Initiation model for intergranular stress corrosion cracking in BWR pipes

International Nuclear Information System (INIS)

Hishida, Mamoru; Kawakubo, Takashi; Nakagawa, Yuji; Arii, Mitsuru.

1981-01-01

Discussions were made on the keys of intergranular stress corrosion cracking of austenitic stainless steel in high-temperature water in laboratories and stress corrosion cracking incidents in operating plants. Based on these discussions, a model was set up of intergranular stress corrosion cracking initiation in BWR pipes. Regarding the model, it was presumed that the intergranular stress corrosion cracking initiates during start up periods whenever heat-affected zones in welded pipes are highly sensitized and suffer dynamic strain in transient water containing dissolved oxygen. A series of BWR start up simulation tests were made by using a flowing autoclave system with slow strain rate test equipment. Validity of the model was confirmed through the test results. (author)

Challenges in Continuum Modelling of Intergranular Fracture

DEFF Research Database (Denmark)

Coffman, Valerie; Sethna, James P.; Ingraffea, A. R.

2011-01-01

of grain boundaries, but also in crucial ways on edges, corners and triple junctions of even greater geometrical complexity. To address the first two challenges, we explore the physical underpinnings for creating functional forms to capture the hierarchical commensurability structure in the grain boundary......Intergranular fracture in polycrystals is often simulated by finite elements coupled to a cohesive zone model for the interfaces, requiring cohesive laws for grain boundaries as a function of their geometry. We discuss three challenges in understanding intergranular fracture in polycrystals. First...... properties. To address the last challenge, we demonstrate a method for atomistically extracting the fracture properties of geometrically complex local regions on the fly from within a finite element simulation....

Computational multiscale modeling of intergranular cracking

International Nuclear Information System (INIS)

Simonovski, Igor; Cizelj, Leon

2011-01-01

A novel computational approach for simulation of intergranular cracks in a polycrystalline aggregate is proposed in this paper. The computational model includes a topological model of the experimentally determined microstructure of a 400 μm diameter stainless steel wire and automatic finite element discretization of the grains and grain boundaries. The microstructure was spatially characterized by X-ray diffraction contrast tomography and contains 362 grains and some 1600 grain boundaries. Available constitutive models currently include isotropic elasticity for the grain interior and cohesive behavior with damage for the grain boundaries. The experimentally determined lattice orientations are employed to distinguish between resistant low energy and susceptible high energy grain boundaries in the model. The feasibility and performance of the proposed computational approach is demonstrated by simulating the onset and propagation of intergranular cracking. The preliminary numerical results are outlined and discussed.

Proceedings: 1991 EPRI workshop on secondary-side intergranular corrosion mechanisms

International Nuclear Information System (INIS)

Partridge, M.J.; Zemitis, W.S.

1992-08-01

A workshop on ''Secondary-Side Intergranular Corrosion Mechanisms'' was organized by EPRI as an effort to give those working in this area an opportunity to share their results, ideas, and plans. Topics covered included: (1) caustic induced intergranular attack/stress corrosion cracking (IGA/IGSCC), (2) plant experience, (3) boric acid as an IGA/IGSCC remedial measure, (4) lead induced IGA/IGSCC, and (5) acid induced IGA/IGSCC

Study of twist boundaries in aluminium. Structure and intergranular diffusion

International Nuclear Information System (INIS)

Lemuet, Daniel

1981-01-01

This research thesis addresses the study of grain boundaries in oriented crystals, and more particularly the systematic calculation of intergranular structures and energies of twist boundaries of <001> axis in aluminium, the determination of intergranular diffusion coefficients of zinc in a set of twist bi-crystals of same axis encompassing a whole range of disorientations, and the search for a correlation between these experimental results and calculated structures

The effect of sintering temperature on the intergranular properties and weak link behavior of Bi2223 superconductors

Directory of Open Access Journals (Sweden)

P. Kameli

2006-03-01

Full Text Available  A systematic study of the intergranular properties of (Bi,Pb2 Sr2 Ca2 Cu3 Oy (Bi2223 polycrystalline samples has been done using the electrical resistivity and AC susceptibility techniques. In this study, we have prepared a series of Bi2223 samples with different sintering temperatures. The XRD results show that by increasing the sintering temperature up to 865° c , the Bi2212 phase fraction decreases. It was found that the Bi2212 phase on the grain boundaries is likely to play the role of the weak links and consequently reduces the intergranular critical current densities.

Intergranular stresses in Incoloy-800

International Nuclear Information System (INIS)

Holden, T.M.; Holt, R.A.; Clarke, A.P.

1997-01-01

The generation of intergranular residual strains under uniaxial loading conditions in the plastic regime has been measured in detail by neutron diffraction in Incoloy-800. A relatively simple theory, based on the Taylor model, gives a good semiquantitative account of the magnitudes of the strains. The results clarify the interpretation of measurements made earlier on Incoloy-800 steam generator tubes. (author)

Assessing resistance of stabilized corrosion resistant steels to intergranular corrosion

International Nuclear Information System (INIS)

Karas, A.; Cihal, V. Jr.; Vanek, V.; Herzan, J.; Protiva, K.; Cihal, V.

1987-01-01

Resistance to intergranular corrosion was determined for four types of titanium-stabilized steels from the coefficients of stabilization efficiency according to the degree the chemical composition was known. The ATA SUPER steel showed the highest resistance parameter value. The resistance of this type of steel of a specific composition, showing a relatively low value of mean nitrogen content was compared with steel of an optimized chemical composition and with low-carbon niobium stabilized, molybdenum modified steels. The comparison showed guarantees of a sufficient resistance of the steel to intergranular corrosion. The method of assessing the resistance to intergranular corrosion using the calculation of the minimum content of Cr', i.e., the effective chromium content, and the maximum effective carbon content C' giving the resistance parameter k seems to be prospective for practical use in the production of corrosion resistant steels. (author). 1 tab., 5 figs., 15 refs

Air Circulation and Heat Exchange Under Reduced Pressures

Science.gov (United States)

Rygalov, V.; Wheeler, R.; Dixon, M.; Fowler, P.; Hillhouse, L.

2010-01-01

Heat exchange rates decrease non-linearly with reductions in atmospheric pressure. This decrease creates risk of thermal stress (elevated leaf temperatures) for plants under reduced pressures. Forced convection (fans) significantly increases heat exchange rate under almost all pressures except below 10 kPa. Plant cultivation techniques under reduced pressures will require forced convection. The cooling curve technique is a reliable means of assessing the influence of environmental variables like pressure and gravity on gas exchange of plant. These results represent the extremes of gas exchange conditions for simple systems under variable pressures. In reality, dense plant canopies will exhibit responses in between these extremes. More research is needed to understand the dependence of forced convection on atmospheric pressure. The overall thermal balance model should include latent and radiative exchange components.

Double coating protection of Nd–Fe–B magnets: Intergranular phosphating treatment and copper plating

International Nuclear Information System (INIS)

Zheng, Jingwu; Chen, Haibo; Qiao, Liang; Lin, Min; Jiang, Liqiang; Che, Shenglei; Hu, Yangwu

2014-01-01

In this work, a double coating protection technique of phosphating treatment and copper plating was made to improve the corrosion resistance of sintered Nd–Fe–B magnets. In other words, the intergranular region of sintered Nd–Fe–B is allowed to generate passive phosphate conversion coating through phosphating treatment, followed by the copper coating on the surface of sintered Nd–Fe–B. The morphology and corrosion resistance of the phosphated sintered Nd–Fe–B were observed using SEM and electrochemical method respectively. The phosphate conversion coating was formed more preferably on the intergranular region of sintered Nd–Fe–B than on the main crystal region; just after a short time of phosphating treatment, the intergranular region of sintered Nd–Fe–B has been covered by the phosphate conversion coating and the corrosion resistance is significantly improved. With the synergistic protection of the intergranular phosphorization and the followed copper electrodeposition, the corrosion resistance of the sintered Nd–Fe–B is significantly better than that with a single phosphate film or single plating protection. - Highlights: • We combined intergranular phosphating and copper plating to protect Nd–Fe–B. • The phosphate conversion coating was formed preferably on the intergranular region. • The phosphating coating can obviously improve the corrosion resistance of Nd–Fe–B. • The corrosion resistance of Nd–Fe–B was improved by double coating protection

Double coating protection of Nd–Fe–B magnets: Intergranular phosphating treatment and copper plating

Energy Technology Data Exchange (ETDEWEB)

Zheng, Jingwu; Chen, Haibo; Qiao, Liang [College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014 (China); Lin, Min [Key Laboratory of Magnetic Materials and Devices, Ningbo Institute of Material Technology and Engineering Chinese Academy of Science, Ningbo 315201 (China); Jiang, Liqiang; Che, Shenglei [College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014 (China); Hu, Yangwu, E-mail: 346648086@qq.com [College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014 (China); Wenzhou Institute of Industry and Science, Wenzhou 325000 (China)

2014-12-15

In this work, a double coating protection technique of phosphating treatment and copper plating was made to improve the corrosion resistance of sintered Nd–Fe–B magnets. In other words, the intergranular region of sintered Nd–Fe–B is allowed to generate passive phosphate conversion coating through phosphating treatment, followed by the copper coating on the surface of sintered Nd–Fe–B. The morphology and corrosion resistance of the phosphated sintered Nd–Fe–B were observed using SEM and electrochemical method respectively. The phosphate conversion coating was formed more preferably on the intergranular region of sintered Nd–Fe–B than on the main crystal region; just after a short time of phosphating treatment, the intergranular region of sintered Nd–Fe–B has been covered by the phosphate conversion coating and the corrosion resistance is significantly improved. With the synergistic protection of the intergranular phosphorization and the followed copper electrodeposition, the corrosion resistance of the sintered Nd–Fe–B is significantly better than that with a single phosphate film or single plating protection. - Highlights: • We combined intergranular phosphating and copper plating to protect Nd–Fe–B. • The phosphate conversion coating was formed preferably on the intergranular region. • The phosphating coating can obviously improve the corrosion resistance of Nd–Fe–B. • The corrosion resistance of Nd–Fe–B was improved by double coating protection.

Fission-induced recrystallization effect on intergranular bubble-driven swelling in U-Mo fuel

Energy Technology Data Exchange (ETDEWEB)

Liang, Linyun; Mei, Zhi-Gang; Yacout, Abdellatif M.

2017-10-01

We have developed a mesoscale phase-field model for studying the effect of recrystallization on the gas-bubble-driven swelling in irradiated U-Mo alloy fuel. The model can simulate the microstructural evolution of the intergranular gas bubbles on the grain boundaries as well as the recrystallization process. Our simulation results show that the intergranular gas-bubble-induced fuel swelling exhibits two stages: slow swelling kinetics before recrystallization and rapid swelling kinetics with recrystallization. We observe that the recrystallization can significantly expedite the formation and growth of gas bubbles at high fission densities. The reason is that the recrystallization process increases the nucleation probability of gas bubbles and reduces the diffusion time of fission gases from grain interior to grain boundaries by increasing the grain boundary area and decreasing the diffusion distance. The simulated gas bubble shape, size distribution, and density on the grain boundaries are consistent with experimental measurements. We investigate the effect of the recrystallization on the gas-bubble-driven fuel swelling in UMo through varying the initial grain size and grain aspect ratio. We conclude that the initial microstructure of fuel, such as grain size and grain aspect ratio, can be used to effectively control the recrystallization and therefore reduce the swelling in U-Mo fuel.

Martensitic transformation in an intergranular corrosion area of austenitic stainless steel during thermal cycling

International Nuclear Information System (INIS)

La Fontaine, Alexandre; Yen, Hung-Wei; Trimby, Patrick; Moody, Steven; Miller, Sarah; Chensee, Martin; Ringer, Simon; Cairney, Julie

2014-01-01

An oxidation-assisted martensitic phase transformation was observed in an austenitic stainless steel after thermal cycling up to 970 °C in air in a solar thermal steam reformer. The intergranular corrosion areas were investigated by electron backscatter diffraction (EBSD), transmission Kikuchi diffraction (TKD) and transmission electron microscopy (TEM). The structural-and-chemical maps revealed that within intergranular corrosion areas this martensitic transformation primarily occurs in oxidation-induced chromium-depleted zones, rather than due to only sensitization. This displacive transformation may also play a significant role in the rate at which intergranular corrosion takes place

Intergranular cracking mechanism in baffle former bolt materials for PWR core internals

Energy Technology Data Exchange (ETDEWEB)

Yonezawa, Toshio; Arioka, Koji; Kanasaki, Hiroshi; Fujimoto, Koji [Takasago R and D Center, Mitsubishi Heavy Industries Ltd., Takasago, Hyogo (Japan); Ajiki, Kazuhide [Kobe Shipyard and Machinery, Mitsubishi Heavy Industries Ltd., Kobe, Hyogo (Japan); Matsuoka, Takanori [Nuclear Development Corp., Tokai, Ibaraki (Japan); Urata, Sigeru; Mizuta, Hitoshi [Kansai Electric Power Co., Inc., Osaka (Japan)

2000-03-01

In this study, the cause of intergranular cracking in baffle former bolts(BFBs) was estimated from metallurgical and chemical viewpoints based upon the experimental data and information published by EdF. At first, five kinds of possibilities were estimated as the cause of intergranular cracking in BFBs. Five possibilities estimated were (1) mechanical cracking caused by high strain in irradiation hardened austenitic stainless steels, (2) O{sub 2} SCC due to residual oxygen in the bolt stagnant region, (3) caustic SCC due to dry and wet phenomenon, (4) low pH SCC due to oxygen concentration cell, and (5) PWSCC due to radiation induced segregation. In this study each possibility was evaluated by the calculation and some out of pile tests. And also, the cause of the intergranular cracking in BFBs was estimated by the data of the post-irradiation examinations and basic out of pile tests for Type 316CW and Type 347 stainless steels in the authors' previous study. From these evaluation, the intergranular cracking in BFBs seems to be caused by the PWSCC, but not caused by mechanical cracking O{sub 2} SCC, caustic SCC or low pH SCC. (author)

The effect of thermal history on intergranular boron segregation and fracture morphology of substoichiometric Ni3Al

International Nuclear Information System (INIS)

Choudhury, A.; White, C.L.; Brooks, C.R.

1986-01-01

While it has attractive mechanical properties and good corrosion resistance, the usefulness of polycrystalline Ni 3 Al has been restricted because of its propensity for brittle intergranular fracture. While this intergranular brittleness can be aggravated by the intergranular segregation of certain impurities, particularly sulfur, the grain boundaries of Ni 3 Al are intrinsically brittle and Ni 3 Al will fail intergranularly in the absence of detectable impurity segregation. Addition of boron resulted in the fracture morphology changing from primarily intergranular to largely transgranular; and more importantly, the intergranular segregation of boron was conclusively demonstrated. The range of boron concentrations over which these beneficial effects are observed is well within the solubility limit, which has been estimated to be 1.5 at. % (4,5). Rice (6) developed a relationship between equilibrium intergranular segregation and grain boundary cohesion. According to this theory, the potential for intergranular embrittlement by a solute is related to the relative intensity of segregation of the solute to free surfaces as compared to segregation to grain boundaries. Rices theory allowed for the case of a solute segregating more strongly to grain boundaries than to free surfaces. If this difference is sufficiently large (approximately a factor of two), Rice's theory predicts an enhancement of grain boudary cohesion. White and coworkers (4,7) noted the rather unusual phenomenon of boron segregating much more strongly to grain boundaries of Ni 3 Al than to free surfaces, while sulfur (an embrittling impurity) was shown to exhibit the opposite effect

Testing of intergranular and pitting corrosion in sensitized welded joints of austenitic stainless steel

Directory of Open Access Journals (Sweden)

Bore V. Jegdic

2017-06-01

Full Text Available Pitting corrosion resistance and intergranular corrosion of the austenitic stainless steel X5Cr Ni18-10 were tested on the base metal, heat affected zone and weld metal. Testing of pitting corrosion was performed by the potentiodynamic polarization method, while testing of intergranular corrosion was performed by the method of electrochemical potentiokinetic reactivation with double loop. The base metal was completely resistant to intergranular corrosion, while the heat affected zone showed a slight susceptibility to intergranular corrosion. Indicators of pitting corrosion resistance for the weld metal and the base metal were very similar, but their values are significantly higher than the values for the heat affected zone. This was caused by reduction of the chromium concentration in the grain boundary areas in the heat affected zone, even though the carbon content in the examined stainless steel is low (0.04 wt. % C.

Weak Frictional Healing as Controlled by Intergranular Pressure Solution

Science.gov (United States)

He, C.

2017-12-01

Unstable fault slips due to velocity weakening requires a frictional healing effect that is stronger than the instantaneous rate effect. Based on a previous analytical result regarding the healing effect at spherical contacts by intergranular pressure solution (He et al., 2013), we extend the analysis to incorporate the full range of dilatancy angles from π/6 to -π/6, covering uphill and downhill situations of many contacts with different dilatancy angles. Assuming that both healing effect (parameter b) and instantaneous rate effect (parameter a) are controlled by intergranular pressure solution, and averaging over the whole range of dilatancy angle, our analysis derives each of the two effects as a function of temperature. The result shows velocity weakening for friction coefficient>0.274. As hydrothermal conditions are important for deep portion of actual fault zones, the strength of velocity weakening is of interest when the related faulting behavior is concerned. As a measure of the strength of velocity weakening, the derived ratio b/a fully controlled by pressure solution shows an upper bound of 1.22. Data analyses in previous studies on plagioclase (He et al., 2013) and oceanic basalt (Zhang and He, 2017) shows a range of b/a =1.05-1.2, consistent with the analytical result. The valuesrate effect, which reduces b/a to levels below the upper bound. These values are significantly less than in dry experiments on granite by Mitchell et al.(2016), where b/a ranges from 1.54-2.59 as inferred by reanalyzing their stick-slip data at temperatures of 20°C, 500°C and 600°C. Comparison between the two ranges of b/a helps understand the dominant mechanism of frictional healing at contacts, especially under hydrothermal conditions in fault zones. For comparable ratios of system stiffness to the critical value, numerical simulations with a single-degree-of-freedom system show that a smaller b/a significantly reduces the peak slip velocity as a result of reduced period

Microstructure and temperature dependence of intergranular strains on diffractometric macroscopic residual stress analysis

Energy Technology Data Exchange (ETDEWEB)

Wagner, J.N., E-mail: Julia.Wagner@kit.edu [KNMF, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany); Hofmann, M. [Forschungs-Neutronenquelle Heinz Maier-Leibnitz (FRM II), TU München, Lichtenbergstr. 1, 85747 Garching (Germany); Wimpory, R. [Helmholtz-Zentrum Berlin für Materialien und Energie, D-14109 Berlin Wannsee (Germany); Krempaszky, C. [Christian-Doppler-Labor für Werkstoffmechanik von Hochleistungslegierungen, TU München, Boltzmannstr. 15, 85747 Garching (Germany); Lehrstuhl für Werkstoffkunde und Werkstoffmechanik, TU München, Boltzmannstr. 15, 85747 Garching (Germany); Stockinger, M. [Böhler Schmiedetechnik GmbH and Co KG, Mariazeller Straße 25, 8605 Kapfenberg (Austria)

2014-11-17

Knowledge of the macroscopic residual stresses in components of complex high performance alloys is crucial when it comes to considering the safety and manufacturing aspects of components. Diffraction experiments are one of the key methods for studying residual stresses. However a component of the residual strain determined by diffraction experiments, known as microstrain or intergranular residual strain, occurs over the length scale of the grains and thus plays only a minor role for the life time of such components. For the reliable determination of macroscopic strains (with the minimum influence of these intergranular residual strains), the ISO standard recommends the use of particular Bragg reflections. Here we compare the build-up of intergranular strain of two different precipitation hardened IN 718 (INCONEL 718) samples, with identical chemical composition. Since intergranular strains are also affected by temperature, results from room temperature measurement are compared to results at T=550 °C. It turned out that microstructural parameters, such as grain size or type of precipitates, have a larger effect on the intergranular strain evolution than the influence of temperature at the measurement temperature of T=550 °C. The results also show that the choice of Bragg reflections for the diffractometric residual stress analysis is dependent not only on its chemical composition, but also on the microstructure of the sample. In addition diffraction elastic constants (DECs) for all measured Bragg reflections are given.

Influence of Ti, C and N concentration on the intergranular corrosion behaviour of AISI 316Ti and 321 stainless steels

International Nuclear Information System (INIS)

Pardo, A.; Merino, M.C.; Coy, A.E.; Viejo, F.; Carboneras, M.; Arrabal, R.

2007-01-01

Intergranular corrosion behaviour of 316Ti and 321 austenitic stainless steels has been evaluated in relation to the influence exerted by modification of Ti, C and N concentrations. For this evaluation, electrochemical measurements - double loop electrochemical potentiokinetic reactivation (DL-EPR) - were performed to produce time-temperature-sensitization (TTS) diagrams for tested materials. Transmission (TEM) and scanning electron microscopy (SEM) were used to determine the composition and nature of precipitates. The addition of Ti promotes better intergranular corrosion resistance in stainless steels. The precipitation of titanium carbides reduces the formation of chromium-rich carbides, which occurs at lower concentrations. Also, the reduction of carbon content to below 0.03 wt.% improves sensitization resistance more than does Ti content. The presence of Mo in AISI 316Ti stainless steel reduces chromium-rich carbide precipitation; the reason is that Mo increases the stability of titanium carbides and tends to replace chromium in the formation of carbides and intermetallic compounds, thus reducing the risks of chromium-depletion

Micromechanical Aspects of Transgranular and Intergranular Failure Competition

Czech Academy of Sciences Publication Activity Database

Dlouhý, Ivo; Tarafder, M.; Hadraba, Hynek

2011-01-01

Roč. 465, - (2011), s. 399-402 ISSN 1013-9826 R&D Projects: GA ČR(CZ) GAP107/10/0361 Institutional research plan: CEZ:AV0Z20410507 Keywords : intergranular fracture * cleavage * fracture toughness Subject RIV: JL - Materials Fatigue, Friction Mechanics

A stereological approach for measuring the groove angles of intergranular corrosion

International Nuclear Information System (INIS)

Gwinner, B.; Borgard, J.-M.; Dumonteil, E.; Zoia, A.

2017-01-01

Highlights: • The ICG morphology has been characterized in 3D by X-ray μ-tomography. • The measurement of the angles of the IGC groove on 2D cross sections induces a bias. • A methodology is proposed to estimate the true value of the IGC groove angles in 3D. - Abstract: Non-sensitized austenitic stainless steels can be prone to intergranular corrosion when they are in contact with an oxidizing medium like nitric acid. Intergranular corrosion is characterized by the formation of grooves along the grain boundaries. The angle of these grooves is a key parameter, which directly informs of the intergranular corrosion kinetics. Most of the time, the angles of the grooves are experimentally measured on 2-dimensional cross sections of the corroded samples. This study discusses the relationship between the groove angle measured on 2-dimensional sections and the true groove angle in 3-dimensional space. This approach could also be easily extended to the study of crack angle in the domains of corrosion-fatigue, stress corrosion cracking or mechanical fracture.

Stress corrosion of Zircaloy-4. Fracture mechanics study of the intergranular - transgranular transition

International Nuclear Information System (INIS)

Farina, Silvia B.; Duffo, Gustavo S.

2003-01-01

Stress corrosion cracking susceptibility of Zircaloy-4 wires was studied in 1M NaCl, 1M KBr and 1M KI aqueous solutions, and in iodine alcoholic solutions. In all cases, intergranular attack preceded transgranular propagation. It is generally accepted that the intergranular-transgranular transition occurs when a critical value of the stress intensity factor is reached. In the present work it was confirmed that the transition from intergranular to transgranular propagation cracking in Zircaloy-4 wires also occurs when a critical value of the stress intensity factor is reached. This critical stress intensity factor in wire samples is independent of the solution tested and close to 10 MPa.m-1/2. This value is in good agreement with those reported in the literature measured by different techniques. (author)

Intergranular phase of the Si3 N4 hot pressed with Mg O/Y2 O3

International Nuclear Information System (INIS)

Costa, Celio A.; Todd, Judith A.

1997-01-01

Monolithic and composite Si 3 N 4 hot-pressed with 3% Mgo or 6% Y 2 O 3 were analyzed with X-ray diffraction and transmission electron microscopy. The results showed materials to be composed of β-Si 3 N 4 grains and an intergranular phase which was partially crystalline and partially amorphous. For the materials sintered with Mg O, the identification of the intergranular phase was not conclusive. For the materials sintered with Y 2 O 3 . It was observed that the amount of intergranular crystalline phase decreased as whiskers were added to the material and the intergranular crystalline part had a crystallographic structure similar to yttrium-silicon-oxide-nitride family. (author)

Microstructural Modeling of Dynamic Intergranular and Transgranular Fracture Modes in Zircaloys

Energy Technology Data Exchange (ETDEWEB)

Mohammed, I. [North Carolina State Univ., Raleigh, NC (United States); Zikry, M.A. [North Carolina State Univ., Raleigh, NC (United States); Ziaei, S. [North Carolina State Univ., Raleigh, NC (United States)

2017-04-01

In this time period, we have continued to focus on (i) refining the thermo-mechanical fracture model for zirconium (Zr) alloys subjected to large deformations and high temperatures that accounts for the cracking of ZrH and ZrH2 hydrides, (ii) formulating a framework to account intergranular fracture due to iodine diffusion and pit formation in grain-boundaries (GBs). Our future objectives are focused on extending to a combined population of ZrH and ZrH2 populations and understanding how thermo-mechanical behavior affects hydride reorientation and cracking. We will also refine the intergranular failure mechanisms for grain boundaries with pits.

Mitigation of intergranular stress corrosion cracking in RBMK reactors. Final report of the programme's steering committee

International Nuclear Information System (INIS)

2002-09-01

In 2000 the IAEA initiated an Extrabudgetary Programme on Mitigation of Intergranular Stress Corrosion Cracking in RBMK Reactors to assist countries operating RBMK reactors in addressing the issue in austenitic stainless steel 300 mm diameter piping. Intergranular stress corrosion cracking of austenitic stainless steel piping in BWRs has been a major safety concern since the early seventies. Similar degradation was found in RBMK reactor piping in 1997. Early in 1998 the IAEA responded to requests for assistance from RBMK operating countries on this issue through activities organized in the framework of Technical Co-operation Department regional projects and the Extrabudgetary Programme on the Safety of WWER and RBMK Nuclear Power Plants. Results of these activities were a basis for the formulation of the objective and scope of the Extrabudgetary Programme on Mitigation of Intergranular Stress Corrosion Cracking in RBMK reactors ('the Programme'). The scope of the Programme included in-service inspection, assessment, repair and mitigation, and water chemistry and decontamination. The Programme was pursued by means of exchange of experience, formulation of guidance, transfer of technology, and training, which will assist the RBMK operators to address related safety concerns. The Programme implementation relied on voluntary extrabudgetary financial contributions from Japan, Spain, the United Kingdom and the USA, and on in kind contributions from Finland, Germany and Sweden. The Programme was implemented in close co-ordination with ongoing national and bilateral activities and major inputs to the Programme were provided through the activities of the Swedish International Project Nuclear Safety and of the US DOE International Nuclear Safety Program. The RBMK nuclear power plants in Lithuania, Russian Federation and Ukraine hosted most of the Programme activities. Support of these Member States involved in the Programme was instrumental for its successful completion in

A multiscale constitutive model for intergranular stress corrosion cracking in type 304 austenitic stainless steel

International Nuclear Information System (INIS)

Siddiq, A; Rahimi, S

2013-01-01

Intergranular stress corrosion cracking (IGSCC) is a fracture mechanism in sensitised austenitic stainless steels exposed to critical environments where the intergranular cracks extends along the network of connected susceptible grain boundaries. A constitutive model is presented to estimate the maximum intergranular crack growth by taking into consideration the materials mechanical properties and microstructure characters distribution. This constitutive model is constructed based on the assumption that each grain is a two phase material comprising of grain interior and grain boundary zone. The inherent micro-mechanisms active in the grain interior during IGSCC is based on crystal plasticity theory, while the grain boundary zone has been modelled by proposing a phenomenological constitutive model motivated from cohesive zone modelling approach. Overall, response of the representative volume is calculated by volume averaging of individual grain behaviour. Model is assessed by performing rigorous parametric studies, followed by validation and verification of the proposed constitutive model using representative volume element based FE simulations reported in the literature. In the last section, model application is demonstrated using intergranular stress corrosion cracking experiments which shows a good agreement

Microstructure and intergranular corrosion resistance of UNS S17400 (17-4PH) stainless steel

Energy Technology Data Exchange (ETDEWEB)

Tavares, S.S.M., E-mail: ssmtavares@terra.com.b [Universidade Federal Fluminense - Programa de Pos-graduacao em Engenharia Mecanica (PGMEC), Rua Passo da Patria, 156 - CEP 24210-240 - Niteroi/RJ (Brazil); Silva, F.J. da; Scandian, C. [Universidade Federal do Espirito Santo - Departamento de Engenharia Mecanica - Av. Fernando Ferrrari, 514 - CEP 29075-910 - Vitoria/ES (Brazil); Silva, G.F. da [Universidade Federal Fluminense - Programa de Pos-graduacao em Engenharia Mecanica (PGMEC), Rua Passo da Patria, 156 - CEP 24210-240 - Niteroi/RJ (Brazil); Abreu, H.F.G. de [Universidade Federal do Ceara - Departamento de Engenharia Metalurgica e Materiais - Campus do Pici, Bloco 702 - CEP 60455-760 - Fortaleza/CE (Brazil)

2010-11-15

UNS S17400 or 17-4PH is a precipitation hardening martensitic stainless steel with many industrial applications. Quite different mechanical properties can be produced in this material by varying the aging temperature. In this work, the influence of aging temperature on the intergranular corrosion susceptibility was evaluated by electrochemical and metallographic tests. The microstructural features were investigated by X-ray diffraction, optical and scanning electron microscopy. Intergranular chromium carbide precipitation occurs in specimens aged at high temperatures, although NbC carbides were also observed. The results obtained by double loop electrochemical potentiodynamic reactivation tests (DL-EPR) show that the susceptibility to intergranular corrosion resistance increases with the increase of aging temperature. Healing due to Cr diffusion in the 600-650 {sup o}C range was not observed by DL-EPR tests.

Microstructure and intergranular corrosion resistance of UNS S17400 (17-4PH) stainless steel

International Nuclear Information System (INIS)

Tavares, S.S.M.; Silva, F.J. da; Scandian, C.; Silva, G.F. da; Abreu, H.F.G. de

2010-01-01

UNS S17400 or 17-4PH is a precipitation hardening martensitic stainless steel with many industrial applications. Quite different mechanical properties can be produced in this material by varying the aging temperature. In this work, the influence of aging temperature on the intergranular corrosion susceptibility was evaluated by electrochemical and metallographic tests. The microstructural features were investigated by X-ray diffraction, optical and scanning electron microscopy. Intergranular chromium carbide precipitation occurs in specimens aged at high temperatures, although NbC carbides were also observed. The results obtained by double loop electrochemical potentiodynamic reactivation tests (DL-EPR) show that the susceptibility to intergranular corrosion resistance increases with the increase of aging temperature. Healing due to Cr diffusion in the 600-650 o C range was not observed by DL-EPR tests.

Intergranular corrosion of Ti-stabilized 11 wt% Cr ferritic stainless steel for automotive exhaust systems

Energy Technology Data Exchange (ETDEWEB)

Kim, Jeong Kil [Graduate Institute of Ferrous Technology, Pohang University of Science and Technology, San 31, Pohang 790-784 (Korea, Republic of); Kim, Yeong Ho; Uhm, Sang Ho; Lee, Jong Sub [POSCO Technical Research Center, Pohang, 790-704 (Korea, Republic of); Kim, Kyoo Young [Graduate Institute of Ferrous Technology, Pohang University of Science and Technology, San 31, Pohang 790-784 (Korea, Republic of)], E-mail: kykim@postech.ac.kr

2009-11-15

Intergranular corrosion (IGC) of type 409L ferritic stainless steel (FSS) was investigated. A free-exposure corrosion and a double loop electrochemical potentiokinetic reactivation (DL-EPR) tests were conducted to examine IGC of the FSS. IGC occurred in the specimens aged at the temperature range of 400-600 deg. C that has the sensitization nose located around 600 deg. C. The critical I{sub r}/I{sub a} value was determined to be about 0.03 above which IGC occurred. Based on the analysis of the intergranular precipitates by an energy dispersive spectroscopy (EDS) and a transmission electron microscopy (TEM), IGC was induced by the Cr depletion zone formation due to Cr segregation around intergranular TiC.

On the Preservation of Intergranular Coesite in UHP Eclogite at Yangkou Bay, Sulu belt of eastern China

Science.gov (United States)

Wang, L.; Wang, S.; Brown, M.

2016-12-01

In contrast to coesite that occurs as inclusions in zircon and rock-forming minerals, intergranular coesite is preserved in UHP eclogite at Yangkou in the Sulu belt. The survival of intergranular coesite is intriguing because the eclogite experienced phengite growth and partial melting during exhumation. The coesite eclogite occurs as rootless isoclinal fold noses within quartz-rich schist which contains 10-20 vol% phengite, whereas phengite is absent from coesite eclogite in the fold noses. To evaluate the factors that control preservation of intergranular coesite, four samples representative of different stages along the retrograde P-T path were selected for study. For each sample we determined the number of intergranular coesite grains per cm2 and the OH content of garnet and omphacite. As the number of coesite grains decreases, the bulk rock OH content increases from transformation to quartz of intergranular coesite outside of the fold noses. The fluid is inferred to have been a supercritical fluid probably residual from prograde dehydration but also derived by dissolution of nominally anhydrous minerals. Post-metamorphic-peak deformation combined with fluid percolation along sheared fold limbs induced phengite growth during initial exhumation and then facilitated partial melting. In contrast, fold hinges in competent layers are unfavourable sites for fluid penetration. At Yangkou, the intergranular coesite is preserved in the fold noses where it was protected from both penetrative deformation and fluid ingress. Therefore, the fold noses maintained a relatively dry environment that allowed preservation of the intergranular coesite. Thus, deformation partitioning and strain localization impose local controls on fluid distribution and migration in UHP eclogite. This study informs our understanding of variations in fluid regime during exhumation of deeply subducted continental crust.

Effect of Zr addition on intergranular corrosion of low-chromium ferritic stainless steel

International Nuclear Information System (INIS)

Park, Jin Ho; Kim, Jeong Kil; Lee, Bong Ho; Seo, Hyung Suk; Kim, Kyoo Young

2014-01-01

Addition of Zr to low-Cr ferritic stainless steel forms a mixture of ZrC and Fe 23 Zr 6 precipitates that can prevent intergranular corrosion. Transmission electron microscopy and three-dimensional atom probe analysis suggest that the ZrC and Fe 23 Zr 6 mixture prevents intergranular corrosion in two ways: by acting as a strong carbide former to suppress the formation of Cr-carbide and by acting as a barrier against the diffusion of the solute Cr towards the grain boundary

Meso-microstructural computational simulation of the hydrogen permeation test to calculate intergranular, grain boundary and effective diffusivities

Energy Technology Data Exchange (ETDEWEB)

Jothi, S., E-mail: s.jothi@swansea.ac.uk [College of Engineering, Swansea University, Singleton Park, Swansea SA2 8PP (United Kingdom); Winzer, N. [Fraunhofer Institute for Mechanics of Materials IWM, Wöhlerstraße 11, 79108 Freiburg (Germany); Croft, T.N.; Brown, S.G.R. [College of Engineering, Swansea University, Singleton Park, Swansea SA2 8PP (United Kingdom)

2015-10-05

Highlights: • Characterized polycrystalline nickel microstructure using EBSD analysis. • Development meso-microstructural model based on real microstructure. • Calculated effective diffusivity using experimental electrochemical permeation test. • Calculated intergranular diffusivity of hydrogen using computational FE simulation. • Validated the calculated computation simulation results with experimental results. - Abstract: Hydrogen induced intergranular embrittlement has been identified as a cause of failure of aerospace components such as combustion chambers made from electrodeposited polycrystalline nickel. Accurate computational analysis of this process requires knowledge of the differential in hydrogen transport in the intergranular and intragranular regions. The effective diffusion coefficient of hydrogen may be measured experimentally, though experimental measurement of the intergranular grain boundary diffusion coefficient of hydrogen requires significant effort. Therefore an approach to calculate the intergranular GB hydrogen diffusivity using finite element analysis was developed. The effective diffusivity of hydrogen in polycrystalline nickel was measured using electrochemical permeation tests. Data from electron backscatter diffraction measurements were used to construct microstructural representative volume elements including details of grain size and shape and volume fraction of grains and grain boundaries. A Python optimization code has been developed for the ABAQUS environment to calculate the unknown grain boundary diffusivity.

Multi-scale modeling of inter-granular fracture in UO2

Energy Technology Data Exchange (ETDEWEB)

Chakraborty, Pritam [Idaho National Lab. (INL), Idaho Falls, ID (United States); Zhang, Yongfeng [Idaho National Lab. (INL), Idaho Falls, ID (United States); Tonks, Michael R. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Biner, S. Bulent [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2015-03-01

A hierarchical multi-scale approach is pursued in this work to investigate the influence of porosity, pore and grain size on the intergranular brittle fracture in UO2. In this approach, molecular dynamics simulations are performed to obtain the fracture properties for different grain boundary types. A phase-field model is then utilized to perform intergranular fracture simulations of representative microstructures with different porosities, pore and grain sizes. In these simulations the grain boundary fracture properties obtained from molecular dynamics simulations are used. The responses from the phase-field fracture simulations are then fitted with a stress-based brittle fracture model usable at the engineering scale. This approach encapsulates three different length and time scales, and allows the development of microstructurally informed engineering scale model from properties evaluated at the atomistic scale.

Novel implementation of the use of the EPR-in situ technique (Electrochemical potentiodynamic reactivation) to identify intergranular corrosion susceptability of stainless steels exposed to high temperatures

International Nuclear Information System (INIS)

Munoz, N.; Pineda, Y.; Vera, E.; Sepulveda, H.; Heyn, Andreas

2010-01-01

Austenitic stainless steels (18 % Cr), are often used in pieces that are exposed to temperatures of 450 o C to 900 o C (heat exchangers). At these temperatures sensibilization occurs on the grain boundaries, becoming a key factor in the appearance of intergranular corrosion. In order to prevent this phenomena from occurring 0.3% to 0.8% of niobium is added as an alloying element in the manufacturing process, which prevents the carbon present in the steel combines with the chromium, avoiding the formation of carbides. An electrochemical method for in-situ application was developed to evaluate the corrosive behavior of stainless steel and its susceptibility and degree of sensibilizaton to an intergranular attack. This work shows the effectiveness of this technique in evaluating niobium's inhibitory effect in preventing the formation of chromium carbides on the grain boundaries of 18% chromium steel, and also shows the technique's potentiality in determining how susceptible these steels are to intercrystalline corrosion

Triple-membrane reduces need for ion exchange regeneration

International Nuclear Information System (INIS)

Valcour, H.

1989-01-01

Triple-membrane water treatment systems are comprised of ultrafiltration units for pretreatment, electrodialysis reversal primary demineralizers, reverse osmosis secondary demineralizers, portable ion exchange unit polishing demineralizers, and ultraviolet sterilizers. The triple-membrane process is designed to provide an unprecedented degree of pretreatment to maximize efficiency, durability and reliability of the reverse osmosis, whilst reducing the required regeneration frequency of the ion exchange demineralizer by one to two orders of magnitude. (author)

Microstructural Evidences of Intergranular Pressure Solution during Frictional Sliding at Hydrothermal Conditions

Science.gov (United States)

Ma, X.; Yao, S.; He, C.

2017-12-01

In the framework of rate- and state-dependent friction, velocity weakening is the result of a healing effect at intergranular contacts that is stronger than the instantaneous rate effect. Intergranular pressure solution has been proposed to be a feasible mechanism for the frictional healing effect (He et al., 2013), but to date no substantial evidences have been reported in related microstructures. In this study we report our reanalyses on samples of plagioclase gouge deformed at hydrothermal conditions with effective normal stresses of 100 MPa, 200 MPa, and 300 MPa, pore pressures of 30 MPa and 100 MPa, and temperatures from 100oC to 600oC. With an Inlens image detector in a scanning electron microscope, our focus is to find the evidences of the pressure solution processes during frictional sliding. As it has been difficult to observe the signatures of pressure solution during frictional sliding at the solution sites due to the short contact time of frequently-switching contact pairs, now we focus on the results of precipitation instead, which is the final process of pressure solution. With high magnification, we find the following evidences of intergranular pressure solution: 1) crystal growth as a result of precipitation is ubiquitously observed in deformed samples at temperatures above 200oC; 2) very fine-grained precipitated particles with flaky morphologies typically appear in intensely sheared regions and between relatively large particles in moderately sheared regions; 3) the precipitated grains are concentrated periodically in zones orientated at 45-50 degrees to the fault strike. These observations indicate that intergranular pressure solution is the dominant process responsible for the frictional healing effect.

A fractal model for intergranular fractures in nanocrystals

International Nuclear Information System (INIS)

Lung, C.W.; Xiong, L.Y.; Zhou, X.Z.

1993-09-01

A fractal model for intergranular fractures in nanocrystals is proposed to explain the dependence of fracture toughness with grain size in this range of scale. Based on positron annihilation and internal friction experimental results, we point out that the assumption of a constant grain boundary thickness in previous models is too simplified to be true. (author). 7 refs, 6 figs

Intergranular stress corrosion cracking of ion irradiated 304L stainless steel in PWR environment

International Nuclear Information System (INIS)

Gupta, Jyoti

2016-01-01

IASCC is irradiation - assisted enhancement of intergranular stress corrosion cracking susceptibility of austenitic stainless steel. It is a complex degrading phenomenon which can have a significant influence on maintenance time and cost of PWRs' core internals and hence, is an issue of concern. Recent studies have proposed using ion irradiation (to be specific, proton irradiation) as an alternative of neutron irradiation to improve the current understanding of the mechanism. The objective of this study was to investigate the cracking susceptibility of irradiated SA 304L and factors contributing to cracking, using two different ion irradiations; iron and proton irradiations. Both resulted in generation of point defects in the microstructure and thereby causing hardening of the SA 304L. Material (unirradiated and iron irradiated) showed no susceptibility to intergranular cracking on subjection to SSRT with a strain rate of 5 * 10 -8 s -1 up to 4 % plastic strain in inert environment. But, irradiation (iron and proton) was found to increase intergranular cracking severity of material on subjection to SSRT in simulated PWR primary water environment at 340 C. Correlation between the cracking susceptibility and degree of localization was studied. Impact of iron irradiation on bulk oxidation of SA 304L was studied as well by conducting an oxidation test for 360 h in simulated PWR environment at 340 C. The findings of this study indicate that the intergranular cracking of 304L stainless steel in PWR environment can be studied using Fe irradiation despite its small penetration depth in material. Furthermore, it has been shown that the cracking was similar in both iron and proton irradiated samples despite different degrees of localization. Lastly, on establishing iron irradiation as a successful tool, it was used to study the impact of surface finish and strain paths on intergranular cracking susceptibility of the material. (author) [fr

Air Circulation and Heat Exchange under Reduced Pressures

Science.gov (United States)

Rygalov, Vadim; Wheeler, Raymond; Dixon, Mike; Hillhouse, Len; Fowler, Philip

Low pressure atmospheres were suggested for Space Greenhouses (SG) design to minimize sys-tem construction and re-supply materials, as well as system manufacturing and deployment costs. But rarified atmospheres modify heat exchange mechanisms what finally leads to alter-ations in thermal control for low pressure closed environments. Under low atmospheric pressures (e.g., lower than 25 kPa compare to 101.3 kPa for normal Earth atmosphere), convection is becoming replaced by diffusion and rate of heat exchange reduces significantly. During a period from 2001 to 2009, a series of hypobaric experiments were conducted at Space Life Sciences Lab (SLSLab) NASA's Kennedy Space Center and the Department of Space Studies, University of North Dakota. Findings from these experiments showed: -air circulation rate decreases non-linearly with lowering of total atmospheric pressure; -heat exchange slows down with pressure decrease creating risk of thermal stress (elevated leaf tem-peratures) for plants in closed environments; -low pressure-induced thermal stress could be reduced by either lowering system temperature set point or increasing forced convection rates (circulation fan power) within certain limits; Air circulation is an important constituent of controlled environments and plays crucial role in material and heat exchange. Theoretical schematics and mathematical models are developed from a series of observations. These models can be used to establish optimal control algorithms for low pressure environments, such as a space greenhouse, as well as assist in fundamental design concept developments for these or similar habitable structures.

Intergranular stress corrosion cracking of sensitized stainless steels. Final report

International Nuclear Information System (INIS)

Vyas, B.; Isaacs, H.S.; Weeks, J.R.

1976-12-01

A study was conducted of the intergranular stress corrosion cracking of materials used in Boiling Water Reactors (BWR) aimed at developing an understanding of the mechanism(s) of this mode of failure and at developing tests to determine the susceptibility of a given material to this form of attack

Evolution of interphase and intergranular stresses in Zr-2.5Nb during room temperature deformation

International Nuclear Information System (INIS)

Cai, S.; Daymond, M.R.; Holt, R.A.; Gharghouri, M.A.; Oliver, E.C.

2009-01-01

Both in situ tension and compression tests have been carried out on textured Zr-2.5Nb plate material at room temperature. Deformation along all the three principle plate directions has been studied and the evolution of interphase and intergranular strains along the loading and the principle Poisson's directions has been investigated by neutron diffraction. The evolution of interphase and intergranular strain was determined by the relative phase properties, crystal properties and texture distribution. The average phase behaviors are similar during tension and compression, where the β-phase in this material is stronger than the α-phase. The asymmetric yielding of the α-{0 0 0 2} grain family results in a relatively large intergranular strain in the loading direction during compression and different dependence of strength during tension and compression on texture. The combination of the thermal residual stress and the asymmetric CRSS in the axis gives the {0 0 0 2} grain family a higher strength in compression than in tension

Analysis of defect tubes of fast reactor heat exchanger

International Nuclear Information System (INIS)

Rukhlyada, N.Ya.

2014-01-01

The experimental Auger electron spectroscopy and X-ray diffraction microanalysis data of laboratory investigations of defect tubes of heat exchanger with sodium coolant are presented. Element distribution through depth of corrosion layers form on the side of coolant (sodium) and on the surface contacting with steam in heat exchanger tube is studied. Sodium presence through all thickness of the tube is determined. It is shown that treatment of 12Cr18N9 steel surface by plasma pulses decreases intergranular corrosion susceptibility. It is related with structural changes of surface layer (∼ 20 μm), its enrichment by chromium and formation of chromium oxide protective film [ru

Intergranular and inter-phased boundaries in the materials

International Nuclear Information System (INIS)

Aslanides, A.; Backhaus-Ricoult, M.; Bayle-Guillemaud, P.

2000-01-01

This document collects the abstracts of the talks presented during the colloquium J2IM on the intergranular and inter-phased boundaries in the materials. Around the themes of the interfaces behaviour and grain boundaries defects in materials, these days dealt with the microstructure behaviour in many domains such as the interfaces in batteries, the irradiation damages and the special case of the fuel-cladding interactions, the stressed interfaces, the alumina or silicon carbides substrates. (A.L.B.)

A phenomenological variational multiscale constitutive model for intergranular failure in nanocrystalline materials

KAUST Repository

Siddiq, A.; El Sayed, Tamer S.

2013-01-01

We present a variational multiscale constitutive model that accounts for intergranular failure in nanocrystalline fcc metals due to void growth and coalescence in the grain boundary region. Following previous work by the authors, a nanocrystalline

Conversion of transgranular to intergranular fracture in NiCr steels

Czech Academy of Sciences Publication Activity Database

Hadraba, Hynek; Němec, O.; Dlouhý, Ivo

2008-01-01

Roč. 75, č. 12 (2008), s. 3677-3691 ISSN 0013-7944 R&D Projects: GA AV ČR IAA200410502 Institutional research plan: CEZ:AV0Z20410507 Keywords : intergranular fracture * cleavage * fracture toughness * fracture stress * micromechanics * micromechanism * fractal dimension Subject RIV: JL - Materials Fatigue, Friction Mechanics Impact factor: 1.713, year: 2008

Intergranular stress study of TC11 titanium alloy after laser shock peening by synchrotron-based high-energy X-ray diffraction

Science.gov (United States)

Su, R.; Li, L.; Wang, Y. D.; Nie, Z. H.; Ren, Y.; Zhou, X.; Wang, J.

2018-05-01

The distribution of residual lattice strain as a function of depth were carefully investigated by synchrotron-based high energy X-ray diffraction (HEXRD) in TC11 titanium alloy after laser shock peening (LSP). The results presented big compressive residual lattice strains at surface and subsurface, then tensile residual lattice strains in deeper region, and finally close to zero lattice strains in further deep interior with no plastic deformation thereafter. These evolutions in residual lattice strains were attributed to the balance of direct load effect from laser shock wave and the derivative restriction force effect from surrounding material. Significant intergranular stress was evidenced in the processed sample. The intergranular stress exhibited the largest value at surface, and rapidly decreased with depth increase. The magnitude of intergranular stress was proportional to the severity of the plastic deformation caused by LSP. Two shocks generated larger intergranular stress than one shock.

Intergranular corrosion of 13Cr and 17Cr martensitic stainless steels in accelerated corrosive solution and high-temperature, high-purity water

International Nuclear Information System (INIS)

Ozaki, Toshinori; Ishikawa, Yuichi

1988-01-01

Intergranular corrosion behavior of 13Cr and 17Cr martensitic stainless steels was studied by electrochemical and immersing corrosion tests. Effects of the mEtallurgical and environmental conditions on the intergranular corrosion of various tempered steels were examined by the following tests and discussed. (a) Anodic polarization measurement and electrolytical etching test in 0.5 kmol/m 3 H 2 SO 4 solution at 293 K. (b) Immersion corrosion test in 0.88 kmol/m 3 HNO 3 solution at 293 K. (c) Long-time immersion test for specimens with a crevice in a high purity water at 473 K∼561 K. It was found from the anodic polarization curves in 0.5 kmol/m 3 H 2 SO 4 solution-at 293 K that the steels tempered at 773∼873 K had susceptibility to intergranular corrosion in the potential region indicating a second current maximum (around-0.1 V. vs. SCE). But the steel became passive in the more noble potential region than the second current peak potential, while in the less noble potential region general corrosion occurred independent of its microstructure. The intergranular corrosion occurred due to the localized dissolution along the pre-austenitic grain boundary and the martensitic lath boundary. It could be explained by the same dissolution model of the chromium depleted zone as proposed for the intergranular corrosion of austenitic and ferritic stainless steels. The intergranular corrosion occurred entirely at the free surface in 0.88 kmol/m 3 HNO 3 solution, while in the high temperature and high purity water only the entrance of the crevice corroded. It was also suggested that this intergranular corrosion might serve as the initiation site for stress corrosion cracking of the martensitic stainless steel. (author)

Quantitative assessment of intergranular damage due to PWR primary water exposure in structural Ni-based alloys

International Nuclear Information System (INIS)

Ter-Ovanessian, Benoît; Deleume, Julien; Cloué, Jean-Marc; Andrieu, Eric

2013-01-01

Highlights: ► IG damage occurred on Ni-base alloys during exposure at high temperature water. ► Two characterization methods yield a tomographic analysis of this IG damage. ► Connected or isolated intergranular oxygen/oxide penetrations are quantified. ► Such quantitative description provides information on IGSCC susceptibility. - Abstract: Two nickel-based alloys, alloy 718 and alloy 600, known to have different resistances to IGSCC, were exposed to a simulated PWR primary water environment at 360 °C for 1000 h. The intergranular oxidation damage was analyzed in detail using an original approach involving two characterization methods (Incremental Mechanical Polishing/Microcopy procedure and SIMS imaging) which yielded a tomographic analysis of the damage. Intergranular oxygen/oxide penetrations occurred either as connected or isolated penetrations deep under the external oxide/substrate interface as far as 10 μm for alloy 600 and only 4 μm for alloy 718. Therefore, assessing this damage precisely is essential to interpret IGSCC susceptibility.

Techniques for intergranular crack formation and assessment in alloy 600 base and alloy 182 weld metals

International Nuclear Information System (INIS)

Lee, Tae Hyun; Hwang, Il Soon; Kim, Hong Deok; Kim, Ji Hyun

2015-01-01

A technique developed to produce artificial intergranular stress corrosion cracks in structural components was applied to thick, forged alloy 600 base and alloy 182 weld metals for use in the qualification of nondestructive examination techniques for welded components in nuclear power plants. An externally controlled procedure was demonstrated to produce intergranular stress corrosion cracks that are comparable to service-induced cracks in both the base and weld metals. During the process of crack generation, an online direct current potential drop method using array probes was used to measure and monitor the sizes and shapes of the cracks. A microstructural characterization of the produced cracks revealed realistic conformation of the crack faces unlike those in machined notches produced by an electrodischarge machine or simple fatigue loading using a universal testing machine. A comparison with a destructive metallographic examination showed that the characteristics, orientations, and sizes of the intergranular cracks produced in this study are highly reproducible.

Thresholds of time dependent intergranular crack growth in a nickel disc alloy Alloy 720Li

Directory of Open Access Journals (Sweden)

Li Hangyue

2014-01-01

Full Text Available At high temperatures in air, introducing a dwell period at the peak stress of fatigue cycles promotes time dependent intergranular crack growth which can increase crack growth rates by upto a few orders of magnitude from the rates of transgranular fatigue crack growth in superalloys. It is expected that time dependent intergranular crack growth in nickel-based superalloys may not occur below a critical mechanical driving force, ΔKth−IG, analogous to a fatigue threshold (ΔKth and a critical temperature, Tth. In this study, dwell fatigue crack growth tests have been carefully designed and conducted on Alloy 720Li to examine such thresholds. Unlike a fatigue threshold, the threshold stress intensity factor range for intergranular crack growth is observed to be highly sensitive to microstructure, dwell time and test procedure. The near threshold crack growth behaviour is made complex by the interactions between grain boundary oxidation embrittlement and crack tip stress relaxation. In general, lower ΔKth−IG values are associated with finer grain size and/or shorter dwell times. Often a load increasing procedure promotes stress relaxation and tends to lead to higher ΔKth−IG. When there is limited stress relaxation at the crack tip, similar ΔKth−IG values are measured with load increasing and load shedding procedures. They are generally higher than the fatigue threshold (ΔKth despite faster crack growth rates (da/dN in the stable crack growth regime. Time dependent intergranular crack growth cannot be activated below a temperature of 500 ∘C.

Critical current of the nonuniform Josephson transition at intergranular boundary with random dislocation distribution

International Nuclear Information System (INIS)

Mejlikhov, E.Z.; Farzetdinova, R.M.

1997-01-01

Critical current of inhomogeneous intergranular Josephson transition is calculated in the assumption concerning superconductivity suppression by local strains of boundary dislocations with random distribution

Intergranular penetration of liquid gold into stainless steel

OpenAIRE

Favez, Denis; Deillon, Léa; Wagnière, Jean-Daniel; Rappaz, Michel

2011-01-01

Intergranular penetration of liquid 18 K gold into a superaustenitic stainless steel, which occurs during laser welding of these two materials, has been studied using a C-ring device which can be put under tensile stresses by a screw. It is shown that liquid gold at 1000 degrees C penetrates the immersed stainless steel C-ring at grain boundaries, but only when tensile stresses are applied. Based on the thickness of the peritectic phase that forms all along the liquid crack and on the transve...

Ion exchange filter transition plan for BWRs and PWRs

International Nuclear Information System (INIS)

Garcia, Susan; McElrath, Joel; Varnam, Jeremie; Giannelli, Joseph F.

2014-01-01

Analysis and quantification of reactor water, feedwater, and chemical and volume control system (CVCS) soluble metals and radioisotopes are essential for monitoring species that impact fuel performance, steam generator and heat exchanger performance, mitigation of stress corrosion cracking of reactor piping and internals, radiation fields and ensuring that dose mitigation techniques are effective. Soluble species in the CVCS, feedwater, reactor water and other process sample streams are usually collected on ion exchange membranes after the sample has passed through a 0.45 or 0.1 μm membrane filter. Cationic species are predominantly of interest. Most nuclear plants currently use cation exchange membranes from Toray Industries, Inc. In September 2012, it was reported that Toray Industries, Inc. would discontinue the manufacturing of cation exchange membranes at the end of 2012. Similar reports were received concerning ion exchange membranes manufactured by Pall Corporation. These reports prompted several plants and utilities to begin evaluating other products from various vendors to replace their current ion exchange membranes in preparation for a transition. With this possible change having a potential impact on the water chemistry analyses that are important for monitoring fuel reliability and corrosion and dose control, an initial scoping evaluation of ion exchange membrane availability from various vendor and plant experiences was conducted. Recommended approaches were provided to close identified gaps and reduce burden on nuclear plant chemistry laboratories. Additional work required in 2014, includes an independent laboratory review of membrane performance and in-plant demonstrations. These demonstrations and evaluations will assist the industry by providing the technical input needed to manage a change in membrane use so that preferred processes and media can be identified to minimize any adverse impacts on chemistry analyses that support chemistry control

The probability distribution of intergranular stress corrosion cracking life for sensitized 304 stainless steels in high temperature, high purity water

International Nuclear Information System (INIS)

Akashi, Masatsune; Kenjyo, Takao; Matsukura, Shinji; Kawamoto, Teruaki

1984-01-01

In order to discuss the probability distribution of intergranular stress corrsion carcking life for sensitized 304 stainless steels, a series of the creviced bent beem (CBB) and the uni-axial constant load tests were carried out in oxygenated high temperature, high purity water. The following concludions were resulted; (1) The initiation process of intergranular stress corrosion cracking has been assumed to be approximated by the Poisson stochastic process, based on the CBB test results. (2) The probability distribution of intergranular stress corrosion cracking life may consequently be approximated by the exponential probability distribution. (3) The experimental data could be fitted to the exponential probability distribution. (author)

Kohn–Sham exchange-correlation potentials from second-order reduced density matrices

Energy Technology Data Exchange (ETDEWEB)

Cuevas-Saavedra, Rogelio; Staroverov, Viktor N., E-mail: vstarove@uwo.ca [Department of Chemistry, The University of Western Ontario, London, Ontario N6A 5B7 (Canada); Ayers, Paul W. [Department of Chemistry and Chemical Biology, McMaster University, Hamilton, Ontario L8S 4M1 (Canada)

2015-12-28

We describe a practical algorithm for constructing the Kohn–Sham exchange-correlation potential corresponding to a given second-order reduced density matrix. Unlike conventional Kohn–Sham inversion methods in which such potentials are extracted from ground-state electron densities, the proposed technique delivers unambiguous results in finite basis sets. The approach can also be used to separate approximately the exchange and correlation potentials for a many-electron system for which the reduced density matrix is known. The algorithm is implemented for configuration-interaction wave functions and its performance is illustrated with numerical examples.

Effect of intergranular stress on yielding of 316H during room temperature cyclic loading

International Nuclear Information System (INIS)

Al Mamun, Abdullah; Moat, Richard; Bouchard, John; Kelleher, Joe

2016-01-01

Assessment of cyclic deformation is an integral part of nuclear power plant life assessment code, as many of the components in plant go through scheduled and unscheduled cyclic deformation owing to varying thermal and mechanical stresses. In polycrystalline material like 316H, a type of micro stress known as intergranular stress is generated due to elastic and plastic anisotropies during such cyclic loading. In tension-compression loading cycles, these stresses remain in the material as a residual stress upon unloading to zero stress from the tensile/compressive peak or intermediates stresses. The magnitude of these stresses vary depending on the point in the cycle from which it was unloaded from. When the material is re-loaded either in the same or reverse loading direction these residual stresses increase or decrease the effective stress acting in the material and as such the macroscopic yield stress of the material in subsequent cycle is changed significantly. The magnitude of intergranular stresses in many differently oriented grain families can be measured simultaneously using time of flight (ToF) neutron diffraction technique. In this paper, we have used this technique to experimentally study, how these intergranular stresses affect the yield (proof) stress of 316H at room temperature. (author)

Effects of Dy{sub 71.5}Fe{sub 28.5} intergranular addition on the microstructure and the corrosion resistance of Nd–Fe–B sintered magnets

Energy Technology Data Exchange (ETDEWEB)

Liang, Liping; Ma, Tianyu, E-mail: maty@zju.edu.cn; Zhang, Pei; Yan, Mi, E-mail: mse_yanmi@zju.edu.cn

2015-06-15

To satisfy high-temperature applications, heavy rare-earth (RE) Dy is commonly introduced into the Nd–Fe–B sintered magnets to improve the coercivity. In addition to forming (Nd, Dy){sub 2}Fe{sub 14}B, Dy also exists in the intergranular RE-rich phase. Hence, understanding the effect of Dy on the electrochemical characteristics of the RE-rich phase and corrosion resistance of the magnet is of importance. In this work, eutectic alloy Dy{sub 71.5}Fe{sub 28.5} powders were added into the (Pr{sub 0.2}Nd{sub 0.8}){sub 12.3}Fe{sub bal}B{sub 6.1} magnet through binary-alloy approach to investigate the corrosion resistance of the magnet in electrochemical and hot/humid environments. The results demonstrate that Dy is enriched in the intergranular phase, improving its electrode potential and stability due to the higher electrode potential of Dy than Nd or Pr. As a consequence, the electrode potential difference between the 2:14:1 phase and the RE-rich phase is reduced, improving the corrosion resistance. Furthermore, formation of (Pr, Nd, Dy){sub 2}Fe{sub 14}B shell with stronger local anisotropy surrounding the 2:14:1 phase grains improves the coercivity with a slight remanence loss. Therefore, intergranular adding Dy–Fe alloy powders can obtain both high magnetic properties and good corrosion resistance simultaneously. - Highlights: • Eutectic Dy{sub 71.5}Fe{sub 28.5} powders were intergranular added to NdFeB sintered magnets. • The doped magnet showed improved corrosion resistance compared to Dy-free magnet. • Dy enrichment in RE-rich intergranular phase improved its electrode potential. • (Nd, Dy){sub 2}Fe{sub 14}B shell was expected to form in the surface of Nd{sub 2}Fe{sub 14}B grains. • Both corrosion resistance and coercivity were improved in Dy–Fe doped magnet.

First-principles study of the effects of halogen dopants on the properties of intergranular films in silicon nitride ceramics

International Nuclear Information System (INIS)

Painter, Gayle S.; Becher, Paul F.; Kleebe, H.-J.; Pezzotti, G.

2002-01-01

The nanoscale intergranular films that form in the sintering of ceramics often occur as adherent glassy phases separating the crystalline grains in the ceramic. Consequently, the properties of these films are often equal in importance to those of the constituent grains in determining the ceramic's properties. The measured characteristics of the silica-rich phase separating the crystalline grains in Si 3 N 4 and many other ceramics are so reproducible that SiO 2 has become a model system for studies of intergranular films (IGF's). Recently, the influence of fluorine and chlorine dopants in SiO 2 -rich IGF's in silicon nitride was precisely documented by experiment. Along with the expected similarities between the halogens, some dramatically contrasting effects were found. But the atomic-scale mechanisms distinguishing the effects F and Cl on IGF behavior have not been well understood. First-principles density functional calculations reported here provide a quantum-level description of how these dopant-host interactions affect the properties of IGF's, with specific modeling of F and Cl in the silica-rich IGF in silicon nitride. Calculations were carried out for the energetics, structural changes, and forces on the atoms making up a model cluster fragment of an SiO 2 intergranular film segment in silicon nitride with and without dopants. Results show that both anions participate in the breaking of bonds within the IGF, directly reducing the viscosity of the SiO 2 -rich film and promoting decohesion. Observed differences in the way fluorine and chlorine affect IGF behavior become understandable in terms of the relative stabilities of the halogens as they interact with Si atoms that have lost one if their oxygen bridges

Grain boundary segregation and intergranular failure

International Nuclear Information System (INIS)

White, C.L.

