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Sample records for reorientation task michael

  1. Using Perceptrons to Explore the Reorientation Task

    Science.gov (United States)

    Dawson, Michael R. W.; Kelly, Debbie M.; Spetch, Marcia L.; Dupuis, Brian

    2010-01-01

    The reorientation task is a paradigm that has been used extensively to study the types of information used by humans and animals to navigate in their environment. In this task, subjects are reinforced for going to a particular location in an arena that is typically rectangular in shape. The subject then has to find that location again after being…

  2. Age-related differences during a gaze reorientation task while standing or walking on a treadmill.

    Science.gov (United States)

    Cinelli, Michael; Patla, Aftab; Stuart, Bethany

    2008-02-01

    Falls among adults over the age of 65 years have become a growing concern. Two factors related to high incidence of falls in this group of adults are decreased head stability and impaired balance. Older adults' level of control of head stability or balance is unknown when they must reorient their gaze. In the current study, ten older adults (69 +/- 3.27 years) performed a gaze reorienting task while standing or walking on a treadmill. The task was the same as that used on young adults by Cinelli et al. (2007). The results show that older adults use a different strategy than young adults when reorienting gaze. Shoulder and hip rotations occurred synchronously when standing and were more variable when walking on a treadmill. As well, there was a larger difference between the onset of eye movements and body segment movement in the older adults. These differences can be accounted for by decreases in physiological subsystems. The visual presence of a visual target helped the older adults stabilize their heads-in-space by incorporating information from more than one sensory system.

  3. rTMS of medial parieto-occipital cortex interferes with attentional reorienting during attention and reaching tasks.

    Science.gov (United States)

    Ciavarro, Marco; Ambrosini, Ettore; Tosoni, Annalisa; Committeri, Giorgia; Fattori, Patrizia; Galletti, Claudio

    2013-09-01

    Unexpected changes in the location of a target for an upcoming action require both attentional reorienting and motor planning update. In both macaque and human brain, the medial posterior parietal cortex is involved in both phenomena but its causal role is still unclear. Here we used on-line rTMS over the putative human V6A (pV6A), a reach-related region in the dorsal part of the anterior bank of the parieto-occipital sulcus, during an attention and a reaching task requiring covert shifts of attention and planning of reaching movements toward cued targets in space. We found that rTMS increased RTs to invalidly cued but not to validly cued targets during both the attention and reaching task. Furthermore, we found that rTMS induced a deviation of reaching endpoints toward visual fixation and that this deviation was larger for invalidly cued targets. The results suggest that reorienting signals are used by human pV6A area to rapidly update the current motor plan or the ongoing action when a behaviorally relevant object unexpectedly occurs in an unattended location. The current findings suggest a direct involvement of the action-related dorso-medial visual stream in attentional reorienting and a more specific role of pV6A area in the dynamic, on-line control of reaching actions.

  4. Michael Thonet

    Index Scriptorium Estoniae

    2005-01-01

    Saksa päritolu austria mööblidisaineri ja mööblitöösturi Michael Thonet' (1796-1871) disainiloomingust. 1859. a. Michael Thonet' loodud tool nr. 14 on endiselt tootmises ja on tuntud ka Viini toolina. 2 ill

  5. Michael Thonet

    Index Scriptorium Estoniae

    2005-01-01

    Saksa päritolu austria mööblidisaineri ja mööblitöösturi Michael Thonet' (1796-1871) disainiloomingust. 1859. a. Michael Thonet' loodud tool nr. 14 on endiselt tootmises ja on tuntud ka Viini toolina. 2 ill

  6. Michael Schwantzer

    Institute of Scientific and Technical Information of China (English)

    ROGERZHANG

    2004-01-01

    In the seven years that he has been in China, German-native Michael, Schwantzer has found himself at the sharp end of business,building up a successful enterprise from humble beginnings in a highly competitive market. Michael initially came to China in 1997 to run a Sino-German joint venture supplying the shipbuilding industry in Nanjing. Two years later he joined LAP, starting the company's China operations. Within two years he had helped bring LAP's annual China sales from zero to US$ 5 million, in part through his extensive contacts within the steel industry.Based in Shanghai, where he lives with his wife and two children, Michael has caught the China-bug and has no plans to return to his native Germany. “Why would I?” he says.“Shanghai is the place to be right now.”

  7. Michael Scott

    Directory of Open Access Journals (Sweden)

    Ersin Hussein

    2015-04-01

    Full Text Available Associate Professor Michael Scott is a researcher and lecturer based in the department of Classics and Ancient History at the University of Warwick. He is also President of the Lytham St Annes Classical Association. Prior to his appointment at Warwick, Michael was the Moses and Mary Finley Research Fellow in ancient history at Darwin College, as well as an Affiliated Lecturer in the Faculty of Classics, at Cambridge University.Michael's research and teaching engages with interdisciplinary approaches to the literary, epigraphic and material evidence to investigate ancient Greek and Roman society, particularly focusing on Delphi and Olympia as religious spaces.While Michael has contributed significantly to the field of classics and ancient history by publishing extensively, he has also enjoyed great success in engaging wider audiences with the ancient world. He regularly talks in schools around the country, writes books intended for the popular market as well as articles for national and international newspapers and magazines. Michael's experience in writing and presenting a range of programmes intended for TV and radio audiences has made him a household name. He has written and presented programmes for the National Geographic, History Channel, Nova, and the BBC including Delphi: bellybutton of the ancient world (BBC4; Guilty Pleasures: luxury in the ancient and medieval words (BBC4; Jesus: rise to power (Natural Geographic; Ancient Discoveries (History Channel; Who were the Greeks? (BBC2; The Mystery of the X Tombs (BBC2/Nova; The Greatest Show on Earth (BBC4, in conjunction with the Open University. He has also presented a radio series for BBC Radio 4, Spin the Globe. Michael's most recent programme, Roman Britain from the Air, was aired on ITV in December 2014.In this interview, I talk to him about his engagement with other disciplines within the humanities, his forthcoming book project, and his experiences writing and presenting TV and radio

  8. Michael Jordan

    Institute of Scientific and Technical Information of China (English)

    汪仙美

    2000-01-01

    Many of us know Michael Jordan is a famous American basketball star. He is perhaps the greatest player in basketball history. Jordan is 1.98m tall. He plays guard(后卫)for the Chicago Bulls. He led his team to six NBA(National Basketball Association ) championships (冠军4).

  9. Spinning in the Scanner: Neural Correlates of Virtual Reorientation

    Science.gov (United States)

    Sutton, Jennifer E.; Joanisse, Marc F.; Newcombe, Nora S.

    2010-01-01

    Recent studies have used spatial reorientation task paradigms to identify underlying cognitive mechanisms of navigation in children, adults, and a range of animal species. Despite broad interest in this task across disciplines, little is known about the brain bases of reorientation. We used functional magnetic resonance imaging to examine neural…

  10. Spinning in the Scanner: Neural Correlates of Virtual Reorientation

    Science.gov (United States)

    Sutton, Jennifer E.; Joanisse, Marc F.; Newcombe, Nora S.

    2010-01-01

    Recent studies have used spatial reorientation task paradigms to identify underlying cognitive mechanisms of navigation in children, adults, and a range of animal species. Despite broad interest in this task across disciplines, little is known about the brain bases of reorientation. We used functional magnetic resonance imaging to examine neural…

  11. Navigation as a source of geometric knowledge: Young children’s use of length, angle, distance, and direction in a reorientation task

    Science.gov (United States)

    Lee, Sang Ah; Sovrano, Valeria A.; Spelke, Elizabeth S.

    2012-01-01

    Geometry is one of the highest achievements of our species, but its foundations are obscure. Consistent with longstanding suggestions that geometrical knowledge is rooted in processes guiding navigation, the present study examines potential sources of geometrical knowledge in the navigation processes by which young children establish their sense of orientation. Past research reveals that children reorient both by the shape of the surface layout and the shapes of distinctive landmarks, but it fails to clarify what shape properties children use. The present study explores two-year-old children's sensitivity to angle, length, distance and direction by testing disoriented children’s search in a variety of fragmented rhombic and rectangular environments. Children reoriented themselves in accord with surface distances and directions, but they failed to use surface lengths or corner angles either for directional reorientation or as local landmarks. Thus, navigating children navigate by some but not all of the abstract properties captured by formal Euclidean geometry. While navigation systems may contribute to children's developing geometric understanding, they likely are not the sole source of abstract geometric intuitions. PMID:22257573

  12. Reorienting with terrain slope and landmarks.

    Science.gov (United States)

    Nardi, Daniele; Newcombe, Nora S; Shipley, Thomas F

    2013-02-01

    Orientation (or reorientation) is the first step in navigation, because establishing a spatial frame of reference is essential for a sense of location and heading direction. Recent research on nonhuman animals has revealed that the vertical component of an environment provides an important source of spatial information, in both terrestrial and aquatic settings. Nonetheless, humans show large individual and sex differences in the ability to use terrain slope for reorientation. To understand why some participants--mainly women--exhibit a difficulty with slope, we tested reorientation in a richer environment than had been used previously, including both a tilted floor and a set of distinct objects that could be used as landmarks. This environment allowed for the use of two different strategies for solving the task, one based on directional cues (slope gradient) and one based on positional cues (landmarks). Overall, rather than using both cues, participants tended to focus on just one. Although men and women did not differ significantly in their encoding of or reliance on the two strategies, men showed greater confidence in solving the reorientation task. These facts suggest that one possible cause of the female difficulty with slope might be a generally lower spatial confidence during reorientation.

  13. Reorienting Hypnosis Education.

    Science.gov (United States)

    Alter, David S; Sugarman, Laurence Irwin

    2017-01-01

    The legacy model of professional clinical hypnosis training presents a restrictive frame increasingly incompatible with our evolving understanding of psychobiology, health, and care. Emerging science recognizes human experience not as disease and diagnosis, but as manifestations of individual, uniquely-endowed, adaptively self-regulating systems. Hypnosis is a particularly well-suited discipline for effecting beneficial change in this paradigm. Training in clinical hypnosis must progress from the current linearly-structured, diagnosis-based, reductionist model toward a more responsive, naturalistic, and client-centered curriculum in order to remain relevant and accessible to clinicians beginning to integrate it into their practices. To that end, this article extends Hope and Sugarman's (2015) thesis of hypnosis as a skill set for systemic perturbation and reorientation to consider what those skills may be, the principles on which they are based, and how they may be taught. Parsing a clinical vignette reveals how incorporation of novelty and uncertainty results in less restrictive and more naturalistic hypnotic encounters that, in response to client-generated cues, elicit psychophysiological plasticity. This disruptive hypnosis education and training framework extends the utility and benefit of applied clinical hypnosis.

  14. Cell reorientation under cyclic stretching

    CERN Document Server

    Livne, Ariel; Geiger, Benjamin

    2014-01-01

    Mechanical cues from the extracellular microenvironment play a central role in regulating the structure, function and fate of living cells. Nevertheless, the precise nature of the mechanisms and processes underlying this crucial cellular mechanosensitivity remains a fundamental open problem. Here we provide a novel framework for addressing cellular sensitivity and response to external forces by experimentally and theoretically studying one of its most striking manifestations -- cell reorientation to a uniform angle in response to cyclic stretching of the underlying substrate. We first show that existing approaches are incompatible with our extensive measurements of cell reorientation. We then propose a fundamentally new theory that shows that dissipative relaxation of the cell's passively-stored, two-dimensional, elastic energy to its minimum actively drives the reorientation process. Our theory is in excellent quantitative agreement with the complete temporal reorientation dynamics of individual cells, measu...

  15. Optimal Reorientation Of Spacecraft Orbit

    Directory of Open Access Journals (Sweden)

    Chelnokov Yuriy Nikolaevich

    2014-06-01

    Full Text Available The problem of optimal reorientation of the spacecraft orbit is considered. For solving the problem we used quaternion equations of motion written in rotating coordinate system. The use of quaternion variables makes this consideration more efficient. The problem of optimal control is solved on the basis of the maximum principle. An example of numerical solution of the problem is given.

  16. Reorientation from Altered States: Please, More Carefully.

    Science.gov (United States)

    Heikkinen, Charles A.

    1989-01-01

    Claims counselors too often appear to forget to reorient clients from altered states of consciousness used in counseling and that failure to reorient can result in unnecessary discomfort for clients. Provides suggestions for when and how to reorient to avoid unwanted, lingering aftereffects. (Author/ABL)

  17. Following Michael Faraday's Footprints

    Science.gov (United States)

    Galeano, Javier

    2011-01-01

    Last fall I had the good fortune of receiving financial support to shoot a documentary about Michael Faraday. I took the opportunity to learn more about this great experimentalist and to visit the highlights of places in his life. In this paper, I would like to share a list and description of some of the most remarkable places in London suitable…

  18. Michael Faraday's Bicentenary.

    Science.gov (United States)

    Williams, L. Pearce; And Others

    1991-01-01

    Six articles discuss the work of Michael Faraday, a chemist whose work revolutionized physics and led directly to both classical field and relativity theory. The scientist as a young man, the electromagnetic experiments of Faraday, his search for the gravelectric effect, his work on optical glass, his laboratory notebooks, and his creative use of…

  19. Michael Faraday, media man.

    Science.gov (United States)

    Fara, Patricia

    2006-03-01

    Michael Faraday was an enthusiastic portrait collector, and he welcomed the invention of photography not only as a possible means of recording observations accurately, but also as a method for advertising science and its practitioners. This article (which is part of the Science in the Industrial Revolution series) shows that like many eminent scientists, Faraday took advantage of the burgeoning Victorian media industry by posing in various roles.

  20. Genomic Signals of Reoriented ORFs

    Directory of Open Access Journals (Sweden)

    Paul Dan Cristea

    2004-01-01

    Full Text Available Complex representation of nucleotides is used to convert DNA sequences into complex digital genomic signals. The analysis of the cumulated phase and unwrapped phase of DNA genomic signals reveals large-scale features of eukaryote and prokaryote chromosomes that result from statistical regularities of base and base-pair distributions along DNA strands. By reorienting the chromosome coding regions, a “hidden” linear variation of the cumulated phase has been revealed, along with the conspicuous almost linear variation of the unwrapped phase. A model of chromosome longitudinal structure is inferred on these bases.

  1. A Molecular Jump Mechanism of Water Reorientation

    National Research Council Canada - National Science Library

    Damien Laage; James T. Hynes

    2006-01-01

    .... This water reorientation mechanism involves large-amplitude angular jumps, rather than the commonly accepted sequence of small diffusive steps, and therefore calls for reinterpretation of many...

  2. Environmental Geometry Aligns the Hippocampal Map during Spatial Reorientation.

    Science.gov (United States)

    Keinath, Alex T; Julian, Joshua B; Epstein, Russell A; Muzzio, Isabel A

    2017-02-06

    When a navigator's internal sense of direction is disrupted, she must rely on external cues to regain her bearings, a process termed spatial reorientation. Extensive research has demonstrated that the geometric shape of the environment exerts powerful control over reorientation behavior, but the neural and cognitive mechanisms underlying this phenomenon are not well understood. Whereas some theories claim that geometry controls behavior through an allocentric mechanism potentially tied to the hippocampus, others postulate that disoriented navigators reach their goals by using an egocentric view-matching strategy. To resolve this debate, we characterized hippocampal representations during reorientation. We first recorded from CA1 cells as disoriented mice foraged in chambers of various shapes. We found that the alignment of the recovered hippocampal map was determined by the geometry of the chamber, but not by nongeometric cues, even when these cues could be used to disambiguate geometric ambiguities. We then recorded hippocampal activity as disoriented mice performed a classical goal-directed spatial memory task in a rectangular chamber. Again, we found that the recovered hippocampal map aligned solely to the chamber geometry. Critically, we also found a strong correspondence between the hippocampal map alignment and the animal's behavior, making it possible to predict the search location of the animal from neural responses on a trial-by-trial basis. Together, these results demonstrate that spatial reorientation involves the alignment of the hippocampal map to local geometry. We hypothesize that geometry may be an especially salient cue for reorientation because it is an inherently stable aspect of the environment. Copyright © 2017 Elsevier Ltd. All rights reserved.

  3. Michael Learns to Rock

    Institute of Scientific and Technical Information of China (English)

    汪海涛

    2004-01-01

    夜幕降临.空气中传来北欧的声音,来自丹麦的四人流行乐队Michael Learns to Rock(迈克学摇滚)正把探情款款的歌声带到上海的咖啡厅和酒吧。北欧一直活跃着一批世界顶级的乐队.从丹麦的A-Ha到Aqua,从瑞典的ABBA到Roxette和Ace of Base,从挪威的Se

  4. Michael Frayn visits CERN

    CERN Document Server

    2007-01-01

    Award-winning playwright and novelist Michael Frayn gave a guest lecture in the main auditorium at CERN on Friday 15 March about his new book The Human Touch: Our Part in the Creation of the Universe. The lecture focused on cosmology and philosophy and the limitations that language places on our ability to understand the creation of a universe in which we seem to play such a small part. In addition to his novels and plays, which include Copenhagen, a play about the 1941 meeting between German physicist Werner Heisenberg and Danish physicist Niels Bohr, Frayn has translated several works from Russian, including plays by Chekhov and Tolstoy.

  5. INIST: databases reorientation; INIST: reorientation des bases de donnees

    Energy Technology Data Exchange (ETDEWEB)

    Bidet, J.C.

    1995-08-01

    INIST is a CNRS (Centre National de la Recherche Scientifique) laboratory devoted to the treatment of scientific and technical informations and to the management of these informations compiled in a database. Reorientation of the database content has been proposed in 1994 to increase the transfer of research towards enterprises and services, to develop more automatized accesses to the informations, and to create a quality assurance plan. The catalog of publications comprises 5800 periodical titles (1300 for fundamental research and 4500 for applied research). A science and technology multi-thematic database will be created in 1995 for the retrieval of applied and technical informations. ``Grey literature`` (reports, thesis, proceedings..) and human and social sciences data will be added to the base by the use of informations selected in the existing GRISELI and Francis databases. Strong modifications are also planned in the thematic cover of Earth sciences and will considerably reduce the geological information content. (J.S.). 1 tab.

  6. The reorientation of spatial planning systems and policies

    DEFF Research Database (Denmark)

    Galland, Daniel; Enemark, Stig

    2012-01-01

    spatial planning has become reoriented. This is performed through an empirical analysis regarding the transformation of spatial planning in relation with the evolving conception of planning policies at different scales, the changing role of planning in conceiving and handling growth and development......Danish spatial planning has been increasingly subjected to profound reorientations over the past two decades. The comprehensive frame wherein planning policies and practices operated across different levels of administration has become significantly altered. This has been particularly evident after...... radical shifts in terms of the scope of planning policies, the implementation of land-use tasks as well as the performance of the institutional arrangements operating within and beyond the planning system. Based on an in-depth analysis concerned with these changes, the paper endeavours into discussing how...

  7. Professor Michael Levitt

    Directory of Open Access Journals (Sweden)

    Gemma-Louise Davies

    2015-10-01

    Full Text Available Professor Michael Levitt (Stanford University, USA won the 2013 Nobel Prize in Chemistry for the development of multiscale models for complex chemical systems—computational tools which can calculate the course of chemical reactions. Professor Levitt was born in Pretoria, South Africa; he came to the UK on a summer vacation aged 16, where he decided to stay and study for his A‑levels. His interest in the physics of living systems drove him to study biophysics at King’s College London, before securing a PhD position at the Laboratory of Molecular Biology in Cambridge. In the interim year between his degree and beginning his PhD, Professor Levitt worked at the Weizmann Institute of Science in Israel, where he met his future wife. They married later that year and moved to Cambridge, where their three children were born. After completing his PhD, he spent time working in Israel, Cambridge, the Salk Institute and Stanford (both California. Since 1986, he has split his time between Israel and California. Outside of science, he is a keen hiker and he is well-known to have attended the eclectic ‘Burning Man’ Festival in California.[1]Professor Levitt visited the University of Warwick to speak at the Computational Molecular Science Annual Conference in March 2015. In this interview, Dr Gemma-Louise Davies, an Institute of Advanced Study Global Research Fellow, spoke to Professor Levitt about the importance of Interdisciplinarity in his field, role models in Academia, and his plans for the future.Image: Professor Michael Levitt (left with Dr Scott Habershon (right, organiser of the 2015 Computational Molecular Science Annual Conference during his visit to the University of Warwick in March 2015.[1] ‘Burning Man’ is a unique annual festival dedicated to community, art, music, self-expression and self-reliance. Tens of thousands of people flock to this temporary metropolis built in the Californian desert.

  8. Enantioselective Michael Addition of Water

    NARCIS (Netherlands)

    Chen, B.S.; Resch, V.; Otten, L.G.; Hanefeld, U.

    2014-01-01

    The enantioselective Michael addition using water as both nucleophile and solvent has to date proved beyond the ability of synthetic chemists. Herein, the direct, enantioselective Michael addition of water in water to prepare important β-hydroxy carbonyl compounds using whole cells of Rhodococcus st

  9. Interview with Michael Gazzaniga.

    Science.gov (United States)

    Gazzaniga, Michael

    2011-04-01

    Widely considered the father of the field of cognitive neuroscience, Professor Michael S. Gazzaniga is one of the world's premier neuroscientists. He founded the Center for Neuroscience at the University of California, Davis; the Center for Cognitive Neuroscience at Dartmouth College; the Cognitive Neuroscience Institute; Journal of Cognitive Neuroscience; and the Cognitive Neuroscience Society. He is currently the director of the Sage Center for the Study of the Mind at the University of California, Santa Barbara. Born on December 12, 1939 in Los Angeles and educated at Dartmouth College, he received his Ph.D. in psychobiology at the California Institute of Technology under the tutelage of Roger Sperry. As a graduate student, Professor Gazzaniga initiated the first lateralized testing of human split-brain patients, leading to a fundamental shift in our understanding of functional lateralization in the brain and how the cerebral hemispheres communicate with one another. His many scholarly publications and pioneering work during the last 50 years have produced significant contributions to our understanding of how the brain enables the mind. His landmark 1995 book for MIT Press, The Cognitive Neurosciences, now in its fourth edition, is recognized as the sourcebook for the field. He has also published many books accessible to a lay audience, including Mind Matters, Nature's Mind, and The Ethical Brain.

  10. Stimulus-driven reorienting in the ventral frontoparietal attention network: the role of emotion

    Directory of Open Access Journals (Sweden)

    David Witt Frank

    2012-05-01

    Full Text Available Activity in the human temporoparietal junction and inferior frontal gyrus is hypothesized to underlie stimulus-driven, or bottom-up attention reorienting. Demanding tasks require focused attention, and as task difficulty increases, activity suppression in the ventral network correlates positively with task performance, an effect thought to reflect the gating of irrelevant cues. However, activation in these structures is elicited by a range of stimulus features and task demands that vary across multiple characteristics, complicating the interpretation of the functional role of this pathway. Consideration of several current studies suggests that, in addition to task difficulty, the motivational relevance or emotional intensity of distractor stimuli may supersede ongoing task priority, and evoke ventral network activation. Support for this possibility is offered from a review of recent reports, and the import of this perspective for models of attention reorienting are discussed.

  11. Junction Plasmon-Induced Molecular Reorientation

    Energy Technology Data Exchange (ETDEWEB)

    El-Khoury, Patrick Z.; Hu, Dehong; Hess, Wayne P.

    2013-10-17

    Time and frequency dependent intensity variations in sequences of Raman spectra recorded at plasmonic junctions can be assigned to molecular reorientation. This is revealed through Raman trajectories recorded at a nanojunction formed between a silver AFM tip and a corrugated silver surface coated with biphenyl-4,4’-dithiol. Molecular motion is not observed when the tip is retracted and only surface enhancement is operative. In effect, junction plasmon induced molecular reorientation is tracked.

  12. The reorientation of spatial planning in Denmark

    DEFF Research Database (Denmark)

    Galland, Daniel

    2011-01-01

    has been reoriented at national, regional and urban/local levels over time. The fundamental objective of the project is hence to explore and examine the history and evolution of Danish spatial planning through three embedded case studies from inception until most recent transformations. Respectively......, these studies embrace the reorientations of Danish national spatial planning; regional spatial planning in North Jutland; and urban planning and waterfront redevelopment in the city of Aalborg. In attaining its aim, the dissertation is guided by the general premise that the reorientations of spatial planning...... planning practices at different administrative levels. As a whole, the outcome of this dissertation confirms that there is an increasing policy and institutional mismatch between national, regional and urban/local planning practices. It further suggests that the lack of spatial reflexion embedded...

  13. Q&A: Michael Honey

    Science.gov (United States)

    Helicher, Karl

    2007-01-01

    The mid-1960s saw civil rights victories in Congress during Lyndon B. Johnson's presidency. In "Going Down Jericho Road," Michael Honey wrote how Martin Luther King Jr.'s final focus showed that the struggle for black and working class parity continued. The 1968 Memphis sanitation workers strike was a gritty struggle won in the streets by a host…

  14. Michael Beitz: Objects of Communication

    Science.gov (United States)

    Hoefferle, Mary

    2014-01-01

    For this Instructional Resource, the author interviewed contemporary sculptor Michael Beitz, who uses art to explore the role of designed objects in human communication and emotional experience. This column was written in response to calls for using Enduring Understandings/Big Ideas (National Coalition for Core Arts Standards, 2013; Stewart &…

  15. Reorientation of magnetic anisotropy in epitaxial cobalt ferrite thin films

    NARCIS (Netherlands)

    Lisfi, A.; Williams, C.M.; Nguyen, L.T.; Lodder, J.C.; Coleman, A.; Corcoran, H.; Johnson, A.; Chang, P.; Kumar, A.; Morgan, W.

    2007-01-01

    Spin reorientation has been observed in CoFe2O4 thin single crystalline films epitaxially grown on (100) MgO substrate upon varying the film thickness. The critical thickness for such a spin-reorientation transition was estimated to be 300 nm. The reorientation is driven by a structural transition

  16. Reorientation of magnetic anisotropy in epitaxial cobalt ferrite thin films

    NARCIS (Netherlands)

    Lisfi, A.; Williams, C.M.; Nguyen, L.T.; Lodder, J.C.; Coleman, A.; Corcoran, H.; Johnson, A.; Chang, P.; Abhishek Kumar, A.K.; Kumar, A.; Morgan, W.

    2007-01-01

    Spin reorientation has been observed in CoFe2O4 thin single crystalline films epitaxially grown on (100) MgO substrate upon varying the film thickness. The critical thickness for such a spin-reorientation transition was estimated to be 300 nm. The reorientation is driven by a structural transition

  17. Michael J. Fox: Spurring Research on Parkinson's

    Science.gov (United States)

    ... please turn JavaScript on. Feature: Parkinson's Disease Michael J. Fox: Spurring Research on Parkinson's Past Issues / Winter 2014 Table of Contents Michael J. Fox and his wife, actress Tracy Pollan, founded ...

  18. The reorientation of spatial planning systems and policies

    DEFF Research Database (Denmark)

    Galland, Daniel; Enemark, Stig

    2012-01-01

    Danish spatial planning has been increasingly subjected to profound reorientations over the past two decades. The comprehensive frame wherein planning policies and practices operated across different levels of administration has become significantly altered. This has been particularly evident after...... the implementation of a structural reform that changed the political and administrative structure in the country. Most importantly, the reform abolished the county level, which caused that planning policies, functions and responsibilities were re-scaled to municipal and national levels. This situation brought about...... radical shifts in terms of the scope of planning policies, the implementation of land-use tasks as well as the performance of the institutional arrangements operating within and beyond the planning system. Based on an in-depth analysis concerned with these changes, the paper endeavours into discussing how...

  19. Michael Faraday vs. the Spiritualists

    Science.gov (United States)

    Hirshfeld, Alan

    2006-12-01

    In the 1850s, renowned physicist Michael Faraday launched a public campaign against pseudoscience and spiritualism, which were rampant in England at the time. Faraday objected especially to claims that electrical or magnetic forces were responsible for paranormal phenomena, such as table-spinning and communication with the dead. Using scientific methods, Faraday unmasked the deceptions of spiritualists, clairvoyants and mediums and also laid bare the credulity of a public ill-educated in science. Despite his efforts, Victorian society's fascination with the paranormal swelled. Faraday's debacle anticipates current controversies about public science education and the interface between science and religion. This episode is one of many described in the new biography, The Electric Life of Michael Faraday (Walker & Co.), which chronicles Faraday's discoveries and his unlikely rise from poverty to the pinnacle of the English science establishment.

  20. Michael Niegl (1985-2009)

    CERN Multimedia

    2009-01-01

    Our friend and colleague Michael Niegl died in a tragic accident in the first hours of the new year. Michael was a Master’s student in Microsystems Engineering at the University of Applied Sciences Wiener Neustadt. He was responsible for the development of the ATLAS Beam Conditions Monitor (BCM) ROD FPGA firmware, which acquires the data from the BCM detector modules and provides online monitoring of the LHC beams within the ATLAS experiment. He spent several months at CERN to carry out beam tests on the BCM detectors and received his Bachelor of Science with first class honours for his thesis: Concept and Implementation of an FPGA-based Data Recorder and Processor for the ATLAS Beam Conditions Monitor. Michael spent six months at CERN last year to finish the development and commissioning of the ROD firmware for the first beam. He worked the entire night of 10 September to fine tune the system for the first beam. It was a joy to ...

  1. Michael De Sousa (1989 - 2012)

    CERN Multimedia

    2012-01-01

    We are deeply saddened to announce the death of Mr Michael De Sousa on 13 May 2012. Mr De Sousa, who was born on 02.09.1989, was working as an apprentice in the TE Department and had been at CERN since 24.08.2009. The Director-General has sent a message of condolence to his family on behalf of the CERN personnel. Social Affairs Human Resources Department     It is with great emotion and deep sadness that we learn of the tragic loss of our colleague and friend Michael De Sousa. Michael was a hard working colleague, cordial and considerate. Within a few months, he marked his presence by the implementation of the instrumentation benches for gas permeation measurement in polymers, and the calibration of high technology gas analyzers, necessary for vacuum technology. His last contribution will enable us to measure pressures in the extreme high vacuum range for the ELENA project.  With the continuation of this activity, his memory will remain. His accomplishments will remain...

  2. Organocatalytic aza-Michael/retro-aza-Michael reaction: pronounced chirality amplification in aza-Michael reaction and racemization via retro-aza-Michael reaction.

    Science.gov (United States)

    Cai, Yong-Feng; Li, Li; Luo, Meng-Xian; Yang, Ke-Fang; Lai, Guo-Qiao; Jiang, Jian-Xiong; Xu, Li-Wen

    2011-05-01

    A detailed experimental investigation of an aza-Michael reaction of aniline and chalcone is presented. A series of Cinchona alkaloid-derived organocatalysts with different functional groups were prepared and used in the aza-Michael and retro-aza-Michael reaction. There was an interesting finding that a complete reversal of stereoselectivity when a benzoyl group was introduced to the cinchonine and cinchonidine. The chirality amplification vs. time proceeds in the quinine-derived organocatalyst containing silicon-based bulky group, QN-TBS, -catalyzed aza-Michael reaction under solvent-free conditions. In addition, we have demonstrated for the first time that racemization was occurred in suitable solvents under mild conditions due to retro-aza-Michael reaction of the Michael adduct of aniline with chalcone. These indicate the equilibrium of retro-aza-Michael reaction and aza-Michael reaction produce the happening of chirality amplification in aza-Michael reaction and racemization via retro-aza-Michael reaction under different conditions, which would be beneficial to the development of novel chiral catalysts for the aza-Michael reactions.

  3. Fundamental experiments on hydride reorientation in zircaloy

    Science.gov (United States)

    Colas, Kimberly B.

    In the current study, an in-situ X-ray diffraction technique using synchrotron radiation was used to follow directly the kinetics of hydride dissolution and precipitation during thermomechanical cycles. This technique was combined with conventional microscopy (optical, SEM and TEM) to gain an overall understanding of the process of hydride reorientation. Thus this part of the study emphasized the time-dependent nature of the process, studying large volume of hydrides in the material. In addition, a micro-diffraction technique was also used to study the spatial distribution of hydrides near stress concentrations. This part of the study emphasized the spatial variation of hydride characteristics such as strain and morphology. Hydrided samples in the shape of tensile dog-bones were used in the time-dependent part of the study. Compact tension specimens were used during the spatial dependence part of the study. The hydride elastic strains from peak shift and size and strain broadening were studied as a function of time for precipitating hydrides. The hydrides precipitate in a very compressed state of stress, as measured by the shift in lattice spacing. As precipitation proceeds the average shift decreases, indicating average stress is reduced, likely due to plastic deformation and morphology changes. When nucleation ends the hydrides follow the zirconium matrix thermal contraction. When stress is applied below the threshold stress for reorientation, hydrides first nucleate in a very compressed state similar to that of unstressed hydrides. After reducing the average strain similarly to unstressed hydrides, the average hydride strain reaches a constant value during cool-down to room temperature. This could be due to a greater ease of deforming the matrix due to the applied far-field strain which would compensate for the strains due to thermal contraction. Finally when hydrides reorient, the average hydride strains become tensile during the first precipitation regime and

  4. The reorientation of spatial planning in Denmark

    DEFF Research Database (Denmark)

    Galland, Daniel

    2011-01-01

    have been increasingly overridden by growth-oriented and competitiveness logics. More recently, the effects of a structural reform that changed the geographies of inter-governmental arrangements within the country have significantly transformed the orientation, scope, structure and performance...... has been reoriented at national, regional and urban/local levels over time. The fundamental objective of the project is hence to explore and examine the history and evolution of Danish spatial planning through three embedded case studies from inception until most recent transformations. Respectively...

  5. Video interview with Michael Dell

    CERN Multimedia

    CERN Bulletin

    2010-01-01

    Michael Dell, founder and presently Chairman of the Board of Directors and Chief Executive Office of the DELL computer company visited CERN on Tuesday 26th January 2010. The Bulletin and the Video productions team had the opportunity to meet him. The video interview is transcribed for your convenience.   Michael S. Dell with CERN Director-General Rolf Heuer. What motivated you to come and visit CERN? I obviously heard about the great science and research has going on here, and DELL is very pleased to be a partner and providing a lot of the computers to analyse the data and I really wanted to see for myself in person, some of the great science that is going on here. What is your view on fundamental research in IT, and in general? I think if you look at the field of science in the last hundred years, we have been able to solve a lot of problems, but there are still lots of unsolved problems and unsolved mysteries. And it is only through basic fundamental research that we will address these probl...

  6. Reorientation of Defect Dipoles in Ferroelectric Ceramics

    Institute of Scientific and Technical Information of China (English)

    LI Bao-Shan; LI Guo-Rong; ZHAO Su-Chuan; ZHU Zhi-Gang; DING Ai-Li

    2005-01-01

    @@ We investigate the frequency, temperature, tetragonality and quenched temperature dependences of the hysteresis loops in Pb[(Zr0.52 Ti0.48)0.95 (Mn1/3Nb2/3)0.05]O3 (PMnN-PZT) ceramics. It has been demonstrated that the polarization-field hysteresis curves show "pinched" shapes when tested at room temperature, higher frequency or using the large-tetragonality specimen. While normal square-like loops are observed at 200 ℃ and 0.01 Hz or using the small-tetragonality one. Meanwhile, close relations between the P-E loops and the applied frequency,temperature or tetragonality reveal that there exists a typical relaxation time corresponding to the reorientation of the defect dipoles. It can be seen further from the quenched temperature dependences of the loops that the reorientation of the defect dipoles may influence the pinching. Compared to the intrinsic depinning procedure induced by changes of the distribution of defect dipoles, we provide new evidence for extrinsic depinning mechanism of the defect dipoles in the ferroelectric ceramics.

  7. Involvement of the head and trunk during gaze reorientation during standing and treadmill walking.

    Science.gov (United States)

    Cinelli, Michael; Patla, Aftab; Stuart, Bethany

    2007-07-01

    As individuals stand or walk in an environment their gaze may be reoriented from one location to another in response to auditory or visual stimuli. In order to reorient gaze, the eyes and/or the head and trunk must rotate. However, what determines the exact degree of rotation of each segment while standing or walking is not fully understood. In the current study we show that when participants were asked to reorient their gaze towards light cues positioned at eccentric locations of up to 90 degrees while standing or walking on a treadmill their eyes and head mainly facilitated the action. Rotations of the head-in-space were similar for both tasks, but the rotation of the shoulders- and hips-in-space were lower for the treadmill walking condition. It is argued that this difference in the level of head-on-trunk rotation during the two tasks is controlled by the vestibular feedback loop. The regulation of this feedback loop is performed by the cerebellum in response to the level of threat to postural stability.

  8. Resting-state functional connectivity of ventral parietal regions associated with attention reorienting and episodic recollection

    Directory of Open Access Journals (Sweden)

    Sander M Daselaar

    2013-02-01

    Full Text Available In functional neuroimaging studies, ventral parietal cortex (VPC is recruited by very different cognitive tasks. Explaining the contributions VPC to these tasks has become a topic of intense study and lively debate. Perception studies frequently find VPC activations during tasks involving attention-reorienting, and memory studies frequently find them during tasks involving episodic recollection. According to the Attention to Memory (AtoM model, both phenomena can be explained by the same VPC function: bottom-up attention. Yet, a recent functional MRI (fMRI meta-analysis suggested that attention-reorienting activations are more frequent in anterior VPC, whereas recollection activations are more frequent in posterior VPC. Also, there is evidence that anterior and posterior VPC regions have different functional connectivity patterns. To investigate these issues, we conducted a resting-state functional connectivity analysis using as seeds the center-of-mass of attention-reorienting and recollection activations in the meta-analysis, which were located in the supramarginal gyrus (SMG, around the temporo-parietal junction—TPJ and in the angular gyrus (AG, respectively. The SMG seed showed stronger connectivity with ventrolateral prefrontal cortex (VLPFC and occipito-temporal cortex, whereas the AG seed showed stronger connectivity with the hippocampus and default network regions. To investigate whether these connectivity differences were graded or sharp, VLPFC and hippocampal connectivity was measured in VPC regions traversing through the SMG and AG seeds. The results showed a graded pattern: VLPFC connectivity gradually decreases from SMG to AG, whereas hippocampal connectivity gradually increases from SMG to AG. Importantly, both gradients showed an abrupt break when extended beyond VPC borders. This finding suggests that functional differences between SMG and AG are more subtle than previously thought. These connectivity differences can be

  9. A new biomarker to examine the role of hippocampal function in the development of spatial reorientation in children: a review.

    Science.gov (United States)

    Vieites, Vanessa; Nazareth, Alina; Reeb-Sutherland, Bethany C; Pruden, Shannon M

    2015-01-01

    Spatial navigation is an adaptive skill that involves determining the route to a particular goal or location, and then traveling that path. A major component of spatial navigation is spatial reorientation, or the ability to reestablish a sense of direction after being disoriented. The hippocampus is known to be critical for navigating, and has more recently been implicated in reorienting in adults, but relatively little is known about the development of the hippocampus in relation to these large-scale spatial abilities in children. It has been established that, compared to school-aged children, preschool children tend to perform poorly on certain spatial reorientation tasks, suggesting that their hippocampi may not be mature enough to process the demands of such a task. Currently, common techniques used to examine underlying brain activity, such as electroencephalography (EEG) and functional magnetic resonance imaging (fMRI), are not suitable for examining hippocampal development in young children. In the present paper, we argue instead for the use of eyeblink conditioning (EBC), a relatively under-utilized, inexpensive, and safe method that is easy to implement in developing populations. In addition, EBC has a well defined neural circuitry, which includes the hippocampus, making it an ideal tool to indirectly measure hippocampal functioning in young children. In this review, we will evaluate the literature on EBC and its relation to hippocampal development, and discuss the possibility of using EBC as an objective measure of associative learning in relation to large-scale spatial skills. We support the use of EBC as a way to indirectly access hippocampal function in typical and atypical populations in order to characterize the neural substrates associated with the development of spatial reorientation abilities in early childhood. As such, EBC is a potential, simple biomarker for success in tasks that require the hippocampus, including spatial reorientation.

  10. A New Biomarker to Examine the Role of Hippocampal Function in the Development of Spatial Reorientation in Children: A Review

    Directory of Open Access Journals (Sweden)

    Vanessa eVieites

    2015-04-01

    Full Text Available Spatial navigation is an adaptive skill that involves determining the route to a particular goal or location, and then travelling that path. A major component of spatial navigation is spatial reorientation, or the ability to reestablish a sense of direction after being disoriented. The hippocampus is known to be critical for navigating, and has more recently been implicated in reorienting in adults, but relatively little is known about the development of the hippocampus in relation to these large-scale spatial abilities in children. It has been established that, compared to school-aged children, preschool children tend to perform poorly on certain spatial reorientation tasks, suggesting that their hippocampi may not be mature enough to process the demands of such a task. Currently, common techniques used to examine underlying brain activity, such as electroencephalography (EEG and functional magnetic resonance imaging (fMRI, are not suitable for examining hippocampal development in young children. In the present paper, we argue for the use of eyeblink conditioning (EBC, a relatively under-utilized, inexpensive, and safe method that is easy to implement in developing populations. In addition, EBC has a well defined neural circuitry, which includes the hippocampus, making it an ideal tool to indirectly measure hippocampal functioning in young children. In this review, we will evaluate the literature on EBC and its relation to hippocampal development, and discuss the possibility of using EBC as an objective measure of associative learning in relation to large-scale spatial skills. We support the use of EBC as a way to indirectly access hippocampal function in typical and atypical populations in order to characterize the neural substrates associated with the development of spatial reorientation abilities in early childhood. Thus, we advocate for EBC as a simple biomarker for success in various tasks that require the hippocampus, including spatial

  11. PIE techniques for hydride reorientation test at NDC

    Energy Technology Data Exchange (ETDEWEB)

    Tsuda, Tomohiro; Shinohara, Yasunari; Yamaguchi, Yoichiro [Nuclear Development Corporation, Ibaraki (Japan)

    2008-11-15

    Dry storage of spent fuels in the interim storage facility is being planned in Japan. However, the gradual deterioration of the mechanical property of fuel cladding due to internal pressure and temperature during the storage term is known. Therefore, the integrity of stored fuel rods should be confirmed before the start of dry storage. For the last several years, NDC had a lot of experiences on the hydride reorientation test. The specimen preparation techniques on the hydride reorientation test and the mechanical testing techniques after the hydride reorientation are shown in this paper.

  12. Spatial reorientation decline in aging: the combination of geometry and landmarks.

    Science.gov (United States)

    Caffò, Alessandro O; Lopez, Antonella; Spano, Giuseppina; Serino, Silvia; Cipresso, Pietro; Stasolla, Fabrizio; Savino, Michelina; Lancioni, Giulio E; Riva, Giuseppe; Bosco, Andrea

    2017-07-20

    The study is focused on the assessment of reorientation skills in a sample of community-dwelling elderly people, manipulating landmarks and geometric (layout) information. A neuropsychological assessment was administered to 286 elderly participants, divided into six groups (healthy controls, HC; four subgroups of participants with mild cognitive impairment, MCI; participants with probable dementia, Prob_D) and tested with the Virtual Reorientation Test (VReoT). VReoT manipulated different spatial cues: geometry and landmarks (proximal and distal). Compared with HC, participants with MCI and Prob_D showed to be impaired in tasks involving geometry, landmarks and a combination of them. Both single and multiple domain impairment in MCI had an impact on reorientation performance. Moreover, VReoT was marginally able to discriminate between amnesic and non-amnesic MCI. The occurrence of getting lost events seemed to be associated to learning of geometric information. The associative strength between landmark and target plays an important role in affecting spatial orientation performance of cognitively impaired participants. Geometry significantly supports landmark information and becomes helpful with the increase of cognitive impairment which is linked to a decrement in landmark encoding. VReoT seems to represent a reliable evaluation supplement for spatial orientation deficits in prodromal stages of dementia.

  13. Reorientation of the early lunar pole

    Science.gov (United States)

    Takahashi, Futoshi; Tsunakawa, Hideo; Shimizu, Hisayoshi; Shibuya, Hidetoshi; Matsushima, Masaki

    2014-06-01

    Palaeomagnetic measurements suggest that an active core dynamo operated on the Moon from 4.2 to 3.56 billion years ago. Since the Apollo era, many magnetic anomalies have been observed on the Moon. The magnetization of the lunar crust in some of these regions could preserve the signature of an early dipolar magnetic field generated by a core dynamo. Thus, the magnetic anomalies may yield information about the position of the palaeomagnetic pole during the time that the dynamo operated. Here we present a comprehensive survey of magnetic anomalies on the lunar surface using magnetometer data obtained by the Lunar Prospector and Kaguya lunar orbiters. We extract magnetization vectors from 24 magnetic anomalies using an iterative inversion method and derive the palaeomagnetic poles. We find that the north poles, as well as the antipodal south poles, cluster in two distinct locations: one near the present rotation axis and the other at mid-latitude. The clustering is consistent with a dipole-dominated magnetic field generated in the lunar core by a dynamo that was reversing, much like that of Earth. Furthermore, the two pole clusters imply that the Moon experienced a polar wander event during its ancient history due to the reorientation of the Moon with respect to its spin axis by 45°-60°.

  14. Linguistic Theories and Intellectual History in Michael Baxandall’s Giotto and the Orators

    Directory of Open Access Journals (Sweden)

    Allan Langdale

    2009-12-01

    Full Text Available This essay examines some theoretical and methodological aspects of Michael Baxandall’s book Giotto and the Orators. Humanist observers of painting in Italy and the discovery of pictorial composition of 1971. It includes reflections on the book’s reorientations of the scholarly debate over the relationship between Renaissance/Early Modern humanism and painting, as well as consideration of the linguistic theories that either directly or tangentially inform Baxandall’s method. Sources such as Wittgenstein, Cassirer, Ordinary Language Philosophy, and the Sapir-Whorf Hypothesis are discussed. Some of the book’s aims and methods are clarified by a comparison to Panofsky’s Gothic Architecture and Scholasticism of 1951.

  15. Michael Wood’s Yangzhou Dream

    Institute of Scientific and Technical Information of China (English)

    Yuan; Dan

    2014-01-01

    <正>Mr.Michael Wood is a wellknown British historian and documentary maker who has produced more than a hundred documentaries on various national histories and cultures exemplified by The Story of India.They enjoy wide popularity in more than 150 countries.I met him in February when he took his fi lm crew to Yangzhou to shoot The Story of China documentary for the British Broadcasting Corporation(BBC).It was a snowy day,cold and wet,but Michael said happily that the

  16. Spatial reorientation in rats (Rattus norvegicus): Use of geometric and featural information as a function of arena size and feature location

    NARCIS (Netherlands)

    Maes, J.H.R.; Fontanari, L.; Regolin, L.

    2009-01-01

    Rats were used in a spatial reorientation task to assess their ability to use geometric and non-geometric, featural, information. Experimental conditions differed in the size of the arena (small, medium, or large) and whether the food-baited corner was near or far from a visual feature. The main mea

  17. Planar reorientation maneuvers of space multibody systems using internal controls

    Science.gov (United States)

    Reyhanoglu, Mahmut; Mcclamroch, N. H.

    1992-01-01

    In this paper a reorientation maneuvering strategy for an interconnection of planar rigid bodies in space is developed. It is assumed that there are no exogeneous torques, and torques generated by joint motors are used as means of control so that the total angular momentum of the multibody system is a constant, assumed to be zero in this paper. The maneuver strategy uses the nonintegrability of the expression for the angular momentum. We demonstrate that large-angle maneuvers can be designed to achieve an arbitrary reorientation of the multibody system with respect to an inertial frame. The theoretical background for carrying out the required maneuvers is briefly summarized. Specifications and computer simulations of a specific reorientation maneuver, and the corresponding control strategies, are described.

  18. Michael Hauskeller: Sex and the Posthuman Condition

    NARCIS (Netherlands)

    Miller, Lantz Eugene

    2016-01-01

    This new book from Michael Hauskeller explores the currently marketed or projected sex/love products that exhibit some trait of so-called “posthumanistic” theory or design. These products are so designated because of their intention to fuse high technologies, including robotics and computing, with

  19. Michael Hauskeller: Sex and the Posthuman Condition

    NARCIS (Netherlands)

    Miller, Lantz Flemming

    2016-01-01

    This new book from Michael Hauskeller explores the currently marketed or projected sex/love products that exhibit some trait of so-called “posthumanistic” theory or design. These products are so designated because of their intention to fuse high technologies, including robotics and computing, with t

  20. Reframing Michael Scott: Exploring Inappropriate Workplace Communication

    Science.gov (United States)

    Schaefer, Zachary A.

    2010-01-01

    Individuals who work in professional settings interact with others who may exhibit a variety of cultural beliefs and decision-making approaches. Page (2007) argues that cognitive diversity (i.e., how people approach and attempt to solve problems) is a vital asset in effective organizations. Michael Scott, who portrays the inept main character on…

  1. Comments on Michael (1993): Establishing Operations

    Science.gov (United States)

    Moore, J.

    2013-01-01

    The present comments concern Michael's concept of motivative variables, and the implications of that concept for our understanding of the nature of reinforcement as well as the extinction of responses maintained through positive and negative reinforcement. We note that both extinction and altering motivative variables decrease responding, but…

  2. TIME CAPSULE: MICHAEL LUCHKOVICH AND THE FAMINE

    Directory of Open Access Journals (Sweden)

    Serge Cipko

    2013-05-01

    Full Text Available This paper examines the reaction of the Ukrainian community in Canada at the Ukrainian famine of 1932–1933 in particular highlights the activities member of parliament, a Ukrainian-born Michael Luchkovich which 5 February 1934 gave a speech in federal parliament, reporting on the famine in the USSR and the related this protest the Ukrainian diaspora.

  3. Reflections: Michael Watts interviewed by Murat Arsel

    NARCIS (Netherlands)

    M. Arsel (Murat)

    2009-01-01

    textabstractMichael Watts is ‘Class of 1963’ Chair in Undergraduate Studies and Chancellor’s Professor of Geography at the University of California, Berkeley. Born and raised in rural southwest England, Watts studied at University College London and completed his PhD in 1979 at the University of Mic

  4. Resting-state functional connectivity of ventral parietal regions associated with attention reorienting and episodic recollection

    Science.gov (United States)

    Daselaar, S. M.; Huijbers, W.; Eklund, K.; Moscovitch, M.; Cabeza, R.

    2013-01-01

    In functional neuroimaging studies, ventral parietal cortex (VPC) is recruited by very different cognitive tasks. Explaining the contributions of VPC to these tasks has become a topic of intense study and lively debate. Perception studies frequently find VPC activations during tasks involving attention-reorienting, and memory studies frequently find them during tasks involving episodic recollection. According to the Attention to Memory (AtoM) model, both phenomena can be explained by the same VPC function: bottom-up attention. Yet, a recent functional MRI (fMRI) meta-analysis suggested that attention-reorienting activations are more frequent in anterior VPC, whereas recollection activations are more frequent in posterior VPC. Also, there is evidence that anterior and posterior VPC regions have different functional connectivity patterns. To investigate these issues, we conducted a resting-state functional connectivity analysis using as seeds the center-of-mass of attention-reorienting and recollection activations in the meta-analysis, which were located in the supramarginal gyrus (SMG, around the temporo-parietal junction—TPJ) and in the angular gyrus (AG), respectively. The SMG seed showed stronger connectivity with ventrolateral prefrontal cortex (VLPFC) and occipito-temporal cortex, whereas the AG seed showed stronger connectivity with the hippocampus and default network regions. To investigate whether these connectivity differences were graded or sharp, VLPFC and hippocampal connectivity was measured in VPC regions traversing through the SMG and AG seeds. The results showed a graded pattern: VLPFC connectivity gradually decreases from SMG to AG, whereas hippocampal connectivity gradually increases from SMG to AG. Importantly, both gradients showed an abrupt break when extended beyond VPC borders. This finding suggests that functional differences between SMG and AG are more subtle than previously thought. These connectivity differences can be explained by

  5. The World Is Not Flat: Can People Reorient Using Slope?

    Science.gov (United States)

    Nardi, Daniele; Newcombe, Nora S.; Shipley, Thomas F.

    2011-01-01

    Studies of spatial representation generally focus on flat environments and visual input. However, the world is not flat, and slopes are part of most natural environments. In a series of 4 experiments, we examined whether humans can use a slope as a source of allocentric, directional information for reorientation. A target was hidden in a corner of…

  6. Why water reorientation slows without iceberg formation around hydrophobic solutes.

    Science.gov (United States)

    Laage, Damien; Stirnemann, Guillaume; Hynes, James T

    2009-02-26

    The dynamics of water molecules next to hydrophobic solutes is investigated, specifically addressing the recent controversy raised by the first time-resolved observations, which concluded that some water molecules are immobilized by hydrophobic groups, in strong contrast to previous NMR conclusions. Through molecular dynamics simulations and an analytic jump reorientation model, we identify the water reorientation mechanism next to a hydrophobic solute and provide evidence that no water molecules are immobilized by hydrophobic solutes. Their moderate rotational slowdown compared to bulk water (e.g., by a factor of less than 2 at low solute concentration) is mainly due to slower hydrogen-bond exchange. The slowdown is quantitatively described by a solute excluded volume effect at the transition state for the key hydrogen-bond exchange in the reorientation mechanism. We show that this picture is consistent with both ultrafast anisotropy and NMR experimental results and that the transition state excluded volume theory yields quantitative predictions of the rotational slowdown for diverse hydrophobic solutes of varying size over a wide concentration range. We also explain why hydrophobic groups slow water reorientation less than do some hydrophilic groups.

  7. Reorientation of magnetic anisotropy in obliquely sputtered metallic thin films

    NARCIS (Netherlands)

    Lisfi, A.; Lodder, J.C.; Wormeester, H.; Poelsema, B.

    2002-01-01

    Reorientation in the magnetic anisotropy as a function of film thickness has been observed in Co-Ni and Co thin films, obliquely sputtered on a polyethylene terephthalate substrate at a large incidence angle (70°). This effect is a consequence of the low magnetocrystalline anisotropy of the films (f

  8. Stategic reorientation of industrial R&D towards commercial objectives.

    NARCIS (Netherlands)

    Brook, Jacques W.; de Bruijn, E.J.; McDonough III, Edward F.; Kaynak, E.; Harcar, T.D.

    2007-01-01

    In an effort to leverage R&D knowledge asset and to create more value from industrial R&D in today’s increasing liberalized and globalising business environments, some corporations adopt a strategic reorientation of their industrial R&D organisation towards commercial objectives. This study suggests

  9. Michael Haneke film Euroopa parim / M. T.

    Index Scriptorium Estoniae

    M. T.

    2005-01-01

    IX PÖFFil linastuv Michael Haneke film "Varjatud" ("Cache") võitis laupäeval mitu Euroopa Filmiakadeemia auhinda, selhulgas parima filmi, parima lavastaja, parima meesnäitleja (Daniel Auteuil) ja FIPRESCI auhinna. Parim naisnäitleja - Julia Jentsch ("Sophie Scholli viimased päevad"), operaator - Franz Lustig ("Don't Come Knocking"), stsenaarium - Hany Abu-Assad, Bero Beyer ("Kohe paradiisi")

  10. STS-86 Pilot Michael Bloomfield suits up

    Science.gov (United States)

    1997-01-01

    STS-86 Pilot Michael J. Bloomfield relaxes for a moment while donning his launch and entry suit with the assistance of a suit technician in the Operations and Checkout Building. This will be Bloomfields first spaceflight. He and the six other crew members will depart shortly for Launch Pad 39A, where the Space Shuttle Atlantis awaits liftoff on a 10-day mission slated to be the seventh docking of the Space Shuttle with the Russian Space Station Mir.

