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Sample records for refinery wastewaters aplicacao

  1. Application of an aerobic fixed bed bioreactor for treatment of petroleum refinery wastewaters; Aplicacao de um bio-reator aerobio de leito fixo para tratamento de efluentes do refino de petroleo

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    Vendramel, Simone M.; Dezzotti, Marcia; Sant' Anna Junior, Geraldo L. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Programa de Engenharia Quimica

    2004-07-01

    The motivation of this work was to investigate a biological treatment system, which requires low installation area and presents high flexibility. Thus, a laboratory scale aerated submerged fixed-film bioreactor was applied to the treatment of a petroleum refinery wastewater and its performance was monitored. The reactor was continuously operated during 260 days and submitted to different organic loadings in the range of 0.5 to 2.4 kgCOD.m{sup -3}.d{sup -1}. The following removal efficiencies were attained: COD (75 - 91%), TSS and TVS (60 - 92%) and DOC (56 - 91%) and turbidity (71 - 95%). The reactor presented a high level of mixing and showed to be stable when submitted to different hydraulic and organic loadings. Loss of biofilm was negligible and medium clogging problems were not observed. The support medium (PVC plates) showed to be very adequate for microbial adhesion and growth, resulting in stable bioreactor operation. (author)

  2. Treatment of Tehran refinery wastewater using rotating biological contactor

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    Ghazi, Masoud; Mirsajadi, Hassan; Ganjidoust, Hossien [Tarbeyat Modarres Univ., Teheran (Iran, Islamic Republic of). Environmental Engineering Dept.

    1993-12-31

    Tehran Refinery is a large plant which produces several petroleum products. The wastewaters are generated from several different refinery processes and units. Because of the wastewaters uniqueness they need to be treated in each specific plant. Currently, an activated sludge system is the main biological wastewater treatment process in Tehran refinery plant. A study was initiated in order to find a more suitable and reliable process which can produce a better treated effluent which might, in case the process be successful, be reused for irrigation lands. 5 refs., 5 figs.

  3. Evaluation of treatment efficiency of processes for petroleum refinery`s wastewater

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    Kee, Kean Chin [National Univ. of Singapore, Kent Ridge (Singapore). Dept. of Civil Engineering

    1993-12-31

    Processes used in the treatment of a petroleum refinery wastewater included initial API oil separator to be followed by dissolved air flotation and extended aeration system. The use of extended aeration biological system proved to be an improvement but not a solution yet in such kind of treatment. 2 refs., 2 tabs.

  4. Advanced purification of petroleum refinery wastewater by catalytic vacuum distillation.

    Science.gov (United States)

    Yan, Long; Ma, Hongzhu; Wang, Bo; Mao, Wei; Chen, Yashao

    2010-06-15

    In our work, a new process, catalytic vacuum distillation (CVD) was utilized for purification of petroleum refinery wastewater that was characteristic of high chemical oxygen demand (COD) and salinity. Moreover, various common promoters, like FeCl(3), kaolin, H(2)SO(4) and NaOH were investigated to improve the purification efficiency of CVD. Here, the purification efficiency was estimated by COD testing, electrolytic conductivity, UV-vis spectrum, gas chromatography-mass spectrometry (GC-MS) and pH value. The results showed that NaOH promoted CVD displayed higher efficiency in purification of refinery wastewater than other systems, where the pellucid effluents with low salinity and high COD removal efficiency (99%) were obtained after treatment, and the corresponding pH values of effluents varied from 7 to 9. Furthermore, environment estimation was also tested and the results showed that the effluent had no influence on plant growth. Thus, based on satisfied removal efficiency of COD and salinity achieved simultaneously, NaOH promoted CVD process is an effective approach to purify petroleum refinery wastewater. Copyright 2010 Elsevier B.V. All rights reserved.

  5. Photocatalysis as a tertiary treatment for petroleum refinery wastewaters

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    F. V. Santos

    2006-12-01

    Full Text Available Photocatalysis has been used as tertiary treatment for petroleum refinery wastewaters to comply with the regulatory discharge limits and to oxidize persistent compounds that had not been oxidized in the biological treatment. The wastewater is generated by the refinery and directly discharged into the Guanabara Bay (Rio de Janeiro. Although BOD removal is high, a residual and persistent COD, besides a somewhat high phenol content remains. Three photocatalysts were tested - TiO2 (Aldrich, ZnO (Aldrich, and TiO2 (P25, Degussa - the third being the most active. The optimized conditions obtained with an experimental design were 3.0 g L-1 TiO2 and pH 6.3. The use of hydrogen peroxide (H2O2 showed no beneficial effect. Removal of 93% of phenols, 63% of dissolved organic carbon (DOC, and more than 50% of oil and grease (OG were achieved in the photocatalytic process, improving the quality of the treated wastewater.

  6. In vitro analysis of the phytotoxic and genotoxic potential of Aligarh wastewater and Mathura refinery wastewater

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    Naveed Ahmad Fazili

    2014-01-01

    Full Text Available Present report deals with the phytotoxicity and genotoxicity of Mathura refinery wastewater and Aligarh wastewater of Northern India. The IC50 value in Allium cepa root growth inhibition test was recorded to be 0.14X and 0.10X for Mathura refinery and Aligarh industrial wastewaters, respectively. Significant decline in the survival of various Escherichia coli K12 DNA repair defective mutants was observed when the tester strains were exposed to the aforementioned samples. The order of sensitivity was invariably as: AB1157 (wild type < AB2494 (lexA mutant < AB2463 (recA mutant < AB2480 (uvrA recA double mutant. These results suggested a significant amount of DNA damage within the bacterial cells exposed to test wastewaters. A. cepa genotoxicity test also demonstrated a considerable amount of chromosomal damage of A. cepa brought about by the test samples. The aberration index (A.I. for Aligarh wastewater and refinery wastewater was recorded to be 11.2% and 14.7%, respectively, whereas the aquaguard mineral water serving as negative control displayed the A.I. value to be 2.6%. Interestingly, genotoxicity of both industrial wastewaters was reduced to a remarkable extent in presence of mannitol, the hydroxyl radical scavenger. Present study clearly indicated a distinct pattern of the chromosomal aberrations showing predominantly stickiness and stray chromosomes in case of AWW while clumping and stickiness in case of RWW, thereby affirming the genotoxicity of both test waters.

  7. Treatability studies on different refinery wastewater samples using high-throughput microbial electrolysis cells (MECs)

    KAUST Repository

    Ren, Lijiao

    2013-05-01

    High-throughput microbial electrolysis cells (MECs) were used to perform treatability studies on many different refinery wastewater samples all having appreciably different characteristics, which resulted in large differences in current generation. A de-oiled refinery wastewater sample from one site (DOW1) produced the best results, with 2.1±0.2A/m2 (maximum current density), 79% chemical oxygen demand removal, and 82% headspace biological oxygen demand removal. These results were similar to those obtained using domestic wastewater. Two other de-oiled refinery wastewater samples also showed good performance, with a de-oiled oily sewer sample producing less current. A stabilization lagoon sample and a stripped sour wastewater sample failed to produce appreciable current. Electricity production, organics removal, and startup time were improved when the anode was first acclimated to domestic wastewater. These results show mini-MECs are an effective method for evaluating treatability of different wastewaters. © 2013 Elsevier Ltd.

  8. Purification and detoxification of petroleum refinery wastewater by electrocoagulation process.

    Science.gov (United States)

    Gousmi, N; Sahmi, A; Li, H Z; Poncin, S; Djebbar, R; Bensadok, K

    2016-09-01

    The treatment of synthetic oily wastewater having the characteristics of a typical petroleum refinery wastewater (PRW) by electrocoagulation (EC) using iron and aluminum electrodes was conducted in an electrolytic reactor equipped with fluid recirculation. During the treatment, the emulsion stability was followed by the measurement of Zeta potential and particle sizes. Effects of some operating conditions such as electrodes material, current density and electrolysis time on removal efficiencies of turbidity, and chemical oxygen demand (COD) were investigated in detail. The PRW purification by the EC process was found to be the most effective using aluminum as the anode and cathode, current density of 60 A/m(2) and 30 min of electrolysis time. Under these conditions, the process efficiencies were 83.52% and 99.94%, respectively, for COD and turbidity removals which correspond to final values of 96 mg O2/L and 0.5 NTU. A moderate energy consumption (0.341 kWh) was needed to treat 1 m(3) of PRW. Besides, the ecotoxicity test proved that toxic substances presented in the PRW, and those inhibiting the germination growth of whet, were eliminated by the EC technique.

  9. MBBR evaluation for oil refinery wastewater treatment, with post-ozonation and BAC, for wastewater reuse.

    Science.gov (United States)

    Schneider, E E; Cerqueira, A C F P; Dezotti, M

    2011-01-01

    This work evaluated the performance of a Moving Bed Biofilm Reactor (MBBR) in the treatment of an oil refinery wastewater. Also, it investigated the possibility of reuse of the MBBR effluent, after ozonation in series with a biological activated carbon (BAC) column. The best performance of the MBBR was achieved with a hydraulic retention time (HRT) of 6 hours, employing a bed to bioreactor volume ratio (V(B)/V(R)) of 0.6. COD and N-NH₄(+) MBBR effluent concentrations ranged from 40 to 75 mg L⁻¹ (removal efficiency of 69-89%) and 2 to 6 mg L⁻¹ (removal efficiency of 45-86%), respectively. Ozonation carried out for 15 min with an ozone concentration of 5 mg L⁻¹ was able to improve the treated wastewater biodegradability. The treatment performance of the BAC columns was practically the same for ozonated and non ozonated MBBR effluents. The dissolved organic carbon (DOC) content of the columns of the activated carbon columns (CAG) was in the range of 2.1-3.8 mg L⁻¹, and the corresponding DOC removal efficiencies were comprised between 52 and 75%. The effluent obtained at the end of the proposed treatment presented a quality, which meet the requirements for water reuse in the oil refinery.

  10. Treatment of oil refinery wastewater using crude Coprinus cinereus peroxidase and hydrogen peroxide

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    Ikehata, K.; Buchanan, I. D.; Smith, D. W. [University of Alberta, Dept. of Civil and Environmental Engineering, Edmonton, AB (Canada)

    2003-11-01

    Enzymatic treatment of oil refinery wastewater was investigated using crude peroxidase derived from the fungus Coprinus cinereus (CIP), and hydrogen peroxide. Further objectives were to investigate the effects of residual organic compounds in the crude enzyme, and compare the performance of CIP to those of purified horseradish peroxidase (HRP) and Arthromyces ramosus peroxidase (ARP) in the treatment of a strong refinery wastewater. Phenols in the wastewater were converted to coloured polymeric products and then removed by coagulation with alum. As a result of the enzymatic treatment and alum coagulation of the wastewater containing 6.4 mM total phenol, the chemical oxygen demand and the 5-d biochemical oxygen demand were reduced by 52 per cent and 58 per cent, respectively. Reduction of the oxygen demands notwithstanding, the dissolved organic materials in the crude CIP were not affected by either of these processes and tended to remain in the treated wastewater. 31 refs., 1 tab., 7 figs.

  11. Development of optimum conditions for modification of Kpautagi clay for application in petroleum refinery wastewater treatment

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    Matthew A. ONU

    2015-12-01

    Full Text Available Kautagi clay is a kaolin type deposit that is abundantly available in Niger State, Nigeria with potential for application in pollution control such as wastewater treatment. This study investigates the optimum conditions for modification of Kpautagi clay for application in refinery wastewater treatment. Sulphuric acid was used in the modification of the clay and the modification variables considered were acid concentration, activation time and temperature. To develop the optimum conditions for the modification variables, the sulphuric acid modified Kpautagi clay was applied in the treatment of refinery wastewater in column mode at a fixed flow rate and mass of adsorbent. The results obtained indicate that the optimum conditions for modification of Kpautagi clay for application in the treatment of petroleum refinery wastewater are: acid concentration of 4M; activation time of 120min and activation temperature of 100°C. Therefore, the optimum conditions developed in this study for modification of Kpautagi clay could be applied for improved performance in the treatment of petroleum refinery wastewater.

  12. Determination of the priority indexes for the oil refinery wastewater treatment process

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    Chesnokova, M. G.; Myshlyavtsev, A. V.; Kriga, A. S.; Shaporenko, A. P.; Markelov, V. V.

    2017-08-01

    The wastewater biological treatment intensity and effectiveness are influenced by many factors: temperature, pH, presence and concentration of toxic substances, the biomass concentration et al. Regulation of them allows controlling the biological treatment process. Using the Bayesian theorem the link between changes was determined and the wastewater indexes normative limits exceeding influence for activated sludge characteristics alteration probability was evaluated. The estimation of total, or aposterioric, priority index presence probability, which characterizes the wastewater treatment level, is an important way to use the Bayesian theorem in activated sludge swelling prediction at the oil refinery biological treatment unit.

  13. Electricity Generation and Wastewater Treatment of Oil Refinery in Microbial Fuel Cells Using Pseudomonas putida

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    Dip Majumder

    2014-09-01

    Full Text Available Microbial fuel cells (MFCs represent a novel platform for treating wastewater and at the same time generating electricity. Using Pseudomonas putida (BCRC 1059, a wild-type bacterium, we demonstrated that the refinery wastewater could be treated and also generate electric current in an air-cathode chamber over four-batch cycles for 63 cumulative days. Our study indicated that the oil refinery wastewater containing 2213 mg/L (ppm chemical oxygen demand (COD could be used as a substrate for electricity generation in the reactor of the MFC. A maximum voltage of 355 mV was obtained with the highest power density of 0.005 mW/cm2 in the third cycle with a maximum current density of 0.015 mA/cm2 in regard to the external resistor of 1000 Ω. A maximum coulombic efficiency of 6 × 10−2% was obtained in the fourth cycle. The removal efficiency of the COD reached 30% as a function of time. Electron transfer mechanism was studied using cyclic voltammetry, which indicated the presence of a soluble electron shuttle in the reactor. Our study demonstrated that oil refinery wastewater could be used as a substrate for electricity generation.

  14. Electricity generation and wastewater treatment of oil refinery in microbial fuel cells using Pseudomonas putida.

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    Majumder, Dip; Maity, Jyoti Prakash; Tseng, Min-Jen; Nimje, Vanita Roshan; Chen, Hau-Ren; Chen, Chien-Cheng; Chang, Young-Fo; Yang, Tsui-Chu; Chen, Chen-Yen

    2014-09-22

    Microbial fuel cells (MFCs) represent a novel platform for treating wastewater and at the same time generating electricity. Using Pseudomonas putida (BCRC 1059), a wild-type bacterium, we demonstrated that the refinery wastewater could be treated and also generate electric current in an air-cathode chamber over four-batch cycles for 63 cumulative days. Our study indicated that the oil refinery wastewater containing 2213 mg/L (ppm) chemical oxygen demand (COD) could be used as a substrate for electricity generation in the reactor of the MFC. A maximum voltage of 355 mV was obtained with the highest power density of 0.005 mW/cm² in the third cycle with a maximum current density of 0.015 mA/cm² in regard to the external resistor of 1000 Ω. A maximum coulombic efficiency of 6 × 10⁻²% was obtained in the fourth cycle. The removal efficiency of the COD reached 30% as a function of time. Electron transfer mechanism was studied using cyclic voltammetry, which indicated the presence of a soluble electron shuttle in the reactor. Our study demonstrated that oil refinery wastewater could be used as a substrate for electricity generation.

  15. Pretreatment of super viscous oil wastewater and its application in refinery

    Institute of Scientific and Technical Information of China (English)

    Chen Chunmao; Yan Guangxu; Guo Shaohui; Yang Yong

    2008-01-01

    Wastewater from super viscous oil processing cannot be effectively treated by conventional wastewater treatment plants in refineries because of its high concentration of various organic pollutants.In order to resolve this problem,a number of investigations were conducted in our work to understand the physicochemical properties,sedimentation,demulsification and pretreatment of such super viscous oil refinery wastewater.The results showed that the key issues for pretreatment of this wastewater were:(1)Optimized process parameters were used in the sedimentation and demulsification processes for oil removal to effectively recover oil and remove scum from wastewater;(2)A suitable flocculation process was selected to minimize oil,suspended solids(SS)and chemical oxygen demand(CODcr).A pretreatment process including three continuous steps:oil removal by sedimentation,oil removal by demulsification,and flotation separation,was proposed and applied in Liaohe Petrochemical Company,PetroChina and the oil content in effluents was Iess than 200 mg/L and CODcr less than 2,500 mg/L,which completely met the requirement for influent of the conventional wastewater treatment plant,and the recovered super viscous oil reached 5,873 tons in the initial year in Liaohe Petrochemical Company,PetroChina.

  16. Phenol removal from refinery wastewater by mutant recombinant horseradish peroxidase.

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    Asad, Sedigheh; Dabirmanesh, Bahareh; Khajeh, Khosro

    2014-01-01

    Application of mutated recombinant horseradish peroxidase (HRP) for phenol removal from refinery effluents is reported. Recombinant HRP produced in Escherichia coli suffers from the disadvantage of lacking glycosylation, which affects its catalytic efficiency and stability toward inactivating parameters such as increased temperature and enhanced amounts of hydrogen peroxide. In the present study, the previously reported variant (in which Asn268 was substituted with Asp, N268D) with improved stability characteristics and catalytic efficiency was used to remove phenol from a petroleum refinery effluent. The presence and removal of phenol was studied by high-performance liquid chromatography; the precipitated oxidized phenol was also observed and removed from the sample by centrifugation. Results showed that the N268D variant can remove 61%, 67%, and 81% of phenol from effluent in 1, 2, and 16 H, respectively. By exploiting the N268D mutant, removal of 50% phenol could be achieved in 42 Min, which was more than 22 times less than the treatment time required by native recombinant enzyme.

  17. Bioremediation of refinery wastewater using immobilised Burkholderia cepacia and Corynebacterium sp and their transconjugants

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    Abdullahi T. Ajao

    2013-07-01

    Full Text Available When oil spill occurs, it poses serious toxic hazards to all forms of life. Mixed culture of Burkholderia cepacia and Corynebacterium sp isolated from refinery sludge using selective enrichment technique was used for bioremediation of refinery wastewater in a laboratoryscale bioreactor. Physicochemical parameters of both raw and treated water were as determined and compared with Federal Environ - mental Protection Agency (FEPA-limit, Abuja, Nigeria to asses the efficiency of the bioremediation process. Each of the bacterium was screened for the presence of plasmid DNA and for the involvement or otherwise of plasmid in the bioremediation of wastewater. The immobilised cells showed percentage decrease in chemical oxygen demand (97%, biochemical oxygen demand (94%, phenol (98%, total petroleum hydrocarbon (79%, oil and grease (90% of the refinery waste water after 20 days of treatment while their transconjugants showed the multiplicative effect by achieving the same percentage after 10 days of treatment. Therefore, the findings revealed that bioaugmentation of wastewater using transmissible catabolic plasmid will enhance efficiency of the bioremediation by spreading the plasmid among indigenous microbial community either through horizontal gene transfer or transformation.

  18. The Efficiency of Anaerobic Wastewater Stabilization Pond in Removing Phenol from Kermanshah Oil Refinery Wastewater

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    Ali Almasi

    2012-04-01

    Full Text Available Normal 0 false false false EN-US X-NONE AR-SA MicrosoftInternetExplorer4 Background and Objectives: Phenol is one of the aromatic compounds, which due to its high toxicity and its presence in the industrial effluents, should be removed and prevented it, to the receiving water resources. The natural biological plant has been accepted as one of the most feasible, eco-friendly and cost-effective options for the treatment of pollutants such as Phenol. The aim of this study is efficiency evaluation of the anaerobic stabilization pond performance in removing phenol and other organic compounds from Kermanshah oil refinery wastewater. Materials and Methods: The method of study was experimental and analytical, a laboratory scale anaerobic stabilization pond, with dimensions of 1 × 1 × 0/2 m, using fiberglass sheet with a thickness of 6 mm was designed and built up. In this study The hydraulic retention time and hydraulic loading rate were expected 2 days and 95 liters per day respectively. Organic loading rate for anaerobic pond was 100 g/m3. After starting, seeding and biological stability, samples were taken. Initial phenol concentration was added about of 100 mg/l to pilot input, then the parameters such as NH3, PO4 and Phenol were measured by Varian spectrophotometer model UV-120-02 in the wavelength 425, 690, 500 nm respectively.  TCOD, SCOD, TBOD, SBOD, pH and ORP were measured according to the standard methods of water and wastewater. Results: The results showed that the removal efficiency of NH3, PO4, phenol, TCOD, SCOD, TBOD, SBOD in the anaerobic pond were obtained 91.51%, 64.34%, 89.82% 74.99 % 73.34% 71.75%, 68.9% respectively. Conclusion: The results showed that the ability for phenol and other organic compounds removal in anaerobic pond using petroleum refinery wastewater is higher than the other systems which are expensive and complex. st1":*{behavior:url(#ieooui } /* Style Definitions */ table.MsoNormalTable {mso

  19. Treatment of Slightly Polluted Wastewater in an Oil Refinery Using a Biological Aerated Filter Process

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    XIE Wenyu; ZHONG Li; CHEN Jianjun

    2007-01-01

    The slightly polluted wastewater from oil refinery contains some COD, oil pollutants and suspended solids (SS). A small-scale fixed film biological aerated filter (BAF) process was used to treat the wastewater. The influences of hydraulic retention time (HRT), air/water volume flow ratio and backwashing cycle on treatment efficiencies were investigated. The wastewater was treated by the BAF process under optimal conditions: the HRT of backwashing cycle of every 4-7 days. The results showed that the average removal efficiency of COD, oil pollutants and SS was 84.5%, 94.0% and 83.4%, respectively. And the average effluent concentration of COD, oil pollutants and SS was 12.5, 0.27, 14.5the BAF process is a suitable and highly efficient method to treat the wastewater.

  20. Separation and Molecular Identification of Resistant Bacteria to Lead from Behbahan Bidboland Gas Refinery Wastewater (Iran

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    Azam Mehrbakhsh

    2016-01-01

    Full Text Available Heavy metals are one of the pollution sources in environment. The pollution due to these metals is the problem that could have negative impact on water. Human is faced with these poisons effects due to occupational reasons. The lead is regarded as heavy metal whose industrial applications cause environmental pollution in high rate.The aim of this project was Separation and Molecular Identification of Resistant Bacteria to Lead from Behbahan Bidboland Gas Refinery Wastewater (Iran. For this aim, 6 samples of water and refinery output wastewater is provided after sampling, pH, COD, BOD rates and lead metal primary concentration was determined in wastewaters, after this phase the concentration and separation of resistant bacteria was done to separate them from lead. In this phase the minimum inhibitory concentration was defined from heavy metal growth (MIC. To determine the bacteria identity first the evaluation method of bacteria morphologic and gram staining and then biochemical tests and finally colony-–PCR molecular method was used and then separated bacteria 16S rRNA gen was identified. The obtained results from this research showed that among the separated bacteria from Behbahan Bidboland gas refinery wastewater, the Providencia genous had the most resistant toward Pb. The MIC rate for this bacteria was calculated at 1140 mg/l. the result of this study showed that separated bacteria in this wastewater seemed to have high resistant toward heavy metals due to long encountering to pollution sources and hence they could be proper factor for bioremediation process of heavy metals

  1. Modeling of biobasins of an oil refinery wastewater treatment plant

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    RADOSTIN K. KUTSAROV

    2015-04-01

    Full Text Available The biobasins of the largest wastewater treatment plant (WWTP on the Balkans has been examined. Samples were taken four times from the inlet and outlet flow. The concentration of the total hydrocarbons, benzene, toluene, ethylbenzene, p-xylene, m-xylene, o-xylene and styrene in the wastewater has been obtained by gas chromatography. The average experimental concentrations were used when the mass balance was made. The results indicate that about 60% of pollutants are emitted in the air, about 22% are assimilated through biodegradation, and nearly 18% leave WWTP with the purified water. The measured concentrations were also modeled by Water 9.3 program. Comparison between the measured amounts of pollution concentrations and those forecasted by the Water 9.3 program has been made.

  2. ENHANCEMENT OF PHENOL REMOVAL EFFICIENCY IN DORA REFINERY WASTEWATER TREATMENT PLANT

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    Salah F. Sharif

    2013-05-01

    Full Text Available   Because the sanctions imposed on Iraq by the United Nations, programmed maintenance and wearing parts replacement has not been performed according to schedules in DORA Refinery Wastewater Unit, which resulted in higher phenol content and BOD5 in effluents disposed to river. The investigations showed that two main reasons were behind this problem: Firstly, increased emissions of hydrocarbons in the complexity of refinery equipment and Secondly, the decreased efficiency of the aerators in the biological. During the last few months, phenol average concentration in the effluent, after biological treatment was found to be between 0.06-0.13 mg/L, while COD was exceeding 110 mg/L after treatment in the same period. Considerable enhancement, has been indicated recently, after the following performances: First: Recycling wastewater from some heat exchangers, and the segregation of low and high strength of wastewaters, Second: Minimizing emissions of hydrocarbons from fluid catalytic cracking and steam cracking, Third: Replacement of driving motors of the aerators in the biological treatment unit. After replacement of these units, a significant decrease in phenol concentration was obtained in purified water (0.03-0.05 mg/L and COD of 60 mg/L before the tertiary treatment. It is concluded that a better quality of effluents has been obtained after a series of emissions control and wastewater treatment unit equipment maintenance performances.

  3. Pilot scale thin film plate reactors for the photocatalytic treatment of sugar refinery wastewater.

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    Saran, S; Kamalraj, G; Arunkumar, P; Devipriya, S P

    2016-09-01

    Pilot scale thin film plate reactors (TFPR) were fabricated to study the solar photocatalytic treatment of wastewater obtained from the secondary treatment plant of a sugar refinery. Silver-impregnated titanium dioxide (TiO2) was prepared by a facile chemical reduction method, characterized, and immobilized onto the surface of ceramic tiles used in the pilot scale reactors. On 8 h of solar irradiation, percentage reduction of chemical oxygen demand (COD) of the wastewater by Ag/TiO2, pure TiO2, and control (without catalyst) TFPR was about 95, 86, and 22 % respectively. The effects of operational parameters such as, flow rate, pH, and addition of hydrogen peroxide (H2O2) were optimized as they influence the rate of COD reduction. Under 3 h of solar irradiation, 99 % COD reduction was observed at an optimum flow rate of 15 L h(-1), initial pH of 2, and addition of 5 mM of H2O2. The results show that Ag/TiO2 TFPR could be effectively used for the tertiary treatment of sugar refinery effluent using sunlight as the energy source. The treated water could be reused for industrial purposes, thus reducing the water footprint of the industry. Graphical Abstract Sugar refinery effluent treatment by solar photocatalytic TFPR.

  4. Study on Application of Novel Flocculating Agent in Treating Refinery Wastewater with High Concentration of Pollutants

    Institute of Scientific and Technical Information of China (English)

    Zhang Baoji; Qin Bing

    2009-01-01

    After conducting a lot of screening experiments the appropriate flocculating formulations for treating high-con-centration wastewater discharged fi'om a certain refinery were selected. The oil removal rate and COD removal achieved by these flocculating formulations were better than that achieved by the conventional compound formulation consisting of polyaluminium chloride (PAC) and polyactylamide (PAA). Addition of an oil/water separating agent to the formulation could improve its oil removal performance to facilitate the oil/water separation of the oil-in-water emulsion in the high-concentra-tion wastewater along with improved adaptability of the formulation to the wastewater containing high concentration of pollutants. This flocculating agent has promising prospects for commercial application.

  5. Optimization of Anaerobic Treatment of Petroleum Refinery Wastewater Using Artificial Neural Networks

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    H.A. Gasim

    2013-07-01

    Full Text Available Treatment of petroleum refinery wastewater using anaerobic treatment has many advantages over other biological method particularly when used to treat complex wastewater. In this study, accumulated data of Up-flow Anaerobic Sludge Blanket (UASB reactor treating petroleum refinery wastewater under six different volumetric organic loads (0.58, 1.21, 0.89, 2.34, 1.47 and 4.14 kg COD/m3.d, respectively were used for developing mathematical model that could simulate the process pattern. The data consist of 160 entries and were gathered over approximately 180 days from two UASB reactors that were continuously operating in parallel. Artificial neural network software was used to model the reactor behavior during different loads applied. Two transfer functions were compared and different number of neurons was tested to find the optimum model that predicts the reactor pattern. The tangent sigmoid transfer function (tansig at hidden layer and a linear transfer function (purelin at output layer with 12 neurons were selected as the optimum best model.

  6. Achieving very low mercury levels in refinery wastewater by membrane filtration.

    Energy Technology Data Exchange (ETDEWEB)

    Urgun Demirtas, M.; Benda, P.; Gillenwater, P. S.; Negri, M. C.; Xiong, H.; Snyder, S. W. (Center for Nanoscale Materials); ( ES)

    2012-05-15

    Microfiltration (MF), ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) membranes were evaluated for their ability to achieve the world's most stringent Hg discharge criterion (<1.3 ng/L) in an oil refinery's wastewater. The membrane processes were operated at three different pressures to demonstrate the potential for each membrane technology to achieve the targeted effluent mercury concentrations. The presence of mercury in the particulate form in the refinery wastewater makes the use of MF and UF membrane technologies more attractive in achieving very low mercury levels in the treated wastewater. Both NF and RO were also able to meet the target mercury concentration at lower operating pressures (20.7 bar). However, higher operating pressures ({ge}34.5 bar) had a significant effect on NF and RO flux and fouling rates, as well as on permeate quality. SEM images of the membranes showed that pore blockage and narrowing were the dominant fouling mechanisms for the MF membrane while surface coverage was the dominant fouling mechanism for the other membranes. The correlation between mercury concentration and particle size distribution was also investigated to understand mercury removal mechanisms by membrane filtration. The mean particle diameter decreased with filtration from 1.1 {+-} 0.0 {micro}m to 0.74 {+-} 0.2 {micro}m after UF.

  7. Study on Immobilized Algal Cells for Treatment and Recycle of Refinery Wastewater

    Institute of Scientific and Technical Information of China (English)

    Yu Baocheng; Liu Deqi; Dong Lihua; Li Gang

    2005-01-01

    Compared to the algal oxidation pond, treatment of wastewater using the immobilized algal cell technology has excellent effect, which not only can effectively avoid the disadvantage of oxidation pond,but can also remarkably improve the efficiency of treating system and the effluent quality. When the treating system operates under an optimal control conditions, such as a 55% loading rate, an illumination intensity of 2500-3500 lux and a hydraulic residence time of 4 hours, the COD and ammonia nitrogen removal can reach 90%. Water after deep treatment can comply with the requirement of the refinery for the quality of recycled water.

  8. WATER PINCH TECHNOLOGY APPLICATION TO MINIMIZE SULPHUROUS WASTEWATER IN AN OIL REFINERY

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    Gabriel Orlando Lobelles Sardiñas

    2017-01-01

    Full Text Available In oil refining industries there is a high water consumption, which influences the high production costs and impacts the environment due to the discharge of their wastes. It is known that there are no technological conditions for the reuse of industrial water at the oil refineries, based on hydroskimming processes. The objective of this study is to implement the process integration methodology, Water Pinch, to a sour water stripper unit, as a unitary process of an oil refinery, to minimize the amount of sulphurous waste water and reduce contamination of the bay that receives these wastes. The technology is applied to evaluate the volume of sulphurous wastewater generated in the Cienfuegos oil refinery. This technology allows identifying opportunities for recovery and reuse of water, based on concentration ranges of contaminants. To achieve this purpose, a sour water stripper tower was assessed with the help of Water Pinch software, which provided an optimized distribution network, as a proposed technological improvement. This facilitated to recover and reuse 667 757, 28 m3 of water per year, and 1 035 023, 78 CUC were saved, at the same time the amount of polluting effluents decreased in approximately 2 % of non-reusable treated water.

  9. Identification of genes and pathways related to phenol degradation in metagenomic libraries from petroleum refinery wastewater.

    Directory of Open Access Journals (Sweden)

    Cynthia C Silva

    Full Text Available Two fosmid libraries, totaling 13,200 clones, were obtained from bioreactor sludge of petroleum refinery wastewater treatment system. The library screening based on PCR and biological activity assays revealed more than 400 positive clones for phenol degradation. From these, 100 clones were randomly selected for pyrosequencing in order to evaluate the genetic potential of the microorganisms present in wastewater treatment plant for biodegradation, focusing mainly on novel genes and pathways of phenol and aromatic compound degradation. The sequence analysis of selected clones yielded 129,635 reads at an estimated 17-fold coverage. The phylogenetic analysis showed Burkholderiales and Rhodocyclales as the most abundant orders among the selected fosmid clones. The MG-RAST analysis revealed a broad metabolic profile with important functions for wastewater treatment, including metabolism of aromatic compounds, nitrogen, sulphur and phosphorus. The predicted 2,276 proteins included phenol hydroxylases and cathecol 2,3- dioxygenases, involved in the catabolism of aromatic compounds, such as phenol, byphenol, benzoate and phenylpropanoid. The sequencing of one fosmid insert of 33 kb unraveled the gene that permitted the host, Escherichia coli EPI300, to grow in the presence of aromatic compounds. Additionally, the comparison of the whole fosmid sequence against bacterial genomes deposited in GenBank showed that about 90% of sequence showed no identity to known sequences of Proteobacteria deposited in the NCBI database. This study surveyed the functional potential of fosmid clones for aromatic compound degradation and contributed to our knowledge of the biodegradative capacity and pathways of microbial assemblages present in refinery wastewater treatment system.

  10. Identification of genes and pathways related to phenol degradation in metagenomic libraries from petroleum refinery wastewater.

    Science.gov (United States)

    Silva, Cynthia C; Hayden, Helen; Sawbridge, Tim; Mele, Pauline; De Paula, Sérgio O; Silva, Lívia C F; Vidigal, Pedro M P; Vicentini, Renato; Sousa, Maíra P; Torres, Ana Paula R; Santiago, Vânia M J; Oliveira, Valéria M

    2013-01-01

    Two fosmid libraries, totaling 13,200 clones, were obtained from bioreactor sludge of petroleum refinery wastewater treatment system. The library screening based on PCR and biological activity assays revealed more than 400 positive clones for phenol degradation. From these, 100 clones were randomly selected for pyrosequencing in order to evaluate the genetic potential of the microorganisms present in wastewater treatment plant for biodegradation, focusing mainly on novel genes and pathways of phenol and aromatic compound degradation. The sequence analysis of selected clones yielded 129,635 reads at an estimated 17-fold coverage. The phylogenetic analysis showed Burkholderiales and Rhodocyclales as the most abundant orders among the selected fosmid clones. The MG-RAST analysis revealed a broad metabolic profile with important functions for wastewater treatment, including metabolism of aromatic compounds, nitrogen, sulphur and phosphorus. The predicted 2,276 proteins included phenol hydroxylases and cathecol 2,3- dioxygenases, involved in the catabolism of aromatic compounds, such as phenol, byphenol, benzoate and phenylpropanoid. The sequencing of one fosmid insert of 33 kb unraveled the gene that permitted the host, Escherichia coli EPI300, to grow in the presence of aromatic compounds. Additionally, the comparison of the whole fosmid sequence against bacterial genomes deposited in GenBank showed that about 90% of sequence showed no identity to known sequences of Proteobacteria deposited in the NCBI database. This study surveyed the functional potential of fosmid clones for aromatic compound degradation and contributed to our knowledge of the biodegradative capacity and pathways of microbial assemblages present in refinery wastewater treatment system.

  11. Oil refinery wastewater treatment using coupled electrocoagulation and fixed film biological processes

    Science.gov (United States)

    Pérez, Laura S.; Rodriguez, Oscar M.; Reyna, Silvia; Sánchez-Salas, José Luis; Lozada, J. Daniel; Quiroz, Marco A.; Bandala, Erick R.

    2016-02-01

    Oil refinery wastewater was treated using a coupled treatment process including electrocoagulation (EC) and a fixed film aerobic bioreactor. Different variables were tested to identify the best conditions using this procedure. After EC, the effluent was treated in an aerobic biofilter. EC was capable to remove over 88% of the overall chemical oxygen demand (COD) in the wastewater under the best working conditions (6.5 V, 0.1 M NaCl, 4 electrodes without initial pH adjustment) with total petroleum hydrocarbon (TPH) removal slightly higher than 80%. Aluminum release from the electrodes to the wastewater was found an important factor for the EC efficiency and closely related with several operational factors. Application of EC allowed to increase the biodegradability of the sample from 0.015, rated as non-biodegradable, up to 0.5 widely considered as biodegradable. The effluent was further treated using an aerobic biofilter inoculated with a bacterial consortium including gram positive and gram negative strains and tested for COD and TPH removal from the EC treated effluent during 30 days. Cell count showed the typical bacteria growth starting at day three and increasing up to a maximum after eight days. After day eight, cell growth showed a plateau which agreed with the highest decrease on contaminant concentration. Final TPHs concentration was found about 600 mgL-1 after 30 days whereas COD concentration after biological treatment was as low as 933 mgL-1. The coupled EC-aerobic biofilter was capable to remove up to 98% of the total TPH amount and over 95% of the COD load in the oil refinery wastewater.

  12. Preliminary characterization of biosurfactants produced by microorganisms isolated from refinery wastewaters.

    Science.gov (United States)

    Yalçin, Emine; Ergene, Aysun

    2010-02-01

    Some bacterial strains isolated from refinery wastewaters were identified as Pseudomonas aeruginosa RWI, Pseudomonas putida RWII, Pseudomonas fluorescens RWIII and Burkholderia cepacia RWIV, and the biosurfactants produced by these strains were coded as BS-I, BS-II, BS-III and BS-IV, respectively. The bacterial strains were characterized by the following biochemical methods: Gram stain, oxidase activity, indol, lactose and growth at 42 degrees C. Biosurfactant production was evaluated by: emulsification activity, surface tension measurement and critical micelle concentration. Chemical characterization of the biosurfactants was done by: FTIR and analysis of carbohydrate, protein and lipid content. The biosurfactants showed good emulsification activity against different hydrocarbon sources. The initial surface tension of culture broth was determined as 67.3 mN/m, and production of BS-I, BS-II, BS-III and BS-IV lowered this value to 35.9, 49.2, 51.6 and 45.7 mN/m, respectively. The critical micelle concentration of the biosurfactants was found to be in the range 10-50 mg/L. From the results of this study it was observed that the refinery wastewaters are a suitable source for isolation of biosurfactant-producing bacteria, but are not a substrate for biosurfactant production.

  13. Phytoremediation of heavy metals (Cd, Pb and V in gas refinery wastewater using common reed (Phragmitis australis

    Directory of Open Access Journals (Sweden)

    Amir Hossein Hamidian

    2014-02-01

    Full Text Available Industrial wastewaters are of the major sources of heavy metal pollution in the environment. In the Middle East, gas and oil industry is the major source of heavy metal pollution and releases significant amounts of metals into the terrestrial and aquatic environment. In this research the capability of the common reed (Phragmitis australis in absorbing heavy metals Cd, Pb and V from the wastewater of a gas refinery plant in Iran was investigated. The plant samples were collected from the vicinity of the Bidboland gas refinery plant in Iran and were used for the treatment of wastewaters collected from the outflow of the refinery plant. The metal concentrations were measured in the roots of the plant species before treatment and after 2, 6 and 10 days of treatment procedure. The heavy metal concentrations were measured after acid digestion and using an ICP-OES instrument. After 10 days of treatment, the concentrations of the metals in plant tissues increased by 2.5, 6.9 and 2.7 times for Cd, Pb and V, respectively. The best treatment time was suggested to be 6 days. The common reed was observed to have a very good capability in removing heavy metals from the gas refinery wastewater.

  14. Bioremediation of wastewater from edible oil refinery factory using oleaginous microalga Desmodesmus sp. S1.

    Science.gov (United States)

    Mar, Cho Cho; Fan, Yong; Li, Fu-Li; Hu, Guang-Rong

    2016-12-01

    Edible oil industry produced massive wastewater, which requires extensive treatment to remove pungent smell, high phosphate, carbon oxygen demand (COD), and metal ions prior to discharge. Traditional anaerobic and aerobic digestion could mainly reduce COD of the wastewater from oil refinery factories (WEORF). In this study, a robust oleaginous microalga Desmodesmus sp. S1 was adapted to grow in WEORF. The biomass and lipid content of Desmodesmus sp. S1 cultivated in the WEORF supplemented with sodium nitrate were 5.62 g·L(-1) and 14.49%, whereas those in the WEORF without adding nitrate were 2.98 g·L(-1) and 21.95%. More than 82% of the COD and 53% of total phosphorous were removed by Desmodesmus sp. S1. In addition, metal ions, including ferric, aluminum, manganese and zinc were also diminished significantly in the WEORF after microalgal growth, and pungent smell vanished as well. In comparison with the cells grown in BG-11 medium, the cilia-like bulges and wrinkles on the cell surface of Desmodesmus sp. S1 grown in WEORF became out of order, and more polyunsaturated fatty acids were detected due to stress derived from the wastewater. The study suggests that growing microalgae in WEORF can be applied for the dual roles of nutrient removal and biofuel feedstock production.

  15. Application of Response Surface Methodology to Enhance Phenol Removal from Refinery Wastewater by Microwave Process

    Directory of Open Access Journals (Sweden)

    Sherif A. Younis

    2014-01-01

    Full Text Available Phenol contaminated petroleum refinery wastewater presents a great threat on water resources safety. This study investigates the effect of microwave irradiation on removal of different concentrations of phenol in an attempt for petroleum refinery wastewater treatment. The obtained results show that the MW output power and irradiation time have a significant positive effect on the removal efficiency of phenol. The kinetic reaction is significantly affected by initial MW output power and initial phenol concentrations. Response surface methodology (RSM was employed to optimize and study the interaction effects of process parameters: MW output power, irradiation time, salinity, pH, and H2O2 concentration using central composite design (CCD. From the CCD design matrix, a quadratic model was considered as an ultimate model (R2 = 0.75 and its adequacy was justified through analysis of variance (ANOVA. The overall reaction rates were significantly enhanced in the combined MW/H2O2 system as proved by RSM. The optimum values for the design parameters of the MW/H2O2 process were evaluated giving predicted phenol removal percentage of 72.90% through RSM by differential approximation and were confirmed by experimental phenol removal of 75.70% in a batch experiment at optimum conditions of 439 W MW power, irradiation time of 24.22 min, salinity of 574 mg/L, pH 5.10, and initial H2O2 concentration of 10% (v/v.

  16. Bioproducts for Sludge Reduction in Activated Sludge Systems Treating Oil Refinery Wastewater

    Directory of Open Access Journals (Sweden)

    Alexandre V.M.F.

    2016-03-01

    Full Text Available The use of bioproducts that change the cellular metabolism and reduce microbial growth without affecting the organic matter removal is very promising for reducing the amount of sludge in wastewater treatment systems. In this study, two bioproducts were evaluated and compared with a well-known chemical (2,4-DiNitroPhenol – DNP in activated sludge treating petroleum refinery wastewater. In batch experiments, 10 mg/L of DNP, 0.8 mg/L of a bioproduct based on Folic Acid (FA and 10 mg/L of a bioproduct based on Stress Proteins (SP led to 30.6%, 43.2% and 29.8% lower disposal of total solids, respectively. Operating on a continuous regimen, the addition of 10 mg/L of the bioproduct based on SP led to 45.7% lower disposal for 50 days. In all cases, no loss of efficiency in the Chemical Oxygen Demand (COD removal was observed.

  17. Treating refinery wastewaters in microbial fuel cells using separator electrode assembly or spaced electrode configurations

    KAUST Repository

    Zhang, Fang

    2014-01-01

    The effectiveness of refinery wastewater (RW) treatment using air-cathode, microbial fuel cells (MFCs) was examined relative to previous tests based on completely anaerobic microbial electrolysis cells (MECs). MFCs were configured with separator electrode assembly (SEA) or spaced electrode (SPA) configurations to measure power production and relative impacts of oxygen crossover on organics removal. The SEA configuration produced a higher maximum power density (280±6mW/m2; 16.3±0.4W/m3) than the SPA arrangement (255±2mW/m2) due to lower internal resistance. Power production in both configurations was lower than that obtained with the domestic wastewater (positive control) due to less favorable (more positive) anode potentials, indicating poorer biodegradability of the RW. MFCs with RW achieved up to 84% total COD removal, 73% soluble COD removal and 92% HBOD removal. These removals were higher than those previously obtained in mini-MEC tests, as oxygen crossover from the cathode enhanced degradation in MFCs compared to MECs. © 2013 Elsevier Ltd.

  18. Bio-Refineries Bioprocess Technologies for Waste-Water Treatment, Energy and Product Valorization

    Science.gov (United States)

    Keith Cowan, A.

    2010-04-01

    Increasing pressure is being exerted on communities and nations to source energy from forms other than fossil fuels. Also, potable water is becoming a scarce resource in many parts of the world, and there remains a large divide in the demand and utilization of plant products derived from genetically modified organisms (GMOs) and non-GMOs. The most extensive user and manager of terrestrial ecosystems is agriculture which is also the de facto steward of natural resources. As stated by Miller (2008) no other industry or institution comes close to the comparative advantage held for this vital responsibility while simultaneously providing food, fiber, and other biology-based products, including energy. Since modern commercial agriculture is transitioning from the production of bulk commodities to the provision of standardized products and specific-attribute raw materials for differentiated markets, we can argue that processes such as mass cultivation of microalgae and the concept of bio-refineries be seen as part of a `new' agronomy. EBRU is currently exploring the integration of bioprocess technologies using microalgae as biocatalysts to achieve waste-water treatment, water polishing and endocrine disruptor (EDC) removal, sustainable energy production, and exploitation of the resultant biomass in agriculture as foliar fertilizer and seed coatings, and for commercial extraction of bulk commodities such as bio-oils and lecithin. This presentation will address efforts to establish a fully operational solar-driven microalgae bio-refinery for use not only in waste remediation but to transform waste and biomass to energy, fuels, and other useful materials (valorisation), with particular focus on environmental quality and sustainability goals.

  19. Application of oxidative technique for organic matter remove from a petroleum refinery spent caustic stream; Aplicacao de tecnicas oxidativas para a remocao do teor de materia organica de uma corrente de soda gasta de refinaria de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Cavalcante, Aline M.; Sant' Anna Junior, Geraldo L.; Dezzotti, Marcia [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Programa de Engenharia Quimica

    2004-07-01

    Spent caustic is a hazardous wastewater produced in several petroleum refineries. After the specific treatment for toxicity reduction, performed in the industrial site, this stream still presents high organic matter content. Thus, many times a further treatment is required. In this work, the removal of dissolved organic carbon (DOC) from the spent caustic stream, previously submitted to wet air oxidation (WAO), was investigated. This softening process is required to reduce the impact of the spent caustic effluent on the downstream industrial wastewater biological treatment plant. Among the softening techniques tested, Fenton and photo-Fenton processes were the most efficient. The combination of these processes led to 49% of DOC removal in time intervals of 85 min, using molars ratios H{sub 2}O{sub 2}/DOC=1.34 and H{sub 2}O{sub 2}/Fe{sup 2+}=10. (author)

  20. Control of occupational exposure to phenol in industrial wastewater treatment plant of a petroleum refinery in Alexandria, Egypt: An intervention application case study.

    Science.gov (United States)

    Zaki, Gehan R; El-Marakby, Fadia A; Ramadan, Alaa El-Din K; Issa, Ahmed I; Nofal, Faten H

    2016-11-01

    Phenol exposure is one of the hazards in the industrial wastewater treatment basin of any refinery. It additively interacts with hydrogen sulfide emitted from the wastewater basin. Consequently, its concentration should be greatly lower than its threshold limit value. The present study aimed at controlling occupational exposure to phenol in the work environment of wastewater treatment plant in a refinery by reducing phenolic compounds in the industrial wastewater basin. This study was conducted on both laboratory and refinery scales. The first was completed by dividing each wastewater sample from the outlets of different refinery units into three portions; the first was analyzed for phenolic compounds. The second and third were for laboratory scale charcoal and bacterial treatments. The two methods were compared regarding their simplicities, design, and removal efficiencies. Accordingly, bacterial treatment by continuous flow of sewage water containing Pseudomonas Aeruginosa was used for refinery scale treatment. Laboratory scale treatment of phenolic compounds revealed higher removal efficiency of charcoal [100.0(0.0) %] than of bacteria [99.9(0.013) %]. The refinery scale bacterial treatment was [99.8(0.013) %] efficient. Consequently, level of phenol in the work environment after refinery-scale treatment [0.069(0.802) mg/m(3)] was much lower than that before [5.700(26.050) mg/m(3)], with removal efficiency of [99.125(2.335) %]. From the present study, we can conclude that bacterial treatment of phenolic compounds in industrial wastewater of the wastewater treatment plant using continuous flow of sewage water containing Pseudomonas Aeruginosa reduces the workers' exposure to phenol.

  1. A Study on the Preparation of Regular Multiple Micro-Electrolysis Filler and the Application in Pretreatment of Oil Refinery Wastewater

    Directory of Open Access Journals (Sweden)

    Ruihong Yang

    2016-04-01

    Full Text Available Through a variety of material screening experiments, Al was selected as the added metal and constituted a multiple micro-electrolysis system of Fe/C/Al. The metal proportion of alloy-structured filler was also analyzed with the best Fe/C/Al ratio of 3:1:1. The regular Fe/C/Al multiple micro-electrolysis fillers were prepared using a high-temperature anaerobic roasting method. The optimum conditions for oil refinery wastewater treated by Fe/C/Al multiple micro-electrolysis were determined to be an initial pH value of 3, reaction time of 80 min, and 0.05 mol/L Na2SO4 additive concentration. The reaction mechanism of the treatment of oil refinery wastewater by Fe/C/Al micro-electrolysis was investigated. The process of the treatment of oil refinery wastewater with multiple micro-electrolysis conforms to the third-order reaction kinetics. The gas chromatography–mass spectrometry (GC–MS used to analyze the organic compounds of the oil refinery wastewater before and after treatment and the Ultraviolet–visible spectroscopy (UV–VIS absorption spectrum analyzed the degradation process of organic compounds in oil refinery wastewater. The treatment effect of Fe/C/Al multiple micro-electrolysis was examined in the continuous experiment under the optimum conditions, which showed high organic compound removal and stable treatment efficiency.

  2. VOC emission from oil refinery and petrochemical wastewater treatment plant estimation

    Directory of Open Access Journals (Sweden)

    Mihajlović Marina A.

    2013-01-01

    Full Text Available The introduction of environmental legislation improvement for industrial producers in Serbia, notably the Integrated Pollution Prevention Control (IPPC license, will oblige the industrial producers to provide annual report on the pollutant emissions into the environment, as well as to pay certain environment fee. Wastewater treatment plant can be a significant source of volatile organic compounds (VOCs diffuse emissions, which are difficult to measure directly. In the near future reporting obligations might expend to benzene and other VOCs. This paper deals with gaseous emissions calculations from API separator based on the emission factors and the adequate software applications. The analyzed results show that the estimated emission values differ depending on the applied method. The VOC emissions have been estimated using US EPA and CONCAWE emissions factors. The calculated emissions range from 40 to 4500 tons/year for oil refinery WWTP of 2,000,000 m3/year. The calculations of benzene and toluene emissions have been performed using three methods: US EPA emission factors, WATER9, and Toxchem+ software. The calculated benzene and toluene emissions range from 5.5-60 and 0.7-20 tons/year, respectively. The highest emission values were obtained by the US EPA emission factors, while the lowest values were the result of Toxchem+ analysis. The sensitivity analysis of obtained results included the following parameters: flow, temperature, oil content, and the concentration of benzene and toluene in the effluent. Wide range of results indicates the need for their official interpretation for the conditions typical for Serbia, thus establishing adequate national emission factors for future utilization of the “polluter pays principle” on the VOC and benzene emissions.

  3. Mutagenicity and cytotoxicity evaluation of photo-catalytically treated petroleum refinery wastewater using an array of bioassays.

    Science.gov (United States)

    Iqbal, Munawar; Nisar, Jan; Adil, Muhammad; Abbas, Mazhar; Riaz, Muhammad; Tahir, M Asif; Younus, Muhammad; Shahid, Muhammad

    2017-02-01

    Degradation and detoxification of petroleum refinery wastewater (PRW) was carried out by advanced oxidation processes (UV/TiO2/H2O2 and gamma radiation/H2O2). Response surface methodology (RSM) was used to optimize the independent variables. The cytotoxicity was evaluated using Allium cepa, brime shrimp and haemolytic assays; whereas mutagenicity was tested by Ames tests (TA98 and TA100 strains). Maximum reductions in COD and BOD were recorded as 78% and 87% for UV/TiO2/H2O2 and 77% and 86% for gamma ray/H2O2, respectively. Treatments with both methods at optimized conditions reduced the cytotoxicity and mutagenicity of PRW, however, UV/TiO2/H2O2 system was found slightly efficient as compared to gamma ray/H2O2. From the results, it can be concluded that AOP's can successfully be utilized for the degradation of toxic pollutants in petroleum refinery wastewater. Moreover, the bioassays used in this study offered a good reliability for checking the detoxification of treated and un-treated PRW wastewater. Copyright © 2016 Elsevier Ltd. All rights reserved.

  4. APPLICATION OF CASSAVA PEELS ACTIVATED CARBON IN THE TREATMENT OF OIL REFINERY WASTEWATER – A COMPARATIVE ANALYSIS

    OpenAIRE

    Kigho Moses Oghenejoboh; Smith Orode Otuagoma; Evuensiri Onogwharitefe Ohimor

    2016-01-01

    A comparative analysis of the efficiency of activated carbon produced from fermented cassava peels (CPB), unfermented cassava peels (CPA) and commercial grade activated carbon (CAC) in the treatment of refinery wastewater was carried out. CPB was found to be 8% and 18% more efficient when compared to CPA and CAC in the removal of COD, and 14% and 3% better than CAC and CPA respectively in the removal of BOD5. The removal efficiency of Pb2+ by CPB was 100% compared to 95% and 57% by CPA and CA...

  5. Treatment of petroleum refinery wastewater containing heavily polluting substances in an aerobic submerged fixed-bed reactor.

    Science.gov (United States)

    Vendramel, S; Bassin, J P; Dezotti, M; Sant'Anna, G L

    2015-01-01

    Petroleum refineries produce large amount of wastewaters, which often contain a wide range of different compounds. Some of these constituents may be recalcitrant and therefore difficult to be treated biologically. This study evaluated the capability of an aerobic submerged fixed-bed reactor (ASFBR) containing a corrugated PVC support material for biofilm attachment to treat a complex and high-strength organic wastewater coming from a petroleum refinery. The reactor operation was divided into five experimental runs which lasted more than 250 days. During the reactor operation, the applied volumetric organic load was varied within the range of 0.5-2.4 kgCOD.m(-3).d(-1). Despite the inherent fluctuations on the characteristics of the complex wastewater and the slight decrease in the reactor performance when the influent organic load was increased, the ASFBR showed good stability and allowed to reach chemical oxygen demand, dissolved organic carbon and total suspended solids removals up to 91%, 90% and 92%, respectively. Appreciable ammonium removal was obtained (around 90%). Some challenging aspects of reactor operation such as biofilm quantification and important biofilm constituents (e.g. polysaccharides (PS) and proteins (PT)) were also addressed in this work. Average PS/volatile attached solids (VAS) and PT/VAS ratios were around 6% and 50%, respectively. The support material promoted biofilm attachment without appreciable loss of solids and allowed long-term operation without clogging. Microscopic observations of the microbial community revealed great diversity of higher organisms, such as protozoa and rotifers, suggesting that toxic compounds found in the wastewater were possibly removed in the biofilm.

  6. Photodegradation and removal of phenol and phenolic derivatives from petroleum refinery wastewater using nanoparticles of TiO2

    Directory of Open Access Journals (Sweden)

    F. Shahrezaei, A. Akhbari, A. Rostami

    2012-01-01

    Full Text Available This study explores the potential application of TiO2 photocatalysis as primary degradation system of phenol and phenolic derivatives from refinery wastewater. The removal of phenol was investigated in terms of various parameters namely: pH, temperature and catalyst concentration. Determination of phenol and phenolic derivatives compounds is carried out by gas chromatography using a flame ionization detector. In order to analyze the process, chemical oxygen demand fraction (R was studied. The region of the exploration for the process was taken as the area enclosed by pH (2-10, temperature (293-318 k and catalyst concentration (10-200 mg/l boundaries. The optimum conditions for phenol and phenolic derivatives removal were found to be 3, 318 k and 100 mg/l, respectively, for pH, temperature and catalyst concentration. The results showed that, at optimum conditions, remarkable removal of 90% of phenol after 2 h can be achieved. The main feature of this work is the use of inexpensive and recoverable catalyst and may be considered for preliminary application in the refinery wastewater treatments after physicochemical treatments to avoid solids and colloids.

  7. Photodegradation and removal of phenol and phenolic derivatives from petroleum refinery wastewater using nanoparticles of TiO2

    Energy Technology Data Exchange (ETDEWEB)

    Shahrezaei, F. [Academic Center for Education, Culture & Research (ACECR), Kermanshah (Iran, Islamic Republic of); Akhbari, A. [Department of Analytical Chemistry, Faculty of Chemistry, Razi University, Kermanshah (Iran, Islamic Republic of); Water and Wastewater Research Center (WWRC), Razi University, Kermanshah (Iran, Islamic Republic of); Rostami, A. [Kermanshah Oil Refinery company, R& amp; D department (KORC), Kermanshah (Iran, Islamic Republic of)

    2012-07-01

    This study explores the potential application of TiO2 photocatalysis as primary degradation system of phenol and phenolic derivatives from refinery wastewater. The removal of phenol was investigated in terms of various parameters namely: pH, temperature and catalyst concentration. Determination of phenol and phenolic derivatives compounds is carried out by gas chromatography using a flame ionization detector. In order to analyze the process, chemical oxygen demand fraction (R) was studied. The region of the exploration for the process was taken as the area enclosed by pH (2-10), temperature (293-318 k) and catalyst concentration (10-200 mg/l) boundaries. The optimum conditions for phenol and phenolic derivatives removal were found to be 3, 318 k and 100 mg/l, respectively, for pH, temperature and catalyst concentration. The results showed that, at optimum conditions, remarkable removal of 90% of phenol after 2 h can be achieved. The main feature of this work is the use of inexpensive and recoverable catalyst and may be considered for preliminary application in the refinery wastewater treatments after physicochemical treatments to avoid solids and colloids.

  8. Integration of biofiltration and advanced oxidation processes for tertiary treatment of an oil refinery wastewater aiming at water reuse.

    Science.gov (United States)

    Nogueira, A A; Bassin, J P; Cerqueira, A C; Dezotti, M

    2016-05-01

    The combination of biological and chemical oxidation processes is an interesting approach to remove ready, poor, and non-biodegradable compounds from complex industrial wastewaters. In this study, biofiltration followed by H2O2/UV oxidation (or microfiltration) and final reverse osmosis (RO) step was employed for tertiary treatment of an oil refinery wastewater. Biofiltration alone allowed obtaining total organic carbon (TOC), chemical oxygen demand (COD), UV absorbance at 254 nm (UV254), ammonium, and turbidity removal of around 46, 46, 23, 50, and 61 %, respectively. After the combined biological-chemical oxidation treatment, TOC and UV254 removal amounted to 88 and 79 %, respectively. Whereas, the treatment performance achieved with different UV lamp powers (55 and 95 W) and therefore distinct irradiance levels (26.8 and 46.3 mW/cm(2), respectively) were very similar and TOC and UV254 removal rates were highly affected by the applied C/H2O2 ratio. Silt density index (SDI) was effectively reduced by H2O2/UV oxidation, favoring further RO application. C/H2O2 ratio of 1:4, 55 W UV lamp, and 20-min oxidation reaction corresponded to the experimental condition which provided the best cost/benefit ratio for TOC, UV254, and SDI reduction from the biofilter effluent. The array of treatment processes proposed in this study has shown to be adequate for tertiary treatment of the oil refinery wastewater, ensuring the mitigation of membrane fouling problems and producing a final effluent which is suitable for reuse applications.

  9. Phylogenetic and functional diversity of metagenomic libraries of phenol degrading sludge from petroleum refinery wastewater treatment system.

    Science.gov (United States)

    Silva, Cynthia C; Hayden, Helen; Sawbridge, Tim; Mele, Pauline; Kruger, Ricardo H; Rodrigues, Marili Vn; Costa, Gustavo Gl; Vidal, Ramon O; Sousa, Maíra P; Torres, Ana Paula R; Santiago, Vânia Mj; Oliveira, Valéria M

    2012-03-27

    In petrochemical refinery wastewater treatment plants (WWTP), different concentrations of pollutant compounds are received daily in the influent stream, including significant amounts of phenolic compounds, creating propitious conditions for the development of particular microorganisms that can rapidly adapt to such environment. In the present work, the microbial sludge from a refinery WWTP was enriched for phenol, cloned into fosmid vectors and pyrosequenced. The fosmid libraries yielded 13,200 clones and a comprehensive bioinformatic analysis of the sequence data set revealed a complex and diverse bacterial community in the phenol degrading sludge. The phylogenetic analyses using MEGAN in combination with RDP classifier showed a massive predominance of Proteobacteria, represented mostly by the genera Diaphorobacter, Pseudomonas, Thauera and Comamonas. The functional classification of phenol degrading sludge sequence data set generated by MG-RAST showed the wide metabolic diversity of the microbial sludge, with a high percentage of genes involved in the aerobic and anaerobic degradation of phenol and derivatives. In addition, genes related to the metabolism of many other organic and xenobiotic compounds, such as toluene, biphenyl, naphthalene and benzoate, were found. Results gathered herein demonstrated that the phenol degrading sludge has complex phylogenetic and functional diversities, showing the potential of such community to degrade several pollutant compounds. This microbiota is likely to represent a rich resource of versatile and unknown enzymes which may be exploited for biotechnological processes such as bioremediation.

  10. APPLICATION OF CASSAVA PEELS ACTIVATED CARBON IN THE TREATMENT OF OIL REFINERY WASTEWATER – A COMPARATIVE ANALYSIS

    Directory of Open Access Journals (Sweden)

    Kigho Moses Oghenejoboh

    2016-04-01

    Full Text Available A comparative analysis of the efficiency of activated carbon produced from fermented cassava peels (CPB, unfermented cassava peels (CPA and commercial grade activated carbon (CAC in the treatment of refinery wastewater was carried out. CPB was found to be 8% and 18% more efficient when compared to CPA and CAC in the removal of COD, and 14% and 3% better than CAC and CPA respectively in the removal of BOD5. The removal efficiency of Pb2+ by CPB was 100% compared to 95% and 57% by CPA and CAC while 96% of phenol was removed by CPB against 93% and 83% by CPA and CAC respectively. This better performance of CPB over CPA and CAC is not unconnected with its higher pH resulting from the removal of cyanide from the peels during the fermentation process. However, despite the high phenol removal efficiency by CPB, the concentration of phenol in the treated effluent does not meet the environmental guidelines for disposal. It is therefore, recommended that a two-stage CPB adsorption column arranged in series is necessary to treat refinery wastewater efficiently if it is desired to totally remove phenol from the effluent or reduce the concentration to 0.005mg/l allowed by the Federal environmental protection agency (FEPA. The equilibrium adsorption test conducted showed that the Freundlich isotherm is a better fit for the adsorption of phenol by the three activated carbons with correlation coefficients (R2 of 0.9364, 0.9383 and 0.9541 for CAC, CPA and CPB respectively. CPB was found to be a better adsorbent as it has the highest adsorptive capacity as evidenced from its better Freundlich exponent.

  11. Isolation of Bacillus sp Producing Polyhydroxyalkanoate (PHA from Isfahan Refinery Wastewater and Qualification of Production in Submerged Fermentation

    Directory of Open Access Journals (Sweden)

    Mahsa Keshavarz Azam

    2015-12-01

    Full Text Available Introduction: The aim of present study was isolation of polyhydroxybutyrate producing Bacillus species from oil refinery waste water, Isfahan, Iran and primarily optimization of production condition. Petroleum wastes are rich of carbon sources and have low amounts of nitrogen and phosphorus sources. AS the most important factor in production of intracellular inclusions is increasing the C/N ratio, it seemed that polyhydroxybutyrate producing microorganisms will be found in these wastes. Materials and methods: Bacillus species were isolated and purified from oil refinery wastewater. The polymer was verified using different staining procedures. Polymer was extracted by digestion method and the optimum production conditions were investigated in minimal salt medium with the organic carbon source by submerged fermentation. Production of polyhydroxybutyrate was studied using dry weight and optical density measurement. Results: Between various isolated Bacillus strains, two of them (B1 and B2 were polyhydroxybutyrate producers. Maximum PHA production based on dry weight and concentration were obtained for strain B1 after 72 hours incubation, at 31°C, in the presence of glucose as carbon source and yeast extract as nitrogen source, pH=7, and aeration in 120 rpm; and for strain B2 in the same condition, except optimal temperature which was 32°C. The most production amounts were 367 mg.ml-1 for B1 and 473 mg.ml-1 for B2 isolates. Also the most polymer percentage was 52/16 and 58.43 for B1 and B2 isolates respectively. Discussion and conclusion: The results showed that the production of polyhydroxybutyrate was increased by optimization of the conditions in both isolates. Using petroleum wastes as well as production of biodegradable plastics, leads to decontamination of theses wastes.