1980-01-01

Trace elements and impurities often segregate strongly to grain boundaries in metals and alloys. Concentrations of these elements at grain boundaries are often 10 3 to 10 5 times as great as their overall concentration in the alloy. Because of such segregation, certain trace elements can exert a disproportionate influence on material properties. One frequently observed consequence of trace element segregation to grain boundaries is the occurrence of grain boundary failure and low ductility. Less well known are incidences of improved ductility and inhibition of grain boundary fracture resulting from trace element segregation to grain boundaries in certain systems. An overview of trace element segregation and intergranular failure in a variety of alloy systems as well as preliminary results from studies on Al 3% Li will be presented

The distribution of intergranular gaps along α tracks recorded in ionographic emulsions

International Nuclear Information System (INIS)

Wittendorp-Rechenmann, E.; Senger, B.; Koziel-Vigneron, V.; Rechenmann, R.V.

1990-01-01

Detailed microscopic analyses performed at high statistics (size: 1100) on 8.776 MeV α tracks materialised in nuclear emulsion demonstrated a distribution of intergranular gaps along the primary ion's path that was not only non-random but also fluctuated significantly with the energy of the projectile. The highest and lowest gap frequencies measured correspond to the energy region of 0.7 - 1.5 MeV and 7 MeV, respectively. The gap length distributions followed an exponential law, a known characteristic of the intergranular gaps distributed along the tracks of high energy charged particles. A tentative interpretation of these observations has been undertaken in terms of spatial distributions of δ rays around the incoming ion's path, by applying the Double-Differential Cross-Section Mixed Treatment to the geometrical configuration of the AgBr microcrystals embedded in the gelatin matrix. At this preliminary stage of our modelling, the main experimental data could already be reproduced satisfactorily. (author)

Evaluation of austenitic stainless steels for transpassive corrosion by metal purification technology. Synergistic effect of Si and P on intergranular corrosion of Fe-18Cr-14Ni alloys

International Nuclear Information System (INIS)

Mayuzumi, Masami; Ohta, Joji; Kako, Kenji; Kawakami, Eishi

2001-01-01

The synergistic effect of Si, Mn, C, P, and S on the transpassive corrosion of HP18Cr-14Ni alloys was studied in 13N nitric acid. The specimens were fabricated using a cold crucible method in a high-vacuum chamber to reduce contamination. The additions of Si<1% and Mn<2% had no effect on the corrosion behavior of HP18Cr-14Ni alloys, and the addition of Si<1% also had no effect on the corrosion behavior of HP18Cr-14Ni-1Mn alloys, although 1% Si induced intergranular corrosion in both the alloys. Thus, HP18Cr-14Ni-1Mn-0.5Si alloys were selected to evaluate the effects of C, P and S (100 ppm each). The addition of P, and the co-addition of C, P, and S to HP18Cr-14Ni-1Mn-0.5Si induced intergranular corrosion of the same degree in the solution annealed condition. This result suggests the synergistic effect of Si and P to induce intergranular corrosion, since the single addition of Si or P to this level did not lead to intergranular corrosion of HP18Cr-14Ni alloys. HP18Cr-14Ni-1Mn-0.5Si alloys containing C, P, and S at the 100 ppm level each showed superior corrosion resistance compared to a commercial Type 304L in 13N nitric acid. (author)

Intergranular corrosion susceptibility in supermartensitic stainless steel weldments

Energy Technology Data Exchange (ETDEWEB)

Aquino, J.M. [Sao Carlos Federal University (UFSCar), Materials Engineering Department, Rodovia Washington Luis, km 235, CEP 13565-905, Sao Carlos, SP (Brazil)], E-mail: dsek@power.ufscar.br; Della Rovere, C.A.; Kuri, S.E. [Sao Carlos Federal University (UFSCar), Materials Engineering Department, Rodovia Washington Luis, km 235, CEP 13565-905, Sao Carlos, SP (Brazil)

2009-10-15

The intergranular corrosion susceptibility in supermartensitic stainless steel (SMSS) weldments was investigated by the double loop - electrochemical potentiokinetic reactivation (DL-EPR) technique through the degree of sensitization (DOS). The results showed that the DOS decreased from the base metal (BM) to the weld metal (WM). The heat affected zone (HAZ) presented lower levels of DOS, despite of its complex precipitation mechanism along the HAZ length. Chromium carbide precipitate redissolution is likely to occur due to the attained temperature at certain regions of the HAZ during the electron beam welding (EBW). Scanning electron microscopy (SEM) images showed preferential oxidation sites in the BM microstructure.

Towards modeling intergranular stress corrosion cracks on grain size scales

International Nuclear Information System (INIS)

Simonovski, Igor; Cizelj, Leon

2012-01-01

Highlights: ► Simulating the onset and propagation of intergranular cracking. ► Model based on the as-measured geometry and crystallographic orientations. ► Feasibility, performance of the proposed computational approach demonstrated. - Abstract: Development of advanced models at the grain size scales has so far been mostly limited to simulated geometry structures such as for example 3D Voronoi tessellations. The difficulty came from a lack of non-destructive techniques for measuring the microstructures. In this work a novel grain-size scale approach for modelling intergranular stress corrosion cracking based on as-measured 3D grain structure of a 400 μm stainless steel wire is presented. Grain topologies and crystallographic orientations are obtained using a diffraction contrast tomography, reconstructed within a detailed finite element model and coupled with advanced constitutive models for grains and grain boundaries. The wire is composed of 362 grains and over 1600 grain boundaries. Grain boundary damage initialization and early development is then explored for a number of cases, ranging from isotropic elasticity up to crystal plasticity constitutive laws for the bulk grain material. In all cases the grain boundaries are modeled using the cohesive zone approach. The feasibility of the approach is explored.

Intergranular stress corrosion in soldered joints of stainless steel 304.; Corrosion intergranular bajo esfuerzo en uniones soldadas de acero inoxidable 304

Energy Technology Data Exchange (ETDEWEB)

Zamora R, L [Instituto Nacional de Investigaciones Nucleares, Mexico City (Mexico)

1994-12-31

The intergranular stress cracking of welded joints of austenitic stainless steel, AISI 304, is a serious problem in BWR type reactors. It is associated with the simultaneous presence of three factors; stress, a critical media and sensibilization (DOS). EPR technique was used in order to verify the sensibilization degree in the base metal, and the zone affected by heat and welding material. The characterization of material was done. The objective of this work is the study of microstructure and the evaluation of EPR technique used for the determination of DOS in a welded plate of austenitic stainless steel AISI 304. (Author).

The intergranular corrosion susceptibility of 2024 Al alloy during re–ageing after solution treating and cold–rolling

International Nuclear Information System (INIS)

Wang, Zhixiu; Chen, Peng; Li, Hai; Fang, Bijun; Song, Renguo; Zheng, Ziqiao

2017-01-01

Highlights: • No intergranular corrosion occured for the peak–re–aged and over–re–aged 2024 Al alloy. • Absence of intergranular corrosion in the re–aged samples resulted from no continuous grain boundary S–Al_2CuMg phase. • Aggregated pits were observed in the over–re–aged samples. • Aggregated pitting corrosion was related to the preferential precipitation of S–phase on the dislocation cell walls. - Abstract: The intergranular corrosion (IGC) susceptibility of 2024 Al alloy during re–ageing after solution treating and cold–rolling was investigated by accelerated corrosion testing, open circuit potential testing, transmission electron microscopy and scanning electron microscopy. The absence of IGC in both the peak–re–aged and over–re–aged samples is related to the dislocation pile–ups which prevent the supersaturated solutes from diffusing into the grain boundaries and precipitating the continuous S–Al_2CuMg phase. The aggregated pitting corrosion in the over–re–aged samples arises from the S–phase precipitates on the dislocation cell walls which accelerate the anodic dissolution of the cell interiors.

Investigation of intergranular stress corrosion cracking in the fuel pool at Three Mile Island Unit 1

International Nuclear Information System (INIS)

Czajkowski, C.J.

1985-01-01

An intergranular stress corrosion cracking failure of 304 stainless steel pipe in 2000 ppM B as H 3 BO 3 + H 2 O at 100 0 C has been investigated. Constant extension rate testing has produced an intergranular type failure in material in air. Chemical analysis was performed on both the base metal and weld material, in addition to fractography, EPR testing and optical microscopy in discerning the mode of failure. Various effects of Cl - , O 2 , and MnS are discussed. The results have indicated that the cause of failure was the severe sensitization coupled with probable contamination by S and possibly by Cl ions

Molecular-dynamics Simulation-based Cohesive Zone Representation of Intergranular Fracture Processes in Aluminum

Science.gov (United States)

Yamakov, Vesselin I.; Saether, Erik; Phillips, Dawn R.; Glaessgen, Edward H.

2006-01-01

A traction-displacement relationship that may be embedded into a cohesive zone model for microscale problems of intergranular fracture is extracted from atomistic molecular-dynamics simulations. A molecular-dynamics model for crack propagation under steady-state conditions is developed to analyze intergranular fracture along a flat 99 [1 1 0] symmetric tilt grain boundary in aluminum. Under hydrostatic tensile load, the simulation reveals asymmetric crack propagation in the two opposite directions along the grain boundary. In one direction, the crack propagates in a brittle manner by cleavage with very little or no dislocation emission, and in the other direction, the propagation is ductile through the mechanism of deformation twinning. This behavior is consistent with the Rice criterion for cleavage vs. dislocation blunting transition at the crack tip. The preference for twinning to dislocation slip is in agreement with the predictions of the Tadmor and Hai criterion. A comparison with finite element calculations shows that while the stress field around the brittle crack tip follows the expected elastic solution for the given boundary conditions of the model, the stress field around the twinning crack tip has a strong plastic contribution. Through the definition of a Cohesive-Zone-Volume-Element an atomistic analog to a continuum cohesive zone model element - the results from the molecular-dynamics simulation are recast to obtain an average continuum traction-displacement relationship to represent cohesive zone interaction along a characteristic length of the grain boundary interface for the cases of ductile and brittle decohesion. Keywords: Crack-tip plasticity; Cohesive zone model; Grain boundary decohesion; Intergranular fracture; Molecular-dynamics simulation

Three-dimensional study of grain boundary engineering effects on intergranular stress corrosion cracking of 316 stainless steel in high temperature water

Science.gov (United States)

Liu, Tingguang; Xia, Shuang; Bai, Qin; Zhou, Bangxin; Zhang, Lefu; Lu, Yonghao; Shoji, Tetsuo

2018-01-01

The intergranular cracks and grain boundary (GB) network of a GB-engineered 316 stainless steel after stress corrosion cracking (SCC) test in high temperature high pressure water of reactor environment were investigated by two-dimensional and three-dimensional (3D) characterization in order to expose the mechanism that GB-engineering mitigates intergranular SCC. The 3D microstructure shown that the essential characteristic of the GB-engineered microstructure is formation of many large twin-boundaries as a result of multiple-twinning, which results in the formation of large grain-clusters. The large grain-clusters played a key role to the improvement of intergranular SCC resistance by GB-engineering. The main intergranular cracks propagated in a zigzag along the outer boundaries of these large grain-clusters because all inner boundaries of the grain-clusters were twin-boundaries (∑3) or twin-related boundaries (∑3n) which had much lower susceptibility to SCC than random boundaries. These large grain-clusters had tree-ring-shaped topology structure and very complex morphology. They got tangled so that difficult to be separated during SCC, resulting in some large crack-bridges retained in the crack surface.

Achieving reduced fouling of cooling water exchangers with stainless steel tubes

International Nuclear Information System (INIS)

Iftikhar, A.; Mir, N.

2010-01-01

Good performance of cooling water heat exchangers plays a vital role in the over all energy efficiency of a chemical plant. Heavy fouling on carbon steel tubes of the cooling water exchangers was causing poor performance and frequent cleaning requirement. The carbon steel tubes were replaced with stainless steel tubes. Improved performance was achieved and cleaning frequency reduced. The paper covers the details of study and methodology applied for the above changes along with summary of results. (author)

Order in nanometer thick intergranular films at Au-sapphire interfaces

Energy Technology Data Exchange (ETDEWEB)

Baram, Mor [Department of Materials Engineering, Technion-Israel Institute of Technology, Haifa 32000 (Israel); Garofalini, Stephen H. [Department of Materials Science and Engineering, Rutgers University, Piscataway, NJ 08854-8065 (United States); Kaplan, Wayne D., E-mail: kaplan@tx.technion.ac.il [Department of Materials Engineering, Technion-Israel Institute of Technology, Haifa 32000 (Israel)

2011-08-15

Highlights: {yields} Au particles were equilibrated on (0 0 0 1) sapphire in the presence of anorthite. {yields} 1.2 nm thick equilibrium films (complexions) were formed at the Au-sapphire interfaces. {yields} Quantitative HRTEM was used to study the atomistic structure of the films. {yields} Structural order was observed in the 1.2 nm thick films adjacent to the sapphire crystal. {yields} This demonstrates that ordering is an intrinsic part of equilibrium intergranular films. - Abstract: In recent years extensive studies on interfaces have shown that {approx}1 nm thick intergranular films (IGF) exist at interfaces in different material systems, and that IGF can significantly affect the materials' properties. However, there is great deal of uncertainty whether such films are amorphous or partially ordered. In this study specimens were prepared from Au particles that were equilibrated on sapphire substrates in the presence of anorthite glass, leading to the formation of 1.2 nm thick IGF at the Au-sapphire interfaces. Site-specific cross-section samples were characterized using quantitative high resolution transmission electron microscopy to study the atomistic structure of the films. Order was observed in the 1.2 nm thick films adjacent to the sapphire crystal in the form of 'Ca cages', experimentally demonstrating that ordering is an intrinsic part of IGF, as predicted from molecular dynamics and diffuse interface theory.

Effect of aging time on intergranular corrosion behavior of a newly developed LDX 2404 lean duplex stainless steel

Energy Technology Data Exchange (ETDEWEB)

Zhao, Hui [School of Materials Engineering, Shanghai University of Engineering Science, Shanghai 201620 (China); Zhang, Ziying, E-mail: zzying@sues.edu.cn [School of Materials Engineering, Shanghai University of Engineering Science, Shanghai 201620 (China); Zhang, Huizhen [School of Management, University of Shanghai for Science and Technology, Shanghai 200093 (China); Hu, Jun [School of Materials Engineering, Shanghai University of Engineering Science, Shanghai 201620 (China); Li, Jin [Department of Materials Science, Fudan University, Shanghai 200433 (China)

2016-07-05

The effect of aging at 700 °C for various times on the intergranular corrosion behavior of LDX 2404 duplex stainless steel is investigated by morphological observation and electrochemical detection. Scanning electronic microscopy and transmission electronic microscopy analysis reveal that Cr{sub 2}N, M{sub 23}C{sub 6} and the sigma and chi phases nucleate simultaneously at the initial stages of aging. The granular particles of sigma phase grow larger but fewer with the increase of aging time. The electrochemical detection results show that intergranular corrosion become more severe and the corrosion type evolves from intergranular corrosion into general corrosion as the holding time extends to 48 h. - Highlights: • The IGC behavior of aged LDX 2404 is investigated. • Cr{sub 2}N, M{sub 23}C{sub 6} and the σ and χ phases nucleate simultaneously at the initial stages of aging. • IGC resistance decreases with the increase of aging time. • The corrosion type evolves from IGC into general corrosion for longer aging times.

Influence of C, N and Ti concentration on the intergranular corrosion resistance of AISI 316 Ti stainless steel

Energy Technology Data Exchange (ETDEWEB)

Pardo, A.; Merino, M.C.; Carboneras, M.; Coy, A.E.; Viejo, F.; Arrabal, R.; Munoz, J.A. [Departamento de Ciencia de Materiales, Facultad de Quimica, Universidad Complutense, 28040, Madrid (Spain)

2004-07-01

The influence of Ti, C, and N concentration on the intergranular corrosion resistance of AISI 316 Ti stainless steel has been studied. A kinetic study of the corrosion process has been carried out using gravimetric tests according to ASTM A-262 practices B and C (Streicher and Huey, respectively). The TTS diagrams were drawn as a function of alloying elements concentration (C, N and Ti). Materials characterization under several test conditions was carried out using Scanning Electron Microscopy (SEM) analysing microstructural characteristics and the attack microstructure. The chemical resistance of these steels to intergranular test was function of N, C and Ti concentration. High Ti and N concentration favoured the precipitation of TiN during the material manufacture process. N forms TiN very stable, causing the removal of Ti from the matrix and, indirectly, favouring the Cr{sub 23}C{sub 6} precipitation during the sensitization process and increasing the corrosion rate. In order to inhibit the intergranular corrosion in these materials the N and Ti concentrations must be optimised. (authors)

Influence of C, N and Ti concentration on the intergranular corrosion resistance of AISI 316 Ti stainless steel

International Nuclear Information System (INIS)

Pardo, A.; Merino, M.C.; Carboneras, M.; Coy, A.E.; Viejo, F.; Arrabal, R.; Munoz, J.A.

2004-01-01

The influence of Ti, C, and N concentration on the intergranular corrosion resistance of AISI 316 Ti stainless steel has been studied. A kinetic study of the corrosion process has been carried out using gravimetric tests according to ASTM A-262 practices B and C (Streicher and Huey, respectively). The TTS diagrams were drawn as a function of alloying elements concentration (C, N and Ti). Materials characterization under several test conditions was carried out using Scanning Electron Microscopy (SEM) analysing microstructural characteristics and the attack microstructure. The chemical resistance of these steels to intergranular test was function of N, C and Ti concentration. High Ti and N concentration favoured the precipitation of TiN during the material manufacture process. N forms TiN very stable, causing the removal of Ti from the matrix and, indirectly, favouring the Cr 23 C 6 precipitation during the sensitization process and increasing the corrosion rate. In order to inhibit the intergranular corrosion in these materials the N and Ti concentrations must be optimised. (authors)

Reducing nitrogen crossover in microbial reverse-electrodialysis cells by using adjacent anion exchange membranes and anion exchange resin

KAUST Repository

Wallack, Maxwell J.; Geise, Geoffrey M.; Hatzell, Marta C.; Hickner, Michael A.; Logan, Bruce E.

2015-01-01

Microbial reverse electrodialysis cells (MRECs) combine power generation from salinity gradient energy using reverse electrodialysis (RED), with power generation from organic matter using a microbial fuel cell. Waste heat can be used to distill ammonium bicarbonate into high (HC) and low salt concentration (LC) solutions for use in the RED stack, but nitrogen crossover into the anode chamber must be minimized to avoid ammonia loses, and foster a healthy microbial community. To reduce nitrogen crossover, an additional low concentration (LC) chamber was inserted before the anode using an additional anion exchange membrane (AEM) next to another AEM, and filled with different amounts of anion or cation ion exchange resins. Addition of the extra AEM increased the ohmic resistance of the test RED stack from 103 Ω cm2 (1 AEM) to 295 Ω cm2 (2 AEMs). However, the use of the anion exchange resin decreased the solution resistance of the LC chamber by 74% (637 Ω cm2, no resin; 166 Ω cm2 with resin). Nitrogen crossover into the anode chamber was reduced by up to 97% using 50% of the chamber filled with an anion exchange resin compared to the control (no additional chamber). The added resistance contributed by the use of the additional LC chamber could be compensated for by using additional LC and HC membrane pairs in the RED stack.

Intergranular fracture stress and phosphorus grain boundary segregation of a Mn-Ni-Mo steel

International Nuclear Information System (INIS)

Naudin, C.; Frund, J.M.; Pineau, A.

1999-01-01

Nuclear Reactor Pressure Vessel (RPV) steel A508 class 3 which is a low alloyed steel is not usually sensitive to reversible temper embrittlement when properly heat treated. However heterogeneous zones may be present in particular near the inner side of the vessel. These zones result from the segregation of the alloying elements (C, Mn, Ni, Mo) and impurities (S, P) taking place during solidification of the material. They are called segregated zones (or ghost lines). They can reach 2 mm thick along the radius and 30 mm long through the circumferential direction. Their susceptibility to reversible temper embrittlement is mainly due to grain boundary phosphorus segregation triggering brittle intergranular fracture when the material is tested at low temperature. In this material like in other steels the influence of some other alloying elements (Mo, Mn...) is clearly significant and should also be taken into account. But phosphorus effect has proved to be predominant. The aim of the present study is therefore to find out a quantitative relationship between grain boundary phosphorus segregation and critical intergranular fracture stress. A synthetic steel with a chemical composition representative of an average segregated zone was prepared for the present study. A number of heat treatments were applied to reach different embrittlement conditions. Then brittle fracture properties were obtained by performing cryogenic fracture tests on notched tensile specimens while the corresponding grain boundary phosphorus levels were measured by Auger electron spectroscopy. Systematic fractographic observations were carried out. Moreover an attempt to determine the influence of temperature on the critical intergranular fracture stress was made

The study of intergranular corrosion in aircraft aluminium alloys using X-ray tomography

International Nuclear Information System (INIS)

Knight, S.P.; Salagaras, M.; Trueman, A.R.

2011-01-01

Research highlights: → IGC is stochastic, where initiation is statistical and growth kinetics was somewhat predictable. → Dissolved oxygen concentration was more important than the concentration of salt in the droplet. → A limiting depth occurred for AA2024, whereas no limiting depth occurs for AA7050 after 168 h exposure. → A limiting depth may be controlled by the transport of dissolved oxygen down the corrosion fissure. → A limiting IGC depth is dependent on the overpotential of the SDZ (adjacent to the grain boundary). - Abstract: Atmospheric corrosion is one of the leading causes of structural damage to aircraft. Of particular importance is pitting and intergranular corrosion, which can develop into fatigue cracks, stress corrosion cracks, or exfoliation. Therefore it is of interest to the Australian Defence Force (ADF) to understand how corrosion ensues in susceptible aircraft aluminium alloys, such as AA2024-T351 and 7050-T7451. However, there are many difficulties in measuring the extent of intergranular corrosion, since it is predominantly hidden below the surface. Traditionally, cross-sectioning has been used to view and measure the depth of attack. In the present work, 2 mm diameter pin specimens were contaminated with a droplet of 3.5% NaCl and exposed to constant humidity that resulted in intergranular corrosion. X-ray computed tomography was then used to non-destructively assess the depth and volume of corrosion both as a function of time in 97% relative humidity, and as a function of relative humidity after 168 h exposure. Both corrosion depth and volume increased with time, but there was evidence for a limiting depth in AA2024. Depth and volume also increased with relative humidity of the environment, for which the time-of-wetness and oxygen concentration of the droplets were considered the important factors in driving the corrosion process.

Intergranular fracture in UO2: derivation of traction-separation law from atomistic simulations

Energy Technology Data Exchange (ETDEWEB)

Yongfeng Zhang; Paul C Millett; Michael R Tonks; Xian-Ming Bai; S Bulent Biner

2013-10-01

In this study, the intergranular fracture behavior of UO2 was studied by molecular dynamics simulations using the Basak potential. In addition, the constitutive traction-separation law was derived from atomistic data using the cohesive-zone model. In the simulations a bicrystal model with the (100) symmetric tilt E5 grain boundaries was utilized. Uniaxial tension along the grain boundary normal was applied to simulate Mode-I fracture. The fracture was observed to propagate along the grain boundary by micro-pore nucleation and coalescence, giving an overall intergranular fracture behavior. Phase transformations from the Fluorite to the Rutile and Scrutinyite phases were identified at the propagating crack tips. These new phases are metastable and they transformed back to the Fluorite phase at the wake of crack tips as the local stress concentration was relieved by complete cracking. Such transient behavior observed at atomistic scale was found to substantially increase the energy release rate for fracture. Insertion of Xe gas into the initial notch showed minor effect on the overall fracture behavior.

Determination of susceptibility to intergranular corrosion of stainless steels type X5CrNi18-10 in field

Directory of Open Access Journals (Sweden)

Bore V. Jegdic

2016-12-01

Full Text Available In this paper, the DL EPR method (electrochemical potentiokinetic reactivation with double loop was modified and used to study the susceptibility to intergranular corrosion and stress corrosion cracking of a stainless steel type X5CrNi18-10. The tests were performed in a special electrochemical cell, with the electrolyte in the gel form. Modified DL EPR method is characterized by simple and high accuracy measurements as well as repeatability of the test results. The indicator of susceptibility to intergranular corrosion (Qr/QpGBA obtained by modified DL EPR method is in a very good agreement with the same indicator obtained by standard DL EPR method. The modified DL EPR method is quantitative and highly selective method. Small differences in the susceptibility of the stainless steel type CrNi18-10 to intergranular corrosion and stress corrosion cracking can be determined. Test results can be obtained in a short time. The cost of tests performed by modified DL EPR method is much lower than the cost of tests by conventional chemical methods. Modified DL EPR method can be applied in the field on the stainless steels constructions.

Influence of the selected structural parameter on a depth of intergranular corrosion of Al-Si7-Mg0,3 aluminum alloy

Directory of Open Access Journals (Sweden)

L. Bernat

2015-10-01

Full Text Available The paper presents an influence of the Dendrite Arm Spacing (DAS microstructure parameter on the intergranular corrosion of AlSi7Mg aluminum alloy. The samples were subjected to the corrosion process for: 2,5; 12; 24; 48 and 96 hours in NaCl + HCl + H2O solution. It was noted that the DAS parameter significantly influenced on a distribution and depth of the intergranular corrosion of the hypoeutectic Al - Si - Mg silumin.

Intergranular Corrosion of 316L Stainless Steel by Aging and UNSM (Ultrasonic Nano-crystal Surface Modification) treatment

International Nuclear Information System (INIS)

Lee, J. H.; Kim, Y. S.

2015-01-01

Austenitic stainless steels have been widely used in many engineering fields because of their high corrosion resistance and good mechanical properties. However, welding or aging treatment may induce intergranular corrosion, stress corrosion cracking, pitting, etc. Since these types of corrosion are closely related to the formation of chromium carbide in grain boundaries, the alloys are controlled using methods such as lowering the carbon content, solution heat treatment, alloying of stabilization elements, and grain boundary engineering. This work focused on the effects of aging and UNSM (Ultrasonic Nano-crystal Surface Modification) on the intergranular corrosion of commercial 316L stainless steel and the results are discussed on the basis of the sensitization by chromium carbide formation and carbon segregation, residual stress, grain refinement, and grain boundary engineering

Influence of the grain boundary atomic structure on the intergranular precipitation

International Nuclear Information System (INIS)

Le Coze, J.

1975-01-01

The number of intergranular precipitates after long time annealing is calculated taking into account nucleation, growth and coarsening. With intermediate supersaturation, the great number of precipitates which is observed in some boundaries may have different causes: in low misorientation boundaries and (111) twin, the maxima come from semi-coherent nucleation with one grain; in the other boundaries, the maxima are connected with a great number of high energy atomic sites. Depending on supersaturation, some maxima may disappear whereas others are reinforced [fr

Determination of the equivalent intergranular void ratio - Application to the instability and the critical state of silty sand

Directory of Open Access Journals (Sweden)

Nguyen Trung-Kien

2017-01-01

Full Text Available This paper presents an experimental study of mechanical response of natural Camargue silty sand. The analysis of test results used the equivalent intergranular void ratio instead of the global void ratio. The calculation of equivalent intergranular void ratio requires the determination of parameter b which represents, physically, the fraction of active fines participating on the chain forces network, hence the strength of the soil. A new formula for determining the parameter b by using an approach based on the coordination number distribution and probability calculation is proposed. The validation of the developed relationship was done through back-analysis of published datasets in literature on the effect of fines content on silty sand behavior. It is shown that the equivalent intergranular void ratio calculated with the b value obtained by the new formula is able to provide strong correlation to not only the critical state of but also the onset of instability of various silty sands, in different terms as peak deviator stress, peak stress ratio or cyclic resistance. Therefore, it is suggested that the use of the equivalent void ratio concept and the new b calculating formula is highly desirable in predicting of the silty sand behavior.

Intergranular stress corrosion in soldered joints of stainless steel 304

International Nuclear Information System (INIS)

Zamora R, L.

1994-01-01

The intergranular stress cracking of welded joints of austenitic stainless steel, AISI 304, is a serious problem in BWR type reactors. It is associated with the simultaneous presence of three factors; stress, a critical media and sensibilization (DOS). EPR technique was used in order to verify the sensibilization degree in the base metal, and the zone affected by heat and welding material. The characterization of material was done. The objective of this work is the study of microstructure and the evaluation of EPR technique used for the determination of DOS in a welded plate of austenitic stainless steel AISI 304. (Author)

Oxidation assisted intergranular cracking under loading at dynamic strain aging temperatures in Inconel 718 superalloy

Energy Technology Data Exchange (ETDEWEB)

Rezende, M.C., E-mail: monica_crezende@hotmail.com [Universidade Federal do Rio de Janeiro, Departamento de Engenharia Metalúrgica e de Materiais, C.P. 68505, Rio de Janeiro 21945-970 (Brazil); Araújo, L.S.; Gabriel, S.B. [Universidade Federal do Rio de Janeiro, Departamento de Engenharia Metalúrgica e de Materiais, C.P. 68505, Rio de Janeiro 21945-970 (Brazil); Dille, J. [Université Libre de Bruxelles, 4MAT Department, Av. F. Roosevelt 50, C.P. 194/03, Brussels (Belgium); Almeida, L.H. de [Universidade Federal do Rio de Janeiro, Departamento de Engenharia Metalúrgica e de Materiais, C.P. 68505, Rio de Janeiro 21945-970 (Brazil)

2015-09-15

Highlights: • Mechanical properties are controlled by DSA, precipitation hardening and OAIC. • Between 600 and 700 °C the critical strain for serrations increases with temperature. • This is related to the consumption of matrix elements (especially Nb: for γ′ and γ″). • A reduction in ductility occurs (related to the OAIC) when the DSA is no longer effective. • This reduction is accompanied by an increase in intergranular brittle fracture. - Abstract: It is well established that 718 superalloy exhibits brittle intergranular cracking when deformed under tension at temperatures above 600 °C. This embrittlement effect is related with grain boundary penetration by oxygen (Oxygen Assisted Intergranular Cracking – OAIC). Simultaneously, impacting on its mechanical properties, the precipitation of coherent γ′ and γ″ phases occur above 650 °C and Dynamic Strain Aging (DSA) occurs in the temperature range between 200 and 800 °C. Although literature indicates that OAIC is the mechanism that controls mechanical properties at high temperatures, its interactions with DSA and precipitation are still under discussion. The objective of this work is to investigate the interactions between the embrittlement phenomena (OAIC and DSA) and the hardening mechanism of γ′ and γ″ precipitation on the mechanical properties of an annealed 718 superalloy. Tensile tests were performed at a strain rate of 3.2 × 10{sup −4} s{sup −1} under secondary vacuum, in temperatures ranging from 200 to 800 °C. Fracture surfaces were observed by scanning electron microscopy (SEM) and precipitation by transmission electron microscopy (TEM). The effect of DSA and precipitation on the strength and of OAIC on the ductility was verified.

An Abrupt Transition to an Intergranular Failure Mode in the Near-Threshold Fatigue Crack Growth Regime in Ni-Based Superalloys

Science.gov (United States)

Telesman, J.; Smith, T. M.; Gabb, T. P.; Ring, A. J.

2018-06-01

Cyclic near-threshold fatigue crack growth (FCG) behavior of two disk superalloys was evaluated and was shown to exhibit an unexpected sudden failure mode transition from a mostly transgranular failure mode at higher stress intensity factor ranges to an almost completely intergranular failure mode in the threshold regime. The change in failure modes was associated with a crossover of FCG resistance curves in which the conditions that produced higher FCG rates in the Paris regime resulted in lower FCG rates and increased ΔK th values in the threshold region. High-resolution scanning and transmission electron microscopy were used to carefully characterize the crack tips at these near-threshold conditions. Formation of stable Al-oxide followed by Cr-oxide and Ti-oxides was found to occur at the crack tip prior to formation of unstable oxides. To contrast with the threshold failure mode regime, a quantitative assessment of the role that the intergranular failure mode has on cyclic FCG behavior in the Paris regime was also performed. It was demonstrated that even a very limited intergranular failure content dominates the FCG response under mixed mode failure conditions.

The application of in situ analytical transmission electron microscopy to the study of preferential intergranular oxidation in Alloy 600

Energy Technology Data Exchange (ETDEWEB)

Burke, M.G., E-mail: m.g.burke@manchester.ac.uk; Bertali, G.; Prestat, E.; Scenini, F.; Haigh, S.J.

2017-05-15

In situ analytical transmission electron microscopy (TEM) can provide a unique perspective on dynamic reactions in a variety of environments, including liquids and gases. In this study, in situ analytical TEM techniques have been applied to examine the localised oxidation reactions that occur in a Ni-Cr-Fe alloy, Alloy 600, using a gas environmental cell at elevated temperatures. The initial stages of preferential intergranular oxidation, shown to be an important precursor phenomenon for intergranular stress corrosion cracking in pressurized water reactors (PWRs), have been successfully identified using the in situ approach. Furthermore, the detailed observations correspond to the ex situ results obtained from bulk specimens tested in hydrogenated steam and in high temperature PWR primary water. The excellent agreement between the in situ and ex situ oxidation studies demonstrates that this approach can be used to investigate the initial stages of preferential intergranular oxidation relevant to nuclear power systems. - Highlights: • In situ analytical TEM has been performed in 1 bar H{sub 2}-H{sub 2}O vapor at 360–480 °C. • Nanoscale GB migration and solute partitioning correlate with ex situ data for Alloy 600 in H{sub 2}-steam. • This technique can provide new insights into localised reactions associated with localised oxidation.

Intergranular attack evaluation from hideout return

International Nuclear Information System (INIS)

Nordmann, F.; Dupin, M.; Menet, O.; Fiquet, J.-M.

1989-01-01

Intergranular Attack (IGA) is the secondary side corrosion mechanism on PWR steam generator tubing, which can occur most frequently even with a good waterchemistry. It has moderately developed in a few French units. Consequently, several remedies have been implemented, such as sodium content decrease in makeup water and application of more stringent chemistry specifications. In order to evaluate the local chemistry in restricted areas where IGA may occur, a large hideout return programme has been carried out on many units. It shows that free alkalinity returning during shutdown is usually ranging from 0.5 to 5 g of sodium per steam generator, and that the required time to let it return is about 40 hours. However, high temperature pH calculations indicate that such an amount of alkalinity can correspond to a potentially corrosive solution in restricted areas, where a concentration factor of 10 5 to 10 7 can be reached, inducing a pH of 10 at 300 o C. Studies are still in progress in order to define when a shutdown should be required to allow hideout return and help to prevent IGA. (author)

Two-phase flow experiments through intergranular stress corrosion cracks

International Nuclear Information System (INIS)

Collier, R.P.; Norris, D.M.

1984-01-01

Experimental studies of critical two-phase water flow, through simulated and actual intergranular stress corrosion cracks, were performed to obtain data to evaluate a leak flow rate model and investigate acoustic transducer effectiveness in detecting and sizing leaks. The experimental program included a parametric study of the effects of crack geometry, fluid stagnation pressure and temperature, and crack surface roughness on leak flow rate. In addition, leak detection, location, and leak size estimation capabilities of several different acoustic transducers were evaluated as functions of leak rate and transducer position. This paper presents flow rate data for several different cracks and fluid conditions. It also presents the minimum flows rate detected with the acoustic sensors and a relationship between acoustic signal strength and leak flow rate

Estimation of flow rates through intergranular stress corrosion cracks

International Nuclear Information System (INIS)

Collier, R.P.; Norris, D.M.

1984-01-01

Experimental studies of critical two-phase water flow, through simulated and actual intergranular stress corrosion cracks, were performed to obtain data to evaluate a leak flow rate model and investigate acoustic transducer effectiveness in detecting and sizing leaks. The experimental program included a parametric study of the effects of crack geometry, fluid stagnation pressure and temperature, and crack surface roughness on leak flow rate. In addition, leak detection, location, and leak size estimation capabilities of several different acoustic transducers were evaluated as functions of leak rate and transducer position. This paper presents flow rate data for several different cracks and fluid conditions. It also presents the minimum flow rate detected with the acoustic sensors and a relationship between acoustic signal strength and leak flow rate

Is a more stable exchange rate associated with reduced exchange rate pass-through?

OpenAIRE

Mark J. Holmes

2007-01-01

Pass-through from the nominal effective exchange rate to import prices is modelled within a regime-switching environment. Evidence suggests that exchange rate pass through can be characterised as regime-specific where the probability of switching between regimes is influenced by the extent of exchange rate volatility.

Standard Test Methods for Detecting Susceptibility to Intergranular Corrosion in Wrought, Nickel-Rich, Chromium-Bearing Alloys

CERN Document Server

American Society for Testing and Materials. Philadelphia

2008-01-01

1.1 These test methods cover two tests as follows: 1.1.1 Method A, Ferric Sulfate-Sulfuric Acid Test (Sections 3-10, inclusive)—This test method describes the procedure for conducting the boiling ferric sulfate—50 % sulfuric acid test which measures the susceptibility of certain nickel-rich, chromium-bearing alloys to intergranular corrosion (see Terminology G 15), which may be encountered in certain service environments. The uniform corrosion rate obtained by this test method, which is a function of minor variations in alloy composition, may easily mask the intergranular corrosion components of the overall corrosion rate on alloys N10276, N06022, N06059, and N06455. 1.1.2 Method B, Mixed Acid-Oxidizing Salt Test (Sections 11-18, inclusive)—This test method describes the procedure for conducting a boiling 23 % sulfuric + 1.2 % hydrochloric + 1 % ferric chloride + 1 % cupric chloride test which measures the susceptibility of certain nickel-rich, chromium-bearing alloys to display a step function increa...

Demonstration through EPR tests of the sensitivity of austeno-ferritic steels to intergranular corrosion and stress corrosion cracking

International Nuclear Information System (INIS)

Lopez, Nathalie

1997-01-01

Duplex stainless steels can be sensitised to intergranular corrosion and stress corrosion cracking (SCC) under some conditions (heat treatments, welding). The aim of this work is to contribute to the validation of the EPR (Electrochemical Potentiodynamic Reactivation) test in order to determine conditions for normalisation. This method, based on the dissolution of chromium depleted areas due to precipitation of σ-phase, provides a degree of sensitisation to intergranular corrosion. The test is broaden considering the mechanical stress by the way of slow strain rate tests, performed in chloride magnesium and in a solution similar to the EPR solution. A metallurgical study puts on the precipitates and the structural modifications due to welding and heat treatments, in order to make a critical analysis of the EPR test. (author) [fr

Fracture statistics of brittle materials with intergranular cracks

International Nuclear Information System (INIS)

Batdorf, S.B.

1975-01-01

When brittle materials are used for structural purposes, the initial design must take their relatively large dispersion in fracture stress properly into account. This is difficult when failure probabilities must be extremely low, because empirically based statistical theories of fracture, such as that of Weibull, cannot reliably predict the stresses corresponding to failure probabilities much lower than n -1 , where n is the number of specimens tested. Recently McClintock proposed a rational method of predicting the size distribution of intergranular cracks. The method assumed that large cracks are random aggregations of cracked grain boundaries. The present paper employs this method to find the size distribution of penny-shaped cracks, and also P(f), the probability of failure of a specimen of volume V subjected to a tensile stress sigma. The present paper is a pioneering effort, which should be applicable to ceramics and related materials

Development of seamless forged pipe and fitting for BWR recirculation loop piping with improved resistance to intergranular stress corrosion cracking

International Nuclear Information System (INIS)

Ohnishi, Keizo; Tsukada, Hisashi; Kobayashi, Masayoshi; Iwadate, Tadao; Ono, Shinichi

1981-01-01

As a primary remedy for IGSCC of primary loop piping, especially Recirculation Loop Piping of BWR, extra low carbon stainless steel with high nitrogen content has become to be used. While, in order to make In-service Inspection easier and complete, new design of piping which decrease both number and total length of weld line has been considered. Japan Steel Works has developed the research on large size seamless forged pipe and fitting made from high nitrogen extra low carbon 316 stainless steel. This paper describes the key points of manufacturing technology as well as the material properties, especially strength and intergranular-corrosion and intergranular- stress-corrosion-cracking-resistivities of these forged pipe and fitting. (author)

Effects of microstructure and local mechanical fields on intergranular stress corrosion cracking of a friction stir welded aluminum–copper–lithium 2050 nugget

International Nuclear Information System (INIS)

Dhondt, Matthieu; Aubert, Isabelle; Saintier, Nicolas; Olive, Jean Marc

2014-01-01

Highlights: • Applied stress changes the corrosion mode from pitting to intergranular cracking. • Residual stresses are sufficient to induce intergranular stress corrosion cracking. • Effect of crystallographic texture on the development of IGSCC evidenced by EBSD. • Cubic elasticity drives the local orientation of the intergranular cracking. • Tomography observations show the 3D nature of the corrosion development. - Abstract: The effects of the microstructure and mechanical fields on intergranular stress corrosion cracking (IGSCC) of the nugget zone of heat treated welds obtained by friction stir welding in the AA2050 aluminum alloy have been investigated at different scales. At low strain rate, in 1.0 NaCl aqueous solution, IGSCC develops in the microstructure, whereas only pitting corrosion is observed without any mechanical stress. Based on surface observations, EBSD analysis and X-ray tomography, the key role of sub-millimetric textured bands (induced by the welding process) on the IGSCC is demonstrated. Analyses at a more local scale show the grain boundary (low angle boundary, special coincident site lattice boundary or high angle boundary) do not have a significant effect on crack initiation. Crystal plasticity finite element calculations show that the threshold normal stress at grain boundaries for IGSCC development is about 80% of the macroscopic stress. It is also highlighted by crystal plasticity calculations that there is a drastic effect of the local stress field on the shape of cracks. Finally, it is shown that plasticity induced residual stresses are sufficient for the formation of IGSCC

An Electrochemical Framework to Explain Intergranular Stress Corrosion Cracking in an Al-5.4%Cu-0.5%Mg-0.5%Ag Alloy

Science.gov (United States)

Little, D. A.; Connolly, B. J.; Scully, J. R.

2001-01-01

A modified version of the Cu-depletion electrochemical framework was used to explain the metallurgical factor creating intergranular stress corrosion cracking susceptibility in an aged Al-Cu-Mg-Ag alloy, C416. This framework was also used to explain the increased resistance to intergranular stress corrosion cracking in the overaged temper. Susceptibility in the under aged and T8 condition is consistent with the grain boundary Cu-depletion mechanism. Improvements in resistance of the T8+ thermal exposure of 5000 h at 225 F (T8+) compared to the T8 condition can be explained by depletion of Cu from solid solution.

Reducing the energy consumption of an earth–air heat exchanger with a PID control system

International Nuclear Information System (INIS)

Diaz-Mendez, S.E.; Patiño-Carachure, C.; Herrera-Castillo, J.A.

2014-01-01

Highlights: • The application of control actions to green technologies has been simulated. • Energy consumption of green technologies can be reduced even more. • The efficiency of green technologies can be raised. • Environmental concerns can be diminished. • The sustainability of the planet can be increased. - Abstract: Reducing environmental emissions is one of the challenges that human being has to overcome. It can only be reached with a proper energetic efficiency and management of the processes that exist in the society nowadays. Several academic works have mentioned that raising the efficiency of a process it also increases sustainability and in turn decreases the environmental impact. One process that requires much attention is the cooling and heating of buildings; this process contributes to the major part of the electric bill, in particular, if a conventional and old air conditioning is used as commonly occurs in many countries. In recent years there have been developed new alternatives that are used in few countries, such as the earth–air heat exchanger, where air is passed through a heat exchanger buried a few meters below the ground. The heat exchanger takes advantage of the well-known difference between the temperature of the surrounding air and the temperature of the ground for cooling or heating the air that is subsequently injected into the buildings. This process requires less energy, then in the present work is thought that a PID (Proportional, Integral and Derivative) controller can be applied to an earth–air heat exchanger to reduce even more the energy consumption. Therefore, a simulation of a thermodynamic model of an earth–air heat exchanger was done and used along with a PID controller, to estimate savings in energy consumption. The results show that the energy consumption can be reduced up to 87% with the PID control, hence the efficiency of the process is increased as well as the sustainability of the planet and thus the

Exchanging and Storing Energy. Reducing Energy Demand through Heat Exchange between Functions and Temporary Storage

Energy Technology Data Exchange (ETDEWEB)

Sillem, E.

2011-06-15

As typical office buildings from the nineties have large heating and cooling installations to provide heat or cold wherever and whenever needed, more recent office buildings have almost no demand for heating due to high internal heat loads caused by people, lighting and office appliances and because of the great thermal qualities of the contemporary building envelope. However, these buildings still have vast cooling units to cool down servers and other energy consuming installations. At the same time other functions such as dwellings, swimming pools, sporting facilities, archives and museums still need to be heated most of the year. In the current building market there is an increasing demand for mixed-use buildings or so called hybrid buildings. The Science Business Centre is no different and houses a conference centre, offices, a museum, archives, an exhibition space and a restaurant. From the initial program brief it seemed that the building will simultaneously house functions that need cooling most of the year and functions that will need to be heated the majority of the year. Can this building be equipped with a 'micro heating and cooling network' and where necessary temporarily store energy? With this idea a research proposal was formulated. How can the demand for heating and cooling of the Science Business Centre be reduced by using energy exchange between different kinds of functions and by temporarily storing energy? In conclusion the research led to: four optimized installation concepts; short term energy storage in pavilion concept and museum; energy exchange between the restaurant and archives; energy exchange between the server space and the offices; the majority of heat and cold will be extracted from the soil (long term energy storage); the access heat will be generated by the energy roof; PV cells from the energy roof power all climate installations; a total energy plan for the Science Business Centre; a systematic approach for exchanging

The intergranular corrosion behavior of 6000-series alloys with different Mg/Si and Cu content

Energy Technology Data Exchange (ETDEWEB)

Zou, Yun; Liu, Qing, E-mail: qingliu@cqu.edu.cn; Jia, Zhihong, E-mail: zhihongjia@cqu.edu.cn; Xing, Yuan; Ding, Lipeng; Wang, Xueli

2017-05-31

Highlights: • High Cu alloy with high Mg/Si ratio has the best comprehensive property. • Addition of excess Mg could improve the intergranular corrosion resistance. • Si containing particles on the grain boundaries of Si-rich alloys promote IGC. • IGC susceptibility depends primarily on Cu content and secondarily on Mg/Si ratio. - Abstract: 6000-series aluminium alloys with high Cu or excess Si addition were susceptible to intergranular corrosion (IGC). In order to obtain good IGC resistance, four alloys with low/high Cu and various Mg/Si ratios were designed. The corrosion behaviour of four alloys was investigated by accelerated corrosion test, electrochemical test and electron microscopies. It was revealed that IGC susceptibility of alloys was the result of microgalvanic coupling between the noble grain boundary precipitates and the adjacent precipitates free zone (PFZ), which was closely related to a combination of Cu content and the Mg/Si ratio. Excess Mg could improve the IGC resistance of alloys by forming discontinuous precipitates on the grain boundaries. The designed alloy with high Cu and excess Mg has the same corrosion level as the commercial alloy with low Cu and excess Si, which provides possibility for developing new alloy.

Techniques for intergranular crack formation and assessment in alloy 600 base and alloy 182 weld metals

Directory of Open Access Journals (Sweden)

Tae Hyun Lee

2015-02-01

Conclusion: A comparison with a destructive metallographic examination showed that the characteristics, orientations, and sizes of the intergranular cracks produced in this study are highly reproducible.

Intergranular Cracking as a Major Cause of Long-Term Capacity Fading of Layered Cathodes.

Science.gov (United States)

Liu, Hao; Wolf, Mark; Karki, Khim; Yu, Young-Sang; Stach, Eric A; Cabana, Jordi; Chapman, Karena W; Chupas, Peter J

2017-06-14

Capacity fading has limited commercial layered Li-ion battery electrodes to NCA) electrode change after capacity fade following months of slow charge-discharge. The changes in the reactions that underpin energy storage after long-term cycling directly correlate to the capacity loss; heterogeneous reaction kinetics observed during extended cycles quantitatively account for the capacity loss. This reaction heterogeneity is ultimately attributed to intergranular fracturing that degrades the connectivity of subsurface grains within the polycrystalline NCA aggregate.

Coercivity enhancement of Dy-free Nd–Fe–B sintered magnets by intergranular adding Ho{sub 63.4}Fe{sub 36.6} alloy

Energy Technology Data Exchange (ETDEWEB)

Liang, Liping; Ma, Tianyu, E-mail: maty@zju.edu.cn; Wu, Chen; Zhang, Pei; Liu, Xiaolian; Yan, Mi, E-mail: mse_yanmi@zju.edu.cn

2016-01-01

High coercivity Nd–Fe–B sintered magnets serving in high-temperature environments always consume expensive and scarce heavy rare-earth Dy, which has simulated considerable interest to reduce Dy usage. In this work, coercivity of Dy-free magnets was investigated through intergranular adding eutectic Ho{sub 63.4}Fe{sub 36.6} powders. The coercivity increases gradually up to 4 wt% Ho{sub 63.4}Fe{sub 36.6} addition, however the remanence starts to deteriorate drastically as the addition is over 2.5 wt%. Coercivity above 18.0 kOe is obtained at the expense of a slight reduction in remanence through optimizing the addition amount and sintering conditions. The coercivity enhancement is explained through microstructural observations and elemental distribution analysis. (i) (Nd, Ho){sub 2}Fe{sub 14}B shell forms in the outer region of 2:14:1 phase grains, strengthening the local magnetic anisotropy filed, (ii) RE-rich grain boundary phase with low Fe content is thickened, weakening the magnetic coupling between adjacent 2:14:1 phase grains, and (iii) 2:14:1 phase grains are refined upon lowering sintering temperature, reducing the microstructural defects and the stray fields aroused from neighboring grains. - Highlights: • Eutectic Ho{sub 63.4}Fe{sub 36.6} powders were intergranular added to NdFeB sintered magnets. • The doped Dy-free magnet possessed coercivity of 18.0 kOe, remanence of 13.15 kGs. • (Nd, Ho){sub 2}Fe{sub 14}B shell formed in the surface of the matrix grains, increasing the H{sub A}. • Thick grain boundaries with low Fe content formed, decoupling the matrix grains. • By sintered at lower temperature, the matrix phase grains were refined.

Evaluation of intergranular corrosion techniques to determine phosphorus segregation in NiCrMoV rotor steel

International Nuclear Information System (INIS)

Bruemmer, S.M.; Thomas, M.T.; Arey, B.W.

1985-01-01

Several chemical and electrochemical etching techniques have been evaluated for the indirect measurement of grain boundary phosphorus segregation. A picric acid based solution was found to promote intergranular attack proportional to the grain boundary phosphorus composition measured by Auger Electron Spectroscopy. Preliminary results indicate this solution may enable the nondestructive evaluation of a rotor steel's susceptibility to temper embrittlement and IGSCC

Analysis of the intergranular fracture surface by the Fourier spectrum method

Energy Technology Data Exchange (ETDEWEB)

Hao Yao; Tian Jifeng; Wang Zhongguang (National Lab. for Fatigue and Fracture of Materials, Inst. of Metal Research, Academia Sinica, Shen Yang (China))

1991-11-30

A quantitative analysis of the fracture surface of a 1045 steel was undertaken in order to relate important microstructural features to brittle intergranular fractures in the steel. It was found that the character of the profile was not random but periodic. There is a direct correspondence between the Fourier spectrum of the profile and the microstructure features. Utilization of secondary-electron line scanning facilitated the analysis of the fracture surface in this case. The results of the analysis from both the profile and the scanning line showed that the first autocorrelation length is related to the average grain size and that the total power corresponds to the impact energy of the fracture. (orig.).

Mechanistic differences between transgranular and intergranular stress corrosion cracking

International Nuclear Information System (INIS)

Serebrinsky, Santiago A.; Galvele, Jose R.

2000-01-01

Constant extension rate tests (CERT or CSRT) with the strain rate (SR) covering a 7 orders of magnitude range were applied to the study of many systems. In particular, the kinetics of SCC were measured via the stress corrosion (SCC) crack propagation rate (CPR). The main experimental findings are: a) increasing SR produces a monotonic (logarithmic) increase in CPR; b) the slopes α in log CPR vs. log SR plots take distinct values depending on the morphology: intergranular (IG) cracks are more steeply accelerated by SR than transgranular (TG), with α lG =0.4 to 0.7 and α TG =0.2 to 0.3; c) an increase in SR only shifts the log CPR vs. potential curves to higher CPR values, without changing its shape. Quantitative evaluation shows that dislocations piled-up at grain boundaries may combine with the surface mobility mechanism to give the experimental results. (author)

Signal Characteristics of Eddy Current Test for Intergranular Attack of Steam Generator Tubes

International Nuclear Information System (INIS)

Choi, Myung Sik; Lee, Deok Hyun; Han, Jung Ho; Hur, Do Haeng; Cho, Se Gon; Yim, Chang Jae

2002-01-01

Because intergranular attack (IGA), one of the localized corrosion forms occurring on steam generator tubes, can not be fabricated by an electric discharge machining method, there are few data for the eddy current test (ECT) characteristics of IGA. In this paper, the characteristics of eddy current signals are evaluated using nonexpanded tubes with IGA defects formed in 0.1 M sodium tetrathionate solution at 40 .deg. C. The detectability and sizing accuracy of IGA were discussed in terms of the coil type and frequency of the ECT probes

Characterization of acoustic emission signals generated by water flow through intergranular stress corrosion cracks

International Nuclear Information System (INIS)

Claytor, T.N.; Kupperman, D.S.

1985-05-01

A program is under way at Argonne National Laboratory (ANL) to develop an independent capability to assess the effectiveness of current and proposed techniques for acoustic leak detection (ALD) in reactor coolant systems. The program will establish whether meaningful quantitative data on flow rates and leak location can be obtained from acoustic signatures of leaks due to intergranular stress corrosion cracks (TGSCCs) and fatigue cracks, and whether these can be distinguished from other types of leaks. 5 refs., 3 figs

Pilot scale ion exchange column study for reducing radioactivity discharges to environment

International Nuclear Information System (INIS)

Kore, S.G.; Yadav, V.K.; Sonar, N.L.; Valsala, T.P.; Narayan, J.; Sharma, S.P.; Chattopadhyay, S.; Dani, U.; Vishwaraj, I.

2013-01-01

Low level liquid waste (LLW) is generated during operation of Tarapur Atomic Power Station (TAPS). Chemical co-precipitation is the treatment method used for decontamination of this waste with respect to radionuclide prior to discharge to environment. Further polishing of effluent from the treated LLW was planned using ion exchange column to reduce the discharges to the environment In view of this ion exchange column study was carried out in the laboratory using in-house prepared cobalt ferrocyanide (COFC) based composite resin. Based on the encouraging results obtained in the lab studies, pilot scale study was carried out in the plant. Decontamination factor (DF) of 14-15 was obtained with respect to Cs isotopes and overall DF of 2-5 was obtained with respect to gross beta activity. (author)

Dual capillary tube / heat exchanger in combination with cycle priming for reducing charge migration

Science.gov (United States)

Gomes, Alberto Regio; Kuehl, Steven J.; Litch, Andrew D.; Wu, Guolian

2017-07-04

A refrigerator appliance including a multi-capacity compressor and a refrigerant circuit with two conduits and pressure reducing devices arranged in parallel between an evaporator and a condenser. Refrigerant can flow through one, both or none of the conduits and pressure reducing devices. The appliance also has a heat exchanger in contact with either one pressure reducing device, or one conduit between the pressure reducing device and the valve system. The appliance also includes a controller for priming the compressor above a nominal capacity for a predetermined or calculated duration at the beginning of an ON-cycle.

Effect of boric acid on intergranular corrosion and on hideout return efficiency of sodium in the tube support plate crevices

International Nuclear Information System (INIS)

Paine, J.P.N.; Shoemaker, C.E.; Campan, J.L.; Brunet, J.P.; Schindler, P.; Stutzmann, A.

1995-01-01

Sodium hydroxide is one of the main causes of intergranular attack/stress corrosion cracking (IGA/SCC) of alloy 600 steam generator (S.G.) tubes. Boric acid appears to be one of the possible remedies for intergranular corrosion process inhibition. In order to obtain data on boric acid injection efficiency, an experimental program was performed on previously corroded tubes. To prevent premature tube wall cracking, samples were sleeved on alloy 690 tubes. The objective of the tests was to evaluate, on a statistically valid number of samples, the effectiveness of boric acid and tube sleeving as possible remedies for IGA/SCC extension. Another independent experimental program was initiated to determine the hideout return efficiency in the tube support plate (TSP) and tubesheet (TS) crevices after a significant duration (≤ 180 hours) of sodium hideout. The main objective of the first tests being a statistical evaluation of the efficiency of boric acid treatment, was not achieved. The tests did demonstrate that sleeving effectively reduces IGA/SCC growth. In an additional program, cracks were obtained on highly susceptible tubes when specimens were not sleeved. The companion tests performed in the same conditions but with an addition of boric acid did not show any IGA or cracks. These results seem to demonstrate the possible effect of boric acid in preventing the corrosion process. Results of the second tests did not demonstrate any difference in the amount of sodium piled up in the crevices before and after boric acid injection. They however showed an increase of the hideout return efficiency at the tube support plate level from 78 % without boric acid to 95 % when boric acid is present in the feed water

Cutting of metal components by intergranular cracking

International Nuclear Information System (INIS)

Chavand, J.; Gauthier, A.; Lopez, J.J.; Tanis, G.

1985-01-01

The objective of this contract was to study a new steel-sheet cutting technique for dismantling nuclear installations without in principle producing secondary waste. This technique is based on intergranular cracking of steel induced by the combined action of penetration of molten metal into the steel and application of a mechanical load. Cutting has been achieved for stainless-steel sheets with thicknesses ranging from a few mm to 50 mm and for carbon-steel plates with thicknesses between 20 and 60 mm. For carbon steel is seems possible that components as thick as 100 mm can be cut. The tests have permitted selection of the heating methods and determination of the cracking parameters for the materials and range of thickness studied. In the case of thin sheets, results were obtained for cutting in varied positions suited to the techniques of dismantling in hot cells. A temperature-measuring system using an infrared camera has been developed to determine the variation of the temperature field established in the component. In association with the three-dimensional computation code COCO developed by the CEA, this system permits prediction of the changes in stresses in the cracked zone when the cutting parameters are modified. 34 figs

Intergranular and inter-phased boundaries in the materials; Joints intergranulaires et interphases dans les materiaux

Energy Technology Data Exchange (ETDEWEB)

Aslanides, A. [Electricite de France, Dept. CIMA, 77 - Moret sur Loing (France); Backhaus-Ricoult, M. [Centre d' Etudes de Chimie metallurgique, 94 - Vitry-sur-Seine (France); Bayle-Guillemaud, P. [CEA Grenoble, Dept. de Recherche Fondamentale sur la Matiere Condensee, 38 (France)] [and others

2000-07-01

This document collects the abstracts of the talks presented during the colloquium J2IM on the intergranular and inter-phased boundaries in the materials. Around the themes of the interfaces behaviour and grain boundaries defects in materials, these days dealt with the microstructure behaviour in many domains such as the interfaces in batteries, the irradiation damages and the special case of the fuel-cladding interactions, the stressed interfaces, the alumina or silicon carbides substrates. (A.L.B.)

Cohesive zone modeling of intergranular cracking in polycrystalline aggregates

International Nuclear Information System (INIS)

Simonovski, Igor; Cizelj, Leon

2015-01-01

Highlights: • Alternative approach to cohesive elements is proposed: cohesive-zone contact. • Applicability to measured and simulated grain structures is demonstrated. • Normal and normal/shear separation as a damage initialization is explored. • Normal/shear damage initialization significantly reduces ductility. • Little difference in Voronoi aggregate size on macroscopic response. - Abstract: Understanding and controlling early damage initiation and evolution are amongst the most important challenges in nuclear power plants, occurring in ferritic, austenitic steels and nickel based alloys. In this work a meso-scale approach to modeling initiation and evolution of early intergranular cracking is presented. This damage mechanism is present in a number of nuclear power plant components and depends on the material (e.g. composition, heat treatment, microstructure), environment and load. Finite element modeling is used to explicitly model the microstructure – both the grains and the grain boundaries. Spatial Voronoi tessellation is used to obtain the grain topology. In addition, measured topology of a 0.4 mm stainless steel wire is used. Anisotropic elasticity and crystal plasticity are used as constitutive laws for the grains. Grain boundaries are modeled using the cohesive zone approach. Different modeling assumptions/parameters are evaluated against the numerical stability criteria. The biggest positive contribution to numerical stability is the use of cohesive-type contact instead of cohesive elements. A small amount of viscous regularization should be also used along with the addition of a small amount of viscous forces to the global equilibrium equations. Two cases of grain boundary damage initiation are explored: (1) initiation due to normal separation and (2) initiation due to a combination of normal and shear separation. The second criterion significantly decreases the ductility of an aggregate and slightly improves the numerical stability

Simulation of Intergranular Ductile Cracking in β Titanium Alloys Based on a Micro-Mechanical Damage Model.

Science.gov (United States)

Li, Huan; Li, Jinshan; Tang, Bin; Fan, Jiangkun; Yuan, Huang

2017-10-30

The intergranular crack propagation of the lamellar structure β titanium alloys is investigated by using a modified Gurson-type damage model. The representative microstructure of the lamellar alloy, which consists of the soft α phase layer surrounding the hard grain interiors, is generated based on an advanced Voronoi algorithm. Both the normal fracture due to void growth and the shear fracture associated with void shearing are considered for the grain boundary α layer. The individual phase properties are determined according to the experimental nanoindentation result and the macroscopic stress-strain curve from a uni-axial tensile test. The effects of the strain hardening exponent of the grain interiors and the void shearing mechanism of the grain boundary α layer on fracture toughness and the intergranular crack growth behavior are emphatically studied. The computational predictions indicate that fracture toughness can be increased with increasing the strain hardening ability of the grain interiors and void shearing can be deleterious to fracture toughness. Based on the current simulation technique, qualitative understanding of relationships between the individual phase features and the fracture toughness of the lamellar alloys can be obtained, which provides useful suggestions to the heat treatment process of the β titanium alloys.

Seasonal trends in reduced leaf gas exchange and ozone-induced foliar injury in three ozone sensitive woody plant species

International Nuclear Information System (INIS)

Novak, K.; Schaub, M.; Fuhrer, J.; Skelly, J.M.; Hug, C.; Landolt, W.; Bleuler, P.; Kraeuchi, N.