  11. Comments on Michael (1993): Establishing Operations

    OpenAIRE

    Moore, J

    2013-01-01

    The present comments concern Michael's concept of motivative variables, and the implications of that concept for our understanding of the nature of reinforcement as well as the extinction of responses maintained through positive and negative reinforcement. We note that both extinction and altering motivative variables decrease responding, but they do so differently. The former does so by discontinuing the response-reinforcer relation. The latter does so by altering the motivation to respond. ...

  12. Michael Haneke film Euroopa parim / M. T.

    Index Scriptorium Estoniae

    M. T.

    2005-01-01

    IX PÖFFil linastuv Michael Haneke film "Varjatud" ("Cache") võitis laupäeval mitu Euroopa Filmiakadeemia auhinda, selhulgas parima filmi, parima lavastaja, parima meesnäitleja (Daniel Auteuil) ja FIPRESCI auhinna. Parim naisnäitleja - Julia Jentsch ("Sophie Scholli viimased päevad"), operaator - Franz Lustig ("Don't Come Knocking"), stsenaarium - Hany Abu-Assad, Bero Beyer ("Kohe paradiisi")

  13. Obituary: Michael James Ledlow, 1964-2004

    Science.gov (United States)

    Puxley, Philip John; Grashuis, Randon M.

    2004-12-01

    Michael James Ledlow died on 5 June 2004 from a large, unsuspected brain tumor. Since 2000 he had been on the scientific staff of the Gemini Observatory in La Serena, Chile, initially as a Science Fellow and then as a tenure-track astronomer. Michael was born in Bartlesville, Oklahoma on 1 October 1964 to Jerry and Sharon Ledlow. He obtained his Bachelor Degree in astrophysics at the University of Oklahoma in 1987 and attended the University of New Mexico for his graduate work, obtaining his PhD while studying Galaxy Clusters under Frazer Owen in 1994. From 1995-1997 Michael held a postdoctoral position with Jack Burns at New Mexico State University where he used various astronomical facilities including the VLA and Apache Point Observatory to study distant galaxies. From 1998-2000 Michael rejoined the Physics and Astronomy Department at the University of New Mexico where he was a visiting professor until he moved on to Gemini. At the Gemini Observatory, Mike shared in the excitement, hard work and many long days and nights associated with bringing on-line a major new astronomical facility and its instrumentation. Following its commissioning he assisted visiting observers, supported and took data for many more remote users via the queue system, and for each he showed the same care and attention to detail evident in his own research to ensure that all got the best possible data. His research concentrated on the radio and optical properties of galaxy clusters, especially rich Abell clusters such as A2125, on luminous radio galaxies, including the detection of a powerful double radio source in the "wrong sort of galaxy," the spiral system 0313-192, and on EROs (extremely red objects), dusty galaxies barely detectable at optical wavelengths. Michael thoroughly enjoyed living in Chile and enthusiastically immersed himself in the culture of his surroundings. He and his family were actively involved with the International English Spanish Association in La Serena. He had a

  14. ORNL Interim Progress Report on Hydride Reorientation CIRFT Tests

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jy-An John [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Yan, Yong [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Wang, Hong [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2016-10-28

    A systematic study of H. B. Robinson (HBR) high burnup spent nuclear fuel (SNF) vibration integrity was performed in Phase I project under simulated transportation environments, using the Cyclic Integrated Reversible-Bending Fatigue Tester (CIRFT) hot cell testing technology developed at Oak Ridge National Laboratory in 2013–14. The data analysis on the as-irradiated HBR SNF rods demonstrated that the load amplitude is the dominant factor that controls the fatigue life of bending rods. However, previous studies have shown that the hydrogen content and hydride morphology has an important effect on zirconium alloy mechanical properties. To address the effect of radial hydrides in SNF rods, in Phase II a test procedure was developed to simulate the effects of elevated temperatures, pressures, and stresses during transfer-drying operations. Pressurized and sealed fuel segments were heated to the target temperature for a preset hold time and slow-cooled at a controlled rate. The procedure was applied to both non-irradiated/prehydrided and high-burnup Zircaloy-4 fueled cladding segments using the Nuclear Regulatory Commission-recommended 400°C maximum temperature limit at various cooling rates. Before testing high-burnup cladding, four out-of-cell tests were conducted to optimize the hydride reorientation (R) test condition with pre-hydride Zircaloy-4 cladding, which has the same geometry as the high burnup fuel samples. Test HR-HBR#1 was conducted at the maximum hoop stress of 145 MPa, at a 400°C maximum temperature and a 5°C/h cooling rate. On the other hand, thermal cycling was performed for tests HR-HBR#2, HR-HBR#3, and HR-HBR#4 to generate more radial hydrides. It is clear that thermal cycling increases the ratio of the radial hydride to circumferential hydrides. The internal pressure also has a significant effect on the radial hydride morphology. This report describes a procedure and experimental results of the four out-of-cell hydride reorientation tests of

  15. Reorienting programme budgeting and marginal analysis (PBMA towards disinvestment

    Directory of Open Access Journals (Sweden)

    Mortimer Duncan

    2010-10-01

    Full Text Available Abstract Background Remarkable progress has been made over the past 40 years in developing rational, evidence-based mechanisms for the allocation of health resources. Much of this progress has centred on mechanisms for commissioning new medical devices and pharmaceuticals. The attention of fund-managers and policy-makers is only now turning towards development of mechanisms for decommissioning, disinvesting or redeploying resources from currently funded interventions. While Programme Budgeting and Marginal Analysis would seem well-suited to this purpose, past applications include both successes and failures in achieving disinvestment and resource release. Discussion Drawing on recent successes/failures in achieving disinvestment and resource release via PBMA, this paper identifies four barriers/enablers to disinvestment via PBMA: (i specification of the budget constraint, (ii scope of the programme budget, (iii composition and role of the advisory group, and (iv incentives for/against contributing to a 'shift list' of options for disinvestment and resource release. A number of modifications to the PBMA process are then proposed with the aim of reorienting PBMA towards disinvestment. Summary The reoriented model is differentiated by four features: (i hard budget constraint with budgetary pressure; (ii programme budgets with broad scope but specific investment proposals linked to disinvestment proposals with similar input requirements; (iii advisory/working groups that include equal representation of sectional interests plus additional members with responsibility for advocating in favour of disinvestment, (iv 'shift lists' populated and developed prior to 'wish lists' and investment proposals linked to disinvestment proposals within a relatively narrow budget area. While the argument and evidence presented here suggest that the reoriented model will facilitate disinvestment and resource release, this remains an empirical question. Likewise

  16. Rocket propellant reorientation and fluid management used in space commercialization

    Science.gov (United States)

    Hung, R. J.; Lee, C. C.; Shyu, K. L.

    1990-01-01

    In a spacecraft design, the requirements of settled propellant are different for tank pressurization, engine restart, venting, or propellant transfer. The requirement to settle or to position liquid fuel over the outlet end of the spacecraft propellant tank prior main engine restart possess a microgravity fluid behavior problem. In this paper, the dynamical behavior of liquid propellant, fluid reorientation, and propellant resettling have been carried out.

  17. A conversation with Michael Freeman, MD.

    Science.gov (United States)

    Freeman, M

    1994-12-01

    The Institute for Behavioral Healthcare, a nonprofit organization that serves as an informational resource on issues surrounding the delivery of Behavioral Health Care Services, has been directed by Dr. Michael Freeman since its inception in 1988. In this crucial, unstable period in health care, membership in the Institute and attendance at its sponsored meetings has increased dramatically. Recently, Medical Interface talked with Dr. Freeman about topics of interest to the behavioral health care industry, ranging from any willing provider laws to the benefit itself.

  18. Anne Michaels e le ferite del linguaggio

    Directory of Open Access Journals (Sweden)

    Oriana Palusci

    2014-04-01

    Fugitive Pieces is analysed taking into consideration its polyphonic structure, the manifold motives and threads that weave together an intricate pattern, based on historical events and personal stories. Thanks to her use of scientific language from the realm of geology, paleobotany and geography, Michaels excavates time and space, past and present, in order to find a language to unveil the atrocities of Nazism against Jews, to preserve and evoke the memories of the survivors, but at the same time lead to a possible reconciliation with the past.

  19. Richard Michael Suzman (1942-2015).

    Science.gov (United States)

    Kahneman, Daniel

    2016-01-01

    Presents an obituary for Richard Michael Suzman, who died on April 16, 2015. Suzman was trained as a sociologist and anthropologist, but he was attracted to the approaches of demography and economics. He came to know a great deal about diverse fields of science, including health, physiology, psychology, genetics, and economics. He was a scientific leader who was on a quest to develop new transdisciplinary fields and to mobilize the best scientists to work in them. Suzman's passion for transdisciplinary science was fully expressed in his greatest achievement: the famous Health and Retirement Survey (HRS), which he initiated in 1988 and continued to guide and inspire. (PsycINFO Database Record

  20. A model of cytoskeletal reorientation in response to substrate stretching

    Directory of Open Access Journals (Sweden)

    Lazopoulos K.A.

    2008-01-01

    Full Text Available Living adherent cells change their orientation in response to substrate stretching such that their cytoskeletal components reorganize in a new direction. To study this phenomenon, we model the cytoskeleton as a planar system of elastic cables and struts both pinned at their endpoints to a flat flexible substrate. Tensed (pre-strained cables represent acting stress fibers, whereas compression-bearing struts represent microtubules. We assume that in response to uniaxial substrate stretching the model reorients and deforms into a new configuration that minimizes its total potential energy. Using the Maxwell's global stability criterion, we find global minima configurations during static extension and compression of the substrate. Based on these results, we predict reorientation during cyclic stretching of the substrate. We find that in response to cyclic stretching cells either reorient transversely to the direction of stretching, or exhibit multiple configurations symmetrically distributed relative to the direction of stretching. These predictions are consistent with experimental data on living cells from the literature.

  1. Michael Roitmann : Kalandus ei ole Eestile ilmselt prioriteetne valdkond / Michael Roitmann ; interv. Marko Saaret

    Index Scriptorium Estoniae

    Roitmann, Michael

    2003-01-01

    Ilmunud ka: Delovõje Vedomosti 3. dets. lk. 9. Euroopa Komisjoni kalandusdirektoraadi koordinaator Euroopa Liidu laienemise küsimuses Michael Roitmann juhib tähelepanu Eesti kalanduse suurematele probleemidele ning prognoosib EL-iga liitumise mõju Eesti kalandussektori arengule

  2. Michael Roitmann : Kalandus ei ole Eestile ilmselt prioriteetne valdkond / Michael Roitmann ; interv. Marko Saaret

    Index Scriptorium Estoniae

    Roitmann, Michael

    2003-01-01

    Ilmunud ka: Delovõje Vedomosti 3. dets. lk. 9. Euroopa Komisjoni kalandusdirektoraadi koordinaator Euroopa Liidu laienemise küsimuses Michael Roitmann juhib tähelepanu Eesti kalanduse suurematele probleemidele ning prognoosib EL-iga liitumise mõju Eesti kalandussektori arengule

  3. Involuntary Capture and Voluntary Reorienting of Attention Decline in Middle-Aged and Old Participants

    Science.gov (United States)

    Correa-Jaraba, Kenia S.; Cid-Fernández, Susana; Lindín, Mónica; Díaz, Fernando

    2016-01-01

    The main aim of this study was to examine the effects of aging on event-related brain potentials (ERPs) associated with the automatic detection of unattended infrequent deviant and novel auditory stimuli (Mismatch Negativity, MMN) and with the orienting to these stimuli (P3a component), as well as the effects on ERPs associated with reorienting to relevant visual stimuli (Reorienting Negativity, RON). Participants were divided into three age groups: (1) Young: 21–29 years old; (2) Middle-aged: 51–64 years old; and (3) Old: 65–84 years old. They performed an auditory-visual distraction-attention task in which they were asked to attend to visual stimuli (Go, NoGo) and to ignore auditory stimuli (S: standard, D: deviant, N: novel). Reaction times (RTs) to Go visual stimuli were longer in old and middle-aged than in young participants. In addition, in all three age groups, longer RTs were found when Go visual stimuli were preceded by novel relative to deviant and standard auditory stimuli, indicating a distraction effect provoked by novel stimuli. ERP components were identified in the Novel minus Standard (N-S) and Deviant minus Standard (D-S) difference waveforms. In the N-S condition, MMN latency was significantly longer in middle-aged and old participants than in young participants, indicating a slowing of automatic detection of changes. The following results were observed in both difference waveforms: (1) the P3a component comprised two consecutive phases in all three age groups—an early-P3a (e-P3a) that may reflect the orienting response toward the irrelevant stimulation and a late-P3a (l-P3a) that may be a correlate of subsequent evaluation of the infrequent unexpected novel or deviant stimuli; (2) the e-P3a, l-P3a, and RON latencies were significantly longer in the Middle-aged and Old groups than in the Young group, indicating delay in the orienting response to and the subsequent evaluation of unattended auditory stimuli, and in the reorienting of

  4. Michael Maier--nine newly discovered letters.

    Science.gov (United States)

    Lenke, Nils; Roudet, Nicolas; Tilton, Hereward

    2014-02-01

    The authors provide a transcription, translation, and evaluation of nine newly discovered letters from the alchemist Michael Maier (1568-1622) to Gebhardt Johann von Alvensleben (1576-1631), a noble landholder in the vicinity of Magdeburg. Stemming from the final year of his life, this correspondence casts new light on Maier's biography, detailing his efforts to secure patronage amid the financial crisis of the early Thirty Years' War. While his ill-fated quest to perfect potable gold continued to form the central focus of his patronage suits, Maier also offered his services in several arts that he had condemned in his printed works, namely astrology and "supernatural" magic. Remarks concerning his previously unknown acquaintance with Heinrich Khunrath call for a re-evaluation of Maier's negotiation of the discursive boundaries between Lutheran orthodoxy and Paracelsianism. The letters also reveal Maier's substantial contribution to a work previously ascribed solely to the English alchemist Francis Anthony.

  5. STS-97 Crew Interviews: Michael J. Bloomfield

    Science.gov (United States)

    2000-01-01

    Live footage of a preflight interview with Pilot Michael J. Bloomfield is shown. The interview addresses many different questions including why Bloomfield became interested in the space program, the events and people that influence him and ultimately led to his interest, and his vigorous training in the astronaut program. Other interesting information that this one-on-one interview discusses are the main goals of the STS-97 mission, its scheduled docking with the new International Space Station (ISS), and its delivery of the first set of U.S.-provided solar arrays, batteries, and radiators. Bloomfield briefly discusses his responsibilities during the much-anticipated docking as well as during the scheduled space-walks.

  6. Spatial re-orienting of visual attention along the horizontal or the vertical axis.

    Science.gov (United States)

    Macaluso, E; Patria, F

    2007-06-01

    Neuroimaging data indicate functional segregation between voluntary and stimulus-driven control of spatial attention in dorsal and ventral fronto-parietal regions, respectively. While recent evidences demonstrated location-specific attentional effects in dorsal regions, little is known about any location or direction selectivity within the ventral network. Here, we used a spatial cueing paradigm to investigate stimulus-driven spatial re-orienting along different axes (horizontal or vertical). We found that re-orienting of attention activated the ventral attentional network, irrespective of axis-orientation. Statistical comparisons between homologous regions in the two hemispheres revealed significant main effects of attention re-orienting (common activation for the two hemispheres), irrespective of leftward or rightward re-orienting along the horizontal axis, or re-orienting along the vertical axis. We conclude that in healthy volunteers, a bilateral ventral network controls spatial covert re-orienting, and that this system is multidirectional.

  7. Young children reorient by computing layout geometry, not by matching images of the environment.

    Science.gov (United States)

    Lee, Sang Ah; Spelke, Elizabeth S

    2011-02-01

    Disoriented animals from ants to humans reorient in accord with the shape of the surrounding surface layout: a behavioral pattern long taken as evidence for sensitivity to layout geometry. Recent computational models suggest, however, that the reorientation process may not depend on geometrical analyses but instead on the matching of brightness contours in 2D images of the environment. Here we test this suggestion by investigating young children's reorientation in enclosed environments. Children reoriented by extremely subtle geometric properties of the 3D layout: bumps and ridges that protruded only slightly off the floor, producing edges with low contrast. Moreover, children failed to reorient by prominent brightness contours in continuous layouts with no distinctive 3D structure. The findings provide evidence that geometric layout representations support children's reorientation.

  8. Book Review: Invitation to Topological Robotics by Michael Farber

    DEFF Research Database (Denmark)

    Raussen, Martin

    2009-01-01

    Book Review: Invitaton to Topological Robotics by Michael Farber. Zurich Lectures in Advanced Mathematics, European Mathematical Society (2008), ISBN 978-3-03719-054-8......Book Review: Invitaton to Topological Robotics by Michael Farber. Zurich Lectures in Advanced Mathematics, European Mathematical Society (2008), ISBN 978-3-03719-054-8...

  9. Interview with Michael Apple: The Biography of a Public Intellectual

    Science.gov (United States)

    Peters, Michael A.

    2015-01-01

    Michael W. Apple is the John Bascom Professor of Curriculum and Instruction and Educational Policy Studies in the Departments of Curriculum and Instruction (CI) and Educational Policy Studies (EPS) at the University of Wisconsin-Madison School of Education where he has taught since 1970. Michael Apple is one of the foremost educational theorists…

  10. Michael J. Meaney: Award for Distinguished Scientific Contributions

    Science.gov (United States)

    American Psychologist, 2012

    2012-01-01

    Presents Michael J. Meaney as one of the winners of the American Psychological Association's Award for Distinguished Scientific Contributions (2012). Michael J. Meaney has taken the phenomenon of "handling" of newborn rats and opened a new area of investigation that has given new meaning to epigenetics via his work demonstrating transgenerational…

  11. Michael Young and the Curriculum Field in South Africa

    Science.gov (United States)

    Hoadley, Ursula

    2015-01-01

    The paper addresses the question of what we should make of Michael Young's recent work with respect to curriculum theory by considering the particular case of South African curriculum reform. The paper thus traces two trajectories: the evolution of Michael Young's ideas over time and South African curriculum reform in the post-apartheid period.…

  12. Reorientation of Sputnik Planitia implies a subsurface ocean on Pluto.

    Science.gov (United States)

    Nimmo, F; Hamilton, D P; McKinnon, W B; Schenk, P M; Binzel, R P; Bierson, C J; Beyer, R A; Moore, J M; Stern, S A; Weaver, H A; Olkin, C B; Young, L A; Smith, K E

    2016-12-01

    The deep nitrogen-covered basin on Pluto, informally named Sputnik Planitia, is located very close to the longitude of Pluto's tidal axis and may be an impact feature, by analogy with other large basins in the Solar System. Reorientation of Sputnik Planitia arising from tidal and rotational torques can explain the basin's present-day location, but requires the feature to be a positive gravity anomaly, despite its negative topography. Here we argue that if Sputnik Planitia did indeed form as a result of an impact and if Pluto possesses a subsurface ocean, the required positive gravity anomaly would naturally result because of shell thinning and ocean uplift, followed by later modest nitrogen deposition. Without a subsurface ocean, a positive gravity anomaly requires an implausibly thick nitrogen layer (exceeding 40 kilometres). To prolong the lifetime of such a subsurface ocean to the present day and to maintain ocean uplift, a rigid, conductive water-ice shell is required. Because nitrogen deposition is latitude-dependent, nitrogen loading and reorientation may have exhibited complex feedbacks.

  13. A new twist on old ideas: how sitting reorients crawlers.

    Science.gov (United States)

    Soska, Kasey C; Robinson, Scott R; Adolph, Karen E

    2015-03-01

    Traditionally, crawling and sitting are considered distinct motor behaviors with different postures and functions. Ten- to 12-month-old infants were observed in the laboratory or in their homes while being coaxed to crawl continuously over long, straight walkways (Study 1; N = 20) and during spontaneous crawling during free play (Study 2; N = 20). In every context, infants stopped crawling to sit 3-6 times per minute. Transitions from crawling to sitting frequently turned infants' bodies away from the direction of heading; subsequent transitions back to crawling were offset by as much as 180° from the original direction of heading. Apparently, body reorientations result from the biomechanics of transitioning between crawling and sitting. Findings indicate that sustained, linear crawling is likely an epiphenomenon of how gait is studied in standard paradigms. Postural transitions between crawling and sitting are ubiquitous and can represent a functional unit of action. These transitions and the accompanying body reorientations likely have cascading effects for infants' exploration, visual perception, and spatial cognition.

  14. Reorientation of Sputnik Planitia implies a subsurface ocean on Pluto

    Science.gov (United States)

    Nimmo, F.; Hamilton, D. P.; McKinnon, W. B.; Schenk, P. M.; Binzel, R. P.; Bierson, C. J.; Beyer, R. A.; Moore, J. M.; Stern, S. A.; Weaver, H. A.; Olkin, C. B.; Young, L. A.; Smith, K. E.; Moore, J. M.; McKinnon, W. B.; Spencer, J. R.; Beyer, R.; Binzel, R. P.; Buie, M.; Buratti, B.; Cheng, A.; Cruikshank, D.; Ore, C. Dalle; Earle, A.; Gladstone, R.; Grundy, W.; Howard, A. D.; Lauer, T.; Linscott, I.; Nimmo, F.; Parker, J.; Porter, S.; Reitsema, H.; Reuter, D.; Roberts, J. H.; Robbins, S.; Schenk, P. M.; Showalter, M.; Singer, K.; Strobel, D.; Summers, M.; Tyler, L.; White, O. L.; Umurhan, O. M.; Banks, M.; Barnouin, O.; Bray, V.; Carcich, B.; Chaikin, A.; Chavez, C.; Conrad, C.; Hamilton, D. P.; Howett, C.; Hofgartner, J.; Kammer, J.; Lisse, C.; Marcotte, A.; Parker, A.; Retherford, K.; Saina, M.; Runyon, K.; Schindhelm, E.; Stansberry, J.; Steffl, A.; Stryk, T.; Throop, H.; Tsang, C.; Verbiscer, A.; Winters, H.; Zangari, A.; Stern, S. A.; Weaver, H. A.; Olkin, C. B.; Young, L. A.; Smith, K. E.

    2016-12-01

    The deep nitrogen-covered basin on Pluto, informally named Sputnik Planitia, is located very close to the longitude of Pluto’s tidal axis and may be an impact feature, by analogy with other large basins in the Solar System. Reorientation of Sputnik Planitia arising from tidal and rotational torques can explain the basin’s present-day location, but requires the feature to be a positive gravity anomaly, despite its negative topography. Here we argue that if Sputnik Planitia did indeed form as a result of an impact and if Pluto possesses a subsurface ocean, the required positive gravity anomaly would naturally result because of shell thinning and ocean uplift, followed by later modest nitrogen deposition. Without a subsurface ocean, a positive gravity anomaly requires an implausibly thick nitrogen layer (exceeding 40 kilometres). To prolong the lifetime of such a subsurface ocean to the present day and to maintain ocean uplift, a rigid, conductive water-ice shell is required. Because nitrogen deposition is latitude-dependent, nitrogen loading and reorientation may have exhibited complex feedbacks.

  15. Surface instabilities and reorientation induced by vibration in microgravity conditions

    Science.gov (United States)

    Porter, Jeff; Laverón-Simavilla, Ana; Tinao Perez-Miravete, Ignacio; Fernandez Fraile, Jose Javier; Ezquerro Navarro, Jose Miguel

    2012-07-01

    The behavior of vibrated fluids and, in particular, the surface or interfacial instabilities that commonly arise in these systems have been the subject of continued experimental and theoretical attention since Faraday's seminal experiments in 1831. Both orientation and frequency are critical in determining the response of the fluid to excitation. Low frequencies are associated with sloshing while higher frequencies may generate Faraday waves or cross-waves, depending on whether the axis of vibration is perpendicular or parallel to the interface. In addition, high frequency vibrations are known to produce large scale reorientation of the fluid (vibroequilibria), an effect that becomes especially pronounced in the absence of gravity. We describe the results of investigations conducted at the ESA affiliated Spanish User Support and Operations Centre (E-USOC) on the effect of vibrations on fluid interfaces, particularly the interaction between Faraday waves, which arise in vertically vibrated systems, cross-waves, which are found in horizontally forced systems, and large scale reorientation (vibroequilibria). Ongoing ground experiments utilizing a dual-axis shaker configuration are described, including the effect on pattern formation of varying the two independent forcing frequencies, amplitudes, and phases. Theoretical results, based on the analysis of reduced models, and on numerical simulations, are then described and compared to experiment. Finally, the interest of a corresponding microgravity experiment is discussed and implications for fluid management strategies considered.

  16. An Interview with Sir Michael Marmot

    Directory of Open Access Journals (Sweden)

    Editors

    2009-06-01

    Full Text Available In August of 2008 the WHO Commission on the Social Determinants of Health concluded its work with the publication of a report entitled: “Closing the gap in a generation: Health equity through action on the social determinants of health.” The Commission’s chair, Sir Michael Marmot, was kind enough to answer our questions about the Commission’s recommendations. This interview was conducted by email in May of this year. Social Medicine: We congratulate the Com-mission on its excellent work in bringing attention to the social determinants of health and the Commission’s call for health equity. We appreciated the Commission’s recognition that: “Social Justice is a matter of life and death.” We were also happy that the Commission included representatives of civil society in their work. This was an important affirmation of democratic values. When thinking about health inequalities people often use the analogue of the ladder to show how the gradient of worsening health outcomes affects all people in society except (presumably those at the very top. Thinking about the ladder leads us to pose the following question: Is making the ladder shorter (i.e. reducing inequalities the only approach to inequalities or is it possible to imagine making the ladder disappear entirely? Sir Michael Marmot: All societies have hier-archies. It is not conceivable, therefore, to have a society with no ladder. The conceptual framework of the Commission on Social Determinants of Health leads us to think of at least two (linked ways to address the relation between position on the ladder and health: act at the societal level to reduce social inequalities, and break the link between position in the social hierarchy and health. The first argues for reducing the slope of the social gradient. To see this, suppose, just for a moment, that the ladder were defined on the basis of years of education. People who had three years or fewer had life expectancy of 50 years

  17. Race, punishment, and the Michael Vick experience.

    Science.gov (United States)

    Piquero, Alex R; Piquero, Nicole Leeper; Gertz, Marc; Baker, Thomas; Batton, Jason; Barnes, J C

    2011-01-01

    Objective. The relationship between race and crime has been contentious, focusing primarily on offending and incarceration patterns among minorities. There has been some limited work on public perceptions of criminal punishment, and findings show that while minorities believe in the role and rule of law, they simultaneously perceive the justice system as acting in a biased and/or unfair manner. Two limitations have stalled this literature. First, research has focused mainly on criminal punishments to the neglect of noncriminal punishments. Second, most studies have not examined whether race remains salient after considering other demographic variables or discrimination and legitimacy attitudes.Methods. Using data from 400 adults, we examine how race affects perceptions of criminal punishment and subsequent reinstatement into the National Football League in the case of Michael Vick, a star professional quarterback who pled guilty to charges of operating an illegal dog-fighting ring.Results. Findings show that whites are more likely to view Vick's punishment as too soft and that he should not be reinstated, while nonwhites had the opposite views. Race remained significant after controlling for other variables believed to be related to punishment perceptions.Conclusion. Attitudes toward both criminal punishment and NFL reinstatement vary across race such that there exists important divides in how individuals perceive the system meting out punishment and subsequently reintegrating offenders back into society. These results underscore that white and nonwhites perceive the law and its administration differently.

  18. Obituary: Michael John Klein, 1940-2005

    Science.gov (United States)

    Gulkis, Samuel

    2006-12-01

    Michael John Klein died on 14 May 2005 at home in South Pasadena, California. The cause of death was tongue cancer that metastasized to the lungs. He was a non-smoker. Mike was a passionate radio astronomer, a trusted astronomical observer, an educator and a family man. Mike was born on 19 January 1940 in Ames, Iowa, the son of Florence Marie (Graf) and Fred Michael Klein. His mother was a homemaker, and his father was a banker. Mike had two older sisters, Lois Jean (Klein) Flauher and Marilyn June (Klein) Griffin. In 1962, Mike married his high school sweetheart Barbara Dahlberg, who survives him along with their three children, Kristin Marie (Klein) Shields, Michael John Klein Jr., Timothy Joel Klein, and six grandchildren. Mike developed a love for astronomy early in his life, and credited an early morning, newspaper-delivery route that he had at age twelve, which took him outside well before sunrise. He told family members that as he walked along his route, he stared into the sky and wondered what everything was. He studied sky charts, located stars, and began to understand how the planets shifted their positions relative to the stars each day. Another big influence in Mike's life was his brother in-law, Jim Griffin. Jim helped Mike understand that his passion for science did not have to remain a hobby, but could and should become a career. Jim's encouragement led Mike to attend Iowa State University in Ames, where he earned a BS in electrical engineering in 1962. Mike then started graduate school in electrical engineering at Michigan State, but after one semester transferred to the University of Michigan, Ann Arbor, where he earned an MS (1966) and PhD (1968) in astronomy. His doctoral dissertation, under the direction of Professor Fred Haddock, was based on extensive observations of the planets and examined the physical and thermal properties of planetary atmospheres and surfaces. Mike was awarded a Resident Research Associate position at JPL by the National

  19. On the reorientation of non-spherical prey particles in a feeding current

    DEFF Research Database (Denmark)

    Visser, Andre; Jonsson, P.R.

    2000-01-01

    Potentially, non-spherical prey can be re-oriented in a flow field and impact on the predator's feeding structures in a non- random manner. Herein, we quantify a process whereby this passive reorientation occurs, and present a model that predicts the orientation of a spheroidal prey as a function...

  20. Thin film magnetoelectric composites near spin reorientation transition

    Energy Technology Data Exchange (ETDEWEB)

    Tiercelin, N. [Joint European Laboratory LEMAC: IEMN CNRS 8520-Ecole Centrale de Lille, Villeneuve d' Ascq 59652 (France)], E-mail: Nicolas.Tiercelin@iemn.univ-lille1.fr; Preobrazhensky, V. [Joint European Laboratory LEMAC: IEMN CNRS 8520-Ecole Centrale de Lille, Villeneuve d' Ascq 59652 (France); Joint European Laboratory LEMAC: WRC-GPI-RAS 117454, Vernadsky prosp. 78, Moscow (Russian Federation); Mortet, V. [Institute for Materials Research (IMO), Hasselt University, IMEC vzw, Division IMOMEC, B-3590 Diepenbeek (Belgium); Talbi, A. [Joint European Laboratory LEMAC: IEMN CNRS 8520-Ecole Centrale de Lille, Villeneuve d' Ascq 59652 (France); Soltani, A. [IEMN CNRS 8520, Bd Poincare, Villeneuve d' Ascq 59651 (France); Haenen, K. [Institute for Materials Research (IMO), Hasselt University, IMEC vzw, Division IMOMEC, B-3590 Diepenbeek (Belgium); Pernod, P. [Joint European Laboratory LEMAC: IEMN CNRS 8520-Ecole Centrale de Lille, Villeneuve d' Ascq 59652 (France)

    2009-06-15

    We report the use of a magnetic instability of the spin reorientation transition type to enhance the magnetoelectric sensitivity in magnetostrictive-piezoelectric structures. We present the theoretical study of a clamped beam resonant actuator composed of a piezoelectric element on a passive substrate actuated by a magnetostrictive nanostructured layer. The experiments were made on a polished 150 {mu}m thick 18x3 mm{sup 2} lead zirconate titanate (PZT) plate glued to a 50 {mu}m thick silicon plate and coated with a giant magnetostrictive nanostructured Nx(TbCo{sub 25nm}/FeCo{sub 5nm}) layer. A second set of experiments was done with magnetostrictive layer deposited on PZT plate. Finally, a film/film structure using magnetostrictive and aluminium nitride films on silicon substrate was realized, and showed ME amplitudes reaching 30 V Oe{sup -1} cm{sup -1}. Results agree with analytical theory.

  1. Understanding the reorientations and roles of spatial planning

    DEFF Research Database (Denmark)

    Galland, Daniel

    2012-01-01

    Spatial planning commonly adopts a diversity of functions and logics in contributing to handle growth and development. Being influenced by an array of contextual driving forces that result in specific institutional practices and policy agendas, spatial planning seems to be constantly reoriented...... by analytical concepts drawn from planning theory, state spatial theory and discourse analysis. Based on an in-depth study, the article then attempts to qualify, illustrate and synthesise the diverse roles that spatial planning has taken in Denmark throughout that time frame. The article concludes that spatial...... in terms of its purposes and reasoning. This article sets out to explore the diverse orientations and roles that spatial planning has assumed in Denmark over a 50-year period. In doing so, the article examines the evolution of national planning policy by means of a multi-disciplinary framework comprised...

  2. Tidal reorientation and the fracturing of Jupiter's moon Europa

    Science.gov (United States)

    Mcewen, A. S.

    1986-01-01

    The lineaments on Europa are discussed in terms of the orientation of the lineaments relative to the tensile stress trajectories due to tidal distortions and to nonsynchronous rotation. The cracks are noticeable by their darker albedo compared to the presumed water ice surrounding them. The stress trajectories for tidal distortion of a thin elastic shell are superimposed on Mercator projection maps of the lineaments. It is shown that the lineaments are mainly oriented at high angles to the tensile stress trajectories that would be expected for regularly occurring nonsynchronous rotation, i.e., extensional fractures would appear. The reorientation motions which would cause the fractures are estimated. It is suggested that the fractures occur episodically to release stresses built up on the tensile surface of the crust during the continuous nonsynchronous rotation of Europa.

  3. Reorienting MHD colliding flows: a shock physics mechanism for generating filaments normal to magnetic fields

    Science.gov (United States)

    Fogerty, Erica; Carroll-Nellenback, Jonathan; Frank, Adam; Heitsch, Fabian; Pon, Andy

    2017-09-01

    We present numerical simulations of reorienting oblique shocks that form in the collision layer between magnetized colliding flows. Reorientation aligns post-shock filaments normal to the background magnetic field. We find that reorientation begins with pressure gradients between the collision region and the ambient medium. This drives a lateral expansion of post-shock gas, which reorients the growing filament from the outside-in (i.e. from the flow/ambient boundary, towards the colliding flows axis). The final structures of our simulations resemble polarization observations of filaments in Taurus and Serpens South, as well as the integral-shaped filament in Orion A. Given the ubiquity of colliding flows in the interstellar medium, shock reorientation may be relevant to the formation of filaments normal to magnetic fields.

  4. Reorienting MHD Colliding Flows: A Shock Physics Mechanism for Generating Filaments Normal to Magnetic Fields

    CERN Document Server

    Fogerty, Erica L; Frank, Adam; Heitsch, Fabian; Pon, Andy

    2016-01-01

    We present numerical simulations of reorienting oblique shocks that form in the collision layer between magnetized colliding flows. Reorientation aligns parsec-scale post-shock filaments normal to the background magnetic field. We find that reorientation begins with pressure gradients between the collision region and the ambient medium. This drives a lateral expansion of post-shock gas, which reorients the growing filament from the outside-in (i.e. from the flow-ambient boundary, toward the colliding flows axis). The final structures of our simulations resemble polarization observations of filaments in Taurus and Serpens South, as well as the integral-shaped filament in Orion A. Given the ubiquity of colliding flows in the interstellar medium, shock reorientation may be relevant to the formation of filaments normal to magnetic fields.

  5. Meet EPA Scientist Michael Nye, Ph.D.

    Science.gov (United States)

    Michael Nye, Ph.D., is a social scientist who studies natural risk, socio-demographic change and sustainable behavior. Prior to joining EPA, he worked for the UK Environment Agency in flood risk management and emergency preparedness

  6. Nitrosonium (NO+) catalyzed Michael addition of indoles to unsaturated enones

    Institute of Scientific and Technical Information of China (English)

    Guai Li Wu; Long Min Wu

    2008-01-01

    An efficient Michael addition of indoles to unsaturated enones, such as chalcones and β-nitrostyrenes, was achieved in thepresence of a catalytic amount of nitrosoninm tetrafluoroborate in ethyl ether.

  7. Immigration and Social Systems : Collected Essays of Michael Bommes

    NARCIS (Netherlands)

    2012-01-01

    Michael Bommes (hoogleraar Sociologie en Migratieonderzoek) was een van de meest briljante en originele geleerden in zijn vakgebied. Deze postume bundel bevat een selectie van zijn belangrijkste werk over immigratie en de verzorgingsstaat, de integratie van immigranten, discriminatie, illegale

  8. Michael Polanyi: Science as Personal Knowledge and Social Practice.

    Science.gov (United States)

    Nye, Mary Jo

    2017-03-20

    Tacit knowing: 2016 marked the 125th anniversary of the birth of the physical chemist Michael Polanyi, as well as the 40th of his death. This essay discusses his philosophy of science-in particular, his most significant work in this area, Personal Knowledge-from the perspective of his personal biography, as well as its lasting influence on the social sciences. In the photograph: Michael Polanyi at the Fritz Haber Institute in 1968.

  9. Does constraining field of view prevent extraction of geometric cues for humans during virtual-environment reorientation?

    Science.gov (United States)

    Sturz, Bradley R; Kilday, Zachary A; Bodily, Kent D

    2013-10-01

    Environment size has been shown to influence the reliance on local and global geometric cues during reorientation. Unless changes in environment size are produced by manipulating length and width proportionally, changes in environment size are confounded by the amount of the environment that is visible from a single vantage point. Yet, the influence of the amount of the environment that is visible from any single vantage point on the use of local and global geometric cues remains unknown. We manipulated the amount of an environment that was visually available to participants by manipulating field of view (FOV) in a virtual environment orientation task. Two groups of participants were trained in a trapezoid-shaped enclosure to find a location that was uniquely specified by both local and global geometric cues. One group (FOV 50°) had visually less of the environment available to them from any one perspective compared to another group (FOV 100°). Following training, we presented both groups with a control test along with three novel-shaped environments. Testing assessed the use of global geometry in isolation, in alignment with local geometry, or in conflict with local geometry. Results (confirmed by a follow-up experiment) indicated that constraining FOV prevented extraction of geometric properties and relationships of space and resulted in an inability to use either global or local geometric cues for reorientation.

  10. Reorienting in virtual 3D environments: do adult humans use principal axes, medial axes or local geometry?

    Directory of Open Access Journals (Sweden)

    Althea H Ambosta

    Full Text Available Studies have shown that animals, including humans, use the geometric properties of environments to orient. It has been proposed that orientation is accomplished primarily by encoding the principal axes (i.e., global geometry of an environment. However, recent research has shown that animals use local information such as wall length and corner angles as well as local shape parameters (i.e., medial axes to orient. The goal of the current study was to determine whether adult humans reorient according to global geometry based on principal axes or whether reliance is on local geometry such as wall length and sense information or medial axes. Using a virtual environment task, participants were trained to select a response box located at one of two geometrically identical corners within a featureless rectangular-shaped environment. Participants were subsequently tested in a transformed L-shaped environment that allowed for a dissociation of strategies based on principal axes, medial axes and local geometry. Results showed that participants relied primarily on a medial axes strategy to reorient in the L-shaped test environment. Importantly, the search behaviour of participants could not be explained by a principal axes-based strategy.

  11. "Alarme de incêndio": Michael Löwy e a crítica ecossocialista da civilização capitalista moderna "Fire alarm": Michael Löwy and the ecosocialist critique of the modern capitalist civilization

    Directory of Open Access Journals (Sweden)

    Fabio Mascaro Querido

    2013-04-01

    Full Text Available A emergência da crise ecológica, como sintoma mais nítido de uma verdadeira crise civilizató-ria, impôs novos desafios ao pensamento crítico e, em especial, ao marxismo. Partindo desse pressuposto, o objetivo deste artigo é apresentar a defesa de Michael Löwy de uma radicalização ecossocialista da crítica marxista da modernidade, tarefa para a qual a grande recusa de Walter Benjamin das ideologias do pro- gresso é uma das fontes decisivas de inspiração. Para Michael Löwy, a ruptura com as ideologias do progresso e com o paradigma civilizatório capitalista moderno é uma condição indispensável para a atua-lização ecossocialista do marxismo.The emergence of the ecological crisis as a clearer symptom of a true civilizatory crisis has imposed new challenges to critical thought and, in particular, to Marxism. Based on this assumption, this article aims to present Michael Löwy's defense of an ecosocialist radicalization of the Marxist critique of modernity, a task for which Walter Benjamin's great refusal of the ideologies of progress is one of the critical sources of inspiration. To Michael Löwy, breaking away from the ideologies of progress and from the modern capitalistic civilizatory paradigm is a prerequisite for the ecosocialist updating of Marxism.

  12. The effect of stress state on zirconium hydride reorientation

    Science.gov (United States)

    Cinbiz, Mahmut Nedim

    Prior to storage in a dry-cask facility, spent nuclear fuel must undergo a vacuum drying cycle during which the spent fuel rods are heated up to elevated temperatures of ≤ 400°C to remove moisture the canisters within the cask. As temperature increases during heating, some of the hydride particles within the cladding dissolve while the internal gas pressure in fuel rods increases generating multi-axial hoop and axial stresses in the closed-end thin-walled cladding tubes. As cool-down starts, the hydrogen in solid solution precipitates as hydride platelets, and if the multiaxial stresses are sufficiently large, the precipitating hydrides reorient from their initial circumferential orientation to radial orientation. Radial hydrides can severely embrittle the spent nuclear fuel cladding at low temperature in response to hoop stress loading. Because the cladding can experience a range of stress states during the thermo-mechanical treatment induced during vacuum drying, this study has investigated the effect of stress state on the process of hydride reorientation during controlled thermo-mechanical treatments utilizing the combination of in situ X-ray diffraction and novel mechanical testing analyzed by the combination of metallography and finite element analysis. The study used cold worked and stress relieved Zircaloy-4 sheet containing approx. 180 wt. ppm hydrogen as its material basis. The failure behavior of this material containing radial hydrides was also studied over a range of temperatures. Finally, samples from reactor-irradiated cladding tubes were examined by X-ray diffraction using synchrotron radiation. To reveal the stress state effect on hydride reorientation, the critical threshold stress to reorient hydrides was determined by designing novel mechanical test samples which produce a range of stress states from uniaxial to "near-equibiaxial" tension when a load is applied. The threshold stress was determined after thermo-mechanical treatments by

  13. Time course and auxin sensitivity of cortical microtubule reorientation in maize roots

    Science.gov (United States)

    Blancaflor, E. B.; Hasenstein, K. H.

    1995-01-01

    The kinetics of MT [microtubule] reorientation in primary roots of Zea mays cv. Merit, were examined 15, 30, 45, and 60 min after horizontal positioning. Confocal microscopy of longitudinal tissue sections showed no change in MT orientation 15 and 30 min after horizontal placement. However, after 45 and 60 min, MTs of the outer 4-5 cortical cell layers along the lower side were reoriented. In order to test whether MT reorientation during graviresponse is caused by an auxin gradient, we examined the organization of MTs in roots that were incubated for 1 h in solutions containing 10(-9) to 10(-6) M IAA. IAA treatment at 10(-8) M or less showed no major or consistent changes but 10(-7) M IAA resulted in MT reorientation in the cortex. The auxin effect does not appear to be acid-induced since benzoic acid (10(-5) M) did not cause MT reorientation. The region closest to the maturation zone was most sensitive to IAA. The data indicate that early stages of gravity induced curvature occur in the absence of MT reorientation but sustained curvature leads to reoriented MTs in the outer cortex. Growth inhibition along the lower side of graviresponding roots appears to result from asymmetric distribution of auxin following gravistimulation.

  14. Basic-functionalized recyclable ionic liquid catalyst: A solvent-free approach for Michael addition of 1,3-dicarbonyl compounds to nitroalkenes under ultrasound irradiation.

    Science.gov (United States)

    Narayanaperumal, Senthil; da Silva, Rodrigo César; Feu, Karla Santos; de la Torre, Alexander Fernández; Corrêa, Arlene G; Paixão, Márcio Weber

    2013-05-01

    A task-specific ionic liquid (TSIL) has been introduced as a recyclable catalyst in Michael addition. A series of nitroalkenes and various C-based nucleophiles were reacted in the presence of 30mol% of recyclable basic-functionalized ionic liquid. Good to excellent yields were obtained in 30min under ultrasound irradiation.

  15. Principles of Chemistry (by Michael Munowitz)

    Science.gov (United States)

    Kovac, Reviewed By Jeffrey

    2000-05-01

    At a time when almost all general chemistry textbooks seem to have become commodities designed by marketing departments to offend no one, it is refreshing to find a book with a unique perspective. Michael Munowitz has written what I can only describe as a delightful chemistry book, full of conceptual insight, that uses a novel and interesting pedagogic strategy. This is a book that has much to recommend it. This is the best-written general chemistry book I have ever read. An editor with whom I have worked recently remarked that he felt his job was to help authors make their writing sing. Well, the writing in Principles of Chemistry sings with the full, rich harmonies and creative inventiveness of the King's Singers or Chanticleer. Here is the first sentence of the introduction: "Central to any understanding of the physical world is one discovery of paramount importance, a truth disarmingly simple yet profound in its implications: matter is not continuous." This is prose to be savored and celebrated. Principles of Chemistry has a distinct perspective on chemistry: the perspective of the physical chemist. The focus is on simplicity, what is common about molecules and reactions; begin with the microscopic and build bridges to the macroscopic. The author's perspective is clear from the organization of the book. After three rather broad introductory chapters, there are four chapters that develop the quantum mechanical theory of atoms and molecules, including a strong treatment of molecular orbital theory. Unlike many books, Principles of Chemistry presents the molecular orbital approach first and introduces valence bond theory later only as an approximation for dealing with more complicated molecules. The usual chapters on descriptive inorganic chemistry are absent (though there is an excellent chapter on organic and biological molecules and reactions as well as one on transition metal complexes). Instead, descriptive chemistry is integrated into the development of

  16. Spin reorientation transition in Co/Au multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Quispe-Marcatoma, J., E-mail: jquispem@unmsm.edu.pe [Centro Brasileiro de Pesquisas Físicas, Rio de Janeiro 22290-180 (Brazil); Facultad de Ciencias Físicas, Universidad Nacional Mayor de San Marcos, P.O. Box 14-0149, Lima 14, Perú (Peru); Tarazona, H. [Facultad de Ciencias Físicas, Universidad Nacional Mayor de San Marcos, P.O. Box 14-0149, Lima 14, Perú (Peru); Pandey, B. [Centro Brasileiro de Pesquisas Físicas, Rio de Janeiro 22290-180 (Brazil); Department of Applied Science, Symbiosis Institute of Technology, SIU, Lavale, Pune 412 115, India. (India); Sousa, M.A. de [Instituto de Física, Universidade Federal de Goiás, Goiânia 74001-970 (Brazil); Carvalho, M. [Centro Brasileiro de Pesquisas Físicas, Rio de Janeiro 22290-180 (Brazil); Landauro, C.V. [Facultad de Ciencias Físicas, Universidad Nacional Mayor de San Marcos, P.O. Box 14-0149, Lima 14, Perú (Peru); Pelegrini, F. [Instituto de Física, Universidade Federal de Goiás, Goiânia 74001-970 (Brazil); Baggio Saitovitch, E. [Centro Brasileiro de Pesquisas Físicas, Rio de Janeiro 22290-180 (Brazil)

    2014-10-01

    We report a study about the spin reorientation transition (SRT) from perpendicular easy axis to in-plane easy axis of magnetization in Co/Au multilayers. A series of multilayers of Si/Au(100 Å)/{[Co(t_C_o)/Au(20 Å)]_2_0}/Au(50 Å) family were studied, with Co layer thickness varying between 6 Å to 30 Å. The thickness of the Au layer was chosen large enough in order to minimize the interlayer exchange coupling between Co layers. In such thick Au-layer samples the magnetic properties are mainly the result of competition between interlayer magnetostatic coupling due to stray field, perpendicular magnetic anisotropy and shape anisotropy. The effective anisotropy constant K{sub eff} and the second order anisotropy K{sub 2} were deduced from the fit of the resonant magnetic field obtained from out of plane dependence Ferromagnetic Resonance (FMR) experiments. To study the SRT, we have plotted the phase diagram between K{sub eff} and K{sub 2}. The results show that SRT occurs through the metastable region with K{sub 2} ≤ −½ K{sub eff}, (K{sub eff} > 0). It is interesting to note that FMR shows the coexistence of two modes with different anisotropy for small Co thickness, while for thick Co layers the modes have the same anisotropy. Moreover, in thick Co layer samples, volume and surface spin wave resonance (SWR) modes were also excited by the microwave field, around the perpendicular FMR geometry, giving a clear evidence of a magnetic coupling between the Co layers. - Highlights: • Co/Au multilayers with varying Co layer thickness are prepared by DC-magnetron sputtering. • The spin reorientation transition (SRT) and flipping of magnetic moment are studied. • Effective anisotropy constant (K) and 2nd order anisotropy constant (K{sub 2}) are calculated. • K Vs K{sub 2} plot showed that SRT occurs through the metastable region with K{sub 2} ≤ −½ K, (K > 0). • Ferromagnetic Resonance spectra showed the coexistence of two resonance modes.

  17. Temperature-driven spin reorientation transition of magnetron sputtered nickel thin film

    Institute of Scientific and Technical Information of China (English)

    Song Xiao-Hui; Zhang Dian-Lin

    2008-01-01

    The temperature-driven spin reorientation transition of magnetron sputtered Ni/Si(111)systems has been studied.The relationship between ac initial susceptibility and temperature of nickel films with different thicknesses shows that the magnetization orientation changes from in-plane to out-of-plane with the increase of temperature.The temperature dependence of magnetoelastic,magneto-crystalline,and magnetostatic anisotropies determines the direction of the reorientation transition.The temperature-driven spin reorientation transition is supported by Hall coefficient measurements which show that its temperature dependence is similar to that of susceptibility.

  18. Entrevista al profesor D. Michael Walker. - Interview with Professor D. Michael Walker.

    Directory of Open Access Journals (Sweden)

    Caravaca Guerrero, Consuelo Isabel

    2014-12-01

    Full Text Available Entrevistar a un investigador de la talla de D. Michael Walker supone hablar de un investigador reconocido a nivel nacional e internacional, uno de los mayores expertos en evolución humana de nuestros días. Nació en Colchester (Inglaterra en 1941 y tiene doble nacionalidad: británica y australiana. Actualmente es profesor emérito de la Universidad de Murcia en el Departamento de Zoología y Antropología Física de la Facultad de Biología. Pero su currículum no acaba aquí, Michael realizó tres carreras, Fisiología Animal, Medicina, y Arqueología Prehistórica, en la Universidad de Oxford. Es Doctor por esta universidad, gracias a su tesis leída sobre Paleoantropología y Prehistoria de las cuencas de los ríos Segura y Vinalopó. Nuestro entrevistado, también fue elegido Académico (Fellow –F.S.A.- en 1988 de la Society of Antiquaries of Londono SAL. Fundada en 1707, la SAL es la equivalente británica de la española Real Academia de la Historia. Es Fellow también del Real Instituto Antropológico de la Gran Bretaña (Royal Anthropological Institute of Great Britain y socio emérito de la Asociación Americana de Antropólogos Físicos (American Association of Physical Anthropologists.

  19. Stress-induced martensite variant reorientation in magnetic shape memory Ni Mn Ga single crystal studied by neutron diffraction

    Science.gov (United States)

    Molnar, P.; Sittner, P.; Lukas, P.; Hannula, S.-P.; Heczko, O.

    2008-06-01

    Stress-induced martensite variant reorientation in magnetic shape memory Ni-Mn-Ga single crystal was studied in situ by the neutron diffraction technique. Principles of determination of individual tetragonal martensitic variants in shape memory alloys are explained. Using neutron diffraction we show that the macroscopic strain originates solely from the martensite structure reorientation or variant redistribution. Neutron diffraction also reveals that the reorientation of martensite is not fully completed even at a stress value of 25 MPa, which is about 20 times larger than the mean stress needed for reorientation. Only one twinning system is active during the reorientation process.

  20. Structure-induced spin reorientation in magnetic nanostructures

    Science.gov (United States)

    Neumann, Alexander; Frauen, Axel; Vollmers, Julian; Meyer, Andreas; Oepen, Hans Peter

    2016-09-01

    We report on structuring-induced changes of the magnetic anisotropy of cylindrical nanostructures which are carved out of thin Pt/Co/Pt films. The magnetic properties of films and structures with a diameter of about 34 nm were investigated via magneto-optic Kerr effect. The magnetic anisotropy is determined for both films and nanostructures for varying Co thicknesses (0.5-7 nm). In general, the nanostructures exhibit larger perpendicular anisotropy than the films. On thickness increase of the Co layer two spin reorientation transitions at about 2.2 and 5 nm are found. At 2.2 nm the nanostructures exhibit the transition from perpendicular to in-plane orientation of magnetization while at 5 nm the reversed transition is found. The variation of the magnetic anisotropy of the Co nanostructures is not solely caused by the change of shape anisotropy. The net change, corrected for the shape, reveals a reduction of strain in the thinnest Co layers while the increase of the anisotropy of the nanostructures at higher Co thicknesses is caused by a transformation of the Co lattice from fcc to hcp.

  1. Resolving coiled shapes reveals new reorientation behaviors in C. elegans

    Science.gov (United States)

    Broekmans, Onno D; Rodgers, Jarlath B; Ryu, William S; Stephens, Greg J

    2016-01-01

    We exploit the reduced space of C. elegans postures to develop a novel tracking algorithm which captures both simple shapes and also self-occluding coils, an important, yet unexplored, component of 2D worm behavior. We apply our algorithm to show that visually complex, coiled sequences are a superposition of two simpler patterns: the body wave dynamics and a head-curvature pulse. We demonstrate the precise Ω-turn dynamics of an escape response and uncover a surprising new dichotomy in spontaneous, large-amplitude coils; deep reorientations occur not only through classical Ω-shaped postures but also through larger postural excitations which we label here as δ-turns. We find that omega and delta turns occur independently, suggesting a distinct triggering mechanism, and are the serpentine analog of a random left-right step. Finally, we show that omega and delta turns occur with approximately equal rates and adapt to food-free conditions on a similar timescale, a simple strategy to avoid navigational bias. DOI: http://dx.doi.org/10.7554/eLife.17227.001 PMID:27644113

  2. Guest Foreword from Michael Thomas CMG QC

    Directory of Open Access Journals (Sweden)

    Michael Thomas

    2012-04-01

    precedents and thought in a unique legal market in which ideas drawn from Islamic law, civil law and common law can intermingle and blend. It is not surprising therefore to see that this new publication will be dedicated to the subject of international law, both public and private. Its laudable aim is to promote legal discourse around the world, and to promote a wider international understanding of contemporary legal issues for the common benefit. As an open access, bilingual journal, addressing topics concerning any jurisdiction, I hope it will reach a wide audience, and fulfil its aim of promoting understanding between different cultures. I am sure that the journal will not only benefit Qatar’s legal community by advancing academic and practice-based legal discussion. I am also confident that it will stimulate thought in the global legal community at large. May I wish it every success and a long life. Michael Thomas CMG QC

  3. Water reorientation in the hydration shells of hydrophilic and hydrophobic solutes

    Institute of Scientific and Technical Information of China (English)

    LAAGE; Damien; STIRNEMANN; Guillaume; HYNES; James; T.

