WorldWideScience

Sample records for reported bond distances

  1. Distance Protection of Cross-Bonded Transmission Cable-Systems

    DEFF Research Database (Denmark)

    Bak, Claus Leth; F. Jensen, Christian

    2014-01-01

    In this paper the problems of protecting a cross-bonded cable system using distance protection are analysed. The combination of the desire to expand the high voltage transmission grid and the public's opinion towards new installations of overhead lines (OHL), more and more transmission cable syst...

  2. Shear bond strength of bonding to enamel with different laser irradiation distances.

    Science.gov (United States)

    Başaran, Güvenç; Hamamcı, Nihal; Akkurt, Atılım

    2011-03-01

    The aim of this study was to investigate the shear bond strength of bonding to enamel following laser etching with the Er:YAG or Er,Cr:YSGG laser using different irradiation distances. Of 99 extracted human premolar teeth, 90 were divided equally into nine groups. In the control group (group A) the teeth were etched with 38% phosphoric acid. In the laser groups (groups B-I) the enamel surface of the teeth was laser-irradiated, groups B-E with the Er:YAG laser and groups F-I with the Er,Cr:YSGG laser at distances of 1, 2, 4 and 6 mm, respectively. The shear bond strengths were tested using a universal testing machine. The shear bond strengths associated with the Er:YAG laser at 4 and 6 mm and the Er,Cr:YSGG laser at 2, 4 and 6 mm were significantly less than the strengths obtained with the other irradiation distances (penamel in the same manner (p>0.05). This finding was confirmed by scanning electron microscopy examination. Irradiation distance did influence the strength of adhesion to enamel. The mean shear bond strengths and enamel surface etching obtained with the Er:YAG laser at 1 and 2 mm and the Er,Cr:YSGG laser at 1 mm were comparable to that obtained with acid etching.

  3. Bond-specific dissociation following excitation energy transfer for distance constraint determination in the gas phase.

    Science.gov (United States)

    Hendricks, Nathan G; Lareau, Nichole M; Stow, Sarah M; McLean, John A; Julian, Ryan R

    2014-09-24

    Herein, we report chemistry that enables excitation energy transfer (EET) to be accurately measured via action spectroscopy on gaseous ions in an ion trap. It is demonstrated that EET between tryptophan or tyrosine and a disulfide bond leads to excited state, homolytic fragmentation of the disulfide bond. This phenomenon exhibits a tight distance dependence, which is consistent with Dexter exchange transfer. The extent of fragmentation of the disulfide bond can be used to determine the distance between the chromophore and disulfide bond. The chemistry is well suited for the examination of protein structure in the gas phase because native amino acids can serve as the donor/acceptor moieties. Furthermore, both tyrosine and tryptophan exhibit unique action spectra, meaning that the identity of the donating chromophore can be easily determined in addition to the distance between donor/acceptor. Application of the method to the Trpcage miniprotein reveals distance constraints that are consistent with a native-like fold for the +2 charge state in the gas phase. This structure is stabilized by several salt bridges, which have also been observed to be important previously in proteins that retain native-like structures in the gas phase. The ability of this method to measure specific distance constraints, potentially at numerous positions if combined with site-directed mutagenesis, significantly enhances our ability to examine protein structure in the gas phase.

  4. Influence of charge and coordination number on bond dissociation energies, distances, and vibrational frequencies for the phosphorus-phosphorus bond.

    Science.gov (United States)

    Chitnis, Saurabh S; Whalen, J Marc; Burford, Neil

    2014-09-01

    We report a comprehensive and systematic experimental and computational assessment of the P-P bond in prototypical molecules that represent a rare series of known compounds. The data presented complement the existing solid-state structural data and previous computational studies to provide a thorough thermodynamic and electronic understanding of the P-P bond. Comparison of homolytic and heterolytic bond dissociation for tricoordinate-tricoordinate, tricoordinate-tetracoordinate, and tetracoordinate-tetracoordinate P-P bonds in frameworks 1-6 provides fundamental insights into covalent bonding. For all types of P-P bond discussed, homolytic dissociation is favored over heterolytic dissociation, although the distinction is small for 2(1+) and 6(1+). The presence of a single cationic charge in a molecule substantially strengthens the P-P bond (relative to analogous neutral frameworks) such that it is comparable with the C-C bond in alkanes. Nevertheless, P-P distances are remarkably independent of molecular charge or coordination number, and trends in values of d(PC) and νsymm(PC) imply that a molecular cationic charge is distributed over the alkyl substituents. In the gas phase, the diphosphonium dication 3(2+) has similar energy to two [PMe3](+) radical cations, so that it is the lattice enthalpy of 3[OTf]2 in the solid-state that enables isolation, highlighting that values from gas-phase calculations are poor guides for synthetic planning for ionic compounds. There are no relationships or correlations between bond lengths, strengths, and vibrational frequencies.

  5. On the Correlation between the Blue Shift of Hydrogen Bonding and the Proton Donor-Proton Acceptor Distance

    Institute of Scientific and Technical Information of China (English)

    WANG,Jin-Ti(王金姼); FENG,Yong(封勇); LIU,Lei(刘磊); LI,Xiao-Song(李晓松); GUO,Qing-Xiang(郭庆祥)

    2004-01-01

    It is demonstrated that in all types of hydrogen bonds (X-H…Y) there is a balance between the long-range attractive orbital interactions and short-range Pauli/nucleus repulsions. When the proton acceptor approaches the proton donor from distance, the hydrogen bonding energy becomes more negative at relatively large distance, goes through a minimum, and then starts to become less negative when the short-range repulsive forces come into effect.Meanwhile, the X-H bond length increases at relatively large distances, goes through a maximum and starts to shorten when the short-range repulsive forces come into effect. Whether the hydrogen bond is red or blue shifted is dictated by the energy minimum position. If at the energy minimum position the X-H bond length is shorter than that for the free monomer, the hydrogen bond is blue shifted and vice versa. Further studies demonstrate that the recent report about the correlation of C-H bond lengths with proton donor-acceptor distance in F3C-H…OH2 and F3C-H…Cl- is not fully correct because the authors conducted an inappropriate comparison. Furthermore, it is shown for the first time that the Pauli/nucleus repulsion theory is applicable to the blue-shifted hydrogen bonds in the X-H…π complexes and the blue-shifted lithium bonds in the X-Li…Y complexes.

  6. Distance Education Report, 2011-2012

    Science.gov (United States)

    California Community Colleges, Chancellor's Office, 2013

    2013-01-01

    This is a report on distance education in the California Community College. This is the seventh report to the California Community Colleges Board of Governors (BOG) per BOG Standing Order 409 (b) "that evaluates the effectiveness of distance education and education technology system wide and provides analysis of data demographically (by age,…

  7. Validity of Self-Reported Running Distance.

    Science.gov (United States)

    Dideriksen, Mette; Soegaard, Cristina; Nielsen, Rasmus O

    2016-06-01

    It is unclear whether there is a difference between subjective evaluation and objective global positioning systems (GPS) measurement of running distance. The purpose of this study was to investigate if such difference exists. A total of 100 participants (51% men; median age, 41.5; body mass, 78.1 kg ±13.8 SD) completed a run of free choice, then subjectively reported the distance in kilometer (km). This information was subsequently compared with the distance derived from a nondifferential GPS watch using paired t-tests and Bland-Altman's 95% limits of agreement. No significant difference was found between the mean paired differences between subjective evaluations and GPS measurements (1.86%, 95% confidence interval = -1.53%; 5.25%, p = 0.96). The Bland-Altman 95% limits of agreement revealed considerable variation (lower limit = -28% and upper limit = 40%). Such variation exceeds the clinical error range of 10%. In conclusion, the mean running distance (km) is similar between self-reporting and GPS measurements. However, researchers should consider using GPS measurements in favor of subjective reporting of running distance because of considerable variation on an individual level.

  8. Space-efficient path-reporting approximate distance oracles

    DEFF Research Database (Denmark)

    Elkin, Michael; Neiman, Ofer; Wulff-Nilsen, Christian

    2016-01-01

    We consider approximate path-reporting distance oracles, distance labeling and labeled routing with extremely low space requirements, for general undirected graphs. For distance oracles, we show how to break the nlog⁡n space bound of Thorup and Zwick if approximate paths rather than distances need...

  9. Research in Distance Education: A Status Report

    Directory of Open Access Journals (Sweden)

    Farhad Saba

    2000-06-01

    Full Text Available Since the 1950s and expansion of social science research, distance education has been studied in comparison to face-to-face or classroom instruction. Although researchers continue to conduct comparative studies, their usefulness in revealing more information has diminished over the years; invariably, they have returned a “no significant difference” result between various forms of instruction. In recent years, researchers have moved beyond atheoretical, experimental comparative studies and have introduced new methods, such as discourse analysis, and in-depth interview of learners. These new methods overcome many methodological and theoretical limitations of the physical science view of distance education. These studies have further revealed the complexity of distance education, indicating the many variables involved in the concept. Starting with the core issue of instructional interaction and grounded on the theory of transactional distance, a new strand of research using methods related to systems dynamics, hierarchy and complexity theories, promises a more comprehensive understanding.

  10. Raman spectroscopy of supported chromium oxide catalysts : determination of chromium-oxygen bond distances and bond orders

    NARCIS (Netherlands)

    Weckhuysen, B.M.; Wachs, I.E.

    1996-01-01

    An empirical correlation is described for relating Raman stretching frequencies of chromium—oxygen (Cr—O) bonds to their bond lengths in chromium oxide reference compounds. An exponential fit of crystallographically determined Cr—O bond lengths to Cr—O Raman symmetric stretching frequencies (800–130

  11. Relationship between ionoluminescence emission and bond distance (M-O) in carbonates

    Energy Technology Data Exchange (ETDEWEB)

    Calvo del Castillo, H. [Universidad Autonoma de Madrid, Fac. Ciencias, Dpto. Qca. Agricola, Geologia y Geoquimica, 28049, Cantoblanco, Madrid (Spain); Sil, J.L. Ruvalcaba [Universidad Nacional Autonoma de Mexico, Instituto de Fisica, 04510 Ciudad Universitaria, Mexico, DF (Mexico)]. E-mail: sil@fisica.unam.mx; Alvarez, M.A. [Universidad de Sevilla, Dpto. Qca. Agricola y Cristalografia, Fac. de Quimica, Sevilla (Spain); Beneitez, P. [Universidad Autonoma de Madrid, Fac. Ciencias, Dpto. Qca.-Fisica Aplicada, 28049, Cantoblanco, Madrid (Spain); Millan, M.A. [Universidad Autonoma de Madrid, Fac. Ciencias, Dpto. Qca. Agricola, Geologia y Geoquimica, 28049, Cantoblanco, Madrid (Spain); Calderon, T. [Universidad Autonoma de Madrid, Fac. Ciencias, Dpto. Qca. Agricola, Geologia y Geoquimica, 28049, Cantoblanco, Madrid (Spain)

    2006-08-15

    Ionoluminescence emission spectra induced by 2 MeV protons are reported for a range of carbonates. A major feature in these spectra, are the Mn{sup 2+} luminescence centres that appear within all the samples. The emission wavelengths for the Mn{sup 2+} are linearly correlated to the metal-oxygen bonding length, both in rhombohedral and orthorhombic lattices for the minerals studied. The Mn{sup 2+} band, is in each case related to the corresponding energy level diagram of the mineral's crystal lattice, as this ion perturbs the crystal field term, which for emission in rhombohedral calcite has a value of 1000 cm{sup -1}, and for orthorhombic sites in aragonite is 1200 cm{sup -1}.

  12. Evaluation of hydrogen-bonding distance in organic nonlinear optical crystals for high-output terahertz-wave generation

    Science.gov (United States)

    Matsukawa, Takeshi; Hoshikawa, Akinori; Ishikawa, Yoshihisa; Ishigaki, Toru

    2017-04-01

    The crystal structure of deuterated 4-dimethylamino-N-methyl-4-stilbazolium tosylate (DAST-d26) was obtained by powder X-ray and neutron diffraction measurements. The scattering length density distributions of deuterium atoms were successfully obtained from neutron diffraction data using the maximum-entropy method. From the density distributions, we estimated the hydrogen-bonding distances, which contribute significantly to the vibrational modes of DAST at 1 THz. Inhibition of these hydrogen bonds could allow the development of new nonlinear optical materials with low THz absorption.

  13. Perturbation calculations on the variation of hydrogen---bond energies with intermolecular distance

    NARCIS (Netherlands)

    Duijneveldt-van de Rijdt, J.G.C.M. van; Duijneveldt, F.B. van

    1968-01-01

    In previous perturbation calculations on the hydrogen bond [6] the short-range repulsion was seriously underestimated. It is shown that this can be remedied by choosing a more realistic model system and using exact 3-centre integrals.

  14. Quality and Standards in Distance Education. Report to the National Distance Education Conference.

    Science.gov (United States)

    Nunan, Ted; Calvert, Jocelyn

    A study to examine quality and standards in distance education identified the elements of quality, indicators that would signify their achievement, and processes that foster the achievement of quality. It focused on perceptions of quality of particular stakeholders. Documentation provided by institutions showed that they define and determine what…

  15. University of the West Indies Distance Teaching Experiment (UWIDITE). Report.

    Science.gov (United States)

    Lalor, Gerald C.; Marrett, Christine

    Since March 1983, the University of the West Indies has been conducting a distance teaching experiment that links its three campuses and the Extra Mural Centres in Antigua, Dominica, and St. Lucia by telecommunications. The network is used for interactive distance teaching and other types of teleconferences. A variety of modern audio and video…

  16. Bridging the Distance: A Report on Four Distance Education Workshops Held February 1991 = La distance apprivoisee: Un rapport de quatre ateliers sur la formation a distance tenus en feview 19911.

    Science.gov (United States)

    McGreal, Rory; And Others

    This report summarizes activities and recommendations from workshops in Northern Ontario, Canada which were designed to inform principals of the details of the distance education initiative and to examine problems involved in the delivery and reception of distance education courses at the secondary level. Separate workshops were organized for…

  17. Computer Conferencing and Mass Distance Education. CITE Report No. 98.

    Science.gov (United States)

    Kaye, Anthony R.

    This paper briefly reviews the first large-scale use of computer mediated communication (CMC) at the Open University (OU) in Milton Keynes, England, including computer conferencing and electronic mail, in an adjunct mode on a multimedia distance education course with 1,500 students. The first part of the paper outlines the rationale for…

  18. Non-monotonic, distance-dependent relaxation of water in reverse micelles: propagation of surface induced frustration along hydrogen bond networks.

    Science.gov (United States)

    Biswas, Rajib; Chakraborti, Tamaghna; Bagchi, Biman; Ayappa, K G

    2012-07-07

    Layer-wise, distance-dependent orientational relaxation of water confined in reverse micelles (RM) is studied using theoretical and computational tools. We use both a newly constructed "spins on a ring" (SOR) Ising-type model (with Shore-Zwanzig rotational dynamics) and atomistic simulations with explicit water. Our study explores the effect of reverse micelle size and role of intermolecular correlations, compromised by the presence of a highly polar surface, on the distance (from the interface) dependence of water relaxation. The "spins on a ring" model can capture some aspects of distance dependence of relaxation, such as acceleration of orientational relaxation at intermediate layers. In atomistic simulations, layer-wise decomposition of hydrogen bond formation pattern clearly reveals that hydrogen bond arrangement of water at a certain distance away from the surface can remain frustrated due to the interaction with the polar surface head groups. This layer-wise analysis also reveals the presence of a non-monotonic slow relaxation component which can be attributed to this frustration effect and which is accentuated in small to intermediate size RMs. For large size RMs, the long time component decreases monotonically from the interface to the interior of the RMs with slowest relaxation observed at the interface.

  19. Atomic volume, atomic distances and chemical bonding in solid metallic elements; Atomvolumen, Atomabstaende und chemische Bindung in festen metallischen Elementen

    Energy Technology Data Exchange (ETDEWEB)

    Troemel, M.; Huebner, S. [Frankfurt Univ. (Germany). Inst. fuer Anorganische Chemie

    2001-05-01

    Relationships between bond lengths and bond numbers and also between atomic volumes and valencies are derived and parameters for their calculation are given for the s-block, p-block, and d-block metals. From the atomic volumes under pressure, the valencies of three solid lanthanoids have been confirmed or redetermined: La 3; Ce 2, 3, and 4; Yb 2 and 3. (orig.)

  20. Technical Evaluation Report 39: Marriage Mentorship at a Distance

    Directory of Open Access Journals (Sweden)

    Harry Doxsee

    2004-11-01

    Full Text Available Marriage mentorship is one of the most effective methods through which a couple can enrich their marriage. A good mentorship relationship is based on feelings of warmth and affinity between mentors and mentees. When a relationship of trust is established, the mentees feel more freedom to express their deeper feelings and to explore new paths of mutual understanding. In what ways does the quality of interaction change when mentors and mentees interact via a technological medium such as online audio-conferencing? This paper compares three marriage mentoring experiences that employed online conferencing as the medium of interaction. Audio-conferencing methods provided a particularly warm, trusting interaction between participants, and an effective environment for learning and for practicing communication skills. The paper makes recommendations for efficient online mentoring practice, and builds on a previous discussion of online practice in the community advocacy context (Report #35 in this series.

  1. Adult Attachment and Parental Bonding: Correlations between Perceived Relationship Qualities and Self-Reported Anxiety

    Science.gov (United States)

    Ambruster, Ellen W.; Witherington, David C.

    2016-01-01

    Adult attachment and parental bonding have been linked to anxiety disorders, but rarely have these associations been demonstrated in the same study. To fill this gap in the research literature, we utilized several different self-report measures to examine the relationships among adult attachment style, memories of early bonding experiences, and…

  2. Management of Limited Interocclusal Distance with the Aid of a Modified Surgical Guide: A Clinical Report

    Directory of Open Access Journals (Sweden)

    Farideh Geramipanah

    2017-08-01

    Full Text Available In completely edentulous patients, limited interarch distance can compromise conventional prosthetic fabrication. Bone reduction through various surgical procedures has been recommended to restore an acceptable interarch distance. In such circumstances, a surgical guide built on a mounted cast can be used to minimize and control the amount of bone reduction performed. In the present report, an innovative method of fabrication of surgical guide has been described.Keywords: Osteotomy; Stents; Dental Articulators; Denture, Complete

  3. The University of the West Indies Distance Teaching Project. Report to the Advisory Council. ACEP 7.

    Science.gov (United States)

    Lalor, Gerald C.

    The three papers in this report relate to the development and activities of the University of the West Indies Distance Teaching Project (UWIDITE), through which the University of the West Indies (UWI) is continuing experiments on the use of telecommunications to extend its regional services. A report to the advisory council, the first paper,…

  4. Biotic and abiotic carbon to sulfur bond cleavage. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Frost, J.W.

    1994-05-01

    The microbial desulfurization of organosulfur compounds occurs by unprecedented and largely unexplored biochemical processes. A study of such biotic desulfurizations can be expected to give rise to new and useful chemistry and enzymology. The potential value of understanding and harnessing these processes is seen in relation to the need for methods for the removal of organically bound sulfur from coal and the degradation of organic sulfur-containing pollutants. This research effort has been directed towards an examination of desulfurization ability in well characterized microorganisms, the isolation of bacteria with desulfurization ability from natural sources, the characterization and mechanistic evaluation of the observed biocatalytic processes, the development of biomimetic synthetic organic chemistry based on biotic desulfurization mechanisms and the design and preparation of improved coal model compounds for use in microbial selection processes. A systematic approach to studying biodesulfurizations was undertaken in which organosulfur compounds have been broken down into classes based on the oxidation state of the sulfur atom and the structure of the rest of the organic material. Microbes have been evaluated in terms of ability to degrade organosulfur compounds with sulfur in its sulfonic acid oxidation state. These compounds are likely intermediates in coal desulfurization and are present in the environment as persistent pollutants in the form of detergents. It is known that oxygen bonded to sulfur lowers the carbon-sulfur bond energy, providing a thermodynamic basis for starting with this class of compounds.

  5. Bonding distances as Exact Sums of the Radii of the Constituent Atoms in Nanomaterials - Boron Nitride and Coronene

    CERN Document Server

    Heyrovska, Raji

    2010-01-01

    This paper presents for the first time the exact structures at the atomic level of two important nanomaterials, boron nitride and coronene. Both these compounds are hexagonal layer structures similar to graphene in two dimensions and to graphite in three-dimensions. However, they have very different properties: whereas graphene is a conductor, h-BN is an electrical insulator and coronene is a polycyclic aromatic hydrocarbon of cosmological interest. The atomic structures presented here are based on bond lengths as the sums of the atomic radii.

  6. "Long-distance" H/D isotopic self-organization phenomena in scope of the infrared spectra of hydrogen-bonded terephthalic and phthalic acid crystals

    Science.gov (United States)

    Flakus, Henryk T.; Hachuła, Barbara.; Hołaj-Krzak, Jakub T.; Al-Agel, Faisal A.; Rekik, Najeh

    2017-02-01

    This paper deals with the experimental and theoretical studies of abnormal properties of terephthalic acid (TAC) and phthalic acid (PAC) crystals manifested in the H/D isotopic exchange. The widely utilized deuteration routine appeared to be insufficiently effective in the case of the h6-TAC isotopomer. In the case of the d4-TAC derivative the isotopic exchange process occurred noticeably more effectively. In contrast, both isotopomers of PAC, h6 and d4, appeared much more susceptible for deuteration. A theoretical model was elaborated describing "long-distance" dynamical co-operative interactions involving hydrogen bonds in TAC and PAC crystals. The model assumes extremely strong dynamical co-operative interactions of hydrogen bonds from the adjacent (COOH)2 cycles. This leads to an additional stabilization of h6-TAC molecular chains. The interaction energies affect the chemical equilibrium of the H/D isotopic exchange. The model predicts a differentiated influence of the H and D atoms linked to the aromatic rings on to the process. In this approach the totally-symmetric Csbnd H bond stretching vibrations and the proton stretching totally symmetric vibrations couple with the π-electronic motions. It was also shown that identical hydrogen isotope atoms, H or D, in whole TAC molecules, noticeably enlarge the energy of the dynamical co-operative interactions in the crystals, in contrast to the case of different hydrogen isotopes present in the carboxyl groups and linked to the aromatic rings. The "long-distance" dynamical co-operative interactions in PAC crystals were found of a minor importance due to the electronic properties of PAC molecules.

  7. Phosphate-bonded glass cements for geothermal wells. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Rockett, T.J.

    1979-09-01

    Calcium aluminosilicate glasses were found to react with phosphoric acid in three ways depending upon silica content. Above 55% SiO/sub 2/ they are insoluble while below 50% they dissolve readily. The transition compositions release calcium and aluminum ions and a silica gel phase replaces the glass. Activation energies in the order of 10 kcal/mole are associated with the dissolution. Equilibrium studies in the systems CaO-P/sub 2/O/sub 5/-H/sub 2/O, Al/sub 2/O/sub 3/-P/sub 2/O/sub 5/-H/sub 2/O, and CaO-Al/sub 2/O/sub 3/-P/sub 2/O/sub 5/-H/sub 2/O were made to determine the phases which are stable at 200/sup 0/C in excess water. The CaO system shows hydroxylapatite, monetite and monocalcium orthophosphate are the stable phases. The Al/sub 2/O/sub 3/ system contains augelite, berlinite, and a high phosphate aluminum hydrate. The quaternary system shows the above phase plus a lime alumina hydrogarnet and crandallite. Cement made from a glass frit of the composition 45% SiO/sub 2/: 24% CaO: 24% Al/sub 2/O/sub 3/ has a compressive strength of 500 psi after several days in steam at 200/sup 0/C and 800 psi after months in steam. Bonding of cements to mild steel are discussed.

  8. A steerable/distance enhanced penetrometer delivery system: Phase II. Topical report

    Energy Technology Data Exchange (ETDEWEB)

    Amini, A.; Shenhar, J.; Lum, K.D.

    1996-05-01

    This report summarizes the phase II work on the Position Location Device (POLO) for penetrometers. Phase II was carried out to generate an integrated design of a full-scale steerable/distance enhanced penetrometer delivery system. Steering provides for the controlled and directional use of the penetrometer, while vibratory thrusting can provide greater penetration ability.

  9. Final Technical Report: Discovering the Nature of Dark Energy: Towards Better Distances from Type Ia Supernovae

    Energy Technology Data Exchange (ETDEWEB)

    Saurabh W. Jha

    2012-10-03

    The final technical report from the project "Discovering the Nature of Dark Energy: Towards Better Distances from Type Ia Supernovae" led at Rutgers the State University of New Jersey by Prof. Saurabh W. Jha is presented, including all publications resulting from this award.

  10. Long-distance inter-hydrogen bond coupling effects in the polarized IR spectra of succinic acid crystals

    Science.gov (United States)

    Flakus, Henryk T.; Hachuła, Barbara; Hołaj-Krzak, Jakub T.

    2015-05-01

    The spectral properties of four different crystalline succinic acid (HOOC-(CH2)2-COOH) (SAC) isotopomer systems, h6, d2, d4 and d6, were examined by means of the IR spectroscopy in polarized light aided by numerical simulations of the νO-H and νO-D band contour shapes on utilizing the "strong-coupling" model. The abnormal IR spectral properties of SAC crystals in relation to the corresponding properties of glutaric, pimelic and adipic acid crystals were ascribed to the hyperconjugation electronic effects in the acid associated molecules. A vibronic coupling mechanism involving the proton stretching vibrations in the (COOH)2 cycles and the electronic motions in the molecular skeletons, the isotopic "H/D self-organization" mechanisms and a long-distance vibrational exciton coupling between the adjacent (COOH)2 cycles in the molecular chains are mainly responsible for the generation of the temperature effects in the crystalline IR spectra.

  11. Hydrogen bonding in asphaltenes and coal. Comprehensive progress report, December 1975--Februray 1977. [13 references

    Energy Technology Data Exchange (ETDEWEB)

    Li, N.C.

    1977-01-01

    Proton magnetic resonance (PMR) studies are reported of hydrogen bonding between the OH proton of o-phenylphenol (OPP) and the nitrogen electron donor of quinoline (Qu). Data are also reported on the hydrogen bonding of a coal-derived asphaltene and its acid and base components with OPP. Determination was made of the equilibrium constants of the 1:1 complex between OPP and Qu at 39, 32, 1, and -18/sup 0/C from the PMR studies. Qualitative results are reported for the interaction between the base fraction of asphaltene and OPP at 32, 1, and -26/sup 0/C.

  12. [Paste deposition and chip bonding process development]. IBM, Endicott tenth quarterly report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    The scope of Endicott activity during this quarter includes: paste deposition process development and chip bonding process development. It was discovered that small voids exist in the photobumps. These are typically at the base of the bump and are believed to have always been present. Although the reliability test results have been positive and no failure is attributed to voids, the process development work during the last quarter has focused on understanding how these form and how to reduce them. High feed pressure, slow nozzle speed and lower viscosity reduce void formation. Nozzle design changes have been identified. One change will increase the shearing of the paste during feed, thus reducing the viscosity, a second change will allow higher feed pressures. Chip bonding process development has focused on correlating bonding results between the IBM in-house chip bonder made by Research Devices, Inc. and the Universal development bond tool. Two variables have been identified that correlate with poor bond results. The report describes more detail of the activity during the tenth quarter for paste deposition and chip bonding in each of these areas.

  13. Distance Education in European Higher Education--The Potential. Report 3 (of 3) of the IDEAL (Impact of Distance Education on Adult Learning Project. Extended Version

    Science.gov (United States)

    Owusu-Boampong, Angela; Holmberg, Carl

    2015-01-01

    This report is the third in a series published by the IDEAL (Impact of Distance Education on Adult Learning) project. The IDEAL project ran from October 2013 to September 2015 with financial support from the EU Lifelong Learning Programme. The project aims to: (1) offer insights on the needs of adult learners to both policymakers and distance…

  14. Distance Education in European Higher Education--The Students. Report 2 (of 3) of the IDEAL (Impact of Distance Education on Adult Learning) Project

    Science.gov (United States)

    Schneller, Chripa; Holmberg, Carl

    2014-01-01

    This report is the second in a series published by the IDEAL (Impact of Distance Education on Adult Learning) project. The IDEAL project ran from October 2013 to September 2015 with financial support from the EU Lifelong Learning Programme. The project aims to: (1) offer insights on the needs of adult learners to both policymakers and distance…

  15. Distance Education in European Higher Education--The Offer. Report 1 (of 3) of the IDEAL (Impact of Distance Education on Adult Learning) Project

    Science.gov (United States)

    Schneller, Chripa; Holmberg, Carl

    2014-01-01

    This report is the first in a series published by the IDEAL (Impact of Distance Education on Adult Learning) project. The IDEAL project ran from October 2013 to September 2015 with financial support from the EU Lifelong Learning Programme. The project aims to: (1) offer insights on the needs of adult learners to both policymakers and distance…

  16. The University of North Carolina Report on Expanding Access to Higher Education through State-Funded Distance Education Programs

    Science.gov (United States)

    University of North Carolina General Administration, 2012

    2012-01-01

    Legislation in 1998 provided enrollment funding for UNC distance education. This report documents the growth of UNC distance education programs and their role in meeting the high priority education and economic development needs of the State. As highlighted in the Executive Summary and documented throughout this report, state enrollment funding…

  17. 26 CFR 1.149(e)-1 - Information reporting requirements for tax-exempt bonds.

    Science.gov (United States)

    2010-04-01

    ... into account under section 146 (relating to volume cap on private activity bonds), the state... the Tax Reform Act of 1986), the issuer must submit the annual report containing information on the... (k)(6). (2) State certification with respect to volume cap—(i) In general. If an issue is subject...

  18. Industrial Development Bonds for Financing Projects in Rural Areas. Agricultural Experiment Station Research Report 216.

    Science.gov (United States)

    Fuller, Stephen W.

    As one of several special reports on development possibilities for the agriculture and forestry sector of the Four Corners Economic Development Region, this monograph deals with the use of industrial development bonds as a means of resolving finance problems arising from inadequate or nonexistent credit in rural areas. Distinguishing between the…

  19. Public knowledge, attitudes, social distance and reported contact regarding people with mental illness 2009-2015.

    Science.gov (United States)

    Henderson, C; Robinson, E; Evans-Lacko, S; Corker, E; Rebollo-Mesa, I; Rose, D; Thornicroft, G

    2016-08-01

    To investigate whether public knowledge, attitudes, desire for social distance and reported contact in relation to people with mental health problems have improved in England during the Time to Change (TTC) programme to reduce stigma and discrimination 2009-2015. Using data from an annual face-to-face survey of a nationally representative sample of adults, we analysed longitudinal trends in the outcomes with regression modelling using standardised scores of the measures overall and by age and gender subgroups. There were improvements in all outcomes. The improvement for knowledge was 0.17 standard deviation units in 2015 compared to 2009 (95% CI 0.10, 0.23); for attitudes 0.20 standard deviation units (95% CI 0.14, 0.27) and for social distance 0.17 standard deviation units (95% CI 0.11, 0.24). Survey year for 2015 vs. 2009 was associated with a higher likelihood of reported contact (OR 1.32, 95% CI 1.13, 1.53). Statistically significant interactions between year and age suggest the campaign had more impact on the attitudes of the target age group (25-45) than those aged over 65 or under 25. Women's reported contact with people with mental health problems increased more than did men's. The results provide support for the effectiveness of TTC. © 2016 The Authors. Acta Psychiatrica Scandinavica Published by John Wiley & Sons Ltd.

  20. Final report on supplementary comparison EURAMET.L-S20: Comparison of laser distance measuring instruments

    Science.gov (United States)

    Wisniewski, Mariusz; Ramotowski, Zbigniew; Pollinger, Florian; Wedde, Martin; Matus, Michael; Banhidi-Bergendorf, Zita; Stalder, Oliver; Thalmann, Rudolf; Lassila, Antti; Unkuri, Jarkko; Balling, Petr; Hynek, Jaromír; Astrua, Milena; Pisani, Marco; Prieto, Emilio; Karlsson, Helge; Hansrud Kjær, Peter; Flys, Olena; Lillepea, Lauri; Odrats, Indrek; Fíra, Roman; Fodrekova, Anna; Harnosova, Eva; Duta, Alexandru; Teoderescu, Dragos

    2014-01-01

    The results of the supplementary comparison EURAMET.L-S20 of laser distance measuring instruments (EDMs) are reported. It was the first comparison of EDMs. Four EDMs were circulated among 13 European NMIs. Each EDM was calibrated at a distance of 0.3 m and at regularly spaced intervals every 5 m for a range up to 50 m. The measurements were conducted between 2011 and 2012. The test of the stability of the EDMs showed significant changes in the mean results over timescales of months or even days. The uncertainty of the results mainly comes from the uncertainty due to the reproducibility, and it is difficult to distinguish the part relevant to the laboratories' calibration and measurement capabilities. For the analysis both the deviations from the reference value and the En numbers were calculated. For the evaluation of the reference value, the weighted mean approach has been chosen, although the consistency check failed in many cases. A more complicated procedure for the evaluation of the reference value was proposed, which slightly changes the uncertainty of the reference value. Most results agreed within the claimed uncertainties. Some 4.7% of the results showed some larger deviations. Some participants may have a high percentage of values that are not compliant with their CMC claims due to the influence of the artifact and the estimation of its uncertainty. Main text. To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/. The final report has been peer-reviewed and approved for publication by the CCL, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).

  1. Reliability of Adhesive Bonds Under Severe Environments. Report of the Committee on Reliability of Adhesive Bonds in Severe Environments

    Science.gov (United States)

    1984-12-01

    Arlington, Virginia LAWRENCE T. DRZAL, Air Force Wright Aeronautical Laboratory, Wright-Patterson Air Force Base, Ohio BEN A. WILCOX , Defense Advanced...area of mechanics included additi, nal research in the area of nondestructive evaluation ( NDE ), the - - r. w-o I----- - -: - -." .--. search for...carried out on the cffects of additives and impurities on adhesive bond durability. • . - I MECHANICS o Efforts should be made to develop NDE

  2. Representing distance, consuming distance

    DEFF Research Database (Denmark)

    Larsen, Gunvor Riber

    to mobility and its social context. Such an understanding can be approached through representations, as distance is being represented in various ways, most noticeably in maps and through the notions of space and Otherness. The question this talk subsequently asks is whether these representations of distance...... are being consumed in the contemporary society, in the same way as places, media, cultures and status are being consumed (Urry 1995, Featherstone 2007). An exploration of distance and its representations through contemporary consumption theory could expose what role distance plays in forming...... are present in theoretical and empirical elaborations on mobility, but these remain largely implicit and unchallenged (Bauman 1998). This talk will endeavour to unmask distance as a theoretical entity by exploring ways in which distance can be understood and by discussing distance through its representations...

  3. Single Tooth Replacement Using InCeram Resin Bonded Fixed Partial Denture: A Clinical Report.

    Directory of Open Access Journals (Sweden)

    Elnaz Moslehifard

    2014-02-01

    Full Text Available This clinical report describes a treatment option for replacement of a missing mandibular anterior tooth using InCeram resin bonded fixed partial denture (RBFPD. The conventional approach for replacing mandibular incisors dictates the placement of either a conventional porcelain-fused-to-metal (PFM bridge, Maryland bridge, or fiber-reinforced composite veneer bridge and several appearance-related disadvantages have been reported in the use of a prosthesis that incorporates a metal substructure. The InCeram bridge is a minimally invasive restoration and eliminates undesirable incisal graying frequently observed in metal RBFPDs. This method was successfully clinically applied to overcome shortcomings of other approaches that may require a minimal invasive technique to preserve lasting sound tooth structure.

  4. Bond percolation in films

    Science.gov (United States)

    Korneta, W.; Pytel, Z.

    1988-04-01

    Bond percolation in films with simple cubic structure is considered. It is assumed that the probability of a bond being present between nearest-neighbor sites depends on the distances to surfaces. Based on the relation between the Potts model and the bond percolation model, and using the mean-field approximation, the phase diagram and profiles of the percolation probability have been obtained.

  5. Hospitalization for early bonding of the genetic mother after a surrogate pregnancy: report of two cases.

    Science.gov (United States)

    Sharan, H; Yahav, J; Peleg, D; Ben-Rafael, Z; Merlob, P

    2001-12-01

    In surrogate pregnancies the genetic parents have little opportunity for early bonding to their infant, either prenatally (in utero) or in the immediate postnatal period. The purpose of this article is to describe a new method for encouraging early parent-infant bonding after surrogate pregnancy by hospitalizing the genetic mother in the maternity ward immediately after the delivery. Two genetic mothers were hospitalized in the maternity ward (rooming-in system) at the Rabin Medical Center in Israel immediately after delivery of their infants by surrogate arrangement. The first birth was a singleton pregnancy with vaginal delivery and the second, a twin pregnancy with delivery by cesarean section. The genetic parents were counseled by a social worker from the adoption agency, starting 3 months before the estimated date of delivery. The parents were referred to the hospital social worker before the delivery. To assess attachment, we observed the parents' behavior toward their children during two daily 15-minute periods of free, unstructured interaction. The parents showed good primary caregiving functions and established affective verbal and physical contact with the infants. They began to recognize the infants' needs and temperament, and exhibited an aura of self-confidence during their interactions. All expressed satisfaction with the method at discharge and reported on reduction of their fears about returning home with the infants. We believe that early hospitalization of the genetic mother in a surrogate delivery may be desirable to establish good and safe early mother-infant bonding, and that it should be considered for adoption as regular hospital policy. Further randomized studies with larger samples over the long term are warranted.

  6. The Terabyte Analysis Machine Project The Distance Machine:Performance Report

    Institute of Scientific and Technical Information of China (English)

    JamesAnnis; KoenHoltman; 等

    2001-01-01

    The Terabyte Analysis Machine Project is Developing hardware and software to analyze Terabyte scale datasets.The Distance Machine framework provides facilities to flexibly interface application specific indexing and partitioning algorthms to large scientific databases.

  7. A Report to the Australian Development Assistance Bureau. Regional Symposium on Distance Teaching in Asia (Penang, Malaysia, May 1981).

    Science.gov (United States)

    Reid-Smith, Edward R.

    Reports and summaries of papers presented at the 1981 Regional Symposium on Distance Teaching in Asia are presented. The symposium, which was represented by 22 countries, was organized by the Universiti Sains (University of Science) Malaysia as part of the activities associated with the completion of 10 years of off-campus program facilities. The…

  8. Hydrogen bonding in asphaltenes and coal. Quarterly Report for July 1, 1978 - September 30, 1978

    Energy Technology Data Exchange (ETDEWEB)

    Li, N.C.; Tewari, K.C.

    1978-09-29

    Two coal liquid products derived from the same Kentucky hvAb coal have been separated into toluene-insoluble, asphaltene, and pentane-soluble heavy oil fractions. Viscosity and calorimetric studies are reported of the interaction between heavy oil and asphaltene(A) and its acid/neutral(AA) and base(BA) components in solvent benzene. The increase in viscosity and molar enthalpy of interaction, {Delta}H{sup 0}, in the order BA>A>AA, correlate well with the proton magnetic resonance downfield chemical shift of the OH signal of o-phenylphenol, as a function of added asphaltene (A, AA, BA) concentration in solvent CS{sub 2}· The results suggest that when asphaltene .and heavy oil are present together, hydrogen-bonding involving largely phenolic OH, is one of the mechanisms by which asphaltene-heavy oil interactions are achieved and, in part, is responsible for the viscosity increase of coal liquids.

  9. Ab initio MO study on equilibrium bond distance between Fe and pyridine in bis(pyridine)(porphinato) iron for various electronic states

    Science.gov (United States)

    Saito, Minoru; Kashiwagi, Hiroshi

    1985-04-01

    For bis(pyridine)(porphinato) iron [FeP(py)2], a correlation between the iron electronic state and the equilibrium Fe-Npy distance was investigated. Potential energy curves as a function of the Fe-Npy distance were calculated for low-spin, intermediate-spin, and high-spin states of the ferric and ferrous ions by the ab initio SCF MO method. The equilibrium Fe-Npy distances were obtained from the potential curves. The values obtained for the ferric low-spin and high-spin states were in good agreement with the experimental values for Fe(III)(OEP)(3-Clpy)2 within the differences, ±0.05 Å. The following significant features were found. The equilibrium distance is elongated by the occupation of the 3dz2 orbital and is shortened by the oxidation of the iron atom. The distance and the force constant for the symmetrical py-Fe-py stretching are strongly correlated with the overlap population between the 3dz2 orbital and pyridine-nitrogen orbitals.

  10. Experiences in Distance Education. Report of a Conference (Kingston, Jamaica, July 14-16, 1990).

    Science.gov (United States)

    University of the West Indies, Mona (Jamaica).

    These proceedings present three opening speeches, eight presentations, and a summary of the presentations from a 3-day conference at which distance teaching practitioners from selected institutions shared their experiences. The opening address (Alister McIntyre) is followed by a speech (Dennis Irvine) that discusses the Commonwealth of Learning,…

  11. Fuel Fabrication Capability WBS 01.02.01.05 - HIP Bonding Experiments Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Dickerson, Patricia O' Donnell [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Summa, Deborah Ann [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Liu, Cheng [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Tucker, Laura Arias [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Chen, Ching-Fong [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Aikin, Beverly [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Aragon, Daniel Adrian [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Beard, Timothy Vance [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Montalvo, Joel Dwayne [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Pena, Maria Isela [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dombrowski, David E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-06-10

    The goals of this project were to demonstrate reliable, reproducible solid state bonding of aluminum 6061 alloy plates together to encapsulate DU-10 wt% Mo surrogate fuel foils. This was done as part of the CONVERT Fuel Fabrication Capability effort in Process Baseline Development . Bonding was done using Hot Isotatic Pressing (HIP) of evacuated stainless steel cans (a.k.a HIP cans) containing fuel plate components and strongbacks. Gross macroscopic measurements of HIP cans prior to HIP and after HIP were used as part of this demonstration, and were used to determine the accuracy of a finitie element model of the HIP bonding process. The quality of the bonding was measured by controlled miniature bulge testing for Al-Al, Al-Zr, and Zr-DU bonds. A special objective was to determine if the HIP process consistently produces good quality bonding and to determine the best characterization techniques for technology transfer.

  12. Self-reported maximum walking distance in persons with MS may affect the EDSS.

    Science.gov (United States)

    Berger, Warren; Payne, Michael W C; Morrow, Sarah A

    2017-08-15

    In persons with MS (PwMS), the Expanded Disability Status Scale (EDSS) is used to monitor disability progression. Scores between 4.0 and 7.0 are determined by maximum walking distance. Self-estimation of this value is often employed in clinic settings. To examine the accuracy with which PwMS estimate their walking distance, and observe subsequent changes to the EDSS. This prospective cohort study recruited PwMS with previously recorded EDSS of 3.5-7.0. Participants estimated their maximum walking distance and then walked as far as they could along a pre-specified course. Each distance was converted to an EDSS score, the "estimated EDSS" and the "actual EDSS". Chi-Square analysis was used to compare EDSS scores. Logistic regression was used to determine predictors of inaccurate estimations. Of the 66 PwMS in this study, 43.9% had a difference in the actual EDSS compared to the estimated EDSS. Median estimated EDSS was 4.75 (range 3.0-7.0); after walking assessment, median actual EDSS was 5.0 (range 3.0-7.0), which represented a significant difference [X(2) (df 64, N=66)=206.9; pEDSS decreased in 9 PwMS (13.6%) and increased in 20 PwMS (30.3%). Logistic regression did not find any demographic/disease characteristic to be predictive of this discrepancy. Some PwMS do not accurately estimate maximum walking distance; only 56.1% of PwMS accurately estimated their actual EDSS. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. Effect of Edge Distance on Yield Initiation in a Remotely Loaded Half-Plane Containing a Bonded Interference-Fit Disc of the Same Material.

    Science.gov (United States)

    1985-01-01

    Division STATUTORY AND STATE AUTHORITIES AND INDUSTRY CSIRO Materials Science Division, Library Trans-Australia Airlines, Library Qantas Airways Limited...example, rrlq = (rq)i+(Frq)s. 3. INITIATION OF YIELD Plane stress conditions are assumed in this analysis . For non-principal stresses, the von Mises...may be (select) unrestricted (or) as for 13 a. 14. Descriptors 15. COSATI Group -Yield , :,/Stress analysis 11130 Bonding Elastic properties . ri

  14. Training for quality management: report on a nationwide distance learning initiative for physicians in Spain.

    Science.gov (United States)

    Saturno, P J

    1999-02-01

    Under the sponsorship of a pharmaceutical firm, a distance-learning course on Quality Management methods was developed at the University of Murcia (Spain) and offered nationwide to primary health care physicians working in the public system. A total of 7104 physicians (47.7% of the census) signed up (at least one in 92.2% of the health centres). The course content follows the author's model of quality improvement, monitoring and design trilogy, but focuses mainly on methods for a quality improvement cycle using a learning-by-doing and problem-solving approach. The unexpected success of this initiative has led us to reflect on the interest in learning about quality improvement methods shown by physicians, the usefulness of the distance-learning approach, and also to continue the project with new initiatives such as: a summary poster, software containing all the necessary tools and data analysis for quality improvement, and a manual.

  15. Comparison of Continuing Bonds Reported by Parents and Siblings after a Child's Death from Cancer

    Science.gov (United States)

    Foster, Terrah L.; Gilmer, Mary Jo; Davies, Betty; Dietrich, Mary S.; Barrera, Maru; Fairclough, Diane L.; Vannatta, Kathryn; Gerhardt, Cynthia A.

    2011-01-01

    Few studies have distinguished similarities and differences between continuing bonds as they appear in various bereaved populations, particularly parent versus sibling cohorts following a child's death. This mixed-method study compared how parents and siblings experienced continuing bonds in 40 families who lost a child to cancer. Thirty-six…

  16. Twelve-year results of a direct-bonded partial prosthesis in a patient with advanced periodontitis: a clinical report.

    Science.gov (United States)

    Minami, Hiroyuki; Minesaki, Yoshito; Suzuki, Shiro; Tanaka, Takuo

    2012-08-01

    Prosthodontic treatment for patients with advanced periodontitis is a therapeutic challenge. A minimally invasive technique is preferred to preserve the remaining mobile abutment teeth. This report describes the initial clinical treatment and 12-year follow-up of a direct-bonded prosthesis reinforced with a cast metal framework, used as a conservative treatment option to replace periodontally involved maxillary lateral incisors.

  17. Final report of the Static Bonding Team, Pantex Plant, Amarillo, Texas

    Energy Technology Data Exchange (ETDEWEB)

    Jones, R.D.; Chen, K.C.; Holmes, S.W.

    1993-12-01

    The integrity of the electrostatic bonding procedures used to equilibrate operating technicians and weapon components was questioned during the course of the quality evaluation assessments of the W70, W68, and B57 dismantlement programs. A multi-disciplined, interlaboratory team was convened on an ad hoc basis to resolve certain static bonding issues. The accomplishments of this team in upgrading the integrity of the bonding process include recommendations on the proper use of wrist straps, training of technicians in their use, and procedures to reduce accumulation of static charge on components during routine handling operations.

  18. DISCOM2: Distance Computing the SP2 Pilot FY98 Report

    Energy Technology Data Exchange (ETDEWEB)

    Beiriger, Judy; Byers, Rupert K.; Ernest, Martha J.; Goudy, Sue P.; Noe, John P.; Pratt, Thomas J.; Shirley, David N.; Tarman, Thomas D.; VanDevender, Walter H.; Wiltzius, David P.

    1999-05-01

    As a way to bootstrap the DISCOM(2) Distance Computing Program the SP2 Pilot Project was launched in March 1998. The Pilot was directed towards creating an environment to allow Sandia users to run their applications on the Accelerated Strategic Computing Initiative's (ASCI) Blue Pacific computation platform, the unclassified IBM SP2 platform at Lawrence Livermore National Laboratory (LLNL). The DISCOM(2) Pilot leverages the ASCI PSE (Problem solving Environment) efforts in networking and services to baseline the performance of the current system. Efforts in the following areas of the pilot are documented: applications, services, networking, visualization, and the system model. It details not only the running of two Sandia codes CTH and COYOTE on the Blue Pacific platform, but also the buildong of the Sandia National Laboratories (SNL) proxy environment of the RS6000 platforms to support the Sandia users.

  19. Discovering the Nature of Dark Energy: Towards Better Distances from Type Ia Supernovae -- Final Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Filippenko, Alexei Vladimir [Univ. of California, Berkeley, CA (United States)

    2014-05-09

    Type Ia supernovae (SNe Ia; exploding white-dwarf stars) were the key to the Nobel-worthy 1998 discovery and subsequent verification that the expansion of the Universe is accelerating, driven by the effects of dark energy. Understanding the nature of this mysterious, yet dominant, component of the Universe is at the forefront of research in cosmology and fundamental physics. SNe Ia will continue to play a leading role in this enterprise, providing precise cosmological distances that improve constraints on the nature of dark energy. However, for this effort to succeed, we need to more thoroughly understand relatively nearby SNe Ia, because our conclusions come only from comparisons between them and distant (high-redshift) SNe Ia. Thus, detailed studies of relatively nearby SNe Ia are the focus of this research program. Many interesting results were obtained during the course of this project; these were published in 32 refereed research papers that acknowledged the grant. A major accomplishment was the publication of supernova (SN) rates derived from about a decade of operation of the Lick Observatory Supernova Search (LOSS) with the 0.76-meter Katzman Automatic Imaging Telescope (KAIT). We have determined the most accurate rates for SNe of different types in large, nearby galaxies in the present-day Universe, and these can be compared with SN rates far away (and hence long ago in the past) to set constraints on the types of stars that explode. Another major accomplishment was the publication of the light curves (brightness vs. time) of 165 SNe Ia, along with optical spectroscopy of many of these SNe as well as other SNe Ia, providing an extensive, homogeneous database for detailed studies. We have conducted intensive investigations of a number of individual SNe Ia, including quite unusual examples that allow us to probe the entire range of SN explosions and provide unique insights into these objects and the stars before they explode. My team's studies have also

  20. Distance threshold for the effect of urban agriculture on elevated self-reported malaria prevalence in Accra, Ghana.

    Science.gov (United States)

    Stoler, Justin; Weeks, John R; Getis, Arthur; Hill, Allan G

    2009-04-01

    Irrigated urban agriculture (UA), which has helped alleviate poverty and increase food security in rapidly urbanizing sub-Saharan Africa, may inadvertently support malaria vectors. Previous studies have not identified a variable distance effect on malaria prevalence from UA. This study examines the relationships between self-reported malaria information for 3,164 women surveyed in Accra, Ghana, in 2003, and both household characteristics and proximity to sites of UA. Malaria self-reports are associated with age, education, overall health, socioeconomic status, and solid waste disposal method. The odds of self-reported malaria are significantly higher for women living within 1 km of UA compared with all women living near an irrigation source, the association disappearing beyond this critical distance. Malaria prevalence is often elevated in communities within 1 km of UA despite more favorable socio-economic characteristics than communities beyond 1 km. Neighborhoods within 1 km of UA should be reconsidered as a priority for malaria-related care.

  1. Organization and Technology Issues Related to Distance Education. TDC Research Report No. 3.

    Science.gov (United States)

    Kovel-Jarboe, Patricia

    This report focuses on the first of three phases in a project at the Institute of Agriculture, Forestry, and Home Economics (IAFHE) at the University of Minnesota. This project has been charged with developing a plan for delivering credit and on-credit educational offerings at multiple locations in the state. Background information on the project…

  2. Bond-length distributions for ions bonded to oxygen: alkali and alkaline-earth metals.

    Science.gov (United States)

    Gagné, Olivier Charles; Hawthorne, Frank Christopher

    2016-08-01

    Bond-length distributions have been examined for 55 configurations of alkali-metal ions and 29 configurations of alkaline-earth-metal ions bonded to oxygen, for 4859 coordination polyhedra and 38 594 bond distances (alkali metals), and for 3038 coordination polyhedra and 24 487 bond distances (alkaline-earth metals). Bond lengths generally show a positively skewed Gaussian distribution that originates from the variation in Born repulsion and Coulomb attraction as a function of interatomic distance. The skewness and kurtosis of these distributions generally decrease with increasing coordination number of the central cation, a result of decreasing Born repulsion with increasing coordination number. We confirm the following minimum coordination numbers: ([3])Li(+), ([3])Na(+), ([4])K(+), ([4])Rb(+), ([6])Cs(+), ([3])Be(2+), ([4])Mg(2+), ([6])Ca(2+), ([6])Sr(2+) and ([6])Ba(2+), but note that some reported examples are the result of extensive dynamic and/or positional short-range disorder and are not ordered arrangements. Some distributions of bond lengths are distinctly multi-modal. This is commonly due to the occurrence of large numbers of structure refinements of a particular structure type in which a particular cation is always present, leading to an over-representation of a specific range of bond lengths. Outliers in the distributions of mean bond lengths are often associated with anomalous values of atomic displacement of the constituent cations and/or anions. For a sample of ([6])Na(+), the ratio Ueq(Na)/Ueq(bonded anions) is partially correlated with 〈([6])Na(+)-O(2-)〉 (R(2) = 0.57), suggesting that the mean bond length is correlated with vibrational/displacement characteristics of the constituent ions for a fixed coordination number. Mean bond lengths also show a weak correlation with bond-length distortion from the mean value in general, although some coordination numbers show the widest variation in mean bond length for zero distortion, e.g. Li(+) in

  3. The challenge of global water access monitoring: evaluating straight-line distance versus self-reported travel time among rural households in Mozambique.

    Science.gov (United States)

    Ho, Jeff C; Russel, Kory C; Davis, Jennifer

    2014-03-01

    Support is growing for the incorporation of fetching time and/or distance considerations in the definition of access to improved water supply used for global monitoring. Current efforts typically rely on self-reported distance and/or travel time data that have been shown to be unreliable. To date, however, there has been no head-to-head comparison of such indicators with other possible distance/time metrics. This study provides such a comparison. We examine the association between both straight-line distance and self-reported one-way travel time with measured route distances to water sources for 1,103 households in Nampula province, Mozambique. We find straight-line, or Euclidean, distance to be a good proxy for route distance (R(2) = 0.98), while self-reported travel time is a poor proxy (R(2) = 0.12). We also apply a variety of time- and distance-based indicators proposed in the literature to our sample data, finding that the share of households classified as having versus lacking access would differ by more than 70 percentage points depending on the particular indicator employed. This work highlights the importance of the ongoing debate regarding valid, reliable, and feasible strategies for monitoring progress in the provision of improved water supply services.

  4. Professional employment assitance practices in Quebec's Carrefour jeunesse-emploi : bonding with youth distanced from the labor market and leading them to action

    OpenAIRE

    Provencher, Ysabel; Tremblay-Roy, Julie

    2014-01-01

    Our article reports part of the findings of research conducted in Québec (Canada) with professionals employed by Carrefours jeunesse-emploi, a network of community organizations dedicated to employment participation of young people aged 16 to 35 (Provencher, Émond & Tremblay-Roy, 2010). The study was an effort to generate knowledge about employment coaching, a practice that is now shared by the different professionals attached to public, private and community employment assistance networks in...