2005-01-01

Seasonal trends in leaf gas exchange and ozone-induced visible foliar injury were investigated for three ozone sensitive woody plant species. Seedlings of Populus nigra L., Viburnum lantana L., and Fraxinus excelsior L. were grown in charcoal-filtered chambers, non-filtered chambers and open plots. Injury assessments and leaf gas exchange measurements were conducted from June to October during 2002. All species developed typical ozone-induced foliar injury. For plants exposed to non-filtered air as compared to the charcoal-filtered air, mean net photosynthesis was reduced by 25%, 21%, and 18% and mean stomatal conductance was reduced by 25%, 16%, and 8% for P. nigra, V. lantana, and F. excelsior, respectively. The timing and severity of the reductions in leaf gas exchange were species specific and corresponded to the onset of visible foliar injury. - Reductions in leaf gas exchange corresponded to the onset of ozone-induced visible foliar injury for seedlings exposed to ambient ozone exposures

Seasonal trends in reduced leaf gas exchange and ozone-induced foliar injury in three ozone sensitive woody plant species

Energy Technology Data Exchange (ETDEWEB)

Novak, K. [Swiss Federal Institute for Forest, Snow and Landscape Research WSL, Zuercherstrasse 111, 8903 Birmensdorf (Switzerland)]. E-mail: kristopher.novak@wsl.ch; Schaub, M. [Swiss Federal Institute for Forest, Snow and Landscape Research WSL, Zuercherstrasse 111, 8903 Birmensdorf (Switzerland); Fuhrer, J. [Swiss Federal Research Station for Agroecology and Agriculture FAL, 8046 Zurich (Switzerland); Skelly, J.M. [Department of Plant Pathology, The Pennsylvania State University, University Park, PA 16802 (United States); Hug, C. [Swiss Federal Institute for Forest, Snow and Landscape Research WSL, Zuercherstrasse 111, 8903 Birmensdorf (Switzerland); Landolt, W. [Swiss Federal Institute for Forest, Snow and Landscape Research WSL, Zuercherstrasse 111, 8903 Birmensdorf (Switzerland); Bleuler, P. [Swiss Federal Institute for Forest, Snow and Landscape Research WSL, Zuercherstrasse 111, 8903 Birmensdorf (Switzerland); Kraeuchi, N. [Swiss Federal Institute for Forest, Snow and Landscape Research WSL, Zuercherstrasse 111, 8903 Birmensdorf (Switzerland)

2005-07-15

Seasonal trends in leaf gas exchange and ozone-induced visible foliar injury were investigated for three ozone sensitive woody plant species. Seedlings of Populus nigra L., Viburnum lantana L., and Fraxinus excelsior L. were grown in charcoal-filtered chambers, non-filtered chambers and open plots. Injury assessments and leaf gas exchange measurements were conducted from June to October during 2002. All species developed typical ozone-induced foliar injury. For plants exposed to non-filtered air as compared to the charcoal-filtered air, mean net photosynthesis was reduced by 25%, 21%, and 18% and mean stomatal conductance was reduced by 25%, 16%, and 8% for P. nigra, V. lantana, and F. excelsior, respectively. The timing and severity of the reductions in leaf gas exchange were species specific and corresponded to the onset of visible foliar injury. - Reductions in leaf gas exchange corresponded to the onset of ozone-induced visible foliar injury for seedlings exposed to ambient ozone exposures.

eBgateway : a solution to reduce document exchange expenses

Energy Technology Data Exchange (ETDEWEB)

Demers, D. [ElectroBusiness, Calgary, AB (Canada)

2004-07-01

This paper provides a description of electroBusiness, a document exchange company based in Calgary. Details of the company's exchange methods in servicing multiple companies were presented. A mapping of internal systems and the different formats available for information sharing were outlined. An outdated supply exchange agreement with 10 partners was presented as the basis for a critique of earlier communications technologies and their ineffectiveness and costliness. An industry business solution, including proof-of-concept architecture and security. Advantages of the electroBusiness model included significant cost reductions and effective and up to date secure private community trading data. A list of e-Business utility exchanges was presented, including producers, technology companies as well as suppliers, contractors and distributors. Contact information was given at the end of the presentation. tabs, figs.

Oxidation studies of β-sialon ceramics containing amorphous and / or crystalline intergranular phases

International Nuclear Information System (INIS)

Persson, J.; Kall, P.O.; Jansson, K.; Nygren, M.

1992-01-01

β-sialon ceramics of equal overall compositions but containing amorphous, partly crystalline and almost completely crystalline intergranular phase(s) have been oxidized in oxygen at 1350 deg C for 20 hours. The obtained weight gain curves do not follow the parabolic rate law (ΔW/A 0 ) 2 = k p t + β. To the extent that crystallization occurs in the oxide scale during the oxidation experiment, the amorphous cross section area through which oxygen most easily diffuses will decrease with time. A brief description of this new rate law is given, and the obtained oxidation curves will be discussed within that framework. 4 refs., 2 tabs., 2 figs

Electromigration of intergranular voids in metal films for microelectronic interconnects

CERN Document Server

Averbuch, A; Ravve, I

2003-01-01

Voids and cracks often occur in the interconnect lines of microelectronic devices. They increase the resistance of the circuits and may even lead to a fatal failure. Voids may occur inside a single grain, but often they appear on the boundary between two grains. In this work, we model and analyze numerically the migration and evolution of an intergranular void subjected to surface diffusion forces and external voltage applied to the interconnect. The grain-void interface is considered one-dimensional, and the physical formulation of the electromigration and diffusion model results in two coupled fourth-order one-dimensional time-dependent PDEs. The boundary conditions are specified at the triple points, which are common to both neighboring grains and the void. The solution of these equations uses a finite difference scheme in space and a Runge-Kutta integration scheme in time, and is also coupled to the solution of a static Laplace equation describing the voltage distribution throughout the grain. Since the v...

Imaging and thickness measurement of amorphous intergranular films using TEM

International Nuclear Information System (INIS)

MacLaren, I.

2004-01-01

Fresnel fringe analysis is shown to be unreliable for grain boundaries in yttrium-doped alumina: the determined thicknesses do not agree well with those measured from high resolution transmission electron microscopy (HRTEM), the asymmetry between under- and overfocus is very large, and Fresnel fringes are sometimes shown at boundaries which contain no amorphous film. An alternative approach to the analysis of HRTEM images of grain boundary films is demonstrated: Fourier filtering is used to remove the lattice fringes from the image thereby significantly enhancing the visibility of the intergranular films. The apparent film thickness shows a discrepancy between measurements from the original HRTEM image and the filtered image. It was shown that fringe delocalisation and diffuseness of the amorphous/crystalline interfaces will lead to a significant underestimate of the thickness in unprocessed HRTEM images. In contrast to this, the average thickness can be much more accurately measured from the Fourier-filtered image, provided the boundary is oriented accurately edge-on

Intergranular attack observed in radiation-enhanced corrosion of mild steel

International Nuclear Information System (INIS)

Reda, R.J.; Kelly, J.L.; Harna, S.L.A.

1988-01-01

Experiments were conducted to determine the effects of gamma radiation on the corrosion of AISI 1018 mild steel in deaerated brine solutions of various sodium, magnesium, and chloride ion concentrations. Immersed metal specimens were irradiated at an exposure rate of 3 x 10/sup 5/ R/h (0.3 MR/h) for up to 1250 h at a temperature of --25 C. The corrosion rates of the irradiated specimens were found to be roughly a factor of 10 greater than the rates for the non-irradiated specimens. The radiation-enhanced corrosion rate was also found to have increased with the chloride concentration. Electron micrographs revealed that the surface morphology of the specimens exposed to irradiated brines differed greatly from the non-irradiated specimens. The non-irradiated specimens had undergone uniform corrosion, while the irradiated specimens exhibited intergranular corrosion (IGC), a phenomenon not yet observed in mild steel. An explanation for this observation is offered in terms of the relative rates of formation and recombination of radiolytic species

Exchange rate rebounds after foreign exchange market interventions

Science.gov (United States)

Hoshikawa, Takeshi

2017-03-01

This study examined the rebounds in the exchange rate after foreign exchange intervention. When intervention is strongly effective, the exchange rate rebounds at next day. The effect of intervention is reduced slightly by the rebound after the intervention. The exchange rate might have been 67.12-77.47 yen to a US dollar without yen-selling/dollar-purchasing intervention of 74,691,100 million yen implemented by the Japanese government since 1991, in comparison to the actual exchange rate was 103.19 yen to the US dollar at the end of March 2014.

Diffusion-controlled intergranular penetration and embrittlement of copper by liquid bismuth between 300 and 600 Celsius degrees; Penetration intergranulaire fragilisante du cuivre par le bismuth liquide: identification de la cinetique et du mecanisme de type diffusionnel entre 300 et 600 deg

Energy Technology Data Exchange (ETDEWEB)

Laporte, V

2005-02-15

Hybrid reactors are a new concept for energy production and nuclear waste treatment. Among other requirements, structural materials have to withstand liquid metal embrittlement. This thesis aimed therefore to identify the controlling mechanism for the intergranular embrittlement of copper in contact with liquid bismuth. Scanning electron microscopy, Auger electron spectroscopy, X-ray photoelectron spectroscopy and Rutherford backscattering spectroscopy have been used to analyze fracture surfaces of both copper polycrystals and a copper bicrystal (symmetric tilt boundary 50 degrees <100>). These analyses reveal both parabolic intergranular penetration kinetics and a maximal intergranular bismuth concentration that is less than two monolayers equivalent. These two results allow us to identify grain boundary diffusion as the controlling mechanism for the intergranular penetration of copper by liquid bismuth between 300 and 600 Celsius degrees, showing the absence of perfect grain boundary wetting. (author)

Mitigating Intergranular Stress Corrosion Cracking in Age-Hardenable Al-Zn-Mg-Cu Alloys

Science.gov (United States)

Ajay Krishnan, M.; Raja, V. S.; Shukla, Shweta; Vaidya, S. M.

2018-06-01

This article reports an attempt to develop high-strength aluminum alloys of 7xxx series resistant to intergranular stress corrosion cracking (SCC). A novel aging technique reported in this work exhibited improved strength levels (as high as 100 MPa to that of conventional overaged temper for AA 7050) with significant resistance to SCC measured even at a low strain rate (10-7 s-1) in 3.5 wt pct NaCl. The novel aging heat treatment produced a microstructure that is finer and dense enough in the matrix to impart strength, whereas it is enriched with Cu on the grain boundaries to impart SCC resistance. A detailed explanation for the enhanced strength and SCC resistance is discussed.

Mitigating Intergranular Stress Corrosion Cracking in Age-Hardenable Al-Zn-Mg-Cu Alloys

Science.gov (United States)

Ajay Krishnan, M.; Raja, V. S.; Shukla, Shweta; Vaidya, S. M.

2018-04-01

This article reports an attempt to develop high-strength aluminum alloys of 7xxx series resistant to intergranular stress corrosion cracking (SCC). A novel aging technique reported in this work exhibited improved strength levels (as high as 100 MPa to that of conventional overaged temper for AA 7050) with significant resistance to SCC measured even at a low strain rate (10-7 s-1) in 3.5 wt pct NaCl. The novel aging heat treatment produced a microstructure that is finer and dense enough in the matrix to impart strength, whereas it is enriched with Cu on the grain boundaries to impart SCC resistance. A detailed explanation for the enhanced strength and SCC resistance is discussed.

Extended Hall-Petch Relationships for Yield, Cleavage and Intergranular Fracture Strengths of bcc Steel and Its Deformation and Fracture Behaviors

Science.gov (United States)

Heo, N. H.; Heo, Y.-U.; Kwon, S. K.; Kim, N. J.; Kim, S.-J.; Lee, H.-C.

2018-03-01

Extended Hall-Petch relationships for yield ( σy ), cleavage ( σ_{cl} ) and intergranular fracture ( σ_{ig} ) strengths of pure iron have been established through the direct calculation of the proportional constant (k) and the estimation of the friction stress (σ0 ) . The magnitude orders of k and σ0 are generally ky causes the high work hardening rate.

The Effect of MoO42- Addition on the Intergranular Corrosion Behavior of Sensitized type 304 Stainless Steel

International Nuclear Information System (INIS)

Lee, Kee Pyo; Kim, Kwan Hyu

1988-01-01

This experiment is aimed at the investigation of the effect of MoO 4 2- added to the electrolyte on the corrosion behavior of sensitized 304 stainless steel. The specimens of 304 stainless steel were sensitized for 1 hour at 800 .deg. C, and also for 1 hour at 800 .deg. C followed by 600 .deg. C for 2 hours. Polarization curves of the specimens were obtained in 1N H 2 SO 4 + 0.2N NCl (with or without 0.001M MoO 4 2- ) and in 1N H 2 SO 4 + 0.01N KSCN (with or without 0.001M MoO 4 2- )solutions. All specimens after corrosion test were subjected to microstructural analysis by using an optical microscope. The susceptibility of 304 stainless steel to the intergranular corrosion was decreased by the addition of MoO 4 2- to the electrolyte. It is suggested that the MoO 4 2- in the electrolyte leads to the easy formation of a passive film on the stainless steel substrate. It was confirmed that the area of intergranular attack of stainless steel was decreased by the addition of MoO 4 2- to the electrolyte

The effect of capped layer thickness on switching behavior in perpendicular CoCrPt based coupled granular/continuous media

International Nuclear Information System (INIS)

Li, W.M.; Lim, W.K.; Shi, J.Z.; Ding, J.

2013-01-01

A systematic investigation of magnetic switching behavior of CoCrPt based capped media (perpendicularly coupled granular/continuous (CGC) media consisting of granular CoCrPt:SiO 2 TiO 2 Ta 2 O 5 /capped CoCrPt(B)) is performed by varying the thickness of the capped layer from 0 to 9 nm. The microscopic structures of CGC media with different thickness of capped layer are examined by transmission electron microscope. We find out that CoCrPt magnetic grains are separated by nonmagnetic oxide grain boundaries. Grain size and grain boundary are about 8.9 nm and 2 nm, respectively. The nonmagnetic oxide grain boundaries in the granular layer do not disappear immediately at the interface between the granular and capped layers. The amorphous grain boundary phase in the granular layer propagates to the top surface of the capped layer. After capping with the CoCrPt(B) layer, the grain size at the surface of CGC structure increases and the grain boundary decreases. Both coercivity and intergranular exchange coupling of the CGC media are investigated by Polar magneto-optic Kerr effect magnetometer and alternating gradient force magnetometer. Although H c apparently decreases at thicker capped layer, no obvious variation of macroscopic switching field distribution (SFD/H c ) is observed. We separate intrinsic switching field distribution from intergranular interactions. The investigation of reduced intrinsic SFD/H c and increased hysteresis loop slope at coercivity, suggests that improvement of absolute switching field distribution (SFD) is caused by both strong intergranular exchange coupling and uniform grain size. Micromagnetic simulation results further verify our conclusion that the capped layer in CGC media is not uniformly continuous but has some granular nature. However, grains in the CoCrPt(B) capped layer is not absolutely isolated, strong exchange coupling exists between grains. - Highlights: • In CGC media, CoCrPt magnetic grains are separated by nonmagnetic oxide

Development of intergranular thermal residual stresses in beryllium during cooling from processing temperatures

Energy Technology Data Exchange (ETDEWEB)

Brown, D.W. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)], E-mail: dbrown@lanl.gov; Sisneros, T.A.; Clausen, B.; Abeln, S.; Bourke, M.A.M.; Smith, B.G.; Steinzig, M.L.; Tome, C.N.; Vogel, S.C. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

2009-02-15

The intergranular thermal residual stresses in texture-free solid polycrystalline beryllium were determined by comparison of crystallographic lattice parameters in solid and powder samples measured by neutron diffraction during cooling from 800 deg. C. The internal stresses are not significantly different from zero >575 deg. C and increase nearly linearly <525 deg. C. At room temperature, the c axis of an average grain is under {approx}200 MPa of compressive internal stress, and the a axis is under 100 MPa of tensile stress. For comparison, the stresses have also been calculated using an Eshelby-type polycrystalline model. The measurements and calculations agree very well when temperature dependence of elastic constants is accounted for, and no plastic relaxation is allowed in the model.

Grain boundary segregation of elements of groups 14 and 15 and its consequences for intergranular cohesion of ferritic iron

Czech Academy of Sciences Publication Activity Database

Lejček, Pavel; Šandera, P.; Horníková, J.; Řehák, Petr; Pokluda, J.

2017-01-01

Roč. 52, č. 10 (2017), s. 5822-5834 ISSN 0022-2461 R&D Projects: GA ČR GAP108/12/0144; GA MŠk(CZ) LQ1601 Institutional support: RVO:68378271 ; RVO:68081723 Keywords : grain boundary segregation * segregation enthalpy * intergranular fracture * strengthening/embrittling energy Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) Impact factor: 2.599, year: 2016

Exchange functional by a range-separated exchange hole

International Nuclear Information System (INIS)

Toyoda, Masayuki; Ozaki, Taisuke

2011-01-01

An approximation to the exchange-hole density is proposed for the evaluation of the exact exchange energy in electronic structure calculations within the density-functional theory and the Kohn-Sham scheme. Based on the localized nature of density matrix, the exchange hole is divided into the short-range (SR) and long-range (LR) parts by using an adequate filter function, where the LR part is deduced by matching of moments with the exactly calculated SR counterpart, ensuring the correct asymptotic -1/r behavior of the exchange potential. With this division, the time-consuming integration is truncated at a certain interaction range, largely reducing the computation cost. The total energies, exchange energies, exchange potentials, and eigenvalues of the highest-occupied orbitals are calculated for the noble-gas atoms. The close agreement of the results with the exact values suggests the validity of the approximation.

Journal of Earth System Science | Indian Academy of Sciences

Indian Academy of Sciences (India)

The model elucidates the nature of element exchange between two minerals via the mediation of an intergranular fluid. It is shown that a coupling of thermodynamics and kinetics controls the evolution of the system and the concentration of an element in the intergranular fluid is a key parameter of interest. The results have ...

Localized deformation as a key precursor to initiation of intergranular stress corrosion cracking of austenitic stainless steels employed in nuclear power plants

International Nuclear Information System (INIS)

Karlsen, Wade; Diego, Gonzalo; Devrient, Bastian

2010-01-01

Cold-work has been associated with the occurrence of intergranular cracking of stainless steels employed in light water reactors. This study examined the deformation behavior of AISI 304, AISI 347 and a higher stacking fault energy model alloy subjected to bulk cold-work and (for 347) surface deformation. Deformation microstructures of the materials were examined and correlated with their particular mechanical response under different conditions of temperature, strain rate and degree of prior cold-work. Select slow-strain rate tensile tests in autoclaves enabled the role of local strain heterogeneity in crack initiation in pressurized water reactor environments to be considered. The high stacking fault energy material exhibited uniform strain hardening, even at sub-zero temperatures, while the commercial stainless steels showed significant heterogeneity in their strain response. Surface treatments introduced local cold-work, which had a clear effect on the surface roughness and hardness, and on near-surface residual stress profiles. Autoclave tests led to transgranular surface cracking for a circumferentially ground surface, and intergranular crack initiation for a polished surface.

Influence of Si content on the intergranular corrosion of SUS 309L stainless steels

International Nuclear Information System (INIS)

Lin, D.-Y.; Chang, T.-C.

2003-01-01

The effect of Si content on the intergranular corrosion resistance of SUS 309L stainless steels was investigated by 10 wt.% oxalic acid test, 65 wt.% boiling nitric acid test, double loop electrochemical potential reactivation (DLEPR) method, optical microscope (OM) and scanning electronic microscope (SEM). A maximum corrosion rate, weight loss of 2.80 g m -1 h, was obtained when SUS 309L stainless steel containing 0.73 wt.% Si was subjected to heat treatment at 800 deg. C for 1 h. It shows that the Cr depletion zone formed due to σ phase precipitation. The same result is obtained in DLEPR test and the ditch microstructure after oxalic test was found in samples that showed the minimum corrosion rate

Reduced Flavin: NMR investigation of N(5-H exchange mechanism, estimation of ionisation constants and assessment of properties as biological catalyst

Directory of Open Access Journals (Sweden)

Rüterjans Heinz

2005-11-01

Full Text Available Abstract Background The flavin in its FMN and FAD forms is a versatile cofactor that is involved in catalysis of most disparate types of biological reactions. These include redox reactions such as dehydrogenations, activation of dioxygen, electron transfer, bioluminescence, blue light reception, photobiochemistry (as in photolyases, redox signaling etc. Recently, hitherto unrecognized types of biological reactions have been uncovered that do not involve redox shuffles, and might involve the reduced form of the flavin as a catalyst. The present work addresses properties of reduced flavin relevant in this context. Results N(5-H exchange reactions of the flavin reduced form and its pH dependence were studied using the 15N-NMR-signals of 15N-enriched, reduced flavin in the pH range from 5 to 12. The chemical shifts of the N(3 and N(5 resonances are not affected to a relevant extent in this pH range. This contrasts with the multiplicity of the N(5-resonance, which strongly depends on pH. It is a doublet between pH 8.45 and 10.25 that coalesces into a singlet at lower and higher pH values. From the line width of the 15N(5 signal the pH-dependent rate of hydrogen exchange was deduced. The multiplicity of the 15N(5 signal and the proton exchange rates are little dependent on the buffer system used. Conclusion The exchange rates allow an estimation of the pKa value of N(5-H deprotonation in reduced flavin to be ≥ 20. This value imposes specific constraints for mechanisms of flavoprotein catalysis based on this process. On the other hand the pK ≈ 4 for N(5-H protonation (to form N(5+-H2 would be consistent with a role of N(5-H as a base.

Short intergranular cracks in the piecewise anisotropic continuum model of the microstructure

International Nuclear Information System (INIS)

Cizelj, L.; Kovse, I.

2001-01-01

Computational algorithms aiming at modeling and visualization of the initiation and growth of intergranular stress corrosion cracks (e.g., in the steam generator tubes) on the grain-size scale have already been proposed [6]. The main focus of the paper is given to the influence of randomly oriented neighboring grains on the microscopic stress fields at crack tips. The incompatibility strains, which develop along the boundaries of randomly oriented anisotropic grains, are shown to influence the local stress fields at crack tips significantly. Special attention has been paid to the implementation and comparison of different numerical methods estimating the local stress fields at crack tips, aiming at optimizing the computational time and the numerical accuracy of the results. The limited number of calculations indicate that the anisotropic arrangement of grains with local incompatibility strains causes on average about 10% (plane strain) and 26% (plane stress) higher J-integral values at the crack tips than expected from the calculations in the isotropic case.(author)

Inter-granular glassy phases in the low-CaO-doped HIPed Si{sub 3}N{sub 4} ceramics. A review

Energy Technology Data Exchange (ETDEWEB)

Gu, Hui [State Key Lab of High Performance Ceramics and Superfine Microstructures, Shanghai Inst. of Ceramics, Chinese Academy of Sciences, SH (China); Tanaka, Isao [Dept. of Materials Science and Engineering, Kyoto Univ. (Japan); Cannon, Rowland M. [Materials Science Div., Lawrence Berkeley National Lab., CA (United States); Pan, Xiaoqing [Dept. of Materials Science and Engineering, Michigan Univ., Ann Arbor (United States); Ruehle, Manfred [Max Planck Inst. for Metals Research, Stuttgart (Germany)

2010-01-15

This review outlines the essence of a progressive study on the glassy inter-granular film (IGF) in a model ceramic system, the low-CaO-doped HIPed high-purity Si{sub 3}N{sub 4}. This was initiated from the finding of a systematic variation of equilibrium IGF thickness following the dopant chemistry, manifesting its fundamental important to ceramic processing. By employing analytical transmission electron microscopy to measure the local chemistry in IGF, however, significant discrepancy was found between trends of local IGF chemistry and thickness. A stable IGF composition was revealed in this system, while a bi-level distribution of Ca segregation establishes a correspondence between the IGF structure and the surface crystallography. The detection of similar levels of nitrogen in IGF through the whole series further supports the presence of a rather stable IGF chemistry. After the saturation of dopants in the stable IGF, extra CaO was found to re-distribute in pockets by enrichment at tips, leading to a liquid phase separation with the Ca-rich phase wetting the entrance zone contacting IGF. The perspective for establishing a comprehensive correlation between the inter-granular phases and the bi-modal microstructure induced by faster growth of basal facets is briefly discussed to pave the way for future work. (orig.)

Effect of water purity on intergranular stress corrosion cracking of stainless steel and nickel alloys in BWRs

Energy Technology Data Exchange (ETDEWEB)

Gordon, B. [Structural Integrity Associates (United States); Garcia, S. [Electric Power Research Institute (United States)

2011-07-01

Boiling water reactors (BWRs) operate with very high purity water. While even the utilization of a very low conductivity water (e.g., 0.06 {mu}S/cm) coolant cannot prevent intergranular stress corrosion cracking (IGSCC) of sensitized stainless steel and nickel alloys under oxygenated conditions, the presence of certain impurities in the coolant can dramatically increase the probability of this most insidious form of corrosion. The goal of this paper is to present the effect of effect of only a few ionic impurities plus zinc on the IGSCC propensities of BWR stainless steel piping and reactor internals under both oxygenated, i.e., normal water chemistry (NWC) and deoxygenated, i.e., hydrogen water chemistry (HWC) conditions. More specifically, of the numerous impurities identified in the BWR coolant (e.g., lithium, sodium, potassium, silica, borate, chromate, phosphate, sulphate, chloride, nitrate, cuprous, cupric, ferrous, etc.) only strong acid anions sulfate and chloride that are stable in the highly reducing crack tip environment rather than the bulk water conductivity will be discussed in detail. Nitrate will be briefly discussed as representing a species that is not thermodynamically stable in the crack while the effects of zinc is discussed as a deliberate additive to the BWR environment. (authors)

Ultrasonic inspection reliability for intergranular stress corrosion cracks

Energy Technology Data Exchange (ETDEWEB)

Heasler, P G; Taylor, T T; Spanner, J C; Doctor, S R; Deffenbaugh, J D [Pacific Northwest Lab., Richland, WA (USA)

1990-07-01

A pipe inspection round robin entitled Mini-Round Robin'' was conducted at Pacific Northwest Laboratory from May 1985 through October 1985. The research was sponsored by the US Nuclear Regulatory Commission, Office of Nuclear Regulatory Research under a program entitled Evaluation and Improvement of NDE Reliability for Inservice Inspection of Light Water Reactors.'' The Mini-Round Robin (MRR) measured the intergranular stress corrosion (GSC) crack detection and sizing capabilities of inservice inspection (ISI) inspectors that had passed the requirements of IEB 83-02 and the Electric Power Research Institute (EPRI) sizing training course. The MRR data base was compared with an earlier Pipe Inspection Round Robin (PIRR) that had measured the performance of inservice inspection prior to 1982. Comparison of the MRR and PIRR data bases indicates no significant change in the inspection capability for detecting IGSCC. Also, when comparing detection of long and short cracks, no difference in detection capability was measured. An improvement in the ability to differentiate between shallow and deeper IGSCC was found when the MRR sizing capability was compared with an earlier sizing round robin conducted by the EPRI. In addition to the pipe inspection round robin, a human factors study was conducted in conjunction with the Mini-Round Robin. The most important result of the human factors study is that the Relative Operating Characteristics (ROC) curves provide a better methodology for describing inspector performance than only probability of detection (POD) or single-point crack/no crack data. 6 refs., 55 figs., 18 tabs.

Pt nanoparticle-reduced graphene oxide nanohybrid for proton exchange membrane fuel cells.

Science.gov (United States)

Park, Dae-Hwan; Jeon, Yukwon; Ok, Jinhee; Park, Jooil; Yoon, Seong-Ho; Choy, Jin-Ho; Shul, Yong-Gun

2012-07-01

A platinum nanoparticle-reduced graphene oxide (Pt-RGO) nanohybrid for proton exchange membrane fuel cell (PEMFC) application was successfully prepared. The Pt nanoparticles (Pt NPs) were deposited onto chemically converted graphene nanosheets via ethylene glycol (EG) reduction. According to the powder X-ray diffraction (XRD) pattern and transmission electron microscopy (TEM) analysis, the face-centered cubic Pt NPs (3-5 nm in diameter) were homogeneously dispersed on the RGO nanosheets. The electrochemically active surface area and PEMFC power density of the Pt-RGO nanohybrid were determined to be 33.26 m2/g and 480 mW/cm2 (maximum values), respectively, at 75 degrees C and at a relative humidity (RH) of 100% in a single-cell test experiment.

Diffusive intergranular cavity growth in creep in tension and torsion

International Nuclear Information System (INIS)

Stanzl, S.E.; Argon, A.S.; Tschegg, E.K.

1983-01-01

Creep experiments were performed at 500 C in tension and torsion on high conductivity copper tubes with a uniform initial coverage of implanted water vapor bubbles on all grain boundaries. No significant differences were found in the times to fracture over a wide stress range when the results were correlated according to the maximum principal tensile stress in the two fields. The results indicate that the cavities grow in a crack-like mode but at one tenth the rate predicted from the theoretical model of Pharr and Nix. This difference is attributed partly to load shedding from boundaries normal to the maximum principal tensile stress to slanted boundaries, and partly to a lack of knowledge about th surface diffusion constant. The results indicate further that the contribution to intergranular cavity growth by power-law creep in negligible in comparison to the contribution by diffusional flow. Complementary tension and torsion experiments performed in initially uncavitated samples results in shorter creep lives in torsion than in tension due to more effective cavity nucleation in the former. The times to fracture in both of these cases obey Monkman and Grant's law, indicating the presence of constraints on growth by the lagging deformations by power-law creep in the surroundings of the cavitating isolated grain facets

Development of Intergranular Residual Stress and Its Implication to Mechanical Behaviors at Elevated Temperatures in AL6XN Austenitic Stainless Steel

Science.gov (United States)

Hong, Yanyan; Li, Shilei; Li, Hongjia; Li, Jian; Sun, Guangai; Wang, Yan-Dong

2018-05-01

Neutron diffraction was used to investigate the residual lattice strains in AL6XN austenitic stainless steel subjected to tensile loading at different temperatures, revealing the development of large intergranular stresses after plastic deformation. Elastic-plastic self-consistent modeling was employed to simulate the micromechanical behavior at room temperature. The overall variations of the modeled lattice strains as a function of the sample direction with respect to the loading axis agree in general with the experimental values, indicating that dislocation slip is the main plastic deformation mode. At 300 °C, the serrated flow in the stress-strain curve and the great amount of slip bands indicate the appearance of dynamic strain aging. Except for promoting the local strain concentration, the long-range stress field caused by the planar slip bands near the grain boundaries is also attributed to the decrease in the experimental intergranular strains. An increase in the lattice strains localized at some specific specimen orientations for reflections at 600 °C may be explained by the segregation of solute atoms (Cr and Mo) at dislocation slip bands. The evolution of full-width at half-maximum demonstrates that the dynamic recovery indeed plays an important role in alleviating the local strain concentrations during tensile loading at 600 °C.

Assessment of susceptibility of Type 304 stainless steel to intergranular stress corrosion cracking in simulated Savannah River Reactor environments

International Nuclear Information System (INIS)

Ondrejcin, R.S.; Caskey, C.R. Jr.

1989-01-01

Intergranular stress corrosion cracking (IGSCC) of Type 304 stainless steel rate tests (CERT) of specimens machined was evaluated by constant extension from Savannah River Plant (SRP) decontaminated process water piping. Results from 12 preliminary CERT tests verified that IGSCC occurred over a wide range of simulated SRP envirorments. 73 specimens were tested in two statistical experimental designs of the central composite class. In one design, testing was done in environments containing hydrogen peroxide; in the other design, hydrogen peroxide was omitted but oxygen was added to the environment. Prediction equations relating IGSCC to temperature and environmental variables were formulated. Temperature was the most important independent variable. IGSCC was severe at 100 to 120C and a threshold temperature between 40C and 55C was identified below which IGSCC did not occur. In environments containing hydrogen peroxide, as in SRP operation, a reduction in chloride concentration from 30 to 2 ppB also significantly reduced IGSCC. Reduction in sulfate concentration from 50 to 7 ppB was effective in reducing IGSCC provided the chloride concentration was 30 ppB or less and temperature was 95C or higher. Presence of hydrogen peroxide in the environment increased IGSCC except when chloride concentration was 11 ppB or less. Actual concentrations of hydrogen peroxide, oxygen and carbon dioxide did not affect IGSCC. Large positive ECP values (+450 to +750 mV Standard Hydrogen Electrode (SHE)) in simulated SRP environments containing hydrogen peroxide and were good agreement with ECP measurements made in SRP reactors, indicating that the simulated environments are representative of SRP reactor environments. Overall CERT results suggest that the most effective method to reduce IGSCC is to reduce chloride and sulfate concentrations

Grain boundary segregation and intergranular stress corrosion cracking susceptibility of austenitic stainless steels in high temperature water

International Nuclear Information System (INIS)

Shoji, T.; Yamaki, K.; Ballinger, R.G.; Hwang, I.S.

1992-01-01

The effects of grain boundary segregation on intergranular stress corrosion cracking of austenitic stainless steels in high temperature water have been examined as a function of heat treatment. The materials investigated were: (1) two commercial purity Type 304; (2) low sulfur Type 304; (3) nuclear grade Type 304; (4) ultra high purity Type 304L; and (5) Type 316L and Type 347L. Specimens were solution treated at 1050 degrees C for 0.5 hour and given a sensitization heat treatment at 650 degrees C for 50 hours. Some of the specimens were then subjected to an aging heat treatment at 850 degrees C for from one to ten hours to cause Cr recovery at the grain boundaries. The effects of heat treatments on degree of sensitization and grain boundary segregation were evaluated by Electrochemical Potentiokinetic Reactivation (EPR) and Coriou tests, respectively. The susceptibility to stress corrosion (SCC) was evaluated using slow strain rate tests technique (SSRT) in high temperature water. SSRT tests were performed in an aerated pure water (8 ppm dissolved oxygen) at 288 degrees C at a strain rate of 1.33 x 10 -6 /sec. Susceptibility to intergranular stress corrosion cracking was compared with degree of sensitization and grain boundary segregation. The results of the investigation indicate that EPR is not always an accurate indicator of SCC susceptibility. The Coriou test provides a more reliable measure of SCC susceptibility especially for 304L, 304NG, 316L, and 347L stainless steels. The results also indicate that grain boundary segregation as well as degree of sensitization must be considered in the determination of SCC susceptibility

Effect of boric acid on intergranular corrosion in tube support plate crevices

International Nuclear Information System (INIS)

Brunet, J.P.; Campan, J.L.

1993-10-01

Intergranular attack on steam generator tubing is one important phenomenon involved in availability of Pressurized Water Reactors. Boric acid appears to be a possible candidate for inhibiting the corrosion process. The program performed in Cadarache was supposed to give statistical informations on the boric acid effect. It was based on a large number of samples initially attacked during a program performed by BABCOCK ampersand WILCOX. These samples were sleeved onto Alloy 690 tubes, in order to prevent premature cracking. Unfortunately it was not possible to find chemical conditions able to produce significant additional corrosion; we postulated mainly due to a drastic reduction of the thermal flux resulting from the increase of the tube wall thickness under the tube support plates (TSP). The tests demonstrate that such sleeve could be a possible remedy of the corrosion when introduced under the TSP. The tests show indications of a possible beneficial effect of the boric acid, a large variability of the heats sensitivity to the IGA and a predominant effect of Na 2 CO 3 on IGA production

Strongly reduced band gap in NiMn2O4 due to cation exchange

International Nuclear Information System (INIS)

Huang, Jhih-Rong; Hsu, Han; Cheng, Ching

2014-01-01

NiMn 2 O 4 is extensively used as a basis material for temperature sensors due to its negative temperature coefficient of resistance (NTCR), which is commonly attributed to the hopping mechanism involving coexisting octahedral-site Mn 4+ and Mn 3+ . Using density-functional theory + Hubbard U calculations, we identify a ferrimagnetic inverse spinel phase as the collinear ground state of NiMn 2 O 4 . By a 12.5% cation exchange, a mixed phase with slightly higher energy can be constructed, accompanied by the formation of an impurity-like band in the original 1 eV band gap. This impurity-like band reduces the gap to 0.35 eV, suggesting a possible source of NTCR. - Highlights: • Density functional based calculations were used to study collinear phase of NiMn 2 O 4 . • The ground-state structure is a ferrimagnetic inverse spinel phase. • The tetrahedral and octahedral Mn cations have ferromagnetic interactions. • A 12.5% cation exchange introduces an impurity-like band in the original 1 eV gap. • The 0.35 eV gap suggests a source of negative temperature coefficient of resistance

Origin of open recoil curves in L1_0-A1 FePt exchange coupled nanocomposite thin film

International Nuclear Information System (INIS)

Goyal, Rajan; Kapoor, Akanksha; Lamba, S.; Annapoorni, S.

2016-01-01

Mixed phase FePt systems with intergranular coupling may be looked upon as natural exchange spring systems. The coupling strength between the soft and hard phase in these systems can be analyzed using recoil curves. However, the origin of open recoil curves depicting the breakdown of exchange coupling or anisotropy variation in hard phase is still an ambiguity and requires an in-depth analysis. In order to investigate this, an analysis of the recoil curves for L1_0–A1 FePt nanocomposite thin films of varying thickness have been performed. The switching field distribution reveals that the maximum of openness of recoil curve is directly proportional to the amount of uncoupled soft phase present in the system. The coupling between the hard and soft phase is also found to increase with the thickness of the film. Monte Carlo simulations on a model three dimensional array of interacting nanomagnetic grains provide further insight into the effect of inter granular exchange interactions between the soft and hard phases. - Highlights: • L1_0-A1 FePt nanocomposites thin films of different thickness have been fabricated by DC sputtering. • Hysteresis curve measurements exhibit perfect single phase (L1_0) like behavior for thicker films. • SFD reveals that the openness of recoil curves is directly linked with the amount of uncoupled soft (A1) phase. • Monte Carlo simulation predicts that the extent of exchange interaction increases with thickness of the film.

Reheat cracking of austenitic stainless steels - pre-strain effect on intergranular damage; Fissuration en relaxation des aciers inoxydables austenitiques - influence de l'ecrouissage sur l'endommagement intergranulaire

Energy Technology Data Exchange (ETDEWEB)

Auzoux, Q

2004-01-01

Welding process induces strain in 316 stainless steel affected zones. Their microstructure was reproduce by rolling of three different steels (316L, 316L(N) et 316H). Traction, creep and relaxation tests were performed at 550 deg C and 600 deg C on smooth, notched and pre-cracked specimens. Pre-strain by rolling increases the hardness and the creep resistance because of the high dislocation density but decreases ductility because of the fast development of intergranular damage. This embrittlement leads to crack propagation during relaxation tests on pre-strained steels without distinction in respect to their carbon or nitrogen content. A new intergranular damage model was built using local micro-cracks measurements and finite elements analysis. Pre-strain effect and stress triaxiality ratio effect are reproduced by the modelling so that the reheat cracking risk near welds can now be estimated. (author)

Left-colon water exchange preserves the benefits of whole colon water exchange at reduced cecal intubation time conferring significant advantage in diagnostic colonoscopy - a prospective, randomized controlled trial.

Science.gov (United States)

Wang, Xiangping; Luo, Hui; Xiang, Yi; Leung, Felix W; Wang, Limei; Zhang, Linhui; Liu, Zhiguo; Wu, Kaichun; Fan, Daiming; Pan, Yanglin; Guo, Xuegang

2015-07-01

Whole-colon water exchange (WWE) reduces insertion pain, increases cecal intubation success and adenoma detection rate, but requires longer insertion time, compared to air insufflation (AI) colonoscopy. We hypothesized that water exchange limited to the left colon (LWE) can speed up insertion with equivalent results. This prospective, randomized controlled study (NCT01735266) allocated patients (18-80 years) to WWE, LWE or AI group (1:1:1). The primary outcome was cecal intubation time. Three hundred subjects were randomized to the WWE (n = 100), LWE (n = 100) or AI group (n = 100). Ninety-four to ninety-five per cent of patients underwent diagnostic colonoscopy. Baseline characteristics were balanced. The median insertion time was shorter in LWE group (4.8 min (95%CI: 3.2-6.2)) than those in WWE (7.5 min (95%CI: 6.0-10.3)) and AI (6.4 min (95%CI: 4.2-9.8)) (both p rates in unsedated patients of the two water exchange methods (WWE 99%, LWE 99%) were significantly higher than that (89.8%) in AI group (p = 0.01). The final success rates were comparable among the three groups after sedation was given. Maximum pain scores and number of patients needing abdominal compression between WWE and LWE groups were comparable, both lower than those in AI group (p higher in WWE group. By preserving the benefits of WWE and reducing insertion time, LWE is appropriate for diagnostic colonoscopy, especially in settings with tight scheduling of patients. The higher PDR in the right colon in WWE group deserves to be further investigated.

Anion exchange membrane

Science.gov (United States)

Verkade, John G; Wadhwa, Kuldeep; Kong, Xueqian; Schmidt-Rohr, Klaus

2013-05-07

An anion exchange membrane and fuel cell incorporating the anion exchange membrane are detailed in which proazaphosphatrane and azaphosphatrane cations are covalently bonded to a sulfonated fluoropolymer support along with anionic counterions. A positive charge is dispersed in the aforementioned cations which are buried in the support to reduce the cation-anion interactions and increase the mobility of hydroxide ions, for example, across the membrane. The anion exchange membrane has the ability to operate at high temperatures and in highly alkaline environments with high conductivity and low resistance.

Origin of open recoil curves in L1{sub 0}-A1 FePt exchange coupled nanocomposite thin film

Energy Technology Data Exchange (ETDEWEB)

Goyal, Rajan [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Kapoor, Akanksha [M. Tech Nanoscience and Nanotechnology, University of Delhi, Delhi 110007 (India); Lamba, S. [School of Sciences, Indira Gandhi National Open University, New Delhi 110068 (India); Annapoorni, S., E-mail: annapoornis@yahoo.co.in [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India)

2016-11-15

Mixed phase FePt systems with intergranular coupling may be looked upon as natural exchange spring systems. The coupling strength between the soft and hard phase in these systems can be analyzed using recoil curves. However, the origin of open recoil curves depicting the breakdown of exchange coupling or anisotropy variation in hard phase is still an ambiguity and requires an in-depth analysis. In order to investigate this, an analysis of the recoil curves for L1{sub 0}–A1 FePt nanocomposite thin films of varying thickness have been performed. The switching field distribution reveals that the maximum of openness of recoil curve is directly proportional to the amount of uncoupled soft phase present in the system. The coupling between the hard and soft phase is also found to increase with the thickness of the film. Monte Carlo simulations on a model three dimensional array of interacting nanomagnetic grains provide further insight into the effect of inter granular exchange interactions between the soft and hard phases. - Highlights: • L1{sub 0}-A1 FePt nanocomposites thin films of different thickness have been fabricated by DC sputtering. • Hysteresis curve measurements exhibit perfect single phase (L1{sub 0}) like behavior for thicker films. • SFD reveals that the openness of recoil curves is directly linked with the amount of uncoupled soft (A1) phase. • Monte Carlo simulation predicts that the extent of exchange interaction increases with thickness of the film.

ZEISIG: Approximate calculation of the intergranular gas fraction and the intragranular gas driven swelling for SAS4A

International Nuclear Information System (INIS)

Vaeth, L.

1993-02-01

A simple model has been developed for estimating, under steady-state irradiation conditions and for operational transients, the fraction of intergranular gas residing in fast reactor fuel and the intragranular gas driven swelling. The total gas retention in the fuel, the grain size and the irradiation conditions (mainly time dependent temperatures) must be known. Use has been made of parts of the fission gas model contained in the code LAKU and of results calculated with this code. The routine (named ZEISIG) is intended for insertion into the fast reactor accident model SAS4A as an extension of its fission gas model for steady-state reactor operation. (orig.) [de

Intergranular Corrosion Behavior of Low-Nickel and 304 Austenitic Stainless Steels

Science.gov (United States)

Bansod, Ankur V.; Patil, Awanikumar P.; Moon, Abhijeet P.; Khobragade, Nilay N.

2016-09-01

Intergranular corrosion (IGC) susceptibility for Cr-Mn austenitic stainless steel and 304 austenitic stainless steel (ASS) was estimated using electrochemical techniques. Optical and SEM microscopy studies were carried out to investigate the nature of IGC at 700 °C with increasing time (15, 30, 60, 180, 360, 720, 1440 min) according to ASTM standard 262 A. Quantitative analysis was performed to estimate the degree of sensitization (DOS) using double loop electrochemical potentiokinetic reactivation (DLEPR) and EIS technique. DLEPR results indicated that with the increase in thermal aging duration, DOS becomes more severe for both types of stainless steel. The DOS for Cr-Mn ASS was found to be higher (65.12% for 1440 min) than that of the AISI 304 ASS (23% for 1440 min). The higher degree of sensitization resulted in lowering of electrical charge capacitance resistance. Chronoamperometry studies were carried out at a passive potential of 0.4 V versus SCE and was observed to have a higher anodic dissolution of the passive film of Cr-Mn ASS. EDS studies show the formation of chromium carbide precipitates in the vicinity of the grain boundary. The higher Mn content was also observed for Cr-Mn ASS at the grain boundary.

Interfacial reactions in Ti-6Al-4V with laser-embedded SiC particles and the origin of intergranular corrosion susceptibility of an Al-Mg alloy

NARCIS (Netherlands)

Kooi, BJ; De Hosson, JTM; Carter, CB; Hall, EL; Nutt,; Briant, CL

2000-01-01

In the first part of the paper the microstructure of Ti-6Al-4V with laser embedded SiC particle is explained. The interfacial reaction between Ti and SiC is responsible for the largely improved wear resistance of the Ti alloy. In the second part the phase responsible for the intergranular corrosion

A phenomenological variational multiscale constitutive model for intergranular failure in nanocrystalline materials

KAUST Repository

Siddiq, A.

2013-09-01

We present a variational multiscale constitutive model that accounts for intergranular failure in nanocrystalline fcc metals due to void growth and coalescence in the grain boundary region. Following previous work by the authors, a nanocrystalline material is modeled as a two-phase material consisting of a grain interior phase and a grain boundary affected zone (GBAZ). A crystal plasticity model that accounts for the transition from partial dislocation to full dislocation mediated plasticity is used for the grain interior. Isotropic porous plasticity model with further extension to account for failure due to the void coalescence was used for the GBAZ. The extended model contains all the deformation phases, i.e. elastic deformation, plastic deformation including deviatoric and volumetric plasticity (void growth) followed by damage initiation and evolution due to void coalescence. Parametric studies have been performed to assess the model\\'s dependence on the different input parameters. The model is then validated against uniaxial loading experiments for different materials. Lastly we show the model\\'s ability to predict the damage and fracture of a dog-bone shaped specimen as observed experimentally. © 2013 Elsevier B.V.

Numerical modelling of intergranular fracture in polycrystalline materials and grain size effects

Directory of Open Access Journals (Sweden)

P. Wriggers

2011-07-01

Full Text Available In this paper, the phenomenon of intergranular fracture in polycrystalline materials is investigated using a nonlinear fracture mechanics approach. The nonlocal cohesive zone model (CZM for finite thickness interfaces recently proposed by the present authors is used to describe the phenomenon of grain boundary separation. From the modelling point of view, considering the dependency of the grain boundary thickness on the grain size observed in polycrystals, a distribution of interface thicknesses is obtained. Since the shape and the parameters of the nonlocal CZM depend on the interface thickness, a distribution of interface fracture energies is obtained as a consequence of the randomness of the material microstructure. Using these data, fracture mechanics simulations are performed and the homogenized stress-strain curves of 2D representative volume elements (RVEs are computed. Failure is the result of a diffuse microcrack pattern leading to a main macroscopic crack after coalescence, in good agreement with the experimental observation. Finally, testing microstructures characterized by different average grain sizes, the computed peak stresses are found to be dependent on the grain size, in agreement with the trend expected according to the Hall-Petch law.

Direct visualization of β phase causing intergranular forms of corrosion in Al–Mg alloys

Energy Technology Data Exchange (ETDEWEB)

Yang, Young-Ki, E-mail: deltag@naver.com; Allen, Todd

2013-06-15

For a more effective examination of microstructure in Al–Mg alloys, a new etching solution has been developed; dissolved ammonium persulfate in water. It is demonstrated how β phase (Al{sub 3}Mg{sub 2}) in Al–Mg alloys respond to this solution using samples of a binary Al–Mg alloy and a commercial 5083 aluminum alloy. Nanometer sized β phase is clearly visualized for the first time using scanning electron microscopy (SEM) instead of transmission electron microscopy (TEM). It is anticipated that direct and unambiguous visualization of β phase will greatly augment intergranular corrosion research in 5xxx series aluminum alloys. - Highlights: • Nanometer sized β phase in Al-10% Mg is first clearly visualized with SEM. • Nanometer sized β phase in wrought alloy 5083 is first clearly visualized with SEM. • Grain boundary decorating β phase and isolated sponge-like β phase are shown. • This phase is confirmed to be β phase using composition analysis.

Evolution of interphase and intergranular strain in zirconium-niobium alloys during deformation at room temperature

Science.gov (United States)

Cai, Song

Zr-2.5Nb is currently used for pressure tubes in the CANDU (CANada Deuterium Uranium) reactor. A complete understanding of the deformation mechanism of Zr-2.5Nb is important if we are to accurately predict the in-reactor performance of pressure tubes and guarantee normal operation of the reactors. This thesis is a first step in gaining such an understanding; the deformation mechanism of ZrNb alloys at room temperature has been evaluated through studying the effect of texture and microstructure on deformation. In-situ neutron diffraction was used to monitor the evolution of the lattice strain of individual grain families along both the loading and Poisson's directions and to track the development of interphase and intergranular strains during deformation. The following experiments were carried out with data interpreted using elasto-plastic modeling techniques: (1) Compression tests of a 100%betaZr material at room temperature. (2) Tension and compression tests of hot rolled Zr-2.5Nb plate material. (3) Compression of annealed Zr-2.5Nb. (4) Cyclic loading of the hot rolled Zr-2.5Nb. (5) Compression tests of ZrNb alloys with different Nb and oxygen contents. The experimental results were interpreted using a combination of finite element (FE) and elasto-plastic self-consistent (EPSC) models. The phase properties and phase interactions well represented by the FE model, the EPSC model successfully captured the evolution of intergranular constraint during deformation and provided reasonable estimates of the critical resolved shear stress and hardening parameters of different slip systems under different conditions. The consistency of the material parameters obtained by the EPSC model allows the deformation mechanism at room temperature and the effect of textures and microstructures of ZrNb alloys to be understood. This work provides useful information towards manufacturing of Zr-2.5Nb components and helps in producing ideal microstructures and material properties for

In-situ observation of intergranular stress corrosion cracking in AA2024-T3 under constant load conditions

International Nuclear Information System (INIS)

Liu Xiaodong; Frankel, G.S.; Zoofan, B.; Rokhlin, S.I.

2007-01-01

A specially designed setup was used to apply a constant load to a thin sheet sample of AA2024-T3 and, using microfocal X-ray radiography, to observe in situ the resulting intergranular stress corrosion cracking (IGSCC) from the exposed edge of the sample. The growth of and competition between multiple IGSCC sites was monitored. In many experiments twin cracks initiated close to each other. Furthermore, the deepest crack at the beginning of every experiment was found to slow or stop growing, and was then surpassed by another crack that eventually penetrated through the sample. These observations cannot be explained by the theory of fracture mechanics in inert environments. The possible mechanisms underlying the competition between cracks are discussed

Application of Principal Component Analysis (PCA) to Reduce Multicollinearity Exchange Rate Currency of Some Countries in Asia Period 2004-2014

Science.gov (United States)

Rahayu, Sri; Sugiarto, Teguh; Madu, Ludiro; Holiawati; Subagyo, Ahmad

2017-01-01

This study aims to apply the model principal component analysis to reduce multicollinearity on variable currency exchange rate in eight countries in Asia against US Dollar including the Yen (Japan), Won (South Korea), Dollar (Hong Kong), Yuan (China), Bath (Thailand), Rupiah (Indonesia), Ringgit (Malaysia), Dollar (Singapore). It looks at yield…

A study of intergranular corrosion of austenitic stainless steel by electrochemical potentiodynamic reactivation, electron back-scattering diffraction and cellular automaton

Energy Technology Data Exchange (ETDEWEB)

Yu Xiaofei [Department of Chemistry, Shandong University, Jinan 250100 (China); Chen Shenhao [Department of Chemistry, Shandong University, Jinan 250100 (China); State Key Laboratory for Corrosion and Protection, Shenyang 110016 (China)], E-mail: shchen@sdu.edu.cn; Liu Ying; Ren Fengfeng [Department of Chemistry, Shandong University, Jinan 250100 (China)

2010-06-15

The impact of solution and sensitization treatments on the intergranular corrosion (IGC) of austenitic stainless steel (316) was studied by electrochemical potentiodynamic reactivation (EPR) test, and the results showed the degree of sensitization (DOS) decreased as solution treatment temperature and time went up, but it increased as sensitization temperature prolonged. Factors that affected IGC were investigated by field emission scanning electron microscope (FE-SEM) and electron back-scattering diffraction (EBSD). Furthermore, the precipitation evolution of Cr-rich carbides and the distribution of chromium concentration were simulated by cellular automaton (CA), clearly showing the effects of solution and sensitization treatments on IGC.

Atomistic Structure, Strength, and Kinetic Properties of Intergranular Films in Ceramics

Energy Technology Data Exchange (ETDEWEB)

Garofalini, Stephen H

2015-01-08

Intergranular films (IGFs) present in polycrystalline oxide and nitride ceramics provide an excellent example of nanoconfined glasses that occupy only a small volume percentage of the bulk ceramic, but can significantly influence various mechanical, thermal, chemical, and optical properties. By employing molecular dynamics computer simulations, we have been able to predict structures and the locations of atoms at the crystal/IGF interface that were subsequently verified with the newest electron microscopies. Modification of the chemistry of the crystal surface in the simulations provided the necessary mechanism for adsorption of specific rare earth ions from the IGF in the liquid state to the crystal surface. Such results had eluded other computational approaches such as ab-initio calculations because of the need to include not only the modified chemistry of the crystal surfaces but also an accurate description of the adjoining glassy IGF. This segregation of certain ions from the IGF to the crystal caused changes in the local chemistry of the IGF that affected fracture behavior in the simulations. Additional work with the rare earth ions La and Lu in the silicon oxynitride IGFs showed the mechanisms for their different affects on crystal growth, even though both types of ions are seen adhering to a bounding crystal surface that would normally imply equivalent affects on grain growth.

Grain-boundary microchemistry and intergranular cracking of irradiated austenitic stainless steels

International Nuclear Information System (INIS)

Chung, H.M.; Ruther, W.E.; Sanecki, J.E.; Kassner, T.F.

1993-01-01

Constant-extension-rate tensile tests and grain-boundary analysis by Auger electron spectroscopy were conducted on high and commercial-purity (HP and CP) Type 304 stainless steel (SS) specimens from irradiated boiling-water reactor (BWR) components to identify the mechanisms of irradiation-assisted stress corrosion cracking (IASCC). Contrary to previous beliefs, susceptibility to intergranular fracture could not be correlated with radiation-induced segregation of impurities such as Si, P, C, or S, but a correlation was obtained with grain-boundary Cr concentration, indicating a role for Cr depletion. Detailed analysis of grain-boundary chemistry was conducted on BWR neutron absorber tubes that were fabricated from two similar heats of HP Type 304 SS of virtually identical bulk chemical composition but exhibiting a significant difference in susceptibility to IASCC after irradiation to ∼2 x 10 21 n/cm 2 (E > 1 MeV). Grain-boundary concentrations of Cr Ni, Si, P, S, and C of the cracking-resistant and -susceptible HP heats were virtually identical. However, grain boundaries of the cracking-resistant material contained less N and more B and Li than those of the cracking-susceptible material. This observation indicates that, besides the deleterious effect of grain-boundary Cr depletion, a synergism between grain-boundary segregation of N and B and transmutation to H and Li plays an important role in IASCC

Electrochemical Methods for the Intergranular Corrosion Property Evaluation of Stainless Steels

International Nuclear Information System (INIS)

Lee, Jung Bok

1987-01-01

For the last fifteen years, the Electrochemical Potentiokinetic Reactivation (EPR) method, an electrochemical method, has been actively investigated for use in determining the degree of sensitization (DOS) in stainless steels (a metallurgical structure susceptible to intergranular corrosion). One of the reasons for this active investigation was due to the fact that the technique may be usable for field nondestructive measurements of DOS in stainless steels. In this paper, a brief overview of the technique, including the advantages and limitations, is discussed. Then, a new test method which is able to detect the sensitized metallurgical structures nondestructively after field welding is introduced. This new nondestructive method is a modification of the ASTM A262-A (the oxalic acid etch test). The improved test method employs a 30 second etching in a 10% oxalic acid solution under an anodic current density of 1 ampere per square centimeter at the temperatures above 60 .deg. C. Between 50 and 60 .deg. C the thirty second etching test should be used first. When the thirty second etching shows an under etched grain boundary, the etching time should be increased to ninety seconds. At temperatures below 50 .deg. C the ninety second etching, as described in ASTM A 262-A, should be employed. This improved test method can be used in the temperature range of 0 and 100 .deg. C

Effect of static mixer on the performance of compact plate heat exchanger with zwitterionic type of drag-reducing additives

Energy Technology Data Exchange (ETDEWEB)

Blais, C.; Wollerstrand, J.

1997-06-01

The main task of the project was to investigate the influence of drag-reducing additives (DRA) dissolved in circulating hot water on heat transfer in compact plate heat exchangers (PHE). Furthermore the result of flow disturbance (static mixing) immediately before the PHE on pressure drop and heat transfer was clarified. The project used a new type of DRA (surfactants of zwitterionic type) for two different temperature ranges. A dedicated test rig, `Ansgar`, was built for the purpose. Good thermal and mechanical stability also outside the operating range was observed except some sensitivity for water hardness at high temperatures for DRA2. Similarly to known investigations, the heat transfer coefficient was significantly reduced by DRA in heat exchangers. In PHE used however, the heat transfer reduction was considerably lower in the high flow region. A static mixer placed in front of the PHE was found to significantly improve heat transfer, especially at high flow rates. On the other hand, an additional pressure drop was introduced. Therefore the optimal choice of static mixer needs further investigation. Specially designed PHE combining mixing and heat transfer functions could be beneficial to reducing the effects of additives in thermal systems. The relaxation time (RT) of drag-reducing additives in water solutions flowing through test pipes with known geometries was estimated by monitoring specific pressure drop variation along the pipe. These preliminary experiments in respect to relaxation time showed that RT depends on the flow rate and on the temperature 12 refs, 11 figs, 1 tab

Effect of laser heat treatment on intergranular corrosion of austenitic stainless steel; Austenite kei stainless ko no ryukai fushoku kanjusei ni oyobosu laser netsushori no eikyo

Energy Technology Data Exchange (ETDEWEB)

Osawa, M.; Yoneyama, T. [Tokyo Denki University, Tokyo (Japan). Faculty of Engineering; Isshiki, Y. [Tokyo Metropolitan Industrial Technology Center, Tokyo (Japan)

1995-03-15

The laser heat treatment of SUS304 steel was studied to lower the intergranular corrosion sensitivity of austenitic stainless steel. By the short-time heating around 923K, the SUS304 steel is sensitized to the intergranular corrosion with the deposition of Cr carbide into the granular field of crystals. To recover it, it is necessary to solidly dissolve, and simultaneously, quickly cool the Cr carbide above 1273K. For such solution heat treatment, CO2 laser beams were used with the treatment condition that the power and beam diameter were 800 to 1200W and 0.3 to 0.64cm, respectively. Regardless of both power density and beam diameter, the desensitization was observed at heating temperatures above 1323K. As a result of calculation by simulation, the solid dissolution of Cr carbide and recovery of Cr`s depletion zone in the granular field of crystals took place in a very short time at heating temperatures above 1323K. It agreed well with the experimental result. The laser beams are effective in the solution heat treatment of stainless steel. 14 refs., 15 figs., 1 tab.

Intergranular fluid compositions from the Waste Isolation Pilot Plant (WIPP) southeastern New Mexico

International Nuclear Information System (INIS)

Krumhansl, J.L.; Kimball, K.M.; Stein, C.L.

1991-01-01

The objective of this study was to perform a systematic sampling of the intergranular brines that slowly ''weep'' from four of the main stratigraphic units exposed in the WIPP. This information was added to the data base on brine compositions used in performance assessment and also employed in characterizing Salado Formation hydrology at the repository horizon. Concentrations of Na, K, Mg, Ca, Cl, SO 4 , and Br were all highly variable. It was also established that this variability reflects neither post-excavation evaporation nor imprecision in the analytical techniques. Compositional variability on the length scale of a few tens of centimeters is as large as that found over several hundreds of meters. Stratigraphy did not appear to exert any control over weep brine compositions. Programmatically relevant applications of these results are: (1) a valid performance assessment must consider the possibility of a wide range of brines, rather than carry out evaluations using a single ''best'' average brine, and (2) the Salado appears not to function as a continuous aquifer since brines originating millions of years ago have failed to homogenize though separated by only short distances. 10 refs., 19 figs., 11 tabs

Coercivity enhancement of Nd–Fe–B sintered magnets with intergranular adding (Pr, Dy, Cu)−H{sub x} powders

Energy Technology Data Exchange (ETDEWEB)

Zhang, Yujing; Ma, Tianyu, E-mail: maty@zju.edu.cn; Liu, Xiaolian; Liu, Pan; Jin, Jiaying; Zou, Junding; Yan, Mi, E-mail: mse_yanmi@zju.edu.cn

2016-02-01

Forming Nd{sub 2}Fe{sub 14}B/(Nd, Dy){sub 2}Fe{sub 14}B core–shell structure by intergranular adding Dy-containing sources into Nd–Fe–B sintered magnets is effective to improve coercivity and to minimize remanence loss simultaneously. However, the excessive Dy located in the intergranular regions has nearly no hard magnetic contribution, causing its low utilization efficiency. In this work, diluted Dy powders (Pr{sub 37}Dy{sub 30}Cu{sub 33})–H{sub x} were prepared and incorporated into Nd–Fe–B sintered magnets via a dual-alloy approach. The coercivity increases rapidly from 15.0 to 18.2 kOe by 21.3% with 2.0 wt% (Pr, Dy, Cu)–H{sub x} addition (the equivalent Dy is only 0.32 at%). The deduced coercivity incremental ratio is 10.0 kOe per unit Dy at%. Dehydrogenation reaction of (Pr, Dy, Cu)–H{sub x} occurs during sintering, which favors Dy diffusion towards the 2:14:1 phase grains as well as smoothing the grain boundaries (GBs). The enhanced local anisotropic field and the well decoupled 2:14:1 phase grains contribute to such rapid coercivity enhancement. This work suggests that adding diluted Dy hydrides is promising for fabricating high coercivity Nd–Fe–B sintered magnets with less heavy rare-earth consumption. - Highlights: • (Pr, Dy, Cu)–H{sub x} hydride powders were introduced into Nd–Fe–B sintered magnets. • Rapid coercivity enhancement from 15.0 kOe to 18.2 kOe with only 0.32 at% Dy was realized. • High utilization efficiency of Dy was achieved due to its promoted diffusion process. • Wettability and mobility of grain boundary phase was improved.

Investigation and application of reduced-order methods for flows study in heat exchanger tube bundles

International Nuclear Information System (INIS)

Pomarede, M.

