Enhancement of single particle rare earth doped NaYF4: Yb, Er emission with a gold shell

International Nuclear Information System (INIS)

Li, Ling; Green, Kory; Hallen, Hans; Lim, Shuang Fang

2015-01-01

Upconversion of infrared light to visible light has important implications for bioimaging. However, the small absorption cross-section of rare earth dopants has limited the efficiency of these anti-Stokes nanomaterials. We present enhanced excitation absorption and single particle fluorescent emission of sodium yttrium fluoride, NaYF 4 : Yb, Er based upconverting nanoparticles coated with a gold nanoshell through surface plasmon resonance. The single gold-shell coated nanoparticles show enhanced absorption in the near infrared, enhanced total emission intensity, and increased green relative to red emission. We also show differences in enhancement between single and aggregated gold shell nanoparticles. The surface plasmon resonance of the gold-shell coated nanoparticle is shown to be dependent on the shell thickness. In contrast to other reported results, our single particle experimental observations are corroborated by finite element calculations that show where the green/red emission enhancement occurs, and what portion of the enhancement is due to electromagnetic effects. We find that the excitation enhancement and green/red emission ratio enhancement occurs at the corners and edges of the doped emissive core. (paper)

Fabrication and micro-photoluminescence property of CdSe/CdS core/shell nanowires

Energy Technology Data Exchange (ETDEWEB)

Dai, Guozhang; Gou, Guangyang; Wu, Zeming; Chen, Yu; Li, Hongjian [Central South University, Hunan Key Laboratory for Super-microstructure and Ultrafast Process, School of Physics and Electronics, Changsha, Hunan (China); Wan, Qiang [Hunan University, School of Physics and Electronics, Changsha (China); Zou, Bingsuo [Beijing Institute of Technology, Beijing Key Lab of Nanophotonics and Ultrafine Optoelectronic Systems, School of Physics, Beijing (China)

2015-04-01

Hetero-epitaxial CdSe/CdS core/shell nanowires (NWs) were prepared by a source-controllable chemical vapor deposition method. A two-stage growth mechanism was proposed to the growth process of the core/shell NWs. Micro-photoluminescence (μ-PL) property of individual NW was studied by a confocal microscopy system. The pure CdSe NW emits a red light with peak at 712.3 nm, which is inconsistent with the CdSe band-edge emission. The CdSe/CdS core/shell NW emits two apparent peaks, one is an intensive red emission peak centered at 715.2 nm and the other is a weak green emission peak located at 516.2 nm. The room temperature μ-PL spectrum shows that the PL intensity of CdSe NW was evidently promoted by coating the CdS shell, and this is because CdS improves the surface state optimizing the energy band structure of CdSe NW. The as-synthesized CdSe/CdS core/shell NW has more efficient PL quantum yields than pure CdSe NW and may find potential applications in nanoscale photonic devices. (orig.)

Fabrication and micro-photoluminescence property of CdSe/CdS core/shell nanowires

International Nuclear Information System (INIS)

Dai, Guozhang; Gou, Guangyang; Wu, Zeming; Chen, Yu; Li, Hongjian; Wan, Qiang; Zou, Bingsuo

2015-01-01

Hetero-epitaxial CdSe/CdS core/shell nanowires (NWs) were prepared by a source-controllable chemical vapor deposition method. A two-stage growth mechanism was proposed to the growth process of the core/shell NWs. Micro-photoluminescence (μ-PL) property of individual NW was studied by a confocal microscopy system. The pure CdSe NW emits a red light with peak at 712.3 nm, which is inconsistent with the CdSe band-edge emission. The CdSe/CdS core/shell NW emits two apparent peaks, one is an intensive red emission peak centered at 715.2 nm and the other is a weak green emission peak located at 516.2 nm. The room temperature μ-PL spectrum shows that the PL intensity of CdSe NW was evidently promoted by coating the CdS shell, and this is because CdS improves the surface state optimizing the energy band structure of CdSe NW. The as-synthesized CdSe/CdS core/shell NW has more efficient PL quantum yields than pure CdSe NW and may find potential applications in nanoscale photonic devices. (orig.)

Red-Light-Driven Water Splitting by Au(Core)-CdS(Shell) Half-Cut Nanoegg with Heteroepitaxial Junction.

Science.gov (United States)

Naya, Shin-Ichi; Kume, Takahiro; Akashi, Ryo; Fujishima, Musashi; Tada, Hiroaki

2018-01-31

A key material for artificial photosynthesis including water splitting is heteronanostructured (HNS) photocatalysts. The photocatalytic activity depends on the geometry and dimension, and the quality of junctions between the components. Here we present a half-cut Au(core)-CdS(shell) (HC-Au@CdS) nanoegg as a new HNS plasmonic photocatalyst for water splitting. UV-light irradiation of Au nanoparticle (NP)-loaded ZnO (Au/ZnO) at 50 °C induces the selective deposition of hexagonal CdS on the Au surface of Au/ZnO with an epitaxial (EPI) relation of CdS{0001}/Au{111}. The subsequent selective dissolution of the ZnO support at room temperature yields HC-Au@CdS with the Au NP size and EPI junction (#) retained. Red-light irradiation (λ ex = 640 nm) of HC-Au@#CdS gives rise to continuous stoichiometric water splitting with an unprecedentedly high external quantum yield of 0.24%.

Isogeometric shell formulation based on a classical shell model

KAUST Repository

Niemi, Antti

2012-09-04

This paper constitutes the first steps in our work concerning isogeometric shell analysis. An isogeometric shell model of the Reissner-Mindlin type is introduced and a study of its accuracy in the classical pinched cylinder benchmark problem presented. In contrast to earlier works [1,2,3,4], the formulation is based on a shell model where the displacement, strain and stress fields are defined in terms of a curvilinear coordinate system arising from the NURBS description of the shell middle surface. The isogeometric shell formulation is implemented using the PetIGA and igakit software packages developed by the authors. The igakit package is a Python package used to generate NURBS representations of geometries that can be utilised by the PetIGA finite element framework. The latter utilises data structures and routines of the portable, extensible toolkit for scientific computation (PETSc), [5,6]. The current shell implementation is valid for static, linear problems only, but the software package is well suited for future extensions to geometrically and materially nonlinear regime as well as to dynamic problems. The accuracy of the approach in the pinched cylinder benchmark problem and present comparisons against the h-version of the finite element method with bilinear elements. Quadratic, cubic and quartic NURBS discretizations are compared against the isoparametric bilinear discretization introduced in [7]. The results show that the quadratic and cubic NURBS approximations exhibit notably slower convergence under uniform mesh refinement as the thickness decreases but the quartic approximation converges relatively quickly within the standard variational framework. The authors future work is concerned with building an isogeometric finite element method for modelling nonlinear structural response of thin-walled shells undergoing large rigid-body motions. The aim is to use the model in a aeroelastic framework for the simulation of flapping wings.

Morphological and mechanical changes in juvenile red-eared slider turtle (Trachemys scripta elegans) shells during ontogeny.

Science.gov (United States)

Fish, Jennifer F; Stayton, Charles T

2014-04-01

Turtles experience numerous modifications in the morphological, physiological, and mechanical characteristics of their shells through ontogeny. Although a general picture is available of the nature of these modifications, few quantitative studies have been conducted on changes in turtle shell shape through ontogeny, and none on changes in strength or rigidity. This study investigates the morphological and mechanical changes that juvenile Trachemys scripta elegans undergo as they increase in size. Morphology and shell rigidity were quantified in a sample of 36 alcohol-preserved juvenile Trachemys scripta elegans. Morphometric information was used to create finite element models of all specimens. These models were used to assess the mechanical behavior of the shells under various loading conditions. Overall, we find that turtles experience complementary changes in size, shape, deformability, and relative strength as they grow. As turtles age their shells become larger, more elongate, relatively flatter, and more rigid. These changes are associated with decreases in relative (size independent) strength, even though the shells of larger turtles are stronger in an absolute sense. Decreased deformability is primarily due to changes in the size of the animals. Residual variation in deformability cannot be explained by changes in shell shape. This variation is more likely due to changes in the degree of connectedness of the skeletal elements in the turtle's shells, along with changes in the thickness and degree of mineralization of shell bone. We suggest that the mechanical implications of shell size, shape, and deformability may have a large impact on survivorship and development in members of this species as they mature. Copyright © 2013 Wiley Periodicals, Inc.

Red luminescence of Zn /ZnO core–shell nanorods in a mixture of LTZA/Zinc acetate matrix: Study of the effects of Nitrogen bubbling, Cobalt doping and thioglycolic acid

International Nuclear Information System (INIS)

Karimipour, Masoud; Kheshabnia, Alireza; Molaei, Mehdi

2016-01-01

Zn/ZnO core–shell nanorods were synthesized using a very simple low temperature and low pressure Solvothermal method. Effect of N 2 gas bubbling, insertion of thioglycolic acid (TGA) and cobalt doping with Co/Zn=x: 0%, 0.1%, 0.3% and 0.5% was studied by means of scanning electron microscopy, transmission electron microscopy, x-ray diffraction, Furrier transformed infrared(FTIR) spectroscopy, UV–Vis spectroscopy and photoluminescence (PL) measurement. XRD analysis showed that hexagonal metallic zinc and wurtzite ZnO phases are available in all the samples. Zinc acetate crystallizes together with Zn and ZnO phases as well, but it transforms to l-thereonine zinc acetate(LTZA) after the insertion of TGA. Moreover, gas bubbling and cobalt doping do not change the crystal phases. FTIR spectroscopy also confirms the formation of zincacetate and LTZA phases. Williamson–Hall analysis indicates that with the insertion of TGA, mean crystallite size decreases and the value of microstrain is the least for x=0.1%. SEM images depict that with the insertion of TGA, the morphology of the compound changes from rounded particles to nanorods. TEM images revealed that the microstructure of the compounds is of the Zn/ZnO core–shell type. UV–vis spectroscopy demonstrates the blue shift of absorption edge and the size reduction due to insertion of TGA. PL spectroscopy shows that the samples have strong blue emission with peaks range from 316 nm up to 480 nm. Bubbling simply causes that the samples emit a narrow and sharp band peaked at 605 nm. Insertion of TGA prevents the blue emission and enhances the pure red emission band. At the presence of TGA, the optimum value of pure red emission for Co-doping was found to be 0.1% which was compatible with XRD analysis. With x>0.1%, the blue and red emission of samples started quenching and light emission for the value of x=0.5% vanished completely. The results show that the other crystal phases such as zincacetate, LTZA do not affect

Removal of Procion Red dye from colored effluents using H2SO4-/HNO3-treated avocado shells (Persea americana) as adsorbent.

Science.gov (United States)

Georgin, Jordana; da Silva Marques, Bianca; da Silveira Salla, Julia; Foletto, Edson Luiz; Allasia, Daniel; Dotto, Guilherme Luiz

2018-03-01

The treatment of colored effluents containing Procion Red dye (PR) was investigated using H 2 SO 4 and HNO 3 modified avocado shells (Persea americana) as adsorbents. The adsorbent materials (AS-H 2 SO 4 and AS-HNO 3 ) were properly characterized. The adsorption study was carried out considering the effects of adsorbent dosage and pH. Kinetic, equilibrium, and thermodynamic aspects were also evaluated. Finally, the adsorbents were tested to treat simulated dye house effluents. For both materials, the adsorption was favored using 0.300 g L -1 of adsorbent at pH 6.5, where, more than 90% of PR was removed from the solution. General order model was able to explain the adsorption kinetics for both adsorbents. The Sips model was adequate to represent the isotherm data, being the maximum adsorption capacities of 167.0 and 212.6 mg g -1 for AS-H 2 SO 4 and AS-HNO 3 , respectively. The adsorption processes were thermodynamically spontaneous, favorable (- 17.0 Avocado shells, after a simple acid treatment, can be a low-cost option to treat colored effluents.

Gravity modes as a way to distinguish between hydrogen- and helium-burning red giant stars

DEFF Research Database (Denmark)

Bedding, Timothy R.; Mosser, Benoit; Huber, Daniel

2011-01-01

Red giants are evolved stars that have exhausted the supply of hydrogen in their cores and instead burn hydrogen in a surrounding shell. Once a red giant is sufficiently evolved, the helium in the core also undergoes fusion. Outstanding issues in our understanding of red giants include...... uncertainties in the amount of mass lost at the surface before helium ignition and the amount of internal mixing from rotation and other processes. Progress is hampered by our inability to distinguish between red giants burning helium in the core and those still only burning hydrogen in a shell....... Asteroseismology offers a way forward, being a powerful tool for probing the internal structures of stars using their natural oscillation frequencies. Here we report observations of gravity-mode period spacings in red giants that permit a distinction between evolutionary stages to be made. We use high...

Functions and Requirements for Automated Liquid Level Gauge Instruments in Single-Shell and Double-Shell Tank Farms

International Nuclear Information System (INIS)

CARPENTER, K.E.

1999-01-01

This functions and requirements document defines the baseline requirements and criteria for the design, purchase, fabrication, construction, installation, and operation of automated liquid level gauge instruments in the Tank Farms. This document is intended to become the technical baseline for current and future installation, operation and maintenance of automated liquid level gauges in single-shell and double-shell tank farms

From red giants to planetary nebulae: Asymmetries, dust, and polarization

International Nuclear Information System (INIS)

Johnson, J.J.

1990-01-01

In order to investigate the development of aspherical planetary nebulae, polarimetry was obtained for a group of planetary nebulae and for objects that will evolve into planetary nebulae, i.e., red giants, late asymptotic giant branch (AGB) objects, proto-planetary nebulae, and young planetary nebulae. To study the dust around the objects in our sample, we also used data from the Infrared Astronomy Satellite (IRAS) mission. The youngest objects in our survey, red giants, had the hottest dust temperatures while planetary nebulae had the coolest. Most of the objects were intrinsically polarized, including the red giants. This indicated that the circumstellar dust shells of these objects were aspherical. Both carbon- and oxygen-rich objects could be intrinsically polarized. The intrinsic polarizations of a sample of our objects were modeled using an ellipsoidal circumstellar dust shell. The findings of this study suggest that the asphericities that lead to an aspherical planetary nebula originate when a red giant begins to undergo mass loss. The polarization and thus the asphericity as the star evolves, with both reaching a maximum during the proto-planetary nebula stage. The circumstellar dust shell will dissipate after the proto-planetary nebulae stage since no new material is being added. The polarization of planetary nebulae will thus be low. In the most evolved planetary nebulae, the dust has either been destroyed or dissipated into the interstellar medium. In these objects no polarization was observed

Gravity modes as a way to distinguish between hydrogen- and helium-burning red giant stars

NARCIS (Netherlands)

Bedding, T.R.; Mosser, B.; Huber, D.; Montalbán, J.; Beck, P.; Christensen-Dalsgaard, J.; Elsworth, Y.P.; García, R.A.; Miglio, A.; Stello, D.; White, T.R.; de Ridder, J.; Hekker, S.; Aerts, C.; Barban, C.; Belkacem, K.; Broomhall, A.M.; Brown, T.M.; Buzasi, D.L.; Carrier, F.; Chaplin, W.J.; Di Mauro, M.P.; Dupret, M.-A.; Frandsen, S.; Gilliland, R.L.; Goupil, M.J.; Jenkins, J.M.; Kallinger, T.; Kawaler, S.; Kjeldsen, H.; Mathur, S.; Noels, A.; Silva Aguirre, V.; Ventura, P.