  5. Research Notes: Interim Report: A Case Study of Internet-Based Distance Education Program Development in Vietnam

    Directory of Open Access Journals (Sweden)

    Patrick J. Fahy

    2004-04-01

    Full Text Available This is a report of the role of Distance education (DE in enhancing education and training in developing countries. As countries compete in an ever more challenging international marketplace, they recognize the need to continually train and upgrade their citizenry. As national leaders struggle to cope with increasing populations and decreasing budgets, DE can be an additional and often essential tool in accomplishing this goal.This paper is a case study of the efforts of one college in Vietnam, Fisheries College Number 4, to develop a plan to introduce a small distance education offering to its regular courses. Its purpose was to better serve farmers in remote regions. The first author, Ramona Materi, through her company, Ingenia Consulting, carried out the work on behalf of the International Development Research Centre (IDRC, a public corporation created by the Parliament of Canada to help researchers and communities in the developing world to find solutions to their social, economic, and environmental problems. Materi’s assignment was to work with College officials to develop the DE plan and funding proposal.The paper begins with a brief description of the role of information and communications technology (ICT in education and development, particularly in South East Asia. It then provides an overview of Vietnam and its current activities in DE. The next section offers a detailed examination of the challenges the College faced in developing a plan for DE on the Internet. The paper concludes with Materi’s personal observations and commentary on lessons learned.

  6. A steerable/distance enhanced penetrometer delivery system: Phase I. Topical report, August 1994--August 1995

    Energy Technology Data Exchange (ETDEWEB)

    Amini, A.; Shenhar, J.

    1995-08-01

    The characterization, monitoring, and remediation of many of the nation`s highly contaminated sites are among the highest priorities of the Department of Energy (DOE). In underground contaminated sites, detection and mapping of the plume of contamination and in-situ remediation are the first steps towards clean up. The needs for these steps include a depth capability ranging from tens of feet to between 100 to 200 feet, ability to go around underground obstacles with curvatures that do not damage downhole components, and downhole access for delivery of environmental sensors. In addition, in some instances it is necessary to use light weight equipment over underground storage tanks in order to avoid collapse of the tank. Baseline technologies of {open_quotes}aim and shoot{close_quotes} well drilling do not satisfy all of these needs, are not as efficient, and can further contaminate the site by bringing underground contaminants to the surface. As a result new technologies are needed to carry out underground site clean up more efficiently. This report describes phase I of the development of a device for the control and penetration of penetrometers termed the Position Location Device (POLO). Work consisted of the design of steering components and vibratory penetration components.

  7. Distance Learning

    Science.gov (United States)

    1997-12-01

    A study reviewing the existing Army Distance Learning Plan (ADLP) and current Distance Learning practices, with a focus on the Army’s training and...educational challenges and the benefits of applying Distance Learning techniques. The ASB study panel makes six specific recommendations, the most

  8. Distance dependence of nonadiabaticity in the branching between C-Br and C-Cl bond fission following 1[n(O),π*(C=O)] excitation in bromopropionyl chloride

    Science.gov (United States)

    Kash, P. W.; Waschewsky, G. C. G.; Butler, L. J.; Francl, M. M.

    1993-09-01

    increasing the distance between the C-Br and C=O chromophores decreases the electronic configuration interaction matrix elements which mix and split the 1n(O)π*(C=O) and np(Br)σ*(C-Br) configurations at the barrier to C-Br bond fission in bromopropionyl chloride. The smaller splitting between the adiabats at the barrier to C-Br fission increases the probability of nonadiabatic recrossing of the barrier, nearly completely suppressing C-Br bond fission in bromopropionyl chloride. Preliminary ab initio calculations of the adiabatic barrier heights and the electronic configuration interaction matrix elements which split the adiabats at the barrier to C-Br and C-Cl fission in both bromopropionyl chloride and bromoacetyl chloride support the interpretation of the experimental results. We end by identifying a class of reactions, those allowed by overall electronic symmetry but Woodward-Hoffmann forbidden, in which nonadiabatic recrossing of the reaction barrier should markedly reduce the rate constant, both for ground state and excited state surfaces.

  9. Learning string edit distance

    CERN Document Server

    Ristad, E S; Ristad, Eric Sven; Yianilos, Peter N.

    1996-01-01

    In many applications, it is necessary to determine the similarity of two strings. A widely-used notion of string similarity is the edit distance: the minimum number of insertions, deletions, and substitutions required to transform one string into the other. In this report, we provide a stochastic model for string edit distance. Our stochastic model allows us to learn a string edit distance function from a corpus of examples. We illustrate the utility of our approach by applying it to the difficult problem of learning the pronunciation of words in conversational speech. In this application, we learn a string edit distance with one fourth the error rate of the untrained Levenshtein distance. Our approach is applicable to any string classification problem that may be solved using a similarity function against a database of labeled prototypes. Keywords: string edit distance, Levenshtein distance, stochastic transduction, syntactic pattern recognition, prototype dictionary, spelling correction, string correction, ...

  10. A case report of bilateral Brodie bite in early mixed dentition using bonded constriction quad-helix appliance.

    Science.gov (United States)

    Nojima, Kunihiko; Takaku, Sakiko; Murase, Chiaki; Nishii, Yasushi; Sueishi, Kenji

    2011-01-01

    Brodie bite is a comparatively rare type of malocclusion found in primary and mixed dentition. It not only adversely affects chewing and muscle functions, but also impairs normal growth and development of the mandible. This report describes the therapeutic results of a patient with bilateral Brodie bite in early mixed dentition after using a bonded constriction quad-helix appliance. The patient, a boy aged 9 years and 2 months, first visited our hospital after occlusal abnormality in the molar region was detected at a local dental clinic. Case analysis resulted in a diagnosis of bilateral Brodie bite with slight mandibular retrognathism. Treatment objectives were to reduce the arch width of the maxillary dentition and expand the mandibular arch in order to establish and stabilize molar occlusion and to achieve a Class I molar relation and appropriate overbite and overjet. Treatment comprised covering the occlusal surface of the maxillary molars with resin and attaching a bonded constriction quad-helix appliance joined with a 0.040-inch quad-helix wire. A bi-helix appliance was also fixed to the mandibular dentition. Brodie bite visibly improved after 5 months. Cervical headgear was then fitted and the patient observed until eruption of the permanent dentition was complete. Class I molar relation was achieved after 2 years and 6 months, although spacing remained in the maxillary and mandibular dentitions. Treatment of bilateral Brodie bite in mixed dentition by means of a bonded constriction quad-helix appliance attached to the maxillary dentition enabled effective bite opening and reduction in the width of maxillary arch independent of the patient's cooperation, providing good therapeutic outcome in a short time period.

  11. Hydrogen bonding in asphaltenes and coal. Progress report, April 1, 1978--June 30, 1978

    Energy Technology Data Exchange (ETDEWEB)

    Li, N.C.; Tewari, K.C.

    1978-06-01

    A direct calorimetric method has been used to determine simultaneously the molar enthalpy, ..delta..H/sup 0/, and equilibrium constant, K, for quinoline (QU) interaction with coal-derived asphaltenes (A), acid/neutral (AA) and base (BA) components of A, silylated asphaltenes (A(TMS)) and heavy oil (HO) fractions in solvent C/sub 6/H/sub 6/. Solvent fractionated A and HO fractions were from three centrifuged liquid product (CLP) samples prepared in the 450 kg (/sup 1///sub 2/ ton) per-day Process Development Unit at Pittsburgh Energy Research Center, at different process conditions from the same feed coal, Kentucky hvAb. For a given system, Qu-A (AA or BA), Qu-HO, the almost constant value of K and linear variation of ..delta..H/sup 0/ with the phenolic oxygen content of coal liquid fractions, have been attributed to the dominance of hydrogen-bonding effects, involving phenolic OH, over other types of molecular interactions in solution. In Qu-A(TMS) system, -..delta..H/sup 0/ values increase with decrease in molecular weight of A(TMS), while -..delta..S/sup 0/ values increase with increase in aromaticity of A fraction. The degree of complexation, in absence of OH groups, is much smaller than Qu-A system and largely depends upon some unusual entropy effects.

  12. Hydrogen bonding in asphaltenes and coal. Progress report, March 1, 1977--August 31, 1977

    Energy Technology Data Exchange (ETDEWEB)

    Li, N.C.; Tewari, K.C.

    1977-08-01

    A calorimetric method is presented for the simultaneous evaluation of equilibrium constant, K, and molar enthalpy, ..delta..H/sup 0/, for 1 : 1 adduct formation of quinoline (Qu) with asphaltene (A), together with its acid/neutral (AA) fraction and its base (BA) fraction, isolated from a centrifuged liquid product (CLP) sample prepared from Kentucky hvAb coal at 27.6 MPa hydrogen pressure and 723K, with reactor charged with glass pellets. The same procedure was used to determine K and ..delta..H/sup 0/ for 1 : 1 adduct formation of Qu with asphaltene and heavy oils obtained from CLP samples (FB-53) prepared with CoMo catalyst at different run times and process conditions. The effects of the CoMo catalyst, run time, and residence times on viscosity, molecular weight, ..delta..H/sup 0/, heteratom content, contents of preasphaltene, asphaltene and heavy oil, aromaticity, and structural parameters, are determined. These findings lead to the conclusion that hydrogen bonding plays an important role in determining viscosity, and contributes more to the enthalpy of interaction than does ..pi..-interaction. The toluene-insoluble fraction, asphaltene (whole, acid/neutral and base fractions), and heavy oil were isolated from a solvent-refined-coal (SRC) conversion product. Data obtained from several infrared and viscosity experiments indicate that the behavior of different fractions isolated from SRC is similar to that of corresponding fractions isolated from CLP samples.

  13. Information Distance

    CERN Document Server

    Bennett, Charles H; Li, Ming; Vitanyi, Paul M B; Zurek, Wojciech H

    2010-01-01

    While Kolmogorov complexity is the accepted absolute measure of information content in an individual finite object, a similarly absolute notion is needed for the information distance between two individual objects, for example, two pictures. We give several natural definitions of a universal information metric, based on length of shortest programs for either ordinary computations or reversible (dissipationless) computations. It turns out that these definitions are equivalent up to an additive logarithmic term. We show that the information distance is a universal cognitive similarity distance. We investigate the maximal correlation of the shortest programs involved, the maximal uncorrelation of programs (a generalization of the Slepian-Wolf theorem of classical information theory), and the density properties of the discrete metric spaces induced by the information distances. A related distance measures the amount of nonreversibility of a computation. Using the physical theory of reversible computation, we give...

  14. Performance and Reliability of Bonded Interfaces for High-Temperature Packaging. Annual Report

    Energy Technology Data Exchange (ETDEWEB)

    DeVoto, Douglas [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2016-04-01

    Current generation automotive power electronics packages utilize silicon devices and lead-free solder alloys. To meet stringent technical targets for 2020 and beyond (for cost, power density, specific power, efficiency and reliability), wide-bandgap devices are being considered since they offer advantages such as operation at higher frequencies, voltages, and temperatures. Traditional power electronics packages must be redesigned to utilize the full potential of wide-bandgap devices, and the die- and substrate-attach layers are key areas where new material development and validation is required. Present solder alloys do not meet the performance requirements for these new package designs while also meeting cost and hazardous substance restrictions. Sintered silver (Ag) promises to meet the needs for die- and substrate-attach interfaces but synthesis optimization and reliability evaluation must be completed. Sintered Ag material was proposed as an alternative solution in power electronics packages almost 20 years back. However, synthesis pressure requirements up 40 MPa caused a higher complexity in the production process and more stringent flatness specifications for the substrates. Recently, several manufacturers have developed sintered Ag materials that require lower (3-5 MPa) or even no bonding pressures. Degradation mechanisms for these sintered Ag materials are not well known and need to be addressed. We are addressing these aspects to some extent in this project. We are developing generalized (i.e., independent of geometry) stress intensity factor versus cycles-to-failure relations for sintered Ag. Because sintered Ag is a relatively new material for automotive power electronics, the industry currently does not have a good understanding of recommended synthesis parameters or expected reliability under prescribed conditions. It is an important deliverable of this project to transfer findings to industry to eliminate barriers to using sintered Ag as a viable and

  15. Imaging long distance propagating calcium signals in intact plant leaves with the BRET-based GFP-Aequorin reporter

    Directory of Open Access Journals (Sweden)

    Tou Cheu eXiong

    2014-02-01

    Full Text Available Calcium (Ca2+ is a second messenger involved in many plant signalling processes. Biotic and abiotic stimuli induce Ca2+ signals within plant cells, which, when decoded, enable these cells to adapt in response to environmental stresses. Multiple examples of Ca2+ signals from plants containing the fluorescent yellow cameleon sensor (YC have contributed to the definition of the Ca2+ signature in some cell types such as root hairs, pollen tubes and guard cells. YC is, however, of limited use in highly autofluorescent plant tissues, in particular mesophyll cells. Alternatively, the bioluminescent reporter aequorin enables Ca2+ imaging in the whole plant, including mesophyll cells, but this requires specific devices capable of detecting the low amounts of emitted light. Another type of Ca2+ sensor, referred to as GFP-aequorin (G5A, has been engineered as a chimeric protein, which combines the two photoactive proteins from the jellyfish Aequorea victoria, the green fluorescent protein (GFP and the bioluminescent protein aequorin. The Ca2+-dependent light-emitting property of G5A is based on a bioluminescence resonance energy transfer (BRET between aequorin and GFP. G5A has been used for over 10 years for enhanced in vivo detection of Ca2+ signals in animal tissues.Here, we apply G5A in Arabidopsis and show that G5A greatly improves the imaging of Ca2+ dynamics in intact plants. We describe a simple method to image Ca2+ signals in autofluorescent leaves of plants with a cooled charge-coupled device (cooled CCD camera. We present data demonstrating how plants expressing the G5A probe can be powerful tools for imaging of Ca2+ signals. It is shown that Ca2+ signals propagating over long distances can be visualized in intact plant leaves and are visible mainly in the veins.

  16. Human Capital Development (HCD) through Open, Distance and E-Learning: Evidence from Corporate Annual Reports (CARs) of Top South African Listed Companies

    Science.gov (United States)

    Adelowotan, Mo

    2014-01-01

    This paper discusses the role of open, distance and e-learning in the development of human resources by examining human capital development related disclosures in the corporate annual reports (CARs) of top South African listed companies. The study employed content analysis method to analyse the CARs of these companies with the aid of qualitative…

  17. CHEMICALLY BONDED CEMENTS FROM BOILER ASH AND SLUDGE WASTES. PHASE I REPORT AUGUST 1997 - JULY 1998

    Energy Technology Data Exchange (ETDEWEB)

    SUGAMA,T.; YAGER,K.A.

    2002-08-05

    In exploring methods to recycle boiler ash (BA) and waste water treatment sludge (WWTS), by-products generated from Keyspan's power plants, into commercially viable materials, we synthesized chemically bonded cements (CBC) offering the following three specific characteristics; (1) immobilization of hazardous heavy metals, such as Pb, Ni, and V, (2) rapid hardening and setting properties, and (3) development of high mechanical strength. The CBCs were prepared through an acid-base reaction between these by-products acting as the solid base reactants and the sodium polyphosphate solution as the cement-forming acid reactant, followed by a hydrating reaction. Furthermore, two additives, the calcium aluminate cements (CAC) and the calcium silicate cements (CSC) were incorporated into the CBC systems to improve their properties. Using a CBC formulation consisting of 53.8 wt% WWTS, 23.1 wt% CSC, and 23.1 wt% [40 wt% -(-NaPO{sub 3}-)-{sub n}]{sub 2} the Toxicity Characteristics Leaching Procedure (TCLP) tests showed that the concentrations of Pb, Ni, and V metals leached out from the specimens were minimal. This formulation originally contained {approx} 28800 mg/kg of Pb, {approx} 6300 mg/kg of Ni, and {approx} 11130 mg/kg of V; the amounts leaching into the acid extraction fluid were only 0.15 mg/L of Pb, 0.15 mg/L of Ni, and 4.63 mgiL of V. On the other hand, CBC specimens derived from a formulation consisting of 42 wt% BA, 18 wt% CAC and 40 wt% [40 wt% -(-NaPO{sub 3}-)-{sub n}] displayed an excellent compressive strength of 10.8 MPa at an early curing age of 2 hours after mixing at room temperature. The reason for its rapid hardening was due to a high exothermic energy evolved by the acid-base reaction. Furthermore, when these specimens were immersed for 28 days in water at 25 C, and exposed for 20 hours to steam at 80 C, a very high compressive strength of 3.32 MPa developed. Two physico-chemical factors played an important role in improving the mechanical strength

  18. CHEMICALLY BONDED CEMENTS FROM BOILER ASH AND SLUDGE WASTES. PHASE II REPORT, SEPT.1998-JULY 1999.

    Energy Technology Data Exchange (ETDEWEB)

    SUGAMA,T.YAGER,K.A.BLANKENHORN,D.(KEYSPAN R AND D INITIATIVE)

    1999-08-01

    Based upon the previous Phase I research program aimed at looking for ways of recycling the KeySpan-generated wastes, such as waste water treatment sludge (WWTS) and bottom ash (BA), into the potentially useful cementitious materials called chemically bonded cement (CBC) materials, the emphasis of this Phase II program done at Brookhaven National Laboratory, in a period of September 1998 through July 1999, was directed towards the two major subjects: One was to assess the technical feasibility of WWTS-based CBC material for use as Pb-exchange adsorbent (PEA) which remediates Pb-contaminated soils in the field; and the other was related to the establishment of the optimum-packaging storage system of dry BA-based CBC components that make it a promising matrix material for the steam-cured concrete products containing sand and coarse aggregate. To achieve the goal of the first subject, a small-scale field demonstration test was carried out. Using the PEA material consisting of 30 wt% WWTS, 13 wt% Type I cement and 57 wt% water, the PES slurry was prepared using a rotary shear concrete mixer, and then poured on the Pb-contaminated soil. The PEA-to-soil ratio by weight was a factor of 2.0. The placed PEA slurry was blended with soil using hand mixing tools such as claws and shovels. The wettability of soils with the PEA was very good, thereby facilitating the soil-PEA mix procedures. A very promising result was obtained from this field test; in fact, the mount of Pb leached out from the 25-day-aged PEA-treated soil specimen was only 0.74 mg/l, meeting the requirement for EPA safe regulation of < 5 mg/l. In contrast, a large amount (26.4 mg/l) of Pb was detected from the untreated soil of the same age. Thus, this finding demonstrated that the WWTS-based CBC has a potential for use as PEA material. Regarding the second subject, the dry-packed storage system consisting of 68.7 wt% BA, 13.0 wt% calcium aluminate cement (CAC), 13.0 wt% Type I portland cement and 5.3 wt

  19. Molecularly Tuning the Radicaloid N-H···O═C Hydrogen Bond.

    Science.gov (United States)

    Lu, Norman; Chung, Wei-Cheng; Ley, Rebecca M; Lin, Kwan-Yu; Francisco, Joseph S; Negishi, Ei-Ichi

    2016-03-01

    Substituent effects on the open shell N-H···O═C hydrogen-bond has never been reported. This study examines how 12 functional groups composed of electron donating groups (EDG), halogen atoms and electron withdrawing groups (EWG) affect the N-H···O═C hydrogen-bond properties in a six-membered cyclic model system of O═C(Y)-CH═C(X)N-H. It is found that group effects on this open shell H-bonding system are significant and have predictive trends when X = H and Y is varied. When Y is an EDG, the N-H···O═C hydrogen-bond is strengthened; and when Y is an EWG, the bond is weakened; whereas the variation in electronic properties of X group do not exhibit a significant impact upon the hydrogen bond strength. The structural impact of the stronger N-H···O═C hydrogen-bond are (1) shorter H and O distance, r(H···O) and (2) a longer N-H bond length, r(NH). The stronger N-H···O═C hydrogen-bond also acts to pull the H and O in toward one another which has an effect on the bond angles. Our findings show that there is a linear relationship between hydrogen-bond angle and N-H···O═C hydrogen-bond energy in this unusual H-bonding system. In addition, there is a linear correlation of the r(H···O) and the hydrogen bond energy. A short r(H···O) distance corresponds to a large hydrogen bond energy when Y is varied. The observed trends and findings have been validated using three different methods (UB3LYP, M06-2X, and UMP2) with two different basis sets.

  20. A survey of U.S. Fish and Wildlife Service employees regarding topics for distance education-Summary report to respondents

    Science.gov (United States)

    Ratz, Joan M.; Shuster, Rudy M.; Marcy, Ann M.

    2011-01-01

    This report provides a summary of responses to the questions included in the U.S. Fish and Wildlife Service (FWS) National Conservation Training Center (NCTC) Distance Education survey conducted from January 26, 2010, to February 8, 2010. The survey included questions for two studies sponsored by the Division of Education Outreach (DEO) at the NCTC. The first study identifies the topics of interest to FWS employees on which training could be provided via distance education. The topics were limited to the area of conservation and environmental education, outreach, and partnerships because these topics are within the scope of the DEO. The second study focused on characterizing the relation between onsite course enrollment at NCTC and distance education offerings. Because there were only a few questions on the survey for the second study and because the target populations were the same for both, the two surveys were combined.

  1. Minimally invasive preparation and design of a cantilevered, all-ceramic, resin-bonded, fixed partial denture in the esthetic zone: a case report and descriptive review.

    Science.gov (United States)

    Barwacz, Christopher A; Hernandez, Marcela; Husemann, R Henry

    2014-01-01

    Resin-bonded, fixed partial dentures have the potential to offer a minimally invasive, fixed-prosthetic approach to tooth replacement in patients who may not be candidates for implant therapy. However, traditional preparation protocols often recommend extensive preparation designs on two abutment teeth, thereby potentially compromising the long-term health of the adjacent abutments and often resulting in unilateral debonding of one of the retainers in the long term. In light of advances in high-strength ceramic systems capable of being reliably bonded to tooth structure and offering improved esthetic outcomes, as well as clinical and case-series research demonstrating improved survivability of cantilevered resin-bonded fixed partial dentures, new preparation designs and methodologies can be advocated. The following case report demonstrates the clinical application of sonoabrasion, coupled with a dental operating microscope, to minimally prepare a single abutment for a cantilevered, all-ceramic resin-bonded fixed partial denture. Relevant historic and contemporary literature regarding double versus single-retainer resin-bonded fixed partial dentures are reviewed, as well as clinical conditions that are most favorable for such restorations to have an optimal long-term prognosis. If appropriate clinical conditions exist, a cantilevered, all-ceramic, resin-bonded, fixed partial denture may be the most conservative means of tooth replacement in a patient who is not a candidate for an endosseous implant. © 2013 Wiley Periodicals, Inc.

  2. Additional disulfide bonds in insulin

    DEFF Research Database (Denmark)

    Vinther, Tine N; Pettersson, Ingrid; Huus, Kasper

    2015-01-01

    The structure of insulin, a glucose homeostasis-controlling hormone, is highly conserved in all vertebrates and stabilized by three disulfide bonds. Recently, we designed a novel insulin analogue containing a fourth disulfide bond located between positions A10-B4. The N-terminus of insulin's B......-chain is flexible and can adapt multiple conformations. We examined how well disulfide bond predictions algorithms could identify disulfide bonds in this region of insulin. In order to identify stable insulin analogues with additional disulfide bonds, which could be expressed, the Cβ cut-off distance had...... in comparison to analogues with additional disulfide bonds that were more difficult to predict. In contrast, addition of the fourth disulfide bond rendered all analogues resistant to fibrillation under stress conditions and all stable analogues bound to the insulin receptor with picomolar affinities. Thus...

  3. Bond Issues.

    Science.gov (United States)

    Pollack, Rachel H.

    2000-01-01

    Notes trends toward increased borrowing by colleges and universities and offers guidelines for institutions that are considering issuing bonds to raise money for capital projects. Discussion covers advantages of using bond financing, how use of bonds impacts on traditional fund raising, other cautions and concerns, and some troubling aspects of…

  4. Three self-report questionnaires of the early mother-to-infant bond: reliability and validity of the Dutch version of the MPAS, PBQ and MIBS.

    Science.gov (United States)

    van Bussel, Johan C H; Spitz, Bernard; Demyttenaere, Koen

    2010-10-01

    In this study, we investigated the reliability and validity of three self-report questionnaires measuring the early emotional bond between a mother and her newborn infant: the Maternal Postpartum Attachment Scale (MPAS), the Postpartum Bonding Questionnaire (PBQ) and the Mother-to-Infant Bonding Scale (MIBS). In a monocentric prospective observational cohort study, 263 mothers completed the MPAS, the PBQ and the MIBS at 8-12 and at 20-25 weeks postpartum. The participants also completed measures of mental health and, during their pregnancy, measures of recalled parental bonding, adult romantic attachment, antenatal attachment and social desirability. In our study, the internal reliabilities of the PBQ and the MPAS were high at 8-12 weeks postpartum but dropped significantly at 20-25 weeks postpartum. Moderately strong correlations between the scales of the PBQ, the MPAS and the MIBS supported their construct validity. Further, weak correlations were found with social desirability and adult attachment representations, whereas moderate correlations were found with antenatal feelings of attachment and antenatal attitudes to motherhood. Finally, maternal feelings of bonding were also moderately associated with maternal mood. Overall, our findings suggest that the MPAS, the PBQ and the MIBS provide a reliable and valid indication of the early emotional tie between a woman and her newborn infant.

  5. F-111 Adhesive Bonded Repairs Assessment Program - Progress Report 2: Analysis of FM300-2K Repairs

    Science.gov (United States)

    2015-01-01

    areas of honeycomb- core stiffened aluminium panels, which exist across the fuselage and are used for most control surfaces. The honeycomb panels...typically are manufactured by adhesively bonding an upper and lower aluminium skin to aluminium honeycomb-core. The structure provides added stiffness to... aluminium doubler of similar thickness to the skin thickness is bonded over the exposed core with a prescribed overlap length (Figure 1). The purpose

  6. Bond forming reactions of carbyne and nitrene complexes. Final technical report for DE-FG02-96ER14608

    Energy Technology Data Exchange (ETDEWEB)

    Templeton, J.L.

    2002-09-01

    An isolobal relationship among terminal carbyne, nitrene and oxo ligands provided the basis for our efforts to explore new synthetic routes to such complexes and to probe bond forming reactions of these ligands. The specific goals of this project were to explore reactions of carbyne and nitrene ligands, and a summary of our results follows. Manipulation of metal-ligand pi bonds to control reactivity patterns provided the conceptual basis for this work. New transformations and coupling reactions of the CR and NR moieties bound to metal centers have been explored and transformations of carbyne or nitrene ligands have been achieved. Perhaps the most exciting results have come in the area of the simplest ligand: the CH carbyne unit. Treatment of [Tp'(CO){sub 2}W{triple_bond}C-PPh{sub 3}] [PF{sub 6}] Tp' = hydridotris(3,5-dimethylpyrazolylborate) with Na[HBEt{sub 3}] forms the methylidyne complex Tp' (CO){sub 2}W{triple_bond}C-H via formyl and carbene intermediates. Protonation of the Tp'(CO){sub 2}W{triple_bond}C-H methylidyne complex yields the cationic agostic methylidene complex, [Tp'(CO){sub 2}W=CH{sub 2}][BF{sub 4}]. The methylidyne complex with a pK{sub a} of 28.7 can be deprotonated to provide the anionic terminal carbide Tp' (CO){sub 2}W{triple_bond}C-Li; a resonance at 556 ppm in the {sup 13}C NMR spectrum has been assigned to the carbide carbon. Addition of excess Na[HBEt{sub 3}] to Tp'(CO){sub 2}W{triple_bond}C-H generates the anionic methylidene complex [Na] [Tp'(CO){sub 2}W{triple_bond}CH{sub 2}].

  7. Effects of Explosive Type Strength Training on Selected Physical and Technical Performance Characteristics in Middle Distance Running - a Case Report

    Directory of Open Access Journals (Sweden)

    Maćkała Krzysztof

    2015-03-01

    Full Text Available Introduction. Distance running performance is a simple function of developing high speeds and maintaining this speed as long as possible. Thus a correct running technique becomes an important component of performance. Technique is effective if the competitor can reach a better performance result with the same or lower energy consumption. The purpose of this investigation was to examine a six weeks application explosive type strength training on lower extremities power and maximum speed performance improvement in order to facilitate running technique in sub-elite male middle-distance runner. Material and methods. A sub-elite runner performed twice a week special exercises and running drills. He completed a pre and post-training jumping (SJ, CMJ, standing long jump, standing five jump and speed (20 m from standing and flying start field tests. For kinematical analysis, a video (SIMI Motion System of a 10 m sprint from a 20 m flying start was collected. Results. Improvement occurred in all measurements but strong changes were evident in the 10 m from 20 flying start and in stride frequency from 3.90 to 4.01 Hz, due to decreasing of ground contact time from 160 to 156 ms. No strong evidence in the participant's running technique changes. Conclusion. This proved that six weeks of dynamic type strength program seems to improve neuromuscular characteristics of running speed and explosive power and no changes in running technique.

  8. Parental Bonding

    Directory of Open Access Journals (Sweden)

    T. Paul de Cock

    2014-08-01

    Full Text Available Estimating the early parent–child bonding relationship can be valuable in research and practice. Retrospective dimensional measures of parental bonding provide a means for assessing the experience of the early parent–child relationship. However, combinations of dimensional scores may provide information that is not readily captured with a dimensional approach. This study was designed to assess the presence of homogeneous groups in the population with similar profiles on parental bonding dimensions. Using a short version of the Parental Bonding Instrument (PBI, three parental bonding dimensions (care, authoritarianism, and overprotection were used to assess the presence of unobserved groups in the population using latent profile analysis. The class solutions were regressed on 23 covariates (demographics, parental psychopathology, loss events, and childhood contextual factors to assess the validity of the class solution. The results indicated four distinct profiles of parental bonding for fathers as well as mothers. Parental bonding profiles were significantly associated with a broad range of covariates. This person-centered approach to parental bonding has broad utility in future research which takes into account the effect of parent–child bonding, especially with regard to “affectionless control” style parenting.

  9. Self-reported emotional and behavioral symptoms, parent-adolescent bonding and family functioning in clinically referred adolescent offspring of Croatian PTSD war veterans.

    Science.gov (United States)

    Boričević Maršanić, Vlatka; Aukst Margetić, Branka; Jukić, Vlado; Matko, Vlasta; Grgić, Vesna

    2014-05-01

    The presence of posttraumatic stress disorder (PTSD) in male war veterans has been linked with family dysfunction and psychopathology in their children [1, 2]. This study aimed to evaluate self-reported emotional and behavioral symptoms, parent-adolescent bonding and family functioning in clinically referred adolescent offspring of Croatian PTSD war veterans and determine the degree that parent-child bonding and family functioning contributed to adolescent behavior problems. Internalizing and externalizing behavior problems, parent-child bonding and family functioning were assessed in a sample of clinically referred Croatian PTSD veterans adolescent offspring (N = 122) and non-PTSD veteran adolescent offspring (N = 122) matched for age, sex, educational level, family income, parental employment status, ethnicity, and residential area. Youth Self-Report, Parental Bonding Instrument, Family Assessment Device were used. Adolescent offspring of PTSD veterans reported having significantly more internalizing and externalizing problems than non-PTSD veteran offspring, and also more difficulties in their family functioning, lower levels of maternal and paternal care, and more impaired mother-child and father-child bonding than control subjects. Internalizing symptoms were associated with family dysfunction, while externalizing symptoms were associated with paternal overcontrol/overprotection, and low maternal and paternal care. In conclusion, the increase in internalizing and externalizing symptoms as well as family and parental dysfunction among clinically referred adolescent offspring of PTSD veterans compared to their non-PTSD veteran counterparts indicates a need for early detection and interventions targeting both adolescent psychopathology and family relationships.

  10. Indications of chemical bond contrast in AFM images of a hydrogen-terminated silicon surface

    Science.gov (United States)

    Labidi, Hatem; Koleini, Mohammad; Huff, Taleana; Salomons, Mark; Cloutier, Martin; Pitters, Jason; Wolkow, Robert A.

    2017-02-01

    The origin of bond-resolved atomic force microscope images remains controversial. Moreover, most work to date has involved planar, conjugated hydrocarbon molecules on a metal substrate thereby limiting knowledge of the generality of findings made about the imaging mechanism. Here we report the study of a very different sample; a hydrogen-terminated silicon surface. A procedure to obtain a passivated hydrogen-functionalized tip is defined and evolution of atomic force microscopy images at different tip elevations are shown. At relatively large tip-sample distances, the topmost atoms appear as distinct protrusions. However, on decreasing the tip-sample distance, features consistent with the silicon covalent bonds of the surface emerge. Using a density functional tight-binding-based method to simulate atomic force microscopy images, we reproduce the experimental results. The role of the tip flexibility and the nature of bonds and false bond-like features are discussed.

  11. Indications of chemical bond contrast in AFM images of a hydrogen-terminated silicon surface

    Science.gov (United States)

    Labidi, Hatem; Koleini, Mohammad; Huff, Taleana; Salomons, Mark; Cloutier, Martin; Pitters, Jason; Wolkow, Robert A.

    2017-01-01

    The origin of bond-resolved atomic force microscope images remains controversial. Moreover, most work to date has involved planar, conjugated hydrocarbon molecules on a metal substrate thereby limiting knowledge of the generality of findings made about the imaging mechanism. Here we report the study of a very different sample; a hydrogen-terminated silicon surface. A procedure to obtain a passivated hydrogen-functionalized tip is defined and evolution of atomic force microscopy images at different tip elevations are shown. At relatively large tip-sample distances, the topmost atoms appear as distinct protrusions. However, on decreasing the tip-sample distance, features consistent with the silicon covalent bonds of the surface emerge. Using a density functional tight-binding-based method to simulate atomic force microscopy images, we reproduce the experimental results. The role of the tip flexibility and the nature of bonds and false bond-like features are discussed. PMID:28194036

  12. 2 Cases of Bullosis Diabeticorum following Long-Distance Journeys by Road: A Report of 2 Cases

    Directory of Open Access Journals (Sweden)

    Fatima Bello

    2012-01-01

    Full Text Available Background. Bullosis diabeticorum is a distinct, spontaneous, noninflammatory, and blistering condition of acral skin that is unique to diabetics. It is rare. Exact aetiopathogenesis is not known, but many attributed peripheral neuropathy as a potent risk factor, others hypothesized the role of trauma, UV light, and nephropathy. Aim. To present cases of bullosis diabeticorum following long-distance journeys by road. Methods. History and physical examinations were done on 2 diabetics who presented with bilateral feet bullae following a long journey. Biopsy of a circumferential area of the bullae including adjoining apparently normal skin was done. Results. Features of peripheral neuropathy were noted. One developed digital gangrene without features of peripheral vascular disease. Culture of aspirate from a bullae yielded Staphylococcus aureus. Tissue biopsy showed hyperkeratotic focally acanthotic pigmented epidermis with subcorneal separation of the granular layer of the epidermis by aggregates of viable and nonviable polymorphs and lymphocytes. There is mild acantholysis of the epidermis, and a fibrocollagenous dermis which is moderately infiltrated by lymphocytes. Conclusion. Long journeys by road is a strong factor in the aetiopathogenesis of bullosis diabeticorum on a background of peripheral neuropathy. Diabetics especially those with peripheral neuropathy should be cautious while traveling long journeys by road.

  13. 2 Cases of Bullosis Diabeticorum following Long-Distance Journeys by Road: A Report of 2 Cases.

    Science.gov (United States)

    Bello, Fatima; Samaila, O Modupe; Lawal, Yakubu; Nkoro, U Kufre

    2012-01-01

    Background. Bullosis diabeticorum is a distinct, spontaneous, noninflammatory, and blistering condition of acral skin that is unique to diabetics. It is rare. Exact aetiopathogenesis is not known, but many attributed peripheral neuropathy as a potent risk factor, others hypothesized the role of trauma, UV light, and nephropathy. Aim. To present cases of bullosis diabeticorum following long-distance journeys by road. Methods. History and physical examinations were done on 2 diabetics who presented with bilateral feet bullae following a long journey. Biopsy of a circumferential area of the bullae including adjoining apparently normal skin was done. Results. Features of peripheral neuropathy were noted. One developed digital gangrene without features of peripheral vascular disease. Culture of aspirate from a bullae yielded Staphylococcus aureus. Tissue biopsy showed hyperkeratotic focally acanthotic pigmented epidermis with subcorneal separation of the granular layer of the epidermis by aggregates of viable and nonviable polymorphs and lymphocytes. There is mild acantholysis of the epidermis, and a fibrocollagenous dermis which is moderately infiltrated by lymphocytes. Conclusion. Long journeys by road is a strong factor in the aetiopathogenesis of bullosis diabeticorum on a background of peripheral neuropathy. Diabetics especially those with peripheral neuropathy should be cautious while traveling long journeys by road.

  14. A displaced stress fracture of the femoral neck in an adolescent female distance runner with female athlete triad: A case report.

    Science.gov (United States)

    Okamoto, Shinichi; Arai, Yuji; Hara, Kunio; Tsuzihara, Takashi; Kubo, Toshikazu

    2010-03-05

    This report presents a case of a displaced stress fracture of the femoral neck in an adolescent female distance runner with amenorrhea. Both reduction and internal fixation were performed early after the injury. At 24 months postoperatively, magnetic resonance imaging and bone scintigraphy showed no positive signs of femoral head necrosis and bone union was confirmed on plain X-ray. A medical examination for the presence of the signs of the female athlete triad by checking weight, calorie intake and menstrual cycles is most important to prevent such stress fractures. Athletes as well as their coaches or parents therefore need to understand female athlete triad.

  15. A displaced stress fracture of the femoral neck in an adolescent female distance runner with female athlete triad: A case report

    Directory of Open Access Journals (Sweden)

    Okamoto Shinichi

    2010-03-01

    Full Text Available Abstract This report presents a case of a displaced stress fracture of the femoral neck in an adolescent female distance runner with amenorrhea. Both reduction and internal fixation were performed early after the injury. At 24 months postoperatively, magnetic resonance imaging and bone scintigraphy showed no positive signs of femoral head necrosis and bone union was confirmed on plain X-ray. A medical examination for the presence of the signs of the female athlete triad by checking weight, calorie intake and menstrual cycles is most important to prevent such stress fractures. Athletes as well as their coaches or parents therefore need to understand female athlete triad.

  16. Rapport in Distance Education

    Science.gov (United States)

    Murphy, Elizabeth; Rodriguez-Manzanares, Maria A.

    2012-01-01

    Rapport has been recognized as important in learning in general but little is known about its importance in distance education (DE). The study we report on in this paper provides insights into the importance of rapport in DE as well as challenges to and indicators of rapport-building in DE. The study relied on interviews with 42 Canadian…

  17. Hydrogen bonding in asphaltenes and coal. Progress report, July 1, 1976--December 31, 1976. [Between quinoline and o-phenylphenol

    Energy Technology Data Exchange (ETDEWEB)

    Li, N.C.

    1977-01-04

    Calorimetric studies of hydrogen bonding between quinoline and o-phenylphenol were carried out because they represent the nitrogenous heteronuclear aromatic bases and aromatic bases, respectively, found in the liquefaction products from coal. Further experiments are planned to try to resolve discrepancies observed between experimental and calculated values. (EJH)

  18. Lifetime of the P-selectin-carbohydrate bond and its response to tensile force in hydrodynamic flow

    Science.gov (United States)

    Alon, Ronen; Hammer, Daniel A.; Springer, Timothy A.

    1995-04-01

    SELECTINS tether to the blood vessel wall leukocytes that are flowing in the bloodstream and support subsequent labile rolling interactions as the leukocytes are subjected to hydrodynamic drag forces1,2. To support this rolling, selectins have been proposed to have rapid bond association and dissociation rate constants, and special mechanical properties linking tensile forces and bond dissociation3-6. We have visualized transient tethering and release of neutrophils in hydrodynamic flow on lipid bilayers containing densities of P-selectin below those required to support rolling. We report here that transient tethers had first-order kinetics and other characteristics suggesting a unimolecular interaction between P-selectin and its glycoprotein ligand (PSGL-1). The unstressed dissociation constant (off rate) was 1 s-1. Hydrodynamic shear stresses of up to 1.1 dyn cm-2, corresponding to a force on the bond of up to HOpN, increased the off rate only modestly, to 3.5 s-1. The data was adequately matched by a proposed equation7 relating off rate to the exponential of tensile force on the bond and the bond interaction distance, and gave a bond interaction distance of 0.5Å. This distance is compatible with hydrogen and metal coordination bonds between P-selectin and PSGL-1. Fast on and off rates, together with the high tensile strength of the selectin bond, appear necessary to support rolling at physiological shear stresses.

  19. Bond Boom

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    The Ministry of Finance recently kick-started a pilot program allowing local governments of Shanghai and Shenzhen,and Zhejiang and Guangdong provinces to issue bonds for the first time.How will the new policy affect fiscal capacities of local governments and the broader economy? What else should the country do to build a healthy bond market? Economists and experts discussed these issues in an interview with the Shanghai Securities Journal.Edited excerpts follow.

  20. Bond Boom

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    The Ministry of Finance recently kick-started a pilot program allowing local governments of Shanghai and Shenzhen, and Zhejiang and Guangdong provinces to issue bonds for the first time. How will the new policy affect fiscal capacities of local governments and the broader economy? What else should the country do to build a healthy bond market? Economists and experts discussed these issues in an interview with the ShanghaiSecuritiesJournal. Edited excerpts follow:

  1. CRADA/NFE-15-05761 Report: Additive Manufacturing of Isotropic NdFeB Bonded Permanent Magnets

    Energy Technology Data Exchange (ETDEWEB)

    Paranthaman, M Parans [ORNL

    2016-07-18

    The technical objective of this technical collaboration phase I proposal is to fabricate net shape isotropic NdFeB bonded magnets utilizing additive manufacturing technologies at the ORNL MDF. The goal is to form complex shapes of thermoplastic and/or thermoset bonded magnets without expensive tooling and with minimal wasted material. Two additive manufacturing methods; the binder jet process; and big area additive manufacturing (BAAM) were used. Binder jetting produced magnets with the measured density of the magnet of 3.47 g/cm3, close to 46% relative to the NdFeB single crystal density of 7.6 g/cm3 were demonstrated. Magnetic measurements indicate that there is no degradation in the magnetic properties. In addition, BAAM was used to fabricate isotropic near-net-shape NdFeB bonded magnets with magnetic and mechanical properties comparable or better than those of traditional injection molded magnets. The starting polymer magnet composite pellets consist of 65 vol% isotropic NdFeB powder and 35 vol% polyamide (Nylon-12). The density of the final BAAM magnet product reached 4.8 g/cm3, and the room temperature magnetic properties are: Intrinsic coercivity Hci = 8.65 kOe, Remanence Br = 5.07 kG, and energy product (BH)max = 5.47 MGOe (43.50 kJ/m3). This study provides a new pathway for preparing near-net shape bonded magnets for various magnetic applications.

  2. Bonding All-Ceramic Restorations with Two Resins Cement Techniques: A Clinical Report of Three-Year Follow-Up

    Science.gov (United States)

    Anchieta, Rodolfo Bruniera; Rocha, Eduardo Passos; de Almeida, Erika Oliveira; Junior, Amilcar Chagas Freitas; Martini, Ana Paula

    2011-01-01

    Ceramics have been widely used for esthetic and functional improvements. The resin cement is the material of choice for bonding ceramics to dental substrate and it can also dictate the final esthetic appearance and strength of the restoration. The correct use of the wide spectrum of resin luting agents available depends on the dental tooth substrate. This article presents three-year clinical results of a 41 years old female patient B.H.C complaining about her unattractive smile. Two all-ceramic crowns and two laminates veneers were placed in the maxillary incisors and cemented with a self-adhesive resin luting cement and conventional resin luting cement, respectively. After a three-year follow-up, the restorations and cement/teeth interface were clinically perfect with no chipping, fractures or discoloration. Proper use of different resin luting cements shows clinical appropriate behavior after a three-year follow-up. Self-adhesive resin luting cement may be used for cementing all-ceramic crowns with high predictability of success, mainly if there is a large dentin surface available for bonding and no enamel at the finish line. Otherwise, conventional resin luting agent should be used for achieving an adequate bonding strength to enamel. PMID:21912505

  3. Comparison of Bond in Roll-bonded and Adhesively Bonded Aluminums

    Science.gov (United States)

    Schwensfeir, R. J., Jr.; Trenkler, G.; Delagi, R. G.; Forster, J. A.

    1985-01-01

    Lap-shear and peel test measurements of bond strength have been carried out as part of an investigation of roll bonding of 2024 and 7075 aluminum alloys. Shear strengths of the bonded material in the F temper are in the range of 14 to 16 ksi. Corresponding peel strengths are 120 to 130 lb/inch. These values, which are three to five times those reported in the literature for adhesively bonded 2024 and 7075, are a result of the true metallurgical bond achieved. The effects of heat-treating the bonded material are described and the improvements in bond strength discussed relative to the shear strength of the parent material. The significance of the findings for aerospace applications is discussed.

  4. Direct and Auger Electron-Induced, Single- and Double-Strand Breaks on Plasmid DNA Caused by 99mTc-Labeled Pyrene Derivatives and the Effect of Bonding Distance

    Science.gov (United States)

    Reissig, Falco; Mamat, Constantin; Steinbach, Joerg; Pietzsch, Hans-Juergen; Freudenberg, Robert; Navarro-Retamal, Carlos; Caballero, Julio; Kotzerke, Joerg; Wunderlich, Gerd

    2016-01-01

    It is evident that 99mTc causes radical-mediated DNA damage due to Auger electrons, which were emitted simultaneously with the known γ-emission of 99mTc. We have synthesized a series of new 99mTc-labeled pyrene derivatives with varied distances between the pyrene moiety and the radionuclide. The pyrene motif is a common DNA intercalator and allowed us to test the influence of the radionuclide distance on damages of the DNA helix. In general, pUC 19 plasmid DNA enables the investigation of the unprotected interactions between the radiotracers and DNA that results in single-strand breaks (SSB) or double-strand breaks (DSB). The resulting DNA fragments were separated by gel electrophoresis and quantified by fluorescent staining. Direct DNA damage and radical-induced indirect DNA damage by radiolysis products of water were evaluated in the presence or absence of the radical scavenger DMSO. We demonstrated that Auger electrons directly induced both SSB and DSB in high efficiency when 99mTc was tightly bound to the plasmid DNA and this damage could not be completely prevented by DMSO, a free radical scavenger. For the first time, we were able to minimize this effect by increasing the carbon chain lengths between the pyrene moiety and the 99mTc nuclide. However, a critical distance between the 99mTc atom and the DNA helix could not be determined due to the significantly lowered DSB generation resulting from the interaction which is dependent on the type of the 99mTc binding motif. The effect of variable DNA damage caused by the different chain length between the pyrene residue and the Tc-core as well as the possible conformations of the applied Tc-complexes was supplemented with molecular dynamics (MD) calculations. The effectiveness of the DNA-binding 99mTc-labeled pyrene derivatives was demonstrated by comparison to non-DNA-binding 99mTcO4–, since nearly all DNA damage caused by 99mTcO4– was prevented by incubating with DMSO. PMID:27583677

  5. Partial-prep bonded restorations in the anterior dentition: Long-term gingival health and predictability. A case report.

    Science.gov (United States)

    Molina, Ivan Contreras; Molina, Gil Contreras; Stanley, Kyle; Lago, Carlo; Xavier, Clessius Ferreira; Volpato, Claudia Angela Maziero

    2016-01-01

    Bonded porcelain restorations are a predictable and durable treatment option that can restore not only the strength and function of the teeth but also the esthetic appearance. One important issue in adhesive dentistry is the preservation of sound enamel. Following biomimetic principles, employing minimally invasive applications and adhesive technologies is of paramount importance for successful restorations. While it is widely accepted that minimally invasive restorative techniques should be favored, there is still some controversy over the noninvasive approaches. The purpose of this article is to question the complete "no-prep veneer" concept due to the possible negative effects on periodontal health caused by excessive contour and overhangs of the ceramic restoration, and to propose a new method to assess the quality and longevity of veneers with a partial-prep concept.

  6. Intermolecular atom-atom bonds in crystals - a chemical perspective.

    Science.gov (United States)

    Thakur, Tejender S; Dubey, Ritesh; Desiraju, Gautam R

    2015-03-01

    Short atom-atom distances between molecules are almost always indicative of specific intermolecular bonding. These distances may be used to assess the significance of all hydrogen bonds, including the C-H⋯O and even weaker C-H⋯F varieties.

  7. Cooperativity in beryllium bonds.

    Science.gov (United States)

    Alkorta, Ibon; Elguero, José; Yáñez, Manuel; Mó, Otilia

    2014-03-07

    A theoretical study of the beryllium bonded clusters of the (iminomethyl)beryllium hydride and (iminomethyl)beryllium fluoride [HC(BeX)=NH, X = H, F] molecules has been carried out at the B3LYP/6-311++G(3df,2p) level of theory. Linear and cyclic clusters have been characterized up to the decamer. The geometric, energetic, electronic and NMR properties of the clusters clearly indicate positive cooperativity. The evolution of the molecular properties, as the size of the cluster increases, is similar to those reported in polymers held together by hydrogen bonds.

  8. AAA-DDD triple hydrogen bond complexes.

    Science.gov (United States)

    Blight, Barry A; Camara-Campos, Amaya; Djurdjevic, Smilja; Kaller, Martin; Leigh, David A; McMillan, Fiona M; McNab, Hamish; Slawin, Alexandra M Z

    2009-10-01

    Experiment and theory both suggest that the AAA-DDD pattern of hydrogen bond acceptors (A) and donors (D) is the arrangement of three contiguous hydrogen bonding centers that results in the strongest association between two species. Murray and Zimmerman prepared the first example of such a system (complex 3*2) and determined the lower limit of its association constant (K(a)) in CDCl(3) to be 10(5) M(-1) by (1)H NMR spectroscopy (Murray, T. J. and Zimmerman, S. C. J. Am. Chem. Soc. 1992, 114, 4010-4011). The first cationic AAA-DDD pair (3*4(+)) was described by Bell and Anslyn (Bell, D. A. and Anslyn, E. A. Tetrahedron 1995, 51, 7161-7172), with a K(a) > 5 x 10(5) M(-1) in CH(2)Cl(2) as determined by UV-vis spectroscopy. We were recently able to quantify the strength of a neutral AAA-DDD arrangement using a more chemically stable AAA-DDD system, 6*2, which has an association constant of 2 x 10(7) M(-1) in CH(2)Cl(2) (Djurdjevic, S., Leigh, D. A., McNab, H., Parsons, S., Teobaldi, G. and Zerbetto, F. J. Am. Chem. Soc. 2007, 129, 476-477). Here we report on further AA(A) and DDD partners, together with the first precise measurement of the association constant of a cationic AAA-DDD species. Complex 6*10(+)[B(3,5-(CF(3))(2)C(6)H(3))(4)(-)] has a K(a) = 3 x 10(10) M(-1) at RT in CH(2)Cl(2), by far the most strongly bound triple hydrogen bonded system measured to date. The X-ray crystal structure of 6*10(+) with a BPh(4)(-) counteranion shows a planar array of three short (NH...N distances 1.95-2.15 A), parallel (but staggered rather than strictly linear; N-H...N angles 165.4-168.8 degrees), primary hydrogen bonds. These are apparently reinforced, as theory predicts, by close electrostatic interactions (NH-*-N distances 2.78-3.29 A) between each proton and the acceptor atoms of the adjacent primary hydrogen bonds.

  9. Higher Education: Use of New Data Could Help Improve Oversight of Distance Education. Report to Congressional Requesters. GAO-12-39

    Science.gov (United States)

    Scott, George A.

    2011-01-01

    As the largest provider of financial aid in higher education, with about $134 billion in Title IV funds provided to students in fiscal year 2010, the Department of Education (Education) has a considerable interest in distance education. Distance education--that is, offering courses by the Internet, video, or other forms outside the classroom--has…

  10. The Interaction of the Solar Wind with Solar Probe Plus - 3D Hybrid Simulation. Report 1; The Study for the Distance 4.5Rs

    Science.gov (United States)

    Lipatov, Alexander S.; Sittler, Edward C.; Hartle, Richard E.; Cooper, John F.

    2010-01-01

    Our report devotes a 3D numerical hybrid model of the interaction of the solar wind with the Solar Probe spacecraft. The Solar Probe Plus (SPP) model includes 3 main parts, namely, a non-conducting heat shield, a support system, and cylindrical section or spacecraft bus that contains the particle analysis devices and antenna. One observes an excitation of the low frequency Alfven and whistler type wave directed by the magnetic field with an amplitude of about (0.06-0.6) V/m. The compression waves and the jumps in an electric field with an amplitude of about (0.15-0.7) V/m were also observed. The wave amplitudes are comparable to or greater than previously estimated max wave amplitudes that SPP is expected to measure. The results of our hybrid simulation will be useful for understanding the plasma environment near the SPP spacecraft at the distance 4.5 Rs. Future simulation will take into account the charging of the spacecraft, the charge separation effects, an outgassing from heat shield, a photoionization and an electron impact ionization effects near the spacecraft.

  11. Hydrogen bonding motifs in a hydroxy-bisphosphonate moiety: revisiting the problem of hydrogen bond identification.

    Science.gov (United States)

    Ashouri, Mitra; Maghari, Ali; Karimi-Jafari, M H

    2015-05-28

    Bisphosphonates are important therapeutic agents in bone-related diseases and exhibit complex H-bonding networks. To assess the role of H-bonds in biophosphonate stability, a full conformational search was performed for methylenebisphosphonate (MBP) and 1-hydroxyethylidene-1,1-diphosphonate (HEDP) using the MP2 method in conjunction with the continuum solvation model. The most stable structures and their equilibrium populations were analyzed at two protonation states via assignment of H-bonding motifs to each conformer. Geometrical and topological approaches for the identification and characterization of H-bonds were compared with each other, and some of the important correlations between H-bond features were described over the entire conformational space of a hydroxy-bisphosphonate moiety. The topologically derived H-bond energy obtained from the local density of potential energy at bond critical points shows consistent correlations with other measures such as H-bond frequency shift. An inverse power form without an intercept predicts topological H-bond energies from hydrogen-acceptor distances with an RMS error of less than 1 kcal mol(-1). The consistency of this measure was further checked by building a model that reasonably reproduces the relative stabilities of different conformers from their hydrogen-acceptor distances. In all systems, the predictions of this model are improved by the consideration of weak H-bonds that have no bond critical point.