2012-01-01

The objective of this thesis is to study the ability of model reduction for investigations of flow-induced vibrations in heat exchangers tube bundle systems.These mechanisms are a cause of major concern because heat exchangers are key elements of nuclear power plants and on-board stoke-holds.In a first part, we give a recall on heat exchangers functioning and on vibratory problems to which they are prone. Then, complete calculations leaded with the CFD numerical code Code-Saturne are carried out, first for the flow around a single circular cylinder (fixed then elastically mounted) and then for the case of a tube bundle system submitted to cross-flow. Reduced-order method POD is applied to the flow resolution with fixed structures. The obtained results show the efficiency of this technique for such configurations, using stabilization methods for the dynamical system resolution in the tube-bundle case. Multiphase-POD, which is a method enabling the adaptation of POD to fluid-structure interactions, is applied. Large displacements of a single cylinder elastically mounted under cross-flow, corresponding to the lock-in phenomenon,are well reproduced with this reduction technique. In the same way, large displacements of a confined moving tube in a bundle are shown to be faithfully reconstructed.Finally, the use of model reduction is extended to parametric studies. First, we propose to use the method which consists in projecting Navier-Stokes equations for several values of the Reynolds number on to a unique POD basis. The results obtained confirm the fact that POD predictability is limited to a range of parameter values. Then, a basis interpolation method, constructed using Grassmann manifolds and allowing the construction of a POD basis from other pre-calculated basis, is applied to basic cases. (author)

Reducing employees’ turnover intention through Hr-induced organizational citizenship behaviour: Leader-member exchange as the mediator

Directory of Open Access Journals (Sweden)

YU GHEE WEE

2013-07-01

Full Text Available This study examines the possibility of inducing organizational citizenship behavior (OCB through human resource (HR philosophy and high involvement HR practices administered at the workplace. Leader-member exchange (LMX, a basis of relational infrastructure, is posited to be a potential mediator. Data was collected from hotel frontline employees, tested and analyzed through structural equation modeling. Findings show that HR philosophy drives the formulation of the bundles of high involvement human resource practices and such philosophy contribute to employees’ willingness in exhibiting organizational citizenship behavior (OCB directed at individuals (OCBI as well as organizations (OCBO as a whole. High involvement HR practices, however, do not elicit OCB but these practices are significantly related to LMX, a new theoretical insight which should invite future research. Although exchanges between supervisors and subordinates are shown to have influences on employees’ willingness in performing OCB, LMX does not, however, mediate the relationship between high involvement HR practices and OCB. Overall, hotel frontline employees participated in this study exhibit more OCBO, rather than OCBI; and such behavior reduce their intention to leave. Both theoretical and practical implications as well as avenues for future research are discussed.

Exchange rate policy

Directory of Open Access Journals (Sweden)

Plačkov Slađana

2013-01-01

Full Text Available Small oscillations of exchange rate certainly affect the loss of confidence in the currency (Serbian dinar, CSD and because of the shallow market even the smallest change in the supply and demand leads to a shift in exchange rate and brings uncertainty. Some economists suggest that the course should be linked to inflation and thus ensure predictable and stable exchange rates. Real exchange rate or slightly depressed exchange rate will encourage the competitiveness of exporters and perhaps ensure the development of new production lines which, in terms of overvalued exchange rate, had no economic justification. Fixed exchange rate will bring lower interest rates, lower risk and lower business uncertainty (uncertainty avoidance, but Serbia will also reduce foreign exchange reserves by following this trend. On the other hand, a completely free exchange rate, would lead to a (real fall of Serbian currency, which in a certain period would lead to a significant increase in exports, but the consequences for businessmen and citizens with loans pegged to the euro exchange rate, would be disastrous. We will pay special attention to the depreciation of the exchange rate, as it is generally favorable to the export competitiveness of Serbia and, on the other hand, it leads to an increase in debt servicing costs of the government as well as of the private sector. Oscillations of the dinar exchange rate, appreciation and depreciation, sometimes have disastrous consequences on the economy, investors, imports and exports. In subsequent work, we will observe the movement of the dinar exchange rate in Serbia, in the time interval 2009-2012, in order to strike a balance and maintain economic equilibrium. A movement of foreign currencies against the local currency is controlled in the foreign exchange market, so in case economic interests require, The National Bank of Serbia (NBS, on the basis of arbitrary criteria, can intervene in the market.

Grain boundary selective oxidation and intergranular stress corrosion crack growth of high-purity nickel binary alloys in high-temperature hydrogenated water

Energy Technology Data Exchange (ETDEWEB)

Bruemmer, S. M.; Olszta, M. J.; Toloczko, M. B.; Schreiber, D. K.

2018-02-01

The effects of alloying elements in Ni-5at%X binary alloys on intergranular (IG) corrosion and stress corrosion cracking (SCC) have been assessed in 300-360°C hydrogenated water at the Ni/NiO stability line. Alloys with Cr or Al additions exhibited grain boundary oxidation and IGSCC, while localized degradation was not observed for pure Ni, Ni-Cu or Ni-Fe alloys. Environment-enhanced crack growth was determined by comparing the response in water and N2 gas. Results demonstrate that selective grain boundary oxidation of Cr and Al promoted IGSCC of these Ni alloys in hydrogenated water.

Minimizing Back Exchange in the Hydrogen Exchange-Mass Spectrometry Experiment

Science.gov (United States)

Walters, Benjamin T.; Ricciuti, Alec; Mayne, Leland; Englander, S. Walter

2012-12-01

The addition of mass spectrometry (MS) analysis to the hydrogen exchange (HX) proteolytic fragmentation experiment extends powerful HX methodology to the study of large biologically important proteins. A persistent problem is the degradation of HX information due to back exchange of deuterium label during the fragmentation-separation process needed to prepare samples for MS measurement. This paper reports a systematic analysis of the factors that influence back exchange (solution pH, ionic strength, desolvation temperature, LC column interaction, flow rates, system volume). The many peptides exhibit a range of back exchange due to intrinsic amino acid HX rate differences. Accordingly, large back exchange leads to large variability in D-recovery from one residue to another as well as one peptide to another that cannot be corrected for by reference to any single peptide-level measurement. The usual effort to limit back exchange by limiting LC time provides little gain. Shortening the LC elution gradient by 3-fold only reduced back exchange by ~2 %, while sacrificing S/N and peptide count. An unexpected dependence of back exchange on ionic strength as well as pH suggests a strategy in which solution conditions are changed during sample preparation. Higher salt should be used in the first stage of sample preparation (proteolysis and trapping) and lower salt (<20 mM) and pH in the second stage before electrospray injection. Adjustment of these and other factors together with recent advances in peptide fragment detection yields hundreds of peptide fragments with D-label recovery of 90 % ± 5 %.

Minimizing back exchange in the hydrogen exchange-mass spectrometry experiment.

Science.gov (United States)

Walters, Benjamin T; Ricciuti, Alec; Mayne, Leland; Englander, S Walter

2012-12-01

The addition of mass spectrometry (MS) analysis to the hydrogen exchange (HX) proteolytic fragmentation experiment extends powerful HX methodology to the study of large biologically important proteins. A persistent problem is the degradation of HX information due to back exchange of deuterium label during the fragmentation-separation process needed to prepare samples for MS measurement. This paper reports a systematic analysis of the factors that influence back exchange (solution pH, ionic strength, desolvation temperature, LC column interaction, flow rates, system volume). The many peptides exhibit a range of back exchange due to intrinsic amino acid HX rate differences. Accordingly, large back exchange leads to large variability in D-recovery from one residue to another as well as one peptide to another that cannot be corrected for by reference to any single peptide-level measurement. The usual effort to limit back exchange by limiting LC time provides little gain. Shortening the LC elution gradient by 3-fold only reduced back exchange by ~2%, while sacrificing S/N and peptide count. An unexpected dependence of back exchange on ionic strength as well as pH suggests a strategy in which solution conditions are changed during sample preparation. Higher salt should be used in the first stage of sample preparation (proteolysis and trapping) and lower salt (<20 mM) and pH in the second stage before electrospray injection. Adjustment of these and other factors together with recent advances in peptide fragment detection yields hundreds of peptide fragments with D-label recovery of 90% ± 5%.

Heat exchanger performance monitoring guidelines

International Nuclear Information System (INIS)

Stambaugh, N.; Closser, W. Jr.; Mollerus, F.J.

1991-12-01

Fouling can occur in many heat exchanger applications in a way that impedes heat transfer and fluid flow and reduces the heat transfer or performance capability of the heat exchanger. Fouling may be significant for heat exchanger surfaces and flow paths in contact with plant service water. This report presents guidelines for performance monitoring of heat exchangers subject to fouling. Guidelines include selection of heat exchangers to monitor based on system function, safety function and system configuration. Five monitoring methods are discussed: the heat transfer, temperature monitoring, temperature effectiveness, delta P and periodic maintenance methods. Guidelines are included for selecting the appropriate monitoring methods and for implementing the selected methods. The report also includes a bibliography, example calculations, and technical notes applicable to the heat transfer method

Method of burning ion-exchange resin contaminated with radioactivity

International Nuclear Information System (INIS)

Suzuki, Shigenori.

1986-01-01

Purpose: To process spent ion exchange resins to reduce their volume, without increasing the load on a off-gas system and in a stable state and at the same time not leaving any uncombusted portions. Method: The water slurries of the ion exchange resins contaminated with radioactive materials is dehydrated or dry combusted to reduce the water content. A binder is then added to solidify the ion exchange resin. The solidified ion exchange resins are then combusted in a furnace. This prevents the ion exchange resin from being dispersed by air and combustion gases. Furthermore, the solidified ion exchange resins in the form of small pellets burn from the surface inwards. Moreover the binder is carbonized by the combustion heat and promotes combustion to convert the ion exchange resins into a solid mass, making sure that no uncombusted portion is left. (Takahashi, M.)

Strain-Annealing Based Grain Boundary Engineering to Evaluate its Sole Implication on Intergranular Corrosion in Extra-Low Carbon Type 304L Austenitic Stainless Steel

Science.gov (United States)

Pradhan, S. K.; Bhuyan, P.; Kaithwas, C.; Mandal, Sumantra

2018-07-01

Strain-annealing based thermo-mechanical processing has been performed to promote grain boundary engineering (GBE) in an extra-low carbon type austenitic stainless steel without altering the grain size and residual strain to evaluate its sole influence on intergranular corrosion. Single-step processing comprising low pre-strain ( 5 and 10 pct) followed by annealing at 1273 K for 1 hour have resulted in a large fraction of Σ3 n boundaries and significant disruption in random high-angle grain boundaries (RHAGBs) connectivity. This is due to the occurrence of prolific multiple twinning in these specimens as confirmed by their large twin-related domain and twin-related grain size ratio. Among the iterative processing, the schedule comprising two cycles of 10 and 5 pct deformation followed by annealing at 1173 K for 1 hour has yielded the optimum GBE microstructure with the grain size and residual strain akin to the as-received condition. The specimens subjected to the higher number of iterations failed to realize GBE microstructures due to the occurrence of partial recrystallization. Owing to the optimum grain boundary character distribution, the GBE specimen has exhibited remarkable resistance against sensitization and intergranular corrosion as compared to the as-received condition. Furthermore, the lower depth of percolation in the GBE specimen is due to the significant disruption of RHAGBs connectivity as confirmed from its large twin-related domain and lower fractal dimension.

The intergranular segregation of boron in substoichiometric Ni/sub 3/Al

Energy Technology Data Exchange (ETDEWEB)

Choudhury, A.

1987-12-01

The intermetallic compound Ni/sub 3/Al offers promise as a material for high temperature applications. In addition to its unusual property of increasing strength with temperature (until approx.700/sup 0/C), it has excellent corrosion and oxidation resistance. Microalloying the alloy with boron has been shown to be dramatically effective in improving its inherent intergranular brittleness. This improvement results from the strong tendency of boron to segregate to the grain boundaries of Ni/sub 3/Al. This research deals with the study of the segregation behavior of boron. Auger electron spectroscopy was chosen as the technique adopted to study this segregation. The strong effect of segregant level on the grain boundary strength level can be controlled by thermal history variations and by variations in the level of solute in the bulk. Cathodic hydrogen charging was shown to be a potent tool in opening up other wise cohesive boundaries for analysis. The effective binding energy of boron at the grain boundaries of Ni/sub 3/Al was calculated from experimental data; it was found to vary between 0.2 and 0.45 eV. Kinetics of segregation have been investigated; the present set of kinetic studies were shown to be inadequate to find a diffusion coefficient and that temperatures lower than those studied here need to be used. As an associated investigation, a set of elemental standards were developed for the particular scanning Auger microprobe used in this study. 141 refs., 94 figs., 26 tabs.

Oxygen-induced intergranular fracture of the nickel-base alloy IN718 during mechanical loading at high temperatures

Directory of Open Access Journals (Sweden)

Krupp Ulrich

2004-01-01

Full Text Available There is a transition in the mechanical-failure behavior of nickel-base superalloys from ductile transgranular crack propagation to time-dependent intergranular fracture when the temperature exceeds about 600 °C. This transition is due to oxygen diffusion into the stress field ahead of the crack tip sufficient to cause brittle decohesion of the grain boundaries. Since very high cracking rates were observed during fixed-displacement loading of IN718, it is not very likely that grain boundary oxidation governs the grain-boundary-separation process, as has been proposed in several studies on the fatigue-damage behavior of the nickel-base superalloy IN718. Further studies on bicrystal and thermomechanically processed specimens of IN718 have shown that this kind of brittle fracture, which has been termed "dynamic embrittlement", depends strongly on the structure of the grain boundaries.

Acetone and Water on TiO(110): H/D Exchange

International Nuclear Information System (INIS)

Henderson, Michael A.

2005-01-01

Isotopic H/D exchange between coadsorbed acetone and water on the TiO(110) surface was examined using temperature programmed desorption (TPD) as a function of coverage and two surface pretreatments (oxidation and reduction). Coadsorbed acetone and water interact repulsively on reduced TiO(110) based on results from the companion paper to this study, with water exerting a greater influence in destabilizing acetone and acetone having only a nominal influence on water. Despite the repulsive interaction between these coadsorbates, about 0.02 ML of a 1 ML d6-acetone on the reduced surface exhibits H/D exchange with coadsorbed water, with the exchange occurring exclusively in the high temperature region of the d?-acetone TPD spectrum at ∼340 K. The effect was confirmed with combinations of d?-acetone and D?O. The extent of exchange decreased on the reduced surface with water coverages above ∼0.3 ML due to the ability of water to displace coadsorbed acetone from first layer sites to the multilayer. In contrast, the extent of exchange increased by a factor of 3 when the surface was pre-oxidized prior to coadsorption. In this case, there was no evidence for the negative influence of high water coverages on the extent of H/D exchange. Comparison of the TPD spectra from the exchange products (either d?- or d?-acetone depending on the coadsorption pairing) suggests that, in addition to the 340 K exchange process seen on the reduced surface, a second exchange process was observed on the oxidized surface at ∼390 K. In both cases (oxidized and reduced), desorption of the H/D exchange products appeared to be reaction limited and to involve the influence of OH/OD groups (or water formed during recombinative desorption of OH/OD groups) instead of molecularly adsorbed water. The 340 K exchange process is assigned to reaction at step sites and the 390 K exchange process is attributed to the influence of oxygen adatoms deposited during surface oxidation. The H/D exchange

Protection of type 316 austenitic stainless steel from intergranular stress corrosion cracking by thermo-mechanical treatment

International Nuclear Information System (INIS)

Kiuchi, Kiyoshi; Tsuji, Hirokazu; Kondo, Tatsuo

1980-03-01

Thermomechanical treatment that causes carbide stabilizing aging of cold worked material followed by recrystallization heating made standard stainless steels highly resistant to intergranular corrosion and stress corrosion cracking in different test environments. After a typical thermal history of simulated welding, several IGSCC susceptibility tests were made. The results showed that the treatment was successful in type 316 steel in wide range of conditions, while type 304 was protected only to a small extent even by closely controlled treatment. Response of the materials to the sensitizing heating in terms of impurity segregation at grain boundaries was also examined by means of microchemical analysis. Advantage of method is that no special care is required in selecting heats of material, so that conventional type 316 is usable by improving the mechanical properties substantially through the treatment. In some optimized cases the mechanical property improvement was typically recognized by the yield strength by about 20% higher at room temperature, compared with the material mill annealed. (author)

Performance demonstration testing at the EPRI NDE center for intergranular stress corrosion cracking in BWR piping

International Nuclear Information System (INIS)

Pherigo, G.

1986-01-01

Intergranular stress corrosion cracking (IGSCC) has become a significant concern for the commercial electric utility industry during the past four years. As the IGSCC problem manifested itself, the Nuclear Regulatory Commission (NRC) responded by issuing Inspection and Enforcement (I and E) Bulletin 82-03 which required that ultrasonic inspection procedures be demonstrated on service- removed samples. The ability to reliably detect and discriminate IGSCC was recognized by the industry as a very difficult task, at best. Concurrent with the NRC bulletin, state-of-the-art yet practical techniques for the detection and discrimination of IGSCC had to be developed, demonstrated, and transferred to the field in a relatively short time. With the release of I and E Bulletin 83-02, procedures as well as personnel had to be qualified on service-removed samples. This paper reports how the EPRI Nondestructive Evaluation (NDE) Center developed the necessary technology and a formal training and qualification program to meet these needs on behalf of the industry

Evaluation by the Double Loop Electrochemical Potentiokinetic Reactivation Test of Aged Ferritic Stainless Steel Intergranular Corrosion Susceptibility

Science.gov (United States)

Sidhom, H.; Amadou, T.; Braham, C.

2010-12-01

An experimental design method was used to determine the effect of factors that significantly affect the response of the double loop-electrochemical potentiokinetic reactivation (DL-EPR) test in controlling the susceptibility to intergranular corrosion (IGC) of UNS S43000 (AISI 430) ferritic stainless steel. The test response is expressed in terms of the reactivation/activation current ratio ( I r / I a pct). Test results analysed by the analysis of variance (ANOVA) method show that the molarity of the H2SO4 electrolyte and the potential scanning rate have a more significant effect on the DL-EPR test response than the temperature and the depassivator agent concentration. On the basis of these results, a study was conducted in order to determine the optimal operating conditions of the test as a nondestructive technique for evaluating IGC resistance of ferritic stainless steel components. Three different heat treatments are considered in this study: solution annealing (nonsensitized), aging during 3 hours at 773 K (500 °C) (slightly sensitized), and aging during 2 hours at 873 K (600 °C) (highly sensitized). The aim is to find the operating conditions that simultaneously ensure the selectivity of the attack (intergranular and chromium depleted zone) and are able to detect the effect of low dechromization. It is found that a potential scanning rate of 2.5 mV/s in an electrolyte composed of H2SO4 3 M solution without depassivator, at a temperature around 293 K (20 °C), is the optimal operating condition for the DL-EPR test. Using this condition, it is possible to assess the degree of sensitization (DOS) to the IGC of products manufactured in ferritic stainless steels rapidly, reliably, and quantitatively. A time-temperature-start of sensitization (TTS) diagram for the UNS S43000 (France Inox, Villepinte, France) stainless steel was obtained with acceptable accuracy by this method when the IGC sensitization criterion was set to I r / I a > 1 pct. This diagram is in

Status report: Intergranular stress corrosion cracking of BWR core shrouds and other internal components

International Nuclear Information System (INIS)

1996-03-01

On July 25, 1994, the US Nuclear Regulatory Commission (NRC) issued Generic Letter (GL) 94-03 to obtain information needed to assess compliance with regulatory requirements regarding the structural integrity of core shrouds in domestic boiling water reactors (BWRs). This report begins with a brief description of the safety significance of intergranular stress corrosion cracking (IGSCC) as it relates to the design and function of BWR core shrouds and other internal components. It then presents a brief history of shroud cracking events both in the US and abroad, followed by an indepth summary of the industry actions to address the issue of IGSCC in BWR core shrouds and other internal components. This report summarizes the staff's basis for issuing GL 94-03, as well as the staff's assessment of plant-specific responses to GL 94-03. The staff is continually evaluating the licensee inspection programs and the results from examinations of BWR core shrouds and other internal components. This report is representative of submittals to and evaluations by the staff as of September 30, 1995. An update of this report will be issued at a later date

Performance of Helical Coil Heat Recovery Exchanger using Nanofluid as Coolant

Directory of Open Access Journals (Sweden)

Navid Bozorgan

2015-07-01

Full Text Available Nanofluids are expected to be a promising coolant condidate in chemical processes for heat transfer system size reduction. This paper focuses on reducing the number of turns in a helical coil heat recovery exchanger with a given heat exchange capacity in a biomass heating plant using γ-Al2O3/n-decane nanofluid as coolant. The nanofluid flows through the tubes and the hot n-hexane flows through the shell. The numerical results show that using nanofluid as coolant in a helical coil heat exchanger can reduce the manufacturing cost of the heat exchanger and pumping power by reducing the number of turns of the coil.

Approach to mitigate intergranular stress corrosion cracking and dose rate reduction rate by water chemistry control in Tokai-2

International Nuclear Information System (INIS)

Hisamune, Kenji

2015-01-01

The Japan Atomic Power Company (JAPC) had been working on material replacement and measures to mitigate stress in order to maintain the integrity of the structural material of Tokai-Daini nuclear power plant (Tokai-2, BWR, 1,100 MWe; commercial operation started on November 28, 1978). In addition, as Stress Corrosion Cracking (SCC) environmental mitigation measures, we have been reducing the sulfate ion concentration in the reactor water by improving the regeneration method of the ion exchange resin at condensate purification system. Furthermore, in conducting the SCC environmental mitigation measures by applying hydrogen water chemistry (HWC) and HWC during start-up (HDS), we have been reducing the oxidizing agent concentration in the reactor water. On the other hand, as a plant that has not installed condensate filters, we have been working on feed water iron concentration reduction measures in Tokai-2 as part of the dose reduction measures. Therefore, we have improved condensate demineralizer's ion exchange resin and the ion exchange resin cleaning method using the ARCS (Advanced Resin Cleaning System) in order to improve the iron removal performance of condensate demineralizer. This document reports the improvement effect of the SCC environmental mitigation measures and the dose reduction measures by water chemistry management at Tokai-2. In addition, the dose reduction effect of the recently applied zinc injection, and the Electrochemical Corrosion Potential (ECP) monitoring plan under the On-Line Noble Chemical Addition (OLNC™) to be implemented later shall be introduced. (author)

Fibrinogen Reduction During Selective Plasma Exchange due to Membrane Fouling.

Science.gov (United States)

Ohkubo, Atsushi; Okado, Tomokazu; Miyamoto, Satoko; Hashimoto, Yurie; Komori, Shigeto; Yamamoto, Motoki; Maeda, Takuma; Itagaki, Ayako; Yamamoto, Hiroko; Seshima, Hiroshi; Kurashima, Naoki; Iimori, Soichiro; Naito, Shotaro; Sohara, Eisei; Uchida, Shinichi; Rai, Tatemitsu

2017-06-01

Fibrinogen is substantially reduced by most plasmapheresis modalities but retained in selective plasma exchange using Evacure EC-4A10 (EC-4A). Although EC-4A's fibrinogen sieving coefficient is 0, a session of selective plasma exchange reduced fibrinogen by approximately 19%. Here, we investigated sieving coefficient in five patients. When the mean processed plasma volume was 1.15 × plasma volume, the mean reduction of fibrinogen during selective plasma exchange was approximately 15%. Fibrinogen sieving coefficient was 0 when the processed plasma volume was 1.0 L, increasing to 0.07 when the processed plasma volume was 3.0 L, with a mean of 0.03 during selective plasma exchange. When fibrinogen sieving coefficient was 0, selective plasma exchange reduced fibrinogen by approximately 10%. Scanning electron microscopy images revealed internal fouling of EC-4A's hollow fiber membrane by substances such as fibrinogen fibrils. Thus, fibrinogen reduction by selective plasma exchange may be predominantly caused by membrane fouling rather than filtration. © 2017 International Society for Apheresis, Japanese Society for Apheresis, and Japanese Society for Dialysis Therapy.

Mitigation strategies of intergranular corrosion in systems of reactors of water boiling (BWR). Combined action of the chemistry of the hydrogen and the oxygen; Estrategias de mitigacion de la corrosion intergranular en sistemas de reactores de agua en ebullicion (BWR). Accion combinada de la quimica del hidrogeno y del oxigeno

Energy Technology Data Exchange (ETDEWEB)

Verdugo, M.

2015-07-01

Inter-Granular Stress Corrosion cracking (IGSCC) in austenitic stainless steel and in austenitic nickel-based alloys has been the subject of many studies the aim of which was to resolve one of the main problems faced by BWR nuclear power plants since the 1960s. This corrosion phenomenon is the result of the combined action of three factors: sensitization of the material, high local stresses and an aggressive medium. This paper deals with these factors separately and analyzes the oxidative chemistry of BWR reactors (aggressivity of the medium) as one the main causes if IGSCC. (Author)

Intergranular brittle fracture of a low alloy steel induced by grain boundary segregation of impurities: influence of the microstructure; Rupture intergranulaire fragile d'un acier faiblement allie induite par la segregation d'impuretes aux joints de grains: influence de la microstructure

Energy Technology Data Exchange (ETDEWEB)

Raoul, St

1999-07-01

The study contributes to improve the comprehension of intergranular embrittlement induced by the phosphorus segregation along prior austenitic grain boundaries of low alloy steels used in pressurized power reactor vessel. A part of this study was performed using a A533 steel which contains chemical fluctuations (ghost lines) with two intensities. Axi-symmetrically notched specimens were tested and intergranular brittle de-cohesions were observed in the ghost lines. The fracture initiation sites observed on fracture surfaces were identified as MnS inclusions. A bimodal statistic obtained in a probabilistic model of the fracture is explained by the double population of ghost lines' intensities. A metallurgical study was performed on the same class of steel by studying the influence of the microstructure on the susceptibility to temper embrittlement. Brittle fracture properties of such microstructures obtained by dilatometric experiments were tested on sub-sized specimens to measure the V-notched fracture toughness. Fraction areas of brittle fracture modes were determined on surface fractures. A transition of the fracture mode with the microstructure is observed. It is shown that tempered microstructures of martensite and lower bainite are more susceptible to intergranular embrittlement than tempered upper bainitic microstructure. The intergranular fracture is the most brittle mode. The analysis of crystalline mis-orientations shows a grain boundary structure appreciably more coherent for tempered microstructures of martensite and lower bainite. The higher density of randomgrain boundaries is susceptible to drag the phosphorus in the upper bainitic matrix and to make the quantity of free phosphorus decreasing. Microstructure observations show a difference in the size and the spatial distribution of carbides, essentially cementite, between tempered martensite and upper bainite. It can explain the bigger susceptibility of this last microstructure to cleavage mode

Mechanistic study on exchange between labeled cyanide and nitriles

International Nuclear Information System (INIS)

Hussain, Munir; Chaney, J.E.; Digenis, G.A.; Layton, W.J.

1985-01-01

The potential of a clean, rapid exchange between the nitrile function of mandelonitrile and cyanide was examined for the preparation of labeled mandelonitrile which could be subsequently rapidly reduced with borane to labeled phenylethanolamine (PEOH). The mandelonitrile exchange (CN-CN) was studied using [ 13 C]-NaCN with crown ethers in THF, monitoring the results with 13 C-NMR. A large increase in the intensity of the signal due to [ 13 C]-nitrile was observed. The exchange was also carried out using [ 14 C]-NaCN, and the exchanged nitrile was reduced to [ 14 C]-PEOH. The chemical yield for the reduction of [ 14 C]-mandelonitrile to [ 14 C]-PEOH was 60% and the overall radio-chemical yield of the cyanide-exchange and borane reduction (based on [ 14 C]-NaCN used) was 20%. Mechanisms are proposed which were found to be consistent with results of cyanide exchange of appropriately selected nitriles. (author)

Intergranular corrosion following friction stir welding of aluminum alloy 7075-T651

Energy Technology Data Exchange (ETDEWEB)

Lumsden, J.B.; Mahoney, M.W.; Pollock, G.; Rhodes, C.G.

1999-12-01

Friction stir welding (FSW), a relatively new solid-state joining process, is used to join Al alloys of all compositions, including alloys essentially considered unweldable. This study focused on microstructures in FSW Al alloy 7075-T651 (AA 7075-T651 [UNS 97075-T651]), an alloy not commonly fusion welded, and the resultant corrosion susceptibility. Although the heat input associated with FSW was relatively low and the time at temperature was short compared to fusion welding, localized microstructures, chemical segregation, and precipitate distributions were created that generally are not present in parent metal AA 7075-T651. Typically, in the weld and heat affected zone (HAZ), the times at peak temperature were short, cooling was relatively rapid, and peak temperatures were {lt} {approx}500 C. Accordingly, a corresponding microstructural gradient developed from the weld nugget into the unaffected parent metal with the precipitate distribution in and around grain boundaries reflecting this temperature excursion. Some of these microstructures, when exposed to a corrosive environment, showed selective grain boundary attack and a decrease in the pitting potential relative to the parent metal. A characterization of the microstructure and localized chemistry differences within the weld zones suggested that the decrease in corrosion resistance correlated with a depletion of Cu within the grain boundaries and precipitate-free zones. These results provided evidence that the lowered resistance to intergranular corrosion following FSW of AA 7075-T651 was caused by a difference in pitting potentials.

Chemical uranium enrichment with ion exchanger

International Nuclear Information System (INIS)

Takeda, Kunihiko; Onitsuka, Hatsuki; Obanawa, Heiichiro

1991-01-01

The uranium enrichment by using ion-exchange has been studied and developed since 1972. The ion-exchange rate has been improved approx. 3000 times and the electron exchange reaction, which occurs with ion-exchange reaction, was also accelerated with catalyst. Flow disturbance in a ion-exchange column has been fully studied and the value of turbulence has been reduced to 150μm. These results allowed us to design a very fine separation column, in which about 10000 stages can be obtained even when the column is more than 1 m in diameter. In the course of the development, a self-regenerating reaction between the redox agents was discovered and incorporated into the process, and has resulted in a reduction of 70 % in the separation energy requirement. (author)

Analysis of proton exchange membrane fuel cell polarization losses at elevated temperature 120 C and reduced relative humidity

Energy Technology Data Exchange (ETDEWEB)

Xu, Hui; Kunz, H. Russell [Department of Chemical Engineering, University of Connecticut, Storrs, CT (United States); Fenton, James M. [Florida Solar Energy Center, University of Central Florida, Cocoa, FL (United States)

2007-03-01

Polarization losses of proton exchange membrane (PEM) fuel cells at 120 C and reduced relative humidity (RH) were analyzed. Reduced RH affects membrane and electrode ionic resistance, catalytic activity and oxygen transport. For a cell made of Nafion {sup registered} 112 membrane and electrodes that have 35 wt.% Nafion {sup registered} and 0.3 mg/cm{sup 2} platinum supported on carbon, membrane resistance at 20%RH was 0.407 {omega} cm{sup 2} and electrode resistance 0.203 {omega} cm{sup 2}, significantly higher than 0.092 and 0.041 {omega} cm{sup 2} at 100%RH, respectively. In the kinetically controlled region, 20%RH resulted in 96 mV more cathode activation loss than 100%RH. Compared to 100%, 20%RH also produced significant oxygen transport loss across the ionomer film in the electrode, 105 mV at 600 mA/cm{sup 2}. The significant increase in polarization losses at elevated temperature and reduced RH indicates the extreme importance of designing electrodes for high temperature PEM fuel cells since membrane development has always taken most emphasis. (author)

Exchange of deuterium with hydrogen of zeolite catalyst surface

International Nuclear Information System (INIS)

Minachev, Kh.M.; Dmitriev, R.V.; Penchev, V.; Kanazirev, V.; Minchev, Kh.; Kasimov, Ch.K.; Bylgarska Akademiya na Naukite, Sofia. Inst. za Obshta i Organichna Khimiya; AN Azerbajdzhanskoj SSR, Baku. Inst. Neftekhimicheskikh Protsessov)

1981-01-01

Isotope heteromolecular exchange of hydrogen on the reduced nickel-containing zeolites takes places at the temperatures above 100 deg and it is controlled by activated hydrogen transfer from metal particles on the substrate surface. High-temperature redox treatment of nickel-containing zeolites results in the formation of large nickel crystallites on zeolite external faces. The rest part of nickel remains in zeolite pores and conditions a high promoting effect in the exchange reaction. Catalytic activity of reduced zeolites NiCaNaY in toluene disproportionation increases considerably only in the cases when nickel is introduced into zeolite by means of ion exchange. Close spatial location of nickel particles and OH groups promotes the procedure of both isotope exchange and disproportionation of toluene [ru

Hibernation and gas exchange.

Science.gov (United States)

Milsom, William K; Jackson, Donald C

2011-01-01

Hibernation in endotherms and ectotherms is characterized by an energy-conserving metabolic depression due to low body temperatures and poorly understood temperature-independent mechanisms. Rates of gas exchange are correspondly reduced. In hibernating mammals, ventilation falls even more than metabolic rate leading to a relative respiratory acidosis that may contribute to metabolic depression. Breathing in some mammals becomes episodic and in some small mammals significant apneic gas exchange may occur by passive diffusion via airways or skin. In ectothermic vertebrates, extrapulmonary gas exchange predominates and in reptiles and amphibians hibernating underwater accounts for all gas exchange. In aerated water diffusive exchange permits amphibians and many species of turtles to remain fully aerobic, but hypoxic conditions can challenge many of these animals. Oxygen uptake into blood in both endotherms and ectotherms is enhanced by increased affinity of hemoglobin for O₂ at low temperature. Regulation of gas exchange in hibernating mammals is predominately linked to CO₂/pH, and in episodic breathers, control is principally directed at the duration of the apneic period. Control in submerged hibernating ectotherms is poorly understood, although skin-diffusing capacity may increase under hypoxic conditions. In aerated water blood pH of frogs and turtles either adheres to alphastat regulation (pH ∼8.0) or may even exhibit respiratory alkalosis. Arousal in hibernating mammals leads to restoration of euthermic temperature, metabolic rate, and gas exchange and occurs periodically even as ambient temperatures remain low, whereas body temperature, metabolic rate, and gas exchange of hibernating ectotherms are tightly linked to ambient temperature. © 2011 American Physiological Society.

Simulation of the high temperature intergranular strain hardening in fatigue of materials with hold time; Modelisation de l'ecrouissage intragranulaire en fatigue des metaux a haute temperature avec temps de maintien

Energy Technology Data Exchange (ETDEWEB)

Sauzay, M.; Mottot, M.; Noblecourt, M.; Allais, L.; Monnet, I.; Perinet, J

2003-07-01

This paper aims to simulate the behavior of some alloys in high temperature fatigue-relaxation (creep), for a long hold time (one month for each cycle) when laboratory experiments are difficult to realize. The first part presents an estimation of the internal intergranular stresses. The second part deals with the recovery occurring during the hold time. (A.L.B.)

Exchange rate regimes and inflation: Evidence from India.

OpenAIRE

Mohanty, Biswajit; Bhanumurthy, N.R.

2014-01-01

Exchange rate stability is crucial for inflation management as a stable rate is expected to reduce domestic inflation pressures through a `policy discipline effect'- restricting money supply growth, and a `credibility effect'- inducing higher money demand and reduced velocity of money. Alternatively, the impossibility trillema predicts that in the presence of an open capital account, a stable exchange rate may lead to lack of control on monetary policy and, hence, higher inflation. Using a mo...

Reducing elution in anion exchange chromatography as a pretreatment of colorimetry of chromium(VI) and vanadium(V)

International Nuclear Information System (INIS)

Shigetomi, Yasumasa; Hatamoto, Takeji; Nagoshi, Kimie; Yamashige, Takashi.

1976-01-01

In order to increase the selectivity of the colorimetry of chromium and vanadium, the separation by means of anion exchange chromatography was tested. The column, phi 0.8x5.0 cm packing (50--100 mesh) Dowex 1x4 anion exchange resin was used for the separation of chromium. The solution containing chromium (VI), zinc(II), cadmium(II), iron(III) and reducing organic substances contained in industrial waste water was introduced into the column and then the substances other than chromium(VI) were removed by washing the column with distilled water. Finally chromium(VI) was reduced to chromium(III) by hydroxylamine in the eluent and eluted. The concentration of sulfuric acid and hydroxylamine in the eluent were 0.1 mol/l and 0.001 mol/l respectively. For analyzing chromium(III) in the mixture of chromium(VI) and chromium(III), after removal of chromium(VI) it should be oxidized to chromium(VI) anion with the oxidant, e.g., sodium peroxide or hydrogen peroxide, before introducing it into the column. In terms of the pretreatment by using the acetate form resin column, chromium (VI) and chromium(III) can be determined separately in the solution whose concentration ranges from 0.05 ppm to 0.5 ppm despite the presence of contaminants, which interfere with the colorimetric determination of chromium(VI) using diphenylcarbonohydrazide, in the original solution. The separation of vanadium(V) in the solution containing copper(II), cobalt(II) and etc. was made using the mixed solution of hydrochloric acid (2 mol/l) and hydroxylamine (0.2 mol/l) similarly to chromium(VI). In terms of the similar pretreatment vanadium could be determined precisely as far as 0.1 ppm by the colorimetry using 4-(2-pyridylazo) resorcinol despite the presence of copper(II), cobalt(II), nickel(II) and etc in the original solution. (auth.)

Operation control device for a nuclear reactor fuel exchanger

International Nuclear Information System (INIS)

Aida, Takashi.

1984-01-01

Purpose: To provide a operation control device for a nuclear reactor fuel exchanger with reduced size and weight capable of optionally meeting the complicated and versatile mode of the operation scope. Constitution: The operation range of a fuel exchanger is finely divided so as to attain the state capable of discriminating between operation-allowable range and operation-inhibitive range, which are stored in a memory circuit. Upon operating the fuel exchanger, the position is detected and a divided range data corresponding to the present position is taken out from the memory circuit so as to determine whether the fuel exchanger is to be run or stopped. Use of reduced size and compact IC circuits (calculation circuit, memory circuit, data latch circuit) and input/output interface circuits or the likes contributes to the size reduction of the exchanger control system to enlarge the floor maintenance space. (Moriyama, K.)

Influence of competition between intragranular dislocation nucleation and intergranular slip transfer on mechanical properties of ultrafine-grained metals

International Nuclear Information System (INIS)

Tsuru, Tomohito; Kaji, Yoshiyuki; Aoyagi, Yoshiteru; Shimokawa, Tomotsugu

2013-01-01

Huge-scale atomistic simulations of shear deformation tests to the aluminum polycrystalline thin film containing the Frank-Read source are performed to elucidate the relationship between the inter- and intragranular plastic deformation processes and the mechanical properties of ultrafine-grained metals. Two-types of polycrystalline models, which consist of several grain boundaries reproducing easy and hard slip transfer, respectively, are prepared to investigate the effect of grain boundary on flow stress. While the first plastic deformation occurs by the dislocation bow-out motion within the grain region for both models, the subsequent plastic deformation is strongly influenced by the resistance of the slip transfer by dislocation transmission through grain boundaries. The influence of the competition between the intragranular dislocation nucleation and intergranular slip transfer on the material strength is considered. The nanostructured material's strength depending on local defect structures associated with grain size and dislocation source length is assessed quantitatively. (author)

Evaluation of intergranular cracks on the ring header cross at Grand Gulf Unit No. 1

International Nuclear Information System (INIS)

Czajkowski, C.J.

1987-01-01

A metallurgical investigation was performed on a sample of cracked ring header cross material from the Grand Gulf Unit No. 1 Nuclear Power Station. The cracks were located in a 6-7 in (15-17.5 cm) width band running circumferentially below the cross to cap weld with a similar band above the cross to discharger pipe weld. The indications were up to 19 mm in length and 6.0 mm in depth. This particular sample was cut from a cross which had not seen actual service but which had been used to qualify the induction heating stress improvement (IHSI) technique for the Grand Gulf units. The base material was SA 182 material manufactured to SA 403-type WP 304 stainless steel. The investigation consisted of visual/dye penetrant examination, chemical analysis, hardness testing, optical microscopy, scanning electron microscopy and energy dispersive spectroscopy. The evaluated cracks were intergranular and initiated on the forging's exterior surface. The grain size of the material was larger than ASTM 00 and no definitive corrosive species were found by Energy Dispersive Spectroscopy (EDS). The cracking is considered to be the result of the forging having been overheated/burned during manufacture. (author)

Heat exchanger network retrofit optimization involving heat transfer enhancement

International Nuclear Information System (INIS)

Wang Yufei; Smith, Robin; Kim, Jin-Kuk

2012-01-01

Heat exchanger network retrofit plays an important role in energy saving in process industry. Many design methods for the retrofit of heat exchanger networks have been proposed during the last three decades. Conventional retrofit methods rely heavily on topology modifications which often result in a long retrofit duration and high initial costs. Moreover, the addition of extra surface area to the heat exchanger can prove difficult due to topology, safety and downtime constraints. Both of these problems can be avoided through the use of heat transfer enhancement in heat exchanger network retrofit. This paper presents a novel design approach to solve heat exchanger network retrofit problems based on heat transfer enhancement. An optimisation method based on simulated annealing has been developed to find the appropriate heat exchangers to be enhanced and to calculate the level of enhancement required. The physical insight of enhanced exchangers is also analysed. The new methodology allows several possible retrofit strategies using different retrofit methods be determined. Comparison of these retrofit strategies demonstrates that retrofit modification duration and payback time are reduced when heat transfer enhancement is utilised. Heat transfer enhancement can be also used as a substitute for increased heat exchanger network surface area to reduce retrofit investment costs.

Effect of thickness and composition on the structure and ordering in La-doped intergranular films between Si{sub 3}N{sub 4} crystals

Energy Technology Data Exchange (ETDEWEB)

Jiang Yun [Interfacial Molecular Science Laboratory, Department of Materials Science and Engineering, Rutgers University, 607 Taylor Rd., Piscataway, NJ 08855 (United States); Garofalini, Stephen H., E-mail: shg@rutgers.edu [Interfacial Molecular Science Laboratory, Department of Materials Science and Engineering, Rutgers University, 607 Taylor Rd., Piscataway, NJ 08855 (United States)

2011-08-15

Molecular dynamics simulations were used to determine the effect of the composition and thickness on the atomistic structure of La-Si-O-N intergranular films (IGFs) between prism and misaligned high-index silicon nitride crystals. Results showed that ordered La adsorption onto the prism-terminated surface is not affected by the orientation of the opposing crystal, although the extent of the ordering away from the interface is affected by IGF thickness. La adsorption at ordered sites 1 and 2 on the prism surface occurred for almost all of the compositions in both 1.8 and 0.6 nm thick IGFs and at sites farther from the prism interface in the thicker IGF, similar to adsorption in triple points. La adsorption on the prism surface occurred at sites precisely the same as seen in high-angle annular dark field scanning transmission electron microscopy studies. Saturation of available sites is affected by the thickness of the IGF, which governs the number of La ions (and N ions) in the IGF, with lower site filling in the thinner IGF. There are clear energy differences for La in the interior of the IGF vs. the interface based on composition and IGF thickness, with the thicker IGF showing greater variation in driving forces for segregation or La incorporation into the IGF. Fracture is affected by both composition and thickness and occurs in the glassy IGF and not in the ordered interfacial regions, consistent with experimentally observed intergranular fracture for La-doped silicon nitride. Segregation of La to the interface affects N distribution within the interior of the IGF, which affects strength.

Heat exchanger. [Nuclear power plants

Energy Technology Data Exchange (ETDEWEB)

Molina, C; Brisseaux, A

1976-01-19

This invention concerns a heat exchanger between a fluid flowing through a tube and a gas. Such an exchanger can be used, inter alia, for removing calories that cannot be used for generating electricity in a thermal or nuclear power station. This exchanger can withstand any pressure surges in the system and even the use of a high vapour pressure coolant such as ammonia, since the fluid flows in a round tube with low pressure drops (both with respect to the fluid to be cooled and the cooling air). It is rigid enough to stand up to being moved and handled as well as to gusts of wind. It is formed of units that can be handled without difficulty and that are easily dismantable and interchangeable, even in service, and it is easily maintained. The exchange area is high for a minimum frontal area and this enables the size of the supporting frame to be reduced and makes it easy to hide it behind a screen of trees should this prove necessary. Finally, it is composed of a small number of standard units thus reducing the industrial production cost. These units are rectangular plates, each one being a flat tubular coil fitted between two flat parallel sheet metal plates having on their outer sides flat top raised bosses. These units are assembled together by the tops of the bosses so as to form an exchanger bank, each bank comprising two collectors to which the bank coils are tightly connected.

Reduced-Dimensionality Semiclassical Transition State Theory: Application to Hydrogen Atom Abstraction and Exchange Reactions of Hydrocarbons.

Science.gov (United States)

Greene, Samuel M; Shan, Xiao; Clary, David C

2015-12-17

Quantum mechanical methods for calculating rate constants are often intractable for reactions involving many atoms. Semiclassical transition state theory (SCTST) offers computational advantages over these methods but nonetheless scales exponentially with the number of degrees of freedom (DOFs) of the system. Here we present a method with more favorable scaling, reduced-dimensionality SCTST (RD SCTST), that treats only a subset of DOFs of the system explicitly. We apply it to three H abstraction and exchange reactions for which two-dimensional potential energy surfaces (PESs) have previously been constructed and evaluated using RD quantum scattering calculations. We differentiated these PESs to calculate harmonic frequencies and anharmonic constants, which were then used to calculate cumulative reaction probabilities and rate constants by RD SCTST. This method yielded rate constants in good agreement with quantum scattering results. Notably, it performed well for a heavy-light-heavy reaction, even though it does not explicitly account for corner-cutting effects. Recent extensions to SCTST that improve its treatment of deep tunneling were also evaluated within the reduced-dimensionality framework. The success of RD SCTST in this study suggests its potential applicability to larger systems.

Effect of creep and oxidation on reduced fatigue life of Ni-based alloy 617 at 850 °C

Energy Technology Data Exchange (ETDEWEB)

Chen, Xiang, E-mail: chenx@ornl.gov [Department of Nuclear, Plasma, and Radiological Engineering, University of Illinois at Urbana-Champaign, 104 South Wright Street, Urbana, IL 61801 (United States); Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, TN 37831 (United States); Yang, Zhiqing [Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, TN 37831 (United States); Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Sokolov, Mikhail A.; Erdman, Donald L. [Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, TN 37831 (United States); Mo, Kun; Stubbins, James F. [Department of Nuclear, Plasma, and Radiological Engineering, University of Illinois at Urbana-Champaign, 104 South Wright Street, Urbana, IL 61801 (United States)

2014-01-15

Low cycle fatigue (LCF) and creep–fatigue testing of Ni-based alloy 617 was carried out at 850 °C. Compared with its LCF life, the material’s creep–fatigue life decreases to different extents depending on test conditions. To elucidate the microstructure-fatigue property relationship for alloy 617 and the effect of creep and oxidation on its fatigue life, systematic microstructural investigations were carried out using scanning electron microscopy, energy-dispersive X-ray spectroscopy, and electron backscatter diffraction (EBSD). In LCF tests, as the total strain range increased, deformations concentrated near high angle grain boundaries (HAGBs). The strain hold period in the creep–fatigue tests introduced additional creep damage to the material, which revealed the detrimental effect of the strain hold time on the material fatigue life in two ways. First, the strain hold time enhanced the localized deformation near HAGBs, resulting in the promotion of intergranular cracking of alloy 617. Second, the strain hold time encouraged grain boundary sliding, which resulted in interior intergranular cracking of the material. Oxidation accelerated the initiation of intergranular cracking in alloy 617. In the crack propagation stage, if oxidation was promoted and the cyclic oxidation damage was greater than the fatigue damage, oxidation-assisted intergranular crack growth resulted in a significant reduction in the material’s fatigue life.

Method of pyrolysis for spent ion-exchange resins

International Nuclear Information System (INIS)

Aoyama, Yoshiyuki; Matsuda, Masami; Kawamura, Fumio; Yusa, Hideo.

1985-01-01

Purpose: To prevent the generation of noxious sulfur oxide and ammonia on the pyrolysis for spent ion-exchange resins discharged from nuclear power plants. Method: In the case where the pyrolysis is made for the cationic exchange resins having sulfonic acids as the ion-exchange group, alkali metals or alkaline earth metals capable of reacting with sulfonic acid groups to form solid sulfates are previously deposited by way of ion-exchange reactions prior to the pyrolysis. In another case of the anionic exchange resins having quarternary ammonium groups as the ion-exchange groups, halogenic elements capable of reacting with the ammonium groups to form solid ammonium salts are deposited to the ion-exchange resins through ion-exchange reactions prior to the pyrolysis. As a result, the amount of the binders used can be reduced, and this method can be used in a relatively simple processing facility. (Horiuchi, T.)

Penetration and characteristics of an intergranular-liquid phase during sintering of CaSi2O5-dropped 8 mol%-yttria-stabilized zirconia estimation by impedance spectroscopy

International Nuclear Information System (INIS)

Jung, Young-Soo; Choi, Jung-Hae; Lee, Jong-Heun

2004-01-01

The grain-boundary resistivity of CaSi 2 O 5 -dropped 8 mol%-yttria-stabilized zirconia (8YSZ) was determined by impedance spectroscopy using sub-millimeter-scale electrodes. During sintering, a liquid that formed at the top surface of the specimen penetrated into the 8YSZ and induced enhanced grain growth near the surface region. The grain-boundary resistivity of the specimen surface was observed to be 150 times higher than that of the interior. The deterioration of the grain-boundary conductivity was explained in terms of the presence of an intergranular siliceous phase

Microscale Regenerative Heat Exchanger

Science.gov (United States)

Moran, Matthew E.; Stelter, Stephan; Stelter, Manfred

2006-01-01

The device described herein is designed primarily for use as a regenerative heat exchanger in a miniature Stirling engine or Stirling-cycle heat pump. A regenerative heat exchanger (sometimes called, simply, a "regenerator" in the Stirling-engine art) is basically a thermal capacitor: Its role in the Stirling cycle is to alternately accept heat from, then deliver heat to, an oscillating flow of a working fluid between compression and expansion volumes, without introducing an excessive pressure drop. These volumes are at different temperatures, and conduction of heat between these volumes is undesirable because it reduces the energy-conversion efficiency of the Stirling cycle.

The Skill-Biased Effects of Exchange Rate Fluctuations

OpenAIRE

Boris Kaiser; Michael Siegenthaler

2015-01-01

This paper examines the linkages between real exchange rate movements and firms' skill demand. Real exchange rate movements may affect unskilled workers differently than skilled workers because of skill-specific adjustment costs, or because exchange rates lead to changes in relative factor prices and firms' competition intensity. Using panel data on Swiss manufacturers, we find that an appreciation increases high-skilled and reduces low-skilled employment in most firms, while total employment...

Intergranular corrosion testing of austenitic stainless steels in nitric acid solutions

Energy Technology Data Exchange (ETDEWEB)

Whillock, G.O.H.; Dunnett, B. F. [British Nuclear Fuels plc, BNFL, B170, Sellafield, Seascale, Cumbria CA20 1PG (United Kingdom)

2004-07-01

In hot strong nitric acid solutions, stainless steels exhibit intergranular corrosion. Corrosion rates are often measured from immersion testing of specimens manufactured from the relevant material (e.g. plate or pipe). The corrosion rates, measured from weight loss, are found to increase with time prior to reaching steady state, which can take thousands of hours to achieve. The apparent increase in corrosion rate as a function of time was found to be an artefact due to the surface area of the specimen's being used in the corrosion rate calculations, rather than that of the true area undergoing active corrosion i.e. the grain boundaries. The steady state corrosion rate coincided with the onset of stable grain dropping, where the use of the surface area of the specimen to convert the weight loss measurements to corrosion rates was found to be appropriate. This was confirmed by sectioning of the specimens and measuring the penetration depths. The rate of penetration was found to be independent of time and no induction period was observed. A method was developed to shorten considerably the testing time to reach the steady state corrosion rate by use of a pre-treatment that induces grain dropping. The long-term corrosion rates from specimens which were pre-treated was similar to that achieved after prolonged testing of untreated (i.e. initially ground) specimens. The presence of cut surfaces is generally unavoidable in the simple immersion testing of specimens in test solutions. However, inaccuracy in the results may occur as the measured corrosion rate is often influenced by the orientation of the microstructure, the highest rates typically being observed on the cut surfaces. Two methods are presented which allow deconvolution of the corrosion rates from immersion testing of specimens containing cut surfaces, thus allowing reliable prediction of the long-term corrosion rate of plate surfaces. (authors)

The fate of benzotriazole pollutants in an urban oxic intergranular aquifer.

Science.gov (United States)

Trček, Branka; Žigon, Dušan; Zidar, Vlasta Kramarič; Auersperger, Primož

2017-12-26

Benzotriazoles (BTs) are considered as Contaminants of Emerging Concern (CECs); however, information about their fate in aquifers continues to be absent. This was the focus of the present study, which provides the first evidence for relevant BTs' degradation products (BTTPs) in urban aquifers that may impact the groundwater quality. The mechanisms and biotransformation pathways of BTs were investigated in an oxic intergranular medium. The BTs and BTTPs were identified and quantified by gas chromatography-mass spectrometry (GC-MS) and liquid chromatography-mass spectrometry (LC-MS) analytical techniques based on reference standards and internal materials. The major transformation products were identified as 2-methyl-2H-benzotriazole (2-MeBT) for the degradation of 1H-benzotriazole (BT) and as 2,4-dimethyl-2H-benzotriazole (2,4-dMeBT) and 1,4-dimethyl-1H-benzotriazole (1,4-dMeBT) for the degradation of 4-methyl-1H-benzotriazole (4-MeBT), and most probably also 5-methyl-1H-benzotriazole (5-MeBT). The leakage of wastewater pipelines is most probably the source of BTs. Sediments with a lower hydraulic conductivity give rise to perched aquifer conditions that lead to the temporal storage of leaking effluents and presumably the majority of BTs' transformation processes via methylation and tautomerization. The most stable BTTPs entered the saturated zone of the aquifer, where they prevailed. Concentrations up to 1500 ng L -1 were measured for the 2,4-dMeBT, which suggest a contamination risk for groundwater that is or may be used as a source for drinking water in the case of a constant input of pollutant loads from sewer systems. Copyright © 2017 Elsevier Ltd. All rights reserved.

Exchange rate volatility and international trade: The option approach

OpenAIRE

Franke, Günter

1986-01-01

Usually it is argued that an increase in exchange rate volatility reduces the volume of international trade since trading firms are risk averse. This paper shows for risk neutral firms that the expected international trade volume in standardized commodities grows with exchange rate volatility. The firms adjust their trade volume to the exchange rate level. The more favorable the exchange rate is, the higher is the export volume. If the rate drops below some level, exports are stopped. Thus in...

Reducing nuclear danger through intergovernmental technical exchanges on nuclear materials safety management

International Nuclear Information System (INIS)

Jardine, L.J.; Peddicord, K.L.; Witmer, F.E.; Krumpe, P.F.; Lazarev, L.; Moshkov, M.

1997-01-01

The United States and Russia are dismantling nuclear weapons and generating hundreds of tons of excess plutonium and high enriched uranium fissile nuclear materials that require disposition. The U.S. Department of Energy and Russian Minatom organizations.are planning and implementing safe, secure storage and disposition operations for these materials in numerous facilities. This provides a new opportunity for technical exchanges between Russian and Western scientists that can establish an improved and sustained common safety culture for handling these materials. An initiative that develops and uses personal relationships and joint projects among Russian and Western participants involved in fissile nuclear materials safety management contributes to improving nuclear materials nonproliferation and to making a safer world. Technical exchanges and workshops are being used to systematically identify opportunities in the nuclear fissile materials facilities to improve and ensure the safety of workers, the public, and the environment

Increased CEST specificity for amide and fast-exchanging amine protons using exchange-dependent relaxation rate.

Science.gov (United States)

Zhang, Xiao-Yong; Wang, Feng; Xu, Junzhong; Gochberg, Daniel F; Gore, John C; Zu, Zhongliang

2018-02-01

Chemical exchange saturation transfer (CEST) imaging of amides at 3.5 ppm and fast-exchanging amines at 3 ppm provides a unique means to enhance the sensitivity of detection of, for example, proteins/peptides and neurotransmitters, respectively, and hence can provide important information on molecular composition. However, despite the high sensitivity relative to conventional magnetic resonance spectroscopy (MRS), in practice, CEST often has relatively poor specificity. For example, CEST signals are typically influenced by several confounding effects, including direct water saturation (DS), semi-solid non-specific magnetization transfer (MT), the influence of water relaxation times (T 1w ) and nearby overlapping CEST signals. Although several editing techniques have been developed to increase the specificity by removing DS, semi-solid MT and T 1w influences, it is still challenging to remove overlapping CEST signals from different exchanging sites. For instance, the amide proton transfer (APT) signal could be contaminated by CEST effects from fast-exchanging amines at 3 ppm and intermediate-exchanging amines at 2 ppm. The current work applies an exchange-dependent relaxation rate (R ex ) to address this problem. Simulations demonstrate that: (1) slowly exchanging amides and fast-exchanging amines have distinct dependences on irradiation powers; and (2) R ex serves as a resonance frequency high-pass filter to selectively reduce CEST signals with resonance frequencies closer to water. These characteristics of R ex provide a means to isolate the APT signal from amines. In addition, previous studies have shown that CEST signals from fast-exchanging amines have no distinct features around their resonance frequencies. However, R ex gives Lorentzian lineshapes centered at their resonance frequencies for fast-exchanging amines and thus can significantly increase the specificity of CEST imaging for amides and fast-exchanging amines. Copyright © 2017 John Wiley & Sons

Cryptographic Combinatorial Securities Exchanges

Science.gov (United States)

Thorpe, Christopher; Parkes, David C.

We present a useful new mechanism that facilitates the atomic exchange of many large baskets of securities in a combinatorial exchange. Cryptography prevents information about the securities in the baskets from being exploited, enhancing trust. Our exchange offers institutions who wish to trade large positions a new alternative to existing methods of block trading: they can reduce transaction costs by taking advantage of other institutions’ available liquidity, while third party liquidity providers guarantee execution—preserving their desired portfolio composition at all times. In our exchange, institutions submit encrypted orders which are crossed, leaving a “remainder”. The exchange proves facts about the portfolio risk of this remainder to third party liquidity providers without revealing the securities in the remainder, the knowledge of which could also be exploited. The third parties learn either (depending on the setting) the portfolio risk parameters of the remainder itself, or how their own portfolio risk would change if they were to incorporate the remainder into a portfolio they submit. In one setting, these third parties submit bids on the commission, and the winner supplies necessary liquidity for the entire exchange to clear. This guaranteed clearing, coupled with external price discovery from the primary markets for the securities, sidesteps difficult combinatorial optimization problems. This latter method of proving how taking on the remainder would change risk parameters of one’s own portfolio, without revealing the remainder’s contents or its own risk parameters, is a useful protocol of independent interest.

Electrically switched cesium ion exchange

International Nuclear Information System (INIS)

Lilga, M.A.; Orth, R.J.; Sukamto, J.P.H.; Schwartz, D.T.; Haight, S.M.; Genders, J.D.

1997-04-01

Electrically Switched Ion Exchange (ESIX) is a separation technology being developed as an alternative to conventional ion exchange for removing radionuclides from high-level waste. The ESIX technology, which combines ion exchange and electrochemistry, is geared toward producing electroactive films that are highly selective, regenerable, and long lasting. During the process, ion uptake and elution are controlled directly by modulating the potential of an ion exchange film that has been electrochemically deposited onto a high surface area electrode. This method adds little sodium to the waste stream and minimizes the secondary wastes associated with traditional ion exchange techniques. Development of the ESIX process is well underway for cesium removal using ferrocyanides as the electroactive films. Films having selectivity for perrhenate (a pertechnetate surrogate) over nitrate also have been deposited and tested. A case study for the KE Basin on the Hanford Site was conducted based on the results of the development testing. Engineering design baseline parameters for film deposition, film regeneration, cesium loading, and cesium elution were used for developing a conceptual system. Order of magnitude cost estimates were developed to compare with conventional ion exchange. This case study demonstrated that KE Basin wastewater could be processed continuously with minimal secondary waste and reduced associated disposal costs, as well as lower capital and labor expenditures

Advanced heat exchanger development for molten salts

Energy Technology Data Exchange (ETDEWEB)

Sabharwall, Piyush, E-mail: Piyush.Sabharwall@inl.gov [Idaho National Laboratory, Idaho Falls, ID 83415 (United States); Clark, Denis; Glazoff, Michael [Idaho National Laboratory, Idaho Falls, ID 83415 (United States); Zheng, Guiqiu; Sridharan, Kumar; Anderson, Mark [University of Wisconsin, Madison (United States)

2014-12-15

Highlights: • Hastelloy N and 242, shows corrosion resistance to molten salt at nominal operating temperatures. • Both diffusion welds and sheet material in Hastelloy N were corrosion tested in at 650, 700, and 850 °C for 200, 500, and 1000 h. • Thermal gradients and galvanic couples in the molten salts enhance corrosion rates. • Corrosion rates found were typically <10 mils per year. - Abstract: This study addresses present work concerned with advanced heat exchanger development for molten salt in nuclear and non-nuclear thermal systems. The molten salt systems discussed herein use alloys, such as Hastelloy N and 242, that show good corrosion resistance in molten salt at nominal operating temperatures up to 700 °C. These alloys were diffusion welded, and the corresponding information is presented. Test specimens were prepared for exposing diffusion welds to molten salt environments. Hastelloy N and 242 were found to be weldable by diffusion welding, with ultimate tensile strengths about 90% of base metal values. Both diffusion welds and sheet material in Hastelloy N were corrosion tested in 58 mol% KF and 42 mol% ZrF{sub 4} at 650, 700, and 850 °C for 200, 500, and 1000 h. Corrosion rates were similar between welded and nonwelded materials, typically <100 μm per year after 1000 h of corrosion tests. No catastrophic corrosion was observed in the diffusion welded regions. For materials of construction, nickel-based alloys and alloys with dense nickel coatings are effectively inert to corrosion in fluorides, but not so in chlorides. Hence, additional testing of selected alloys for resistance to intergranular corrosion is needed, as is a determination of corrosion rate as a function of the type of salt impurity and alloy composition, with respect to chromium and carbon, to better define the best conditions for corrosion resistance. Also presented is the division of the nuclear reactor and high-temperature components per American Society of Mechanical

Effect of Silicon on Intergranular Corrosion Resistance of Ti-stabilized 11 wt% Cr Ferritic Stainless Steels

International Nuclear Information System (INIS)

Hyun, Youngmin; Kim, Heesan

2013-01-01

Ti-stabilized 11 wt% Cr ferritic stainless steels (FSSs) for automotive exhaust systems have been experienced intergranular corrosion (IC) in some heat-affected zone (HAZ). The effects of sensitizing heat-treatment and silicon on IC were studied. Time-Temperature-Sensitization (TTS) curves showed that sensitization to IC was observed at the steels heat-treated at the temperature lower than 650 .deg. C and that silicon improved IC resistance. The sensitization was explained by chromium depletion theory, where chromium is depleted by precipitation of chromium carbide during sensitizing heat-treatment. It was confirmed with the results from the analysis of precipitates as well as the thermodynamical prediction of stable phases. In addition, the role of silicon on IC was explained with the stabilization of grain boundary. In other words, silicon promoted the formation of the grain boundaries with low energy where precipitation was suppressed and consequently, the formation of Cr-depleted zone was retarded. The effect of silicon on the formation of grain boundaries with low energy was proved by the analysis of coincidence site lattice (CSL) grain boundary, which is a typical grain boundary with low energy

Effect of Silicon on Intergranular Corrosion Resistance of Ti-stabilized 11 wt% Cr Ferritic Stainless Steels

Energy Technology Data Exchange (ETDEWEB)

Hyun, Youngmin; Kim, Heesan [Hongik Univ., Sejong (Korea, Republic of)

2013-06-15

Ti-stabilized 11 wt% Cr ferritic stainless steels (FSSs) for automotive exhaust systems have been experienced intergranular corrosion (IC) in some heat-affected zone (HAZ). The effects of sensitizing heat-treatment and silicon on IC were studied. Time-Temperature-Sensitization (TTS) curves showed that sensitization to IC was observed at the steels heat-treated at the temperature lower than 650 .deg. C and that silicon improved IC resistance. The sensitization was explained by chromium depletion theory, where chromium is depleted by precipitation of chromium carbide during sensitizing heat-treatment. It was confirmed with the results from the analysis of precipitates as well as the thermodynamical prediction of stable phases. In addition, the role of silicon on IC was explained with the stabilization of grain boundary. In other words, silicon promoted the formation of the grain boundaries with low energy where precipitation was suppressed and consequently, the formation of Cr-depleted zone was retarded. The effect of silicon on the formation of grain boundaries with low energy was proved by the analysis of coincidence site lattice (CSL) grain boundary, which is a typical grain boundary with low energy.

