorbed with mercury show that mercury is bound as Hg 2+ . Sorbed mercury is quantitatively eluted from polyaniline with 0.5N HNO 3 . Polyaniline can be used for separation and pre-concentration of inorganic mercury from aqueous samples. (author)

  6. Phenanthrene sorption on biochar-amended soils

    DEFF Research Database (Denmark)

    Kahawaththa Gamage, Inoka Damayanthi Kumari; Moldrup, Per; Paradelo Pérez, Marcos

    2014-01-01

    on their influences on the sorption of environmental contaminants. In a field-based study at two experimental sites in Denmark, we investigated the effect of birch wood-derived biochar (Skogans kol) on the sorption of phenanthrene in soils with different properties. The soil sorption coefficient, Kd (L kg-1......), of phenanthrene was measured on sandy loam and loamy sand soils which have received from zero up to 100 t ha-1 of biochar. Results show that birch wood biochar had a higher Kd compared to soils. Furthermore, the application of birch wood biochar enhanced the sorption of phenanthrene in agricultural soils...... carbon, while it negatively correlated with clay content. The results also revealed that biochar-mineral interactions play an important role in the sorption of phenanthrene in biochar-amended soil....

  7. Cobalt sorption onto Savannah River Plant soils

    International Nuclear Information System (INIS)

    Hoeffner, S.L.

    1985-06-01

    A laboratory study of cobalt-60 sorption was conducted using Savannah River Plant soil and groundwater from the low-level waste burial ground. Systematic variation of soil and water composition indicates that cobalt sorption is most strongly a function of pH. Over a pH range of 2 to 9, the distribution coefficient ranged from 2 to more than 10,000 mL/g. Changes in clay content and in K + , Ca 2+ , or Mg 2+ concentrations influence cobalt sorption indirectly through the slight pH changes which result. The ions Na + , Cl - , and NO 3 - have no effect on cobalt sorption. Ferrous ion, added to groundwater to simulate the condition of water at the bottom of the waste trenches, accounts for part of the decrease in cobalt sorption observed with trench waters. 17 refs., 3 figs., 4 tabs

  8. Prediction of metal sorption in soils

    International Nuclear Information System (INIS)

    Westrich, Henry R.; Anderson, Harold L. Jr.; Arthur, Sara E.; Brady, Patrick V.; Cygan, Randall T.; Liang, Jianjie; Zhang, Pengchu; Yee, N.

    2000-01-01

    Radionuclide transport in soils and groundwaters is routinely calculated in performance assessment (PA) codes using simplified conceptual models for radionuclide sorption, such as the K D approach for linear and reversible sorption. Model inaccuracies are typically addressed by adding layers of conservativeness (e.g., very low K D 's), and often result in failed transport predictions or substantial increases in site cleanup costs. Realistic assessments of radionuclide transport over a wide range of environmental conditions can proceed only from accurate, mechanistic models of the sorption process. They have focused on the sorption mechanisms and partition coefficients for Cs + , Sr 2+ and Ba 2+ (analogue for Ra 2+ ) onto iron oxides and clay minerals using an integrated approach that includes computer simulations, sorption/desorption measurements, and synchrotron analyses of metal sorbed substrates under geochemically realistic conditions. Sorption of Ba 2+ and Sr 2+ onto smectite is strong, pH-independent, and fully reversible, suggesting that cation exchange at the interlayer basal sites controls the sorption process. Sr 2+ sorbs weakly onto geothite and quartz, and is pH-dependent. Sr 2+ sorption onto a mixture of smectite and goethite, however, is pH- and concentration dependent. The adsorption capacity of montmorillonite is higher than that of goethite, which may be attributed to the high specific surface area and reaction site density of clays. The presence of goethite also appears to control the extent of metal desorption. In-situ, extended X-ray absorption fine structure (EXAFS) spectroscopic measurements for montmorillonite and goethite show that the first shell of adsorbed Ba 2+ is coordinated by 6 oxygens. The second adsorption shell, however, varies with the mineral surface coverage of adsorbed Ba 2+ and the mineral substrate. This suggests that Ba 2+ adsorption on mineral surfaces involves more than one mechanism and that the stability of sorbed

  9. Techno-economic analysis of a coal-fired CHP based combined heating system with gas-fired boilers for peak load compensation

    International Nuclear Information System (INIS)

    Wang Haichao; Jiao Wenling; Lahdelma, Risto; Zou Pinghua

    2011-01-01

    Combined heat and power (CHP) plants dominate the heating market in China. With the ongoing energy structure reformation and increasing environmental concerns, we propose gas-fired boilers to be deployed in underperforming heating substations of heating networks for peak load compensation, in order to improve both energy efficiency and environmental sustainability. However, due to the relatively high price of gas, techno-economic analysis is required for evaluating different combined heating scenarios, characterized by basic heat load ratio (β). Therefore, we employ the dynamic economics and annual cost method to develop a techno-economic model for computing the net heating cost of the system, considering the current state of the art of cogeneration systems in China. The net heating cost is defined as the investment costs and operations costs of the system subtracted by revenues from power generation. We demonstrate the model in a real-life combined heating system of Daqing, China. The results show that the minimum net heating cost can be realized at β=0.75 with a cost reduction of 16.8% compared to coal heating alone. Since fuel cost is the dominating factor, sensitivity analyses on coal and gas prices are discussed subsequently. - Highlights: ► Combined heating systems comply with the energy structure reformation in China. ► We consider the current state of the art of cogeneration systems in China. ► Combined heating systems can be economically more feasible and sustainable. ► The net heating cost of a combined heating system is more sensitive to coal price. ► The optimal basic heat load ratio is more easily influenced by gas price.

  10. Guidelines for residential commissioning

    Energy Technology Data Exchange (ETDEWEB)

    Wray, Craig P.; Walker, Iain S.; Sherman, Max H.

    2003-01-31

    Currently, houses do not perform optimally or even as many codes and forecasts predict, largely because they are field assembled and there is no consistent process to identify problems or to correct them. Residential commissioning is a solution to this problem. This guide is the culmination of a 30-month project that began in September 1999. The ultimate objective of the project is to increase the number of houses that undergo commissioning, which will improve the quality, comfort, and safety of homes for California citizens. The project goal is to lay the groundwork for a residential commissioning industry in California focused on end-use energy and non-energy issues. As such, we intend this guide to be a beginning and not an end. Our intent is that the guide will lead to the programmatic integration of commissioning with other building industry processes, which in turn will provide more value to a single site visit for people such as home energy auditors and raters, home inspectors, and building performance contractors. Project work to support the development of this guide includes: a literature review and annotated bibliography, which facilitates access to 469 documents related to residential commissioning published over the past 20 years (Wray et al. 2000), an analysis of the potential benefits one can realistically expect from commissioning new and existing California houses (Matson et al. 2002), and an assessment of 107 diagnostic tools for evaluating residential commissioning metrics (Wray et al. 2002). In this guide, we describe the issues that non-experts should consider in developing a commissioning program to achieve the benefits we have identified. We do this by providing specific recommendations about: how to structure the commissioning process, which diagnostics to use, and how to use them to commission new and existing houses. Using examples, we also demonstrate the potential benefits of applying the recommended whole-house commissioning approach to

  11. Sorption behavior of cesium onto bentonite colloid

    International Nuclear Information System (INIS)

    Iijima, Kazuki; Masuda, Tsuguya; Tomura, Tsutomu

    2004-01-01

    It is considered that bentonite colloid might be generated from bentonite which will be used as buffer material in geological disposal system, and can facilitate the migration of radionuclides by means of sorption. In order to examine this characteristic, sorption and desorption experiments of Cs onto bentonite colloid were carried out to obtain its distribution coefficient (Kd) and information on the reversibility of its sorption. In addition, particle size distribution and shape of colloid were investigated and their effect on the sorption behavior was discussed. Kds for Cs were around 20 m 3 /kg for sorption and 30 m 3 /kg for desorption, in which sorbed Cs was desorbed by 8.4x10 -4 mol/l of NaCl solution. These values did not show any dependencies on Cs concentration and duration of sorption and desorption. The first 20% of sorbed Cs was desorbed reversibly at least. Most of colloidal particles were larger than 200 nm and TEM micrographs showed they had only several sheets of the clay crystal. Obtained Kds for colloidal bentonite were larger than those for powdered bentonite. This can be caused by difference of competing ions in the solution, characteristics of contained smectite, or sorption site density. (author)

  12. Sorption of uranyl ions on hydrous oxides

    International Nuclear Information System (INIS)

    Gupta, A.R.; Venkataramani, B.

    1988-01-01

    Sorption of uranyl ions on hydrous titanium oxide (HTiO), magnetite (MAG), and hydrous thorium oxide (HThO) has been studied as a function of pH. Hydrous oxides have been characterized by their pH-titration curves, intrinsic dissociation constants (pK ai * ) and point of zero charge (pH pzc ). The fraction of protonated surface hydroxyl groups as well as the surface pH (pH surf ) as a function of solution pH have been computed. The distribution of various hydrolyzed species of uranyl ions with solution pH have been compared with uranyl sorption isotherm on these oxides. Sorption edge in all the cases occurs when free hydroxyl groups are available on the surface and pH surf is sufficiently high to favor the formation of dimer-like species on the surface. A new model for the sorption process, called surface hydrolysis model, which explains these and other features of uranyl sorption on hydrous oxides has been proposed. The model visualizes the sorption process as linking of uranyl ions with two adjacent free surface hydroxyl groups without deprotonation (provided the surface pH is high for the hydrolysis of uranyl ions) and formation of dimer-like structures on the surface. The new model has been successfully applied to the present and other available data on uranyl ion sorption on hydrous oxides. (author)

  13. Sorption equilibria of ethanol on cork.

    Science.gov (United States)

    Lequin, Sonia; Chassagne, David; Karbowiak, Thomas; Bellat, Jean-Pierre

    2013-06-05

    We report here for the first time a thermodynamic study of gaseous ethanol sorption on raw cork powder and plate. Our study aims at a better understanding of the reactivity of this material when used as a stopper under enological conditions, thus in close contact with a hydroethanolic solution, wine. Sorption−desorption isotherms were accurately measured by thermogravimetry at 298 K in a large range of relative pressures. Sorption enthalpies were determined by calorimetry as a function of loading. Sorption−desorption isotherms exhibit a hysteresis loop probably due to the swelling of the material and the absorption of ethanol. Surprisingly, the sorption enthalpy of ethanol becomes lower than the liquefaction enthalpy as the filling increases. This result could be attributed to the swelling of the material, which would generate endothermic effects. Sorption of SO₂ on cork containing ethanol was also studied. When the ethanol content in cork is 2 wt %, the amount of SO₂ sorbed is divided by 2. Thus, ethanol does not enhance the sorption rate for SO₂ but, on the contrary, decreases the SO₂ sorption activity onto cork, probably because of competitive sorption mechanisms.

  14. Sorption of streptococcus faecium to glass

    International Nuclear Information System (INIS)

    Oerstavik, D.

    1977-01-01

    A method has been developed by which to study the sorption of Streptococcus faecium to soda-lime cover glasses. Conditions were chosen to minimize the influence on sorption of bacterial polymer production, passive sorption being studied rather than attachment mediated by metabolic activities. Sorption of S. faecium increased with increasing temperature (to 50degC), time, and cell concentration, but equilibrium apparently was not reached even after incubation for 8 hours or at a cell concentration of 3 x 10 10 per ml. Sorption increased with solute molarity up to 0.1 M concentration of NaCl and KCl, indicating an effect of the electrical double layers on the apposition of cells to the glass surface. Desorption of bacteria could be obtained after multiple washings of the glasses in buffer or by the action of Tween 80, but not if sorbed bacteria were left in distilled water, various salt solutions, urea, or in suspensions of unlabelled bacteria. It was concluded that sorption occurred as a result of chemical interactions between the glass and the cell surface. Tween 80 at a concentration of 1 per cent inhibited sorption to 26 per cent of buffer controls, 2 M urea was less effective, and 1 M NaCl was without effect. It is suggested that hydrophobic interactions may be of importance in the binding of S. faecium to glass. (author)

  15. Heavy metal sorption by microalgae

    International Nuclear Information System (INIS)

    Sandau, E.; Sandau, P.; Pulz, O.

    1996-01-01

    Viable microalgae are known to be able to accumulate heavy metals (bioaccumulation). Against a background of the increasing environmental risks caused by heavy metals, the microalgae Chlorella vulgaris and Spirulina platensis and their potential for the biological removal of heavy metals from aqueous solutions were taken as an example for investigation. Small-scale cultivation tests (50 l) with Cd-resistant cells of Chlorella vulgaris have shown that approx. 40% of the added 10 mg Cd/l was removed from the solution within seven days. At this heavy metal concentration sensitive cells died. Non-viable microalgae are able to eliminate heavy metal ions in a short time by biosorption in uncomplicated systems, without any toxicity problems. Compared with original biomasses, the sorption capacity of microalgal by-products changes only insignificantly. Their low price makes them economical. (orig.)

  16. Metal Sorption to Dolomite Surfaces

    International Nuclear Information System (INIS)

    Brady, P.V.; Papenguth, H.W.; Kelly, J.W.

    1999-01-01

    Potential human intrusion into the Waste Isolation Pilot Plant (WIPP) might release actinides into the Culebra Dolomite where sorption reactions will affect of radiotoxicity from the repository. Using a limited residence time reactor the authors have measured Ca, Mg, Nd adsorption/exchange as a function of ionic strength, P CO2 , and pH at 25 C. By the same approach, but using as input radioactive tracers, adsorption/exchange of Am, Pu, U, and Np on dolomite were measured as a function of ionic strength, P CO2 , and pH at 25 C. Metal adsorption is typically favored at high pH. Calcium and Mg adsorb in near-stoichiometric proportions except at high pH. Adsorption of Ca and Mg is diminished at high ionic strengths (e.g., 0.5M NaCl) pointing to association of Na + with the dolomite surface, and the possibility that Ca and Mg sorb as hydrated, outer-sphere complexes. Sulfate amplifies sorption of Ca and Mg, and possibly Nd as well. Exchange of Nd for surface Ca is favored at high pH, and when Ca levels are low. Exchange for Ca appears to control attachment of actinides to dolomite as well, and high levels of Ca 2+ in solution will decrease Kds. At the same time, to the extent that high P CO2 increase Ca 2+ levels, JK d s will decrease with CO 2 levels as well, but only if sorbing actinide-carbonate complexes are not observed to form (Am-carbonate complexes appear to sorb; Pu-complexes might sorb as well; U-carbonate complexation leads to desorption). This indirect CO 2 effect is observed primarily at, and above, neutral pH. High NaCl levels do not appear to affect to actinide K d s

  17. Sorption of methylxanthines by different sorbents

    Science.gov (United States)

    Dmitrienko, S. G.; Andreeva, E. Yu.; Tolmacheva, V. V.; Terent'eva, E. A.

    2013-05-01

    Sorption of caffeine, theophylline, theobromine, diprophylline, and pentoxyphylline on different sorbents (supercross-linked polystyrene, surface-modified copolymer of styrene and divinylbenzene Strata-X, and carbon nanomaterials Taunit and Diasorb-100-C16T) was studied in a static mode in an effort to find new sorbents suitable for sorption isolation and concentration of methylxanthines. The peculiarities of sorption of methylxanthines were explained in relation to the solution acidity, the nature of the sorbates and their concentration, the nature of the solvent, and the structural characteristics of the sorbents.

  18. Sorption isolation of strontium from seawater

    International Nuclear Information System (INIS)

    Avramenko, V.A.; Zheleznov, V.V.; Kaplun, E.V.; Sokol'nitskaya, T.A.; Yukhkam, A.A.

    2001-01-01

    Sorption isolation of strontium from seawater is considered and prospects of use of selective adsorbents for purification of seawater or liquid radioactive wastes mixed with seawater from 90 Sr are discussed. Comparative analysis of sorptive properties of adsorbents of different nature is done. It is shown that sorption-reagent materials developed by authors can to afford effective separation of 90 Sr from seawater. Possible mechanism of strontium sorption by these adsorbents is considered. The prospect of their use for purification of liquid radioactive wastes from strontium is shown [ru

  19. Re-thinking residential mobility

    Science.gov (United States)

    van Ham, Maarten; Findlay, Allan M.

    2015-01-01

    While researchers are increasingly re-conceptualizing international migration, far less attention has been devoted to re-thinking short-distance residential mobility and immobility. In this paper we harness the life course approach to propose a new conceptual framework for residential mobility research. We contend that residential mobility and immobility should be re-conceptualized as relational practices that link lives through time and space while connecting people to structural conditions. Re-thinking and re-assessing residential mobility by exploiting new developments in longitudinal analysis will allow geographers to understand, critique and address pressing societal challenges. PMID:27330243

  20. Large-Scale Residential Demolition

    Science.gov (United States)

    The EPA provides resources for handling residential demolitions or renovations. This includes planning, handling harmful materials, recycling, funding, compliance assistance, good practices and regulations.

  1. PCB congener sorption to carbonaceous sediment components: Macroscopic comparison and characterization of sorption kinetics and mechanism

    International Nuclear Information System (INIS)

    Choi, Hyeok; Al-Abed, Souhail R.

    2009-01-01

    Sorption of polychlorinated biphenyls (PCBs) to sediment is a key process in determining their mobility, bioavailability, and chemical decomposition in aquatic environments. In order to examine the validity of currently used interpretation approaches for PCBs sorption, comparative results on 2-chlorobiphenyl sorption to carbonaceous components in sediments (activated carbon, carbon black, coal, soot, graphite, flyash, wood) were macroscopically correlated with the structural, morphological, crystallographic, and compositional properties of the carbonaceous components. Since the Freundlich sorption constant, K F (L kg -1 ) spanned several orders of magnitude, ranging from log K F of 6.13-5.27 for activated carbon, 5.04 for carbon black, 3.83 for coal to 3.08 for wood, organic carbon partitioning approach should be more specifically categorized, considering the various forms, nature and origins of organic carbon in sediment. Sorption rate constants and fraction parameters, which were numerically defined from empirical kinetic model with fast and slow sorption fractions, were closely related to the physicochemical properties of the carbonaceous components. Sorption interpretation approaches with a specific property and viewpoint, such as organic carbon partitioning, soot carbon distribution, or surface area correlation, did not properly explain the overall results on sorption capacity, fast and slow sorption kinetics, and partitioning coefficient. It is also important to emphasize the heterogeneous nature of sediment and the difficulties of encompassing the partitioning among its carbonaceous components.

  2. PCB congener sorption to carbonaceous sediment components: Macroscopic comparison and characterization of sorption kinetics and mechanism

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Hyeok [National Risk Management Research Laboratory, U.S. Environmental Protection Agency, 26 West Martin Luther King Drive, Cincinnati, OH 45268 (United States); Al-Abed, Souhail R., E-mail: al-abed.souhail@epa.gov [National Risk Management Research Laboratory, U.S. Environmental Protection Agency, 26 West Martin Luther King Drive, Cincinnati, OH 45268 (United States)

    2009-06-15

    Sorption of polychlorinated biphenyls (PCBs) to sediment is a key process in determining their mobility, bioavailability, and chemical decomposition in aquatic environments. In order to examine the validity of currently used interpretation approaches for PCBs sorption, comparative results on 2-chlorobiphenyl sorption to carbonaceous components in sediments (activated carbon, carbon black, coal, soot, graphite, flyash, wood) were macroscopically correlated with the structural, morphological, crystallographic, and compositional properties of the carbonaceous components. Since the Freundlich sorption constant, K{sub F} (L kg{sup -1}) spanned several orders of magnitude, ranging from log K{sub F} of 6.13-5.27 for activated carbon, 5.04 for carbon black, 3.83 for coal to 3.08 for wood, organic carbon partitioning approach should be more specifically categorized, considering the various forms, nature and origins of organic carbon in sediment. Sorption rate constants and fraction parameters, which were numerically defined from empirical kinetic model with fast and slow sorption fractions, were closely related to the physicochemical properties of the carbonaceous components. Sorption interpretation approaches with a specific property and viewpoint, such as organic carbon partitioning, soot carbon distribution, or surface area correlation, did not properly explain the overall results on sorption capacity, fast and slow sorption kinetics, and partitioning coefficient. It is also important to emphasize the heterogeneous nature of sediment and the difficulties of encompassing the partitioning among its carbonaceous components.

  3. Techno-economic analysis of sorption-enhanced steam methane reforming in a fixed bed reactor network integrated with fuel cell

    Science.gov (United States)

    Diglio, Giuseppe; Hanak, Dawid P.; Bareschino, Piero; Mancusi, Erasmo; Pepe, Francesco; Montagnaro, Fabio; Manovic, Vasilije

    2017-10-01

    Sorption-enhanced steam methane reforming (SE-SMR) is a promising alternative for H2 production with inherent CO2 capture. This study evaluates the techno-economic performance of SE-SMR in a network of fixed beds and its integration with a solid oxide fuel cell (SE-SMR-SOFC) for power generation. The analysis revealed that both proposed systems are characterised by better economic performance than the reference systems. In particular, for SE-SMR the levelised cost of hydrogen is 1.6 €ṡkg-1 and the cost of CO2 avoided is 29.9 €ṡtCO2-1 (2.4 €ṡkg-1 and 50 €ṡtCO2-1, respectively, for SMR with CO2 capture) while for SE-SMR-SOFC the levelised cost of electricity is 0.078 €ṡkWh-1 and the cost of CO2 avoided is 36.9 €ṡtCO2-1 (0.080 €ṡkWh-1 and 80 €ṡtCO2-1, respectively, for natural gas-fired power plant with carbon capture). The sensitivity analysis showed that the specific cost of fuel and the capital cost of fuel cell mainly affect the economic performance of SE-SMR and SE-SMR-SOFC, respectively. The daily revenue of the SE-SMR-SOFC system is higher than that of the natural gas-fired power plant if the difference between the carbon tax and the CO2 transport and storage cost is > 6 €ṡtCO2-1.

  4. Carbon dioxide sorption on EDTA modified halloysite

    Directory of Open Access Journals (Sweden)

    Waszczuk Patrycja

    2016-01-01

    Full Text Available In this paper the sorption study of CO2 on EDTA surface modified halloysite was conducted. In the paper chemical modification of halloysite from the Dunino deposit (Poland and its influence on sorption of CO2 are presented. A halloysite samples were washed with water-EDTA 1% solution, centrifuged to separate liquid and impurities and dried. The samples were tested for the sorption capacity using a manometric method with pressure up to 3 MPa. A Langmuir adsorption model was fitted to the data. The results showed that EDTA had a limited effect on the increase of sorption potential at low pressure and the samples exhibited similar results to that ones treated solely with the water solution.

  5. Sorption of metaldehyde using granular activated carbon

    Directory of Open Access Journals (Sweden)

    S. Salvestrini

    2017-09-01

    Full Text Available In this work, the ability of granular activated carbon (GAC to sorb metaldehyde was evaluated. The kinetic data could be described by an intra-particle diffusion model, which indicated that the porosity of the sorbent strongly influenced the rate of sorption. The analysis of the equilibrium sorption data revealed that ionic strength and temperature did not play any significant role in the metaldehyde uptake. The sorption isotherms were successfully predicted by the Freundlich model. The GAC used in this paper exhibited a higher affinity and sorption capacity for metaldehyde with respect to other GACs studied in previous works, probably as a result of its higher specific surface area and high point of zero charge.

  6. Study of sorption of technetium on pyrrhotine

    International Nuclear Information System (INIS)

    Shen Dong; Fan Xianhua; Su Xiguang; Zeng Jishu

    2001-01-01

    The sorption behaviors of technetium on pyrrhotine are studied with batch experiment and dilute sulfuric acid is used to dissolve the technetium adsorbed on pyrrhotine. Sorption and desorption experiment are performed under aerobic and anaerobic conditions (inert gas box). The results show that a significant sorption of technetium on pyrrhotine is found under aerobic and anaerobic conditions, and the sorption on the mineral is supposed to be due to the reduction of TcO 4 - to insoluble TcO 2 ·nH 2 O. Desorption process of the sorbed technetium into dilute sulfuric acid is found to be different under aerobic and anaerobic conditions. On addition of H 2 O 2 to the leach solution a sudden increase of the technetium concentration is observed

  7. Radionuclide sorption on granitic drill core material

    International Nuclear Information System (INIS)

    Eriksen, T.E.; Locklund, B.

    1987-11-01

    Distribution ratios were determined for Sr-85, Cs-134 and Eu-152 on crushed granite and fissure coating/filling material from Stripa mines. Measurements were also carried out on intact fissure surfaces. The experimental data for Sr-85, Cs-134 on crushed material can be accomodated by a sorption model based on the assumption that the crushed material consists of porous spheres with outer and inner surfaces available for sorption. In the case of Eu-152 only sorption on the outer surfaces of the crushed material was observed. The absence of sorption on inner surfaces is most probably due to high depletion of the more strongly sorbed Eu-152 in the water phase and very low diffusivity of Eu-152 in the sorbed state. (orig./HP)

  8. ASHRAE and residential ventilation

    Energy Technology Data Exchange (ETDEWEB)

    Sherman, Max H.

    2003-10-01

    In the last quarter of a century, the western world has become increasingly aware of environmental threats to health and safety. During this period, people psychologically retreated away from outdoors hazards such as pesticides, smog, lead, oil spills, and dioxin to the seeming security of their homes. However, the indoor environment may not be healthier than the outdoor environment, as has become more apparent over the past few years with issues such as mold, formaldehyde, and sick-building syndrome. While the built human environment has changed substantially over the past 10,000 years, human biology has not; poor indoor air quality creates health risks and can be uncomfortable. The human race has found, over time, that it is essential to manage the indoor environments of their homes. ASHRAE has long been in the business of ventilation, but most of the focus of that effort has been in the area of commercial and institutional buildings. Residential ventilation was traditionally not a major concern because it was felt that, between operable windows and envelope leakage, people were getting enough outside air in their homes. In the quarter of a century since the first oil shock, houses have gotten much more energy efficient. At the same time, the kinds of materials and functions in houses changed in character in response to people's needs. People became more environmentally conscious and aware not only about the resources they were consuming but about the environment in which they lived. All of these factors contributed to an increasing level of public concern about residential indoor air quality and ventilation. Where once there was an easy feeling about the residential indoor environment, there is now a desire to define levels of acceptability and performance. Many institutions--both public and private--have interests in Indoor Air Quality (IAQ), but ASHRAE, as the professional society that has had ventilation as part of its mission for over 100 years, is the

  9. Sorption of heteropoly acids by polyurethane foam

    International Nuclear Information System (INIS)

    Dmitreinko, S.G.; Goncharova, L.V.; Runov, V.K.; Zakharov, V.N.; Aslanova, L.A.

    1997-01-01

    Sorption of oxidized and reduced forms of molybdosilicic, molybdophosphoric and molybdovanadophosphoric acids by polyurethane foam based on ethers and esters is studied. On the basis of sorption dependence on solution pH, polyurethane foam type and spectral characteristics of sorbates the suggestion has been made that in the polyurethane foam phase there are two main types of sorbent-sorbate interaction: electrostatic (ion-ion) and with hydrogen bond formation: and it is impossible to determine the contribution of every interaction

  10. Sorption of organophosphate esters by carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Yan, Wei; Yan, Li [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 (China); Duan, Jinming [School of Environmental and Municipal Engineering, Xi’an University of Architecture and Technology, Xi’an 710055 (China); Jing, Chuanyong, E-mail: cyjing@rcees.ac.cn [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 (China)

    2014-05-01

    Graphical abstract: The interfacial interactions between the OPE molecules and CNTs. - Highlights: • Oxygen-containing groups on CNTs change the sorption property for OPEs. • Molecular configuration of OPEs has insignificant impact on their sorption. • Hydrophobic, π–π EDA and Brønsted acid–base interaction occurred between the CNTs and OPEs. - Abstract: Insights from the molecular-level mechanism of sorption of organophosphate esters (OPEs) on carbon nanotubes (CNTs) can further our understanding of the fate and transport of OPEs in the environment. The motivation for our study was to explore the sorption process of OPEs on multi-walled CNTs (MWCNTs), single-walled CNTs (SWCNTs) and their oxidized counterparts (O-MWCNTs and O-SWCNTs), and its molecular mechanism over a wide concentration range. The sorption isotherm results revealed that the hydrophobicity of OPEs dominated their affinities on a given CNT and the π–π electron donor–acceptor (EDA) interaction also played an important role in the sorption of aromatic OPEs. This π–π EDA interaction, verified with Raman and FT-IR spectroscopy, could restrict the radial vibration of SWCNTs and affect the deformation vibration γ(CH) bands of OPE molecules. The OPE surface coverage on CNTs, estimated using the nonlinear Dubinin–Ashtakhov model, indicated that the oxygen-containing functional groups on CNTs could interact with water molecules by H-bonding, resulting in a decrease in effective sorption sites. In addition, FTIR analysis also confirmed the occurrence of Brønsted acid–base interactions between OPEs and surface OH groups of SWCNTs. Our results should provide mechanistic insights into the sorption mechanism of OPE contaminants on CNTs.

  11. Sorption of cesium and uranium to Feldspar

    International Nuclear Information System (INIS)

    Wijland, G.C.; Pennders, R.M.J.

    1990-07-01

    Within safety assessment studies, for nuclear waste disposal in deep geologic formations, calculation for the migration of radionuclides through the geosphere are often carried out with models taking sorption into account. In the past 8 years the insight grew that other physico-chemical processes, besides sorption, could affect migration behaviour. While the currently used transport models were being improved taking either linear or non-linear sorption into account, the coupling of geochemical and transport models came into scope. In spite of these developments models which are still based on the sorption theory are frequently applied in studying migration behaviour of radionuclides. This is caused by the necessity of making preliminary pronouncements, while coupled models are still in stage of development and thermodynamic data are very limited available. Therefore one has to obtain insight in the reliability of the models based on the sorption theory. within the sorption database there is a lack of knowledge about mineralogy, composition of the fluid and the experimental conditions underlying the data. Therefore the Expert Group on geochemical Modelling supported by the Finnish proposal in order to obtain insight in the possible deviation of the sorption coefficients that can be estimated from experiments performed with standard samples, fluid composition and experimental conditions. Nine laboratories from OECD membership countries took part in this intercalibration study. In the framework of the Dutch safety assessment studies the Dutch National Institute of Public health and Environmental protection (RIVM) has decided to participate in this exercise. In this report the results are presented of sorption experiments for cesium and natural Uranium to Feldspar. (H.W.). 4 refs.; 1 fig.; 7 tabs

  12. Sorption of fomesafen in Brazilian soils

    OpenAIRE

    Silva,G.R.; D'Antonino,L.; Faustino,L.A.; Silva,A.A.; Ferreira,F.A.; Texeira,C.C.

    2013-01-01

    The study of the dynamics of a herbicide in the soil focus on the interactions with environmental components to obtain agronomic efficiency, ensuring selectivity to the culture and risk reduction of environmental impact. This study evaluated the sorption process of fomesafen in the Brazilian soils Ultisol, Cambisol, and Organosol. Besides soil, washed sand was used as an inert material for determination of the sorption ratio of fomesafen in the soil. The bioassay method was applied, using Sor...

  13. Kinetics of strontium sorption in calcium phosphate

    International Nuclear Information System (INIS)

    Bacic, S.; Komarov, V.F.; Vukovic, Z.

    1989-01-01

    Kinetics of strontium sorption by highly dispersed solids: tricalcium phosphate (Ca 3 (PO 4 ) 2 , TCP) and hydroxyapatite (Ca 5 (PO 4 ) 3 )H, HAP) were investigated. Analysis of sorption data was made taking into consideration composition and morphology of ultra micro particles. Conclusion is that the isomorphous strontium impurity is structurally sensitive element for calcium phosphate. It was determined that the beginning of strontium desorption corresponds to the beginning of transformation of the TCP - HAP (author)

  14. Comparison of LCA results of low temperature heat plant using electric heat pump, absorption heat pump and gas-fired boiler

    International Nuclear Information System (INIS)

    Nitkiewicz, Anna; Sekret, Robert

    2014-01-01

    Highlights: • Usage of geothermal heat pump can bring environmental benefits. • The lowest environmental impact for whole life cycle is obtained for absorption heat pump. • The value of heat pump COP has a significant influence on environmental impact. • In case of coal based power generation the damage to human health is significant. - Abstract: This study compares the life cycle impacts of three heating plant systems which differ in their source of energy and the type of system. The following heating systems are considered: electric water-water heat pump, absorption water-water heat pump and natural gas fired boiler. The heat source for heat pump systems is low temperature geothermal source with temperature below 20 °C and spontaneous outflow 24 m 3 /h. It is assumed that the heat pumps and boiler are working in monovalent system. The analysis was carried out for heat networks temperature characteristic at 50/40 °C which is changing with outdoor temperature during heating season. The environmental life cycle impact is evaluated within life cycle assessment methodological framework. The method used for life cycle assessment is eco-indicator ‘99. The functional unit is defined as heating plant system with given amount of heat to be delivered to meet local heat demand in assumed average season. The data describing heating plant system is derived from literature and energy analysis of these systems. The data describing the preceding life cycle phases: extraction of raw materials and fuels, production of heating devices and their transportation is taken from Ecoinvent 2.0 life cycle inventory database. The results were analyzed on three levels of indicators: single score indicator, damage category indicators and impact category indicator. The indicators were calculated for characterization, normalization and weighting phases as well. SimaPro 7.3.2 is the software used to model the systems’ life cycle. The study shows that heating plants using a low

  15. Iodine sorption by microwave irradiated hydrotalcites

    Energy Technology Data Exchange (ETDEWEB)

    Paredes, S.P. [Universidad Autonoma de Puebla, Facultad de Ciencias Quimicas, C.P. 72570, Puebla, Pue (Mexico); Instituto Politecnico Nacional, ESIQIE, C.P. 07738, Mexico, D.F. (Mexico); Fetter, G. [Universidad Autonoma de Puebla, Facultad de Ciencias Quimicas, C.P. 72570, Puebla, Pue (Mexico)]. E-mail: geolarfetter@yahoo.com.mx; Bosch, P. [Universidad Nacional Autonoma de Mexico, Instituto de Investigaciones en Materiales, C.P. 04510, Mexico, D.F. (Mexico); Bulbulian, S. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, C.P. 11801, Mexico, D.F. (Mexico)

    2006-12-15

    Mg-Al hydrotalcite-like compounds (HT) were prepared by the microwave method on the one hand with ethoxide-acetylacetonate and on the other with acetylacetonate as precursors. They presented a maximum sorption capacity of 2.179 and 1.517 meq of {sup 131}I{sup -}/g of hydrotalcite respectively. When the hydrotalcites were calcined and rehydrated in a {sup 131}I{sup -} solution, iodine sorption decreased in both samples to 1.515 and 1.446, respectively. The corresponding value for nitrated hydrotalcite which was prepared by the conventional method for comparison purposes, was 0.570. The radionuclide content in hydrotalcites was determined by {gamma}-spectrometry. {sup 131}I{sup -} sorption is dependent on two main parameters: one is the type of the interlayer organic material and the second the surface area. It was found that hydrotalcites prepared with ethoxide-acetylacetonate were better sorbents for {sup 131}I{sup -} than those with acetylacetonate. Still, if the specific surface area increased, {sup 131}I{sup -}sorption increased as well; nitrated HT resulted in low specific surface area and a low sorption capacity. It is, therefore, concluded that organic residues present in the samples prepared by the microwave method favor the sorption of radioactive anions, in particular {sup 131}I{sup -} if compared with nitrated and/or carbonate interlayered hydrotalcites.

  16. Migration and sorption phenomena in packaged foods.

    Science.gov (United States)

    Gnanasekharan, V; Floros, J D

    1997-10-01

    Rapidly developing analytical capabilities and continuously evolving stringent regulations have made food/package interactions a subject of intense research. This article focuses on: (1) the migration of package components such as oligomers and monomers, processing aids, additives, and residual reactants in to packaged foods, and (2) sorption of food components such as flavors, lipids, and moisture into packages. Principles of diffusion and thermodynamics are utilized to describe the mathematics of migration and sorption. Mathematical models are developed from first principles, and their applicability is illustrated using numerical simulations and published data. Simulations indicate that available models are system (polymer-penetrant) specific. Furthermore, some models best describe the early stages of migration/sorption, whereas others should be used for the late stages of these phenomena. Migration- and/or sorption-related problems with respect to glass, metal, paper-based and polymeric packaging materials are discussed, and their importance is illustrated using published examples. The effects of migrating and absorbed components on food safety, quality, and the environment are presented for various foods and packaging materials. The impact of currently popular packaging techniques such as microwavable, ovenable, and retortable packaging on migration and sorption are discussed with examples. Analytical techniques for investigating migration and sorption phenomena in food packaging are critically reviewed, with special emphasis on the use and characteristics of food-simulating liquids (FSLs). Finally, domestic and international regulations concerning migration in packaged foods, and their impact on food packaging is briefly presented.

  17. Residential Mechanical Precooling

    Energy Technology Data Exchange (ETDEWEB)

    German, Alea [Davis Energy Group, Davis, CA (United States). Alliance for Residential Building Innovation (ARBI); Hoeschele, Marc [Davis Energy Group, Davis, CA (United States). Alliance for Residential Building Innovation (ARBI)

    2014-12-01

    Residential air conditioning (AC) represents a challenging load for many electric utilities with poor load factors. Mechanical precooling improves the load factor by shifting cooling operation from on-peak to off-peak hours. This provides benefits to utilities and the electricity grid, as well as to occupants who can take advantage of time-of-use (TOU) electricity rates. Performance benefits stem from reduced compressor cycling, and shifting condensing unit operation to earlier periods of the day when outdoor temperatures are more favorable to operational efficiency. Finding solutions that save energy and reduce demand on the electricity grid is an important national objective and supports key Building America goals. The Alliance for Residential Building Innovation team evaluated mechanical AC precooling strategies in homes throughout the United States. EnergyPlus modeling was used to evaluate two homes with different performance characteristics in seven climates. Results are applicable to new construction homes and most existing homes built in the last 10 years, as well as fairly efficient retrofitted homes. A successful off-peak AC strategy offers the potential for increased efficiency and improved occupant comfort, and promotes a more reliable and robust electricity grid. Demand response capabilities and further integration with photovoltaic TOU generation patterns provide additional opportunities to flatten loads and optimize grid impacts.

  18. Residential energy demand in Brazil

    International Nuclear Information System (INIS)

    Arouca, M.; Gomes, F.M.; Rosa, L.P.

    1981-01-01

    The energy demand in Brazilian residential sector is studied, discussing the methodology for analyzing this demand from some ideas suggested, for developing an adequate method to brazilian characteristics. The residential energy consumption of several fuels in Brazil is also presented, including a comparative evaluation with the United States and France. (author)

  19. Influence of sorption competition on sorption data for MX-80 bentonite used in performance assessment

    International Nuclear Information System (INIS)

    Bradbury, M.H.; Baeyens, B.; Marques Fernandes, M.

    2012-01-01

    Document available in extended abstract form only. In order to obtain a (quasi) mechanistic understanding of radionuclide uptake on clay minerals and argillaceous rocks, the majority of sorption experiments have been carried out on purified clay minerals such as montmorillonite and illite at trace concentrations (sorption edges), or as a function of concentration (sorption isotherms), with a single radionuclide under well-defined conditions in simple background electrolytes. As a result of such studies the 2 site proto-lysis non electrostatic surface complexation cation exchange (2SPNE SC/CE) sorption model, was developed and has been successfully applied to quantitatively describe the uptake of numerous radionuclides of differing valences as a function of pH and concentration on montmorillonite. In a deep geological repository for high level waste, stable impurities arise from many sources: they are present in the pore waters, in the tunnel back fill materials and host rock formations, they arise from the corrosion of the carbon steel canister and finally they are dissolved from the spent fuel and vitrified high level waste simultaneously with the radionuclides. These impurities, which are an integral part of a realistic repository system, can potentially compete with radionuclides for the sorption sites on the backfill materials and host rock and thus reduce their uptake on them. The influence of competitive sorption is not intrinsically included (or only partly so) in the sorption model. It is clearly an inherently important issue to quantify the influence of sorption competition on the transport of released radionuclides through the multi-barrier system in a deep repository. In this study an extreme case of a competitive sorption scenario in the near field of a HLW repository is presented. Two factors are considered: one associated with the high concentrations and the other with competitive sorption effects. The tendency in both cases is to cause a reduction in

  20. Radionuclides sorption in clay soils

    International Nuclear Information System (INIS)

    Siraky, G.; Lewis, C.; Hamlat, S.; Nollmann, C.E.

    1987-01-01

    The sorption behaviour of clay soils is examined through a parametric study of the distribution coefficient (Kd) for the radionuclides of interest, Cs and Sr. This work is a preliminary stage of the migration studies of these nuclides in a porous medium (ground of Ezeiza, Argentina) and the evaluation of radiologic impact of the removal of low and intermediate activity wastes in shallow trenches. The determination of Kd is performed by a static technique or batch. The phases are separated by centrifugation at 20000 g during 1 hour. The activity of supernatant solution of Cs-137 and Sr-85 is measured in a detecting system of I Na(Tl) well-type. Two types of parameters were changed: a) those related to the determination method: phase separation (centrifugation vs. centrifugation plus filtration); equilibrium period, ratio solid/liquid; b) those related to the geochemical system: pH of contact solution, carrier concentration, competitive ions, ionic strength, desorption. It was observed that the modification of parameters in the Kd-measurement does not change the order of magnitude of results. (Author)

  1. Neptunium(V) sorption on kaolinite

    Energy Technology Data Exchange (ETDEWEB)

    Amayri, S.; Jermolajev, A.; Reich, T. [Mainz Univ. (Germany). Inst. of Nuclear Chemistry

    2011-07-01

    The sorption behavior of neptunium(V) onto the clay mineral kaolinite was studied in batch experiments under different experimental conditions: [Np(V)] = 7 x 10{sup -12}-8 x 10{sup -6} M, solid-to-liquid ratio 2-20 g L{sup -1}, I = 0.1 and 0.01 M NaClO{sub 4}, pH = 6-10, ambient air and Ar atmosphere. The short-lived isotope {sup 239}Np (T{sub 1/2} = 2.36 d) was used instead of {sup 237}Np (T{sub 1/2} = 2.14 x 10{sup 6} a) to study the sorption behavior of Np(V) at environmentally-relevant concentrations, i.e., 7 x 10{sup -12} M Np. In addition, {sup 239}Np(V) served as tracer to measure sorption isotherms over six orders of magnitude in Np concentration (4.8 x 10{sup -12}-1.0 x 10{sup -4} M). The results show that Np(V) sorption on kaolinite is strongly influenced by pH, CO{sub 2}, and ionic strength. The sorption of 8 x 10{sup -6} M Np(V) at pH 9.0, and ionic strength of 0.1 M NaClO{sub 4} was proportional to the solid-to-liquid ratio of kaolinite in the range of 2-10 g L{sup -1}. In the absence of CO{sub 2}, the Np(V) uptake increased continuously with increasing pH value up to 97% at pH 10. Under ambient CO{sub 2}, the sorption of Np decreased above pH 8 up to zero at pH 10. An increase of Np(V) concentration from 7 x 10{sup -12} to 8 x 10{sup -6} M resulted in a shift of the sorption pH edge by up to one pH unit to higher pH values. The ionic strength influenced the Np(V) sorption onto kaolinite only in the presence of ambient CO{sub 2}. Under Ar atmosphere the sorption of Np(V) was independent from ionic strength, indicating the formation of inner-sphere complexes of Np(V) with kaolinite. Time-dependent batch experiments at pH 9.0 under ambient CO{sub 2} showed that the sorption of Np(V) on kaolinite is fast and fully reversible over six orders in Np(V) concentration. (orig.)

  2. Sorption behavior of neptunium on bentonite -- Effect of calcium ion on the sorption

    International Nuclear Information System (INIS)

    Kozai, Naofumi; Ohnuki, Toshihiko; Muraoka, Susumu

    1995-01-01

    The sorption behavior of neptunium on bentonite was studied with batch type sorption and desorption experiments over a pH range of 2 to 8. A series of parallel studies using Na-smectite, Ca-smectite and admixtures of Na-smectite and calcite quantified the capacity of Ca 2+ (which occurs in bentonite as an exchangeable cation of smectite and as a component of calcite) to inhibit the sorption of neptunium. The distribution coefficient (K d ) of neptunium for bentonite was constant from pH 2 to 7, while for pure Na-smectite K d increased below pH 5 due to specific sorption of neptunium on Na-smectite. Specific sorption was defined as occurring when neptunium could be desorbed by a strong acid (1 M HCl) but was stable in the presence of 1 M KCl. It was found that the quantity of neptunium sorbed on Na-smectite was inversely proportional to the concentration of Ca 2+ in solution, an effect most pronounced at pH 2+ limits the specific sorption capacity of Na-smectite for neptunium. Similarly, in the mixture of Na-smectite and calcite, sufficient Ca 2+ was solubilized to depress neptunium sorption. This investigation demonstrates that Ca 2+ contained in bentonite as exchangeable cation and released from calcite reduces the specific sorption of neptunium

  3. Effects of sorption behaviour on contaminant migration

    International Nuclear Information System (INIS)

    Melnyk, T.W.

    1985-11-01

    The effects of sorption behaviour on contaminant migration in groundwater systems are varied. Retardation of migration and dispersive effects can vary widely and contaminant concentration profiles can take a number of different shapes. This report examines the nature of some of these effects, especially those due to sorption behaviours that are dependent on the concentration of the contaminant in the groundwater. The effects are calculated using, in most cases, analytical solutions to the chemical equations imbedded in a simple reaction-cell or box-model transport algorithm. The hydrogeological parameters are held constant, and radioactive decay and hydrodynamic dispersion are excluded. A general discussion of the role of sorption equations in transport modelling is followed by presentation of migration results for a number of models of sorption behaviour varying from linear isotherms, Langmuir, Freundlich and ion-exchange isotherms, to precipitation reactions and multiple-site sorption reactions. The results are compared and general conclusions are drawn about the various migration behaviours calculated. The conclusions are that equilibrium sorption of trace contaminants can be modelled with linear isotherms (constant distribution coefficients or constant retardation factors) but the evaluation and extrapolation of the distribution coefficient are not easy. Nonlinear isotherms lead to unsymmetrical migration fronts. A comparison of Freundlich and linear isotherms is made. Sorption/desorption kinetic factors can be significant on the time scale of laboratory experiments and can cause large dispersive effects. Slow but important reactions can be missed altogether. Precipitation or mineralization behaviour cannot be modelled with constant distribution coefficients. Also, mineralization reactions can be kinetically slow even on the geological time scale. 89 refs

  4. Technetium sorption by stibnite from natural water

    International Nuclear Information System (INIS)

    Peretroukhine, V.; Sergeant, C.; Deves, G.; Poulain, S.; Vesvres, M.H.; Thomas, B.; Simonoff, M.

    2006-01-01

    The sorption of technetium by powdered and polished mineral stibnite Sb 2 S 3 has been investigated in simulated and natural underground waters from the Meuse/Haute-Marne region (France). The sorption by powdered stibnite has been found to be complete under both aerobic and anaerobic conditions in batch experiments. The sorption rate is higher in the absence of oxygen than under aerobic condition. Increasing the temperature from 30 C to 60 C results in a rise of the sorption rate by 9.1 and 27 times under anaerobic and aerobic conditions, respectively. The observed differences in sorption kinetics in the presence and in absence of oxygen are explained by the interaction of oxygen with sulfide ion in aerobic conditions and by the reduction of technetium(VII) by iron(II) and by other impurities present in natural water and in the mineral, and by the subsequent sorption of Tc(IV) on stibnite under anaerobic conditions. The sorption on a polished mineral surface resulted in the formation of a technetium film, probably Tc 2 S 7 , with a thickness of 1-3 μg Tc/cm 2 pH 3-6 and 4-12 μg Tc/cm 2 at 9-12. The simultaneous formation of stibnite colloids with adsorbed technetium occurs at pH 9-12. The study of the technetium film on the mineral by proton induced X-ray emission analysis showed it to be at least one order of magnitude thinner on the SiO 2 impurities than on the main Sb 2 S 3 component and the iron impurities. (orig.)

  5. Computer simulation of molecular sorption in zeolites

    International Nuclear Information System (INIS)

    Calmiano, Mark Daniel

    2001-01-01

    The work presented in this thesis encompasses the computer simulation of molecular sorption. In Chapter 1 we outline the aims and objectives of this work. Chapter 2 follows in which an introduction to sorption in zeolites is presented, with discussion of structure and properties of the main zeolites studied. Chapter 2 concludes with a description of the principles and theories of adsorption. In Chapter 3 we describe the methodology behind the work carried out in this thesis. In Chapter 4 we present our first computational study, that of the sorption of krypton in silicalite. We describe work carried out to investigate low energy sorption sites of krypton in silicalite where we observe krypton to preferentially sorb into straight and sinusoidal channels over channel intersections. We simulate single step type I adsorption isotherms and use molecular dynamics to study the diffusion of krypton and obtain division coefficients and the activation energy. We compare our results to previous experimental and computational studies where we show our work to be in good agreement. In Chapter 5 we present a systematic study of the sorption of oxygen and nitrogen in five lithium substituted zeolites using a transferable interatomic potential that we have developed from ab initio calculations. We show increased loading of nitrogen compared to oxygen in all five zeolites studied as expected and simulate adsorption isotherms, which we compare to experimental and simulated data in the literature. In Chapter 6 we present work on the sorption of ferrocene in the zeolite NaY. We show that a simulated, low energy sorption site for ferrocene is correctly located by comparing to X-ray powder diffraction results for this same system. The thesis concludes with some overall conclusions and discussion of opportunities for future work. (author)

  6. Residential Energy Performance Metrics

    Directory of Open Access Journals (Sweden)

    Christopher Wright

    2010-06-01

    Full Text Available Techniques for residential energy monitoring are an emerging field that is currently drawing significant attention. This paper is a description of the current efforts to monitor and compare the performance of three solar powered homes built at Missouri University of Science and Technology. The homes are outfitted with an array of sensors and a data logger system to measure and record electricity production, system energy use, internal home temperature and humidity, hot water production, and exterior ambient conditions the houses are experiencing. Data is being collected to measure the performance of the houses, compare to energy modeling programs, design and develop cost effective sensor systems for energy monitoring, and produce a cost effective home control system.