2011-01-01

Red giants are evolved stars that have exhausted the supply of hydrogen in their cores and instead burn hydrogen in a surrounding shell. Once a red giant is sufficiently evolved, the helium in the core also undergoes fusion. Outstanding issues in our understanding of red giants include uncertainties

Ag@ZnO core-shell nanoparticles study by first principle: The structural, magnetic and optical properties

Energy Technology Data Exchange (ETDEWEB)

Cheng, Hai-Xia [Department of Physics, University of Science and Technology Beijing, Beijing 100083 (China); Wang, Xiao-Xu [Department of Physics, University of Science and Technology Beijing, Beijing 100083 (China); Beijing Computing Center, Beijing 100094 (China); Hu, Yao-Wen [Department of Physics, Tsinghua University, Beijing 100084 (China); Song, Hong-Quan; Huo, Jin-Rong; Li, Lu [Department of Physics, University of Science and Technology Beijing, Beijing 100083 (China); Qian, Ping, E-mail: ustbqianp@163.com [Department of Physics, University of Science and Technology Beijing, Beijing 100083 (China); Song, Yu-Jun [Department of Physics, University of Science and Technology Beijing, Beijing 100083 (China)

2016-12-15

Ag@ZnO core-shell nanoparticles of around 72 atoms have been investigated by the density functional theory, revealing proving for the first time that the core-shell structure exhibits a shrinkage phenomenon from outer shell in agreement with the other studies in literatures. Our calculations predict that the Ag@ZnO core-shell structure is a ferromagnetic spin polarized state, and the magnetism mainly stems from the spin splitting of 2p electrons of O atoms. In addition, the total and partial DOS of Ag@ZnO indicate that the nanostructure is a half-metallic nanoparticle and has the characters of the p-type semiconductor. Furthermore, the optical properties calculations show that the absorption edge of Ag@ZnO have a red shift and good photocatalysis compare to that of the bulk ZnO. These results of the Ag@ZnO core-shell structure obtain a well agreement with the experimental measurement. - Graphical abstract: Geometric structure of (a) Ag@ZnO core-shell nanostructure; (b) the core of Ag; (c) the shell of ZnO The core-shell nanoparticle Ag@ZnO contains Ag inner core of radius of 4 Å and ZnO outer shell with thickness of 2 Å. Ag@ZnO core-shell nanoparticles of around 72 atoms have been proved for the first time that the core-shell structure exhibit a shrinkage phenomenon from outer shell. Our calculations predict that the Ag@ZnO core-shell structure is a half-metallic nanoparticle and has the characters of the p-type semiconductor. The absorption edge of Ag@ZnO have a red shift and get good photo-catalysis compare to that of the bulk ZnO.

Analytic Solution to Shell Boundary – Value Problems

Directory of Open Access Journals (Sweden)

Yu. I. Vinogradov

2015-01-01

Full Text Available Object of research is to find analytical solution to the shell boundary – value problems, i.e. to consider the solution for a class of problems concerning the mechanics of hoop closed shells strain.The objective of work is to create an analytical method to define a stress – strain state of shells under non-axisymmetric loading. Thus, a main goal is to derive the formulas – solutions of the linear ordinary differential equations with variable continuous coefficients.The partial derivative differential equations of mechanics of shells strain by Fourier's method of variables division are reduced to the system of the differential equations with ordinary derivatives. The paper presents the obtained formulas to define solutions of the uniform differential equations and received on their basis formulas to define a particular solution depending on a type of the right parts of the differential equations.The analytical algorithm of the solution of a boundary task uses an approach to transfer the boundary conditions to the randomly chosen point of an interval of changing independent variable through the solution of the canonical matrix ordinary differential equation with the subsequent solution of system of algebraic equations for compatibility of boundary conditions at this point. Efficiency of algorithm is based on the fact that the solution of the ordinary differential equations is defined as the values of Cauchy – Krylova functions, which meet initial arbitrary conditions.The results of researches presented in work are useful to experts in the field of calculus mathematics, dealing with solution of systems of linear ordinary differential equations and creation of effective analytical computing methods to solve shell boundary – value problems.

Free and Forced Vibrations of Thick-Walled Anisotropic Cylindrical Shells

Science.gov (United States)

Marchuk, A. V.; Gnedash, S. V.; Levkovskii, S. A.

2017-03-01

Two approaches to studying the free and forced axisymmetric vibrations of cylindrical shell are proposed. They are based on the three-dimensional theory of elasticity and division of the original cylindrical shell with concentric cross-sectional circles into several coaxial cylindrical shells. One approach uses linear polynomials to approximate functions defined in plan and across the thickness. The other approach also uses linear polynomials to approximate functions defined in plan, but their variation with thickness is described by the analytical solution of a system of differential equations. Both approaches have approximation and arithmetic errors. When determining the natural frequencies by the semi-analytical finite-element method in combination with the divide and conqure method, it is convenient to find the initial frequencies by the finite-element method. The behavior of the shell during free and forced vibrations is analyzed in the case where the loading area is half the shell thickness

Shell report 2001; Les personnes, la planete, les profits. Shell rapport 2001

Energy Technology Data Exchange (ETDEWEB)

NONE

2002-07-01

In 2001, Shell saw mixed results across the social, environmental and economic spectrum. In order to contribute to the sustainable development, the Group is on track towards meeting its target to reduce greenhouse gas emissions to 10 % below 1990 levels by the end of 2002, although there was a significant increase in spill volumes and greenhouse gas emissions rose. Shell has articulated the business case and defined seven principles of sustainable development for use across the Group in business plans and daily operations: generating robust profitability; delivering value to customers; protecting the environment; managing resources; respecting and safeguarding people; benefiting communities; and working with stakeholders. Key points from the Shell Report include: in the framework of Managing, an independent review of the Shell Nigeria Community Development programme and testing of a human rights assessment tool in Shell South Africa and the implementing of a new Diversity and Inclusiveness Standard; in the framework of the economy the cost improvements of 5,1 billion dollars, ahead of target, the second highest earnings ever in difficult market conditions and the election of Shell top brand for fifth year running by motorists; in the framework of the Social, the safety performance, the avoidance of 100 contracts for incompatibility with Shell Business Principles; in the framework of the Environment, the publication of the Fresh water usage report for the first time, the Greenhouse gas emissions, the increase of spills as a result of a small number of incidents including a pipeline rupture in Nigeria and a well blow out in Oman. The economic, environmental and social data of the Shell Report are externally verified. (A.L.B.)

Shell morphology and Raman spectra of epitaxial Ge-SixGe1-x and Si-SixGe1-x core-shell nanowires

Science.gov (United States)

Wen, Feng; Dillen, David C.; Kim, Kyounghwan; Tutuc, Emanuel

2017-06-01

We investigate the shell morphology and Raman spectra of epitaxial Ge-SixGe1-x and Si-SixGe1-x core-shell nanowire heterostructures grown using a combination of a vapor-liquid-solid (VLS) growth mechanism for the core, followed by in-situ epitaxial shell growth using ultra-high vacuum chemical vapor deposition. Cross-sectional transmission electron microscopy reveals that the VLS growth yields cylindrical Ge, and Si nanowire cores grown along the ⟨111⟩, and ⟨110⟩ or ⟨112⟩ directions, respectively. A hexagonal cross-sectional morphology is observed for Ge-SixGe1-x core-shell nanowires terminated by six {112} facets. Two distinct morphologies are observed for Si-SixGe1-x core-shell nanowires that are either terminated by four {111} and two {100} planes associated with the ⟨110⟩ growth direction or four {113} and two {111} planes associated with the ⟨112⟩ growth direction. We show that the Raman spectra of Si- SixGe1-x are correlated with the shell morphology thanks to epitaxial growth-induced strain, with the core Si-Si mode showing a larger red shift in ⟨112⟩ core-shell nanowires compared to their ⟨110⟩ counterparts. We compare the Si-Si Raman mode value with calculations based on a continuum elasticity model coupled with the lattice dynamic theory.

CIRCUMSTELLAR SHELL FORMATION IN SYMBIOTIC RECURRENT NOVAE

Energy Technology Data Exchange (ETDEWEB)

Moore, Kevin; Bildsten, Lars [Department of Physics, Broida Hall, University of California, Santa Barbara, CA 93106 (United States)

2012-12-20

We present models of spherically symmetric recurrent nova shells interacting with circumstellar material (CSM) in a symbiotic system composed of a red giant (RG) expelling a wind and a white dwarf accreting from this material. Recurrent nova eruptions periodically eject material at high velocities ({approx}> 10{sup 3} km s{sup -1}) into the RG wind profile, creating a decelerating shock wave as CSM is swept up. High CSM densities cause the shocked wind and ejecta to have very short cooling times of days to weeks. Thus, the late-time evolution of the shell is determined by momentum conservation instead of energy conservation. We compute and show evolutionary tracks of shell deceleration, as well as post-shock structure. After sweeping up all the RG wind, the shell coasts at a velocity {approx}100 km s{sup -1}, depending on system parameters. These velocities are similar to those measured in blueshifted CSM from the symbiotic nova RS Oph, as well as a few Type Ia supernovae that show evidence of CSM, such as 2006X, 2007le, and PTF 11kx. Supernovae occurring in such systems may not show CSM interaction until the inner nova shell gets hit by the supernova ejecta, days to months after the explosion.

Influence of Shell Thickness on the Colloidal Stability of Magnetic Core-Shell Particle Suspensions.

Science.gov (United States)

Neville, Frances; Moreno-Atanasio, Roberto

2018-01-01

We present a Discrete Element study of the behavior of magnetic core-shell particles in which the properties of the core and the shell are explicitly defined. Particle cores were considered to be made of pure iron and thus possessed ferromagnetic properties, while particle shells were considered to be made of silica. Core sizes ranged between 0.5 and 4.0 μm with the actual particle size of the core-shell particles in the range between 0.6 and 21 μm. The magnetic cores were considered to have a magnetization of one tenth of the saturation magnetization of iron. This study aimed to understand how the thickness of the shell hinders the formation of particle chains. Chain formation was studied with different shell thicknesses and particle sizes in the presence and absence of an electrical double layer force in order to investigate the effect of surface charge density on the magnetic core-shell particle interactions. For core sizes of 0.5 and 4.0 μm the relative shell thicknesses needed to hinder the aggregation process were approximately 0.4 and 0.6 respectively, indicating that larger core sizes are detrimental to be used in applications in which no flocculation is needed. In addition, the presence of an electrical double layer, for values of surface charge density of less than 20 mC/m 2 , could stop the contact between particles without hindering their vertical alignment. Only when the shell thickness was considerably larger, was the electrical double layer able to contribute to the full disruption of the magnetic flocculation process.

High-efficiency red electroluminescent device based on multishelled InP quantum dots.

Science.gov (United States)

Jo, Jung-Ho; Kim, Jong-Hoon; Lee, Ki-Heon; Han, Chang-Yeol; Jang, Eun-Pyo; Do, Young Rag; Yang, Heesun

2016-09-01

We report on the synthesis of highly fluorescent red-emitting InP quantum dots (QDs) and their application to the fabrication of a high-efficiency QD-light-emitting diode (QLED). The core/shell heterostructure of the QDs is elaborately tailored toward a multishelled structure with a composition-gradient ZnSeS intermediate shell and an outer ZnS shell. Using the resulting InP/ZnSeS/ZnS QDs as an emitting layer, all-solution-processible red InP QLEDs are fabricated with a hybrid multilayered device structure having an organic hole transport layer (HTL) and an inorganic ZnO nanoparticle electron transport layer. Two HTLs of poly(9-vinlycarbazole) or poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(4,4'-(N-(4-sec-butylphenyl))diphenyl-amine), whose hole mobilities are different by at least three orders of magnitude, are individually applied for QLED fabrication and such HTL-dependent device performances are compared. Our best red device displays exceptional figures of merit such as a maximum luminance of 2849  cd/m2, a current efficiency of 4.2  cd/A, and an external quantum efficiency of 2.5%.

Preparation of yolk-shell MoS2 nanospheres covered with carbon shell for excellent lithium-ion battery anodes

Science.gov (United States)

Guo, Bangjun; Feng, Yu; Chen, Xiaofan; Li, Bo; Yu, Ke

2018-03-01

Molybdenum disulfide is regarded as one of the most promising electrode materials for high performance lithium-ion batteries. Designing firm basal structure is a key point to fully utilize the high capacity of layered MoS2 nanomaterials. Here, yolk-shell structured MoS2 nanospheres is firstly designed and fabricated to meet this needs. This unique yolk-shell nanospheres are transformed from solid nanospheres by a simply weak alkaline etching method. Then, the yolk-shell MoS2/C is synthesized by a facile process to protect the outside MoS2 shell and promote the conductivity. Taking advantages of high capacity and well-defined cavity space, allowing the core MoS2 to expand freely without breaking the outer shells, yolk-shell MoS2/C nanospheres delivers long cycle life (94% of capacity retained after 200 cycles) and high rate behaviour (830 mA h g-1 at 5 A g-1). This design of yolk-shell structure may set up a new strategy for preparing next generation anode materials for LIBs.

Red luminescence of Zn /ZnO core–shell nanorods in a mixture of LTZA/Zinc acetate matrix: Study of the effects of Nitrogen bubbling, Cobalt doping and thioglycolic acid

Energy Technology Data Exchange (ETDEWEB)

Karimipour, Masoud, E-mail: masoud.karimipour@gmail.com; Kheshabnia, Alireza; Molaei, Mehdi

2016-10-15

Zn/ZnO core–shell nanorods were synthesized using a very simple low temperature and low pressure Solvothermal method. Effect of N{sub 2} gas bubbling, insertion of thioglycolic acid (TGA) and cobalt doping with Co/Zn=x: 0%, 0.1%, 0.3% and 0.5% was studied by means of scanning electron microscopy, transmission electron microscopy, x-ray diffraction, Furrier transformed infrared(FTIR) spectroscopy, UV–Vis spectroscopy and photoluminescence (PL) measurement. XRD analysis showed that hexagonal metallic zinc and wurtzite ZnO phases are available in all the samples. Zinc acetate crystallizes together with Zn and ZnO phases as well, but it transforms to l-thereonine zinc acetate(LTZA) after the insertion of TGA. Moreover, gas bubbling and cobalt doping do not change the crystal phases. FTIR spectroscopy also confirms the formation of zincacetate and LTZA phases. Williamson–Hall analysis indicates that with the insertion of TGA, mean crystallite size decreases and the value of microstrain is the least for x=0.1%. SEM images depict that with the insertion of TGA, the morphology of the compound changes from rounded particles to nanorods. TEM images revealed that the microstructure of the compounds is of the Zn/ZnO core–shell type. UV–vis spectroscopy demonstrates the blue shift of absorption edge and the size reduction due to insertion of TGA. PL spectroscopy shows that the samples have strong blue emission with peaks range from 316 nm up to 480 nm. Bubbling simply causes that the samples emit a narrow and sharp band peaked at 605 nm. Insertion of TGA prevents the blue emission and enhances the pure red emission band. At the presence of TGA, the optimum value of pure red emission for Co-doping was found to be 0.1% which was compatible with XRD analysis. With x>0.1%, the blue and red emission of samples started quenching and light emission for the value of x=0.5% vanished completely. The results show that the other crystal phases such as zincacetate, LTZA do not

Coherently Strained Si-SixGe1-x Core-Shell Nanowire Heterostructures.

