Taking inventory on VOC releases from Amoco's Yorktown refinery

International Nuclear Information System (INIS)

Klee, H.H. Jr.; Schmitt, R.E.; Harrass, M.C.; Podar, M.K.

1996-01-01

Amoco's Yorktown, Virginia, refinery is a 35-year-old, 53,000 bbl/day facility that manufacturers gasoline, heating oil, liquid petroleum gas, sulfur, and coke. In a cooperative and voluntary effort, Amoco Corporation and the US Environmental Protection Agency conducted a joint project to study pollution prevention opportunities at an operating industrial facility. Source reduction efforts--key to pollution prevention strategies--require knowledge of specific sources of releases. However, data on releases from individual process units are limited in favor of data to monitor existing end-of-pipe pollution control requirements. The study's sampling program sought to portray the distribution of releases within the refinery, their management within the refinery, and ultimate releases leaving the refinery. Subsequent tests of blowdown stack and fugitive emissions further improved total release estimates. The initial study estimated that the refinery generates about 25,000 metric tons (t)/year of potential pollutants. Of these, about half are released from the refinery as airborne, waterborne, or land-disposed releases. Airborne releases comprise the majority of releases by mass, about 12,000 t/year. Most of the airborne releases are volatile organic compound hydrocarbons. The inventory sampling project and subsequent work identified differences with Toxic Release Inventory (TRI) values and standard emission factors (AP-42). The inventory and other data provided an opportunity to consider options for, and limitations of, specific pollution prevention or source reduction strategies

Petroleum Refineries (Catalytic Cracking, Catalytic Reforming and Sulfur Recovery Units): National Emission Standards for Hazardous Air Pollutants (NESHAP)

Science.gov (United States)

learn more about the NESHAP for catalytic cracking and reforming units, as well as sulfur recovery units in petroleum refineries by reading the rule history, rule summary, background information documents, and compliance information

Energy efficiency improvement and cost saving opportunities forpetroleum refineries

Energy Technology Data Exchange (ETDEWEB)

Worrell, Ernst; Galitsky, Christina

2005-02-15

The petroleum refining industry in the United States is the largest in the world, providing inputs to virtually any economic sector,including the transport sector and the chemical industry. The industry operates 146 refineries (as of January 2004) around the country,employing over 65,000 employees. The refining industry produces a mix of products with a total value exceeding $151 billion. Refineries spend typically 50 percent of cash operating costs (i.e., excluding capital costs and depreciation) on energy, making energy a major cost factor and also an important opportunity for cost reduction. Energy use is also a major source of emissions in the refinery industry making energy efficiency improvement an attractive opportunity to reduce emissions and operating costs. Voluntary government programs aim to assist industry to improve competitiveness through increased energy efficiency and reduced environmental impact. ENERGY STAR (R), a voluntary program managed by the U.S. Environmental Protection Agency, stresses the need for strong and strategic corporate energy management programs. ENERGY STAR provides energy management tools and strategies for successful corporate energy management programs. This Energy Guide describes research conducted to support ENERGY STAR and its work with the petroleum refining industry.This research provides information on potential energy efficiency opportunities for petroleum refineries. This Energy Guide introduces energy efficiency opportunities available for petroleum refineries. It begins with descriptions of the trends, structure, and production of the refining industry and the energy used in the refining and conversion processes. Specific energy savings for each energy efficiency measure based on case studies of plants and references to technical literature are provided. If available, typical payback periods are also listed. The Energy Guide draws upon the experiences with energy efficiency measures of petroleum refineries worldwide

Ashland outlines $261 million in refinery unit construction

International Nuclear Information System (INIS)

Anon.

1992-01-01

This paper reports that Ashland Petroleum Co. has spelled out $261 million in projects completed, under way, or planned to produce cleaner fuel and further reduce emissions at two U.S. refineries. The company: Started up at $13 million pollution control system at its 213,400 b/cd Catlettsburg, Ky., plant. Started construction on six projects at its 67,100 b/cd St. Paul Park, Minn., refinery that will cost about $114 million and enable the plant to produce cleaner burning diesel fuel and further reduce emissions

Thermodynamic simulation and evaluation of sugar refinery evaporators using a steady state modelling approach

International Nuclear Information System (INIS)

Lewis, A.E.; Khodabocus, F.; Dhokun, V.; Khalife, M.

2010-01-01

In a sugar refinery, the juice is concentrated through evaporation, with the objective of concentrating the juice to syrup as rapidly as possible. Because the heat of vaporization of water is relatively high, the evaporation process can be highly energy intensive, and therefore the economical use of steam is important in the refinery. This paper reports on the development of a simulation model for the evaporation sections of two Mauritian sugar refineries. The first objective was to use the simulation model to carry out an energy balance over the evaporators in order to assess the economy of steam usage over the refinery. The second objective was to examine to what extent a fundamental steady state model, based on thermodynamics (not kinetics) was capable of predicting the material and energy flows in two operating sugar refineries and thereby to evaluate the applicability of the modelling framework. The simulation model was validated using historical data as well as data from the plant DCS system. The simulation results generally correlated well with the measured values, except for one of the evaporators on one refinery. Some suggestions were made as to the cause of the discrepancy. On balance, it was found that both refineries are extremely efficient in terms of steam and equipment usage and that there is not much scope for energy optimisation within the present configuration - nor for much spare steam capacity for an additional refinery. It was also shown that steady state process simulation, using thermodynamic models, can generate a very useful representation of a working refinery. Besides being able to use the model to 'benchmark' the operation and thus evaluate its performance as a whole as well as across individual units, it could also be used to evaluate refinery performance across refineries, nationally as well as globally.

Amoco/Environmental Protection Agency Pollution Prevention Project, Yorktown refinery. Refinery release inventory. Final report

International Nuclear Information System (INIS)

Klee, H.; Kizier, G.J.; Baloo, S.; Hockman, E.L.; Couzens-Roberts, C.

1992-07-01

The report volume summarizes physical data obtained during a 2-year pollution prevention study of Amoco Oil Company's Yorktown Virginia Refinery. The study was jointly sponsored as a cooperative effort of Amoco Corporation and the United States Environmental Protection Agency. A multi-media sampling program was used to identify potential pollution sources within the Refinery. Sampling and analysis included air, surface water, groundwater, and solid waste data. Public perceptions about environmental issues of concern in the vicinity of the Refinery were also surveyed. The inventory showed that nearly 99 percent of the releases were airborne at the facility. Most of the remainder involved land disposal of solid wastes. Specific sources of major pollutants are identified

Auxiliary units for refining of high nitrogen content oils: Premium II refinery case

Energy Technology Data Exchange (ETDEWEB)

Nicolato, Paolo Contim; Pinotti, Rafael [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)

2012-07-01

PETROBRAS is constantly investing on its refining park in order to increase the production of clean and stable fuels and to be capable to process heavier oils with high contaminants content. Sulfur and nitrogen are the main heteroatoms present in petroleum. They are responsible for some undesirable fuels properties like corrosivity and instability, and also emit pollutants when burnt. Hydrotreating and hydrocracking processes are designed to remove these contaminants and adjust other fuel properties, generating, as byproduct, sour gases and sour water streams rich in H{sub 2}S and NH{sub 3}, which are usually sent to Sour Water Treatment Units and Sulfur Recovery Units. The regeneration of the amine used for the light streams treatment, as fuel gas and LPG, also generates sour gas streams that must be also sent to Sulfur Recovery Units. As the ammonia content in the sour streams increases, some design parameters must be adjusted to avoid increasing the Refinery emissions. Sulfur Recovery Units must provide proper NH3 destruction. Sour Water Treatment must have a proper segregation between H{sub 2}S and ammonia streams, whenever desirable. Amine Regeneration Systems must have an efficient procedure to avoid the ammonia concentration in the amine solution. This paper presents some solutions usually applied to the Petroleum Industry and analyses some aspects related to Premium II Refinery Project and how its design will help the Brazilian refining park to meet future environmental regulation and market demands. (author)

Feasibility study on the modernization and expansion of the Tema Oil Refinery. Executive Summary. Export trade information

International Nuclear Information System (INIS)

Anon.

1992-04-01

The Tema Oil Refinery (TOR), which was commissioned in 1963, is a simple hydro-skimming plant which processes crude oil into LPG, gasoline, kerosene, gasoil, and fuel oil. It is the only petroleum refinery in Ghana. Over the years some of the equipment in the refinery has deteriorated or become obsolete necessitating major rehabilitation. A study of the refinery expansion project takes into consideration earlier studies and, equally important, recognizes the extensive work done by TOR in rehabilitating the refinery. The program, carried out in phases because of funding limitations, has addressed the critical repairs and replacements in the process units and utilities necessary to prolong the life of the refinery and assure reliability and safe operation. It undertook the task of investigating the feasibility of modernizing and expanding the refinery at Tema, Ghana to meet projected market demands until the year 2005. A process planning study was conducted to select the optimal process and utility configuration which would result in economic benefits to Ghana

Scheduling of Crude Oil Operations in Refinery without Sufficient Charging Tanks Using Petri Nets

Directory of Open Access Journals (Sweden)

Yan An

2017-05-01

Full Text Available A short-term schedule for crude oil operations in a refinery should define and sequence the activities in detail. Each activity involves both discrete-event and continuous variables. The combinatorial nature of the scheduling problem makes it difficult to solve. For such a scheduling problem, charging tanks are a type of critical resources. If the number of charging tanks is not sufficient, the scheduling problem is further complicated. This work conducts a study on the scheduling problem of crude oil operations without sufficient charging tanks. In this case, to make a refinery able to operate, a charging tank has to be in simultaneous charging and feeding to a distiller for some time, called simultaneously-charging-and-feeding (SCF mode, leading to disturbance to the oil distillation in distillers. A hybrid Petri net model is developed to describe the behavior of the system. Then, a scheduling method is proposed to find a schedule such that the SCF mode is minimally used. It is computationally efficient. An industrial case study is given to demonstrate the obtained results.

Aspects of petrochemistry in a fuels refinery

Energy Technology Data Exchange (ETDEWEB)

Esser, J.; Mielicke, C.J.; Maier, T. [MIRO - Mineraloelraffinerie Oberrhein GmbH und Co. KG, Karlsruhe (Germany)

2007-07-01

Classical links between refinery and petrochemical downstream operations are light naphtha, C2-C4-Olefins and various aromatic compounds. Additionally long chain paraffines from dewaxing or even heavy residues can be interesting starting materials for petrochemistry. Some aspects of these links between refining and petrochemistry as well as their impact on refinery operation and product pools are discussed. (orig.)

Current situation of oil refinery in Bulgaria

Science.gov (United States)

Vershkova, Elena; Petkova, Petinka; Grinkevich, Anastasia

2016-09-01

This article deals with the classification approach for oil refineries in international practices. Criteria of refinery estimation group, including its financial status estimation, have been investigated. The analysis object is “Lukoil Neftochim Bourgas” AD (LNCHB) activity. This company is a leading enterprise in Bulgaria. The analysis of LNCHB operating: energy intensity index; index of operating costs and return on investment index have been performed.

Feasibility study report for the Imperial Valley Ethanol Refinery: a 14. 9-million-gallon-per-year ethanol synfuel refinery utilizing geothermal energy

Energy Technology Data Exchange (ETDEWEB)

1981-03-01

The construction and operation of a 14,980,000 gallon per year fuel ethanol from grain refinery in the Imperial Valley of California is proposed. The Imperial Valley Ethanol Refinery (refinery) will use hot geothermal fluid from geothermal resources at the East Mesa area as the source of process energy. In order to evaluate the economic viability of the proposed Project, exhaustive engineering, cost analysis, and financial studies have been undertaken. This report presents the results of feasibility studies undertaken in geothermal resource, engineering, marketing financing, management, environment, and permits and approvals. The conclusion of these studies is that the Project is economically viable. US Alcohol Fuels is proceeding with its plans to construct and operate the Refinery.

HDS unit revamp and operating experience

Energy Technology Data Exchange (ETDEWEB)

Reinhardt, J. [Veba Oel Verarbeitungs-GmbH, Gelsenkirchen (Germany); Balfanz, U. [Aral Forschung, Gelsenkirchen (Germany); Dimmig, T. [TU Bergakademie Freiberg, Freiberg (Germany)

2002-12-01

Ruhr Oel GmbH, a joint venture between BP and PDVSA, operates a HDS unit at its Gelsenkirchen-Scholven site. The unit produces a major blend component for diesel fuel. Driven by ambitious German environmental policy and by an agreement between the German car and oil industries on the one hand and the government on the other, more stringent low sulphur fuel specifications will be enforced in Germany much earlier than in the rest of the European Union. In view of this situation a project was developed to fulfill the new product specifications with minimum investment. In a joint effort involving the refinery, the company research facilities and the catalyst supplier (AKZO NOBEL), pilot plant tests were performed to develop the best catalyst system and the new process conditions. Based on these results, an existing HDS unit was accordingly revamped. After the revamp, the unit produced diesel fuel with 50 ppm sulphur content and furthermore test runs at 10 ppm were carried out successfully. These results are displayed in this article. (orig.)

The life and times of a western refinery

International Nuclear Information System (INIS)

Thomas, W.

1998-01-01

An historical account is given of the discovery of oil by Imperial Oil Ltd., at Leduc in 1947, and the opening of a refinery in Edmonton in 1948. The discovery at Leduc was the first major strike to be made in western Canada, but Imperial Oil did not have a refinery at the site to process the new found crude. Given the economic constraints of the postwar era, Imperial Oil decided to dismantle and move an idle and virtually brand-new refinery located at Whitehorse, Yukon. It took 10 months to reassemble the refinery at its newly prepared site at Edmonton. Regular expansions and improvements helped to ensure that the refinery kept up with the advances in technology and market demand. By the early 1970s, small refineries were becoming uneconomical as distribution of products by pipelines became possible. In 1976 Imperial Oil spent more than $300 million to consolidate its four Prairie refineries, those in Calgary, Winnipeg, Regina and Edmonton, into one large facility at the Edmonton site. The role that the refinery plays in today's community and the effort that Imperial Oil makes to comply with stringent environmental regulations were described. Today, the refinery is producing 165,000 barrels a day of fuels and lubricants and another 20,000 barrels of asphalt. The refinery supplies more than 200 different products to customers across Canada, with unit costs which are amongst the lowest of North American refineries. figs

Thermoeconomic and environmental assessment of a crude oil distillation unit of a Nigerian refinery

International Nuclear Information System (INIS)

Waheed, M.A.; Oni, A.O.; Adejuyigbe, S.B.; Adewumi, B.A.

2014-01-01

The renovation of refineries should be aimed at achieving the highest possible technical efficiencies at a considerable investment cost and not only at replacing damaged components to attain full capacity utilisation. This study examined a crude distillation unit (CDU) of a Nigerian refinery plant comprising the atmospheric distillation unit (ADU), vacuum distillation unit (VDU), preflash unit (PFU), splitter unit (SPU), stabiliser unit (SBU) and heat exchanger network (HEN) to determine critical areas of inefficiencies as the plant managements plan renovation. Using real plant data, the CDU was simulated with Aspen Hysys ® and the thermoeconomic and environmental analyses were carried out. The results show that the energy and exergy efficiencies of the CDU were 9.0 and 4.0% respectively. The specific CO 2 emission was 3.67 kg CO 2 /bbl. The highly inefficient subunits accounting for 77.4 and 90.0% of the overall energy and exergy losses respectively and 60.3% of the emission released were the PFU, ADU and HEN. The highly inefficient components are the furnaces which accounted for 51.6% of the overall exergy losses. The environmental and economic analysis also indicated that these components are the most potent for improvement. The columns of the PFU and ADU should be revamped to reduce their energy demands and the HEN should be modified to minimise effluent losses. - Highlights: •The assessment of a crude distillation unit (CDU) in Nigeria was carried out. •The assessment considered thermodynamic, thermoeconomic and environment analysis. •The assessment revealed areas with poor performance in the CDU. •Large thermodynamic and economic losses are responsible for the poor performance. •Areas with large losses and emission rate should be targeted for improvement

Thermoeconomic and environmental assessment of a crude oil distillation unit of a Nigerian refinery

Energy Technology Data Exchange (ETDEWEB)

Waheed, M. A. [Department of Mechanical Engineering, Federal University of Agriculture, Abeokuta, P.M.B. 2240, Abeokuta, Ogun State (Nigeria); Oni, A.O., E-mail: fem2day@yahoo.com [Department of Mechanical Engineering, Federal University of Agriculture, Abeokuta, P.M.B. 2240, Abeokuta, Ogun State (Nigeria); Adejuyigbe, S. B. [Department of Mechanical Engineering, Federal University of Agriculture, Abeokuta, P.M.B. 2240, Abeokuta, Ogun State (Nigeria); Adewumi, B. A. [Department of Agricultural Engineering, Federal University of Agriculture, Abeokuta, P.M.B. 2240, Abeokuta, Ogun State (Nigeria)

2014-05-01

The renovation of refineries should be aimed at achieving the highest possible technical efficiencies at a considerable investment cost and not only at replacing damaged components to attain full capacity utilisation. This study examined a crude distillation unit (CDU) of a Nigerian refinery plant comprising the atmospheric distillation unit (ADU), vacuum distillation unit (VDU), preflash unit (PFU), splitter unit (SPU), stabiliser unit (SBU) and heat exchanger network (HEN) to determine critical areas of inefficiencies as the plant managements plan renovation. Using real plant data, the CDU was simulated with Aspen Hysys{sup ®} and the thermoeconomic and environmental analyses were carried out. The results show that the energy and exergy efficiencies of the CDU were 9.0 and 4.0% respectively. The specific CO{sub 2} emission was 3.67 kg CO{sub 2}/bbl. The highly inefficient subunits accounting for 77.4 and 90.0% of the overall energy and exergy losses respectively and 60.3% of the emission released were the PFU, ADU and HEN. The highly inefficient components are the furnaces which accounted for 51.6% of the overall exergy losses. The environmental and economic analysis also indicated that these components are the most potent for improvement. The columns of the PFU and ADU should be revamped to reduce their energy demands and the HEN should be modified to minimise effluent losses. - Highlights: •The assessment of a crude distillation unit (CDU) in Nigeria was carried out. •The assessment considered thermodynamic, thermoeconomic and environment analysis. •The assessment revealed areas with poor performance in the CDU. •Large thermodynamic and economic losses are responsible for the poor performance. •Areas with large losses and emission rate should be targeted for improvement.

Production planning and scheduling in refinery industry

International Nuclear Information System (INIS)

Persson, Jan.

1999-01-01

In this thesis we consider production planning and scheduling in refinery industry, in particular we study the planning and scheduling at the Nynaes AB refinery and at the Scanraff AB refinery. The purpose is to contribute to the development and the use of optimization models to support efficient decision making. We identify various decision problems concerning the aggregated production planning, the shipment planning, the scheduling of operation modes, and the utilization of pipes and tanks; and we discuss the potential to successfully apply optimization models on these problems. We formulate a mixed integer linear programming model for the scheduling of operation modes at Nynaes. The model concerns decisions about which mode of operation to use at a particular point in time in order to minimize costs of changing modes and costs of keeping inventories, given demands for products. We derive several types of valid inequalities for this mathematical problem and show how these inequalities can improve the lower bound obtained from the linear programming relaxation of the problem. We also show how the valid inequalities can be used to improve the performance of a branch and bound solution approach. Further, a tabu search heuristic is developed for the scheduling problem. The solution methods are tested on data provided by the Nynaes refinery, and the performance of the methods are discussed. We present several extensions of the proposed model, and illustrate how the model can be used to support both operational and strategic decision making at the refinery. 66 refs, 6 figs, 32 tabs. Also published as: Dissertation from the International Graduate School of Management and Industrial Engineering, No 25, Licenciate Thesis

Production planning and scheduling in refinery industry

Energy Technology Data Exchange (ETDEWEB)

Persson, Jan

1999-07-01

In this thesis we consider production planning and scheduling in refinery industry, in particular we study the planning and scheduling at the Nynaes AB refinery and at the Scanraff AB refinery. The purpose is to contribute to the development and the use of optimization models to support efficient decision making. We identify various decision problems concerning the aggregated production planning, the shipment planning, the scheduling of operation modes, and the utilization of pipes and tanks; and we discuss the potential to successfully apply optimization models on these problems. We formulate a mixed integer linear programming model for the scheduling of operation modes at Nynaes. The model concerns decisions about which mode of operation to use at a particular point in time in order to minimize costs of changing modes and costs of keeping inventories, given demands for products. We derive several types of valid inequalities for this mathematical problem and show how these inequalities can improve the lower bound obtained from the linear programming relaxation of the problem. We also show how the valid inequalities can be used to improve the performance of a branch and bound solution approach. Further, a tabu search heuristic is developed for the scheduling problem. The solution methods are tested on data provided by the Nynaes refinery, and the performance of the methods are discussed. We present several extensions of the proposed model, and illustrate how the model can be used to support both operational and strategic decision making at the refinery. 66 refs, 6 figs, 32 tabs. Also published as: Dissertation from the International Graduate School of Management and Industrial Engineering, No 25, Licenciate Thesis.

Production planning and scheduling in refinery industry

Energy Technology Data Exchange (ETDEWEB)

Persson, Jan

1999-06-01

In this thesis we consider production planning and scheduling in refinery industry, in particular we study the planning and scheduling at the Nynaes AB refinery and at the Scanraff AB refinery. The purpose is to contribute to the development and the use of optimization models to support efficient decision making. We identify various decision problems concerning the aggregated production planning, the shipment planning, the scheduling of operation modes, and the utilization of pipes and tanks; and we discuss the potential to successfully apply optimization models on these problems. We formulate a mixed integer linear programming model for the scheduling of operation modes at Nynaes. The model concerns decisions about which mode of operation to use at a particular point in time in order to minimize costs of changing modes and costs of keeping inventories, given demands for products. We derive several types of valid inequalities for this mathematical problem and show how these inequalities can improve the lower bound obtained from the linear programming relaxation of the problem. We also show how the valid inequalities can be used to improve the performance of a branch and bound solution approach. Further, a tabu search heuristic is developed for the scheduling problem. The solution methods are tested on data provided by the Nynaes refinery, and the performance of the methods are discussed. We present several extensions of the proposed model, and illustrate how the model can be used to support both operational and strategic decision making at the refinery. 66 refs, 6 figs, 32 tabs. Also published as: Dissertation from the International Graduate School of Management and Industrial Engineering, No 25, Licenciate Thesis

Economic impacts of oil spills: Spill unit costs for tankers, pipelines, refineries, and offshore facilities

International Nuclear Information System (INIS)

1993-01-01

The impacts of oil spills -- ranging from the large, widely publicized Exxon Valdez tanker incident to smaller pipeline and refinery spills -- have been costly to both the oil industry and the public. For example, the estimated costs to Exxon of the Valdez tanker spill are on the order of $4 billion, including $2.8 billion (in 1993 dollars) for direct cleanup costs and $1.125 billion (in 1992 dollars) for settlement of damages claims caused by the spill. Application of contingent valuation costs and civil lawsuits pending in the State of Alaska could raise these costs appreciably. Even the costs of the much smaller 1991 oil spill at Texaco's refinery near Anacortes, Washington led to costs of $8 to 9 million. As a result, inexpensive waming, response and remediation technologies could lower oil spin costs, helping both the oil industry, the associated marine industries, and the environment. One means for reducing the impact and costs of oil spills is to undertake research and development on key aspects of the oil spill prevention, warming, and response and remediation systems. To target these funds to their best use, it is important to have sound data on the nature and size of spills, their likely occurrence and their unit costs. This information could then allow scarce R ampersand D dollars to be spent on areas and activities having the largest impact. This report is intended to provide the ''unit cost'' portion of this crucial information. The report examines the three key components of the US oil supply system, namely, tankers and barges; pipelines and refineries; and offshore production facilities. The specific purpose of the study was to establish the unit costs of oil spills. By manipulating this key information into a larger matrix that includes the size and frequency of occurrence of oil spills, it will be possible' to estimate the likely future impacts, costs, and sources of oil spills

Challenges and technological opportunities for the oil refining industry: A Brazilian refinery case

International Nuclear Information System (INIS)

Castelo Branco, David A.; Gomes, Gabriel L.; Szklo, Alexandre S.

2010-01-01

The worldwide oil refining industry currently faces strong challenges related to uncertainties about future feedstock and characteristics of oil products. These challenges favor two main strategies for the sector: the first strategy is increasing refinery complexity and versatility; the second is integrating the refining and petrochemical industries, adding value to the crude oil while guaranteeing market share to premium oil products. Both strategies aim at increasing production of highly specified oil products, simultaneously reducing the environmental impacts of the refining industry. This paper analyses the case of a Brazilian refinery, Gabriel Passos Refinery (REGAP), by proposing additional investments to alter and/or expand its current production scheme. All the proposed options present relatively low investment rates of return. However, investments in a hydrocracking based configuration with a gasification unit providing hydrogen and power can further improve the operational profitability, due to reduced natural gas consumption.

Risk assessment of occupational exposure to benzene using numerical simulation in a complex geometry of a reforming unit of petroleum refinery.

Science.gov (United States)

Bayatian, Majid; Ashrafi, Khosro; Azari, Mansour Rezazadeh; Jafari, Mohammad Javad; Mehrabi, Yadollah

2018-04-01

There has been an increasing concern about the continuous and the sudden release of volatile organic pollutants from petroleum refineries and occupational and environmental exposures. Benzene is one of the most prevalent volatile compounds, and it has been addressed by many authors for its potential toxicity in occupational and environmental settings. Due to the complexities of sampling and analysis of benzene in routine and accidental situations, a reliable estimation of the benzene concentration in the outdoor setting of refinery using a computational fluid dynamics (CFD) could be instrumental for risk assessment of occupational exposure. In the present work, a computational fluid dynamic model was applied for exposure risk assessment with consideration of benzene being released continuously from a reforming unit of a refinery. For simulation of benzene dispersion, GAMBIT, FLUENT, and CFD post software are used as preprocessing, processing, and post-processing, respectively. Computational fluid dynamic validation was carried out by comparing the computed data with the experimental measurements. Eventually, chronic daily intake and lifetime cancer risk for routine operations through the two seasons of a year are estimated through the simulation model. Root mean square errors are 0.19 and 0.17 for wind speed and concentration, respectively. Lifetime risk assessments of workers are 0.4-3.8 and 0.0096-0.25 per 1000 workers in stable and unstable atmospheric conditions, respectively. Exposure risk is unacceptable for the head of shift work, chief engineer, and general workers in 141 days (38.77%) in a year. The results of this study show that computational fluid dynamics is a useful tool for modeling of benzene exposure in a complex geometry and can be used to estimate lifetime risks of occupation groups in a refinery setting.

Airborne concentrations of metals and total dust during solid catalyst loading and unloading operations at a petroleum refinery.

Science.gov (United States)

Lewis, Ryan C; Gaffney, Shannon H; Le, Matthew H; Unice, Ken M; Paustenbach, Dennis J

2012-09-01

Workers handle catalysts extensively at petroleum refineries throughout the world each year; however, little information is available regarding the airborne concentrations and plausible exposures during this type of work. In this paper, we evaluated the airborne concentrations of 15 metals and total dust generated during solid catalyst loading and unloading operations at one of the largest petroleum refineries in the world using historical industrial hygiene samples collected between 1989 and 2006. The total dust and metals, which included aluminum, cadmium, chromium, cobalt, copper, iron, lead, manganese, molybdenum, nickel, platinum, silicon, silver, vanadium, and zinc, were evaluated in relation to the handling of four different types of solid catalysts associated with three major types of catalytic processes. Consideration was given to the known components of the solid catalysts and any metals that were likely deposited onto them during use. A total of 180 analytical results were included in this analysis, representing 13 personal and 54 area samples. Of the long-term personal samples, airborne concentrations of metals ranged from refinery and perhaps other modern refineries during the timeframe examined. Copyright © 2011 Elsevier GmbH. All rights reserved.

Decision 99-8 : Shell Canada Limited application to construct and operate an oil sands bitumen upgrader in the Fort Saskatchewan area : Shell Canada Products Limited application to amend refinery approval in the Fort Saskatchewan area

International Nuclear Information System (INIS)

1999-01-01

The Alberta Energy and Utilities Board considered an application by Shell Canada Limited to construct and operate an oil sands bitumen upgrader on Shell's property adjoining the existing Scotford refinery in the County of Strathcona. The upgrader would process bitumen from Shell's proposed Muskeg River Mine, located 70 km north of Fort McMurray, and other feedstocks available in the area. The Board also considered an application for an amendment to the existing Scotford refinery approval, Industrial Development Permit 89-10, for the processing of 3.75 million cubic metres per year of sour conversion feedstock. Under a coordinated application process, Shell filed a joint Shell Scotford Upgrader application/Environmental Impact Assessment. Issues considered with respect to these applications were: technology selection, air/health, sulphur recovery, noise/traffic, and land use conflict. Shell stated that its Scotford refinery is the most energy efficient refinery in the Americas and that is has the highest liquid yield per unit volume of crude oil feedstock of any refinery in the world. The refinery's hydrocracking capacity would make it possible to use hydro-conversion technology for its upgrader which is environmentally advantageous. After examining all of the evidence pertaining to the applications, the Board found the projects to be in the public interest and is prepared to approve the Scotford Upgrader and Scotford Refinery modifications assuming that certain prescribed conditions are met

Treatment of Tehran refinery wastewater using rotating biological contactor

Energy Technology Data Exchange (ETDEWEB)

Ghazi, Masoud; Mirsajadi, Hassan; Ganjidoust, Hossien [Tarbeyat Modarres Univ., Teheran (Iran, Islamic Republic of). Environmental Engineering Dept.

1994-12-31

Tehran Refinery is a large plant which produces several petroleum products. The wastewaters are generated from several different refinery processes and units. Because of the wastewaters uniqueness they need to be treated in each specific plant. Currently, an activated sludge system is the main biological wastewater treatment process in Tehran refinery plant. A study was initiated in order to find a more suitable and reliable process which can produce a better treated effluent which might, in case the process be successful, be reused for irrigation lands. 5 refs., 5 figs.

Treatment of Tehran refinery wastewater using rotating biological contactor

Energy Technology Data Exchange (ETDEWEB)

Ghazi, Masoud; Mirsajadi, Hassan; Ganjidoust, Hossien [Tarbeyat Modarres Univ., Teheran (Iran, Islamic Republic of). Environmental Engineering Dept.

1993-12-31

Tehran Refinery is a large plant which produces several petroleum products. The wastewaters are generated from several different refinery processes and units. Because of the wastewaters uniqueness they need to be treated in each specific plant. Currently, an activated sludge system is the main biological wastewater treatment process in Tehran refinery plant. A study was initiated in order to find a more suitable and reliable process which can produce a better treated effluent which might, in case the process be successful, be reused for irrigation lands. 5 refs., 5 figs.

Economic forces push down selling prices of U.S. refineries

International Nuclear Information System (INIS)

Anon.

1996-01-01

Recent data on US refinery sales reveal that selling prices have continued to decline in the 1990s. Reasons for this decrease include increased plant investments to meet regulatory requirements, excess refining capacity, increased imports of refined products, and reduced margins. While these expenditures enable a refinery to continue operating, they do not make the refinery more profitable or valuable. Other factors contributing to reduced selling prices of US refineries are: declining local crude production; unstable crude costs; increased energy conservation; growing competition from alternative fuels

Two refineries running crude; third to restart by September

International Nuclear Information System (INIS)

Tippee, B.

1993-01-01

Kuwait's downstream oil and gas industry, which sustained less damage than the country's oil field infrastructure during the Iraqi occupation of the 1990-91, has nearly completed reconstruction. Two of three refineries have resumed operations, one of them at reduced crude distillation rates. And state-owned Kuwait National Petroleum Co. hopes to put the other refinery, Shuaiba, back on stream in September, although not at preinvasion throughput rates. Major reconstruction will be complete by year end, with crude oil distillation capacity at 650,000 b/sd. Preinvasion crude capacities of Kuwait's refineries totaled 840,000 b/d. The article describes an overview of the recovery; the status of the Mina Abdulla processing plant, the Mina Al-Ahmadi refinery, and the Shuaiba refinery; modernization plans, and plans for petrochemicals

Retrofitting refinery and petrochemical plants

Energy Technology Data Exchange (ETDEWEB)

Kesler, M.G.

1988-06-01

This article focuses on process improvements as the best way to reduce plant energy use. The emphasis on process revamp is well justified, as an energy profile for a typical refinery shows. The diagram shows that 60% of the total heat losses are in water and air cooling. Most of this heat loss results from condensing and cooling in fractionators and recycle systems, intermediate product cooling, and condensing of turbine steam. These losses, of mostly low-level heat, are tied to the basic approach previously used for the process design of existing refineries. Despite the progress to date, there is growing evidence that these heat losses can be further reduced economically by about 20-30% in most refineries and petrochemical plants. One way to reduce the losses is to increase recovery of low-level heat by improved heat exchange, which has been the subject of most publications on plant energy conservation. A better way, presented here, is to develop new process schemes that require less air/water cooling. One useful concept in developing new schemes is to concentrate on heat losses, rather than heat input, as an easier measure of proposed improvements. By an overall heat balance, eliminating a unit of energy loss is equivalent to saving a unit of heat input somewhere in the plant.

Benzene exposure in a Japanese petroleum refinery.

Science.gov (United States)

Kawai, T; Yamaoka, K; Uchida, Y; Ikeda, M

1990-07-01

Time-weighted average (TWA) intensity of exposure of workers to benzene vapor during a shift was monitored by diffusive sampling technique in a Japanese petroleum refinery. The subjects monitored (83 in total) included refinery operators, laboratory personnel and tanker-loading workers. The results showed that the time-weighted average exposures are well below 1 ppm in most cases. The highest exposure was recorded in 1 case involved in bulk loading of tanker ships, in which exposure of over 1 ppm might take place depending on operational conditions. The observation was generally in agreement with levels previously reported.

Refinery siting workbook: appendices A and B

Energy Technology Data Exchange (ETDEWEB)

1980-07-01

The objective of this effort is to develop and provide basic refinery-related information for use by state and local government officials as a basis for establishing responsible refinery siting requirements and policies consistent with the federal clean air and water standards and socio-economic concerns. The report will be organized into two volumes. The main text comprises the basic topics of physical concerns, regulatory requirements, and permitting activities, while the second volume includes the detailed appendix materials such as the applicable laws, and the necessary permits, as available and a glossary of pertinent terms. As a means to this objective, three refinery sizes, 200,000, 100,000 and 30,000 barrels per day crude charge will be discussed in technical terms. Process unit configuration will be presented which will maximize either gasoline or heating oil production with either sweet or sour crude oil feedstocks. The major issues affecting the socio-economic impact of siting the refinery in a given locale will be presented. These data will review the factors affecting the human environment and the issues that must be addressed to assess the impact that a refinery will have on a community. The key federal registrations which impact upon a refinery siting decision shall be reviewed. Summaries of these regulations and a simplified decision diagram for the air and water acts shall be presented to assist both government and refinery officials in understanding the scope of regulatory impact. All pertinent procedures required for refinery permitting shall be reviewed under the generalized headings of air, water, health and safety, land use, and miscellaneous permits. This categorization at the federal, state and local levels of government shall be used as a basis for establishing degrees of emphasis.

Influence of operating conditions on the air gasification of dry refinery sludge in updraft gasifier

International Nuclear Information System (INIS)

Ahmed, R; Sinnathambi, C M

2013-01-01

In the present work, details of the equilibrium modeling of dry refinery sludge (DRS) are presented using ASPEN PLUS Simulator in updraft gasifier. Due to lack of available information in the open journal on refinery sludge gasification using updraft gasifier, an evaluate for its optimum conditions on gasification is presented in this paper. For this purpose a Taguchi Orthogonal array design, statistical software is applied to find optimum conditions for DRS gasification. The goal is to identify the most significant process variable in DRS gasification conditions. The process variables include; oxidation zone temperature, equivalent ratio, operating pressure will be simulated and examined. Attention was focused on the effect of optimum operating conditions on the gas composition of H 2 and CO (desirable) and CO 2 (undesirable) in terms of mass fraction. From our results and finding it can be concluded that the syngas (H 2 and CO) yield in term of mass fraction favors high oxidation zone temperature and at atmospheric pressure while CO 2 acid gas favor at a high level of equivalent ratio as well as air flow rate favoring towards complete combustion.

Valve automation in Indian refinery; Armaturenautomatisierung in indischer Raffinerie

Energy Technology Data Exchange (ETDEWEB)

Herbstritt, M. [AUMA Riester GmbH und Co. KG, Muellheim (Germany)

2006-12-15

The Mahul refinery near Mumbai is the third largest site of its kind in India. It is operated by BPCL, Bharat Petroleum Corporation Ltd. During the last few months, the refinery was extended. A plant for manufacturing motor lubricants was built, together with a tank farm for the products (LOBS = lube oil base stock). In April 2006 the new plant sections were put into operation. This article deals with the valve automation for this project. (orig.)

Industrial application of gasoline aromatization and desulfurization technology in Hohhot refinery

Directory of Open Access Journals (Sweden)

Li Zixia

2017-01-01

Full Text Available Gasoline aromatization and desulfurization (GARDES technology is extensively used in refineries of Petrochina, aiming to produce high quality ultraclean fluid catalytic cracking (FCC gasoline. This article introduces the industrial application results on the hydrodesulfurization unit of the Hohhot refinery, which plays an important role in guiding next round gasoline upgrading. The characteristics and the principle of GARDES technology were elaborated by analyzing the distribution of sulfur and hydrocarbon compounds in the feed and product. The analysis results proved that the presence of broad ranged sulfur types in the feed can be removed at different stages. Olefin can be decreased by saturation and conversion into i-paraffins and aromatics. The sulfur content of the blend product can be limited under 10 mg/kg, showing GARDES technology has excellent sulfur removal ability. The olefin reduction can also satisfy the ever-increasing severe requirement about the olefin limitation, while the loss of research octane number (RON can be minimized to an acceptable level. Furthermore, according to the demand of gasoline upgrading, GARDES technology has great flexibility by adjusting operation condition without any further investment, which brings more economic benefits for refinery.

Multi-unit Operations in Non-Nuclear Systems: Lessons Learned for Small Modular Reactors

Energy Technology Data Exchange (ETDEWEB)

OHara J. M.; Higgins, J.; DAgostino, A.

2012-01-17

The nuclear-power community has reached the stage of proposing advanced reactor designs to support power generation for decades to come. Small modular reactors (SMRs) are one approach to meet these energy needs. While the power output of individual reactor modules is relatively small, they can be grouped to produce reactor sites with different outputs. Also, they can be designed to generate hydrogen, or to process heat. Many characteristics of SMRs are quite different from those of current plants and may be operated quite differently. One difference is that multiple units may be operated by a single crew (or a single operator) from one control room. The U.S. Nuclear Regulatory Commission (NRC) is examining the human factors engineering (HFE) aspects of SMRs to support licensing reviews. While we reviewed information on SMR designs to obtain information, the designs are not completed and all of the design and operational information is not yet available. Nor is there information on multi-unit operations as envisioned for SMRs available in operating experience. Thus, to gain a better understanding of multi-unit operations we sought the lesson learned from non-nuclear systems that have experience in multi-unit operations, specifically refineries, unmanned aerial vehicles and tele-intensive care units. In this paper we report the lessons learned from these systems and the implications for SMRs.

Api Energia IGCC plant is fully integrated with refinery

Energy Technology Data Exchange (ETDEWEB)

Del Bravo, R. [api Energia, Rome (Italy); Trifilo, R. [ABB Sadelmi, Milan (Italy); Chiantore, P.V. [api anonima petroli Italiania Spa, Rome (Italy); Starace, F. [ABB Power Generation, Baden (Switzerland); O`Keefe, L.F. [Texico, White Plains (United States)

1998-06-01

The api Energia integrated gasification combined cycle (IGCC) plant being built at Falconara Marittima, on Italy`s Adriatic coast, is one of the three IGCC plants under construction in Italy following the liberalization of the electricity production sector. The plant will take 59.2 t/h of high sulphur heavy oil produced by the Falconara refinery, convert it to syngas and use the gas to generate 280 MW of electricity, plus steam and other gases for use in the refinery. The IGCC plant will be highly integrated into the refining process, with a large number of interchanges between the IGCC unit and the rest of the refinery. (author)

Ranking environmental liabilities at a petroleum refinery

International Nuclear Information System (INIS)

Lupo, M.

1995-01-01

A new computer model is available to allow the management of a petroleum refinery to prioritize environmental action and construct a holistic approach to remediation. A large refinery may have numerous solid waste management units regulated by the Resource Conservation and Recovery Act (RCRA), as well as process units that emit hazardous chemicals into the environment. These sources can impact several environmental media, potentially including the air, the soil, the groundwater, the unsaturated zone water, and surface water. The number of chemicals of concern may be large. The new model is able to rank the sources by considering the impact of each chemical in each medium from each source in terms of concentration, release rate, and a weighted index based on toxicity. In addition to environmental impact, the sources can be ranked in three other ways: (1) by cost to remediate, (2) by environmental risk reduction caused by the remediation in terms of the decreases in release rate, concentration, and weighted index, and (3) by cost-benefit, which is the environmental risk reduction for each source divided by the cost of the remedy. Ranking each unit in the refinery allows management to use its limited environmental resources in a pro-active strategic manner that produces long-term results, rather than in reactive, narrowly focused, costly, regulatory-driven campaigns that produce only short-term results

The refinery industry within the Mediterranean area

International Nuclear Information System (INIS)

1999-01-01

During the period 1997-1998 Ome (Observatorie Mediterraneen de l'Energie) within a working group which was formed by the experts among the associated companies, has carried on an analysis on the prospects of refinery industry in the Mediterranean area in view of 2010. The aim of this study was to make clear, to the different operators, the consequences of the political choices in investments on refinery industry in the context of the progressive liberalization of the sector [it

Dunkerque`s refinery. Mobil-BP-Elf: matrimonial triangle with background anxiety; Raffinerie de Dunkerque. Mobil-BP-Elf: menage a trois sur fond d`inquietude

Energy Technology Data Exchange (ETDEWEB)

Vogue, A. de

1997-08-01

The annual production of the Dunkerque`s refinery (France) represents 330000 t of lubricants, 16000 t of paraffins, 17000 t of wax, 34000 t of extracts, 304000 t of diesel fuel and 300000 t of bitumens. From the legal aspect, Mobil is operator of the unit which belongs to an independent company held by BP (60%) and Elf (40%). After the BP-Mobil agreement was signed, the Dunkerque`s refinery entered into new Mobil`s network of 6 lubricants refineries which represent an overall over-capacity of 400000 t/year. This over-capacity is a consequence of export limitations due to profits reduction. (J.S.)

Oil refining in a CO2 constrained world: Effects of carbon pricing on refineries globally

International Nuclear Information System (INIS)

Abdul-Manan, Amir F.N.; Arfaj, Abdullah; Babiker, Hassan

2017-01-01

Six aggregated refinery linear programming (LP) models were developed to represent actual refineries in North America, Latin America, Europe (including the CIS), Middle East, Asia (excluding China) and China. The models were used to conduct regional comparative assessments and to evaluate the effects of carbon pricing on refinery operations globally. We found that the average refinery energy efficiencies for the regions were estimated to range from 92.2% to 95.2%. The well-to-refinery gate carbon intensities for gasoline, diesel and jet fuels were estimated to be 17.1 (16.4–19.4), 13.3 (12.5–14.2) and 10.1 (9.6–10.8) gCO2eq/MJ, respectively. If refineries are forced to at least meet the 2014 regional volume demands for oil products, pricing CO 2 would not have an impact on either refinery productions, efficiency or emissions. If refineries are allowed to re-optimize production slates to reduce CO 2 emissions, refineries would opt to increase gasoline yield at the expense of diesel. This is counter intuitive since gasoline has a higher carbon intensity than diesel. The refinery bias against dieselization creates a supply preference toward a less efficient transportation end use. Here, we argue that if carbon pricing is not administered properly, this can lead to emissions leakage from refineries to the road transport sector. - Highlights: • Investigate actual refinery productions in 6 regions globally. • Refineries already operate at the most efficient levels. • Complex refineries tolerate higher CO 2 prices better. • Carbon pricing induces bias against dieselization. • Identify potential emissions leakage.

Integrated pollution control for oil refinery complexes

Energy Technology Data Exchange (ETDEWEB)

Kiperstok, A [Bahia Univ., Salvador, BA (Brazil); Sharratt, P N [Manchester Univ. (United Kingdom). Inst. of Science and Technology

1994-12-31

Improving environmental performance of oil refineries is a complex task. Emission limits, operating constraints, available technologies, operating techniques, and local environment sensitivity must all be considered. This work describes efforts to build an interactive software to deal with this problem. 8 refs., 5 figs.

Integrated pollution control for oil refinery complexes

Energy Technology Data Exchange (ETDEWEB)

Kiperstok, A. [Bahia Univ., Salvador, BA (Brazil); Sharratt, P.N. [Manchester Univ. (United Kingdom). Inst. of Science and Technology

1993-12-31

Improving environmental performance of oil refineries is a complex task. Emission limits, operating constraints, available technologies, operating techniques, and local environment sensitivity must all be considered. This work describes efforts to build an interactive software to deal with this problem. 8 refs., 5 figs.

Petroleum Refinery Jobs and Economic Development Impact (JEDI) Model User Reference Guide

Energy Technology Data Exchange (ETDEWEB)

Goldberg, Marshall [MRG and Associates, Nevada City, CA (United States)

2013-12-31

The Jobs and Economic Development Impact (JEDI) models, developed through the National Renewable Energy Laboratory (NREL), are user-friendly tools utilized to estimate the economic impacts at the local level of constructing and operating fuel and power generation projects for a range of conventional and renewable energy technologies. The JEDI Petroleum Refinery Model User Reference Guide was developed to assist users in employing and understanding the model. This guide provides information on the model's underlying methodology, as well as the parameters and references used to develop the cost data utilized in the model. This guide also provides basic instruction on model add-in features, operation of the model, and a discussion of how the results should be interpreted. Based on project-specific inputs from the user, the model estimates job creation, earning and output (total economic activity) for a given petroleum refinery. This includes the direct, indirect and induced economic impacts to the local economy associated with the refinery's construction and operation phases. Project cost and job data used in the model are derived from the most current cost estimations available. Local direct and indirect economic impacts are estimated using economic multipliers derived from IMPLAN software. By determining the regional economic impacts and job creation for a proposed refinery, the JEDI Petroleum Refinery model can be used to field questions about the added value refineries may bring to the local community.

Repair procedure used in removing corroded pits in the distillation towers of the Getulio Vargas Refinery Unit 2100

Energy Technology Data Exchange (ETDEWEB)

Lordelos, H.M.; Santin, J.L.

1977-07-01

A description is given of the corrosion pits on ASTM A240, Type 405 steel cladded to carbon steel plates used in Petroleo Brasileiro S.A.'s Getulio Vargas Refinery Unit 2100 distillation towers; the repair procedure used, including sand blasting of the corroded surfaces, grinding of the pits, and welding of those pits whose depth was above a maximum limit, and the use of liquid penetrant to check the repairs made; and hydrostatic testing of the T2201 catalytic cracking unit, which used also cladded metals and on which the pits were much smaller in size and number than those on the distillation units.

Pyrolysis oil upgrading for Co-processing in standard refinery units

NARCIS (Netherlands)

De Miguel Mercader, F.

2010-01-01

This thesis considers the route that comprises the upgrading of pyrolysis oil (produced from lingo-cellulosic biomass) and its further co-processing in standard refineries to produce transportation fuels. In the present concept, pyrolysis oil is produced where biomass is available and then

Petroleum refining. 5, refinery operation and management; Le raffinage du petrole. 5. Exploitation et gestion de la raffinerie

Energy Technology Data Exchange (ETDEWEB)

Favennec, J.P. (ed.)

2001-07-01

In this volume, the reader will find: an analysis of the refining industry's current environment and economics, including the importance of crude oil, the demand for petroleum products, markets and price setting mechanisms for crude oil and oil products, refining costs and margins, the evolution of the refining capacity and of constraints on the industry; a review of the tools available for optimising and controlling operations; an explanation of material balance management and a description of refinery management and organisation. Contents: I. Background to refining. 1. Oil and Energy. 2. Petroleum products applications, characteristics, markets. 3. International oil markets. 4. Refining: a technical summary investments, margins, costs probable future developments. II. Refining tools. 5. Introduction to linear programming as used in the refining industry. 6. Application of linear programming to refining. 7. Automation, process control and information technology. 8. Applications and their implementation. III. Management and organisation. 9. Management and optimisation of refinery operations. 10. Logistics: transport and dispatch. 11. Functional and organisational analysis. 12. Managerial aspects. Glossary. Index. (author)

Multi objective multi refinery optimization with environmental and catastrophic failure effects objectives

Science.gov (United States)

Khogeer, Ahmed Sirag

2005-11-01

Petroleum refining is a capital-intensive business. With stringent environmental regulations on the processing industry and declining refining margins, political instability, increased risk of war and terrorist attacks in which refineries and fuel transportation grids may be targeted, higher pressures are exerted on refiners to optimize performance and find the best combination of feed and processes to produce salable products that meet stricter product specifications, while at the same time meeting refinery supply commitments and of course making profit. This is done through multi objective optimization. For corporate refining companies and at the national level, Intea-Refinery and Inter-Refinery optimization is the second step in optimizing the operation of the whole refining chain as a single system. Most refinery-wide optimization methods do not cover multiple objectives such as minimizing environmental impact, avoiding catastrophic failures, or enhancing product spec upgrade effects. This work starts by carrying out a refinery-wide, single objective optimization, and then moves to multi objective-single refinery optimization. The last step is multi objective-multi refinery optimization, the objectives of which are analysis of the effects of economic, environmental, product spec, strategic, and catastrophic failure. Simulation runs were carried out using both MATLAB and ASPEN PIMS utilizing nonlinear techniques to solve the optimization problem. The results addressed the need to debottleneck some refineries or transportation media in order to meet the demand for essential products under partial or total failure scenarios. They also addressed how importing some high spec products can help recover some of the losses and what is needed in order to accomplish this. In addition, the results showed nonlinear relations among local and global objectives for some refineries. The results demonstrate that refineries can have a local multi objective optimum that does not

Fiscal 1999 feasibility study on energy conservation at Novo-oil refinery in Ufa City

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-31

An energy conservation plan was examined for Novo oil refinery of Bashneftechim Company in Ufa City, Bashkortstan, Russia for the purpose of making the plan tied to the COP3 joint implementation. The objective units in the study include an atmospheric and vacuum distillation unit with throughput of 7.8 million tons/year, a visbreaker and a vacuum gas oil hydrodesulfurization unit (for feedstock of FCC in Lenin Refinery), and a catalytic cracking unit, for example. Energy conservation measures are improvement and revamping of heating furnace to control excess air ratio in furnace, installation of air pre-heater or heat recovery boiler to recover heat from exhaust gas of heating furnace, additional installation of heat exchangers to recover heat from product oils, and efficiency improvement of overall operation by modernization of instrumentation and controlling equipment. The policy is not complete rebuilding of the facilities but utilizing the existing facilities by improving energy efficiency as far as possible. The study shows that investment for energy saving will be recovered within 3-6 years in many cases while total investment is estimated to be 1.5-3.0 billion yen. Total reduction of fuel consumption will be 500-800 million yen. Yearly reduction of CO2 emission will amount to 0.29 million tons (23%). (NEDO)

Economic impacts of oil spills: Spill unit costs for tankers, pipelines, refineries, and offshore facilities. [Task 1, Final report

Energy Technology Data Exchange (ETDEWEB)

1993-10-15

The impacts of oil spills -- ranging from the large, widely publicized Exxon Valdez tanker incident to smaller pipeline and refinery spills -- have been costly to both the oil industry and the public. For example, the estimated costs to Exxon of the Valdez tanker spill are on the order of $4 billion, including $2.8 billion (in 1993 dollars) for direct cleanup costs and $1.125 billion (in 1992 dollars) for settlement of damages claims caused by the spill. Application of contingent valuation costs and civil lawsuits pending in the State of Alaska could raise these costs appreciably. Even the costs of the much smaller 1991 oil spill at Texaco`s refinery near Anacortes, Washington led to costs of $8 to 9 million. As a result, inexpensive waming, response and remediation technologies could lower oil spin costs, helping both the oil industry, the associated marine industries, and the environment. One means for reducing the impact and costs of oil spills is to undertake research and development on key aspects of the oil spill prevention, warming, and response and remediation systems. To target these funds to their best use, it is important to have sound data on the nature and size of spills, their likely occurrence and their unit costs. This information could then allow scarce R&D dollars to be spent on areas and activities having the largest impact. This report is intended to provide the ``unit cost`` portion of this crucial information. The report examines the three key components of the US oil supply system, namely, tankers and barges; pipelines and refineries; and offshore production facilities. The specific purpose of the study was to establish the unit costs of oil spills. By manipulating this key information into a larger matrix that includes the size and frequency of occurrence of oil spills, it will be possible` to estimate the likely future impacts, costs, and sources of oil spills.

Future fuels: Canada's coast-to-coast network of refineries is emerging from a $3-billion-plus spending binge to take the lead in producing low sulphur gasoline

International Nuclear Information System (INIS)

Lunan, D.

2004-01-01

A series of investments to convert Canada's 22 operating refineries to produce low-sulphur gasoline are discussed. The investment involves more than $3-billion that will transform Canada's portfolio of aging refineries into one of the most efficient in the western world, and in the process reduce sulphur content in Canadian gasoline to 30 ppm. In some cases the refitting will be completed years ahead of the required 2005 deadline. Total refining capacity in Canada is about 2.5 million barrels per day of crude oil, which includes 580,000 barrels per day of capacity that is dedicated to upgrading bitumen into synthetic crude oil. The initiative to update the refineries was led by Irving Oil, which launched a one billion dollar refit of its 250,000 barrels per day Saint John refinery in the year 2000. Irving Oil's efforts were driven by the company's marketing program in the United States where regional fuel quality standards are higher than national standards either in Canada or the United States. Shell Canada and Imperial Oil are also on track to meet the 30 ppm sulphur level ahead of schedule. For example, Shell Canada is cooperating with Suncor Energy Products in the construction of a hydrotreater at Suncor's Sarnia refinery which will be used to reduce sulphur content of diesel from both the Shell and Suncor refineries, while Imperial Oil is investing over $520 million to refit its refineries in Alberta, Ontario and Nova Scotia. Petro-Canada too, has embarked on a $450 million capital program late in 2003 to introduce low sulphur gasoline; this was in addition to the $1.2 billion program to integrate its bitumen production, upgrading and refining operations. Ultramar launched its $300 million desulphurization program in late 2002; the project is now nearing completion. Refit of Ultramar's Jean Gaulin refinery on Quebec's South Shore will also include a 30,000 barrels per day continuous regeneration platformer to provide a second hydrogen source for the

Refinery Upgrading of Hydropyrolysis Oil From Biomass

Energy Technology Data Exchange (ETDEWEB)

Roberts, Michael [Gas Technology Inst., Des Plaines, IL (United States); Marker, Terry [Gas Technology Inst., Des Plaines, IL (United States); Ortiz-Toral, Pedro [Gas Technology Inst., Des Plaines, IL (United States); Linck, Martin [Gas Technology Inst., Des Plaines, IL (United States); Felix, Larry [Gas Technology Inst., Des Plaines, IL (United States); Wangerow, Jim [Gas Technology Inst., Des Plaines, IL (United States); Swanson, Dan [Gas Technology Inst., Des Plaines, IL (United States); McLeod, Celeste [CRI Catalyst, Houston, TX (United States); Del Paggio, Alan [CRI Catalyst, Houston, TX (United States); Urade, Vikrant [CRI Catalyst, Houston, TX (United States); Rao, Madhusudhan [CRI Catalyst, Houston, TX (United States); Narasimhan, Laxmi [CRI Catalyst, Houston, TX (United States); Gephart, John [Johnson Timber, Hayward, WI (United States); Starr, Jack [Cargill, Wayzata, MN (United States); Hahn, John [Cargill, Wayzata, MN (United States); Stover, Daniel [Cargill, Wayzata, MN (United States); Parrish, Martin [Valero, San Antonio, TX (United States); Maxey, Carl [Valero, San Antonio, TX (United States); Shonnard, David [MTU, Friedrichshafen (Germany); Handler, Robert [MTU, Friedrichshafen (Germany); Fan, Jiquig [MTU, Friedrichshafen (Germany)

2015-08-31

Cellulosic and woody biomass can be converted to bio-oils containing less than 10% oxygen by a hydropyrolysis process. Hydropyrolysis is the first step in Gas Technology Institute’s (GTI) integrated Hydropyrolysis and Hydroconversion IH2®. These intermediate bio-oils can then be converted to drop-in hydrocarbon fuels using existing refinery hydrotreating equipment to make hydrocarbon blending components, which are fully compatible with existing fuels. Alternatively, cellulosic or woody biomass can directly be converted into drop-in hydrocarbon fuels containing less than 0.4% oxygen using the IH2 process located adjacent to a refinery or ethanol production facility. Many US oil refineries are actually located near biomass resources and are a logical location for a biomass to transportation fuel conversion process. The goal of this project was to work directly with an oil refinery partner, to determine the most attractive route and location for conversion of biorenewables to drop in fuels in their refinery and ethanol production network. Valero Energy Company, through its subsidiaries, has 12 US oil refineries and 11 ethanol production facilities, making them an ideal partner for this analysis. Valero is also part of a 50- 50 joint venture with Darling Ingredients called Diamond Green Diesel. Diamond Green Diesel’s production capacity is approximately 11,000 barrels per day of renewable diesel. The plant is located adjacent to Valero’s St Charles, Louisiana Refinery and converts recycled animal fats, used cooking oil, and waste corn oil into renewable diesel. This is the largest renewable diesel plant in the U.S. and has successfully operated for over 2 years For this project, 25 liters of hydropyrolysis oil from wood and 25 liters of hydropyrolysis oils from corn stover were produced. The hydropyrolysis oil produced had 4-10% oxygen. Metallurgical testing of hydropyrolysis liquids was completed by Oak Ridge National Laboratories (Oak Ridge) and showed the

Refinery evaluation of optical imaging to locate fugitive emissions.