  7. Sorption of cesium in intact rock

    International Nuclear Information System (INIS)

    Puukko, E.

    2014-04-01

    The mass distribution coefficient K d is used in performance assessment (PA) to describe sorption of a radionuclide on rock. The R d is determined using crushed rock which causes uncertainty in converting the R d values to K d values for intact rock. This work describes a method to determine the equilibrium of sorption on intact rock. The rock types of the planned Olkiluoto waste disposal site were T-series mica gneiss (T-MGN), T-series tonalite granodiorite granite gneiss (T-TGG), P-series tonalite granodiorite granite gneiss (P-TGG) and pegmatitic granite (PGR). These rocks contain different amount of biotite which is the main sorbing mineral. The sorption of cesium on intact rock slices was studied by applying an electrical field to speed up migration of cesium into the rock. Cesium is in the solution as a noncomplex cation Cs + and it is sorbed by ion exchange. The tracer used in the experiments was 134 Cs. The experimental sorption on the intact rock is compared with values calculated using the in house cation exchange sorption model (HYRL model) in PHREEQC program. The observed sorption on T-MGN and T-TGG rocks was close to the calculated values. Two PGR samples were from a depth of 70 m and three samples were from a depth of 150 m. Cesium sorbed more than predicted on the two 70 m PGR samples. The sorption of Cs on the three 150 m PGR samples was small which was consistent with the calculations. The pegmatitic granite PGR has the smallest content of biotite of the four rock types. In the case of P-TGG rock the observed values of sorption were only half of the calculated values. Two kind of slices were cut from P-TGG drill core. The slices were against and to the direction of the foliation of the biotite rims. The sorption of cesium on P-TGG rock was same in both cases. The results indicated that there was no effect of the directions of the electric field and the foliation of biotite in the P-TGG rock. (orig.)

  8. Recent progress in sorption mechanisms and models

    International Nuclear Information System (INIS)

    Fedoroff, M.; Lefevre, G.

    2005-01-01

    Full text of publication follows: Sorption-desorption phenomena play an important role in the migration of radioactive species in surface and underground waters. In order to predict the transport of these species, we need a good knowledge of sorption processes and data, together with reliable models able to be included in transport calculation. Traditional approaches based on experimentally determined distribution coefficients (Kd) and sorption isotherms have a limited predictive capability, since they are very sensitive to the numerous parameters characterizing the solution and the solid. Models based on thermodynamic equilibria were developed to account for the influence these parameters: the ion exchange model and the surface complexation models (2-pK mono-site, 1-pK multi-site, with several different electrostatic models: CCM, DLM, BSM, TLM,...). Although these models are very useful, studies performed in recent years showed that they have important theoretical and experimental limitations, which result in the fact that we must be very careful when we use them for extrapolating sorption data to long term and to large natural systems. Among all problems which can be found are: the possibility to fit a set of experimental data with different models, sometimes bad adequacy with the real sorption processes, some theoretical limitations such as a rigorous definition of reference and standard states in surface equilibria, slow kinetics which prevent from equilibrium achievement, irreversibility, solubility and evolution of solid phases... Through the increase of the number of sensitive spectroscopic methods, we are now able to know more about sorption processes at the atomic scale. Models such as the 1-pK CD-MUSIC model can account for the influence of orientation of the faces of the solid. More and more examples of the influence of this orientation on the sorption properties are known. Calculations performed by 'ab initio' modeling is also useful to predict the

  9. The NEA sorption data base (SDB)

    International Nuclear Information System (INIS)

    Ruegger, B.; Ticknor, K.

    1992-01-01

    The current NEA Sorption Data Base is developed to replace the former International Sorption Information Retrieval System (ISIRS) initiated at Pacific Northwest Laboratory and contains about 11,000 distribution coefficients with corresponding experimental condition parameters describing sorption of key nuclides for a large variety of solid and liquid phases. The SDB is designed to run on a micro-computer using the commercially available database software dBASE III Plus. For each recorded sorption experiment, the SDB provides a bibliographical reference, the most complete characterization of the solid and liquid phases available, a description of the experimental conditions and the distribution coefficient or retardation factor for each element studied. When available, parameters such as temperature, initial radionuclide concentration, pH, Eh, contact time, solid to solution ratio, sample origin, oxidation state and type of solution are included. The SDB provides information for a wide variety of rocks or geological materials, buffer backfill candidates, concretes/cements, elements (Am, Cs, Co, I, Np, Pu, Ra, Sr, Se, Tc, U and, to a lesser extent, Ag, Ba, C, Ce, Eu, Fe, Mn, Mo, Na, Nb, Ni, Pd, Pm, Ru, Sb, Sn, Y, Zn, and Zr), or radioisotopes. A compilation of sorption data like SDB provide a readily available source of data for radioactive waste repository performance assessments when site specific data are not available or essential, for example, during a site selection phase. 2 appendices

  10. Radionuclide sorption from the safety evaluation perspective

    International Nuclear Information System (INIS)

    1992-01-01

    Research and development directed towards the assessment of the long-term performance of radioactive waste disposal systems has been recognised as a priority area with a strong need for international co-operation and co-ordination. The ultimate aims is to promote the quality and credibility of safety assessment techniques for radioactive waste disposal. Sorption in the geosphere is one of the key processes for retarding the transport of radionuclide from the underground disposal facility to the biosphere. In many cases, sorption in the near field and in the biosphere is also important. A workshop, organised to favor discussion around a small number of invited papers, was held in October 1991: - to evaluate critically the way sorption processes are incorporated in performance assessment models; - to identify open issues of high priority, and; - to propose future activities to resolve these issues. These proceedings reproduce the invited papers and the conclusions and recommendations adopted by the workshop. Eight papers are in the INIS SCOPE. The main subjects studied are: sorption database comparison, sorption database development and three case studies, experimental techniques, adsorption models

  11. Sorption of radionuclides by tertiary clays

    International Nuclear Information System (INIS)

    Wagner, J.F.; Czurda, K.A.

    1990-01-01

    The sorption capacity of different clay types for some metals (Co, Cs, Sr and Zn), occurring as common radionuclides in radioactive waste deposits, had been analysed by a static (batch technique) and a dynamic method (percolation tests, in which the driving force is a hydraulic gradient). Sorption capacity generally increased with an increasing pH of solution. A decrease of sorption capacity had been observed in the order Zn > Cs ≥ Co > Sr for the batch and Cs > Zn > Sr > Co for the percolation tests. Clay marls showed a distinctly higher sorption respectively retention capacity as pure clays. Sorption capacity depends on solution parameters like type and concentration of radionuclide, pH, salt concentration, etc., and on rock parameters like mineral content (e.g. swelling clay minerals and carbonates), organic material, rock pH, micro fabric, etc. A third parameter of great influence is the contact time between clay and solution. The adsorption isotherms reflect two different adsorption mechanisms: a very rapid adsorption (a few minutes) on the external surfaces of clay minerals and a slow adsorption process (weeks and longer), due to the diffusion of metal ions into the interlayer space of clay minerals. 12 refs., 9 figs., 1 tab

  12. Moisture sorption of Thai red curry powder

    Directory of Open Access Journals (Sweden)

    Sudathip Inchuen

    2009-12-01

    Full Text Available Moisture sorption study was conducted on Thai red curry powder prepared by two different drying methods, viz. microwave and hot-air drying. Moisture sorption isotherms of the red curry powder at 30 C and water activity in the range of 0.113-0.970 were determined by a static gravimetric method. The isotherms exhibited Type III behaviour. The moisture sorption data were fitted to several sorption models and a non-linear regression analysis method was used to evaluate the constants of the sorption equations. The fit was evaluated using the coefficient of determination (R2, the reduced chi-square (2 and the root mean square error (RMSE. The GAB model followed by the Lewiski-3 model gave the best fit to the experimental data. The monolayer moisture content, taken as the safe minimum moisture level in the red curry powder, was determined using the BET equation and was found to range between 0.080 - 0.085 gram water per gram dry matter.

  13. Research on the Improvement of a Natural Gas Fired Burner for the CHP Application in a Central Heating Boiler using Radiant Burner Technology

    Energy Technology Data Exchange (ETDEWEB)

    Bieleveld, T.

    2010-08-15

    These days, the reduction of CO2 emissions from combustion devices is one of the main priorities for each design improvement. For the domestic use of the central heating boiler, Microgen Engine Corporation produces free piston Stirling engines for the Combined Heat and Power (CHP) application in these central heating boilers (Dutch: 'HRe ketel'). With CHP, the generation of electricity and heat are combined to increase overall efficiency, as heat is generally a waste product from the combustion to electric generation process. In this application, the Stirling engine, which can be defined as an external combustion engine, is heated by a natural gas fired engine-burner and cooled by a coolant flow. The heat transfer into the engine is converted into mechanical work and a heat flux from the engine. The mechanical work is used to produce electricity via a linear alternator. Heat in the flue gasses from the engine-burner is reused in a secondary burner and condensing heat exchanger. The coolant flow from the engine, after passing the secondary burner, is used for heating purposes. The heat transfer from engine-burner to the Stirling engine is analyzed and via several motivations it is found that it is favorable to improve fuel to electric conversion efficiency, for which the heat transfer efficiency of the engine-burner to the Stirling engine should be improved, as the engine design is not to be altered. From an initially developed linear free piston Stirling engine model and measurements performed at Microgen Engine Corporation, St. Petersborough, (UK), the engine power demand and engine-burner performance are found. The results are used to visualize the current energy flows of the Stirling engine and engine burner subsystem. The heat transfer to the engine is analyzed to find possible heat transfer improvements. It is concluded that heat transfer from the engine-burner to the engine can be approved if the flue losses due to convective heat transfer are

  14. Solid oxide fuel cell systems for residential micro-combined heat and power in the UK: Key economic drivers

    Science.gov (United States)

    Hawkes, Adam; Leach, Matthew

    The ability of combined heat and power (CHP) to meet residential heat and power demands efficiently offers potentially significant financial and environmental advantages over centralised power generation and heat-provision through natural-gas fired boilers. A solid oxide fuel cell (SOFC) can operate at high overall efficiencies (heat and power) of 80-90%, offering an improvement over centralised generation, which is often unable to utilise waste heat. This paper applies an equivalent annual cost (EAC) minimisation model to a residential solid oxide fuel cell CHP system to determine what the driving factors are behind investment in this technology. We explore the performance of a hypothetical SOFC system—representing expectations of near to medium term technology development—under present UK market conditions. We find that households with small to average energy demands do not benefit from installation of a SOFC micro-CHP system, but larger energy demands do benefit under these conditions. However, this result is sensitive to a number of factors including stack capital cost, energy import and export prices, and plant lifetime. The results for small and average dwellings are shown to reverse under an observed change in energy import prices, an increase in electricity export price, a decrease in stack capital costs, or an improvement in stack lifetime.

  15. Sorption behaviour of radioactive technetium in soils

    International Nuclear Information System (INIS)

    Xia Deying

    1996-01-01

    The sorption behaviour of technetium in different soils has been studied by batch experiments under aerobic conditions. The soil samples have been taken to study the characteristics and to derive the pH-Eh values. In addition, the activated carbon and reduced iron powder have been selected as additives to the JAERI sand according to the former research work, so that the technetium sorption behaviour in the artificial soils can be studied under similar conditions. The experimental results show that all these soil samples except for the gluey soil have a very small distribution coefficient for Tc, while the artificial soils have a very large distribution coefficient for Tc. Besides, for artificial soils, the distribution coefficient (R d ) values will become larger and larger when more additive is added and more contact time is allowed. The physico-chemical fixation processes and possible sorption modes have been discussed as well

  16. Sorption of Europium in zirconium silicate

    International Nuclear Information System (INIS)

    Garcia R, G.

    2004-01-01

    Some minerals have the property of sipping radioactive metals in solution, that it takes advantage to manufacture contention barriers that are placed in the repositories of nuclear wastes. The more recent investigations are focused in the development of new technologies guided to the sorption of alpha emissors on minerals which avoid their dispersion in the environment. In an effort to contribute to the understanding of this type of properties, some studies of sorption of Europium III are presented like homologous of the americium, on the surface of zirconium silicate (ZrSiO 4 ). In this work the results of sorption experiences are presented as well as the interpretation of the phenomena of the formation of species in the surface of the zirconium silicate. (Author)

  17. Sorption of radioactive technetium on pyrrhotine

    International Nuclear Information System (INIS)

    Shen, D.; Fan, X.H.; Su, X.G.; Zeng, J.S.; Dong, Y.

    2002-01-01

    The sorption behavior of technetium on pyrrhotine was studied with batch experiments and diluted sulfuric acid (less than 2.88 mol/l) was used to dissolve the technetium adsorbed on pyrrhotine. A significant sorption of technetium on pyrrhotine was observed under aerobic and anaerobic conditions, and the sorption on the mineral was supposed to be due to the reduction of TcO 4 - to insoluble TcO 2 x nH 2 O. Sorbed technetium on the mineral could be desorbed by diluted sulfuric acid. The maximum desorption ratio under aerobic conditions was much higher than that of under anaerobic conditions, meanwhile, the desorption rates under anaerobic conditions were higher than that of under aerobic conditions in the initial stage of the experiments. (author)

  18. Water sorption and transport in dry crispy bread crust

    NARCIS (Netherlands)

    Meinders, M.B.J.; Nieuwenhuijzen, van N.H.; Tromp, R.H.; Hamer, R.J.; Vliet, van T.

    2010-01-01

    Water sorption and dynamical properties of bread crust have been studied using gravimetric sorption experiments. Water uptake and loss were followed while relative humidity (RH) was stepwise in- or decreased (isotherm experiment) or varied between two adjusted values (oscillatory experiment).

  19. The sorption of acids in cellular side of apple pressing

    International Nuclear Information System (INIS)

    Asoev, M.G.; Mukhiddinov, Z.K.

    1994-01-01

    Equilibrium swell of sample refuse after separation of water is use for study of sorption of hydrochloric acid. Quantity adsorb acids set a price to difference her concentration before and after equilibrium sorption

  20. Molecular simulation of polycyclic aromatic hydrocarbon sorption to black carbon

    NARCIS (Netherlands)

    Haftka, J.J.H.; Parsons, J.R.; Govers, H.A.J.

    2009-01-01

    Strong sorption of hydrophobic organic contaminants to soot or black carbon (BC) is an important environmental process limiting the bioremediation potential of contaminated soils and sediments. Reliable methods to predict BC sorption coefficients for organic contaminants are therefore required. A

  1. Tritium sorption on protective coatings for concrete

    International Nuclear Information System (INIS)

    Miller, J.M.; Senohrabek, J.A.; Allsop, P.A.

    1992-11-01

    Because of the high sorption level of tritium on unprotected concrete, a program to examine the effectiveness of various concrete coatings and sealants in reducing tritium sorption was undertaken, and various exposure conditions were examined. Coatings of epoxy, polyurethane, bituminous sealant, bituminous sealant covered with polyvinylidene chloride wrap, alkyd paint, and sodium silicate were investigated with tritium (HTO) vapor concentration, humidity and contact time being varied. An exposure to HT was also carried out, and the effect of humidity on the tritium desorption rate was investigated. The relative effectiveness of the coatings was in the order of bituminous sealant + wrap > bituminous sealant > solvent-based epoxy > 100%-solids epoxy > alkyd paint > sodium silicate. The commercially available coatings for concrete resulted in tritium sorption being reduced to less than 7% of unprotected concrete. This was improved to ∼0.1% with the use of the Saran wrap (polyvinylidene chloride). The amount of tritium sorbed was proportional to tritium concentration. The total tritium sorbed decreased with an increase in humidity. A saturation effect was observed with increasing exposure time for both the coated and unprotected samples. Under the test conditions, complete saturation was not achieved within the maximum 8-hour contact time, except for the solvent-based epoxy. The desorption rate increased with a higher-humidity air purge stream. HT desorbed more rapidly than HTO, but the amount sorbed was smaller. The experimental program showed that HTO sorption by concrete can be significantly reduced with the proper choice of coating. However, tritium sorption on concrete and proposed coatings will continue to be a concern until the effects of the various conditions that affect the adsorption and desorption of tritium are firmly established for both chronic and acute tritium release conditions. Material sorption characteristics must also be considered in

  2. On the derivation of a sorption database

    International Nuclear Information System (INIS)

    Ewart, F.T.; Haworth, A.; Wisbey, S.J.

    1992-01-01

    The safety arguments in support of many radioactive waste repository concepts are heavily dependent on the existence of a sorption reaction. Such a reaction will, in the near field, reduce the magnitude of the release of a number of hazardous radionuclides so that their release to the geosphere is dispersed in time. In the geosphere, the sorption reactions provide a mechanism whereby the migration of the elements released from the repository is retarded and the radioisotopes then subsequently decay. The processes involved in sorption cannot in many cases be satisfactorily represented in thermodynamic terms such as are employed in the description of dissolution and precipitation. Experiments that investigate these reactions are not easy to perform. The sorption parameters that are obtained experimentally for the near field relate, in the UK case, to sorption on to a cementitious surface. These surfaces, since they consist substantially of calcium hydroxide or calcium silicate hydrates, control the aqueous chemistry, do not permit pH changes to be made and limit the range of concentrations of sorbate that may be used. In the far field, on the other hand, the surfaces are not in general so active with respect to the solution chemistry and data can be obtained across a wide spectrum of aqueous chemistries. These data, although they may be useful in testing and parameterizing models, may not have validity under field conditions since the minerals will, inevitably, react to the changes in water chemistry, over geological timescales. The uncertainties in the experimental data are, for many elements and solids, balanced by a reasonable agreement between workers in the values of the parameters used to describe sorption. 22 refs., 1 fig., 1 tab

  3. ENERGY STAR Certified Residential Dishwashers

    Data.gov (United States)

    U.S. Environmental Protection Agency — Certified models meet all ENERGY STAR requirements as listed in the Version 6.0 ENERGY STAR Program Requirements for Residential Dishwashers that are effective as of...

  4. ENERGY STAR Certified Residential Freezers

    Data.gov (United States)

    U.S. Environmental Protection Agency — Certified models meet all ENERGY STAR requirements as listed in the Version 5.0 ENERGY STAR Program Requirements for Residential Refrigerators and Freezers that are...

  5. ENERGY STAR Certified Residential Refrigerators

    Data.gov (United States)

    U.S. Environmental Protection Agency — Certified models meet all ENERGY STAR requirements as listed in the Version 5.0 ENERGY STAR Program Requirements for Residential Refrigerators and Freezers that are...

  6. Sorption Properties of Some Romanian Gingerbread

    Directory of Open Access Journals (Sweden)

    Tulbure Anca

    2014-06-01

    Full Text Available Water activity of gingerbread is very important for keeping the product freshness and shelf life. Water activity is influenced by composition, water content and temperature. The water content of gingerbread could vary according with storage condition. i.e. rH. 11 gingerbread samples were analysed. The water content and water activity lies between 7.0 and 12.6% and respectively 0.590 and 0.715. The sorption isotherms were determined at 30°C by gravimetric method. The moisture sorption is influenced by composition, especially sweeteners and humectants. Honey and invert sugar have the same impact on gingerbread higroscopicity.

  7. Sorption of radionuclides on hard rocks

    International Nuclear Information System (INIS)

    Berry, J.A.; Bourke, P.J.; Green, A.; Littleboy, A.K.

    1987-09-01

    Methods for measuring sorption on hard rocks, particularly of strontium, caesium, neptunium and americium on Darley Dale sandstone and Welsh slate have been investigated. The methods tried included batch tests with crushed rock and tests of simultaneous diffusion and convection with sorption on intact rock. High pressures (800m H 2 O) were used in the convective tests to pump water quickly through the rock samples and to measure high sorptivities in times shorter than those needed in the diffusive methods with intact samples. (author)

  8. A Sorption Hysteresis Model For Cellulosic Materials

    DEFF Research Database (Denmark)

    Frandsen, Henrik Lund; Damkilde, Lars

    2006-01-01

    The equilibrium concentration of adsorbed water in cellulosic materials is dependent on the history of the variations of vapor pressure in the ambient air, i.e. sorption hysteresis. Existing models to describe this phenomenon such as the independent domain theory have numerical drawbacks and....../or imply accounting for the entire history variations of every material point. This paper presents a sorption hysteresis model based on a state formulation and expressed in closed-form solutions, which makes it suitable for implementation into a numerical method....

  9. Sorption of natural uranium by algerian bentonite

    International Nuclear Information System (INIS)

    Megouda, N.; Kadi, H.; Hamla, M.S.; Brahimi, H.

    2004-01-01

    Full text.Batch sorption experiments have been used to assess the sorption behaviour of uranium onto natural and drilling bentonites. The operating parameters (pH, aolis-liquid ratio, particle size, time and initial uranium concentration) influenced the rate of adsorption. The distribution coefficient (Kd) range values at equilibrium time are 45.95-1079.26 ml/g and 32.81-463053 ml/g for the drilling and natural bentonites respectively. The equilibrium isotherms show that the data correlate with both Freundlich and Langmuir models

  10. Economics of residential gas furnaces and water heaters in United States new construction market

    Energy Technology Data Exchange (ETDEWEB)

    Lekov, Alex B.; Franco, Victor H.; Wong-Parodi, Gabrielle; McMahon, James E.; Chan, Peter

    2009-05-06

    New single-family home construction represents a significant and important market for the introduction of energy-efficient gas-fired space heating and water-heating equipment. In the new construction market, the choice of furnace and water-heater type is primarily driven by first cost considerations and the availability of power vent and condensing water heaters. Few analysis have been performed to assess the economic impacts of the different combinations of space and water-heating equipment. Thus, equipment is often installed without taking into consideration the potential economic and energy savings of installing space and water-heating equipment combinations. In this study, we use a life-cycle cost analysis that accounts for uncertainty and variability of the analysis inputs to assess the economic benefits of gas furnace and water-heater design combinations. This study accounts not only for the equipment cost but also for the cost of installing, maintaining, repairing, and operating the equipment over its lifetime. Overall, this study, which is focused on US single-family new construction households that install gas furnaces and storage water heaters, finds that installing a condensing or power-vent water heater together with condensing furnace is the most cost-effective option for the majority of these houses. Furthermore, the findings suggest that the new construction residential market could be a target market for the large-scale introduction of a combination of condensing or power-vent water heaters with condensing furnaces.

  11. The sorption behaviour of 99Tc on activated carbon

    International Nuclear Information System (INIS)

    Xia Deying; Zeng Jishu

    2004-01-01

    The sorption behaviour of 99 Tc on apricot-pit activated carbon with batch experiment is studied. The influence of such factors as sorbent particle size, temperature, pH value on sorption ratio, and the Freundlich sorption isotherms are reported in this paper. (author)

  12. Suitability of Moshi Pumice for Phosphorus Sorption in Constructed ...

    African Journals Online (AJOL)

    The study of Moshi Pumice's phosphorus sorption behaviours and properties was carried out in laboratory scale where by 1-2 mm, 2-4 mm and 4-8 mm grains were tested using batch experiments. The results show that Moshi Pumice has high phosphorus sorption capacity. The sorption capacity for the Moshi Pumice was ...

  13. Phosphorus sorption in relation to soil grain size and geochemical ...

    African Journals Online (AJOL)

    By using stepwise regression, the combination of Al, Fe, clay and Ca predicted more than 94% of the variation in the P sorption capacity of soils samples from Simiyu and Kagera basins. These four soil properties, which are strongly related to P sorption, could therefore be used as quick tests for predicting the P sorption ...

  14. Sorption of Heterocyclic Organic Compounds to Multiwalled Carbon Nanotubes.

    Science.gov (United States)

    Metzelder, Florian; Funck, Matin; Schmidt, Torsten C

    2018-01-16

    Sorption is an important natural and technical process. Sorption coefficients are typically determined in batch experiments, but this may be challenging for weakly sorbing compounds. An alternative method enabling analysis of those compounds is column chromatography. A column packed with the sorbent is used and sorption data are determined by relating sorbate retention to that of a nonretarded tracer. In this study, column chromatography was applied for the first time to study sorption of previously hardly investigated heterocyclic organic compounds to multiwalled carbon nanotubes (MWCNTs). Sorption data for these compounds are very limited in literature, and weak sorption is expected from predictions. Deuterium oxide was used as nonretarded tracer. Sorption isotherms were well described by the Freundlich model and data showed reasonable agreement with predicted values. Sorption was exothermic and physisorption was observed. H-bonding may contribute to overall sorption, which is supported by reduced sorption with increasing ionic strength due to blocking of functional groups. Lowering pH reduced sorption of ionizable compounds, due to electrostatic repulsion at pH 3 where sorbent as well as sorbates were positively charged. Overall, column chromatography was successfully used to study sorption of heterocyclic compounds to MWCNTs and could be applied for other carbon-based sorbents.

  15. Attenuation of polychlorinated biphenyl sorption to charcoal by humic acids

    NARCIS (Netherlands)

    Koelmans, A.A.; Meulman, B.; Meijer, T.; Jonker, M.T.O.

    2009-01-01

    Strong sorption to black carbon may limit the environmental risks of organic pollutants, but interactions with cosorbing humic acid (HA) may interfere. We studied the attenuative effect of HA additions on the sorption of polychlorinated biphenyls (PCBs) to a charcoal. "Intrinsic" sorption to

  16. Sorption mechanisms of perfluorinated compounds on carbon nanotubes

    International Nuclear Information System (INIS)

    Deng Shubo; Zhang Qiaoying; Nie Yao; Wei Haoran; Wang Bin; Huang Jun; Yu Gang; Xing Baoshan

    2012-01-01

    Sorption of perfluorinated compounds (PFCs) on carbon nanotubes (CNTs) is critical for understanding their subsequent transport and fate in aqueous environments, but the sorption mechanisms remain largely unknown. In this study, the sorption of six PFCs on CNTs increased with increasing C-F chain length when they had a same functional group, and the CNTs with hydroxyl and carboxyl groups had much lower adsorbed amount than the pristine CNTs, indicating that hydrophobic interaction dominated the sorption of PFCs on the CNTs. Electrostatic repulsion suppressed the sorption of PFCs on the CNTs, resulting in the lower sorption with increasing pH. Hydrogen bonding interaction was negligible. The hydrophobic C-F chains can be closely adsorbed on the CNTs surface in parallel to the axis or along the curvature, making it impossible to form micelles on the CNT surface, leading to the lower sorption than other adsorbents. Highlights: ► Sorption capacities of PFOA on different CNTs are less than that on activated carbon and resins. ► Hydrophobic interaction is principally involved in the sorption of PFCs on CNTs. ► Electrostatic repulsion suppresses the sorption of PFCs on CNTs. - Hydrophobic interaction dominated the sorption of perfluorinated compounds on carbon nanotubes, while electrostatic repulsion suppressed their sorption.

  17. Hydration and sorption characteristics of a polyfunctional weak-base anion exchanger after the sorption of vanillin and ethylvanillin

    Science.gov (United States)

    Rodionova, D. O.; Voronyuk, I. V.; Eliseeva, T. V.

    2016-07-01

    Features of the sorption of substituted aromatic aldehydes by a weak-base anion exchanger under equilibrium conditions are investigated using vanillin and ethylvanillin as examples. Analysis of the sorption isotherms of carbonyl compounds at different temperatures allows us to calculate the equilibrium characteristics of their sorption and assess the entropy and enthalpy contributions to the energy of the process. Hydration characteristics of the macroporous weak-base anion exchanger before and after the sorption of aromatic aldehydes are compared.

  18. A suggested approach toward measuring sorption and applying sorption data to repository performance assessment

    International Nuclear Information System (INIS)

    Rundberg, R.S.

    1991-01-01

    The sorption of radioisotopes in relation to geologic disposal of radioactive wastes is discussed. Properties of the radioactive materials, rocks, and minerals, and the chemistry involved are described. 51 refs., 12 figs. CBS

  19. Sorption of fission nuclides on model milk components. II. Sorption of radiostrontium on hydroxyapatite in milk and whey

    International Nuclear Information System (INIS)

    Rosskopfova, O.; Kopunec, R.; Matel, L.; Macasek, F.

    1999-01-01

    In this work the whey was chosen as a model solution of liquid phase for sorption study of strontium on hydroxyapatite. The whey was obtained using two methods - ultracentrifugation and precipitation of casein. The sorption was studied at a different pH and at a different concentration of calcium. The sorption of strontium on hydroxyapatite from milk was studied, too. (authors)

  20. Development of mechanistic sorption model and treatment of uncertainties for Ni sorption on montmorillonite/bentonite

    International Nuclear Information System (INIS)

    Ochs, Michael; Ganter, Charlotte; Tachi, Yukio; Suyama, Tadahiro; Yui, Mikazu

    2011-02-01

    Sorption and diffusion of radionuclides in buffer materials (bentonite) are the key processes in the safe geological disposal of radioactive waste, because migration of radionuclides in this barrier is expected to be diffusion-controlled and retarded by sorption processes. It is therefore necessary to understand the detailed/coupled processes of sorption and diffusion in compacted bentonite and develop mechanistic /predictive models, so that reliable parameters can be set under a variety of geochemical conditions relevant to performance assessment (PA). For this purpose, JAEA has developed the integrated sorption and diffusion (ISD) model/database in montmorillonite/bentonite systems. The main goal of the mechanistic model/database development is to provide a tool for a consistent explanation, prediction, and uncertainty assessment of K d as well as diffusion parameters needed for the quantification of radionuclide transport. The present report focuses on developing the thermodynamic sorption model (TSM) and on the quantification and handling of model uncertainties in applications, based on illustrating by example of Ni sorption on montmorillonite/bentonite. This includes 1) a summary of the present state of the art of thermodynamic sorption modeling, 2) a discussion of the selection of surface species and model design appropriate for the present purpose, 3) possible sources and representations of TSM uncertainties, and 4) details of modeling, testing and uncertainty evaluation for Ni sorption. Two fundamentally different approaches are presented and compared for representing TSM uncertainties: 1) TSM parameter uncertainties calculated by FITEQL optimization routines and some statistical procedure, 2) overall error estimated by direct comparison of modeled and experimental K d values. The overall error in K d is viewed as the best representation of model uncertainty in ISD model/database development. (author)

  1. Gas Sorption, Diffusion, and Permeation in Nafion

    KAUST Repository

    Mukaddam, Mohsin Ahmed; Litwiller, Eric; Pinnau, Ingo

    2015-01-01

    The gas permeability of dry Nafion films was determined at 2 atm and 35 °C for He, H2, N2, O2, CO2, CH4, C2H6, and C3H8. In addition, gas sorption isotherms were determined by gravimetric and barometric techniques as a function of pressure up to 20

  2. Development of a microminiature sorption cooler

    NARCIS (Netherlands)

    Burger, Johannes; Holland, Harry; ter Brake, Marcel; Rogalla, Horst; Wade, Larry

    1997-01-01

    The development of a microcooler for operations below 80 K, for low temperature electronic devices requiring small cooling powers of the order of 10 mW is described. A sorption compressor combined with Joule-Thomson (JT) expansion was selected for miniaturization. The advantage of the system is

  3. Sorption of radiocalcium on human hair

    International Nuclear Information System (INIS)

    Rakovic, M.; Pilecka, N.

    1987-01-01

    The sorption of 45 Ca on hair from a 45 CaCl 2 solution (2.5x10 -3 mol l -1 ) was studied. The calcium amounts sorbed in 1 min to 5 h range between 0.8 and 7.2% with respect to the originally present calcium in hair. (author) 3 refs

  4. Sorption of methanol in alkali exchange zeolites

    NARCIS (Netherlands)

    Rep, M.; Rep, M.; Corma, Avelino; Palomares, A.E.; Palomares gimeno, A.E.; van Ommen, J.G.; Lefferts, Leonardus; Lercher, J.A.

    2000-01-01

    Metal cation methanol sorption complexes in MFI (ZSM5), MOR and X have been studied by in situ i.r. spectroscopy in order to understand the nature of interactions of methanol in the molecular sieve pores. The results show that (a) a freely vibrating hydroxy and methyl group of methanol exist on

  5. Radionuclide sorption database for Swiss safety assessment

    International Nuclear Information System (INIS)

    McKinley, I.G.; Hadermann, J.

    1984-10-01

    Recommended sorption data for use in transport models for a Swiss High-Level Waste repository are presented. The models used in 'Project Gewaehr 1985' assume linear sorption isotherms and require elemental partition coefficient (Kd) data. On the basis of a literature search 'realistic' Kd data for 22 elements have been selected for weathered crystalline rock and sediments in contact with a reducing groundwater and also sediments with a less reducing groundwater. In an appendix sorption data for 28 elements on bentonite backfill are given. These data are supplemented with 'conservative' estimates taken to represent minimum reasonable values. Available data are discussed for each element clearly exhibiting (i) the large gaps in knowledge, (ii) their unbalanced distribution between different elements and, hence, (iii) the need for further experiments in the laboratory, the field and analogue studies. An overview of the theoretical concepts of sorption, experimental methodology and data interpretation is given in order to put the values into context. General problem areas are identified. (Auth.)

  6. Radionuclide sorption kinetics and column sorption studies with Columbia River basalts

    International Nuclear Information System (INIS)

    Barney, G.S.

    1983-09-01

    The kinetics of radionuclide sorption and desorption reactions in basalt-groundwater systems were evaluated at 60 degrees C using a batch equilibration method. It was found that many sorption reactions on surfaces of fresh (unaltered) basalt from the Umtanum and Cohassett flows are slow. Some reactions require more than 50 days to reach a steady state. Sorption of neptunium and uranium in oxidizing (air saturated) groundwater appears to be controlled by slow reduction of these elements by the basalt surfaces. The resulting lower oxidation states are more strongly sorbed. Technetium and selenium, which are anionic under oxidizing conditions, are not measurably sorbed on fresh basalt surfaces, but are slightly sorbed on the altered surfaces of flow top basalt. Under reducing conditions, where the groundwater contains dilute hydrazine, sorption is faster for neptunium, uranium, technetium, selenium, and lead. Plutonium sorption rates were not affected by the groundwater Eh. It was shown that radium was precipitated rather than sorbed under the conditions of these experiments. Umtanum flow top material sorbed radionuclides much faster than fresh basalt surfaces due to its greater surface area and cation exchange capacity. Desorption rates for plutonium, uranium, neptunium, technetium, and selenium were generally much less than sorption rates (especially for reducing conditions). These radionuclides are irreversibly sorbed on the basalts. 25 refs., 20 figs., 19 tabs

  7. Radionuclide sorption on crushed and intact granitic rock

    International Nuclear Information System (INIS)

    Eriksen, Tryggve E.; Locklund, Birgitta

    1989-05-01

    The specific surface areas and distribution ratios for sorption of 85 Sr, 137 Cs and 152 Eu were measured for crushed and intact granite rock. The experimental data can be accommodated by a sorption model encompassing sorption on outer and inner surface. It is clearly demonstrated that the time required to obtain reliable Kd-values for the sorption of strongly sorbing radionuclides like 152 Eu is very long due to solution depletion and slow diffusion into the rock. A combination of surface area measurements and batch sorption with small particles may therefore be preferable when studying strongly sorbing nuclides. (authors) (17 figs., 6 tabs.)

  8. Sorption and migration of neptunium in porous sedimentary materials

    International Nuclear Information System (INIS)

    Tanaka, Tadao; Mukai, Masayuki; Nakayama, Shinichi

    2005-01-01

    Column migration experiments of neptunium were conducted for porous sedimentary materials: coastal sand, tuffaceous sand, ando soil, reddish soil, yellowish soil and loess, and migration behavior, sorption mechanisms and chemical formation of Np were investigated. The migration behavior of Np in each material was much different each other, due to chemical formation in solution and/or sorption mechanism of Np. Mathematical models of different concepts were applied to the experimental results to interpret the sorption mechanism and the migration behavior. It can be concluded that both of instantaneous equilibrium sorption and sorption-desorption kinetics have to be considered to model the Np migration in sedimentary materials. (author)

  9. Sorption of niobium on boreal forest soil

    Energy Technology Data Exchange (ETDEWEB)

    Soederlund, Mervi; Hakanen, Martti; Lehto, Jukka [Helsinki Univ. (Finland). Lab. of Radiochemistry

    2015-07-01

    The sorption of niobium (Nb) was investigated on humus and mineral soil samples taken from various depths of a four-metre deep forest soil pit on Olkiluoto Island, southwestern Finland. Mass distribution coefficients, K{sub d}, were determined in batch sorption tests. The steady state of Nb sorption was observed in the mineral soil samples already after one week of equilibration, and sorption decreased with depth from a very high value of 185000 mL/g at 0.7 m to 54000 mL/g at 3.4 m. The reason behind this decrease is probably the tenfold reduction in the specific surface area of the soil at the same depth range. Distribution coefficients were clearly lower in the humus layer (1000 mL/g). The K{sub d} values determined in pure water at a pH range of 4.7-6.5 were at a high level (above 55000 mL/g), but decreased dramatically above pH 6.5, corresponding to the change in the major Nb species from the neutral Nb(OH){sub 5} to the low-sorbing anionic Nb(OH){sub 6}{sup -} and Nb(OH){sub 7}{sup 2-}. However, the K{sub d} values in the model soil solution were in the slightly alkaline range an order of magnitude higher than in pure water, which is probably caused by the formation of calcium niobate surface precipitate or electrostatic interaction between surface-sorbed calcium and solute Nb. Among nine soil constituent minerals kaolinite performed best in retaining Nb in both pure water and model soil solution at pH 8, whereas potassium feldspar showed the poorest sorption. The K{sub d} value for kaolinite was above 500000 mL/g in both solutions, while the respective potassium feldspar values were in the range of 120-220 mL/g.

  10. Sorption behaviour of perfluoroalkyl substances in soils.

    Science.gov (United States)

    Milinovic, Jelena; Lacorte, Silvia; Vidal, Miquel; Rigol, Anna

    2015-04-01

    The sorption behaviour of three perfluoroalkyl substances (PFASs), perfluorooctane sulfonic acid (PFOS), perfluorooctanoic acid (PFOA) and perfluorobutane sulfonic acid (PFBS), was studied in six soils with contrasting characteristics, especially in the organic carbon content. Sorption isotherms were obtained by equilibrating the soil samples with 0.01 mol L(-1) CaCl2 solutions spiked with increasing concentrations of the target PFAS. The sorption reversibility of PFASs was also tested for some of the samples. Liquid chromatography coupled to tandem mass spectrometry was used to quantify the target PFASs in the solutions. Both the Freundlich and linear models were appropriate to describe the sorption behaviour of PFASs in soils, and enabled us to derive solid-liquid distribution coefficients (Kd) for each compound in each soil. Kd values increased from 19 to 295 mL g(-1) for PFOS, from 2.2 to 38 mL g(-1) for PFOA and from 0.4 to 6.8 mL g(-1) for PFBS, and were positively correlated with the organic carbon content of the soil. KOC values obtained from the correlations were 710, 96 and 17 mL g(-1) for PFOS, PFOA and PFBS, respectively. Whereas Kd values decreased in the sequence PFOS>PFOA>PFBS, desorption yields were lower than 13% for PFOS, from 24 to 58% for PFOA, and from 32 to 60% for PFBS. This shows that the physicochemical characteristics of PFASs, basically their hydrophobicity, controlled their sorption behaviour in soils, with PFOS being the most irreversibly sorbed PFAS. Copyright © 2014 Elsevier B.V. All rights reserved.

  11. Modeling Fission Product Sorption in Graphite Structures

    International Nuclear Information System (INIS)

    Szlufarska, Izabela; Morgan, Dane; Allen, Todd

    2013-01-01

    The goal of this project is to determine changes in adsorption and desorption of fission products to/from nuclear-grade graphite in response to a changing chemical environment. First, the project team will employ principle calculations and thermodynamic analysis to predict stability of fission products on graphite in the presence of structural defects commonly observed in very high-temperature reactor (VHTR) graphites. Desorption rates will be determined as a function of partial pressure of oxygen and iodine, relative humidity, and temperature. They will then carry out experimental characterization to determine the statistical distribution of structural features. This structural information will yield distributions of binding sites to be used as an input for a sorption model. Sorption isotherms calculated under this project will contribute to understanding of the physical bases of the source terms that are used in higher-level codes that model fission product transport and retention in graphite. The project will include the following tasks: Perform structural characterization of the VHTR graphite to determine crystallographic phases, defect structures and their distribution, volume fraction of coke, and amount of sp2 versus sp3 bonding. This information will be used as guidance for ab initio modeling and as input for sorptivity models; Perform ab initio calculations of binding energies to determine stability of fission products on the different sorption sites present in nuclear graphite microstructures. The project will use density functional theory (DFT) methods to calculate binding energies in vacuum and in oxidizing environments. The team will also calculate stability of iodine complexes with fission products on graphite sorption sites; Model graphite sorption isotherms to quantify concentration of fission products in graphite. The binding energies will be combined with a Langmuir isotherm statistical model to predict the sorbed concentration of fission products

  12. SORPTION OF Au(III BY Saccharomyces cerevisiae BIOMASS

    Directory of Open Access Journals (Sweden)

    Amaria Amaria

    2010-07-01

    Full Text Available Au(III sorption by S. cerevisiae biomass extracted from beer waste industry was investigated. Experimentally, the sorption was conducted in batch method. This research involved five steps: 1 identification the functional groups present in the S. cerevisiae biomass by infrared spectroscopic technique, 2 determination of optimum pH, 3 determination of the sorption capacity and energy, 4 determination of the sorption type by conducting desorption of sorbed Au(III using specific eluents having different desorption capacity such as H2O (van der Waals, KNO3 (ion exchange, HNO3 (hydrogen bond, and tiourea (coordination bond, 5 determination of effective eluents in Au(III desorption by partial desorption of sorbed Au(III using thiourea, NaCN and KI. The remaining Au(III concentrations in filtrate were analyzed using Atomic Absorption Spectrophotometer. The results showed that: 1 Functional groups of S. cerevisiae biomass that involved in the sorption processes were hydroxyl (-OH, carboxylate (-COO- and amine (-NH2, 2 maximum sorption was occurred at pH 4, equal to 98.19% of total sorption, 3 The sorption capacity of biomass was 133.33 mg/g (6.7682E-04 mol/g and was involved sorption energy 23.03 kJ mol-1, 4 Sorption type was dominated by coordination bond, 5 NaCN was effective eluent to strip Au(III close to 100%.   Keywords: sorption, desorption, S. cerevisiae biomass, Au(III

  13. Thermodynamic sorption modelling in support of radioactive waste disposal safety cases - NEA sorption project phase III

    International Nuclear Information System (INIS)

    2012-01-01

    A central safety function of radioactive waste disposal repositories is the prevention or sufficient retardation of radionuclide migration to the biosphere. Performance assessment exercises in various countries, and for a range of disposal scenarios, have demonstrated that one of the most important processes providing this safety function is the sorption of radionuclides along potential migration paths beyond the engineered barriers. Thermodynamic sorption models (TSMs) are key for improving confidence in assumptions made about such radionuclide sorption when preparing a repository's safety case. This report presents guidelines for TSM development as well as their application in repository performance assessments. They will be of particular interest to the sorption modelling community and radionuclide migration modellers in developing safety cases for radioactive waste disposal Contents: 1 - Thermodynamic sorption models and radionuclide migration: Sorption and radionuclide migration; Applications of TSMs in radioactive waste disposal studies; Requirements for a scientifically defensible, calibrated TSM applicable to radioactive waste disposal; Current status of TSMs in radioactive waste management; 2 - Theoretical basis of TSMs and options in model development: Conceptual building blocks of TSMs and integration with aqueous chemistry; The TSM representation of sorption and relationship with Kd values; Theoretical basis of TSMs; Example of TSM for uranyl sorption; Options in TSM development; Illustration of TSM development and effects of modelling choices; Summary: TSMs for constraining Kd values - impact of modelling choices; 3 - Determination of parameters for TSMs: Overview of experimental determination of TSM parameters; Theoretical estimation methods of selected model parameters; Case study: sorption modelling of trivalent lanthanides/actinides on illite; Indicative values for certain TSM parameters; Parameter uncertainty; Illustration of parameter sensitivity

  14. Ab-sorption machines for heating and cooling in future energy systems - Final report

    Energy Technology Data Exchange (ETDEWEB)

    Tozer, R.; Gustafsson, M.

    2000-12-15

    After the Executive Summary and a brief introductory chapter, Chapter 2, Sorption Technologies for Heating and Cooling in Future Energy Systems, reviews the main types of sorption systems. Chapter 3, Market Segmentation, then considers the major segments of the market including residential, commercial/institutional and industrial, and the types of sorption hardware most suitable to each. The highly important residential and commercial/institutional markets are mostly concerned with air-conditioning of buildings. More applications are identified and discussed for the industrial market, including refrigeration, food-storage cooling, process cooling, and process heating at various temperature ranges from hot water for hand-washing to high-temperature (greater than 130C). Other interesting industrial applications are absorption cooling or heating combined with co-generation, desiccant cooling, gas turbine inlet air cooling, combining absorption chillers with district heating systems, direct-fired absorption heat pumps (AHPs), and a closed greenhouse concept being developed for that economically important sector in the Netherlands. Most of the sorption market at this time comprises direct-fired absorption chillers, or hot water or steam absorption chillers indirectly driven by direct-fired boilers. Throughout the report, this category of absorption chillers is referred to generically as 'direct-fired'. In addition, this report covers absorption (reversible) heat pumps, absorption heat transformers, compression-absorption heat pumps, and adsorption chillers and heat pumps. Adsorption systems together with desiccant systems are also addressed. Chapter 4, Factors Affecting the Market, considers economic, environmental and policy issues. The geographical make-up of the world sorption market is then reviewed, followed by a number of practical operating and control considerations. These include vacuum requirements, crystallisation, corrosion, maintenance, health and

  15. Defluoridation by Bacteriogenic Iron Oxides: Sorption Studies

    Science.gov (United States)

    Evans, K.; Ferris, F.

    2009-05-01

    At concentrations above 1 mg/L, fluoride in drinking water can lead to dental and skeletal fluorosis, a disease that causes mottling of the teeth, calcification of ligaments, crippling bone deformities and many other physiological disorders that can, ultimately, lead to death. Conservative estimates are that fluorosis afflicts tens of millions of people worldwide. As there is no treatment for fluorosis, prevention is the only means of controlling the disease. While numerous defluoridation techniques have been explored, no single method has been found to be both effective and inexpensive enough to implement widely. Our research began in India, with a large-scale geochemical study of the groundwater in a fluoride-contaminated region of Orissa. Having developed a better understanding of the geochemical relationships that exist between fluoride and other parameters present in an affected area, as well as the complex relationships that arise among those parameters that can impact the presence of fluoride, we began investigating certain remediation scenarios involving iron oxides. A common approach to remediation involves the partitioning of fluoride from groundwater by sorption onto a variety of materials, one of the most effective of which is iron oxide whose surface area acts as a scavenger for fluoride. In the presence of iron oxidizing bacteria, the oxidation rate of iron has been shown to be ˜6 times greater than in their absence; fluoride should, therefore, be removed from an aqueous environment by bacteriogenic iron oxides (BIOS) much more quickly than by abiotic iron oxides. Most recently, sorption studies have been conducted using both BIOS and synthetic hydrous ferric oxides in order to compare the behavior between biotic and abiotic sorbents. These studies have provided sorption isotherms that allow comparison of fluoride removed by sorption to BIOS versus synthetic iron oxides. Sorption affinity constants have also been determined, which allow for the

  16. Isotherm, kinetic, and thermodynamic study of ciprofloxacin sorption on sediments.

    Science.gov (United States)

    Mutavdžić Pavlović, Dragana; Ćurković, Lidija; Grčić, Ivana; Šimić, Iva; Župan, Josip

    2017-04-01

    In this study, equilibrium isotherms, kinetics and thermodynamics of ciprofloxacin on seven sediments in a batch sorption process were examined. The effects of contact time, initial ciprofloxacin concentration, temperature and ionic strength on the sorption process were studied. The K d parameter from linear sorption model was determined by linear regression analysis, while the Freundlich and Dubinin-Radushkevich (D-R) sorption models were applied to describe the equilibrium isotherms by linear and nonlinear methods. The estimated K d values varied from 171 to 37,347 mL/g. The obtained values of E (free energy estimated from D-R isotherm model) were between 3.51 and 8.64 kJ/mol, which indicated a physical nature of ciprofloxacin sorption on studied sediments. According to obtained n values as measure of intensity of sorption estimate from Freundlich isotherm model (from 0.69 to 1.442), ciprofloxacin sorption on sediments can be categorized from poor to moderately difficult sorption characteristics. Kinetics data were best fitted by the pseudo-second-order model (R 2  > 0.999). Thermodynamic parameters including the Gibbs free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) were calculated to estimate the nature of ciprofloxacin sorption. Results suggested that sorption on sediments was a spontaneous exothermic process.