  12. Encyclopedia of distances

    CERN Document Server

    Deza, Michel Marie

    2016-01-01

    This 4th edition of the leading reference volume on distance metrics is characterized by updated and rewritten sections on some items suggested by experts and readers, as well a general streamlining of content and the addition of essential new topics. Though the structure remains unchanged, the new edition also explores recent advances in the use of distances and metrics for e.g. generalized distances, probability theory, graph theory, coding theory, data analysis. New topics in the purely mathematical sections include e.g. the Vitanyi multiset-metric, algebraic point-conic distance, triangular ratio metric, Rossi-Hamming metric, Taneja distance, spectral semimetric between graphs, channel metrization, and Maryland bridge distance. The multidisciplinary sections have also been supplemented with new topics, including: dynamic time wrapping distance, memory distance, allometry, atmospheric depth, elliptic orbit distance, VLBI distance measurements, the astronomical system of units, and walkability distance. Lea...

  13. Distance Education Council.

    Science.gov (United States)

    Indira Gandhi National Open University, New Delhi (India). Distance Education Council.

    Since its inception in India in 1962, distance education has grown in popularity. The Distance Education Council (DEC) directs distance learning within India's higher education system. The DEC's promotion, coordination, and maintenance of standards for distance education are its three major roles. Its initiatives include grants, support for…

  14. Training for Distance Teaching through Distance Learning.

    Science.gov (United States)

    Cadorath, Jill; Harris, Simon; Encinas, Fatima

    2002-01-01

    Describes a mixed-mode bachelor degree course in English language teaching at the Universidad Autonoma de Puebla (Mexico) that was designed to help practicing teachers write appropriate distance education materials by giving them the experience of being distance students. Includes a course outline and results of a course evaluation. (Author/LRW)

  15. Concept Feasibility Report for Using Co-Extrusion to Bond Metals to Complex Shapes of U-10Mo

    Energy Technology Data Exchange (ETDEWEB)

    Lavender, Curt A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Paxton, Dean M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Smith, Mark T. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Soulami, Ayoub [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Joshi, Vineet V. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Burkes, Douglas [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2013-12-01

    In support of the Convert Program of the U.S. Department of Energy’s National Nuclear Security Administration (DOE/NNSA) Global Threat Reduction Initiative (GTRI), Pacific Northwest National Laboratory (PNNL) has been investigating manufacturing processes for the uranium-10% molybdenum (U-10Mo) alloy plate fuel for the U.S. high-performance research reactors (USHPRR). This report documents the results of PNNL’s efforts to develop the extrusion process for this concept. The approach to the development of a co-extruded complex-shaped fuel has been described and an extrusion of DU-10Mo was made. The initial findings suggest that given the extrusion forces required for processing U-10Mo, the co-extrusion process can meet the production demands of the USHPRR fuel and may be a viable production method. The development activity is in the early stages and has just begun to identify technical challenges to address details such as dimensional tolerances and shape control. New extrusion dies and roll groove profiles have been developed and will be assessed by extrusion and rolling of U-10Mo during the next fiscal year. Progress on the development and demonstration of the co-extrusion process for flat and shaped fuel is reported in this document

  16. Concept Feasibility Report for Using Co-Extrusion to Bond Metals to Complex Shapes of U-10Mo

    Energy Technology Data Exchange (ETDEWEB)

    Lavender, Curt A.; Paxton, Dean M.; Smith, Mark T.; Soulami, Ayoub; Joshi, Vineet V.; Burkes, Douglas

    2013-12-30

    In support of the Convert Program of the U.S. Department of Energy’s National Nuclear Security Administration (DOE/NNSA) Global Threat Reduction Initiative (GTRI), Pacific Northwest National Laboratory (PNNL) has been investigating manufacturing processes for the uranium-10% molybdenum (U-10Mo) alloy plate fuel for the U.S. high-performance research reactors (USHPRR). This report documents the results of PNNL’s efforts to develop the extrusion process for this concept. The approach to the development of a co-extruded complex-shaped fuel has been described and an extrusion of DU-10Mo was made. The initial findings suggest that given the extrusion forces required for processing U-10Mo, the co-extrusion process can meet the production demands of the USHPRR fuel and may be a viable production method. The development activity is in the early stages and has just begun to identify technical challenges to address details such as dimensional tolerances and shape control. New extrusion dies and roll groove profiles have been developed and will be assessed by extrusion and rolling of U-10Mo during the next fiscal year. Progress on the development and demonstration of the co-extrusion process for flat and shaped fuel is reported in this document

  17. Encyclopedia of distances

    CERN Document Server

    Deza, Michel Marie

    2014-01-01

    This updated and revised third edition of the leading reference volume on distance metrics includes new items from very active research areas in the use of distances and metrics such as geometry, graph theory, probability theory and analysis. Among the new topics included are, for example, polyhedral metric space, nearness matrix problems, distances between belief assignments, distance-related animal settings, diamond-cutting distances, natural units of length, Heidegger’s de-severance distance, and brain distances. The publication of this volume coincides with intensifying research efforts into metric spaces and especially distance design for applications. Accurate metrics have become a crucial goal in computational biology, image analysis, speech recognition and information retrieval. Leaving aside the practical questions that arise during the selection of a ‘good’ distance function, this work focuses on providing the research community with an invaluable comprehensive listing of the main available di...

  18. Influence of bonding temperature on interfacial phases in diffusion-bonded joints of 6063, 5005, and 7NO1 alloys. Report 3. Diffusion-bonding mechanism of aluminum alloys by transmission electron microscopy; 6063, 5005 oyobi 7NO1 gokin no setsugo kaimen no keiseiso ni oyobosu setsugo ondo no eikyo. 3. Toka denshi kenbikyo kansatsu ni yoru Al gokin no kakusan setsugo kiko no kento

    Energy Technology Data Exchange (ETDEWEB)

    Kotani, K. [Industrial Research Inst. of Aichi Prefecture, Aichi (Japan); Ikeuchi, K.; Matsuda, F. [Osaka Univ., Osaka (Japan). Welding Research Inst.

    1996-05-05

    The authors of the paper have observed oxide films and oxide grains formed at joint interfaces of practical alloys with a transmission electron microscopy up to now. In this paper, among the practical alloys reported in the former report, 3 kinds of alloys with different Mg contents, Al-Mg-Si 6063 alloy, Al-Mg 5005 alloy and Al-Zn-Mg 7N01 alloy are selected, the joint interfaces of the alloys at different bonding temperatures are observed with TEM and the formed phases in the joint interfaces are identified by electron ray diffraction. Then, by comparing the TEM observation results with the bonding strength as well as the tensile fracture, the influences of the formed phase on the bondability are investigated. As the results of the study, the followings are clarified. The oxides formed at the joint interfaces alter from uncrystallized oxide films to crystallized grains with the increasing of the bonding temperature. The uncrystallized oxide films disappear at lower bonding temperature as the Mg content is higher. 7 refs., 16 figs., 2 tabs.

  19. A molecular dynamics study of bond exchange reactions in covalent adaptable networks.

    Science.gov (United States)

    Yang, Hua; Yu, Kai; Mu, Xiaoming; Shi, Xinghua; Wei, Yujie; Guo, Yafang; Qi, H Jerry

    2015-08-21

    Covalent adaptable networks are polymers that can alter the arrangement of network connections by bond exchange reactions where an active unit attaches to an existing bond then kicks off its pre-existing peer to form a new bond. When the polymer is stretched, bond exchange reactions lead to stress relaxation and plastic deformation, or the so-called reforming. In addition, two pieces of polymers can be rejoined together without introducing additional monomers or chemicals on the interface, enabling welding and reprocessing. Although covalent adaptable networks have been researched extensively in the past, knowledge about the macromolecular level network alternations is limited. In this study, molecular dynamics simulations are used to investigate the macromolecular details of bond exchange reactions in a recently reported epoxy system. An algorithm for bond exchange reactions is first developed and applied to study a crosslinking network formed by epoxy resin DGEBA with the crosslinking agent tricarballylic acid. The trace of the active units is tracked to show the migration of these units within the network. Network properties, such as the distance between two neighboring crosslink sites, the chain angle, and the initial modulus, are examined after each iteration of the bond exchange reactions to provide detailed information about how material behaviors and macromolecular structure evolve. Stress relaxation simulations are also conducted. It is found that even though bond exchange reactions change the macroscopic shape of the network, microscopic network characteristic features, such as the distance between two neighboring crosslink sites and the chain angle, relax back to the unstretched isotropic state. Comparison with a recent scaling theory also shows good agreement.

  20. Why are Hydrogen Bonds Directional?

    Indian Academy of Sciences (India)

    ABHISHEK SHAHI; ELANGANNAN ARUNAN

    2016-10-01

    The recent IUPAC recommendation on the definition of hydrogen bonding points out that directionality is a defining characteristic of a hydrogen bond and the angle ∠X-H-Y is generally linear or 180◦. It also suggests that the X-H· · ·Y angle be greater than 110◦ for an interaction to be characterized as a hydrogenbond but does not provide any rationale for the same. This article reports a rationale for limiting the angle, based on the electron density topology using the quantum theory of atoms in molecules. Electron density topology for common hydrogen bond donors HF, HCl, HBr, HNC, HCN and HCCH are reported in this work. These calculations lead to an interesting observation that the atomic basins of H atom in all these donor molecules are limited justifying the restriction of hydrogen bond angle. Moreover, similar analysis on some hydrogen bonded complexes confirms that beyond this angle the acceptor atom Y starts interacting with the atomic basin on X. However, conclusions based on bond lengths and angles have to be treated with care and as the IUPAC recommendation points out that independent ‘evidence for bond formation’ in every case is important.

  1. Understanding Bonds - Denmark

    DEFF Research Database (Denmark)

    Rimmer, Nina Røhr

    2016-01-01

    a specified rate of interest during the life of the bond and to repay the face value of the bond (the principal) when it “matures,” or comes due. Among the types of bonds you can choose from are: Government securities, municipal bonds, corporate bonds, mortgage and asset-backed securities, federal agency...

  2. Roll bonding of strained aluminium

    DEFF Research Database (Denmark)

    Staun, Jakob M.

    2003-01-01

    This report investigates roll bonding of pre-strained (å ~ 4) aluminium sheets to produce high strain material from high purity aluminium (99.996%) and commercial pure aluminium (99.6%). The degree of bonding is investigated by optical microscopy and ultrasonic scanning. Under the right...... of the cross rolled volume fraction is found. To further asses this effect, and the anisotropy, it is necessary to acquire knowledge about both texture and microstructure, e.g. by TEM. Roll bonding of pre-strained aluminium is found to be a possible alternative to ARB in the quest for ultra-fine grained...

  3. Roll bonding of strained aluminium

    DEFF Research Database (Denmark)

    Staun, Jakob M.

    2003-01-01

    This report investigates roll bonding of pre-strained (å ~ 4) aluminium sheets to produce high strain material from high purity aluminium (99.996%) and commercial pure aluminium (99.6%). The degree of bonding is investigated by optical microscopy and ultrasonic scanning. Under the right...... of the cross rolled volume fraction is found. To further asses this effect, and the anisotropy, it is necessary to acquire knowledge about both texture and microstructure, e.g. by TEM. Roll bonding of pre-strained aluminium is found to be a possible alternative to ARB in the quest for ultra-fine grained...

  4. Distances from Planetary Nebulae

    CERN Document Server

    Ciardullo, R

    2003-01-01

    The [O III] 5007 planetary nebula luminosity function (PNLF) occupies an important place on the extragalactic distance ladder. Since it is the only method that is applicable to all the large galaxies of the Local Supercluster, it is uniquely useful for cross-checking results and linking the Population I and Population II distance scales. We review the physics underlying the method, demonstrate its precision, and illustrate its value by comparing its distances to distances obtained from Cepheids and the Surface Brightness Fluctuation (SBF) method. We use the Cepheid and PNLF distances to 13 galaxies to show that the metallicity dependence of the PNLF cutoff is in excellent agreement with that predicted from theory, and that no additional systematic corrections are needed for either method. However, when we compare the Cepheid-calibrated PNLF distance scale with the Cepheid-calibrated SBF distance scale, we find a significant offset: although the relative distances of both methods are in excellent agreement, th...

  5. Four-Junction Solar Cell with 40% Target Efficiency Fabricated by Wafer Bonding and Layer Transfer: Final Technical Report, 1 January 2005 - 31 December 2007

    Energy Technology Data Exchange (ETDEWEB)

    Atwater, H. A.

    2008-11-01

    We realized high-quality InGaP/GaAs 2-junction top cells on Ge/Si, InGaAs/InP bottom cells, direct-bond series interconnection of tandem cells, and modeling of bonded 3- and 4-junction device performance.

  6. Mechanically enforced bond dissociation reports synergistic influence of Mn2+ and Mg2+ on the interaction between integrin α7β1 and invasin

    DEFF Research Database (Denmark)

    Ligezowska, Agnieszka; Boye, Kristian; Eble, Johannes A.

    2011-01-01

    Integrins require the divalent ions magnesium and manganese for ligand recognition. Here we mechanically enforced bond dissociation to explore the influence of these ions on the mechanical strength of the specific bond between α7β1 integrin and its pathologically relevant ligand invasin. Upon add...

  7. A highly efficient 3D micromixer using soft PDMS bonding

    Science.gov (United States)

    Cha, Junghun; Kim, Jinseok; Ryu, Suk-Kyu; Park, Jungyul; Jeong, Yongwon; Park, Sewan; Park, Sukho; Kim, Hyeon Cheol; Chun, Kukjin

    2006-09-01

    This paper presents a novel highly efficient passive micromixer that employs diffusion for micromixing. Since conventional fabrication methods cannot form precise aligned microchannels, the realization of a complex 3D micromixer has been difficult. Here, we report a novel micromixer, named a chessboard mixer. In addition, a new polydimethylsiloxane (PDMS) bonding method was developed to produce the proposed mixer. The new PDMS bonding technique requires PDMS-to-PDMS bonding and the moldable flexibility of partially cured PDMS to form the structure. Accordingly, a two-step curing process was used to solve these problems. Adhesion control was also considered when forming the PDMS membranes. Complex 3D microchannels in the micromixer were aligned within 1 m using the proposed new bonding method. The presented micromixer could increase the mixing effect by expanding interfaces between mixing fluids. Thus, this mixer makes it possible to mix within a shorter distance than other pre-existing micromixers do. A simulation using computational fluid dynamics (CFD)-ACE software showed a highly efficient performance, and an experiment involving the mixing of NaOH and phenolphthalein confirmed the rapid mixing performance (<1400 µm).

  8. A generalized evidence distance

    Institute of Scientific and Technical Information of China (English)

    Hongming Mo; Xi Lu; Yong Deng

    2016-01-01

    How to efficiently measure the distance between two basic probability assignments (BPAs) is an open issue. In this paper, a new method to measure the distance between two BPAs is proposed, based on two existing measures of evidence distance. The new proposed method is comprehen-sive and generalized. Numerical examples are used to ilus-trate the effectiveness of the proposed method.

  9. Distance Education: Improved Data on Program Costs and Guidelines on Quality Assessments Needed To Inform Federal Policy. Report to Congressional Requesters.

    Science.gov (United States)

    Ashby, Cornelia M.

    Distance education--that is, offering courses by Internet, video, or other forms outside the classroom--has changed considerably in recent years and is a growing force in postsecondary education. More than a decade ago, concerns about fraud and abuse by some correspondence schools led to federal restrictions on, among other things, the percentage…

  10. Distance Education at the University of the West Indies. Report of an Appraisal Carried Out on Behalf of the Commonwealth of Learning.

    Science.gov (United States)

    Renwick, William; And Others

    An appraisal was made of the policy implications of a commitment by the University of the West Indies (UWI) to develop distance education as an integral feature of its teaching responsibilities. Information was gathered through interviews with 163 educators and administrators at the 3 campuses of the University of the West Indies, its 8 member…

  11. Cross Shear Roll Bonding

    DEFF Research Database (Denmark)

    Bay, Niels; Bjerregaard, Henrik; Petersen, Søren. B;

    1994-01-01

    The present paper describes an investigation of roll bonding an AlZn alloy to mild steel. Application of cross shear roll bonding, where the two equal sized rolls run with different peripheral speed, is shown to give better bond strength than conventional roll bonding. Improvements of up to 20......-23% in bond strength are found and full bond strength is obtained at a reduction of 50% whereas 65% is required in case of conventional roll bonding. Pseudo cross shear roll bonding, where the cross shear effect is obtained by running two equal sized rolls with different speed, gives the same results....

  12. Halogen bonding origin properties and applications

    Energy Technology Data Exchange (ETDEWEB)

    Hobza, Pavel [Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 166 10 Prague (Czech Republic); Regional Center of Advanced Technologies and Materials, Department of Physical Chemistry, Palacky University, 77146 Olomouc (Czech Republic)

    2015-12-31

    σ-hole bonding represents an unusual and novel type of noncovalent interactions in which atom with σ- hole interacts with Lewis base such as an electronegative atom (oxygen, nitrogen, …) or aromatic systems. This bonding is of electrostatic nature since the σ-hole bears a positive charge. Dispersion energy forms equally important energy term what is due to the fact that two heavy atoms (e.g. halogen and oxygen) having high polarizability lie close together (the respective distance is typically shorter than the sum of van der Waals radii). Among different types of σ-hole bondings the halogen bonding is by far the most known but chalcogen and pnictogen bondings are important as well.

  13. Development of test acceptance standards for qualification of the glass-bonded zeolite waste form. Interim annual report, October 1995--September 1996

    Energy Technology Data Exchange (ETDEWEB)

    Simpson, L.J.; Wronkiewicz, D.J.; Fortner, J.A.

    1997-09-01

    Glass-bonded zeolite is being developed at Argonne National Laboratory in the Electrometallurgical Treatment Program as a potential ceramic waste form for the disposition of radionuclides associated with the US Department of Energy`s (DOE`s) spent nuclear fuel conditioning activities. The utility of standard durability tests [e.g. Materials Characterization Center Test No. 1 (MCC-1), Product Consistency Test (PCT), and Vapor Hydration Test (VHT)] are being evaluated as an initial step in developing test methods that can be used in the process of qualifying this material for acceptance into the Civilian Radioactive Waste Management System. A broad range of potential repository conditions are being evaluated to determine the bounding parameters appropriate for the corrosion testing of the ceramic waste form, and its behavior under accelerated testing conditions. In this report we provide specific characterization information and discuss how the durability test results are affected by changes in pH, leachant composition, and sample surface area to leachant volume ratios. We investigate the release mechanisms and other physical and chemical parameters that are important for establishing acceptance parameters, including the development of appropriate test methodologies required to measure product consistency.

  14. Tourists consuming distance

    DEFF Research Database (Denmark)

    Larsen, Gunvor Riber

    The environmental impact of tourism mobility is linked to the distances travelled in order to reach a holiday destination, and with tourists travelling more and further than previously, an understanding of how the tourists view the distance they travel across becomes relevant. Based on interviews...... contribute to an understanding of how it is possible to change tourism travel behaviour towards becoming more sustainable. How tourists 'consume distance' is discussed, from the practical level of actually driving the car or sitting in the air plane, to the symbolic consumption of distance that occurs when...... travelling on holiday becomes part of a lifestyle and a social positioning game. Further, different types of tourist distance consumers are identified, ranging from the reluctant to the deliberate and nonchalant distance consumers, who display very differing attitudes towards the distance they all travel...

  15. Interface Simulation Distances

    Directory of Open Access Journals (Sweden)

    Pavol Černý

    2012-10-01

    Full Text Available The classical (boolean notion of refinement for behavioral interfaces of system components is the alternating refinement preorder. In this paper, we define a distance for interfaces, called interface simulation distance. It makes the alternating refinement preorder quantitative by, intuitively, tolerating errors (while counting them in the alternating simulation game. We show that the interface simulation distance satisfies the triangle inequality, that the distance between two interfaces does not increase under parallel composition with a third interface, and that the distance between two interfaces can be bounded from above and below by distances between abstractions of the two interfaces. We illustrate the framework, and the properties of the distances under composition of interfaces, with two case studies.

  16. Tensile Characteristics of Bond of Stainless Steel Overlay Weld after Absorption of Hydrogen : Study on a Stainless Steel Overlay Welding Process for Superior Resistance to Disbonding (Report 4)

    OpenAIRE

    Akiyoshi, FUJI; Etsuo, KUDO; Tomoyuki, TAKAHASHI; The Japan Steel Works, Ltd., Muroran Plant

    1987-01-01

    The tensile characteristics of the bond of the disbanding-resistant overlay weld after absorption of hydrogen were studied and compared with those of the conventional overlay weld. It was found that the tensile strength of the bond of the conventional overlay weld was lower than that of the disbanding-resistant overlay weld. This is due to existence of the coarse planar grains in first layer overlay weld metal adjacent to the bond. The coarse planar grains strongly reduce the resistance to hy...

  17. Wire bonding in microelectronics

    CERN Document Server

    Harman, George G

    2010-01-01

    Wire Bonding in Microelectronics, Third Edition, has been thoroughly revised to help you meet the challenges of today's small-scale and fine-pitch microelectronics. This authoritative guide covers every aspect of designing, manufacturing, and evaluating wire bonds engineered with cutting-edge techniques. In addition to gaining a full grasp of bonding technology, you'll learn how to create reliable bonds at exceedingly high yields, test wire bonds, solve common bonding problems, implement molecular cleaning methods, and much more. Coverage includes: Ultrasonic bonding systems and technologies, including high-frequency systems Bonding wire metallurgy and characteristics, including copper wire Wire bond testing Gold-aluminum intermetallic compounds and other interface reactions Gold and nickel-based bond pad plating materials and problems Cleaning to improve bondability and reliability Mechanical problems in wire bonding High-yield, fine-pitch, specialized-looping, soft-substrate, and extreme-temperature wire bo...

  18. Brotherly Bonds

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Chinese Premier Wen Jiabao just completed his official visit to Pakistan at the invitation of Prime Minister Yousuf Raza Gilani. Masood Khan, Pakistan’s Ambassador to China, talked on December 10-prior to Wen’s visit-with Beijing Review reporter Yu Yan about the significance of Wen’s visit, the foundations of the China-Pakistan partnership, Pakistan’s relations with India and Pakistan’s domestic situations.

  19. Parental Bonding and Mental Health in Adolescence.

    Science.gov (United States)

    Canetti, Laura; Bachar, Eytan; Galili-Weisstub, Esti; De-Nour, Atara Kaplan; Shalev, Arieh Y.

    1997-01-01

    Examines the relationship between parental bonding and mental health in healthy adolescents. Results, based on 847 Israeli high school students, show that those who reported high care and low control (optimal bonding) reported less distress, better general well-being, and better social support than did all other groups. (RJM)

  20. Comparison of hearing results following the use of NiTiBOND versus Nitinol prostheses in stapes surgery: a retrospective controlled study reporting short-term postoperative results.

    Science.gov (United States)

    Révész, Péter; Szanyi, István; Ráth, Gábor; Bocskai, Tímea; Lujber, László; Piski, Zalán; Karosi, Tamás; Gerlinger, Imre

    2016-05-01

    The aim of this retrospective study was to compare the 3-month postoperative hearing results following laser stapedotomy with the use of NiTiBOND versus Nitinol prostheses (31 and 39 patients, respectively). The operations were performed between September 2012 and September 2014, and between March 2006 and December 2012 regarding NiTiBOND and Nitinol, respectively. Twenty of the consecutive 31 patients were female and 11 were male for NiTiBOND, while 11 were male and 28 were female for Nitinol. The mean age was 43.8 years (range 22-61) and 46.9 years (range 28-83) for NiTiBOND and Nitinol, respectively. No significant cochlear trauma was documented postoperatively. The mean air-bone gap (ABG) for the frequencies 0.5, 1, 2 and 3 kHz at the 3-month postoperative follow-up was 7.6 dB (SD 4.7), and 9.3 dB (SD 4.1) for NiTiBOND and Nitinol, respectively. The differences between the mean pre- (p = 0.179), and postoperative (p = 0.059) ABG of the two groups were not significant. ABG closure within 10 dB was achieved in 77.4 and 59 % for NiTiBOND and Nitinol, respectively, the difference was not significant (p = 0.10). Two cases of delayed facial paralysis occurred, 1 with Nitinol and 1 with the NiTiBOND. All patients attained an ABG <20 dB following surgery. Laser stapedotomy with the application of either heat-memory piston prosthesis allowed an easy and minimally invasive approach with excellent short-term hearing results when the NiTiBOND prosthesis was applied. Laser application allowed manipulation in a bloodless environment and avoided manual crimping of the incus.

  1. Keeping Your Distance

    Directory of Open Access Journals (Sweden)

    Glen Gatin

    2013-06-01

    Full Text Available This analysis began with inquiries into the substantive area of distance education using the classic grounded theory method. Analysis revealed a pattern of problemsolving behavior, from which the theory Keeping Your Distance emerged. The theory is an integrated set of concepts referring to the conscious and unconscious strategiesthat people use to regulate distance, physical and representative, in their everyday lives. Strategies are used to control physical, emotional, and psychological realities and to conserve personal energy in interactions with individuals and/or institutions.For all social interactions, people use a personalized algorithm of engagement that mitigates conditions and consequences and preserves optimal distance. Keeping Your Distance provides a theoretical starting point for considerations of the changing notions of distance. In part, these changes have been brought about bydevelopments in the fields of Information and Communication Technology (ICT and online social networking.

  2. Numerical distance protection

    CERN Document Server

    Ziegler, Gerhard

    2011-01-01

    Distance protection provides the basis for network protection in transmission systems and meshed distribution systems. This book covers the fundamentals of distance protection and the special features of numerical technology. The emphasis is placed on the application of numerical distance relays in distribution and transmission systems.This book is aimed at students and engineers who wish to familiarise themselves with the subject of power system protection, as well as the experienced user, entering the area of numerical distance protection. Furthermore it serves as a reference guide for s

  3. Learner characteristics involved in distance learning

    Energy Technology Data Exchange (ETDEWEB)

    Cernicek, A.T.; Hahn, H.A.

    1991-01-01

    Distance learning represents a strategy for leveraging resources to solve educational and training needs. Although many distance learning programs have been developed, lessons learned regarding differences between distance learning and traditional education with respect to learner characteristics have not been well documented. Therefore, we conducted a survey of 20 distance learning professionals. The questionnaire was distributed to experts attending the second Distance Learning Conference sponsored by Los Alamos National Laboratory. This survey not only acquired demographic information from each of the respondents but also identified important distance learning student characteristics. Significant distance learner characteristics, which were revealed statistically and which influence the effectiveness of distance learning, include the following: reading level, student autonomy, and self-motivation. Distance learning cannot become a more useful and effective method of instruction without identifying and recognizing learner characteristics. It will be important to consider these characteristics when designing all distance learning courses. This paper will report specific survey findings and their implications for developing distance learning courses. 9 refs., 6 tabs.

  4. Normalized information distance

    NARCIS (Netherlands)

    Vitányi, P.M.B.; Balbach, F.J.; Cilibrasi, R.L.; Li, M.; Emmert-Streib, F.; Dehmer, M.

    2009-01-01

    The normalized information distance is a universal distance measure for objects of all kinds. It is based on Kolmogorov complexity and thus uncomputable, but there are ways to utilize it. First, compression algorithms can be used to approximate the Kolmogorov complexity if the objects have a string

  5. Normalized information distance

    NARCIS (Netherlands)

    Vitányi, P.M.B.; Balbach, F.J.; Cilibrasi, R.L.; Li, M.

    2008-01-01

    The normalized information distance is a universal distance measure for objects of all kinds. It is based on Kolmogorov complexity and thus uncomputable, but there are ways to utilize it. First, compression algorithms can be used to approximate the Kolmogorov complexity if the objects have a string

  6. Incremental Distance Transforms (IDT)

    NARCIS (Netherlands)

    Schouten, Theo E.; van den Broek, Egon; Erçil, A.; Çetin, M.; Boyer, K.; Lee, S.-W.

    2010-01-01

    A new generic scheme for incremental implementations of distance transforms (DT) is presented: Incremental Distance Transforms (IDT). This scheme is applied on the cityblock, Chamfer, and three recent exact Euclidean DT (E2DT). A benchmark shows that for all five DT, the incremental implementation r

  7. ORDERED WEIGHTED DISTANCE MEASURE

    Institute of Scientific and Technical Information of China (English)

    Zeshui XU; Jian CHEN

    2008-01-01

    The aim of this paper is to develop an ordered weighted distance (OWD) measure, which is thegeneralization of some widely used distance measures, including the normalized Hamming distance, the normalized Euclidean distance, the normalized geometric distance, the max distance, the median distance and the min distance, etc. Moreover, the ordered weighted averaging operator, the generalized ordered weighted aggregation operator, the ordered weighted geometric operator, the averaging operator, the geometric mean operator, the ordered weighted square root operator, the square root operator, the max operator, the median operator and the min operator axe also the special cases of the OWD measure. Some methods depending on the input arguments are given to determine the weights associated with the OWD measure. The prominent characteristic of the OWD measure is that it can relieve (or intensify) the influence of unduly large or unduly small deviations on the aggregation results by assigning them low (or high) weights. This desirable characteristic makes the OWD measure very suitable to be used in many actual fields, including group decision making, medical diagnosis, data mining, and pattern recognition, etc. Finally, based on the OWD measure, we develop a group decision making approach, and illustrate it with a numerical example.

  8. Duty and Distance

    NARCIS (Netherlands)

    C. Binder (C.); C. Heilmann (Conrad)

    2017-01-01

    markdownabstractEver since the publication of Peter Singer’s article ‘‘Famine, Affluence, and Morality’’ has the question of whether the (geographical) distance to people in need affects our moral duties towards them been a hotly debated issue. Does geographical distance affect our moral duties?

  9. Biomechanics of Distance Running.

    Science.gov (United States)

    Cavanagh, Peter R., Ed.

    Contributions from researchers in the field of running mechanics are included in the 13 chapters of this book. The following topics are covered: (1) "The Mechanics of Distance Running: A Historical Perspective" (Peter Cavanagh); (2) "Stride Length in Distance Running: Velocity, Body Dimensions, and Added Mass Effects" (Peter Cavanagh, Rodger…

  10. Distance Learning Environment Demonstration.

    Science.gov (United States)

    1996-11-01

    The Distance Learning Environment Demonstration (DLED) was a comparative study of distributed multimedia computer-based training using low cost high...measurement. The DLED project provides baseline research in the effective use of distance learning and multimedia communications over a wide area ATM/SONET

  11. Duty and Distance

    NARCIS (Netherlands)

    C. Binder (C.); C. Heilmann (Conrad)

    2017-01-01

    markdownabstractEver since the publication of Peter Singer’s article ‘‘Famine, Affluence, and Morality’’ has the question of whether the (geographical) distance to people in need affects our moral duties towards them been a hotly debated issue. Does geographical distance affect our moral

  12. Competition between Hydrogen Bonds and Coordination Bonds Steered by the Surface Molecular Coverage.

    Science.gov (United States)

    Cai, Liangliang; Sun, Qiang; Bao, Meiling; Ma, Honghong; Yuan, Chunxue; Xu, Wei

    2017-04-25

    In addition to the choices of metal atoms/molecular linkers and surfaces, several crucial parameters, including surface temperature, molecular stoichiometric ratio, electrical stimulation, concentration, and solvent effect for liquid/solid interfaces, have been demonstrated to play key roles in the formation of on-surface self-assembled supramolecular architectures. Moreover, self-assembled structural transformations frequently occur in response to a delicate control over those parameters, which, in most cases, involve either conversions from relatively weak interactions to stronger ones (e.g., hydrogen bonds to coordination bonds) or transformations between the comparable interactions (e.g., different coordination binding modes or hydrogen bonding configurations). However, intermolecular bond conversions from relatively strong coordination bonds to weak hydrogen bonds were rarely reported. Moreover, to our knowledge, a reversible conversion between hydrogen bonds and coordination bonds has not been demonstrated before. Herein, we have demonstrated a facile strategy for the regulation of stepwise intermolecular bond conversions from the metal-organic coordination bond (Cu-N) to the weak hydrogen bond (CH···N) by increasing the surface molecular coverage. From the DFT calculations we quantify that the loss in intermolecular interaction energy is compensated by the increased molecular adsorption energy at higher molecular coverage. Moreover, we achieved a reversible conversion from the weak hydrogen bond to the coordination bond by decreasing the surface molecular coverage.

  13. Estimating distances from parallaxes

    Science.gov (United States)

    Astraatmadja, Tri L.; Bailer-Jones, Coryn

    2017-01-01

    In astrometric surveys such as Gaia and LSST, parallaxes will be measured for about a billion stars, but zero distances will be measured. Distances must be inferred from the parallaxes, and the common inference practice is by inverting the parallax. This, however, is only appropriate when there is no noise present. As noise will always be present and most stars in future surveys will have non-negligible fractional parallax uncertainties, we must treat distance estimation as an inference problem. The usage of prior assumptions become unavoidable. In this talk I will present a method on how to infer distances using Bayesian inference. Three minimalists, isotropic priors are used, as well an anisotropic prior derived from the observability of stars in a Milky Way model. The performance of these priors are investigated using a simulated Gaia-like catalogue. Recent results of distance estimation using the parallaxes of 2 million Gaia DR1 stars will also be discussed.

  14. Normalized Information Distance

    CERN Document Server

    Vitanyi, Paul M B; Cilibrasi, Rudi L; Li, Ming

    2008-01-01

    The normalized information distance is a universal distance measure for objects of all kinds. It is based on Kolmogorov complexity and thus uncomputable, but there are ways to utilize it. First, compression algorithms can be used to approximate the Kolmogorov complexity if the objects have a string representation. Second, for names and abstract concepts, page count statistics from the World Wide Web can be used. These practical realizations of the normalized information distance can then be applied to machine learning tasks, expecially clustering, to perform feature-free and parameter-free data mining. This chapter discusses the theoretical foundations of the normalized information distance and both practical realizations. It presents numerous examples of successful real-world applications based on these distance measures, ranging from bioinformatics to music clustering to machine translation.

  15. Changes in derived measures from six-minute walk distance following home-based exercise training in congestive heart failure: A preliminary report.

    Science.gov (United States)

    Babu, Abraham Samuel; Desai, Charmie V; Maiya, Arun G; Guddattu, Vasudeva; Padmakumar, Ramachandran

    2016-01-01

    The response of derived parameters from six-minute walk distance (6MWD), like 6MW work (6MWW), to exercise training and its correlation with quality of life (QoL) in congestive heart failure (CHF) is not known. A secondary analysis from a randomized controlled trial on 30 patients (23 males; mean age 57.7±10.4 years; mean ejection fraction 31±10%) with CHF in NYHA class I-IV who completed an eight-week home-based exercise training program found a significant improvement in 6MWW (p<0.05), with similar correlations between 6MWD and 6MWW with QoL. 6MWW does not appear to provide additional benefit to 6MWD in cardiac rehabilitation for CHF.

  16. Bonding and Anti-bonding Modes of Plasmon Coupling Effects in TiO2-Ag Core-shell Dimers

    Science.gov (United States)

    Li, Quanshui; Zhang, Zhili

    2016-01-01

    Bonding and anti-bonding modes of plasmon coupling effects are numerically investigated in TiO2-Ag core-shell nano dimers. First, splitting phenomena of the coupled anti-bonding modes are observed under the longitudinal polarization when the distance between the monomers decreases to a certain level. Second, one of the split resonance modes is identified to be formed by the dipole anti-bonding mode of the monomers from charge density distribution patterns. Those split modes have similar redshift behaviors as the coupled dipole bonding modes in the same situations. Furthermore, the intensities of those anti-bonding modes weaken with decreasing distance between the monomers, because of the interaction of the induced dipole moment in the monomers and the charge distribution variation on the facing surfaces of the gap by the coulomb attraction. Other split bands are the higher-order mode (octupole-like or triakontadipole-like), which do not have obvious peak-shift behavior, and the intensities have very little attenuation with decreasing distance. Finally, the coupling of the bonding and anti-bonding modes under the longitudinal polarization is symmetric (bonding).

  17. Estimating distances from parallaxes

    CERN Document Server

    Bailer-Jones, C A L

    2015-01-01

    Astrometric surveys such as Gaia and LSST will measure parallaxes for hundreds of millions of stars. Yet they will not measure a single distance. Rather, a distance must be estimated from a parallax. In this didactic article, I show that doing this is not trivial once the fractional parallax error is larger than about 20%, which will be the case for about 80% of stars in the Gaia catalogue. Estimating distances is an inference problem in which the use of prior assumptions is unavoidable. I investigate the properties and performance of various priors and examine their implications. A supposed uninformative uniform prior in distance is shown to give very poor distance estimates (large bias and variance). Any prior with a sharp cut-off at some distance has similar problems. The choice of prior depends on the information one has available - and is willing to use - concerning, for example, the survey and the Galaxy. I demonstrate that a simple prior which decreases asymptotically to zero at infinite distance has g...

  18. Redox-controlled hydrogen bonding: turning a superbase into a strong hydrogen-bond donor.

    Science.gov (United States)

    Wild, Ute; Neuhäuser, Christiane; Wiesner, Sven; Kaifer, Elisabeth; Wadepohl, Hubert; Himmel, Hans-Jörg

    2014-05-12

    Herein the synthesis, structures and properties of hydrogen-bonded aggregates involving redox-active guanidine superbases are reported. Reversible hydrogen bonding is switched on by oxidation of the hydrogen-donor unit, and leads to formation of aggregates in which the hydrogen-bond donor unit is sandwiched by two hydrogen-bond acceptor units. Further oxidation (of the acceptor units) leads again to deaggregation. Aggregate formation is associated with a distinct color change, and the electronic situation could be described as a frozen stage on the way to hydrogen transfer. A further increase in the basicity of the hydrogen-bond acceptor leads to deprotonation reactions.

  19. MOTIVATION FOR DISTANCE EDUCATION

    Directory of Open Access Journals (Sweden)

    R zvan TEF NESCU

    2009-10-01

    Full Text Available Beginning with the 1980’s the new information, communication and computer based technologies stimulated the development of the distance education. In Romania the universities adapted rapidly to this type of learning that became an important financing source for most of them. In this article we approach the causes of attraction for the distance education. For this purpose we use an investigation we did on a group of students at Distance Education including interviews regarding their reasons for choosing this type of learning.

  20. Self-Reported Emotional and Behavioral Problems, Family Functioning and Parental Bonding among Psychiatric Outpatient Adolescent Offspring of Croatian Male Veterans with Partial PTSD

    Science.gov (United States)

    Sarajlic Vukovic, Iris; Boricevic Maršanic, Vlatka; Aukst Margetic, Branka; Paradžik, Ljubica; Vidovic, Domagoj; Buljan Flander, Gordana

    2015-01-01

    Background: Posttraumatic stress disorder (PTSD) in male veterans has been linked with impaired family relationships and psychopathology in their children. Less is known about symptoms in children of veterans with partial PTSD. Objective: To compare mental health problems, family functioning and parent-child bonding among adolescent offspring of…

  1. Social Bond and Self-Reported Nonviolent and Violent Delinquency: A Study of Traditional Low Risk, At-Risk, and Adjudicated Male Chinese Adolescents

    Science.gov (United States)

    Chan, Heng Choon Oliver; Chui, Wing Hong

    2015-01-01

    Background: Little is known about the level of social bond elements and their effects on delinquency among nonadjudicated (traditional low and at-risk school-aged) and adjudicated Chinese male adolescents. Objective: Using a large adolescent sample (N = 1,177) from Hong Kong and Macau, this study aims to distinguish the level of social bond…

  2. Bonding with Your Baby

    Science.gov (United States)

    ... in infant massage in your area. Breastfeeding and bottle-feeding are both natural times for bonding. Infants respond ... activities include: participating together in labor and delivery feeding ( breast or bottle ); sometimes dad forms a special bond with baby ...

  3. EXAMINING POLICY GUIDELINES FOR DISTANCE EDUCATION IN ...

    African Journals Online (AJOL)

    User

    The study reports a case of distance education policy in the Kwame Nkrumah University of Sci- ... used to obtain information from 21 purposively selected key informants in the University. Policy ... practice must contain values among which is.

  4. Distance learning perspectives.

    Science.gov (United States)

    Pandza, Haris; Masic, Izet

    2013-01-01

    The development of modern technology and the Internet has enabled the explosive growth of distance learning. distance learning is a process that is increasingly present in the world. This is the field of education focused on educating students who are not physically present in the traditional classrooms or student's campus. described as a process where the source of information is separated from the students in space and time. If there are situations that require the physical presence of students, such as when a student is required to physically attend the exam, this is called a hybrid form of distance learning. This technology is increasingly used worldwide. The Internet has become the main communication channel for the development of distance learning.

  5. Learning Pullback HMM Distances.

    Science.gov (United States)

    Cuzzolin, Fabio; Sapienza, Michael

    2014-07-01

    Recent work in action recognition has exposed the limitations of methods which directly classify local features extracted from spatio-temporal video volumes. In opposition, encoding the actions' dynamics via generative dynamical models has a number of attractive features: however, using all-purpose distances for their classification does not necessarily deliver good results. We propose a general framework for learning distance functions for generative dynamical models, given a training set of labelled videos. The optimal distance function is selected among a family of pullback ones, induced by a parametrised automorphism of the space of models. We focus here on hidden Markov models and their model space, and design an appropriate automorphism there. Experimental results are presented which show how pullback learning greatly improves action recognition performances with respect to base distances.

  6. Keeping U.S. Bonds in Hand

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    U.S. bonds still comprise a major share of Chinese foreign reserves People are becoming increasingly uneasy about reports saying China is reducing its holdings of U.S.bonds. Currently, China is the sec-ond largest holder of U.S.

  7. Acrylic mechanical bond tests

    Energy Technology Data Exchange (ETDEWEB)

    Wouters, J.M.; Doe, P.J.

    1991-02-01

    The tensile strength of bonded acrylic is tested as a function of bond joint thickness. 0.125 in. thick bond joints were found to posses the maximum strength while the acceptable range of joints varied from 0.063 in. to almost 0.25 in. Such joints are used in the Sudbury Neutrino Observatory.

  8. Effect of solvent on proton location and dynamic behavior in short intramolecular hydrogen bonds studied by molecular dynamics simulations and NMR experiments

    Science.gov (United States)

    Mori, Yukie; Masuda, Yuichi

    2015-09-01

    Hydrogen phthalate anion has a short strong O-H-O hydrogen bond (H-bond). According to previous experimental studies, the H-bond is asymmetric and two tautomers are interconverted in aqueous solutions. In the present study, the effects of polar solvents on the H-bond in a zwitterionic hydrogen phthalate derivative 1 were investigated by quantum mechanics/molecular mechanics molecular dynamics (MD) simulations. The analyses of the trajectories for the methanol solution showed that the H-bonding proton tends to be located closer to the carboxylate group that forms fewer intermolecular H-bonds, than to the other carboxylate group and that the intramolecular proton transfer in 1 is triggered by the breakage and/or formation of an intermolecular H-bond. The enol form of dibenzoylmethane (2) also has a short H-bond, and the OH bond is reported to be rather long (>1.1 Å) in the crystal. In the present study, the effects of the solvent on the H-bond in 2 were investigated by molecular orbital (MO) calculations, MD simulations and nuclear magnetic resonance (NMR) spectroscopy. Density functional theory (DFT) calculations for 2 in vacuum indicated that the barrier height for the intramolecular proton transfer is almost the same as the zero-point energy of the vibrational ground state, resulting in broad distribution of the proton density along the H-bond, owing to the nuclear quantum effect. The OH distances were determined in CCl4, acetonitrile, and dimethylsulfoxide solutions from the magnetic dipolar interactions between the 17O and 1H nuclei monitoring the nuclear magnetic relaxation times of 1H. The experimental results indicated that the H-bond geometry of 2 is influenced by the interactions with dimethylsulfoxide, suggesting the formation of a bifurcated H-bond, which was supported by the DFT calculations. The MD simulations for the methanol solution of 2 showed that the asymmetry of the OH distance is correlated with the asymmetry in the electrostatic field of the

  9. Chemical bond fundamental aspects of chemical bonding

    CERN Document Server

    Frenking, Gernot

    2014-01-01

    This is the perfect complement to ""Chemical Bonding - Across the Periodic Table"" by the same editors, who are two of the top scientists working on this topic, each with extensive experience and important connections within the community. The resulting book is a unique overview of the different approaches used for describing a chemical bond, including molecular-orbital based, valence-bond based, ELF, AIM and density-functional based methods. It takes into account the many developments that have taken place in the field over the past few decades due to the rapid advances in quantum chemica

  10. Development of a novel plasma scanning technique for high-quality anodic bonding

    Science.gov (United States)

    Wu, Jim-Wei; Yang, Chii-Rong; Huang, Che-Yi

    2016-04-01

    Anodic bonding is a type of nonintermediate wafer bonding technique that has been widely used in microelectromechanical systems for sealing devices or assembling microstructures. However, the conventional anodic bonding method has a limitation. The specimens being bonded must typically be in contact with the anode and cathode electrodes during the bonding process. In general, the initial bonding position corresponds to the contact area of the two electrodes; subsequently, the bonded region gradually extends to cover the entire target region. Nevertheless, the traditional diffuse bonding method provides limited bonding efficiency in industrial applications. Therefore, this paper proposes a novel plasma bonding technique for 2D scanning anodic bonding. In this technique, the plasma is positioned to simultaneously heat and bond specimens. We conducted an experiment that entailed bonding 4-inch silicon/glass wafers by using N2 plasma. The results revealed that an almost bubble-free bonded interface and an average bonding strength exceeding 37 MPa were achieved for a bonding time of 15 min 53 s, bonding voltage of 2 kV, noncontact distance (between the cathode electrode and the bonding specimens) of 3 mm, variable raster scan path, scan speed of 3 mm s-1, and continuous scan steps of 2.5 mm in the x- and y-axes. A comprehensive series of experiments were performed to validate the bonding performance of the proposed technique.

  11. Halogen Bonding in (Z-2-Iodocinnamaldehyde

    Directory of Open Access Journals (Sweden)

    Miriam Rossi

    2013-07-01

    Full Text Available Based on the bulkiness of the iodine atom, a non-planar conformation was expected for the title compound. Instead, its molecular structure is planar, as experimentally determined using single crystal X-ray diffraction, and confirmed theoretically by DFT calculations on the single molecule and the halogen pair paired molecules, therefore ruling out crystal packing forces as a principal factor leading to planarity. Indeed, planarity is ascribed to the carbonyl double bond, as when this bond is saturated on forming the related alcohol derivative, the molecule loses planarity. The X-ray molecular structure shows an intermolecular separation between the iodine and the oxygen of the carbonyl shorter than the corresponding van der Waals distance suggesting a weak halogen bond interaction. DFT minimization of this 2-molecule arrangement shows the iodine--oxygen distance much shorter than that observed in the crystal interaction and confirming its stronger halogen bond nature. A trend between increasing I•••O(carbonyl separation and decreasing C-I•••O(carbonyl angle is demonstrated, further confirming the existence of a halogen bond.

  12. Hydrogen bonds in concreto and in computro: the sequel

    Science.gov (United States)

    Stouten, Pieter F. W.; Van Eijck, Bouke P.; Kroon, Jan

    1991-02-01

    In the framework of our comparative research concerning hydrogen bonding in the crystalline and liquid phases we have carried out molecular dynamics (MD) simulations of liquid methanol. Six different rigid three site models are compared. Five of them had been reported in the literature and one (OM2) we developed by a fit to the experimental molar volume, heat of vaporization and neutron weighted radial distribution function. In general the agreement with experiment is satisfactory for the different models. None of the models has an explicit hydrogen bond potential, but five of the six models show a degree of hydrogen bonding comparable to experiments on liquid methanol. The analysis of the simulation hydrogen bonds indicates that there is a distinct preference of the O⋯O axis to lie in the acceptor lone pairs plane, but hardly any for the lone pair directions. Ab initio calculations and crystal structure statistics of OH⋯O hydrogen bonds agree with this observation. The O⋯O hydrogen bond length distributions are similar for most models. The crystal structures show a sharper O⋯O distribution. Explicit introduction of harmonic motion with a quite realistic root mean square amplitude of 0.08 Å to the thermally averaged crystal distribution results in a distribution comparable to OM2 although the maximum of the former is found at shorter distance. On the basis of the analysis of the static properties of all models we conclude that our OM2, Jorgenson's OPLS and Haughney, Ferrario and McDonald's HFM1 models are good candidates for simulations of liquid methanol under isothermal, isochoric conditions. Partly flexible and completely rigid OM2 are simulated at constant pressure and with fixed volume. The flexible simulations give essentially the same (correct) results under both conditions, which is not surprising because the flexible form was fitted under both conditions. Rigid OM2 has a similar potential energy but larger pressure in the

  13. Poisson analysis of streptococcal bond strengthening on stainless steel with and without a salivary conditioning film

    NARCIS (Netherlands)

    Mei, Li; van der Mei, Henny C.; Ren, Yijin; Norde, Willem; Busscher, Henk J.

    2009-01-01

    Poisson analysis of retract force-distance curves in atomic force microscopy (AFM) has yielded a new dimension to the decoupling of individual bond forces into a hydrogen bonding and nonspecific force component. Accordingly, bacterial adhesion forces have been decoupled into a hydrogen bonding and

  14. Poisson analysis of streptococcal bond strengthening on stainless steel with and without salivary conditioning film

    NARCIS (Netherlands)

    Mei, Li; Mei, van der H.C.; Ren, Y.; Norde, W.; Busscher, H.J.

    2009-01-01

    Poisson analysis of retract force-distance curves in atomic force microscopy (AFM) has yielded a new dimension to the decoupling of individual bond forces into a hydrogen bonding and nonspecific force component. Accordingly, bacterial adhesion forces have been decoupled into a hydrogen bonding and

  15. Double-bridge bonding of aluminium and hydrogen in the crystal structure of gamma-AlH3.

    Science.gov (United States)

    Yartys, Volodymyr A; Denys, Roman V; Maehlen, Jan Petter; Frommen, Christoph; Fichtner, Maximilian; Bulychev, Boris M; Emerich, Hermann

    2007-02-19

    Aluminum trihydride (alane) is one of the most promising among the prospective solid hydrogen-storage materials, with a high gravimetric and volumetric density of hydrogen. In the present work, the alane, crystallizing in the gamma-AlH3 polymorphic modification, was synthesized and then structurally characterized by means of synchrotron X-ray powder diffraction. This study revealed that gamma-AlH3 crystallizes with an orthorhombic unit cell (space group Pnnm, a = 5.3806(1) A, b = 7.3555(2) A, c = 5.77509(5) A). The crystal structure of gamma-AlH3 contains two types of AlH6 octahedra as the building blocks. The Al-H bond distances in the structure vary in the range of 1.66-1.79 A. A prominent feature of the crystal structure is the formation of the bifurcated double-bridge bonds, Al-2H-Al, in addition to the normal bridge bonds, Al-H-Al. This former feature has not been previously reported for Al-containing hydrides so far. The geometry of the double-bridge bond shows formation of short Al-Al (2.606 A) and Al-H (1.68-1.70 A) bonds compared to the Al-Al distances in Al metal (2.86 A) and Al-H distances for Al atoms involved in the formation of normal bridge bonds (1.769-1.784 A). The crystal structure of gamma-AlH3 contains large cavities between the AlH6 octahedra. As a consequence, the density is 11% less than for alpha-AlH3.

  16. Presence at a distance.

    Science.gov (United States)

    Haddouk, Lise

    2015-01-01

    Nowadays in the context of the cyberculture, computer-mediated inter-subjective relationships are part of our everyday lives, in both the professional and personal spheres, and for all age groups. In the clinical field, many applications have been developed to facilitate the exchange of informations and mediate the relationship between patient and therapist. In psychology, more or less immersive technologies are used, to encourage the feeling of presence among the users, and to trigger certain psychological processes. In our research, we have explored the remote clinical interview through videoconferencing, with the development and utilisation of the iPSY platform, totally focused on this objective. In this context, we have considered the notion of intersubjectivity, despite the physical absence. This research is leading us today to envision the notions of distance and presence, and possibly to redefine them. Thus, can we still oppose physical distance to psychological distance? Can we still affirm that the physical absence does not permit a psychological co-presence in certain interactions, like this observed in video interviews? The results show that the psychological processes, activated in this context, are similar to those observed in "traditional" clinical consults between the patient and the therapist. However, certain specifics have led us to consider the concept of distance, here influenced by the framework, and to observe its effects. This distance could possibly constitute a therapeutic lever for some patients, notably for those who have difficulties establishing the right psychological distance in their relationships with others. According to these results, can "distance" still be opposed to "presence", or could it be re-defined? This also opens up questions on the more general concept of digital relationships, and the definition of their specificities.

  17. The impact of limited English proficiency and physician language concordance on reports of clinical interactions among patients with diabetes: the DISTANCE study.

    Science.gov (United States)

    Schenker, Yael; Karter, Andrew J; Schillinger, Dean; Warton, E Margaret; Adler, Nancy E; Moffet, Howard H; Ahmed, Ameena T; Fernandez, Alicia

    2010-11-01

    To assess the association of limited English proficiency (LEP) and physician language concordance with patient reports of clinical interactions. Cross-sectional survey of 8638 Kaiser Permanente Northern California patients with diabetes. Patient responses were used to define English proficiency and physician language concordance. Quality of clinical interactions was based on 5 questions drawn from validated scales on communication, 2 on trust, and 3 on discrimination. Respondents included 8116 English-proficient and 522 LEP patients. Among LEP patients, 210 were language concordant and 153 were language discordant. In fully adjusted models, LEP patients were more likely than English-proficient patients to report suboptimal interactions on 3 out of 10 outcomes, including 1 communication and 2 discrimination items. In separate analyses, LEP-discordant patients were more likely than English-proficient patients to report suboptimal clinician-patient interactions on 7 out of 10 outcomes, including 2 communication, 2 trust, and 3 discrimination items. In contrast, LEP-concordant patients reported similar interactions to English-proficient patients. Reports of suboptimal interactions among patients with LEP were more common among those with language-discordant physicians. Expanding access to language concordant physicians may improve clinical interactions among patients with LEP. Quality and performance assessments should consider physician-patient language concordance. Copyright © 2010 Elsevier Ireland Ltd. All rights reserved.

  18. Distance learning for similarity estimation

    NARCIS (Netherlands)

    Yu, J.; Amores, J.; Sebe, N.; Radeva, P.; Tian, Q.

    2008-01-01

    In this paper, we present a general guideline to find a better distance measure for similarity estimation based on statistical analysis of distribution models and distance functions. A new set of distance measures are derived from the harmonic distance, the geometric distance, and their generalized

  19. Bonding and Anti-bonding Modes of Plasmon Coupling Effects in TiO2-Ag Core-shell Dimers

    OpenAIRE

    Quanshui Li; Zhili Zhang

    2016-01-01

    Bonding and anti-bonding modes of plasmon coupling effects are numerically investigated in TiO2-Ag core-shell nano dimers. First, splitting phenomena of the coupled anti-bonding modes are observed under the longitudinal polarization when the distance between the monomers decreases to a certain level. Second, one of the split resonance modes is identified to be formed by the dipole anti-bonding mode of the monomers from charge density distribution patterns. Those split modes have similar redsh...