Science.gov (United States)

Robinson, Donald R; Luke-Boone, Ronke; Aggarwal, Vineet; Harris, Buzz; Anderson, Eric; Ranum, David; Kulp, Thomas J; Armstrong, Karla; Sommers, Ricky; McRae, Thomas G; Ritter, Karin; Siegell, Jeffrey H; Van Pelt, Doug; Smylie, Mike

2007-07-01

Fugitive emissions account for approximately 50% of total hydrocarbon emissions from process plants. Federal and state regulations aiming at controlling these emissions require refineries and petrochemical plants in the United States to implement a Leak Detection and Repair Program (LDAR). The current regulatory work practice, U.S. Environment Protection Agency Method 21, requires designated components to be monitored individually at regular intervals. The annual costs of these LDAR programs in a typical refinery can exceed US$1,000,000. Previous studies have shown that a majority of controllable fugitive emissions come from a very small fraction of components. The Smart LDAR program aims to find cost-effective methods to monitor and reduce emissions from these large leakers. Optical gas imaging has been identified as one such technology that can help achieve this objective. This paper discusses a refinery evaluation of an instrument based on backscatter absorption gas imaging technology. This portable camera allows an operator to scan components more quickly and image gas leaks in real time. During the evaluation, the instrument was able to identify leaking components that were the source of 97% of the total mass emissions from leaks detected. More than 27,000 components were monitored. This was achieved in far less time than it would have taken using Method 21. In addition, the instrument was able to find leaks from components that are not required to be monitored by the current LDAR regulations. The technology principles and the parameters that affect instrument performance are also discussed in the paper.

Yugoslavian Petroleum Refinery development program

International Nuclear Information System (INIS)

Ocic, Ozren

1999-01-01

This paper shows the analysis of the world petroleum industry development, being an important factor in planning the development of the Yugoslav petroleum industry and Pancevo Petroleum Refinery, as well. Then Yugoslav petroleum industry development is analysed, including the appropriate balances of crude oil production and crude oil products consumption. The way of realizing the basic targets are also proposed. Likewise, the analysis of the condition within West European refineries has been conducted, from the aspects of technology, energy consumption and environmental protection and the same analysis for Pancevo Petroleum Refinery has been presented, too. The analysis of the condition within the refineries in the European Union countries and comparing it with the condition within Pancevo Petroleum Refinery, makes it mainly possible to recognize the development programmes which should be realized in order that Pancevo Petroleum Refinery could reach the refining level of the EU countries. (Original)

Planning and scheduling for petroleum refineries using mathematical programming

Directory of Open Access Journals (Sweden)

Joly M.

2002-01-01

Full Text Available The objective of this paper is the development and solution of nonlinear and mixed-integer (MIP optimization models for real-world planning and scheduling problems in petroleum refineries. Firstly, we present a nonlinear planning model that represents a general refinery topology and allows implementation of nonlinear process models as well as blending relations. The optimization model is able to define new operating points, thus increasing the production of the more valuable products and simultaneously satisfying all specification constraints. The second part addresses scheduling problems in oil refineries, which are formulated as MIP optimization models and rely on both continuous and discrete time representations. Three practical applications closely related to the current refinery scenario are presented. The first one addresses the problem of crude oil inventory management of a refinery that receives several types of crude oil delivered exclusively by a single oil pipeline. Subsequently, two optimization models intended to define the optimal production policy, inventory control and distribution are proposed and solved for the fuel oil and asphalt plant. Finally, the planning model of Moro et al. (1998 is extended in order to sequence decisions at the scheduling level in the liquefied petroleum gas (LPG area for maximization of the production of petrochemical-grade propane and product delivery.

Analysis of the overall energy intensity of alumina refinery process using unit process energy intensity and product ratio method

Energy Technology Data Exchange (ETDEWEB)

Liu, Liru; Aye, Lu [International Technologies Center (IDTC), Department of Civil and Environmental Engineering,The University of Melbourne, Vic. 3010 (Australia); Lu, Zhongwu [Institute of Materials and Metallurgy, Northeastern University, Shenyang 110004 (China); Zhang, Peihong [Department of Municipal and Environmental Engineering, Shenyang Architecture University, Shenyang 110168 (China)

2006-07-15

Alumina refinery is an energy intensive industry. Traditional energy saving methods employed have been single-equipment-orientated. Based on two concepts of 'energy carrier' and 'system', this paper presents a method that analyzes the effects of unit process energy intensity (e) and product ratio (p) on overall energy intensity of alumina. The important conclusion drawn from this method is that it is necessary to decrease both the unit process energy intensity and the product ratios in order to decrease the overall energy intensity of alumina, which may be taken as a future policy for energy saving. As a case study, the overall energy intensity of the Chinese Zhenzhou alumina refinery plant with Bayer-sinter combined method between 1995 and 2000 was analyzed. The result shows that the overall energy intensity of alumina in this plant decreased by 7.36 GJ/t-Al{sub 2}O{sub 3} over this period, 49% of total energy saving is due to direct energy saving, and 51% is due to indirect energy saving. The emphasis in this paper is on decreasing product ratios of high-energy consumption unit processes, such as evaporation, slurry sintering, aluminium trihydrate calcining and desilication. Energy savings can be made (1) by increasing the proportion of Bayer and indirect digestion, (2) by increasing the grade of ore by ore dressing or importing some rich gibbsite and (3) by promoting the advancement in technology. (author)

FEASIBILITY STUDY FOR A PETROLEUM REFINERY FOR THE JICARILLA APACHE TRIBE

International Nuclear Information System (INIS)

Jones, John D.

2004-01-01

A feasibility study for a proposed petroleum refinery for the Jicarilla Apache Indian Reservation was performed. The available crude oil production was identified and characterized. There is 6,000 barrels per day of crude oil production available for processing in the proposed refinery. The proposed refinery will utilize a lower temperature, smaller crude fractionation unit. It will have a Naphtha Hydrodesulfurizer and Reformer to produce high octane gasoline. The surplus hydrogen from the reformer will be used in a specialized hydrocracker to convert the heavier crude oil fractions to ultra low sulfur gasoline and diesel fuel products. The proposed refinery will produce gasoline, jet fuel, diesel fuel, and a minimal amount of lube oil. The refinery will require about $86,700,000 to construct. It will have net annual pre-tax profit of about $17,000,000. The estimated return on investment is 20%. The feasibility is positive subject to confirmation of long term crude supply. The study also identified procedures for evaluating processing options as a means for American Indian Tribes and Native American Corporations to maximize the value of their crude oil production

Techno-Economic Evaluation of Technologies to Mitigate Greenhouse Gas Emissions at North American Refineries.

Science.gov (United States)

Motazedi, Kavan; Abella, Jessica P; Bergerson, Joule A

2017-02-07

A petroleum refinery model, Petroleum Refinery Life-cycle Inventory Model (PRELIM), that estimates energy use and CO 2 emissions was modified to evaluate the environmental and economic performance of a set of technologies to reduce CO 2 emissions at refineries. Cogeneration of heat and power (CHP), carbon capture at fluid catalytic cracker (FCC) and steam methane reformer (SMR) units, and alternative hydrogen production technologies were considered in the analysis. The results indicate that a 3-44% reduction in total annual refinery CO 2 emissions (2-24% reductions in the CO 2 emissions on a per barrel of crude oil processed) can be achieved in a medium conversion refinery that processes a typical U.S. crude slate obtained by using the technologies considered. A sensitivity analysis of the quality of input crude to a refinery, refinery configuration, and prices of natural gas and electricity revealed how the magnitude of possible CO 2 emissions reductions and the economic performance of the mitigation technologies can vary under different conditions. The analysis can help inform decision making related to investment decisions and CO 2 emissions policy in the refining sector.

Carbon flow analysis and Carbon emission reduction of FCC in Chinese oil refineries

Science.gov (United States)

Jia, Fengrui; Wei, Na; Ma, Danzhu; Liu, Guangxin; Wu, Ming; Yue, Qiang

2017-08-01

The major problem of the energy production in oil refineries is the high emission of CO2 in China. The fluid catalytic cracking unit (FCC) is the key source of carbon emission in the oil refineries. According to the statistical data, the carbon emission of FCC unit accounts for more than 31% for the typical oil refineries. The carbon flow of FCC in the typical Chinese oil refineries were evaluated and analysed, which aimed at the solution of CO2 emission reduction. The method of substances flow analysis (SFA) and the mathematical programming were used to evaluate the carbon metabolism and optimize the carbon emission. The results indicated that the combustion emission of the reaction-regeneration subsystem (RRS) was the major source of FCC. The quantity of CO2 emission of RSS was more than 90%. The combustion efficiency and the amount of residual oil affected the carbon emission of RRS most according to the optimized analysis of carbon emission reduction. Moreover, the fractionation subsystem (TFS) had the highest environmental efficiency and the absorption-stabilization subsystem (ASS) had the highest resource efficiency (approximately to 1) of carbon.

Detection of impurities in fluid flowing in refinery pipeline or oil production operations using nuclear techniques

International Nuclear Information System (INIS)

Arnold, D.M.; Peelman, H.E.; Langford, O.M.; Paap, H.J.; Sopernaw, I.R.

1977-01-01

Fluid in a pipeline or container at a refinery or at any of various petroleum producing operations is bombarded with neutrons and high energy gamma rays resulting from capture of thermal neutrons are detected. The spectra of the detected gamma rays are then analyzed to determine the concentration of the element chlorine, which gives an indication of the presence and concentration of salt water in the fluid. The concentration of sulfur and the percentage gas in the fluid may be determined simultaneously with the concentration of chlorine. (Auth.)

U.S. Refinery compliance costs - the elements of and estimate

International Nuclear Information System (INIS)

Musgrove, J.G.; Swain, E.J.

1993-01-01

A recent National Petroleum Council study identified the environmental costs facing the refining industry from 1995 through 2010. Four broad areas were identified: air pollution control, wastewater treatment, solid and hazardous waste treatment, and occupational health and safety. This paper will present the technical issues and engineering information required to produce an estimate of cost impact. For each of the four areas of impact, the kinds of information required of the refinery manager in order to build an estimate will be tabulated and discussed. For air pollution control, issues will include size and type of unit, product mix of output, and the impact of facility location relative to non-attainment issues. For wastewater, issues will include stormwater segregation, benzene NESHAP, and other treatment system requirements. For hazardous waste treatment, issues will include groundwater protection and leak detection and contaminated soil segregation. For occupational health and safety, issues will include process changes required and worker training required. For all issues, the major dollar factors will be identified as a function of the technical data available. The refinery costs in each areas were estimated for seven groups of refinery sizes. The presentation will conclude with tabulation of cost estimates for each area of investigation and each refinery group. The total costs for each refinery group over the fifteen-year period will also be presented

The energy efficiency of crude oil refining in Brazil: A Brazilian refinery plant case

International Nuclear Information System (INIS)

Lima, Romulo S. de; Schaeffer, Roberto

2011-01-01

This article evaluates energy efficiency in Brazilian crude oil refining in comparison with the crude oil refining in the United States between 1930 and 2008. It aims to show that increased refinery complexity reduces the energy consumption of products of high value added. Moreover, the article shows that improvements in energy efficiency result in higher quality products and increased processing of oil. A Brazilian refinery with a capacity of 157,000 barrels per day (kbpd) was modernized in 2008 at a cost of US $1.3 billion. As a result, its capacity increased by 17%, from 157 to 189 kbpd. Its complexity index also rose from 3.2 to 6.8, allowing an improvement in the EII (energy intensity index) from 110% to 93%. In relation to the crude oil processed before being modernized, energy consumption fell from 0.75 to 0.52 MBtu (million British thermal units) per barrel processed. These proceedings show that increases in complexity reduce the energy consumed in the production of final products with high value added, such as gasoline, diesel and jet fuel. -- Highlights: → Increased refinery complexity reduces the energy consumption of products of high value added. → Improvements in refinery energy efficiency result in higher quality products and increased processing of oil. → Brazilian refineries were not affected significantly in the 2008 crisis, such as the US refineries, due to many factors. → The EII of Brazilian refining presents real opportunities for gains through changes in the profile of energy consumed.

Benchmarking of refinery emissions performance : Executive summary

International Nuclear Information System (INIS)

2003-07-01

This study was undertaken to collect emissions performance data for Canadian and comparable American refineries. The objective was to examine parameters that affect refinery air emissions performance and develop methods or correlations to normalize emissions performance. Another objective was to correlate and compare the performance of Canadian refineries to comparable American refineries. For the purpose of this study, benchmarking involved the determination of levels of emission performance that are being achieved for generic groups of facilities. A total of 20 facilities were included in the benchmarking analysis, and 74 American refinery emission correlations were developed. The recommended benchmarks, and the application of those correlations for comparison between Canadian and American refinery performance, were discussed. The benchmarks were: sulfur oxides, nitrogen oxides, carbon monoxide, particulate, volatile organic compounds, ammonia and benzene. For each refinery in Canada, benchmark emissions were developed. Several factors can explain differences in Canadian and American refinery emission performance. 4 tabs., 7 figs

Treatment and disposal of refinery sludges: Indian scenario.

Science.gov (United States)

Bhattacharyya, J K; Shekdar, A V

2003-06-01

Crude oil is a major source of energy and feedstock for petrochemicals. Oily sludge, bio-sludge and chemical sludge are the major sludges generated from the processes and effluent treatment plants of the refineries engaged in crude oil refining operations. Refineries in India generate about 28,220 tons of sludge per annum. Various types of pollutants like phenols, heavy metals, etc. are present in the sludges and they are treated as hazardous waste. Oily sludge, which is generated in much higher amount compared to other sludges, contains phenol (90-100 mg/kg), nickel (17-25 mg/kg), chromium (27-80 mg/kg), zinc (7-80 mg/kg), manganese (19-24 mg/kg), cadmium (0.8-2 mg/kg), copper (32-120 mg/kg) and lead (0.001-0.12 mg/ kg). Uncontrolled disposal practices of sludges in India cause degradation of environmental and depreciation of aesthetic quality. Environmental impact due to improper sludge management has also been identified. Salient features of various treatment and disposal practices have been discussed. Findings of a case study undertaken by the authors for Numaligarh Refinery in India have been presented. Various system alternatives have been identified for waste management in Numaligarh Refinery. A ranking exercise has been carried out to evaluate the alternatives and select the appropriate one. A detailed design of the selected waste management system has been presented.

Profitability diagnosis of refinery and improvement proposal; Seiyusho no shueki shindan to kaizen teian

Energy Technology Data Exchange (ETDEWEB)

Aoyama, H.

2000-07-01

Based on consulting service RPS-J under joint operation of Nikki, UOP LLC of U.S.A. and Nikki Universal, approaching ways applied for profitability improvement and improvement proposal for refineries and analyzing techniques used for resolution of process bottlenecks were described. In RPS-J, themes of (1) energy saving, (2) quality upgrading, (3) improvement of disintegrating ratio, (4) reduction of give-away, (5) improvement of equipment operation ratio, (6) reduction of maintenance cost, (7) effective utilization of catalysts, are considered for profitability improvement fields. Procedures from idea excavation for profitability improvement to realization of profitability improvement are carried out in the order of, (1) Grasping of the present state, (2) Excavation of improving items and selection, (3) Quantitative evaluation of draft profitability improvement plan and focusing, (4) Profitability improvement by operation improvement, (5) Profitability improvement by minor improvement, (6) Profitability improvement in middle- and long-term vision, (7) Final focusing by feasibility study. Afterwards, examination to economically solve bottlenecks of critical facilities, examination on bottlenecks of distillation tower and refining tower and utility analysis are carried out. RPS-J was already applied to 4 refineries including Muroran Refinery and Negishi Refinery of Nisseki Mitsubishi, and profitability improvement themes were found to improve profitability of 50 to 150 cents per barrel. (NEDO)

Occupational health experience with a contractor uranium refinery

International Nuclear Information System (INIS)

Heatherton, R.C.

1975-01-01

This paper presents information related to the occupational exposure of workers in uranium refinery operations at the Feed Materials Production Center since 1958. Included are: a brief history of the FMPC; a description of the operations and the principal sources of exposure; airborne uranium, urinary excretion, in vivo monitoring and tissue analysis data; and some observations regarding the exposure and health status of employees

Large scale and long term application of bioslurping: the case of a Greek petroleum refinery site.

Science.gov (United States)

Gidarakos, E; Aivalioti, M

2007-11-19

This paper presents the course and the remediation results of a 4-year application of bioslurping technology on the subsurface of a Greek petroleum refinery, which is still under full operation and has important and complicated subsurface contamination problems, mainly due to the presence of light non-aqueous phase liquids (LNAPL). About 55 wells are connected to the central bioslurping unit, while a mobile bioslurping unit is also used whenever and wherever is necessary. Moreover, there are about 120 additional wells for the monitoring of the subsurface of the facilities that cover a total area of 1,000,000 m(2). An integrated monitoring program has also been developed and applied on the site, including frequent LNAPL layer depth and thickness measurements, conduction of bail-down and recovery tests, sampling and chemical analysis of the free oil phase, etc., so as to evaluate the remediation technique's efficiency and ensure a prompt tracing of any new potential leak. Despite the occurrence of new leaks within the last 4 years and the observed entrapment of LNAPL in the vadoze zone, bioslurping has managed to greatly restrict the original plume within certain and relatively small parts of the refinery facilities.

Allocating the CO2 emissions of an oil refinery with Aumann-Shapley prices

International Nuclear Information System (INIS)

Pierru, A.

2005-06-01

Linear programming is widely used by multi-product oil-refining firms, which minimize a refinery's variable cost under a set of constraints. In addition to operating costs, this variable cost can include the cost associated with the refinery's CO 2 emissions. We suggest a quite general approach combining use of Aumann-Shapley cost-sharing method and breakdown of the objective function of the linear program. This approach determines an appropriate rule for the allocation of the refinery's CO 2 emissions (or, in general, variable costs) among the various finished products, which can be used for purposes of Life Cycle Assessment. A numerical application to a simplified refining model is presented. (author)

Pemex to acquire interest in Shell Texas refinery

International Nuclear Information System (INIS)

Anon.

1992-01-01

This paper reports that Petroleos Mexicanos and Shell Oil Co. have signed a memorandum of understanding to form a joint refining venture involving Shell's 225,000 b/d Deer Park, Tex., refinery. Under the agreement, Mexico's state owned oil company is to purchase a 50% interest in the refinery, and Shell is to sell Pemex unleaded gasoline on a long term basis. Under the venture, Shell and Pemex plan to add undisclosed conversion and upgrading units tailored to process heavy Mexican crude. The revamp will allow Pemex to place more than 100,000 b/d of Mayan heavy crude on the U.S. market. Mayan accounts for 70% of Mexico's crude oil exports. In turn, Shell will sell Pemex as much as 45,000 b/d of unleaded gasoline to help meet Mexico's rapidly growing demand

Hydrogen management in the MiRO refinery

Energy Technology Data Exchange (ETDEWEB)

Neumann, G. [Mineraloelraffinerie Oberrhein GmbH und Co. KG, Karlsruhe (Germany)

2010-12-30

The importance of hydrogen in refineries has increased over the last 20 years as new regulations affecting gasoline and diesel composition have been implemented throughout Europe and in an environment of increasingly stringent clean fuel regulations, decreasing heavy fuel oil demand and increasing heavy more sour crude supply. In Germany, the introduction of sulphur free gasoline and diesel with less than 10ppm sulphur(Auto Oil Program) and light home fuel oil with less than 50ppm this year were the last link in a long chain of environmental regulations, which had a considerable effect on the hydrogen demand in refineries. In the complex MiRO-refinery with a large FCC- and Coker-Unit for atmospheric residue conversion and a total throughput of more than 15 Mio.T/ a and more than 14 Mio.T/a crude oils of different origin from high sulphur, bituminous crudes to medium, low sulphur crudes for calcinate-production from green coke the only source of hydrogen for a long time was catalytic reforming. The only chance of balancing the hydrogen production and consumption was to improve the existing catalytic reforming and the optimisation of hydrogen recovery from waste or purge streams and the hydrogen network of the refinery. In 2007 a new hydrogen plant via steam reforming of natural gas went on stream. The main reason for this step was the shrinking market for gasoline in the last ten years and the blending of bio-ethanol into the gasoline pool, which released reforming capacities and the demand for octane. Another important issue is the production planning taking into account the potentials of hydrogen production via catalytic and steam reforming and the hydrogen consumption via desulphurisation and the saturation of olefins and (poly-)aromatics of the main product streams, gasoline, diesel and light home fuel oil. (orig.)

The rise and fall of refineries

International Nuclear Information System (INIS)

Chretien, D.

2002-01-01

This paper described the rise and fall of refineries in Montreal. Well before Calgary, Montreal was the hub of activity for oil refineries because Montreal was the principle consuming market for petroleum products in Canada. The location was good, particularly since the soil was clay which helped prevent soil infiltration of petroleum. The first refinery in Montreal was constructed in 1916 by Esso, followed by Texaco in 1921 and Gulf in 1931. Initially oil was shipped by boat to the Port of Montreal from Saudi Arabia. Later, the petroleum came mostly from Venezuela. At the beginning of the 1980s many refineries were closed because they became obsolete and upgrading them would have been too costly. Only 3 refineries remain in Quebec, of which 2 are in Montreal. They are owned by Shell and PetroCanada. The third refinery in Quebec is in St-Romuald and is owned by UltraMar. One of the major contributing factors to the decline of the refining industry in Montreal was the decision in 1984 by former Prime Minister Trudeau to force Canadian provinces to purchase their petroleum from Alberta. This caused the petrochemical industry to locate in Sarnia in Ontario, leaving the Montreal refining centre to become obsolete. 3 figs

Monitoring coastal pollution associated with the largest oil refinery complex of Venezuela

Directory of Open Access Journals (Sweden)

Aldo Croquer

2016-06-01

Full Text Available This study evaluated pollution levels in water and sediments of Península de Paraguaná and related these levels with benthic macrofauna along a coastal area where the largest Venezuelan oil refineries have operated over the past 60 years. For this, the concentration of heavy metals, of hydrocarbon compounds and the community structure of the macrobenthos were examined at 20 sites distributed along 40 km of coastline for six consecutive years, which included windy and calm seasons. The spatial variability of organic and inorganic compounds showed considerably high coastal pollution along the study area, across both years and seasons. The southern sites, closest to the refineries, had consistently higher concentrations of heavy metals and organic compounds in water and sediments when compared to those in the north. The benthic community was dominated by polychaetes at all sites, seasons and years, and their abundance and distribution were significantly correlated with physical and chemical characteristics of the sediments. Sites close to the oil refineries were consistently dominated by families known to tolerate xenobiotics, such as Capitellidae and Spionidae. The results from this study highlight the importance of continuing long-term environmental monitoring programs to assess the impact of effluent discharge and spill events from the oil refineries that operate in the western coast of Paraguaná, Venezuela.

Multi-media pollution prevention: A case study of a refinery

International Nuclear Information System (INIS)

Schmitt, R.E.; Podar, M.K.

1994-01-01

In late 1989, Amoco Corporation and the United States Environmental Protection Agency began a voluntary, joint project to study pollution prevention opportunities at an industrial facility. Amoco proposed use of its refinery at Yorktown, Virginia, to conduct a multi-media assessment of releases to the environment, then to develop and evaluate options to reduce these releases. A Workgroup composed of state, federal, and Amoco representatives provided oversight to the Project. Monthly Workgroup meetings provided Project oversight, a forum for presentations on different Project components, and an opportunity for informal discussion of different viewpoints about environmental management. The Workgroup identified four objectives for this study: (1) Inventory refinery releases to the environment to define their chemical type, quantity, source, and medium of release; (2) develop options to reduce selected releases identified, as well as rank and prioritize the options based on a variety of criteria and perspectives; (3) identify and evaluate factors as technical, legislative, regulatory, institutional, permitting, and economic, that impede or encourage pollution prevention; and (4) enhance participates' knowledge of refinery and regulatory systems

Well-to-Wheels Greenhouse Gas Emission Analysis of High-Octane Fuels with Ethanol Blending: Phase II Analysis with Refinery Investment Options

Energy Technology Data Exchange (ETDEWEB)

Han, Jeongwoo [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division; Wang, Michael [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division; Elgowainy, Amgad [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division; DiVita, Vincent [Jacobs Consultancy Inc., Houston, TX (United States)

2016-08-01

Higher-octane gasoline can enable increases in an internal combustion engine’s energy efficiency and a vehicle’s fuel economy by allowing an increase in the engine compression ratio and/or by enabling downspeeding and downsizing. Producing high-octane fuel (HOF) with the current level of ethanol blending (E10) could increase the energy and greenhouse gas (GHG) emissions intensity of the fuel product from refinery operations. Alternatively, increasing the ethanol blending level in final gasoline products could be a promising solution to HOF production because of the high octane rating and potentially low blended Reid vapor pressure (RVP) of ethanol at 25% and higher of the ethanol blending level by volume. In our previous HOF well-to-wheels (WTW) report (the so-called phase I report of the HOF WTW analysis), we conducted WTW analysis of HOF with different ethanol blending levels (i.e., E10, E25, and E40) and a range of vehicle efficiency gains with detailed petroleum refinery linear programming (LP) modeling by Jacobs Consultancy and showed that the overall WTW GHG emission changes associated with HOFVs were dominated by the positive impact associated with vehicle efficiency gains and ethanol blending levels, while the refining operations to produce gasoline blendstock for oxygenate blending (BOB) for various HOF blend levels had a much smaller impact on WTW GHG emissions (Han et al. 2015). The scope of the previous phase I study, however, was limited to evaluating PADDs 2 and 3 operation changes with various HOF market share scenarios and ethanol blending levels. Also, the study used three typical configuration models of refineries (cracking, light coking, and heavy coking) in each PADD, which may not be representative of the aggregate response of all refineries in each PADD to various ethanol blending levels and HOF market scenarios. Lastly, the phase I study assumed no new refinery expansion in the existing refineries, which limited E10 HOF production to the

Application of PIMS Software in Monthly Planning of Refinery Production

Institute of Scientific and Technical Information of China (English)

无

2005-01-01

This article describes the application of the PIMS software in formulating monthly refining production plan. Application of the PIMS software can help to solve a series of problems related with monthly plan of refining production such as optimized selection of crude and feedstocks, optimized selection of production scale and processing scheme, identification of bottlenecks and their mitigation,optimized selection of turnaround time and optimized selection of operating regime, which have increased the economic benefits of refining enterprises. With the further development and improvement of models the PIMS software will play an increasingly important role in formulating monthly plans of refining operations and production management at refineries. This article also explores the problems existing in refinery monthly planning, and has made recommendations on developing and improving models and reporting system, enhancement of basic data acquisition, model maintenance personnel and staff training.

Hydroprocessing and premium II refinery: a new refining philosophy for an era of clean fuels

Energy Technology Data Exchange (ETDEWEB)

Delgaudio, Caio Veiga Penna; Pinotti, Rafael [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)

2012-07-01

This paper discusses a brief history of Brazilian's emission and fuel specifications, since the appearance of PROCONVE until the late stages of the program for vehicles powered by gasoline and diesel. The development of the Brazilian refining is analyzed taking into account the emission and specification evolutions, and it can be perceived that the system's complexity increases while new constraints are imposed by the regulator. This aspect is even more apparent when the detailed scheme of the Premium II refinery and its main unit, the catalytic hydrocracker (HCC, which has not yet been part of PETROBRAS' refining park and will appear in three of the four new refineries of the company) is described. The new projects represent the culmination of the intensive use of energy and raw material for obtaining the products with the new specifications. There is a price for this development, both in investments and increased operating costs due to greater complexity of the system. To adapt to the era of clean fuels, refiners will present a series of challenges that will lead them to seek for more efficient processes and operational excellence (and ongoing efforts to reduce their emissions) in order to ensure positive refining margins. (author)

[Occupational accidents in an oil refinery in Brazil].

Science.gov (United States)

Souza, Carlos Augusto Vaz de; Freitas, Carlos Machado de

2002-10-01

Work in oil refineries involves the risk of minor to major accidents. National data show the impact of accidents on this industry. A study was carried out to describe accident profile and evaluate the adequacy of accident reporting system. Data on all accidents reported in an oil refinery in the state of Rio de Janeiro for the year 1997 were organized and analyzed. The study population consisted of 153 injury cases, 83 hired and 69 contracted workers. The variables were: type of accident, operation mode and position of the worker injured. Among hired workers, minor accidents predominated (54.2%) and they occurred during regular operation activities (62.9%). Among contracted workers, there also predominated minor accidents (75.5%) in a higher percentage, but they occurred mainly during maintenance activities (96.8%). The study results showed that there is a predominance of accidents in lower hierarchy workers, and these accidents occur mainly during maintenance activities. There is a need to improve the company's accident reporting system and accident investigation procedures.

Radioisotope techniques for problem-solving on refineries

International Nuclear Information System (INIS)

Charlton, J.S.; Webb, M.

1994-01-01

Increasingly, refineries worldwide are recognizing the value of radioisotope technology in studying the operation of on-line plant. Using case studies, this paper illustrates the versatility of radioisotope techniques in a wide range of investigations: the density-profiling of distillation columns; the investigation of leaks on feed/effluent exchangers; on-line flowrate measurement; underground leakage detection. The economic benefits deriving from radioisotope applications are indicated

A Steam Utility Network Model for the Evaluation of Heat Integration Retrofits – A Case Study of an Oil Refinery

Directory of Open Access Journals (Sweden)

Sofie Marton

2017-12-01

Full Text Available This paper presents a real industrial example in which the steam utility network of a refinery is modelled in order to evaluate potential Heat Integration retrofits proposed for the site. A refinery, typically, has flexibility to optimize the operating strategy for the steam system depending on the operation of the main processes. This paper presents a few examples of Heat Integration retrofit measures from a case study of a large oil refinery. In order to evaluate expected changes in fuel and electricity imports to the refinery after implementation of the proposed retrofits, a steam system model has been developed. The steam system model has been tested and validated with steady state data from three different operating scenarios and can be used to evaluate how changes to steam balances at different pressure levels would affect overall steam balances, generation of shaft power in turbines, and the consumption of fuel gas.

Assessment and control design for steam vent noise in an oil refinery.

Science.gov (United States)

Monazzam, Mohammad Reza; Golmohammadi, Rostam; Nourollahi, Maryam; Momen Bellah Fard, Samaneh

2011-06-13

Noise is one of the most important harmful agents in work environment. Noise pollution in oil refinery industries is related to workers' health. This study aimed to determine the overall noise pollution of an oil refinery operation and its frequency analysis to determine the control plan for a vent noise in these industries. This experimental study performed in control unit of Tehran Oil Refinery in 2008. To determine the noise distributions, environmental noise measurements were carried out by lattice method according to basic information and technical process. The sound pressure level and frequency distribution was measured for each study sources subject separately was performed individually. According to the vent's specification, the measured steam noise characteristics reviewed and compared to the theoretical results of steam noise estimation. Eventually, a double expansion muffler was designed. Data analysis and graphical design were carried out using Excel software. The results of environmental noise measurements indicated that the level of sound pressure was above the national permitted level (85 dB (A)). The Mean level of sound pressure of the studied steam jet was 90.3 dB (L). The results of noise frequency analysis for the steam vents showed that the dominant frequency was 4000 Hz. To obtain 17 dB noise reductions, a double chamber aluminum muffler with 500 mm length and 200 mm diameter consisting pipe drilled was designed. The characteristics of steam vent noise were separated from other sources, a double expansion muffler was designed using a new method based on the level of steam noise, and principle sound frequency, a double expansion muffler was designed.

Analysis and control of odors from petroleum refineries

International Nuclear Information System (INIS)

O'Brien, M.A.; Duffee, R.A.; Ostojic, N.

1992-01-01

This paper presents a proven approach used to effectively solve odor problems associated with atmospheric emissions from petroleum refineries. A systematic evaluation is first conducted to identify all emissions with the potential for off-site odor impacts. Sampling is then conducted and dynamic dilution olfactometry is used to quantify the odor emission rates of each source. Community odor surveys are performed simultaneously with the source sampling to quantitatively document the downwind odor impacts. Atmospheric dispersion modeling specifically designed for odor is then used to predict instantaneous odor occurrences at various receptor sites under meteorological conditions not actually encountered during the field study. The findings make it possible to rank sources by their odor emission rates and potential for odor impacts in the community. It is then possible to determine how much odor reduction is required to bring the present odor impacts of the individual sources to an acceptable level under worst-case meteorological conditions. Once the degree of control required is determined, control alternatives are selected and evaluated. Case histories have been selected to illustrate the application of this approach at petroleum refineries. They provide descriptions of odor assessment and abatement studies conducted specifically for refinery effluent treatment plant sources as well as process unit emission sources. The sources identified as needing control and the odor abatement measures taken are discussed

The regulation of uranium refineries and conversion facilities in Canada

International Nuclear Information System (INIS)

Didyk, J.P.

1986-04-01

The nuclear regulatory process as it applies to uranium refineries and conversion facilities in Canada is reviewed. In the early 1980s, Eldorado Resources Limited proposed to construct and operate new facilities for refining yellowcake and for the production of uranium hexafluoride (UF 6 ). These projects were subject to regulation by the Atomic Energy Control Board (AECB). A description of the AECB's comprehensive licensing process covering all stages of siting, construction, operation and eventual decommissioning of nuclear facilities is traced as it was applied to the Eldorado projects. The AECB's concern with occupational health and safety, with public health and safety and with the protection of the environment in so far as it affects public health and safety is emphasized. Some regulatory difficulties encountered during the project's development which led to opening up the licensing process to public input and closer coordination of regulatory activities with other provincial and federal regulatory agencies are described. The Board's regulatory operational compliance program for uranium refineries and conversion facilities is summarized

Feasibility study on energy saving and reduction of CO2 emissions at Pertamina's Cilacap Refinery

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

With an objective of saving energy and reducing greenhouse gas emission, a basic survey has been performed on the atmospheric crude oil distillation units and the high vacuum distillation units at Cilacap Refinery in Indonesia. The first site survey in September 2000 has carried out a survey on the situation of the facilities and operation upon obtaining the facility data and operation information from Pertamina. As a result, it was revealed that there is a room of improvement in the heat recovery, whereas a modification design was executed on the improvement proposals on the heat exchanger system. However, the second site survey in November 2000 has revealed that Pertamina had executed in 1998 through 1999 the de-bottlenecking project on the crude oil atmospheric distillation units (two units) and the high vacuum distillation units (two units), by which the capability has been expanded, and the heat recovery rate has been increased. It is not possible to look for extremely large enhancement of the heat recovery rate beyond that point, and the reduction of CO2 emission would also be small. As a result of discussions, the present project was found capable of reducing annually the CO2 emission by 36,500 tons. (NEDO)

Opportunities for Biorenewables in Oil Refineries

Energy Technology Data Exchange (ETDEWEB)

Marker, T.L.

2005-12-19

Abstract: The purpose of this study was to evaluate the potential for using biorenewable feedstocks in oil refineries. Economic analyses were conducted, with support from process modeling and proof of principle experiments, to assess a variety of potential processes and configurations. The study considered two primary alternatives: the production of biodiesel and green diesel from vegetable oils and greases and opportunities for utilization of pyrolysis oil. The study identified a number of promising opportunities for biorenewables in existing or new refining operations.

ENHANCEMENT OF PHENOL REMOVAL EFFICIENCY IN DORA REFINERY WASTEWATER TREATMENT PLANT

Directory of Open Access Journals (Sweden)

Salah F. Sharif

2013-05-01

Full Text Available Because the sanctions imposed on Iraq by the United Nations, programmed maintenance and wearing parts replacement has not been performed according to schedules in DORA Refinery Wastewater Unit, which resulted in higher phenol content and BOD5 in effluents disposed to river. The investigations showed that two main reasons were behind this problem: Firstly, increased emissions of hydrocarbons in the complexity of refinery equipment and Secondly, the decreased efficiency of the aerators in the biological. During the last few months, phenol average concentration in the effluent, after biological treatment was found to be between 0.06-0.13 mg/L, while COD was exceeding 110 mg/L after treatment in the same period. Considerable enhancement, has been indicated recently, after the following performances: First: Recycling wastewater from some heat exchangers, and the segregation of low and high strength of wastewaters, Second: Minimizing emissions of hydrocarbons from fluid catalytic cracking and steam cracking, Third: Replacement of driving motors of the aerators in the biological treatment unit. After replacement of these units, a significant decrease in phenol concentration was obtained in purified water (0.03-0.05 mg/L and COD of 60 mg/L before the tertiary treatment. It is concluded that a better quality of effluents has been obtained after a series of emissions control and wastewater treatment unit equipment maintenance performances.

40 CFR 80.94 - Requirements for gasoline produced at foreign refineries.

Science.gov (United States)

2010-07-01

... inspection or audit if a baseline petition has not been approved, and any work papers related to refinery... foreign refineries. 80.94 Section 80.94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... for gasoline produced at foreign refineries. (a) Definitions. (1) A foreign refinery is a refinery...

Eldorado Port Hope refinery - uranium production (1933-1951)

International Nuclear Information System (INIS)

Arsenault, J.E.

2008-01-01

Since the discovery of pitchblende in 1930 by Gilbert LaBine at Great Bear Lake (GBL), North West Territories, uranium has played a central role in the growth of the Canadian mining sector and it in turn has propelled the country into it's present position as the world's top uranium producer. The rich ore mined there was used originally by Eldorado Gold Mines Limited to build a business based on the extraction of radium, which was selling at $70,000 a gram at the time, and silver which was present in the ore in commercial amounts. The mine site on GBL became known as Port Radium. In 1933 Eldorado brought a refinery on-line at Port Hope, Ontario nearly 4,000 miles away from the mine, and began to produce radium, silver and uranium products. Initially uranium played a minor role in the business and the products were sold into the ceramics industry to manufacture a variety of crockery with long-lasting colours. In addition, there were sales and loans of uranium products to research laboratories that were exploring nuclear energy for possible use in weapons and power generation, as the potential for this was clearly understood from 1939 onwards. These laboratories included the National Research Council (George Laurence), Columbia University (Enrico Fermi) and International Chemical Industries (J.P. Baxter). With the beginning of World War II the radium business suffered from poor sales and by 1940 the mine was closed but the refinery continued operation, using accumulated stockpiles. By 1942 uranium had become a strategic material, the mine was reopened, and the refinery began to produce large quantities of uranium oxide destined for The Manhattan Project. As events unfolded Eldorado was unable to produce sufficient ore from GBL so that a large quantity of ore from the Belgian Congo was also processed at Port Hope. Ultimately, as a result of the efforts of this enterprise, World War II was finally ended by use of atomic weapons. After World War II the refinery

Eldorado Port Hope refinery - uranium production (1933-1951)

Energy Technology Data Exchange (ETDEWEB)

Arsenault, J.E

2008-03-15

Since the discovery of pitchblende in 1930 by Gilbert LaBine at Great Bear Lake (GBL), North West Territories, uranium has played a central role in the growth of the Canadian mining sector and it in turn has propelled the country into it's present position as the world's top uranium producer. The rich ore mined there was used originally by Eldorado Gold Mines Limited to build a business based on the extraction of radium, which was selling at $70,000 a gram at the time, and silver which was present in the ore in commercial amounts. The mine site on GBL became known as Port Radium. In 1933 Eldorado brought a refinery on-line at Port Hope, Ontario nearly 4,000 miles away from the mine, and began to produce radium, silver and uranium products. Initially uranium played a minor role in the business and the products were sold into the ceramics industry to manufacture a variety of crockery with long-lasting colours. In addition, there were sales and loans of uranium products to research laboratories that were exploring nuclear energy for possible use in weapons and power generation, as the potential for this was clearly understood from 1939 onwards. These laboratories included the National Research Council (George Laurence), Columbia University (Enrico Fermi) and International Chemical Industries (J.P. Baxter). With the beginning of World War II the radium business suffered from poor sales and by 1940 the mine was closed but the refinery continued operation, using accumulated stockpiles. By 1942 uranium had become a strategic material, the mine was reopened, and the refinery began to produce large quantities of uranium oxide destined for The Manhattan Project. As events unfolded Eldorado was unable to produce sufficient ore from GBL so that a large quantity of ore from the Belgian Congo was also processed at Port Hope. Ultimately, as a result of the efforts of this enterprise, World War II was finally ended by use of atomic weapons. After World War II the

An investigation of the air dispersion characteristics of refinery land treatment units

International Nuclear Information System (INIS)

Brewer, K.R.; Zaizhong Wang; Lupo, M.J.

1991-01-01

Numerical simulations of air emission and dispersion of volatile organic waste constituents from the land treatment units (LTU's) of four refineries were performed using the ISCST model. Particular attention was given to benzene. In order to realistically model the area pollutant source, each LTU had to be subdivided into smaller cells and the cell concentrations summed. The emission rate of the waste from the LTU's, one of the key inputs to the dispersion model, was periodically adjusted to reflect the rapid decay in rate following waste application. Meteorological conditions were found to be significant in determining boundary concentrations. The specific meteorological conditions most favorable for dispersion were investigated. The results of these simulations showed that mixing height is only minimally important in the dispersion of wastes from LTU's as currently regulated by EPA. Wind speed and variation of wind direction were both more important in atmospheric mixing of the volatile waste. It was found that care should be exercised in attempting to correlate any single meteorological parameter with favorable periods for land treatment. In comparisons of the cases, the results suggest that differences in LTU geometry may also be important in the modeling of long-term pollutant concentrations. Model simulations were performed to ascertain the impact of LTU geometry on boundary concentration

The miraculously saved refineries

International Nuclear Information System (INIS)

Cosnard, D.

2005-01-01

During 20 years, refining has been the weak link of the petroleum industry. This sector has always suffered from a chronical overcapacity. Today, on the contrary, there is a lack of facilities and shortage is threatening. The Reichstett refinery (Alsace, France) is the smallest French refinery. It has been several times threatened with closure but today, thanks to the increasing demand, it works at full capacity. This short paper summarizes the history of this facility and its social and environmental impact in the region. (J.S.)

Refinery expansion and upgrading: Trends and needs

International Nuclear Information System (INIS)

Sloan, D.E.

1993-01-01

Much of the world's reserves of heavy, high sulfur crude oil are located in the western hemisphere. One may look from north to south and find these types of crudes. in Canada, there are the vast deposits of tar sands and other heavy oils. In the United States we find heavy, high sulfur crude in California's San joaquin Valley, the Rockies' shale oil deposits and in other areas. Moving south, Mexico's Maya crude is well known to refiners, as are the heavy crudes of Venezuela's Orinoco Belt. On the other hand, many refineries outside the United States are limited in their ability to handle heavy, high sulfur crudes either because of metallurgy or processing configurations

Impact of Energy Production on Respiratory Outcomes: Evidence from the Flandres Refinery in France

International Nuclear Information System (INIS)

Lavaine, Emmanuelle

2016-01-01

This article examines the impact of sulphur dioxide (SO_2) concentration on respiratory admissions in the north of France at municipal level from 2007 to 2011. The Flandres refinery closure in the north of France, in September 2009, is used as a natural experiment. First, this study shows that the halt in the refinery's operations, followed by its closure in 2010, reduces SO_2 concentration. We then use this exogenous shock to analyse the health impact of the high SO_2 concentration generated by energy production. Our estimates highlight that the reduction in SO_2 concentration has significantly reduced the severity of respiratory outcomes. Additionally, the refinery closure has had statistically significant effects on the revenue of municipalities in the area

Production of advanced biofuels: co-processing of upgraded pyrolysis oil in standard refinery units

NARCIS (Netherlands)

De Miguel Mercader, F.; de Miguel Mercader, F.; Groeneveld, M.J.; Hogendoorn, Kees; Kersten, Sascha R.A.; Way, N.W.J.; Schaverien, C.J.

2010-01-01

One of the possible process options for the production of advanced biofuels is the co-processing of upgraded pyrolysis oil in standard refineries. The applicability of hydrodeoxygenation (HDO) was studied as a pyrolysis oil upgrading step to allow FCC co-processing. Different HDO reaction end

Capital vs. service contract at Conoco Humber Refinery

International Nuclear Information System (INIS)

Threlfall, Peter; Sperring, Simon

1999-01-01

The value of outsourcing for water treatment is illustrated through experience at the Conoco Humber refinery. A point was reached where the quality of water at the plant was so poor that demineralized water was brought to the site by tanker. The paper describes how and why it was decided to design, build, operate and maintain an outsourced system. It points out how the newer technologies can be environmentally friendly and, at the same time, reduce operating and maintenance costs, optimise manpower and cut management costs. (UK)

Biodegradation of oil refinery wastes under OPA and CERCLA

International Nuclear Information System (INIS)

Banipal, B.S.; Myers, J.M.; Fisher, C.W.

1995-01-01

Land treatment of oil refinery wastes has been used as a disposal method for decades. More recently, numerous laboratory studies have been performed attempting to quantify degradation rates of more toxic polycyclic aromatic hydrocarbon compounds (PAHs). This paper discusses the results of the full-scale aerobic biodegradation operations using land treatment at the Macmillan Ring-Free Oil refining facility. The tiered feasibility approach in the evaluation of using biodegradation as a treatment method to achieve site-specific clean-up including pilot scale biodegradation operations is included in an earlier paper. Analytical results of biodegradation indicate that degradation rates observed in the laboratory can be met and exceeded under field conditions and that the site-specific cleanup criteria can be attained within a proposed project time. Also presented are degradation rates and half-lives for PAHs for which cleanup criteria has been established. PAH degradation rates and half-life values are determined and compared with the laboratory degradation rates and half-life values which used similar oil refinery wastes by other investigators (API 1987)

Biodegradation of oil refinery wastes under OPA and CERCLA

Energy Technology Data Exchange (ETDEWEB)

Gamblin, W.W.; Banipal, B.S.; Myers, J.M. [Ecology and Environment, Inc., Dallas, TX (United States)] [and others

1995-12-31

Land treatment of oil refinery wastes has been used as a disposal method for decades. More recently, numerous laboratory studies have been performed attempting to quantify degradation rates of more toxic polycyclic aromatic hydrocarbon compounds (PAHs). This paper discusses the results of the fullscale aerobic biodegradation operations using land treatment at the Macmillan Ring-Free Oil refining facility. The tiered feasibility approach of evaluating biodegradation as a treatment method to achieve site-specific cleanup criteria, including pilot biodegradation operations, is discussed in an earlier paper. Analytical results of biodegradation indicate that degradation rates observed in the laboratory can be met and exceeded under field conditions and that site-specific cleanup criteria can be attained within a proposed project time. Also prevented are degradation rates and half-lives for PAHs for which cleanup criteria have been established. PAH degradation rates and half-life values are determined and compared with the laboratory degradation rates and half-life values which used similar oil refinery wastes by other in investigators (API 1987).

Former Soviet refineries face modernization, restructuring

International Nuclear Information System (INIS)

Anon.

1993-01-01

A massive modernization and restructuring program is under way in the refining sector of Russia and other former Soviet republics. Economic reforms and resulting economic dislocation following the collapse of the Soviet Union has left refineries in the region grappling with a steep decline and changes in product demand. At the same time, rising oil prices and an aging, dilapidated infrastructure promise a massive shakeout. Even as many refineries in the former Soviet Union (FSU) face possible closure because they are running at a fraction of capacity, a host of revamps, expansions, and grass roots refineries are planned or under way. The paper discusses plans

High temperature degradation in power plants and refineries

Directory of Open Access Journals (Sweden)

Furtado Heloisa Cunha

2004-01-01

Full Text Available Thermal power plants and refineries around the world share many of the same problems, namely aging equipment, high costs of replacement, and the need to produce more efficiently while being increasingly concerned with issues of safety and reliability. For equipment operating at high temperature, there are many different mechanisms of degradation, some of which interact, and the rate of accumulation of damage is not simple to predict. The paper discusses the mechanisms of degradation at high temperature and methods of assessment of such damage and of the remaining safe life for operation.

Energy saving in refineries and petrochemical complexes

Energy Technology Data Exchange (ETDEWEB)

Verde, L

1975-01-01

Possible measures applicable in the design of refineries and petrochemical complexes, to effect energy savings were investigated. This was not limited to the single process unit problems, on the contrary the attention is mainly addressed to the identification of the interrelations between different units, emphasizing possible integrations. Particularly, the optimization of the pressure levels and number of the utility networks for steam distribution inside plant facilities, is considered, in order to maximize heat recovery in the process units, and electric power production in the central steampower generation plant. A computer program of general application, based on profitability evaluation at various fuel oil prices and different project configurations, has been developed for these purposes. The general measures applicable within certain limits are then briefly examined. The task of the process engineer is discussed in the perspective of the ''energy saving'' goal.

Co-processing potential of HTL bio-crude at petroleum refineries

DEFF Research Database (Denmark)

Jensen, Claus Uhrenholt; Hoffmann, Jessica; Rosendahl, Lasse Aistrup

2016-01-01

An experimental study on hydrotreatment of ligno-cellulosic hydrothermal liquefaction (HTL) bio-crude to achieve a bio-feed compatible for co-processing at a refinery was made to investigate the effect of operating temperature, pressure and hydrogen to oil ratio. Using a conventional NiMo/Al2O3 h...

ASSESSMENT OF CO2 EMISSION MITIGATION FOR A BRAZILIAN OIL REFINERY

Directory of Open Access Journals (Sweden)

W. N. Chan

Full Text Available Abstract Currently the oil refining sector is responsible for approximately 5% of the total Brazilian energy related CO2 emissions. Possibilities to reduce CO2 emissions and related costs at the largest Brazilian refinery have been estimated. The abatement costs related to energy saving options are negative, meaning that feasibility exists without specific income due to emission reductions. The assessment shows that short-term mitigation options, i.e., fuel substitution and energy efficiency measures, could reduce CO2 emissions by 6% of the total current refinery emissions. It is further shown that carbon capture and storage offers the greatest potential for more significant emission reductions in the longer term (up to 43%, but costs in the range of 64 to162 US$/t CO2, depending on the CO2 emission source (regenerators of FCC units or hydrogen production units and the CO2 capture technology considered (oxyfuel combustion or post-combustion. Effects of uncertainties in key parameters on abatement costs are also evaluated via sensitivity analysis.

Discrete event simulation for petroleum transfers involving harbors, refineries and pipelines

Energy Technology Data Exchange (ETDEWEB)

Martins, Marcella S.R.; Lueders, Ricardo; Delgado, Myriam R.B.S. [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil)

2009-07-01

Nowadays a great effort has been spent by companies to improve their logistics in terms of programming of events that affect production and distribution of products. In this case, simulation can be a valuable tool for evaluating different behaviors. The objective of this work is to build a discrete event simulation model for scheduling of operational activities in complexes containing one harbor and two refineries interconnected by a pipeline infrastructure. The model was developed in Arena package, based on three sub-models that control pier allocation, loading of tanks, and transfers to refineries through pipelines. Preliminary results obtained for a given control policy, show that profit can be calculated by taking into account many parameters such as oil costs on ships, pier using, over-stay of ships and interface costs. Such problem has already been considered in the literature but using different strategies. All these factors should be considered in a real-world operation where decision making tools are necessary to obtain high returns. (author)

Feasibility study on energy saving and reduction of CO2 emissions at Pertamina's Cilacap Refinery

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

With an objective of saving energy and reducing greenhouse gas emission, a basic survey has been performed on the atmospheric crude oil distillation units and the high vacuum distillation units at Cilacap Refinery in Indonesia. The first site survey in September 2000 has carried out a survey on the situation of the facilities and operation upon obtaining the facility data and operation information from Pertamina. As a result, it was revealed that there is a room of improvement in the heat recovery, whereas a modification design was executed on the improvement proposals on the heat exchanger system. However, the second site survey in November 2000 has revealed that Pertamina had executed in 1998 through 1999 the de-bottlenecking project on the crude oil atmospheric distillation units (two units) and the high vacuum distillation units (two units), by which the capability has been expanded, and the heat recovery rate has been increased. It is not possible to look for extremely large enhancement of the heat recovery rate beyond that point, and the reduction of CO2 emission would also be small. As a result of discussions, the present project was found capable of reducing annually the CO2 emission by 36,500 tons. (NEDO)

Bioremediation of petroleum refinery effluent by Planococcus ...

African Journals Online (AJOL)

In the present investigation, Planococcus halophilus was screened for hydrocarbon degradation and bioremediation of refinery effluent. The test organism, P. halophilus, showed the capability to utilize kerosene as carbon source in minimal medium. Biological treatment of the refinery effluent with P. halophilus reduced the ...

An estimation of cogeneration potential by using refinery residuals in Mexico

International Nuclear Information System (INIS)

Marin-Sanchez, J.E.; Rodriguez-Toral, M.A.

2007-01-01

Electric power generation in Mexico is mainly based on fossil fuels, specifically heavy fuel oil, although the use of natural gas combined cycles (NGCC) is becoming increasingly important. This is the main destination that has promoted growing imports of natural gas, currently accounting for about 20% of the total national annual consumption. Available crude oil is becoming heavier; thus refineries should be able to process it, and to handle greater quantities of refinery residuals. If all refinery residuals are used in cogeneration plants serving petroleum refineries, the high heat/power ratio of refinery needs, leads to the availability of appreciable quantities of electricity that can be exported to the public utility. Thus, in a global perspective, Mexican imports of natural gas may be reduced by cogeneration using refinery residuals. This is not the authors' idea; in fact, PEMEX, the national oil company, has been entitled by the Mexican congress to sell its power leftovers to The Federal Electricity Commission (CFE) in order to use cogeneration in the way described for the years to come. A systematic way of determining the cogeneration potential by using refinery residuals from Mexican refineries is presented here, taking into account residual quantities and composition, from a national perspective, considering expected scenarios for Maya crude content going to local refineries in the years to come. Among different available technologies for cogeneration using refinery residuals, it is believed that the integrated gasification combined cycle (IGCC) would be the best option. Thus, considering IGCC plants supplying heat and power to refineries where it is projected to have refinery residuals for cogeneration, the expected electric power that can be sent to the public utility is quantified, along with the natural gas imports mitigation that may be attained. This in turn would contribute to a necessary fuel diversification policy balancing energy, economy and

Improving profitability in a grassroots refinery

Energy Technology Data Exchange (ETDEWEB)

Coombs, T. [Star Petroleum Refining Co. Ltd. (Thailand); Kennedy, P.; Bhargava, S. [KBC Process Technology Ltd. (United Kingdom)

1999-05-01

Actions taken to maximise profit at the Star Refinery in Thailand are described. The company made good use of the Profit Improvement Programme (PIP) (which specialises in refinery economics) and the way in which PIP addressed the problem and the benefits derived therefrom is the nub of this paper. The efforts appear to have been more than satisfactory from the aspect of increasing profit margins. (UK)

POSSIBILITIES OF CARBON DIOXIDE FIXATION BY MICROALGAE IN REFINERY

OpenAIRE

Šingliar, Michal; Mikulec, Jozef; Kušnir, Patrik; Polakovičova, Gabriela

2013-01-01

Capture and sequestration of carbon dioxide is one of the most critical challenges today for businesses and governments worldwide. Thousands of emitting power plants and industries worldwide face this costly challenge – reduce the CO2 emissions or pay penalties. One possibility for carbon dioxide sequestration is its fixation in microalgae. Microalgae can sequester CO2 from flue gases emitted from fossil fuel-fired refinery plants and units, thereby reducing emissions of a major greenhouse ga...

Refinery profitability

International Nuclear Information System (INIS)

Tobin, G.

1998-01-01

Recently there has been considerable shutting down of oil refinery capacity in response to the increasing pressures on profitability. This article examines the situation and the industry's response to it, including the drive for mergers, disposal of fuel oil, downsizing of workforces and strategic alliances. Future trends and their implications are also discussed. (UK)

Management and analysis of data from petroleum refinery wastewater treatment plants

Energy Technology Data Exchange (ETDEWEB)

Chapman, D T [Wastewater, Technology Centre, Burlington, ON (Canada); Grammas, J [SOHO, Lima, OH (USA)

1989-01-01

Current efforts to monitor trace contaminants in treated oil refinery wastewaters increase the need to implement systematic, clear, and consistent procedures for reporting and presenting all monitoring data. The ability to interpret trace contaminant data which is to be collected by the governments of the U.S. and Canada for regulations development will rely on information about operating procedures and the efficiency of removal of conventional pollutants. An overview is provided of the main issues which must be addressed in managing and analyzing data from wastewater treatment facilities. The objectives of enviromental data management and analysis are discussed from the point of view of both the plant operator or owner and the regulatory authority. Based on the examination of the 1985 records of flow and phenol concentrations from seven Canadian petroleum refineries, recommendations are made for improving existing databases. In analyzing environmental data to transform raw data into information, exploratory data analysis techniques should be used by engineers or operators who do not have formal statistical training. These methods employ simple statistical summaries and graphical data displays. The paper concludes with a brief discussion about future trends in environmental data management and analysis. 15 refs., 5 figs., 2 tabs.

Fiscal 1998 joint promotion basic research report. Energy saving project for Achinsk refinery in Russia; 1998 nendo kyodo jisshi nado suishin kiso chosa. Roshia Achinsuku seiyujo shoene project

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-03-01

For prevention of global warming by greenhouse effect gas, study was made on energy saving measures for Achinsk refinery in Russia. Achinsk refinery is a relatively new plant put into operation in 1983, however, because of no various equipment for use combustion heat effectively, its average thermal efficiency is as low as 60%-70%, resulting in fuel consumption more than necessary one. Based on the study result, the following remodeling designs were made: Improvement of a heat exchange efficiency by relocation of heat exchangers to reduce fuel consumption of a heating furnace as much as possible, conversion of an existing heating furnace based on an old design concept to an advanced one, installation of a waste heat recovery system including a preheating convection unit and air preheater, reinforcement of heating furnace wall insulator, installation of an optimum control system for furnace operation, and improvement of a fuel supply system efficiency. This design showed possible reduction of heating furnace load, and possible furnace thermal efficiency of 90%. (NEDO)

Pursuing the pre-combustion CCS route in oil refineries – The impact on fired heaters

International Nuclear Information System (INIS)

Weydahl, Torleif; Jamaluddin, Jamal; Seljeskog, Morten; Anantharaman, Rahul

2013-01-01

Highlights: ► The aim is to approach Carbon Capture and Storage (CCS) to refinery fired heaters. ► An identical simplified burner configuration is applied where refinery fuel is replaced with hydrogen. ► Initial simulations indicate that hydrogen replacement do not alter heater operation in a negative way. ► Despite the higher flame temperature in the hydrogen case, the NO x emissions are not higher. ► The prompt-NO mechanism contributes significantly in the refinery fuel case. -- Abstract: The work presented in this paper investigates the effect of replacing refinery fuel gas in the radiant section burners of a fired heater with hydrogen. The aim is to approach pre-combustion CCS to refinery fired heaters by identifying the impact on heat-, flow- and radiation distribution in the lower radiant section of the fired heater when simply switching refinery gas with hydrogen at equivalent power using the same burner geometrics. Additionally the formation of NO x is considered. The investigations are performed using a conventional Reynolds Average Navier Stokes (RANS), Computational Fluid Dynamics (CFD) approach using detailed reaction kinetics consisting of 325 elementary reactions and 53 species. Simplified and generalized furnace and burner geometries are used in the present work. The results show that approximately the same average wall heat flux density is achieved when the refinery fuel is replaced by hydrogen. However, the distribution of heat on the inner surfaces changes. The hydrogen case has, as expected, a higher flame temperature than the base case, nevertheless, the nitric oxide (NO x ) emissions are comparable to base case emissions. Several indications point in the direction of a significant contribution to the base case emissions from the less temperature dependent prompt-NO mechanism, which obviously is not contributing to the hydrogen case emissions.