  17. Testosterone sorption and desorption: Effects of soil particle size

    Energy Technology Data Exchange (ETDEWEB)

    Qi, Yong, E-mail: yqi01@unomaha.edu [Civil Engineering Dept., University of Nebraska-Lincoln at Omaha Campus, Omaha, NE 68182 (United States); Zhang, Tian C. [Civil Engineering Dept., University of Nebraska-Lincoln at Omaha Campus, Omaha, NE 68182 (United States); Ren, Yongzheng [School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China)

    2014-08-30

    Graphical abstract: - Highlights: • Smaller soil particles have higher sorption and lower desorption rates. • The sorption capacity ranks as clay > silt > sand. • Small particles like clays have less potential for desorption. • Colloids (clays) have high potential to facilitate the transport of hormones in soil–water environments. - Abstract: Soils contain a wide range of particles of different diameters with different mobility during rainfall events. Effects of soil particles on sorption and desorption behaviors of steroid hormones have not been investigated. In this study, wet sieve washing and repeated sedimentation methods were used to fractionate the soils into five ranges. The sorption and desorption properties and related mechanisms of testosterone in batch reactors filled with fractionated soil particles were evaluated. Results of sorption and desorption kinetics indicate that small soil particles have higher sorption and lower desorption rates than that of big ones. Thermodynamic results show the sorption processes are spontaneous and exothermal. The sorption capacity ranks as clay > silt > sand, depending mainly on specific surface area and surface functional groups. The urea control test shows that hydrogen bonding contributes to testosterone sorption onto clay and silt but not on sand. Desorption tests indicate sorption is 36–65% irreversible from clay to sand. Clays have highest desorption hysteresis among these five soil fractions, indicating small particles like clays have less potential for desorption. The results provide indirect evidence on the colloid (clay)-facilitated transport of hormones (micro-pollutants) in soil environments.

  18. Effect of natural organic materials on cadmium and neptunium sorption

    International Nuclear Information System (INIS)

    Kung, K.S.; Triay, I.R.

    1994-01-01

    In a batch sorption study of the effect of naturally occurring organic materials on the sorption of cadmium and neptunium on oxides and tuff surfaces, the model sorbents were synthetic goethite, boehmite, amorphous silicon oxides, and a crushed tuff material from Yucca Mountain, Nevada. An amino acid, 3-(3,4-dihydroxypheny)-DL-alanine (DOPA), and an aquatic-originated fulvic material, Nordic aquatic fulvic acid (NAFA), were used as model organic chemicals. Sorption isotherm results showed that DOPA sorption followed the order aluminum oxide > iron oxide > silicon oxide and that the amount of DOAP sorption for a given sorbent increased as the solution pH was raised. The sorption of cadmium and neptunium on the iron oxide was about ten times higher than that on the aluminum oxide. The sorption of cadmium and neptunium on natural tuff material was much lower than that on aluminum and iron oxides. The sorption of cadmium on iron and aluminum oxides was found to be influenced by the presence of DOPA, and increasing the amount of DOPA coating resulted in higher cadmium sorption on aluminum oxide. However, for iron oxide, cadmium sorption decreased with increasing DOPA concentration. The presence of the model organic materials DOPA and NAFA did not affect the sorption of neptunium on tuff material or on the iron and aluminum oxides. Spectroscopic results indicate that cadmium complexes strongly with DOPA. Therefore, the effect of the organic material, DOPA, on the cadmium sorption is readily observed. However, neptunium is possibly complexed weakly with organic material. Thus, DOPA and NAFA have little effect on neptunium sorption on all sorbents selected for study

  19. Sorption of actinides in granitic rock

    International Nuclear Information System (INIS)

    Allard, B

    1982-11-01

    The sorption of americium (III), neptunium(V) and plutonium on geologic media under oxic conditions has been measured by a batch technique. The aqueous phase was a synthetic groundwater or 4M NaCl solution. The solid phase was a pure mineral, representative of igneous rocks, or granite. Altogether 40 different minerals and rocks were used. The effects of pH and the ionic strength of the aqueous phase as well as of the cation exchange capacity and the surface/mass ratio of the solid sorbent are discussed. Empirical equations giving the distribution coefficient as a function of pH in the environmental pH-range 7-9 are suggested. Some observations and conclusions concerning sorption mechanisms are given. (author)

  20. Sorption analyses in materials science: selected oxides

    International Nuclear Information System (INIS)

    Fuller, E.L. Jr.; Condon, J.B.; Eager, M.H.; Jones, L.L.

    1981-01-01

    Physical adsorption studies have been shown to be extremely valuable in studying the chemistry and structure of dispersed materials. Many processes rely on the access to the large amount of surface made available by the high degree of dispersion. Conversely, there are many applications where consolidation of the dispersed solids is required. Several systems (silica gel, alumina catalysts, mineralogic alumino-silicates, and yttrium oxide plasters) have been studied to show the type and amount of chemical and structural information that can be obtained. Some review of current theories is given and additional concepts are developed based on statistical and thermodynamic arguments. The results are applied to sorption data to show that detailed sorption analyses are extremely useful and can provide valuable information that is difficult to obtain by any other means. Considerable emphasis has been placed on data analyses and interpretation of a nonclassical nature to show the potential of such studies that is often not recognized nor utilized

  1. Sorption of zinc on human teeth

    International Nuclear Information System (INIS)

    Helal, A.; Amin, H.; Alian, G.

    1997-01-01

    Zinc containing dental amalgams are sometimes used as fillings by dentists. The freshly mixed mass of the amalgam alloy and liquid mercury packed or condensed into a prepared tooth cavity. Zinc has been included in amalgams alloys up to 2% as an aid in manufacturing by helping to produce clean sound castings of the ingots. Although such restorations have a relatively long service life, they are subject to corrosion and galvanic action, thus releasing metallic products into the oral environment. The aim of this paper is to investigate the uptake (sorption) of Zinc ionic species on human teeth using the radioactive tracer technique. For this purpose the isotope Zn-65 produced from pile-irradiation of zinc metal was used. The various liquids studied were drinking water (tap water), tea, coffee, red tea and chicken soup. Sorption was studied through immersion of a single human tooth (extracted) in each of these liquids

  2. Sorption of 60 Co on inorganic solids

    International Nuclear Information System (INIS)

    Granados C, F.; Bulbulian G, S.; Mardel V, B.

    2003-01-01

    The behavior of sorption of the 60 Co in aqueous solution under static conditions to different values of pH of the aqueous solution (1, 3, 5, 7, and 10) on MgO, MnO 2 , SnO, TiO 2 , activated carbon and calcinate hydrotalcite was investigated. It was found that the best sorbents of the 60 Co was the MnO 2 , activated carbon and TiO 2 whose sorption was incremented when increasing the pH value of the aqueous solutions, in the one case of the hydrated oxides, the 60 Co interacted with the electrically charged surface of the sorbents that depends on the pH of the solution and of the point of zero charge (zpc) of the sorbent. (Author)

  3. Noble metal extraction and sorption concentrating

    International Nuclear Information System (INIS)

    Petrukhin, O.M.; Malofeeva, G.I.

    1985-01-01

    Works performed in the USSR Academy of Sciences GEOCHI laboratory of extraction methods and devoted to selectivity problems of extraction and sorption methods of platinum metal, cadmium and indium concentrating in analytical chemistry are discussed. On choosing complexino. reagent main attention is paid to the selectivity variation based on different stability of metal complexes. Platinum metals are extracted in the form of ion associates when usinq hard, mainly oxyqen-containing, extractants. Coordination-solvated metal complexes are extracted white usinq extractants containing sulfur, trivalent phosphorus and aromatic nitroqen as donor anions. Selectivity is maximum for sulfur- and nitroren-containinq extractants and sorbents. In case of the group extraction of platinum metals sorption is preferable and in case of selective extraction of individual metals, especially, in case of need of relative concentratinq extraction is preferable

  4. Uranium sorption on tezontle volcanic rock

    International Nuclear Information System (INIS)

    Lopez M, B. E.; Duran B, J. M.; Iturbe G, J. L.; Olguin G, M. T.

    2009-01-01

    It is described a study that demonstrates that hexavalent uranium ions were sorbed by the naturally occurring mineral using a batch technique. This mineral is found in abundant quantities in Mexico. Our study focused on the separation of U Vi from synthetic aqueous systems of both H 2 O-UO 2 (NO 3 ) 2 .6H 2 O (acid) and H 2 O-Na 4 [UO 2 (CO 3 ) 3 ] (basic). The chemical speciation was performed by using high voltage electrophoresis, and the uranium content was determined by UV-Vis spectroscopy. The quantified U(Vi) sorption by tezontle from acidic and basic systems was 2.72 and 1.68 μmol/g, respectively, and the sorption behavior is discussed considering the surface charge of the tezontle at different ph values based on the point of zero charge characteristic of this material. (Author)

  5. Sorption of phenanthrene on agricultural soils

    DEFF Research Database (Denmark)

    Soares, Antonio; Møldrup, Per; Minh, Luong Nhat

    2013-01-01

    Polyaromatic hydrocarbon (PAH) sorption to soil is a key process deciding the transport and fate of PAH, and potential toxic impacts in the soil and groundwater ecosystems, for example in connection with atmospheric PAH deposition on soils. There are numerous studies on PAH sorption in relatively......, 0.25–1-m depth) by the single-point adsorption method. The organic carbon partition coefficient, KOC (liter per kilogram) for topsoils was found generally to fall between the KOC values estimated by the two most frequently used models for PAH partitioning, the Abdul et al. (Hazardous Waste...... & Hazardous Materials 4(3):211–222, 1987) model and Karickhoff et al. (Water Research 13:241–248, 1979) model. A less-recognized model by Karickhoff (Chemosphere 10:833–846, 1981), yielding a KOC of 14,918 L kg−1, closely corresponded to the average measured KOC value for the topsoils, and this model...

  6. Sorption of radionuclides on London clay

    International Nuclear Information System (INIS)

    Berry, J.A.; Bourke, P.J.; Green, A.; Littleboy, A.K.

    1989-02-01

    Techniques for studying the sorption of radionuclides on London clay have been investigated. This work involved the use of through-diffusion, in-diffusion, high-pressure convection and batch methods to study the sorption of iodide, strontium, caesium and americium. Through-diffusion and high-pressure convection methods were found to be most useful for investigating weakly and moderately sorbing nuclides and give realistic values for sorptivity. The batch technique remains the most practical method of obtaining large quantities of data within a relatively short timescale but gives very high sorptivity values. It is however very useful for intercomparisons of nuclides or geological media. The in-diffusion method requires further refinement for use with strongly sorbing nuclides. Good agreement between through-diffusion and high-pressure convection methods was obtained for the sorptivity of strontium, whilst trends observed for caesium by through-diffusion were confirmed by batch measurements. (author)

  7. Positron Spectroscopy of Nanodiamonds after Hydrogen Sorption

    Directory of Open Access Journals (Sweden)

    Lyudmila Nikitina

    2018-01-01

    Full Text Available The structure and defects of nanodiamonds influence the hydrogen sorption capacity. Positronium can be used as a sensor for detecting places with the most efficient capture of hydrogen atoms. Hydrogenation of carbon materials was performed from gas atmosphere. The concentration of hydrogen absorbed by the sample depends on the temperature and pressure. The concentration 1.2 wt % is achieved at the temperature of 243 K and the pressure of 0.6 MPa. The hydrogen saturation of nanodiamonds changes the positron lifetime. Increase of sorption cycle numbers effects the positron lifetime, as well as the parameters of the Doppler broadening of annihilation line. The electron-positron annihilation being a sensitive method, it allows detecting the electron density fluctuation of the carbon material after hydrogen saturation.

  8. Sorption studies of radioelements on geological materials

    International Nuclear Information System (INIS)

    Berry, John A.; Yui, Mikazu; Kitamura, Akira

    2007-11-01

    Batch sorption experiments have been carried out to study the sorption of uranium, technetium, curium, neptunium, actinium, protactinium, polonium, americium and plutonium onto bentonite, granodiorite and tuff. Mathematical modelling using the HARPHRQ program and the HATCHES database was carried out to predict the speciation of uranium and technetium in the equilibrated seawater, and neptunium, americium and plutonium in the rock equilibrated water. Review of the literature for thermodynamic data for curium, actinium, protactinium and polonium was carried out. Where sufficient data were available, predictions of the speciation and solubility were made. This report is a summary report of the experimental work conducted by AEA Technology during April 1991-March 1998, and the main results have been presented at Material Research Society Symposium Proceedings and published as proceedings of them. (author)

  9. Sorption behaviour of herbicides in soils

    International Nuclear Information System (INIS)

    Luchini, L.C.; Wiendl, F.M.; Ruegg, E.F.; Instituto Biologico, Sao Paulo

    1988-01-01

    Environmental contamination by herbicides is related with the sorption phenomenon of these compounds in the soils. The behaviour of paraquat, 2,4-D and diuron was studied in soils with different physico-chemical properties, through the Freundlich adsorption and desorption isotherms, using 14 C-radiolabeled herbicides. Results of the range of the adsorption-desorption of each herbicide was related mainly with the chemical characteristics of these compounds. (author) [pt

  10. Phosphate sorption characteristics of European alpine soils

    Czech Academy of Sciences Publication Activity Database

    Kaňa, Jiří; Kopáček, Jiří; Camarero, L.; Garcia-Pausas, J.

    2011-01-01

    Roč. 75, č. 3 (2011), s. 862-870 ISSN 0361-5995 R&D Projects: GA ČR(CZ) GA526/09/0567; GA AV ČR(CZ) KJB600960907 Grant - others:EU EMERGE(CZ) EVK1-CT-1999-00032 Institutional research plan: CEZ:AV0Z60170517 Keywords : phosphate sorption * alpine soil s * acidification Subject RIV: DJ - Water Pollution ; Quality Impact factor: 1.979, year: 2011

  11. Moisture sorption isotherms of dehydrated whey proteins

    Directory of Open Access Journals (Sweden)

    Suzana Rimac Brnčić

    2010-03-01

    Full Text Available Moisture sorption isotherms describe the relation between the moisture content of the dry material (food and relative humidity of the surrounding environment. The data obtained are important in modelling of drying process conditions, packaging and shelf-life stability of food that will provide maximum retaining of aroma, colour and texture as well as nutritive and biological value. The objective of this research was to establish the equilibrium moisture content and water activity, as well as monolayer value of two commercial powdered whey protein isolates before and after tribomechanical micronisation and enzymatic hydrolysis, respectively. At the same time it was necessary to evaluate the best moisture sorption isotherm equation to fit the experimental data. The equilibrium moisture contents in investigated samples were determined using standard gravimetric method at 20 °C. The range of water activities was 0.11 to 0.75. The monolayer moisture content was estimated from sorption data using Brunauer-Emmett-Teller (BET and Guggenheim-Anderson-de Boer (GAB models. The results have shown that tribomechanically treated whey protein isolates as well as protein hydrolizates had lower monolayer moisture content values as well as higher corresponding water activity. Therefore, in spite of the fact that they have lower moisture content, they can be storage at higher relative humidity compared to untreated samples. BET model gave better fit to experimental sorption data for a water activity range from 0.11-0.54, while GAB model gave the closest fit for a water activity to 0.75.

  12. Moisture sorption isotherms of dehydrated whey proteins

    OpenAIRE

    Suzana Rimac Brnčić; Vesna Lelas; Zoran Herceg; Marija Badanjak

    2010-01-01

    Moisture sorption isotherms describe the relation between the moisture content of the dry material (food) and relative humidity of the surrounding environment. The data obtained are important in modelling of drying process conditions, packaging and shelf-life stability of food that will provide maximum retaining of aroma, colour and texture as well as nutritive and biological value. The objective of this research was to establish the equilibrium moisture content and water activity, as well as...

  13. Sorption studies of caesium by complex hexacyanoferrates

    International Nuclear Information System (INIS)

    Jacobi, D.

    1992-01-01

    A comprehensive literature review was carried out on the preparation of complex hexacyanoferrates in a granular form suitable for use in a packed column. The preparation of sodium nickel hexacyanoferrate using a freeze-thaw method was studied in detail and a method developed to produce a consistent and reproducible granular product. The equilibrium and sorption kinetics were studied using batch and column tests, and the process modelled to predict performance under various conditions. (author)

  14. Understanding Residential Polarization in a Globalizing City

    Directory of Open Access Journals (Sweden)

    Ibrahim Rotimi Aliu

    2013-12-01

    Full Text Available This study examines the spatial polarization that characterizes the dwellings in the African leading megacity of Lagos. Data were collected through an extensive housing survey carried out on 1,485 household residences in 56 wards within 12 administrative units in Lagos megacity. The spatial dimension of residential density in the city generates three unique residential patterns which are low residential density (LRD, medium residential density (MRD, and high residential density (HRD areas. Descriptive and multivariate inferential statistics were used to render explanations for the spatial variations in the residential quality variables in the study area. Findings indicated that a clear difference exists in the residential quality within the three residential density areas of Lagos. High correlations exist among the residential quality indicators and housing type. The principal component analysis shows that residential polarizations that occur in the LRD, MRD, and HRD are based on the location, dwelling facility, interior and exterior quality, neighborhood integrity, social bond, barrier to entry, and security. The practical implications of residential polarizations along the residential density areas are explicitly expressed.

  15. Sorption of antimony on human teeth

    International Nuclear Information System (INIS)

    Nofal, M.; Amin, H.; Alian, G.

    1997-01-01

    The study of the uptake of toxic elements on human teeth represents an interesting research area, as the fate of these elements when present in the human food is of health significance. Since antimony is one of the common toxic elements and since, the chemical behaviour of antimony is similar to that of arsenic, one of the most important toxic elements commonly encountered in cases of food poisoning, it has been decided to investigate its uptake on human teeth and on other restoration materials. The radioactive tracer technique was used to evaluate the concentration of antimony sorbed on teeth. This tracer was obtained by irradiation of antimony metal in the reactor, subsequent dissolution in concentrated sulphuric acid, evaporation to dryness and making the solution 6 M in Hydrochloric acid (1). Antimony prepared in this way is in the trivalent state (Sb III). Sorption was studied in water, tea, coffee, red tea and chicken soup. The highest sorption was achieved from water and chicken soup and least sorption was noticed in case of coffee. The results are presented in the form of the depletion of the radioactivity (A) of antimony with time in presence of a tooth in water and other drinks

  16. Sorption of radon-222 to natural sediments

    International Nuclear Information System (INIS)

    Wong, C.S.; Chin, Y.P.; Gschwend, P.M.

    1992-01-01

    The sorption of radon to sediments was investigated, since this may affect the use of porewater radon profiles for estimating bed irrigation rates. Batch experiments showed that radon has an organic-carbon-normalized sediment-water partition coefficient (K oc , L kg oc -1 ) of 21.1 ± 2.9 for a Boston Harbor sediment, 25.3 ± 2.1 for a Charles River sediment, and 22.4 ± 2.6 for a Buzzards Bay sediment. These values are in close agreement with predictions using radon's octanol-water partition coefficient (K ow ), which was measured to be 32.4 ± 1.5. Temperature and ionic strength effects on K oc were estimated to be small. Given rapid sorption kinetics, the authors suggest that slurry stripping techniques used by many investigators to measure 222 Rn in sediment samples collect both sorbed and dissolved radon. Sorption effects were included in a transport model to obtain revised estimates of irrigation rates from existing literature profiles. Irrigation rates had to be increased over previously reported values in proportion to the sediment organic matter content

  17. Radionuclide sorption studies on abyssal red clays

    International Nuclear Information System (INIS)

    Erickson, K.L.

    1979-01-01

    The radionuclide sorption properties of a widely distributed abyssal red clay are being experimentally investigated using batch equilibration techniques. This paper summarizes sorption equilibrium data obtained when 0.68 N NaCl solutions containing either Tc, U, Pu, Am or Cm were contacted with samples of the red clay and also summarizes some initial results from experiments designed to determine the relative selectivity of the clay for various nuclides. Under mildly oxidizing conditions, the sorption equilibrium distribution coefficients for technetium were essentially zero. At solution-phase nuclide concentrations on the order of 10 -6 M and less and at solution pH values of about 6.9, the distribution coefficients for plutonium were about 3 x 10 3 m1/gm and for uranium, americium, and curium were about 10 5 ml/gm or greater. However, at solution pH values of about 2.7, the distribution coefficients for each of the nuclides were greatly diminished. Initial experiments conducted in order to determine the relative selectivity of the clay for cesium, barium, and cerium, indicated that the silicate phases in the clay were selective for cesium over barium and cerium. These experiments also indicated that the hydrous oxide phases were selective for cerium over barium and for barium over cesium

  18. Lead sorption-desorption from organic residues.

    Science.gov (United States)

    Duarte Zaragoza, Victor M; Carrillo, Rogelio; Gutierrez Castorena, Carmen M

    2011-01-01

    Sorption and desorption are mechanisms involved in the reduction of metal mobility and bioavailability in organic materials. Metal release from substrates is controlled by desorption. The capacity of coffee husk and pulp residues, vermicompost and cow manure to adsorb Pb2+ was evaluated. The mechanisms involved in the sorption process were also studied. Organic materials retained high concentrations of lead (up to 36,000 mg L(-1)); however, the mechanisms of sorption varied according to the characteristics of each material: degree of decomposition, pH, cation exchange capacity and percentage of organic matter. Vermicompost and manure removed 98% of the Pb from solution. Lead precipitated in manure and vermicompost, forming lead oxide (PbO) and lead ferrite (PbFe4O7). Adsorption isotherms did not fit to the typical Freundlich and Langmuir equations. Not only specific and non-specific adsorption was observed, but also precipitation and coprecipitation. Lead desorption from vermicompost and cow manure was less than 2%. For remediation of Pb-polluted sites, the application of vermicompost and manure is recommended in places with alkaline soils because Pb precipitation can be induced, whereas coffee pulp residue is recommended for acidic soils where Pb is adsorbed.

  19. Technical Problems of Residential Construction

    Science.gov (United States)

    Nowogońska, Beata; Cibis, Jerzy

    2017-10-01

    Beauty, utility, durability - these are the features of good architecture and should also be the distinguishing qualities of every residential building. But do beauty and utility remain along with the passing of time? Performance characteristics are an indicator of both, the technical as well as aesthetic state of buildings. Aesthetic needs are in disagreement with the merciless aging process. The beauty of a city is formed not only by the original forms of new residential buildings, but also by existing tenement housing; thus preserving their aesthetics becomes a necessity. Time is continuously passing and along with it, aging intensifies. The aging process is a natural phenomenon for every material. The life expectancy of building materials is also limited. Along with the passing of time, the technical state of residential buildings continuously deteriorates. With the passing of time, the aesthetic values and preferences of users of flats change and the usability of the building decreases. The permanence of buildings, including residential buildings, is shaped not only by the forces of nature but also by activities of humans. A long lifespan is ensured by carrying out ongoing, systematic renovation-repair works. It is thanks to them that buildings derived from past centuries are still being used, and their market attractiveness is not decreasing.

  20. Main challenges of residential areas

    Directory of Open Access Journals (Sweden)

    Oana Luca

    2017-06-01

    Full Text Available The present article is a position paper aiming to initiate a professional debate related to the aspects related to the urban dysfunctions leading to the wear of the residential areas. The paper proposes a definition of the wear process, identify the main causes leading to its occurrence and propose a number of solutions to neutralise the dysfunctions. The three wearing phases of residential areas components are emphasized, exploring their lifecycle. In order to perform the study of urban wear, the status of the residential areas components can be established and monitored, and also the variables of the function that can mathematically model the specific wear process may be considered. The paper is considered a first step for the model adjustment, to be tested and validated in the following steps. Based on the mathematical method and model, there can be created, in a potential future research, the possibility of determining the precarity degree for residential areas/neighbourhoods and cities, by minimising the subjective component of the analyses preceding the decision for renovation or regeneration.

  1. Residential solar-heating system

    Science.gov (United States)

    1978-01-01

    Complete residential solar-heating and hot-water system, when installed in highly-insulated energy-saver home, can supply large percentage of total energy demand for space heating and domestic hot water. System which uses water-heating energy storage can be scaled to meet requirements of building in which it is installed.

  2. Convergence of Residential Gateway Technology

    NARCIS (Netherlands)

    Hartog, F.T.H. den; Balm, M.; Jong, C.M. de; Kwaaitaal, J.J.B.

    2004-01-01

    A new OSI-based model is described that can be used for the classification of residential gateways. It is applied to analyze current gateway solutions and draw evolutionary paths for the medium to long term. From this it is concluded that particularly set-top boxes and broadband modems, as opposed

  3. Convergence of residential gateway technology

    NARCIS (Netherlands)

    Hartog, den F.T.H.; Balm, M.; Jong, de C.M.; Kwaaitaal, J.J.B.

    2004-01-01

    A new OSI-based model is described that can be used for the classification of residential gateways. It is applied to analyze current gateway solutions and draw evolutionary paths for the medium to long term. From this it is concluded that particularly set-top boxes and broadband modems, as opposed

  4. Trends of Sustainable Residential Architecture

    OpenAIRE

    Narvydas, A

    2014-01-01

    The article is based on Master’s research conducted during Scottish Housing Expo 2010. The aim of the research was to determine the prevailing trends in sustainable residential architecture. Each trend can be described by features detected during visual and technical observation of project data. Based on that architects may predict possible problems related to a specific trend.

  5. Reduce tax on residential mobility

    NARCIS (Netherlands)

    van Ewijk, C.; van Leuvensteijn, M.

    2010-01-01

    How can Europe increase structural growth? This column argues that labour market flexibility is key. As a major barrier to labour movement is rigidity in the housing market, abolishing transfer taxes on residential property could result in gains of up to 0.4% of GDP.

  6. Zones 30 : urban residential areas.

    NARCIS (Netherlands)

    2006-01-01

    Sustainable Safety uses a road categorization in which through traffic is concentrated on motorways and other main roads. In residential areas, which have a living, shopping, or work function, through traffic is discouraged by setting a speed limit of 30 km/h, and by speed reducing measures such as

  7. Mathematical Modeling of Moisture Sorption Isotherms and Determination of Isosteric Heats of Sorption of Ziziphus Leaves

    Directory of Open Access Journals (Sweden)

    Amel Saad

    2014-01-01

    Full Text Available Desorption and adsorption equilibrium moisture isotherms of Ziziphus spina-christi leaves were determined using the gravimetric-static method at 30, 40, and 50°C for water activity (aw ranging from 0.057 to 0.898. At a given aw, the results show that the moisture content decreases with increasing temperature. A hysteresis effect was observed. The experimental data of sorption were fitted by eight models (GAB, BET, Henderson-Thompson, modified-Chung Pfost, Halsey, Oswin, Peleg, and Adam and Shove. After evaluating the models according to several criteria, the Peleg and Oswin models were found to be the most suitable for describing the sorption curves. The net isosteric heats of desorption and adsorption of Ziziphus spina-christi leaves were calculated by applying the Clausius-Clapeyron equation to the sorption isotherms and an expression for predicting these thermodynamic properties was given.

  8. Geochemical modelling of the sorption of tetravalent radioelements

    International Nuclear Information System (INIS)

    Bond, K.A.; Tweed, C.J.

    1991-05-01

    The results of an experimental study of the sorption of a range of tetravalent radioelements, plutonium (IV), tin (IV), thorium(IV) and uranium(IV), onto clay at pH8 and pH11 have been successfully simulated using a triple layer sorption model. The model has been incorporated into HARPHRQ, a geochemical program based on PHREEQE. The model has been parameterised using data for sorption onto ferric oxyhydroxide and goethite. The effects of hydroxycarboxylic acids on the sorption process have also been investigated experimentally. It was generally observed that in the presence of 2x10 -3 M gluconate, sorption was reduced by up two orders of magnitude. The model has satisfactorily simulated these lower sorptivities, through assuming competing sorption and complexation reactions. This work, therefore, further confirms the need to take account of such organic materials in safety assessment modelling. (author)

  9. Investigation of metal ions sorption of brown peat moss powder

    Science.gov (United States)

    Kelus, Nadezhda; Blokhina, Elena; Novikov, Dmitry; Novikova, Yaroslavna; Chuchalin, Vladimir

    2017-11-01

    For regularities research of sorptive extraction of heavy metal ions by cellulose and its derivates from aquatic solution of electrolytes it is necessary to find possible mechanism of sorption process and to choice a model describing this process. The present article investigates the regularities of aliovalent metals sorption on brown peat moss powder. The results show that sorption isotherm of Al3+ ions is described by Freundlich isotherm and sorption isotherms of Na+ i Ni2+ are described by Langmuir isotherm. To identify the mechanisms of brown peat moss powder sorption the IR-spectra of the initial brown peat moss powder samples and brown peat moss powder samples after Ni (II) sorption were studied. Metal ion binding mechanisms by brown peat moss powder points to ion exchange, physical adsorption, and complex formation with hydroxyl and carboxyl groups.

  10. Sorption of citalopram, irbesartan and fexofenadine in soils: Estimation of sorption coefficients from soil properties.

    Science.gov (United States)

    Klement, Aleš; Kodešová, Radka; Bauerová, Martina; Golovko, Oksana; Kočárek, Martin; Fér, Miroslav; Koba, Olga; Nikodem, Antonín; Grabic, Roman

    2018-03-01

    The sorption of 3 pharmaceuticals, which may exist in 4 different forms depending on the solution pH (irbesartan in cationic, neutral and anionic, fexofenadine in cationic, zwitter-ionic and anionic, and citalopram cationic and neutral), in seven different soils was studied. The measured sorption isotherms were described by Freundlich equations, and the sorption coefficients, K F (for the fixed n exponent for each compound), were related to the soil properties to derive relationships for estimating the sorption coefficients from the soil properties (i.e., pedotransfer rules). The largest sorption was obtained for citalopram (average K F value for n = 1 was 1838 cm 3  g -1 ) followed by fexofenadine (K F  = 35.1 cm 3/n μg 1-1/n g -1 , n = 1.19) and irbesartan (K F  = 3.96 cm 3/n μg 1-1/n g -1 , n = 1.10). The behavior of citalopram (CIT) in soils was different than the behaviors of irbesartan (IRB) and fexofenadine (FEX). Different trends were documented according to the correlation coefficients between the K F values for different compounds (R IRB,FEX  = 0.895, p-valuesoil properties in the pedotransfer functions. While the K F value for citalopram was positively related to base cation saturation (BCS) or sorption complex saturation (SCS) and negatively correlated to the organic carbon content (Cox), the K F values of irbesartan and fexofenadine were negatively related to BCS, SCS or the clay content and positively related to Cox. The best estimates were obtained by combining BCS and Cox for citalopram (R 2  = 93.4), SCS and Cox for irbesartan (R 2  = 96.3), and clay content and Cox for fexofenadine (R 2  = 82.9). Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Influence of selected factors on strontium sorption on bentonites

    International Nuclear Information System (INIS)

    Galambos, M.; Kufcakova, J.; Rajec, P.

    2007-01-01

    Sorption on bentonite will play an important role in retarding the migration of radionuclides from a waste repository. Bentonite is a natural clay and one of the most promising candidates for use as a buffer material in the geological disposal systems for high-level nuclear waste. It is intended to isolate metal canisters with highly radioactive waste products from the surrounding rocks because of its ability to retard the movement of radionuclides by sorption. Bentonite is characterized by low permeability, water swelling capability and excellent sorption potential for cationic radionuclides. To correctly assess the sorption potential of radionuclides on bentonite is essential for the development of predictive migration models. The sorption of strontium on bentonite from different Slovak deposits - Jelsovy potok, Kopernica and Lieskovec has been investigated under various experimental conditions, such as contact time, sorbate concentrations, presence of complementary cation. Sorption was studied using the batch technique. The uptake of Sr was rapid and equilibrium was reached almost instantaneously. The instantaneous uptake may be due to adsorption and/or exchange of the metal with some ions on the surface of the adsorbent. The best sorption characteristics distinguish bentonite Kopernica, sorption capacity for Sr of the fraction under 45 mm is 0,48 mmol·g -1 for Sr. The highest values of distribution coefficient were reached for the bentonite Jelsovy potok. Radiation stability has been investigated, the higher sorption parameters were observed for the irradiated bentonites, which can be explained by the increase of specific surface of the bentonite samples. The presence of complementary cations depresses the sorption of Sr on bentonite. Cations Ca 2+ exhibit higher effect on cesium sorption than the Na 2+ ions. Results indicate that the sorption of Sr 2+ on bentonite will be affected by the presence of high concentrations of various salts in the waste water

  12. suitability of murram for phosphorus sorption in constructed wetlands

    African Journals Online (AJOL)

    Mimi

    sorption isotherms, determination of Phosphorus sorption capacity of the substrates, determination of. Phosphorus sorption as the function of time and determination of effect of temperature on the ... (Na2O + K2O) % SiO2. %. P2O5. %. TiO2. %. LOI. %. 19.2. 1.3. 0.69. 5.13. 0.05. 6.7. 61.9. 0.04. 0.51. 4.4. As presented in ...

  13. Mechanism of cesium sorption on potassium titanium hexacyanoferrate

    International Nuclear Information System (INIS)

    Sun Yongxia; Xu Shiping; Song Chongli

    1998-01-01

    The mechanism of cesium sorption on potassium titanium hexacyanoferrate is described. The dependence of the sorption speed on temperature, particle granule size, and the stirring speed is studied. The results show that the sorption process is controlled by liquid film diffusion and particle diffusion. An exchange reaction occurs mainly between K + in the exchanger and Cs + in the solution, i.e. potassium titanium hexacyanoferrate, and Cs + of simulated high-level liquid waste

  14. Sorption of curium by silica colloids: Effect of humic acid

    International Nuclear Information System (INIS)

    Kar, Aishwarya Soumitra; Kumar, Sumit; Tomar, B.S.; Manchanda, V.K.

    2011-01-01

    Sorption of curium by silica colloids has been studied as a function of pH and ionic strength using 244 Cm as a tracer. The sorption was found to increase with increasing pH and reach a saturation value of ∼95% at pH beyond 5.3. The effect of humic acid on the sorption of 244 Cm onto silica was studied by changing the order of addition of the metal ion and humic acid. In general, in the presence of humic acid (2 mg/L), the sorption increased at lower pH (<5) while it decreased in the pH range 6.5-8 and above pH 8, the sorption was found to increase again. As curium forms strong complex with humic acid, its presence results in the enhancement of curium sorption at lower pH. At higher pH the humic acid present in the solution competes with the surface sites for curium thus decreasing the sorption. The decrease in the Cm sorption in presence of humic acid was found to be less when humic acid was added after the addition of curium. Linear additive model qualitatively reproduced the profile of the Cm(III) sorption by silica in presence of humic acid at least in the lower pH region, however it failed to yield quantitative agreement with the experimental results. The results of the present study evidenced the incorporation of Cm into the silica matrix.

  15. Development of Web-based Software for Sorption Database

    International Nuclear Information System (INIS)

    Han, Byoung Sub; Lee, Jae Min; Seo, Min Seok; Kim, Dong Keon

    2009-08-01

    Sorption studies of radionuclides are important parts of research on radioactive waste disposal which is commonly faced in most countries where nuclear programs (power production, a variety of peaceful applications, and research) are implemented. The Sorption Database (DB) plays a very important role in the safety assessment of the radioactive waste disposal. The Sorption DB which is opened externally can be used as reference material of establishing a national policy by improving and changing the pre-developed Sorption program to be web-based. From the industrial point of view, if the Sorption DB is opened to the outside, the safety-related confidence can be achieved for nuclear industry. As the information of Sorption DB is opened, not only credibility can be provided to the administration, local governments and nearby residents, but also input of the collected information can be achieved by online. In addition, the reference material and external awareness/reliability about the domestic level of the Sorption DB management system and the current state can be achieved internationally. In order to provide the information of Sorption DB to users in more efficient way, the analysis and complement of management and search capability for the existing Sorption DB program have been performed and web-based management system has been built to provide services to users. In addition, by applying statistical techniques, it has been designed and implemented to display the accuracy and error of the information

  16. Determining Sorption Rate by a Continuous Gravimetric Method

    National Research Council Canada - National Science Library

    Hall, Monicia R; Procell, Lawrence R; Bartram, Philip W; Shuely, Wendel J

    2003-01-01

    ... were automatically recorded in an Excel file while CARC coupons were submerged in solvent. Initial sorption rates were determined for butyl acetate, butyl ether, cyclohexane and propylene carbonate...

  17. The sorption of polonium, actinium and protactinium onto geological materials

    International Nuclear Information System (INIS)

    Baston, G.M.N.; Berry, J.A.; Brownsword, M.; Heath, T.G.; Ilett, D.J.; McCrohon, R.; Tweed, C.J.; Yui, M.

    1999-01-01

    This paper describes a combined experimental and modeling program of generic sorption studies to increase confidence in the performance assessment for a potential high-level radioactive waste repository in Japan. The sorption of polonium, actinium and protactinium onto geological materials has been investigated. Sorption of these radioelements onto bentonite, tuff and granodiorite from equilibrated de-ionized water was studied under reducing conditions at room temperature. In addition, the sorption of actinium and protactinium was investigated at 60 C. Thermodynamic chemical modeling was carried out to aid interpretation of the results

  18. The sorption of polonium, actinium and protactinium onto geological materials

    Energy Technology Data Exchange (ETDEWEB)

    Baston, G.M.N.; Berry, J.A.; Brownsword, M.; Heath, T.G.; Ilett, D.J.; McCrohon, R.; Tweed, C.J.; Yui, M.

    1999-07-01

    This paper describes a combined experimental and modeling program of generic sorption studies to increase confidence in the performance assessment for a potential high-level radioactive waste repository in Japan. The sorption of polonium, actinium and protactinium onto geological materials has been investigated. Sorption of these radioelements onto bentonite, tuff and granodiorite from equilibrated de-ionized water was studied under reducing conditions at room temperature. In addition, the sorption of actinium and protactinium was investigated at 60 C. Thermodynamic chemical modeling was carried out to aid interpretation of the results.

  19. Comparison of neptunium sorption results using batch and column techniques

    International Nuclear Information System (INIS)

    Triay, I.R.; Furlano, A.C.; Weaver, S.C.; Chipera, S.J.; Bish, D.L.

    1996-08-01

    We used crushed-rock columns to study the sorption retardation of neptunium by zeolitic, devitrified, and vitric tuffs typical of those at the site of the potential high-level nuclear waste repository at Yucca Mountain, Nevada. We used two sodium bicarbonate waters (groundwater from Well J-13 at the site and water prepared to simulate groundwater from Well UE-25p No. 1) under oxidizing conditions. It was found that values of the sorption distribution coefficient, Kd, obtained from these column experiments under flowing conditions, regardless of the water or the water velocity used, agreed well with those obtained earlier from batch sorption experiments under static conditions. The batch sorption distribution coefficient can be used to predict the arrival time for neptunium eluted through the columns. On the other hand, the elution curves showed dispersivity, which implies that neptunium sorption in these tuffs may be nonlinear, irreversible, or noninstantaneous. As a result, use of a batch sorption distribution coefficient to calculate neptunium transport through Yucca Mountain tuffs would yield conservative values for neptunium release from the site. We also noted that neptunium (present as the anionic neptunyl carbonate complex) never eluted prior to tritiated water, which implies that charge exclusion does not appear to exclude neptunium from the tuff pores. The column experiments corroborated the trends observed in batch sorption experiments: neptunium sorption onto devitrified and vitric tuffs is minimal and sorption onto zeolitic tuffs decreases as the amount of sodium and bicarbonate/carbonate in the water increases

  20. Experimental study of strontium sorption on fissure filling material

    Energy Technology Data Exchange (ETDEWEB)

    Eriksen, T E; Cui, Daqing [Royal Institute of Technology, Stockholm (Sweden). Dept. of Chemistry

    1994-12-01

    We have carried out a comparative study of sorption and desorption of strontium in groundwater on separated magnetic and size fractions of fissure filling material taken from natural fissures in granitic rock. Complete reversibility of the sorption process was demonstrated by identical Freundlich isotherms, isotopic exchangeability and pH dependence of the distribution coefficients Rd. The sorption was found to be strongly pH dependent in the range 3-11. The pH effect can be accommodated in the sorption model by considering the surface areas and surface charges of the minerals in the fissure filling material. 20 refs, 9 figs, 3 tabs.

  1. Experimental study of strontium sorption on fissure filling material

    International Nuclear Information System (INIS)

    Eriksen, T.E.; Cui, Daqing

    1994-12-01

    We have carried out a comparative study of sorption and desorption of strontium in groundwater on separated magnetic and size fractions of fissure filling material taken from natural fissures in granitic rock. Complete reversibility of the sorption process was demonstrated by identical Freundlich isotherms, isotopic exchangeability and pH dependence of the distribution coefficients Rd. The sorption was found to be strongly pH dependent in the range 3-11. The pH effect can be accommodated in the sorption model by considering the surface areas and surface charges of the minerals in the fissure filling material. 20 refs, 9 figs, 3 tabs

  2. Acquisition of sorption isotherms for modified woods by the use of dynamic vapour sorption instrumentation. Principles and Practice

    DEFF Research Database (Denmark)

    Engelund, Emil Tang; Klamer, Morten; Venås, Thomas Mark

    2010-01-01

    The complex wood-water relationship has been the topic of numerous studies. Sorption isotherms – in particular – have been derived for hundreds of wood species, their sap- and heartwood sections as well as for decayed, engineered and modified wood materials. However, the traditional methods...... for obtaining sorption isotherms are very time consuming. With new dynamic vapour sorption (DVS) instrumentation, the acquisition of data for constructing sorption isotherms is suddenly dramatically lowered. Where the traditional methods often required months, data can now be obtained in a matter of days...... depending on the number of data points required. The fast data acquisition makes DVS a useful tool in studying the sorption properties of wood, and especially in studying the effect of different modification treatments on these properties. This study includes an investigation of the sorption properties...

  3. 3.3. Sorption activity of cross-linked polymers of ethynyl-piperidol

    International Nuclear Information System (INIS)

    Khalikov, D.Kh.

    2012-01-01

    The sorption activity of cross-linked polymers of ethynyl-piperidol was studied. The bilirubin sorption was studied as well. The kinetic of bilirubin sorption and human serum albumin at their joint presence in hydrogel solutions was defined. Bilirubin sorption and change of albumin composition was considered. The sorption of middle molecular peptides was considered as well. The sorption of endogenous toxin by means of ethynyl-piperidol polymers was done.

  4. Sorption of nitrate onto amine-crosslinked wheat straw: characteristics, column sorption and desorption properties.

    Science.gov (United States)

    Xing, Xu; Gao, Bao-Yu; Zhong, Qian-Qian; Yue, Qin-Yan; Li, Qian

    2011-02-15

    The nitrate removal process was evaluated using a fixed-bed column packed with amine-crosslinked wheat straw (AC-WS). Column sorption and desorption characteristics of nitrate were studied extensively. Solid-state (13)C NMR and zeta potential analysis validated the existence of crosslinked amine groups in AC-WS. Raman shift of the nitrate peaks suggested the electrostatic attraction between the adsorbed ions and positively charged amine sites. The column sorption capacity (q(ed)) of the AC-WS for nitrate was 87.27 mg g(-1) in comparison with the raw WS of 0.57 mg g(-1). Nitrate sorption in column was affected by bed height, influent nitrate concentration, flow rate and pH, and of all these, influent pH demonstrated an essential effect on the performance of the column. In addition, desorption and dynamic elution tests were repeated for several cycles, with high desorption rate and slight losses in its initial column sorption capacity. Copyright © 2010 Elsevier B.V. All rights reserved.

  5. Humidity sorption on natural building stone

    Science.gov (United States)

    Franzen, C.; Mirwald, P.

    2003-04-01

    processes, physical, chemical or biological, depend on the presence of water. Like most porous materials building stone respond on humidity by water uptake. The sorption isotherm represents the equilibrium moisture, specific for each material. The determination of the isotherm for stone of low and small porosity like marble is difficult. With the help of a newly developed water sorption analysis chamber [2], which allows the simultaneous measurement of 11 samples, good results on stone/rock samples have been obtained. Even at marble species with pore volumes lower than 0.4 % isotherms are measured. This analytical method offers new insights in the pore behaviour of low porosity materials. The advantages of this technique which supplements other techniques (e.g. BET, Hg-porosimetry) are: i) the testing agent is identical to the weathering agent, water; ii) the atmospheric parameters at the measurement reflect the natural conditions - thus no changes to the material properties have to be considered; iii) due to the small diameter of the water molecule (~0.28 nm), smaller pores are reached than e.g. with N2 (~0.31 nm). Sorption isotherms of sandstone (Baumberg, Obernkirchen, Groeden), granite (Brixen), and marble (Sterzing, Laas) are presented. Particular as to marbles the resolution is considerably higher. A previously observed negative hysteresis [3] seems an effect due to limited data resolution. [1] Snethlage, R. (1984) Steinkonservierung, Bayer. LA Denkmalpflege, Ah. 22, 203 S. [2] Griesser, U.J., Dillenz, J. (2002) Neuartiges, vollautomatisches Feuchtesorptionsprüfgerät mit hohem Probendurchsatz, Feuchtetag 2002, Weimar, 85-93. [3] Fimmel, R. (1996) Verwitterungsverhalten der alpinen Marmore von Laas und Sterzing, Diss. Univ. Ibk, 116 S.

  6. EXAFS study of plutonium sorption onto kaolinite

    International Nuclear Information System (INIS)

    Reich, T.Y.; Banik, L.; Buda, R.A.; Amayri, S.; Drebert, J.; Kratz, J.V.; Trautmann, N.; Reich, T.; Ageev, A.L.; Korshunov, M.E.

    2007-01-01

    The uptake mechanism of plutonium by kaolinite was investigated by applying X-ray absorption spectroscopy to batch sorption samples (total Pu concentrations 1 and 10 μM; 4 g kaolinite/L in 0.1 M NaClO 4 ; 1 ≤ pH ≤ 9; presence and absence of ambient CO 2 ). For XAFS measurements, one sample was prepared from a Pu(III) solution at pH 6 under argon atmosphere. Three samples were obtained by sorption of Pu(IV) at pH I, 4, and 9 in an air-equilibrated system. The Pu L III -edge XANES spectra indicated that in all samples, including the Pu(III) sample, plutonium is sorbed at the kaolinite surface as Pu(IV). The Pu L III -edge k 3 -weighted EXAFS spectra showed eight oxygen atoms at an average Pu-O distance of 2.3 angstrom. Two Pu atoms were detected at ∼ 3.7 angstrom in all spectra, indicating the formation of polynuclear Pu(IV) species at the kaolinite surface. For the sample prepared from Pu(III) solution, an additional Pu-O shell at 3.2 angstrom was observed. The spectra of samples prepared from Pu(IV) included a Pu-Al/Si co-ordination shell at approximately 3.6 angstrom, indicating formation of inner-sphere sorption complexes. The structural models used in the least-squares fits were confirmed by an alternative EXAFS data analysis approach based on a modified Tikhonov regularization method. (authors)

  7. Sorption of pesticides to aquifer minerals

    DEFF Research Database (Denmark)

    Clausen, Liselotte; Fabricius, Ida Lykke

    2000-01-01

    This paper summarizes results from a work were the sorption of five pesticides on seven minerals were studied in order to quantify the adsorption to different mineral surfaces. Investigated mineral phases are: quartz, calcite, kaolinite, a-alumina, and three iron oxides (2-line ferrihydrite......, goethite, lepidocrocite). Selected pesticides are: atrazine, isoproturon, mecoprop, 2,4-D, and bentazone. The results demonstrate that pesticides adsorb to pure mineral surfaces. However, the size of the adsorption depends on the type of pesticide and the type of mineral....

  8. Tritium sorption by cement and subsequent release

    International Nuclear Information System (INIS)

    Ono, F.; Tanaka, S.; Yamawaki, M.

    1994-01-01

    In a fusion reactor or tritium handling facilities, contamination of concrete by tritium and subsequent release from it to the reactor or experimental rooms is a matter of problem for safety control of tritium and management of operational environment. In order to evaluate these tritium behavior, interaction of tritiated water with concrete or cement should be clarified. In the present study, HTO sorption and subsequent release from cement were studied by combining various experimental methods. From the basic studies on tritium-cement interactions, it has become possible to evaluate tritium uptake by cement or concrete and subsequent tritium release behavior as well as tritium removing methods from them

  9. Thermodynamics of imidacloprid sorption in Croatian soils

    Science.gov (United States)

    Milin, Čedomila; Broznic, Dalibor

    2015-04-01

    Neonicotinoids are increasingly replacing the organophosphate and methylcarbamate acetylcholinesterase inhibitors which are losing their effectiveness because of selection for resistant pest populations. Imidacloprid is the most important neonicotinoid with low soil persistence, high insecticidal potency and relatively low mammalian toxicity. In Croatia, imidacloprid is most commonly used in olive growing areas, including Istria and Kvarner islands, as an effective means of olive fruit fly infestation control. Sorption-desorption behavior of imidacloprid in six soils collected from five coastal regions in Croatia at 20, 30 and 40°C was investigated using batch equilibrium technique. Isothermal data were applied to Freundlich, Langmuir and Temkin equation, and the thermodynamic parameters ΔH°, ΔG°, ΔS° were calculated. The sorption isotherm curves were of non-linear and may be classified as L-type suggesting a relatively high sorption capacity for imidacloprid. Our results showed that the KFsor values decreased for all the tested soils as the temperature increases, indicating that the temperature strongly influence the sorption. Values of ΔG° were negative (-4.65 to -2.00 kJ/mol) indicating that at all experimental temperatures the interactions of imidacloprid with soils were spontaneous process. The negative and small ΔH° values (-19.79 to -8.89 kJ/mol) were in the range of weak forces, such as H-bonds, consistent with interactions and par¬titioning of the imidacloprid molecules into soil organic matter. The ΔS° values followed the range of -57.12 to -14.51 J/molK, suggesting that imidacloprid molecules lose entropy during transition from the solution phase to soil surface. It was found that imidacloprid desorption from soil was concentration and temperature dependent, i.e. at lower imidacloprid concentrations and temperature, lower desorption percentage occurred. Desorption studies revealed that hysteretic behavior under different temperature

  10. Sorption of radiostrontium from liquid metallic rubidium

    International Nuclear Information System (INIS)

    Zhujkov, B.L.; Kokhnyuk, V.M.; Vincent, J.S.