  12. Effect of long-term application of oil refinery wastewater on soil health with special reference to microbiological characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Hayat, S.; Azam, Z.M.; Ahmad, A.; Inam, A.; Samiullah [Aligarh Muslim University (India). Department of Botany; Ahmad, I. [Aligarh Muslim University (India). R.A.K. Institute of Agricultural Sciences, Department of Agricultural Microbiology

    2002-09-01

    The ground water (GW), treated wastewater (TW) and the soil at the agricultural farm in the premises of the Mathura Oil Refinery have been monitored for various physico-chemical characteristics, over the last 12 years (1987-1998). It was noted that the heavy metal content in the soil, repeatedly irrigated with TW, was increasing because the wastewater itself was a better source of these metals than GW. However, the level of these metals, both in the wastewater and the soil, was very much below the permissible limits. The quantitative analysis of various functional groups of microorganism and their interaction with metals revealed that the viable count of aerobic heterotrophs, asymbiotic nitrogen fixers, actinomycetes and fungi were in the ranges of 2.6x10{sup 6}-7.2x10{sup 7}, 5.0x10{sup 4}-6.8x10{sup 5}, 2.0x10{sup 4}-2.8x10{sup 5} and 2.5x10{sup 4}-7.5x10{sup 5}, respectively. The presence of Rhizobium spp. in the soil was shown by the nodulation in the leguminous crops cultivated in the experimental field. The significant viable counts of above functional groups of bacteria on each heavy metal supplemented plate indicated that these populations could tolerate high levels ({>=}200{sup {mu}}g/ml) of metal. Among them, nitrogen fixers and aerobic heterotrophs (largely, Gram-negative) had a higher degree of resistance to heavy metals than actinomycetes. Similarly, the strains of Rhizobium, isolated from the experimental field, showed a higher degree of resistance under in vitro conditions and the minimum inhibitory concentration (MIC) was in the range of 50-800{sup {mu}}g/ml, determined by a plate dilution method. It may, therefore, be deduced that 12 years repeated application of treated wastewater had not significantly changed the microbial dynamics of the soil and possibly the bacteria had adapted to the changed soil environment by developing various levels of metals resistance. (author)

  13. A combination of solvent extraction and freeze thaw for oil recovery from petroleum refinery wastewater treatment pond sludge.

    Science.gov (United States)

    Hu, Guangji; Li, Jianbing; Hou, Haobo

    2015-01-01

    A combination of solvent extraction and freeze thaw was examined for recovering oil from the high-moisture petroleum refinery wastewater treatment pond sludge. Five solvents including cyclohexane (CHX), dichloromethane (DCM), methyl ethyl ketone (MEK), ethyl acetate (EA), and 2-propanol (2-Pro) were examined. It was found that these solvents except 2-Pro showed a promising oil recovery rate of about 40%, but the recycling of DCM solvent after oil extraction was quite low. Three solvents (CHX, MEK and EA) were then selected for examining the effect of freeze/thaw treatment on improving the quality of recovered oil. This treatment increased the total petroleum hydrocarbon (TPH) content in recovered oil from about 40% to 60% for both MEK and EA extractions, but little effect was observed for CHX extraction. Although the solid residue after oil recovery had a significantly decreased TPH content, a high concentration of heavy metals was observed, indicating that this residue may require proper management. In general, the combination of solvent extraction with freeze/thaw is effective for high-moisture oily hazardous waste treatment.

  14. Effects of Phosphorus and Nitrate in Wastewater Shahinshahr City Use for Oil Refinery

    OpenAIRE

    Rohollah Rezaei; Amir Samimi

    2013-01-01

    Polymeric phosphates in detergents are used widely in construction and hence have a significant concentration in the wastewater. Phosphate may result in sewage and industrial waste is waste from the body. Phosphate caused a rapid growth of aquatic plants such as algae and it is disturbing factor in the treatment processes. For example, concentrations in the range ppm 2/0 in order to reduce the turbidity of water contract will play the role of the intruder. Nitrogen gas (N2) and the primary co...

  15. Individual and combined effects of organic, toxic, and hydraulic shocks on sequencing batch reactor in treating petroleum refinery wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Mizzouri, Nashwan Sh., E-mail: nashwan_mizzouri@yahoo.com [Department of Civil Engineering, University of Malaya, Lembah Pantai, 50603 Kuala Lumpur (Malaysia); Department of Civil Engineering, University of Duhok, Kurdistan (Iraq); Shaaban, Md Ghazaly [Department of Civil Engineering, University of Malaya, Lembah Pantai, 50603 Kuala Lumpur (Malaysia)

    2013-04-15

    Highlights: ► This research focuses on the combined impact of shock loads on the PRWW treatment. ► System failure resulted when combined shock of organic and hydraulic was applied. ► Recovery was achieved by replacing glucose with PRWW and OLR was decreased to half. ► Worst COD removals were 68.9, and 57.8% for organic, and combined shocks. -- Abstract: This study analyzes the effects of toxic, hydraulic, and organic shocks on the performance of a lab-scale sequencing batch reactor (SBR) with a capacity of 5 L. Petroleum refinery wastewater (PRWW) was treated with an organic loading rate (OLR) of approximately 0.3 kg chemical oxygen demand (COD)/kg MLSS d at 12.8 h hydraulic retention time (HRT). A considerable variation in the COD was observed for organic, toxic, hydraulic, and combined shocks, and the worst values observed were 68.9, 77.1, 70.2, and 57.8%, respectively. Improved control of toxic shock loads of 10 and 20 mg/L of chromium (VI) was identified. The system was adversely affected by the organic shock when a shock load thrice the normal value was used, and this behavior was repeated when the hydraulic shock was 4.8 h HRT. The empirical recovery period was greater than the theoretical period because of the inhibitory effects of phenols, sulfides, high oil, and grease in the PRWW. The system recovery rates from the shocks were in the following order: toxic, organic, hydraulic, and combined shocks. System failure occurred when the combined shocks of organic and hydraulic were applied. The system was resumed by replacing the PRWW with glucose, and the OLR was reduced to half its initial value.

  16. A comprehensive evaluation of re-circulated bio-filter as a pretreatment process for petroleum refinery wastewater.

    Science.gov (United States)

    Dai, Xiaoli; Chen, Chunmao; Yan, Guangxu; Chen, Yu; Guo, Shaohui

    2016-12-01

    Conventional biological treatment process is not very efficient for the treatment of petroleum refinery wastewater (PRW) that contains high-concentration of organic contaminants. Prior to biological treatment, an additional pretreatment process for PRW is required for the effluent to meet the discharge standards. While re-circulated bio-filter (RBF) has been applied as a pretreatment process in several PRW treatment plants, its effects have not been comprehensively evaluated. In this study, the parameters of operation, the changes in pollution indexes and contaminant composition in an engineered RBF have been investigated. We found that mainly highly active de-carbonization bacteria were present in the RBF, while no nitrification bacteria were found in the RBF. This indicated the absence of nitrification in this process. The biodegradable organic contaminants were susceptible to degradation by RBF, which decreased the Biological Oxygen Demand (BOD5) by 83.64% and the Chemical Oxygen Demand (CODCr) by 54.63%. Consequently, the alkalinity and pH value of RBF effluent significantly increased, which was unfavorable for the control of operating parameters in subsequent biological treatment. Along with the decrease of CODCr, the RBF effluent exhibited a reduction in biodegradability. 834 kinds of recalcitrant polar organic contaminants remained in the effluent; most of the contaminant molecules having complex structures of aromatic, polycyclic and heterocyclic rings. The results of this study showed that RBF could efficiently treat PRW for biodegradable organic contaminants removal; however, it is difficult to treat bio-refractory organic contaminants, which was unfavorable for the subsequent biological treatment process operation. An improved process might provide overall guarantees for the PRW treatment. Copyright © 2016. Published by Elsevier B.V.

  17. PREDICTION OF BOD AND COD OF A REFINERY WASTEWATER USING MULTILAYER ARTIFICIAL NEURAL NETWORKS

    Directory of Open Access Journals (Sweden)

    Eldon Raj Rene

    2008-06-01

    Full Text Available In the recent past, artificial neural networks (ANNs have shown the ability to learn and capture non-linear static or dynamic behaviour among variables based on the given set of data. Since the knowledge of internal procedure is not necessary, the modelling can take place with minimum previous knowledge about the process through proper training of the network. In the present study, 12 ANN based models were proposed to predict the Biochemical Oxygen Demand (BOD5 and Chemical Oxygen Demand (COD concentrations of wastewater generated from the effluent treatment plant of a petrochemical industry. By employing the standard back error propagation (BEP algorithm, the network was trained with 103 data points for water quality indices such as Total Suspended Solids (TSS, Total Dissolved Solids (TDS, Phenol concentration, Ammoniacal Nitrogen (AMN, Total Organic Carbon (TOC and Kjeldahl’s Nitrogen (KJN to predict BOD and COD. After appropriate training, the network was tested with a separate test data and the best model was chosen based on the sum square error (training and percentage average relative error (% ARE for testing. The results from this study reveal that ANNs can be accurate and efficacious in predicting unknown concentrations of water quality parameters through its versatile training process.

  18. Research on the advanced treatment of refinery wastewater%炼油污水深度处理试验研究

    Institute of Scientific and Technical Information of China (English)

    龚小芝

    2013-01-01

    The effluent water from secondary settling tank in the wastewater treatment plant of a refinery,as the water source,has been treated by the combined process of pretreatment-ultrafiltration-reverse osmosis.The water produced by this combined process can be reused as make-up water for the desalted water plant.The said pretreatment process includes the processes of efficient fiber filter,biological activated carbon and electrocoagulation.The experimental results show that the combined process of efficient fiber filter-biological activated carbon-electrocoagula-tion-ultrafiltration-reverse osmosis is feasible and effective.After the refinery wastewater is treated by this process,the oil,CODMn,and NH3-N contained in the effluent would be less than 1 mg/L,1 mg/L,and 1 mg/L,respectively,meeting the requirements for ion exchange resin influent water in the refinery.%以某炼油厂的污水场二沉池外排污水为水源,经预处理+超滤+反渗透工艺处理后产水回用于脱盐水站补水.其中预处理包括高效纤维过滤、生物活性炭和电絮凝.试验结果表明,高效纤维过滤+生物活性炭+电絮凝+超滤+反渗透工艺可行,炼油废水经过该工艺处理后,出水中油≤1 mg/L、CODMn≤1 mg/L、氨氮≤l mg/L,达到了该厂对离子交换树脂进水要求.

  19. Reliability increasing of the Cubatao refinery mechanical equipment yard. An application of the reliability engineering concepts; Aumento da confiabilidade do parque de equipamentos mecanicos da Refinaria de Cubatao. Uma aplicacao dos conceitos da engenharia de confiabilidade

    Energy Technology Data Exchange (ETDEWEB)

    Afonso, Luiz Otavio Amaral [PETROBRAS, Cubatao, RJ (Brazil). Div. de Engenharia

    1998-07-01

    This paper reports the history of the reliability engineering applied to the reduction of failures quantity in mechanic equipment at the Cubatao, Brazil, refinery. The work describes the work system used for obtaining a 68 per cent reduction in the number of failures on the 1500 machines installed in a period of approximately seven years. Includes a brief description of the data bank or failure analysis in mechanic equipment (MICRO-SAFE), presently containing 5500 records, used to obtain statistical data on the equipment failures.

  20. Treatment of wastewater from an oil refinery sour water stripping unit using an aerated submerged biological filter

    Energy Technology Data Exchange (ETDEWEB)

    Ramaswamy, J.; Veenstra, J.N. [Oklahoma State Univ., Stillwater, OK (United States)

    1995-12-31

    The purpose of this research was to determine the kinetic constants for an Aerated Submerged Biological Filter (ASBF) used to reduce the toxicity of a petroleum refinery Process wastewater. The system was run at three different organic loadings and data were collected at steady state conditions for each loading. This data along with data obtained for three other loading conditions done a previous study (1) were used to determine the biokinetics constants which are required for the design of a full scale system. To measure the acute toxicity reduction, a 48- hour static bioassay was done on the ASBF unit influent and effluent. An attempt was also made to identify a significant fraction contributing to the toxicity by running the samples through a clinoptilolite column and then running a bioassay on the treated samples. At lower loading conditions (14.0 g COD/m{sup 2}/day), the ASBF gave maximum reduction of monitored parameters except ammonia. At the highest loading condition (24.0 COD/m{sup 2}/day), the reductions were smaller because the unit seemed to be operating near maximum organic loading capacity. Bioassays showed the LC{sub 50} generally increased after ASBF treatment, indicating toxicity reduction. The bioassays done on the samples treated by clinoptilolite showed further increase in the LC{sub 50} for the ASBF unit effluent indicating that ammonia may be a toxic fraction in the effluent. The kinetic constants were analyzed using the models proposed by Eckenfelder (2) and Korengay and Andrews (3). The proportionality constant for the former was equal to 0.00458 m{sup 3}/m{sup 2}/day. The area capacity constant for the latter was 22.8 g/m{sup 2}/day and the saturation constant 88.8 mg/{ell}. A model proposed by Kincannon and Stover (4) was also used to predict the kinetic constants. From this model the maximum specific substrate removal rate was determined to be 33.3 g/m{sup 2}/day and the proportionality constant was equal to 23.7 g/m{sup 2}/day.

  1. Degradation of Refinery Wastewater by Ozonation Combined With Catalytic Technology%臭氧协同催化剂处理炼油废水实验研究

    Institute of Scientific and Technical Information of China (English)

    崔金久

    2012-01-01

    利用臭氧催化氧化技术,开展降解炼油废水的实验研究.通过模拟活性污泥法验证污水生物降解性能的调控效果.结果表明:利用臭氧非均相催化技术可有效降解炼油废水中有机污染物且生物降解性能显著提高,COD平均去除率达65.0%,BOD5/COD从0.13提高至0.28;对于本实验装置,处理4 000 mL炼油废水最佳反应条件为臭氧流量40 L/h,催化剂为200 cm3载铜活性炭,pH=11,反应时间40 min.%The efficiency of catalytic ozonation on treating refinery wastewater was investigated and a simulated activated sludge process was conducted to determine the biodcgradability improvement. The experimental results show that the heterogeneous catalyst of copper loaded activated carbon combined ozonation is effective on degrading the organic pollutants and improving the hiodegradability of refinery wastewater. When treating 4 000 mL wastewater, the average COD removal rate of 65. 0% is attained while the BOD5/COD rate is improved from 0. 13 to 0. 28, under the optimal operational conditions of pH 11 , ozone flow rate 40 L/h, catalyst quantity 200 cm3 and reaction time 40 min.

  2. 炼油厂含盐废水中环烷酸的鉴定与分析%Analysis of Naphthenic Acids in Brine Wastewater from Refineries

    Institute of Scientific and Technical Information of China (English)

    李凌波; 郭宏山; 周艳红; 马荣华

    2012-01-01

    分别用快速化学定性法、GC-MS法、电喷雾(ESI)-MS法和FTIR法研究了加工高酸原油含盐废水及其处理过程废水中环烷酸的快速鉴定、来源、分子识别及含量.实验结果表明,利用在酸性和碱性条件下均产生沉淀的现象可快速鉴定炼油厂含盐废水中的环烷酸;GC-MS法可确定环烷酸主要来自含酸原油电脱盐过程,是影响含酸原油加工废水达标排放的主要组分;ESI-MS法能有效鉴定废水中环烷酸的类型及相对分子质量分布,某炼油厂含盐废水生化处理出水中检出碳数为5~41、相对分子质量为102~ 596、环数为0~6的环烷酸,其中C18环烷酸的含量最高;FTIR法测定某炼油厂气浮和生化处理后,环烷酸的总去除率为93.3%.%Naphthenic acids in brine wastewater from refineries processing acidic crude oil were analyzed by means of chemical analysis, GC-MS, electrospray ionization tandem MS and FTIR. The results showed that the naphthenic acids could be rapidly identified by chemical deposition under acidic and basic conditions. The naphthenic acids were found to derive mainly from crude oil desalter effluent by GC-MS, and were main components to prevent brine wastewater treatment effluent from reaching the discharge standards. The structures and relative molecular mass distributions of the naphthenic acids can be determined by anion electrospray ionization tandem MS. The naphthenic acids in biologically treated brine wastewater from a refinery were identified with the results of the relative molecular mass 102-596, the carbon number 5-41 and the ring number 0-6, in which the content of C18 naphthenic acids was the highest. The naphthenic acid concentration in crude oil desalter effluent from a refinery could be removed 93.3% by gas floatation and biochemical treatment.

  3. Refinery scheduling

    Energy Technology Data Exchange (ETDEWEB)

    Magalhaes, Marcus V.; Fraga, Eder T. [PETROBRAS, Rio de Janeiro, RJ (Brazil); Shah, Nilay [Imperial College, London (United Kingdom)

    2004-07-01

    This work addresses the refinery scheduling problem using mathematical programming techniques. The solution adopted was to decompose the entire refinery model into a crude oil scheduling and a product scheduling problem. The envelope for the crude oil scheduling problem is composed of a terminal, a pipeline and the crude area of a refinery, including the crude distillation units. The solution method adopted includes a decomposition technique based on the topology of the system. The envelope for the product scheduling comprises all tanks, process units and products found in a refinery. Once crude scheduling decisions are Also available the product scheduling is solved using a rolling horizon algorithm. All models were tested with real data from PETROBRAS' REFAP refinery, located in Canoas, Southern Brazil. (author)

  4. Treatment of petroleum refinery wastewater using a sequential anaerobic-aerobic moving-bed biofilm reactor system based on suspended ceramsite.

    Science.gov (United States)

    Lu, Mang; Gu, Li-Peng; Xu, Wen-Hao

    2013-01-01

    In this study, a novel suspended ceramsite was prepared, which has high strength, optimum density (close to water), and high porosity. The ceramsite was used to feed a moving-bed biofilm reactor (MBBR) system with an anaerobic-aerobic (A/O) arrangement to treat petroleum refinery wastewater for simultaneous removal of chemical oxygen demand (COD) and ammonium. The hydraulic retention time (HRT) of the anaerobic-aerobic MBBR system was varied from 72 to 18 h. The anaerobic-aerobic system had a strong tolerance to shock loading. Compared with the professional emission standard of China, the effluent concentrations of COD and NH3-N in the system could satisfy grade I at HRTs of 72 and 36 h, and grade II at HRT of 18 h. The average sludge yield of the anaerobic reactor was estimated to be 0.0575 g suspended solid/g CODremoved. This work demonstrated that the anaerobic-aerobic MBBR system using the suspended ceramsite as bio-carrier could be applied to achieving high wastewater treatment efficiency.

  5. The application of membrane bioreactor technology(MBR) in refinery biological wastewater treatment%MBR技术在炼油污水生化处理中的应用

    Institute of Scientific and Technical Information of China (English)

    周海燕

    2011-01-01

    为了提高炼厂污水生化处理能力,长庆石化公司采用膜生物反应器技术(MBR)与生化A/O(缺氧/好氧)工艺相结合,处理装置生产中产生的炼油废水。应用结果表明,在工艺控制平稳的情况下,采用膜生物反应器处理含油废水,加快加大了生物处理能力,能有效的降低炼油废水中各种污染物含量,达到污水处理后直接回用或进一步深度处理后回用,实现污水的资源化利用。%In order to improve the capacity of the refinery Biological wastewater treatment, Changqing Petrochemical Company uses membrane bioreactor technology (MBR) and biochemical A / O (anoxic / aerobic) process combined treatment to treat the refinery wastewater.Application results show that, in the case of a smooth process control, the use of MBR treatment of oil wastewater, biological treatment increased the ability to speed up, can effectively reduce the levels of various pollutants in refinery wastewater. Using the of way of sewage treatment ,the refinery wastewate can directly reuse or further back with the depth of treatment.This allows utilization of water resources.

  6. Comparison of Efficiencies and Mechanisms of Catalytic Ozonation of Recalcitrant Petroleum Refinery Wastewater by Ce, Mg, and Ce-Mg Oxides Loaded Al2O3

    Directory of Open Access Journals (Sweden)

    Chunmao Chen

    2017-02-01

    Full Text Available The use of catalytic ozonation processes (COPs for the advanced treatment of recalcitrant petroleum refinery wastewater (RPRW is rapidly expanding. In this study, magnesium (Mg, cerium (Ce, and Mg-Ce oxide-loaded alumina (Al2O3 were developed as cost efficient catalysts for ozonation treatment of RPRW, having performance metrics that meet new discharge standards. Interactions between the metal oxides and the Al2O3 support influence the catalytic properties, as well as the efficiency and mechanism. Mg-Ce/Al2O3 (Mg-Ce/Al2O3-COP reduced the chemical oxygen demand by 4.7%, 4.1%, 6.0%, and 17.5% relative to Mg/Al2O3-COP, Ce/Al2O3-COP, Al2O3-COP, and single ozonation, respectively. The loaded composite metal oxides significantly increased the hydroxyl radical-mediated oxidation. Surface hydroxyl groups (–OHs are the dominant catalytic active sites on Al2O3. These active surface –OHs along with the deposited metal oxides (Mg2+ and/or Ce4+ increased the catalytic activity. The Mg-Ce/Al2O3 catalyst can be economically produced, has high efficiency, and is stable under acidic and alkaline conditions.

  7. Pretreatment of Refinery Wastewater by Heterogeneous Catalytic Ozonation%臭氧多相催化氧化预处理石油炼制污水

    Institute of Scientific and Technical Information of China (English)

    魏令勇; 马静园; 刘月佳

    2013-01-01

    采用湿混捏法制备了Mn负载型中孔活性炭催化剂,并对催化剂试样进行N2吸附-脱附、TG和XRD表征,研究了臭氧多相催化氧化预处理石油炼制污水及其氧化机理.表征结果显示,催化剂制备过程中加入的Mn(NO3)2既生成了催化活性中心MnOx,又提高了催化剂的中孔率.污水预处理实验结果表明,添加5份Mn(质量份数)制备的Mn负载型中孔活性炭催化剂催化臭氧预处理石油炼制污水的效果最好,在污水预处理100 min后,COD去除率达到56.90%,五日生化需氧量与COD的比值为0.32,满足后续生化处理工艺的进水要求;污水中加入叔丁醇后导致污水的COD去除率明显降低,验证了臭氧多相催化氧化体系产生了羟基自由基,具有高级氧化技术的特征.%Manganese supported mesoporous activate carbon catalysts were prepared by wet mixing-kneading and used in heterogeneous catalytic ozonation for the pretreatment of refinery wastewater.The ozonation mechanism was investigated.The catalysts were characterized by means of N2 adsorption-desorption,TG and XRD.The characterization results indicated that the addition of manganous nitrate in the catalyst preparation not only generated the MnOx active site,but also increased the amount of mesopores.The pretreatment results showed that the catalyst prepared with 5 mass shares of Mn was optimal,and after the wastewater was pretreated for 100 min the removal efficiency of COD researched 56.90% and the ratio of 5-day biochemical oxygen demand to COD increased to 0.32,which was beneficial to the further biological treatment.The removal efficiency of COD decreased significantly after the addition of tert-butyl alcohol,which demonstrated that hydroxyl radicals were generated.

  8. Study on the composite system with flocculants for treating refinery wastewater%复配体系絮凝剂处理炼油废水的试验研究

    Institute of Scientific and Technical Information of China (English)

    王茂玉

    2011-01-01

    The circulating wastewater from a refinery plant has been studied. The synergistic effect of the composite system with different flocculants including polysilicate aluminum zinc (PSAZ), cationic-type starch flocculant, polyaluminium chloride (PAC), polymerization ferric chloride (PFC), cationic-type polyacrylamide(CPAM) and an-ionic-type polyacrylamide(APAM) on the treatment of refinery wastewater are investigated and studied respectively. The results show that among the composite systems, the system of PSAZ combined with cationic-type starch flocculant displays the best performance in treating refinery wastewater. Its removing rates of oil and turbidity are above 96% and 98% respectively.%以某炼油厂循环废水为处理对象,分别考察和研究了聚硅酸铝锌(PSAZ)与阳离子淀粉絮凝剂聚合氯化铝(PAC)、聚合氯化铁(PFC)、阳离子型聚丙烯酰胺(CPAM)、阴离子型聚丙烯酰胺(APAM)等复配体系絮凝剂协同作用下对炼油废水的处理效果.结果表明,在几种复配体系中,聚硅酸铝锌与阳离子淀粉絮凝剂的复配体系具有最佳的絮凝效果,对废水中油的去除率可达到96%以上,对浊度的去除率达98%以上.

  9. Tratamento de efluentes de refinaria de petróleo em reatores com Aspergillus niger Treatment of petroleum refinery wastewater by reactors inoculated with Aspergillus niger

    Directory of Open Access Journals (Sweden)

    Sandra Tédde Santaella

    2009-03-01

    Full Text Available Neste trabalho, avaliou-se o efeito do tempo de detenção hidráulica (TDH no desempenho de três reatores aeróbios inoculados com Aspergillus niger AN400, usados para tratamento de efluentes de refinarias de petróleo. Cada reator foi operado com um tempo de detenção hidráulica diferente: 4, 8 e 12 horas, durante 152 dias. Eles possuíam leito fixo de espuma de poliuretano e o escoamento era ascendente e contínuo. Determinaram-se: pH, fenóis, demanda química de oxigênio (DQO, amônia, nitrito e nitrato, no afluente e efluentes dos reatores. O TDH de oito horas foi o melhor para remoção de DQOsolúvel e não houve diferença entre os TDHs para remoção de fenóis totais. No período estável não houve remoção de nitrato; no entanto ocorreu remoção de nitrito de aproximadamente 99%. Além disto, houve produção de amônia devido à amonificação a partir do nitrito presente no meio.This paper evaluated the effect of hydraulic retention time (HRT on the performance of three upflow aerobic reactors, with polyurethane foam as support material, inoculated with Aspergillus niger AN400, used for the treatment of petroleum refinery wastewater. Each reactor was operated with a different HRT: 4, 8 and 12 hours, during 152 days. The performance was evaluated based on pH; phenols; COD, nitrate and nitrite. The results show that for the COD removal, it is more reasonable to operate the reactor with HRT of eight hours. However, there was no difference among results of phenol removal efficiency of the different HRTs. During steady state condition, nitrite was removed in approximately 99%, but there was no reduction on the nitrate concentration. Ammonia was produced in all reactors, probably due to ammonification of nitrite.

  10. Project design for treatment of super heavy oil refinery wastewater by biological process%超稠油炼制污水生化处理工程设计

    Institute of Scientific and Technical Information of China (English)

    蔡玉颖

    2011-01-01

    针对辽河石化稠油与超稠油加工污水高含油、高乳化、高CODCr、高NH3 -N及高悬浮物的特点,设计了以一级水解酸化、CAST、二级水解酸化、曝气生物滤池(BAF)为核心的生化处理工艺,出水达到《辽宁省污水综合排放标准》(DB 21/1627-2008)中第二类污染物新扩改一级标准.%Heavy oil and super heavy oil refinery wastewater from Liaohe Petrochemical Company is characterized by high degree of emulsification and high concentration of oil, CODCr, ammonia nitrogen and suspended solids. The project design of biochemical treatment process with primary hydrolysis acidification, CAST, secondary hydrolysis acidification and biological aerated filters (BAF) as its core is proposed by this paper. The effluent after treatment could reach to the first level of integrated wastewater discharge standard in Liaoning province( DB 21/1627-2008).

  11. 提高炼油废水处理场的氨氮去除率%Improving of Existing Refinery Wastewater Plant for Increasing Its Ammonia Nitrogen Removal Rate

    Institute of Scientific and Technical Information of China (English)

    范进昕; 孙杰

    2011-01-01

    对炼油废水处理场现有工艺进行流程优化,将MBR装置调整在接触氧化池之后运行.优化流程后氨氮平均去除率可从近于0提高至71.70%;COD平均去除率可从50.00%提高至72.00%.通过对工艺流程的对比,分析了现有工艺氨氮质量浓度难以降低的原因,指出废水中存在的某些污染物对硝化细菌起到抑制作用,减少了反应器中硝化细菌的数量,降低了氨氮去除效率.%The existing refinery wastewater treatment process was optimized by replacing the membrane bioreactor (MBR) after the contact oxidation tank. The average removal rate of ammonia nitrogen can be increased from about 0 to 71. 70% and that of COD can be increased from 50. 00% to 72. 00%. The causes for very low ammonia nitrogen removal rate of the original process are analyzed. It is pointed out that some pollutants in the wastewater may inhibit nitrobacteria decreasing ammonia nitrogen removal rate.

  12. Toxicity reduction in the treatment of refinery waste water

    Energy Technology Data Exchange (ETDEWEB)

    Eckenfelder, W.W. Jr.

    1995-12-31

    Aquatic Toxicity in refinery and petrochemical wastewaters may result from chemicals present in the feedstock, chemicals added or generated in the process, or chemicals generated during the wastewater treatment process, usually referred to as soluble microbial products (SMP). In most cases, the chemicals originally present or generated are biodegradable and can be removed in the biological treatment process. In some cases, a physical-chemical source treatment may be required. SMP generated through the wastewater treatment process are non-biodegradable and are best handled by the application of powdered activated carbon (PAC) integrated into the activated sludge process. This paper describes toxicity reduction in refinery effluents.

  13. Trace organics variation across the wastewater treatment system of a Class-B refinery and estimate of removal of refractory organics by add-on mixed-media filtration and granular activated carbon at pilot scale

    Energy Technology Data Exchange (ETDEWEB)

    Raphaelian, L. A.; Harrison, W.

    1978-06-01

    Wastewater at SOHIO's Toledo refinery was sampled every four hours for four successive days in December 1976. Effluents from the full-scale system (dissolved-air-flotation (DAF) unit and final clarifier for the activated-sludge unit) and an add-on pilot-scale unit (mixed-media filter and activated-carbon columns) were sampled for analysis of common wastewater parameters and trace organic compounds. Grab samples taken every four hours were composited daily. Organics were isolated into acid, base, and neutral fractions. Four-day composites of these daily extracts were analyzed by capillary-column gas chromatography/mass spectrometry. Some 304 compounds were identified in the neutral fraction of the DAF effluent and removal of these organics by the activated-sludge and add-on treatment units was estimated. Numerous data for the approximate concentration of organic compounds are presented. Common wastewater parameters are also presented for comparison to specific organics concentration data. The activated-sludge unit removed aromatic compounds better than it did nonaromatics whereas the activated-carbon unit was better at removal of nonaromatic compounds. Average percentage removal of those organics present in the DAF effluent was greater than 99 percent (activated sludge), approximately 0 percent (mixed-media filter), and less than 1 percent (activated carbon). Of the approximately 1 percent of trace organics remaining in the final-clarifier effluent, 81 percent (by weight) were removed by the activated carbon. Because of variations in extraction efficiencies, amount of sample injected, losses on the GC column and transfer lines, and other sources of error, these are only approximate removal estimates.

  14. WASTEWATER

    African Journals Online (AJOL)

    acid in the ozonized wastewater were degraded completely by ... wastewater from pulp and paper plants pose serious environmental problems when they are ... support aquatic life (Stern & Gasner 1974), Gupta and Battacharya 1985).

  15. Study on Magnetic Separation Treatment of High Concentration Wastewater from Refinery%磁分离技术处理炼油厂高浓度废水的研究

    Institute of Scientific and Technical Information of China (English)

    吴巍; 赵景霞; 回军; 李宝忠; 李丽杰

    2013-01-01

      为了处理炼油厂污水处理场隔油池高浓度出水,通过采用磁分离技术进行净化。研究了磁分离处理效果并与污水处理场多级气浮工艺效果相比较。结果为,经磁分离工艺处理后 COD 平均去除率近60%,比现有多级气浮效果相对优异。待磁助剂回收利用后,药剂成本将与气浮药剂成本相当,但电耗较之大大降低,是污水处理场节能减排的新方向。%The magnetic separation technology was used to treat the high concentration wastewater from refinery;the treatment effect of magnetic separator was studied and compared with the treatment effect of multistage flotation technology in sewage farm. The results show that, after the magnetic separation, the average removal rate of COD can reach almost 60%, and is better than that of the existing multistage flotation technology. After magnetic additives are recycled, the method’s additive cost will be equal to the existing multistage flotation technology, but power consumption is greatly reduced. It is the new direction of energy conservation and emissions reduction for wastewater treatment plants.

  16. Characterization of Foam in Refinery Wastewater Activated Sludge Process%炼油废水活性污泥处理工艺中泡沫的形成研究

    Institute of Scientific and Technical Information of China (English)

    余伟; 李海港; 于萍; 王黎明; 罗运柏

    2011-01-01

    Scum and foaming as one of the most common operating problems in aerobic activated sludge process would affect the normal operation of wastewater treatment system and effluent quality. Anionic suffactants and non-ionic surface active agents in refinery wastewater were detected and characterized with GC-MS technique and chemical methods. Results indicated that the foam forming in refinery wastewater activated sludge process was due to anionic surfactants and non-ionic surface active agents presented in system and Nocardioform actinomycetes presented in the activated sludge. Stable foam was chemical foam and biological foam. Anionic surfactant was carboxylic acids and non-ionic surface was polyoxyethylene nonionic surfactants, with the concentration as 0.480mg/L and 0.891mg/L respectively. The influence of some parameters on the stable foam forming were studied and described in details, such as pH value, DO and infiuent COD concentration as well as hydrophobic substances concentration. Mathematical model by which foam could be prevented was also established.%活性污泥法处理废水产生的泡沫会影响废水处理系统的正常运行及出水水质.采用气相色谱-质谱(GC-MS)对炼油废水的成分进行了鉴定,并用化学鉴定方法进行了对照,废水中存在阴离子和非离子表面活性剂.试验研究证明,炼油废水活性污泥处理工艺中产生泡沫的主要原因是系统中存在阴离子表面活性剂、非离子表面活性剂及活性污泥中存在诺卡氏放线菌.稳定泡沫属于化学泡沫与生物泡沫.进一步试验证明,废水中的阴离子表面活性剂属于羧酸盐类,非离子表面活性剂属于聚氧乙烯类,含量分别为0.480 mg/L、0.891 mg/L.试验分别研究了pH值、溶解氧浓度、进水COD含量和憎水性物质含量等因素对稳定泡沫的影响.通过曲线拟合,提出了预防泡沫形成的控制参数模型,借助该数学模型可以有效预测、判断及控制泡沫.

  17. Efeito da aplicacao pre-colheita de calcio na qualidade e no teor de nutrientes de manga 'Tommy Atkins'

    National Research Council Canada - National Science Library

    Silva, Davi Jose; Choudhury, Mohammad Menhazuddin; Mendes, Alessandra Monteiro Salviano; Dantas, Barbara Franca

    2008-01-01

    Com o objetivo de avaliar o efeito da aplicacao pre-colheita de calcio na qualidade e no teor de nutrientes de frutos de manga Tommy Atkins, foi realizado um experimento em um pomar comercial com dez...

  18. NAA application in the geochemical behavior study of lake sediments elements of a wastewater treatment plant; Aplicacao da NAA no estudo do comportamento geoquimico de elementos de interesse em sedimentos lacustres de uma estacao de tratamento de esgoto

    Energy Technology Data Exchange (ETDEWEB)

    Ribeiro, Andreza P.; Figueiredo, Ana Maria G. [Instituto de Pesquisas Energeticas e Nucleares (IPEN), Sao Paulo, SP (Brazil). Supervisao de Radioquimica. Lab. de Ativacao Neutronica]. E-mail: andreza@curiango.ipen.br; Sigolo, Joel B. [Sao Paulo Univ., SP (Brazil). Inst. de Geociencias]. E-mail: jbsigolo@usp.br; Figueira, Rubens C.L. [Universidade Cruzeiro do Sul (UNICSUL), Sao Miguel, SP (Brazil)

    2002-07-01

    Neutron activation analysis have been employed to determine 24 elements in bottom sediments from one lake of the Wastewater Treatment Plant of Barueri, SP, aiming to verify a possible contamination of this lake due to the wastes produced in the plant. The results obtained were compared with the concentration determined in soil profile and in a sample of rock, in natura, representing the lithologies of the region. Analysis was used in dry and wet seasons. The analysis of the data did not show a significant variation in concentration levels during the different periods, except for As. The results obtained showed a homogeneous distribution of the elements all along the lake and indicate that only As, Cr and Zn can have their origin associated with the residues disposed around the lake. (author)

  19. 活性污泥-生物膜共生系统处理炼油废水中试研究%Pilot study on the treatment of refinery wastewater using the activated sludge-biofilm symbiotic system

    Institute of Scientific and Technical Information of China (English)

    任建松; 许建民; 梅慧瑞

    2015-01-01

    The pilot study on the treatment of organic matter and ammonia nitrogen in refinery wastewater using the multiplex activated sludge-biofilm symbiotic system has been carried out. The COD and ammonia nitrogen can efficiently be removed by the biofilm system formed with the 卍-shaped nesting packing,while the influence of petroleum on micro-bacteria can be eliminated by the pre-sludge removing technology. The results show that under the following conditions:the卍-shaped packing dosing rate is 30%,retention time 18 h,influent COD 580-779 mg/L, ammonia nitrogen 48.4-70.4 mg/L,and petroleum 14.1-23.6 mg/L,the effluent COD is<50 mg/L,ammonia nitrogen<8 mg/L,petroleum<3 mg/L,volatile phenol and sulfide removing rates are both more than 60%. Compared with the conventional activated sludge process,the sludge concentration in the system has increased by twice or more.%采用复合式活性污泥—生物膜共生系统进行炼油废水有机物和氨氮处理的中试研究,卍字形嵌套填料形成的生物膜系统可高效去除COD和氨氮,利用前置排泥技术可消除石油类对微生物的影响。研究表明,在卍字形填料投加率为30%、停留时间为18 h的工况下,试验进水COD为580~779 mg/L、氨氮48.4~70.4 mg/L、石油类14.1~23.6 mg/L时,出水COD<50 mg/L、氨氮<8 mg/L、石油类<3 mg/L,挥发酚及硫化物去除率也在60%以上。与传统活性污泥法相比,系统内污泥浓度提高了2倍以上。

  20. Producao de fitomassa e acumulo de nutrientes pela aveia-preta em funcao da aplicacao de calcario e gesso em superficie na implantacao do sistema plantio direto

    National Research Council Canada - National Science Library

    Peres Soratto, Rogerio; Costa Crusciol, Carlos Alexandre

    2008-01-01

    Com o objetivo de avaliar a influencia da aplicacao de calcario e gesso em superficie, na implantacao do sistema plantio direto, sobre a producao de materia seca e ciclagem de nutrientes pela aveia...

  1. Maximizing petrochemicals from refineries

    Energy Technology Data Exchange (ETDEWEB)

    Glover, B.; Foley, T.; Frey, S. [UOP, Des Plaines, IL (United States)

    2007-07-01

    New fuel quality requirements and high growth rates for petrochemicals are providing both challenges and opportunities for refineries. A key challenge in refineries today is to improve of the value of the products from the FCC unit. In particular, light FCC naphtha and LCO are prime candidates for improved utilization. Processing options have been developed focusing on new opportunities for these traditional fuel components. The Total Petrochemicals/UOP Olefin Cracking Process cracks C4-C8 olefins to produce propylene and ethylene. This process can be integrated into FCC units running at all severity levels to produce valuable light olefins while reducing the olefin content of the light FCC naphtha. Integration of the Olefin Cracking Process with an FCC unit can be accomplished to allow a range of operating modes which can accommodate changing demand for propylene, cracked naphtha and alkylate. Other processes developed by UOP allow for upgrading LCO into a range of products including petrochemical grade xylenes, benzene, high cetane diesel and low sulfur high octane gasoline. Various processing options are available which allow the products from LCO conversion to be adjusted based on the needs and opportunities of an individual refinery, as well as the external petrochemical demand cycles. This presentation will examine recent refining and petrochemical trends and highlight new process technologies that can be used to generate additional revenue from petrochemical production while addressing evolving clean fuel demands. (orig.)

  2. 40 CFR 63.647 - Wastewater provisions.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 10 2010-07-01 2010-07-01 false Wastewater provisions. 63.647 Section... Emission Standards for Hazardous Air Pollutants From Petroleum Refineries § 63.647 Wastewater provisions... wastewater stream shall comply with the requirements of §§ 61.340 through 61.355 of 40 CFR part 61,...

  3. The flocculants applied in the oil refining plant wastewater treatment

    Science.gov (United States)

    Chesnokova, M. G.; Shalay, V. V.; Kriga, A. S.; Shaporenko, A. P.

    2017-08-01

    Flocculation methods for the oil refinery wastewater treatment are necessary, effective and economic, and are used, as a rule, for the demulsification of petroleum products from wastewater. In addition, flocculants can be used to remove other pollutants, not only oil products. The research purpose was to analyze the separate indicators level, measured on the oil refinery wastewater treatment facilities. Oil refinery wastewater purification rate was studied, indicating a different level of indicators considered. An influence of cationic and anionic flocculants working efficiency showed that the flocculants allows to increase the flotation technological indicators and to increase the solids content in water.

  4. ENERGY MANAGEMENT IN REFINERIES

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Japan energy saving activities of refineries in 1970s and 1980s were reviewed. The activities led by task teams were strongly supported by the corporate management. The teams consisted of well-trained and experienced persons from technical, maintenance, operation and manufacturing planning, and focused on cost cut, preventing energy losses, uncovering a lot of energy losses and preventing losses with no or small investment. For instance, loss measurement, less stripping steam, less reflux ratios, less treat gas, lower pressure and lower temperature, etc. In 1990s, environmental discussions suggested to introduce ultra low sulfur fuels and less CO2 emission fuels. In addition to the above, oil prices hike and supply shortage drive these activities. Energy saving should be evaluated by the overall optimization (saving and value generation). Energy utilization can be managed.

  5. Removal of ammonia nitrogen and hydrogen sulphide from refinery wastewater's and use of the recovered ammonia as an NO{sub x}-reducing agent; Entfernung von Ammonium-Stickstoff und Schwefelwasserstoff aus Raffinerieabwaessern und Einsatz des gewonnenen Ammoniaks als DeNO{sub x}-Agens

    Energy Technology Data Exchange (ETDEWEB)

    Stein, C.; Heine, I.; Sachse, J.; Peper, H.; Elster, J. [Holborn Europa Raffinerie GmbH, Hamburg (Germany)

    1999-07-01

    In a two-stage project for improved wastewater treatment the Holborn Europe refinery has achieved a drastic reduction of its emissions to water and air. In a first step, carried out in 1995, the steam stripping process for removing hydrogen sulphide from process water was reconstructed. In a second step a physicochemical treatment stage for removing ammonia nitrogen from the partial stream to be purified was completed. The existing single-stage biological wastewater treatment process is being operated without any additional equipment. With its investment costs of around 6.5 million marks, low overall wastewater costs (less than 2 marks/m{sup 3}), improved flexibility, avoidance of additional waste materials and substantial emission reductions, this combined plant, which in the meantime has been operating successfully for almost two years, serves as a positive example of how new environmental standards in the mineral oil industry can be met. [German] Mit einem zweistufigen Projekt zur verbesserten Abwasserbehandlung hat die Holborn Europa Raffinerie drastische Emissionsverminderungen in Wasser und Luft erzielt. Im ersten Schritt wurde 1995 die Dampfstrippung von Schwefelwasserstoff aus Prozesswaessern umgebaut. Im zweiten Schritt wurde die Ammonium-Stickstoff-Entfernung durch chemisch-physikalische Behandlung lediglich des aufbereitungsrelevanten Teilstroms realisiert. Die vorhandene einstufige biologische Abwasserbehandlung wird ohne Zusatzbauten weiter betrieben. Mit Investitionskosten von rund 6,5 Mio. DM, niedrigen Gesamtabwasserkosten (<2 DM/m{sup 3}), verbesserter Flexibilitaet, Vermeidung von zusaetzlichen Abfallstoffen und deutlicher Emissionsreduzierung ist die nun seit fast zwei Jahren erfolgreich betriebene Anlagenkombination ein positives Beispiel fuer die Bewaeltigung neuer Umweltanforderungen in der Mineraloelindustrie. (orig./SR)

  6. Analysis on Competitiveness of China's Refineries

    Institute of Scientific and Technical Information of China (English)

    Sun Yuguo

    2005-01-01

    The paper reviewed the refining and marketing business of both domestic and international oil companies, and tried to figure out the gap of domestic refining enterprises in terms of the refinery scale,processing unit configuration, stream factor and competitive edge as compared to overseas refineries. The paper also concluded that the net margin of domestic refineries is about $1.0/bbl lower than that of the overseas refineries, and proposed some ideas to sharpen the competitive edge of Chinese refining industry.

  7. Trends in oil discharged with aqueous effluents from oil refineries in Europe. 2005 and 2008 survey data

    Energy Technology Data Exchange (ETDEWEB)

    Baldoni-Andrey, P.; Girling, A.; Garcia Biosca, E.; Struijk, K.; De Borman, F.; Smith, R.; Kitow, I.; Negroni, J.; Neal, G.; Den Haan, K.

    2011-03-15

    This report summarises data gathered by CONCAWE in surveys of effluent water quantity, oil content and treatment processes for refinery locations situated in the EU-27 countries and those in Norway and Switzerland for the years 2005 and 2008. Data obtained in previous surveys are included for comparison. The number of refinery locations reporting in 2008 has increased to 125. The results of the surveys show that the trend for lower volumes of effluent discharge relative to refinery capacity and throughput has continued. Changes in the total amounts of discharged oil, ammonia, total nitrogen (TN), phenols, BOD (Biochemical Oxygen Demand), COD (Chemical Oxygen Demand) and TOC (Total Organic Carbon) are related to the increase in the number of refineries reporting in these years. The associated slight increases in the ratios of oil, TN, phenol, BOD and COD discharged relative to refining capacity and/or throughput may reflect the inclusion of additional refineries in countries that joined the EU in that period and whose performance may not have been at the same level as those previously surveyed. The results show that 89% of the refineries surveyed in 2005 had at least one stage of biological treatment in their wastewater treatment facilities. For 2008, this number rose to 94% for the reporting refineries. A different system of refinery complexity classification has been adopted for the 2005 and 2008 surveys. The Nelson Complexity Index (NCI) is an industry standard measure that takes account of each piece of refinery equipment on a refinery site. The 2005 and 2008 NCI scores show that the trend towards more complex refineries that was evident in the data set for the years 1969 to 2000 continues.

  8. Treatment of Refinery-Coking Wastewater by Aeration Micro-electrolysis Process with Hydrogen Peroxide%曝气微电解-双氧水工艺处理炼厂焦化废水

    Institute of Scientific and Technical Information of China (English)

    林伟帮; 李琪琪; 杨贺群; 谭毅; 蒋伟芬; 陈英; 陈东

    2012-01-01

    The rcfinery-coking wastewater was treated by aeration micro-electrolysis process with hydrogen peroxide. The influence of pH, reaction time, hydrogen peroxide and Iron filings dosage, and air flow on the removal of COD and NH3-N, and the ratio of BOD and COD for the waste water was investigated. The removal of COD and NH3-N in the wastewater was 37.6 % and 29.9 % respectively under the conditions of pH 5-7, Iron filings dosage of 100 g/L, hydrogen peroxide (30 % concentration)dosage of 2 mL/L, and 60 L/h air flow per 150 mL wastewater after reaction 90 rain. The ratio of BOD and COD increased from 0.25 to 0.66, which implied that the biodegradability of the wastewater was improved.%采用曝气微电解-双氧水工艺处理炼厂焦化废水,考察了废水pH、反应时间、双氧水投加量以及空气流量等因素对废水COD、NH3-N2、除率和BOD/COD比值的影响。结果表明,在pH5~7、铁稻用量100g/L、双氧水(浓度为30%)用量2mL/L,反应时间1.5h、空气流量60L/h(实验废水量150mL)的条件下,COD、NH3-N的去除率分别为37.6%和299%,BOD/COD比值从0.25提高到0.66,废水可生化性提高。

  9. Pretreatment of refinery waste water by wet oxidation. LOPROX {sup registered} procedure: Alternative treatment of sulfidic waste lyes by wet oxidation; Vorbehandlung von Raffinerieabwasser durch Nassoxidation. LOPROX {sup registered} -Verfahren: Alternative Behandlung von sulfidischen Ablaugen durch Nassoxidation

    Energy Technology Data Exchange (ETDEWEB)

    Leonhaeuser, Johannes; Weissenberg, Dirk; Birkenbeul, Udo [Bayer Technology Services GmbH (BTS), Leverkusen (Germany). Technology Development and Engineering; Bloecher, Christoph [Currenta (Germany)

    2012-05-15

    The authors of the contribution under consideration report on the treatment of refinery wastewater by means of the wet oxidation. The authors present the LOPROX {sup registered} method as an alternative treatment of sulfidic waste lyes. This method can not only treat successfully organic polluted wastewater from the chemical industry, but also various waste lyes from refinery processes. Based on a customer-specific process optimization in pilot scale, a cost-effective treatment can be achieved.

  10. Evaluation of toxicity to the biological treatment and removal of recalcitrant organic compounds from oil refineries wastewaters; Avaliacao da toxicidade ao tratamento biologico e remocao de compostos organicos recalcitrantes existentes em efluentes de refinarias de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Barros Junior, Laerte M.; Macedo, Gorete R.; Bezerra, Marcio S.; Pereira, Franklin M.S. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Dept. de Engenharia Quimica; Schmidell, Willibaldo [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil)

    2004-07-01

    Oil industry waste water usually contains recalcitrant chemical compounds, like phenol, benzene, toluene, xylene, naphthalene and acenaphthene. The respirometry, determination of respiration rate of an active biomass, is an adequate methodology for quantification of aerobic activity biological. This study aims evaluate the inhibition effect of phenol in the oxidation capacity of an industrial sludge. This work also intends to study the phenol removal through biological and photochemical-biological processes. The respirometry was carried out with synthetic solution, using sludge from an oil processing industry. The phenol degradation experiments were carried out in an activated sludge unit and in a photochemical reactor. This work suggests the potential of photochemical-biological treatment use, in relation to the biological process with a no-acclimated sludge, in the removal of refractory organic compounds from oil industry wastewaters. The characterization of biomass using the respirometry methodology showed which is a useful tool in evaluation of phenol toxicity to biological treatment. (author)

  11. Oil refinery hazardous effluents minimization by membrane filtration: An on-site pilot plant study.

    Science.gov (United States)

    Santos, Bruno; Crespo, João G; Santos, Maria António; Velizarov, Svetlozar

    2016-10-01

    Experiments for treating two different types of hazardous oil refinery effluents were performed in order to avoid/minimize their adverse impacts on the environment. First, refinery wastewater was subjected to ultrafiltration using a ceramic membrane, treatment, which did not provide an adequate reduction of the polar oil and grease content below the maximal contaminant level allowed. Therefore the option of reducing the polar oil and grease contamination at its main emission source point in the refinery - the spent caustic originating from the refinery kerosene caustic washing unit - using an alkaline-resistant nanofiltration polymeric membrane treatment was tested. It was found that at a constant operating pressure and temperature, 99.9% of the oil and grease and 97.7% of the COD content were rejected at this emission point. Moreover, no noticeable membrane fouling or permeate flux decrease were registered until a spent caustic volume concentration factor of 3. These results allow for a reuse of the purified permeate in the refinery operations, instead of a fresh caustic solution, which besides the improved safety and environmentally related benefits, can result in significant savings of 1.5 M€ per year at the current prices for the biggest Portuguese oil refinery. The capital investment needed for nanofiltration treatment of the spent caustic is estimated to be less than 10% of that associated with the conventional wet air oxidation treatment of the spent caustic that is greater than 9 M€. The payback period was estimated to be 1.1 years. The operating costs for the two treatment options are similar, but the reuse of the nanofiltration spent caustic concentrate for refinery pH control applications can further reduce the operating expenditures. Overall, the pilot plant results obtained and the process economics evaluation data indicate a safer, environmentally friendly and highly competitive solution offered by the proposed nanofiltration treatment, thus

  12. Post-treatment of refinery wastewater effluent using a combination of AOPs (H2O2 photolysis and catalytic wet peroxide oxidation) for possible water reuse. Comparison of low and medium pressure lamp performance.

    Science.gov (United States)

    Rueda-Márquez, J J; Levchuk, I; Salcedo, I; Acevedo-Merino, A; Manzano, M A

    2016-03-15

    The main aim of this work was to study the feasibility of multi-barrier treatment (MBT) consisting of filtration, hydrogen peroxide photolysis (H2O2/UVC) and catalytic wet peroxide oxidation (CWPO) for post-treatment of petroleum refinery effluent. Also the possibility of water reuse or safe discharge was considered. The performance of MBT using medium (MP) and low (LP) pressure lamps was compared as well as operation and maintenance (O&M) cost. Decomposition of organic compounds was followed by means of gas chromatography-mass spectrometry (GC-MS), total organic carbon (TOC) and chemical oxygen demand (COD) analysis. After filtration step (25 μm) turbidity and concentration of suspended solids decreased by 92% and 80%, respectively. During H2O2/UVC process with LP lamp at optimal conditions (H2O2:TOC ratio 8 and UVC dose received by water 5.28 WUVC s cm(-2)) removal of phenolic compounds, TOC and COD was 100%, 52.3% and 84.3%, respectively. Complete elimination of phenolic compounds, 47.6% of TOC and 91% of COD was achieved during H2O2/UVC process with MP lamp at optimal conditions (H2O2:TOC ratio 5, UVC dose received by water 6.57 WUVC s cm(-2)). In order to compare performance of H2O2/UVC treatment with different experimental set up, the UVC dose required for removal of mg L(-1) of COD was suggested as a parameter and successfully applied. The hydrophilicity of H2O2/UVC effluent significantly increased which in turn enhanced the oxidation of organic compounds during CWPO step. After H2O2/UVC treatment with LP and MP lamps residual H2O2 concentration was 160 mg L(-1) and 96.5 mg L(-1), respectively. Remaining H2O2 was fully consumed during subsequent CWPO step (6 and 3.5 min of contact time for LP and MP, respectively). Total TOC and COD removal after MBT was 94.7% and 92.2% (using LP lamp) and 89.6% and 95%, (using MP lamp), respectively. The O&M cost for MBT with LP lamp was estimated to be 0.44 € m(-3) while with MP lamp it was nearly five

  13. Aspects of petrochemistry in a fuels refinery

    Energy Technology Data Exchange (ETDEWEB)

    Esser, J.; Mielicke, C.J.; Maier, T. [MIRO - Mineraloelraffinerie Oberrhein GmbH und Co. KG, Karlsruhe (Germany)

    2007-07-01

    Classical links between refinery and petrochemical downstream operations are light naphtha, C2-C4-Olefins and various aromatic compounds. Additionally long chain paraffines from dewaxing or even heavy residues can be interesting starting materials for petrochemistry. Some aspects of these links between refining and petrochemistry as well as their impact on refinery operation and product pools are discussed. (orig.)

  14. Refinery burner simulation design architecture summary.

    Energy Technology Data Exchange (ETDEWEB)

    Pollock, Guylaine M.; McDonald, Michael James; Halbgewachs, Ronald D.

    2011-10-01

    This report describes the architectural design for a high fidelity simulation of a refinery and refinery burner, including demonstrations of impacts to the refinery if errors occur during the refinery process. The refinery burner model and simulation are a part of the capabilities within the Sandia National Laboratories Virtual Control System Environment (VCSE). Three components comprise the simulation: HMIs developed with commercial SCADA software, a PLC controller, and visualization software. All of these components run on different machines. This design, documented after the simulation development, incorporates aspects not traditionally seen in an architectural design, but that were utilized in this particular demonstration development. Key to the success of this model development and presented in this report are the concepts of the multiple aspects of model design and development that must be considered to capture the necessary model representation fidelity of the physical systems.

  15. Genotoxicity of refinery waste assessed by some DNA damage tests.

    Science.gov (United States)

    Gupta, Amit Kumar; Ahmad, Irshad; Ahmad, Masood

    2015-04-01

    Refinery waste effluent is well known to contain polycyclic aromatic hydrocarbons, phenols and heavy metals as potentially genotoxic substances. The aim of the present study was to assess the genotoxic potential of Mathura refinery wastewater (MRWW) by various in vitro tests including the single cell gel electrophoresis, plasmid nicking assay and S1 nuclease assay. Treatment of human lymphocytes to different MRWW concentrations (0.15×, 0.3×, 0.5× and 0.78×) caused the formation of comets of which the mean tail lengths increased proportionately and differed significantly from those of unexposed controls. The toxic effect of MRWW on DNA was also studied by plasmid nicking assay and S1 nuclease assay. Strand breaks formation in the MRWW treated pBR322 plasmid confirmed its genotoxic effect. Moreover, a dose dependent increase in cleavage of calf thymus DNA in S1 nuclease assay was also suggestive of the DNA damaging potential of MRWW. A higher level of ROS generation in the test water sample was recorded which might be contributing to its genotoxicity. Interaction between the constituents of MRWW and calf thymus DNA was also ascertained by UV-visible spectroscopy.

  16. Improving secondary clarifier performance at the Oakville Oil Refinery

    Energy Technology Data Exchange (ETDEWEB)

    Edwards, S.M.; Bagley, D.M. [Univ. of Toronto, Dept. of Civil Engineering, Toronto, Ontario (Canada)

    2002-06-15

    The purpose of this study was threefold: to investigate the relationship between settleability and the physical properties of activated sludge, to correlate settleability and key operational parameters such as chemical oxygen demand (COD) concentration at the aeration basin inlet and to determine potential operational improvements to the Oakville Oil Refinery Wastewater Treatment Plant. Nine separate sets of stirred sludge-settling tests were conducted over a six-month period to measure settleability. The stirred sludge volume index (SSVI), the zone settling constants, and the Zheng-Bagley compression constants were determined. State point analyses were conducted to determine the maximum solids flux of the clarifiers. The concentrations of Al, Mn, Mg, Fe, Ca, Na, and K were determined to identify potential correlations to settling characteristics. Extracellular polymeric substances were extracted from the sludge and analyzed for the same reason. The performance of the clarifiers was highly variable during the period examined. As the refinery process flows and effluent streams changed, influent COD increased, from an average of 180mg/L to 600mg/L. Concurrently the settleability of the sludge decreased from excellent (SSVI = 68mL/g) to very poor (150mL/g), perhaps as the result of under aeration. State point analyses indicated that the clarifiers are under-sized for process upsets of this magnitude. (author)

  17. Mazeikiai refinery woes deepen on all fronts

    Index Scriptorium Estoniae

    2007-01-01

    Leedu rahandusminister teatas, et riigieelarvet mõjutavad probleemid Mazeikiai tehasega, mis on Leedu suurim maksumaksja. Lisa: Russian oil company to build refinery. Surgutneftegaz teatas plaanist ehitada naftatöötlustehas Peterburi lähedale

  18. Mazeikiai refinery woes deepen on all fronts

    Index Scriptorium Estoniae

    2007-01-01

    Leedu rahandusminister teatas, et riigieelarvet mõjutavad probleemid Mazeikiai tehasega, mis on Leedu suurim maksumaksja. Lisa: Russian oil company to build refinery. Surgutneftegaz teatas plaanist ehitada naftatöötlustehas Peterburi lähedale

  19. Refinery siting workbook: appendices A and B

    Energy Technology Data Exchange (ETDEWEB)

    1980-07-01

    The objective of this effort is to develop and provide basic refinery-related information for use by state and local government officials as a basis for establishing responsible refinery siting requirements and policies consistent with the federal clean air and water standards and socio-economic concerns. The report will be organized into two volumes. The main text comprises the basic topics of physical concerns, regulatory requirements, and permitting activities, while the second volume includes the detailed appendix materials such as the applicable laws, and the necessary permits, as available and a glossary of pertinent terms. As a means to this objective, three refinery sizes, 200,000, 100,000 and 30,000 barrels per day crude charge will be discussed in technical terms. Process unit configuration will be presented which will maximize either gasoline or heating oil production with either sweet or sour crude oil feedstocks. The major issues affecting the socio-economic impact of siting the refinery in a given locale will be presented. These data will review the factors affecting the human environment and the issues that must be addressed to assess the impact that a refinery will have on a community. The key federal registrations which impact upon a refinery siting decision shall be reviewed. Summaries of these regulations and a simplified decision diagram for the air and water acts shall be presented to assist both government and refinery officials in understanding the scope of regulatory impact. All pertinent procedures required for refinery permitting shall be reviewed under the generalized headings of air, water, health and safety, land use, and miscellaneous permits. This categorization at the federal, state and local levels of government shall be used as a basis for establishing degrees of emphasis.

  20. Current situation of oil refinery in Bulgaria

    Science.gov (United States)

    Vershkova, Elena; Petkova, Petinka; Grinkevich, Anastasia

    2016-09-01

    This article deals with the classification approach for oil refineries in international practices. Criteria of refinery estimation group, including its financial status estimation, have been investigated. The analysis object is “Lukoil Neftochim Bourgas” AD (LNCHB) activity. This company is a leading enterprise in Bulgaria. The analysis of LNCHB operating: energy intensity index; index of operating costs and return on investment index have been performed.

  1. Status and tasks of oil refinery industry

    Energy Technology Data Exchange (ETDEWEB)

    Ku, I.M. [Korea Petroleum Association, Seoul (Korea, Republic of)

    1998-05-01

    The oil refinery industry is currently undergoing more difficulties than other industries. Since crude oil is all imported, whose import amount is the biggest as single item, and usance financing that once extended up to one hundred eighty (180) days is not easy to get under the current exchange and financial crisis, there are many hardships in import of crude oil. With this, domestic petroleum products demand shows sudden decline trend while competition gets more intensified due to remarkable regulation relief and liberalization measures in oil refinery industry such as the liberalization of domestic oil prices, etc. It is estimated that it entered the low growth stage as high-growth age of double-digit ends due to several complicated factors and rapid changes of economic environment. Under these crisis situations, domestic oil refinery industry drives super retrenchment management and restructuring for survival, but they are bombarded with piled up tasks while faced with liberalization and outward opening of imminent oil refinery business and domestic petroleum market. Domestic oil refinery industry should provide petroleum energy, which is blood of national economy and industries steadily without interruption overcoming wisely the worst management crisis with collective wisdom based on the accumulated management know-how and experience for the past first generation, and I also firmly believe that they can do that. 21 tabs.

  2. Sinopec Builds World-class Refinery in Qingdao

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    @@ Sinopec launched a subsidiary company in midNovember, Sinopec Qingdao Refinery and Chemical Company, to construct and operate a US$ 1.2 billion refinery in Qingdao, East China's Shandong Province. The refinery,which was first initiated 12 years ago, is an important move for Sinopec to complete its refinery deployment along the coast line to cash in on rapid market growth and better handle imports of crude oil.

  3. Research of combined adsorption-coagulation process in treating petroleum refinery effluent.

    Science.gov (United States)

    Wang, Bing; Shui, Yiyu; Ren, Hongyang; He, Min

    2017-02-01

    The petroleum refinery industry generates a significant amount of wastewater that contains a high level of organic matter, which calls for effective and costly treatments. In this research, the effectiveness of the petroleum refinery effluent (PRE) treatment with physicochemical process of combined adsorption and coagulation was evaluated. The effects of initial pH, hydraulic condition , and combined sequence of treatment process, different treating reagent types and dosages on the chemical oxygen demand (COD) removal were investigated. Additionally, the elimination efficiency of pollutant wastewater was monitored by gas chromatography-mass spectrometry (GC-MS), and Fourier transformed infrared (FT-IR) spectrophotometer was adopted to describe the structure of the wastewater. Wooden activated carbon was chosen as adsorbent at the dosage of 10 g/L as a primary treatment, and 1500 mg/L polymeric magnesium ferric sulfate was used in coagulation. Results showed that adsorption and subsequent coagulation displayed the best performance when initial pH was 9 at shear rates (G) of G1 = 65 s(-1) and G2 = 20 s(-1), which reached maximal removal rate of COD and total organic carbon GC-MS testing result revealed that adsorption was effective in phenols and iso-alkanes removal, whereas coagulation was good at removing esters and n-alkanes.

  4. A planning model for petroleum refineries

    Directory of Open Access Journals (Sweden)

    Pinto J.M.

    2000-01-01

    Full Text Available The main objective of this paper is to develop a nonlinear planning model for refinery production. The model described here represents a general petroleum refinery and its framework allows the implementation of nonlinear process models as well as blending relations. This model assumes the existence of several processing units, producing a variety of intermediate streams, with different properties, that can be blended to constitute the desired kinds of products. Two real-world applications are developed, one for the planning of diesel production in the RPBC refinery in Cubatão (SP and the other for the general production planning in the REVAP refinery in S. José dos Campos (SP. In both cases, different market scenarios were analyzed using the planning optimization and the results were compared with the current situation, in which there is no extensive use of planning decision support tools. Results revealed that there is a very large potential of profitability embedded in the planning activity, reaching several millions of dollars per year.

  5. Refinery siting workbook: appendices C to O

    Energy Technology Data Exchange (ETDEWEB)

    1980-07-01

    Applicable laws and permits available for the selection and building of petroleum refineries are enclosed. A glossary of pertinent terms is also included. References related to the National Environmental Policy Act, the Clean Air Act, the Federal Water Pollution Control Act, Resource Conservation and Recovery Act, Toxic Substance Control Act, and Wetlands and Coastal Zone are included. Permit information is also presented. (DC)

  6. Integrated pollution control for oil refinery complexes

    Energy Technology Data Exchange (ETDEWEB)

    Kiperstok, A. [Bahia Univ., Salvador, BA (Brazil); Sharratt, P.N. [Manchester Univ. (United Kingdom). Inst. of Science and Technology

    1993-12-31

    Improving environmental performance of oil refineries is a complex task. Emission limits, operating constraints, available technologies, operating techniques, and local environment sensitivity must all be considered. This work describes efforts to build an interactive software to deal with this problem. 8 refs., 5 figs.

  7. Typical Industrial Cluster - Chemistry/refinery/petrochemistry

    OpenAIRE

    Bungener, Stéphane Laurent

    2016-01-01

    A refinery and petrochemical site are described in the document. Data for the steam consumption and production of the cluster's process units are also described. The cluster can be broken down into two individual sites made up of process units and process utility requirements.

  8. SUPERTARGET: Applications software for oil refinery retrofit

    Energy Technology Data Exchange (ETDEWEB)

    Ahmad, S.; Patela, E.

    1987-01-01

    Pinch Technology has recently delivered radically new procedures for process retrofit. Software appropriate to these techniques is implemented in SUPERTARGET. It is now possible to predict, ahead of design, targets for energy savings, capital investment, and payback. The procedures account for how poorly the existing design is being used. This paper shows the techniques performed in an actual oil refinery retrofit using SUPERTARGET.

  9. [Sumac (Rhus chinensis Mill) biomass refinery engineering].

    Science.gov (United States)

    Wang, Lan; Wang, Ning; Li, Tan; Chen, Hongzhang

    2014-05-01

    Sumac (Rhus chinensis Mill) is an abundant and widely distributed Chinese native plant. Sumac fruit contains low content of vegetable oil, as an atypical oil plants hardly being processed through traditional vegetable oil production technologies. Based on our own studies on the characteristics of sumac fruit and branches, we established a novel model of sumac biomass refinery, and constructed the sumac biomass refinery technology system and eco-industrial chain integration. Steam explosion was the key technology, and several components fractionation technologies were integrated in the sumac biomass refinery system. The fractionated components were converted into different products depending on their functional features. Eight products including sumac fruit oil, biodiesel, protein feed, flavonoids, unbleached facial tissue, phenolic resin, biomass briquette and biogas were produced in the refinery. The extracted sumac fruit oil by steam explosion pretreatment was applied for the new food resource of Ministry of Health, and the permit was approved. This research provides a new model for the development of atypical wild plant resources.