    2010-01-01

    We discuss some key aspects of our recent theoretical work on water reorientation dynamics,which is important in a wide range of phenomena,including aqueous phase chemical reactions,protein folding,and drug binding to proteins and DNA. It is shown that,contrary to the standard conception that these dynamics are diffusional,the reorientation of a water molecule occurs by sudden,large amplitude angular jumps. The mechanism involves the exchange of one hydrogen bond for another by the reorienting water,and the process can be fruitfully viewed as a chemical reaction. The results for reorientation times,which can be well described analytically,are discussed in the context of the molecular level interpretation of recent ultrafast infrared spectroscopic results,focusing on the concepts of structure making/breaking and solvent ’icebergs’.

  4. Spin reorientation transition process in single crystal NdFeO3

    Science.gov (United States)

    Song, Gaibei; Jiang, Junjie; Kang, Baojuan; Zhang, Jincang; Cheng, Zhenxiang; Ma, Guohong; Cao, Shixun

    2015-06-01

    The spin reorientation transition in single crystal NdFeO3 is studied using AC magnetic susceptibility, hysteresis loops, and polarized terahertz (THz) time domain spectroscopy measurements. Different frequency dependence behaviors of AC susceptibility reflect that the dynamic response of magnetization inside the spin reorientation region differs from the phase outside the transition region. The magnetization hysteresis loops at different temperatures reveal that domains formed during the spin reorientation process, which coincides with the abrupt increase of AC magnetic susceptibility during the transition. In addition, temperature dependent THz wave excitation of quasi-antiferromagnetic mode indicates the process of spin reorientation as a continuous rotation of Fe3+ spins rather than a mixed phase of Γ4 and Γ2.

  5. Switching of bacterial adhesion to a glycosylated surface by reversible reorientation of the carbohydrate ligand

    DEFF Research Database (Denmark)

    Weber, Theresa; Chrasekaran, Vijayan; Stamer, Insa

    2014-01-01

    The surface recognition in many biological systems is guided by the interaction of carbohydrate-specific proteins (lectins) with carbohydrate epitopes (ligands) located within the unordered glycoconjugate layer (glycocalyx) of cells. Thus, for recognition, the respective ligand has to reorient...

  6. Obituary: Michael John Seaton, 1923-2007

    Science.gov (United States)

    Pradhan, Anil; Nahar, Sultana

    2007-12-01

    Professor Michael John Seaton, hailed as the "Father of Atomic Astrophysics," passed away on May 29, 2007. He was one of the few Honorary Fellows of both the American Astronomical Society and the American Physical Society, so honored for his monumental contributions to both physics and astronomy. Mike Seaton was born on January 16, 1923 in Bristol, England. He attended Wallington County High School. But his leftist political activities, even at that stage, led to his expulsion, though he was eventually allowed to matriculate. He enlisted in the Royal Air Force as a navigator during the Second World War, and flew many dangerous missions. His legendary concentration and precision are reflected in the following anecdote. Once after a bombing mission his aircraft was lost in fog over the Alps. Seaton calculated the position and coordinates in flight to guide the aircraft. When the fog lifted, the crew found themselves flying perilously close to the mountains, but made it safely back. His associates often said, "A Seaton calculation is carried out as if his life depended on it." After the War he was admitted to University College London (UCL) as an undergraduate. Thereafter, he spent all of his professional career at UCL. Seaton received his Batchelor's degree in 1948, and his Ph.D. in 1951. His tenure at UCL coincided with the golden age of atomic astrophysics, for he was largely responsible for it. Seaton was elected Fellow of the Royal Society in 1967, and as President of the Royal Astronomical Society (RAS) in 1978. He was the recipient of an Honorary Doctorate from the Observatoire de Paris, an Honorary D.Sc. from the Queen's University of Belfast, the Gold Medal for Astronomy by the RAS, the Guthrie Medal by the Institute of Physics, the Royal Society Hughes award for lifetime work by the RAS, and several other prestigious awards. Nevertheless, as Alex Dalgarno recently remarked, Seaton was not part of the establishment because he chose not to be. Though rooted in

  7. Triphenylphosphine-Catalyzed Michael Addition of Alcohols to Acrylic Compounds

    Institute of Scientific and Technical Information of China (English)

    LIU, Hai-Ling; JIANG, Huan-Feng; WANG, Yu-Gang

    2007-01-01

    A facile triphenylphosphine-catalyzed Michael addition of alcohols to acrylic compounds was described. The reaction was carried out in open air at refluxing temperature in the presence of 10 mol% PPh3. Michael addition of saturated and unsaturated alcohols to acrylonitrile or acrylates has been examined. The reaction gaveβ-alkoxy derivatives with isolated yields of 5%-79%. PPh3 is cheaper and more stable than those trialkylphosphines previously used for the similar reactions, and the products can be easily separated from the reaction mixture via distillation.

  8. Low temperature spin reorientation in dysprosium iron garnet

    Energy Technology Data Exchange (ETDEWEB)

    Lahoubi, M; Younsi, W; Soltani, M L [Department of Physics, Badji-Mokhtar University, BP-12 Annaba, 23000 (Algeria); Voiron, J; Schmitt, D, E-mail: mlahoubi@gmail.co [Louis Neel Laboratory, CNRS-UJF, BP-166, 38042 Grenoble Cedex 9 (France)

    2009-03-01

    The spin reorientation (SR) phase transition in dysprosium iron garnet (Dy{sub 3}Fe{sub 5}O{sub 12} or DyIG) have been studied by specific heat C{sub p}(T) and high field magnetisation measurements M{sub T}(H) and M{sub H}(T) on single crystals at low temperature. A first order SR is observed with a sharp jump at T{sub SR} = 14.5+-0.5 K in the C{sub p}(T) curve which corresponds to a spontaneous change from the high temperature (HT) easy direction (111) to an (uuw) angular low temperature (LT) phases. Above T{sub SR}, the magnetic structure is described by the irreducible representation (IR) A{sub 2g} of the rhombohedral space group R 3 c. Below T{sub SR}, the magnetic structure changes in the monoclinic the space group C2/c with the IR A{sub g}. When the field H is kept aligned along the hard symmetry directions (100) and (110), we obtain respectively the variation of the angular positions theta(T) and theta'(T) from the total spontaneous magnetisation down to 1.5 K (theta = 39.23 deg. and theta' = 30.14 deg.) and the results are in good agreement with the previous observations in low fields. When the sample is allowed to rotate freely on itself, the critical field H{sub c}(T) between the HT(111) and the LT(uuw) angular phases permits us to precise the transition line up to 15 T and 40 K between the so called canted field induced (FI) and the associated collinear magnetic phases. The experimental magnetic phase diagram (MPD) is precisely determined in the (H{sub c}-T) plane and the domains of the existence and the stability of the two magnetic phases are specified.

  9. Subliminal Reorientation and Repositioning in Immersive Virtual Environments using Saccadic Suppression.

    Science.gov (United States)

    Bolte, Benjamin; Lappe, Markus

    2015-04-01

    Virtual reality strives to provide a user with an experience of a simulated world that feels as natural as the real world. Yet, to induce this feeling, sometimes it becomes necessary for technical reasons to deviate from a one-to-one correspondence between the real and the virtual world, and to reorient or reposition the user's viewpoint. Ideally, users should not notice the change of the viewpoint to avoid breaks in perceptual continuity. Saccades, the fast eye movements that we make in order to switch gaze from one object to another, produce a visual discontinuity on the retina, but this is not perceived because the visual system suppresses perception during saccades. As a consequence, our perception fails to detect rotations of the visual scene during saccades. We investigated whether saccadic suppression of image displacement (SSID) can be used in an immersive virtual environment (VE) to unconsciously rotate and translate the observer's viewpoint. To do this, the scene changes have to be precisely time-locked to the saccade onset. We used electrooculography (EOG) for eye movement tracking and assessed the performance of two modified eye movement classification algorithms for the challenging task of online saccade detection that is fast enough for SSID. We investigated the sensitivity of participants to translations (forward/backward) and rotations (in the transverse plane) during trans-saccadic scene changes. We found that participants were unable to detect approximately ±0.5m translations along the line of gaze and ±5° rotations in the transverse plane during saccades with an amplitude of 15°. If the user stands still, our approach exploiting SSID thus provides the means to unconsciously change the user's virtual position and/or orientation. For future research and applications, exploiting SSID has the potential to improve existing redirected walking and change blindness techniques for unlimited navigation through arbitrarily-sized VEs by real walking.

  10. Lipase-Catalyzed Aza-Michael Reaction on Acrylate Derivatives

    NARCIS (Netherlands)

    Steunenberg, P.; Sijm, M.; Zuilhof, H.; Sanders, J.P.M.; Scott, E.L.; Franssen, M.C.R.

    2013-01-01

    A methodology has been developed for an efficient and selective lipase-catalyzed aza-Michael reaction of various amines (primary and secondary) with a series of acrylates and alkylacrylates. Reaction parameters were tuned, and under the optimal conditions it was found that Pseudomonas stutzeri lipas

  11. Michael hydratase alcohol dehydrogenase or just alcohol dehydrogenase?

    NARCIS (Netherlands)

    Resch, V.A.; Jin, J.; Chen, B.S.; Hanefeld, U.

    2014-01-01

    The Michael hydratase – alcohol dehydrogenase (MhyADH) from Alicycliphilus denitrificans was previously identified as a bi-functional enzyme performing a hydration of α,β-unsaturated ketones and subsequent oxidation of the formed alcohols. The investigations of the bi-functionality were based on a

  12. Michael Moore kaevati kohtusse pettuse eest / Mari Rebane

    Index Scriptorium Estoniae

    Rebane, Mari

    2006-01-01

    Dokumentaalfilm "9/11 Fahrenheiti" ("Fahrenheit 9/11") : režissöör Michael Moore : USA 2004. Iraagi sõja invaliidistunud veteran andis režissööri kohtusse teda kujutavate flmikaadrite loata ja tenentsliku kasutamise pärast

  13. Reading Michael Apple--The Sociological Imagination at Work

    Science.gov (United States)

    Ball, Stephen J.

    2007-01-01

    This article discusses Michael Apple's contribution to the sociology of education and education policy analysis and the politics of education. It focuses on ways of "reading" Apple as an intellectual and an activist and looks at the trajectory of his work over a long and illustrious career.

  14. Eesti luksushotellide ristiisa / Michael Stenner ; interv. Malle Koido

    Index Scriptorium Estoniae

    Stenner, Michael

    2007-01-01

    Eesti tipphotelle 1997. aastast juhtinud sakslane, praegu hotellide Kolm Õde ja Telegraaf juht räägib Eesti ja Saksamaa erinevustest, Eesti hotelliärist, teeninduskultuurist ja personalist. Lisa: Kes on Michael Stenner ning kuidas ta Eestisse sattus? Ilmunud ka: Linnaleht : Pärnu, 23. veebr. 2007, lk. 5-6

  15. Tweeting Prayers and Communicating Grief over Michael Jackson Online

    Science.gov (United States)

    Sanderson, Jimmy; Cheong, Pauline Hope

    2010-01-01

    Death and bereavement are human experiences that new media helps facilitate alongside creating new social grief practices that occur online. This study investigated how people's postings and tweets facilitated the communication of grief after pop music icon Michael Jackson died. Drawing on past grief research, religion, and new media studies, a…

  16. Genres and Genre Theory: A Response to Michael Rosen

    Science.gov (United States)

    Christie, Frances

    2013-01-01

    This paper responds to Michael Rosen's blog entries, "How Genre Theory Saved the World", arguing that genre theory in the tradition of systemic functional linguistics (SFL) has made an important contribution to language and literacy pedagogy. It emerged in the Australian context in about 1980 and was initially developed in response to…

  17. Michael Moore kaevati kohtusse pettuse eest / Mari Rebane

    Index Scriptorium Estoniae

    Rebane, Mari

    2006-01-01

    Dokumentaalfilm "9/11 Fahrenheiti" ("Fahrenheit 9/11") : režissöör Michael Moore : USA 2004. Iraagi sõja invaliidistunud veteran andis režissööri kohtusse teda kujutavate flmikaadrite loata ja tenentsliku kasutamise pärast

  18. Solvent-free microwave-mediated Michael addition reactions

    Indian Academy of Sciences (India)

    H Surya Prakash Rao; S Jothilingam

    2005-07-01

    Facile Michael addition of active methylene compounds to ,-unsaturated carbonyl compounds takes place on the surface of potassium carbonate under microwave irradiation. Further studies on microwave-mediated Robinson annulations reveal a convenient and facile method for condensation of chalcone with methylene compounds to furnish cyclohexenones.

  19. SuchThatCast Episode 6: Michael Boylan

    NARCIS (Netherlands)

    Soraker, Johnny

    2012-01-01

    Michael Boylan is the John J. McDonnell jr chair in Ethics, and professor and chair of the philosophy department at Marymount University in Arlington, Virginia. In addition to being a poet and novelist, he has written more than 100 published articles and 25 books primarily in ethics, social and

  20. The correspondence of Michael Faraday, v.4 1849-1855

    CERN Document Server

    James, F

    2008-01-01

    This volume includes 70% of previously unpublished letters of Michael Farday spanning half of the 1850s and most of 1860. Topics include Faraday's work on regelation, the transmission of light through gold and his appointment by Emperor Napoleon III to be a Commander of the Legion of Honour.

  1. Correspondence of Michael Faraday, v.5 1855-1860

    CERN Document Server

    Faraday, Michael

    2008-01-01

    This volume includes 70% of previously unpublished letters of Michael Farday spanning half of the 1850s and most of 1860. Topics include Faraday's work on regelation, the transmission of light through gold and his appointment by Emperor Napoleon III to be a Commander of the Legion of Honour.

  2. Aza-Michael Reaction for an Undergraduate Organic Chemistry Laboratory

    Science.gov (United States)

    Nigam, Manisha; Rush, Brittney; Patel, Jay; Castillo, Raul; Dhar, Preeti

    2016-01-01

    A green, aza-Michael reaction is described that can be used to teach undergraduate students conjugate addition of nitrogen nucleophile to an a,ß-unsaturated ester. Students analyze spectral data of the product obtained from the assigned reaction to determine product structure and propose the mechanism of its formation. The experiment requires…

  3. Professor Porter ja tema viis konkurentsitegurit / Michael E Porter

    Index Scriptorium Estoniae

    Porter, Michael E

    2008-01-01

    Maailmas tuntud juhtimisguru Michael Porter viie konkurentsijõu teooriast ja selle rakendatavusest erinevates valdkondades. Lisad: Erinevused valdkondade kasumlikkuses; 5 määravat konkurentsijõudu; Investeeritud kapitali keskmine tasuvus; Mõnede USA tegevusvaldkondade kasumlikkus; Valdkonnaanalüüs praktikas; Valdkonna määratlemine; Valdkonnaanalüüsi sammud

  4. Michael Young's "The Rise of the Meritocracy": A Philosophical Critique

    Science.gov (United States)

    Allen, Ansgar

    2011-01-01

    This paper examines Michael Young's 1958 dystopia, "The Rise of the Meritocracy". In this book, the word "meritocracy" was coined and used in a pejorative sense. Today, however, meritocracy represents a positive ideal against which we measure the justice of our institutions. This paper argues that, when read in the twenty-first century, Young's…

  5. Aza-Michael Reaction for an Undergraduate Organic Chemistry Laboratory

    Science.gov (United States)

    Nigam, Manisha; Rush, Brittney; Patel, Jay; Castillo, Raul; Dhar, Preeti

    2016-01-01

    A green, aza-Michael reaction is described that can be used to teach undergraduate students conjugate addition of nitrogen nucleophile to an a,ß-unsaturated ester. Students analyze spectral data of the product obtained from the assigned reaction to determine product structure and propose the mechanism of its formation. The experiment requires…

  6. Educational Implications of Michael Fishbane's "Sacred Attunement: A Jewish Theology"

    Science.gov (United States)

    Marom, Daniel

    2008-01-01

    This article posits Michael Fishbane's Judaic scholarship as a prime resource for Jewish education. The link between the two fields can be made through a translation of the theological underpinnings of Fishbane's insights into Judaism to educational purposes and practices. Initial work with Jewish educators on establishing this link encouraged…

  7. An active and selective heterogeneous catalytic system for Michael addition

    Institute of Scientific and Technical Information of China (English)

    Hoda Keipour; Mohammad A. Khalilzadeh; Abolfazl Hosseini; Afsaneh Pilevar; Daryoush Zareyee

    2012-01-01

    Potassium fluoride doped natural zeolite was found to be an efficient and selective solid base catalyst for 1,4-Michael addition.The catalyst is easily prepared and the workup procedure simplified by simple filtration.All products were obtained in high yields as well as short reaction times.

  8. Fooling LC: Michael Crichton and "Eaters of the Dead."

    Science.gov (United States)

    Lonergan, David

    1998-01-01

    Chronicles the variety of means with which the novelist Michael Crichton has attempted to give his works the appearance of nonfiction. Specific and successful techniques utilized in "Eaters of the Dead" are noted, and the resulting erroneous classifications by the Library of Congress and subsequent catalogers are discussed. (Author)

  9. Berliinis võidutses Michael Haneke / Jüri Laulik

    Index Scriptorium Estoniae

    Laulik, Jüri, 1959-

    2005-01-01

    IX PÖFFil linastuv Michael Haneke film "Varjatud" ("Cache") võitis laupäeval mitu Euroopa Filmiakadeemia auhinda, sealhulgas parima filmi, parima lavastaja ja parima meesnäitleja (Daniel Auteuil) auhinna. Parima naisnäitleja tiitli pälvis Julia Jentsch ("Sophie Scholli viimased päevad"). Elutööpreemia sai sir Sean Connery

  10. "No More Excuses": Michael M. Crow on Analytics

    Science.gov (United States)

    Crow, Michael M.

    2012-01-01

    Michael M. Crow became the 16th president of Arizona State University in July 2002, with the goal of transforming ASU into what he calls a "New American University"--an institution combining the highest levels of academic excellence, inclusiveness to a broad demographic, and maximum societal impact. His view included increasing graduate…

  11. A Good Time: A Conversation with C. Michael Nelson

    Science.gov (United States)

    Zabel, Robert; Kaff, Marilyn; Teagarden, Jim

    2015-01-01

    C. Michael Nelson began his special education career as a teacher of adolescents with learning and behavior disorders. He has worked as a child psychologist and as a professor with the Department of Special Education and Rehabilitation Counseling at the University of Kentucky. He coordinated the graduate Personnel Preparation Program for Teachers…

  12. Michael hydratase alcohol dehydrogenase or just alcohol dehydrogenase?

    NARCIS (Netherlands)

    Resch, V.A.; Jin, J.; Chen, B.S.; Hanefeld, U.

    2014-01-01

    The Michael hydratase – alcohol dehydrogenase (MhyADH) from Alicycliphilus denitrificans was previously identified as a bi-functional enzyme performing a hydration of α,β-unsaturated ketones and subsequent oxidation of the formed alcohols. The investigations of the bi-functionality were based on a s

  13. SuchThatCast Episode 6: Michael Boylan

    NARCIS (Netherlands)

    Søraker, J.H.

    2012-01-01

    Michael Boylan is the John J. McDonnell jr chair in Ethics, and professor and chair of the philosophy department at Marymount University in Arlington, Virginia. In addition to being a poet and novelist, he has written more than 100 published articles and 25 books primarily in ethics, social and poli

  14. Insight into the Mechanism of the Michael Reaction.

    Science.gov (United States)

    Giraldo, Carolina; Gómez, Sara; Weinhold, Frank; Restrepo, Albeiro

    2016-07-01

    The mechanism for the nucleophilic addition step of the Michael reaction between methanethiol as a model Michael donor and several α-substituted methyl acrylates (X=F, Cl, Me, H, CN, NO2 ) as model Michael acceptors is described in detail. We suggest a novel way to condense electrophilic Fukui functions at specific atoms in terms of the contributions from the atomic orbitals to the LUMO or, more generally, to the orbital controlling the reaction. This procedure correctly associates activation energies to local electrophilic Fukui indices for the cases treated in this work. The calculated reaction barriers strongly depend on the nature of the substituent. As a general rule, activation energies are governed by structural changes, although electronic factors are significant for electron-withdrawing groups. Nucleophilic addition to Michael receptors is best described as a highly nonsynchronous process, in which the geometry of the transition state comprises a nonplanar six-membered ring. Formation of the S⋅⋅⋅C bond, which defines the interaction between the reactants, progresses ahead of all other primitive processes in the early stages of the transformation. In view of our results, we postulate that highly complex chemical reactions, as is the case for the nucleophilic addition step studied herein, that involve cleavage/formation of a total of six bonds, lower their activation energies by favoring nonsynchronicity, that is, for these types of systems, primitive changes should advance at different rates.

  15. Professor Porter ja tema viis konkurentsitegurit / Michael E Porter

    Index Scriptorium Estoniae

    Porter, Michael E

    2008-01-01

    Maailmas tuntud juhtimisguru Michael Porter viie konkurentsijõu teooriast ja selle rakendatavusest erinevates valdkondades. Lisad: Erinevused valdkondade kasumlikkuses; 5 määravat konkurentsijõudu; Investeeritud kapitali keskmine tasuvus; Mõnede USA tegevusvaldkondade kasumlikkus; Valdkonnaanalüüs praktikas; Valdkonna määratlemine; Valdkonnaanalüüsi sammud

  16. Tweeting Prayers and Communicating Grief over Michael Jackson Online

    Science.gov (United States)

    Sanderson, Jimmy; Cheong, Pauline Hope

    2010-01-01

    Death and bereavement are human experiences that new media helps facilitate alongside creating new social grief practices that occur online. This study investigated how people's postings and tweets facilitated the communication of grief after pop music icon Michael Jackson died. Drawing on past grief research, religion, and new media studies, a…

  17. Immigration and Social Systems : Collected Essays of Michael Bommes

    OpenAIRE

    2012-01-01

    Popular science Michael Bommes (hoogleraar Sociologie en Migratieonderzoek) was een van de meest briljante en originele geleerden in zijn vakgebied. Deze postume bundel bevat een selectie van zijn belangrijkste werk over immigratie en de verzorgingsstaat, de integratie van immigranten, discriminatie, illegale migratie, migrantennetwerken en migratiebeleidsonderzoek. Deze bundel laat zien hoe Bommes' inzichten en deskundigheid een fundamentele bijdrage hebben geleverd aan immigratiestudies....

  18. Domino Michael-Michael and Aldol-Aldol Reactions: Diastereoselective Synthesis of Functionalized Cyclohexanone Derivatives Containing Quaternary Carbon Center.

    Science.gov (United States)

    Ghorai, Manas K; Halder, Sandipan; Das, Subhomoy

    2015-10-02

    A simple strategy for the synthesis of highly functionalized cyclohexanone derivatives containing an all-carbon quaternary center from α-(aryl/alkyl)methylidene-β-keto esters or β-diketones via a K-enolate mediated domino Michael-Michael reaction sequence with moderate to good yield and excellent diastereoselectivity (de > 99%) is described. Interestingly, Li-base mediated reaction of α-arylmethylidene-β-diketones affords functionalized 3,5-dihydroxy cyclohexane derivatives as the kinetically controlled products via a domino aldol-aldol reaction sequence with excellent diastereoselectivity. Li-enolates of the β-keto esters or β-diketones undergo facile domino Michael-Michael reaction with nitro-olefins to afford the corresponding nitrocyclohexane derivatives in good yields and excellent diastereoselectivity (de > 99%). The formation of the products and the observed stereoselectivity were explained by plausible mechanisms and supported by extensive computational study. An asymmetric version of the protocol was explored with (L)-menthol derived nonracemic substrates, and the corresponding nonracemic cyclohexanone derivatives containing an all-carbon quaternary center were obtained with excellent stereoselectivity (de, ee > 99%).

  19. Michael Pärt ئ suure muusika taustajõud / Michael Pärt ; interv. Siim Nestor

    Index Scriptorium Estoniae

    Pärt, Michael

    2008-01-01

    Arvo Pärdi pojast Michael Pärdist. Tema tööst "music editor"-ina - helimonteerijana, tööst muusika produktsiooni, salvestamise ja muusika kirjutamise abijõuna. Koostööst maailmas tuntud muusikutega

  20. Michael Pärt ئ suure muusika taustajõud / Michael Pärt ; interv. Siim Nestor

    Index Scriptorium Estoniae

    Pärt, Michael

    2008-01-01

    Arvo Pärdi pojast Michael Pärdist. Tema tööst "music editor"-ina - helimonteerijana, tööst muusika produktsiooni, salvestamise ja muusika kirjutamise abijõuna. Koostööst maailmas tuntud muusikutega

  1. Aza-Michael Addition of Isatin and Phthalimide to Symmetrical Fumaric Esters in Ionic Liquid Media

    Institute of Scientific and Technical Information of China (English)

    IMANZADEH Gholam Hassan; MOLLAEI TAVANA Mahdieh; ZAMANLOO Mohammad Reza; MANSOORI Yagoub

    2009-01-01

    Highly efficient aza-Michael additions of isatin and phthalimide to symmetrical fumaric esters in ionic liquid media to produce the corresponding Michael adducts in excellent yields are described which were performed at 100 ℃ for 1-5 h. The results show that these aza-Michael additions are not effective with fumaric esters containing sterically hindered alkoxy groups.

  2. Reorientation phenomena in imidazolium methyl sulfonate as probed by advanced solid-state NMR.

    Science.gov (United States)

    Goward, Gillian R; Saalwächter, Kay; Fischbach, Ingrid; Spiess, Hans Wolfgang

    2003-01-01

    Evidence for reorientation of imidazolium rings in imidazolium methylsulfonate is demonstrated using solid-state NMR. This material is a model system for exciting new proton-conducting materials based on imidazole. Two advanced NMR methods, including 1H-13C and 1H-15N recoupled polarization transfer with dipolar sideband pattern analysis and analysis of the coalescence of 13C lineshapes are used to characterize the ring reorientation. The process is found to occur at temperatures well below the melting point of the salt, between 240 and 380 K, and is described by a single activation energy, of 38+/-5 kJ/mol. This material is considered as a model system for quantifying the ring reorientation process, which is often proposed to be the rate-limiting step in proton transport in imidazole-based proton conducting materials.

  3. Influence of Rayleigh-Taylor Instability on Liquid Propellant Reorientation in a Low-Gravity Environment

    Institute of Scientific and Technical Information of China (English)

    LI Zhang-Guo; LIU Qiu-Sheng; LIU Rong; HU Wei; DENG Xin-Yu

    2009-01-01

    A computational simulation is conducted to investigate the influence of Rayleigh-Taylor instability on liquid propellant reorientation flow dynamics for the tank of CZ-3A launch vehicle series fuel tanks in a low-gravity environment. The volume-of-fluid (VOF) method is used to simulate the free surface flow of gas-liquid. The process of the liquid propellant reorientation started from initially fiat and curved interfaces are numerically studied. These two different initial conditions of the gas-liquid interface result in two modes of liquid flow. It is found that the Rayleigh-Taylor instability can be reduced evidently at the initial gas-liquid interface with a high curve during the process of liquid reorientation in a low-gravity environment.

  4. Femtosecond study of the effects of ions on the reorientation dynamics of water

    CERN Document Server

    van der Post, Sietse T; Bakker, Huib J

    2013-01-01

    We study the effects of ions on the reorientation dynamics of liquid water with polarization-resolved femtosecond mid-infared spectroscopy. We probe the anisotropy of the excitation of the O-D stretch vibration of HDO molecules in solutions of NaCl, NaI and tetra-alkylammonium bromide salts in 8 percent HDO:H2O. We find that the reorientation O-D groups of HDO molecules hydrating the Cl- and I- anions occurs on two different time scales with time constants of 2pm0.3 ps and 9pm2 ps. The fast component is due to a wobbling motion of the O-D group that keeps the hydrogen bond with the halogenic anion intact. For solutions of tetra-alkylammonium bromide salts we observe a very strong slowing down of the reorientation of water that is associated with the hydration of the hydrophobic alkyl groups of the tetra-alkylammonium ions.

  5. Reorientation of single-wall carbon nanotubes in negative anisotropy liquid crystals by an electric field

    Directory of Open Access Journals (Sweden)

    Amanda García-García

    2016-06-01

    Full Text Available Single-wall carbon nanotubes (SWCNT are anisotropic nanoparticles that can cause modifications in the electrical and electro-optical properties of liquid crystals. The control of the SWCNT concentration, distribution and reorientation in such self-organized fluids allows for the possibility of tuning the liquid crystal properties. The alignment and reorientation of CNTs are studied in a system where the liquid crystal orientation effect has been isolated. Complementary studies including Raman spectroscopy, microscopic inspection and impedance studies were carried out. The results reveal an ordered reorientation of the CNTs induced by an electric field, which does not alter the orientation of the liquid crystal molecules. Moreover, impedance spectroscopy suggests a nonnegligible anchoring force between the CNTs and the liquid crystal molecules.

  6. Reorientation response of magnetic microspheres attached to gold electrodes under an applied magnetic field

    Energy Technology Data Exchange (ETDEWEB)

    De Los Santos Valladares, L.; Reeve, R.M.; Mitrelias, T.; Langford, R.M.; Barnes, C.H.W., E-mail: luis_d_v@hotmail.com [Cavendish Laboratory, Department of Physics, University of Cambridge Materials and Structures Laboratory (United Kingdom); Bustamante Dominguez, A. [Laboratorio de Ceramicos y Nanomateriales, Facultad de Ciencias Fisicas, Universidad Nacional Mayor de San Marcos, Lima (Peru); Aguiar, J. Albino [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil). Departamento de Fisica; Azuma, Y. [Materials and Structures Laboratory, Tokyo Institute of Technology, Midori-ku, Yokohama (Japan); Majima, Y. [CREST, Japan Science and Technology Agency (JST), Midori-ku, Yokohama (Japan)

    2013-08-15

    In this work, we report the mechanical reorientation of thiolated ferromagnetic microspheres bridging a pair of gold electrodes under an external magnetic field. When an external magnetic field (7 kG) is applied during the measurement of the current-voltage characteristics of a carboxyl ferromagnetic microsphere (4 μm diameter) attached to two gold electrodes by self-assembled monolayers (SAMs) of octane dithiol (C{sub 8}H{sub 18}S{sub 2}), the current signal is distorted. Rather than due to magnetoresistance, this effect is caused by a mechanical reorientation of the ferromagnetic sphere, which alters the number of SAMs between the sphere and the electrodes and therefore affects conduction. To study the physical reorientation of the ferromagnetic particles, we measure their hysteresis loops while suspended in a liquid solution. (author)

  7. Fluidization, resolidification, and reorientation of the endothelial cell in response to slow tidal stretches.

    Science.gov (United States)

    Krishnan, Ramaswamy; Canovic, Elizabeth Peruski; Iordan, Andreea L; Rajendran, Kavitha; Manomohan, Greeshma; Pirentis, Athanassios P; Smith, Michael L; Butler, James P; Fredberg, Jeffrey J; Stamenovic, Dimitrije

    2012-08-15

    Mechanical stretch plays an important role in regulating shape and orientation of the vascular endothelial cell. This morphological response to stretch is basic to angiogenesis, neovascularization, and vascular homeostasis, but mechanism remains unclear. To elucidate mechanisms, we used cell mapping rheometry to measure traction forces in primary human umbilical vein endothelial cells subjected to periodic uniaxial stretches. Onset of periodic stretch of 10% strain amplitude caused a fluidization response typified by attenuation of traction forces almost to zero. As periodic stretch continued, the prompt fluidization response was followed by a slow resolidification response typified by recovery of the traction forces, but now aligned along the axis perpendicular to the imposed stretch. Reorientation of the cell body lagged reorientation of the traction forces, however. Together, these observations demonstrate that cellular reorientation in response to periodic stretch is preceded by traction attenuation by means of cytoskeletal fluidization and subsequent traction recovery transverse to the stretch direction by means of cytoskeletal resolidification.

  8. Effect of spin reorientation on magnetocaloric and transport properties of NdAl2

    Science.gov (United States)

    de Souza, M. V.; da Silva, J. A.; Silva, L. S.

    2017-01-01

    We report the magneto-thermal and resistive properties of rare-earth dialuminide NdAl2, including spin reorientation transition. To this purpose, we used a theoretical model that considers the interactions of exchange and Zeeman, besides the anisotropy due to the electrical crystal field. The theoretical results obtained were compared to experimental data of the NdAl2 in single crystal and bulk forms. Explicitly, we have calculated the anisotropic variation of magnetic entropy with the magnetic field oriented along the three principal crystallographic directions: [100], [110], and [111] of NdAl2 single crystal, where a signature of the spin reorientation is observed in the [110] and [111] directions. Moreover, of magnetoresistivity we consider the applied magnetic field along the crystallographic directions [100] and [110]. In turn, for the polycrystalline form, the good agreement between theory and experiment confirms the presence of spin reorientation, which was predicted theoretically in magnetization curves.

  9. Chaotic attitude and reorientation maneuver for completely liquid-filled spacecraft with flexible appendage

    Institute of Scientific and Technical Information of China (English)

    Baozeng Yue

    2009-01-01

    The present paper investigates the chaotic attitude dynamics and reorientation maneuver for completely viscous liquid-filled spacecraft with flexible appendage. All of the equations of motion are derived by using Lagrangian mechanics and then transformed into a form consisting of an unperturbed part plus perturbed terms so that the system's nonlinear characteristics can be exploited in phase space.Emphases are laid on the chaotic attitude dynamics produced from certain sets of physical parameter values of the spacecraft when energy dissipation acts to derive the body from minor to major axis spin. Numerical solutions of these equations show that the attitude dynamics of liquid-filled flexible spacecraft possesses characteristics common to random, nonperiodic solutions and chaos, and it is demonstrated that the desired reorientation maneuver is guaranteed by using a pair of thruster impulses. The control strategy for reorientation maneuver is designed and the numerical simulation results are presented for both the uncontrolled and controlled spins transition.

  10. Reorientation of single-wall carbon nanotubes in negative anisotropy liquid crystals by an electric field

    Science.gov (United States)

    García-García, Amanda; Vergaz, Ricardo; Algorri, José F; Zito, Gianluigi; Cacace, Teresa; Marino, Antigone; Otón, José M

    2016-01-01

    Summary Single-wall carbon nanotubes (SWCNT) are anisotropic nanoparticles that can cause modifications in the electrical and electro-optical properties of liquid crystals. The control of the SWCNT concentration, distribution and reorientation in such self-organized fluids allows for the possibility of tuning the liquid crystal properties. The alignment and reorientation of CNTs are studied in a system where the liquid crystal orientation effect has been isolated. Complementary studies including Raman spectroscopy, microscopic inspection and impedance studies were carried out. The results reveal an ordered reorientation of the CNTs induced by an electric field, which does not alter the orientation of the liquid crystal molecules. Moreover, impedance spectroscopy suggests a nonnegligible anchoring force between the CNTs and the liquid crystal molecules. PMID:27547599

  11. Delirium prevention in critically ill adults through an automated reorientation intervention - A pilot randomized controlled trial.

    Science.gov (United States)

    Munro, Cindy L; Cairns, Paula; Ji, Ming; Calero, Karel; Anderson, W McDowell; Liang, Zhan

    Explore the effect of an automated reorientation intervention on ICU delirium in a prospective randomized controlled trial. Delirium is common in ICU patients, and negatively affects outcomes. Few prevention strategies have been tested. Thirty ICU patients were randomized to 3 groups. Ten received hourly recorded messages in a family member's voice during waking hours over 3 ICU days, 10 received the same messages in a non-family voice, and 10 (control) did not receive any automated reorientation messages. The primary outcome was delirium free days during the intervention period (evaluated by CAM-ICU). Groups were compared by Fisher's Exact Test. The family voice group had more delirium free days than the non-family voice group, and significantly more delirium free days (p = 0.0437) than the control group. Reorientation through automated, scripted messages reduced incidence of delirium. Using identical scripted messages, family voice was more effective than non-family voice. Copyright © 2017 Elsevier Inc. All rights reserved.

  12. Electron spin relaxation due to reorientation of a permanent zero field splitting tensor.

    Science.gov (United States)

    Schaefle, Nathaniel; Sharp, Robert

    2004-09-15

    Electron spin relaxation of transition metal ions with spin S> or =1 results primarily from thermal modulation of the zero field splitting (zfs) tensor. This occurs both by distortion of the zfs tensor due to intermolecular collisions and, for complexes with less than cubic symmetry, by reorientational modulation of the permanent zfs tensor. The reorientational mechanism is much less well characterized in previous work than the distortional mechanism although it is an important determinant of nuclear magnetic resonance (NMR) paramagnetic relaxation enhancement phenomena (i.e., the enhancement of NMR relaxation rates produced by paramagnetic ions in solution or NMR-PRE). The classical density matrix theory of spin relaxation does not provide an appropriate description of the reorientational mechanism at low Zeeman field strengths because the zero-order spin wave functions are stochastic functions of time. Using spin dynamics simulation techniques, the time correlation functions of the spin operators have been computed and used to determine decay times for the reorientational relaxation mechanism for S=1. In the zfs limit of laboratory field strengths (H(Zeem)spin decay is exponential, the spin relaxation time, tau(S) (composite function) approximately 0.53tau(R)((1)), where tau(R)((1)) is the reorientational correlation time of a molecule-fixed vector. The value of tau(S) (composite function) is independent of the magnitude of the cylindrical zfs parameter (D), but it depends strongly on low symmetry zfs terms (the E/D ratio). Other spin dynamics (SD) simulations examined spin decay in the intermediate regime of field strengths where H(Zeem) approximately H(zfs) (composite function), and in the vicinity of the Zeeman limit. The results demonstrate that the reorientational electron spin relaxation mechanism is often significant when H(zfs) (composite function)> or =H(Zeem), and that its neglect can lead to serious errors in the interpretation of NMR-PRE data.

  13. Tribute to Professor Anthony J. McMichael

    Directory of Open Access Journals (Sweden)

    Ashwin Swaminathan

    2014-11-01

    Full Text Available Emeritus Professor A. J. “Tony” McMichael (1942–2014 was an internationally renowned and pioneering Australian academic and advocate in epidemiology, who was passionate about understanding the influences of the environment on human health. In an illustrious career spanning more than four decades, he made significant contributions to the scientific community and policy discourse—including ground-breaking research related to the health of children. McMichael was a prolific academic writer with over 300 peer-reviewed papers; 160 book chapters and two sole-authored books. However, his outstanding talent was for integrating complex and seemingly unrelated strands from the environmental and health sciences into a cohesive narrative—and highlighting its relevance to lay persons, scientists and governments alike. He was instrumental in validating this nascent field of research and inspiring many others to follow his lead.

  14. Double Michael Addition Reaction of Bischalcone under Ultrasound

    Institute of Scientific and Technical Information of China (English)

    LI,Ji-Tai; XU,Wen-Zhi; CHEN,Guo-Feng; LI,Tong-Shuang

    2004-01-01

    @@ The Michael addition of 1,5-diaryl-1,4-pentadien-3-ones with active methylene compounds has been the subjects of many investigations. Ultrasound has increasingly been used in organic synthesis in the last three decades. Compared with traditional methods, this method is more convenient and easily controlled. A large number of organic reactions can be carried out in higher yield, shorter reaction time or milder conditions under ultrasonic irradiation. KF/Al2O3 as a useful solid supported catalyst has received considerable attention because of their high level of chemoselectivity and environmental compatibility as well as simplicity of operation and their ready availability at low cost. Herein we report the double Michael addition of dibenzalacetone with active methlene compounds such as dimethyl malonate, diethyl malonate,methyl cyanoacetate and ethyl cyanoacetate catalyzed by KF/Al2O3 under ultrasound irradiation.

  15. Tribute to Professor Anthony J. McMichael.

    Science.gov (United States)

    Swaminathan, Ashwin; Lucas, Robyn M; Harley, David

    2014-11-26

    Emeritus Professor A. J. "Tony" McMichael (1942-2014) was an internationally renowned and pioneering Australian academic and advocate in epidemiology, who was passionate about understanding the influences of the environment on human health. In an illustrious career spanning more than four decades, he made significant contributions to the scientific community and policy discourse-including ground-breaking research related to the health of children. McMichael was a prolific academic writer with over 300 peer-reviewed papers; 160 book chapters and two sole-authored books. However, his outstanding talent was for integrating complex and seemingly unrelated strands from the environmental and health sciences into a cohesive narrative-and highlighting its relevance to lay persons, scientists and governments alike. He was instrumental in validating this nascent field of research and inspiring many others to follow his lead.

  16. Pengaruh Tipografi pada Era Massimo Vignelli terhadap Tipografi Michael Bierut

    Directory of Open Access Journals (Sweden)

    Irwan Harnoko

    2011-09-01

    Full Text Available Massimo Vignelli is a senior graphic designer lived in New York, as a vocal modernism against postmodernism. His statement firmly opposing post-modernism in several occasions: interview in Helvetica the movie, type radio, talk show, and some articles in Looking Closer or AIGA Journal. Graphic design works of Massimo Vignelli reflected his characteristic, which is firmly choosing typeface. Typefaces of Vignelly are around 5 typefaces: Bodoni, Helvetica, Times Roman, Century, and Futura. The article uses formal analysis method. The writers collected materials about Michael Bierut, Massimo VIgnelli and Tibor Kalman from books and websites. The writers compare the typeface opinion of Massimo Vignelli (modernism designer, Michael Bierut designer (transition era designer from modernism to post-modernism, and Tibor Kalman (a designer in A Century of Graphic Design, as the influence of Bieruts betrayal over Vignelli.

  17. Pengaruh Tipografi pada Era Massimo Vignelli terhadap Tipografi Michael Bierut

    Directory of Open Access Journals (Sweden)

    Irwan Harnoko

    2011-10-01

    Full Text Available Massimo Vignelli is a senior graphic designer lived in New York, as a vocal modernism against post-modernism. His statement firmly opposing post-modernism in several occasions: interview in Helvetica the movie, typeradio, talkshow, and some articles in Looking Closer or AIGA Journal. Graphic design works of Massimo Vignelli reflected his characteristic, which is firmly choosing typeface. Typefaces of Vignelly are around 5 typefaces: Bodoni, Helvetica, Times Roman, Century, and Futura. The article uses formal analysis method. The writers collected materials about Michael Bierut, Massimo VIgnelli and Tibor Kalman from books and websites. The writers compare the typeface opinion of Massimo Vignelli (modernism designer, Michael Bierut designer (transition era designer from modernism to post-modernism, and Tibor Kalman (a designer in A Century of Graphic Design, as the influencer of Bierut’s betrayal over Vignelli. 

  18. Euroopa parimaks filmiks sai Michael Haneke "Valge lint" / Andres Laasik

    Index Scriptorium Estoniae

    Laasik, Andres, 1960-2016

    2009-01-01

    Euroopa Filmiakadeemia auhindadest: parima filmiauhinna sai Saksamaal Bochumis toimunud tseremoonial Michael Haneke "Valge lint", mille eest Haneke sai ka parima režissööri ja stsenaristi auhinna. Parimaks meesnäitlejaks pärjati Tahar Rahim ("Un Prophete"), parimaks naisnäitlejaks Kate Winslet ("The Reader"), publikupreemia sai Danny Boyle'i "Rentslimiljonär. Ka teistest võitjatest

  19. The cinema of Michael Bay : an aesthetic of excess

    OpenAIRE

    Bennett, Bruce

    2015-01-01

    The hyper-kinetic action films of Michael Bay have come to exemplify the commercial, technical and aesthetic transformations of contemporary blockbuster cinema during a period in which the dynamic, disorienting effects of media convergence are reconfiguring viewing practices and remodelling cinematic institutions. However, despite their commercial success and cultural visibility, these films remain more or less absent from academic criticism of late twentieth and early twenty-first century gl...

  20. Analysis of the black crust on Saint Michael's Church

    Science.gov (United States)

    Popister, I.; Zeman, A.

    2012-04-01

    The goal of the present study is to characterize the black crust on the main stone used at Saint Michael's Church in Cluj-Napoca, Romania. The gases in the atmosphere, along with natural and artificial pollutants can cause damage the integrity of the stone when it comes in contact with the stone's chemistry. In order to explain the mechanism of stone decay due to black crust it is necessary to know what "weathering" means, so it must be seen as a complex process that consists of: type of material, the environment in which the material is located, and the amount of time required for the process to take place. Each material has particular properties, due to its composition and genesis. When it comes in contact with the acidity of the "acid rain" (caused by sulphur, nitrogen oxides and carbon dioxide), the rain penetrates into the pore structure, corroding it and "allowing" the atmospheric particles to penetrate the stone. St. Michael's Church is one of the oldest Gothic architectural monuments in Cluj, Romania, being built predominantly from Cenozoic (Upper Eocene) limestone, locally known as the Cluj Limestone. The main quarry was in Baciu, near Cluj. The samples that were collected from the Saint Michael's Church were characterized by means of: optical microscope, Scattering Electronic Microscope, thin sections, EDS The samples that were collected from the Saint Michael's Church went through a series of tests: optical microscope, Scattering Electronic Microscope, thin sections, EDX, and cross-section. The optical microscope analysis of the thin sections revealed that the black crust layer is approximately 0.01mm, and in the sample there are perfectly shaped ooides, which is characteristic to this type of limestone. The SEM analysis shows a resedimentation layer on the surface of the black crust, which occurred probably due to the effect of acid rain. Further information regarding the results of the test will be presented on the poster.

  1. Euroopa parimaks filmiks sai Michael Haneke "Valge lint" / Andres Laasik

    Index Scriptorium Estoniae

    Laasik, Andres, 1960-2016

    2009-01-01

    Euroopa Filmiakadeemia auhindadest: parima filmiauhinna sai Saksamaal Bochumis toimunud tseremoonial Michael Haneke "Valge lint", mille eest Haneke sai ka parima režissööri ja stsenaristi auhinna. Parimaks meesnäitlejaks pärjati Tahar Rahim ("Un Prophete"), parimaks naisnäitlejaks Kate Winslet ("The Reader"), publikupreemia sai Danny Boyle'i "Rentslimiljonär. Ka teistest võitjatest

  2. Orbital magnetic moment instability at the spin reorientation transition of Nd2Fe14B

    Science.gov (United States)

    Garcia; Chaboy; Bartolome; Goedkoop

    2000-07-10

    Highly accurate soft-XMCD data recorded on a Nd2Fe14B single crystal, through the spin reorientation transition show that the average Fe orbital moment (a) is proportional to the macroscopic Fe anisotropy constant, and (b) diverges 15 K below the reorientation transition temperature. This divergence is indicative of a critical behavior and it is related to a tetragonal distortion. These results give experimental evidence of the mutual dependence between orbital moment, macroscopic magnetic anisotropy, and tetragonal distortion. Furthermore, it is argued that the critical behavior of the orbital moment is at the origin of similar divergences previously observed in Mossbauer and Hall-effect data.

  3. New fractal math tool providing simultaneous reorientation and acceleration of spacecraft

    Science.gov (United States)

    Yefremov, Alexander P.

    2017-10-01

    Quaternion based math system of spacecraft reorientation is extended by admitting imaginary rotation parameters, thus involving hyperbolic functions. For simplicity only one simple hyperbolic rotation is added as the last one in the series of orthogonal matrices. The scheme is reduced to a single rotation about instant axis, and to transformation of primitive basis on a 2D fractal space of dimension ½. This new tool is proved to simultaneously reorient the spacecraft and to accelerate it the kinematics automatically described as relativistic. With a small speed the problem becomes a classical one.

  4. Temperature-pressure-induced solid-solid to reorientation in FCC metallic nanowire: a molecular dynamic study.

    Science.gov (United States)

    Sutrakar, Vijay Kumar; Roy Mahapatra, D; Pillai, A C R

    2012-01-11

    Atomistic simulation of initial oriented FCC Cu nanowires shows a novel coupled temperature-pressure dependent reorientation from to phase. A temperature-pressure-induced solid-solid to reorientation diagram is generated for Cu nanowire with varying cross-sectional sizes. A critical pressure is reported for Cu nanowires with varying cross-sectional sizes, above which an initial oriented nanowire shows temperature independent reorientation into the phase. The effect of surface stresses on the to reorientation is also studied. The results indicate that above a critical cross-sectional size for a given temperature-pressure, to reorientation is not possible. It is also reported here that for a given applied pressure, an increase in temperature is required for the to reorientation with increasing cross-sectional size of the nanowire. The temperature-pressure-induced solid-solid to reorientation diagram reported in the present paper could further be used as guidelines for controlling the reorientations/shape memory in nano-scale applications of FCC metallic nanowires.

  5. RHO binding to FAM65A regulates Golgi reorientation during cell migration

    Science.gov (United States)

    Marshall, Christopher J.

    2016-01-01

    ABSTRACT Directional cell migration involves reorientation of the secretory machinery. However, the molecular mechanisms that control this reorientation are not well characterised. Here, we identify a new Rho effector protein, named FAM65A, which binds to active RHOA, RHOB and RHOC. FAM65A links RHO proteins to Golgi-localising cerebral cavernous malformation-3 protein (CCM3; also known as PDCD10) and its interacting proteins mammalian STE20-like protein kinases 3 and 4 (MST3 and MST4; also known as STK24 and STK26, respectively). Binding of active RHO proteins to FAM65A does not affect the kinase activity of MSTs but results in their relocation from the Golgi in a CCM3-dependent manner. This relocation is crucial for reorientation of the Golgi towards the leading edge and subsequent directional cell migration. Our results reveal a previously unidentified pathway downstream of RHO that regulates the polarity of migrating cells through Golgi reorientation in a FAM65A-, CCM3- and MST3- and MST4-dependent manner. PMID:27807006

  6. Social reorientation in adolescence : neurobiological changes and individual differences in empathic concern

    NARCIS (Netherlands)

    Overgaauw, Sandy

    2015-01-01

    One of the most prominent changes in adolescence is social reorientation. In other words, adolescents develop more intimate relationships with peers, they discover what it is like to be involved in a romantic relationship, and they take (social) risks by for example showing risky driving in the pres

  7. Use of Geometry for Spatial Reorientation in Children Applies Only to Symmetric Spaces

    Science.gov (United States)

    Lew, Adina R.; Gibbons, Bryony; Murphy, Caroline; Bremner, J. Gavin

    2010-01-01

    Proponents of the geometric module hypothesis argue that following disorientation, many species reorient by use of macro-environment geometry. It is suggested that attention to the surface layout geometry of natural terrain features may have been selected for over evolutionary time due to the enduring and unambiguous location information it…

  8. Why Size Counts: Children's Spatial Reorientation in Large and Small Enclosures

    Science.gov (United States)

    Learmonth, Amy E.; Newcombe, Nora S.; Sheridan, Natalie; Jones, Meredith

    2008-01-01

    When mobile organisms are spatially disoriented, for instance by rapid repetitive movement, they must re-establish orientation. Past research has shown that the geometry of enclosing spaces is consistently used for reorientation by a wide variety of species, but that non-geometric features are not always used. Based on these findings, some…

  9. Time-dependent solution for reorientation of rotating tidally deformed visco-elastic bodies

    Science.gov (United States)

    Hu, Haiyang; van der Wal, Wouter; Vermeersen, Bert

    2017-04-01

    Many icy satellites or planets contain features which suggest a (past) reorientation of the body, such as the tiger stripes on Enceladus and the heart-shaped Sputnik Planum on Pluto. Most of these icy bodies are tidally locked and this creates a large tidal bulge which is about three times of its centrifugal (equatorial) bulge. To study the reorientation of such rotating tidally deformed body is complicated and most previous studies apply the so-called fluid limit method. The fluid limit approach ignores the viscous response of the body and assumes that it immediately reaches its fluid limit when simulating the reorientation due to a changing load. As a result, this method can only simulate cases when the change in the load is much slower than the dominant viscous modes of the body. For other kinds of load, for instance, a Heaviside load due to an impact which creates an instant relocation of mass, it does not give us a prediction of how the reorientation is accomplished (e.g. How fast? Along which path?). We establish a new method which can give an accurate time-dependent solution for reorientation of rotating tidally deformed bodies. Our method can be applied both semi-analytically or numerically (with finite element method) to include features such as lateral heterogeneity or non-linear material. We also present an extension of our method to simulate the e ffect of a fossil bulge. With our method, we show that reorientation of a tidally deformed body driven by a positive mass anomaly near the poles has a preference for rotating around the tidal axis instead of towards it, contrary to predictions in previous studies. References Hu, H., W. van der Wal and L.L.A. Vermeersen (2017). A numerical method for reorientation of rotating tidally deformed visco-elastic bodies. Journal of Geophysical Research: Planets, doi:10.1002/2016JE005114, 2016JE005114. Matsuyama, I. and Nimmo, F. (2007). Rotational stability of tidally deformed planetary bodies. Journal of Geophysical

  10. Michael Marinov memorial volume multiple facets of quantization and supersymmetry

    CERN Document Server

    Vainshtein, A I

    2002-01-01

    This book is dedicated to the memory of Michael Marinov, the theorist who, together with Felix Berezin, introduced the classical description of spin by anticommuting Grassmann variables. It contains original papers and reviews by physicists and mathematicians written specifically for the book. These articles reflect the current status and recent developments in the areas of Marinov's research: quantum tunneling, quantization of constrained systems, supersymmetry, and others. The personal recollections included portray the human face of M Marinov, a person of great knowledge and integrity.