    2008-01-01

    One studied the radiostrontium (in particular, 82 Sr) sorption from the liquid metallic Rb in various inorganic sorbents (both metals and oxides). One studied the temperature dependence and the dynamics of the adsorption and put forward an interpretation of the observed mechanisms. The elaborated approach enables to extract 82 Sr efficiently from the Rb targets upon their irradiation by the accelerated protons. One studies various procedures and the applicability of the process to ensure elaboration of a new highly efficient process to produce 82 Sr, in particular, with the targets of the circulating Rb [ru

  11. Pu sorption to activated conglomerate anaerobic bacteria

    International Nuclear Information System (INIS)

    Sasaki, Takayuki; Kudo, Akira

    2001-01-01

    The sorption of Pu to the anaerobic bacteria activated under specific conditions of temperature, pH and depleted nutrients after long dormant period was investigated. After 4 h at neutral pH, the distribution coefficient (K d ) between bacteria and aqueous phase at 308 and 278 K had around 10 3 to 10 4 . After over 5 days, however, the K d at only 308 K had increased to over 10 5 . Sterilized (dead) and dormant anaerobic bacteria adsorbed Pu to the same extent. (author)

  12. Residential mobility and childhood leukemia.

    Science.gov (United States)

    Amoon, A T; Oksuzyan, S; Crespi, C M; Arah, O A; Cockburn, M; Vergara, X; Kheifets, L

    2018-07-01

    Studies of environmental exposures and childhood leukemia studies do not usually account for residential mobility. Yet, in addition to being a potential risk factor, mobility can induce selection bias, confounding, or measurement error in such studies. Using data collected for California Powerline Study (CAPS), we attempt to disentangle the effect of mobility. We analyzed data from a population-based case-control study of childhood leukemia using cases who were born in California and diagnosed between 1988 and 2008 and birth certificate controls. We used stratified logistic regression, case-only analysis, and propensity-score adjustments to assess predictors of residential mobility between birth and diagnosis, and account for potential confounding due to residential mobility. Children who moved tended to be older, lived in housing other than single-family homes, had younger mothers and fewer siblings, and were of lower socioeconomic status. Odds ratios for leukemia among non-movers living mobility, including dwelling type, increased odds ratios for leukemia to 2.61 (95% CI: 1.76-3.86) for living mobility of childhood leukemia cases varied by several sociodemographic characteristics, but not by the distance to the nearest power line or calculated magnetic fields. Mobility appears to be an unlikely explanation for the associations observed between power lines exposure and childhood leukemia. Copyright © 2018 Elsevier Inc. All rights reserved.

  13. RESIDENTIAL MORTGAGE IN MODERN RUSSIA

    Directory of Open Access Journals (Sweden)

    Dementiev N. P.

    2015-03-01

    Full Text Available The article presents a comparative analysis of residential mortgages in Russia and the United States. The primary ways of mortgage refinancing are outlined. Predominance of the elements of two-level refinancing system of residential mortgage in Russia and the United States is shown. The activity of the Agency for Housing Mortgage Lending (AHML, the basic tool of the Russian government’s mortgage policy, is described in detail. In its objectives and functions the AHML is similar to the American mortgage agencies Ginnie Mae, Fannie Mae and Freddie Mac. Similarities were identified in the Russian and US residential mortgages in the pre-crisis period (high rates of mortgage growth, favourable economic conjuncture, low interest rates, large increase in house prices, speculative housing demand. During the mortgage crisis, the policies of the Russian and US governments and monetary authorities had also much in common (monetary policy easing, cheap central banks loans, extended facilities of mortgage refinancing on the part of state agencies, mortgage rescue scheme, social mortgage programs. But the scope of mortgage in Russia is enormously narrow as compared to the US mortgage. The most important reason for that - low incomes of the Russian population.

  14. Column Chromatography To Obtain Organic Cation Sorption Isotherms.

    Science.gov (United States)

    Jolin, William C; Sullivan, James; Vasudevan, Dharni; MacKay, Allison A

    2016-08-02

    Column chromatography was evaluated as a method to obtain organic cation sorption isotherms for environmental solids while using the peak skewness to identify the linear range of the sorption isotherm. Custom packed HPLC columns and standard batch sorption techniques were used to intercompare sorption isotherms and solid-water sorption coefficients (Kd) for four organic cations (benzylamine, 2,4-dichlorobenzylamine, phenyltrimethylammonium, oxytetracycline) with two aluminosilicate clay minerals and one soil. A comparison of Freundlich isotherm parameters revealed isotherm linearity or nonlinearity was not significantly different between column chromatography and traditional batch experiments. Importantly, skewness (a metric of eluting peak symmetry) analysis of eluting peaks can establish isotherm linearity, thereby enabling a less labor intensive means to generate the extensive data sets of linear Kd values required for the development of predictive sorption models. Our findings clearly show that column chromatography can reproduce sorption measures from conventional batch experiments with the benefit of lower labor-intensity, faster analysis times, and allow for consistent sorption measures across laboratories with distinct chromatography instrumentation.

  15. Sorption of Triangular Silver Nanoplates on Polyurethane Foam

    Science.gov (United States)

    Furletov, A. A.; Apyari, V. V.; Garshev, A. V.; Volkov, P. A.; Tolmacheva, V. V.; Dmitrienko, S. G.

    2018-02-01

    The sorption of triangular silver nanoplates on polyurethane foam is investigated as a procedure for creating a nanocomposite sensing material for subsequent use in optical means of chemical analysis. Triangular silver nanoplates are synthesized and characterized, and a simple sorption technique for the formation of a composite material based on these nanoplates is proposed.

  16. Sorption and desorption of diuron in Oxisol under biochar application

    Directory of Open Access Journals (Sweden)

    Fabiano André Petter

    Full Text Available ABSTRACT The objective of this study was to verify the kinetics of sorption and desorption of diuron in an Oxisol under application of biochar. The samples were collected in a field experiment conducted in randomized design blocks consisted of 2 base fertilization levels (0 and 400 kg∙ha−1 NPK 00-20-20 fertilizer formula and 3 doses of biochar (0, 8 and 16 Mg∙ha−1. In the evaluation of sorption and desorption, Batch Equilibrium method was used. The kinetics of sorption and desorption of diuron, total organic carbon, fulvic acid, humic acid and humin, pH and partition coefficient to organic carbon were evaluated. The Freundlich isotherm was adjusted appropriately to describe diuron sorption kinetics in all the studied treatments. The application of biochar provided increment in the sorption (Kf and reduction in the desorption of diuron in 64 and 44%, respectively. This effect is attributed to the biochar contribution to the total organic carbon and C-humin and of these to diuron through hydrophobic interactions and hydrogen bonds. The positive correlation between the partition coefficient to organic carbon and Kf confirms the importance of soil organic compartment in the sorption of diuron. There was no competition of NPK fertilizer for the same sorption site of diuron. The increase and reduction in sorption and desorption, respectively, show that the application of biochar is an important alternative for the remediation of soil leaching of diuron, especially in sandy soils.

  17. Kinetics and reversibility of micropollutant sorption in sludge.

    Science.gov (United States)

    Barret, Maialen; Carrère, Hélène; Patau, Mathieu; Patureau, Dominique

    2011-10-01

    The fate of micropollutants throughout wastewater treatment systems is highly dependent on their sorption interactions with sludge matter. In this study, both the sorption and desorption kinetics of polycyclic aromatic hydrocarbons (PAHs) in activated sludge were shown to be very rapid in comparison to biodegradation kinetics. It was concluded that PAH transfer does not limit their biodegradation and that their fate is governed by the sorption/desorption equilibrium state. The effect of contact time between sludge and PAHs was also investigated. It was shown that aging did not influence the sorption/desorption equilibrium although PAH losses during aging suggest that sequestration phenomena had occurred. This implies that for PAH sorption assessment within treatment processes there is no need to include a contact time dimension. As a consequence, thanks to an innovative approach taking into account sorption equilibria and sequestration, this work has demonstrated that studies in the literature which, in main, deal with micropollutant sorption in sewage sludge with only a short contact time can be extrapolated to real systems in which sorption, desorption and aging occur.

  18. CO2 sorption of a ceramic separation membrane

    NARCIS (Netherlands)

    Wormeester, Herbert; Benes, Nieck Edwin; Spijksma, G.I.; Verweij, H.; Poelsema, Bene

    2004-01-01

    The ellipsometric characterization of the CO2 sorption of a silica membrane provides a fast and accurate technique for the characterization of maximum sorption and the heat of adsorption. Both parameters are evaluated for the 73 nm thick silica layer as well as the 1650 nm thick supporting γ-layer.

  19. Status report on SIRS: sorption information retrieval system

    International Nuclear Information System (INIS)

    Hostetler, D.D.; Serne, R.J.; Baldwin, A.J.; Petrie, G.M.

    1980-11-01

    Two major uses were identified for the Sorption Information Retrieval System: (1) to aid geochemists in the elucidation of sorption mechanisms; and (2) to aid safety assessment modelers in selection of Kds for any given scenerio. Other benefits such as providing an auditable vehicle for the Kd selection were also discussed

  20. Effect of humic acid (HA) on sulfonamide sorption by biochars

    International Nuclear Information System (INIS)

    Lian, Fei; Sun, Binbin; Chen, Xi; Zhu, Lingyan; Liu, Zhongqi; Xing, Baoshan

    2015-01-01

    Effect of quantity and fractionation of loaded humic acid (HA) on biochar sorption for sulfonamides was investigated. The HA was applied in two different modes, i.e. pre-coating and co-introduction with sorbate. In pre-coating mode, the polar fractions of HA tended to interact with low-temperature biochars via H-bonding, while the hydrophobic fractions were likely to be adsorbed by high-temperature biochars through hydrophobic and π-π interactions, leading to different composition and structure of the HA adlayers. The influences of HA fractionation on biochar sorption for sulfonamides varied significantly, depending on the nature of interaction between HA fraction and sorbate. Meanwhile, co-introduction of HA with sulfonamides revealed that the effect of HA on sulfonamide sorption was also dependent on HA concentration. These findings suggest that the amount and fractionation of adsorbed HA are tailored by the surface properties of underlying biochars, which differently affect the sorption for organic contaminants. - Highlights: • Effect of quantity and fractionation of coated HA on sorption of sulfonamides by BC was studied. • Fractionation of coated HA is tailored by surface properties of BC. • Roles of HA in BC sorption depend on interaction between HA adlayer and sorbate. • Roles of HA in sulfonamide sorption by BC also depend on HA aqueous concentration. - The quantity and fractionation of adsorbed HA play a major role in sulfonamide sorption by biochars

  1. Sorption of malachite green (MG) by cassava stem biochar (CSB ...

    African Journals Online (AJOL)

    Cassava stem biochar (CSB) was produced by pyrolyzing CS at 500°C for 2 hours at nitrogen environment. Proximate and ultimate analyses were conducted on CS and CSB. Batch sorption experiment on synthetic MG wastewater was optimized for the sorbent dosage, MG solution pH and contact time. Sorption data was ...

  2. Competitive sorption of heavy metals by water hyacinth roots.

    Science.gov (United States)

    Zheng, Jia-Chuan; Liu, Hou-Qi; Feng, Hui-Min; Li, Wen-Wei; Lam, Michael Hon-Wah; Lam, Paul Kwan-Sing; Yu, Han-Qing

    2016-12-01

    Heavy metal pollution is a global issue severely constraining aquaculture practices, not only deteriorating the aquatic environment but also threatening the aquaculture production. One promising solution is adopting aquaponics systems where a synergy can be established between aquaculture and aquatic plants for metal sorption, but the interactions of multiple metals in such aquatic plants are poorly understood. In this study, we investigated the absorption behaviors of Cu(II) and Cd(II) in water by water hyacinth roots in both single- and binary-metal systems. Cu(II) and Cd(II) were individually removed by water hyacinth roots at high efficiency, accompanied with release of protons and cations such as Ca 2+ and Mg 2+ . However, in a binary-metal arrangement, the Cd(II) sorption was significantly inhibited by Cu(II), and the higher sorption affinity of Cu(II) accounted for its competitive sorption advantage. Ionic exchange was identified as a predominant mechanism of the metal sorption by water hyacinth roots, and the amine and oxygen-containing groups are the main binding sites accounting for metal sorption via chelation or coordination. This study highlights the interactive impacts of different metals during their sorption by water hyacinth roots and elucidates the underlying mechanism of metal competitive sorption, which may provide useful implications for optimization of phytoremediation system and development of more sustainable aquaculture industry. Copyright © 2016 Elsevier Ltd. All rights reserved.

  3. Analysis of ideal sorption compressor cycles operating with gas mixtures

    NARCIS (Netherlands)

    Tzabar, N.; ter Brake, H.J.M.

    2018-01-01

    Sorption-based compressors are thermally driven and because of the absence of moving parts they are vibration free, and have the potential for long life. Sorption-based compressors have been reported to operate Joule–Thomson (JT) cryogenic coolers with pure working fluids. However, using mixed

  4. Picloram and Aminopyralid Sorption to Soil and Clay Minerals

    Science.gov (United States)

    Aminopyralid sorption data are lacking, and these data are needed to predict off-target transport and plant available herbicide in soil solution. The objective of this research was to determine the sorption of picloram and aminopyralid to five soils and three clay minerals and determine if the pote...

  5. Hysteresis and Temperature Dependency of Moisture Sorption – New Measurements

    DEFF Research Database (Denmark)

    Rode, Carsten; Hansen, Kurt Kielsgaard

    2011-01-01

    measurements of hysteresis and temperature dependency of the moisture sorption characteristics of three different porous building materials: aerated concrete, cement paste and spruce. Scanning curves are measured for all three materials where periods with adsorption and desorption interrupt each other...... intermittently. For one of the materials, aerated concrete, the sorption curves are determined at three different temperatures....

  6. Sorption of fluoroquinolones and sulfonamides in 13 Brazilian soils.

    Science.gov (United States)

    Leal, Rafael Marques Pereira; Alleoni, Luis Reynaldo Ferracciú; Tornisielo, Valdemar Luiz; Regitano, Jussara Borges

    2013-08-01

    Animal production is a leading economic activity in Brazil and antibiotics are widely used. However, the occurrence, behavior, and impacts of antibiotics in Brazilian soils are still poorly known. We evaluated the sorption behavior of four fluoroquinolones (norfloxacin, ciprofloxacin, danofloxacin, and enrofloxacin) and five sulfonamides (sulfadiazine, sulfachloropyridazine, sulfamethoxazole, sulfadimidine, and sulfathiazole) in 13 Brazilian soils with contrasting physical, chemical, and mineralogical properties. Fluoroquinolone sorption was very high (Kd≥544 L kg(-1)) whereas sulfonamide sorption ranged from low to high (Kd=0.7-70.1 L kg(-1)), consistent with previous reports in the literature. Soil texture and cation exchange capacity were the soil attributes that most affected sorption. Cation exchange was the most important sorption mechanism for the fluoroquinolones in highly weathered tropical soils, although cation bridging and ion pairing could not be ruled out. Hydrophobic partition played an important role in the sorption of the sulfonamides, but sorption was also affected by non-hydrophobic interactions with organic and/or mineral surfaces. Sorption for both compound classes tended to be higher in soils with high Al and Fe oxihydroxide contents, but they were not correlated with Kd values. No direct effect of soil pH was seen. The fluoroquinolones are not expected to leach even in worst-case scenarios (soils rich in sand and poor in organic carbon), whereas soil attributes dictate leaching potential for the sulfonamides. Copyright © 2013 Elsevier Ltd. All rights reserved.

  7. Regionalised tertiary psychiatric residential facilities.

    Science.gov (United States)

    Lesage, Alain; Groden, David; Goldner, Elliot M; Gelinas, Daniel; Arnold, Leslie M

    2008-01-01

    Psychiatric hospitals remain the main venue for long-term mental health care and, despite widespread closures and downsizing, no country that built asylums in the last century has done away with them entirely--with the recent exception of Italy. Differentiated community-based residential alternatives have been developed over the past decades, with staffing levels that range from full-time professional, to daytime only, to part-time/on-call. This paper reviews the characteristics of community-based psychiatric residential care facilities as an alternative to long-term care in psychiatric hospitals. It describes five factors decision makers should consider: 1. number of residential places needed; 2. staffing levels; 3. physical setting; 4. programming; and 5. governance and financing. In Italy, facilities with full-time professional staff have been developed since the mid-1990s to accommodate the last cohorts of patients discharged from psychiatric hospitals. In the United Kingdom, experiments with hostel wards since the 1980s have shown that home-like, small-scale facilities with intensive treatment and rehabilitation programming can be effective for the most difficult-to-place patients. More recently in Australia, Community Care Units (CCUs) have been applying this concept. In the Canadian province of British Columbia (BC), Tertiary Psychiatric Residential Facilities (TPRFs) have been developed as part of an effort to regionalise health and social services and downsize and ultimately close its only psychiatric hospital. This type of service must be further developed in addition to the need for forensic, acute-care and intermediate-level beds, as well as for community-based care such as assertive community treatment and intensive case management. All these types of services, together with long-term community-based residential care, constitute the elements of a balanced mental health care system. As part of a region's balanced mental health care plan, these Tertiary

  8. Sorption of Np (Ⅴ) on Beishan granite fracture filling materials

    International Nuclear Information System (INIS)

    Jiang Tao; Wang Bo; Bao Liangjin; Zhou Duo; Long Haoqi; Song Zhixin; Chen Xi

    2012-01-01

    The sorption behaviors of Np (Ⅴ) on the granite fracture filling materials were studied by batch experiments under anaerobic in Beishan groundwater. The impact of pH of groundwater, CO 3 2- , humic acid and different components of granite fracture filling materials on sorption of Np (Ⅴ) was investigated. The results show that the granite fracture filling materials have strong capacity of Np (Ⅴ) adsorption. The value of K d , for Np (Ⅴ) sorption on the granite fracture filling materials is 843 mL/g. With the increase of pH, the value of K d increases at first and then decreases. K d of Np sorption on granite fracture filling materials in the presence of CO 3 2- and humic acid decreases. The chlorite and feldspar are major contributors to the sorption of Np (Ⅴ) on Beishan granite fracture filling materials. (authors)

  9. Sorption of polycyclic aromatic hydrocarbons on particulate organic matters

    International Nuclear Information System (INIS)

    Guo Xueyan; Luo Lei; Ma Yibing; Zhang Shuzhen

    2010-01-01

    Particulate organic matter (POM) is a key organic matter fraction which can influence soil fertility. Its interactions with hydrophobic organic pollutants (HOCs) have not been characterized and the mechanisms of retention of HOCs by POM remain unclear. In the present study, sorption behaviors of polycyclic aromatic hydrocarbons (PAHs) naphthalene (NAP), phenanthrene (PHE), and pyrene (PYR) by POMs separated from different soils were examined and the POMs were characterized by elemental analysis, solid state 13 C NMR, and Fourier transform infrared spectroscopy (FT-IR). The results indicated that POMs were mainly composed of aliphatic components with high polarity. The different original POMs showed similar chemical composition and configuration. Sorption behaviors of PAHs indicated that there was no significant difference in sorption capacity among the POMs. Sorption of NAP and PHE by POMs displayed a nonlinear isotherm, while sorption of PYR yielded a linear isotherm. No significant hysteresis and ionic strength effect were observed for PAH desorption from the POMs.

  10. Sorption of perfluoroalkyl substances to two types of minerals.

    Science.gov (United States)

    Hellsing, Maja S; Josefsson, Sarah; Hughes, Arwel V; Ahrens, Lutz

    2016-09-01

    The sorption of perfluoroalkyl substances (PFASs) was investigated for two model soil mineral surfaces, alumina (Al2O3) and silica (SiO2), on molecular level using neutron scattering. The PFASs were selected (i.e. perfluorohexanoic acid (PFHxA), perfluorooctanoic acid (PFOA), perfluorononanoic acid (PFNA), and perfluorooctane sulfonic acid (PFOS)) to examine the role of hydrophobic chain length and hydrophilic functional group on their sorption behaviour. All four PFASs were found to sorb to alumina surface (positively charged) forming a hydrated layer consisting of 50% PFASs. The PFAS solubility limit, which decrease with chain length, was found to strongly influence the sorption behaviour. The sorbed PFAS layer could easily be removed by gentle rinsing with water, indicating release upon rainfall in the environment. No sorption was observed for PFOA and PFOS at silica surface (negatively charged), showing electrostatic interaction being the driving force in the sorption process. Copyright © 2016 Elsevier Ltd. All rights reserved.

  11. Sorption behaviour of cobalt-60 on Suez Canal bottom sediments

    International Nuclear Information System (INIS)

    Abdel Gawad, S.A.; El-Shinawy, R.M.K.; Abdel Malik, W.E.Y.

    1981-01-01

    Mineralogical, elemental analysis and sorption behaviour of the Suez Canal bottom sediments in the Port Said area were investigated. It was found that the bottom sediment consist mainly of quartz, feldspars and traces of calcite mineral. The cation-exchange capacity was found to increase as the particle size of the sediment decreased. Sorption of 60 Co by the bottom sediment increased with contact time up to 6 h. Variation of the solution pH from 4 to 9 showed limited increase in the sorption of 60 Co. As carrier concentrations increase from 10 -7 N to 10 -3 N, sorption of Co was found to increase linearly following Freundlich isotherm. The presence of Mg 2+ and Fe 3+ in solution depressed the sorption of 60 Co by the sediments. The desorption of 60 Co from bottom sediment with distilled and Suez Canal water was found to increase with contact time. (author)

  12. Sorption mechanisms of metals to graphene oxide

    International Nuclear Information System (INIS)

    Showalter, Allison R; Bunker, Bruce A; Duster, Thomas A; Szymanowski, Jennifer E S; Na, Chongzheng; Fein, Jeremy B

    2016-01-01

    Environmental toxic metal contamination remediation and prevention is an ongoing issue. Graphene oxide is highly sorptive for many heavy metals over a wide pH range under different ionic strength conditions. We present x-ray absorption fine structure (XAFS) spectroscopy results investigating the binding environment of Pb(II), Cd(II) and U(VI) ions onto multi-layered graphene oxide (MLGO). Analysis indicates that the dominant sorption mechanism of Pb to MLGO changes as a function of pH, with increasing inner sphere contribution as pH increases. In contrast, the sorption mechanism of Cd to MLGO remains constant under the studied pH range. This adsorption mechanism is an electrostatic attraction between the hydrated Cd +2 ion and the MLGO surface. The U(VI), present as the uranyl ion, changes only subtly as a function of pH and is bound to the surface via an inner sphere bond. Knowledge of the binding mechanism for each metal is necessary to help in optimizing environmental remediation or prevention in filtration systems. (paper)

  13. Mercury Sorption onto Malt Spent Rootlets

    Science.gov (United States)

    Manariotis, I. D.; Anagnostopoulos, V.; Karapanagioti, H. K.; Chrysikopoulos, C.

    2011-12-01

    Mercury is a metal of particular concern due to its toxicity even at relatively low concentrations. The maximum permissible level for mercury in drinking water set by the European Union is 0.001 mg/L. Mercury is released into the environment via four principal pathways: (1) natural processes; i.e. a volcanic eruption, (2) incidental to some other activity; i.e. coal burning power plants, (3) accidentally during the manufacture, breakage or disposal of products that have mercury put into them deliberately, and (4) direct use in industrial settings. The present study focuses on the removal of mercury (II) from aqueous solutions via sorption onto Malt Spent Rootlets (MSR). Batch experiments were conducted employing MSR with size ranging from 0.18 to 1 mm. The effects of pH, mercury concentration, contact time, and solid to liquid ratio on mercury sorption onto MSR were investigated. The highest mercury removal from the aqueous phase, of 41%, was observed at pH of 5.

  14. Tritium sorption by cement and subsequent release

    International Nuclear Information System (INIS)

    Ono, F.; Yamawaki, M.

    1995-01-01

    In a fusion reactor or tritium-handling facilities, contamination of concrete by tritium and subsequent release from it to the reator or experimental room is a matter of problem for safe control of tritium and management of operational environment. In order to evaluate this tritium behavior, interaction of tritiated water with concrete or cement should be clarified. In the present study, HTO sorption and subsequent release from cement were experimentally studied.(1)Sorption experiments were conducted using columns packed with cement particles of different sizes. From the analysis of the breakthrough curve, tritium diffusivity in macropores and microparticles were evaluated.(2)From the short-term tritium release experiments, effective desorption rate constants were evaluated and the effects of temperature and moisture were studied.(3)In the long-term tritium release experiments to 6000h, the tritium release mechanism was found to be composed of three kinds of water: initially from capillary water, and in the second stage from gel water and from the water in the cement crystal.(4)Tritium release behavior by heat treatment to 800 C was studied. A high temperature above 600 C was required for the tritium trapped in the crystal water to be released. (orig.)

  15. Sorption of uranium by cellulose derivatives

    International Nuclear Information System (INIS)

    Muroi, M.; Imai, S.; Hamaguchi, A.

    1985-01-01

    The sorption behaviour of uranium was investigated by batch and column methods using four cellulose derivatives, two having an amino group and two having an amino group plus a dithiocarboxylate group. All four derivatives showed maximum uranium sorption from pure water in the neutral region or from artificial sea water in the acidic region. In the batch method, quantitative removal of 100 μg of uranium from 50 ml of water at pH 5.0 was achieved by equilibration with 50 mg of any of the four sorbents. The percentage removal under these conditions decreased gradually with increasing concentration of uranium above 100 μg per 50 ml. A similar high percentage removal of uranium was achieved using artificial sea water. In the column method, quantitative removal of 5 μg of uranium from 1l of water at pH 6.7 was achieved with 200 mg of either of the two sorbents. Similar quantitative removal of uranium was achieved from 1l of artificial sea water at pH 5.4 with 500 mg of either of the two sorbents. (author)

  16. Uranium sorption on tezontle volcanic rock

    Energy Technology Data Exchange (ETDEWEB)

    Lopez M, B. E.; Duran B, J. M.; Iturbe G, J. L.; Olguin G, M. T., E-mail: beatriz.lopez@inin.gob.m [ININ, Departamento de Quimica, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2009-07-01

    It is described a study that demonstrates that hexavalent uranium ions were sorbed by the naturally occurring mineral using a batch technique. This mineral is found in abundant quantities in Mexico. Our study focused on the separation of U Vi from synthetic aqueous systems of both H{sub 2}O-UO{sub 2}(NO{sub 3}){sub 2}.6H{sub 2}O (acid) and H{sub 2}O-Na{sub 4}[UO{sub 2}(CO{sub 3}){sub 3}] (basic). The chemical speciation was performed by using high voltage electrophoresis, and the uranium content was determined by UV-Vis spectroscopy. The quantified U(Vi) sorption by tezontle from acidic and basic systems was 2.72 and 1.68 mumol/g, respectively, and the sorption behavior is discussed considering the surface charge of the tezontle at different ph values based on the point of zero charge characteristic of this material. (Author)

  17. Gas Sorption, Diffusion, and Permeation in Nafion

    KAUST Repository

    Mukaddam, Mohsin Ahmed

    2015-12-22

    The gas permeability of dry Nafion films was determined at 2 atm and 35 °C for He, H2, N2, O2, CO2, CH4, C2H6, and C3H8. In addition, gas sorption isotherms were determined by gravimetric and barometric techniques as a function of pressure up to 20 atm. Nafion exhibited linear sorption uptake for low-solubility gases, following Henry’s law, and convex behavior for highly sorbing condensable gases, indicating rubber-like behavior at 35 °C. XRD results demonstrated that Nafion contains bimodal amorphous chain domains with average d-spacing values of 2.3 and 5.3 Å. Only helium and hydrogen showed relatively high gas permeability of 37 and 7 barrers, respectively; all other gases exhibited low permeability that decreased significantly as penetrant size increased. Dry Nafion was characterized by extraordinarily high selectivities: He/H2 = 5.2, He/CH4 = 445, He/C2H6 = 1275, He/C3H8 = 7400, CO2/CH4 = 28, CO2/C2H6 = 79, CO2/C3H8 = 460, H2/CH4 = 84, H2/C2H6 = 241, and H2/C3H8 = 1400. These high selectivities could make Nafion a potential candidate membrane material for dry feeds for helium recovery and carbon dioxide separation from natural gas and removal of higher hydrocarbons from hydrogen-containing refinery gases.

  18. Status of sorption information retrieval system

    International Nuclear Information System (INIS)

    Hostetler, D.D.; Serne, R.J.; Brandstetter, A.

    1979-09-01

    A Sorption Information Retrieval System (SIRS) is being designed to provide an efficient, computerized, data base for information on radionuclide sorption in geologic media. The data bank will include Kd values for a large number of radionuclides occurring in radioactive wastes originating from the commercial nuclear power industry. Kd values determined to date span several groundwater compositions and a wide variety of rock types and minerals. The data system will not only include Kd values, but also background information on the experiments themselves. This will allow the potential user to retrieve not only the Kd values of interest but also sufficient information to evaluate the accuracy and usefulness of the data. During FY-1979, the logic structure of the system was designed, the software programmed, the data categories selected, and the data format specified. About 40% of the approximately 5000 Kd experiments performed by the Waste Isolation Safety Assessment Program (WISAP) and its subcontractors during FY-1977 and FY-1978 have been evaluated, coded and keypunched. Additional software improvements and system testing are needed before the system will be fully operational. A workshop requested by the NEA was held to discuss potential internatioal participation in the data system

  19. Residential care : Dutch and Italian residents of residential care facilities compared

    NARCIS (Netherlands)

    de Heer-Wunderink, Charlotte; Caro-Nienhuis, Annemarie D.; Sytema, Sjoerd; Wiersma, Durk

    2008-01-01

    Aims - Characteristics of patients living in residential care facilities and the availability of mental hospital- and residential beds in Italy and The Netherlands were compared to assess whether differences in the process of deinstitutionalisation have influenced the composition of their

  20. The relation between residential property and its surroundings and day- and night-time residential burglary

    NARCIS (Netherlands)

    Montoya, Lorena; Junger, Marianne; Ongena, Yfke

    This article examines how residential property and its surroundings influence day- and night-time residential burglary. Crime Prevention Through Environmental Design (CPTED) principles of territoriality, surveillance, access control, target hardening, image maintenance, and activity support underpin

  1. The Relation Between Residential Property and its Surroundings and Day- and Night-Time Residential Burglary

    NARCIS (Netherlands)

    Montoya, L.; Junger, Marianne; Ongena, Yfke

    This article examines how residential property and its surroundings influence day- and night-time residential burglary. Crime Prevention Through Environmental Design (CPTED) principles of territoriality, surveillance, access control, target hardening, image maintenance, and activity support underpin

  2. Sorption and diffusion of Cs and I in concrete

    International Nuclear Information System (INIS)

    Andersson, K.; Torstenfelt, B.; Allard, B.

    1983-01-01

    Concrete has been suggested as a possible encapsulation material for long-term storage of low and medium level radioactive waste. At an underground storage of concrete encapsulated waste, a slow release of radioactive elements into the groundwater by diffusion through the concrete must be considered in the safety analysis. The diffusion may be delayed by sorption reactions on the solid. A wide range of long-lived radionuclides may be present in the low and medium level radioactive waste. Here, the sorption and diffusion of iodide and cesium on slag cement paste and concrete has been studied. The influence of four different water phases (pore water, groundwater, Baltic Sea water and sea water) as well as the influence of some added species (carbonate, sulphate and magnesium) has been investigated. A significant sorption of iodide on cement paste in contact with pore water was observed, indicating that the diffusion may be expected to be retarded in this medium. For cesium the highest sorption was found for concrete and groundwater. This means that the sorption increases as the concrete is weathered. Low or insignificant sorption was found for the cement paste, indicating that the ballast is responsible for the Cs-sorption. Carbonatization enhances the Cs-sorption by about a factor of 3. The diffusivity of Cs in concrete and cement paste was determined to between 2x10 - 14 and 8x10 - 14 m 2 /s in pore water (where an insignificant sorption was observed). The choice of ballast as well as addition of suitable getters with high sorption of the long-lived radionuclides might decrease the mass transfer rate through the cement. (Authors)

  3. Effect of humic acid on sorption of technetium by alumina

    International Nuclear Information System (INIS)

    Kumar, S.; Rawat, N.; Kar, A.S.; Tomar, B.S.; Manchanda, V.K.

    2011-01-01

    Highlights: → Tc sorption on alumina has been studied under aerobic as well anaerobic condition over pH 3-10. → Effect of humic acid on sorption of Tc by alumina has been investigated. → Linear additive modeling and surface complexation modeling were carried out to delineate the role of humic acid in Tc(IV) sorption in ternary system of Tc(IV)-humic acid-alumina. → Sorption of humic acid onto alumina and strong complexation of Tc(IV) with humic acid were found to govern the sorption of Tc(IV) in the ternary system. - Abstract: Sorption of technetium by alumina has been studied in absence as well as in presence of humic acid using 95 Tc m as a tracer. Measurements were carried out at fixed ionic strength (0.1 M NaClO 4 ) under varying pH (3-10) as well as redox (aerobic and reducing anaerobic) conditions. Under aerobic conditions, negligible sorption of technetium was observed onto alumina both in absence and in presence of humic acid. However, under reducing conditions (simulated with [Sn(II)] = 10 -6 M), presence of humic acid enhanced the sorption of technetium in the low pH region significantly and decreased at higher pH with respect to that in absence of humic acid. Linear additive as well as surface complexation modeling of Tc(IV) sorption in presence of humic acid indicated the predominant role of sorbed humic acid in deciding technetium sorption onto alumina.

  4. Sorption of cesium in young till soils

    Energy Technology Data Exchange (ETDEWEB)

    Lusa, Merja; Lempinen, Janne; Ahola, Hanna; Soederlund, Mervi; Lehto, Jukka [Helsinki Univ. (Finland). Laboratory of Radiochemistry; Lahdenperae, Anne-Maj [Saanio and Riekkola Oy, Consulting Engineers, Helsinki (Finland); Ikonen, Ari T.K. [Posiva Oy, Eurajoki (Finland)

    2014-10-01

    Soil samples from three forest soil pits were examined down to a depth of approximately three metres using 1 M ammonium acetate extraction and microwave-assisted extraction with concentrated nitric acid (HNO{sub 3}), to study the binding of cesium (Cs) at Olkiluoto Island, southern Finland. Ammonium acetate was used to extract the readily exchangeable Cs fractions roughly representing the Cs fraction in soil which is available for plants. Microwave-assisted HNO{sub 3} extraction dissolves various minerals, e.g. carbonates, most sulphides, arsenides, selenides, phosphates, molybdates, sulphates, iron (Fe) and manganese (Mn) oxides and some silicates (olivine, biotite, zeolite), and reflects the total Cs concentrations. Cs was mostly found in the strongly bound fraction obtained through HNO{sub 3} extraction. The average Cs concentrations found in this fraction were 3.53 ± 0.30 mg/kg (d.w.), 3.06 ± 1.86 mg/kg (d.w.) and 1.83 ± 0.42 mg/kg (d.w.) in the three soil pits, respectively. The average exchangeable Cs found in the ammonium acetate extraction in all three sampling pits was 0.015 ± 0.008 mg/kg (d.w.). In addition, Cs concentrations in the soil solution were determined and in situ distribution coefficients (K{sub d}) for Cs were calculated. Furthermore, the in situ K{sub d} data was compared with the Cs K{sub d} data obtained using the model batch experiments. The in situ K{sub d} values were observed to fairly well follow the trend of batch sorption data with respect to soil depth, but on average the batch distribution coefficients were almost an order of magnitude higher than the in situ K{sub d} data. In situ Cs sorption data could be satisfactory fitted with the Langmuir sorption isotherm, but the Freundlich isotherm failed to fit the data. Finally, distribution coefficients were calculated by an ion exchange approach using soil solution data, the cation exchange capacity (CEC) as well as Cs to sodium (Na) and Cs to potassium (K) ion exchange selectivity

  5. A suggested approach toward measuring sorption and applying sorption data to repository performance assessment

    International Nuclear Information System (INIS)

    Rundberg, R.S.

    1992-01-01

    The prediction of radionuclide migration for the purpose of assessing the safety of a nuclear waste repository will be based on a collective knowledge of hydrologic and geochemical properties of the surrounding rock and groundwater. This knowledge along with assumption about the interactions of radionuclides with groundwater and minerals form the scientific basis for a model capable of accurately predicting the repository's performance. Because the interaction of radionuclides in geochemical systems is known to be complicated, several fundamental and empirical approaches to measuring the interaction between radionuclides and the geologic barrier have been developed. The approaches applied to the measurement of sorption involve the use of pure minerals, intact, or crushed rock in dynamic and static experiments. Each approach has its advantages and disadvantages. There is no single best method for providing sorption data for performance assessment models which can be applied without invoking information derived from multiple experiments. 53 refs., 12 figs

  6. Study of sorption processes of copper on synthetic hydroxyapatite

    International Nuclear Information System (INIS)

    Rosskopfova, O.; Galambos, M.; Ometakova, J.; Rajec, P.; Caplovicova, M.

    2012-01-01

    The sorption of copper on synthetic hydroxyapatite was investigated using a batch method and radiotracer technique. The hydroxyapatite sample prepared by a wet precipitation process was of high crystallinity with Ca/P ratio of 1.688. The sorption of copper on hydroxyapatite was pH independent ranging from 4 to 6 as a result of buffering properties of hydroxyapatite. The adsorption of copper was rapid and the percentage of Cu sorption was >98% during the first 15-30 min of the contact time. The experimental data for sorption of copper have been interpreted in the term of Langmuir isotherm. The sorption of Cu 2+ ions was performed by ion-exchange with Ca 2+ cations on the crystal surface of hydroxyapatite under experimental conditions. The competition effect of Zn 2+ , Fe 2+ and Pb 2+ towards Cu 2+ sorption was stronger than that of Co 2+ , Ni 2+ and Ca 2+ ions. The ability of the bivalent cations to depress the sorption of copper on hydroxyapatite was in the following order Pb 2+ > Fe 2+ > Zn 2+ > Co 2+ ∼ Ni 2+ . (author)

  7. Sorption of U(VI) species on hydroxyapatite

    International Nuclear Information System (INIS)

    Thakur, P.; Moore, R.C.; Choppin, G.R.

    2005-01-01

    The sorption of uranyl (UO 2 2+ ) cations to hydroxyapatite was studied as a function of the amount of sorbent, ionic strength, U(VI) concentration, pH and temperature. The rate of uranyl sorption on hydroxyapatite decreased with increased uranyl concentrations. The amount sorbed decreased with increased ionic strength and increased with pH to a maximum at 7-8. The sorption data for UO 2 2+ were fitted well by the Freundlich and Dubinin-Radushkevich (D-R) isotherms. The anions Cl - , NO 3 - , SO 4 2- and CH 3 COO - decreased the sorption of uranium on hydroxyapatite while S 2 O 3 2- slightly increased it. The sorbed uranium was desorbed by 0.10 M and 1.00 M solutions of HCl and HNO 3 . The thermodynamic parameters for the sorption of UO 2 2+ were measured at temperatures of 298, 313, 323 and 333 K. The temperature dependence confirmed an endothermic heat of sorption. The activation energy for the sorption process was calculated to be +2.75±0.02 kJ/mol. (orig.)

  8. Artificial Weathering of Biotite and Uranium Sorption Characteristics

    International Nuclear Information System (INIS)

    Lee, Seung Yeop; Baik, Min Hoon; Lee, Jae Kwang

    2009-01-01

    An experiment for uranium sorption onto fresh and weathered biotites was performed. After centrifugation, concentrations of uranium in the supernatants were analyzed using ICP-MS, and biotite samples were investigated using XRD and SEM. With powdered biotites (<3 mm in size), we have conducted uranium sorption experiments about fresh and weathered biotites to obtain uranium sorption amounts in various pH conditions. The uranium sorption was not high at a low pH (e.g., pH 3), but increased with increasing pH. There were lower uranium sorption by the weathered biotites than by the fresh ones, and the difference was much larger at higher pH (e.g., pH 11). The lower sorption values of uranium by the weathered biotites may be caused by a change of mineral surfaces and a chemical behavior of surrounding dissolved elements. It seems that the uranium-mineral interaction has been diminished, especially, in the weathered biotite by a destruction and dissolution of preferential sorption sites on the mineral surfaces and by the colloidal formation from dissolved elements.

  9. Mechanisms of metal sorption by biochars: Biochar characteristics and modifications.

    Science.gov (United States)

    Li, Hongbo; Dong, Xiaoling; da Silva, Evandro B; de Oliveira, Letuzia M; Chen, Yanshan; Ma, Lena Q

    2017-07-01

    Biochar produced by thermal decomposition of biomass under oxygen-limited conditions has received increasing attention as a cost-effective sorbent to treat metal-contaminated waters. However, there is a lack of information on the roles of different sorption mechanisms for different metals and recent development of biochar modification to enhance metal sorption capacity, which is critical for biochar field application. This review summarizes the characteristics of biochar (e.g., surface area, porosity, pH, surface charge, functional groups, and mineral components) and main mechanisms governing sorption of As, Cr, Cd, Pb, and Hg by biochar. Biochar properties vary considerably with feedstock material and pyrolysis temperature, with high temperature producing biochars with higher surface area, porosity, pH, and mineral contents, but less functional groups. Different mechanisms dominate sorption of As (complexation and electrostatic interactions), Cr (electrostatic interactions, reduction, and complexation), Cd and Pb (complexation, cation exchange, and precipitation), and Hg (complexation and reduction). Besides sorption mechanisms, recent advance in modifying biochar by loading with minerals, reductants, organic functional groups, and nanoparticles, and activation with alkali solution to enhance metal sorption capacity is discussed. Future research needs for field application of biochar include competitive sorption mechanisms of co-existing metals, biochar reuse, and cost reduction of biochar production. Published by Elsevier Ltd.

  10. Role of interlayer hydration in lincomycin sorption by smectite clays.

    Science.gov (United States)

    Wang, Cuiping; Ding, Yunjie; Teppen, Brian J; Boyd, Stephen A; Song, Cunyi; Li, Hui

    2009-08-15

    Lincomycin, an antibiotic widely administered as a veterinary medicine, is frequently detected in water. Little is known about the soil-water distribution of lincomycin despite the fact that this is a major determinant of its environmental fate and potential for exposure. Cation exchange was found to be the primary mechanism responsible for lincomycin sorption by soil clay minerals. This was evidenced by pH-dependent sorption, and competition with inorganic cations for sorptive sites. As solution pH increased, lincomycin sorption decreased. The extent of reduction was consistent with the decrease in cationic lincomycin species in solution. The presence of Ca2+ in solution diminished lincomycin sorption. Clay interlayer hydration status strongly influenced lincomycin adsorption. Smectites with the charge deficit from isomorphic substitution in tetrahedral layers (i.e., saponite) manifest a less hydrated interlayer environment resulting in greater sorption than that by octahedrally substituted clays (i.e., montmorillonite). Strongly hydrated exchangeable cations resulted in a more hydrated clay interlayer environment reducing sorption in the order of Ca- smectite. X-ray diffraction revealed that lincomycin was intercalated in smectite clay interlayers. Sorption capacity was limited by clay surface area rather than by cation exchange capacity. Smectite interlayer hydration was shown to be a major, yet previously unrecognized, factor influencing the cation exchange process of lincomycin on aluminosilicate mineral surfaces.

  11. Web-based sorption database (KAERI-SDB)

    International Nuclear Information System (INIS)

    Lee, Jae Kwang; Baik, Min Hoon

    2010-10-01

    Radionuclide sorption data is necessary for the safety assessment of radioactive waste disposal. However the accessibility to the nuclide sorption database is limited. The web-based sorption database (KAERI-SDB) was developed to provide sorption data in a convenient way. The development of the KAERI-SDB was achieved by improving the performance of pre-existing sorption DB programme (SDB-21C) and incorporating the user requirement. The KAERI-SDB was designed that users can access it by using a web browser. Main functions of the KAERI-SDB include (1) log-in/join, (2) search and store of sorption data and (3) scatter plot chart and index chart. It is expected that the KAERI-SDB is widely applied to the safety assessment of radioactive waste disposal by enhancing the accessibility to experts and practitioner related the nuclear industry and governmental administration. It is also expected that reliabilities for the radioactive waste disposal increased by opening the web-based sorption DB to public

  12. A mechanistic approach to the generation of sorption databases

    International Nuclear Information System (INIS)

    Bradbury, M.H.; Baeyens, B.

    1992-01-01

    Sorption of radionuclides in the near and far fields of an underground nuclear waste repository is one of the most important processes retarding their release to the environment. In the vast majority of cases sorption data have been presented in terms of empirical parameters such as distribution coefficients and isotherm equations. A consequence of this empirical methodology is that the sorption data are only strictly valid under the experimental conditions at which they were measured. Implicit in this approach is the need to generate large amounts of data and fitting parameters necessary for an empirical description of sorption under all realistically conceivable conditions which may arise in space and time along the migration pathway to Man. An alternative approach to the problem is to try to understand, and develop model descriptions of, underlying retention mechanisms and to identify those systems parameters which essentially determine the extent of sorption. The aim of this work is to see to what extent currently existing mechanistic models, together with their associated data, can be applied to predict sorption data from laboratory experiments on natural systems. This paper describes the current status of this work which is very much in an early stage of development. An example is given whereby model predictions are compared with laboratory results for the sorption of Np at trace concentrations under oxidizing conditions on a series of minerals relevant to granite formations. 31 refs., 11 figs., 5 tabs

  13. Water vapor sorption thermodynamics of the Nafion ionomer membrane.

    Science.gov (United States)

    Wadsö, Lars; Jannasch, Patric

    2013-07-18

    The water interactions of polymer electrolyte membranes are of significant interest when these materials are used in, for example, fuel cells. We have therefore studied the sorption thermodynamics of Nafion with a sorption calorimeter that simultaneously measures the sorption isotherm and the mixing (sorption) enthalpy. This unique method is suitable for investigating the sorption thermodynamics of ionic polymers. The measurements were made at 25 °C on a series of samples dried at different temperatures from 25 to 120 °C. The sorption isotherms indicate that the samples dried at 120 °C lost about 0.8 more water molecules per sulfonic group during the drying than did the samples dried at 25 °C, and this result was verified gravimetrically. The mixing enthalpies showed several peaks or plateaus for the samples dried at 60-120 °C. This behavior was seen up to about 2 water molecules per sulfonic group. As these peaks were not directly related to any feature in the sorption isotherm, they probably have their origin in a secondary process, such as a reorganization of the polymer.

  14. Sorption of strontium by magnetically modified yeast cells

    International Nuclear Information System (INIS)

    Hu Yantao; Ji Yanqin; Tian Qing; Shao Xianzhang; Shi Jianhe; Ivo Safarik; Zhang Shengdong; Li Jinying

    2008-01-01

    Magnetically modified fodder's yeast (Kluyveromyces fragilis) cells using water based magnetic fluid, were characterized by scanning electron microscopy (SEM) and Vibrating Sample Magnetometer (VSM). The sorption-desorption properties of Sr 2+ by these yeast cells from nitrate salt of Sr 2+ were studied. The results demonstrated that the Sr 2+ sorption volume by these cells enhanced with increasing pH and reached a plateau between pH 4.0 and 7.0. A minor effect by temperature was observed. The sorption volumes are 19.5 mg/g and 53.5 mg/g from 10 ppm and 40 ppm Sr 2+ solution respectively within 20 min. The sorption of Sr 2+ in these cells can be desorbed under 0.1 mol/L HNO 3 solution. The maximum Sr 2+ sorption volume is 96.7 mg/g at 20℃. The sorption characteristic fits Langmuir model well with 140.8 mg/g calculated maximum sorption volume by these yeast cells. (authors)

  15. Plutonium sorption to nanocast mesoporous carbon

    Energy Technology Data Exchange (ETDEWEB)

    Parsons-Moss, Tashi; Wang, Deborah; Jones, Stephen; Olive, Daniel; Nitsche, Heino [California Univ., Berkeley, CA (United States). Dept. of Chemistry; Lawrence Berkeley National Laboratory, Berkeley, CA (United States). Nuclear Science Div.; Tueysuez, Harun [Lawrence Berkeley National Laboratory, Berkeley, CA (United States). Nuclear Science Div.; Max-Planck-Institut fuer Kohlenforschung, Muelheim an der Ruhr (Germany)

    2014-09-01

    Nanocast ordered mesoporous carbons are attractive as sorbents because of their extremely high surface areas and large pore volumes. This paper compares Pu uptake, added as Pu(VI), to both untreated and chemically oxidized CMK-(carbon molecular sieves from KAIST) type mesoporous carbon with that to a commercial amorphous activated carbon. The CMK was synthesized via nanocasting by using cubic ordered mesoporous silica KIT-6 as a hard template, and characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), and nitrogen adsorption. A portion of the CMK was oxidized by treatment with nitric acid, and will be called OX CMK. The three carbon powders have similar particle morphology, and high BET surface areas. The activated carbon is disordered, while the CMK materials show large domains of ordered cubic mesostructure. The CMK material seems to have more oxygen-containing functional groups than the activated carbon, and the oxidation of the CMK increased the density of these groups, especially - COOH, thus lowering the point of zero charge (PZC) of the material. Batch studies of all 3 materials with plutonium solutions, in a 0.1 M NaClO{sub 4} matrix were performed to investigate pH dependence, sorption kinetics, Pu uptake capacities, competition with ethylenediaminetetraacetic acid (EDTA) in solution, and Pu desorption. Both CMK materials demonstrated high Pu sorption from solutions of pH 3 or greater, and the oxidized CMK also showed high sorption from pH 2 solutions. The activated carbon bound less Pu, and at a much slower rate than CMK. All other batch experiments were carried out in pH 4 solutions. The Pu uptake from low-concentration solutions was faster for the oxidized CMK than for untreated CMK, but in more concentrated samples (∝ 250 μM Pu), the Pu uptake kinetics and apparent capacity were the same for oxidized and untreated CMK. The 23-h Pu uptake capacity of the CMK

  16. Sorption compressor/mechanical expander hybrid refrigeration

    Science.gov (United States)

    Jones, J. A.; Britcliffe, M.