  10. Refinery Upgrading of Hydropyrolysis Oil From Biomass

    Energy Technology Data Exchange (ETDEWEB)

    Roberts, Michael [Gas Technology Inst., Des Plaines, IL (United States); Marker, Terry [Gas Technology Inst., Des Plaines, IL (United States); Ortiz-Toral, Pedro [Gas Technology Inst., Des Plaines, IL (United States); Linck, Martin [Gas Technology Inst., Des Plaines, IL (United States); Felix, Larry [Gas Technology Inst., Des Plaines, IL (United States); Wangerow, Jim [Gas Technology Inst., Des Plaines, IL (United States); Swanson, Dan [Gas Technology Inst., Des Plaines, IL (United States); McLeod, Celeste [CRI Catalyst, Houston, TX (United States); Del Paggio, Alan [CRI Catalyst, Houston, TX (United States); Urade, Vikrant [CRI Catalyst, Houston, TX (United States); Rao, Madhusudhan [CRI Catalyst, Houston, TX (United States); Narasimhan, Laxmi [CRI Catalyst, Houston, TX (United States); Gephart, John [Johnson Timber, Hayward, WI (United States); Starr, Jack [Cargill, Wayzata, MN (United States); Hahn, John [Cargill, Wayzata, MN (United States); Stover, Daniel [Cargill, Wayzata, MN (United States); Parrish, Martin [Valero, San Antonio, TX (United States); Maxey, Carl [Valero, San Antonio, TX (United States); Shonnard, David [MTU, Friedrichshafen (Germany); Handler, Robert [MTU, Friedrichshafen (Germany); Fan, Jiquig [MTU, Friedrichshafen (Germany)

    2015-08-31

    Cellulosic and woody biomass can be converted to bio-oils containing less than 10% oxygen by a hydropyrolysis process. Hydropyrolysis is the first step in Gas Technology Institute’s (GTI) integrated Hydropyrolysis and Hydroconversion IH2®. These intermediate bio-oils can then be converted to drop-in hydrocarbon fuels using existing refinery hydrotreating equipment to make hydrocarbon blending components, which are fully compatible with existing fuels. Alternatively, cellulosic or woody biomass can directly be converted into drop-in hydrocarbon fuels containing less than 0.4% oxygen using the IH2 process located adjacent to a refinery or ethanol production facility. Many US oil refineries are actually located near biomass resources and are a logical location for a biomass to transportation fuel conversion process. The goal of this project was to work directly with an oil refinery partner, to determine the most attractive route and location for conversion of biorenewables to drop in fuels in their refinery and ethanol production network. Valero Energy Company, through its subsidiaries, has 12 US oil refineries and 11 ethanol production facilities, making them an ideal partner for this analysis. Valero is also part of a 50- 50 joint venture with Darling Ingredients called Diamond Green Diesel. Diamond Green Diesel’s production capacity is approximately 11,000 barrels per day of renewable diesel. The plant is located adjacent to Valero’s St Charles, Louisiana Refinery and converts recycled animal fats, used cooking oil, and waste corn oil into renewable diesel. This is the largest renewable diesel plant in the U.S. and has successfully operated for over 2 years For this project, 25 liters of hydropyrolysis oil from wood and 25 liters of hydropyrolysis oils from corn stover were produced. The hydropyrolysis oil produced had 4-10% oxygen. Metallurgical testing of hydropyrolysis liquids was completed by Oak Ridge National Laboratories (Oak Ridge) and showed the

  11. Production planning and scheduling in refinery industry

    Energy Technology Data Exchange (ETDEWEB)

    Persson, Jan

    1999-07-01

    In this thesis we consider production planning and scheduling in refinery industry, in particular we study the planning and scheduling at the Nynaes AB refinery and at the Scanraff AB refinery. The purpose is to contribute to the development and the use of optimization models to support efficient decision making. We identify various decision problems concerning the aggregated production planning, the shipment planning, the scheduling of operation modes, and the utilization of pipes and tanks; and we discuss the potential to successfully apply optimization models on these problems. We formulate a mixed integer linear programming model for the scheduling of operation modes at Nynaes. The model concerns decisions about which mode of operation to use at a particular point in time in order to minimize costs of changing modes and costs of keeping inventories, given demands for products. We derive several types of valid inequalities for this mathematical problem and show how these inequalities can improve the lower bound obtained from the linear programming relaxation of the problem. We also show how the valid inequalities can be used to improve the performance of a branch and bound solution approach. Further, a tabu search heuristic is developed for the scheduling problem. The solution methods are tested on data provided by the Nynaes refinery, and the performance of the methods are discussed. We present several extensions of the proposed model, and illustrate how the model can be used to support both operational and strategic decision making at the refinery. 66 refs, 6 figs, 32 tabs. Also published as: Dissertation from the International Graduate School of Management and Industrial Engineering, No 25, Licenciate Thesis.

  12. Production planning and scheduling in refinery industry

    Energy Technology Data Exchange (ETDEWEB)

    Persson, Jan

    1999-06-01

    In this thesis we consider production planning and scheduling in refinery industry, in particular we study the planning and scheduling at the Nynaes AB refinery and at the Scanraff AB refinery. The purpose is to contribute to the development and the use of optimization models to support efficient decision making. We identify various decision problems concerning the aggregated production planning, the shipment planning, the scheduling of operation modes, and the utilization of pipes and tanks; and we discuss the potential to successfully apply optimization models on these problems. We formulate a mixed integer linear programming model for the scheduling of operation modes at Nynaes. The model concerns decisions about which mode of operation to use at a particular point in time in order to minimize costs of changing modes and costs of keeping inventories, given demands for products. We derive several types of valid inequalities for this mathematical problem and show how these inequalities can improve the lower bound obtained from the linear programming relaxation of the problem. We also show how the valid inequalities can be used to improve the performance of a branch and bound solution approach. Further, a tabu search heuristic is developed for the scheduling problem. The solution methods are tested on data provided by the Nynaes refinery, and the performance of the methods are discussed. We present several extensions of the proposed model, and illustrate how the model can be used to support both operational and strategic decision making at the refinery. 66 refs, 6 figs, 32 tabs. Also published as: Dissertation from the International Graduate School of Management and Industrial Engineering, No 25, Licenciate Thesis

  13. Evaluation of the dispersion of oil refinery liquid effluent; Avaliacao da dispersao de efluente liquido de refinaria de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Mariano, Adriano Pinto; Silva, Ariovaldo Jose da; Oliveira, Valdenilson Jose Alves de; Angelis, Dejanira de Franceschi de [Universidade Estadual Paulista (UNESP), Rio Claro, SP (Brazil). Dept. de Bioquimica e Microbiologia. Inst. de Biociencias], e-mail: adrianomariano@yahoo.com.br

    2010-07-15

    In this paper, two techniques to evaluate the dispersion of the effluent of an oil refinery are presented. Thus, the dispersion plume was characterized by field measurements of electrical conductivity and by computational simulation (Cormix simulator). An oil refinery whose effluent is discharged on the Atibaia river (Paulinia/SP) is taken as study case. The behavior of the effluent was evaluated until 1000 m after the discharge. The results show that the measurement of electrical conductivity is a suitable technique to evaluate the dispersion of oil refinery wastewaters, since they have high conductivity and for this reason there is a strong contrast between the values of the wastewater and the ambient background. Furthermore, other water quality parameters had a dispersion behavior similar to that shown by the conductivity. The dispersion plume generated by the computational simulator showed high concordance with the field data. In this manner, computational simulation can be a useful tool to evaluate the dispersion of discharges considering hypothetical scenarios, as well as to design the discharge channel. (author)

  14. THE EFFECT OF REFINERY AND PETROCHEMICAL EFFLUENT ...

    African Journals Online (AJOL)

    Dr Osondu

    estuary and the largest oil producing state in Nigeria. Consequently ... health hazards associated with exploration and ... and refinery effluents and the health of aquatic ..... 2.85±0.04 p>0.05 10. Salinity (mg/l) 47.43,40.00. 45.32,45.19. 47.43,45.23 ... exposure to manganese during welding. Tech. D.Welding Allied Process.

  15. Opportunities for Biorenewables in Oil Refineries

    Energy Technology Data Exchange (ETDEWEB)

    Marker, T.L.

    2005-12-19

    Abstract: The purpose of this study was to evaluate the potential for using biorenewable feedstocks in oil refineries. Economic analyses were conducted, with support from process modeling and proof of principle experiments, to assess a variety of potential processes and configurations. The study considered two primary alternatives: the production of biodiesel and green diesel from vegetable oils and greases and opportunities for utilization of pyrolysis oil. The study identified a number of promising opportunities for biorenewables in existing or new refining operations.

  16. All Hydrogen Refinery with Zero Residue Discharge

    Institute of Scientific and Technical Information of China (English)

    Zhao Weifan; Sun Lili; Ju Linqing

    2007-01-01

    This article summarizes the block process flow scheme for the 8.0 Mt/a refining project at Hainan Refining and Chemical Company, Ltd., highlighting a green route for processing sour heavy oils, and the enlarged scale of production with Chinese content. The refinery is targeted at hydrotreating of process streams, integration and intensified design of process units, clean gasoline and diesel production, centralized recovery and utilization of light ends and optimization of sulphur recovery systems.

  17. Ranking environmental liabilities at a petroleum refinery

    Energy Technology Data Exchange (ETDEWEB)

    Lupo, M. [K. W. Brown Environmental Services, College Station, TX (United States)

    1995-12-31

    A new computer model is available to allow the management of a petroleum refinery to prioritize environmental action and construct a holistic approach to remediation. A large refinery may have numerous solid waste management units regulated by the Resource Conservation and Recovery Act (RCRA), as well as process units that emit hazardous chemicals into the environment. These sources can impact several environmental media, potentially including the air, the soil, the groundwater, the unsaturated zone water, and surface water. The number of chemicals of concern may be large. The new model is able to rank the sources by considering the impact of each chemical in each medium from each source in terms of concentration, release rate, and a weighted index based on toxicity. In addition to environmental impact, the sources can be ranked in three other ways: (1) by cost to remediate, (2) by environmental risk reduction caused by the remediation in terms of the decreases in release rate, concentration, and weighted index, and (3) by cost-benefit, which is the environmental risk reduction for each source divided by the cost of the remedy. Ranking each unit in the refinery allows management to use its limited environmental resources in a pro-active strategic manner that produces long-term results, rather than in reactive, narrowly focused, costly, regulatory-driven campaigns that produce only short-term results.

  18. MALODOR POLLUTION FROM REFINERY SEWAGE TREATMENT SYSTEM AND TREATMENT TECHNOLOGY

    Institute of Scientific and Technical Information of China (English)

    LIUZhong-sheng; GUOBing-bing; WANGYu-ting; LIUNian-zeng

    2003-01-01

    Main malodor pollutants from oil separator of Refinery A are hydrocarbons and a small quantity of sulfides.Main malodor pollutants from surface aeration tank of Refinery B are sulfides,especially CH3SH.And main malodor pollutants from bubbling aeration tank of Refinery C are also sulfides,of which H2S concentration is the highest,Catalytic combustion technology is applied to treat malodorous gas from oil separator of Refinery A,in which the total hydrocarbon removal was over 97%.The purified gas meets the national standard.Activated carbon adsorption is used to treat malodorous gas from surface aeration tank of Refinery B,and main pollutant CH3SH removal reached up to 98%-100%.As for malodorous gas from bubbling aeration tank of Refinery C,biopacking tower is used and the removals of hydrogen sulfide,organic sulfides and benzene series reached up to 80%-98%.

  19. Oil Refinery Supply Chain Modelling Using Pipe Transportation Simulator

    Directory of Open Access Journals (Sweden)

    Jakub Dyntar

    2012-03-01

    Full Text Available This paper describes an application of Pipe Transportation Simulator (PTS in oil refinery supply chain modelling. We develop the simulator in Witness simulation software environment using MS Excel for input data loading and outputs upgrading. PTS is particularly suitable for “what-if” analysis in the crude oil, fuels or gas supply chains where the products are transported among warehouses and refineries through the pipe lines. To discuss the basic functionality of proposed simulator we employ PTS to simulate a real oil refinery supply chain consisting of 16 warehouses and 3 refineries placed in the Czech Republic and Slovakia. The refineries and warehouses are connected together with 21 pipe lines. PTS is used to verify a plan of fuels movements among warehouses and refineries as well as a plan of repairs of certain pipe lines in the selected time period of the length of 30 days.

  20. Wastewater Outfalls

    Data.gov (United States)

    Iowa State University GIS Support and Research Facility — Outfalls which discharge wastewater from wastewater treatment facilities with individual NPDES permits. It does not include NPDES general permits.

  1. Sinopec to Construct New Refinery in East China

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    @@ China Petrochemical Corp (Sinopec), Asia's largest refiner, is beckoning Saudi Arabian Oil Company, or Saudi Aramco, to take a stake in its proposed US$13 billion refinery in Qingdao, East China's Shandong Province, in an attempt to bring in crude imports from Saudi Arabia to feed the refinery. A feasibility study on the refinery has been submitted for approval to the State Development and Reform Commission.

  2. 75 FR 37730 - National Emission Standards for Hazardous Air Pollutants From Petroleum Refineries

    Science.gov (United States)

    2010-06-30

    ... Petroleum Refineries AGENCY: Environmental Protection Agency (EPA). ACTION: Final rule; correction. SUMMARY... air pollutants from heat exchange systems at petroleum refineries. These requirements were published as amendments to the national emission standards for petroleum refineries. In this notice, we are...

  3. Electrochemical treatment of industrial wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Rajkumar, D. [Centre for Environmental Studies, Anna University, Chennai 600 025 (India); Palanivelu, K. [Centre for Environmental Studies, Anna University, Chennai 600 025 (India)]. E-mail: kpvelu@hotmail.com

    2004-09-10

    This paper presents the results of the treatment of phenolic compounds containing wastewater generated from phenol-formaldehyde resin manufacturing, oil refinery and bulk drug manufacturing industries by electrochemical method. Experiments were conducted at a fixed current density of 5.4 A/dm{sup 2} using Ti/TiO{sub 2}-RuO{sub 2}-IrO{sub 2} electrode and an undivided reactor. During the various stages of electrolysis, parameters such as COD and TOC concentrations were determined in order to know the feasibility of electrochemical treatment. Adsorbable organic halogens (AOX) were detected at high concentrations during the electrolytic treatment of the effluents. However, it was observed that increasing the electrolysis time bring down the AOX concentration to lower levels. Energy consumption and current efficiency during the electrolysis were calculated and presented. The present study proves the effectiveness of electrochemical treatment for highly concentrated bio-refractory organic pollutants present in the industrial wastewater.

  4. [Low temperature plasma technology for biomass refinery].

    Science.gov (United States)

    Fu, Xiaoguo; Chen, Hongzhang

    2014-05-01

    Biorefinery that utilizes renewable biomass for production of fuels, chemicals and bio-materials has become more and more important in chemical industry. Recently, steam explosion technology, acid and alkali treatment are the main biorefinery treatment technologies. Meanwhile, low temperature plasma technology has attracted extensive attention in biomass refining process due to its unique chemical activity and high energy. We systemically summarize the research progress of low temperature plasma technology for pretreatment, sugar platflow, selective modification, liquefaction and gasification in biomass refinery. Moreover, the mechanism of low temperature plasma in biorefinery and its further development were also discussed.

  5. Efficiency in Brazilian Refineries Under Different DEA Technologies

    Directory of Open Access Journals (Sweden)

    Claudia Aparecida Cavalheiro Francisco

    2012-11-01

    following as outputs: refinery production volume and generated effluents, desirable and undesirable, respectively, besides the uncontrollable variable, the refinery age. With the comparison result between the models, we observed the clear importance of the environmental variable for a more realistic analysis of the production process.

  6. Biostimulation of indigenous microbial community for bioremediation of petroleum refinery sludge.

    Directory of Open Access Journals (Sweden)

    Jayeeta Sarkar

    2016-09-01

    Full Text Available Nutrient deficiency severely impairs the catabolic activity of indigenous microorganisms in hydrocarbon rich environments (HREs and limits the rate of intrinsic bioremediation. The present study aimed to characterize the microbial community in refinery waste and evaluate the scope for biostimulation based in situ bioremediation. Samples recovered from the wastewater lagoon of Guwahati refinery revealed a hydrocarbon enriched high total petroleum hydrocarbon (TPH, oxygen-, moisture-limited, reducing environment. Intrinsic biodegradation ability of the indigenous microorganisms was enhanced significantly (>80% reduction in TPH by 90 days with nitrate amendment. Preferred utilization of both higher- (>C30 and middle- chain (C20-30 length hydrocarbons were evident from GC-MS analysis. Denaturing gradient gel electrophoresis (DGGE and community level physiological profiling (CLPP analyses indicated distinct shift in community’s composition and metabolic abilities following nitrogen (N amendment. High throughput deep sequencing of 16S rRNA gene showed that the native community was mainly composed of hydrocarbon degrading, syntrophic, methanogenic, nitrate/iron/sulfur reducing facultative anaerobic bacteria and archaebacteria, affiliated to γ- and δ-Proteobacteria and Euryarchaeota respectively. Genes for aerobic and anaerobic alkane metabolism (alkB and bssA, methanogenesis (mcrA, denitrification (nirS and narG and N2 fixation (nifH were detected. Concomitant to hydrocarbon degradation, lowering of dissolve O2 and increase in oxidation-reduction potential (ORP marked with an enrichment of N2 fixing, nitrate reducing aerobic/facultative anaerobic members e.g., Azovibrio, Pseudoxanthomonas and Commamonadaceae members was evident in N amended microcosm. This study highlighted that indigenous community of refinery sludge was intrinsically diverse, yet appreciable rate of in situ bioremediation could be achieved by supplying adequate N sources.

  7. 77 FR 56421 - Standards of Performance for Petroleum Refineries; Standards of Performance for Petroleum...

    Science.gov (United States)

    2012-09-12

    ... for Petroleum Refineries; Standards of Performance for Petroleum Refineries for Which Construction... CFR Parts 9 and 60 RIN 2060-AN72 Standards of Performance for Petroleum Refineries; Standards of Performance for Petroleum Refineries for Which Construction, Reconstruction, or Modification Commenced After...

  8. Optimization of water network in petroleum refinery; Otimizacao de redes de agua em refinarias de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Faria, Debora C.; Souza, Selene M.A. Guelli Ulson de; Souza, Antonio A. Ulson de [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil)

    2004-07-01

    The petroleum refineries have shown high water's consuming that creates high costs and damages the hydric resources. However, the industrial sector, especially the petroleum industry, has been looking for alternatives that minimizing the impact caused by to use these natural resources. Currently, methodologies of controlling the pollution on the source have been appearing how a strong tendency and the reuse and/or recycle of wastewater can be emphasized. The optimization by mathematical programming, together with engineering know-how, is one of the great tendency in process integration technology developed. The present work presents one optimization mathematical model that objectifies to reduce the water's consuming and/or operational costs. The model is based in chemical species and mass conservation equation. This work presents the solution of one case found in literature that broach one petroleum refinery's network of water. This network is composed of six operations and three regenerative processes, and there are four keys contaminants. The water's consuming was minimized first and next the minimum cost in the minimum consume was broached. The results found were enough satisfactory and presented reductions up to 76% in the water consume and approximately 65% in the operational costs. (author)

  9. Potential and optimization of two-phase anaerobic digestion of oil refinery waste activated sludge and microbial community study

    Science.gov (United States)

    Wang, Qinghong; Liang, Ying; Zhao, Peng; Li, Qing X.; Guo, Shaohui; Chen, Chunmao

    2016-12-01

    Oil refinery waste activated sludge produced from oil wastewater biological treatment is a major industrial sludge. Two-phase anaerobic digestion of oil refinery waste activated sludge was studied for the first time. Thermal pretreatment under 170 °C is effective on sludge solubilization. At the optimum hydrolytic-acidogenic condition which was pH of 6.5, temperature of 55 °C and HRT of 2 days, 2754 mg/L volatile fatty acids (VFAs) were produced and acetic acid and butyric acid were the key components. Comparative studies of single-phase and two-phase anaerobic digestion in terms of organic removal, biogas production and methane concentration were conducted. The cumulative methane production and soluble COD (SCOD) removal efficiency in the two-phase system were 228 mL/g COD added and 77.8%, respectively, which were 1.6 and 2.1 times higher than those in single-phase anaerobic digestion. Such improved performance is attributed to intensification of dominant microbial population in separated reactors. Caloramator, Ureibacillus, Dechloromonas, Petrobacter, and T78 played important roles in hydrolytic-acidification and oil-organics degradation. Syntrophic bacteria in the family Porphyromonadaceae and the genus Anaerobranca provide acetate for methanogen. The results demonstrated the potential and operating condition of two-phase anaerobic digestion in treatment of oil refinery waste activated sludge.

  10. Potential and optimization of two-phase anaerobic digestion of oil refinery waste activated sludge and microbial community study.

    Science.gov (United States)

    Wang, Qinghong; Liang, Ying; Zhao, Peng; Li, Qing X; Guo, Shaohui; Chen, Chunmao

    2016-12-01

    Oil refinery waste activated sludge produced from oil wastewater biological treatment is a major industrial sludge. Two-phase anaerobic digestion of oil refinery waste activated sludge was studied for the first time. Thermal pretreatment under 170 °C is effective on sludge solubilization. At the optimum hydrolytic-acidogenic condition which was pH of 6.5, temperature of 55 °C and HRT of 2 days, 2754 mg/L volatile fatty acids (VFAs) were produced and acetic acid and butyric acid were the key components. Comparative studies of single-phase and two-phase anaerobic digestion in terms of organic removal, biogas production and methane concentration were conducted. The cumulative methane production and soluble COD (SCOD) removal efficiency in the two-phase system were 228 mL/g COD added and 77.8%, respectively, which were 1.6 and 2.1 times higher than those in single-phase anaerobic digestion. Such improved performance is attributed to intensification of dominant microbial population in separated reactors. Caloramator, Ureibacillus, Dechloromonas, Petrobacter, and T78 played important roles in hydrolytic-acidification and oil-organics degradation. Syntrophic bacteria in the family Porphyromonadaceae and the genus Anaerobranca provide acetate for methanogen. The results demonstrated the potential and operating condition of two-phase anaerobic digestion in treatment of oil refinery waste activated sludge.

  11. Environmental Code of Practice for base metals smelters and refineries : Code of Practice, Canadian Environmental Protection Act, 1999

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-03-15

    This document described operational activities of base metals smelters and refineries and the associated environmental concerns, particularly the release of toxic substances from the sector. The document referred to smelters and refineries of primary copper, primary and secondary lead, primary zinc, primary nickel and primary cobalt. Environmental performance standards for mitigating these concerns were proposed. These included the implementation of environmental management systems and the prevention and control of atmospheric emissions, wastewater effluents and wastes. In smelters and refineries, ores and concentrates are supplied from mines and mills. Recycled material is supplied for further recovery and purification of metals. Operations in this sector include pretreatment of the ores, roasting, smelting, converting, fire refining, electrorefining, carbonyl refining, leaching, electrowinning, casting, and process off-gas conditioning. The pollutant releases of concern associated with these operations include process air emissions from stacks; process air emissions from open process equipment and buildings; fugitive air emissions from outdoor storage piles; accidentally released pollutants; water effluents from processes; water effluents from site runoff; and, slags, sludges and other residues and wastes. Sulphur dioxide, particulates, heavy metal compounds and certain organics are the pollutant that pose the greatest concern in facility air emissions. Oil, grease, solids and metals are the substances in water effluents that pose the greatest concern, along with acidic or alkaline effluents. 25 refs., 8 tabs., 2 figs., 2 appendices.

  12. Potential and optimization of two-phase anaerobic digestion of oil refinery waste activated sludge and microbial community study

    Science.gov (United States)

    Wang, Qinghong; Liang, Ying; Zhao, Peng; Li, Qing X.; Guo, Shaohui; Chen, Chunmao

    2016-01-01

    Oil refinery waste activated sludge produced from oil wastewater biological treatment is a major industrial sludge. Two-phase anaerobic digestion of oil refinery waste activated sludge was studied for the first time. Thermal pretreatment under 170 °C is effective on sludge solubilization. At the optimum hydrolytic-acidogenic condition which was pH of 6.5, temperature of 55 °C and HRT of 2 days, 2754 mg/L volatile fatty acids (VFAs) were produced and acetic acid and butyric acid were the key components. Comparative studies of single-phase and two-phase anaerobic digestion in terms of organic removal, biogas production and methane concentration were conducted. The cumulative methane production and soluble COD (SCOD) removal efficiency in the two-phase system were 228 mL/g COD added and 77.8%, respectively, which were 1.6 and 2.1 times higher than those in single-phase anaerobic digestion. Such improved performance is attributed to intensification of dominant microbial population in separated reactors. Caloramator, Ureibacillus, Dechloromonas, Petrobacter, and T78 played important roles in hydrolytic-acidification and oil-organics degradation. Syntrophic bacteria in the family Porphyromonadaceae and the genus Anaerobranca provide acetate for methanogen. The results demonstrated the potential and operating condition of two-phase anaerobic digestion in treatment of oil refinery waste activated sludge. PMID:27905538

  13. Wastewater Treatment

    Science.gov (United States)

    ... make water safe. Effects of wastewater pollutants If wastewater is not properly treated, then the environment and human health can be negatively impacted. These impacts can include harm to fish and wildlife ... in wastewater and the potentially harmful effects these substances can ...

  14. Electrochemical generation of Fenton's reagent to treat spent caustic wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Hansen, H. K.; Nunez, P.; Rodriguez, N.; Guzman, J.

    2009-07-01

    An important wastewater stream from oil refineries is the spent caustic. Caustic solutions are used as scrubbing agent during the desulphurization process to eliminate sulphur an mercaptans from oil and gasses. Spent caustic is classified as DOO3 (reactive sulphide) hazardous waste under the US Resource Conservation and Recovery Act (RCRA). (Author)

  15. Assessment of the effect of effluent discharge from coffee refineries ...

    African Journals Online (AJOL)

    Admin

    coffee refineries on river water quality based on physicochemical parameters and benthos assemblages as ... Water pollution is an acute problem in all water bodies, and major river ...... Mananga River, Cebu, Philippines. Philipp. Sci. Lett.

  16. environmental impact of illegal refineries on the vegetation of the ...

    African Journals Online (AJOL)

    Dr. O. M. Adesope

    impact of illegal oil refineries in the Niger Delta, Nigeria, the floristic ... ecosystem of Rivers State, five species of Mangroves and two species of grasses .... polluted air, contaminated environment, degraded forests, biodiversity loss and high.

  17. PetroChina to Expand Dushanzi Refinery on Large Scale

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    @@ A large-scale expansion project for PetroChina Dushanzi Petrochemical Company has been given the green light, a move which will make it one of the largest refineries and petrochemical complexes in the country.

  18. Aerobic Biological Fluidized Bed Technology Treatment of Sulfur and High Ammonia-nitrogen Wastewater in a Petroleum Refinery%曝气生物流化床处理炼油厂含硫和高氨氮污水的研究

    Institute of Scientific and Technical Information of China (English)

    叶正芳; 温丽丽; A.G.L.Borthwick; 倪晋仁

    2005-01-01

    炼油厂含硫污水因含高浓度的油、COD、硫化物及挥发酚而难于生化降解,催化剂生产中排放的污水因含高浓度的氨氮、盐类、悬浮物质以及低浓度的有机物而成为水处理的难题.本文采用一种曝气生物流化床(ABFT)工艺,对含硫污水和催化剂高氨氮污水的混合污水进行了现场连续试验,结果表明:在混合污水COD为2090mg/L、氨氮为600mg/L、挥发酚为27mg/L和硫化物为154mg/L的情况下,ABFT系统出水COD为95mg/L、氨氮为4.0mg/L、挥发酚为0.30mg/L和硫化物为0.0067mg/L,出水达到了国家污水排放标准一级标准.在处理工艺中,动态氧化和混凝沉淀作为预处理,ABFT反应器采用了合成高分子载体固定化微生物技术,该载体具有大孔网状以及优良的机械强度和化学性能,高效微生物B350通过化学键固定在载体上.克氏定氮法表明,ABFT中生物负载量为32mg/L.试验结果显示:在处理高氨氮污水方面,ABFT工艺比SBR工艺具有更强的优势,同时,ABFT系统具有较高的处理效率和耐冲击负荷能力.%Wastewaters from petrochemical plants are of two types: high sulfur wastewater with high levels of sulfur, oil, chemical oxygen demand (COD) and phenol; and high ammonia-nitrogen wastewater emanating from catalyst workshops, which contains large concentrations of ammonia-nitrogen, salinity, suspended solids (SS) and lower organic pollutants.Conventional biological treatments are expensive and not very effective at handling both kinds of wastewater stream. In this paper, a new aerobic biological fluidized bed technology (ABFT) process is proposed, whereby a mixture of the two kinds of wastewater is treated. A pilot experiment has been conducted to examine the feasibility of treating the mixed wastewater stream. In the experiment, the initial mean concentrations of contaminants in the mixed wastewater are: COD = 2090mg · L-1, NH4+-N = 600mg · L-1, volatile phenol = 27mg · L-1,and

  19. Chinese Government Approves Nanhai Oil Refinery Project of CNOOC

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    @@ The Nanhai Oil Refinery Project independently funded by CNOOC was approved by the related governmental departments in late July. The offshore oil giant builds the 12 million ton-per-year oil refinery in Guangdong Province in the next three years to tap the lucrative South China oil market.The investment in the project will total at least 16 billion yuan (US$1.93 billion).

  20. Challenges Facing Chinese Refineries and Demand Forecast for 2015

    Institute of Scientific and Technical Information of China (English)

    Sun Yongsheng

    2003-01-01

    @@ After several decades of development the processing capac ity of Chinese refineries has reached 276 million tons per year,ranking the fourth in the world. The refining industry has made great contribution to the growth of national economy in China. With changing times, especially after China's accession to the WTO, significant changes have occurred in economy, politics and petroleum market both at home and abroad. The survival and growth of Chinese refineries has faced new challenges.

  1. Long term effects of irrigation with petrochemical industry wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Aziz, O.; Inam, A.; Samiullah; Siddiqi, R.H. [Aligarh Muslim Univ. (India)

    1996-11-01

    Split plot designed field trials were conducted during 1988-1995 to study the long term effects of petrochemical industry wastewater on six crops and agricultural soils. It was observed that wastewater irrigation resulted in increased seed yield of all the crops selected, viz. wheat, triticale, chickpea, lentil and pigeonpea, except summer moong which showed a decrease in seed yield. Soil receiving the wastewater showed no significant changes in pH, total organic carbon, electrical conductivity, cation exchange capacity, micro- and macro-nutrients and SAR. Thus, it may be concluded that treated refinery wastewater met the irrigational quality requirements as its physico-chemical characteristics were within the permissible limits. The same could be said for the accumulation of heavy metals in the soil as well as in the grains making the latter safe for human consumption. 28 refs., 5 figs., 2 tabs.

  2. Palm-based biofuel refinery (PBR) to substitute petroleum refinery: An energy and emergy assessment

    Energy Technology Data Exchange (ETDEWEB)

    Goh, Chun Sheng; Lee, Keat Teong [School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, Seri Ampangan, 14300 Nibong Tebal, Seberang Perai Selatan, Pulau Pinang (Malaysia)

    2010-12-15

    As the most active palm industry cluster in the world, Malaysia produces enormous amount of biomass from the industry. This work studies the possibility of creating a renewable and sustainable source of energy by fully utilizing an area of land to provide liquid biofuel for the country. Palm-based biofuel refinery (PBR) proposed in this study has the ultimate goal to displace petroleum fuels and fulfill domestic energy demand. It fully utilizes indigenous palm biomass to fulfill 35.5% of energy demand in the country by using land area of only 8% of current palm cultivation. The operation concept of PBR is similar to petroleum refinery in which a single source feedstock (crude petroleum) can be processed to multiple products. In PBR, products from an oil palm plantation will be converted to various biofuel end products. Renewable biofuel such as biodiesel and bioethanol can be produced from crude palm oil and lignocellulosic residues. Energy and emergy assessment were made in this work to evaluate the sustainability and efficiency of PBR. Biofuel produced from PBR has a high energy equivalent of 31.56 MJ/kg as 1 ha of land can produce 182,142 MJ annually. Although there are still obstacles to be overcome, it is important for Malaysia to develop its own energy supply from indigenous resources as an initiative not only for security but also lower carbon emission. (author)

  3. Fingerprinting aliphatic hydrocarbon pollutants over agricultural lands surrounding Tehran oil refinery.

    Science.gov (United States)

    Bayat, Javad; Hashemi, Seyed Hossein; Khoshbakht, Korros; Deihimfard, Reza

    2016-11-01

    The analysis of aliphatic hydrocarbons, which are composed of n-alkanes as well as branched and cyclic alkanes, can be used to distinguish between the sources of hydrocarbon contamination. In this study, the concentration of aliphatic hydrocarbons, soil pH, and organic matter in agricultural soils located south of Tehran were monitored. Eighty-three soil samples were taken from two depth ranges of 0-30 and 30-60 cm. The results showed that aliphatic compounds ranged from 0.22-68.11 mg kg(-1) at the top to 0.33-53.18 mg kg(-1) at subsoil. The amount of hydrocarbons increases from the northern parts toward the south, and hydrocarbon pollutants originated from both petroleum and non-petroleum sources. Higher concentrations of aliphatic compounds in the southern parts indicated that, aside from the practice of irrigating with untreated wastewater, leakage from oil refinery storage tanks possibly contributed to soil pollution. The results also showed that several sources have polluted the agricultural soils. It is necessary to develop a new local pollution criterion as a diagnostic index that includes not only hydrocarbons but also other parameters such as heavy metal content in both soil and untreated wastewater, surface runoff, and other irrigation water resources to determine the exact origin of pollution.

  4. Wastewater Collection.

    Science.gov (United States)

    Chatterjee, Samar; And Others

    1978-01-01

    Presents a literature review of wastewater collection systems and components. This review covers: (1) planning, (2) construction; (3) sewer system evaluation; (4) maintenance; (5) rehabilitation; (6) overview prevention; and (7) wastewater pumping. A list of 111 references is also presented. (HM)

  5. Planning and scheduling for petroleum refineries using mathematical programming

    Directory of Open Access Journals (Sweden)

    Joly M.

    2002-01-01

    Full Text Available The objective of this paper is the development and solution of nonlinear and mixed-integer (MIP optimization models for real-world planning and scheduling problems in petroleum refineries. Firstly, we present a nonlinear planning model that represents a general refinery topology and allows implementation of nonlinear process models as well as blending relations. The optimization model is able to define new operating points, thus increasing the production of the more valuable products and simultaneously satisfying all specification constraints. The second part addresses scheduling problems in oil refineries, which are formulated as MIP optimization models and rely on both continuous and discrete time representations. Three practical applications closely related to the current refinery scenario are presented. The first one addresses the problem of crude oil inventory management of a refinery that receives several types of crude oil delivered exclusively by a single oil pipeline. Subsequently, two optimization models intended to define the optimal production policy, inventory control and distribution are proposed and solved for the fuel oil and asphalt plant. Finally, the planning model of Moro et al. (1998 is extended in order to sequence decisions at the scheduling level in the liquefied petroleum gas (LPG area for maximization of the production of petrochemical-grade propane and product delivery.

  6. Diversity of birds at Panipat refinery, Haryana (India).

    Science.gov (United States)

    Dhadse, Sharda; Kotangale, J P; Chaudhari, P R; Wate, S R

    2009-11-01

    Avifaunal study was carried out in Panipat refinery area before and after commissioning. A total of 63 birds were observed during the study, of which 39 and 49 birds were present during 1992 and 2001 respectively. Of these, 25 birds were common during both the study period. Blue rock pigeon was most dominant during 1992 whereas house sparrow was dominant during 2001. Species diversity index was found to be 5.26 and 6.64 in respective years. Jaccard's and Sorenson similarity indices were 0.40 and 0.57 respectively. Majority of birds were insectivorous in habits followed by granivorous birds in 1992 and piscivorous birds in 2001. The study reveals that less diversity was observed in 1992 when Panipat refinery was commissioned, but more birds especially aquatic ones were observed after the commissioning of the refinery. This has been attributed to increase in birds habitats due to developments of wetlands in and outside refinery, development of green belt around refinery and increase in green cover of area due to boosting of agroforestry and social forestry.

  7. 77 FR 29362 - Conocophillips Company, Trainer Refinery, Trainer, PA; Notice of Affirmative Determination...

    Science.gov (United States)

    2012-05-17

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF LABOR Employment and Training Administration Conocophillips Company, Trainer Refinery, Trainer, PA; Notice of... former workers of ConocoPhillips Company, Trainer Refinery, Trainer, Pennsylvania (subject firm)....

  8. Operational planning of refineries; Planejamento operacional de refinarias

    Energy Technology Data Exchange (ETDEWEB)

    Sinay, Maria Cristina Fogliatti de [Instituto Militar de Engenharia (IME), Rio de Janeiro, RJ (Brazil); Bueno, Catia [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2004-07-01

    The activities integration that compose the petroleum logistic chain makes more complex its planning which is normally done in a joined level, using operation research models in order to find optimized solutions. When this integrated planning is repassed to the companies and its constitutes parts (mainly refinery) uncertainness are generated about the solution that will be adopted in case of new restrictions appear. Then, the purpose of this work is propose a procedure that is capable to adequate and specifies optimized solutions presented by corporative model to refinery operations, using 'What-if' and deterministic simulation technique with optimization. To achieve this objective will be analysed typical activities in refineries and basic principles to their operational planning. (author)

  9. A new heavy residue upgrading process to retrofit existing refineries

    Energy Technology Data Exchange (ETDEWEB)

    Ghaedian, Maryam; Zarkesh, Jamshid [NIOC-Research Institute of Petroleum Industry (Russian Federation); Khadzhiev, S.; Kadiev, H. [Russian Academy of science (Russian Federation)

    2011-07-01

    Light crude oil reserves have declined and new fields being explored tend to be heavy oil, requiring processes to convert heavy residue to light products. The aim of this paper is to present the use of heavy residue hydroconversion (HRH) to upgrade heavy residues in existing refineries. A case study was carried out on a refinery with 250,000 barrel per day capacity, two cases were examined: the base case and the HRH case. Results showed that HRH provides higher IRR and NPV than the base case for the same investment. The heavy residue hydroconversion process was proved to be a feasible and reliable alternative which could eliminate residue while creating added value in existing refineries.

  10. 40 CFR 80.596 - How is a refinery motor vehicle diesel fuel volume baseline calculated?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false How is a refinery motor vehicle diesel... Requirements § 80.596 How is a refinery motor vehicle diesel fuel volume baseline calculated? (a) For purposes of this subpart, a refinery's motor vehicle diesel fuel volume baseline is calculated using...

  11. Optimization Model for Refinery Hydrogen Networks Part II

    Directory of Open Access Journals (Sweden)

    Enrique E. Tarifa

    2016-10-01

    Full Text Available In the first part of this work, a model of optimization was presented that minimizes the consumption of the hydrogen of a refinery. In this second part, the model will be augmented to take into account the length of the pipelines, the addition of purification units and the installation of new compressors, all features of industrial real networks. The model developed was implemented in the LINGO software environment. For data input and results output, an Excel spreadsheet was developed that interfaces with LINGO. The model is currently being used in YPFLuján de Cuyo refinery (Mendoza, Argentina

  12. Development of a distribution management system in refinery industry

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Developing an information system for managing the product distribution in a refinery demands sophisticated design solutions. First, organization models are created to describe the structural relationships among employees and the ways in which they will use the information system. Second, function models are created to hierarchically describe how sales, transports, deliveries and vehicles are managed. Thirdly, an information model is built to represent the data entities and their dynamic interactions. Based on the system design, a distribution management system is developed and implemented in a refinery, which has considerably increased the distribution management efficiency and effectiveness.

  13. Optimization of existing heat-integrated refinery distillation systems

    Energy Technology Data Exchange (ETDEWEB)

    Gadalla, M.; Jobson, M.; Smith, R.

    2003-01-01

    Existing refinery distillation systems are highly energy-intensive, and have complex column configurations that interact strongly with the associated heat exchanger network. An optimization approach is developed for existing refinery distillation processes. The optimization framework includes shortcut models developed for the simulation of the existing distillation column, and a retrofit shortcut model for the heat exchanger network. The existing distillation process is optimized by changing key operating parameters, while simultaneously accounting for hydraulic limitations and the design and the performance of the existing heat exchanger network. A case study shows that a reduction in energy consumption and operating costs of over 25% can be achieved. (Author)

  14. Wastewater reuse

    Directory of Open Access Journals (Sweden)

    Milan R. Radosavljević

    2013-12-01

    Full Text Available Water scarcity and water pollution are some of the crucial issues that must be addressed within local and global perspectives. One of the ways to reduce the impact of water scarcity  and to minimizine water pollution is to expand water and wastewater reuse. The local conditions including regulations, institutions, financial mechanisms, availability of local technology and stakeholder participation have a great influence on the decisions for wastewater reuse. The increasing awareness of food safety and the influence of the countries which import food are influencing policy makers and agriculturists to improve the standards of wastewater reuse in agriculture. The environmental awareness of consumers has been putting pressure on the producers (industries to opt for environmentally sound technologies including those which conserve water and reduce the level of pollution. It may be observed that we have to move forwards to implement strategies and plans for wastewater reuse. However, their success and sustainability will depend on political will, public awareness and active support from national and international agencies to create favorable    environment for the promotion of environmentally sustainable technologies. Wastewater treatment has a long history, especially in agriculture, but also in industry and households. Poor quality of wastewater can pose a significant risk to the health of farmers and users of agricultural products. The World Health Organization (WHO is working on a project for the reuse of wastewater in agriculture. To reduce effects of human activities to the minimum, it is necessary to provide such technical and technological solutions that would on the one hand ensure complying with  the existing regulations and legislation, and on the other hand provide economically viable systems as seen through investments and operating costs. The use of wastewater The practice of using wastewater varies from country to country. Its

  15. Wastewater Districts

    Data.gov (United States)

    Vermont Center for Geographic Information — The Wastewater districts layer is part of a larger dataset that contains administrative boundaries for Vermont's Agency of Natural Resources. The dataset includes...

  16. Wastewater Treatment.

    Science.gov (United States)

    Zoltek, J., Jr.; Melear, E. L.

    1978-01-01

    Presents the 1978 literature review of wastewater treatment. This review covers: (1) process application; (2) coagulation and solids separation; (3) adsorption; (4) ion exchange; (5) membrane processes; and (6) oxidation processes. A list of 123 references is also presented. (HM)

  17. Using relative risk analysis to set priorities for pollution prevention at a petroleum refinery

    Energy Technology Data Exchange (ETDEWEB)

    Schmitt, R.E.; Klee, H.; Sparks, D.M. [Amoco Corporation, Warrenville, IL (United States). Environmental Technical Services; Podar, M.K. [U.S. Environmental Protection Agency, Washington, DC (United States)

    1998-12-31

    This paper traces the background to the study site, Amoco`s Yorktown refinery, which currently manufactures gasoline, heating oil, liquefied petroleum gases (LPG), sulphur and coke, and the project to assess all the refinery emissions and evaluate options for reducing the releases. The assembling of the inventory of refinery releases, and the evaluation of the risks posed by the refinery emissions to air, surface water, drinking water and groundwater are described. The measuring of public perception of the refinery, the development and assessment of options to reduce the releases, ranking methods and results, and implementation of the selected option are discussed. (UK)

  18. Removal of sulfur compounds from petroleum refinery wastewater through adsorption on modified activated carbon.

    Science.gov (United States)

    Ben Hariz, Ichrak; Al Ayni, Foued; Monser, Lotfi

    2014-01-01

    The adsorption of sulfur compounds from petroleum refinery wastewater on a chemically modified activated carbon (MAC) was investigated. The modification technique (nitric acid, hydrogen peroxide and thermal modification) enhanced the removal capacity of carbon and therefore decreases cost-effective removal of sulfide from refinery wastewater. Adsorption equilibrium and kinetics data were determined for sulfur removal from real refinery wastewater. The data were evaluated according to several adsorption isotherm and kinetics models. The Freundlich isotherm fitted well with the equilibrium data of sulfur on different adsorbents, whereas the kinetics data were best fitted by the pseudo-second-order model. Insights of sulfide removal mechanisms indicated that the sorption was controlled through the intraparticle diffusion mechanism with a significant contribution of film diffusion. The MAC adsorbent was found to have an effective removal capacity of approximately 2.5 times that of non-modified carbon. Using different MAC, sulfides were eliminated with a removal capacity of 52 mg g(-1). Therefore, MAC can be utilized as an effective and less expensive adsorbent for the reduction of sulfur in refinery wastewater.

  19. Optimization Model for Refinery Hydrogen Networks Part I

    Directory of Open Access Journals (Sweden)

    Enrique E. Tarifa

    2016-10-01

    Full Text Available Petroleum refineries have many process units that consume hydrogen.These process units are distributed in different places everywhere in the refinery.In order to feed them, it is necessary to have sources capable of supplying, in amount and quality, the hydrogen that every consuming unit needs.It is also needed to have a distribution network that it is correctly designed and which operation is adjusted in an optimal manner to the changing conditions of the refinery.This involves the minimization of the cost of installation and operation of the hydrogen network.The installation cost is dominated by the amount of pipelines, compressors and purifying units; while the cost of operation is dominated by the amount of fresh hydrogen that the plant consumes.In this work a mathematical model is developed for a hydrogen network,which is adapted to the different information levels available in the different stages of design of that system.The model is currently in use in the YPFLuján de Cuyo refinery (Mendoza, Argentina. In this first part, the basic model is presented; whereas in a second part, the model is enlarged to accommodate the incorporation of purifying units and new compressors

  20. a factorial study of corporate performance of nigerian refineries ...

    African Journals Online (AJOL)

    eobe

    2016-01-01

    Jan 1, 2016 ... of Kendall's coefficient of concordance, which ranks varia of Kendall's ... There are oodles of factors that contribute to this kind ..... Choice of Outsourcing. 49. Refinery .... The Nigerian consumers are in need of ... Government should hold fast to the vision and mission ... Toxicology and Food Technology, Vol.

  1. Construction of Refinery Planned in China's Coastal Area

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    @@ CNOOC plans to build a 12-million-ton-per-year oil refinery in Southeast China's Guangdong Province in the next three years to tap the lucrative oil market in the southern part of the nation. Investment in the project, which was approved by the central government in mid-July, will total at least 16 billion yuan (US$1.93 billion).

  2. 76 FR 52556 - Election To Expense Certain Refineries

    Science.gov (United States)

    2011-08-23

    ... is more than 20 percent of the total cost of the property. (ii) Sale-leaseback. If any new portion of... the total amount allocated, determined on the basis of each cooperative owner's ownership interest in... directly from shale or tar sands. (iv) The total cost basis of the qualified refinery property at issue for...

  3. Energy efficiency improvement and cost saving opportunities forpetroleum refineries

    Energy Technology Data Exchange (ETDEWEB)

    Worrell, Ernst; Galitsky, Christina

    2005-02-15

    The petroleum refining industry in the United States is the largest in the world, providing inputs to virtually any economic sector,including the transport sector and the chemical industry. The industry operates 146 refineries (as of January 2004) around the country,employing over 65,000 employees. The refining industry produces a mix of products with a total value exceeding $151 billion. Refineries spend typically 50 percent of cash operating costs (i.e., excluding capital costs and depreciation) on energy, making energy a major cost factor and also an important opportunity for cost reduction. Energy use is also a major source of emissions in the refinery industry making energy efficiency improvement an attractive opportunity to reduce emissions and operating costs. Voluntary government programs aim to assist industry to improve competitiveness through increased energy efficiency and reduced environmental impact. ENERGY STAR (R), a voluntary program managed by the U.S. Environmental Protection Agency, stresses the need for strong and strategic corporate energy management programs. ENERGY STAR provides energy management tools and strategies for successful corporate energy management programs. This Energy Guide describes research conducted to support ENERGY STAR and its work with the petroleum refining industry.This research provides information on potential energy efficiency opportunities for petroleum refineries. This Energy Guide introduces energy efficiency opportunities available for petroleum refineries. It begins with descriptions of the trends, structure, and production of the refining industry and the energy used in the refining and conversion processes. Specific energy savings for each energy efficiency measure based on case studies of plants and references to technical literature are provided. If available, typical payback periods are also listed. The Energy Guide draws upon the experiences with energy efficiency measures of petroleum refineries worldwide

  4. Emission characteristics of volatile organic compounds and their secondary organic aerosol formation potentials from a petroleum refinery in Pearl River Delta, China.

    Science.gov (United States)

    Zhang, Zhijuan; Wang, Hao; Chen, Dan; Li, Qinqin; Thai, Phong; Gong, Daocheng; Li, Yang; Zhang, Chunlin; Gu, Yinggang; Zhou, Lei; Morawska, Lidia; Wang, Boguang

    2017-02-08

    A campaign was carried out to measure the emission characteristics of volatile organic compounds (VOCs) in different areas of a petroleum refinery in the Pearl River Delta (PRD) region in China. In the refining area, 2-methylpentane, 2,3-dimethylbutane, methylcyclopentane, 3-methylhexane, and butane accounted for >50% of the total VOCs; in the chemical industry area, 2-methylpentane, p-diethylbenzene, 2,3-dimethylbutane, m-diethylbenzene and 1,2,4-trimethylbenzene were the top five VOCs detected; and in the wastewater treatment area, the five most abundant species were 2-methylpentane, 2,3-dimethylbutane, methylcyclopentane, 3-methylpentane and p-diethylbenzene. The secondary organic aerosol (SOA) formation potential was estimated using the fractional aerosol coefficients (FAC), secondary organic aerosol potential (SOAP), and SOA yield methods. The FAC method suggests that toluene, p-diethylbenzene, and p-diethylbenzene are the largest contributors to the SOA formation in the refining, chemical industry, and wastewater treatment areas, respectively. With the SOAP method, it is estimated that toluene is the largest contributor to the SOA formation in the refining area, but o-ethyltoluene contributes the most both in the chemical industry and wastewater treatment areas. For the SOA yield method, aromatics dominate the yields and account for nearly 100% of the total in the three areas. The SOA concentrations estimated of the refining, chemical industry and wastewater treatment areas are 30, 3835 and 137μgm(-3), respectively. Despite the uncertainties and limitations associated with the three methods, the SOA yield method is suggested to be used for the estimation of SOA formation from the petroleum refinery. The results of this study have demonstrated that the control of VOCs, especially aromatics such as toluene, ethyltoluene, benzene and diethylbenzene, should be a focus of future regulatory measures in order to reduce PM pollution in the PRD region.

  5. Optimisation of petroleum refinery water network systems retrofit incorporating reuse, regeneration and recycle strategies

    Energy Technology Data Exchange (ETDEWEB)

    Khor, Cheng Seong; Shah, Nilay [Imperial College London (United Kingdom); Mahadzir, Shuhaimi [Universiti Teknologi Petronas (Malaysia); Elkamel, Ali [University of Waterloo (Canada)

    2012-02-15

    Increasingly strict environmental regulations have given rise to higher requirements for operating efficiency and optimization and water has become a vital resource in the refining process and allied industries. Due to this high demand for water, plants may be exposed to supply interruptions and shortages in the future. Major concerns in the petroleum refining industry are the scarcity of fresh water supply and increasingly rigid rules on wastewater discharge, which have resulted from concerns over the environmental impact. This paper presents the efforts made to develop an optimization framework for design of petroleum refinery water network systems and retrofitting that incorporates reuse, regeneration, and recycling strategies. This framework includes the complementary advantage of water pinch analysis (WPA). Water minimization strategies were incorporated as first postulates in a superstructural representation that includes all feasible flow-sheet options for taking advantage of water reuse, regeneration and recycling opportunities. Additionally, a post-optimization analysis was carried out to evaluate the repeated treatment processes required to identify the most efficient retrofit option.

  6. Analysis of the implementation of ergonomic design at the new units of an oil refinery.

    Science.gov (United States)

    Passero, Carolina Reich Marcon; Ogasawara, Erika Lye; Baú, Lucy Mara Silva; Buso, Sandro Artur; Bianchi, Marcos Cesar

    2012-01-01

    Ergonomic design is the adaptation of working conditions to human limitations and skills in the physical design phase of a new installation, a new working system, or new products or tools. Based on this concept, the purpose of this work was to analyze the implementation of ergonomic design at the new industrial units of an oil refinery, using the method of Ergonomic Workplace Assessment. This study was conducted by a multidisciplinary team composed of operation, maintenance and industrial safety technicians, ergonomists, designers and engineers. The analysis involved 6 production units, 1 industrial wastewater treatment unit, and 3 utilities units, all in the design detailing phase, for which 455 ergonomic requirements were identified. An analysis and characterization of the requirements identified for 5 of the production units, involving a total of 246 items, indicated that 62% were related to difficult access and blockage operations, while 15% were related to difficulties in the circulation of employees inside the units. Based on these data, it was found that the ergonomic requirements identified in the design detailing phase of an industrial unit involve physical ergonomics, and that it is very difficult to identify requirements related to organizational or cognitive ergonomics.

  7. Application of PIMS Software in Monthly Planning of Refinery Production

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    This article describes the application of the PIMS software in formulating monthly refining production plan. Application of the PIMS software can help to solve a series of problems related with monthly plan of refining production such as optimized selection of crude and feedstocks, optimized selection of production scale and processing scheme, identification of bottlenecks and their mitigation,optimized selection of turnaround time and optimized selection of operating regime, which have increased the economic benefits of refining enterprises. With the further development and improvement of models the PIMS software will play an increasingly important role in formulating monthly plans of refining operations and production management at refineries. This article also explores the problems existing in refinery monthly planning, and has made recommendations on developing and improving models and reporting system, enhancement of basic data acquisition, model maintenance personnel and staff training.

  8. Refinery production planning and scheduling: the refining core business

    Directory of Open Access Journals (Sweden)

    M. Joly

    2012-06-01

    Full Text Available Intelligent production planning and scheduling are of paramount importance to ensure refinery profitability, logistic reliability and safety at the local and corporate levels. In Brazil, such activities play a particularly critical role, since the Brazilian downstream model is moving towards a demand-driven model rather than a supply-driven one. Moreover, new and specialized non-linear constraints are continuously being incorporated into these large-scale problems: increases in oil prices implying the need for processing poor quality crudes, increasing demand and new demand patterns for petroleum products, new stringent environmental regulations related to clean fuels and start-up of new production technologies embedded into more complex refining schemes. This paper aims at clarifying the central role of refinery planning and scheduling activities in the Petrobras refining business. Major past and present results are outlined and corporate long-term strategies to deal with present and future challenges are presented.

  9. Evaluation of O{sub 3}UV e H{sub 2}O{sub 2}/UV processes combined with biological activated carbon for reuse refinery waste water; Avaliacao dos processos O{sub 3}UV e H{sub 2}O{sub 2}/UV combinados com carvao ativado granulado com biofilme para reuso de efluentes de refinaria

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Bianca Miguel de; Dezotti, Marcia [Coordenacao dos Programas de Pos-Graduacao de Engenharia (COPPE/UFRJ), RJ (Brazil); Cerqueira, Ana Claudia Figueiras Pereira de [Petroleo Brasileiro S.A. (CENPES/PETROBRAS), Rio de Janeiro, RJ (Brazil). Centro de Pesquisas e Desenvolvimento

    2012-07-01

    The treatment of refinery wastewater by advanced oxidation processes (AOP) coupled with biological activated carbon (BAC) was investigated aiming to generate water for reuse. The Gabriel Passos Refinery wastewater was previously treated in a membrane bioreactor, but still presented a high TOC content (30 mg/L) which may cause biofouling in the subsequent process of reverse osmosis. O3/UV and H2O2/UV processes were employed to oxidize the organic matter and BAC process to remove the residual organic matter from the AOP effluent. AOP promoted oxidation of recalcitrant organic matter as observed by drops on the treated wastewater absorbance and TOC values. BAC filters reached a TOC removal of 65% after 84 days of operation, while GAC filters were saturated after 28 days. Inoculated sand filters were also tested at different flow rates to compare with BAC filters. Low TOC values were achieved by the combined treatment, reaching values around 5 mg/L and allowing water reuse. BAC filters showed to be quite efficient for removal of organic compounds found in biologically treated oil refinery wastewater. (author)

  10. Use of the photo-Fenton process in degradation of the gasoline of refinery in water way; Utilizacao do processo foto-Fenton na degradacao da gasolina de refinaria em meio aquoso

    Energy Technology Data Exchange (ETDEWEB)

    Mota, Andre Luis N.; Silva, Douglas N. [Rio Grande do Norte Univ., Natal, RN (Brazil). Dept. de Engenharia Quimica. Programa de Recursos Humanos da ANP para o Setor Petroleo e Gas, PRH-ANP-14; Chiavone-Filho, Osvaldo [Universidade Federal do Rio Grande do Norte, Natal, RN (Brazil). Dept. de Engenharia Quimica]. E-mail: osvaldo@eq.ufrn.br; Moraes, Jose Ermirio F.; Nascimento, Claudio A.O. [Universidade de Sao Paulo, SP (Brazil). Dept. de Engenharia Quimica]. E-mail: jefm@lscp.pgi.eq.usp.br

    2003-07-01

    This work focus in the photo-Fenton process (combination between Fe{sup 2+}, H{sub 2}O{sub 2} and UV-visible light) for the degradation of the refinery gasoline (without alcohol and additives) in aqueous phase. This process represents a powerful alternative for the degradation of organic substances contained in wastewaters, because it generates more biodegradable products or even it results in the complete mineralization of the pollutant. The study of the degradation of the refinery gasoline using the process photo-Fenton has as short term goal the treatment of wastewater polluted with that type of pollutant, and as long term goal serving as study-base for the application of that process in the degradation of the oil contained in the water produced in fields of petroleum. The experiments of photo degradation of aqueous solutions containing refinery gasoline were accomplished using a falling films solar reactor. The influences of the following parameters were analyzed: the concentration of hydrogen peroxide (100 - 200 mM), the concentration of ions iron (0,5 - 1 mM) and the concentration of chloride of sodium (200 - 2000 ppm). (author)

  11. Global Warming Potential Of A Waste Refinery Using Enzymatic Treatment

    DEFF Research Database (Denmark)

    Tonini, Davide; Astrup, Thomas

    2010-01-01

    and fossil resources. This is especially important with respect to the residual waste (i.e. the remains after source-separation and separate collection) which is typically incinerated or landfilled. In this paper the energy and Global Warming performance of a pilot-scale waste refinery for the enzymatic...... plants and utilization of the liquid fraction for biogas production turned out to be the best options with respect to energy and Global Warming performance....

  12. Global Warming Potential Of A Waste Refinery Using Enzymatic Treatment

    DEFF Research Database (Denmark)

    Tonini, Davide; Astrup, Thomas

    2010-01-01

    and fossil resources. This is especially important with respect to the residual waste (i.e. the remains after source-separation and separate collection) which is typically incinerated or landfilled. In this paper the energy and Global Warming performance of a pilot-scale waste refinery for the enzymatic...... plants and utilization of the liquid fraction for biogas production turned out to be the best options with respect to energy and Global Warming performance....

  13. POSSIBILITIES OF CARBON DIOXIDE FIXATION BY MICROALGAE IN REFINERY

    OpenAIRE

    Šingliar, Michal; Mikulec, Jozef; Kušnir, Patrik; Polakovičova, Gabriela

    2013-01-01

    Capture and sequestration of carbon dioxide is one of the most critical challenges today for businesses and governments worldwide. Thousands of emitting power plants and industries worldwide face this costly challenge – reduce the CO2 emissions or pay penalties. One possibility for carbon dioxide sequestration is its fixation in microalgae. Microalgae can sequester CO2 from flue gases emitted from fossil fuel-fired refinery plants and units, thereby reducing emissions of a major greenhouse ga...

  14. Legitimacy in Green: Pollution vs. Profit in Canadian Oil Refineries

    Directory of Open Access Journals (Sweden)

    Vanessa Magness

    2007-06-01

    light of changing societal expectations have created an external environment that encourages the development of new technologies that promote cost efficiencies and good environmental performance simultaneously.  Russo and Fouts (1997 argued that industries subject to rapid technological advance are well suited to respond to these changes in the external environment. The findings of this paper suggest that the petroleum refinery sector of the oil and gas industry may be meeting the challenge of the environmental movement.

  15. Modeling and Multi-objective Optimization of Refinery Hydrogen Network

    Institute of Scientific and Technical Information of China (English)

    焦云强; 苏宏业; 廖祖维; 侯卫锋

    2011-01-01

    The demand of hydrogen in oil refinery is increasing as market forces and environmental legislation, so hydrogen network management is becoming increasingly important in refineries. Most studies focused on single-objective optimization problem for the hydrogen network, but few account for the multi-objective optimization problem. This paper presents a novel approach for modeling and multi-objective optimization for hydrogen network in refineries. An improved multi-objective optimization model is proposed based on the concept of superstructure. The optimization includes minimization of operating cost and minimization of investment cost of equipment. The proposed methodology for the multi-objective optimization of hydrogen network takes into account flow rate constraints, pressure constraints, purity constraints, impurity constraints, payback period, etc. The method considers all the feasible connections and subjects this to mixed-integer nonlinear programming (MINLP). A deterministic optimization method is applied to solve this multi-objective optimization problem. Finally, a real case study is intro-duced to illustrate the applicability of the approach.

  16. Energy Consumption and Analysis on Energy Saving Measures at SINOPEC's Large Refineries

    Institute of Scientific and Technical Information of China (English)

    Zhuang Jian; Hou Kaifeng; Yan Chun; Li Zhiqiang

    2007-01-01

    This article sums up the energy consumption of process units and the overall energy consumption of 10 Mt/a class refineries constructed or revamped in recent years.The energy saving measures adopted in design of these refineries are analyzed and discussed.Finally,this article also makes comments and puts forward recommendations on the objectives for energy conservation at refineries jn the future.

  17. Development of a life cycle cost estimating framework for oil refineries

    OpenAIRE

    Okafor, Okechukwu Peter

    2011-01-01

    This study is concerned with the understanding of some vital features of various life cycle costing methodologies and tools. Integrating these features with the refinery technical processes would assist in the development of a life cycle costing framework for oil refineries. The aim of this research is to develop a comprehensive life cycle cost estimating framework for the evaluation of not only the total cost and system effectiveness of new refineries but also the revamping, and maintenance ...

  18. Oil Refineries Emissions Impact on Urban Localities Using AERMOD

    Directory of Open Access Journals (Sweden)

    Amira M.W. Abdelrasoul

    2010-01-01

    Full Text Available Problem statement: The absolute necessity of compulsory fuel utilities, no matter small or big has resulted into substantial high hazards pollutants. Petroleum refineries are major industrial installations that are necessary for providing the best suited fuel for various necessary utilities, but are responsible of the emission of several hazardous pollutants into the atmosphere. Hydrocarbons are among the most perilous air pollutants that are emitted from almost all refining processes in petroleum refineries. Approach: Every day leaks and gaseous discharge from relief valves and liquid discharge, which are often directed to knock-out drums, are flared to minimize the impact of hydrocarbons emissions. But these flares are not that efficient and result into partial discharge of pollutants that have severe impact on the industrial area and urban localities in the vicinity of industrial refining complex. Results: In the present study, a thorough investigation has been completed to estimate the total emissions of sulfur dioxide SO2 and non methane hydrocarbons NMHC (VOCs and to assess their impact on the air quality in industrial and suburban areas. The latest version AMS/EPA Regulatory Model (AERMOD specially designed to support the US Environmental Protection Agency (EPA’s was used to predict the ground level concentrations of SO2, VOCs from AL-Ahmadi and Al-Shuiba Refineries of total refining capacity of 646 thousand barrels/day. Conclusion/Recommendations: These concentrations are compared with EPA standards to indicate the ambient air quality. The dispersion model was corroborated with extensive one year hourly record of the surface and upper air meteorological data for year 2006 and emission rates of the specified pollutants, with detailed refinery stacks parameters, such as stack height, diameter, exit flue gas velocity and temperature to determine the fraction of total study area in the vicinity of refineries that had substantially high

  19. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters

    Energy Technology Data Exchange (ETDEWEB)

    Benson, Charles; Wilson, Robert

    2014-04-30

    This project culminated in the demonstration of a full-scale industrial burner which allows a broad range of “opportunity” gaseous fuels to be cost-effectively and efficiently utilized while generating minimal emissions of criteria air pollutants. The burner is capable of maintaining a stable flame when the fuel composition changes rapidly. This enhanced stability will contribute significantly to improving the safety and reliability of burner operation in manufacturing sites. Process heating in the refining and chemicals sectors is the primary application for this burner. The refining and chemical sectors account for more than 40% of total industrial natural gas use. Prior to the completion of this project, an enabling technology did not exist that would allow these energy-intensive industries to take full advantage of opportunity fuels and thereby reduce their natural gas consumption. Opportunity gaseous fuels include biogas (from animal and agricultural wastes, wastewater plants, and landfills) as well as syngas (from the gasification of biomass, municipal solid wastes, construction wastes, and refinery residuals). The primary challenge to using gaseous opportunity fuels is that their composition and combustion performance differ significantly from those of conventional fuels such as natural gas and refinery fuel gas. An effective fuel-flexible burner must accept fuels that range widely in quality and change in composition over time, often rapidly. In Phase 1 of this project, the team applied computational fluid dynamics analysis to optimize the prototype burner’s aerodynamic, combustion, heat transfer, and emissions performance. In Phase 2, full-scale testing and refinement of two prototype burners were conducted in test furnaces at Zeeco’s offices in Broken Arrow, OK. These tests demonstrated that the full range of conventional and opportunity fuels could be utilized by the project’s burner while achieving robust flame stability and very low levels of

  20. Reduction of petroleum hydrocarbons and toxicity in refinery wastewater by bioremediation.

    Science.gov (United States)

    Płaza, Grazyna A; Jangid, Kamlesh; Lukasik, Krystyna; Nałecz-Jawecki, Grzegorz; Berry, Christopher J; Brigmon, Robin L

    2008-10-01

    The aim of the study was to investigate petroleum waste remediation and toxicity reduction by five bacterial strains: Ralstonia picketti SRS (BP-20), Alcaligenes piechaudii SRS (CZOR L-1B), Bacillus subtilis (I'-1a), Bacillus sp. (T-1), and Bacillus sp. (T'-1), previously isolated from petroleum-contaminated soils. Petroleum hydrocarbons were significantly degraded (91%) by the mixed bacterial cultures in 30 days (reaching up to 29% in the first 72 h). Similarly, the toxicity of the biodegraded petroleum waste decreased 3-fold after 30 days. This work shows the influence of bacteria on hydrocarbon degradation and associated toxicity, and its dependence on the specific microorganisms present. The ability of these mixed cultures to degrade hydrocarbons and reduce toxicity makes them candidates for environmental restoration applications at other hydrocarbon-contaminated environments.