  20. Stereoscopic distance perception

    Science.gov (United States)

    Foley, John M.

    1989-01-01

    Limited cue, open-loop tasks in which a human observer indicates distances or relations among distances are discussed. By open-loop tasks, it is meant tasks in which the observer gets no feedback as to the accuracy of the responses. What happens when cues are added and when the loop is closed are considered. The implications of this research for the effectiveness of visual displays is discussed. Errors in visual distance tasks do not necessarily mean that the percept is in error. The error could arise in transformations that intervene between the percept and the response. It is argued that the percept is in error. It is also argued that there exist post-perceptual transformations that may contribute to the error or be modified by feedback to correct for the error.

  1. Fundamental aspects of recoupled pair bonds. I. Recoupled pair bonds in carbon and sulfur monofluoride

    Energy Technology Data Exchange (ETDEWEB)

    Dunning, Thom H., E-mail: thdjr@uw.edu; Xu, Lu T.; Takeshita, Tyler Y. [Department of Chemistry, University of Illinois at Urbana-Champaign, 600 S. Mathews Avenue, Urbana, Illinois 61801 (United States)

    2015-01-21

    The number of singly occupied orbitals in the ground-state atomic configuration of an element defines its nominal valence. For carbon and sulfur, with two singly occupied orbitals in their {sup 3}P ground states, the nominal valence is two. However, in both cases, it is possible to form more bonds than indicated by the nominal valence—up to four bonds for carbon and six bonds for sulfur. In carbon, the electrons in the 2s lone pair can participate in bonding, and in sulfur the electrons in both the 3p and 3s lone pairs can participate. Carbon 2s and sulfur 3p recoupled pair bonds are the basis for the tetravalence of carbon and sulfur, and 3s recoupled pair bonds enable sulfur to be hexavalent. In this paper, we report generalized valence bond as well as more accurate calculations on the a{sup 4}Σ{sup −} states of CF and SF, which are archetypal examples of molecules that possess recoupled pair bonds. These calculations provide insights into the fundamental nature of recoupled pair bonds and illustrate the key differences between recoupled pair bonds formed with the 2s lone pair of carbon, as a representative of the early p-block elements, and recoupled pair bonds formed with the 3p lone pair of sulfur, as a representative of the late p-block elements.

  2. Distances to Dark Clouds: Comparing Extinction Distances to Maser Parallax Distances

    CERN Document Server

    Foster, Jonathan B; Benjamin, Robert A; Hoare, Melvin G; Jackson, James M

    2012-01-01

    We test two different methods of using near-infrared extinction to estimate distances to dark clouds in the first quadrant of the Galaxy using large near infrared (2MASS and UKIDSS) surveys. VLBI parallax measurements of masers around massive young stars provide the most direct and bias-free measurement of the distance to these dark clouds. We compare the extinction distance estimates to these maser parallax distances. We also compare these distances to kinematic distances, including recent re-calibrations of the Galactic rotation curve. The extinction distance methods agree with the maser parallax distances (within the errors) between 66% and 100% of the time (depending on method and input survey) and between 85% and 100% of the time outside of the crowded Galactic center. Although the sample size is small, extinction distance methods reproduce maser parallax distances better than kinematic distances; furthermore, extinction distance methods do not suffer from the kinematic distance ambiguity. This validatio...

  3. Sets avoiding integral distances

    CERN Document Server

    Kurz, Sascha

    2012-01-01

    We study open point sets in Euclidean spaces $\\mathbb{R}^d$ without a pair of points an integral distance apart. By a result of Furstenberg, Katznelson, and Weiss such sets must be of Lebesgue upper density zero. We are interested in how large such sets can be in $d$-dimensional volume. We determine the lower and upper bounds for the volumes of the sets in terms of the number of their connected components and dimension, and also give some exact values. Our problem can be viewed as a kind of inverse to known problems on sets with pairwise rational or integral distances.

  4. Distance Teaching on Bornholm

    DEFF Research Database (Denmark)

    Hansen, Finn J. S.; Clausen, Christian

    2001-01-01

    The case study represents an example of a top-down introduction of distance teaching as part of Danish trials with the introduction of multimedia in education. The study is concerned with the background, aim and context of the trial as well as the role and working of the technology and the organi......The case study represents an example of a top-down introduction of distance teaching as part of Danish trials with the introduction of multimedia in education. The study is concerned with the background, aim and context of the trial as well as the role and working of the technology...

  5. Distances to star forming regions

    CERN Document Server

    Loinard, Laurent

    2014-01-01

    The determination of accurate distances to star-forming regions are discussed in the broader historical context of astronomical distance measurements. We summarize recent results for regions within 1 kpc and present perspectives for the near and more distance future.

  6. The Lesotho Distance Teaching Centre: Five Years' Learning. IEC Broadsheets on Distance Learning No. 16.

    Science.gov (United States)

    Murphy, Paud

    This report describes the activities of the first 5 years of the Lesotho Distance Teaching Center, which uses distance teaching methods to bring education to more people in Lesotho. Also described are the Center's internal organization, its relationship to other organizations in Lesotho, its costs, and some evaluation findings. Background…

  7. The Lesotho Distance Teaching Centre: Five Years' Learning. IEC Broadsheets on Distance Learning No. 16.

    Science.gov (United States)

    Murphy, Paud

    This report describes the activities of the first 5 years of the Lesotho Distance Teaching Center, which uses distance teaching methods to bring education to more people in Lesotho. Also described are the Center's internal organization, its relationship to other organizations in Lesotho, its costs, and some evaluation findings. Background…

  8. Experiments on room temperature optical fiber-fiber direct bonding

    Science.gov (United States)

    Hao, Jinping; Yan, Ping; Xiao, Qirong; Wang, Yaping; Gong, Mali

    2012-08-01

    High quality permanent connection between optical fibers is a significant issue in optics and communication. Studies on room temperature optical large diameter fiber-fiber direct bonding, which is essentially surface interactions of glass material, are presented here. Bonded fiber pairs are obtained for the first time through the bonding technics illustrated here. Two different kinds of bonding technics are provided-fresh surface (freshly grinded and polished) bonding and hydrophobic surface (activated by H2SO4 and HF) bonding. By means of fresh surface bonding, a bonded fiber pair with light transmitting efficiency of 98.1% and bond strength of 21.2 N is obtained. Besides, in the bonding process, chemical surface treatment of fibers' end surfaces is an important step. Therefore, various ways of surface treatment are analyzed and compared, based on atomic force microscopy force curves of differently disposed surfaces. According to the comparison, fresh surfaces are suggested as the prior choice in room temperature optical fiber-fiber bonding, owing to their larger adhesive force, attractive force, attractive distance, and adhesive range.

  9. Signaling Over Distances.

    Science.gov (United States)

    Saito, Atsushi; Cavalli, Valeria

    2016-02-01

    Neurons are extremely polarized cells. Axon lengths often exceed the dimension of the neuronal cell body by several orders of magnitude. These extreme axonal lengths imply that neurons have mastered efficient mechanisms for long distance signaling between soma and synaptic terminal. These elaborate mechanisms are required for neuronal development and maintenance of the nervous system. Neurons can fine-tune long distance signaling through calcium wave propagation and bidirectional transport of proteins, vesicles, and mRNAs along microtubules. The signal transmission over extreme lengths also ensures that information about axon injury is communicated to the soma and allows for repair mechanisms to be engaged. This review focuses on the different mechanisms employed by neurons to signal over long axonal distances and how signals are interpreted in the soma, with an emphasis on proteomic studies. We also discuss how proteomic approaches could help further deciphering the signaling mechanisms operating over long distance in axons. © 2016 by The American Society for Biochemistry and Molecular Biology, Inc.

  10. Weighted Feature Distance

    DEFF Research Database (Denmark)

    Ortiz-Arroyo, Daniel; Yazdani, Hossein

    2017-01-01

    The accuracy of machine learning methods for clustering depends on the optimal selection of similarity functions. Conventional distance functions for the vector space might cause an algorithm to being affected by some dominant features that may skew its final results. This paper introduces a flexib...

  11. Encyclopedia of Distance Learning

    Science.gov (United States)

    Howard, Caroline, Ed.; Boettecher, Judith, Ed.; Justice, Lorraine, Ed.; Schenk, Karen, Ed.; Rogers, Patricia, Ed.; Berg, Gary, Ed.

    2005-01-01

    The innovations in computer and communications technologies combined with on-going needs to deliver educational programs to students regardless of their physical locations, have lead to the innovation of distance education programs and technologies. To keep up with recent developments in both areas of technologies and techniques related to…

  12. Accreditation of Distance Learning

    Science.gov (United States)

    Demirel, Ergün

    2016-01-01

    The higher education institutes aspire to gain reputation of quality having accreditation from internationally recognized awarding bodies. The accreditation leads and provides quality assurance for education. Although distance learning becomes a significant part of the education system in the 21st century, there is still a common opinion that the…

  13. Prospect of Distance Learning

    Science.gov (United States)

    Rahman, Monsurur; Karim, Reza; Byramjee, Framarz

    2015-01-01

    Many educational institutions in the United States are currently offering programs through distance learning, and that trend is rising. In almost all spheres of education a developing country like Bangladesh needs to make available the expertise of the most qualified faculty to her distant people. But the fundamental question remains as to whether…

  14. Misconceptions of Astronomical Distances

    Science.gov (United States)

    Miller, Brian W.; Brewer, William F.

    2010-01-01

    Previous empirical studies using multiple-choice procedures have suggested that there are misconceptions about the scale of astronomical distances. The present study provides a quantitative estimate of the nature of this misconception among US university students by asking them, in an open-ended response format, to make estimates of the distances…

  15. A rare case report of peri-implant bone necrosis: Mapping the distance of initial peri-implant complication toward a path of success

    Directory of Open Access Journals (Sweden)

    S K Salaria

    2011-01-01

    Full Text Available In the past decade, science of implant placement has greatly advanced and at the same time much success has been experienced with the endosseous implant. Despite the long-term predictability of the implants, however, biological, technical and esthetic complications do occur. The use of osseointegrated implants as a foundation for prosthetic replacement of missing teeth has been highly predictable, but still at present, there is no consensus of how to best manage the complications occurring after implant placement. In this report, we discuss post-insertion complication of bone necrosis and its successful management.

  16. Bayesian field theoretic reconstruction of bond potential and bond mobility in single molecule force spectroscopy

    CERN Document Server

    Chang, Joshua C; Chou, Tom

    2015-01-01

    Quantifying the forces between and within macromolecules is a necessary first step in understanding the mechanics of molecular structure, protein folding, and enzyme function and performance. In such macromolecular settings, dynamic single-molecule force spectroscopy (DFS) has been used to distort bonds. The resulting responses, in the form of rupture forces, work applied, and trajectories of displacements, have been used to reconstruct bond potentials. Such approaches often rely on simple parameterizations of one-dimensional bond potentials, assumptions on equilibrium starting states, and/or large amounts of trajectory data. Parametric approaches typically fail at inferring complex-shaped bond potentials with multiple minima, while piecewise estimation may not guarantee smooth results with the appropriate behavior at large distances. Existing techniques, particularly those based on work theorems, also do not address spatial variations in the diffusivity that may arise from spatially inhomogeneous coupling to...

  17. Students' Perceptions of Parental Bonding Styles and Their Academic Burnout

    Science.gov (United States)

    Shin, Hyojung; Lee, Jayoung; Kim, Boyoung; Lee, Sang Min

    2012-01-01

    This study investigated how parental bonding style affects academic burnout in Korean adolescents. Participants were 447 middle school students, who completed the Parental Bonding Instrument and the Maslach Burnout Inventory-Student Survey. MANCOVA results confirmed that adolescents reporting the optimal bonding parental style, for both mother and…

  18. Students' Perceptions of Parental Bonding Styles and Their Academic Burnout

    Science.gov (United States)

    Shin, Hyojung; Lee, Jayoung; Kim, Boyoung; Lee, Sang Min

    2012-01-01

    This study investigated how parental bonding style affects academic burnout in Korean adolescents. Participants were 447 middle school students, who completed the Parental Bonding Instrument and the Maslach Burnout Inventory-Student Survey. MANCOVA results confirmed that adolescents reporting the optimal bonding parental style, for both mother and…

  19. Equilibrium CO bond lengths

    Science.gov (United States)

    Demaison, Jean; Császár, Attila G.

    2012-09-01

    Based on a sample of 38 molecules, 47 accurate equilibrium CO bond lengths have been collected and analyzed. These ultimate experimental (reEX), semiexperimental (reSE), and Born-Oppenheimer (reBO) equilibrium structures are compared to reBO estimates from two lower-level techniques of electronic structure theory, MP2(FC)/cc-pVQZ and B3LYP/6-311+G(3df,2pd). A linear relationship is found between the best equilibrium bond lengths and their MP2 or B3LYP estimates. These (and similar) linear relationships permit to estimate the CO bond length with an accuracy of 0.002 Å within the full range of 1.10-1.43 Å, corresponding to single, double, and triple CO bonds, for a large number of molecules. The variation of the CO bond length is qualitatively explained using the Atoms in Molecules method. In particular, a nice correlation is found between the CO bond length and the bond critical point density and it appears that the CO bond is at the same time covalent and ionic. Conditions which permit the computation of an accurate ab initio Born-Oppenheimer equilibrium structure are discussed. In particular, the core-core and core-valence correlation is investigated and it is shown to roughly increase with the bond length.

  20. Copper wire bonding

    CERN Document Server

    Chauhan, Preeti S; Zhong, ZhaoWei; Pecht, Michael G

    2014-01-01

    This critical volume provides an in-depth presentation of copper wire bonding technologies, processes and equipment, along with the economic benefits and risks.  Due to the increasing cost of materials used to make electronic components, the electronics industry has been rapidly moving from high cost gold to significantly lower cost copper as a wire bonding material.  However, copper wire bonding has several process and reliability concerns due to its material properties.  Copper Wire Bonding book lays out the challenges involved in replacing gold with copper as a wire bond material, and includes the bonding process changes—bond force, electric flame off, current and ultrasonic energy optimization, and bonding tools and equipment changes for first and second bond formation.  In addition, the bond–pad metallurgies and the use of bare and palladium-coated copper wires on aluminum are presented, and gold, nickel and palladium surface finishes are discussed.  The book also discusses best practices and re...

  1. FINAL TECHNICAL REPORT for grant DE-FG02-93ER14353 "Carbon-Hydrogen Bond Functionalization Catalyzed by Transition Metal Systems"

    Energy Technology Data Exchange (ETDEWEB)

    Goldman, Alan S

    2012-05-21

    Alkanes are our most abundant organic resource but are highly resistant to selective chemical transformations. Alkenes (olefins) by contrast are the single most versatile class of molecules for selective transformations, and are intermediates in virtually every petrochemical process as well as a vast range of commodity and fine chemical processes. Over the course of this project we have developed the most efficient catalysts to date for the selective conversion of alkanes to give olefins, and have applied these catalysts to other dehydrogenation reactions. We have also developed some of the first efficient catalysts for carbonylation of alkanes and arenes to give aldehydes. The development of these catalysts has been accompanied by elucidation of the mechanism of their operation and the factors controlling the kinetics and thermodynamics of C-H bond activation and other individual steps of the catalytic cycles. This fundamental understanding will allow the further improvement of these catalysts, as well as the development of the next generation of catalysts for the functionalization of alkanes and other molecules containing C-H bonds.

  2. Distance Education Programs in Social Work: Current and Emerging Trends

    Science.gov (United States)

    Vernon, Robert; Vakalahi, Halaevalu; Pierce, Dean; Pittman-Munke, Peggy; Adkins, Lynn Frantz

    2009-01-01

    This article reports on current and emerging trends in the use of distance education technologies in social work education. Areas studied include the extent of distance education programs, curricular areas covered, technologies used, pedagogical approaches, intentions for degree-program development, sources of pressure to adopt distance education…

  3. An erbium-based bifuctional heterogeneous catalyst: a cooperative route towards C-C bond formation.

    Science.gov (United States)

    Oliverio, Manuela; Costanzo, Paola; Macario, Anastasia; De Luca, Giuseppina; Nardi, Monica; Procopio, Antonio

    2014-07-15

    Heterogeneous bifuctional catalysts are multifunctional synthetic catalysts enabling efficient organic transformations by exploiting two opposite functionalities without mutual destruction. In this paper we report the first Er(III)-based metallorganic heterogeneous catalyst, synthesized by post-calcination MW-assisted grafting and modification of the natural aminoacid L-cysteine. The natural acid-base distance between sites was maintained to assure the cooperation. The applicability of this new bifunctional heterogeneous catalyst to C-C bond formation and the supposed mechanisms of action are discussed as well.

  4. An Erbium-Based Bifuctional Heterogeneous Catalyst: A Cooperative Route Towards C-C Bond Formation

    Directory of Open Access Journals (Sweden)

    Manuela Oliverio

    2014-07-01

    Full Text Available Heterogeneous bifuctional catalysts are multifunctional synthetic catalysts enabling efficient organic transformations by exploiting two opposite functionalities without mutual destruction. In this paper we report the first Er(III-based metallorganic heterogeneous catalyst, synthesized by post-calcination MW-assisted grafting and modification of the natural aminoacid L-cysteine. The natural acid–base distance between sites was maintained to assure the cooperation. The applicability of this new bifunctional heterogeneous catalyst to C-C bond formation and the supposed mechanisms of action are discussed as well.

  5. Fuzzy clustering with Minkowski distance

    NARCIS (Netherlands)

    P.J.F. Groenen (Patrick); U. Kaymak (Uzay); J.M. van Rosmalen (Joost)

    2006-01-01

    textabstractDistances in the well known fuzzy c-means algorithm of Bezdek (1973) are measured by the squared Euclidean distance. Other distances have been used as well in fuzzy clustering. For example, Jajuga (1991) proposed to use the L_1-distance and Bobrowski and Bezdek (1991) also used the L_inf

  6. The sound of distance.

    Science.gov (United States)

    Rabaglia, Cristina D; Maglio, Sam J; Krehm, Madelaine; Seok, Jin H; Trope, Yaacov

    2016-07-01

    Human languages may be more than completely arbitrary symbolic systems. A growing literature supports sound symbolism, or the existence of consistent, intuitive relationships between speech sounds and specific concepts. Prior work establishes that these sound-to-meaning mappings can shape language-related judgments and decisions, but do their effects generalize beyond merely the linguistic and truly color how we navigate our environment? We examine this possibility, relating a predominant sound symbolic distinction (vowel frontness) to a novel associate (spatial proximity) in five studies. We show that changing one vowel in a label can influence estimations of distance, impacting judgment, perception, and action. The results (1) provide the first experimental support for a relationship between vowels and spatial distance and (2) demonstrate that sound-to-meaning mappings have outcomes that extend beyond just language and can - through a single sound - influence how we perceive and behave toward objects in the world. Copyright © 2016 Elsevier B.V. All rights reserved.

  7. Tolman's Luminosity-Distance, Poincare's Light-Distance and Cayley-Klein's Hyperbolic Distance

    CERN Document Server

    Pierseaux, Yves

    2009-01-01

    We deduce Tolman's formula of luminosity-distance in Cosmology from Poincare's definition of light-distance with Lorentz Transformation (LT).In Minkowskian metric, if distance is proper time (as it is often argued) then light-distance must be also the shortest distance, like proper duration (unlike Einstein's longest length within rest system). By introducing Poincare's proper light-distance in Einstein's basic synchronization we deduce a dilated distance between observer and receding mirror (with relativistic Doppler factor). Such a distance corresponds not to an Euclidean distance (Einstein's rigid rod) but to an Hyperbolic distance (Cayley-Klein) with a Lobatchevskian Horizon. From a basic proportionality hyperbolic distance-velocity, we deduce the law of Hubble. By following Penrose's Lobatchevskian representation of LT, we transform Special Relativity (SR) into an Hyperbolic Cosmological Relativity (HCR). by using only the LT but the whole LT. In Hyperbolic Rotation motion (basic active LT or Einstein's ...

  8. Distance, Borders, and Time

    DEFF Research Database (Denmark)

    Skillicorn, David; Walther, Olivier; Zheng, Quan

    is a combination of the physical geography of the target environment, and the mental and physical cost of following a seemingly random pattern of attacks. Focusing on the distance and time between attacks and taking into consideration the transaction costs that state boundaries impose, we wish to understand what......” of North and West Africa that depicts the permeability to violence. A better understanding of how location, time, and borders condition attacks enables planning, prepositioning, and response....

  9. Bond Tension in Tethered Macromolecules.

    Science.gov (United States)

    Sheiko, Sergei S; Panyukov, Sergey; Rubinstein, Michael

    2011-06-14

    The paper presents scaling analysis of mechanical tension generated in densely branched macromolecules tethered to a solid substrate with a short linker. Steric repulsion between branches results in z-fold amplification of tension in the linker, where z is the number of chain-like arms. At large z ~ 100-1000, the generated tension may exceed the strength of covalent bonds and sever the linker. Two types of molecular architectures were considered: polymer stars and polymer "bottlebrushes" tethered to a solid substrate. Depending on the grafting density, one distinguishes the so-called mushroom, loose grafting, and dense grafting regimes. In isolated (mushroom) and loosely tethered bottlebrushes, the linker tension is by a factor of [Formula: see text] smaller than the tension in a tethered star with the same number of arms z. In densely tethered stars, the effect of interchain distance (d) and number of arms (z) on the magnitude of linker tension is given by f ≅ f0z(3/2)(b/d) for stars in a solvent environment and f ≅ f0z(2) (b/d)(2) for dry stars, where b is the Kuhn length and f0 ≅ kBT/b is intrinsic bond tension. These relations are also valid for tethered bottlebrushes with long side chains. However, unlike molecular stars, bottlebrushes demonstrate variation of tension along the backbone f ≅ f0s z(1/2) / d as a function of distance s from the free end of the backbone. In dense brushes [Formula: see text] with z ≅ 1000, the backbone tension increases from f ≅ f0 = 1 pN at the free end of the backbone (s ≅ b) to its maximum f ≅ zf0 ≅ 1 nN at the linker to the substrate (s ≅ zb).

  10. Comparison of Gold Bonding with Mercury Bonding

    NARCIS (Netherlands)

    Kraka, Elfi; Filatov, Michael; Cremer, Dieter

    2009-01-01

    Nine AuX molecules (X = H, O, S, Se, Te, F, Cl, Br, I), their isoelectronic HgX(+) analogues, and the corresponding neutral HgX diatomics have been investigated using NESC (Normalized Elimination of the Small Component) and B3LYP theory to determine relativistic effects for bond dissociation energie

  11. Comparison of Gold Bonding with Mercury Bonding

    NARCIS (Netherlands)

    Kraka, Elfi; Filatov, Michael; Cremer, Dieter

    2009-01-01

    Nine AuX molecules (X = H, O, S, Se, Te, F, Cl, Br, I), their isoelectronic HgX(+) analogues, and the corresponding neutral HgX diatomics have been investigated using NESC (Normalized Elimination of the Small Component) and B3LYP theory to determine relativistic effects for bond dissociation

  12. The dissociative bond.

    Science.gov (United States)

    Gordon, Nirit

    2013-01-01

    Dissociation leaves a psychic void and a lingering sense of psychic absence. How do 2 people bond while they are both suffering from dissociation? The author explores the notion of a dissociative bond that occurs in the aftermath of trauma--a bond that holds at its core an understanding and shared detachment from the self. Such a bond is confined to unspoken terms that are established in the relational unconscious. The author proposes understanding the dissociative bond as a transitional space that may not lead to full integration of dissociated knowledge yet offers some healing. This is exemplified by R. Prince's (2009) clinical case study. A relational perspective is adopted, focusing on the intersubjective aspects of a dyadic relationship. In the dissociative bond, recognition of the need to experience mutual dissociation can accommodate a psychic state that yearns for relationship when the psyche cannot fully confront past wounds. Such a bond speaks to the need to reestablish a sense of human relatedness and connection when both parties in the relationship suffer from disconnection. This bond is bound to a silence that becomes both a means of protection against the horror of traumatic memory and a way to convey unspoken gestures toward the other.

  13. The samurai bond market

    OpenAIRE

    1997-01-01

    Issuance in the samurai bond market has more than tripled over the past several years. Some observers have attributed this growth to a systematic underestimation of credit risk in the market. A detailed review of credit quality, ratings differences, and initial issue pricing in the samurai bond market, however, turns up little evidence to support this concern.

  14. Hydrogen bond dynamics in bulk alcohols

    Energy Technology Data Exchange (ETDEWEB)

    Shinokita, Keisuke; Cunha, Ana V.; Jansen, Thomas L. C.; Pshenichnikov, Maxim S., E-mail: Maxim.Pchenitchnikov@RuG.nl [Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen (Netherlands)

    2015-06-07

    Hydrogen-bonded liquids play a significant role in numerous chemical and biological phenomena. In the past decade, impressive developments in multidimensional vibrational spectroscopy and combined molecular dynamics–quantum mechanical simulation have established many intriguing features of hydrogen bond dynamics in one of the fundamental solvents in nature, water. The next class of a hydrogen-bonded liquid—alcohols—has attracted much less attention. This is surprising given such important differences between water and alcohols as the imbalance between the number of hydrogen bonds, each molecule can accept (two) and donate (one) and the very presence of the hydrophobic group in alcohols. Here, we use polarization-resolved pump-probe and 2D infrared spectroscopy supported by extensive theoretical modeling to investigate hydrogen bond dynamics in methanol, ethanol, and isopropanol employing the OH stretching mode as a reporter. The sub-ps dynamics in alcohols are similar to those in water as they are determined by similar librational and hydrogen-bond stretch motions. However, lower density of hydrogen bond acceptors and donors in alcohols leads to the appearance of slow diffusion-controlled hydrogen bond exchange dynamics, which are essentially absent in water. We anticipate that the findings herein would have a potential impact on fundamental chemistry and biology as many processes in nature involve the interplay of hydrophobic and hydrophilic groups.

  15. Monge Distance between Quantum States

    CERN Document Server

    Zyczkowski, K; Zyczkowski, Karol; Slomczynski, Wojciech

    1998-01-01

    We define a metric in the space of quantum states taking the Monge distance between corresponding Husimi distributions (Q--functions). This quantity fulfills the axioms of a metric and satisfies the following semiclassical property: the distance between two coherent states is equal to the Euclidean distance between corresponding points in the classical phase space. We compute analytically distances between certain states (coherent, squeezed, Fock and thermal) and discuss a scheme for numerical computation of Monge distance for two arbitrary quantum states.

  16. Hydrophobic interactions and hydrogen bonds in \\beta-sheet formation

    CERN Document Server

    Narayanan, Chitra

    2013-01-01

    In this study, we investigate interactions of extended conformations of homodimeric peptides made of small (glycine or alanine) and large hydrophobic (valine or leucine) sidechains using all-atom molecular dynamics simulations to decipher driving forces for \\beta-sheet formation. We make use of a periodic boundary condition setup in which individual peptides are infinitely long and stretched. Dimers adopt \\beta-sheet conformations at short interpeptide distances (\\xi ~ 0.5 nm) and at intermediate distances (~ 0.8 nm), valine and leucine homodimers assume cross-\\beta-like conformations with side chains interpenetrating each other. These two states are identified as minima in the Potential of Mean Force (PMF). While the number of interpeptide hydrogen bonds increases with decreasing interpeptide distance, the total hydrogen bond number in the system does not change significantly, suggesting that formation of \\beta-sheet structures from extended conformations is not driven by hydrogen bonds. This is supported by...

  17. Corporate Bonds in Denmark

    DEFF Research Database (Denmark)

    Tell, Michael

    2015-01-01

    Corporate financing is the choice between capital generated by the corporation and capital from external investors. However, since the financial crisis shook the markets in 2007–2008, financing opportunities through the classical means of financing have decreased. As a result, corporations have...... to think in alternative ways such as issuing corporate bonds. A market for corporate bonds exists in countries such as Norway, Germany, France, the United Kingdom and the United States, while Denmark is still behind in this trend. Some large Danish corporations have instead used foreign corporate bonds...... markets. However, NASDAQ OMX has introduced the First North Bond Market in December 2012 and new regulatory framework came into place in 2014, which may contribute to a Danish based corporate bond market. The purpose of this article is to present the regulatory changes in Denmark in relation to corporate...

  18. Molecular dynamics simulations of the hydration of poly(vinyl methyl ether): Hydrogen bonds and quasi-hydrogen bonds

    Institute of Scientific and Technical Information of China (English)

    WU RongLiang; JI Qing; KONG Bin; YANG XiaoZhen

    2008-01-01

    Atomistic detailed hydration structures of poly(vinyl methyl ether) (PVME) have been investigated by molecular dynamics simulations under 300 K at various concentrations. Both radial distribution func-tions and the distance distributions between donors and acceptors in hydrogen bonds show that the hydrogen bonds between the polymer and water are shorter by 0.005 nm than those between water molecules. The Quasi-hydrogen bonds take only 7.2% of the van der Waals interaction pairs. It was found the hydrogen bonds are not evenly distributed along the polymer chain, and there still exists a significant amount (10%) of ether oxygen atoms that are not hydrogen bonded to water at a concentra-tion as low as 3.3%. This shows that in polymer solutions close contacts occur not only between polymer chains but also between chain segments within the polymer, which leads to inefficient con-tacts between ether oxygen atoms and water molecules. Variation of the quasi-hydrogen bonds with the concentration is similar to that of hydrogen bonds, but the ratio of the repeat units forming quasi-hydrogen bonds to those forming hydrogen bonds approaches 0.2. A transition was found in the demixing enthalpy at around 30% measured by dynamic testing differential scanning calorimetry (DTDSC) for aqueous solutions of a mono-dispersed low molecular weight PVME, which can be related to the transition of the fractions of hydrogen bonds and quasi-hydrogen bonds at ~27%. The transition of the fractions of hydrogen bonds and quasi-hydrogen bonds at ~27% can be used to explain the demixing enthalpy transition at 30% at a molecular scale. In addition, at the concentration of 86%, each ether oxygen atom bonded with water is assigned 1.56 water molecules on average, and 'free' water molecules emerge at the concentration of around 54%.

  19. Molecular dynamics simulations of the hydration of poly(vinyl methyl ether):Hydrogen bonds and quasi-hydrogen bonds

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Atomistic detailed hydration structures of poly(vinyl methyl ether)(PVME) have been investigated by molecular dynamics simulations under 300 K at various concentrations. Both radial distribution functions and the distance distributions between donors and acceptors in hydrogen bonds show that the hydrogen bonds between the polymer and water are shorter by 0.005 nm than those between water molecules. The Quasi-hydrogen bonds take only 7.2% of the van der Waals interaction pairs. It was found the hydrogen bonds are not evenly distributed along the polymer chain,and there still exists a significant amount(10%) of ether oxygen atoms that are not hydrogen bonded to water at a concentration as low as 3.3%. This shows that in polymer solutions close contacts occur not only between polymer chains but also between chain segments within the polymer,which leads to inefficient contacts between ether oxygen atoms and water molecules. Variation of the quasi-hydrogen bonds with the concentration is similar to that of hydrogen bonds,but the ratio of the repeat units forming quasi-hydrogen bonds to those forming hydrogen bonds approaches 0.2. A transition was found in the demixing enthalpy at around 30% measured by dynamic testing differential scanning calorimetry(DTDSC) for aqueous solutions of a mono-dispersed low molecular weight PVME,which can be related to the transition of the fractions of hydrogen bonds and quasi-hydrogen bonds at ~27%. The transition of the fractions of hydrogen bonds and quasi-hydrogen bonds at ~27% can be used to explain the demixing enthalpy transition at 30% at a molecular scale. In addition,at the concentration of 86%,each ether oxygen atom bonded with water is assigned 1.56 water molecules on average,and ’free’ water molecules emerge at the concentration of around 54%.

  20. On the nature of blueshifting hydrogen bonds.

    Science.gov (United States)

    Mo, Yirong; Wang, Changwei; Guan, Liangyu; Braïda, Benoît; Hiberty, Philippe C; Wu, Wei

    2014-07-01

    The block-localized wave function (BLW) method can derive the energetic, geometrical, and spectral changes with the deactivation of electron delocalization, and thus provide a unique way to elucidate the origin of improper, blueshifting hydrogen bonds versus proper, redshifting hydrogen bonds. A detailed analysis of the interactions of F(3)CH with NH(3) and OH(2) shows that blueshifting is a long-range phenomenon. Since among the various energy components contributing to hydrogen bonds, only the electrostatic interaction has long-range characteristics, we conclude that the contraction and blueshifting of a hydrogen bond is largely caused by electrostatic interactions. On the other hand, lengthening and redshifting is primarily due to the short-range n(Y)→σ*(X-H) hyperconjugation. The competition between these two opposing factors determines the final frequency change direction, for example, redshifting in F(3)CH⋅⋅⋅NH(3) and blueshifting in F(3)CH⋅⋅⋅OH(2). This mechanism works well in the series F(n)Cl(3)-n CH⋅⋅⋅Y (n=0-3, Y=NH(3), OH(2), SH(2)) and other systems. One exception is the complex of water and benzene. We observe the lengthening and redshifting of the O-H bond of water even with the electron transfer between benzene and water completely quenched. A distance-dependent analysis for this system reveals that the long-range electrostatic interaction is again responsible for the initial lengthening and redshifting.

  1. The DDO IVC Distance Project

    CERN Document Server

    Gladders, M D; Burns, C R; Attard, A; Casey, M P; Hamilton, D; Mallén-Ornelas, G; Karr, J L; Poirier, S M; Sawicki, M; Barrientos, F; Barkhouse, W A; Brodwin, M; Clark, J; McNaughton, R; Ruetalo-Pacheco, M; Mochnacki, S W; Gladders, Michael D.; Clarke, Tracy E.; Burns, Christopher R.; Attard, Allen; Casey, Michael P.; Hamilton, Devon; Mallen-Ornelas, Gabriela; Karr, Jennifer L.; Poirier, Sara M.; Sawicki, Marcin; Barrientos, Felipe; Barkhouse, Wayne; Brodwin, Mark; Clark, Jason; Naughton, Rosemary Mc; Ruetalo-Pacheco, Marcelo; Mochnacki, Stefan W.

    1998-01-01

    We present the first set of distance limits from the David Dunlap Observatory Intermediate Velocity Cloud (DDO IVC) distance project. Such distance measures are crucial to understanding the origins and dynamics of IVCs, as the distances set most of the basic physical parameters for the clouds. Currently there are very few IVCs with reliably known distances. This paper describes in some detail the basic techniques used to measure distances, with particular emphasis on the the analysis of interstellar absorption line data, which forms the basis of our distance determinations. As an example, we provide a detailed description of our distance determination for the Draco Cloud. Preliminary distance limits for a total of eleven clouds are provided.

  2. Advanced hierarchical distance sampling

    Science.gov (United States)

    Royle, Andy

    2016-01-01

    In this chapter, we cover a number of important extensions of the basic hierarchical distance-sampling (HDS) framework from Chapter 8. First, we discuss the inclusion of “individual covariates,” such as group size, in the HDS model. This is important in many surveys where animals form natural groups that are the primary observation unit, with the size of the group expected to have some influence on detectability. We also discuss HDS integrated with time-removal and double-observer or capture-recapture sampling. These “combined protocols” can be formulated as HDS models with individual covariates, and thus they have a commonality with HDS models involving group structure (group size being just another individual covariate). We cover several varieties of open-population HDS models that accommodate population dynamics. On one end of the spectrum, we cover models that allow replicate distance sampling surveys within a year, which estimate abundance relative to availability and temporary emigration through time. We consider a robust design version of that model. We then consider models with explicit dynamics based on the Dail and Madsen (2011) model and the work of Sollmann et al. (2015). The final major theme of this chapter is relatively newly developed spatial distance sampling models that accommodate explicit models describing the spatial distribution of individuals known as Point Process models. We provide novel formulations of spatial DS and HDS models in this chapter, including implementations of those models in the unmarked package using a hack of the pcount function for N-mixture models.

  3. Distance Metric Tracking

    Science.gov (United States)

    2016-03-02

    520, 2004. 16 [12] E.C. Hall and R.M. Willett. Online convex optimization in dynamic environ- ments. Selected Topics in Signal Processing, IEEE Journal...Conference on Machine Learning, pages 1160–1167. ACM, 2008. [25] Eric P Xing, Michael I Jordan, Stuart Russell, and Andrew Y Ng. Distance metric...whereBψ is any Bregman divergence and ηt is the learning rate parameter. From ( Hall & Willett, 2015) we have: Theorem 1. G` = max θ∈Θ,`∈L ‖∇f(θ)‖ φmax = 1

  4. Long distance tunneling

    CERN Document Server

    Ivlev, B I

    2005-01-01

    Quantum tunneling between two potential wells in a magnetic field can be strongly increased when the potential barrier varies in the direction perpendicular to the line connecting the two wells and remains constant along this line. A periodic structure of the wave function is formed in the direction joining the wells. The resulting motion can be coherent like motion in a conventional narrow band periodic structure. A particle penetrates the barrier over a long distance which strongly contrasts to WKB-like tunneling. The whole problem is stationary. The coherent process can be influenced by dissipation.

  5. Distances on Lozenge Tilings

    CERN Document Server

    Bodini, Olivier; Fernique, Thomas

    2009-01-01

    In this paper, a structural property of the set of lozenge tilings of a 2n-gon is highlighted. We introduce a simple combinatorial value called Hamming-distance, which is a lower bound for the flipdistance (i.e. the number of necessary local transformations involving three lozenges) between two given tilings. It is here proven that, for n5, We show that there is some deficient pairs of tilings for which the flip connection needs more flips than the combinatorial lower bound indicates.

  6. Distance Teaching on Bornholm

    DEFF Research Database (Denmark)

    Hansen, Finn J. S.; Clausen, Christian

    2001-01-01

    and the organisational set-up. It is debated which kind of social learning that has taken place. The innovation process was based on the implementation of an inflexible video-conference system without any proactive considerations of organisational change or pedagocical development. User appropriation of the technology......The case study represents an example of a top-down introduction of distance teaching as part of Danish trials with the introduction of multimedia in education. The study is concerned with the background, aim and context of the trial as well as the role and working of the technology...

  7. Development of new bond release criteria for surface coal mines in the eastern and interior coal provinces of the United States. Open file report (final) 18 jul 77-18 jul 78

    Energy Technology Data Exchange (ETDEWEB)

    Knuth, W.M.; Fritz, E.L.; Schad, J.A.; Nagle, W.F.

    1978-09-18

    This study involved a review of bonding and bond release practices in the States of the eastern and midwestern coal provinces. Data was collected from regulatory authorities and site visits to document the bonding and release procedures in the States related to achieving successful reclamation. The regulations related to PL95-87 were reviewed. The analysis included suggested modified or new bond release criteria based on a review of applicable bond release inspection techniques, a conceptual graduated bonding system, and incentive procedures for reclamation of surface mine sites to alternative or higher land uses.

  8. Strength of hydrogen bonds of water depends on local environment.

    Science.gov (United States)

    Huš, Matej; Urbic, Tomaz

    2012-04-14

    In-depth knowledge of water-water potential is important for devising and evaluating simple water models if they are to accurately describe water properties and reflect various solvation phenomena. Water-water potential depends upon inter-molecular distance, relative orientation of water molecules, and also local environment. When placed at a favorable distance in a favorable orientation, water molecules exhibit a particularly strong attractive interaction called hydrogen bond. Although hydrogen bond is very important for its effects on the elements of life, industrial applications, and bulk water properties, there is no scientific consensus on its true nature and origin. Using quantum-mechanical methods, hydrogen bond strength was calculated in different local environments. A simple empirical linear relationship was discovered between maximum hydrogen bond strength and the number of water molecules in the local environment. The local environment effect was shown to be considerable even on the second coordination shell. Additionally, a negative linear correlation was found between maximum hydrogen bond strength and the distance, at which it was observed. These results provide novel insights into the nature of hydrogen bonding.

  9. Effect of ultrasonic power and bonding force on the bonding strength of copper ball bonds

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Copper wire, serving as a cost-saving alternative to gold wire, has been used in many high-end thermosonic ball bonding applications. In this paper, the bond shear force, bond shear strength, and the ball bond diameter are adopted to evaluate the bonding quality. It is concluded that the efficient ultrasonic power is needed to soften the ball to form the copper bonds with high bonding strength. However, excessive ultrasonic power would serve as a fatigue loading to weaken the bonding. Excessive or less bonding force would cause cratering in the silicon.

  10. Distance Learning. Volume I: Distance Learning Analysis Study.

    Science.gov (United States)

    1998-09-01

    The primary focus of this project is the determination of the feasibility and cost effectiveness of applying Distance Learning strategies to 22...selected PPSCP courses and development of a Distance Learning Analysis Procedures Manual.

  11. PERBANDINGAN EUCLIDEAN DISTANCE DENGAN CANBERRA DISTANCE PADA FACE RECOGNITION

    Directory of Open Access Journals (Sweden)

    Sendhy Rachmat Wurdianarto

    2014-08-01

    Full Text Available Perkembangan ilmu pada dunia komputer sangatlah pesat. Salah satu yang menandai hal ini adalah ilmu komputer telah merambah pada dunia biometrik. Arti biometrik sendiri adalah karakter-karakter manusia yang dapat digunakan untuk membedakan antara orang yang satu dengan yang lainnya. Salah satu pemanfaatan karakter / organ tubuh pada setiap manusia yang digunakan untuk identifikasi (pengenalan adalah dengan memanfaatkan wajah. Dari permasalahan diatas dalam pengenalan lebih tentang aplikasi Matlab pada Face Recognation menggunakan metode Euclidean Distance dan Canberra Distance. Model pengembangan aplikasi yang digunakan adalah model waterfall. Model waterfall beriisi rangkaian aktivitas proses yang disajikan dalam proses analisa kebutuhan, desain menggunakan UML (Unified Modeling Language, inputan objek gambar diproses menggunakan Euclidean Distance dan Canberra Distance. Kesimpulan yang dapat ditarik adalah aplikasi face Recognation menggunakan metode euclidean Distance dan Canverra Distance terdapat kelebihan dan kekurangan masing-masing. Untuk kedepannya aplikasi tersebut dapat dikembangkan dengan menggunakan objek berupa video ataupun objek lainnya.   Kata kunci : Euclidean Distance, Face Recognition, Biometrik, Canberra Distance

  12. Transversely Compressed Bonded Joints

    DEFF Research Database (Denmark)

    Hansen, Christian Skodborg; Schmidt, Jacob Wittrup; Stang, Henrik

    2012-01-01

    The load capacity of bonded joints can be increased if transverse pressure is applied at the interface. The transverse pressure is assumed to introduce a Coulomb-friction contribution to the cohesive law for the interface. Response and load capacity for a bonded single-lap joint was derived using...... non-linear fracture mechanics. The results indicated a good correlation between theory and tests. Furthermore, the model is suggested as theoretical base for determining load capacity of bonded anchorages with transverse pressure, in externally reinforced concrete structures....

  13. An Intramolecular CAr-H•••O=C Hydrogen Bond and the Configuration of Rotenoids.

    Science.gov (United States)

    Ren, Yulin; Gallucci, Judith C; Kinghorn, A Douglas

    2017-04-20

    Over the past half a century, the structure and configuration of the rotenoids, a group of natural products showing multiple promising bioactivities, have been established by interpretation of their NMR and electronic circular dichroism spectra and confirmed by analysis of single-crystal X-ray diffraction data. The chemical shift of the H-6' (1)H NMR resonance has been found to be an indicator of either a cis or trans C/D ring system. In the present study, four structures representing the central rings of a cis-, a trans-, a dehydro-, and an oxadehydro-rotenoid have been plotted using the Mercury program based on X-ray crystal structures reported previously, with the conformations of the C/D ring system, the local bond lengths or interatomic distances, hydrogen bond angles, and the H-6' chemical shift of these compounds presented. It is shown for the first time that a trans-fused C/D ring system of rotenoids is preferred for the formation of a potential intramolecular C6'-H6'•••O=C4 H-bond, and that such H-bonding results in the (1)H NMR resonance for H-6' being shifted downfield. Georg Thieme Verlag KG Stuttgart · New York.

  14. Dinuclear Complexes Formed by Hydrogen Bonds: Synthesis, Structure and Magnetic and Electrochemical Properties.

    Science.gov (United States)

    Granelli, Matteo; Downward, Alan M; Huber, Robin; Guénée, Laure; Besnard, Céline; Krämer, Karl W; Decurtins, Silvio; Liu, Shi-Xia; Thompson, Laurence K; Williams, Alan F

    2017-05-23

    The synthesis is reported of a series of homo- and hetero-dinuclear octahedral complexes of the ligand 1, 1,2-bis(1-methyl-benzimidazol-2-yl) ethanol, where the two metal centres are linked by hydrogen bonds between coordinated alcohols and coordinated alkoxides. Homonuclear divalent M(II) M(II) , mixed-valent M(II) M(III) and heteronuclear M(II) M'(III) species are prepared. The complexes have been characterised by X-ray crystallography and show unusually short O⋅⋅⋅O distances for the hydrogen bonds. Magnetic measurements show the hydrogen-bond bridges can lead to ferromagnetic or antiferromagnetic coupling. The electrochemistry of the dinuclear species is significantly different from the mononuclear systems: the latter show irreversible waves in cyclic voltammograms as a result of the need to couple proton and electron transfer. The dinuclear species, in contrast, show reversible waves, which are attributed to rapid intramolecular proton transfer facilitated by the hydrogen-bonded structure. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Minimal distances between SCFTs

    Energy Technology Data Exchange (ETDEWEB)

    Buican, Matthew [Department of Physics and Astronomy, Rutgers University,Piscataway, NJ 08854 (United States)

    2014-01-28

    We study lower bounds on the minimal distance in theory space between four-dimensional superconformal field theories (SCFTs) connected via broad classes of renormalization group (RG) flows preserving various amounts of supersymmetry (SUSY). For N=1 RG flows, the ultraviolet (UV) and infrared (IR) endpoints of the flow can be parametrically close. On the other hand, for RG flows emanating from a maximally supersymmetric SCFT, the distance to the IR theory cannot be arbitrarily small regardless of the amount of (non-trivial) SUSY preserved along the flow. The case of RG flows from N=2 UV SCFTs is more subtle. We argue that for RG flows preserving the full N=2 SUSY, there are various obstructions to finding examples with parametrically close UV and IR endpoints. Under reasonable assumptions, these obstructions include: unitarity, known bounds on the c central charge derived from associativity of the operator product expansion, and the central charge bounds of Hofman and Maldacena. On the other hand, for RG flows that break N=2→N=1, it is possible to find IR fixed points that are parametrically close to the UV ones. In this case, we argue that if the UV SCFT possesses a single stress tensor, then such RG flows excite of order all the degrees of freedom of the UV theory. Furthermore, if the UV theory has some flavor symmetry, we argue that the UV central charges should not be too large relative to certain parameters in the theory.

  16. Porcelain laminate veneer restorations bonded with a three-liquid silane bonding agent and a dual-activated luting composite.

    Science.gov (United States)

    Matsumura, Hideo; Aida, Yukiko; Ishikawa, Yumi; Tanoue, Naomi

    2006-12-01

    This clinical report describes the fabrication and bonding of porcelain laminate veneer restorations in a patient with anterior open spaces. Laminate veneer restorations made of feldspathic porcelain were etched with 5% hydrofluoric acid, rinsed under tap water, ultrasonically cleaned with methanol, and primed with a chemically activated three-liquid silane bonding agent (Clearfil Porcelain Bond). The enamel surfaces were etched with 40% phosphoric acid, rinsed with water, and primed with a two-liquid bonding agent (Clearfil New Bond) that contained a hydrophobic phosphate (10-methacryloyloxydecyl dihydrogen phosphate; MDP). The restorations were bonded with a dual-activated luting composite (Clapearl DC). The veneers have been functioning satisfactorily for an observation period of one year. Combined use of the Clearfil bonding agents and Clapearl DC luting composite is an alternative to conventional materials for seating porcelain laminate veneer restorations, although the system is inapplicable to dentin bonding.

  17. Hydrogen bonding in asphaltenes and coal liquids. Quarterly report, May 1, 1981-July 31, 1981. [Effects of phenols or anisole on aging of SRC blends

    Energy Technology Data Exchange (ETDEWEB)

    Li, N.C.; Jones, L.; Yaggi, N.F.

    1981-01-01

    Coal-derived liquids are very susceptible to oxidative degradation. Oxygen and temperature exert a dramatic effect on enhancing the viscosity of coal-derived fuels, and a free-radical mechanism is an obvious choice for the mechanism of this noted oxidative degradation. In the present study, several different phenols were added to blends consisting of two different ratios of SRC I and SRC II middle distillate: 20/80 and 30/70 by weight. The objective of this research is to study the effect of phenols on the aging of the SRC blends. It has been found that upon the addition of phenol itself, the original hydrogen bonding between the acidic and basic functional groups in the coal-derived liquids is apparently disrupted because the added phenol can now interact with the proton-accepting species in liquids, thus, leading to a lower viscosity. When anisole (which contains no hydroxyl group) is added instead of phenol, the effect of slowing down the aging process is much smaller. o-Phenylphenol is a hindered phenol, and the effect on the aging process is intermediate between anisole and phenol.

  18. Effect of solvent on proton location and dynamic behavior in short intramolecular hydrogen bonds studied by molecular dynamics simulations and NMR experiments

    Energy Technology Data Exchange (ETDEWEB)

    Mori, Yukie, E-mail: mori.yukie@ocha.ac.jp; Masuda, Yuichi

    2015-09-08

    Highlights: • MD simulations were performed to study dynamics of strong hydrogen bonds. • Nuclear magnetic relaxation times of proton were measured in solution. • The hydrogen bond of dibenzoylmethane enol is asymmetric in methanol solution. • Formation or breakage of intermolecular hydrogen bonds can trigger proton transfer. • Dimethylsulfoxide may form a bifurcated hydrogen bond with a hydrogen-bonded system. - Abstract: Hydrogen phthalate anion has a short strong O–H–O hydrogen bond (H-bond). According to previous experimental studies, the H-bond is asymmetric and two tautomers are interconverted in aqueous solutions. In the present study, the effects of polar solvents on the H-bond in a zwitterionic hydrogen phthalate derivative 1 were investigated by quantum mechanics/molecular mechanics molecular dynamics (MD) simulations. The analyses of the trajectories for the methanol solution showed that the H-bonding proton tends to be located closer to the carboxylate group that forms fewer intermolecular H-bonds, than to the other carboxylate group and that the intramolecular proton transfer in 1 is triggered by the breakage and/or formation of an intermolecular H-bond. The enol form of dibenzoylmethane (2) also has a short H-bond, and the OH bond is reported to be rather long (>1.1 Å) in the crystal. In the present study, the effects of the solvent on the H-bond in 2 were investigated by molecular orbital (MO) calculations, MD simulations and nuclear magnetic resonance (NMR) spectroscopy. Density functional theory (DFT) calculations for 2 in vacuum indicated that the barrier height for the intramolecular proton transfer is almost the same as the zero-point energy of the vibrational ground state, resulting in broad distribution of the proton density along the H-bond, owing to the nuclear quantum effect. The OH distances were determined in CCl{sub 4}, acetonitrile, and dimethylsulfoxide solutions from the magnetic dipolar interactions between the {sup 17

  19. Measurement of bonding energy in an anhydrous nitrogen atmosphere and its application to silicon direct bonding technology

    Science.gov (United States)

    Fournel, F.; Continni, L.; Morales, C.; Da Fonseca, J.; Moriceau, H.; Rieutord, F.; Barthelemy, A.; Radu, I.

    2012-05-01

    Bonding energy represents an important parameter for direct bonding applications as well as for the elaboration of physical mechanisms at bonding interfaces. Measurement of bonding energy using double cantilever beam (DCB) under prescribed displacement is the most used technique thanks to its simplicity. The measurements are typically done in standard atmosphere with relative humidity above 30%. Therefore, the obtained bonding energies are strongly impacted by the water stress corrosion at the bonding interfaces. This paper presents measurements of bonding energies of directly bonded silicon wafers under anhydrous nitrogen conditions in order to prevent the water stress corrosion effect. It is shown that the measurements under anhydrous nitrogen conditions (less than 0.2 ppm of water in nitrogen) lead to high stable debonding lengths under static load and to higher bonding energies compared to the values measured under standard ambient conditions. Moreover, the bonding energies of Si/SiO2 or SiO2/SiO2 bonding interfaces are measured overall the classical post bond annealing temperature range. These new results allow to revisit the reported bonding mechanisms and to highlight physical and chemical phenomena in the absence of stress corrosion effect.

  20. The Gould's Belt Distances Survey (GOBELINS) III. The distance to the Serpens/Aquila Molecular Complex

    CERN Document Server

    Ortiz-León, Gisela N; Kounkel, Marina A; Loinard, Laurent; Mioduszewski, Amy J; Rodríguez, Luis F; Torres, Rosa M; Pech, Gerardo; Rivera, Juana L; Hartmann, Lee; Boden, Andrew F; Evans, Neal J; Briceño, Cesar; Tobin, John J; Galli, Phillip A B

    2016-01-01

    We report on new distances and proper motions to seven stars across the Serpens/Aquila complex. The observations were obtained as part of the Gould's Belt Distances Survey (GOBELINS) project between September 2013 and April 2016 with the Very Long Baseline Array (VLBA). One of our targets is the proto-Herbig AeBe object EC 95, which is a binary system embedded in the Serpens Core. For this system, we combined the GOBELINS observations with previous VLBA data to cover a total period of ~8 years, and derive the orbital elements and an updated source distance. The individual distances to sources in the complex are fully consistent with each other, and the mean value corresponds to a distance of $436.0\\pm9.2$~pc for the Serpens/W40 complex. Given this new evidence, we argue that Serpens Main, W40 and Serpens South are physically associated and form a single cloud structure.

  1. Minimal model for dynamic bonding in colloidal transient networks

    Science.gov (United States)

    Krinninger, Philip; Fortini, Andrea; Schmidt, Matthias

    2016-04-01

    We investigate a model for colloidal network formation using Brownian dynamics computer simulations. Hysteretic springs establish transient bonds between particles with repulsive cores. If a bonded pair of particles is separated by a cutoff distance, the spring vanishes and reappears only if the two particles contact each other. We present results for the bond lifetime distribution and investigate the properties of the van Hove dynamical two-body correlation function. The model displays crossover from fluidlike dynamics, via transient network formation, to arrested quasistatic network behavior.

  2. A study of hydrogen-bond dynamics in carboxylic acids by NMR T1 measurements: isotope effects and hydrogen-bond length dependence

    Science.gov (United States)

    Agaki, T.; Imashiro, F.; Terao, T.; Hirota, N.; Hayashi, S.

    1987-08-01

    Proton (deuteron) transfer of hydrogen bonds in benzoic, glutaric and p-formylbenzoic acids was studied by proton (deuteron) T1 measurements. Deuteration of carboxylic protons was found to increase the barriers to classical proton jumping as well as quantum-mechanical tunneling. The former barriers increase as the hydrogen-bond distance increases.