Superfund Record of Decision (EPA Region 2): Sinclair Refinery, Allegany County, Wellsville, NY. (Second remedial action), September 1991. Final report

International Nuclear Information System (INIS)

1991-01-01

The Sinclair Refinery site is a former refinery in Wellsville, Allegany County, New York. The site is composed of a 90-acre refinery area, 10-acre landfill area, and 14-acre offsite tank farm. From 1901 to 1958, the site was used to process Pennsylvania grade crude oil until a fire in 1958 halted operations. Currently, some private companies and the State University of New York occupy the site. A 1981 site inspection revealed that debris from the eroding landfill area has washed into and contaminated the Genesee River. The ROD addresses OU2, remediation of the remaining contaminated areas at the site located within the 90-acre refinery area and the offsite tank farm including the contaminated ground water beneath the refinery. The primary contaminants of concern affecting the soil and ground water are VOCs including benzene and xylenes, semi-volatile compounds including naphthalene and nitrobenzene, and metals including arsenic and lead. The selected remedial action for the site is included

40 CFR 80.1141 - Small refinery exemption.

Science.gov (United States)

2010-07-01

.... (a)(1) Gasoline produced at a refinery by a refiner, or foreign refiner (as defined at § 80.1165(a... effective beginning on January 1 of the following calendar year, at which point the gasoline produced at... from the calculation of its Renewable Volume Obligation (under § 80.1107(a)) gasoline from any refinery...

Detection of impurities in fluid flowing in refinery pipeline or oil production operations using nuclear techniques

International Nuclear Information System (INIS)

1981-01-01

Chlorine (from salt water) and sulphur are determined in crude oil in a well head conduit or refined product in a petroleum refinery by bombardment with neutrons and measuring the gamma rays emitted by neutron capture reactions. (U.K.)

Effect of adoption of gas turbine in oil refinery

Energy Technology Data Exchange (ETDEWEB)

Tamai, Hiroto

1988-08-01

With progress in energy saving, and increase in automation in facilities, the dependence on electric power increases relative steam power. Further in order to reduce the production cost, the adoption of gas turbine combined cycle system, mainly aimed at power generation, is considered to be most suitable. This adoption, accompanied with the utilization of refinery offgas, dresults in a reduction in unit power generation cost, by increasing the ratio of domestic power generation. The gas turbine using deethanizing tower offgas as main fuel and butane as auxillary fuel, the combined cycle system, where steam produced from the turbine waste heat boiler drives the existing back pressure turbine, was constituted. The generator is 118 kVA in capacity. Against the maximum power demand being 16,500 kWh in the oil refinery, the obtainment of 11,000 kWh by the gas turbine and 2,500 kWh by the back pressure turbine was assured, with a considerable lowering in power to be purchased. (7 figs, 1 tab, 1 ref)

Amoco-US Environmental Protection Agency, pollution prevention project, Yorktown, Virginia: Yorktown refinery project workplan

International Nuclear Information System (INIS)

Curran, L.; Grieves, C.; Browning, R.; Hanlon, D.; Crane, C.

1990-09-01

The report provides a detailed workplan for obtaining data and analyzing results for a 2-year pollution prevention study of Amoco Oil Company's Yorktown Virginia Refinery. The study was jointly sponsored as a cooperative effort of Amoco Corporation and the United States Environmental Protection Agency. The goals of the study include (1) a multi-media inventory of all releases entering the environment from the Refinery, (2) development of possible engineering options to reduce the releases, (3) analysis of each option in terms of release reduction potential, impact on human health risk, ecological impact, changes in future liability, etc. and (4) identification of obstacles and incentives for implementation of any of the options considered

Joint refinery selenium treatability study

International Nuclear Information System (INIS)

Meyer, C.L.; Folwarkow, S.

1993-01-01

The San Francisco Regional Water Quality Control Board recently established mass limits on discharges of selenium to the San Francisco Bay from several petroleum refineries. The refineries had been working independently to develop control strategies, including both source control and treatment options, for removal of selenium from their discharges. By January 1992, over fifty different combinations of treatment technologies, wastewater streams, and pretreatment steps had been investigated to determine their effectiveness and feasibility as selenium removal processes. No treatment process studied could achieve the required mass limits without serious negative environmental consequences, such as generation of large amounts of hazardous sludge. To better facilitate the development of a feasible selenium treatment process, the six Bay Area refineries shared results of their studies and identified several technologies that, with further work, could be developed further. This additional work is currently being carried out as part of a joint selenium treatability study sponsored by the Western States Petroleum Association. A review of the previous source control and treatment studies, along with a description of the current treatability studies will be discussed

Petroleum Refinery Effluents Treatment by Advanced Oxidation Process with Methanol

Energy Technology Data Exchange (ETDEWEB)

Shoucheng, Wen [Yangtze Univ., HuBei Jingzhou (China)

2014-02-15

Petroleum refinery effluents are waste originating from industries primarily engaged in refining crude oil. It is a very complex compound of various oily wastes, water, heavy metals and so on. Conventional processes are unable to effectively remove the chemical oxygen demand (COD) of petroleum refinery effluents. Supercritical water oxidation (SCWO) was proposed to treat petroleum refinery effluents. In this paper, methanol was used to investigate co-oxidative effect of methanol on petroleum refinery effluents treatment. The results indicated that supercritical water oxidation is an effective process for petroleum refinery effluents treatment. Adding methanol caused an increase in COD removal. When reaction temperature is 440 .deg. C, residence time is 20 min, OE is 0.5 and initial COD is 40000 mg/L, and COD removal increases 8.5%.

Petroleum Refinery Effluents Treatment by Advanced Oxidation Process with Methanol

International Nuclear Information System (INIS)

Shoucheng, Wen

2014-01-01

Petroleum refinery effluents are waste originating from industries primarily engaged in refining crude oil. It is a very complex compound of various oily wastes, water, heavy metals and so on. Conventional processes are unable to effectively remove the chemical oxygen demand (COD) of petroleum refinery effluents. Supercritical water oxidation (SCWO) was proposed to treat petroleum refinery effluents. In this paper, methanol was used to investigate co-oxidative effect of methanol on petroleum refinery effluents treatment. The results indicated that supercritical water oxidation is an effective process for petroleum refinery effluents treatment. Adding methanol caused an increase in COD removal. When reaction temperature is 440 .deg. C, residence time is 20 min, OE is 0.5 and initial COD is 40000 mg/L, and COD removal increases 8.5%

Simulation of the Stabilization Unit Refinery “Hermanos Díaz” Using Aspen Hysys 8.0

Directory of Open Access Journals (Sweden)

Thayset Mariño-Peacok

2016-07-01

Full Text Available In this paper a study of the production of liquefied petroleum gas is carried out in the Stabilization Unit refinery “Hermanos Díaz”. Implementation of this process was conducted in the simulator Aspen Hysys 8.0 with the aim of developing a simulation that would increase the efficiency of this plant. Different alternatives are evaluated using the simulator tool Databook, as were the analysis of the temperature and pressure and its influence on the flow of the compounds of interest in the separators; the number of trays and the feed tray to the distillation column and its influence on the energy of the condenser and reboiler. It was determined that at 44°C and 160 kPa in the separator D-120 and at 34,5 °C and 738.8 kPa in the separator D-109 ensures good performance of the process. In addition it was found that with 50 trays and a feed tray 27 in the distillation tower T-104 guarantee lower consumption of energy (1,4*10 7 kJ/kmol and 1,5*107 kJ/kmol for the condenser and reboiler respectively. It was shown that an increased flow of unstabilized light naphtha fed to the plant, leads to increased efficiency of the unit. The simulation of the process led to raise the efficiency of the plant because the flow of liquefied petroleum gas increased in 11.79% to quality established.

Environmental nickel exposure from oil refinery emissions: a case study in Ecuador.

Science.gov (United States)

Harari, Raúl; Harari, Florencia; Forastiere, Francesco

2016-01-01

Nickel is a strong skin and respiratory sensitizer and a recognized carcinogen. Oil refineries are important sources of atmospheric emissions of toxic pollutants, including nickel. Populations residing close to oil refineries are at potential risk. The aim of this study was to evaluate the exposure to nickel in a population living close to the largest oil refinery in Ecuador, located in the city of Esmeraldas. We recruited 47 workers from the oil refinery as well as 195 students from 4 different schools close to the plant and 94 students from another school 25 km far from the industry. Urinary nickel concentrations were used to assess the exposure to nickel. Students from the school next to the oil refinery showed the highest urinary nickel concentrations while workers from the refinery showed the lowest concentrations. Median nickel concentrations were > 2µg/L in all study groups. The populations living close to the oil refineries are potentially exposed to nickel from atmospheric emissions. Further studies investigating nickel-related health effects in the population residing close to the refinery of Esmeralda are needed.

Solid waste management : a case study of National Refinery Limited

Energy Technology Data Exchange (ETDEWEB)

Syed, A.H.; Syed, Z.R. [National Refinery Ltd., Karachi (Pakistan); NED Univ. of Engineering and Technology, Karachi (Pakistan)

2000-07-01

A study was conducted to quantify and classify the waste generated at the National Refinery Limited (NRL). This refinery, located in Karachi, Pakistan, produces naphtha, motor gasoline, diesel, kerosene and lubricating oils and much more. Various units such as crude oil storage, thermal cracking, catalytic cracking and others were surveyed to assess the source and nature of the pollution. It was found that the major contributor to air pollution was the sulfur released through the burning of fuel oil during day-to-day operations. It was determined that approximately 2000 metric tons of solid waste were produced each day, along with 0.55 million gallons of waste water. In addition, sulfur, carbon dioxide, carbon monoxide and nitrogen dioxide were also released in the atmosphere. The solid waste was composed of municipal waste, sludges from the API and other discarded materials. The authors then proceeded to determine the heavy metals contents in samples obtained from combined sludge dumping areas on the premises. The sludges contained sulfur (0-1.26 wt per cent), lead (0-0.156 wt per cent), iron (0.01-3.4 wt per cent), chromium (0-0.159 per cent), copper (0-0.05 wt per cent), cadmium (0-0.0034 wt per cent), nickel (0-0.168 wt per cent), and manganese (0.0015-0.0776 wt per cent). It was recommended that hazardous and non-hazardous wastes be segregated, that a separate feasibility study be undertaken to determine the best possible course of action to dispose of solid waste, and that government guidelines be established on the same topic. 5 refs., 4 tabs.

Integrating planning and scheduling in an oil refinery with a rolling horizon approach

NARCIS (Netherlands)

Zondervan, E.; Kaland, M.; van Elzakker, M.A.H.; Fransoo, J.C.; Meuldijk, J.; Klemes, J.J.; Varbanov, P.S.; Liew, P.Y.

2014-01-01

Decisions in an oil refinery are made at three levels: planning, scheduling and control. Existing facilities have to be operated close to their maximum capacity, while continuously responding to cost fluctuations. In many of the currently reported planning models each decision level has its own

Feasibility of flare gas reformation to practical energy in Farashband gas refinery: no gas flaring.

Science.gov (United States)

Rahimpour, Mohammad Reaza; Jokar, Seyyed Mohammad

2012-03-30

A suggested method for controlling the level of hazardous materials in the atmosphere is prevention of combustion in flare. In this work, three methods are proposed to recover flare gas instead of conventional gas-burning in flare at the Farashband gas refinery. These methods aim to minimize environmental and economical disadvantages of burning flare gas. The proposed methods are: (1) gas to liquid (GTL) production, (2) electricity generation with a gas turbine and, (3) compression and injection into the refinery pipelines. To find the most suitable method, the refinery units that send gas to the flare as well as the required equipment for the three aforementioned methods are simulated. These simulations determine the amount of flare gas, the number of GTL barrels, the power generated by the gas turbine and the required compression horsepower. The results of simulation show that 563 barrels/day of valuable GTL products is produced by the first method. The second method provides 25 MW electricity and the third method provides a compressed natural gas with 129 bar pressure for injection to the refinery pipelines. In addition, the economics of flare gas recovery methods are studied and compared. The results show that for the 4.176MMSCFD of gas flared from the Farashband gas refinery, the electricity production gives the highest rate of return (ROR), the lowest payback period, the highest annual profit and mild capital investment. Therefore, the electricity production is the superior method economically. Copyright © 2012 Elsevier B.V. All rights reserved.

Prospective techno-economic and environmental assessment of carbon capture at a refinery and CO

NARCIS (Netherlands)

Fernandez Dacosta, C.; Van Der Spek, Mijndert; Hung, Christine Roxanne; Oregionni, Gabriel David; Skagestad, Ragnhild; Parihar, Prashant; Gokak, D. T.; Strømman, Anders Hammer; Ramirez Ramirez, C.A.

2017-01-01

CO₂ utilisation is gaining interest as a potential element towards a sustainable economy. CO₂ can be used as feedstock in the synthesis of fuels, chemicals and polymers. This study presents a prospective assessment of carbon capture from a hydrogen unit at a refinery, where

WATER PINCH TECHNOLOGY APPLICATION TO MINIMIZE SULPHUROUS WASTEWATER IN AN OIL REFINERY

Directory of Open Access Journals (Sweden)

Gabriel Orlando Lobelles Sardiñas

2017-01-01

Full Text Available In oil refining industries there is a high water consumption, which influences the high production costs and impacts the environment due to the discharge of their wastes. It is known that there are no technological conditions for the reuse of industrial water at the oil refineries, based on hydroskimming processes. The objective of this study is to implement the process integration methodology, Water Pinch, to a sour water stripper unit, as a unitary process of an oil refinery, to minimize the amount of sulphurous waste water and reduce contamination of the bay that receives these wastes. The technology is applied to evaluate the volume of sulphurous wastewater generated in the Cienfuegos oil refinery. This technology allows identifying opportunities for recovery and reuse of water, based on concentration ranges of contaminants. To achieve this purpose, a sour water stripper tower was assessed with the help of Water Pinch software, which provided an optimized distribution network, as a proposed technological improvement. This facilitated to recover and reuse 667 757, 28 m3 of water per year, and 1 035 023, 78 CUC were saved, at the same time the amount of polluting effluents decreased in approximately 2 % of non-reusable treated water.

Optimal Renewable Energy Integration into Refinery with CO2 Emissions Consideration: An Economic Feasibility Study

Science.gov (United States)

Alnifro, M.; Taqvi, S. T.; Ahmad, M. S.; Bensaida, K.; Elkamel, A.

2017-08-01

With increasing global energy demand and declining energy return on energy invested (EROEI) of crude oil, global energy consumption by the O&G industry has increased drastically over the past few years. In addition, this energy increase has led to an increase GHG emissions, resulting in adverse environmental effects. On the other hand, electricity generation through renewable resources have become relatively cost competitive to fossil based energy sources in a much ‘cleaner’ way. In this study, renewable energy is integrated optimally into a refinery considering costs and CO2 emissions. Using Aspen HYSYS, a refinery in the Middle East was simulated to estimate the energy demand by different processing units. An LP problem was formulated based on existing solar energy systems and wind potential in the region. The multi-objective function, minimizing cost as well as CO2 emissions, was solved using GAMS to determine optimal energy distribution from each energy source to units within the refinery. Additionally, an economic feasibility study was carried out to determine the viability of renewable energy technology project implementation to overcome energy requirement of the refinery. Electricity generation through all renewable energy sources considered (i.e. solar PV, solar CSP and wind) were found feasible based on their low levelized cost of electricity (LCOE). The payback period for a Solar CSP project, with an annual capacity of about 411 GWh and a lifetime of 30 years, was found to be 10 years. In contrast, the payback period for Solar PV and Wind were calculated to be 7 and 6 years, respectively. This opens up possibilities for integrating renewables into the refining sector as well as optimizing multiple energy carrier systems within the crude oil industry

The impact of CO2 taxation on the configuration of new refineries: An application to Brazil

International Nuclear Information System (INIS)

Gomes, Gabriel Lourenco; Szklo, Alexandre; Schaeffer, Roberto

2009-01-01

This article evaluates the impact of pricing CO 2 emissions over the configuration of new refinery complexes in their conceptual phase. Two refineries' schemes were simulated through a linear programming optimization model in order to compare the optimum configuration obtained before and after the input of different CO 2 prices. The cases analyzed represent refining projects to be located in Brazil, a growing market for fuels and petrochemical feedstocks, as well as an oil producing country with rising crude exports. After 2012, emerging countries, such as Brazil, may adopt carbon emission reduction targets. Therefore, it is worth analyzing the impact of pricing CO 2 emissions in these countries, where the majority of new refining projects will be located. Our findings indicate that the initial refinery configurations proposed are quite rigid technologically for CO 2 prices up to US$ 100/t CO 2 . For CO 2 prices higher than US$ 100/t CO 2 , refineries reduced their emissions by increasing the consumption of natural gas used to produce hydrogen, and through changes in the original configurations towards less-energy consuming process units. Promising technological advances, such as carbon capture and storage (CCS), can also diminish the rigidity of the model and facilitate actions to curb carbon emissions.

Report on the degradation of the environment at the site of NIS Novi Sad oil refinery and remediation measures

International Nuclear Information System (INIS)

Pavlovic, P.; Pavlovic, M.; Ivankovic, M.; Sokolovic, S.

2002-01-01

Before the NATO bombing, Refinery had available 149 tanks for the storage of crude oil, intermediate and final products, additives etc. All tanks are placed within the impermeable embankments of concrete or soil and connected to the storm and oil sewerage systems which enables the monitoring and control of of oil leakage and storm waste. During the NATO bombing practically all processing units were either destroyed or damaged. The summary of damages inflicted to the processing units is given. During the NATO bombing campaign over 51% of the available storage capacity was destroyed and over 34% of it was severely damaged. A summary of available, destroyed and damaged tank capacities in the NIS Novi Sad Oil Refinery is given. (author)

environmental impact of illegal refineries on the vegetation

African Journals Online (AJOL)

Dr. O. M. Adesope

impact of illegal oil refineries in the Niger Delta, Nigeria, the floristic composition of the fresh water swamp forest at refining sites in two river systems and a brackish ... ecosystem of Rivers State, five species of Mangroves and two species of ... Visual observation was made along the Rivers to identify illegal refinery stations.

Market survey on products from the Tema Oil Refinery carried out as part of the feasibility study on the Tema Oil Refinery expansion project. Export trade information

International Nuclear Information System (INIS)

Anon.

1991-10-01

The Tema Oil Refinery (TOR), which was commissioned in 1963, is a simple hydroskimming plant which processes crude oil into LPG, gasoline, kerosene, gasoil, and fuel oil. It is the only petroleum refinery in Ghana. Over the years some of the equipment in the refinery has deteriorated or become obsolete necessitating major rehabilitation. A feasibility study is investigating the modernization and expansion of the refinery to meet projected market demands until the year 2005. The report presents the results of a market survey done on products from TOR

Effect of oil spills on coastal power plants, refineries, and desalination plants

International Nuclear Information System (INIS)

Kiefer, C.; Mussali, Y.

1992-01-01

Major oil spills such as those experienced in the Gulf War, in Alaska, and in the Gulf of Mexico have raised concern for the protection of coastal facilities which use seawater for cooling or process purposes such as power stations, refineries, and desalination plants. Because of the availability of large quantities of cooling water, many power stations and refineries are located along the coastline in the United States and throughout the world. In addition, many countries in the Middle East, the Caribbean, and other areas of the world depend on desalination plants located along the coast for the vital supply of drinking water. The objective of this paper is to determine the levels of oil contamination which will adversely affect plant performance or result in damage to specific plant equipment such as condensers, heat exchangers, pumps, screens, water treatment equipment, and other vital water handling mechanisms

Assessment of Petroleum Leakage in Groundwater of the Abadan Refinery

Directory of Open Access Journals (Sweden)

Seyed Reza Shadizadeh

2010-06-01

Full Text Available Knowledge of petroleum leakage at oil refineries is vital for environmental study of water and soil pollution. Abadan Refinery is located between the Arvandrud and Bahmanshir rivers in the highly populated area of Abadan city. These rivers supply domestic, industrial, and agricultural water toAbadancity. During the war betweenIranandIraq, enormous volumes of oil and petroleum products leaked from storage tanks and pipelines at Abadan Refinery into the surrounding environment. The resulting pollution is a serious threat and a growing environmental concern for the region. In this work, twenty boreholes were dug to investigate petroleum leaks into the surrounding area both during and after the war. The thickness of petroleum floating on underground waters at the refinery was measured by sampling underground water over a period of one year along with measuring the piezometric heads of groundwater monitoring wells. Also, groundwater movement pattern at Abadan Refinery was determined by measuring the water table in each well over the same period. The results of sampling indicate that oil leaks were observed in just two wells; namely, wells No.3 and No.11. The results also show that the greatest portion of the oil spill in underground layers at Abadan Refinery was absorbed into clay soil.

Improving secondary clarifier performance at the Oakville Oil Refinery

International Nuclear Information System (INIS)

Edwards, S.M.; Bagley, D.M.

2002-01-01

The purpose of this study was threefold: to investigate the relationship between settleability and the physical properties of activated sludge, to correlate settleability and key operational parameters such as chemical oxygen demand (COD) concentration at the aeration basin inlet and to determine potential operational improvements to the Oakville Oil Refinery Wastewater Treatment Plant. Nine separate sets of stirred sludge-settling tests were conducted over a six-month period to measure settleability. The stirred sludge volume index (SSVI), the zone settling constants, and the Zheng-Bagley compression constants were determined. State point analyses were conducted to determine the maximum solids flux of the clarifiers. The concentrations of Al, Mn, Mg, Fe, Ca, Na, and K were determined to identify potential correlations to settling characteristics. Extracellular polymeric substances were extracted from the sludge and analyzed for the same reason. The performance of the clarifiers was highly variable during the period examined. As the refinery process flows and effluent streams changed, influent COD increased, from an average of 180mg/L to 600mg/L. Concurrently the settleability of the sludge decreased from excellent (SSVI = 68mL/g) to very poor (150mL/g), perhaps as the result of under aeration. State point analyses indicated that the clarifiers are under-sized for process upsets of this magnitude. (author)

Improving secondary clarifier performance at the Oakville Oil Refinery

Energy Technology Data Exchange (ETDEWEB)

Edwards, S.M.; Bagley, D.M. [Univ. of Toronto, Dept. of Civil Engineering, Toronto, Ontario (Canada)

2002-06-15

The purpose of this study was threefold: to investigate the relationship between settleability and the physical properties of activated sludge, to correlate settleability and key operational parameters such as chemical oxygen demand (COD) concentration at the aeration basin inlet and to determine potential operational improvements to the Oakville Oil Refinery Wastewater Treatment Plant. Nine separate sets of stirred sludge-settling tests were conducted over a six-month period to measure settleability. The stirred sludge volume index (SSVI), the zone settling constants, and the Zheng-Bagley compression constants were determined. State point analyses were conducted to determine the maximum solids flux of the clarifiers. The concentrations of Al, Mn, Mg, Fe, Ca, Na, and K were determined to identify potential correlations to settling characteristics. Extracellular polymeric substances were extracted from the sludge and analyzed for the same reason. The performance of the clarifiers was highly variable during the period examined. As the refinery process flows and effluent streams changed, influent COD increased, from an average of 180mg/L to 600mg/L. Concurrently the settleability of the sludge decreased from excellent (SSVI = 68mL/g) to very poor (150mL/g), perhaps as the result of under aeration. State point analyses indicated that the clarifiers are under-sized for process upsets of this magnitude. (author)

Evaluation of treatment efficiency of processes for petroleum refinery`s wastewater

Energy Technology Data Exchange (ETDEWEB)

Kee, Kean Chin [National Univ. of Singapore, Kent Ridge (Singapore). Dept. of Civil Engineering

1994-12-31

Processes used in the treatment of a petroleum refinery wastewater included initial API oil separator to be followed by dissolved air flotation and extended aeration system. The use of extended aeration biological system proved to be an improvement but not a solution yet in such kind of treatment. 2 refs., 2 tabs.

Evaluation of treatment efficiency of processes for petroleum refinery`s wastewater

Energy Technology Data Exchange (ETDEWEB)

Kee, Kean Chin [National Univ. of Singapore, Kent Ridge (Singapore). Dept. of Civil Engineering

1993-12-31

Processes used in the treatment of a petroleum refinery wastewater included initial API oil separator to be followed by dissolved air flotation and extended aeration system. The use of extended aeration biological system proved to be an improvement but not a solution yet in such kind of treatment. 2 refs., 2 tabs.

Reformulated gasoline: Costs and refinery impacts

International Nuclear Information System (INIS)

Hadder, G.R.

1994-02-01

Studies of reformulated gasoline (RFG) costs and refinery impacts have been performed with the Oak Ridge National Laboratory Refinery Yield Model (ORNL-RYM), a linear program which has been updated to blend gasolines to satisfy emissions constraints defined by preliminary complex emissions models. Policy makers may use the reformulation cost knee (the point at which costs start to rise sharply for incremental emissions control) to set emissions reduction targets, giving due consideration to the differences between model representations and actual refining operations. ORNL-RYM estimates that the reformulation cost knee for the US East Coast (PADD I) is about 15.2 cents per gallon with a 30 percent reduction of volatile organic compounds (VOCs). The estimated cost knee for the US Gulf Coast (PADD III) is about 5.5 cents per gallon with a VOC reduction of 35 percent. Reid vapor pressure (RVP) reduction is the dominant VOC reduction mechanism. Even with anti-dumping constraints, conventional gasoline appears to be an important sink which permits RFG to be blended with lower aromatics and sulfur contents in PADD III. In addition to the potentially large sensitivity of RFG production to different emissions models, RFG production is sensitive to the non-exhaust VOC share assumption for a particular VOC model. ORNL-RYM has also been used to estimate the sensitivity of RFG production to the cost of capital; to the RVP requirements for conventional gasoline; and to the percentage of RFG produced in a refining region

Optimization of refinery operations when uncertainty exists: Algeria's case; Optimisation des operations du raffinage en presence d'incertitudes: Cas de l'Algerie

Energy Technology Data Exchange (ETDEWEB)

Benyoucef, Abderrezak; Lantz, Frederic

2010-09-15

The objective of this article is to analyze the development of Algeria refinery industry when uncertainty exists, from a dynamic linear programming model. Because of the different market conditions volatility, many parameters must be able to be considered as uncertain. In our study, we treat mainly uncertainties of petroleum products demand. The model gives production levels, the units market rate and the exterior exchange of products at horizons 2030. It allows to appreciate the impact of volatility on this industry's development. [French] L'objectif de cet article est d'analyser le developpement de l'industrie algerienne du raffinage en presence d'incertitudes, a partir d'un modele de programmation lineaire dynamique. En raison de la volatilite des differentes conditions du marche, de nombreux parametres doivent pouvoir etre consideres comme incertains. Dans notre etude, nous traitons en particulier des incertitudes sur la demande des produits petroliers. Le modele fournit les niveaux de production, le taux de marche des unites et les echanges exterieurs de produits a l'horizon 2030. Il permet ainsi d'apprecier l'impact de la volatilite sur le developpement de cette industrie.

Implementation of NOx control technologies in petroleum refining applications, Mobil Torrance Refinery

International Nuclear Information System (INIS)

Younis, M.P.

1994-01-01

Existing NO x technologies implemented by the Mobil Torrance refinery have been reviewed. Technologies utilized are Lo-NO x burners, Ultra-Lo-NO x burners and selective catalytic reduction in boilers and process heaters, as well as selective non-catalytic reduction in fluid catalytic cracker/CO boiler applications. With the implementation of the Regional Clean Air Incentives Market (RECLAIM), research at Mobil is directed towards reducing operational costs and improving efficiency in selective catalytic reduction with high and low temperature catalysts. Research is also directed at improved selective non-catalytic reduction efficiency in CO boiler applications and at further NO x reduction in fluid catalytic cracker regenerator offgases. The implementation of proven and enhanced technology is expected to reduce refinery NO x emissions from 1734 metric tons per yr to 487 metric tons per yr by the year 2003. 4 refs., 7 figs

Energy markets : refinery outages can have varying gasoline price impacts, but gaps in federal data limit understanding of impacts.

Science.gov (United States)

2009-07-01

In 2008, GAO reported that, with : the exception of the period : following Hurricanes Katrina and : Rita, refinery outages in the United : States did not show discernible : trends in reduced production : capacity, frequency, and location : from 2002 ...

Personal exposure to benzene and 1,3-butadiene during petroleum refinery turnarounds and work in the oil harbour.

Science.gov (United States)

Akerstrom, M; Almerud, P; Andersson, E M; Strandberg, B; Sallsten, G

2016-11-01

Petroleum refinery workers' exposure to the carcinogens benzene and 1,3-butadiene has decreased during normal operations. However, certain occupational groups or events at the refineries still involve a risk of higher exposures. The aim of this study was to examine the personal exposure to benzene and 1,3-butadiene at refinery turnarounds and during work in the oil harbour. Personal exposure measurements of benzene and 1,3-butadiene were taken during work shifts, with a priori assumed higher benzene exposure, using PerkinElmer diffusive samplers filled with Carbopack X. Mean exposure levels were calculated, and repeated exposure measurements, when available, were assessed using mixed effect models. Group and individual compliance with the Swedish occupational exposure limit (OEL) was tested for the different exposure groups. Mean benzene exposure levels for refinery workers during the three measured turnarounds were 150, 610 and 960 µg/m 3 , and mean exposures for oil harbour workers and sewage tanker drivers were 310 and 360 µg/m 3 , respectively. Higher exposures were associated with handling benzene-rich products. Most occupational groups did not comply with the Swedish OEL for benzene nor did the individuals within the groups. The exposure to 1,3-butadiene was very low, between Work within the petroleum refinery industry, with potential exposure to open product streams containing higher fractions of benzene, pose a risk of personal benzene exposures exceeding the OEL. Refinery workers performing these work tasks frequently, such as contractors, sewage tanker drivers and oil harbour workers, need to be identified and protected.

Oil refineries

International Nuclear Information System (INIS)

Boehmer, S.; Winter, B.

2001-01-01

In refineries in particular attention is paid to the minimization of the generation of waste. Therefor catalysts in many processes are regenerated, absorbents are recycled and oily by-products are re-refined or used as fuels. This study discusses the origin and utilization of by-products from the oil industry. The processing of crude oils causes by-products and waste resulting from the crude oil itself or from cleaning measures for water pre-treatment, effluent treatment and flue gas treatment. (author)

Occupational exposure to benzene at the ExxonMobil refinery in Baytown, TX (1978-2006).

Science.gov (United States)

Gaffney, Shannon H; Panko, Julie M; Unice, Ken M; Burns, Amanda M; Kreider, Marisa L; Gelatt, Richard H; Booher, Lindsay E; Paustenbach, Dennis J

2011-01-01

Although occupational benzene exposure of refinery workers has been studied for decades, no extensive analysis of historical industrial hygiene data has been performed focusing on airborne concentrations at specific refineries and tasks. This study characterizes benzene exposures at the ExxonMobil Baytown, TX, refinery from 1978 to 2006 to understand the variability in workers' exposures over time and during different job tasks. Exposures were grouped by operational status, job title, and tasks. More than 9000 industrial hygiene air samples were evaluated; approximately 4000 non-task (> 3 h) and 1000 task-related (work areas, and 16 task bins (when applicable). Process technicians were sampled most frequently, resulting in the following mean benzene concentrations by area: hydrofiner (n=245, mean=1.3 p.p.m.), oil movements (n=286, mean=0.23 p.p.m.), reformer (n=575, mean=0.10 p.p.m.), tank farm (n=9, mean=0.65 p.p.m.), waste treatment (n=446, mean=0.13 p.p.m.), and other areas (n=460, mean=0.062 p.p.m.). The most frequently sampled task was sample collection (n=218, mean=0.40 p.p.m.). Job title and area did not significantly impact task-related exposures. Airborne concentrations were significantly lower after 1990 than before 1990. Results of this task-focused study may be useful when analyzing benzene exposures at other refineries.

Managing Exposure to Benzene and Total Petroleum Hydrocarbons at Two Oil Refineries 1977-2014.

Science.gov (United States)

Tuomi, Tapani; Veijalainen, Henna; Santonen, Tiina

2018-01-24

Air concentrations of and inhalation exposure to total petroleum hydrocarbons (TPH) and benzene was monitored separately at two oil refineries from 1977 to 2014. Prevention policies and control measures that may explain changes were surveyed. The aim was to evaluate how the application of of Occupational Health and Safety Assessment Series OHSAS 18001.04 principles as well as Environmental protection Agency EPA and European Oil Company Organisation for Environment, Health and Safety CONCAWE practices have influenced air concentrations. Benzene air concentrations declined in 11 of 17 units, six of which were associated with declining exposures. Benzene air concentrations declined across all units on average by 46%. This amounts to an average yearly decline of 1.7%. TPH air concentrations declined in 10 of 17 units, seven of which were associated with declining exposures. The average decline in TPH air concentrations was 49%, corresponding to 1.3% per year. As a result, average working day exposure in 10 of 17 units have declined significantly and today, benzene and TPH exposure in most units are well below 10% of the current Occupational Exposure Limit (OEL 8h :s). A decline in air concentrations have coincided with consistent implementation of control measures. Such measures include on-line monitoring of leaks; benzene recovery; floating container roofs; improved valves and seals; hermetic pumps; recovery of loading gases and instalment of torches in terminals; cutback in coke combustion; a new production line spanning directly from the dock to aromatics production; and recovery of loading gases in the doc. Other tools in exposure management include personal leak monitors, on-line measurements, monitoring campaigns, risk assessment, and availability and user training of protective equipment. However, improvements are still needed. Hydrocarbon or benzene air concentrations have not declined in 8 of 17 units, in some of which concentrations exceed 10% of the relevant

Electrochemical removal of phenol from oil refinery wastewater.

Science.gov (United States)

Abdelwahab, O; Amin, N K; El-Ashtoukhy, E-S Z

2009-04-30

This study explores the possibility of using electrocoagulation to remove phenol from oil refinery waste effluent using a cell with horizontally oriented aluminum cathode and a horizontal aluminum screen anode. The removal of phenol was investigated in terms of various parameters namely: pH, operating time, current density, initial phenol concentration and addition of NaCl. Removal of phenol during electrocoagulation was due to combined effect of sweep coagulation and adsorption. The results showed that, at high current density and solution pH 7, remarkable removal of 97% of phenol after 2h can be achieved. The rate of electrocoagulation was observed to increase as the phenol concentration decreases; the maximum removal rate was attained at 30 mg L(-1) phenol concentration. For a given current density using an array of closely packed Al screens as anode was found to be more effective than single screen anode, the percentage phenol removal was found to increase with increasing the number of screens per array. After 2h of electrocoagulation, 94.5% of initial phenol concentration was removed from the petroleum refinery wastewater. Energy consumption and aluminum Electrode consumption were calculated per gram of phenol removed. The present study shows that, electrocoagulation of phenol using aluminum electrodes is a promising process.

Urinary excretion of platinum from South African precious metals refinery workers.

Science.gov (United States)

Linde, Stephanus J L; Franken, Anja; du Plessis, Johannes L

2018-03-30

Urinary platinum (Pt) excretion is a reliable biomarker for occupational Pt exposure and has been previously reported for precious metals refinery workers in Europe but not for South Africa, the world's largest producer of Pt. This study aimed to quantify the urinary Pt excretion of South African precious metals refinery workers. Spot urine samples were collected from 40 workers (directly and indirectly exposed to Pt) at two South African precious metals refineries on three consecutive mornings prior to their shifts. Urine samples were analysed for Pt using inductively coupled plasma-mass spectrometry and were corrected for creatinine content. The urinary Pt excretion of workers did not differ significantly between sampling days. Urinary Pt excretions ranged from work area (P=0.0006; η 2 =0.567) and the number of years workers were employed at the refineries (P=0.003; η 2 =0.261) influenced their urinary Pt excretion according to effect size analyses. Directly exposed workers had significantly higher urinary Pt excretion compared with indirectly exposed workers (P=0.007). The urinary Pt excretion of South African precious metals refinery workers reported in this study is comparable with that of seven other studies conducted in precious metals refineries and automotive catalyst plants in Europe. The Pt body burden of workers is predominantly determined by their work area, years of employment in the refineries and whether they are directly or indirectly exposed to Pt. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2018. All rights reserved. No commercial use is permitted unless otherwise expressly granted.

Allowance Allocation and CO2 intensity of the EU15 and Norwegian refineries

International Nuclear Information System (INIS)

Nilsson, Kristina; Zetterberg, Lars; Aahman, Markus

2005-02-01

On 1 January 2005, the European Union Emission Trading Scheme (EU ETS) was launched. The launch has been preceded by an allocation process in each of the Member States. The main objective of this study was to analyse the allocation in relation to CO 2 efficiency for the mineral oil refining sector. A CO 2 intensity index for mineral oil refineries has been defined and calculated for the refineries within the EU15 and Norway. The IVL CO 2 intensity index is based both on the Solomon Energy Intensity Index (EII), an assumed fuel mix, and process-specific emissions. Due to uncertainties in input data, the determined values for the individual refineries are quite uncertain. However, the regional values can be used to identify trends. It was concluded that there are substantial differences in the CO 2 intensity between refineries within different regions/countries in the EU and these differences have not been considered in the allocation process. Only a few countries have mentioned energy efficiency or reduction potential due to CO 2 intensity of fuels used. Only one country (Denmark) has explicitly given a benchmark that will be used for allocation to new mineral oil refineries. The allocation has generally been based on historic emissions, which will result in refineries with historically higher emissions being allocated larger amounts than refineries with historically lower emissions. This might be favourable for refineries that recently have performed emission-reducing measures but might be less favourable for refineries that during a long time period have implemented emission-reducing measures

Enterprise Integration of Management and Automation in a Refinery

Science.gov (United States)

Wang, Chengen

Traditionally, problems in a petroleum refinery were separately modeled and solved with respect to disciplines. The segregated implementations of various disciplinary technologies resulted in considerable barriers impeding the pursuit of global optimal performance. It is recognized that enterprise-wide integration of the managerial and automation systems is of fundamental significance for refineries to promptly respond to global market requirements. In this paper, the technical implementations are disciplinarily categorized into managerial and automatic systems. Then, typical managerial and automatic implementations in a refinery are depicted to give an insight perception of the heterogeneous data sources manipulated by these systems. Finally, an integration approach based on data reconciliation techniques is proposed to link up the heterogeneous data sources.

An investigation of the matrix sensitivity of refinery gas analysis using gas chromatography with flame ionisation detection.

Science.gov (United States)

Ferracci, Valerio; Brown, Andrew S; Harris, Peter M; Brown, Richard J C

2015-02-27

The response of a flame ionisation detector (FID) on a gas chromatograph to methane, ethane, propane, i-butane and n-butane in a series of multi-component refinery gas standards was investigated to assess the matrix sensitivity of the instrument. High-accuracy synthetic gas standards, traceable to the International System of Units, were used to minimise uncertainties. The instrument response exhibited a small dependence on the component amount fraction: this behaviour, consistent with that of another FID, was thoroughly characterised over a wide range of component amount fractions and was shown to introduce a negligible bias in the analysis of refinery gas samples, provided a suitable reference standard is employed. No significant effects of the molar volume, density and viscosity of the gas mixtures on the instrument response were observed, indicating that the FID is suitable for the analysis of refinery gas mixtures over a wide range of component amount fractions provided that appropriate drift-correction procedures are employed. Copyright © 2015 Elsevier B.V. All rights reserved.

Reducing refinery CO2 emissions through amine solvent upgrade and optimization

Energy Technology Data Exchange (ETDEWEB)

Alonso, Thiago V.; Valenzuela, Michelle [The Dow Chemical Company, Midland, MI (United States)

2012-07-01

Regional initiatives are underway to reduce and limit the emissions of greenhouse gases. With CO2 emissions making up over 80% of the greenhouse gases, cap-and-trade programs will focus on those industries that consume the most energy. Refineries are among the top energy consumers and are seeking opportunities to reduce usage. With tightening margins, energy management programs will not only help refineries meet CO{sub 2} emission regulations, but can also provide a competitive advantage. With the trend towards heavier and higher sulfur containing crudes, refineries are increasing processing capabilities, which can include capital-intensive projects and additional energy consumption. Energy conservation plans should include optimization of these processes. One area to consider includes the acid gas removal systems in refineries. Through the selection and use of optimal solvents and implementation of energy efficiency techniques, which require minimal capital investment and expenditures, refineries can reduce energy usage, overall CO{sub 2} emissions, and total cost in acid gas systems. This paper will discuss these approaches and share case studies detailing the implementation and results. (author)

Control of occupational exposure to phenol in industrial wastewater treatment plant of a petroleum refinery in Alexandria, Egypt: An intervention application case study.

Science.gov (United States)

Zaki, Gehan R; El-Marakby, Fadia A; Ramadan, Alaa El-Din K; Issa, Ahmed I; Nofal, Faten H

2016-11-01

Phenol exposure is one of the hazards in the industrial wastewater treatment basin of any refinery. It additively interacts with hydrogen sulfide emitted from the wastewater basin. Consequently, its concentration should be greatly lower than its threshold limit value. The present study aimed at controlling occupational exposure to phenol in the work environment of wastewater treatment plant in a refinery by reducing phenolic compounds in the industrial wastewater basin. This study was conducted on both laboratory and refinery scales. The first was completed by dividing each wastewater sample from the outlets of different refinery units into three portions; the first was analyzed for phenolic compounds. The second and third were for laboratory scale charcoal and bacterial treatments. The two methods were compared regarding their simplicities, design, and removal efficiencies. Accordingly, bacterial treatment by continuous flow of sewage water containing Pseudomonas Aeruginosa was used for refinery scale treatment. Laboratory scale treatment of phenolic compounds revealed higher removal efficiency of charcoal [100.0(0.0) %] than of bacteria [99.9(0.013) %]. The refinery scale bacterial treatment was [99.8(0.013) %] efficient. Consequently, level of phenol in the work environment after refinery-scale treatment [0.069(0.802) mg/m(3)] was much lower than that before [5.700(26.050) mg/m(3)], with removal efficiency of [99.125(2.335) %]. From the present study, we can conclude that bacterial treatment of phenolic compounds in industrial wastewater of the wastewater treatment plant using continuous flow of sewage water containing Pseudomonas Aeruginosa reduces the workers' exposure to phenol.

40 CFR 73.90 - Allowance allocations for small diesel refineries.

Science.gov (United States)

2010-07-01

... refineries. 73.90 Section 73.90 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) SULFUR DIOXIDE ALLOWANCE SYSTEM Small Diesel Refineries § 73.90 Allowance allocations... application for certification, submitted to the address in § 73.13 of this chapter, shall include the...

Comparison of Risk Assessment Using HAZOP and ETBA Techniques: Case Study of a Gasoline Refinery Unit in Iran

Directory of Open Access Journals (Sweden)

Shirazeh Arghami

2015-12-01

Full Text Available Background: Prevention of accidents—a crucial requirement in oil industries—involves hazard recognition, risk assessment, and corrective actions. The purpose of this study was to compare the ETBA and HAZOP techniques for risk assessment in a gasoline refinery unit. Methods: In this case study, data were collected using process flow diagram, walking–talking through method, piping and instrumentation diagram, and direct observations. Worksheets for both techniques were filled on the basis of the risk assessment matrix MIL-STD-882E. Results: The HAZOP method identified 44 deviations attributable to 118 causes. In addition, 11.37% of the identified hazards were associated with unacceptable risk, and 36.36%, with unfavorable risk. The ETBA method detected 10 groups of energy (24 subgroups; 33 hazards were detected, 10.62% of which were associated with unacceptable risk. Conclusion: HAZOP proved to be the more powerful technique for the prediction and identification of hazards. However, ETBA detected certain hazards that were not identifiable using HAZOP. Therefore, a combination of these two methods is desirable for the assessment of hazard risk in process industries.

How to perform Energy Trace & BarrierAnalysis (ETBA in industries? Acase study in Isomax Unit of Tehran refinery

Directory of Open Access Journals (Sweden)

J Adl

2006-04-01

Full Text Available Background and Aims: People, equipments and properties are continuously exposed tonumerous hazards while technology develops. The global increasing rate of accidents and workrelatedinjuries, especially in Iran, is an evidence for these hazards. There are numerous methodsfor hazard analysis such as the Energy Trace & Barrier Analysis (ETBA, which is a process ofanalysis based on system safety for detecting and definition of hazards and also risks that maycause system damage.Method: This is a case study in the Isomax unit of Tehran refinery and allied section. Datecollection and completion of the ETBAsheets were conducted through observation and interviewmethod with experts, walking - talking through method, investigation of technical and operativedocuments.Results: Twelve different kinds of energy and 28 subgroups were investigated. The types ofenergies, existence barriers, vulnerable targets, risk assessment code, and adequacy of barriers aswell as recommendations for decreasing risk level through tolerable risk were identified.Conclusion: The results of this study show potential application of ETBA in different industries,especially chemical industry, which is a method for identification hazards and prevention ofwork-related injuries.

Proposal of a procedure of the operative program optimization of production in the petroleum refinery of PCK / Oder, Federal Republic of Germany

Directory of Open Access Journals (Sweden)

Josef Maily

2015-11-01

Full Text Available The blended of raw petroleum is an operation that can be optimized and it is based on a great quantity of knowledge and experience. The planning of these operations consists in obtaining a mixture of components with different properties and specification as octane, flow, level of sulfur etc., besides keeping in mind the existent capacities and the demand. This is considered important in this type of industries, since their profitability depends on finding the good mixture, due to the variability of the prices in the final products. The objective of this paper is to determine the good variant of production of the refinery PCK/Oder, Federal Republic of Germany that achieves the maximum of utilities, by means of the Parametric Lineal Programming. The preliminary validation, presents advantages in the utilities of until 4 %, in comparison with the use of the current method.

40 CFR 80.1280 - How are refinery benzene baselines calculated?

Science.gov (United States)

2010-07-01

... benzene). i = Individual batch of gasoline produced at the refinery from January 1, 2004 through December 31, 2005. n = Total number of batches of gasoline produced at the refinery from January 1, 2004... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Benzene Averaging, Banking and Trading...

Environmental performance of an innovative waste refinery based on enzymatic treatment

DEFF Research Database (Denmark)

Tonini, Davide; Astrup, Thomas

2011-01-01

for virgin material and saving fossil resources. In this paper a life-cycle assessment of a pilot-scale waste refinery for the enzymatic treatment of municipal solid waste (MSW) is presented. The refinery produced a liquid (liquefied organic materials and paper) and a solid fraction (non-degradable materials......Decrease of fossil fuel dependence and global warming mitigation has become increasingly important issues during the last decades. With respect to waste management higher recycling rates for valuable materials as well as energy recovery from waste streams could play a significant role substituting......) from the waste. The waste refinery was compared to alternative treatments such as incineration, bioreactor landfill and mechanical-biological treatment followed by utilization of the RDF (refuse-derived fuel) for energy. The performance of the waste refinery turned out to be comparable...

Managing Exposure to Benzene and Total Petroleum Hydrocarbons at Two Oil Refineries 1977–2014

Science.gov (United States)

Tuomi, Tapani; Veijalainen, Henna; Santonen, Tiina

2018-01-01

Air concentrations of and inhalation exposure to total petroleum hydrocarbons (TPH) and benzene was monitored separately at two oil refineries from 1977 to 2014. Prevention policies and control measures that may explain changes were surveyed. The aim was to evaluate how the application of of Occupational Health and Safety Assessment Series OHSAS 18001.04 principles as well as Environmental protection Agency EPA and European Oil Company Organisation for Environment, Health and Safety CONCAWE practices have influenced air concentrations. Benzene air concentrations declined in 11 of 17 units, six of which were associated with declining exposures. Benzene air concentrations declined across all units on average by 46%. This amounts to an average yearly decline of 1.7%. TPH air concentrations declined in 10 of 17 units, seven of which were associated with declining exposures. The average decline in TPH air concentrations was 49%, corresponding to 1.3% per year. As a result, average working day exposure in 10 of 17 units have declined significantly and today, benzene and TPH exposure in most units are well below 10% of the current Occupational Exposure Limit (OEL8h:s). A decline in air concentrations have coincided with consistent implementation of control measures. Such measures include on-line monitoring of leaks; benzene recovery; floating container roofs; improved valves and seals; hermetic pumps; recovery of loading gases and instalment of torches in terminals; cutback in coke combustion; a new production line spanning directly from the dock to aromatics production; and recovery of loading gases in the doc. Other tools in exposure management include personal leak monitors, on-line measurements, monitoring campaigns, risk assessment, and availability and user training of protective equipment. However, improvements are still needed. Hydrocarbon or benzene air concentrations have not declined in 8 of 17 units, in some of which concentrations exceed 10% of the relevant

Investigation reactor D-2201 polypropylene production unit using nuclear technique

International Nuclear Information System (INIS)

Wibisono; Sugiharto; Jefri Simanjuntak

2016-01-01

D-2201 reactor is a unit in the polypropylene production process at Pertamina Refinery Unit III Plaju. Reactor with a capacity of 45 kilo liter is not operated in normal operation condition. The validity of liquid level indicator on the unit is doubtful when refers to the production quality. Gamma source of 150 mCi Cobalt-60 and a scintillation detector had been used to scan the outer wall of the reactor to detect the liquid level during operation with a capacity of 40 %. Measurements were made along the reactor walls with 25 mm scan resolution and 5 seconds time sampling. Experiment result shows that the liquid level at the position of 40 % and at normal level position are not observed. Investigation did not find the liquid level above normal. D-2201 is diagnose not normal operating condition diagnosed with liquid abundant passed the recommended limits. Investigation advised to repair or to calibrate the liquid level indicator which is currently installed. (author)

Fuel specification, energy consumption and CO2 emission in oil refineries

International Nuclear Information System (INIS)

Szklo, Alexandre; Schaeffer, Roberto

2007-01-01

The more stringent environmental quality specifications for oil products worldwide are tending to step up energy use and, consequently, CO 2 emissions at refineries. In Brazil, for example, the stipulated reduction in the sulfur content of diesel and gasoline between 2002 and 2009 should increase the energy use of Brazil's refining industry by around 30%, with effects on its CO 2 emissions. Thus, the world refining industry must deal with trade-offs between emissions of pollutants with local impacts (due to fuel specifications) and emissions of pollutants with global impacts (due to the increased energy use at refineries to remove contaminants from oil products). Two promising technology options for refineries could ease this clash in the near-to-mid term: the reduction per se of the energy use at the refinery; and the development of treatment processes using non-hydrogen consuming techniques. For instance, in Brazilian refineries, the expanded energy use resulting from severe hydrotreatment to comply with the more stringent specifications of oil products may be almost completely offset by energy saving options and alternative desulfurization techniques, if barriers to invest in technological innovations are overcome. (author)

Allowance Allocation and CO{sub 2} intensity of the EU15 and Norwegian refineries

Energy Technology Data Exchange (ETDEWEB)

Nilsson, Kristina; Zetterberg, Lars; Aahman, Markus

2005-02-01

On 1 January 2005, the European Union Emission Trading Scheme (EU ETS) was launched. The launch has been preceded by an allocation process in each of the Member States. The main objective of this study was to analyse the allocation in relation to CO{sub 2} efficiency for the mineral oil refining sector. A CO{sub 2} intensity index for mineral oil refineries has been defined and calculated for the refineries within the EU15 and Norway. The IVL CO{sub 2} intensity index is based both on the Solomon Energy Intensity Index (EII), an assumed fuel mix, and process-specific emissions. Due to uncertainties in input data, the determined values for the individual refineries are quite uncertain. However, the regional values can be used to identify trends. It was concluded that there are substantial differences in the CO{sub 2} intensity between refineries within different regions/countries in the EU and these differences have not been considered in the allocation process. Only a few countries have mentioned energy efficiency or reduction potential due to CO{sub 2} intensity of fuels used. Only one country (Denmark) has explicitly given a benchmark that will be used for allocation to new mineral oil refineries. The allocation has generally been based on historic emissions, which will result in refineries with historically higher emissions being allocated larger amounts than refineries with historically lower emissions. This might be favourable for refineries that recently have performed emission-reducing measures but might be less favourable for refineries that during a long time period have implemented emission-reducing measures.

[Factors of work environment and employment of workers in production of fuels and solvents at the oil refinery].

Science.gov (United States)

Chebotarev, P A; Kharlashova, N V

2012-01-01

Factors of the industrial environment and labor activity of workers of manufacture propellants and solvents at the oil refining enterprise. Working conditions of workers at all installations of manufacture No 1 JSC "Naftan" of Novopolotsk of Byelorussia (production of fuels and solvents). Hygienic evaluation of working conditions of persons working in the production of fuels and solvents at the oil refinery. Sanitary description of the production with hygienic analysis of project design and technological documentation, qualitative and quantitative characteristics of conventional methods in the work environment and working process of employees in the workplace for the main modes of operation of the equipment. The working environment of refineries is influenced by a number of simultaneously acting factors, which have different material nature and characteristics of the action on the human body, the workers in production of fuels and solvents at the refinery, are exposed to a variety of hazardous and dangerous factors of production, a chemical factor is prevalent, of course.

77 FR 56421 - Standards of Performance for Petroleum Refineries; Standards of Performance for Petroleum...

Science.gov (United States)

2012-09-12

... Parts 9 and 60 Standards of Performance for Petroleum Refineries; Standards of Performance for Petroleum...-9672-3] RIN 2060-AN72 Standards of Performance for Petroleum Refineries; Standards of Performance for Petroleum Refineries for Which Construction, Reconstruction, or Modification Commenced After May 14, 2007...

Preliminary life-cycle assessment of biomass-derived refinery feedstocks for reducing CO2 emissions

International Nuclear Information System (INIS)

Marano, J.J.; Rogers, S.; Spath, P.L.; Mann, M.K.

1995-01-01

The US by ratification of the United Nations Framework Convention on Climate Change has pledged to emit no higher levels of greenhouse gases in the year 2000 than it did in 1990. Biomass-derived products have been touted as a possible solution to the potential problem of global warming. However, past studies related to the production of liquid fuels, chemicals, gaseous products, or electricity from biomass, have only considered the economics of producing these commodities. The environmental benefits have not been fully quantified and factored into these estimates until recently. Evaluating the environmental impact of various biomass systems has begun using life-cycle assessment. A refinery Linear Programming model previously developed has been modified to examine the effects of CO 2 -capping on the US refining industry and the transportation sector as a whole. By incorporating the results of a CO 2 emissions inventory into the model, the economic impact of emissions reduction strategies can be estimated. Thus, the degree to which global warming can be solved by supplementing fossil fuels with biomass-derived products can be measured, allowing research and development to be concentrated on the most environmentally and economically attractive technology mix. Biomass gasification to produce four different refinery feedstocks was considered in this analysis. These biomass-derived products include power, fuel gas, hydrogen for refinery processing, and Fischer-Tropsch liquids for upgrading and blending into finished transportation fuels

Gasification in petroleum refinery of 21. century; La gazeification dans la raffinerie du petrole du 21. siecle

Energy Technology Data Exchange (ETDEWEB)

Furimsky, E. [IMAF Group, Ottawa, Ontario (Canada)

1999-07-01

The worldwide trends in the crude oil supply indicate a continuous increase of the heavy crudes. The increase in the yield of distillation residues is complemented by an increase in their sulfur content. Additional distillates are produced by upgrading the residues. The upgrading step generates final residues, such as visbreaking tar, coke and asphalt which are produced by visbreaking, coking and de-asphalting, respectively. The final residues can be converted to usable products such as hydrogen, steam, electricity, ammonia and chemicals. For this purpose, gasification has emerged as the technology of choice because of its superior environmental performance when compared with the competing means for residue utilization. Also, refinery sludges can be co-gasified with the final residues and as such, be converted to usable products. If integrated with the petroleum refinery, gasification can diminish any environmental problems associated with residue and sludge disposal. The economic indicators of the refinery can improve as well. The trends in deregulation of the power market enable petroleum refineries to enter this lucrative market either alone or in a partnership with the utilities. The potential of co-production of chemicals and steam with electricity offers the flexibility to respond to market demands. Gasification technology is commercially proven. Among several types, entrained bed gasifiers are the gasifiers of choice. A number of commercial projects in Europe, Asia and United States use a gasifier employing either a slurry feeding system or a dry feeding system. (author)

Opportunities and challenges at the interface between petrochemistry and refinery. Preprints

Energy Technology Data Exchange (ETDEWEB)

Ernst, S.; Leitner, W.; Lercher, J.A.; Nees, F.; Perego, C.; Rupp, M.; Santacesaria. E. (eds.)

2007-07-01

Within the DGMK/SCI-Conference 'Opportunities and Challenges at the Interface between Petrochemistry and refinery' between 10th and 12th October, 2007, in Hamburg (Federal Republic of Germany) the following lectures were held: (a) Maximizing petrochemicals from refineries (B. Glover, T. Foley, S. Frey); (b) Opportunities and challenges at the interface between petrochemistry and refinery - the OMV view (J. Lichtscheidl); (c) Aspects of petrochemistry in a fuels refinery (J. Essler, J. Mielicke, T. Maier); (d) Enhanced propylene production in FCC by novel catalytic materials (C.P. Kelkar, D. Harris, M. Xu, J. Fu); (e) Retrofit of an MTBE-unit to ETBE (A. Rix, U. Peters); (f) Opportunities and challenges at the interface between petrochemistry and refinery - The BASF perspectives (H.-J. Blankertz); (g) Light olefins - challenges from new production routes? (H. Zimmermann); (h) Conversion of heavy aromatic hydrocarbons to valuable synthetic feed for steamcrackers (A. Cesana, L. Dalloro, F. Rivetti, R. Buzzoni, R. Bignazzi); (i) C{sub 4} olefin/paraffin separation over the metal organic framework material Cu{sub 3}BTC{sub 2} (S. Kunz, O. Tangermann, M. Hartmann); (j) Glycerol tertiary butyl ethers via etherification of glycerol with isobutene (A. Behr); (k) Biorefineries: From concepts to reality? (K. Wagemann); (l) Modern concepts in reactor and separation technologies (D. Agar); (m) Innovative reactive distillation process for the production of the MTBE substitute isooctane from isobutene (M. Chalakova, R. Kaur, H. Freund, S. Mahajani, K. Sundmacher); (n) Supported ionic liquid phase (SILP) systems - novel fixed bed reactor concepts for homogeneous catalysis (A. Riisager, R. Fehrmann, M. Haumann, M. Jakuttis, J. Joni, P. Wasserscheid); (o) Selective oxidations to industrial intermediates (S. Schunck); (p) Perspectives of industrial realization for propane oxidative dehydrogenation over chromium oxide catalysts (A.L. Lapidus, N.A. Gaidai, Yu. A. Agafonov, M

40 CFR 63.7886 - What are the general standards I must meet for my affected remediation material management units?

Science.gov (United States)

2010-07-01

... refinery) is no longer subject to this subpart. (3) If the remediation material management unit is also... emissions limitations and work practice standards under the other subpart (e.g., you install and operate the required air pollution controls or have implemented the required work practice to reduce HAP emissions to...