  11. Michael Kohlhaas or the Germans and Their Law

    Directory of Open Access Journals (Sweden)

    Heike Jung

    2014-12-01

    Full Text Available Asked to pick a single representative ‘German’ piece for a discourse on ‘Law and Literature’ one almost inevitably ends up with Kleist’s tale Michael Kohlhaas. It seems to be the literary incarnation of the German stance vis-à-vis the law. It is all about horses; it could just as well be about dogs. Kohlhaas fights a devastating battle, using legal means and outright violence, even warfare, for their recovery in good shape. Victorious eventually with his legal actions, he is happy to trade in his own life for this victory, thus giving an extreme example for the nice line between being in the right and pursuing this position with disproportionate rigour. Of course, the interpretations of Michael Kohlhaas (which, in its complete version, dates of 1810 have varied from epoch to epoch as well as from reader to reader. It is not possible to rehearse the bulk of ‘Kohlhaas literature’. In comparing legal cultures, it might be of interest to look into the question why such a somber story on the law forms part and will continue to form part of the German cultural heritage. Si se tiene que elegir un único representante “alemán” para una ponencia sobre “derecho y literatura”, es inevitable optar por la obra de Kleist, Michael Kohlhaas. Parece la encarnación literaria de la posición alemana hacia el derecho. El libro trata de caballos; también podría tratar sobre perros. Kohlhaas libra una batalla devastadora usando medios legales y la violencia pura y dura, incluso la guerra, para que se recuperen en buena forma. Finalmente resulta ganador mediante acciones legales, está contento de dedicar su propia vida para conseguir esta victoria, dando así un ejemplo extremo de la línea que existe entre tener la razón y seguir esta posición con un rigor desproporcionado. Por supuesto, las interpretaciones de Michael Kohlhaas (publicado en 1810 han variado de una época a otra, y de un lector a otro. No es posible revisar el grueso de

  12. Hechter Michael, Horne Christine (Dir., Theories of Social Order

    Directory of Open Access Journals (Sweden)

    Yves Laberge

    2011-09-01

    Full Text Available Cette anthologie méconnue examine le concept fondamental de l’ordre social en 34 textes tantôt anciens (de Tocqueville, Marx, Engels, Simmel ou relativement récents (le chapitre 19 comparant les groupes humains aux fourmis date de 2007. Ici, l’ordre social est compris de diverses manières ; Michael Hechter et Christine Horne rappellent d’emblée que « sans ordre social, il ne peut y avoir ni agriculture, ni industrie, ni commerce, ni investissement, ni développement économique, ni justice, n...

  13. Estratégia competitiva: Michael Porter 30 anos depois

    OpenAIRE

    Manuel Portugal Ferreira; Fernando A. Ribeiro Serra; Marcelo Lopes Carneiro; Aline Botelho Schneider

    2009-01-01

    Os estudos de estratégia têm sido muito influenciados pelos trabalhos de Michael Porter, em todas as suas fases, como as cinco forças, as estratégias genéricas, a cadeia de valor e as vantagens competitivas das nações. Neste artigo, analisou-se a influência de Porter nos trabalhos brasileiros em estratégia, a partir dos trabalhos selecionados e apresentados no EnANPAD. No levantamento para a análise dos artigos, considerando 10 anos de EnANPAD (1997-2006), foram selecionados 46 artigos. A ide...

  14. The Correspondence of Michael Faraday Pt 6 1860-1867

    CERN Document Server

    Frank, James

    2012-01-01

    Michael Faraday (1791-1867) was one of the most important men of science in nineteenth century Britain. His discoveries of electro-magnetic rotations (1821) and electro-magnetic induction (1831) laid the foundations of the modern electrical industry. His discovery of the magneto-optical effect and diamagnetism (1845) led him to formulate the field theory of electro-magnetism, which forms one of the cornerstones of modern physics.These and a whole host of other fundamental discoveries in physics and chemistry, together with his lecturing at the Royal Institution, his work for the state (includi

  15. Glutathione Adduct Patterns of Michael-Acceptor Carbonyls.

    Science.gov (United States)

    Slawik, Christian; Rickmeyer, Christiane; Brehm, Martin; Böhme, Alexander; Schüürmann, Gerrit

    2017-02-22

    Glutathione (GSH) has so far been considered to facilitate detoxification of soft organic electrophiles through covalent binding at its cysteine (Cys) thiol group, followed by stepwise catalyzed degradation and eventual elimination along the mercapturic acid pathway. Here we show that in contrast to expectation from HSAB theory, Michael-acceptor ketones, aldehydes and esters may form also single, double and triple adducts with GSH involving β-carbon attack at the much harder N-terminus of the γ-glutamyl (Glu) unit of GSH. In particular, formation of the GSH-N single adduct contradicts the traditional view that S alkylation always forms the initial reaction of GSH with Michael-acceptor carbonyls. To this end, chemoassay analyses of the adduct formation of GSH with nine α,β-unsaturated carbonyls employing high performance liquid chromatography and tandem mass spectrometry have been performed. Besides enriching the GSH adductome and potential biomarker applications, electrophilic N-terminus functio-nalization is likely to impair GSH homeostasis substantially through blocking the γ-glutamyl transferase catalysis of the first breakdown step of modified GSH, and thus its timely reconstitution. The discussion includes a comparison with cyclic adducts of GSH and furan metabolites as reported in literature, and quantum chemically calculated thermodynamics of hard-hard, hard-soft and soft-soft adducts.

  16. En recuerdo de Michael Heyd (1943-2014

    Directory of Open Access Journals (Sweden)

    Peset, José Luis

    2016-12-01

    Full Text Available In homage to Professor Michael Heyd, in this paper are presented some of the main influences of his book “Be sober and reasonable” (1995 on several studies about Robert Burton and his classical book The Anatomy of Melancholy. Mainly, the relations between medicine and religious thought are briefly followed, looking for confluences between North and South Europe. The influence of “enthusiasm” and “melancholy” in the history of European thought was always an important interest in the life and teaching of this very intelligent researcher of cultural history.En homenaje al Profesor Michael Heyd, se muestran en este artículo algunas de las influencias principales de su libro “Be sober and reasonable” (1995 en algunos estudios sobre el clásico libro de Robert Burton The Anatomy of Melancholy. En especial, se siguen brevemente las relaciones entre la medicina y el pensamiento religioso, buscando confluencias entre el norte y el sur de Europa. La influencia de “entusiasmo” y “melancolía” en la historia del pensamiento europeo fue siempre un importante interés en la vida y la enseñanza de este muy inteligente investigador en historia cultural.

  17. Asymmetric Michael Addition of Activated Alkenes to Nitro Alkenes Catalyzed by Organic Catalyst

    Institute of Scientific and Technical Information of China (English)

    XUE Dong; CHEN Yong-Chun; CUI Xin; WANG Qi-Wei; ZHU Jin; DENG Jin-Gen

    2003-01-01

    @@ Enantioselective Michael addition is one of the most powerfulbond-forming reaction in organic synthesis. [1] A mong the Michael acceptors, nitro alkenes are very attractive, because the nitro group is the most electron-withdrawing group known and it can serve as masked functionality to be further transformed after the addition has taken place. [2] Recently, asymmetric Michael reactions catalyzed by organic catalyst have draw much attention.[3

  18. Enantioselective Synthesis of β-(3-Hydroxypyrazol-1-yl)ketones Using An Organocatalyzed Michael Addition Reaction

    Science.gov (United States)

    Gogoi, Sanjib; Zhao, Cong-Gui; Ding, Derong

    2009-01-01

    β-(3-Hydroxypyrazol-1-yl)ketones have been prepared in high yields and excellent enantioselectivities (94–98% ee) via a Michael addition reaction between 2-pyrazolin-5-ones and aliphatic acyclic α,β-unsaturated ketones using 9-epi-9-amino-9-deoxyquinine as the catalyst. These results account for the first example of an aza-Michael addition of the ambident 2-pyrazolin-5-one anion to a Michael acceptor. PMID:19415906

  19. Measuring molecular reorientation at liquid surfaces with time-resolved sum-frequency spectroscopy: a theoretical framework.

    Science.gov (United States)

    Nienhuys, Han-Kwang; Bonn, Mischa

    2009-05-28

    A theoretical framework is presented for the design and analysis of ultrafast time- and polarization-resolved surface vibrational spectroscopy, aimed at elucidating surface molecular reorientational motion in real time. Vibrational excitation with linearly polarized light lifts the azimuthal symmetry of the surface transition-dipole distribution, causing marked, time-dependent changes in the surface sum-frequency generation (SFG) intensity. The subsequent recovery of the SFG signal generally reflects both vibrational relaxation and reorientational motion of surface molecules. We present experimental schemes that allow direct quantification of the time scale of surface molecular reorientational diffusive motion.

  20. BUS 320 Assignment 2: Case Study: Michael Dell—The Man Behind Dell

    OpenAIRE

    Laynebaril

    2017-01-01

    BUS 320 Assignment 2: Case Study: Michael Dell—The Man Behind Dell   Click Link Below To Buy: http://hwcampus.com/shop/bus-320-assignment-2-case-study-michael-dell-the-man-behind-dell/ Or Visit www.hwcampus.com   Assignment 2: Case Study: Michael Dell—The Man Behind Dell Presentation (Change Management) Michael Dell began building and selling computers from his dorm room at age 19. He dropped out of the University of Texas when his sales hit $60 million and has nev...

  1. Effect of thermo-mechanical cycling on zirconium hydride reorientation studied in situ with synchrotron X-ray diffraction

    Science.gov (United States)

    Colas, Kimberly B.; Motta, Arthur T.; Daymond, Mark R.; Almer, Jonathan D.

    2013-09-01

    The circumferential hydrides normally present in nuclear reactor fuel cladding after reactor exposure may dissolve during drying for dry storage and re-precipitate when cooled under load into a more radial orientation, which could embrittle the fuel cladding. It is necessary to study the rates and conditions under which hydride reorientation may happen in order to assess fuel integrity in dry storage. The objective of this work is to study the effect of applied stress and thermal cycling on the hydride morphology in cold-worked stress-relieved Zircaloy-4 by combining conventional metallography and in situ X-ray diffraction techniques. Metallography is used to study the evolution of hydride morphology after several thermo-mechanical cycles. In situ X-ray diffraction performed at the Advanced Photon Source synchrotron provides real-time information on the process of hydride dissolution and precipitation under stress during several thermal cycles. The detailed study of diffracted intensity, peak position and full-width at half-maximum provides information on precipitation kinetics, elastic strains and other characteristics of the hydride precipitation process. The results show that thermo-mechanical cycling significantly increases the radial hydride fraction as well as the hydride length and connectivity. The radial hydrides are observed to precipitate at a lower temperature than circumferential hydrides. Variations in the magnitude and range of hydride strains due to reorientation and cycling have also been observed. These results are discussed in light of existing models and experiments on hydride reorientation. The study of hydride elastic strains during precipitation shows marked differences between circumferential and radial hydrides, which can be used to investigate the reorientation process. Cycling under stress above the threshold stress for reorientation drastically increases both the reoriented hydride fraction and the hydride size. The reoriented hydride

  2. Effect of dopant nanoparticles on reorientation process in polymer-dispersed liquid crystals

    Science.gov (United States)

    Zobov, K. V.; Zharkova, G. M.; Syzrantsev, V. V.

    2016-01-01

    The analysis of the experimental data of the nanoscale powders application for doping polymer-dispersed liquid crystals (PDLC) was represented in this work. A model based on the separation of the liquid crystals reorientation process on the surface mode and the volume mode was proposed and tested. In the research the wide-spread model mixture PDLC were used. But alumina nanoparticles were the distinctive ones obtained by electron beam evaporation. The proposed model allowed to conclude that the nanoparticles localization at the surface of the droplets (as in the Pickering emulsion) lead to the variation of the connection force between the liquid crystals and the polymer. The effect of nanoparticles resulted in an acceleration of the reorientation process near the surface when the control field is turned on and in a deceleration when it is turned off. The effect for the different size particles was confirmed.

  3. A mechanism for reorientation of cortical microtubule arrays driven by microtubule severing.

    Science.gov (United States)

    Lindeboom, Jelmer J; Nakamura, Masayoshi; Hibbel, Anneke; Shundyak, Kostya; Gutierrez, Ryan; Ketelaar, Tijs; Emons, Anne Mie C; Mulder, Bela M; Kirik, Viktor; Ehrhardt, David W

    2013-12-06

    Environmental and hormonal signals cause reorganization of microtubule arrays in higher plants, but the mechanisms driving these transitions have remained elusive. The organization of these arrays is required to direct morphogenesis. We discovered that microtubule severing by the protein katanin plays a crucial and unexpected role in the reorientation of cortical arrays, as triggered by blue light. Imaging and genetic experiments revealed that phototropin photoreceptors stimulate katanin-mediated severing specifically at microtubule intersections, leading to the generation of new microtubules at these locations. We show how this activity serves as the basis for a mechanism that amplifies microtubules orthogonal to the initial array, thereby driving array reorientation. Our observations show how severing is used constructively to build a new microtubule array.

  4. Transient Reorientation of a Doped Liquid Crystal System under a Short Laser Pulse

    Institute of Scientific and Technical Information of China (English)

    LI Tao; XIANG Ying; LIU Yi-Kun; WANG Jian; YANG Shun-Lin

    2009-01-01

    The transient optical nonlinearity of a nematic liquid crystal doped with azo-dye DRW is examined.The optical reorientation threshold of a 25-μm-thick planar-aligned sample of 5CB using a 50 ns pulse duration 532 nm YAG laser pulse is observed to decrease from 800 mJ/mm2 to 0.6 mJ/mm2 after the addition of 1 vol% azo dopant,a reduction of three orders of magnitude.When using a laser pulse duration of 10 ns,no such effect is observed.Experimental results indicate that the azo dopant molecules undergo photoisomerization from trans-isomer to cis-isomer under exposure to light,and this conformation change reorients the 5CB molecules via intermolecular coupling between guest and host.This guest-host couphng also affects the azo photoisomerization process.

  5. Optimal reorientation of underactuated spacecraft using genetic algorithm with wavelet approximation

    Institute of Scientific and Technical Information of China (English)

    Xinsheng Ge; Liqun Chen

    2009-01-01

    The optimal attitude control of an underactuated spacecraft is investigated in this paper. The flywheels of the spacecraft can somehow only provide control inputs in two independent directions. The dynamic equations are formulated for the spacecraft under a nonholonomic constraint resulting from the constant time-rate of the total angular momentum of the system. The reorientation of such underactuated spacecraft is transformed into an optimal control problem. A ggnetic algorithm is proposed to derive the control laws of the two flywheels angle velocity inputs. The control laws are approximated by the discrete orthogonal wavelets.The numerical simulations indicate that the genetic algorithm with the wavelet approximation is an effective approach to deal with the optimal reorientation of underactuated spacecraft.

  6. Paleomagnetic reorientation of San Andreas Fault Observatory at Depth (SAFOD) core

    Science.gov (United States)

    Pares, J.M.; Schleicher, A.M.; van der Pluijm, B.A.; Hickman, S.

    2008-01-01

    We present a protocol for using paleomagnetic analysis to determine the absolute orientation of core recovered from the SAFOD borehole. Our approach is based on determining the direction of the primary remanent magnetization of a spot core recovered from the Great Valley Sequence during SAFOD Phase 2 and comparing its direction to the expected reference field direction for the Late Cretaceous in North America. Both thermal and alternating field demagnetization provide equally resolved magnetization, possibly residing in magnetite, that allow reorientation. Because compositionally similar siltstones and fine-grained sandstones were encountered in the San Andreas Fault Zone during Stage 2 rotary drilling, we expect that paleomagnetic reorientation will yield reliable core orientations for continuous core acquired from directly within and adjacent to the San Andreas Fault during SAFOD Phase 3, which will be key to interpretation of spatial properties of these rocks. Copyright 2008 by the American Geophysical Union.

  7. Influence of an electric field on the spin-reorientation transition in Ni/Cu(100)

    Energy Technology Data Exchange (ETDEWEB)

    Gerhard, Lukas [Institut für Nanotechnologie, Karlsruhe Institute of Technology, 76344 Eggenstein-Leopoldshafen (Germany); Bonell, Frédéric; Suzuki, Yoshishige [CREST, Japan Science Technology, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 (Japan); Graduate School of Engineering Science, Osaka University, Osaka 560-8531 (Japan); Wulfhekel, Wulf [Institut für Nanotechnologie, Karlsruhe Institute of Technology, 76344 Eggenstein-Leopoldshafen (Germany); Physikalisches Institut, Karlsruhe Institute of Technology, 76131 Karlsruhe (Germany)

    2014-10-13

    Magnetoelectric coupling offers the possibility to change the magnetic state of a material by an applied electric field. Over the last few years, metallic systems have come up as simple prototypes for this interaction. While the previous studies focused on Fe and Co thin films or their alloys, here we demonstrate magnetoelectric coupling in a Ni thin film which is close to a spin-reorientation transition. Our magneto-optic Kerr effect measurements on 10 ML of Ni/Cu(100) show a considerable influence of the applied electric field on the magnetism. This rounds off the range of magnetic metals that exhibit magnetoelectric coupling, and it reveals the possibility of an electric field control of a spin-reorientation transition.

  8. A structured continuum modelling framework for martensitic transformation and reorientation in shape memory materials.

    Science.gov (United States)

    Bernardini, Davide; Pence, Thomas J

    2016-04-28

    Models for shape memory material behaviour can be posed in the framework of a structured continuum theory. We study such a framework in which a scalar phase fraction field and a tensor field of martensite reorientation describe the material microstructure, in the context of finite strains. Gradients of the microstructural descriptors naturally enter the formulation and offer the possibility to describe and resolve phase transformation localizations. The constitutive theory is thoroughly described by a single free energy function in conjunction with a path-dependent dissipation function. Balance laws in the form of differential equations are obtained and contain both bulk and surface terms, the latter in terms of microstreses. A natural constraint on the tensor field for martensite reorientation gives rise to reactive fields in these balance laws. Conditions ensuring objectivity as well as the relation of this framework to that provided by currently used models for shape memory alloy behaviour are discussed.

  9. Pluto followed its heart: reorientation and faulting of Pluto due to volatile loading in Sputnik Planum

    Science.gov (United States)

    Tuttle Keane, James; Matsuyama, Isamu; Kamata, Shunichi; Steckloff, Jordan

    2016-10-01

    The New Horizons flyby of Pluto revealed the dwarf planet to be a strikingly diverse, geologically active world. Perhaps the most intriguing feature on the New Horizons encounter hemisphere is Sputnik Planum—a 1000 km diameter, probable impact basin, filled with several kilometers of actively convecting volatile ices (N2, CH4, CO). One salient characteristic of Sputnik Planum is its curious alignment with the Pluto-Charon tidal axis. The alignment of large geologic features with principal axis of inertia (such as the tidal axis) is the hallmark of global reorientation, i.e. true polar wander. Here we show that the present location of Sputnik Planum is a natural consequence of loading of 1-2 km of volatile ices within the Sputnik Planum basin. Larger volatile ice thicknesses (like those inferred from studies of ice convection within Sputnik Planum) betray an underlying negative gravity anomaly associated with the basin. As Pluto reoriented in response to the loading of volatile ices within Sputnik Planum, stresses accumulated within the lithosphere (as each geographic location experiences a change in tidal/rotational potential). These reorientation stresses, coupled with loading stresses, and stresses from the freezing of a subsurface ocean resulted in the fracturing of Pluto's lithosphere in a characteristic, global pattern of extensional faults. Our predicted pattern of extensional faults due to this reorientation closely replicates the observed distribution of faults on Pluto (more so than global expansion, orbit migration, de-spinning, or loading alone). Sputnik Planum likely formed ~60° northwest of its present location, and was loaded with volatile ices over millions of years due to seasonal volatile transport cycles. This result places Pluto in a truly unique category of planetary bodies where volatiles are not only controlling surface geology and atmospheric processes, but they are also directly controlling the orientation of the entire dwarf planet

  10. Geometric and featural systems, separable and combined: Evidence from reorientation in people with Williams syndrome

    Science.gov (United States)

    Ferrara, Katrina; Landau, Barbara

    2015-01-01

    Spatial reorientation by humans and other animals engages geometric representations of surface layouts as well as featural landmarks; however, the two types of information are thought to be behaviorally and neurally separable. In this paper, we examine the use of these two types of information during reorientation among children and adults with Williams syndrome (WS), a genetic disorder accompanied by abnormalities in brain regions that support use of both geometry and landmarks. Previous studies of reorientation in adolescents and adults with WS have shown deficits in the ability to use geometry for reorientation, but intact ability to use features, suggesting that the two systems can be differentially impaired by genetic disorder. Using a slightly modified layout, we found that many WS participants could use geometry, and most could use features along with geometry. However, the developmental trajectories for the two systems were quite different from one other, and different from those found in typical development. Purely geometric responding was not correlated with age in WS, and search processes appeared similar to those in typically developing (TD) children. In contrast, use of features in combination with geometry was correlated with age in WS, and search processes were distinctly different from TD children. The results support the view that use of geometry and features stem from different underlying mechanisms, that the developmental trajectories and operation of each are altered in WS, and that combination of information from the two systems is atypical. Given brain abnormalities in regions supporting the two kinds of information, our findings suggest that the co-operation of the two systems is functionally altered in this genetic syndrome. PMID:26275835

  11. Giant magnetostrictive superlattices: from spin reorientation transition to MEMS. Static and dynamical properties

    CERN Document Server

    Tiercelin, N; Preobrazhensky, V; Pernod, P; Gall, H L

    2002-01-01

    The results of development of 'giant magnetostrictive' multilayers with spin reorientation transition (SRT) for microactuators are presented. Manifestations of magneto-mechanical instability and nonlinearity near SRT are studied experimentally and simulated numerically. Improvement of magneto-mechanical sensitivity near SRT is demonstrated for various modes of linear and nonlinear actuation of magnetostrictive unimorph. Limitations of sensitivity caused by magnetic field distortions are described by a numerical model, the results are compared with the experimental data.

  12. GOLPH3 drives cell migration by promoting Golgi reorientation and directional trafficking to the leading edge.

    Science.gov (United States)

    Xing, Mengke; Peterman, Marshall C; Davis, Robert L; Oegema, Karen; Shiau, Andrew K; Field, Seth J

    2016-12-01

    The mechanism of directional cell migration remains an important problem, with relevance to cancer invasion and metastasis. GOLPH3 is a common oncogenic driver of human cancers, and is the first oncogene that functions at the Golgi in trafficking to the plasma membrane. Overexpression of GOLPH3 is reported to drive enhanced cell migration. Here we show that the phosphatidylinositol-4-phosphate/GOLPH3/myosin 18A/F-actin pathway that is critical for Golgi-to-plasma membrane trafficking is necessary and limiting for directional cell migration. By linking the Golgi to the actin cytoskeleton, GOLPH3 promotes reorientation of the Golgi toward the leading edge. GOLPH3 also promotes reorientation of lysosomes (but not other organelles) toward the leading edge. However, lysosome function is dispensable for migration and the GOLPH3 dependence of lysosome movement is indirect, via GOLPH3's effect on the Golgi. By driving reorientation of the Golgi to the leading edge and driving forward trafficking, particularly to the leading edge, overexpression of GOLPH3 drives trafficking to the leading edge of the cell, which is functionally important for directional cell migration. Our identification of a novel pathway for Golgi reorientation controlled by GOLPH3 provides new insight into the mechanism of directional cell migration with important implications for understanding GOLPH3's role in cancer. © 2016 Xing, Peterman, et al. This article is distributed by The American Society for Cell Biology under license from the author(s). Two months after publication it is available to the public under an Attribution–Noncommercial–Share Alike 3.0 Unported Creative Commons License (http://creativecommons.org/licenses/by-nc-sa/3.0).

  13. MICHAEL GORBOVY AS AN ORGANIZER OF THE SCOUTING MOVEMENT IN GUTSULSCHINA (THE BEGINNING OF THE XX CENTURY

    Directory of Open Access Journals (Sweden)

    Iryna Didukh

    2015-04-01

    Full Text Available The Ukrainian scouting movement on western Ukrainian territories reached the highest level during the interwar period. Despite the relative integrity it had its own features in Galicia, Volyn', on Bukovyna, Transcarpathia. As living conditions turned out to be peaceful, old plast centres started to form in schools. "Plast" in Galicia was an example of inheritance and incentive to the development on other western Ukrainian territories and in emigration. The figure of famous Hutsul plastun Michael Gorbovy (1896 – 1941 is very interesting and multidimensional. Indeed, it is a symbolic name in the history of Ukrainian scout organization. He was a member of many national public organizations. With his name economic and cooperative activities of "Plast" in Gutsulschina are connected. He was the organizer of craft departments of "Plast". The unicity of this disjoint person is expressed in his great love for Ukraine and responsibility for its future. Gorbovy considered physical, moral and national-patriotic education of children and youth as his main task. He strived to spread the idea of Ukrainian scouting among wide groups of people. For this work on 22th of May, 1924 he was awarded with a plast title of a scoutmaster. Michael Gorbovy formed national consciousness, high spirituality, love of God and Ukraine among youth for the "great aim" which is to build an independent Ukrainian nation. Experts qualify current spiritual and moral state of the Ukrainian society as "crisis". School is not able to fill the educational vacuum which has appeared after the elimination of the Pioneer and Komsomol organizations. No new alternative children's institutions have been suggested. In such a difficult situation the experience of the activity of the Ukrainian scouting movement may be useful. Creative and practical achievements of "Plast" leaders as key figures and main carriers of the plast's educational methods are especially important. These include a figure of

  14. Reorientation and faulting of Pluto due to volatile loading within Sputnik Planitia.

    Science.gov (United States)

    Keane, James T; Matsuyama, Isamu; Kamata, Shunichi; Steckloff, Jordan K

    2016-12-01

    Pluto is an astoundingly diverse, geologically dynamic world. The dominant feature is Sputnik Planitia-a tear-drop-shaped topographic depression approximately 1,000 kilometres in diameter possibly representing an ancient impact basin. The interior of Sputnik Planitia is characterized by a smooth, craterless plain three to four kilometres beneath the surrounding rugged uplands, and represents the surface of a massive unit of actively convecting volatile ices (N2, CH4 and CO) several kilometres thick. This large feature is very near the Pluto-Charon tidal axis. Here we report that the location of Sputnik Planitia is the natural consequence of the sequestration of volatile ices within the basin and the resulting reorientation (true polar wander) of Pluto. Loading of volatile ices within a basin the size of Sputnik Planitia can substantially alter Pluto's inertia tensor, resulting in a reorientation of the dwarf planet of around 60 degrees with respect to the rotational and tidal axes. The combination of this reorientation, loading and global expansion due to the freezing of a possible subsurface ocean generates stresses within the planet's lithosphere, resulting in a global network of extensional faults that closely replicate the observed fault networks on Pluto. Sputnik Planitia probably formed northwest of its present location, and was loaded with volatiles over million-year timescales as a result of volatile transport cycles on Pluto. Pluto's past, present and future orientation is controlled by feedbacks between volatile sublimation and condensation, changing insolation conditions and Pluto's interior structure.

  15. Optimal reorientation of asymmetric underactuated spacecraft using differential flatness and receding horizon control

    Science.gov (United States)

    Cai, Wei-wei; Yang, Le-ping; Zhu, Yan-wei

    2015-01-01

    This paper presents a novel method integrating nominal trajectory optimization and tracking for the reorientation control of an underactuated spacecraft with only two available control torque inputs. By employing a pseudo input along the uncontrolled axis, the flatness property of a general underactuated spacecraft is extended explicitly, by which the reorientation trajectory optimization problem is formulated into the flat output space with all the differential constraints eliminated. Ultimately, the flat output optimization problem is transformed into a nonlinear programming problem via the Chebyshev pseudospectral method, which is improved by the conformal map and barycentric rational interpolation techniques to overcome the side effects of the differential matrix's ill-conditions on numerical accuracy. Treating the trajectory tracking control as a state regulation problem, we develop a robust closed-loop tracking control law using the receding-horizon control method, and compute the feedback control at each control cycle rapidly via the differential transformation method. Numerical simulation results show that the proposed control scheme is feasible and effective for the reorientation maneuver.

  16. Free energy barrier for melittin reorientation from a membrane-bound state to a transmembrane state

    CERN Document Server

    Irudayam, Sheeba J; Berkowitz, Max L

    2013-01-01

    An important step in a phospholipid membrane pore formation by melittin antimicrobial peptide is a reorientation of the peptide from a surface into a transmembrane conformation. In this work we perform umbrella sampling simulations to calculate the potential of mean force (PMF) for the reorientation of melittin from a surface-bound state to a transmembrane state and provide a molecular level insight into understanding peptide and lipid properties that influence the existence of the free energy barrier. The PMFs were calculated for a peptide to lipid (P/L) ratio of 1/128 and 4/128. We observe that the free energy barrier is reduced when the P/L ratio increased. In addition, we study the cooperative effect; specifically we investigate if the barrier is smaller for a second melittin reorientation, given that another neighboring melittin was already in the transmembrane state. We observe that indeed the barrier of the PMF curve is reduced in this case, thus confirming the presence of a cooperative effect.

  17. Is height a core geometric cue for navigation? Young children's use of height in reorientation.

    Science.gov (United States)

    Hu, Qingfen; Zhang, Jing; Wu, Di; Shao, Yi

    2015-02-01

    With respect to reorientation, children older than 1.5 to 2 years can use geometric cues (distance and left/right sense). However, because previous studies have focused mainly on the plane geometric properties, little is known about the role of information with respect to vertical dimension in children's reorientation. The current study aimed to examine whether and how 3- and 4-year-old children use height information to search for a hidden toy when disoriented in a small enclosure. In a slant-ceiling rectangular room and a slant-ceiling square room, 4-year-olds were able to use height information to reorient and search for the toy in the correct corner, whereas 3-year-olds were not able to do so. Our results suggest that children can, at least by the age of 4 years, use height information and that height is not used as early as other geometric properties that are in the core geometry system for navigation. Copyright © 2014 Elsevier Inc. All rights reserved.

  18. Hypergravity induces reorientation of cortical microtubules and modifies growth anisotropy in azuki bean epicotyls.

    Science.gov (United States)

    Soga, Kouichi; Wakabayashi, Kazuyuki; Kamisaka, Seiichiro; Hoson, Takayuki

    2006-11-01

    We examined the changes in the orientation of cortical microtubules during the hypergravity-induced modification of growth anisotropy (inhibition of elongation growth and promotion of lateral growth) in azuki bean (Vigna angularis Ohwi et Ohashi) epicotyls. The percentage of cells with transverse microtubules was decreased, while that with longitudinal microtubules was increased, in proportion to the logarithm of the magnitude of gravity. The percentage of cells with longitudinal microtubules showed an increase within 0.5 h of transfer of the 1g-grown seedlings to a 300g-hypergravity condition. Lanthanum and gadolinium, blockers of calcium channels, nullified the modification of growth anisotropy and reorientation of microtubules by hypergravity. Horizontal and acropetal hypergravity modified growth anisotropy and reorientation of microtubules, as did basipetal hypergravity, and these changes were not seen in the presence of lanthanum or gadolinium. These results suggest that hypergravity changes activities of lanthanum- and gadolinium-sensitive calcium channels independently of its direction, which may lead to reorientation of cortical microtubules and modification of growth anisotropy in azuki bean epicotyls.

  19. Stable panoramic views facilitate snap-shot like memories for spatial reorientation in homing pigeons.

    Directory of Open Access Journals (Sweden)

    Tommaso Pecchia

    Full Text Available Following spatial disorientation, animals can reorient themselves by relying on geometric cues (metric and sense specified both by the macroscopic surface layout of an enclosed space and prominent visual landmarks in arrays. Whether spatial reorientation in arrays of landmarks is based on explicit representation of the geometric cues is a matter of debate. Here we trained homing pigeons (Columba livia to locate a food-reward in a rectangular array of four identical or differently coloured pipes provided with four openings, only one of which allowed the birds to have access to the reward. Pigeons were trained either with a stable or a variable position of the opening on pipes, so that they could view the array either from the same or a variable perspective. Explicit mapping of configural geometry would predict successful reorientation irrespective of access condition. In contrast, we found that a stable view of the array facilitated spatial learning in homing pigeons, likely through the formation of snapshot-like memories.

  20. Neural mechanisms underlying pain's ability to reorient attention: evidence for sensitization of somatic threat detectors.

    Science.gov (United States)

    Dowman, Robert

    2014-06-01

    Pain typically signals damage to the body, and as such can be perceived as threatening and can elicit a strong emotional response. This ecological significance undoubtedly underlies pain's well-known ability to demand attention. However, the neural mechanisms underlying this ability are poorly understood. Previous work from the author's laboratory has reported behavioral evidence suggesting that participants disengage their attention from an incorrectly cued visual target stimulus and reorient it toward a somatic target more rapidly when the somatic target is painful than when it is nonpainful. Furthermore, electrophysiological data suggest that this effect is mediated by a stimulus-driven process, in which somatic threat detectors located in the dorsal posterior insula activate the medial and lateral prefrontal cortex areas involved in reorienting attention toward the painful target. In these previous studies, the painful and nonpainful somatic targets were given in separate experiments involving different participants. Here, the nonpainful and painful somatic targets were presented in random order within the same block of trials. Unlike in the previous studies, both the nonpainful and painful somatic targets activated the somatic threat detectors, and the times taken to disengage and reorient attention were the same for both. These electrophysiological and behavioral data suggest that somatic threat detectors can become sensitized to nonpainful somatic stimuli that are presented in a context that includes painful stimuli.

  1. Reorientation dynamics of nematics encapsulated in microscopic volumes in a strong electric field

    Science.gov (United States)

    Zakharov, A. V.; Vakulenko, A. A.; Pasechnik, S. V.

    2016-09-01

    We theoretically describe a new regime of reorientation of the director field widehat n and velocity v of a nematic liquid crystal (LC) encapsulated in a rectangular cell under the action of strong electric field E directed at angle α ( π/2) to the horizontal surfaces bounding the LC cell. The numerical calculations in the framework of nonlinear generalization of the classical Eriksen-Leslie theory showed that at certain relations between the torques and momenta affecting the unit LC volume and E ≫ E th, transition periodic structures can arise during reorientation of widehat n, if the corresponding distortion mode has the fastest response and, thus, suppresses all the rest of the modes, including uniform ones. The position of sites of these periodic structures is affected by the value of field E, angle α, and the character of anchoring of LC molecules to the bounding surfaces. The calculations performed for the nematic formed by 4-n-penthyl-4'-cyanobiphenyl showed that several vortexes can form in an LC cell under the action of reorientation of the nematic field; the boundaries of these vortexes are determined by the positions of periodic structure sites.

  2. Proline Based Chiral Ionic Liquids for Enantioselective Michael Reaction

    Directory of Open Access Journals (Sweden)

    Kaoru Nobuoka

    2014-01-01

    Full Text Available Chiral ionic liquids, starting from (S-proline, have been prepared and evaluated the ability of a chiral catalyst. In Michael reaction of trans-β-nitrostyrene and cyclohexanone, all the reactions were carried out under homogeneous conditions without any solvent except for excess cyclohexanone. The chiral ionic liquid catalyst with the positive charge delocalized bulky pyrrolidinium cation shows excellent yields (up to 92%, diastereoselectivities (syn/anti = 96/4, and enantioselectivities (up to 95% ee and could be reused at least three times without any loss of its catalytic activity. Such results demonstrated a promising new approach for green and economic chiral synthesis by using the chiral ionic liquids as a chiral catalyst and a chiral medium.

  3. Profiles in medical courage: Michael Wilkins and the Willowbrook School

    Directory of Open Access Journals (Sweden)

    Robbins RA

    2012-03-01

    Full Text Available No abstract available. Article truncated at 150 words. “Never doubt that a small group of thoughtful, committed citizens can change the world. Indeed, it is the only thing that ever has. "- Margaret Mead With this article we begin an intermittent series on physicians who displayed courage in trying to help their patients. Although there are many examples, hopefully what will be illustrated are examples of the lesser known doctors who identified problems and stood up to address them. Few remember the controversy surrounding the now closed Willowbrook School and Dr. Michael Wilkins’ involvement. However, Wilkins’ courage in advocating for change not only resulted in substantial improvement in conditions at the school but also led to the Civil Rights of Institutionalized Persons Act (CRIPA of 1980.Wilkins was originally from Kansas City and graduated from the University of Missouri School of Medicine in 1967 (1. He left Missouri to do his pediatric internship and complete his military obligation…

  4. Solvent-free Michael addition reaction of fluorene with chalcon

    Institute of Scientific and Technical Information of China (English)

    Fu Feng

    2011-01-01

    A series of novel Michael addition products of fluorene to chalcone were obtained in the presence of sodium hydroxide under solvent-free condition. The advantages of this procedure were mild reaction conditions, simple protocol, and high yields. The structures of the products were characterized by IR, 1H NMR, MS and X-ray diffraction. The crystal of the new compound 3 h is y= 64.2440(10)°, V = 2.4137(3) nm3, Z= 4, Dc=1.220 g/cm3, μ = 0.286 mm-1, F(000) = 920, R = 0.0656 and wR = 0.1554 for 5664 observed reflection with I > 2σ(I).

  5. Michael Longley’s Father: Memory, Mourning and History

    Directory of Open Access Journals (Sweden)

    Barry Sloan

    2012-03-01

    Full Text Available Michael Longley’s father has been a recurring presence in the poet’s work from his earliest to his most recent collection. This paper examines the exceptional strength of that bond reflected in the varied and changing ways in which the poet has responded to it – memorizing and mourning his loss; discovering through his father’s First World War stories a means of memorialising loss of life in contemporary conflicts and a way of facing the history of the twentieth century; confronting his own ageing and sense of mortality; and marking the specific, but also representative, generational history of his family. Close readings of key poems are offered to highlight Longley’s skills in meeting his own exacting standards of aesthetic propriety and moral and social responsibility for writers of elegy in order to avoid either exploitation of tragedy and loss, or facile gestures of consolation.

  6. Michael Tenzer, ed., Analytical Studies in World Music

    OpenAIRE

    Martin,Denis-Constant

    2007-01-01

    Pour Michael Tenzer, professeur de musique à l’Université de Colombie britannique et spécialiste (analyste et interprète) de musique pour gamelan, la réunion des textes proposés dans cet ouvrage a deux objectifs : construire une théorie de la musique dans le monde qui s’émancipe des oppositions entre musiques « classiques » et « populaires », « occidentales » et « non occidentales », c’est-à-dire jeter les bases d’une théorie générale de la musique et, pour ce faire, montrer que l’analyse mus...

  7. A Study of Postmodern Narrative in Michael Cunningham's The Hours

    Directory of Open Access Journals (Sweden)

    Hajar Abbasi Narinabad

    2012-09-01

    Full Text Available This project aims at providing a detailed analysis of the major features of the theory of postmodern narrative and at going through the novel The Hours by the American writer Michael Cunningham concentrating on some postmodern narrative techniques. To do so, the researcher goes through the theories set forth by some postmodern theoreticians like Roland Barthes, Jacque Derrida, Jean-François Lyotard and Julia Kristeva to investigate the postmodern narrative techniques and elements used in the novel. The researcher first examines the theories and then critically applies them on the novel. The article goes through the most eminent elements of postmodern narrative including intertextuality, stream of consciousness style, fragmentation and representation respectively which are delicately utilized in The Hours. The article concludes by recommending a few directions for the further research.

  8. A new biomarker to examine the role of hippocampal function in the development of spatial reorientation in children: a review

    OpenAIRE

    Vanessa eVieites; Alina eNazareth; Reeb-Sutherland, Bethany C.; Shannon M Pruden

    2015-01-01

    Spatial navigation is an adaptive skill that involves determining the route to a particular goal or location, and then travelling that path. A major component of spatial navigation is spatial reorientation, or the ability to reestablish a sense of direction after being disoriented. The hippocampus is known to be critical for navigating, and has more recently been implicated in reorienting in adults, but relatively little is known about the development of the hippocampus in relation to these l...

  9. Arousal and attention re-orienting in autism spectrum disorders: evidence from auditory event-related potentials

    OpenAIRE

    2014-01-01

    The extended phenotype of autism spectrum disorders (ASD) includes a combination of arousal regulation problems, sensory modulation difficulties, and attention re-orienting deficit. A slow and inefficient re-orienting to stimuli that appear outside of the attended sensory stream is thought to be especially detrimental for social functioning. Event-related potentials (ERPs) and magnetic fields (ERFs) may help to reveal which processing stages underlying brain response to unattended but salient...

  10. Arousal and attention re-orienting in autism spectrum disorders: evidence from auditory event-related potentials

    OpenAIRE

    2014-01-01

    The extended phenotype of autism spectrum disorders (ASD) includes a combination of arousal regulation problems, sensory modulation difficulties, and attention re-orienting deficit. A slow and inefficient re-orienting to stimuli that appear outside of the attended sensory stream is thought to be especially detrimental for social functioning. Event-related potentials (ERPs) and magnetic fields (ERFs) may help to reveal which processing stages underlying brain response to unattended but salien...

  11. Asymmetric synthesis of functionalized cyclohexanes bearing five stereocenters via a one-pot organocatalytic Michael-Michael-1,2-addition sequence.

    Science.gov (United States)

    Chauhan, Pankaj; Urbanietz, Gregor; Raabe, Gerhard; Enders, Dieter

    2014-07-04

    A highly stereoselective one-pot procedure involving an enantioselective Michael addition promoted by low loading of an amino-squaramide catalyst followed by an achiral base catalyzed domino Michael-Knoevenagel-type 1,2-addition sequence provides efficient access to fully substituted cyclohexanes bearing five contiguous stereogenic centers in good yields (68-86%) and excellent stereoselectivities (>30 : 1 dr and 96-99% ee).

  12. Estratégia competitiva: Michael Porter 30 anos depois

    Directory of Open Access Journals (Sweden)

    Manuel Portugal Ferreira

    2009-12-01

    Full Text Available Os estudos de estratégia têm sido muito influenciados pelos trabalhos de Michael Porter, em todas as suas fases, como as cinco forças, as estratégias genéricas, a cadeia de valor e as vantagens competitivas das nações. Neste artigo, analisou-se a influência de Porter nos trabalhos brasileiros em estratégia, a partir dos trabalhos selecionados e apresentados no EnANPAD. No levantamento para a análise dos artigos, considerando 10 anos de EnANPAD (1997-2006, foram selecionados 46 artigos. A identificação e seleção dos artigos envolveram os seguintes critérios: busca complementar por palavra-chave Porter na base de dados do EnANPAD; avaliação dos títulos e resumos dos artigos apresentados na área de estratégia entre 1997 e 2006, bem como na íntegra quando necessário. Procedeu-se também à análise das referências utilizadas nos artigos e o posicionamento dos autores em relação às tipologias de Porter. Como resultado, verificou-se que Michael Porter é um autor com grande influência nas pesquisas acadêmicas de estratégia. Seus estudos mais utilizados são os da análise da indústria e das estratégias genéricas, e também se verificou que a maioria dos estudos analisados é favorável aos seus conceitos, mesmo existindo pesquisas contrárias.

  13. Domino Mukaiyama-Michael reactions in the synthesis of polycyclic systems

    NARCIS (Netherlands)

    Sarabèr, F.C.E.; Dratch, S.; Bosselaar, G.; Jansen, B.J.M.; Groot, de Æ.

    2006-01-01

    Good results were obtained in the Mukaiyama-Michael reaction of the silyl enol ether of cyclohexanone with 2-methyl-2cyclopentenone and carvone, with transfer of the silyl group to the receiving enone and with TrSbCl6 as catalyst. A second Mukaiyama-Michael reaction of this new silyl enol ether with

  14. Asymmetric Michael Reaction of Malononitrile Catalyzed by Chiral Ru(Ⅱ) Complex and Achiral Base

    Institute of Scientific and Technical Information of China (English)

    MA Ya-Ping; XING Zhi-Kui; ZHU Jin; CUI Xin; CUN Lin-Feng; DENG Jin-Gen

    2003-01-01

    @@ Michael addition reactions represent one of the most important carbon-carbon bond forming reactions in modern synthetic organic chemistry. [1 ~3] We achieved catalytic enantioselective Michael addition reactions of malononitrile with chiral vicinal diamine-Ru(Ⅱ) complex in the presence of achiral base. High yields and moderate ee were observed.

  15. 75 FR 22436 - Michael Williams-Control Exemption-St. Maries River Railroad, Inc.

    Science.gov (United States)

    2010-04-28

    ... Surface Transportation Board Michael Williams-Control Exemption-St. Maries River Railroad, Inc. Michael Williams (applicant),\\1\\ a noncarrier, has filed a verified notice of exemption to acquire control of St... from STMA's parent, Potlatch Land & Lumber, LLC, by Williams Group, Inc. (WG).\\2\\ Applicant...

  16. Domino Mukaiyama-Michael reactions in the synthesis of polycyclic systems

    NARCIS (Netherlands)

    Sarabèr, F.C.E.; Dratch, S.; Bosselaar, G.; Jansen, B.J.M.; Groot, de Æ.

    2006-01-01

    Good results were obtained in the Mukaiyama-Michael reaction of the silyl enol ether of cyclohexanone with 2-methyl-2cyclopentenone and carvone, with transfer of the silyl group to the receiving enone and with TrSbCl6 as catalyst. A second Mukaiyama-Michael reaction of this new silyl enol ether with

  17. A Response to Michael Newman's "Calling Transformative Learning into Question: Some Mutinous Thoughts"

    Science.gov (United States)

    Cranton, Patricia; Kasl, Elizabeth

    2012-01-01

    This article presents the authors' response to Michael Newman's "Calling Transformative Learning into Question: Some Mutinous Thoughts". The authors begin by noting their appreciation of Michael Newman's challenge to transformative learning theory. In their response, the authors review and comment on the fatal flaws presented by Newman and then…

  18. Markets, Marx, Modernity and Mathematics Education: A Response to Michael Apple.

    Science.gov (United States)

    Gates, Peter

    This paper is a response to Michael Apple's paper, "What Postmodernists Forget: Cultural Capital and Official Knowledge." The paper advocates Michael's identification of the current dangers and processes of the growth of new right ideologies in the development of subjectivity, society, and education. The differences in success in the education…

  19. Navigation as a Source of Geometric Knowledge: Young Children's Use of Length, Angle, Distance, and Direction in a Reorientation Task

    Science.gov (United States)

    Lee, Sang Ah; Sovrano, Valeria A.; Spelke, Elizabeth S.

    2012-01-01

    Geometry is one of the highest achievements of our species, but its foundations are obscure. Consistent with longstanding suggestions that geometrical knowledge is rooted in processes guiding navigation, the present study examines potential sources of geometrical knowledge in the navigation processes by which young children establish their sense…

  20. A numerical method for reorientation of rotating tidally deformed viscoelastic bodies

    Science.gov (United States)

    Hu, H.; Wal, W.; Vermeersen, L. L. A.

    2017-01-01

    Existing approaches for simulating the true polar wander (TPW) of a viscoelastic body can be divided into three categories: (i) a linear dynamic approach which uses the linearized Liouville equation (e.g., Wu and Peltier (1984) and Mitrovica et al. (2005)); (ii) a nonlinear dynamic approach which is based on the quasi-fluid approximation (e.g., Sabadini and Peltier (1981), Ricard et al. (1993), and Cambiotti et al. (2011)); and (iii) a long-term limit approach which only considers the fluid limit of a reorientation (e.g., Matsuyama and Nimmo (2007)). Several limitations of these approaches have not been studied: the range for which the linear approach is accurate, the validity of the quasi-fluid approximation, and the dynamic solution for TPW of a tidally deformed rotating body. We establish a numerical procedure which is able to determine the large-angle reorientation of a viscoelastic celestial body that can be both centrifugally and tidally deformed. We show that the linear approach leads to significant errors for loadings near the poles or the equator. Second, we show that slow relaxation modes can have a significant effect on large-angle TPW of Earth or other planets. Finally, we show that reorientation of a tidally deformed body driven by a positive mass anomaly near the poles has a preference for rotating around the tidal axis instead of toward it. At a tidally deformed body which does not have a remnant bulge, positive mass anomalies are more likely to be found near the equator and the plane perpendicular to the tidal axis, while negative mass anomalies tend to be near the great circle that contains the tidal and rotational axes.

  1. Reorientation of Magnetic Graphene Oxide Nanosheets in Crosslinked Quaternized Polyvinyl Alcohol as Effective Solid Electrolyte

    Directory of Open Access Journals (Sweden)

    Jia-Shuin Lin

    2016-11-01

    Full Text Available This work aims to clarify the effect of magnetic graphene oxide (GO reorientation in a polymer matrix on the ionic conduction and methanol barrier properties of nanocomposite membrane electrolytes. Magnetic iron oxide (Fe3O4 nanoparticles were prepared and dispersed on GO nanosheets (GO-Fe3O4. The magnetic GO-Fe3O4 was imbedded into a quaternized polyvinyl alcohol (QPVA matrix and crosslinked (CL- with glutaraldehyde (GA to obtain a polymeric nanocomposite. A magnetic field was applied in the through-plane direction during the drying and film formation steps. The CL-QPVA/GO-Fe3O4 nanocomposite membranes were doped with an alkali to obtain hydroxide-conducting electrolytes for direct methanol alkaline fuel cell (DMAFC applications. The magnetic field-reoriented CL-QPVA/GO-Fe3O4 electrolyte demonstrated higher conductivity and lower methanol permeability than the unoriented CL-QPVA/GO-Fe3O4 membrane or the CL-QPVA film. The reoriented CL-QPVA/GO-Fe3O4 nanocomposite was used as the electrolyte in a DMAFC and resulted in a maximum power density of 55.4 mW·cm−2 at 60 °C, which is 73.7% higher than that of the composite without the magnetic field treatment (31.9 mW·cm−2. In contrast, the DMAFC using the CL-QPVA electrolyte generated only 22.4 mW·cm−2. This research proved the surprising benefits of magnetic-field-assisted orientation of GO-Fe3O4 in facilitating the ion conduction of a polymeric electrolyte.

  2. Environment size and the use of feature and geometric cues for reorientation.

    Science.gov (United States)

    Sturz, Bradley R; Kelly, Debbie M

    2013-02-01

    We tested associative-based accounts of orientation by investigating the influence of environment size on the use of feature and geometric cues for reorientation. Two groups of participants were trained in dynamic three-dimensional virtual rectangular environments that differed in size to find a distinctly colored bin located at one of the four corners. Subsequently, we probed the reliance on feature and geometric cues for reorientation during test trials by presenting six trial types: Small Geometry Only, Large Geometry Only, Small Cue Conflict, Large Cue Conflict, Small Distal, and Large Distal. During Geometry Only test trials, all bins were black; thus, all distinctive featural information was removed leaving only geometric cues. For Cue Conflict test trials, all colored bins were shifted counter-clockwise one corner; thus, the geometric cues from the trained corner and the trained color were in direct conflict. During Distal test trials, the bin in the geometrically incorrect corner farthest from the trained corner was colored the same as during training; the remaining three bins were black. Thus, only this distant feature cue could be used to determine the location of the goal bin. Results suggested that geometric cues were used across changes in environment size, featural cues exerted greater influence when in conflict with geometric cues, and the far featural cue was used to disambiguate the correct from the rotationally equivalent location. In short, both feature and geometric cues were used for reorientation, and environment size influenced the relative use of feature and geometric cues. Collectively, our results provide evidence against associative-based accounts of orientation. Copyright © 2012 Elsevier B.V. All rights reserved.

  3. Reorientation and faulting of Pluto due to volatile loading within Sputnik Planitia

    Science.gov (United States)

    Keane, James T.; Matsuyama, Isamu; Kamata, Shunichi; Steckloff, Jordan K.

    2016-12-01

    Pluto is an astoundingly diverse, geologically dynamic world. The dominant feature is Sputnik Planitia—a tear-drop-shaped topographic depression approximately 1,000 kilometres in diameter possibly representing an ancient impact basin. The interior of Sputnik Planitia is characterized by a smooth, craterless plain three to four kilometres beneath the surrounding rugged uplands, and represents the surface of a massive unit of actively convecting volatile ices (N2, CH4 and CO) several kilometres thick. This large feature is very near the Pluto-Charon tidal axis. Here we report that the location of Sputnik Planitia is the natural consequence of the sequestration of volatile ices within the basin and the resulting reorientation (true polar wander) of Pluto. Loading of volatile ices within a basin the size of Sputnik Planitia can substantially alter Pluto’s inertia tensor, resulting in a reorientation of the dwarf planet of around 60 degrees with respect to the rotational and tidal axes. The combination of this reorientation, loading and global expansion due to the freezing of a possible subsurface ocean generates stresses within the planet’s lithosphere, resulting in a global network of extensional faults that closely replicate the observed fault networks on Pluto. Sputnik Planitia probably formed northwest of its present location, and was loaded with volatiles over million-year timescales as a result of volatile transport cycles on Pluto. Pluto’s past, present and future orientation is controlled by feedbacks between volatile sublimation and condensation, changing insolation conditions and Pluto’s interior structure.

  4. Spatial reorientation experiments for NMR of solids and partially oriented liquids.

    Science.gov (United States)

    Martin, Rachel W; Kelly, John E; Collier, Kelsey A

    2015-11-01

    Motional reorientation experiments are extensions of Magic Angle Spinning (MAS) where the rotor axis is changed in order to average out, reintroduce, or scale anisotropic interactions (e.g. dipolar couplings, quadrupolar interactions or chemical shift anisotropies). This review focuses on Variable Angle Spinning (VAS), Switched Angle Spinning (SAS), and Dynamic Angle Spinning (DAS), all of which involve spinning at two or more different angles sequentially, either in successive experiments or during a multidimensional experiment. In all of these experiments, anisotropic terms in the Hamiltonian are scaled by changing the orientation of the spinning sample relative to the static magnetic field. These experiments vary in experimental complexity and instrumentation requirements. In VAS, many one-dimensional spectra are collected as a function of spinning angle. In SAS, dipolar couplings and/or chemical shift anisotropies are reintroduced by switching the sample between two different angles, often 0° or 90° and the magic angle, yielding a two-dimensional isotropic-anisotropic correlation spectrum. Dynamic Angle Spinning (DAS) is a related experiment that is used to simultaneously average out the first- and second-order quadrupolar interactions, which cannot be accomplished by spinning at any unique rotor angle in physical space. Although motional reorientation experiments generally require specialized instrumentation and data analysis schemes, some are accessible with only minor modification of standard MAS probes. In this review, the mechanics of each type of experiment are described, with representative examples. Current and historical probe and coil designs are discussed from the standpoint of how each one accomplishes the particular objectives of the experiment(s) it was designed to perform. Finally, applications to inorganic materials and liquid crystals, which present very different experimental challenges, are discussed. The review concludes with perspectives

  5. 77 FR 30047 - Notice of Opportunity for Public Comment on Surplus Property Release at Michael J Smith Field...

    Science.gov (United States)

    2012-05-21

    ... Michael J Smith Field, Beaufort, NC AGENCY: Federal Aviation Administration (FAA), DOT. ACTION: Notice... approximately 7.5 acres of airport property, located at the Michael J Smith Field, be used for aeronautical... Authority to release approximately 7.5 acres of airport property at the Michael J Smith Field. The...

  6. 75 FR 62635 - Proposed Information Collection (Patient Satisfaction Survey Michael E. DeBakey Home Care Program...

    Science.gov (United States)

    2010-10-12

    ... AFFAIRS Proposed Information Collection (Patient Satisfaction Survey Michael E. DeBakey Home Care Program... needed to determine patients' satisfaction with services provided by or through the Michael E. DeBakey.... Title: Patient Satisfaction Survey Michael E. DeBakey Home Care Program, VA Form 10-0476. OMB...

  7. Slosh wave excitation due to cryogenic liquid reorientation in space-based propulsion system

    Science.gov (United States)

    Hung, R. J.; Shyu, K. L.; Lee, C. C.