Intergranular stress corrosion cracking of low alloy and carbon steels in high temperature pure water

International Nuclear Information System (INIS)

Tsubota, M.; Sakamoto, H.; Tsuzuki, R.

1993-01-01

Stress corrosion cracking (SCC) behavior of low alloy steels (A508 and SNCM630) and a carbon steel (SGV480) in high temperature water has been examined with relation to the heat treatment condition, including a long time aging, and the mechanical properties. Intergranular stress corrosion cracking (IGSCC) as observed in the highly hardened specimens, and there was observed in the highly hardened specimens, and there was observed in the highly hardened specimens, and there was observed a close relationship between hardness and SCC susceptibility. From the engineering point of view, it was concluded that adequate SR (stress relief) or tempering heat treatment is necessary to avoid the IGSCC of the welded structures made of low alloy and carbon steels. A508 heat treated with specified quench and temper did not show the SCC susceptibility, even after aging 10000 hours at 350, 400 and 450 degrees C. Tensile properties corresponding to the critical hardness for SSC susceptibility coincided with the values at the 'necking point' in the true stress-strain curve. Ductile-brittle transition observed in the fracture toughness test also occurred at around the critical hardness for SCC susceptibility. Therefore, it was conjectured that the limitation of plasticity was an absolute cause for the SCC susceptibility of the steels

The study on intergranular corrosion of sensitized Alloy 600 using DL-EPR and Huey method

International Nuclear Information System (INIS)

Lee, B. G.; Lee, H. R.; Kim, H. P.; Ryu, W. S.; Rhee, C. K.

1998-01-01

Intergranular corrosion(IGC) of sensitized Alloy 600 has been studied with double loop-electrochemical potentiokinetic reactivation(DL-EPR) and Huey tests. Corrosion of solution annealed Ni-XCr-10Fe(X=6∼15) alloys was also evaluated with DL-EPR and Huey methods to simulate corrosion of Cr-depleted grain boundary region of Alloy 600. Cr concentration of Cr-depleted grain boundary region of Alloy 600. Cr concentration profile across grain boundary was measured with TEM. In the range of the Cr concentration from 6 to 8%, corrosion rates of solution annealed Ni-XCr-10Fe(X=6∼15) alloys were much higher in Huey test than those in DL-EPR. But in the range of the Cr concentration from 12 to 15%, the trend was reversed. The width of IGC crack of Alloy 600 was higher in DL-EPR test than in Huey test in agreement with corrosion of solution annealed Ni-XCr-10Fe alloys. Width of IGC produced by DL-EPR test was almost uniform and wide while that produced by Huey test was sharp and marrow. These results suggest that IGC in DL-EPR test conforms to uniform dissolution model and IGC in Huey test conforms to Cr concentration dependent dissolution model

Evaluating Predictive Uncertainty of Hyporheic Exchange Modelling

Science.gov (United States)

Chow, R.; Bennett, J.; Dugge, J.; Wöhling, T.; Nowak, W.

2017-12-01

Hyporheic exchange is the interaction of water between rivers and groundwater, and is difficult to predict. One of the largest contributions to predictive uncertainty for hyporheic fluxes have been attributed to the representation of heterogeneous subsurface properties. This research aims to evaluate which aspect of the subsurface representation - the spatial distribution of hydrofacies or the model for local-scale (within-facies) heterogeneity - most influences the predictive uncertainty. Also, we seek to identify data types that help reduce this uncertainty best. For this investigation, we conduct a modelling study of the Steinlach River meander, in Southwest Germany. The Steinlach River meander is an experimental site established in 2010 to monitor hyporheic exchange at the meander scale. We use HydroGeoSphere, a fully integrated surface water-groundwater model, to model hyporheic exchange and to assess the predictive uncertainty of hyporheic exchange transit times (HETT). A highly parameterized complex model is built and treated as `virtual reality', which is in turn modelled with simpler subsurface parameterization schemes (Figure). Then, we conduct Monte-Carlo simulations with these models to estimate the predictive uncertainty. Results indicate that: Uncertainty in HETT is relatively small for early times and increases with transit times. Uncertainty from local-scale heterogeneity is negligible compared to uncertainty in the hydrofacies distribution. Introducing more data to a poor model structure may reduce predictive variance, but does not reduce predictive bias. Hydraulic head observations alone cannot constrain the uncertainty of HETT, however an estimate of hyporheic exchange flux proves to be more effective at reducing this uncertainty. Figure: Approach for evaluating predictive model uncertainty. A conceptual model is first developed from the field investigations. A complex model (`virtual reality') is then developed based on that conceptual model

Cinética de rehidratación y deterioro biológico en Zea mays almacenado a una Humedad Relativa del Aire Intergranular (HRAI del 92%

Directory of Open Access Journals (Sweden)

Eguiazu, G. M.

1993-12-01

Full Text Available Maize grains (Zea mays var indurata «Plata» tipe destined to commercialization were submitted to a relative humidity of the intergranular air of 92% during 120 days to 25 °C. The kinetics of rehydration, humidity and biological damage («mouldy» «blue eye» and «spoiled» was determined. After 14 to 17 days, the sample rehydrates on the basis of commercialization of 14,5% of humidity and in the same period a degree of standard of commercial quality is lost. It is established that the basis of commercialization of 14,5% is very near the limit which favours the biological damage.Granos de maíz (Zea mays var. indurata tipo «Plata», destinado a comercialización, fueron sometidos a una Humedad Relativa del Aire Intergranular del 92% a 25 °C durante 120 días. Se determinó la cinética de rehidratación, humedad y el deterioro biológico («Verdín» y «Dañado». Se observó que luego de 14 a 17 días la muestra se rehidrató por sobre la base de comercialización del 14,5% de humedad y en el mismo periodo se pierde un grado en el estandard de calidad comercial. Se plantea que la base de comercialización del 14,5% se halla muy cercana al límite que favorece el deterioro biológico.

Exchange-rate-based stabilization in Argentina and Chile : a fresh look

OpenAIRE

Kiguel, Miguel A.; Liviatan, Nissan

1994-01-01

Exchange-rate-based stabilization is designed to reduce inflation by using the exchange rate as the main nominal anchor. This does not necessarily mean a fixed exchange rate. A crawling peg with a low rate of depreciation or a pre-announced gradual reduction in the rate of devaluation are alternative ways to use the exchange rate as a nominal anchor. Exchange-rate-based stabilization (ERBS) has been widely used in the high-inflation economies of Latin America. Argentina, Chile, and Uruguay ad...

Analysis of proton exchange membrane fuel cell polarization losses at elevated temperature 120 {sup o}C and reduced relative humidity

Energy Technology Data Exchange (ETDEWEB)

Xu, Hui [Department of Chemical Engineering, University of Connecticut, Storrs, CT (United States)]. E-mail: huixu@lanl.gov; Kunz, H. Russell [Department of Chemical Engineering, University of Connecticut, Storrs, CT (United States); Fenton, James M. [Florida Solar Energy Center, University of Central Florida, Cocoa, FL (United States)

2007-03-01

Polarization losses of proton exchange membrane (PEM) fuel cells at 120 {sup o}C and reduced relative humidity (RH) were analyzed. Reduced RH affects membrane and electrode ionic resistance, catalytic activity and oxygen transport. For a cell made of Nafion (registered) 112 membrane and electrodes that have 35 wt.% Nafion (registered) and 0.3 mg/cm{sup 2} platinum supported on carbon, membrane resistance at 20%RH was 0.407 {omega} cm{sup 2} and electrode resistance 0.203 {omega} cm{sup 2}, significantly higher than 0.092 and 0.041 {omega} cm{sup 2} at 100%RH, respectively. In the kinetically controlled region, 20%RH resulted in 96 mV more cathode activation loss than 100%RH. Compared to 100%, 20%RH also produced significant oxygen transport loss across the ionomer film in the electrode, 105 mV at 600 mA/cm{sup 2}. The significant increase in polarization losses at elevated temperature and reduced RH indicates the extreme importance of designing electrodes for high temperature PEM fuel cells since membrane development has always taken most emphasis.

Microstructural-Scale Model for Surfaces Spreading of Intergranular Corrosion in Sensitized Stainless Steels and Aluminum-Magnesium (AA5XXX) Alloys

Science.gov (United States)

Jain, Swati

Components from AA5XXX (Al-Mg alloys with more than 3 wt% Mg) alloys are X attractive due to availability of low cost, high strength to weight ratio and good weldability. Therefore, these alloys have potential applications in Naval ships. However, these alloys become susceptible to IGC (intergranular corrosion) due to beta-phase precipitation due to improper heat treatment or inadvertent thermal exposure. Stainless steels may also become susceptible due to carbide precipitation and chromium depletion on grain boundaries. IGC susceptibility depends on the interplay between the metallurgical conditions, electrochemical conditions, and chemical conditions. Specific combinations cause IGC while others do not. The objective of this study is to investigate the conditions which bring about surface spreading of IGC in these alloy classes. To accomplish this goal, a microstructure scale model was developed with experimental inputs to understand the 2-D IGC spreading in stainless steels and AA5XXX alloys. The conditions strongly affecting IGC spreading were elucidated. Upon natural and artificial aging, the stainless steels become susceptible to intergranular corrosion because of chromium depletion in the grain boundaries. After aging Al-Mg (AA5XXX) alloys show susceptibility due to the precipitation of the beta-phase (Al3Mg7) in the grain boundaries. Chromium depleted grain boundaries in stainless steels are anodically more active as compared to the interior of the grains. (3-phase rich grain boundaries have lower OCP (open circuit potential) and pitting potentials as compared to the Al-Mg solid solutions. A new approach to modeling the IGC surface spreading in polycrystalline materials that is presented. This model is the first to couple several factors into one granular scale model that illustrates the way in which they interact and IGC occurs. It sheds new information on conditions which cause IGC spreading in two alloy classes and describes a new theory for the critical

Solution of operational problems utilization of an EX-IRT-2000 heat exchanger

International Nuclear Information System (INIS)

Razak, Abdu

1986-01-01

The Bandung TRIGA Mark II Reactor has been successfully operated for 21 years, especially in low power operation or as neutron sources for various experiments. Most of the operating time, approximately 80% of routine operation, was dedicated for radio-isotope production. During routine operation for radio-isotope production, the reactor could not be operated at full power. The reactor was operated at 60% of the maximum power (1 MWth) due to the inability of the original heat exchanger to operate properly. The reason is that slack deposition was built-up on the secondary side of the heat exchanger. Therefore, it reduced the coefficient of heat transfer considerably. To solve the problems, a set of heat exchanger including the pump was installed In parallel with the original unit. The heat exchanger was an IRT-2000 Reactor Heat exchanger which was collected from the abandoned IRT-2000 Project. The heat exchanger has capacity of 1.25 MW. The new heat exchanger could reduced the outlet temperature of the primary coolant Into 42 deg. C. While the original-heat exchanger at the worst condition and at 600 kW of power reach outlet temperature 49 deg. C. The IRT Heat Exchanger is a counter flow heat exchanger. (author)

Solution of operational problems utilization of an EX-IRT-2000 heat exchanger

Energy Technology Data Exchange (ETDEWEB)

Razak, Abdu [Research Centre for Nuclear Techniques, National Atomic Energy Agency (Indonesia)

1986-07-01

The Bandung TRIGA Mark II Reactor has been successfully operated for 21 years, especially in low power operation or as neutron sources for various experiments. Most of the operating time, approximately 80% of routine operation, was dedicated for radio-isotope production. During routine operation for radio-isotope production, the reactor could not be operated at full power. The reactor was operated at 60% of the maximum power (1 MWth) due to the inability of the original heat exchanger to operate properly. The reason is that slack deposition was built-up on the secondary side of the heat exchanger. Therefore, it reduced the coefficient of heat transfer considerably. To solve the problems, a set of heat exchanger including the pump was installed In parallel with the original unit. The heat exchanger was an IRT-2000 Reactor Heat exchanger which was collected from the abandoned IRT-2000 Project. The heat exchanger has capacity of 1.25 MW. The new heat exchanger could reduced the outlet temperature of the primary coolant Into 42 deg. C. While the original-heat exchanger at the worst condition and at 600 kW of power reach outlet temperature 49 deg. C. The IRT Heat Exchanger is a counter flow heat exchanger. (author)

Optimization of the Single Staggered Wire and Tube Heat Exchanger

Directory of Open Access Journals (Sweden)

Arsana I Made

2016-01-01

Full Text Available Wire and tube heat exchanger consists of a coiled tube, and wire is welded on the two sides of it in normal direction of the tube. Generally,wire and tube heat exchanger uses inline wire arrangement between the two sides, whereas in this study, it used staggered wire arrangement that reduces the restriction of convection heat transfer. This study performed the optimization of single staggered wire and tube heat exchanger to increase the capacity and reduce the mass of the heat exchanger. Optimization was conducted with the Hooke-Jeeves method, which aims to optimize the geometry of the heat exchanger, especially on the diameter (dw and the distance between wires (pw. The model developed to present heat transfer correlations on single staggered wire and tube heat exchanger was valid. The maximum optimization factor obtained when the diameter wire was 0.9 mm and the distance between wires (pw was 11 mm with the fref value = 1.5837. It means that the optimized design only using mass of 59,10 % and could transfer heat about 98,5 % from the basis design.

Practical design of a heat exchanger for dilution refrigeration. 1

Energy Technology Data Exchange (ETDEWEB)

Oda, Y; Fujii, G; Nagano, H [Tokyo Univ. (Japan). Inst. for Solid State Physics

1978-02-01

A compact heat exchanger for a dilution refrigerator with a high thermal efficiency is presented. Discrete heat exchangers with by-pass channels were used to decrease the flow impedance. This heat exchanger was designed so that the thermal conductance of liquid along the stream was greatly reduced. The effective thickness of the sponge material in the heat exchanger and mixer is also discussed. The obtained minimum temperatures of 12 mK was very close to the designed value of 10.8 mK. Moreover a rapid response was obtained. This is attributed to the small liquid volume of the heat exchanger.

Exact exchange-correlation potential and approximate exchange potential in terms of density matrices

International Nuclear Information System (INIS)

Holas, A.; March, N.H.

1995-01-01

An exact expression in terms of density matrices (DM) is derived for δF[n]/δn(r), the functional derivative of the Hohenberg-Kohn functional. The derivation starts from the differential form of the virial theorem, obtained here for an electron system with arbitrary interactions, and leads to an expression taking the form of an integral over a path that can be chosen arbitrarily. After applying this approach to the equivalent system of noninteracting electrons (Slater-Kohn-Sham scheme) and combining the corresponding result with the previous one, an exact expression for the exchange-correlation potential v xc (r) is obtained which is analogous in character to that for δF[n]/δn(r), but involving, besides the interacting-system DMs, also the noninteracitng DMs. Equating the former DMs to the latter ones, we reduce the result for the exact v xc (r) to that for an approximate exchange-only potential v x (r). This leads naturally to the Harbola-Sahni exchange-only potential

Heat exchanger tube inspection using ultrasonic arrays

International Nuclear Information System (INIS)

Meyer, P.A.; Carodiskey, T.J.

1986-01-01

Tubing used in industrial heat exchangers is often subject to failure caused by corrosion and cracking. Technical conferences are used as a forum in the steam generator industry to ensure that the failure mechanisms are well understood and that the quality of the heat exchanger is maintained. The quality of a heat exchanger can be thought of as its ability to operate to design specifications over its intended life. This is the motivation to inspect and evaluate these devices periodically. Inspection, however, normally requires shutdown of the heat exchanger which is costly but is much more acceptable than an unscheduled shutdown due to failure of a tube. Therefore, the degree of inspection is established by balancing the cost of inspection with the risk of a tube failure. Any method of reducing the cost of inspection will permit a higher degree of inspection and, therefore, improve heat exchanger quality. This paper reviews the design and performance of an improved method of ultrasonic inspection of heat exchanger tubing with emphasis on applications in the nuclear industry

Incineration of spent ion exchange resin

International Nuclear Information System (INIS)

Hasegawa, Chiaki

1990-01-01

It is a pressing need to reduce radioactive waste which is generated from the maintenance and operation of a nuclear power plant. Incineration of low level combustible solid waste such as polyethylene seats, paper and others have been successfully performed since 1984 at the Shimane Nuclear Power Station. Furthermore, for extending incineration treatment to spent ion exchange resin, the incineration test was carried out in 1989. However, as the cation exchange resin contains sulfur and then incineration generates SOx gases, so the components of this facility will be in a corrosive environment. We surveyed incineration conditions to improve the corrosive environment at the exhaust gas treatment system. This paper includes these test results and improved method to incinerate spent ion exchange resin. (author)

Replica exchange with solute tempering: A method for sampling biological systems in explicit water

Science.gov (United States)

Liu, Pu; Kim, Byungchan; Friesner, Richard A.; Berne, B. J.

2005-09-01

An innovative replica exchange (parallel tempering) method called replica exchange with solute tempering (REST) for the efficient sampling of aqueous protein solutions is presented here. The method bypasses the poor scaling with system size of standard replica exchange and thus reduces the number of replicas (parallel processes) that must be used. This reduction is accomplished by deforming the Hamiltonian function for each replica in such a way that the acceptance probability for the exchange of replica configurations does not depend on the number of explicit water molecules in the system. For proof of concept, REST is compared with standard replica exchange for an alanine dipeptide molecule in water. The comparisons confirm that REST greatly reduces the number of CPUs required by regular replica exchange and increases the sampling efficiency. This method reduces the CPU time required for calculating thermodynamic averages and for the ab initio folding of proteins in explicit water. Author contributions: B.J.B. designed research; P.L. and B.K. performed research; P.L. and B.K. analyzed data; and P.L., B.K., R.A.F., and B.J.B. wrote the paper.Abbreviations: REST, replica exchange with solute tempering; REM, replica exchange method; MD, molecular dynamics.*P.L. and B.K. contributed equally to this work.

Effect of the microstructure on the sensibilization to intergranular corrosion of a 24. 7 Cr7. 4Ni duplex stainless steel. Efecto de la microestructura en la sensibilizacion a la corrosion inoxidable duplex 24, 7Cr7,Ni

Energy Technology Data Exchange (ETDEWEB)

Otero, E; Pardo, A; Merino, C; Hierro, P; Perez, F J

1993-01-01

The influence of microstructure on the resistance to intergranular corrosion of a 24.4Cr7.4Ni is studied. The results are discussed both in terms of the Huey experiment as well as of the sweeping corresponding to the experimental conditions under which the experiments have been performed. Author (11 refs.)

Intergranular corrosion behavior associated with delta-ferrite transformation of Ti-modified Super304H austenitic stainless steel

International Nuclear Information System (INIS)

Bai, Guanshun; Lu, Shanping; Li, Dianzhong; Li, Yiyi

2015-01-01

Highlights: • Relationship between delta-ferrite transformation and IGC behavior was evaluated by DL-EPR test quantitatively. • The IGC site at austenite/ferrite grain boundary changes with aging time at 650 °C. • A higher fraction of delta-ferrite with poor stability increases the IGC sensitisation. • Self-healing of IGC was mainly induced by the Cr diffusion from primary austenite rather than the delta-ferrite. - Abstract: A double loop electrochemical potentiokinetic reactivation (DL-EPR) test was conducted to investigate the relationship between the evolution of delta-ferrite and the intergranular corrosion (IGC) of Ti-modified Super304H, which was aged at 650 °C for 4–500 h. Scanning electron microscopy and transmission electron microscopy were adopted to analyze the evolution of delta-ferrite. The results indicated that a higher fraction of delta-ferrite with poor stability increased the IGC sensitisation of Ti-modified Super304H. Moreover, the self-healing of the sensitisation of Ti-modified Super304H occurred after 48 h due to the diffusion of chromium atoms mainly from the adjacent primary austenite rather than the delta-ferrite

Cardioplegia heat exchanger design modelling using computational fluid dynamics.

Science.gov (United States)

van Driel, M R

2000-11-01

A new cardioplegia heat exchanger has been developed by Sorin Biomedica. A three-dimensional computer-aided design (CAD) model was optimized using computational fluid dynamics (CFD) modelling. CFD optimization techniques have commonly been applied to velocity flow field analysis, but CFD analysis was also used in this study to predict the heat exchange performance of the design before prototype fabrication. The iterative results of the optimization and the actual heat exchange performance of the final configuration are presented in this paper. Based on the behaviour of this model, both the water and blood fluid flow paths of the heat exchanger were optimized. The simulation predicted superior heat exchange performance using an optimal amount of energy exchange surface area, reducing the total contact surface area, the device priming volume and the material costs. Experimental results confirm the empirical results predicted by the CFD analysis.

Intergranular Corrosion Behavior of 304LN Stainless Steel Heat Treated at 623 K (350 °C)

Science.gov (United States)

Singh, Raghuvir; Kumar, Mukesh; Ghosh, Mainak; Das, Gautam; Singh, P. K.; Chattoraj, I.

2013-01-01

Low temperature sensitization of 304LN stainless steel from the two pipes, differing slightly in chemical composition, has been investigated; specimens were aged at 623 K (350 °C) for 20,000 hours and evaluated for intergranular corrosion and degree of sensitization. The base and heat-affected zone (HAZ) of the 304LN-1 appear resistant to sensitization, while 304LN-2 revealed a "dual" type microstructure at the transverse section and HAZ. The microstructure at 5.0-mm distance from the fusion line indicates qualitatively less sensitization as compared to that at 2.0 mm. The 304LN-2 base alloy shows overall lower degree of sensitization values as compared to the 304LN-1. A similar trend of degree of sensitization was observed in the HAZ where it was higher in the 304LN-1 as compared to the 304LN-2. The weld zone of both the stainless steels suffered from cracking during ASTM A262 practice E, while the parent metals and HAZs did not show such fissures. A mottled image within the ferrite lamella showed spinodal decomposition. The practice E test and transmission electron microscopy results indicate that the interdendritic regions may suffer from failure due to carbide precipitation and due to the evolution of brittle phase from spinodal decomposition.

Calculation of Scattering Amplitude Without Partial Analysis. II; Inclusion of Exchange

Science.gov (United States)

Temkin, Aaron; Shertzer, J.; Fisher, Richard R. (Technical Monitor)

2002-01-01

There was a method for calculating the whole scattering amplitude, f(Omega(sub k)), directly. The idea was to calculate the complete wave function Psi numerically, and use it in an integral expression for f, which can be reduced to a 2 dimensional quadrature. The original application was for e-H scattering without exchange. There the Schrodinger reduces a 2-d partial differential equation (pde), which was solved using the finite element method (FEM). Here we extend the method to the exchange approximation. The S.E. can be reduced to a pair of coupled pde's, which are again solved by the FEM. The formal expression for f(Omega(sub k)) consists two integrals, f+/- = f(sub d) +/- f(sub e); f(sub d) is formally the same integral as the no-exchange f. We have also succeeded in reducing f(sub e) to a 2-d integral. Results will be presented at the meeting.

Sulfur Isotope Exchange between S-35 Labeled Inorganic Sulfur-Compounds in Anoxic Marine-Sediments

DEFF Research Database (Denmark)

FOSSING, H.; THODEANDERSEN, S.; JØRGENSEN, BB

1992-01-01

of isotope exchange, specific radioactivities of the reduced sulfur pools were poorly defined and could not be used to calculate their rates of formation. Such isotope exchange reactions between the reduced inorganic sulfur compounds will affect the stable isotope distribution and are expected to decrease...

Spinor exchange in AdSd+1

International Nuclear Information System (INIS)

Kawano, Teruhiko; Okuyama, Kazumi

2000-01-01

We explicitly calculate a Witten diagram with general spinor field exchange on (d+1)-dimensional Euclidean Anti-de Sitter space, which is necessary to evaluate four-point correlation functions with spinor fields when we make use of the AdS/CFT correspondence, especially in supersymmetric cases. We also show that the amplitude can be reduced to a scalar exchange amplitude. We discuss the operator product expansion of the dual conformal field theory by interpreting the short distance expansion of the amplitude according to the AdS/CFT correspondence

Ion exchange removal of technetium from salt solutions

International Nuclear Information System (INIS)

Walker, D.D.

1983-01-01

Ion exchange methods for removing technetium from waste salt solutions have been investigated by the Savannah River Laboratory (SRL). These experiments have shown: Commercially available anion exchange resins show high selectivity and capacity for technetium. In column runs, 150 column volumes of salt solution were passed through an ion exchange column before 50% 99 Tc breakthrough was reached. The technetium can be eluted from the resin with nitric acid. Reducing resins (containing borohydride) work well in simple hydroxide solutions, but not in simulated salt solutions. A mercarbide resin showed a very high selectivity for Tc, but did not work well in column operation

Creep-fatique interactions in 316 stainless steel under torsional loading

International Nuclear Information System (INIS)

Wei, K.; Dyson, B.F.

1982-01-01

Some fatigue, fatigue with creep dwells and creep tests have been performed in torsion using 316 stainless steel at 600 0 C. As expected from push-pull testing, the introduction of a creep dwell reduced fatigue endurances and changed the fracture from classical transgranular to intergranular. Optical microscopical examination revealed a large number of intergranular cracks concentrated along shear planes, but quantitative assessment identified the importance of creep tensile stresses in crack development. In contrast, little intergranular damage was found after torsion creep, which is consistent with its exhibited buckling mode of failure. It is concluded that reverse plastic strain is the cause of intergranular crack formation in the material and is therefore the primary mechanism of creep-fatigue interaction. (author)

Exchanging grooming, but not tolerance and aggression in common marmosets (Callithrix jacchus).

Science.gov (United States)

Campennì, Marco; Manciocco, Arianna; Vitale, Augusto; Schino, Gabriele

2015-02-01

In this study, we investigated the reciprocal exchanges of grooming, tolerance and reduced aggression in common marmosets (Callithrix jacchus), a cooperatively breeding primate whose groups are typically characterized by uniformly high genetic relatedness and high interdependency between group members. Both partner control and partner choice processes played a role in the reciprocal exchanges of grooming. In contrast, we did not find any evidence of reciprocity between grooming and tolerance over a preferred food source or between grooming and reduced aggression. Thus, reciprocity seems to play a variable role in the exchange of cooperative behaviors in marmosets. © 2014 Wiley Periodicals, Inc.

Role of Lu and La in the intergranular films on growth of the prism surface in β-Si_3N_4: A molecular dynamics study

International Nuclear Information System (INIS)

Jiang, Yun; Garofalini, Stephen H.

2016-01-01

The different roles of Lu and La in the intergranular film in silicon nitride on the growth morphology are investigated via molecular dynamics simulations. While advanced microscopy shows each rare earth on the prism surface at room temperature, each additive affects the outward (perpendicular) growth of the surface differently. The simulations show the effect of elevated temperature on the adsorption of La and Lu on this surface that affects growth and provides the atomistic mechanism for the different growth morphology. - Graphical abstract: At elevated temperature, Lu ions move away from the surface as it grows, but remain in near contact (a-start, b-end), whereas La ions remain at the surface and prevent growth (c-start, d-end).

Magnetization reversal processes of isotropic permanent magnets with various inter-grain exchange interactions

Directory of Open Access Journals (Sweden)

Hiroshi Tsukahara

2017-05-01

Full Text Available We performed a large-scale micromagnetics simulation on a supercomputing system to investigate the properties of isotropic nanocrystalline permanent magnets consisting of cubic grains. In the simulation, we solved the Landau–Lifshitz–Gilbert equation under a periodic boundary condition for accurate calculation of the magnetization dynamics inside the nanocrystalline isotropic magnet. We reduced the inter-grain exchange interaction perpendicular and parallel to the external field independently. Propagation of the magnetization reversal process is inhibited by reducing the inter-grain exchange interaction perpendicular to the external field, and the coercivity is enhanced by this restraint. In contrast, when we reduce the inter-grain exchange interaction parallel to the external field, the coercivity decreases because the magnetization reversal process propagates owing to dipole interaction. These behaviors show that the coercivity of an isotropic permanent magnet depends on the direction of the inter-grain exchange interaction.

Eddy current technology for heat exchanger and steam generator tube inspection

Energy Technology Data Exchange (ETDEWEB)

Obrutsky, L.; Lepine, B.; Lu, J.; Cassidy, R.; Carter, J. [Atomic Energy of Canada Limited, Chalk River, Ontario (Canada)

2004-07-01

A variety of degradation modes can affect the integrity of both heat exchanger (HX) and balance of plant tubing, resulting in expensive repairs, tube plugging or replacement of tube bundles. One key component for ensuring tube integrity is inspection and monitoring for detection and characterization of the degradation. In-service inspection of HX and balance of plant tubing is usually carried out using eddy current (EC) bobbin coils, which are adequate for the detection of volumetric degradations. However, detection and quantification of additional modes of degradation such as pitting, intergranular attack (IGA), axial cracking and circumferential cracking require specialized probes. The need for timely, reliable detection and characterization of these modes of degradation is especially critical in Nuclear Generating Stations. Transmit-receive single-pass array probes, developed by AECL, offer high defect detectability in conjunction with fast and reliable inspection capabilities. They have strong directional properties, permitting probe optimization for circumferential or axial crack detection. Compared to impedance probes, they offer improved performance in the presence of variable lift-off. This EC technology can help resolve critical detection issues at susceptible areas, such as the rolled-joint transitions at the tubesheet, U-bends and tube-support intersections. This paper provides an overview of the operating principles and the capabilities of advanced ET inspection technology available for HX tube inspection. Examples of recent application of this technology in Nuclear Generating Stations (NGSs) are discussed. (author)

Eddy current technology for heat exchanger and steam generator tube inspection

International Nuclear Information System (INIS)

Obrutsky, L.; Lepine, B.; Lu, J.; Cassidy, R.; Carter, J.

2004-01-01

A variety of degradation modes can affect the integrity of both heat exchanger (HX) and balance of plant tubing, resulting in expensive repairs, tube plugging or replacement of tube bundles. One key component for ensuring tube integrity is inspection and monitoring for detection and characterization of the degradation. In-service inspection of HX and balance of plant tubing is usually carried out using eddy current (EC) bobbin coils, which are adequate for the detection of volumetric degradations. However, detection and quantification of additional modes of degradation such as pitting, intergranular attack (IGA), axial cracking and circumferential cracking require specialized probes. The need for timely, reliable detection and characterization of these modes of degradation is especially critical in Nuclear Generating Stations. Transmit-receive single-pass array probes, developed by AECL, offer high defect detectability in conjunction with fast and reliable inspection capabilities. They have strong directional properties, permitting probe optimization for circumferential or axial crack detection. Compared to impedance probes, they offer improved performance in the presence of variable lift-off. This EC technology can help resolve critical detection issues at susceptible areas, such as the rolled-joint transitions at the tubesheet, U-bends and tube-support intersections. This paper provides an overview of the operating principles and the capabilities of advanced ET inspection technology available for HX tube inspection. Examples of recent application of this technology in Nuclear Generating Stations (NGSs) are discussed. (author)

Causes and Results of Exchange Rate Intervention Under Inflation Targeting

Directory of Open Access Journals (Sweden)

Bora Suslu

2012-06-01

Full Text Available Under inflation targeting, central banks exchange rate interventions are discussed frequently in the economic literature recently. Effectiveness of intervention in exchange rate under inflation targeting are examined from three perspectives. These are expectations of the actors and the impact on the variance, reserve accumulation and the cost of sterilization. Since 2003 the Central Bank of Turkey has intervened exchange rate with both direct and indirect methods. The purpose of this study is to examine the results of these three aspects of the CBRT and the foreign exchange interventions. We found that by logit analysis under the inflation targeting of CBRT as a result of the intervention of exchange rate is effect expectations of economic unit and reduce of exchange rate the variance; after thes intervention the variance of exchange rate and cost of sterilization are increased. In this respect, the effectiveness of the intervention of the Central Bank exchange rate market is only reserve accumulation

Thermal stability, thermal expansion and grain-growth in exchange-coupled Fe-Pt-Ag-B bulk nanocomposite magnets

International Nuclear Information System (INIS)

Nicula, R.; Crisan, O.; Crisan, A.D.; Mercioniu, I.; Stir, M.; Vasiliu, F.

2015-01-01

Highlights: • Formation of the L10 FePt hard-magnetic phase (>90%) directly in the as-cast state. • Specific alternating hard/soft nanostructure is stable to 600 °C without grain growth. • Anisotropic and non-linear thermal expansion effects. • The FePtAgB alloy behaves like a single magnetic phase (full exchange coupling). - Abstract: Rare-earth free (RE-free) exchange coupling nanocomposite magnets are intensively studied nowadays due to their potential use in applications demanding stable high-temperature operation and corrosion resistance. In this respect, the FePt alloy system is one of the most actively addressed potential permanent magnet solutions. In FePt alloys, promising magnetic features arise from the co-existence of hard magnetic L1 0 FePt and soft magnetic L1 2 Fe 3 Pt phases emerged from the same metastable precursor. The present work deals with an in-situ temperature-resolved synchrotron radiation study of the thermal stability, thermal expansion and microstructure evolution in exchange-coupled FePtAgB alloys. The as-cast microstructural state as well as the optimized magnetic behavior are given as reference and correlated to the observed microstructural evolution with temperature. The melt-spun Fe 48 Pt 28 Ag 6 B 18 alloy ribbons were examined in situ by synchrotron X-ray powder diffraction from ambient temperature up to 600 °C. The FePt-Fe 3 Pt exchange-coupled microstructure achieved by rapid solidification is not significantly altered during the high temperature exposure. The thermal expansion of the FePt L1 0 unit cell has been found to be strongly anisotropic, being essentially an in-plane expansion which may be seen as an anisotropic invar effect. For the FePt L1 0 phase, a significant deviation from linear thermal expansion is observed at the Curie temperature T C = 477 °C. This non-linear behavior above T C is tentatively linked to a diffusion/segregation mechanism of Ag. The promising hard magnetic properties as well as the

Desirable levels of exchangeable K and Ca and their concentration in the soil solution to reduce uptake of radioactive Cs by rice plants

International Nuclear Information System (INIS)

Sekimoto, Hitoshi; Yamada, Takashi; Hotsuki, Tomoe; Matsuzaki, Akio; Mimura, Tetsuro

2014-01-01

K in the soil solution can control the uptake of radioactive Cs by rice plants, but this control is not accomplished only by K; it is affected by other ionic species. It is therefore important to investigate uptake of radioactive Cs from the perspective of the concentration of major cations such as Ca in the soil solution and the levels of exchangeable cations in the soil. To clarify the effects of K and Ca in the soil solution and of the levels of soil exchangeable cations to prevent uptake of radioactive Cs, we conducted a pot experiment and field experiments in a paddy soil in 2011 and 2012. To reduce the uptake of radioactive Cs, it was necessary to achieve a K concentration in the soil solution of 0.5 mmol L"-"1, and a Ca concentration higher than 2 mmol L"-"1 based on the results of the pot experiment. In addition, we obtained the desirable levels of exchangeable cations and the cation exchange capacity (CEC) in the soil from previous reports and the results of our field experiments. On this basis, we propose the following threshold levels for exchangeable cations and CEC in the soil as a standard: 0.53 K cmol_c kg"-"1, 18.0 Ca cmol_c kg"-"1, 2.0 Mg cmol_c kg"-"1, i.e. 25 mg K_2O 100 g"-"1, 505 mg CaO 100 g"-"1, 40 Mg O mg 100 g"-"1, and a CEC of 30 cmol_c kg"-"1. Converting these values into the corresponding levels in the soil solution, we obtained concentrations of 0.71 mmol K L"-"1, 4.22 mmol Ca L"-"1, and 1.35 mmol Mg L"-"1. These levels are within the improving standard for fertility of paddy soils in Japan. Consequently, it will be necessary to improve the fertility of paddy soils to control the uptake of radioactive Cs by rice plants. (author)

Method of processing spent ion exchange resins

International Nuclear Information System (INIS)

Mori, Kazuhide; Tamada, Shin; Kikuchi, Makoto; Matsuda, Masami; Aoyama, Yoshiyuki.

1985-01-01

Purpose: To decrease the amount of radioactive spent ion exchange resins generated from nuclear power plants, etc and process them into stable inorganic compounds through heat decomposition. Method: Spent ion exchange resins are heat-decomposed in an inert atmosphere to selectively decompose only ion exchange groups in the preceeding step while high molecular skeltons are completely heat-decomposed in an oxidizing atmosphere in the succeeding step. In this way, gaseous sulfur oxides and nitrogen oxides are generated in the preceeding step, while gaseous carbon dioxide and hydrogen requiring no discharge gas procession are generated in the succeeding step. Accordingly, the amount of discharged gases requiring procession can significantly be reduced, as well as the residues can be converted into stable inorganic compounds. Further, if transition metals are ionically adsorbed as the catalyst to the ion exchange resins, the ion exchange groups are decomposed at 130 - 300 0 C, while the high molecular skeltons are thermally decomposed at 240 - 300 0 C. Thus, the temperature for the heat decomposition can be lowered to prevent the degradation of the reactor materials. (Kawakami, Y.)

Study of the thermal transformations of Co- and Fe-exchanged zeolites A and X by 'in situ' XRD under reducing atmosphere

Energy Technology Data Exchange (ETDEWEB)

Ronchetti, Silvia, E-mail: silvia.ronchetti@polito.it [Dipartimento di Scienza dei Materiali e Ingegneria Chimica, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino (Italy); Turcato, Elisa Aurelia; Delmastro, Alessandro [Dipartimento di Scienza dei Materiali e Ingegneria Chimica, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino (Italy); Esposito, Serena; Ferone, Claudio; Pansini, Michele [Laboratorio Materiali del Dipartimento di Meccanica, Strutture, Ambiente e Territorio, Facolta di Ingegneria dell' Universita di Cassino, Via G. Di Biasio 43, 03043 Cassino (Italy); Onida, Barbara; Mazza, Daniele [Dipartimento di Scienza dei Materiali e Ingegneria Chimica, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino (Italy)

2010-06-15

'In situ' high temperature X-ray diffraction under reducing atmosphere is used for the first time to study the thermal stability and transformations of Co- and Fe-exchanged A and X zeolites. TG-DTA and 'ex situ' XRD characterization were also carried out. The temperature of incipient crystallization of metallic phase was found to be 700 {sup o}C in Fe-zeolites and 800 {sup o}C in Co-zeolites. Moreover, ex situ X-ray experiments, after thermal treatment both under inert and reducing atmosphere, revealed the formation of ceramic phases upon the thermal collapse of the zeolitic framework. Metal nanoparticles were obtained by reduction and the size of metal clusters was found to range between 24 and 40 nm.

Method of stopping operation of PWR type reactor

International Nuclear Information System (INIS)

Ueno, Takashi; Tsuge, Ayao; Kawanishi, Yasuhira; Onimura, Kichiro; Kadokami, Akira.

1989-01-01

In PWR type reactors after long period of l00 % power operation, since boiling is caused in heat conduction pipes and water is depleted within the intergranular corrosion fracture face in the crevis portion to result in a dry-out state, impregnation and concentration of corrosion inhibitors into the intergranular corrosion fracture face are insufficient. In view of the above, the corrosion inhibitor at a high concentration is impregnated into the intergranular corrosion fracture face by keeping to inject the corrosion inhibitor from l00 % thermal power load by way of the thermal power reduction to the zero power state upon operatioin shutdown. That is, if the thermal power is reduced to or near the 0 power upon reactor shutdown, feedwater in the crevis portion is put to subcooled state, by which the steam present in the intergranular corrosion fracture face are condensated and the corrosion inhibitor at high concentration impregnated into the crevis portion are penetrated into the intergranular corrosion fracture face. (K.M.)

Insurance Exchange Marketplace: Implications for Emergency Medicine Practice

Directory of Open Access Journals (Sweden)

David S. Rankey, MD, MPH

2012-05-01

Full Text Available The Patient Protection and Affordable Care Act of 2010 requires states to establish healthcareinsurance exchanges by 2014 to facilitate the purchase of qualified health plans. States are required toestablish exchanges for small businesses and individuals. A federally operated exchange will beestablished, and states failing to participate in any other exchanges will be mandated to join the federalexchange. Policymakers and health economists believe that exchanges will improve healthcare atlower cost by promoting competition among insurers and by reducing burdensome transaction costs.Consumers will no longer be isolated from monthly insurance premium costs. Exchanges will increasethe number of patients insured with more cost-conscious managed care and high-deductible plans.These insurance plan models have historically undervalued emergency medical services, while alsounderinsuring patients and limiting their healthcare system access to the emergency department. Thisparadoxically increases demand for emergency services while decreasing supply. The continualdevaluation of emergency medical services by insurance payers will result in inadequate distribution ofresources to emergency care, resulting in further emergency department closures, increases inemergency department crowding, and the demise of acute care services provided to families andcommunities.

Structure design of primary heat-exchanger for the MHWRR

International Nuclear Information System (INIS)

Li Yanshui; Cao Zhibin

1999-01-01

Primary heat-exchanger is one of the key equipment in the Multi-application Heavy Water Research Reactor (MHWRR). Its structure design ought to meet as much possible as the demands for safety, feasibility and economy. To reduce the liquid resistance, the locating structure between inner tube and outer tube is distributed spirally. The edge of outer tube is processed in the shape of hexahedron and then splice-welded into honeycomb structure thereby the heat-exchanger has the smallest outer diameter compared with that with the same heat-exchanging area according to 'Normal Design', 'Anabasis Design' is applied to the design for parts with Safety Class I, to ensure safety of the heat-exchanger

Various methods to improve heat transfer in exchangers

Directory of Open Access Journals (Sweden)

Pavel Zitek

2015-01-01

Full Text Available The University of West Bohemia in Pilsen (Department of Power System Engineering is working on the selection of effective heat exchangers. Conventional shell and tube heat exchangers use simple segmental baffles. It can be replaced by helical baffles, which increase the heat transfer efficiency and reduce pressure losses. Their usage is demonstrated in the primary circuit of IV. generation MSR (Molten Salt Reactors. For high-temperature reactors we consider the use of compact desk heat exchangers, which are small, which allows the integral configuration of reactor. We design them from graphite composites, which allow up to 1000°C and are usable as exchangers: salt-salt or salt-acid (e.g. for the hydrogen production. In the paper there are shown thermo-physical properties of salts, material properties and principles of calculations.

12 CFR 614.4900 - Foreign exchange.

Science.gov (United States)

2010-01-01

... with relationship to the customer's financial capability to bear the financial risks assumed. The bank..., where such transactions or positions normally reduce risks in the conduct and management of..., liabilities, and foreign exchange contracts. (3) Outstanding contracts with individual customers and banks. (4...

Operating experience with ion exchanger beds in CIRUS

International Nuclear Information System (INIS)

Acharya, V.N.; Hajra, P.

1977-01-01

Operating experience with the ion exchanger beds in CIRUS reactor is narrated. Ion exchangers are provided for demineralisation of make up water and purification of closed loop water circuits. Exhaustion of resin is assessed on the basis of CO 2 concentration in the helium vent gas of the heavy water system. It is recommended that valves in the resin columns for rod handling bays be located outside the enclosure and each bed to reduce man-rem consumption during maintenance. Repeated backwash of the bed reduces chocking of water space with resin fines. Preventive maintenance avoids leakage past valves. Active resin from the resin beds is removed by hydraulic transfer method. (M.G.B.)

Heat transfer enhancement in cross-flow heat exchanger using vortex generator

International Nuclear Information System (INIS)

Yoo, S. Y.; Kwon, H. K.; Kim, B. C.; Park, D. S.; Lee, S. S.

2003-01-01

Fouling is very serious problem in heat exchanger because it rapidly deteriorates the performance of heat exchanger. Cross-flow heat exchanger with vortex generators is developed, which enhance heat transfer and reduce fouling. In the present heat exchanger, shell and baffle are removed from the conventional shell-and-tube heat exchanger. The naphthalene sublimation technique is employed to measure the local heat transfer coefficients. The experiments are performed for single circular tube, staggered array tube bank and in-line array tube bank with and without vortex generators. Local and average Nusselt numbers of single tube and tube bank with vortex generator are investigated and compared to those of without vortex generator

Charge exchange in a divertor plasma with excited particles

International Nuclear Information System (INIS)

Krasheninnikov, S.I.; Lisitsa, V.S.; Pigarov, A.Y.

1988-01-01

A model is constructed for the dynamics of neutral atoms and multicharged ions in a tokamak plasma. The influence of cascade excitation on charge exchange and ionization is taken into account. The effective rates of the resonant charge exchange of a proton with a hydrogen atom, the nonresonant charge exchange of a helium atom with a proton, and that of an α particle with atomic hydrogen are calculated as functions of the parameters of the divertor plasma in a tokamak. The charge exchange H + +He→H+He + can represent a significant fraction (∼30%) of the total helium ionization rate. Incorporating the charge exchange of He 2+ with atomic hydrogen under the conditions prevailing in the divertor plasma of the INTOR reactor can lead to substantial He 2+ →He + conversion and thereby reduce the sputtering of the divertor plates by helium ions

New anion-exchange polymers for improved separations

International Nuclear Information System (INIS)

Jarvinen, G.D.; Barr, M.E.; Marsh, S.F.

1997-01-01

Objective is to improve the understanding of how the structure of a new class of anion-exchange polymers controls the binding of anionic actinide complexes from solution. This is needed to develop practical separation systems that will reduce the cost of actinide processing operations within the DOE complex. In addition anion exchange is widely used in industry. Several new series of bifunctional anion- exchange polymers have been designed, synthesized, and tested for removing Pu(IV), Am(III), and U(VI) from nitric acid. The polymers contain a pyridinium site derived from the host poly(4-vinylpyridine) and a second cationic site attached through a chain of 2 to 6 methylene groups. The new polymers removed Pu four to ten times more efficiently than the best commercial materials

On the spillover of exchange rate risk into default risk

Directory of Open Access Journals (Sweden)

Božović Miloš

2009-01-01

Full Text Available In order to reduce the exchange-rate risk, banks in emerging markets are typically denominating their loans in foreign currencies. However, in the event of a substantial depreciation of the local currency, the payment ability of a foreign-currency borrower may be reduced significantly, exposing the lender to additional default risk. This paper analyses how the exchange-rate risk of foreign currency loans spills over into default risk. We show that in an economy where foreign currency loans are a dominant source of financing economic activity, depreciation of the local currency establishes a negative feedback mechanism that leads to higher default probabilities, reduced credit supply, and reduced growth. This finding has some important implications that may be of special interest for regulators and market participants in emerging economies.

Ultrafiltration Membrane Fouling and the Effect of Ion Exchange Resins

KAUST Repository

Jamaly, Sanaa

2011-12-01

Membrane fouling is a challenging process for the ultrafiltration membrane during wastewater treatment. This research paper determines the organic character of foulants of different kinds of wastewater before and after adding some ion exchange resins. Two advanced organic characterization methods are compared in terms of concentration of dissolved organic carbons: The liquid chromatography with organic carbon (LC-OCD) and Shimadzu total organic carbon (TOC). In this study, two secondary wastewater effluents were treated using ultrafiltration membrane. To reduce fouling, pretreatment using some adsorbents were used in the study. Six ion exchange resins out of twenty were chosen to compare the effect of adsorbents on fouling membrane. Based on the percent of dissolved organic carbon’s removal, three adsorbents were determined to be the most efficient (DOWEX Marathon 11 anion exchange resin, DOWEX Optipore SD2 polymeric adsorbent, and DOWEX PSR2 anion exchange), and three other ones were determined to the least efficient (DOWEX Marathon A2 anion exchange resin, DOWEX SAR anion exchange resin, and DOWEX Optipore L493 polymeric adsorbent). Organic characterization for feed, permeate, and backwash samples were tested using LC-OCD and TOC to better understand the characteristics of foulants to prevent ultrafiltration membrane fouling. The results suggested that the polymeric ion exchange resin, DOWEX SD2, reduced fouling potential for both treated wastewaters. All the six ion exchange resins removed more humic fraction than other organic fractions in different percent, so this fraction is not the main for cause for UF membrane fouling. The fouling of colloids was tested before and after adding calcium. There is a severe fouling after adding Ca2+ to effluent colloids.

Macro and intergranular stress responses of austenitic stainless steel to 90° strain path changes

International Nuclear Information System (INIS)

Gonzalez, D.; Kelleher, J.F.; Quinta da Fonseca, J.; Withers, P.J.

2012-01-01

Highlights: ► We measure and model the macro and IG stresses of ASS to 90° strain path changes. ► The macro stress–strain curves show a clear Bauschinger effect on reloading. ► This is only partially captured by the model. ► The measured {h k l} families show an earlier microyield than predicted. ► This difference is more noticeable for a strain path with a higher reversibility. - Abstract: Strain path history can play a crucial role in sensitising/desensitising metals to various damage mechanisms and yet little work has been done to quantify and understand how intergranular strains change upon path changes, or their effect on the macroscopic behaviour. Here we have measured, by neutron diffraction, and modelled, by crystal plasticity finite elements, the stress–strain responses of 316L stainless steel over three different 90° strain path changes using an assembled microstructure of randomly oriented crystallites. The measurements show a clear Bauschinger effect on reloading that is only partially captured by the model. Further, measurements of the elastic response of different {h k l} grain families revealed an even earlier onset of yield for strain paths reloaded in compression while a strain path reloaded in tension showed good agreement with corresponding predictions. Finally, we propose that the study of strain path effects provides a more rigorous test of crystal plasticity models than conventional in situ diffraction studies of uniaxial loading.

Standard test method for determining the susceptibility to intergranular corrosion of 5XXX series Aluminum alloys by mass loss after exposure to nitric acid (NAMLT Test)

CERN Document Server

American Society for Testing and Materials. Philadelphia

2004-01-01

1.1 This test method describes a procedure for constant immersion intergranular corrosion testing of 5XXX series aluminum alloys. 1.2 This test method is applicable only to wrought products. 1.3 This test method covers type of specimen, specimen preparation, test environment, and method of exposure. 1.4 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

The gecko visual pigment: the chromophore dark exchange reaction.

Science.gov (United States)

Crescitelli, F

1988-02-01

This study confirms the occurrence of a dark-exchange reaction in the extracted 521-pigment of the Tokay gecko (G. gekko). The present study involved the exchange, in the dark, of the natural 11-cis-chromophore by the 9-cis-10-F-retinal analog. This analog is able to combine with the 521-opsin to regenerate a photopigment at 492 nm. In addition to this shift in absorbance from 521 to 492 nm, the analog photopigment has a photosensitivity some 2.4% that of the native 521-system in the chloride-sufficient state. These two properties of the regenerated analog pigment have simplified the demonstration of a dark exchange of chromophores. At 15 degrees C the 9-cis-10-F-analog replaces the 11-cis-chromophore by at least 30% (density-wise) in about 15 hr. This exchange occurs with the system in the chloride-deficient state. The presence of chloride during the period in the dark significantly reduces the magnitude of the exchange. Apparently, the protein has a more open structure at the chromophoric binding site, allowing this interchange of chromophores. The addition of chloride induces a conformational change at this site, 'burying' the Schiff base and reducing the exchange reaction. The biological implication of this mobile property of the gecko opsin is that it is similar to the behavior of the cone pigment iodopsin but is unlike that of rhodopsins. This supports the idea that the gecko visual cells, despite their appearance as rods, are phylogenetically related to ancestral photopic receptors.

Segmented heat exchanger

Science.gov (United States)

Baldwin, Darryl Dean; Willi, Martin Leo; Fiveland, Scott Byron; Timmons, Kristine Ann

2010-12-14

A segmented heat exchanger system for transferring heat energy from an exhaust fluid to a working fluid. The heat exchanger system may include a first heat exchanger for receiving incoming working fluid and the exhaust fluid. The working fluid and exhaust fluid may travel through at least a portion of the first heat exchanger in a parallel flow configuration. In addition, the heat exchanger system may include a second heat exchanger for receiving working fluid from the first heat exchanger and exhaust fluid from a third heat exchanger. The working fluid and exhaust fluid may travel through at least a portion of the second heat exchanger in a counter flow configuration. Furthermore, the heat exchanger system may include a third heat exchanger for receiving working fluid from the second heat exchanger and exhaust fluid from the first heat exchanger. The working fluid and exhaust fluid may travel through at least a portion of the third heat exchanger in a parallel flow configuration.

Speeding-up exchange-mediated saturation transfer experiments by Fourier transform

Energy Technology Data Exchange (ETDEWEB)

Carneiro, Marta G.; Reddy, Jithender G.; Griesinger, Christian; Lee, Donghan, E-mail: dole@nmr.mpibpc.mpg.de [Max-Planck Institute for Biophysical chemistry, Department of NMR-based Structural Biology (Germany)

2015-11-15

Protein motions over various time scales are crucial for protein function. NMR relaxation dispersion experiments play a key role in explaining these motions. However, the study of slow conformational changes with lowly populated states remained elusive. The recently developed exchange-mediated saturation transfer experiments allow the detection and characterization of such motions, but require extensive measurement time. Here we show that, by making use of Fourier transform, the total acquisition time required to measure an exchange-mediated saturation transfer profile can be reduced by twofold in case that one applies linear prediction. In addition, we demonstrate that the analytical solution for R{sub 1}ρ experiments can be used for fitting the exchange-mediated saturation transfer profile. Furthermore, we show that simultaneous analysis of exchange-mediated saturation transfer profiles with two different radio-frequency field strengths is required for accurate and precise characterization of the exchange process and the exchanging states.

Speeding-up exchange-mediated saturation transfer experiments by Fourier transform

International Nuclear Information System (INIS)

Carneiro, Marta G.; Reddy, Jithender G.; Griesinger, Christian; Lee, Donghan

2015-01-01

Protein motions over various time scales are crucial for protein function. NMR relaxation dispersion experiments play a key role in explaining these motions. However, the study of slow conformational changes with lowly populated states remained elusive. The recently developed exchange-mediated saturation transfer experiments allow the detection and characterization of such motions, but require extensive measurement time. Here we show that, by making use of Fourier transform, the total acquisition time required to measure an exchange-mediated saturation transfer profile can be reduced by twofold in case that one applies linear prediction. In addition, we demonstrate that the analytical solution for R 1 ρ experiments can be used for fitting the exchange-mediated saturation transfer profile. Furthermore, we show that simultaneous analysis of exchange-mediated saturation transfer profiles with two different radio-frequency field strengths is required for accurate and precise characterization of the exchange process and the exchanging states

Use of storage tank holdup measurements to reduce inventory differences in an ion exchange process

International Nuclear Information System (INIS)

Bonner, C.A.; Marshall, R.

1986-01-01

Inventory differences (ID) in an ion exchange process area have plagued the Los Alamos National Laboratory for years. The problem has always been attributed to plutonium precipitation in banks of horizontally oriented storage tanks; however, efforts to maintain the precipitates at low enough or even stable levels failed. Factoring tank holdup measurements into the end-of-month inventory balance would probably solve the ID problem; however, the authors were advised that gamma-based holdup measurements would yield very poor quality holdup estimates because of difficulties in determining transmission corrections and tank ''cross talk.'' When the ID problem became particularly troublesome in the spring of 1985, the authors evaluated two different gamma-based measurement techniques for estimating tank holdup. Not only did holdup estimates made by the two techniques agree, but plutonium recovered during intensive tank cleanout confirmed that the holdup measurements were of sufficient accuracy to be used for material balance adjustments. The measurement method chosen for routine use is somewhat unique since it is calibrated using tank cleanout data and requires no transmission corrections. The holdup measurements are made on a monthly basis and have dramatically reduced end-of-month inventory differences. This paper will present both a description of the measurement methodology and the inventory difference improvements

Tensor exchange amplitudes in K +- N charge exchange reactions

International Nuclear Information System (INIS)

Svec, M.

1979-01-01

Tensor (A 2 ) exchange amplitudes in K +- N charge exchange (CEX) are constructed from the K +- N CEX data supplemented by information on the vector (rho) exchange amplitudes from πN sca tering. We observed new features in the t-structure of A 2 exchange amplitudes which contradict the t-de pendence anticipated by most of the Regge models. The results also provide evidence for violation of weak exchange degeneracy

Real Exchange Rates in Advanced Transition Economies

Directory of Open Access Journals (Sweden)

Sanja Grubacic

2015-10-01

Full Text Available The recent evidence from Eastern Europe suggests that one of the major obstacles towards the adoption of euro may lie in the impact that the recession of 2008 exerted on the trajectory of real exchange rates in new member countries (European Commission, 2015.  This paper aims to establish and explain the relationship between the external shocks derived from the global financial crisis and recession of 2008 and equilibrium real exchange rate in advanced transition economies of Eastern Europe. The interplay between the external and internal balances is explained by developing an inter-temporal optimizing model of the real exchange rate determination in a small open economy with structural distortions. The results of our model suggest that, in the aftermath of recession, if the Eastern European economies attempt to restore and maintain the balance between the consumption, saving, and investment, the equilibrium real exchange rate will tend to reverse its trajectory from appreciation to depreciation over time in order to encourage a greater production in the future. The equilibrium real exchange rate depreciation in the future may obtain either as a result of an increase in the direct subsidies on investment or as a result of reduced subsidies on the "net-of-investment" income.  The deprecation of countries’ real exchange rate, however, may continue to act as an effective constraint against the adoption of euro.

Study on actinoid isolation by antimonide ion exchanger

Energy Technology Data Exchange (ETDEWEB)

Tsuji, Masamichi [Tokyo Inst. of Tech. (Japan). Faculty of Science; Kubota, Masumitsu; Yamagishi, Isao

1996-01-01

To establish a containment of long-life nuclides and an effective reduction of waste volume is important to reduce the loadings on the natural environment. Chemical isolation of radioactive nuclides from wastes was attempted by using inorganic ion exchanger with high specificity and thermal stability. In this study, titanium antimonide was used as an ion exchanger to investigate the adsorption of trivalent metallic ions according to Kielland plot curves. When the ionic equivalent fraction (X-bar{sub M}) was around 0.005, Kielland plot curve of either of 3-valent metallic ions was bent, suggesting the exchanger had two different adsorption sites. The slope of the curve became smaller as an elevation of temperature. These results show that the ion radius was decreased resulting from partial elimination of the hydrated water of ion and thus, the steric conditions around the exchange site might be improved. (M.N.)

Eddy current testing of heat exchangers tubes

International Nuclear Information System (INIS)

Gouez, J.F.; Rieusset, A.; Groix, F.

An automatic system for Eddy Current testing of heat exchangers tubes of warships was developed. The advantages are an exposure of the controller limited at the time required to put in place the system and a reduced time of control [fr

Harnessing Private-Sector Innovation to Improve Health Insurance Exchanges.

Science.gov (United States)

Gresenz, Carole Roan; Hoch, Emily; Eibner, Christine; Rudin, Robert S; Mattke, Soeren

2016-05-09

Overhauling the individual health insurance market-including through the creation of health insurance exchanges-was a key component of the Patient Protection and Affordable Care Act's multidimensional approach to addressing the long-standing problem of the uninsured in the United States. Despite succeeding in enrolling millions of Americans, the exchanges still face several challenges, including poor consumer experience, high operational and development costs, and incomplete market penetration. In light of these challenges, analysts considered a different model for the exchanges-privately facilitated exchanges-which could address these challenges and deepen the Affordable Care Act's impact. In this model, the government retains control over sovereign exchange functions but allows the private sector to assume responsibility for more-peripheral exchange functions, such as developing and sustaining exchange websites. Although private-sector entities have already undertaken exchange-related functions on a limited basis, privately facilitated exchanges could conceivably relieve the government of its responsibility for front-end website operations and consumer decision-support functions entirely. A shift to privately facilitated exchanges could improve the consumer experience, increase enrollment, and lower costs for state and federal governments. A move to such a model requires, nonetheless, managing its risks, such as reduced consumer protection, increased consumer confusion, and the possible lack of a viable revenue base for privately facilitated exchanges, especially in less populous states. On net, the benefits are large enough and the risks sufficiently manageable to seriously consider such a shift. This paper provides background information and more detail on the analysts' assessment.

THE RELATIONSHIP BETWEEN THE EXCHANGE RATE AND THE INFLATION: EMPIRICAL SURVEY FOR ROMANIA

OpenAIRE

Catalina Adriana Handoreanu

2008-01-01

The influence on price level of changes in exchange rate comeback in the last period in the attention of economists and policy makers. The price level movement due to the changes in the exchange rate is named exchange rate pass-through and is important for the monetary policy and for the exchange rate choice. A reduced passthrough makes the monetary policy more independent and more easily implementation of inflation targeting. This working paper analyzed this phenomenon through a recursive eq...

Optimization of liquid LBE-helium heat exchanger in ADS

International Nuclear Information System (INIS)

Meng Ruixue; Cai Jun; Huai Xiulan; Chen Fei

2015-01-01

The multi-parameter optimization of the liquid LBE-helium heat exchanger in ADS was conducted by genetic algorithm with entransy dissipation number and total cost as objective functions. The results show that the effectiveness of heat exchanger increases by 10.5% and 3.8%, and the total cost-reduces by 5.9% and 27.0% respectively with two optimization methods. Nevertheless, the optimization processes trade off increasing heat transfer area and decreasing heat transfer effectiveness respectively against achieving optimization targets. By comprehensively considering heat exchanger performance and cost-benefit, the optimization method with entransy dissipation number as the objective function is found to be more advantageous. (authors)

77 FR 16304 - Self-Regulatory Organizations; International Securities Exchange, LLC; Notice of Filing and...

Science.gov (United States)

2012-03-20

... pricing that reduces rates for ISE Market Makers based on the level of business they bring to the Exchange.\\15\\ This proposed rule change targets a particular segment in which the Exchange seeks to attract... specific FX Options which has its own pricing. See ISE Schedule of Fees. \\15\\ The Exchange currently has a...