40 CFR 80.1238 - How is a refinery's or importer's average benzene concentration determined?

Science.gov (United States)

2010-07-01

... concentration determined? (a) The average benzene concentration of gasoline produced at a refinery or imported... percent benzene). i = Individual batch of gasoline produced at the refinery or imported during the applicable averaging period. n = Total number of batches of gasoline produced at the refinery or imported...

Extra heavy oil and refinery residues upgrading through Eni Slurry Technology : first EST commercial unit

Energy Technology Data Exchange (ETDEWEB)

Rispoli, G.; Sanfilippo, D.; Amoroso, A [Eni S.p.A., Rome (Italy)

2009-07-01

The production of heavy crude oils is projected to continue to grow in the upstream oil industry given that large reserves of unconventional extra heavy crude and bitumen exist in several geographic areas including Canada and Venezuela. As reserves of conventional crude oil continue to decline, these unconventional feedstocks are becoming an opportunity to pursue, but they require effective technologies for upgrading and meeting the growing demand for light and middle distillate fuels. This paper described the proprietary technology that offers a solution to upstream and downstream oil producers for bottom-of-the-barrel upgrading. En i Slurry Technology (EST) is constructing an industrial plant in its Sannazzaro refinery in Italy. The plant is designed to convert 23,000 BPSD of vacuum residue into high quality diesel and other valuable refinery streams such as liquefied petroleum gas, naphtha and jet fuel. EST is an H-addition process characterized by the use of a special homogeneous isothermal intrinsically safe reactor, and of a nano-dispersed non-ageing catalyst. EST converts more than 98 per cent of any type of residues to about 110 per cent volume of light products and distillates or extra heavy oils to high quality bottomless SCO. In typical performance, HDS is greater than 85 per cent, HDM greater than 99 per cent and HDCCR greater than 97 per cent. EST also achieves the target of zero fuel oil - zero coke. 12 refs., 4 tabs., 5 figs.

Organization of Control Units with Operational Addressing

OpenAIRE

Alexander A. Barkalov; Roman M. Babakov; Larysa A. Titarenko

2012-01-01

The using of operational addressing unit as the block of control unit is proposed. The new structure model of Moore finite-state machine with reduced hardware amount is developed. The generalized structure of operational addressing unit is suggested. An example of synthesis process for Moore finite-state machine with operational addressing unit is given. The analytical researches of proposed structure of control unit are executed.

Production of ethanol from refinery waste gases. Phase 2, technology development, annual report

Energy Technology Data Exchange (ETDEWEB)

Arora, D.; Basu, R.; Phillips, J.R.; Wikstrom, C.V.; Clausen, E.C.; Gaddy, J.L.

1995-07-01

Oil refineries discharge large volumes of H{sub 2}, CO, and CO{sub 2} from cracking, coking, and hydrotreating operations. This program seeks to develop a biological process for converting these waste gases into ethanol, which can be blended with gasoline to reduce emissions. Production of ethanol from all 194 US refineries would save 450 billion BTU annually, would reduce crude oil imports by 110 million barrels/year and emissions by 19 million tons/year. Phase II efforts has yielded at least 3 cultures (Clostridium ljungdahlii, Isolate O-52, Isolate C-01) which are able to produce commercially viable concentrations of ethanol from CO, CO{sub 2}, and H{sub 2} in petroleum waste gas. Single continuous stirred tank reactor studies have shown that 15-20 g/L of ethanol can be produced, with less than 5 g/L acetic acid byproduct. Culture and reactor optimization in Phase III should yield even higher ethanol concentrations and minimal acetic acid. Product recovery studies showed that ethanol is best recovered in a multi-step process involving solvent extraction/distillation to azeotrope/azeotropic distillation or pervaporation, or direct distillation to the azeotrope/azeotropic distillation or pervaporation. Projections show that the ethanol facility for a typical refinery would require an investment of about $30 million, which would be returned in less than 2 years.

Energy demand analysis of Port-Harcourt refinery, Nigeria and its policy implications

International Nuclear Information System (INIS)

Jesuleye, O.A.; Siyanbola, W.O.; Sanni, S.A.; Ilori, M.O.

2007-01-01

This paper analyses energy demand of Port-Harcourt refinery, Nigeria, based on information obtained from its annual publications, backed-up by spot interviews. The analytical approach adopted for the study involves the calculation of energy intensities to determine the refinery's annual energy demand for various energy types considered from 1989 to 2004. The results showed that the actual energy demand per year for processing crude oil into refined products, exceeded, in varying degrees the stipulated refinery standard of 4 barrels of oil equivalent (BOE) per 100 BOE. It varied from 4.28-8.58 BOE per 100 BOE. In terms of energy demand efficiency, this implies very poor performance of the refinery during the 16-year period under investigation. The excess demand which translates to an average daily wastage of about 2005 BOE is estimated to be $56,196 (US Dollars) based on the 2003 OPEC basket price of $28.0213 per barrel. Lack of optimal fuel utilization-mix and non-compliance with the Turn-Around-Maintenance schedules were attributed to the refinery's inefficient energy demand pattern

An Approximation Solution to Refinery Crude Oil Scheduling Problem with Demand Uncertainty Using Joint Constrained Programming

OpenAIRE

Duan, Qianqian; Yang, Genke; Xu, Guanglin; Pan, Changchun

2014-01-01

This paper is devoted to develop an approximation method for scheduling refinery crude oil operations by taking into consideration the demand uncertainty. In the stochastic model the demand uncertainty is modeled as random variables which follow a joint multivariate distribution with a specific correlation structure. Compared to deterministic models in existing works, the stochastic model can be more practical for optimizing crude oil operations. Using joint chance constraints, the demand unc...

A newer concept of setting up coal refineries in coal utilising industries through environmentally sound clean coal technology of organosuper refining of coals

International Nuclear Information System (INIS)

Sharma, D.K.

1994-01-01

In order to reduce the losses of premium organic matter of coal and its immense potential energy which is present in the form of stronger interatomic and intramolecular bonding energies, a newer and convenient technique of recovering the premium organic matter from low grade coals by organosuper-refining technique which operates under ambient pressure conditions has been developed. The residual coal obtained can be used as environmentally clean fuel or as a feedstock for the industries based on carbonization and gasification. It is suggested that a beginning be made by setting up coal refineries in coal utilizing industries on the basis of the presently developed new technology of organosuper-refining of coals to recover premium grade organic chemical feed stocks from coals before utilizing coal by techniques such as bubble bed or recirculatory fluidized bed or pulverized coal combustion in thermal power stations, carbonization in steel plants or other carbonization units, gasification in fertilizer industries or in integrated coal gasification combined cycle power generation. Thus, coal refineries may produce value added aromatic chemical feed stocks, formed coke or coke manufacturing; and carbon fillers for polymers. (author). 100 refs., 1 fig

First refinery opened in Kyrgyz Republic

International Nuclear Information System (INIS)

Anon.

1996-01-01

The first oil refinery in the Kyrgyz Republic was opened on 5 October 1996 in Jalalabad in a ceremony attended by the President of the Central Asian country, Askar Akaev. The 10,000 barrels of oil per day (bopd) modular refinery has been financed by the Canadian oil junior, Kyrgoil Corporation, which has also formed a joint venture with the national oil company, Kyrgyzneft, to redevelop where viable the 628 underperforming oil wells in the Kyrgyz Republic sector of the Fergana Basin. The opening is the first significant milestone in a programme initiated by Akaev to develop the oil production industry in the Kyrgyz Republic. Currently the country imports more than 50,000 barrels of oil equivalent per day, mostly from Kazakhstan. In the year ending March 1996, 110 million was spent on imports of fuel products, an amount that exceeds the trade deficit over the same period. Built in only eight months, the Pound 12 million refinery will gradually be brought to full capacity. By January, it is expected that more than 5,000 barrels of gasoline, diesel and fuel oil will be produced every day. Although there is some crude oil in storage, the ramping of production is tied into the programme of workovers of the existing wells. There are no current plans to import crude, although most of the infrastructure is in place should it become necessary. (author)

Fitting partially upgraded oils into pipelines and refinery markets

International Nuclear Information System (INIS)

Flaherty, G.

2000-01-01

The logistics of transporting partially upgraded crudes in feeder and trunk pipeline systems is discussed. Logistic alternatives are evaluated against economic drivers for partial upgrading, and the impact of crude transportation logistics on the quality of crude that reaches refinery gates is assessed. The potential advantages of partial upgrading in the field are reviewed (including reduction of diluent required to meet pipeline density and viscosity specifications, cost and availability of diluent, limitations in diluent transportation infrastructure, increased chemical stability, increased attractiveness to refineries, shortage of refinery coking capacity, higher market value). The pros and cons of various upgrading processes, and the implications of each for producers and refiners are explained. The advantages of moving to large common streams, as opposed to the concept of 'boutique' crudes, are stressed as the surest way for producers to realize the maximum value of partially upgraded crudes

Refineries in Europe under pressure

International Nuclear Information System (INIS)

Widdershoven, C.

2008-01-01

Current oil price developments and the economic and financial crisis are leading to a negative situation for the European refining sector. Analysts expect that a number of European oil refineries will lower their production in the coming months as a result of decreased petrol demand. [mk] [nl

More evidence of unpublished industry studies of lead smelter/refinery workers

Science.gov (United States)

2015-01-01

Background Lead smelter/refinery workers in the US have had significant exposure to lead and are an important occupational group to study to understand the health effects of chronic lead exposure in adults. Recent research found evidence that studies of lead smelter/refinery workers have been conducted but not published. This paper presents further evidence for this contention. Objectives To present further evidence of industry conducted, unpublished epidemiologic studies of lead smelter/refinery workers and health outcomes. Methods Historical research relying on primary sources such as internal industry documents and published studies. Results ASARCO smelter/refinery workers were studied in the early 1980s and found to have increased risk of lung cancer and stroke in one study, but not in another. Conclusions Because occupational lead exposure is an on-going concern for US and overseas workers, all epidemiologic studies should be made available to evaluate and update occupational health and safety standards. PMID:26070220

Mild Biomass Liquefaction Process for Economic Production of Stabilized Refinery-Ready Bio-oil

Energy Technology Data Exchange (ETDEWEB)

Gangwal, Santosh [Southern Research, Durham, NC (United States); Meng, Jiajia [Southern Research, Durham, NC (United States); McCabe, Kevin [Southern Research, Durham, NC (United States); Larson, Eric [Princeton Univ., NJ (United States). Princeton Environmental Inst.; Mastro, Kelly [Southern Research, Durham, NC (United States)

2016-04-25

Southern Research (SR) in cooperation with U.S. Department of Energy (DOE), Bioenergy Technology Office (BETO), investigated a biomass liquefaction process for economic production of stabilized refinery-ready bio-oil. The project was awarded by DOE under a Funding Opportunity Announcement (DE-FOA-0000686) for Bio-oil Stabilization and Commoditization that intended to evaluate the feasibility of using bio-oil as a potential feedstock in an existing petroleum refinery. SR investigated Topic Area 1 of the FOA at Technology Readiness Level 2-3 to develop thermochemical liquefaction technologies for producing a bio-oil feedstock from high-impact biomass that can be utilized within a petroleum refinery. Bio-oil obtained from fast pyrolysis of biomass is a green intermediate that can be further upgraded into a biofuel for blending in a petroleum refinery using a hydro-deoxygenation (HDO) route. Co-processing pyrolysis bio-oil in a petroleum refinery is an attractive approach to leverage the refinery’s existing capital. However, the petroleum industry is reluctant to accept pyrolysis bio-oil because of a lack of a standard definition for an acceptable bio-oil feedstock in existing refinery processes. Also per BETO’s multiyear program plan, fast pyrolysis-based bio-fuel is presently not cost competitive with petroleum-based transportation fuels. SR aims to develop and demonstrate a cost-effective low-severity thermal liquefaction and hydrodeoxygenation (HDO) process to convert woody biomass to stabilized bio-oils that can be directly blended with hydrotreater input streams in a petroleum refinery for production of gasoline and/or diesel range hydrocarbons. The specific project objectives are to demonstrate the processes at laboratory scale, characterize the bio-oil product and develop a plan in partnership with a refinery company to move the technology towards commercialization.

Carbon Capture and Sequestration from a Hydrogen Production Facility in an Oil Refinery

Energy Technology Data Exchange (ETDEWEB)

Engels, Cheryl; Williams, Bryan, Valluri, Kiranmal; Watwe, Ramchandra; Kumar, Ravi; Mehlman, Stewart

2010-06-21

The project proposed a commercial demonstration of advanced technologies that would capture and sequester CO2 emissions from an existing hydrogen production facility in an oil refinery into underground formations in combination with Enhanced Oil Recovery (EOR). The project is led by Praxair, Inc., with other project participants: BP Products North America Inc., Denbury Onshore, LLC (Denbury), and Gulf Coast Carbon Center (GCCC) at the Bureau of Economic Geology of The University of Texas at Austin. The project is located at the BP Refinery at Texas City, Texas. Praxair owns and operates a large hydrogen production facility within the refinery. As part of the project, Praxair would construct a CO2 capture and compression facility. The project aimed at demonstrating a novel vacuum pressure swing adsorption (VPSA) based technology to remove CO2 from the Steam Methane Reformers (SMR) process gas. The captured CO2 would be purified using refrigerated partial condensation separation (i.e., cold box). Denbury would purchase the CO2 from the project and inject the CO2 as part of its independent commercial EOR projects. The Gulf Coast Carbon Center at the Bureau of Economic Geology, a unit of University of Texas at Austin, would manage the research monitoring, verification and accounting (MVA) project for the sequestered CO2, in conjunction with Denbury. The sequestration and associated MVA activities would be carried out in the Hastings field at Brazoria County, TX. The project would exceed DOE?s target of capturing one million tons of CO2 per year (MTPY) by 2015. Phase 1 of the project (Project Definition) is being completed. The key objective of Phase 1 is to define the project in sufficient detail to enable an economic decision with regard to proceeding with Phase 2. This topical report summarizes the administrative, programmatic and technical accomplishments completed in Phase 1 of the project. It describes the work relative to project technical and design activities

Fiscal 1999 basic survey report for promotion of joint implementation. Study on energy saving and CO2 reduction at Balikpapan refinery; 1999 nendo Balikpapan seiyusho ni okeru shoene CO{sub 2} sakugen chosa hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

Concerning the reduction of greenhouse gas emissions for the embodiment of clean development mechanisms (CDMs) in Indonesia, a survey is conducted about energy saving and CO2 reduction at its Balikpapan refinery. At the refinery, a crude-oil atmospheric distillation unit operates at 200,000 BPSD (barrels per stream day) and a vacuum distillation unit at 81,000 BPSD, with the fuel consumed by the two units discharging approximately 470,000 tons/year of CO2. The result of the survey discloses that there is need for some improvement in relation with heat recovery and that the great distance between the two distillation units presents a problem in relation with heat efficiency. To settle the problems, heat recovery will be enhanced and the fuel to be burned in the heating furnace will be reduced. A plan to modify the heat exchanger system is worked out using JGC Corporation's energy-saving technology, and a rough design is drafted for the modification. When the modification is carried out, there will be a CO2 reduction of 18,636-61,597 tons/year. The Pertamina also wants the plan to be realized, wishing that technical and financial aids will be available. The plan when realized will serve as a stimulus to the local community and to the industry as a whole. (NEDO)

Operable Unit Boundaries

Data.gov (United States)

U.S. Environmental Protection Agency — This dataset consists of operable unit data from multiple Superfund sites in U.S. EPA Region 8. These data were acquired from multiple sources at different times and...

Oil refinery dusts: morphological and size analysis by TEM.

Science.gov (United States)

Sielicki, Przemysław; Janik, Helena; Guzman, Agnieszka; Broniszewski, Mieczysław; Namieśnik, Jacek

2011-03-01

The objectives of this work were to develop a means of sampling atmospheric dusts on the premises of an oil refinery for electron microscopic study to carry out preliminary morphological analyses and to compare these dusts with those collected at sites beyond the refinery limits. Carbon and collodion membranes were used as a support for collection of dust particles straight on transmission electron microscopy (TEM) grids. Micrographs of the dust particles were taken at magnifications from ×4,000 to ×80,000 with a Tesla BS500 transmission electron microscope. Four parameters were defined on the basis of the micrographs: surface area, Feret diameter, circumference, and shape coefficient. The micrographs and literature data were used to classify the atmospheric dusts into six groups: particles with an irregular shape and rounded edges; particles with an irregular shape and sharp edges; soot and its aggregates; spherical particles; singly occurring, ultrafine dust particles; and particles not allocated to any of the previous five groups. The types of dusts found in all the samples were similar, although differences did exist between the various morphological parameters. Dust particles with the largest Feret diameter were present in sample 3 (mean, 0.739 μm)-these were collected near the refinery's effluent treatment plant. The particles with the smallest diameter were found in the sample that had been intended to be a reference sample for the remaining results (mean, 0.326 μm). The dust particles collected in the refinery had larger mean Feret diameters, even 100% larger, than those collected beyond it. Particles with diameters from 0.1 to 0.2 μm made up the most numerous group in all the samples collected in the refinery.

Oil refinery dusts: morphological and size analysis by TEM

Energy Technology Data Exchange (ETDEWEB)

Sielicki, Przemyslaw; Janik, Helena; Guzman, Agnieszka [Gdansk University of Technology, Department of Polymer Technology, Chemical Faculty, Gdansk (Poland); Broniszewski, Mieczyslaw [Environmental Protection Office, Lotos Group, Gdansk (Poland); Namiesnik, Jacek [Gdansk University of Technology, Department of Analytical Chemistry, Chemical Faculty, Gdansk (Poland)

2011-03-15

The objectives of this work were to develop a means of sampling atmospheric dusts on the premises of an oil refinery for electron microscopic study to carry out preliminary morphological analyses and to compare these dusts with those collected at sites beyond the refinery limits. Carbon and collodion membranes were used as a support for collection of dust particles straight on transmission electron microscopy (TEM) grids. Micrographs of the dust particles were taken at magnifications from x 4,000 to x 80,000 with a Tesla BS500 transmission electron microscope. Four parameters were defined on the basis of the micrographs: surface area, Feret diameter, circumference, and shape coefficient. The micrographs and literature data were used to classify the atmospheric dusts into six groups: particles with an irregular shape and rounded edges; particles with an irregular shape and sharp edges; soot and its aggregates; spherical particles; singly occurring, ultrafine dust particles; and particles not allocated to any of the previous five groups. The types of dusts found in all the samples were similar, although differences did exist between the various morphological parameters. Dust particles with the largest Feret diameter were present in sample 3 (mean, 0.739 {mu}m) - these were collected near the refinery's effluent treatment plant. The particles with the smallest diameter were found in the sample that had been intended to be a reference sample for the remaining results (mean, 0.326 {mu}m). The dust particles collected in the refinery had larger mean Feret diameters, even 100% larger, than those collected beyond it. Particles with diameters from 0.1 to 0.2 {mu}m made up the most numerous group in all the samples collected in the refinery. (orig.)

Material Balance And Reaction Kinetics Modeling For Penex Isomerization Process In Daura Refinery

Directory of Open Access Journals (Sweden)

Hamadi Adel Sharif

2017-01-01

Full Text Available Penex Deisohexanizer isomerization of light straight run naphtha is a significant process for petroleum refining and proved to be effective technology to produce gasoline components with a high octane number. Modeling of the chemical kinetic reactions is an important tool because it is a better tool for optimization of the experimental data into parameters used for industrial reactors. The present study deals on the isomerization process in Daura refinery. Material balance calculations were done mathematically on the unit for the kinetics prediction purpose. A kinetic mathematical model was derived for the prediction rate constants K1 and K2 and activation energy Ea at operating temperatures range 120-180°C. According to the model, the results show that with increasing of temperature leads to increased K1 directly, where the K2 values proportional inversely. The activation energy results show that Ea1(nC6

Reconstruction of historical exposures at a Welsh nickel refinery (1953-2000).

Science.gov (United States)

Sivulka, Donna J; Seilkop, Steven K; Lascelles, Keith; Conard, Bruce R; Jones, Sian F; Collinson, Eric C

2014-07-01

Past epidemiological studies of workers in a nickel refinery in Clydach, Wales, have shown evidence of large excess respiratory cancer mortality risks [lung cancer relative risk (RR) ≈ 3; nasal cancer RR ≈ 140] in those employed prior to 1930, with risks dropping dramatically in workers hired subsequently. The pre-1930 risks have generally been attributed to high exposures to mixtures of nickel compounds. More recent studies of this refinery's workers have focused on those first hired in 1953, when many of the operations that presumably gave rise to the high exposures were no longer in operation. While these studies have shown greatly decreased lung cancer risks overall (RR ≈ 1.4), and no substantive evidence of increased nasal cancer risk, the absence of reliable exposure estimates have made it difficult to ascertain whether the increased lung cancer risks are nickel related or due to other factors. This study uses nickel measurements from the 1970s to the present, documentation of process changes, and dust measurements taken around the 1950s to construct an exposure matrix for the recent cohort. It provides evidence of at least 30-fold decreases in levels of nickel exposure from the 1950s to the present, with estimated inhalable nickel concentrations in the 1950s in excess of 5mg Ni m(-3). © The Author 2014. Published by Oxford University Press on behalf of the British Occupational Hygiene Society.

Prospective techno-economic and environmental assessment of carbon capture at a refinery and CO2 utilisation in polyol synthesis

NARCIS (Netherlands)

Fernández-Dacosta, Cora; Van Der Spek, Mijndert; Hung, Christine Roxanne; Oregionni, Gabriel David; Skagestad, Ragnhild; Parihar, Prashant; Gokak, D. T.; Strømman, Anders Hammer; Ramirez, Andrea

2017-01-01

CO2 utilisation is gaining interest as a potential element towards a sustainable economy. CO2 can be used as feedstock in the synthesis of fuels, chemicals and polymers. This study presents a prospective assessment of carbon capture from a hydrogen unit at a refinery, where the CO2 is either stored,

Assessment of accidental refinery wastewater discharge: a case study

Energy Technology Data Exchange (ETDEWEB)

Bandyopadhyay, Amitava [University of Calcutta, Department of Chemical Engineering, Kolkata (India)

2011-04-15

The physicochemical qualities of an accidental discharge of refinery liquid waste, water, and soil sediment of that effluent-receiving water body (canal) were investigated. Analyses of the discharge, qualities of water, and sediment of the canal showed high parametric concentrations. Investigations revealed that the discharge took place form the spent caustic that was generated from the caustic wash tower of Fluidized Catalytic Cracker of the refinery. A simple but realistic model was suggested for the remediation of sediments of the canal with an estimated cost of about US $1.86 million. Recommendations were made to prevent such discharges and to revise thoroughly the Indian effluent discharge standards in force for petroleum oil refinery. Subsequently, revised standards were notified under Indian guidelines. Interestingly, cyanide besides many other parameters was introduced into these standards. Furthermore, Volatile Organic Compound (VOC) was also stipulated as an emission parameter from the waste water treatment plants. Concentration- and mass-based standards thus promulgated were stricter than the existing standards. (orig.)

Enhanced treatment of refinery soils with open-system slurry reactors

International Nuclear Information System (INIS)

Blackburn, J.W.; Lee, M.K.; Horn, W.C.

1995-01-01

Refinery site cleanups of residual hydrocarbons arising from long-term operations have become a concern. Because contaminated soil has been generated over many years from spills of many types of materials, it is often difficult to identify the actual spilled material. Because many of these materials are weathered, the less degradable fractions can predominate, creating a challenge for bioremedial process solutions. Open-system slurry reactors were run with an aged refinery soil after a 6-month period of field bioremediation in which 23% TPH removal resulted. The open system (a system where the liquid medium was replaced daily and the solids were retained in the reactor for 2 weeks) achieved 60 to 80% total petroleum hydrocarbon (TPH) removal based on the initial, prefield bioremediation soil concentration. A process concept twice as effective as other bioremediation schemes has been devised that takes advantage of the formation and removal of small black particulate solids in an open or continuous slurry reactor configuration. These small black particles are chemically or biologically produced in the open system and with their small size and low density are easily elutriated from the bioreactor as the liquid medium is changed. A statistically designed experiment has determined optimal values of nutrients, temperature, and mixing

40 CFR 80.596 - How is a refinery motor vehicle diesel fuel volume baseline calculated?

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 16 2010-07-01 2010-07-01 false How is a refinery motor vehicle diesel... Requirements § 80.596 How is a refinery motor vehicle diesel fuel volume baseline calculated? (a) For purposes of this subpart, a refinery's motor vehicle diesel fuel volume baseline is calculated using the...

The effects of the natural coagulant Moringa oleifera and alum in wastewater treatment at the Bandar Abbas Oil Refinery

Directory of Open Access Journals (Sweden)

Mohsen Dehghani

2016-11-01

Full Text Available Background: The refining process generates large volumes of wastewater containing a variety of chemical contaminants. The use of natural substitutes in treating wastewater which have fewer harmful effects is considered an effective step towards protecting the environment and sustaining the development of these industries. This study focused on the use of Moringa oleifera and alum at the Wastewater Unit at Bandar Abbas Refinery. Methods: This study was performed in 2014 in a laboratory using jar apparatus. These experiments were conducted in batch system and effective parameters including pH, coagulant dose and contact time were investigated on the wastewater obtained from Bandar Abbas Oil Refinery. Results: The jar test experiment showed that M. oleifera at 70 mg/L, optimum temperature, pH, and mixing speed could remove 38.60% of chemical oxygen demand (COD, 63.70% of turbidity, and 62.05% of total suspended solids (TSS. Also, alum at 40 mg/L removed COD, turbidity, and TSS by 51.72%, 92.16%, and 85.26% respectively from the refinery wastewater. Moreover, when M. oleifera and alum was used together with a 2:1 dosage ratio (alum at 80 mg/L and M. oleifera at 70 mg/L, they will remove COD, turbidity, and TSS by up to 50.41%, 86.14%, and 81.52% respectively. Conclusion: The use of M. oleifera as a natural coagulant is important in treating refinery wastewater not only from an environmental but also an economic point of view.

200-BP-5 operable unit treatability test report

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-04-01

The 200-BP-5 Operable Unit was established in response to recommendations presented in the 200 East Groundwater Aggregate Area Management Study Report (AAMSR) (DOE-RL 1993a). Recognizing different approaches to remediation, the groundwater AAMSR recommended separating groundwater from source and vadose zone operable units and subdividing 200 East Area groundwater into two operable units. The division between the 200-BP-5 and 200-PO-1 Operable Units was based principally on source operable unit boundaries and distribution of groundwater plumes derived from either B Plant or Plutonium/Uranium Extraction (PUREX) Plant liquid waste disposal sites.

200-BP-5 operable unit treatability test report

International Nuclear Information System (INIS)

1996-04-01

The 200-BP-5 Operable Unit was established in response to recommendations presented in the 200 East Groundwater Aggregate Area Management Study Report (AAMSR) (DOE-RL 1993a). Recognizing different approaches to remediation, the groundwater AAMSR recommended separating groundwater from source and vadose zone operable units and subdividing 200 East Area groundwater into two operable units. The division between the 200-BP-5 and 200-PO-1 Operable Units was based principally on source operable unit boundaries and distribution of groundwater plumes derived from either B Plant or Plutonium/Uranium Extraction (PUREX) Plant liquid waste disposal sites

Reconstruction of refinery industry in Chechen Republic on the resource- and energy-saving basis

Energy Technology Data Exchange (ETDEWEB)

Geieva, L.A.; Meshalkin, V.P.; Sarkissov, P.D. [Mendeleev Univ. of Chemical Technology of Russia, Moscow (Russian Federation); Hadzhiev, S.N. [Inst. of Petrochemical Synthesis of Russian Academy of Sciences after A.V. Topchiev (Russian Federation)

2003-07-01

In 2000, the Russian Federation implemented measures to increase oil production in the Chechen Republic from 73 thousand metric tons to 1.5 million metric tons by 2002. As a result, the oil refining industry in the Chechen Republic is currently in a state of crisis. More advanced and effective refining processes are required along with a reduction in production costs. The reconstruction program for refineries in Grozny requires new process system designs that can handle the appropriate petroleum products in the correct quantities and required qualities. There is also a need to balance the use of natural resources with fixed facilities and operating costs. The challenge to design optimal process systems for refineries in Grozny is both multicriterial and complex. The design will have to consider the use of various crudes and petroleum products. Advances in refining capability and resource conservation technologies would lead to greater energy consumption resulting from additional petroleum production.

Integrated Ground Operations Demonstration Units

Data.gov (United States)

National Aeronautics and Space Administration — The overall goal of the AES Integrated Ground Operations Demonstration Units (IGODU) project is to demonstrate cost efficient cryogenic operations on a relevant...

Assessment of refinery effluents and receiving waters using biologically-based effect methods

International Nuclear Information System (INIS)

2012-01-01

Within the EU it is apparent that the regulatory focus on the use of biologically-based effects methods in the assessment of refinery effluents and receiving waters has increased in the past decade. This has been reflected in a recent refinery survey which revealed an increased use of such methods for assessing the quality of refinery effluents and their receiving waters. This report provides an overview of recent techniques used for this purpose. Several case studies provided by CONCAWE member companies describe the application of biological methods to effluent discharge assessment and surface water monitoring. The case studies show that when biological methods are applied to refinery effluents and receiving waters they raise different questions compared with those obtained using physical and chemical methods. Although direct measurement of the toxicity of effluent and receiving to aquatic organisms is the most cited technique, more recent efforts include tests that also address the persistence of effluent toxicity once discharged into the receiving water. Similarly, ecological monitoring of receiving waters can identify effects of effluent inputs arising from species interactions and other secondary effects that would not always be apparent from the results of biological tests conducted on single aquatic organisms. In light of recent and proposed regulatory developments the objectives of this report are therefore to: Discuss the application of biologically-based effects methods (including ecological monitoring) to refinery discharges and receiving waters; Assess the implications of such methods for future regulation of refinery discharges; and Provide guidance on good practice that can be used by refineries and the downstream oil industry to carry out and interpret data obtained using biologically-based effects methods. While the emphasis is on the toxic effects of effluents, other properties will also be covered because of their interdependency in determining

Assessment of refinery effluents and receiving waters using biologically-based effect methods

Energy Technology Data Exchange (ETDEWEB)

NONE

2012-01-15

Within the EU it is apparent that the regulatory focus on the use of biologically-based effects methods in the assessment of refinery effluents and receiving waters has increased in the past decade. This has been reflected in a recent refinery survey which revealed an increased use of such methods for assessing the quality of refinery effluents and their receiving waters. This report provides an overview of recent techniques used for this purpose. Several case studies provided by CONCAWE member companies describe the application of biological methods to effluent discharge assessment and surface water monitoring. The case studies show that when biological methods are applied to refinery effluents and receiving waters they raise different questions compared with those obtained using physical and chemical methods. Although direct measurement of the toxicity of effluent and receiving to aquatic organisms is the most cited technique, more recent efforts include tests that also address the persistence of effluent toxicity once discharged into the receiving water. Similarly, ecological monitoring of receiving waters can identify effects of effluent inputs arising from species interactions and other secondary effects that would not always be apparent from the results of biological tests conducted on single aquatic organisms. In light of recent and proposed regulatory developments the objectives of this report are therefore to: Discuss the application of biologically-based effects methods (including ecological monitoring) to refinery discharges and receiving waters; Assess the implications of such methods for future regulation of refinery discharges; and Provide guidance on good practice that can be used by refineries and the downstream oil industry to carry out and interpret data obtained using biologically-based effects methods. While the emphasis is on the toxic effects of effluents, other properties will also be covered because of their interdependency in determining

Optimization of water network in petroleum refinery; Otimizacao de redes de agua em refinarias de petroleo

Energy Technology Data Exchange (ETDEWEB)

Faria, Debora C.; Souza, Selene M.A. Guelli Ulson de; Souza, Antonio A. Ulson de [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil)

2004-07-01

The petroleum refineries have shown high water's consuming that creates high costs and damages the hydric resources. However, the industrial sector, especially the petroleum industry, has been looking for alternatives that minimizing the impact caused by to use these natural resources. Currently, methodologies of controlling the pollution on the source have been appearing how a strong tendency and the reuse and/or recycle of wastewater can be emphasized. The optimization by mathematical programming, together with engineering know-how, is one of the great tendency in process integration technology developed. The present work presents one optimization mathematical model that objectifies to reduce the water's consuming and/or operational costs. The model is based in chemical species and mass conservation equation. This work presents the solution of one case found in literature that broach one petroleum refinery's network of water. This network is composed of six operations and three regenerative processes, and there are four keys contaminants. The water's consuming was minimized first and next the minimum cost in the minimum consume was broached. The results found were enough satisfactory and presented reductions up to 76% in the water consume and approximately 65% in the operational costs. (author)

Refinery boom in Southeast Asia

International Nuclear Information System (INIS)

Gruson, J.F.; Virondaud, C.

1996-01-01

The Asia demand for oil is increasing dramatically, particularly in the non OECD countries, which represent, today more than 15 % of the world oil market. The expected economic growth in these areas should contribute to a rise in oil demand by about 5.4 per year and hence to a significant increase of this share to 25 % in 2010; virtually a large part of this evolution will come from the transportation sector. The proceeding investments of the regional, refining industry are very high (some evaluations come to around 140 billion of dollars), all the more the protection of the environment takes an increasing significant place. Accordingly the most important challenge to be taken up by these countries will be to mobilize long term fundings to develop and adapt the capabilities of the refineries to meet the growth of gasoline and gas oil demand. The contribution of private operators or capital will be necessary, but will depend strongly on refining margin improvement and on progress of free market areas announced by several countries. (authors)

Test plan: the Czechowice Oil Refinery bioremediation demonstration of a process waste lagoon

Energy Technology Data Exchange (ETDEWEB)

Altman, D.J.; Lombard, K.H.; Hazen, T.C.

1997-03-31

The remediation strategies that will be applied at the Czechowice Oil Refinery waste lagoon in Czechowice, Poland are designed, managed, and implemented under the direction of the Westinghouse Savannah River Company (WSRC) for the United States Department of Energy (DOE). WSRC will be assisted in the demonstration by The Institute for Ecology of Industrial Areas (IETU). This collaboration between IETU and DOE will provide the basis for international technology transfer of new and innovative remediation technologies that can be applied in Poland and the Eastern European Region as well.

Utilization of the BR-SIPP systems (Integrated Refinery Scheduling System) at the PETROBRAS Capuava refinery; Utilizacao do sistema BR-SIPP - Sistema Integrado de Programacao de Producao PETROBRAS na refinaria de Capuava

Energy Technology Data Exchange (ETDEWEB)

Joly, Marcel [PETROBRAS, Maua, SP (Brazil). Refinaria de Capuava (RECAP). Gerencia de Otimizacao]. E-mail: joly@petrobras.com.br; Hassimotto, Marcelo Kenji [PETROBRAS, Rio de Janeiro, RJ (Brazil). Gerencia de Solucoes de Negocios de Logistica e Planejamento]. E-mail: kenji@petrobras.com.br; Magalhaes, Marcus Vinicius de Oliveira [PETROBRAS, Rio de Janeiro, RJ (Brazil). Gerencia de Otimizacao]. E-mail: vinicius@petrobras.com.br

2007-04-15

The BR-SIPP is a production scheduling decision support tool for refineries. It is integrated into the Corporate Inventory, Movements and Quality Data Base and is based on events simulation technology for the elaboration and analysis of scheduling scenarios. Its utilization at the Capuava Refinery allows the production programming team to analyze and anticipate difficulties and opportunities, thereby being able to make viable a potential integration of management and people directly involved with the refinery scheduling information, such as planning, logistics and commercial areas. (author)

Opportunities and challenges at the interface between petrochemistry and refinery. The BASF perspective

Energy Technology Data Exchange (ETDEWEB)

Blankertz, H.J. [BASF AG, Ludwigshafen (Germany)

2007-07-01

The author of the contribution under consideration reports on the BASF perspective according to opportunities and challenges at the interface between petrochemistry and refinery. This contribution is divided into the following chapters: (a) Overview BASF-Group; (b) Overview BASF Petrochemicals; (c) The refinery-chemistry interface; (d) Main focus refineries; (e) Interface challenges and opportunities; (f) What can BASF do for refineries. BASF employs the Verbund concept, a system that combines production with energy needs in an intelligent way. The idea is to reduce of primary energy carriers both in terms of raw materials and for power and steam generation. The authors describes the petrochemicals of BASF AG (Ludwigshafen, Federal Republic of Germany), the raw material development, evolution of thermal steamcracking and crackerproducts. Major feedstock source of the European petrochemical industry are streams out of refineries which can't be used for transportation fuels. The gap between propylene demand and production out of steam crackers has to be closed by propylene out for FCC's. Demand for aromatics (xylenes and benzene, and to a lesser extent toluene) needs to be filled in by aromatics out of refineries. Market drivers for the refining industry are lowering crude costs, growing clean products, increasing capacity and enhancing E and P integration. BASF has various business with the oil und refining industry and provides solutions for oil field chemicals, process chemicals and performance additives. The author explains which kind of products and services BASF provides for refiners.

Management of waste generation in the oil refining industry. The PETROBRAS - Henrique Lage Refinery experience

Energy Technology Data Exchange (ETDEWEB)

Coelho, J I; Machado, J B; Linhares, C A; Mazarino, P R [PETROBRAS, Sao Jose dos Campos, SP (Brazil). REVAP. Refinaria Henrique Lage

1994-12-31

The PETROBRAS - Henrique Lages Refinery - located in Sao Paulo State (Southeast Brazil), has been developing for many years a systematic program for solid, liquid and gaseous wastes generation reduction. The waste minimization management program success has been built due to the structure behavioural modifications due to the new environment protection and quality politics; the training and equipment investments, and operational procedures changes. (author). 7 figs., 3 tabs.

Management of waste generation in the oil refining industry. The PETROBRAS - Henrique Lage Refinery experience

Energy Technology Data Exchange (ETDEWEB)

Coelho, J.I.; Machado, J.B.; Linhares, C.A.; Mazarino, P.R. [PETROBRAS, Sao Jose dos Campos, SP (Brazil). REVAP. Refinaria Henrique Lage

1993-12-31

The PETROBRAS - Henrique Lages Refinery - located in Sao Paulo State (Southeast Brazil), has been developing for many years a systematic program for solid, liquid and gaseous wastes generation reduction. The waste minimization management program success has been built due to the structure behavioural modifications due to the new environment protection and quality politics; the training and equipment investments, and operational procedures changes. (author). 7 figs., 3 tabs.

Physical protection of nuclear operational units

International Nuclear Information System (INIS)

1981-07-01

The general principles of and basic requirements for the physical protection of operational units in the nuclear field are established. They concern the operational units whose activities are related with production, utilization, processing, reprocessing, handling, transport or storage of materials of interest for the Brazilian Nuclear Program. (I.C.R.) [pt

Mazeikiai refinery woes deepen on all fronts

Index Scriptorium Estoniae

2007-01-01

Leedu rahandusminister teatas, et riigieelarvet mõjutavad probleemid Mazeikiai tehasega, mis on Leedu suurim maksumaksja. Lisa: Russian oil company to build refinery. Surgutneftegaz teatas plaanist ehitada naftatöötlustehas Peterburi lähedale

Optimization of the fluid catalytic cracking unit performance by application of a high motor Octane catalyst and reduction of gasoline vapour pressure

International Nuclear Information System (INIS)

Chavdarov, I.; Stratiev, D.; Shishkova, I.; Dinkov, R.; Petkov, P.

2013-01-01

Full text: The fluid catalytic cracking (FCC) gasoline is the main contributor to the refinery gasoline pool in the LUKOIL Neftohim Burgas (LNB) refinery. Next in quantity contributor in the refinery gasoline pool is the reformate. The FCC gasoline sensitivity (MON-RON) is about 12 points. The reformer gasoline sensitivity is 11 points. The high sensitivity of the main contributors to the LNB refinery gasoline pool leads to a shortage in the motor octane number. For that reason a selection of an FCC catalyst that is capable of increasing the motor octane number of the FCC gasoline was performed. The application of this catalyst in the LNB FCC unit has led to an increase of the motor octane number of the FCC gasoline by 0.5 points, which enabled the refinery to increase the production of automotive gasolines by 1.3 % and to increase the share of premium automotive gasoline by 5 %. This had an effect of improvement of the refinery economics by a six figure number of US $ per year. The optimization of the FCC gasoline Reid Vapor Pressure (RVP) during the winter season, consisting in a reduction of the RVP from 60 to 50 kPa and an increase of the FCC C 4 olefins yield, has led to an augmentation of high motor octane number alkylate production. As a result the refinery economics was improved by a five figure number of US $ per year. key words: FCC gasoline motor octane number, gasoline RVP, FCC operation profitability

Treatment of Refinery Waste Water Using Environmental Friendly Adsorbent

Science.gov (United States)

Devi, M. Geetha; Al-Moshrafi, Samira Mohammed Khamis; Al Hudaifi, Alaa; Al Aisari, Buthaina Hamood

2017-12-01

This research evaluates the effectiveness of activated carbon prepared from walnut shell in the removal of pollutants from refinery waste water by adsorption technique. A series of batch experiments were carried out by varying the effluent solution pH, stirring time, stirring speed and adsorbent dosage in the reduction of pollutants from refinery effluent. Characterization of the adsorbent was performed using Scanning Electron Microscopy (SEM), Brunauer Emmett and Teller (BET) isotherm and Fourier Transform Infrared (FTIR) Spectroscopy. The best quality activated carbon was obtained with a particle size of 0.75 µm, activation temperature of 800 °C and activation time 24 h. The maximum BET surface area obtained was 165.2653 m2/g. The experimental results demonstrates that the highest percentage reduction in COD was 79%, using 0.6 g walnut shell powder at an optimum stirring speed of 100 rpm, at pH 6 and 120 min of contact time. The outcome of the result shows that walnut shell carbon is a potentially useful adsorbent for the removal of pollutants from refinery waste water.

Storage and distribution/Linear programming for storage operations

Energy Technology Data Exchange (ETDEWEB)

Coleman, D

1978-07-15

The techniques of linear programing to solve storage problems as applied in a tank farm tie-in with refinery throughput operation include: (1) the time-phased model which works on storage and refinery operations input parameters, e.g., production, distribution, cracking, etc., and is capable of representing product stockpiling in slack periods to meet future peak demands, and investigating alternative strategies such as exchange deals and purchase and leasing of additional storage, and (2) the Monte Carlo simulation method, which inputs parameters, e.g., arrival of crude products at refinery, tankage size, likely demand for products, etc., as probability distributions rather than single values, and is capable of showing the average utilization of facilities, potential bottlenecks, investment required to achieve an increase in utilization, and to enable the user to predict total investment, cash flow, and profit emanating from the original financing decision. The increasing use of computer techniques to solve refinery and storage problems is attributed to potential savings resulting from more effective planning, reduced computer costs, ease of access and more usable software. Diagrams.

Automatic crude oil handling through a pressurized system from the wellhead to the refinery

Energy Technology Data Exchange (ETDEWEB)

Davis, W.B.; Truman, P.W.; Groeneman, A.R.

1967-01-01

Production from 51 wells completed in the 3 unitized formations of the Lost Soldier Field, Sweetwater Co., Wyoming, is brought to a central point through individual flow lines. Here the fluids are directed through separate automatic well testing and oil treating facilities, one for each formation. After separation of oil, gas and water, the oil goes to pressurized surge tanks and then to lease automatic custody transfer units. There is one surge tank and one LACT unit for each formation. The oil is automatically transferred to the Sinclair Pipe Line Co. for delivery to Sinclair's refinery at Sinclair, Wyoming, through a closed pipe line system. A central console provides: (1) supervisory control from the wellheads through the LACT units, (2) well test and production data logging, and (3) monitoring by activating alarms for abnormal conditions of flow, liquid levels, temperatures and pressures.

76 FR 42052 - National Emission Standards for Hazardous Air Pollutants From Petroleum Refineries

Science.gov (United States)

2011-07-18

...-AO55 National Emission Standards for Hazardous Air Pollutants From Petroleum Refineries AGENCY... the National Emission Standards for Hazardous Air Pollutants From Petroleum Refineries. EPA is now... signed a final rule amending the National Emission Standards for Hazardous Air Pollutants From Petroleum...

Reuse of refinery's tertiary-treated wastewater in cooling towers: microbiological monitoring.

Science.gov (United States)

Dos Santos, Vera Lúcia; Veiga, Andréa Azevedo; Mendonça, Rafael Silva; Alves, Andrea Lima; Pagnin, Sérgio; Santiago, Vânia M J

2015-02-01

The study was planned to quantify the distribution of bacteria between bulk water and biofilm formed on different materials in an industrial scale cooling tower system of an oil refinery operating with clarified and chlorinated freshwater (CCW) or chlorinated tertiary effluent (TRW) as makeup water. The sessile and planktonic heterotrophic bacteria and Pseudomonas aeruginosa densities were significantly higher in the cooling tower supplied with clarified and chlorinated freshwater (CTCW) (p towers, the biofilm density was higher on the surface of glass slides and stainless steel coupons than on the surface of carbon steel coupons. The average corrosion rates of carbon steel coupons (0.4-0.8 millimeters per year (mpy)) and densities of sessile (12-1.47 × 10(3) colony-forming unit (CFU) cm(-1)) and planktonic (0-2.36 × 10(3) CFU mL(-1)) microbiota remained below of the maximum values of reference used by water treatment companies as indicative of efficient microbial control. These data indicate that the strategies of the water treatment station (WTS) (free chlorine) and industrial wastewater treatment station (IWTS) followed by reverse electrodialysis system (RES) (free chlorine plus chloramine) were effective for the microbiological control of the two makeup water sources.

University of Maine Integrated Forest Product Refinery (IFPR) Technology Research

Energy Technology Data Exchange (ETDEWEB)

Pendse, Hemant P.

2010-11-23

This project supported research on science and technology that forms a basis for integrated forest product refinery for co-production of chemicals, fuels and materials using existing forest products industry infrastructure. Clear systems view of an Integrated Forest Product Refinery (IFPR) allowed development of a compelling business case for a small scale technology demonstration in Old Town ME for co-production of biofuels using cellulosic sugars along with pulp for the new owners of the facility resulting in an active project on Integrated Bio-Refinery (IBR) at the Old Town Fuel & Fiber. Work on production of advanced materials from woody biomass has led to active projects in bioplastics and carbon nanofibers. A lease for 40,000 sq. ft. high-bay space has been obtained to establish a Technology Research Center for IFPR technology validation on industrially relevant scale. UMaine forest bioproducts research initiative that began in April 2006 has led to establishment of a formal research institute beginning in March 2010.

Analysis of standard and innovative methods for allocating upstream and refinery GHG emissions to oil products

International Nuclear Information System (INIS)

Moretti, Christian; Moro, Alberto; Edwards, Robert; Rocco, Matteo Vincenzo; Colombo, Emanuela

2017-01-01

Highlights: •Traditional and innovative methods for allocating emissions at refinery level are reviewed. •Added value has been introduced as a novel allocation method. •Hydrogen-based consistency test has been introduced to validate the allocation methods. •Consistent allocation methods assign negative refinery emissions to heavy products. -- Abstract: Alternative fuel policies need accurate and transparent methods to find the embedded carbon intensity of individual refinery products. This study investigates different ways of allocating greenhouse gases emissions deriving from refining and upstream crude oil supply. Allocation methods based on mass, energy content, economic value and, innovatively, added-value, are compared with the marginal refining emissions calculated by CONCAWE’s linear-programming model to the average EU refinery, which has been adopted as reference in EU legislation. Beside the most important transportation fuels (gasoline, diesel, kerosene/jet fuel and heavy fuel oil), the analysis extends to petroleum coke and refinery hydrogen. Moreover, novel criteria, based on the implications due to hydrogen usage by each fuel pathway, have been introduced to test the consistency of the analyzed approaches. It is found that only two economic-based allocation methods are consistent with the introduced criteria. These two methods also give negative refinery emissions for heavy products, which is coherent with the marginal emissions calculated through the CONCAWE refinery model. The recommended allocation methods are transparent and use only publicly available statistical data, so they may be useful not only for future EU legislation, but also in jurisdictions where a representative refinery model is not available.

Metal leaching from refinery waste hydroprocessing catalyst.

Science.gov (United States)

Marafi, Meena; Rana, Mohan S

2018-05-18

The present study aims to develop an eco-friendly methodology for the recovery of nickel (Ni), molybdenum (Mo), and vanadium (V) from the refinery waste spent hydroprocessing catalyst. The proposed process has two stages: the first stage is to separate alumina, while the second stage involves the separation of metal compounds. The effectiveness of leaching agents, such as NH 4 OH, (NH 4 ) 2 CO 3 , and (NH 4 ) 2 S 2 O 8 , for the extraction of Mo, V, Ni, and Al from the refinery spent catalyst has been reported as a function of reagent concentration (0.5 to 2.0 molar), leaching time (1 to 6 h), and temperature (35 to 60°C). The optimal leaching conditions were achieved to obtain the maximum recovery of Mo, Ni, and V metals. The effect of the mixture of multi-ammonium salts on the metal extraction was also studied, which showed an adverse effect for Ni and V, while marginal improvement was observed for Mo leaching. The ammonium salts can form soluble metal complexes, in which stability or solubility depends on the nature of ammonium salt and the reaction conditions. The extracted metals and support can be reused to synthesize a fresh hydroprocessing catalyst. The process will reduce the refinery waste and recover the expensive metals. Therefore, the process is not only important from an environmental point of view but also vital from an economic perspective.

Analysis on Isolation Condenser Operation by Fukushima Daiichi Unit 1 Operators

International Nuclear Information System (INIS)

Kim, Man Cheol

2014-01-01

Fukushima Daiichi nuclear accident resulted in the core damage in three reactors and the release of considerable amount of radioactive material to the environment, not to mention significant social impact and anti-nuclear atmosphere all around the world. This paper provides a review of the findings related to shift operators' operation of the isolation condenser in Unit 1 to examine shift operators' response to the situation. Based on the review of the findings, a situation assessment model was developed to analyze shift operators' understanding on whether core cooling was successfully performed in Unit 1 through the operation of isolation condenser. It was found that lack of information could be one of the main causes for the failure in core cooling by the IC in Unit 1. It is also recommended that the differences in the mathematical model for the situation assessment and that of the real operator need to be further investigated

Analysis on Isolation Condenser Operation by Fukushima Daiichi Unit 1 Operators

Energy Technology Data Exchange (ETDEWEB)

Kim, Man Cheol [Chungang University, Seoul (Korea, Republic of)

2014-08-15

Fukushima Daiichi nuclear accident resulted in the core damage in three reactors and the release of considerable amount of radioactive material to the environment, not to mention significant social impact and anti-nuclear atmosphere all around the world. This paper provides a review of the findings related to shift operators' operation of the isolation condenser in Unit 1 to examine shift operators' response to the situation. Based on the review of the findings, a situation assessment model was developed to analyze shift operators' understanding on whether core cooling was successfully performed in Unit 1 through the operation of isolation condenser. It was found that lack of information could be one of the main causes for the failure in core cooling by the IC in Unit 1. It is also recommended that the differences in the mathematical model for the situation assessment and that of the real operator need to be further investigated.

Assessing refinery capacity and readiness to take Canadian product : is Canadian crude pushing or pulling?

International Nuclear Information System (INIS)

Friesner, J.M.

2005-01-01

This presentation addressed some of the challenges facing oil sands production in Canada. Refinery products and refining investments were discussed, as was the impact of alternative crude supply on the markets and pricing of oil sands. The oils sands products discussed include various qualities of sweet synthetic crude oil produced via upgraders; virgin and cracked intermediate products from oil sands upgraders; mined or Steam Assisted Gravity Drainage (SAGD) produced bitumen blended products; and synthetic heavy crude produced via hydrocracking. Products were listed in terms of ease of production, and a rationale for generic ranking was provided. A chart of 2003 characteristics of non-Canadian imports to the mid-west United States was provided. Various marketing strategies for different oil sands products were discussed, as well as issues concerning logistics. Strategies for the development of a bigger market include producer investment in refining capability; the acquisition of refining assets; investment in refiners' upgrading capability; and securing a long term supply deal. Core and extended markets for Western Canadian oil sands products were reviewed. A chart of North American refining capacity was presented. Details of a refinery with both coking and cracking capacity were examined. An increase in hydro processing capacity and expanded coking capacity, as well as an upgrade of metallurgy were suggested as possible upgrading options. Various refinery configurations were discussed in relation to lower cost feedstocks and clean fuels specifications. Issues concerning crude supply were examined with reference to pricing parity points and declines in traditional crude production. Specific supply issues concerning oil sands production were discussed, including transportation costs; adequate refining capacity; and availability of supply. Various logistic investments were considered. A map of BP's 5 U.S. refineries was presented. A forecast of expected changes in

Removal of hydrocarbon from refinery tank bottom sludge employing microbial culture.

Science.gov (United States)

Saikia, Rashmi Rekha; Deka, Suresh

2013-12-01

Accumulation of oily sludge is becoming a serious environmental threat, and there has not been much work reported for the removal of hydrocarbon from refinery tank bottom sludge. Effort has been made in this study to investigate the removal of hydrocarbon from refinery sludge by isolated biosurfactant-producing Pseudomonas aeruginosa RS29 strain and explore the biosurfactant for its composition and stability. Laboratory investigation was carried out with this strain to observe its efficacy of removing hydrocarbon from refinery sludge employing whole bacterial culture and culture supernatant to various concentrations of sand-sludge mixture. Removal of hydrocarbon was recorded after 20 days. Analysis of the produced biosurfactant was carried out to get the idea about its stability and composition. The strain could remove up to 85 ± 3 and 55 ± 4.5 % of hydrocarbon from refinery sludge when whole bacterial culture and culture supernatant were used, respectively. Maximum surface tension reduction (26.3 mN m(-1)) was achieved with the strain in just 24 h of time. Emulsification index (E24) was recorded as 100 and 80 % with crude oil and n-hexadecane, respectively. The biosurfactant was confirmed as rhamnolipid containing C8 and C10 fatty acid components and having more mono-rhamnolipid congeners than the di-rhamnolipid ones. The biosurfactant was stable up to 121 °C, pH 2-10, and up to a salinity value of 2-10 % w/v. To our knowledge, this is the first report showing the potentiality of a native strain from the northeast region of India for the efficient removal of hydrocarbon from refinery sludge.

Nuclear units operating improvement by using operating experience

International Nuclear Information System (INIS)

Rotaru, I.; Bilegan, I.C.

1997-01-01

The paper presents how the information experience can be used to improve the operation of nuclear units. This areas include the following items: conservative decision making; supervisory oversight; teamwork; control room distraction; communications; expectations and standards; operator training and fundamental knowledge, procedure quality and adherence; plant status awareness. For each of these topics, the information illustrate which are the principles, the lessons learned from operating experience and the most appropriate exemplifying documents. (authors)

Exergy and exergoeconomic analysis of a petroleum refinery utilities plant using the condensing to power method

Energy Technology Data Exchange (ETDEWEB)

Mendes da Silva, Julio Augusto; Pellegrini, Luiz Felipe; Oliveira Junior, Silvio [Polytechnic School of the University of Sao Paulo, SP (Brazil)], e-mails: jams@usp.br, luiz.pellegrini@usp.br, soj@usp.br; Plaza, Claudio; Rucker, Claudio [Petrobras - Petroleo Brasileiro S.A., Rio de Janeiro, RJ (Brazil)], e-mails: claudioplaza@petrobras.com.br, rucker@petrobras.com.br

2010-07-01

In this paper a brief description of the main processes present in a modern high capacity refinery is done. The methodology used to evaluate, through exergy analysis, the performance of the refinery's utilities plant since it is responsible for a very considerable amount of the total exergy destruction in a refinery is presented. The utilities plant products: steam, electricity, shaft power and high pressure water had their exergy unit cost determined using exergoeconomic approach. A simple and effective method called condensing to power was used to define the product of the condensers in exergy basis. Using this method it is possible to define the product of the condenser without the use of negentropy concept nor the aggregation of condensers to the steam turbines. By using this new approach, the costs obtained for the plant's products are exactly the same costs obtained when the condenser is aggregated to the steam turbine but with the advantage that the information about the stream between condenser and the steam turbine is not lost and the condenser can be evaluated singly. The analysis shows that the equipment where attention and resources should be focused are the boilers followed by the gas turbine, that together, are responsible for 80% of total exergy destruction in the utilities plant. The total exergy efficiency found for the utilities plant studied is 35% while more than 280 MW of exergy is destroyed in the utilities processes. (author)

Crude incompatibility problems at heavy crude unit desalter

International Nuclear Information System (INIS)

Kirmani, Z.; Khurshid, A.; Alam, N.; Gul, S.; Ahmed, N.