  3. The Distance to M51

    CERN Document Server

    McQuinn, Kristen B W; Dolphin, Andrew E; Berg, Danielle; Kennicutt, Robert

    2016-01-01

    Great investments of observing time have been dedicated to the study of nearby spiral galaxies with diverse goals ranging from understanding the star formation process to characterizing their dark matter distributions. Accurate distances are fundamental to interpreting observations of these galaxies, yet many of the best studied nearby galaxies have distances based on methods with relatively large uncertainties. We have started a program to derive accurate distances to these galaxies. Here we measure the distance to M51 - the Whirlpool galaxy - from newly obtained Hubble Space Telescope optical imaging using the tip of the red giant branch method. We measure the distance modulus to be 8.58+/-0.10 Mpc (statistical), corresponding to a distance modulus of 29.67+/-0.02 mag. Our distance is an improvement over previous results as we use a well-calibrated, stable distance indicator, precision photometry in a optimally selected field of view, and a Bayesian Maximum Likelihood technique that reduces measurement unce...

  4. Handbook of wafer bonding

    CERN Document Server

    Ramm, Peter; Taklo, Maaike M V

    2011-01-01

    Written by an author and editor team from microsystems companies and industry-near research organizations, this handbook and reference presents dependable, first-hand information on bonding technologies.In the first part, researchers from companies and institutions around the world discuss the most reliable and reproducible technologies for the production of bonded wafers. The second part is devoted to current and emerging applications, including microresonators, biosensors and precise measuring devices.

  5. Improved directional-distance filter

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    This paper proposes a new spatial-distance weighting function.By combining the weighting function and the traditional directional-distance filter (DDF) in a novel way,a new vector filter-the adaptive distance-weighted directional-distance filter (ADWDDF)-is presented.The experimental results show that the proposed solution provides better filtering performance and preserves better image chromaticity and edge or detail information compared with the traditional DDF and some other typical vector filters.

  6. Isolation by distance, web service

    OpenAIRE

    Bohonak Andrew J; Jensen Jeffrey L; Kelley Scott T

    2005-01-01

    Abstract Background The population genetic pattern known as "isolation by distance" results from spatially limited gene flow and is a commonly observed phenomenon in natural populations. However, few software programs exist for estimating the degree of isolation by distance among populations, and they tend not to be user-friendly. Results We have created Isolation by Distance Web Service (IBDWS) a user-friendly web interface for determining patterns of isolation by distance. Using this site, ...

  7. Reconsidering Moore's Transactional Distance Theory

    Science.gov (United States)

    Giossos, Yiannis; Koutsouba, Maria; Lionarakis, Antonis; Skavantzos, Kosmas

    2009-01-01

    One of the core theories of distance education is Michael Graham Moore's "Theory of Transactional Distance" that provides the broad framework of the pedagogy of distance education and allows the generation of almost infinite number of hypotheses for research. However, the review of the existing studies relating to the theory showed the use of a…

  8. Description of a Distance-Dependant Road Pricing System

    DEFF Research Database (Denmark)

    Jensen, Peder; Kildebogaard, Jan

    1999-01-01

    The report describes the functional requirements of a distance dependant road pricing system. In addition it presents an implementation of these requirements in the form of a demonstration model.......The report describes the functional requirements of a distance dependant road pricing system. In addition it presents an implementation of these requirements in the form of a demonstration model....

  9. Distance Measurement Solves Astrophysical Mysteries

    Science.gov (United States)

    2003-08-01

    Location, location, and location. The old real-estate adage about what's really important proved applicable to astrophysics as astronomers used the sharp radio "vision" of the National Science Foundation's Very Long Baseline Array (VLBA) to pinpoint the distance to a pulsar. Their accurate distance measurement then resolved a dispute over the pulsar's birthplace, allowed the astronomers to determine the size of its neutron star and possibly solve a mystery about cosmic rays. "Getting an accurate distance to this pulsar gave us a real bonanza," said Walter Brisken, of the National Radio Astronomy Observatory (NRAO) in Socorro, NM. Monogem Ring The Monogem Ring, in X-Ray Image by ROSAT satellite CREDIT: Max-Planck Institute, American Astronomical Society (Click on Image for Larger Version) The pulsar, called PSR B0656+14, is in the constellation Gemini, and appears to be near the center of a circular supernova remnant that straddles Gemini and its neighboring constellation, Monoceros, and is thus called the Monogem Ring. Since pulsars are superdense, spinning neutron stars left over when a massive star explodes as a supernova, it was logical to assume that the Monogem Ring, the shell of debris from a supernova explosion, was the remnant of the blast that created the pulsar. However, astronomers using indirect methods of determining the distance to the pulsar had concluded that it was nearly 2500 light-years from Earth. On the other hand, the supernova remnant was determined to be only about 1000 light-years from Earth. It seemed unlikely that the two were related, but instead appeared nearby in the sky purely by a chance juxtaposition. Brisken and his colleagues used the VLBA to make precise measurements of the sky position of PSR B0656+14 from 2000 to 2002. They were able to detect the slight offset in the object's apparent position when viewed from opposite sides of Earth's orbit around the Sun. This effect, called parallax, provides a direct measurement of

  10. Chemical Bonding: The Orthogonal Valence-Bond View

    Directory of Open Access Journals (Sweden)

    Alexander F. Sax

    2015-04-01

    Full Text Available Chemical bonding is the stabilization of a molecular system by charge- and spin-reorganization processes in chemical reactions. These processes are said to be local, because the number of atoms involved is very small. With multi-configurational self-consistent field (MCSCF wave functions, these processes can be calculated, but the local information is hidden by the delocalized molecular orbitals (MO used to construct the wave functions. The transformation of such wave functions into valence bond (VB wave functions, which are based on localized orbitals, reveals the hidden information; this transformation is called a VB reading of MCSCF wave functions. The two-electron VB wave functions describing the Lewis electron pair that connects two atoms are frequently called covalent or neutral, suggesting that these wave functions describe an electronic situation where two electrons are never located at the same atom; such electronic situations and the wave functions describing them are called ionic. When the distance between two atoms decreases, however, every covalent VB wave function composed of non-orthogonal atomic orbitals changes its character from neutral to ionic. However, this change in the character of conventional VB wave functions is hidden by its mathematical form. Orthogonal VB wave functions composed of orthonormalized orbitals never change their character. When localized fragment orbitals are used instead of atomic orbitals, one can decide which local information is revealed and which remains hidden. In this paper, we analyze four chemical reactions by transforming the MCSCF wave functions into orthogonal VB wave functions; we show how the reactions are influenced by changing the atoms involved or by changing their local symmetry. Using orthogonal instead of non-orthogonal orbitals is not just a technical issue; it also changes the interpretation, revealing the properties of wave functions that remain otherwise undetected.

  11. Failure of dissimilar material bonded joints

    Science.gov (United States)

    Konstantakopoulou, M.; Deligianni, A.; Kotsikos, G.

    2016-03-01

    Joining of materials in structural design has always been a challenge for engineers. Bolting and riveting has been used for many years, until the emergence of fusion welding which revolutionised construction in areas such as shipbuilding, automotive, infrastructure and consumer goods. Extensive research in the past 50 years has resulted in better understanding of the process and minimised the occurrence of failures associated with fusion welding such as, residual stress cracking, stress corrosion and corrosion fatigue cracking, localised reduction in mechanical properties due to microstructural changes (heat affected zone) etc. Bonding has been a technique that has been proposed as an alternative because it eliminates several of the problems associated with fusion welding. But, despite some applications it has not seen wide use. There is however a renewed interest in adhesively bonded joints, as designers look for ever more efficient structures which inevitably leads to the use and consequently joining of combinations of lightweight materials, often with fundamentally different mechanical and physical properties. This chapter provides a review of adhesively bonded joints and reports on improvements to bonded joint strength through the introduction of carbon nanotubes at the bond interface. Results from various workers in the field are reported as well as the findings of the authors in this area of research. It is obvious that there are several challenges that need to be addressed to further enhance the strength of bonded joints and worldwide research is currently underway to address those shortcomings and build confidence in the implementation of these new techniques.

  12. Hydrolyzable polyureas bearing hindered urea bonds.

    Science.gov (United States)

    Ying, Hanze; Cheng, Jianjun

    2014-12-10

    Hydrolyzable polymers are widely used materials that have found numerous applications in biomedical, agricultural, plastic, and packaging industrials. They usually contain ester and other hydrolyzable bonds, such as anhydride, acetal, ketal, or imine, in their backbone structures. Here, we report the first design of hydrolyzable polyureas bearing dynamic hindered urea bonds (HUBs) that can reversibly dissociate to bulky amines and isocyanates, the latter of which can be further hydrolyzed by water, driving the equilibrium to facilitate the degradation of polyureas. Polyureas bearing 1-tert-butyl-1-ethylurea bonds that show high dynamicity (high bond dissociation rate), in the form of either linear polymers or cross-linked gels, can be completely degraded by water under mild conditions. Given the simplicity and low cost for the production of polyureas by simply mixing multifunctional bulky amines and isocyanates, the versatility of the structures, and the tunability of the degradation profiles of HUB-bearing polyureas, these materials are potentially of very broad applications.

  13. Keeping Your Distance is Hard

    OpenAIRE

    Burke, Kyle; Heubach, Silvia; Huggan, Melissa; Huntemann, Svenja

    2016-01-01

    We study the computational complexity of distance games, a class of combinatorial games played on graphs. A move consists of colouring an uncoloured vertex subject to it not being at certain distances determined by two sets, D and S. D is the set of forbidden distances for colouring vertices in different colors, while S is the set of forbidden distances for the same colour. The last player to move wins. Well-known examples of distance games are Node-Kayles, Snort, and Col, whose complexities ...

  14. Distance learning and perioperative nursing.

    Science.gov (United States)

    Gruendemann, Barbara J

    2007-03-01

    Distance learning in nursing education is arriving with unprecedented speed, which has led to much uncertainty among educators. This article provides an overview of distance learning and its application to perioperative nursing. Lack of face-to-face interaction is of foremost concern in distance learning, and educators must develop new teaching strategies to address this problem. Models for assessing outcomes and effectiveness are important tools to use when implementing a distance learning program. Basic perioperative nursing concepts, skills, procedures, and recommended practices can be introduced effectively with online distance learning modalities and then reinforced through a clinical component.

  15. Supporting Distance Learners: Making Practice More Effective

    Science.gov (United States)

    Pratt, Keryn

    2015-01-01

    This paper reports on a qualitative evaluation of the postgraduate courses offered by distance in one university department. The types and amount of support provided to students was evaluated and compared with Simpson's (2008a) Proactive Motivational Support model (PaMS). While students were largely satisfied with the support they received during…

  16. New distances to RAVE stars

    CERN Document Server

    Binney, James; Kordopatis, Georges; McMillan, Paul J; Sharma, Sanjib; Zwitter, Tomaz; Bienayme, Olivier; Bland-Hawthorn, Joss; Steinmetz, Matthias; Gilmore, Gerry; Williams, Mary E K; Navarro, Julio; Grebel, Eva K; Helmi, Amina; Parker, Quentin; Reid, Warren A; Seabroke, George; Watson, Fred; Wyse, Rosie F G

    2013-01-01

    Probability density functions are determined from new stellar parameters for the distance moduli of stars for which the RAdial Velocity Experiment (RAVE) has obtained spectra with S/N>=10. The expectation value of distance is larger than the distance implied by the expectation of distance modulus; the latter is itself larger than the distance implied by the expectation value of the parallax. Our parallaxes of Hipparcos stars agree well with the values measured by Hipparcos, so the expectation of parallax is the most reliable distance indicator. The latter are improved by taking extinction into account. We provide one- two- or three-Gaussian fits to the distance pdfs. The effective temperature absolute-magnitude diagram of our stars is significantly improved when these pdfs are used to make the diagram. We use the method of kinematic corrections devised by Schoenrich, Binney & Asplund to check for systematic errors in our estimators for ordinary stars and confirm the conclusion reached from the Hipparcos s...

  17. Modelling longevity bonds: Analysing the Swiss Re Kortis bond

    OpenAIRE

    2015-01-01

    A key contribution to the development of the traded market for longevity risk was the issuance of the Kortis bond, the world's first longevity trend bond, by Swiss Re in 2010. We analyse the design of the Kortis bond, develop suitable mortality models to analyse its payoff and discuss the key risk factors for the bond. We also investigate how the design of the Kortis bond can be adapted and extended to further develop the market for longevity risk.

  18. Fundamentals of fiber bonding in thermally point-bonded nonwovens

    Science.gov (United States)

    Chidambaram, Aparna

    Thermal point bonding (TPB) uses heat and pressure to bond a web of fibers at discrete points imparting strength to the manufactured fabric. This process significantly reduces the strength and elongation of the bridging fibers between bond points while strengthening the web. Single fiber experiments were performed with four structurally different polypropylene fibers to analyze the inter-relationships between fiber structure, fiber properties and bonding process. Two fiber types had a low birefringence sheath or surface layer while the remaining had uniform birefringence profiles through their thickness. Bonds were formed between isolated pairs of fibers by subjecting the fibers to a calendering process and simulating TPB process conditions. The dependence of bond strength on bonding temperature and on the type of fiber used was evaluated. Fiber strengths before and after bonding were measured and compared to understand the effect of bonding on fiber strength. Additionally, bonded fiber strength was compared to the strength of single fibers which had experienced the same process conditions as the bonded pairs. This comparison estimated the effect of mechanical damage from pressing fibers together with steel rolls while creating bonds in TPB. Interfiber bond strength increased with bonding temperature for all fiber types. Fiber strength decreased with increasing bonding temperature for all fiber types except for one type of low birefringent sheath fibers. Fiber strength degradation was unavoidable at temperatures required for successful bonding. Mechanical damage from compression of fibers between rolls was an insignificant factor in this strength loss. Thermal damage during bonding was the sole significant contributor to fiber strength degradation. Fibers with low birefringence skins formed strong bonds with minimal fiber strength loss and were superior to fibers without such surface layers in TPB performance. A simple model to predict the behavior of a two-bond

  19. Unified description of hydrogen bonding by a two-state effective Hamiltonian

    CERN Document Server

    McKenzie, Ross H

    2011-01-01

    An effective Hamiltonian is considered for hydrogen bonding between two molecules due to the quantum mechanical interaction between the orbitals of the H-atom and the donor and acceptor atoms in the molecules. The Hamiltonian acts on two diabatic states and has a simple chemically motivated form for its matrix elements. The model gives insight into the "H-bond puzzle", describes different classes of bonds, and empirical correlations between the donor-acceptor distance $R$ and binding energies, bond lengths, and the softening of vibrational frequencies. A key prediction is the UV photo-dissociation of H-bonded complexes via an excited electronic state with an exalted vibrational frequency.

  20. Behavior of oxide at diffusion-bonded interface of Al-Mg-Si series 6063 alloy. 1st Report. Diffusion-bonding mechanism of aluminium alloys by transmission electron microscopy; Al-Mg-Si kei 6063 gokin no kakusan setsugo kaimen ni okeru sankabutsu no kyodo. 1. Toka denshi kenbikyo kansatsu ni yoru Al gokin no kakusan setsugo kiko no kento

    Energy Technology Data Exchange (ETDEWEB)

    Ikeuchi, K.; Matsuda, F. [Osaka University, Osaka (Japan). Welding Research Institute; Kotani, K. [Industrial Research Institute of Aichi Prefecture, Aichi (Japan)

    1996-02-05

    Transmission electron microscopic observation and a joint strength test were carried out on diffusion-bonded interface of Al-Mg-Si series 6063 alloy to investigate behavior of the surface oxide film and its effect on the bonding strength. The test pieces are made of the Al-Mg-Si series 6063 alloy and industrial pure aluminum 1080 cut out from a rod as a reference material. The bonded surface was applied with electrolytic grinding or wire brush finish. Analysis of electron diffraction diagram revealed formation of Al2MgO4 on the bonded interface of the 6063 alloy in either case of the electrolytic grinding or the wire brush finish. However, it was not possible to derive the electron diffraction diagram from oxide film on the bonded interface of pure aluminum, and the oxide film was thought amorphous. Tensile strength of the diffusion-bonded joint of the 6063 alloy approached the strength of the base material at considerably lower bonding temperature and with smaller bonding deformation than in pure aluminum in either case of the bonded surface electrolytically ground or wire-brush finished. This was thought to have been caused from difference in behavior of the oxide film. 16 refs., 12 figs., 3 tabs.

  1. Fast computation of distance estimators

    Directory of Open Access Journals (Sweden)

    Lagergren Jens

    2007-03-01

    Full Text Available Abstract Background Some distance methods are among the most commonly used methods for reconstructing phylogenetic trees from sequence data. The input to a distance method is a distance matrix, containing estimated pairwise distances between all pairs of taxa. Distance methods themselves are often fast, e.g., the famous and popular Neighbor Joining (NJ algorithm reconstructs a phylogeny of n taxa in time O(n3. Unfortunately, the fastest practical algorithms known for Computing the distance matrix, from n sequences of length l, takes time proportional to l·n2. Since the sequence length typically is much larger than the number of taxa, the distance estimation is the bottleneck in phylogeny reconstruction. This bottleneck is especially apparent in reconstruction of large phylogenies or in applications where many trees have to be reconstructed, e.g., bootstrapping and genome wide applications. Results We give an advanced algorithm for Computing the number of mutational events between DNA sequences which is significantly faster than both Phylip and Paup. Moreover, we give a new method for estimating pairwise distances between sequences which contain ambiguity Symbols. This new method is shown to be more accurate as well as faster than earlier methods. Conclusion Our novel algorithm for Computing distance estimators provides a valuable tool in phylogeny reconstruction. Since the running time of our distance estimation algorithm is comparable to that of most distance methods, the previous bottleneck is removed. All distance methods, such as NJ, require a distance matrix as input and, hence, our novel algorithm significantly improves the overall running time of all distance methods. In particular, we show for real world biological applications how the running time of phylogeny reconstruction using NJ is improved from a matter of hours to a matter of seconds.

  2. Catalytic applications of mono- and dinuclear complexes containing metal-carbon sigma bonds. Final report, November 1, 1993--October 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Norton, J.R.

    1996-12-31

    This report discusses results from several studies involved in the project. Investigations include: vibrational models for surface olefins and alkylidenes; mechanism of the formation and fragmentation of diosmacyclobutanes; reaction of dienes and allenes with diosmacyclobutanes; determination by nematic phase NMR of the structure of mononuclear and dinuclear ethylene complexes of osmium; and generation of ``coordinatively unsaturated`` complexes by protonation of methyl osmium complexes.

  3. Romanian government bond market

    Directory of Open Access Journals (Sweden)

    Cornelia POP

    2012-12-01

    Full Text Available The present paper aims to present the level of development reached by Romanian government bond market segment, as part of the country financial market. The analysis will be descriptive (the data series available for Romania are short, based on the secondary data offered by the official bodies involved in the process of issuing and trading the Romanian government bonds (Romanian Ministry of Public Finance, Romanian National Bank and Bucharest Stock Exchange, and also on secondary data provided by the Federation of European Stock Exchanges.To enhance the market credibility as a benchmark, a various combination of measures is necessary; among these measures are mentioned: the extension of the yield curve; the issuance calendars in order to improve transparency; increasing the disclosure of information on public debt issuance and statistics; holding regular meetings with dealers, institutional investors and rating agencies; introducing a system of primary dealers; establishing a repurchase (repo market in the government bond market. These measures will be discussed based on the evolution presented inside the paper.The paper conclude with the fact that, until now, the Romanian government bond market did not provide a benchmark for the domestic financial market and that further efforts are needed in order to increase the government bond market transparency and liquidity.

  4. Safe and Liquid Mortgage Bonds

    DEFF Research Database (Denmark)

    Dick-Nielsen, Jens; Gyntelberg, Jacob; Lund, Jesper

    This paper shows that strict match pass-through funding of covered bonds provides safe and liquid mortgage bonds. Despite a 30% drop in house prices during the 2008 global crisis Danish mortgage bonds remained as liquid as most European government bonds. The Danish pass-through system effectively...... eliminates credit risk from the investor's perspective. Similar to other safe bonds, funding liquidity becomes the main driver of mortgage bond liquidity and this creates commonality in liquidity across markets and countries. These findings have implications for how to design a robust mortgage bond system...

  5. Safe and Liquid Mortgage Bonds

    DEFF Research Database (Denmark)

    Dick-Nielsen, Jens; Gyntelberg, Jacob; Lund, Jesper

    This paper shows that strict match pass-through funding of covered bonds provides safe and liquid mortgage bonds. Despite a 30% drop in house prices during the 2008 global crisis Danish mortgage bonds remained as liquid as most European government bonds. The Danish pass-through system effectively...... eliminates credit risk from the investor's perspective. Similar to other safe bonds, funding liquidity becomes the main driver of mortgage bond liquidity and this creates commonality in liquidity across markets and countries. These findings have implications for how to design a robust mortgage bond system...

  6. Planning with Reachable Distances

    KAUST Repository

    Tang, Xinyu

    2009-01-01

    Motion planning for spatially constrained robots is difficult due to additional constraints placed on the robot, such as closure constraints for closed chains or requirements on end effector placement for articulated linkages. It is usually computationally too expensive to apply sampling-based planners to these problems since it is difficult to generate valid configurations. We overcome this challenge by redefining the robot\\'s degrees of freedom and constraints into a new set of parameters, called reachable distance space (RD-space), in which all configurations lie in the set of constraint-satisfying subspaces. This enables us to directly sample the constrained subspaces with complexity linear in the robot\\'s number of degrees of freedom. In addition to supporting efficient sampling, we show that the RD-space formulation naturally supports planning, and in particular, we design a local planner suitable for use by sampling-based planners. We demonstrate the effectiveness and efficiency of our approach for several systems including closed chain planning with multiple loops, restricted end effector sampling, and on-line planning for drawing/sculpting. We can sample single-loop closed chain systems with 1000 links in time comparable to open chain sampling, and we can generate samples for 1000-link multi-loop systems of varying topology in less than a second. © 2009 Springer-Verlag.

  7. Strength and leak testing of plasma activated bonded interfaces

    DEFF Research Database (Denmark)

    Visser, M.M.; Weichel, Steen; Reus, Roger De

    2002-01-01

    Bond strength and hermeticity of plasma activated bonded (PAB) Si-Si interfaces are reported. Bonding of 100 mm Si(1 0 0) wafers was performed. An average bond strength of 9.0+/-3.9 MPa was achieved without performing any annealing steps. Cavities bonded in vacuum were found to be hermetic based...... on detection of changes in membrane deflections. The detection limit for leak was 8E-13 mbar l/s. For comparison, strength and leak tests were also performed with regular fusion bonded wafers annealed at 1100 degreesC. The PAB was found to withstand post-processing steps such as RCA cleaning, 24 h in de......-ionised water (DIW), 24 h in 2.5% HF, 24 h in acetone and 60 s in a resist developer. By analysing the thin silicon oxide present on the surfaces to be bonded with optical methods, the influence of pre-cleaning and activation process parameters was investigated....

  8. Explorations in Physics and Distance Learning

    Science.gov (United States)

    Caviness, Kenneth

    2010-02-01

    How can the activity-based directed inquiry model be applied in a distance learning class? Lessons learned during a two-year pilot program (2007-2009) using the ``Explorations in Physics'' curriculum (David P. Jackson, Priscilla W. Laws, Scott V. Franklin) for a class taught over the internet using VCAM technology. The author reports on the successes, difficulties and surprises of teaching an exploratory physics class at a distance, where teacher-student interaction occurred via high-definition camera and big screen, two-way sight and sound carried by high-speed internet. )

  9. Distance learning for similarity estimation.

    Science.gov (United States)

    Yu, Jie; Amores, Jaume; Sebe, Nicu; Radeva, Petia; Tian, Qi

    2008-03-01

    In this paper, we present a general guideline to find a better distance measure for similarity estimation based on statistical analysis of distribution models and distance functions. A new set of distance measures are derived from the harmonic distance, the geometric distance, and their generalized variants according to the Maximum Likelihood theory. These measures can provide a more accurate feature model than the classical Euclidean and Manhattan distances. We also find that the feature elements are often from heterogeneous sources that may have different influence on similarity estimation. Therefore, the assumption of single isotropic distribution model is often inappropriate. To alleviate this problem, we use a boosted distance measure framework that finds multiple distance measures which fit the distribution of selected feature elements best for accurate similarity estimation. The new distance measures for similarity estimation are tested on two applications: stereo matching and motion tracking in video sequences. The performance of boosted distance measure is further evaluated on several benchmark data sets from the UCI repository and two image retrieval applications. In all the experiments, robust results are obtained based on the proposed methods.

  10. Reliability of flip-chip bonded RFID die using anisotropic conductive paste hybrid material

    Institute of Scientific and Technical Information of China (English)

    Jun-Sik LEE; Jun-Ki KIM; Mok-Soon KIM; Namhyun KANG; Jong-Hyun LEE

    2011-01-01

    A reliability of flip-chip bonded die as a function of anisotropic conductive paste (ACP) hybrid materials. bonding conditions, and antenna pattern materials was investigated during the assembly of radio frequency identification(RFID) inlay. The optimization condition for flip-chip bonding was determined from the behavior of bonding strength. Under the optimized condition,the shear strength for the antenna printed with paste-type Ag ink was larger than that for Cu antenna. Furthermore, an identification distance was varied from the antenna materials. Comparing with the Ag antenna pattern, the as-bonded die on Cu antenna showed a larger distance of identification, However, the long-term reliability of inlay using the Cu antenna was decreased significantly as a function of aging time at room temperature because of the bended shape of Cu antenna formed during the flip-chip bonding process.

  11. Stellar twins measure the distance of the Pleiades

    CERN Document Server

    Mädler, Thomas; Gilmore, Gerard; Worley, C Clare; Soubiran, Caroline; Blanco-Cuaresma, Sergi; Hawkins, Keith; Casey, Andrew R

    2016-01-01

    Since the release of the Hipparcos catalog in 1997, the distance to the Pleiades open cluster has been heavily debated. The distance obtained from Hipparcos and those by alternative methods differ by 10 to 15 %. As accurate stellar distances are key to understanding stellar structure and evolution, this dilemma puts the validity of stellar evolution models into question. Using our model-independent method to determine distances based on twin stars, we report individual distance estimates of 15 FGK type stars in the Pleiades in anticipation of the astrometric mission Gaia. Their averaged distances result in a cluster distance of ${ 134.8\\pm 1.7~\\mathrm{pc}}$. This value agrees with the current results obtained from stellar evolution models.

  12. Delicate balance of hydrogen bonding forces in D-threoninol.

    Science.gov (United States)

    Vaquero-Vara, Vanesa; Zhang, Di; Dian, Brian C; Pratt, David W; Zwier, Timothy S

    2014-09-01

    The seven most stable conformers of D-threoninol (2(S)-amino-1,3(S)-butanediol), a template used for the synthesis of artificial nucleic acids, have been identified and characterized from their pure rotational transitions in the gas phase using chirped-pulse Fourier transform microwave spectroscopy. D-Threoninol is a close analogue of glycerol, differing by substitution of an NH2 group for OH on the C(β) carbon and by the presence of a terminal CH3 group that breaks the symmetry of the carbon framework. Of the seven observed structures, two are H-bonded cycles containing three H-bonds that differ in the direction of the H-bonds in the cycle. The other five are H-bonded chains containing OH···NH···OH H-bonds with different directions along the carbon framework and different dihedral angles along the chain. The two structural types (cycles and chains of H-bonds) are in surprisingly close energetic proximity. Comparison of the rotational constants with the calculated structures at the MP2/6-311++G(d,p) level of theory reveals systematic changes in the H-bond distances that reflect NH2 as a better H-bond acceptor and poorer donor, shrinking the H-bond distances by ∼0.2 Å in the former case and lengthening them by a corresponding amount in the latter. Thus revealed is the subtle effect of asymmetric substitution on the energy landscape of a simple molecule, likely to be important in living systems.

  13. The Trouble With Bonds

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    @@ In early June,global financial markets gyrated downwards in the wake of central banks'tough language on inflation.At one point bond prices reflected expectations of four rate hikes by the US Federal Reserve (Fed) in the next 12 months.As a result,the dollar firmed,oil prices stabilized,and yield curves flattened around the world.If all these inflation-fighting measures are real,the situation bodes well for bonds.But,I think otherwise.

  14. Anodic bonded graphene

    Science.gov (United States)

    Balan, Adrian; Kumar, Rakesh; Boukhicha, Mohamed; Beyssac, Olivier; Bouillard, Jean-Claude; Taverna, Dario; Sacks, William; Marangolo, Massimiliano; Lacaze, Emanuelle; Gohler, Roger; Escoffier, Walter; Poumirol, Jean-Marie; Shukla, Abhay

    2010-09-01

    We show how to prepare graphene samples on a glass substrate with the anodic bonding method. In this method, a graphite precursor in flake form is bonded to a glass substrate with the help of an electrostatic field and then cleaved off to leave few layer graphene on the substrate. Now that several methods are available for producing graphene, the relevance of our method is in its simplicity and practicality for producing graphene samples of about 100 µm lateral dimensions. This method is also extensible to other layered materials. We discuss some detailed aspects of the fabrication and results from Raman spectroscopy, local probe microscopy and transport measurements on these samples.

  15. Anodic bonded graphene

    Energy Technology Data Exchange (ETDEWEB)

    Balan, Adrian; Kumar, Rakesh; Boukhicha, Mohamed; Beyssac, Olivier; Bouillard, Jean-Claude; Taverna, Dario; Sacks, William; Shukla, Abhay [Universite Pierre et Marie Curie-Paris 6, CNRS-UMR7590, Institut de Mineralogie et de Physique des Milieux Condenses, 140 rue de Lourmel, Paris, F-75015 France (France); Marangolo, Massimiliano; Lacaze, Emanuelle; Gohler, Roger [Universite Pierre et Marie Curie-Paris 6, CNRS-UMR7588, Institut des Nanosciences de Paris, 140 rue de Lourmel, Paris, F-75015 France (France); Escoffier, Walter; Poumirol, Jean-Marie, E-mail: abhay.shukla@upmc.f [Laboratoire National des Champs Magnetiques Intenses, INSA UPS CNRS, UPR 3228, Universite de Toulouse, 143 avenue de Rangueil, 31400 Toulouse (France)

    2010-09-22

    We show how to prepare graphene samples on a glass substrate with the anodic bonding method. In this method, a graphite precursor in flake form is bonded to a glass substrate with the help of an electrostatic field and then cleaved off to leave few layer graphene on the substrate. Now that several methods are available for producing graphene, the relevance of our method is in its simplicity and practicality for producing graphene samples of about 100 {mu}m lateral dimensions. This method is also extensible to other layered materials. We discuss some detailed aspects of the fabrication and results from Raman spectroscopy, local probe microscopy and transport measurements on these samples.

  16. Hydrogen bonded supramolecular materials

    CERN Document Server

    Li, Zhan-Ting

    2015-01-01

    This book is an up-to-date text covering topics in utilizing hydrogen bonding for constructing functional architectures and supramolecular materials. The first chapter addresses the control of photo-induced electron and energy transfer. The second chapter summarizes the formation of nano-porous materials. The following two chapters introduce self-assembled gels, many of which exhibit unique functions. Other chapters cover the advances in supramolecular liquid crystals and the versatility of hydrogen bonding in tuning/improving the properties and performance of materials. This book is designed

  17. Giant Sparks at Cosmological Distances?

    CERN Document Server

    Kulkarni, S R; Neill, J D; Zheng, Z; Juric, M

    2014-01-01

    [Abridged] Millisecond duration bright radio pulses in the 1.4-GHz band and with inferred dispersion measures (DM) well in excess of Galactic values have been reported by Lorimer et al. and Thornton et al.. The all-sky rate of these events is large, ~10^4 per day above ~1 Jy. To add to the mystery there now exists "Perytons'' -- also pulsed and dispersed sources but most certainly of local (artificial or atmospheric) origin. The suggested models now range from sources originating in the Earth's atmosphere, in stellar coronae, in other galaxies and at even cosmological distances. Using a series of physically motivated assumptions combined with the observed properties of these bursts, we explore possible constraints on sites or processes that can account for such high DMs. In our analysis, we focus on the first such reported event by Lorimer et al.: a 30 Jy, 5-ms duration burst with a dispersion measure of 375 cm^-3 pc and exhibiting a steep frequency-dependent pulse width (hereafter dubbed as the Sparker). Ass...

  18. Scenario Crisis Cases in Distance Learning Sessions

    Science.gov (United States)

    Antunes, A.

    2013-04-01

    We discuss early results using student-lead role-play of crises and disaster scenarios to encourage engagement in distance learning sessions. The disadvantage of distance learning via web interface—the lack of face-to-face and the ease with which a student can remain quiet—is balanced by the wealth of Internet-accessible media reports of past mission disasters. Capitol College minimizes the lecture component to simply frame each session's open-ended crisis in our Mission Operations engineering course. The students are presented with a historical ‘disaster’ but not its resolution; they present their course of action, then the lecturer steps in to debrief. With a wealth of past cases available on the web, use of scenarios rather than lectures shows early signs of being viable model for encouraging discussion and interaction within distance learning for a variety of course topics.

  19. On the bonding and the electric field gradient of the uranyl ion

    NARCIS (Netherlands)

    de Jong, WA; Visscher, L; Nieuwpoort, WC

    1999-01-01

    Molecular properties of the uranyl ion ([UO2](2+)) are studied using both a non-relativistic and a relativistic method. Inclusion of relativity leads to a bond length expansion and makes the electric field gradient (EFG) at the uranium nucleus strongly dependent on the U-O bond distance, The non-rel

  20. Hydrogen bond and halogen bond inside the carbon nanotube

    Science.gov (United States)

    Wang, Weizhou; Wang, Donglai; Zhang, Yu; Ji, Baoming; Tian, Anmin

    2011-02-01

    The hydrogen bond and halogen bond inside the open-ended single-walled carbon nanotubes have been investigated theoretically employing the newly developed density functional M06 with the suitable basis set and the natural bond orbital analysis. Comparing with the hydrogen or halogen bond in the gas phase, we find that the strength of the hydrogen or halogen bond inside the carbon nanotube will become weaker if there is a larger intramolecular electron-density transfer from the electron-rich region of the hydrogen or halogen atom donor to the antibonding orbital of the X-H or X-Hal bond involved in the formation of the hydrogen or halogen bond and will become stronger if there is a larger intermolecular electron-density transfer from the electron-rich region of the hydrogen or halogen atom acceptor to the antibonding orbital of the X-H or X-Hal bond. According to the analysis of the molecular electrostatic potential of the carbon nanotube, the driving force for the electron-density transfer is found to be the negative electric field formed in the carbon nanotube inner phase. Our results also show that the X-H bond involved in the formation of the hydrogen bond and the X-Hal bond involved in the formation of the halogen bond are all elongated when encapsulating the hydrogen bond and halogen bond within the carbon nanotube, so the carbon nanotube confinement may change the blue-shifting hydrogen bond and the blue-shifting halogen bond into the red-shifting hydrogen bond and the red-shifting halogen bond. The possibility to replace the all electron nanotube-confined calculation by the simple polarizable continuum model is also evaluated.

  1. Molecular model with quantum mechanical bonding information.

    Science.gov (United States)

    Bohórquez, Hugo J; Boyd, Russell J; Matta, Chérif F

    2011-11-17

    The molecular structure can be defined quantum mechanically thanks to the theory of atoms in molecules. Here, we report a new molecular model that reflects quantum mechanical properties of the chemical bonds. This graphical representation of molecules is based on the topology of the electron density at the critical points. The eigenvalues of the Hessian are used for depicting the critical points three-dimensionally. The bond path linking two atoms has a thickness that is proportional to the electron density at the bond critical point. The nuclei are represented according to the experimentally determined atomic radii. The resulting molecular structures are similar to the traditional ball and stick ones, with the difference that in this model each object included in the plot provides topological information about the atoms and bonding interactions. As a result, the character and intensity of any given interatomic interaction can be identified by visual inspection, including the noncovalent ones. Because similar bonding interactions have similar plots, this tool permits the visualization of chemical bond transferability, revealing the presence of functional groups in large molecules.

  2. Clinical effectiveness of contemporary dentin bonding agents

    Science.gov (United States)

    Krithikadatta, Jogikalmat

    2010-01-01

    Aim: The purpose of this paper is to review the literature on the clinical effectiveness of contemporary resin-based dentin bonding agents primarily focussing on the longevity of restoration. Materials and Methods: The literature published from June 2004 up to September 2010 was reviewed for clinical trials that tested the effectiveness of dentin bonding agents in the longevity of noncarious class V restoration. Results of each study reported using the USPHS criteria for clinical assessment of restoration were included and tabulated. The American Dental Association guidelines for dentin and enamel adhesives were used as a reference to compare the performance of individual bonding agents. Kruskal–Wallis followed by Mann–Whitney U was done to compare the mean Alfa score percentage for the three categories of bonding systems [etch-and-rinse (ER), self-etch primer (SEP), and self-etch-adhesive (SEA)]. Results: A comparison of the mean Alfa score percentages revealed no difference between the ER, SEP, and SEA categories of bonding systems except for marginal adaptation where ER was found to be superior to SEA. Conclusion: The clinical effectiveness of resin-based bonding agents is comparable among the three categories. PMID:21217944

  3. Novel approach to the concept of bond-valence vectors.

    Science.gov (United States)

    Zachara, Janusz

    2007-11-12

    A new approach to the old idea of deriving a bond-valence vector from the well-known bond-valence concept has been proposed. The foundation of the proposal is the previous electrostatic model in which bond valences are interpreted as electric fluxes. The outcome of this approach is actual vectorial quantities whose magnitudes are strictly but nonlinearly related to the scalar bond valences and are directed along the bond lines. It has been proved that the sum of all these bond-valence vectors drawn from a coordination center to its ligating atoms will be close to zero for the complete coordination sphere. Therefore, unlike the scalar bond valences, the obtained vectors provide information about the spatial arrangement of ligands. The geometrical consequences of the proposed bond-valence vector (BVV) model are analyzed for the geometries of the carbonates, phosphates, and five-coordinated organoaluminum compounds with CO3, PO4, and AlCO4 skeletons, respectively, retrieved from the Cambridge Structural Database. For acyclic carbonates this BVV model allows one to predict the O-C-O angles with a mean absolute error of 1.0 degrees using the empirical C-O distances only. Furthermore, this BVV model is able to quantitatively describe the strains in cyclic carbonates. The preliminary studies for NO2E, PO3E, and SO3E systems with a strongly stereoactive lone electron pair (E) show that the model may serve as a quantitative description of the lone electron pair effect on the coordination sphere. A great advantage of the presented BVV approach is that the derived relation between a bond-valence vector, bond valence, and bond length is given by an uncomplicated equation allowing quick and simple computations, thus providing a new analytical tool for describing the geometry of a coordination sphere that may be applied for structure validation.

  4. Hydrogen bonds in concreto and in computro

    Science.gov (United States)

    Stouten, Pieter F. W.; Kroon, Jan

    1988-07-01

    Molecular dynamics simulations of liquid water and liquid methanol have been carried out. For both liquids an effective pair potential was used. The models were fitted to the heat of vaporization, pressure and various radial distribution functions resulting from diffraction experiments on liquids. In both simulations 216 molecules were put in a cubic periodical ☐. The system was loosely coupled to a temperature bath and to a pressure bath. Following an initial equilibration period relevant data were sampled during 15 ps. The distributions of oxygen—oxygen distances in hydrogen bonds obtained from the two simulations are essentially the same. The distribution obtained from crystal data is somewhat different: the maximum has about the same position, but the curve is much narrower, which can be expected merely from the fact that diffraction experiments only supply average atomic positions and hence average interatomic distances. When thermal motion is taken into account a closer likeness is observed.

  5. On distances between phylogenetic trees

    Energy Technology Data Exchange (ETDEWEB)

    DasGupta, B. [Rutgers Univ., Camden, NJ (United States); He, X. [SUNY, Buffalo, NY (United States); Jiang, T. [McMaster Univ., Hamilton, Ontario (Canada)] [and others

    1997-06-01

    Different phylogenetic trees for the same group of species are often produced either by procedures that use diverse optimality criteria or from different genes in the study of molecular evolution. Comparing these trees to find their similarities and dissimilarities, i.e. distance, is thus an important issue in computational molecular biology. The nearest neighbor interchange distance and the subtree-transfer distance are two major distance metrics that have been proposed and extensively studied for different reasons. Despite their many appealing aspects such as simplicity and sensitivity to tree topologies, computing these distances has remained very challenging. This article studies the complexity and efficient approximation algorithms for computing the nni distance and a natural extension of the subtree-transfer distance, called the linear-cost subtree-transfer distance. The linear-cost subtree-transfer model is more logical than the subtree-transfer model and in fact coincides with the nni model under certain conditions. The following results have been obtained as part of our project of building a comprehensive software package for computing distances between phylogenies. (1) Computing the nni distance is NP-complete. This solves a 25 year old open question appearing again and again in, for example, under the complexity-theoretic assumption of P {ne} NP. We also answer an open question regarding the nni distance between unlabeled trees for which an erroneous proof appeared in. We give an algorithm to compute the optimal nni sequence in time O(n{sup 2} logn + n {circ} 2{sup O(d)}), where the nni distance is at most d. (2) Biological applications require us to extend the nni and linear-cost subtree-transfer models to weighted phylogenies, where edge weights indicate the length of evolution along each edge. We present a logarithmic ratio approximation algorithm for nni and a ratio 2 approximation algorithm for linear-cost subtree-transfer, on weighted trees.

  6. DISTANCE EDUCATOR: A Multiskill Personality

    Directory of Open Access Journals (Sweden)

    Sangeeta MALIK

    2013-01-01

    Full Text Available When we talk about a distance educator and a conventional educator the difference we found nd about both of them is that, a distance educator needs to play multiple roles as compared to a conventional educator. They require more skills and knowledge cater to the needs of the learner. In this article we will cover all the responsible areas of a distance educator & why we should consider them as a multiskill personality?

  7. Shear bond strength of the Tenure Solution dentin bonding system.

    Science.gov (United States)

    Barkmeier, W W; Cooley, R L

    1989-10-01

    A liquid solution of an oxalate bonding system containing NTG-GMA and PMDM has become commercially available. The bond strength of this oxalate adhesive (Tenure Solution) to dentin was determined by bonding composite resin cylinders to extracted teeth. The bond strengths obtained in this study are compared to the bond strengths obtained in earlier studies with the first and second generation oxalate adhesives whose components were supplied as powders and required mixing. The oxalate solutions developed significantly higher bond strengths than the original powder type systems.

  8. Doctoral education from a distance.

    Science.gov (United States)

    Effken, Judith A

    2008-12-01

    This article describes the environmental factors that have contributed to the recent rapid growth of nursing doctoral education at a distance. Early and recent efforts to deliver distance doctoral education are discussed, using The University of Arizona College of Nursing experience as the key exemplar. The Community of Inquiry model is introduced as an appropriate model for doctoral education and then used as a framework to evaluate the current state of the art in distance doctoral nursing education. Successes and challenges in delivering doctoral education from a distance are described.

  9. The Extended Edit Distance Metric

    CERN Document Server

    Fuad, Muhammad Marwan Muhammad

    2007-01-01

    Similarity search is an important problem in information retrieval. This similarity is based on a distance. Symbolic representation of time series has attracted many researchers recently, since it reduces the dimensionality of these high dimensional data objects. We propose a new distance metric that is applied to symbolic data objects and we test it on time series data bases in a classification task. We compare it to other distances that are well known in the literature for symbolic data objects. We also prove, mathematically, that our distance is metric.

  10. Maternal Effects on Anogenital Distance in a Wild Marmot Population

    OpenAIRE

    Fouqueray, Timothée D.; Daniel T. Blumstein; Raquel Monclús; Martin, Julien G. A.

    2014-01-01

    In mammals, prenatal exposure to sex steroid hormones may have profound effects on later behavior and fitness and have been reported under both laboratory and field conditions. Anogenital distance is a non-invasive measure of prenatal exposure to sex steroid hormones. While we know that intra-uterine position and litter sex ratio influence anogenital distance, there are other, heretofore unstudied, factors that could influence anogenital distance, including maternal effects. We capitalized on...

  11. Transactional Distance and Autonomy in a Distance Learning Environment

    Science.gov (United States)

    Vasiloudis, G.; Koutsouba, M.; Giossos, Y.; Mavroidis, I.

    2015-01-01

    This paper studies the transactional distance between the students and the tutor as well as the autonomy of students in a postgraduate course of the Hellenic Open University (HOU). The aim of the paper is to examine how the relation between autonomy and transactional distance evolves during an academic year and how this relation is affected by…

  12. Distance spectra and Distance energy of Integral Circulant Graphs

    CERN Document Server

    c, Aleksandar Ili\\'

    2011-01-01

    The distance energy of a graph $G$ is a recently developed energy-type invariant, defined as the sum of absolute values of the eigenvalues of the distance matrix of $G$. There was a vast research for the pairs and families of non-cospectral graphs having equal distance energy, and most of these constructions were based on the join of graphs. A graph is called circulant if it is Cayley graph on the circulant group, i.e. its adjacency matrix is circulant. A graph is called integral if all eigenvalues of its adjacency matrix are integers. Integral circulant graphs play an important role in modeling quantum spin networks supporting the perfect state transfer. In this paper, we characterize the distance spectra of integral circulant graphs and prove that these graphs have integral eigenvalues of distance matrix $D$. Furthermore, we calculate the distance spectra and distance energy of unitary Cayley graphs. In conclusion, we present two families of pairs $(G_1, G_2)$ of integral circulant graphs with equal distanc...

  13. Bonding in cementitious composites

    Energy Technology Data Exchange (ETDEWEB)

    Mindess, S. (British Columbia Univ., Vancouver, BC (Canada)) Shah, S.P. (Northwestern Univ., Evanston, IL (USA))

    1988-01-01

    These proceedings discuss the papers presented at the symposium on the subject of high performance cement composites. Some of the topics discussed were; calcium hydroxides treated ceramics microspheres and mechanical properties of high temperature light weight cements; microstructure and chemical variations of class F fly ash; microstructure and bond strength of cement and crack propagation as detected by laser holography and acoustic emission.

  14. Photochemical tissue bonding

    Science.gov (United States)

    Redmond, Robert W.; Kochevar, Irene E.

    2012-01-10

    Photochemical tissue bonding methods include the application of a photosensitizer to a tissue and/or tissue graft, followed by irradiation with electromagnetic energy to produce a tissue seal. The methods are useful for tissue adhesion, such as in wound closure, tissue grafting, skin grafting, musculoskeletal tissue repair, ligament or tendon repair and corneal repair.

  15. Thermal Bond System.

    Science.gov (United States)

    1995-10-31

    a twill weave, a crowfoot weave, a satin weave (FIG. 2), and a leno weave. Descriptions of the various weave types can be found in " Composite ...together to define a fabric mesh having first and second opposing woven surfaces. An adhesive bond that is flowable prior to drying is used to wet and

  16. Amide-directed photoredox-catalysed C-C bond formation at unactivated sp3 C-H bonds

    Science.gov (United States)

    Chu, John C. K.; Rovis, Tomislav

    2016-11-01

    Carbon-carbon (C-C) bond formation is paramount in the synthesis of biologically relevant molecules, modern synthetic materials and commodity chemicals such as fuels and lubricants. Traditionally, the presence of a functional group is required at the site of C-C bond formation. Strategies that allow C-C bond formation at inert carbon-hydrogen (C-H) bonds enable access to molecules that would otherwise be inaccessible and the development of more efficient syntheses of complex molecules. Here we report a method for the formation of C-C bonds by directed cleavage of traditionally non-reactive C-H bonds and their subsequent coupling with readily available alkenes. Our methodology allows for amide-directed selective C-C bond formation at unactivated sp3 C-H bonds in molecules that contain many such bonds that are seemingly indistinguishable. Selectivity arises through a relayed photoredox-catalysed oxidation of a nitrogen-hydrogen bond. We anticipate that our findings will serve as a starting point for functionalization at inert C-H bonds through a strategy involving hydrogen-atom transfer.

  17. Respect distances. Rationale and means of computation

    Energy Technology Data Exchange (ETDEWEB)

    Munier, Raymond [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden); Hoekmark, Harald [Clay Technology, Lund (Sweden)

    2004-12-01

    Canisters with spent nuclear fuel can obviously not be located within deformation zones as this might jeopardise their long term mechanical stability and thereby constitute a potential hazard to the biosphere. Less apparent, but equally important, is the fact that earthquakes trigger reactivation, slip, of structures some distance from their hypocentres due to, among many other factors, stress redistribution. Fault slip across a deposition hole might damage the isolation capacity of the canister and thereby jeopardise the overall integrity of the barrier system. Therefore, the following question might be posed: What is the distance from a deformation zone beyond which a canister can be safely emplaced? This respect distance cannot be readily computed because, unknown future events aside, there are some complicated aspects that need to be addressed e.g. degree of conservatism, scale, our ability to model ice sheets and earthquakes, etc. In this report we discuss various aspects of the assignment of respect distances, propose a methodology for its assignment and apply the methodology to the Forsmark Site as a worked example. Our main concern, in the context discussed in this report, is the post glacial faults anticipated to occur after the next glaciations. To properly address conservativeness, analysis of risk, and its implementation in safety analysis, we provide an extensive compilation of our current knowledge on post glacial faults as an appendix.

  18. Short Carboxylic Acid–Carboxylate Hydrogen Bonds Can Have Fully Localized Protons

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Jiusheng; Pozharski, Edwin; Wilson, Mark A.

    2017-01-17

    Short hydrogen bonds (H-bonds) have been proposed to play key functional roles in several proteins. The location of the proton in short H-bonds is of central importance, as proton delocalization is a defining feature of low-barrier hydrogen bonds (LBHBs). Experimentally determining proton location in H-bonds is challenging. Here, bond length analysis of atomic (1.15–0.98 Å) resolution X-ray crystal structures of the human protein DJ-1 and its bacterial homologue, YajL, was used to determine the protonation states of H-bonded carboxylic acids. DJ-1 contains a buried, dimer-spanning 2.49 Å H-bond between Glu15 and Asp24 that satisfies standard donor–acceptor distance criteria for a LBHB. Bond length analysis indicates that the proton is localized on Asp24, excluding a LBHB at this location. However, similar analysis of the Escherichia coli homologue YajL shows both residues may be protonated at the H-bonded oxygen atoms, potentially consistent with a LBHB. A Protein Data Bank-wide screen identifies candidate carboxylic acid H-bonds in approximately 14% of proteins, which are typically short [O–O> = 2.542(2) Å]. Chemically similar H-bonds between hydroxylated residues (Ser/Thr/Tyr) and carboxylates show a trend of lengthening O–O distance with increasing H-bond donor pKa. This trend suggests that conventional electronic effects provide an adequate explanation for short, charge-assisted carboxylic acid–carboxylate H-bonds in proteins, without the need to invoke LBHBs in general. This study demonstrates that bond length analysis of atomic resolution X-ray crystal structures provides a useful experimental test of certain candidate LBHBs.

  19. Trading in Treasury Bond Futures Contracts and Bonds in Australia

    OpenAIRE

    Belinda Cheung

    2014-01-01

    Treasury bond futures are a key financial product in Australia, with turnover in Treasury bond futures contracts significantly larger than turnover in the market for Commonwealth Government securities (CGS). Treasury bond futures contracts provide a wide variety of market participants with the ability to hedge against, or gain exposure to, interest rate risk. This article discusses some of the features of the Treasury bond futures contract, and how the contract is used to facilitate hedging a...

  20. Virtual Bioinformatics Distance Learning Suite

    Science.gov (United States)

    Tolvanen, Martti; Vihinen, Mauno

    2004-01-01

    Distance learning as a computer-aided concept allows students to take courses from anywhere at any time. In bioinformatics, computers are needed to collect, store, process, and analyze massive amounts of biological and biomedical data. We have applied the concept of distance learning in virtual bioinformatics to provide university course material…

  1. The Psychology of Psychic Distance

    DEFF Research Database (Denmark)

    Håkanson, Lars; Ambos, Björn; Schuster, Anja

    2016-01-01

    and their theoretical underpinnings assume psychic distances to be symmetric. Building on insights from psychology and sociology, this paper demonstrates how national factors and cognitive processes interact in the formation of asymmetric distance perceptions. The results suggest that exposure to other countries...

  2. The Distance to M104

    Science.gov (United States)

    McQuinn, Kristen. B. W.; Skillman, Evan D.; Dolphin, Andrew E.; Berg, Danielle; Kennicutt, Robert

    2016-11-01

    M104 (NGC 4594; the Sombrero galaxy) is a nearby, well-studied elliptical galaxy included in scores of surveys focused on understanding the details of galaxy evolution. Despite the importance of observations of M104, a consensus distance has not yet been established. Here, we use newly obtained Hubble Space Telescope optical imaging to measure the distance to M104 based on the tip of the red giant branch (TRGB) method. Our measurement yields the distance to M104 to be 9.55 ± 0.13 ± 0.31 Mpc equivalent to a distance modulus of 29.90 ± 0.03 ± 0.07 mag. Our distance is an improvement over previous results as we use a well-calibrated, stable distance indicator, precision photometry in a optimally selected field of view, and a Bayesian maximum likelihood technique that reduces measurement uncertainties. The most discrepant previous results are due to Tully-Fisher method distances, which are likely inappropriate for M104 given its peculiar morphology and structure. Our results are part of a larger program to measure accurate distances to a sample of well-known spiral galaxies (including M51, M74, and M63) using the TRGB method. Based on observations made with the NASA/ESA Hubble Space Telescope, obtained from the Data Archive at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS 5-26555.

  3. The Distance to M51

    Science.gov (United States)

    McQuinn, Kristen. B. W.; Skillman, Evan D.; Dolphin, Andrew E.; Berg, Danielle; Kennicutt, Robert

    2016-07-01

    Great investments of observing time have been dedicated to the study of nearby spiral galaxies with diverse goals ranging from understanding the star formation process to characterizing their dark matter distributions. Accurate distances are fundamental to interpreting observations of these galaxies, yet many of the best studied nearby galaxies have distances based on methods with relatively large uncertainties. We have started a program to derive accurate distances to these galaxies. Here we measure the distance to M51—the Whirlpool galaxy—from newly obtained Hubble Space Telescope optical imaging using the tip of the red giant branch method. We measure the distance modulus to be 8.58 ± 0.10 Mpc (statistical), corresponding to a distance modulus of 29.67 ± 0.02 mag. Our distance is an improvement over previous results as we use a well-calibrated, stable distance indicator, precision photometry in a optimally selected field of view, and a Bayesian Maximum Likelihood technique that reduces measurement uncertainties. Based on observations made with the NASA/ESA Hubble Space Telescope, obtained from the Data Archive at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS 5-26555.