  1. Environmental contaminants in the aquatic bird food chain of an oil refinery wastewater pond in Wyoming

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — Petroleum Hydrocarbons Based on higher PAH levels in sediment and vegetation, one would expect Pond 1 to pose a greater risk to wildlife than Pond 2. However, in...

  2. Waste-water Treatment Coupled with Biodiesel Production Using Microalgae: A Bio-refinery Approach

    NARCIS (Netherlands)

    Wijffels, R.H.

    2013-01-01

    Scarcity and non-renewable nature of petroleum based liquid fuels have made them an un-reliable source of energy. Excessive greenhouse gas emissions and the associated effects on global warming have become noteworthy environmental, economic and social threats. In this milieu, the development of rene

  3. Waste-water Treatment Coupled with Biodiesel Production Using Microalgae: A Bio-refinery Approach

    NARCIS (Netherlands)

    Wijffels, R.H.

    2013-01-01

    Scarcity and non-renewable nature of petroleum based liquid fuels have made them an un-reliable source of energy. Excessive greenhouse gas emissions and the associated effects on global warming have become noteworthy environmental, economic and social threats. In this milieu, the development of

  4. Trend of Mathematical Models in Microbial Fuel Cell for Environmental Energy Refinery from Waste/Water

    Science.gov (United States)

    Oh, Sung Taek

    A microbial fuel cell (MFC) is a device to use for bio electrochemical energy production. Electrophilic bacteria produce electrons in their metabolic pathway and the electrons can be extracted and concentrated on electrode by the electric potential difference (i.e. Galvanic cell). The bio-electrode may provide new opportunities for the renewable energy in waste water/swage treatment plants.

  5. Characterisation of wastewater for modelling of wastewater ...

    African Journals Online (AJOL)

    wastewater treatment plants receiving industrial effluent. FT Mhlanga* and ... The modelling of biological wastewater treatment systems has developed ..... of KwaZulu-Natal. ORHON D and CORGNOR EU (1996) COD fractionation in waste-.

  6. Wastewater treatment

    Directory of Open Access Journals (Sweden)

    Ranđel N. Kitanović

    2013-10-01

    Full Text Available Quality of life on Earth in the future will largely depend on the amount of safe water. As the most fundamental source of life, water is relentlessly consumed and polluted. To halt this trend, many countries are taking extensive measures and investing substantial resources in order to stop the contamination of water and return at least tolerably good water quality to nature. The goal of water purification is to obtain clean water with the sewage sludge as a by-product. Clean water is returned to nature, and further treatment of sludge may be subject to other procedures. The conclusion of this paper is simple. The procedure with purified water is easily achievable, purified water is discharged into rivers, lakes and seas, but the problem of further treatment of sludge remains. This paper presents the basic methods of wastewater treatment and procedures for processing the products from contaminated water. The paper can serve as a basis for further elaboration. Water Pollution In order to ensure normal life of living creatures, the water in which they live or the water they use must have a natural chemical composition and natural features. When, as a result of human activities, the chemical composition of water and the ratio of its chemical elements significantly change, we say that water is polluted. When the pollutants come from industrial plants, we are talking about industrial wastewater, and when they come from households and urban areas, we are talking about municipal wastewater. Both contain a huge amount of pollutants that eventually end up in rivers. Then, thousands of defenseless birds, fish and other animals suffer, and environmental consequences become immeasurable. In addition, the waste fed to the water often ends up in the bodies of marine animals, so they can return to us as food. Thermal water pollution also has multiple effects on the changes in the wildlife composition of aquatic ecosystems. Polluted water can be purified by

  7. Toxicological characteristics of refinery streams used to manufacture lubricating oils.

    Science.gov (United States)

    Kane, M L; Ladov, E N; Holdsworth, C E; Weaver, N K

    1984-01-01

    In the past, reports on the tumorigenic potential of lubricating oils in experimental animals have poorly defined the materials under study. In this paper the results of mouse skin painting studies with 46 clearly defined samples of refinery streams associated with lubricating oil processing show that modern conventional solvent refining of distillates removes tumorigenic potential while conventional acid refining may not. Furthermore, dewaxing, hydrofinishing, and clay treatments do not appear to mitigate the tumorigenicity of the lubricant distillates. Lubricant processing has changed over the years and assessments of the carcinogenicity of present-day lubricating materials must be based on knowledge of modern processing.

  8. High temperature degradation in power plants and refineries

    Directory of Open Access Journals (Sweden)

    Furtado Heloisa Cunha

    2004-01-01

    Full Text Available Thermal power plants and refineries around the world share many of the same problems, namely aging equipment, high costs of replacement, and the need to produce more efficiently while being increasingly concerned with issues of safety and reliability. For equipment operating at high temperature, there are many different mechanisms of degradation, some of which interact, and the rate of accumulation of damage is not simple to predict. The paper discusses the mechanisms of degradation at high temperature and methods of assessment of such damage and of the remaining safe life for operation.

  9. The roles of aromatics and catalytic reforming in the 2000+ refinery

    Energy Technology Data Exchange (ETDEWEB)

    Genis, O.; Simpson, S.G. [UOP Limited, Guildford (United Kingdom); Penner, D.W.; Gautam, R.; Glover, B.K. [UOPLLC, Des Plaines, IL (United Kingdom)

    2000-10-01

    Upcoming European environmental legislation will restrict the concentration of benzene and other aromatics in gasoline. Because catalytic reforming units are the major source of benzene and aromatics in gasoline as well as refinery hydrogen, the new fuel regulations have the potential to significantly affect refinery operation. The manner in which the new benzene and aromatics limits are met will be critical to refinery profitability and may change the availability of refinery-derived aromatics for petrochemical applications. This paper analyzes the refining and petrochemical market factors and technology options that will influence the way refiners and petrochemical producers respond to the new fuels legislation. Shortages of benzene, toluene, and xylenes (BTX) in Europe for petrochemical production will provide refiners with an outlet for excess gasoline benzene and aromatics and allow them to improve refinery profitability. Instead of turning down catalytic reforming units to meet gasoline aromatics limits, refiners can increase BTX production by using the proper feedstock and reforming catalysts, thereby improving refinery margins by helping to satisfy the petrochemical market demand for aromatics. Catalytic reforming will continue to be an important process unit in the 2000+ refinery not only for gasoline production but also for further linking of refinery and petrochemical operations. (orig.)

  10. 76 FR 64943 - Proposed Cercla Administrative Cost Recovery Settlement; ACM Smelter and Refinery Site, Located...

    Science.gov (United States)

    2011-10-19

    ... AGENCY Proposed Cercla Administrative Cost Recovery Settlement; ACM Smelter and Refinery Site, Located in... administrative settlement for recovery of past and projected future response costs concerning the ACM Smelter and...-5027. Comments should reference the ACM Smelter and Refinery NPL Site, the EPA Docket No....

  11. The Implementation and Maintenance of a Behavioral Safety Process in a Petroleum Refinery

    Science.gov (United States)

    Myers, Wanda V.; McSween, Terry E.; Medina, Rixio E.; Rost, Kristen; Alvero, Alicia M.

    2010-01-01

    A values-centered and team-based behavioral safety process was implemented in a petroleum oil refinery. Employee teams defined the refinery's safety values and related practices, which were used to guide the process design and implementation. The process included (a) a safety assessment; (b) the clarification of safety-related values and related…

  12. 77 FR 47429 - Agency Information Collection Activities; Petroleum Refineries in Foreign Trade Sub-zones

    Science.gov (United States)

    2012-08-08

    ... in Foreign Trade Sub-zones AGENCY: U.S. Customs and Border Protection (CBP), Department of Homeland... concerning the Petroleum Refineries in Foreign Trade Sub-zones. This request for comment is being made... Refineries in Foreign Trade Sub-zones. OMB Number: 1651-0063. Form Number: None. Abstract: The Foreign...

  13. 76 FR 42052 - National Emission Standards for Hazardous Air Pollutants From Petroleum Refineries

    Science.gov (United States)

    2011-07-18

    ... Petroleum Refineries AGENCY: Environmental Protection Agency (EPA). ACTION: Final rule; partial withdrawal... Petroleum Refineries. EPA is now providing final notice of the partial withdrawal. DATES: As of August 17... signed a final rule amending the National Emission Standards for Hazardous Air Pollutants From Petroleum...

  14. The Implementation and Maintenance of a Behavioral Safety Process in a Petroleum Refinery

    Science.gov (United States)

    Myers, Wanda V.; McSween, Terry E.; Medina, Rixio E.; Rost, Kristen; Alvero, Alicia M.

    2010-01-01

    A values-centered and team-based behavioral safety process was implemented in a petroleum oil refinery. Employee teams defined the refinery's safety values and related practices, which were used to guide the process design and implementation. The process included (a) a safety assessment; (b) the clarification of safety-related values and related…

  15. Sounding pollution and the refinery environmental risks; A poluicao sonora e os riscos ambientais das refinarias

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    This chapter gives a general overview on the effects of the sound pollution, the principal pollutants emitted by the oil refineries, control actions for the sound waves emissions, the minimization actions, the risk concepts and evaluation, the risk perception and the accidents in refineries.

  16. 臭氧技术在废水处理中的研究进展%Technology of Ozone Developments in the Research of Wastewater Treatment

    Institute of Scientific and Technical Information of China (English)

    李军; 刘清毅; 井良宵

    2014-01-01

    The technique of ozonation and combined treatment in the area of wastewater treatment is widelyapplicated, such as,tanker wastewater, aniline wastewater,refinery wastewater, pesticide wastewater,textile wastewater,dyeing wastewater, coke plant wastewater,phenolic compounds wastewater,steroid hormones, low-concentration organic wastewater, pharmaceutical wastewater, petrochemical wastewater, photographic waste water, waste seepage filtrate, micro-polluted source water and drinking waterand so on.There are some analysis and commentary to its application andresearch, andintroducedthe new progress of the technique of ozonation and combined treatmentinrecent years.%对臭氧技术在废水处理领域的文献迚行了跟踪研究,综述了臭氧及其联合处理技术在化工废水、农业废水、生活废水及其他生产废水等多个领域内的国内外技术研究现状和应用迚展。分析幵指出了臭氧在废水处理中存在的问题和今后的主要収展方向。

  17. Feasibility study report for the Imperial Valley Ethanol Refinery: a 14. 9-million-gallon-per-year ethanol synfuel refinery utilizing geothermal energy

    Energy Technology Data Exchange (ETDEWEB)

    1981-03-01

    The construction and operation of a 14,980,000 gallon per year fuel ethanol from grain refinery in the Imperial Valley of California is proposed. The Imperial Valley Ethanol Refinery (refinery) will use hot geothermal fluid from geothermal resources at the East Mesa area as the source of process energy. In order to evaluate the economic viability of the proposed Project, exhaustive engineering, cost analysis, and financial studies have been undertaken. This report presents the results of feasibility studies undertaken in geothermal resource, engineering, marketing financing, management, environment, and permits and approvals. The conclusion of these studies is that the Project is economically viable. US Alcohol Fuels is proceeding with its plans to construct and operate the Refinery.

  18. Conservation and reuse of water in Brazilian petroleum refineries; Conservacao e reuso de agua em refinarias de petroleo no Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Pombo, Felipe Ramalho; Magrini, Alessandra; Szklo, Alexandre Salem [Universidade Federal do Rio de Janeiro (PPE/COPPE/UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia. Programa de Planejamento Energetico], Emails: frpombo@ppe.ufrj.br, ale@ppe.ufrj.br, szklo@ppe.ufrj.br

    2010-07-01

    This paper views to present the main technologies for effluent treatment of petroleum refineries having as target the reuse. An analysis of international and Brazilian experiences of water reuse in petroleum refineries is performed viewing to support the proposition of recommendations for Brazilian refineries.

  19. Trends in oil discharged with aqueous effluents from oil refineries in Western Europe, 1993 survey

    Energy Technology Data Exchange (ETDEWEB)

    Dando, D.A.J.; Martin, D.E.

    1994-09-01

    This report summarizes the information gathered by CONCAWE in a survey of Western European oil refineries` effluent water quantity, oil content and treatment processes in 1993. It compares the 1993 data with the results of previous surveys and shows that the trend in the reduction of oil discharges continued, even though the reported refinery throughputs increased by more than 30% since the low point of 1984. The ratio of oil discharged to the amount of oil processed has continued to fall. Furthermore, when allowance is made for changes in the refineries which reported, it is apparent that there was a modest reduction of total effluent discharged in 1993, reinforcing the long-term trend. These two results indicate that overall management of water use in refineries and the efficiency of effluent purification continue to improve. The report indicates that around 85% of the refineries surveyed now include biological treatment in their waste water treatment facilities.

  20. Environmental performance of an innovative waste refinery based on enzymatic treatment

    DEFF Research Database (Denmark)

    Tonini, Davide; Astrup, Thomas

    2011-01-01

    ) from the waste. The waste refinery was compared to alternative treatments such as incineration, bioreactor landfill and mechanical-biological treatment followed by utilization of the RDF (refuse-derived fuel) for energy. The performance of the waste refinery turned out to be comparable...... for virgin material and saving fossil resources. In this paper a life-cycle assessment of a pilot-scale waste refinery for the enzymatic treatment of municipal solid waste (MSW) is presented. The refinery produced a liquid (liquefied organic materials and paper) and a solid fraction (non-degradable materials...... with incineration for most environmental categories. Landfilling turned out to be the worst option with respect to most categories (especially energy-related such as GW). The refinery treatment has large margins of improvement with respect to the environmental performance. These are mainly associated...

  1. Biodegradation of oil refinery wastes under OPA and CERCLA

    Energy Technology Data Exchange (ETDEWEB)

    Gamblin, W.W.; Banipal, B.S.; Myers, J.M. [Ecology and Environment, Inc., Dallas, TX (United States)] [and others

    1995-12-31

    Land treatment of oil refinery wastes has been used as a disposal method for decades. More recently, numerous laboratory studies have been performed attempting to quantify degradation rates of more toxic polycyclic aromatic hydrocarbon compounds (PAHs). This paper discusses the results of the fullscale aerobic biodegradation operations using land treatment at the Macmillan Ring-Free Oil refining facility. The tiered feasibility approach of evaluating biodegradation as a treatment method to achieve site-specific cleanup criteria, including pilot biodegradation operations, is discussed in an earlier paper. Analytical results of biodegradation indicate that degradation rates observed in the laboratory can be met and exceeded under field conditions and that site-specific cleanup criteria can be attained within a proposed project time. Also prevented are degradation rates and half-lives for PAHs for which cleanup criteria have been established. PAH degradation rates and half-life values are determined and compared with the laboratory degradation rates and half-life values which used similar oil refinery wastes by other in investigators (API 1987).

  2. A Novel Transporting System Model for Oil Refinery

    Directory of Open Access Journals (Sweden)

    Razman M. Tahar

    2010-01-01

    Full Text Available Problem statement: Oil refineries are widely used to store various liquids and gases. Petroleum products are in high demand. Oil companies have abundant resources of petroleum products in pipelines and storage tanks. Approach: Included are storage tanks at retail gasoline station, home heating oil tanks, lubricant storage at automotive service facilities, propane tanks in all sorts of application, and oil company terminals across the world. The aim of this study is to present a model by which a decision maker should be able to choose the optimal number of tanks, tank size and truck arrival rate to maximize average total profit per week for an oil terminal operation. Results: In this study, oil terminal modeled by using a discrete event simulation program Arena for AL-Dura refinery, Baghdad, Iraq. Multifactor variance analysis is used to determine different levels of the three factors and their interactions significantly affect the terminal profit including the optimal number of tanks, size of tanks and trucks of the arrival rate to maximize total revenue on average per week. Conclusion/Recommendations: The result showed minimum cost of oil at the terminal and tanker truck fill rates and price and income structure, also predict with 90% confidence levels, a number of factors, which gives highest average total income per week.

  3. Critical parameters for optimal biomass refineries: the case of biohydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Koukios, Emmanuel; Koullas, Dimitrios; Koukios, Irene Daouti; Avgerinos, Emmanouil [National Technical University of Athens, Bioresource Technology Unit, School of Chemical Engineering, Athens (Greece)

    2010-04-15

    The object of this paper is to identify and assess the elements taken from agro-industries and fossil hydrocarbon refineries, especially with respect to biomass logistics, fractionation kinetics, and process energetics. Such critical information will be of immediate use by policy and decision makers, especially in the early phase of planning and designing the first generation of biorefineries. Concerning feedstock logistics, biorefineries have a lot to learn from food and wood supply chains. This learning could lead to the deployment of complex, decentralised, stage-wise biorefining systems, consisting of local agro-refineries, regional biorefineries, where the primary plant fractions are processed and upgraded to useful intermediates, and central bioconversion units for the generation of market-grade biofuels, such as biohydrogen and other high value-added vectors. The kinetic aspects of biorefineries are related to the physico-chemical nature of the macromolecules. Finally, to solve the problem of the non-optimal energy transformations a tailored-up bioenergy plan is proposed for each biorefinery. The example of a wheat bran-based biorefinery, aiming at the production of biohydrogen will be used to illustrate the way ahead. (orig.)

  4. Wastewater treatment pilot

    OpenAIRE

    2016-01-01

    The aim of this thesis was to investigate the functionality of the wastewater treatment pilot and produce a learning manual-handout, as well as to define the parameters of wastewater clarification by studying the nutrient removal and the effluent clarification level of the processed wastewater. As part of the Environmental Engineering studies, Tampere University of Applied Sciences has invested on a Wastewater Treatment Pilot. The pilot simulates the basic wastewater treatment practices u...

  5. Thermophilic biological nitrogen removal in industrial wastewater treatment.

    Science.gov (United States)

    Lopez-Vazquez, C M; Kubare, M; Saroj, D P; Chikamba, C; Schwarz, J; Daims, H; Brdjanovic, D

    2014-01-01

    Nitrification is an integral part of biological nitrogen removal processes and usually the limiting step in wastewater treatment systems. Since nitrification is often considered not feasible at temperatures higher than 40 °C, warm industrial effluents (with operating temperatures higher than 40 °C) need to be cooled down prior to biological treatment, which increases the energy and operating costs of the plants for cooling purposes. This study describes the occurrence of thermophilic biological nitrogen removal activity (nitritation, nitratation, and denitrification) at a temperature as high as 50 °C in an activated sludge wastewater treatment plant treating wastewater from an oil refinery. Using a modified two-step nitrification-two-step denitrification mathematical model extended with the incorporation of double Arrhenius equations, the nitrification (nitrititation and nitratation) and denitrification activities were described including the cease in biomass activity at 55 °C. Fluorescence in situ hybridization (FISH) analyses revealed that Nitrosomonas halotolerant and obligatehalophilic and Nitrosomonas oligotropha (known ammonia-oxidizing organisms) and Nitrospira sublineage II (nitrite-oxidizing organism (NOB)) were observed using the FISH probes applied in this study. In particular, this is the first time that Nitrospira sublineage II, a moderatedly thermophilic NOB, is observed in an engineered full-scale (industrial) wastewater treatment system at temperatures as high as 50 °C. These observations suggest that thermophilic biological nitrogen removal can be attained in wastewater treatment systems, which may further contribute to the optimization of the biological nitrogen removal processes in wastewater treatment systems that treat warm wastewater streams.

  6. Environmental process for elimination of phenolic water present in refinery gasoline tanks; Processo ambiental para eliminacao de agua fenolica presente em tanques de gasolina de refinarias de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Correa Junior, Bentaci; Pedroso, Osmar V.; Furlan, Luis T. [PETROBRAS, SP (Brazil). Refinaria de Paulinia

    2004-07-01

    Gasoline production in petroleum refineries usually implies carrying high phenol contents in water after treatment systems. Phenols are powerful bactericides and, therefore, harmful to microorganisms present in wastewater treatment plants and in rivers. Due to this reason, usually controlled phenolic water drainage is performed, enabling gasoline quality improvement, without jeopardizing the biological treatment. Increase of phenolic contents in the effluent, due to operational disarray during the drainage of gasoline tanks may cause inhibition or even mortality of the existing microorganisms in the wastewater treatment plants. Aiming at changing the traditional treatment logic of environmental demands at the 'end of pipe', sending the phenolic water to the sour water treatment systems was proposed and implemented, which in turn, is reutilized by the latter in the crude desalination of the Distillation Units, where the phenols are reincorporated to the crude oil, preventing negative consequences to the wastewater treatment plant. The implemented process has demonstrated that premises were correct, enabling to implement process flows quite higher than drainage flows, what has meant productivity gains and environmental improvement. (author)

  7. Combined analysis of job and task benzene air exposures among workers at four US refinery operations.

    Science.gov (United States)

    Burns, Amanda; Shin, Jennifer Mi; Unice, Ken M; Gaffney, Shannon H; Kreider, Marisa L; Gelatt, Richard H; Panko, Julie M

    2017-03-01

    Workplace air samples analyzed for benzene at four US refineries from 1976 to 2007 were pooled into a single dataset to characterize similarities and differences between job titles, tasks and refineries, and to provide a robust dataset for exposure reconstruction. Approximately 12,000 non-task (>180 min) personal samples associated with 50 job titles and 4000 task (job titles and task codes across all four refineries, and (5) our analysis of variance (ANOVA) of the distribution of benzene air concentrations for select jobs/tasks across all four refineries. The jobs and tasks most frequently sampled included those with highest potential contact with refinery product streams containing benzene, which reflected the targeted sampling approach utilized by the facility industrial hygienists. Task and non-task data were analyzed to identify and account for significant differences within job-area, task-job, and task-area categories. This analysis demonstrated that in general, areas with benzene containing process streams were associated with greater benzene air concentrations compared to areas with process streams containing little to no benzene. For several job titles and tasks analyzed, there was a statistically significant decrease in benzene air concentration after 1990. This study provides a job and task-focused analysis of occupational exposure to benzene during refinery operations, and it should be useful for reconstructing refinery workers' exposures to benzene over the past 30 years.

  8. Hydrotreating Pyrolytic Lignin to Produce a Refinery Feedstock (Poster)

    Energy Technology Data Exchange (ETDEWEB)

    French, R. J.

    2013-09-01

    Fast pyrolysis of biomass followed by water separation to produce pyrolytic lignin and hydrotreating of the lignin could be used to produce a stable volatile low-oxygen intermediate liquid. Such a liquid could be converted into a finished motor-fuel in a refinery, taking advantage of the existing infrastructure and economies of scale of refineries. Hydrotreating just the lignin would consume less hydrogen while preserving about half of the energy of the original oil. The aqueous by-products could be reformed to produce the needed hydrogen and would contain much of the unwanted acids and unstable oxygenates. To assess such intermediate liquids, several pyrolytic lignins were prepared by mixing pyrolysis oil with water at 1:1 and 3:1 ratios. The carboxylic acidity in the pyrolytic lignin was reduced to 24 and 10 mg-KOH/g-lignin compared to 81 in the whole oil. These lignins were hydrotreated using Ni-Mo(S)/alumina, Pt/char, or Pd/C(activated) in a semi-batch 1 L stirred autoclave. The oil was stabilized under hydrogen at 150-280 degrees C, then water and light organics were removed by partial depressurization. Hydrodeoxygenation was then performed at 340-400 degrees C. Total pressure was controlled at 70 or 170 bar with hydrogen gas. Organic liquid yields of 39-56% were obtained. For many experiments the organic oxygen content was <7%, acidity was < 7 mg-KOH/g-oil, the volatility was greater than or equal to 94% and, on a carbon basis, the total yield of organic products miscible in hydrocarbons at a 1:10 ratio was over 50%. These properties are probably acceptable to a refinery.The residual liquids left in the reactor at the end of the experiment comprised 60-85% of the organic-phase product while the rest was condensate. 13C-NMR of the residual liquids showed that they were 50-80% aliphatic. 13C-NMR coupled with GC-MS identified phenolic compounds as the main oxygenates in most residual liquids.

  9. Shuttle Wastewater Solution Characterization

    Science.gov (United States)

    Adam, Niklas; Pham, Chau

    2011-01-01

    During the 31st shuttle mission to the International Space Station, STS-129, there was a clogging event in the shuttle wastewater tank. A routine wastewater dump was performed during the mission and before the dump was completed, degraded flow was observed. In order to complete the wastewater dump, flow had to be rerouted around the dump filter. As a result, a basic chemical and microbial investigation was performed to understand the shuttle wastewater system and perform mitigation tasks to prevent another blockage. Testing continued on the remaining shuttle flights wastewater and wastewater tank cleaning solutions. The results of the analyses and the effect of the mitigation steps are detailed in this paper.

  10. Petroleum Refinery Hydrogen Production Unit: Exergy and Production Cost Evaluation

    Directory of Open Access Journals (Sweden)

    Silvio de Oliveira Júnior

    2008-12-01

    Full Text Available Some specific processes are required to obtain pure hydrogen and the most usual one is natural gas reforming, where natural gas reacts with superheated steam producing H2, CO, CO2 and H2O. This paper presents the exergy and production costs evaluation of a complete hydrogen production unit of a petroleum refinery. The hydrogen production unit analysed in this paper has to supply 550,000 Nm3 of hydrogen per day to purify diesel oil. Based on a synthesis plant of the hydrogen production unit, the exergy efficiency of each component and of the overall plant are calculated. The hydrogen production cost is determined by means of a thermoeconomic analysis in which the equality cost partition method is employed, including capital and operational costs, in order to determine the production cost of hydrogen and other products of the plant.

  11. Refinery energy profile. Data collection: Task 2 report

    Energy Technology Data Exchange (ETDEWEB)

    Maier, R.W.; Olivent, W.P.; Brandt, D.L.; Golden, T.G.; Hanson, O.L.

    1978-04-01

    Under Task 2, the raw data to be used in developing the various energy balances which will make up the refinery energy profile were gathered and recorded on a unit by unit basis. Temperature, pressure, flow, and composition data for each stream flowing to or from a significant energy producer or consumer were gathered to the maximum extent possible using available instrumentation and additional instrumentation moved on site. The procedures used, the problems encountered, the unit time requirements, comments on the instrumentation used, and representative samples of the data collected are included in the report. Many methods and techniques were employed in gathering the data but no techniques are being recommended in this Task 2 Report. Recommendations will be made in the final report after the data have been evaluated and all profiles prepared.

  12. Removal of mercury from an alumina refinery aqueous stream.

    Science.gov (United States)

    Mullett, Mark; Tardio, James; Bhargava, Suresh; Dobbs, Charles

    2007-06-01

    Digestion condensate is formed as a by-product of the alumina refinery digestion process. The solution exhibits a high pH and is chemically reducing, containing many volatile species such as water, volatile organics, ammonia, and mercury. Because digestion condensate is chemically unique, an innovative approach was required to investigate mercury removal. The mercury capacity and adsorption kinetics were investigated using a number of materials including gold, silver and sulphur impregnated silica and a silver impregnated carbon. The results were compared to commercial sorbents, including extruded and powdered virgin activated carbons and a sulphur impregnated mineral. Nano-gold supported on silica (88% removal under batch conditions and 95% removal under flow conditions) and powdered activated carbon (91% under batch conditions and 98% removal under flow conditions) were the most effective materials investigated. The silver and sulphur impregnated materials were unstable in digestion condensate under the test conditions used.

  13. Utilization of Eucalyptus Oil Refineries Waste for Cement Particle Board

    Directory of Open Access Journals (Sweden)

    Rudi Setiadji

    2012-11-01

    Full Text Available Utilization of eucalyptus oil refinery waste in the manufacture of building material component of cement particle board is expected to reduce the price of housing units. This research used laboratory experimental methods, eucalyptus oil waste in the form of branches an twigs from eucalyptus tree. The variation of the testing were mixtures composition of the particle : cement, additives as accelerators, cold press load during manufacture of cement particle board. Cold press duration of cement board was 24 hours. The size of particle boards were (40 x 40 cm2 and 13 mm thick. The samples were tested for its density, water content, water absorption, flexural strength, thickness swelling, adhesion strength, and the nails pull out strength.

  14. 21世纪的炼油技术和炼油厂(2)%PETROLEUM REFINING TECHNIQUES AND REFINERIES IN 21ST CENTURY

    Institute of Scientific and Technical Information of China (English)

    姚国欣; 刘伯华

    2001-01-01

    Some quality indexes of gasoline and diesel in developedconturies,quality requirements of clean fuels and problems in production,upgrading of traditional techniques for petroleum refining as well as the new techniques to be commercialized in the 21st century were introduced.Prospects for refineries in the 21st century were introduced together with process diagrams of the super-clean gasoline refinery,super-clean diesel refinery,no sludge refinery and conventional natural gas refinery.

  15. In vitro and in vivo investigation of the genotoxic potential of waters from rivers under the influence of a petroleum refinery (São Paulo State - Brazil).

    Science.gov (United States)

    Hara, Raquel Vaz; Marin-Morales, Maria Aparecida

    2017-05-01

    In recent years concern about the chemical composition of wastewater generated by the oil refining industry has increased, even after its treatment. These wastewaters contain substances that can harm both the entire aquatic ecosystem and the health of any exposed organisms. The aim of this study was to evaluate the genotoxic and mutagenic potentials of the effluent generated by the largest Brazilian petroleum refinery, the effectiveness of the treatments used by the refinery, and whether its effluent can compromise the water quality of the river where it is discarded. Chromosomal aberration and micronucleus assays were performed in Allium cepa and micronucleus test in mammalian cell culture (CHO-K1). The samples were collected in three sites at the refinery: one site on the Jaguari River and two sites on the Atibaia Rivers (upstream and downstream of the discharged effluent), under three different climatic conditions. Tests with A. cepa showed increased frequencies of chromosomal aberrations and micronuclei in meristematic cells for the effluent after physico-chemical treatment, but the samples after treatment biological and stabilization pond presented none of these abnormalities. It was observed that the induced damage in the meristematic cells was not observed in the F1 cells of A. cepa roots. The micronucleus test performed with mammalian cell culture also indicated that the effluent, after physico-chemical treatment, induced a significant increase in micronucleus frequencies. Plant and hamster cells exposed to the other samples collected inside the refinery and in the Jaguari and Atibaia Rivers did not present evidence of genotoxicity and mutagenicity in the tests performed. This study showed that the effluent treated carried out by the refinery (biological treatment followed by a stabilization pond) proved to be efficient for the removal of the toxic load still present after the physico-chemical treatment, since no change in the quality of the Atibaia River

  16. Experimental and computational investigation of polyacrylonitrile ultrafiltration membrane for industrial oily wastewater treatment

    Energy Technology Data Exchange (ETDEWEB)

    Adib Hooman; Hassanajili, Shadi; Sheikhi-Kouhsar, Mohammad Reza [Shiraz University, Shiraz (Iran, Islamic Republic of); Salahi, Abdolhamid; Mohammadi, Toraj [Iran University of Science and Technology (IUST), Tehran (Iran, Islamic Republic of)

    2015-01-15

    An experimental study on separation of industrial oil from oily wastewater has been done. A polyacrylonitrile membrane with a molecular weight cut-off (MWCO) of 20 kDa was used and an outlet wastewater of API unit of Tehran refinery was employed. The main purpose of this study was to develop a support vector machine model for permeation flux decline and fouling resistance in a cross-flow hydrophilic polyacrylonitrile membrane during ultrafiltration. The operating conditions which have been applied to develop a support vector machine model were transmembrane pressure (TMP), operating temperature, cross flow velocity (CFV), pH values of oily wastewater, permeation flux decline and fouling resistance. The testing results obtained by the support vector machine models are in very good agreement with experimental data. The calculated squared correlation coefficients for permeation flux decline and fouling resistance were both 0.99. Based on the results, the support vector machine proved to be a reliable accurate estimation method.

  17. Paper 1: Wastewater characterisation

    African Journals Online (AJOL)

    drinie

    the suitability of the prefermented wastewater for downstream biological nutrient removal processes. The raw ... in the secondary treatment processes (BNRAS reactor), without ..... Wastewater and Activated Sludge from European Municipal.

  18. The use of mass flow meters in the PER+ refinery; PER+ verlegt grenzen van massaflowmeters

    Energy Technology Data Exchange (ETDEWEB)

    Dijkgraaf, A. [ed.

    1998-02-01

    An adjusted Coriolis mass flowmeter for 365C and 100 bar is applied in the new Shell refinery PER+ in Rotterdam, Netherlands. The flowmeter can handle the flow of liquid asphalt of which the composition and density can vary strongly

  19. Inefficiency of Malaysian palm oil refineries and the impact of different factors on its inefficiency

    Directory of Open Access Journals (Sweden)

    Zahra Shahverdi

    2015-09-01

    Full Text Available This study aimed to analyze changes in the inefficiency of Malaysian palm oil refineries using DEA window analysis method over the period 1996 to 2009. We investigated the effects of different factors on inefficiency of Malaysian palm oil refineries. Based on empirical results, the effect of all factors such as vertical integration, types of ownership, foreign investment, location, experience, and liberalization on inefficiency of refineries was significant. Experience, liberalization, and joint venture between private and public sectors showed an increase in efficiency, while joint venture between local and foreign investment and vertical integration increased refineries’ inefficiency. However, palm oil refineries which were located in the states of Sabah and Sarawak were less technically inefficient than those located in peninsular Malaysia.

  20. Implication of coastal refineries to the ecology of the Gulf of Kachchh

    Digital Repository Service at National Institute of Oceanography (India)

    Zingde, M.D.; Anand, N

    In order to meet the projected demand of petroleum products it is essential to establish additional refining capacities to process imported crude. Two grass root refineries with a combined capacity to process 24 MMTPA are proposed on the southern...

  1. Inhibition of β-galactosidase and α-glucosidase synthesis in petroleum refinery effluent bacteria by phenolic compounds

    Directory of Open Access Journals (Sweden)

    Gideon C. Okpokwasili

    2011-04-01

    Full Text Available Inhibition of α-glucosidase (EC 3.2.1.20 and β-galactosidase (EC 3.2.1.23 biosynthesis by phenolic compounds (phenol, 2-chlorophenol, 4-chlorophenol, 4-bromophenol and 3,5-dimethylphenol in Escherichia coli, Bacillus and Pseudomonas species isolated from petroleum refinery wastewater was assessed. At sufficient concentrations, phenols inhibited the induction of α-glucosidase and β-galactosidase. The patterns of these toxic effects can be mathematically described with logistic and sigmoid dose-response models. The median inhibitory concentrations (IC50 varied among the phenols, the bacteria and enzymes. Quantitative structure–activity relationship (QSAR models based on the logarithm of the octanol–water partition coefficient (log10Kow were developed for each bacterium. The correlation coefficients varied between 0.84and 0.99 for the enzymes. The test results indicated α-glucosidase and β-galactosidase biosynthesis as important microbial indices for evaluation of toxicity of phenolic compounds.

  2. Preliminary Discussion on the Construction and Development of Modern Refinery in China

    Institute of Scientific and Technical Information of China (English)

    Jiang Rongxing; Sun Lili; Li Zhiqiang

    2004-01-01

    Sustainable development of refinery is an important problem that refining industry faces in the 21st Century. The situation and challenges in front of refining industry are analyzed and illustrated by examples in this paper. It is also recognized that large-scale, clean, light-oriented and integrated refinery is the mode of development in future, and also an important measure for the sustainable development of petroleum resource.

  3. Mild Biomass Liquefaction Process for Economic Production of Stabilized Refinery-Ready Bio-oil

    Energy Technology Data Exchange (ETDEWEB)

    Gangwal, Santosh [Southern Research, Durham, NC (United States); Meng, Jiajia [Southern Research, Durham, NC (United States); McCabe, Kevin [Southern Research, Durham, NC (United States); Larson, Eric [Princeton Univ., NJ (United States). Princeton Environmental Inst.; Mastro, Kelly [Southern Research, Durham, NC (United States)

    2016-04-25

    Southern Research (SR) in cooperation with U.S. Department of Energy (DOE), Bioenergy Technology Office (BETO), investigated a biomass liquefaction process for economic production of stabilized refinery-ready bio-oil. The project was awarded by DOE under a Funding Opportunity Announcement (DE-FOA-0000686) for Bio-oil Stabilization and Commoditization that intended to evaluate the feasibility of using bio-oil as a potential feedstock in an existing petroleum refinery. SR investigated Topic Area 1 of the FOA at Technology Readiness Level 2-3 to develop thermochemical liquefaction technologies for producing a bio-oil feedstock from high-impact biomass that can be utilized within a petroleum refinery. Bio-oil obtained from fast pyrolysis of biomass is a green intermediate that can be further upgraded into a biofuel for blending in a petroleum refinery using a hydro-deoxygenation (HDO) route. Co-processing pyrolysis bio-oil in a petroleum refinery is an attractive approach to leverage the refinery’s existing capital. However, the petroleum industry is reluctant to accept pyrolysis bio-oil because of a lack of a standard definition for an acceptable bio-oil feedstock in existing refinery processes. Also per BETO’s multiyear program plan, fast pyrolysis-based bio-fuel is presently not cost competitive with petroleum-based transportation fuels. SR aims to develop and demonstrate a cost-effective low-severity thermal liquefaction and hydrodeoxygenation (HDO) process to convert woody biomass to stabilized bio-oils that can be directly blended with hydrotreater input streams in a petroleum refinery for production of gasoline and/or diesel range hydrocarbons. The specific project objectives are to demonstrate the processes at laboratory scale, characterize the bio-oil product and develop a plan in partnership with a refinery company to move the technology towards commercialization.

  4. Assuring Mechanical Integrity of Refinery Equipment Through Global ON-Stream Inspection

    Energy Technology Data Exchange (ETDEWEB)

    John W. Berthold

    2006-02-22

    The development of global on-stream inspection technology will have a dramatic effect on how refinery operations are managed in the U.S. in the future. Global on-stream inspection will provide assurance of the mechanical integrity of critical plant equipment and will allow refineries to operate more efficiently with less impact on our environment and with an increased margin of safety.

  5. Affordability analysis of lead emission controls for a smelter-refinery. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Scherer, T.M.

    1989-10-01

    This document evaluates the affordability and economic impact of additional control measures deemed necessary for a smelter-refinery to meet the lead emission standard. The emphasis in the analysis is on the impact of control costs on the smelter-refinery's profitability. The analysis was performed using control-cost data from two different lead-smelter studies in conjunction with other existing industry data.

  6. Petroleum Refinery Jobs and Economic Development Impact (JEDI) Model User Reference Guide

    Energy Technology Data Exchange (ETDEWEB)

    Goldberg, M.

    2013-12-31

    The Jobs and Economic Development Impact (JEDI) models, developed through the National Renewable Energy Laboratory (NREL), are user-friendly tools utilized to estimate the economic impacts at the local level of constructing and operating fuel and power generation projects for a range of conventional and renewable energy technologies. The JEDI Petroleum Refinery Model User Reference Guide was developed to assist users in employing and understanding the model. This guide provides information on the model's underlying methodology, as well as the parameters and references used to develop the cost data utilized in the model. This guide also provides basic instruction on model add-in features, operation of the model, and a discussion of how the results should be interpreted. Based on project-specific inputs from the user, the model estimates job creation, earning and output (total economic activity) for a given petroleum refinery. This includes the direct, indirect and induced economic impacts to the local economy associated with the refinery's construction and operation phases. Project cost and job data used in the model are derived from the most current cost estimations available. Local direct and indirect economic impacts are estimated using economic multipliers derived from IMPLAN software. By determining the regional economic impacts and job creation for a proposed refinery, the JEDI Petroleum Refinery model can be used to field questions about the added value refineries may bring to the local community.

  7. Opportunities and challenges at the interface between petrochemistry and refinery. The BASF perspective

    Energy Technology Data Exchange (ETDEWEB)

    Blankertz, H.J. [BASF AG, Ludwigshafen (Germany)

    2007-07-01

    The author of the contribution under consideration reports on the BASF perspective according to opportunities and challenges at the interface between petrochemistry and refinery. This contribution is divided into the following chapters: (a) Overview BASF-Group; (b) Overview BASF Petrochemicals; (c) The refinery-chemistry interface; (d) Main focus refineries; (e) Interface challenges and opportunities; (f) What can BASF do for refineries. BASF employs the Verbund concept, a system that combines production with energy needs in an intelligent way. The idea is to reduce of primary energy carriers both in terms of raw materials and for power and steam generation. The authors describes the petrochemicals of BASF AG (Ludwigshafen, Federal Republic of Germany), the raw material development, evolution of thermal steamcracking and crackerproducts. Major feedstock source of the European petrochemical industry are streams out of refineries which can't be used for transportation fuels. The gap between propylene demand and production out of steam crackers has to be closed by propylene out for FCC's. Demand for aromatics (xylenes and benzene, and to a lesser extent toluene) needs to be filled in by aromatics out of refineries. Market drivers for the refining industry are lowering crude costs, growing clean products, increasing capacity and enhancing E and P integration. BASF has various business with the oil und refining industry and provides solutions for oil field chemicals, process chemicals and performance additives. The author explains which kind of products and services BASF provides for refiners.

  8. Thermodynamics analysis of refinery sludge gasification in adiabatic updraft gasifier.

    Science.gov (United States)

    Ahmed, Reem; Sinnathambi, Chandra M; Eldmerdash, Usama; Subbarao, Duvvuri

    2014-01-01

    Limited information is available about the thermodynamic evaluation for biomass gasification process using updraft gasifier. Therefore, to minimize errors, the gasification of dry refinery sludge (DRS) is carried out in adiabatic system at atmospheric pressure under ambient air conditions. The objectives of this paper are to investigate the physical and chemical energy and exergy of product gas at different equivalent ratios (ER). It will also be used to determine whether the cold gas, exergy, and energy efficiencies of gases may be maximized by using secondary air injected to gasification zone under various ratios (0, 0.5, 1, and 1.5) at optimum ER of 0.195. From the results obtained, it is indicated that the chemical energy and exergy of producer gas are magnified by 5 and 10 times higher than their corresponding physical values, respectively. The cold gas, energy, and exergy efficiencies of DRS gasification are in the ranges of 22.9-55.5%, 43.7-72.4%, and 42.5-50.4%, respectively. Initially, all 3 efficiencies increase until they reach a maximum at the optimum ER of 0.195; thereafter, they decline with further increase in ER values. The injection of secondary air to gasification zone is also found to increase the cold gas, energy, and exergy efficiencies. A ratio of secondary air to primary air of 0.5 is found to be the optimum ratio for all 3 efficiencies to reach the maximum values.

  9. Thermodynamics Analysis of Refinery Sludge Gasification in Adiabatic Updraft Gasifier

    Directory of Open Access Journals (Sweden)

    Reem Ahmed

    2014-01-01

    Full Text Available Limited information is available about the thermodynamic evaluation for biomass gasification process using updraft gasifier. Therefore, to minimize errors, the gasification of dry refinery sludge (DRS is carried out in adiabatic system at atmospheric pressure under ambient air conditions. The objectives of this paper are to investigate the physical and chemical energy and exergy of product gas at different equivalent ratios (ER. It will also be used to determine whether the cold gas, exergy, and energy efficiencies of gases may be maximized by using secondary air injected to gasification zone under various ratios (0, 0.5, 1, and 1.5 at optimum ER of 0.195. From the results obtained, it is indicated that the chemical energy and exergy of producer gas are magnified by 5 and 10 times higher than their corresponding physical values, respectively. The cold gas, energy, and exergy efficiencies of DRS gasification are in the ranges of 22.9–55.5%, 43.7–72.4%, and 42.5–50.4%, respectively. Initially, all 3 efficiencies increase until they reach a maximum at the optimum ER of 0.195; thereafter, they decline with further increase in ER values. The injection of secondary air to gasification zone is also found to increase the cold gas, energy, and exergy efficiencies. A ratio of secondary air to primary air of 0.5 is found to be the optimum ratio for all 3 efficiencies to reach the maximum values.

  10. Regeneration and reuse waste from an edible oil refinery.

    Science.gov (United States)

    Boukerroui, Abdelhamid; Belhocine, Lydia; Ferroudj, Sonia

    2017-08-21

    A spent bleaching earth (SBE) from an edible oil refinery has been regenerated by thermal processing in oven, followed by washing with a cold solution of hydrochloric acid (1M). Optimal regeneration conditions have been controlled by decolorization tests of degummed and neutralized soybean oil. Optimal values of treatment (temperature 350°C, carbonization time 01 h, and HCl concentration 1M) gave a very efficient material. After bleaching oil by regenerated spent bleaching earth (RSBE), the chlorophyll-a and β-carotenes contained in crude edible oil and observed respectively at 430, 454, and 483 nm, value of λ max, are very much decreased. The results obtained after decolorization of edible oil by RSBE material indicate, that, during the process, the bleaching oil did not undergo any changes in the free fatty acid content. The peroxide value (PV) was reduced from 4.2 to 1.8 meq O2/kg, and the color has been improved (Lovibond color yellow/red: from 50/0.5 to 2.7/0.3, respectively). The RSBE material obtained was characterized by several techniques (FTIR, SEM). The results show that the heat treatment did not affect the mineral structure of RSBE, and the regenerated material recovered its porous structure.

  11. Recent approach to recycling business in Naoshima smelter and refinery

    Energy Technology Data Exchange (ETDEWEB)

    Komori, K.; Shimizu, T.; Usami, N.; Kaneda, A. [Mitsubishi Materials Corp., Tokyo (Japan)

    2007-07-01

    This paper described a recent retrofit conducted at the Naoshima Smelter and Refinery in Japan. Melting pretreatment and fly ash pretreatment plants for recycling industrial waste were installed as a result of recent recycling legislation in Japan. At the melting plant, mixed waste is sorted and incinerated under high temperatures. Melted slag and metal is then granulated by water, crushed, screened, and forwarded to a smelter to recover copper and other precious metals. Offgases are completely combusted in a secondary combustion chamber. Steam created by the waste boiler is used to generate electricity. The fly ash washing treatment plant was constructed to pretreat shredder residue and fly ash. The fly ash from the incinerating and melting plant is transported to a slurry tank where it is mixed with water in order to remove chlorine, sodium, and potassium. Leached fly ash is then filtered into a cake, which can then be treated in the smelter. Pretreated materials are also treated in a Mitsubishi continuous copper smelting and converting process line, which was installed to process waste residues that contained chlorine and tended to vary in size and shape. It was concluded that the installation of the process line has resulted in increased efficiency and reduced environmental impacts. 3 tabs., 8 figs.

  12. Thermodynamics Analysis of Refinery Sludge Gasification in Adiabatic Updraft Gasifier

    Science.gov (United States)

    Ahmed, Reem; Sinnathambi, Chandra M.; Eldmerdash, Usama; Subbarao, Duvvuri

    2014-01-01

    Limited information is available about the thermodynamic evaluation for biomass gasification process using updraft gasifier. Therefore, to minimize errors, the gasification of dry refinery sludge (DRS) is carried out in adiabatic system at atmospheric pressure under ambient air conditions. The objectives of this paper are to investigate the physical and chemical energy and exergy of product gas at different equivalent ratios (ER). It will also be used to determine whether the cold gas, exergy, and energy efficiencies of gases may be maximized by using secondary air injected to gasification zone under various ratios (0, 0.5, 1, and 1.5) at optimum ER of 0.195. From the results obtained, it is indicated that the chemical energy and exergy of producer gas are magnified by 5 and 10 times higher than their corresponding physical values, respectively. The cold gas, energy, and exergy efficiencies of DRS gasification are in the ranges of 22.9–55.5%, 43.7–72.4%, and 42.5–50.4%, respectively. Initially, all 3 efficiencies increase until they reach a maximum at the optimum ER of 0.195; thereafter, they decline with further increase in ER values. The injection of secondary air to gasification zone is also found to increase the cold gas, energy, and exergy efficiencies. A ratio of secondary air to primary air of 0.5 is found to be the optimum ratio for all 3 efficiencies to reach the maximum values. PMID:24672368

  13. Towards effective waste management. Knowledge centre Waste Refinery Activity Report 2007-2009; Mot effektivare avfallshantering. Kunskapscentrum Waste Refinery Verksamhetsrapport 2007-2009

    Energy Technology Data Exchange (ETDEWEB)

    2011-07-01

    This report aims to provide a comprehensive picture of the areas that have been discussed and developed during the knowledge centre Waste Refinery first three years. Details and depth analyzes of each area are contained in project reports, which can be downloaded free of charge through our website www.wasterefinery.se

  14. Assessing the Methane Emissions from Natural Gas-Fired Power Plants and Oil Refineries.

    Science.gov (United States)

    Lavoie, Tegan N; Shepson, Paul B; Gore, Chloe A; Stirm, Brian H; Kaeser, Robert; Wulle, Bernard; Lyon, David; Rudek, Joseph

    2017-03-21

    Presently, there is high uncertainty in estimates of methane (CH4) emissions from natural gas-fired power plants (NGPP) and oil refineries, two major end users of natural gas. Therefore, we measured CH4 and CO2 emissions at three NGPPs and three refineries using an aircraft-based mass balance technique. Average CH4 emission rates (NGPPs: 140 ± 70 kg/h; refineries: 580 ± 220 kg/h, 95% CL) were larger than facility-reported estimates by factors of 21-120 (NGPPs) and 11-90 (refineries). At NGPPs, the percentage of unburned CH4 emitted from stacks (0.01-0.14%) was much lower than respective facility-scale losses (0.10-0.42%), and CH4 emissions from both NGPPs and refineries were more strongly correlated with enhanced H2O concentrations (R(2)avg = 0.65) than with CO2 (R(2)avg = 0.21), suggesting noncombustion-related equipment as potential CH4 sources. Additionally, calculated throughput-based emission factors (EF) derived from the NGPP measurements made in this study were, on average, a factor of 4.4 (stacks) and 42 (facility-scale) larger than industry-used EFs. Subsequently, throughput-based EFs for both the NGPPs and refineries were used to estimate total U.S. emissions from these facility-types. Results indicate that NGPPs and oil refineries may be large sources of CH4 emissions and could contribute significantly (0.61 ± 0.18 Tg CH4/yr, 95% CL) to U.S. emissions.

  15. Energy efficiency and greenhouse gas emission intensity of petroleum products at U.S. refineries.

    Science.gov (United States)

    Elgowainy, Amgad; Han, Jeongwoo; Cai, Hao; Wang, Michael; Forman, Grant S; DiVita, Vincent B

    2014-07-01

    This paper describes the development of (1) a formula correlating the variation in overall refinery energy efficiency with crude quality, refinery complexity, and product slate; and (2) a methodology for calculating energy and greenhouse gas (GHG) emission intensities and processing fuel shares of major U.S. refinery products. Overall refinery energy efficiency is the ratio of the energy present in all product streams divided by the energy in all input streams. Using linear programming (LP) modeling of the various refinery processing units, we analyzed 43 refineries that process 70% of total crude input to U.S. refineries and cover the largest four Petroleum Administration for Defense District (PADD) regions (I, II, III, V). Based on the allocation of process energy among products at the process unit level, the weighted-average product-specific energy efficiencies (and ranges) are estimated to be 88.6% (86.2%-91.2%) for gasoline, 90.9% (84.8%-94.5%) for diesel, 95.3% (93.0%-97.5%) for jet fuel, 94.5% (91.6%-96.2%) for residual fuel oil (RFO), and 90.8% (88.0%-94.3%) for liquefied petroleum gas (LPG). The corresponding weighted-average, production GHG emission intensities (and ranges) (in grams of carbon dioxide-equivalent (CO2e) per megajoule (MJ)) are estimated to be 7.8 (6.2-9.8) for gasoline, 4.9 (2.7-9.9) for diesel, 2.3 (0.9-4.4) for jet fuel, 3.4 (1.5-6.9) for RFO, and 6.6 (4.3-9.2) for LPG. The findings of this study are key components of the life-cycle assessment of GHG emissions associated with various petroleum fuels; such assessment is the centerpiece of legislation developed and promulgated by government agencies in the United States and abroad to reduce GHG emissions and abate global warming.

  16. TRACKING SUBSTRATE TRAJECTORIES IN CONTINUOUS AEROBIC WASTEWATER REACTORS VIA NONLINEAR PI CONTROLLERS

    Directory of Open Access Journals (Sweden)

    Aguilar-Lopez, R

    2006-04-01

    Full Text Available This work addresses the problem of robust tracking of the substrate concentration in a continuous bioreactor in anindustrial wastewater treatment plant of an oil refinery. The entire nonlinear operating region of the process wasapproached by several linear models. The suggested global controller is designed considering an average betweenthe linear single controllers designed for each operating region. The averaging methodology is conducted viainterpolation, considering Gaussian distributions as the interpolating functions. The robust properties of the globalcontroller are shown by employing a Lyapunov function. The corresponding performance of the proposedmethodology is illustrated via numerical simulations.

  17. Nitrification in Saline Industrial Wastewater

    NARCIS (Netherlands)

    Moussa, M.S.

    2004-01-01

    Biological nitrogen removal is widely and successfully applied for municipal wastewater. However, these experiences are not directly applicable to industrial wastewater, due to its specific composition. High salt levels in many industrial wastewaters affect nitrification negatively and improved unde

  18. Nitrification in Saline Industrial Wastewater

    NARCIS (Netherlands)

    Moussa, M.S.

    2004-01-01

    Biological nitrogen removal is widely and successfully applied for municipal wastewater. However, these experiences are not directly applicable to industrial wastewater, due to its specific composition. High salt levels in many industrial wastewaters affect nitrification negatively and improved

  19. Feasibility of flare gas reformation to practical energy in Farashband gas refinery: no gas flaring.

    Science.gov (United States)

    Rahimpour, Mohammad Reaza; Jokar, Seyyed Mohammad

    2012-03-30

    A suggested method for controlling the level of hazardous materials in the atmosphere is prevention of combustion in flare. In this work, three methods are proposed to recover flare gas instead of conventional gas-burning in flare at the Farashband gas refinery. These methods aim to minimize environmental and economical disadvantages of burning flare gas. The proposed methods are: (1) gas to liquid (GTL) production, (2) electricity generation with a gas turbine and, (3) compression and injection into the refinery pipelines. To find the most suitable method, the refinery units that send gas to the flare as well as the required equipment for the three aforementioned methods are simulated. These simulations determine the amount of flare gas, the number of GTL barrels, the power generated by the gas turbine and the required compression horsepower. The results of simulation show that 563 barrels/day of valuable GTL products is produced by the first method. The second method provides 25 MW electricity and the third method provides a compressed natural gas with 129 bar pressure for injection to the refinery pipelines. In addition, the economics of flare gas recovery methods are studied and compared. The results show that for the 4.176MMSCFD of gas flared from the Farashband gas refinery, the electricity production gives the highest rate of return (ROR), the lowest payback period, the highest annual profit and mild capital investment. Therefore, the electricity production is the superior method economically. Copyright © 2012 Elsevier B.V. All rights reserved.

  20. Identification of the odour and chemical composition of alumina refinery air emissions.

    Science.gov (United States)

    Coffey, P S; Ioppolo-Armanios, M

    2004-01-01

    Alcoa World Alumina Australia has undertaken comprehensive air emissions monitoring aimed at characterising and quantifying the complete range of emissions to the atmosphere from Bayer refining of alumina at its Western Australian refineries. To the best of our knowledge, this project represents the most complete air emissions inventory of a Bayer refinery conducted in the worldwide alumina industry. It adds considerably to knowledge of air emission factors available for use in emissions estimation required under national pollutant release and transfer registers (NPRTs), such as the Toxic Releases Inventory, USA, and the National Pollutant Inventory, Australia. It also allows the preliminary identification of the key chemical components responsible for characteristic alumina refinery odours and the contribution of these components to the quality, or hedonic tone, of the odours. The strength and acceptability of refinery odours to employees and neighbours appears to be dependent upon where and in what proportion the odorous gases have been emitted from the refineries. This paper presents the results of the programme and develops a basis for classifying the odour properties of the key emission sources in the alumina-refining process.

  1. Reducing refinery CO2 emissions through amine solvent upgrade and optimization

    Energy Technology Data Exchange (ETDEWEB)

    Alonso, Thiago V.; Valenzuela, Michelle [The Dow Chemical Company, Midland, MI (United States)

    2012-07-01

    Regional initiatives are underway to reduce and limit the emissions of greenhouse gases. With CO2 emissions making up over 80% of the greenhouse gases, cap-and-trade programs will focus on those industries that consume the most energy. Refineries are among the top energy consumers and are seeking opportunities to reduce usage. With tightening margins, energy management programs will not only help refineries meet CO{sub 2} emission regulations, but can also provide a competitive advantage. With the trend towards heavier and higher sulfur containing crudes, refineries are increasing processing capabilities, which can include capital-intensive projects and additional energy consumption. Energy conservation plans should include optimization of these processes. One area to consider includes the acid gas removal systems in refineries. Through the selection and use of optimal solvents and implementation of energy efficiency techniques, which require minimal capital investment and expenditures, refineries can reduce energy usage, overall CO{sub 2} emissions, and total cost in acid gas systems. This paper will discuss these approaches and share case studies detailing the implementation and results. (author)

  2. Predicting refinery effluent toxicity on the basis of hydrocarbon composition determined by GCxGC analysis

    Energy Technology Data Exchange (ETDEWEB)

    Whale, G. [and others

    2013-04-15

    A high resolution analytical method for determining hydrocarbon blocks in petroleum products by comprehensive two-dimensional gas chromatography (GCxGC) was used for the analysis of petroleum hydrocarbons extracted from refinery effluents. From 105 CONCAWE refineries in Europe 111 refinery effluents were collected in the period June 2008 to March 2009 (CONCAWE, 2010). The effluents were analysed for metals, standard effluent parameters (including Chemical Oxygen Demand (COD), Biochemical Oxygen Demand (BOD), oil in water (OiW), GCxGC speciated hydrocarbons, BTEX (Benzene, Toluene, Ethylbenzene, and Xylenes) and volatile organic compounds. This report describes the subsequent analysis of the GCxGC data, as described in hydrocarbon blocks, and uses the PETROTOX model, to predict the environmental toxicity (i.e. ecotoxicity) of the discharged effluents. A further analysis was undertaken to address the potential environmental impact of these predicted effects initially using default dilution factors and then,when necessary site specific factors. The report describes all the methods used to arrive at the predictions, and shows that for the majority of refinery effluents direct toxicity effects in the effluents are not anticipated. Furthermore, when applying either the EU Risk Assessment Technical Guidance Document (TGD) default dilution factors or site specific dilution factors, none of the refineries are predicted to exerting either acute or chronic toxicity to organisms in the receiving aquatic environment, based on their hydrocarbon composition present in the effluent samples.

  3. FEASIBILITY STUDY FOR A PETROLEUM REFINERY FOR THE JICARILLA APACHE TRIBE

    Energy Technology Data Exchange (ETDEWEB)

    John D. Jones

    2004-10-01

    A feasibility study for a proposed petroleum refinery for the Jicarilla Apache Indian Reservation was performed. The available crude oil production was identified and characterized. There is 6,000 barrels per day of crude oil production available for processing in the proposed refinery. The proposed refinery will utilize a lower temperature, smaller crude fractionation unit. It will have a Naphtha Hydrodesulfurizer and Reformer to produce high octane gasoline. The surplus hydrogen from the reformer will be used in a specialized hydrocracker to convert the heavier crude oil fractions to ultra low sulfur gasoline and diesel fuel products. The proposed refinery will produce gasoline, jet fuel, diesel fuel, and a minimal amount of lube oil. The refinery will require about $86,700,000 to construct. It will have net annual pre-tax profit of about $17,000,000. The estimated return on investment is 20%. The feasibility is positive subject to confirmation of long term crude supply. The study also identified procedures for evaluating processing options as a means for American Indian Tribes and Native American Corporations to maximize the value of their crude oil production.

  4. Wastewater Industrial Contributors

    Data.gov (United States)

    Iowa State University GIS Support and Research Facility — Industrial contributors to municipal wastewater treatment facilities in Iowa for the National Pollutant Discharge Elimination System (NPDES) program.

  5. Characterization of oily sludge from a Tehran oil refinery.

    Science.gov (United States)

    Heidarzadeh, Nima; Gitipour, Saeid; Abdoli, Mohammad Ali

    2010-10-01

    In this study, oily sludge samples generated from a Tehran oil refinery (Pond I) were evaluated for their contamination levels and to propose an adequate remediation technique for the wastes. A simple, random, sampling method was used to collect the samples. The samples were analyzed to measure Total petroleum hydrocarbon (TPH), polyaromatic hydrocarbon (PAH) and heavy metal concentrations in the sludge. Statistical analysis showed that seven samples were adequate to assess the sludge with respect to TPH analyses. The mean concentration of TPHs in the samples was 265,600 mg kg⁻¹. A composite sample prepared from a mix of the seven samples was used to determine the sludge's additional characteristics. Composite sample analysis showed that there were no detectable amounts of PAHs in the sludge. In addition, mean concentrations of the selected heavy metals Ni, Pb, Cd and Zn were 2700, 850, 100, 6100 mg kg⁻¹, respectively. To assess the sludge contamination level, the results from the analysis above were compared with soil clean-up levels. Due to a lack of national standards for soil clean-up levels in Iran, sludge pollutant concentrations were compared with standards set in developed countries. According to these standards, the sludge was highly polluted with petroleum hydrocarbons. The results indicated that incineration, biological treatment and solidification/stabilization treatments would be the most appropriate methods for treatment of the sludges. In the case of solidification/stabilization, due to the high organic content of the sludge, it is recommended to use organophilic clays prior to treatment of the wastes.

  6. Biorefineries: Relocating Biomass Refineries to the Rural Area

    Directory of Open Access Journals (Sweden)

    Franka Papendiek

    2012-07-01

    Full Text Available The field for application of biomass is rising. The demand for food and feeding stuff rises while at the same time energy, chemicals and other materials also need to be produced from biomass because of decreasing fossil resources. However, the biorefinery ideas and concepts can help to use the limited renewable raw materials more efficiently than today. With biorefineries, valuable products, such as platform chemicals, can be produced from agricultural feedstock, which can subsequently be further processed into a variety of substances by the chemical industry. Due to the role they play as producers of biomass, rural areas will grow in importance in the decades to come. Parts of the biorefinery process can be relocated to the rural areas to bring a high added value to these regions. By refining biomass at the place of production, new economic opportunities may arise for agriculturists, and the industry gets high-grade pre-products. Additionally, an on-farm refining can increase the quality of the products because of the instant processing. To reduce competition with the food production and to find new possibilities of utilisation for these habitats, the focus for new agricultural biomass should be on grasslands. But also croplands can provide more renewable raw materials without endangering a sustainable agriculture, e.g. by implementing legumes in the crop rotation. To decide if a region can provide adequate amounts of raw material for a biorefinery, new raw material assessment procedures have to be developed. In doing so, involvement of farmers is inevitable to generate a reliable study of the biomass refinery potentials.

  7. Emergency Response Program Designing Based On Case Study ERP Regulations In Ilam Gas Refinery

    Directory of Open Access Journals (Sweden)

    Mehdi Tahmasbi

    2015-08-01

    Full Text Available The study of Emergency response plan designing is one of the most important prevention approaches in crisis management. This study aims to design emergency response plan based on case study ERP regulations in Ilam gas refinery. On the basis of risk assessment and identification techniques such as HAZOP and FMEA in Ilam gas refinery the risks have been prioritized and then according to this prioritization the design of possible scenarios which have the highest rate of occurrence and the highest level of damage has been separated. Possible scenarios were simulated with PHAST software. Then emergency response program has been designed for the special mode or similar cases. According to the internal emergency response plan for Ilam gas refinery and predictable conditions of the process special instructions should be considered at the time of the incident to suffer the least damage on people and environment in the shortest time possible.

  8. Biological remediation of petroleum hydrocarbons from a refinery's soil : comparison of different technologies

    Energy Technology Data Exchange (ETDEWEB)

    Nazare Couto, M.; Vasconcelos, T.S.D. [CIMAR/CIIMAR, Porto (Portugal)

    2007-07-01

    This presentation discussed bioremediation methods used at a refinery in Portugal with a high distillation capacity. The aim of the project was to develop a method for restoring contaminated sites using rhizoremediation and bio-augmentation. Hydrocarbon molecules were tightly sorbed to the soil particles at the refinery. Plants used in the bioremediation project included Scirpus maritimus and Juncus maritimus, as well as Cortoaderia selloana taken from an estuary near the refinery. Tests were conducted both with, and without the use of microorganisms. Commercial bio-augmentation products were used. Plant growth was evaluated for a period of 64 days. It was concluded that the technology is cheaper than many traditional methods of treating hydrocarbon-contaminated soils. tabs., figs.

  9. 77 FR 44685 - ConocoPhillips Company, Trainer Refinery, Including On-Site Leased Workers From Shrack, Young...

    Science.gov (United States)

    2012-07-30

    ... Employment and Training Administration ConocoPhillips Company, Trainer Refinery, Including On-Site Leased Workers From Shrack, Young, and Associates, Inc., and Project Control Associates, Trainer, PA; Notice of... of ConocoPhillips Company, Trainer Refinery, Trainer, Pennsylvania (subject firm). The subject...

  10. Mechanism of removal of undesirable residual amylase, insoluble starch, and select colorants from refinery streams by powdered activated carbons

    Science.gov (United States)

    There is a need in the world-wide sugar industry to find a practical and economical solution to remove or inactivate residual alpha-amylase that are high temperature stable from factory or refinery streams. A survey of refineries that used amylase and had activated carbon systems for decolorization,...