2009-01-01

Attock Refinery Limited (ARL) is based at Rawalpindi, Pakistan and operates a 40,000 Barrels per Stream Day (BPSD) refinery. The Heavy Crude Unit (HCU) of ARL is a fully integrated two-stage 10,000 BPSD Atmospheric and 5,700 BPSD Vacuum Distillation Unit. A 3-stage desalter designed to reduce salt and BS and W content from 2,000 parts per thousand barrels (PTB) and 2% to less than 5 PTB and 0.1% respectively, is part of HCU. The feedstock is a composite blend of 14 local Heavy Crudes received at the Refinery. Although in the past this desalter had been giving good performance, over the last one year, period since August 2005, at least nine shutdowns of the unit took place due to salt slippage and consequential tube leakages at the overhead Crude-Naphtha vapor Heat Exchanger where partial condensation of naphtha takes place. Final condensation is achieved in trim condenser. High salted water carry-over with the crude caused increased hydrolysis, formation of Hydrochloric acid and increase of tail water chlorides. Salt contents at the outlet of third desalter at times increased up to 400 PTB with 3.2% BS and W during the above mentioned upsets, as compared to normal 5-10 PTB. Fallout from this loss of desalter control was the creation of large quantities of slop due to draining of strong water oil emulsion from the desalters. Individual crudes of the blend were analyzed for affinity of water and emulsion stability. It was observed that 3 of the 14 crudes formed very strong while the remaining crudes formed weak oil water emulsion, which easily separated water from oil in desalter without any operational problem. Study was further narrowed down to one crude evaluation. Alkaline earth metallic naphthenate surfactants were detected and isolated as responsible for the strong water oil and sediments emulsion. The isolated crude was next withdrawn from the Heavy Crude blend. As soon as it was isolated and its ratio in heavy crude tank came down to 0.7 %, the problem began

Inefficiency of Malaysian palm oil refineries and the impact of different factors on its inefficiency

Directory of Open Access Journals (Sweden)

Zahra Shahverdi

2015-09-01

Full Text Available This study aimed to analyze changes in the inefficiency of Malaysian palm oil refineries using DEA window analysis method over the period 1996 to 2009. We investigated the effects of different factors on inefficiency of Malaysian palm oil refineries. Based on empirical results, the effect of all factors such as vertical integration, types of ownership, foreign investment, location, experience, and liberalization on inefficiency of refineries was significant. Experience, liberalization, and joint venture between private and public sectors showed an increase in efficiency, while joint venture between local and foreign investment and vertical integration increased refineries’ inefficiency. However, palm oil refineries which were located in the states of Sabah and Sarawak were less technically inefficient than those located in peninsular Malaysia.

Effects of work-related stress on work ability index among refinery workers.

Science.gov (United States)

Habibi, Ehsanollah; Dehghan, Habibollah; Safari, Shahram; Mahaki, Behzad; Hassanzadeh, Akbar

2014-01-01

Work-related stress is one of the basic problems in industrial also top 10 work-related health problems and it is increasingly implicated in the development a number of problems such as cardiovascular disease, musculoskeletal diseases, early retirement to employees. On the other hand, early retirement to employees from the workplace has increased on the problems of today's industries. Hereof, improving work ability is one of the most effective ways to enhance the ability and preventing disability and early retirement. The aim of This study is determine the relationship between job stress score and work ability index (WAI) at the refinery workers. This is a cross-sectional study in which 171 workers from a refinery in isfahan in 2012 who were working in different occupational groups participated. Based on appropriate assignment sampling, 33 office workers, 69 operational workers, and 69 maintenance workers, respectively, were invited to participate in this study. Two questionnaires including work related-stress and WAI were filled in. Finally, the information was analyzed using the SPSS-20 and statistic tests namely, analysis of covariance Kruskal-Wallis test. Pearson correlation coefficient, ANOVA and t-test. Data analysis revealed that 86% and 14% of participants had moderate and severe stress respectively. Average score of stress and standard deviation was 158.7 ± 17.3 that was in extreme stress range. Average score and standard deviation of WAI questionnaire were 37.18 and 3.86 respectively. That placed in a good range. Pearson correlation coefficient showed that WAI score had significant reversed relationship with a score of stress. According to the results, mean stress score among refinery worker was high and one fator that affect work abiity was high stress, hence training on communication skills and safe working environment in order to decreses stress, enhance the work ability of workers.

Computer model for refinery operations with emphasis on jet fuel production. Volume 3: Detailed systems and programming documentation

Science.gov (United States)

Dunbar, D. N.; Tunnah, B. G.

1978-01-01

The FORTRAN computing program predicts flow streams and material, energy, and economic balances of a typical petroleum refinery, with particular emphasis on production of aviation turbine fuels of varying end point and hydrogen content specifications. The program has a provision for shale oil and coal oil in addition to petroleum crudes. A case study feature permits dependent cases to be run for parametric or optimization studies by input of only the variables which are changed from the base case.

Operation and Maintenance Plan for the 300-FF-5 Operable Unit

International Nuclear Information System (INIS)

Singleton, K.M.

1996-09-01

This document is the operation and maintenance plan for the 300-FF-5 groundwater operable unit. The purpose of this plan is to identify tasks necessary to verify the effectiveness of the selected alternative. This plan also describes the monitoring program and administrative tasks that will be used as the preferred alternative for the remediation of groundwater in the 300-FF-5 Operable Unit. The preferred alternative selected for remediation of groundwater consists of institutional controls

The Implementation and Maintenance of a Behavioral Safety Process in a Petroleum Refinery

Science.gov (United States)

Myers, Wanda V.; McSween, Terry E.; Medina, Rixio E.; Rost, Kristen; Alvero, Alicia M.

2010-01-01

A values-centered and team-based behavioral safety process was implemented in a petroleum oil refinery. Employee teams defined the refinery's safety values and related practices, which were used to guide the process design and implementation. The process included (a) a safety assessment; (b) the clarification of safety-related values and related…

Air Pollution Dispersion Modeling of Abadan oil Refinery Using SCREEN3

International Nuclear Information System (INIS)

Hedayati Rad, F.; Salman-Mahini, A.; Mirkarimi, H.

2016-01-01

Air pollution is a major problem that has been recognized throughout the world. Refineriers normally create environmental pollution through emissions of pollutants gaseous from a variety of sources. Analysing air pollution distribution and dispersion can help in reducing the negative effects. In this study NO_X and SO_2 emissions and distributions were investigated for Abadan oil refinery using SCREEN3 software. In this softweare, wind speed and direction, air temperature, location and physical characteristics of chimnies and atmospheric stability were taken into consideration.The concentration of pollutants in different distances from the stacks in the range 25 km were predicted and mapped in Idrisi software. The output from software SCREEN3 for emissions from stacks were also examined and compared with the standard output of the refineries. According to our results, the concentration of pollutants in summer and autumn seasons exceeds of the environmental standards.

Junior Leader Training Development in Operational Units

Science.gov (United States)

2012-04-01

UNITS Successful operational units do not arise without tough, realistic, and challenging training. Field Manual (FM) 7-0, Training Units and D...operations. The manual provides junior leaders with guidance on how to conduct training and training management. Of particular importance is the definition...1 Relation htp between ADDIE and the Anny Training Management Model. The Army Training Management Model and ADDIE process appear in TRADOC PAM 350

Integration : OPEC is now in 35 foreign refineries

International Nuclear Information System (INIS)

Terzian, P.

1994-01-01

Seven countries from OPEC own now share holdings in 35 foreign refineries. By this process of downstream reintegration, these countries hope to reach a better stability of crude oil prices. (Author). 3 tabs

Analysis of Serbian Military Riverine Units Capability for Participation in the United Nations Peacekeeping Operations

Directory of Open Access Journals (Sweden)

Slobodan Radojevic

2017-06-01

Full Text Available This paper analyses required personnel, training capacities and equipment for participation in the United Nations peacekeeping operations with the riverine elements. In order to meet necessary capabilities for engagement in United Nations peacekeeping operations, Serbian military riverine units have to be compatible with the issued UN requirements. Serbian Armed Forces have the potential to reach such requirements with the River Flotilla as a pivot for the participation in UN missions. Serbian Military Academy adopted and developed educational and training program in accordance with the provisions and recommendations of the IMO conventions and IMO model courses. Serbian Military Academy has opportunities for education and training military riverine units for participation in the United Nations peacekeeping operations. Moreover, Serbia has Multinational Operations Training Center and Peacekeeping Operations Center certified to provide selection, training, equipping and preparations of individuals and units to the United Nations multinational operations.

FY 2000 report on the potential survey of implementation of a model project for improvement of thermal efficiency and energy conservation in refineries of Indonesia; 2000 nendo chosa hokokusho. Indonesia ni okeru seiyujo netsukoritsu kojo shoenergy model jigyo jisshi kanosei chosa

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-07-01

For the purpose of heightening the thermal efficiency in oil refineries in Indonesia, survey was conducted of two main refineries of Pertamina (Cilacap Refinery and Balikpapan Refinery), and a potentiality of spreading energy conservation technology was studied. As a result of the study, the following were found out. In Cilacap Refinery, there is a possibility of energy conservation by enhancing the efficiency of the atmospheric distillation system and rationalizing utility facilities. As to Balikpapan Refinery, when effects of energy conservation are calculated by effectively using the by-producing off-gas emitted from the oil refining process which was recovered as on-site fuel, the amount of reduction in fuel consumption became 2.3 KL-FOE/h, and the year of simple investment recovery 1.7 years. Further, by recovering/effectively using hydrogen in the separation gas emitted from the hydrocracking unit, fuel/raw material in the hydrogen producing facilities were reduced, and the energy conservation effect became 2.98 KL-FOE/h in the amount of reduction in fuel consumption and 2.9 years in the year of simple investment recovery. (NEDO)

Cleaner shipping. Trade off between air pollution, costs and refinery CO2 emissions

International Nuclear Information System (INIS)

De Wilde, H.P.J.; Kroon, P.

2008-05-01

Still subject to final approval in October 2008, the International Maritime Organisation (IMO) agreed on a maximum sulphur content of 0.5% for shipping fuels in 2020. This target will induce major changes in the global refinery industry. We have estimated the impact on the Dutch refinery industry, which annually produces about 8 million tons of heavy fuel oil for sea shipping, with refinery residues as main component. It is technically possible to convert all residues, although this process will cause an additional energy use of about one million tons of crude oil and a related CO2 emission of about 4 million tons. The investment costs for these major changes in the Dutch refinery industry are estimated at about 1.5 tot 2 billion euros. The recent IMO agreement enables a gradual introduction of cleaner shipping fuels, which will reduce market disruptions and peak prices. Nevertheless, Rotterdam may not necessarily be able to develop a similar position in import, export and bunkering of future low sulphur fuels, compared to its present strong position in the market of heavy marine bunkers. Extrapolation of our national study to the global scale suggests that the deep conversion of 350 million tons of heavy fuel oil for shipping would require refinery investments in the order of 70-100 billion euros. The associated CO2 emissions would amount up to 175 Mton. The net additional CO2 emission, however, would be smaller since lighter shipping fuels result in less CO2 emissions at sea. On balance, we expect that the improvements in fuel economy, driven by the expensive low-carbon shipping fuels, will decrease CO2 emissions more than the increase in CO2 emissions from additional desulphurization in the refineries. Nevertheless CO2 emissions from sea shipping will continue to increase since marine transport is rapidly growing

Advanced purification of petroleum refinery wastewater by catalytic vacuum distillation.

Science.gov (United States)

Yan, Long; Ma, Hongzhu; Wang, Bo; Mao, Wei; Chen, Yashao

2010-06-15

In our work, a new process, catalytic vacuum distillation (CVD) was utilized for purification of petroleum refinery wastewater that was characteristic of high chemical oxygen demand (COD) and salinity. Moreover, various common promoters, like FeCl(3), kaolin, H(2)SO(4) and NaOH were investigated to improve the purification efficiency of CVD. Here, the purification efficiency was estimated by COD testing, electrolytic conductivity, UV-vis spectrum, gas chromatography-mass spectrometry (GC-MS) and pH value. The results showed that NaOH promoted CVD displayed higher efficiency in purification of refinery wastewater than other systems, where the pellucid effluents with low salinity and high COD removal efficiency (99%) were obtained after treatment, and the corresponding pH values of effluents varied from 7 to 9. Furthermore, environment estimation was also tested and the results showed that the effluent had no influence on plant growth. Thus, based on satisfied removal efficiency of COD and salinity achieved simultaneously, NaOH promoted CVD process is an effective approach to purify petroleum refinery wastewater. Copyright 2010 Elsevier B.V. All rights reserved.

U.S. petroleum refining: Meeting requirements for cleaner fuels and refineries

International Nuclear Information System (INIS)

Warden, R.B.

1993-01-01

A review is presented of a study carried out by the National Petroleum Council that assessed the ability of the U.S. oil industry to manufacture and supply the quantity and quality of products required in the 1990s and beyond. The competitiveness of domestic supply vs product imports was analyzed and the investment requirements and other costs associated with meeting new environmental legislation and regulations on petroleum products and refineries were addressed. In particular, the requirements of the 1990 Clean Air Act Amendments and other environmental, health, and safety initiatives, both current and prospective, were evaluated. Refineries and the logistics system were studied but not crude oil supply or service stations. The costs of stationary source health, safety and environmental regulations and requirements were evaluated for the years 1995, 2000 and 2010, and sources of U.S. light products and U.S. refinery utilization were modelled for these years. Three demand scenarios were considered: growth, no-growth, and decline. Annual expenditures for health, safety and environment programs inside refineries are expected to double in the 1990s. Expenditures of $106 billion are projected over the period 1990-2010 for new facilities and programs necessary for current and anticipated stationary source regulations. Refining and logistics costs will increase substantially. Other conclusions related to capital expenditures, refining capability, product compatibility, oxygenates and foreign product supply cost are drawn. 26 figs

Optimization model of a system of crude oil distillation units with heat integration and metamodeling

International Nuclear Information System (INIS)

Lopez, Diana C; Mahecha, Cesar A; Hoyos, Luis J; Acevedo, Leonardo; Villamizar Jaime F

2010-01-01

The process of crude distillation impacts the economy of any refinery in a considerable manner. Therefore, it is necessary to improve it taking good advantage of the available infrastructure, generating products that conform to the specifications without violating the equipment operating constraints or plant restrictions at industrial units. The objective of this paper is to present the development of an optimization model for a Crude Distillation Unit (CDU) system at a ECOPETROL S.A. refinery in Barrancabermeja, involving the typical restrictions (flow according to pipeline capacity, pumps, distillation columns, etc) and a restriction that has not been included in bibliographic reports for this type of models: the heat integration of streams from Atmospheric Distillation Towers (ADTs) and Vacuum Distillation Towers (VDT) with the heat exchanger networks for crude pre-heating. On the other hand, ADTs were modeled with Metamodels in function of column temperatures and pressures, pump a rounds flows and return temperatures, stripping steam flows, Jet EBP ASTM D-86 and Diesel EBP ASTM D-86. Pre-heating trains were modeled with mass and energy balances, and design equation of each heat exchanger. The optimization model is NLP, maximizing the system profit. This model was implemented in GAMSide 22,2 using the CONOPT solver and it found new operating points with better economic results than those obtained with the normal operation in the real plants. It predicted optimum operation conditions of 3 ADTs for constant composition crude and calculated the yields and properties of atmospheric products, additional to temperatures and duties of 27 Crude Oil exchangers.

Allocating the CO2 emissions of an oil refinery with Aumann-Shapley prices. Comment

International Nuclear Information System (INIS)

Tehrani Nejad Moghaddam, Alireza

2010-01-01

The allocation of CO 2 emissions of petroleum refineries to their oil products is a necessary step in the retrospective Well-to-Tank (WTT) analysis. These allocated emissions are used to evaluate the environmental impacts of automotive fuels' production within the refinery. Oil refining is a complex joint production system and there exists no simple and unique answer to this allocation question. Recently, Pierru proposed adapting the Aumann-Shapley cost sharing method to deal with this issue. Our paper aims at describing the conceptual and technical difficulties of this adaptation to the WTT context. Moreover, we show that this approach, as proposed by Pierru, is not applicable to any real-type refinery model. Different suggestions are provided to improve its applicability (when it is possible) in real situations. A simple numerical example as well as a real-type refinery case study is provided for illustrations. Finally, we discuss an alternative allocation approach which we believe more adapted to the WTT context. (author)

Treatment of petroleum refinery wastewater containing heavily polluting substances in an aerobic submerged fixed-bed reactor.

Science.gov (United States)

Vendramel, S; Bassin, J P; Dezotti, M; Sant'Anna, G L

2015-01-01

Petroleum refineries produce large amount of wastewaters, which often contain a wide range of different compounds. Some of these constituents may be recalcitrant and therefore difficult to be treated biologically. This study evaluated the capability of an aerobic submerged fixed-bed reactor (ASFBR) containing a corrugated PVC support material for biofilm attachment to treat a complex and high-strength organic wastewater coming from a petroleum refinery. The reactor operation was divided into five experimental runs which lasted more than 250 days. During the reactor operation, the applied volumetric organic load was varied within the range of 0.5-2.4 kgCOD.m(-3).d(-1). Despite the inherent fluctuations on the characteristics of the complex wastewater and the slight decrease in the reactor performance when the influent organic load was increased, the ASFBR showed good stability and allowed to reach chemical oxygen demand, dissolved organic carbon and total suspended solids removals up to 91%, 90% and 92%, respectively. Appreciable ammonium removal was obtained (around 90%). Some challenging aspects of reactor operation such as biofilm quantification and important biofilm constituents (e.g. polysaccharides (PS) and proteins (PT)) were also addressed in this work. Average PS/volatile attached solids (VAS) and PT/VAS ratios were around 6% and 50%, respectively. The support material promoted biofilm attachment without appreciable loss of solids and allowed long-term operation without clogging. Microscopic observations of the microbial community revealed great diversity of higher organisms, such as protozoa and rotifers, suggesting that toxic compounds found in the wastewater were possibly removed in the biofilm.

Case study of energy conservation at national refinery limited, Karachi (Pakistan)

International Nuclear Information System (INIS)

Shah, F.A.; Shaikh, M.B.; Mahesar, G.H.

2000-01-01

Petroleum refining is one of the four top most industries in Pakistan in energy consumption and to save energy is the concern of every one. In this research, authors have calculated the designed and actual efficiency of the industrial furnaces at ''Two stage distillation unit'' of National Refinery Limited, Karachi. Observations were made for energy (Oil) consumption, heat (radiation) losses, through the furnace wall, tubing and stacks flue gases. The study shows difference in the data given at the time of design and at present working data. The furnace (01-F1) is 60% efficient and recorded 9% pounds of oil more per hour, giving 18% more heat loss. The reasons behind the fuel and energy losses are discussed with the suggestions. (authors)

Leak detection in a high-pressure heat exchanger system in a refinery using radiotracer technique

International Nuclear Information System (INIS)

Samantray, J.S.; Sunil Goswami; Sharma, V.K.; Jayashree Biswal; Pant, H.J.

2014-01-01

A radiotracer investigation was carried out in a diesel hydrotreater (DHDT) unit in a refinery for leak detection in a breech-lock heat exchanger system. The main objectives of the study were to identify the leaking heat exchanger in a system with six heat exchangers and estimate the leak rate. Bromine-82 as dibromobiphenyl was selected and used as radiotracer for the investigation. The radiotracer was instantaneously injected into the suction end of the feed pump line to the heat exchanger of the DHDT unit. The movement of the tracer was measured at strategically selected locations using NaI(Tl) scintillation detectors. Based upon the results of the radiotracer investigation, it was found that out of six heat exchangers, exchanger E-1F was leaking. (author)

Environmental monitoring near urban lead refineries by photon and neutron activation analysis

International Nuclear Information System (INIS)

Paciga, J.J.; Chattopadhyay, A.; Jervis, R.E.

1974-01-01

Photon activation has been used in conjunction with neutron activation for multielement determinations in airborne particulates, soil, and hair samples collected near two secondary lead refineries in Metropolitan Toronto. Particle size distributions of suspended particulates collected with a high volume Andersen sampler are reported for Al, Sb, As, Br, Cl, Mn, Na, Pb, Ti and V. Increases in the concentrations of Pb, As and Sb associated with particles >3.3 μm diameter on certain days near the refineries has resulted in localized contamination as reflected in higher concentrations of these elements in soil. To assess Pb accumulation in local residents compared with control groups, approximately 250 hair samples were analyzed for Pb by photon activation analysis. Children living close to the refineries, especially boys, exhibit the most elevated levels: up to 20 times urban control values in some cases

Test Report Emission Test Program EPA Information Collection Request for Delayed Coking Units 736 Coker Unit

Science.gov (United States)

ARI Environmental, Inc. (ARI) was retained by Houston Refining LP (HRO) to conduct an emission test program at their refinery located in Houston, Texas. The testing was conducted on on the 736 Delayed Coking Unit (DCU) in response to EPA's ICR.

Corrosion resistance of high performance stainless steels in cooling water and other refinery environments

International Nuclear Information System (INIS)

Kovach, C.W.; Redmerski, L.S.

1984-01-01

The recent successful introduction of high performance stainless steels as tubing for seawater cooled electric utility condensers suggests that these alloys can also provide useful service in refinery heat exchanger applications. Since many of these applications involve higher temperature exposure than steam condensers, a study was conducted to evaluate crevice corrsion resistance over a range of cooling water temperature and chloride concentrations, and also to evaluate general corrosion resistance in some strong chemical and refinery environments. These stainless steels display excellent crevice corrosion resistance as well as good resistance to a variety of chemical environments that may be encountered in refinery, petrochemical and chemical plant service

Refinery water (intake and effluent) quality: Update of 1970s with 1990s toxicity testing

International Nuclear Information System (INIS)

Chapman, P.M.; Paine, M.D.; Moran, T.; Kierstead, T.

1994-01-01

The quality of two separate refinery intake waters and effluents was investigated: Petro-Canada (Oakville) and Novacor (Corunna Operations). This study comprised eight different test organized and 22 different toxicity end points, was built on and complemented pioneering 1970s work at the Petro-Canada refinery, and was designed to (a) determine any changes in effluent quality, (b) determine any previously unsuspected effluent toxicity, and (c) determine any potential for chronic toxicity in the effluent. Although Petro-Canada has steadily reduced contaminants in its effluent since the earlier study, toxicity has not changed and no new toxic effects were identified. Effect thresholds for the most sensitive animal species (Daphnia pulex) were 1 to 10% effluent in both studies. The Novacor effluent had lesser effects on biota than the Petro-Canada effluent. Intake waters demonstrated toxicity in some tests. Chronic effects on invertebrates and fish in receiving waters are predicted not to occur in the Novacor effluent is diluted 10- to 20-fold and the Petro-Canada effluent is diluted 50- to 100-fold

Treatment of Mineral Oil Refinery Wastewater in Microbial Fuel Cells Using Ionic Liquid Based Separators

Directory of Open Access Journals (Sweden)

Hasna Addi

2018-03-01

Full Text Available Microbial fuel cells (MFCs are an environmentally friendly technology that can recover electricity directly from several wastes at ambient temperatures. This work explores the use of mineral oil refinery wastewater as feedstock in single-chamber air-cathode MFC devices. A polymer inclusion membrane based on the ionic liquid methyltrioctylammonium chloride, [MTOA+][Cl−], at a concentration of 70% w/w, was used as separator, showing a good efficiency in power production and chemical oxygen demand (COD removal. The power and the chemical oxygen demand removal reached values of 45 mW/m3 and over 80%, respectively. The evolution of other parameters of the wastewater including nitrites, phosphates and sulphates were also studied. Kjeldahl nitrogen and sulphates were significantly reduced during MFC operation. The results show that mineral oil refinery wastewater can be used as feedstock in air breathing cathode-microbial fuel cells based on polymer ionic liquid inclusion membranes. This configuration could represent a good alternative for wastewater depuration while producing energy during the process.

Continues treatment of oily sludge at Colombian refineries

International Nuclear Information System (INIS)

Echeverria, Victor; Monsalve, Gladys; Vidales, Humberto

2002-01-01

The Colombian Petroleum institute - ICP, the research and development branch of Ecopetrol has developed a unique technological package used to treat oily sludge in a continuous way. The sludge comes from a refinery with 220000 barrels of crude per day load, located in the Middle Madgalena River Valley in Colombia. The technological package allows for a) the recovery of the hydrocarbon contained in oily wastes (up to 50%) b) the elimination of the oil contained in solid using a biodegradation process and, c) the availability economically and technically feasible solution to handle oily sludge generated in the refinery. The oily treated in this process come from maintenance of refinery's equipment and also from the physical chemical separation process at the industrial wastewater treatment plant. Oily sludge is a complex system where light and heavy oils, contaminated water and contaminated solids coexist in the form of direct, inverse and multiple emulsions. The comprehensive technological package allows the treatment of oily sludge in a cost effective way. ICP technological package developed includes technologies combining mechanical, thermal, chemical and electrostatic dehydration techniques and stimulated and intensive bioremediation to decontamination of solids saturated with residual oil. This technological package brings a solution to old environmental problem caused by the inappropriate final disposal of oily wastes such as storage in ponds, marshes and open pits: Nowadays wastes generated are treated in a continuous process that is environmentally friendly and economically profitable

Integration of RTO and MPC in the Hydrogen Network of a Petrol Refinery

Directory of Open Access Journals (Sweden)

Cesar de Prada

2017-01-01

Full Text Available This paper discusses the problems associated with the implementation of Real Time Optimization/Model Predictive Control (RTO/MPC systems, taking as reference the hydrogen distribution network of an oil refinery involving eighteen plants. This paper addresses the main problems related to the operation of the network, combining data reconciliation and a RTO system, designed for the optimal generation and redistribution of hydrogen, with a predictive controller for the on-line implementation of the optimal policies. This paper describes the architecture of the implementation, showing how RTO and MPC can be integrated, as well as the benefits obtained in terms of improved information about the process, increased hydrocarbon load to the treatment plants and reduction of the hydrogen required for performing the operations.

Optimization model of a system of crude oil distillation units whit heat integration and meta modeling

International Nuclear Information System (INIS)

Lopez, Diana C; Mahecha, Cesar A; Hoyos, Luis J; Acevedo, Leonardo; Villamizar Jaime F

2009-01-01

The process of crude distillation impacts the economy of any refinery in a considerable manner. Therefore, it is necessary to improve it taking good advantage of the available infrastructure, generating products that conform to the specifications without violating the equipment operating constraints or plant restrictions at industrial units. The objective of this paper is to present the development of an optimization model for a Crude Distillation Unit (CDU) system at a ECOPETROL S.A. refinery in Barrancabermeja, involving the typical restrictions (flow according to pipeline capacity, pumps, distillation columns, etc) and a restriction that has not been included in bibliographic reports for this type of models: the heat integration of streams from Atmospheric Distillation Towers (ADTs) and Vacuum Distillation Towers (VDT) with the heat exchanger networks for crude pre-heating. On the other hand, ADTs were modeled with Meta models in function of column temperatures and pressures, pumparounds flows and return temperatures, stripping steam flows, Jet EBP ASTM D-86 and Diesel EBP ASTM D-86. Pre-heating trains were modeled with mass and energy balances, and design equation of each heat exchanger. The optimization model is NLP, maximizing the system profit. This model was implemented in GAMSide 22,2 using the CONOPT solver and it found new operating points with better economic results than those obtained with the normal operation in the real plants. It predicted optimum operation conditions of 3 ADTs for constant composition crude and calculated the yields and properties of atmospheric products, additional to temperatures and duties of 27 Crude Oil exchangers.

Evaluation of phase separator number in hydrodesulfurization (HDS) unit

Science.gov (United States)

Jayanti, A. D.; Indarto, A.

2016-11-01

The removal process of acid gases such as H2S in natural gas processing industry is required in order to meet sales gas specification. Hydrodesulfurization (HDS)is one of the processes in the refinery that is dedicated to reduce sulphur.InHDS unit, phase separator plays important role to remove H2S from hydrocarbons, operated at a certain pressure and temperature. Optimization of the number of separator performed on the system is then evaluated to understand the performance and economics. From the evaluation, it shows that all systems were able to meet the specifications of H2S in the desired product. However, one separator system resulted the highest capital and operational costs. The process of H2S removal with two separator systems showed the best performance in terms of both energy efficiency with the lowest capital and operating cost. The two separator system is then recommended as a reference in the HDS unit to process the removal of H2S from natural gas.

Carbon Capture and Sequestration (via Enhanced Oil Recovery) from a Hydrogen Production Facility in an Oil Refinery

Energy Technology Data Exchange (ETDEWEB)

Stewart Mehlman

2010-06-16

The project proposed a commercial demonstration of advanced technologies that would capture and sequester CO2 emissions from an existing hydrogen production facility in an oil refinery into underground formations in combination with Enhanced Oil Recovery (EOR). The project is led by Praxair, Inc., with other project participants: BP Products North America Inc., Denbury Onshore, LLC (Denbury), and Gulf Coast Carbon Center (GCCC) at the Bureau of Economic Geology of The University of Texas at Austin. The project is located at the BP Refinery at Texas City, Texas. Praxair owns and operates a large hydrogen production facility within the refinery. As part of the project, Praxair would construct a CO2 capture and compression facility. The project aimed at demonstrating a novel vacuum pressure swing adsorption (VPSA) based technology to remove CO2 from the Steam Methane Reformers (SMR) process gas. The captured CO2 would be purified using refrigerated partial condensation separation (i.e., cold box). Denbury would purchase the CO2 from the project and inject the CO2 as part of its independent commercial EOR projects. The Gulf Coast Carbon Center at the Bureau of Economic Geology, a unit of University of Texas at Austin, would manage the research monitoring, verification and accounting (MVA) project for the sequestered CO2, in conjunction with Denbury. The sequestration and associated MVA activities would be carried out in the Hastings field at Brazoria County, TX. The project would exceed DOE’s target of capturing one million tons of CO2 per year (MTPY) by 2015. Phase 1 of the project (Project Definition) is being completed. The key objective of Phase 1 is to define the project in sufficient detail to enable an economic decision with regard to proceeding with Phase 2. This topical report summarizes the administrative, programmatic and technical accomplishments completed in Phase 1 of the project. It describes the work relative to project technical and design activities

A dynamic, efficient, and flexible metal HAP standard for petroleum refinery FCCs

Energy Technology Data Exchange (ETDEWEB)

Rao, P. [Pennsylvania State Univ., University Park, PA (United States)

2000-07-01

The Petroleum Refinery Maximum Achievable Control Technology (MACT) II standards were recently announced by the United States Environmental Protection Agency. The standards are designed to control hazardous air pollutants (HAPs) from fluid catalytic cracking (FCC), catalytic reforming and sulfur recovery units. The major role of feed quality in determining emissions of heavy metals, sulfur oxides (SOx) and nitrous oxides from FCC vents were discussed. The impact of FCC feed quality on carbon dioxide emissions was also examined. Some potential loopholes in the SOx new source performance standard for FCCs were also identified. This paper also outlined regulatory issues that occur when pollutant emission rates vary with raw material or fuel quantity. When input qualities vary, the format of emission standards take on special meaning. In particular, proportional control standards perform poorly resulting in environmentally damaged inputs. Precautions should be taken in profit-induced moves to avoid lower quality inputs, particularly at this time for setting new directions for a cleaner environment. 22 refs., 2 tabs., 10 figs.

The acid refinery wastes in environment

International Nuclear Information System (INIS)

Samesova, D.; Ladomersky, J.; Hroncova, E.

2003-01-01

The aim of our paper is to assign ways and means of the pollution extension from the old landfills of the petrochemical sludges. In the past the sludges were deposited in sludge landfills. Nowadays remediation of the landfills is a key problem. We analyse condition of the refinery sludges latching. We found out the meaning influences of leachate time, temperature, concentration and liquid kind. (authors)

200-UP-2 Operable Unit technical baseline report

International Nuclear Information System (INIS)

Deford, D.H.

1991-02-01

This report is prepared in support of the development of a Remedial Investigation/Feasibility Study (RI/FS) Work Plan for the 200-UP-2 Operable Unit by EBASCO Environmental, Incorporated. It provides a technical baseline of the 200-UP-2 Operable Unit and results from an environmental investigation undertaken by the Technical Baseline Section of the Environmental Engineering Group, Westinghouse Hanford Company (Westinghouse Hanford). The 200-UP-2 Operable Unit Technical Baseline Report is based on review and evaluation of numerous Hanford Site current and historical reports, Hanford Site drawings and photographs and is supplemented with Hanford Site inspections and employee interviews. No field investigations or sampling were conducted. Each waste site in the 200-UP-2 Operable Unit is described separately. Close relationships between waste units, such as overflow from one to another, are also discussed. The 200-UP-2 Operable Unit consists of liquid-waste disposal sites in the vicinity of, and related to, U Plant operations in the 200 West Area of the Hanford Site. The ''U Plant'' refers to the 221-U Process Canyon Building, a chemical separations facility constructed during World War 2. It also includes the Uranium Oxide (UO 3 ) Plant, which was constructed at the same time and, like the 221-U Process Canyon Building, was later converted for other missions. Waste sites in the 200-UP-2 Operable Unit are associated with the U Plant Uranium Metal Recovery Program mission that occurred between 1952 and 1958 and the UO 3 Plant's ongoing uranium oxide mission and include one or more cribs, reverse wells, french drains, septic tanks and drain fields, trenches, catch tanks, settling tanks, diversion boxes, waste vaults, and the lines and encasements that connect them. 11 refs., 1 tab

Catalytic hydrotreatment of refinery waste

Energy Technology Data Exchange (ETDEWEB)

1989-01-01

The object of the project is to produce liquid hydrocarbons by the catalytic hydroprocessing of solid refinery wastes (hard pitches) in order to improve the profitability of deep conversion processes and reduce the excess production of heavy fuels. The project was mostly carried out on the ASVAHL demonstration platform site, at Solaize, and hard pitches were produced primarily by deasphalting of atmospheric or vacuum distillation residues. The project includes two experimental phases and an economic evaluation study phase. In phase 1, two granular catalysts were used to transform pitch into standard low sulphur fuel oil: a continuously moving bed, with demetallation and conversion catalyst; a fixed bed, with hydrorefining catalyst. In phase 2 of the project, it was proven that a hydrotreatment process using a finely dispersed catalyst in the feedstock, can, under realistic operating conditions, transform with goods yields hard pitch into distillates that can be refined through standard methods. In phase 3 of the project, it was shown that the economics of such processes are tightly linked to the price differential between white and black oil products, which is expected to increase in the future. Furthermore, the evolution of environmental constraints will impel the use of such methods, thus avoiding the coproduction of polluting solid residues.

Potential and optimization of two-phase anaerobic digestion of oil refinery waste activated sludge and microbial community study

Science.gov (United States)

Wang, Qinghong; Liang, Ying; Zhao, Peng; Li, Qing X.; Guo, Shaohui; Chen, Chunmao

2016-01-01

Oil refinery waste activated sludge produced from oil wastewater biological treatment is a major industrial sludge. Two-phase anaerobic digestion of oil refinery waste activated sludge was studied for the first time. Thermal pretreatment under 170 °C is effective on sludge solubilization. At the optimum hydrolytic-acidogenic condition which was pH of 6.5, temperature of 55 °C and HRT of 2 days, 2754 mg/L volatile fatty acids (VFAs) were produced and acetic acid and butyric acid were the key components. Comparative studies of single-phase and two-phase anaerobic digestion in terms of organic removal, biogas production and methane concentration were conducted. The cumulative methane production and soluble COD (SCOD) removal efficiency in the two-phase system were 228 mL/g COD added and 77.8%, respectively, which were 1.6 and 2.1 times higher than those in single-phase anaerobic digestion. Such improved performance is attributed to intensification of dominant microbial population in separated reactors. Caloramator, Ureibacillus, Dechloromonas, Petrobacter, and T78 played important roles in hydrolytic-acidification and oil-organics degradation. Syntrophic bacteria in the family Porphyromonadaceae and the genus Anaerobranca provide acetate for methanogen. The results demonstrated the potential and operating condition of two-phase anaerobic digestion in treatment of oil refinery waste activated sludge. PMID:27905538

Allocating the CO{sub 2} emissions of an oil refinery with Aumann-Shapley prices. Comment

Energy Technology Data Exchange (ETDEWEB)

Tehrani Nejad Moghaddam, Alireza [Department of Economic Studies, Institut Francais du Petrole (I.F.P.), 92852, Rueil-Malmaison (France)

2010-01-15

The allocation of CO{sub 2} emissions of petroleum refineries to their oil products is a necessary step in the retrospective Well-to-Tank (WTT) analysis. These allocated emissions are used to evaluate the environmental impacts of automotive fuels' production within the refinery. Oil refining is a complex joint production system and there exists no simple and unique answer to this allocation question. Recently, Pierru proposed adapting the Aumann-Shapley cost sharing method to deal with this issue. Our paper aims at describing the conceptual and technical difficulties of this adaptation to the WTT context. Moreover, we show that this approach, as proposed by Pierru, is not applicable to any real-type refinery model. Different suggestions are provided to improve its applicability (when it is possible) in real situations. A simple numerical example as well as a real-type refinery case study is provided for illustrations. Finally, we discuss an alternative allocation approach which we believe more adapted to the WTT context. (author)

Improving cost-effectiveness for the furnace in a full-scale refinery plant with reuse of waste tail gas fuel

Energy Technology Data Exchange (ETDEWEB)

Lee, Chien-Li [Department of Leisure and Recreation Management, Diwan University, Tainan (China); Hou, Shuhn-Shyurng [Department of Mechanical Engineering, Kun Shan University (China); Lee, Wen-Jhy [Department of Environmental Engineering, National Cheng Kung University (China); Jou, Chih-Ju G. [Department of Safety, Health and Environmental Engineering, National Kaohsiung First University of Science and Technology, 2, Juoyue Rd., Nantz District, Kaohsiung 811 (China)

2010-02-15

The waste tail gas fuel emitted from refinery plant in Taiwan e.g. catalytic reforming unit, catalytic cracking unit and residue desulfurization unit, was recovered and reused as a replacement fuel. In this study, it was slowly added to the fuel stream of a heater furnace to replace natural gas for powering a full-scale distillation process. The waste tail gas fuel contained on average 60 mol% of hydrogen. On-site experimental results show that both the flame length and orange-yellowish brightness decrease with increasing proportion of waste gas fuel in the original natural gas fuel. Moreover, the adiabatic flame temperature increases as the content of waste gas fuel is increased in the fuel mixture since waste gas fuel has a higher adiabatic flame temperature than that of natural gas. The complete replacement of natural gas by waste gas fuel for a heater furnace operating at 70% loading (i.e. 3.6 x 10{sup 7} kcal/h of combustion capacity) will save 5.8 x 10{sup 6} m{sup 3} of natural gas consumption, and 3.5 x 10{sup 4} tons (or 53.4%) of CO{sub 2} emission annually. Recovering and reusing the waste tail gas fuel as natural gas replacement will achieve tremendous savings of natural gas usage and effectively lower the emission of carbon dioxide. (author)

Conservation and reuse of water in Brazilian petroleum refineries; Conservacao e reuso de agua em refinarias de petroleo no Brasil

Energy Technology Data Exchange (ETDEWEB)

Pombo, Felipe Ramalho; Magrini, Alessandra; Szklo, Alexandre Salem [Universidade Federal do Rio de Janeiro (PPE/COPPE/UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia. Programa de Planejamento Energetico], Emails: frpombo@ppe.ufrj.br, ale@ppe.ufrj.br, szklo@ppe.ufrj.br

2010-07-01

This paper views to present the main technologies for effluent treatment of petroleum refineries having as target the reuse. An analysis of international and Brazilian experiences of water reuse in petroleum refineries is performed viewing to support the proposition of recommendations for Brazilian refineries.

Opportunities and challenges at the interface between petrochemicals and refinery. The OMV view

Energy Technology Data Exchange (ETDEWEB)

Lichtscheidl, J. [OMV Refining and Marketing GmbH, Vienna (Austria)

2007-07-01

OMV's refineries have been integrated into petrochemicals since the first steam cracker came on line in 1970. The refineries in Schwechat, Burghausen and Romania, especially Arpechim, have significant petrochemical capacities. In 1998 PCD was merged with Borealis, a leading producer of high grade polymers. OMV's initial 25% stake in Borealis increased to 36 in 2007. The last years have seen major investments in Schwechat and Burghausen: Schwechat's cracker was expanded by approximately 150 KTA to a nominal 500 KTA of ethylene. And in Burghausen the revamp of the cracker has been combined with a metathesis unit in order to feed a new 330 KTA polypropylene plant. The polymer market is still growing. However, the bulk of investments to increase capacity are located in the Middle East and in the Asia-Pacific region, predominately in China. As more and more products from these regions find their way to Europe, the European petrochemicals industry faces fierce competition. The response is restructuring: the creation of Arkema (Total), the takeover of BP's petrochemical assets by INEOS, the disposal of Shell-BASF subsidiary Basell to Haldia Petrochemical and Accent Industries, and the transfer of Statoil's interest in Borealis to IPIC and OMV. And most recently, Basell's acquisition of Lyondell. Compared with competitors in the Middle East and the Asia-Pacific region, producers in Europe are burdened with serious disadvantages: fairly old, small units and high costs of labor, energy and raw materials. There is no single solution. OMV, however, will continue to follow the strategies that have been successful so far: - Ever closer integration of refining and petrochemicals; - Capturing market opportunities for profitable growth; -Remaining market orientated. (orig.)

Advanced Oxidation Processes (AOPs for Refinery Wastewater Treatment Contains High Phenol Concentration

Directory of Open Access Journals (Sweden)

Azizah Alif Nurul

2018-01-01

Full Text Available Petroleum Refinery wastewater is characterized by a high phenol content. Phenol is toxic and resistant to biological processes for treatment of the petroleum refinery wastewater. The combination of an AOP and a biological process can be used for treatment of the refinery wastewater. It is necessary to conduct a study to determine the appropriate condition of AOP to meet the phenol removal level. Two AOP configurations were investigated: H2O2 / UV and H2O2 / UV / O3. From each process samples, COD, phenol and pH were measured. The oxidation was carried out until the targeted phenol concentration of treated effluent were obtained. The better result obtained by using process H2O2 / UV / O3 with the H2O2 concentration 1000 ppm. After 120 minutes, the final target has been achieved in which phenol concentration of 37.5 mg/L or phenol degradation of 93.75%.

Analysis of operating reliability of WWER-1000 unit

International Nuclear Information System (INIS)

Bortlik, J.

1985-01-01

The nuclear power unit was divided into 33 technological units. Input data for reliability analysis were surveys of operating results obtained from the IAEA information system and certain indexes of the reliability of technological equipment determined using the Bayes formula. The missing reliability data for technological equipment were used from the basic variant. The fault tree of the WWER-1000 unit was determined for the peak event defined as the impossibility of reaching 100%, 75% and 50% of rated power. The period was observed of the nuclear power plant operation with reduced output owing to defect and the respective time needed for a repair of the equipment. The calculation of the availability of the WWER-1000 unit was made for different variant situations. Certain indexes of the operating reliability of the WWER-1000 unit which are the result of a detailed reliability analysis are tabulated for selected variants. (E.S.)

Predicting refinery effluent toxicity on the basis of hydrocarbon composition determined by GCxGC analysis

Energy Technology Data Exchange (ETDEWEB)

Whale, G. [and others

2013-04-15

A high resolution analytical method for determining hydrocarbon blocks in petroleum products by comprehensive two-dimensional gas chromatography (GCxGC) was used for the analysis of petroleum hydrocarbons extracted from refinery effluents. From 105 CONCAWE refineries in Europe 111 refinery effluents were collected in the period June 2008 to March 2009 (CONCAWE, 2010). The effluents were analysed for metals, standard effluent parameters (including Chemical Oxygen Demand (COD), Biochemical Oxygen Demand (BOD), oil in water (OiW), GCxGC speciated hydrocarbons, BTEX (Benzene, Toluene, Ethylbenzene, and Xylenes) and volatile organic compounds. This report describes the subsequent analysis of the GCxGC data, as described in hydrocarbon blocks, and uses the PETROTOX model, to predict the environmental toxicity (i.e. ecotoxicity) of the discharged effluents. A further analysis was undertaken to address the potential environmental impact of these predicted effects initially using default dilution factors and then,when necessary site specific factors. The report describes all the methods used to arrive at the predictions, and shows that for the majority of refinery effluents direct toxicity effects in the effluents are not anticipated. Furthermore, when applying either the EU Risk Assessment Technical Guidance Document (TGD) default dilution factors or site specific dilution factors, none of the refineries are predicted to exerting either acute or chronic toxicity to organisms in the receiving aquatic environment, based on their hydrocarbon composition present in the effluent samples.

Chemical composition of individual aerosol particles from working areas in a nickel refinery.

Science.gov (United States)

Höflich, B L; Wentzel, M; Ortner, H M; Weinbruch, S; Skogstad, A; Hetland, S; Thomassen, Y; Chaschin, V P; Nieboer, E

2000-06-01

Individual aerosol particles (n = 1170) collected at work stations in a nickel refinery were analyzed by wavelength-dispersive electron-probe microanalysis. By placing arbitrary restrictions on the contents of sulfur and silicon, the particles could be divided into four main groups. Scanning electron images indicated that most of the particles examined were relatively small (refinery intermediates. The implications of the findings for aerosol speciation measurements, toxicological studies and interpretation of adverse health effects are explored.

Licensed operating reactors. Operating units status report, data as of 2-28-79

International Nuclear Information System (INIS)

1979-03-01

This report is divided into three sections: the first contains monthly highlights and statistics for commercial operating units, and errata from previously reported data; the second is a compilation of detailed information on each unit, provided by NRC Regional Offices and IE Headquarters; and the third section is an appendix containing comparative statistics of U.S. nuclear/fossil capacity, identification of nuclear power plants within regional Electric Reliability Councils, the relative status of U.S. nuclear electric production to all U.S. electric production by state, and selected Edison Electric Institute operating statistics. Throughout the report, statistical factors for periods greater than a report month, or for more than one unit, are computed as the arithmetic average of each unit's individual operating statistics. The statistical factors for each unit for the report month are computed from actual power production for the month. The factors for the life-span of each unit (the ''Cumulative'' column) are reported by the utility and are not entirely re-computed by NRC. Utility power production data is checked for consistency with previously submitted statistics

HERA an HTR for use in a refinery

International Nuclear Information System (INIS)

Chaubernard, P.

1977-01-01

It is shown that it was technically possible to use a High Temperature Reactor to provide a large part of the energy (process heat, steam, electricity) consumed in a refinery. Nevertheless, economic calculations have lead to a prime cost of spared crude oil twice the existing price

Monitoring of Emissions From a Refinery Tank Farm Using a Combination of Optical Remote Sensing Techniques

Science.gov (United States)

Polidori, A.; Tisopulos, L.; Pikelnaya, O.; Mellqvist, J.; Samuelsson, J.; Marianne, E.; Robinson, R. A.; Innocenti, F.; Finlayson, A.; Hashmonay, R.

2016-12-01

Despite great advances in reducing air pollution, the South Coast Air Basin (SCAB) still faces challenges to attain federal health standards for air quality. Refineries are large sources of ozone precursors and, hence contribute to the air quality problems of the region. Additionally, petrochemical facilities are also sources of other hazardous air pollutants (HAP) that adversely affect human health, for example aromatic hydrocarbons. In order to assure safe operation, decrease air pollution and minimize population exposure to HAP the South Coast Air Quality Management District (SCAQMD) has a number of regulations for petrochemical facilities. However, significant uncertainties still exist in emission estimates and traditional monitoring techniques often do not allow for real-time emission monitoring. In the fall of 2015 the SCAQMD, Fluxsense Inc., the National Physical Laboratory (NPL), and Atmosfir Optics Ltd. conducted a measurement study to characterize and quantify gaseous emissions from the tank farm of one of the largest oil refineries in the SCAB. Fluxsense used a vehicle equipped with Solar Occultation Flux (SOF), Differential Optical Absorption Spectroscopy (DOAS), and Extractive Fourier Transform Infrared (FTIR) spectroscopy instruments. Concurrently, NPL operated their Differential Absorption Lidar (DIAL) system. Both research groups quantified emissions from the entire tank farm and identified fugitive emission sources within the farm. At the same time, Atmosfir operated an Open Path FTIR (OP-FTIR) spectrometer along the fenceline of the tank farm. During this presentation we will discuss the results of the emission measurements from the tank farm of the petrochemical facility. Emission rates resulting from measurements by different ORS methods will be compared and discussed in detail.

Bio-refinery approach for spent coffee grounds valorization.

Science.gov (United States)

Mata, Teresa M; Martins, António A; Caetano, Nídia S

2018-01-01

Although normally seen as a problem, current policies and strategic plans concur that if adequately managed, waste can be a source of the most interesting and valuable products, among which metals, oils and fats, lignin, cellulose and hemicelluloses, tannins, antioxidants, caffeine, polyphenols, pigments, flavonoids, through recycling, compound recovery or energy valorization, following the waste hierarchy. Besides contributing to more sustainable and circular economies, those products also have high commercial value when compared to the ones obtained by currently used waste treatment methods. In this paper, it is shown how the bio-refinery framework can be used to obtain high value products from organic waste. With spent coffee grounds as a case study, a sequential process is used to obtain first the most valuable, and then other products, allowing proper valorization of residues and increased sustainability of the whole process. Challenges facing full development and implementation of waste based bio-refineries are highlighted. Copyright © 2017 Elsevier Ltd. All rights reserved.

Sounding pollution and the refinery environmental risks; A poluicao sonora e os riscos ambientais das refinarias

Energy Technology Data Exchange (ETDEWEB)

NONE

2005-07-01

This chapter gives a general overview on the effects of the sound pollution, the principal pollutants emitted by the oil refineries, control actions for the sound waves emissions, the minimization actions, the risk concepts and evaluation, the risk perception and the accidents in refineries.

77 FR 44685 - ConocoPhillips Company, Trainer Refinery, Including On-Site Leased Workers From Shrack, Young...

Science.gov (United States)

2012-07-30

..., Trainer Refinery, Including On-Site Leased Workers From Shrack, Young, and Associates, Inc., and Project Control Associates, Trainer, PA; Notice of Revised Determination on Reconsideration On April 30, 2012, the... applicable to workers and former workers of ConocoPhillips Company, Trainer Refinery, Trainer, Pennsylvania...

40 CFR Table 40 to Subpart Uuu of... - Requirements for Installation, Operation, and Maintenance of Continuous Opacity Monitoring...

Science.gov (United States)

2010-07-01

... CATEGORIES National Emission Standards for Hazardous Air Pollutants for Petroleum Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU, Table 40 Table 40...

Economics and the refinery's CO2 emissions allocation problem

International Nuclear Information System (INIS)

Pierru, A.

2007-01-01

The establishment of a market for CO 2 emission rights in Europe leads oil-refining companies to add a cost associated with carbon emissions to the objective function of linear programming models used to manage refineries. These models may be used to compute the marginal contribution of each finished product to the CO 2 emissions of the refinery. Babusiaux (Oil. Gas Sci. Technol., 58, 2003, 685-692) has shown that, under some conditions, this marginal contribution is a relevant means of allocating the carbon emissions of the refinery. Thus, it can be used in a well-to-wheel Life Cycle Assessment. In fact, this result holds if the demand equations are the only binding constraints with a non-zero right-hand side coefficient. This is not the case for short-run models with fixed capacity. Then, allocating CO 2 emissions on a marginal basis tends to over-value (or undervalue) the total volume of emissions. In order to extend the existing methodology, we discuss two distinct solutions to this problem, inspired by economic theory: adapting either the Aumann-Shapley cost sharing method (Values of non-atomic games, 1974, Princeton University Press) or the Ramsey pricing formula (Econ. J., 37, 1927, 47-61; J. Econ. Theory, 3, 1971, 219-240). We compare these two solutions, with a strong argument in favour of Ramsey prices, based on the determination of the optimal environmental tax rate to which imported finished products should be subject. (author)

Prevention of refinery tower plugging by residual oil gellant chemicals in crude-pilot plant evaluation of alternative oil gellants

Energy Technology Data Exchange (ETDEWEB)

Taylor, R.S.; Fyten, G.C.; Cheng, A. [Halliburton Energy Services, Calgary, AB (Canada); Stemler, P.S. [Petro-Canada Oil and Gas Inc., Calgary, AB (Canada); Lemieux, A. [Omnicon Consultants Inc., Calgary, AB (Canada)

2006-07-01

Tower fouling at petroleum refineries is related to background volatile phosphorus components originating from phosphate ester oil gellants. In an attempt to reduce the cost of unplanned refinery shut downs, the Canadian Association of Petroleum Producers (CAPP) may institute a new specification in July 2006 of 0.5 ppm maximum volatile phosphorus in crude. In concept, volatile phosphorus can be removed from phosphate esters by eliminating volatile components in the original phosphate ester gellant. However, the issue of of whether modified phosphate esters can really reduce refinery tower fouling has been questioned. For that reason, this study focused on water hydrolysis which may occur in a distillation tower, causing localized areas of acidity and causticity. Halogenation reactions could occur in the presence of acid at high temperatures if halogen ions are present. The source of halide ions could be any salts that have not been removed in the de-salters. Full-scale testing at a pilot plant facility was conducted over several days with flowback captured after actual fracturing treatments. Fouling of distillation tower trays was measured along with fouling of the packing material. The study examined how fouling was influenced by changes in operating parameters such as rate, temperature, or pressure during each test. Three full-scale pilot evaluations were conducted using actual flowback fluids from fracturing treatments conducted with 3 different oil gellants: conventional phosphate ester, modified phosphate and phosphonate ester. The comparison of actual tower fouling between these alternative gellants can be used as a guide when choosing oil gellant systems to reduce refinery tower and heat exchanger fouling. It was concluded that phosphonate gellants are hydrolytically stable at higher temperatures and should minimize volatile phosphorus created through the hydrolysis of phosphate esters. However, they are more expensive since they are more complex to create

Refinery siting workbook: appendices C to O

Energy Technology Data Exchange (ETDEWEB)

1980-07-01

Applicable laws and permits available for the selection and building of petroleum refineries are enclosed. A glossary of pertinent terms is also included. References related to the National Environmental Policy Act, the Clean Air Act, the Federal Water Pollution Control Act, Resource Conservation and Recovery Act, Toxic Substance Control Act, and Wetlands and Coastal Zone are included. Permit information is also presented. (DC)

Smart microgrids in refineries, Mexico case; Microrredes inteligentes en refinerias, caso Mexico

Energy Technology Data Exchange (ETDEWEB)

Estrada Garcia, Javier Alejandro; Linan Garcia, Roberto; Picasso Blanquel, Cuitlahuac; Silva Farias, Jose Luis [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

2013-03-01

In this paper we present the technological trends on smart microgrids for refineries, case Mexico. Distributed generation on refineries is a model of microgrid with great challenges to solve, considering renewable energy. Also it discusses the scenario in bidirectional connection from refineries to the utility supergrid Comision Federal de Electricidad (CFE by its acronym in Spanish) and how to reach the development of a smart microgrid. We look different scenarios in power systems refineries, and the feasibility to achieve and develop the technology concepts in smart grid, such as: demand response in real time, exchange of energy between microgrid with supergrid-CFE and viceversa, energy efficiency, microgrid automation, selfhealing/real time autorecovery fault in power systems, storage energy and its application on power systems blackout in refineries. Finally we discussed the concepts that represent the greatest challenges to be solved on the smart microgrids and consider obtaining alternatives solution in medium or long term. [Spanish] En este documento se presentan las tendencias tecnologicas en micro redes inteligentes para refinerias, en el caso de Mexico. La generacion distribuida en refinerias es un modelo de micro red con grandes desafios por resolver, considerando la energia renovable. Se analiza tambien el escenario en conexion bidireccional de refinerias a la super red de la Comision Federal de Electricidad (CFE), la empresa electrica mexicana, y como lograr el desarrollo de una micro red inteligente. Se consideran diferentes escenarios en refinerias de sistemas de potencia, y la factibilidad de alcanzar y desarrollar los conceptos de tecnologia en una red inteligente, tales como: respuesta de demanda en tiempo real, intercambio de energia entre la micro red con la super red de la CFE y viceversa, eficiencia de energia, automatizacion de micro redes, autorrecuperacion de fallas en autoarreglo/tiempo real. En sistemas de potencia, almacenamiento de

Assessment of the effect of effluent discharge from coffee refineries ...

African Journals Online (AJOL)

Admin

2Department of Environmental Health, Jimma University, Jimma, Ethiopia. ... cherries, transport them hydraulically through the pulping ..... Table 2. Interaction effects of effluent discharges by coffee refineries on physical characteristics between.

CARBON ACCOUNTING INITIATIVES: CASE STUDY OF A PETROLEUM REFINERY IN MALAYSIA TO PREPARE FOR FUTURE CARBON MARKET

Directory of Open Access Journals (Sweden)

AMANDA H.L. CHEE

2010-06-01

Full Text Available Petroleum refining process produces a large amount of atmospheric pollutants including greenhouse gases which are attributed to global warming. The international community inevitably addressed the global warming issue by introducing a market-based mechanism known as Emission Trading Systems (ETS under the Kyoto Protocol which imposes binding limits to developed nations using three flexibility mechanisms, including the Clean Development Mechanism (CDM. This case study was carried out in a petroleum refinery in Malaysia to explore the possibility for the refinery to participate in CDM. Information was collected through observatory field survey at the refinery and documentation review. Results show that the current monitoring tool using indirect calculation of fuel consumption provides a comprehensive coverage of emission sources but the reporting frequency should be increased for data accuracy. An accounting system was then created to predict the emissions gap of the refinery with reference to the baseline-year set by the Kyoto Protocol. It was concluded that the refinery showed promising potential to participate in CDM to benefit from technology transfer by selling their ‘credits’ to Annex I countries despite the uncertainty on the impact of the carbon market in a Non-Annex I country.

Initial startup and operations of Yonggwang Units 3 and 4

International Nuclear Information System (INIS)

Collier, T.J.; Chari, D.R.; Kiraly, F.

1996-01-01

A significant milestone in the nuclear power industry was achieved in 1995, when Yonggwang (YGN) Units 3 and 4 were accepted into in commercial operation by Korea Electric Power Corporation (KEPCO). YGN Unit 3 was accepted into commercial operation on March 31, 1995, the original date established during project initiation. YGN Unit 4 was accepted into operation on January 1, 1996, 3 months ahead of schedule. Each YGN unit produces approximately 1,050 Mwe and supplies approximately ten percent of the total electric power demand in the Republic of Korea (ROK). The overall plant efficiency is approximately 37% which is at least 1% higher than most nuclear units. Since achieving commercial operation, YGN Unit 3 has operated at essentially full power which has resulted in an annual performance rate in excess of 85%. YGN Unit 3 is the first of six pressurized water reactors which are currently under design and construction in the ROK and serves as the reference design for the Korean Standard Nuclear Power Plant program. Both YGN Units 3 and 4 include a System 800 Nuclear Steam Supply System (NSSS). The NSSS is rated at 2,815 Mwth and is the ABB-CE standard design. The design includes numerous advanced design features which enhance plant safety, performance and operability. A well executed startup test program was successfully completed on both units prior to commercial operation. A summary of the YGN NSSS design features, the startup test program and selected test results demonstrating the performance of those features are presented in this paper

Operating performance of LWR nuclear generating units

International Nuclear Information System (INIS)

Pia, S.