Science.gov (United States)

Dillen, David C; Wen, Feng; Kim, Kyounghwan; Tutuc, Emanuel

2016-01-13

Coherently strained Si-SixGe1-x core-shell nanowire heterostructures are expected to possess a positive shell-to-core conduction band offset, allowing for quantum confinement of electrons in the Si core. We report the growth of epitaxial, coherently strained Si-SixGe1-x core-shell heterostructures through the vapor-liquid-solid mechanism for the Si core, followed in situ by the epitaxial SixGe1-x shell growth using ultrahigh vacuum chemical vapor deposition. The Raman spectra of individual nanowires reveal peaks associated with the Si-Si optical phonon mode in the Si core and the Si-Si, Si-Ge, and Ge-Ge vibrational modes of the SixGe1-x shell. The core Si-Si mode displays a clear red-shift compared to unstrained, bare Si nanowires thanks to the lattice mismatch-induced tensile strain, in agreement with calculated values using a finite-element continuum elasticity model combined with lattice dynamic theory. N-type field-effect transistors using Si-SixGe1-x core-shell nanowires as channel are demonstrated.

Ground state energy fluctuations in the nuclear shell model

International Nuclear Information System (INIS)

Velazquez, Victor; Hirsch, Jorge G.; Frank, Alejandro; Barea, Jose; Zuker, Andres P.

2005-01-01

Statistical fluctuations of the nuclear ground state energies are estimated using shell model calculations in which particles in the valence shells interact through well-defined forces, and are coupled to an upper shell governed by random 2-body interactions. Induced ground-state energy fluctuations are found to be one order of magnitude smaller than those previously associated with chaotic components, in close agreement with independent perturbative estimates based on the spreading widths of excited states

Study of dinosaur's egg shell by EPR method

International Nuclear Information System (INIS)

Tleuberdina, R.A.; Nasirov, R.N.

1998-01-01

Two varieties of calcium carbonate are defined on base of ESR spectra radiation-inducted signals containing in mollusc shell and dinosaur and ostrich egg shell; their spectral characters are studied by infrared-spectroscopy methods and X-ray analysis. Possibility of correlation between ESR signals intensity of CO 2 -radical of investigated object and geological age is determined. (author)

Nearly suppressed photoluminescence blinking of small-sized, blue-green-orange-red emitting single CdSe-based core/gradient alloy shell/shell quantum dots: correlation between truncation time and photoluminescence quantum yield.

Science.gov (United States)

Roy, Debjit; Mandal, Saptarshi; De, Chayan K; Kumar, Kaushalendra; Mandal, Prasun K

2018-04-18

CdSe-based core/gradient alloy shell/shell semiconductor quantum dots (CGASS QDs) have been shown to be optically quite superior compared to core-shell QDs. However, very little is known about CGASS QDs at the single particle level. Photoluminescence blinking dynamics of four differently emitting (blue (λem = 510), green (λem = 532), orange (λem = 591), and red (λem = 619)) single CGASS QDs having average sizes 600 nm). In this manuscript, we report nearly suppressed PL blinking behaviour of CGASS QDs with average sizes correlation between the event durations and found that residual memory exists in both the ON- and OFF-event durations. Positively correlated successive ON-ON and OFF-OFF event durations and negatively correlated (anti-correlated) ON-OFF event durations perhaps suggest the involvement of more than one type of trapping process within the blinking framework. The timescale corresponding to the additional exponential term has been assigned to hole trapping for ON-event duration statistics. Similarly, for OFF-event duration statistics, this component suggests hole detrapping. We found that the average duration of the exponential process for the ON-event durations is an order of magnitude higher than that of the OFF-event durations. This indicates that the holes are trapped for a significantly long time. When electron trapping is followed by such a hole trapping, long ON-event durations result. We have observed long ON-event durations, as high as 50 s. The competing charge tunnelling model has been used to account for the observed blinking behaviour in these CGASS QDs. Quite interestingly, the PLQY of all of these differently emitting QDs (an ensemble level property) could be correlated with the truncation time (a property at the single particle level). A respective concomitant increase-decrease of ON-OFF event truncation times with increasing PLQY is also indicative of a varying degree of suppression of the Auger recombination processes in these four

Temperature Condition and Spherical Shell Shape Variation of Space Gauge-Alignment Spacecraft

Directory of Open Access Journals (Sweden)

V. S. Zarubin

2016-01-01

Full Text Available A high precision spherical shell is one of the geometrical shape embodiments of a gaugealignment spacecraft to determine and control a radar channel energy potential of the ground-based complex for the traffic control of space objects. Passive relays of signals and some types of smallsized instrumentation standard reflectors used for radar gauge and alignment have the same shape. Orbits of the considered spacecraft can be either circular with a height of about 1000 km, including those close to the polar, or elliptical with an apogee of up to 2200 km.In case there is no thermal control system in spacecrafts of these types the solar radiation is a major factor to define the thermal state of a spherical shell in the illuminated orbit area. With the shell in fixed position with respect to direction towards the Sun an arising uneven temperature distribution over its surface leads to variation of the spherically ideal shell shape, which may affect the functional characteristics of the spacecraft. The shell rotation about an axis perpendicular to the direction towards the Sun may reduce an unevenness degree of the temperature distribution.The uneven temperature distribution over the spherical shell surface in conditions of the lowEarth space and this unevenness impact on the shell shape variation against its spherical shape can be quantively estimated by the appropriate methods of mathematical modeling using modification of a previously developed mathematical model to describe steady temperature state of such shell on the low-Earth orbit. The paper considers the shell made from a polymeric composite material. Its original spherical shape is defined by rather low internal pressure. It is assumed that equipment in the shell, if any, is quite small-sized. This allows us to ignore its impact on the radiative transfer in the shell cavity. Along with defining the steady temperature distribution over the shell surface at its fixed orientation with respect to

Infrared Model Spectra for Evolving Red Supergiants

Directory of Open Access Journals (Sweden)

Kyung-Won Suh

1993-06-01

Full Text Available The space and ground based infrared spectra of red supergiants are modeled and arranged in order of their evolutionary status with their theoretical model parameters. The chemical compositions of the dust shells around red supergiants are affected by the nuclear reaction and dredge-up processes of the cental stars. The processes are sensitively dependent on the initial mass, the initial chemical composition, and the evolutionary status. Miras, infrared carbon stars, and OH/IR stars have close link in their evolution in manu aspects, i,e., the chemical composition, the optical depths and the mass loss rates. The evolutionary tracks for the three classes of red supergiants on infrared two-color diagrams have been made from model calculations and IRAS observational data.

Strength Calculation of Locally Loaded Orthotropic Shells

Directory of Open Access Journals (Sweden)

Yu. I. Vinogradov

2015-01-01

Full Text Available The article studies laminated orthotropic cylindrical, conic, spherical, and toroidal shells, which are often locally loaded in the aircraft designs over small areas of their surfaces.The aim of this work is to determine stress concentration in shells versus structure of orthotropic composite material, shell form and parameters, forms of loading areas, which borders do not coincide with lines of main curvatures of shells. For this purpose, an analytical computing algorithm to estimate strength of shells in terms of stress is developed. It enables us to have solution results of the boundary value problem with a controlled error. To solve differential equations an analytical method is used. An algorithm of the boundary value problem solution is multiplicative.The main results of researches are graphs of stress concentration in the orthotropic shells versus their parameters and areas of loading lineated by circles and ellipses.Among the other works aimed at determination of stress concentration in shells, the place of this one is defined by the analytical solution of applied problems for strength estimation in terms of shell stresses of classical forms.The developed effective analytical algorithm to solve the boundary value problem and received results are useful in research and development.

The Mendelian inheritance of rare flesh and shell colour variants in the black-lipped pearl oyster (Pinctada margaritifera).

Science.gov (United States)

Ky, Chin-Long; Nakasai, Seiji; Pommier, Steve; Sham Koua, Manaarii; Devaux, Dominique

2016-10-01

Pinctada margaritifera is French Polynesia's most economically important aquaculture species. This pearl oyster has the specific ability to produce cultured pearls with a very wide range of colours, depending on the colour phenotypes of donor oysters used. Its aquaculture is still based on natural spat collection from wild stocks. We investigated three rare colour variants of P. margaritifera - orange flesh, and red and white shell colour phenotypes - in comparison with the wild-type black flesh and shell commonly found in this species. The study aimed to assess the geographic distribution and genetic basis of these colour variants. Colour frequencies were evaluated during transfer and graft processes of pearl oyster seed captured at collector stations. Among the collection locations studied, Mangareva Island showed the highest rate of the orange flesh phenotype, whereas Takaroa and Takume atolls had relatively high rates of red and white shell phenotypes respectively. Broodstocks were made of these rare colour variants, and crosses were performed to produce first- and second-generation progenies to investigate segregation. The results were consistent with Mendelian ratios and suggest a distinct model with no co-dominance: (i) a two-allele model for flesh trait, whereby the orange allele is recessive to the black fleshed type, and (ii) a three-allele model for shell trait, whereby the black wild-type allele is dominant to the red coloration, which is dominant to the white shell. Furthermore, the proposed model provides the basis for producing selected donor pearl oyster lines through hatchery propagation. © 2016 Stichting International Foundation for Animal Genetics.

Synthesis and characterization of ZnSe:Fe/ZnSe core/shell nanocrystals

Energy Technology Data Exchange (ETDEWEB)

Yang, Lin; Zhu, Jianguo, E-mail: yanglin_1028@163.com; Xiao, Dingquan

2014-04-15

High-quality ZnSe:Fe/ZnSe core/shell nanocrystals were prepared via a hydrothermal microemulsion technique. Effective surface passivation of monodisperse ZnSe:Fe nanocrystals is achieved by overcoating them with a ZnSe shell. The samples were characterized by means of XRD, EDX, TEM, PSD, XPS, photoluminescence, and Raman spectrum. The results show that the as-synthesized nanocrystals are cubic zinc blende ZnSe structure with high purity and the average particle size of ZnSe:Fe/ZnSe core/shell nanocrystal is larger than that of ZnSe:Fe core. The growth of ZnSe shell causes a small red shift in PL spectra, and then the PL quantum yield (QY) increases from 16% before shell growth to the maximum of 37% after increasing shell thickness up to 1.2 monolayers (ML). Moreover, both transverse optic (TO) and longitudinal optic (LO) phonon modes of ZnSe are shifted toward lower frequency as compared with the reported ones. -- Highlights: • ZnSe:Fe/ZnSe core/shell QDs were prepared by a hydrothermal microemulsion method. • ZnSe shell efficiently passivates surface defects by serving as a physical barrier. • The particle size and PL properties can be turned with the growth of ZnSe shell. • The luminescence efficiency and stability of QDs could be improved in this manner.

7X performance results - final report : ASCI Red vs Red Storm.

Energy Technology Data Exchange (ETDEWEB)

Dinge, Dennis C. (Cray Inc., Albuquerque, NM); Davis, Michael E. (Cray Inc., Albuquerque, NM); Haskell, Karen H.; Ballance, Robert A.; Gardiner, Thomas Anthony; Stevenson, Joel O.; Noe, John P.

2011-04-01

The goal of the 7X performance testing was to assure Sandia National Laboratories, Cray Inc., and the Department of Energy that Red Storm would achieve its performance requirements which were defined as a comparison between ASCI Red and Red Storm. Our approach was to identify one or more problems for each application in the 7X suite, run those problems at multiple processor sizes in the capability computing range, and compare the results between ASCI Red and Red Storm. The first part of this report describes the two computer systems, the applications in the 7X suite, the test problems, and the results of the performance tests on ASCI Red and Red Storm. During the course of the testing on Red Storm, we had the opportunity to run the test problems in both single-core mode and dual-core mode and the second part of this report describes those results. Finally, we reflect on lessons learned in undertaking a major head-to-head benchmark comparison.

21 CFR 640.10 - Red Blood Cells.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 7 2010-04-01 2010-04-01 false Red Blood Cells. 640.10 Section 640.10 Food and... ADDITIONAL STANDARDS FOR HUMAN BLOOD AND BLOOD PRODUCTS Red Blood Cells § 640.10 Red Blood Cells. The proper name of this product shall be Red Blood Cells. The product is defined as red blood cells remaining...

On-shell diagrams for N=8 supergravity amplitudes

Energy Technology Data Exchange (ETDEWEB)

Heslop, Paul; Lipstein, Arthur E. [Department of Mathematical Sciences, Durham University,Lower Mountjoy, Stockton Road, Durham, DH1 3LE (United Kingdom)

2016-06-10

We define recursion relations for N=8 supergravity amplitudes using a generalization of the on-shell diagrams developed for planar N=4 super-Yang-Mills. Although the recursion relations generically give rise to non-planar on-shell diagrams, we show that at tree-level the recursion can be chosen to yield only planar diagrams, the same diagrams occurring in the planar N=4 theory. This implies non-trivial identities for non-planar diagrams as well as interesting relations between the N=4 and N=8 theories. We show that the on-shell diagrams of N=8 supergravity obey equivalence relations analogous to those of N=4 super-Yang-Mills, and we develop a systematic algorithm for reading off Grassmannian integral formulae directly from the on-shell diagrams. We also show that the 1-loop 4-point amplitude of N=8 supergravity can be obtained from on-shell diagrams.

Methane explosion suppression characteristics based on the NaHCO3/red-mud composite powders with core-shell structure.

Science.gov (United States)

Wang, Yan; Cheng, Yi-Shen; Yu, Ming-Gao; Li, Yao; Cao, Jian-Liang; Zheng, Li-Gang; Yi, Hong-Wei

2017-08-05

The NaHCO 3 /red-mud (RM) composite powders were successfully prepared by the solvent-anti-solvent method for methane explosion suppression. The RM was used as a carrier, and the NaHCO 3 was used as a loaded inhibitor. The NaHCO 3 /RM composite powders showed a special core-shell structure and excellent endothermic performance. The suppression properties of NaHCO 3 /RM composite for 9.5% CH 4 explosion were tested in a 20L spherical explosion vessel and a 5L Perspex duct. The results showed that the NaHCO 3 /RM composite powders displayed a much better suppression property than the pure RM or NaHCO 3 powders. The loading amount of NaHCO 3 has an intensive influence on the inhibition property of NaHCO 3 /RM composite powders. The best loaded content of NaHCO 3 is 35%. It exhibited significant inhibitory effect that the explosion max-pressure declined 44.9%, the max-pressure rise rate declined 96.3% and the pressure peak time delayed 366.7%, respectively. Copyright © 2017 Elsevier B.V. All rights reserved.