    1987-01-01

    Experience with Deep Space Network (DSN) ground-based cryogenic refrigerators has proved the reliability of the basic two-stage Gifford-McMahon helium refrigerator. A very long life cryogenic refrigeration system appears possible by combining this expansion system or a turbo expansion system with a hydride sorption compressor in place of the usual motor driven piston compressor. To test the feasibility of this system, a commercial Gifford-McMahon refrigerator was tested using hydrogen gas as the working fluid. Although no attempt was made to optimize the system for hydrogen operation, the refrigerator developed 1.3 W at 30 K and 6.6 W at 60 K. The results of the test and of theoretical performances of the hybrid compressor coupled to these expansion systems are presented.

  17. Retention/sorption and geochemical modelling

    Energy Technology Data Exchange (ETDEWEB)

    Arcos, D.; Grandia, F.; Domenech, C. [Enviros Spain, S.L., Barcelona (Spain); SCK-CEN, Mol (Belgium); Sellin, P. [SKB - Swedish Nuclear Fuel and Waste Management, SE, Stockholm (Sweden); Hunter, F.M.I.; Bate, F.; Heath, T.G.; Hoch, A. [Serco Assurance, Oxfordshire (United Kingdom); Werme, L.O. [SKB - Svensk Karnbranslehantering AB, Stockholm (Sweden); Bruggeman, C.; Maes, I.A.; Breynaert, E.; Vancluysen, J. [Leuven Katholieke Univ., Lab. for Colloid Chemistry (Belgium); Montavon, G.; Guo, Z. [Ecole des Mines, 44 - Nantes (France); Riebe, B.; Bunnenberg, C.; Meleshyn, A. [Leibniz Univ. Hannover, Zentrum fur Strahlenschutz und Radiookologie, Hannover (Germany); Dultz, S. [Leibniz Univ. Hannover, Institut fur Bodenkunde, Hannover (Germany)

    2007-07-01

    This session gathers 4 articles dealing with: the long-term geochemical evolution of the near field of a KBS-3 HLNW repository: insights from reactive transport modelling (D. Arcos, F. Grandia, C. Domenech, P. Sellin); the investigation of iron transport into bentonite from anaerobically corroding steel: a geochemical modelling study (F.M.I. Hunter, F. Bate, T.G. Heath, A. Hoch, L.O. Werme); SeO{sub 3}{sup 2-} adsorption on conditioned Na-illite: XAS spectroscopy, kinetics, surface complexation model and influence of compaction (C. Bruggeman, A. Maes, G. Montavon, E. Breynaert, Z. Guo, J. Vancluysen); the influence of temperature and gamma-irradiation on the anion sorption capacity of modified bentonites (B. Riebe, C. Bunnenberg, A. Meleshyn, S. Dultz)

  18. Sorption of radionuclides on a soil

    International Nuclear Information System (INIS)

    Fukui, Masami

    1979-01-01

    Disposal of radioactive wastes into the ground has been discussed, and this paper emphasized significance of the investigation for underground water flow and for the prediction of radionuclides through a stratified aquifer using column experiments to evaluate the internal radiation dose. Distributions and redistributions of radionuclides in a sandy layer were observed to identify the sorption model which predicts the behavior, and the underground water flow in the Plio-Pleistocene Osaka Group was investigated as an example, by mean of the measurement of 222 Rn concentration, the pumping technique and the tracer technique using the activation analysis. Then, the estimation of radioactive concentration in the underground water was worked out for the boundary condition of steady state inflow of liquid wastes and of which the 90 Sr are leached from the solidified body, moreover, the equation which easily evaluates the suitability of the disposal site was proposed. These approach may be useful for the actual site selection of radioactive wastes disposal. (author)

  19. Study of the radium sorption/desorption on goethite

    International Nuclear Information System (INIS)

    Bassot, S.; Stammose, D.; Mallet, C.; Lefebvre, C.; Ferreux, J.-M.

    2000-01-01

    The oxi-hydroxides, present at trace level in uranium mill tailings, are responsible of about 70% of the 226 radium sorption, half being fixed on crystallized forms. This radionuclide (half time=1622y), present at high level (50 to 100kBq.kg -1 ), can be released in groundwater, involving a possible contamination of the food chain (actual concentration limit=0.37Bq.1 -1 ). So, it is very important to point out the mechanisms of the radium sorption/desorption on crystallized oxi-hydroxides as a function of chemical conditions of the system. The radium sorption on synthetic goethite α-FeOOH has been studied as a function of contact time, initial radium activity, pH, sodium and calcium concentrations. The results show that, after one hour of contact time (necessary to reach equilibrium), the radium sorption increases widely in a pH range 6-7. The increase of Na + concentration is without influence on the radium sorption, indicating the low interactions between sodium and surface sites. At the opposite, the presence of calcium in solution decreases widely the radium sorption, that indicates a competition between calcium and radium for the same kind of sorption sites of the oxi-hydroxide surface. The percentage of radium desorbed increases widely with time, from 1 to 120h and becomes constant at a time higher than 120h. This long equilibrium time for desorption in comparison with sorption one can be explain by a local evolution of the sorption sites of the solid, which become less accessible for the solution in contact. (author)

  20. Sorption of Metal Ions on Clay Minerals.

    Science.gov (United States)

    Schlegel; Manceau; Chateigner; Charlet

    1999-07-01

    The local structural environment of Co sorbed on hectorite (a magnesian smectite) has been investigated by polarized EXAFS (P-EXAFS) spectroscopy on a self-supporting film of Co-sorbed hectorite. This sorption sample was prepared by contacting Co and hectorite at pH 6.5 and at high ionic strength (0.3 M NaNO3) to favor pH-dependent sorption reaction over cation exchange. A self-supporting film was elaborated after 120 h of reacting time, when apparent quasi-equilibrium conditions were attained. The half-width at half maximum of the orientation distribution of c* axis of individual clay platelets off the film normal was determined by quantitative texture analysis, and found to be equal to 18.9 degrees. Co K-edge P-EXAFS spectra were recorded at angles between the incident beam and the film normal equal to 0 degrees, 35 degrees, 50 degrees, and 60 degrees; the 90 degrees spectrum was obtained by extrapolation. Spectral analysis led to the identification of the two nearest cationic subshells containing 1.6 +/- 0.4 Mg at 3.03 Å and 2.2 +/- 0.5 Si at 3.27 Å. These distances are respectively characteristic of edge-sharing linkages between Mg and Co octahedra and of corner-sharing linkages between Co octahedra and Si tetrahedra, as in clay structures. The angular dependence of the Co-Mg and Co-Si contributions indicates that Co-Mg pairs are oriented parallel to the film plane, whereas Co-Si pairs are not. These results are interpreted by the formation of Co inner-sphere mononuclear surface complexes located at the edges of hectorite platelets, in the continuity of the (Mg, Li) octahedral sheet. Copyright 1999 Academic Press.

  1. Residential Electricity Consumption in Poland

    Directory of Open Access Journals (Sweden)

    Edyta Ropuszyńska-Surma

    2016-01-01

    Full Text Available Key factors influencing electricity consumption in the residential sector in Poland have been identified. A fixed-effects model was used, which includes time effects, and a set of covariates, based on the model developed by Houthakker et al. This model estimates electricity demand by using lagged values of the dependent variable along with current and lagged values of electricity prices, and other variables that affect electricity demand such as: population, economic growth, income per capita, price of related goods, etc. The model has been identified according to the research results of the authors and those obtained by Bentzen and Engsted. The set of covariates was extended to the lagged electricity price given by a tariff (taken from two years previous to the time of interest and heating degree days index, a very important factor in European Union countries, where the climate is temperate. The authors propose four models of residential electricity demand, for which a confidence interval of 95% has been assumed. Estimation was based on Polish quarterly data for the years 2003-2013. (original abstract

  2. Residential ventilation standards scoping study

    Energy Technology Data Exchange (ETDEWEB)

    McKone, Thomas E.; Sherman, Max H.

    2003-10-01

    The goals of this scoping study are to identify research needed to develop improved ventilation standards for California's Title 24 Building Energy Efficiency Standards. The 2008 Title 24 Standards are the primary target for the outcome of this research, but this scoping study is not limited to that timeframe. We prepared this scoping study to provide the California Energy Commission with broad and flexible options for developing a research plan to advance the standards. This document presents the findings of a scoping study commissioned by the Public Interest Energy Research (PIER) program of the California Energy Commission to determine what research is necessary to develop new residential ventilation requirements for California. This study is one of three companion efforts needed to complete the job of determining the ventilation needs of California residences, determining the bases for setting residential ventilation requirements, and determining appropriate ventilation technologies to meet these needs and requirements in an energy efficient manner. Rather than providing research results, this scoping study identifies important research questions along with the level of effort necessary to address these questions and the costs, risks, and benefits of pursuing alternative research questions. In approaching these questions and corresponding levels of effort, feasibility and timing were important considerations. The Commission has specified Summer 2005 as the latest date for completing this research in time to update the 2008 version of California's Energy Code (Title 24).

  3. SORPTION OF Cu2+ IONS ONTO DIATOMITE CONSTITUENTS

    Directory of Open Access Journals (Sweden)

    Vasile Rusu

    2009-06-01

    Full Text Available Studies of the sorption capacity towards Cu2+ ions of diatomite from the Ghidirim location of RM, as well as of the extracted clay phase are presented. Separated clay fraction from diatomic material is clean enough, and especially is rich in montmorillonite. Maximum sorption capacity for studied clay fraction is achieved by rising the temperature of calcination treatment up to 200oC. At higher temperatures the lattice of montmorillonite is contracted and its sorption capacity towards Cu2+ ions decreases strongly.

  4. Modeling and Prediction of Soil Water Vapor Sorption Isotherms

    DEFF Research Database (Denmark)

    Arthur, Emmanuel; Tuller, Markus; Moldrup, Per

    2015-01-01

    Soil water vapor sorption isotherms describe the relationship between water activity (aw) and moisture content along adsorption and desorption paths. The isotherms are important for modeling numerous soil processes and are also used to estimate several soil (specific surface area, clay content.......93) for a wide range of soils; and (ii) develop and test regression models for estimating the isotherms from clay content. Preliminary results show reasonable fits of the majority of the investigated empirical and theoretical models to the measured data although some models were not capable to fit both sorption...... directions accurately. Evaluation of the developed prediction equations showed good estimation of the sorption/desorption isotherms for tested soils....

  5. Sorption and desorption of diuron in Oxisol under biochar application

    OpenAIRE

    Petter, Fabiano André; Ferreira, Tamara Santos; Sinhorin, Adilson Paulo; Lima, Larissa Borges de; Morais, Leidimar Alves de; Pacheco, Leandro Pereira

    2016-01-01

    ABSTRACT The objective of this study was to verify the kinetics of sorption and desorption of diuron in an Oxisol under application of biochar. The samples were collected in a field experiment conducted in randomized design blocks consisted of 2 base fertilization levels (0 and 400 kg∙ha−1 NPK 00-20-20 fertilizer formula) and 3 doses of biochar (0, 8 and 16 Mg∙ha−1). In the evaluation of sorption and desorption, Batch Equilibrium method was used. The kinetics of sorption and desorption of diu...

  6. Interim report on modeling sorption with EQ3/6

    International Nuclear Information System (INIS)

    Viani, B.

    1988-01-01

    Reversible, equilibrium models of sorption to be incorporated into the EQ3/6 geochemical modeling package are summarized. Empirical sorption models as formulated in linear, Langmuir, and Freundlich isotherms will be developed as options to EQ3/6. This work will be done at LLNL. Options for modeling sorption using surface- complexation constructs (diffuse, constant capacitance, and triple-layer models) will also be developed. Development of the surface-complexation options will require part of the work be done under contract. 27 refs., 1 fig

  7. Implementation of sorption hysteresis in multi-Fickian moisture transport

    DEFF Research Database (Denmark)

    Frandsen, Henrik Lund; Svensson, Staffan

    2007-01-01

    In the cellular structure of wood, bound-water diffusion and water-vapor diffusion interact via sorption in a complex moisture-transportation system. At low relative humidities, moisture transport may be modeled by a Fickian diffusion equation with a good approximation. At higher relative......-35% in moisture content. Hence, for a precise moisture content computation, sorption hysteresis must be taken into account. The present paper explains the relation between sorption hysteresis and multi-Fickian moisture transport, and clarifies how models for the two phenomena are coupled. To illustrate...

  8. Sorption of molybdenum by cellulose polyphosphate from acid solutions

    International Nuclear Information System (INIS)

    Luneva, N.K.; Oputina, A.G.; Ermolenko, I.N.

    1985-01-01

    The sorption of molybdenum on cellulose polyphosphate from acid solutions of ammonium molybdate depending on the phosphorus content in samples, concentration and pH of the solution, sorption time is studied. It is shown that a maximum molybdenum content on the cellulose samples with different phosphorus content is pointed out at an ammonium molybdate concentration 0.02 M. Saturation of the sorption curve is attained at molar ratio of adsrbed molybdenum to phosphorus 1:4. In case of small fillings the compound with molybdenum to phosphorus ratio 1:10 is formed

  9. Sorption of Co2+ on modified inorganic materials

    International Nuclear Information System (INIS)

    Hanzel, R.; Rajec, P.

    1999-01-01

    The aim of this study was preparation and characterization of sorbents on the base a silica-gel matrix with immobilized functional group (imidazole or crown-ether). Sorption of cobalt from aqueous solutions on prepared sorbents in static conditions (by 'batch' method) in the dependence of concentration, pH value,, as well as kinetics of sorption were studied. The influence of heavy or toxic metals [Hg(II), Cd(II), Mn(II), Zn(II), Cu(II), Fe(III), Cr(III), Al(III), Na and K] on sorption of cobalt was studied, too

  10. Arsenic Sorption on Mechanically Activated Magnetite and Olivine

    Directory of Open Access Journals (Sweden)

    Zdenka Bujňáková

    2012-12-01

    Full Text Available Arsenic sorption on mechanically activated minerals such as magnetite Fe3O4 (Kiruna, Sweden and olivine (Mg,Fe2SiO4 (Ǻheim,Norway has been studied and compared in this work. Experiments were carried out with non-activated and mechanically activatedsamples. The activation of both minerals was performed in a planetary mill at different milling conditions. The specific surface areaand consequent sorption activity were enhanced by mechanical activation. The using of olivine seems to be better than magnetite fromthe point of view of milling time, which is necessary for achievement of the same sorption effect.

  11. Sorption of trace cesium on 21 Hanford Site sediment types

    International Nuclear Information System (INIS)

    Routson, R.C.; Barney, G.S.; Smith, R.M.; Delegard, C.A.

    1980-03-01

    Sorption of trace cesium (Cs) was measured on 21 Hanford Site sediment types. A Box-Behnken statistical design was used to develop empirical-statistical equations predicting 137 Cs sorption as a function of the equilibrium concentrations of macroions Na + , K + , and Ca +2 in solution over the concentration ranges of 3.0 to 0.001M, 0.2 to 0.002M, and 0.2 to 0.002M, respectively. These equations are required to estimate trace Cs transport from Hanford ground disposal sites. Average Cs sorption equations for the 21 sediments will be presented and discussed

  12. Research, Development and Demonstration of Micro-CHP System for Residential Applications

    Energy Technology Data Exchange (ETDEWEB)

    Karl Mayer

    2010-03-31

    challenge to the development of a long life LIC system is the development of a reliable and efficient steam generator. The steam generator and support equipment development is described in Section 7. Just one year ago, ECR International announced through its joint venture company, Climate Energy, that it was introducing to the USA market a new class of Micro-CHP product using the state-of-the-art Honda MCHP gas fired internal combustion (IC) engine platform. We now have installed Climate Energy Micro-CHP systems in 20 pilot demonstration sites for the 2005/2006 heating season. This breakthrough success with IC engine based systems paves the way for future advanced steam cycle Micro-CHP systems to be introduced.

  13. Integration of motor traffic in residential areas.

    NARCIS (Netherlands)

    Schreuder, D.A.

    1977-01-01

    In stead of banning the cars from residential areas, the plan is to integrate them in such a way that they can still be used, but that they will loose their predominant position. The areas where this integration is to take place are called residential yards. This paper concentrates on the lighting

  14. Integrated sorption and diffusion model for bentonite. Part 1. Clay-water interaction and sorption modeling in dispersed systems

    International Nuclear Information System (INIS)

    Tachi, Yukio; Suyama, Tadahiro; Ochs, Michael

    2014-01-01

    To predict the long-term migration of radionuclides (RNs) under variable conditions within the framework of safety analyses for geological disposal, thermodynamic sorption models are very powerful tools. The integrated sorption and diffusion (ISD) model for compacted bentonite was developed to achieve a consistent combination of clay–water interaction, sorption, and diffusion models. The basic premise considered in the ISD model was to consistently use the same simple surface model design and parameters for describing RNs sorption/diffusion as well as clay surface and porewater chemistry. A simple 1-site non-electrostatic surface complexation model in combination with a 1-site ion exchange model was selected to keep sorption model characteristics relatively robust for compacted systems. Fundamental parameters for the proposed model were evaluated from surface titration data for purified montmorillonite. The resulting basic model was then parameterized on the basis of selected published sorption data-sets for Np(V), Am(III), and U(VI) in dispersed systems, which cover a range of key geochemical conditions such as pH, ionic strength, and carbonate concentration. The sorption trends for these RNs can be quantitatively described by the model considering a full suite of surface species including hydrolytic and carbonate species. The application of these models to the description of diffusive-sorptive transport in compacted bentonites is presented in Part 2. (author)

  15. Development of a Self-Consistent Model of Plutonium Sorption: Quantification of Sorption Enthalpy and Ligand-Promoted Dissolution

    Energy Technology Data Exchange (ETDEWEB)

    Powell, Brian [Clemson Univ., SC (United States); Kaplan, Daniel I [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Arai, Yuji [Univ. of Illinois, Urbana-Champaign, IL (United States); Becker, Udo [Univ. of Michigan, Ann Arbor, MI (United States); Ewing, Rod [Stanford Univ., CA (United States)

    2016-12-29

    This university lead SBR project is a collaboration lead by Dr. Brian Powell (Clemson University) with co-principal investigators Dan Kaplan (Savannah River National Laboratory), Yuji Arai (presently at the University of Illinois), Udo Becker (U of Michigan) and Rod Ewing (presently at Stanford University). Hypothesis: The underlying hypothesis of this work is that strong interactions of plutonium with mineral surfaces are due to formation of inner sphere complexes with a limited number of high-energy surface sites, which results in sorption hysteresis where Pu(IV) is the predominant sorbed oxidation state. The energetic favorability of the Pu(IV) surface complex is strongly influenced by positive sorption entropies, which are mechanistically driven by displacement of solvating water molecules from the actinide and mineral surface during sorption. Objectives: The overarching objective of this work is to examine Pu(IV) and Pu(V) sorption to pure metal (oxyhydr)oxide minerals and sediments using variable temperature batch sorption, X-ray absorption spectroscopy, electron microscopy, and quantum-mechanical and empirical-potential calculations. The data will be compiled into a self-consistent surface complexation model. The novelty of this effort lies largely in the manner the information from these measurements and calculations will be combined into a model that will be used to evaluate the thermodynamics of plutonium sorption reactions as well as predict sorption of plutonium to sediments from DOE sites using a component additivity approach.

  16. Environmental Conditions Influencing Sorption of Inorganic Anions to Multiwalled Carbon Nanotubes Studied by Column Chromatography.

    Science.gov (United States)

    Metzelder, Florian; Schmidt, Torsten C

    2017-05-02

    Sorption to carbon-based nanomaterials is typically studied in batch experiments. An alternative method offering advantages to study sorption is column chromatography. Sorbent packed columns are used and sorption data are determined by relating sorbate retention to that of a nonretarded tracer. We have now for the first time applied this technique to study the influence of environmental conditions on sorption of inorganic anions (bromide, nitrite, nitrate, and iodide) to multiwalled carbon nanotubes. Deuterium oxide was used as nonretarded tracer. Sorption isotherms were best described by the Freundlich model. Sorption increased in the order bromide 4.5 the surface charge was negative, but sorption was still detectable at pH 6 and 9. Consequently, other forces than electrostatic attraction contributed to sorption. These forces may include H-bonding as indicated by sorption enthalpy determined by variation of column temperature. Overall, column chromatography represents a promising alternative in sorption studies to reveal sorbent properties.

  17. Therapeutic Residential Care for Children and Youth:

    DEFF Research Database (Denmark)

    Whittaker, James K.; Holmes, Lisa; del Valle, Jorge F.

    2016-01-01

    so in closer collaboration with their families and in closer proximity to their home communities; and, (3) with the hope of reducing the high costs often associated with group residential provision. In some jurisdictions, efforts to reduce residential care resources in the absence of sufficient...... alternatives to serve high-resource needing youth has had unintended and negative consequences. It is within this context that a working group international experts representing research, policy, service delivery and families (International Work Group for Therapeutic Residential Care) convened at the Centre...... for Child and Family Research, Loughborough University in the U.K. for a Summit meeting on therapeutic residential care for children and youth funded by the Sir Halley Stewart Trust (UK). The focus centered on what is known about therapeutic residential care and what key questions should inform a priority...

  18. Sorption of radioiodine in organo-clays and -soils

    International Nuclear Information System (INIS)

    Bors, J.

    1990-01-01

    In the framework of investigations on the sorption of radioiodine to natural and artificially altered soil components, a number of clay minerals and natural soils were treated with quaternary alkylammonium ions to replace the exchangeable metal cations. With help of batch experiments the resulting organo-clays were tested with respect to their sorption capability of radioiodine quantified by the distribution ratio (R D -value). Treatment of bentonite, vermiculite and cretaceous clay as well as of samples from natural horizons of chernozem soil with hexadecylpyridinium (HDPY + ) and benzethonium (BE + ) exhibited sorptions rates and amounts, which are several orders of magnitude higher than those of the respective untreated samples. Moderate increases of the R D -values were found after cation exchange with hexadecyltrimethylammonium (HDTMA + ), while the applications of trimethylphenylammonium (TMPA + ) and tetramethylammonium (TMA + ) were ineffective. Considerable sorption of radioiodine was observed with the commercially available Bentone. (orig.)

  19. Sorption of radioiodine in organo-clays and -soils

    Energy Technology Data Exchange (ETDEWEB)

    Bors, J. (Niedersaechsisches Inst. fuer Radiooekologie, Hannover (Germany, F.R.))

    1990-01-01

    In the framework of investigations on the sorption of radioiodine to natural and artificially altered soil components, a number of clay minerals and natural soils were treated with quaternary alkylammonium ions to replace the exchangeable metal cations. With help of batch experiments the resulting organo-clays were tested with respect to their sorption capability of radioiodine quantified by the distribution ratio (R{sub D}-value). Treatment of bentonite, vermiculite and cretaceous clay as well as of samples from natural horizons of chernozem soil with hexadecylpyridinium (HDPY{sup +}) and benzethonium (BE{sup +}) exhibited sorptions rates and amounts, which are several orders of magnitude higher than those of the respective untreated samples. Moderate increases of the R{sub D}-values were found after cation exchange with hexadecyltrimethylammonium (HDTMA{sup +}), while the applications of trimethylphenylammonium (TMPA{sup +}) and tetramethylammonium (TMA{sup +}) were ineffective. Considerable sorption of radioiodine was observed with the commercially available Bentone. (orig.).

  20. Transformation and sorption of illicit drug biomarkers in sewer biofilms

    DEFF Research Database (Denmark)

    Ramin, Pedram; Brock, Andreas Libonati; Causanilles Llanes, Ana

    2017-01-01

    , 16 drug biomarkers were selected, including the major human metabolites of mephedrone, methadone, cocaine, heroin, codeine and tetrahydrocannabinol (THC). Transformation and sorption of these substances were assessed in targeted batch experiments using laboratory-scale biofilm reactors operated under...

  1. Isothermal, kinetic and thermodynamic studies on basic dye sorption ...

    African Journals Online (AJOL)

    Isothermal, kinetic and thermodynamic studies on basic dye sorption onto tartaric acid esterified wheat straw. ... African Journal of Biotechnology ... esterified wheat straw (EWS), was originally prepared by solid phase thermochemistry method.

  2. Isothermal, kinetic and thermodynamic studies on basic dye sorption ...

    African Journals Online (AJOL)

    PRECIOUS

    2009-12-15

    Dec 15, 2009 ... The isothermal data correlated with the Langmuir model better than the. Freundlich model. ... there were two intra-particle diffusion steps in the dye sorption processes. .... rated monolayer of sorbate molecule on the sorbent.

  3. Sorption and desorption of insecticides in Brazilian soils

    International Nuclear Information System (INIS)

    Luchini, L.C.; Lord, K.A.; Ruegg, E.F.

    1980-01-01

    The sorption from aqueous solution of ten Brazilian soil types of four organochlorine, two organophosphorus and one carbamate insecticide was determined in the laboratory using gas chromatographic and radiometric techniques. Measurements showed that soils richest in organic matter, sorbed all substances except aldrin more strongly than the other soils. DDT was the most and aldrin the least sorbed organochlorine pesticide, being dieldrin sorbed two to four times more strongly than aldrin. Sorption of lindane varied in different soils. The organophosphate insecticides malathion and parathion were strongly sorbed in the soils richest in organic matter and weakly sorbed in the poorest soils heing moderately sorbed by the other soils. Sorption of carbaryl by all soils is small. Lindane was desorbed from the soil richest in organic matter and the extent of desorption was dependent on the sorption time. (Author) [pt

  4. Sorption of 237Pu by the diatom Asterionella formosa

    International Nuclear Information System (INIS)

    Conway, H.L.; Wahlgren, M.A.; Peterson, N.; Nelson, D.M.

    1976-01-01

    Knowledge of the behavior of the man-made radionuclide plutonium within aquatic environments is of fundamental importance in assessing its potential hazards and ecological impact. The sorption of plutonium by phytoplankton and other algae is the dominant factor in the biological transport of plutonium in the aquatic environment, and it has been suggested that sorption by phytoplankton may be responsible for the seasonal loss of plutonium from the epilimnion of Lake Michigan. A unialgal diatom culture was spiked with 237 Pu tracer solution in an attempt to simulate the behavior of fallout plutonium observed in field studies. The results were encouraging in that the 237 Pu in the filtered lake water medium exhibited strongly anionic properties similar to fallout plutonium in Lake Michigan, with limited sorption on container walls. The purpose of the present study was to extend the investigations of the sorption of plutonium by phytoplankton in a controlled environment using continuous culture techniques

  5. Copper foliar sorption: study of cuticular uptake and penetration

    International Nuclear Information System (INIS)

    Chamel, Andre; Bougie, Bernadette

    1977-01-01

    Results show that copper is easily retained by enzymatically isolated cuticles from pear leaves discs. The sorption is very rapid during the first hour, then progressively slower with increasing time. Upper and lower cuticles exhibit the same sorption when immersed, but the sorption by the upper internal surface is greater than that by the external surface. Sorption depends on the dates of sampling of the leaves and vegetal species. The variation of the process with concentrations is hyperbolic. The retained copper may be partially exchanged: from 16 to 95% after 24 hours of exchange in a cupric solution, as the Cu concentration increases from 10 -6 to 10 -2 M. The penetration of copper through astomatous cuticular discs is extremely reduced if there is pure water in the receiver unit [fr

  6. Effects of sorption hysteresis on radionuclide releases from waste packages

    International Nuclear Information System (INIS)

    Barney, G.S.; Reed, D.T.

    1985-01-01

    A one-dimensional, numerical transport model was used to calculate radionuclide releases from waste packages emplaced in a nuclear waste repository in basalt. The model incorporates both sorption and desorption isotherm parameters measured previously for sorption of key radionuclides on the packing material component of the waste package. Sorption hysteresis as described by these isotherms lowered releases of some radionuclides by as much as two orders of magnitude. Radionuclides that have low molar inventories (relative to uranium), high solubility, and strongly sorbed, are most affected by sorption hysteresis. In these cases, almost the entire radionuclide inventory is sorbed on the packing material. The model can be used to help optimize the thickness of the packing material layer by comparing release rate versus packing material thickness curves with Nuclear Regulatory Commission (NRC) and Environmental Protection Agency (EPA) release limits

  7. Understanding mechanisms to predict and optimize biochar for agrochemical sorption

    Science.gov (United States)

    Hall, Kathleen; Gámiz, Beatriz; Cox, Lucia; Spokas, Kurt; Koskinen, William

    2017-04-01

    The ability of biochars to bind various organic compounds has been widely studied due to the potential effects on pesticide fate in soil and interest in the adoption of biochar as a "low-cost" filter material. However, the sorptive behaviors of biochars are extremely variable and much of the reported data is limited to specific biochar-chemical interactions. The lack of knowledge regarding biochar sorption mechanisms limits our current ability to predict and optimize biochar's use. This work unveils mechanistic drivers of organic pesticide sorption on biochars through targeted alteration of biochar surface chemistry. Changes in the quantity and type of functional groups on biochars and other black carbon materials were achieved through treatments with H2O2, and CO2, and characterized using Fourier transform infrared spectroscopy and scanning electron microscope (SEM/EDX). The sorption capacities of these treated biochars were subsequently measured to evaluate the effects of different surface moieties on the binding of target herbicides cyhalofop acid ((R)-2-[4-(4-cyano-2-fluorophenoxy)phenoxy]propionic acid) and clomazone (2-[(2-chlorophenyl)methyl]-4,4-dimethyl-1,2-oxazolidin-3-one). Sorption of both herbicides on the studied biochars increased following H2O2 activation; however, the influence of the H2O2 activation on sorption was more pronounced for cyhalofop acid (pKa = 3.9) than clomazone, which is non-ionizable. Increased cyhalofop acid sorption on H2O2 treated biochars can be attributed to the increase in oxygen containing functional groups as well as the decrease in biochar pH. In contrast, CO2 activation reduced the sorption of cyhalofop acid compared to untreated biochar. FTIR data suggest the reduced sorption on CO2 -treated biochar was due to the removal of surface carboxyl groups, further supporting the role of specific functionality in the sorption of ionizable herbicides. Results from this work offer insight into the mechanisms of sorption and

  8. Kinetics of the sorption of triterpene saponin by hypercrosslinked polystyrene

    Science.gov (United States)

    Mironenko, N. V.; Brezhneva, T. A.; Selemenev, V. F.

    2013-03-01

    The kinetics of sorption of triterpene saponin by the polymer sorbent NM-200 is considered. The influence of the surface activity of glycoside on the rate of formation and structure of the adsorption layer on the sorbent's surface is established. The rate-determining step of sorption is found to be diffusion into the sorbent grain. The value of the activation energy demonstrates the determining role of dispersion forces in the interaction between triterpene saponin and the polymer sorbent MN-200.

  9. Further developments of the RES3T sorption database

    International Nuclear Information System (INIS)

    Brendler, V.

    2002-01-01

    RES 3 T - the Rossendorf expert system for surface and sorption thermodynamics currently under development has been expanded towards the provision of comprehensive sorption data sets suitable for complex natural systems of rocks and soils. Also a statistical evaluation of the available SCM (surface complexation model) data is now implemented. Finally, a normalization of SCM parameters to a standard site density has been incorporated. (orig.)

  10. Sorption heat engines: simple inanimate negative entropy generators

    OpenAIRE

    Muller, Anthonie W. J.; Schulze-Makuch, Dirk

    2005-01-01

    The name 'sorption heat engines' is proposed for simple negative entropy generators that are driven by thermal cycling and work on alternating adsorption and desorption. These generators are in general not explicitly recognized as heat engines. Their mechanism is applicable to the fields of engineering, physics, chemistry, geology, and biology, in particular the origin of life. Four kinds of sorption heat engines are distinguished depending on the occurrence of changes in the adsorbent or ads...

  11. Sorption Properties of Steam Treated Wood and Plant Fibres

    DEFF Research Database (Denmark)

    Hoffmeyer, Preben; Jensen, Signe Kamp; Jones, Dennis

    2003-01-01

    temperatures the behaviour was different for low/medium RH and high RH. For low/medium range RH (.... This behaviour corresponds to the reduction of the number of primary sorption sites on e.g. hemicellulose. For high range RH (> ca. 85 %) two additional mechanisms may have been active. One is the capillary sorption in micropores created as a result of the thermal degradation of cell wall matter. A second...

  12. Sorption and pertechnetate by salts of molybdophosphoric acid

    International Nuclear Information System (INIS)

    Suess, M.; Pfrepper, G.

    1983-01-01

    The sorption of pertechnetate on salts of molybdophosphoric acid from nitric acid and in the presence of electrolytes was investigated. Distribution coefficients from 10 to 100 ml/g were found. The sorption of pertechnetate can be increased by the addition of K + , NH 4 + , Rb + and Cs + salts. A saturation capacity of proportional 0,19 mmol/g ammonium phosphomolybdate was found from the adsorption isotherms. The formation of alkali metal pertechnetate associates in the sorbent phase is supposed. (orig.)

  13. Residential electricity demand in Singapore

    International Nuclear Information System (INIS)

    Ang, B.W.; Goh, T.N.; Liu, X.Q.

    1992-01-01

    Residential electricity consumption in Singapore increased at a rate of 8.8% per year between 1972 and 1990. Estimates of the long-run income and price elasticities are 1.0 and -0.35, respectively. The energy-conservation campaigns that have been launched are found to have marginal effects on consumption. A statistical analysis shows that the consumption is sensitive to small changes in climatic variables, particularly the temperature, which is closely linked to the growing diffusion of electric appliances for environmental controls. There has been a temporal increase in the ownership levels of appliances associated with increasing household incomes. However, other factors were involved since the ownership levels would also increase over time after the elimination of the income effect. A large part of the future growth in electricity demand will arise from the growing need for air-conditioning, which will lead to increasingly large seasonal variations in electricity use. (author)

  14. Residential radon survey in Finland

    International Nuclear Information System (INIS)

    Arvela, H.; Maekelaeinen, I.; Castren, O.

    1993-02-01

    The study measured the indoor radon concentration in the dwellings of 3074 persons, selected randomly from the central population register of Finland. Alpha track detectors and two consecutive half year measuring periods were used. The national mean of indoor radon concentration for persons living in low-rise residential buildings as well as blocks of flats was 145 and 82 Bq/m 3 , respectively. The mean for the total population was 123 Bq/m 3 . Based on the decision of the Ministry of Social Affairs and Health in 1992, the indoor radon concentration should not exceed 400 Bq/m 3 in already existing houses, the target for new construction being less than 200 Bq/m 3 . According to the study, the percentage of the Finnish population living in houses with an indoor radon concentration exceeding 200, 400 and 800 Bq/m 3 was 12.3 %, 3.6 % and 1.0 %

  15. Sorption of strontium on bentonites from Slovak deposits

    International Nuclear Information System (INIS)

    Kufcakova, J.; Galambos, M.; Rajc, P.

    2005-01-01

    Sorption on bentonite from different Slovak deposits / Jelsovy potok, Kopernica and Lieskove has been investigated under various experimental conditions, such as contact time, pH, sorbate concentrations, presence of complementary cation. The sorption of strontium from aqueous solutions was investigated using a radiometric determination of distribution coefficient, Kd. The individual solutions were labelled with radiotracer. Radiation stability has been investigated, the higher sorption parameters were observed for the irradiated bentonites /tab.l/ , which can be explained by the increase of specific surface and change of solubility of the irradiated samples of bentonite. The presence of complementary cations, Na + , K + , NH 4 + , Ca 2+ , Mg 2+ and Ba 2+ depresses the sorption of Sr on bentonite. In the case of bentonite Kopernica the effectiveness in reducing the sorption of strontium by cations followed the order K + 4 + + 2+ 2+ 2+ . Results indicate that the sorption of Sr + on bentonite will be affected by the presence of high concentrations of various salts in the waste water effluents. (author)

  16. Moisture sorption isotherms and thermodynamic properties of bovine leather

    Science.gov (United States)

    Fakhfakh, Rihab; Mihoubi, Daoued; Kechaou, Nabil

    2018-04-01

    This study was aimed at the determination of bovine leather moisture sorption characteristics using a static gravimetric method at 30, 40, 50, 60 and 70 °C. The curves exhibit type II behaviour according to the BET classification. The sorption isotherms fitting by seven equations shows that GAB model is able to reproduce the equilibrium moisture content evolution with water activity for moisture range varying from 0.02 to 0.83 kg/kg d.b (0.9898 thermodynamic properties such as isosteric heat of sorption, sorption entropy, spreading pressure, net integral enthalpy and entropy. Net isosteric heat of sorption and differential entropy were evaluated through direct use of moisture isotherms by applying the Clausius-Clapeyron equation and used to investigate the enthalpy-entropy compensation theory. Both sorption enthalpy and entropy for desorption increase to a maximum with increasing moisture content, and then decrease sharply with rising moisture content. Adsorption enthalpy decreases with increasing moisture content. Whereas, adsorption entropy increases smoothly with increasing moisture content to a maximum of 6.29 J/K.mol. Spreading pressure increases with rising water activity. The net integral enthalpy seemed to decrease and then increase to become asymptotic. The net integral entropy decreased with moisture content increase.

  17. Investigation of rare earths sorption from sulfuric- and hydrochloric media

    International Nuclear Information System (INIS)

    Nikonov, V.N.; Mikhlin, E.B.; Norina, T.M.; Afonina, T.A.

    1978-01-01

    A rate of equilibrium attainment has been studied during REE sorption from sulfuric and hydrochloric acid solutions and pulps. It has been shown that equilibrium upon sorption from hydrochloric acid solutions is attained faster than from sulfuric acid solutions. Equilibrium upon sorption from pulps is attained considerably slower than upon sorption from solutions. In all cases REM of cerium subgroup are sorbed better. An effect has been studied of the medium acidity on sorbability of REM and elements of iron and calcium impurities. It has been established that sorbability of these elements decreases with increasing acid concentration. Selectivity of REM sorption from sulfuric acid solutions decreases with a rise in H 2 SO 4 concentration in the solution. For hydrochloric acid solutions it remains constant in a wide range of HCl concentrations. Sorption leaching of REM from concentrates and cakes of sulfuric and hydrochloric acids in the presence of KU-2 leads to high technical and economic indexes: extraction with respect to the total amount of REM and yttrium into a commercial product is 76-86% for sulfuric acid solutions and 81-90% for hydrochloric solutions

  18. Modelling of a diffusion-sorption experiment on sandstone

    International Nuclear Information System (INIS)

    Smith, P.A.

    1989-11-01

    The results of a diffusion-sorption experiment on a sample of Darley Dale sandstone, using simulated groundwater spiked with a mixture of 125 I, 85 Sr and 137 Cs, are modelled by a one-dimensional porous medium approach in which sorption is described by Freundlich isotherms. The governing equations are solved analytically for the special case of a linear isotherm, and numerically using the computer code RANCHDIFF for non-linear isotherms. A set of time-dependent, ordinary differential equations is obtained using the Lagrange interpolation technique and integrated by Gear's variable order predictor-corrector method. It is shown that the sorption behaviour of 85 Sr can be modelled successfully by a linear isotherm, using a sorption parameter consistent with batch-sorption tests. The behaviour of 137 Cs may be modelled by a non-linear isotherm, but the amount of 137 Cs sorbed is less than that anticipated from batch-sorption tests. 125 I is assumed to be non-sorbing and is used to determine the porosity of the sandstone. (author) 10 figs., 4 tabs., 6 refs

  19. The sorption of silver by poorly crystallized manganese oxides

    Science.gov (United States)

    Anderson, B.J.; Jenne, E.A.; Chao, T.T.

    1973-01-01

    The sorption of silver by poorly crystallized manganese oxides was studied using synthesized samples of three members of the manganous manganite (birnessite) group, of different chemical composition and crystallinity, and a poorly organized ??-MnO2. All four oxides sorbed significant quantities of silver. The manganous manganites showed the greatest sorption (up to 0.5 moles silver/mole MnOx at pH 7) while the ??-MnO2 showed the least (0.3 moles silver/ mole MnOx at pH 7). Sorption of silver was adequately described by the Langmuir equation over a considerable concentration range. The relationship failed at low pH values and high equilibrium silver concentrations. The sorption capacity showed a direct relationship with pH. However, the rate of increase of sorption capacity decreased at the higher pH values. Silver sorption maxima. were not directly related to surface area but appeared to vary with the amount of occluded sodium and potassium present in the manganese oxide. The important processes involved in the uptake of silver by the four poorly crystallized manganese oxides ara considered to be surface exchange for manganese, potassium and sodium as well as exchange for structural manganese, potassium and sodium. ?? 1973.

  20. Thermodynamic parameters and sorption of U(VI) on ACSD

    International Nuclear Information System (INIS)

    Donat, R.; Cilgi, G.K.; Cetisli, H.; Aytas, S.

    2009-01-01

    This paper discusses the sorption properties for U(VI) by alginate coated CaSO 4 x 2H 2 O sepiolite and calcined diatomite earth (Kieselguhr) (ACSD). The removal of U(VI) from aqueous solution by sorption onto ACSF in a single component system with various contact times, pH, temperatures, and initial concentrations of U(VI) was investigated. The sorption patterns of uranium on the composite adsorbent followed the Langmuir, Freundlich and Dubinin-Radushkhevic (D-R) isotherms. The Freundlich, Langmuir, and D-R models have been applied and the data correlated well with Freundlich model and that the sorption was physical in nature (sorption energy, E a = 17.05 kJ/mol). The thermodynamic parameters such as variation of enthalpy ΔH, variation of entropy ΔS and variation of Gibbs free energy ΔG were calculated from the slope and intercept of lnK 0 vs. 1/T plots. Thermodynamic parameters (ΔH ads = 31.83 kJ/mol, ΔS ads = 167 J/mol x K, ΔGdeg ads (293.15 K) = -17.94 kJ/mol) showed the endothermic heat of sorption and the feasibility of the process. The thermodynamics of U(VI) ion/ACSD system indicates the spontaneous and endothermic nature of the process. It was noted that an increase in temperature resulted in a higher uranium loading per unit weight of the adsorbent. (author)

  1. Compilation of radionuclide sorption coefficients for performance assessment

    Energy Technology Data Exchange (ETDEWEB)

    Carbol, P.; Engkvist, I. [PI Chemical Consulting HB, Landvetter (Sweden)

    1997-09-01

    The report presents four possible site-specific conditions in Sweden. The different sorption mechanisms applicable to the studied elements together with the K{sub d} concept are shortly summarised. The influence of organic substances present in the groundwater on the element`s sorption and mobility is also discussed. Criteria for selection of K{sub d} values are presented together with sensitivity of the values to pH, E{sub h} and salinity. Sorption coefficients are recommended for elements in the repository with half-life above 5.3 years. The elements reviewed are: Cs, Sr, Ra, Ln, Ac, Th, Pa, U, Np, Pu, Am, Cm, Co, Ni, Cd, Zr, Nb, Tc, Pd, Ag, Sn, C, I, Cl, Se and Kr. For every element there is a recommendation of a realistic K{sub d} value with an uncertainty limit. The selection is based on experimental investigations or chemical analogues. In some cases few or no K{sub d} data were found, and it is recommended that sorption studies be performed on elements such as Cd, Pa, Cm, Zr, Nb, Pd, Ag and Sn. The recommended K{sub d} values for the different element`s sorption on granitic rock, serve as a guidance of the sorption performance 87 refs, 18 tabs

  2. Compilation of radionuclide sorption coefficients for performance assessment

    International Nuclear Information System (INIS)

    Carbol, P.; Engkvist, I.

    1997-09-01

    The report presents four possible site-specific conditions in Sweden. The different sorption mechanisms applicable to the studied elements together with the K d concept are shortly summarised. The influence of organic substances present in the groundwater on the element's sorption and mobility is also discussed. Criteria for selection of K d values are presented together with sensitivity of the values to pH, E h and salinity. Sorption coefficients are recommended for elements in the repository with half-life above 5.3 years. The elements reviewed are: Cs, Sr, Ra, Ln, Ac, Th, Pa, U, Np, Pu, Am, Cm, Co, Ni, Cd, Zr, Nb, Tc, Pd, Ag, Sn, C, I, Cl, Se and Kr. For every element there is a recommendation of a realistic K d value with an uncertainty limit. The selection is based on experimental investigations or chemical analogues. In some cases few or no K d data were found, and it is recommended that sorption studies be performed on elements such as Cd, Pa, Cm, Zr, Nb, Pd, Ag and Sn. The recommended K d values for the different element's sorption on granitic rock, serve as a guidance of the sorption performance

  3. Experimental determination of sorption in fractured flow systems

    Science.gov (United States)

    Zimmerman, Mitchell D.; Bennett, Philip C.; Sharp, John M.; Choi, Wan-Joo

    2002-09-01

    Fracture "skins" are alteration zones on fracture surfaces created by a variety of biological, chemical, and physical processes. Skins increase surface area, where sorption occurs, compared to the unaltered rock matrix. This study examines the sorption of organic solutes on altered fracture surfaces in an experimental fracture-flow apparatus. Fracture skins containing abundant metal oxides, clays, and organic material from the Breathitt Formation (Kentucky, USA) were collected in a manner such that skin surface integrity was maintained. The samples were reassembled in the lab in a flow-through apparatus that simulated ˜2.7 m of a linear fracture "conduit." A dual-tracer injection scheme was utilized with the sorbing or reactive tracer compared to a non-reactive tracer (chloride) injected simultaneously. Sorption was assessed from the ratio of the first temporal moments of the breakthrough curves and from the loss of reactive tracer mass and evaluated as a function of flow velocity and solute type. The breakthrough curves suggest dual-flow regimes in the fracture with both sorbing and non-sorbing flow fields. Significant sorption occurs for the reactive components, and sorption increased with decreasing flow rate and decreasing compound solubility. Based on moment analysis, however, there was little retardation of the center of solute mass. These data suggest that non-equilibrium sorption processes dominate and that slow desorption and boundary layer diffusion cause extensive tailing in the breakthrough curves.

  4. Sorption Coefficients for Iodine, Silver, and Cesium on Dust Particles

    International Nuclear Information System (INIS)

    Stempniewicz, M.M.; Goede, P.

    2014-01-01

    This paper describes the work performed to find relevant experimental data and find the sorption coefficients that represent well the available data for cesium, iodine, and silver on dust particles. The purpose of this work is to generate a set of coefficients that may be recommended for the computer code users. The work was performed using the computer code SPECTRA. Calculations were performed for the following data: • I-131 on AVR dust; • Ag-110m on AVR dust; • Cs-13 and Cs-137 on AVR dust. Available data was matched using the SPECTRA Sorption Model. S = A(T) · C_V-B(T) · C_d. The results are summarized as follows: • The available data can be correlated. The data scatter is about 4 orders of magnitude. Therefore the coefficients of the Langmuir isotherms vary by 4 orders of magnitude. • Sorption rates are higher at low temperatures and lower at high temperatures. This tendency has been observed in the data compiled at Oak Ridge. It is therefore surmised that the highest value of the sorption coefficients are appropriate for the low temperatures and the lowest value of the sorption coefficients are appropriate for the high temperatures. The recommended sorption coefficients are presented in this paper. • The present set of coefficients is very rough and should be a subject for future verification against experimental data. (author)

  5. Correlational study between sorption and goo apparent organoclays

    International Nuclear Information System (INIS)

    Silva, D.L.; Silva, M.R.O.; Ferreira, H.S.; Brasileiro, C.T.

    2016-01-01

    The sorption of surfactants in bentonite clay can occur through the mechanism of adsorption and absorption, this being a very supple phenomenon according clay and surfactant utilized. Thus the more surfactant sorbed at the organoclay it becomes, and can be used in various applications, including in oil drilling fluid. This study aimed to correlate the sorption of surfactants with the rheological properties of non-aqueous fluids (oil base). In organophilization process was used Bentongel clay which had its concentration varied from 3.16 to 7.16% by weight of clay. It was used to organophilization an ionic surfactant Praepagem WB with 75% of active matter, where its concentration ranged from 127-181 mEq. After organophilizated the clays were filtered, dried in an oven for 48 hours and passed in ABNT sieve No. 200, to be so characterized. Sorption was calculated from mathematical equations. Non-aqueous fluids were prepared according to standard Petrobras (EP-1EP-00023A) for rheological testing. Correlating the sorption of surfactant, and the rheological properties of non-aqueous fluid, obtained satisfactory results where observed through the scatter plots there is a strong correlation between the variables sorption and apparent viscosity, it should also be noted that the viscosity is a variable which increases with an increase in sorption, confirming that the surfactant concentration influences the viscosity. (author)

  6. Sorption and diffusion of FE(II) in bentonite

    International Nuclear Information System (INIS)

    Muurinen, A.; Tournassat, C.; Hadi, J.; Greneche, J.-M.