1984-01-01

This work aims at reviewing, on the basis of historical data, the operational problem areas which explain the degree of availability and productivity achieved up to now by nuclear power plants in commercial operation in the world. The operating performance data of nuclear power plants area analysed with respect to plant type, size and other significant reference parameters and they are evaluated also by comparison with fossil generating unit data. Major performance indices data are presented for both nuclear and fossil units type and distribution of outage causes. Unplanned full outages caused by nuclear power plant equipment and components failure are particulary emphasized. The trend for unplanned full outages due to the failure of components shows decreasing numerical values in 1981 with respect to the previous years. But this result should be weighed with the increasing plant unavailability hours needed for maintenance and repair action (chiefly preventive maintenance on critical components). This means that the number and downtime of forced outage must be drastically reduced for economic reasons (production losses and problems associated with the unavailable unit unplanned replacement) as well as for plant safe and reliable operation (sudden unavailability of key components and frequency of transients associated with plant shutdown and routine startup operation)

Development of the data logging and graphical presentation for gamma scanning, trouble shooting and process evaluation in the petroleum refinery column

International Nuclear Information System (INIS)

Saengchantr, Dhanaj; Chueinta Siripone

2009-07-01

Full text: Software of data logging and graphical presentation on gamma scanning for trouble shooting and process evaluation of the petroleum refinery column was developed. While setting the gamma source and gamma detector at the opposite orientation along side the column and recording the transmitted radiation through the column at several elevations, the relative density gamma intensity vs. vertical elevation could be obtained in the graphical mode. In comparison with engineering drawing, the physical and process abnormalities could be clearly evaluated during field investigation. The program could also accumulate up to 8 data sets, each of 1,000 points allowing with convenience, the comparison of different operational parameters adjustment during remedy of the problem and/or process optimization. Incorporated with this development and other factors, the technology capability of the TINT Service Center to the petroleum refinery was also enhanced

Oil refinery wastewater treatment using physicochemical, Fenton and Photo-Fenton oxidation processes.

Science.gov (United States)

Tony, Maha A; Purcell, Patrick J; Zhao, Yaqian

2012-01-01

The objective of this study was to investigate the application of advanced oxidation processes (AOPs) to the treatment of wastewaters contaminated with hydrocarbon oil. Three different oil-contaminated wastewaters were examined and compared: (i) a 'real' hydrocarbon wastewater collected from an oil refinery (Conoco-Phillips Whitegate refinery, County Cork, Ireland); (ii) a 'real' hydrocarbon wastewater collected from a car-wash facility located at a petroleum filling station; and (iii) a 'synthetic' hydrocarbon wastewater generated by emulsifying diesel oil and water. The AOPs investigated were Fe(2+)/H(2)O(2) (Fenton's reagent), Fe(2+)/H(2)O(2)/UV (Photo-Fenton's reagent) which may be used as an alternative to, or in conjunction with, conventional treatment techniques. Laboratory-scale batch and continuous-flow experiments were undertaken. The photo-Fenton parametric concentrations to maximize COD removal were optimized: pH = 3, H(2)O(2) = 400 mg/L, and Fe(2+) = 40 mg/L. In the case of the oil-refinery wastewater, photo-Fenton treatment achieved approximately 50% COD removal and, when preceded by physicochemical treatment, the percentage removal increased to approximately 75%.

Towards effective waste management. Knowledge centre Waste Refinery Activity Report 2007-2009; Mot effektivare avfallshantering. Kunskapscentrum Waste Refinery Verksamhetsrapport 2007-2009

Energy Technology Data Exchange (ETDEWEB)

2011-07-01

This report aims to provide a comprehensive picture of the areas that have been discussed and developed during the knowledge centre Waste Refinery first three years. Details and depth analyzes of each area are contained in project reports, which can be downloaded free of charge through our website www.wasterefinery.se

40 CFR 80.410 - What are the additional requirements for gasoline produced at foreign refineries having...

Science.gov (United States)

2010-07-01

... inspections and audits of the foreign refinery. (i) Inspections and audits may be either announced in advance... prohibitions in this section and § 80.385; and (vi) The independent audit requirements under § 80.415... of the refinery at which the gasoline was produced, assurance that the gasoline remained segregated...

Control valves for critical applications in refineries; Stellventile bei kritischen Prozessbedingungen in Raffinerien

Energy Technology Data Exchange (ETDEWEB)

Kiesbauer, J. [Samson AG, Frankfurt am Main (Germany)

2001-09-01

In refineries, the process media flowing through valves are primarily liquids. With liquids, critical operating conditions caused by cavitation or flashing may occur. Symptoms are, for instance, increased noise emission, erosion of valve and pipe components or low-frequency mechanical vibration in the valve and the connected pipeline. Under these conditions, in particular, neglecting details can result in negative influences on the plant performance and the costs of ownership. Unfortunately, it is a common practice nowadays to select control valves in a ''quick and dirty'' fashion, because the phases of planning, bidding and order processing are connected with significant pressures of cost and time. This article presents the basic principles underlying the above problems and shows how to eliminate them based on practical examples from refineries. Moreover, a new throttling element is introduced, which is especially suited to the reduction of noise emission produced by cavitation. This new throttling element is implemented in refineries with increasing success. (orig.) [German] In Raffinerien werden Stellgeraete oft mit Fluessigkeiten durchstroemt. Dadurch koennen sich kritische Betriebszustaende als Folge von Kavitation oder Flashing ergeben. Dies aeussert sich z. B. in erhoehter Schallemission, in Erosion an Ventil- und Rohrleitungsbauteilen oder in niederfrequenten mechanischen Vibrationen im Ventil und der angeschlossenen Rohrleitung. Werden solche Einfluesse nicht von Anfang an richtig erfasst und ernst genommen, dann kann sich dies aeusserst negativ auf die Anlagen- und Prozesszuverlaessigkeit auswirken, verbunden mit deutlich erhoehten ''costs of ownership''. Leider ist es gerade heutzutage ueblich, Stellventile ''quick and dirty'' auszulegen, weil die Phasen der Planung, des Angebots und der Bestellung einem sehr starken Zeit- und Kostendruck unterliegen. Dieser Beitrag stellt die wesentlichen

Health implications of petroleum refinery air emissions: Part I main report : Final : Executive summary

International Nuclear Information System (INIS)

2003-03-01

This report provides a review of recent public health risk assessments performed in the field of petroleum refineries, and epidemiological or community health studies of populations residing close to petroleum refineries. The objective was to identify and access information concerning possible health impacts specific to this industry. The small number of studies performed on the topic as well as shortcomings in study design, concomitant exposure to other industrial sources and somewhat inconsistent findings make the data difficult to interpret. Potential concerns include short-term respiratory effects from exposure to sulphur dioxide and other substances, and cancer risks from benzene and other substances. There was very limited support for these findings in epidemiology studies of populations in the vicinity of petroleum refineries. This review provides additional support concerning cardiac and respiratory effects of air pollution including particulate matter (PM) and ground level ozone

Refinery production planning and scheduling: the refining core business

Directory of Open Access Journals (Sweden)

M. Joly

2012-06-01

Full Text Available Intelligent production planning and scheduling are of paramount importance to ensure refinery profitability, logistic reliability and safety at the local and corporate levels. In Brazil, such activities play a particularly critical role, since the Brazilian downstream model is moving towards a demand-driven model rather than a supply-driven one. Moreover, new and specialized non-linear constraints are continuously being incorporated into these large-scale problems: increases in oil prices implying the need for processing poor quality crudes, increasing demand and new demand patterns for petroleum products, new stringent environmental regulations related to clean fuels and start-up of new production technologies embedded into more complex refining schemes. This paper aims at clarifying the central role of refinery planning and scheduling activities in the Petrobras refining business. Major past and present results are outlined and corporate long-term strategies to deal with present and future challenges are presented.

Refinery Integration of By-Products from Coal-Derived Jet Fuels

Energy Technology Data Exchange (ETDEWEB)

Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2006-05-17

This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses

The prospects for refinery profitability

Energy Technology Data Exchange (ETDEWEB)

Weale, G. [European Energy Services, London (United Kingdom)

1997-05-01

The outlook for the European refining industry is assessed. The conclusion reached is that the industry is struggling for its existence. Over time, an unsatisfactory balance has grown between refinery capacity and market volumes. High exit barriers have prevented capacity being considerably lower than it is. In the future, a typical integrated oil company might be content to confine itself to retailing oil products without having to refine them. Given the reduction in gasoline demand in particular, it can be expected that 20-25% of capacity will be sold off in the next 15 years and much of it will be closed. (Author)

The changing refinery/vendor relationship: One tool for increased competitiveness

International Nuclear Information System (INIS)

Borowski, C.J.; Swett, G.H.

1996-01-01

The historic relationship between many petroleum refineries and vendors was adversarial. However, during the past 10 years, many industrial firms have found that working together with vendors is critical to reducing costs and improving quality--the two key elements required to maintain a competitive position. As refiners have begun working with their vendors more like partners, numerous benefits have accrued to the refining industry. This paper analyzes how the refiner-vendor relationship has changed. Specifically, the authors address the following issues: the competitive threat that has forced a different approach to contracting services and goods; how right-sizing and capacity creep have contributed to the need to re-examine historic practices; key elements in a successful refinery/vendor relationship; how does it work in real life; and implementing a partnering program

Simulation of Concentrations and Dispersion of Hydrogen Sulfide (H2S Due to Incinerators of Sulfur Recovery Units in a Gas Refinery in Asaluyeh

Directory of Open Access Journals (Sweden)

Azam Minabi

2017-09-01

Conclusion: The results of this study showed that the variations of measured concentrations were consistent with those of simulated ones. Meanwhile, the contribution of neighbor industries was determined. Comparision of 8-h H2S concentrations with OSHA and NIOSH standard limits indicated that there was no significant health risk in this refinery.

A strategic review of the petroleum refinery industry sector

International Nuclear Information System (INIS)

1999-10-01

The report studies the environmental performance of the U.K. petroleum refinery industry sector with reference to world-wide best practice and describes the five most practical strategic options for emission reduction in the context of projected technology, cost, demand, capacity and legislation. (author)

Atmospheric BTEX concentrations in the vicinity of the crude oil refinery of the Baltic region.

Science.gov (United States)

Baltrėnas, Pranas; Baltrėnaitė, Edita; Serevičienė, Vaida; Pereira, Paulo

2011-11-01

Among chemical industries, petroleum refineries have been identified as large emitters of a wide variety of pollutants. Benzene, toluene, ethylbenzene, and xylene (BTEX) form an important group of aromatic volatile organic compounds (VOCs) because of their role in the troposphere chemistry and the risk posed to human health. A very large crude oil refinery of the Baltic States (200,000 bbl/day) is situated in the northern, rural part of Lithuania, 10 km from the town of Mažeikiai (Lithuania). The objectives of this study were: (1) to determine of atmospheric levels of BTEX in the region rural and urban parts at the vicinity of the crude oil refinery; and (2) to investigate the effect of meteorological parameters (wind speed, wind direction, temperature, pressure, humidity) on the concentrations measured. The averaged concentration of benzene varied from 2.12 ppbv in the rural areas to 2.75 ppbv in the urban areas where the traffic was determined to be a dominant source of BTEX emissions. Our study showed that concentration of benzene, as strictly regulated air pollutant by EU Directive 2008/50/EC, did not exceed the limit of 5 ppbv in the region in the vicinity of the crude oil refinery during the investigated period. No significant change in air quality in the vicinity of the oil refinery was discovered, however, an impact of the industry on the background air quality was detected. The T/B ratio (0.50-0.81) that was much lower than 2.0, identified other sources of pollution than traffic.

Development of optimum conditions for modification of Kpautagi clay for application in petroleum refinery wastewater treatment

Directory of Open Access Journals (Sweden)

Matthew A. ONU

2015-12-01

Full Text Available Kautagi clay is a kaolin type deposit that is abundantly available in Niger State, Nigeria with potential for application in pollution control such as wastewater treatment. This study investigates the optimum conditions for modification of Kpautagi clay for application in refinery wastewater treatment. Sulphuric acid was used in the modification of the clay and the modification variables considered were acid concentration, activation time and temperature. To develop the optimum conditions for the modification variables, the sulphuric acid modified Kpautagi clay was applied in the treatment of refinery wastewater in column mode at a fixed flow rate and mass of adsorbent. The results obtained indicate that the optimum conditions for modification of Kpautagi clay for application in the treatment of petroleum refinery wastewater are: acid concentration of 4M; activation time of 120min and activation temperature of 100°C. Therefore, the optimum conditions developed in this study for modification of Kpautagi clay could be applied for improved performance in the treatment of petroleum refinery wastewater.

Toxicity identification evaluation methods for identification of toxicants in refinery effluents

International Nuclear Information System (INIS)

Barten, K.A.; Mount, D.R.; Hackett, J.R.

1993-01-01

During the last five years, the authors have used Toxicity Identification Evaluation (TIE) methods to characterize and identify the source(s) of toxicity in effluents from dozens of municipal and industrial facilities. In most cases, specific chemicals responsible for toxicity have been identified. Although generally successful, the initial experience was that for several refinery effluents, they were able only to qualitatively characterize the presence of organic toxicants; standard toxicant identification procedures were not able to isolate specific organic chemicals. They believe that organic toxicity in these refinery effluents is caused by multiple organic compounds rather than by just a few; evidence for this includes an inability to isolate toxicity in a small number of fractions using liquid chromatography and the presence of very large numbers of compounds in isolated fractions. There is also evidence that the toxicant(s) may be ionic, in that the toxicity of whole effluent and isolated fractions often show increasing toxicity with decreasing pH. Finally, positive-pressure filtration has also reduced toxicity in some samples. In this presentation the authors summarize their experiences with refinery effluents, focusing on typical patterns they have observed and alternative procedures they have used to better understand the nature of these toxicants

Basic investigation on promotion of joint implementation in fiscal 2000. Survey on energy saving and CO2 emission reduction in Cilacap Refinery; 2000 nendo kyodo jisshi nado suishin kiso chosa hokokusho. Cilacap seiyusho ni okeru shoene CO2 sakugen chosa

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

With an objective of saving energy and reducing greenhouse gas emission, a basic survey has been performed on the atmospheric crude oil distillation units and the high vacuum distillation units at Cilacap Refinery in Indonesia. The first site survey in September 2000 has carried out a survey on the situation of the facilities and operation upon obtaining the facility data and operation information from Pertamina. As a result, it was revealed that there is a room of improvement in the heat recovery, whereas a modification design was executed on the improvement proposals on the heat exchanger system. However, the second site survey in November 2000 has revealed that Pertamina had executed in 1998 through 1999 the de-bottlenecking project on the crude oil atmospheric distillation units (two units) and the high vacuum distillation units (two units), by which the capability has been expanded, and the heat recovery rate has been increased. It is not possible to look for extremely large enhancement of the heat recovery rate beyond that point, and the reduction of CO2 emission would also be small. As a result of discussions, the present project was found capable of reducing annually the CO2 emission by 36,500 tons. (NEDO)

Current status of vegetation of six PETROBRAS refineries; Status dos fragmentos de vegetacao em seis refinarias da PETROBRAS

Energy Technology Data Exchange (ETDEWEB)

Basbaum, Marcos Andre; Bonafini, Fabio Loureiro; Porciano, Patricia Pereira [SEEBLA, Servicos de Engenharia Emilio Baumgart Ltda., Rio de Janeiro, RJ (Brazil); Torggler, Bianca Felippe; Fernandes, Renato [PETROBRAS, Rio de Janeiro, RJ (Brazil). Engenharia; Vieira, Elisa Diniz Reis [PETROBRAS, Rio de Janeiro, RJ (Brazil)

2008-07-01

Most of refineries from PETROBRAS have significant vegetation areas within their limits. The purpose of this study was to develop a preliminary assessment study of the vegetation fragments on six refineries, including the quantification of permanent preservation areas (Brazilian environmental law requirement). Besides that, the authors propose potential recovery areas and some reforestation techniques. The methodology was based on Rapid Ecological Assessment, that consists on the selection of target areas by image analysis (satellite or aerial photos) and expedite fieldwork - three days on each refinery. The main features of vegetation, like phytophysiognomy and successional stage were obtained, and registered on a specific form developed to be used at fieldwork. The results achieved show that 44,7% of the areas from these six refineries were occupied by vegetation. The most representative categories of vegetation were Atlantic forest fragments and mangroves, as well as to permanent preservation areas. (author)

Analysis of Petroleum Downstream Industry Potential in Riau Province

Directory of Open Access Journals (Sweden)

Tomi Erfando

2017-06-01

Full Text Available Petroleum downstream industry in Riau Province is still not optimal. The data shows that from 98,892,755 barrels lifting oil each year only 62,050,000 barrels could be processed in refinery unit II Dumai operated by PT Pertamina. There is a potential of 35-40% of downstream industry. Indonesian Government through The Ministry of Energy and Mineral Resources declared the construction of a mini refinery to boost oil processing output in the downstream sector. A feasibility study of development plan mini refinery is needed. The study includes production capacity analysis, product analysis, development & operational refinery  analysis and economic analysis. The results obtained by the mini refinery capacity is planned to process crude oil 6000 BOPD with the products produced are gasoline, kerosene, diesel and oil. Investment cost consist of is capital cost US $ 104419784 and operating cost US $ 13766734 each year with net profit earned US $ 12330063/year and rate of return from investment 11.63%

Test plan, the Czechowice Oil Refinery bioremediation demonstration of a process waste lagoon. Revision 1

International Nuclear Information System (INIS)

Altman, D.J.; Hazen, T.C.; Tien, A.J.

1997-01-01

The overall objective of the bioremediation project is to provide a cost effective bioremediation demonstration of petroleum contaminated soil at the Czechowice Oil Refinery. Additional objectives include training of personnel, and transfer of this technology by example to Poland, and the Risk Abatement Center for Central and Eastern Europe (RACE). The goal of the remediation is to reduce the risk of PAH compounds in soil and provide a green zone (grassy area) adjacent to the site boundary. Initial project discussions with the Czechowice Oil Refinery resulted in helping the refinery find an immediate cost effective solution for the dense organic sludge in the lagoons. They found that when mixed with other waste materials, the sludge could be sold as a fuel source to local cement kilns. Thus the waste was incinerated and provided a revenue stream for the refinery to cleanup the lagoon. This allowed the bioremediation project to focus on remediation of contaminated soil that unusable as fuel, less recalcitrant and easier to handle and remediate. The assessment identified 19 compounds at the refinery that represented significant risk and would require remediation. These compounds consisted of metals, PAH's, and BTEX. The contaminated soil to be remediated in the bioremediation demonstration contains only PAH (BTEX and metals are not significantly above background concentrations). The final biopile design consists of (1) dewatering and clearing lagoon A to clean clay, (2) adding a 20 cm layer of dolomite with pipes for drainage, leachate collection, air injection, and pH adjustment, (3) adding a 1.1 m layer of contaminated soil mixed with wood chips to improve permeability, and (4) completing the surface with 20 cm of top soil planted with grass

Biota of the 300-FF-1 operable unit. [Westinghouse Hanford Company

Energy Technology Data Exchange (ETDEWEB)

Rickard, W.H. Jr.; Fitzner, R.E.; Brandt, C.A.

1990-10-01

This report summarizes Task 5a-2 of the Phase I Remedial Investigation -- Operable Unit Characterization of the 300-FF-1 Operable Unit on the Hanford Site, near Richland, Washington. The ultimate goal of Phase I is to determine the nature and extent of the threat to public health and the environment from releases of hazardous substances from the operable unit. The purpose of Task 5a-2 was to determine what species inhabit the 300-FF-1 Operable Unit and how they use the unit. The focus is on those species listed as endangered or threatened, those that are economically important, or those that constitute significant components of the human food chain. 39 refs., 5 figs., 5 tabs.

Treatability studies on different refinery wastewater samples using high-throughput microbial electrolysis cells (MECs)

KAUST Repository

Ren, Lijiao; Siegert, Michael; Ivanov, Ivan; Pisciotta, John M.; Logan, Bruce E.

2013-01-01

High-throughput microbial electrolysis cells (MECs) were used to perform treatability studies on many different refinery wastewater samples all having appreciably different characteristics, which resulted in large differences in current generation. A de-oiled refinery wastewater sample from one site (DOW1) produced the best results, with 2.1±0.2A/m2 (maximum current density), 79% chemical oxygen demand removal, and 82% headspace biological oxygen demand removal. These results were similar to those obtained using domestic wastewater. Two other de-oiled refinery wastewater samples also showed good performance, with a de-oiled oily sewer sample producing less current. A stabilization lagoon sample and a stripped sour wastewater sample failed to produce appreciable current. Electricity production, organics removal, and startup time were improved when the anode was first acclimated to domestic wastewater. These results show mini-MECs are an effective method for evaluating treatability of different wastewaters. © 2013 Elsevier Ltd.

Emergency Response Program Designing Based On Case Study ERP Regulations In Ilam Gas Refinery

Directory of Open Access Journals (Sweden)

Mehdi Tahmasbi

2015-08-01

Full Text Available The study of Emergency response plan designing is one of the most important prevention approaches in crisis management. This study aims to design emergency response plan based on case study ERP regulations in Ilam gas refinery. On the basis of risk assessment and identification techniques such as HAZOP and FMEA in Ilam gas refinery the risks have been prioritized and then according to this prioritization the design of possible scenarios which have the highest rate of occurrence and the highest level of damage has been separated. Possible scenarios were simulated with PHAST software. Then emergency response program has been designed for the special mode or similar cases. According to the internal emergency response plan for Ilam gas refinery and predictable conditions of the process special instructions should be considered at the time of the incident to suffer the least damage on people and environment in the shortest time possible.

Treatability studies on different refinery wastewater samples using high-throughput microbial electrolysis cells (MECs)

KAUST Repository

Ren, Lijiao

2013-05-01

High-throughput microbial electrolysis cells (MECs) were used to perform treatability studies on many different refinery wastewater samples all having appreciably different characteristics, which resulted in large differences in current generation. A de-oiled refinery wastewater sample from one site (DOW1) produced the best results, with 2.1±0.2A/m2 (maximum current density), 79% chemical oxygen demand removal, and 82% headspace biological oxygen demand removal. These results were similar to those obtained using domestic wastewater. Two other de-oiled refinery wastewater samples also showed good performance, with a de-oiled oily sewer sample producing less current. A stabilization lagoon sample and a stripped sour wastewater sample failed to produce appreciable current. Electricity production, organics removal, and startup time were improved when the anode was first acclimated to domestic wastewater. These results show mini-MECs are an effective method for evaluating treatability of different wastewaters. © 2013 Elsevier Ltd.

Treatment of petroleum refinery sourwater by advanced oxidation processes

International Nuclear Information System (INIS)

Coelho, Alessandra; Castro, Antonio V.; Dezotti, Marcia; Sant'Anna, G.L.

2006-01-01

The performance of several oxidation processes to remove organic pollutants from sourwater was investigated. Sourwater is a specific stream of petroleum refineries, which contains slowly biodegradable compounds and toxic substances that impair the industrial biological wastewater treatment system. Preliminary experiments were conducted, using the following processes: H 2 O 2 , H 2 O 2 /UV, UV, photocatalysis, ozonation, Fenton and photo-Fenton. All processes, except Fenton and photo-Fenton, did not lead to satisfactory results, reducing at most 35% of the sourwater dissolved organic carbon (DOC). Thus, further experiments were performed with these two techniques to evaluate process conditions and organic matter removal kinetics. Batch experiments revealed that the Fenton reaction is very fast and reaches, in a few minutes, an ultimate DOC removal of 13-27%, due to the formation of iron complexes. Radiation for an additional period of 60 min can increase DOC removal up to 87%. Experiments were also conducted in a continuous mode, operating one 0.4 L Fenton stirred reactor and one 1.6 L photo-Fenton reactor in series. DOC removals above 75% were reached, when the reaction system was operated with hydraulic retention times (HRT) higher than 85 min. An empirical mathematical model was proposed to represent the DOC removal kinetics, allowing predicting process performance quite satisfactorily

Nuclear refinery - advanced energy complex for electricity generation, clean fuel production, and heat supply

International Nuclear Information System (INIS)

McDonald, C.F.

1992-01-01

In planning for increased U.S. energy users' demand after the year 2000 there are essentially four salient vectors: (1) reduced reliance on imported crude oil; (2) provide a secure supply with stable economics; (3) supply system must be in concert with improved environment goals; and (4) maximum use to be made of indigenous resources. For the last decade of this century the aforementioned will likely be met by increasing utilization of natural gas. Early in the next century, however, in the U.S. and the newly industrializing nations, the ever increasing energy demand will only be met by the combined use of uranium and coal. The proposed nuclear refinery concept is an advanced energy complex that has at its focal point an advanced modular helium reactor (MHR). This nuclear facility, together with a coal feedstock, could contribute towards meeting the needs of the four major energy sectors in the U.S., namely electricity, transportation, industrial heating and chemical feedstock, and space and water heating. Such a nuclear/coal synergistic system would be in concert with improved air quality goals. This paper discusses the major features and multifaceted operation of a nuclear refinery concept, and identifies the enabling technologies needed for such an energy complex to become a reality early in the 21st century. (Author)

A METHODOLOGY BASED ON AN ECOLOGICAL ECONOMY APPROACH FOR THE INTEGRATING MANAGEMENT OF THE SULPHUROUS WATER IN AN OIL REFINERY

Directory of Open Access Journals (Sweden)

Gabriel Orlando Lobelles Sardiñas

2016-10-01

Full Text Available Despite the current highly stringent international standards regulating the contaminating emissions to the environment, the Oil refinery of Cienfuegos is still generating liquid and gaseous emissions contaminating the environment. The construction of new units as part of the Refinery expansion leads to an increase of these emissions due to the lack of technologies for the reutilization of the sulphurous water. The objective of this paper is to propose a methodology for the integral management of the sulphurous residual water in the oil refining process, including the evaluation and selection of the most feasible technological variant to minimize the sulphur contamination of water and the resulting emissions during the process. The methodology is based on the ecological economy tools, allowing a comprehensible evaluation of six technological variants at the refinery of Cienfuegos. The Life Cycle Assessment was applied (ACV by its Spanish acronym, by means of the software SimaPro 7.1. It was evaluated through the Eco Speed Method, to minimize the possible uncertainty. An economic evaluation was performed, taking into account the external costs for a more comprehensive analysis, enabling, along with the ecological indicators, the selection of the best technological variant, achieving a methodology based on a comprehensive evaluation, and as a positive impact, the implementation of the chosen variant (V5, 98.27% of the process water was recovered, as well as the sulphur that recovered from 94 to 99.8 %, reducing the emissions from 12 200 to 120 mg/Nm3 as SO2.

Feasibility study report for the 200-BP-1 operable unit

Energy Technology Data Exchange (ETDEWEB)

1993-06-01

This feasibility study examines a range of alternatives and provides recommendations for selecting a preferred alternative for remediating contamination at the 200-BP-1 operable unit. The 200-BP-1 operable unit is located in the center of the Hanford Site along the northern boundary of the 200 East Area. The 241-BY Tank Farm is located immediately to the south of the operable unit. 200-BP-1 is a source operable unit with contaminated soils associated primarily with nine inactive cribs (known as the 216-B cribs). These cribs were used for disposal of low-level radioactive liquid waste from U Plant uranium recovery operations, and waste storage tank condensate from the adjacent 241-BY Tank Farm. The cribs used for disposal of U Plant waste were in operation from 1955--1965, and the cribs used for disposal of tank condensate were in operation from 1965--1975. In addition to the cribs, four unplanned releases of radioactive materials have occurred within the operable unit. Contaminated surface soils associated with the unplanned releases have been consolidated over the cribs and covered with clean soil to reduce contaminant migration and exposure. Discharge of wastes to the cribs has resulted in soil and groundwater contamination. The groundwater is being addressed as part of the 200 East Aggregate Area, groundwater operable unit. Contaminated soils at the site can be categorized by the types of contaminants, their distribution in the soil column, and the risk posed by the various potential exposure pathways. Below the clean soil cover, the near surface soils contain low-levels of contamination with cesium-137, radium-226, strontium-90, thorium-228, and uranium. The lifetime incremental cancer risk associated with these soils if they were exposed at the surface is 9{times}10{sup {minus}5}.

Feasibility study report for the 200-BP-1 operable unit

International Nuclear Information System (INIS)

1993-06-01

This feasibility study examines a range of alternatives and provides recommendations for selecting a preferred alternative for remediating contamination at the 200-BP-1 operable unit. The 200-BP-1 operable unit is located in the center of the Hanford Site along the northern boundary of the 200 East Area. The 241-BY Tank Farm is located immediately to the south of the operable unit. 200-BP-1 is a source operable unit with contaminated soils associated primarily with nine inactive cribs (known as the 216-B cribs). These cribs were used for disposal of low-level radioactive liquid waste from U Plant uranium recovery operations, and waste storage tank condensate from the adjacent 241-BY Tank Farm. The cribs used for disposal of U Plant waste were in operation from 1955--1965, and the cribs used for disposal of tank condensate were in operation from 1965--1975. In addition to the cribs, four unplanned releases of radioactive materials have occurred within the operable unit. Contaminated surface soils associated with the unplanned releases have been consolidated over the cribs and covered with clean soil to reduce contaminant migration and exposure. Discharge of wastes to the cribs has resulted in soil and groundwater contamination. The groundwater is being addressed as part of the 200 East Aggregate Area, groundwater operable unit. Contaminated soils at the site can be categorized by the types of contaminants, their distribution in the soil column, and the risk posed by the various potential exposure pathways. Below the clean soil cover, the near surface soils contain low-levels of contamination with cesium-137, radium-226, strontium-90, thorium-228, and uranium. The lifetime incremental cancer risk associated with these soils if they were exposed at the surface is 9x10 -5

Feasibility study report for the 200-BP-1 operable unit

International Nuclear Information System (INIS)

1994-01-01

This feasibility study (FS) examines a range of alternatives and provides recommendations for selecting a preferred altemative for remediating contamination at the 200-BP-1 operable unit. The 200-BP-1 operable unit is located in the center of the Hanford Site along the northern boundary of the 200 East Area. The 241-BY Tank Farm is located immediately to the south of the operable unit. 200-BP-1 is a source operable unit with contaminated soils associated primarily with nine inactive cribs (known as the 216-B cribs). These cribs were used for disposal of low-level radioactive liquid waste from U Plant uranium recovery operations, and waste storage tank condensate from the adjacent 241-BY Tank Farm. The cribs used for disposal of U Plant waste were in operation from 1955--1965, and the cribs used for disposal of tank condensate were in operation from 1965-1975. In addition to the cribs, four unplanned releases of radioactive materials have occurred within the operable unit. Contaminated surface soils associated with the unplanned releases have been consolidated over the cribs and covered with clean soil to reduce contaminant migration and exposure. Discharge of wastes to the cribs has resulted in soil and groundwater contamination. The groundwater is being addressed as part of the 200 East Aggregate Area groundwater operable unit. Contaminated soils at the site can be categorized by the types of contaminants, their distribution in the soil column, and the risk posed by the various potential exposure pathways. Below the clean soil cover, the near surface soils contain low-:levels of contamination with cesium-137, radium-226, strontium-90, thorium-228 and uranium. The lifetime incremental cancer risk associated with these soils if they were exposed at the surface is 9 x 10 5

Litvinov splits into units, Sokolov gets state guarantees

International Nuclear Information System (INIS)

Alperowicz, N.

1993-01-01

Chemopetrol Litvinov, the largest chemical producer in the Czech Republic, has split its operation into four divisions in a move designed to make the process of privatization easier. Four key production divisions-refinery, petrochemicals, agro, and phenols-will function as independant legal entities. The petrochemical division includes the 450,000-m.t./year steam cracker, plastics production units, ethanol ethylbenzene, and oxo alcohols. Units producing ammonia, urea, carbon dioxide, and carbon black are in the division. Sources at Litvinov say a modified proposal to buy the company's refining operations has been received form a consortium composed of Agip, Conoco, and Total. The parties are discussing issues such as prices of intermediates and investment programs. Although Western partners have not shown interest in the steam cracker, Amoco is looking at the possibility of buying a stake in the polypropylene plant; Neste is considering a stake in polyethylene; and PCD is looking at a stake in both plastics, on a minority basis initially but with options to extend. The potential partners propose to expand capacity in line with market developments. Litinov is considering transferring the cracker into the refining division

Determination of levels nd interfaces in oil refinery fractioning towers, with neutron retrodispersion

International Nuclear Information System (INIS)

Diaz, F; Henriquez, P; Vega, P

2003-01-01

In the petrochemical industry and, especially, in oil refineries measurement and the control of levels and interfaces in tanks, fractioning towers and processing equipment, in general, are extremely important for managing and knowing about the different fluids that are processed in the plants. Usually there is on-line instrumentation at the plant's critical points, like floaters, external glass columns and, even, gamma radiation sources through the transmission system. A problem arises with the need for a system that can rapidly and non destructively measure levels and interfaces, outside the system to be inspected and verify the functioning of the on-line instrumentation and in places where there is no instrumentation. This work presents a methodology based on the retrodispersion of neutrons that have been used in 3 breakdown towers at the Petrox Oil Refinery, Region VIII in Chile, to identify levels and interfaces in different points in order to verify the functioning of a gamma level meter, glass column meters and to observe on site and in real time the variations in level and interfaces when carrying out different operations that will modify the values in the towers. The set of instruments used include a 1010 GBq Americium-Beryllium source and a measuring system consisting of a BF 3 (boron trifluoride) detector and its electronically related Model 2241 from Ludlum Instruments. The set is placed in a geometry that permits precise measurements (Cw)

Bio-Refineries Bioprocess Technologies for Waste-Water Treatment, Energy and Product Valorization

Science.gov (United States)

Keith Cowan, A.

2010-04-01

Increasing pressure is being exerted on communities and nations to source energy from forms other than fossil fuels. Also, potable water is becoming a scarce resource in many parts of the world, and there remains a large divide in the demand and utilization of plant products derived from genetically modified organisms (GMOs) and non-GMOs. The most extensive user and manager of terrestrial ecosystems is agriculture which is also the de facto steward of natural resources. As stated by Miller (2008) no other industry or institution comes close to the comparative advantage held for this vital responsibility while simultaneously providing food, fiber, and other biology-based products, including energy. Since modern commercial agriculture is transitioning from the production of bulk commodities to the provision of standardized products and specific-attribute raw materials for differentiated markets, we can argue that processes such as mass cultivation of microalgae and the concept of bio-refineries be seen as part of a `new' agronomy. EBRU is currently exploring the integration of bioprocess technologies using microalgae as biocatalysts to achieve waste-water treatment, water polishing and endocrine disruptor (EDC) removal, sustainable energy production, and exploitation of the resultant biomass in agriculture as foliar fertilizer and seed coatings, and for commercial extraction of bulk commodities such as bio-oils and lecithin. This presentation will address efforts to establish a fully operational solar-driven microalgae bio-refinery for use not only in waste remediation but to transform waste and biomass to energy, fuels, and other useful materials (valorisation), with particular focus on environmental quality and sustainability goals.

Report on basic survey project for promoting joint implementation in 1999. Feasibility study on energy conservation and reduction of CO2 emission at Balikpapan Refinery

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

With an objective of implementation as the clean development mechanism (CDM), a survey was performed on energy conservation and CO2 reduction at Balikpapan Refinery in Indonesia with respect to reducing emission of greenhouse effect gases. A crude oil atmospheric distillation unit with a capacity of 200,000 BPSD, and a vacuum distillation unit with a capacity of 81,000 BPSD are in operation, which emit carbon dioxide of about 470,000 tons annually from fuels burned and consumed by these units. The result of the survey revealed that there is a room for improvement in heat recovery, and that these units are separated into two groups located far away with each other in distance, resulting in low thermal efficiency and wastes in fuel. Increase in heat recovery should be achieved, and fuel consumption in the heating furnace should be reduced. Energy saving technologies owned by JGC were applied to establish a modification plan. The plan calls for maximum annual reduction of carbon dioxide of about 61,000 tons at a reduction rate of 13%, and maximum annual fuel conservation of 190 times 10{sup 9} kcal at a saving rate of 13%. PERTAMINA also desires the realization thereof if technical and financial assistance is made available. The project has a significance that it would give a great impetus to the entire regions and industries. (NEDO)

Environmental impact of illegal refineries on the vegetation of the ...

African Journals Online (AJOL)

... aesthetic scenery of the forest, regeneration of plant species and destruction of wildlife habitat, disruption of water cycle and loss of medicinal plant species. Youth empowerment, through vocational training and environmental education can ameliorate the situation. Keywords: Environmental degradation, Illegal Refineries, ...

Particulate matters modelling: Participation to Eurodelta and application at a refinery

International Nuclear Information System (INIS)

Raffort, Valentin

2017-01-01

the month of April 2013, in the vicinity of the Total refinery of Grandpuits, Seine-et-Marne. Model performance is evaluated at the regional scale, with the refinery sources treated with the Plume-in-Grid representation. The refinery contribution to local inhalable particle concentrations, in interaction with local sources, is analyzed. Next, the model is applied to two measurement campaigns of the TEMMAS project ('Tele-detection, Measure, Modeling of Atmospheric pollutants on industrial sites'), conducted in the vicinity of the Total refinery at La Mede, Bouches-du-Rhone, in September 2015 and February 2016. The performance of the Polyphemus Plume-in-Grid model is evaluated with intensive measurements of mass concentrations, number concentrations, and chemical composition of particles in the vicinity of the refinery. (author) [fr

Test plan, the Czechowice Oil Refinery bioremediation demonstration of a process waste lagoon. Revision 1

Energy Technology Data Exchange (ETDEWEB)

Altman, D.J.; Hazen, T.C.; Tien, A.J. [Westinghouse Savannah River Co., Aiken, SC (United States). Savannah River Technology Center; Worsztynowicz, A.; Ulfig, K. [Inst. for Ecology of Industrial Areas, Katowice (Poland)

1997-05-10

The overall objective of the bioremediation project is to provide a cost effective bioremediation demonstration of petroleum contaminated soil at the Czechowice Oil Refinery. Additional objectives include training of personnel, and transfer of this technology by example to Poland, and the Risk Abatement Center for Central and Eastern Europe (RACE). The goal of the remediation is to reduce the risk of PAH compounds in soil and provide a green zone (grassy area) adjacent to the site boundary. Initial project discussions with the Czechowice Oil Refinery resulted in helping the refinery find an immediate cost effective solution for the dense organic sludge in the lagoons. They found that when mixed with other waste materials, the sludge could be sold as a fuel source to local cement kilns. Thus the waste was incinerated and provided a revenue stream for the refinery to cleanup the lagoon. This allowed the bioremediation project to focus on remediation of contaminated soil that unusable as fuel, less recalcitrant and easier to handle and remediate. The assessment identified 19 compounds at the refinery that represented significant risk and would require remediation. These compounds consisted of metals, PAH`s, and BTEX. The contaminated soil to be remediated in the bioremediation demonstration contains only PAH (BTEX and metals are not significantly above background concentrations). The final biopile design consists of (1) dewatering and clearing lagoon A to clean clay, (2) adding a 20 cm layer of dolomite with pipes for drainage, leachate collection, air injection, and pH adjustment, (3) adding a 1.1 m layer of contaminated soil mixed with wood chips to improve permeability, and (4) completing the surface with 20 cm of top soil planted with grass.

40 CFR Table 11 to Subpart Uuu of... - Requirements for Performance Tests for Organic HAP Emissions From Catalytic Cracking Units Not...

Science.gov (United States)

2010-07-01

... Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63, Subpt. UUU... Organic HAP Emissions From Catalytic Cracking Units Not Subject to New Source Performance Standard (NSPS... From Catalytic Cracking Units Not Subject to New Source Performance Standard (NSPS) for Carbon Monoxide...

Study theorizes use of geothermal sources for energy in refineries

NARCIS (Netherlands)

Golombok, M.; Beintema, K.

2008-01-01

Geothermal sources for direct heating can theoretically serve as an alternative source of high-temperature heat in processing plants. Cutting CO2 emissions from a refinery requires reducing the amount of fuel burned. Heat obtained from geothermal energy is more efficiently used for directly powering

The importance of new delayed coking units in he fuel market; A importancia das novas unidade de coqueamento retardado no mercado de combustiveis

Energy Technology Data Exchange (ETDEWEB)

Moreira, Fabricia S. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Programa de Recursos Humanos 13; Seidl, Peter R.; Guimaraes, Maria Jose O.C. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil)

2008-07-01

The increase in production of heavier oils and the recent changes in the demand for petroleum derivatives requires modifications in refining schemes of Brazilian refineries, which were originally projected for processing light oils and production of mainly gasoline by fluid catalytic cracking units. This is necessary because forecasts indicate a larger increase in demand for diesel oil instead of gasoline. These same forecasts reveal an expressive reduction in the demand for fuel oil, which still is produced in large amounts in Brazilian refineries due to the quality of the oils from local fields that are processed. The current challenge for the local oil industry is to adapt the present refineries to produce more valuable derivatives from heavy oils. For this purpose, PETROBRAS is investing in the construction of conversion units with technology for processing heavier feeds, especially in the Delayed Coking process. This work has as an objective to identify the importance of the delayed coke units in the current scenario of the oil industry, highlighting the main investments in construction of new units and evaluating the impact of the existing units on the market for petroleum derivatives. (author)

Oil-refinery and automotive emissions of rare earth elements

International Nuclear Information System (INIS)

Kitto, M.E.; Gordon, G.E.; Anderson, D.L.; Olmez, I.

1991-01-01

The concentration pattern of rare-earth elements (REEs) in emissions from oil refineries and newer-model automobiles shows a distortion from the crustal abundance pattern. The REEs arise from the zeolite cracking catalysts used in petroleum refining and emission-control substrates used in automobile catalytic converters, respectively. Ten petroleum cracking catalysts from four countries and 12 catalytic converters from five automobile manufacturers were characterized for their REE content. The cracking catalysts are highly enriched in light REEs, whereas the automobile catalysts are enriched primarily in Ce. Incorporation of zeolite catalysts into refined oil provides new atmospheric elemental signatures for tracing emissions from refineries and oil-fired power plants on a regional scale. Though both have enhanced La/REE ratios, emissions from these two sources can be distinguished by their La/V ratios. Although REE demand by the petroleum industry has dropped considerably in recent years, automobile catalytic converters containing REEs are expected to increase dramatically as more stringent emission regulations are adopted in Europe, Japan and the US

Process-optimization in Europe's largest refinery; Prozessoptimierung in Europas groesster Raffinerie

Energy Technology Data Exchange (ETDEWEB)

Herbstritt, M. [AUMA Riester GmbH und Co. KG, Muellheim (Germany)

2007-06-15

More than 1000 valves are to be replaced, with new actuator systems, in the context of the PROMS (''Profitable Oil Movement Systems'') project at the Nerefco refinery in Rotterdam. The requirements for this project include redundant data transmission, facilities for scanning of all actuator parameters and states from the control room, and the ability to record torque curves for the valves, in order to permit deductions concerning valve condition. Explosion-safety and high resistance to corrosion are, of course, basic preconditions. Finally, conversion to the new valve and actuator systems is to be accomplished without interruption to plant operation. A single manufacturer, who thus simultaneously plays the role of a system integrator, has been able to meet all these demands. (orig.)

Biological treatment of refinery spent caustics under halo-alkaline conditions.

Science.gov (United States)

de Graaff, Marco; Bijmans, Martijn F M; Abbas, Ben; Euverink, Gert-J W; Muyzer, Gerard; Janssen, Albert J H

2011-08-01

The present research demonstrates the biological treatment of refinery sulfidic spent caustics in a continuously fed system under halo-alkaline conditions (i.e. pH 9.5; Na(+)= 0.8M). Experiments were performed in identical gas-lift bioreactors operated under aerobic conditions (80-90% saturation) at 35°C. Sulfide loading rates up to 27 mmol L(-1)day(-1) were successfully applied at a HRT of 3.5 days. Sulfide was completely converted into sulfate by the haloalkaliphilic sulfide-oxidizing bacteria belonging to the genus Thioalkalivibrio. Influent benzene concentrations ranged from 100 to 600 μM. At steady state, benzene was removed by 93% due to high stripping efficiencies and biodegradation. Microbial community analysis revealed the presence of haloalkaliphilic heterotrophic bacteria belonging to the genera Marinobacter, Halomonas and Idiomarina which might have been involved in the observed benzene removal. The work shows the potential of halo-alkaliphilic bacteria in mitigating environmental problems caused by alkaline waste. Copyright © 2011 Elsevier Ltd. All rights reserved.

Estimation and reduction of CO2 emissions from crude oil distillation units

International Nuclear Information System (INIS)

Gadalla, M.; Olujic, Z.; Jobson, M.; Smith, R.

2006-01-01

Distillation systems are energy-intensive processes, and consequently contribute significantly to the greenhouse gases emissions (e.g. carbon dioxide (CO 2 ). A simple model for the estimation of CO 2 emissions associated with operation of heat-integrated distillation systems as encountered in refineries is introduced. In conjunction with a shortcut distillation model, this model has been used to optimize the process conditions of an existing crude oil atmospheric tower unit aiming at minimization of CO 2 emissions. Simulation results indicate that the total CO 2 emissions of the existing crude oil unit can be cut down by 22%, just by changing the process conditions accordingly, and that the gain in this respect can be doubled by integrating a gas turbine. In addition, emissions reduction is accompanied by substantial profit increase due to utility saving and/or export

Assessment of the effect of effluent discharge from coffee refineries ...

African Journals Online (AJOL)

The ecohydrological quality of water resource of Ethiopia is declining at an alarming rate, resulting in severe environmental degradation. This study finds out the effects of effluent discharge from intensive coffee refineries on river water quality based on physicochemical parameters and benthos assemblages as biological ...

Integrated refinery waste management

Energy Technology Data Exchange (ETDEWEB)

Shieh, Y -S [ETG Environmental, Inc., Blue Bell, PA (US); Sheehan, W J [Separation and Recovery Systems, Inc., Irvine, CA (US)

1992-01-01

In response to the RCRA land ban regulations and TC rule promulgated by the U.S. Federal Environmental Protection Agency (EPA) in 1988-1990, an Integrated Refinery Waste Management (IRWM) program has been developed to provide cost-effective solutions to petroleum industry customers. The goal of IRWM is to provide technology based remediation treatment services to manage sludges and wastewaters generated from the oil refining processes, soils contaminated with petroleum distillates and groundwater contaminated with fuels. Resource recovery, volume reduction and waste minimization are the primary choices to mitigate environmental problems. Oil recovery has been performed through phase separation (such as centrifugation and filtration) and heating of heavy oils. Volume reduction is achieved by dewatering systems such as centrifuges and filter presses, and low temperature thermal treatment. Waste minimization can be accomplished by bioremediation and resource recovery through a cement kiln. (Author).

REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

Energy Technology Data Exchange (ETDEWEB)

Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2005-05-18

This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

Refinery Integration of By-Products from Coal-Derived Jet Fuels

Energy Technology Data Exchange (ETDEWEB)

Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2005-11-17

This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

Refinery Integration of By-Products from Coal-Derived Jet Fuels

Energy Technology Data Exchange (ETDEWEB)

Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

2004-09-17

This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

200-BP-5 operable unit Technical Baseline report

International Nuclear Information System (INIS)

Jacques, I.D.; Kent, S.K.

1991-10-01

This report supports development of a remedial investigation/feasibility study work plan for the 200-BP-5 operable unit. The report summarizes baseline information for waste sites and unplanned release sites located in the 200-BP-5 operable unit. The sites were investigated by the Technical Baseline Section of the Environmental Engineering Group, Westinghouse Hanford Company (Westinghouse Hanford). The investigation consisted of review and evaluation of current and historical Hanford Site reports, drawings, and photographs, and was supplemented with recent inspections of the Hanford Site and employee interviews. No field investigations or sampling were conducted

Unpacking Referent Units in Fraction Operations

Science.gov (United States)

Philipp, Randolph A.; Hawthorne, Casey

2015-01-01

Although fraction operations are procedurally straightforward, they are complex, because they require learners to conceptualize different units and view quantities in multiple ways. Prospective secondary school teachers sometimes provide an algebraic explanation for inverting and multiplying when dividing fractions. That authors of this article…

40 CFR Table 26 to Subpart Uuu of... - Initial Compliance With Inorganic HAP Emission Limits for Catalytic Reforming Units

Science.gov (United States)

2010-07-01

... Emission Limits for Catalytic Reforming Units 26 Table 26 to Subpart UUU of Part 63 Protection of... Pollutants for Petroleum Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery... HAP Emission Limits for Catalytic Reforming Units As stated in § 63.1567(b)(4), you shall meet each...

Material resources, energy, and nutrient recovery from waste: are waste refineries the solution for the future?

DEFF Research Database (Denmark)

Tonini, Davide; Martinez-Sanchez, Veronica; Astrup, Thomas Fruergaard

2013-01-01

Waste refineries focusing on multiple outputs of material resources, energy carriers, and nutrients may potentially provide more sustainable utilization of waste resources than traditional waste technologies. This consequential life cycle assessment (LCA) evaluated the environmental performance....... Overall, the waste refinery provided global warming (GW) savings comparable with efficient incineration, MBT, and bioreactor landfilling technologies. The main environmental benefits from waste refining were a potential for improved phosphorus recovery (about 85%) and increased electricity production (by...

Centrifugal microfluidic platforms: advanced unit operations and applications.

Science.gov (United States)

Strohmeier, O; Keller, M; Schwemmer, F; Zehnle, S; Mark, D; von Stetten, F; Zengerle, R; Paust, N

2015-10-07

Centrifugal microfluidics has evolved into a mature technology. Several major diagnostic companies either have products on the market or are currently evaluating centrifugal microfluidics for product development. The fields of application are widespread and include clinical chemistry, immunodiagnostics and protein analysis, cell handling, molecular diagnostics, as well as food, water, and soil analysis. Nevertheless, new fluidic functions and applications that expand the possibilities of centrifugal microfluidics are being introduced at a high pace. In this review, we first present an up-to-date comprehensive overview of centrifugal microfluidic unit operations. Then, we introduce the term "process chain" to review how these unit operations can be combined for the automation of laboratory workflows. Such aggregation of basic functionalities enables efficient fluidic design at a higher level of integration. Furthermore, we analyze how novel, ground-breaking unit operations may foster the integration of more complex applications. Among these are the storage of pneumatic energy to realize complex switching sequences or to pump liquids radially inward, as well as the complete pre-storage and release of reagents. In this context, centrifugal microfluidics provides major advantages over other microfluidic actuation principles: the pulse-free inertial liquid propulsion provided by centrifugal microfluidics allows for closed fluidic systems that are free of any interfaces to external pumps. Processed volumes are easily scalable from nanoliters to milliliters. Volume forces can be adjusted by rotation and thus, even for very small volumes, surface forces may easily be overcome in the centrifugal gravity field which enables the efficient separation of nanoliter volumes from channels, chambers or sensor matrixes as well as the removal of any disturbing bubbles. In summary, centrifugal microfluidics takes advantage of a comprehensive set of fluidic unit operations such as

Upgrading refineries performance: a necessity at the time of lean kine

International Nuclear Information System (INIS)

Anon.

1995-01-01

The increasing problem of petroleum refining in Europe and France has been debated during a seminar organized by the ENSPM (Ecole Nationale Superieure des Petroles et Moteurs) Formation Industrie at Rueil-Malmaison (France) on June 15, 1995. For a new modern refinery, the processing cost for one ton of crude oil can reach 40 US $ and exceeds the refining gross profit. Introduction of unleaded gasoline and the forthcoming 0.05% sulfur gas oil represent additional investments of about 20 US $/t. The increasing production of lighter crude oils, which represent 2/3 of worldwide supplies, has increased the gas oil and fuel price difference. A better equilibrium between supply and demand and significant improvements of refineries performances are required to reduce processing costs. New methods and computerized systems have been developed in this way and presented during this seminar. (J.S.). 1 fig

Lymphohematopoietic cancer mortality and morbidity of workers in a refinery/petrochemical complex in Korea.

Science.gov (United States)

Koh, Dong-Hee; Kim, Tae-Woo; Yoon, Yong-Hoon; Shin, Kyung-Seok; Yoo, Seung-Won

2011-03-01

The purpose of this retrospective cohort study was to investigate the relationship between exposure of Korean workers to petrochemicals in the refinery/petrochemical industry and lymphohematopoietic cancers. The cohort consisted of 8,866 male workers who had worked from the 1960s to 2007 at one refinery and six petrochemical companies located in a refinery/petrochemical complex in Korea that produce benzene or use benzene as a raw material. Standardized mortality ratios (SMRs) and standardized incidence ratios (SIRs) were calculated for 1992-2007 and 1997-2005 based on the death rate and cancer incidence rate of the Korean male population according to job title (production, maintenance, laboratory, and office workers). The overall mortality and most cause-specific mortalities were lower among these workers than those of the general Korean population. Increased SMRs were observed for leukemia (4/1.45; SMR 2.77, 95% CI: 0.75-7.09) and lymphohematopoietic cancers (5/2.51; SMR 2, 95% CI: 0.65-4.66) in production workers, and increased SIRs were also observed in leukemia (3/1.34; SIR 2.24, 95% CI: 0.46-6.54) and lymphohematopoietic cancers (5/3.39; SIR 1.47, 95% CI: 0.48-3.44) in production workers, but the results were not statistically significant. The results showed a potential relationship between leukemia and lymphohematopoietic cancers and exposure to benzene in refinery/petrochemical complex workers. This study yielded limited results due to a short observational period; therefore, a follow-up study must be performed to elucidate the relationship between petrochemical exposure and cancer rates.

Semipermeable membrane devices concentrate mixed function oxygenase inducers from oil sands and refinery wastewaters

International Nuclear Information System (INIS)

Parrott, J.L.; Hewitt, L.M.

2002-01-01

The health of fish in the Athabasca River was examined to determine the effects of both natural and anthropogenic oil sands exposure on liver mixed function oxygenase (MFO) enzymes. Semipermeable membrane devices (SPMD) were used to concentrate bioavailable compounds that may result in MFO induction. The SPMDs were used for a period of 2 weeks in the Steepbank River as well as in oil refinery wastewater and intake ponds. They were then tested to see if they induced ethoxyresorufin-O-deethylase (EROD) activity in hepatoma cells, a cell line derived from a liver cancer of a small fish. SPMDs from the wastewater pond contained potent EROD inducers in fish liver cells. SPMDs from the Athabasca River exhibited some EROD inducers, but they were 1/100 as potent as those of the refinery wastewater. The characteristics of MFO inducers from refinery wastewater were different from natural inducers from the oil sands in the Athabasca and Steepbank Rivers. For instance, log Kow was less than 5 for refinery wastewater, but it was greater than 5 for Athabasca River wastewater and from natural oil sands exposure. In the case of the Steepbank River, the pattern of MFO induction was similar to the MFO induction seen in wild fish.The highest MFO inducers were found to be in the area of the mine, suggesting and anthropogenic pollution source. The less potent inducers were in the area of the natural and undisturbed oil sands. Very few inducers were found outside of the oil sands formation

Twenty years of operation of WWER 440/230 units in Jaslovske Bohunice

International Nuclear Information System (INIS)

Tomek, J.

1998-01-01

It is twenty years this year since the first unit WWER 440 of Slovak Nuclear Power Plant Jaslovske Bohunice was commissioned. There are four units WWER 440 in operation Jaslovske Bohunice site. First two units of older soviet PWR design V-230 (also known as V-1) and other two units of newer V-213 type (also known as V-2). The goal of this presentation is to summarize and evaluate the operation of Unit 1 and 2 for this period of time and mainly to describe what has been done and what is planned to be done to increase the nuclear safety and operational reliability of both units. The operating organization and regulatory authority assume that an internationally acceptable level of safety will be reached by accomplishing of the upgrading program.(author)

Oil refinery wastewater treatment using coupled electrocoagulation and fixed film biological processes

Science.gov (United States)

Pérez, Laura S.; Rodriguez, Oscar M.; Reyna, Silvia; Sánchez-Salas, José Luis; Lozada, J. Daniel; Quiroz, Marco A.; Bandala, Erick R.

2016-02-01

Oil refinery wastewater was treated using a coupled treatment process including electrocoagulation (EC) and a fixed film aerobic bioreactor. Different variables were tested to identify the best conditions using this procedure. After EC, the effluent was treated in an aerobic biofilter. EC was capable to remove over 88% of the overall chemical oxygen demand (COD) in the wastewater under the best working conditions (6.5 V, 0.1 M NaCl, 4 electrodes without initial pH adjustment) with total petroleum hydrocarbon (TPH) removal slightly higher than 80%. Aluminum release from the electrodes to the wastewater was found an important factor for the EC efficiency and closely related with several operational factors. Application of EC allowed to increase the biodegradability of the sample from 0.015, rated as non-biodegradable, up to 0.5 widely considered as biodegradable. The effluent was further treated using an aerobic biofilter inoculated with a bacterial consortium including gram positive and gram negative strains and tested for COD and TPH removal from the EC treated effluent during 30 days. Cell count showed the typical bacteria growth starting at day three and increasing up to a maximum after eight days. After day eight, cell growth showed a plateau which agreed with the highest decrease on contaminant concentration. Final TPHs concentration was found about 600 mgL-1 after 30 days whereas COD concentration after biological treatment was as low as 933 mgL-1. The coupled EC-aerobic biofilter was capable to remove up to 98% of the total TPH amount and over 95% of the COD load in the oil refinery wastewater.

40 CFR Table 27 to Subpart Uuu of... - Continuous Compliance With Inorganic HAP Emission Limits for Catalytic Reforming Units

Science.gov (United States)

2010-07-01

... HAP Emission Limits for Catalytic Reforming Units 27 Table 27 to Subpart UUU of Part 63 Protection of... Pollutants for Petroleum Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery... Inorganic HAP Emission Limits for Catalytic Reforming Units As stated in § 63.1567(c)(1), you shall meet...

Calculation and analysis of environmental costs of the atmospheric pollution from brazilian oil refinery; Calculo e analise dos custos ambientais da poluicao atmosferica emitida por uma refinaria de petroleo brasileira

Energy Technology Data Exchange (ETDEWEB)

Mariano, Jacqueline [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Programa de Planejamento Energetico

2004-07-01

The present study presents a calculation of the environmental costs associated with the atmospheric pollution from a brazilian oil refinery and its analysis (the name of this oil refinery is confidential, for this reason it will not be mentioned). The calculation of the costs was based on a study of north-american researchers, about the environmental costs of five main atmospheric pollutants: particulate matter, sulphur oxides, nitrogen oxides, volatile organic compounds (VOC's) and carbon monoxide. The original American study offers an statistical analysis of several other American studies about environmental costs of atmospheric pollution, that present maximum, medium and minimum costs. Based on these values, the total environmental costs of the atmospheric pollution from the brazilian oil refinery were calculated, considering a fifty year operational time for the facility. The internalization of the atmospheric pollution environmental costs by the refiners is aligned with the world tendency of enforcement of the environmental limitations faced by the oil refining sector, and therefore, the adoption of a pro-active attitude is recommended by the present study. (author)

Identifying ideology: media representations of the Irving Oil Refinery strike, 1994-1996

Energy Technology Data Exchange (ETDEWEB)

Steuter, E.C.