    1991-01-01

    The objective of the cryogenic fluid management of the spacecraft propulsion system is to develop the technology necessary for acquistion or positioning of liquid and vapor within a tank in reduced gravity to enable liquid outflow or vapor venting. In this study slosh wave excitation induced by the resettling flow field activated by 1.0 Hz medium frequency impulsive reverse gravity acceleration during the course of liquid fluid reorientation with the initiation of geyser for liquid filled levels of 30, 50, and 80 percent have been studied. Characteristics of slosh waves with various frequencies excited are discussed.

  8. Reaction and reorientation of electronically excited H{sub 2}(B)

    Energy Technology Data Exchange (ETDEWEB)

    Pibel, C.D.

    1992-09-01

    The room temperature rate (TR) constants for fluorescence quenching fluorescence of H{sub 2}, HD, and D{sub 2} B {sup 1}{Sigma}{sub u}{sup +} by {sup 4}He were measured as a function of the initially excited rotational and vibrational level of the hydrogen molecule, and the RT rate constants for molecular angular momentum reorientation of H{sub 2}, HD and D{sub 2} (B {sup 1}{Sigma}{sub u}{sup +}. v{prime}=0, J{prime}=1, M{sub J}=0) in collisions with He, Ne, Ar and H{sub 2}(X {sup 1}{Sigma}{sub g}{sup +}) were also measured. Vibrational state dependence of the quenching cross sections fits a vibrationally adiabatic model of the quenching process. From the vibrational state dependence of the quenching cross section, the barrier height for the quenching reaction is found to be 250{plus_minus}40 cm{sup {minus}1}, and the difference in the H-H stretching frequencies between H{sub 2}(B) and the H{sub 2}-He complex at the barrier to reaction is 140{plus_minus}80 cm{sup {minus}1}. The effective cross sections for angular momentum reorientation in collisions of H{sub 2}, HD, D{sub 2} with He and Ne were found to be about 30 {Angstrom}{sup 2} and were nearly the same for each isotope and with He and Ne as collision partners. Cross sections forreorientation of HD and D{sub 2} in collisions with Ar were 10.6{plus_minus}2.0 and 13.9{plus_minus}3.0 {Angstrom}{sup 2}, respectively. Reorientation of D{sub 2}(B) in collisions with room temperature H{sub 2}(X) occurs with a 7.6{plus_minus}3.4 {Angstrom}{sup 2} cross section. Calculated cross sections using semiclassical and quantum close coupled methods give cross sections for reorientation of H{sub 2}(B) and D{sub 2}(B) in collisions with He that agree quantitatively with experiment. Discrepancy between the calculated and experimental cross sections for HD(B)-HE are likely due to rotational relaxation in HD a Turbo PASCAL version of the data-taking program is included.

  9. Reaction and reorientation of electronically excited H[sub 2](B)

    Energy Technology Data Exchange (ETDEWEB)

    Pibel, C.D.

    1992-09-01

    The room temperature rate (TR) constants for fluorescence quenching fluorescence of H[sub 2], HD, and D[sub 2] B [sup 1][Sigma][sub u][sup +] by [sup 4]He were measured as a function of the initially excited rotational and vibrational level of the hydrogen molecule, and the RT rate constants for molecular angular momentum reorientation of H[sub 2], HD and D[sub 2] (B [sup 1][Sigma][sub u][sup +]. v[prime]=0, J[prime]=1, M[sub J]=0) in collisions with He, Ne, Ar and H[sub 2](X [sup 1][Sigma][sub g][sup +]) were also measured. Vibrational state dependence of the quenching cross sections fits a vibrationally adiabatic model of the quenching process. From the vibrational state dependence of the quenching cross section, the barrier height for the quenching reaction is found to be 250[plus minus]40 cm[sup [minus]1], and the difference in the H-H stretching frequencies between H[sub 2](B) and the H[sub 2]-He complex at the barrier to reaction is 140[plus minus]80 cm[sup [minus]1]. The effective cross sections for angular momentum reorientation in collisions of H[sub 2], HD, D[sub 2] with He and Ne were found to be about 30 [Angstrom][sup 2] and were nearly the same for each isotope and with He and Ne as collision partners. Cross sections forreorientation of HD and D[sub 2] in collisions with Ar were 10.6[plus minus]2.0 and 13.9[plus minus]3.0 [Angstrom][sup 2], respectively. Reorientation of D[sub 2](B) in collisions with room temperature H[sub 2](X) occurs with a 7.6[plus minus]3.4 [Angstrom][sup 2] cross section. Calculated cross sections using semiclassical and quantum close coupled methods give cross sections for reorientation of H[sub 2](B) and D[sub 2](B) in collisions with He that agree quantitatively with experiment. Discrepancy between the calculated and experimental cross sections for HD(B)-HE are likely due to rotational relaxation in HD a Turbo PASCAL version of the data-taking program is included.

  10. Dynamic Isovector Reorientation of Deuteron as a Probe to Nuclear Symmetry Energy.

    Science.gov (United States)

    Ou, Li; Xiao, Zhigang; Yi, Han; Wang, Ning; Liu, Min; Tian, Junlong

    2015-11-20

    We present the calculations on a novel reorientation effect of deuteron attributed to isovector interaction in the nuclear field of heavy target nuclei. The correlation angle determined by the relative momentum vector of the proton and the neutron originating from the breakup deuteron, which is experimentally detectable, exhibits significant dependence on the isovector nuclear potential but is robust against the variation of the isoscaler sector. In terms of sensitivity and cleanness, the breakup reactions induced by the polarized deuteron beam at about 100 MeV/u provide a more stringent constraint to the symmetry energy at subsaturation densities.

  11. Influence of family, religion, and social conformity on client participation in sexual reorientation therapy.

    Science.gov (United States)

    Maccio, Elaine M

    2010-01-01

    This study examined the likelihood of participating in sexual reorientation therapy (SRT) based on actual or expected family reactions to the disclosure of one's same-sex sexuality, religious fundamentalism, social conformity, and several demographic variables. A sample of 52 SRT participants and 211 SRT nonparticipants who had ever identified as gay, lesbian, or bisexual completed a survey either online or in hardcopy format. Actual or expected negative family reactions, high religious fundamentalism, and identifying as spiritual significantly increased one's odds of participating in SRT. The findings are essential for preparing practitioners in any clinical practice setting to work with clients struggling with their sexuality.

  12. Nd-induced Mn spin-reorientation transition in NdMnAsO

    OpenAIRE

    Marcinkova, A.; Hansen, T.C.; Curfs, C.; Margadonna, S.; Bos, J. -W. G.

    2010-01-01

    A combination of synchrotron x-ray, neutron powder-diffraction, magnetization, heat-capacity, and electrical-resistivity measurements reveals that NdMnAsO is an antiferromagnetic semiconductor with large Neel temperature [T-N=359(2) K]. At room temperature the magnetic propagation vector k=0 and the Mn moments are directed along the crystallographic c axis [m(Mn)=2.41(6) mu(B)]. Upon cooling a spin-reorientation (SR) transition of the Mn moments into the ab plane occurs (T-SR=23 K). This coin...

  13. Periodic structures induced by director reorientation in the lyotropic nematic phase of disodium cromoglycate-water

    Science.gov (United States)

    Hui, Y. W.; Kuzma, M. R.; San Miguel, M.; Labes, M. M.

    1985-07-01

    A nonequilibrium periodic structure is induced by a magnetic field H applied to an aligned lyotropic uniaxial nematic phase of disodium cromoglycate-water. A series of parallel lines perpendicular to H represents boundaries between 180° out-of-phase regions of director reorientation. The distance between the lines decreases with increasing H. The line spacing is also directly proportional to thickness of the sample (in a limited range of thickness), and a secondary periodicity, consisting of nodes in these lines, is observed in thicker samples. An extension of a theoretical model by Guyon et al. is used to qualitatively interpret the abovementioned dependencies.

  14. A Musical Italy: Michael W. Balfe’s Italian Experiences

    Directory of Open Access Journals (Sweden)

    Basil Walsh

    2016-06-01

    Full Text Available The Dublin-born musician, Michael W. Balfe, was a singer, composerand conductor whose brilliant musical career was heavily influenced byformative experiences in Italy. In 1825, Balfe, interested in broadeninghis musical studies first went to Paris where he was introduced to thegreat composers, Luigi Cherubini and Gioachino Rossini, who took apersonal interest in him and his musical talents. On the advice of Rossinihe spent the next few years in Italy studying singing with the famousRossini singer, Filippo Galli, and taking music composition lessonsfrom Ferdinando Paer, in Rome. Later in Milan he studied harmonyand counterpoint with Vincenzo Federici. By 1831, when he was only23 years old, his first three operas had been produced in Palermo, Pavia,and Milan. He returned to London in August 1835, participatingwith the great Lablache, Tamburini, Rubini and Grisi in a concert inVauxhall Gardens. In 1834 he made his debut at La Scala, Milan, singingopposite the renowned mezzo-soprano, Maria Malibran in Rossini’sOtello. He appeared again with Malibran in Venice early in 1835,singing once more in Rossini and Bellini operas. Balfe worked as a singerand composer throughout the Italian peninsula/states during the years,1825-1835 and this article will chart these experiences and demonstratehow the time he spent in Italy and the people he met, influenced hislife and later career as an important and popular European composer.

  15. El fetiche etnográfico de Michael Taussig

    Directory of Open Access Journals (Sweden)

    Matthew Carlin

    2014-01-01

    Full Text Available El antropólogo Michael Taussig ha producido una gran cantidad de trabajo etnográfico sobre América Latina en el que toma por objeto la universalidad de la cultura burguesa y en el que, al reorientar la mirada del etnógrafo hacia los elementos embriagantes y orgiásticos de la vida, atenúa las líneas que dividen ciencia y arte. En este ensayo tengo la intención de mostrar lo siguiente: 1 que sus etnografías sobre magia, violencia y el Es-tado, están enraizadas en su priorización del mundo fenomenológico y en una concepción materialista en deuda con la teoría estética alemana del si-glo XIX y con la antropología especulativa de Karl Marx y Walter Benjamin; 2 que su proyecto etnográfico no consiste en la eliminación de la ciencia del ámbito de la etnografía, sino en disminuir el papel de la explicación en favor de una forma de escritura que, como el arte, trabaja para refundar las imágenes del mundo.

  16. Michael Field’s “A Dance of Death”

    Directory of Open Access Journals (Sweden)

    LeeAnne Richardson

    2012-03-01

    Full Text Available The 1912 poem "A Dance of Death" by Michael Field (pen name of Katherine Bradley and her niece Edith Cooper depicts Salome in an alternate version of the biblical story: this Salome dances on a frozen river, falls through the ice, and is decapitated on a jagged edge. Nonetheless, her beautiful head continues dancing over the frozen river. This poem is highly unusual, especially in the context of the other poems in the postconversion volume Poems of Adoration, because it questions, rather than submits to, authority. In re-writing a familiar Christian tale, as well as a familiar decadent theme, Field uses the poem to assert the supremacy of their artistic vision, which (despite their ardent Catholicism cannot be subject to any law outside themselves. Like the continually dancing head of Salome, which continues to create beauty even after nature (and perhaps God has struck it down, the poet is subjugate only to her own law and creates without boundaries or restrictions on her art. Bradley and Cooper were acutely aware of their authorial persona (actively taking not only a masculine but also a singular poetic identity, and their mode of reconciling the apparent contradictions of this identity are mirrored in their presentation of Salome in a "Dance of Death."

  17. Subjetividade e defesa na obra de Michael Balint

    Directory of Open Access Journals (Sweden)

    Renata Mello

    2008-01-01

    Full Text Available Currently we can observe the diffusion of the so-called tough patients in psychoanalytic clinic. These patients have proven resistant to the classic psychoanalysis technique, leading to the necessity of relying on their psychic dynamics, aiming at a broader understanding of what is at stake in these cases. It can be observed that the subjectivation process relates to a precocious traumatic experience that touches the relation of the individual with what is external to him. Because of the overwhelming intensity provoked by the trauma, elementary protection measures are mobilized in order to prevent a narcissistic collapse. The defense then becomes the preferred way through which psychism constitutes itself, which translates into a meaningful impoverishment of subjective life. In an attempt to understand this dynamic and propose a direction for the psychic treatment, we will resort to Michael Balint¿s ideas about primary object relations, as his thinking offers important elements for a renewal of the understanding of both the analytical practice and the very psychic dynamic we currently see. In regards to Balint¿s ideas, we will hold on to his primary love theory and to the question of the modalities of defensive links - ocnophilia and philobatism - given the lack of loving of the primordial objects, ideas that can provide subsidies to deal with these tough patients.

  18. A three-dimensional model of magneto-mechanical behaviors of martensite reorientation in ferromagnetic shape memory alloys

    Science.gov (United States)

    Chen, Xue; Moumni, Ziad; He, Yongjun; Zhang, Weihong

    2014-03-01

    The large strain in Ferromagnetic Shape Memory Alloys (FSMA) is due to the martensite reorientation driven by mechanical stresses and/or magnetic fields. Although most experiments studying the martensite reorientation in FSMA are under 1D condition (uniaxial stress plus a perpendicular magnetic field), it has been shown that the 2D/3D configurations can improve the working stress and give much flexibility of the material's applications [He, Y.J., Chen, X., Moumni, Z., 2011. Two-dimensional analysis to improve the output stress in ferromagnetic shape memory alloys. Journal of Applied Physics 110, 063905]. To predict the material's behaviors in 3D loading conditions, a constitutive model is developed in this paper, based on the thermodynamics of irreversible processes with internal variables. All the martensite variants are considered in the model and the temperature effect is also taken into account. The model is able to describe all the behaviors of martensite reorientation in FSMA observed in the existing experiments: rotating/non-rotating magnetic-field-induced martensite reorientation, magnetic-field-assisted super-elasticity, super-elasticity under biaxial compressions and temperature-dependence of martensite reorientation. The model is further used to study the nonlinear bending behaviors of FSMA beams and provides some basic guidelines for designing the FSMA-based bending actuators.

  19. Low speed maneuvering flight of the rose-breasted cockatoo (Eolophus roseicapillus). II. Inertial and aerodynamic reorientation.

    Science.gov (United States)

    Hedrick, T L; Usherwood, J R; Biewener, A A

    2007-06-01

    The reconfigurable, flapping wings of birds allow for both inertial and aerodynamic modes of reorientation. We found evidence that both these modes play important roles in the low speed turning flight of the rose-breasted cockatoo Eolophus roseicapillus. Using three-dimensional kinematics recorded from six cockatoos making a 90 degrees turn in a flight corridor, we developed predictions of inertial and aerodynamic reorientation from estimates of wing moments of inertia and flapping arcs, and a blade-element aerodynamic model. The blade-element model successfully predicted weight support (predicted was 88+/-17% of observed, N=6) and centripetal force (predicted was 79+/-29% of observed, N=6) for the maneuvering cockatoos and provided a reasonable estimate of mechanical power. The estimated torque from the model was a significant predictor of roll acceleration (r(2)=0.55, Pflight dynamics (approximately -0.45), were required to bring our estimates of reorientation due to aerodynamic torque back into conjunction with the measured changes in orientation. Our estimates of inertial reorientation were statistically significant predictors of the measured reorientation within wingbeats (r(2) from 0.2 to 0.37, Pflight muscles: the pectoralis, supracoracoideus, biceps brachii and extensor metacarpi radialis (r(2) from 0.27 to 0.45, Pflight maneuvers rely on production of asymmetries throughout the flight apparatus rather than in a specific set of control or turning muscles.

  20. Nuclear magnetic resonance studies of atomic motion in borohydride-based materials: Fast anion reorientations and cation diffusion

    Energy Technology Data Exchange (ETDEWEB)

    Skripov, A.V., E-mail: skripov@imp.uran.ru; Soloninin, A.V.; Babanova, O.A.; Skoryunov, R.V.

    2015-10-05

    Highlights: • Solid solutions LiBH{sub 4}–LiI: extremely fast BH{sub 4} reorientations down to low T. • LiLa(BH{sub 4}){sub 3}Cl: Li-ion diffusive jumps and BH{sub 4} reorientations at the same frequency scale. • Dramatic acceleration of B{sub 12}H{sub 12} reorientations in the disordered phase of Na{sub 2}B{sub 12}H{sub 12}. • Fast Na-ion diffusion in the disordered phase of Na{sub 2}B{sub 12}H{sub 12}. - Abstract: Two basic types of thermally activated atomic jump motion are known to exist in solid borohydrides and the related systems: the reorientations of complex anions ([BH{sub 4}]{sup −}, [B{sub 12}H{sub 12}]{sup 2−}) and the translational diffusion of metal cations or complex anions. This paper reviews recent progress in nuclear magnetic resonance (NMR) studies of these jump processes in complex hydrides, such as solid solutions of halide anions in borohydrides, bimetallic borohydrides and borohydride–chlorides, borohydride–amides, and B{sub 12}H{sub 12}-based compounds. The emphasis is put on the systems showing fast-ion conductivity. For these systems, we discuss a possible relation between the reorientational motion of complex anions and the translational motion of metal cations.

  1. Magnetic structure and spin reorientation of quaternary Dy2Fe2Si2C

    Science.gov (United States)

    Susilo, R. A.; Cadogan, J. M.; Hutchison, W. D.; Stewart, G. A.; Avdeev, M.; Campbell, S. J.

    2017-03-01

    We have investigated the low temperature magnetic properties of Dy2Fe2Si2C by using magnetisation, specific heat, x-ray diffraction, neutron powder diffraction and 57Fe Mössbauer spectroscopy measurements over the temperature range 1.5 K–300 K. Dy2Fe2Si2C exhibits two magnetic transitions at low temperatures: an antiferromagnetic transition at {{T}\\text{N}}∼ 26 K and a spin-reorientation transition at {{T}t}∼ 6 K. The magnetic structure above T t can be described with a propagation vector \\mathbf{k}~=~≤ft(0~0~\\frac{1}{2}\\right) with the ordering of the Dy magnetic moments along the monoclinic b-axis whereas on cooling below T t the Dy moment tips away from the b-axis towards the ac-plane. We find that the spin-reorientation in Dy2Fe2Si2C is mainly driven by the competition between the second-order crystal field term B 20 and the higher-order terms, in particular B 40 and B 64.

  2. Converse magnetoelectric effect via strain-driven magnetization reorientations in ultrathin ferromagnetic films on ferroelectric substrates

    Science.gov (United States)

    Pertsev, N. A.

    2015-07-01

    A phenomenological theory is developed for the strain-driven magnetization reorientations occurring in ultrathin ferromagnetic films coupled to ferroelectric substrates experiencing electric-field-induced piezoelectric deformations. The theory takes into account the surface/interface magnetic anisotropy playing an important role in the energetics of such films and first describes the thickness-driven spin reorientation transitions emerging in the presence of substrate-induced lattice strains. Then the threshold and critical intensities of the electric field created in a ferroelectric substrate are calculated, at which different magnetic states acquire the same energy or become unstable in a strained ferromagnetic overlayer. To demonstrate stability ranges of various possible magnetization orientations, we introduce magnetoelectric orientational diagrams, where the electric-field intensity and film thickness are employed as two variables. Such diagrams are constructed for ultrathin Ni, Fe, and F e60C o40 films coupled to single crystals of classical and relaxor ferroelectrics. The inspection of these diagrams shows that the use of multiferroic hybrids comprising ultrathin ferromagnetic films significantly enlarges the range of ferroic materials suitable for experimental observations of the strain-mediated converse magnetoelectric effect.

  3. Strain induced magnetic transitions and spin reorientations in quantum paraelectric EuTiO3 material

    Science.gov (United States)

    Li, Chengdi; Zhao, Jinglong; Dong, Zhengchao; Zhong, Chonggui; Huang, Yanyan; Min, Yi; Wang, Meng; Zhou, Pengxia

    2015-05-01

    Strain induced magnetic transitions and spin reorientations in quantum paraelectric EuTiO3 material have been investigated using the first-principles calculations based on density functional theory. Four kinds of magnetic configurations and three possible directions of magnetic moments in every configuration are taken into consideration, respectively, in paraelectric and ferroelectric phases induced by the biaxial compressive and tensile strains. The calculated results indicate that the strain, regardless of the compressive or tensile strain, can induce not only the magnetic transitions from G-type antiferromagnetic to ferromagnetic phase, but also the reorientation of spin polarization in EuTiO3. The compressive strain can induce a ferromagnetic phase with spin polarization along a axis while the tensile one make magnetic moments along c axis. The further analysis for the electronic density of states (DOS) discover that the magnetic moment direction of EuTiO3 have intrinsic correlation with these orbitals, where the density of states are the most localized. In addition, Anderson super-exchange model is proposed to explain the changes of exchange coupling properties induced by the biaxial strains.

  4. Fast local trust region technique for diffusion tensor registration using exact reorientation and regularization.

    Science.gov (United States)

    Li, Junning; Shi, Yonggang; Tran, Giang; Dinov, Ivo; Wang, Danny J J; Toga, Arthur

    2014-05-01

    Diffusion tensor imaging is widely used in brain connectivity research. As more and more studies recruit large numbers of subjects, it is important to design registration methods which are not only theoretically rigorous, but also computationally efficient. However, the requirement of reorienting diffusion tensors complicates and considerably slows down registration procedures, due to the correlated impacts of registration forces at adjacent voxel locations. Based on the diffeomorphic Demons algorithm (Vercauteren , 2009), we propose a fast local trust region algorithm for handling inseparable registration forces for quadratic energy functions. The method guarantees that, at any time and at any voxel location, the velocity is always within its local trust region. This local regularization allows efficient calculation of the transformation update with numeric integration instead of completely solving a large linear system at every iteration. It is able to incorporate exact reorientation and regularization into the velocity optimization, and preserve the linear complexity of the diffeomorphic Demons algorithm. In an experiment with 84 diffusion tensor images involving both pair-wise and group-wise registrations, the proposed algorithm achieves better registration in comparison with other methods solving large linear systems (Yeo , 2009). At the same time, this algorithm reduces the computation time and memory demand tenfold.

  5. Human sperm pattern of movement during chemotactic re-orientation towards a progesterone source

    Institute of Scientific and Technical Information of China (English)

    Cecilia Soledad Blengini; Maria Eugenia Teves; Diego Rafael Unates; Hector Alejandro Guidobaldi; Laura Virginia Gatica; Laura Cecilia Giojalas

    2011-01-01

    @@ Human spermatozoa may chemotactically find out the egg by following an increasing gradient of attractant molecules.Although human spermatozoa have been observed to show several of the physiological characteristics of chemotaxis,the chemotactic pattern of movement has not been easy to describe.However,it is apparent that chemotactic cells may be identified while returning to the attractant source.This study characterizes the pattern of movement of human spermatozoa during chemotactic re-orientation towards a progesterone source,which is a physiological attractant candidate.By means of videomicroscopy and image analysis,a chemotactic pattern of movement was identified as the spermatozoon returned towards the source of a chemotactic concentration of progesterone (10 pmol l-1).First,as a continuation of its original path,the spermatozoon swims away from the progesterone source with linear movement and then turns back with a transitional movement that can be characterized by an increased velocity and decreased linearity.This sperm behaviour may help the spermatozoon to re-orient itself towards a progesterone source and may be used to identify the few cells that are undergoing chemotaxis at a given time.

  6. Ion induced magnetization reorientation in Co/Pt multilayers for patterned media

    Energy Technology Data Exchange (ETDEWEB)

    Weller, D.; Baglin, J.E.E.; Kellock, A.J.; Hannibal, K.A.; Toney, M.F.; Kusinski, G.; Lang, S.; Best, M.E.; Terris, B.D.

    2000-01-01

    Co/Pt multilayer films with perpendicular magnetic anisotropy and large out-of-plane coercivities of 3.9 - 8.5 kOe have been found to undergo a spin reorientation transition from out-of-plane to in-plane upon irradiation with 700 keV nitrogen ions. X-ray reflectivity experiments show that the multilayer structure gets progressively disrupted with increasing ion dose, providing direct evidence for local atomic displacements at the Co/Pt interfaces. This effectively destroys the magnetic interface anisotropy, which was varied by about a factor of two, between KS@ 0.4 erg/cm2 and KS@ 0.85 erg/cm2 for two particular films. The dose required to initiate spin-reorientation, 6x1014 N+/cm2 and 1.5x1015 N+/cm2, respectively, scales with KS. It is roughly equal to the number of Co interface atoms per unit interface area contributing to KS.

  7. Peculiarities in the director reorientation and evolution of NMR spectra under the influence of crossed electric and magnetic fields

    Science.gov (United States)

    Zakharov, A. V.

    2016-12-01

    Theoretical description is proposed for new modes of reorientation of the director field widehat n and the evolution of the NMR spectrum I(ν) of a nematic liquid crystal (LC) formed by molecules of deuterated 4-n-pentyl-4'-cyanobiphenyl encapsulated in a rectangular LC cell under the action of crossed electric, E, and magnetic, B, fields directed at an angle of α to one another. Numerical calculations in the framework of the nonlinear generalization of the classical Ericksen-Leslie theory show that, under certain relations between the forces and moments acting upon a unit volume of the LC phase upon the reorientation of widehat n, transient periodic structures can arise if the corresponding distortion mode is characterized by the fastest response and thus suppresses all other modes, including uniform ones. It is shown that the rise of these periodic structures leads to a reduction in the time for the reorientation of the director field.

  8. Eesti disain on kõva, ent see tuleb moondada ekspordiks / Michael Thomson ; interv. Urmas Oja

    Index Scriptorium Estoniae

    Thomson, Michael

    2008-01-01

    Euroopa Disainiassotsiatsioonide Liidu presidendi ja Tallinnas toimunud festivali Disainiöö Eesti disainiauhinna Bruno žürii juhi Michael Thomsoni arvamus eesti disainist ning disainipoliitika vajalikkusest Eestis. Auhinnasaajate nimekiri

  9. Theory and practice in action: the contributions of Michael Perkins to clinical linguistics.

    Science.gov (United States)

    Damico, Jack S; Lynch, Karen E

    2013-01-01

    This article reviews the scholarly contributions of Michael R. Perkins in the discipline of clinical linguistics and provides some indication of the reasons that he has been so successful. Three primary attributes were described through an analysis of his publications.

  10. Tõsine fotoelamus Dubrovnikus / Wade Goddard, Heidi Levine, Michael Robinson Chaver ; interv. Ahto Külvet

    Index Scriptorium Estoniae

    Goddard, Wade

    2007-01-01

    Dubrovniku vanalinnas asub Sõjafotokeskus. Intervjuu keskuse asutaja, kanadalasest fotograafi Wade Goddardi ja kahe seal augustis avatud näitusel osalenud fotograafi Heidi Levine'i ja Michael Robinson Chavez'iga. Sõjafotograafi tööst

  11. Reports of the working groups / Eino Tamm, Sahlin Michael, Valve Kirsipuu...[jt.

    Index Scriptorium Estoniae

    1999-01-01

    Töögruppide "EU enlargement and relevant institutional reforms" (juhatajad Eino Tamm, Michael Sahlin) ja "Maintaining of competitiveness of Estonia and other candidate countries" (juhatajad Valve Kirsipuu, Terry Calbom) tööst. Autor: Reformierakond

  12. Tõsine fotoelamus Dubrovnikus / Wade Goddard, Heidi Levine, Michael Robinson Chaver ; interv. Ahto Külvet

    Index Scriptorium Estoniae

    Goddard, Wade

    2007-01-01

    Dubrovniku vanalinnas asub Sõjafotokeskus. Intervjuu keskuse asutaja, kanadalasest fotograafi Wade Goddardi ja kahe seal augustis avatud näitusel osalenud fotograafi Heidi Levine'i ja Michael Robinson Chavez'iga. Sõjafotograafi tööst

  13. High Blood Cholesterol Q&A Dr. Michael Lauer | NIH MedlinePlus the Magazine

    Science.gov (United States)

    ... high cholesterol research. Dr. Michael Lauer and his wife, Dr. Robin Avery, agree on the health benefits ... trial of the drug methotrexate in high-risk patients with vascular disease. We have come to appreciate ...

  14. Chiral Aminophosphines as Catalysts for Enantioselective Double-Michael Indoline Syntheses

    Directory of Open Access Journals (Sweden)

    Ohyun Kwon

    2012-05-01

    Full Text Available The bisphosphine-catalyzed double-Michael addition of dinucleophiles to electron-deficient acetylenes is an efficient process for the synthesis of many nitrogen-containing heterocycles. Because the resulting heterocycles contain at least one stereogenic center, this double-Michael reaction would be even more useful if an asymmetric variant of the reaction were to be developed. Aminophosphines can also facilitate the double-Michael reaction and chiral amines are more readily available in Nature and synthetically; therefore, in this study we prepared several new chiral aminophosphines. When employed in the asymmetric double-Michael reaction between ortho-tosylamidophenyl malonate and 3-butyn-2-one, the chiral aminophosphines produced indolines in excellent yields with moderate asymmetric induction.

  15. Dr. Michael DeBakey "is a magician of the heart…"

    Science.gov (United States)

    ... of Baylor's new Michael E. DeBakey Library and Museum. In a lengthy Christmas Day interview that year ... blood circulation. — 1706 Raymond de Vieussens, a French anatomy professor, first describes the structure of the heart's ...

  16. Reports of the working groups / Eino Tamm, Sahlin Michael, Valve Kirsipuu...[jt.

    Index Scriptorium Estoniae

    1999-01-01

    Töögruppide "EU enlargement and relevant institutional reforms" (juhatajad Eino Tamm, Michael Sahlin) ja "Maintaining of competitiveness of Estonia and other candidate countries" (juhatajad Valve Kirsipuu, Terry Calbom) tööst. Autor: Reformierakond

  17. Trimethylsilylethynyl ketones as surrogates for ethynyl ketones in the double Michael reaction.

    Science.gov (United States)

    Holeman, Derrick S; Rasne, Ravindra M; Grossman, Robert B

    2002-05-01

    Trimethylsilylethynyl ketones can be desilylated in the presence of a tethered carbon diacid and induced to undergo a double Michael reaction in situ. The trimethylsilylethynyl ketones can serve as surrogates of ethynyl ketones that are difficult to prepare or isolate.

  18. A Conversation with his Honour Chief Judge Michael Rozenes AO County Court of Victoria

    Directory of Open Access Journals (Sweden)

    Michael Rozenes

    2014-10-01

    Full Text Available VULJ Editors and invited students interviewed the Chief Judge of the County Court of Victoria, His Honour Michael Rozenes AO QC, on Tuesday 19 August 2014 at the College of Law & Justice, Victoria University.

  19. Reorienting the future role of the religión: humanize humanity. The role of the religión in society of the future will be purely spiritual

    Directory of Open Access Journals (Sweden)

    José María Vigil

    2015-04-01

    Full Text Available The post-Religional paradigm enables emerge in many people, questions about the future of religiosity and religions. The author confronts himself with this concern and tries to control, in a concrete way, the possibilities of a future for religions. In order, and as a starting point, the current process of secularization and the new and growing social phenomenon of 'no religion', this article analyzes the profound changes that are occurring in this time of transition. Then makes a proposal for extension and conversion of the old anthropological concept of spirituality to redirect it towards human depth. In presenting these profound changes, this new concept of spirituality seeks to understand the dimensions and functions that religions are no longer able to keep in post agrarian society what is to come, contributing with ideas and suggestions to deploy creativity with the central task from which religions should reorient and focus, that is, the task of humanizing humanity.

  20. L-prolinol as a highly enantioselective catalyst for Michael addition of cyclohexanone to nitroolefins.

    Science.gov (United States)

    Chua, Pei Juan; Tan, Bin; Zeng, Xiaofei; Zhong, Guofu

    2009-07-15

    Though many chiral amines such as l-proline and its derivatives have proven to be versatile catalysts in many reactions, L-prolinol was seldom used as organocatalyst for reactions. Herein, we report the first L-prolinol catalyzed asymmetric Michael addition of cyclohexanone to nitroolefins in the presence of benzoic acid to afford Michael adducts with high diastereoselectivities (87:13->99:1) and enantioselectivities (82-96%).

  1. Giant rotating magnetocaloric effect in the region of spin-reorientation transition in the NdCo₅ single crystal.

    Science.gov (United States)

    Nikitin, S A; Skokov, K P; Koshkid'ko, Yu S; Pastushenkov, Yu G; Ivanova, T I

    2010-09-24

    We have investigated the anisotropy of the magnetocaloric effect in a NdCo₅ single crystal in a wide range of temperatures, including the spin-reorientation temperature region. In the field μ(0)H =1.3 T in the spin-reorientation region 250-310 K, we discovered a giant rotating magnetocaloric effect of ~ 1.6 K, caused by rotation of the magnetization vector. The calculations of the anisotropy magnetocaloric effect for the field μ(0)H =1.3 T have been carried out.

  2. A post-Byzantine creation: The archangel Michael triumphant and psychopomp

    Directory of Open Access Journals (Sweden)

    Leontakianakou Irini

    2009-01-01

    Full Text Available This paper deals with a specific iconographic type of Archangel Michael: he is shown bearing a soul in the form of a swaddled infant, while subduing an old man who is wearing only a loincloth. Who is Michael subduing? Three possible answers are considered: 1 the figure can be identified with Satan the fallen angel who, like Michael, has an immaterial nature and is commonly considered as his enemy par excellence; 2 he can also be an anonymous sinner, whose soul is depicted in Michael's hand; 3 finally, one could identify him with Hades, the god of the Underworld and personification of death, because he is depicted as an old man, semi-nude with a pronounced musculature, as well as because of the assimilation of Michael to God. Rather than making a single choice, the author proposes a combined interpretation of the image, which allows for the integration of all the aspects of Michael's cult (military, triumph over Satan, psychopomp, archangel of the Last Judgment and unifies the past (the fall of Satan, the present (death of a sinner and the future (Last Judgment.

  3. A geometrical approach to determine reorientation start and continuation conditions in ferromagnetic shape memory alloys considering the effects of loading history

    Science.gov (United States)

    Shirani, M.; Kadkhodaei, M.

    2014-12-01

    Ferromagnetic shape memory alloys (FSMAs) and magnetic shape memory alloys (MSMAs) are metallic alloys that can undergo inelastic responses when exposed to magnetic fields. Several constitutive models have been proposed so far to model the behaviors of FSMAs. In this work, the effects of loading history on reorientation start conditions are considered, and it is shown that reorientation start conditions are not fixed values; rather, they change with respect to the amount of loading history. To consider the effects of loading history on reorientation start conditions, an available phase diagram in stress-field space is generalized to reorientation surfaces in stress-field-loading history space. Correspondingly, kinetic laws are derived in a continuum framework to be used with the reorientation surfaces to determine the amount of the martensitic variant 2 volume fraction. Based on the geometry of the reorientation surfaces, conditions that must be satisfied to ensure the continuation of reorientations are obtained. Available experimental findings validate the proposed model and the reorientation surfaces.

  4. Young Children's Use of Features to Reorient Is More than Just Associative: Further Evidence against a Modular View of Spatial Processing

    Science.gov (United States)

    Newcombe, Nora S.; Ratliff, Kristin R.; Shallcross, Wendy L.; Twyman, Alexandra D.

    2010-01-01

    Proponents of a geometric module have argued that instances of young children's use of features as well as geometry to reorient can be explained by a two-stage process. In this model, only the first stage is a true reorientation, accomplished by using geometric information alone; features are considered in a second stage using association (Lee,…

  5. In-situ particles reorientation during magnetic hyperthermia application: Shape matters twice

    Science.gov (United States)

    Simeonidis, Konstantinos; Morales, M. Puerto; Marciello, Marzia; Angelakeris, Makis; de La Presa, Patricia; Lazaro-Carrillo, Ana; Tabero, Andrea; Villanueva, Angeles; Chubykalo-Fesenko, Oksana; Serantes, David

    2016-12-01

    Promising advances in nanomedicine such as magnetic hyperthermia rely on a precise control of the nanoparticle performance in the cellular environment. This constitutes a huge research challenge due to difficulties for achieving a remote control within the human body. Here we report on the significant double role of the shape of ellipsoidal magnetic nanoparticles (nanorods) subjected to an external AC magnetic field: first, the heat release is increased due to the additional shape anisotropy; second, the rods dynamically reorientate in the orthogonal direction to the AC field direction. Importantly, the heating performance and the directional orientation occur in synergy and can be easily controlled by changing the AC field treatment duration, thus opening the pathway to combined hyperthermic/mechanical nanoactuators for biomedicine. Preliminary studies demonstrate the high accumulation of nanorods into HeLa cells whereas viability analysis supports their low toxicity and the absence of apoptotic or necrotic cell death after 24 or 48 h of incubation.

  6. Temperature-dependent magnetostriction as the key factor for martensite reorientation in magnetic field

    Science.gov (United States)

    L'vov, Victor A.; Kosogor, Anna

    2016-09-01

    The magnetic field application leads to spatially inhomogeneous magnetostriction of twinned ferromagnetic martensite. When the increasing field and magnetostrictive strain reach certain threshold values, the motion of twin boundaries and magnetically induced reorientation (MIR) of twinned martensite start. The MIR leads to giant magnetically induced deformation of twinned martensite. In the present article, the threshold field (TF) and temperature range of observability of MIR were calculated for the Ni-Mn-Ga martensite assuming that the threshold strain (TS) is temperature-independent. The calculations show that if the TS is of the order of 10-4, the TF strongly depends on temperature and MIR can be observed only above the limiting temperature (~220 K). If the TS is of the order of 10-6, the TF weakly depends on temperature and MIR can be observed at extremely low temperatures. The obtained theoretical results are in agreement with available experimental data.

  7. Power-controlled transition from standard to negative refraction in reorientational soft matter.

    Science.gov (United States)

    Piccardi, Armando; Alberucci, Alessandro; Kravets, Nina; Buchnev, Oleksandr; Assanto, Gaetano

    2014-11-25

    Refraction at a dielectric interface can take an anomalous character in anisotropic crystals, when light is negatively refracted with incident and refracted beams emerging on the same side of the interface normal. In soft matter subject to reorientation, such as nematic liquid crystals, the nonlinear interaction with light allows tuning of the optical properties. We demonstrate that in such material a beam of light can experience either positive or negative refraction depending on input power, as it can alter the spatial distribution of the optic axis and, in turn, the direction of the energy flow when traveling across an interface. Moreover, the nonlinear optical response yields beam self-focusing and spatial localization into a self-confined solitary wave through the formation of a graded-index waveguide, linking the refractive transition to power-driven readdressing of copolarized guided-wave signals, with a number of output ports not limited by diffraction.

  8. Mechanism of dynamic reorientation of cortical microtubules due to mechanical stress

    CERN Document Server

    Muratov, Alexander

    2015-01-01

    Directional growth caused by gravitropism and corresponding bending of plant cells has been explored since 19th century, however, many aspects of mechanisms underlying the perception of gravity at the molecular level are still not well known. Perception of gravity in root and shoot gravitropisms is usually attributed to gravisensitive cells, called statocytes, which exploit sedimentation of macroscopic and heavy organelles, amyloplasts, to sense the direction of gravity. Gravity stimulus is then transduced into distal elongation zone, which is several mm far from statocytes, where it causes stretching. It is suggested that gravity stimulus is conveyed by gradients in auxin flux. We propose a theoretical model that may explain how concentration gradients and/or stretching may indirectly affect the global orientation of cortical microtubules, attached to the cell membrane and induce their dynamic reorientation perpendicular to the gradients. In turn, oriented microtubules arrays direct the growth and orientatio...

  9. Nonlinear continuous-wave optical propagation in nematic liquid crystals: Interplay between reorientational and thermal effects

    Science.gov (United States)

    Alberucci, Alessandro; Laudyn, Urszula A.; Piccardi, Armando; Kwasny, Michał; Klus, Bartlomiej; Karpierz, Mirosław A.; Assanto, Gaetano

    2017-07-01

    We investigate nonlinear optical propagation of continuous-wave (CW) beams in bulk nematic liquid crystals. We thoroughly analyze the competing roles of reorientational and thermal nonlinearity with reference to self-focusing/defocusing and, eventually, the formation of nonlinear diffraction-free wavepackets, the so-called spatial optical solitons. To this extent we refer to dye-doped nematic liquid crystals in planar cells excited by a single CW beam in the highly nonlocal limit. To adjust the relative weight between the two nonlinear responses, we employ two distinct wavelengths, inside and outside the absorption band of the dye, respectively. Different concentrations of the dye are considered in order to enhance the thermal effect. The theoretical analysis is complemented by numerical simulations in the highly nonlocal approximation based on a semi-analytic approach. Theoretical results are finally compared to experimental results in the Nematic Liquid Crystals (NLC) 4-trans-4'-n-hexylcyclohexylisothiocyanatobenzene (6CHBT) doped with Sudan Blue dye.

  10. Observation of second spin reorientation transition within ultrathin region in Fe films on Ag(001) surface

    Energy Technology Data Exchange (ETDEWEB)

    Khim, T.-Y. [c-CCMR and Department of Physics, POSTECH, Pohang 790-784 (Korea, Republic of); Shin, M.; Lee, H., E-mail: easyscan@sookmyung.ac.kr, E-mail: jhp@postech.ac.kr [Department of Chemistry, Sookmyung Women' s University, Seoul 140-742 (Korea, Republic of); Park, B.-G. [Pohang Accelerator Laboratory (PAL), Pohang 790-784 (Korea, Republic of); Park, J.-H., E-mail: easyscan@sookmyung.ac.kr, E-mail: jhp@postech.ac.kr [c-CCMR and Department of Physics, POSTECH, Pohang 790-784 (Korea, Republic of); Division of Advanced Materials Science, POSTECH, Pohang 790-784 (Korea, Republic of); Max Plank POSTECH Center for Complex Phase Materials, POSTECH, Pohang 790-784 (Korea, Republic of)

    2014-06-21

    We acquired direct measurements for in-plane and perpendicular-to-plane magnetic moments of Fe films using an x-ray magnetic circular dichroism technique with increase of the Fe thickness (up to 40 Å) on the Ag(001) surface. Epitaxial Fe/Ag(001) films were grown in situ with the thickness varying from 2 Å to 40 Å, and the magnetic anisotropy was carefully investigated as a function of the film thickness. We found re-entrance of the in-plane magnetic anisotropy of the Fe film in ultrathin region. The results manifest that the epitaxial Fe/Ag(001) film undergoes two distinct spin reorientation transitions from in-plane to out-of-plane at the film thickness t ≈ 9 Å and back to in-plane at t ≈ 18 Å as t increases.

  11. Rotational reorientation dynamics of C60 in various solvents. Picosecond transient grating experiments

    Science.gov (United States)

    Rubtsov, I. V.; Khudiakov, D. V.; Nadtochenko, V. A.; Lobach, A. S.; Moravskii, A. P.

    1994-11-01

    The picosecond transient grating technique has been used to study the rotational reorientation of C60 in various solvents: in toluene 7 +/- 1.5 ps, o-dichlorobenzene 10.3 +/- 1.5 ps, o-xylene 13 +/- 2 ps and in decalin 3.5 +/- 1.5 ps. The data obtained cannot be described by hydrodynamic Debye theory. Rough-sphere fluid theory predicts the correct values for C60 rotation in toluene, o-dichlorobenzene and in decalin. The deviations for o-xylene are probably connected with the specifics of the local solvent structure or with the stronger interaction of C60 with solvent molecules. The rotation of C60 in decalin is rapid and approaches the rotation in the gas phase determined by inertia.

  12. An image analysis approach for automatically re-orienteering CT images for dental implants.

    Science.gov (United States)

    Cucchiara, Rita; Lamma, Evelina; Sansoni, Tommaso

    2004-06-01

    In the last decade, computerized tomography (CT) has become the most frequently used imaging modality to obtain a correct pre-operative implant planning. In this work, we present an image analysis and computer vision approach able to identify, from the reconstructed 3D data set, the optimal cutting plane specific to each implant to be planned, in order to obtain the best view of the implant site and to have correct measures. If the patient requires more implants, different cutting planes are automatically identified, and the axial and cross-sectional images can be re-oriented accordingly to each of them. In the paper, we describe the defined algorithms in order to recognize 3D markers (each one aligned with a missed tooth for which an implant has to be planned) in the 3D reconstructed space, and the results in processing real exams, in terms of effectiveness and precision and reproducibility of the measure.

  13. An NMR study of molecular reorientations and diffusion in solid LiBF4

    Science.gov (United States)

    Reynhardt, E. C.; Lourens, J. A. J.

    1984-06-01

    The 19F second moment and the 19F, 11B, and 7Li spin-lattice relaxation times in a powdered sample of LiBF4 have been measured as a function of temperature. The results show that the BF-4 ion reorients isotropically while the Li+ ion remains stationary. The activation energy associated with the BF-4 motion is 8.5 kcal/mol. Above ˜385 K the BF-4 and Li+ diffuse through the lattice resulting in a 19F second moment which is almost zero. The activation energy of this process is 19.2 kcal/mol. A librational motion presumably influences the 19F T1ρ results just before diffusion sets in. The migration of Li+ around the BF-4 ion, which seems to be a strong possibility in the case of an isolated LiBF4 molecule, does not take place in the solid.

  14. Communication: On the origin of the non-Arrhenius behavior in water reorientation dynamics.

    Science.gov (United States)

    Stirnemann, Guillaume; Laage, Damien

    2012-07-21

    We combine molecular dynamics simulations and analytic modeling to determine the origin of the non-Arrhenius temperature dependence of liquid water's reorientation and hydrogen-bond dynamics between 235 K and 350 K. We present a quantitative model connecting hydrogen-bond exchange dynamics to local structural fluctuations, measured by the asphericity of Voronoi cells associated with each water molecule. For a fixed local structure the regular Arrhenius behavior is recovered, and the global anomalous temperature dependence is demonstrated to essentially result from a continuous shift in the unimodal structure distribution upon cooling. The non-Arrhenius behavior can thus be explained without invoking an equilibrium between distinct structures. In addition, the large width of the homogeneous structural distribution is shown to cause a growing dynamical heterogeneity and a non-exponential relaxation at low temperature.

  15. Dynamic selective switching in antiferromagnetically-coupled bilayers close to the spin reorientation transition

    Energy Technology Data Exchange (ETDEWEB)

    Fernández-Pacheco, A., E-mail: af457@cam.ac.uk; Mansell, R.; Petit, D.; Lee, J. H.; Cowburn, R. P. [Cavendish Laboratory, University of Cambridge, J. J. Thomson Avenue, Cambridge CB3 0HE (United Kingdom); Ummelen, F. C.; Swagten, H. J. M. [Department of Applied Physics, Center for NanoMaterials, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands)

    2014-09-01

    We have designed a bilayer synthetic antiferromagnet where the order of layer reversal can be selected by varying the sweep rate of the applied magnetic field. The system is formed by two ultra-thin ferromagnetic layers with different proximities to the spin reorientation transition, coupled antiferromagnetically using Ruderman-Kittel-Kasuya-Yosida interactions. The different dynamic magnetic reversal behavior of both layers produces a crossover in their switching fields for field rates in the kOe/s range. This effect is due to the different effective anisotropy of both layers, added to an appropriate asymmetric antiferromagnetic coupling between them. Field-rate controlled selective switching of perpendicular magnetic anisotropy layers as shown here can be exploited in sensing and memory applications.

  16. Altruism and Re-Orientation as Core for the Development of Africa

    Directory of Open Access Journals (Sweden)

    Simeon Omale

    2014-11-01

    Full Text Available Jan Knippers Black in his book, Development in Theory and Practice: Paradigm and Paradoxes had identified theories ranging from Liberal international School; modernization school; cultural weakness; Interdependence School as reasons for the unparalleled development of the world. While often these are used along the like of cultural imperialism and the un-even trade opportunities as reasons for Africa’s developmental quagmire, it is the opinion of this paper that Africa’s underdevelopment are largely products of our actions and non-actions. It is in this light that we seek to argue for the development of the spirit of Altruism and a reorientation of the national consciousness via investment in the Early Child Education adopting participatory learning and communication approach as necessary panacea for Africa’s development. By instilling in the young minds the expediency of a more altruistic modus vivendi, the culture of egoistic corruption could be overturned.

  17. Early mammalian development under conditions of reorientation relative to the gravity vector

    Science.gov (United States)

    Wolgemuth, D. J.; Grills, G. S.

    1985-01-01

    A clinostat was used to assess the effects of reorientation relative to the gravity vector on mammalian germ cells cultured in vitro. Previous studies using this system revealed an inhibition of meiotic maturation of mouse oocytes. In the present study, the effects of clinostat rotation on in vitro fertilization were examined. The frequency of fertilization of experimental cultures did not vary from that of the clinostat vertical control cultures at either of the rotation rates examined. Importantly, no abnormalities of fertilization, such as parthenogenetic activation, fragmentation, or polyspermy were seen. It is concluded that the initial events of fertilization were unaffected by this treatment, although the developmental potential of these embryos remains to be assessed.

  18. Re-orienting a remote acute care model towards a primary health care approach: key enablers.

    Science.gov (United States)

    Carroll, Vicki; Reeve, Carole A; Humphreys, John S; Wakerman, John; Carter, Maureen

    2015-01-01

    The objective of this study was to identify the key enablers of change in re-orienting a remote acute care model to comprehensive primary healthcare delivery. The setting of the study was a 12-bed hospital in Fitzroy Crossing, Western Australia. Individual key informant, in-depth interviews were completed with five of six identified senior leaders involved in the development of the Fitzroy Valley Health Partnership. Interviews were recorded and transcripts were thematically analysed by two investigators for shared views about the enabling factors strengthening primary healthcare delivery in a remote region of Australia. Participants described theestablishment of a culturally relevant primary healthcare service, using a community-driven, 'bottom up' approach characterised by extensive community participation. The formal partnership across the government and community controlled health services was essential, both to enable change to occur and to provide sustainability in the longer term. A hierarchy of major themes emerged. These included community participation, community readiness and desire for self-determination; linkages in the form of a government community controlled health service partnership; leadership; adequate infrastructure; enhanced workforce supply; supportive policy; and primary healthcare funding. The strong united leadership shown by the community and the health service enabled barriers to be overcome and it maximised the opportunities provided by government policy changes. The concurrent alignment around a common vision enabled implementation of change. The key principle learnt from this study is the importance of community and health service relationships and local leadership around a shared vision for the re-orientation of community health services.

  19. The impact of reorienting cone-beam computed tomographic images in varied head positions on the coordinates of anatomical landmarks

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jae Hun; Jeong, Ho Gul; Hwang, Jae Joon; Lee, Jung Hee; Han, Sang Sun [Dept. of Oral and Maxillofacial Radiology, Yonsei University, College of Dentistry, Seoul (Korea, Republic of)

    2016-06-15

    The aim of this study was to compare the coordinates of anatomical landmarks on cone-beam computed tomographic (CBCT) images in varied head positions before and after reorientation using image analysis software. CBCT images were taken in a normal position and four varied head positions using a dry skull marked with 3 points where gutta percha was fixed. In each of the five radiographic images, reference points were set, 20 anatomical landmarks were identified, and each set of coordinates was calculated. Coordinates in the images from the normally positioned head were compared with those in the images obtained from varied head positions using statistical methods. Post-reorientation coordinates calculated using a three-dimensional image analysis program were also compared to the reference coordinates. In the original images, statistically significant differences were found between coordinates in the normal-position and varied-position images. However, post-reorientation, no statistically significant differences were found between coordinates in the normal-position and varied-position images. The changes in head position impacted the coordinates of the anatomical landmarks in three-dimensional images. However, reorientation using image analysis software allowed accurate superimposition onto the reference positions.

  20. Flux line lattice reorientation in the borocarbide superconductors with ¤H¤ parallel to ¤a¤

    DEFF Research Database (Denmark)

    Eskildsen, M.R.; Abrahamsen, A.B.; Lopez, D.

    2001-01-01

    Small angle neutron scattering studies of the flux line lattice in LuNi2B2C and ErNi2B2C induced by a held parallel to the a axis reveal a first order flux Line lattice reorientation transition. Below the transition the Bur line lattice nearest neighbor direction is parallel to the b axis, and ab...

  1. Symmetry breaking, slow relaxation dynamics, and topological defects at the field-induced helix reorientation in MnSi

    Science.gov (United States)

    Bauer, A.; Chacon, A.; Wagner, M.; Halder, M.; Georgii, R.; Rosch, A.; Pfleiderer, C.; Garst, M.

    2017-01-01

    We report a study of the reorientation of the helimagnetic order in the archetypal cubic chiral magnet MnSi as a function of magnetic field direction. The reorientation process as inferred from small-angle neutron scattering, the magnetization, and the ac susceptibility is in excellent agreement with an effective mean-field theory taking into account the precise symmetries of the crystallographic space group. Depending on the field and temperature history and the direction of the field with respect to the crystalline axes, the helix reorientation may exhibit a crossover, a first-order, or a second-order transition. The magnetization and ac susceptibility provide evidence that the reorientation of helimagnetic domains is associated with large relaxation times exceeding seconds. At the second-order transitions residual Ising symmetries are spontaneously broken at continuous elastic instabilities of the helimagnetic order. In addition, on the time scales explored in our experiments these transitions are hysteretic as a function of field suggesting, within the same theoretical framework, the formation of an abundance of plastic deformations of the helical spin order. These deformations comprise topologically nontrivial disclinations, reminiscent of the skyrmions discovered recently in the same class of materials.

  2. The impact of reorienting cone-beam computed tomographic images in varied head positions on the coordinates of anatomical landmarks

    Science.gov (United States)

    Kim, Jae Hun; Hwang, Jae Joon; Lee, Jung-Hee

    2016-01-01

    Purpose The aim of this study was to compare the coordinates of anatomical landmarks on cone-beam computed tomographic (CBCT) images in varied head positions before and after reorientation using image analysis software. Materials and Methods CBCT images were taken in a normal position and four varied head positions using a dry skull marked with 3 points where gutta percha was fixed. In each of the five radiographic images, reference points were set, 20 anatomical landmarks were identified, and each set of coordinates was calculated. Coordinates in the images from the normally positioned head were compared with those in the images obtained from varied head positions using statistical methods. Post-reorientation coordinates calculated using a three-dimensional image analysis program were also compared to the reference coordinates. Results In the original images, statistically significant differences were found between coordinates in the normal-position and varied-position images. However, post-reorientation, no statistically significant differences were found between coordinates in the normal-position and varied-position images. Conclusion The changes in head position impacted the coordinates of the anatomical landmarks in three-dimensional images. However, reorientation using image analysis software allowed accurate superimposition onto the reference positions. PMID:27358821

  3. Using Cognitive Task Analysis and Eye Tracking to Understand Imagery Analysis

    Science.gov (United States)

    2006-01-01

    Using Cognitive Task Analysis and Eye Tracking to Understand Imagery Analysis Laura Kurland, Abigail Gertner, Tom Bartee, Michael Chisholm and...environment to capture qualitative and quantitative data by recording time-stamped eye tracking , screen capture of an Electronic Light Table...TITLE AND SUBTITLE Using Cognitive Task Analysis and Eye Tracking to Understand Imagery Analysis 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM

  4. The CHINA CONNECTION: Michael Rossmann and his first encounter with me

    Institute of Scientific and Technical Information of China (English)

    Jia-huai Wang

    2010-01-01

    @@ "We would have never belived it, if it were not told by Dorothy Hodgkin," Michael Rossmann of Purdue University said to me. He was referring to what the late Nobel laureate Dorothy Hodgkin announced in an international meeting about the achievements of Chinese scientists in determining the crystal structure of insulin in early 70's. This significant contribution occurred at the time when China was still deeply entangled in the chaos of the Cultural Revolution, while even in the international community there were less than a dozen protein structures solved by scientists (Michael included) from a handful of countries. Michael and I sat in his cozy dinning room. While enjoying a breakfast with his favorite applesauce,observing a wild rabbit sneaking underneath the bush in the garden, we had a long chat. That was dudng my first visit to his lab in West Lafayette in 1980.