  11. 40 CFR 80.205 - How is the annual refinery or importer average and corporate pool average sulfur level determined?

    Science.gov (United States)

    2010-07-01

    ... average and corporate pool average sulfur level determined? 80.205 Section 80.205 Protection of... ADDITIVES Gasoline Sulfur Gasoline Sulfur Standards § 80.205 How is the annual refinery or importer average and corporate pool average sulfur level determined? (a) The annual refinery or importer average...

  12. Cleaner shipping. Trade off between air pollution, costs and refinery CO2 emissions

    Energy Technology Data Exchange (ETDEWEB)

    De Wilde, H.P.J.; Kroon, P. [ECN Policy Studies, Petten (Netherlands)

    2008-05-15

    Still subject to final approval in October 2008, the International Maritime Organisation (IMO) agreed on a maximum sulphur content of 0.5% for shipping fuels in 2020. This target will induce major changes in the global refinery industry. We have estimated the impact on the Dutch refinery industry, which annually produces about 8 million tons of heavy fuel oil for sea shipping, with refinery residues as main component. It is technically possible to convert all residues, although this process will cause an additional energy use of about one million tons of crude oil and a related CO2 emission of about 4 million tons. The investment costs for these major changes in the Dutch refinery industry are estimated at about 1.5 tot 2 billion euros. The recent IMO agreement enables a gradual introduction of cleaner shipping fuels, which will reduce market disruptions and peak prices. Nevertheless, Rotterdam may not necessarily be able to develop a similar position in import, export and bunkering of future low sulphur fuels, compared to its present strong position in the market of heavy marine bunkers. Extrapolation of our national study to the global scale suggests that the deep conversion of 350 million tons of heavy fuel oil for shipping would require refinery investments in the order of 70-100 billion euros. The associated CO2 emissions would amount up to 175 Mton. The net additional CO2 emission, however, would be smaller since lighter shipping fuels result in less CO2 emissions at sea. On balance, we expect that the improvements in fuel economy, driven by the expensive low-carbon shipping fuels, will decrease CO2 emissions more than the increase in CO2 emissions from additional desulphurization in the refineries. Nevertheless CO2 emissions from sea shipping will continue to increase since marine transport is rapidly growing.

  13. U.S. refinery efficiency: impacts analysis and implications for fuel carbon policy implementation.

    Science.gov (United States)

    Forman, Grant S; Divita, Vincent B; Han, Jeongwoo; Cai, Hao; Elgowainy, Amgad; Wang, Michael

    2014-07-01

    In the next two decades, the U.S. refining industry will face significant changes resulting from a rapidly evolving domestic petroleum energy landscape. The rapid influx of domestically sourced tight light oil and relative demand shifts for gasoline and diesel will impose challenges on the ability of the U.S. refining industry to satisfy both demand and quality requirements. This study uses results from Linear Programming (LP) modeling data to examine the potential impacts of these changes on refinery, process unit, and product-specific efficiencies, focusing on current baseline efficiency values across 43 existing large U.S. refineries that are operating today. These results suggest that refinery and product-specific efficiency values are sensitive to crude quality, seasonal and regional factors, and refinery configuration and complexity, which are determined by final fuel specification requirements. Additional processing of domestically sourced tight light oil could marginally increase refinery efficiency, but these benefits could be offset by crude rebalancing. The dynamic relationship between efficiency and key parameters such as crude API gravity, sulfur content, heavy products, residual upgrading, and complexity are key to understanding possible future changes in refinery efficiency. Relative to gasoline, the efficiency of diesel production is highly variable, and is influenced by the number and severity of units required to produce diesel. To respond to future demand requirements, refiners will need to reduce the gasoline/diesel (G/D) production ratio, which will likely result in greater volumes of diesel being produced through less efficient pathways resulting in reduced efficiency, particularly on the marginal barrel of diesel. This decline in diesel efficiency could be offset by blending of Gas to Liquids (GTL) diesel, which could allow refiners to uplift intermediate fuel streams into more efficient diesel production pathways, thereby allowing for the

  14. FUZZY MODELING APPLICATION OF FLUID CATALYTIC CRACKING UNIT (FCCU OF A PETROLEUM REFINERY (TÜPRAŞ

    Directory of Open Access Journals (Sweden)

    Mithat ZEYDAN

    2004-01-01

    Full Text Available In this study, fuzzy modeling of FCCU in the refinery system as the most important part of Petrochemical Industry was carried out. FCCU is the most important unit in the refinery system as it is a higly nonlinear system with MIMO (Multi input-multi output, internal feedback, strongly coupling, time-varying, distributed parameter, significantly uncertain behaviours in nature. Mathematical Models is not enough to identify this system. On the occasion of this, FCCU has a characteristic specifications as a subject of Fuzzy Logic.

  15. Characteristics of grey wastewater

    DEFF Research Database (Denmark)

    Eriksson, Eva; Auffarth, Karina Pipaluk Solvejg; Henze, Mogens

    2002-01-01

    The composition of grey wastewater depends on sources and installations from where the water is drawn, e.g. kitchen, bathroom or laundry. The chemical compounds present originate from household chemicals, cooking, washing and the piping. In general grey wastewater contains lower levels of organic...

  16. APPLICATIONS OF LAYERED DOUBLE HYDROXIDES IN REMOVING OXYANIONS FROM OIL REFINING AND COAL MINING WASTEWATER

    Energy Technology Data Exchange (ETDEWEB)

    Song Jin; Paul Fallgren

    2006-03-01

    Western Research Institute (WRI), in conjunction with the U.S. Department of Energy (DOE), conducted a study of using the layered double hydroxides (LDH) as filter material to remove microorganisms, large biological molecules, certain anions and toxic oxyanions from various waste streams, including wastewater from refineries. Results demonstrate that LDH has a high adsorbing capability to those compounds with negative surface charge. Constituents studied include model bacteria, viruses, arsenic, selenium, vanadium, diesel range hydrocarbons, methyl tert-butyl ether (MTBE), mixed petroleum constituents, humic materials and anions. This project also attempted to modify the physical structure of LDH for the application as a filtration material. Flow characterizations of the modified LDH materials were also investigated. Results to date indicate that LDH is a cost-effective new material to be used for wastewater treatment, especially for the treatment of anions and oxyanions.

  17. A Typical Case Study: Solid Waste Management in Petroleum Refineries

    Directory of Open Access Journals (Sweden)

    Jadea S. Alshammari

    2008-01-01

    Full Text Available The current environmental concerns have forced developed and developing countries to reduce air, water and land pollution for sustainable growth. Solid refinery waste is cocktail of hydrocarbons, water, heavy metal and fine solids and is substantial in quantity. The principal processes of waste management focus mainly on waste source reduction, reusing, recycling, composting, incineration with or without energy recovery, fuel production and land filling. Waste management models have a common approach of assignment of generating sources to landfills, transfer stations sitting, site selection for landfills, etc. but recently new integrated models have been developed and applied. Waste management system in an industrial complexes uses multi-objective mixed integer programming approach for the running of existing facilities in dynamic net work flow models with nonlinear costs of management. The latest multi-objective mixed integer programming techniques are applied to resolve the potential conflict between environmental and economic goals and to evaluate sustainable strategies for waste management. In this approach, material recycling in an economic sense exhibits huge indirect benefits, although the emphasis of environmental quality as a major objective in decision-making drives the optimal solution toward pro-recycling programs. The use of grey and fuzzy system theories as uncertainty analysis tools as an enhancement of this modeling analysis proves to be highly profitable. A multi-objective optimization model based on the goal programming approach has been developed and tested in this study for passable management of solid waste generated by a typical petroleum refining industry in the state of Kuwait. The analytic hierarchy process, a decision-making approach, including qualitative and quantitative aspects of a problem, has been integrated in the model to prioritize the conflicting goals existing in the waste management problems of the petroleum

  18. Trends in desulfurization capabilities, processing technologies, and the availability of crude oils: U. S. refineries; Caribbean ''exporting'' refineries

    Energy Technology Data Exchange (ETDEWEB)

    Peer, E. L.; Marsik, F. V.

    1977-12-01

    A review of all U.S. refineries and their downstream equipment has led to the conclusion that slightly more than 40 percent of the existing capacity can handle some sour crude of one type or another. For various reasons, this cannot be an exactly defined number, nor does it coincide with the percent of hydroprocessing equipment in relation to crude capacity. A few refineries have hydrotreating facilities and yet only have sweet crude capability. A few refiners may only have capability to handle sour crudes in the lower sulfur ranges, say 0.5 to 1.0 percent, due to emissions problems or other limitations. These are limitations which can be overcome by investments. Still others would face problems in their product output pattern due to low gravity of some sour crudes. Catalytic hydroprocessing (hydrocracking, hydrorefining, and hydrotreating) removes sulfur from refinery streams so that the total amount of sulfur in the products and residues is less than that in the crude oil feedstock. For this reason, changes in hydroprocessing capacity are used to express the changing capabilities of refiners to process sour crudes. On the other hand, thermal processes (vacuum distillation, visbreaking, and coking), segregate most of the sulfur contained in the refinery feedstocks into residual fractions, allowing the production of low sulfur containing products, but the total amount of sulfur in the products and in the residual fractions is essentially the same as that in the crude oil feedstocks. In this regard, thermal processes are limited in their ability to produce low-sulfur products.

  19. Pyrolysis oil upgrading for Co-processing in standard refinery units

    NARCIS (Netherlands)

    De Miguel Mercader, Ferran

    2010-01-01

    This thesis considers the route that comprises the upgrading of pyrolysis oil (produced from lingo-cellulosic biomass) and its further co-processing in standard refineries to produce transportation fuels. In the present concept, pyrolysis oil is produced where biomass is available and then transport

  20. MIGREYD Modular IGCC concepts for in-Refinery Energy and Hydrogen supply

    Energy Technology Data Exchange (ETDEWEB)

    Romey, I.; Obladen, M.; Schulz, A. [Univ. Duisburg-Essen, Inst. Technology of Energy Supply and Energery Conversion Systems (TEE), Essen (Germany)

    2004-07-01

    There is an increasing tendency for refineries to produce a greater proportion of light, high-hydrogen-content chemicals, which also results in greater quantities of heavy residues which require disposal. Gasification of these residues offers a number of options for utilisation of the resulting products. Importantly, gasification offers the opportunity for cost-effective production of hydrogen, which may not only be used in the refinery processes, but also in future fuel cell applications, either for stationary or transport options. The MIGREYD project opens an important bridge for the transition from the use of conventional fossil fuels to a future hydrogen based energy system. Through this project, an advanced, highly efficient in-refinery energy and hydrogen supply system will be developed that is flexible in terms of fuels (biomass, oil refinery residues, low-grade fossil fuels) and products (hydrogen, cogeneration of power and process heat, and other chemicals). The improved efficiency of the process stages and the synergistic benefits of poly-generation will realise savings of primary fossil energy resources, sustainable pollution control and a significant decrease of the total plant's CO{sub 2} emissions. (orig.)

  1. Biological treatment of refinery spent caustics under halo-alkaline conditions

    NARCIS (Netherlands)

    Graaff, de M.; Bijmans, M.F.M.; Abbas, B.; Euverink, G.J.W.; Muyzer, G.; Janssen, A.J.H.

    2011-01-01

    The present research demonstrates the biological treatment of refinery sulfidic spent caustics in a continuously fed system under halo-alkaline conditions (i.e. pH 9.5; Na(+)= 0.8M). Experiments were performed in identical gas-lift bioreactors operated under aerobic conditions (80-90% saturation) at

  2. REMOTE SENSING DAMAGE ASSESSMENT OF CHEMICAL PLANTS AND REFINERIES FOLLOWING HURRICANES KATRINA AND RITA

    Science.gov (United States)

    The massive destruction brought by Hurricanes Katrina and Rita also impacted the many chemical plants and refineries in the region. The achievement of this rapid analysis capability highlights the advancement of this technology for air quality assessment and monitoring. Case st...

  3. Use of activated carbons to remove undesirable residual amylase from factory and refinery streams

    Science.gov (United States)

    In recent years, there has been increased world-wide concern over residual (carry-over) activity of mostly high temperature (HT) and very high temperature (VHT) stable amylases in white, refined sugars from refineries to various food and end-user industries. HT and VHT stable amylases were develope...

  4. Profitability diagnosis of refinery and improvement proposal; Seiyusho no shueki shindan to kaizen teian

    Energy Technology Data Exchange (ETDEWEB)

    Aoyama, H.

    2000-07-01

    Based on consulting service RPS-J under joint operation of Nikki, UOP LLC of U.S.A. and Nikki Universal, approaching ways applied for profitability improvement and improvement proposal for refineries and analyzing techniques used for resolution of process bottlenecks were described. In RPS-J, themes of (1) energy saving, (2) quality upgrading, (3) improvement of disintegrating ratio, (4) reduction of give-away, (5) improvement of equipment operation ratio, (6) reduction of maintenance cost, (7) effective utilization of catalysts, are considered for profitability improvement fields. Procedures from idea excavation for profitability improvement to realization of profitability improvement are carried out in the order of, (1) Grasping of the present state, (2) Excavation of improving items and selection, (3) Quantitative evaluation of draft profitability improvement plan and focusing, (4) Profitability improvement by operation improvement, (5) Profitability improvement by minor improvement, (6) Profitability improvement in middle- and long-term vision, (7) Final focusing by feasibility study. Afterwards, examination to economically solve bottlenecks of critical facilities, examination on bottlenecks of distillation tower and refining tower and utility analysis are carried out. RPS-J was already applied to 4 refineries including Muroran Refinery and Negishi Refinery of Nisseki Mitsubishi, and profitability improvement themes were found to improve profitability of 50 to 150 cents per barrel. (NEDO)

  5. Monitoring coastal pollution associated with the largest oil refinery complex of Venezuela.

    Science.gov (United States)

    Croquer, Aldo; Bone, David; Bastidas, Carolina; Ramos, Ruth; García, Elia

    2016-01-01

    This study evaluated pollution levels in water and sediments of Península de Paraguaná and related these levels with benthic macrofauna along a coastal area where the largest Venezuelan oil refineries have operated over the past 60 years. For this, the concentration of heavy metals, of hydrocarbon compounds and the community structure of the macrobenthos were examined at 20 sites distributed along 40 km of coastline for six consecutive years, which included windy and calm seasons. The spatial variability of organic and inorganic compounds showed considerably high coastal pollution along the study area, across both years and seasons. The southern sites, closest to the refineries, had consistently higher concentrations of heavy metals and organic compounds in water and sediments when compared to those in the north. The benthic community was dominated by polychaetes at all sites, seasons and years, and their abundance and distribution were significantly correlated with physical and chemical characteristics of the sediments. Sites close to the oil refineries were consistently dominated by families known to tolerate xenobiotics, such as Capitellidae and Spionidae. The results from this study highlight the importance of continuing long-term environmental monitoring programs to assess the impact of effluent discharge and spill events from the oil refineries that operate in the western coast of Paraguaná, Venezuela.

  6. Pyrolysis oil upgrading for Co-processing in standard refinery units

    NARCIS (Netherlands)

    De Miguel Mercader, F.

    2010-01-01

    This thesis considers the route that comprises the upgrading of pyrolysis oil (produced from lingo-cellulosic biomass) and its further co-processing in standard refineries to produce transportation fuels. In the present concept, pyrolysis oil is produced where biomass is available and then

  7. Lymphohematopoietic Cancer Mortality and Morbidity of Workers in a Refinery/Petrochemical Complex in Korea

    Directory of Open Access Journals (Sweden)

    Dong-Hee Koh

    2011-03-01

    Conclusion: The results showed a potential relationship between leukemia and lymphohematopoietic cancers and exposure to benzene in refinery/petrochemical complex workers. This study yielded limited results due to a short observational period; therefore, a follow-up study must be performed to elucidate the relationship between petrochemical exposure and cancer rates.

  8. Environmental and economic sustainability of integrated production in bio-refineries: The thistle case in Sardinia

    NARCIS (Netherlands)

    Yazan, Devrim; Yazan, Devrim Murat; Mandras, Giovanni; Garau, Giorgio

    2016-01-01

    This paper aims at evaluating the environmental and economic sustainability of bio-refineries that produce multiple products through their supply chains (SCs). A physical enterprise input-output (EIO) model is used to quantify the material/energy/waste flows and integrated to the monetary EIO model

  9. Production of advanced biofuels: Co-processing of upgraded pyrolysis oil in standard refinery units

    NARCIS (Netherlands)

    Miguel Mercader, de F.; Groeneveld, M.J.; Kersten, S.R.A.; Way, N.W.J.; Schaverien, C.J.; Hogendoorn, J.A.

    2010-01-01

    One of the possible process options for the production of advanced biofuels is the co-processing of upgraded pyrolysis oil in standard refineries. The applicability of hydrodeoxygenation (HDO) was studied as a pyrolysis oil upgrading step to allow FCC co-processing. Different HDO reaction end temper

  10. Material resources, energy, and nutrient recovery from waste: are waste refineries the solution for the future?

    DEFF Research Database (Denmark)

    Tonini, Davide; Martinez-Sanchez, Veronica; Astrup, Thomas Fruergaard

    2013-01-01

    of a Danish waste refinery solution against state-of-the-art waste technology alternatives (incineration, mechanical-biological treatment (MBT), and landfilling). In total, 252 scenarios were evaluated, including effects from source-segregation, waste composition, and energy conversion pathway efficiencies...

  11. 40 CFR 80.1238 - How is a refinery's or importer's average benzene concentration determined?

    Science.gov (United States)

    2010-07-01

    ... average benzene concentration determined? 80.1238 Section 80.1238 Protection of Environment ENVIRONMENTAL... concentration determined? (a) The average benzene concentration of gasoline produced at a refinery or imported...: ER26FE07.012 Where: Bavg = Average benzene concentration for the applicable averaging period (volume...

  12. Recent grassland losses are concentrated around U.S. ethanol refineries

    Science.gov (United States)

    Wright, Christopher K.; Larson, Ben; Lark, Tyler J.; Gibbs, Holly K.

    2017-04-01

    Although the United States has pursued rapid development of corn ethanol as a matter of national biofuel policy, relatively little is known about this policy’s widespread impacts on agricultural land conversion surrounding ethanol refineries. This knowledge gap impedes policy makers’ ability to identify and mitigate potentially negative environmental impacts of ethanol production. We assessed changes to the landscape during initial implementation of the Renewable Fuel Standard v2 (RFS2) from 2008 to 2012 and found nearly 4.2 million acres of arable non-cropland converted to crops within 100 miles of refinery locations, including 3.6 million acres of converted grassland. Aggregated across all ethanol refineries, the rate of grassland conversion to cropland increased linearly with proximity to a refinery location. Despite this widespread conversion of the landscape, recent cropland expansion could have made only modest contributions to mandated increases in conventional biofuel capacity required by RFS2. Collectively, these findings demonstrate a shortcoming in the existing ‘aggregate compliance’ method for enforcing land protections in the RFS2 and suggest an alternative monitoring mechanism would be needed to appropriately capture the scale of observed land use changes.

  13. Materials And Carbon Flow In A Waste Refinery Process Using Enzymes

    DEFF Research Database (Denmark)

    Tonini, Davide; Woods, M.; Astrup, Thomas

    2011-01-01

    that the waste refinery has great potential for resource recovery: about 100% of the Cbiogenic and up to 90% of N and P can potentially be recovered in the bioslurry and returned to land after anaerobic digestion. Recovery of ferrous and non-ferrous material is estimated double compared to recovering the same...

  14. Utilization of the BR-SIPP systems (Integrated Refinery Scheduling System) at the PETROBRAS Capuava refinery; Utilizacao do sistema BR-SIPP - Sistema Integrado de Programacao de Producao PETROBRAS na refinaria de Capuava

    Energy Technology Data Exchange (ETDEWEB)

    Joly, Marcel [PETROBRAS, Maua, SP (Brazil). Refinaria de Capuava (RECAP). Gerencia de Otimizacao]. E-mail: joly@petrobras.com.br; Hassimotto, Marcelo Kenji [PETROBRAS, Rio de Janeiro, RJ (Brazil). Gerencia de Solucoes de Negocios de Logistica e Planejamento]. E-mail: kenji@petrobras.com.br; Magalhaes, Marcus Vinicius de Oliveira [PETROBRAS, Rio de Janeiro, RJ (Brazil). Gerencia de Otimizacao]. E-mail: vinicius@petrobras.com.br

    2007-04-15

    The BR-SIPP is a production scheduling decision support tool for refineries. It is integrated into the Corporate Inventory, Movements and Quality Data Base and is based on events simulation technology for the elaboration and analysis of scheduling scenarios. Its utilization at the Capuava Refinery allows the production programming team to analyze and anticipate difficulties and opportunities, thereby being able to make viable a potential integration of management and people directly involved with the refinery scheduling information, such as planning, logistics and commercial areas. (author)

  15. Quantitative Estimate of Unorganized Emission of VOCs from Petroleum Refinery Wastwater Treatment%石化炼油废水处理VOCs无组织排放定量估算研究

    Institute of Scientific and Technical Information of China (English)

    戴晓波; 邱贤锋; 何金平; 王文成; 陈选文

    2012-01-01

    炼油厂废水处理中无组织排放VOCs是石化企业污染源核查的重要内容。概述了影响VOCs挥发因素,利用基于MATLAB神经网络工具箱的图形用户界面GUI,并且使用在某石化企业所收集的相关数据,建立了石化企业炼油废水处理中无组织排放VOCs的定量模型。通过实验,证明了模型具有更广泛的应用范围,弥补了新建项目环境影响评价中的缺陷。%In view of the fact that unorganized emission of VOSc from Wastwater Treatment is one of the major pollution sources of a petroleum refinery, this paper studies effecting factors of VOCs volatilization and establishes a quantitative model of unorganized VOCs emission from Wastewater Treatment on the basis of the data from a petroleum refinery by means of GUI of MATLAB neural network toolbox. Experiments prove that the model fits for a wide range of applications, which will im- prove project environment impact assessments.

  16. Contribution of Tula Refinery flaring emissions to the Mexico megacity

    Science.gov (United States)

    Almanza, Victor; Molina, Luisa; Sosa, Gustavo

    2013-04-01

    Flaring is an important source of greenhouse gases, particulate matter and Volatile Organic Compounds (VOCs) in both upstream and downstream operations in the oil and gas industry. In 2010 Mexico was the eleventh emitting country with 2.5 billion cubic meters of gas flared (World Bank, 2012). Black carbon (a component of soot) emissions from flaring facilities are of particular interest because soot is considered a short-lived climate forcer (SLCF) (UNEP, 2011). In 2011 there were 23 megacities of at least 10 million inhabitants. It is expected that this number increase to 37 by 2025, which will include one more in Northern America (NA) and two more in Latin America (UN, 2012). International collaborative projects like MILAGRO in NA and MEGAPOLI/CityZen in Europe, have been conducted to assess the impact of megacities air pollution at several scales. The former focused on the air pollution plume of Mexico City Metropolitan Area (MCMA), the largest megacity in NA. This work studies the contribution of flaring emissions from Tula Refinery to regional air quality. This is accomplished in two steps. First, the flame of a representative sour gas flare is modeled with a CFD combustion code in order to estimate emission rates of combustion by-products of interest for air quality. Mass flow rates of acetylene, ethylene, nitrogen oxides, carbon monoxide, soot and sulfur dioxide are obtained. The emission rates of NO2 and SO2 are compared with measurements obtained at Tula as part of MILAGRO field campaign. The rates of soot, VOCs and CO emissions are compared with estimates obtained by Instituto Mexicano del Petróleo (IMP). The second stage takes the flaring emission rates of the aforementioned species as inputs to WRF-Chem in order to simulate the chemical transport of the plume from 22 March to 27 March of 2006. The air quality model presented reliable performance of the resolved meteorology, with respect to the Mean Absolute Error (MAE), Root Mean Square Error (RMSE

  17. Becoming a refinery leader by changing operations to match new product quality regulations

    Energy Technology Data Exchange (ETDEWEB)

    Mendez, Maryro P. [KBC Advanced Technologies, Surrey (United Kingdom)

    2012-07-01

    Global environmental concerns have forced the automotive and oil industries to increase efficiency and reduce emissions, which has led to the tightening of fuels specifications around the world. The implementation of ultra-low sulphur transport fuels has become a worldwide trend with growing momentum. Compliance with these standards requires the refiner to make decisions in advance of the implementation date. Therefore, in order to make changes on time, refiners are currently assessing options and changes required to comply with regulations by 2016. Similar regulations have been implemented in Europe already and KBC has the methodology and experience to assess the existing refinery configuration, unit capability and facility infrastructure to provide the basis for decision making. This paper focus on KBC's methodology which looks at the molecular management needed to produce the low levels of sulfur and toxic required in today's refined products. A key element to the study is the use of Petro-SIM for development of a representative detailed non-linear model, of the refinery which has been used to test ideas and configurations and help confirm the Refinery LP development activities. Using a Petro-SIM representation, KBC is able to make an assessment of the impact of imposing Tier 3 gasoline (sulphur to < 10 ppm) on the refinery, examining critical blending constraints, unused stream qualities and quantities and likely type and scale of capital investment that would be required while optimising unit operations and maximising margins. This paper illustrates KBC's current thinking based on studies done to date to review clean fuels and Tier 3 specifications options for specific refinery configurations. (author)

  18. Management of environmental liability and remediation of the La Pampilla Oil Refinery, Lima, Peru

    Energy Technology Data Exchange (ETDEWEB)

    Wood, M.S. [Hazco Environmental Services, Calgary, AB (Canada)

    2007-07-01

    The La Pampilla Oil Refinery has a capacity of 102,000 barrels per day, and supplies over 50 per cent of Peru's petroleum products. The area surrounding the refinery was severely polluted due to continuous leaks and spills. Remediation of the area began in 2001. The remediation project was divided into 5 sub-projects: (1) free product recovery in refinery area; (2) free recovery in beach area; (3) secure industrial and hazardous landfill; (4) bioremediation of treatable soil contamination; and (5) characterization, handling and shipping of hazardous historical waste. Recovery wells, collection tanks, and air compressors were located at various sites on the refinery grounds. A pneumatic skimmer was used to recover an estimated 33,000 bbls of free product in the refinery area over a period of 3.5 years. Product thickness on the groundwater table is remaining stable. Over 2000 bbls of free product were recovered in the beach area through the combined use of pump recovery and skimmer pumps. Two landfill cells were sited on the property with over 140,000 tonnes of hydrocarbons. Details of liner construction and installation were provided, as well as details of the earthquake design adjustments needed to ensure the safety of the landfills. Soils in the area are being bioremediated by digging 29 pits using segregated materials and a combination of aeration and organic amendments with air biopiles. Excavated volumes to date are 498,000 m{sup 3}. It was concluded that soils contaminated with tetraethyl lead, asbestos, and heavy metals are now being classified and disposed of. The total volume of disposed solid wastes has exceeded 12,000 cubic metres. tabs., figs.

  19. Test plan, the Czechowice Oil Refinery bioremediation demonstration of a process waste lagoon. Revision 1

    Energy Technology Data Exchange (ETDEWEB)

    Altman, D.J.; Hazen, T.C.; Tien, A.J. [Westinghouse Savannah River Co., Aiken, SC (United States). Savannah River Technology Center; Worsztynowicz, A.; Ulfig, K. [Inst. for Ecology of Industrial Areas, Katowice (Poland)

    1997-05-10

    The overall objective of the bioremediation project is to provide a cost effective bioremediation demonstration of petroleum contaminated soil at the Czechowice Oil Refinery. Additional objectives include training of personnel, and transfer of this technology by example to Poland, and the Risk Abatement Center for Central and Eastern Europe (RACE). The goal of the remediation is to reduce the risk of PAH compounds in soil and provide a green zone (grassy area) adjacent to the site boundary. Initial project discussions with the Czechowice Oil Refinery resulted in helping the refinery find an immediate cost effective solution for the dense organic sludge in the lagoons. They found that when mixed with other waste materials, the sludge could be sold as a fuel source to local cement kilns. Thus the waste was incinerated and provided a revenue stream for the refinery to cleanup the lagoon. This allowed the bioremediation project to focus on remediation of contaminated soil that unusable as fuel, less recalcitrant and easier to handle and remediate. The assessment identified 19 compounds at the refinery that represented significant risk and would require remediation. These compounds consisted of metals, PAH`s, and BTEX. The contaminated soil to be remediated in the bioremediation demonstration contains only PAH (BTEX and metals are not significantly above background concentrations). The final biopile design consists of (1) dewatering and clearing lagoon A to clean clay, (2) adding a 20 cm layer of dolomite with pipes for drainage, leachate collection, air injection, and pH adjustment, (3) adding a 1.1 m layer of contaminated soil mixed with wood chips to improve permeability, and (4) completing the surface with 20 cm of top soil planted with grass.

  20. SELECTION OF CHEMICAL TREATMENT PROGRAM FOR OILY WASTEWATER

    Directory of Open Access Journals (Sweden)

    Miguel Díaz

    2017-04-01

    Full Text Available When selecting a chemical treatment program for wastewater to achieve an effective flocculation and coagulation is crucial to understand how individual colloids interact. The coagulation process requires a rapid mixing while flocculation process needs a slow mixing. The behavior of colloids in water is strongly influenced by the electrokinetic charge, where each colloidal particle carries its own charge, which in its nature is usually negative. Polymers, which are long chains of high molecular weight and high charge, when added to water begin to form longer chains, allowing removing numerous particles of suspended matter. A study of physico-chemical treatment by addition of coagulant and flocculant was carried out in order to determine a chemical program for oily wastewater coming from the gravity separation process in a crude oil refinery. The tests were carried out in a Jar Test equipment, where commercial products: aluminum polychloride (PAC, aluminum sulfate and Sintec D50 were evaluated with five different flocculants. The selected chemical program was evaluated with fluids at three temperatures to know its sensitivity to this parameter and the mixing energy in the coagulation and flocculation. The chemical program and operational characteristics for physico-chemical treatment with PAC were determined, obtaining a removal of more than 93% for suspended matter and 96% for total hydrocarbons for the selected coagulant / flocculant combination.

  1. Wastewater Treatment Plants

    Data.gov (United States)

    Iowa State University GIS Support and Research Facility — The actual treatment areas for municipal, industrial, and semi-public wastewater treatment facilities in Iowa for the National Pollutant Discharge Elimination System...

  2. Wastewater Treatment Facilities

    Data.gov (United States)

    Iowa State University GIS Support and Research Facility — Individual permits for municipal, industrial, and semi-public wastewater treatment facilities in Iowa for the National Pollutant Discharge Elimination System (NPDES)...

  3. Wastewater Treatment in Greenland

    DEFF Research Database (Denmark)

    Gunnarsdottir, Ragnhildur

    The Arctic nature is vulnerable to environmental contaminants because of low biological diversity, lack of nutrients and extreme seasonal variations in light. In Greenland neither industrial nor domestic wastewater is treated before it is discharged to the recipients, which in most cases is the sea...... treatment in these regions. However, designing, constructing and operating wastewater collection systems in the Arctic is challenging because of e.g. permafrost conditions, hard rock surfaces, freezing, limited quantity of water and high costs of electricity, fuel and transportation, as well as a settlement...... collection systems, and be more economically and environmentally sustainable than traditional wastewater collection and treatment systems. Possible alternative wastewater treatment methods for Greenlandic communities are dry composting or anaerobic digestion of excreta, collected at household level using dry...

  4. Biohydrogen production from industrial wastewaters.

    Science.gov (United States)

    Moreno-Andrade, Iván; Moreno, Gloria; Kumar, Gopalakrishnan; Buitrón, Germán

    2015-01-01

    The feasibility of producing hydrogen from various industrial wastes, such as vinasses (sugar and tequila industries), and raw and physicochemical-treated wastewater from the plastic industry and toilet aircraft wastewater, was evaluated. The results showed that the tequila vinasses presented the maximum hydrogen generation potential, followed by the raw plastic industry wastewater, aircraft wastewater, and physicochemical-treated wastewater from the plastic industry and sugar vinasses, respectively. The hydrogen production from the aircraft wastewater was increased by the adaptation of the microorganisms in the anaerobic sequencing batch reactor.

  5. Current status of vegetation of six PETROBRAS refineries; Status dos fragmentos de vegetacao em seis refinarias da PETROBRAS

    Energy Technology Data Exchange (ETDEWEB)

    Basbaum, Marcos Andre; Bonafini, Fabio Loureiro; Porciano, Patricia Pereira [SEEBLA, Servicos de Engenharia Emilio Baumgart Ltda., Rio de Janeiro, RJ (Brazil); Torggler, Bianca Felippe; Fernandes, Renato [PETROBRAS, Rio de Janeiro, RJ (Brazil). Engenharia; Vieira, Elisa Diniz Reis [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2008-07-01

    Most of refineries from PETROBRAS have significant vegetation areas within their limits. The purpose of this study was to develop a preliminary assessment study of the vegetation fragments on six refineries, including the quantification of permanent preservation areas (Brazilian environmental law requirement). Besides that, the authors propose potential recovery areas and some reforestation techniques. The methodology was based on Rapid Ecological Assessment, that consists on the selection of target areas by image analysis (satellite or aerial photos) and expedite fieldwork - three days on each refinery. The main features of vegetation, like phytophysiognomy and successional stage were obtained, and registered on a specific form developed to be used at fieldwork. The results achieved show that 44,7% of the areas from these six refineries were occupied by vegetation. The most representative categories of vegetation were Atlantic forest fragments and mangroves, as well as to permanent preservation areas. (author)

  6. Sulfur Dioxide (SO2 Accumulation in Soil and Plant's Leaves around an Oil Refinery: A Case Study from Saudi Arabia

    Directory of Open Access Journals (Sweden)

    M. O. Al-Jahdali

    2008-01-01

    Full Text Available The accumulative levels of SO2 in soil and plant's leaves around an oil refinery were monitored. Four different sites around the refinery area were chosen; west, south east, north east and the northern side. The refinery southern side was not accessible. In addition to the soil samples, leaves samples of the dominant plants species Myoporum pictum were randomly collected from all sites. Highly significant levels of sulfate were found in soil and plant leaves samples at all sites compared to the control. The highest level of sulfate in soil (9,000 ± 1200 µg g-1 and plant's leaves (65,774 ± 320 µg g-1 were found in the southern east side. This high content of sulfate indicates high levels of air contamination with SO2 around the refinery which negatively effects the environment and public health at this populated area.

  7. Development of a research method to measure insoluble and soluble starch in sugarcane factory and refinery products

    Science.gov (United States)

    A rapid, quantitative research method using microwave-assisted probe ultrasonication was developed to facilitate the determination of total insoluble, and soluble starch in various sugar factory and refinery products. Several variables that affect starch solubilization were evaluated: 1) conductiv...

  8. Current status of vegetation of six PETROBRAS refineries; Status dos fragmentos de vegetacao em seis refinarias da PETROBRAS

    Energy Technology Data Exchange (ETDEWEB)

    Basbaum, Marcos Andre; Bonafini, Fabio Loureiro; Porciano, Patricia Pereira [SEEBLA, Servicos de Engenharia Emilio Baumgart Ltda., Rio de Janeiro, RJ (Brazil); Torggler, Bianca Felippe; Fernandes, Renato [PETROBRAS, Rio de Janeiro, RJ (Brazil). Engenharia; Vieira, Elisa Diniz Reis [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2008-07-01

    Most of refineries from PETROBRAS have significant vegetation areas within their limits. The purpose of this study was to develop a preliminary assessment study of the vegetation fragments on six refineries, including the quantification of permanent preservation areas (Brazilian environmental law requirement). Besides that, the authors propose potential recovery areas and some reforestation techniques. The methodology was based on Rapid Ecological Assessment, that consists on the selection of target areas by image analysis (satellite or aerial photos) and expedite fieldwork - three days on each refinery. The main features of vegetation, like phytophysiognomy and successional stage were obtained, and registered on a specific form developed to be used at fieldwork. The results achieved show that 44,7% of the areas from these six refineries were occupied by vegetation. The most representative categories of vegetation were Atlantic forest fragments and mangroves, as well as to permanent preservation areas. (author)

  9. Virtual industrial water usage and wastewater generation in the Middle East/North African region

    Directory of Open Access Journals (Sweden)

    S. R. Sakhel

    2013-01-01

    Full Text Available This study deals with the quantification of volumes of water usage, wastewater generation, virtual water export, and wastewater generation from export for eight export relevant industries present in the Middle East/North Africa (MENA. It shows that about 3400 million m3 of water is used per annum while around 793 million m3 of wastewater is generated from products that are meant for domestic consumption and export. The difference between volumes of water usage and wastewater generation is due to water evaporation or injecting underground (oil wells pressure maintenance. The wastewater volume generated from production represents a population equivalent of 15.5 million in terms of wastewater quantity and 30.4 million in terms of BOD. About 409 million m3 of virtual water flows from MENA to EU27 (resulting from export of eight commodities which is equivalent to 12.1% of the water usage of those industries and Libya is the largest virtual water exporter (about 87 million m3. Crude oil and refined petroleum products represent about 89% of the total virtual water flow, fertilizers represent around 10% and 1% remaining industries. EU27 poses the greatest indirect pressure on the Kuwaiti hydrological system where the virtual water export represents about 96% of the actual renewable water resources in this country. The Kuwaiti crude oil water use in relation to domestic water withdrawal is about 89% which is highest among MENA countries. Pollution of water bodies, in terms of BOD, due to production is very relevant for crude oil, slaughterhouses, refineries, olive oil, and tanneries while pollution due to export to EU27 is most relevant for crude oil industry and olive oil mills.

  10. A Survey on the Removal Efficiency of Fat, Oil and Grease in Shiraz Municipal Wastewater Treatment Plant

    Directory of Open Access Journals (Sweden)

    Dehghani

    2014-12-01

    Full Text Available Background Fat, oil and grease (FOG in municipal wastewater treatment plant (MWWTP caused many problems. Objectives This study aimed to determine the removal efficiency of FOG in Shiraz MWWTP. Materials and Methods The removal efficiencies of FOG in the MWWTP were studied from June 2011 to September 2011 in Shiraz (Iran. The influent and effluent wastewater samples were collected in a volume of one liter (4 samples per week and analyzed according to the standard methods. Samples are transferred to the laboratory immediately. The concentration of FOG was determined using the solvent extraction and separating funnel and then compared with the effluent standards. To analyze the data, SPSS (version 11.5, Chi-square test and t test were used. Results The results showed that the FOG amount in input raw sewage in the MWWTP from June 2011 to September 2011 was around 25.5 mg/L and the amount in treated wastewater was about 8.1 mg/L. The FOG removal efficiency in this refinery was about 70% and met the environmental standards for the discharge (less than 10 mg/L (P < 0.05. Conclusions The effluent can be discharged to surface waters or used for irrigation. In order to the FOG concentration met the effluent standards, it is very crucial to control the entrance of industrial wastewater to the municipal wastewater collection networks. Otherwise, the MWWTP should be upgraded and the special techniques used to reduce FOG.

  11. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-11-17

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  12. Genotoxic evaluation of an industrial effluent from an oil refinery using plant and animal bioassays

    Directory of Open Access Journals (Sweden)

    Fernando Postalli Rodrigues

    2010-01-01

    Full Text Available Polycyclic aromatic hydrocarbons (PAHs are genotoxic chemicals commonly found in effluents from oil refineries. Bioassays using plants and cells cultures can be employed for assessing environmental safety and potential genotoxicity. In this study, the genotoxic potential of an oil refinery effluent was analyzed by means of micronucleus (MN testing of Alium cepa, which revealed no effect after 24 h of treatment. On the other hand, primary lesions in the DNA of rat (Rattus norvegicus hepatoma cells (HTC were observed through comet assaying after only 2 h of exposure. On considering the capacity to detect DNA damage of a different nature and of these cells to metabolize xenobiotics, we suggest the association of the two bioassays with these cell types, plant (Allium cepa and mammal (HTC cells, for more accurately assessing genotoxicity in environmental samples.

  13. Materials And Carbon Flow In A Waste Refinery Process Using Enzymes

    DEFF Research Database (Denmark)

    Tonini, Davide; Woods, M.; Astrup, Thomas

    2011-01-01

    Recovery of resources from mixed Municipal Solid Waste (MSW) is a crucial aspect of waste management practices. In this paper the materials and carbon flows of an innovative waste refinery process using enzymes are presented. Through enzymatic treatment the process produces two main streams from...... the initial mixed MSW: a bioslurry (liquefied paper and organics) and a solid fraction (non-degradable materials). The discussion is based on the performance of the process in separating recyclables and recovery Cbiogenic as well as nutrients from the input MSW. The results of MFA and SFA illustrate...... that the waste refinery has great potential for resource recovery: about 100% of the Cbiogenic and up to 90% of N and P can potentially be recovered in the bioslurry and returned to land after anaerobic digestion. Recovery of ferrous and non-ferrous material is estimated double compared to recovering the same...

  14. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    Energy Technology Data Exchange (ETDEWEB)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-04-23

    This report summarizes the accomplishments toward project goals during the first six months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  15. Toward zero waste to landfill: an effective method for recycling zeolite waste from refinery industry

    Science.gov (United States)

    Homchuen, K.; Anuwattana, R.; Limphitakphong, N.; Chavalparit, O.

    2017-07-01

    One-third of landfill waste of refinery plant in Thailand was spent chloride zeolite, which wastes a huge of land, cost and time for handling. Toward zero waste to landfill, this study was aimed at determining an effective method for recycling zeolite waste by comparing the chemical process with the electrochemical process. To investigate the optimum conditions of both processes, concentration of chemical solution and reaction time were carried out for the former, while the latter varied in term of current density, initial pH of water, and reaction time. The results stated that regenerating zeolite waste from refinery industry in Thailand should be done through the chemical process with alkaline solution because it provided the best chloride adsorption efficiency with cost the least. A successful recycling will be beneficial not only in reducing the amount of landfill waste but also in reducing material and disposal costs and consumption of natural resources as well.

  16. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    Energy Technology Data Exchange (ETDEWEB)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-05-18

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  17. Striving for an Energy and Resources Saving Refinery with Harmonious Development

    Institute of Scientific and Technical Information of China (English)

    Sun Lili

    2007-01-01

    The operating circumstances of refinery industry in China in 2005 were referred to in this paper,along with the processes for development of petrochemical industry aimed at regionalization,concentrated disposition of enterprises and construction of industrial bases.The pressure faced currently by the oil refining industry in terms of resources avalibility and environmental regulations was analyzed.The key elements associated with the refining industry restructuring to economize on all kinds of resources were discussed and presented.It is stated that the key for building an energy and materials saving oil refining industry should rely on the adoption of advanced process and engineering technology,adjustment of refinery configuration,improving the energy and resources utilization efficiency,deep processing of crude oils,optimizing all kinds of resources,reducing effluents by saving water,as well as boosting the integration of oil refining with chemical production,concentrated disposition and realization of large scale of process units.

  18. Mathematical Model for Predicting Corrosion Rates in Furnace Internal Wall Tubes of The Refinery Boiler

    Directory of Open Access Journals (Sweden)

    Edori, E. S

    2016-08-01

    Full Text Available A model for predicting the corrosion rates in the furnace internal wall tubes of the refinery boiler was resolved, using the first order differential equation derived from the material balance equation of the system. The mathematical model was able to predict the metal loss recorded by ultrasonic thickness scanning technique (UTS, and the results shows an agreement. The results from both the model and UTS shows that in the various tubes of the furnace, internal wall of the refinery boiler were between the same range. The percentage deviation which was calculated to ascertain the acceptability of the model result as compared to that from UTS proved that the model is effective. The inhibitor model result show that corrosion will drastically reduce in the presence of corrosion inhibitors under proper chemical treatment and management. The model developed can be used to monitor furnace internal wall corrosion even when the system is in operation by extrapolating the result to further years.

  19. Life-cycle assessment of a waste refinery process for enzymatic treatment of municipal solid waste

    DEFF Research Database (Denmark)

    Tonini, Davide; Astrup, Thomas

    2012-01-01

    Decrease of fossil fuel dependence and resource saving has become increasingly important in recent years. From this perspective, higher recycling rates for valuable materials (e.g. metals) as well as energy recovery from waste streams could play a significant role substituting for virgin material...... production and saving fossil resources. This is especially important with respect to residual waste (i.e. the remains after source-separation and separate collection) which in Denmark is typically incinerated. In this paper, a life-cycle assessment and energy balance of a pilot-scale waste refinery...... for the enzymatic treatment of municipal solid waste (MSW) is presented. The refinery produced a liquid (liquefied organic materials and paper) and a solid fraction (non-degradable materials) from the initial waste. A number of scenarios for the energy utilization of the two outputs were assessed. Co...

  20. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-09-17

    This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  1. Microalgal biofilms for wastewater treatment

    NARCIS (Netherlands)

    Boelee, N.C.

    2013-01-01

    The objective of this thesis was to explore the possibilities of using microalgal biofilms for the treatment of municipal wastewater, with a focus on the post-treatment of municipal wastewater effluent. The potential of microalgal biofilms for wastewater treatment was first investigated using a scen

  2. Microalgal biofilms for wastewater treatment

    NARCIS (Netherlands)

    Boelee, N.C.

    2013-01-01

    The objective of this thesis was to explore the possibilities of using microalgal biofilms for the treatment of municipal wastewater, with a focus on the post-treatment of municipal wastewater effluent. The potential of microalgal biofilms for wastewater treatment was first investigated using a scen

  3. Management of waste generation in the oil refining industry. The PETROBRAS - Henrique Lage Refinery experience

    Energy Technology Data Exchange (ETDEWEB)

    Coelho, J.I.; Machado, J.B.; Linhares, C.A.; Mazarino, P.R. [PETROBRAS, Sao Jose dos Campos, SP (Brazil). REVAP. Refinaria Henrique Lage

    1993-12-31

    The PETROBRAS - Henrique Lages Refinery - located in Sao Paulo State (Southeast Brazil), has been developing for many years a systematic program for solid, liquid and gaseous wastes generation reduction. The waste minimization management program success has been built due to the structure behavioural modifications due to the new environment protection and quality politics; the training and equipment investments, and operational procedures changes. (author). 7 figs., 3 tabs.

  4. Optimal Renewable Energy Integration into Refinery with CO2 Emissions Consideration: An Economic Feasibility Study

    Science.gov (United States)

    Alnifro, M.; Taqvi, S. T.; Ahmad, M. S.; Bensaida, K.; Elkamel, A.

    2017-08-01

    With increasing global energy demand and declining energy return on energy invested (EROEI) of crude oil, global energy consumption by the O&G industry has increased drastically over the past few years. In addition, this energy increase has led to an increase GHG emissions, resulting in adverse environmental effects. On the other hand, electricity generation through renewable resources have become relatively cost competitive to fossil based energy sources in a much ‘cleaner’ way. In this study, renewable energy is integrated optimally into a refinery considering costs and CO2 emissions. Using Aspen HYSYS, a refinery in the Middle East was simulated to estimate the energy demand by different processing units. An LP problem was formulated based on existing solar energy systems and wind potential in the region. The multi-objective function, minimizing cost as well as CO2 emissions, was solved using GAMS to determine optimal energy distribution from each energy source to units within the refinery. Additionally, an economic feasibility study was carried out to determine the viability of renewable energy technology project implementation to overcome energy requirement of the refinery. Electricity generation through all renewable energy sources considered (i.e. solar PV, solar CSP and wind) were found feasible based on their low levelized cost of electricity (LCOE). The payback period for a Solar CSP project, with an annual capacity of about 411 GWh and a lifetime of 30 years, was found to be 10 years. In contrast, the payback period for Solar PV and Wind were calculated to be 7 and 6 years, respectively. This opens up possibilities for integrating renewables into the refining sector as well as optimizing multiple energy carrier systems within the crude oil industry

  5. Analysis of Accidents in Nine Iranian Gas Refineries: 2007–2011

    OpenAIRE

    AR Shakibmanesh; Bolouri, A.; R Mehrdad

    2013-01-01

    Background: Occupational accidents are one of the major health hazards in industries and associated with high mortality, morbidity, spiritual damage and economic losses in the world.Objective: To determine the incidence of occupational accidents in 9 Iranian gas refineries between March 2007 and February 2011.Methods: Data on all occupational accidents occurred between March 2007 and February 2011, as well as other possible associated variables including time of accident, whether the accident...

  6. Decreasing emission factor of pollutants in an oil refinery by renovating the furnace design

    Directory of Open Access Journals (Sweden)

    A. Zabihi

    2016-05-01

    Full Text Available The significant consumption of gas in the World results in the emission of greenhouse gases into atmosphere. Abadan refinery has always been the biggest and oldest oil refinery in the Middle East and has a variety of refined products. After six months of collecting data about pollutant concentration emitted from a stack of old furnaces of units 75 and new unit 200, the emission factor of the pollutant was calculated. The result showed that the emission factor of some hazardous pollutants emitted from old unit 75 was tremendously higher than that of unit 200. This study suggests the installation of a forced fan to provide the excess air and a feed temperature controlling system to control fuel gas consumption. These would make the fuel combustion complete and decrease its consumption. Meanwhile, further results showed that the renovation of unit 75 could lead to a significant annual reduction of some pollutants such as CO, H2S, and CxHx to 66 ton, 3 ton, and 800 kg, respectively; this would increase the emission rate of pollutant SO2 up to 150 ton annually. Finally, the new data of pollution coming from unit 75 were compared to pollution standard at American refineries. Results showed that the emission factor of most pollutants were below the American standard limits. However, the emission factor of sulfur dioxide emitted from upgraded furnace of unit 75 surpassed the American standard values. Fuel gas needs to be free of hydrogen sulfide in order to decrease SO2 emission in unit 75. It is predicted that the renovation of other 11 old furnaces belonging to Abadan refinery will result in significant decrease of pollutants CO, CxHx and H2S up to 320, 94 and 76 ton annually.

  7. A Spatial Risk Analysis of Oil Refineries within the United States

    Science.gov (United States)

    2012-03-01

    Daniels, V. (2003, November 24). Review of Literature: Responses to "Empirical and Hermeneutic Approaches to Phenomenological Research in Psychology ...a Comparison. Retrieved May 31, 2011 , from Gestalt -L: http://www.g-gej.org/5-2/reviewlit.html Cox, J. A. (2008). Limitations of "Risk = Threat x...May, 2011, from Stanford Encyclopedia of Psychology : http://plato.stanford.edu/entries/game- theory/#Neu47 96 Rusco, F. (2008). Refinery Outages

  8. PetroChina and Sinopec Raises Oil Ex-refinery Prices

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    @@ Sinopec and PetroChina have raised ex-refinery prices for gasoline and diesel to boost sagging margins as it faces soaring crude prices. The Chinese refiners increased 90-octane gasoline price by 100 yuan (US$12) a ton to about 3,580 yuan (US$432) a ton, and that of diesel by 40 yuan (US$4.80) a ton to 3,602 yuan (US$435),effective September 17.

  9. PetroChina and Kuwait to Construct Joint Venture Refinery in South China

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    @@ PetroChina, China's largest oil producer and Asia's most profitable company, and Kuwait may build a planned joint venture oil refinery in South China's Pearl River Delta area, according to Guangdong Province's Executive Vice Governor Zhong Yangsheng, who told reporters at the Boao Forum for Asia in Hainan Province in late April.However, he declined to provide further details. The Pearl River Delta region accounts for about a third of the nation's exports.

  10. Microbial community succession in alkaline, saline bauxite residue: a cross-refinery study

    Science.gov (United States)

    Santini, T.; Malcolm, L. I.; Tyson, G. W.; Warren, L. A.

    2015-12-01

    Bauxite residue, a byproduct of the Bayer process for alumina refining, is an alkaline, saline tailings material that is generally considered to be inhospitable to microbial life. In situ remediation strategies promote soil formation in bauxite residue by enhancing leaching of saline, alkaline pore water, and through incorporation of amendments to boost organic matter content, decrease pH, and improve physical structure. The amelioration of chemical and physical conditions in bauxite residue is assumed to support diversification of microbial communities from narrow, poorly functioning microbial communities towards diverse, well-functioning communities. This study aimed to characterise microbial communities in fresh and remediated bauxite residues from refineries worldwide, to identify (a) whether initial microbial communities differed between refineries; (b) major environmental controls on microbial community composition; and (c) whether remediation successfully shifts the composition of microbial communities in bauxite residue towards those found in reference (desired endpoint) soils. Samples were collected from 16 refineries and characterised using 16S amplicon sequencing to examine microbial community composition and structure, in conjunction with physicochemical analyses. Initial microbial community composition was similar across refineries but partitioned into two major groups. Microbial community composition changes slowly over time and indicates that alkalinity and salinity inhibit diversification. Microbially-based strategies for in situ remediation should consider the initial microbial community composition and whether the pre-treatment of chemical properties would optimise subsequent bioremediation outcomes. During in situ remediation, microbial communities become more diverse and develop wider functional capacity, indicating progression towards communities more commonly observed in natural grassland and forest soils.

  11. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses

  12. Identification of wastewater processes

    DEFF Research Database (Denmark)

    Carstensen, Niels Jacob

    -known theory of the processes with the significant effects found in data. These models are called grey box models, and they contain rate expressions for the processes of influent load of nutrients, transport of nutrients between the aeration tanks, hydrolysis and growth of biomass, nitrification...... function. The grey box models are estimated on data sets from the Lundtofte pilot scale plant and the Aalborg West wastewater treatment plant. Estimation of Monod- kinetic expressions is made possible through the application of large data sets. Parameter extimates from the two plants show a reasonable......The introduction of on-line sensors for monitoring of nutrient salts concentrations on wastewater treatment plants with nutrient removal, opens a wide new area of modelling wastewater processes. The subject of this thesis is the formulation of operational dynamic models based on time series...

  13. Treatment of electroplating wastewater

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    To study the feasibility of treated water being used as rinsing water with CP/ED (chemical precipitation/electrodialysis) system, the relation between concentration of Cr (VI) and conductivity of water is investigated, the effect of electrodialysis (ED) for different wastewater is also studied. And several parameters of importance that are relevant to the process are identified. Analysis of ICP (Inductively coupled plasma) and IC (Ion chromatography) shows that the main reason of conductivity increase in CP treated water is the increase of Na+ and Cl- ions. The 93.8%-100% of ions from wastewater both in ED and CP/ED systems was removed successfully. The results of experiments indicate that the CP/ED system is a feasible method for electroplating wastewater treatment, the CP/ED system used as a way of wastwater is not only in favour of environment, but also economic beneficial to achieve.

  14. Optimization of operating conditions of distillation columns: an energy saving option in refinery industry

    Directory of Open Access Journals (Sweden)

    Alireza Fazlali

    2010-01-01

    Full Text Available While energy prices continue to climb, it conservation remains the prime concern for process industries. The daily growth of energy consumption throughout the world and the real necessity of providing it, shows that optimization of energy generation and consumption units is an economical and sometimes vital case. Hence, the optimization of a petroleum refinery is aimed towards great production and an increase in quality. In this research, the atmospheric distillation unit of the Iran-Arak-Shazand petroleum refinery was subject to optimization efforts. It was performed by the means of using a simulator with the aim to earn more overhead products. In the next step the optimization results from the simulators were carried out in the real world, at the above mentioned unit. Results demonstrate that the changes in the real operating conditions increase the overhead products with desirable quality. Finally, a net economical balance between the increments of the overhead products and the energy consumption shows an energy saving in this refinery.

  15. Exergy and exergoeconomic analysis of a petroleum refinery utilities plant using the condensing to power method

    Energy Technology Data Exchange (ETDEWEB)

    Mendes da Silva, Julio Augusto; Pellegrini, Luiz Felipe; Oliveira Junior, Silvio [Polytechnic School of the University of Sao Paulo, SP (Brazil)], e-mails: jams@usp.br, luiz.pellegrini@usp.br, soj@usp.br; Plaza, Claudio; Rucker, Claudio [Petrobras - Petroleo Brasileiro S.A., Rio de Janeiro, RJ (Brazil)], e-mails: claudioplaza@petrobras.com.br, rucker@petrobras.com.br

    2010-07-01

    In this paper a brief description of the main processes present in a modern high capacity refinery is done. The methodology used to evaluate, through exergy analysis, the performance of the refinery's utilities plant since it is responsible for a very considerable amount of the total exergy destruction in a refinery is presented. The utilities plant products: steam, electricity, shaft power and high pressure water had their exergy unit cost determined using exergoeconomic approach. A simple and effective method called condensing to power was used to define the product of the condensers in exergy basis. Using this method it is possible to define the product of the condenser without the use of negentropy concept nor the aggregation of condensers to the steam turbines. By using this new approach, the costs obtained for the plant's products are exactly the same costs obtained when the condenser is aggregated to the steam turbine but with the advantage that the information about the stream between condenser and the steam turbine is not lost and the condenser can be evaluated singly. The analysis shows that the equipment where attention and resources should be focused are the boilers followed by the gas turbine, that together, are responsible for 80% of total exergy destruction in the utilities plant. The total exergy efficiency found for the utilities plant studied is 35% while more than 280 MW of exergy is destroyed in the utilities processes. (author)

  16. Analysis on Refinery System as a Complex Task-resource Network

    Institute of Scientific and Technical Information of China (English)

    LIU Suyu; RONG Gang

    2013-01-01

    Refinery system,a typical example of process systems,is presented as complex network in this paper.The topology of this system is described by task-resource network and modeled as directed and weighted graph,in which nodes represent various tasks and edges denote the resources exchanged among tasks.Using the properties of node degree distribution,strength distribution and other weighted quantities,we demonstrate the heterogeneity of the network and point out the relation between structural characters of vertices and the functionality of corresponding tasks.The above phenomena indicate that the design requirements and principles of production process contribute to the heterogeneous features of the network.Besides,betweenness centrality of nodes can be used as an importance indicator to provide additional information for decision making.The correlations between structure and weighted properties are investigated to further address the influence brought by production schemes in system connectivity patterns.Cascading failures model is employed to analyze the robustness of the network when targeted attack happens.Two capacity assignment strategies are compared in order to improve the robustness of the network at certain cost.The refinery system displays more reliable behavior when the protecting strategy considers heterogeneous properties.This phenomenon further implies the structure-activity relationship of the refinery system and provides insightful suggestions for process system design.The results also indicate that robustness analysis is a promising application of methodologies from complex networks to process system engineering.

  17. Production of ethanol from refinery waste gases. Phase 2, technology development, annual report

    Energy Technology Data Exchange (ETDEWEB)

    Arora, D.; Basu, R.; Phillips, J.R.; Wikstrom, C.V.; Clausen, E.C.; Gaddy, J.L.

    1995-07-01

    Oil refineries discharge large volumes of H{sub 2}, CO, and CO{sub 2} from cracking, coking, and hydrotreating operations. This program seeks to develop a biological process for converting these waste gases into ethanol, which can be blended with gasoline to reduce emissions. Production of ethanol from all 194 US refineries would save 450 billion BTU annually, would reduce crude oil imports by 110 million barrels/year and emissions by 19 million tons/year. Phase II efforts has yielded at least 3 cultures (Clostridium ljungdahlii, Isolate O-52, Isolate C-01) which are able to produce commercially viable concentrations of ethanol from CO, CO{sub 2}, and H{sub 2} in petroleum waste gas. Single continuous stirred tank reactor studies have shown that 15-20 g/L of ethanol can be produced, with less than 5 g/L acetic acid byproduct. Culture and reactor optimization in Phase III should yield even higher ethanol concentrations and minimal acetic acid. Product recovery studies showed that ethanol is best recovered in a multi-step process involving solvent extraction/distillation to azeotrope/azeotropic distillation or pervaporation, or direct distillation to the azeotrope/azeotropic distillation or pervaporation. Projections show that the ethanol facility for a typical refinery would require an investment of about $30 million, which would be returned in less than 2 years.

  18. Bioremediation of oil refinery sludge by landfarming in semiarid conditions: influence on soil microbial activity.

    Science.gov (United States)

    Marin, J A; Hernandez, T; Garcia, C

    2005-06-01

    Bioremediation of a refinery sludge containing hydrocarbons in a semi-arid climate using landfarming techniques is described. The objective of this study was to assess the ability of this technique to reduce the total hydrocarbon content added to the soil with the refinery sludge in semiarid climate (low rain and high temperature). In addition, we have evaluated the effect of this technique on the microbial activity of the soil involved. For this, biological parameters (carbon fractions, microbial biomass carbon, basal respiration and ATP) and biochemical parameters(different enzymatic activities) were determined. The results showed that 80% of the hydrocarbons were eliminated in eleven months, half of this reduction taking place during the first three months. The labile carbon fractions, MBC, basal respiration and ATP of the soils submitted to landfarming showed higher values than the control soil during the first months of the process, although these values fell down by the end of the experimental period as the hydrocarbons were degraded by mineralisation. All the enzymatic activities studied: oxidoreductases such as dehydrogenase activity, and hydrolases of C(beta-glucosidase activity) and N Cycle (urease and protease) showed higher values in the soils amended with the refinery sludge than in the control. As in the case of the previous parameters, these value fell down as the bioremediation of the hydrocarbons progressed, many of them reaching levels similar to those of the control soil after eleven months.

  19. Plant biotests in the bioindication of the rainfall pollution in an oil refinery region

    Energy Technology Data Exchange (ETDEWEB)

    Zukowska-Wieszczek, D.; Zimny, H.

    1980-01-01

    Rainfall was collected during spring and summer at four points localized in the vicinity of the largest oil refinery in Europe. The rain water was analyzed chemically by atomic absorption spectroscopy. Sulfur was estimated by nephelometric methods, chlorine was measured argentometrically and pH, electrometrically. Beans, beetroot and cucumber were grown in the rainwater. Rainwater collected near the industrial and oil refinery regions had a pH value ranging from 2.4 to 4.4. Chemical analysis showed that the water was high in minerals and pollution by heavy metal ions as well as having increased acidity due to sulfates, nitrates and nitrites. The germination capacity of seeds treated with rain water from the refinery region was significantly decreased in comparison to those germinating on distilled water. Impairment of seed germination capacity was higher for seeds germinating on water from the summer than from the spring rainfalls. Seedling growth, while vigorous at first, soon showed signs of shortening and thickening of the hypocotyl and maceration of root-cap. Beetroot showed the most significant changes. 5 references, 4 tables.

  20. Corrosion monitoring in the oil refinery LUKoil-Neftochim-Burgas AD, Bulgaria

    Energy Technology Data Exchange (ETDEWEB)

    Stoyanov, V.; Papazov, B. [Laboratory Corrosion Protection, LUKoil-Neftochim Burgas AD, Strandsha str. 20 A, 8001-Burgas (Bulgaria)

    2004-07-01

    A great variety of corrosion processes are observed on the territory of the Oil Refinery LUKoil-Neftochim Burgas AD, Bulgaria. They are a result of aggressive action of wide range of chemical active reagents and environments, industrial atmosphere with sea climate influence and underground water with varied composition. Substantial corrosion monitoring is used in oil distillation plant, petrochemical and other refinery units. A part of the most important cases of successfully solved corrosion problems are included in this paper - corrosion in Ethyl-benzene unit alcilators, corrosion protection of equipment and floors in concentrated sulfuric acid in the Sulfuric Acid Alkylation plant, corrosion protection of electro-filters in the Chemical Cleaning of Service Water System, chemical resistant floor in PAN and AN plant, outside varnish protection of tanks, vessels, pumps, steelworks etc. There are many proper solutions suggested, including wide range of coatings and new resistant materials offered by well-known companies - Hempel, Chesterton, Permatex DuPont, Paint International and many others which work in close collaboration with our laboratory. Those problems are typical of all oil refineries and petrochemical plants and are possible to be applied successfully. (authors)

  1. Bioactive Compounds of Palm Fatty Acid Distillate (PFAD from Several Palm Oil Refineries

    Directory of Open Access Journals (Sweden)

    Teti Estiasih

    2013-09-01

    Full Text Available This research studied the characteristics of Palm Fatty Acids Distillates (PFADs from several palm oil refineries. It was aimed to know the potency of PFAD as bioactive compounds source, including vitamin E (mainly tocotrienols, phytosterols, squalene and possibly co-enzyme Q10 and polycosanol. Sampling was conducted at 6 palm oil refineries. The results showed that PFAD was dominated by free fatty acids of 85-95% with low oxidation level indicated by peroxide value of 1-10 meq/kg and anisidin value of 6-31. Bioactive compounds found were vitamin E 60-200 ppm, phytosterols 400-7500 ppm and squalene 400-2800 ppm, meanwhile polycosanol and co-enzyme Q10 were not found. Vitamin E was dominated by tocotrienols and γ tocotrienol was the major vitamin E, followed by α and δ tocotrienols. Phytosterols in PFADs from several palm oil refineries had variety in quantity and composition. Generally it was dominated by &beta sitosterol, followed by stigmasterol and campesterol

  2. Who lives near coke plants and oil refineries An exploration of the environmental inequity hypothesis

    Energy Technology Data Exchange (ETDEWEB)

    Graham, J.D.; Beaulieu, N.D.; Sussman, D.; Sadowitz, M.; Li, Y.C. (Harvard Center for Risk Analysis, Boston, MA (United States))

    1999-04-01

    Facility-specific information on pollution was obtained for 36 coke plants and 46 oil refineries in the US and matched with information on populations surrounding these 82 facilities. These data were analyzed to determine whether environmental inequities were present, whether they were more economic or racial in nature, and whether the racial composition of nearby communities has changed significantly since plants began operations. The Census tracts near coke plants have a disproportionate share of poor and nonwhite residents. Multivariate analyses suggest that existing inequities are primarily economic in nature. The findings for oil refineries are not strongly supportive of the environmental inequity hypothesis. Rank ordering of facilities by race, poverty, and pollution produces limited (although not consistent) evidence that the more risky facilities tend to be operating in communities with above-median proportions of nonwhite residents (near coke plants) and Hispanic residents (near oil refineries). Over time, the radical makeup of many communities near facilities has changed significantly, particularly in the case of coke plants sited in the early 1900s. Further risk-oriented studies of multiple manufacturing facilities in various industrial sectors of the economy are recommended.