Automatic determination of 3D orientations of fossilized oyster shells from a densely packed Miocene shell bed

Science.gov (United States)

Puttonen, Ana; Harzhauser, Mathias; Puttonen, Eetu; Mandic, Oleg; Székely, Balázs; Molnár, Gábor; Pfeifer, Norbert

2018-02-01

Shell beds represent a useful source of information on various physical processes that cause the depositional condition. We present an automated method to calculate the 3D orientations of a large number of elongate and platy objects (fossilized oyster shells) on a sedimentary bedding plane, developed to support the interpretation of possible depositional patterns, imbrications, or impact of local faults. The study focusses on more than 1900 fossil oyster shells exposed in a densely packed Miocene shell bed. 3D data were acquired by terrestrial laser scanning on an area of 459 m2 with a resolution of 1 mm. Bivalve shells were manually defined as 3D-point clouds of a digital surface model and stored in an ArcGIS database. An individual shell coordinate system (ISCS) was virtually embedded into each shell and its orientation was determined relative to the coordinate system of the entire, tectonically tilted shell bed. Orientation is described by the rotation angles roll, pitch, and yaw in a Cartesian coordinate system. This method allows an efficient measurement and analysis of the orientation of thousands of specimens and is a major advantage compared to the traditional 2D approach, which measures only the azimuth (yaw) angles. The resulting data can variously be utilized for taphonomic analyses and the reconstruction of prevailing hydrodynamic regimes and depositional environments. For the first time, the influence of possible post-sedimentary vertical displacements can be quantified with high accuracy. Here, the effect of nearby fault lines—present in the reef—was tested on strongly tilted oyster shells, but it was found out that the fault lines did not have a statistically significant effect on the large tilt angles. Aside from the high reproducibility, a further advantage of the method is its non-destructive nature, which is especially suitable for geoparks and protected sites such as the studied shell bed.

Tropical sea snail shells: Possible exotic sources for ceramic biomaterial synthesis

Science.gov (United States)

Oktar, F. N.; Kiyici, I. A.; Gökçe, H.; Aǧaogulları, D.; Kayali, E. S.

2013-12-01

In this study, chemical and structural properties of sea snail shell based bioceramic materials (i.e. hydroxyapatite, whitlockite and other phases) are produced by using mechano-chemical (ultrasonic) conversion method. For this purpose, differential thermal and gravimetric analysis (DTA/TG), X-ray diffraction, infra-red (IR) and scanning electron microscope (SEM) studies are performed.

Tropical sea snail shells: Possible exotic sources for ceramic biomaterial synthesis

Energy Technology Data Exchange (ETDEWEB)

Oktar, F. N. [Bioengineering Dept., Faculty of Engineering, Marmara Univ., Istanbul, Turkey, and Medical Imaging Technics Dept., School of Health Related Professions, Marmara Univ., Istanbul, Turkey, and Nanotechnology and Biomaterials Research and Application Cen (Turkey); Kiyici, I. A. [Graduate School of Natural and Applied Sciences, Biomedical Engineering, Kocaeli University, Kocaeli (Turkey); Gökçe, H. [Metallurgical and Materials Engineering Dept., Istanbul Technical Univ., Istanbul, Turkey, and Prof. Dr. Adnan Tekin Material Sciences and Production Technologies Applied Research Center, Istanbul Technical Univ., Istanbul (Turkey); Ağaogulları, D.; Kayali, E. S. [Metallurgical and Materials Engineering Dept., Istanbul Technical Univ., Istanbul (Turkey)

2013-12-16

In this study, chemical and structural properties of sea snail shell based bioceramic materials (i.e. hydroxyapatite, whitlockite and other phases) are produced by using mechano-chemical (ultrasonic) conversion method. For this purpose, differential thermal and gravimetric analysis (DTA/TG), X-ray diffraction, infra-red (IR) and scanning electron microscope (SEM) studies are performed.

Yang-Mills theory on the mass shell

International Nuclear Information System (INIS)

Cvitanovic, P.

1976-01-01

Gauge-invariant mass-shell amplitudes for quantum electrodynamics (QED) and Yang-Mills theory are defined by dimensional regularization. Gauge invariance of the mass-shell renormalization constants is maintained through interplay of ultraviolet and infrared divergences. Quark renormalizations obey the same simple Ward identity as do the electron renormalizations in QED, while the gluon contributions to gluon renormalizations are identically zero. The simplest amplitude finite in QED, the magnetic moment, is gauge-invariant but divergent in Yang-Mills theory for both external gluon and external photon

Graphitic carbon nitride nanosheet@metal-organic framework core-shell nanoparticles for photo-chemo combination therapy

Science.gov (United States)

Chen, Rui; Zhang, Jinfeng; Wang, Yu; Chen, Xianfeng; Zapien, J. Antonio; Lee, Chun-Sing

2015-10-01

Recently, nanoscale metal-organic frameworks (NMOFs) have started to be developed as a promising platform for bioimaging and drug delivery. On the other hand, combination therapies using multiple approaches are demonstrated to achieve much enhanced efficacy. Herein, we report, for the first time, core-shell nanoparticles consisting of a photodynamic therapeutic (PDT) agent and a MOF shell while simultaneously carrying a chemotherapeutic drug for effective combination therapy. In this work, core-shell nanoparticles of zeolitic-imadazolate framework-8 (ZIF-8) as shell embedded with graphitic carbon nitride (g-C3N4) nanosheets as core are fabricated by growing ZIF-8 in the presence of g-C3N4 nanosheets. Doxorubicin hydrochloride (DOX) is then loaded into the ZIF-8 shell of the core-shell nanoparticles. The combination of the chemotherapeutic effects of DOX and the PDT effect of g-C3N4 nanosheets can lead to considerably enhanced efficacy. Furthermore, the red fluorescence of DOX and the blue fluorescence of g-C3N4 nanosheets provide the additional function of dual-color imaging for monitoring the drug release process.Recently, nanoscale metal-organic frameworks (NMOFs) have started to be developed as a promising platform for bioimaging and drug delivery. On the other hand, combination therapies using multiple approaches are demonstrated to achieve much enhanced efficacy. Herein, we report, for the first time, core-shell nanoparticles consisting of a photodynamic therapeutic (PDT) agent and a MOF shell while simultaneously carrying a chemotherapeutic drug for effective combination therapy. In this work, core-shell nanoparticles of zeolitic-imadazolate framework-8 (ZIF-8) as shell embedded with graphitic carbon nitride (g-C3N4) nanosheets as core are fabricated by growing ZIF-8 in the presence of g-C3N4 nanosheets. Doxorubicin hydrochloride (DOX) is then loaded into the ZIF-8 shell of the core-shell nanoparticles. The combination of the chemotherapeutic effects of DOX

'Smart' Diblock Copolymers as Templates for Magnetic-Core Gold-Shell Nanoparticle Synthesis

International Nuclear Information System (INIS)

Nash, Michael A.; Lai, James J.; Hoffman, Allan S.; Yager, Paul; Stayton, Partick S.

2010-01-01

We report a new strategy for synthesizing temperature-responsive γ-Fe 2 O 3 -core/Au-shell nanoparticles (Au-mNPs) from diblock copolymer micelles. The amphiphilic diblock copolymer chains were synthesized using reversible addition-fragmentation chain-transfer (RAFT) with a thermally responsive 'smart' poly(N-isopropylacrylamide) (pNIPAAm) block and an amine-containing poly(N,N-dimethylaminoethylacrylamide) (DMAEAm) block that acted as a reducing agent during gold shell formation. The Au-mNPs reversibly aggregated upon heating the solution above the transition temperature of pNIPAAm, resulting in a red-shifted localized surface plasmon resonance.

Stepwise synthesis of cubic Au-AgCdS core-shell nanostructures with tunable plasmon resonances and fluorescence.

Science.gov (United States)

Liu, Xiao-Li; Liang, Shan; Nan, Fan; Pan, Yue-Yue; Shi, Jun-Jun; Zhou, Li; Jia, Shuang-Feng; Wang, Jian-Bo; Yu, Xue-Feng; Wang, Qu-Quan

2013-10-21

Cubic Au-AgCdS core-shell nanostructures were synthesized through cation exchange method assisted by tributylphosphine (TBP) as a phase-transfer agent. Among intermediate products, Au-Ag core-shell nanocubes exhibited many high-order plasmon resonance modes related to the special cubic shape, and these plasmon bands red-shifted along with the increasing of particle size. The plasmon band of Au core first red-shifted and broadened at the step of Au-Ag₂S and then blue-shifted and narrowed at the step of Au-AgCdS. Since TBP was very crucial for the efficient conversion from Ag₂S to CdS, we found that both absorption and fluorescence of the final products could be controlled by TBP.

Pair of null gravitating shells: III. Algebra of Dirac's observables

International Nuclear Information System (INIS)

Kouletsis, I; Hajicek, P

2002-01-01

The study of the two-shell system started in 'pair of null gravitating shells I and II' is continued. The pull back of the Liouville form to the constraint surface, which contains complete information about the Poisson brackets of Dirac observables, is computed in the singular double-null Eddington-Finkelstein (DNEF) gauge. The resulting formula shows that the variables conjugate to the Schwarzschild masses of the intershell spacetimes are simple combinations of the values of the DNEF coordinates on these spacetimes at the shells. The formula is valid for any number of in- and outgoing shells. After applying it to the two-shell system, the symplectic form is calculated for each component of the physical phase space; regular coordinates are found, defining it as a symplectic manifold. The symplectic transformation between the initial and final values of observables for the shell-crossing case is given

Structure of the first- and second-neighbor shells of simulated water: Quantitative relation to translational and orientational order

Science.gov (United States)

Yan, Zhenyu; Buldyrev, Sergey V.; Kumar, Pradeep; Giovambattista, Nicolas; Debenedetti, Pablo G.; Stanley, H. Eugene

2007-11-01

We perform molecular dynamics simulations of water using the five-site transferable interaction potential (TIP5P) model to quantify structural order in both the first shell (defined by four nearest neighbors) and second shell (defined by twelve next-nearest neighbors) of a central water molecule. We find that the anomalous decrease of orientational order upon compression occurs in both shells, but the anomalous decrease of translational order upon compression occurs mainly in the second shell. The decreases of translational order and orientational order upon compression (called the “structural anomaly”) are thus correlated only in the second shell. Our findings quantitatively confirm the qualitative idea that the thermodynamic, structural, and hence dynamic anomalies of water are related to changes upon compression in the second shell.

NIF Double Shell outer/inner shell collision experiments

Science.gov (United States)

Merritt, E. C.; Loomis, E. N.; Wilson, D. C.; Cardenas, T.; Montgomery, D. S.; Daughton, W. S.; Dodd, E. S.; Desjardins, T.; Renner, D. B.; Palaniyappan, S.; Batha, S. H.; Khan, S. F.; Smalyuk, V.; Ping, Y.; Amendt, P.; Schoff, M.; Hoppe, M.

2017-10-01

Double shell capsules are a potential low convergence path to substantial alpha-heating and ignition on NIF, since they are predicted to ignite and burn at relatively low temperatures via volume ignition. Current LANL NIF double shell designs consist of a low-Z ablator, low-density foam cushion, and high-Z inner shell with liquid DT fill. Central to the Double Shell concept is kinetic energy transfer from the outer to inner shell via collision. The collision determines maximum energy available for compression and implosion shape of the fuel. We present results of a NIF shape-transfer study: two experiments comparing shape and trajectory of the outer and inner shells at post-collision times. An outer-shell-only target shot measured the no-impact shell conditions, while an `imaging' double shell shot measured shell conditions with impact. The `imaging' target uses a low-Z inner shell and is designed to perform in similar collision physics space to a high-Z double shell but can be radiographed at 16keV, near the viable 2DConA BL energy limit. Work conducted under the auspices of the U.S. DOE by LANL under contract DE-AC52-06NA25396.

Synthesis and optical study of green light emitting polymer coated CdSe/ZnSe core/shell nanocrystals

Energy Technology Data Exchange (ETDEWEB)

Tripathi, S.K., E-mail: surya@pu.ac.in [Department of Physics, Center of Advanced Study in Physics, Panjab University, Chandigarh 160 014 (India); Sharma, Mamta [Department of Physics, Center of Advanced Study in Physics, Panjab University, Chandigarh 160 014 (India)

2013-05-15

Highlights: ► Synthesis of Polymer coated core CdSe and CdSe/ZnSe core/shell NCs. ► From TEM image, the spherical nature of CdSe and CdSe/ZnSe is obtained. ► Exhibiting green band photoemission peak at 541 nm and 549 nm for CdSe core and CdSe/ZnSe core/shell NCs. ► The shell thickness has been calculated by using superposition of quantum confinement energy model. - Abstract: CdSe/ZnSe Core/Shell NCs dispersed in PVA are synthesized by chemical method at room temperature. This is characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), UV/Vis spectra and photoluminescence spectroscopy (PL). TEM image shows the spherical nature of CdSe/ZnSe core/shell NCs. The red shift of absorption and emission peak of CdSe/ZnSe core/shell NCs as compared to CdSe core confirmed the formation of core/shell. The superposition of quantum confinement energy model is used for calculation of thickness of ZnSe shell.

Energy transfer in aggregated CuInS2/ZnS core-shell quantum dots deposited as solid films

International Nuclear Information System (INIS)

Gardelis, S; Georgiadou, D; Travlos, A; Nassiopoulou, A G; Fakis, M; Droseros, N

2017-01-01

We report on the morphology and optical properties of CuInS 2 /ZnS core-shell quantum dots in solid films by means of AFM, SEM, HRTEM, steady state and time-resolved photoluminescence (PL) spectroscopy. The amount of aggregation of the CuInS 2 /ZnS QDs was controlled by changing the preparation conditions of the films. A red-shift of the PL spectrum of CuInS 2 /ZnS core-shell quantum dots, deposited as solid films on silicon substrates, is observed upon increasing the amount of aggregation. The presence of larger aggregates was found to lead to a larger PL red-shift. Besides, as the degree of aggregation increased, the PL decay became slower. We attribute the observed PL red-shift to energy transfer from the smaller to the larger dots within the aggregates, with the emission being realized via a long decay recombination mechanism (100–200 ns), the origin of which is discussed. (paper)

The feasibility of bomb radiocarbon analysis to support an age-at-length relationship for red abalone, Haliotis rufescens Swainson in northern California

Energy Technology Data Exchange (ETDEWEB)

Leaf, R T; Andrews, A H; Cailliet, G M; Brown, T A

2009-01-07

Analysis of bomb generated radiocarbon ({sup 14}C) changes in a red abalone, Haliotis rufescens Swainson shell was used to investigate age-at-length relationships derived from data from a previous multi-year, multi-site tag-recapture study. Shell carbonate was extracted from four successive growth trajectory locations in a single shell with a length of 251 mm MSL. Extraction locations were based on VBGF predictions and chosen to span the initial rise of the {sup 14}C-bomb pulse that is known to have occurred in surface ocean waters during 1958 {+-} 1 y in the northeast Pacific. The close temporal correspondence of the red abalone sample series to regional {Delta}{sup 14}C records demonstrated the utility of the technique for validating age-at-length relationships for the red abalone. The findings provided support for a mean VBGF derived age of 32 y (range 30 to 33 y) for the specimen; however, the analysis of {sup 14}C data indicated that the specimen could be older.