1998-07-01

Media coverage of a strike at the Irving Oil Refinery in Saint John, New Brunswick which began in 1994 and lasted until 1996 is used as a background for the examination of ideology, used here in the more inclusive sense, one in which the term suggests a frame of mind without the coherence and easily recognized label usually associated with political ideology. Central issues such as monopoly ownership of the New Brunswick media by the Irving Group of Companies (also owners of the refinery) , the ideological presentation of strikes in general, and the representation of changing labour relations in a post-industrial, globally-oriented society are analyzed to show how these issues influenced media coverage. Four New Brunswick dailies as well as selected English-language dailies from other parts of Canada have been scrutinized in an effort to determine their ideological stand. It was found that restrictive ideologies such as liberalism or conservatism are on the decline; instead, more inclusive ideologies like defeatism and individualism were prominently featured especially by the St. John Telegraph-Journal in New Brunswick and other papers outside the province. The most striking finding was that if the media coverage of the Irving Refinery strike is representative of public opinion, the current organization of the provincial political economy is accepted as 'natural' by a majority of New Brunswickers.

Assessment of the estrogenic potency of effluents from petrochemical facilities and a petroleum refinery in Ontario

International Nuclear Information System (INIS)

Sherry, J.P.; Trepanier, T.; Tinson, C.; Munro, S.

2002-01-01

Studies have shown that wastewater from refineries could induce vitellogenin (Vg) in juvenile rainbow trout. Vg is a biomarker of exposure to estrogenic chemicals. This study reassessed the estrogenic potency of the wastewater from an Ontario refinery and assessed the estrogenicity of wastewater from 3 petrochemical facilities. A 21 day static renewal test was conducted to test the effluents and in which a competitive binding ELISA detected induced Vg. Statistical testing for tank effects was performed in a replicated tank design and the St. Clair River water from upstream industrial facilities was used as a negative reference. The positive control treatment was waterborne 17β-estradiol. Wastewater from the petroleum refinery induced Vg in the treated fish, but wastewater from the petrochemical effluents did not induce detectable levels of Vg in treated trout. The information obtained through this study will be used to determine the potential for responses in feral fish

Eielson Air Force Base Operable Unit 2 baseline risk assessment

Energy Technology Data Exchange (ETDEWEB)

Lewis, R.E.; Jarvis, T.T.; Jarvis, M.R.; Whelan, G.

1994-10-01

Operable Unit 2 at Eielson Air Force Base (AFB) near Fairbanks, is one of several operable units characterized by petroleum, oil, and lubricant contamination, and by the presence of organic products floating at the water table, as a result of Air Force operations since the 1940s. The base is approximately 19,270 acres in size, and comprises the areas for military operations and a residential neighborhood for military dependents. Within Operable Unit 2, there are seven source areas. These source areas were grouped together primarily because of the contaminants released and hence are not necessarily in geographical proximity. Source area ST10 includes a surface water body (Hardfill Lake) next to a fuel spill area. The primary constituents of concern for human health include benzene, toluene, ethylbenzene, and xylenes (BTEX). Monitored data showed these volatile constituents to be present in groundwater wells. The data also showed an elevated level of trace metals in groundwater.

Operational safety experience reporting in the United States

International Nuclear Information System (INIS)

Hartfield, R.A.

1978-01-01

Licensees of nuclear power plants in the United States have many reporting requirements included in their technical specifications and the code of federal regulations, title 10. The Nuclear Regulatory Commisson receives these reports and utilizes them in its regulatory program. Part of this usage includes collecting and publishing this operating experience data in various reports and storing information in various data systems. This paper will discuss the data systems and reports on operating experience published and used by the NRC. In addition, some observations on operating experience will be made. Subjects included will be the Licensee Event Report (LER) Data File, the Operating Unit Status Report (Gray Book), Radiation Exposure Reports, Effluents Reports, the Nuclear Plant Reliability Data System, Current Events, Bulletin Wrapups and Annual Summaries. Some of the uses of the reports and systems will be discussed. The Abnormal Occurence Report to the US Congress will also be described and discussed. (author)

A Study on the Preparation of Regular Multiple Micro-Electrolysis Filler and the Application in Pretreatment of Oil Refinery Wastewater.

Science.gov (United States)

Yang, Ruihong; Zhu, Jianzhong; Li, Yingliu; Zhang, Hui

2016-04-29

Through a variety of material screening experiments, Al was selected as the added metal and constituted a multiple micro-electrolysis system of Fe/C/Al. The metal proportion of alloy-structured filler was also analyzed with the best Fe/C/Al ratio of 3:1:1. The regular Fe/C/Al multiple micro-electrolysis fillers were prepared using a high-temperature anaerobic roasting method. The optimum conditions for oil refinery wastewater treated by Fe/C/Al multiple micro-electrolysis were determined to be an initial pH value of 3, reaction time of 80 min, and 0.05 mol/L Na₂SO₄ additive concentration. The reaction mechanism of the treatment of oil refinery wastewater by Fe/C/Al micro-electrolysis was investigated. The process of the treatment of oil refinery wastewater with multiple micro-electrolysis conforms to the third-order reaction kinetics. The gas chromatography-mass spectrometry (GC-MS) used to analyze the organic compounds of the oil refinery wastewater before and after treatment and the Ultraviolet-visible spectroscopy (UV-VIS) absorption spectrum analyzed the degradation process of organic compounds in oil refinery wastewater. The treatment effect of Fe/C/Al multiple micro-electrolysis was examined in the continuous experiment under the optimum conditions, which showed high organic compound removal and stable treatment efficiency.

Analysis of snow-cap pollution for air quality assessment in the vicinity of an oil refinery.

Science.gov (United States)

Krastinyte, Viktorija; Baltrenaite, Edita; Lietuvninkas, Arvydas

2013-01-01

Snow-cap can be used as a simple and effective indicator of industrial air pollution. In this study snow-cap samples were collected from 11 sites located in the vicinity of an oil refinery in Mazeikiai, a region in the north-west of Lithuania, in the winter of 2011. Analysis of snowmelt water and snow-dust was used to determine anthropogenic pollutants such as: sulphates and chlorides, nitrites, nitrates, ammonium nitrogen, total carbon, total nitrogen; heavy metals: lead (Pb), copper (Cu), chromium (Cr), cadmium (Cd). Concentrations of heavy metals in snow-dust were detected thousands of times higher than those in the snowmelt water. In this study, analysis of heavy metal concentration was conducted considering different distances and the wind direction within the impact zone of the oil refinery. The sequence of heavy metals according to their mean concentrations in the snow-dust samples was the following: Pb > Cr > Cu > Cd. Heavy metals highly correlated among each other. The load of snow-dust was evaluated to determine the pollution level in the study area. The highest daily load of snow-dust was 45.81 +/- 12.35 mg/m2 in the north-western direction from the oil refinery. According to classification of the daily load of snow-dust a lower than medium-risk level of pollution was determined in the vicinity of the oil refinery.

Materials And Carbon Flow In A Waste Refinery Process Using Enzymes

DEFF Research Database (Denmark)

Tonini, Davide; Woods, M.; Astrup, Thomas

2011-01-01

Recovery of resources from mixed Municipal Solid Waste (MSW) is a crucial aspect of waste management practices. In this paper the materials and carbon flows of an innovative waste refinery process using enzymes are presented. Through enzymatic treatment the process produces two main streams from...... the initial mixed MSW: a bioslurry (liquefied paper and organics) and a solid fraction (non-degradable materials). The discussion is based on the performance of the process in separating recyclables and recovery Cbiogenic as well as nutrients from the input MSW. The results of MFA and SFA illustrate...... that the waste refinery has great potential for resource recovery: about 100% of the Cbiogenic and up to 90% of N and P can potentially be recovered in the bioslurry and returned to land after anaerobic digestion. Recovery of ferrous and non-ferrous material is estimated double compared to recovering the same...

Application of Ozone MBBR Process in Refinery Wastewater Treatment

Science.gov (United States)

Lin, Wang

2018-01-01

Moving Bed Biofilm Reactor (MBBR) is a kind of sewage treatment technology based on fluidized bed. At the same time, it can also be regarded as an efficient new reactor between active sludge method and the biological membrane method. The application of ozone MBBR process in refinery wastewater treatment is mainly studied. The key point is to design the ozone +MBBR combined process based on MBBR process. The ozone +MBBR process is used to analyze the treatment of concentrated water COD discharged from the refinery wastewater treatment plant. The experimental results show that the average removal rate of COD is 46.0%~67.3% in the treatment of reverse osmosis concentrated water by ozone MBBR process, and the effluent can meet the relevant standard requirements. Compared with the traditional process, the ozone MBBR process is more flexible. The investment of this process is mainly ozone generator, blower and so on. The prices of these items are relatively inexpensive, and these costs can be offset by the excess investment in traditional activated sludge processes. At the same time, ozone MBBR process has obvious advantages in water quality, stability and other aspects.

Implication of coastal refineries to the ecology of the Gulf of Kachchh

Digital Repository Service at National Institute of Oceanography (India)

Zingde, M.D.; Anand, N.M.

bank of the Gulf of Kachchh. An assessment of probable impact of establishment of these refineries to the rich biodiversity of the Gulf and suggestions to minimise these impacts have been made in this paper....

200-UP-2 operable unit radiological surveys

International Nuclear Information System (INIS)

Wendling, M.A.

1994-01-01

This report summarizes and documents the results of the radiological surveys conducted from August 17 through December 16, 1993 over a partial area of the 200-UP-2 Operable Unit, 200-W Area, Hanford Site, Richland, Washington. In addition, this report explains the survey methodology of the Mobile Surface Contamination Monitor 11 (MSCM-II) and the Ultra Sonic Ranging And Data System (USRADS). The radiological survey of the 200-UP-2 Operable Unit was conducted by the Site Investigative Surveys/Environmental Restoration Health Physics Organization of the Westinghouse Hanford Company. The survey methodology for the majority of area was based on utilization of the MSCM-II or the USRADS for automated recording of the gross beta/gamma radiation levels at or near six (6) inches from the surface soil

Evaluation the Phytoremediation of Oil-contaminated Soils Around Isfahan Oil Refinery

Directory of Open Access Journals (Sweden)

Farida Iraji-Asiabadi

2016-07-01

Full Text Available Petroleum compounds are pollutants that most commonly occur in soils around oil refineries and that often find their ways into groundwater resources. Phytoremediation is a cost-effective alternative to physicochemical methods for oil-contaminated soil remediation, where feasible. In this study, a greenhouse experiment was conducted to evaluate the phytoremediation of oil-contaminated soils around Isfahan Oil Refinery. Four different plants (namely, sorghum, barley, agropyron, and festuca were initially evaluated in terms of their germinability in both contaminated and control (non-contaminated soils. Sorghum and barley (recording the highest germinability values were chosen as the species for use in the phytoremediation experiments. Shoot and root dry weights, total and oil-degrading bacteria counts, microbial activity, and total concentrations of petroleum hydrocarbons (TPHs were determined at harvest 120 days after planting. A significant difference was observed in the bacterial counts (total and oil-degrading bacteria between the planted soils and the control. In contaminated soils, a higher microbial activity was observed in the rhizosphere of the sorghum soil than in that of barley. TPHs concentration decreased by 52%‒64% after 120 days in contaminated soil in which sorghum and barley had been cultivated. This represented an improvement of 30% compared to the contaminated soil without plants. Based on the results obtained, sorghum and barley may be recommended for the removal of petro-contaminants in areas close to Isfahan Oil Refinery. Nevertheless, caution must be taken as such cultivated lands may need to be protected against grazing animals.

Studies of the terrestrial environment and ambient air quality in the vicinity of the Eldorado Resources Ltd. Refinery at Blind River, Ontario 1981-1987

Energy Technology Data Exchange (ETDEWEB)

Spires, A.C.; Negusanti, J.J.; Bazinet, D.J.

1989-08-01

In 1981, a program was initiated to obtain background data on soils and vegetation in the vicinity of the Eldorado uranium trioxide plant in Blind River, Ontario prior to operational startup in 1983. Soil and vegetation samples have been collected annually for chemical analyses at 7 plot sites between 1981 and 1987. All samples were anlayzed for U, Cu, Ni, Pb, Zn, Co, Fe, S, Ca, Mg, and K. Of these elements, only uranium showed an increase in concentration in foliage samples collected in close proximity to the refinery following startup. Uranium accumulation occurred in red and white pine needles up to a level of 100 [mu]g/g. Uranium levels found in all soil and wild edible samples were considered normal. The increase of uranium content observed over time in the collected vegetation samples shows deposition from the refinery is being retained in annual vegetation and accumulated in conifers. Since uranium levels are low in soil, the levels in vegetation result from deposition and not uptake. A high-volume air sampling program was also initiated in 1982 in Blind River. Air sampler filters were weighed to determine total suspended particulate and were subjected to radiological analysis. Particulate levels were found to be low and no increase in particulate or radiological parameter levels was observed since the startup of the refinery. 9 refs., 4 figs., 17 tabs.

Refinery plugging by residual oil gellant chemicals in crude : understanding and preventing the problem through new oil gellant chemistry

Energy Technology Data Exchange (ETDEWEB)

Taylor, R.S.; Cheng, A.; Tamayo, C.; Funkhouser, G.P. [Halliburton, Calgary, AB (Canada); Stemler, P. [Petro-Canada Oil and Gas, Inc., Calgary, AB (Canada); Lemieux, A. [Omnicon Consultants Inc., Edmonton, AB (Canada)

2004-07-01

Phosphate ester oil gellants are the most prevalent oil gellant technology in use by service companies. However, in 1995, they were found to be responsible for plugging distillation trays at 3 refineries across Canada including Imperial Oil's Strathcona refinery in Edmonton, Petro-Canada's refinery in Oakville, Ontario and Chevron's refinery in Burnaby, British Columbia. Since 1998, additional fouling has occurred in Canada, and in 2002, fouling was detected at a refinery in Pennsylvania while processing Canadian sweet, light crude. Since refiners pay a high cost for unscheduled refinery shutdowns, much effort has gone into solving this problem and to maintain the value of Canadian sweet, light crude. Studies by the Canadian Crude Quality Technical Association (CCQTA) have shown that phosphate esters begin to decompose through hydrolysis of the ester linkage at approximately 240 degrees. Gases cool as they move up the tower through distillation trays. Trays in the temperature range of 230 to 290 degrees C produce most of the volatile phosphorous compounds that condense out of the gas phase and cause plugging, thereby reducing the efficiency of distillation. Phosphate esters are often used with a metal crosslinker such as ferric iron or aluminium to gel hydrocarbons for use as a fracturing fluid. This paper described the advantages of existing ferric iron-crosslinked phosphate ester oil gels over the older, alternative oil gellant chemistries. Carbon dioxide-miscible, gelled hydrocarbon fracturing fluids provide better well stimulation by avoiding capillary pressure effects associated with water-based fluids. The fluid properties of the new phosphonate ester system were compared to those of a conventional phosphate ester system. Field tests from two fracturing treatments were also presented. Plugging did not occur with the new phosphonate ester treatment. 6 refs., 1 tab., 12 figs.

A Novel Transporting System Model for Oil Refinery

OpenAIRE

Razman M. Tahar; Waleed K. Abduljabbar

2010-01-01

Problem statement: Oil refineries are widely used to store various liquids and gases. Petroleum products are in high demand. Oil companies have abundant resources of petroleum products in pipelines and storage tanks. Approach: Included are storage tanks at retail gasoline station, home heating oil tanks, lubricant storage at automotive service facilities, propane tanks in all sorts of application, and oil company terminals across the world. The aim of this study is to present a model by which...

US refineries lament lack of final CAA rules

International Nuclear Information System (INIS)

Anon.

1992-01-01

Bush administration spokesman appeared unconvinced about the extent of the U.S. refining industry's problems at a Senate energy committee hearing. This paper reports that the oversight hearing examined various challenges facing refiners. Roger Beach, president of Unocal Refining and Marketing Division, testified for the National Petroleum Refiners Association, of which he is chairman. Beach the refineries still do not know what final Clean Air Act (CAA) amendments regulations will be, and state rules are changing, too

Increasing the flexibility of base-load generating units in operation on fossil fuel

Energy Technology Data Exchange (ETDEWEB)

Girshfel' d, V Ya; Khanaev, V A; Volkova, E D; Gorelov, V A; Gershenkroi, M L

1979-01-01

Increasing the flexibility of base-load generating units operating on fossil fuel by modifying them is a necessary measure. The highest economic effect is attained with modification of gas- and oil-fired generating units in the Western United Power Systems of the European part of the SPSS. On the basis of available experience, 150- and 200-MW units can be extensively used to regulate the power in the European part of the SPSS through putting them into reserve for the hours of the load dip at night. The change under favorable conditions of 150- and 200-MW units operating on coal to a district-heating operating mode does not reduce the possibilities for flexible operation of these units because it is possible greatly to unload the turbines while the minimum load level of the pulverized fuel fired boiler is retained through transferring a part of the heat load to the desuperheater. It is necessary to accumulate and analyze experience with operation of generating units (especially of supercritical units) with regular shutdowns and starts of groups of units and to solve the problems of modification of generating units, with differentiation with respect to types of fuel and to the united power supply system.

100-KR-1 Operable Unit focused feasibility study report

International Nuclear Information System (INIS)

1994-11-01

The standard Comprehensive Environmental Response, Compensation, and Liability Act of 1980 Feasibility Study (FS) includes development and screening of alternatives and the detailed analysis of alternatives. This focused feasibility study (FFS) was conducted for the 100-KR-1 Operable Unit at the Hanford Site in southeastern Washington. The objective of this operable unit-specific FFS is to provide decision makers with sufficient information to allow appropriate and timely selection of interim remedial measures (IRM) for the five sites (116-K-1 crib, 116-K-2 trench, 116-KE-4 and 116-KW-3 retention basins, and process effluent pipelines) associated with the 100-KR-1 Operable Unit. The IRM candidate waste sites are determined in the limited field investigation. Site profiles are developed for each of these waste site. The site profiles are used in the application of the plug-in approach. The waste site either plugs into the analysis of the alternatives for the group, or deviations from the developed group alternatives are described and documented

Meteorologically estimated exposure but not distance predicts asthma symptoms in schoolchildren in the environs of a petrochemical refinery: a cross-sectional study

CSIR Research Space (South Africa)

White, N

2009-09-01

Full Text Available Community concern about asthma prompted an epidemiological study of children living near a petrochemical refinery in Cape Town, South Africa. Because of resource constraints and the complexity of refinery emissions, neither direct environmental...

Olefin recovery from FCC off-gas can pay off

International Nuclear Information System (INIS)

Brahn, M.G.

1992-01-01

This paper reports on olefins recovery from refinery FCC offgas streams which offers an attractive cash flow from olefins from a tail-gas stream that has typically been consumed as refinery fuel. Such recovery schemes can be employed in refineries or olefins plants, and can be tailored to fit individual requirements. Mobil Chemical Co. has operated such a dephlegmator-based off-gas recovery unit at its Beaumont, Tex., olefin plant since 1987. It reported that the project was paid out within 11 months of initial start-up

Catalytic hydrotreatment of refinery waste: Demonstration project

Energy Technology Data Exchange (ETDEWEB)

1989-01-01

The object of this project and report is to produce liquid hydrocarbons by the catalytic hydroprocessing of solid refinery wastes (hard pitches) in order to improve the profitability of deep conversion processes and reduce the excess production of heavy fuels. The project was mostly carried out on the ASVAHL demonstration platform site, at Solaize, and hard pitches were produced primarily by deasphalting of atmospheric or vacuum distillation residues. The project includes two experimental phases and an economic evaluation study phase. In Phase 1, two granular catalysts were used to transform pitch into standard low sulfur fuel oil: a continuously moving bed, with demetallation and conversion catalyst; a fixed bed, with hydrorefining catalyst. In Phase 2 of the project, it was proven that a hydrotreatment process using a finely dispersed catalyst in the feedstock, can, under realistic operating conditions, transform with good yields hard pitch into distillates that can be refined through standard methods. In Phase 3 of the project, it was shown that the economics of such processes are tightly linked to the price differential between white'' and black'' oil products, which is expected to increase in the future. Furthermore, the evolution of environmental constraints will impel the use of such methods, thus avoiding the coproduction of polluting solid residues. 11 figs., 1 tab.

100 Area source operable unit focused feasibility study report. Draft A

International Nuclear Information System (INIS)

1994-09-01

In accordance with the Hanford Past-Practice Strategy (HPPS), a focused feasibility study (FFS) is performed for those waste sites which have been identified as candidates for interim remedial measures (IRM) based on information contained in applicable work plans and limited field investigations (LFI). The FFS process for the 100 Area source operable units will be conducted in two stages. This report, hereafter referred to as the Process Document, documents the first stage of the process. In this stage, IRM alternatives are developed and analyzed on the basis of waste site groups associated with the 100 Area source operable units. The second stage, site-specific evaluation of the IRM alternatives presented in this Process Document, is documented in a series of operable unit-specific reports. The objective of the FFS (this Process Document and subsequent operable unit-specific reports) is to provide decision makers with sufficient information to allow appropriate and timely selection of IRM for sites associated with the 100 Area source operable units. Accordingly, the following information is presented: a presentation of remedial action objectives; a description of 100 Area waste site groups and associated group profiles; a description of IRM alternatives; and detailed and comparative analyses of the IRM alternatives

2014 Highlights of Ferry Operations in the United States

Science.gov (United States)

2016-05-01

Based on information provided by operators who responded to the 2014 National Census of Ferry Operators (NCFO), the Bureau of Transportation Statistics (BTS) conservatively estimates that ferries in the United States carried just over 115 million pas...

Evaluating the performance of an integrated CALPUFF-MM5 modeling system for predicting SO{sub 2} emission from a refinery

Energy Technology Data Exchange (ETDEWEB)

Abdul-Wahab, Sabah Ahmed [Sultan Qaboos University, Department of Mechanical and Industrial Engineering, College of Engineering, Muscat (Oman); Ali, Sappurd [National Engineering and Scientific Commission (NESCOM), Islamabad (Pakistan); Sardar, Sabir; Irfan, Naseem [Pakistan Institute of Engineering and Applied Sciences (PIEAS), Islamabad (Pakistan); Al-Damkhi, Ali [Public Authority for Applied Education and Training (PAAET), Department of Environmental Sciences College of Health Sciences, Salmiyah (Kuwait)

2011-12-15

Oil refineries are one of the proven sources of environmental pollution as they emit more than 100 chemicals into the atmosphere including sulfur dioxide (SO{sub 2}). The dispersion patterns of SO{sub 2} from emissions of Sohar refinery was simulated by employing California Puff (CALPUFF) model integrated with state of the art meteorological Mesoscale Model (MM5). The results of this simulation were used to quantify the ground level concentrations of SO{sub 2} in and around the refinery. The evaluation of the CALPUFF and MM5 modeling system was carried out by comparing the estimated results with that of observed data of the same area. The predicted concentrations of SO{sub 2} agreed well with the observed data, with minor differences in magnitudes. In addition, the ambient air quality of the area was checked by comparing the model results with the regulatory limits for SO{sub 2} set by the Ministry of Environment and Climate Affairs (MECA) in Oman. From the analysis of results, it was found that the concentration of SO{sub 2} in the nearby communities of Sohar refinery is well within the regulatory limits specified by MECA. Based on these results, it was concluded that no health risk, due to SO{sub 2} emissions, is present in areas adjacent to the refinery. (orig.)

A Study on the Preparation of Regular Multiple Micro-Electrolysis Filler and the Application in Pretreatment of Oil Refinery Wastewater

Directory of Open Access Journals (Sweden)

Ruihong Yang

2016-04-01

Full Text Available Through a variety of material screening experiments, Al was selected as the added metal and constituted a multiple micro-electrolysis system of Fe/C/Al. The metal proportion of alloy-structured filler was also analyzed with the best Fe/C/Al ratio of 3:1:1. The regular Fe/C/Al multiple micro-electrolysis fillers were prepared using a high-temperature anaerobic roasting method. The optimum conditions for oil refinery wastewater treated by Fe/C/Al multiple micro-electrolysis were determined to be an initial pH value of 3, reaction time of 80 min, and 0.05 mol/L Na2SO4 additive concentration. The reaction mechanism of the treatment of oil refinery wastewater by Fe/C/Al micro-electrolysis was investigated. The process of the treatment of oil refinery wastewater with multiple micro-electrolysis conforms to the third-order reaction kinetics. The gas chromatography–mass spectrometry (GC–MS used to analyze the organic compounds of the oil refinery wastewater before and after treatment and the Ultraviolet–visible spectroscopy (UV–VIS absorption spectrum analyzed the degradation process of organic compounds in oil refinery wastewater. The treatment effect of Fe/C/Al multiple micro-electrolysis was examined in the continuous experiment under the optimum conditions, which showed high organic compound removal and stable treatment efficiency.

Zn isotope study of atmospheric emissions and dry depositions within a 5 km radius of a Pb-Zn refinery

Science.gov (United States)

Mattielli, Nadine; Petit, Jérôme C. J.; Deboudt, Karine; Flament, Pascal; Perdrix, Esperanza; Taillez, Aurélien; Rimetz-Planchon, Juliette; Weis, Dominique

The present paper examines the use of zinc isotopes as tracers of atmospheric sources and focuses on the potential fractionation of Zn isotopes through anthropogenic processes. In order to do so, Zn isotopic ratios are measured in enriched ores and airborne particles associated with pyrometallurgical activities of one of the major Pb-Zn refineries in France. Supporting the isotopic investigation, this paper also compares morphological and chemical characteristics of Zn particles collected on dry deposition plates ("environmental samples") placed within a 5 km radius of the smelter, with those of Zn particles collected inside the plant ("process samples"), i.e. dust collected from the main exhaust system of the plant. To ensure a constant isotopic "supply", the refinery processed a specific set of ores during the sampling campaigns, as agreed with the executive staff of the plant. Enriched ores and dust produced by the successive Zn extraction steps show strong isotope fractionation (from -0.66 to +0.22‰) mainly related to evaporation processes within the blast furnaces. Dust from the main chimney displays a δ 66Zn value of -0.67‰. Application of the Rayleigh equation to evaluate the fractionation factor associated with the Zn vapor produced after a free evaporation gives a range of αore/vapor from 1.0004 to 1.0008. The dry deposits, collected on plates downwind of the refinery, display δ 66Zn variations of up to +0.7‰. However, it is to be noted that between 190 and 1250 m from the main chimney of the refinery, the dry deposits show a high level of large (>10 μm) Zn, S, Fe and O bearing aggregates characterized by positive δ 66Zn values (+0.02 to +0.19‰). These airborne particles probably derive from the re-suspension of slag heaps and local emissions from the working-units. In contrast, from 1720 to 4560 m, the dry deposits are comprised of small (PM10) particles, including spherical Zn-bearing aggregates, showing negative δ 66Zn values (-0.52 to -0

Advances made in development of competence of refining plant operators. The REPAR case, PR, Brazil; Avancos realizados no desenvolvimento de competencias de operadores de plantas de refino: o caso da REPAR

Energy Technology Data Exchange (ETDEWEB)

Reis, Mario [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas. Recursos Humanos]. E-mail: marioreis@petrobras.com.br

2004-12-01

The work presents a synthesis of the outcome of two years of research and experiments for the development of competence of Refinery operators in a project carried out by REPAR - Presidente Getulio Vargas Refinery in partnership with the Parana Federal University Education sector. From the Refinery need to reformulate its operators formation and development process, an important perspective was open to discuss and implement pedagogical principles based on the competence category as praxis. Such category brings forth the commitment to transform the workers educational processes and the production social relations excelling the models based on Taylorian/Fordian paradigm.(author)

Fiscal 1998 research report. Feasibility study on the CO{sub 2} reduction project by residue power generation at the oil refinery in China; 1998 nendo chosa hokokusho. Chugoku no seiyusho ni okeru zansa hatsuden ni yoru CO{sub 2} sakugen project ni kansuru F/S chosa

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-03-01

As a part of the basic research on joint project promotion, this feasibility study supposed introduction of IGCC (integrated gasification combined cycle) to Nanjing oil refinery of Jinling Petrochemical Corp. (JPC) in China, estimated the CO{sub 2} emission reduction effect by in-refinery efficient power generation using petroleum coke residue as fuel, and assessed the feasibility of the project together with a cost benefit. The feasibility study result showed the effectiveness of IGCC introduction to the oil refinery for reducing CO{sub 2} emissions, occupying the interest of JPC. However, Nanjing oil refinery already making a decision to adopt another system (BTG) answered that early adoption of this project is difficult. The feasibility study result also showed that efficient operation of IGCC is difficult because of lower generation efficiency of petroleum coke residue, and achievement of the supposed CO{sub 2} emission reduction effect and profitability is difficult. The project based on this feasibility study result is probably difficult to be realized. (NEDO)

Impact of PAH [Polycyclic Aromatic Hydrocarbons] outlets from an oil refinery on the receiving water area - sediment trap fluxes and multivariate statistical analysis

International Nuclear Information System (INIS)

Pettersen, Harald; Naef, Carina; Broman, Dag

1997-01-01

PAH concentrations (15 compounds) in settling particulate matter (SPM) collected in the waters outside a petroleum refinery on the Swedish Baltic coast, and in samples of particulate and dissolved fractions in the wastewater from the refinery were determined. SPM concentrations varied between 550 and 4250 ng x gdw -1 and the corresponding calculated fluxes varied between 0.1 and 3.7 ng x cm -2 x day -1 . Both concentrations and fluxes did not differ significantly from background coastal or offshore locations in the Baltic. PAH profiles of the SPM samples were compared with the wastewater samples and SPM samples from background areas in the Baltic, using pattern recognition techniques. This analysis showed that the SPM samples from the petroleum refinery displayed a PAH composition similar to that found in background reference sites in the Baltic, and that the SPM samples could not be connected to the wastewater samples from the refinery. This indicates that Nynas AB is not a significant source of PAHs to the waters in its immediate surroundings, i.e. the waters in the Nynashamn area, and/or that the hydraulic residence time of the water outside the refinery is low. A budget calculation showed that the wastewater outlet from Nynas AB is only a minor contributor of the PAH load to the waters outside the refinery. (Author)

Evaluation of the impact of Kaduna refinery effluent on river Romi ...

African Journals Online (AJOL)

The continuous global quest for management of the scarce water resources to make available to the human populace, portable water for drinking has necessitated this study. River Romi is the effluent discharge point of Kaduna Refining and Petrochemical Company Limited where the refinery waste water is disposed after ...

Use of various acute, sublethal and early life-stage tests to evaluate the toxicity of refinery effluents

International Nuclear Information System (INIS)

Sherry, J.; Scott, B.; Dutka, B.

1997-01-01

The toxicities of effluents from three Ontario, Canada, refineries were assessed with microbes, plants, invertebrates, and fish. Acute toxicity was assessed by the Microtox test, an assay based on electron transport activity in submitochondrial particles, and Daphnia magna (water flea); growth of Selenastrum capricornutum (alga); growth of Lemna minor (aquatic plant); germination of Lactuca sativa (nonaquatic plant); survival, growth, and maturation of Panagrellus redivivus (nematode); and genotoxicity in the SOS-Chromotest. Only the Microtox test and the submitochondrial particle test detected acute toxicity in the effluent samples. Reduced survival and sublethal responses were caused by some effluents, but not all effluents were toxic, and none caused a response in all of the tests applied. The results suggest that the effluent treatment systems used at Ontario refineries have largely eliminated acute toxicity to the organisms in their test battery. Although reduced survival and sublethal effects were detected in some of the effluents, the effects were minor. Some of the tests provided evidence, albeit weak, of variations in the responses of the test organisms to a temporal series of effluent samples. Not unexpectedly, there were also minor differences in the responses of the tests to effluents from the three refineries. The fathead minnow test seems to be a sensitive indicator of the sublethal toxicity of Ontario refinery effluents

Biostimulation of indigenous microbial community for bioremediation of petroleum refinery sludge.

Directory of Open Access Journals (Sweden)

Jayeeta Sarkar

2016-09-01

Full Text Available Nutrient deficiency severely impairs the catabolic activity of indigenous microorganisms in hydrocarbon rich environments (HREs and limits the rate of intrinsic bioremediation. The present study aimed to characterize the microbial community in refinery waste and evaluate the scope for biostimulation based in situ bioremediation. Samples recovered from the wastewater lagoon of Guwahati refinery revealed a hydrocarbon enriched high total petroleum hydrocarbon (TPH, oxygen-, moisture-limited, reducing environment. Intrinsic biodegradation ability of the indigenous microorganisms was enhanced significantly (>80% reduction in TPH by 90 days with nitrate amendment. Preferred utilization of both higher- (>C30 and middle- chain (C20-30 length hydrocarbons were evident from GC-MS analysis. Denaturing gradient gel electrophoresis (DGGE and community level physiological profiling (CLPP analyses indicated distinct shift in community’s composition and metabolic abilities following nitrogen (N amendment. High throughput deep sequencing of 16S rRNA gene showed that the native community was mainly composed of hydrocarbon degrading, syntrophic, methanogenic, nitrate/iron/sulfur reducing facultative anaerobic bacteria and archaebacteria, affiliated to γ- and δ-Proteobacteria and Euryarchaeota respectively. Genes for aerobic and anaerobic alkane metabolism (alkB and bssA, methanogenesis (mcrA, denitrification (nirS and narG and N2 fixation (nifH were detected. Concomitant to hydrocarbon degradation, lowering of dissolve O2 and increase in oxidation-reduction potential (ORP marked with an enrichment of N2 fixing, nitrate reducing aerobic/facultative anaerobic members e.g., Azovibrio, Pseudoxanthomonas and Commamonadaceae members was evident in N amended microcosm. This study highlighted that indigenous community of refinery sludge was intrinsically diverse, yet appreciable rate of in situ bioremediation could be achieved by supplying adequate N sources.

Biostimulation of Indigenous Microbial Community for Bioremediation of Petroleum Refinery Sludge

Science.gov (United States)

Sarkar, Jayeeta; Kazy, Sufia K.; Gupta, Abhishek; Dutta, Avishek; Mohapatra, Balaram; Roy, Ajoy; Bera, Paramita; Mitra, Adinpunya; Sar, Pinaki

2016-01-01

Nutrient deficiency severely impairs the catabolic activity of indigenous microorganisms in hydrocarbon rich environments (HREs) and limits the rate of intrinsic bioremediation. The present study aimed to characterize the microbial community in refinery waste and evaluate the scope for biostimulation based in situ bioremediation. Samples recovered from the wastewater lagoon of Guwahati refinery revealed a hydrocarbon enriched [high total petroleum hydrocarbon (TPH)], oxygen-, moisture-limited, reducing environment. Intrinsic biodegradation ability of the indigenous microorganisms was enhanced significantly (>80% reduction in TPH by 90 days) with nitrate amendment. Preferred utilization of both higher- (>C30) and middle- chain (C20-30) length hydrocarbons were evident from GC-MS analysis. Denaturing gradient gel electrophoresis and community level physiological profiling analyses indicated distinct shift in community’s composition and metabolic abilities following nitrogen (N) amendment. High throughput deep sequencing of 16S rRNA gene showed that the native community was mainly composed of hydrocarbon degrading, syntrophic, methanogenic, nitrate/iron/sulfur reducing facultative anaerobic bacteria and archaebacteria, affiliated to γ- and δ-Proteobacteria and Euryarchaeota respectively. Genes for aerobic and anaerobic alkane metabolism (alkB and bssA), methanogenesis (mcrA), denitrification (nirS and narG) and N2 fixation (nifH) were detected. Concomitant to hydrocarbon degradation, lowering of dissolve O2 and increase in oxidation-reduction potential (ORP) marked with an enrichment of N2 fixing, nitrate reducing aerobic/facultative anaerobic members [e.g., Azovibrio, Pseudoxanthomonas and Comamonadaceae members] was evident in N amended microcosm. This study highlighted that indigenous community of refinery sludge was intrinsically diverse, yet appreciable rate of in situ bioremediation could be achieved by supplying adequate N sources. PMID:27708623

Commissioning and startup of the Blind River uranium refinery

International Nuclear Information System (INIS)

Schisler, J.M.

1987-01-01

In the last five years Eldorado Resources Ltd. (ERL) has undergone a major expansion and modernization of its uranium refining and conversion plants. A new refinery for processing yellow cake to UO/sub 3/ was constructed at Blind River in northern Ontario and started up in 1983. Its rated capacity is 18,000 t/a uranium as UO/sub 3/. At Port Hope, Ontario, ERL's new UF/sub 6/ conversion plant has been constructed. This plant started up in 1984. It utilizes the novel, wet-way process to produce UF/sub 4/ and gives the company a UF/sub 6/ production capacity of 14,500 t/a U. Also at Port Hope is Eldorado's ceramic UO/sub 2/ powder production facility, commissioned in late 1980. It has a capacity of 1700 t/a uranium as UO/sub 2/. With the completion of these capital projects, Eldorado has the largest and most up-to-date refining and conversion facilities in the western world. This paper reviews the refining process and process design. The methodology used to start up the Blind River plant is described as are some startup difficulties, solutions that were developed, and the resultant current operation

Gasification of refinery sludge in an updraft reactor for syngas production

Energy Technology Data Exchange (ETDEWEB)

Ahmed, Reem; Eldmerdash, Usama [Department of Chemical Engineering, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak (Malaysia); Sinnathambi, Chandra M., E-mail: chandro@petronas.com.my [Fundamental and Applied Sciences Department, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak (Malaysia)

2014-10-24

The study probes into the investigation on gasification of dry refinery sludge. The details of the study includes; influence of operation time, oxidation temperature and equivalence ratios on carbon gas conversion rate, gasification efficiency, heating value and fuel gas yield are presented. The results show that, the oxidation temperature increased sharply up to 858°C as the operating time increased up to 36 min then bridging occurred at 39 min which cause drop in reaction temperature up to 819 °C. This bridging was found to affect also the syngas compositions, meanwhile as the temperature decreased the CO, H{sub 2}, CH{sub 4} compositions are also found to be decreases. Higher temperature catalyzed the reduction reaction (CO{sub 2}+C = 450 2CO), and accelerated the carbon conversion and gasification efficiencies, resulted in more solid fuel is converted to a high heating value gas fuel. The equivalence ratio of 0.195 was found to be the optimum value for carbon conversion and cold gas efficiencies, high heating value of gas, and fuel gas yield to reach their maximum values of 96.1 % and 53.7 %, 5.42 MJ Nm{sup −3} of, and 2.5 Nm{sup 3} kg{sup −1} respectively.

Gasification of refinery sludge in an updraft reactor for syngas production

International Nuclear Information System (INIS)

Ahmed, Reem; Eldmerdash, Usama; Sinnathambi, Chandra M.

2014-01-01

The study probes into the investigation on gasification of dry refinery sludge. The details of the study includes; influence of operation time, oxidation temperature and equivalence ratios on carbon gas conversion rate, gasification efficiency, heating value and fuel gas yield are presented. The results show that, the oxidation temperature increased sharply up to 858°C as the operating time increased up to 36 min then bridging occurred at 39 min which cause drop in reaction temperature up to 819 °C. This bridging was found to affect also the syngas compositions, meanwhile as the temperature decreased the CO, H 2 , CH 4 compositions are also found to be decreases. Higher temperature catalyzed the reduction reaction (CO 2 +C = 450 2CO), and accelerated the carbon conversion and gasification efficiencies, resulted in more solid fuel is converted to a high heating value gas fuel. The equivalence ratio of 0.195 was found to be the optimum value for carbon conversion and cold gas efficiencies, high heating value of gas, and fuel gas yield to reach their maximum values of 96.1 % and 53.7 %, 5.42 MJ Nm −3 of, and 2.5 Nm 3 kg −1 respectively

Optimum Design of Heat Exchangers Networks Part-2: case study: Atmospheric Crude Distillation Unit

International Nuclear Information System (INIS)

Gabr, E.M.A.; EI-Temtamy, S.A.; Deriasl, S.F.; Moustafa, H.A.

2004-01-01

In this paper the computerized framework introduced in part-I for Heat Exchanger Network Synthesis (HENS) with optimality conditions of achieving the least operating and capital cost has been applied on an industrial atmospheric distillation unit existing in one of the Egyptian refineries . The application includes two types of designing: grass-root and revamp of the existing design. For the final grass-root design, the saving of utilities is 50% of the actual consumption while the net annual saving reaches 2,193,690 S/year .For revamping of existing design the % saving of hot and cold utilities are 38.1% and 43.2% respectively and the annual saving of 1,723,104 $/year is achieved

Advanced oxidation processes for treatment of petroleum refinery sour waters; Processos oxidativos avancados para tratamento de aguas acidas de refinaria de petroleo

Energy Technology Data Exchange (ETDEWEB)

Castro, Antonio V.; Coelho, Alessandra D.; Sant' Anna Junior, Geraldo L.; Dezotti, Marcia [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Programa de Engenharia Quimica

2004-07-01

The characteristics of the waste water generated by the petroleum refineries are related to the type and amount of processed oil, to the nature and the efficiency of the refining operation. The effluents are composed basically of oily waters, originating from of the contact with the oil. Among them, the current of sour water is one of the most preoccupying due to its composition: sulfide, ammonia, mercaptans, phenol, dissolved oil, basic pH, dissolved organic carbon (DOC) and chemical oxygen demand (COD) high. The aim of this work was to evaluate the advanced oxidation processes to degrade sour water (UV radiation, H{sub 2}O{sub 2} and H{sub 2}O{sub 2}/UV, photocatalysis, Fenton and photo-Fenton). All process, except Fenton and photo-Fenton, did not supply satisfactory results, reducing 25% of initial DOC, which it is of 450 mg/L. The results using the Fenton process reached removal of 50% of the initial COD, and when photo- Fenton process obtaining removal of 90%. The processes Fenton and photo-Fenton were shown capable to degrade this kind of waste water, minimizing the environmental problems and corrosion, operating as a pre-treatment for the biological system, or acting alone to degrade the organic matter contained, seeking the water reuse. The effluent used in this work came from Duque de Caxias Refinery (Reduc)/PETROBRAS. (author)

Key outcomes from risk based assessment of pressure equipment in refineries

International Nuclear Information System (INIS)

Firth, D.; Lichti, K.; Hill, T.; Thomas, C.; Widrig, J.; Simmonds, G.; Karstensen, A.

2012-01-01

Risk based assessment (RBA) has become the best industry practice for management of pressure equipment reliability. Application of RBA programs significantly reduces risk and gives opportunity to optimize inspection programs and produce long term financial benefits. Quest Integrity Group have implemented risk based inspection programs n a variety of industries including ammonia, methanol, geothermal power, :combined cycle power, gas turbines, gas production facilities and refineries. This paper outlines the semi quantitative RBA procedures that have been followed and lists some of the specific technical outcomes. Advanced inspection and life assessment methods used in support of RBI in refineries ire discussed. Piping in refineries is a key risk issue and it is not uncommon for piping failures to result in major incidents. Specific inspection programs are available to monitor differing damage processes such as flow assisted corrosion, hydrogen damage and corrosion under insulation. During assessment it s often found that numerous pipes have never been inspected especially underground smaller diameter pipes which are frequently considered to be un-piggable using conventional technologies and difficult to inspect. Advanced high accuracy flexible miniaturized ultrasonic intelligent pigging combined with fitness for service assessment such as Invista TM is recommended for inspection of critical pipelines which previously have been un-piggable. The processing of crude oil from a range of sources can result in significant variations in the levels of contaminants such as chlorides and sulfides. Major failures have occurred as a result of very rapid increases in corrosion rates in hydrotreating processes due to rapid changes in chemistry. The outcome of the assessment of plants that have potentially high and variable levels of contaminants often results in a review the process chemistry, how it is monitored and development of a detailed corrosion monitoring program. Fired

Toward effective ecological risk-management of refinery corrective action

International Nuclear Information System (INIS)

Metzger, B.H.; Rury, P.M.; Turton, D.; Archibald, B.; Clark, J.; Cura, J.

1995-01-01

Cleanup of complex industrial sites, such as refineries, requires risk-based decision tools to ensure that environmentally protective remediation is consistent with current and future land use. However, conventional ecological risk assessment approaches are not well suited for complex industrial sites. Site risk assessments focus on hypothetical chemical risk assuming diverse and undisturbed ecosystems, rather than industrial and disturbed area conditions. In addition, they offer little guidance as to how to make timely and effective risk management decisions. An innovative methodology is proposed to assist industry and regulatory risk managers with rapid EcoRisk reconnaissance and cost-effective remedial decision-making at complex industrial sites. Phase 1 comprises a three-step risk screening of areas of ecological concern at the site, which integrates habitat quality characteristics and potential chemical hazards. It yields an ordering of areas as follows: areas of no significant risk; areas of potentially significant risk; and areas of likely significant risk. A decision rule is then applied to determine appropriate risk management action, including: no action; additional study; and remedial or management action. In Phase 2, additional study is conducted for areas that exhibit potentially significant risk so as to facilitate risk management. This methodology is currently being applied at the 1,300 acre, former Exxon Bayway Refinery in New Jersey

Cathodic Protection Design Algorithms for Refineries Aboveground Storage Tanks

Directory of Open Access Journals (Sweden)

Kosay Abdul sattar Majbor

2017-12-01

Full Text Available Storage tanks condition and integrity is maintained by joint application of coating and cathodic protection. Iraq southern region rich in oil and petroleum product refineries need and use plenty of aboveground storage tanks. Iraq went through conflicts over the past thirty five years resulting in holding the oil industry infrastructure behind regarding maintenance and modernization. The primary concern in this work is the design and implementation of cathodic protection systems for the aboveground storage tanks farm in the oil industry. Storage tank external base area and tank internal surface area are to be protected against corrosion using impressed current and sacrificial anode cathodic protection systems. Interactive versatile computer programs are developed to provide the necessary system parameters data including the anode requirements, composition, rating, configuration, etc. Microsoft-Excel datasheet and Visual Basic.Net developed software were used throughout the study in the design of both cathodic protection systems. The case study considered in this work is the eleven aboveground storage tanks farm situated in al-Shauiba refinery in southern IRAQ. The designed cathodic protection systems are to be installed and monitored realistically in the near future. Both systems were designed for a life span of (15-30 years, and all their parameters were within the internationally accepted standards.

Psidium guajava as a bioaccumulator of nickel around an oil refinery, southern Brazil.

Science.gov (United States)

Trindade Perry, Carolina; Divan, Armando Molina; Raya Rodriguez, Maria Teresa; Lúcia Atz, Vera

2010-05-01

To evaluate the potential of Psidium guajava as a biological accumulator of air pollutants, saplings were exposed at nine sites receiving atmospheric emissions from an oil refinery (five within, four outside the industrial area) and another reference site located at the Federal University of Rio Grande do Sul, 27 km from the refinery. Exposures lasted about 3 months each, coincided with the seasons, and totaled five exposures between 2005 and 2006. The following parameters were evaluated: dry weight of leaves, stems, and roots, leaf area, rate of relative height increase, Ni and S contents, maximum assimilation rate, and carboxylation efficiency invivo. P. guajava was found to be an efficient accumulator of Ni, since highly significant differences were observed (Pguajava is a good bioaccumulator for Ni. Copyright 2009 Elsevier Inc. All rights reserved.

Phase 1 remedial investigation report for 200-BP-1 operable unit

International Nuclear Information System (INIS)

1993-09-01

The US Department of Energy (DOE) Hanford Site, in Washington State is organized into numerically designated operational areas including the 100, 200, 300, 400, 600, and 1100 Areas. The US Environmental Protection Agency (EPA), in November 1989 included the 200 Areas of the Hanford Site on the National Priority List (NPL) under the Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA). Inclusion on the NPL initiated the remedial investigation (RD process for the 200-BP-1 operable unit. These efforts are being addressed through the Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1989) which was negotiated and approved by the DOE, the EPA, and the State of Washington Department of Ecology (Ecology) in May 1989. This agreement, known as the Tri-Party Agreement, governs all CERCLA efforts at Hanford. In March of 1990, the Department of Energy, Richland Operations (DOE-RL) issued a Remedial Investigation/Feasibility Study (RI/FS) work plan (DOE-RL 1990a) for the 200-BP-1 operable unit. The work plan initiated the first phase of site characterization activities associated with the 200-BP-1 operable unit. The purpose of the 200-BP-1 operable unit RI is to gather and develop the necessary information to adequately understand the risks to human health and the environment posed by the site and to support the development and analysis of remedial alternatives during the FS. The RI analysis will, in turn, be used by Tri-Party Agreement signatories to make a risk-management-based selection of remedies for the releases of hazardous substances that have occurred from the 200-BP-1 operable unit

South Africa's refineries: waiting for Maduna

International Nuclear Information System (INIS)

Anon.

1997-01-01

A definitive energy policy from the new Energy Minister, Penuell Maduna, is awaited by the petroleum industry in South Africa. Some of the complexities of the South African oil market and past legacies which make the task of producing a policy difficult, are examined here. They include the allegations made initially in 1994 that oil refineries are illegally repatriating profits by paying too much for imported products. Accusations of this transfer pricing have resurfaced in the light of recent figures published by the South African Petroleum Industry Association (SAPIA) which show that the oil industry's profitability is not as high as some had presumed. However, compelling evidence for the allegations has not appeared and it is unlikely that the foreign investors in SAPIA would endanger their operations in this way. SAPIA members are key investors in the national infrastructure and make large tax contributions much needed by the treasury. In its turn, SAPIA is unhappy about the continuation of the payment of large taxpayer funded subsidies to the privatised Sasol, the South African synthetic fuel company, seeing as anti-competitive and having negative implications for the national economy. For its part Sasol argues its entitlement to the same tariff protection enjoyed by 80% of local manufacturing industries in South Africa. Some government action has been taken to reduce the subsidies though. The oil companies in SAPIA require clarity on future energy policy and deregulation before committing themselves to further heavy capital investment and Sasol also requires an end to the present uncertainties. (UK)

Environmental Control Plan for the 300-FF-1 Operable Unit Remedial Action

International Nuclear Information System (INIS)

Carlson, R.A.

2000-01-01

This environmental control plan is for the 300-FF-1 Operable Unit Remedial Action Project. The purpose of this plan is to identify environmental requirements for the 300-FF-1 operable unit Remedial Action/Waste Disposal Project

Phase I remedial investigation report for the 300-FF-5 operable unit, Volume 1

Energy Technology Data Exchange (ETDEWEB)

NONE

1994-01-01

The focus of this remedial investigation (RI) is the 300-FF-5 operable unit, one of five operable units associated with the 300 Area aggregate of the U.S. Department of Energy`s (DOE`s) Hanford Site. The 300-FF-5 operable unit is a groundwater operable unit beneath the 300-FF-1, 300-FF-2, and 300-FF-3 source operable units. This operable unit was designated to include all contamination detected in the groundwater and sediments below the water table that emanates from the 300-FF-1, 300-FF-2, and 300-FF-3 operable units (DOE-RL 1990a). In November 1989, the U.S. Environmental Protection Agency (EPA) placed the 300 Area on the National Priorities List (NPL) contained within Appendix B of the National Oil and Hazardous Substance Pollution Contingency Plan (NCP, 53 FR 51391 et seq.). The EPA took this action pursuant to their authority under the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA, 42 USC 9601 et seq.). The DOE Richland Operations Office (DOE-RL), the EPA and Washington Department of Ecology (Ecology) issued the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement), in May 1989 (Ecology et al. 1992, Rev. 2). This agreement, among other matters, governs all CERCLA efforts at the Hanford Site. In June 1990, a remedial investigation/feasibility study (RI/FS) workplan for the 300-FF-5 operable unit was issued pursuant to the Tri-Party Agreement.

Phase I remedial investigation report for the 300-FF-5 operable unit, Volume 1

International Nuclear Information System (INIS)

1994-01-01

The focus of this remedial investigation (RI) is the 300-FF-5 operable unit, one of five operable units associated with the 300 Area aggregate of the U.S. Department of Energy's (DOE's) Hanford Site. The 300-FF-5 operable unit is a groundwater operable unit beneath the 300-FF-1, 300-FF-2, and 300-FF-3 source operable units. This operable unit was designated to include all contamination detected in the groundwater and sediments below the water table that emanates from the 300-FF-1, 300-FF-2, and 300-FF-3 operable units (DOE-RL 1990a). In November 1989, the U.S. Environmental Protection Agency (EPA) placed the 300 Area on the National Priorities List (NPL) contained within Appendix B of the National Oil and Hazardous Substance Pollution Contingency Plan (NCP, 53 FR 51391 et seq.). The EPA took this action pursuant to their authority under the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA, 42 USC 9601 et seq.). The DOE Richland Operations Office (DOE-RL), the EPA and Washington Department of Ecology (Ecology) issued the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement), in May 1989 (Ecology et al. 1992, Rev. 2). This agreement, among other matters, governs all CERCLA efforts at the Hanford Site. In June 1990, a remedial investigation/feasibility study (RI/FS) workplan for the 300-FF-5 operable unit was issued pursuant to the Tri-Party Agreement

40 CFR 80.295 - How is a refinery sulfur baseline determined?

Science.gov (United States)

2010-07-01

... of gasoline batch i. n = Total number of batches of gasoline produced during January 1, 1997 through... refinery, the total number of batches of gasoline produced and imported into the U.S. during January 1, 1997 through December 31, 1998, or, the total number of batches of gasoline produced and imported into...

Analysis of the sector petroleum refineries in energy scenarios for The Netherlands. Analyse van de sector raffinaderijen voor de Nationale Energie Verkenningen

Energy Technology Data Exchange (ETDEWEB)

Van Oostvoorn, F

1926-07-01

The calculations with regard to the oil sector in general and the petroleum refineries in particular of the energy scenarios for The Netherlands are described. Calculations have been made with the help of the energy models SELPE and SERUM, developed for the total energy scene of The Netherlands and the petroleum refineries respectively. The results of the calculations with respect to the petroleum refineries are compared. This resulted in adjustment of the parameters for the oil sector in the SELPE energy model and the consequences of these adjustments for the energy scenarios for The Netherlands. 3 figs., 15 tabs., 10 refs.

Waste Water Treatment Unit

International Nuclear Information System (INIS)

Ramadan, A.E.K.

2004-01-01

A wastewater treatment plant to treat both the sanitary and industrial effluent originated from process, utilities and off site units of the refinery is described. The purpose is to obtain at the end of the treatment plant, a water quality that is in compliance with contractual requirements and relevant environmental regulations. first treatment (pretreatment). Primary de-oiling, Equalization, Neutralization, Secondary de-oiling. Second treatment (Biological), The mechanism of BOD removal, Biological flocculation, Nutrient requirements, Nitrification, De-nitrification, Effect of temperature, Effect of ph, Toxicity

Sulphurfree diesel - modifications and experiences on a HDS-unit; Modifikationen und Betriebserfahrungen an einer Mitteldestillatentschwefelung

Energy Technology Data Exchange (ETDEWEB)

Reinhardt, J. [Veba Oel-Verarbeitungs-GmbH, Gelsenkirchen (Germany); Balfanz, U. [Aral Forschung FDT, Gelsenkirchen (Germany); Dimmig, T. [TU Bergakademie Freiberg (Germany)

2002-10-01

Ruhr Oel GmbH, a joint venture between BP and PDVSA, is operating a HDS-unit at their facilities at Gelsenkirchen-Scholven. The product of this unit is a major blend component for Diesel fuel. Driven by ambitious German environmental policy and by an agreement between the German car and oil industry on the one side and the government on the other side, more stringent low sulphur fuels will be introduced in Germany much earlier than in the rest of the European Union. In view of this background a project was developed to realise the new product specifications with minimum investment. In cooperation between the refinery, company research facilities and the catalyst supplier (AKZO NOBEL), pilot plant test were performed to find out the best catalyst system and the new process conditions. Based on this, an existing HDS-unit was revamped. After the revamp, the unit produce Diesel fuel with 50 ppm sulphur content, test runs for 10 ppm were carried out successfully. These results were demonstrated in this article. (orig.)

Control system design for the deethanizer absorber tower pressure in the light end unit of the Nico Lopez refinery; Diseno del sistema de control para la presion en la torre absorvedora deetanizadora de la unidad de finales ligeros de la refineria Nico Lopez

Energy Technology Data Exchange (ETDEWEB)

Morales Corral, Camilo [Refineria Nico Lopez, Ciudad Habana (Cuba)]. E-mail: Camilo.morales@refhab.cupet.cu; Pedre Mendoza, Isabel [DAISA, Ciudad Habana (Cuba)]. E-mail: Isabel@daisa.copextel.com.cu; Garcini Leal, Hector J. [Instituto Superior Politecnico Jose A. Echeverria, La Habana (Cuba)]. E-mail: garcini,novi@electrica.cujae.edu.cu; Fernandez, Luis M. [Instituto de Cibernetica, Matematica y Fisica, La Habana (Cuba)]. E-mail: luis@icmf.inf.cu; Benitez Gonzalez, Ivon Oristela [Instituto Superior Politecnico Jose A. Echeverria, La Habana (Cuba)

2010-11-15

This paper is about pressure feed forward control. It is for an absorber tower of the Light End Unit. This one is in the Havana Oil Refinery. Control loop was designed using identification technic and simulation software. Moreover the design control loop has been validated and his quality has been determined. [Spanish] En el presente trabajo se aborda un control anticipatorio de presion. Fue desarrollado para la torre absorvedora de la Unidad de Finales Ligeros. La cual pertenece a la refineria de La Habana. Fue disenado un lazo de control empleando tecnicas de identificacion y programas de simulacion. Ademas el lazo disenado es validado y se determina su calidad.

Preparation status for continuous operation of Kori unit 1 NPP in Korea

International Nuclear Information System (INIS)

Choi, C.H. . E-mail : chechee@khnp.co.kr

2005-01-01

Kori unit 1 Nuclear Power Plant is the first commercial operation plant in Korea. In Korea, the life extension of NPP beyond design lifetime reached practically application stage. Preparations status for continuous operation of Kori unit 1, Many researches have demonstrated that life extension beyond design lifetime is possible in terms of technology. This paper is to introduce and to share the continuous operation preparations status and schedule for Kori unit 1 License Renewal Process an additional every 10 years beyond the design life 30 years term. (author)

Biblis 1,300 MW unit B in operation for thirty years

International Nuclear Information System (INIS)

Lauer, H.