Low-field susceptibility of classical Heisenberg chains with arbitrary and different nearest-neighbour exchange

International Nuclear Information System (INIS)

Cregg, P J; Murphy, K; Garcia-Palacios, J L; Svedlindh, P

2008-01-01

Interest in molecular magnets continues to grow, offering a link between the atomic and nanoscale properties. The classical Heisenberg model has been effective in modelling exchange interactions in such systems. In this, the magnetization and susceptibility are calculated through the partition function, where the Hamiltonian contains both Zeeman and exchange energy. For an ensemble of N spins, this requires integrals in 2N dimensions. For two, three and four spin nearest-neighbour chains these integrals reduce to sums of known functions. For the case of the three and four spin chains, the sums are equivalent to results of Joyce. Expanding these sums, the effect of the exchange on the linear susceptibility appears as Langevin functions with exchange term arguments. These expressions are generalized here to describe an N spin nearest-neighbour chain, where the exchange between each pair of nearest neighbours is different and arbitrary. For a common exchange constant, this reduces to the result of Fisher. The high-temperature expansion of the Langevin functions for the different exchange constants leads to agreement with the appropriate high-temperature quantum formula of Schmidt et al, when the spin number is large. Simulations are presented for open linear chains of three, four and five spins with up to four different exchange constants, illustrating how the exchange constants can be retrieved successfully

Temperature response functions (G-functions) for single pile heat exchangers

International Nuclear Information System (INIS)

Loveridge, Fleur; Powrie, William

2013-01-01

Foundation piles used as heat exchangers as part of a ground energy system have the potential to reduce energy use and carbon dioxide emissions from new buildings. However, current design approaches for pile heat exchangers are based on methods developed for boreholes which have a different geometry, with a much larger aspect (length to diameter) ratio. Current methods also neglect the transient behaviour of the pile concrete, instead assuming a steady state resistance for design purposes. As piles have a much larger volume of concrete than boreholes, this neglects the significant potential for heat storage within the pile. To overcome these shortcomings this paper presents new pile temperature response functions (G-functions) which are designed to reflect typical geometries of pile heat exchangers and include the transient response of the pile concrete. Owing to the larger number of pile sizes and pipe configurations which are possible with pile heat exchangers it is not feasible to developed a single unified G-function and instead upper and lower bound solutions are provided for different aspects ratios. - Highlights: • We present new temperature response functions for pile heat exchangers. • The functions include transient heat transfer within the pile concrete. • Application of the functions reduces the resulting calculated temperature ranges. • Greater energy efficiency is possible by accounting for heat storage in the pile

Analysis of Intergranular Precipitation in Isothermally Aged Nitrogen-Containing Austenitic Stainless Steels by an Electrochemical Method and Its Relation to Cryogenic Toughness

Directory of Open Access Journals (Sweden)

Maribel L. Saucedo-Muñoz

2011-01-01

Full Text Available The precipitation process in two N-containing austenitic stainless steels, aged at temperatures between 873 and 1173 K for times from 10 to 1000 min, was analyzed by an electrochemical method based on the anodic polarization test with an electrolyte of 1 N KOH solution. The anodic polarization curves showed the following intergranular precipitation sequence: austenite → austenite + Cr23C6→ austenite + Cr23C6 + Cr2N. Besides, the fastest precipitation kinetics was detected in the aged steel with the highest content of nitrogen and carbon due to its higher driving force for precipitation. The higher the aging temperature, the higher volume fraction of precipitates. The precipitation fraction can be associated with the current density of the dissolution peaks of each phase. The Charpy-V-Notch impact energy of the aged specimens decreased with the increase in the volume fraction of precipitates.

Molecular dynamics simulations of the atomistic structure of the intergranular film between silicon nitride grains: Effect of composition, thickness, and surface vacancies

International Nuclear Information System (INIS)

Garofalini, Stephen H.

2006-01-01

Molecular dynamics computer simulations were used to study the atomistic structure of intergranular films (IGFs) between two basal oriented Si 3 N 4 crystals or between combined basal and prism oriented crystals. Ordering of the ions into the IGF induced by the crystal surfaces was observed using density profiles of the ions, although that ordering is effected by the roughness of the crystal surface. Density profiles of the sum of all ions misleadingly shows a rapid decay in the density oscillations and apparent ordering into the IGF. However, this is an artifact of the coincidence of the maximum in the peaks of one species with the minimum of another species and the actual oscillations of individual species extend into the IGF farther than the sum profile indicates. This result would have important implications regarding the density oscillations observed in physical experiments with regard to the actual extent of ordering into the IGF induced by the crystal surface

E-Commerce and Exchange Rate Exposure Management

DEFF Research Database (Denmark)

Aabo, Tom

2001-01-01

The aim of this paper is to address the impact of E-commerce on the balance between real hedging and financial hedging in the context of exchange rate exposure management in non-financial companies. A cross-case study of industrial companies highlights the inadequacy in taking a partial and static...... financial approach when managing exchange rate exposures. The paper argues that the emergence of E-commerce - by reducing the cost of obtaining, analyzing and allocating information - affects the dynamics of the markets and the dynamics of the company in such a way that a general tilt towards real hedging...

On-line fouling monitor for heat exchangers

International Nuclear Information System (INIS)

Tsou, J.L.

1995-01-01

Biological and/or chemical fouling in utility service water system heat exchangers adversely affects operation and maintenance costs, and reduced heat transfer capability can force a power deaerating or even a plant shut down. In addition, service water heat exchanger performance is a safety issue for nuclear power plants, and the issue was highlighted by NRC in Generic Letter 89-13. Heat transfer losses due to fouling are difficult to measure and, usually, quantitative assessment of the impact of fouling is impossible. Plant operators typically measure inlet and outlet water temperatures and flow rates and then perform complex calculations for heat exchanger fouling resistance or ''cleanliness''. These direct estimates are often imprecise due to inadequate instrumentation. Electric Power Research Institute developed and patented an on-line condenser fouling monitor. This monitor may be installed in any location within the condenser; does not interfere with routine plant operations, including on-line mechanical and chemical treatment methods; and provides continuous, real-time readings of the heat transfer efficiency of the instrumented tube. This instrument can be modified to perform on-line monitoring of service water heat exchangers. This paper discusses the design, construction of the new monitor, and algorithm used to calculate service water heat exchanger fouling

System for processing ion exchange resin regeneration waste liquid in atomic power plant

International Nuclear Information System (INIS)

Onaka, Noriyuki; Tanno, Kazuo; Shoji, Saburo.

1976-01-01

Object: To reduce the quantity of radioactive waste to be solidified by recovering and repeatedly using sulfuric acid and sodium hydroxide which constitute the ion exchange resin regeneration waste liquid. Structure: Cation exchange resin regeneration waste liquid is supplied to an anion exchange film electrolytic dialyzer for recovering sulfuric acid through separation from impurity cations, while at the same time anion exchange resin regeneration waste liquid is supplied to a cation exchange film electrolytic dialyzer for recovering sodium hydroxide through separation from impurity anions. The sulfuric acid and sodium hydroxide thus recovered are condensed by a thermal condenser and then, after density adjustment, repeatedly used for the regeneration of the ion exchange resin. (Aizawa, K.)

Foreign exchange intervention and central bank independence: The Latin American experience

OpenAIRE

Nunes, Mauricio; Da Silva, Sergio

2007-01-01

Employing data from 13 Latin American countries, we find that greater central bank independence is associated with lesser intervention in the foreign exchange market, and also with leaning-against-the-wind intervention. We also find that the structural reforms that occurred in Latin America mostly in the 1990s helped to reduce the need for foreign exchange intervention.

Automated exchange transfusion and exchange rate.

Science.gov (United States)

Funato, M; Shimada, S; Tamai, H; Taki, H; Yoshioka, Y

1989-10-01

An automated blood exchange transfusion (BET) with a two-site technique has been devised by Goldmann et al and by us, using an infusion pump. With this method, we successfully performed exchange transfusions 189 times in the past four years on 110 infants with birth weights ranging from 530 g to 4,000 g. The exchange rate by the automated method was compared with the rate by Diamond's method. Serum bilirubin (SB) levels before and after BET and the maximal SB rebound within 24 hours after BET were: 21.6 +/- 2.4, 11.5 +/- 2.2, and 15.0 +/- 1.5 mg/dl in the automated method, and 22.0 +/- 2.9, 11.2 +/- 2.5, and 17.7 +/- 3.2 mg/dl in Diamond's method, respectively. The result showed that the maximal rebound of the SB level within 24 hours after BET was significantly lower in the automated method than in Diamond's method (p less than 0.01), though SB levels before and after BET were not significantly different between the two methods. The exchange rate was also measured by means of staining the fetal red cells (F cells) both in the automated method and in Diamond's method, and comparing them. The exchange rate of F cells in Diamond's method went down along the theoretical exchange curve proposed by Diamond, while the rate in the automated method was significantly better than in Diamond's, especially in the early stage of BET (p less than 0.01). We believe that the use of this automated method may give better results than Diamond's method in the rate of exchange, because this method is performed with a two-site technique using a peripheral artery and vein.

[Effect of leader-member exchange on nurses'sense of calling in workplace].

Science.gov (United States)

Zhang, L G; Ma, H L; Wang, Z J; Zhou, Y Y; Jin, T T

2017-12-20

Objective: To investigate the effect of leader-member exchange on nurses'sense of calling in workplace based on self-determination theory. Methods: A total of 381 nurses were randomly selected from five tertiary general hospitals in Zhejiang province, China from October to December, 2016. They were subjected to a survey using the Leader-Member Exchange Scale, Job Autonomy Scale, Core Self-Evaluation Scale, and Calling Scale. The mediating effect was used to test the procedures and the data were subjected to hierarchical regression analysis. Results: The leader-member exchange was positively correlated with job autonomy, core self-evaluation, and sense of calling ( r =0.471, P exchange had a positive predictive effect on job autonomy and sense of calling ( β = 0.47, P exchange and sense of calling ( F =66.50, P exchange and job autonomy ( F =27.81, P exchange enhances the sense of calling by improving staffs' job autonomy and the core self-evaluation reduces the positive relationship between leader-member exchange and job autonomy.

Exchanging a few commercial, regularly consumed food items with improved fat quality reduces total cholesterol and LDL-cholesterol: a double-blind, randomised controlled trial.

Science.gov (United States)

Ulven, Stine M; Leder, Lena; Elind, Elisabeth; Ottestad, Inger; Christensen, Jacob J; Telle-Hansen, Vibeke H; Skjetne, Anne J; Raael, Ellen; Sheikh, Navida A; Holck, Marianne; Torvik, Kristin; Lamglait, Amandine; Thyholt, Kari; Byfuglien, Marte G; Granlund, Linda; Andersen, Lene F; Holven, Kirsten B

2016-10-01

The healthy Nordic diet has been previously shown to have health beneficial effects among subjects at risk of CVD. However, the extent of food changes needed to achieve these effects is less explored. The aim of the present study was to investigate the effects of exchanging a few commercially available, regularly consumed key food items (e.g. spread on bread, fat for cooking, cheese, bread and cereals) with improved fat quality on total cholesterol, LDL-cholesterol and inflammatory markers in a double-blind randomised, controlled trial. In total, 115 moderately hypercholesterolaemic, non-statin-treated adults (25-70 years) were randomly assigned to an experimental diet group (Ex-diet group) or control diet group (C-diet group) for 8 weeks with commercially available food items with different fatty acid composition (replacing SFA with mostly n-6 PUFA). In the Ex-diet group, serum total cholesterol (PLDL-cholesterol (Pcholesterol and LDL-cholesterol, respectively. No difference in change in plasma levels of inflammatory markers (high-sensitive C-reactive protein, IL-6, soluble TNF receptor 1 and interferon-γ) was observed between the groups. In conclusion, exchanging a few regularly consumed food items with improved fat quality reduces total cholesterol, with no negative effect on levels of inflammatory markers. This shows that an exchange of a few commercially available food items was easy and manageable and led to clinically relevant cholesterol reduction, potentially affecting future CVD risk.

System for exchanging tools and end effectors on a robot

International Nuclear Information System (INIS)

Burry, D.B.; Williams, P.M.

1991-01-01

A system and method for exchanging tools and end effectors on a robot permits exchange during a programmed task. The exchange mechanism is located off the robot, thus reducing the mass of the robot arm and permitting smaller robots to perform designated tasks. A simple spring/collet mechanism mounted on the robot is used which permits the engagement and disengagement of the tool or end effector without the need for a rotational orientation of the tool to the end effector/collet interface. As the tool changing system is not located on the robot arm no umbilical cords are located on robot. 12 figures

Copper metal foam as an essential construction element of innovative heat exchanger

Directory of Open Access Journals (Sweden)

R. Rybár

2016-07-01

Full Text Available Paper deals with creation of the innovative heat exchanger - manifold header for the heat pipe evacuated tube solar collector, which essential functional element is heat exchange chamber made of the copper metal foam. Design of the heat exchanger is based on effective utilization of the unique properties of the metal foam which makes it possible to design highly effective and space saving devices. Inner volume of heat exchanger was reducing from 0,00045 m3 to 0,000135 m3 and heat exchange surface was increase from 0,0104 m2 to 0,1403 m2 at proposed prototype, what drastically increase heat exchange efficiency. The proposal itself is based on the unique physical properties of the metal foam, which was described by computational analysis.

Heat exchanger

International Nuclear Information System (INIS)

Dostatni, A.W.; Dostatni, Michel.

1976-01-01

In the main patent, a description was given of a heat exchanger with an exchange surface in preformed sheet metal designed for the high pressure and temperature service particularly encountered in nuclear pressurized water reactors and which is characterised by the fact that it is composed of at least one exchanger bundle sealed in a containment, the said bundle or bundles being composed of numerous juxtaposed individual compartments whose exchange faces are built of preformed sheet metal. The present addendun certificate concerns shapes of bundles and their positioning methods in the exchanger containment enabling its compactness to be increased [fr

The electrochemistry of IGSCC mitigation

International Nuclear Information System (INIS)

Macdonald, D.D.

2002-01-01

A brief review is presented of the electrochemical mitigation of intergranular stress corrosion cracking (IGSCC) in watercooled reactor heat transport circuit structural materials. Electrochemical control and mitigation is possible because of the existence of a critical potential for intergranular stress corrosion cracking and due to the feasibility of modifying the environment to displace the corrosion potential to a value that is more negative than the critical value. However, even in cases where the corrosion potential cannot be displaced sufficiently in the negative direction to become more negative than the critical potential, considerable advantage is accrued, because of the roughly exponential dependence of the crack growth rate on potential. The most important parameters in affecting electrochemical control over the corrosion potential and crack growth rate are the kinetic parameters (exchange current densities and Tafel constants) for the redox reactions involving the principal radiolysis products of water (O 2 , H 2 H 2 O 2 ), external solution composition (concentrations of O 2 , H 2 O 2 , and H 2 ), flow velocity, and the conductivity of the bulk environment. The kinetic parameters for the redox reactions essentially determine the charge transfer impedance of the steel surface, which is shown to be one of the key parameters in affecting the magnitude of the coupling current and hence the crack growth rate. The exchange current densities, in particular, are amenable to control by catalysis or inhibition, with the result that surface modification techniques are highly effective in controlling and mitigating intergranular stress corrosion cracking in reactor coolant circuit materials. (orig.)

Influence of cooling and annealing procedure on the intergranular coupling of Ag-Bi[sub 2]Sr[sub 2]CaCu[sub 2]O[sub x] screen-printed tape. [BiSrCaCuO

Energy Technology Data Exchange (ETDEWEB)

Noji, H; Zhou, W [IRC in Superconductivity, Univ. of Cambridge (United Kingdom); Glowacki, B A [IRC in Superconductivity, Univ. of Cambridge (United Kingdom) Dept. of Materials Science and Metallurgy, Univ. of Cambridge (United Kingdom); Oota, A [IRC in Superconductivity, Univ. of Cambridge (United Kingdom) Dept. of Electric and Electronic Engineering, Toyohashi Univ. of Tech. (Japan)

1993-02-01

A study of the influence of the processing conditions of screen-printed ''Bi-2212'' tapes on their intergranular coupling properties, measured by AC susceptibility and DC transport critical current density, has been conducted. Samples have been prepared by melt-solidification and sintering on silver substrates under the same conditions but with different cooling procedures, such as slow cooling, slow cooling and reannealing, rapid cooling and quenching. The cooling rate and the annealing procedure strongly affect not only the superconducting critical temperature, Tc, but also the intergranular coupling properties of the samples. It was found that the Tc value decreases with a decrease in cooling rate. The reannealing in N[sub 2] can improve the Tc value of the slow-cooled samples. The different cooling procedures lead to the crossover of the field dependence of the AC loss-peak temperature of [chi]'' characteristics for all investigated samples. The crossover phenomena do not alter the correlation between the transport critical current density, J[sub c], versus temperature and the AC loss-peak temperature versus AC applied field for the samples in the range of the LN[sub 2] temperature (90-65 K), except for the slow-cooled one. The lack of correlation for the slow-cooled sample in this temperature range can be explained by a very significant difference of flux creep between the slow-cooled sample and the rest of the fast-cooled or reannealed samples. (orig.).

Intergranular corrosion in AA5XXX aluminum alloys with discontinuous precipitation at the grain boundaries

Science.gov (United States)

Bumiller, Elissa

The US Navy currently uses AA5xxx aluminum alloys for structures exposed to a marine environment. These alloys demonstrate excellent corrosion resistance over other aluminum alloys (e.g., AA2xxx or AA7xxx) in this environment, filling a niche in the marine structures market when requiring a light-weight alternative to steel. However, these alloys are susceptible to localized corrosion; more specifically, intergranular corrosion (IGC) is of concern. IGC of AA5xxx alloys due to the precipitation of beta phase on the grain boundaries is a well-established phenomenon referred to as sensitization. At high degrees of sensitization, the IGC path is a continuous anodic path of beta phase particles. At lower degrees of sensitization, the beta phase coverage at the grain boundaries is not continuous. The traditional ranges of susceptibility to IGC as defined by ASTM B928 are in question due to recent studies. These studies showed that even at mid range degrees of sensitization where the beta phase is no longer continuous, IGC may still occur. Previous thoughts on IGC of these alloy systems were founded on the idea that once the grain boundary precipitate became discontinuous the susceptibility to IGC was greatly reduced. Additionally, IGC susceptibility has been defined metallurgically by compositional gradients at the grain boundaries. However, AA5xxx alloys show no compositional gradients at the grain boundaries, yet are still susceptible to IGC. The goal of this work is to establish criteria necessary for IGC to occur given no continuous beta phase path and no compositional gradient at the grain boundaries. IGC performance of the bulk alloy system AA5083 has been studied along with the primary phases present in the IGC system: alpha and beta phases using electrochemistry and modeling as the primary tools. Numerical modeling supports that at steady-state the fissure tip is likely saturated with Mg in excess of the 4% dissolved in the matrix. By combining these results

An investigation on the effects of conservatism on reducing risk of stock market investment: A case study of Tehran Stock Exchange

Directory of Open Access Journals (Sweden)

Rezvan Hejazi

2013-07-01

Full Text Available Accounting conservatism limits managerial incentive and ability to overstate performance and hide bad news from investors, which, in turn, reduces stock price crash risk. This study examines relationship between conservatism on financial reports and risk of stock price crash. Using a sample of 54 listed firms in Tehran Stock Exchange over the period of 2006–2010 and panel logistic regression, we examine different hypotheses. The results indicate that accounting conservatism, as measured by Khan and Watts (2009 CSCORE [Khan, M., & Watts, R. L. (2009. Estimation and empirical properties of a firm-year measure of accounting conservatism. Journal of Accounting and Economics, 48(2, 132-150.], reduces the likelihood of a firm experiencing stock price crashes. The finding holds after controlling other variables such as: negative skewness of firm-specific-weekly return, standard deviation of firm-specific-weekly return, the mean of firm-specific-weekly return, detrend share turnover, size, market to book value of equity ratio, total debt ratio and return on asset ratio, but we did not observe any relationship between these variables during stock price crash.

The impact of ion exchange media and filters on LLW processing

International Nuclear Information System (INIS)

James, K.L.; Miller, C.C.

1992-01-01

Optimized ion exchange media at Diablo Canyon have steadily improved the treatment of radioactive liquid waste. The activity released to the environment has been reduced while simultaneously reducing the volume of solid radwaste generated from processing radioactive liquids. This has lowered the liquid waste processing costs and reduced the number of radioactive shipments from the plant. A cobalt treatment technique was identified and successfully implemented prior to reactor coolant chemistry alteration. A cesium treatment using zeolite has been successfully implemented. A cobalt removal treatment, combining series cation ion exchange with submicron filtration, has successfully removed cobalt after reactor coolant chemistry alteration. A new carbon-based material will be monitored to find a media to remove cobalt from high-conductivity liquids. (author)

High-performance ion-exchange chromatography of alkali metals with conductivity detection

International Nuclear Information System (INIS)

Ahmad, M.; Khan, A.R.

1981-01-01

High-performance ion-exchange chromatography of alkali metal and ammonium ions was studied using a conductivity meter as detector. Elution with 0.003 N mitric acid gave excellent resolution. Sensitivity levels, for a 200 micro litre injection, vary from 5 ppm for potassium to 0.1 ppm for lithium. A method to decrease retention times by reducing the exchange capacity of the cation exchange column used by loading it with calciumions, without affecting the resolation, has been described. Application of the method to water, soil and uranium dioxide samples has been demonstrated. (author)

Manufacture of heat exchangers

International Nuclear Information System (INIS)

Burton, J.E.; Tombs, R.W.T.

1980-01-01

A tube bundle for use in a heat exchanger has a series of spaced parallel tubes supported by tube plates and is manufactured by depositing welding material around the end of each tube, machining the deposited material to form an annular flange around the end of the tube and welding the flange into apertures in the tube plate. Preferably the tubes have a length which is slightly less than the distance between the outer surfaces of the tube plates and the deposited material is deposited so that it overlaps and protects the end surfaces of the tubes. A plug may be inserted in the bore of the tubes during the welding material deposition which, as described, is effected by manual metal arc welding. One use of heat exchangers incorporating a tube bundle manufactured as above is in apparatus for reducing the volume of, and recovering nitric acid from, radioactive effluents from a nuclear reprocessing plant. (author)

Cointegration and Causality Test Among Export, Import, and Foreign Exchange

Directory of Open Access Journals (Sweden)

Haryono Subiyakto

2016-06-01

Full Text Available The rupiah exchange rate, import, and export are the important indicators in economy, including the Indonesia economy. The debate regarding the relationship among the exchange rate, import, and export has been persisting for several decades. Some researchers found that there is a relationship among those three and others explained that there is no correlation among them. The aim of this research is to obtain the empirical evidence of the causal relationship among the export, import, and foreign exchange rate by using the monthly data from January 2010 to April 2014. The export and import data are the export and import values in US dollar. The exchange rate data is the median exchange rates of the Indonesian Bank. The Johansen Cointegration Test and the Granger Causality Test are used to analyze the data. The research result shows that export and import have no causal relationship at five percent. Next, the foreign exchange rate influences the export and import at 10 percent level. The result indicates that the foreign exchange rate has small effects on the export and import. Based on the results, the government should control the balance of trade and should not make any policy that is based on the exchange rate values. Finally, it can be said that the exchange rate policy is not effective in increasing the exports and reducing the imports.

Device for processing regenerative wastes of ion exchange resin

International Nuclear Information System (INIS)

Kuroda, Osamu; Ebara, Katsuya; Shindo, Toshikazu; Takahashi, Sankichi

1986-01-01

Purpose: To facilitate the operation and maintenance of a processing device by dividing radioactive wastes produced in the regenerative process of ion exchange resin into a regenerated usable recovery liquid and wastes. Constitution: Sulfuric acid is recovered by a diffusion dialysis method from wastes containing sulfuric acid that are generated in the regenerative process of cation-exchange resin and also caustic soda is recovered by the diffusion dialysis method from wastes containing caustic soda that are generated in the regenerative process of anion-exchange resin. The sulfuric acid and caustic soda thus recovered are used for the regeneration of ion-exchange resin. A concentrator is provided for concentrating the sulfuric acid and caustic soda water solution to concentration suitable for the regeneration of these ion-exchange resins. Also provided is a recovery device for recovering water generated from the concentrator. This device is of so simple a constitution that its operation and maintenance can be performed very easily, thereby greatly reducing the quantity of waste liquid required to be stored in drums. (Takahashi, M.)

An Empirical Assessment of the Real Exchange Rate and Poverty in Nigeria

OpenAIRE

Ben. U. Omojimite; Victor E. Oriavwote

2012-01-01

This paper investigated the influence of the real exchange rate on poverty within the framework of a dependent economy model. Using data covering 1980 to 2010, the result of a Vector Error Correction model (VECM) showed that the volatility of the real exchange rate has significant influence on the level of poverty in Nigeria. Thus, government policies that targets real exchange rate could play significant role in reducing the level of poverty in Nigeria, particularly if supported by basic ins...

Impact of exchange rate depreciation on the balance of payments: Empirical evidence from Nigeria

Directory of Open Access Journals (Sweden)

Martins Iyoboyi

2014-12-01

Full Text Available The paper investigates the impact of exchange rate depreciation on the balance of payments (BOP in Nigeria over the period 1961–2012. The analysis is based on a multivariate vector error correction framework. A long-term equilibrium relationship was found between BOP, exchange rate and other associated variables. The empirical results are in favour of bidirectional causality between BOP and other variables employed. Results of the generalized impulse response functions suggest that one standard deviation innovation on exchange rate reduces positive BOP in the medium and long term, while results of the variance decomposition indicate that a significant variation in Nigeria’s BOP is not due to changes in exchange rate movements. The policy implication is that exchange rate depreciation which has been preponderant in Nigeria since the mid-1980s has not been very useful in promoting the country’s positive BOP. It is recommended that growth in the real sector should be improved to enhance exports, create employment, curb inflation and reduce poverty, while cutting non-productive imports, attracting foreign private investment and implementing well coordinated macroeconomic policies that impact inflation positively and stimulate exchange rate stability.

Financial Performance of Health Insurers: State-Run Versus Federal-Run Exchanges.

Science.gov (United States)

Hall, Mark A; McCue, Michael J; Palazzolo, Jennifer R

2018-06-01

Many insurers incurred financial losses in individual markets for health insurance during 2014, the first year of Affordable Care Act mandated changes. This analysis looks at key financial ratios of insurers to compare profitability in 2014 and 2013, identify factors driving financial performance, and contrast the financial performance of health insurers operating in state-run exchanges versus the federal exchange. Overall, the median loss of sampled insurers was -3.9%, no greater than their loss in 2013. Reduced administrative costs offset increases in medical losses. Insurers performed better in states with state-run exchanges than insurers in states using the federal exchange in 2014. Medical loss ratios are the underlying driver more than administrative costs in the difference in performance between states with federal versus state-run exchanges. Policy makers looking to improve the financial performance of the individual market should focus on features that differentiate the markets associated with state-run versus federal exchanges.

Supervision of the thermal performance of heat exchanger trains

Energy Technology Data Exchange (ETDEWEB)

Negrao, C.O.R.; Tonin, P.C.; Madi, M. [Federal University of Technology Parana UTFPR, Post-graduate Program in Mechanical and Materials Engineering PPGEM, Thermal Science Laboratory LACIT, Av. Sete de Setembro, 3165, CEP 80230-901, Curitiba, Parana (Brazil)

2007-02-15

In oil refining, heat exchanger networks are employed to recover heat and therefore save energy of the plant. However, many heat exchangers in crude oil pre-heat trains are under high risk of fouling. Under fouling conditions, the thermal performance of heat exchangers is continuously reduced and its supervision becomes an important task. The large number of heat exchangers in pre-heat trains and the change of operation conditions and feedstock charges make the daily supervision a difficult task. This work applies an approach to follow the performance of heat exchangers [M.A.S. Jeronimo, L.F. Melo, A.S. Braga, P.J.B.F. Ferreira, C. Martins, Monitoring the thermal efficiency of fouled heat exchangers - A simplified method, Experimental Thermal and Fluid Science 14 (1997) 455-463] and extends it to monitor the whole train. The approach is based on the comparison of measured and predicted heat exchanger effectiveness. The measured value is computed from the four inlet and outlet temperatures of a heat exchanger unit. The predicted clean and dirty values of effectiveness are calculated from classical literature relations as a function of NTU and of heat capacity ratio (R). NTU and R are continuously adjusted according to mass flow rate changes. An index of fouling is defined for the whole network and the results show the performance degradation of the network with time. The work also suggests that Jeronimo's index of fouling can be used to estimate the fouling thermal resistance of heat exchangers. (author)

Contribution of solution pH and buffer capacity to suppress intergranular stress corrosion cracking of sensitized type 304 stainless steel at 95 C

International Nuclear Information System (INIS)

Zhang, S.; Shibata, T.; Haruna, T.

1999-01-01

Controlling pH of high-temperature water to ∼pH 7 at 300 C by adding lithium hydroxide (LiOH) into the coolant system of a pressurized water reactor (PWR) successfully has been mitigating the corrosion of PWR component materials. The effects of solution pH and buffer capacity on intergranular stress corrosion cracking (IGSCC) of sensitized type 304 stainless steel ([SS] UNS S30400) was examined at 95 C by slow strain rate technique (SSRT) with an in-situ cracking observation system. It was found that an increase in solution pH or buffer capacity increased crack initiation time and decreased mean crack initiation frequency, but exerted almost no effect on crack propagation. This inhibition effect on IGSCC initiation was explained as resulting from a retarding effect of solution pH and buffer capacity on the decrease in pH at crack nuclei caused by the hydrolysis of metal ions dissolved when the passive film was ruptured by strain in SSRT

Magnetoresistance of nanogranular Ni/NiO controlled by exchange anisotropy

International Nuclear Information System (INIS)

Del Bianco, L.; Spizzo, F.; Tamisari, M.; Allia, P.

2013-01-01

A link between exchange anisotropy and magnetoresistance has been found to occur in a Ni/NiO sample consisting of Ni nanocrystallites (mean size ∼13 nm, Ni content ∼33 vol%) dispersed in a NiO matrix. This material shows metallic-type electric conduction and isotropic spin-dependent magnetoresistance as well as exchange bias effect. The latter is the outcome of an exchange anisotropy arising from the contact interaction between the Ni phase and the NiO matrix. Combined analysis of magnetization M(H) and magnetoresistance MR(H) loops measured in the 5–250 K temperature range after zero-field-cooling (ZFC) and after field-cooling (FC) from 300 K reveals that the magnetoresistance is influenced by exchange anisotropy, which is triggered by the FC process and can be modified in strength by varying the temperature. Compared to the ZFC case, the exchange anisotropy produces a horizontal shift of the FC MR(H) loop along with a reduction of the MR response associated to the reorientation of the Ni moments. A strict connection between magnetoresistance and remanent magnetization of FC loops on one side and the exchange field on the other, ruled by exchange anisotropy, is indicated. - Highlights: • Nanogranular Ni/NiO with giant magnetoresistance (MR) and exchange bias effect. • Exchange anisotropy produces a shift of the field-cooled MR(H) loop and reduces MR. • MR, remanence of field-cooled loops and exchange field are three correlated quantities. • It is possible to control MR of nanogranular systems through the exchange anisotropy

Ion exchange equilibrium constants

CERN Document Server

Marcus, Y

2013-01-01

Ion Exchange Equilibrium Constants focuses on the test-compilation of equilibrium constants for ion exchange reactions. The book first underscores the scope of the compilation, equilibrium constants, symbols used, and arrangement of the table. The manuscript then presents the table of equilibrium constants, including polystyrene sulfonate cation exchanger, polyacrylate cation exchanger, polymethacrylate cation exchanger, polysterene phosphate cation exchanger, and zirconium phosphate cation exchanger. The text highlights zirconium oxide anion exchanger, zeolite type 13Y cation exchanger, and

Mark-18A Ion Exchange Raffinate Management Strategy & Processing Recommendations

Energy Technology Data Exchange (ETDEWEB)

Smith, T. E. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Nash, C. A. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2017-06-21

It is desired to recover Cm-244 through Cm-248 from dissolved Mark-18A targets following anion exchange processing to remove the Pu. The Cm will be sent to Oak Ridge National Laboratory (ORNL) for additional R&D. Approximately 5-8 L per quarter of a Mark-18A target will have undergone anion exchange treatment and will contain Cm. A significant portion of this volume of anion exchange raffinate solution is dissolved fission products not desired to be recovered which could be sent to waste. To reduce the amount of material being sent to ORNL, a waste and volume minimization strategy was developed and is described in this report.

The study of development of welded compact plate heat exchanger for high temperature and pressure

International Nuclear Information System (INIS)

Park, Jae Hong; Lim, Hyug; Kim, Jung Kyu; Cho, Sung Youl; Kwon, Oh Boong

2009-01-01

In view of space saving, the design of more compact heat exchangers is relatively important. Also, to meet the demand for saving energy and resources today, manufacturers are trying to enhance efficiency and reduce the size and weight of heat exchangers. Over the past decade, there has been tremendous advancement in the manufacturing technology of high efficiency heat exchangers. This has allowed the use of smaller and high performance heat exchangers. Consequently, the use of smaller and high performance heat exchanger becomes popular in the design of heat exchangers. Welded compact plate heat exchanger is used in high temperature and pressure. In the design of heat exchanger, it is necessary to understand the heat transfer characteristics, so performance data are provided to help design of this type heat exchanger.

Impact of Annealing Prior to Solution Treatment on Aging Precipitates and Intergranular Corrosion Behavior of Al-Cu-Li Alloy 2050

Science.gov (United States)

Ye, Zhi-hao; Cai, Wen-xin; Li, Jin-feng; Chen, Xiang-rong; Zhang, Rui-feng; Birbilis, Nick; Chen, Yong-lai; Zhang, Xu-hu; Ma, Peng-cheng; Zheng, Zi-qiao

2018-04-01

The influences of annealing prior to solution treatment on the grain structure, subsequent aging precipitates, and intergranular corrosion (IGC) of Al-Cu-Li alloy (AA2050) sheet with T6 aging at 448 K (175 °C) were investigated. Annealing impedes the full recrystallization during solution treatment, increasing the population density of T1 (Al2CuLi) precipitates, but decreasing that of θ' (Al2Cu) precipitates, of the aged alloy. Meanwhile, annealing leads to the heterogeneous distribution of T1 precipitates, increasing the alloy hardness, and decreasing the open-circuit potential of the aged alloy. With prolonged aging time, the corrosion mode of the aged AA2050 samples with and without annealing evolved in a similar manner. The corrosion mode as a function of aging may be summarized as local IGC with pitting and general IGC with pitting (following initial aging and under the underaged condition), pitting corrosion (later in the under-aging stage), pitting with slight IGC (near the peak-aged condition), and pitting with local IGC (under the overaging condition). The annealing treatment hinders IGC propagation on the rolling surface while accelerating the IGC on transverse surfaces.

Reactive oxygen species production and discontinuous gas exchange in insects

OpenAIRE

Boardman, Leigh; Terblanche, John S.; Hetz, Stefan K.; Marais, Elrike; Chown, Steven L.

2011-01-01

While biochemical mechanisms are typically used by animals to reduce oxidative damage, insects are suspected to employ a higher organizational level, discontinuous gas exchange mechanism to do so. Using a combination of real-time, flow-through respirometry and live-cell fluorescence microscopy, we show that spiracular control associated with the discontinuous gas exchange cycle (DGC) in Samia cynthia pupae is related to reactive oxygen species (ROS). Hyperoxia fails to increase mean ROS produ...

Searching for long-range dependence in real effective exchange rate: towards parity?

Directory of Open Access Journals (Sweden)

André M. Marques

2015-12-01

Full Text Available Abstract After the widespread adoption of flexible exchange rate regime since 1973 the volatility of the exchange rate has increased, as a consequence of greater trade openness and financial integration. As a result, it has become difficult to find evidence of the purchasing power parity hypothesis (PPP. This study investigates the possibility of a fall in the persistence of the real exchange rate as a consequence of the financial and commercial integration by employing monthly real effective exchange rate dataset provided by the International Monetary Fund (IMF. Beginning with an exploratory data analysis in the frequency domain, the fractional coefficient d was estimated employing the bias-reduced estimator on a sample of 20 countries over the period ranging from 1975 to 2011. As the main novelty, this study applies a bias-reduced log-periodogram regression estimator instead of the traditional method proposed by GPH which eliminates the first and higher orders biases by a data-dependent plug-in method for selecting the number of frequencies to minimize asymptotic mean-squared error (MSE. Additionally, this study also estimates a moving window of fifteen years to observe the path of the fractional coefficient in each country. No evidence was found of a statistically significant change in the persistence of the real exchange rate.

Calculation of the Full Scattering Amplitude without Partial Wave Decomposition II: Inclusion of Exchange

Science.gov (United States)

Shertzer, Janine; Temkin, A.

2003-01-01

As is well known, the full scattering amplitude can be expressed as an integral involving the complete scattering wave function. We have shown that the integral can be simplified and used in a practical way. Initial application to electron-hydrogen scattering without exchange was highly successful. The Schrodinger equation (SE), which can be reduced to a 2d partial differential equation (pde), was solved using the finite element method. We have now included exchange by solving the resultant SE, in the static exchange approximation, which is reducible to a pair of coupled pde's. The resultant scattering amplitudes, both singlet and triplet, calculated as a function of energy are in excellent agreement with converged partial wave results.

Risk Based Inspection of Gas-Cooling Heat Exchanger

Directory of Open Access Journals (Sweden)

Dwi Priyanta

2017-09-01

Full Text Available On October 2013, Pertamina Hulu Energi Offshore North West Java (PHE – ONWJ platform personnel found 93 leaking tubes locations in the finfan coolers/ gas-cooling heat exchanger. After analysis had been performed, the crack in the tube strongly indicate that stress corrosion cracking was occurred by chloride. Chloride stress corrosion cracking (CLSCC is the cracking occurred by the combined influence of tensile stress and a corrosive environment. CLSCC is the one of the most common reasons why austenitic stainless steel pipework or tube and vessels deteriorate in the chemical processing, petrochemical industries and maritime industries. In this thesis purpose to determine the appropriate inspection planning for two main items (tubes and header box in the gas-cooling heat exchanger using risk based inspection (RBI method. The result, inspection of the tubes must be performed on July 6, 2024 and for the header box inspection must be performed on July 6, 2025. In the end, RBI method can be applicated to gas-cooling heat exchanger. Because, risk on the tubes can be reduced from 4.537 m2/year to 0.453 m2/year. And inspection planning for header box can be reduced from 4.528 m2/year to 0.563 m2/year.

Need for speed? Exchange latency and liquidity

NARCIS (Netherlands)

Menkveld, Albert J.; Zoican, Marius A.

2017-01-01

A faster exchange does not necessarily improve liquidity. On the one hand, speed enables a high-frequency market maker (HFM) to update quotes faster on incoming news. This reduces payoff risk and thus lowers the competitive bid-ask spread. On the other hand, HFM price quotes are more likely to meet

Automated Sample Exchange Robots for the Structural Biology Beam Lines at the Photon Factory

International Nuclear Information System (INIS)

Hiraki, Masahiko; Watanabe, Shokei; Yamada, Yusuke; Matsugaki, Naohiro; Igarashi, Noriyuki; Gaponov, Yurii; Wakatsuki, Soichi

2007-01-01

We are now developing automated sample exchange robots for high-throughput protein crystallographic experiments for onsite use at synchrotron beam lines. It is part of the fully automated robotics systems being developed at the Photon Factory, for the purposes of protein crystallization, monitoring crystal growth, harvesting and freezing crystals, mounting the crystals inside a hutch and for data collection. We have already installed the sample exchange robots based on the SSRL automated mounting system at our insertion device beam lines BL-5A and AR-NW12A at the Photon Factory. In order to reduce the time required for sample exchange further, a prototype of a double-tonged system was developed. As a result of preliminary experiments with double-tonged robots, the sample exchange time was successfully reduced from 70 seconds to 10 seconds with the exception of the time required for pre-cooling and warming up the tongs

Reversible brain inactivation induces discontinuous gas exchange in cockroaches.

Science.gov (United States)

Matthews, Philip G D; White, Craig R

2013-06-01

Many insects at rest breathe discontinuously, alternating between brief bouts of gas exchange and extended periods of breath-holding. The association between discontinuous gas exchange cycles (DGCs) and inactivity has long been recognised, leading to speculation that DGCs lie at one end of a continuum of gas exchange patterns, from continuous to discontinuous, linked to metabolic rate (MR). However, the neural hypothesis posits that it is the downregulation of brain activity and a change in the neural control of gas exchange, rather than low MR per se, which is responsible for the emergence of DGCs during inactivity. To test this, Nauphoeta cinerea cockroaches had their brains inactivated by applying a Peltier-chilled cold probe to the head. Once brain temperature fell to 8°C, cockroaches switched from a continuous to a discontinuous breathing pattern. Re-warming the brain abolished the DGC and re-established a continuous breathing pattern. Chilling the brain did not significantly reduce the cockroaches' MR and there was no association between the gas exchange pattern displayed by the insect and its MR. This demonstrates that DGCs can arise due to a decrease in brain activity and a change in the underlying regulation of gas exchange, and are not necessarily a simple consequence of low respiratory demand.

Control rod pattern exchange in a BWR/6 utilizing gang mode withdrawal

International Nuclear Information System (INIS)

Auvil, A.B. Jr.; Aldemir, T.; Hajek, B.K.

1986-01-01

The use of checkerboard pattern of alternating inserted and fully withdrawn control rods and the uneven void distribution in boiling water reactor (BWR) cores can cause large burnup gradients even after a short time of operation. To compensate for these effects, power has to be reshaped periodically (typically every two full-power months) by individually manipulating the control rods. During this manipulation process (called the control rod pattern exchange), the core power is reduced to 60% of nominal power by means of flow reduction to limit power swings to tolerable levels and to ensure that fuel thermal limits are not exceeded. A control rod pattern exchange by individual rod manipulation typically takes 4 to 8 h and represents a large cost burden to the utility in terms of reduced system output. The latest generation of BWRs, the BWR/6, possesses the capability to simultaneously move up to four symmetrically located control rods. The rods corresponding to a given gang may have rotational symmetry, mirror symmetry, or a combination of the two. This paper presents a pattern exchange procedure that exploits the capability of gang mode rod withdrawal to reduce the pattern exchange execution time and radial power distribution asymmetry associated with individual rod manipulation. The working model used in the study is the Perry Nuclear Power Plant Unit 1, located in Perry, Ohio, and owned by the Cleveland Electric Illuminating Company

Oxo-exchange of gas-phase uranyl, neptunyl, and plutonyl with water and methanol.

Science.gov (United States)

Lucena, Ana F; Odoh, Samuel O; Zhao, Jing; Marçalo, Joaquim; Schreckenbach, Georg; Gibson, John K

2014-02-17

A challenge in actinide chemistry is activation of the strong bonds in the actinyl ions, AnO2(+) and AnO2(2+), where An = U, Np, or Pu. Actinyl activation in oxo-exchange with water in solution is well established, but the exchange mechanisms are unknown. Gas-phase actinyl oxo-exchange is a means to probe these processes in detail for simple systems, which are amenable to computational modeling. Gas-phase exchange reactions of UO2(+), NpO2(+), PuO2(+), and UO2(2+) with water and methanol were studied by experiment and density functional theory (DFT); reported for the first time are experimental results for UO2(2+) and for methanol exchange, as well as exchange rate constants. Key findings are faster exchange of UO2(2+) versus UO2(+) and faster exchange with methanol versus water; faster exchange of UO2(+) versus PuO2(+) was quantified. Computed potential energy profiles (PEPs) are in accord with the observed kinetics, validating the utility of DFT to model these exchange processes. The seemingly enigmatic result of faster exchange for uranyl, which has the strongest oxo-bonds, may reflect reduced covalency in uranyl as compared with plutonyl.

Exchange Rate Regime and External Adjustment in CEE Countries

Directory of Open Access Journals (Sweden)

Jacek Pietrucha

2015-04-01

Full Text Available The paper reviews effects of exchange rate regime's choice for adjustments processes in current accounts (CA in the Central and Eastern Europe countries between 2008-2012. During the period of global financial crisis, Poland may be treated as a handbook example of the reaction of floating exchange rate to shock and adjustments in the form of expenditure switching. However, the Polish experience is not typical among the Central and Eastern Europe countries. There is no evidence for the positive role of floating exchange rate in macroeconomic adjustments after the crisis in Central and Eastern Europe countries which belong to EU. The adjustments in the countries with fixed regimes were fast and deep. The real exchange rate decreased and export, CA and goods and services balance improved, development distance against EU countries was reduced. However, the experience of Baltic countries, which have internal devaluation, should be very carefully conveyed to other countries.

Composite polymer membranes for proton exchange membrane fuel cells operating at elevated temperatures and reduced humidities

Science.gov (United States)

Zhang, Tao

Proton Exchange Membrane Fuel Cells (PEMFCs) are the leading candidate in the fuel cell technology due to the high power density, solid electrolyte, and low operational temperature. However, PEMFCs operating in the normal temperature range (60-80°C) face problems including poor carbon monoxide tolerance and heat rejection. The poisoning effect can be significantly relieved by operating the fuel cell at elevated temperature, which also improves the heat rejection and electrochemical kinetics. Low relative humidity (RH) operation is also desirable to simplify the reactant humidification system. However, at elevated temperatures, reduced RH PEMFC performance is seriously impaired due to irreversible water loss from presently employed state-of-the-art polymer membrane, Nafion. This thesis focuses on developing polymer electrolyte membranes with high water retention ability for operation in elevated temperature (110-150°C), reduced humidity (˜50%RH) PEMFCs. One approach is to alter Nafion by adding inorganic particles such as TiO2, SiO2, Zr(HPO 4)2, etc. While the presence of these materials in Nafion has proven beneficial, a reduction or no improvement in the PEMFC performance of Nafion/TiO2 and Nafion/Zr(HPO4)2 membranes is observed with reduced particle sizes or increased particle loadings in Nafion. It is concluded that the PEMFC performance enhancement associated with addition of these inorganic particles was not due to the particle hydrophilicity. Rather, the particle, partially located in the hydrophobic region of the membrane, benefits the cell performance by altering the membrane structure. Water transport properties of some Nafion composite membranes were investigated by NMR methods including pulsed field gradient spin echo diffusion, spin-lattice relaxation, and spectral measurements. Compared to unmodified Nafion, composite membranes materials exhibit longer longitudinal relaxation time constant T1. In addition to the Nafion material, sulfonated styrene

Thermo-hydraulic design of earth-air heat exchangers

Energy Technology Data Exchange (ETDEWEB)

Paepe, M. de [Ghent University (Belgium). Department of Flow, Heat and Combustion Mechanics; Janssens, A. [Ghent University (Belgium). Department of Architecture and Urbanism

2003-05-01

Earth-air heat exchangers, also called ground tube heat exchangers, are an interesting technique to reduce energy consumption in a building. They can cool or heat the ventilation air, using cold or heat accumulated in the soil. Several papers have been published in which a design method is described. Most of them are based on a discretisation of the one-dimensional heat transfer problem in the tube. Three-dimensional complex models, solving conduction and moisture transport in the soil are also found. These methods are of high complexity and often not ready for use by designers. In this paper, a one-dimensional analytical method is used to analyse the influence of the design parameters of the heat exchanger on the thermo-hydraulic performance. A relation is derived for the specific pressure drop, linking thermal effectiveness with pressure drop of the air inside the tube. The relation is used to formulate a design method which can be used to determine the characteristic dimensions of the earth-air heat exchanger in such a way that optimal thermal effectiveness is reached with acceptable pressure loss. The choice of the characteristic dimensions, becomes thus independent of the soil and climatological conditions. This allows designers to choose the earth-air heat exchanger configuration with the best performance. (author)

Thermo-hydraulic design of earth-air heat exchangers

Energy Technology Data Exchange (ETDEWEB)

De Paepe, M. [Department of Flow, Heat and Combustion Mechanics, Ghent University, Ghent (Belgium); Janssens, A. [Department of Architecture and Urbanism, Ghent University, Ghent (Belgium)

2003-07-01

Earth-air heat exchangers, also called ground tube heat exchangers, are an interesting technique to reduce energy consumption in a building. They can cool or heat the ventilation air, using cold or heat accumulated in the soil. Several papers have been published in which a design method is described. Most of them are based on a discretisation of the one-dimensional heat transfer problem in the tube. Three-dimensional complex models, solving conduction and moisture transport in the soil are also found. These methods are of high complexity and often not ready for use by designers. In this paper, a one-dimensional analytical method is used to analyse the influence of the design parameters of the heat exchanger on the thermo-hydraulic performance. A relation is derived for the specific pressure drop, linking thermal effectiveness with pressure drop of the air inside the tube. The relation is used to formulate a design method which can be used to determine the characteristic dimensions of the earth-air heat exchanger in such a way that optimal thermal effectiveness is reached with acceptable pressure loss. The choice of the characteristic dimensions, becomes thus independent of the soil and climatological conditions. This allows designers to choose the earth-air heat exchanger configuration with the best performance. (author)

Nanomaterials-Enhanced Electrically Switched Ion Exchange Process for Water Treatment

International Nuclear Information System (INIS)

Lin, Yuehe; Choi, Daiwon; Wang, Jun; Bontha, Jagannadha R.

2009-01-01

The objective of our work is to develop an electrically switched ion exchange (ESIX) system based on conducting polymer/carbon nanotube (CNT) nanocomposites as a new and cost-effective approach for removal of radioactive cesium, chromate, and perchlorate from contaminated groundwater. The ESIX technology combines ion exchange and electrochemistry to provide a selective, reversible method for the removal of target species from wastewater. In this technique, an electroactive ion exchange layer is deposited on a conducting substrate, and ion uptake and elution are controlled directly by modulation of the potential of the layer. ESIX offers the advantages of highly-efficient use of electrical energy combined with no secondary waste generation. Recently, we have improved upon the ESIX process by modifying the conducting substrate with carbon nanotubes prior to the deposition of the electroactive ion exchanger. The nanomaterial-based electroactive ion exchange technology will remove cesium-137, chromate, and perchlorate rapidly from wastewater. The high porosity and high surface area of the electroactive ion exchange nanocomposites results in high loading capacity and minimize interferences for non-target species. Since the ion adsorption/desorption is controlled electrically without generating a secondary waste, this electrically active ion exchange process is a green process technology that will greatly reduce operating costs

Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers

Energy Technology Data Exchange (ETDEWEB)

Edward Levy; Harun Bilirgen; John DuPoint

2011-03-31

Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: (1) An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing high-moisture, low rank coals. (2) Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. (3) Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. (4) Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. (5) Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. (6) Condensed flue gas water treatment needs and costs. (7) Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. (8) Results of cost-benefit studies of condensing heat exchangers.

Recovery of Water from Boiler Flue Gas Using Condensing Heat Exchangers

Energy Technology Data Exchange (ETDEWEB)

Levy, Edward; Bilirgen, Harun; DuPont, John

2011-03-31

Most of the water used in a thermoelectric power plant is used for cooling, and DOE has been focusing on possible techniques to reduce the amount of fresh water needed for cooling. DOE has also been placing emphasis on recovery of usable water from sources not generally considered, such as mine water, water produced from oil and gas extraction, and water contained in boiler flue gas. This report deals with development of condensing heat exchanger technology for recovering moisture from flue gas from coal-fired power plants. The report describes: • An expanded data base on water and acid condensation characteristics of condensing heat exchangers in coal-fired units. This data base was generated by performing slip stream tests at a power plant with high sulfur bituminous coal and a wet FGD scrubber and at a power plant firing highmoisture, low rank coals. • Data on typical concentrations of HCl, HNO{sub 3} and H{sub 2}SO{sub 4} in low temperature condensed flue gas moisture, and mercury capture efficiencies as functions of process conditions in power plant field tests. • Theoretical predictions for sulfuric acid concentrations on tube surfaces at temperatures above the water vapor dewpoint temperature and below the sulfuric acid dew point temperature. • Data on corrosion rates of candidate heat exchanger tube materials for the different regions of the heat exchanger system as functions of acid concentration and temperature. • Data on effectiveness of acid traps in reducing sulfuric acid concentrations in a heat exchanger tube bundle. • Condensed flue gas water treatment needs and costs. • Condensing heat exchanger designs and installed capital costs for full-scale applications, both for installation immediately downstream of an ESP or baghouse and for installation downstream of a wet SO{sub 2} scrubber. • Results of cost-benefit studies of condensing heat exchangers.

Progress of sintered NdFeB permanent magnets by the diffusion of non-rare earth elements and their alloy compounds

Directory of Open Access Journals (Sweden)

Lyu Meng

2017-12-01

Full Text Available It has been found that the coercivity (HC and corrosivity of sintered NdFeB magnets are closely related to the components and microstructure of their intergranular phase.The traditional smelting NdFeB magnets with adding heavy rare earth elements can modify intergranular phase to improve the HC and corrosion resistance of magnets.However,it makes the additives be homogenously distributed on the main phase,and causes magnetic decrease and cost increase.With the addition of non-rare earth materials into grain boundary,the microstructure of intergranular phase as well as its electrochemical potential and wettability can be optimized.As a result,the amount of heavy rare earth elements and cost of magnets could be reduced whilst the HC and corrosion resistance of magnets can be improved.This paper summarized the research on regulating the components and the microstructure of intergranular phase in sintered NdFeB magnets by non-rare earth metals and compounds,and its influence on coercivity and corrosion resistance.

Exchange market pressure

NARCIS (Netherlands)

Jager, H.; Klaassen, F.; Durlauf, S.N.; Blume, L.E.

2010-01-01

Currencies can be under severe pressure in the foreign exchange market, but in a fixed (or managed) exchange rate regime that is not fully visible via the change in the exchange rate. Exchange market pressure (EMP) is a concept developed to nevertheless measure the pressure in such cases. This

Linking pinch analysis and bridge analysis to save energy by heat-exchanger network retrofit

International Nuclear Information System (INIS)

Bonhivers, Jean-Christophe; Moussavi, Alireza; Alva-Argaez, Alberto; Stuart, Paul R.

2016-01-01

Highlights: • The flow rate of cascaded heat in exchangers is presented between composite curves. • Reducing energy consumption implies decreasing the flow rate of cascaded heat. • Removing cross-pinch transfers is not necessary to reduce energy consumption. • Bridge modifications are necessary to reduce energy consumption. • Bridge modifications are evaluated on the Heat Exchanger Load Diagram. - Abstract: Reduction of energy requirements in the process industries results in increased profitability and better environmental performance. Methods for heat exchanger network (HEN) retrofit are based on thermodynamic analysis and insights, numerical optimization, or combined approaches. Numerical optimization-based methods are highly complex and may not guarantee identification of the global optimum. Pinch analysis, which is an approach based on thermodynamic analysis and composite curves, is the most widely used in the industry. Its simplicity, the use of graphical tools, and the possibility for the user to interact at each step of the design process help identify solutions with consideration of practical feasibility. In the last few years, bridge analysis has been developed for HEN retrofit. It includes the following tools: (a) the definition of the necessary conditions to reduce energy consumption which are expressed in the bridge formulation, (b) a method for enumerating the bridges, (c) the representation of the flow rate of cascaded heat through each existing exchanger on the energy transfer diagram (ETD), and (4) the use of the Heat Exchanger Load Diagram (HELD) to identify a suitable HEN configuration corresponding to modifications. It has been shown that reducing energy consumption implies decreasing the flow rate of cascaded heat through the existing exchangers across the entire temperature range between the hot and cold utilities. The ETD shows all possibilities to reduce the flow rate of cascaded heat through a HEN. The objective of this paper is

Quantitative Comparisons on the Intrinsic Features of Foreign Exchange Rates Between the 1920s and the 2010s: Case of the USD-GBP Exchange Rate

Directory of Open Access Journals (Sweden)

Young Wook Han

2016-09-01

Full Text Available This paper quantitatively compares the intrinsic features of the daily USD-GBP exchange rates in two different periods, the 1920s and the 2010s, under the same freely floating exchange rate system. Even though the foreign exchange markets in the 1920s seem to be much less organized and developed than in the 2010s, this paper finds that both the long memory volatility property and the structural break appear to be the common intrigue features of the exchange rates in the two periods by using the FIGARCH model. In particular, the long memory volatility properties in the two periods are found to be upward biased and overstated because of the structural breaks in the exchange markets. Thus this paper applies the Adaptive-FIGARCH model to consider the long memory volatility property and the structural breaks jointly. The main finding is that the structural breaks in the exchange markets affect the long memory volatility property significantly in the two periods but the degree of the long memory volatility property in the 1920s is reduced more remarkably than in the 2010s after the structural breaks are accounted for; thus implying that the structural breaks in the foreign exchange markets in the 1920s seem to be more significant.

EXTERNALITIES IN EXCHANGE NETWORKS AN ADAPTATION OF EXISTING THEORIES OF EXCHANGE NETWORKS

NARCIS (Netherlands)

Dijkstra, Jacob

2009-01-01

The present paper extends the focus of network exchange research to externalities in exchange networks. Externalities of exchange are defined as direct effects on an actor's utility, of an exchange in which this actor is not involved. Existing theories in the field of network exchange do not inform

Effects of ageing conditions on the precipitates evolution, chromium depletion and intergranular corrosion susceptibility of AISI 316L: experimental and modeling results

Energy Technology Data Exchange (ETDEWEB)

Sahlaoui, H.; Makhlouf, K.; Sidhom, H.; Philibert, J

2004-05-15

Chromium carbides and intermetallic phases which form in industrial AISI 316L stainless steel during ageing for up to 80 000 h between 550 and 650 deg. C were identified by combining transmission electron microscopy (TEM) thin foil imaging and electron diffraction and used to establish the time-temperature-precipitation (TTP) diagram. Following the precipitation phenomena, the chemical changes in the grain boundary region were determined by energy-dispersive X-ray microprobe analysis using a scanning transmission electron microscope (STEM). From the experimentally determined chromium profiles the chromium depleted zones were quantified. The interactions between carbide precipitation involving chromium depletion and intergranular corrosion (IGC) were clearly visible from superposition of TTP diagrams and time-temperature-sensitization (TTS) diagrams obtained from ASTM standardized tests. In addition, an experimental criterion to sensitization-desensitization phenomenon was established. Moreover, an analytical model has been developed in this study and successfully validated to predict the profiles of chromium depleted zones. This model coupled with the previously described criterion provides TTS diagrams in good agreement with experimental results.

Estimación de la corrosión intergranular en la aleación de magnesio AZ31B soldada por fricción - agitación

Directory of Open Access Journals (Sweden)

Willian Aperador Chaparro

2013-12-01

Full Text Available En este trabajo se evalúa la corrosión intergranular, que se presenta en las soldaduras de la aleación de magnesio AZ31B unidas por los procesos de fricción-agitación y comparada con la soldadura con arco de tungsteno y gas, con el fin de evaluar y comparar el comportamiento a la corrosión de ambas soldaduras por medio la técnica de Espectroscopia de Impedancias Electroquímica. Adicionalmente se realizaron análisis microestructurales de los límites de grano por medio del microscopio. Los resultados obtenidos en esta investigación muestran una mayor resistencia a la corrosión de las muestras obtenidas con el proceso de fricción-agitación.

Heat exchanger

International Nuclear Information System (INIS)

Leigh, D.G.

1976-01-01

The arrangement described relates particularly to heat exchangers for use in fast reactor power plants, in which heat is extracted from the reactor core by primary liquid metal coolant and is then transferred to secondary liquid metal coolant by means of intermediate heat exchangers. One of the main requirements of such a system, if used in a pool type fast reactor, is that the pressure drop on the primary coolant side must be kept to a minimum consistent with the maintenance of a limited dynamic head in the pool vessel. The intermediate heat exchanger must also be compact enough to be accommodated in the reactor vessel, and the heat exchanger tubes must be available for inspection and the detection and plugging of leaks. If, however, the heat exchanger is located outside the reactor vessel, as in the case of a loop system reactor, a higher pressure drop on the primary coolant side is acceptable, and space restriction is less severe. An object of the arrangement described is to provide a method of heat exchange and a heat exchanger to meet these problems. A further object is to provide a method that ensures that excessive temperature variations are not imposed on welded tube joints by sudden changes in the primary coolant flow path. Full constructional details are given. (U.K.)

Evolution of magnetic order in mechanically alloyed Al-1 at%Fe

International Nuclear Information System (INIS)

Sebastian, Varkey; Lakshmi, N.; Venugopalan, K.

2007-01-01

The evolution of ferromagnetic order in high-energy ball-milled Al-1 at% Fe before the onset of a considerable Fe-Al solid solution phase has been investigated using 57 Fe Moessbauer and bulk magnetization studies. The unmilled sample does not exhibit bulk magnetic properties and an onset of bulk magnetization is observed only after 30 min of milling, when the grain size becomes comparable to the ferromagnetic exchange length. The Curie temperatures of all the samples are less than that of pure iron. The reduction in grain size is accompanied by an increase in coercivity and reduced remanence and a decrease in T C . The effective magnetic moment per iron atom decreases with the development of a non-magnetic, Al-rich Fe-Al solution on longer milling. The clustering of Fe at grain boundaries is responsible for the observed bulk magnetic ordering. The systematic variation of the magnetic properties has been qualitatively correlated with the evolution of microstructure, reduction in grain size and enhanced inter-granular exchange coupling

Effects of apolipoproteins on the kinetics of cholesterol exchange

International Nuclear Information System (INIS)

Letizia, J.Y.; Phillips, M.C.

1991-01-01

The effects of apolipoproteins on the kinetics of cholesterol exchange have been investigated by monitoring the transfer of [ 14 C]cholesterol from donor phospholipid/cholesterol complexes containing human apolipoproteins A, B, or C. Negatively charged discoidal and vesicular particles containing purified apolipoproteins complexed with lipid and a trace of [ 14 C]cholesterol were incubated with a 10-fold excess of neutral, acceptor, small unilamellar vesicles. The donor and acceptor particles were separated by chromatogrphy of DEAE-Sepharose, and the rate of movement of labeled cholesterol was analyzed as a first-order exchange process. The kinetics of exchange of cholesterol from both vesicular and discoidal complexes that contain apoproteins are consistent with an aqueous diffusion mechanism, as has been established previously for PC/cholesterol SUV. Apolipoproteins A-I, A-II, reduced and carboxymethylated A-11, and B-100 present in SUV at the same lipid/protein (w/w) ratio all enhance the rate of cholesterol exchange to about the same degree. Cholesterol molecules exchange more rapidly from discoidal complexes. Generally, as the diameter of apoprotein/phospholipid/cholesterol discs decreases, t 1/2 for cholesterol exchange decreases. Since small bilayer discs have a relatively high ratio of boundary to face surface area, cholesterol molecules desorb more rapidly than from larger discs. The modulation of lipid packing by the apoprotein molecules present at the surface of lipoprotein particles affects the rate of cholesterol exchange from such particles

Selection of Rational Heat Transfer Intensifiers in the Heat Exchanger

Directory of Open Access Journals (Sweden)

S. A. Burtsev

2016-01-01

Full Text Available The paper considers the applicability of different types of heat transfer intensifiers in the heat exchange equipment. A review of the experimental and numerical works devoted to the intensification of the dimpled surface, surfaces with pins and internally ribbed surface were presented and data on the thermal-hydraulic characteristics of these surfaces were given. We obtained variation of thermal-hydraulic efficiency criteria for 4 different objective functions and 15 options for the intensification of heat transfer. This makes it possible to evaluate the advantages of the various heat transfer intensifiers. These equations show influence of thermal and hydraulic characteristics of the heat transfer intensifiers (the values of the relative heat transfer and drag coefficients on the basic parameters of the shell-and-tube heat exchanger: the number and length of the tubes, the volume of the heat exchanger matrix, the coolant velocity in the heat exchanger matrix, coolant flow rate, power to pump coolant (or pressure drop, the amount of heat transferred, as well as the average logarithmic temperature difference. The paper gives an example to compare two promising heat transfer intensifiers in the tubes and shows that choosing the required efficiency criterion to search for optimal heat exchanger geometry is of importance. Analysis is performed to show that a dimpled surface will improve the effectiveness of the heat exchanger despite the relatively small value of the heat transfer intensification, while a significant increase in drag of other heat transfer enhancers negatively affects their thermalhydraulic efficiency. For example, when comparing the target functions of reducing the heat exchanger volume, the data suggest that application of dimpled surfaces in various fields of technology is possible. But there are also certain surfaces that can reduce the parameters of a heat exchanger. It is shown that further work development should be aimed at

Estimating Exchange Market Pressure and the Degree of Exchange Market Intervention for Finland during the Floating Exchange Rate Regime

OpenAIRE

Pösö, Mika; Spolander, Mikko

1997-01-01

In this paper, we use a fairly simple monetary macro model to calculate the quarterly measures of exchange market pressure and the degree of the Bank of Finland's intervention during the time the markka was floated. Exchange market pressure measures the size of the exchange rate change that would have occurred if the central bank had unexpectedly refrained from intervening in the foreign exchange market. Intervention activity of the central bank is measured as the proportion of exchange marke...