  5. Aza-Michael Mono-addition Using Acidic Alumina under Solventless Conditions

    Directory of Open Access Journals (Sweden)

    Giovanna Bosica

    2016-06-01

    Full Text Available Aza-Michael reactions between primary aliphatic and aromatic amines and various Michael acceptors have been performed under environmentally-friendly solventless conditions using acidic alumina as a heterogeneous catalyst to selectively obtain the corresponding mono-adducts in high yields. Ethyl acrylate was the main acceptor used, although others such as acrylonitrile, methyl acrylate and acrylamide were also utilized successfully. Bi-functional amines also gave the mono-adducts in good to excellent yields. Such compounds can serve as intermediates for the synthesis of anti-cancer and antibiotic drugs.

  6. Michael Goodsite gæsteprofessor på Thunderbird School of Global Management

    DEFF Research Database (Denmark)

    Pedersen, Jens Christian

    2010-01-01

    Professor Michael Goodsite er blevet udnævnt til "Visiting Professor of Global Processes and Senior Research Fellow in Climate Strategy" ved Thunderbird School of Global Management, som har verdens højst rangerede MBA uddannelse inden for international handel.......Professor Michael Goodsite er blevet udnævnt til "Visiting Professor of Global Processes and Senior Research Fellow in Climate Strategy" ved Thunderbird School of Global Management, som har verdens højst rangerede MBA uddannelse inden for international handel....

  7. Beyond the techno-thriller: Michael Crichton and societal issues in science and technology

    OpenAIRE

    Stengler, E.

    2015-01-01

    Michael Crichton is primarily known for being an outstanding writer of techno-thrillers and co-creator of the genre. In this paper I suggest that his fictional works can and should be considered under the deeper and wider perspective of his concern for societal issues regarding science and technology with a profound consideration of their effects and on the life of people and the development of society.\\ud \\ud In fact this defining feature of his work is inclusive of numerous works by Michael...

  8. Copper-catalyzed asymmetric conjugate addition of organometallic reagents to extended Michael acceptors

    Directory of Open Access Journals (Sweden)

    Thibault E. Schmid

    2015-12-01

    Full Text Available The copper-catalyzed asymmetric conjugate addition (ACA of nucleophiles onto polyenic Michael acceptors represents an attractive and powerful methodology for the synthesis of relevant chiral molecules, as it enables in a straightforward manner the sequential generation of two or more stereogenic centers. In the last decade, various chiral copper-based catalysts were evaluated in combination with different nucleophiles and Michael acceptors, and have unambiguously demonstrated their usefulness in the control of the regio- and enantioselectivity of the addition. The aim of this review is to report recent breakthroughs achieved in this challenging field.

  9. A Greener, Efficient Approach to Michael Addition of Barbituric Acid to Nitroalkene in Aqueous Diethylamine Medium

    Directory of Open Access Journals (Sweden)

    Hany J. Al-Najjar

    2014-01-01

    Full Text Available An efficient method for the synthesis of a variety of pyrimidine derivatives 3a–t by reaction of barbituric acids 1a,b as Michael donor with nitroalkenes 2a–k as Michael acceptor using an aqueous medium and diethylamine is described. This 1,4-addition strategy offers several advantages, such as using an economic and environmentally benign reaction media, high yields, versatility, and shorter reaction times. The synthesized compounds were identified by 1H-NMR, 13C-NMR, CHN, IR, and MS. The structure of compound 3a was further confirmed by single crystal X-ray structure determination.

  10. Reorienting land degradation towards sustainable land management: linking sustainable livelihoods with ecosystem services in rangeland systems.

    Science.gov (United States)

    Reed, M S; Stringer, L C; Dougill, A J; Perkins, J S; Atlhopheng, J R; Mulale, K; Favretto, N

    2015-03-15

    This paper identifies new ways of moving from land degradation towards sustainable land management through the development of economic mechanisms. It identifies new mechanisms to tackle land degradation based on retaining critical levels of natural capital whilst basing livelihoods on a wider range of ecosystem services. This is achieved through a case study analysis of the Kalahari rangelands in southwest Botswana. The paper first describes the socio-economic and ecological characteristics of the Kalahari rangelands and the types of land degradation taking place. It then focuses on bush encroachment as a way of exploring new economic instruments (e.g. Payments for Ecosystem Services) designed to enhance the flow of ecosystem services that support livelihoods in rangeland systems. It does this by evaluating the likely impacts of bush encroachment, one of the key forms of rangeland degradation, on a range of ecosystem services in three land tenure types (private fenced ranches, communal grazing areas and Wildlife Management Areas), before considering options for more sustainable land management in these systems. We argue that with adequate policy support, economic mechanisms could help reorient degraded rangelands towards more sustainable land management.

  11. A study of methyl reorientation in solid nitromethane by neutron scattering

    Science.gov (United States)

    Trevino, S. F.; Rymes, W. H.

    1980-09-01

    The geometrical and dynamical properties of the reorientation of the methyl group of nitromethane in the solid state have been studied by inelastic neutron scattering. Quasielastic scattering spectra have been obtained for several values of momentum transfer at five temperatures between 50° and 150 °K. The spectra are shown to be consistent with jumps of 120 ° about an axis coincident with the C-N bond. The temperature dependence of the residence time yields a barrier of 234 cal/mole. An inelastic neutron spectrum obtained at 4.2 °K suggests a tunnel splitting of the torsional ground state of 0.045±0.005 meV, which is consistent with the derived activation energy. Inelastic neutron scattering has also been used to determine the energy of the tunnel split first excited state which in CH3NO2 has a mean energy of 7.4 meV above the ground state and is split by 1.8 meV. In the deuterated compound, the first excited stated is at 5.3 meV above the ground state and its splitting is less than the instrumental resolution.

  12. Quantifying Signaling-Induced Reorientation of TCR's During Immunological Synapse Formation

    Energy Technology Data Exchange (ETDEWEB)

    Moss, W C; Irvine, D J; Davis, M M; Krummel, M F

    2002-10-17

    Productive T cell recognition of antigen-presenting cells (APCs) is normally accompanied by the formation of a cell-cell contact called the 'immunological synapse.' Our understanding of the steps leading up to this formation has been limited by the absence of tools for analyzing 3D surfaces and surface distributions as they change over time. Here we use a 3D fluorescence quantitation method to show that T cell receptors are recruited in bulk within the first minute after the onset of activation and with velocities ranging from 0.04 to 0.1 {micro}m/s; a speed significantly greater than unrestricted diffusion. Our method reveals a second feature of this reorientation: a conformational change as the T cell pushes more total membrane into the interface creating a larger contact area for additional receptors. Analysis of individual T cell receptor velocities using a single-particle tracking method confirms our velocity measurement. This method should permit the quantitation of other dynamic membrane events and the associated movement of cell-surface molecules.

  13. Teaching-Service integration within the National Professional Health Education Reorientation Program.

    Science.gov (United States)

    Vendruscolo, Carine; Prado, Marta Lenise do; Kleba, Maria Elisabeth

    2016-09-01

    This integrative literature review aimed at identifying the characteristics and describing how teaching-service integration is expressed in studies on Pró-Saúde (Charitable institution for social and hospital assistance) published in Brazil in the period 2007-2012. For the search, the term National Professional Health Education Reorientation Program was entered in the following databases: Virtual Health Library (BVS), Google Scholar and the Bank of Theses of the Coordination for the Improvement of Higher Education Personnel (CAPES). Forty-one publications were selected with the following inclusion criteria: scientific papers; theses and dissertations; studies in English, Portuguese or Spanish. The critical review of studies was performed through a comprehensive reading of the texts. Outcomes are presented in two categories: Dialogue and partnership as tools for teaching-service integration and Movements of change in teaching-service through Pró-Saúde. Studies have shown that changes in professional education and practice are possible and necessary, especially when supported by strategies that encourage active participation of subjects and confirm teaching-service integration as opportunity for dialogue, promoted by this inducing policy.

  14. Noble metal capping effects on the spin-reorientation transitions of Co/Ru(0001)

    Energy Technology Data Exchange (ETDEWEB)

    El Gabaly, Farid; Figuera, Juan de la [Centro de Microanalisis de Materiales, Universidad Autonoma de Madrid, Madrid 28049 (Spain); McCarty, Kevin F [Sandia National Laboratories, Livermore, CA 94550 (United States); Schmid, Andreas K [Lawrence Berkeley National Laboratory, Berkeley 94720 (United States); Munoz, M Carmen; Gallego, Silvia [Instituto de Ciencia de Materiales de Madrid, CSIC, Madrid 28049 (Spain); Szunyogh, Laszlo [Department of Theoretical Physics, Institute of Physics, Budapest University of Technology and Economics, H-111 Budapest (Hungary); Weinberger, Peter [Center for Computational Nanoscience, A-1010 Wien (Austria)], E-mail: juan.delafiguera@iqfr.csic.es

    2008-07-15

    Thin films of Co/Ru(0001) are known to exhibit an unusual spin reorientation transition (SRT) coupled to the completion of Co atomic layers for Co thicknesses under four layers. By means of spin-polarized low-energy electron microscopy, we follow in real space the magnetization orientation during the growth of atomically thick capping layers on Co/Ru(0001). Capping with noble metal (Cu, Ag and Au) elements modifies the SRT depending on the Co and overlayer thickness and on the overlayer material, resulting in an expanded range of structures with high perpendicular magnetic anisotropy. The origin of the SRT can be explained in terms of ab initio calculations of the layer-resolved contributions to the magnetic anisotropy energy. Besides the changes in the SRT introduced by the capping, a quantitative enhancement of the magnetic anisotropy is identified. A detailed analysis of the interplay between strain and purely electronic effects allows us to identify the conditions that lead to a high perpendicular magnetic anisotropy in thin hcp Co films.

  15. Structural changes induced spin-reorientation of ultrathin Mn films grown on Ag(001)

    Energy Technology Data Exchange (ETDEWEB)

    Ouarab, N., E-mail: ouarab_nourdine@yahoo.fr [Quantum Physics and Dynamical Systems Laboratory, Ferhat Abbas University of Sétif (Algeria); Semiconductor Technology Research Center for Energetic-(CRTSE), 02, Bd Frantz Fanon Algiers, BP N° 140 (Algeria); Haroun, A. [Quantum Physics and Dynamical Systems Laboratory, Ferhat Abbas University of Sétif (Algeria); Baadji, N. [School of Physics and CRANN, Trinity College, Dublin 2 (Ireland)

    2016-12-01

    The strained body centered tetragonal (bct) Mn ultrathin film from lattice parameter a=2.89 Å to lattice value of 2.73 Å induces anti-ferromagnetic behavior between Mn layers. The magnetic easy axis of Mn film was demonstrated theoretically to switch from the in-plane to out-of-plane by magneto-optical Kerr effect investigation. By including spin–orbit coupling in full potential linearized augmented plane waves and linearized muffin-tin orbitals methods, manganese ultrathin film displays different magnetic behaviors and the spin-reorientation transition is shown to be correlated to these structural changes. The calculated magnetic moment of manganese planes are enhanced and reach a value of ~4.02 μ{sub B}. The polar magneto-optical Kerr effect is calculated for a photon energy range extended to 15 eV. It shows a pronounced peak in visible light. - Highlights: • The applied strain in Mn-bct structure induces anti-ferromagnetic behavior. • The easy magnetization axis is demonstrated to be out-of-plane. • The magnetic moment of Mn-layers are enhanced and reach a value of ~4.02 μ{sub B}. • Kerr spectra show significant polar responses for Mn films in the visible range. • The prominent structures in the Kerr spectra have been identified.

  16. Microscopic structure and reorientation kinetics of B-H complexes in silicon

    Science.gov (United States)

    Noya, José C.; Herrero, Carlos P.; Ramírez, Rafael

    1997-12-01

    Structural and dynamical properties of hydrogen and deuterium in boron-doped silicon have been studied by the path-integral Monte Carlo method as a function of temperature in the range between 30 and 400 K. The Si-Si and Si-B interactions were modeled by Stillinger-Weber-type potentials, and the Si-H and B-H interactions were parametrized by following the results of earlier pseudopotential-density-functional calculations for this system. Impurity energy, nuclei delocalization, and lattice relaxation are analyzed, the latter resulting to be mass dependent. The reorientation rate of the complex is obtained from quantum transition-state theory. A break in the slope of the Arrhenius plot for the jump rate of hydrogen is obtained at T~60 K, indicating a crossover from thermally activated quasiclassical motion over a barrier to thermally assisted quantum tunneling, in good agreement with previous experimental results. For deuterium, this deviation from an Arrhenius law is found at T~35 K. Both the impurity and the host nuclei are treated quantum mechanically, and it is shown that the defect complex undergoing quantum tunneling consists of hydrogen, boron, and the nearest silicon atoms.

  17. Estrogen-induced collagen reorientation correlates with sympathetic denervation of the rat myometrium.

    Science.gov (United States)

    Martínez, G F; Bianchimano, P; Brauer, M M

    2016-12-01

    Estrogen inhibits the growth and causes the degeneration (pruning) of sympathetic nerves supplying the rat myometrium. Previous cryoculture studies evidenced that substrate-bound signals contribute to diminish the ability of the estrogenized myometrium to support sympathetic nerve growth. Using electron microscopy, here we examined neurite-substrate interactions in myometrial cryocultures, observing that neurites grew associated to collagen fibrils present in the surface of the underlying cryosection. In addition, we assessed quantitatively the effects of estrogen on myometrial collagen organization in situ, using ovariectomized rats treated with estrogen and immature females undergoing puberty. Under low estrogen levels, most collagen fibrils were oriented in parallel to the muscle long axis (83% and 85%, respectively). Following estrogen treatment, 89% of fibrils was oriented perpendicularly to the muscle main axis; while after puberty, 57% of fibrils acquired this orientation. Immunohistochemistry combined with histology revealed that the vast majority of fine sympathetic nerve fibers supplying the myometrium courses within the areas where collagen realignment was observed. Finally, to assess whether depending on their orientation collagen fibrils can promote or inhibit neurite outgrowth, we employed cryocultures, now using as substrate tissue sections of rat-tail tendon. We observed that neurites grew extensively in the direction of the parallel-aligned collagen fibrils in the tendon main axis but were inhibited to grow perpendicularly to this axis. Collectively, these findings support the hypothesis that collagen reorientation may be one of the factors contributing to diminish the neuritogenic capacity of the estrogen-primed myometrial substrate.

  18. A novel computational modelling to describe the anisotropic, remodelling and reorientation behaviour of collagen fibrres in articular cartilage

    CERN Document Server

    Cortez, S; Alves, J L

    2016-01-01

    In articular cartilage the orientation of collagen fibres is not uniform, varying mostly with the depth on the tissue. Besides, the biomechanical response of each layer of the articular cartilage differs from the neighbouring ones, evolving through thickness as a function of the distribution, density and orientation of the collagen fibres. Based on a finite element implementation, a new continuum formulation is proposed to describe the remodelling and reorientation of the collagen fibres under arbitrary mechanical loads: the cartilaginous tissue is modelled based on a hyperelastic formulation, being the ground isotropic matrix described by a neo-Hookean law and the fibrillar anisotropic part modelled by a new anisotropic formulation introduced for the first time in the present work, in which both reorientation and remodelling are taken into account. To characterize the orientation of fibres, a structure tensor is defined to represent the expected distribution and orientation of fibres around a reference direc...

  19. A 3D finite-strain-based constitutive model for shape memory alloys accounting for thermomechanical coupling and martensite reorientation

    Science.gov (United States)

    Wang, Jun; Moumni, Ziad; Zhang, Weihong; Xu, Yingjie; Zaki, Wael

    2017-06-01

    The paper presents a finite-strain constitutive model for shape memory alloys (SMAs) that accounts for thermomechanical coupling and martensite reorientation. The finite-strain formulation is based on a two-tier, multiplicative decomposition of the deformation gradient into thermal, elastic, and inelastic parts, where the inelastic deformation is further split into phase transformation and martensite reorientation components. A time-discrete formulation of the constitutive equations is proposed and a numerical integration algorithm is presented featuring proper symmetrization of the tensor variables and explicit formulation of the material and spatial tangent operators involved. The algorithm is used for finite element analysis of SMA components subjected to various loading conditions, including uniaxial, non-proportional, isothermal and adiabatic loading cases. The analysis is carried out using the FEA software Abaqus by means of a user-defined material subroutine, which is then utilized to simulate a SMA archwire undergoing large strains and rotations.

  20. 78 FR 6851 - Proposed Information Collection (Patient Satisfaction Survey Michael E. DeBakey Home Care Program...

    Science.gov (United States)

    2013-01-31

    ... AFFAIRS Proposed Information Collection (Patient Satisfaction Survey Michael E. DeBakey Home Care Program....'' SUPPLEMENTARY INFORMATION: Title: Patient Satisfaction Survey Michael E. DeBakey Home Care Program, VA Form 10.... Abstract: VA Form 10-0476 will be used to gather feedback from patients regarding their satisfaction...

  1. 77 FR 69550 - Proposed Information Collection (Patient Satisfaction Survey Michael E. DeBakey Home Care Program...

    Science.gov (United States)

    2012-11-19

    ... AFFAIRS Proposed Information Collection (Patient Satisfaction Survey Michael E. DeBakey Home Care Program.... This notice solicits comments on information needed to determine patients' satisfaction with services... information technology. Title: Patient Satisfaction Survey Michael E. DeBakey Home Care Program, VA Form...

  2. 76 FR 624 - Proposed Information Collection (Patient Satisfaction Survey Michael E. DeBakey Home Care Program...

    Science.gov (United States)

    2011-01-05

    ... AFFAIRS Proposed Information Collection (Patient Satisfaction Survey Michael E. DeBakey Home Care Program.... 2900-New (VA Form 10-0476).'' SUPPLEMENTARY INFORMATION: Title: Patient Satisfaction Survey Michael E... Review: New collection. Abstract: VA Form 10-0476 will be used to gather feedback from patients...

  3. Pyrrolidinyl-sulfamide derivatives as a new class of bifunctional organocatalysts for direct asymmetric Michael addition of cyclohexanone to nitroalkenes.

    Science.gov (United States)

    Chen, Jia-Rong; Fu, Liang; Zou, You-Quan; Chang, Ning-Jie; Rong, Jian; Xiao, Wen-Jing

    2011-07-21

    A series of chiral pyrrolidinyl-sulfamide derivatives have been identified as efficient bifunctional organocatalysts for the direct Michael addition of cyclohexanone to a wide range of nitroalkenes. The desired Michael adducts were obtained in high chemical yields and excellent stereoselectivities (up to 99/1 dr and 95% ee).

  4. Reorientable dipolar CuCa antisite and anomalous screening in CaCu3Ti4O12

    Science.gov (United States)

    Delugas, Pietro; Alippi, Paola; Fiorentini, Vincenzo; Raineri, Vito

    2010-02-01

    Based on first-principles calculations, we show that the abundant CuCa antisite defect contributes sizably to dielectric screening in single-crystal CaCu3Ti4O12 . CuCa has a multi-minimum off-center equilibrium configuration, whereby it possesses a large and easily reorientable dipole moment. The low-temperature and frequency cut-off behavior of CuCa -induced response is consistent with experiment.

  5. Observation of re-entrant spin reorientation in TbFe1-xMnxO3

    Science.gov (United States)

    Fang, Yifei; Yang, Ya; Liu, Xinzhi; Kang, Jian; Hao, Lijie; Chen, Xiping; Xie, Lei; Sun, Guangai; Chandragiri, Venkatesh; Wang, Chin-Wei; Cao, Yiming; Chen, Fei; Liu, Yuntao; Chen, Dongfeng; Cao, Shixun; Lin, Chengtian; Ren, Wei; Zhang, Jincang

    2016-09-01

    We report a spin reorientation from Γ4(Gx, Ay, Fz) to Γ1(Ax, Gy, Cz) magnetic configuration near room temperature and a re-entrant transition from Γ1(Ax, Gy, Cz) to Γ4(Gx, Ay, Fz) at low temperature in TbFe1-xMnxO3 single crystals by performing both magnetization and neutron diffraction measurements. The Γ4 - Γ1 spin reorientation temperature can be enhanced to room temperature when x is around 0.5 ~ 0.6. These new transitions are distinct from the well-known Γ4 - Γ2 transition observed in TbFeO3, and the sinusoidal antiferromagnetism to complex spiral magnetism transition observed in multiferroic TbMnO3. We further study the evolution of magnetic entropy change (-ΔSM) versus Mn concentration to reveal the mechanism of the re-entrant spin reorientation behavior and the complex magnetic phase at low temperature. The variation of -ΔSM between a and c axes indicates the significant change of magnetocrystalline anisotropy energy in the TbFe1-xMnxO3 system. Furthermore, as Jahn-Teller inactive Fe3+ ions coexist with Jahn-Teller active Mn3+ ions, various anisotropy interactions, compete with each other, giving rise to a rich magnetic phase diagram. The large magnetocaloric effect reveals that the studied material could be a potential magnetic refrigerant. These findings expand our knowledge of spin reorientation phenomena and offer the alternative realization of spin-switching devices at room temperature in the rare-earth orthoferrites.

  6. Arousal and attention re-orienting in autism spectrum disorders: evidence from auditory event-related potentials.

    Science.gov (United States)

    Orekhova, Elena V; Stroganova, Tatiana A

    2014-01-01

    The extended phenotype of autism spectrum disorders (ASD) includes a combination of arousal regulation problems, sensory modulation difficulties, and attention re-orienting deficit. A slow and inefficient re-orienting to stimuli that appear outside of the attended sensory stream is thought to be especially detrimental for social functioning. Event-related potentials (ERPs) and magnetic fields (ERFs) may help to reveal which processing stages underlying brain response to unattended but salient sensory event are affected in individuals with ASD. Previous research focusing on two sequential stages of the brain response-automatic detection of physical changes in auditory stream, indexed by mismatch negativity (MMN), and evaluation of stimulus novelty, indexed by P3a component,-found in individuals with ASD either increased, decreased, or normal processing of deviance and novelty. The review examines these apparently conflicting results, notes gaps in previous findings, and suggests a potentially unifying hypothesis relating the dampened responses to unattended sensory events to the deficit in rapid arousal process. Specifically, "sensory gating" studies focused on pre-attentive arousal consistently demonstrated that brain response to unattended and temporally novel sound in ASD is already affected at around 100 ms after stimulus onset. We hypothesize that abnormalities in nicotinic cholinergic arousal pathways, previously reported in individuals with ASD, may contribute to these ERP/ERF aberrations and result in attention re-orienting deficit. Such cholinergic dysfunction may be present in individuals with ASD early in life and can influence both sensory processing and attention re-orienting behavior. Identification of early neurophysiological biomarkers for cholinergic deficit would help to detect infants "at risk" who can potentially benefit from particular types of therapies or interventions.

  7. Arousal and attention re-orienting in autism spectrum disorders: evidence from auditory event-related potentials

    Directory of Open Access Journals (Sweden)

    Elena V Orekhova

    2014-02-01

    Full Text Available The extended phenotype of autism spectrum disorders (ASD includes a combination of arousal regulation problems, sensory modulation difficulties, and attention re-orienting deficit. A slow and inefficient re-orienting to stimuli that appear outside of the attended sensory stream is thought to be especially detrimental for social functioning. Event-related potentials (ERPs and magnetic fields (ERFs may help to reveal which processing stages underlying brain response to unattended but salient sensory event are affected in individuals with ASD. Previous research focusing on two sequential stages of the brain response - automatic detection of physical changes in auditory stream, indexed by mismatch negativity (MMN, and evaluation of stimulus novelty, indexed by P3a component, - found in individuals with ASD either increased, decreased or normal processing of deviance and novelty. The review examines these apparently conflicting results, notes gaps in previous findings, and suggests a potentially unifying hypothesis relating the dampened responses to unattended sensory events to the deficit in rapid arousal process. Specifically, ‘sensory gating’ studies focused on pre-attentive arousal consistently demonstrated that brain response to unattended and temporally novel sound in ASD is already affected at around 100 ms after stimulus onset. We hypothesize that abnormalities in nicotinic cholinergic arousal pathways, previously reported in individuals with ASD, may contribute to these ERP/ERF aberrations and result in attention re-orienting deficit. Such cholinergic dysfunction may be present in individuals with ASD early in life and can influence both sensory processing and attention re-orienting behavior. Identification of early neurophysiological biomarkers for cholinergic deficit would help to detect infants at risk who can potentially benefit from particular types of therapies or interventions.

  8. Rational Design of an Ultrasensitive and Highly Selective Chemodosimeter by a Dual Quenching Mechanism for Cysteine Based on a Facile Michael-Transcyclization Cascade Reaction.

    Science.gov (United States)

    Li, Xiangmin; Zheng, Yongjun; Tong, Hongjuan; Qian, Rui; Zhou, Lin; Liu, Guixia; Tang, Yun; Li, Hao; Lou, Kaiyan; Wang, Wei

    2016-06-27

    Differentiation of biologically important thiols, such as cysteine (Cys), homocysteine (Hcy), and glutathione (GSH) is still a challenging task. Herein, we present a novel fluorescent chemodosimeter capable of selectively detecting Cys over other biothiols including Hcy and GSH and other amino acids by a facile thiol-Michael addition/transcyclization rearrangement cascade click process. The unique transcyclization step is critical for the selectivity as a result of the kinetically favorable formation of a six-membered ring with the Cys Michael adduct. Moreover, the probe adopts a distinctive dual quenching mechanism-photoinduced electron transfer (PET) and photoinduced intramolecular charge transfer (ICT) to deliver a drastic turn-on fluorescence response only at the Cys-selective transcylization step. The judicious selection of strong electron-withdrawing naphthalimide fluorophore with maleimide group enhances the electrophilicity and thus reactivity for the cascade process leading to fast detection and ultrasensitivity with a detection limit of 2.0 nm (S/N=3). The probe has demonstrated its practical utility potential in Cys imaging in live cells.

  9. Michael Shaffer, 6th July 1936 to 23rd March 2009: A heartfelt tribute

    Science.gov (United States)

    Mr. Michael Shaffer, Retired Pyraloidea Curator, at the Natural History Museum, London, England, passed away on March 23, 2009. He was an acknowledged world expert on Pyraloidea, a group of agriculturally important moths. He was curator of the largest Pyraloidea type collection in the world, and a...

  10. Michael Corleone's Destiny——From the perspective of interpersonal metafunction to analyze Godfather

    Institute of Scientific and Technical Information of China (English)

    胡爱洁

    2010-01-01

    Godfather is Maria Puzo's famous long story. Maria Puzo presented us the unknown Italians-American's life with underworld background. Although many comments from different perspectives have been made, few studies are made. with Halliday's framework. This paper is an attempt to study the destiny of Michael Corleone from the perspective of interpersonal metafunction in systemic functional linguistis.

  11. Training and Mastery of Techniques in Wittgenstein's Later Philosophy: A Response to Michael Luntley

    Science.gov (United States)

    Stickney, Jeff

    2008-01-01

    Responding to Michael Luntley's article, "Learning, Empowerment and Judgement," the author shows he cannot successfully make the following three moves: (1) dissolve the analytic distinction between learning by training and learning by reasoning, while advocating the latter; (2) diminish the role of training in Wittgenstein's philosophy, nor…

  12. Wolff-Michael Roth's passibility: at the limits of the constructivist metaphor: a book review

    Science.gov (United States)

    Brendel, Michelle

    2014-12-01

    Wolff-Michael Roth deconstructs the preeminent role conceded to constructivism in Science Education and demonstrates how we learn and know through pain, suffering, love or passion. This review explores his book "Passibility: At the Limits of the Constructivist Metaphor" through the eyes of an outsider to the world of science education.

  13. European Management: an emerging competitive advantage of European nations : A reply to Michael Porter

    NARCIS (Netherlands)

    F.A.J. van den Bosch (Frans); A.A. van Prooijen

    1992-01-01

    textabstractThis article extends the debate begun in the June 1992 issue of EMJ when the authors first criticized Michael Porter's explanatory framework in his Competitive Advantage of Nations (1990), over the role of national culture on the competitive advantage of nations. In this paper, Frans van

  14. Little Mosie from the Margaree: A Biography of Moses Michael Coady.

    Science.gov (United States)

    Welton, Michael R.

    This book examines the life of the Reverend Moses Michael Coady (1890-1959), a Roman Catholic priest who led the Antigonish Movement. During the Antigonish Movement, residents of the small maritime town of Antigonish, Nova Scotia, worked to achieve a nonviolent alternative to communism and fascism and to effect the social and economic…

  15. From Gouldner to Gramsci: The Making of Michael Apple's "Ideology and Curriculum"

    Science.gov (United States)

    Gottesman, Isaac

    2012-01-01

    Michael Apple's "Ideology and Curriculum", published in 1979, helped initiate a broad turn in the field of education in the United States to Marxist thought as a lens through which to analyze the relationship between school and society. This classic text continues to inform scholarship in the field. While "Ideology" has…

  16. Ytterbium triflate catalyzed Michael additions of beta-ketoesters in water

    NARCIS (Netherlands)

    Keller, E; Feringa, BL

    1996-01-01

    Michael addition of various beta-ketoesters towards enones and alpha,beta-unsaturated aldehydes resulted in a quantitative conversion to the corresponding 1,4-adducts by performing the reactions in water in the presence of ytterbium triflate as a water-tolerant Lewis acid.

  17. Highly efficient ytterbium triflate catalyzed Michael additions of alpha-nitroesters in water

    NARCIS (Netherlands)

    Keller, E; Feringa, B.L.

    Michael additions of alpha-nitroesters with enones and alpha,beta-unsaturated aldehydes result in quantitative conversions to the corresponding 1,4-adducts by performing the reactions in water in the presence of ytterbium triflate as water-tolerant Lewis acid.

  18. Novel chiral thioureas for highly enantioselective Michael reactions of malonates to nitroalkenes

    Institute of Scientific and Technical Information of China (English)

    Li Jun Yan; Quan Zhong Liu; Xue Lian Wang

    2009-01-01

    Highly efficient Michael addition reactions of malonates to nitroalkenes catalyzed by novel chiral thioureas derived from optically pure BINOL and amino acids are reported. Various trans-nitroalkenes reacted with malonates affording the desired products in up to 95% yield with excellent enantioselectivities (up to 97% ee).

  19. On the study of culture and mind: Interview with Prof. Michael Cole

    DEFF Research Database (Denmark)

    Glaveanu, Vlad Petre

    2011-01-01

    the two. And yet, as Professor Michael Cole and, more broadly, cultural psychologists would argue: there is no way of making sense of one if we disregard the other. Culture and mind constitute each other through action and communication and it is their intricate relationship that holds the key...

  20. European Management: an emerging competitive advantage of European nations : A reply to Michael Porter

    NARCIS (Netherlands)

    F.A.J. van den Bosch (Frans); A.A. van Prooijen

    1992-01-01

    textabstractThis article extends the debate begun in the June 1992 issue of EMJ when the authors first criticized Michael Porter's explanatory framework in his Competitive Advantage of Nations (1990), over the role of national culture on the competitive advantage of nations. In this paper, Frans van

  1. KF-Montmorillonite-catalyzed Michael Addition Reaction of Malononitrile to α,β-Unsaturated Ketones

    Institute of Scientific and Technical Information of China (English)

    SHI Daqing; WU Nan; ZHUANG Qiya

    2009-01-01

    The Michael addition reaction of α,β-unsaturated ketones with malononitrile catalyzed by KF-montmorillonite was investigated. It was interesting to note that at different reaction temperatures the addition and cycloaddition re-action products were obtained. This method has the advantages of good yields, mild reaction conditions, easy work-up and inexpensive reagents over the existing procedures.

  2. SYNTHESIS OF SOME PROLINE DERIVATIVES BY MEANS OF MICHAEL ADDITIONS OF GLYCINE ESTERS

    NARCIS (Netherlands)

    VANDERWERF, A; KELLOGG, RM

    1991-01-01

    Addition of the Schiff bases derived from reaction of glycine alkyl esters with benzophenoneimine to alpha,beta-unsaturated ketones, followed by hydrogenation of the addition products, leads to 5- or 3,5-substituted prolines. Hydrolysis of the Michael adducts rather than hydrogenation allows

  3. 78 FR 69661 - Michael Canales v. Edison International, EIX, Southern California Edison; Notice of Complaint

    Science.gov (United States)

    2013-11-20

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Federal Energy Regulatory Commission Michael Canales v. Edison International, EIX, Southern California Edison; Notice of Complaint Take notice that on November 11, 2013, pursuant to sections 205, 206, and 301 of the Federal Power Act (FPA), 16 U.S.C....

  4. Michael Eric Dyson: A Scholar and a Hip-Hop Preacher.

    Science.gov (United States)

    Fletcher, Michael A.

    2000-01-01

    Introduces Michael Eric Dyson, an African American man who grew up in the ghetto and eventually received a PhD from Princeton University. Today, he is a professor at DePaul University, the author of a radically revisionist new biography of Martin Luther King, Jr., a lecturer and talk show guest, a Baptist preacher, and a self-styled hip-hop…

  5. A Metal-Ligand Cooperative Pathway for Intermolecular Oxa-Michael Additions to Unsaturated Nitriles

    NARCIS (Netherlands)

    Perdriau, Sebastien; Zijlstra, Douwe S.; Heeres, Hero J.; de Vries, Johannes G.; Otten, Edwin

    2015-01-01

    An unprecedented catalytic pathway for oxa-Michael addition reactions of alcohols to unsaturated nitriles has been revealed using a PNN pincer ruthenium catalyst with a dearomatized pyridine backbone. The isolation of a catalytically competent Ru-dieneamido complex from the reaction between the Ru

  6. How to move things around a hospital: transport logistics at St. Michael's.

    Science.gov (United States)

    Yau, A; Zorn, R; McLaughlin, J

    1998-01-01

    Ongoing fiscal restraint challenges hospitals to focus their resources primarily on core services. Support services receive much less attention. This article describes the experience of Toronto's St. Michael's Hospital when it re-engineered its transport logistics by consolidating centralized support services into a logistics department and creating new roles and processes to enhance patient care.

  7. Moral Education and Education in Altruism: Two Replies to Michael Hand

    Science.gov (United States)

    White, John

    2016-01-01

    This article is a critical discussion of two recent papers by Michael Hand on moral education. The first is his "Towards a Theory of Moral Education", published in the "Journal of Philosophy of Education" in 2014 (Volume 48, Issue 4). The second is a chapter called "Beyond Moral Education?" in an edited book of new…

  8. The power of virtual integration: an interview with Dell Computer's Michael Dell. Interview by Joan Magretta.

    Science.gov (United States)

    Dell, M

    1998-01-01

    Michael Dell started his computer company in 1984 with a simple business insight. He could bypass the dealer channel through which personal computers were then being sold and sell directly to customers, building products to order. Dell's direct model eliminated the dealer's markup and the risks associated with carrying large inventories of finished goods. In this interview, Michael Dell provides a detailed description of how his company is pushing that business model one step further, toward what he calls virtual integration. Dell is using technology and information to blur the traditional boundaries in the value chain between suppliers, manufacturers, and customers. The individual pieces of Dell's strategy--customer focus, supplier partnerships, mass customization, just-in-time manufacturing--may be all be familiar. But Michael Dell's business insight into how to combine them is highly innovative. Direct relationships with customers create valuable information, which in turn allows the company to coordinate its entire value chain back through manufacturing to product design. Dell describes how his company has come to achieve this tight coordination without the "drag effect" of ownership. Dell reaps the advantages of being vertically integrated without incurring the costs, all the while achieving the focus, agility, and speed of a virtual organization. As envisioned by Michael Dell, virtual integration may well become a new organizational model for the information age.

  9. SYNTHESIS OF SOME PROLINE DERIVATIVES BY MEANS OF MICHAEL ADDITIONS OF GLYCINE ESTERS

    NARCIS (Netherlands)

    VANDERWERF, A; KELLOGG, RM

    1991-01-01

    Addition of the Schiff bases derived from reaction of glycine alkyl esters with benzophenoneimine to alpha,beta-unsaturated ketones, followed by hydrogenation of the addition products, leads to 5- or 3,5-substituted prolines. Hydrolysis of the Michael adducts rather than hydrogenation allows synthes

  10. "Raising Standards" or Reducing Aspirations and Opportunities Still Further? Michael Gove and Examination Reforms

    Science.gov (United States)

    Allen, Martin

    2013-01-01

    Well before the examinations grade crisis of 2012, Michael Gove had set out clear intentions for reforming public examinations. Though he claimed to be improving examinations and assessment by replicating practices that took place in high-performing countries and thus improving the ability of the UK economy to "compete", this…

  11. Noted astrophysicist Michael S. Turner to Head NSF'S mathematical and physical sciences directorate

    CERN Multimedia

    2003-01-01

    "The National Science Foundation has named celebrated astrophysicist Michael S. Turner of the University of Chicago as Assistant Director for Mathematical and Physical Sciences. He will head a $1 billion directorate that supports research in mathematics, physics, chemistry, materials and astronomy, as well as multidisciplinary programs and education" (1/2 page).

  12. Guanidinium Lactate Ionic Liquid:An Efficient and Recycling Catalyst for Michael Addition Reaction

    Institute of Scientific and Technical Information of China (English)

    LIANG Da-peng; XIN Xin; GAO Han; DUAN Hai-feng; LIN Ying-jie

    2009-01-01

    A facile and efficient 1,4-conjungate addition(Michael addition) reaction of active methylene compounds to a,β-unsaturated compounds,catalyzed by guanidinium lactate ionic liquid(IL9),has been developed.A range of chaicones and nitroaikenes together with active methylene compounds have been converted smoothly to the corresponding products in high yields.

  13. Synthesis of bicyclic guanidines via cascade hydroamination/Michael additions of mono-N-acryloylpropargylguanidines.

    Science.gov (United States)

    Kwon, Ki-Hyeok; Serrano, Catherine M; Koch, Michael; Barrows, Louis R; Looper, Ryan E

    2014-12-05

    A cascade silver(I)-catalyzed hydroamination/Michael addition sequence has been developed to deliver highly substituted bicyclic guanidines. This transformation gives rise to geometrically and constitutionally stable ene-guanidines and generates a remote stereocenter with moderate to high diastereoselectivity.

  14. Aza-Michael reaction of 12-N-carboxamide of (-)-cytisine under high pressure conditions.

    Science.gov (United States)

    Tsypysheva, Inna P; Lobov, Alexander N; Kovalskaya, Alena V; Petrova, Polina R; Ivanov, Sergey P; Rameev, Shamil A; Borisevich, Sophia S; Safiullin, Rustam L; Yunusov, Marat S

    2015-01-01

    The first example of aza-Michael reaction of 12-N-carboxamide of quinolizidine alkaloid (-)-cytisine with α,β-unsaturated ketones, dimethyl acetylenedicarboxylate and β-nitrostyrene under high pressure condition has been described. It has been shown that the [4+2]-cycloaddition takes place in the case with N-phenylmaleimide.

  15. Little Mosie from the Margaree: A Biography of Moses Michael Coady.

    Science.gov (United States)

    Welton, Michael R.

    This book examines the life of the Reverend Moses Michael Coady (1890-1959), a Roman Catholic priest who led the Antigonish Movement. During the Antigonish Movement, residents of the small maritime town of Antigonish, Nova Scotia, worked to achieve a nonviolent alternative to communism and fascism and to effect the social and economic…

  16. Hexafluorobenzene: A powerful solvent for a noncovalent stereoselective organocatalytic Michael addition reaction

    KAUST Repository

    Lattanzi, Alessandra

    2012-01-01

    A dramatic enhancement of the diastereo- and enantioselectivity in the nitro-Michael addition reaction organocatalysed by a commercially available α,α-l-diaryl prolinol was disclosed when performing the reaction in unconventional hexafluorobenzene as a medium. DFT calculations were performed to clarify the origin of stereoselectivity and the role of C 6F 6. © The Royal Society of Chemistry 2012.

  17. Michael Pressley's Contributions to the History and Future of Strategies Research

    Science.gov (United States)

    Harris, Karen R.; Alexander, Patricia; Graham, Steve

    2008-01-01

    The history of strategies research during the past quarter century has been a story of significant conceptualizations and reconceptualizations regarding the nature, development, and teaching of cognitive and metacognitive strategies. Theoretical models, empirical research, and discussions contributed by Michael Pressley have been central to…

  18. Outside in America: George Michael's music video, public sex and global pop culture

    NARCIS (Netherlands)

    Kooijman, J.

    2004-01-01

    Six months after his controversial arrest for ‘lewd conduct’ at a men’s public restroom in Beverly Hills, British pop star George Michael released the song and music video ‘Outside’ which can be seen as an explicit commentary on the controversy. In this article, I read the music video in three ways:

  19. Vice Premier Zeng Peiyan Meets with Michael Cohrs, CEO of Corporate & Investment Banking of Deutsche Bank

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    <正>Invited by the CPAFFC, Michael Cohrs, Chief Executive Officer of the Corporate and Investment Banking of Deutsche Bank, visited Beijing from February 26 to 28, 2004. Vice Premier Zeng Peiyan of the State Council met with Cohrs and his party. Deutsche Bank AG, a global multipurpose bank

  20. Gender Relations and Sexual Harassment in the Workplace: Michael Crichton's "Disclosure" as a Teaching Tool.

    Science.gov (United States)

    Comer, Debra R.; Cooper, Elizabeth A.

    1998-01-01

    Describes how to use Michael Crichton's novel "Disclosure" and the film based on it for class discussions of such issues as what constitutes sexual harassment, harassment of men, relationship between sexual harassment and power, organizational responses to harassment, and gender differences in career advancement tactics. (SK)

  1. Briti ekspert : euroliidus kaob Eestist tööpuudus / Michael Richardson ; interv. Airi Ilisson

    Index Scriptorium Estoniae

    Richardson, Michael

    2003-01-01

    Eestis Suurbritannia tööreformi tutvustava töö- ja sotsiaalnõuniku sõnul on Suurbritannias peaaegu kadunud pikaajaline töötus noorte hulgas, vanematest inimestest on vaid üksikud tööta kauem kui aasta. Vt. samas: Kes on Michael Richardson?

  2. Michael Peters' Lyotardian Account of Postmodernism and Education: Some Epistemic Problems and Naturalistic Solutions

    Science.gov (United States)

    Clark, John A.

    2006-01-01

    Postmodernism has established a significant hold in educational thought and some of the most important ideas are to be found in the writings of Michael Peters. This paper examines his postmodern stance and use of Lyotard's account of knowledge, and from a naturalist point of view raises a number of objections centred on science as a metanarrative,…

  3. Schools as "Poetry-Friendly Places": Michael Rosen on Poetry in the Curriculum

    Science.gov (United States)

    Xerri, Daniel

    2014-01-01

    This article explores the views of children's poet Michael Rosen in relation to poetry in education. It is based on an interview in which Rosen not only discusses the significance of encouraging young people to engage with poetry at school but also analyzes a number of threats to poetry's place in the English curriculum. This article identifies…

  4. Training and Mastery of Techniques in Wittgenstein's Later Philosophy: A Response to Michael Luntley

    Science.gov (United States)

    Stickney, Jeff

    2008-01-01

    Responding to Michael Luntley's article, "Learning, Empowerment and Judgement," the author shows he cannot successfully make the following three moves: (1) dissolve the analytic distinction between learning by training and learning by reasoning, while advocating the latter; (2) diminish the role of training in Wittgenstein's philosophy, nor…

  5. Subjectivity and Cultural Adjustment in Mathematics Education: A Response to Wolff-Michael Roth

    Science.gov (United States)

    Brown, Tony

    2012-01-01

    In this volume, Wolff-Michael Roth provides a critical but partial reading of Tony Brown's book "Mathematics Education and Subjectivity". The reading contrasts Brown's approach with Roth's own conception of subjectivity as derived from the work of Vygotsky, in which Roth aims to "reunite" psychology and sociology. Brown's book, however, focuses on…

  6. Enzymatic carbon-carbon bond-forming Michael-type additions

    NARCIS (Netherlands)

    Geertsema, Edzard; Poelarends, Gerrit; Faber, Kurt; Fessner, Wolf-Dieter; Turner, Nicholas

    2014-01-01

    This chapter gives an overview of practical biocatalytic procedures for C-C bond-forming Michael(-type) additions suitable for organic synthesis purposes. Reported product yields, workup and isolation methods, stereoselectivity, and availability of the applied enzymes are assessed. All methodologies

  7. Kunstlik viljastamine - kas rahva püsimajäämise võti? / Michael Cook

    Index Scriptorium Estoniae

    Cook, Michael

    2007-01-01

    Kunstlikust viljastamisest pole üksi abi - vaid siis, kui noored mehed ja naised pööravad selja tarbimiskultusele ja individualismile, hakkab sündimus tõusma taastootmisest kõrgemale, kirjutab BioEdge toimetaja Michael Cook

  8. The Educational Philosophies of Mordecai Kaplan and Michael Rosenak: Surprising Similarities and Illuminating Differences

    Science.gov (United States)

    Schein, Jeffrey; Caplan, Eric

    2014-01-01

    The thoughts of Mordecai Kaplan and Michael Rosenak present surprising commonalities as well as illuminating differences. Similarities include the perception that Judaism and Jewish education are in crisis, the belief that Jewish peoplehood must include commitment to meaningful content, the need for teachers to teach from a position of…

  9. Michael Perelman: An ecological future in view of Marxist Economics (Ⅱ)

    Institute of Scientific and Technical Information of China (English)

    Ren Xiaomei

    2009-01-01

    @@ Interviewee profile: Michael Perelman, currently professor of Economics Department of California State University, USA, American economist and economic historian with nearly 20 publications in the field of economics criticism, including Railroading Economics, Manufacturing Discontent, The Perverse Economy, and The Invention of Capitalism.

  10. Neuroscientific Investigator of High Mathematical Ability: An Interview with Michael W. O'Boyle

    Science.gov (United States)

    Kalbfleisch, M. Layne

    2008-01-01

    This article presents an interview with Michael W. O'Boyle, a neuroscientific investigator of high mathematical ability. O'Boyle is a professor in the Department of Human Development and Family Studies, Texas Tech University, and Adjunct Professor of Pharmacology and Neuroscience, School of Medicine, Texas Tech University Health Sciences Center.…

  11. A tribute to Michael R. Raupach for contributions to aeolian fluid dynamics

    Science.gov (United States)

    Since the early work of Bagnold in the 1940s, aeolian research has grown to become a major integral part of earth-system studies. Many individuals have contributed to this development, and Dr. Michael R. Raupach (MR2, 1950 – 2015) was one of the most outstanding. MR2 worked for about a decade (1985 ...

  12. Synthesis of β3-Amino Acids via Catalyst- and Solvent-Free Aza-Michael Reaction

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    A safe, environmentally friendly and cost-effective method for the synthesis of β-amino acid derivatives has been developed. Treatment of α,β-unsaturated compounds with aliphatic amines furnishes β-amino acid derivatives in good to excellent yields via a catalyst- and solvent-free aza-Michael addition.

  13. What Work Do the Concepts of "Language" and "Literature" Do for Michael Rosenak?

    Science.gov (United States)

    Levisohn, Jon A.

    2014-01-01

    Michael Rosenak uses the twin metaphors of "language" and "literature," borrowed from Oakeshott and Peters, to argue that the goal of education is initiation into a language. This goal transcends the study of literature in that language. It includes, as well, the development of the capacity both to critique literature and to…

  14. Book Review of "The Molecular Biology of Cancer" by Stella Pelengaris, Michael Khan (Editors

    Directory of Open Access Journals (Sweden)

    Schmidt Christian

    2007-11-01

    Full Text Available Abstract Here, a review of "The Molecular Biology of Cancer" (Stella Pelengaris and Michael Khan [Editors] is given. The detailed description of the book is provided here: Pelengaris S, Khan M (Eds: The Molecular Biology of Cancer; Blackwell Publishing, Oxford (U.K.; 2006. 531 pages, 214 illustrations, ISBN 9-78140-511-814-9, £31.99.

  15. Highly efficient ytterbium triflate catalyzed Michael additions of alpha-nitroesters in water

    NARCIS (Netherlands)

    Keller, E; Feringa, B.L.

    1997-01-01

    Michael additions of alpha-nitroesters with enones and alpha,beta-unsaturated aldehydes result in quantitative conversions to the corresponding 1,4-adducts by performing the reactions in water in the presence of ytterbium triflate as water-tolerant Lewis acid.

  16. Outside in America: George Michael's music video, public sex and global pop culture

    NARCIS (Netherlands)

    Kooijman, J.

    2004-01-01

    Six months after his controversial arrest for ‘lewd conduct’ at a men’s public restroom in Beverly Hills, British pop star George Michael released the song and music video ‘Outside’ which can be seen as an explicit commentary on the controversy. In this article, I read the music video in three ways:

  17. Michael Faraday on the Learning of Science and Attitudes of Mind.

    Science.gov (United States)

    Crawford, Elspeth

    1998-01-01

    Makes use of Michael Faraday's ideas on learning, focusing on his attitudes toward the unknowns of science and the development of an attitude that improves scientific decision making. This approach acknowledges that there is an inner struggle involved in facing unknowns. (DDR)

  18. Two Commentaries on Ron Sheen's "A Critical Analysis of the Advocacy of the Task-Based Syllabus." A Reader Reacts... [and] On the Advocacy of the Task-Based Syllabus [and] The Author Responds....

    Science.gov (United States)

    Nunan, David; And Others

    1994-01-01

    An author, David Nunan, responds to a previous article that criticizes his advocacy of task-based syllabuses. Another author, Michael Long, points out inaccuracies in the criticism, and the author of the criticism, Ron Sheen, defends his earlier claim. (45 references) (JL)

  19. Two Commentaries on Ron Sheen's "A Critical Analysis of the Advocacy of the Task-Based Syllabus." A Reader Reacts... [and] On the Advocacy of the Task-Based Syllabus [and] The Author Responds....

    Science.gov (United States)

    Nunan, David; And Others

    1994-01-01

    An author, David Nunan, responds to a previous article that criticizes his advocacy of task-based syllabuses. Another author, Michael Long, points out inaccuracies in the criticism, and the author of the criticism, Ron Sheen, defends his earlier claim. (45 references) (JL)

  20. Dual reorientation relaxation routes of water molecules in oxyanion’s hydration shell: A molecular geometry perspective

    Energy Technology Data Exchange (ETDEWEB)

    Xie, Wen Jun; Yang, Yi Isaac; Gao, Yi Qin, E-mail: gaoyq@pku.edu.cn [Institute of Theoretical and Computational Chemistry, College of Chemistry and Molecular Engineering and Biodynamic Optical Imaging Center, Peking University, Beijing 100871 (China)

    2015-12-14

    In this study, we examine how complex ions such as oxyanions influence the dynamic properties of water and whether differences exist between simple halide anions and oxyanions. Nitrate anion is taken as an example to investigate the hydration properties of oxyanions. Reorientation relaxation of its hydration water can occur through two different routes: water can either break its hydrogen bond with the nitrate to form one with another water or switch between two oxygen atoms of the same nitrate. The latter molecular mechanism increases the residence time of oxyanion’s hydration water and thus nitrate anion slows down the translational motion of neighbouring water. But it is also a “structure breaker” in that it accelerates the reorientation relaxation of hydration water. Such a result illustrates that differences do exist between the hydration of oxyanions and simple halide anions as a result of different molecular geometries. Furthermore, the rotation of the nitrate solute is coupled with the hydrogen bond rearrangement of its hydration water. The nitrate anion can either tilt along the axis perpendicularly to the plane or rotate in the plane. We find that the two reorientation relaxation routes of the hydration water lead to different relaxation dynamics in each of the two above movements of the nitrate solute. The current study suggests that molecular geometry could play an important role in solute hydration and dynamics.

  1. Role of rare earth on the Mn3+ spin reorientation in multiferroic Ho1-xLuxMnO3

    Science.gov (United States)

    Magesh, J.; Murugavel, P.; Mangalam, R. V. K.; Singh, K.; Simon, Ch.; Prellier, W.

    2013-09-01

    The role of rare earth ion R3+ in spin reorientation and magneto dielectric response is investigated by substitution of non-magnetic smaller ionic radii Lu3+ in multiferroic hexagonal HoMnO3. The XRD analysis suggests that the dopant may preferably goes to C3V site up to 1/3rd of the composition in order to reduce the lattice distortion. We suggest that the R3+ ion at C3 site could play a strong role in spin reorientation than the C3V site. The observation of TSR even in LuMnO3 precludes the role of rare earth magnetic moment in driving the spin reorientation. Surprisingly, the magneto dielectric response of HoMnO3 is dominated by the rare earth RO8 dipoles. The oppositely oriented RO8 dipole at the C3V and C3 determines the magneto dielectric response in various magnetic phases reaffirming the site specific substitution. Thus, site specific doping could be a way to enhance the magnetoelectric coupling strength.

  2. Tooth reorientation affects tooth function during prey processing and tooth ontogeny in the lesser electric ray, Narcine brasiliensis.

    Science.gov (United States)

    Dean, Mason N; Ramsay, Jason B; Schaefer, Justin T

    2008-01-01

    The dental anatomy of elasmobranch fishes (sharks, rays and relatives) creates a functional system that is more dynamic than that of mammalian dentition. Continuous dental replacement (where new teeth are moved rostrally to replace older ones) and indirect fibrous attachment of the dentition to the jaw allow teeth to reorient relative to the jaw over both long- and short-term scales, respectively. In this study, we examine the processing behavior and dental anatomy of the lesser electric ray Narcine brasiliensis (Olfers, 1831) to illustrate that the freedom of movement of elasmobranch dentition allows a functional flexibility that can be important for complex prey processing behaviors. From static manipulations of dissected jaws and observations of feeding events in live animals, we show that the teeth rotate during jaw protrusion, resulting in a secondary grasping mechanism that likely serves to hold prey while the buccal cavity is flushed free of sediment. The function of teeth is not always readily apparent from morphology; in addition to short-term reorientation, the long-term dental reorientation during replacement allows a given tooth to serve multiple functions during tooth ontogeny. Unlike teeth inside the mouth, the cusps of external teeth (on the portion of the tooth pad that extends past the occlusal plane) lay flat, such that the labial faces act as a functional battering surface, protecting the jaws during prey excavation.