2006-01-01

Over the past thirty years, unit B of the Biblis nuclear power station has contributed towards safe, reliable and non-polluting electricity generation. Unit B was the first 1,300 MW unit in the world confirming the good experience accumulated in the construction and operation of plants this size. It laid the foundation for the advanced development of nuclear power plants up to the convoy line. The good availability this plant has achieved in its operating cycles proves the mature state of technology and the high level of qualification and motivation of the power plant staff and the personnel of external firms contracted to work for Biblis. Biblis B has served as a reference plant in German nuclear safety research, demonstrating that units this size can be operated safely. Unit B is also living proof of the possibility to raise nuclear power plants built in the seventies to the current state of the art by implementing the appropriate backfitting and modernization measures. Today, Biblis B is operated at a safety level clearly higher than that to be achieved for new plants internationally. This is also evident from comparison with the guiding values for the safety of new facilities as published by the International Atomic Energy Agency (IAEA). (orig.)

The role of transnational companies as oil suppliers to the United States

International Nuclear Information System (INIS)

Palazuelos, Enrique

2010-01-01

This paper analyzes the extent to which the international oil production of transnational companies meets the oil requirements of the United States. Disaggregated data from each company have been used to determine which companies (refineries) are importing crude oil, how much oil each transnational company is produced abroad, and where this production goes to. The analysis show that American international oil production represents a small part of U.S. oil imports. Two conclusions are reached. The first is that U.S. refineries buy the majority of the crude oil they process on the international market and, as a result, are dependent on the unstable conditions of this market. The second is that the economic interests the large American oil companies have abroad are far greater than those they have within the United States and, as a result, these companies do not play a decisive role in a national strategy to guarantee foreign supply.

Methodology for determination of the operational limits in a atmospheric oven as a function of the load characteristics; Metodologia para determinacao dos limites operacionais de um forno atmosferico em funcao das caracteristicas da carga

Energy Technology Data Exchange (ETDEWEB)

Mundstock, Rene [Refinaria Alberto Pasqualini (REFAP), Canoas, RS (Brazil); Correa, Eduardo Coelho [PETROBRAS, Rio de Janeiro, RJ (Brazil)

2000-07-01

The necessity of increasing the crude processing with operation periods even greater, are resulting in Atmospheric Distillation Units in severe conditions, requiring even more rigorous operational procedures. The crude fired heaters are the critical equipment in this context, because they are the most susceptible to failures, if some determined limits are exceeded. This work was originated from the tube failure analysis of the fired heater F-101 of Alberto Pasqualini Refinery (REFAP), occurred in july/98, due to internal cocking, with unit emergency shut-down. During this analysis, it was verified that the operational limit of a fired heater cannot be determined only by its design thermal duty, it must be also taken into account the influence of the crude composition. This will determine, due to its film coefficient, the region of the radiation zone of the fired heater where it will begin the crude vaporization and will occur the greater temperatures. The work conclusions resulted on the revision of the Unit operational procedures and definition of new crude processing limits. The fired heater operates with no problems since then. (author)

Expert system for operational personnel support during power unit operation control in regulation range

International Nuclear Information System (INIS)

Yanitskij, V.A.

1992-01-01

The problems met when developing the systems for NPP operator support in the process of power unit operation are considered. The expert system for NPP personnel intelligent support combining the properties belonging to the artificial intelligence systems including selection of the analysis method taking into account the concrete technological situation and capability of application of algothmic calculations of the equipment characteristics using the information accumulated during the system development, erection and operation is described

Bioproducts for Sludge Reduction in Activated Sludge Systems Treating Oil Refinery Wastewater

Directory of Open Access Journals (Sweden)

Alexandre V.M.F.

2016-03-01

Full Text Available The use of bioproducts that change the cellular metabolism and reduce microbial growth without affecting the organic matter removal is very promising for reducing the amount of sludge in wastewater treatment systems. In this study, two bioproducts were evaluated and compared with a well-known chemical (2,4-DiNitroPhenol – DNP in activated sludge treating petroleum refinery wastewater. In batch experiments, 10 mg/L of DNP, 0.8 mg/L of a bioproduct based on Folic Acid (FA and 10 mg/L of a bioproduct based on Stress Proteins (SP led to 30.6%, 43.2% and 29.8% lower disposal of total solids, respectively. Operating on a continuous regimen, the addition of 10 mg/L of the bioproduct based on SP led to 45.7% lower disposal for 50 days. In all cases, no loss of efficiency in the Chemical Oxygen Demand (COD removal was observed.

Yearly refinery construction indexes listed for 68 years

International Nuclear Information System (INIS)

Farrar, G.

1996-01-01

Yearly values are presented for the Nelson-Farrar refinery inflation cost index since 1926. They are based on 1946 as 100, since that was the date of index inception. Values from 1926 to 1945 were back calculated. Data are presented on indexed cost of materials, labor, and miscellaneous equipment for 1926 through 1994. A second table of itemized refining cost indexes for the years 1954, 1972, 1992--1994, and the first eight months of 1995 is also presented. This table subdivides materials, labor, and equipment into component costs

Rationalization of imports, refineries and distribution of petroleum in Sub-Saharan Africa

International Nuclear Information System (INIS)

Mayorga Alba, E.

1993-01-01

This paper outlines policies to secure and reduce the cost of oil supplies in Sub-Saharan Africa (SSA), taking into account the existing forces at play: limited foreign exchange, competition for increasingly scarce funds, and the likely emergence of Africa as the fastest growing centre of energy demand over the coming decade. It identifies major inefficiencies in petroleum procurement, refining and distribution, and analyses the specific bottlenecks at each stage of the supply chain. Many of the diseconomies, estimated to yield savings of US$ 1.4 per year, are traced to an inefficient regulatory set-up in SSA countries, as well as unnecessary government interference in the downstream petroleum sector. In particular, price controls, small topping refineries, monopolistic agencies, government subsidies and opaque management structures prevent the working of efficient market mechanisms. The paper discusses the importance of policy reform, outlining what changes need to be implemented on the levels of institutional arrangements, closing of inefficient units, petroleum pricing and encouraging foreign investment in the sector. (author). 1 ref., 7 figs

Stability Analysis for Operation of DG Units in Smart Grids

DEFF Research Database (Denmark)

Pouresmaeil, Edris; Shaker, Hamid Reza; Mehrasa, Majid

2015-01-01

This paper presents a multifunction control strategy for the stable operation of Distributed Generation (DG) units during grid integration. The proposed control model is based on Direct Lyapunov Control (DLC) theory and provides a stable region for the appropriate operation of DG units during grid....... Application of this concept can guarantee to reduce the stress on the grid during the energy demand peak. Simulation results are presented to demonstrate the proficiency and performance of the proposed DLC technique in DG technology....

Implementation of Active Learning Method in Unit Operations II Subject

OpenAIRE

Ma'mun, Sholeh

2018-01-01

ABSTRACT: Active Learning Method which requires students to take an active role in the process of learning in the classroom has been applied in Department of Chemical Engineering, Faculty of Industrial Technology, Islamic University of Indonesia for Unit Operations II subject in the Even Semester of Academic Year 2015/2016. The purpose of implementation of the learning method is to assist students in achieving competencies associated with the Unit Operations II subject and to help in creating...

Decommissioning strategy of the operating WWER type units in the Ukraine

International Nuclear Information System (INIS)

Litvinsky, L.L.; Lobach, Yu.N.; Skripov, A.E.

2002-01-01

At present in Ukraine, 13 WWER type units are in operation and two other ones are in the final stage of construction. Decommissioning of these units is expected after the year 2010. General planning of their decommissioning is developed in the framework of the decommissioning strategy of operating WWER type units. The strategy contains the objectives, principles and main tasks of the decommissioning as well as the activities at each phase of decommissioning. It is considered a broad range of factors important for the planning and implementation of decommissioning. (author)

Refinery Integration of By-Products from Coal-Derived Jet Fuels

Energy Technology Data Exchange (ETDEWEB)

Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2006-09-17

This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO

Combined environmental impacts from production and use of the products. An EIS-application project for refineries; Sammanvaegd miljoepaaverkan fraan produktion och anvaendning av produkterna. Ett MKB-tillaempningsprojekt foer raffinaderier

Energy Technology Data Exchange (ETDEWEB)

Kindbom, K; LoevbIad, G.; Stripple, H.

2001-12-01

At European refineries a change in production is planned in order to obtain better qualities of gasoline and diesel, from an environmental point of view. This change will, however, lead to higher emissions at the refineries. The present study of the combined effects of emissions at the refineries and the use of the products gives the opportunity for considering the entire system and gives a stronger positive signal than the traditional EIS would do. Three different methods were used: Net change in emissions to air; Exposure of men and ecosystems for air pollutants; and Exceeding norms and critical levels. The results for the Swedish refinery at Lysekil shows that the emissions from using the products are much higher than the emissions from the refinery for all cases studied. The net emissions from production and use of the products will be reduced for the new products compared to the present situation. Risks for exceeding norms and critical levels due to the changes at the refinery exist for emissions of sulfur and nitrogen oxides, but a lower background load will probably mean that the total future load will be reasonably close to the critical level in the area affected by the refinery. In the urban environment, reduced risks for exceeding the levels for benzen and low levels for toluene and xylene give greater advantages than the increased emissions of sulfur and nitrogen close to the refinery.

Preparing nuclear power plant units for operation

International Nuclear Information System (INIS)

Hudcovic, R.; Telgarsky, K.; Kmosena, J.

1984-01-01

The factors are listed which have to be taken into consideration for planning the unit operation, i.e., the implementation of planned repairs, checks of equipment and refuellings. All basic input data were evaluated as the basic for drawing up the schedule of routine repairs and overhauls for the coming period. (E.S.)

Effect of Novi Sad oil refinery bombardment and fires on soil properties in Vojvodina province

International Nuclear Information System (INIS)

Sekulic, P.; Ralev, J.; Zeremski-Skoric, T.

2002-01-01

The bombing of the Novi Sad Oil Refinery in 1999 has lead to soil pollution by the products of burning oil and oil derivatives. These products were first carried by winds to the Rimski Sancevi Experiment Field of the Institute of Field and Vegetable Crops (located in the vicinity of the Novi Sad Oil Refinery), where they entered the soil via precipitation. Later, they spread to the city of Novi Sad, its vicinity, and the whole of the Vojvodina province, contaminating the soil. In the present study, we examined the extent to which this soil had been polluted. In 1999, we began to study the level of soil contamination at the Institute's Experiment Field at Rimski Sancevi. In 2000, we carried out the same kind of study in and around the city of Novi Sad, while in 2001 we expanded the study to the whole of Vojvodina. The studies' findings show that the soil reaction has not changed and that the levels of heavy metals in the soil have not exceeded the maximum tolerable concentration (MTC). The presence of PAHs at various concentrations was detected, however. This presence is a result of the fires at the Novi Sad Oil Refinery. (author)

Steam explosion and its combinatorial pretreatment refining technology of plant biomass to bio-based products.

Science.gov (United States)

Chen, Hong-Zhang; Liu, Zhi-Hua

2015-06-01

Pretreatment is a key unit operation affecting the refinery efficiency of plant biomass. However, the poor efficiency of pretreatment and the lack of basic theory are the main challenges to the industrial implementation of the plant biomass refinery. The purpose of this work is to review steam explosion and its combinatorial pretreatment as a means of overcoming the intrinsic characteristics of plant biomass, including recalcitrance, heterogeneity, multi-composition, and diversity. The main advantages of the selective use of steam explosion and other combinatorial pretreatments across the diversity of raw materials are introduced. Combinatorial pretreatment integrated with other unit operations is proposed as a means to exploit the high-efficiency production of bio-based products from plant biomass. Finally, several pilot- and demonstration-scale operations of the plant biomass refinery are described. Based on the principle of selective function and structure fractionation, and multi-level and directional composition conversion, an integrated process with the combinatorial pretreatments of steam explosion and other pretreatments as the core should be feasible and conform to the plant biomass refinery concept. Combinatorial pretreatments of steam explosion and other pretreatments should be further exploited based on the type and intrinsic characteristics of the plant biomass used, the bio-based products to be made, and the complementarity of the processes. Copyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Assessment of sludges and tank bottoms treatment processes

International Nuclear Information System (INIS)

Bhutto, A.W.; Bazmi, A.A.

2005-01-01

The petroleum refining industries generate considerable amounts of sludge and tank bottoms as waste. Petroleum refinery receives crude oil containing emulsified water and solids. As the crude oil storage tanks are repeatedly filled and emptied, the water and solids settle towards the bottom as sludge. For tanks that have been in service for several years, the sludge accumulation becomes several feet deep, results in a loss of ullage in refinery crude storage tanks. The accumulation of crude storage tank bottoms is a serious problem experienced by local refineries. The refinery sludge waste is categorized as hazardous waste, which is at present buried in the tankform ground. Since the no hazardous material land filling option available, the disposal of these hazardous materials has become a major problem because of the ISO-14000 certification requirements and expectation of stakeholder. To maximize the waste oil recovery from sludge and tank bottoms and to minimize the volume of the hazardous waste, a number of waste recovery and treatment processes are available. The process designs and unit operations of each process are different and each has its own merits, in terms of the technical complexity, operation friendliness, and costs and economics. A study on each of these technologies and the subsequent tide-up to the existing unit operations is conducted, and the associated technical comparisons are made. (author)

Nurse managers' decision-making in daily unit operation in peri-operative settings: a cross-sectional descriptive study.

Science.gov (United States)

Siirala, Eriikka; Peltonen, Laura-Maria; Lundgrén-Laine, Heljä; Salanterä, Sanna; Junttila, Kristiina

2016-09-01

To describe the tactical and the operational decisions made by nurse managers when managing the daily unit operation in peri-operative settings. Management is challenging as situations change rapidly and decisions are constantly made. Understanding decision-making in this complex environment helps to develop decision support systems to support nurse managers' operative and tactical decision-making. Descriptive cross-sectional design. Data were collected from 20 nurse managers with the think-aloud method during the busiest working hours and analysed using thematic content analysis. Nurse managers made over 700 decisions; either ad hoc (n = 289), near future (n = 268) or long-term (n = 187) by nature. Decisions were often made simultaneously with many interruptions. Ad hoc decisions covered staff allocation, ensuring adequate staff, rescheduling surgical procedures, confirmation tangible resources and following-up the daily unit operation. Decisions in the near future were: planning of surgical procedures and tangible resources, and planning staff allocation. Long-term decisions were: human recourses, nursing development, supplies and equipment, and finances in the unit. Decision-making was vulnerable to interruptions, which sometimes complicated the managing tasks. The results can be used when planning decision support systems and when defining the nurse managers' tasks in peri-operative settings. © 2016 John Wiley & Sons Ltd.

Industrial wastewater reuse in petroleum refinery using the WSD for regeneration systems

Directory of Open Access Journals (Sweden)

Lídia Yokoyama

2011-12-01

Full Text Available Wastewater reuse practices in the industry require an adequate understanding of the characteristics of the manufacture processes, to minimize the water consumption and the generation of effluent. The objective of this work was to apply the WSD method, used to defining the target of minimum process water consumption in a case study of oil refinery, by means of the reuse and recycling operations, including regeneration processes. The importance and influence of the wastewater treatment plant in the regeneration quality, including intermediate process streams, for the reuse and the recycling operations, were evaluated. Furthermore, centralized and distributed treatment flowsheet configurations were tested. Thus, this work presented the solution of a case study with three contaminants in water streams processes, different interconnections approaches, used to illustrate the application of this procedure showing the reduction of water flow rate and total costs compared to the original flowsheet. The scenarios revealed to be greatly promising, and flowsheet configurations were reached with higher than 4 % and 20 % of reduction in the water flow rate consumption and the total costs, respectively. Regarding the ecoefficiency processes, the results demonstrate that the applied technique is successful when the minimum water consumption is the main goal in the industry.

Report of fiscal 1999 basic survey for joint implementation, etc. Feasibility study on energy conservation and reduction of CO2 emission at Omsk Refinery

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

This paper explains fiscal 1999 survey on energy conservation and reduction of CO2 at Omsk Refinery in the Russian Federation for the purpose of making the project tied to the COP3 joint implementation. This refinery is the largest class refinery in Russia having a capacity of 600,000 BPSD. The atmospheric distillation unit AVT-10, which emits 470,000 t-CO2/year, was selected for the object of the survey. As the modification plans, optimization of process system, modification of waste heat boiler and installation of new furnaces were considered. The plans 1, 2 are possible due to their low investment costs. The plan 3 to install new furnaces is able to reduce the large volume of CO2 emission though its investment cost is higher. For each modification plan, estimation was made for the investment cost, the benefit by energy saving and the volume of reduction of CO2 emission. The results for each of the plans 1, 2 and 3 were 907x10{sup 3}, 3,377x10{sup 3}, 50,400x10{sup 3} in US$; 535x10{sup 3}, 928x10{sup 3}, 1,407x10{sup 3} in US$; and 36.1x10{sup 3}, 68.2x10{sup 3}, 86.6x10{sup 3} tons/year. The Russian side showed their satisfaction of the results and keen interest in the energy saving effect. For the purpose of realizing this plan, financial assistance and technological cooperation are essential. Russia shows their great expectations for the Japanese government. (NEDO)

Induced bioelectrochemical metabolism for bioremediation of petroleum refinery wastewater: Optimization of applied potential and flow of wastewater.

Science.gov (United States)

Mohanakrishna, Gunda; Al-Raoush, Riyadh I; Abu-Reesh, Ibrahim M

2018-07-01

Hybrid based bioelectrochemical system (BES) configured with embedded anode and cathode electrodes in soil was tested for the bioelectrochemical degradation of petroleum refinery wastewater (PRW). Four applied potentials were studied to optimize under batch mode operation, among which 2 V resulted in higher COD degradation (69.2%) and power density (725 mW/m 2 ) during 7 days of operation. Further studies with continuous mode of operation at optimized potential (2 V) showed that hydraulic retention time (HRT) of 19 h achieved the highest COD removal (37%) and highest power density (561 mW/m 2 ). BES function with respect to treatment efficiencies of other pollutants of PRW was also identified with respect to oil and grease (batch mode, 91%; continuous mode, 34%), total dissolved salts (batch mode, 53%; continuous mode, 24%) and sulfates (batch mode, 59%; continuous mode, 42%). Soil microenvironment in association with BES forms complex processes, providing suitable conditions for efficient treatment of PRW. Copyright © 2018 Elsevier Ltd. All rights reserved.

Feasibility study on reduction of greenhouse gas emissions at Thanlyin oil refinery by the modernization of existing facilities

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

The feasibility study was conducted on a project in Myanmar for the energy saving effect and reduction of the greenhouse gas emissions by introducing modern refining facilities in Thanlyin Refinery of Myanmar Petrochemical Enterprise. The project items selected as a result of the study are improvement in the heat recovery efficiency of crude distillation unit, improvement in the furnace efficiency of crude distillation unit and coker plant, improvement in the efficiency of power plant, reduction of steam loss, modernization of the cooling water system, recovery and reuse of off-gas and LPG in crude distillation unit, and modernization of intermediate products run-down system. The conceptual designs and studies on these items indicate that implementation of these projects could lead to energy saving of 25,844 tons/y as crude and CO2 emission abatement of 57,457 tons/y, 46% and 33% reduction from the baseline. The total expenses for all of these items are estimated at 4,300 million yen. These are judged to be promising projects, with estimated investment recovery period of 9 years and internal profit rate of 12.9%, when the special yen loans are available. (NEDO)

Prospects and requirements for an operational modelling unit in flood crisis situations

Directory of Open Access Journals (Sweden)

Anders Katharina

2016-01-01

Full Text Available Dike failure events pose severe flood crisis situations on areas in the hinterland of dikes. In recent decades the importance of being prepared for dike breaches has been increasingly recognized. However, the pre-assessment of inundation resulting from dike breaches is possible only based on scenarios, which might not reflect the situation of a real event. This paper presents a setup and workflow that allows to model dike breachinduced inundation operationally, i.e. when an event is imminent or occurring. A comprehensive system setup of an operational modelling unit has been developed and implemented in the frame of a federal project in Saxony-Anhalt, Germany. The modelling unit setup comprises a powerful methodology of flood modelling and elaborated operational guidelines for crisis situations. Nevertheless, it is of fundamental importance that the modelling unit is instated prior to flood events as a permanent system. Moreover the unit needs to be fully integrated in flood crisis management. If these crucial requirements are met, a modelling unit is capable of fundamentally supporting flood management with operational prognoses of adequate quality even in the limited timeframe of crisis situations.

Purification and detoxification of petroleum refinery wastewater by electrocoagulation process.

Science.gov (United States)

Gousmi, N; Sahmi, A; Li, H Z; Poncin, S; Djebbar, R; Bensadok, K

2016-09-01

The treatment of synthetic oily wastewater having the characteristics of a typical petroleum refinery wastewater (PRW) by electrocoagulation (EC) using iron and aluminum electrodes was conducted in an electrolytic reactor equipped with fluid recirculation. During the treatment, the emulsion stability was followed by the measurement of Zeta potential and particle sizes. Effects of some operating conditions such as electrodes material, current density and electrolysis time on removal efficiencies of turbidity, and chemical oxygen demand (COD) were investigated in detail. The PRW purification by the EC process was found to be the most effective using aluminum as the anode and cathode, current density of 60 A/m(2) and 30 min of electrolysis time. Under these conditions, the process efficiencies were 83.52% and 99.94%, respectively, for COD and turbidity removals which correspond to final values of 96 mg O2/L and 0.5 NTU. A moderate energy consumption (0.341 kWh) was needed to treat 1 m(3) of PRW. Besides, the ecotoxicity test proved that toxic substances presented in the PRW, and those inhibiting the germination growth of whet, were eliminated by the EC technique.

77 FR 62247 - Dynamic Positioning Operations Guidance for Vessels Other Than Mobile Offshore Drilling Units...

Science.gov (United States)

2012-10-12

... Operations Guidance for Vessels Other Than Mobile Offshore Drilling Units Operating on the U.S. Outer... ``Mobile Offshore Drilling Unit Dynamic Positioning Guidance''. The notice recommended owners and operators of Mobile Offshore Drilling Units (MODUs) follow Marine Technology Society (MTS) Dynamic Positioning...

Thunderstorm Algorithm for Determining Unit Commitment in Power System Operation

Directory of Open Access Journals (Sweden)

Arif Nur Afandi

2016-12-01

Full Text Available Solving the unit commitment problem is an important task in power system operation for deciding a balanced power production between various types of generating units under technical constraints and environmental limitations. This paper presents a new intelligent computation method, called the Thunderstorm Algorithm (TA, for searching the optimal solution of the integrated economic and emission dispatch (IEED problem as the operational assessment for determining unit commitment. A simulation using the IEEE-62 bus system showed that TA has smooth convergence and is applicable for solving the IEED problem. The IEED’s solution is associated with the total fuel consumption and pollutant emission. The proposed TA method seems to be a viable new approach for finding the optimal solution of the IEED problem.

Optimal operation of cogeneration units. State of art and perspective

International Nuclear Information System (INIS)

Polimeni, S.

2001-01-01

Optimal operation of cogeneration plants and of power plant fueling waste products is a complex challenge as they have to fulfill, beyond the contractual obligation of electric power supply, the constraints of supplying the required thermal energy to the user (for cogeneration units) or to burn completely the by-products of the industrial complex where they are integrated. Electrical power market evolution is pushing such units to a more and more volatile operation caused by uncertain selling price levels. This work intends to pinpoint the state of art in the optimization of these units outlining the important differences among the different size and cycles. The effect of the market liberalization on the automation systems and the optimization algorithms will be discussed [it

A geoprocessing model for the selection of populations most affected by diffuse industrial contamination: the case of oil refinery plants

Directory of Open Access Journals (Sweden)

Roberto Pasetto

2013-03-01

Full Text Available INTRODUCTION. A method to select populations living in areas affected by diffuse environmental contamination is presented, with particular regard to oil refineries, in the Italian context. The reasons to use municipality instead of census tract populations for environment and health small-area studies of contaminated sites are discussed. METHODS. Populations most affected by diffuse environmental contamination are identified through a geoprocessing model. Data from the national census 2001 were used to estimate census tract level populations. A geodatabase was developed using the municipality and census tract layers provided by the Italian National Bureau of Statistics (ISTAT. The orthophotos of the Italian territory - year 2006 - available on the geographic information systems (GIS of the National Cartographic Portal, were considered. The area within 2 km from the plant border was used as an operational definition to identify the area at major contamination. RESULTS. The geoprocessing model architecture is presented. The results of its application to the selection of municipality populations in a case study are shown. CONCLUSIONS. The application of the proposed geoprocessing model, the availability of long time series of mortality and morbidity data, and a quali-quantitative estimate of contamination over time, could allow an appraisal of the health status of populations affected by oil refinery emissions.

Data reconciliation and optimal operation of a Catalytic naphtha reformer

Directory of Open Access Journals (Sweden)

Tore Lid

2008-10-01

Full Text Available The naphtha reforming process converts low-octane gasoline blending components to high-octane components for use in high-performance gasoline fuels. The reformer also has an important function as the producer of hydrogen to the refinery hydrotreaters. A process model based on a unit model structure, is used for estimation of the process condition using data reconciliation. Measurements are classified as redundant or non redundant and the model variables are classified as observable, barely observable or unobservable. The computed uncertainty of the measured and unmeasured variables shows that even if a variable is observable it may have a very large uncertainty and may thereby be practically unobservable. The process condition at 21 data points, sampled from two years of operation, was reconciled and used to optimize the process operation. There are large seasonal variations in the reformer product price and two operational cases are studied. In case 1, the product price is high and throughput is maximized with respect to process and product quality constraints. In case 2, the product price is low and the throughput is minimized with respect to a low constraint on the hydrogen production. Based on the characteristics of the optimal operation, a "self optimizing" control structure is suggested for each of the two operational cases.

Conceptual design and techno-economic evaluation of efficient oil shale refinery processes ingratiated with oil and gas products upgradation

International Nuclear Information System (INIS)

Yang, Qingchun; Qian, Yu; Zhou, Huairong; Yang, Siyu

2016-01-01

Highlights: • Three integrated oil shale refinery processes are proposed. • Techno-economic performance of three proposed processes is conducted and compared. • Competitiveness of the three proposed processes is investigated at different scenarios. • A development direction for oil shale refinery industry is suggested. - Abstract: Compared with the petrochemical industry, oil shale refinery industry is still relatively backward and has many shortcomings, such as poor quality of shale oil, inefficient utilization of retorting gas, and the unsatisfactory economic performance. In the situation of the low oil price, many oil shale refinery plants are forced to stop or cut production. Thus, oil shale industry is facing a severe problem. How to relieve monetary loss or turn it into profits? This paper proposes three integrated oil shale refinery processes: an integrated with hydrogen production from retorting gas, an integrated with hydrogenation of shale oil, and an integrated with hydrogen production and oil hydrogenation. The techno-economic performance of the three different processes is conducted and compared with that of a conventional oil shale process. Results show the exergy destruction ratio of the oil shale process integrated with hydrogen production from retorting gas is the least, 41.6%, followed by the oil shale process integrated with hydrogen production and oil hydrogenation, 45.9%. Furthermore, these two proposed processes have the best economic performance. Especially they can turn losses of the conventional oil shale process into profits at the situation of low oil price. The oil shale process integrated with hydrogen production from retorting gas is recommended to the oil shale plants which use the oil shale with oil content lower than 12.9%, while the plants using oil shale with oil content higher than 12.9% are better to select the oil shale process integrated with hydrogen production and oil hydrogenation.

Model-centered approach to early planning and design of an eco-industrial park around an oil refinery.

Science.gov (United States)

Zhang, Xiangping; Strømman, Anders H; Solli, Christian; Hertwich, Edgar G

2008-07-01

Industrial symbiosis promises environmental and economic gains through a utilization of the waste of some processes as a resource for other processes. Because of the costs and difficulties of transporting some wastes, the largest theoretical potential for industrial symbiosis is given when facilities are colocated in an eco-industrial park (EIP). This study proposes a model-centered approach with an eight-step procedure for the early planning and design of an eco-industrial park considering technical and environmental factors. Chemical process simulation software was used to model the energy and material flows among the prospective members and to quantify the benefits of integration among different firms in terms of energy and resources saved as compared to a reference situation. Process simulation was based on a combination of physical models of industrial processes and empirical models. The modeling allows for the development and evaluation of different collaboration opportunities and configurations. It also enables testing chosen configurations under hypothetical situations or external conditions. We present a case study around an existing oil and gas refinery in Mongstad, Norway. We used the approach to propose the colocation of a number of industrial facilities around the refinery, focused on integrating energy use among the facilities. An EIP with six main members was designed and simulated, matching new hypothetical members in size to the existing operations, modeling material and energy flows in the EIP, and assessing these in terms of carbon and hydrogen flows.

Analysis of Fukushima unit 2 accident considering the operating conditions of RCIC system

Energy Technology Data Exchange (ETDEWEB)

Kim, Sung Il, E-mail: sikim@kaeri.re.kr; Park, Jong Hwa; Ha, Kwang Soon; Cho, Song-Won; Song, JinHo

2016-03-15

Highlights: • Fukushima unit 2 accident was analyzed using MELCOR 1.8.6. • RCIC operating conditions were assumed and best case was selected. • Effect of RCIC operating condition on accident scenario was found. - Abstract: A severe accident in Fukushima occurred on March 11, 2011 and units 1, 2 and 3 were damaged severely. A tsunami following an earthquake made the supply of electricity power stop, and the safety systems, which use AC or DC power in plants could not operate properly. It is supposed that the degree of core degradation of unit 2 is less serious than in the other plants, and it was estimated that the operation of reactor core isolation cooling (RCIC) system at the initial stage of the accident minimized the core damage through decay heat removal. Although the operating conditions of the RCIC system are not known clearly, it can be important to analyze the accident scenario of unit 2. In this study, best case of the Fukushima unit 2 accident was presented considering the operating conditions of the RCIC system. The effects of operating condition on core degradation and fission product release rate to environment were also examined. In addition, importance of torus room flooding level in the accident analysis was discussed. MELCOR 1.8.6 was used in this research, and the geometries of plant and operating conditions of safety system were obtained from TEPCO through OECD/NEA BSAF Project.

Structural characterization and condition for measurement statistics preservation of a unital quantum operation

International Nuclear Information System (INIS)

Lee, Kai-Yan; Fung, Chi-Hang Fred; Chau, H F

2013-01-01

We investigate the necessary and sufficient condition for a convex cone of positive semidefinite operators to be fixed by a unital quantum operation ϕ acting on finite-dimensional quantum states. By reducing this problem to the problem of simultaneous diagonalization of the Kraus operators associated with ϕ, we can completely characterize the kinds of quantum states that are fixed by ϕ. Our work has several applications. It gives a simple proof of the structural characterization of a unital quantum operation that acts on finite-dimensional quantum states—a result not explicitly mentioned in earlier studies. It also provides a necessary and sufficient condition for determining what kind of measurement statistics is preserved by a unital quantum operation. Finally, our result clarifies and extends the work of Størmer by giving a proof of a reduction theorem on the unassisted and entanglement-assisted classical capacities, coherent information, and minimal output Renyi entropy of a unital channel acting on a finite-dimensional quantum state. (paper)

Ground based measurements of SO2 and NO2 emissions from the oil refinery 'la Teja' in Montevideo city

International Nuclear Information System (INIS)

Frins, Erna; Casaballe, Nicolas; Osorio, Matias; Arismendi, Federico; Ibrahim, Ossama; Wagner, Thomas; Platt, Ulrich

2011-01-01

We present preliminary results of ground based measurements of SO 2 and NO 2 emissions from 'La Teja' oil refinery located in the northern part of Montevideo Bay. Our study is part of a long term effort to localize and monitor relevant emission sources in the city area of Montevideo. These measurements were performed with a Miniature Multi AXis Differential Optical Absorption Spectrometry (MiniMAX-DOAS) instrument, which is basically a temperature controlled medium-resolution spectrometer (∼ 0.5 nm) equipped with a small telescope and a stepper motor allowing automatic scans in one dimension. We present a discussion about the evolution and transformation of both above species in the atmosphere. Our observation site was approximately 1.9 km away from the oil refinery and we were able to perform vertical and horizontal scans of the plume emitted (during our measurements) almost horizontally from its stacks. The maximum value of the SO 2 slant column density (SCD) was found to be ∼ 4x10 17 molec cm -2 directly over the oil refinery, decreasing as the plume disperses. In contrast, the NO 2 SCD peaks at ∼ 1x10 16 molec cm -2 directly over the source and increases continuously as the plume disperses. The SO 2 flux measured immediately downwind of the refinery was found to be about 1200 kg h -1 (±40% uncertainty).

Limited field investigation report for the 100-KR-4 Operable Unit

International Nuclear Information System (INIS)

1994-07-01

This limited field investigation (LFI) was conducted to optimize the use of interim remedial measures (IRM) for expediting clean up while maintaining a technically sound and cost-effective program. The 100-KR-4 Operable Unit is one of four operable units associated with the 100 K Area. Operable units KR-1, KR-2 and KR-3 address contaminant sources while 100-KR-4 addresses contamination present in the underlying groundwater. The IRM decision process for groundwater operable units is based on three aspects: (1) Is the concentration greater than Hanford background? (2) Does the concentration present a medium or high human-health risk? (3) Does the concentration exceed an ecologically based applicable, relevant and appropriate requirements (ARAR) or present an environmental hazard quotient > I? The primary methods of investigation used during this LFI were the installation of monitoring wells and sampling of groundwater. The samples collected from the groundwater and soils were submitted for laboratory analysis. Boreholes were surveyed for radiological contamination using downhole geophysical techniques to further delineate the location and degree of contamination. All soil samples were screened to ascertain the presence of volatile organic compounds and radionuclides. Analytical data were subjected to validation; all first round and a minimum of 10% of subsequent round data were validated

Limited field investigation report for the 100-DR-1 Operable Unit

International Nuclear Information System (INIS)

1994-06-01

This limited field investigation (LFI) report summarizes the data collection and analysis activities conducted during the 100-DR-1 Source Operable Unite LFI and the associated qualitative risk assessment (QRA), and makes recommendations on the continued candidacy of high-priority sites for interim remedial measures (IRM). The results and recommendations presented in this report are generally independent of future land use scenarios. The 100-DR-1 Operable Unit is one of four operable units associated with the 100 D/DR Area at the Hanford Site. The 100-DR-1 Operable Unit encompasses approximately 1.5 km 2 (0.59 mi 2 ) and is located immediately adjacent to the Columbia River shoreline. In general, it contains waste facilities associated with the original plant facilities constructed to support D Reactor facilities, as well as cooling water retention basin systems for both D and DR Reactors. The 100-DR-1 LFI began the investigative phase of the remedial investigation for a select number of high-priority sites. The LFI was performed to provide additional data needed to support selection, design and implementation of IRM, if needed. The LFI included data compilation, nonintrusive investigations, intrusive investigations, summarization of 100 Area aggregate studies, and data evaluation

Poland petroleum refinery sludge lagoon demonstration project

International Nuclear Information System (INIS)

Altman, D.J.

2000-01-01

The US Department of Energy and the Institute for Ecology of Industrial Area have been working together to develop mutually beneficial, cost-effective environmental remediation technologies such as the demonstration of bioremediation techniques for the clean up of acidic petroleum sludge impacted soils at an oil refinery in southern Poland. After an expedited site characterization, treatability study, and a risk assessment study, a remediation strategy was devised. The waste material was composed primarily of high molecular weight paraffinic and polynuclear aromatic hydrocarbons. A biopile design which employed a combination of passive and active aeration in conjunction with nutrient and surfactant application as used to increase the biodegradation of the contaminants of concern

Field Operations and Enforcement Manual for Air Pollution Control. Volume III: Inspection Procedures for Specific Industries.

Science.gov (United States)

Weisburd, Melvin I.

The Field Operations and Enforcement Manual for Air Pollution Control, Volume III, explains in detail the following: inspection procedures for specific sources, kraft pulp mills, animal rendering, steel mill furnaces, coking operations, petroleum refineries, chemical plants, non-ferrous smelting and refining, foundries, cement plants, aluminum…

Energetics of the United States of America: An Atlas

Energy Technology Data Exchange (ETDEWEB)

Drysdale, F. R.; Calef, C. E.

1976-09-01

A description of the United States' energy system is presented in the form of thirty-one maps and eight major tables. The county has been chosen as the basic unit for reporting estimations of many energy, demographic, and economic variables. The variables include production of all fuels (including hydroelectricity), use of fuels and electricity broken down by sector and end use, existing and planned electricity generation capacity, refinery capacities, and emissions of air pollutants from fuel use. Calculations and assumptions used to make county-level energy estimates are described in detail.

Geohydrology, water quality, and simulation of ground-water flow in the vicinity of a former waste-oil refinery near Westville, Indiana, 1997-2000

Science.gov (United States)

Duwelius, Richard F.; Yeskis, Douglas J.; Wilson, John T.; Robinson, Bret A.

2002-01-01

Geohydrologic and water-quality data collected during 1997 through 2000 in the vicinity of a former waste-oil refinery near Westville, Indiana, define a plume of 1,4-dioxane in ground water that extends to the southwest approximately 0.8 miles from the refinery site. Concentrations of 1,4-dioxane in the plume ranged from 3 to 31,000 micrograms per liter. Ground water containing 1,4-dioxane is discharged to Crumpacker Ditch, approximately one-half mile west of the refinery site. Concentrations of 1,4-dioxane detected in surface water ranged from 8 to 140 micrograms per liter; 1,4-dioxane also is transported in ground water beneath the ditch.

Global Warming Potential Of A Waste Refinery Using Enzymatic Treatment

DEFF Research Database (Denmark)

Tonini, Davide; Astrup, Thomas

2010-01-01

and fossil resources. This is especially important with respect to the residual waste (i.e. the remains after source-separation and separate collection) which is typically incinerated or landfilled. In this paper the energy and Global Warming performance of a pilot-scale waste refinery for the enzymatic...... plants and utilization of the liquid fraction for biogas production turned out to be the best options with respect to energy and Global Warming performance....

Refinery Integration of By-Products from Coal-Derived Jet Fuels

Energy Technology Data Exchange (ETDEWEB)

Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2008-03-31

The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using known refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to

Integrated Ground Operations Demonstration Units Testing Plans and Status

Science.gov (United States)

Johnson, Robert G.; Notardonato, William U.; Currin, Kelly M.; Orozco-Smith, Evelyn M.

2012-01-01

Cryogenic propellant loading operations with their associated flight and ground systems are some of the most complex, critical activities in launch operations. Consequently, these systems and operations account for a sizeable portion of the life cycle costs of any launch program. NASA operations for handling cryogens in ground support equipment have not changed substantially in 50 years, despite advances in cryogenics, system health management and command and control technologies. This project was developed to mature, integrate and demonstrate advancement in the current state of the art in these areas using two distinct integrated ground operations demonstration units (GODU): GODU Integrated Refrigeration and Storage (IRAS) and GODU Autonomous Control

Fiscal 1998 industrial science and technology R and D system. R and D report on human media / R and D on the advanced information system technology for oil refinery plants; 1998 nendo seika hokokusho. Human media no kenkyu kaihatsu, sekiyu plant kodo johoka system gijutsu kenkyu kaihatsu

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-03-01

As a part of R and D on human media, this report describes the fiscal 1998 result on development of the advanced information system for oil refinery plants. The R and D on human media have been promoted toward construction of a new information system around human beings by advanced integrated media technology since fiscal 1994. The whole concept is body sensation-, heart sensation- and knowledge- friendly media. For safe operation of oil refinery plants, this project develops (1) the intelligent monitoring of measuring instrument information and image information, (2) the display and guidance for facilitating collection of operation data by operator, (3) the modeling for efficient management of previous data and their effective use for current operations, and (4) the autonomous cooperative control technology. In fiscal 1998, the following subsystems were designed and prepared: The interface agent, virtual plant display interface, semantic representation interface, ontology, distributed cooperative processing technology, plant model and interface system. (NEDO)

Competitive strategy to provide technology and basic designs for the construction of new refineries premium of the PETROBRAS; Estrategia competitiva para prover tecnologias e projetos basicos para a construcao de novas refinarias premium da PETROBRAS

Energy Technology Data Exchange (ETDEWEB)

Claudia, Baptista M.L.A.; Adalberto, Barbalho S [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)

2012-07-01

Nowadays, there are major incentives for the construction of new refineries in Brazil: the increase of the local market and the discovery of huge oil reserves in the southeastern Atlantic coast of Brazil. In this scenario, PETROBRAS decided to construct two new refineries, Premium I and II, with a total refining capacity of 900.000 BPSD. The refineries will be designed to process a mix of Brazilian national crudes. The main objects of this ambitious project are to produce high quality diesel and jet fuel from an elevated nitrogen content feedstock, minimizing capital expenditure and schedule. Both refineries will have the same flow scheme with a target to maximize Middle distillate production for the European and local markets. In order to assure that the refinery scheme and the technologies selected will provide the best Net Present Value (NPV), it was decided to perform a Design Competition process to select the company to provide the basic design for all Premium refineries. As the concepts behind a Design Competition were new for PETROBRAS a rigorous process was developed and followed, which entailed contracting three benchmark companies with outstanding knowledge and experience in hydroprocessing to provide independent conceptual studies for a 300.000 BPSD refinery called Premium II. The vision was to utilize the same refinery scheme in the construction of the Premium I refinery which will have two identical trains processing 300.000 BPD. The awarded company was selected based on technical and economic evaluations, supported by state of the art hydroprocessing technologies, block flow diagram optimization and heat integration. This strategy allowed PETROBRAS to acquire the best refinery scheme and process designs for the PREMIUM refineries. The present paper discusses the design competition process, the refinery scheme adopted and the results achieved. (author)

Reduction of heavy metals in refinery waste sludge using em treatment

International Nuclear Information System (INIS)

Ahmad, J.; Ahmad, F.; Saleemi, A.R.; Ahmad, I.

2005-01-01

This paper presents the efforts of National Cleaner Production Center (NCPC) and Attock Refinery Limited (ARL) Rawalpindi, to address the problem of refinery solid waste. A trial project was designed to treat and convert 1.7 m ton to oil sludge into environmental friendly residue (compost) under anaerobic conditions. The residue can be treated as bio fertilizer for agricultural purpose. The trial on bio remediation (anaerobic) of oily sludge of ARL, Rawalpindi within its premises using EM technology was successfully completed with the collaboration of effective microorganism research organization (EMRO), NCPC and ARL between 29th October to 10th December, 2002. The effective microorganisms transformed the undiluted oily sludge from ARL into bioactive sludge; which may be called as bio sludge. For heavy metal breakdown the trial data shows that Ba has been reduced by 85% in the EM. Treated oily sludge as compared to original ARL sludge, and Pb, Fe, Zn and Ni have been reduced by about 50% in the treated bio sludge. The contents of As, Cr, Cu and Mn showed no change. The residue obtained can be used as a bio fertilizer. (author)

Assessment of availability of a Fluid Catalytic Cracking Unit through simulation

International Nuclear Information System (INIS)

Thangamani, G.; Narendran, T.T.; Subramanian, R.

1995-01-01

This paper presents a systematic approach to estimate the availability of process plants. The study includes a live problem at a Fluid Catalytic Cracking Unit (FCCU) of a refinery requiring high levels of availability for cost-effective operation. The system is modelled as a fault tree which is often used in the analysis of chemical process industries. A numerical evaluation of the fault tree assesses the characteristic safety parameters such as reliability and availability of the system. However, for large and complex systems, such analysis will normally require enormous computational effort, involving the breakdown of the fault tree into minimal cut sets. An alternative approach is to simulate the system using the Monte Carlo method. This paper presents an availability analysis of the Reactor/Regenerator system of the Fluid Catalytic Cracking Unit using the Monte Carlo simulation. The results of the simulation are validated by a comparison with the actual system. The method promises to be a useful tool for assessing the availability of complex systems with alternative configurations

Programming of a refinery from the perspective of the decision makers: trade-offs analysis for corporate and technical guidelines; A programacao de uma refinaria sob a otica do decisor: uma analise dos trade-offs diante das orientacoes tecnicas e corporativas

Energy Technology Data Exchange (ETDEWEB)

Spiegel, Thais; Caulliraux, Heitor Mansur; Proenca, Adriano [Coordenacao dos Programas de Pos-Graduacao de Engenharia (COPPE/UFRJ), RJ (Brazil)

2012-07-01

Refineries usually gather a set of activities that shape how complex and dynamic it is. Adding to the complexity of the refining process, there is also a great freedom in the refinery operations, multiple arrangements possible to convert certain oil in derivatives. In this context, this article focuses on decision-making processes that lead refineries of an integrated oil company in their day to day. As decision-making, the text refers to a process that always brings a kind of conflict resolution, in which contradictory goals have to be negotiated and reconciled. The object of analysis is inserted in hierarchical decision-making processes, ie a process of disintegration, which begins with a comprehensive assessment, and then divides the decision in elements smaller and more defined, so that they are interdependent. The output at an aggregate level shall be the input in the next detailed level. In each level of the hierarchical, decision-making is the result of a problem, presented in a given context to a decision maker. Decision maker will be the responsible for the direction of the refinery production to which it is allocated. The programmer of each refinery is general guidelines that should be considered, albeit non-explicit or non-configurable, in some cases these take the form of technical criteria and in other situations derived from the business. From these, this article presents a critical and analytical in the face of dilemmas that emerge in front of decision makers search for converging a production schedule that meets both the criteria set. (author)

Development of a biorefinery optimized biofuel supply curve for the western United States

Science.gov (United States)

Nathan Parker; Peter Tittmann; Quinn Hart; Richard Nelson; Ken Skog; Anneliese Schmidt; Edward Gray; Bryan Jenkins

2010-01-01

A resource assessment and biorefinery siting optimization model was developed and implemented to assess potential biofuel supply across the Western United States from agricultural, forest, urban, and energy crop biomass. Spatial information including feedstock resources, existing and potential refinery locations and a transportation network model is provided to a mixed...

The impact of the maintenance management system: a case study of the PetroSA GTL refinery

Directory of Open Access Journals (Sweden)

Mahlangu, Bafana Petrus

2015-11-01

Full Text Available This research study investigated the impact of the maintenance management system (MMS on production output and profitability (PO&P at the PetroSA GTL refinery, a state-owned company. The two groups that participated were the maintenance group, consisting of 56 respondents, and the production group, with 38 respondents. The main findings of the research study suggested that the MMS impacts positively on PO&P at the PetroSA GTL refinery. The maintenance scorecard assessment tool – consisting of six perspectives – was used to assess the gap between the MMS and PO&P. The positivism paradigm, the deductive process, a cross-sectional quantitative survey, and descriptive statistics were used to conduct the research study.

Hydroisomerization of different refinery naphtha streams by using a beta zeolite catalyst

Energy Technology Data Exchange (ETDEWEB)

Ramos, Maria Jesus; de Lucas, Antonio; Jimenez, Vicente; Sanchez, Paula; Valverde, Jose Luis [Departamento de Ingenieria Quimica, Facultad de Ciencias Quimicas, Universidad de Castilla-La Mancha, Avd. Camilo Jose Cela s/n, 13071 Ciudad Real (Spain)

2008-08-15

In this work, the evaluation of a catalyst based on beta zeolite agglomerated with bentonite in the hydroisomerization of three feeds obtained by distillation of refinery naphtha streams provided by the petroleum company REPSOL-YPF was considered. These refinery naphthas were different in composition, being constituted mostly by different proportions of paraffin, aromatic and naphthenic compounds. The highest overall paraffin conversion value was obtained with that naphtha with the highest content in linear paraffins. As the classical hydroisomerization mechanism predicts, linear alkanes were transformed into branched isomers. Thus, the relation between branched isomers and linear paraffins (iC6/nC6, iC7/nC7 and iC8/nC8) was higher in the products than in the feed. The presence of the aromatic compounds (benzene and toluene) was detected in the three feeds. In all cases, a complete benzene conversion, leading to naphthenic compounds formation, was reached. Long-term tests showed that, regardless of the type of naphtha fed to the reactor, the research octane number of the products remained practically constant. (author)

Oil prices: The role of refinery utilization, futures markets and non-linearities

International Nuclear Information System (INIS)

Kaufmann, Robert K.; Mann, Michael; Dees, Stephane; Gasteuil, Audrey

2008-01-01

We test the hypothesis that real oil prices are determined in part by refinery capacity, non-linearities in supply conditions, and/or expectations and that observed changes in these variables can account for the rise in prices between 2004 and 2006. Results indicate that the refining sector plays an important role in the recent price increase, but not in the way described by many analysts. The relationship is negative such that higher refinery utilization rates reduce crude oil prices. This effect is associated with shifts in the production of heavy and light grades of crude oil and price spreads between them. Non-linear relationships between OPEC capacity and oil prices as well as conditions on the futures markets also account for changes in real oil prices. Together, these factors allow the model to generate a one-step ahead out-of-sample forecast that performs as well as forecasts implied by far-month contracts on the New York Mercantile Exchange and is able to account for much of the $27 rise in crude oil prices between 2004 and 2006. (author)

Operating experience with unit for sulfuric acid alkylation of isobutane by butylenes

Energy Technology Data Exchange (ETDEWEB)

Tagavov, I.T.; Sumanov, V.T.; Khadzhiev, S.N.

1988-09-01

The operation of units for the sulfuric acid alkylation of isobutanes by butylenes have been performed. The reaction was carried out in a KSG-3 horizontal sulfuric acid contractor. A butane-butylene fraction from catalytic cracking and an isobutane fraction from the central gas fractionating unit were used as a feedstock. The studies have shown that the unit will give a high-quality product under various conditions of operation. The specific consumption of sulfuric acid in processing different types of feed remains within acceptable limits.

2005 Annual Operations Report for INTEC Operable Unit 3-13, Group 1, Tank Farm Interim Action

International Nuclear Information System (INIS)

D. Shanklin

2006-01-01

This annual operations report describes the requirements followed and activities conducted to inspect, monitor, and maintain the items installed during performance of the Waste Area Group 3, Operable Unit 3-13, Group 1, Tank Farm Interim Action, at the Idaho Nuclear Technology and Engineering Center. This report describes inspection and monitoring activities for the surface-sealed areas within the tank farm, concrete-lined ditches and culverts in and around the tank farm, the lift station, and the lined evaporation pond. These activities are intended to assure that the interim action is functioning adequately to meet the objectives stated in the Operable Unit 3-13, Record of Decision for the Group 1, Tank Farm Interim Action, (DOE/ID-10660) and as amended by the agreement to resolve dispute, which was effective in February 2003

Treating refinery wastewaters in microbial fuel cells using separator electrode assembly or spaced electrode configurations

KAUST Repository

Zhang, Fang; Ahn, Yongtae; Logan, Bruce E.

2014-01-01

The effectiveness of refinery wastewater (RW) treatment using air-cathode, microbial fuel cells (MFCs) was examined relative to previous tests based on completely anaerobic microbial electrolysis cells (MECs). MFCs were configured with separator

Limited field investigation report for the 100-HR-3 operable unit

International Nuclear Information System (INIS)

1994-09-01

This limited field investigation (LFI) was conducted to assess the applicability of interim remedial measures (IRM) for reducing human health and environmental risks within the 100-HR-3 Groundwater Operable Unit. The 100-HR-3 Operable Unit is comprised of three subareas; the 100 D Area, the 100 H Area and those portions of the 600 Area between the two reactor areas. The operable unit is one of seven operable units associated with the 100 D and H Areas. Operable units 100-DR-1, 100-DR-2, 100-DR-3, 100-HR-1, 100-HR-2 and 100-IU-4 address contaminant sources while 100-HR-3 addresses contamination present in the underlying groundwater. The primary method of field investigation used during this LFI was the installation and sampling of monitoring wells. Samples were collected from the groundwater and soils, and submitted for laboratory analysis. Boreholes were surveyed for radiological contamination using downhole geophysical techniques to further delineate the locations and levels of contaminants. All samples were screened to ascertain the presence of volatile organic compounds and radionuclides. Analytical data were subjected to validation; all round one, two and three and a minimum of 10% of round four data associated with the LFI were validated. A screening method was used to identify contaminants of potential concern (COPC). This screening method eliminated from further consideration, constituents that were below background. Constituents which are considered non-toxic to humans were eliminated from the human health evaluation. Data consistency and blank contamination were also evaluated in the screening process. These COPC were then evaluated further in the qualitative risk assessment (QRA). A human health QRA was performed using conservative (maximum equilibrated contaminant levels from the LFI) analyses

Limited field investigation report for the 100-HR-2 Operable Unit

International Nuclear Information System (INIS)

1994-09-01

This report summarizes the data collection and analysis activities conducted during the 100-HR-2 Operable Unit investigative phase and the associated qualitative risk assessment (QRA). The 100-HR-2 Operable Unit contains solid waste burial grounds, an ash pit, bum pits, electrical facilities, septic systems, and support facilities. All known and suspected areas of contamination were classified as solid waste burial grounds or low-priority waste sites based on the collective knowledge of the operable unit managers (representatives from the US Department of Energy [DOE], the US Environmental Protection Agency [EPA], and Washington Department of Ecology [Ecology]) during the preparation of the 100-HR-2 Operable Unit work plan (DOE/RL 1993f). Solid waste burial grounds were judged to pose sufficient risk(s), through one or more pathways, to require evaluation for an interim remedial measure (IRM) as per the Hanford Past-Practice Strategy (HPPS) (DOE/RL 1991) and negotiations with DOE, EPA, and Ecology. An IRM is intended to achieve remedies that are likely to lead to a final record of decision. Low-priority sites are those judged not to pose significant risk to require the streamlined evaluation. There were six low-priority waste sites and seven solid waste burial grounds identified. The investigative phase was conducted in accordance with the RCRA Facility Investigation/Corrective Measures Study Work Plan for the 100-HR-2 Operable Unit (DOE/RL 1993f). The QRA was performed in accordance with the Hanford Site Baseline Risk Assessment Methodology (DOE/RL 1993b) and the recommendations incorporate the strategies of the HPPS. The purpose of this report is to: (1) provide a summary of site investigative activities; (2) refine the conceptual exposure model (as needed); (3) identify chemical- and location-specific corrective action requirements; and (4) provide a human health and ecological QRA associated with solid waste burial grounds

REMOTE SENSING DAMAGE ASSESSMENT OF CHEMICAL PLANTS AND REFINERIES FOLLOWING HURRICANES KATRINA AND RITA

Science.gov (United States)

The massive destruction brought by Hurricanes Katrina and Rita also impacted the many chemical plants and refineries in the region. The achievement of this rapid analysis capability highlights the advancement of this technology for air quality assessment and monitoring. Case st...

Legitimacy in Green: Pollution vs. Profit in Canadian Oil Refineries

Directory of Open Access Journals (Sweden)

Vanessa Magness

2007-06-01

light of changing societal expectations have created an external environment that encourages the development of new technologies that promote cost efficiencies and good environmental performance simultaneously.  Russo and Fouts (1997 argued that industries subject to rapid technological advance are well suited to respond to these changes in the external environment. The findings of this paper suggest that the petroleum refinery sector of the oil and gas industry may be meeting the challenge of the environmental movement.

Increasing the complexity of a refinery: a analysis of the economic impacts of the introduction of new process in refineries; O aumento da complexidade de uma refinaria: uma analise dos impactos economicos da introducao de novos processos em refinarias

Energy Technology Data Exchange (ETDEWEB)

Fontes, Cristiane M; Seidl, Peter R [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Escola de Quimica

2008-07-01

The importance of the refining segment in the oil productive chain turns decision making on production and investment to be made at refineries dependent upon general context of the oil industry. Several technical and economic factors limit the possibilities to be foreseen by the managers. The ultimate goal of a refinery is to meet market demand in a region. Moreover, the type of processed oil and refining techniques will shape the profile of the production of derivatives. In a segment dynamic and full of uncertainties, such as refining, where the type of oil supplied to processing, specifications of products, and their demands, changes in the course of time, how to keep refining margins acceptable? This paper presents the relationship between the characteristics and the use of different kinds of oil, the characteristics of the national market of derivatives, and some characteristics of the refining processes considered in the study. The possible economic impacts that the introduction of different processes can bring to a refinery are analysed and alternatives for expansion are evaluated. To achieve these goals, a methodology for analysis considering the yield of Marlin oil refining for different schemes has been developed. (author)

Radioactive acid digestion test unit nonradioactive startup operations

International Nuclear Information System (INIS)

Allen, C.R.; Cowan, R.G.; Crippen, M.D.; Divine, J.R.

1978-05-01

The Radioactive Acid Digestion Test Unit (RADTU) will process 5 kg/hour of combustible solid waste and is designed to handle almost all solid combustible waste found in plutonium processing with plutonium contamination levels up to scrap. The RADTU is designed with special safety features to safely contain high masses of fissile materials and to safely handle unusual materials and reactive chemicals which may find their way into the waste. Nonradioactive operating experience to date has been very satisfactory. RADTU has been operated for extended runs on both a 24-hour per day basis as well as on a one shift per day basis. Some minor operating problems have been encountered as expected in a shakedown operation. In general, solutions to these have been readily found. 12 figures

Genotoxic evaluation of an industrial effluent from an oil refinery using plant and animal bioassays.

Science.gov (United States)

Rodrigues, Fernando Postalli; Angeli, José Pedro Friedmann; Mantovani, Mário Sérgio; Guedes, Carmen Luisa Barbosa; Jordão, Berenice Quinzani

2010-01-01

Polycyclic aromatic hydrocarbons (PAHs) are genotoxic chemicals commonly found in effluents from oil refineries. Bioassays using plants and cells cultures can be employed for assessing environmental safety and potential genotoxicity. In this study, the genotoxic potential of an oil refinery effluent was analyzed by means of micronucleus (MN) testing of Alium cepa, which revealed no effect after 24 h of treatment. On the other hand, primary lesions in the DNA of rat (Rattus norvegicus) hepatoma cells (HTC) were observed through comet assaying after only 2 h of exposure. On considering the capacity to detect DNA damage of a different nature and of these cells to metabolize xenobiotics, we suggest the association of the two bioassays with these cell types, plant (Allium cepa) and mammal (HTC) cells, for more accurately assessing genotoxicity in environmental samples.

Analysis of long-time operation of micro-cogeneration unit with fuel cell