Desalination by electrodialysis with ion-exchange membrane prepared by radiation-induced graft polymerization

Energy Technology Data Exchange (ETDEWEB)

Choi, Seong-Ho; Jeong, Young Han; Ryoo, Jae Jeong; Lee, Kwang-Pill [Department of Chemistry Graduate School, Kyungpook National University, Taegu (Korea)

2000-07-01

Ion-exchange membranes modified with triethylamine [-N(CH{sub 2}CH{sub 3}){sub 3}] and phosphoric acid (-PO{sub 3}H) groups were prepared by radiation-induced grafting of glycidyl methacrylate (GMA) onto polyolefin nonwavon fabric (PNF) and subsequent chemical modification of poly (GMA) graft chains. The physical and chemical properties of the GMA-grafted PNF and the PNF modified with ion-exchange groups were investigated by SEM and XPS. The ion-exchange capacities of the cation- and anion-exchange membrane were 0.20 and 1.24mmol/g, respectively. The content of cation- and anion exchange group increased with increasing grafting yield (d.g.=100%). Electrical resistance of PNF modified with TEA and -PO{sub 3}H group decreased with increasing ion-exchange group capacities. Application of the graft-type ion-exchange membranes as separators for electrodialysis enabled use to reduce the time required to achieve 85.5% desalination of the 0.5M NaCl solution. (author)

Brine reuse in ion-exchange softening: salt discharge, hardness leakage, and capacity tradeoffs.

Science.gov (United States)

Flodman, Hunter R; Dvorak, Bruce I

2012-06-01

Ion-exchange water softening results in the discharge of excess sodium chloride to the aquatic environment during the regeneration cycle. In order to reduce sodium chloride use and subsequent discharge from ion-exchange processes, either brine reclaim operations can be implemented or salt application during regeneration can be reduced. Both result in tradeoffs related to loss of bed volumes treated per cycle and increased hardness leakage. An experimentally validated model was used to compare concurrent water softening operations at various salt application quantities with and without the direct reuse of waste brine for treated tap water of typical midwestern water quality. Both approaches were able to reduce salt use and subsequent discharge. Reducing salt use and discharge by lowering the salt application rate during regeneration consequently increased hardness leakage and decreased treatment capacity. Single or two tank brine recycling systems are capable of reducing salt use and discharge without increasing hardness leakage, although treatment capacity is reduced.

Evaluation of ferrocyanide anion exchange resins regarding the uptake of Cs+ ions and their regeneration

International Nuclear Information System (INIS)

Won, Hui Jun; Mooon, Jei Kwon; Jung, Chong Hun; Chung, Won Yang

2008-01-01

Ferrocyanide-anion exchange resin was prepared and the prepared ion exchange resins were tested on the ability to uptake Cs + ion. The prepared ion exchange resins were resin-KCoFC, resin-KNiFC, and resin-KCuFC. The three tested ion exchange resins showed ion exchange selectivity on the Cs + ion of the surrogate soil decontamination solution, and resin- KCoFC showed the best Cs + ion uptake capability among the tested ion exchange resins. The ion exchange behaviors were explained well by the modified Dubinin-Polanyi equation. A regeneration feasibility study of the spent ion exchange resins was also performed by the successive application of hydrogen peroxide and hydrazine. The desorption of the Cs + ion from the ion exchange resin satisfied the electroneutrality condition in the oxidation step; the desorption of the Fe 2+ ion in the reduction step could also be reduced by adding the K + ion

A continuous exchange factor method for radiative exchange in enclosures with participating media

International Nuclear Information System (INIS)

Naraghi, M.H.N.; Chung, B.T.F.; Litkouhi, B.

1987-01-01

A continuous exchange factor method for analysis of radiative exchange in enclosures is developed. In this method two types of exchange functions are defined, direct exchange function and total exchange function. Certain integral equations relating total exchange functions to direct exchange functions are developed. These integral equations are solved using Gaussian quadrature integration method. The results obtained based on the present approach are found to be more accurate than those of the zonal method

Effects of interest and exchange rate policies on Brazilian exports

Directory of Open Access Journals (Sweden)

Cláudia Maria Sonaglio

2016-01-01

Full Text Available In heterodox literature, the industrial sector is considered strategic for economic development. Consequently, reducing the contribution of this sector in the production of the country before it has reached the stage of economic maturity, affects the productive dynamics and slow technical progress. The appreciation of the real exchange rate is seen as one of the factors responsible for the reduction of the external competitiveness of Brazilian manufactures, and this exchange rate valuation may be occurring due to the differences between domestic and international interest rates. Given this context, the aim of this study is to evaluate the impact of changes in the monetary and exchange rate policy and in the composition of the total exports on the performance of the Brazilian economy using a structuralist model. The results reinforce the importance of the manufacturing sector to economic growth, especially in a competitive exchange rate environment.

Horizontal Parallel Pipe Ground Heat Exchanger : Analytical Conception and Experimental Study

International Nuclear Information System (INIS)

Naili, Nabiha; Jemli, Ramzi; Farhat, Abdel Hamid; Ben Nasrallah, Sassi

2009-01-01

Due to limited amount of natural resources exploited for heating, and in order to reduce the environmental impact, people should strive to use renewable energy resources. Ambient low-grade energy may be upgraded by the ground heat exchanger (GH E), which exploits the ground thermal inertia for buildings heating and cooling. In this study, analytical performance and experiments analysis of a horizontal ground heat exchanger have been performed. The analytical study, relates to the dimensioning of the heat exchanger, shows that the heat exchanger characteristics are very important for the determination of heat extracted from ground. The experimental results were obtained during the period 30 November to 10 December 2007, in the heating season of the greenhouses. Measurements show that the ground temperature under a certain depth remains relatively constant. To exploit effectively the heat capacity of the ground, a horizontal heat exchanger system has to be constructed and tested in the Center of Research and Technology of Energy, in Tunisia

Separation and purification of uranium by ion exchange on stannic phosphate

International Nuclear Information System (INIS)

Mayankutty, P.C.; Nadkarni, M.N.; Venkateswarlu, K.S.

1977-01-01

Exchange of uranium, plutonium and some fission product elements was investigated on stannic phosphate (SnP) exchanger from nitric acid solutions. Batch equilibration studies exhibited stronger absorption of plutonium (IV) and some of the fission products on the exchanger than uranium. This indicated the possibility of separation and purification of uranium from plutonium and fission products. Breakthrough studies were carried out to determine the effects of flow-rates and uranium, plutonium and free nitric acid concentrations in the feed to establish the optimum conditions for this separation. Several reagents were also tested to find suitable eluting agents to desorb plutonium from the exchanger. The results indicate that traces of plutonium and fission products present as impurities in the uranium product of the purex process stream can be removed by ion exchange method using SnP. 1 M nitric acid solution containing low concentrations of reducing agents such as ferrous sulfamate or ascorbic acid was found to be an effective eluting agent for plutonium. (author)

Surface treatment to reduce icing; Oberflaechenbehandlung zur Vereisungsverringerung

Energy Technology Data Exchange (ETDEWEB)

Hoffmann, P.; Kulik, G.; Zehnder, M.

2003-07-01

This final report for the Swiss Federal Office of Energy (SFOE) presents the results of work done at the Swiss Federal Institute of Technology in Lausanne, Switzerland, on reducing ice formation on the evaporators of air-water heat-pumps and speeding-up the defrosting cycle by making their surfaces hydrophobic. The authors report that highest water repellence was achieved by high surface roughness and application of a strongly hydrophobic per fluorosilane coating. The results of tests carried out with uncoated and differently coated sample heat exchangers are presented. Three geometrically identical miniaturised heat exchangers were used that differed in roughness and surface wettability. Surprisingly, the rough and strongly repellent heat-exchanger showed worse defrosting behaviour than the uncoated heat-exchanger. The flat and hydrophobic-coated heat-exchanger showed the best performance. The amount of frost formed was 25% less and defrosting time was much shorter.

Electron exchange reaction in anion exchangers as observed in uranium isotope separation

International Nuclear Information System (INIS)

Obanawa, Heiichiro; Takeda, Kunihiko; Seko, Maomi

1991-01-01

The mechanism of electron exchange in an ion exchanger, as occurring between U 4+ and UO 2 2+ in uranium isotope separation, was investigated. The height of the separation unit (H q ) in the presence of metal ion catalysts, as obtained from the separation experiments, was found to be almost coincident with the theoretical value of H q as calculated on the basis of the intrasolution acceleration mechanism of the metal ion, suggesting that the electron exchange mechanism in the ion-exchanger is essentially the same as that in the solution when metal ion catalysts are present. Separation experiments with no metal ion catalyst, on the other hand, showed the electron exchange reaction in the ion exchanger to be substantially higher than that in the solution, suggesting an acceleration of the electron exchange reaction by the ion-exchanger which is due to the close existence of higher order Cl - complexes of UO 2 2+ and U 4+ in the vicinity of the ion-exchange group. (author)

Transfer coefficients for plate fin and elliptical tube heat exchangers

International Nuclear Information System (INIS)

Saboya, S.M.; Saboya, F.E.M.

1981-01-01

In order to determine transfer coefficients for plate fin and elliptical tube exchangers, mass transfer experiments have been performed using the naphthalene sublimation technique. By means of the heat-mass transfer analogy, the results can be converted to heat transfer results. The transfer coefficients were compared with those for circular tube exchangers and the comparison revealed no major differences. This is a positive outcome, since the use of elliptical tubes may reduce substantially the pressure drop, without affecting the transfer characteristics.(Author) [pt

77 FR 3295 - Self-Regulatory Organizations; International Securities Exchange, LLC; Notice of Filing and...

Science.gov (United States)

2012-01-23

... PHLX, Inc. (``PHLX'') and Nasdaq Options Market (``NOM'') Update Pricing Effective January 3, 2012... pricing that reduces rates for market makers based on the level of business they bring to the Exchange.\\11\\ This proposed rule change targets a particular segment in which the Exchange seeks to garnish greater...

Investigation of Chemical Exchange at Intermediate Exchange Rates using a Combination of Chemical Exchange Saturation Transfer (CEST) and Spin-Locking methods (CESTrho)

Science.gov (United States)

Kogan, Feliks; Singh, Anup; Cai, Keija; Haris, Mohammad; Hariharan, Hari; Reddy, Ravinder

2011-01-01

Proton exchange imaging is important as it allows for visualization and quantification of the distribution of specific metabolites with conventional MRI. Current exchange mediated MRI methods suffer from poor contrast as well as confounding factors that influence exchange rates. In this study we developed a new method to measure proton exchange which combines chemical exchange saturation transfer (CEST) and T1ρ magnetization preparation methods (CESTrho). We demonstrated that this new CESTrho sequence can detect proton exchange in the slow to intermediate exchange regimes. It has a linear dependence on proton concentration which allows it to be used to quantitatively measure changes in metabolite concentration. Additionally, the magnetization scheme of this new method can be customized to make it insensitive to changes in exchange rate while retaining its dependency on solute concentration. Finally, we showed the feasibility of using CESTrho in vivo. This sequence is able to detect proton exchange at intermediate exchange rates and is unaffected by the confounding factors that influence proton exchange rates thus making it ideal for the measurement of metabolites with exchangeable protons in this exchange regime. PMID:22009759

Investigation of chemical exchange at intermediate exchange rates using a combination of chemical exchange saturation transfer (CEST) and spin-locking methods (CESTrho).

Science.gov (United States)

Kogan, Feliks; Singh, Anup; Cai, Keija; Haris, Mohammad; Hariharan, Hari; Reddy, Ravinder

2012-07-01

Proton exchange imaging is important as it allows for visualization and quantification of the distribution of specific metabolites with conventional MRI. Current exchange mediated MRI methods suffer from poor contrast as well as confounding factors that influence exchange rates. In this study we developed a new method to measure proton exchange which combines chemical exchange saturation transfer and T(1)(ρ) magnetization preparation methods (CESTrho). We demonstrated that this new CESTrho sequence can detect proton exchange in the slow to intermediate exchange regimes. It has a linear dependence on proton concentration which allows it to be used to quantitatively measure changes in metabolite concentration. Additionally, the magnetization scheme of this new method can be customized to make it insensitive to changes in exchange rate while retaining its dependency on solute concentration. Finally, we showed the feasibility of using CESTrho in vivo. This sequence is able to detect proton exchange at intermediate exchange rates and is unaffected by the confounding factors that influence proton exchange rates thus making it ideal for the measurement of metabolites with exchangeable protons in this exchange regime. Copyright © 2011 Wiley Periodicals, Inc.

Effects of intermediate layers on magnetic properties and read/write performance in CoCrPt perpendicular recording media with an FeHfN soft magnetic underlayer

International Nuclear Information System (INIS)

Hong, D.H.; Shin, J.N.; Lee, T.D.; Hong, S.Y.; Lee, H.J.

2003-01-01

In this study, the effects of CoCrPtTa and CoCrPtB magnetic intermediate layers (ILs) on the magnetic properties and read/write performance of CoCrPt/soft magnetic layer perpendicular recording media were investigated. Even though the perpendicular coercivity of the media with these ILs was reduced by 500 Oe, these media still showed a low exchange slope of 1.4 and a large negative nucleation field of about -1000 Oe. Additionally, the reduced grain size of the media with these IL was observed by transmission electron microscopy. From the read/write test, these media with ILs showed improved performance of 3-5 dB higher signal-to-noise ratio and overwrite ratio (OW) compared to the media without ILs. These enhancements could be attributed to the reduction of grain size of the magnetic layer and weakening of the intergranular interaction between grains by insertion of the IL

On one pion exchange potential with quark exchange in the resonating group method

International Nuclear Information System (INIS)

Braeuer, K.; Faessler, A.; Fernandez, F.; Shimizu, K.

1985-01-01

The effect of quark exchange between different nucleons on the one pion exchange potential is studied in the framework of the resonating group method. The calculated phase shifts including the one pion exchange potential with quark exchange in addition to the one gluon plus sigma meson exchange are shown to be consistent with experiments. Especially the p-wave phase shifts are improved by taking into account the quark exchange on the one pion exchange potential. (orig.)

Performance analysis of an organic Rankine cycle with internal heat exchanger having zeotropic working fluid

Directory of Open Access Journals (Sweden)

Thoranis Deethayat

2015-09-01

Full Text Available In this study, performance of a 50 kW organic Rankine cycle (ORC with internal heat exchanger (IHE having R245fa/R152a zeotropic refrigerant with various compositions was investigated. The IHE could reduce heat rate at the ORC evaporator and better cycle efficiency could be obtained. The zeotropic mixture could reduce the irreversibilities during the heat exchanges at the ORC evaporator and the ORC condenser due to its gliding temperature; thus the cycle working temperatures came closer to the temperatures of the heat source and the heat sink. In this paper, effects of evaporating temperature, mass fraction of R152a and effectiveness of internal heat exchanger on the ORC performances for the first law and the second law of thermodynamics were considered. The simulated results showed that reduction of R245fa composition could reduce the irreversibilities at the evaporator and the condenser. The suitable composition of R245fa was around 80% mass fraction and below this the irreversibilities were nearly steady. Higher evaporating temperature and higher internal heat exchanger effectiveness also increased the first law and second law efficiencies. A set of correlations to estimate the first and the second law efficiencies with the mass fraction of R245fa, the internal heat exchanger effectiveness and the evaporating temperature were also developed.

78 FR 48522 - Self-Regulatory Organizations; New York Stock Exchange LLC; Notice of Filing of Proposed Rule...

Science.gov (United States)

2013-08-08

... systems and would reduce the systemic and administrative burdens on market participants by avoiding the... Arca rules rather than having the Exchange enforce NYSE Arca rules. In sum, the Exchange believes that...

THREATS AND BENEFITS OF EXCHANGE RATE REGIMES FOR UKRAINE IN TERMS OF EUROPEAN INTEGRATION

OpenAIRE

Svitlana Glushchenko; Svitlana Tkalenko

2016-01-01

The purpose of the paper is to determine threats and benefits of exchange rate regimes in terms of the integration of Ukraine into the European community. Emphasizing features of the manifestation of currency exchange rate in Ukrainian practice is a precondition for choosing the optimal exchange rate regime for Ukraine, which, in its turn, will provide an opportunity to reduce inflation and implement effective tools of monetary and fiscal policies to promote further economic growth and compet...

Social preferences influence the short-term exchange of social grooming among male bonobos.

Science.gov (United States)

Surbeck, Martin; Hohmann, Gottfried

2015-03-01

The emotional mediation hypothesis proposes a mediating role of social bonds in the exchange of services. This model predicts that the form of short-term exchange of services depends on the relationship between the individuals involved. Here, we test this prediction in the exchange of grooming among males in a wild bonobo community for which close relatedness could be excluded. As bonobo males hardly engage in food sharing or agonistic support, grooming is mainly exchanged for grooming. While overall grooming, both given and received, correlates across dyads and within sessions, the form of grooming exchange within a given session differs according to dyadic association preferences. Individuals with a higher tendency to associate, ergo more familiar individuals, exhibit larger time differences and reduced reciprocation in consecutive grooming bouts than less familiar individuals. These results support the idea that emotional components are involved in the exchange of services between unrelated individuals.

Two-stage single-volume exchange transfusion in severe hemolytic disease of the newborn.

Science.gov (United States)

Abbas, Wael; Attia, Nayera I; Hassanein, Sahar M A

2012-07-01

Evaluation of two-stage single-volume exchange transfusion (TSSV-ET) in decreasing the post-exchange rebound increase in serum bilirubin level, with subsequent reduction of the need for repeated exchange transfusions. The study included 104 neonates with hyperbilirubinemia needing exchange transfusion. They were randomly enrolled into two equal groups, each group comprised 52 neonates. TSSV-ET was performed for the 52 neonates and the traditional single-stage double-volume exchange transfusion (SSDV-ET) was performed to 52 neonates. TSSV-ET significantly lowered rebound serum bilirubin level (12.7 ± 1.1 mg/dL), compared to SSDV-ET (17.3 ± 1.7 mg/dL), p < 0.001. Need for repeated exchange transfusions was significantly lower in TSSV-ET group (13.5%), compared to 32.7% in SSDV-ET group, p < 0.05. No significant difference was found between the two groups as regards the morbidity (11.5% and 9.6%, respectively) and the mortality (1.9% for both groups). Two-stage single-volume exchange transfusion proved to be more effective in reducing rebound serum bilirubin level post-exchange and in decreasing the need for repeated exchange transfusions.

Managing operations of plug-in hybrid electric vehicle (PHEV) exchange stations for use with a smart grid

International Nuclear Information System (INIS)

Nurre, Sarah G.; Bent, Russell; Pan, Feng; Sharkey, Thomas C.

2014-01-01

We consider a deterministic integer programming model for determining the optimal operations of multiple plug-in hybrid electric vehicle (PHEV) battery exchange stations over time. The operations include the number of batteries to charge, discharge, and exchange at each point in time over a set time horizon. We allow discharging of batteries back to the power grid, through vehicle-to-grid technology. We incorporate the exchange station's dependence on the power network, transportation network, and other exchange stations. The charging and discharging at these exchange stations lead to a greater amount of variability which creates a less predictable and flat power generation curve. We introduce and test three policies to smooth the power generation curve by balancing its load. Further, tests are conducted evaluating these policies while factoring wind energy into the power generation curve. These computational tests use realistic data and analysis of the results suggest general operating procedures for exchange stations and evaluate the effectiveness of these power flattening policies. - Highlights: • Model the operations of plug-in hybrid electric vehicle battery exchange stations. • Determine the optimal and general charging, discharging, and exchange operations. • Conclude that forced customer service levels are unnecessary with proper pricing. • Examine policies to reduce variability in power generation from PHEVs and wind. • Observe that strict constraints on exchange stations best reduce variability

Ground Source Heat Pump Sub-Slab Heat Exchange Loop Performance in a Cold Climate

Energy Technology Data Exchange (ETDEWEB)

Mittereder, Nick [IBACOS, Inc., Pittsburgh, PA (United States); Poerschke, Andrew [IBACOS, Inc., Pittsburgh, PA (United States)

2013-11-01

This report presents a cold-climate project that examines an alternative approach to ground source heat pump (GSHP) ground loop design. The innovative ground loop design is an attempt to reduce the installed cost of the ground loop heat exchange portion of the system by containing the entire ground loop within the excavated location beneath the basement slab. Prior to the installation and operation of the sub-slab heat exchanger, energy modeling using TRNSYS software and concurrent design efforts were performed to determine the size and orientation of the system. One key parameter in the design is the installation of the GSHP in a low-load home, which considerably reduces the needed capacity of the ground loop heat exchanger. This report analyzes data from two cooling seasons and one heating season.

Chemical-exchange-sensitive MRI of amide, amine and NOE at 9.4 T versus 15.2 T.

Science.gov (United States)

Chung, Julius Juhyun; Choi, Wonmin; Jin, Tao; Lee, Jung Hee; Kim, Seong-Gi

2017-09-01

Chemical exchange (CE)-sensitive MRI benefits greatly from stronger magnetic fields; however, field effects on CE-sensitive imaging have not yet been studied well in vivo. We have compared CE-sensitive Z-spectra and maps obtained at the fields of 9.4 T and 15.2 T in phantoms and rats with off-resonance chemical-exchange-sensitive spin lock (CESL), which is similar to conventional chemical exchange saturation transfer. At higher fields, the background peak at water resonance has less spread and the exchange rate relative to chemical shift decreases, thus CESL intensity is dependent on B 0 . For the in vivo amide and nuclear Overhauser enhancement (NOE) composite resonances of rat brains, intensities were similar for both magnetic fields, but effective amide proton transfer and NOE values obtained with three-point quantification or a curve fitting method were larger at 15.2 T due to the reduced spread of attenuation at the direct water resonance. When using intermediate exchange-sensitive irradiation parameters, the amine proton signal was 65% higher at 15.2 T than at 9.4 T due to a reduced ratio of exchange rate to chemical shift. In summary, increasing magnetic field provides enhancements to CE-sensitive signals in the intermediate exchange regime and reduces contamination from background signals in the slow exchange regime. Consequently, ultrahigh magnetic field is advantageous for CE-sensitive MRI, especially for amine and hydroxyl protons. Copyright © 2017 John Wiley & Sons, Ltd.

The role of the spiracles in gas exchange during development of Samia cynthia (Lepidoptera, Saturniidae).

Science.gov (United States)

Hetz, Stefan K

2007-12-01

Spiracles and the tracheal system of insects allow effective delivery of respiratory gases. During development, holometabolous insects encounter large changes in the functional morphology of gas exchange structures. To investigate changes in respiratory patterns during development, CO2-release was measured in larvae, pre-pupae and pupae of Samia cynthia (Lepidoptera, Saturniidae). Gas exchange patterns showed great variability. Caterpillars had high metabolic rates and released carbon dioxide continuously. Pre-pupae and pupae showed typical discontinuous gas exchange cycles (DGC) at reduced metabolic rates. Changes in gas exchange patterns can partly be explained with low metabolic rates during pupation. Sequential blocking of spiracles in pre-pupae and pupae reduced spiracle conductance with tracheal conductance remaining unaffected. Analysis of gas exchange patterns indicates that caterpillars and pre-pupae use more than 14 spiracles simultaneously while pupae only use 8 to 10 spiracles. Total conductance is not a simple multiple of single spiracles, but may be gradually adaptable to gas exchange demands. Surprisingly, moth pupae showed a DGC if all except one spiracle were blocked. The huge conductance of single spiracles is discussed as a pre-adaptation to high metabolic demands at the beginning and the end of the pupal as well as in the adult stage.

The role of intensive phototherapy in decreasing the need for exchange transfusion in neonatal jaundice

International Nuclear Information System (INIS)

Edris, A.A.F.; Ghany, E.A.G.A.; Razek, A.R.A.A.

2014-01-01

Objectives: To assess the effectiveness of intensive phototherapy in reducing the need for exchange transfusion and the duration of phototherapy. Methods: The prospective study with historical controls was conducted at Cairo University Paediatric Hospital, from February to July 2012, and comprised 360 newborns with indirect hyperbilirubinaemia. The 183 subjects were treated with Bilisphere 360 (Bilisphere group) compared with 177 who had been treated with conventional phototherapy (control group). Both groups were subjected to complete clinical evaluation and laboratory investigations. Results: Bilisphere 360 decreased the need for exchange transfusion in 19 (10.4%) neonates of the Bilisphere group versus 130 (73.4%) of the control group (p<0.001); decreased the level of serum bilirubin as exchange transfusion (6.7 mg/dl (24.9%) in the subjects vs. 6.9 mg/dl (22.7%) in the controls); shortened the duration of phototherapy (2.7 days in the subjects, vs. 4.2 days in the controls; p<0.001). Conclusion: The use of Bilisphere 360 in the treatment of indirect pathological hyperbilirubinaemia is as effective as exchange transfusion in lowering Total Serum Bilirubin when its level is within 2-3 mg/dl (34-51umol/l) of the exchange level. Bilisphere 360 is effective in reducing needs for exchange transfusion and duration of phototherapy. (author)

Tritium permeation losses in HYLIFE-II heat exchanger tubes

International Nuclear Information System (INIS)

Longhurst, G.R.; Dolan, T.J.

1990-01-01

Tritium permeation through the intermediate heat exchanger of the HYLIFE-II inertial fusion design concept is evaluated for routine operating conditions. The permeation process is modelled using the Lewis analogy combined with surface recombination. It is demonstrated that at very low driving potentials, permeation becomes proportional to the first power of the driving potential. The model predicts that under anticipated conditions the primary cooling loop will pass about 6% of the tritium entering it to the intermediate coolant. Possible approached to reducing tritium permeation are explored. Permeation is limited by turbulent diffusion transport through the molten salt. Hence, surface barriers with impendance factors typical of present technology can do very little to reduce permeation. Low Flibe viscosity is desirable. An efficient tritium removal system operating on the Flibe before it gets to the intermediate heat exchanger is required. Needs for further research are highlighted. 9 refs., 2 figs., 1 tab

76 FR 77279 - Self-Regulatory Organizations; International Securities Exchange, LLC; Notice of Filing and...

Science.gov (United States)

2011-12-12

... orders; \\7\\ and tiered pricing that reduces rates for market makers based on the level of business they bring to the Exchange.\\8\\ This proposed rule change targets a particular segment in which the Exchange... place for certain specific FX Options which has its own pricing. See ISE Schedule of Fees. \\8\\ The...

76 FR 50783 - Self-Regulatory Organizations; International Securities Exchange, LLC; Notice of Filing and...

Science.gov (United States)

2011-08-16

... lower fees (or no fees) for customer orders; \\6\\ and tiered pricing that reduces rates for market makers based on the level of business they bring to the Exchange.\\7\\ This proposed rule change targets yet... pricing. See ISE Schedule of Fees. \\7\\ The Exchange currently has a sliding scale fee structure that...

Isotope exchange reaction on solid breeder materials

International Nuclear Information System (INIS)

Baba, A.; Nishikawa, M.; Eguchi, T.; Kawagoe, T.

2000-01-01

Lithium ceramic materials such as Li 2 O, LiAlO 2 , Li 2 ZrO 3 , Li 2 TiO 3 and Li 4 SiO 4 are considered to be as candidate for the tritium breeding material in a deuterium-tritium (D-T) fusion reactor. In the recent blanket designs, helium gas with hydrogen or deuterium is planned to be used as the blanket purge gas to reduce tritium inventory and promote tritium release from the breeding material. In addition, the rate of isotope exchange reaction between hydrogen isotopes in the purge gas and tritium on the surface of the breeding material is necessary to analyze the tritium release behavior from the breeding materials. However, the rate of isotope exchange reactions between hydrogen isotopes in the purge gas and tritium on the surface of those materials has not been quantified until recently. Recently, the present authors quantified the rate of isotope exchange reaction on Li 2 O and Li 2 ZrO 3 . The overall mass transfer coefficients representing the isotope exchange reaction between H 2 and D 2 O on breeding materials or the same between D 2 and H 2 O are experimentally obtained in this study. Comparison to isotope exchange reaction rates on various breeding materials is also performed in this study. Discussions about the effects of temperature, concentration of hydrogen in the purge gas or flow rate of the purge gas on the conversion of tritiated water to tritium gas are also performed

Selective catalytic reduction of nitric oxide by ammonia over Cu-exchanged Cuban natural zeolites

International Nuclear Information System (INIS)

Moreno-Tost, Ramon; Santamaria-Gonzalez, Jose; Rodriguez-Castellon, Enrique; Jimenez-Lopez, Antonio; Autie, Miguel A.; Glacial, Marisol Carreras; Gonzalez, Edel; Pozas, Carlos De las

2004-01-01

The catalytic selective reduction of NO over Cu-exchanged natural zeolites (mordenite (MP) and clinoptilolite (HC)) from Cuba using NH 3 as reducing agent and in the presence of excess oxygen was studied. Cu(II)-exchanged zeolites are very active catalysts, with conversions of NO of 95%, a high selectivity to N 2 at low temperatures, and exhibiting good water tolerance. The chemical state of the Cu(II) in exchanged zeolites was characterized by H 2 -TPR and XPS. Cu(II)-exchanged clinoptilolite underwent a severe deactivation in the presence of SO 2 . However, Cu(II)-exchanged mordenite not only maintained its catalytic activity, but even showed a slight improvement after 20h of reaction in the presence of 100ppm of SO 2

Intergranular tellurium cracking of nickel-based alloys in molten Li, Be, Th, U/F salt mixture

Science.gov (United States)

Ignatiev, Victor; Surenkov, Alexander; Gnidoy, Ivan; Kulakov, Alexander; Uglov, Vadim; Vasiliev, Alexander; Presniakov, Mikhail

2013-09-01

In Russia, R&D on Molten Salt Reactor (MSR) are concentrated now on fast/intermediate spectrum concepts which were recognized as long term alternative to solid fueled fast reactors due to their attractive features: strong negative feedback coefficients, easy in-service inspection, and simplified fuel cycle. For high-temperature MSR corrosion of the metallic container alloy in primary circuit is the primary concern. Key problem receiving current attention include surface fissures in Ni-based alloys probably arising from fission product tellurium attack. This paper summarizes results of corrosion tests conducted recently to study effect of oxidation state in selected fuel salt on tellurium attack and to develop means of controlling tellurium cracking in the special Ni-based alloys recently developed for molten salt actinide recycler and tranforming (MOSART) system. Tellurium corrosion of Ni-based alloys was tested at temperatures up to 750 °C in stressed and unloaded conditions in molten LiF-BeF2 salt mixture fueled by about 20 mol% of ThF4 and 2 mol% of UF4 at different [U(IV)]/[U(III)] ratios: 0.7, 4, 20, 100 and 500. Following Ni-based alloys (in mass%): HN80М-VI (Mo—12, Cr—7.6, Nb—1.5), HN80МТY (Mo—13, Cr—6.8, Al—1.1, Ti—0.9), HN80МТW (Mo—9.4, Cr—7.0, Ti—1.7, W—5.5) and ЕМ-721 (W—25.2, Cr—5.7, Ti—0.17) were used for the study in the corrosion facility. If the redox state the fuel salt is characterized by uranium ratio [U(IV)]/[U(III)] uranium intermetallic compounds and alloys with nickel and molybdenum. This leads to spontaneous behavior of alloy formation processes on the specimens' surface and further diffusion of uranium deep into the metallic phase. As consequence of this films of intermetallic compounds and alloys of nickel, molybdenum, tungsten with uranium are formed on the alloys specimens' surface, and intergranular corrosion does not take place. In the fuel salt with [U(IV)]/[U(III)] = 4-20 the potentials of uranium

Development of a Thin Film Primary Surface Heat Exchanger for Advanced Power Cycles

Energy Technology Data Exchange (ETDEWEB)

Allison, Tim [Southwest Research Inst., San Antonio, TX (United States); Beck, Griffin [Southwest Research Inst., San Antonio, TX (United States); Bennett, Jeffrey [Southwest Research Inst., San Antonio, TX (United States); Hoopes, Kevin [Southwest Research Inst., San Antonio, TX (United States); Miller, Larry [Southwest Research Inst., San Antonio, TX (United States)

2016-06-29

This project objective is to develop a high-temperature design upgrade for an existing primary surface heat exchanger so that the redesigned hardware is capable of operation in CO₂ at temperatures up to 1,510°F (821°C) and pressure differentials up to 130 psi (9 bar). The heat exchanger is proposed for use as a recuperator in an advanced low-pressure oxy-fuel Brayton cycle that is predicted to achieve over 50% thermodynamic efficiency, although the heat exchanger could also be used in other high-temperature, low-differential pressure cycles. This report describes the progress to date, which includes continuing work performed to select and test new candidate materials for the recuperator redesign, final mechanical and thermal performance analysis results of various redesign concepts, and the preliminary design of a test loop for the redesigned recuperator including a budgetary estimate for detailed test loop design, procurement, and test operation. A materials search was performed in order to investigate high-temperature properties of many candidate materials, including high-temperature strength and nickel content. These properties were used to rank the candidate materials, resulting in a reduced list of nine materials for corrosion testing. Multiple test rigs were considered and analyzed for short-term corrosion testing and Thermal Gravimetric Analysis (TGA) was selected as the most cost-effective option for evaluating corrosion resistance of the candidate materials. In addition, tantalum, niobium, and chromium coatings were identified as potential options for increased corrosion resistance. The test results show that many materials exhibit relatively low weight gain rates, and that niobium and tantalum coatings may improve corrosion resistance for many materials, while chromium coatings appear to oxidize and debond quickly. Metallurgical analysis of alloys was also performed, showing evidence of intergranular attack in 282 that may cause long

Optimization of Heat Exchangers for Intercooled Recuperated Aero Engines

Directory of Open Access Journals (Sweden)

Dimitrios Misirlis

2017-03-01

Full Text Available In the framework of the European research project LEMCOTEC, a section was devoted to the further optimization of the recuperation system of the Intercooled Recuperated Aero engine (IRA engine concept, of MTU Aero Engines AG. This concept is based on an advanced thermodynamic cycle combining both intercooling and recuperation. The present work is focused only on the recuperation process. This is carried out through a system of heat exchangers mounted inside the hot-gas exhaust nozzle, providing fuel economy and reduced pollutant emissions. The optimization of the recuperation system was performed using computational fluid dynamics (CFD computations, experimental measurements and thermodynamic cycle analysis for a wide range of engine operating conditions. A customized numerical tool was developed based on an advanced porosity model approach. The heat exchangers were modeled as porous media of predefined heat transfer and pressure loss behaviour and could also incorporate major and critical heat exchanger design decisions in the CFD computations. The optimization resulted in two completely new innovative heat exchanger concepts, named as CORN (COnical Recuperative Nozzle and STARTREC (STraight AnnulaR Thermal RECuperator, which provided significant benefits in terms of fuel consumption, pollutants emission and weight reduction compared to more conventional heat exchanger designs, thus proving that further optimization potential for this technology exists.

Role of copper and aluminum additions on the hydrogen embrittlement susceptibility of austenitic Fe-Mn-C TWIP steels

International Nuclear Information System (INIS)

Dieudonne, T.; Chene, J.; Marchetti, L.; Wery, M.; Allely, C.; Cugy, P.; Scott, C.P.

2014-01-01

The role of alloying elements on the hydrogen embrittlement (HE) susceptibility of a Fe-18Mn-0.6C alloy was investigated by in situ tensile tests and characterized by the ductility loss associated with intergranular fracture. Under cathodic polarization an improvement of HE resistance is related to the SFE increase with Cu or Al additions reducing the stress-strain and H localization at grain boundaries, which prevents H-induced intergranular cracking. At rest potential, beneficial effects of Cu and Al are related to their influence on hydrogen absorption during the corrosion process. However, residual phosphorus strongly reduces the beneficial effect of aluminum. (authors)

How did China's foreign exchange reform affect the efficiency of foreign exchange market?

Science.gov (United States)

Ning, Ye; Wang, Yiming; Su, Chi-wei

2017-10-01

This study compares the market efficiency of China's onshore and offshore foreign exchange markets before and after the foreign exchange reform on August 11, 2015. We use the multifractal detrended fluctuation analysis of the onshore and offshore RMB/USD spot exchange rate series as basis. We then find that the onshore foreign exchange market before the reform has the lowest market efficiency, which increased after the reform. The offshore foreign exchange market before the reform has the highest market efficiency, which dropped after the reform. This finding implies the increased efficiency of the onshore foreign exchange market and the loss of efficiency in the offshore foreign exchange market. We also find that the offshore foreign exchange market is more efficient than the onshore market and that the gap shrank after the reform. Changes in intervention of the People's Bank of China since the reform is a possible explanation for the changes in the efficiency of the foreign exchange market.

Random matrix theory and portfolio optimization in Moroccan stock exchange

Science.gov (United States)

El Alaoui, Marwane

2015-09-01

In this work, we use random matrix theory to analyze eigenvalues and see if there is a presence of pertinent information by using Marčenko-Pastur distribution. Thus, we study cross-correlation among stocks of Casablanca Stock Exchange. Moreover, we clean correlation matrix from noisy elements to see if the gap between predicted risk and realized risk would be reduced. We also analyze eigenvectors components distributions and their degree of deviations by computing the inverse participation ratio. This analysis is a way to understand the correlation structure among stocks of Casablanca Stock Exchange portfolio.

Effect of geometric factors on performance of a sodium to air heat exchanger in a fast breeder reactor

International Nuclear Information System (INIS)

Kannan, K.; Vinod, V.; Padmakumar, G.; Rudramoorthy, R.; Rajan, K.K.

2015-01-01

Highlights: • A heat exchanger analysis (HE) before scale up reduces excess heat transfer area. • Representative Elementary Volume analysis of a HE speeds up the solution. • The error in air temperature rise prediction by numerical across HE is within 5%. • When both pitches are reduced, the maximum increase in heat flux is experienced. • The experience has resulted in better design of next level heat exchangers. - Abstract: Prototype fast breeder reactor (PFBR) has a safety grade decay heat removal system whose performance depends on the effective functioning of natural convection heat exchangers called sodium to air heat exchangers. The development of Representative Elementary Volume (REV) model for the sodium to air heat exchanger is necessary to envisage its design and to study the effect of various factors for continuous improvement in design. With a Representative Elementary Volume, the hydrodynamic and heat transfer characteristics of the heat exchanger was studied and the results agree well with experimental data. The effect of longitudinal pitch and transverse pitch on the heat exchanger performance has been studied and an improvement of 22% in heat transfer is predicted

Investigating the effects of liquidity and exchange rate on Tehran Stock Exchange

Directory of Open Access Journals (Sweden)

Younos Vakil Alroaia

2014-08-01

Full Text Available This paper presents an empirical investigation to study the effects of two macroeconomic factors; namely exchange rate and liquidity on stock index. The proposed study was applied in Iran and on major index of Tehran Stock Exchange over the period 2001-2011. They reported that the currency exchange maintained negative impact on stock exchange for the period of investigation. This is due to the fact that when currency devalued, working capital decreases and firms did not enough money to purchase raw materials, pay wages, etc. In addition, liquidity marinated a direct and positive relationship with exchange index. However, the impact of liquidity seems to be bigger than currency exchange.

Theory and design of heat exchanger : air cooled plate, spiral heat exchanger

International Nuclear Information System (INIS)

Min, Ui Dong

1960-02-01

This book deals with air cooled heat exchanger, which introduces heat rejection system, wet surface cooler in new from, explanation of structure and design, materials, basic design like plenums chambers and fan ring, finned tube fouling factor, airflow in forced draft and fan design. It also tells of plate heat exchanger and spiral heat exchanger giving descriptions of summary, selection, basic design, device and safety function, maintenance, structure of plate heat exchanger, frames and connector plate and, basic things of spiral tube heat exchanger.

Electron self-exchange in hemoglobins revealed by deutero-hemin substitution.

Science.gov (United States)

Athwal, Navjot Singh; Alagurajan, Jagannathan; Sturms, Ryan; Fulton, D Bruce; Andreotti, Amy H; Hargrove, Mark S

2015-09-01

Hemoglobins (phytoglobins) from rice plants (nsHb1) and from the cyanobacterium Synechocystis (PCC 6803) (SynHb) can reduce hydroxylamine with two electrons to form ammonium. The reaction requires intermolecular electron transfer between protein molecules, and rapid electron self-exchange might play a role in distinguishing these hemoglobins from others with slower reaction rates, such as myoglobin. A relatively rapid electron self-exchange rate constant has been measured for SynHb by NMR, but the rate constant for myoglobin is equivocal and a value for nsHb1 has not yet been measured. Here we report electron self-exchange rate constants for nsHb1 and Mb as a test of their role in hydroxylamine reduction. These proteins are not suitable for analysis by NMR ZZ exchange, so a method was developed that uses cross-reactions between each hemoglobin and its deutero-hemin substituted counterpart. The resulting electron transfer is between identical proteins with low driving forces and thus closely approximates true electron self-exchange. The reactions can be monitored spectrally due to the distinct spectra of the prosthetic groups, and from this electron self-exchange rate constants of 880 (SynHb), 2900 (nsHb1), and 0.05M(-1) s(-1) (Mb) have been measured for each hemoglobin. Calculations of cross-reactions using these values accurately predict hydroxylamine reduction rates for each protein, suggesting that electron self-exchange plays an important role in the reaction. Copyright © 2015 Elsevier Inc. All rights reserved.

Nongeminate radiative recombination of free charges in cation-exchanged PbS quantum dot films

Energy Technology Data Exchange (ETDEWEB)

Marshall, Ashley R. [National Renewable Energy Laboratory, 15013 Denver West Pkwy., Golden, CO 80401 (United States); Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309 (United States); Beard, Matthew C.; Johnson, Justin C. [National Renewable Energy Laboratory, 15013 Denver West Pkwy., Golden, CO 80401 (United States)

2016-06-01

Highlights: • Photoluminescence and transient absorption are used to probe PbS QD films. • Cation-exchanged PbS QDs show room-temperature PL emission. • Bimolecular recombination is shown for the first time in coupled, PbS QD films. - Abstract: Using photoluminescence (PL) spectroscopy we explore the radiative recombination pathways in PbS quantum dots (QDs) synthesized by two methods. We compare conventionally synthesized PbS from a PbO precursor to PbS synthesized using cation-exchange from CdS QDs. We show that strongly coupled films of PbS QDs from the cation-exchange luminesce with significant efficiency at room temperature. This is in stark contrast to conventional PbS QDs, which have exceedingly weak room temperature emission. Moreover, the power dependence of the emission is quadratic, indicating bimolecular radiative recombination that is reasonably competitive with trap-assisted recombination, a feature previously unreported in coupled PbS QD films. We interpret these results in terms of a greatly reduced defect concentration for cation-exchanged QDs that mitigates the influence of trap-assisted recombination. Cation-exchanged QDs have recently been employed in highly efficient and air-stable lead chalcogenide QD devices, and the reduced number of trap states inferred here may lead to improved current collection and higher open circuit voltage.

Ground Source Heat Pump Sub-Slab Heat Exchange Loop Performance in a Cold Climate

Energy Technology Data Exchange (ETDEWEB)

Mittereder, N.; Poerschke, A.

2013-11-01

This report presents a cold-climate project that examines an alternative approach to ground source heat pump (GSHP) ground loop design. The innovative ground loop design is an attempt to reduce the installed cost of the ground loop heat exchange portion of the system by containing the entire ground loop within the excavated location beneath the basement slab. Prior to the installation and operation of the sub-slab heat exchanger, energy modeling using TRNSYS software and concurrent design efforts were performed to determine the size and orientation of the system. One key parameter in the design is the installation of the GSHP in a low-load home, which considerably reduces the needed capacity of the ground loop heat exchanger. This report analyzes data from two cooling seasons and one heating season. Upon completion of the monitoring phase, measurements revealed that the initial TRNSYS simulated horizontal sub-slab ground loop heat exchanger fluid temperatures and heat transfer rates differed from the measured values. To determine the cause of this discrepancy, an updated model was developed utilizing a new TRNSYS subroutine for simulating sub-slab heat exchangers. Measurements of fluid temperature, soil temperature, and heat transfer were used to validate the updated model.

Reactor fuel exchanging facility

International Nuclear Information System (INIS)

Kubota, Shin-ichi.

1981-01-01

Purpose: To enable operation of an emergency manual operating mechanism for a fuel exchanger with all operatorless trucks and remote operation of a manipulator even if the exchanger fails during the fuel exchanging operation. Constitution: When a fuel exchanging system fails while connected to a pressure tube of a nuclear reactor during a fuel exchanging operation, a stand-by self-travelling truck automatically runs along a guide line to the position corresponding to the stopping position at that time of the fuel exchanger based on a command from a central control chamber. At this time the truck is switched to manual operation, and approaches the exchanger while being monitored through a television camera and then stops. Then, a manipurator is connected to the emergency manual operating mechanism of the exchanger, and is operated through necessary emergency steps by driving the snout, the magazine, the grab or the like in the exchanger in response to the problem, and necessary operations for the emergency treatment are thus performed. (Sekiya, K.)

Theory and design of heat exchanger : Double pipe and heat exchanger in abnormal condition

International Nuclear Information System (INIS)

Min, Ui Dong

1996-02-01

This book introduces theory and design of heat exchanger, which includes HTRI program, multiple tube heat exchanger external heating, theory of heat transfer, basis of design of heat exchanger, two-phase flow, condensation, boiling, material of heat exchanger, double pipe heat exchanger like hand calculation, heat exchanger in abnormal condition such as Jackets Vessel, and Coiled Vessel, design and summary of steam tracing.

High Temperature Thermosetting Polyimide Nanocomposites Prepared with Reduced Charge Organoclay

Science.gov (United States)

Campbell, Sandi; Liang, Margaret I.

2005-01-01

The naturally occurring sodium and calcium cations found in bentonite clay galleries were exchanged with lithium cations. Following the cation exchange, a series of reduced charge clays were prepared by heat treatment of the lithium bentonite at 130 C, 150 C, or 170 C. Inductively coupled plasma (ICP) analysis showed that heating the lithium clay at elevated temperatures reduced its cation exchange capacity. Ion exchange of heat-treated clays with either a protonated alkyl amine or a protonated aromatic diamine resulted in decreasing amounts of the organic modifier incorporated into the lithium clay. The level of silicate dispersion in a thermosetting polyimide matrix was dependent upon the temperature of Li-clay heat treatment as well as the organic modification. In general, clays treated at 150 C or 170 C, and exchanged with protonated octadcylamine or protonated 2,2'-dimethlybenzidine (DMBZ) showed a higher degree of dispersion than clays treated at 130 C, or exchanged with protonated dodecylamine. Dynamic mechanical analysis showed little change in the storage modulus or T(sub g) of the nanocomposites compared to the base resin. However, long term isothermal aging of the samples showed a significant decrease in the resin oxidative weight loss. Nanocomposite samples aged in air for 1000 hours at 288 C showed of to a decrease in weight loss compared to that of the base resin. This again was dependent on the temperature at which the Li-clay was heated and the choice of organic modification.

Can knowledge exchange support the implementation of a health-promoting schools approach? Perceived outcomes of knowledge exchange in the COMPASS study.

Science.gov (United States)

Brown, Kristin M; Elliott, Susan J; Robertson-Wilson, Jennifer; Vine, Michelle M; Leatherdale, Scott T

2018-03-13

Despite the potential population-level impact of a health-promoting schools approach, schools face challenges in implementation, indicating a gap between school health research and practice. Knowledge exchange provides an opportunity to reduce this gap; however, there has been limited evaluation of these initiatives. This research explored researchers' and knowledge users' perceptions of outcomes associated with a knowledge exchange initiative within COMPASS, a longitudinal study of Canadian secondary students and schools. Schools received annual tailored summaries of their students' health behaviours and suggestions for action and were linked with knowledge brokers to support them in taking action to improve student health. Qualitative semi-structured interviews were conducted with COMPASS researchers (n = 13), school staff (n = 13), and public health stakeholders (n = 4) to explore their experiences with COMPASS knowledge exchange. Key issues included how knowledge users used school-specific findings, perceived outcomes of knowledge exchange, and suggestions for change. Outcomes for both knowledge users and researchers were identified; interestingly, knowledge users attributed more outcomes to using school-specific findings than knowledge brokering. School and public health participants indicated school-specific findings informed their programming and planning. Importantly, knowledge exchange provided a platform for partnerships between researchers, schools, and public health units. Knowledge brokering allowed researchers to gain feedback from knowledge users to enhance the study and a better understanding of the school environment. Interestingly, COMPASS knowledge exchange outcomes aligned with Samdal and Rowling's eight theory-driven implementation components for health-promoting schools. Hence, knowledge exchange may provide a mechanism to help schools implement a health-promoting schools approach. This research contributes to the limited

76 FR 46866 - Self-Regulatory Organizations; Chicago Stock Exchange, Incorporated; Notice of Filing of Proposed...

Science.gov (United States)

2011-08-03

... reduce the credit risk to the parties involved in the transaction. Failure to cancel or offset the stock... Organizations; Chicago Stock Exchange, Incorporated; Notice of Filing of Proposed Rule Change To Amend Article... Cancellation of the Stock Leg of Stock- Option Transactions Done on the Exchange July 28, 2011. Pursuant to...

The Metaphysics of Economic Exchanges

Directory of Open Access Journals (Sweden)

Massin Olivier

2017-05-01

Full Text Available What are economic exchanges? The received view has it that exchanges are mutual transfers of goods motivated by inverse valuations thereof. As a corollary, the standard approach treats exchanges of services as a subspecies of exchanges of goods. We raise two objections against this standard approach. First, it is incomplete, as it fails to take into account, among other things, the offers and acceptances that lie at the core of even the simplest cases of exchanges. Second, it ultimately fails to generalize to exchanges of services, in which neither inverse preferences nor mutual transfers hold true. We propose an alternative definition of exchanges, which treats exchanges of goods as a special case of exchanges of services and which builds in offers and acceptances. According to this theory: (i The valuations motivating exchanges are propositional and convergent rather than objectual and inverse; (ii All exchanges of goods involve exchanges of services/actions, but not the reverse; (iii Offers and acceptances, together with the contractual obligations and claims they bring about, lie at the heart of all cases of exchange.

Manual exchange transfusion for severe imported falciparum malaria: a retrospective study.

Science.gov (United States)

Lin, Jinfeng; Huang, Xiaoying; Qin, Gang; Zhang, Suyan; Sun, Weiwei; Wang, Yadong; Ren, Ke; Xu, Junxian; Han, Xudong

2018-01-16

This study was designed to evaluate the efficacy of exchange transfusion in patients with severe imported falciparum malaria. Twelve patients who met the diagnostic criteria for severe malaria were treated with exchange transfusion 14 times according to a conventional anti-malarial treatment. This study evaluated the efficacy of exchange transfusion for severe imported falciparum malaria. Clinical data of severe imported falciparum malaria patients admitted to the intensive care unit (ICU) of Nantong Third People's Hospital from January 2007 to December 2016 were investigated in this retrospective study. Patients were divided into the intervention group, which received exchange transfusion, and the control group. This study assessed parasite clearance and outcomes of the two groups, and levels of erythrocytes, haemoglobin, platelets, coagulation, liver function, lactate, C-reactive protein, and procalcitonin, before and after exchange transfusion in the intervention group. There was no significant difference in the severity of admitted patients. Exchange transfusion was successfully applied 14 times in the intervention group. Differences in the levels of erythrocytes, haemoglobin and platelets did not reach statistical significance. Exchange transfusion improved coagulation, liver function, lactic acid, C-reactive protein, and procalcitonin. No differences were observed in parasite clearance, ICU and hospital length of stay, in-hospital mortality, and costs of hospitalization between the two groups. Exchange transfusion as adjunctive therapy for severe malaria was observed to be safe in this setting. Exchange transfusion can improve liver function and coagulation and reduce inflammation, but it failed to improve parasite clearance and the outcomes of severe imported falciparum malaria in this case series.

Exchange Rate Volatility and Employment Growth in Developing Countries: Evidence from Turkey

OpenAIRE

Demir, Firat

2010-01-01

Employing a unique panel of 691 private firms that accounted for 26% of total value-added in manufacturing in Turkey, the paper explores the impacts of exchange rate volatility on employment growth during the period of 1983 - 2005. The empirical analysis using a variety of specifications, estimation techniques, and robustness tests suggests that exchange rate volatility has a statistically and economically significant employment growth reducing effect on manufacturing firms. Using point estim...

Marriage exchanges, seed exchanges, and the dynamics of manioc diversity.

Science.gov (United States)

Delêtre, Marc; McKey, Doyle B; Hodkinson, Trevor R

2011-11-08

The conservation of crop genetic resources requires understanding the different variables-cultural, social, and economic-that impinge on crop diversity. In small-scale farming systems, seed exchanges represent a key mechanism in the dynamics of crop genetic diversity, and analyzing the rules that structure social networks of seed exchange between farmer communities can help decipher patterns of crop genetic diversity. Using a combination of ethnobotanical and molecular genetic approaches, we investigated the relationships between regional patterns of manioc genetic diversity in Gabon and local networks of seed exchange. Spatially explicit Bayesian clustering methods showed that geographical discontinuities of manioc genetic diversity mirror major ethnolinguistic boundaries, with a southern matrilineal domain characterized by high levels of varietal diversity and a northern patrilineal domain characterized by low varietal diversity. Borrowing concepts from anthropology--kinship, bridewealth, and filiation--we analyzed the relationships between marriage exchanges and seed exchange networks in patrilineal and matrilineal societies. We demonstrate that, by defining marriage prohibitions, kinship systems structure social networks of exchange between farmer communities and influence the movement of seeds in metapopulations, shaping crop diversity at local and regional levels.

Simulation Suggests that medical group mergers won't undermine the potential utility of health information exchanges.

Science.gov (United States)

Rudin, Robert S; Schneider, Eric C; Volk, Lynn A; Szolovits, Peter; Salzberg, Claudia A; Simon, Steven R; Bates, David W

2012-03-01

Federal and state agencies are investing substantial resources in the creation of community health information exchanges, which are consortia that enable independent health care organizations to exchange clinical data. However, under pressure to form accountable care organizations, medical groups may merge and support private health information exchanges. Such activity could reduce the potential utility of community exchanges-that is, the exchanges' capacity to share patient data across hospitals and physician practices that are independent. Simulations of care transitions based on data from ten Massachusetts communities suggest that there would have to be many such mergers to undermine the potential utility of health information exchanges. At the same time, because hospitals and the largest medical groups account for only 10-20 percent of care transitions in a community, information exchanges will still need to recruit a large proportion of the medical groups in a given community for the exchanges to maintain their usefulness in fostering information exchange across independent providers.

Evaluation of ferrocyanide anion exchange resins regarding the uptake of Cs{sup +} ions and their regeneration

Energy Technology Data Exchange (ETDEWEB)

Won, Hui Jun; Mooon, Jei Kwon; Jung, Chong Hun [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Chung, Won Yang [Kangwon University, Chuncheon (Korea, Republic of)

2008-10-15

Ferrocyanide-anion exchange resin was prepared and the prepared ion exchange resins were tested on the ability to uptake Cs{sup +} ion. The prepared ion exchange resins were resin-KCoFC, resin-KNiFC, and resin-KCuFC. The three tested ion exchange resins showed ion exchange selectivity on the Cs{sup +} ion of the surrogate soil decontamination solution, and resin- KCoFC showed the best Cs{sup +} ion uptake capability among the tested ion exchange resins. The ion exchange behaviors were explained well by the modified Dubinin-Polanyi equation. A regeneration feasibility study of the spent ion exchange resins was also performed by the successive application of hydrogen peroxide and hydrazine. The desorption of the Cs{sup +} ion from the ion exchange resin satisfied the electroneutrality condition in the oxidation step; the desorption of the Fe{sup 2+} ion in the reduction step could also be reduced by adding the K{sup +} ion.

Memory effect versus exchange bias for maghemite nanoparticles

International Nuclear Information System (INIS)

Nadeem, K.; Krenn, H.; Szabó, D.V.

2015-01-01

We studied the temperature dependence of memory and exchange bias effects and their dependence on each other in maghemite (γ-Fe 2 O 3 ) nanoparticles by using magnetization studies. Memory effect in zero field cooled process in nanoparticles is a fingerprint of spin-glass behavior which can be due to i) surface disordered spins (surface spin-glass) and/or ii) randomly frozen and interacting nanoparticles core spins (super spin-glass). Temperature region (25–70 K) for measurements has been chosen just below the average blocking temperature (T B =75 K) of the nanoparticles. Memory effect (ME) shows a non-monotonous behavior with temperature. It shows a decreasing trend with decreasing temperature and nearly vanishes below 30 K. However it also decreased again near the blocking temperature of the nanoparticles e.g., 70 K. Exchange bias (EB) in these nanoparticles arises due to core/shell interface interactions. The EB increases sharply below 30 K due to increase in core/shell interactions, while ME starts vanishing below 30 K. We conclude that the core/shell interface interactions or EB have not enhanced the ME but may reduce it in these nanoparticles. - Highlights: • We studied the T-dependent memory and exchange bias (EB) effects in maghemite nanoparticles. • EB causes spin-canting at the core/shell interface which may reduces the memory effect (ME). • Interface interactions does not increase the ME in these nanoparticles

Memory effect versus exchange bias for maghemite nanoparticles

Energy Technology Data Exchange (ETDEWEB)

Nadeem, K., E-mail: kashif.nadeem@iiu.edu.pk [Materials Research Laboratory, Department of Physics, International Islamic University, Islamabad (Pakistan); Krenn, H. [Institute of Physics, Karl-Franzens University Graz, Universitätsplatz 5, A-8010 Graz (Austria); Szabó, D.V. [Karlsruhe Institute of Technology, Institute for Applied Materials, 76344 Eggenstein-Leopoldshafen (Germany)

2015-11-01

We studied the temperature dependence of memory and exchange bias effects and their dependence on each other in maghemite (γ-Fe{sub 2}O{sub 3}) nanoparticles by using magnetization studies. Memory effect in zero field cooled process in nanoparticles is a fingerprint of spin-glass behavior which can be due to i) surface disordered spins (surface spin-glass) and/or ii) randomly frozen and interacting nanoparticles core spins (super spin-glass). Temperature region (25–70 K) for measurements has been chosen just below the average blocking temperature (T{sub B}=75 K) of the nanoparticles. Memory effect (ME) shows a non-monotonous behavior with temperature. It shows a decreasing trend with decreasing temperature and nearly vanishes below 30 K. However it also decreased again near the blocking temperature of the nanoparticles e.g., 70 K. Exchange bias (EB) in these nanoparticles arises due to core/shell interface interactions. The EB increases sharply below 30 K due to increase in core/shell interactions, while ME starts vanishing below 30 K. We conclude that the core/shell interface interactions or EB have not enhanced the ME but may reduce it in these nanoparticles. - Highlights: • We studied the T-dependent memory and exchange bias (EB) effects in maghemite nanoparticles. • EB causes spin-canting at the core/shell interface which may reduces the memory effect (ME). • Interface interactions does not increase the ME in these nanoparticles.

Emission trading in Europe with an exchange rate

International Nuclear Information System (INIS)

Klassen, G.A.J.; Amann, M.; Foersund, F.R.

1994-01-01

The analytical and empirical properties of a new method for emission trading according to a fixed exchange rate are explored. The exchange rate is based on the ratios of the marginal costs of abatement in the optimal solution in order to account for the impact of the location of emission sources on the deposition. It is shown that, generally, this system will not achieve the optimal solution and does not guarantee that environmental deposition constraints are not violated, although total abatement costs are always reduced. A routine was developed to mimic trading as a bilateral, sequential process, subject to an exchange rate. Use has been made of an adapted version of the optimization module in the RAINS (REgional Acidification INformation and Simulation) model. In the example used, results for SO 2 emissions in Europe show that, starting from a uniform reduction, exchange-rate trading achieves higher cost savings than one-to-one trading, without achieving the cost minimum. Sulfur deposition targets are not violated since the initial emission allocation overfulfilled targets at many places. The results are sensitive to: pre-trade emission levels, the transaction costs, the availability of information on potential cost savings and assumptions made on the behavior of trading partners. 6 figs., 3 tabs., 28 refs

Study of kinetics, equilibrium and isotope exchange in ion exchange systems Pt. 6

International Nuclear Information System (INIS)

Plicka, J.; Stamberg, K.; Cabicar, J.; Gosman, A.

1986-01-01

The description of kinetics of ion exchange in ternary system was based upon three Nernst-Planck equations, each of them describing the particle diffusion flux of a given counterion as an independent process. For experimental verification, the strongly acidic cation exchanger OSTION KS 08 the shallow-bed technique, and 0.2 mol x dm -3 aqueous nitrate solutions were chosen. The kinetics of ion exchange in the system of cations Na + - Mg 2+ - UO 2 2+ was studied. The values of diffusion coefficients obtained by evaluating of kinetics of isotope exchange and binary ion exchange were used for calculation. The comparison of calculated exchange rate curves with the experimental ones was made. It was found that the exchanging counterions were affected by each other. (author)

Quantification of exchangeable and non-exchangeable organically bound tritium (OBT) in vegetation

International Nuclear Information System (INIS)

Kim, S.B.; Korolevych, V.

2013-01-01

The objective of this study is to quantify the relative amounts of exchangeable organically bound tritium (OBT) and non-exchangeable OBT in various vegetables. A garden plot at Perch Lake, where tritium levels are slightly elevated due to releases of tritium from a nearby nuclear waste management area and Chalk River Laboratories (CRL) operations, was used to cultivate a variety of vegetables. Five different kinds of vegetables (lettuce, cabbage, tomato, radish and beet) were studied. Exchangeable OBT behaves like tritium in tissue free water in living organisms and, based on past measurements, accounts for about 20% of the total tritium in dehydrated organic materials. In this study, the percentage of the exchangeable OBT was determined to range from 20% to 57% and was found to depend on the type of vegetables as well as the sequence of the plants exposure to HTO. -- Highlights: ► This study was to quantify the amount of exchangeable OBT compared to non-exchangeable OBT in vegetables. ► The percentage of exchangeable OBT varied between vegetable types and HTO exposure conditions. ► Exchangeable OBT varied from 20 to 36% in un-treated vegetables and from 30 to 57% in treated vegetables

Horizontal Curve Virtual Peer Exchange : an RSPCB Peer Exchange

Science.gov (United States)

2014-06-01

This report summarizes the Horizontal Curve Virtual Peer Exchange sponsored by the Federal Highway Administration (FHWA) Office of Safetys Roadway Safety Professional Capacity Building Program on June 17, 2014. This virtual peer exchange was the f...