    2014-02-01

    The iron in the engineering barrier system of a nuclear waste repository interacts via the corrosion process with the swelling clay intended as the buffer material. This interaction may affect the sealing properties of the clay. In the case of iron-bentonite interaction, redox reactions, dissolution/precipitation, the diffusion and sorption are coupled together. In a combined study different processes are difficult to distinguish from each other, and more specific studies are needed for the separate processes. In particular, there is a need for well-controlled diffusion and sorption experiments where iron is kept as Fe(II). In this project, sorption and diffusion of Fe(II) in bentonite have been studied. The experiments were carried out under low-oxygen conditions in an anaerobic glove-box. The radioactive isotope ( 55 Fe) was used as a tracer in the experiments. The sorption experiments were carried out with two batches of purified MX-80 bentonite. One was purified at Bureau de Recherches Geologiques et Minieres, French Geological Survey (BRGM) and the other one at VTT Technical Research Centre of Finland (VTT). Experiments were also carried out with synthetic smectite, which did not include iron, which was prepared at LMPC (ENSC, F 68093 Mulhouse, France). The sorption experiments were carried out in 0.3 M and 0.05 M NaCl solutions as a function of pH, and in 0.3 M NaCl solution buffered at pH 5 as a function of added Fe(II) concentration. The separation of bentonite and solution at the end of the sorption experiment was carried out in the early phase by centrifuging only. In the later phase, ultrafiltering was added in order to improve the separation. The diffusion experiments were carried out in compacted samples prepared from MX-80 purified at VTT and saturated with 0.3 M NaCl at pH 8 and 5. A non-steady-state diffusion experiment method, where the tracer was introduced as an impulse source between two bentonite plugs was used in the measurements

  7. Sorption and diffusion of FE(II) in bentonite

    Energy Technology Data Exchange (ETDEWEB)

    Muurinen, A. [VTT Technical Research Centre of Finland, Espoo (Finland); Tournassat, C.; Hadi, J. [BRGM, Orleans (France); Greneche, J.-M. [LPCE, Le Mans (France)

    2014-02-15

    The iron in the engineering barrier system of a nuclear waste repository interacts via the corrosion process with the swelling clay intended as the buffer material. This interaction may affect the sealing properties of the clay. In the case of iron-bentonite interaction, redox reactions, dissolution/precipitation, the diffusion and sorption are coupled together. In a combined study different processes are difficult to distinguish from each other, and more specific studies are needed for the separate processes. In particular, there is a need for well-controlled diffusion and sorption experiments where iron is kept as Fe(II). In this project, sorption and diffusion of Fe(II) in bentonite have been studied. The experiments were carried out under low-oxygen conditions in an anaerobic glove-box. The radioactive isotope ({sup 55}Fe) was used as a tracer in the experiments. The sorption experiments were carried out with two batches of purified MX-80 bentonite. One was purified at Bureau de Recherches Geologiques et Minieres, French Geological Survey (BRGM) and the other one at VTT Technical Research Centre of Finland (VTT). Experiments were also carried out with synthetic smectite, which did not include iron, which was prepared at LMPC (ENSC, F 68093 Mulhouse, France). The sorption experiments were carried out in 0.3 M and 0.05 M NaCl solutions as a function of pH, and in 0.3 M NaCl solution buffered at pH 5 as a function of added Fe(II) concentration. The separation of bentonite and solution at the end of the sorption experiment was carried out in the early phase by centrifuging only. In the later phase, ultrafiltering was added in order to improve the separation. The diffusion experiments were carried out in compacted samples prepared from MX-80 purified at VTT and saturated with 0.3 M NaCl at pH 8 and 5. A non-steady-state diffusion experiment method, where the tracer was introduced as an impulse source between two bentonite plugs was used in the measurements

  8. Sorption of organic water pollutants on dead vegetable biomass; Sorption organischer Wasserschadstoffe an abgestorbene pflanzliche Biomasse

    Energy Technology Data Exchange (ETDEWEB)

    Kraeuter, A.

    2001-03-01

    Hemp-derived biological sorption agents were produced, and their physical, chemical and sorptive characteristics were tested in batch and filter tests. The experiments were accompanied by model calculations. In the natural state, the sorption agents had a kation exchange capacity of 0.1-0.3 mmol/g, modified sorption agents had about 2 mmol/g. Kationized hemp had values of 0.34 mmol/g and thermally modified hemp absorption agents absorbed more than 1.2 mmol/g of dichlorophenol. In the case of a liquid effluent from a textile dyeing plant, only a discoloration effect was achieved. The absorption agents can be regenerated, combusted or composted after use. [German] Im Rahmen dieser Arbeit wurden naturbelassene und modifizierte Billig-Biosorbentien aus Hanfschaeben zur Entfernung organischer Schadstoffe aus Waessern hergestellt und ihre physikalischen, chemischen und sorptiven Eigenschaften in Batch- und Filterversuchen untersucht. Wegen der Komplexheit des Systems ''Biosorption organischer Wasserschadstoffe'' wurden die ermittelten Sorptionsisothermen mit den Ansaetzen nach Langmuir und Freundlich beschrieben. Die Sorptionskinetik und das Durchbruchsverhalten wurde ebenfalls mit einfachen Ansaetzen modelliert. Naturbelassene Hanfschaeben erreichten Kationenaustauschkapazitaeten von 0,1-0,3 mmol/g, entsprechend modifizierte Hanfschaeben ca. 2 mmol/g. Kationisierte Hanfschaeben dagegen erreichten Anionenaustauschkapazitaeten von 0,34 mmol/g und thermisch modifizierte Hanfschaeben sorbierten bis ueber 1,2 mmol/g Dichlorphenol. Bei der Behandlung eines Abwassers aus einer Textilfaerberei beschraenkte sich die Reinigungsleistung der hergestellten Biosorbentien auf eine Entfaerbung. Nach Schadstoffbeladung koennen die Hanfschaeben regeneriert, thermisch verwertet oder kompostiert werden. (orig.)

  9. Application of simplified desorption method to sorption study. (2) Sorption of neptunium (V) on montmorillonite-based mixtures

    International Nuclear Information System (INIS)

    Kozai, Naofumi; Ohnuki, Toshihiko

    2013-01-01

    To elucidate the sorption behaviors of radionuclides in multi-mineral systems and the mutual effects of minerals on the sorption, this paper carried out the sorption and desorption experiments of neptunium(V) on montmorillonite-based two-mineral mixtures. The Np sorbed on montmorillonite at pH from 4 to 8 was desorbed with 1M KCl solutions, indicating that the sorption was cation exchange. The Np sorbed on apatite and calcite was nondesorbable with 1M KCl solutions, which is in harmony with the knowledge that Np forms strong complexes with the phosphate groups of apatite and the carbonate groups of calcite. This study utilized these clear distinguishes of the desorption behaviors for examining the two-mineral systems. In montmorillonite-apatite mixtures, the sorption on the montmorillonite was decreased and Np was accumulated on the apatite. In montmorillonite-calcite mixtures, the sorption on the montmorillonite was decreased due to the interference by the calcium and carbonate ions dissolved from calcite while no accumulation of Np to calcite was observed. (author)

  10. Vertical barriers with increased sorption capacities

    International Nuclear Information System (INIS)

    Bradl, H.B.

    1997-01-01

    Vertical barriers are commonly used for the containment of contaminated areas. Due to the very small permeability of the barrier material which is usually in the order of magnitude of 10-10 m/s or less the advective contaminant transport can be more or less neglected. Nevertheless, there will always be a diffusive contaminant transport through the barrier which is caused by the concentration gradient. Investigations have been made to increase the sorption capacity of the barrier material by adding substances such as organoclays, zeolites, inorganic oxides and fly ashes. The contaminants taken into account where heavy metals (Pb) and for organic contaminants Toluole and Phenantrene. The paper presents results of model calculations and experiments. As a result, barrier materials can be designed 'tailor-made' depending on the individual contaminant range of each site (e.g. landfills, gasworks etc.). The parameters relevant for construction such as rheological properties, compressive strength and permeability are not affected by the addition of the sorbents

  11. Characterization of nanoporous shales with gas sorption

    Science.gov (United States)

    Joewondo, N.; Prasad, M.

    2017-12-01

    The understanding of the fluid flow in porous media requires the knowledge of the pore system involved. Fluid flow in fine grained shales falls under different regime than transport regime in conventional reservoir due to the different average pore sizes in the two materials; the average pore diameter of conventional sandstones is on the micrometer scale, while of shales can be as small as several nanometers. Mercury intrusion porosimetry is normally used to characterize the pores of conventional reservoir, however with increasingly small pores, the injection pressure required to imbibe the pores becomes infinitely large due to surface tension. Characterization of pores can be expressed by a pore size distribution (PSD) plot, which reflects distribution of pore volume or surface area with respect to pore size. For the case of nanoporous materials, the surface area, which serves as the interface between the rock matrix and fluid, becomes increasingly large and important. Physisorption of gas has been extensively studied as a method of nanoporous solid characterization (particularly for the application of catalysis, metal organic frameworks, etc). The PSD is obtained by matching the experimental result to the calculated theoretical result (using Density Functional Theory (DFT), a quantum mechanics based modelling method for molecular scale interactions). We present the challenges and experimental result of Nitrogen and CO2 gas sorption on shales with various mineralogy and the interpreted PSD obtained by DFT method. Our result shows significant surface area contributed by the nanopores of shales, hence the importance of surface area measurements for the characterization of shales.

  12. 12 CFR 541.23 - Residential real estate.

    Science.gov (United States)

    2010-01-01

    ... 12 Banks and Banking 5 2010-01-01 2010-01-01 false Residential real estate. 541.23 Section 541.23... AFFECTING FEDERAL SAVINGS ASSOCIATIONS § 541.23 Residential real estate. The terms residential real estate... home used in part for business); (c) Other real estate used for primarily residential purposes other...

  13. 12 CFR 541.16 - Improved residential real estate.

    Science.gov (United States)

    2010-01-01

    ... 12 Banks and Banking 5 2010-01-01 2010-01-01 false Improved residential real estate. 541.16... REGULATIONS AFFECTING FEDERAL SAVINGS ASSOCIATIONS § 541.16 Improved residential real estate. The term improved residential real estate means residential real estate containing offsite or other improvements...

  14. Material Research on Salt Hydrates for Seasonal Heat Storage Application in a Residential Environment

    Energy Technology Data Exchange (ETDEWEB)

    Ferchaud, C.J.; Zondag, H.A.; De Boer, R. [ECN Biomass and Energy Efficiency, Petten (Netherlands)

    2013-09-15

    Water vapor sorption in salt hydrates is a promising method to realize seasonal solar heat storage in the residential sector. Several materials already showed promising performance for this application. However, the stability of these materials needs to be improved for long-term (30 year) application in seasonal solar heat storages. The purpose of this article is to identify the influence of the material properties of the salt hydrates on the performance and the reaction kinetics of the sorption process. The experimental investigation presented in this article shows that the two salt hydrates Li2SO4.H2O and CuSO4.5H2O can store and release heat under the operating conditions of a seasonal solar heat storage in a fully reversible way. However, these two materials show differences in terms of energy density and reaction kinetics. Li2SO4.H2O can release heat with an energy density of around 0.80 GJ/m{sup 3} within 4 hours of rehydration at 25C, while CuSO4.5H2O needs around 130 hours at the same temperature to be fully rehydrated and reaches an energy density of 1.85 GJ/m{sup 3}. Since the two salts are dehydrated and hydrated under the same conditions, this difference in behavior is directly related to the intrinsic properties of the materials.

  15. Sorption data bases for generic Swiss argillaceous rock systems

    International Nuclear Information System (INIS)

    Bradbury, M. H.; Baeyens, B.; Thoenen, T.

    2010-09-01

    In Switzerland the site selection procedure for both high level waste (HLW) and low and intermediate level waste (L/ILW) repositories is specified by the Swiss Federal Office of Energy in the Sectoral Plan for Deep Geological Repositories. In the forthcoming stage 2 of this plan, potential sites will be identified within regions previously selected based on the presence of suitable host rocks, namely Opalinus Clay, 'Brauner Dogger', Effingen Member and Helvetic Marl. Preliminary safety analyses are an integral part of this procedure, and require, amongst other information, the radionuclide sorption properties of the host rock. This report describes a methodology to develop a Generic Rock Sorption Data Base (GR-SDB) for argillaceous rocks. The method will be used to compile specific SDBs for the above mentioned host rocks. Arguments are presented that the main factor influencing sorption on argillaceous rocks is the phyllosilicate mineral content. These minerals are particularly effective at binding metals to their surfaces by cation exchange and surface complexation. Generally, the magnitude of sorption is directly correlated with the phyllosilicate content (2:1 type clays: illite/smectite/illitesmectite mixed layers), and this parameter best reflects the sorption potential of a given mineral assembly. Consequently, sorption measurements on illite were preferably used as source data for the GR-SDB. The second component influencing radionuclide sorption is the porewater chemistry. In the present report, generic water compositions were extracted from the analytical ranges of deep ground waters in various sedimentary formations in Switzerland. In order to cover the range of ionic strength (I) and pH values of Swiss ground waters in argillaceous rocks, five types of generic water compositions were defined, combining low, intermediate and high values of ionic strength and pH. The GR-SDB for in situ conditions was derived using conversion factors (CF). As the name

  16. Development of Residential SOFC Cogeneration System

    Science.gov (United States)

    Ono, Takashi; Miyachi, Itaru; Suzuki, Minoru; Higaki, Katsuki

    2011-06-01

    Since 2001 Kyocera has been developing 1kW class Solid Oxide Fuel Cell (SOFC) for power generation system. We have developed a cell, stack, module and system. Since 2004, Kyocera and Osaka Gas Co., Ltd. have been developed SOFC residential co-generation system. From 2007, we took part in the "Demonstrative Research on Solid Oxide Fuel Cells" Project conducted by New Energy Foundation (NEF). Total 57 units of 0.7kW class SOFC cogeneration systems had been installed at residential houses. In spite of residential small power demand, the actual electric efficiency was about 40%(netAC,LHV), and high CO2 reduction performance was achieved by these systems. Hereafter, new joint development, Osaka Gas, Toyota Motors, Kyocera and Aisin Seiki, aims early commercialization of residential SOFC CHP system.

  17. Development of Residential SOFC Cogeneration System

    International Nuclear Information System (INIS)

    Ono, Takashi; Miyachi, Itaru; Suzuki, Minoru; Higaki, Katsuki

    2011-01-01

    Since 2001 Kyocera has been developing 1kW class Solid Oxide Fuel Cell (SOFC) for power generation system. We have developed a cell, stack, module and system. Since 2004, Kyocera and Osaka Gas Co., Ltd. have been developed SOFC residential co-generation system. From 2007, we took part in the 'Demonstrative Research on Solid Oxide Fuel Cells' Project conducted by New Energy Foundation (NEF). Total 57 units of 0.7kW class SOFC cogeneration systems had been installed at residential houses. In spite of residential small power demand, the actual electric efficiency was about 40%(netAC,LHV), and high CO2 reduction performance was achieved by these systems. Hereafter, new joint development, Osaka Gas, Toyota Motors, Kyocera and Aisin Seiki, aims early commercialization of residential SOFC CHP system.

  18. Forecasting residential electricity demand in provincial China.

    Science.gov (United States)

    Liao, Hua; Liu, Yanan; Gao, Yixuan; Hao, Yu; Ma, Xiao-Wei; Wang, Kan

    2017-03-01

    In China, more than 80% electricity comes from coal which dominates the CO2 emissions. Residential electricity demand forecasting plays a significant role in electricity infrastructure planning and energy policy designing, but it is challenging to make an accurate forecast for developing countries. This paper forecasts the provincial residential electricity consumption of China in the 13th Five-Year-Plan (2016-2020) period using panel data. To overcome the limitations of widely used predication models with unreliably prior knowledge on function forms, a robust piecewise linear model in reduced form is utilized to capture the non-deterministic relationship between income and residential electricity consumption. The forecast results suggest that the growth rates of developed provinces will slow down, while the less developed will be still in fast growing. The national residential electricity demand will increase at 6.6% annually during 2016-2020, and populous provinces such as Guangdong will be the main contributors to the increments.

  19. Influence of Macroeconomic Factors on Residential Property ...

    African Journals Online (AJOL)

    Sultan

    exerted by macroeconomic factors on residential property returns in Abuja. The backward .... explanatory power and positive influence of employment and ...... Project. Management In Property Development: the Nigeria experience. Ibadan:.

  20. Plasma Processing of Model Residential Solid Waste

    Science.gov (United States)

    Messerle, V. E.; Mossé, A. L.; Nikonchuk, A. N.; Ustimenko, A. B.; Baimuldin, R. V.

    2017-09-01

    The authors have tested the technology of processing of model residential solid waste. They have developed and created a pilot plasma unit based on a plasma chamber incinerator. The waste processing technology has been tested and prepared for commercialization.

  1. Sorption mechanisms of chromate with coprecipitated ferrihydrite in aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Mamun, Abdullah Al, E-mail: mamun@toki.waseda.jp [Graduate School of Creative Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555 (Japan); Morita, Masao, E-mail: masao.swimer@akane.waseda.jp [Graduate School of Creative Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555 (Japan); Matsuoka, Mitsuaki, E-mail: m-matsuoka@aoni.waseda.jp [Faculty of Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555 (Japan); Tokoro, Chiharu, E-mail: tokoro@waseda.jp [Faculty of Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555 (Japan)

    2017-07-15

    Highlights: • Coprecipitation showed twice the sorption density of simple adsorption at pH 5. • Mechanism shift from outer- to inner-sphere surface complexation at high Cr/Fe. • In coprecipitation the mechanism shift occurs at lower Cr/Fe ratios than adsorption. • Higher-molar-ratio bidentate binuclear Cr−Fe bonds; yielded ferrihydrite expansion. - Abstract: Hexavalent chromium (Cr(VI)) attracted researchers’ interest for its toxicity, natural availability and removal difficulty. Nevertheless, its sorption mechanism is not clearly understood yet. In this work, we elucidated the sorption mechanism of the co-precipitation of chromates with ferrihydrite through quantitative analysis. The influence of Cr/Fe molar ratio on sorption was investigated by zeta potential measurements, X-ray diffraction (XRD) and X-ray adsorption fine-structure analysis (XAFS). Coprecipitation at pH 5 showed almost twice the sorption density of adsorption at pH 5. In co-precipitation, a shift of the XRD peak due to inner-sphere sorption of chromate was observed at Cr/Fe molar ratio 0.5. For adsorption, the same peak shift was confirmed at Cr/Fe molar ratio of 1. Zeta potential at pH 5 suggested that the sorption mechanism changed at Cr/Fe molar ratio 0.25 for coprecipitation and at Cr/Fe molar ratio of 1 for adsorption. Fitting of Cr and Fe K-edge extended X-ray adsorption fine-structure suggested that ferrihydrite immobilized Cr(VI) via outer sphere surface complexation for lower Cr/Fe ratios and via inner-sphere surface complexation for higher molar ratios. At higher molar ratios, bidentate binuclear Cr−Fe bonds were well established, thus resulting in the expansion of the ferrihydrite structure.

  2. Sorption of radionuclides from spent fuel in crystalline rocks

    International Nuclear Information System (INIS)

    Nikula, A.

    1982-10-01

    The safe disposal of spent nuclear fuel or reprocessed waste is an essential element in the expansion of the nuclear power industry. Stable rock formations e.g. granite are considered to be potential sites for disposal. A major factor in evaluating the degree of safety of the disposal is the sorption of radionuclides in rock, which affects their retardation. The report considers the chemical forms of the hazardous radionuclides of spent nuclear fuel in groundwater and the effects of the water's properties on them. In the groundwater near the Olkiluoto power plant site cesium, strontium and radium are in cationic form, iodine as I - . Technetium would occur as TcO +2 , but the pertechnetate form is also possible. Uranium most probably would be as U(VI) plutonium and neptunium as Np(IV) or Np(V). The valences for thorium, americium and curium are not changed in this groundwater and would be +4, +3 and +3, respectively. The actinides in groundwater are all in hydrated or complex form. An increase on the ionic stregth of the groundwater in most instances causes a decrease in the sorption of nuclides since the ion exchange capacity of the rock is limited. Anionic ligands also decrease sorption of cations by complex formation. In some case, on the other hand, high salt concentrations may cause formation of radiocolloids of lanthanides and neptunium and thus increase sorption. In all cases the degree of sorption described by the distribution ratio Ksub(d) was influenced by the pH of the groundwater. Sorption of cesium and strontium increased with growing pH. The sorption behaviour of actinides was in positive correlation with formation of hydroxide complexes at different pH values. The Ksub(d) values of Cs, Sr, Co, Ni and Am for Olkiluoto granites were found to agree with Swedish values, also determined at ambient atmospheric conditions

  3. Comparing uranyl sorption complexes on soil and reference clays

    International Nuclear Information System (INIS)

    Chisholm-Brause, C.J.; Berg, J.M.; Conradson, S.D.; Morris, D.E.; McKinley, J.P.; Zachara, J.M.

    1993-01-01

    Clay minerals and other components in natural soils may play a key role in limiting the mobility of uranium in the environment through the formation of sorption complexes. Reference clays are frequently used as models to study sorption processes because they have well-known chemical and physical properties, but they may differ chemically and morphologically from clays derived from natural soils. Therefore, inferences based on reference clay data have been questioned. The authors have used luminescence and x-ray absorption spectroscopies to characterize the sorption complexes of aqueous uranyl (UO 2 2+ ) species on two soil smectites from the Kenoma and Ringold formations, and compared these results to those obtained on reference smectite clays. The pH dependence of uptake suggests that the ratio of sorption on amphoteric edge sites is greater for the soil smectites than for reference clays such as Wyoming montmorillonite (SWy-1). The luminescence spectra for uranyl sorbed to the soil clays are very similar to those for uranyl sorbed principally to the edge sites of SWy-1. This observation supports the solution data suggesting that adsorption to amphoteric sites is a more important mechanism for soil clays. However, the spectral data indicate that the sorption complexes on natural and reference clays are quite similar. Furthermore, as with the reference clays, the authors have found that the chemistry of the solution plays a greater role in defining the sorption complex than does the clay matrix. Thus, if differences in surface properties are adequately taken into account, the reference clays may serve as useful analogs for soil clays in investigations of metal-ion sorption

  4. Natural minerals and synthetic materials for sorption of radioactive anions

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Mun Ja; Chun, Kwan Sik; Kim, Seung Soo

    1998-07-01

    Technetium-99 and iodine-129 are fission products with long half-lives, and exist as highly soluble anionic species. Studies on natural and synthetic materials sorbing TcO{sub 4} and/or I have been performed by several researchers. The application of these materials as an additive in the high-level waste disposal has been considered. The iron- or sulfide-containing minerals such as metal iron, iron powder, stibnite and pyrrhotite show a high capacity for TcO{sub 4} sorption. And the small amounts of activated carbon are reported to have high distribution coefficients recently. In the iodine sorption studies, sulfide-, copper-, lead- or mercury-containing minerals can be a candidate. Pyrite, chalcopyrite, galena, Cu{sub 2}S and CuS reveal a high capacity for I sorption. The synthetic materials were found to have high sorption capacity and compensate the defects of natural minerals, which contain hydrous oxides such as zirconium oxide, aluminium oxide and mercarbide. The mercarbide has the high distribution coefficients for the sorption of TcO{sub 4} and I. Recently it was proposed that the synthetic clay, hydrotalcite, could be useful for the fixation of anion. However, to determine the applicability of those natural and synthetic materials as an additive to a buffer or backfill material for sorption of TcO{sub 4} and/or I, the sorption behavior of the anions on those materials under the repository conditions should be identified. (author). 32 refs., 21 tabs., 10 figs

  5. Sericitization of illite decreases sorption capabilities for cesium

    Science.gov (United States)

    Choung, S.; Hwang, J.; Han, W.; Shin, W.

    2017-12-01

    Release of radioactive cesium (137Cs) to environment occurs through nuclear accidents such as Chernobyl and Fukushima. The concern is that 137Cs has long half-life (t1/2 = 30.2 years) with chemical toxicity and γ-radiation. Sorption techniques are mainly applied to remove 137Cs from aquatic environment. In particular, it has been known well that clay minerals (e.g, illite) are effective and economical sorbents for 137Cs. Illite that was formed by hydrothermal alteration exist with sericite through "sericitization" processes. Although sericite has analogous composition and lattice structure with illite, the sorptive characteristics of illite and sericite for radiocesium could be different. This study evaluated the effects of hydrothermal alteration and weathering process on illite cesium sorption properties. Natural illite samples were collected at Yeongdong area in Korea as the world-largest hydrothermal deposits for illite. The samples were analyzed by XRF, XRD and SEM-EDX to determine mineralogy, chemical compositions and morphological characteristics, and used for batch sorption experiments. The Yeongdong illites predominantly consist of illite, sericite, quartz, and albite. The measured cesium sorption distribution coefficients (Kd,Cs) of reference illite and sericite were approximately 6000 and 400 L kg-1 at low aqueous concentration (Cw 10-7 M), respectively. In contrast, Kd,Cs values for the Yeongdong illite samples ranged from 500 to 4000 L kg-1 at identical concentration. The observed narrow and sharp XRD peak of sericite indicated that the sericite has better crystallinity compared to illite. These experimental results suggested that sericitization processes of illite can decline the sorption capabilities of illite for cesium under various hydrothermal conditions. In particular, weathering experiments raised the cesium sorption to illite, which seems to be related to the increase of preferential sorption sites for cesium through crystallinity destruction

  6. Architectural design of passive solar residential building

    Directory of Open Access Journals (Sweden)

    Ma Jing

    2015-01-01

    Full Text Available This paper studies thermal environment of closed balconies that commonly exist in residential buildings, and designs a passive solar residential building. The design optimizes the architectural details of the house and passive utilization of solar energy to provide auxiliary heating for house in winter and cooling in summer. This design might provide a more sufficient and reasonable modification for microclimate in the house.

  7. Sorption of microamount of colloidal silver iodide on hydrated iron(III) oxide

    International Nuclear Information System (INIS)

    Kepak, F.; Nova, J.

    1975-01-01

    Sorption of a microamount of colloidal silver iodide labelled with 131 I on hydrated iron/III/ oxide suspension was studied. The sorption dependence upon pH, sorbent amount, and inert electrolyte concentration has revealed that sorption of silver iodide reaches no more than 63%. The sorption lasted one hour during which the maximum value was reached. Desorption time was one hour, as well. Except for measuring the sorption dependence on pH, the sorption pH was 7.0, temperature 24+-2 0 C. (F.G.)

  8. The 1986 residential occupant survey

    Energy Technology Data Exchange (ETDEWEB)

    Ivey, D.L.; Alley, P.K.

    1987-04-01

    In 1986, Pacific Northwest Laboratory developed the Residential Occupant Survey-Spring '86, which was implemented. The overall purpose of the study was to collect demographic, attitudinal, and behavioral data related to the use and conservation of electricity in dwellings participating in the Bonneville Power Administration's End-Use Load and Conservation Assessment Program (ELCAP). Information was collected on the respondents' perceptions of the energy efficiency of their dwelling, temperature the dwelling was kept when people were at home and awake during the last heating season, which rooms, if any, were not heated during the last heating season, number of times the dwelling was unoccupied for at least one week, number of times pets were let out of the dwelling per day, attitudes toward energy use and conservation and several socio-demographic variables such as age, sex, and total household income. The results of the data analyses showed age to be an important factor for reported indoor temperature and perceived energy efficiency of the dwelling. The results also showed that almost 60% of the ELCAP occupants do not heat one or more rooms during the heating season, and almost 45% of the ELCAP dwellings were unoccupied for at least one week during the reporting period. In terms of the reported allocation of household income for household energy expenses, the results showed that the reported dollar amount spent for the expenses remained relatively constant over income levels.

  9. Sorption of tetracycline on organo-montmorillonites

    International Nuclear Information System (INIS)

    Liu, Niu; Wang, Ming-xia; Liu, Ming-ming; Liu, Fan; Weng, Liping; Koopal, Luuk K.; Tan, Wen-feng

    2012-01-01

    Highlights: ► The sorption capacity of tetracycline on Mont. modified with QACs was highly promoted. ► Tetracycline adsorbed on organoclay was affected by the amount and the length of QACs. ► Tetracycline adsorption on organoclay exhibited high pH-dependence below 5. - Abstract: Tetracycline (TC) is a veterinary antibiotic that is frequently detected as pollutant in the environment. Powerful adsorbents are required for removing TC. The present paper compares the TC adsorption capacity of Na-montmorillonite (Na-mont) with six organo-montmorillonites (organo-monts). Three quaternary ammonium cations (QACs) with different alkyl-chain lengths were used as modifiers. Powder X-ray diffraction indicated that the d 001 values of organo-monts increased with increasing the QACs loading and alkyl-chain length. The CECs of the organo-monts were substantially lower than that of Na-mont and decreased with QACs chain length and increased loading. The modeling of the adsorption kinetics revealed that the processes of TC adsorption on the tested samples could be well fitted by the pseudo-second-order equation. The maximum adsorption capacities of TC on the organo-monts (1000–2000 mmol/kg) were considerably higher than that on Na-mont (769 mmol/kg). Both the Langmuir and Freundlich model could fit the adsorption isotherms. The TC adsorption to the organo-monts increase significantly with decreasing the pH below 5.5 because of the electrostatic interaction, and a high QACs loading performed better than a low loading at around pH 3.

  10. Calcium silicate hydrate: Crystallisation and alkali sorption

    International Nuclear Information System (INIS)

    Hong, S.

    2000-01-01

    Homogeneous single C-S-H gels has been prepared for the investigation of alkali binding potential and crystallisation. A distribution coefficient, R d , was introduced to express the partition of alkali between solid and aqueous phases at 25 deg. C. R d is independent of alkali hydroxide concentration and depends only on Ca:Si ratio over wide ranges of alkali concentration. The trend of numerical values of R d indicates that alkali bonding into the solid improves as its Ca:Si ratio decreases. Reversibility is demonstrated, indicating a possibility of constant R d value of the material. Al has been introduced to form C-A-S-H gels and their alkali sorption properties also determined. Al substituted into C-S-H markedly increases R d , indicating enhancement of alkali binding. However, the dependence of R d on alkali concentration is non-ideal with composition. A two-site model for bonding is presented. Crystallisation both under saturated steam and 1 bar vapour pressure has been investigated. It has been shown that heat treatment by saturated steam causes crystallisation of gels. The principal minerals obtained were (i) C-S-H gel and Ca(OH) 2 at -55 deg. C, (ii) 1.1 nm tobermorite, jennite and afwillite at 85 -130 deg. C, and (iii) xonotlite, foshagite and hillebrandite at 150-180 deg. C. Properties of crystalline C-S-H were also reported for reversible phase transformation, pH conditioning ability, seeding effect and solubility. At 1 bar pressure, crystallisation is slower than in saturated steam due to lower water activity. Tobermorite-like nanodomains develop during reaction at low Ca/Si ratios. In some Ca-rich compositions, Ca(OH) 2 is exsolved and occurs as nano-sized crystallites. (author)

  11. Heat cascading regenerative sorption heat pump

    Science.gov (United States)

    Jones, Jack A. (Inventor)

    1995-01-01

    A simple heat cascading regenerative sorption heat pump process with rejected or waste heat from a higher temperature chemisorption circuit (HTCC) powering a lower temperature physisorption circuit (LTPC) which provides a 30% total improvement over simple regenerative physisorption compression heat pumps when ammonia is both the chemisorbate and physisorbate, and a total improvement of 50% or more for LTPC having two pressure stages. The HTCC contains ammonia and a chemisorbent therefor contained in a plurality of canisters, a condenser-evaporator-radiator system, and a heater, operatively connected together. The LTPC contains ammonia and a physisorbent therefor contained in a plurality of compressors, a condenser-evaporator-radiator system, operatively connected together. A closed heat transfer circuit (CHTC) is provided which contains a flowing heat transfer liquid (FHTL) in thermal communication with each canister and each compressor for cascading heat from the HTCC to the LTPC. Heat is regenerated within the LTPC by transferring heat from one compressor to another. In one embodiment the regeneration is performed by another CHTC containing another FHTL in thermal communication with each compressor. In another embodiment the HTCC powers a lower temperature ammonia water absorption circuit (LTAWAC) which contains a generator-absorber system containing the absorbent, and a condenser-evaporator-radiator system, operatively connected together. The absorbent is water or an absorbent aqueous solution. A CHTC is provided which contains a FHTL in thermal communication with the generator for cascading heat from the HTCC to the LTAWAC. Heat is regenerated within the LTAWAC by transferring heat from the generator to the absorber. The chemical composition of the chemisorbent is different than the chemical composition of the physisorbent, and the absorbent. The chemical composition of the FHTL is different than the chemisorbent, the physisorbent, the absorbent, and ammonia.

  12. Sorption Properties of Aerogel in Liquid Nitrogen

    Science.gov (United States)

    Johnson, Wesley L.

    2006-01-01

    Aerogel products are now available as insulation materials of the future. The Cryogenics Test Laboratory at the NASA Kennedy Space Center is developing aerogel-based thermal insulation systems for space launch applications. Aerogel beads (Cabot Nanogel ) and aerogel blankets (Aspen Aerogels Spaceloft ) have outstanding ambient pressure thermal performance that makes them useful for applications where sealing is not possible. Aerogel beads are open-celled silicone dioxide and have tiny pores that run throughout the body of the bead. It has also recently been discovered that aerogel beads can be used as a filtering device for aqueous compounds at room temperature. With their hydrophobic covering, the beads absorb any non-polar substance and they can be chemically altered to absorb hot gases. The combination of the absorption and cryogenic insulating properties of aerogel beads have never been studied together. For future cryogenic insulation applications, it is crucial to know how the beads react while immersed in cryogenic liquids, most notably liquid nitrogen. Aerogel beads in loose-fill situation and aerogel blankets with composite fiber structure have been tested for absorption properties. Depending on the type of aerogel used and the preparation, preliminary results show the material can absorb up to seven times its own weight of liquid nitrogen, corresponding to a volumetric ratio of 0.70 (unit volume nitrogen per unit volume aerogel). These tests allow for an estimate on how much insulation is needed in certain situations. The theory behind the different processes of sorption is necessary for a better understanding of the preparation of the beads before they are used in an insulation system.

  13. Improved hydrogen sorption kinetics in wet ball milled Mg hydrides

    Energy Technology Data Exchange (ETDEWEB)

    Meng, Li

    2011-05-04

    In this work, wet ball milling method is used in order to improve hydrogen sorption behaviour due to its improved microstructure of solid hydrogen materials. Compared to traditional ball milling method, wet ball milling has benefits on improvement of MgH{sub 2} microstructure and further influences on its hydrogen sorption behavior. With the help of solvent tetrahydrofuran (THF), wet ball milled MgH{sub 2} powder has much smaller particle size and its specific surface area is 7 times as large as that of dry ball milled MgH{sub 2} powder. Although after ball milling the grain size is decreased a lot compared to as-received MgH{sub 2} powder, the grain size of wet ball milled MgH{sub 2} powder is larger than that of dry ball milled MgH{sub 2} powder due to the lubricant effect of solvent THF during wet ball milling. The improved particle size and specific surface area of wet ball milled MgH{sub 2} powder is found to be determining its hydrogen sorption kinetics especially at relatively low temperatures. And it also shows good cycling sorption behavior, which decides on its industrial applicability. With three different catalysts MgH{sub 2} powder shows improved hydrogen sorption behavior as well as the cyclic sorption behavior. Among them, the Nb{sub 2}O{sub 5} catalyst is found to be the most effective one in this work. Compared to the wet ball milled MgH{sub 2} powder, the particle size and specific surface area of the MgH{sub 2} powder with catalysts are similar to the previous ones, while the grain size of the MgH{sub 2} with catalysts is much finer. In this case, two reasons for hydrogen sorption improvement are suggested: one is the reduction of the grain size. The other may be as pointed out in some literatures that formation of new oxidation could enhance the hydrogen sorption kinetics, which is also the reason why its hydrogen capacity is decreased compared to without catalysts. After further ball milling, the specific surface area of wet ball milled Mg

  14. Sorption-desorption behavior of polybrominated diphenyl ethers in soils

    International Nuclear Information System (INIS)

    Olshansky, Yaniv; Polubesova, Tamara; Vetter, Walter; Chefetz, Benny

    2011-01-01

    Polybrominated diphenyl ethers (PBDEs) are flame retardants that are commonly found in commercial and household products. These compounds are considered persistent organic pollutants. In this study, we used 4,4'-dibromodiphenyl ether (BDE-15) as a model compound to elucidate the sorption and desorption behavior of PBDEs in soils. The organic carbon-normalized sorption coefficient (K OC ) of BDE-15 was more than three times higher for humin than for bulk soils. However, pronounced desorption hysteresis was obtained mainly for bulk soils. For humin, increasing concentration of sorbed BDE-15 resulted in decreased desorption. Our data illustrate that BDE-15 and probably other PBDEs exhibit high sorption affinity to soils. Moreover, sorption is irreversible and thus PBDEs can potentially accumulate in the topsoil layer. We also suggest that although humin is probably a major sorbent for PBDEs in soils, other humic materials are also responsible for their sequestration. - Highlights: → BDE-15 exhibited pronounced desorption hysteresis. → BDE-15 sowed higher sorption affinity to humin as compared to the bulk soils. → Sequestration of PBDEs depends on soil organic matter constitutes other than humin. - Pronounced desorption hysteresis was observed for BDE-15 in natural soils.

  15. Study of sorption processes of strontium on the synthetic hydroxyapatite

    International Nuclear Information System (INIS)

    Rosskopfova, O.; Galambos, M.; Rajec, P.

    2011-01-01

    The sorption of strontium on synthetic hydroxyapatite was investigated using batch method and radiotracer technique. The hydroxyapatite samples were prepared by a wet precipitation process followed by calcination of calcium phosphate that precipitated from aqueous solution. Also, commercial hydroxyapatites were used. The sorption of strontium on hydroxyapatite depended on the method of preparation and it was pH independent ranging from 4 to 9 as a result of buffering properties of hydroxyapatite. The distribution coefficient K d was significantly decreased with increasing concentration of Sr 2+ and Ca 2+ ions in solution with concentration above 1 x 10 -3 mol dm -3 . The percentage strontium sorption for commercial and by wet method prepared hydroxyapatite was in the range of 83-96%, while calcined hydroxyapatite was ranging from 10 to 30%. The experimental data for sorption of strontium have been interpreted in the term of Langmuir isotherm. The sorption of Sr 2+ ions was performed by ion-exchange with Ca 2+ cations on the crystal surface of hydroxyapatite. Although calcined hydroxyapatite is successfully used as biomaterial for hard tissues repair, it is not used for the treatment of liquid wastes. (author)

  16. Sorption and desorption of indaziflam degradates in several agricultural soils

    Directory of Open Access Journals (Sweden)

    Diego Gonçalves Alonso

    2016-04-01

    Full Text Available ABSTRACT Processes regulating pesticide fate in the environment are influenced by the physicochemical properties of pesticides and soils. Sorption and desorption are important processes as they regulate the movement of pesticides in soil. Although sorption-desorption is widely studied for herbicides, studies involving their metabolites in soil are scarce. Sorption and desorption of indaziflam metabolites (indaziflam-triazinediamine (FDAT, indaziflam-triazine-indanone (ITI and indaziflam-carboxilic acid (ICA were investigated in six Brazilian (BRA soils and three United States (USA soils with different physicochemical properties. The Freundlich equation described sorption of the metabolites for all soils (R2 > 0.98; 1/n ~ 1. Sorption order (Kf was ITI > ICA > FDAT. Mean values of Kf,oc were 453, 289, and 81 (BRA and 444, 48, and 48 (USA for metabolites ITI, ICA, and FDAT respectively. Desorption was hysteretic for all metabolites in all soils. These results suggest that these metabolites fall in the classification range of mobile to moderately mobile in soils.

  17. INFLUENCES OF SOIL PROPERTIES ON CHROMIUM (III SORPTION

    Directory of Open Access Journals (Sweden)

    R. Salmasi, F. Salmasi

    2007-07-01

    Full Text Available Soil adsorbing properties reduce sorption ability of the metal, which in turn may influence decision for remediation at contaminated sites. The objective of this study is presentation of a model based on soil properties to estimate the sorption of Cr(III in chromium contaminated soils. Twenty uncontaminated soil samples, with properties similar to the contaminated soils were selected from around of city of Tabriz and treated with Cr as CrCl3. A multiple regression analysis with statgraph software was used to drive an expression that related Cr sorption to common soil properties. The results showed that four soil properties were important in determining the amount of Cr adsorbed by the soils including pH, cation exchange capacity, total inorganic carbon and clay content with nearly 80% variability in Cr sorption and a reasonable level of confidence by this model. The obtained model suggested that Cr(III sorption was enhanced by higher soil pH, more total inorganic carbon, more clay, and higher cation exchange capacity.

  18. Sorption characteristics of radioactive cesium and strontium on smectite

    International Nuclear Information System (INIS)

    Ohnuki, Toshihiko; Kozai, Naofumi

    1994-01-01

    Sorption of 137 Cs and 85 Sr on smectite has been studied by combining sorption and desorption experiments. In the desorption experiments, the 137 Cs and 85 Sr were desorbed from the smectite by 0.1 N different desorption reagents solution of Li + , Na + , K + , Rb + , Cs + , Mg 2+ , Ca 2+ and Ba 2+ . The effects of Cs and Sr concentrations on sorption were examined by desorption experiments using 1 N KCl as a desorption reagent over a Cs and Sr concentrations range from 10 -8 to 1 N (saturated). All of Sr sorbed was desorbed with a 1 N KCl solution over Sr concentrations range of 10 -8 and 1 M. Approximately 50% of the 137 Cs sorbed at a concentration of 10 -8 M was desorbed with a 1 N KCl solution, and the fraction desorbed increased with increasing a Cs concentration. These results show that all Sr was reversibly sorbed on smectite, and a fraction of Cs was irreversibly sorbed on smectite. Thus, smectite has reversible sorption sites for Sr and both reversible and irreversible sorption sites for Cs. The fractions of Sr desorbed were related to the products of an ionic radius and charge of a desorption reagent, and those of Cs were related to the hydration energy. These results suggest that sorbed Sr and Cs reversibly on smectite form hydrated and dehydrated ions, respectively. (orig.)

  19. Comparative study about hydrogen sorption in sponge and powder titanium

    International Nuclear Information System (INIS)

    Vasut, Felicia; Preda, Anisoara; Zamfirache, Marius; Ducu, Catalin; Malinovschi, Viorel

    2005-01-01

    Currently, hydrogen may be stored as a compressed gas or a cryogenic liquid. Neither method appears to be practical for many applications in which hydrogen use would otherwise be attractive. For example, gaseous storage of stationary fuel is not feasible because of the large volume or weight of the storage vessels. Liquid hydrogen could be use extensively but the liquefaction process is relatively expensive. The hydrogen can be stored for a long term with a high separation factor, as a solid metal hydride. Using hydride-forming metals and intermetallic compounds, for example, recovery, purification and storage of heavy isotopes in tritium containing system, can solve many problems arising in the nuclear-fuel cycle. The paper presents a comparative study about hydrogen sorption on two titanium structures: powder and sponge. Also, it is presented the characterization, by X-Ray diffraction, of two structures, before and after sorption process. From our results, one can conclude that sorption method is efficient for both samples. Kinetic curves indicates that sorption rate for titanium powder is lower than for sponge titanium. This is the effect of reaction surface, which is larger for powder titanium. Sorption capacity for hydrogen is lower in powder titanium for identical experimental conditions. The difference between storage capacities could be explained by activation temperature, which was lower for titanium powder than for sponge. (authors)

  20. Sorption of Emerging Organic Wastewater Contaminants to Four Soils

    Directory of Open Access Journals (Sweden)

    Sarah Roberts

    2014-04-01

    Full Text Available Conventional onsite wastewater treatment system design relies on a septic tank and soil treatment unit (STU for treatment of wastewater and integration of the final effluent into the environment. Organic water contaminants (OWCs, chemicals found in pharmaceutical drugs, detergents, surfactants, and other personal care and cleaning products, have been observed in septic tank effluent and the environment. Sorption of OWC mass to soil is a key mechanism in the removal and retardation of many of these chemicals in effluent as it travels through an STU. The primary purpose of this study was to investigate the relationship between the fraction of organic carbon of soil and the equilibrium sorption partitioning coefficient of a selected group of relevant and diverse OWCs. A secondary goal is to evaluate current methods of modeling the sorption of selected OWCs in soil. Five point Freundlich isotherms were constructed from equilibrium sorption batch tests for target OWCs with four different soils. For soils with organic carbon fraction between 0.021 and 0.054, Kd values were calculated between 60 and 185 for 4-nonylphenol, 75 to 260 for triclosan, 115 to 270 for bisphenol-A, 3 to 255 for 17β-estradiol, 40 to 55 for 17α-ethynylestradiol, and 28 to 70 for estrone. An empirically derived, direct relationship between foc and Kd may be a useful approach to estimating sorption for a soil based on organic carbon content.

  1. Sorption behaviour of well-defined oxidation states

    International Nuclear Information System (INIS)

    Allard, B.; Olofsson, U.; Torstenfelt, B.; Kipatsi, H.

    1983-05-01

    The sorption of the actinides Am(III), Th(IV), Np(V), Pa(V), U(VI) and Pu has been studied as a function of pH (2-12) for two nuclide concentrations (10 -7 -10 -9 M) (only one for Pa and U) in the systems Al 2 0 3 - 0.01 M NaCl0 4 and Si0 2 - 0.01 M NaCl0 4 . Distribution coefficients have been determined by a batch technique after various contact times (6h - 6w) at constant temperature (25degreeC) in systems equilibrated with air. The observed sorption behaviour indicates a predominantly physical adsorption mechanism, where pH of the aqueous phase is the principal chemical parameter of influence. The sorption is highly related to the degree of hydrolysis, with a maximum in the pH-region where neutral species dominate and with a reduction of the sorption under conditions when anionic species (hydroxides or carbonates) would exist in solution. This is particularly the case for U(VI) at pH above 7-8 when anionic carbonate complexes would be formed. Plutonium is predominantly tetravalent under the present conditions, as indicated by the sorption behaviour. (authors)

  2. Effects of organic degradation products on the sorption of actinides

    International Nuclear Information System (INIS)

    Baston, G.M.N.; Berry, J.A.; Bond, K.A.; Brownsword, M.; Linklater, C.M.

    1992-01-01

    Previous work has shown that products from the chemical degradation of cellulosic matter can significantly reduce sorption of uranium(VI) and plutonium(IV) on geological materials. Uranium(IV) batch sorption experiments have now been performed to study the effect of organic degradation products in a reducing environment. Thorium(IV) sorption has also been studied since thorium is an important radioelement in its own right and has potential use as a simulant for other tetravalent actinides. Sorption onto London clay, Caithness flagstones and St. Bees sandstone was investigated. Experimental conditions were chosen to simulate both those expected close to cementitious repository (pH ∝ 11) and at the edge of the zone of migration of the alkaline plume (pH ∝ 8). Work was carried out with both authentic degradation products and with gluconate, acting as a well-characterized simulant for cellulosic degradation products. The results show that the presence of organic species can cause a reduction in sorption. This is especially so in the presence of a high concentration of gluconate ions, but the reduction is significantly less with authentic degradation products. (orig.)

  3. Effects of organic degradation products on the sorption of actinides

    Energy Technology Data Exchange (ETDEWEB)

    Baston, G.M.N.; Berry, J.A.; Bond, K.A.; Brownsword, M.; Linklater, C.M. (AEA Decommissioning and Radwaste, Harwell Lab. (United Kingdom))

    1992-01-01

    Previous work has shown that products from the chemical degradation of cellulosic matter can significantly reduce sorption of uranium(VI) and plutonium(IV) on geological materials. Uranium(IV) batch sorption experiments have now been performed to study the effect of organic degradation products in a reducing environment. Thorium(IV) sorption has also been studied since thorium is an important radioelement in its own right and has potential use as a simulant for other tetravalent actinides. Sorption onto London clay, Caithness flagstones and St. Bees sandstone was investigated. Experimental conditions were chosen to simulate both those expected close to cementitious repository (pH [proportional to] 11) and at the edge of the zone of migration of the alkaline plume (pH [proportional to] 8). Work was carried out with both authentic degradation products and with gluconate, acting as a well-characterized simulant for cellulosic degradation products. The results show that the presence of organic species can cause a reduction in sorption. This is especially so in the presence of a high concentration of gluconate ions, but the reduction is significantly less with authentic degradation products. (orig.).

  4. Sorption of uranium and cesium by Hanford basalts and associated secondary smectite

    International Nuclear Information System (INIS)

    Ames, L.L.; McGarrah, J.E.; Walker, B.A.; Salter, P.F.

    1982-01-01

    Three characterized basalts and an associated secondary smectite were used in comparative uranium and cesium sorption studies. Experiments utilizing two synthetic characteristic basalt groundwaters at 23 and 60 0 C allowed comparison of increased temperature and carbonate concentration effects on Cs and U sorption. The sorption data were fitted to the Dubinin-Radushkevich (D-R) isotherm, and loading maxima and energetics derived. An increase in temperature caused a decrease in Cs sorption maxima on all solids from all groundwaters studied and an increase in U sorption maxima, especially from the higher-carbonate-content groundwater. Sorption energies were characteristic of ion exchange for both Cs and U sorption processes. Basalt U sorption maxima were relatively insignificant, but smectite U sorption maxima surpassed Cs sorption maxima in both groundwaters at 60 0 C. The uranyl carbonate complexes thus may be relatively temperature-sensitive. Upon removal of excess Fe-oxides from the secondary smectite, U sorption decreased and the D-R isotherm reverted to a normal Freundlich sorption isotherm. Removal of excess Fe-oxides from the basalts and secondary smectite would probably result in Freundlich sorption isotherms for both Cs and U. (Auth.)