A methodology to define the flow rate and pressure requirements for transfer of double-shell tank waste slurries

International Nuclear Information System (INIS)

Bamberger, J.A.; Liljegren, L.M.

1993-04-01

This document presents an analysis of the pressure drop and flow rate double-shell tank slurries. Experiments to requirements for transport of characterize the transport of double-shell tank slurries through piping networks and to resuspend materials that settle during pump outages are proposed. Reported values of physical properties of double-shell tank slurries were analyzed to evaluate the flow regimes that are likely to occur during transport. The results of these evaluations indicate that the slurry will be pseudohomogeneous during transport and that the slurry rheology is sufficiently non-Newtonian to affect both the pressure drop achieved during transport and the critical Reynolds number. The transport data collected in the non-Newtonian experiment will be used to determine whether a non-Newtonian correlation developed by Hanks (1978) adequately describes the experimental results

Single-step generation of fluorophore-encapsulated gold nanoparticle core-shell materials

International Nuclear Information System (INIS)

Sardar, R; Shem, P M; Pecchia-Bekkum, C; Bjorge, N S; Shumaker-Parry, J S

2010-01-01

We report a simple route to produce fluorophore-encapsulated gold nanoparticles (AuNPs) in a single step under aqueous conditions using the fluorophore 1-pyrenemethylamine (PMA). Different amounts of PMA were used and the resulting core-shell gold nanoparticles were analyzed using UV-visible absorption spectroscopy, fluorescence spectroscopy, and transmission and scanning electron microscopy. Electron microscopy analysis shows nanoparticles consisting of a gold nanoparticle core which is encapsulated with a lower contrast shell. In the UV-visible spectra, we observed a significant red shift (37 nm) of the localized surface plasmon resonance (LSPR) absorption maximum (λ max ) compared to citrate-stabilized AuNPs of a similar size. We attribute the prominent LSPR wavelength shift for PMA-AuNP conjugates to the increase in the local dielectric environment near the gold nanoparticles due to the shell formation. This simple, aqueous-based synthesis is a new approach to the production of fluorophore-encapsulated AuNPs that could be applicable in biological sensing systems and photonic device fabrication.

Data on internal cDNA amplification and color changes of the proteins derived from Pacific white leg shrimp shell.

Science.gov (United States)

Chuang, Pan; Shoichiro, Ishizaki; Yuji, Nagashima; Jialong, Gao; Shugo, Watabe

2018-02-01

In this article, we report original data on the designation of the primers for full-length cDNA amplification and the internal cDNA amplification of red color-related pigment-binding protein derived from shrimp shell. Data on the color shifts of different soluble proteins under 100 °C 10 min heat treatment and the effects of heating temperatures (from 30 to 100 °C) on the color changes of crude water-soluble proteins are also included in this report. For further details and experimental findings please refer to the article "Isolation and cDNA cloning of a novel red color-related pigment-binding protein derived from the shell of shrimp, Litopenaeus vannamei " (Chuang et al., 2017) [1].

Data on internal cDNA amplification and color changes of the proteins derived from Pacific white leg shrimp shell

Directory of Open Access Journals (Sweden)

Pan Chuang

2018-02-01

Full Text Available In this article, we report original data on the designation of the primers for full-length cDNA amplification and the internal cDNA amplification of red color-related pigment-binding protein derived from shrimp shell. Data on the color shifts of different soluble proteins under 100 °C 10 min heat treatment and the effects of heating temperatures (from 30 to 100 °C on the color changes of crude water-soluble proteins are also included in this report. For further details and experimental findings please refer to the article “Isolation and cDNA cloning of a novel red color-related pigment-binding protein derived from the shell of shrimp, Litopenaeus vannamei” (Chuang et al., 2017 [1].

Open source integrated modeling environment Delta Shell

Science.gov (United States)

Donchyts, G.; Baart, F.; Jagers, B.; van Putten, H.

2012-04-01

In the last decade, integrated modelling has become a very popular topic in environmental modelling since it helps solving problems, which is difficult to model using a single model. However, managing complexity of integrated models and minimizing time required for their setup remains a challenging task. The integrated modelling environment Delta Shell simplifies this task. The software components of Delta Shell are easy to reuse separately from each other as well as a part of integrated environment that can run in a command-line or a graphical user interface mode. The most components of the Delta Shell are developed using C# programming language and include libraries used to define, save and visualize various scientific data structures as well as coupled model configurations. Here we present two examples showing how Delta Shell simplifies process of setting up integrated models from the end user and developer perspectives. The first example shows coupling of a rainfall-runoff, a river flow and a run-time control models. The second example shows how coastal morphological database integrates with the coastal morphological model (XBeach) and a custom nourishment designer. Delta Shell is also available as open-source software released under LGPL license and accessible via http://oss.deltares.nl.

Electroless nickel – phosphorus coating on crab shell particles and its characterization

Energy Technology Data Exchange (ETDEWEB)

Arulvel, S., E-mail: gs.arulvel.research@gmail.com; Elayaperumal, A.; Jagatheeshwaran, M.S.

2017-04-15

Being hydrophilic material, crab shell particles have only a limited number of applications. It is, therefore, necessary to modify the surface of the crab shell particles. To make them useful ever for the applications, the main theme we proposed in this article is to utilize crab shell particles (CSP) with the core coated with nickel phosphorus (NiP) as a shell using the electroless coating process. For dealing with serious environmental problems, utilization of waste bio-shells is always an important factor to be considered. Chelating ability of crab shell particles eliminates the surface activation in this work proceeding to the coating process. The functional group, phase structure, microstructure, chemical composition and thermal analysis of CSP and NiP/CSP were characterized using Fourier transform infra-red spectroscopy (FTIR), x-ray diffraction analyzer (XRD), scanning electron microscope (SEM), energy-dispersive x-ray spectroscopy (EDS), and thermogravimetric analysis (TGA). The combination of an amorphous and crystalline structure was exhibited by CSP and NiP/CSP. NiP/CSP has shown a better thermal stability when compared to uncoated CSP. Stability test, adsorption test, and conductivity test were conducted for the study of adsorption behavior and conductivity of the particles. CSP presented a hydrophilic property in contrast to hydrophobic NiP/CSP. NiP/CSP presented a conductivity of about 44% greater compared to the CSP without any fluctuations. - Highlights: • Utilization of crab shell waste is focused on. • NiP coating on crab shell particle is fabricated using electroless process. • Thermal analysis, stability test, adsorption test and conductivity test were done. • Organic matrix of crab shell particle favors the coating process. • Results demonstrate the characterization of CSP core – NiP shell structure.

Shell Venster

International Nuclear Information System (INIS)

De Wit, P.; Looijesteijn, B.; Regeer, B.; Stip, B.

1995-03-01

In the bi-monthly issues of 'Shell Venster' (window on Shell) attention is paid to the activities of the multinational petroleum company Shell Nederland and the Koninklijke/Shell Groep by means of non-specialist articles

Single-shell tank interim stabilization project plan

Energy Technology Data Exchange (ETDEWEB)

Ross, W.E.

1998-05-11

This project plan establishes the management framework for conduct of the TWRS Single-Shell Tank Interim Stabilization completion program. Specifically, this plan defines the mission needs and requirements; technical objectives and approach; organizational structure, roles, responsibilities, and interfaces; and operational methods. This plan serves as the project executional baseline.

Food Protein Based Core-Shell Nanocarriers for Oral Drug Delivery: Effect of Shell Composition on in Vitro and in Vivo Functional Performance of Zein Nanocarriers.

Science.gov (United States)

Alqahtani, Mohammed S; Islam, M Saiful; Podaralla, Satheesh; Kaushik, Radhey S; Reineke, Joshua; Woyengo, Tofuko; Perumal, Omathanu

2017-03-06

The study was aimed at systematically investigating the influence of shell composition on the particle size, stability, release, cell uptake, permeability, and in vivo gastrointestinal distribution of food protein based nanocarriers for oral delivery applications. Three different core-shell nanocarriers were prepared using food-grade biopolymers including zein-casein (ZC) nanoparticles, zein-lactoferrin (ZLF), nanoparticles and zein-PEG (ZPEG) micelles. Nile red was used as a model hydrophobic dye for in vitro studies. The nanocarriers had negative, positive, and neutral charge, respectively. All three nanocarriers had a particle size of less than 200 nm and a low polydispersity index. The nanoparticles were stable at gastrointestinal pH (2-9) and ionic strength (10-200 mM). The nanocarriers sustained the release of Nile red in simulated gastric and intestinal fluids. ZC nanoparticles showed the slowest release followed by ZLF nanoparticles and ZPEG micelles. The nanocarriers were taken up by endocytosis in Caco-2 cells. ZPEG micelles showed the highest cell uptake and transepithelial permeability followed by ZLF and ZC nanoparticles. ZPEG micelles also showed P-gp inhibitory activity. All three nanocarriers showed bioadhesive properties. Cy 5.5, a near IR dye, was used to study the in vivo biodistribution of the nanocarriers. The nanocarriers showed longer retention in the rat gastrointestinal tract compared to the free dye. Among the three formulations, ZC nanoparticles was retained the longest in the rat gastrointestinal tract (≥24 h). Overall, the outcomes from this study demonstrate the structure-function relationship of core-shell protein nanocarriers. The findings from this study can be used to develop food protein based oral drug delivery systems with specific functional attributes.

Importance-truncated shell model for multi-shell valence spaces

Energy Technology Data Exchange (ETDEWEB)

Stumpf, Christina; Vobig, Klaus; Roth, Robert [Institut fuer Kernphysik, TU Darmstadt (Germany)

2016-07-01

The valence-space shell model is one of the work horses in nuclear structure theory. In traditional applications, shell-model calculations are carried out using effective interactions constructed in a phenomenological framework for rather small valence spaces, typically spanned by one major shell. We improve on this traditional approach addressing two main aspects. First, we use new effective interactions derived in an ab initio approach and, thus, establish a connection to the underlying nuclear interaction providing access to single- and multi-shell valence spaces. Second, we extend the shell model to larger valence spaces by applying an importance-truncation scheme based on a perturbative importance measure. In this way, we reduce the model space to the relevant basis states for the description of a few target eigenstates and solve the eigenvalue problem in this physics-driven truncated model space. In particular multi-shell valence spaces are not tractable otherwise. We combine the importance-truncated shell model with refined extrapolation schemes to approximately recover the exact result. We present first results obtained in the importance-truncated shell model with the newly derived ab initio effective interactions for multi-shell valence spaces, e.g., the sdpf shell.

Desorption of Reactive Red 198 from activated carbon prepared from walnut shells: effects of temperature, sodium carbonate concentration and organic solvent dose

Directory of Open Access Journals (Sweden)

Zohreh Alimohamadi

2017-04-01

Full Text Available This study investigated the effect of temperature, different concentrations of sodium carbonate,and the dose of organic solvent on the desorption of Reactive Red 198 dye from dye-saturated activated carbon using batch and continuous systems. The results of the batch desorption test showed 60% acetone in water as the optimum amount. However, when the concentration of sodium carbonate was raised, the dye desorption percentage increased from 26% to 42% due to economic considerations; 15 mg/L of sodium carbonate was selected to continue the processof desorption. Increasing the desorption temperature can improve the dye desorption efficiency.According to the column test results, dye desorption concentration decreased gradually with the passing of time. The column test results showed that desorption efficiency and the percentage of dye adsorbed decreased; however, it seemed to stabilize after three repeated adsorption/desorption cycles. The repeated adsorption–desorption column tests (3 cycles showed that the activated carbon which was prepared from walnut shell was a suitable and economical adsorbent for dye removal.

MicroShell Minimalist Shell for Xilinx Microprocessors

Science.gov (United States)

Werne, Thomas A.

2011-01-01

MicroShell is a lightweight shell environment for engineers and software developers working with embedded microprocessors in Xilinx FPGAs. (MicroShell has also been successfully ported to run on ARM Cortex-M1 microprocessors in Actel ProASIC3 FPGAs, but without project-integration support.) Micro Shell decreases the time spent performing initial tests of field-programmable gate array (FPGA) designs, simplifies running customizable one-time-only experiments, and provides a familiar-feeling command-line interface. The program comes with a collection of useful functions and enables the designer to add an unlimited number of custom commands, which are callable from the command-line. The commands are parameterizable (using the C-based command-line parameter idiom), so the designer can use one function to exercise hardware with different values. Also, since many hardware peripherals instantiated in FPGAs have reasonably simple register-mapped I/O interfaces, the engineer can edit and view hardware parameter settings at any time without stopping the processor. MicroShell comes with a set of support scripts that interface seamlessly with Xilinx's EDK tool. Adding an instance of MicroShell to a project is as simple as marking a check box in a library configuration dialog box and specifying a software project directory. The support scripts then examine the hardware design, build design-specific functions, conditionally include processor-specific functions, and complete the compilation process. For code-size constrained designs, most of the stock functionality can be excluded from the compiled library. When all of the configurable options are removed from the binary, MicroShell has an unoptimized memory footprint of about 4.8 kB and a size-optimized footprint of about 2.3 kB. Since MicroShell allows unfettered access to all processor-accessible memory locations, it is possible to perform live patching on a running system. This can be useful, for instance, if a bug is

Immediate catalytic upgrading of soybean shell bio-oil

International Nuclear Information System (INIS)

Bertero, Melisa; Sedran, Ulises

2016-01-01

The pyrolysis of soybean shell and the immediate catalytic upgrading of the bio-oil over an equilibrium FCC catalyst was studied in order to define its potential as a source for fuels and chemicals. The experiments of pyrolysis and immediate catalytic upgrading were performed at 550 °C during 7 min with different catalysts to oil relationships in an integrated fixed bed pyrolysis-conversion reactor. The results were compared under the same conditions against those from pine sawdust, which is a biomass source commonly used for the production of bio-oil. In the pyrolysis the pine sawdust produced more liquids (61.4%wt.) than the soybean shell (54.7%wt.). When the catalyst was presented, the yield of hydrocarbons increased, particularly in the case of soybean shell, which was four time higher than in the pyrolysis. The bio-oil from soybean shell produced less coke (between 3.1 and 4.3%wt.) in its immediate catalytic upgrading than that from pine sawdust (between 5 and 5.8%wt.), due to its lower content of phenolic and other high molecular weight compounds (three and five times less, respectively). Moreover, soybean shell showed a higher selectivity to hydrocarbons in the gasoline range, with more olefins and less aromatic than pine sawdust. - Highlights: • Soybean shell is a possible source of fuels with benefits as compared to pine sawdust. • Bio-oils upgraded over FCC catalyst in an integrated pyrolysis-conversion reactor. • Pine sawdust bio-oil had more phenols than soybean shell bio-oil. • Soybean shell bio-oil produced more hydrocarbons in gasoline range and less coke.