  3. Spin reorientation driven by the interplay between spin-orbit coupling and Hund's rule coupling in iron pnictides

    Science.gov (United States)

    Christensen, Morten H.; Kang, Jian; Andersen, Brian M.; Eremin, Ilya; Fernandes, Rafael M.

    2015-12-01

    In most magnetically-ordered iron pnictides, the magnetic moments lie in the FeAs planes, parallel to the modulation direction of the spin stripes. However, recent experiments in hole-doped iron pnictides have observed a reorientation of the magnetic moments from in-plane to out-of-plane. Interestingly, this reorientation is accompanied by a change in the magnetic ground state from a stripe antiferromagnet to a tetragonal nonuniform magnetic configuration. Motivated by these recent observations, here we investigate the origin of the spin anisotropy in iron pnictides using an itinerant microscopic electronic model that respects all the symmetry properties of a single FeAs plane. We find that the interplay between the spin-orbit coupling and the Hund's rule coupling can account for the observed spin anisotropies, including the spin reorientation in hole-doped pnictides, without the need to invoke orbital or nematic order. Our calculations also reveal an asymmetry between the magnetic ground states of electron- and hole-doped compounds, with only the latter displaying tetragonal magnetic states.

  4. Reorientational eigenmode dynamics: a combined MD/NMR relaxation analysis method for flexible parts in globular proteins.

    Science.gov (United States)

    Prompers, J J; Brüschweiler, R

    2001-08-01

    An approach is presented for the interpretation of heteronuclear NMR spin relaxation data in mobile protein parts in terms of reorientational eigenmode dynamics. The method is based on the covariance matrix of the spatial functions of the nuclear spin interactions that cause relaxation expressed as spherical harmonics of rank 2. The approach was applied to characterize the dynamics of a loop region of ubiquitin. The covariance matrix was determined from a conformational ensemble generated by a 5 ns molecular dynamics simulation. It was found that the time correlation functions of the dominant eigenmodes decay in good approximation with a single correlation time. From the reorientational eigenmodes, their eigenvalues, and correlation times, NMR relaxation data were calculated in accordance with Bloch-Wangsness-Redfield relaxation theory and directly compared with experimental (15)N relaxation parameters. Using a fitting procedure, agreement between calculated and experimental data was improved significantly by adjusting eigenvalues and correlation times of the dominant modes. The presented procedure provides detailed information on correlated reorientational dynamics of flexible parts in globular proteins. The covariance matrix was linked to the covariance matrix of backbone dihedral angle fluctuations, allowing one to study the motional behavior of these degrees of freedom on nano- and subnanosecond time scales.

  5. On the nonlinear problem of the three-axis reorientation of a three-rotor gyrostat in the game noise model

    Science.gov (United States)

    Vorotnikov, V. I.; Martyshenko, Yu. G.

    2013-09-01

    The nonlinear game problem of the three-axis reorientation of an asymmetric solid body with three flywheels (rotors) has been solved. Acceptable levels of uncontrollable noise depending on given constraints of control moments have been estimated.

  6. Reorientation Timescales and Pattern Dynamics for Titan's Dunes: Does the Tail Wag the Dog or the Dragon?

    Science.gov (United States)

    Ewing, R. C.; Hayes, A. G.; McCormick, C.; Ballard, C.; Troy, S. A.

    2012-04-01

    Fields of bedform patterns persist across many orders of magnitude, from cm-scale sub-aqueous current ripples to km-scale aeolian dunes, and form with surprisingly little difference in expression despite a range of formative environments. Because of the remarkable similarity among bedform patterns, extracting information about climate and environment from these patterns is a challenge. For example, crestline orientation is not diagnostic of a particular flow regime; similar patterns form under many different flow configurations. On Titan, these challenges have played out with many attempts to reconcile dune crestline orientation with modeled and expected wind regimes. We propose that thinking about the time-scale of the change in dune orientation, rather than the orientation itself, can provide new insights on the long-term stability of the dune-field patterns and the formative wind regime. In this work, we apply the crestline re-orientation model developed by Werner and Kocurek [Geology, 1997] to the equatorial dune fields of Titan. We use Cassini Synthetic Aperture Radar images processed through a de-noising algorithm recently developed by Lucas et al. [LPSC, 2012] to measure variations in pattern parameters (crest spacing, crest length and defect density, which is the number of defect pairs per total crest length) both within and between Titan's dune fields to describe pattern maturity and identify areas where changes in dune orientation are likely to occur (or may already be occurring). Measured defect densities are similar to Earth's largest linear dune fields, such as the Namib Sand Sea and the Simpson Desert. We use measured defect densities in the Werner and Kocurek model to estimate crestline reorientation rates. We find reorientation timescales varying from ten to a hundred thousand times the average migration timescale (time to migrate a bedform one meter, ~1 Titan year according to Tokano (Aeolian Research, 2010)). Well-organized patterns have the

  7. Reorientation mechanisms of phyllosilicates in the mudstone-to-slate transition at Lehigh Gap, Pennsylvania

    Science.gov (United States)

    Ho, Nei-Che; Peacor, Donald R.; van der Pluijm, Ben A.

    1995-03-01

    The mudstone-to-slate transition of the Martinsburg Formation at Lehigh Gap, Pennsylvania, was re-examined using a new transmission-mode X-ray texture goniometer, supplemented by SEM, XRD, and optical studies. Three mesoscopic zones are recognized in the outcrop: (I) mudstone, (II) transition, and (III) slate zone. In the mudstone zone, the mica basal planes are parallel to bedding whereas the preferred orientation of the chlorite basal planes is up to 30° shallower than bedding. The angular difference between chlorite and mica decreases towards the transition zone, becoming subparallel at ca. 50 m from the contact with the overlying Shawangunk Formation. In the transition zone, the preferred orientations of both mica and chlorite are intermediate to bedding and cleavage orientations, which is consistent with mechanical reorientation of phyllosilicates. This is supported by a decrease in March strain with a minimum at ca. 95 m from the contact for both mica and chlorite. SEM observations similarly show the importance of grain rotation in large detrital grains. In the slate zone, both chlorite and mica orientations are parallel to cleavage. Chlorite and mica in the cleavage orientation of the slate zone have high Fe contents, whereas low-Fe mica and Mg > Fe chlorite dominate in the mudstone and transition zone, which indicates that dissolution-neocrystallization is the dominant mechanism in the slate zone. Thus, mechanical rotation of large detrital grains is important in the early stages of cleavage development, with dissolution—neocrystallization occurring at all stages and becoming dominant in the more evolved stages.

  8. Re-orienting crop improvement for the changing climatic conditions of the 21st century

    Directory of Open Access Journals (Sweden)

    Mba Chikelu

    2012-06-01

    Full Text Available Abstract A 70% increase in food production is required over the next four decades to feed an ever-increasing population. The inherent difficulties in achieving this unprecedented increase are exacerbated by the yield-depressing consequences of climate change and variations and by the pressures on food supply by other competing demographic and socioeconomic demands. With the dwindling or stagnant agricultural land and water resources, the sought-after increases will therefore be attained mainly through the enhancement of crop productivity under eco-efficient crop production systems. ‘Smart’ crop varieties that yield more with fewer inputs will be pivotal to success. Plant breeding must be re-oriented in order to generate these ‘smart’ crop varieties. This paper highlights some of the scientific and technological tools that ought to be the staple of all breeding programs. We also make the case that plant breeding must be enabled by adequate policies, including those that spur innovation and investments. To arrest and reverse the worrisome trend of declining capacities for crop improvement, a new generation of plant breeders must also be trained. Equally important, winning partnerships, including public-private sector synergies, are needed for 21st century plant breeding to bear fruits. We also urge the adoption of the continuum approach to the management of plant genetic resources for food and agriculture as means to improved cohesion of the components of its value chain. Compellingly also, the National Agricultural Research and Extension System of developing countries require comprehensive overhauling and strengthening as crop improvement and other interventions require a sustained platform to be effective. The development of a suite of actionable policy interventions to be packaged for assisting countries in developing result-oriented breeding programs is also called for.

  9. Magnetic reorientation induced by pressure solution: A potential mechanism for orogenic-scale remagnetizations

    Science.gov (United States)

    Oliva-Urcia, Belén; Pueyo, Emilio L.; Larrasoaña, Juan C.

    2008-01-01

    New paleomagnetic analyses of Triassic, Cretaceous and Eocene strata in the south-central Pyrenees show evidence for a widespread remagnetization, located along the southern border of the Axial Zone, the Internal Sierras, and the northern part of the Jaca-Pamplona basin. This remagnetization, always reversed in polarity, was acquired after an extensive period of Late Eocene-Early Oligocene folding and tilting in the area, and affects limestones, sandstones, marls and red beds. In addition, a characteristic prefolding component was identified in 30% of Upper Cretaceous and Triassic red beds. These results, together with a revaluation of previously published paleomagnetic data from the central Pyrenees, indicate that the spatial distribution of the postfolding remagnetization coincides with that of a domain of pressure solution cleavage. A relationship between the intensity of the remagnetization and the characteristic (prefolding component) with respect to the density of cleavage surfaces, leads us to propose a mechanism for the remagnetization related to the development of pressure solution cleavage that is framed within the tectonic evolution of the central Pyrenees. Partial dissolution of rock under tectonic compression leads to the liberation and subsequent accumulation of insoluble minerals in cleavage planes. Magnetic grains are part of the relatively insoluble residue, and they reorient in the presence of the ambient field after they are freed during dissolution of the rock matrix. Chemical reequilibrium (dissolution and/or neoformation of magnetic carriers) during this process cannot be excluded. The remagnetization mechanism we propose can help to explain widespread remagnetizations in low to moderately deformed rocks without the need of large-scale migration of orogenic fluids.

  10. Pressure-induced spin fluctuations and spin reorientation in hexagonal manganites

    Science.gov (United States)

    Kozlenko, D. P.; Kichanov, S. E.; Lee, S.; Park, J.-G.; Savenko, B. N.

    2007-04-01

    The magnetic structures of hexagonal manganites YMnO3 and LuMnO3 have been studied by powder neutron diffraction up to 6 GPa in the temperature range 10-295 K. At ambient pressure, a triangular antiferromagnetic (AFM) state of a Γ1 irreducible representation is stable below TN = 70 K in YMnO3. Upon the application of high pressure, a spin reorientation is induced and the triangular AFM structure evolves from Γ1 to Γ1+Γ2 representations. On the other hand, in LuMnO3 the triangular AFM state of a Γ2 irreducible representation with TNap90 K remains stable over the entire pressure range investigated. The ordered magnetic moment values decrease under pressure with dM/dP = -0.35 μB GPa-1 in YMnO3 and -0.08 μB GPa-1 in LuMnO3. Simultaneously, a considerable increase in diffuse scattering intensity was found in YMnO3, while it was much less pronounced for LuMnO3. Both features indicate the enhancement of spin fluctuations due to geometrical frustration effects and an increase in the volume fraction of the spin-liquid state coexisting with the ordered AFM phase. The characteristic spin correlation length is weakly affected by pressure. The relationship between the pressure-induced behaviour of magnetic structure and the structural characteristics of the quasi-two-dimensional (2D) triangular network formed by Mn and O ions in hexagonal RMnO3 is analysed.

  11. Re-orientation transition in molecular thin films: Potts model with dipolar interaction.

    Science.gov (United States)

    Hoang, Danh-Tai; Kasperski, Maciej; Puszkarski, Henryk; Diep, H T

    2013-02-06

    We study the low-temperature behavior and the phase transition of a thin film by Monte Carlo simulation. The thin film has a simple cubic lattice structure where each site is occupied by a Potts parameter which indicates the molecular orientation of the site. We take only three molecular orientations in this paper, which correspond to the three-state Potts model. The Hamiltonian of the system includes (i) the exchange interaction J(ij) between nearest-neighbor sites i and j, (ii) the long-range dipolar interaction of amplitude D truncated at a cutoff distance r(c), and (iii) a single-ion perpendicular anisotropy of amplitude A. We allow J(ij) = J(s) between surface spins, and J(ij) = J otherwise. We show that the ground state depends on the ratio D/A and r(c). For a single layer, for a given A, there is a critical value D(c) below (above) which the ground-state (GS) configuration of molecular axes is perpendicular (parallel) to the film surface. When the temperature T is increased, a re-orientation transition occurs near D(c): the low-T in-plane ordering undergoes a transition to the perpendicular ordering at a finite T, below the transition to the paramagnetic phase. The same phenomenon is observed in the case of a film with a thickness. Comparison with the Fe/Gd experiment is given. We show that the surface phase transition can occur below or above the bulk transition depending on the ratio J(s)/J. Surface and bulk order parameters as well as other physical quantities are shown and discussed.

  12. Novel Ionic Liquid with Both Lewis and Brønsted Acid Sites for Michael Addition

    Directory of Open Access Journals (Sweden)

    Runpu Shen

    2011-10-01

    Full Text Available Ionic liquid with both Lewis and Brønsted acid sites has been synthesized and its catalytic activities for Michael addition were carefully studied. The novel ionic liquid was stable to water and could be used in aqueous solution. The molar ratio of the Lewis and Brønsted acid sites could be adjusted to match different reactions. The results showed that the novel ionic liquid was very efficient for Michael addition with good to excellent yields within several min. Operational simplicity, high stability to water and air, small amount used, low cost of the catalyst used, high yields, chemoselectivity, applicability to large-scale reactions and reusability are the key features of this methodology, which indicated that this novel ionic liquid also holds great potential for environmentally friendly processes.

  13. Sir Michael Francis Addison Woodruff (1911-2001) FRS DSc MD MS FRCS.

    Science.gov (United States)

    Leigh, Winston

    2011-02-01

    Michael Woodruff performed the first successful renal transplant in the UK and described the technique of joining the ureter of the transplant to the bladder. He contributed to all aspects of transplantation biology and was responsible for the design of the first purpose-built transplant unit in the world. As a Japanese prisoner of war at Changi in Singapore, Michael Woodruff studied the effects of malnutrition and devised a machine for extracting vitamins and trace elements from grass. After the war he demonstrated that the anterior chamber of the eye was an immunologically privileged site. He was the first person to describe 'adaptation'. He showed that antilymphocytic serum was effective as an immunosuppressive agent for homografts.

  14. An Analysis of Michael Long's Interaction Hypothesis in Second Language Acquisition

    Institute of Scientific and Technical Information of China (English)

    单映

    2009-01-01

    The Interaction Hypothesis,which was first advanced by Michael Long,is considered ag a further supplement or extension of the Input Hypothesis in the field of second language acquisition.This paper explains the main claims of Michael Long'8 Interaction Hypothesis,the three steps to study how input and interaction affect the acquisition of a second language,and the importance of the interactional modifications applied by both participants of the interaction.Emphasis is placed on the evaluation of the theory as well as its relation to second language teaching,with many researchers'findings and arguments discussed as supporting evidence.It aims to help the effective application of this theory in second language teaching.

  15. Interviews with Michael Baxandall, February 3rd and 4th, 1994, Berkeley, CA

    Directory of Open Access Journals (Sweden)

    Allan Langdale

    2009-12-01

    Full Text Available The following interviews with Michael Baxandall were conducted in Berkeley on February 3rd and 4th of 1994. The content of these interviews include general responses about developments in art history in the years between 1960 and 1985, a period of dramatic modifications in the discipline. Among the issues are the rise of the social history of art and the sources from anthropology that informed Baxandall’s concept of the ‘Period Eye’. Baxandall talks about his own work, his personal intellectual history, and the scholars of past and current generations who influenced him. Other topics include Baxandall’s professional trajectory, the Warburg Library, and aspects of cultural history having to do with Renaissance Humanism. These interviews first appeared as an appendix to the PhD dissertation by Allan Langdale, Art History and Intellectual History: Michael Baxandall’s Work between 1963 and 1985, U. C. Santa Barbara, 1995.

  16. [An exceptional human relationship (Michael P. Kierkegaard, Søren Kierkegaard)].

    Science.gov (United States)

    Jacobs, R

    1978-01-01

    There were a father and a son, Michael and Sören Kierkegaard, both highly talented, imaginitive, witty, humorous, especially interested in shrewd dialectrical dialogues respectively debates, both profound melancholy ponderers. But according to very own individuality their congeniality wasn't absolute. The father, being under a questionable rigorous opinion of sin, suffered from undeserved divine grace since early childhood. And Michael Kierkegaard made Sören anxious with the religious experience of original sin. This anxiety moved (touched or affected) the sensitive son mighty. Nevertheless he should not despair hopelessly like his unlucky father. On the contrary: Sørens incomparable melancholy, mental agony and anxiety (fear or anguish) forced the faith, existing independently of them, in a radical refining. That is why Sören Kierkegaard succeeded in sublimation of all psychological and philosophic (al) attitudes (or opinions) in the sphere of religiousness. And the result? A novel philosophy of life: Christian existentialism.

  17. Michael K. Scullin: Psi Chi/APA Edwin B. Newman Graduate Research Award.

    Science.gov (United States)

    2011-11-01

    Presents Michael K. Scullin as the 2011 winner of the American Psychological Association Psi Chi/APA Edwin B. Newman Graduate Research Award. "For an outstanding research paper that examines the relationship between prospective memory in executing a goal and various lapses of time from 20 minutes up to a 12- hour wake delay and a 12-hour sleep delay. The results suggest that consolidation processes active during sleep increase the probability of goal execution. The paper, titled 'Remembering to Execute a Goal: Sleep On It!' was published in Psychological Science in 2010 and was the basis for Michael K. Scullin's selection as the recipient of the 2011 Psi Chi/APA Edwin B. Newman Graduate Research Award. Mark A. McDaniel, PhD, served as faculty research advisor." (PsycINFO Database Record (c) 2011 APA, all rights reserved). 2011 APA, all rights reserved

  18. Navigating Transition: Freedom, Limitation and the Post-colonial Persona in Michael Ondaatje's The Cat's Table

    Directory of Open Access Journals (Sweden)

    Alaa Alghamdi

    2012-11-01

    Full Text Available Michael Ondaatje's 2011 novel The Cat's Table follows a young boy's voyage from Colombo, Sri Lanka to London, England. Through this character and the unique environment of the ship, which forms a compelling sense of transitory place, Ondaatje explores liminality and its relationship with limitations or barriers. The young protagonist, Michael, and his companions enjoy an unusual level of freedom aboard the contained and hierarchically segmented ship. Polarization and transition between Eastern and Western culture is present but pales in importance compared to the validation of the self that is located within and defined by the sense of the in-between, an essential rite of passage undertaken before re-joining society.

  19. An Integral Part of the Frederick Community—Michael Dean | Poster

    Science.gov (United States)

    For more than 30 years, Michael Dean, Ph.D., has been an integral part of the NCI at Frederick community. In addition to studying several different aspects of genomics and cancer research, he has worked with the Werner H. Kirsten Student Intern Program and also volunteered his time with Mission of Mercy, a community-based organization providing free healthcare and free prescription medications to the uninsured and under-insured.

  20. Highlighting High Performance: Michael E. Capuano Early Childhood Center; Somerville, Massachusetts

    Energy Technology Data Exchange (ETDEWEB)

    2006-03-01

    This brochure describes the key high-performance building features of the Michael E. Capuano Early Childhood Center. The brochure was paid for by the Massachusetts Technology Collaborative as part of their Green Schools Initiative. High-performance features described are daylighting and energy-efficient lighting, indoor air quality, solar and wind energy, building envelope, heating and cooling systems, water conservation, and acoustics. Energy cost savings are also discussed.

  1. Is there sexism?——Feminist discourse analysis of the recruitment advertisement of Michael Page

    Institute of Scientific and Technical Information of China (English)

    段绘宇

    2010-01-01

    Sexism can be discovered in every sector oftbe society although it is under different guises. Women as a whole are treated oppressively and differently from men and they are subject to personal and institutional discrimination. This paper reveals sexism common in the business world through analyzing the register of tbe recruitment advert of'Michael Page' in 'Financial World' to raise critical gender awareness of the readers so that true equality between men and women can be eventually realized in the world.

  2. Horror movie aspects and experimentation in Michael Jackson’s Thriller music video

    OpenAIRE

    Vargas, Herom; Universidade Municipal de São Caetano do Sul - USCS; Gonçalves, Rafael; Universidade Municipal de São Caetano do Sul - USCS

    2016-01-01

    This article analyzes the use of elements from the horror fi lm genre in the music video Thriller (1982), by Michael Jackson, as experimentation within the field of pop music. Based on the semiotics of culture, grounded on the concepts of cultural text, semiosphere, border and modeling, developed by Iuri Lotman, the analysis identified innovations in the use of horror as humor and, in the music, modeling of creatures, moving among horror, the fantastic and the reality.Keywords: horror, music ...

  3. Efficient Lewis Acids Catalyzed Aza-Michael Reactions of Enones with Carbamates

    Institute of Scientific and Technical Information of China (English)

    XIA Chun-Gu; XU Li-Wen

    2004-01-01

    The a-amino carbonyl functionality is not only a segment of biologically important natural products but also a versatile intermediate for the synthesis of nitrogen-containing compounds.1 The development of novel synthetic methods leading to a-amino ketone, a-amino acids or their derivatives has attracted much attention in organic synthesis.2 Among the traditional methods for generating a-amino carbonyl compounds, Mannich-type reaction is one of the classical and powerful methods.3 However, the classic Mannich reaction presents serious disadvantages, for example, there is still a drawback in that the silyl enolates have to be prepared from the corresponding carbonyl compounds. Alternatively, aza-Michael additions can be used to create carbon-heteroatom bonds by reaction of a,a-unsaturated carbonyl compounds with amines. Although recent advances have made this route more attractive, development of cheaper, simpler, and more efficient metal catalyst, especially which can be applied to chalcone, is highly desirable.In this paper, we demonstrated that the first aza-Michael reaction of chalcone with a less nucleophilic carbamates can be accomplished on Me3SiCFFeCl3 catalyst system under very mild conditions. Apart from experimental simplicity, the advantages of this methodology are the use of a very cheap Lewis acid catalyst and the insensitivity of the reaction mixture towards air and moisture.catalyst for aza-Michael reaction of chalcone and cyclic enones with carbamates. And with the cyclic enones with carbamates in dichloromethane at room temperature were also investigated. In this conjugate addition reaction, good to excellent yields of a-amino ketones were obtained with system could also mediates aza-Michael addition of carbamates to chalcone and derivatives.These new strategies opened efficient procedures for the synthesis of a-amino ketones under mild conditions.

  4. Asymmetric Synthesis of Fully Substituted Cyclopentane-Oxindoles through an Organocatalytic Triple Michael Domino Reaction

    Science.gov (United States)

    Zou, Liang-Hua; Philipps, Arne R; Raabe, Gerhard; Enders, Dieter

    2015-01-01

    An efficient, highly stereoselective asymmetric synthesis of fully functionalized cyclopentanes bearing an oxindole moiety and several other functional groups in one pot has been developed. Key step is an organocatalytic triple Michael domino reaction forming three C–C bonds and six stereocenters, including a quaternary one. Starting from equimolar amounts of simple substrates, a high molecular complexity can be reached after a Wittig olefination in one pot. The new protocol can easily be scaled up to gram amounts. PMID:25470781

  5. Tetramethylguanidium Lactate Ionic Liquid:Catalyst-free Medium for Michael Addition Reaction

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    A catalyst-free, facile and efficient Michael addition reaction of active methylene compounds as well as nitromethane with chalcones catalyzed by guanidinium lactate ionic liquid was done. A series of chalcones,nitromethane, and active methylene compounds were converted smoothly to the corresponding products in high yields.The simple procedure, very mild conditions, high yields, and reuse of the IL without any loss of catalytic activity make this protocol considerably attractive for academic researches and practical applications.

  6. Catalytic enantioselective Michael addition reactions of alpha-nitroesters to alpha,beta-unsaturated ketones

    NARCIS (Netherlands)

    Keller, E; Veldman, N; Spek, AL; Feringa, BL

    1997-01-01

    Enantioselective Michael additions of alpha-nitroesters 2a-d with alpha,beta-unsaturated ketones were carried out in the presence of a catalytic amount of chiral Al-Li-(R,R')-2,2'-dihydroxy-1,1'-binaphthyl ('AlLiBINOL') complex prepared in situ from LiAlH4 and 2.45 equiv. of (R,R')-BINOL. The enanti

  7. Catalytic enantioselective Michael addition reactions of α-nitroesters to α,β-unsaturated ketones

    NARCIS (Netherlands)

    Keller, Erik; Veldman, Nora; Spek, Anthony L.; Feringa, Bernard

    1997-01-01

    Enantioselective Michael additions of α-nitroesters 2a-d with α,β-unsaturated ketones were carried out in the presence of a catalytic amount of chiral Al-Li-(R,R')-2,2'-dihydroxy-1,1'-binaphthyl (‘AlLiBINOL’) complex prepared in situ from LiAlH4 and 2.45 equiv. of (R,R')-BINOL. The enantioselectivit

  8. Functionalized 3D Architected Materials via Thiol-Michael Addition and Two-Photon Lithography.

    Science.gov (United States)

    Yee, Daryl W; Schulz, Michael D; Grubbs, Robert H; Greer, Julia R

    2017-04-01

    Fabrication of functionalized 3D architected materials is achieved by a facile method using functionalized acrylates synthesized via thiol-Michael addition, which are then polymerized using two-photon lithography. A wide variety of functional groups can be attached, from Boc-protected amines to fluoroalkanes. Modification of surface wetting properties and conjugation with fluorescent tags are demonstrated to highlight the potential applications of this technique. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Feeding Health: Michael Pollan on Improving Public Health through the Food Systems

    Centers for Disease Control (CDC) Podcasts

    2009-08-19

    In this podcast, author Michael Pollan discusses his March 2009 visit to CDC and offers his thoughts on the intersection between the government, the food systems, and public health.  Created: 8/19/2009 by National Center for Environmental Health (NCEH), National Center for Chronic Disease Prevention and Health Promotion (NCCDPHP), Office of Sustainability.   Date Released: 4/15/2010.

  10. N-1 regioselective Michael-type addition of 5-substituted uracils to (2-hydroxyethyl acrylate

    Directory of Open Access Journals (Sweden)

    Walczak Krzysztof Z

    2007-11-01

    Full Text Available Abstract N-1 regioselective Michael-type addition of 5-substituted uracils to (2-hydroxyethyl acrylate is presented. The reactions were performed in polar aprotic solvents and with avoidance of polymerization of acrylic substrate. The obtained adducts may serve as versatile substrates for further functionalization, e.g. into (3-uracil-1-ylpropanoic acids or transformations, with participation of hydroxyl group, into ester-conjugated acyclic nucleosides.

  11. Remote Sensing of Sea Surface Wind of Hurricane Michael by GPS Reflected Signals

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    In this paper, the propagating geometry and the waveform of the GPS reflected signals are expatiated in detail. Furthermore, the principle and the method of retrieving sea surface wind are presented. In order to test the feasibility of retrieval, the experiment data obtained by NASA in Hurricane Michael are used. The result shows that the retrieval accuracy of wind speed is about 2 m/s.

  12. Translation of Michael Sadowsky's paper "The differential equations of the M\\"obius band"

    CERN Document Server

    Hinz, Denis F

    2014-01-01

    This article is a translation of Michael Sadowsky's original paper "Die Differentialgleichungen des M\\"obiusschen Bandes." in Jahresbericht der Deutschen Mathermatiker-Vereinigung 39 (2. Abt. Heft 5/8, Jahresversammlung vom 16. bis 23. September), 49-51 (1929), which is a short version of his paper "Theorie der elastisch biegsamen undehnbaren B\\"ander mit Anwendungen auf das M\\"obiussche Band" in 3. internationaler Kongress f\\"ur technische Mechanik, Stockholm, 1930.

  13. An Integral Part of the Frederick Community—Michael Dean | Poster

    Science.gov (United States)

    For more than 30 years, Michael Dean, Ph.D., has been an integral part of the NCI at Frederick community. In addition to studying several different aspects of genomics and cancer research, he has worked with the Werner H. Kirsten Student Intern Program and also volunteered his time with Mission of Mercy, a community-based organization providing free healthcare and free prescription medications to the uninsured and under-insured.

  14. Monetary Regimes and Policy on a Global Scale: The Oeuvre of Michael D. Bordo

    OpenAIRE

    Rockoff, Hugh; Eugene N. White

    2012-01-01

    Michael D. Bordo has helped to define the modern field of monetary history, drawing from it important policy lessons for current practitioners. For his seventieth year, we survey his contributions to our understanding of the Great Depression, money and the economy in historical perspective, exchange rate regimes including the gold standard, Bretton Woods, and the European Monetary Union, globalization, financial crises, the Canadian monetary experience, and historical guidance for monetary p...

  15. FY 2016 Status Report: CIRFT Testing on Spent Nuclear Fuels and Hydride Reorientation Study

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jy-An John [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Wang, Hong [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Yan, Yong [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Bevard, Bruce B. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Scaglione, John M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division

    2016-08-04

    This report provides a detailed description of the Cyclic Integrated Reversible-Bending Fatigue Tester (CIRFT) testing conducted on spent nuclear fuel (SNF) rods in FY 2016, including hydride reorientation test results. Contact-based measurement, or three-LVDT-based curvature measurement, of SNF rods has proven to be quite reliable in CIRFT testing. However, how the linear variable differential transformer (LVDT) head contacts the SNF rod may have a significant effect on the curvature measurement, depending on the magnitude and direction of rod curvature. To correct such contact/curvature issues, sensor spacing, defined as the amount of separation between the three LVDT probes, is a critical measurement that can be used to calculate rod curvature once the deflections are obtained. Recently developed CIRFT data analyses procedures were integrated into FY 2016 CIRFT testing results for the curvature measurements. The variations in fatigue life are provided in terms of moment, equivalent stress, curvature, and equivalent strain for the tested SNFs. The equivalent stress plot collapsed the data points from all of the SNFs into a single zone. A detailed examination revealed that, at same stress level, fatigue lives display a descending order as follows: H. B. Robinson Nuclear Power Station (HBR), Limerick Nuclear Power Station (LMK), mixed uranium-plutonium oxide (MOX). If looking at the strain, then LMK fuel has a slightly longer fatigue life than HBR fuel, but the difference is subtle. The knee point of endurance limit in the curve of moment and curvature or equivalent quantities is more clearly defined for LMK and HBR fuels. The treatment affects the fatigue life of specimens. Both a drop of 12 in. and radial hydride treatment (RHT) have a negative impact on fatigue life. The effect of thermal annealing on MOX fuel rods was relatively small at higher amplitude but became significant at low amplitude of moment. Thermal annealing tended to extend the fatigue life of

  16. FY 2016 Status Report: Documentation of All CIRFT Data including Hydride Reorientation Tests (Draft M2)

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jy-An John [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Wang, Hong [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Jiang, Hao [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Yan, Yong [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Bevard, Bruce B. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Scaglione, John M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division

    2016-09-04

    The first portion of this report provides a detailed description of fiscal year (FY) 2015 test result corrections and analysis updates based on FY 2016 updates to the Cyclic Integrated Reversible-Bending Fatigue Tester (CIRFT) program methodology, which is used to evaluate the vibration integrity of spent nuclear fuel (SNF) under normal conditions of transport (NCT). The CIRFT consists of a U-frame test setup and a real-time curvature measurement method. The three-component U-frame setup of the CIRFT has two rigid arms and linkages connecting to a universal testing machine. The curvature SNF rod bending is obtained through a three-point deflection measurement method. Three linear variable differential transformers (LVDTs) are clamped to the side connecting plates of the U-frame and used to capture deformation of the rod. The second portion of this report provides the latest CIRFT data, including data for the hydride reorientation test. The variations in fatigue life are provided in terms of moment, equivalent stress, curvature, and equivalent strain for the tested SNFs. The equivalent stress plot collapsed the data points from all of the SNF samples into a single zone. A detailed examination revealed that, at the same stress level, fatigue lives display a descending order as follows: H. B. Robinson Nuclear Power Station (HBR), LMK, and mixed uranium-plutonium oxide (MOX). Just looking at the strain, LMK fuel has a slightly longer fatigue life than HBR fuel, but the difference is subtle. The third portion of this report provides finite element analysis (FEA) dynamic deformation simulation of SNF assemblies . In a horizontal layout under NCT, the fuel assembly’s skeleton, which is formed by guide tubes and spacer grids, is the primary load bearing apparatus carrying and transferring vibration loads within an SNF assembly. These vibration loads include interaction forces between the SNF assembly and the canister basket walls. Therefore, the integrity of the guide

  17. FY 2016 Status Report: Documentation of All CIRFT Data including Hydride Reorientation Tests (Draft M2)

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jy-An John [ORNL; Wang, Hong [ORNL

    2016-09-01

    The first portion of this report provides a detailed description of fiscal year (FY) 2015 test result corrections and analysis updates based on FY 2016 updates to the Cyclic Integrated Reversible-Bending Fatigue Tester (CIRFT) program methodology, which is used to evaluate the vibration integrity of spent nuclear fuel (SNF) under normal conditions of transport (NCT). The CIRFT consists of a U-frame test setup and a real-time curvature measurement method. The three-component U-frame setup of the CIRFT has two rigid arms and linkages connecting to a universal testing machine. The curvature SNF rod bending is obtained through a three-point deflection measurement method. Three linear variable differential transformers (LVDTs) are clamped to the side connecting plates of the U-frame and used to capture deformation of the rod. The second portion of this report provides the latest CIRFT data, including data for the hydride reorientation test. The variations in fatigue life are provided in terms of moment, equivalent stress, curvature, and equivalent strain for the tested SNFs. The equivalent stress plot collapsed the data points from all of the SNF samples into a single zone. A detailed examination revealed that, at the same stress level, fatigue lives display a descending order as follows: H. B. Robinson Nuclear Power Station (HBR), LMK, and mixed uranium-plutonium oxide (MOX). Just looking at the strain, LMK fuel has a slightly longer fatigue life than HBR fuel, but the difference is subtle. The third portion of this report provides finite element analysis (FEA) dynamic deformation simulation of SNF assemblies . In a horizontal layout under NCT, the fuel assembly’s skeleton, which is formed by guide tubes and spacer grids, is the primary load bearing apparatus carrying and transferring vibration loads within an SNF assembly. These vibration loads include interaction forces between the SNF assembly and the canister basket walls. Therefore, the integrity of the guide

  18. Organocatalytic Asymmetric Michael Addition of 4-Hydroxycoumarin to β,γ-Unsaturated α-Keto Esters

    Energy Technology Data Exchange (ETDEWEB)

    Suh, Chang Won; Han, Tae Hyun; Kim, Dae Young [Soonchunhyang Univ., Asan (Korea, Republic of)

    2013-06-15

    In conclusion, we have developed organocatalytic enantioselective conjugate addition reaction of 4-hydroxycoumarin (1) to β,γ-unsaturated α-keto esters 2 to afford biologically valuable warfarin derivatives 3. The process is efficiently catalyzed by a binaphthyl-modified thiourea organocatalyst. The coumarin core is present as a characteristic structural motif in a large number of natural products and biologically active molecules.1 Particularly, many of these naturally occurring 4-hydroxycoumarin and their synthetic analogues are important precursors for the synthesis of natural products and pharmaceuticals. Enantioselective organocatalytic conjugate addition of 4-hydroxycoumarin to α,β-unsaturated ketones is a straightforward method to access warfarin which is an effective anticoagulants. Although a number of reactions of α,β-unsaturated ketones as Michael acceptors have been reported, the corresponding β,γ-unsaturated α-keto esters have received relatively little attention as Michael acceptors. Recently, several groups have reported the asymmetric Michael addition of 4-hydroxycoumarin to β,γ-unsaturated α-keto esters catalyzed by Cu(II)-bisoxazoline, N,N'-dioxide-Ni(II) complexes, thiourea catalysts. Although several efficient methods have been achieved by these systems, an effective method for the synthesis of warfarin analogues is still a challenge.

  19. En memoria de Michael Jiménez (1948-2001

    Directory of Open Access Journals (Sweden)

    Mauricio Archila Neira

    2010-08-01

    Full Text Available El 1 de septiembre de 2001 murió el historiador Michael Jiménez. Su apellido provenía de España de donde emigró su abuelo en busca de mejor suerte al otro lado del Atlántico. Nacido en el pequeño pueblo de Merced, California (Estados Unidos en agosto de 1948 en el seno de una familia obrera, Michael vivió su infancia en Colombia. A fines de ese año, su padre se desplazó a estas tierras para ser funcionario de la Texas, una multinacional petrolera que tenía sus reales en Puerto Boyacá. Michael estudió en el colegio Nueva Granada -becado por la Texas- hasta los catorce años. En dicho colegio fue compañero de pupitre de Herbert Braun, descendiente a su vez de una familia de emigrantes a Colombia, y con quien la vida lo juntaría de nuevo en las tierras del norte y en oficios similares.

  20. TDDFT Study on Different Sensing Mechanisms of Similar Cyanide Sensors Based on Michael Addition Reaction

    Institute of Scientific and Technical Information of China (English)

    Guang-yue Li; Ping Song; Guo-zhong He

    2011-01-01

    The solvents and substituents of two similar fluorescent sensors for cyanide, 7-diethylamino-3-formylcoumarin (sensor a) and 7-diethylamino-3-(2-nitrovinyl)coumarin (sensor b), are proposed to account for their distinct sensing mechanisms and experimental phenomena.The time-dependent density functional theory has been applied to investigate the ground states and the first singlet excited electronic states of the sensor as well as their possible Michael reaction products with cyanide, with a view to monitoring their geometries and photophysical properties. The theoretical study indicates that the protic water solvent could lead to final Michael addition product of sensor a in the ground state, while the aprotic acetonitrile solvent could lead to carbanion as the final product of sensor b. Furthermore,the Michael reaction product of sensor a has been proved to have a torsion structure in its first singlet excited state. Correspondingly, sensor b also has a torsion structure around the nitrovinyl moiety in its first singlet excited state, while not in its carbanion structure. This could explain the observed strong fluorescence for sensor a and the quenching fluorescencefor the sensor b upon the addition of the cyanide anions in the relevant sensing mechanisms.

  1. Michael addition reactions of cyclanones with acrylamides: Producing 2-carbamoylethyl derivatives or ene-lactams

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The electron-withdrawing groups (EWGs) in the electrophilic alkenes employed in the Michael addition reaction are almost only CO2R, CN, COR, NO2, and SO2Ph. Although amides (CONR1R2) are also typical electron-withdrawing groups and are of great importance in organic synthesis, they are scarcely em-ployed as the EWGs of the electrophilic alkenes in the Michael addition reaction. In this work, the Mi-chael reactions of acrylamide and its derivatives with cyclanones were successfully carried out in the presence of enough radical inhibitors. The amide groups play a key role in producing the preferred products. The N-substituted acrylamides, including N-monosubstituted and N,N-disubstituted acryla-mides could react with cyclohexanone (CHn) to give the expected 2-carbamoylethyl derivatives; how-ever, acrylamide reacting with cyclohexanone only produced ene-lactam. Cyclanones also have effects on the products, while the ring size of cyclanones influences the reaction yield and the α-substituent decides the ratio of resulting isomeric ene-lactams.

  2. En memoria de Michael Jiménez (1948-2001

    Directory of Open Access Journals (Sweden)

    Mauricio Archila Neira

    2001-01-01

    Full Text Available El 1 de septiembre de 2001 murió el historiador Michael Jiménez. Su apellido provenía de España de donde emigró su abuelo en busca de mejor suerte al otro lado del Atlántico. Nacido en el pequeño pueblo de Merced, California (Estados Unidos en agosto de 1948 en el seno de una familia obrera, Michael vivió su infancia en Colombia. A fines de ese año, su padre se desplazó a estas tierras para ser funcionario de la Texas, una multinacional petrolera que tenía sus reales en Puerto Boyacá. Michael estudió en el colegio Nueva Granada -becado por la Texas- hasta los catorce años. En dicho colegio fue compañero de pupitre de Herbert Braun, descendiente a su vez de una familia de emigrantes a Colombia, y con quien la vida lo juntaría de nuevo en las tierras del norte y en oficios similares.

  3. Class analysis and the reorientation of class theory: the case of persisting differentials in educational attainment. 1996.

    Science.gov (United States)

    Goldthorpe, John H

    2010-01-01

    In class analysis the main regularities that have been established by empirical research are not ones of long-term class formation or decomposition, as envisaged in Marxist or liberal theory, but rather ones that exhibit the powerful resistance to change of class relations and associated life-chances and patterns of social action. If these regularities are to be explained, theory needs to be correspondingly reoriented, and must abandon functionalist and teleological assumptions in favour of providing more secure micro-foundations. This argument is developed and illustrated in the course of an attempt to apply rational action theory to the explanation of persisting class differentials in educational attainment.

  4. Reorientation of the high mobility plane in pentacene-based carbon nanotube enabled vertical field effect transistors.

    Science.gov (United States)

    McCarthy, Mitchell A; Liu, Bo; Jayaraman, Ramesh; Gilbert, Stephen M; Kim, Do Young; So, Franky; Rinzler, Andrew G

    2011-01-25

    The large current densities attained by carbon nanotube enabled vertical field effect transistors using crystalline organic channel materials are somewhat unexpected given the known large anisotropy in the mobility of crystalline organics and their conventional ordering on dielectric surfaces which tends to orient their high mobility axes parallel to the surface. This seeming contradiction is resolved by the finding that the nanotubes induce a molecular ordering that reorients the high mobility axes to favor current flow in a direction perpendicular to the substrate surface.

  5. Temperature-Induced Magnetization Reorientation in GdFeCo/TbFeCo Exchange-Coupled Double Layer Films

    Institute of Scientific and Technical Information of China (English)

    王现英; 张约品; 李佐宜; 沈德芳; 干福熹

    2003-01-01

    GdFeCo/TbFeCo exchange-coupled double-layer (ECDL) films used for centre aperture type magnetically in duced super resolution were investigated through experiments and theoretical calculation. The ECDL films were prepared by the magnetron sputtering method. Polar Kerr effect measurements showed that magnetization reorientation occurred in the GdFeCo layer with the temperature rising, which was subsequently analysed by the micromagnetic calculation based on the mean-field theory and a continuum model. Theoretical analysis is in agreement well with the experimental results.

  6. Steering Demands Diminish the Early-P3, Late-P3 and RON Components of the Event-Related Potential of Task-Irrelevant Environmental Sounds.

    Science.gov (United States)

    Scheer, Menja; Bülthoff, Heinrich H; Chuang, Lewis L

    2016-01-01

    The current study investigates the demands that steering places on mental resources. Instead of a conventional dual-task paradigm, participants of this study were only required to perform a steering task while task-irrelevant auditory distractor probes (environmental sounds and beep tones) were intermittently presented. The event-related potentials (ERPs), which were generated by these probes, were analyzed for their sensitivity to the steering task's demands. The steering task required participants to counteract unpredictable roll disturbances and difficulty was manipulated either by adjusting the bandwidth of the roll disturbance or by varying the complexity of the control dynamics. A mass univariate analysis revealed that steering selectively diminishes the amplitudes of early P3, late P3, and the re-orientation negativity (RON) to task-irrelevant environmental sounds but not to beep tones. Our findings are in line with a three-stage distraction model, which interprets these ERPs to reflect the post-sensory detection of the task-irrelevant stimulus, engagement, and re-orientation back to the steering task. This interpretation is consistent with our manipulations for steering difficulty. More participants showed diminished amplitudes for these ERPs in the "hard" steering condition relative to the "easy" condition. To sum up, the current work identifies the spatiotemporal ERP components of task-irrelevant auditory probes that are sensitive to steering demands on mental resources. This provides a non-intrusive method for evaluating mental workload in novel steering environments.

  7. Tagasipöördumine esteetika juurde = Return to aesthetics / Keith Moxey, Michael Ann Holly ; interv. Anu Allas

    Index Scriptorium Estoniae

    Moxey, Keith

    2007-01-01

    Ameerika kunstiajaloolased Keith Moxey ning Michael Ann Holly tutvustavad uut lähenemist kunstiajaloole (new art history). Nn. naasmine esteetika juurde tähendab püüet integreerida kunstiajalukku ja -teooriasse uuesti ja tugevamalt kunstiteos

  8. Tandem Knoevenagel–Michael reactions in aqueous diethylamine medium: A greener and efficient approach toward bis-dimedone derivatives

    Directory of Open Access Journals (Sweden)

    Abdullah Mohammed Al-Majid

    2017-02-01

    The use of inexpensive, eco-friendly and readily available reagents, easy work-up, and high purity products makes the procedure a convenient and robust method for the synthesis of tandem Knoevenagel–Michael adducts.

  9. Vice Premier Zeng Peiyan Meets with Michael Cohrs,CEO of Corporate & Investment Banking of Deutsche Bank

    Institute of Scientific and Technical Information of China (English)

    LuHongwei

    2004-01-01

    Invited by the CPAFFC, Michael Cohrs, Chief Executive Officer of the Corporate and Investment Banking of Deutsche Bank, visited Beijing from February 26 to 28, 2004. Vice Premier Zeng Peiyan of the State Council met with Cohrs and his party.

  10. The big picture : What the Baltics may learn from Ireland's success story / Michael Bourke ; interv. Maris Biezaitis

    Index Scriptorium Estoniae

    Bourke, Michael

    2002-01-01

    Ilmunud ka: Baltiiskii kurss 2002/Zima/Vesna nr. 20 lk. 14-17. Iirimaa aukonsul Lätis, Michael Joseph Bourke arutleb Iirimaa majandusedu teemal ning pakub välja, mida Baltimaad saaksid sellest õppida. Tabel, diagramm. Lisa

  11. The big picture : What the Baltics may learn from Ireland's success story / Michael Bourke ; interv. Maris Biezaitis

    Index Scriptorium Estoniae

    Bourke, Michael

    2002-01-01

    Ilmunud ka: Baltiiskii kurss 2002/Zima/Vesna nr. 20 lk. 14-17. Iirimaa aukonsul Lätis, Michael Joseph Bourke arutleb Iirimaa majandusedu teemal ning pakub välja, mida Baltimaad saaksid sellest õppida. Tabel, diagramm. Lisa

  12. Michael T. Westrate. Living Soviet in Ukraine from Stalin to Maidan: Under the Falling Red Star in Kharkiv.

    Directory of Open Access Journals (Sweden)

    Charitie V. Hyman

    2017-09-01

    Full Text Available Book review of Michael T. Westrate. Living Soviet in Ukraine from Stalin to Maidan: Under the Falling Red Star in Kharkiv. Rowman & Littlefield, 2016. xx, 232 pp. Illustrations. Appendices. Bibliography. Index. $85.00, cloth.

  13. 77 FR 40878 - Californians for Renewable Energy, Inc., Michael E. Boyd, Robert M. Sarvey, v. California Public...

    Science.gov (United States)

    2012-07-11

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF ENERGY Federal Energy Regulatory Commission Californians for Renewable Energy, Inc., Michael E. Boyd, Robert M. Sarvey, v. California Public Utilities Commission, California Department of Water Resources, Pacific Gas...

  14. Asymmetric Synthesis of Substituted Thiolanes through Domino Thia-Michael-Henry Dynamic Covalent Systemic Resolution using Lipase Catalysis.

    Science.gov (United States)

    Zhang, Yan; Vongvilai, Pornrapee; Sakulsombat, Morakot; Fischer, Andreas; Ramström, Olof

    2014-03-24

    Dynamic systems based on consecutive thia-Michael and Henry reactions were generated and transformed using lipase-catalyzed asymmetric transformation. Substituted thiolane structures with three contiguous stereocenters were resolved in the process in high yields and high enantiomeric excesses.

  15. Pursuing perfection: an interview with Don Berwick and Michael Rothman. Interview by Andrea Kabcenell and Jane Roessner.

    Science.gov (United States)

    Berwick, Don; Rothman, Michael

    2002-05-01

    Don Berwick and Michael Rothman discuss the Pursuing Perfection initiative, which is intended to help health care organizations integrate improvement work into day-to-day life, with systemwide changes in infrastructure, project management, care, and leadership.

  16. Tagasipöördumine esteetika juurde = Return to aesthetics / Keith Moxey, Michael Ann Holly ; interv. Anu Allas

    Index Scriptorium Estoniae

    Moxey, Keith

    2007-01-01

    Ameerika kunstiajaloolased Keith Moxey ning Michael Ann Holly tutvustavad uut lähenemist kunstiajaloole (new art history). Nn. naasmine esteetika juurde tähendab püüet integreerida kunstiajalukku ja -teooriasse uuesti ja tugevamalt kunstiteos

  17. ERP indices of persisting and current inhibitory control: a study of saccadic task switching.

    Science.gov (United States)

    Mueller, S C; Swainson, R; Jackson, G M

    2009-03-01

    Previous studies have found that inhibition of a biologically dominant prepotent response tendency is required during the execution of a less familiar, non-prepotent response. However, the lasting impact of this inhibition and the cognitive mechanisms to flexibly switch between prepotent and non-prepotent responses are poorly understood. We examined the neurophysiological (ERP) correlates of switching between prosaccade and antisaccade responses in 22 healthy volunteers. The behavioural data showed significant switch costs in terms of response latency for the prosaccade task only. These costs occurred exclusively in trials when preparation for the switch was limited to 300 ms, suggesting that inhibition of the prepotent prosaccade task either passively dissipated or was actively overcome during the longer 1000 ms preparation interval. In the neurophysiological data, a late frontal negativity (LFN) was visible during preparation for a switch to the prosaccade task that was absent when switching to the antisaccade task, which may reflect the overcoming of persisting inhibition. During task implementation both saccade types were associated with a late parietal positivity (LPP) for switch relative to repetition trials, possibly indicating attentional reorienting to the switched-to task, and visible only with short preparation intervals. When the prosaccade and antisaccade task were contrasted directly during task implementation, the antisaccade task exhibited increased stimulus-locked N2 and decreased P3 amplitudes indicative of active inhibition. The present findings indicate that neurophysiological markers of persisting and current inhibition can be revealed using a prosaccade/antisaccade-switching task.

  18. A perspectiva de Michael Apple para os estudos das políticas educacionais

    Directory of Open Access Journals (Sweden)

    Luís Armando Gandin

    Full Text Available Resumo Este artigo tem como objetivo analisar as contribuições de Michael Apple para o campo da pesquisa em políticas educacionais. Na extensa obra de Michael Apple, destacamos seis elementos que podem auxiliar aqueles que estão interessados na área de políticas em educação: o princípio epistemológico da análise relacional; o exame do Estado como relação; a herança de Antonio Gramsci e de Raymond Williams que Michael Apple incorpora no uso de conceitos como hegemonia e senso comum; a análise que Michael Apple faz das políticas educacionais como políticas culturais, como disputas por visão de mundo, como luta por consolidação de uma hegemonia que vai além do econômico; a sua postura de pesquisador; e a capacidade que Michael Apple tem de ir além da lógica da reprodução e determinação para enfatizar o papel da agência e da contra-hegemonia. Através de exemplos práticos da própria obra de Apple e de outras pesquisas empíricas, apresentam-se as implicações de cada um dos seis pontos acima citados para os pesquisadores interessados na área de políticas educacionais. Conclui-se que muitas das contribuições de Apple podem auxiliar em pesquisas nessa área, tendo em vista a discussão que o autor realiza em sua obra e sua crítica ao determinismo econômico nas análises do campo educacional, salientando a importância, assim, de aspectos que estão relacionados à esfera da cultura.

  19. Why SIT works: normal function despite typical myofiber pattern in Situs Inversus Totalis (SIT) hearts derived by shear-induced myofiber reorientation.

    Science.gov (United States)

    Pluijmert, Marieke; Kroon, Wilco; Rossi, Alessandro C; Bovendeerd, Peter H M; Delhaas, Tammo

    2012-01-01

    The left ventricle (LV) of mammals with Situs Solitus (SS, normal organ arrangement) displays hardly any interindividual variation in myofiber pattern and experimentally determined torsion. SS LV myofiber pattern has been suggested to result from adaptive myofiber reorientation, in turn leading to efficient pump and myofiber function. Limited data from the Situs Inversus Totalis (SIT, a complete mirror image of organ anatomy and position) LV demonstrated an essential different myofiber pattern, being normal at the apex but mirrored at the base. Considerable differences in torsion patterns in between human SIT LVs even suggest variation in myofiber pattern among SIT LVs themselves. We addressed whether different myofiber patterns in the SIT LV can be predicted by adaptive myofiber reorientation and whether they yield similar pump and myofiber function as in the SS LV. With a mathematical model of LV mechanics including shear induced myofiber reorientation, we predicted myofiber patterns of one SS and three different SIT LVs. Initial conditions for SIT were based on scarce information on the helix angle. The transverse angle was set to zero. During reorientation, a non-zero transverse angle developed, pump function increased, and myofiber function increased and became more homogeneous. Three continuous SIT structures emerged with a different location of transition between normal and mirrored myofiber orientation pattern. Predicted SIT torsion patterns matched experimentally determined ones. Pump and myofiber function in SIT and SS LVs are similar, despite essential differences in myocardial structure. SS and SIT LV structure and function may originate from same processes of adaptive myofiber reorientation.

  20. Review: Michael Crandall & Karen E. Fisher (Eds) Digital Inclusion: Measuring the Impact of Information and Community Technology

    DEFF Research Database (Denmark)

    Pors, Niels Ole

    2010-01-01

    Review: Michael Crandall & Karen E. Fisher (Eds) Digital Inclusion: Measuring the Impact of Information and Community Technology. Medford. Information Today. ASIS&T Monographs, 2009. 185 pages. $ 59.50. ISBN 978-1-57387-373-4......Review: Michael Crandall & Karen E. Fisher (Eds) Digital Inclusion: Measuring the Impact of Information and Community Technology. Medford. Information Today. ASIS&T Monographs, 2009. 185 pages. $ 59.50. ISBN 978-1-57387-373-4...

  1. Rh(III)-Catalyzed C-H Bond Addition/Amine-Mediated Cyclization of Bis-Michael Acceptors.

    Science.gov (United States)

    Potter, Tyler J; Ellman, Jonathan A

    2016-08-01

    A Rh(III)-catalyzed C-H bond addition/primary amine-promoted cyclization of bis-Michael acceptors is reported. The C-H bond addition step occurs with high chemoselectivity, and the subsequent intramolecular Michael addition, mediated by a primary amine catalyst, sets three contiguous stereocenters with high diastereoselectivity. A broad range of directing groups and both aromatic and alkenyl C-H bonds were shown to be effective in this transformation, affording functionalized piperidines, tetrahydropyrans, and cyclohexanes.

  2. Review: Michael Crandall & Karen E. Fisher (Eds) Digital Inclusion: Measuring the Impact of Information and Community Technology

    DEFF Research Database (Denmark)

    Pors, Niels Ole

    2010-01-01

    Review: Michael Crandall & Karen E. Fisher (Eds) Digital Inclusion: Measuring the Impact of Information and Community Technology. Medford. Information Today. ASIS&T Monographs, 2009. 185 pages. $ 59.50. ISBN 978-1-57387-373-4......Review: Michael Crandall & Karen E. Fisher (Eds) Digital Inclusion: Measuring the Impact of Information and Community Technology. Medford. Information Today. ASIS&T Monographs, 2009. 185 pages. $ 59.50. ISBN 978-1-57387-373-4...