  5. Sorption of humic acid to functionalized multi-walled carbon nanotubes

    International Nuclear Information System (INIS)

    Wang, Fei; Yao, Jun; Chen, Huilun; Yi, Zhengji; Xing, Baoshan

    2013-01-01

    The environmental behavior of carbon nanotubes (CNTs) and humic acid (HA) is a prominent concern, but effect of functionalities on their sorption is not clear yet. Functionalized multi-walled CNTs (MCNT15) and HA were used to study their sorption behavior. Sorption rate of HA to MCNTs was dominantly controlled by its diffusion from liquid-MCNT boundary to MCNT surfaces. The sorption is in the sequence of MCNT15 > MCNT15-NH 2 > MCNT15-OH > MCNT15-COOH > MCNT15-Ni, which was dependent on their surface area and meso- and macro-pore volume. The functionalities of MCNTs regulated the sorption by affecting their interaction mechanisms (i.e., H-bonding, π–π, and hydrophobic interaction). Additionally, the amount of these functionalities on the MCNT surface reduced indirectly the sorption sites due to the steric hindrance. Electrostatic repulsion deceased the sorption of HA by MCNTs with increasing pH. This study demonstrated the importance of functionalities on the MCNTs for the sorption of HA. -- Highlights: •HA sorption kinetics was well fitted using Lagergren pseudo second-order model. •Sorption rate of HA was controlled by diffusion from liquid-MCNT boundary to MCNT surfaces. •Sorption was dependent on their surface area and meso- and macro-pore volume. •Functionalities of MCNTs regulated the sorption by affecting interaction mechanisms. -- The functionalities of MCNTs regulated the sorption behavior between MCNTs and HA

  6. Study on sorption capacity of synthetic zeolite for simulated nuclide Cs+

    International Nuclear Information System (INIS)

    Wang Jinming; Yi Facheng

    2006-01-01

    For the sake of understanding the functionary order of simulated nuclide Cs + and Synthetic Zeolite (ZF), the sorption equilibrium time and sorption capacity of simulated nuclide Cs + on ZF are studied with the intermittence method. The difference of temperature, pH value, Cs + concentration and medium on sorption capacity and sorption ratio are investigated. The results show that the sorption complexion of simulated nuclide Cs + on ZF in the same concentration solution are sorption equilibrium quantity in range of 155-190 mg/g in different temperatures and that in range of 165-190 mg/g in different pH values and that in range of 120-210 mg/g in different media; and changing order of equilibrium adsorption ratio is the same to that of sorption equilibrium quantity, but their changing range are wider than that of sorption equilibrium quantity; equilibrium adsorption quantity in range of 180-380 mg/g in different concentration solutions, and changing order of equilibrium adsorption ratio is opposite to that of sorption equilibrium quantity, and more-over, their changing range are wider than that of the sorption equilibrium quantity. Sorption equilibrium time of simulated nuclide Cs + on ZF is about ten to fifteen days. So the changing range of sorption capacity of simulated nuclide Cs + on ZF with conditions effects is smaller and the sorption equilibrium time is also less and ZF preferably absorbs Cs in radiation wastes and thus consumedly reduces the effect of radwaste on the environment. (authors)

  7. Differences between Residential and Non-Residential Fathers on Sexual Socialisation of African American Youth

    Science.gov (United States)

    Sneed, Carl D.; Willis, Leigh A.

    2016-01-01

    This study investigated differences between residential and non-residential fathers on topics discussed during father-child sex communication and factors associated with child sexual socialisation. Young people (N = 159, 53% female) provided self-reports using computer surveys on the role of their fathers on father-child sex communication, general…

  8. Post-Retrofit Residential Assessments

    Energy Technology Data Exchange (ETDEWEB)

    Lancaster, Ross; lutzenhiser, Loren; Moezzi, Mithra; Widder, Sarah H.; Chandra, Subrato; Baechler, Michael C.

    2012-04-30

    This study examined a range of factors influencing energy consumption in households that had participated in residential energy-efficiency upgrades. The study was funded by a grant from the U.S. Department of Energy’s Pacific Northwest National Laboratory and was conducted by faculty and staff of Portland State University Center for Urban Studies and Department of Economics. This work was made possible through the assistance and support of the Energy Trust of Oregon (ETO), whose residential energy-efficiency programs provided the population from which the sample cases were drawn. All households in the study had participated in the ETO Home Performance with Energy Star (HPwES) program. A number of these had concurrently pursued measures through other ETO programs. Post-retrofit energy outcomes are rarely investigated on a house-by-house basis. Rather, aggregate changes are ordinarily the focus of program impact evaluations, with deviation from aggregate expectations chalked up to measurement error, the vagaries of weather and idiosyncrasies of occupants. However, understanding how homes perform post-retrofit on an individual basis can give important insights to increase energy savings at the participant and the programmatic level. Taking a more disaggregated approach, this study analyzed energy consumption data from before and after the retrofit activity and made comparisons with engineering estimates for the upgrades, to identify households that performed differently from what may have been expected based on the estimates. A statistical analysis using hierarchal linear models, which accounted for weather variations, was performed looking separately at gas and electrical use during the periods before and after upgrades took place. A more straightforward comparison of billing data for 12-month periods before and after the intervention was also performed, yielding the majority of the cases examined. The later approach allowed total energy use and costs to be

  9. Sorption behavior of thorium onto montmorillonite and illite

    International Nuclear Information System (INIS)

    Iida, Yoshihisa; Barr, Logan; Yamaguchi, Tetsuji; Hemmi, Ko

    2016-01-01

    Thorium (Th)-229 is one of the important radionuclides for the performance assessment calculations for high-level radioactive waste repositories. The sorption behavior of Th onto montmorillonite and illite were investigated by batch sorption experiments. Experiments were carried out under variable pH and carbonate concentrations. The sorbability of montmorillonite was higher than that of illite. Distribution coefficients, K d (m 3 kg -1 ), decreased with increased carbonate concentrations and showed the minimal value at around pH 10. The sorption behaviors of Th were analyzed by the non-electrostatic surface complex model with PHREEQC computer program. The model calculations were able to explain the experimental results reasonably well. The decreases of K d was likely due to the stabilization of aqueous species by hydroxo-carbonate complexations in the solutions. (author) [ja

  10. Sorption of tritium and tritiated water on construction materials

    International Nuclear Information System (INIS)

    Dickson, R.S.; Miller, J.M.

    1991-11-01

    Sorption and desorption of tritium (HT) and tritiated water (HTO) on materials to be used in the construction of fusion facilities were studied. In ∼ 24-hour exposures in argon or room air, metal samples sorbed 8-200 μCi/m 2 of tritium from atmospheres of 5-9 Ci/m 3 HT, and non-metallic samples sorbed 60-800 μCi/m 2 from atmospheres of 14 Ci/m 3 HT. Sorption of HTO varied much more widely than HT sorption for different samples, ranging from 4 μCi/m 2 for glass to 1,300,000 μCi/m 2 for concrete samples, in 24-hour exposures to 1 Ci/m 3 HTO in room air. Time dependence of desorption in dry air showed a rapid initial process and a slower secondary process. (Author) (10 refs., 4 figs., 2 tabs.)

  11. Dinamics of BF3 sorption on activated carbons

    International Nuclear Information System (INIS)

    Polevoj, A.S.; Petrenko, A.E.

    1989-01-01

    The dynamics of BF 3 sorption on BAUAG-3 and SKT-4A carbons is studied by recording the curve of BF 3 concentration change in time at the outlet from the column filled with activated carbon when blowing it with a current of BF 3 and helium mixture. The effect of sorbent type, temperature and pressure of the gaseous mixture, BF 3 content in it and its partial pressure, BF 3 consumption on the width of sorption zone is studied. The results of studies can be used to calculate and optimize the conditions of sorption processes connected with the absorption of BF 3 by carbons from the gaseous flows in the dynamic mode

  12. Mathematical modelling of the sorption isotherms of quince

    Directory of Open Access Journals (Sweden)

    Mitrevski Vangelce

    2017-01-01

    Full Text Available The moisture adsorption isotherms of quince were determined at four temperatures 15, 30, 45, and 60°C over a range of water activity from 0.110 to 0.920 using the standard static gravimetric method. The experimental data were fitted with generated three parameter sorption isotherm models on Mitrevski et al., and the referent Anderson model known in the scientific and engineering literature as Guggenheim- Anderson-de Boer model. In order to find which models give the best results, large number of numerical experiments was performed. After that, several statistical criteria for estimation and selection of the best sorption isotherm model was used. The performed statistical analysis shows that the generated three parameter model M11 gave the best fit to the sorption data of quince than the referent three parameter Anderson model.

  13. Autoradiographic studies of actinide sorption in groundwater systems

    International Nuclear Information System (INIS)

    O'Kelley, G.D.; Beall, G.W.; Allard, B.

    1980-01-01

    Autoradiography is a convenient and sensitive technique for the study of spacial distributions of alpha radioactive nuclides on slabs of rock or on other planar surfaces. The autoradiographic camera contains an arrangement for placing in firm contact Polaroid sheet film, a plastic scintillator screen, and the radioactive face of the specimen. As an example of the use of the autoradiographic method, a series of sorption experiments were carried out in which synthetic groundwater solutions of americium, neptunium, uranium, and plutonium were contacted with Climax Stock granite under aerated and anoxic conditions at pH 8 to 9. The sorption observed at specific mineral sites was correlated with data on sorption of these actinides on pure minerals

  14. Radionuclide and metal sorption on cement and concrete

    CERN Document Server

    Ochs, Michael; Wang, Lian

    2016-01-01

    Cementitious materials are being widely used as solidification/stabilisation and barrier materials for a variety of chemical and radioactive wastes, primarily due to their favourable retention properties for metals, radionuclides and other contaminants. The retention properties result from various mineral phases in hydrated cement that possess a high density and diversity of reactive sites for the fixation of contaminants through a variety of sorption and incorporation reactions. This book presents a state of the art review and critical evaluation of the type and magnitude of the various sorption and incorporation processes in hydrated cement systems for twenty-five elements relevant for a broad range of radioactive and industrial wastes. Effects of cement evolution or ageing on sorption/incorporation processes are explicitly evaluated and quantified. While the immobilisation of contaminants by mixing-in during hydration is not explicitly addressed, the underlying chemical processes are similar. A quantitativ...

  15. Sorption of americium and neptunium by deep-sea sediments

    International Nuclear Information System (INIS)

    Higgo, J.J.W.; Rees, L.V.C.; Cronan, D.S.

    1983-01-01

    The sorption and desorption of americium and neptunium by a wide range of deep-sea sediments from natural sea water at 4 0 C has been studied using a carefully controlled batch technique. All the sediments studied should form an excellent barrier to the migration of americium since distribution coefficients were uniformly greater than 10 5 and the sorption-desorption reaction may not be reversible. The sorption of neptunium was reversible and, except for one red clay, the distribution coefficients were greater than 10 3 for all the sediments investigated. Nevertheless the migration of neptunium should also be effectively retarded by most deep-sea sediments even under relatively oxidizing conditions. The neptunium in solution remained in the V oxidation state throughout the experiments. Under the experimental conditions used colloidal americium was trapped by the sediment and solubility did not seem to be the controlling factor in the desorption of americium. (Auth.)

  16. Sorption Energies for Atrazine onto Devolatalized Vitellaria paradoxa

    International Nuclear Information System (INIS)

    Itodo, A. U.; Abdulrahman, F. W.; Hassan, L. G.; Happiness, U. I.

    2012-01-01

    We utilize isotherm models in contributing to scholarly knowledge in simple terms, to measure the forces or energy defining certain adsorption phenomenon. Gas Chromatography coupled with Mass Spectrophotometer detector was utilized to measure equilibrium phase atrazine after adsorption onto Shea nut Shells acid derived activated carbon. Data were fitted into the D-R and Temkin isotherm relationships for energy data estimation of Sorption energy value (B D ), mean free energy (E D ) and heat of sorption (B). They were estimated as 0.7600mol 2 KJ -2 , 0.8111 kjmor -1 and 0.790Jmol -1 respectively. The parameter predicting the type of adsorption was evaluated B D , B D 2 = 0.979 proves a better choice in explaining sorption energies. Generally, shea nut shells can be used as alternative precursors for activated carbon production via the two steps and acid treatment method.

  17. Sorption-desorption of radiocesium interception potential in tropical soils

    International Nuclear Information System (INIS)

    Roque, Mario L.; Boaretto, Rodrigo M.; Boaretto, Antonio E.; Smolders, Erik E.T.

    2000-01-01

    A study of sorption of radiocaesium in soils of tropical climate (Brazil) was carried. The values of definitive fixation of the radiocaesium were determined by analytic methodology of sorption-desorption and the availability to plants were calculated by the determination of radiocesium interception potential (RIP). The values of sorption varied from 1,2 to 74,8% and the fixation varied from 3,2% to 32,2%. The results shown that the radiocaesium did remain adsorbed mainly to the frayed edge site. The low values of interception potential and definitive fixation demonstrated high capacity of the tropical soils in disposal the radionuclide for the solution and, consequently, to plants. (author)

  18. Sorption behaviour of caesium on a bentonite sample

    International Nuclear Information System (INIS)

    Hurel, C.; Marmier, N.; Fromage, F.; Seby, F.; Bourg, A.C.M.; Giffaut, E.

    2002-01-01

    Sorption of elements like Cs on clay is one of the principal processes delaying their release from deep repositories of nuclear wastes into the environment. The sorption processes taking place between non-purified natural clay material (bentonite) and synthetic groundwater (containing Ca, Mg, Na, K and carbonates) were therefore studied experimentally and modelled for Cs to determine whether thermodynamic computer codes capable of predicting the behaviour of this element in natural systems might be developed. The model used, based on the properties of a pure montmorillonite phase, incorporates the surface reactions for natural major ions and sorbing cations but does not have any adjustable parameters. The weight of each parameters used in the model is assessed. Surface reactions are classified as either major or minor, and a simplified model of Cs sorption that considers only the major processes is proposed. This simplified model might correspond to the less sophisticated thermodynamic model included in coupled geochemistry-transport models. (orig.)

  19. Investigation of strontium sorption on Kula volcanites treated with HCl

    International Nuclear Information System (INIS)

    Kuetahyali, C.; Cetinkaya, B.; Acar, M. B.; Isik, N. O.; Cireli, I.

    2009-01-01

    In planning the disposal of radioactive waste in a deep geologic repository, consideration must be given to the ways in which radionuclides might leave the repository and migrate through the geosphere. In performance assessment studies the uptake of the radioactive elements by rock formations play an important role in retarding their aqueous phase migration. Sorption studies of radionuclides have been conducted to obtain data on the distribution coefficient (K d ) that is as an input parameter in the performance assessment of the geological disposal of radioactive wastes. In many studies, the sorption experiments employed natural soils and rocks as sorbents. Adsorption experiments were studied in a batch adsorption system using Sr(NO 3 ) 2 (Merck) solution. Strontium sorption on Kula Volcanites treated with HCl was investigated. Central Composite Design Method was used in the experiments. Sr adsorption was studied as a function of pH, contact time, concentration of adsorbate, and temperature.

  20. Study of the sorption properties of the peat for removal of heavy metals

    International Nuclear Information System (INIS)

    Hayrapetyan, S.S.; Gevorgyan, S.A.; Hayrapetyan, L.S.; Bareghamyan, S.F.; Pirumyan, G.P.

    2016-01-01

    The processes of sorption of several heavy metals on peat samples taken from basin of lake Sevan (near Vardenis Gegharkunik region of Armenia) were investigated. The peat samples were taken from different locations from 1 m depth. The sorption processes have been done in the static mode. The peat samples were used without any modification, i.e. the sorption properties of natural raw peat were studied. The studies were conducted on the basis of synthetic solution containing ions of these following metals - Ni, Co, As, U, Ba. The sorption properties of peat were estimated by ICP-MS. Thus, peat can be a very effective sorption medium for removal of heavy metals from water. Most of them are absorbed in the first minutes of peat exposure to aqueous solution. For the sorption of barium, uranium, arsenic peat exhibits very high sorption efficiency. For comparison, their relative sorption values about 10 times more than those of cobalt, nickel and zinc.

  1. Sorption isotherms: A review on physical bases, modeling and measurement

    Energy Technology Data Exchange (ETDEWEB)

    Limousin, G. [Atomic Energy Commission, Tracers Technology Laboratory, 38054 Grenoble Cedex (France) and Laboratoire d' etude des Transferts en Hydrologie et Environnement (CNRS-INPG-IRD-UJF), BP 53, 38041 Grenoble Cedex (France)]. E-mail: guillaumelimousin@yahoo.fr; Gaudet, J.-P. [Laboratoire d' etude des Transferts en Hydrologie et Environnement (CNRS-INPG-IRD-UJF), BP 53, 38041 Grenoble Cedex (France); Charlet, L. [Laboratoire de Geophysique Interne et Techtonophysique - CNRS-IRD-LCPC-UJF-Universite de Savoie, BP 53, 38041 Grenoble Cedex (France); Szenknect, S. [Atomic Energy Commission, Tracers Technology Laboratory, 38054 Grenoble Cedex (France); Barthes, V. [Atomic Energy Commission, Tracers Technology Laboratory, 38054 Grenoble Cedex (France); Krimissa, M. [Electricite de France, Division Recherche et Developpement, Laboratoire National d' Hydraulique et d' Environnement - P78, 6 quai Watier, 78401 Chatou (France)

    2007-02-15

    The retention (or release) of a liquid compound on a solid controls the mobility of many substances in the environment and has been quantified in terms of the 'sorption isotherm'. This paper does not review the different sorption mechanisms. It presents the physical bases underlying the definition of a sorption isotherm, different empirical or mechanistic models, and details several experimental methods to acquire a sorption isotherm. For appropriate measurements and interpretations of isotherm data, this review emphasizes 4 main points: (i) the adsorption (or desorption) isotherm does not provide automatically any information about the reactions involved in the sorption phenomenon. So, mechanistic interpretations must be carefully verified. (ii) Among studies, the range of reaction times is extremely wide and this can lead to misinterpretations regarding the irreversibility of the reaction: a pseudo-hysteresis of the release compared with the retention is often observed. The comparison between the mean characteristic time of the reaction and the mean residence time of the mobile phase in the natural system allows knowing if the studied retention/release phenomenon should be considered as an instantaneous reversible, almost irreversible phenomenon, or if reaction kinetics must be taken into account. (iii) When the concentration of the retained substance is low enough, the composition of the bulk solution remains constant and a single-species isotherm is often sufficient, although it remains strongly dependent on the background medium. At higher concentrations, sorption may be driven by the competition between several species that affect the composition of the bulk solution. (iv) The measurement method has a great influence. Particularly, the background ionic medium, the solid/solution ratio and the use of flow-through or closed reactor are of major importance. The chosen method should balance easy-to-use features and representativity of the studied

  2. Sorption and desorption of carbamazepine from water by smectite clays.

    Science.gov (United States)

    Zhang, Weihao; Ding, Yunjie; Boyd, Stephen A; Teppen, Brian J; Li, Hui

    2010-11-01

    Carbamazepine is a prescription anticonvulsant and mood stabilizing pharmaceutical administered to humans. Carbamazepine is persistent in the environment and frequently detected in water systems. In this study, sorption and desorption of carbamazepine from water was measured for smectite clays with the surface negative charges compensated with K+, Ca2+, NH4+, tetramethylammonium (TMA), trimethylphenylammonium (TMPA) and hexadecyltrimethylammonium (HDTMA) cations. The magnitude of sorption followed the order: TMPA-smectite≥HDTMA-smectite>NH4-smectite>K-smectite>Ca-smectite⩾TMA-smectite. The greatest sorption of carbamazepine by TMPA-smectite is attributed to the interaction of conjugate aromatic moiety in carbamazepine with the phenyl ring in TMPA through π-π interaction. Partitioning process is the primary mechanism for carbamazepine uptake by HDTMA-smectite. For NH4-smectite the urea moiety in carbamazepine interacts with exchanged cation NH4+ by H-bonding hence demonstrating relatively higher adsorption. Sorption by K-, Ca- and TMA-smectites from water occurs on aluminosilicate mineral surfaces. These results implicate that carbamazepine sorption by soils occurs primarily in soil organic matter, and soil mineral fractions play a secondary role. Desorption of carbamazepine from the sorbents manifested an apparent hysteresis. Increasing irreversibility of desorption vs. sorption was observed for K-, Ca-, TMA-, TMPA- and HDTMA-clays as aqueous carbamazepine concentrations increased. Desorption hysteresis of carbamazepine from K-, Ca-, NH4-smectites was greater than that from TMPA- and HDTMA-clays, suggesting that the sequestrated carbamazepine molecules in smectite interlayers are more resistant to desorption compared to those sorbed by organic phases in smectite clays. Copyright © 2010 Elsevier Ltd. All rights reserved.

  3. Sorption of thiabendazole in sub-tropical Brazilian soils.

    Science.gov (United States)

    de Oliveira Neto, Odilon França; Arenas, Alejandro Yopasa; Fostier, Anne Hélène

    2017-07-01

    Thiabendazole (TBZ) is an ionizable anthelmintic agent that belongs to the class of benzimidazoles. It is widely used in veterinary medicine and as a fungicide in agriculture. Sorption and desorption are important processes influencing transport, transformation, and bioavailability of xenobiotic compounds in soils; data related to sorption capacity are therefore needed for environmental risk assessments. The aim of this work was to assess the sorption potential of TBZ in four Brazilians soils (sandy, sandy-clay, and clay soils), using batch equilibrium experiments at three pH ranges (2.3-3.0, 3.8-4.2, and 5.5-5.7). The Freundlich sorption coefficient (K F ) ranged from 9.0 to 58 μg 1-1/n  (mL) 1/n  g -1 , with higher values generally observed at the lower pH ranges (2.3-3.0 and 3.8-4.2) and for clay soils. The highest organic carbon-normalized sorption coefficients (K OC ) obtained at pH 3.8-5.7 (around the natural pH range of 4.1-5.0) for both clay soils and sandy-clay soil were 3255 and 2015 mL g -1 , respectively. The highest correlations K F vs SOM (r = 0.70) and K F vs clay content (r = 0.91) were observed at pH 3.8-4.2. Our results suggest that TBZ sorption/desorption is strongly pH dependent and that its mobility could be higher in the studied soils than previously reported in soils from temperate regions.

  4. Characteristics of and sorption to biochars derived from waste material

    Science.gov (United States)

    Sun, Huichao; Kah, Melanie; Sigmund, Gabriel; Hofmann, Thilo

    2015-04-01

    Biochars can exhibit a high sorption potential towards heavy metals and organic contaminants in various environmental matrices (e.g., water, soil). They have therefore been proposed for environmental remediation purposes to sequester contaminants. To date, most studies have focused on the physicochemical and sorption properties of mineral phases poor biochars, which are typically produced from plant residues. Only little knowledge is available for biochars derived from human and animal waste material, which are typically characterized by high mineral contents (e.g., sewage sludge, manure). Using human and animal waste as source material to produce biochars would support the development of attractive combined strategies for waste management and remediation. The potential impact of mineral phases on the physicochemical and sorption properties of biochars requires further studies so that the potential as sorbent material can be evaluated. With this purpose, different source material biochars were produced at 200°C, 350°C and 500°C, to yield a series of biochars representing a range of mineral content. The derived biochars from wood shavings (sludge (50-70% ash) and pig manure (30-60% ash), as well as a commercial biochar derived from grain husks (40% ash), were extensively characterized (e.g., element composition, surface area, porosity, Fourier transform infrared spectroscopy). The contents of potentially toxic elements (i.e., heavy metals and polycyclic aromatic hydrocarbons) of all materials were within the guidelines values proposed by the International Biochar Initiative, indicating their suitability for environmental application. Single point sorption coefficients for the model sorbate pyrene were measured to investigate the effect of mineral content, feedstock, pyrolysis temperature, particle size fractions and acid demineralization on sorption behavior. Overall, sorption of pyrene was strong for all materials (4 waste material and exhibiting high mineral

  5. Numerical analysis of coupled water transport in wood with a focus on the coupling parameter sorption

    DEFF Research Database (Denmark)

    Hozjan, T.; Turk, G.; Rodman, U.

    2011-01-01

    This paper presents a study of sorption rate function in a so-called multi-Fickian or multi-phase model. This model describes the complex moisture transport system in wood, which consists of separate water-vapour and bound-water diffusion interacting through sorption. In the numerical example inf...... influence of the sorption rate function on water transport is presented. It can be seen that the sorption rate function has a noticeable influence on coupled water transport in wood....

  6. 137Cs sorption onto Fullers' Earth (calcium montmorillonite) -the influence of sulphate reducing bacteria

    International Nuclear Information System (INIS)

    West, J.M.; Haigh, D.G.; Hooker, P.J.; Rowe, E.J.

    1987-12-01

    The influences of Desulfovibrio desulfuricans on the sorption of 137 Cs onto Fullers' Earth (Calcium montmorillonite) has been studied using batch sorption methods. Results were expressed as distributions ratios (Rd) and as Freundlich and Dubinin-Radushkevich isotherms. They show that microbes present naturally in the Fullers' Earth did not influence sorption data, however the addition of microbes in the aqueous phase alters the sorption properties in a complex manner. (author)

  7. Sorption and desorption of diuron in Oxisol under biochar application

    OpenAIRE

    Petter,Fabiano André; Ferreira,Tamara Santos; Sinhorin,Adilson Paulo; Lima,Larissa Borges de; Morais,Leidimar Alves de; Pacheco,Leandro Pereira

    2016-01-01

    ABSTRACT The objective of this study was to verify the kinetics of sorption and desorption of diuron in an Oxisol under application of biochar. The samples were collected in a field experiment conducted in randomized design blocks consisted of 2 base fertilization levels (0 and 400 kg∙ha−1 NPK 00-20-20 fertilizer formula) and 3 doses of biochar (0, 8 and 16 Mg∙ha−1). In the evaluation of sorption and desorption, Batch Equilibrium method was used. The kinetics of sorpti...

  8. Cerium sorption in grounds modified by anti-deflation treatment

    International Nuclear Information System (INIS)

    Firsova, L.P.; Bogatyrev, I.O.

    2001-01-01

    Influence of soils and grounds treatment by anti-deflation compositions on the size of the soil particles was studied. Under static conditions sorption of 144 Ce by turf-podsolic soils prior to an after their modification by the anti-deflation reagents, i.e. bitumens and insoluble in water polyelectrolytic complexes, was considered. Degrees of 144 Ce sorption in the soil-solution systems, depending on solutions pH, presence of alkali metal carbonates and cerium concentration, were determined [ru

  9. Sorption, Diffusion and Solubility Databases for Performance Assessment

    International Nuclear Information System (INIS)

    Garcia Gutierrez, M.

    2000-01-01

    This report presents a deterministic and probabilistic databases for application in Performance Assessment of a high-level radioactive waste disposal. This work includes a theoretical description of sorption, diffusion and solubility phenomena of radionuclides in geological media. The report presents and compares the databases of different nuclear wastes management agencies, describes the materials in the Spanish reference system, and the results of sorption diffusion and solubility in this system, with both the deterministic and probabilistic approximation. The probabilistic approximation is presented in the form of probability density functions (pdf). (Author) 52 refs

  10. Sorption techniques for production of high purity refractory metals

    International Nuclear Information System (INIS)

    Shatalov, V.V.; Peganov, V.A.; Logvinenko, I.A.; Molchanova, T.V.

    2004-01-01

    A consideration is given to potentialities of sorption processes tot provide a high quality of refractory metal and their alloys when using hydrometallurgical methods for raw material processing. The efficiency of application of ion exchange technology is shown for complex solutions reprocessing for various types of polymetallic raw materials, among them uranium ores, enriched concentrates of refractory metal ores, intermediate products, waste solutions. Based on investigation results on the behaviour of elements in process solutions and the mechanism of their sorption and elution, the process of pure chemical compounds production are developed which provide thereafter manufacturing compact metals. The flowsheets developed are mastered on a commercial scale [ru

  11. Sorption of 60 Co in natural zeolite (clinoptilolite)

    International Nuclear Information System (INIS)

    Hernandez B, E.

    1996-01-01

    A Mexican zeolite (clinoptilolite) from Taxco, Guerrero, was partially stabilized with sodium cations. Radioactive Cobalt ( 60 Co) was used to study the Co 2+ sorption in the stabilized zeolite (Na + ). It was found that sorption in general does not favour the diffusion of cobalt between framework, it explains because of it is a natural zeolite and its composition heterogeneous decrease its exchange capacity by the generated competence to the existence other type of exchange ions. The cobalt retention reached the highest level, around 0.408 m eq Co 2+ /g in the Na-Clinoptilolite. The crystallinity of the aluminosilicates was maintained during experiments, it was verified by XRD patterns. (Author)

  12. Determination of 60Co sorption in natural clinoptilolite

    International Nuclear Information System (INIS)

    Hernandez B, E.; Granados C, F.

    1997-01-01

    It was studied the clinoptilolite behavior coming from a deposit in Taxco, Guerrero in hydration and stabilization conditions with sodium for determining its sorption properties. The ion exchange process was carried out through gamma spectrometry using a CoCl 2 solution marked with 60 Co at p H 6.5 in different contact times. It was observed a maximum sorption of 0.408 m eq Co +2 /g mineral, from 0.314 m eq Co +2 /g mineral correspond at ion exchange. (Author)

  13. Integration of fuel cells into residential buildings

    International Nuclear Information System (INIS)

    Bell, J.M.; Entchev, E.; Gusdorf, J.; Szadkowski, F.; Swinton, M.; Kalbfleisch, W.; Marchand, R.

    2004-01-01

    Integration of small combined heat and power systems (CHP) into residential buildings is challenging as the loads are small, the load diversity is limited and there are a number of unresolved issues concerning sizing, control, peak loads, emergency operation, grid connection and export, etc. Natural Resources Canada has undertaken an initiative to investigate and develop techniques for the integration of small CHP systems into residential buildings using a highly instrumented house modified to allow quick installation and thorough monitoring of CHP integration techniques as well determining the performance of the CHP systems themselves when operating in a house. The first CHP system installed was a Stirling engine residential CHP system. It was used to examine the completeness of the CHP modifications to the house, to evaluate various building integration techniques and to measure the performance of the CHP system itself. The testing demonstrated the modified house to be an excellent facility for the development of CHP building integration techniques and the testing of residential CHP systems. The Stirling engine CHP system was found to operate well and produce meaningful input to the house. A second system (residential fuel cell) is presently being installed and building integration techniques and the performance of the fuel cell will be tested over the coming year. (author)

  14. Integrated Management of Residential Energy Resources

    Directory of Open Access Journals (Sweden)

    Antunes C. H.

    2012-10-01

    Full Text Available The increasing deployment of distributed generation systems based on renewables in the residential sector, the development of information and communication technologies and the expected evolution of traditional power systems towards smart grids are inducing changes in the passive role of end-users, namely with stimuli to change residential demand patterns. The residential user should be able to make decisions and efficiently manage his energy resources by taking advantages from his flexibility in load usage with the aim to minimize the electricity bill without depreciating the quality of energy services provided. The aim of this paper is characterizing electricity consumption in the residential sector and categorizing the different loads according to their typical usage, working cycles, technical constraints and possible degree of control. This categorization of end-use loads contributes to ascertain the availability of controllable loads to be managed as well as the different direct management actions that can be implemented. The ability to implement different management actions over diverse end-use load will increase the responsiveness of demand and potentially raises the willingness of end-users to accept such activities. The impacts on the aggregated national demand of large-scale dissemination of management systems that would help the end-user to make decisions regarding electricity consumption are predicted using a simulator that generates the aggregated residential sector electricity consumption under variable prices.

  15. Residentialization of Public Spaces: Bratislava Example

    Science.gov (United States)

    Bacová, Andrea; Puškár, Branislav; Vráblová, Edita

    2017-10-01

    The housing estates in Bratislava saturated the housing needs of a large number of inhabitants who come after World War II to the city. Design of public spaces often did not have priority in the process of designing. The solutions for mentioned exterior spaces had been planned after blocks of flat realization, but many of them are not realized to this day. The article analyzes the example of the unrealized public spaces in existing housing estates Devinska Nova Ves and Petržalka (city districts of Bratislava) and offer practical solutions in relation to residencialization method. Residencialization of missing public places is an effective method of adding identities to settlements. It improves the quality of residential environment and public spaces. The main aim is to create better conditions for social activities in public areas, which are missing on the present. The research will be focused on the examination of the urban, cultural and construction potential of the existing residential enviroment in Bratislava. The main aim of residentialization is not only to enhance the quality of spatial and building structures in the selected residential area and maintain long-term sustainability in the pertinent programme area, but mainly to improve the quality of living for the residents. The outputs of the project are proposals and practical procedures developed with regard to planning documents for local municipal authorities and regional organizations. The solutions will have a positive impact on the enhancement of the quality of public spaces, attractive social activities and of a conceptual link - residentialization.

  16. Sorption of V and VI group metalloids (As, Sb, Te on modified peat sorbents

    Directory of Open Access Journals (Sweden)

    Ansone-Bertina Linda

    2016-01-01

    Full Text Available The present work investigates arsenic, antimony and tellurium sorption using iron modified peat. The results were obtained using batch tests and the sorption was studied as a function of initial metalloid concentration, pH and sorption time, as well as the presence of competing substances. The obtained results indicate that modification of peat with Fe compounds significantly enhances the sorption capacity of the sorbents used for sorption of arsenic, antimony and tellurium. The optimal pH interval for the sorption of Sb(III is 6.5–9 and for As(V and Sb(V – 3–6, while As(III and tellurium sorption using Fe-modified peat is favourable in a wider interval of 3–9. The presence of competing ions as well as HA affect sorption of metalloids on Fe-modified peat. A minor impact on the reduction of metalloid sorption was detected in the presence of nitrate, sulphate, carbonate and tartrate ions, while in the presence of phosphate and HA the sorption ability of metalloids can be considerably reduced. The obtained results of kinetic experiments indicate that sorption of metalloids on Fe-modified peat mainly occurs relying on mechanisms of physical sorption processes.

  17. Co-contaminants and factors affecting the sorption behaviour of two sulfonamides in pasture soils

    International Nuclear Information System (INIS)

    Srinivasan, Prakash; Sarmah, Ajit K.; Manley-Harris, Merilyn

    2013-01-01

    We investigated the effect of soil pH, organic carbon, ionic strength and steroid hormones on the sorption of sulfamethoxazole (SMO) and sulfachloropyridazine (SCP) in three pastoral soils of New Zealand. A model linking sorbate speciation with species-specific sorption coefficients describing the pH dependence of the apparent sorption coefficients was used to derive the fraction of each species of SMO. All soils displayed a decrease in sorption when pH was increased, with SMO exhibiting the highest sorption at pH 2. The cationic form of SMO appeared to sorb more close to pH ≥ pK a1 and, when pH ≥ pK a2 (6.5, 7.5 and 8.5) the anionic species seems to dominate, however, its sorption affinity to all soils was low. SMO sorption was affected by ionic strengths and organic carbon content, while the presence of hormones showed only a subtle decrease in SCP sorption in a selected model pasture soil. -- Highlights: •The effect of OC content on sulfamethoxazole sorption is nullified by the pH effect. •Steroid hormone has a subtle influence on the sulfachloropyridazine sorption in pastoral soil. •Increased hormone concentrations decrease sulfachloropyridazine sorption in soils. -- Sorption affinity of SMO and SCP are strongly governed by multitude of factors, and variations in these factors can be significant when manure and fertilisers are added to soil

  18. Transport and sorption of volatile organic compounds and water vapor in porous media

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Tsair-Fuh [Univ. of California, Berkeley, CA (United States)

    1995-07-01

    To gain insight on the controlling mechanisms for VOC transport in porous media, the relations among sorbent properties, sorption equilibrium and intraparticle diffusion processes were studied at the level of individual sorbent particles and laboratory columns for soil and activated carbon systems. Transport and sorption of VOCs and water vapor were first elucidated within individual dry soil mineral grains. Soil properties, sorption capacity, and sorption rates were measured for 3 test soils; results suggest that the soil grains are porous, while the sorption isotherms are nonlinear and adsorption-desorption rates are slow and asymmetric. An intragranular pore diffusion model coupled with the nonlinear Freundlich isotherm was developed to describe the sorption kinetic curves. Transport of benzene and water vapor within peat was studied; partitioning and sorption kinetics were determined with an electrobalance. A dual diffusion model was developed. Transport of benzene in dry and moist soil columns was studied, followed by gaseous transport and sorption in activated carbon. The pore diffusion model provides good fits to sorption kinetics for VOCs to soil and VOC to granular activated carbon and activated carbon fibers. Results of this research indicate that: Intraparticle diffusion along with a nonlinea sorption isotherm are responsible for the slow, asymmetric sorption-desorption. Diffusion models are able to describe results for soil and activated carbon systems; when combined with mass transfer equations, they predict column breakthrough curves for several systems. Although the conditions are simplified, the mechanisms should provide insight on complex systems involving transport and sorption of vapors in porous media.

  19. Sorption of fission nuclides on model milk components. I. Sorption of radiostrontium on hydroxyapatite in aqueous solutions

    International Nuclear Information System (INIS)

    Rosskopfova, O.; Kopunec, R.; Matel, L.; Macasek, F.; Kristin, J.

    1999-01-01

    Hydroxyapatite, Ca 10 (PO 4 ) 6 (OH) 2 is a mineral widely spread in nature as a main constituent of phosphate rocks, and also as the major inorganic component of bones and teeth. It was found that sorption process occurs by an ion exchange reaction mechanism between strontium ions in solution and calcium ions in apatite. Ca 2+ → Sr 2+ substitution in hydroxyapatite is important since it explains the mechanism of incorporation of beta-active Sr-90 of atomic debris into the human skeletal system. The strontium uptake at 100 grad C is done by adsorption and diffusion while at 25 grad C it is done by the process of adsorption only. The hydroxyapatite was prepared from aqueous solutions and characterized by standard analytical methods. Some samples of hydroxyapatite were modified by heating after its precipitation from aqueous solution. The sample obtained had characteristics of well crystallized stoichiometric hydroxyapatite. Also, commercial hydroxy-apatites were used. Sorption of strontium ions on synthetic hydroxyapatite was examined using batch method and sorption depends on the method of preparation of hydroxyapatite. In generally, sorption of strontium decreases with the increase in the particle size of hydroxyapatite and decreases with the increase in the pH ( hydroxyapatite surface is amphoteric and acts as a buffer in a wide pH range). The sorption of strontium increases with the increase in [Sr 2+ ] or [Ca 2+ ] in solution to ∼ 10 -5 mol · dm -3 for the hydroxyapatite prepared by heating. The experimental data for sorption of strontium has been fitted with Langmuir-adsorption isotherm. (authors)

  20. Experimental studies of Cs, Sr, Ni, and Eu sorption on Na-illite and the modelling of Cs sorption

    International Nuclear Information System (INIS)

    Poinssot, C.; Baeyens, B.; Bradbury, M.H.

    1999-08-01

    A natural illite (illite du Puy) was purified and converted to the homo-ionic Na-form. The conditioned Na-illite was characterised in terms of its mineralogy, chemical inventory and physico-chemical properties. The structural formula was determined from energy dispersive spectroscopic analyses (SEM/TEM-EDS) and bulk chemistry measurements. A cation exchange capacity of 127 meq kg -1 was determined by the 22 Na isotope dilution method at neutral pH. The Na-CEC was also measured as a function of pH. The stability of Na-illite as a function of pH in the range between 3 and 6 was investigated. At low pH values partial dissolution of the illite occurs releasing the structural elements Al, Si, Mg, and K into solution. The presence of Ca and Sr in solution was interpreted as being due to desorption from cation exchange sites. All of these elements are also present at neutral pH but at considerably lower levels. Such effects cannot be avoided and must be considered in the interpretation of the sorption measurements. The main focus of the experimental work presented here is on the sorption behaviour of Cs, Sr, Ni and Eu on conditioned Na-illite as a function of NaClO 4 background electrolyte concentration (0.1 and 0.01 M), nuclide concentration and pH in the range between 3 and 11. Sorption edge data (R d versus pH) and sorption isotherms (quantity of nuclide sorbed versus equilibrium nuclide concentration) are presented for these four elements. Prior to beginning these experiments, sorption kinetics were measured. The broad based pool of sorption measurements generated from this work will provide the source data sets for subsequent modelling. So far only the Cs sorption measurements have been modelled. A two site cation exchange model was developed to describe the sorption of Cs over the whole range of experimental conditions. The two site types were termed 'frayed edge sites' (FES, high affinity/low capacity) and 'type II sites' (low affinity/high capacity). Selectivity

  1. Solar-aided air conditioning through sorption. Final report. Phase 2; Solar unterstuetzte Klimatisierung ueber Sorption. Endbericht zur Phase 2

    Energy Technology Data Exchange (ETDEWEB)

    Laevemann, E; Kessling, W; Peltzer, M

    1996-09-24

    The present article reports on possibilities of using solar energy for cooling buildings. It contains the following chapters: Current state of research and development; room air conditioning; planning and results of the studies; theory; experimental studies on the sorption dehumidifier; development of exchange surfaces; development of solution distributors; cooling of exchange surfaces; construction of a sorption dehumidifier. (HW) [Deutsch] Die Arbeit berichtet ueber Moeglichkeiten der Anwendung von Solarenergie zur Kuehlung von Gebaeuden. Die Arbeit enthaelt folgende Kapitel: - Stand der Forschung und Entwicklung - Raumklimatisierung - Planung und Ergebnis der Untersuchungen - Theorie - Experimentelle Untersuchungen am Sorptionsentfeuchter - Entwicklung von Austauschflaechen - Entwicklung von Loesungsverteilern - Kuehlung von Austauschflaechen - Konstruktion eines Sorptionsentfeuchters. (HW)

  2. Estimation of energy efficiency of residential buildings

    Directory of Open Access Journals (Sweden)

    Glushkov Sergey

    2017-01-01

    Full Text Available Increasing energy performance of the residential buildings by means of reducing heat consumption on the heating and ventilation is the last segment in the system of energy resources saving. The first segments in the energy saving process are heat producing and transportation over the main lines and outside distribution networks. In the period from 2006 to 2013. by means of the heat-supply schemes optimization and modernization of the heating systems. using expensive (200–300 $US per 1 m though hugely effective preliminary coated pipes. the economy reached 2.7 mln tons of fuel equivalent. Considering the multi-stage and multifactorial nature (electricity. heat and water supply of the residential sector energy saving. the reasonable estimate of the efficiency of the saving of residential buildings energy should be performed in tons of fuel equivalent per unit of time.

  3. Residential neighbourhoods in Kathmandu: Key design guidelines

    Directory of Open Access Journals (Sweden)

    Bijaya K. Shrestha

    2013-01-01

    Full Text Available Residential neighbourhoods developed using various techniques in Kathmandu by both the public and private sectors have not only provided a poor urban setting and failed to address socio-cultural needs, but are also poor at building a community and creating links to the built environment, with the result that the planned areas lack a sense of place and the inhabitants lack a feeling of home. Although traditional neighbourhoods in the historic core area had many features of a good residential neighbourhood in the past, they are currently undergoing rapid destruction. The residents of these neighbourhoods have little awareness of these issues. The existing legal and institutional frameworks are inadequate and ineffective and cannot address these problems, and so the formulation of design guidelines, their strict implementation, and enhancement of socio-cultural events including social networking are recommended for future residential neighbourhood development.

  4. Gentrification and Residential Mobility in Philadelphia.

    Science.gov (United States)

    Ding, Lei; Hwang, Jackelyn; Divringi, Eileen

    2016-11-01

    Gentrification has provoked considerable controversy surrounding its effects on residential displacement. Using a unique individual-level, longitudinal data set, this study examines mobility rates and residential destinations of residents in gentrifying neighborhoods during the recent housing boom and bust in Philadelphia for various strata of residents and different types of gentrification. We find that vulnerable residents, those with low credit scores and without mortgages, are generally no more likely to move from gentrifying neighborhoods compared with their counterparts in nongentrifying neighborhoods. When they do move, however, they are more likely to move to lower-income neighborhoods. Residents in gentrifying neighborhoods at the aggregate level have slightly higher mobility rates, but these rates are largely driven by more advantaged residents. These findings shed new light on the heterogeneity in mobility patterns across residents in gentrifying neighborhoods and suggest that researchers should focus more attention on the quality of residential moves and nonmoves for less advantaged residents, rather than mobility rates alone.

  5. Expressions of Prayer in Residential Care Homes.

    Science.gov (United States)

    Reimer-Kirkham, Sheryl; Sharma, Sonya; Smith, Brenda; Schutt, Kelly; Janzen, Kyla

    2018-01-01

    Although the value of spiritual care in the care of older adults is supported by research, few studies have focused specifically on prayer in residential care settings. This ethnographic study with fifteen chaplains and administrators in eleven residential care homes involved analyses of walking interviews and research diaries. Findings revealed the spaces in which prayer happens and the forms it takes. The identities of chaplains-their own spiritual practices, religious beliefs, and positioning within the facility-shaped their dis/comfort with prayer and how they located prayer within public and private spaces. Where organizational leadership endorsed the legitimacy of chaplaincy services, prayer was more likely to be offered. Even in these circumstances, however, religious diversity and questions about secularism left chaplains ambivalent about the appropriateness of prayer. The results demonstrate the relevance of religion and spirituality to residential care, and illustrate how prayer functions as an opportunity for connection and understanding.

  6. Service Differentiation in Residential Broadband Networks

    DEFF Research Database (Denmark)

    Sigurdsson, Halldór Matthias

    2004-01-01

    As broadband gains widespread adoption with residential users, revenue generating voice- and video-services have not yet taken off. This slow uptake is often attributed to lack of Quality of Service management in residential broadband networks. To resolve this and induce service variety, network...... access providers are implementing service differentiation in their networks where voice and video gets prioritised before data. This paper discusses the role of network access providers in multipurpose packet based networks and the available migration strategies for supporting multimedia services...... in digital subscriber line (DSL) based residential broadband networks. Four possible implementation scenarios and their technical characteristics and effects are described. To conclude, the paper discusses how network access providers can be induced to open their networks for third party service providers....

  7. Solar Photovoltaic Financing: Residential Sector Deployment

    Energy Technology Data Exchange (ETDEWEB)

    Coughlin, J.; Cory, K.

    2009-03-01

    This report presents the information that homeowners and policy makers need to facilitate PV financing at the residential level. The full range of cash payments, bill savings, and tax incentives is covered, as well as potentially available solar attribute payments. Traditional financing is also compared to innovative solutions, many of which are borrowed from the commercial sector. Together, these mechanisms are critical for making the economic case for a residential PV installation, given its high upfront costs. Unfortunately, these programs are presently limited to select locations around the country. By calling attention to these innovative initiatives, this report aims to help policy makers consider greater adoption of these models to benefit homeowners interested installing a residential PV system.

  8. Energy savings in Danish residential building stock

    DEFF Research Database (Denmark)

    Tommerup, Henrik M.; Svendsen, Svend

    2006-01-01

    a short account of the technical energy-saving possibilities that are present in existing dwellings and presents a financial methodology used for assessing energy-saving measures. In order to estimate the total savings potential detailed calculations have been performed in a case with two typical...... buildings representing the residential building stock and based on these calculations an assessment of the energy-saving potential is performed. A profitable savings potential of energy used for space heating of about 80% is identified over 45 years (until 2050) within the residential building stock......A large potential for energy savings exists in the Danish residential building stock due to the fact that 75% of the buildings were constructed before 1979 when the first important demands for energy performance of building were introduced. It is also a fact that many buildings in Denmark face...

  9. Modelling and forecasting Turkish residential electricity demand

    International Nuclear Information System (INIS)

    Dilaver, Zafer; Hunt, Lester C

    2011-01-01

    This research investigates the relationship between Turkish residential electricity consumption, household total final consumption expenditure and residential electricity prices by applying the structural time series model to annual data over the period from 1960 to 2008. Household total final consumption expenditure, real energy prices and an underlying energy demand trend are found to be important drivers of Turkish residential electricity demand with the estimated short run and the long run total final consumption expenditure elasticities being 0.38 and 1.57, respectively, and the estimated short run and long run price elasticities being -0.09 and -0.38, respectively. Moreover, the estimated underlying energy demand trend, (which, as far as is known, has not been investigated before for the Turkish residential sector) should be of some benefit to Turkish decision makers in terms of energy planning. It provides information about the impact of past policies, the influence of technical progress, the impacts of changes in consumer behaviour and the effects of changes in economic structure. Furthermore, based on the estimated equation, and different forecast assumptions, it is predicted that Turkish residential electricity demand will be somewhere between 48 and 80 TWh by 2020 compared to 40 TWh in 2008. - Research highlights: → Estimated short run and long run expenditure elasticities of 0.38 and 1.57, respectively. → Estimated short run and long run price elasticities of -0.09 and -0.38, respectively. → Estimated UEDT has increasing (i.e. energy using) and decreasing (i.e. energy saving) periods. → Predicted Turkish residential electricity demand between 48 and 80 TWh in 2020.

  10. Strategy Guideline: High Performance Residential Lighting

    Energy Technology Data Exchange (ETDEWEB)

    Holton, J.

    2012-02-01

    The Strategy Guideline: High Performance Residential Lighting has been developed to provide a tool for the understanding and application of high performance lighting in the home. The high performance lighting strategies featured in this guide are drawn from recent advances in commercial lighting for application to typical spaces found in residential buildings. This guide offers strategies to greatly reduce lighting energy use through the application of high quality fluorescent and light emitting diode (LED) technologies. It is important to note that these strategies not only save energy in the home but also serve to satisfy the homeowner's expectations for high quality lighting.

  11. Sorption equilibrium of mercury onto ground-up tree fern.

    Science.gov (United States)

    Ho, Yuh-Shan; Wang, Chung-Chi

    2008-08-15

    The sorption behavior of mercury at different temperatures onto ground-up tree fern was investigated. The experimental results were fitted to two two-parameter isotherms, the Freundlich and Langmuir isotherms, as well as to two three-parameter isotherms, the Redlich-Peterson and Sips isotherms to obtain the characteristic parameters of each model. A comparison of best-fitting was performed using the coefficient of determination and Chi-square test. Both the Langmuir and Redlich-Peterson isotherms were found to well represent the measured sorption data. According to the evaluation using the Langmuir equation, the saturated monolayer sorption capacity of mercury ions onto ground-up tree fern was 26.5 mg/g at 298 K. It was noted that an increase in temperature resulted in a higher mercury ion loading per unit weight of the tree fern. In addition, various thermodynamic parameters, such as DeltaG degrees, DeltaH degrees, and DeltaS degrees, were calculated and compared with the sorption of mercury by other sorbents.