Interest Rate Rules, Exchange Market Pressure, and Successful Exchange Rate Management

NARCIS (Netherlands)

Klaassen, F.; Mavromatis, K.

2016-01-01

Central banks with an exchange rate objective set the interest rate in response to what they call ''pressure.'' Instead, existing interest rate rules rely on the exchange rate minus its target. To stay closer to actual policy, we introduce a rule that uses exchange market pressure (EMP), the

Standardizing exchange formats

International Nuclear Information System (INIS)

Lemmel, H.D.; Schmidt, J.J.

1992-01-01

An international network of co-operating data centres is described who maintain identical data bases which are simultaneously updated by an agreed data exchange procedure. The agreement covers ''data exchange formats'' which are compatible to the centres' internal data storage and retrieval systems which remain different, optimized at each centre to the available computer facilities and to the needs of the data users. Essential condition for the data exchange is an agreement on common procedures for the data exchange is an agreement on common procedures for the data compilation, including critical data analysis and validation. The systems described (''EXFOR'', ''ENDF'', ''CINDA'') are used for ''nuclear reaction data'', but the principles used for data compilation and exchange should be valid also for other data types. (author). 24 refs, 4 figs

76 FR 23634 - Self-Regulatory Organizations; Chicago Stock Exchange, Inc.; Notice of Filing and Immediate...

Science.gov (United States)

2011-04-27

... Exchange and reduce automatic cancellations by the Exchange's core trading facility, the Matching System, for orders which lock or cross the best displayed quotes in the National Market System. CHX Only... the CHX Only order locks the NBBO at the time of order entry, and not if it crosses the NBBO. Such...

Meson exchange currents in nuclei; the triton beta decay as an example

International Nuclear Information System (INIS)

Jaus, W.

1976-01-01

The method used to reduce the four-dimensional Bethe-Salpeter equation to the three-dimensional Schroedinger equation, thus defining a potential in terms of the field theoretic interaction, can be generalized to define a consistent exchange by considering the relativistic interaction of a current with a bound state of nucleons. This covariant approach allows a unified treatment of exchange current effects, renormalization of the nuclear wave function due to meson exchange, relativistic corrections and negative energy contributions to the wave function and it is discussed in detail how these effects influence the Gamow-Teller matrix element for the decay 3 H→ 3 He + e + antiγ. One and two-meson exchange processes are calculated including nucleon resonances in intermediate states, and good agreement of theoretical and experimental predictions for the GT matrix element is found. (Auth.)

HDL-apoA-I exchange: rapid detection and association with atherosclerosis.

Directory of Open Access Journals (Sweden)

Mark S Borja

Full Text Available High density lipoprotein (HDL cholesterol levels are associated with decreased risk of cardiovascular disease, but not all HDL are functionally equivalent. A primary determinant of HDL functional status is the conformational adaptability of its main protein component, apoA-I, an exchangeable apolipoprotein. Chemical modification of apoA-I, as may occur under conditions of inflammation or diabetes, can severely impair HDL function and is associated with the presence of cardiovascular disease. Chemical modification of apoA-I also impairs its ability to exchange on and off HDL, a critical process in reverse cholesterol transport. In this study, we developed a method using electron paramagnetic resonance spectroscopy (EPR to quantify HDL-apoA-I exchange. Using this approach, we measured the degree of HDL-apoA-I exchange for HDL isolated from rabbits fed a high fat, high cholesterol diet, as well as human subjects with acute coronary syndrome and metabolic syndrome. We observed that HDL-apoA-I exchange was markedly reduced when atherosclerosis was present, or when the subject carries at least one risk factor of cardiovascular disease. These results show that HDL-apoA-I exchange is a clinically relevant measure of HDL function pertinent to cardiovascular disease.

Magnetic stability in exchange-spring and exchange bias systems after multiple switching cycles.

Energy Technology Data Exchange (ETDEWEB)

Jiang, J. S.; Inomata, A.; You, C.-Y.; Pearson, J. E.; Bader, S. D.

2001-06-01

We have studied the magnetic stability in exchange bias and exchange spring systems prepared via epitaxial sputter deposition. The two interfacial exchange coupled systems, Fe/Cr(211) double superlattices consisting of a ferromagnetic and an antiferromagnetic Fe/Cr superlattice that are exchange coupled through a Cr spacer, and Sin-Co/Fe exchange-spring bilayer structures with ferromagnetically coupled hard Sin-Co layer and soft Fe layer, were epitaxially grown on suitably prepared Cr buffer layers to give rise to different microstructure and magnetic anisotropy. The magnetic stability was investigated using the magneto-optic Kerr effect during repeated reversal of the soft layer magnetization by field cycling up to 10{sup 7} times. For uniaxial Fe/Cr exchange biased double superlattices and exchange spring bilayers with uniaxial Sin-Co, small but rapid initial decay in the exchange bias field HE and in the remanent magnetization is observed. However, the exchange spring bilayers with biaxial and random in-plane anisotropy in the Sin-Co layer shows gradual decay in H{sub E} and without large reduction of the magnetization. The different decay behaviors are attributed to the different microstructure and spin configuration of the pinning layers.

The effects of real exchange rate misalignment and real exchange volatility on exports

OpenAIRE

Diallo, Ibrahima Amadou

2011-01-01

This paper uses panel data cointegration techniques to study the impacts of real exchange rate misalignment and real exchange rate volatility on total exports for a panel of 42 developing countries from 1975 to 2004. The results show that both real exchange rate misalignment and real exchange rate volatility affect negatively exports. The results also illustrate that real exchange rate volatility is more harmful to exports than misalignment. These outcomes are corroborated by estimations on s...

Impulse Response of the Exchange Rate Volatility to a Foreign Exchange Intervention Shock

OpenAIRE

Hoshikawa, Takeshi

2009-01-01

This paper uses Lin's technique (1997) to report on the impulse response function analysis that traces the dynamics of exchange rate volatility from innovations in Japanese foreign exchange intervention. Using a multivariate GARCH model, we employed a volatility impulse response function based on Lin (1997) to detect the impulse response of exchange rate volatility on a one-unit foreign exchange intervention shock. The main findings of t his paper are as follows: (1) a foreign exchange inter...

Analysis of the Technological Parameters of the Heat Exchanger in the Heating Pipe

Directory of Open Access Journals (Sweden)

Knyazev Vladimir

2017-01-01

Full Text Available The main purpose of this article is to analyze the selecting of technological parameters for the heat exchanger to improve the heat transfer and reduce the noise during operation in the heating pipe, which is used in the different systems of the planes and helicopters. In result of this study, the best technical parameters are found, considering different variations of deformation cutting heat exchanger pipes.

Progress Report for Diffusion Welding of the NGNP Process Application Heat Exchangers

Energy Technology Data Exchange (ETDEWEB)

R.E. Mizia; D.E. Clark; M.V. Glazoff; T.E. Lister; T.L. Trowbridge

2011-12-01

The U.S. Department of Energy selected the high temperature gas-cooled reactor as the basis for the Next Generation Nuclear Plant (NGNP). The NGNP will demonstrate the use of nuclear power for electricity, hydrogen production, and process heat applications. The NGNP Project is currently investigating the use of metallic, diffusion welded, compact heat exchangers to transfer heat from the primary (reactor side) heat transport system to the secondary heat transport system. An intermediate heat exchanger will transfer this heat to downstream applications such as hydrogen production, process heat, and electricity generation. The channeled plates that make up the heat transfer surfaces of the intermediate heat exchanger will have to be assembled into an array by diffusion welding. This report describes the preliminary results of a scoping study that evaluated the diffusion welding process parameters and the resultant mechanical properties of diffusion welded joints using Alloy 800H. The long-term goal of the program is to progress towards demonstration of small heat exchanger unit cells fabricated with diffusion welds. Demonstration through mechanical testing of the unit cells will support American Society of Mechanical Engineers rules and standards development, reduce technical risk, and provide proof of concept for heat exchanger fabrication methods needed to deploy heat exchangers in several potential NGNP configurations.1 Researchers also evaluated the usefulness of modern thermodynamic and diffusion computational tools (Thermo-Calc and Dictra) in optimizing the parameters for diffusion welding of Alloy 800H. The modeling efforts suggested a temperature of 1150 C for 1 hour with an applied pressure of 5 MPa using 15 {micro}m nickel foil as joint filler to reduce chromium oxidation on the welded surfaces. Good agreement between modeled and experimentally determined concentration gradients was achieved

Experimental Characterization and Modelization of Ion Exchange Kinetics for a Carboxylic Resin in Infinite Solution Volume Conditions. Application to Monovalent-Trivalent Cations Exchange

Energy Technology Data Exchange (ETDEWEB)

Picart, S.; Mokhtari, H.; Jobelin, I. [CEA Marcoule, Nucl Energy Div, RadioChem and Proc Dept, Actinides Chem and Convers Lab, F-30207 Bagnols Sur Ceze (France); Ramiere, I. [Fuel Simulat Lab, Fuel Study Dept, F-13108 St Paul Les Durance (France)

2010-07-01

This study is devoted to the characterization of ion exchange inside a microsphere of carboxylic resin. It aims at describing the kinetics of this exchange reaction which is known to be controlled by interdiffusion in the particle. The fractional attainment of equilibrium function of time depends on the concentration of the cations in the resin which can be modelled by the Nernst-Planck equation. A powerful approach for the numerical resolution of this equation is introduced in this paper. This modeling is based on the work of Helfferich but involves an implicit numerical scheme which reduces the computational cost. Knowing the diffusion coefficients of the cations in the resin and the radius of the spherical exchanger, the kinetics can be hence completely determined. When those diffusion parameters are missing, they can be deduced by fitting experimental data of fractional attainment of equilibrium. An efficient optimization tool coupled with the implicit resolution has been developed for this purpose. A monovalent/trivalent cation exchange had been experimentally characterized for a carboxylic resin. Diffusion coefficients and concentration profiles in the resin were then deduced through this new model. (authors)

Experimental Characterization and Modelization of Ion Exchange Kinetics for a Carboxylic Resin in Infinite Solution Volume Conditions. Application to Monovalent-Trivalent Cations Exchange

International Nuclear Information System (INIS)

Picart, S.; Mokhtari, H.; Jobelin, I.; Ramiere, I.

2010-01-01

This study is devoted to the characterization of ion exchange inside a microsphere of carboxylic resin. It aims at describing the kinetics of this exchange reaction which is known to be controlled by interdiffusion in the particle. The fractional attainment of equilibrium function of time depends on the concentration of the cations in the resin which can be modelled by the Nernst-Planck equation. A powerful approach for the numerical resolution of this equation is introduced in this paper. This modeling is based on the work of Helfferich but involves an implicit numerical scheme which reduces the computational cost. Knowing the diffusion coefficients of the cations in the resin and the radius of the spherical exchanger, the kinetics can be hence completely determined. When those diffusion parameters are missing, they can be deduced by fitting experimental data of fractional attainment of equilibrium. An efficient optimization tool coupled with the implicit resolution has been developed for this purpose. A monovalent/trivalent cation exchange had been experimentally characterized for a carboxylic resin. Diffusion coefficients and concentration profiles in the resin were then deduced through this new model. (authors)

MULTIFRACTAL STRUCTURE OF CENTRAL AND EASTERN EUROPEAN FOREIGN EXCHANGE MARKETS

Directory of Open Access Journals (Sweden)

Cn#259;pun#351;an Rn#259;zvan

2012-07-01

Full Text Available It is well known that empirical data coming from financial markets, like stock market indices, commodities, interest rates, traded volumes and foreign exchange rates have a multifractal structure. Multifractals were introduced in the field of economics to surpass the shortcomings of classical models like the fractional Brownian motion or GARCH processes. In this paper we investigate the multifractal behavior of Central and Eastern European foreign exchange rates, namely the Czech koruna, Croatian kuna, Hungarian forint, Polish zlot, Romanian leu and Russian rouble with respect to euro from January 13, 2000 to February 29, 2012. The dynamics of exchange rates is of interest for investors and traders, monetary and fiscal authorities, economic agents or policy makers. The exchange rate movements affect the international balance of payments, trade flows, and allocation of the resources in national and international economy. The empirical results from the multifractal detrending fluctuation analysis algorithm show that the six exchange rate series analysed display significant multifractality. Moreover, generating shuffled and surrogate time series, we analyze the sources of multifractality, long-range correlations and heavy-tailed distributions, and we find that this multifractal behavior can be mainly attributed to the latter. Finally, we propose a foreign exchange market inefficiency ranking by considering the multifractality degree as a measure of inefficiency. The regulators, through policy instruments, aim to improve the informational inefficiency of the markets, to reduce the associated risks and to ensure economic stabilization. Evaluation of the degree of information efficiency of foreign exchange markets, for Central and Eastern Europe countries, is important to assess to what extent these countries are prepared for the transition towards fully monetary integration. The weak form efficiency implies that the past exchange rates cannot help to

Two-dimensional exchange and nutation exchange nuclear quadrupole resonance spectroscopy

International Nuclear Information System (INIS)

Mackowiak, M.; Sinyavsky, N.; Velikite, N.; Nikolaev, D.

2002-01-01

A theoretical treatment of the 2D exchange NQR pulse sequence is presented and applied to a quantitative study of exchange processes in molecular crystals. It takes into account the off-resonance irradiation, which critically influences the spin dynamics. The response to the three-pulse sequence of a system of spins I=3/2 in zero applied field, experiencing electric quadrupole couplings, is analysed. The mixing dynamics by exchange and the expected cross-peak intensities as a function of the frequency offset have been derived. The theory is illustrated by a study of the optimization procedure, which is of crucial importance for the detection of the cross- and diagonal-peaks in a 2D-exchange spectrum. The systems investigated are hexachloroethane and tetrachloroethylene. They show threefold and twofold reorientational jumps about the carbon-carbon axis, respectively. A new method of direct determination of rotational angles based on two-dimensional nutation exchange NQR spectroscopy is proposed. The method involves the detection of exchange processes through NQR nutation spectra recorded after the mixing interval. The response of a system of spins I=3/2 to the three-pulse sequence with increasing pulse widths is analyzed. It is shown that the 2D-nutation exchange NQR spectrum exhibits characteristic ridges, which manifest the motional mechanism in a model-independent fashion. The angles through which the molecule rotates can be read directly from elliptical ridges in the 2D spectrum, which are also sensitive to the asymmetry parameter of the electric field gradient tensor. (orig.)

The role of time-dependent deformation in intergranular crack initiation of alloy 600 steam generator tubing material

International Nuclear Information System (INIS)

Was, G.S.; Lian, K.

1998-03-01

Intergranular stress corrosion cracking (IGSCC) of two commercial alloy 600 conditions (600LT, 600HT) and controlled- purity Ni-18Cr-9Fe alloys (CDMA, CDTT) were investigated using constant extension rate tensile (CERT) tests in primary water (0.01M LiOH+0.01M H 3 BO 3 ) with 1 bar hydrogen overpressure at 360 degrees C and 320 degrees C. Heat treatments produced two types of microstructures in both commercial and controlled-purity alloys: one dominated by grain boundary carbides (600HT and CDTT) and one dominated by intragranular carbides (600LT and CDMA). CERT tests were conducted over a range of strain rates and at two temperatures with interruptions at specific strains to determine the crack depth distributions. Results show that in all samples, IGSCC was the dominant failure mode. For both the commercial alloy and the controlled-purity alloys, the microstructure with grain boundary carbides showed delayed crack initiation and shallower crack depths than did the intragranular carbide microstructure under all experimental conditions. This data indicates that a grain boundary carbide microstructure is more resistant to IGSCC than an intragranular carbide microstructure. Observations support both the film rupture/slip dissolution mechanism and enhanced localized plasticity. The advantage of these results over previous studies is that the different carbide distributions were obtained in the same commercial alloy using different heat treatments, and in the other case, in nearly identical controlled-purity alloys. Therefore, observations of the effects of carbide distribution on IGSCC can more confidently be attributed to the carbide distribution alone rather than other potentially significant differences in microstructure or composition

Control and prevention of ice formation and accretion on heat exchangers for ventilation systems

DEFF Research Database (Denmark)

Rahimi, Maral; Afshari, Alireza

2015-01-01

In cold climates, the application of mechanical ventilation systems with heat recovery like are airto-air exchangers is used for reducing energy consumption for heating buildings by transferring heat exhausted air to supply air. However, increase efficiency of heat exchanger results in lower...... exhaust air temperatures and Ice formation on heat exchanger fins, which can cause problem and is not favourable. Therefore, prevention and control of ice formation on heat exchangers is necessary. The existing methods are divided into two different methods: active and passive ice control methods....... The active methods are e.g. bypass, recirculation, preheating. The passive methods relate to the surface characteristics of the heat exchanger fins as they have effect on ice formation in initial phase. All these methods have varying levels of success, cost, and effectiveness, which are depending on the heat...

Thermal Analysis for Ion-Exchange Column System

Energy Technology Data Exchange (ETDEWEB)

Lee, Si Y.; King, William D.

2012-12-20

Models have been developed to simulate the thermal characteristics of crystalline silicotitanate ion exchange media fully loaded with radioactive cesium either in a column configuration or distributed within a waste storage tank. This work was conducted to support the design and operation of a waste treatment process focused on treating dissolved, high-sodium salt waste solutions for the removal of specific radionuclides. The ion exchange column will be installed inside a high level waste storage tank at the Savannah River Site. After cesium loading, the ion exchange media may be transferred to the waste tank floor for interim storage. Models were used to predict temperature profiles in these areas of the system where the cesium-loaded media is expected to lead to localized regions of elevated temperature due to radiolytic decay. Normal operating conditions and accident scenarios (including loss of solution flow, inadvertent drainage, and loss of active cooling) were evaluated for the ion exchange column using bounding conditions to establish the design safety basis. The modeling results demonstrate that the baseline design using one central and four outer cooling tubes provides a highly efficient cooling mechanism for reducing the maximum column temperature. In-tank modeling results revealed that an idealized hemispherical mound shape leads to the highest tank floor temperatures. In contrast, even large volumes of CST distributed in a flat layer with a cylindrical shape do not result in significant floor heating.

Polarization tests of one-particle-exchange mechanisms

International Nuclear Information System (INIS)

Goldstein, G.R.; Moravcsik, M.J.

1984-01-01

Since one-particle-exchange (OPE) mechanisms are predominant in all aspects of elementary-particle dynamics, a novel class of polarization tests is proposed for such mechanisms. They test whether a single particle of total angular momentum J is exchanged (''J constraints'') and whether the process can be factorized into two vertices (''factorization constraints''), but the tests are independent of more detailed dynamical features such as the exact nature of the coupling at the vertices. Except for a restricted type of processes containing some low spin values, the constraints reduce the number of reaction amplitudes and offer tests of OPE which are independent of the value of J. The tests have a particularly simple form in a ''magic'' formalism in which the quantization directions of the particles are in the reaction plane and are rotated from the helicity directions by a ''magic'' angle which can be easily specified for a given s and t. The tests consist of measuring whether a certain polarization quantity vanishes or not, thus providing sensitive ''null experiments'' for the exploration of particle dynamics. The results are illustrated on the popular reaction (1/2)+(1/2)→(1/2)+(1/2), which is embodied, for example, in elastic nucleon-nucleon scattering. The tests can be used either for one single-exchange mechanism or for a combination of such mechanisms (even if they involve different J exchanges), as long as they all have the same type of parity

Econometric analysis of exchange rate in Serbia and its influence on agricultural sector

Directory of Open Access Journals (Sweden)

Pažun Brankica

2016-01-01

Full Text Available This paper attempts to empirically estimate equilibrium exchange rate level of Serbian dinar. In that purpose reduced form equilibrium real exchange rate approach (ERER is used, developed by IMF's Consultative Group on Exchange Rate Issues (CGER. The research was made by using ARDL approach in the single-country analysis. It has been started from dynamic model which has described relation between real effective exchange rate and a set of fundamental variables. Bound test has been provided due to determination of the long-term relationship existence between variables. F-statistics has been used for long-term relationship testing between dependent variable and set of indicators. Since assumptions were met, least squares method was used for coefficient estimation. The results have shown constant dinar's overvaluation over medium term.

Noninvasive mapping of water diffusional exchange in the human brain using filter-exchange imaging.

Science.gov (United States)

Nilsson, Markus; Lätt, Jimmy; van Westen, Danielle; Brockstedt, Sara; Lasič, Samo; Ståhlberg, Freddy; Topgaard, Daniel

2013-06-01

We present the first in vivo application of the filter-exchange imaging protocol for diffusion MRI. The protocol allows noninvasive mapping of the rate of water exchange between microenvironments with different self-diffusivities, such as the intracellular and extracellular spaces in tissue. Since diffusional water exchange across the cell membrane is a fundamental process in human physiology and pathophysiology, clinically feasible and noninvasive imaging of the water exchange rate would offer new means to diagnose disease and monitor treatment response in conditions such as cancer and edema. The in vivo use of filter-exchange imaging was demonstrated by studying the brain of five healthy volunteers and one intracranial tumor (meningioma). Apparent exchange rates in white matter range from 0.8±0.08 s(-1) in the internal capsule, to 1.6±0.11 s(-1) for frontal white matter, indicating that low values are associated with high myelination. Solid tumor displayed values of up to 2.9±0.8 s(-1). In white matter, the apparent exchange rate values suggest intra-axonal exchange times in the order of seconds, confirming the slow exchange assumption in the analysis of diffusion MRI data. We propose that filter-exchange imaging could be used clinically to map the water exchange rate in pathologies. Filter-exchange imaging may also be valuable for evaluating novel therapies targeting the function of aquaporins. Copyright © 2012 Wiley Periodicals, Inc.

Students as effective harm reductionists and needle exchange organizers.

Science.gov (United States)

Barbour, Kyle; McQuade, Miriam; Brown, Brandon

2017-03-17

Needle exchange programs are safe, highly effective programs for promoting health among people who inject drugs. However, they remain poorly funded, and often illegal, in many places worldwide due to fear and stigma surrounding drug use. Continued advocacy, education, and implementation of new needle exchanges are thus essential to improve public health and reduce structural inequality. We argue that students, and especially professional and graduate students, have the potential to play an important role in advancing harm reduction. Students benefit from the respect given to the professions they are training to enter, which gives them leverage to navigate the political hurdles often faced by needle exchange organizers, especially in areas that presently lack services. In addition, due to their relative simplicity, needle exchanges do not require much of the licensing, clinical knowledge, and infrastructure associated with more traditional student programs, such as student-run free medical clinics. Students are capable of learning harm reduction cultural approaches and techniques if they remain humble, open-minded, and seek the help of the harm reduction community. Consequently, students can generate tremendous benefits to their community without performing beyond their appropriate clinical limitations. Students benefit from organizing needle exchanges by gaining applied experience in advocacy, organization-building, and political finesse. Working in a needle exchange significantly helps erode stigma against multiple marginalized populations. Students in health-related professions additionally learn clinically-relevant knowledge that is often lacking from their formal training, such as an understanding of structural violence and inequality, root causes of substance use, client-centered approaches to health services, and interacting with clients as peers, rather than through the standard hierarchical medical interaction. We therefore encourage students to learn about

Sediment exchange to mitigate pollutant exposure in urban soil.

Science.gov (United States)

Walsh, Daniel; Glass, Katherine; Morris, Samantha; Zhang, Horace; McRae, Isabel; Anderson, Noel; Alfieri, Alysha; Egendorf, Sara Perl; Holberton, Shana; Owrang, Shahandeh; Cheng, Zhongqi

2018-05-15

Urban soil is an ongoing source for lead (Pb) and other pollutant exposure. Sources of clean soil that are locally-available, abundant and inexpensive are needed to place a protective cover layer over degraded urban soil to eliminate direct and indirect pollutant exposures. This study evaluates a novel sediment exchange program recently established in New York City (NYC Clean Soil Bank, CSB) and found that direct exchange of surplus sediment extracted from urban construction projects satisfies these criteria. The CSB has high total yield with 4.2 × 10 5  t of sediment exchanged in five years. Average annual yield (8.5 × 10 4  t yr -1 ) would be sufficient to place a 15-cm (6-in.) sediment cover layer over 3.2 × 10 5  m 2 (80 acres) of impacted urban soil or 1380 community gardens. In a case study of sediment exchange to mitigate community garden soil contamination, Pb content in sediment ranged from 2 to 5 mg kg -1 . This sediment would reduce surface Pb concentrations more than 98% if it was used to encapsulate soil with Pb content exceeding USEPA residential soil standards (400 mg kg -1 ). The maximum observed sediment Pb content is a factor of 42 and 71 lower than median surface soil and garden soil in NYC, respectively. All costs (transportation, chemical testing, etc.) in the CSB are paid by the donor indicating that urban sediment exchange could be an ultra-low-cost source for urban soil mitigation. Urban-scale sediment exchange has advantages over existing national- or provincial-scale sediment exchanges because it can retain and upcycle local sediment resources to attain their highest and best use (e.g. lowering pollutant exposure), achieve circular urban materials metabolism, improve livability and maximize urban sustainability. Published by Elsevier Ltd.

The mean-size dependence of the exchange narrowing in molecular J-aggregates

International Nuclear Information System (INIS)

Chen Yulu; Zhao Jijun

2011-01-01

The effect of segment-size fluctuations on exchange narrowing in a molecular J-aggregate of site-energy disordered distributions is studied using a one-dimensional Frenkel-exciton model. It is found that the segment-size disorder leads to the width of the absorption spectra deviating from the scaling law, σ 4/3 of the site-energy disordered standard deviation σ, being suitable for the system only with the site-energy disorder. In larger σ, the segment-size disorder has little influence on the linear absorption spectra. With increasing segment mean-length, the absorption line width monotonically increases, and then approaches a saturated value. By comparing a system of larger mean-length segment with a smaller one, both with the same segment-size disorder, it is found that the absorption line width of the former is broadened, and the exchange narrowing effect is reduced. The present result shows that the correlation effect can be partially maintained for the system with larger mean-length segment. -- Research Highlights: → Segment fluctuations affect the exchange narrowing of molecular J-aggregates. → The width of the absorption spectra is found to deviate from the scaling law. → Increase in segment size causes increase in the width and then saturates. → Exchange narrowing is reduced for larger mean-size segment. → Correlation can be kept partly in the larger size segment.

The sodium-calcium exchanger is a mechanosensitive transporter.

Science.gov (United States)

Reeves, John P; Abdellatif, Maha; Condrescu, Madalina

2008-03-15

This report describes the influence of fluid flow and osmotically induced volume changes on Na(+)-Ca(2+) exchange (NCX) activity in transfected CHO cells. Exchange activity was measured as Na(+)-dependent Ca(2+) or Ba(2+) fluxes using the fluorescent probe fura-2. When exchange activity was initiated by superfusing Ba(2+)-containing solutions over the cells for a 20 s interval, a high rate of Ba(2+) uptake was observed while the solution was being applied but the rate of Ba(2+) uptake declined > 10-fold when the solution flow ceased. Ba(2+) efflux in exchange for extracellular Na(+) or Ca(2+) (Ba(2+)-Ca(2+) exchange) was similarly biphasic. During NCX-mediated Ca(2+) uptake, a rapid increase in cytosolic [Ca(2+)] to a peak value occurred, followed by a decline in [Ca(2+)](i) to a lower steady-state value after solution flow ceased. When NCX activity was initiated by an alternate procedure that minimized the duration of solution flow, the rapid phase of Ba(2+) influx was greatly reduced in magnitude and Ca(2+) uptake became nearly monophasic. Solution superfusion did not produce any obvious changes in cell shape or volume. NCX-mediated Ba(2+) and Ca(2+) influx were also sensitive to osmotically induced changes in cell volume. NCX activity was stimulated in hypotonic media and inhibited in hypertonic media; the osmotically induced changes in activity occurred within seconds and were rapidly reversible. We conclude that NCX activity is modulated by both solution flow and osmotically induced volume changes.

Optimization of Heat Exchangers

International Nuclear Information System (INIS)

Catton, Ivan

2010-01-01

The objective of this research is to develop tools to design and optimize heat exchangers (HE) and compact heat exchangers (CHE) for intermediate loop heat transport systems found in the very high temperature reator (VHTR) and other Generation IV designs by addressing heat transfer surface augmentation and conjugate modeling. To optimize heat exchanger, a fast running model must be created that will allow for multiple designs to be compared quickly. To model a heat exchanger, volume averaging theory, VAT, is used. VAT allows for the conservation of mass, momentum and energy to be solved for point by point in a 3 dimensional computer model of a heat exchanger. The end product of this project is a computer code that can predict an optimal configuration for a heat exchanger given only a few constraints (input fluids, size, cost, etc.). As VAT computer code can be used to model characteristics (pumping power, temperatures, and cost) of heat exchangers more quickly than traditional CFD or experiment, optimization of every geometric parameter simultaneously can be made. Using design of experiment, DOE and genetric algorithms, GE, to optimize the results of the computer code will improve heat exchanger design.

Gas exchange under water. Acclimation of terrestrial plants to submergence

NARCIS (Netherlands)

Mommer, L.

2005-01-01

Gas exchange between the plant and the environment is severely hampered when plants are submerged, leading to oxygen and energy deficits. A straightforward way to reduce these shortages of oxygen and carbohydrates would be prolonged photosynthesis under water, but this has received only little

Probable causes of damage of heat-exchange tubes of low-pressure-exchanges of PND-3 type and repair methods

Science.gov (United States)

Trifonov, N. N.; Esin, S. B.; Nikolaenkova, E. K.; Sukhorukov, Yu. G.; Svyatkin, F. A.; Sintsova, T. G.; Modestov, V. S.

2017-08-01

The structures of low-pressure heaters (LPH), which are installed at nuclear power plants with the K-1000-60/1500 type turbine plants are considered. It was revealed that only the PND-3 type low-pressure heaters have the damages of the heat exchange tubes. For a short operation life, the number of the damaged heat-exchange tubes of PND-3 is approximately 50 pcs for Kalinin NPP and 100-150 pcs for Balakovo NPP. The low-pressure heaters were manufactured at AO Ural Plant of Chemical Machine-Building "Uralkhimmash," OAO Taganrog Boiler-Making Works "Krasny Kotelshchik," and Vitkovice Machinery Group, but the damage nature of the heat-exchange tubes is identical for all PND-3. The damages occur in the place of passage of the heat exchange tubes through the first, the second, and the third partitions over the lower tube plate (the first path of the turbine condensate). Hydraulic shocks can be one of the possible causes of the damage of the heat-exchange tubes of PND-3. The analysis of the average thermal and dynamic loads of the tube systems of PND-1-PND-4 revealed that PND-3 by the thermal power are loaded 1.4-1.6 times and by the dynamic effects are loaded 1.8-2.0 times more than the remaining LPHs. Another possible cause of damage can be the cascaded drain of the separate into PND-4 and then through the drainage heat exchange into PND-3. An additional factor can be the structure of the condensate drainage unit. The advanced system of the heating steam flow and pumping scheme of the separate drain using the existing drainage pumps of PND-3 for K-1000-60/1500 turbine plants for Balakovo and Kalinin NPPs were proposed. The considered decisions make it possible to reduce the flow rate of the heating steam condensate from PND-3 into PND-4 and the speed of the heating steam in the tube space of PND-3 and eliminate the occurrence of hydraulic shocks and damages of the heat exchanger tubes.

Time-series analysis of multiple foreign exchange rates using time-dependent pattern entropy

Science.gov (United States)

Ishizaki, Ryuji; Inoue, Masayoshi

2018-01-01

Time-dependent pattern entropy is a method that reduces variations to binary symbolic dynamics and considers the pattern of symbols in a sliding temporal window. We use this method to analyze the instability of daily variations in multiple foreign exchange rates. The time-dependent pattern entropy of 7 foreign exchange rates (AUD/USD, CAD/USD, CHF/USD, EUR/USD, GBP/USD, JPY/USD, and NZD/USD) was found to be high in the long period after the Lehman shock, and be low in the long period after Mar 2012. We compared the correlation matrix between exchange rates in periods of high and low of the time-dependent pattern entropy.

Optimization of shell-and-tube heat exchangers conforming to TEMA standards with designs motivated by constructal theory

International Nuclear Information System (INIS)

Yang, Jie; Fan, Aiwu; Liu, Wei; Jacobi, Anthony M.

2014-01-01

Highlights: • A design method of heat exchangers motivated by constructal theory is proposed. • A genetic algorithm is applied and the TEMA standards are rigorously followed. • Three cases are studied to illustrate the advantage of the proposed design method. • The design method will reduce the total cost compared to two other methods. - Abstract: A modified optimization design approach motivated by constructal theory is proposed for shell-and-tube heat exchangers in the present paper. In this method, a shell-and-tube heat exchanger is divided into several in-series heat exchangers. The Tubular Exchanger Manufacturers Association (TEMA) standards are rigorously followed for all design parameters. The total cost of the whole shell-and-tube heat exchanger is set as the objective function, including the investment cost for initial manufacture and the operational cost involving the power consumption to overcome the frictional pressure loss. A genetic algorithm is applied to minimize the cost function by adjusting parameters such as the tube and shell diameters, tube length and tube arrangement. Three cases are studied which indicate that the modified design approach can significantly reduce the total cost compared to the original design method and traditional genetic algorithm design method

A Liquid-Liquid Thermoelectric Heat Exchanger as a Heat Pump for Testing Phase Change Material Heat Exchangers

Science.gov (United States)

Sheth, Rubik B.; Makinen, Janice; Le, Hung V.

2016-01-01

The primary objective of the Phase Change HX payload on the International Space Station (ISS) is to test and demonstrate the viability and performance of Phase Change Material Heat Exchangers (PCM HX). The system was required to pump a working fluid through a PCM HX to promote the phase change material to freeze and thaw as expected on Orion's Multipurpose Crew Vehicle. Due to limitations on ISS's Internal Thermal Control System, a heat pump was needed on the Phase Change HX payload to help with reducing the working fluid's temperature to below 0degC (32degF). This paper will review the design and development of a TEC based liquid-liquid heat exchanger as a way to vary to fluid temperature for the freeze and thaw phase of the PCM HX. Specifically, the paper will review the design of custom coldplates and sizing for the required heat removal of the HX.

Development of a High-Throughput Ion-Exchange Resin Characterization Workflow.

Science.gov (United States)

Liu, Chun; Dermody, Daniel; Harris, Keith; Boomgaard, Thomas; Sweeney, Jeff; Gisch, Daryl; Goltz, Bob

2017-06-12

A novel high-throughout (HTR) ion-exchange (IEX) resin workflow has been developed for characterizing ion exchange equilibrium of commercial and experimental IEX resins against a range of different applications where water environment differs from site to site. Because of its much higher throughput, design of experiment (DOE) methodology can be easily applied for studying the effects of multiple factors on resin performance. Two case studies will be presented to illustrate the efficacy of the combined HTR workflow and DOE method. In case study one, a series of anion exchange resins have been screened for selective removal of NO 3 - and NO 2 - in water environments consisting of multiple other anions, varied pH, and ionic strength. The response surface model (RSM) is developed to statistically correlate the resin performance with the water composition and predict the best resin candidate. In case study two, the same HTR workflow and DOE method have been applied for screening different cation exchange resins in terms of the selective removal of Mg 2+ , Ca 2+ , and Ba 2+ from high total dissolved salt (TDS) water. A master DOE model including all of the cation exchange resins is created to predict divalent cation removal by different IEX resins under specific conditions, from which the best resin candidates can be identified. The successful adoption of HTR workflow and DOE method for studying the ion exchange of IEX resins can significantly reduce the resources and time to address industry and application needs.

Ferromagnetism and interlayer exchange coupling in thin metallic films

Energy Technology Data Exchange (ETDEWEB)

Kienert, Jochen

2008-07-15

This thesis is concerned with the ferromagnetic Kondo lattice (s-d,s-f) model for film geometry. The spin-fermion interaction of this model refers to substances in which localized spins interact with mobile charge carriers like in (dilute) magnetic semiconductors, manganites, or rare-earth compounds. The carrier-mediated, indirect interaction between the localized spins comprises the long-range, oscillatory RKKY exchange interaction in the weak-coupling case and the short-range doubleexchange interaction for strong spin-fermion coupling. Both limits are recovered in this work by mapping the problem onto an effective Heisenberg model. The influence of reduced translational symmetry on the effective exchange interaction and on the magnetic properties of the ferromagnetic Kondo lattice model is investigated. Curie temperatures are obtained for different parameter constellations. The consequences of charge transfer and of lattice relaxation on the magnetic stability at the surface are considered. Since the effective exchange integrals are closely related to the electronic structure in terms of the density of states and of the kinetic energy, the discussion is based on the modifications of these quantities in the dimensionally-reduced case. The important role of spin waves for thin film and surface magnetism is demonstrated. Interlayer exchange coupling represents a particularly interesting and important manifestation of the indirect interaction among localized magnetic moments. The coupling between monatomic layers in thin films is studied in the framework of an RKKY approach. It is decisively determined by the type of in-plane and perpendicular dispersion of the charge carriers and is strongly suppressed above a critical value of the Fermi energy. Finally, the temperature-dependent magnetic stability of thin interlayer-coupled films is addressed and the conditions for a temperature-driven magnetic reorientation transition are discussed. (orig.)

Health literacy in the "oral exchange": an important element of patient-provider communication.

Science.gov (United States)

Nouri, Sarah S; Rudd, Rima E

2015-05-01

Oral communication between health care providers and patients--the "oral exchange"--greatly impacts patient health outcomes; however, only recently have health literacy inquiries been incorporated into this field. This review examines the intersection between oral and aural literacy and the oral exchange. A systematic literature search was carried out. Papers published in English since 2003 that specifically examine oral/aural literacy and oral patient-provider communication were included. The search yielded 999 articles, 12 of which were included in this review. Three tools have been developed to measure either patient or provider oral/aural literacy. There is a discrepancy between patient and provider oral/aural literacy levels, and high literacy demand is associated with reduced patient learning. Low patient oral/aural literacy is associated with poor health outcomes. Two interventions have been developed to reduce literacy demand. This review demonstrates the critical role of oral and aural literacy in the oral exchange, the importance of reducing literacy demand, and the need for future research in this field. Recommendations include the use of plain language and teach-back by providers, as well as incorporation of awareness of oral and aural literacy into community programs and health care provider education and training. Copyright © 2015 Elsevier Ireland Ltd. All rights reserved.

Investigation of thermally sensitised stainless steels as analogues for spent AGR fuel cladding to test a corrosion inhibitor for intergranular stress corrosion cracking

Science.gov (United States)

Whillock, Guy O. H.; Hands, Brian J.; Majchrowski, Tom P.; Hambley, David I.

2018-01-01

A small proportion of irradiated Advanced Gas-cooled Reactor (AGR) fuel cladding can be susceptible to intergranular stress corrosion cracking (IGSCC) when stored in pond water containing low chloride concentrations, but corrosion is known to be prevented by an inhibitor at the storage temperatures that have applied so far. It may be necessary in the future to increase the storage temperature by up to ∼20 °C and to demonstrate the impact of higher temperatures for safety case purposes. Accordingly, corrosion testing is needed to establish the effect of temperature increases on the efficacy of the inhibitor. This paper presents the results of studies carried out on thermally sensitised 304 and 20Cr-25Ni-Nb stainless steels, investigating their grain boundary compositions and their IGSCC behaviour over a range of test temperatures (30-60 °C) and chloride concentrations (0.3-10 mg/L). Monitoring of crack initiation and propagation is presented along with preliminary results as to the effect of the corrosion inhibitor. 304 stainless steel aged for 72 h at 600 °C provided a close match to the known pond storage corrosion behaviour of spent AGR fuel cladding.

Foreign Exchange Speculation: An Event Study

Directory of Open Access Journals (Sweden)

Rob Hayward

2018-02-01

Full Text Available Does speculation facilitate price discovery or instability? If it is price discovery, it is beneficial and should be encouraged; if it is instability, welfare is enhanced by its reduction. This paper seeks to distinguish between these two characteristics by analysing those times when speculation in the foreign exchange market is most extreme. A series of event studies are conducted on the extremes of speculative sentiment and speculative activity. If speculation is noise, extreme sentiment and extreme positions should lead to overshooting and increase risk of subsequent reversals. The finding that speculative extremes do not provide information about subsequent returns implies that speculation is part of the process of price discovery and that efforts to reduce it would reduce the informational efficiency of financial markets.

Chemical exchange rotation transfer imaging of intermediate-exchanging amines at 2 ppm.

Science.gov (United States)

Zu, Zhongliang; Louie, Elizabeth A; Lin, Eugene C; Jiang, Xiaoyu; Does, Mark D; Gore, John C; Gochberg, Daniel F

2017-10-01

Chemical exchange saturation transfer (CEST) imaging of amine protons exchanging at intermediate rates and whose chemical shift is around 2 ppm may provide a means of mapping creatine. However, the quantification of this effect may be compromised by the influence of overlapping CEST signals from fast-exchanging amines and hydroxyls. We aimed to investigate the exchange rate filtering effect of a variation of CEST, named chemical exchange rotation transfer (CERT), as a means of isolating creatine contributions at around 2 ppm from other overlapping signals. Simulations were performed to study the filtering effects of CERT for the selection of transfer effects from protons of specific exchange rates. Control samples containing the main metabolites in brain, bovine serum albumin (BSA) and egg white albumen (EWA) at their physiological concentrations and pH were used to study the ability of CERT to isolate molecules with amines at 2 ppm that exchange at intermediate rates, and corresponding methods were used for in vivo rat brain imaging. Simulations showed that exchange rate filtering can be combined with conventional filtering based on chemical shift. Studies on samples showed that signal contributions from creatine can be separated from those of other metabolites using this combined filter, but contributions from protein amines may still be significant. This exchange filtering can also be used for in vivo imaging. CERT provides more specific quantification of amines at 2 ppm that exchange at intermediate rates compared with conventional CEST imaging. Copyright © 2017 John Wiley & Sons, Ltd.

Ion exchange kinetics of alkaline earths on Zr(IV) arsenosilicate cation exchanger

International Nuclear Information System (INIS)

Varshney, K.G.; Agrawal, S.; Varshney, K.

1984-01-01

A new approach based on the Nernst-Planck equations was applied to study the ion exchange kinetics for the exchange reactions of Mg(II), Ca(II), Sr(II) and Ba(II) with H + -ions at various temperatures on the zirconium(IV) arsenosilicate phase. Under the conditions of particle diffusion, the rate of exchange was found to be independent of the metal ion concentration at and above 0.1 M in aqueous medium. Energy and entropy of activation were determined and found to vary linearly with the ionic radii and mobilities of alkaline earths, a unique feature observed for an inorganic ion exchanger. The results are useful for predicting the ion exchange processes occurring on the surface of an inorganic material of the type studied. (author)

Differential multiple quantum relaxation caused by chemical exchange outside the fast exchange limit

International Nuclear Information System (INIS)

Wang Chunyu; Palmer, Arthur G.

2002-01-01

Differential relaxation of multiple quantum coherences is a signature for chemical exchange processes in proteins. Previous analyses of experimental data have used theoretical descriptions applicable only in the limit of fast exchange. Theoretical expressions for differential relaxation rate constants that are accurate outside fast exchange are presented for two-spin-system subject to two-site chemical exchange. The theoretical expressions are validated using experimental results for 15 N- 1 H relaxation in basic pancreatic trypsin inhibitor. The new theoretical expression is valuable for identification and characterization of exchange processes in proteins using differential relaxation of multiple quantum coherences

Outlook for ion exchange

International Nuclear Information System (INIS)

Kunin, R.

1977-01-01

This paper presents the history and theory of ion exchange technology and discusses the usefulness of ion exchange resins which found broad applications in chemical operations. It is demonstrated that the theory of ion exchange technology seems to be moving away from the physical chemist back to the polymer chemist where it started originally. This but confronted the polymer chemists with some knotty problems. It is pointed out that one has still to learn how to use ion exchange materials as efficiently as possible in terms of the waste load that is being pumped into the environment. It is interesting to note that, whereas ion exchange is used for abating pollution, it is also a polluter. One must learn how to use ion exchange as an antipollution device, and at the same time minimize its polluting properties

Longitudinal exchange: an alternative strategy towards quantification of dynamics parameters in ZZ exchange spectroscopy

International Nuclear Information System (INIS)

Kloiber, Karin; Spitzer, Romana; Grutsch, Sarina; Kreutz, Christoph; Tollinger, Martin

2011-01-01

Longitudinal exchange experiments facilitate the quantification of the rates of interconversion between the exchanging species, along with their longitudinal relaxation rates, by analyzing the time-dependence of direct correlation and exchange cross peaks. Here we present a simple and robust alternative to this strategy, which is based on the combination of two complementary experiments, one with and one without resolving exchange cross peaks. We show that by combining the two data sets systematic errors that are caused by differential line-broadening of the exchanging species are avoided and reliable quantification of kinetic and relaxation parameters in the presence of additional conformational exchange on the ms–μs time scale is possible. The strategy is applied to a bistable DNA oligomer that displays different line-broadening in the two exchanging species.

Analytical applications of ion exchangers

CERN Document Server

Inczédy, J

1966-01-01

Analytical Applications of Ion Exchangers presents the laboratory use of ion-exchange resins. This book discusses the development in the analytical application of ion exchangers. Organized into 10 chapters, this book begins with an overview of the history and significance of ion exchangers for technical purposes. This text then describes the properties of ion exchangers, which are large molecular water-insoluble polyelectrolytes having a cross-linked structure that contains ionic groups. Other chapters consider the theories concerning the operation of ion-exchange resins and investigate th

Gas Transfer in Cellularized Collagen-Membrane Gas Exchange Devices.

Science.gov (United States)

Lo, Justin H; Bassett, Erik K; Penson, Elliot J N; Hoganson, David M; Vacanti, Joseph P

2015-08-01

Chronic lower respiratory disease is highly prevalent in the United States, and there remains a need for alternatives to lung transplant for patients who progress to end-stage lung disease. Portable or implantable gas oxygenators based on microfluidic technologies can address this need, provided they operate both efficiently and biocompatibly. Incorporating biomimetic materials into such devices can help replicate native gas exchange function and additionally support cellular components. In this work, we have developed microfluidic devices that enable blood gas exchange across ultra-thin collagen membranes (as thin as 2 μm). Endothelial, stromal, and parenchymal cells readily adhere to these membranes, and long-term culture with cellular components results in remodeling, reflected by reduced membrane thickness. Functionally, acellular collagen-membrane lung devices can mediate effective gas exchange up to ∼288 mL/min/m(2) of oxygen and ∼685 mL/min/m(2) of carbon dioxide, approaching the gas exchange efficiency noted in the native lung. Testing several configurations of lung devices to explore various physical parameters of the device design, we concluded that thinner membranes and longer gas exchange distances result in improved hemoglobin saturation and increases in pO2. However, in the design space tested, these effects are relatively small compared to the improvement in overall oxygen and carbon dioxide transfer by increasing the blood flow rate. Finally, devices cultured with endothelial and parenchymal cells achieved similar gas exchange rates compared with acellular devices. Biomimetic blood oxygenator design opens the possibility of creating portable or implantable microfluidic devices that achieve efficient gas transfer while also maintaining physiologic conditions.

Incineration of ion exchange resins using concentric burners

International Nuclear Information System (INIS)

Fukasawa, T.; Chino, K.; Kawamura, F.; Kuriyama, O.; Yusa, H.

1985-01-01

A new incineration method, using concentric burners, is studied to reduce the volume of spent ion exchange resins generated from nuclear power plants. Resins are ejected into the center of a propane-oxygen flame and burned within it. The flame length is theoretically evaluated by the diffusion-dominant model. By reforming the burner shape, flame length can be reduced by one-half. The decomposition ratio decreases with larger resin diameters due to the loss of unburned resin from the flame. A flame guide tube is adapted to increase resin holding time in the flame, which improves the decomposition ratio to over 98 wt%

Oil prices and the rise and fall of the U.S. real exchange rate

International Nuclear Information System (INIS)

Amano, R.A.; Norden, S. van.

1993-12-01

It is examined whether a link exists between oil price shocks and the U.S. real effective exchange rate. Data used for the study are described and their time series properties and the long-run explanatory power of oil prices for the real exchange rate are examined. Apparent causal relationships between exchange rates and oil prices are examined. An unrestricted error correction model is reduced until an error correction model with reasonable properties is derived. Results show that the two variables appear to be cointegrated and that causality runs from oil prices to the exchange rate and not vice-versa. The single equation error correction model linking these two variables is stable and captures much of the in- and out-of-sample movement in the exchange rate in dynamic simulation. Tests are presented to show that the error correction model has significant post-sample predictive ability for both the size and sign of changes in the real effective exchange rate. The results suggest that oil prices may have been the dominant source of persistant real exchange rate shocks over the post-Bretton Woods period and that energy prices may have important implications for future work on exchange rate behaviour. 61 refs., 3 figs., 7 tabs

Simulation of high-resolution MFM tip using exchange-spring magnet

Energy Technology Data Exchange (ETDEWEB)

Saito, H. [Faculty of Resource Science and Engineering, Akita University, Akita 010-8502 (Japan)]. E-mail: hsaito@ipc.akita-u.ac.jp; Yatsuyanagi, D. [Faculty of Resource Science and Engineering, Akita University, Akita 010-8502 (Japan); Ishio, S. [Faculty of Resource Science and Engineering, Akita University, Akita 010-8502 (Japan); Ito, A. [Nitto Optical Co. Ltd., Misato, Akita 019-1403 (Japan); Kawamura, H. [Nitto Optical Co. Ltd., Misato, Akita 019-1403 (Japan); Ise, K. [Research Institute of Advanced Technology Akita, Akita 010-1623 (Japan); Taguchi, K. [Research Institute of Advanced Technology Akita, Akita 010-1623 (Japan); Takahashi, S. [Research Institute of Advanced Technology Akita, Akita 010-1623 (Japan)

2007-03-15

The transfer function of magnetic force microscope (MFM) tips using an exchange-spring trilayer composed of a centered soft magnetic layer and two hard magnetic layers was calculated and the resolution was estimated by considering the thermodynamic noise limit of an MFM cantilever. It was found that reducing the thickness of the centered soft magnetic layer and the magnetization of hard magnetic layer are important to obtain high resolution. Tips using an exchange-spring trilayer with a very thin FeCo layer and isotropic hard magnetic layers, such as CoPt and FePt, are found to be suitable for obtaining a resolution less than 10 nm at room temperature.

Kinetics and mechanism of photoaccelerated isotope exchange between U(VI) and U(IV) in oxalate solutions

International Nuclear Information System (INIS)

Shaban, I.S.; Owreit, M.F.; Nikitenko, S.I.

1992-01-01

A kinetic study of thermal and photoaccelerated U(IV)-U(VI) isotope exchange has been carried out in oxalate solutions at 11-40 deg C. The rate and quantum yield were determined as a function of U(IV), U(VI) and oxalate concentration, wavelength of incident light, temperature and absorbed dose of γ-radiation. The kinetic equations for thermal and photoaccelerated exchange have been obtained. It was assumed that the mechanism of exchange involves formation of U(V) as an intermediate, followed by slow exchange between U(V) and U(IV). The isokinetic dependence confirms the identity of limiting stages for thermal and photostimulated exchange. The upper component of photoexcited T 1 level of uranyl is supposed to be the most reactive in the process of U(V) generation. It was observed that the small doses of γ-radiation evoke the acceleration of isotope exchange, however, at D>100 krad the rate of exchange is reduced to the level of thermal exchange. (author) 8 refs.; 4 figs.; 2 tabs

Natural clinoptilolite exchanged with iron: characterization and catalytic activity in nitrogen monoxide reduction

Directory of Open Access Journals (Sweden)

Daria Tito-Ferro

2016-12-01

Full Text Available The aim of this work was to characterize the natural clinoptilolite from Tasajeras deposit, Cuba, modified by hydrothermal ion-exchange with solutions of iron (II sulfate and iron (III nitrate in acid medium. Besides this, its catalytic activity to reduce nitrogen monoxide with carbon monoxide/propene in the presence of oxygen was evaluated. The characterization was performed by Mössbauer and UV-Vis diffuse reflectance spectroscopies and adsorption measurements. The obtained results lead to conclude that in exchanged samples, incorporated divalent and trivalent irons are found in octahedral coordination. Both irons should be mainly in cationic extra-framework positions inside clinoptilolite channels as charge compensating cations, and also as iron oxy-hydroxides resulting from limited hydrolysis of these cations. The iron (III exchanged samples has a larger amount of iron oxy-hydroxides agglomerates. The iron (II exchanged samples have additionally iron (II sulfate adsorbed. The catalytic activity in the nitrogen monoxide reduction is higher in the exchanged zeolites than starting. Among all samples, those exchanged of iron (II has the higher catalytic activity. This lead to outline that, main catalytically active centers are associated with divalent iron.

Ion exchange for treatment of industrial effluents

International Nuclear Information System (INIS)

Moreno Daudinot, Aurora Maria; Ge Leyva, Midalis

2016-01-01

The acid leaching and ammoniacal carbonate technologies of laterite respectively, are responsible for the low quality of life of the local population, the big deforested areas due to the mining tilling, the elevated contents of solids in the air and waters, as well as the chemical contamination by metals presence, the acidity or basicity of the effluents of both industries, that arrive through the river and the bay to aquifer's mantle. The ion exchange resins allow ions separation contained in low concentrations in the solutions, where the separation of these elements for solvents, extraction or another chemical methods would be costly. Technological variants are proposed in order to reduce the impact produced on the flora and the fauna, by the liquid effluents of nickel industry, by means of ion exchange resins introduction as well as the recuperation of metals and their re incorporation to the productive process. (Author)

Social dilemmas as exchange dilemmas

NARCIS (Netherlands)

Dijkstra, Jacob; van Assen, Marcel A.L.M.

2016-01-01

We develop a new paradigm to study social dilemmas, called exchange dilemmas. Exchange dilemmas arise from externalities of exchanges with third parties, and many real-life social dilemmas are more accurately modeled as exchange dilemmas rather than prisoner's dilemmas. Building on focusing and

Social dilemmas as exchange dilemmas

NARCIS (Netherlands)

Dijkstra, J.; van Assen, M.A.L.M.

2016-01-01

We develop a new paradigm to study social dilemmas, called exchange dilemmas. Exchange dilemmas arise from externalities of exchanges with third parties, and many real-life social dilemmas are more accurately modeled as exchange dilemmas rather than prisoner's dilemmas. Bulding on focusing and

Update heat exchanger designing principles

International Nuclear Information System (INIS)

Lipets, A.U.; Yampol'skij, A.E.

1985-01-01

Update heat exchanger design principles are analysed. Different coolant pattern in a heat exchanger are considered. It is suggested to rationally organize flow rates irregularity in it. Applying on heat exchanger designing measures on using really existing temperature and flow rate irregularities will permit to improve heat exchanger efficiency. It is expedient in some cases to artificially produce irregularities. In this connection some heat exchanger design principles must be reviewed now

Compact heat exchanger for power plants

International Nuclear Information System (INIS)

Kinnunen, L.

2001-01-01

Vahterus Oy, located at Kalanti, has manufactured heat exchangers since the beginning of 1990s. About 90% of the equipment produced are exported. In the PSHE (Plate and Shell) solution of the Vahterus heat exchanger the heat is transferred by round plated welded to form a compact package, which is assembled into a cylindrical steel casing. The heat exchanger contains no gaskets or soldered joints, which eliminates the leak risks. Traditional heat exchanges are usually operated at higher temperatures and pressures, but the heat transfer capacities of them are lower. Plate heat exchangers, on the other hand, are efficient, but the application range of them is narrow. Additionally, the rubber gasket of the heat exchange plates, sealing the joints of the heat exchanging plates, does not stand high pressures or temperatures, or corroding fluids. The new welded plate heat exchanger combine the pressure and temperature resistance of tube heat exchangers and the high heat exchange capacity of plate heat exchangers. The new corrosion resisting heat exchanger can be applied for especially hard conditions. The operating temperature range of the PSHE heat exchanger is - 200 - 900 deg C. The pressure resistance is as high as 100 bar. The space requirement of PSHE is only one tenth of the space requirement of traditional tube heat exchangers. Adjusting the number of heat exchanging plates can change the capacity of the heat exchanger. Power range of the heat exchanger can be as high as 80 MW. Due to the corrosion preventive construction and the small dimension the PSHE heat exchanger can be applied for refrigerators using ammonia as refrigerant. These kinds of new Vahterus heat exchangers are in use in 60 countries in more than 2000 refrigerators

Exchanging Description Logic Knowledge Bases

NARCIS (Netherlands)

Arenas, M.; Botoeva, E.; Calvanese, D.; Ryzhikov, V.; Sherkhonov, E.

2012-01-01

In this paper, we study the problem of exchanging knowledge between a source and a target knowledge base (KB), connected through mappings. Differently from the traditional database exchange setting, which considers only the exchange of data, we are interested in exchanging implicit knowledge. As

A comparing study of alloy 600 and alloy 690 on resistance to intergranular stress corrosion cracking(IGSCC)

International Nuclear Information System (INIS)

Lee, Jae Hun

1993-02-01

In order to compare the effect of senitization on the intergranular stress corrosion cracking(IGSCC) between Alloy 600 and Alloy 690, these alloys have been sensitized for 1 to 100 hours at 700 .deg. C. The degree of sensitization(DOS) has evaluated by the ratio of Ir(the maximum current density at anodic scan) to Ia(the maximum current density at reverse scan) in the modified double loop EPR(electrochemical potentiokinetic reactivation) test in 0.01M H 2 SO 4 + 0.0001M KSCN at 25 .deg. C and at scan rate of 0.5mV/sec. The susceptibility to IGSCC has been measured in 0.01M Na 2 S 4 O 6 solution using CERT(constant extension rate tester) at strain rate of 1.0 x 10 -6 S -1 . With increasing sensitization time the DOS of Alloy 600 increases to the maximum value at 5 hours and decreases gradually due to the replenishment of Cr to the Cr-depleted grain boundaries. For Alloy 600 samples except those sensitized for less than 1 hour, the DOS measured by the modified EPR test parallel to susceptibility to IGSCC revealed by the ratio of strain to failure (εf, Na 2 S 4 O 6 /εf, Air). It appears that the susceptibility to IGSCC is closely associated with the depth in Cr-depleted concentration profile across grain boundary. For the sensitized Alloy 690 samples exhibited extremely low value of Ir/Ia less than 0.074% and also were immune to IGSCC. The good resistance of Alloy 690 to IGSCC is considered to be attributed to the higher Cr concentration to avoid serious Cr-depletion problems adjacent to grain boundary

Charge exchange collisions in gases in the presence of competing processes

International Nuclear Information System (INIS)

Senba, Masayoshi; British Columbia Univ., Vancouver

1988-01-01

The slowing down of charged particles in noble gases has been investigated theoretically from the charge exchange regime down to thermal energy. A formalism has been developed which allows one to calculate the rate of energy loss, the collision rate, the slowing down time, the neutral fraction and other quantities of interest directly from the cross sections of the atomic process involved. The formalism has been applied to the case of muons in He where two experimental observables, the fraction of the neutral species (muonium) and the muon spin depolarisation during charge exchange, have been calculated. The calculations have reproduced experimental results very well. It has also been found that the elastic process at the end of the slowing down reduces the number of charge exchange collisions drastically, thus sensitively affecting the neutral fraction and the muon spin depolarisation. (author)

The behaviour of the lande factor and effective exchange parameter in a group of Pr intermetallics observed through reduced level scheme models

International Nuclear Information System (INIS)

Ranke, P.J. von; Caldas, A.; Palermo, L.

1993-01-01

The present work constitutes a portion of a continuing series of studies dealing with models, in which we retain only the two lowest levels of the crystal field splitting scheme of rare-earth ion in rare-earth intermetallics. In these reduced level scheme models, the crystal field and the magnetic Hamiltonians are represented in matrix notation. These two matrices constitute the model Hamiltonian proposed in this paper, from which we derive the magnetic state equations of interest for this work. Putting into these equations a group of adequate experimental data found in the literature for a particular rare-earth intermetallic we obtain the Lande factor and effective exchange parameter related to this rare-earth intermetallic. This study will be applied to a group of Pr intermetallics, in cubic symmetry, in which the ground level may be a non-magnetic singlet level or a non-magnetic doublet level. In both cases, the first excited level is a triplet one. (orig.)

Social dilemmas as exchange dilemmas

OpenAIRE

Dijkstra, J.; van Assen, M.A.L.M.

2016-01-01

We develop a new paradigm to study social dilemmas, called exchange dilemmas. Exchange dilemmas arise from externalities of exchanges with third parties, and many real-life social dilemmas are more accurately modeled as exchange dilemmas rather than prisoner's dilemmas. Bulding on focusing and framing research we predict that defection is omnipresent in exchange dilemmas, which is corroborated in to very different experiments. Our results suggest that the fundamental problem of cooperation in...

Nanofiltration: ion exchange system for effective surfactant removal from water solutions

Directory of Open Access Journals (Sweden)

I. Kowalska

2014-12-01

Full Text Available A system combining nanofiltration and ion exchange for highly effective separation of anionic surfactant from water solutions was proposed. The subjects of the study were nanofiltration polyethersulfone membranes and ion-exchange resins differing in type and structure. The quality of the treated solution was affected by numerous parameters, such as quality of the feed solution, membrane cut-off, resin type, dose and the solution contact time with the resin. A properly designed purification system made it possible to reduce the concentration of anionic surfactant below 1 mg L-1 from feed solutions containing surfactant in concentrations above the CMC value.

Experimental Study on the Airside Performance of Aluminum Heat Exchangers Having Slim Louver Fins

Energy Technology Data Exchange (ETDEWEB)

Kim, Nae Hyun [Incheon Nat’l Univ., Incheon (Korea, Republic of); Cho, Honggi [Samsung Electronics Daejeon, Suwon (Korea, Republic of)

2017-09-15

Recent trends in slim air conditioners require heat exchangers of reduced flow depth. In this study, slim louver fin geometry was obtained using predictive correlations. The deduced geometry yielded 10 mm flow depth, 0.9 mm louver pitch, and 35° louver angle. Samples were made and tests were conducted. The new slim sample yielded 36% higher j factor and 2.3% higher f factor compared with those of the standard sample. This implies that 26% reduction of heat exchanger volume was possible by reducing the flow depth. In addition, the j/f1/3 of the slim sample was 55% larger than that of the standard sample. Furthermore, the results are compared with predictions made using existing correlations.

Experimental Study on the Airside Performance of Aluminum Heat Exchangers Having Slim Louver Fins

International Nuclear Information System (INIS)

Kim, Nae Hyun; Cho, Honggi

2017-01-01

Recent trends in slim air conditioners require heat exchangers of reduced flow depth. In this study, slim louver fin geometry was obtained using predictive correlations. The deduced geometry yielded 10 mm flow depth, 0.9 mm louver pitch, and 35° louver angle. Samples were made and tests were conducted. The new slim sample yielded 36% higher j factor and 2.3% higher f factor compared with those of the standard sample. This implies that 26% reduction of heat exchanger volume was possible by reducing the flow depth. In addition, the j/f1/3 of the slim sample was 55% larger than that of the standard sample. Furthermore, the results are compared with predictions made using existing correlations.