  3. "Task" as Research Construct

    Science.gov (United States)

    Seedhouse, Paul

    2005-01-01

    The article examines "task" as research construct as predominantly conceived in terms of task-as-workplan in the task-based learning/second language acquisition literature. It is suggested that "task" has weak construct validity and ontology in an overwhelmingly quantitative paradigm because the construct has a "split personality."…

  4. Reorientation of M{sub A}{sup +}-centres in CaF{sub 2}:Me{sup +} crystals

    Energy Technology Data Exchange (ETDEWEB)

    Chornyi, Z.P.; Shchur, G.O.; Salapak, V.M. [Ukrainian State Univ. of Forestry and Wood Technology, Lviv (Ukraine); Kravchuk, I.M.; Kachan, S.I. [State Univ. ' ' Lvivska Polytekhnika' ' , Lviv (Ukraine)

    2001-02-01

    Studies of photoinductive dichroism allow to define the orientation of colour centres. The photo-inductive dichroism of absorption testifies the fact that oscillators, responsible for the long-wave absorption band of M{sub A}{sup +}-centres, are located along left angle 100 right angle crystallographic directions, and high-energetic oscillators, along left angle 110 right angle crystallographic directions. Various impurities cause unequal perturbations in the crystal lattice. The determination of the kinetic parameters of the reorientation processes in simple and complex colour centres allows establishing the structure of the aggregative centre. The size of the impurity ion influences the energy of reorientation of M{sub A}{sup +}-centres, and this, in turn, is connected with the displacement of vacancies towards the anion sites of the crystal. It is found that the anion vacancy in M{sub A}{sup +}-centres jumps in left angle 110 right angle directions, but in F{sub A}{sup +}-centres it jumps in left angle 100 right angle directions. (orig.)

  5. [The trajectory of the national policy for the reorientation of professional training in health in the Unified Health System (SUS)].

    Science.gov (United States)

    Dias, Henrique Sant'anna; Lima, Luciana Dias de; Teixeira, Márcia

    2013-06-01

    This paper examines the national policy and its antecedents for reorientation of professional health training implemented after 2003. It highlights landmarks and transformations in the course of policies between 1980 and 2010, elements of continuity and change and the connections between past and current policy initiatives. The study involved a review of the literature on the subject and document analysis supported by theoretical analysis of public policies, particularly historical institutionalism. The results point to four different moments during the trajectory of the policy, marked by changes in the initiatives of reorientation of higher education in health: antecedents; initial experiences; university protagonism; broadening and enhancement. As an element of continuity, there is the permanence of objects in the guiding principles advocated in the policies. The evidence of implementation expresses prospects of enhancement, with diversification of mobilized actors and organizations, and more projects implemented. The accumulated experience suggests structural maturity of the structural bases of action and the main changes relate to the enhancement of decision-making bodies of the SUS and the approximation to the process of decentralization and regionalization of national health policy.

  6. Beacons and surface features differentially influence human reliance on global and local geometric cues when reorienting in a virtual environment.

    Science.gov (United States)

    Bodily, Kent D; Kilday, Zachary A; Eastman, Caroline K; Gaskin, Katherine A; Graves, April A; Roberts, Jonathan E; Sturz, Bradley R

    2013-02-01

    In the reorientation literature, non-geometric cues include discrete objects (e.g., beacons) and surface-based features (e.g., colors, textures, and odors). To date, these types of non-geometric cues have been considered functionally similar, and it remains unknown whether beacons and surface features differentially influence the extent to which organisms reorient via global and local geometric cues. In the present experiment, we trained human participants to approach a location in a trapezoid-shaped enclosure uniquely specified by global and local geometric cues. We explored the role of beacons on the use of geometric cues by training participants in the presence or absence of uniquely-colored beacons. We explored the role of surface features on the use of geometric cues by recoloring two adjacent walls at the correct location and/or adding a line on the floor which corresponded to the major principal axis of the enclosure. All groups were then tested in novel-shaped enclosures in the absence of unique beacons and surface features to assess the relative use of global and local geometric cues. Results suggested that beacons facilitated the use of global geometric cues, whereas surface features either facilitated or hindered the use of geometric cues, depending on the feature. Published by Elsevier B.V.

  7. Reorientation of lineation in the Central Crystalline Zone, Munsiari–Milam area of the Kumaun Greater Himalaya

    Indian Academy of Sciences (India)

    A K Verma; A R Bhattacharya

    2015-03-01

    During large scale ductile shear deformation, linear features of the rocks tend to be reoriented towards the direction of bulk shear. This is demonstrated in a crustal scale shear zone of the Himalaya, the Main Central Thrust (MCT), typically exposed in the Munsiari–Milam area of eastern Kumaun Greater Himalaya. Along the MCT, the crystalline rocks of the Greater Himalaya are thrust over the younger sedimentary belt of the Lesser Himalaya. In the study area, the scatter of lineation orientation in the vicinity of the MCT has been observed to drastically reduce within 27° in a zone of about 18 km (about 13 km in the crystalline rocks and about 5 km in the sedimentary rocks). Beyond this zone, the scatter is very high, up to 70° or more. The low scatter of lineation orientation around the MCT could be related to the strong ductile shear deformation associated with the movement along this thrust due to which the linear features got reoriented towards the direction of bulk shear. Away from this zone, ductile shearing had negligible or no effect on the rocks and, therefore, the scatter of lineation remains very high.

  8. Development of skin conductance orienting, habituation, and reorienting from ages 3 to 8 years: a longitudinal latent growth curve analysis.

    Science.gov (United States)

    Gao, Yu; Raine, Adrian; Dawson, Michael E; Venables, Peter H; Mednick, Sarnoff A

    2007-11-01

    Little is known about the development of the skin conductance orienting response (SCOR) in childhood. This longitudinal study examines the effects of age on initial SCOR, habituation, and reorienting. Skin conductance responses to nonsignal auditory stimuli were recorded from 200 male and female children at five different time points (ages 3, 4, 5, 6, and 8 years). Longitudinal latent growth curve analyses were used to determine the trajectory of each SCOR measure during this period. Results indicated that (a) initial SCOR is present at age 3, increases thereafter to peak at age 6, and then levels off, (b) habituation is absent at age 3, but becomes apparent at age 4 years and increases thereafter with increasing age, (c) SC reorienting is absent from ages 3 to 8, and (d) boys and girls do not exhibit different developmental trajectories. Results suggest that from age 3 to 8 years, the transition from the functionally immature to mature neural network underlying orienting and habituation is a continuous process and may be related to children's cognitive development during this period.

  9. Ab initio prediction of giant magnetostriction and spin-reorientation in strained Au/FeCo/MgO heterostructure

    Energy Technology Data Exchange (ETDEWEB)

    Ong, P.V., E-mail: phuongvu.ong@csun.edu; Kioussis, Nicholas, E-mail: nick.kioussis@csun.edu

    2016-02-15

    Employing ab initio electronic structure calculations we have investigated the magnetostrictive properties and the effect of epitaxial strain on the magnetic anisotropy (MA) of Au/FeCo/MgO heterostructure. Under small expansive strain on the FeCo layer the system exhibits an in-plane MA. The calculations reveal that the strain dependence of the MA is nonlinear and that the FeCo film undergoes a spin reorientation at a critical strain between 2 and 4%. The underlying mechanism is the strain-induced shift of the spin–orbit coupled d-states of the Fe atoms. We predict a giant magnetostriction coefficient of about 420×10{sup −6} in the heterostructure. - Highlights: • Nonlinear strain dependence of magnetic anisotropy. • The FeCo film undergoes a spin reorientation at a critical strain between 2 and 4%. • The underlying mechanism is the strain-induced shift of the spin–orbit coupled d-states of the Fe atoms. • Giant magnetostriction coefficient of about 420×10{sup -6} in the heterostructure.

  10. Recalling academic tasks

    Science.gov (United States)

    Draper, Franklin Gno

    This study was focused on what students remembered about five middle school science tasks when they were juniors and seniors in high school. Descriptions of the five tasks were reconstructed from available artifacts and teachers' records, notes and recollections. Three of the five tasks were "authentic" in the sense that students were asked to duplicate the decisions practitioners make in the adult world. The other two tasks were more typical school tasks involving note taking and preparation for a quiz. All five tasks, however, involved use of computers. Students were interviewed to examine what and how well they recalled the tasks and what forms or patterns of recall existed. Analysis of their responses indicated that different kinds of tasks produced different levels of recall. Authentically situated tasks were remembered much better than routine school tasks. Further, authentic tasks centered on design elements were recalled better than those for which design was not as pivotal. Patterns of recall indicated that participants most often recalled the decisions they made, the scenarios of the authentically situated tasks, the consequences of their tasks and the social contexts of the classroom. Task events, in other words, appeared to form a framework upon which students constructed stories of the tasks. The more salient the events, the richer the story, the deeper and more detailed the recall of the task. Thus, authentic tasks appeared to lend themselves to creating stories better than regular school tasks and therefore such tasks were recalled better. Implications of these patterns of recall are discussed with respect to issues of school learning and assessment.

  11. Magnetization reorientation induced by interfacial structures in ultrathin disordered FePt film sandwiched by SiO{sub 2} layers

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Guang; Zhang, Jing-Yan [Department of Materials Physics and Chemistry, University of Science and Technology Beijing, Beijing 100083 (China); State Key Laboratory of Magnetism, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Wang, Shou-Guo, E-mail: sgwang@iphy.ac.cn [State Key Laboratory of Magnetism, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Jiang, Shao-Long; Zhao, Yun-Chi [Department of Materials Physics and Chemistry, University of Science and Technology Beijing, Beijing 100083 (China); Ma, Qi-Di; Wang, Chao; Dong, Bo-Wen; Liu, Jia-Long; Zhang, Ying; Sun, Young [State Key Laboratory of Magnetism, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Wu, Zheng-Long [Analytical and Testing Center, Beijing Normal University, Beijing 100875 (China); Yu, Guang-Hua, E-mail: ghyu@mater.ustb.edu.cn [Department of Materials Physics and Chemistry, University of Science and Technology Beijing, Beijing 100083 (China)

    2015-10-30

    In general, ultrathin disordered FePt film exhibits in-plane magnetic anisotropy due to large demagnetization fields and negligible volume anisotropy. Here, we demonstrated that magnetization reorientation from in-plane to out-of-plane takes place when ultrathin disordered FePt film is sandwiched by amorphous SiO{sub 2} layers and annealed at 350 °C. Based on the interfacial and structural analysis from X-ray photoelectron spectroscopy and high resolution transmission electron microscopy, the reorientation originates from the electronic structural changes because of strong bonding between Fe and O atoms at the top FePt/SiO{sub 2} interface. This interface anisotropy plays a crucial role in the magnetic behaviour, resulting in magnetization reorientation of ultrathin disordered FePt film.

  12. Electric field triggering the spin reorientation and controlling the absorption and release of heat in the induced multiferroic compound EuTiO3

    Science.gov (United States)

    von Ranke, P. J.; Gama, S.; Ribeiro, P. O.; Carvalho, A. Magnus G.; Alho, B. P.; Alvarenga, T. S. T.; Nobrega, E. P.; Caldas, A.; de Sousa, V. S. R.; Lopes, P. H. O.; de Oliveira, N. A.

    2015-12-01

    We report remarkable results due to the coupling between the magnetization and the electric field induced polarization in EuTiO3. Using a microscopic model Hamiltonian to describe the three coupled sublattices, Eu-(spin-up), Eu-(spin-down), and Ti-(moment), the spin flop and spin reorientation phase transitions were described with and without the electric-magnetic coupling interaction. The external electric field can be used to tune the temperature of the spin reorientation phase transition TSR = TSR(E). When the TSR is tuned around the EuTiO3—Néel temperature (TN = 5.5 K), an outstanding effect emerges in which EuTiO3 releases heat under magnetic field change. The electric field controlling the spin reorientation transition and the endo-exothermic processes are discussed through the microscopic interactions model parameters.

  13. Magnetic anisotropy and spin reorientation effects in Gd/Fe and Gd/(FeCo) multilayers for high density magneto-optical recording

    Science.gov (United States)

    Stavrou, E.; Sbiaa, R.; Suzuki, T.; Knappmann, S.; Röll, K.

    2000-05-01

    We have investigated the anisotropy behavior and temperature dependent changes of the magnetic anisotropy in Gd/Fe and Gd/(FeCo) multilayers. The spin reorientation effects are very important for the super resolution readout in new methods for high-density magneto-optical recording. Gd/(Fe, Co) multilayered films are a good alternative to the common Gd(Fe, Co) alloy films, because the magnetic anisotropy and also spin reorientation effects can be comfortably adjusted by varying the interface and volume anisotropy components and the composition using experimental parameters such as the periodicity λ=tGd+tTM [tGd,tTM: the sublayer thicknesses of the Gd and transition metal Fe, FeCo (TM)] and the ratio of the sublayer thicknesses tGd/tTM. We have found the mechanisms for spin reorientation, which are explained qualitatively with a new model.

  14. Kokkos? Task DAG Capabilities.

    Energy Technology Data Exchange (ETDEWEB)

    Edwards, Harold C.; Ibanez, Daniel Alejandro

    2017-09-01

    This report documents the ASC/ATDM Kokkos deliverable "Production Portable Dy- namic Task DAG Capability." This capability enables applications to create and execute a dynamic task DAG ; a collection of heterogeneous computational tasks with a directed acyclic graph (DAG) of "execute after" dependencies where tasks and their dependencies are dynamically created and destroyed as tasks execute. The Kokkos task scheduler executes the dynamic task DAG on the target execution resource; e.g. a multicore CPU, a manycore CPU such as Intel's Knights Landing (KNL), or an NVIDIA GPU. Several major technical challenges had to be addressed during development of Kokkos' Task DAG capability: (1) portability to a GPU with it's simplified hardware and micro- runtime, (2) thread-scalable memory allocation and deallocation from a bounded pool of memory, (3) thread-scalable scheduler for dynamic task DAG, (4) usability by applications.

  15. On the relative preference of enamine/iminium pathways in an organocatalytic Michael addition reaction.

    Science.gov (United States)

    Patil, Mahendra P; Sunoj, Raghavan B

    2009-05-04

    The mechanism of the organocatalyzed Michael addition between propanal and methyl vinyl ketone is investigated using the density functional and ab intio methods. Different modes of substrate activation offered by a secondary amine (pyrrolidine) organocatalyst are reported. The electrophilic activation of enone (P-I) through the formation of an iminium ion, and nucleophilic activation of propanal (P-II) in the form of enamine have been examined by identifying the corresponding transition states. The kinetic preference for the formation of key intermediates is established in an effort to identify the competing pathways associated with the title reaction. A comparison of barriers associated with different pathways as well as intermediate formation allows us to provide a suitable mechanistic rationale for Michael addition reactions catalyzed by a secondary amine. The overall barriers for the C-C bond formation pathways involving enol or iminium intermediates are identified as higher than the enamine pathway. Additionally, the generation of iminium is found to be less favored as compared to enamine formation. The effect of co-catalyst/protic solvent on the energetics of the overall reaction is also studied using the cluster continuum approach. Significant reduction in the activation energies for each step of the reaction is predicted for the solvent-assisted models. The co-catalyst assisted addition of propanal-enamine to methyl vinyl ketone is identified as the most preferred pathway (P-IV) for the Michael addition reaction. The results are in concurrence with the available experimental reports on the rate acceleration by the use of a co-catalyst in this reaction.

  16. Compassionate leadership? Some reflections on the work and life of Michael Lapsley

    Directory of Open Access Journals (Sweden)

    Ian A. Nell

    2016-03-01

    Full Text Available In June 2007, I had the privilege of attending a Healing of Memories workshop lead by Father Michael Lapsley, one of the founder members of the Institute for Healing of Memories. The purpose of the workshop was to help the predominantly white members of a middle class Dutch Reformed congregation in the Northern Suburbs of Cape Town and the predominantly coloured members of a congregation of the Evangelical Lutheran Church in Elsies River on the Cape Flats, to share their stories of the past with regard to apartheid with each other. Apart from the stories that were told and the sharing of experiences about the apartheid history that took place, I was struck by the way in which Father Lapsley conducted the workshop. There was a deep compassion for all the participants as was embodied through the way in which he treated each of us with respect. But apart from his cordiality in leading the workshop, one could sense a deeper source of compassion, a source revealing a compassionate understanding of God�s presence amidst the violence and turmoil in our broken world. The aim of this article is to reflect on whether one could speak of something like �compassionate leadership�, and to take a closer look at the relationship between compassion and God images in the life and work of Michael Lapsley. Special attention will be given to the way in which he exercises leadership through his many involvements related to his own personal story of trauma.Intradisciplinary and/or interdisciplinary implications: This article presents literary research on the notion of compassionate leadership as a specific kind of leadership. The results indicate that the leadership of Father Michael Lapsley does indeed portray features of this kind of leadership. The research can become the source for finding new strategies for religious leadership.

  17. Enantio- and Diastereoselective Synthesis of exo-Peroxyacetals: An Organocatalyzed Peroxyhemiacetalization/oxa-Michael Addition Cascade.

    Science.gov (United States)

    Maity, Sanjay; Parhi, Biswajit; Ghorai, Prasanta

    2016-06-27

    An unprecedented enantioselective peroxyhemiacetalization/oxa-Michael addition cascade of ortho-formyl homochalcones has been developed using cinchona-alkaloid-based chiral bifunctional organocatalysts to provide cis-configured exo-peroxyacetals, a new class of organic peroxide, in good yields with excellent enantio- and diastereoselectivities. The resulting cis-configured exo-peroxyacetals were converted into the corresponding trans-configured peroxyacetals without affecting the enantioselectivity. Furthermore, the displacement of the peroxide moiety of exo-peroxyacetals with various nucleophiles has been demonstrated to afford 1,3-disubstituted isochromans with high diastereoselectivities and excellent enantioselectivities. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. Michael Porter 30 anos depois de Estratégia Competitiva

    OpenAIRE

    Schneider,Aline; Carneiro,Marcelo; Serra, Fernando; Ferreira, Manuel Portugal

    2008-01-01

    Os estudos de estratégia empresarial têm sido muito influenciados pelos trabalhos de Michael Porter, em particular na estratégia competitiva, análise da indústria e das vantagens competitivas das nações. Neste artigo, analisamos a influência de Porter nos trabalhos brasileiros em estratégia, a partir dos trabalhos selecionados e apresentados no ENANPAD. No levantamento para a análise dos artigos, considerando 10 anos de ENANPAD (1997 – 2006), foram selecionados 46 artigos. A identificação e s...

  19. Michael Lloyd. Sophocles: Electra : Duckworth, London, 2005, 160 pp.

    OpenAIRE

    Moretti, María Inés

    2008-01-01

    Este estudio sobre Electra de Sófocles pertenece a la serie «Duckworth Companions to Greek and Roman Tragedy», editada por Thomas Harrison, cuyo objetivo es proporcionar introducciones para tragedias antiguas y discutir los aspectos principales de las obras incorporando los nuevos desarrollos de la crítica moderna. Sophocles: Electra de Michael Lloyd, resulta al mismo tiempo un libro simple pero muy completo, didáctico, para un público no especializado, aunque interesante también para los esp...

  20. Critical notice: Michael Tomasello on the “prosocial” human animal

    DEFF Research Database (Denmark)

    Larsen, Steen Nepper

    2014-01-01

    Abstract According to Michael Tomasello humans cannot help to be informative. Apes, like chimps, do not point at each other, only humans do so in order to attract attention, i.e. to (get) help, play and share experiences. In shared cooperative activities, individual rationality is transformed...... of the prosocial nature of the infant lacks convincing arguments; Tomasello reflects and honours the Zeitgeist (i.e. the hope that we will see a scientific shift away from predominant methodological individualism towards more ‘social’ and ‘emphatic’ ways of thinking); his concepts of language as a tool...

  1. The Great War and All That in A Hundred Doors by Michael Longley

    Directory of Open Access Journals (Sweden)

    Elisabeth Delattre

    2015-03-01

    Full Text Available The Great War has featured regularly in Michael Longley’s poetry, for personal, family, aesthetic and political reasons. His collection published in 2011 under the title A Hundred Doors contains a number of poems relating to his father and the so-called War Poets, in connection with others in which love and nature, life and death are also dominant themes. This article will show how, as elsewhere in his poetry, everything is interrelated, “the nature poetry”, in Longley’s words, “fertilizing the war poetry”.

  2. Michael Farquhar, Circuits of Faith: Migration, Education and the Wahhabi Mission

    OpenAIRE

    Pétriat, Philippe

    2017-01-01

    Using the concept of what he calls a “transnational religious economy” centered on the Islamic University of Medina (IUM), Michael Farquhar’s Circuits of Faith is an important and historicized contribution to the debate over the export of Wahhabism and its role in global Salafism. The detailed history of the IUM is probably the main interest of this book based on an array of IUM publications (syllabuses) and interviews. It deals with historicized facts and provides precise knowledge of one o...

  3. An Interview with Michael Betancourt, author of Agnotology & Crisis in Digital Capitalism

    Directory of Open Access Journals (Sweden)

    Sean Scanlan

    2015-03-01

    Full Text Available Sean Scanlan, NANO's editor, interviews artist, curator, art historian and critical theorist Michael Betancourt to discuss the nature of agnotology, a term that means the “creation of uncertainty and ambivalent ‘fact’; it is a competitive tool incompatible with the idealized ‘free market’ of capitalism.” Betancourt is skeptical of Big Data and the ways that the consumers who unknowingly “produce” data for business interpretation are increasingly becoming transformed into a “token of exchange (valorized by the database.”

  4. Michael E. Lamb: Award for Distinguished Senior Career Contributions to Psychology in the Public Interest.

    Science.gov (United States)

    2015-11-01

    The APA Awards for Distinguished Contributions to Psychology in the Public Interest recognize persons who have advanced psychology as a science and/or profession by a single extraordinary achievement or a lifetime of outstanding contributions in the public interest. The 2015 co-recipient of the Award for Distinguished Senior Career Contributions to Psychology in the Public Interest is Michael E. Lamb. Lamb was selected because his "work profoundly shaped the fields of developmental psychology, social welfare, child and family policy, and law." Lamb's award citation, biography, and a selected bibliography are presented here.

  5. Asymmetric synthesis of fully substituted cyclopentane-oxindoles through an organocatalytic triple Michael domino reaction.

    Science.gov (United States)

    Zou, Liang-Hua; Philipps, Arne R; Raabe, Gerhard; Enders, Dieter

    2015-01-12

    An efficient, highly stereoselective asymmetric synthesis of fully functionalized cyclopentanes bearing an oxindole moiety and several other functional groups in one pot has been developed. Key step is an organocatalytic triple Michael domino reaction forming three C-C bonds and six stereocenters, including a quaternary one. Starting from equimolar amounts of simple substrates, a high molecular complexity can be reached after a Wittig olefination in one pot. The new protocol can easily be scaled up to gram amounts. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Social and Racial Problem Exposed in Michael Jackson’s Selected Songs

    OpenAIRE

    2015-01-01

    In this thesis, I analyze some of Michael Jackson’ songs which concern to the negatively social and racial problem. Social problem that happened to the society in this world, then racial problem that happened to the Black people, such as: Skin Color, Prejudice, Discrimination, Stereotypes, and Racial Segregation. In his songs entitled Heal The World, We Are The World, and The Man In The Mirror have the meaning of to make a better world. Other songs entitled Black or White, and They Don’t Care...

  7. Michael Butter, Patrick Keller, and Simon Wendt, eds. Arnold Schwarzenegger: Interdisciplinary Perspectives on Body and Image.

    OpenAIRE

    Liokaftos, Dimitrios

    2012-01-01

    Arnold Schwarzenegger: Interdisciplinary Perspectives on Body and Image has been edited by Michael Butter, Patrick Keller, and Simon Wendt, all of whom have contributed individual essays to the volume.Most of the essays appearing in this collection were first presented at the “Arnold Schwarzenegger: Interdisziplinäre Perspektiven auf Körper und Image” conference that took place at the Heidelberg Centre for American Studies from September 18-20, 2009. Although there is no formal division of th...

  8. 专访BEA首席技术专家Michael Smith

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    WebLogic Platform8.1是BEA第一款中文化的产品.由此也足见BEA对这款产品以及中国市场的重视。为了这次“开发者日”.BEA公司CTO办公室首席技术专家Michael Smith也赶到中国.并接受了笔者的专访。以下是关于WebLogic Platform的对话。

  9. Realismo y antirrealismo en la filosofía de Michael Dummett

    OpenAIRE

    Pablo Cubides; David González; David Rey

    2013-01-01

    Michael Dummett es reconocido por haber propuesto una caracterización semántica del debate realismo-antirrealismo. A partir de esta caracterización, Dummett busca defender una aproximación ascendente a los problemas metafísicos tradicionales, la cual consiste en resolver los desacuerdos metafísicos entre el realista y el antirrealista mediante la elaboración de teorías semánticas para ciertos conjuntos de enunciados. En este artículo argumentamos que la caracterización de Dummett no captura l...

  10. Project Tasks in Robotics

    DEFF Research Database (Denmark)

    Sørensen, Torben; Hansen, Poul Erik

    1998-01-01

    Description of the compulsary project tasks to be carried out as a part of DTU course 72238 Robotics......Description of the compulsary project tasks to be carried out as a part of DTU course 72238 Robotics...

  11. Launching Complex Tasks

    Science.gov (United States)

    Jackson, Kara J.; Shahan, Emily C.; Gibbons, Lynsey K.; Cobb, Paul A.

    2012-01-01

    Mathematics lessons can take a variety of formats. In this article, the authors discuss lessons organized around complex mathematical tasks. These lessons usually unfold in three phases. First, the task is introduced to students. Second, students work on solving the task. Third, the teacher "orchestrates" a concluding whole-class discussion in…

  12. Task assignment and coaching

    NARCIS (Netherlands)

    Dominguez-Martinez, S.

    2009-01-01

    An important task of a manager is to motivate her subordinates. One way in which a manager can give incentives to junior employees is through the assignment of tasks. How a manager allocates tasks in an organization, provides information to the junior employees about his ability. Without coaching fr

  13. Elevated levels of 4-hydroxynonenal-histidine Michael adduct in the hippocampi of patients with Alzheimer's disease.

    Science.gov (United States)

    Fukuda, Mitsugu; Kanou, Fumihisa; Shimada, Nobuko; Sawabe, Motoji; Saito, Yuko; Murayama, Shigeo; Hashimoto, Masakatsu; Maruyama, Naoki; Ishigami, Akihito

    2009-08-01

    Alzheimer's disease (AD) is among the most common causes of progressive cognitive impairment in humans and is characterized by neurodegeneration in the brain. Lipid peroxidation is thought to play a role in the pathogenesis of AD. 4-hydroxynonenal (HNE) results from peroxidation of polyunsaturated fatty acids and it in turn gives evidence of lipid peroxidation in vivo. HNE reacts with protein histidine residue to form a stable HNE-histidine Michael adduct. To clarify the influence of lipid peroxidation on the pathogenesis of AD, we measured HNE-histidine Michael adduct in hippocampi from four AD patients and four age-matched controls by means of semiquantitative immunohistochemistry using a specific antibody to cyclic hemiacetal type of HNE-histidine Michael adduct. This antibody does not react with the ring-opened form of HNE-histidine Michael adduct and the pyrrole form of HNE-lysine Michael adduct. The HNE adduct was detected in the hippocampi of both AD and control donors, especially in the CA2, CA3 and CA4 sectors. Immunoreactive intensity of HNE adduct in these sectors were significantly higher in AD patients than in the controls. The HNE adduct was found in the perikarya of pyramidal cells in the hippocampus. These results show that the hippocampi of patients with AD undergo lipid peroxidation and imply that this activity underlies the production of cytotoxic products such as HNE that are responsible for the pathogenesis of AD.

  14. Ferroelectricity and magnetoelectric coupling in h-YbMnO{sub 3}: Spin reorientation and defect effect

    Energy Technology Data Exchange (ETDEWEB)

    Qiang, Gang; Fang, Yifei; Lu, Xiaowen; Cao, Shixun; Zhang, Jincang, E-mail: jczhang@shu.edu.cn [Materials Genome Institute and Department of Physics, Shanghai University, Shanghai 200444 (China)

    2016-01-11

    Low-temperature magnetic and electric properties in hexagonal multiferroic compound YbMnO{sub 3} were studied. The Mn{sup 3+} spin moments order at T{sub N} = 85 K and reoriented around 43.5 K, leading to the magnetic phase transition from B{sub 2}(P6{sub 3}cm) → A{sub 2}(P6{sub 3}cm). The concomitant ferroelectric polarization is observed and explained microscopically by the destruction of initial symmetric relationship of the polarization between the upper and lower half of the magnetic unit cell. The asymmetry of the polarization vs temperature curves under opposite poling voltage revealed the pinning effect of the defects on the electrical polarization.

  15. Element-resolved magnetism across the temperature- and pressure-induced spin reorientation in MnBi

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Yongseong; Jiang, Xiujuan; Bi, Wenli; Lapa, Pavel; Chouhan, Rajiv K.; Paudyal, D.; Varga, Tamas; Popov, Dmitry; Cui, Jun; Haskel, Daniel; Jiang, J. S.

    2016-11-01

    Rare-earth free permanent magnet MnBi (NiAs-type crystal structure) displays strong magnetic anisotropy above its 90 K spin reorientation transition (SRT). X-ray magnetic circular dichroism (XMCD) shows induced magnetism in Bi 5d band, which is strongly coupled to the magnetism of Mn. A clear increase in Bi orbital-to-spin moment ratio is observed above the SRT. Hydrostatic pressure mimics the e*ect of temperature on the SRT, and the pressure effect also leads to anisotropic lattice contraction, which is known to be induced by cooling. These results reveal that temperature and pressure can similarly induce the coupled structural and magnetic responses, suggesting the importance of the anisotropic lattice change and Mn-Bi hybridization to the magnetic anisotropy change across the SRT.

  16. Stripe-to-bubble transition of magnetic domains at the spin reorientation of (Fe/Ni)/Cu/Ni/Cu(001)

    Energy Technology Data Exchange (ETDEWEB)

    Wu, J.; Choi, J.; Won, C.; Wu, Y. Z.; Scholl, A.; Doran, A.; Hwang, Chanyong; Qiu, Z.

    2010-06-09

    Magnetic domain evolution at the spin reorientation transition (SRT) of (Fe/Ni)/Cu/Ni/Cu(001) is investigated using photoemission electron microscopy. While the (Fe/Ni) layer exhibits the SRT, the interlayer coupling of the perpendicularly magnetized Ni layer to the (Fe/Ni) layer serves as a virtual perpendicular magnetic field exerted on the (Fe/Ni) layer. We find that the perpendicular virtual magnetic field breaks the up-down symmetry of the (Fe/Ni) stripe domains to induce a net magnetization in the normal direction of the film. Moreover, as the virtual magnetic field increases to exceed a critical field, the stripe domain phase evolves into a bubble domain phase. Although the critical field depends on the Fe film thickness, we show that the area fraction of the minority domain exhibits a universal value that determines the stripe-to-bubble phase transition.

  17. [Hallux valgus and hypermobility of the first ray--causal treatment using tarso-metatarsal reorientation arthrodesis].

    Science.gov (United States)

    Klaue, K

    1991-12-01

    Today, bunion surgery is still very controversial. Considering that a bunion deformity is actually a result of multiple possible causes, the rationale of the currently applied techniques has not been conclusively demonstrated. Multiple techniques are still applied with uncertain outcome, as shown by the not insignificant recurrence rate. The tarsometatarsal reorientation arthrodesis addresses the deficient anteromedial buttress which is due to the most often concomittent hypermobile first ray. This is an important aspect of treating hallux valgus deformity and includes the sagittal alignment besides the horizontal reposition of the metatarsal over the sesamoid complex. Since in hallux valgus, the first metatarsal looses its position also by the insufficiency of the intrinsic musculature and the ligamento-capsular structures, the arthrodesis regulates the elasticity of the multiarticular first ray within the sagittal plane. Recurrences are less likely after this operation, even when performed on the adolescent hallux which is known as very difficult to be treated successfully.

  18. Probing temperature-driven spin reorientation transition of GdFeCo film by Kerr loops and ferromagnetic resonance

    Energy Technology Data Exchange (ETDEWEB)

    He, Wei, E-mail: hewei@aphy.iphy.ac.cn; Liu, Hao-Liang; Cai, Jian-Wang; Cheng, Zhao-Hua, E-mail: zhcheng@aphy.iphy.ac.cn [State Key Laboratory of Magnetism and Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Wu, Hong-Ye [Department of Physics, Baotou Teachers College, Baotou 014030 (China)

    2015-01-26

    The magnetic anisotropy is of both scientific and technological interest for magneto-optical material GdFeCo film. We characterize the magnetic anisotropy of a 20 nm GdFeCo film from 265 K to 320 K via Kerr loops and ferromagnetic resonance. With increasing temperature, both of the first-order uniaxial magnetic anisotropy and shape anisotropy increase. However, the competition between them causes a temperature-driven spin reorientation transition (SRT) and the effective perpendicular magnetic anisotropy decrease from 2.22 × 10{sup 4 }ergs/cm{sup 3} (288 K) to −1.56 × 10{sup 4 }ergs/cm{sup 3} (317 K). The positive second-order uniaxial magnetic anisotropy determines an easy-cone state as the mediated state during SRT.

  19. Microscopic analysis of the composition driven spin-reorientation transition in Ni(x)Pd(1-x)/Cu(001).

    Science.gov (United States)

    Gottlob, Daniel M; Doğanay, Hatice; Nickel, Florian; Cramm, Stefan; Krug, Ingo P; Nemšák, Slavomír; Schneider, Claus M

    2015-12-01

    The spin-reorientation transition (SRT) in epitaxial NixPd1-x/Cu(001) is studied by photoemission microscopy utilizing the X-ray magnetic circular dichroism effect at the Ni L2,3 edge. In a composition/thickness wedged geometry, a composition driven SRT could be observed between 37 ML and 60 ML, and 0 and 38% of Pd. Microspectroscopy in combination with azimuthal sample rotation confirms a magnetization preference changing from the [001] to an in-plane easy axis. At this increased thickness, the domain patterns arrange comparable to SRTs in ultrathin films. The images document domains equivalent to a canted state SRT, at which an additional effect of in-plane anisotropies could be identified.

  20. LECTURE CANCELLED - “The power of collaboration - innovating collaborative relationships" by Michael Kimmel | 8 March

    CERN Multimedia

    2013-01-01

    PLEASE NOTE THAT THIS LECTURE IS CANCELLED Friday, 8 March -  from 11.30 a.m. to 1 p.m. Globe of Science and Innovation Route de Meyrin, 1211 Geneva International Women’s Day Conference Lecture will be in English - Interpreting available in French Limited number of seats - registration is essential Reservation: + 41 22 767 76 76 or cern.reception@cern.ch Dr. Michael Kimmel, a renowned sociologist and an expert on male-female relationships, will share his latest findings on gender collaboration and how it can lead to innovation and improved relationships both at work and in the world outside. Michael Kimmel is among the world’s leading experts on male-female relationships. A Professor of Sociology at the State University of New York at Stony Brook, he is the author or editor of more than 20 books on the topic. He consults corporations, NGOs and public sector organisations all over the world on gender equity issues, including work-family balance, reducing workplac...

  1. The role of noninnocent solvent molecules in organocatalyzed asymmetric Michael addition reactions.

    Science.gov (United States)

    Patil, Mahendra P; Sunoj, Raghavan B

    2008-01-01

    A proline-catalyzed asymmetric Michael addition between ketones and trans-beta-nitrostyrene was studied by using the density-functional theory with mPW1PW91 and B3LYP functionals. Improved insight into the enantio- and diastereoselective formation of gamma-nitroketones/-aldehydes is obtained through transition-state analysis. Consideration of the activation parameters obtained from gas-phase calculations and continuum solvation models failed to reproduce the reported experimental stereoselectivities for the reaction between cyclohexanone and 3-pentanone with trans-beta-nitrostyrene. The correct diastereo- and enantioselectivites were obtained only upon explicit inclusion of solvent molecules in the diastereomeric transition states that pertain to the C--C bond formation. Among the several transition-state models that were examined, the one that exhibits cooperative hydrogen-bonding interactions with two molecules of methanol could explain the correct stereochemical outcome of the Michael reaction. The change in differential stabilization that arises as a result of electrostatic and hydrogen-bonding interactions in the key transition states is identified as the contributing factor toward obtaining the correct diastereomer. This study establishes the importance of including explicit solvent molecules in situations in which the gas-phase and continuum models are inadequate in obtaining meaningful insight regarding experimental stereoselectivities.

  2. Adapting Shakespeare – Converting Shylock in Michael Radford’s the Merchant of Venice

    Directory of Open Access Journals (Sweden)

    Oakes Luke

    2016-08-01

    Full Text Available This article aims to explore the extension and evolution of Shakespeare’s The Merchant of Venice through Michael Radford’s 2004 cinematic adaptation. By investigating the concept of adaptation and the significance of intertextuality, Shakespeare’s source text is considered alongside Radford’s twenty-first century recreation to reimagine and redefine the construction of Shylock as both a comic and tragic device utilized across film and play. Issues of racial and religious prejudices alongside anti- Semitic views were particularly prominent in Elizabethan England and, by concentrating on recontextualisation, this article looks to expose Shakespeare’s characterization as a reflective commentary concerning societal discriminations at the time of the play’s performance. By focusing primarily on Shakespeare’s Jewish Usurer, Radford is able to reconstruct and reestablish the dramatic devices and characters within the cinematic version, metaphorically converting Shylock from comic villain to tragic victim. Finally, it argues that this dynamic shift inevitably metamorphoses Shylock from a spectator’s perspective and provides Michael Radford with an opportunity to offer a social commentary on social inequality in the twenty-first century.

  3. Bioengineered vascular graft with autologous stem cells: first use in the clinic. Interview with Michael Olausson.

    Science.gov (United States)

    Olausson, Michael

    2012-11-01

    Michael Olausson talks to Regenerative Medicine about the pioneering clinical use of a bioengineered vascular graft to treat a 9-year-old girl with extrahepatic portal vein obstruction and the future potential of bioengineered vessels. Michael Olausson has been Professor of Transplantation Surgery at Gothenburg University (Gothenburg, Sweden) since 2000, and was Chairman of the Sahlgrenska Transplant Institute at Sahlgrenska University Hospital (Gothenburg, Sweden) between 1994 and June 2011. His scientific interests include transplant immunology and experimental and clinical transplantation studies. He has published over 240 original articles, reviews and book chapters in the field of transplantation. He has been invited as a speaker at several national and international meetings all over the world. He has pioneered several innovative surgical procedures in the Nordic countries, Europe and the rest of the world. Last year, he performed the first operation in the world using a stem cell-derived vein and recently he performed the two first mother-to-daughter live donor uterus transplantations in the world, together with a team from Gothenburg. In the past, he has been President of The Swedish Transplantation Society, and board member and Vice President of the European Liver and Intestinal Transplantation Association. In 2008 he received the Carl-Gustav Groth Scandinavian Transplant Prize.

  4. Traces of the Unrepresentable in the Modernist Discourse of Clement Greenberg and Michael Fried

    Directory of Open Access Journals (Sweden)

    Gal, Nissim

    2013-08-01

    Full Text Available The present essay aims to remap the modernist writing of Clement Greenberg and his successor Michael Fried from the late 1930s to the 1960s. For many years these two critics/theorists were considered leaders of the American modernist camp that promoted the purity of the medium and the total dependence of reading art on the primacy of perception. Attentive reading of the canonical texts they authored will surprisingly reveal that between the theoretical lines of their writings dwells an essential element that contradicts the absolute dominance of eyesight. Lying at the heart of the Greenbergian act is a metaphysical foundation that poses the question of the invisible as part of the inquiry into the "essence of the visible". As such the modernist debate will be revealed not only as a means for assembling a canon of works, but also as a means to formulating an experience of revelation in terms of the visual. Attentive reading of the writings of Clement Greenberg and the early Michael Fried, reveals a theoretical element or regulative idea that will be termed here "the unrepresentable".

  5. Spin reorientation in α-Fe2O3 nanoparticles induced by interparticle exchange interactions in alpha-Fe2O3/NiO nanocomposites

    DEFF Research Database (Denmark)

    Frandsen, Cathrine; Lefmann, Kim; Lebech, Bente

    2011-01-01

    We report that the spin structure of alpha-Fe2O3 nanoparticles rotates coherently out of the basal (001) plane at low temperatures when interacting with thin plate-shaped NiO nanoparticles. The observed spin reorientation (up to similar to 70 degrees) in alpha-Fe2O3 nanoparticles has, in appearan...

  6. Spin reorientation in α-Fe2O3 nanoparticles induced by interparticle exchange interactions in alpha-Fe2O3/NiO nanocomposites

    DEFF Research Database (Denmark)

    Frandsen, Cathrine; Lefmann, Kim; Lebech, Bente;

    2011-01-01

    We report that the spin structure of alpha-Fe2O3 nanoparticles rotates coherently out of the basal (001) plane at low temperatures when interacting with thin plate-shaped NiO nanoparticles. The observed spin reorientation (up to similar to 70 degrees) in alpha-Fe2O3 nanoparticles has, in appearan...

  7. Cellular basis for the automorphic curvature of rice coleoptiles on a three-dimensional clinostat: possible involvement of reorientation of cortical microtubules.

    Science.gov (United States)

    Saiki, Mizue; Fujita, Hiroshi; Soga, Kouichi; Wakabayashi, Kazuyuki; Kamisaka, Seiichiro; Yamashita, Masamichi; Hoson, Takayuki

    2005-06-01

    Coleoptiles of rice (Oryza sativa L.) show a spontaneous (automorphic) curvature toward the caryopsis under microgravity conditions. The possible involvement of the reorientation of cortical microtubules in automorphic curvature was studied in rice coleoptiles grown on a three-dimensional clinostat. When rice seedlings that had been grown in the normal gravitational field were transferred to the clinostat in the dark, cortical microtubules of epidermal cells in the dorsal side of the coleoptiles oriented more transversely than the ventral side within 0.5 h. The rotation on the clinostat also increased the cell wall extensibility in the dorsal side and decreased the extensibility in the ventral side, and induced automorphic curvature. The reorientation of cortical microtubules preceded the changes in the cell wall extensibility and the curvature. The irradiation of rice seedlings with white light from above inhibited microtubule reorientation and changes in the cell wall extensibility, as well as curvature of coleoptiles. Also, colchicine, applied to the bending region of coleoptiles, partially inhibited the automorphic curvature. These results suggest that reorientation of cortical microtubules is involved in causing automorphic curvature in rice coleoptiles on the clinostat.

  8. Transient increase in the levels of γ-tubulin complex and katanin are responsible for reorientation by ethylene and hypergravity of cortical microtubules.

    Science.gov (United States)

    Soga, Kouichi; Yamaguchi, Aya; Kotake, Toshihisa; Wakabayashi, Kazuyuki; Hoson, Takayuki

    2010-11-01

    The body shape of a plant is primarily regulated by orientation of cortical microtubules. γ-Tubulin complex and katanin are required for the nucleation and the severing of microtubules, respectively. Here we discuss the role of γ-tubulin complex and katanin during reorientation of cortical microtubules. 1-Aminocyclopropane-1-carboxylic acid (ACC), the immediate precursor of ethylene, modifies growth anisotropy of azuki bean epicotyls; it inhibits elongation growth and promotes lateral growth. The ACC-induced reorientation of cortical microtubules from transverse to longitudinal directions preceded the modification of growth anisotropy. The transcript level of γ-tubulin complex (VaTUG and VaGCP3) and katanin (VaKTN1) was increased transiently by ACC treatment. During reorientation of cortical microtubules by hypergravity, which also modifies growth anisotropy of shoots, the expression levels of both γ-tubulin complex and katanin genes were increased transiently. The increase in the number of the nucleated microtubule branch as well as the microtubule-severing activity via upregulation of γ-tubulin complex genes and katanin genes may be involved in the reorientation of cortical microtubules, and contribute to the regulation of the shape of plant body.

  9. (1)H and (19)F spin-lattice relaxation and CH3 or CF3 reorientation in molecular solids containing both H and F atoms.

    Science.gov (United States)

    Beckmann, Peter A; Rheingold, Arnold L

    2016-04-21

    The dynamics of methyl (CH3) and fluoromethyl (CF3) groups in organic molecular (van der Waals) solids can be exploited to survey their local environments. We report solid state (1)H and (19)F spin-lattice relaxationexperiments in polycrystalline 3-trifluoromethoxycinnamic acid, along with an X-ray diffraction determination of the molecular and crystal structure, to investigate the intramolecular and intermolecular interactions that determine the properties that characterize the CF3 reorientation. The molecule is of no particular interest; it simply provides a motionless backbone (on the nuclear magnetic resonance(NMR) time scale) to investigate CF3 reorientation occurring on the NMR time scale. The effects of (19)F-(19)F and (19)F-(1)H spin-spin dipolar interactions on the complicated nonexponential NMRrelaxation provide independent inputs into determining a model for CF3 reorientation. As such, these experiments provide much more information than when only one spin species (usually (1)H) is present. In Sec. IV, which can be read immediately after the Introduction without reading the rest of the paper, we compare the barrier to CH3 and CF3 reorientation in seven organic solids and separate this barrier into intramolecular and intermolecular components.

  10. A polystyrene-supported 9-amino(9-deoxy)epi quinine derivative for continuous flow asymmetric Michael reactions.

    Science.gov (United States)

    Izquierdo, Javier; Ayats, Carles; Henseler, Andrea H; Pericàs, Miquel A

    2015-04-14

    A polystyrene (PS)-supported 9-amino(9-deoxy)epi quinine derivative catalyzes Michael reactions affording excellent levels of conversion and enantioselectivity using different nucleophiles and structurally diverse enones. The highly recyclable, immobilized catalyst has been used to implement a single-pass, continuous flow process (residence time: 40 min) that can be operated for 21 hours without significant decrease in conversion and with improved enantioselectivity with respect to batch operation. The flow process has also been used for the sequential preparation of a small library of enantioenriched Michael adducts.

  11.  Bibliographie annotée des œuvres publiées de Michael Leff

    Directory of Open Access Journals (Sweden)

    Steven R. Edscorn

    2011-04-01

    Full Text Available LivresLeff, Michael & Fred Kauffeld (eds. 1989. Texts in Contexts: Dialogues on Significant Episodes in American Political Rhetoric [Textes en contexte : dialogues sur les épisodes significatifs de la rhétorique politique américaine] (Davis: Hermagoras PressCe recueil de dialogues tente de recréer l’esprit et l’orientation des discussions tenues au cours du « Symposium du Wisconsin sur le discours public : études de cas de rhétorique politique ». Horner, Winifred & Michael Leff (eds. 1995....

  12. Isoindolinones as Michael Donors under Phase Transfer Catalysis: Enantioselective Synthesis of Phthalimidines Containing a Tetrasubstituted Carbon Stereocenter

    Directory of Open Access Journals (Sweden)

    Francesco Scorzelli

    2015-05-01

    Full Text Available Readily available chiral ammonium salts derived from cinchona alkaloids have proven to be effective phase transfer catalysts in the asymmetric Michael reaction of 3-substituted isoindolinones. This protocol provides a convenient method for the construction of valuable asymmetric 3,3-disubstituted isoindolinones in high yields and  moderate to good enantioselectivity. Diastereoselectivity was also investigated in the construction of contiguous tertiary and quaternary stereocenters. The use of acrolein as Michael acceptor led to an interesting tricyclic derivative, a pyrroloisoindolinone analogue, via a tandem conjugated addition/cyclization reaction.

  13. N-Heterocyclic Carbene-Catalysed Diastereoselective Vinylogous Michael Addition Reaction of gamma-Substituted deconjugated Butenolides

    KAUST Repository

    Guo, Hao

    2015-11-16

    An efficient N-heterocyclic carbene (NHC)-catalysed vinylogous Michael addition of deconjugated butenolides was developed. In the presence of 5 mol% of the NHC catalyst, both γ-alkyl and aryl-substituted deconjugated butenolides undergo vinylogous Michael addition with various α, β-unsaturated ketones, esters, or nitriles to afford γ,γ-disubstituted butenolides containing adjacent quaternary and tertiary carbon centers in good to excellent yields with excellent diastereoselectivities. In this process, the free carbene is assumed to act as a strong Brønsted base to promote the conjugate addition.

  14. Overtraining and the use of feature and geometric cues for reorientation.

    Science.gov (United States)

    Sturz, Bradley R; Gaskin, Katherine A; Bodily, Kent D

    2013-03-01

    Using a dynamic three-dimensional virtual environment task, we investigated the influence of overtraining of feature and geometric cues on preferential spatial cue use. We trained two groups of human participants to respond to feature and geometric cues in separate enclosures before placing these cues in conflict on a critical test trial. All participants learned to respond to rewarded features located along the principal axis of a rectangular search space and to rewarded geometric cues of a rectangular search space in separate training phases followed by a single test trial. During the test trial, we situated the rewarded features in the unrewarded geometric corners and the unrewarded features in rewarded geometric corners. For one group, participants were overtrained with feature cues compared to geometric cues before experiencing the conflict test; whereas, for another group, participants were overtrained with geometric cues compared to feature cues before experiencing the conflict test. Although both groups learned to respond to both feature and geometric cues at an equivalent rate and to an equivalent level of terminal accuracy, testing results revealed no difference between the groups with respect to their preference for feature or geometric cues. Despite a lack of influence of overtraining on spatial cue preference, participants showed an overall preference for feature cues. We discuss the results with respect to implications for theoretical accounts of spatial learning.

  15. Cue salience influences the use of height cues in reorientation in pigeons (Columba livia).

    Science.gov (United States)

    Du, Yu; Mahdi, Nuha; Paul, Breanne; Spetch, Marcia L

    2016-07-01

    Although orienting ability has been examined with numerous types of cues, most research has focused only on cues from the horizontal plane. The current study investigated pigeons' use of wall height, a vertical cue, in an open-field task and compared it with their use of horizontal cues. Pigeons were trained to locate food in 2 diagonal corners of a rectangular enclosure with 2 opposite high walls as height cues. Before each trial, pigeons were rotated to disorient them. In training, pigeons could use either the horizontal cues from the rectangular enclosure or the height information from the walls to locate the food. In testing, the apparatus was modified to provide (a) horizontal cues only, (b) height cues only, and (c) both height and horizontal cues in conflict. In Experiment 1 the lower and high walls, respectively, were 40 and 80 cm, whereas in Experiment 2 they were made more perceptually salient by shortening them to 20 and 40 cm. Pigeons accurately located the goal corners with horizontal cues alone in both experiments, but they searched accurately with height cues alone only in Experiment 2. When the height cues conflicted with horizontal cues, pigeons preferred the horizontal cues over the height cues in Experiment 1 but not in Experiment 2, suggesting that perceptual salience influences the relative weighting of cues. (PsycINFO Database Record

  16. Michael Hauskeller: Sex and the Posthuman Condition : Palgrave-Macmillan, 2014, 98 pp.

    Science.gov (United States)

    Miller, Lantz Fleming

    2016-10-01

    This new book from Michael Hauskeller explores the currently marketed or projected sex/love products that exhibit some trait of so-called "posthumanistic" theory or design. These products are so designated because of their intention to fuse high technologies, including robotics and computing, with the human user. The author offers several arguments for why the theory behind these products leads to inconsistencies. The book uses a unique approach to philosophical argument by enmeshing the argument's major points in a concomitant discussion of pieces from world literature pertaining to posthumanism. The method is compelling, heightened by great world authorial insights that rarely find their way into philosophy and shores up some strong argumentative points. Yet some of the argument still needs more elucidating.

  17. Tradições e rupturas no cinema político de Michael Moore

    OpenAIRE

    Cristiane Toledo Maria

    2015-01-01

    Esta pesquisa tem como objetivo analisar a produção fílmica do cineasta norte-americano Michael Moore, tendo como questão central a relação que se estabelece entre arte e política num momento histórico que, de um lado, aponta para a crise do capitalismo e, de outro, para a fragmentação política da classe trabalhadora. A partir da análise formal de dois de seus filmes, estabelecemos uma relação com os momentos históricos que lhes deram condições de produção, a fim de compreender o método desen...

  18. A highly selective fluorescent probe based on Michael addition for fast detection of hydrogen sulfide

    Science.gov (United States)

    Gao, Baozhen; Cui, Lixia; Pan, Yong; Xue, Minjie; Zhu, Boyu; Zhang, Guomei; Zhang, Caihong; Shuang, Shaomin; Dong, Chuan

    2017-02-01

    A new 4-hydroxy-1,8-naphthalimide-based compound (probe 1) has been designed and synthesized. The colorimetric and fluorescent properties of probe 1 towards hydrogen sulfide (H2S) were investigated in detail. The results show that the probe 1 could selectively and sensitively recognize H2S rather than other reactive sulfur species. The reaction mechanism of this probe is an intramolecular cyclization caused by the Michael addition of H2S to give 4-hydroxy-1,8-naphthalimide. The intramolecular charge transfer of 4-hydroxy-1,8-naphthalimide is significant. Probe 1 quickly responded to H2S and showed a 75-fold fluorescence enhancement in 5 min. Moreover, probe 1 could detect H2S quantitatively with a detection limit as low as 0.23 μM.

  19. Michael Kwass, Contraband: Louis Mandrin and the Making of a Global Underground.

    OpenAIRE

    Goldner, Erik

    2015-01-01

    C’est une plongée dans les « profondeurs de l’économie souterraine » destinée à éclairer « le côté obscur de la mondialisation » que propose Michael Kwass (p. 9). Dès l’introduction, l’auteur reproche à Daniel Roche et aux historiens français qui l’ont suivi de donner une vision trop optimiste de la « révolution de la consommation » du XVIIIe siècle considérée comme un moteur d’émancipation individuelle et de démocratisation sociale d’objets, de pratiques et d’idées. Selon lui, cette vision p...

  20. Inverting the diastereoselectivity of the mukaiyama-michael addition with graphite-based catalysts

    KAUST Repository

    Acocella, Maria Rosaria

    2014-02-07

    Here, we show that graphite-based catalysts, mainly graphite oxide (GO) and exfoliated GO, are effective recyclable catalysts for a relevant stereoselective Mukaiyama-Michael addition, outperforming currently available catalysts. Moreover, the graphite-based catalysts described here invert the diastereoselectivity relative to that observed with known catalysts, with the unprecedented large prevalence of the anti diastereoisomer. This inverted diastereoselectivity is increased when the catalyst concentration is reduced and after catalyst recycling. Density functional theory calculations suggest that the selectivity is determined by two types of supramolecular interactions operating between the catalyst and the substrates at the diastereoselectivity- determining transition state, specifically, the π-stacking of b-nitrostyrene with graphite and the van der Waals interaction between the SiMe3 group of the silyl ether and the graphite. © 2013 American Chemical Society.