  4. Quality Content in Distance Education

    Science.gov (United States)

    Yildiz, Ezgi Pelin; Isman, Aytekin

    2016-01-01

    In parallel with technological advances in today's world of education activities can be conducted without the constraints of time and space. One of the most important of these activities is distance education. The success of the distance education is possible with content quality. The proliferation of e-learning environment has brought a need for…

  5. Virtual Bioinformatics Distance Learning Suite

    Science.gov (United States)

    Tolvanen, Martti; Vihinen, Mauno

    2004-01-01

    Distance learning as a computer-aided concept allows students to take courses from anywhere at any time. In bioinformatics, computers are needed to collect, store, process, and analyze massive amounts of biological and biomedical data. We have applied the concept of distance learning in virtual bioinformatics to provide university course material…

  6. Distance labeling schemes for trees

    DEFF Research Database (Denmark)

    Alstrup, Stephen; Gørtz, Inge Li; Bistrup Halvorsen, Esben;

    2016-01-01

    We consider distance labeling schemes for trees: given a tree with n nodes, label the nodes with binary strings such that, given the labels of any two nodes, one can determine, by looking only at the labels, the distance in the tree between the two nodes. A lower bound by Gavoille et al. [Gavoill...

  7. New distances to RAVE stars

    NARCIS (Netherlands)

    Binney, J.; Burnett, B.; Kordopatis, G.; McMillan, P. J.; Sharma, S.; Zwitter, T.; Bienayme, O.; Bland-Hawthorn, J.; Steinmetz, M.; Gilmore, G.; Williams, M. E. K.; Navarro, J.; Grebel, E. K.; Helmi, A.; Parker, Q.; Reid, W. A.; Seabroke, G.; Watson, F.; Wyse, R. F. G.

    Probability density functions (pdfs) are determined from new stellar parameters for the distance moduli of stars for which the RAdial Velocity Experiment (RAVE) has obtained spectra with S/N >= 10. Single-Gaussian fits to the pdf in distance modulus suffice for roughly half the stars, with most of

  8. Distance labeling schemes for trees

    DEFF Research Database (Denmark)

    Alstrup, Stephen; Gørtz, Inge Li; Bistrup Halvorsen, Esben

    2016-01-01

    variants such as, for example, small distances in trees [Alstrup et al., SODA, 2003]. We improve the known upper and lower bounds of exact distance labeling by showing that 1/4 log2(n) bits are needed and that 1/2 log2(n) bits are sufficient. We also give (1 + ε)-stretch labeling schemes using Theta...

  9. Faculty Attitudes about Distance Education

    Science.gov (United States)

    Smidt, Esther; McDyre, Brian; Bunk, Jennifer; Li, Rui; Gatenby, Tanya

    2014-01-01

    In recent years, there has been a dramatic increase in distance learning in higher education. Given this, it is extremely important to understand faculty attitudes about distance education, not only because they can vary widely, but also because it is the faculty, through their design and implementation of online courses, that will shape the…

  10. Distance-constrained grid colouring

    Directory of Open Access Journals (Sweden)

    Aszalós László

    2016-06-01

    Full Text Available Distance-constrained colouring is a mathematical model of the frequency assignment problem. This colouring can be treated as an optimization problem so we can use the toolbar of the optimization to solve concrete problems. In this paper, we show performance of distance-constrained grid colouring for two methods which are good in map colouring.

  11. Indirect bonding technique in orthodontics

    Directory of Open Access Journals (Sweden)

    Kübra Yıldırım

    2016-08-01

    Full Text Available ‘Direct Bonding Technique’ which allows the fixed orthodontic appliances to be directly bonded to teeth without using bands decreased the clinic time for bracket bonding and increased esthetics and oral hygiene during orthodontic treatment. However, mistakes in bracket positioning were observed due to decreased direct visual sight and access to posterior teeth. ‘Indirect Bonding Technique’ was developed for eliminating these problems. Initially, decreased bond strength, higher bond failure rate, periodontal tissue irritation, compromised oral hygiene and increased laboratory time were the main disadvantages of this technique when compared to direct bonding. The newly developed materials and modified techniques help to eliminate these negative consequences. Today, the brackets bonded with indirect technique have similar bond strength with brackets bonded directly. Moreover, indirect and direct bonding techniques have similar effects on periodontal tissues. However, indirect bonding technique requires more attention and precision in laboratory and clinical stage, and has higher cost. Orthodontist's preference between these two bonding techniques may differ according to time spent in laboratory and clinic, cost, patient comfort and personal opinion.

  12. Hierarchical traits distances explain grassland Fabaceae species’ ecological niches distances

    Directory of Open Access Journals (Sweden)

    Florian eFort

    2015-02-01

    Full Text Available Fabaceae species play a key role in ecosystem functioning through their capacity to fix atmospheric nitrogen via their symbiosis with Rhizobium bacteria. To increase benefits of using Fabaceae in agricultural systems, it is necessary to find ways to evaluate species or genotypes having potential adaptations to sub-optimal growth conditions. We evaluated the relevance of phylogenetic distance, absolute trait distance and hierarchical trait distance for comparing the adaptation of 13 grassland Fabaceae species to different habitats, i.e. ecological niches. We measured a wide range of functional traits (root traits, leaf traits and whole plant traits in these species. Species phylogenetic and ecological distances were assessed from a species-level phylogenetic tree and species’ ecological indicator values, respectively. We demonstrated that differences in ecological niches between grassland Fabaceae species were related more to their hierarchical trait distances than to their phylogenetic distances. We showed that grassland Fabaceae functional traits tend to converge among species with the same ecological requirements. Species with acquisitive root strategies (thin roots, shallow root systems are competitive species adapted to non-stressful meadows, while conservative ones (coarse roots, deep root systems are able to tolerate stressful continental climates. In contrast, acquisitive species appeared to be able to tolerate low soil-P availability, while conservative ones need high P availability. Finally we highlight that traits converge along the ecological gradient, providing the assumption that species with similar root-trait values are better able to coexist, regardless of their phylogenetic distance.

  13. Unwilling U-U bonding in U2@C80: cage-driven metal-metal bonds in di-uranium fullerenes.

    Science.gov (United States)

    Foroutan-Nejad, Cina; Vícha, Jan; Marek, Radek; Patzschke, Michael; Straka, Michal

    2015-10-07

    Endohedral actinide fullerenes are rare and a little is known about their molecular properties. Here we characterize the U2@C80 system, which was recently detected experimentally by means of mass spectrometry (Akiyama et al., JACS, 2001, 123, 181). Theoretical calculations predict a stable endohedral system, (7)U2@C80, derived from the C80:7 IPR fullerene cage, with six unpaired electrons. Bonding analysis reveals a double ferromagnetic (one-electron-two-center) U-U bond at an rU-U distance of 3.9 Å. This bonding is realized mainly via U(5f) orbitals. The U-U interaction inside the cage is estimated to be about -18 kcal mol(-1). U-U bonding is further studied along the U2@Cn (n = 60, 70, 80, 84, 90) series and the U-U bonds are also identified in U2@C70 and U2@C84 systems at rU-U∼ 4 Å. It is found that the character of U-U bonding depends on the U-U distance, which is dictated by the cage type. A concept of unwilling metal-metal bonding is suggested: uranium atoms are strongly bound to the cage and carry a positive charge. Pushing the U(5f) electron density into the U-U bonding region reduces electrostatic repulsion between enclosed atoms, thus forcing U-U bonds.

  14. Trends and Issues in Distance Education: International Perspectives

    Directory of Open Access Journals (Sweden)

    Erhan EROGLU

    2006-04-01

    quality, accredition and recognition: issues in the delivery of transnational education.” Third perspective is “the long and short of distance education: trends and issues from a planetary human develeopment perspective.” Fourth perspective is “distance education reappraised: emerging trends in traditional universities and corporate training institutions.” And fifth one is “what the world needs now: international research on distance education.” Part II contains a series of interviews that that were conducted with international distance education leaders. This section has four chapters. The individuals interviewes in this section were selected because they have played a significant role in the development of distance education theory, research and practice. Part III of the book presents a fascinating array of case studies in distance education. This section has eight chapters. The chapters in Part III section of the book cover experiences with programs and initiatives in places as diverse as South Africa, Brazil, and Turkey. Some of these case studies report on experience with in a specific nation. Part IV, the last part of the book, focuses on practical issues in distance education. In tih section, there are three chapters. In this section, authors of the chapters discuss some of the key trends in the design and development of distance education for international audiences and settings. For example, “wide array of technologies and strategies that can be used for distance education, while giving special consideration to the impact of human and environmental differences on the selection of approaches”, “analysing of how mentoring roles evolve as the technologies enabling distance learning become increasingly interactive and accomodating of student-to-student and student-to-instructor interaction. CONTENTS OF THE BOOK Introduction Yusra Laila VISSER, Lya VISSER, Michael SIMONSON, and Ray Amirault PART I PERSPECTIVES ON GLOBAL TRENDS AND ISSUES IN DISTANCE EDUCATION A

  15. Distance labeling schemes for trees

    DEFF Research Database (Denmark)

    Alstrup, Stephen; Gørtz, Inge Li; Bistrup Halvorsen, Esben

    2016-01-01

    We consider distance labeling schemes for trees: given a tree with n nodes, label the nodes with binary strings such that, given the labels of any two nodes, one can determine, by looking only at the labels, the distance in the tree between the two nodes. A lower bound by Gavoille et al. [Gavoille...... variants such as, for example, small distances in trees [Alstrup et al., SODA, 2003]. We improve the known upper and lower bounds of exact distance labeling by showing that 1/4 log2(n) bits are needed and that 1/2 log2(n) bits are sufficient. We also give (1 + ε)-stretch labeling schemes using Theta......(log(n)) bits for constant ε> 0. (1 + ε)-stretch labeling schemes with polylogarithmic label size have previously been established for doubling dimension graphs by Talwar [Talwar, STOC, 2004]. In addition, we present matching upper and lower bounds for distance labeling for caterpillars, showing that labels...

  16. Wafer bonding using Cu-Sn intermetallic bonding layers

    NARCIS (Netherlands)

    Flötgen, C.; Pawlak, M.; Pabo, E.; Wiel, H.J. van de; Hayes, G.R.; Dragoi, V.

    2014-01-01

    Wafer-level Cu-Sn intermetallic bonding is an interesting process for advanced applications in the area of MEMS and 3D interconnects. The existence of two intermetallic phases for Cu-Sn system makes the wafer bonding process challenging. The impact of process parameters on final bonding layer

  17. Quality Teacher Education via Distance Mode: A Caribbean Experience.

    Science.gov (United States)

    Hall, Winnifred M.; Marrett, Christine

    1996-01-01

    Reports on a study of the University of the West Indies Distance Teaching Experiment, which offers preservice teacher education via distance education using an interactive teleconference network. Surveys of participating teachers (n=169) indicated that the network had several of the desired infrastructures in place for conducting quality teacher…

  18. Turning points in long distance grandparent-grandchild relationships.

    Science.gov (United States)

    Bangerter, Lauren R; Waldron, Vincent R

    2014-04-01

    This study examines changes in long-distance relationships between grandparents and their adolescent grandchildren by identifying relational turning points and trajectories. Qualitative analysis of data collected from interviews with grandparents yielded 100 unique turning points. Constant comparative analysis revealed eight distinct categories of relational turning points; Spending Time Together, Family Relational Dynamics, Geographic Distance, Lack of Relational Investment, Use of Technology, Relational Investment, Lack of Free Time, and Grandchild Gaining Independence. These varied in the degree to which they positively or negatively impacted relational closeness. Application of the Retrospective Interview Technique (RIT) yielded five distinctive relational trajectories: Decrease in Closeness, Increase in Closeness, Multidimensional Changes in Closeness, Minimal Changes in Closeness, and Consistent Relational Closeness. The results expose the communicative challenges faced by long-distance-grandparents, the diversity of these relationships, and the ways in which grandparenting bonds change over time. Implications for an enriched understanding of grandparenting relationships and practical applications for families are explored.

  19. Bond length and adsorbate vibrations of (2×3)N/Cu(110): A SEXAFS study

    Science.gov (United States)

    Wende, H.; Arvanitis, D.; Tischer, M.; Chauvistré, R.; Henneken, H.; May, F.; Baberschke, K.

    1996-08-01

    Temperature- and angle-dependent surface-extended x-ray-absorption fine-structure (SEXAFS) measurements on the system (2×3)N/Cu(110) are reported. Three inequivalent adsorption sites of the N atoms within the surface unit cell are identified. The successful separation of their contributions in the present SEXAFS analysis allows for a determination of N-Cu bond lengths not only within the surface plane but also to the second Cu layer. The temperature-dependent measurements between 60 and 300 K enable us to separate structural from dynamic effects in the SEXAFS amplitude, leading to a reliable determination of coordination numbers. A strong anisotropy is found in the adsorbate vibrations parallel versus perpendicular to the surface. The relative motion of the N atom relative to the first three Cu neighbor shells is characterized by means of the corresponding Einstein temperatures. These indicate that the N atom is primarily bonded only to four Cu atoms, and not to five as previously suggested. Anharmonic corrections are found necessary for a reliable distance determination of the N-Cu bonds to the second layer. The structural parameters are compared to the ones predicted by the pseudo-(100)-c(2×2)-N reconstruction.

  20. NOTE: Fabrication of a gecko-like hierarchical fibril array using a bonded porous alumina template

    Science.gov (United States)

    Suryadi Kustandi, Tanu; Samper, Victor Donald; Ng, Wan Sing; Chong, Ai Shing; Gao, Han

    2007-10-01

    We report a new method to fabricate a hierarchical microfibril array by using bonded porous alumina templates. The fabrication approach extends a powerful and well-established technique of creating porous alumina to create a polymer multilevel structure, mimicking the hierarchical structure of gecko adhesive foot hairs. The nanoporous alumina (pore diameter ≈60 nm; interpore distance ≈100 nm) was generated by the anodization of an aluminum film in an oxalic acid solution. The microporous alumina was produced by exploiting the parallel wafer-scale processing of conventional lithography and anisotropic chemical etching of the thick film of anodic alumina pores. The micro- and nanoporous alumina membranes were subsequently brought into intimate contact and their bonding was accomplished by means of capillary forces and then van der Waals bonding. Hierarchical polymeric microfibrils (fibril diameter ≈10 µm fibril length ≈70 µm) with nanofibril arrays at their tips were obtained after depositing a desired material into the pores and selective etching of the template membranes. The nanofibril has a lateral dimension of approximately 60 nm with length-to-diameter aspect ratios as high as 100:1.

  1. Routes to Hydrogen Bonding Chain-End Functionalized Polymers.

    Science.gov (United States)

    Bertrand, Arthur; Lortie, Frédéric; Bernard, Julien

    2012-12-21

    The contribution of supramolecular chemistry to polymer science opens new perspectives for the design of polymer materials exhibiting valuable properties and easier processability due to the dynamic nature of non-covalent interactions. Hydrogen bonding polymers can be used as supramolecular units for yielding larger assemblies that possess attractive features, arising from the combination of polymer properties and the responsiveness of hydrogen bonds. The post-polymerization modification of reactive end-groups is the most common procedure for generating such polymers. Examples of polymerizations mediated by hydrogen bonding-functionalized precursors have also recently been reported. This contribution reviews the current synthetic routes toward hydrogen bonding sticker chain-end functionalized polymers.

  2. Time- and temperature-dependent failures of a bonded joint

    Energy Technology Data Exchange (ETDEWEB)

    Sihn, Sangwook; Miyano, Yasushi; Tsai, S.W. [Stanford Univ., Palo Alto, CA (United States)

    1997-07-01

    Time and temperature dependent properties of a tubular lap bonded joint are reported. The joint bonds a cast iron rod and a composite pipe together with an epoxy type of an adhesive material containing chopped glass fiber. A new fabrication method is proposed.

  3. Regioselectivity in the Reductive Bond Cleavage of Diarylalkylsulfonium Salts

    DEFF Research Database (Denmark)

    Kampmeier, Jack; Mansurul Hoque, AKM; D. Saeva, Franklin;

    2009-01-01

    This investigation was stimulated by reports that one-electron reductions of monoaryldialkylsulfonium salts never give aryl bond cleavage whereas reductions of diarylmonoalkylsulfonium salts preferentially give aryl bond cleavage. We studied the product ratios from the reductive cleavage of di-4-...

  4. Binding of reactive organophosphate by oximes via hydrogen bond

    Indian Academy of Sciences (India)

    Andrea Pappalardo; Maria E Amato; Francesco P Ballistreri; Valentina La Paglia Fragola; Gaetano A Tomaselli; Rosa Maria Toscano; Giuseppe Trusso Sfrazzetto

    2013-07-01

    In this contribution, the ability of simple oximes to bind a well-known nerve agent simulant (dimethylmethylphosphonate, DMMP) via hydrogen bond is reported. UV/Vis measurements indicate the formation of 1:1 complexes. 1H-, 31P-NMR titrations and T-ROESY experiments confirm that oximes bind the organophosphate via hydrogen bond.

  5. Hydrogen bonding in oxalic acid and its complexes: A database study of neutron structures

    Indian Academy of Sciences (India)

    R Chitra; Amit Das; R R Choudhury; M Ramanadham; R Chidambaram

    2004-08-01

    The basic result of carboxylic group that the oxygen atom of the –OH never seems to be a hydrogen bond acceptor is violated in the cases, namely urea oxalic acid and bis urea oxalic acid complexes, where the hydroxyl oxygen atom is an acceptor of a weak N–H... O hydrogen bond. The parameters of this hydrogen bond, respectively in these structures are: hydrogen acceptor distance 2.110 Å and 2.127 Å and the bending angle at hydrogen, 165.6° and 165.8°. The bond strength around the hydroxyl oxygen is close to 1.91 valence units, indicating that it has hardly any strength left to form hydrogen bonds. These two structures being highly planar, force the formation of this hydrogen bond. As oxalic acid is the common moiety, the structures of the two polymorphs, -oxalic acid and -oxalic acid, also were looked into in terms of hydrogen bonding and packing.

  6. China-Russia Bond

    Institute of Scientific and Technical Information of China (English)

    Ji Zhiye; Ma Zongshi

    2007-01-01

    @@ Thanks to China's successful launching of the Year of Russia, 2006 will surely go down as a milestone in the history of the China-Russia bond. Furthermore, a still-warmer climate will continue to prevail in 2007 when Moscow, in its turn, hosts the Year of China, trying to outshine its next-door neighbor in this regard, as Russian President Vladimir Putin promised in the exchange of new year greetings with his Chinese counterpart, President Hu Jintao.

  7. Direct bonded space maintainers.

    Science.gov (United States)

    Santos, V L; Almeida, M A; Mello, H S; Keith, O

    1993-01-01

    The aim of this study was to evaluate clinically a bonded space maintainer, which would reduce chair-side time and cost. Sixty appliances were fabricated from 0.7 mm stainless steel round wire and bonded using light-cured composite to the two teeth adjacent to the site of extraction of a posterior primary tooth. Twenty males and sixteen females (age range 5-9-years-old) were selected from the Pedodontic clinic of the State University of Rio de Janeiro. The sixty space maintainers were divided into two groups according to the site in which they were placed: a) absent first primary molar and b) absent second primary molar. Impressions and study models were obtained prior to and 6 months after bonding the appliances. During this period only 8.3% of failures were observed, most of them from occlusal or facial trauma. Student t-test did not show statistically significant alterations in the sizes of the maintained spaces during the trial period.

  8. The Distance Field Model and Distance Constrained MAP Adaptation Algorithm

    Institute of Scientific and Technical Information of China (English)

    YUPeng; WANGZuoying

    2003-01-01

    Spatial structure information, i.e., the rel-ative position information of phonetic states in the feature space, is long to be carefully researched yet. In this pa-per, a new model named “Distance Field” is proposed to describe the spatial structure information. Based on this model, a modified MAP adaptation algorithm named dis-tance constrained maximum a poateriori (DCMAP) is in-troduced. The distance field model gives large penalty when the spatial structure is destroyed. As a result the DCMAP reserves the spatial structure information in adaptation process. Experiments show the Distance Field Model improves the performance of MAP adapta-tion. Further results show DCMAP has strong cross-state estimation ability, which is used to train a well-performed speaker-dependent model by data from only part of pho-

  9. Semiconductor Laser Tracking Frequency Distance Gauge

    Science.gov (United States)

    Phillips, James D.; Reasenberg, Robert D.

    2009-01-01

    Advanced astronomical missions with greatly enhanced resolution and physics missions of unprecedented accuracy will require a spaceworthy laser distance gauge of substantially improved performance. The Tracking Frequency Gauge (TFG) uses a single beam, locking a laser to the measurement interferometer. We have demonstrated this technique with pm (10(exp -12) m) performance. We report on the version we are now developing based on space-qualifiable, fiber-coupled distributed-feedback semiconductor lasers.

  10. A distance based test on random trees

    OpenAIRE

    Flesia, Ana Georgina; Fraiman, Ricardo

    2007-01-01

    In this paper, we address the question of comparison between populations of trees. We study an statistical test based on the distance between empirical mean trees, as an analog of the two sample z statistic for comparing two means. Despite its simplicity, we can report that the test is quite powerful to separate distributions with different means but it does not distinguish between different populations with the same mean, a more complicated test should be applied in that setting. The perform...

  11. Report on achievements in fiscal 1999 on research and development of the technology to create biological bonding substances utilizing particulates under the industrial and scientific technology research and development theme [university collaborated type]. Research and development of the technology to create biological bonding substances utilizing particulates; 1999 nendo biryushi riyogata seitai ketsugo busshitsu nado sosei gijutsu no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This paper describes the achievements in fiscal 1999 on development of the technology to create biological bonding substances utilizing particulates. In fixing ligands onto particulates, it is necessary that various compounds be fixed with their receptor bonding specificity maintained. Therefore, carboxylic acid, thiol and bromoacetyl groups were introduced into the particulates. Capping them by using methoxyacetyl was found capable of suppressing non-specific adsorption. Opioid compounds were synthesized for their fixation onto particulates for selection and separation. Carrying particulate bonding precursors in latex beads was realized. Synthesis will continue on opiod compounds in which amide groups are introduced into different positions to provide the particulate carrying ligands with diversity. Biological receptors for different compounds were obtained and refined by using compound fixing particulates. Refinement and acquisition were possible on FK506 bonded protein in a short time from cell extraction liquid by using the fixing particulates for the FK506 bonded protein. The paper also describes analysis of bonded domains, and position-specific fixation of the biological receptors. (NEDO)

  12. The Distance to M104

    CERN Document Server

    McQuinn, Kristen B W; Dolphin, Andrew E; Berg, Danielle; Kennicutt, Robert

    2016-01-01

    M104 (NGC 4594; the Sombrero galaxy) is a nearby, well-studied elliptical galaxy included in scores of surveys focused on understanding the details of galaxy evolution. Despite the importance of observations of M104, a consensus distance has not yet been established. Here, we use newly obtained Hubble Space Telescope optical imaging to measure the distance to M104 based on the tip of the red giant branch method. Our measurement yields the distance to M104 to be 9.55 +/- 0.13 +/- 0.31 Mpc equivalent to a distance modulus of 29.90 +/- 0.03 +/- 0.07 mag. Our distance is an improvement over previous results as we use a well-calibrated, stable distance indicator, precision photometry in a optimally selected field of view, and a Bayesian Maximum Likelihood technique that reduces measurement uncertainties. The most discrepant previous results are due to Tully-Fisher method distances, which are likely inappropriate for M104 given its peculiar morphology and structure. Our results are part of a larger program to measu...

  13. Bond length-bond angle correlation in densified silica—Results from 17O NMR spectroscopy

    Science.gov (United States)

    Trease, Nicole M.; Clark, Ted M.; Grandinetti, Philip J.; Stebbins, Jonathan F.; Sen, Sabyasachi

    2017-05-01

    Pressure induced correlated evolution of the distributions of the Si-O distance and Si-O-Si inter-tetrahedral bond angle in vitreous silica quenched from pressures of up to ˜14 GPa at ambient temperature is measured in unprecedented detail using two-dimensional dynamic-angle-spinning 17O nuclear magnetic resonance spectroscopy. The results demonstrate that, in contrast to the conventional wisdom, vitreous silica undergoes irreversible structural changes even at pressures as low as ˜8 GPa. These structural changes at the short range involve a progressive reduction in the mean Si-O-Si angle and a broadening of the corresponding distribution, with increasing pressure. This bond angle reduction is accompanied by a concomitant monotonic increase in the mean Si-O distance. The mean values of the Si-O-Si angle and Si-O distance at various pressures closely follow the minimum in the corresponding potential energy surface calculated for the H6Si2O7 dimer molecule.

  14. Coulombic Models in Chemical Bonding.

    Science.gov (United States)

    Sacks, Lawrence J.

    1986-01-01

    Compares the coulumbic point charge model for hydrogen chloride with the valence bond model. It is not possible to assign either a nonpolar or ionic canonical form of the valence bond model, while the covalent-ionic bond distribution does conform to the point charge model. (JM)

  15. Optimal Investment in Structured Bonds

    DEFF Research Database (Denmark)

    Jessen, Pernille; Jørgensen, Peter Løchte

    The paper examines the role of structured bonds in the optimal portfolio of a small retail investor. We consider the typical structured bond essentially repacking an exotic option and a zero coupon bond, i.e. an investment with portfolio insurance. The optimal portfolio is found when the investment...

  16. Mittal bonded tongue thrusting appliance

    Directory of Open Access Journals (Sweden)

    Rekha Mittal

    2014-01-01

    Full Text Available These days majority of orthodontist includes bonded molar attachment in their inventory to eliminate the discomfort of molar separation during initial appointment and band spaces left at the end of treatment. This article describes a innovative and economical method of attachment of bonded tongue crib if required during the initial or later stages of treatment along with bonded molar tubes.

  17. Benchmarking Density Functionals for Chemical Bonds of Gold

    DEFF Research Database (Denmark)

    Kepp, Kasper Planeta

    2017-01-01

    Gold plays a major role in nanochemistry, catalysis, and electrochemistry. Accordingly, hundreds of studies apply density functionals to study chemical bonding with gold, yet there is no systematic attempt to assess the accuracy of these methods applied to gold. This paper reports a benchmark...... against 51 experimental bond enthalpies of AuX systems and seven additional polyatomic and cationic molecules. Twelve density functionals were tested, covering meta functionals, hybrids with variable HF exchange, double-hybrid, dispersion-corrected, and nonhybrid GGA functionals. The defined benchmark...... bonds between gold and noble gases. Zero-point vibrational corrections are relatively small for Au-X bonds, ∼ 11-12 kJ/mol except for Au-H bonds. Dispersion typically provides ∼5 kJ/mol of the total bond enthalpy but grows with system size and is 10 kJ/mol for AuXe and AuKr. HF exchange and LYP...

  18. Superstrong encapsulated monolayer graphene by the modified anodic bonding.

    Science.gov (United States)

    Jung, Wonsuk; Yoon, Taeshik; Choi, Jongho; Kim, Soohyun; Kim, Yong Hyup; Kim, Taek-Soo; Han, Chang-Soo

    2014-01-07

    We report a superstrong adhesive of monolayer graphene by modified anodic bonding. In this bonding, graphene plays the role of a superstrong and ultra-thin adhesive between SiO2 and glass substrates. As a result, monolayer graphene presented a strong adhesion energy of 1.4 J m(-2) about 310% that of van der Waals bonding (0.45 J m(-2)) to SiO2 and glass substrates. This flexible solid state graphene adhesive can tremendously decrease the adhesive thickness from about several tens of μm to 0.34 nm for epoxy or glue at the desired bonding area. As plausible causes of this superstrong adhesion, we suggest conformal contact with the rough surface of substrates and generation of C-O chemical bonding between graphene and the substrate due to the bonding process, and characterized these properties using optical microscopy, atomic force microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy.

  19. Reducing the distance in distance-caregiving by technology innovation

    Directory of Open Access Journals (Sweden)

    Lazelle E Benefield

    2007-07-01

    Full Text Available Lazelle E Benefield1, Cornelia Beck21College of Nursing, University of Oklahoma Health Sciences Center, Oklahoma City, Oklahoma, USA; 2Pat & Willard Walker Family Memory Research Center, University of Arkansas for Medical Sciences, Little Rock, Arkansas, USAAbstract: Family caregivers are responsible for the home care of over 34 million older adults in the United States. For many, the elder family member lives more than an hour’s distance away. Distance caregiving is a growing alternative to more familiar models where: 1 the elder and the family caregiver(s may reside in the same household; or 2 the family caregiver may live nearby but not in the same household as the elder. The distance caregiving model involves elders and their family caregivers who live at some distance, defined as more than a 60-minute commute, from one another. Evidence suggests that distance caregiving is a distinct phenomenon, differs substantially from on-site family caregiving, and requires additional assistance to support the physical, social, and contextual dimensions of the caregiving process. Technology-based assists could virtually connect the caregiver and elder and provide strong support that addresses the elder’s physical, social, cognitive, and/or sensory impairments. Therefore, in today’s era of high technology, it is surprising that so few affordable innovations are being marketed for distance caregiving. This article addresses distance caregiving, proposes the use of technology innovation to support caregiving, and suggests a research agenda to better inform policy decisions related to the unique needs of this situation.Keywords: caregiving, family, distance, technology, elders

  20. High Bonding Temperatures Greatly Improve Soy Adhesive Wet Strength

    Directory of Open Access Journals (Sweden)

    Charles R. Frihart

    2016-11-01

    Full Text Available Soy wood adhesive bond strengths reported in different literature studies are difficult to compare because a variety of temperatures and other conditions have been used for the bonding and testing step. Some reports have indicated bond strengths are sensitive to bonding temperature, but the reason(s for this has not been intensively investigated. Although these prior studies differ in other ways (such as type of soy, wood species, and test method, the effect of bonding temperature has not been clearly examined, which is important for focusing commercial applications. A tensile shear test using two-parallel-ply veneer specimens with smooth maple was used to measure both the dry and wet cohesive strength of soy adhesives. Although the soy adhesives gave very good strengths and dry wood failure, they often have low wood failure and shear strengths under wet conditions when bonded at 120 °C. However, wet strength greatly increased as the bonding temperature increased (120, 150 and 180 °C for these two-ply tests with. This study examined the use of different types of soys (flours, concentrates and isolates and different bonding temperatures and bonding conditions to evacuate several possible mechanisms for this temperature sensitivity, with coalescence being the most likely.

  1. Incarcerated adolescents' distress and suicidality in relation to parental bonding styles.

    Science.gov (United States)

    McGarvey, E L; Kryzhanovskaya, L A; Koopman, C; Waite, D; Canterbury, R J

    1999-01-01

    This study examines the relationships between the bonding style of an incarcerated adolescent with parents and his/her current feelings of self-esteem, hopelessness, and suicidal thoughts and attempts. It also investigates differences between bonding to mother and bonding to father. Some 296 incarcerated adolescents were interviewed using the Parental Bonding Instrument. Significant relationships were found between youths' self-esteem, hoplessness, and suicidal behavior and their bonding style. Youths whose parent(s) had a parental bonding style of affectionless control reported the greatest distress, and youths whose parent(s) had an optimal bonding style reported the least distress. Differences were found between bonding styles with the mother and with the father. Attachment theory may be useful in targeting incarcerated youths who have affectionless control bonding with parent(s) for special interventions since these youths are most at risk for psychosocial problems.

  2. The chemical bond in inorganic chemistry the bond valence model

    CERN Document Server

    Brown, I David

    2016-01-01

    The bond valence model is a version of the ionic model in which the chemical constraints are expressed in terms of localized chemical bonds formed by the valence charge of the atoms. Theorems derived from the properties of the electrostatic flux predict the rules obeyed by both ionic and covalent bonds. They make quantitative predictions of coordination number, crystal structure, bond lengths and bond angles. Bond stability depends on the matching of the bonding strengths of the atoms, while the conflicting requirements of chemistry and space lead to the structural instabilities responsible for the unusual physical properties displayed by some materials. The model has applications in many fields ranging from mineralogy to molecular biology.

  3. Influence of argon laser curing on resin bond strength.

    Science.gov (United States)

    Hinoura, K; Miyazaki, M; Onose, H

    1993-04-01

    Light cured resin composites are usually cured with halogen lamps whose light output decreases with time and distance to the resin surface. This study compared bond strengths of resins to tooth structure cured with either an argon laser or a conventional halogen light. The enamel and dentin of bovine incisors were ground on the buccal surface with wet #600 grit SiC paper. A 4 x 2 mm mold was placed on the tooth surface and Scotchbond 2/Silux and Clearfil Photobond/Photo Clearfil A were placed into the molds and cured using a Quick Light or an argon laser for exposure times of 10, 20, and 30 seconds, and distances of 0.0, 0.5, 1.0, and 1.5 mm from the resin surface. The intensity of the Quick Light was measured as 510 mW/cm2 at 470 +/- 15 nm and the intensity of the argon laser was adjusted to 510 mW/cm2 before curing. Shear bond tests at a crosshead speed of 1.0 mm/min were performed after 24 hours of storage in water. The bond strengths obtained with the halogen lamp and the laser were not significantly different at the same exposure times and at 0.0 or 0.5 mm from the resin surface. The laser cured bond strengths did not decrease with increasing distance whereas there was a significant decrease in halogen bond strengths at distances greater than 0.5 mm for both resins. The use of the laser might provide a clinical advantage in cases where the curing light source cannot be brought into proximity to the surface of the resin.

  4. Going the Distance in a "Changing" World: Distance Learning and the Foreign Language Classroom

    Science.gov (United States)

    Gunnels, Bridgette W.

    2008-01-01

    This article offers a critique of the lack of attention to the place of online course offerings in foreign language departments and/or distance education in general by the MLA's 2007 report on foreign language departments and their role in the academy. The article responds to how currently accessible technology (course management system platforms…

  5. Neuroticism as distancing: perceptual sources of evidence.

    Science.gov (United States)

    Liu, Tianwei; Ode, Scott; Moeller, Sara K; Robinson, Michael D

    2013-05-01

    Several theories and self-reported sources of data link individual differences in negative affectivity to avoidance motivation. Chronic avoidance motivation, through repeated practice, may result in a relatively cognitive distance-enhancing dynamic whereby events and stimuli are perceived as further away from the self, even when they are not threatening. Such predictions are novel but follow from cybernetic theories of self-regulation. In 5 studies (total N = 463), relations of this type were investigated. Study 1 presented participants with phrases that were ambiguous and found that trait negative affect predicted phrase interpretation in a distance-enhancing temporal direction. Study 2 replicated this effect across a systematic manipulation of event valence. Study 3 asked individuals to estimate the size of words and found that individuals higher in neuroticism generally perceived words to be smaller than did individuals lower in neuroticism. In Study 4, people high (but not low) in neuroticism perceived words to be shrinking faster than they were growing. In Study 5, greater perceptual distancing, in a font size estimation task, predicted more adverse reactions to negative events in daily life. Although normative effects varied across studies, consistent support for a chronic distancing perspective of individual differences in negative affectivity was found.

  6. Two-step energy transfer enables use of phenylalanine in action-EET for distance constraint determination in gaseous biomolecules.

    Science.gov (United States)

    Hendricks, Nathan G; Julian, Ryan R

    2015-08-18

    Two-step energy transfer is potentially useful for exploring macromolecular structure, but it has not been observed previously in the gas-phase. Single step excitation energy transfer (EET) has been recently documented for tyrosine and tryptophan containing peptides, but not for phenylalanine. Herein, we report sequential energy transfer from phenylalanine to tyrosine to a disulfide, resulting in homolytic cleavage of a sulfur-sulfur bond. Interestingly, energy transfer from phenylalanine is only observed in the presence of tyrosine and only occurs within certain distance constraints. Isolated, electronically excited phenylalanine is known to have an extremely long lifetime in the gas phase, potentially suggesting quicker relaxation occurs via energy transfer to tyrosine. Alternatively, the direct overlap of states between phenylalanine and disulfide bonds is predicted to be poor, in which case tyrosine would serve to bridge the gap. In either case, the distance constraints imposed by this two-step EET are shown to be useful for evaluation and determination of gaseous biomolecular structure.

  7. Picosecond laser bonding of highly dissimilar materials

    Science.gov (United States)

    Carter, Richard M.; Troughton, Michael; Chen, Jianyong; Elder, Ian; Thomson, Robert R.; Lamb, Robert A.; Esser, M. J. Daniel; Hand, Duncan P.

    2016-10-01

    We report on recent progress in developing an industrially relevant, robust technique to bond dissimilar materials through ultra-fast microwelding. This technique is based on the use of a 5.9ps, 400kHz Trumpf laser operating at 1030nm. Tight focusing of the laser radiation at, or around, the interface between two materials allows for simultaneous absorption in both. This absorption rapidly, and locally, heats the material forming plasma from both materials. With suitable surface preparation this plasma can be confined to the interface region where it mixes, cools and forms a weld between the two materials. The use of ps pulses results in a short interaction time. This enables a bond to form whilst limiting the heat affected zone (HAZ) to a region of only a few hundred micrometres across. This small scale allows for the bonding of materials with highly dissimilar thermal properties, and in particular coefficients of thermal expansion e.g. glass-metal bonding. We report on our results for a range of material combinations including, Al-Bk7, Al-SiO2 and Nd:YAG-AlSi. Emphasis will be laid on the technical requirements for bonding including the required surface preparation of the two materials and on the laser parameters required. The quality of the resultant bonds are characterized through shear force measurements (where strengths equal to and exceeding equivalent adhesives will be presented). The lifetime of the welds is also discussed, paying particular attention to the results of thermal cycling tests.

  8. Perniosis in a long-distance cyclist crossing Mongolia.

    Science.gov (United States)

    Neal, Andrew J; Jarman, Alison M; Bennett, Timothy G

    2012-01-01

    We report a case of severe perniosis in a long-distance cyclist. This case demonstrates the importance of identifying those at risk of cold-related injuries who are about to embark on extensive travel in cold environments.

  9. FOREST COVER INFLUENCES DISPERSAL DISTANCE OF WHITE-TAILED DEER

    National Research Council Canada - National Science Library

    Eric S. Long; Duane R. Diefenbach; Christopher S. Rosenberry; Bret D. Wallingford; Marrett D. Grund

    2005-01-01

    ...) in 2 study areas in Pennsylvania. By using a meta-analysis approach, we compared dispersal rates and distances from these populations together with published reports of 10 other nonmigratory populations of white-tailed deer...

  10. Optimal Investment in Structured Bonds

    DEFF Research Database (Denmark)

    Jessen, Pernille; Jørgensen, Peter Løchte

    The paper examines the role of structured bonds in the optimal portfolio of a small retail investor. We consider the typical structured bond essentially repacking an exotic option and a zero coupon bond, i.e. an investment with portfolio insurance. The optimal portfolio is found when the investment...... opportunities consist of a risky reference fund, a risk-free asset and a structured bond. Key model elements are the trading strategy and utility function of the investor. Our numerical results indicate structured bonds do have basis for consideration in the optimal portfolio. The product holdings...

  11. Distance Learning for Special Populations

    Science.gov (United States)

    Bates, Rodger A.

    2012-01-01

    Distance education strategies for remotely deployed, highly mobile, or institutionalized populations are reviewed and critiqued. Specifically, asynchronous, offline responses for special military units, Native Americans on remote reservations, prison populations and other geographically, temporally or technologically isolated niche populations are…

  12. ECONOMICS OF DISTANCE EDUCATION RECONSIDERED

    Directory of Open Access Journals (Sweden)

    Wolfram LAASER

    2008-07-01

    Full Text Available ABSTRACT According to Gartner a certain hype of e-Learning was followed by a downturn but eLearning will continue to be an important factor in learning scenarios. However the economic viability of e-learning projects will be questioned with more scrutiny than in earlier periods. Therefore it seems to be a good opportunity to see what can be learned from past experience in costing distance learning projects and what aspects are added by current attempts to measure economic efficiency. After reviewing early research about costing distance learning some more recent approaches will be discussed, such as eLearning ROI-calculators and the concept of total cost of ownership. Furthermore some microeconomic effects referring to localization of distance learning courses are outlined. Finally several unsolved issues in costing distance education are summarized.

  13. Distance Education in Technological Age

    Directory of Open Access Journals (Sweden)

    R .C. SHARMA

    2005-04-01

    Full Text Available Distance Education in Technological AgeRomesh Verma (Editor, New Delhi: Anmol Publications, 2005, ISBN 81-261-2210-2, pp. 419 Reviewed by R C SHARMARegional DirectorIndira Gandhi National Open University-INDIA The advancements in information and communication technologies have brought significant changes in the way the open and distance learning are provided to the learners. The impact of such changes is quite visible in both developed and developing countries. Switching over to online mode, joining hands with private initiatives and making a presence in foreign waters, are some of the hallmarks of the open and distance education (ODE institutions in developing countries. The compilation of twenty six essays on themes as applicable to ODE has resulted in the book, “Distance Education in Technological Age”. These essays follow a progressive style of narration, starting from describing conceptual framework of distance education, how the distance education was emerged on the global scene and in India, and then goes on to discuss emergence of online distance education and research aspects in ODE. The initial four chapters provide a detailed account of historical development and growth of distance education in India and State Open University and National Open University Model in India . Student support services are pivot to any distance education and much of its success depends on how well the support services are provided. These are discussed from national and international perspective. The issues of collaborative learning, learning on demand, life long learning, learning-unlearning and re-learning model and strategic alliances have also given due space by the authors. An assortment of technologies like communication technology, domestic technology, information technology, mass media and entertainment technology, media technology and educational technology give an idea of how these technologies are being adopted in the open universities. The study

  14. KNOWLEDGE DISTANCE IN INFORMATION SYSTEMS

    Institute of Scientific and Technical Information of China (English)

    Yuhua QIAN; Jiye LIANG; Chuangyin DANG; Feng WANG; Wei XU

    2007-01-01

    In this paper, we first introduce the concepts of knowledge closeness and knowledge distance for measuring the sameness and the difference among knowledge in an information system, respectively.The relationship between these two concepts is a strictly mutual complement relation. We then investigate some important properties of knowledge distance and perform experimental analyses on two public data sets, which show the presented measure appears to be well suited to characterize the nature of knowledge in an information system. Finally, we establish the relationship between the knowledge distance and knowledge granulation, which shows that two variants of the knowledge distance can also be used to construct the knowledge granulation. These results will be helpful for studying uncertainty in information systems.

  15. Graph distance for complex networks

    Science.gov (United States)

    Shimada, Yutaka; Hirata, Yoshito; Ikeguchi, Tohru; Aihara, Kazuyuki

    2016-10-01

    Networks are widely used as a tool for describing diverse real complex systems and have been successfully applied to many fields. The distance between networks is one of the most fundamental concepts for properly classifying real networks, detecting temporal changes in network structures, and effectively predicting their temporal evolution. However, this distance has rarely been discussed in the theory of complex networks. Here, we propose a graph distance between networks based on a Laplacian matrix that reflects the structural and dynamical properties of networked dynamical systems. Our results indicate that the Laplacian-based graph distance effectively quantifies the structural difference between complex networks. We further show that our approach successfully elucidates the temporal properties underlying temporal networks observed in the context of face-to-face human interactions.

  16. Are contemporary tourists consuming distance?

    DEFF Research Database (Denmark)

    Larsen, Gunvor Riber

    2012. Background The background for this research, which explores how tourists represent distance and whether or not distance can be said to be consumed by contemporary tourists, is the increasing leisure mobility of people. Travelling for the purpose of visiting friends and relatives is increasing...... of understanding mobility at a conceptual level, and distance matters to people's manifest mobility: how they travel and how far they travel are central elements of their movements. Therefore leisure mobility (indeed all mobility) is the activity of relating across distance, either through actual corporeal...... that is an inherent part of manifest mobility. Numerous definitions and conceptualisations of tourism have been discussed over the years, with MacCannell (1976) pioneering studies of tourism and leisure travel through to Lash and Urry's (1994) post tourist and Jansson's (2002) hyper-tourist. These definitions...

  17. Academy Distance Learning Tools (IRIS)

    Data.gov (United States)

    Department of Transportation — IRIS is a suite of front-end web applications utilizing a centralized back-end Oracle database. The system fully supports the FAA Academy's Distance Learning Program...

  18. On some hydrogen bond correlations at high pressures

    Science.gov (United States)

    Sikka, S. K.

    2007-09-01

    In situ high pressure neutron diffraction measured lengths of O H and H O pairs in hydrogen bonds in substances are shown to follow the correlation between them established from 0.1 MPa data on different chemical compounds. In particular, the conclusion by Nelmes et al that their high pressure data on ice VIII differ from it is not supported. For compounds in which the O H stretching frequencies red shift under pressure, it is shown that wherever structural data is available, they follow the stretching frequency versus H O (or O O) distance correlation. For compounds displaying blue shifts with pressure an analogy appears to exist with improper hydrogen bonds.

  19. Distance education: turf and technology.

    Science.gov (United States)

    Pickard, M R

    1992-07-01

    Distance learning fits with the mission and strategic plan of the University of Texas at Arlington. We believe these educational opportunities in nursing are highly desirable. The Board of Nurse Examiners for the State of Texas has approved this project and the Texas Higher Education Coordinating Board has approved it as a pilot project. The school will continue evaluation and creative problem-solving in the use of distance education.

  20. Categorical perception of tactile distance

    OpenAIRE

    Knight, F. L. C.; Longo, M. R.; Bremner, A.J.

    2014-01-01

    The tactile surface forms a continuous sheet covering the body. And yet, the perceived distance between two touches varies across stimulation sites. Perceived tactile distance is larger when stimuli cross over the wrist, compared to when both fall on either the hand or the forearm. This effect could reflect a categorical distortion of tactile space across body-part boundaries (in which stimuli crossing the wrist boundary are perceptually elongated) or may simply reflect a localised increased ...

  1. Categorical perception of tactile distance.

    Science.gov (United States)

    Knight, Frances Le Cornu; Longo, Matthew R; Bremner, Andrew J

    2014-05-01

    The tactile surface forms a continuous sheet covering the body. And yet, the perceived distance between two touches varies across stimulation sites. Perceived tactile distance is larger when stimuli cross over the wrist, compared to when both fall on either the hand or the forearm. This effect could reflect a categorical distortion of tactile space across body-part boundaries (in which stimuli crossing the wrist boundary are perceptually elongated) or may simply reflect a localised increased in acuity surrounding anatomical landmarks (in which stimuli near the wrist are perceptually elongated). We tested these two interpretations across two experiments, by comparing a well-documented bias to perceive mediolateral tactile distances across the forearm/hand as larger than proximodistal ones along the forearm/hand at three different sites (hand, wrist, and forearm). According to the 'categorical' interpretation, tactile distances should be elongated selectively in the proximodistal axis thus reducing the anisotropy. According to the 'localised acuity' interpretation, distances will be perceptually elongated in the vicinity of the wrist regardless of orientation, leading to increased overall size without affecting anisotropy. Consistent with the categorical account, we found a reduction in the magnitude of anisotropy at the wrist, with no evidence of a corresponding localised increase in precision. These findings demonstrate that we reference touch to a representation of the body that is categorically segmented into discrete parts, which consequently influences the perception of tactile distance.

  2. Bond strength of direct and indirect bonded brackets after thermocycling.

    Science.gov (United States)

    Daub, Jacob; Berzins, David W; Linn, Brandon James; Bradley, Thomas Gerard

    2006-03-01

    Thermocycling simulates the temperature dynamics in the oral environment. With direct bonding, thermocycling reduces the bond strength of orthodontic adhesives to tooth structure. The purpose of this study was to evaluate the shear bond strengths (SBS) of one direct and two indirect bonding methods/adhesives after thermocycling. Sixty human premolars were divided into three groups. Teeth in group 1 were bonded directly with Transbond XT. Teeth in group 2 were indirect bonded with Transbond XT/Sondhi Rapid Set, which is chemically cured. Teeth in group 3 were indirect bonded with Enlight LV/Orthosolo and light cured. Each sample was thermocycled between 5 degrees C and 55 degrees C for 500 cycles. Mean SBS in groups 1, 2, and 3 were not statistically significantly different (13.6 +/- 2.9, 12.3 +/- 3.0, and 11.6 +/- 3.2 MPa, respectively; P > .05). However, when these values were compared with the results of a previous study using the same protocol, but without thermocycling, the SBS was reduced significantly (P = .001). Weibull analysis further showed that group 3 had the lowest bonding survival rate at the minimum clinically acceptable bond-strength range. The Adhesive Remnant Index was also determined, and group 2 had a significantly (P bond failures at the resin/enamel interface.

  3. A History of the Double-Bond Rule

    Science.gov (United States)

    Hoogenboom, Bernard E.

    1998-05-01

    The tautomeric polar systems recognized by Laar in 1886 contain an active atom that appeared to migrate from its original position. The tautomeric systems are of a general structural form and can be represented as X=Y-Z-A. Later workers recognized the same bond weakening effect in a variety of organic structures in which atom A is halogen, hydrogen, carbon, or nitrogen. Hermann Staudinger recognized the weakness of that bond, an allyl bond, in hydrocarbons and exploited the behavior for the preparation of isoprene from terpene hydrocarbons. In 1922 he formulated a generality, a rule, regarding the allyl bond reactivity He noted that natural rubber also decomposed to form isoprene and therefore concluded that natural rubber is an unsaturated hydrocarbon, that isoprene units in natural rubber represent weakly held allyl substituents, and that natural rubber is a macromolecular combination of isoprene units. From his different experience as an industrial chemist, Otto Schmidt recognized the same bond weakening effect in hydrocarbons and in 1932 postulated the "Double-Bond Rule," stating that the presence of a double bond in a hydrocarbon has an alternating strengthening and weakening effect on single bonds throughout the molecule, diminishing with distance from the double bond. Schmidt not only understood the practical benefit of this rule, but he also offered an explanation for the Rule on theoretical grounds. Novel in its time, his theoretical explanation did not find popular acceptance, despite his considerable efforts to promote it in the literature. His concept of the Rule was supplanted by the new theory of resonance devised by Pauling and Wheland and by the implied notion of the stabilization of products by delocalization effects.

  4. Distance Education in Asia and the Pacific. Volume II. Proceedings of the Regional Seminar on Distance Education (Bangkok, Thailand, November 26-December 3, 1986).

    Science.gov (United States)

    Asian Development Bank, Manila (Philippines).

    The paper presented in this three-part conference report trace the growth and development of distance education in the Asian and Pacific region. Part 1 provides a general review. Part 2 contains the following case studies: "Distance Education in India" (S. P. Mullick); "Distance Education in Indonesia" (Professor Setijadi);…

  5. Bonding and structure of copper nitrenes.

    Science.gov (United States)

    Cundari, Thomas R; Dinescu, Adriana; Kazi, Abul B

    2008-11-03

    Copper nitrenes are of interest as intermediates in the catalytic aziridination of olefins and the amination of C-H bonds. However, despite advances in the isolation and study of late-transition-metal multiply bonded complexes, a bona fide structurally characterized example of a terminal copper nitrene has, to our knowledge, not been reported. In anticipation of such a report, terminal copper nitrenes are studied from a computational perspective. The nitrene complexes studied here are of the form (beta-diketiminate)Cu(NPh). Density functional theory (DFT), complete active space self-consistent-field (CASSCF) electronic structure techniques, and hybrid quantum mechanical/molecular mechanical (QM/MM) methods are employed to study such species. While DFT methods indicate that a triplet (S = 1) is the ground state, CASSCF calculations indicate that a singlet (S = 0) is the ground state, with only a small energy gap between the singlet and triplet. Moreover, the ground-state (open-shell) singlet copper nitrene is found to be highly multiconfigurational (i.e., biradical) and to possess a bent geometry about the nitrene nitrogen, contrasting with the linear nitrene geometry of the triplet copper nitrenes. CASSCF calculations also reveal the existence of a closed-shell singlet state with some degree of multiple bonding character for the copper-nitrene bond.

  6. The representation of object distance: evidence from neuroimaging and neuropsychology

    Directory of Open Access Journals (Sweden)

    Marian Berryhill

    2009-11-01

    Full Text Available Perceived distance in two-dimensional images relies on monocular distance cues. Here, we examined the representation of perceived object distance using a continuous carry-over adaptation design for fMRI. The task was to look at photographs of objects and make a judgment as to whether or not the item belonged in the kitchen. Importantly, this task was orthogonal to the variable of interest: the object’s perceived distance from the viewer. In Experiment 1, whole brain group analyses identified bilateral clusters in the superior occipital gyrus (approximately area V3/V3A that showed parametric adaptation to relative changes in perceived distance. In Experiment 2, retinotopic analyses confirmed that area V3A/B reflected the greatest magnitude of response to monocular changes in perceived distance. In Experiment 3, we report that the functional activations overlap with the occipito-parietal lesions in a patient with impaired distance perception, showing that the same regions monitor implied (two-dimensional and actual (three-dimensional distance. These data suggest that distance information is automatically processed even when it is task-irrelevant and that this process relies on superior occipital areas in and around area V3A.

  7. Changing the bonding force of impression tray to edentulous ...

    African Journals Online (AJOL)

    Key words: Bonding force, impression tray, maxillary jaw. Date of Acceptance: ... The purpose of complete dentures is to restore the dental and alveolar structures. ... A review of the literature revealed a lack of reports evaluating the pressure ...

  8. A New Palladium-Catalyzed Phenyl-Alkene Bond Formation

    Directory of Open Access Journals (Sweden)

    René Roy

    2002-05-01

    Full Text Available A new method of palladium-catalyzed phenyl-alkene bond formation is reported. This reaction involves transfer of all three phenyl groups from triphenylantimony onto alkenes containing allylic protons.

  9. Center—Distance Continuous Probability Models and the Distance Measure

    Institute of Scientific and Technical Information of China (English)

    郑方; 吴文虎; 等

    1998-01-01

    In this paper,a new statistic model named Center-Distance Continuous Probability Model(CDCPM)for speech recognition is described,which is based on Center-Distance Normal(CDN)distribution.In a CDCPM,the probability transition matrix is omitted,and the observation probability density function(PDF)in each state is in the form of embedded multiple-model(EMM)based on the Nearest Neighbour rule.The experimental results on two giant real-world Chinese speech databases and a real-world continuous-manner 2000 phrase system show that this model is a powerful one.Also,a distance measure for CDPMs is proposed which is based on the Bayesian minimum classification error(MCE) discrimination.

  10. Perception of light source distance from shading patterns.

    Science.gov (United States)

    Schütt, Heiko H; Baier, Franziska; Fleming, Roland W

    2016-01-01

    Varying the distance of a light source from an object alters both the intensity and spatial distribution of surface shading patterns. We tested whether observers can use such cues to infer light source distance. Participants viewed stereoscopic renderings of rough objects with diffuse and glossy surfaces, which were illuminated by a point source at a range of distances. In one task, they adjusted the position of a small probe dot in three dimensions to report the apparent location of the light in the scene. In a second task, they adjusted the shading on one object (by moving an invisible light source) until it appeared to be illuminated from the same distance as another object. Participants' responses increased linearly with the true light source distance, suggesting that they have clear intuitions about how light source distance affects shading patterns for a variety of different surfaces. However, there were also systematic errors: Subjects overestimated light source distance in the probe adjustment task, and in both experiments, roughness and glossiness affected responses. We find the pattern of results is predicted surprisingly well by a simplistic model based only on the area of the image that exceeds a certain intensity threshold. Thus, although subjects can report light source distance, they may rely on simple--sometimes erroneous--heuristics to do so.