Evolutionary tradeoffs, Pareto optimality and the morphology of ammonite shells.

Science.gov (United States)

Tendler, Avichai; Mayo, Avraham; Alon, Uri

2015-03-07

Organisms that need to perform multiple tasks face a fundamental tradeoff: no design can be optimal at all tasks at once. Recent theory based on Pareto optimality showed that such tradeoffs lead to a highly defined range of phenotypes, which lie in low-dimensional polyhedra in the space of traits. The vertices of these polyhedra are called archetypes- the phenotypes that are optimal at a single task. To rigorously test this theory requires measurements of thousands of species over hundreds of millions of years of evolution. Ammonoid fossil shells provide an excellent model system for this purpose. Ammonoids have a well-defined geometry that can be parameterized using three dimensionless features of their logarithmic-spiral-shaped shells. Their evolutionary history includes repeated mass extinctions. We find that ammonoids fill out a pyramid in morphospace, suggesting five specific tasks - one for each vertex of the pyramid. After mass extinctions, surviving species evolve to refill essentially the same pyramid, suggesting that the tasks are unchanging. We infer putative tasks for each archetype, related to economy of shell material, rapid shell growth, hydrodynamics and compactness. These results support Pareto optimality theory as an approach to study evolutionary tradeoffs, and demonstrate how this approach can be used to infer the putative tasks that may shape the natural selection of phenotypes.

Optical properties of core-shell and multi-shell nanorods

Science.gov (United States)

Mokkath, Junais Habeeb; Shehata, Nader

2018-05-01

We report a first-principles time dependent density functional theory study of the optical response modulations in bimetallic core-shell (Na@Al and Al@Na) and multi-shell (Al@Na@Al@Na and Na@Al@Na@Al: concentric shells of Al and Na alternate) nanorods. All of the core-shell and multi-shell configurations display highly enhanced absorption intensity with respect to the pure Al and Na nanorods, showing sensitivity to both composition and chemical ordering. Remarkably large spectral intensity enhancements were found in a couple of core-shell configurations, indicative that optical response averaging based on the individual components can not be considered as true as always in the case of bimetallic core-shell nanorods. We believe that our theoretical results would be useful in promising applications depending on Aluminum-based plasmonic materials such as solar cells and sensors.

Economic design in a long-distance migrating molluscivore: how fast-fuelling red knots in Bohai Bay, China, get away with small gizzards.

Science.gov (United States)

Yang, Hong-Yan; Chen, Bing; Ma, Zhi-Jun; Hua, Ning; van Gils, Jan A; Zhang, Zheng-Wang; Piersma, Theunis

2013-10-01

We carried out an observational and experimental study to decipher how resource characteristics, in interaction with the predator's phenotype, constrain a fitness-determining performance measure, i.e. refuelling in a migrant bird. Two subspecies of red knot (Calidris canutus rogersi and C. c. piersmai) use northern Bohai Bay, Yellow Sea, China, for the final prebreeding stopover, during their 10,000-15,000 km long migrations between wintering and breeding areas. Here, they feed on small bivalves, especially 2-7 mm long Potamocorbula laevis. With an average stay of 29 days, and the need to store 80 g of fat for the onward flights to high-Arctic breeding grounds, red knots need to refuel fast. Using existing knowledge, we expected them to achieve this on the basis of (1) prey with high flesh to shell mass ratios, (2) large gizzards to crush the ingested molluscs, or (3) a combination of the two. Rejecting all three predictions, we found that red knots staging in Bohai Bay had the smallest gizzards on record (4.9 ± 0.8 g, mean ± s.e.m., N = 27), and also found that prey quality of P. laevis is much lower than predicted for the measured gizzard size (i.e. 1.3 rather than the predicted 4.5 kJ g(-1) dry shell mass, DM(shell)). The estimated handling time of P. laevis (0.2 s) is much shorter than the observed time between two prey ingestions (0.7 s), indicating that prey handling time is no constraint. Based on field observations of dropping rates and on indoor digestion trails, the shell processing rate was estimated at 3.9 mg DM(shell) s(-1), i.e. three times higher the rate previously predicted for red knots eating as fast as they can with the measured gizzard size. This is explained by the small and easily crushed P. laevis enabling high processing rates. As P. laevis also occurred in high densities, the metabolizable energy intake rate of red knots with small gizzards at 5 J s(-1) was as high as at northward staging sites elsewhere in the world. Currently

The use of waste mussel shells for the adsorption of dyes and heavy metals

Science.gov (United States)

Papadimitriou, Chrysi A.; Krey, Grigorios; Stamatis, Nikolaos; Kallaniotis, Argyris

2016-04-01

Mussel culture is very important sector of the Greek agricultural economy. The majority of mussel culture activities take place in the area of Central Macedonia, Greece, 60% of total mussel production in Greece producing almost 12 tons of waste mussels shells on a daily basis. Currently there is no legislation concerning the disposal of mussel shells. In the present study the waste shells were used for the removal of dyes and heavy metals from aqueous solutions while powdered mussel shells were added in activated sludge processes for the removal of hexavalent chromium. Mussel shells were cleaned, dried and then crushed in order to form a powder. Powdered mussels shells were used in standard adsorption experiments for the removal of methylene blue and methyl red as well as for the removal of Cr (VI), Cd and Cu. Moreover the powdered mussel shells were added in laboratory scale activated sludge reactors treating synthetic wastewater with hexavalent chromium, in order investigate the effects in activated sludge processes and their potential attribution to the removal of hexavalent chromium. Adsorption experiments indicated almost 100% color removal, while adsorption was directly proportional to the amount of powdered mussel shells added in each case. The isotherms calculated for the case of methylene blue indicated similar adsorption capacity and properties to those of the commercially available activated carbon SAE 2, Norit. High removal efficiencies were observed for the metals, especially in the case of chromium and copper. The addition of powdered mussel shells in the activated sludge processes enhanced the removal of chromium and phosphorus, while enabled the formation of heavier activated sludge flocs and thus enhanced the settling properties of the activated sludge.

The effects of staggered bandgap in the InP/CdSe and CdSe/InP core/shell quantum dots.

Science.gov (United States)

Kim, Sunghoon; Park, Jaehyun; Kim, Sungwoo; Jung, Won; Sung, Jaeyoung; Kim, Sang-Wook

2010-06-15

New type-II structures of CdSe/InP and InP/CdSe core-shell nanocrystals which have staggered bandgap alignment were fabricated. Using a simple model for the wave function for electrons and holes in InP/CdSe and CdSe/InP core/shell nanocrystals showed the wave function of the electron and hole spread into the shell, respectively. The probability density of the InP/CdSe and CdSe/InP core/shell QDs also showed a similar tendency. As a result, the structure exhibits increased delocalization of electrons and holes, leading to a red-shift in absorption and emission. Quantum yield increased in the InP/CdSe, however decreased in the CdSe/InP. The reason may be due to the surface trap and high activation barrier for de-trapping in the InP shell. 2010 Elsevier Inc. All rights reserved.

Single-Shell Tank (SST) Interim Stabilization Project Plan

International Nuclear Information System (INIS)

VLADIMIROFF, D.T.; BOYLES, V.C.

2000-01-01

This project plan establishes the management framework for the conduct of the CHG Single-Shell Tank Interim Stabilization completion program. Specifically, this plan defines the mission needs and requirements; technical objectives and approach; organization structure, roles, responsibilities, and interfaces; and operational methods. This plan serves as the project executional baseline

Larval vision contributes to gregarious settlement in barnacles: adult red fluorescence as a possible visual signal

KAUST Repository

Matsumura, K.; Qian, P.-Y.

2014-01-01

surfaces. Moreover, we found that shells of adult B. amphitrite emit red auto-fluorescence and the adult extracts with the fluorescence as a visual signal attracted cyprid larvae to settle around it. We propose that the perception of specific visual signals

Geometric method for stability of non-linear elastic thin shells

CERN Document Server

Ivanova, Jordanka

2002-01-01

PREFACE This book deals with the new developments and applications of the geometric method to the nonlinear stability problem for thin non-elastic shells. There are no other published books on this subject except the basic ones of A. V. Pogorelov (1966,1967,1986), where variational principles defined over isometric surfaces, are postulated, and applied mainly to static and dynamic problems of elastic isotropic thin shells. A. V. Pogorelov (Harkov, Ukraine) was the first to provide in his monographs the geometric construction of the deformed shell surface in a post-critical stage and deriving explicitely the asymptotic formulas for the upper and lower critical loads. In most cases, these formulas were presented in a closed analytical form, and confirmed by experimental data. The geometric method by Pogorelov is one of the most important analytical methods developed during the last century. Its power consists in its ability to provide a clear geometric picture of the postcritical form of a deformed shell surfac...

Mixing core material into the envelopes of red grants

International Nuclear Information System (INIS)

Deupree, R.G.

1986-01-01

A discussion is presented of calculations of four core helium flashes in red giant stars. The starting point for these calculations is a point source explosion on the polar axis of a two-dimensional finite difference grid. The amount of residue of the core helium flash mixed into and above the hydrogen shell is calculated at four temperatures for the elements carbon, oxygen, neon, magnesium, silicon, and sulfur. 7 refs., 1 tab

Pd@Au core-shell nanocrystals with concave cubic shapes: kinetically controlled synthesis and electrocatalytic properties.

Science.gov (United States)

Zhang, Ling; Niu, Wenxin; Zhao, Jianming; Zhu, Shuyun; Yuan, Yali; Hua, Lianzhe; Xu, Guobao

2013-01-01

A new type of concave cubic Pd@Au core-shell nanocrystals is synthesized through a kinetically controlled growth process. Pd nanocubes of 56 nm are used as the inner core, and CTAC and Br(-) are used as the capping agent and selective adsorbent, respectively. A suitable ratio of HAuCl4 and cubic Pd seeds and the presence of Br(-) anions are critical to the growth of the concave cubic Pd@Au core-shell nanocrystals. The fast deposition rate on the corners of the cubic Pd seeds promotes the overgrowth of the Au outer shell along the direction, leading to the formation of concave cubic nanostructures. The reduction process is monitored by the surface plasmon resonance spectra of the nanocrystals, and the extinction band became broader and red shifted as the nanocrystals became larger. The electrocatalytic properties of the concave cubic Pd@Au core-shell nanocrystals were investigated with the cathodic electrochemiluminescence reaction of luminol and H2O2. A possible electrocatalytic mechanism was proposed and analyzed.

Core-shell microspheres with porous nanostructured shells for liquid chromatography.

Science.gov (United States)

Ahmed, Adham; Skinley, Kevin; Herodotou, Stephanie; Zhang, Haifei

2018-01-01

The development of new stationary phases has been the key aspect for fast and efficient high-performance liquid chromatography separation with relatively low backpressure. Core-shell particles, with a solid core and porous shell, have been extensively investigated and commercially manufactured in the last decade. The excellent performance of core-shell particles columns has been recorded for a wide range of analytes, covering small and large molecules, neutral and ionic (acidic and basic), biomolecules and metabolites. In this review, we first introduce the advance and advantages of core-shell particles (or more widely known as superficially porous particles) against non-porous particles and fully porous particles. This is followed by the detailed description of various methods used to fabricate core-shell particles. We then discuss the applications of common silica core-shell particles (mostly commercially manufactured), spheres-on-sphere particles and core-shell particles with a non-silica shell. This review concludes with a summary and perspective on the development of stationary phase materials for high-performance liquid chromatography applications. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Hi shells, supershells, shell-like objects, and ''worms''

International Nuclear Information System (INIS)

Heiles, C.

1984-01-01

We present photographic representations of the combination of two Hi surveys, so as to eliminate the survey boundaries at Vertical BarbVertical Bar = 10 0 . We also present high-contrast photographs for particular velocities to exhibit weak Hi features. All of these photographs were used to prepare a new list of Hi shells, supershells, and shell-like objects. We discuss the structure of three shell-like objects that are associated with high-velocity gas, and with gas at all velocities that is associated with radio continuum loops I, II, and III. We use spatial filtering to find wiggly gas filaments: ''worms'': crawling away from the galactic plane in the inner Galaxy. The ''worms'' are probably parts of shells that are open at the top; such shells should be good sources of hot gas for the galactic halo

Facile consecutive solvothermal growth of highly fluorescent InP/ZnS core/shell quantum dots using a safer phosphorus source.

Science.gov (United States)

Byun, Ho-June; Song, Woo-Seuk; Yang, Heesun

2011-06-10

The work presents a facile, stepwise synthetic approach for the production of highly fluorescent InP/ZnS core/shell quantum dots (QDs) by using a safer phosphorus (P) precursor. First, InP quantum dots (QDs) were solvothermally prepared at 180 °C for 24 h by using a P source of P(N(CH(3))(2))(3). The as-grown InP QDs were consecutively placed in another solvothermal condition for ZnS shell overcoating. In contrast to the almost non-fluorescent InP QDs, due to their highly defective surface states, the ZnS-coated InP QDs were highly fluorescent as a result of effective surface passivation. After the shell growth, the resulting InP/ZnS core/shell QDs were subjected to a size-sorting processing, by which red- to green-emitting QDs with quantum yields (QYs) of 24-60% were produced. Solvothermal shell growth parameters such as the reaction time and Zn/In solution concentration ratio were varied and optimized toward the highest QYs of core/shell QDs.

Facile consecutive solvothermal growth of highly fluorescent InP/ZnS core/shell quantum dots using a safer phosphorus source

International Nuclear Information System (INIS)

Byun, Ho-June; Song, Woo-Seuk; Yang, Heesun

2011-01-01

The work presents a facile, stepwise synthetic approach for the production of highly fluorescent InP/ZnS core/shell quantum dots (QDs) by using a safer phosphorus (P) precursor. First, InP quantum dots (QDs) were solvothermally prepared at 180 deg. C for 24 h by using a P source of P(N(CH 3 ) 2 ) 3 . The as-grown InP QDs were consecutively placed in another solvothermal condition for ZnS shell overcoating. In contrast to the almost non-fluorescent InP QDs, due to their highly defective surface states, the ZnS-coated InP QDs were highly fluorescent as a result of effective surface passivation. After the shell growth, the resulting InP/ZnS core/shell QDs were subjected to a size-sorting processing, by which red- to green-emitting QDs with quantum yields (QYs) of 24-60% were produced. Solvothermal shell growth parameters such as the reaction time and Zn/In solution concentration ratio were varied and optimized toward the highest QYs of core/shell QDs.