  3. Consequence modeling of fire on Methane storage tanks in a gas refinery

    Directory of Open Access Journals (Sweden)

    Sara Shahedi ali abadi

    2016-06-01

    Full Text Available Introduction: using fossil fuels, some hazards such as explosion and fire are probable. This study was aimed to consequence modeling of fire on Methane storage tanks in a gas refinery using analyzing the risk, and modeling and evaluating the related consequences. Method: Hazard analysis by PHA was used to choosing the worst-case scenario. Then, causes of the scenario were determined by FTA. After that, consequence modeling by the PHAST software was applied for the consequence analysis. Results: Based on some criteria, the fire of methane gas tank (V-100 was selected as the worst-case scenario at the refinery. The qualitative fault tree showed three factors including mechanical, process, and human failures contribute in gas leakage. The leakage size and weather conditions were effective on the distance of radiation. Using consequence modeling, thermal radiation was considered as the major outcome of the incident. Finally, for outcome evaluating, probit equations were used to quantify losses and the percentage of fatalities due to the methane gas leakage and fire occurrence. The maximum number of fatalities caused by fire was obtained 23 persons. Conclusions: In conclusion, the methane gas vessel in the refinery can be considered as the main center of hazard, therefore the implementation of the safety rules, eliminating mechanical failures, personal protection and education, and Effective measures to prevent and fighting of fire are proposed for decreasing the probable losses and fatalities.

  4. 炼油污水处理场恶臭污染及其治理研究%MALODOR POLLUTION FROM REFINERY SEWAGE TREATMENT SYSTEM AND TREATMENT TECHNOLOGY

    Institute of Scientific and Technical Information of China (English)

    刘忠生; 郭兵兵; 王玉亭; 刘念曾

    2003-01-01

    Main malodor pollutants from oil separator of Refinery A are hydrocarbons and a small quantity of sulfides. Main malodor pollutants from surface aeration tank of Refinery B are sulfides, especially CH3SH. And main malodor pollutants from bubbling aeration tank of Refinery C are also sulfides, of which H2S concentration is the highest. Catalytic combustion technology is applied to treat malodorous gas from oil separator of Refinery A, in which the total hydrocarbon removal was over 97%. The purified gas meets the national standard. Activated carbon adsorption is used to treat malodorous gas from surface aeration tank of Refinery B, and main pollutant CH3SH removal reached up to 98%~100%. As for malodorous gas from bubbling aeration tank of Refinery C, bio-packing tower is used and the removals of hydrogen sulfide, organic sulfides and benzene series reached up to 80%~98%.

  5. Wastewater treatment models

    DEFF Research Database (Denmark)

    Gernaey, Krist; Sin, Gürkan

    2011-01-01

    The state-of-the-art level reached in modeling wastewater treatment plants (WWTPs) is reported. For suspended growth systems, WWTP models have evolved from simple description of biological removal of organic carbon and nitrogen in aeration tanks (ASM1 in 1987) to more advanced levels including...... of WWTP modeling by linking the wastewater treatment line with the sludge handling line in one modeling platform. Application of WWTP models is currently rather time consuming and thus expensive due to the high model complexity, and requires a great deal of process knowledge and modeling expertise...

  6. Wastewater Treatment Models

    DEFF Research Database (Denmark)

    Gernaey, Krist; Sin, Gürkan

    2008-01-01

    The state-of-the-art level reached in modeling wastewater treatment plants (WWTPs) is reported. For suspended growth systems, WWTP models have evolved from simple description of biological removal of organic carbon and nitrogen in aeration tanks (ASM1 in 1987) to more advanced levels including...... the practice of WWTP modeling by linking the wastewater treatment line with the sludge handling line in one modeling platform. Application of WWTP models is currently rather time consuming and thus expensive due to the high model complexity, and requires a great deal of process knowledge and modeling expertise...

  7. Smart microgrids in refineries, Mexico case; Microrredes inteligentes en refinerias, caso Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Estrada Garcia, Javier Alejandro; Linan Garcia, Roberto; Picasso Blanquel, Cuitlahuac; Silva Farias, Jose Luis [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2013-03-01

    In this paper we present the technological trends on smart microgrids for refineries, case Mexico. Distributed generation on refineries is a model of microgrid with great challenges to solve, considering renewable energy. Also it discusses the scenario in bidirectional connection from refineries to the utility supergrid Comision Federal de Electricidad (CFE by its acronym in Spanish) and how to reach the development of a smart microgrid. We look different scenarios in power systems refineries, and the feasibility to achieve and develop the technology concepts in smart grid, such as: demand response in real time, exchange of energy between microgrid with supergrid-CFE and viceversa, energy efficiency, microgrid automation, selfhealing/real time autorecovery fault in power systems, storage energy and its application on power systems blackout in refineries. Finally we discussed the concepts that represent the greatest challenges to be solved on the smart microgrids and consider obtaining alternatives solution in medium or long term. [Spanish] En este documento se presentan las tendencias tecnologicas en micro redes inteligentes para refinerias, en el caso de Mexico. La generacion distribuida en refinerias es un modelo de micro red con grandes desafios por resolver, considerando la energia renovable. Se analiza tambien el escenario en conexion bidireccional de refinerias a la super red de la Comision Federal de Electricidad (CFE), la empresa electrica mexicana, y como lograr el desarrollo de una micro red inteligente. Se consideran diferentes escenarios en refinerias de sistemas de potencia, y la factibilidad de alcanzar y desarrollar los conceptos de tecnologia en una red inteligente, tales como: respuesta de demanda en tiempo real, intercambio de energia entre la micro red con la super red de la CFE y viceversa, eficiencia de energia, automatizacion de micro redes, autorrecuperacion de fallas en autoarreglo/tiempo real. En sistemas de potencia, almacenamiento de

  8. Microalgae and wastewater treatment

    Science.gov (United States)

    Abdel-Raouf, N.; Al-Homaidan, A.A.; Ibraheem, I.B.M.

    2012-01-01

    Organic and inorganic substances which were released into the environment as a result of domestic, agricultural and industrial water activities lead to organic and inorganic pollution. The normal primary and secondary treatment processes of these wastewaters have been introduced in a growing number of places, in order to eliminate the easily settled materials and to oxidize the organic material present in wastewater. The final result is a clear, apparently clean effluent which is discharged into natural water bodies. This secondary effluent is, however, loaded with inorganic nitrogen and phosphorus and causes eutrophication and more long-term problems because of refractory organics and heavy metals that are discharged. Microalgae culture offers an interesting step for wastewater treatments, because they provide a tertiary biotreatment coupled with the production of potentially valuable biomass, which can be used for several purposes. Microalgae cultures offer an elegant solution to tertiary and quandary treatments due to the ability of microalgae to use inorganic nitrogen and phosphorus for their growth. And also, for their capacity to remove heavy metals, as well as some toxic organic compounds, therefore, it does not lead to secondary pollution. In the current review we will highlight on the role of micro-algae in the treatment of wastewater. PMID:24936135

  9. Microalgae and wastewater treatment.

    Science.gov (United States)

    Abdel-Raouf, N; Al-Homaidan, A A; Ibraheem, I B M

    2012-07-01

    Organic and inorganic substances which were released into the environment as a result of domestic, agricultural and industrial water activities lead to organic and inorganic pollution. The normal primary and secondary treatment processes of these wastewaters have been introduced in a growing number of places, in order to eliminate the easily settled materials and to oxidize the organic material present in wastewater. The final result is a clear, apparently clean effluent which is discharged into natural water bodies. This secondary effluent is, however, loaded with inorganic nitrogen and phosphorus and causes eutrophication and more long-term problems because of refractory organics and heavy metals that are discharged. Microalgae culture offers an interesting step for wastewater treatments, because they provide a tertiary biotreatment coupled with the production of potentially valuable biomass, which can be used for several purposes. Microalgae cultures offer an elegant solution to tertiary and quandary treatments due to the ability of microalgae to use inorganic nitrogen and phosphorus for their growth. And also, for their capacity to remove heavy metals, as well as some toxic organic compounds, therefore, it does not lead to secondary pollution. In the current review we will highlight on the role of micro-algae in the treatment of wastewater.

  10. Modelling of wastewater systems

    DEFF Research Database (Denmark)

    Bechmann, Henrik

    In this thesis, models of pollution fluxes in the inlet to 2 Danish wastewater treatment plants (WWTPs) as well as of suspended solids (SS) concentrations in the aeration tanks of an alternating WWTP and in the effluent from the aeration tanks are developed. The latter model is furthermore used...

  11. Study on Naphthenic Acid Sodium Wastewater Treatment by Flocculation Magnetic Separation Technology%絮凝磁分离技术处理环烷酸钠废水的研究

    Institute of Scientific and Technical Information of China (English)

    鲁风芹; 李兴盼; 孙文

    2011-01-01

    环烷酸钠是导致炼油废水不能达标排放的主要原因,文章采用絮凝磁分离技术处理环烷酸钠废水,研究各因素对实验结果的影响,确定最佳处理条件,并对实际废水进行了实验研究,结果表明该技术可有效去除炼油废水中的CODcr.%The naphthenic acid sodium is the main reason causing the refinery wastewater failed to meet the requirement of discharging. This paper adopts flocculation magnetic separation technology to treat naphthenic acid sodium wastewater through studying the influence of each factor on the experiment to determine the optimum conditions. Then the actual wastewater was treated. The resuhs show that this technology can remove the COD or of refinery wastewater effectively.

  12. CARBON ACCOUNTING INITIATIVES: CASE STUDY OF A PETROLEUM REFINERY IN MALAYSIA TO PREPARE FOR FUTURE CARBON MARKET

    Directory of Open Access Journals (Sweden)

    AMANDA H.L. CHEE

    2010-06-01

    Full Text Available Petroleum refining process produces a large amount of atmospheric pollutants including greenhouse gases which are attributed to global warming. The international community inevitably addressed the global warming issue by introducing a market-based mechanism known as Emission Trading Systems (ETS under the Kyoto Protocol which imposes binding limits to developed nations using three flexibility mechanisms, including the Clean Development Mechanism (CDM. This case study was carried out in a petroleum refinery in Malaysia to explore the possibility for the refinery to participate in CDM. Information was collected through observatory field survey at the refinery and documentation review. Results show that the current monitoring tool using indirect calculation of fuel consumption provides a comprehensive coverage of emission sources but the reporting frequency should be increased for data accuracy. An accounting system was then created to predict the emissions gap of the refinery with reference to the baseline-year set by the Kyoto Protocol. It was concluded that the refinery showed promising potential to participate in CDM to benefit from technology transfer by selling their ‘credits’ to Annex I countries despite the uncertainty on the impact of the carbon market in a Non-Annex I country.

  13. Isolation and characterization of phenol degrading yeasts from wastewater in the coking plant of Zarand, Kerman.

    Science.gov (United States)

    Karimi, Maryam; Hassanshahian, Mehdi

    2016-01-01

    Phenol and phenolic compounds are environmental pollutants present in industrial wastewaters such as coal tar, oil refineries and petrochemical plants. Phenol removal from industrial effluents is extremely important for the protection of environment. Usually, phenol degradation is carried out by physicochemical methods that are costly and produce hazardous metabolites. Recently, phenol biodegradation has been considered. Yeasts are the most important phenol biodegraders. In this study, the phenol-degrading yeast from environmental samples (soil and wastewater) was isolated from the coking plant of Zarand, Kerman. Then total heterotrophic yeasts were counted. The soil samples had higher rates of yeast degrader, in comparison to wastewater samples. After three passages, four yeasts (K1, K2, K7 and K11) that had the highest growth rate were selected for further study. Also, these yeasts were able to remove phenol measured by Gibbs reagent. The effect of four different concentrations of phenol (50, 125, 200 and 275) mgL(-1) was measured and three degradation patterns in these yeasts were observed. The hydrophobicity and emulsification activity were measured in all eleven yeasts. Finally, strong yeasts in phenol degrading yeasts were identified by molecular method using amplification of 18S rRNA gene region. The sequencing results showed that these isolated yeasts belonged to Candida tropicalis strain K1, Pichia guilliermondii strain K2, Meyerozyma guilliermondii strain K7 and C. tropicalis strain K11.

  14. Isolation and characterization of phenol degrading yeasts from wastewater in the coking plant of Zarand, Kerman

    Directory of Open Access Journals (Sweden)

    Maryam Karimi

    2016-03-01

    Full Text Available Abstract Phenol and phenolic compounds are environmental pollutants present in industrial wastewaters such as coal tar, oil refineries and petrochemical plants. Phenol removal from industrial effluents is extremely important for the protection of environment. Usually, phenol degradation is carried out by physicochemical methods that are costly and produce hazardous metabolites. Recently, phenol biodegradation has been considered. Yeasts are the most important phenol biodegraders. In this study, the phenol-degrading yeast from environmental samples (soil and wastewater was isolated from the coking plant of Zarand, Kerman. Then total heterotrophic yeasts were counted. The soil samples had higher rates of yeast degrader, in comparison to wastewater samples. After three passages, four yeasts (K1, K2, K7 and K11 that had the highest growth rate were selected for further study. Also, these yeasts were able to remove phenol measured by Gibbs reagent. The effect of four different concentrations of phenol (50, 125, 200 and 275 mg L−1 was measured and three degradation patterns in these yeasts were observed. The hydrophobicity and emulsification activity were measured in all eleven yeasts. Finally, strong yeasts in phenol degrading yeasts were identified by molecular method using amplification of 18S rRNA gene region. The sequencing results showed that these isolated yeasts belonged to Candida tropicalis strain K1, Pichia guilliermondii strain K2, Meyerozyma guilliermondii strain K7 and C. tropicalis strain K11.

  15. Trends in oil discharged with aqueous effluents from oil refineries in Europe. 2010 survey data

    Energy Technology Data Exchange (ETDEWEB)

    Baldoni-Andrey, P.; Girling, A.; Bakker, A.; Muller, A.; Struijk, K.; Fotiadou, I.; Andres Huertas, A.; Negroni, J.; Neal, G.; Den Haan, K.

    2012-10-15

    This report summarises data gathered by CONCAWE in a 2010 survey of effluent water quantity, oil content and treatment processes for refinery installations situated in the EU-27 countries and those in Croatia Norway and Switzerland. Data obtained in previous surveys are included for comparison. Operators of 100 installations completed questionnaires, of which two of these only reported data for water intake and discharge. The number of 100 reporting locations is lower than the 125 locations that reported in 2008. There are several reasons for this. Since the last data gathering exercise several refinery installations have been closed or moth-balled, turning these into fuels depots without any production. Another four sites that are still operating today informed CONCAWE that these would not be in a position to complete the questionnaire for 2010. Finally, the ownership of some installations changed since 2008, leading to CONCAWE being unable to identify an appropriate contact person for timely completion of the questionnaire. The data provided through the completion of the questionnaire have been extracted into an MS-ACCESS Database. This enabled sorting, extraction, analyses and presentation of the information in a range of formats. The information presented in this report relates to a selected range of parameters that have been covered by previous surveys carried out since 1969. Two further reports will cover the results of the complete survey in more detail; one concerning final discharge quality parameters and the other focussing on water use and consumption. The results reported herein show that the volume of process water that was being discharged from EU-27+3 (Norway, Croatia and Switzerland) - located refineries decreased between 2008 and 2010 while the overall volume of aqueous discharges remained about the same or slightly increased over the same period. When expressed relative to refinery capacities and throughputs there is a slight increase in 2010 in

  16. Removal of Oil and Grease as Emerging Pollutants of Concern (EPC in Wastewater Stream

    Directory of Open Access Journals (Sweden)

    Alade Abass O

    2011-12-01

    Full Text Available Wastewater characteristics, which depend on wastewater source, are increasingly becoming more toxic in recent times. The concentrations of oil and grease in wastewater streams have been observed to increase in wastewater stream with increasing adverse effects on the ecology. This results from the increasing use of oil and grease in high-demanded oil-processed foods, establishment and expansion of oil mills and refineries worldwide, as well as indiscriminate discharge of oil and grease into the water drains, domestically and industrially. This study reports the applications, efficiencies and challenges of the wastewater treatment techniques currently employed in the removal of oil and grease from the industrial wastewater and municipal water stream. The results shows that the concentrations of oil and grease injected into the ecosystem are of higher environmental impact and this needs to be given the desired attention. The desired development for effective removal of oil and grease as emerging pollutants of concern (EPC in wastewater stream are thus proposed. ABSTRAK: Ciri-ciri air sisa, bergantung kepada punca air sisa tersebut, menjadi semakin toksik akhir-akhir ini. Kepekatan minyak dan gris dalam air sisa anak sungai dilihat makin bertambah dalam air sisa anak sungai dengan bertambahnya kesan negatif ke atas ekologi. Ini disebabkan oleh peningkatan penggunaan minyak dan gris dalam makanan berproses yang tinggi permintaannya, penubuhan dan perkembangan kilang pertroleum dan loji penapisan di seluruh dunia. Minyak dan gris juga dibuang sewenang-wenangnya ke dalam parit air, dari kalangan domestik dan industry. Kajian ini membentangkan tentang aplikasi, keberkesanan dan teknik cabaran rawatan air buangan yang kini digunakan dalam pembuangan minyak dan gris dari air sisa industry dan air sungai perbandaran. Keputusan menunjukkan kepekatan minyak dan gris yang wujud dibuang ke dalam ekosistem mempunyai impak yang lebih tinggi terhadap persekitaran

  17. Application of a continuously stirred tank bioreactor (CSTR) for bioremediation of hydrocarbon-rich industrial wastewater effluents

    Energy Technology Data Exchange (ETDEWEB)

    Gargouri, Boutheina; Karray, Fatma; Mhiri, Najla; Aloui, Fathi [Laboratoire des Bioprocedes Environnementaux, Pole d' Excellence Regional AUF-LBPE, Centre de Biotechnologie de Sfax, Universite de Sfax, BP 1117, 3018 Sfax (Tunisia); Sayadi, Sami, E-mail: sami.sayadi@cbs.rnrt.tn [Laboratoire des Bioprocedes Environnementaux, Pole d' Excellence Regional AUF-LBPE, Centre de Biotechnologie de Sfax, Universite de Sfax, BP 1117, 3018 Sfax (Tunisia)

    2011-05-15

    A continuously stirred tank bioreactor (CSTR) was used to optimize feasible and reliable bioprocess system in order to treat hydrocarbon-rich industrial wastewaters. A successful bioremediation was developed by an efficient acclimatized microbial consortium. After an experimental period of 225 days, the process was shown to be highly efficient in decontaminating the wastewater. The performance of the bioaugmented reactor was demonstrated by the reduction of COD rates up to 95%. The residual total petroleum hydrocarbon (TPH) decreased from 320 mg TPH l{sup -1} to 8 mg TPH l{sup -1}. Analysis using gas chromatography-mass spectrometry (GC-MS) identified 26 hydrocarbons. The use of the mixed cultures demonstrated high degradation performance for hydrocarbons range n-alkanes (C10-C35). Six microbial isolates from the CSTR were characterized and species identification was confirmed by sequencing the 16S rRNA genes. The partial 16S rRNA gene sequences demonstrated that 5 strains were closely related to Aeromonas punctata (Aeromonas caviae), Bacillus cereus, Ochrobactrum intermedium, Stenotrophomonas maltophilia and Rhodococcus sp. The 6th isolate was affiliated to genera Achromobacter. Besides, the treated wastewater could be considered as non toxic according to the phytotoxicity test since the germination index of Lepidium sativum ranged between 57 and 95%. The treatment provided satisfactory results and presents a feasible technology for the treatment of hydrocarbon-rich wastewater from petrochemical industries and petroleum refineries.

  18. Application of a continuously stirred tank bioreactor (CSTR) for bioremediation of hydrocarbon-rich industrial wastewater effluents.

    Science.gov (United States)

    Gargouri, Boutheina; Karray, Fatma; Mhiri, Najla; Aloui, Fathi; Sayadi, Sami

    2011-05-15

    A continuously stirred tank bioreactor (CSTR) was used to optimize feasible and reliable bioprocess system in order to treat hydrocarbon-rich industrial wastewaters. A successful bioremediation was developed by an efficient acclimatized microbial consortium. After an experimental period of 225 days, the process was shown to be highly efficient in decontaminating the wastewater. The performance of the bioaugmented reactor was demonstrated by the reduction of COD rates up to 95%. The residual total petroleum hydrocarbon (TPH) decreased from 320 mg TPH l(-1) to 8 mg TPH l(-1). Analysis using gas chromatography-mass spectrometry (GC-MS) identified 26 hydrocarbons. The use of the mixed cultures demonstrated high degradation performance for hydrocarbons range n-alkanes (C10-C35). Six microbial isolates from the CSTR were characterized and species identification was confirmed by sequencing the 16S rRNA genes. The partial 16S rRNA gene sequences demonstrated that 5 strains were closely related to Aeromonas punctata (Aeromonas caviae), Bacillus cereus, Ochrobactrum intermedium, Stenotrophomonas maltophilia and Rhodococcus sp. The 6th isolate was affiliated to genera Achromobacter. Besides, the treated wastewater could be considered as non toxic according to the phytotoxicity test since the germination index of Lepidium sativum ranged between 57 and 95%. The treatment provided satisfactory results and presents a feasible technology for the treatment of hydrocarbon-rich wastewater from petrochemical industries and petroleum refineries.

  19. Wastewater treatment models

    DEFF Research Database (Denmark)

    Gernaey, Krist; Sin, Gürkan

    2011-01-01

    The state-of-the-art level reached in modeling wastewater treatment plants (WWTPs) is reported. For suspended growth systems, WWTP models have evolved from simple description of biological removal of organic carbon and nitrogen in aeration tanks (ASM1 in 1987) to more advanced levels including...... of WWTP modeling by linking the wastewater treatment line with the sludge handling line in one modeling platform. Application of WWTP models is currently rather time consuming and thus expensive due to the high model complexity, and requires a great deal of process knowledge and modeling expertise....... Efficient and good modeling practice therefore requires the use of a proper set of guidelines, thus grounding the modeling studies on a general and systematic framework. Last but not least, general limitations of WWTP models – more specifically activated sludge models – are introduced since these define...

  20. Wastewater Treatment Models

    DEFF Research Database (Denmark)

    Gernaey, Krist; Sin, Gürkan

    2008-01-01

    The state-of-the-art level reached in modeling wastewater treatment plants (WWTPs) is reported. For suspended growth systems, WWTP models have evolved from simple description of biological removal of organic carbon and nitrogen in aeration tanks (ASM1 in 1987) to more advanced levels including...... the practice of WWTP modeling by linking the wastewater treatment line with the sludge handling line in one modeling platform. Application of WWTP models is currently rather time consuming and thus expensive due to the high model complexity, and requires a great deal of process knowledge and modeling expertise....... Efficient and good modeling practice therefore requires the use of a proper set of guidelines, thus grounding the modeling studies on a general and systematic framework. Last but not least, general limitations of WWTP models – more specifically, activated sludge models – are introduced since these define...

  1. Constructed Wetlands for Wastewater Treatment

    OpenAIRE

    Jan Vymazal

    2010-01-01

    The first experiments using wetland macrophytes for wastewater treatment were carried out in Germany in the early 1950s. Since then, the constructed wetlands have evolved into a reliable wastewater treatment technology for various types of wastewater. The classification of constructed wetlands is based on: the vegetation type (emergent, submerged, floating leaved, free-floating); hydrology (free water surface and subsurface flow); and subsurface flow wetlands can be further classified accordi...

  2. Refinery effluent analysis methodologies for relevant parameters from EU-regulatory regimes

    Energy Technology Data Exchange (ETDEWEB)

    Westwood, D.; Ward, T. [Beta Technology Ltd, Heavens Walk, Doncaster, South Yorkshire DN4 5HZ (United Kingdom); Prescott, N.; Rippin, I. [Environment Agency, National Laboratory Service, PO Box 544 Rotherham S60 1BY (United Kingdom); Comber, M.; Den Haan, K.

    2013-08-15

    This report provides guidance to CONCAWE members on the analytical methods that might be used to monitor oil refinery effluents for those refinery-specific parameters covered by relevant European legislation and a comparison of the methods that are used today, as reported in the last Effluent Survey. A method assessment programme is presented whereby the performance of methods of analysis (used to monitor oil refinery effluents) can be compared and prioritised in order of their analytical performance capabilities. Methods for a specific parameter, which is clearly and unambiguously defined, are compared with each other and then prioritised in terms of their overall quality. The quality of these methods is based on an assessment of a combination of characteristic features, namely, precision, bias or recovery, limit of detection (where appropriate), indicative costs, and ease of use. Ranking scores for each feature are assigned to various ranges of each feature, and then added together to give an overall ranking value. The method exhibiting the lowest overall ranking value is deemed the most appropriate method for analysing that parameter. Within this report, several recommendations are made in terms of comparing results of analyses or their associated uses. Where data are to be compared for a particular parameter, then, all CONCAWE members involved in this comparison should agree common objectives, in advance. These include defining a common definition for the: (1) Parameter being analysed and compared; (2) Limit of detection, and how this concentration value should be calculated; (3) Limit of quantification, and how this concentration value should be calculated and how it is to be applied for selective reporting purposes; and (4) Uncertainty of measurement and how it should be calculated. It is further recommended that these involved members should agree on the range of values and ranking scores chosen to reflect the performance characteristic features used in the

  3. Standard practice for evaluating and qualifying oil field and refinery corrosion inhibitors using rotating cage

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2006-01-01

    1.1 This practice covers a generally accepted procedure to use the rotating cage (RC) for evaluating corrosion inhibitors for oil field and refinery applications. 1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

  4. Seismic Scenario in the Acambay Graben and Possible Affectations in the Miguel Hidalgo Refinery

    Science.gov (United States)

    Valderrama Membrillo, S.; Aguirre, J.

    2015-12-01

    In this paper we presented synthetic acceleration records in the Miguel Hidalgo refinery, Hidalgo due to a seismic scenario originated in the graben Acambay, such as occurred in 1912 (70 km distance to it). This earthquake had a magnitude of 6.9 and caused extensive damage, according to reports caused 164 deaths and numerous houses collapsing. To simulate the event of M = 6.9 we used the empirical Greeńs function method proposed by Irikura (1986). Due to the low seismic activity we have not any small earthquake record or an "element earthquake" so that we generated a synthetic seismogram of M = 4.1 to be used as empirical Greeńs function. The seismogram was constructed in two parts. For low frequencies we constructed from cross-correlations of seismic noise, while for high frequencies we made a stochastic simulation. Subsequently, we applied a "matched filter" to join the two frequency bands of synthetic earthquake. For the construction of seismic scenario the method of Irikura (1986) was used. We consider a square fault of 47.75 km long, a radial rupture propagation, rupture velocity of 3.06 m/s, and with the following focal mechanism: strike of 280°, dip of 66 ° and rake of -138 °. With these parameters we obtained the synthetic seismograms. Since there was not any observed earthquake to validate the model, the 1912 event was simulated and then from relationships of intensity (obtained Wald et al.,2005; Sandoval et al., 2013; and Arias, 1969), we estimated the Modified Mercalli Intensity (MMI) for the refinery. We compare our result with isoseismal map obtained by Suter et al. (1996) for the earthquake of 1912. In agreement with Suter, our results shown a MMI V-VI for the Miguel Hidalgo refinery. With this qualitative validation we search the seismic scenario with the higher accelerations and from this synthetic seismogram, we obtained parameters that are of interest in engineering to estimate the possible affectations to the Miguel Hidalgo refinery, such as

  5. Investigation of some solvents for asphalten-wax-paraffin depositions formed on the oil refinery equipment

    Directory of Open Access Journals (Sweden)

    О. В. Тертишна

    2013-07-01

    Full Text Available Тhe methods of asphalten - wax- paraffin depositions removal from the oil refinery equipment were studied. The effectiveness of solvents were estimated by mass losses of samples wrapped up in filter paper after exposition in different reagents, such as once-run petrol, benzene, toluene, hexane and some mixtures of these substances. The best results were obtained in the hexane - benzene mixture with volume ratio 1:1. The maximal level of dissolution was achieved at 30-35 °С

  6. Troubleshooting vacuum systems steam turbine surface condensers and refinery vacuum towers

    CERN Document Server

    Lieberman, Norman P

    2012-01-01

    Vacuum systems are in wide spread use in the petrochemical plants, petroleum refineries and power generation plants. The existing texts on this subject are theoretical in nature and only deal with how the equipment functions when in good mechanical conditions, from the viewpoint of the equipment vendor.  In this much-anticipated volume, one of the most well-respected and prolific process engineers in the world takes on troubleshooting vacuum systems, and especially steam ejectors, an extremely complex and difficult subject that greatly effects the profitability of the majority of the world'

  7. Synergies between bio- and oil refineries for the production of fuels from biomass.

    Science.gov (United States)

    Huber, George W; Corma, Avelino

    2007-01-01

    As petroleum prices continue to increase, it is likely that biofuels will play an ever-increasing role in our energy future. The processing of biomass-derived feedstocks (including cellulosic, starch- and sugar-derived biomass, and vegetable fats) by catalytic cracking and hydrotreating is a promising alternative for the future to produce biofuels, and the existing infrastructure of petroleum refineries is well-suited for the production of biofuels, allowing us to rapidly transition to a more sustainable economy without large capital investments for new reaction equipment. This Review discusses the chemistry, catalysts, and challenges involved in the production of biofuels.

  8. Test plan: the Czechowice Oil Refinery bioremediation demonstration of a process waste lagoon

    Energy Technology Data Exchange (ETDEWEB)

    Altman, D.J.; Lombard, K.H.; Hazen, T.C.

    1997-03-31

    The remediation strategies that will be applied at the Czechowice Oil Refinery waste lagoon in Czechowice, Poland are designed, managed, and implemented under the direction of the Westinghouse Savannah River Company (WSRC) for the United States Department of Energy (DOE). WSRC will be assisted in the demonstration by The Institute for Ecology of Industrial Areas (IETU). This collaboration between IETU and DOE will provide the basis for international technology transfer of new and innovative remediation technologies that can be applied in Poland and the Eastern European Region as well.

  9. Wastewater treatment with algae

    Energy Technology Data Exchange (ETDEWEB)

    Wong Yukshan [Hong Kong Univ. of Science and Technology, Kowloon (China). Research Centre; Tam, N.F.Y. [eds.] [City Univ. of Hong Kong, Kowloon (China). Dept. of Biology and Chemistry

    1998-05-01

    Immobilized algal technology for wastewater treatment purposes. Removal of copper by free and immobilized microalga, Chlorella vulgaris. Biosorption of heavy metals by microalgae in batch and continuous systems. Microalgal removal of organic and inorganic metal species from aqueous solution. Bioaccumulation and biotransformation of arsenic, antimony and bismuth compounds by freshwater algae. Metal ion binding by biomass derived from nonliving algae, lichens, water hyacinth root and spagnum moss. Metal resistance and accumulation in cyanobacteria. (orig.)

  10. Bioindicators of wastewater ecotoxicity.

    Science.gov (United States)

    Jirova, Gabriela; Wittlingerova, Zdenka; Zimova, Magdalena; Vlkova, Alena; Wittlerova, Martina; Dvorakova, Marketa; Jirova, Dagmar

    2016-12-18

    Wastewater, especially containing hospital effluents, exhibits high chemical complexity and specificity since it includes various chemicals, biocides, pharmaceuticals, surfactants, radionuclides, disinfectants and pathogens. Biological tests provide true evidence of the wastewater quality and unlike chemical analytical tests show comprehensive pollution effects on the environment and human health. Normalized conventional bioassays are not sensitive enough for ecotoxicological evaluation of wastewater and there is a great need for the development of suitable sensitive bioassays in order to characterize properly the residual toxicity of treated effluents. Provisions of binding EU legislation regarding protection of animals used for scientific purposes and legislation dealing with test methods for identification and classification of health hazard of chemicals, pharmaceuticals, biocides, medical devices and consumer products such as cosmetics for environmental ecosystems and for man require to employ alternative toxicological methods respecting the 3Rs concept with priority given to methods in vitro. The Fish Embryo Test (FET) is identified as a relevant, reliable and efficient alternative test method in vitro for determination of acute toxicity for fish. Using the FET, additional toxicological endpoints may be investigated to assess organ specific bioaccumulation, genotoxicity and mutagenicity, developmental toxicity, teratogenicity, various forms of neurotoxicity or endocrine disruptivity. The addition of multiparametric sensitive endpoints makes the FET a true alternative in vitro assay and a powerful tool in toxicology.

  11. Training Centers for Onsite Wastewater Treatment

    Science.gov (United States)

    Onsite wastewater training centers offer classes, demonstration projects and research facilities for onsite industry professionals. Classes include wastewater management, new technologies and pre-licensing.

  12. Auxiliary units for refining of high nitrogen content oils: Premium II refinery case

    Energy Technology Data Exchange (ETDEWEB)

    Nicolato, Paolo Contim; Pinotti, Rafael [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)

    2012-07-01

    PETROBRAS is constantly investing on its refining park in order to increase the production of clean and stable fuels and to be capable to process heavier oils with high contaminants content. Sulfur and nitrogen are the main heteroatoms present in petroleum. They are responsible for some undesirable fuels properties like corrosivity and instability, and also emit pollutants when burnt. Hydrotreating and hydrocracking processes are designed to remove these contaminants and adjust other fuel properties, generating, as byproduct, sour gases and sour water streams rich in H{sub 2}S and NH{sub 3}, which are usually sent to Sour Water Treatment Units and Sulfur Recovery Units. The regeneration of the amine used for the light streams treatment, as fuel gas and LPG, also generates sour gas streams that must be also sent to Sulfur Recovery Units. As the ammonia content in the sour streams increases, some design parameters must be adjusted to avoid increasing the Refinery emissions. Sulfur Recovery Units must provide proper NH3 destruction. Sour Water Treatment must have a proper segregation between H{sub 2}S and ammonia streams, whenever desirable. Amine Regeneration Systems must have an efficient procedure to avoid the ammonia concentration in the amine solution. This paper presents some solutions usually applied to the Petroleum Industry and analyses some aspects related to Premium II Refinery Project and how its design will help the Brazilian refining park to meet future environmental regulation and market demands. (author)

  13. Discrete event simulation for petroleum transfers involving harbors, refineries and pipelines

    Energy Technology Data Exchange (ETDEWEB)

    Martins, Marcella S.R.; Lueders, Ricardo; Delgado, Myriam R.B.S. [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil)

    2009-07-01

    Nowadays a great effort has been spent by companies to improve their logistics in terms of programming of events that affect production and distribution of products. In this case, simulation can be a valuable tool for evaluating different behaviors. The objective of this work is to build a discrete event simulation model for scheduling of operational activities in complexes containing one harbor and two refineries interconnected by a pipeline infrastructure. The model was developed in Arena package, based on three sub-models that control pier allocation, loading of tanks, and transfers to refineries through pipelines. Preliminary results obtained for a given control policy, show that profit can be calculated by taking into account many parameters such as oil costs on ships, pier using, over-stay of ships and interface costs. Such problem has already been considered in the literature but using different strategies. All these factors should be considered in a real-world operation where decision making tools are necessary to obtain high returns. (author)

  14. Suitability of Scirpus maritimus for petroleum hydrocarbons remediation in a refinery environment.

    Science.gov (United States)

    Couto, M Nazaré P F S; Basto, M Clara P; Vasconcelos, M Teresa S D

    2012-01-01

    In the ambit of a project searching for appropriate biological approaches for recovering a refinery soil contaminated with petroleum hydrocarbons (PHC), we compared results obtained in the absence and in the presence of the salt marsh plant Scirpus maritimus or Juncus maritimus or an association of these two plants, which were tested in the refinery environment. Synergistic effects caused by addition of a non-ionic surfactant and/or a bioaugmentation product were also investigated. Major challenges of this study were: field conditions and weathered contamination. Transplants of the plants were carried out in individual containers filled with a weathered contaminated soil, which was recontaminated with turbine oil with two purposes: for increasing PHC level and allowing a comparison of the potential of plants for remediation of ancient and recent contamination. Analysis of total PHC led to the conclusion that, after 24-month exposure, neither J. maritimus nor the association caused any improvement in remediation. In contrast, S. maritimus revealed potential for PHC remediation, favoring degradation of both recent and older contamination (which was refractory to natural attenuation). About 15% of remediation improvement was found in the soil layer with higher root density (5-10 cm). A more marked improvement in that layer (28%) was observed when non-ionic surfactant amendment and bioaugmentation were used jointly. The fact that S. maritimus has demonstrated capability for PHC remediation, leads to admit that it has potential to be also used for recovering sediments that have suffered accidental oil spills.

  15. Application of biological marker technology to bioremediation of refinery by-products

    Energy Technology Data Exchange (ETDEWEB)

    Moldowan, J.M.; Dahl, J.; McCaffrey, M.A.; Smith, W.J.; Fetzer, J.C. [Chevron Petroleum Technology Co., Richmond, CA (United States)

    1995-01-01

    The progress of bioremediation of waste petroleum sludge at Chevron`s Perth Amboy, New Jersey, refinery landfarm was evaluated using a ranking scale based on refractory biological marker hydrocarbons that are indigenous to, and ubiquitous in, crude oils. Of the four samples analyzed from different locations in the landfarm, two were virtually identical and showed an absence of the n-alkanes expected to be found in the sludge (light biodegradation ranking). Another showed additional partial degradation of acyclic isoprenoids, e.g., pristane and phytane (moderate ranking). The fourth sample showed complete n-paraffin and isoprenoid loss, partial alteration of hopanes, and losses of C{sub 27} steranes, C{sub 27} diasteranes, C{sub 27} monoaromatic steroids, and C{sub 26} triaromatic steroids relative to the higher steroid homologs in each of these series (heavy ranking). These results suggest a concomitant preferential loss of steroid hydrocarbons that have the cholestane side chain and a possible new steroid biodegradation mechanism that is essentially blind to the structure of the steroid nucleus. The latter sample also showed levels of most polynuclear aromatic hydrocarbons (PAH), suggesting a building up of these compounds as others were removed. However, some of the smaller PAH (acenaphylene, fluorene, fluoranthene) appear to have decreased. These results suggest that a protocol based on such a biodegradation ranking scale could be used to monitor the progress of bioremediation of oil based refinery wastes. 35 refs., 7 figs., 1 tab.

  16. Stabilization of Bio-Oil Fractions for Insertion into Petroleum Refineries

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Robert C. [Iowa State Univ., Ames, IA (United States); Smith, Ryan [Iowa State Univ., Ames, IA (United States); Wright, Mark [Iowa State Univ., Ames, IA (United States); Elliott, Douglas [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Resasco, Daniel [Univ. of Oklahoma, Norman, OK (United States); Crossley, Steven [Univ. of Oklahoma, Norman, OK (United States)

    2014-09-28

    This project is part of a collaboration effort between Iowa State University (ISU), University of Oklahoma (OK) and Pacific Northwest National Laboratory (PNNL). The purpose of this project is to stabilize bio-oil fractions and improve their suitability for insertion into petroleum refineries. Bio-oil from fast pyrolysis of biomass is a complex mixture of unstable organic compounds. These organic compounds react under standard room conditions resulting in increases in bio-oil viscosity and water content – both detrimental for bio-oil storage and transportation. This study employed fractionation and upgrading systems to improve the stability of bio-oil. The fractionation system consists of a series of condensers, and electrostatic precipitators designed to separate bio-oil into five fractions: soluble carbohydrates (SF1&2), clean phenolic oligomers (CPO) and middle fraction (SF3&4), light oxygenates (SF5). A two-stage upgrading process was designed to process bio-oil stage fractions into stable products that can be inserted into a refinery. In the upgrading system, heavy and middle bio-oil fractions were upgraded into stable oil via cracking and subsequent hydrodeoxygenation. The light oxygenate fraction was steam reformed to provide a portion of requisite hydrogen for hydroprocessing. Hydrotreating and hydrocracking employed hydrogen from natural gas, fuel gas and light oxygenates reforming. The finished products from this study consist of gasoline- and diesel-blend stock fuels.

  17. Evaluation and control of worker exposure to fungi in a beet sugar refinery.

    Science.gov (United States)

    Jensen, P A; Todd, W F; Hart, M E; Mickelsen, R L; O'Brien, D M

    1993-12-01

    A study of worker exposure to airborne fungi was undertaken in a sugar beet refinery to evaluate the level of exposure and to determine if controls could be implemented that would lower these exposures. A previous study at this refinery identified one worker who reacted on challenge testing to the moldy but not the fresh sugar beet pulp, had specific Immunoglobulin G to Aspergillus niger, and specific Immunoglobulin E to Aspergillus. Also, two employees were diagnosed with occupational asthma. In the study reported here, two field surveys were conducted, the first during the sugar production campaign (January) and the second during postproduction cleanup and maintenance (June). Approximately 65 personal and area air samples were collected on polycarbonate filters and the culturable fungal spores were identified and enumerated. This study showed high exposure of pellet loaders and pellet silo workers to various species of Aspergillus. Other fungal species that might pose a health hazard were detected. Exposures to fungi during the postproduction cleanup and maintenance phase were much higher than those measured during the production campaign. Engineering controls that would reduce employee exposure are discussed.

  18. Hydroprocessing and premium II refinery: a new refining philosophy for an era of clean fuels

    Energy Technology Data Exchange (ETDEWEB)

    Delgaudio, Caio Veiga Penna; Pinotti, Rafael [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)

    2012-07-01

    This paper discusses a brief history of Brazilian's emission and fuel specifications, since the appearance of PROCONVE until the late stages of the program for vehicles powered by gasoline and diesel. The development of the Brazilian refining is analyzed taking into account the emission and specification evolutions, and it can be perceived that the system's complexity increases while new constraints are imposed by the regulator. This aspect is even more apparent when the detailed scheme of the Premium II refinery and its main unit, the catalytic hydrocracker (HCC, which has not yet been part of PETROBRAS' refining park and will appear in three of the four new refineries of the company) is described. The new projects represent the culmination of the intensive use of energy and raw material for obtaining the products with the new specifications. There is a price for this development, both in investments and increased operating costs due to greater complexity of the system. To adapt to the era of clean fuels, refiners will present a series of challenges that will lead them to seek for more efficient processes and operational excellence (and ongoing efforts to reduce their emissions) in order to ensure positive refining margins. (author)

  19. Trends in advanced wastewater treatment

    DEFF Research Database (Denmark)

    Henze, M.

    1997-01-01

    The paper examines the present trends within wastewater handling and treatment. The trend is towards the extremes, either local low-tech treatment or centralized advanced treatment plants. The composition of the wastewater will change and it will be regarded as a resource. There will be more...

  20. Nutrient Removal in Wastewater Treatment

    Science.gov (United States)

    Shah, Kanti L.

    1973-01-01

    Discusses the sources and effects of nutrients in wastewater, and the methods of their removal in wastewater treatment. In order to conserve water resources and eliminate the cost of nutrient removal, treated effluent should be used wherever possible for irrigation, since it contains all the ingredients for proper plant growth. (JR)

  1. Physico-chemical wastewater treatment

    NARCIS (Netherlands)

    Mels, A.R.; Teerikangas, E.

    2002-01-01

    Wastewater reclamation strategies aimed at closing industrial water cycles and recovery of valuable components will in most cases require a combination of wastewater treatment unit operations. Biological unit operations are commonly applied as the core treatment. In addition, physico-chemical unit o

  2. Physico-chemical wastewater treatment

    NARCIS (Netherlands)

    Mels, A.R.; Teerikangas, E.

    2002-01-01

    Wastewater reclamation strategies aimed at closing industrial water cycles and recovery of valuable components will in most cases require a combination of wastewater treatment unit operations. Biological unit operations are commonly applied as the core treatment. In addition, physico-chemical unit o

  3. Physico-chemical wastewater treatment

    NARCIS (Netherlands)

    Mels, A.R.; Teerikangas, E.

    2002-01-01

    Wastewater reclamation strategies aimed at closing industrial water cycles and recovery of valuable components will in most cases require a combination of wastewater treatment unit operations. Biological unit operations are commonly applied as the core treatment. In addition, physico-chemical unit

  4. Resourceful Utilization of Tannery Wastewater

    Institute of Scientific and Technical Information of China (English)

    Wang Chen; Wang Xikui; Ding Maochen; Zhang Chaoyu

    2012-01-01

    Leather industry is an important light industry in China. Leather making requires a series of chemical treatment. Degreasing, unhairing and chrome tanning wastewaters are the main portions of tannery wastewater. Reclaiming and reusing these wastewaters can eliminate 80% of COD, 75% of BOD, 95% of chromium and 93% of sulfuret, furthermore reduce environment impact, decrease treatment costs, save chemicals and water. Some application methods of wastewater reclamation and reuse for dif- ferent operations were reported. The suitable reclamation and reuse technologies can enable leather making processes more ra- tional, and realize the recovery and recycle of several chemicals in the tannery. Resourceful utilization of tannery wastewater should mate with renovating production technology, updating equipment, and must be guaranteed sufficiently by environmental protection measures.

  5. 40 CFR 63.133 - Process wastewater provisions-wastewater tanks.

    Science.gov (United States)

    2010-07-01

    ..., manages, or treats a Group 1 wastewater stream or a residual removed from a Group 1 wastewater stream, the... fixed roof except that if the wastewater tank is used for heating wastewater, or treating by means of an... 40 Protection of Environment 9 2010-07-01 2010-07-01 false Process wastewater...

  6. Health Effects Associated with Wastewater Treatment, Reuse, and Disposal.

    Science.gov (United States)

    Qu, Xiaoyan; Zhao, Yuanyuan; Yu, Ruoren; Li, Yuan; Falzone, Charles; Smith, Gregory; Ikehata, Keisuke

    2016-10-01

    A review of the literature published in 2015 on topics relating to public and environmental health risks associated with wastewater treatment, reuse, and disposal is presented. This review is divided into the following sections: wastewater management, microbial hazards, chemical hazards, wastewater treatment, wastewater reuse, agricultural reuse in different regions, greywater reuse, wastewater disposal, hospital wastewater, industrial wastewater, and sludge and biosolids.

  7. Analysis of snow-cap pollution for air quality assessment in the vicinity of an oil refinery.

    Science.gov (United States)

    Krastinyte, Viktorija; Baltrenaite, Edita; Lietuvninkas, Arvydas

    2013-01-01

    Snow-cap can be used as a simple and effective indicator of industrial air pollution. In this study snow-cap samples were collected from 11 sites located in the vicinity of an oil refinery in Mazeikiai, a region in the north-west of Lithuania, in the winter of 2011. Analysis of snowmelt water and snow-dust was used to determine anthropogenic pollutants such as: sulphates and chlorides, nitrites, nitrates, ammonium nitrogen, total carbon, total nitrogen; heavy metals: lead (Pb), copper (Cu), chromium (Cr), cadmium (Cd). Concentrations of heavy metals in snow-dust were detected thousands of times higher than those in the snowmelt water. In this study, analysis of heavy metal concentration was conducted considering different distances and the wind direction within the impact zone of the oil refinery. The sequence of heavy metals according to their mean concentrations in the snow-dust samples was the following: Pb > Cr > Cu > Cd. Heavy metals highly correlated among each other. The load of snow-dust was evaluated to determine the pollution level in the study area. The highest daily load of snow-dust was 45.81 +/- 12.35 mg/m2 in the north-western direction from the oil refinery. According to classification of the daily load of snow-dust a lower than medium-risk level of pollution was determined in the vicinity of the oil refinery.

  8. 40 CFR 80.524 - What sulfur content standard applies to motor vehicle diesel fuel downstream of the refinery or...

    Science.gov (United States)

    2010-07-01

    ... to motor vehicle diesel fuel downstream of the refinery or importer? 80.524 Section 80.524 Protection... FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Motor Vehicle Diesel Fuel Standards and Requirements § 80.524 What sulfur content...

  9. Pathways of inhalation exposure to manganese in children living near a ferromanganese refinery: A structural equation modeling approach

    Science.gov (United States)

    Manganese (Mn) is both essential element and neurotoxicant. Exposure to Mn can occur from various sources and routes. Structural equation modeling was used to examine routes of exposure to Mn among children residing near a ferromanganese refinery in Marietta, Ohio. An inhalation ...

  10. Development of a factory/refinery method to measure total, soluble, and insoluble starch in sugar products

    Science.gov (United States)

    An easy, rapid, and inexpensive method was developed to measure total, soluble, and insoluble starch in products at the factory and refinery, using microwave-assisted neutralization chemistry. The method was optimized using the previously developed USDA Starch Research method as a reference. Optimal...

  11. Unit for Production of MTBE and Butene-1 from Refinery C4 Successfully Put on Stream at Guangzhou Petrochemical Complex

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    @@ The unit for manufacture of MTBE with co-production of butene-1 was successfully put on stream at Guangzhou Pet-rochemical Complex (GPC). It is told that this is the first domestic unit that utilizes the refinery C4 fraction to make MTBE and butene-1.

  12. How the physical forms of starch affect filterability at a carbonatation refinery. Part II: simulated carbonatation filtration

    Science.gov (United States)

    Although starch is known to detrimentally impact carbonatation filtration at sugarcane refineries, the physical form(s) of starch responsible is unknown. Thus, a study was undertaken to elucidate the effects of the physical starch forms, i.e., soluble, swollen, and insoluble, and their concentration...

  13. Optimization of two-step bioleaching of spent petroleum refinery catalyst by Acidithiobacillus thiooxidans using response surface methodology.

    Science.gov (United States)

    Srichandan, Haragobinda; Pathak, Ashish; Kim, Dong Jin; Lee, Seoung-Won

    2014-01-01

    A central composite design (CCD) combined with response surface methodology (RSM) was employed for maximizing bioleaching yields of metals (Al, Mo, Ni, and V) from as-received spent refinery catalyst using Acidithiobacillus thiooxidans. Three independent variables, namely initial pH, sulfur concentration, and pulp density were investigated. The pH was found to be the most influential parameter with leaching yields of metals varying inversely with pH. Analysis of variance (ANOVA) of the quadratic model indicated that the predicted values were in good agreement with experimental data. Under optimized conditions of 1.0% pulp density, 1.5% sulfur and pH 1.5, about 93% Ni, 44% Al, 34% Mo, and 94% V was leached from the spent refinery catalyst. Among all the metals, V had the highest maximum rate of leaching (Vmax) according to the Michaelis-Menten equation. The results of the study suggested that two-step bioleaching is efficient in leaching of metals from spent refinery catalyst. Moreover, the process can be conducted with as received spent refinery catalyst, thus making the process cost effective for large-scale applications.

  14. Allocating the CO{sub 2} emissions of an oil refinery with Aumann-Shapley prices. Comment

    Energy Technology Data Exchange (ETDEWEB)

    Tehrani Nejad Moghaddam, Alireza [Department of Economic Studies, Institut Francais du Petrole (I.F.P.), 92852, Rueil-Malmaison (France)

    2010-01-15

    The allocation of CO{sub 2} emissions of petroleum refineries to their oil products is a necessary step in the retrospective Well-to-Tank (WTT) analysis. These allocated emissions are used to evaluate the environmental impacts of automotive fuels' production within the refinery. Oil refining is a complex joint production system and there exists no simple and unique answer to this allocation question. Recently, Pierru proposed adapting the Aumann-Shapley cost sharing method to deal with this issue. Our paper aims at describing the conceptual and technical difficulties of this adaptation to the WTT context. Moreover, we show that this approach, as proposed by Pierru, is not applicable to any real-type refinery model. Different suggestions are provided to improve its applicability (when it is possible) in real situations. A simple numerical example as well as a real-type refinery case study is provided for illustrations. Finally, we discuss an alternative allocation approach which we believe more adapted to the WTT context. (author)

  15. Pathways of inhalation exposure to manganese in children living near a ferromanganese refinery: A structural equation modeling approach

    Science.gov (United States)

    Manganese (Mn) is both essential element and neurotoxicant. Exposure to Mn can occur from various sources and routes. Structural equation modeling was used to examine routes of exposure to Mn among children residing near a ferromanganese refinery in Marietta, Ohio. An inhalation ...

  16. 40 CFR 63.1106 - Wastewater provisions.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 10 2010-07-01 2010-07-01 false Wastewater provisions. 63.1106 Section... Technology Standards § 63.1106 Wastewater provisions. (a) Process wastewater. Except as specified in... source shall comply with the HON process wastewater requirements in §§ 63.132 through 63.148. (1)...

  17. 生物活性炭技术在工业废水处理中的研究进展%Research Progress in BAC Technology for Industrial Wastewater Treatment

    Institute of Scientific and Technical Information of China (English)

    胡顺莹; 赵翠; 施岩

    2014-01-01

    Industrial wastewater is a kind of complex and refractory organic wastewater, and contains a lot of matters, such as heavy metals, solid contaminants, sediment and other toxic substances. It can’t be treated with single technology. In this paper, research status of BAC technology was introduced in the field of dyeing wastewater, papermaking wastewater, wastewater, tannery waste water, refinery wastewater;And future research direction of BAC technology was suggested.%工业废水是一种成分复杂、难降解的有机废水,水中含有大量的氨氮、重金属、固体污染物、泥沙等有毒有害物质。采用单一的生物处理技术难以进行有效治理。主要介绍了生物活性炭技术在处理印染废水、造纸废水、焦化废水、制革废水、炼油废水方面的研究现状,并对今后的研究方向提出了建议。

  18. Xenobiotic organic compounds in wastewater

    DEFF Research Database (Denmark)

    Eriksson, Eva; Baun, Anders; Henze, Mogens

    2002-01-01

    Information regarding the contents of xenobiotic organic compounds (XOCs) in wastewater is limited, but it has been shown that at least 900 different compounds / compound groups could potentially be present in grey wastewater. Analyses of Danish grey wastewater revealed the presence of several...... hundred of XOCs, among them mainly originating from hygiene products: chlorophenols, detergents and phthalates. Several compounds not deriving from hygiene products were also identified e.g. flame-retardants and drugs. A environmental hazard identification showed that a large number of compounds with high...... aquatic toxicity were present and that data for environmental fate could only be retrieved for about half of the compounds....

  19. Constructed Wetlands for Wastewater Treatment

    Directory of Open Access Journals (Sweden)

    Jan Vymazal

    2010-08-01

    Full Text Available The first experiments using wetland macrophytes for wastewater treatment were carried out in Germany in the early 1950s. Since then, the constructed wetlands have evolved into a reliable wastewater treatment technology for various types of wastewater. The classification of constructed wetlands is based on: the vegetation type (emergent, submerged, floating leaved, free-floating; hydrology (free water surface and subsurface flow; and subsurface flow wetlands can be further classified according to the flow direction (vertical or horizontal. In order to achieve better treatment performance, namely for nitrogen, various types of constructed wetlands could be combined into hybrid systems.

  20. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2007-03-17

    This report summarizes the accomplishments toward project goals during the no cost extension period of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts for a third round of testing, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Hydrotreating and hydrogenation of the product has been completed, and due to removal of material before processing, yield of the jet fuel fraction has decreased relative to an increase in the gasoline fraction. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for

  1. Assessment and planning of the electrical systems in Mexican refineries by 2014

    Energy Technology Data Exchange (ETDEWEB)

    Ruiz Flores, Luis Ivan; Rodriguez Martinez, Jose Hugo [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico); Dario Taboada; Guillermo; Pano Jimenez, Javier [PEMEX, (Mexico)

    2012-07-01

    Nowadays the refining sector in Mexico needs to increase the quantity and quality of produced fuels by installing new process plants for gasoline and ultra-low sulphur diesel. These plants require the provision of electricity and steam, among other services to function properly, which can be supplied by the power plants currently installed in each refinery through an expansion of their generation capacity. These power plants need to increase its production of electricity and steam at levels above their installed capacity, which involves the addition of new power generating equipment (gas or steam turbo-generators) as well as the raise of the electrical loads. Currently, the Mexican Petroleum Company (PEMEX) is planning to restructure their electrical and steam systems in order to optimally supply the required services for the production of high quality fuels. In this paper the present status of the original electrical power systems of the refineries is assessed and the electrical integration of new process plants in the typical schemes is analyzed. Also this paper shows the conceptual schemes proposed to restructure the electrical power system for two refineries and the strategic planning focused on implement the modifications required for the integration of new process plants that will demand about 20 MW for each refinery by 2014. The results of the analysis allowed to identify the current conditions of the electrical power systems in the oil refining industry or National Refining Industry (NRI), and thereby to offer technical solutions that could be useful to engineers facing similar projects. [Spanish] Hoy en dia, el sector de refinacion en Mexico necesita aumentar la cantidad y calidad de los combustibles producidos, mediante la instalacion de nuevas plantas de proceso para la gasolina y el diesel ultra bajo en azufre. Estas plantas requieren el suministro de electricidad y vapor de agua, entre otros servicios, para que funcione correctamente, los cuales pueden

  2. Application of organic polymeric fiocculants in centrifugal dewatering of oil refinery sludge

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    In order to evaluate the applicability of the organic polymeric floeculants(OPF) in the treatment of oil refinery sludge, experimentswere conducted to show that OPF have better performance of flocculation than inorganic flocculants. Both the anionic and cationic OPF havesatisfactory flocculation efficiency in oil sludge treatment, but the latter are more cost-efficient. Among the over 20 types of flocculants tested,2OPF(CPAM-2 and HPAM-2) were selected as the treatment agents, based on their good treatment performances, oil-resistance and economicfeasibility. It was demonstrated in the industrial-scale centrifugal dewatering experiments that the application of either CPAM-2 or HPAM-2could achieve high treatment efficiency of the oil sludge dewatering and reduce the COD of centrifugal liquid to less than 1000 mg/L.

  3. Standard guide for evaluating and qualifying oilfield and refinery corrosion inhibitors in the laboratory

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2006-01-01

    1.1 This guide covers some generally accepted laboratory methodologies that are used for evaluating corrosion inhibitors for oilfield and refinery applications in well defined flow conditions. 1.2 This guide does not cover detailed calculations and methods, but rather covers a range of approaches which have found application in inhibitor evaluation. 1.3 Only those methodologies that have found wide acceptance in inhibitor evaluation are considered in this guide. 1.4 This guide is intended to assist in the selection of methodologies that can be used for evaluating corrosion inhibitors. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory requirements prior to use.

  4. Reuse and recycling of secondary effluents in refineries employing advanced multi-barrier systems.

    Science.gov (United States)

    Lahnsteiner, J; Mittal, R

    2010-01-01

    In this paper the reclamation and reuse of municipal secondary effluents, as well as the reclamation and recycling of refinery secondary effluents, are technically and economically evaluated. It is shown that both practices are feasible and sustainable, and that the reclamation costs depend largely on specific circumstances such as legal requirements, price policy, reuse application, raw water composition, etc. The reclaimed water is reused, or respectively recycled, as boiler make-up. Therefore both reclamation plants employ advanced multi-barrier systems including ultra-filtration and reverse osmosis. The employed processes have shown excellent performance with regard to the removal of critical parameters such as silica. For example, this parameter was reduced from 13 mg/l in the raw water to 7 μg/l in the boiler make-up.

  5. Production and characterization of rhamnolipid using palm oil agricultural refinery waste.

    Science.gov (United States)

    Radzuan, Mohd Nazren; Banat, Ibrahim M; Winterburn, James

    2017-02-01

    In this research we assess the feasibility of using palm oil agricultural refinery waste as a carbon source for the production of rhamnolipid biosurfactant through fermentation. The production and characterization of rhamnolipid produced by Pseudomonas aeruginosa PAO1 grown on palm fatty acid distillate (PFAD) under batch fermentation were investigated. Results show that P. aeruginosa PAO1 can grow and produce 0.43gL(-1) of rhamnolipid using PFAD as the sole carbon source. Identification of the biosurfactant product using mass spectrometry confirmed the presence of monorhamnolipid and dirhamnolipid. The rhamnolipid produced from PFAD were able to reduce surface tension to 29mNm(-1) with a critical micelle concentration (CMC) 420mgL(-1) and emulsify kerosene and sunflower oil, with an emulsion index up to 30%. Results demonstrate that PFAD could be used as a low-cost substrate for rhamnolipid production, utilizing and transforming it into a value added biosurfactant product.

  6. Integration of RTO and MPC in the Hydrogen Network of a Petrol Refinery

    Directory of Open Access Journals (Sweden)

    Cesar de Prada

    2017-01-01

    Full Text Available This paper discusses the problems associated with the implementation of Real Time Optimization/Model Predictive Control (RTO/MPC systems, taking as reference the hydrogen distribution network of an oil refinery involving eighteen plants. This paper addresses the main problems related to the operation of the network, combining data reconciliation and a RTO system, designed for the optimal generation and redistribution of hydrogen, with a predictive controller for the on-line implementation of the optimal policies. This paper describes the architecture of the implementation, showing how RTO and MPC can be integrated, as well as the benefits obtained in terms of improved information about the process, increased hydrocarbon load to the treatment plants and reduction of the hydrogen required for performing the operations.

  7. Feed Alternatives Evaluation in an Oil Refinery Using a Process Simulator

    Directory of Open Access Journals (Sweden)

    Anelys Armengol Gálvez

    2014-09-01

    Full Text Available By processing a medium crude, a refinery can only operate 80 days a year due to the declining of itswells supply. In order to ensure a better improvement of its resources some feed alternatives areproposed. That depends of the availability in others country regions of raw material that demandsdilutions because of their heavier and viscosity. Taking advantage of geographic location and demands,asphalt can be obtained and also a wide cut with use in oilfields to reduce viscosity. That is why couldbe attractive to evaluate the possibilities of using the simulation model previously obtained withprofessional simulator HYSYS (version 2.2, complementing the information in order to validate resultsin a test with one of the alternatives proposed (heavy diluted crude with solvents of habitual crudeconfirming the convenience of the chosen option, associated with profitable gains.

  8. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-09-17

    This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO

  9. Monitoring of Emissions From a Refinery Tank Farm Using a Combination of Optical Remote Sensing Techniques

    Science.gov (United States)

    Polidori, A.; Tisopulos, L.; Pikelnaya, O.; Mellqvist, J.; Samuelsson, J.; Marianne, E.; Robinson, R. A.; Innocenti, F.; Finlayson, A.; Hashmonay, R.

    2016-12-01

    Despite great advances in reducing air pollution, the South Coast Air Basin (SCAB) still faces challenges to attain federal health standards for air quality. Refineries are large sources of ozone precursors and, hence contribute to the air quality problems of the region. Additionally, petrochemical facilities are also sources of other hazardous air pollutants (HAP) that adversely affect human health, for example aromatic hydrocarbons. In order to assure safe operation, decrease air pollution and minimize population exposure to HAP the South Coast Air Quality Management District (SCAQMD) has a number of regulations for petrochemical facilities. However, significant uncertainties still exist in emission estimates and traditional monitoring techniques often do not allow for real-time emission monitoring. In the fall of 2015 the SCAQMD, Fluxsense Inc., the National Physical Laboratory (NPL), and Atmosfir Optics Ltd. conducted a measurement study to characterize and quantify gaseous emissions from the tank farm of one of the largest oil refineries in the SCAB. Fluxsense used a vehicle equipped with Solar Occultation Flux (SOF), Differential Optical Absorption Spectroscopy (DOAS), and Extractive Fourier Transform Infrared (FTIR) spectroscopy instruments. Concurrently, NPL operated their Differential Absorption Lidar (DIAL) system. Both research groups quantified emissions from the entire tank farm and identified fugitive emission sources within the farm. At the same time, Atmosfir operated an Open Path FTIR (OP-FTIR) spectrometer along the fenceline of the tank farm. During this presentation we will discuss the results of the emission measurements from the tank farm of the petrochemical facility. Emission rates resulting from measurements by different ORS methods will be compared and discussed in detail.

  10. Isolation and screening of native polyhydroxyalkanoate producing bacteria from oil contaminated soils of Abadan refinery

    Directory of Open Access Journals (Sweden)

    Hossein MOtamedi

    2015-02-01

    Full Text Available   Introduction : Environmental contaminations due to petrochemical plastic usage have forced researchers to search new biological methods for biodegradable polymer production. The aim of this study was to find native PHA producing bacteria from Abadan oil refinery in order to be used in biodegradable polymer production studies.   Materials and method s : For this purpose soil samples were harvested from oil sludge contaminated soil of Abadan refinery. After primary enrichment, screening of PHA producing bacteria was done by PHA- Detection agar and was confirmed by Sudan black and Nile Blue A staining methods. These isolates were identified based on phenotypic methods and sequencing of 16s rRNA. Polymer extraction was performed and optimized using different concentrations of HClO and SDS.   Results : As a result of this study 26 different bacterial isolates were obtained from which 17 isolates were PHA producer with different potentiality. Based on the polymer accumulation 4 isolates were selected for further studies. The efficiency of PHA production in these isolates was 75.53±5.08, 82±19.05, 81.06±6.92 and 79.86±11.84%. Based on sequence analysis in NCBI database, these isolates were identified as Bacillus cereus.   Discussion and conclusion : With respect to the results of this study it can be suggested that oil contaminated soils due to high C/N and C/P ratios and also different carbohydrate contents are suitable candidates for PHA producer bacteria isolation. So the native strains in such habitats with high carbon content can be optimized for industrial polymer production.

  11. Evaluation the Amount of Emission and Sulfur Dioxide Emission Factor from Tehran Oil Refinery

    Directory of Open Access Journals (Sweden)

    Chavoshi B.

    2011-06-01

    Full Text Available Bachgrounds and Objectives: Oil, gas and petrochemical are known as important sources of air pollutants and emission of green house gases. About 99 percent of sulfur dioxide in the air is produced from human resources. Although several samples have been taken from industries and refineries' output by environmental experts and private companies, but accurate assessment is not available based on pollutant emissions on product levels (emission coefficients and on the total amount of the annual emission which, can be used as basic modeling of air pollution and planning.Materials and Methods: This study was cross sectional and the output of the chimney measured with Testo 350 XL system. Performance standard was determined based on ASTM D6522 EPACTMO30-41. The amounts of sulfur dioxide were measured from Tehran oil refinery's outlet from the beginning of the march 2007 till the year 2008 for 20 months. Sampling was carried out on averaged range (9 am to 14 pm.Results: The results showed that Northern Distillation unit produced pollutants' concentration more than 3 times in the southern Distillation unit. An emission of pollutants from Northern unit was, 2.8 times higher than the Southern unit. The northern emission factor was 5.6 times higher than the value obtained from southern unit. The Concentration, emissions and coefficient of sulfur dioxide in North catalyst convert unit were more than 2 times in comparison with the same South unit. These three factors in northern concentration breakers unit were 3, 2.6 and 2.6 times higher than the Southern concentration breakers unit‚ respectively.Discussion: Emission rate in all northern units is 2 to 3 times more than similar southern units. The production volumes in northern units are higher than the southern units and the southern units designed properly to remove more pollutants .The use of new technologies in production processes and application of the latest scientific resources can play a major role

  12. Potential tsunami impact on a refinery in North-Eastern Sicily

    Science.gov (United States)

    Cruz, A. M.; Franchello, G.; Krausmann, E.