  11. Perception of Egocentric Distance during Gravitational Changes in Parabolic Flight.

    Directory of Open Access Journals (Sweden)

    Gilles Clément

    Full Text Available We explored the effect of gravity on the perceived representation of the absolute distance of objects to the observers within the range from 1.5-6 m. Experiments were performed on board the CNES Airbus Zero-G during parabolic flights eliciting repeated exposures to short periods of microgravity (0 g, hypergravity (1.8 g, and normal gravity (1 g. Two methods for obtaining estimates of perceived egocentric distance were used: verbal reports and visually directed motion toward a memorized visual target. For the latter method, because normal walking is not possible in 0 g, blindfolded subjects translated toward the visual target by pulling on a rope with their arms. The results showed that distance estimates using both verbal reports and blind pulling were significantly different between normal gravity, microgravity, and hypergravity. Compared to the 1 g measurements, the estimates of perceived distance using blind pulling were shorter for all distances in 1.8 g, whereas in 0 g they were longer for distances up to 4 m and shorter for distances beyond. These findings suggest that gravity plays a role in both the sensorimotor system and the perceptual/cognitive system for estimating egocentric distance.

  12. Perception of Egocentric Distance during Gravitational Changes in Parabolic Flight.

    Science.gov (United States)

    Clément, Gilles; Loureiro, Nuno; Sousa, Duarte; Zandvliet, Andre

    2016-01-01

    We explored the effect of gravity on the perceived representation of the absolute distance of objects to the observers within the range from 1.5-6 m. Experiments were performed on board the CNES Airbus Zero-G during parabolic flights eliciting repeated exposures to short periods of microgravity (0 g), hypergravity (1.8 g), and normal gravity (1 g). Two methods for obtaining estimates of perceived egocentric distance were used: verbal reports and visually directed motion toward a memorized visual target. For the latter method, because normal walking is not possible in 0 g, blindfolded subjects translated toward the visual target by pulling on a rope with their arms. The results showed that distance estimates using both verbal reports and blind pulling were significantly different between normal gravity, microgravity, and hypergravity. Compared to the 1 g measurements, the estimates of perceived distance using blind pulling were shorter for all distances in 1.8 g, whereas in 0 g they were longer for distances up to 4 m and shorter for distances beyond. These findings suggest that gravity plays a role in both the sensorimotor system and the perceptual/cognitive system for estimating egocentric distance.

  13. Distance perception in mild traumatic brain injury (mTBI).

    Science.gov (United States)

    Ciuffreda, Kenneth J; Yadav, Naveen K; Han, Esther; Ludlam, Diana P; Peddle, Angela; Hulse, Paul; Walter, Suzanne; Han, Jennifer

    2012-04-30

    The purpose of this study was to assess monocular and binocular distance perception, and stereoacuity, in individuals with mild traumatic brain injury (mTBI) who reported the symptom of "poor depth perception"; Ten patients with mTBI were tested and compared with ten visually-normal asymptomatic individuals in the following areas: perceived distance, stereoacuity at distance (3 meters) and near (40 cm), and a 9-item 5-point rating-scale questionnaire related to distance perception. Distance perception was assessed under monocular and binocular viewing conditions in both clustered and isolated static environments. Magnitude estimation was used to obtain the distance perception response function of physical versus perceived distance using common objects positioned at distances of 0.77 to 12.84 meters. The mean distance perception response function slopes were not significantly different in the two groups for any of the test conditions. Stereoacuity (sec arc) was slightly reduced at both near and distance in the individuals with mTBI (36 ± 24.58 and 84 ± 68.34, respectively) as compared with the normal subjects (20 ± 0 and 51 ± 9.93, respectively). The mTBI group mean symptom score was 3.24 ± 0.26 indicating a moderate problematic level; Similarity of the mean distance response functions in the mTBI group under monocular and binocular viewing conditions suggested that their misperception of distance was not due to a "binocular vergence" problem. Similarly, the slightly reduced stereoacuity in the mTBI group was not sufficient to explain their symptom of "poor depth perception." Thus, it is speculated that this problem reflects a higher-level cortical perceptual phenomenon related to diffuse brain damage in areas dealing with visuo-spatial mapping. American Optometric Association.

  14. Bond strength with custom base indirect bonding techniques.

    Science.gov (United States)

    Klocke, Arndt; Shi, Jianmin; Kahl-Nieke, Bärbel; Bismayer, Ulrich

    2003-04-01

    Different types of adhesives for indirect bonding techniques have been introduced recently. But there is limited information regarding bond strength with these new materials. In this in vitro investigation, stainless steel brackets were bonded to 100 permanent bovine incisors using the Thomas technique, the modified Thomas technique, and light-cured direct bonding for a control group. The following five groups of 20 teeth each were formed: (1) modified Thomas technique with thermally cured base composite (Therma Cure) and chemically cured sealant (Maximum Cure), (2) Thomas technique with thermally cured base composite (Therma Cure) and chemically cured sealant (Custom I Q), (3) Thomas technique with light-cured base composite (Transbond XT) and chemically cured sealant (Sondhi Rapid Set), (4) modified Thomas technique with chemically cured base adhesive (Phase II) and chemically cured sealant (Maximum Cure), and (5) control group directly bonded with light-cured adhesive (Transbond XT). Mean bond strengths in groups 3, 4, and 5 were 14.99 +/- 2.85, 15.41 +/- 3.21, and 13.88 +/- 2.33 MPa, respectively, and these groups were not significantly different from each other. Groups 1 (mean bond strength 7.28 +/- 4.88 MPa) and 2 (mean bond strength 7.07 +/- 4.11 MPa) showed significantly lower bond strengths than groups 3, 4, and 5 and a higher probability of bond failure. Both the original (group 2) and the modified (group 1) Thomas technique were able to achieve bond strengths comparable to the light-cured direct bonded control group.

  15. Cocrystals of 1,4-diethynylbenzene with 1,3-diacetylbenzene and benzene-1,4-dicarbaldehyde exhibiting strong nonconventional alkyne-carbonyl C-H...O hydrogen bonds between the components.

    Science.gov (United States)

    Bosch, Eric

    2016-10-01

    Weak interactions between organic molecules are important in solid-state structures where the sum of the weaker interactions support the overall three-dimensional crystal structure. The sp-C-H...N hydrogen-bonding interaction is strong enough to promote the deliberate cocrystallization of a series of diynes with a series of dipyridines. It is also possible that a similar series of cocrystals could be formed between molecules containing a terminal alkyne and molecules which contain carbonyl O atoms as the potential hydrogen-bond acceptor. I now report the crystal structure of two cocrystals that support this hypothesis. The 1:1 cocrystal of 1,4-diethynylbenzene with 1,3-diacetylbenzene, C10H6·C10H10O2, (1), and the 1:1 cocrystal of 1,4-diethynylbenzene with benzene-1,4-dicarbaldehyde, C10H6·C8H6O2, (2), are presented. In both cocrystals, a strong nonconventional ethynyl-carbonyl sp-C-H...O hydrogen bond is observed between the components. In cocrystal (1), the C-H...O hydrogen-bond angle is 171.8 (16)° and the H...O and C...O hydrogen-bond distances are 2.200 (19) and 3.139 (2) Å, respectively. In cocrystal (2), the C-H...O hydrogen-bond angle is 172.5 (16)° and the H...O and C...O hydrogen-bond distances are 2.25 (2) and 3.203 (2) Å, respectively.

  16. 27 CFR 28.66 - Strengthening bonds.

    Science.gov (United States)

    2010-04-01

    ... bonds. In all cases where the penal sum of any bond becomes insufficient, the principal shall either give a strengthening bond with the same surety to attain a sufficient penal sum, or give a new bond to... of any bond to less than its full penal sum. Strengthening bonds shall show the current date...

  17. Conceptualizing Educational Research in Distance Education.

    Science.gov (United States)

    Watkins, Ryan; Schlosser, Charles

    2003-01-01

    Suggests a starting place for formal inquiry into distance education. Topics covered include: background on educational research and research on distance education; research paradigms that are applicable to distance education; subsystems of a distance education program; and a matrix for conceptualizing distance education research. (MES)

  18. Halogen Bonding: An AIM Analysis of the Weak Interactions

    Institute of Scientific and Technical Information of China (English)

    ZOU, Jian-Wei; LU, Yun-Xiang; YU, Qing-Sen; ZHANG, Hua-Xin; JIANG, Yong-Jun

    2006-01-01

    A series of complexes formed between halogen-containing molecules and ammonia have been investigated by means of the atoms in molecules (AIM) approach to gain a deeper insight into halogen bonding. The existence of the halogen bond critical points (XBCP) and the values of the electron density (ρb) and Laplacian of electron density (▽2pb) at the XBCP reveal the closed-shell interactions in these complexes. Integrated atomic properties such as charge, energy, polarization moment, volume of the halogen bond donor atoms, and the corresponding changes (△) upon complexation have been calculated. The present calculations have demonstrated that the halogen bond represents different AIM properties as compared to the well-documented hydrogen bond. Both the electron density and the Laplacian of electron density at the XBCP have been shown to correlate well with the interaction energy, which indicates that the topological parameters at the XBCP can be treated as a good measure of the halogen bond strength.In addition, an excellent linear relationship between the interatomic distance d(X…N) and the logarithm of ρb has been established.

  19. How many hydrogen-bonded α-turns are possible?

    Science.gov (United States)

    Schreiber, Anette; Schramm, Peter; Hofmann, Hans-Jörg

    2011-06-01

    The formation of α-turns is a possibility to reverse the direction of peptide sequences via five amino acids. In this paper, a systematic conformational analysis was performed to find the possible isolated α-turns with a hydrogen bond between the first and fifth amino acid employing the methods of ab initio MO theory in vacuum (HF/6-31G*, B3LYP/6-311 + G*) and in solution (CPCM/HF/6-31G*). Only few α-turn structures with glycine and alanine backbones fulfill the geometry criteria for the i←(i + 4) hydrogen bond satisfactorily. The most stable representatives agree with structures found in the Protein Data Bank. There is a general tendency to form additional hydrogen bonds for smaller pseudocycles corresponding to β- and γ-turns with better hydrogen bond geometries. Sometimes, this competition weakens or even destroys the i←(i + 4) hydrogen bond leading to very stable double β-turn structures. This is also the reason why an "ideal" α-turn with three central amino acids having the perfect backbone angle values of an α-helix could not be localized. There are numerous hints for stable α-turns with a distance between the C(α)-atoms of the first and fifth amino acid smaller than 6-7 Å, but without an i←(i + 4) hydrogen bond.

  20. Computing Distances between Probabilistic Automata

    Directory of Open Access Journals (Sweden)

    Mathieu Tracol

    2011-07-01

    Full Text Available We present relaxed notions of simulation and bisimulation on Probabilistic Automata (PA, that allow some error epsilon. When epsilon is zero we retrieve the usual notions of bisimulation and simulation on PAs. We give logical characterisations of these notions by choosing suitable logics which differ from the elementary ones, L with negation and L without negation, by the modal operator. Using flow networks, we show how to compute the relations in PTIME. This allows the definition of an efficiently computable non-discounted distance between the states of a PA. A natural modification of this distance is introduced, to obtain a discounted distance, which weakens the influence of long term transitions. We compare our notions of distance to others previously defined and illustrate our approach on various examples. We also show that our distance is not expansive with respect to process algebra operators. Although L without negation is a suitable logic to characterise epsilon-(bisimulation on deterministic PAs, it is not for general PAs; interestingly, we prove that it does characterise weaker notions, called a priori epsilon-(bisimulation, which we prove to be NP-difficult to decide.

  1. Distance sampling methods and applications

    CERN Document Server

    Buckland, S T; Marques, T A; Oedekoven, C S

    2015-01-01

    In this book, the authors cover the basic methods and advances within distance sampling that are most valuable to practitioners and in ecology more broadly. This is the fourth book dedicated to distance sampling. In the decade since the last book published, there have been a number of new developments. The intervening years have also shown which advances are of most use. This self-contained book covers topics from the previous publications, while also including recent developments in method, software and application. Distance sampling refers to a suite of methods, including line and point transect sampling, in which animal density or abundance is estimated from a sample of distances to detected individuals. The book illustrates these methods through case studies; data sets and computer code are supplied to readers through the book’s accompanying website.  Some of the case studies use the software Distance, while others use R code. The book is in three parts.  The first part addresses basic methods, the ...

  2. Individual differences in distance perception.

    Science.gov (United States)

    Jackson, Russell E

    2009-05-07

    Distance perception is among the most pervasive mental phenomena and the oldest research topics in behavioural science. However, we do not understand well the most pervasive finding of distance perception research, that of large individual differences. There are large individual differences in acrophobia (fear of heights), which we commonly assume consists of an abnormal fear of stimuli perceived normally. Evolved navigation theory (ENT) instead suggests that acrophobia consists of a more normal fear of stimuli perceived abnormally. ENT suggests that distance perception individual differences produce major components of acrophobia. Acrophobia tested over a broad range in the present study predicted large individual differences in distance estimation of surfaces that could produce falls. This fear of heights correlated positively with distance estimates of a vertical surface-even among non-acrophobic individuals at no risk of falling and without knowledge of being tested for acrophobia. Acrophobia score predicted magnitude of the descent illusion, which is thought to reflect the risk of falling. These data hold important implications in environmental navigation, clinical aetiology and the evolution of visual systems.

  3. Halogen bonding interactions between brominated ion pairs and CO2 molecules: implications for design of new and efficient ionic liquids for CO2 absorption.

    Science.gov (United States)

    Zhu, Xiang; Lu, Yunxiang; Peng, Changjun; Hu, Jun; Liu, Honglai; Hu, Ying

    2011-04-14

    In recent years, several novel halogenated liquids with characteristics of ionic liquids (ILs) were reported. To explore their performance in the absorption of CO(2), in this work, quantum chemical calculations at DFT level have been carried out to investigate halogen bonding interactions between experimentally available brominated ion pairs and CO(2) molecules. It is shown that, as compared to B3LYP, the functional PBE yields geometrical and energetic data more close to those of MP2 for cation-CO(2) systems. The cation of brominated ILs under study can interact with CO(2) molecules through Br···O interactions, possibly making an important impact on the physical solubility of CO(2) in brominated ILs. The optimized geometries of the complexes of the ion pair with CO(2) molecules are quite similar to those of the corresponding complexes of the cation, especially for the essentially linear C-Br···O contacts. However, much weaker halogen bonds are predicted in the former systems, as indicated by the longer intermolecular distances and the smaller interaction energies. Charges derived from NBO analysis reveal the origin of the different optimized conformations and halogen bonding interactions for the CO(2) molecule. Based on the electrostatic potential results, the substitution of hydrogen atoms with fluorine atoms constituting the cation is then applied to enhance halogen bond strength. The QTAIM analysis further validates the existence of halogen bonding interaction in all complexes. The topological properties at the halogen bond critical points indicate that the Br···O interactions in the complexes are basically electrostatic in nature and belong to conventional weak halogen bonds. This study would be helpful for designing new and effective ILs for CO(2) physical absorption.

  4. Bond length, dipole moment, and harmonic frequency of CO

    Science.gov (United States)

    Barnes, Leslie A.; Liu, Bowen; Lindh, Roland

    1993-01-01

    A detailed comparison of some properties of CO is given, at the modified coupled-pair functional, single and double excitation coupled-cluster (CCSD), and CCSD(T) levels of theory (including a perturbational estimate for connected triple excitations), using a variety of basis sets. With very large one-particle basis sets, the CCSD(T) method gives excellent results for the bond distance, dipole moment, and harmonic frequency of CO. In a (6s 5p 4d 3f 2g 1h) + (1s 1p 1d) basis set, the bond distance is about 0.005a0 too large, the dipole moment about 0.005 a.u. too small, and the frequency about 6/cm too small, when compared with experimental results.

  5. Asymmetric distances for binary embeddings.

    Science.gov (United States)

    Gordo, Albert; Perronnin, Florent; Gong, Yunchao; Lazebnik, Svetlana

    2014-01-01

    In large-scale query-by-example retrieval, embedding image signatures in a binary space offers two benefits: data compression and search efficiency. While most embedding algorithms binarize both query and database signatures, it has been noted that this is not strictly a requirement. Indeed, asymmetric schemes that binarize the database signatures but not the query still enjoy the same two benefits but may provide superior accuracy. In this work, we propose two general asymmetric distances that are applicable to a wide variety of embedding techniques including locality sensitive hashing (LSH), locality sensitive binary codes (LSBC), spectral hashing (SH), PCA embedding (PCAE), PCAE with random rotations (PCAE-RR), and PCAE with iterative quantization (PCAE-ITQ). We experiment on four public benchmarks containing up to 1M images and show that the proposed asymmetric distances consistently lead to large improvements over the symmetric Hamming distance for all binary embedding techniques.

  6. Ghost imaging with broad distance

    Institute of Scientific and Technical Information of China (English)

    段德洋; 张路; 杜少将; 夏云杰

    2015-01-01

    We present a scheme that is able to achieve the ghost imaging with broad distance. The physical nature of our scheme is that the different wavelength beams are separated in free space by an optical media according to the slow light or dispersion principle. Meanwhile, the equality of the optical distance of the two light arms is not violated. The photon correlation is achieved by the rotating ground glass plate (RGGP) and spatial light modulator (SLM), respectively. Our work shows that a monochromic ghost image can be obtained in the case of RGGP. More importantly, the position (or distance) of the object can be ascertained by the color of the image. Thus, the imaging and ranging processes are combined as one process for the first time to the best of our knowledge. In the case of SLM, we can obtain a colored image regardless of where the object is.

  7. Euclidean distance geometry an introduction

    CERN Document Server

    Liberti, Leo

    2017-01-01

    This textbook, the first of its kind, presents the fundamentals of distance geometry:  theory, useful methodologies for obtaining solutions, and real world applications. Concise proofs are given and step-by-step algorithms for solving fundamental problems efficiently and precisely are presented in Mathematica®, enabling the reader to experiment with concepts and methods as they are introduced. Descriptive graphics, examples, and problems, accompany the real gems of the text, namely the applications in visualization of graphs, localization of sensor networks, protein conformation from distance data, clock synchronization protocols, robotics, and control of unmanned underwater vehicles, to name several.  Aimed at intermediate undergraduates, beginning graduate students, researchers, and practitioners, the reader with a basic knowledge of linear algebra will gain an understanding of the basic theories of distance geometry and why they work in real life.

  8. Virtual bioinformatics distance learning suite*.

    Science.gov (United States)

    Tolvanen, Martti; Vihinen, Mauno

    2004-05-01

    Distance learning as a computer-aided concept allows students to take courses from anywhere at any time. In bioinformatics, computers are needed to collect, store, process, and analyze massive amounts of biological and biomedical data. We have applied the concept of distance learning in virtual bioinformatics to provide university course material over the Internet. Currently, we provide two fully computer-based courses, "Introduction to Bioinformatics" and "Bioinformatics in Functional Genomics." Here we will discuss the application of distance learning in bioinformatics training and our experiences gained during the 3 years that we have run the courses, with about 400 students from a number of universities. The courses are available at bioinf.uta.fi.

  9. The Distance Geometry of Music

    CERN Document Server

    Demaine, Erik D; Meijer, Henk; Rappaport, David; Taslakian, Perouz; Toussaint, Godfried T; Winograd, Terry; Wood, David R

    2007-01-01

    We demonstrate relationships between the classic Euclidean algorithm and many other fields of study, particularly in the context of music and distance geometry. Specifically, we show how the structure of the Euclidean algorithm defines a family of rhythms which encompass over forty timelines (\\emph{ostinatos}) from traditional world music. We prove that these \\emph{Euclidean rhythms} have the mathematical property that their onset patterns are distributed as evenly as possible: they maximize the sum of the Euclidean distances between all pairs of onsets, viewing onsets as points on a circle. Indeed, Euclidean rhythms are the unique rhythms that maximize this notion of \\emph{evenness}. We also show that essentially all Euclidean rhythms are \\emph{deep}: each distinct distance between onsets occurs with a unique multiplicity, and these multiplicies form an interval $1,2,...,k-1$. Finally, we characterize all deep rhythms, showing that they form a subclass of generated rhythms, which in turn proves a useful prop...

  10. BOOK REVIEW BUILDING VIRTUAL COMMUNITIES OF PRACTICE FOR DISTANCE EDUCATORS

    Directory of Open Access Journals (Sweden)

    Gokhan Deniz DINCER

    2016-01-01

    Full Text Available Dr. M. Aaron Bond currently serves as the Director for Learning Design and Development for Networked Learning Design and Strategies (NLDS at Virginia Tech. He has worked in the field of instructional technology, distance education, and professional development for more than 15 years. He has earned A.A.S. from Virginia Western Community College in Education, a B.A. in History from Mary Baldwin College, an M.A. Interdisciplinary Studies from Fort Hayes State University, an Ed.S. Educational Leadership and Policy Studies from the University of Virginia, and a Ph.D. from Virginia Tech in Curriculum and Instruction. Dr. Bond has served as a corporate trainer, face-to-face classroom instructor, an online instructor, and a secondary principal.

  11. 27 CFR 18.63 - Record of transfer to a bonded wine cellar.

    Science.gov (United States)

    2010-04-01

    ... bonded wine cellar. 18.63 Section 18.63 Alcohol, Tobacco Products and Firearms ALCOHOL AND TOBACCO TAX... Records and Reports § 18.63 Record of transfer to a bonded wine cellar. A proprietor transferring concentrate, juice, or fruit mash to a bonded wine cellar shall prepare a record of transfer as required by...

  12. The Novel Selective Reduction of the C-C Triple Bond

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    A novel reduction system is reported here in which the compounds with terminal C-C triple bond and disubstituted C-C triple bond react with NaBH4/Pd(PPh3)4 in a base condition and only terminal C-C triple bond is reduced.

  13. The coefficient of bond thermal expansion measured by extended x-ray absorption fine structure.

    Science.gov (United States)

    Fornasini, P; Grisenti, R

    2014-10-28

    The bond thermal expansion is in principle different from the lattice expansion and can be measured by correlation sensitive probes such as extended x-ray absorption fine structure (EXAFS) and diffuse scattering. The temperature dependence of the coefficient α(bond)(T) of bond thermal expansion has been obtained from EXAFS for CdTe and for Cu. A coefficient α(tens)(T) of negative expansion due to tension effects has been calculated from the comparison of bond and lattice expansions. Negative lattice expansion is present in temperature intervals where α(bond) prevails over α(tens); this real-space approach is complementary but not equivalent to the Grüneisen theory. The relevance of taking into account the asymmetry of the nearest-neighbours distribution of distances in order to get reliable bond expansion values and the physical meaning of the third cumulant are thoroughly discussed.

  14. Adaptive Distance Protection for Microgrids

    DEFF Research Database (Denmark)

    Lin, Hengwei; Guerrero, Josep M.; Quintero, Juan Carlos Vasquez

    2015-01-01

    Due to the increasing penetration of distributed generation resources, more and more microgrids can be found in distribution systems. This paper proposes a phasor measurement unit based distance protection strategy for microgrids in distribution system. At the same time, transfer tripping scheme...... is adopted to accelerate the tripping speed of the relays on the weak lines. The protection methodology is tested on a mid-voltage microgrid network in Aalborg, Denmark. The results show that the adaptive distance protection methodology has good selectivity and sensitivity. What is more, this system also has...

  15. A simplified indirect bonding technique

    Directory of Open Access Journals (Sweden)

    Radha Katiyar

    2014-01-01

    Full Text Available With the advent of lingual orthodontics, indirect bonding technique has become an integral part of practice. It involves placement of brackets initially on the models and then their transfer to teeth with the help of transfer trays. Problems encountered with current indirect bonding techniques used are (1 the possibility of adhesive flash remaining around the base of the brackets which requires removal (2 longer time required for the adhesive to gain enough bond strength for secure tray removal. The new simplified indirect bonding technique presented here overcomes both these problems.

  16. Photoinduced hydrogen-bonding dynamics.

    Science.gov (United States)

    Chu, Tian-Shu; Xu, Jinmei

    2016-09-01

    Hydrogen bonding dynamics has received extensive research attention in recent years due to the significant advances in femtolaser spectroscopy experiments and quantum chemistry calculations. Usually, photoexcitation would cause changes in the hydrogen bonding formed through the interaction between hydrogen donor and acceptor molecules on their ground electronic states, and such transient strengthening or weakening of hydrogen bonding could be crucial for the photophysical transformations and the subsequent photochemical reactions that occurred on a time scale from tens of femtosecond to a few nanoseconds. In this article, we review the combined experimental and theoretical studies focusing on the ultrafast electronic and vibrational hydrogen bonding dynamics. Through these studies, new mechanisms and proposals and common rules have been put forward to advance our understanding of the hydrogen bondings dynamics in a variety of important photoinduced phenomena like photosynthesis, dual fluorescence emission, rotational reorientation, excited-state proton transfer and charge transfer processes, chemosensor fluorescence sensing, rearrangements of the hydrogen-bond network including forming and breaking hydrogen bond in water. Graphical Abstract We review the recent advances on exploring the photoinduced hydrogen bonding dynamics in solutions through a joint approach of laser spectroscopy and theoretical calculation. The reviewed studies have put forward a new mechanism, new proposal, and new rule for a variety of photoinduced phenomena such as photosynthesis, dual fluorescence emission, rotational reorientation, excited-state proton transfer and charge transfer, chemosensor fluorescence sensing, and rearrangements of the hydrogen-bond network in water.

  17. Wafer bonding applications and technology

    CERN Document Server

    Gösele, Ulrich

    2004-01-01

    During the past decade direct wafer bonding has developed into a mature materials integration technology. This book presents state-of-the-art reviews of the most important applications of wafer bonding written by experts from industry and academia. The topics include bonding-based fabrication methods of silicon-on-insulator, photonic crystals, VCSELs, SiGe-based FETs, MEMS together with hybrid integration and laser lift-off. The non-specialist will learn about the basics of wafer bonding and its various application areas, while the researcher in the field will find up-to-date information about this fast-moving area, including relevant patent information.

  18. Bond Growth under Temperature Gradient.

    Directory of Open Access Journals (Sweden)

    P.K. Satyawali

    1999-12-01

    Full Text Available Grain and bond growth for dry snow are determined by the distribution of temperature andtemperature gradient in the snow matrix. From the standpoint of particle approach and based oncubic packing structure, a bond growth model has been developed for TG metamorphism. The paper.highlights the importance of bond formation and its effect on snow viscosity and finally on the rateof settlement. This is very important for developing a numerical snow pack model if microstructureis considered to be a basic parameter. A few experiments have been carried out to validate bond formation under temperature gradient.

  19. Fast Exact Euclidean Distance (FEED) Transformation

    NARCIS (Netherlands)

    Schouten, Theo; Broek, van den Egon; Kittler, J.; Petrou, M.; Nixon, M.

    2004-01-01

    Fast Exact Euclidean Distance (FEED) transformation is introduced, starting from the inverse of the distance transformation. The prohibitive computational cost of a naive implementation of traditional Euclidean Distance Transformation, is tackled by three operations: restriction of both the number o

  20. X-ray targeted bond or compound destruction

    Energy Technology Data Exchange (ETDEWEB)

    Pravica, Sr., Michael G.

    2016-11-01

    This document provides methods, systems, and devices for inducing a decomposition reaction by directing x-rays towards a location including a particular compound. The x-rays can have an irradiation energy that corresponds to a bond distance of a bond in the particular compound in order to break that bond and induce a decomposition of that particular compound. In some cases, the particular compound is a hazardous substance or part of a hazardous substance. In some cases, the particular compound is delivered to a desired location in an organism and x-rays induce a decomposition reaction that creates a therapeutic substance (e.g., a toxin that kills cancer cells) in the location of the organism. In some cases, the particular compound decomposes to produce a reactant in a reactor apparatus (e.g., fuel cell or semiconductor fabricator).

  1. Reactive Bonding Film for Bonding Carbon Foam Through Metal Extrusion

    CERN Document Server

    Chertok, Maxwell; Irving, Michael; Neher, Christian; Tripathi, Mani; Wang, Ruby; Zheng, Gayle

    2016-01-01

    Future tracking detectors, such as those under development for the High Luminosity LHC, will require mechanical structures employing novel materials to reduce mass while providing excellent strength, thermal conductivity, and radiation tolerance. Adhesion methods for such materials are under study at present. This paper demonstrates the use of reactive bonding film as an adhesion method for bonding carbon foam.

  2. Digital Control of Bonding Force for Gold Wire Bonding Machine

    Directory of Open Access Journals (Sweden)

    Xiaochu Wang

    2013-01-01

    Full Text Available In order to digitally control the bonding force of a wire bonder precisely, this paper uses a DC solenoid as a force source, and by controlling the solenoid’s current, which causes the electromagnetic force, we can control the bonding force that capillary applies. The bonding force control system in this paper is composed of PC (Personal Computer and hypogyny MCU (Micro Controller Unit, which communicate using a RS485 interface. The digital value of a given bonding force is given by the PC to the MCU. By comparing the sampling current of the solenoid, and through PID regulation, D/A converter of the digital potentiometer and the solenoid driver circuit, the half-closed loop control system of bonding force is accomplished. Tuning of the PID parameters is accomplished with fuzzy adaptive control theory and simulated by Matlab simulink. The control system is tested by comparing the desired bonding force and the force actually applied and examming the relationship between bonding quality and bonding force.

  3. Distance Education with a Computerized Astronomy Laboratory

    Science.gov (United States)

    Connors, Martin

    1992-12-01

    Distance Education is the presentation of an educational curriculum through self-study materials supplemented by regular contact with an instructor. As such it is suitable for offering educational opportunities to students in widely dispersed locations typical of Canada. Since 1989 Athabasca University has offered Science 280, Introduction to Astronomy and Astrophysics, as a broad introduction to Astronomy at a pre-calculus level. The course includes a computer-based laboratory (observing simulation) set done in students' homes. The laboratory allows simulation of naked eye astronomical observations, starting with the motions of the sun and moon. The logical jump to motions not apparently centered on Earth (planetary retrograde motion and periods) seems to present difficulty to students. Stellar proper motions are made observable by the use of long observing intervals of up to 30000 years. The distribution of nearby stars in space is studied through use of stellar color and the assumption that all stars are on the Main Sequence. The erroneous results which this engenders are not recognized as such by most students, who happily submit reports with red stars at .02 parsec distance. Star counts enable rough determination of Galactic structure. Widespread availability of PC-compatible computers has enabled distance education to bring astronomical education, including an 'observational' component, to Canadians who otherwise would not have access to it.

  4. 29 CFR 2580.412-19 - Term of the bond, discovery period, other bond clauses.

    Science.gov (United States)

    2010-07-01

    ... SECURITY ACT OF 1974 TEMPORARY BONDING RULES General Bond Rules § 2580.412-19 Term of the bond, discovery... 29 Labor 9 2010-07-01 2010-07-01 false Term of the bond, discovery period, other bond clauses... new bond must be obtained each year. There is nothing in the Act that prohibits a bond for a...

  5. Expected distance between terminal nucleotides of RNA secondary structures.

    Science.gov (United States)

    Clote, Peter; Ponty, Yann; Steyaert, Jean-Marc

    2012-09-01

    In "The ends of a large RNA molecule are necessarily close", Yoffe et al. (Nucleic Acids Res 39(1):292-299, 2011) used the programs RNAfold [resp. RNAsubopt] from Vienna RNA Package to calculate the distance between 5' and 3' ends of the minimum free energy secondary structure [resp. thermal equilibrium structures] of viral and random RNA sequences. Here, the 5'-3' distance is defined to be the length of the shortest path from 5' node to 3' node in the undirected graph, whose edge set consists of edges {i, i + 1} corresponding to covalent backbone bonds and of edges {i, j} corresponding to canonical base pairs. From repeated simulations and using a heuristic theoretical argument, Yoffe et al. conclude that the 5'-3' distance is less than a fixed constant, independent of RNA sequence length. In this paper, we provide a rigorous, mathematical framework to study the expected distance from 5' to 3' ends of an RNA sequence. We present recurrence relations that precisely define the expected distance from 5' to 3' ends of an RNA sequence, both for the Turner nearest neighbor energy model, as well as for a simple homopolymer model first defined by Stein and Waterman. We implement dynamic programming algorithms to compute (rather than approximate by repeated application of Vienna RNA Package) the expected distance between 5' and 3' ends of a given RNA sequence, with respect to the Turner energy model. Using methods of analytical combinatorics, that depend on complex analysis, we prove that the asymptotic expected 5'-3' distance of length n homopolymers is approximately equal to the constant 5.47211, while the asymptotic distance is 6.771096 if hairpins have a minimum of 3 unpaired bases and the probability that any two positions can form a base pair is 1/4. Finally, we analyze the 5'-3' distance for secondary structures from the STRAND database, and conclude that the 5'-3' distance is correlated with RNA sequence length.

  6. Bonding resin thixotropy and viscosity influence on dentine bond strength.

    Science.gov (United States)

    Niem, Thomas; Schmidt, Alexander; Wöstmann, Bernd

    2016-08-01

    To investigate the influence of bonding resin thixotropy and viscosity on dentine tubule penetration, blister formation and consequently on dentine bond strength as a function of air-blowing pressure (air-bp) intensity. Two HEMA-free, acetone-based, one-bottle self-etch adhesives with similar composition except disparate silica filler contents and different bonding resin viscosities were investigated. The high-filler-containing adhesive (G-Bond) featured a lower viscous bonding resin with inherent thixotropic resin (TR) properties compared to the low-filler-containing adhesive (iBond) exhibiting a higher viscous bonding resin with non-thixotropic resin (NTR) properties. Shear bond strength tests for each adhesive with low (1.5bar; 0.15MPa; n=16) and high (3.0bar; 0.30MPa; n=16) air-bp application were performed after specimen storage in distilled water (24h; 37.0±1.0°C). Results were analysed using a Student's t-test to identify statistically significant differences (padhesive specimens were morphologically characterised by SEM. Statistically significant bond strength differences were obtained for the thixotropic resin adhesive (high-pressure: 24.6MPa, low-pressure: 9.6MPa). While high air-bp specimens provided SEM images revealing resin-plugged dentine tubules, resin tags and only marginally blister structures, low air-bp left copious droplets and open dentine tubules. In contrast, the non-thixotropic resin adhesive showed no significant bond strength differences (high-pressure: 9.3MPa, low-pressure: 7.6MPa). A pressure-dependent distinct influence of bonding resin thixotropy and viscosity on dentine bond strength has been demonstrated. Stronger adhesion with high air-bp application is explained by improved resin fluidity and facilitated resin penetration into dentine tubules. Filler particles used in adhesive systems may induce thixotropic effects in bonding resin layers, accounting for improved free-flowing resin properties. In combination with high air

  7. Intramolecular amide bonds stabilize pili on the surface of bacilli

    Energy Technology Data Exchange (ETDEWEB)

    Budzik, Jonathan M.; Poor, Catherine B.; Faull, Kym F.; Whitelegge, Julian P.; He, Chuan; Schneewind, Olaf; (UC); (UCLA-MED)

    2010-01-12

    Gram-positive bacteria elaborate pili and do so without the participation of folding chaperones or disulfide bond catalysts. Sortases, enzymes that cut pilin precursors, form covalent bonds that link pilin subunits and assemble pili on the bacterial surface. We determined the x-ray structure of BcpA, the major pilin subunit of Bacillus cereus. The BcpA precursor encompasses 2 Ig folds (CNA{sub 2} and CNA{sub 3}) and one jelly-roll domain (XNA) each of which synthesizes a single intramolecular amide bond. A fourth amide bond, derived from the Ig fold of CNA{sub 1}, is formed only after pilin subunits have been incorporated into pili. We report that the domains of pilin precursors have evolved to synthesize a discrete sequence of intramolecular amide bonds, thereby conferring structural stability and protease resistance to pili.

  8. The Economic Value of Predicting Bond Risk Premia

    DEFF Research Database (Denmark)

    Sarno, Lucio; Schneider, Paul; Wagner, Christian

    This paper studies whether the evident statistical predictability of bond risk premia translates into economic gains for bond investors. We show that ane term structure models (ATSMs) estimated by jointly tting yields and bond excess returns capture this predictive information otherwise hidden...... to standard ATSM estimations. The model's excess return predictions are unbiased, produce regression R2s beyond those reported in the literature, exhibit high forecast accuracy, and allow to generate positive bond portfolio excess returns in- and out-of-sample. Nevertheless, these models cannot beat...... deviations mainly matter at short horizons and standard predictability metrics are not compatible with common measures of economic value. Overall, the EH remains the benchmark for investment decisions and should be considered an economic prior in models of bond risk premia....

  9. Wax-bonding 3D microfluidic chips

    KAUST Repository

    Gong, Xiuqing

    2013-10-10

    We report a simple, low-cost and detachable microfluidic chip incorporating easily accessible paper, glass slides or other polymer films as the chip materials along with adhesive wax as the recycling bonding material. We use a laser to cut through the paper or film to form patterns and then sandwich the paper and film between glass sheets or polymer membranes . The hot-melt adhesive wax can realize bridge bonding between various materials, for example, paper, polymethylmethacrylate (PMMA) film, glass sheets, or metal plate. The bonding process is reversible and the wax is reusable through a melting and cooling process. With this process, a three-dimensional (3D) microfluidic chip is achievable by vacuating and venting the chip in a hot-water bath. To study the biocompatibility and applicability of the wax-based microfluidic chip, we tested the PCR compatibility with the chip materials first. Then we applied the wax-paper based microfluidic chip to HeLa cell electroporation (EP ). Subsequently, a prototype of a 5-layer 3D chip was fabricated by multilayer wax bonding. To check the sealing ability and the durability of the chip, green fluorescence protein (GFP) recombinant Escherichia coli (E. coli) bacteria were cultured, with which the chemotaxis of E. coli was studied in order to determine the influence of antibiotic ciprofloxacin concentration on the E. coli migration.

  10. Construct Polyoxometalate Frameworks through Covalent Bonds.

    Science.gov (United States)

    Chen, Hong; Zhao, Huishuang; Yu, Zheng-Bao; Wang, Lei; Sun, Licheng; Sun, Junliang

    2015-09-08

    An emerging strategy for exploring the application of polyoxometalates (POMs) is to assemble POM clusters into open-framework materials, especially inorganic-organic hybrid three-dimensional (3D) open-framework materials, via the introduction of different organic linkers between the POM clusters. This strategy has yielded a few 3D crystalline POMs of which a typical class is the group of polyoxometalate metal-organic frameworks (POMMOFs). However, for reported POMMOFs, only coordination bonds are involved between the linkers and POM clusters, and it has not yet produced any covalently bonded polyoxometalate frameworks. Here, the concept of "covalently bonded POMs (CPOMs)" is developed. By using vanadoborates as an example, we showed that the 3D CPOMs can be obtained by a condensation reaction through the oxolation mechanism of polymer chemistry. In particular, suitable single crystals were harvested and characterized by single-crystal X-ray diffraction. This work forges a link among polymer science, POM chemistry, and open-framework materials by demonstrating that it is possible to use covalent bonds according to polymer chemistry principles to construct crystalline 3D open-framework POM materials.

  11. Swelling and Creep of Isocyanate-Bonded Oriented-Particle Board

    OpenAIRE

    SEKINO, Noboru; Suzuki, Masaharu

    1984-01-01

    This paper reports swelling, bending strength, and creep of Isocyanate(ls)bonded oriented-particleboard(face: orlented, core: random), which is compared with Phenol-formaldehyde(PF) bonded and Urea-formaldehyde(UF) bonded oriented-particleboards.Test results are summarized as follows:1) The orientation of flakes greatly reduces linear expansion along the oriented dlreCtion, but the thickness swelling of oriented board is almost equal to that of random-orientedboard.2) ls-bonded particleboard...

  12. The Future of Distance Education.

    Science.gov (United States)

    Saba, Farhad

    2000-01-01

    Examines factors that will influence how distance education is practiced in the first few decades of this new century. Discusses developments in digital technology; the exponential growth of knowledge about the brain, as well as physiology, chemistry, and psychology of learning; the system relationship between individual learners and instructors;…

  13. Using Podcasts in Distance Education

    Science.gov (United States)

    Koppelman, Herman

    2013-01-01

    This paper discusses three possible ways of applying podcasts in distance education: podcasts of recordings of virtual classes, podcasts produced for specific pedagogical aims, and podcasts produced by external organizations. Through a survey we gained insight in the (until now limited) experiences of our distant students with podcasts, and also…

  14. Distance Education Instructional Model Applications.

    Science.gov (United States)

    Jackman, Diane H.; Swan, Michael K.

    1995-01-01

    A survey of graduate students involved in distance education on North Dakota State University's Interactive Video Network included 80 on campus and 13 off. The instructional models rated most effective were role playing, simulation, jurisprudential (Socratic method), memorization, synectics, and inquiry. Direct instruction was rated least…

  15. Distance, Lending Relationships, and Competition

    NARCIS (Netherlands)

    Degryse, H.A.; Ongena, S.

    2003-01-01

    A recent string of theoretical papers has highlighted the importance of geographical distance in explaining loan rates for small firms.Lenders located in the vicinity of small firms face significantly lower transportation and monitoring costs, and hence wield considerable market power, if competing

  16. Favourite distances in high dimensions

    CERN Document Server

    Swanepoel, Konrad J

    2011-01-01

    Let $S$ be a set of $n$ points in $d$-dimensional Euclidean space. Assign to each $x\\in S$ an arbitrary distance $r(x)>0$. Let $e_r(x,S)$ denote the number of points in $S$ at distance $r(x)$ from $x$. Avis, Erd\\"os and Pach (1988) introduced the extremal quantity $f_d(n)=\\max\\sum_{x\\in S}e_r(x,S)$, where the maximum is taken over all $n$-point sets $S$ in $d$-dimensional space and all assignments $r\\colon S\\to(0,\\infty)$ of distances. We give a quick derivation of the asymptotics of the error term of $f_d(n)$ using only the analogous asymptotics of the maximum number of unit distance pairs in a set of $n$ points, which improves on previous results of Avis, Erd\\"os and Pach (1988) and Erd\\"os and Pach (1990). Then we prove a stability result for $d\\geq 4$, asserting that if $(S,r)$ with $|S|=n$ satisfies $e_r(S)=f_d(n)-o(n^2)$, then, up to $o(n)$ points, $S$ is a Lenz construction with $r$ constant. Finally we use stability to show that for $n$ sufficiently large (depending on $d$) the pairs $(S,r)$ that atta...

  17. Lessons in Developing Distance Learning.

    Science.gov (United States)

    Gant, Lenora Peters

    1996-01-01

    Describes the use of video teletraining (VTT) for distance learning in the Department of Defense. Topics include planning and organizing the VTT facility, staff development, site facilitators, the necessity of protocol, instructional design and development strategies, student involvement and interactivity, and evaluation and assessment. (LRW)

  18. Communication Barriers in Distance Education

    Science.gov (United States)

    Isman, Aytekin; Dabaj, Fahme; Altinay, Fahriye; Altinay, Zehra

    2003-01-01

    Communication is a key concept as being the major tool for people in order to satisfy their needs. It is an activity which refers as process and effective communication requires qualified communication with the elimination of communication barriers. As it is known, distance education is a new trend by following contemporary facilities and tools…

  19. Distance Learning: Untried and Untrue

    Science.gov (United States)

    Halfond, Jay A.

    2010-01-01

    G. K. Chesterton famously once said: "Christianity has not been tried and found wanting; it has been found difficult and not tried." This, the author believes, applies to distance learning as well. There is far too much self-congratulatory hyperbole about the growth and pervasiveness of online learning--which exaggerates reality and overlooks the…

  20. Curriculum Control in Distance Education.

    Science.gov (United States)

    Chesterton, Paul

    1985-01-01

    The nature of distance education is to shift the locus of curriculum control toward the institution and its staff and away from the students. This imposes a responsibility on the institution to examine and evaluate the values and assumptions underlying the decision-making and the implications of the patterns of control that emerge. (Author/MSE)

  1. Distance, Lending Relationships and Competition

    NARCIS (Netherlands)

    Degryse, H.A.; Ongena, S.

    2002-01-01

    A recent string of theoretical papers highlights the importance of geographical distance in explaining pricing and availability of loans to small firms.Lenders located in the vicinity of small firms have significantly lower monitoring and transaction costs, and hence considerable market power if com

  2. On Maximum Lee Distance Codes

    OpenAIRE

    Alderson, Tim L.; Svenja Huntemann

    2013-01-01

    Singleton-type upper bounds on the minimum Lee distance of general (not necessarily linear) Lee codes over ℤq are discussed. Two bounds known for linear codes are shown to also hold in the general case, and several new bounds are established. Codes meeting these bounds are investigated and in some cases characterised.

  3. Video Surveillance using Distance Maps

    NARCIS (Netherlands)

    Schouten, Theo E.; Kuppens, Harco C.; Broek, van den Egon L.; Kehtarnavaz, Nasser; Laplante, Phillip A.

    2006-01-01

    Human vigilance is limited; hence, automatic motion and distance detection is one of the central issues in video surveillance. Hereby, many aspects are of importance, this paper specially addresses: efficiency, achieving real-time performance, accuracy, and robustness against various noise factors.

  4. Gesture Interaction at a Distance

    NARCIS (Netherlands)

    Fikkert, F.W.

    2010-01-01

    The aim of this work is to explore, from a perspective of human behavior, which gestures are suited to control large display surfaces from a short distance away; why that is so; and, equally important, how such an interface can be made a reality. A well-known example of the type of interface that is

  5. The Perception of Ideological Distance

    NARCIS (Netherlands)

    Granberg, Donald; Brown, Thad A.

    1992-01-01

    Data from national election studies in Britain, the Netherlands, Sweden, and the U.S. were analyzed to test hypotheses concerning the perception of ideological distance between parties and candidates. The first hypothesis, derived from Sherif's social judgment theory and Heider's balance theory, was

  6. Isolation by distance, web service

    Directory of Open Access Journals (Sweden)

    Bohonak Andrew J

    2005-03-01

    Full Text Available Abstract Background The population genetic pattern known as "isolation by distance" results from spatially limited gene flow and is a commonly observed phenomenon in natural populations. However, few software programs exist for estimating the degree of isolation by distance among populations, and they tend not to be user-friendly. Results We have created Isolation by Distance Web Service (IBDWS a user-friendly web interface for determining patterns of isolation by distance. Using this site, population geneticists can perform a variety of powerful statistical tests including Mantel tests, Reduced Major Axis (RMA regression analysis, as well as calculate FST between all pairs of populations and perform basic summary statistics (e.g., heterozygosity. All statistical results, including publication-quality scatter plots in Postscript format, are returned rapidly to the user and can be easily downloaded. Conclusion IBDWS population genetics analysis software is hosted at http://phage.sdsu.edu/~jensen/ and documentation is available at http://www.bio.sdsu.edu/pub/andy/IBD.html. The source code has been made available on Source Forge at http://sourceforge.net/projects/ibdws/.

  7. Video surveillance using distance maps

    NARCIS (Netherlands)

    Schouten, Theo E.; Kuppens, Harco C.; van den Broek, Egon; Kehtarnavaz, Nasser; Laplante, Phillip A,

    2006-01-01

    Human vigilance is limited; hence, automatic motion and distance detection is one of the central issues in video surveillance. Hereby, many aspects are of importance, this paper specially addresses: efficiency, achieving real-time performance, accuracy, and robustness against various noise factors.

  8. Interaction between Accommodation and Vergence on Distance Perception

    Directory of Open Access Journals (Sweden)

    Tomoyuki Daijogo

    2011-05-01

    Full Text Available Fisher and Ciuffreda (1988 and Mon-Williams and Tresilian (1999 reported that, without vergence cue, diopter change in accommodation induced change in apparent distance. Meanwhile, there is conflicting evidence about the relative roles of accommodation and vergence in distance perception (Richards & Miller, 1969; von Holst, 1973. In the current study, we investigated interaction between accommodation and vergence on distance perception. The perceived distance from integration of vergence evoked by a fixation target and accommodation by a pair of concave or convex lenses in front of eyes is measured with a mirror stereoscope. The stimulus was a white square with a black cross-shaped fixation on a black background. In dark surroundings, subjects were asked to commit the apparent distance of the target to memory, and then without the lenses, re-create the distance by changing distance of another fixation target. The apparent size of the target through lenses were equivalent to the size without lenses. The results showed that not only vergence but accommodation affect the apparent distance, and they were summed linearly.

  9. The quantum nature of the hydrogen bond: insight from path-integral molecular dynamics

    Science.gov (United States)

    Walker, Brent; Li, Xin-Zheng; Michaelides, Angelos

    2011-03-01

    Hydrogen (H) bonds are weak, generally intermolecular bonds, that hold together much of soft matter, the condensed phases of water, network liquids, and many ferroelectric crystals. The small mass of H means H-bonds are inherently quantum mechanical; effects such as zero point motion and tunneling should be considered, although often are not. In particular, a consistent picture of quantum nuclear effects on the strength of H-bonds and consequently the structure of H-bonded systems is still absent. Here, we report ab initio path-integral molecular dynamics studies on the quantum nature of the H-bond. Systematic examination of a range of H-bonded systems shows that quantum nuclei weaken weak H-bonds but strengthen relatively strong ones. This correlation arises from a competition between anharmonic intermolecular bond bending and intramolecular bond stretching. A simple rule of thumb enables predictions to be made for H-bonded bonded materials in general with merely classical knowledge (e.g. H-bond strength or H-bond length). Our work rationalizes the contrasting influence of quantum nuclear dynamics on a wide variety of materials, including liquid water and HF, and highlights the need for flexible molecules in force-field based studies of quantum nuclear dynamics.

  10. Structural Criteria for the Rational Design of Selective Ligands: Convergent Hydrogen Bonding Sites for the Nitrate Anion

    Energy Technology Data Exchange (ETDEWEB)

    Hay, Benjamin P.; Gutowski, Maciej S.; Dixon, David A.; Garza , Jorge; Vargas, Rubicelia; Moyer, Bruce A.

    2004-06-30

    Molecular hosts for anion complexation are often constructed by combining two or more hydrogen bonding functional groups, D–H. The deliberate design of complementary host architectures requires knowledge of the optimal geometry for the hydrogen bonds formed between the host and the guest. Herein, we present a detailed study of the structural aspects of hydrogen bonding interactions with the NO3– anion. A large number of crystal structures are analyzed to determine the number of hydrogen bond contacts per anion and to further characterize the structural aspects of these interactions. Electronic structure calculations are used to determine stable geometries and interaction energies for NO3– complexes with several simple molecules possessing D–H groups, including water, methanol, N-methylformamide, and methane. Theoretical results are reported at several levels of density functional theory, including BP86/DN**, B3LYP/TZVP, and B3LYP/TZVP+, and at MP2/aug-cc-pVDZ. In addition, MP2 binding energies for these complexes were obtained at the complete basis set limit by extrapolating from single point energies obtained with larger correlation-consistent basis sets. The results establish that NO3– has an intrinsic hydrogen bonding topography in which there are six optimal sites for proton location. The structural features observed in crystal structures and in the optimized geometries of complexes are explained by a preference to locate the D–H protons in these positions. For the strongest hydrogen bonding interactions, the N–O•••H angle is bent at an angle of 115 ± 10°, and the hydrogen atom lies in the NO3– plane giving O–N–O•••H dihedral angles of 0 and 180°. In addition, the D-H vector points towards the oxygen atom, giving D–H•••O angles that are near linear, 170 ± 10°. Due to steric hindrance, simple alcohol O–H and amide N–H donors form 3:1 complexes with NO3–, with H•••O distances of 1.85 ± 0.5 Å. Thus, the

  11. Pauling bond strength, bond length and electron density distribution

    Energy Technology Data Exchange (ETDEWEB)

    Gibbs, Gerald V.; Ross, Nancy L.; Cox, David F.; Rosso, Kevin M.; Iversen, Bo B.; Spackman, M. A.

    2014-01-18

    A power law regression equation, = 1.46(<ρ(rc)>/r)-0.19, connecting the average experimental bond lengths, , with the average accumulation of the electron density at the bond critical point, <ρ(rc)>, between bonded metal M and oxygen atoms, determined at ambient conditions for oxide crystals, where r is the row number of the M atom, is similar to the regression equation R(M-O) = 1.39(ρ(rc)/r)-0.21 determined for three perovskite crystals for pressures as high as 80 GPa. The two equations are also comparable with those, = 1.43(/r)-0.21, determined for a large number of oxide crystals at ambient conditions and = 1.39(/r)-0.22, determined for geometry optimized hydroxyacid molecules, that connect the bond lengths to the average Pauling electrostatic bond strength, , for the M-O bonded interactions. On the basis of the correspondence between the two sets of equations connecting ρ(rc) and the Pauling bond strength s with bond length, it appears that Pauling’s simple definition of bond strength closely mimics the accumulation of the electron density between bonded pairs of atoms. The similarity of the expressions for the crystals and molecules is compelling evidence that the M-O bonded interactions for the crystals and molecules 2 containing the same bonded interactions are comparable. Similar expressions, connecting bond lengths and bond strength, have also been found to hold for fluoride, nitride and sulfide molecules and crystals. The Brown-Shannon bond valence, σ, power law expression σ = [R1/(R(M-O)]N that has found wide use in crystal chemistry, is shown to be connected to a more universal expression determined for oxides and the perovskites, <ρ(rc)> = r[(1.41)/]4.76, demonstrating that the bond valence for a bonded interaction is likewise closely connected to the accumulation of the electron density between the bonded atoms. Unlike the Brown-Shannon expression, it is universal in that it holds for the M

  12. A Streaming Distance Transform Algorithm for Neighborhood-Sequence Distances

    Directory of Open Access Journals (Sweden)

    Nicolas Normand

    2014-09-01

    Full Text Available We describe an algorithm that computes a “translated” 2D Neighborhood-Sequence Distance Transform (DT using a look up table approach. It requires a single raster scan of the input image and produces one line of output for every line of input. The neighborhood sequence is specified either by providing one period of some integer periodic sequence or by providing the rate of appearance of neighborhoods. The full algorithm optionally derives the regular (centered DT from the “translated” DT, providing the result image on-the-fly, with a minimal delay, before the input image is fully processed. Its efficiency can benefit all applications that use neighborhood- sequence distances, particularly when pipelined processing architectures are involved, or when the size of objects in the source image is limited.

  13. Computational Chemistry of Adhesive Bonds

    Science.gov (United States)

    Phillips, Donald H.

    1999-01-01

    This investigation is intended to determine the electrical mechanical, and chemical properties of adhesive bonds at the molecular level. The initial determinations will be followed by investigations of the effects of environmental effects on the chemistry and properties of the bond layer.