Facile consecutive solvothermal growth of highly fluorescent InP/ZnS core/shell quantum dots using a safer phosphorus source

Science.gov (United States)

Byun, Ho-June; Song, Woo-Seuk; Yang, Heesun

2011-06-01

The work presents a facile, stepwise synthetic approach for the production of highly fluorescent InP/ZnS core/shell quantum dots (QDs) by using a safer phosphorus (P) precursor. First, InP quantum dots (QDs) were solvothermally prepared at 180 °C for 24 h by using a P source of P(N(CH3)2)3. The as-grown InP QDs were consecutively placed in another solvothermal condition for ZnS shell overcoating. In contrast to the almost non-fluorescent InP QDs, due to their highly defective surface states, the ZnS-coated InP QDs were highly fluorescent as a result of effective surface passivation. After the shell growth, the resulting InP/ZnS core/shell QDs were subjected to a size-sorting processing, by which red- to green-emitting QDs with quantum yields (QYs) of 24-60% were produced. Solvothermal shell growth parameters such as the reaction time and Zn/In solution concentration ratio were varied and optimized toward the highest QYs of core/shell QDs.

Facile consecutive solvothermal growth of highly fluorescent InP/ZnS core/shell quantum dots using a safer phosphorus source

Energy Technology Data Exchange (ETDEWEB)

Byun, Ho-June; Song, Woo-Seuk; Yang, Heesun, E-mail: hyang@hongik.ac.kr [Department of Materials Science and Engineering, Hongik University, Seoul 121-791 (Korea, Republic of)

2011-06-10

The work presents a facile, stepwise synthetic approach for the production of highly fluorescent InP/ZnS core/shell quantum dots (QDs) by using a safer phosphorus (P) precursor. First, InP quantum dots (QDs) were solvothermally prepared at 180 deg. C for 24 h by using a P source of P(N(CH{sub 3}){sub 2}){sub 3}. The as-grown InP QDs were consecutively placed in another solvothermal condition for ZnS shell overcoating. In contrast to the almost non-fluorescent InP QDs, due to their highly defective surface states, the ZnS-coated InP QDs were highly fluorescent as a result of effective surface passivation. After the shell growth, the resulting InP/ZnS core/shell QDs were subjected to a size-sorting processing, by which red- to green-emitting QDs with quantum yields (QYs) of 24-60% were produced. Solvothermal shell growth parameters such as the reaction time and Zn/In solution concentration ratio were varied and optimized toward the highest QYs of core/shell QDs.

Identifying the most influential spreaders in complex networks by an Extended Local K-Shell Sum

Science.gov (United States)

Yang, Fan; Zhang, Ruisheng; Yang, Zhao; Hu, Rongjing; Li, Mengtian; Yuan, Yongna; Li, Keqin

Identifying influential spreaders is crucial for developing strategies to control the spreading process on complex networks. Following the well-known K-Shell (KS) decomposition, several improved measures are proposed. However, these measures cannot identify the most influential spreaders accurately. In this paper, we define a Local K-Shell Sum (LKSS) by calculating the sum of the K-Shell indices of the neighbors within 2-hops of a given node. Based on the LKSS, we propose an Extended Local K-Shell Sum (ELKSS) centrality to rank spreaders. The ELKSS is defined as the sum of the LKSS of the nearest neighbors of a given node. By assuming that the spreading process on networks follows the Susceptible-Infectious-Recovered (SIR) model, we perform extensive simulations on a series of real networks to compare the performance between the ELKSS centrality and other six measures. The results show that the ELKSS centrality has a better performance than the six measures to distinguish the spreading ability of nodes and to identify the most influential spreaders accurately.

Removal of Congo red dye from aqueous solutions by a low-cost adsorbent: activated carbon prepared from Aloe vera leaves shell

Directory of Open Access Journals (Sweden)

Yusef Omidi Khaniabadi

2017-03-01

Full Text Available Background: Synthetic dyes have several harmful effects on human health as well as aquatic life. In this study, activated carbon (AV-AC, based on Aloe vera leaf shells, was used as a novel agricultural adsorbent, one that is low-cost and available for the removal of Congo red (CR as a carcinogenic dye from aqueous solutions. Methods: In the batch system, the influence of different parameters like contact time, pH, adsorbent dosage, and initial CR concentration were examined on the dye removal from liquid medium. The experimental data were fitted by pseudo-first-order and pseudo-second-order kinetics, and also Langmuir and Freundlich isotherms models. Results: The optimum contact time and pH for the uptake of CR were obtained at 20 minutes and acidic pH of 2. The maximum uptake capacity of CR dye by AV-AC was 1850 mg/g. The results showed that the experimental data were well-fitted by the pseudo-second-order kinetic model (R2 > 0.99 and Freundlich isotherm model (R2 > 0.99. Conclusion: According to the results of our study, the AV-AC is a low-cost, non-toxic, and effective adsorbent for the uptake of CR dye from aqueous media.

Removal of Congo Red by magnetic mesoporous titanium dioxide-graphene oxide core-shell microspheres for water purification.

Science.gov (United States)

Li, Leilei; Li, Xiangjun; Duan, Huimin; Wang, Xiaojiao; Luo, Chuannan

2014-06-14

Magnetic mesoporous titanium dioxide-graphene oxide (Fe3O4@mTiO2@GO) with a large surface area and a good magnetic responsiveness was synthesized by immobilizing a mesoporous titanium dioxide (mTiO2) shell on the surface of magnetic Fe3O4 nanoparticles prior to binding with graphene oxide (GO). It showed a tunable pore structure and surface properties, and was mechanically strong. The characteristic results of a Fourier transform infrared spectrometer (FTIR), a scanning electron microscope (SEM), a vibrating sample magnetometer (VSM) and X-ray diffraction (XRD) indicated that Fe3O4@mTiO2@GO has been prepared. Fe3O4@mTiO2@GO was used as an adsorbent for the removal of Congo Red (CR) from simulated wastewater with a fast solid-liquid separation in the presence of an external magnetic field. Batch adsorption experiments were performed to evaluate the adsorption conditions and reusability. The results showed that the maximum adsorption capacity was 89.95 mg g(-1), which is much higher than the previously reported values of other absorbent materials. Moreover, the Fe3O4@mTiO2@GO could be repeatedly used via simple treatment without any obvious structure and performance degradation. The adsorption kinetic data were best described by a pseudo-second-order model and the equilibrium adsorptions were well-described by the Freundlich isotherm model. The Fe3O4@mTiO2@GO may be suitable materials for use in CR pollution cleanup if synthesized on a large scale and at a low price in the near future.

An experimental determination of the drag coefficient of a Mens 8+ racing shell.

Science.gov (United States)

Buckmann, James G; Harris, Samuel D

2014-01-01

This study centered around an experimental analysis of a Mens Lightweight Eight racing shell and, specifically, determining an approximation for the drag coefficient. A testing procedure was employed that used a Global Positioning System (GPS) unit in order to determine the acceleration and drag force on the shell, and through calculations yield a drag coefficient. The testing was run over several days in numerous conditions, and a 95% confidence interval was established to capture the results. The results obtained, over these varying trials, maintained a successful level of consistency. The significance of this study transcends the determination an approximation for the drag coefficient of the racing shell; it defined a successful means of quantifying performance of the shell itself. The testing procedures outlined in the study represent a uniform means of evaluating the factors that influence drag on the shell, and thus influence speed.

Study of dinosaur's egg shell by EPR method; Issledovaniya metodom EhPR skorlupy yaits dinozavrov

Energy Technology Data Exchange (ETDEWEB)

Tleuberdina, R A; Nasirov, R N

1998-07-01

Two varieties of calcium carbonate are defined on base of ESR spectra radiation-inducted signals containing in mollusc shell and dinosaur and ostrich egg shell; their spectral characters are studied by infrared-spectroscopy methods and X-ray analysis. Possibility of correlation between ESR signals intensity of CO{sub 2}-radical of investigated object and geological age is determined. (author)

Tuning of Ag doped core−shell ZnO NWs/Cu2O grown by electrochemical deposition

International Nuclear Information System (INIS)

Makhlouf, Houssin; Messaoudi, Olfa; Souissi, Ahmed; Ben Assaker, Ibtissem; Oueslati, Mihrez; Bechelany, Mikhael; Chtourou, Radhouane

2015-01-01

ZnO nanowires (NWs)/Cu 2 O–Ag core–shell nanostructures (NSs) have been synthesized by electrochemical deposition method on ITO-coated glass substrates in order to improve the efficiency of the type-II transition of core–shell ZnO NWs/Cu 2 O–Ag NSs. The morphologies of the obtained NSs were studied by scanning electron microscopy confirming the presence of core–shell NSs. The crystalline proprieties were analyzed by x-ray diffraction and micro-Raman measurement: wurtzite ZnO and cuprit Cu 2 O phase were founded. The presence of Ag content in core–shell NS was detected by EDX. Optical measurement reveals an additional contribution δE at about 1.72 eV attributed to the type-II interfacial transition between the valance band of cuprit−Cu 2 O and the conduction band of W−ZnO. The effect of the Ag doping into the type-II transition was investigated. A red shift of the type-II transition was detected according to the Ag concentration. These materials could have potential applications in photocatalytic and photovoltaic fields. (paper)

Modification of Ag shell on upconversion populating paths of NaYF4:Yb3+,Er3+@Ag nanocomposites

International Nuclear Information System (INIS)

Sun, Jiao; Liu, Haipeng; Wu, Di; Dong, Biao; Sun, Liankun

2013-01-01

NaYF 4 :Yb 3+ ,Er 3+ @Ag core–shell nanocomposites were prepared. Due to the outer shell of Ag, some modifications were found on the upconversion (UC) processes of NaYF 4 :Yb 3+ ,Er 3+ core nanoparticles (NPs) caused by the co-interaction of surface effect, surface plasma absorption effect and local thermal effect under infrared radiation. Upon 980 nm excitation, the relative UC intensity of the green ( 2 H 11/2 , 4 S 3/2 – 4 I 15/2 ) to red ( 4 F 9/2 – 4 I 15/2 ) and the slope of power-dependence increased intensively, and three-photon population process for the green level appeared. -- Highlights: ► NaYF 4 :Yb 3+ ,Er 3+ @Ag core/shell nanocomposites were fabricated. ► The coating of Ag outer shell leads to the increase of the green UCL. ► Three-photon population process for the green level appeared after Ag coating.

Electrowetting-on-dielectrics for manipulation of oil drops and gas bubbles in aqueous-shell compound drops.

Science.gov (United States)

Li, Jiang; Wang, Yixuan; Chen, Haosheng; Wan, Jiandi

2014-11-21

We present the manipulation of oil, organic and gaseous chemicals by electrowetting-on-dielectric (EWOD) technology using aqueous-shell compound drops. We demonstrate that the transport and coalescence of viscous oil drops, the reaction of bromine with styrene in benzene solution, and the reaction of red blood cells with carbon monoxide bubbles can be accomplished using this method.

Free vibration analysis of delaminated composite shells using different shell theories

International Nuclear Information System (INIS)

Nanda, Namita; Sahu, S.K.

2012-01-01

Free vibration response of laminated composite shells with delamination is presented using the finite element method based on first order shear deformation theory. The shell theory used is the extension of dynamic, shear deformable theory according to the Sanders' first approximation for doubly curved shells, which can be reduced to Love's and Donnell's theories by means of tracers. An eight-noded C 0 continuity, isoparametric quadrilateral element with five degrees of freedom per node is used in the formulation. For modeling the delamination, multipoint constraint algorithm is incorporated in the finite element code. The natural frequencies of the delaminated cylindrical (CYL), spherical (SPH) and hyperbolic paraboloid (HYP) shells are determined by using the above mentioned shell theories, namely Sanders', Love's, and Donnell's. The validity of the present approach is established by comparing the authors' results with those available in the literature. Additional studies on free vibration response of CYL, SPH and HYP shells are conducted to assess the effects of delamination size and number of layers considering all three shell theories. It is shown that shell theories according to Sanders and Love always predict practically identical frequencies. Donnell's theory gives reliable results only for shallow shells. Moreover, the natural frequency is found to be very sensitive to delamination size and number of layers in the shell.

Buckling strength of spherical shells under combined loads

International Nuclear Information System (INIS)

Nagashima, H.; Kokubo, K.; Takayanagi, M.; Hayasaka, Y.; Kume, T.; Nagata, T.

1995-01-01

Many studies on buckling of cylindrical shells have been conducted, and many buckling evaluation equations have been proposed for actual plant designs; however, buckling of spherical shells under combined horizontal and vertical loads cannot be evaluated due to insufficient data. There is a particular lack of buckling data for spherical shells under lateral loads. To establish a method for estimating the buckling strength of spherical shells, we investigate the interactions between horizontal and vertical (compressive tensile) loads by conducting buckling tests. Applying several combinations of these loads in tests and using computer linear analysis, we obtain interaction curves. This study reports on the buckling tests conducted using spherical shell 1120 mm in dia., 0.7 mm thick and 696 mm high, which are shaped individually by press-forming and finally joined together by four meridional welds, using a specially made jig. Initial imperfections before testing and local deformations after each loading increment during testing are measured with special measuring equipment, and the interaction curve of horizontal and vertical loads and effect of imperfection on the buckling strength of spherical shells are obtained. Nonlinear FEM programs are developed using an 8-node isoparametric shell element and a four-node quadrilateral element of C 0 type with reduced integration based upon a Mindlin-Reissner theory which includes transverse shear. Actual initial imperfections are generally in irregular patterns. Thus, there may be several definitions of the equivalent magnitudes of initial imperfections related to buckling loads. Equivalent magnitudes have no practical meaning unless they can be obtained easily not only for small structures such as test shells but also for large actual structures. In the present study, we define the equivalent magnitude of initial imperfections as the maximum local ruggedness measured radially from a circular temperature having a radius equal

On the shell-model-connection of the cluster model

International Nuclear Information System (INIS)

Cseh, J.

2000-01-01

Complete text of publication follows. The interrelation of basic nuclear structure models is a longstanding problem. The connection between the spherical shell model and the quadrupole collective model has been studied extensively, and symmetry considerations proved to be especially useful in this respect. A collective band was interpreted in the shell model language long ago [1] as a set of states (of the valence nucleons) with a specific SU(3) symmetry. Furthermore, the energies of these rotational states are obtained to a good approximation as eigenvalues of an SU(3) dynamically symmetric shell model Hamiltonian. On the other hand the relation of the shell model and cluster model is less well explored. The connection of the harmonic oscillator (i.e. SU(3)) bases of the two approaches is known [2] but it was established only for the unrealistic harmonic oscillator interactions. Here we investigate the question: Can an SU(3) dynamically symmetric interaction provide a similar connection between the spherical shell model and the cluster model, like the one between the shell and collective models? In other words: whether or not the energy of the states of the cluster bands, defined by a specific SU(3) symmetries, can be obtained from a shell model Hamiltonian (with SU(3) dynamical symmetry). We carried out calculations within the framework of the semimicroscopic algebraic cluster model [3,4] in order to find an answer to this question, which seems to be affirmative. In particular, the energies obtained from such a Hamiltonian for several bands of the ( 12 C, 14 C, 16 O, 20 Ne, 40 Ca) + α systems turn out to be in good agreement with the experimental values. The present results show that the simple and transparent SU(3) connection between the spherical shell model and the cluster model is valid not only for the harmonic oscillator interactions, but for much more general (SU(3) dynamically symmetric) Hamiltonians as well, which result in realistic energy spectra. Via

One-pot synthesis of Pd-Pt@Pd core-shell nanocrystals with enhanced electrocatalytic activity for formic acid oxidation

KAUST Repository

Yuan, Qiang

2014-01-01

Well-defined Pd-Pt@Pd core-shell nanocrystals with a Pd-Pt alloy core and a conformal Pd shell of ~2-3 nm were directly synthesized through a one-pot, aqueous solution approach without any preformed Pd or Pt seeds. These Pd-Pt@Pd core-shell nanocrystals show an enhanced electrocatalytic activity for formic acid oxidation compared with commercial Pd black. This journal is © 2014 The Royal Society of Chemistry.