    2009-04-01

    Industrial facilities located in coastal areas subject to tsunami hazards may be at risk of tsunami impact and damage. Furthermore, if hazardous materials are present these can be accidentally released impacting nearby residents and dispersing into the environment. We have analysed the potential impact of two tsunami scenarios originating in the Tyrrhenian Sea and their consequences at an industrial facility located on the coast in North-Eastern Sicily. The results of the tsunami simulations indicate that in both scenarios there would be between 30-45 storage tanks at the industrial facility (potentially exposing up to 1.4 million m3 of chemicals) subject to flooding, with tanks closer to the beach suffering up to 1.6 m inundation. Flow velocities in most areas are less than 1 m/s. This indicates that any damage would occur due to hydrostatic uplift forces due to buoyancy particularly in the western part of the facility where inundation levels are higher and storage tanks are less protected. Damage to the facility due to impact of floating debris may be a problem at the eastern most tip of the refinery where the distance between the waterline and the refinery fence line is less than 20 m. Foundation soils and foundation systems could also be at risk from shear- and liquefaction-induced scour in this section of the plant. The likelihood for hazardous materials releases from inundated storage tanks is low but could occur due to breakage of connected pipelines and flanges due to floating off of storage tanks and other connected appurtenances. Flooding of electrical equipment such as control panels, pumps and motors, not raised above the inundation level could suffer water intrusion.

  13. Opportunities and challenges at the interface between petrochemicals and refinery. The OMV view

    Energy Technology Data Exchange (ETDEWEB)

    Lichtscheidl, J. [OMV Refining and Marketing GmbH, Vienna (Austria)

    2007-07-01

    OMV's refineries have been integrated into petrochemicals since the first steam cracker came on line in 1970. The refineries in Schwechat, Burghausen and Romania, especially Arpechim, have significant petrochemical capacities. In 1998 PCD was merged with Borealis, a leading producer of high grade polymers. OMV's initial 25% stake in Borealis increased to 36 in 2007. The last years have seen major investments in Schwechat and Burghausen: Schwechat's cracker was expanded by approximately 150 KTA to a nominal 500 KTA of ethylene. And in Burghausen the revamp of the cracker has been combined with a metathesis unit in order to feed a new 330 KTA polypropylene plant. The polymer market is still growing. However, the bulk of investments to increase capacity are located in the Middle East and in the Asia-Pacific region, predominately in China. As more and more products from these regions find their way to Europe, the European petrochemicals industry faces fierce competition. The response is restructuring: the creation of Arkema (Total), the takeover of BP's petrochemical assets by INEOS, the disposal of Shell-BASF subsidiary Basell to Haldia Petrochemical and Accent Industries, and the transfer of Statoil's interest in Borealis to IPIC and OMV. And most recently, Basell's acquisition of Lyondell. Compared with competitors in the Middle East and the Asia-Pacific region, producers in Europe are burdened with serious disadvantages: fairly old, small units and high costs of labor, energy and raw materials. There is no single solution. OMV, however, will continue to follow the strategies that have been successful so far: - Ever closer integration of refining and petrochemicals; - Capturing market opportunities for profitable growth; -Remaining market orientated. (orig.)

  14. Bioconversion of biodiesel refinery waste in the bioemulsifier by Trichosporon mycotoxinivorans CLA2

    Directory of Open Access Journals (Sweden)

    de Souza Monteiro Andrea

    2012-05-01

    Full Text Available Abstract Background The microbial bioemulsifiers was surface active compounds, are more effective in stabilizing oil-in-water emulsions. The yeasts have been isolated to produce bioemulsifiers from vegetable oils and industrial wastes. Results Trichosporon mycotoxinivorans CLA2 is bioemulsifier-producing yeast strain isolated from effluents of the dairy industry, with ability to emulsify different hydrophobic substrates. Bioemulsifier production (mg/L and the emulsifying activity (E24 of this strain were optimized by response surface methodology using mineral minimal medium containing refinery waste as the carbon source, which consisted of diatomaceous earth impregnated with esters from filters used in biodiesel purification. The highest bioemulsifier production occurred in mineral minimal medium containing 75 g/L biodiesel residue and 5 g/L ammonium sulfate. The highest emulsifying activity was obtained in medium containing 58 g/L biodiesel refinery residue and 4.6 g/L ammonium sulfate, and under these conditions, the model estimated an emulsifying activity of 85%. Gas chromatography and mass spectrometry analysis suggested a bioemulsifier molecule consisting of monosaccharides, predominantly xylose and mannose, and a long chain aliphatic groups composed of octadecanoic acid and hexadecanoic acid at concentrations of 48.01% and 43.16%, respectively. The carbohydrate composition as determined by GC-MS of their alditol acetate derivatives showed a larger ratio of xylose (49.27%, mannose (39.91%, and glucose (10.81%. 1 H NMR spectra confirmed by COSY suggested high molecular weight, polymeric pattern, presence of monosaccharide’s and long chain aliphatic groups in the bioemulsifier molecule. Conclusions The biodiesel residue is an economical substrate, therefore seems to be very promising for the low-cost production of active emulsifiers in the emulsification of aromatics, aliphatic hydrocarbons, and kerosene.

  15. Manufacture Of Pozzolanic Cement From RFCC Spent Catalyst In Khartoum Refinery

    Directory of Open Access Journals (Sweden)

    Husam E Mustafa

    2015-08-01

    Full Text Available Pozzolana is defined as Siliceous and aluminous material which reacts with calcium hydroxide in presence of water at room temperature to form strong slow-hardening cement. Pozzolana has the advantage of reduction of leachibility of calcium hydroxide liberated during the setting and hydration of cement. In Khartoum Refinery five to ten tons per week of spent catalyst are produced in fine powder this quantity is sent to dumping sites or landfills. In this study pilot experiments were successfully carried out at different ratios to produce cement. The RFCC spent catalyst samples were subjected to chemical analysis to determine the content of Al2O3 SiO3TiO3 CaO and V2O5 ..etc. These were found to be 49.5 41.1 0.32 1.4 and 0.09 percent respectively other compounds are Na2O MgO P2O5SO3 K2O MnOFe2O3Co3O4 and NiO2 with. It is found that the percentages of SiO2 Al2O3 and Fe2O3 amount up to 91.5 that is above the ASTM standard C6182003 which stipulated that the minimum of such compound is 70 . Physical properties of RFCC spent catalyst were also carried out including crystallinity and Pozzolanicity index. The cement produced was tested for compressive strength consistency and setting time .It is concluded that RFCC spent catalyst in Khartoum Refinery is a Pozzolanic material and up to 30 replacement from Portland cement blended cement complies with the Sudanese and European Standards No SSMO 39982011and EN-197-11992 respectively. The study shows that the compressive strength of blended Pozzolanic cements decreases with increasing Pozzolana content. From the foregoing it is recommended to use RFCC spent catalyst with Portland cement as blended cement to produce mortars for construction and concrete.

  16. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31

    The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using known refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to

  17. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31

    The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using known refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to

  18. Wastewater treatment by flotation

    Directory of Open Access Journals (Sweden)

    F.P. Puget

    2000-12-01

    Full Text Available This work deals with the performance analysis of a separation set-up characterized by the ejector-hydrocyclone association, applied in the treatment of a synthetic dairy wastewater effluent. The results obtained were compared with the results from a flotation column (cylindrical body of a hydrocyclone operated both batch and continuously. As far as the experimental set-up studied in this work and the operating conditions imposed to the process, it is possible to reach a 25% decrease in the total effluent chemical oxygen demand (COD. This corresponds approximately to 60% of the COD of the material in suspension. The best results are obtained for ratios air flow rate-feed flow rate (Qair/Q L greater then 0.15 and for ratios underflow rate-overflow rate (Qu/Qo lower than 1.0.

  19. Isolation and Characterization of Hydrocarbon-Degrading Yeast Strains from Petroleum Contaminated Industrial Wastewater

    Directory of Open Access Journals (Sweden)

    Boutheina Gargouri

    2015-01-01

    Full Text Available Two yeast strains are enriched and isolated from industrial refinery wastewater. These strains were observed for their ability to utilize several classes of petroleum hydrocarbons substrates, such as n-alkanes and aromatic hydrocarbons as a sole carbon source. Phylogenetic analysis based on the D1/D2 variable domain and the ITS-region sequences indicated that strains HC1 and HC4 were members of the genera Candida and Trichosporon, respectively. The mechanism of hydrocarbon uptaking by yeast, Candida, and Trichosporon has been studied by means of the kinetic analysis of hydrocarbons-degrading yeasts growth and substrate assimilation. Biodegradation capacity and biomass quantity were daily measured during twelve days by gravimetric analysis and gas chromatography coupled with mass spectrometry techniques. Removal of n-alkanes indicated a strong ability of hydrocarbon biodegradation by the isolated yeast strains. These two strains grew on long-chain n-alkane, diesel oil, and crude oil but failed to grow on short-chain n-alkane and aromatic hydrocarbons. Growth measurement attributes of the isolates, using n-hexadecane, diesel oil, and crude oil as substrates, showed that strain HC1 had better degradation for hydrocarbon substrates than strain HC4. In conclusion, these yeast strains can be useful for the bioremediation process and decreasing petroleum pollution in wastewater contaminated with petroleum hydrocarbons.

  20. Isolation and Characterization of Hydrocarbon-Degrading Yeast Strains from Petroleum Contaminated Industrial Wastewater

    Science.gov (United States)

    Gargouri, Boutheina; Mhiri, Najla; Karray, Fatma; Aloui, Fathi; Sayadi, Sami

    2015-01-01

    Two yeast strains are enriched and isolated from industrial refinery wastewater. These strains were observed for their ability to utilize several classes of petroleum hydrocarbons substrates, such as n-alkanes and aromatic hydrocarbons as a sole carbon source. Phylogenetic analysis based on the D1/D2 variable domain and the ITS-region sequences indicated that strains HC1 and HC4 were members of the genera Candida and Trichosporon, respectively. The mechanism of hydrocarbon uptaking by yeast, Candida, and Trichosporon has been studied by means of the kinetic analysis of hydrocarbons-degrading yeasts growth and substrate assimilation. Biodegradation capacity and biomass quantity were daily measured during twelve days by gravimetric analysis and gas chromatography coupled with mass spectrometry techniques. Removal of n-alkanes indicated a strong ability of hydrocarbon biodegradation by the isolated yeast strains. These two strains grew on long-chain n-alkane, diesel oil, and crude oil but failed to grow on short-chain n-alkane and aromatic hydrocarbons. Growth measurement attributes of the isolates, using n-hexadecane, diesel oil, and crude oil as substrates, showed that strain HC1 had better degradation for hydrocarbon substrates than strain HC4. In conclusion, these yeast strains can be useful for the bioremediation process and decreasing petroleum pollution in wastewater contaminated with petroleum hydrocarbons. PMID:26339653

  1. Optimization of electrocoagulation (EC) process for the purification of a real industrial wastewater from toxic metals.

    Science.gov (United States)

    Gatsios, Evangelos; Hahladakis, John N; Gidarakos, Evangelos

    2015-05-01

    In the present work, the efficiency evaluation of electrocoagulation (EC) in removing toxic metals from a real industrial wastewater, collected from Aspropyrgos, Athens, Greece was investigated. Manganese (Mn), copper (Cu) and zinc (Zn) at respective concentrations of 5 mg/L, 5 mg/L and 10 mg/L were present in the wastewater (pH=6), originated from the wastes produced by EBO-PYRKAL munitions industry and Hellenic Petroleum Elefsis Refineries. The effect of operational parameters such as electrode combination and distance, applied current, initial pH and initial metal concentration, was studied. The results indicated that Cu and Zn were totally removed in all experiments, while Mn exhibited equally high removal percentages (approximately 90%). Decreasing the initial pH and increasing the distance between electrodes, resulted in a negative effect on the efficiency and energy consumption of the process. On the other hand, increasing the applied current, favored metal removal but resulted in a power consumption increase. Different initial concentrations did not affect metal removal efficiency. The optimal results, regarding both cost and EC efficiency, were obtained with a combination of iron electrodes, at 2 cm distance, at initial current of 0.1 A and pH=6. After 90 min of treatment, maximum removal percentages obtained were 89% for Mn, 100% for Cu and 100% for Zn, at an energy consumption of 2.55 kWh/m(3).

  2. Isolation and Characterization of Hydrocarbon-Degrading Yeast Strains from Petroleum Contaminated Industrial Wastewater.

    Science.gov (United States)

    Gargouri, Boutheina; Mhiri, Najla; Karray, Fatma; Aloui, Fathi; Sayadi, Sami

    2015-01-01

    Two yeast strains are enriched and isolated from industrial refinery wastewater. These strains were observed for their ability to utilize several classes of petroleum hydrocarbons substrates, such as n-alkanes and aromatic hydrocarbons as a sole carbon source. Phylogenetic analysis based on the D1/D2 variable domain and the ITS-region sequences indicated that strains HC1 and HC4 were members of the genera Candida and Trichosporon, respectively. The mechanism of hydrocarbon uptaking by yeast, Candida, and Trichosporon has been studied by means of the kinetic analysis of hydrocarbons-degrading yeasts growth and substrate assimilation. Biodegradation capacity and biomass quantity were daily measured during twelve days by gravimetric analysis and gas chromatography coupled with mass spectrometry techniques. Removal of n-alkanes indicated a strong ability of hydrocarbon biodegradation by the isolated yeast strains. These two strains grew on long-chain n-alkane, diesel oil, and crude oil but failed to grow on short-chain n-alkane and aromatic hydrocarbons. Growth measurement attributes of the isolates, using n-hexadecane, diesel oil, and crude oil as substrates, showed that strain HC1 had better degradation for hydrocarbon substrates than strain HC4. In conclusion, these yeast strains can be useful for the bioremediation process and decreasing petroleum pollution in wastewater contaminated with petroleum hydrocarbons.

  3. Treating Wastewater With Immobilized Enzymes

    Science.gov (United States)

    Jolly, Clifford D.

    1991-01-01

    Experiments show enzymes are immobilized on supporting materials to make biocatalyst beds for treatment of wastewater. With suitable combination of enzymes, concentrations of various inorganic and organic contaminants, including ammonia and urea, reduced significantly.

  4. Economic Analysis on Wastewater Reuse

    Institute of Scientific and Technical Information of China (English)

    Yushan WAN; Na LI

    2012-01-01

    Abstract The shortage of water resources social development. Wastewater reuse is an has become a major limiting factor for effective solution to solve water short- ages, which not only has economic benefits, but also has significant social and en- vironmental benefits. The economic evaluation is an important component in the study of wastewater reuse feasibility and the basis for the program optimization and economic feasibility determination.

  5. A review on wastewater disinfection

    OpenAIRE

    Mohammad Mehdi Amin; Hassan Hashemi; Amir Mohammadi Bovini; Yung Tse Hung

    2013-01-01

    Changes in regulations and development of new technologies have affected the selection of alternative for treated wastewater disinfection. Disinfection is the last barrier of wastewater reclamation process to protect ecosystem safety and human health. Driving forces include water scarcity and drinking water supply, irrigation, rapid industrialization, using reclaimed water, source protection, overpopulation, and environmental protection. The safe operation of water reuse depends on effluent d...

  6. Analyzing Perceptions of Wellbeing in Relation to Refinería Esmeraldas, The Largest Oil Refinery in Ecuador

    Science.gov (United States)

    Toledo, K. S.; Valdivia, G.

    2016-12-01

    Refinería Esmeraldas, the largest oil refinery in Ecuador, has a great influence on the wellbeing of the mainly Afro-Ecuadorean neighborhoods that surround it. Understanding the extent of the refinery's influence on the local community is important as it contributes to a more effective planning for the predicted risks of environmental suffering associated with it, some of which may extend for generations to come. The problem of increased environmental burdens in low income communities of color, such as exposure to environmental pollutants, is often linked to improper regulation. Solutions are often framed in terms of stricter government policies, but equally important and more difficult to quantify factors, such as how pollution manifests in everyday life, also need to be addressed. This study uses primarily qualitative data, composed of structured interviews; spatial data; and audiovisual data, all of which was processed using analytic softwares such as Atlas.ti, Tableau, and ArcGIS, to map the experience of pollution and wellbeing in the city of Esmeraldas. The data was collected using a structured sample design, followed by snowball sampling in neighborhoods within the city. The findings indicate that the impacts of the refinery are not always direct, but rather affect various aspects of the life of Esmeraldeños. Several major wellbeing themes include Personal Trajectories, (Dis)able Bodies, and Urban Needs. These themes provide a more holistic understanding of life with pollution and help understand how people see themselves in relation to the refinery and how it affects their wellbeing. Grounded theory, which adopts an inductive approach, was used to analyze the everyday dimensions of the experience of pollution. The findings suggest that there are varying experiences of wellbeing in relation the refinery and that these have health, environmental, social, and physiological roots, which indicate possible connections between epigenetic manifestations and the

  7. Well-to-Wheels Greenhouse Gas Emission Analysis of High-Octane Fuels with Ethanol Blending: Phase II Analysis with Refinery Investment Options

    Energy Technology Data Exchange (ETDEWEB)

    Han, Jeongwoo [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division; Wang, Michael [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division; Elgowainy, Amgad [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division; DiVita, Vincent [Jacobs Consultancy Inc., Houston, TX (United States)

    2016-08-01

    Higher-octane gasoline can enable increases in an internal combustion engine’s energy efficiency and a vehicle’s fuel economy by allowing an increase in the engine compression ratio and/or by enabling downspeeding and downsizing. Producing high-octane fuel (HOF) with the current level of ethanol blending (E10) could increase the energy and greenhouse gas (GHG) emissions intensity of the fuel product from refinery operations. Alternatively, increasing the ethanol blending level in final gasoline products could be a promising solution to HOF production because of the high octane rating and potentially low blended Reid vapor pressure (RVP) of ethanol at 25% and higher of the ethanol blending level by volume. In our previous HOF well-to-wheels (WTW) report (the so-called phase I report of the HOF WTW analysis), we conducted WTW analysis of HOF with different ethanol blending levels (i.e., E10, E25, and E40) and a range of vehicle efficiency gains with detailed petroleum refinery linear programming (LP) modeling by Jacobs Consultancy and showed that the overall WTW GHG emission changes associated with HOFVs were dominated by the positive impact associated with vehicle efficiency gains and ethanol blending levels, while the refining operations to produce gasoline blendstock for oxygenate blending (BOB) for various HOF blend levels had a much smaller impact on WTW GHG emissions (Han et al. 2015). The scope of the previous phase I study, however, was limited to evaluating PADDs 2 and 3 operation changes with various HOF market share scenarios and ethanol blending levels. Also, the study used three typical configuration models of refineries (cracking, light coking, and heavy coking) in each PADD, which may not be representative of the aggregate response of all refineries in each PADD to various ethanol blending levels and HOF market scenarios. Lastly, the phase I study assumed no new refinery expansion in the existing refineries, which limited E10 HOF production to the

  8. Experimental studies and mathematical modeling of an up-flow biofilm reactor treating mustard oil rich wastewater.

    Science.gov (United States)

    Chakraborty, Chandrima; Chowdhury, Ranjana; Bhattacharya, Pinaki

    2011-05-01

    Bioremediation of lipid-rich model wastewater was investigated in a packed bed biofilm reactor (anaerobic filter). A detailed study was conducted about the influence of fatty acid concentration on biomethanation of the high-fat liquid effluent of edible oil refineries. The biochemical methane potential (BMP) of the liquid waste was reported and maximum cumulative methane production at the exit of the reactor is estimated to be 785 ml CH(4) (STP)/(gVSS added). The effects of hydraulic retention time (HRT), organic loading rate (OLR) and bed porosity on the cold gas efficiency or energy efficiency of the bioconversion process were also investigated. Results revealed that the maximum cold gas efficiency of the process is 42% when the total organic load is 2.1 g COD/l at HRT of 3.33 days. Classical substrate uninhibited Monod model is used to generate the differential system equations which can predict the reactor behavior satisfactorily.

  9. 炼油污水回用处理RO系统的稳定运行及维护%Stable Operation and Maintenance of Refinery Sewage Recovery and Treatment RO System

    Institute of Scientific and Technical Information of China (English)

    田艳荣; 王永康; 曾俊峰; 张晓霞; 马文臣

    2012-01-01

    文章介绍了兰州石化公司炼油污水深度处理反渗透(RO)系统的工艺流程及维护.通过进出水电导率、产水回收率等变化情况,分析了RO系统的运行状况.得知:运用此系统,反渗透系统产水回收率达到65%~70%,系统脱盐率在99%以上,产水可以满足一级除盐水要求,实现了装置稳定运行的目标.%This paper describes the process of refinery wastewater advanced treatment reverse osmosis (RO) system in Lanzhou Petrochemical Company. Through outlet and inlet water conductivity and water recovery rate, it analyzes the operating conditions and introduces the maintenance of the RO system. RO water recovery rate is 65% to 70%, and the system desalination rate is more than 99%. The water can meet the first grade requirement of desalted water. Besides it achieves the goal of stable operation of the devices.

  10. Increasing the complexity of a refinery: a analysis of the economic impacts of the introduction of new process in refineries; O aumento da complexidade de uma refinaria: uma analise dos impactos economicos da introducao de novos processos em refinarias

    Energy Technology Data Exchange (ETDEWEB)

    Fontes, Cristiane M.; Seidl, Peter R. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Escola de Quimica

    2008-07-01

    The importance of the refining segment in the oil productive chain turns decision making on production and investment to be made at refineries dependent upon general context of the oil industry. Several technical and economic factors limit the possibilities to be foreseen by the managers. The ultimate goal of a refinery is to meet market demand in a region. Moreover, the type of processed oil and refining techniques will shape the profile of the production of derivatives. In a segment dynamic and full of uncertainties, such as refining, where the type of oil supplied to processing, specifications of products, and their demands, changes in the course of time, how to keep refining margins acceptable? This paper presents the relationship between the characteristics and the use of different kinds of oil, the characteristics of the national market of derivatives, and some characteristics of the refining processes considered in the study. The possible economic impacts that the introduction of different processes can bring to a refinery are analysed and alternatives for expansion are evaluated. To achieve these goals, a methodology for analysis considering the yield of Marlin oil refining for different schemes has been developed. (author)

  11. Removal of recalcitrant organic matter content in wastewater by means of AOPs aiming industrial water reuse.

    Science.gov (United States)

    Souza, Bianca M; Souza, Bruno S; Guimarães, Tarsila M; Ribeiro, Thiago F S; Cerqueira, Ana C; Sant'Anna, Geraldo L; Dezotti, Márcia

    2016-11-01

    This paper comes out from the need to provide an improvement in the current oil refinery wastewater treatment plant (WWTP) aiming to generate water for reuse. The wastewater was pretreated and collected in the WWTP after the biological treatment unit (bio-disks) followed by sand filtration. Ozonation (ozone concentration from 3.0-60 mgO3 L(-1)), UV (power lamp from 15 to 95 W), H2O2 (carbon:H2O2 molar ratio of 1:1, 1:2, and 1:4), and two advanced oxidation processes (UV/O3 and UV/H2O2) were investigated aiming to reduce the wastewater organic matter and generate water with suitable characteristics for the reverse osmosis operation and subsequent industrial reuse. Even after the biological and filtration treatments, the oil refinery wastewater still presented an appreciable amount of recalcitrant organic matter (TOC of 12-19 mgC L(-1)) and silt density index (SDI) higher than 4, which is considered high for subsequent reverse osmosis due to membrane fouling risks. Experiments using non combined processes (O3, H2O2, and UV only) showed a low degree of mineralization after 60 min of reaction, although the pretreatment with ozone had promoted the oxidation of aromatic compounds originally found in the real matrix, which suggests the formation of recalcitrant compounds. When the combined processes were applied, a considerable increase in the TOC removal was observed (max of 95 % for UV/O3 process, 55 W, 60 mgO3 L(-1)), likely due the presence of higher amounts of reactive species, specially hydroxyl radicals, confirming the important role of these species on the photochemical degradation of the wastewater compounds. A zero-order kinetic model was fitted to the experimental data and the rate constant values (k, mgC L(-1) h(-1)) ranged from 4.8 treatment were calculated as 5.4 and 81 Wh L(-1), respectively, for UV/O3 (15 W, 60 mgO3 L(-1)) and UV/H2O2 (95 W, 1C:1H2O2). Good results in terms of water conditioning for reverse osmosis operation were

  12. Induction of micronuclei and nuclear abnormalities in Oreochromis niloticus following exposure to petroleum refinery and chromium processing plant effluents

    Energy Technology Data Exchange (ETDEWEB)

    Cavas, Tolga [Mersin University, Faculty of Sciences and Letters, Department of Biology, 33342 Mersin (Turkey)]. E-mail: tcavas@mersin.edu.tr; Ergene-Goezuekara, Serap [Mersin University, Faculty of Sciences and Letters, Department of Biology, 33342 Mersin (Turkey)

    2005-09-10

    The genotoxic effects of effluents from a petroleum refinery and a chromium processing plant were evaluated in Oreochromis niloticus (Pisces: Perciformes) using the micronucleus test. Fish were exposed to different concentrations (5, 10 and 20%, v/v) of the effluents for 3, 6 and 9 days. Micronucleus analyses were carried out on gill epithelial cells and peripheral blood erythrocytes. Nuclear abnormalities other than micronuclei, considered as genetic damage indicators, were also evaluated on erythrocytes. Cyclophosphamide at a single dose of 4 mg/L was used as a positive control. The results of this study showed that both effluents had genotoxic potential. On the other hand, the level of genetic damage induced by petroleum refinery effluent was considerably higher than that of chromium processing plant effluent. Our results further indicate that nuclear abnormalities other than micronuclei, such as blebbed and lobed nuclei, may also be used as indicators of genotoxic damage.

  13. The impact of the maintenance management system: a case study of the PetroSA GTL refinery

    Directory of Open Access Journals (Sweden)

    Mahlangu, Bafana Petrus

    2015-11-01

    Full Text Available This research study investigated the impact of the maintenance management system (MMS on production output and profitability (PO&P at the PetroSA GTL refinery, a state-owned company. The two groups that participated were the maintenance group, consisting of 56 respondents, and the production group, with 38 respondents. The main findings of the research study suggested that the MMS impacts positively on PO&P at the PetroSA GTL refinery. The maintenance scorecard assessment tool – consisting of six perspectives – was used to assess the gap between the MMS and PO&P. The positivism paradigm, the deductive process, a cross-sectional quantitative survey, and descriptive statistics were used to conduct the research study.

  14. An Analysis of the Technological Structure of Refineries and Blenders: Estimation of the Leontief Multiproduct Cost Function and Reservation Prices

    Directory of Open Access Journals (Sweden)

    Juan Manuel Domínguez

    2015-01-01

    Full Text Available The Leontief multiproduct flexible cost function aims to give an approach to the technology used by refineries and blenders. In general, this cost function satisfies rational behavior restrictions imposed by economic theory. The estimated marginal costs are incorporated in a monopolistic competition model to calculate the virtual prices of other products provided by refineries and blenders in the hypothetical situation in which reformulated gasoline is absent in fuel markets. I have found that conventional gasoline and other product prices are greater than those in the mentioned hypothetical case. This result reflects the fact that consumers are being charged with high prices in order to have available a fuel which satisfies the Environmental Protection Agency (EPA regulations. Finally, when all the products become perfect substitutes, i.e. consumers are not interested in the quality of fuels, price differences tend to be negligibly small.

  15. Production of ethanol from refinery waste gases. Phase 3. Engineering development. Annual report, April 1, 1995--May 15, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Arora, D.; Basu, R.; Phillips, J.R.; Wikstrom, C.V.; Clausen, E.C; Gaddy, J.L.

    1996-11-01

    Refineries discharge large volumes of H2, CO, and CO 2 from cracking, coking, and hydrotreating operations. This R&D program seeks to develop, demonstrate, and commercialize a biological process for converting these waste gases into ethanol for blending with gasoline. A 200,000 BPD refinery could produce up to 38 million gallons ethanol per year. The program is being conducted in 3 phases: II, technology development; III, engineering development; and IV, demonstration. Phase I, exploratory development, has been completed. The research effort has yielded two strains (Isolates O-52 and C-01) which are to be used in the pilot studies to produce ethanol from CO, CO2, and H2 in petroleum waste gas. Results from single continuous stirred tank reactor (CSTR) laboratory tests have shown that 20-25 g/L ethanol can be produced with < 5 g/L acetic acid byproduct. Laboratory studies with two CSTRs in series have yielded ethanol concentrations of 30-35 g/L with 2-4 g/L acetic acid byproduct. Water recycle from distillation back to the fermenter shows that filtration of the water before distillation eliminates the recycle of toxic materials back to the fermenter. Product recovery in the process will use direct distillation to the azeotrope, followed by adsorption to produce neat ethanol. This is less energy intensive than e.g. solvent extraction, azeotropic distillation, or pervaporation. Economic projections are quite attractive; the economics are refinery stream dependent and thus vary depending on refinery location and operation.

  16. Using PM(2.5) lanthanoid elements and nonparametric wind regression to track petroleum refinery FCC emissions.

    Science.gov (United States)

    Du, Li; Turner, Jay

    2015-10-01

    A long term air quality study is being conducted in Roxana, Illinois, USA, at the fenceline of a petroleum refinery. Measurements include 1-in-6 day 24-hour integrated ambient fine particulate matter (PM2.5) speciation following the Chemical Speciation Network (CSN) sampling and analysis protocols. Lanthanoid elements, some of which are tracers of fluidized-bed catalytic cracker (FCC) emissions, are also measured by inductively coupled plasma-mass spectrometry (ICP-MS) after extraction from PM2.5 using hot block-assisted acid digestion. Lanthanoid recoveries of 80-90% were obtained for two ambient particulate matter standard reference materials (NIST SRM 1648a and 2783). Ambient PM2.5 La patterns could be explained by a two-source model representing resuspended soil and FCC emissions with enhanced La/Ce ratios when impacted by the refinery. Nonparametric wind regression demonstrates that when the monitoring station was upwind of the refinery the mean La/Ce ratio is consistent with soil and when the monitoring station is downwind of the refinery the mean ratio is more than four times higher for bearings that corresponds to maximum impacts. Source apportionment modeling using EPA UNMIX and EPA PMF could not reliably apportion PM2.5 mass to the FCC emissions. However, the weight of evidence is that such contributions are small with no large episodes observed for the 164 samples analyzed. This study demonstrates the applicability of a hot block-assisted digestion protocol for the extraction of lanthanoid elements as well as insights obtained from long-term monitoring data including wind direction-based analyses.

  17. Illness Symptoms Experienced by Children Exposed to Benzene After a Flaring Incident at the BP Refinery Facility in Texas City.

    Science.gov (United States)

    D'Andrea, Mark A; Reddy, G Kesava

    2016-10-01

    Objective To evaluate the illness symptoms experienced by children who were exposed to benzene following a flaring incident at the BP refinery in Texas City, Texas. Methods A total of 641 children, aged 5 year (P = .04). Conversely, urinary phenol levels were significantly lower in children 5 years (P = .00). Conclusion Together, these findings reveal that children exposed to benzene experience a range of illness symptoms and an altered profile of urinary phenol indicating their vulnerability to potentially increased health complications.

  18. Establishing a risk reduction model for the inbound supply chain in an oil refinery / H.C. Swanepoel

    OpenAIRE

    Swanepoel, Helena Catharina

    2011-01-01

    Companies are in business to make money; money is not there just to be taken. The drive should be on Cash Focus and Project Excellence, the ultimate goal and first price is always to grow stakeholder value sustainability. To be able to achieve just that, the focus should be on: - Operations excellence - Functional excellence - Capital excellence - Value-driven leadership The mission of the oil refinery is to refine crude oil utilising high conversion capability, gen...

  19. An updated mortality study of workers at a petroleum refinery in Beaumont, Texas.

    Science.gov (United States)

    Raabe, G K; Collingwood, K W; Wong, O

    1998-01-01

    The mortality experience of 7,119 workers who were employed at a Beaumont, Texas, refinery for at least 1 year between 1945 and 1987 was investigated. Mortality analyses based on standardized mortality ratios (SMRs) and 95% confidence intervals (95% CI) showed overall mortality was significantly lower than expected compared with the U.S. general population (SMR = 82, 95% CI = 79-86). Total cancer mortality was also lower than expected (SMR = 92, 95% CI = 84-100). Significant mortality deficits from several malignant and nonmalignant diseases were reported. A significant mortality increase in the broad category of lymphatic and hematopoietic cancers was found (SMR = 133, 95% CI = 103-170). This increase was attributed to a nonsignificant elevation in leukemia of all cell types combined (SMR = 139, 95% CI = 92-201) and a borderline significant increase in other lymphatic tissue cancer (SMR = 158, 95% CI = 101-235). The elevation in leukemia was confined to workers hired before 1950. Furthermore, the leukemia excess was shown to have peaked during the 1960s, with mortality no longer elevated post-1980. Analyses of cell type-specific leukemias showed a similar temporal pattern for acute myeloid leukemia (AML) which was not significantly elevated (SMR = 136, 95% CI = 59-268). Mortality from other leukemia cell types was similar to or lower than expected. Mortality from non-Hodgkin's lymphoma (NHL) (SMR = 140, 95% CI = 88-211) and multiple myeloma (MM) (SMR = 121, 95% CI = 55-230) were increased, but neither was statistically significant nor likely to be related to refinery employment. No death from asbestosis was reported, and mortality from mesothelioma and pulmonary fibrosis was lower than expected. Lung cancer mortality for the overall cohort was similar to expected. For the overall cohort, analyses by duration of employment and time since first employment showed no evidence of any trends for increasing cause-specific mortality. Separate analyses of male workers

  20. An updated mortality study of workers at a petroleum refinery in Beaumont, Texas, 1945 to 1996.

    Science.gov (United States)

    Wong, O; Harris, F; Rosamilia, K; Raabe, G K

    2001-04-01

    The present investigation represents an update of a previous cohort mortality study of 7543 workers who were employed at a petroleum refinery in Beaumont, Texas, for at least 1 year between 1945 and 1996. The updated study covered an observation period of 51 years, from 1946 to 1996, with a total of 208,627 person-years of observation. A total of 3020 (40.0%) cohort members were known to have died. The mortality data were analyzed in terms of cause-specific standardized mortality ratios (SMRs) and 95% confidence intervals (95% CIs). The overall mortality of the cohort was significantly lower than expected when compared with that of the general US population (SMR, 95.7; 95% CI, 92.3 to 99.2). Overall cancer mortality was also lower than expected (SMR, 85.8; 95% CI, 79.4 to 92.5). For specific cancer sites, significant mortality deficits were observed for the following: buccal cavity and pharynx, esophagus, large intestine, rectum, larynx, lung, and bladder and other urinary organs. No significant increase was reported for any site-specific cancer. A non-significant increase in acute myeloid leukemia was observed among male employees (SMR, 147.2; 95% CI, 76.1 to 257.2). Detailed analyses indicated that the excess was restricted to workers hired before 1950. No increase was detected for other leukemia cell-types, non-Hodgkin's lymphoma, or multiple myeloma. For non-malignant diseases, the majority of SMRs were below 100, and no significant increase was observed for any cause. In particular, significant mortality deficits were reported for ischemic heart disease (SMR, 91.0; 95% CI, 85.4 to 96.9), non-malignant respiratory disease (SMR, 61.5; 95% CI, 52.2 to 72.0), pulmonary fibrosis (SMR, 51.0; 95% CI, 22.0 to 100.4), cirrhosis of the liver (SMR, 47.2; 95% CI, 30.6 to 69.7), and accidents (SMR, 81.7; 95% CI, 66.3 to 99.6). Separate analyses of male workers by job classification (process and maintenance) were conducted. Mortality from acute myeloid leukemia was elevated

  1. Carbon Capture and Sequestration from a Hydrogen Production Facility in an Oil Refinery

    Energy Technology Data Exchange (ETDEWEB)

    Engels, Cheryl; Williams, Bryan, Valluri, Kiranmal; Watwe, Ramchandra; Kumar, Ravi; Mehlman, Stewart

    2010-06-21

    The project proposed a commercial demonstration of advanced technologies that would capture and sequester CO2 emissions from an existing hydrogen production facility in an oil refinery into underground formations in combination with Enhanced Oil Recovery (EOR). The project is led by Praxair, Inc., with other project participants: BP Products North America Inc., Denbury Onshore, LLC (Denbury), and Gulf Coast Carbon Center (GCCC) at the Bureau of Economic Geology of The University of Texas at Austin. The project is located at the BP Refinery at Texas City, Texas. Praxair owns and operates a large hydrogen production facility within the refinery. As part of the project, Praxair would construct a CO2 capture and compression facility. The project aimed at demonstrating a novel vacuum pressure swing adsorption (VPSA) based technology to remove CO2 from the Steam Methane Reformers (SMR) process gas. The captured CO2 would be purified using refrigerated partial condensation separation (i.e., cold box). Denbury would purchase the CO2 from the project and inject the CO2 as part of its independent commercial EOR projects. The Gulf Coast Carbon Center at the Bureau of Economic Geology, a unit of University of Texas at Austin, would manage the research monitoring, verification and accounting (MVA) project for the sequestered CO2, in conjunction with Denbury. The sequestration and associated MVA activities would be carried out in the Hastings field at Brazoria County, TX. The project would exceed DOE?s target of capturing one million tons of CO2 per year (MTPY) by 2015. Phase 1 of the project (Project Definition) is being completed. The key objective of Phase 1 is to define the project in sufficient detail to enable an economic decision with regard to proceeding with Phase 2. This topical report summarizes the administrative, programmatic and technical accomplishments completed in Phase 1 of the project. It describes the work relative to project technical and design activities

  2. DEGRADATION OF PETROLEUM REFINERY WASTE BY A CONSORTIUM OF HYDROCARBONOCLASTIC BACTERIA ON SEVERAL C:N:P RATIO

    Directory of Open Access Journals (Sweden)

    Syukria I Zam

    2012-01-01

    Full Text Available Bioremediation is an alternative method to treat petroleum waste using microorganism into nontoxic end product. The method is relatively cheap, effective, and environmental friendly. A key factor influencing bioremediation process for petroleum refinery waste treatment is C:N:P ratio of bacterial growth medium. The objective of this research was to obtain C:N:P ratio of Stone Mineral Salt Solution (SMSS medium that allow optimal degradation of petroleum refinery waste by consortium of hydrocarbonoclastic bacteria. C:N:P ratio of SMSS medium was adjusted to ratio of 100:10:1, 100:10:0.5, 100:5:1, and 100:5:0.5. We demonstrate that optimal degradation of petroleum refinery waste by a consortium of hydrocarbonoclastic bacteria was achieved in SMSS medium with C:N:P ratio of 100:5:1. It allowed 66.55% degradation of total petroleum hydrocarbon (TPH and 85.18 % decrease of chemical oxygen demand (COD value.

  3. Economic impacts of bio-refinery and resource cascading systems: an applied general equilibrium analysis for Poland.

    Science.gov (United States)

    Ignaciuk, Adriana M; Sanders, Johan

    2007-12-01

    Due to more stringent energy and climate policies, it is expected that many traditional chemicals will be replaced by their biomass-based substitutes, bio-chemicals. These innovations, however, can influence land allocation since the demand for land dedicated to specific crops might increase. Moreover, it can have an influence on traditional agricultural production. In this paper, we use an applied general equilibrium framework, in which we include two different bio-refinery processes and incorporate so-called cascading mechanisms. The bio-refinery processes use grass, as one of the major inputs, to produce bio-nylon and propane-diol (1,3PDO) to substitute currently produced fossil fuel-based nylon and ethane-diol. We examine the impact of specific climate policies on the bioelectricity share in total electricity production, land allocation, and production quantities and prices of selected commodities. The novel technologies become competitive, with an increased stringency of climate policies. This switch, however, does not induce a higher share of bioelectricity. The cascade does stimulate the production of bioelectricity, but it induces more of a shift in inputs in the bioelectricity sector (from biomass to the cascaded bio-nylon and 1, 3PDO) than an increase in production level of bioelectricity. We conclude that dedicated biomass crops will remain the main option for bioelectricity production: the contribution of the biomass systems remains limited. Moreover, the bioelectricity sector looses a competition for land for biomass production with bio-refineries.

  4. An investigation of the matrix sensitivity of refinery gas analysis using gas chromatography with flame ionisation detection.

    Science.gov (United States)

    Ferracci, Valerio; Brown, Andrew S; Harris, Peter M; Brown, Richard J C

    2015-02-27

    The response of a flame ionisation detector (FID) on a gas chromatograph to methane, ethane, propane, i-butane and n-butane in a series of multi-component refinery gas standards was investigated to assess the matrix sensitivity of the instrument. High-accuracy synthetic gas standards, traceable to the International System of Units, were used to minimise uncertainties. The instrument response exhibited a small dependence on the component amount fraction: this behaviour, consistent with that of another FID, was thoroughly characterised over a wide range of component amount fractions and was shown to introduce a negligible bias in the analysis of refinery gas samples, provided a suitable reference standard is employed. No significant effects of the molar volume, density and viscosity of the gas mixtures on the instrument response were observed, indicating that the FID is suitable for the analysis of refinery gas mixtures over a wide range of component amount fractions provided that appropriate drift-correction procedures are employed. Copyright © 2015 Elsevier B.V. All rights reserved.

  5. A METHODOLOGY BASED ON AN ECOLOGICAL ECONOMY APPROACH FOR THE INTEGRATING MANAGEMENT OF THE SULPHUROUS WATER IN AN OIL REFINERY

    Directory of Open Access Journals (Sweden)

    Gabriel Orlando Lobelles Sardiñas

    2016-10-01

    Full Text Available Despite the current highly stringent international standards regulating the contaminating emissions to the environment, the Oil refinery of Cienfuegos is still generating liquid and gaseous emissions contaminating the environment. The construction of new units as part of the Refinery expansion leads to an increase of these emissions due to the lack of technologies for the reutilization of the sulphurous water. The objective of this paper is to propose a methodology for the integral management of the sulphurous residual water in the oil refining process, including the evaluation and selection of the most feasible technological variant to minimize the sulphur contamination of water and the resulting emissions during the process. The methodology is based on the ecological economy tools, allowing a comprehensible evaluation of six technological variants at the refinery of Cienfuegos. The Life Cycle Assessment was applied (ACV by its Spanish acronym, by means of the software SimaPro 7.1. It was evaluated through the Eco Speed Method, to minimize the possible uncertainty. An economic evaluation was performed, taking into account the external costs for a more comprehensive analysis, enabling, along with the ecological indicators, the selection of the best technological variant, achieving a methodology based on a comprehensive evaluation, and as a positive impact, the implementation of the chosen variant (V5, 98.27% of the process water was recovered, as well as the sulphur that recovered from 94 to 99.8 %, reducing the emissions from 12 200 to 120 mg/Nm3 as SO2.

  6. Competitive strategy to provide technology and basic designs for the construction of new refineries premium of the PETROBRAS; Estrategia competitiva para prover tecnologias e projetos basicos para a construcao de novas refinarias premium da PETROBRAS

    Energy Technology Data Exchange (ETDEWEB)

    Claudia, Baptista M.L.A.; Adalberto, Barbalho S. [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)

    2012-07-01

    Nowadays, there are major incentives for the construction of new refineries in Brazil: the increase of the local market and the discovery of huge oil reserves in the southeastern Atlantic coast of Brazil. In this scenario, PETROBRAS decided to construct two new refineries, Premium I and II, with a total refining capacity of 900.000 BPSD. The refineries will be designed to process a mix of Brazilian national crudes. The main objects of this ambitious project are to produce high quality diesel and jet fuel from an elevated nitrogen content feedstock, minimizing capital expenditure and schedule. Both refineries will have the same flow scheme with a target to maximize Middle distillate production for the European and local markets. In order to assure that the refinery scheme and the technologies selected will provide the best Net Present Value (NPV), it was decided to perform a Design Competition process to select the company to provide the basic design for all Premium refineries. As the concepts behind a Design Competition were new for PETROBRAS a rigorous process was developed and followed, which entailed contracting three benchmark companies with outstanding knowledge and experience in hydroprocessing to provide independent conceptual studies for a 300.000 BPSD refinery called Premium II. The vision was to utilize the same refinery scheme in the construction of the Premium I refinery which will have two identical trains processing 300.000 BPD. The awarded company was selected based on technical and economic evaluations, supported by state of the art hydroprocessing technologies, block flow diagram optimization and heat integration. This strategy allowed PETROBRAS to acquire the best refinery scheme and process designs for the PREMIUM refineries. The present paper discusses the design competition process, the refinery scheme adopted and the results achieved. (author)

  7. 40 CFR 63.1256 - Standards: Wastewater.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 11 2010-07-01 2010-07-01 true Standards: Wastewater. 63.1256 Section... for Pharmaceuticals Production § 63.1256 Standards: Wastewater. (a) General. Each owner or operator of any affected source (existing or new) shall comply with the general wastewater requirements...

  8. 18 CFR 1304.402 - Wastewater outfalls.

    Science.gov (United States)

    2010-04-01

    ... 18 Conservation of Power and Water Resources 2 2010-04-01 2010-04-01 false Wastewater outfalls. 1304.402 Section 1304.402 Conservation of Power and Water Resources TENNESSEE VALLEY AUTHORITY APPROVAL... Miscellaneous § 1304.402 Wastewater outfalls. Applicants for a wastewater outfall shall provide copies of...

  9. 40 CFR 63.1330 - Wastewater provisions.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 11 2010-07-01 2010-07-01 true Wastewater provisions. 63.1330 Section... for Hazardous Air Pollutant Emissions: Group IV Polymers and Resins § 63.1330 Wastewater provisions... subpart. (10) Whenever §§ 63.132 through 63.149 refer to a Group 1 wastewater stream or a Group...

  10. 40 CFR 63.501 - Wastewater provisions.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 9 2010-07-01 2010-07-01 false Wastewater provisions. 63.501 Section... for Hazardous Air Pollutant Emissions: Group I Polymers and Resins § 63.501 Wastewater provisions. (a... comply with the requirements of §§ 63.132 through 63.147 for each process wastewater stream...

  11. Orientation to Municipal Wastewater Treatment. Training Manual.

    Science.gov (United States)

    Office of Water Program Operations (EPA), Cincinnati, OH. National Training and Operational Technology Center.

    Introductory-level material on municipal wastewater treatment facilities and processes is presented. Course topics include sources and characteristics of municipal wastewaters; objectives of wastewater treatment; design, operation, and maintenance factors; performance testing; plant staffing; and laboratory considerations. Chapter topics include…

  12. 40 CFR 63.1433 - Wastewater provisions.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 11 2010-07-01 2010-07-01 true Wastewater provisions. 63.1433 Section... for Hazardous Air Pollutant Emissions for Polyether Polyols Production § 63.1433 Wastewater provisions. (a) Process wastewater. Except as specified in paragraph (c) of this section, the owner or...

  13. Cancer mortality among petroleum refinery and chemical manufacturing workers in Texas.

    Science.gov (United States)

    Cooper, S P; Labarthe, D; Downs, T; Burau, K; Whitehead, L; Vernon, S; Spitz, M; New, B; Sigurdson, A

    1997-01-01

    Epidemiologic historical cohort studies of petroleum refinery and chemical manufacturing workers in Texas were reviewed to examine their cancer mortality in comparison to the U.S. and to assess the possible impact of cancer mortality among these workers on the State of Texas as a whole. Summary standardized mortality ratios and 95% confidence intervals were calculated for 20 cancer types, taking into account the heterogeneity of individual studies. There were 4314 cancer deaths among the 92,318 workers employed in 10 independent plant populations. Overall, there was a significant deficit in cancer mortality among petrochemical workers compared with the general U.S. population (SMR = 88, 95% CI = 80 to 96). Only the summary SMRs for brain cancer (SMR = 113, 95% CI = 96 to 133) and leukemias (SMR = 112, 95% CI = 94 to 130) approached statistical significance. Lung and liver cancer mortality excesses, noted for Texas as a whole, were decreased in these workers. Additional follow-up of these cohorts, their expansion to include minority and female workers, and additional study of possible occupational contributions to leukemia and brain cancer are recommended.

  14. Mineralisation of target hydrocarbons in three contaminated soils from former refinery facilities

    Energy Technology Data Exchange (ETDEWEB)

    Towell, Marcie G. [Lancaster Environment Centre, Lancaster University, Lancaster LA1 4YQ (United Kingdom); Bellarby, Jessica; Paton, Graeme I. [Institute of Biological and Environmental Sciences, University of Aberdeen, Aberdeen AB24 3UU (United Kingdom); Coulon, Frederic; Pollard, Simon J.T. [School of Applied Sciences, Sustainable Systems Department, Cranfield University, Cranfield (United Kingdom); Semple, Kirk T., E-mail: k.semple@lancaster.ac.u [Lancaster Environment Centre, Lancaster University, Lancaster LA1 4YQ (United Kingdom)

    2011-02-15

    This study investigated the microbial degradation of {sup 14}C-labelled hexadecane, octacosane, phenanthrene and pyrene and considered how degradation might be optimised in three genuinely hydrocarbon-contaminated soils from former petroleum refinery sites. Hydrocarbon mineralisation by the indigenous microbial community was monitored over 23 d. Hydrocarbon mineralisation enhancement by nutrient amendment (biostimulation), hydrocarbon degrader addition (bioaugmentation) and combined nutrient and degrader amendment, was also explored. The ability of indigenous soil microflora to mineralise {sup 14}C-target hydrocarbons was appreciable; {>=}16% mineralised in all soils. Generally, addition of nutrients or degraders increased the rates and extents of mineralisation of {sup 14}C-hydrocarbons. However, the addition of nutrients and degraders in combination had a negative effect upon {sup 14}C-octacosane mineralisation and resulted in lower extents of mineralisation in the three soils. In general, the rates and extents of mineralisation will be dependent upon treatment type, nature of the contamination and adaptation of the ingenious microbial community. - Research highlights: Indigenous microbes actively degrade {sup 14}C-hydrocarbons in field contaminated soils. Addition of nutrients or degraders enhance mineralisation in contaminated soils. Biodegradation is related to the presence of hydrocarbons and microbial activity. - Bioremediation strategy, native hydrocarbon concentrations and prior exposure histories of the microbial community influence hydrocarbon degradation in soil.

  15. Large scale low cost production of submicrometric powder through biomass refinery

    Directory of Open Access Journals (Sweden)

    Daltro Garcia Pinatti

    2003-06-01

    Full Text Available Biomass Refinery (BR is a null pollution thermochemical sequential cracking of any biomass and some petrochemical products, which generates chemicals, liquid or solid fuels and inorganic submicrometric/nanometric powders (SM/NM such as ashes, silica, and carbon black. The processing route, powder characterisation and addition of some ashes to red clay resulting a grès-type ceramics will be presented. Rupture strengths of the vitrified ceramics were respectively 36 MPa for pure clay, 44 MPa for clay + 13.5% MOL ash (organic matter of municipal solid waste, 50 MPa for clay + 20% F+20% CL* ash (50% MOL + 50% wood and 42 MPa for clay + 40% feldspar (used for comparison. The reason why the BR-ashes are better than feldspar is due to their submicrometric and partially nanometric nature. The impact of BR-ash technology can be evaluated by its national potential production of 2 × 10(6 ton/year only from municipal solid waste (MSW compared to 350,000 ton/year of national consumption. The first BR is under installation in Lorena - SP, Brazil.

  16. Electroacoustic isoelectric point determinations of bauxite refinery residues: different neutralization techniques and minor mineral effects.

    Science.gov (United States)

    Freire, Tiago S S; Clark, Malcolm W; Comarmond, M Josick; Payne, Timothy E; Reichelt-Brushett, Amanda J; Thorogood, Gordon J

    2012-08-14

    Bauxite refinery residue (BRR) is a highly caustic, iron hydroxide-rich byproduct from alumina production. Some chemical treatments of BRR reduce soluble alkalinity and lower residue pH (to values IEP) determination difficult. Consequently, the IEP of a BRR and five MBRR derivatives (sulfuric acid-, carbon dioxide-, seawater-, a hybrid neutralization, i.e, partial CO(2) neutralization followed by seawater, and an activated-seawater-neutralized MBRR) were determined using electroacoustic techniques. Residues showed three significantly different groups of IEPs (p IEPs were not significantly different from BRR (pH 6.6-6.9). However, neutralizations generating neoformational minerals (alkalinity precipitation) significantly increased the IEP to pH 8.1, whereas activation (a removal of some primary mineralogy) significantly lowered the IEP to pH 6.2. Moreover, surface charging curves show that surfaces remain in the ±30 mV surface charge instability range, which provides an explanation as to why MBRRs remove trace metals and oxyanions over a broad pH range, often simultaneously. Importantly, this work shows that minor mineral components in complex mineral systems may have a disproportionate effect on the observable bulk IEP. Furthermore, this work shows the appropriateness of electroacoustic techniques in investigating samples with significant soluble mineral components (e.g., ANC).

  17. An environmentally friendly process for the recovery of valuable metals from spent refinery catalysts.

    Science.gov (United States)

    Rocchetti, Laura; Fonti, Viviana; Vegliò, Francesco; Beolchini, Francesca

    2013-06-01

    The present study dealt with the whole valorization process of exhaust refinery catalysts, including metal extraction by ferric iron leaching and metal recovery by precipitation with sodium hydroxide. In the leaching operation the effects on metal recovery of the concentration and kind of acid, the concentration of catalyst and iron (III) were determined. The best operating conditions were 0.05 mol L(-1) sulfuric acid, 40 g L(-1) iron (III), 10% catalyst concentration; almost complete extraction of nickel and vanadium, and 50%extraction efficiency of aluminium and less than 20% for molybdenum. Sequential precipitation on the leach liquor showed that it was not possible to separate metals through such an approach and a recovery operation by means of a single-stage precipitation at pH 6.5 would simplify the procedures and give a product with an average content of iron (68%), aluminium (13%), vanadium (11%), nickel (6%) and molybdenum (1%) which would be potentially of interest in the iron alloy market. The environmental sustainability of the process was also assessed by means of life cycle assessment and yielded an estimate that the highest impact was in the category of global warming potential with 0.42 kg carbon dioxide per kg recovered metal.

  18. Nitrogen cycling in Bioregenerative Life Support Systems: Challenges for waste refinery and food production processes

    Science.gov (United States)

    Clauwaert, Peter; Muys, Maarten; Alloul, Abbas; De Paepe, Jolien; Luther, Amanda; Sun, Xiaoyan; Ilgrande, Chiara; Christiaens, Marlies E. R.; Hu, Xiaona; Zhang, Dongdong; Lindeboom, Ralph E. F.; Sas, Benedikt; Rabaey, Korneel; Boon, Nico; Ronsse, Frederik; Geelen, Danny; Vlaeminck, Siegfried E.

    2017-05-01

    In order to sustain human life in an isolated environment, an efficient conversion of wasted nutrients to food might become mandatory. This is particularly the case for space missions where resupply from earth or in-situ resource utilization is not possible or desirable. A combination of different technologies is needed to allow full recycling of e.g. nitrogenous compounds in space. In this review, an overview is given of the different essential processes and technologies that enable closure of the nitrogen cycle in Bioregenerative Life Support Systems (BLSS). Firstly, a set of biological and physicochemical refinery stages ensures efficient conversion of waste products into the building blocks, followed by the production of food with a range of biological methods. For each technology, bottlenecks are identified. Furthermore, challenges and outlooks are presented at the integrated system level. Space adaptation and integration deserve key attention to enable the recovery of nitrogen for the production of nutritional food in space, but also in closed loop systems on earth.

  19. Life Cycle Analysis of Bitumen Transportation to Refineries by Rail and Pipeline.

    Science.gov (United States)

    Nimana, Balwinder; Verma, Aman; Di Lullo, Giovanni; Rahman, Md Mustafizur; Canter, Christina E; Olateju, Babatunde; Zhang, Hao; Kumar, Amit

    2017-01-03

    Crude oil is currently transported primarily by pipelines and rail from extraction sites to refineries around the world. This research evaluates energy use and greenhouse gas (GHG) emissions for three scenarios (synthetic crude oil and dilbit with and without diluent return) in which 750 000 bpd of Alberta's bitumen is transported 3000 km to determine which method has a lower environmental impact. Each scenario has a pipeline and rail pathway, and the dilbit without diluent return scenario has an additional heated bitumen pathway, which does not require diluent. An Excel based bottom-up model is developed using engineering first-principles to calculate mass and energy balances for each process. Results show that pipeline transportation produced between 61% and 77% fewer GHG emissions than by rail. The GHG emissions decreased by 15% and 73% for rail and pipelines as the capacity increased from 100 000 to 800 000 bpd. A Monte Carlo simulation was performed to determine the uncertainty in the emissions and found that the uncertainty was larger for pipelines (up to ±73%) and smaller for rail (up to ±28%). The uncertainty ranges do not overlap, thus confirming that pipelines have lower GHG emissions, which is important information for policy makers conducting pipeline reviews.

  20. A cross-cultural study of organizational factors on safety: Japanese vs. Taiwanese oil refinery plants.

    Science.gov (United States)

    Hsu, Shang Hwa; Lee, Chun-Chia; Wu, Muh-Cherng; Takano, Kenichi

    2008-01-01

    This study attempts to identify idiosyncrasies of organizational factors on safety and their influence mechanisms in Taiwan and Japan. Data were collected from employees of Taiwanese and Japanese oil refinery plants. Results show that organizational factors on safety differ in the two countries. Organizational characteristics in Taiwanese plants are highlighted as: higher level of management commitment to safety, harmonious interpersonal relationship, more emphasis on safety activities, higher devotion to supervision, and higher safety self-efficacy, as well as high quality of safety performance. Organizational characteristics in Japanese plants are highlighted as: higher level of employee empowerment and attitude towards continuous improvement, more emphasis on systematic safety management approach, efficient reporting system and teamwork, and high quality of safety performance. The casual relationships between organizational factors and workers' safety performance were investigated using structural equation modeling (SEM). Results indicate that the influence mechanisms of organizational factors in Taiwan and Japan are different. These findings provide insights into areas of safety improvement in emerging countries and developed countries respectively.

  1. Gasification of refinery sludge in an updraft reactor for syngas production

    Energy Technology Data Exchange (ETDEWEB)

    Ahmed, Reem; Eldmerdash, Usama [Department of Chemical Engineering, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak (Malaysia); Sinnathambi, Chandra M., E-mail: chandro@petronas.com.my [Fundamental and Applied Sciences Department, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak (Malaysia)

    2014-10-24

    The study probes into the investigation on gasification of dry refinery sludge. The details of the study includes; influence of operation time, oxidation temperature and equivalence ratios on carbon gas conversion rate, gasification efficiency, heating value and fuel gas yield are presented. The results show that, the oxidation temperature increased sharply up to 858°C as the operating time increased up to 36 min then bridging occurred at 39 min which cause drop in reaction temperature up to 819 °C. This bridging was found to affect also the syngas compositions, meanwhile as the temperature decreased the CO, H{sub 2}, CH{sub 4} compositions are also found to be decreases. Higher temperature catalyzed the reduction reaction (CO{sub 2}+C = 450 2CO), and accelerated the carbon conversion and gasification efficiencies, resulted in more solid fuel is converted to a high heating value gas fuel. The equivalence ratio of 0.195 was found to be the optimum value for carbon conversion and cold gas efficiencies, high heating value of gas, and fuel gas yield to reach their maximum values of 96.1 % and 53.7 %, 5.42 MJ Nm{sup −3} of, and 2.5 Nm{sup 3} kg{sup −1} respectively.

  2. Phytoremediation of Petroleum-Contaminated Soils around Isfahan Oil Refinery (Iran by Sorghum and Barley

    Directory of Open Access Journals (Sweden)

    Farida Irajy Asiabadi

    2014-04-01

    Full Text Available Petroleum compounds are one of the most frequently encountered pollutants in soils adjacent to oil refineries. Phytoremediation,where feasible, has become a cost-effective alternative to physicochemical methods of soil remediation. In this study, sorghum (Sorghum bicolor and barley (Hordeum vulgare were selected for phytoremediationand the diminution in the concentration of oil-based contaminants was measured during a 90-day period. Contaminated and control treatments were compared in terms of root and shoot dry weight. Comparisons revealed reductions of about 22% and 30% in root dry matter and 51% and 42% in shoot dry matter of sorghum and barley in contaminated soil, respectively. The control and planted soils were significantly different in total and oil-degrading bacterial counts. Moreover, the concentration of total petroleum hydrocarbons decreased by 52%-64% in 90 days. Since planting the contaminated soil with sorghum and barley resulted in an improvement of 30% compared to unplanted contaminated soil, the two plants were highly efficient in removing petroleum from oil-contaminated soils. Therefore, despite the necessity of further studies to enhance the efficacy of phytoremediation by assessing the appropriateness of various plant species, some genotypes like sorghum and barley were found suitable choices for phytoremediation of the investigated petroleum-contaminated soil.

  3. Summary of the proceedings of the workshop on the refinery of the future

    Energy Technology Data Exchange (ETDEWEB)

    1994-06-01

    This report on the Workshop on the Refinery of the Future has been prepared for participants to provide them with a succinct summary of the presentations, deliberations, and discussions. In preparing the summary, we have striven to capture the key findings (conclusions) and highlight the issues and concerns raised during the plenary and breakout sessions. The presentation of the summary of the proceedings follows the final workshop agenda, which is given in Section I; each section is tabbed to facilitate access to specific workshop topics. The material presented relies heavily on the outline summaries prepared and presented by the Plenary Session Chairman and the Facilitators for each breakout group. These summaries are included essentially as presented. In addition, individuals were assigned to take notes during each session; these notes were used to reconstruct critical issues that were discussed in more detail. The key comments made by the participants, which tended to represent the range of views expressed relative to the issues, are presented immediately following the facilitator`s summary outline in order to convey the flavor of the discussions. The comments are not attributed to individuals, since in many instances they represent a composite of several similar views expressed during the discussion. The facilitators were asked to review the writeups describing the outcomes of their sessions for accuracy and content; their suggested changes were incorporated. Every effort has thus been made to reconstruct the views expressed as accurately as possible; however, errors and/or misinterpretations undoubtedly have occurred.

  4. Production of ethanol from refinery waste gases. Final report, April 1994--July 1997

    Energy Technology Data Exchange (ETDEWEB)

    Arora, D.; Basu, R.; Breshears, F.S.; Gaines, L.D.; Hays, K.S.; Phillips, J.R.; Wikstrom, C.V.; Clausen, E.C.; Gaddy, J.L.

    1997-08-01

    The objective of this program was to develop a commercial process for producing ethanol from refinery waste gases. this report presents results from the development phases. The major focus of this work was the preparation of the prototype design which will demonstrate this technology in a 2.5 lb/hr ethanol production facility. Additional areas of focus included efforts in obtaining an industrial partner to help finance the prototype, and advanced engineering experiments concentrating on process optimization in various areas needing future development and optimization. The advanced engineering experiments were performed in the laboratory in these areas: treatment and use of recycle water from distillation back to fermentation; alternative methods of removing cells from the fermentation broth; the fermentation of streams containing CO{sub 2}/H{sub 2} alone, with little to no CO present; dealing with methanogen contaminants that are capable of fermenting CO{sub 2} and H{sub 2} to methane; and acetate tolerance by the culture. Results from the design, industrial partner search and the laboratory R&D efforts are discussed in this report.

  5. Variables Refinery Process to Ensure Research Unbiasedness (Validity and Invariance (Reliability in Agricultural Extension and Education

    Directory of Open Access Journals (Sweden)

    Iraj M. Mohammadi

    2008-01-01

    Full Text Available Involving many variables, usually uncertain discrete, lowers the level of consistency and certainty in complex human studies like agricultural extension education. This research, as a part of a study entitled: Side by side situational analysis of current versus future situations of agricultural sector in manifesting the Ninth Malaysia Plan, is dealing primarily with the purpose and process of refining a set of uncertain independent variables to higher research validity and reliability. This investigation is quantitative in its nature, Applied in kind and design-wise, it is an Ex-Post-Facto analytical survey research. Eleven personal and professional characteristics of 224 agricultural experts were taken as independent and 158 attitudinal variables, measured based on dual (side-by-side Likert scale, as dependent variables. Research population consisted of all agricultural experts including extension experts in Malaysia. As a result, 13 items (8.2% of the attitudinal questions out of 157 were distinguished as impacted, moderate to very high sensitive variables to few personal characteristics and were eliminated in further data analysis. Applying this variable refinery method considerably increased construct and content validity as well as reliability of the research instrument and helped researcher to construct a rather impact-free side-by-side questionnaire.

  6. Material Balance And Reaction Kinetics Modeling For Penex Isomerization Process In Daura Refinery

    Directory of Open Access Journals (Sweden)

    Hamadi Adel Sharif

    2017-01-01

    Full Text Available Penex Deisohexanizer isomerization of light straight run naphtha is a significant process for petroleum refining and proved to be effective technology to produce gasoline components with a high octane number. Modeling of the chemical kinetic reactions is an important tool because it is a better tool for optimization of the experimental data into parameters used for industrial reactors. The present study deals on the isomerization process in Daura refinery. Material balance calculations were done mathematically on the unit for the kinetics prediction purpose. A kinetic mathematical model was derived for the prediction rate constants K1 and K2 and activation energy Ea at operating temperatures range 120-180°C. According to the model, the results show that with increasing of temperature leads to increased K1 directly, where the K2 values proportional inversely. The activation energy results show that Ea1(nC6

  7. Development of microbial cell factories for bio-refinery through synthetic bioengineering.

    Science.gov (United States)

    Kondo, Akihiko; Ishii, Jun; Hara, Kiyotaka Y; Hasunuma, Tomohisa; Matsuda, Fumio

    2013-01-20

    Synthetic bioengineering is a strategy for developing useful microbial strains with innovative biological functions. Novel functions are designed and synthesized in host microbes with the aid of advanced technologies for computer simulations of cellular processes and the system-wide manipulation of host genomes. Here, we review the current status and future prospects of synthetic bioengineering in the yeast Saccharomyces cerevisiae for bio-refinery processes to produce various commodity chemicals from lignocellulosic biomass. Previous studies to improve assimilation of xylose and production of glutathione and butanol suggest a fixed pattern of problems that need to be solved, and as a crucial step, we now need to identify promising targets for further engineering of yeast metabolism. Metabolic simulation, transcriptomics, and metabolomics are useful emerging technologies for achieving this goal, making it possible to optimize metabolic pathways. Furthermore, novel genes responsible for target production can be found by analyzing large-scale data. Fine-tuning of enzyme activities is essential in the latter stage of strain development, but it requires detailed modeling of yeast metabolic functions. Recombinant technologies and genetic engineering are crucial for implementing metabolic designs into microbes. In addition to conventional gene manipulation techniques, advanced methods, such as multicistronic expression systems, marker-recycle gene deletion, protein engineering, cell surface display, genome editing, and synthesis of very long DNA fragments, will facilitate advances in synthetic bioengineering.