  14. Modelling of the Through-air Bonding Process

    Directory of Open Access Journals (Sweden)

    M. Hossain

    2009-06-01

    Full Text Available A computational fluid dynamics (CFD modelling ofthe through-air bonding process of nonwoven fabricproduction is reported in this article. In the throughairprocess, hot air is passed through the fibrous webto heat and melt polymer fibers. Molten polymersubsequently flows to the point of contact betweenany two fibers to produce a bond. Two differentmodelling strategies are adapted to produce acomprehensive understanding of the through-airbonding process. In macroscale modelling, a CFDmodel is developed treating the whole web as aporous media in order to investigate the effect ofprocess parameters. Results reveal that the timerequired to heat and melt the fibers decreases with theincreasing porosity of the web and the velocity of hotair. The CFD modelling technique is then used toanalyze the bonding process at a more fundamentallevel by considering the bonding of individual fibersat microscale. The effects of the fiber diameter,bonding temperature and contact angle between twofibers on the bonding time are investigated. Resultsshow that the time required to bond fibers is weaklyrelated to bonding temperature and fiber diameter.Fiber orientation angle, on the other hand, hassignificant effect on the progression of bondformation.

  15. SOCIAL BONDING: REGULATION BY NEUROPEPTIDES

    Directory of Open Access Journals (Sweden)

    Claudia eLieberwirth

    2014-06-01

    Full Text Available Affiliative social relationships (e.g., among spouses, family members, and friends play an essential role in human society. These relationships affect psychological, physiological, and behavioral functions. As positive and enduring bonds are critical for the overall well-being of humans, it is not surprising that considerable effort has been made to study the neurobiological mechanisms that underlie social bonding behaviors. The present review details the involvement of the nonapeptides, oxytocin (OT and arginine vasopressin (AVP, in the regulation of social bonding in mammals including humans. In particular, we will discuss the role of OT and AVP in the formation of social bonds between partners of a mating pair as well as between parents and their offspring. Furthermore, the role of OT and AVP in the formation of interpersonal bonding involving trust is also discussed.

  16. Quantum Confinement in Hydrogen Bond

    CERN Document Server

    Santos, Carlos da Silva dos; Ricotta, Regina Maria

    2015-01-01

    In this work, the quantum confinement effect is proposed as the cause of the displacement of the vibrational spectrum of molecular groups that involve hydrogen bonds. In this approach the hydrogen bond imposes a space barrier to hydrogen and constrains its oscillatory motion. We studied the vibrational transitions through the Morse potential, for the NH and OH molecular groups inside macromolecules in situation of confinement (when hydrogen bonding is formed) and non-confinement (when there is no hydrogen bonding). The energies were obtained through the variational method with the trial wave functions obtained from Supersymmetric Quantum Mechanics (SQM) formalism. The results indicate that it is possible to distinguish the emission peaks related to the existence of the hydrogen bonds. These analytical results were satisfactorily compared with experimental results obtained from infrared spectroscopy.

  17. Which Aspects of the English Language Do Distance Learners Find Difficult?

    Science.gov (United States)

    Teoh, George Boon Sai; Lin, Agnes Liau Wei; Belaja, Kathy

    2016-01-01

    This study reports the findings of a research carried out on distance learners at the School of Distance Education (SDE), University Sains Malaysia (USM). The study was explorative in nature with the purpose identifying the aspects of the English language which distance learners found difficult to learn. A quantitative survey questionnaire design…

  18. Facebook Mediated Interaction and Learning in Distance Learning at Makerere University

    Science.gov (United States)

    Mayende, Godfrey; Muyinda, Paul Birevu; Isabwe, Ghislain Maurice Norbert; Walimbwa, Michael; Siminyu, Samuel Ndeda

    2014-01-01

    This paper reports on an investigation of the use of Facebook as a tool to mediate learning amongst distance learners at Makerere University, a dual-mode institution offering both conventional and distance learning programs. While conventional courses take 17 weeks in a semester, the distance learners come in for two residential sessions, each…

  19. Dentin-bonding agents

    Directory of Open Access Journals (Sweden)

    João Carlos Gomes

    2008-01-01

    Full Text Available New dental restorative materials have been developed to meet not only the functional demands, but esthetics as well, and in the last few years an enormous range of new materials has appeared for use in dentistry. Among them, several adhesive systems, and different operative techniques for each group materials. Therefore, is indispensable for the professional to know about the properties, characteristics, and association of these materials with the dental structures, in order to select and use them correctly. Should conventional self-etching adhesive systems be used? This question encouraged this literature review to be conducted, with the aim of comparing the conventional adhesive systems with the self-etching systems and to look for scientific data that would help professionals to choose which adhesive system to use. When compared to conventional systems, it was noted that the self-etching systems show less sensitivity to technique, especially as regards errors the operator could commit. The self-etching systems, particularly the 2-step type, have shown equivalent values of bond strength, marginal microleakage and performance, therefore, will be an option for direct composite resin restorations in posterior teeth.

  20. 27 CFR 24.153 - Strengthening bonds.

    Science.gov (United States)

    2010-04-01

    ... Strengthening bonds. In any instance where the penal sum of the bond on file becomes insufficient, the principal shall either give a strengthening bond with the same surety to attain a sufficient penal sum or give a... limiting the amount of either bond to less than its full penal sum. Strengthening bonds will show...

  1. 27 CFR 19.246 - Strengthening bonds.

    Science.gov (United States)

    2010-04-01

    ... Strengthening bonds. In all cases when the penal sum of any bond becomes insufficient, the principal shall either give a strengthening bond with the same surety to attain a sufficient penal sum, or give a new... amount of any bond to less than its full penal sum. Strengthening bonds shall show the current date...

  2. Effective Teaching in Distance Education. ERIC Digest.

    Science.gov (United States)

    Mielke, Dan

    Distance education is an alternative method for delivering academic course work to students unable to attend traditional campus-based classes. This Digest presents information on the many forms of distance education and keys to successful teaching with distance education. Distance education is a method of education in which the learner is…

  3. The intractability of computing the Hamming distance

    NARCIS (Netherlands)

    Manthey, Bodo; Reischuk, Rüdiger

    2005-01-01

    Given a string x and a language L, the Hamming distance of x to L is the minimum Hamming distance of x to any string in L. The edit distance of a string to a language is analogously defined. First, we prove that there is a language in $AC^0$ such that both Hamming and edit distance to this language

  4. Distance Education Use in Rural Schools

    Science.gov (United States)

    Hannum, Wallace H.; Irvin, Matthew J.; Banks, Jonathan B.; Farmer, Thomas W.

    2009-01-01

    A national survey of rural school systems in the United States was conducted to determine the extent to which distance education is being utilized by rural schools, the technologies used, the curriculum areas impacted, the perceived needs for distance education, their satisfaction with distance education, and the barriers to distance education…

  5. History and Heritage in Distance Education

    Science.gov (United States)

    Anderson, Bill; Simpson, Mary

    2012-01-01

    Distance education's history is a tremendous resource for all involved in distance education. Some aspects of that history provide enduring touchstones for present distance educators, creating a heritage that should not be overlooked as distance education continues to develop and expand. In this article we draw on the concept of generational…

  6. Incommmensurability and unconventional superconductor to insulator transition in the hubbard model with bond-charge interaction.

    Science.gov (United States)

    Aligia, A A; Anfossi, A; Arrachea, L; Degli Esposti Boschi, C; Dobry, A O; Gazza, C; Montorsi, A; Ortolani, F; Torio, M E

    2007-11-16

    We determine the quantum phase diagram of the one-dimensional Hubbard model with bond-charge interaction X in addition to the usual Coulomb repulsion U>0 at half-filling. For large enough Xtransition to a spontaneously dimerized bond-ordered wave phase and then a charge transition to a novel phase in which the dominant correlations at large distances correspond to an incommensurate singlet superconductor.

  7. Determining distances using asteroseismic methods

    CERN Document Server

    Aguirre, V Silva; Basu, S; Campante, T L; Chaplin, W J; Huber, D; Miglio, A; Serenelli, A M; WG#1, KASC

    2012-01-01

    Asteroseismology has been extremely successful in determining the properties of stars in different evolutionary stages with a remarkable level of precision. However, to fully exploit its potential, robust methods for estimating stellar parameters are required and independent verification of the results is needed. In this talk, I present a new technique developed to obtain stellar properties by coupling asteroseismic analysis with the InfraRed Flux Method. Using two global seismic observables and multi-band photometry, the technique determines masses, radii, effective temperatures, bolometric fluxes, and thus distances for field stars in a self-consistent manner. Applying our method to a sample of solar-like oscillators in the {\\it Kepler} field that have accurate {\\it Hipparcos} parallaxes, we find agreement in our distance determinations to better than 5%. Comparison with measurements of spectroscopic effective temperatures and interferometric radii also validate our results, and show that our technique can ...

  8. Managerial Distance and Virtual Ownership

    DEFF Research Database (Denmark)

    Hansmann, Henry; Thomsen, Steen

    Industrial foundations are autonomous nonprofit entities that own and control one or more conventional business firms. These foundations are common in Northern Europe, where they own a number of internationally prominent companies. Previous studies have indicated, surprisingly, that companies con......, but corporate governance and fiduciary behavior more generally....... on differences among the industrial foundations themselves. We work with a rich data set comprising 113 foundation-owned Danish companies over the period 2003-2008. We focus in particular on a composite structural factor that we term “managerial distance.” We propose this as a measure of the extent to which......-seeking outside owners of the company. Consistent with this hypothesis, our empirical analysis shows a positive, significant, and robust association between managerial distance and the economic performance of foundation owned companies. The findings appear to illuminate not just foundation governance...

  9. Theological Librarianship from a Distance

    Directory of Open Access Journals (Sweden)

    Melody Diehl Detar

    2015-08-01

    Full Text Available This essay examines distance theological librarianship and the field’s suitability for remote librarians. A brief introduction to the landscape of online programs in theological education is followed by an overview of virtual librarianship and how theological librarians may serve students while working from a distance themselves. The essay then describes a method for initiating a remote librarian position in a theological library context, and then reviews the steps of determining whether remote work is feasible and desirable at an institution, approaching leadership with a plan, setting up a trial remote work period, and assessing its success. Particular emphasis is given to communication expectations, modes of virtual reference and instruction, campus committee service and meaningful ways of remaining part of the campus community.

  10. Moral distance in dictator games

    Directory of Open Access Journals (Sweden)

    Fernando Aguiar

    2008-04-01

    Full Text Available We perform an experimental investigation using a dictator game in which individuals must make a moral decision --- to give or not to give an amount of money to poor people in the Third World. A questionnaire in which the subjects are asked about the reasons for their decision shows that, at least in this case, moral motivations carry a heavy weight in the decision: the majority of dictators give the money for reasons of a consequentialist nature. Based on the results presented here and of other analogous experiments, we conclude that dicator behavior can be understood in terms of moral distance rather than social distance and that it systematically deviates from the egoism assumption in economic models and game theory. %extit{JEL}: A13, C72, C91

  11. Students’ Role in Distance Learning

    OpenAIRE

    Beers Fägersten, Kristy

    2008-01-01

    1. IntroductionMuch of the support that students have in a traditional classroom is absent in a distance learning course. In the traditional classroom, the learner is together with his or her classmates and the teacher; learning is socially embedded. Students can talk to each other and may learn from each other as they go through the learning process together. They also witness the teacher’s expression of the knowledge firsthand. The class participants communicate to each other not ...

  12. Distance probes of dark energy

    Energy Technology Data Exchange (ETDEWEB)

    Kim, A. G.; Padmanabhan, N.; Aldering, G.; Allen, S. W.; Baltay, C.; Cahn, R. N.; D’Andrea, C. B.; Dalal, N.; Dawson, K. S.; Denney, K. D.; Eisenstein, D. J.; Finley, D. A.; Freedman, W. L.; Ho, S.; Holz, D. E.; Kasen, D.; Kent, S. M.; Kessler, R.; Kuhlmann, S.; Linder, E. V.; Martini, P.; Nugent, P. E.; Perlmutter, S.; Peterson, B. M.; Riess, A. G.; Rubin, D.; Sako, M.; Suntzeff, N. V.; Suzuki, N.; Thomas, R. C.; Wood-Vasey, W. M.; Woosley, S. E.

    2015-03-01

    This document presents the results from the Distances subgroup of the Cosmic Frontier Community Planning Study (Snowmass 2013). We summarize the current state of the field as well as future prospects and challenges. In addition to the established probes using Type Ia supernovae and baryon acoustic oscillations, we also consider prospective methods based on clusters, active galactic nuclei, gravitational wave sirens and strong lensing time delays.

  13. Hardware Euclidean Distance Transform Implementation

    Institute of Scientific and Technical Information of China (English)

    XIE Ying-hua; ZENG Pei-feng; TANG Li-ping

    2004-01-01

    Based on an efficient algorithm of Euclidean distance transform for binary images, a circuit of O(N2) size is proposed. With in-place calculation, both the intermediate data storing and the result output use the same memory with the input data. This reduces the amount of memory largely. By replacing multipliers with counters, comparators, and adders, the circuit size is further reduced and its calculation speed is improved also.

  14. Distance Probes of Dark Energy

    CERN Document Server

    Kim, A; Aldering, G; Allen, S; Baltay, C; Cahn, R; D'Andrea, C; Dalal, N; Dawson, K; Denney, K; Eisenstein, D; Finley, D; Freedman, W; Ho, S; Holz, D; Kent, A; Kasen, D; Kessler, R; Kuhlmann, S; Linder, E; Martini, P; Nugent, P; Perlmutter, S; Peterson, B; Riess, A; Rubin, D; Sako, M; Suntzeff, N; Suzuki, N; Thomas, R; Wood-Vasey, W M; Woosley, S

    2013-01-01

    This document presents the results from the Distances subgroup of the Cosmic Frontier Community Planning Study (Snowmass 2013). We summarize the current state of the field as well as future prospects and challenges. In addition to the established probes using Type IA supernovae and baryon acoustic oscillations, we also consider prospective methods based on clusters, active galactic nuclei, gravitational wave sirens and strong lensing time delays.

  15. Distance effects in electrochemical micromachining

    OpenAIRE

    2016-01-01

    Considering exponential dependence of currents on double-layer voltage and the feedback effect of the electrolyte resistance, a distance effect in electrochemical micromachining is found, namely that both time constant and double-layer voltage depend on the separation of electrodes. The double-layer voltage is the real voltage used in processing. Under DC voltage, the apparent voltages between two electrodes are constant for different separations, but the real voltages change with the separat...

  16. DFT investigation on dihydrogen-bonded amine-borane complexes.

    Science.gov (United States)

    Yan, Shihai; Zou, Hongmei; Kang, Wukui; Sun, Lixiang

    2016-01-01

    The DFT method has been employed in the exploration on dihydrogen-bonded amine-borane complexes, with a special emphasis on the dimerization and substituent group effect. Stable dihydrogen bonded complexes can be generated from these amine-borane monomers with the appearance of NH(δ+)…H(δ-)B interactions. The binding energy decreases gradually with the increase of the steric effect of the substituents. The substituent group number mainly varies the C-N bond length. The dimerization generates close H…H and influences predominantly the N-B distance. The effect of dimerization on IR and vibrational circular dichroism (VCD) spectra is stronger than that of the number of substituent groups, which leads to distinct NBO charge variation on α-C. Both the substituent group number and dimerization enhance the chemical shift difference between hydrogen atoms covalently bonded to N and B, Δδ H-H, which can be hired as an index for structural determination. It is proposed that amine-borane complexes with more substituent groups in higher degree of polymerization are potentially interesting materials for hydrogen storage. Graphical Abstract Both the number of substituent group and dimerization enhance the chemical shift difference of hydrogen atoms covalently bonded on N and B, Δδ H-H, which can be employed as an index for the structural determination.

  17. Effect of hydrogen bonding on infrared absorption intensity

    CERN Document Server

    Athokpam, Bijyalaxmi; McKenzie, Ross H

    2016-01-01

    We consider how the infrared intensity of an O-H stretch in a hydrogen bonded complex varies as the strength of the H-bond varies from weak to strong. We obtain trends for the fundamental and overtone transitions as a function of donor-acceptor distance R, which is a common measure of H-bond strength. Our calculations use a simple two-diabatic state model that permits symmetric and asymmetric bonds, i.e. where the proton affinity of the donor and acceptor are equal and unequal, respectively. The dipole moment function uses a Mecke form for the free OH dipole moment, associated with the diabatic states. The transition dipole moment is calculated using one-dimensional vibrational eigenstates associated with the H-atom transfer coordinate on the ground state adiabatic surface of our model. Over 20-fold intensity enhancements for the fundamental are found for strong H-bonds, where there are significant non-Condon effects. The isotope effect on the intensity yields a non-monotonic H/D intensity ratio as a function...

  18. The Magnetotail at Lunar Distance

    Science.gov (United States)

    Sibeck, D. G.

    2015-12-01

    This presentation reviews some of the single-point observations of the magnetotail at lunar distances made by ALSEP, Explorer 33, 35, ISEE-3, and Geotail that form the framework for interpreting more recent dual-spacecraft ARTEMIS observations. Earth's distant magnetotail flaps, twists, and flattens in response to variations in the solar wind flow direction and interplanetary magnetic field (IMF) orientation. It may even disappear leaving nothing more than a wake during strongly northward IMF orientations. Standing slow mode expansion fans provide for a gradual transition between magnetotail lobe and magnetosheath plasma and magnetic field parameters. The distant neutral line may at times reside at lunar distances, creating jets of sunward-streaming plasma within the cislunar plasma sheet and layers of streaming energetic particles on its boundaries. Reconnection at near-Earth neutral lines releases antisunward-moving plasmoids that transit lunar distances, briefly expanding the diameter of the plasma sheet and magnetotail. Taken as a whole, the distant magnetotail is a fascinating plasma laboratory and a region of great important to the magnetosphere.

  19. Support Services for Distance Education

    Directory of Open Access Journals (Sweden)

    Sandra Frieden

    1999-01-01

    Full Text Available The creation and operation of a distance education support infrastructure requires the collaboration of virtually all administrative departments whose activities deal with students and faculty, and all participating academic departments. Implementation can build on where the institution is and design service-oriented strategies that strengthen institutional support and commitment. Issues to address include planning, faculty issues and concerns, policies and guidelines, approval processes, scheduling, training, publicity, information-line operations, informational materials, orientation and registration processes, class coordination and support, testing, evaluations, receive site management, partnerships, budgets, staffing, library and e-mail support, and different delivery modes (microwave, compressed video, radio, satellite, public television/cable, video tape and online. The process is ongoing and increasingly participative as various groups on campus begin to get involved with distance education activities. The distance education unit must continuously examine and revise its processes and procedures to maintain the academic integrity and service excellence of its programs. It’s a daunting prospect to revise the way things have been done for many years, but each department has an opportunity to respond to new ways of serving and reaching students.

  20. Fingerprinting with Minimum Distance Decoding

    CERN Document Server

    Lin, Shih-Chun; Gamal, Hesham El

    2007-01-01

    This work adopts an information theoretic framework for the design of collusion-resistant coding/decoding schemes for digital fingerprinting. More specifically, the minimum distance decision rule is used to identify 1 out of t pirates. Achievable rates, under this detection rule, are characterized in two distinct scenarios. First, we consider the averaging attack where a random coding argument is used to show that the rate 1/2 is achievable with t=2 pirates. Our study is then extended to the general case of arbitrary $t$ highlighting the underlying complexity-performance tradeoff. Overall, these results establish the significant performance gains offered by minimum distance decoding as compared to other approaches based on orthogonal codes and correlation detectors. In the second scenario, we characterize the achievable rates, with minimum distance decoding, under any collusion attack that satisfies the marking assumption. For t=2 pirates, we show that the rate $1-H(0.25)\\approx 0.188$ is achievable using an ...

  1. Integration of robust fluidic interconnects using metal to glass anodic bonding

    Science.gov (United States)

    Briand, Danick; Weber, Patrick; de Rooij, Nicolaas F.

    2005-09-01

    This paper reports on the encapsulation of a piezoresistive silicon/Pyrex liquid flow sensor using metal to glass anodic bonding. The bonding technique allowed integrating robust metallic microfluidic interconnects and eliminating the use of glue and O-rings. The bonding parameters of a silicon/Pyrex/metal triple stack were chosen to minimize the residual stress and to obtain a strong and liquid tight bonding interface. The silicon/Pyrex liquid flow sensor was successfully bonded to metallic plates of Kovar and Alloy 42, on which tubes were fixed and a printed circuit board (PCB) was integrated. A post-bonding annealing procedure was developed to reduce the residual bonding stress. The characteristics of the encapsulated liquid flow sensor, such as the temperature coefficient of sensitivity, fulfilled the specifications. Wafer level packaging using metal to glass anodic bonding was considered to reduce the packaging size and cost.

  2. Shear bond strength of new self-adhesive flowable composite resins.

    Science.gov (United States)

    Wajdowicz, Michael N; Vandewalle, Kraig S; Means, Mark T

    2012-01-01

    Recently, new self-adhesive flowable composite resin systems have been introduced to the market. These new composite resin systems reportedly bond to dentin and enamel without the application of an adhesive bonding agent. The purpose of this study was to evaluate the shear bond strength to enamel of two new self-adhesive flowable composites with and without the use of an etch-and-rinse bonding agent. The new self-adhesive flowable composites had significantly lower bond strengths to enamel compared to a traditional adhesively bonded flowable composite. Both self-adhesive flowable composites had a significant increase in bond strength to enamel with the use of a phosphoric acid-etch and adhesive bonding agent.

  3. Physical Nature of Hydrogen Bond

    CERN Document Server

    Zhyganiuk, I V

    2015-01-01

    The physical nature and the correct definition of hydrogen bond (H-bond) are considered.\\,\\,The influence of H-bonds on the thermodynamic, kinetic, and spectroscopic properties of water is analyzed.\\,\\,The conventional model of H-bonds as sharply directed and saturated bridges between water molecules is incompatible with the behavior of the specific volume, evaporation heat, and self-diffusion and kinematic shear viscosity coefficients of water. On the other hand, it is shown that the variation of the dipole moment of a water molecule and the frequency shift of valence vibrations of a hydroxyl group can be totally explained in the framework of the electrostatic model of H-bond.\\,\\,At the same time, the temperature dependences of the heat capacity of water in the liquid and vapor states clearly testify to the existence of weak H-bonds.\\,\\,The analysis of a water dimer shows that the contribution of weak H-bonds to its ground state energy is approximately 4--5 times lower in comparison with the energy of electr...

  4. Editorial ~ Global Diversity of Distance Education

    OpenAIRE

    2001-01-01

    In a panel presentation at the recent International Council for Open and Distance Education (ICDE) world conference in Dusseldorf, Germany, I had the opportunity to explain the unique role and mission of International Review of Research in Open and Distance Learning (IRRODL) vis – vis our more established sister journals: Open Praxis, Open Learning, Journal of Distance Education, Distance Education, and American Journal of Distance Education. Although all of these journals share a common comm...

  5. The Monge distance between quantum states

    Energy Technology Data Exchange (ETDEWEB)

    Zyczkowski, Karol [Institute for Plasma Research, University of Maryland, College Park, MD (United States); Slomczynski, Wojciech [Instytut Matematyki, Uniwersytet Jagiellonski, Cracow (Poland)

    1998-11-13

    We define a metric in the space of quantum states taking the Monge distance between corresponding Husimi distributions (Q-functions). This quantity fulfils the axioms of a metric and satisfies the following semiclassical property: the distance between two coherent states is equal to the Euclidean distance between corresponding points in the classical phase space. We compute analytically distances between certain states (coherent, squeezed, Fock and thermal) and discuss a scheme for numerical computation of Monge distance for two arbitrary quantum states. (author)

  6. Atomic bonding between metal and graphene

    KAUST Repository

    Wang, Hongtao

    2013-03-07

    To understand structural and chemical properties of metal-graphene composites, it is crucial to unveil the chemical bonding along the interface. We provide direct experimental evidence of atomic bonding between typical metal nano structures and graphene, agreeing well with density functional theory studies. Single Cr atoms are located in the valleys of a zigzag edge, and few-atom ensembles preferentially form atomic chains by self-assembly. Low migration barriers lead to rich dynamics of metal atoms and clusters under electron irradiation. We demonstrate no electron-instigated interaction between Cr clusters and pristine graphene, though Cr has been reported to be highly reactive to graphene. The metal-mediated etching is a dynamic effect between metal clusters and pre-existing defects. The resolved atomic configurations of typical nano metal structures on graphene offer insight into modeling and simulations on properties of metal-decorated graphene for both catalysis and future carbon-based electronics. © 2013 American Chemical Society.

  7. Electronic properties of anodic bonded graphene

    Science.gov (United States)

    Deepika, Balan, Adrian; Shukla, Abhay; Walter, Escoffier; Kumar, Rakesh

    2013-02-01

    Here, we report electronic properties of graphene field-effect transistor in a magnetic field of 9.0 tesla. Raman spectroscopy on graphene sample prepared by anodic bonding method shows it to be of the highest quality. The observation of charge neutrality point at a positive gate voltage is due to hole doping in the sample from the immobile oxygen ions created during anodic bonding process. Hysteresis observed in the longitudinal resistance (between source and drain) while sweeping voltage at gate in a loop may be due to high viscosity of polythene oxide matrix for mobile Li ions. The longitudinal resistance as a function of gate voltage Vg shows that both kind of charge carriers (electron and hole) can be doped in graphene, which is further ascertained by the Hall measurements.

  8. Applications of total-etch adhesive bonding.

    Science.gov (United States)

    Strassler, Howard E

    2003-06-01

    The concept of total-etch adhesion for enamel and dentin is well accepted. Although new techniques with self-etching adhesives have been introduced, there needs to be more reported clinical trials before making a complete switch to these systems. Currently, the only adhesive systems with long-term data to support confidence and success with their clinical use are total-etch systems. Applications for using a total-etch adhesive bonding technique include sealants, orthodontic brackets, anterior composite resins, posterior composite resins, bonded dental silver amalgam, resin cementation with posts, all-metal, porcelain-metal, composite resin, and ceramic restorations, splinting, core foundations, and conservative treatment of the worn dentition. This article will review the concepts for clinical success with total-etch adhesion for a wide range of clinical applications.

  9. Glutamic Acid Selective Chemical Cleavage of Peptide Bonds.

    Science.gov (United States)

    Nalbone, Joseph M; Lahankar, Neelam; Buissereth, Lyssa; Raj, Monika

    2016-03-04

    Site-specific hydrolysis of peptide bonds at glutamic acid under neutral aqueous conditions is reported. The method relies on the activation of the backbone amide chain at glutamic acid by the formation of a pyroglutamyl (pGlu) imide moiety. This activation increases the susceptibility of a peptide bond toward hydrolysis. The method is highly specific and demonstrates broad substrate scope including cleavage of various bioactive peptides with unnatural amino acid residues, which are unsuitable substrates for enzymatic hydrolysis.

  10. Tensile Behavior of Low Density Thermally Bonded Nonwoven Material

    Directory of Open Access Journals (Sweden)

    Xiaonan Hou

    2009-06-01

    Full Text Available A discontinuous and non-uniform microstructure of alow-density thermally bonded nonwoven materialdisplays in a complicated and unstable tensilebehavior. This paper reports uniaxial tensile tests of alow density thermally bonded nonwoven toinvestigate the effect of the specimen size and shapefactor, as well as the cyclic tensile loading conditionsemployed to investigate the deformational behaviorand performance of the nonwoven at differentloading stages. The experimental data are comparedwith results of microscopic image analysis and FEmodels.

  11. No.3605 report realized by the name of the Foreign Affairs Commission on the law project (no. 3156), authorizing the approbation of the protocol to the 1979 convention on the long distance transfrontier atmospheric pollution relative to the reduction of the acidification, the eutrophication and the tropospheric ozone (nine annexes); No. 3605 rapport fait au nom de la Commission des Affaires Etrangeres sur le projet de Loi (no. 3156), autorisant l'approbation du protocole a la convention de 1979 sur la pollution atmospherique transfrontiere a longue distance relatif a la reduction de l'acidification, de l'eutrophisation et de l'ozone tropospherique (ensemble neuf annexes)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-01-15

    In the framework of the 1979 convention (of Geneva), eight specific protocols have been adopted, amongch the Goteborg protocol on the long distance transfrontier atmospheric pollution. It aims to reduce of 40% to 2010, the emissions of three pollutants (sulfur dioxide, nitrogen oxides and volatile organic compounds). In this context this report presents the reinforcement of the international tools of fight against the atmospheric pollution and the Goteborg protocol in the existing devices of the air pollution abatement. (A.L.B.)

  12. Bonding over Dentin Replacement Materials.

    Science.gov (United States)

    Meraji, Naghmeh; Camilleri, Josette

    2017-08-01

    Dentin replacement materials are necessary in large cavities to protect the pulp and reduce the bulk of filling material. These materials are layered with a composite resin restorative material. Microleakage caused by poor bonding of composite resin to underlying dentin replacement material will result in pulp damage. The aim of this study was to characterize the interface between dentin replacement materials and composite resin and to measure the shear bond strength after dynamic aging. Biodentine (Septodont, Saint Maur-des-Fosses, France), Theracal LC (Bisco, Schaumburg, IL), and Fuji IX (GC, Tokyo, Japan) were used as dentin replacement materials. They were then overlaid with a total-etch and bonding agent or a self-etch primer and composite resin or a glass ionomer cement. All combinations were thermocycled for 3000 cycles. The interface was characterized using scanning electron microscopy and elemental mapping. Furthermore, the shear bond strength was assessed. The Biodentine surface was modified by etching. The Theracal LC and Fuji IX microstructure was unchanged upon the application of acid etch. The Biodentine and glass ionomer interface showed an evident wide open space, and glass particles from the glass ionomer adhered to the Biodentine surface. Elemental migration was shown with aluminum, barium, fluorine, and ytterbium present in Biodentine from the overlying composite resin. Calcium was more stable. The bond strength between Theracal LC and composite using a total-etch technique followed by self-etch primer achieved the best bond strength values. Biodentine exhibited the weakest bond with complete failure of bonding shown after demolding and thermocycling. Dynamic aging is necessary to have clinically valid data. Bonding composite resin to water-based dentin replacement materials is still challenging, and further alternatives for restoration of teeth using such materials need to be developed. Copyright © 2017 American Association of Endodontists

  13. Tensile Bond Strength of Latex-Modified Bonded Concrete Overlays

    Science.gov (United States)

    Dubois, Cameron; Ramseyer, Chris

    2010-10-01

    The tensile bond strength of bonded concrete overlays was tested using the in-situ pull-off method described in ASTM C 1583 with the goal of determining whether adding latex to the mix design increases bond strength. One slab of ductile concrete (f'c > 12,000 psi) was cast with one half tined, i.e. roughened, and one half steel-troweled, i.e. smooth. The slab surface was sectioned off and overlay mixtures containing different latex contents cast in each section. Partial cores were drilled perpendicular to the surface through the overlay into the substrate. A tensile loading device applied a direct tensile load to each specimen and the load was increased until failure occurred. The tensile bond strength was then calculated for comparison between the specimens.

  14. Integration of European Bond Markets

    DEFF Research Database (Denmark)

    Christiansen, Charlotte

    2014-01-01

    I investigate the time variation in the integration of EU government bond markets. The integration is measured by the explanatory power of European factor portfolios for the individual bond markets for each year. The integration of the government bond markets is stronger for EMU than non-EMU memb......-EMU members and stronger for old than new EU members. For EMU countries, the integration is weaker the lower the credit rating is. During the recent crisis periods, the integration is weaker, particularly for EMU countries....

  15. PRICING OF MULTIPLE DEFAULTABLE BOND

    Institute of Scientific and Technical Information of China (English)

    JianZhihong; LiChulin

    2002-01-01

    In this paper a generalized defaultable bond pricing formula is derived by assuming that there exists a defaultable forward rate term structure and that firms in the economy interact when default occurs. Generally,The risk-neutral default intensity χQ is not equal to the empirical or actual default intensity λ,. This paper proves that multiple default intensities are invari-ant under equivalent martingale transformation,given a well-diversified portfolio corresponding to the defaultable bond. Thus one can directly apply default intensities and fractional losses empirically estimated to the evaluation of defaultable bonds or contingent claims.

  16. The chemisorptive bond basic concepts

    CERN Document Server

    Clark, Alfred

    1974-01-01

    The Chemisorptive Bond: Basic Concepts describes the basic concepts of the chemisorptive bond on solid surfaces from the simple analogies with ordinary chemical bonds to the quantum-mechanical approaches.This book is composed of 10 chapters and begins with discussions of simple formulas for correlating measurable quantities in chemisorptions and catalysis. The succeeding chapters deal with theories based on quantum-mechanical principles that describe the mutual interactions of atoms of the solid and foreign atoms on the surface. The remaining chapters consider the possible arrangements

  17. Direct Bonded Pontic (Laporan Kasus

    Directory of Open Access Journals (Sweden)

    Suhandi Sidjaja

    2015-10-01

    Full Text Available Advanced science and technology in dentistry enable dental practitioners to modified she bonding techniques in tooth replacement. A pontic made of composite resin bonded to etched enamel of the adjacent teeth can be used in the replacement of one missing anterior tooth with a virgin or sowed adpicent tooth. The advantages of this technique include a one visit treatment, cow cost, good esthetics, less side effects and easy repair or rebounding. Clinical evaluation showed a high success rate therefore with a proper diagnosis and a perfect skill of the direct bonded technique this treatment can be used as an alternative restoration.

  18. Possible distance indicators in gamma-ray pulsars

    Institute of Scientific and Technical Information of China (English)

    Wei Wang

    2011-01-01

    Distance measurement of gamma-ray pulsars is a current challenge in pulsar studies. The Large Area Telescope (LAT) aboard the Fermi gamma-ray observatory discovered more than 70 gamma-ray pulsars including 24 new gamma-selected pulsars with almost no distance information. We study the relation between gammaray emission efficiency (η = Lγ/E) and pulsar parameters for young radio-selected gamma-ray pulsars with known distance information in the first gamma-ray pulsar catalog reported by Fermi/LAT. We have introduced three generation-order parameters to describe the gamma-ray emission properties of pulsars, and find a strong correlation of rη- ζ3, a generation-order parameter which reflects γ-ray photon generation in the pair cascade processes induced by magnetic field absorption in a pulsar's magnetosphere.A good correlation of η- BLC, the magnetic field at the light cylinder radius, is also found. These correlations are the distance indicators in gamma-ray pulsars used to evaluate distances for gamma-selected pulsars. Distances of 25 gamma-selected pulsars are estimated, which could be tested by other distance measurement methods. The physical origin of the correlations may also be interesting for pulsar studies.

  19. Distance in spatial interpolation of daily rain gauge data

    Directory of Open Access Journals (Sweden)

    B. Ahrens

    2006-01-01

    Full Text Available Spatial interpolation of rain gauge data is important in forcing of hydrological simulations or evaluation of weather predictions, for example. This paper investigates the application of statistical distance, like one minus common variance of observation time series, between data sites instead of geographical distance in interpolation. Here, as a typical representative of interpolation methods the inverse distance weighting interpolation is applied and the test data is daily precipitation observed in Austria. Choosing statistical distance instead of geographical distance in interpolation of available coarse network observations to sites of a denser network, which is not reporting for the interpolation date, yields more robust interpolation results. The most distinct performance enhancement is in or close to mountainous terrain. Therefore, application of statistical distance in the inverse distance weighting interpolation or in similar methods can parsimoniously densify the currently available observation network. Additionally, the success further motivates search for conceptual rain-orography interaction models as components of spatial rain interpolation algorithms in mountainous terrain.

  20. Hirshfeld atom refinement for modelling strong hydrogen bonds.

    Science.gov (United States)

    Woińska, Magdalena; Jayatilaka, Dylan; Spackman, Mark A; Edwards, Alison J; Dominiak, Paulina M; Woźniak, Krzysztof; Nishibori, Eiji; Sugimoto, Kunihisa; Grabowsky, Simon

    2014-09-01

    High-resolution low-temperature synchrotron X-ray diffraction data of the salt L-phenylalaninium hydrogen maleate are used to test the new automated iterative Hirshfeld atom refinement (HAR) procedure for the modelling of strong hydrogen bonds. The HAR models used present the first examples of Z' > 1 treatments in the framework of wavefunction-based refinement methods. L-Phenylalaninium hydrogen maleate exhibits several hydrogen bonds in its crystal structure, of which the shortest and the most challenging to model is the O-H...O intramolecular hydrogen bond present in the hydrogen maleate anion (O...O distance is about 2.41 Å). In particular, the reconstruction of the electron density in the hydrogen maleate moiety and the determination of hydrogen-atom properties [positions, bond distances and anisotropic displacement parameters (ADPs)] are the focus of the study. For comparison to the HAR results, different spherical (independent atom model, IAM) and aspherical (free multipole model, MM; transferable aspherical atom model, TAAM) X-ray refinement techniques as well as results from a low-temperature neutron-diffraction experiment are employed. Hydrogen-atom ADPs are furthermore compared to those derived from a TLS/rigid-body (SHADE) treatment of the X-ray structures. The reference neutron-diffraction experiment reveals a truly symmetric hydrogen bond in the hydrogen maleate anion. Only with HAR is it possible to freely refine hydrogen-atom positions and ADPs from the X-ray data, which leads to the best electron-density model and the closest agreement with the structural parameters derived from the neutron-diffraction experiment, e.g. the symmetric hydrogen position can be reproduced. The multipole-based refinement techniques (MM and TAAM) yield slightly asymmetric positions, whereas the IAM yields a significantly asymmetric position.

  1. 27 CFR 19.245 - Bonds and penal sums of bonds.

    Science.gov (United States)

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Bonds and penal sums of... Bonds and penal sums of bonds. The bonds, and the penal sums thereof, required by this subpart, are as follows: Penal Sum Type of bond Basis Minimum Maximum (a) Operations bond: (1) One plant bond—...

  2. 27 CFR 25.94 - Strengthening bonds.

    Science.gov (United States)

    2010-04-01

    ...) Requirement. When the penal sum of the brewer's bond (calculated as provided in § 25.93) in effect is not... strengthening bond in sufficient penal sum if the surety is the same as on the bond in effect. If the surety is... bond may not in any way release a former bond or limit a bond to less than the full penal sum. (c)...

  3. Increased wall-to-wall curing contraction in thin bonded resin layers.

    Science.gov (United States)

    Feilzer, A J; De Gee, A J; Davidson, C L

    1989-01-01

    Wall-to-wall (WTW) polymerization contraction of filled and unfilled chemically and photo-initiated resins was studied in relation to the WTW distance. In an experimental set-up, the resins were bonded to two opposing disks, and the axial (WTW) displacement resulting from the polymerization shrinkage was measured continuously. It was found that the WTW contraction increased with decreasing WTW distance and ultimately reached a value of almost three times the linear polymerization shrinkage.

  4. Vibrational analysis on the revised potential energy curve of the low-barrier hydrogen bond in photoactive yellow protein

    Directory of Open Access Journals (Sweden)

    Yusuke Kanematsu

    2016-01-01

    Full Text Available Photoactive yellow protein (PYP has a characteristic hydrogen bond (H bond between p-coumaric acid chromophore and Glu46, whose OH bond length has been observed to be 1.21 Å by the neutron diffraction technique [Proc. Natl. Acad. Sci. 106, 440–4]. Although it has been expected that such a drastic elongation of the OH bond could be caused by the quantum effect of the hydrogen nucleus, previous theoretical computations including the nuclear quantum effect have so far underestimated the bond length by more than 0.07 Å. To elucidate the origin of the difference, we performed a vibrational analysis of the H bond on potential energy curve with O…O distance of 2.47 Å on the equilibrium structure, and that with O…O distance of 2.56 Å on the experimental crystal structure. While the vibrationally averaged OH bond length for equilibrium structure was underestimated, the corresponding value for crystal structure was in reasonable agreement with the corresponding experimental values. The elongation of the O…O distance by the quantum mechanical or thermal fluctuation would be indispensable for the formation of a low-barrier hydrogen bond in PYP.

  5. Hydrogen bonding in tight environments

    DEFF Research Database (Denmark)

    Pirrotta, Alessandro; Solomon, Gemma C.; Franco, Ignacio

    2016-01-01

    The single-molecule force spectroscopy of a prototypical class of hydrogen-bonded complexes is computationally investigated. The complexes consist of derivatives of a barbituric acid and a Hamilton receptor that can form up to six simultaneous hydrogen bonds. The force-extension (F-L) isotherms...... of the host-guest complexes are simulated using classical molecular dynamics and the MM3 force field, for which a refined set of hydrogen bond parameters was developed from MP2 ab initio computations. The F-L curves exhibit peaks that signal conformational changes during elongation, the most prominent...... of which is in the 60-180 pN range and corresponds to the force required to break the hydrogen bonds. These peaks in the F-L curves are shown to be sensitive to relatively small changes in the chemical structure of the host molecule. Thermodynamic insights into the supramolecular assembly were obtained...

  6. Modified bonded bridge space maintainer.

    Science.gov (United States)

    Liegeois, F; Limme, M

    1999-01-01

    The premature loss of primary teeth can create the need for space maintenance and restoration of function. This article presents a fixed bonded space maintainer, which allows space to be maintained with economy of dental tissues.

  7. Weld bonding of stainless steel

    DEFF Research Database (Denmark)

    Santos, I. O.; Zhang, Wenqi; Goncalves, V.M.

    2004-01-01

    This paper presents a comprehensive theoretical and experimental investigation of the weld bonding process with the purpose of evaluating its relative performance in case of joining stainless steel parts, against alternative solutions based on structural adhesives or conventional spot...

  8. Adhesives for orthodontic bracket bonding

    Directory of Open Access Journals (Sweden)

    Déborah Daniella Diniz Fonseca

    2010-04-01

    Full Text Available The advent of acid etching, introduced by Buonocore in 1955, brought the possibility of bonding between the bracket base and enamel, contributing to more esthetic and conservative orthodontics. This direct bracket bonding technique has brought benefits such as reduced cost and time in performing the treatment, as well as making it easier to perform oral hygiene. The aim of this study was to conduct a survey of published studies on orthodontic bracket bonding to dental enamel. It was verified that resin composites and glass ionomer are the most studied and researched materials for this purpose. Resin-modified glass ionomer, with its biocompatibility, capacity of releasing fluoride and no need for acid etching on the tooth structure, has become increasingly popular among dentists. However, due to the esthetic and mechanical properties of light polymerizable resin composite, it continues to be one of the adhesives of choice in the bracket bonding technique and its use is widely disseminated.

  9. Mattig's relation and dynamical distance indicators

    CERN Document Server

    Teerikorpi, Pekka

    2016-01-01

    We discuss how the redshift (Mattig) method in Friedmann cosmology relates to dynamical distance indicators based on Newton's gravity (Teerikorpi 2011). It belongs to the class of indicators where the relevant length inside the system is the distance itself (in this case the proper metric distance). As the Friedmann model has Newtonian analogy, its use to infer distances has instructive similarities to classical dynamical distance indicators. In view of the theoretical exact linear distance-velocity law, we emphasize that it is conceptually correct to derive the cosmological distance via the route: redshift (primarily observed) --> space expansion velocity (not directly observed) --> metric distance (physical length in "cm"). Important properties of the proper metric distance are summarized.

  10. Distance caregiving a family member with cancer: A review of the literature on distance caregiving and recommendations for future research.

    Science.gov (United States)

    Douglas, Sara L; Mazanec, Polly; Lipson, Amy; Leuchtag, Mary

    2016-04-10

    Distance caregivers (DCGs) are a growing phenomenon in the United States Family members are struggling to provide care to loved ones with chronic illnesses such as cancer, from a distance. Unlike local caregiving research, distance caregiving research is limited and inconsistent definitions of distance make it difficult to compare studies. To date, DCGs have not been afforded the opportunities for educational and emotional support that local caregivers have received from the health care teams. Because they are not usually present at medical appointments, DCGs do not receive first-hand information from the health care team about the patient's condition, disease progression, and/or treatment options. These caregivers report feeling left out of important family discussions. They experience anxiety related to the uncertainty of the family members' well-being and guilt related to not being available to help local caregivers more. The challenges of distance caregiving are especially evident when the distance caregiver has a parent with advanced cancer. Family-centered care, attending to the needs of the whole family regardless of their geographic location is critical for quality cancer care. In this manuscript, the sparse literature on distance caregiving is reviewed. Recommendations for future research and for the development of creative technologically advanced interventions for this underserved caregiving population are suggested.

  11. An overview on distance and pseudo distance functions and their applications

    Institute of Scientific and Technical Information of China (English)

    ZHU Xiangyang; DING Han; ZHONG Binglin; XIONG Youlun

    2003-01-01

    The fast and accurate collision detection and distance calculation between geometric models is fundamental in robotics, manufacturing and computer-simulated environments. This paper surveys the state of the art in the theory and algorithms of distance and pseudo distance functions between convex sets. An overview on the existing results, including fast algorithms for distance calculation, definitions and properties of various pseudo distance functions (the J-function, the growth distance, and the pseudo minimum translational distance), is presented. The distance and pseudo distance functions are versatile in a wide range of areas. Their applications in robot motion planning, grasp analysis/synthesis, form error evaluation, and engineering optimization is demonstrated.

  12. Variable Distance Angular Symbology Reader

    Science.gov (United States)

    Schramm, Harry F., Jr. (Inventor); Corder, Eric L. (Inventor)

    2006-01-01

    A variable distance angular symbology, reader utilizes at least one light source to direct light through a beam splitter and onto a target. A target may be angled relative to the impinging light beam up to and maybe even greater than 45deg. A reflected beam from the target passes through the beam splitter and is preferably directed 90deg relative to the light source through a telecentric lens to a scanner which records an image of the target such as a direct part marking code.

  13. Understanding Rotation about a C=C Double Bond

    Science.gov (United States)

    Barrows, Susan E.; Eberlein, Thomas H.

    2005-09-01

    In this article, twisting about the C=C double bond and the consequential pyramidalization of sp 2 carbon atoms in alkenes were examined in a molecular modeling study using trans -2-butene as a model system. According to our trans -2-butene model and other similar work, most of the strength of a π bond is retained upon twisting, even for remarkably large C C=C C dihedral angles (up to 90°). The phenomenon of sp 2 carbon atom pyramidalization and preservation of π bond strength upon twisting a C=C double bond is well established in the literature, but is rarely discussed in introductory textbooks. This absence is noteworthy because profound manifestations of this effect do occur in compounds that are covered in an introductory organic chemistry curriculum. We present a simple method of introducing the concept of a flexible C=C π bond into beginning organic chemistry courses. We report the energetic demands of partial twisting about the C=C bond in 2-butene as calculated using DFT, LMP2, and MCSCF methods. Finally, using the results of these calculations, we assessed the degree of strain introduced by the twisted nature of the C=C bond in trans cycloalkenes.

  14. The Impact of Premature Childbirth on Parental Bonding

    Directory of Open Access Journals (Sweden)

    Hannah N. Hoffenkamp

    2012-07-01

    Full Text Available The development of an affectionate parent-infant bond is essential for a newborn infant's survival and development. However, from evolutionary theory it can be derived that parental bonding is not an automatic process, but dependent on infants' cues to reproductive potential and parents' access to resources. The purpose of the present study was to examine the process of bonding in a sample of Dutch mothers (n = 200 and fathers (n = 193 of full-term (n = 69, moderately premature (n = 68, and very premature infants (n = 63. During the first month postpartum parents completed the Pictorial Representation of Attachment Measure (PRAM and Postpartum Bonding Questionnaire (PBQ. Longitudinal analyses revealed that mothers' PRAM scores decreased after moderately preterm delivery, whereas decreases in PRAM scores occurred in both parents after very preterm delivery. As lower PRAM scores represent stronger feelings of parent-infant connectedness, our findings suggest a higher degree of bonding after premature childbirth. Results of the PBQ analysis were in line with PRAM outcomes, as parents of preterm infants reported less bonding problems compared to parents of full-terms. These findings support the hypothesis that in affluent countries with adequate resources, bonding in parents of preterm infants on average may be higher than in parents of full-term infants.

  15. The impact of premature childbirth on parental bonding.

    Science.gov (United States)

    Hoffenkamp, Hannah N; Tooten, Anneke; Hall, Ruby A S; Croon, Marcel A; Braeken, Johan; Winkel, Frans Willem; Vingerhoets, Ad J J M; van Bakel, Hedwig J A

    2012-08-17

    The development of an affectionate parent-infant bond is essential for a newborn infant's survival and development. However, from evolutionary theory it can be derived that parental bonding is not an automatic process, but dependent on infants' cues to reproductive potential and parents' access to resources. The purpose of the present study was to examine the process of bonding in a sample of Dutch mothers (n = 200) and fathers (n = 193) of full-term (n = 69), moderately premature (n = 68), and very premature infants (n = 63). During the first month postpartum parents completed the Pictorial Representation of Attachment Measure (PRAM) and Postpartum Bonding Questionnaire (PBQ). Longitudinal analyses revealed that mothers' PRAM scores decreased after moderately preterm delivery, whereas decreases in PRAM scores occurred in both parents after very preterm delivery. As lower PRAM scores represent stronger feelings of parent-infant connectedness, our findings suggest a higher degree of bonding after premature childbirth. Results of the PBQ analysis were in line with PRAM outcomes, as parents of preterm infants reported less bonding problems compared to parents of full-terms. These findings support the hypothesis that in affluent countries with adequate resources, bonding in parents of preterm infants on average may be higher than in parents of full-term infants.

  16. Doing the Limbo with a Low Barrier: Hydrogen Bonding and Proton Transfer in Hydroxyformylfulvene

    Science.gov (United States)

    Vealey, Zachary; Nemchick, Deacon; Vaccaro, Patrick

    2016-06-01

    Model compounds continue to play crucial roles for elucidating the ubiquitous phenomena of hydrogen bonding and proton transfer, often yielding invaluable insights into kindred processes taking place in substantially larger species. The symmetric double-minimum topography that characterizes the potential-energy landscape for an important subset of these systems allows unambiguous signatures of molecular dynamics (in the form of tunneling-induced bifurcations) to be extracted directly from spectral measurements. As a relatively unexplored member of this class, 6-hydroxy-2-formylfulvene (HFF) contains an intramolecular O-H···O interaction that has participating atoms from the hydroxylic (donor) and ketonic (acceptor) moieties closely spaced in a quasi-linear configuration. This unusual arrangement suggests proton transduction to occur with minimal encumbrance, possibly leading to a pronounced dislocation of the shuttling hydron commensurate with the concepts of low-barrier hydrogen bonding (which are distinguished by great strength, short distance, and vanishingly small potential barriers). A variety of spectroscopic probes built primarily upon the techniques of laser-induced fluorescence and dispersed fluorescence have been enlisted to acquire the first vibronically resolved information reported for the ground [tilde{X}1A1] and lowest-lying singlet excited [tilde{A}1B{2} (π*π)] electronic manifolds of HFF entrained in a cold supersonic free-jet expansion. These experimental findings will be discussed and compared to those obtained for related proton-transfer systems, with complimentary quantum-chemical calculations serving to unravel the unique bonding motifs and reactive pathways inherent to HFF.

  17. Shear Bond Strength of Orthodontic Brackets Bonded to Zirconium Crowns

    Science.gov (United States)

    Mehmeti, Blerim; Azizi, Bleron; Kelmendi, Jeta; Iljazi-Shahiqi, Donika; Alar, Željko

    2017-01-01

    Background An increasing demand for esthetic restorations has resulted in an increased use of all-ceramic restorations, such as zirconium. However, one of the challenges the orthodontist must be willing to face is how to increase bond strength between the brackets and various ceramic restorations.Bond strength can beaffected bybracket type, by the material that bracketsaremade of, and their base surface design or retention mode. ​ Aim: of this study was to perform a comparative analysis of the shear bond strength (SBS) of metallic and ceramic orthodontic brackets bonded to all-zirconium ceramic surfaces used for prosthetic restorations, and also to evaluate the fracture mode of these two types of orthodontic brackets. Material and methods Twenty samples/semi-crowns of all-zirconium ceramic, on which orthodontic brackets were bonded, 10 metallic and 10 ceramic polycrystalline brackets, were prepared for this research. SBS has been testedby Universal Testing Machine, with a load applied using a knife edged rod moving at a fixed rate of 1 mm/min, until failure occurred. The force required to debond the brackets was recorded in Newton, then SBS was calculated to MPa. In addition, the samples were analyzed using a digital camera magnifier to determine Adhesive Remnant Index (ARI). Statistical data were processed using t-test, and the level of significance was set at α = 0.05. Results Higher shear bond strength values were observed in metallic brackets bonded to zirconium crowns compared tothoseof ceramic brackets, with a significant difference. During the test, two of the ceramic brackets were partially or totally damaged. Conclusion Metallic brackets, compared to ceramic polycrystalline brackets, seemed tocreate stronger adhesion with all-zirconium surfaces due to their better retention mode. Also, ceramic brackets showed higher fragility during debonding. PMID:28827846

  18. Anxiety and Resistance in Distance Learning

    Directory of Open Access Journals (Sweden)

    Nazime Tuncay

    2010-06-01

    Full Text Available The purpose of this study was to investigate students' anxiety and resistance towards learning through distance education.Specifically, the study sought answers to the following questions: -What are the reasons of students not choosing distancelearning courses? -Which symptoms of anxiety, if any, do distance learner’s exhibit towards distance learning? Does genderhave any significant relationships with distance learners' perception of factors that affect their anxiety and resistance? A totalof 120 distance education students in Near East University were observed and 96 of them were interviewed. Computer anxiety,language anxiety, social anxiety were observed to be among the reasons of students’ resistance to distance learning.

  19. A note on the path interval distance.

    Science.gov (United States)

    Coons, Jane Ivy; Rusinko, Joseph

    2016-06-01

    The path interval distance accounts for global congruence between locally incongruent trees. We show that the path interval distance provides a lower bound for the nearest neighbor interchange distance. In contrast to the Robinson-Foulds distance, random pairs of trees are unlikely to be maximally distant from one another under the path interval distance. These features indicate that the path interval distance should play a role in phylogenomics where the comparison of trees on a fixed set of taxa is becoming increasingly important.

  20. Lightweight Distance Bounding Protocol against Relay Attacks

    Science.gov (United States)

    Kim, Jin Seok; Cho, Kookrae; Yum, Dae Hyun; Hong, Sung Je; Lee, Pil Joong

    Traditional authentication protocols are based on cryptographic techniques to achieve identity verification. Distance bounding protocols are an enhanced type of authentication protocol built upon both signal traversal time measurement and cryptographic techniques to accomplish distance verification as well as identity verification. A distance bounding protocol is usually designed to defend against the relay attack and the distance fraud attack. As there are applications to which the distance fraud attack is not a serious threat, we propose a streamlined distance bounding protocol that focuses on the relay attack. The proposed protocol is more efficient than previous protocols and has a low false acceptance rate under the relay attack.