  12. New Composite Sorbents for Caesium and Strontium Ions Sorption

    Directory of Open Access Journals (Sweden)

    Mykola Kartel

    2017-06-01

    Full Text Available Composite lignocellulose-inorganic sorbents derived from plant residues of agriculture and food industry, modified with ferrocyanides of d-metals and hydrated antimony pentoxide were prepared. Caesium and strontium ions removal from water was tested by radiotracer method. Sorption of heavy metal ions, methylene blue, gelatin, vitamin B12 was also studied.

  13. Sorption of Heavy Metals from Mine Wastewater by Activated ...

    African Journals Online (AJOL)

    A study on sorption of heavy metal ions: Lead (Pb2+), Copper (Cu2+) and Cadmium (Cd2+) from mine wastewater by activated carbons prepared from coconut husk was conducted. The activated carbons were prepared by carbonisation of the husk at 900 ºC pyrolysis temperature, followed by steam activation of the ...

  14. Development of a 15 K hydrogen-based sorption cooler

    NARCIS (Netherlands)

    Burger, Johannes Faas; Holland, Herman J.; Meijer, R.J.; Linder, M.; ter Brake, Hermanus J.M.

    2010-01-01

    At the University of Twente, a 15 K hydrogen-based sorption cooler is under development, which has no moving parts and, therefore, is essentially vibration-free. Moreover, it has the potential of a very long life. Although the cooler may operate standalone, it is designed to precool a helium-based

  15. Sorption of uranyl ions on hydrous silicon dioxide

    International Nuclear Information System (INIS)

    Lieser, K.H.; Quandt-Klenk, S.; Thybusch, B.

    1992-01-01

    Sorption of uranyl ions on SiO 2 .χH 2 O (silica gel) is investigated in absence and in presence of carbonate as function of pH. The curves obtained are very similar to those observed for sorption of uranyl ion on TiO 2 .χH 2 O, indicating the dominating influence of the uranium species in solution. Between pH 2 and 5 the sorption ratio R s increases with hydrolysis of uranyl ions (formation of UO 2 OH + ), around pH 7 it is nearly independent of pH, and at higher pH it decreases again. The equilibrium constants are calculated for these ranges. In presence of carbonate R s decreases drastically above pH 6, due to the formation of carbonato complexes in solution. Sorption of uranyl ions on SiO 2 .χH 2 O, on TiO 2 .χH 2 O, and on cryst. SiO 2 and Al 2 O 3 is compared. The problems of 'surface complexation' modelling are discussed. (orig.)

  16. The sorption induced glass transition in amorphous glassy polymers

    NARCIS (Netherlands)

    van der Vegt, N.F.A.; Wessling, Matthias; Strathmann, H.; Briels, Willem J.

    1999-01-01

    Sorption of CO2 in both the glassy and the rubbery state of an amorphous polyethylenelike polymer was investigated using molecular dynamics simulations. The temperature was chosen such that the system was in its glassy state at low solute concentrations and its rubbery state at large solute

  17. Sorption kinetics of diuron on volcanic ash derived soils.

    Science.gov (United States)

    Cáceres-Jensen, Lizethly; Rodríguez-Becerra, Jorge; Parra-Rivero, Joselyn; Escudey, Mauricio; Barrientos, Lorena; Castro-Castillo, Vicente

    2013-10-15

    Diuron sorption kinetic was studied in Andisols, Inceptisol and Ultisols soils in view of their distinctive physical and chemical properties: acidic pH and variable surface charge. Two types of kinetic models were used to fit the experimental dates: those that allow to establish principal kinetic parameters and modeling of sorption process (pseudo-first-order, pseudo-second-order), and some ones frequently used to describe solute transport mechanisms of organic compounds on different sorbents intended for remediation purposes (Elovich equation, intraparticle diffusion, Boyd, and two-site nonequilibrium models). The best fit was obtained with the pseudo-second-order model. The rate constant and the initial rate constant values obtained through this model demonstrated the behavior of Diuron in each soil, in Andisols were observed the highest values for both parameters. The application of the models to describe solute transport mechanisms allowed establishing that in all soils the mass transfer controls the sorption kinetic across the boundary layer and intraparticle diffusion into macropores and micropores. The slowest sorption rate was observed on Ultisols, behavior which must be taken into account when the leaching potential of Diuron is considered. Copyright © 2013 Elsevier B.V. All rights reserved.

  18. Sorption of 241Am onto montmorillonite, illite and hematite colloids

    International Nuclear Information System (INIS)

    Degueldre, C.; Ulrich, H.J.; Silby, H.

    1994-01-01

    Actinide sorption on colloids may be described as a competition between the formation of complexes in solution and the build up of surface complexes. The role of particle and of carbonate concentrations on the sorption/desorption of 241 Am on montmorillonite, illite and hematite colloids is investigated. Since the partition coefficient (K p ) values are virtually independent of the colloid concentrations, within the range 1 to 300 ppm, no significant aggregation takes place in the sorption/desorption experiment. At pH 8, a slight decrease of K p is observed if the concentration of total carbonate exceeds 10 -2 M. The formation of the carbonato- (and hydroxo-carbonato-) complexes in the solution competes with the formation of surface complexes on the colloids. A relationship between the sorption coefficient and the complexation of 241 Am in the solution has been found. This leads to the conclusion that, besides free americium cation, the hydroxo-, and carbonato- as well as the mixed hydroxo-carbonato-complexes are sorbed. Only when the tricarbonatocomplex [Am(CO 3 ) 3 ] 3- prevails (total carbonate concentration > 10 -2 M), a significant decrease of the distribution coefficient is observed. At pH 10 this decrease disappears because under these conditions the strong hydroxo-complexes dominate. A pragmatic and relatively simple application of surface complexation model describes the observed features. (orig.)

  19. Review of the sorption of actinides on natural minerals

    International Nuclear Information System (INIS)

    Beall, G.W.

    1981-01-01

    Over the past few years, a large body of data concerning sorption of actinides on geologic media has been built in connection with high-level-waste disposal. The primary aim of the work has been to allow predictions of the migration behavior of these radionuclides in the case of a breach of the repository that allowed groundwater flow through the repository. As a result of this work, some new backfill materials specifically tailored for the actinides have also been designed. Several major mechanisms of sorption that appear to dominate the sorption of actinides have emerged from these studies. These mechanisms can be divided into solution reactions dominated by hydrolysis, chemisorption reactions, and oxidation-reduction reactions. Each of these mechanisms will be discussed in detail, with experimental examples. Surprisingly, one mechanism, cation exchange, does not play an important role; why it fails to operate in any significant way in the environmental pH region will be discussed. The implications of the sorption mechanisms for waste forms and backfill materials will be discussed in detail. These discussions will center primarily around the valence state of the actinide in various waste forms and the effect of various anions on leachability from waste forms and backfill materials

  20. The investigation of wood hydrolysis lignin ability for uranium sorption

    International Nuclear Information System (INIS)

    Rachkova, N.G.; Shuktomova, I.I.; Taskaev, A.I.

    2001-01-01

    The uranium are sorbed in wood hydrolysis lignin efficacious and very strong both in uranyl nitrate solutions and in podsolic soil. It may well be that formation of complexes are possible mechanism of irreversible sorption. The static capacity of lignin are 2.7 mg/g. (author)

  1. Evaluation of phosphorus sorption characteristics of soils from the ...

    African Journals Online (AJOL)

    The evaluation of phosphorus sorption characteristics of soils and their relation to soil properties from the Bambouto sequence of Baranka 1, Baranka 2, Femock 1 and Femock 2 has been studied. Phosphorus, an essential plant nutrient, is often not readily available to plants and this deficiency tends to limit plant growth.

  2. Moisture Sorption Characteristics of Dambu-nama – A Nigerian ...

    African Journals Online (AJOL)

    Moisture sorption characteristics of traditional Dambu-nama (control) (TDBN) and laboratory Dambu-nama (LDBN), a cooked, pounded, shredded and dried Nigerian meat product, were determined at four different temperatures (10oC, 20oC, 30oC and 40oC) and relative humidities of 10 – 96% using the standard static, ...

  3. Heavy metal removal from aqueous solutions by sorption using ...

    African Journals Online (AJOL)

    Heavy metal removal from aqueous solutions by sorption using natural clays from Burkina Faso. ... The high alkaline pH in one of the samples is attributable to the presence of ... The point of zero charge (pHpzc) values of the clays, as determined by ... significant contributions to the removal of metal ions in aqueous systems.

  4. Sorption of organophosphate and triazine agrochemicals on biochars and soils

    Science.gov (United States)

    Biochars are known to strongly sorb polar and nonpolar organic compounds, and biochar soil amendment can have counteracting impacts on the efficacy of, and runoff contamination by agrochemicals. This study investigated the sorption-desorption isotherms and kinetics of triazine (deisopropylatrazine)...

  5. Sorption characteristics of methylene blue onto Nypa fruiticans lignin ...

    African Journals Online (AJOL)

    The sorption characteristics of soda lignin extracted from Nypa fruiticans for the removal of methylene blue dye from aqueous solution was investigated in this study, as an ethically sound way of utilizing this unexploited abundant natural resource. Equilibrium data were fitted to the Langmuir and Freundlich isotherm ...

  6. Moisture sorption in mixtures of biopolymer, disaccharides and water

    NARCIS (Netherlands)

    Sman, van der R.G.M.

    2013-01-01

    The moisture sorption of ternary mixtures of biopolymer, sugar and water is investigated by means of the Free-Volume-Flory-Huggins (FVFH) theory. The earlier FVFH theory developed for binary mixtures of biopolymer/water and sugar/water has to be modified to account for two effects: 1) the change in

  7. Performance of chromatographic systems to model soil-water sorption.

    Science.gov (United States)

    Hidalgo-Rodríguez, Marta; Fuguet, Elisabet; Ràfols, Clara; Rosés, Martí

    2012-08-24

    A systematic approach for evaluating the goodness of chromatographic systems to model the sorption of neutral organic compounds by soil from water is presented in this work. It is based on the examination of the three sources of error that determine the overall variance obtained when soil-water partition coefficients are correlated against chromatographic retention factors: the variance of the soil-water sorption data, the variance of the chromatographic data, and the variance attributed to the dissimilarity between the two systems. These contributions of variance are easily predicted through the characterization of the systems by the solvation parameter model. According to this method, several chromatographic systems besides the reference octanol-water partition system have been selected to test their performance in the emulation of soil-water sorption. The results from the experimental correlations agree with the predicted variances. The high-performance liquid chromatography system based on an immobilized artificial membrane and the micellar electrokinetic chromatography systems of sodium dodecylsulfate and sodium taurocholate provide the most precise correlation models. They have shown to predict well soil-water sorption coefficients of several tested herbicides. Octanol-water partitions and high-performance liquid chromatography measurements using C18 columns are less suited for the estimation of soil-water partition coefficients. Copyright © 2012 Elsevier B.V. All rights reserved.

  8. Aminosilane-Functionalized Cellulosic Polymer for Increased Carbon Dioxide Sorption

    KAUST Repository

    Pacheco, Diana M.

    2012-01-11

    Improvement in the efficiency of CO 2 separation from flue gases is a high-priority research area to reduce the total energy cost of carbon capture and sequestration technologies in coal-fired power plants. Efficient CO 2 removal from flue gases by adsorption systems requires the design of novel sorbents capable of capturing, concentrating, and recovering CO 2 on a cost-effective basis. This paper describes the preparation of an aminosilane-functionalized cellulosic polymer sorbent with enhanced CO 2 sorption capacity and promising performance for use in postcombustion carbon capture via rapid temperature-swing adsorption systems. The introduction of aminosilane functionalities onto the backbone of cellulose acetate was achieved by the anhydrous grafting of N-(2-aminoethyl)-3- aminoisobutyldimethylmethoxysilane. The dry sorption capacity of the modified cellulosic polymer reached 27 cc (STP) CO 2/cc sorbent (1.01 mmol/g sorbent) at 1 atm and 39 cc (STP) CO 2/cc sorbent (1.46 mmol/g sorbent) at 5 atm and 308 K. The amine loading achieved was 5.18 mmol amine(nitrogen)/g sorbent. Exposure to water vapor after the first dry sorption cycle increased the dry sorption capacity of the sorbent by 12% at 1 atm, suggesting its potential for rapid cyclic adsorption processes under humid feed conditions. The CO 2 sorbent was characterized in terms of chemical composition, density changes, molecular structure, thermal stability, and surface morphology. © 2011 American Chemical Society.

  9. Aminosilane-Functionalized Cellulosic Polymer for Increased Carbon Dioxide Sorption

    KAUST Repository

    Pacheco, Diana M.; Johnson, J.R.; Koros, William J.

    2012-01-01

    Improvement in the efficiency of CO 2 separation from flue gases is a high-priority research area to reduce the total energy cost of carbon capture and sequestration technologies in coal-fired power plants. Efficient CO 2 removal from flue gases by adsorption systems requires the design of novel sorbents capable of capturing, concentrating, and recovering CO 2 on a cost-effective basis. This paper describes the preparation of an aminosilane-functionalized cellulosic polymer sorbent with enhanced CO 2 sorption capacity and promising performance for use in postcombustion carbon capture via rapid temperature-swing adsorption systems. The introduction of aminosilane functionalities onto the backbone of cellulose acetate was achieved by the anhydrous grafting of N-(2-aminoethyl)-3- aminoisobutyldimethylmethoxysilane. The dry sorption capacity of the modified cellulosic polymer reached 27 cc (STP) CO 2/cc sorbent (1.01 mmol/g sorbent) at 1 atm and 39 cc (STP) CO 2/cc sorbent (1.46 mmol/g sorbent) at 5 atm and 308 K. The amine loading achieved was 5.18 mmol amine(nitrogen)/g sorbent. Exposure to water vapor after the first dry sorption cycle increased the dry sorption capacity of the sorbent by 12% at 1 atm, suggesting its potential for rapid cyclic adsorption processes under humid feed conditions. The CO 2 sorbent was characterized in terms of chemical composition, density changes, molecular structure, thermal stability, and surface morphology. © 2011 American Chemical Society.

  10. Sorption characteristics of technetium on crosslinked chitosan from aqueous solution

    International Nuclear Information System (INIS)

    Pivarciova, L.; Rosskopfova, O.; Galambos, M.; Rajec, P.

    2014-01-01

    Sorption of technetium on crosslinked chitosan was studied using batch techniques in static arrangement of experiment under aerobic conditions at laboratory temperature. The adsorption of technetium was rapid and the percentage of the technetium sorption was > 98 %. In the pH range of 3-11 adsorption of technetium on crosslinked chitosan was > 98 %. The competition effect of Fe 3+ towards TcO 4 - sorption on crosslinked chitosan was stronger than the competition effect of other observed cations. The selectivity of crosslinked chitosan for these cations in solution with the concentration above 1·10 -3 mol·dm -3 was in the order Fe 3+ > Ca 2+ > Na + > Fe 2+ . The competition effect of (ClO 4 ) - towards TcO 4 - sorption was stronger than the competition effect of (SO 4 ) 2 - ions. From these results it can be expected that crosslinked chitosan could be a suitable sorbent for the immobilization of technetium in the liquid radioactive waste. (authors)

  11. Moisture Sorption in Artificially aged wood-plastic composites

    Science.gov (United States)

    B. Kristoffer Segerholm; Rebecca E. Ibach; Magnus E.P. Wålinder

    2012-01-01

    Moisture sorption in wood-plastic composites (WPCs) affects their durability and dimensional stability. In certain outdoor exposures, the moisture properties of WPCs are altered due to e.g. cracks induced by swelling and shrinkage of the components, as well as UV degradation or biological attack. The aim of this work was to study the effect of different artificial...

  12. SORPTION OF VINCLOZOLIN AND ATRAZINE ON FOUR GEOSORBENTS

    Science.gov (United States)

    The objectives of this study were to evaluate the magnitude and kinetics of vinclozolin and atrazine sorption on one surface soil and three freshwater sediments using batch and column techniques. Data from miscible displacement column studies were analyzed using a two-domain, fir...

  13. Sorption equilibrium of mercury onto ground-up tree fern

    Energy Technology Data Exchange (ETDEWEB)

    Ho, Y.-S. [Department of Chemical Engineering, I-Shou University, No. 1, Section 1, Hsueh-Cheng Road, Ta-Hsu Hsiang, Kaohsiung County 840, Taiwan (China)], E-mail: ysho@isu.edu.tw; Wang, C.-C. [Department of Chemical Engineering, I-Shou University, No. 1, Section 1, Hsueh-Cheng Road, Ta-Hsu Hsiang, Kaohsiung County 840, Taiwan (China)

    2008-08-15

    The sorption behavior of mercury at different temperatures onto ground-up tree fern was investigated. The experimental results were fitted to two two-parameter isotherms, the Freundlich and Langmuir isotherms, as well as to two three-parameter isotherms, the Redlich-Peterson and Sips isotherms to obtain the characteristic parameters of each model. A comparison of best-fitting was performed using the coefficient of determination and Chi-square test. Both the Langmuir and Redlich-Peterson isotherms were found to well represent the measured sorption data. According to the evaluation using the Langmuir equation, the saturated monolayer sorption capacity of mercury ions onto ground-up tree fern was 26.5 mg/g at 298 K. It was noted that an increase in temperature resulted in a higher mercury ion loading per unit weight of the tree fern. In addition, various thermodynamic parameters, such as {delta}G{sup o}, {delta}H{sup o}, and {delta}S{sup o}, were calculated and compared with the sorption of mercury by other sorbents.

  14. Sorption equilibrium of mercury onto ground-up tree fern

    International Nuclear Information System (INIS)

    Ho, Y.-S.; Wang, C.-C.

    2008-01-01

    The sorption behavior of mercury at different temperatures onto ground-up tree fern was investigated. The experimental results were fitted to two two-parameter isotherms, the Freundlich and Langmuir isotherms, as well as to two three-parameter isotherms, the Redlich-Peterson and Sips isotherms to obtain the characteristic parameters of each model. A comparison of best-fitting was performed using the coefficient of determination and Chi-square test. Both the Langmuir and Redlich-Peterson isotherms were found to well represent the measured sorption data. According to the evaluation using the Langmuir equation, the saturated monolayer sorption capacity of mercury ions onto ground-up tree fern was 26.5 mg/g at 298 K. It was noted that an increase in temperature resulted in a higher mercury ion loading per unit weight of the tree fern. In addition, various thermodynamic parameters, such as ΔG o , ΔH o , and ΔS o , were calculated and compared with the sorption of mercury by other sorbents

  15. Sorption of Cs-137 and Co-60 in Natural Zeolites

    International Nuclear Information System (INIS)

    Chales Suarez, G.; Moreno Alvarez, D.; Coutin Correa, D.

    1996-01-01

    The sorption of Cs-137 and Co-60 in natural zeolites under different conditions was studied. The behaviour of samples of mineral and rock from different deposit of the country was obtained and the decontamination of radioactive waters containing both radionuclides was performed; as part of the research to determine its application in the treatment of radioactive wastes in the country

  16. A study of sorption of pertechnetate anion on chitosan

    International Nuclear Information System (INIS)

    Pivarciova, L.; Rosskopfova, O.; Rajec, P.; Galambos, M.

    2015-01-01

    Chitosan is one of the natural materials of biological origin. The sorption of pertechnetate anions from aqueous solutions on chitosan was studied in a batch system. This work was aimed to study influence of the contact time, effect of pH and effect of different ions on sorption of pertechnetate anions on chitosan. This sorbent was characterized by BET-surface area and potentiometric titration. The point of zero charge (pH pzc ) was at pH=7.15. The highest percentage of technetium sorption on chitosan was near pH 3. The adsorption capacity of chitosan decreased with increase in pH value above 3. In the initial pH range of 4-10, final pHs are the same. The selectivity of chitosan for these cations with concentration above 1·10 -3 mol·dm -3 was in the order Na + > Ca 2+ > Fe 3+ > Fe 2+ . The competition effect of (SO 4 ) 2- towards TcO 4 - sorption was stronger than the competition effect (ClO 4 ) - of ions. (authors)

  17. Sorption of europium by Haro river sand in aqueous solution

    International Nuclear Information System (INIS)

    Syed Moosa Hasany; Syed Javaid Khurshid

    1997-01-01

    The sorption of Eu(III) on Haro river sand has been investigated. Influences include composition of the sorptive medium, the concentration of sorbent and sorbate, and shaking time. Haro river sand can be exploited for the preconcentration and removal of europium from very dilute solutions, for the decontamination and treatment of radioactive waste water and effluents from nuclear installations. (Author)

  18. Sorption of Molecular Oxygen by Metal-Ion Exchanger Nanocomposites

    Science.gov (United States)

    Krysanov, V. A.; Plotnikova, N. V.; Kravchenko, T. A.

    2018-03-01

    Kinetic features are studied of the chemisorption and reduction of molecular oxygen from water by metal-ion exchanger nanocomposites that differ in the nature of the dispersed metal and state of oxidation. In the Pd equilibrium sorption coefficient for oxygen dissolved in water ranges from 20 to 50, depending on the nature and oxidation state of the metal component.

  19. Study of boric acid sorption and desorption processes

    International Nuclear Information System (INIS)

    Czosnowska, B.; Laren, E.

    1978-01-01

    The results are given of the experimental determination of the effect on the boric acid flow and sorption and desorption efficiency of the flow rate of boric acid at different concentrations through an ion exchange column 10.2 cm 2 in cross section. The strongly alkaline VOFATIT RO ion exchanger was used. (B.S.)

  20. Sustainable residential districts : the residents' role in project success

    NARCIS (Netherlands)

    Abdalla, G.

    2012-01-01

    Sustainable residential districts have been realized worldwide. These districts are promoted to be efficient in the use of natural materials and sustainable energy resources. Realization of sustainable residential districts can strongly contribute to achieve environmental objectives as imposed by

  1. PRN 2011-1: Residential Exposure Joint Venture

    Science.gov (United States)

    This PR Notice is to advise registrants of an industry-wide joint venture, titled the Residential Exposure Joint Venture (REJV), which has developed a national survey regarding residential consumer use/usage data for pesticides.

  2. Steering Angle Function Algorithm of Morphing of Residential Area

    Directory of Open Access Journals (Sweden)

    XIE Tian

    2015-07-01

    Full Text Available A residential area feature morphing method based on steering angle function is presented. To residential area with the same representation under two different scales,transforming the representation of the residential area polygon from vector coordinates to steering angle function,then using the steering angle function to match,and finding out the similarity and the differences between the residential areas under different scale to get the steering angle function of the the residential areas under any middle scale,the final,transforming the middle scale steering angle function to vector coordinates form,and get the middle shape interpolation of the the residential area polygon.Experimental results show:the residential area morphing method by using steering angle function presented can realize the continuous multi-scale representation under the premise of keeping in shape for the residential area with the rectangular boundary features.

  3. Surface complexation modeling of zinc sorption onto ferrihydrite.

    Science.gov (United States)

    Dyer, James A; Trivedi, Paras; Scrivner, Noel C; Sparks, Donald L

    2004-02-01

    A previous study involving lead(II) [Pb(II)] sorption onto ferrihydrite over a wide range of conditions highlighted the advantages of combining molecular- and macroscopic-scale investigations with surface complexation modeling to predict Pb(II) speciation and partitioning in aqueous systems. In this work, an extensive collection of new macroscopic and spectroscopic data was used to assess the ability of the modified triple-layer model (TLM) to predict single-solute zinc(II) [Zn(II)] sorption onto 2-line ferrihydrite in NaNO(3) solutions as a function of pH, ionic strength, and concentration. Regression of constant-pH isotherm data, together with potentiometric titration and pH edge data, was a much more rigorous test of the modified TLM than fitting pH edge data alone. When coupled with valuable input from spectroscopic analyses, good fits of the isotherm data were obtained with a one-species, one-Zn-sorption-site model using the bidentate-mononuclear surface complex, (triple bond FeO)(2)Zn; however, surprisingly, both the density of Zn(II) sorption sites and the value of the best-fit equilibrium "constant" for the bidentate-mononuclear complex had to be adjusted with pH to adequately fit the isotherm data. Although spectroscopy provided some evidence for multinuclear surface complex formation at surface loadings approaching site saturation at pH >/=6.5, the assumption of a bidentate-mononuclear surface complex provided acceptable fits of the sorption data over the entire range of conditions studied. Regressing edge data in the absence of isotherm and spectroscopic data resulted in a fair number of surface-species/site-type combinations that provided acceptable fits of the edge data, but unacceptable fits of the isotherm data. A linear relationship between logK((triple bond FeO)2Zn) and pH was found, given by logK((triple bond FeO)2Znat1g/l)=2.058 (pH)-6.131. In addition, a surface activity coefficient term was introduced to the model to reduce the ionic strength

  4. Modeling Residential Electricity Consumption Function in Malaysia: Time Series Approach

    OpenAIRE

    L. L. Ivy-Yap; H. A. Bekhet

    2014-01-01

    As the Malaysian residential electricity consumption continued to increase rapidly, effective energy policies, which address factors affecting residential electricity consumption, is urgently needed. This study attempts to investigate the relationship between residential electricity consumption (EC), real disposable income (Y), price of electricity (Pe) and population (Po) in Malaysia for 1978-2011 period. Unlike previous studies on Malaysia, the current study focuses on the residential secto...

  5. Suggestions on Strengthening Greening Construction of Ecological Residential Areas

    OpenAIRE

    Li, Peng

    2013-01-01

    Greening construction is an important part of the construction of ecological residential areas, but there exist some misunderstandings in greening construction of ecological residential districts at present. Based on the description of functions of green space in ecological residential areas, the summarization of principles of greening design, and the discussion of questions in greening construction of ecological residential districts, some suggestions as well as specific measures for strengt...

  6. Glyphosate sorption and desorption in soils with distinct phosphorus levels

    Directory of Open Access Journals (Sweden)

    Prata Fábio

    2003-01-01

    Full Text Available The sorption of glyphosate by soils occurs due to the inner sphere complex formation with metals of soil oxides, which are related to the soil phosphate adsorption capacity. The aim of this study was to evaluate the effects of increasing rates of phosphorus on sorption and desorption of glyphosate in three soils with different mineralogical attributes. Soils were a Rhodic Kandiudalf, an Anionic Acrudox and a Typic Humaquept. Soil samples were amended with KH2PO4 at equivalent rates of 0; 1,000; 5,000; 20,000 and 50,000 kg ha-1 of P2O5, which are high from the agricultural point of view, but necessary in order to perform sorption and desorption studies. The experimental design consisted of a completely randomized factorial: 2 soils x 5 phosphorus rates and 3 replicates. For the sorption experiments, five glyphosate solutions were employed (0.42; 0.84; 1.68; 3.36 and 6.72 mg L-1, with a 14C radioactivity of 0.233 kBq mL-1. Four steps of the desorption procedure with CaCl2 0.01 mol L-1 and one extraction with Mehlich 3 were performed only at one concentration (0.84 mol L-1. Soil samples were afterwards biologically oxidized to establish the radioactive balance. Glyphosate competes with phosphorus for specific sorption sites, but this competition becomes important when phosphorus is present at rates higher than 1,000 mg dm-3. Moreover, a small amount of applied glyphosate was extracted (<10%, and the extraction increased with increasing soil phosphorus content.

  7. General review of solar-powered closed sorption refrigeration systems

    International Nuclear Information System (INIS)

    Sarbu, Ioan; Sebarchievici, Calin

    2015-01-01

    Highlights: • Provide review of development in solar sorption refrigeration technologies. • Theoretical basis and applications of absorption and adsorption cycles are discussed. • Thermodynamic properties of most common working pairs have been reviewed. • Development of hybrid or thermal energy storage adsorption systems was explored. • A comparison between solar-powered absorption and adsorption systems was performed. - Abstract: The negative environmental impacts of burning fossil fuels have forced the energy research community seriously to consider renewable sources, such as naturally available solar energy. Thermally powered refrigeration technologies are classified into two categories: thermo-mechanical technology and sorption technology (open systems or closed systems). This paper provides a detailed review of the solar closed sorption (absorption and adsorption) refrigeration systems, which utilise working pairs (fluids). After an introduction of the basic principles of these systems, the history of development and recent advances in solar sorption refrigeration technologies are reported. The adsorption cooling typically has a lower heat source temperature requirement than the absorption cooling. Based on the coefficient of performance (COP), the absorption systems are preferred over the adsorption systems, and the higher temperature issues can be easily handled with solar adsorption systems. The thermodynamic properties of most common working fluids, as well as the use of ternary mixtures in solar-powered absorption systems, have been reviewed in this study. The paper also refers to new approaches to increase the efficiency and sustainability of the basic adsorption cycles, such as the development of hybrid or thermal energy storage adsorption systems. This research shows that solar-powered closed sorption refrigeration technologies can be attractive alternatives not only to serve the needs for air-conditioning, refrigeration, ice making, thermal

  8. Glyphosate sorption and desorption in soils with distinct phosphorus levels

    International Nuclear Information System (INIS)

    Prata, Fabio; Cardinali, Vanessa Camponez do Brasil; Tornisielo, Valdemar Luiz; Regitano, Jussara Borges; Lavorenti, Arquimedes

    2003-01-01

    The sorption of glyphosate by soils occurs due to the inner sphere complex formation with metals of soil oxides, which are related to the soil phosphate adsorption capacity. The aim of this study was to evaluate the effects of increasing rates of phosphorus on sorption and desorption of glyphosate in three soils with different mineralogical attributes. Soils were a Rhodic Kandiudalf, an Anionic Acrudox and a Typic Humaquept. Soil samples were amended with Kh 2 PO 4 at equivalent rates of 0; 1,000; 5,000; 20,000 and 50,000 kg ha -1 of P 2 O 5 , which are high from the agricultural point of view, but necessary in order to perform sorption and desorption studies. The experimental design consisted of a completely randomized factorial: 2 soils x 5 phosphorus rates and 3 replicates. For the sorption experiments, five glyphosate solutions were employed (0.42; 0.84; 1.68; 3.36 and 6.72 mg L -1 ), with a 14 C radioactivity of 0.233 kBq mL -1 . Four steps of the desorption procedures withCaCl 2 0.01 mol L -1 and one extraction with Mehlich 3 were performed only at one concentration (0.84 mol L -1 ). Soil samples were afterwards biologically oxidized to establish the radioactive balance. Glyphosate competes with phosphorus for specific sorption sites, but this competition becomes important when phosphorus is present at rates higher than 1,000 mg dm -3 . Moreover, a small amount of applied glyphosate was extracted (<10%), and the extraction increased with increasing soil phosphorus content. (author)

  9. Sorption study of U+6 in Brazilian soils

    International Nuclear Information System (INIS)

    Junior, Antonio P.; Wasserman, Maria A.V.; Mantovano, Jose L.; Carvalho, Leonel M.; Perez, Daniel V.

    2015-01-01

    The uranium mining is one of the main activities of the nuclear fuel cycle that can contribute to the increased exposure to radioactive materials and is one of the main routes of contamination of soil by natural radionuclides. This study investigated the sorption of uranium in brazilian soils, through sorption isotherms performed in batch. In this study, two types of soils were selected: Ferralsols Red and Nitosol. The adjustment of the experimental data to the kinetic models were evaluated by two approaches: the traditional, based on the coefficient of determination (R 2 ); and the theoretical and informative, based on Corrected Akaike Information Criteria (AIC C ). The coefficient of determination (R 2 ), revealed that, although empirical, both the kinetic model, Freundlich and Langmuir, describes satisfactorily the experimental data, showing R 2 values higher than 0.9, while the partition constant model was not suitable for describe these sorption data. The AICC model analysis showed that the Langmuir model fit the U sorption curve well for Ferralsols Red, while the Freundlich model fits better to Nitosol. This study has highlighted the role of organic matter on the sorption of uranium in highly weathered soils, rich in oxyhydroxides and low activity clays. The Kd values reported in this study differ from those recommended by the United States Environmental Protection Agency, therefore must be considered as reference values for highly weathered soils, since it refers to Brazilian pedoenvironmental conditions. The low Kd values obtained in this study allowed to evaluate the high vulnerability of highly weathered soils to uranium contamination. (author)

  10. THE SORPTION OF OFLOXACIN BY HYDRATED ALUMINA AND SILICON

    Directory of Open Access Journals (Sweden)

    A. N. Chebotarev

    2016-11-01

    Full Text Available The sorption of ofloxacin (OFL – the antibiotic from class of fluoroquinolones has been studied on alumina (γ-Al2O3 different acid-base modifications – acidic Al2O3(acidic, neutral Al2O3 (Neutral and the basic Al2O3 (core and amorphous silica – silica gel (SG L 5/40 and aerosil A-300. Determination of ofloxacin in solutions has been carried out by spectrophotometry on spectrophotometer SF-46 at λ = 291 nm and acidity 7. To clarify the nature of the sorption surfaces of OFL hydrated on aluminum and silicon oxides were studied according to the degree of extraction (S% from pH, contact time of the phases (min. sample from the sorbent mass (g; sorption isotherms were built and antibiotic desorption was studied. The OFL significant recovery (~ 60% is observed at the pH range of 4 ÷ 8, and reaches its maximum (80-85% at pH 7. The maximum degree of extraction of the antibiotic on aerosil A-300 and L 5/40 silica realized at pH 6 and it was ~ 80%. Comparative analysis of the forms constructed isotherms (L – type indicates a significant affinity investigated hydrated oxides to sorbate. The value of the static exchange capacity and concentration ratios can proof that. Differences in the quantitative characteristics of sorption of aluminum and silicon oxides are associated with nature and the acid-base properties of adsorption sites. In the study of the OFL concentrates desorption in static mode dilute NaOH and HNO3 solutions it was found that growth desorption degree occured with increasing concentration. Desorption was 2-3 times better in the case of aluminum oxide than silicon oxide when there were the same concentrations of acid and alkali. This is another confirmation of the participation in various sorption interactions forces of physical and chemical nature.

  11. Diffusion and sorption properties of radionuclides in compacted bentonite

    Energy Technology Data Exchange (ETDEWEB)

    Yu Ji-Wei; Neretnieks, I. [Royal Inst. of Tech., Stockholm (Sweden). Dept. of Chemical Engineering and Technology

    1997-07-01

    In this report, recent studies on sorption and diffusion of radionuclides in compacted bentonite have been reviewed. The sorption distribution coefficient and diffusion coefficient data obtained from experiments in the literature have been compiled. Based on these experimental data and the report SKB-TR--91-16 (Brandberg and Skagius, 1991), this report proposes a set of sorption distribution coefficient and diffusion coefficient values for modelling purpose for safety analysis of nuclear waste repositories. The variability and uncertainty of the diffusivity data span somewhat more than an order or magnitude up and down. Most of the nuclides have an effective diffusivity in around 10{sup -10} m{sup 2}/s. Ion exclusion effects are observed for C, Cl and for Tc in oxidizing waters. Effective diffusivities are nearly tow orders of magnitude lower for these elements and of the order of 10{sup -12} m{sup 2}/s. Surface diffusion effects are found for Cs, Ni, Pa, Pb, Ra, Sn, Sr and Zr. Effective diffusivities for these elements are of the order of 10{sup -8} m{sup 2}/s. The surface diffusion effect should decrease in saline waters which is seen for Cs and Sr where there are data available. It is also deemed that Ra will have this effect because of its similarity with Sr. The other nuclides should also show this decrease but no data is available. Sorption and diffusion mechanisms in compacted bentonite are discussed in the report. In highly compacted bentonite, sorption and hence its distribution coefficient is not well defined, and a pore diffusion coefficient or a surface diffusion coefficient is not well defined either. Therefore, an apparent diffusion coefficient and a total concentration gradient should be more relevant in describing the diffusion process in compacted bentonite. 99 refs.

  12. Sorption study of U{sup +6} in Brazilian soils

    Energy Technology Data Exchange (ETDEWEB)

    Junior, Antonio P.; Wasserman, Maria A.V.; Mantovano, Jose L.; Carvalho, Leonel M., E-mail: apjunior@ien.gov.br, E-mail: mwasserman@ien.gov.br, E-mail: mantovan@ien.gov.br, E-mail: leonel@ien.gov.br [Instituto de Engenharia Nuclear (IEN/CNEN-RJ), Rio de Janeiro, RJ (Brazil); Perez, Daniel V., E-mail: daniel@cnps.embrapa.br [Empresa Brasileira de Pesquisas Agropecuarias (Embrapa Solos-CNPS), Rio de Janeiro, RJ (Brazil)

    2015-07-01

    The uranium mining is one of the main activities of the nuclear fuel cycle that can contribute to the increased exposure to radioactive materials and is one of the main routes of contamination of soil by natural radionuclides. This study investigated the sorption of uranium in brazilian soils, through sorption isotherms performed in batch. In this study, two types of soils were selected: Ferralsols Red and Nitosol. The adjustment of the experimental data to the kinetic models were evaluated by two approaches: the traditional, based on the coefficient of determination (R{sup 2}); and the theoretical and informative, based on Corrected Akaike Information Criteria (AIC{sub C}). The coefficient of determination (R{sup 2}), revealed that, although empirical, both the kinetic model, Freundlich and Langmuir, describes satisfactorily the experimental data, showing R{sup 2} values higher than 0.9, while the partition constant model was not suitable for describe these sorption data. The AICC model analysis showed that the Langmuir model fit the U sorption curve well for Ferralsols Red, while the Freundlich model fits better to Nitosol. This study has highlighted the role of organic matter on the sorption of uranium in highly weathered soils, rich in oxyhydroxides and low activity clays. The Kd values reported in this study differ from those recommended by the United States Environmental Protection Agency, therefore must be considered as reference values for highly weathered soils, since it refers to Brazilian pedoenvironmental conditions. The low Kd values obtained in this study allowed to evaluate the high vulnerability of highly weathered soils to uranium contamination. (author)

  13. Effect of Suez Canal Marine Sediment on Sorption of Cesium

    International Nuclear Information System (INIS)

    Hassan, H.B.

    2016-01-01

    Suez Canal is surrounded by navigation, industrial, agricultural activities and suffers from high rate of population growth that discharging waste into Suez Canal. The Suez Canal coastal waters are influenced by a complex variety of physical, geochemical and biological processes, which influence the behavior, transport and fate of containments released into the marine environment. Sorption of releasing containment such as cesium in Suez Canal water is investigated because of its toxic effect on the marine environment. The object of present study is to determine the effects some of physical and chemical characteristics of collected sediment samples from the three important locations on Suez Canal (Suez Bay, Bitter Lakes and El- Temsah Lake beaches) on sorption behavior of cesium by using batch experiment. Batch experiment was used to study the sorption of the cesium ion. The sorption process is dependent on mineral constituents of Suez Canal sediment and their characteristics. Analytical methods which included particle size and X-ray diffraction (XRD) analyses found that particle size of Suez Canal sediment samples is characterized by sand to fine sand and quartz is the main mineralogical species. Distribution coefficient (K d ) which represent geochemical processes and particle size of these sediment samples effect on the degree of cesium sorption to the sediment. Also (K d ) increase with increase cation exchangeable capacity (CEC). The Suez Canal sediment samples have low (K d ) values which effected by their physical and chemical properties. Sample (2) has highest distribution coefficient (K d ) between measured samples due to containing ratio 30% of fine sand and high ratio of organic matter.

  14. Temperature and curing time affect composite sorption and solubility

    Directory of Open Access Journals (Sweden)

    Fabrício Luscino Alves de Castro

    2013-04-01

    Full Text Available Objective: This study evaluated the effect of temperature and curing time on composite sorption and solubility. Material and Methods: Seventy five specimens (8×2 mm were prepared using a commercial composite resin (ICE, SDI. Three temperatures (10°C, 25°C and 60°C and five curing times (5 s, 10 s, 20 s, 40 s and 60 s were evaluated. The specimens were weighed on an analytical balance three times: A: before storage (M1; B: 7 days after storage (M2; C: 7 days after storage plus 1 day of drying (M3. The storage solution consisted of 75% alcohol/25% water. Sorption and solubility were calculated using these three weights and specimen dimensions. The data were analyzed using the Kruskal-Wallis and Mann-Whitney U Tests (α=5%. Results: The results showed that time, temperature and their interaction influenced the sorption and solubility of the composite (p0.05. The 60°C composite temperature led to lower values of sorption for all curing times when compared with the 10°C temperature (p0.05. Solubility was similar at 40 s and 60 s for all temperatures (p>0.05, but was higher at 10°C than at 60°C for all curing times (p0.05. Conclusions: In conclusion, higher temperatures or longer curing times led to lower sorption and solubility values for the composite tested; however, this trend was only significant in specific combinations of temperature and curing times.

  15. Glyphosate sorption and desorption in soils with distinct phosphorus levels

    Energy Technology Data Exchange (ETDEWEB)

    Prata, Fabio [BIOAGRI Labs., Piracicaba, SP (Brazil). Div. de Quimica. Lab. de Radioquimica; Cardinali, Vanessa Camponez do Brasil; Tornisielo, Valdemar Luiz; Regitano, Jussara Borges [Sao Paulo Univ., Piracicaba, SP (Brazil). Escola Superior de Agricultura Luiz de Queiroz. Dept. de Ciencias Exatas; Lavorenti, Arquimedes [Centro de Energia Nuclear na Agricultura (CENA), Piracicaba, SP (Brazil). Secao de Toxicologia

    2003-03-01

    The sorption of glyphosate by soils occurs due to the inner sphere complex formation with metals of soil oxides, which are related to the soil phosphate adsorption capacity. The aim of this study was to evaluate the effects of increasing rates of phosphorus on sorption and desorption of glyphosate in three soils with different mineralogical attributes. Soils were a Rhodic Kandiudalf, an Anionic Acrudox and a Typic Humaquept. Soil samples were amended with Kh{sub 2}PO{sub 4} at equivalent rates of 0; 1,000; 5,000; 20,000 and 50,000 kg ha{sup -1} of P{sub 2}O{sub 5}, which are high from the agricultural point of view, but necessary in order to perform sorption and desorption studies. The experimental design consisted of a completely randomized factorial: 2 soils x 5 phosphorus rates and 3 replicates. For the sorption experiments, five glyphosate solutions were employed (0.42; 0.84; 1.68; 3.36 and 6.72 mg L{sup -1}), with a {sup 14}C radioactivity of 0.233 kBq mL{sup -1}. Four steps of the desorption procedures withCaCl{sub 2} 0.01 mol L{sup -1} and one extraction with Mehlich 3 were performed only at one concentration (0.84 mol L{sup -1}). Soil samples were afterwards biologically oxidized to establish the radioactive balance. Glyphosate competes with phosphorus for specific sorption sites, but this competition becomes important when phosphorus is present at rates higher than 1,000 mg dm{sup -3}. Moreover, a small amount of applied glyphosate was extracted (<10%), and the extraction increased with increasing soil phosphorus content. (author)

  16. Influence of light-weight organic matters on strontium sorption to bentonite

    International Nuclear Information System (INIS)

    Wang, Tsing-Hai; Wu, Ding-Chiang; Teng, Shi-Ping

    2010-01-01

    Document available in extended abstract form only. Light-weight organic matters were frequently observed in groundwater. Their existence had significant influence on the transport of radionuclides. In this study, light-weight organic acid species including oxalic (MW 90), succinic (MW 118), adipic (MW 146), azelaic (MW 188), eicosanedioic (MW 306), benzoic (MW 122), salicylic (MW 138), and gallic (MW 170) were selected as the surrogate of natural organic matters. Their effects on strontium sorption to bentonite were evaluated by using a surface complexation model MINEQL+. Under this framework, three sorption mechanisms were considered: 1. structure sorption sites, 2. edge sorption sites, 3. further hydration of adsorbed Sr 2+ . The presence of organic species had no influence on Sr cation sorption to structure sorption sites. However, Sr cation sorption to edge sorption was affected by the organics to certain extent. For example, sorption capability of edge sites toward Sr was increased by the gallic species. Furthermore, hydration of adsorbed Sr was significantly affected by the presence of organic species. This might relate to that adsorbed Sr would become the bridge associating organic species on bentonite surfaces, but this argument required more solid spectral evidences to support. Some preliminary observations on Sr sorption to bentonite were obtained in this work; however, further experiments are still required by conducting experiments with more variety of organic species. By doing a comprehensive study, it would be much beneficial to make a more accurate evaluation of the influence of organic matters on Sr sorption

  17. A study of selenium and tin sorption on granite and geothite

    International Nuclear Information System (INIS)

    Ticknor, K.V.; McMurry, J.

    1996-01-01

    Sensitivity analyses based on an illustrative performance assessment case study of a disposal concept for nuclear fuel waste have shown that radioisotopes of Se and Sn could have a significant effect on cumulative radioactive dose if they were to be transported through the geosphere without retardation. Static batch sorption methods, coupled with 2 n factorial experimental designs, were used to determine the extent to which Se and Sn can be sorbed by granite and goethite as a function of total dissolved solids concentration, [TDS], natural fulvic acid concentration as dissolved organic carbon, [DOC], pH and, for the studies with Se, the Se concentration, [Se]. Aqueous speciation and the saturation indices of solubility-controlling solid phases were estimated using the speciation code HARPHRQ with the HATCHES thermodynamic database. The experimental results indicated that Se sorption on granite was, low and not affected by changes in [DOC] or [TDS]. Increased [Se] and increased pH decreased sorption. For Se sorption on goethite, the pH range was narrow but indicated that sorption decreased as pH increased. Increased [TDS] and [Se] lowered sorption on goethite, but changes in [DOC] had no effect on sorption. For Sn, increased pH, [TDS] and [DOC] decreased sorption on granite. For Sn sorption on goethite, increased [DOC] resulted in decreased sorption, but differences in [TDS] and pH had little consistent effect on sorption. (orig.)

  18. A study of selenium and tin sorption on granite and goethite

    International Nuclear Information System (INIS)

    Ticknor, K.V.; McMurry, J.

    1996-01-01

    Sensitivity analyses based on an illustrative performance assessment case study of a disposal concept for nuclear fuel waste have shown that radioisotopes of Se and Sn could have a significant effect on cumulative radioactive dose if they were to be transported through the geosphere without retardation. Static batch sorption methods, coupled with 2 n factorial experimental designs, were used to determine the extent to which Se and Sn can be sorbed by granite and goethite as a function of total dissolved solids concentration, (TDS), natural fulvic acid concentration as dissolved organic carbon, [DOC], pH and, for the studies with Se, the Se concentration, [Se]. Aqueous speciation and the saturation indices of solubility-controlling solid phases were estimated using the speciation code HARPHRQ with the HATCHES thermodynamic database. The experimental results indicated that Se sorption on granite was low and not affected by changes in [DOC] or [TDS]. Increased [Se] and increased pH decreased sorption. For Se sorption on goethite, the pH range was narrow but indicated that sorption decreased as pH increased. Increased [TDS] and [Se] lowered sorption on goethite, but changes in (DOC] had no effect on sorption. For Sn, increased pH, [TDS] and [DOC] decreased sorption on granite. For Sn sorption on goethite, increased [DOC] resulted in decreased sorption, but differences in [TDS] and pH had little consistent effect on sorption. (author)

  19. Experimental measurements and integrated modelling studies of actinide sorption onto cement

    International Nuclear Information System (INIS)

    Sugiyama, Daisuke; Fujita, Tomonari; Baston, G.M.N.

    2003-01-01

    An Integrated Cement Sorption Model (ICSM) for actinides onto Ordinary Portland Cement (OPC) is developed. The experimental measurements using the batch sorption technique for actinides onto cement and constituent minerals, which were considered in the modelling calculations, are also described. The actinide elements studied (thorium, uranium, neptunium, plutonium and americium) were strongly sorbed onto OPC. An initial comparison of the experimental data relating the sorption values of actinides onto cement-component phases with those onto OPC is carried out. The results suggest that the Calcium Silicate Hydrate (C-S-H) phases were found to be the most likely candidates to be the dominant-sorbing phases in order to describe the sorption of a actinides onto OPC. An approach to develop the integrated cement sorption model, based on a thermodynamic surface complexation model, is described with discussions on the possible mineralogy and phase distribution of OPC. Another approach than sorption, assuming that co-precipitation on the surface of the cement phase dominates 'sorption', is proposed and discussed. A scoring system is introduced to assess the applicability of the proposed ICSMs. It is suggested that the thermodynamic sorption model is recommended for the sorption of ionic species and the surface co-precipitation model is recommended for the sorption of neutral species though the sorption model is still recommended to be used to model OPC-based systems. (author)

  20. Effect of Cosolutes on the Sorption of Phenanthrene onto Mineral Surface of River Sediments and Kaolinite

    Directory of Open Access Journals (Sweden)

    Yinghong Wu

    2014-01-01

    Full Text Available Sorption of phenanthrene onto the natural sediment with low organic carbon content (OC%, organic-free sediment, and kaolinite was investigated through isotherm experiments. Effects of cosolutes (pyrene, 4-n-nonyphenol (NP, and humic acid (HA on phenanthrene sorption were also studied by comparing apparent solid-water distribution coefficients (Kdapp of phenanthrene. Two addition sequences, including “cosolute added prior to phenanthrene” and “cosolute and phenanthrene added simultaneously,” were adopted. The Freundlich model fits phenanthrene sorption on all 3 sorbents well. The sorption coefficients on these sorbents were similar, suggesting that mineral surface plays an important role in the sorption of hydrophobic organic contaminants on low OC% sediments. Cosolutes could affect phenanthrene sorption on the sorbents, which depended on their properties, concentrations, and addition sequences. Pyrene inhibited phenanthrene sorption. Sorbed NP inhibited phenanthrene sorption at low levels and promoted sorption at high levels. Similar to NP, effect of HA on phenanthrene sorption onto the natural sediment depended on its concentrations, whereas, for the organic-free sediment and kaolinite, preloading of HA at high levels led to an enhancement in phenanthrene Kdapp while no obvious effect was observed at low HA levels; dissolved HA could inhibit phenanthrene sorption on the two sorbents.