  8. Petrochemical refinery and integrated petrochemical complexes; Refinaria petroquimica e complexos petroquimicos integrados

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Patricia C. dos; Seidl, Peter R.; Borschiver, Suzana [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Escola de Quimica

    2008-07-01

    Global demand for light olefins points to strong prospects for growth, stimulating investments in overall productive capacity. With propylene demand growing slightly faster than that of ethylene, rising prices and difficulties in supplies of petrochemical feedstocks (mainly naphtha and natural gas), steam crackers alone are not able to fill the light olefins gap nor do they allow extraordinary margins. As petrochemical market dynamics also influence refining activities, there has been significant progress in the development of technologies for petrochemical refining, such as Petrochemical FCC. This petrochemistry-refining integration offers great opportunities for synergism since both industries share many common challenges, like more severe environmental requirements and optimizing the use of utilities. However, in the case of valuation of non-conventional oils (which tend to increase in importance in oil markets), to take full advantage of this opportunity to add value to low cost streams, deep conversion and treatment processes are of great significance in refining scheme to have enough feedstock for cracking. In this context, a petrochemical refinery seems to be an important alternative source of petrochemicals and may be integrated or not to a petrochemical complex. (author)

  9. Applying Neural Network to Dynamic Modeling of Biosurfactant Production Using Soybean Oil Refinery Wastes

    Directory of Open Access Journals (Sweden)

    Shokoufe Tayyebi

    2013-01-01

    Full Text Available Biosurfactants are surface active compounds produced by various microorganisms. Production of biosurfactants via fermentation of immiscible wastes has the dual benefit of creating economic opportunities for manufacturers, while improving environmental health. A predictor system, recommended in such processes, must be scaled-up. Hence, four neural networks were developed for the dynamic modeling of the biosurfactant production kinetics, in presence of soybean oil or refinery wastes including acid oil, deodorizer distillate and soap stock. Each proposed feed forward neural network consists of three layers which are not fully connected. The input and output data for the training and validation of the neural network models were gathered from batch fermentation experiments. The proposed neural network models were evaluated by three statistical criteria (R2, RMSE and SE. The typical regression analysis showed high correlation coefficients greater than 0.971, demonstrating that the neural network is an excellent estimator for prediction of biosurfactant production kinetic data in a two phase liquid-liquid batch fermentation system. In addition, sensitivity analysis indicates that residual oil has the significant effect (i.e. 49% on the biosurfactant in the process.

  10. Safe job analysis in a lead refinery. A practical approach from the process side

    Energy Technology Data Exchange (ETDEWEB)

    Esser, Knut; Meurer, Urban [BERZELIUS Stolberg GmbH, Stolberg (Germany)

    2011-09-15

    In order to increase safety and to maintain legal requirements, Berzelius Stolberg decided in 2009 to update and change the approach for the safe job analysis (SJA). The new approach takes detailed Standard Operation Procedures (SOPs), which were also updated during the new approach, as a basis for all following documents. Together with supervisors and operators all SOPs were structured in single working steps, because only if the real work is properly described, the afterwards performed safe job analysis makes sense and the risks are correctly identified. After updating the SOPs, a draft of each SJA was discussed by representatives from the refinery management, works council, safety officers and operators. For every identified risk one or more measures to avoid the risk were agreed. For the technical and organisational measures an action plan was created. The behavior related measures were concentrated in a safety handbook, representing the basis for future safety training of the operators. In addition to the Safe Job Analysis the SOPs are also the basis for training manuals and also for FMEAs. All in all the new approach of safe job analysis represents not only a way to increase safety systematically according to OHSAS guidelines, but also satisfies all aspects of quality management. (orig.)

  11. Stabilization of oily sediments for cap closure of a refinery oxidation pond

    Energy Technology Data Exchange (ETDEWEB)

    Schifano, V. [ARCADIUS US Inc., Chelmsford, MA (United States); Fabian, K. [ARCADIUS US Inc., Seattle, WA (United States); Weise, T. [ARCADIUS US Inc., Los Altos, CA (United States)

    2010-07-01

    This paper discussed a remediation project in which over 400,000 m{sup 3} of oily sediments, dredged sediments, and soils were used to construct a cap foundation layer for the closure of a refinery oxidation pond used as a regulated waste disposal unit. A value engineering approach was used to identify alternative design schemes and construction methods for the project. Field cone penetration tests were used to test the sediments after curing under field environmental and stress conditions. The stabilization design for the pond was developed to account for heterogeneities in sediment properties as well as time variability in groundwater fluctuations and weather conditions. A binder was optimized to minimize deficiencies and achieve a low rate of re-testing and subsequent stabilization repairs. Depositional and post-depositional projects including self-weight consolidation and drying during the 2 years preceding the stabilization transformed the diluted slurry of dredged sediments into a layer of stiff semi-dry silty clay. The silty clay was then blended with the oily sediments to form a cap foundation layer of a least 0.6 m thickness. A liner was placed on the cap foundation to minimize infiltration into the waste unit. Over $4 million was saved using the new approach. 17 refs., 2 tabs., 7 figs.

  12. Treatment of alumina refinery waste (red mud) through neutralization techniques: A review.

    Science.gov (United States)

    Rai, Suchita; Wasewar, K L; Agnihotri, A

    2017-06-01

    In the Bayer process of extraction of alumina from bauxite, the insoluble product generated after bauxite digestion with sodium hydroxide at elevated temperature and pressure is known as 'red mud' or 'bauxite residue'. This alumina refinery waste is highly alkaline in nature with a pH of 10.5-12.5 and is conventionally disposed of in mostly clay-lined land-based impoundments. The alkaline constituents in the red mud impose severe and alarming environmental problems, such as soil and air pollution. Keeping in view sustainable re-vegetation and residue management, neutralization/treatment of red mud using different techniques is the only alternative to make the bauxite residue environmentally benign. Hence, neutralization techniques, such as using mineral acids, acidic waste (pickling liquor waste), coal dust, superphosphate and gypsum as amenders, CO2, sintering with silicate material and seawater for treatment of red mud have been studied in detail. This paper is based upon and emphasizes the experimental work carried out for all the neutralization techniques along with a comprehensive review of each of the processes. The scope, applicability, limitations and feasibility of these processes have been compared exhaustively. Merits and demerits have been discussed using flow diagrams. All the techniques described are technically feasible, wherein findings obtained with seawater neutralization can be set as a benchmark for future work. Further studies should be focused on exploring the economical viability of these processes for better waste management and disposal of red mud.

  13. Perancangan Safety Instrumented System pada Proses Loading PT Pertamina (Persero Refinery Unit VI Balongan

    Directory of Open Access Journals (Sweden)

    Rahmat Tri widodo

    2013-09-01

    Full Text Available Salah satu proses yang ada di PT Pertamina (Persero Refinery Unit VI adalah pengiriman crude oil menuju kapal tanker. Proses tersebut disebut dengan proses loading. Terdapat beberapa jenis crude yang dikirim pada proses loading tersebut, diantaranya adalah crude Jatibarang dan Crude DCO. Terdapat beberapa masalah yang kerap terjadi pada proses loading ini. Yang sering terjadi adalah kebocoran offshore pipeline yang biasa disebabkan oleh korosi air laut. Selain itu juga pernah terjadi penyumbatan pipa oleh crude akibat heater yang tidak berfungsi dengan baik. Sampai saat ini safety system yang ada pada proses loading ini hanya sebuah shutdown valve yang dijalankan manual dengan menggunakan hand switch. Sistem tersebut masih belum bisa menangani permasalahan yang ada. Oleh karena itu pada tugas akhir kali ini dilakukan perancangan SIS pada jalur loading PT Pertamina RU VI Balongan yang kemudian disimulasikan pada software Matlab (Simulink. Simulasi dilakukan dengan memberikan manipulasi besar disturbance yang merepresentasikan kebocoran pada offshore pipeline. Berdasarkan simulasi yang dilakukan, didapatkan bahwa SIS dapat berjalan dengan baik karena dapat menghentikan proses dengan menutup ESDV dan mematikan pompa saat keadaan perbedaan tekanan antara ujung-ujung pipa offshore tinggi. Tingginya perbedaan tekanan antar ujung offshore pipeline mengindikasikan terjadinya kebocoran. SIS yang sudah dirancang kemudian dihitung nilai PFDtotal dan diapatkan nilai sebesar 0,085 sehingga rancangan SIS.

  14. Effects of hydrogen on mechanical properties of Cr-Mo steel equipment in refinery environments

    Energy Technology Data Exchange (ETDEWEB)

    Toussaint, P. [Industeel Belgium, Charleroi (Belgium); Pillot, S.; Bourges, P. [Industeel Creusot, Le Creusot (France). Centre de Reserche des Materiaux du Creusot; Masson, G. [ArcelorMittal Global Plates Strategy, Luxemboug (Luxembourg); Coudreuse, L. [Industeel Loire, Rive de Gier (France)

    2008-07-01

    This paper discussed an experimental study conducted to determine the effect of hydrogen on the mechanical properties of steel refinery pressure vessels. Hydrogen was introduced into the steel during service as well as during a shut-down operation in order to determine tensile and Charpy-impact properties of the base metal, heat-affected zone, and weld metal. Charpy impact transition curves were assessed in order to evaluate the effect of hydrogen content on the fracture aspect transition temperature (FATT). Tensile specimens were charged with hydrogen in an autoclave at temperatures lower than 450 degrees C. Creep tests were conducted to measure the variation of creep strength and ductility between specimens. The effect of hydrogen on different weld microstructures was examined. Results of the study showed that the FATT was increased by the presence of hydrogen in the metal. Sensitivities in the weld metal were noted. Tests conducted to examine the influence of hydrogen on creep properties demonstrated that the presence of hydrogen reduced rupture times. Hydrogen affected the static, quasi-static, and dynamic properties of the steel samples. It was concluded that vanadium alloyed materials are less sensitive to hydrogen than standard steel grades. 3 refs., 9 tabs., 11 figs.

  15. Lead isotopes in soils near five historic American lead smelters and refineries.

    Science.gov (United States)

    Rabinowitz, Michael B

    2005-06-15

    This survey of soil lead in the vicinity of old industrial sites examines how the stable isotope patterns vary among the sites according to the sources of the lead ore processed at each site. Lead smelters and refineries, which closed down decades ago, are the basis of this investigation. Samples were taken from near five old factory sites in Collinsville and Alton (Illinois), Ponderay (Idaho), East Chicago (Indiana) and Omaha (Nebraska). Historical records were searched for accounts of the sources of the lead. Lead concentrations were measured by atomic absorption flame spectrophotometry, and stable isotopic analysis was done by plasma ionization mass spectrometry. At every site visited, remnants of the old factories, in terms of soil lead pollution, could be found. In spite of potential complications of varying smelter feedstock sourced from mines of different geological age, it was possible to match the isotopic patterns in the soils with the documented sources of the ores. The Collinsville and Alton sites resembled Missouri lead. The Ponderay value was higher than major Bunker Hill, Idaho deposits, but closer to the minor, nearby Oreille County, Washington ores. Mostly Utah ore was used in East Chicago. The Omaha soil reflects lead from Mexico, Colorado and Montana.

  16. [Risks scenarios frameworks in the context of an oil refinery installation at Pernambuco State].

    Science.gov (United States)

    Gurgel, Aline do Monte; Medeiros, Ana Catarina Leite Veras; Alves, Paloma Corrêa; Silva, José Marcos da; Gurgel, Idê Gomes Dantas; Augusto, Lia Giraldo da Silva

    2009-01-01

    The magnitude of the environmental and social problems due to urbanization, industrialization and exhaustion of natural resources has shown an increase in the impact on health and environment. Paradoxically, the consumption patterns demand for the expansion in the industrial production based on the exploitation of the non-renewable resources, which technological risks, especially from the petrochemical industry, have put difficulties on the risk control and health surveillance. The petroleum refining is an activity potentially damageable to the environment and human health, particularly to workers. The main objective of this study was to characterize the scenarios of risk to environmental health due to an oil refinery installation in the Metropolitan Region of Recife (Pernambuco). Based on secondary data and literature review, a Social Reproduction Matrix was made contextualizing the problems in the biological, consciousness and conduct, economic, policy and ecological dimensions, enabling to presume the risks to support the health surveillance development and organization in the state, with intersectoriality, social participation, and able to intervene on risks and prevent diseases among the workers and people in the territory.

  17. MINLP model for simultaneous scheduling and retrofit of refinery preheat train

    Directory of Open Access Journals (Sweden)

    Zulkafli N. Izyan, M. Noryani, Abdul H. Dayanasari, M. Shuhaimi

    2014-01-01

    Full Text Available There is greater awareness today on the depleting fossil energy resources and the growing problem of atmospheric pollution. Engineers are developing practical techniques to ensure energy processes are designed and operated efficiently. Inefficient heat exchangers lead to higher fuel demand and higher carbon emission. This paper presents mixed-integer nonlinear programming (MINLP model for simultaneous cleaning and retrofit of crude preheat train (CPT in oil refinery plant. The formulation of the model is generated and coded in General Algebraic Modeling System (GAMS. The model minimizes the cost of energy and the cost of cleaning. The model takes into account the changes in fouling rates throughout time. There are two cases for this study. The cases are online cleaning (Case 1 and simultaneous online cleaning and retrofit (Case 2. The largest energy saving are found in Case 2. The installation of high efficiency heat exchangers improves furnace inlet temperature (FIT from 215oC to 227oC. Furthermore, Case 2 results in the highest percentage of cost saving by about 59%. The payback period for investment in high efficiency heat exchangers is 5 months. Thus, Case 2 is the most cost effective option for reductions of energy consumption in Crude Distillation Unit (CDU.

  18. Derivative Misconduct and Forms thereof: Western Refinery Ltd v Hlebela 2015 36 ILJ 2280 (LAC

    Directory of Open Access Journals (Sweden)

    Tumo Charles Maloka

    2016-08-01

    Full Text Available Western Platinum Refinery Ltd v Hlebela 2015 36 ILJ 2280 (LAC ("Hlebela" required the Labour Appeal Court to grapple with difficult questions presented by a generic dilemma which confronts an employer who is faced with clear evidence of recurrent theft of precious minerals but is unable to identify the actual culprits, nor are the employees disposed or willing to co-operate with the employer in tracking down the perpetrator(s. Suddenly, the police informed the employer that an employee who had accumulated wealth was a person of interest in their investigations. However, they could give no information about the employee's being engaged, to their knowledge, in particular illegal activities. Hlebela answered the nagging question: what is the appropriate way to discipline an employee who has actual knowledge of the wrongdoing of others or who has actual knowledge of information which the employee subjectively knows is relevant to unlawful conduct against the employer's interests? The categorical answer is that the employer should charge the employee with material breach of the duty of good faith, particularising the knowledge allegedly possessed and alleging a culpable non-disclosure.

  19. Identification and characterization of ethanol utilizing fungal flora of oil refinery contaminated soil.

    Science.gov (United States)

    Srivastava, Alok Kumar; Singh, Pratiksha; Singh, Rajesh Kumar; Kashyap, Prem Lal; Chakdar, Hillol; Kumar, Sudheer; Sharma, Arun Kumar

    2014-02-01

    The indigenous fungal flora of three oil refinery contaminated sites (Bharuch, Valsad and Vadodara) of India has been documented in the present investigation. A total seventy-five fungal morphotypes were isolated from these sites and out of them, only fifteen isolates were capable of utilizing ethanol (0-8%; v:v) as a sole source of carbon and energy for growth. Ten percent ethanol was completely lethal for the growth of all the isolated fungus. Biochemical characterization of the potent ethanol utilizing fungal isolates was studied based on substrate utilization profiles using BIOLOG phenotype microarray plates. Based on the morphological characters and Internal Transcribed Spacer region of ribosomal DNA, the fungal isolates were identified as Fusarium brachygibbosum, Fusarium equiseti, Fusarium acuminatum, Pencillium citrinum, Alternaria tenuissima, Septogloeum mori, Hypocrea lixii, Aureobasidium sp., Penicillium sp., and Fusarium sp. Intra-species genetic diversity among Fusarium sp. was evaluated by whole genome analysis with repetitive DNA sequences (ERIC, REP and BOX) based DNA fingerprinting. It was found that these fungus use alcohol dehydrogenase and acetaldehyde dehydrogenase enzymes based metabolism pathway to utilize ethanol for their growth and colonization.

  20. NOx reduction measures at the Nippon Mitsubishi refinery of Negishi in Yokohama, Japan; Le traitement des oxydes d'azote a la raffinerie NIppon Mitsubishi de Negishi a Yokohama, Japon

    Energy Technology Data Exchange (ETDEWEB)

    Raymond, B. [BR Consultant, 40 - Ondres (France)

    2001-07-01

    The Negishi refinery is the largest and most advanced oil refinery in Japan: 385,000 barrels per day (15 Mt/year). The refinery is located in Yokohama where it is surrounded by natural scenery (sea and parkland) and a residential area. The environmental constraints and regulations concerning pollutant emissions are very ambitious. There are different levels of regulations: National, Regional and Municipal. To reduce NOx emissions from furnaces and boilers in the refinery, various measures are taken, including DeNOx technologies such as DeNOx catalytic reactors which directly remove NOx from the flue gas and low NOx burners which improve combustion. (authors)

  1. Bioremediation of wastewater using microalgae

    Science.gov (United States)

    Chalivendra, Saikumar

    Population expansion and industrial development has deteriorated the quality of freshwater reservoirs around the world and has caused freshwater shortages in certain areas. Discharge of industrial effluents containing toxic heavy metals such as Cd and Cr into the environment have serious impact on human, animal and aquatic life. In order to solve these problems, the present study was focused on evaluating and demonstrating potential of microalgae for bioremediation of wastewater laden with nitrogen (N) in the form of nitrates, phosphorous (P) in the form of phosphates, chromium (Cr (VI)) and cadmium (Cd (II)). After screening several microalgae, Chlorella vulgaris and algae taken from Pleasant Hill Lake were chosen as candidate species for this study. The viability of the process was demonstrated in laboratory bioreactors and various experimental parameters such as contact time, initial metal concentration, algae concentration, pH and temperature that would affect remediation rates were studied. Based on the experimental results, correlations were developed to enable customizing and designing a commercial Algae based Wastewater Treatment System (AWTS). A commercial AWTS system that can be easily customized and is suitable for integration into existing wastewater treatment facilities was developed, and capital cost estimates for system including installation and annual operating costs were determined. The work concludes that algal bioremediation is a viable alternate technology for treating wastewater in an economical and sustainable way when compared to conventional treatment processes. The annual wastewater treatment cost to remove N,P is ~26x lower and to remove Cr, Cd is 7x lower than conventional treatment processes. The cost benefit analysis performed shows that if this technology is implemented at industrial complexes, Air Force freight and other Department of Defense installations with wastewater treatment plants, it could lead to millions of dollars in

  2. 炼油厂恶臭污染源综合监测与评价Ⅰ.污染源监测%COMPREHENSIVE MONITORING AND ASSESSMENT OF ODOUR EMISSION SOURCES FROM REFINERY Ⅰ.MONITORING OF ODOROUS SOURCES

    Institute of Scientific and Technical Information of China (English)

    李凌波; 韩丛碧; 郭兵兵; 周艳红

    2013-01-01

    建立了炼油厂各类贮罐呼吸气、污水处理场逸散气及氧化脱硫醇尾气等恶臭无组织排放源的采样与分析成套技术,监测项目基本涵盖石油炼制特征恶臭污染物和油气组分.废气样品用双连球和聚四氟乙烯采样袋采集.废气中特征恶臭污染物的组成及烃类碳数分布用气相色谱/质谱法定性和半定量分析,挥发性硫化物含量用新型的硫化学发光检测/宽口径毛细管气相色谱法分析,总烃含量用总烃分析仪法分析,C1~C3烃类含量用火焰离子化检测/气相色谱法分析,苯系物和氨气含量参照国家标准方法分析.监测了多家炼油厂的典型恶臭污染源,较为全面和系统地获取了炼油厂恶臭污染源排放特征.%A set of techniques integrated sampling and analysis was developed to monitor and identify offensive odour emissions from refinery, such as emissions from various storage tanks, wastewater treatment facilities and oxidative sweetening units. The monitoring items nearly covered all the typical refining odorous pollutants and hydrocarbons. Waste gases from odour emission sources were sampled and collected by aspirator bulbs and PTFE bags. Odorous compounds and hydrocarbons in waste gases were identified and semi-quantitatively analyzed by gas chromatography-mass spectrometry. Volatile sulfur compounds in waste gases were analyzed using a wide-bore capillary gas chromatography with sulfur chemiluminescence detection. The contents of total hydrocarbons and C1-C3 hydrocarbons in waste gases were determined by total hydrocarbon analyzer and flame ionization detection-packed column gas chromatography, respectively. The contents of benzene homologues and ammonia were determined according to the Chinese national standard methods. Some typical odour emission sources were sampled and analyzed from refineries of SINOPEC and the characteristics of odour emissions derived from petroleum refining were investigated

  3. Biological flocculation treatment on distillery wastewater and recirculation of wastewater.

    Science.gov (United States)

    Zhang, Wen; Xiong, Rongchun; Wei, Gang

    2009-12-30

    In the present study, a wastewater treatment system for the ethanol fermentation industry was developed by recycling distillery wastewater. The waste was able to be recycled for the next fermentation after being treated with bio-flocculation process. The bio-flocculation process contains three steps: screening, treatment with polyaspartic acid and filtration. When the filtrate from this process was recycled, the average ethanol production yield was very close to that in the conventional process using tap water. In contrast, the recycle of wastewater without flocculation and with chemical flocculation showed negative effects on ethanol yield as recycling was repeated. This new process was confirmed to have stable operation over ten recycles. Hazardous materials influencing distillery wastewater recycles on fermentation were also considered. It was found that the content of suspended solids (SS), volatile acid and Fe ions inhibited fermentation and resulted in a decreased ethanol yield. Bio-flocculation was shown to be an effective way to diminish the content of inhibitory compounds drastically when the waste was recirculated.

  4. Electrochemical disinfection of toilet wastewater using wastewater electrolysis cell.

    Science.gov (United States)

    Huang, Xiao; Qu, Yan; Cid, Clément A; Finke, Cody; Hoffmann, Michael R; Lim, Keahying; Jiang, Sunny C

    2016-04-01

    The paucity of proper sanitation facilities has contributed to the spread of waterborne diseases in many developing countries. The primary goal of this study was to demonstrate the feasibility of using a wastewater electrolysis cell (WEC) for toilet wastewater disinfection. The treated wastewater was designed to reuse for toilet flushing and agricultural irrigation. Laboratory-scale electrochemical (EC) disinfection experiments were performed to investigate the disinfection efficiency of the WEC with four seeded microorganisms (Escherichia coli, Enterococcus, recombinant adenovirus serotype 5, and bacteriophage MS2). In addition, the formation of organic disinfection byproducts (DBPs) trihalomethanes (THMs) and haloacetic acids (HAA5) at the end of the EC treatment was also investigated. The results showed that at an applied cell voltage of +4 V, the WEC achieved 5-log10 reductions of all four seeded microorganisms in real toilet wastewater within 60 min. In contrast, chemical chlorination (CC) disinfection using hypochlorite [NaClO] was only effective for the inactivation of bacteria. Due to the rapid formation of chloramines, less than 0.5-log10 reduction of MS2 was observed in toilet wastewater even at the highest [NaClO] dosage (36 mg/L, as Cl2) over a 1 h reaction. Experiments using laboratory model waters showed that free reactive chlorine generated in situ during EC disinfection process was the main disinfectant responsible for the inactivation of microorganisms. However, the production of hydroxyl radicals [OH], and other reactive oxygen species by the active bismuth-doped TiO2 anode were negligible under the same electrolytic conditions. The formation of THMs and HAA5 were found to increase with higher applied cell voltage. Based on the energy consumption estimates, the WEC system can be operated using solar energy stored in a DC battery as the sole power source.

  5. Electrochemical disinfection of toilet wastewater using wastewater electrolysis cell

    Science.gov (United States)

    Huang, Xiao; Qu, Yan; Cid, Clément A.; Finke, Cody; Hoffmann, Michael R.; Lim, Keahying; Jiang, Sunny C.

    2016-01-01

    The paucity of proper sanitation facilities has contributed to the spread of waterborne diseases in many developing countries. The primary goal of this study was to demonstrate the feasibility of using a wastewater electrolysis cell (WEC) for toilet wastewater disinfection. The treated wastewater was designed to reuse for toilet flushing and agricultural irrigation. Laboratory-scale electrochemical (EC) disinfection experiments were performed to investigate the disinfection efficiency of the WEC with four seeded microorganisms (Escherichia coli, Enterococcus, recombinant adenovirus serotype 5, and bacteriophage MS2). In addition, the formation of organic disinfection byproducts (DBPs) trihalomethanes (THMs) and haloacetic acids (HAA5) at the end of the EC treatment was also investigated. The results showed that at an applied cell voltage of +4 V, the WEC achieved 5-log10 reductions of all four seeded microorganisms in real toilet wastewater within 60 min. In contrast, chemical chlorination (CC) disinfection using hypochlorite [NaClO] was only effective for the inactivation of bacteria. Due to the rapid formation of chloramines, less than 0.5-log10 reduction of MS2 was observed in toilet wastewater even at the highest [NaClO] dosage (36 mg/L, as Cl2) over a 1 h reaction. Experiments using laboratory model waters showed that free reactive chlorine generated in situ during EC disinfection process was the main disinfectant responsible for the inactivation of microorganisms. However, the production of hydroxyl radicals [•OH], and other reactive oxygen species by the active bismuth-doped TiO2 anode were negligible under the same electrolytic conditions. The formation of THMs and HAA5 were found to increase with higher applied cell voltage. Based on the energy consumption estimates, the WEC system can be operated using solar energy stored in a DC battery as the sole power source. PMID:26854604

  6. A review on wastewater disinfection

    Directory of Open Access Journals (Sweden)

    Mohammad Mehdi Amin

    2013-01-01

    Full Text Available Changes in regulations and development of new technologies have affected the selection of alternative for treated wastewater disinfection. Disinfection is the last barrier of wastewater reclamation process to protect ecosystem safety and human health. Driving forces include water scarcity and drinking water supply, irrigation, rapid industrialization, using reclaimed water, source protection, overpopulation, and environmental protection. The safe operation of water reuse depends on effluent disinfection. Understanding the differences in inactivation mechanisms is critical to identify rate-limiting steps involved in the inactivation process as well as to develop more effective disinfection strategies. Disinfection byproducts discharged from wastewater treatment plants may impair aquatic ecosystems and downstream drinking-water quality. Numerous inorganic and organic micropollutants can undergo reactions with disinfectants. Therefore, to mitigate the adverse effects and also to enhance that efficiency, the use of alternative oxidation/disinfection systems should be evaluated as possible alternative to chlorine. This review gives a summary of the traditional, innovative, and combined disinfection alternatives and also disinfection byproducts for effluent of municipal wastewater treatment plants.

  7. Sustainability of municipal wastewater treatment.

    NARCIS (Netherlands)

    Roeleveld, P.J.; Klapwijk, A.; Eggels, P.G.; Rulkens, W.H.; Starkenburg, van W.

    1997-01-01

    n this study the insustainability of the treatment of municipal wastewater is evaluated with the LCA-methodology. Life-Cycle Assessments (LCA) analyze and assess the environmental profile over the entire life cycle of a product or process. The LCA-methodology proved to be a proper instrument to

  8. Wastewater Treatment I. Student's Guide.

    Science.gov (United States)

    California Water Pollution Control Association, Sacramento. Joint Education Committee.

    This student's guide is designed to provide students with the job skills necessary for the safe and effective operation and maintenance of wastewater treatment plants. It consists of three sections. Section 1 consists of an introductory note outlining course objectives and the format of the guide. A course outline constitutes the second section.…

  9. Evaluating the performance of an integrated CALPUFF-MM5 modeling system for predicting SO{sub 2} emission from a refinery

    Energy Technology Data Exchange (ETDEWEB)

    Abdul-Wahab, Sabah Ahmed [Sultan Qaboos University, Department of Mechanical and Industrial Engineering, College of Engineering, Muscat (Oman); Ali, Sappurd [National Engineering and Scientific Commission (NESCOM), Islamabad (Pakistan); Sardar, Sabir; Irfan, Naseem [Pakistan Institute of Engineering and Applied Sciences (PIEAS), Islamabad (Pakistan); Al-Damkhi, Ali [Public Authority for Applied Education and Training (PAAET), Department of Environmental Sciences College of Health Sciences, Salmiyah (Kuwait)

    2011-12-15

    Oil refineries are one of the proven sources of environmental pollution as they emit more than 100 chemicals into the atmosphere including sulfur dioxide (SO{sub 2}). The dispersion patterns of SO{sub 2} from emissions of Sohar refinery was simulated by employing California Puff (CALPUFF) model integrated with state of the art meteorological Mesoscale Model (MM5). The results of this simulation were used to quantify the ground level concentrations of SO{sub 2} in and around the refinery. The evaluation of the CALPUFF and MM5 modeling system was carried out by comparing the estimated results with that of observed data of the same area. The predicted concentrations of SO{sub 2} agreed well with the observed data, with minor differences in magnitudes. In addition, the ambient air quality of the area was checked by comparing the model results with the regulatory limits for SO{sub 2} set by the Ministry of Environment and Climate Affairs (MECA) in Oman. From the analysis of results, it was found that the concentration of SO{sub 2} in the nearby communities of Sohar refinery is well within the regulatory limits specified by MECA. Based on these results, it was concluded that no health risk, due to SO{sub 2} emissions, is present in areas adjacent to the refinery. (orig.)

  10. Removal of Arsenic from Wastewaters by Airlift Electrocoagulation: Part 3: Copper Smelter Wastewater Treatment

    DEFF Research Database (Denmark)

    Hansen, H.K.; Ottosen, Lisbeth M.

    2010-01-01

    -arsenate precipitates. This work evaluates the feasibility of EC as a treatment process at various stages during conventional copper smelter wastewater treatment - with a focus on arsenic. The reactor used is a batch airlift electrocoagulator. The results showed that raw copper smelter wastewater was difficult to treat......The arsenic content in wastewater is of major concern for copper smelters. A typical complex wastewater treatment is needed with a combination of chemical and physical processes. Electrocoagulation (EC) has shown its potential for arsenic removal due to the formation of ferric hydroxide...... threshold value for wastewater discharge could rapidly be reached when the conventional method did not clean the wastewater sufficiently....

  11. Benzene exposure from the BP refinery flaring incident alters hematological and hepatic functions among smoking subjects

    Directory of Open Access Journals (Sweden)

    Mark A. D'Andrea

    2017-10-01

    Full Text Available Objectives: To evaluate the health effects of benzene exposure among smoking subjects from a prolonged flaring incident that occurred at the British Petroleum (BP refinery in Texas City, USA. Material and Methods: The study included smoking subjects who had been exposed and unexposed to the benzene release. Using medical charts, clinical data including white blood cell (WBC counts, platelet counts, hemoglobin, hematocrit, blood urea nitrogen (BUN, creatinine, alkaline phosphatase (ALP, aspartate aminotransferase (AST, and alanine aminotransferase (ALT in the case of smoking subjects exposed to benzene was reviewed and analyzed. Results: A total of 791 tobacco smoking subjects (benzene-exposed: N = 733, unexposed: N = 58 were included. Benzene-exposed subjects had significantly higher levels of WBC (×103/μl counts (8±2.1 vs. 7.5±1.6, p = 0.003 and platelet (×103/μl counts (263.7±69.7 vs. 222.9±44.3, p = 0.000 as compared with the unexposed subjects. The mean hemoglobin, hematocrit, BUN, and creatinine levels did not differ significantly between the benzene-exposed and -unexposed smoking subjects. Serum levels of ALP (IU/l was significantly elevated in the benzene-exposed subjects compared with the unexposed subjects (84.5±16.9 vs. 73.8±15.9, p = 0.002. Similarly, benzene-exposed subjects had significantly higher levels of AST and ALT as compared with those unexposed subjects. Conclusions: Despite a smoking history, residents exposed to benzene from the prolonged BP flaring incident experienced significant alterations in hematological and hepatic functions indicating their vulnerability to the risk of developing hepatic or blood related disorders. Int J Occup Med Environ Health 2017;30(6:849–860

  12. Isolation and characterization of hyper phenol tolerant Bacillus sp. from oil refinery and exploration sites.

    Science.gov (United States)

    Banerjee, Aditi; Ghoshal, Aloke K

    2010-04-15

    Bacillus cereus MTCC 9817 strain AKG1 and B. cereus MTCC 9818 strain AKG2 were isolated from petroleum refinery and oil exploration site, respectively. The 16S rDNA sequence of strain AKG1 showed the closest relation to B. cereus 99.63% and Bacillus coagulans 99.63% followed by 99.34% homology with Bacillus thuringiensis strain 2PR56-10. AKG2 is mostly related to B. thuringiensis strain CMG 861 with 99.37% homology. The similarity search between AKG1 and AKG2 gave the lowest similarity 99.19% among same genus similar sequences. At phenol concentration of 1000 mg/L, the optimum growth conditions for AKG1 were found to be 37 degrees C and pH 7.0 and the same were found to be 37 degrees C and pH 7.5 for AKG2. The growth kinetics of the strains AKG1 and AKG2 are best fitted by Yano model (maximum growth rate, mu(max)=1.024 h(-1) and inhibition constant, K(I)=171,800 mg/L) and Edward model (mu(max)=0.5969 h(-1) and K(I)=1483 mg/L) respectively. Growth kinetics of both the strains are also well fitted by the Haldane model with mu(max)=0.4396 h(-1) and K(I)=637.8 mg/L for AKG1 and mu(max)=0.9332 h(-1) and K(I)=494.4 mg/L for AKG2.

  13. Effect of refinery waste effluent on tocopherol, carotenoid, phenolics and other antioxidants content in Allium cepa.

    Science.gov (United States)

    Gupta, Amit Kumar; Ahmad, Masood

    2013-08-01

    Pollution in water used for irrigation is a major cause of stress generation in plant system. Under these stress conditions, reactive oxygen species derived from molecular oxygen can accumulate in plant, resulting in the oxidation of nucleic acids, lipids, chlorophyll and so on. This study was conducted in Allium cepa to analyze the alteration in the levels of nonenzymatic antioxidants as a consequence of Mathura refinery waste water (MRWW) exposure. The studied antioxidants were glutathione (GSH) and ascorbic acid (ASC). Their determination was carried out in A. cepa bulbs exposed to different concentrations of MRWW that is 0.25×, 0.5×, 0.75× and 1.0×. A significant increase in the levels of these nonenzymatic antioxidants in onion bulbs upon treatment with MRWW suggested that these can serve as suitable biomarkers of toxicity. The toxicity of waste water was also tested on the level of tocopherol (Toc) and carotenoid (CAR) in onion bulbs, and in both the cases a high level of these metabolites was noticed. Phenolic content of A. cepa after the waste water insult was found to be increased, again a manifestation of adaptation against heavy metal and oxidative stress. It is clear from our findings that GSH, ASC, Toc and CAR in A. cepa system could serve as potential biomarkers for the presence of toxicants like heavy metals and its hazards in MRWW. The test waste water demonstrated profound effects on these parameters which is suggestive of the warrior strategies adopted by the plant system against the pollution-induced stress.

  14. Mapping of Biomass Fluxes: A Method for Optimizing Biogas-Refinery of Livestock Effluents

    Directory of Open Access Journals (Sweden)

    Francesca Nardin

    2014-09-01

    Full Text Available This paper presents the topic of the management of livestock effluents and, therefore, nutrients (particularly N in the framework of the biogas supply chain. The bio-refinery will be analyzed as a unique system, from the farm to the biomass produced and sent to anaerobic digestion, focusing on the fate/change of the flow of material and nutrients content through the system. Within four categories of farms considered in the article, integrated ones frequently have a breeding consistency from 90 to 320 heads, according to more extensive or intensive settings. These farms must manage from 3.62 to 12.81 m3 day−1 of slurry and from 11.40 to 40.34 kg day−1 of nitrogen (N as the sum of excreta from all herd categories. By selecting a hypo-protein diet, a reduction of 10% and 24% for total effluent amount and for N excreted, respectively, can be achieved. Nitrogen can be reduced up to 45% if the crude protein content is limited and a further 0.23% if animals of similar ages, weights and (or production or management are grouped and fed according to specific requirements. Integrated farms can implement farming activity with biogas production, possibly adding agricultural residues to the anaerobically-digested biomass. Average biogas yields for cattle effluents range from 200 to 400 m3 ton−1 VS (volatile solids. Values from 320 to 672 m3 day−1 of biogas can be produced, obtaining average values from 26 to 54.5 kWe (kilowatt-electric. This type of farm can well balance farm-production profit, environmental protection, animal husbandry well-being and energy self-sufficiency.

  15. Organic contaminants in onsite wastewater treatment systems

    Science.gov (United States)

    Conn, K.E.; Siegrist, R.L.; Barber, L.B.; Brown, G.K.

    2007-01-01

    Wastewater from thirty onsite wastewater treatment systems was sampled during a reconnaissance field study to quantify bulk parameters and the occurrence of organic wastewater contaminants including endocrine disrupting compounds in treatment systems representing a variety of wastewater sources and treatment processes and their receiving environments. Bulk parameters ranged in concentrations representative of the wide variety of wastewater sources (residential vs. non-residential). Organic contaminants such as sterols, surfactant metabolites, antimicrobial agents, stimulants, metal-chelating agents, and other consumer product chemicals, measured by gas chromatography/mass spectrometry were detected frequently in onsite system wastewater. Wastewater composition was unique between source type likely due to differences in source water and chemical usage. Removal efficiencies varied by engineered treatment type and physicochemical properties of the contaminant, resulting in discharge to the soil treatment unit at ecotoxicologically-relevant concentrations. Organic wastewater contaminants were detected less frequently and at lower concentrations in onsite system receiving environments. Understanding the occurrence and fate of organic wastewater contaminants in onsite wastewater treatment systems will aid in minimizing risk to ecological and human health.

  16. Health risk characterization for exposure to benzene in service stations and petroleum refineries environments using human adverse response data

    Directory of Open Access Journals (Sweden)

    Benjamin Edokpolo

    2015-01-01

    Full Text Available Health risk characterization of exposure to benzene in service stations and petroleum refineries has been carried out in previous studies using guideline values set by various agencies. In this work, health risk was characterized with the exposure data as cumulative probability distribution (CPD plots but using human epidemiological data. This was achieved by using lowest observable adverse effects levels (LOAEL data plotted as cumulative probability lowest effects distribution (CPLED. The health risk due to benzene was characterized by using probabilistic methods of hazard quotient (HQ50/50 and HQ95/5, Monte-Carlo simulation (MCS and overall risk probability (ORP. CPD relationships of adverse health effects relationships and exposure data were in terms of average daily dose (ADD and lifetime average daily dose (LADD for benzene. For service station environments HQ50/50 and HQ95/5 were in a range of 0.000071–0.055 and 0.0049–21, respectively. On the other hand, the risk estimated for petroleum refinery environments suggests higher risk with HQ50/50 and HQ95/5 values ranging from 0.0012 to 77 and 0.17 to 560, respectively. The results of Monte-Carlo risk probability (MRP and ORP indicated that workers in petroleum refineries (MRP of 2.9–56% and ORP of 4.6–52% of the affected population were at a higher risk of adverse health effects from exposure to benzene as compared to exposure to benzene in service station environments (MRP of 0.051 –3.4% and ORP of 0.35–2.7% affected population. The adverse effect risk probabilities estimated by using the Monte-Carlo simulation technique and the ORP method were found to be generally consistent.

  17. Isolation and Identification of Carcinogen Acenaphthene-Degrading Endemic Bacteria from Crude Oil Contaminated Soils around Abadan Refinery

    Directory of Open Access Journals (Sweden)

    Farshid Kafilzadeh

    2012-12-01

    Full Text Available Background and Objective: PAHs are non-polar organic compounds consisting of two or more fused benzene multi-rings. Among these compounds, acenaphthene is a multi-ring hydrocarbon that occurs abundantly in nature. Use of microorganisms to clean the contaminations of soil can be cheap and effective. The most important acenaphthene-degrading bacteria are pseudomonas, micrococcus, and Bacillus. The goal of this study was to isolate and identify the bacteria which degrade acenaphthene in soils around Abadan Refinery and to investigate the relation between the levels of environmental pollution with acenaphthene. Materials and Methods: Soil samples were collected from three areas around Abadan Refinery. The number of the bacteria was counted on the nutrient agar culture with and without acenaphthene. Isolation of the bacteria was done by culturing the samples on acenaphthene broth with a mineral-salt medium, and on an acenaphthene agar medium. Then, the bacteria were identified via biochemical diagnostic tests. Results: The logarithm average of the bacteria was 4.786 ± 0.073 at a medium with acenaphthene, which was 6.671 ± 0.073 less than that of the control medium. The maximum number of degrading bacteria was 7.089 ± 0.089 at Station C, and the minimum number of the degrading bacteria was 4.485 ± 0.089 at Station B. In this study, Bacillus sp, Micrococcus Luteus, Corynebacterium sp, Staphylococcus epidermidis, and Pseudomonas sp bacteria were isolated and identified in terms of frequency, respectively. Conclusion: The results of this study showed that the soil around Abadan Refinery contained a great number of acenaphthene degrading bacteria, especially Bacillus and Micrococcus.

  18. Economic impacts of oil spills: Spill unit costs for tankers, pipelines, refineries, and offshore facilities. [Task 1, Final report

    Energy Technology Data Exchange (ETDEWEB)

    1993-10-15

    The impacts of oil spills -- ranging from the large, widely publicized Exxon Valdez tanker incident to smaller pipeline and refinery spills -- have been costly to both the oil industry and the public. For example, the estimated costs to Exxon of the Valdez tanker spill are on the order of $4 billion, including $2.8 billion (in 1993 dollars) for direct cleanup costs and $1.125 billion (in 1992 dollars) for settlement of damages claims caused by the spill. Application of contingent valuation costs and civil lawsuits pending in the State of Alaska could raise these costs appreciably. Even the costs of the much smaller 1991 oil spill at Texaco`s refinery near Anacortes, Washington led to costs of $8 to 9 million. As a result, inexpensive waming, response and remediation technologies could lower oil spin costs, helping both the oil industry, the associated marine industries, and the environment. One means for reducing the impact and costs of oil spills is to undertake research and development on key aspects of the oil spill prevention, warming, and response and remediation systems. To target these funds to their best use, it is important to have sound data on the nature and size of spills, their likely occurrence and their unit costs. This information could then allow scarce R&D dollars to be spent on areas and activities having the largest impact. This report is intended to provide the ``unit cost`` portion of this crucial information. The report examines the three key components of the US oil supply system, namely, tankers and barges; pipelines and refineries; and offshore production facilities. The specific purpose of the study was to establish the unit costs of oil spills. By manipulating this key information into a larger matrix that includes the size and frequency of occurrence of oil spills, it will be possible` to estimate the likely future impacts, costs, and sources of oil spills.

  19. Results of the simulation of gasification of the mexican petroleum coke from the refineries of Ciudad Madero and Cadereyta

    Directory of Open Access Journals (Sweden)

    G. Urquiza–Beltrán

    2008-04-01

    Full Text Available This paper evaluates in terms of energy the gasification of the petroleum coke from the refineries of Cd Madero and Cadereyta in Mexico. The energy evaluation of the synthetic gas (syngas focuses mainly on the chemical composition of the clean syngas (gasl and its energy characteristics: heating value, the energy power, the cold gas efficiency and the thermal efficiency of gasification. The results of the simulation indicate that the gasification of the petroleum coke from Cadereyta called CRC, produces a gasl with better performance and energy characteristics than those obtained when gasifying the coke of petroleum from Cd. Madero, called CRM. When the CRC is gasified, the rate of production of gasl obtained is of 2.07 kggasl/kgcoque, while the rate of production of gasl for the CRM is 1.89 kggasl/kgcoque. The HHV of the gasl of the CRC is 12 729.56 kJ/kggasl while for the CRM is 11 639.13 kJ/kggasl. The energy power of the gasl of the CRC is greater, with a difference of 25.87 GJ/h, with regard to the energy power of the gasl of the CRM. Under the specified conditions of operation, energy is generated ata rate of 26.46 MJ/kgcoque coke in the gasification of the CRC coke of petroleum, while when gasifying the CRM coke of petroleum 22.09 MJ/kgcoque are generated. Currently, the petroleum coke produced in the refinery of Madero is consumed in the power plants of Tamuín, San Luis Potosí, Mexico, while the petroleum coke produced by the refinery of Cadereyta is used in the cement industry.

  20. Effect of rhamnolipid on the aerobic removal of polyaromatic hydrocarbons (PAHs) and COD components from petrochemical wastewater.

    Science.gov (United States)

    Sponza, Delia Teresa; Gök, Oğuzhan

    2010-02-01

    The removal efficiencies of 15 PAHs and some COD components (inert, readily degradable, slowly degradable and metabolic products) from a wastewater taken from a petrochemical industry treatment plant (Izmir, Turkey) have been determined using an aerobic completely stirred tank reactor (CSTR). Addition of rhamnolipid surfactant (15 mg l(-1)) increased the removal efficiencies of PAHs and soluble COD from 72% and 90% to 80% and 99%, respectively. The rhamnolipid treatment caused a significant increase of 5- and 6-ring PAH degradation. The soluble COD removal efficiency was 93%, in CSTR reactors with rhamnolipid added. The inert COD removal efficiency was 60% in a CSTR reactor containing rhamnolipid. Batch tests showed that removal arising from the adsorption of the PAHs was low (between 1.88% and 4.84%) while the removal of PAHs from the petrochemical industry wastewater via volatilization varied between 0.69% and 5.92%. Low sorption capacity (K(p)) values for refinery activated sludge (approximately 2.98 l g(-1)) confirmed that bio-sorption was not an important mechanism controlling the fate of PAHs in aerobic CSTR reactors. Models proposed to simulate the PAH removal indicated that 94% of the PAHs were removed via biodegradation.

  1. Feasibility of Furnace H-701 Energy Recovery in Sarkhoun and Qeshm Gas Refinery Using the Heat Exchanger

    Directory of Open Access Journals (Sweden)

    J. Khorshidi

    2013-12-01

    Full Text Available The aim of this study is the investigation and thermal analysis relating to emissions of the flue-furnace H-701 of Sarkhoun and Qeshm Gas Refinery in Bandarabbas (IRAN and thermal load has been calculated. Then Study of the combustion process and calculation of required combustion air and the heating of air In order to increase its enthalpy using energy combustion gases is done by designing Heat Exchanger. This method helps to optimization of energy consumption and reduction of energy losses and prevents the increase in environment air and will help to cleanliness of the environment. Using this method efficiency of furnace will be increased by 8.63%.

  2. The bioremediation, solution at the land´s pollution caused by hydrocarbon in Sergio Soto oil Refinery.

    Directory of Open Access Journals (Sweden)

    Carlos Blanco Valdivia

    2010-04-01

    Full Text Available The land´s polution caused by hydrocarbon in Sergio Soto oil refinery constituted a problem for the technicians of this entity that in coordination with the Petroleum Investigations Center (CEINPET, carried out a study for the application of the bioremediation in the company. The area to this purpose was determined and the soil impacted was deposit on it, this soil was homogenized with an appropriate equipment (agricultural tractor. The fertilizers were added and the removal stage was made in order to help the soil oxygenation. They were carried out samples and analysis obtaining satisfactory results with the application of the bioremediation in the company.

  3. A novel two-stage Lagrangian decomposition approach for refinery production scheduling with operational transitions in mode switching☆

    Institute of Scientific and Technical Information of China (English)

    Lei Shi; Yongheng Jiang; Ling Wang; Dexian Huang

    2015-01-01

    To address large scale industrial processes, a novel Lagrangian scheme is proposed to decompose a refinery scheduling problem with operational transitions in mode switching into a production subproblem and a blending and delivery subproblem. To accelerate the convergence of Lagrange multipliers, some auxiliary constraints are added in the blending and delivery subproblem. A speed-up scheme is presented to increase the efficiency for solving the production subproblem. An initialization scheme of Lagrange multipliers and a heuristic algorithm to find feasible solutions are designed. Computational results on three cases with different lengths of time hori-zons and different numbers of orders show that the proposed Lagrangian scheme is effective and efficient.

  4. Environmentally-friendly waste water treatment: Removal of ammonium nitrogen and hydrogen sulfide from oil refinery waste water

    Energy Technology Data Exchange (ETDEWEB)

    Stein, C.; Heine, I.; Sachse, J.; Peper, H. [Holborn Europa Raffinerie GmbH, Hamburg (Germany); Elster, J.

    1998-12-01

    The Holborn Europa Raffinerie (HER) in Hamburg, Germany, achieved a drastic reduction in water and air pollutants by implementation of a two step project. The first step was a modification of the H{sub 2}S-stripping of process water, which resulted ultimately in shutting down the H{sub 2}S-incinerator and conversion of the recovered H{sub 2}S to saleable elementary sulfur. Atmospheric pollution was reduced accordingly by 650 t/a SO{sub 2} and 2,200 t/a CO{sub 2}. In compliance with waste water legislation (requirements of Appendix 45, Waste Water Administrative Regulation), the ammonium nitrogen content of refinery waste water was reduced significantly in a second step. In contrast to the common biological treatment used in many refineries, it was decided to concentrate on physico-chemical treatment of the highly contaminated partstream only. To this end ammonia is effectively stripped out of the partstream under alkaline conditions, and concentrated to a 10% aqueous solution by distillation under reflux. This solution is then injected into the hot vent gas stream of the FCC-regenerator (CO-Boiler) as an NO{sub x} reduction agent, and thus disposed of in an environmentall-friendly manner. The introduction of this combination of field proven processes, namely water treatment by steam stripping and NO{sub x} reduction via SNCR, received government grant support and reduced water pollution by 250 t/a ammonium nitrogen and air pollution by 180 t/a NO{sub x}. In view of the relatively low investment and operating costs, enhanced flexibility of the existing biological water treatment plant, avoidance of additional material waste and drastic reduction of overall refinery emission, the adopted scheme is most certainly a prime example of both economical and ecological optimisation. The scheme also has future potential arising from the projected tightening up in motor fuels specifications (EU specifications for years 2000 and 2005) which will necessitate increased use of

  5. Standard practice for evaluating and qualifying oil field and refinery corrosion inhibitors using the rotating cylinder electrode

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2006-01-01

    1.1 This practice covers a generally accepted procedure to use the rotating cylinder electrode (RCE) for evaluating corrosion inhibitors for oil field and refinery applications in defined flow conditions. 1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

  6. Computer model for refinery operations with emphasis on jet fuel production. Volume 2: Data and technical bases

    Science.gov (United States)

    Dunbar, D. N.; Tunnah, B. G.

    1978-01-01

    The FORTRAN computing program predicts the flow streams and material, energy, and economic balances of a typical petroleum refinery, with particular emphasis on production of aviation turbine fuel of varying end point and hydrogen content specifications. The program has provision for shale oil and coal oil in addition to petroleum crudes. A case study feature permits dependent cases to be run for parametric or optimization studies by input of only the variables which are changed from the base case. The report has sufficient detail for the information of most readers.

  7. Impact of software and hardware technologies on occupational health and safety policies in Saudi Arabian oil refineries.

    Science.gov (United States)

    Idreis, Hany M; Siqueira, Carlos E; Levenstein, Charles C

    2006-01-01

    This article seeks to examine the impact of technology importation on occupational health and safety in both Saudi Arabian and U.S. oil refining industries. Technologies imported to the Saudi oil industry take two forms: hardware (sophisticated equipment to run oil facilities) and software (policies and regulations pertaining to workers' health and safety, and employment rights installed by Aramco's founding multinational companies). This study utilizes qualitative, historically oriented, cross-national case studies to compare and assess workers' health, safety, and rights in Saudi Aramco with its U.S. counterpart, Motiva Enterprises. Two facilities were chosen to conduct field research: the Saudi Aramco oil refinery at Jeddah and Motiva's refinery at Port Arthur, Texas. The Jeddah refinery is fully owned by Saudi Aramco, thus, representing Aramco's health and safety policies and regulations. The Port Arthur refinery serves as a reference case study for U.S. oil refining facilities. The aspects of occupational health and safety in Saudi Aramco--ExxonMobil's joint ventures SAMREF and LUBREF--also are discussed to examine workers' health policies in both companies. The American oil industry made a significant contribution in establishing the Saudi oil industry, with the cooperation of the Saudi government. Despite having outstanding employment benefits schemes in Saudi Aramco, the presence of an organized work force better serves employee participation in Motiva than in Aramco. Safety systems such as Process Safety Management (PSM)--applied in Motiva--partially exist in Aramco to operate hardware technologies safely. Motiva training systems are better through PACE's Triangle of Prevention (TOP). Both companies follow the same pattern of handling occupational injuries and diseases; however, Saudi government agencies (GOSI) are responsible for compensating and treating injured workers. Saudi workers expressed conditional support for the worker committee program

  8. Combined environmental impacts from production and use of the products. An EIS-application project for refineries; Sammanvaegd miljoepaaverkan fraan produktion och anvaendning av produkterna. Ett MKB-tillaempningsprojekt foer raffinaderier

    Energy Technology Data Exchange (ETDEWEB)

    Kindbom, K; LoevbIad, G.; Stripple, H.

    2001-12-01

    At European refineries a change in production is planned in order to obtain better qualities of gasoline and diesel, from an environmental point of view. This change will, however, lead to higher emissions at the refineries. The present study of the combined effects of emissions at the refineries and the use of the products gives the opportunity for considering the entire system and gives a stronger positive signal than the traditional EIS would do. Three different methods were used: Net change in emissions to air; Exposure of men and ecosystems for air pollutants; and Exceeding norms and critical levels. The results for the Swedish refinery at Lysekil shows that the emissions from using the products are much higher than the emissions from the refinery for all cases studied. The net emissions from production and use of the products will be reduced for the new products compared to the present situation. Risks for exceeding norms and critical levels due to the changes at the refinery exist for emissions of sulfur and nitrogen oxides, but a lower background load will probably mean that the total future load will be reasonably close to the critical level in the area affected by the refinery. In the urban environment, reduced risks for exceeding the levels for benzen and low levels for toluene and xylene give greater advantages than the increased emissions of sulfur and nitrogen close to the refinery.

  9. Application of the CAST Scheme in Super Viscous Oil Wastewater Treatment%CAST工艺在炼油超稠油加工废水中的应用

    Institute of Scientific and Technical Information of China (English)

    何军; 彭卫

    2013-01-01

      要:本文介绍了炼油厂重油加工污水的生化处理工艺.阐述了污水处理中CAST工艺的结构,其特点是高效、稳定、工艺流程简单.结论表明,CAST生化处理系统在去除污水中有机污染物的同时具有较好的硝化与反硝化功能.CAST工艺的污水处理厂具有较高的自动化水平,可大大降低污水的运行成本,对炼油厂的污水处理完全能够达到国家一级排放标准.%The biochemical treatment technology of refinery sewage was introduced. Characteristics and structure of CAST technology in sewage treatment were discussed in detail. The main characteristics of which is high-efficiency, stability and Simple process. The operation results show that the CAST biochemical treatment system has better nitrification and denitrification. Sewage treatment plant using CAST Process has so high automation level that it can greatly reduce the cost of wastewater treatment plant of operation,refinery sewage treated by the CAST biochemical treatment system can fully meet the national emission standard.

  10. Characteristics and Biodegradability of Wastewater Organic Matter in Municipal Wastewater Treatment Plants Collecting Domestic Wastewater and Industrial Discharge

    OpenAIRE

    Yun-Young Choi; Seung-Ryong Baek; Jae-In Kim; Jeong-Woo Choi; Jin Hur; Tae-U Lee; Cheol-Joon Park; Byung Joon Lee

    2017-01-01

    Municipal wastewater treatment plants (WWTPs) in Korea collect and treat not only domestic wastewater, but also discharge from industrial complexes. However, some industrial discharges contain a large amount of non-biodegradable organic matter, which cannot be treated properly in a conventional biological WWTP. This study aimed to investigate the characteristics and biodegradability of the wastewater organic matter contained in the industrial discharges and to examine the fate of the industri...

  11. Biological wastewater treatment in brewhouses

    Directory of Open Access Journals (Sweden)

    Voronov Yuriy Viktorovich

    2014-03-01

    Full Text Available In the article the working principles of wastewater biological treatment for food companies is reviewed, including dairies and breweries, the waters of which are highly concentrated with dissolved organic contaminants and suspended solids. An example of successful implementation is anaerobic-aerobic treatment plants. Implementation of these treatment plants can achieve the required wastewater treatment at the lowest operational expenses and low volumes of secondary waste generated. Waste water from the food companies have high concentration of various organic contaminants (fats, proteins, starch, sugar, etc.. For such wastewater, high rates of suspended solids, grease and other contaminants are characteristic. Wastewater food industry requires effective purification flowsheets using biological treatment facilities. At the moment methods for the anaerobic-aerobic purification are applied. One of such methods is the treatment of wastewater at ASB-reactor (methane reactor and the further tertiary treatment on the OSB-reactor (aeration. Anaerobic process means water treatment processes in anoxic conditions. The anaerobic treatment of organic contamination is based on the process of methane fermentation - the process of converting substances to biogas. The role of biological effluent treatment is discussed with special attention given to combined anaerobic/aerobic treatment. Combining anaerobic pre-treatment with aerobic post-treatment integrates the advantages of both processes, amongst which there are reduced energy consumption (net energy production, reduced biological sludge production and limited space requirements. This combination allows for significant savings for operational costs as compared to complete aerobic treatment without compromising the required discharge standards. Anaerobic treatment is a proven and energy efficient method to treat industrial wastewater effluents. These days, more and more emphasis is laid on low energy use, a

  12. Sequential micro and ultrafiltration of distillery wastewater

    Directory of Open Access Journals (Sweden)

    Vasić Vesna M.

    2015-01-01

    Full Text Available Water reuse and recycling, wastewater treatment, drinking water production and environmental protection are the key challenges for the future of our planet. Membrane separation technologies for the removal of all suspended solids and a fraction of dissolved solids from wastewaters, are becoming more and more promising. Also, these processes are playing a major role in wastewater purification systems because of their high potential for recovery of water from many industrial wastewaters. The aim of this work was to evaluate the application of micro and ultrafiltration for distillery wastewater purification in order to produce water suitable for reuse in the bioethanol industry. The results of the analyses of the permeate obtained after micro and ultrafiltration showed that the content of pollutants in distillery wastewater was significantly reduced. The removal efficiency for chemical oxygen demand, dry matter and total nitrogen was 90%, 99.2% and 99.9%, respectively. Suspended solids were completely removed from the stillage.

  13. Water and Wastewater Rate Hikes Outpace CPI

    Energy Technology Data Exchange (ETDEWEB)

    Stratton, Hannah [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Fuchs, Heidi [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chen, Yuting [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Dunham, Camilla [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Williams, Alison [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2017-08-31

    Water and wastewater treatment and delivery is the most capital-intensive of all utility services. Historically underpriced, water and wastewater rates have exhibited unprecedented growth in the past fifteen years. Steep annual increases in water and wastewater rates that outpace the Consumer Price Index (CPI) have increasingly become the norm across the United States. In this paper, we analyze water and wastewater rates across U.S. census regions between 2000 and 2014. We also examine some of the driving factors behind these rate increases, including drought, water source, required infrastructure investment, population patterns, and conservation effects. Our results demonstrate that water and wastewater prices have consistently increased and have outstripped CPI throughout the study period nationwide, as well as within each census region. Further, evaluation of the current and upcoming challenges facing water and wastewater utilities suggests that sharp rate increases are likely to continue in the foreseeable future.

  14. Performance of wastewater treatment plants in Jordan and suitability ...

    African Journals Online (AJOL)

    STORAGESEVER

    2008-08-04

    Aug 4, 2008 ... African Journal of Biotechnology Vol. 7 (15), pp. ... Key words: Wastewater, treatment plants, water reuse, wastewater characteristics, wastewater treatment,. Jordan. ... separate), industrial waste entering the sewer, type of.

  15. The developments of anaerobic baffled reactor for wastewater ...

    African Journals Online (AJOL)

    STORAGESEVER

    2010-03-15

    Mar 15, 2010 ... 0.34. Bodkhe (2009). Complex wastewater ..... hydrolysis of complex wastewater into soluble substrates; .... Kinetic analysis of palm oil mill wastewater ... Abdullah LG, Idris A, Ahmadun FR, Baharin BS, Emby F, Megat MNMJ,.

  16. VOCs emission rate estimate for complicated industrial area source using an inverse-dispersion calculation method: A case study on a petroleum refinery in Northern China.

    Science.gov (United States)

    Wei, Wei; Lv, Zhaofeng; Yang, Gan; Cheng, Shuiyuan; Li, Yue; Wang, Litao

    2016-11-01

    This study aimed to apply an inverse-dispersion calculation method (IDM) to estimate the emission rate of volatile organic compounds (VOCs) for the complicated industrial area sources, through a case study on a petroleum refinery in Northern China. The IDM was composed of on-site monitoring of ambient VOCs concentrations and meteorological parameters around the source, calculation of the relationship coefficient γ between the source's emission rate and the ambient VOCs concentration by the ISC3 model, and estimation of the actual VOCs emission rate from the source. Targeting the studied refinery, 10 tests and 8 tests were respectively conducted in March and in June of 2014. The monitoring showed large differences in VOCs concentrations between background and downwind receptors, reaching 59.7 ppbv in March and 248.6 ppbv in June, on average. The VOCs increases at receptors mainly consisted of ethane (3.1%-22.6%), propane (3.8%-11.3%), isobutane (8.5%-10.2%), n-butane (9.9%-13.2%), isopentane (6.1%-12.9%), n-pentane (5.1%-9.7%), propylene (6.1-11.1%) and 1-butylene (1.6%-5.4%). The chemical composition of the VOCs increases in this field monitoring was similar to that of VOCs emissions from China's refineries reported, which revealed that the ambient VOCs increases were predominantly contributed by this refinery. So, we used the ISC3 model to create the relationship coefficient γ for each receptor of each test. In result, the monthly VOCs emissions from this refinery were calculated to be 183.5 ± 89.0 ton in March and 538.3 ± 281.0 ton in June. The estimate in June was greatly higher than in March, chiefly because the higher environmental temperature in summer produced more VOCs emissions from evaporation and fugitive process of the refinery. Finally, the VOCs emission factors (g VOCs/kg crude oil refined) of 0.73 ± 0.34 (in March) and 2.15 ± 1.12 (in June) were deduced for this refinery, being in the same order with previous direct

  17. Research on the characteristic of wastewater from high-sulfur crude oil processing and its treatment technology%加工高硫原油产生污水的性质及其处理工艺

    Institute of Scientific and Technical Information of China (English)

    巫明娟; 卞玉涛

    2013-01-01

    Based on the processing of Western Canada crude oil in a refinery,the properties of the industrial wastewater generated during the processing course are analyzed. The wastewater is characterized by high pH,low sulfide content,low ammonia-nitrogen content,low oil content,and high COD content. It is found that by using the original facilities in the wastewater treatment plant, all of the wastewater generated during the course of high-sulfur Western Canada crude oil processing reaches the emission standard, through adjusting the pH, increasing flocculent dosage and glucose dosage in biochemical pool, and adjusting the temperature of biochemical pool.%对加西原油加工过程产生污水的性质进行分析,该污水具有pH大、硫化物含量低、氨氮含量低、含油量低、COD含量高的特点.在污水处理场原有设施上,通过调节pH、增加絮凝剂投加量、增加生化池葡萄糖投加量、调节生化池温度等措施,使加西原油加工期间所产生的污水全部达标排放.

  18. FAILURE ANALYSIS: WASTEWATER DRUM BULGING

    Energy Technology Data Exchange (ETDEWEB)

    Vormelker, P

    2008-09-15

    A 55 gallon wastewater drum lid was found to be bulged during storage in a remote area. Drum samples were obtained for analysis. The interior surface of these samples revealed blistering and holes in the epoxy phenolic drum liner and corrosion of the carbon steel drum. It is suspected that osmotic pressure drove permeation of the water through the epoxy phenolic coating which was weakened from exposure to low pH water. The coating failed at locations throughout the drum interior. Subsequent corrosion of the carbon steel released hydrogen which pressurized the drum causing deformation of the drum lid. Additional samples from other wastewater drums on the same pallet were also evaluated and limited corrosion was visible on the interior surfaces. It is suspected that, with time, the corrosion would have advanced to cause pressurization of these sealed drums.

  19. Applied math for wastewater plant operators

    CERN Document Server

    Price, Joanne K

    1998-01-01

    With many worked examples, this book provides step-by-step instruction for all calculations required for wastewater treatment. Pertinent calculations are conveniently summarized in each chapter. The text covers all the fundamental math concepts and skills needed for daily wastewater treatment plant operations. The workbook for this book can be purchased separately or together in the Applied Math for Wastewater Plant Operators Set (ISBN: 9781566769891).

  20. Microbiological analysis of municipal wastewater treating photobioreactors

    OpenAIRE

    Krustok, Ivo

    2016-01-01

    Microalgae reactors, commonly known as photobioreactors, have become increasingly popular as an alternative for wastewater treatment. These systems reduce pollutants and remove nutrients such as nitrogen and phosphorous compounds from wastewater utilizing microalgae and bacteria. The biomass produced in the reactors can potentially be used to produce biofuels and decrease some of the energy demands of the process. Wastewater treating photobioreactors are a relatively new technology and many a...