One-pot synthesis of Pd-Pt@Pd core-shell nanocrystals with enhanced electrocatalytic activity for formic acid oxidation

KAUST Repository

Yuan, Qiang; Huang, Dabing; Wang, Honghui; Zhou, Zhiyou; Wang, Qingxiao

2014-01-01

Well-defined Pd-Pt@Pd core-shell nanocrystals with a Pd-Pt alloy core and a conformal Pd shell of ~2-3 nm were directly synthesized through a one-pot, aqueous solution approach without any preformed Pd or Pt seeds. These Pd-Pt@Pd core

Plasma-activated core-shell gold nanoparticle films with enhanced catalytic properties

Energy Technology Data Exchange (ETDEWEB)

Llorca, Jordi, E-mail: jordi.llorca@upc.edu; Casanovas, Albert; Dominguez, Montserrat; Casanova, Ignasi [Universitat Politecnica de Catalunya, Institut de Tecniques Energetiques (Spain); Angurell, Inmaculada; Seco, Miquel; Rossell, Oriol [Universitat de Barcelona, Departament de Quimica Inorganica (Spain)

2008-03-15

Catalytically active gold nanoparticle films have been prepared from core-shell nanoparticles by plasma-activation and characterized by high-resolution transmission electron microscopy, atomic force microscopy, and X-ray photoelectron spectroscopy. Methane can be selectively oxidized into formic acid with an O{sub 2}-H{sub 2} mixture in a catalytic wall reactor functionalized with plasma-activated gold nanoparticle films containing well-defined Au particles of about 3.5 nm in diameter. No catalytic activity was recorded over gold nanoparticle films prepared by thermal decomposition of core-shell nanoparticles due to particle agglomeration.

Plasma-activated core-shell gold nanoparticle films with enhanced catalytic properties

International Nuclear Information System (INIS)

Llorca, Jordi; Casanovas, Albert; Dominguez, Montserrat; Casanova, Ignasi; Angurell, Inmaculada; Seco, Miquel; Rossell, Oriol

2008-01-01

Catalytically active gold nanoparticle films have been prepared from core-shell nanoparticles by plasma-activation and characterized by high-resolution transmission electron microscopy, atomic force microscopy, and X-ray photoelectron spectroscopy. Methane can be selectively oxidized into formic acid with an O 2 -H 2 mixture in a catalytic wall reactor functionalized with plasma-activated gold nanoparticle films containing well-defined Au particles of about 3.5 nm in diameter. No catalytic activity was recorded over gold nanoparticle films prepared by thermal decomposition of core-shell nanoparticles due to particle agglomeration

Composted oyster shell as lime fertilizer is more effective than fresh oyster shell.

Science.gov (United States)

Lee, Young Han; Islam, Shah Md Asraful; Hong, Sun Joo; Cho, Kye Man; Math, Renukaradhya K; Heo, Jae Young; Kim, Hoon; Yun, Han Dae

2010-01-01

Physio-chemical changes in oyster shell were examined, and fresh and composted oyster shell meals were compared as lime fertilizers in soybean cultivation. Structural changes in oyster shell were observed by AFM and FE-SEM. We found that grains of the oyster shell surface became smoother and smaller over time. FT-IR analysis indicated the degradation of a chitin-like compound of oyster shell. In chemical analysis, pH (12.3+/-0.24), electrical conductivity (4.1+/-0.24 dS m(-1)), and alkaline powder (53.3+/-1.12%) were highest in commercial lime. Besides, pH was higher in composted oyster shell meal (9.9+/-0.53) than in fresh oyster shell meal (8.4+/-0.32). The highest organic matter (1.1+/-0.08%), NaCl (0.54+/-0.03%), and moisture (15.1+/-1.95%) contents were found in fresh oyster shell meal. A significant higher yield of soybean (1.33 t ha(-1)) was obtained by applying composted oyster shell meal (a 21% higher yield than with fresh oyster shell meal). Thus composting of oyster shell increases the utility of oyster shell as a liming material for crop cultivation.

The effect of oxide shell thickness on the structural, electronic, and optical properties of Si-SiO{sub 2} core-shell nano-crystals: A (time dependent)density functional theory study

Energy Technology Data Exchange (ETDEWEB)

Nazemi, Sanaz, E-mail: s.nazemi@ut.ac.ir, E-mail: pourfath@ut.ac.ir; Soleimani, Ebrahim Asl [School of Electrical and Computer Engineering, University of Tehran, Tehran 14395-515 (Iran, Islamic Republic of); Pourfath, Mahdi, E-mail: s.nazemi@ut.ac.ir, E-mail: pourfath@ut.ac.ir [School of Electrical and Computer Engineering, University of Tehran, Tehran 14395-515 (Iran, Islamic Republic of); Institute for Microelectronics, Technische Universität Wien, Wien A-1040 (Austria); Kosina, Hans [Institute for Microelectronics, Technische Universität Wien, Wien A-1040 (Austria)

2016-04-14

Due to their tunable properties, silicon nano-crystals (NC) are currently being investigated. Quantum confinement can generally be employed for size-dependent band-gap tuning at dimensions smaller than the Bohr radius (∼5 nm for silicon). At the nano-meter scale, however, increased surface-to-volume ratio makes the surface effects dominant. Specifically, in Si-SiO{sub 2} core-shell semiconductor NCs the interfacial transition layer causes peculiar electronic and optical properties, because of the co-existence of intermediate oxidation states of silicon (Si{sup n+}, n = 0–4). Due to the presence of the many factors involved, a comprehensive understanding of the optical properties of these NCs has not yet been achieved. In this work, Si-SiO{sub 2} NCs with a diameter of 1.1 nm and covered by amorphous oxide shells with thicknesses between 2.5 and 4.75 Å are comprehensively studied, employing density functional theory calculations. It is shown that with increased oxide shell thickness, the low-energy part of the optical transition spectrum of the NC is red shifted and attenuated. Moreover, the absorption coefficient is increased in the high-energy part of the spectrum which corresponds to SiO{sub 2} transitions. Structural examinations indicate a larger compressive stress on the central silicon cluster with a thicker oxide shell. Examination of the local density of states reveals the migration of frontier molecular orbitals from the oxide shell into the silicon core with the increase of silica shell thickness. The optical and electrical properties are explained through the analysis of the density of states and the spatial distribution of silicon sub-oxide species.

Variation in Orthologous Shell-Forming Proteins Contribute to Molluscan Shell Diversity.

Science.gov (United States)

Jackson, Daniel J; Reim, Laurin; Randow, Clemens; Cerveau, Nicolas; Degnan, Bernard M; Fleck, Claudia

2017-11-01

Despite the evolutionary success and ancient heritage of the molluscan shell, little is known about the molecular details of its formation, evolutionary origins, or the interactions between the material properties of the shell and its organic constituents. In contrast to this dearth of information, a growing collection of molluscan shell-forming proteomes and transcriptomes suggest they are comprised of both deeply conserved, and lineage specific elements. Analyses of these sequence data sets have suggested that mechanisms such as exon shuffling, gene co-option, and gene family expansion facilitated the rapid evolution of shell-forming proteomes and supported the diversification of this phylum specific structure. In order to further investigate and test these ideas we have examined the molecular features and spatial expression patterns of two shell-forming genes (Lustrin and ML1A2) and coupled these observations with materials properties measurements of shells from a group of closely related gastropods (abalone). We find that the prominent "GS" domain of Lustrin, a domain believed to confer elastomeric properties to the shell, varies significantly in length between the species we investigated. Furthermore, the spatial expression patterns of Lustrin and ML1A2 also vary significantly between species, suggesting that both protein architecture, and the regulation of spatial gene expression patterns, are important drivers of molluscan shell evolution. Variation in these molecular features might relate to certain materials properties of the shells of these species. These insights reveal an important and underappreciated source of variation within shell-forming proteomes that must contribute to the diversity of molluscan shell phenotypes. © The Author 2017. Published by Oxford University Press on behalf of the Society for Molecular Biology and Evolution.

Off-shell CHY amplitudes

Energy Technology Data Exchange (ETDEWEB)

Lam, C.S., E-mail: Lam@physics.mcgill.ca [Department of Physics, McGill University, Montreal, Q.C., H3A 2T8 (Canada); Department of Physics and Astronomy, University of British Columbia, Vancouver, BC, V6T 1Z1 (Canada); Yao, York-Peng, E-mail: yyao@umich.edu [Department of Physics, The University of Michigan Ann Arbor, MI 48109 (United States)

2016-06-15

The Cachazo–He–Yuan (CHY) formula for on-shell scattering amplitudes is extended off-shell. The off-shell amplitudes (amputated Green's functions) are Möbius invariant, and have the same momentum poles as the on-shell amplitudes. The working principles which drive the modifications to the scattering equations are mainly Möbius covariance and energy momentum conservation in off-shell kinematics. The same technique is also used to obtain off-shell massive scalars. A simple off-shell extension of the CHY gauge formula which is Möbius invariant is proposed, but its true nature awaits further study.

Gravitational entropy of nonstationary black holes and spherical shells

International Nuclear Information System (INIS)

Hiscock, W.A.

1989-01-01

The problem of defining the gravitational entropy of a nonstationary black hole is considered in a simple model consisting of a spherical shell which collapses into a preexisting black hole. The second law of black-hole mechanics strongly suggests identifying one-quarter of the area of the event horizon as the gravitational entropy of the system. It is, however, impossible to accurately locate the position of the global event horizon using only local measurements. In order to maintain a local thermodynamics, it is suggested that the entropy of the black hole be identified with one-quarter the area of the apparent horizon. The difference between the event-horizon entropy (to the extent it can be determined) and the apparent-horizon entropy may then be interpreted as the gravitational entropy of the collapsing shell. The total (event-horizon) gravitational entropy evolves in a smooth (C 0 ) fashion, even in the presence of δ-functional shells of matter

Highly sensitive colorimetric detection of glucose in a serum based on DNA-embeded Au@Ag core–shell nanoparticles

International Nuclear Information System (INIS)

Kang, Fei; Xu, Kun; Hou, Xiangshu

2015-01-01

Glucose is a key energy substance in diverse biology and closely related to the life activities of the organism. To develop a simple and sensitive method for glucose detection is extremely urgent but still remains a key challenge. Herein, we report a colorimetric glucose sensor in a homogeneous system based on DNA-embedded core–shell Au@Ag nanoparticles. In this assay, a glucose substrate was first catalytically oxidized by glucose oxidase to produce H 2 O 2 which would further oxidize and gradually etch the outer silver shell of Au@Ag nanoparticles. Afterwards, the solution color changed from yellow to red and the surface plasmon resonance (SPR) band of Au@Ag nanoparticles declined and red-shifted from 430 to 516 nm. Compared with previous silver-based glucose colorimetric detection strategies, the distinctive SPR band change is superior to the color variation, which is critical to the high sensitivity of this assay. Benefiting from the outstanding optical property, robust stability and well-dispersion of the core–shell Au@AgNPs hybrid, this colorimetric assay obtained a detection limit of glucose as low as 10 nM, which is at least a 10-fold improvement over other AgNPs-based procedures. Moreover, this optical biosensor was successfully employed to the determination of glucose in fetal bovine serum. (paper)

Phases and phase transitions in the algebraic microscopic shell model

Directory of Open Access Journals (Sweden)

Georgieva A. I.

2016-01-01

Full Text Available We explore the dynamical symmetries of the shell model number conserving algebra, which define three types of pairing and quadrupole phases, with the aim to obtain the prevailing phase or phase transition for the real nuclear systems in a single shell. This is achieved by establishing a correspondence between each of the pairing bases with the Elliott’s SU(3 basis that describes collective rotation of nuclear systems. This allows for a complete classification of the basis states of different number of particles in all the limiting cases. The probability distribution of the SU(3 basis states within theirs corresponding pairing states is also obtained. The relative strengths of dynamically symmetric quadrupole-quadrupole interaction in respect to the isoscalar, isovector and total pairing interactions define a control parameter, which estimates the importance of each term of the Hamiltonian in the correct reproduction of the experimental data for the considered nuclei.

A Leonard-Sanders-Budiansky-Koiter-Type Nonlinear Shell Theory with a Hierarchy of Transverse-Shearing Deformations

Science.gov (United States)

Nemeth, Michael P.

2013-01-01

A detailed exposition on a refined nonlinear shell theory suitable for nonlinear buckling analyses of laminated-composite shell structures is presented. This shell theory includes the classical nonlinear shell theory attributed to Leonard, Sanders, Koiter, and Budiansky as an explicit proper subset. This approach is used in order to leverage the exisiting experience base and to make the theory attractive to industry. In addition, the formalism of general tensors is avoided in order to expose the details needed to fully understand and use the theory. The shell theory is based on "small" strains and "moderate" rotations, and no shell-thinness approximations are used. As a result, the strain-displacement relations are exact within the presumptions of "small" strains and "moderate" rotations. The effects of transverse-shearing deformations are included in the theory by using analyst-defined functions to describe the through-the-thickness distributions of transverse-shearing strains. Constitutive equations for laminated-composite shells are derived without using any shell-thinness approximations, and simplified forms and special cases are presented.

Red light emitting solid state hybrid quantum dot-near-UV GaN LED devices

International Nuclear Information System (INIS)

Song, Hongjoo; Lee, Seonghoon

2007-01-01

We produced core-shell (CdSe)ZnSe quantum dots by direct colloidal chemical synthesis and the surface-passivation method-an overcoating of the core CdSe with a larger-bandgap material ZnSe. The (CdSe)ZnSe quantum dots(QDs) play the role of a colour conversion centre. We call these quantum dots nanophosphors. We fabricated red light emitting hybrid devices of (CdSe)ZnSe QDs and a near-UV GaN LED by combining red light emitting (CdSe)ZnSe quantum dots (as a colour conversion centre) with a near-UV(NUV) GaN LED chip (as an excitation source). A few good red phosphors have been known for UV excitation wavelengths, and red phosphors for UV excitation have been sought for a long time. Here we tested the possibility of using (CdSe)ZnSe QDs as red nanophosphors for UV excitation. The fabricated red light emitting hybrid device of (CdSe)ZnSe and a NUV GaN LED chip showed a good luminance. We demonstrated that the (CdSe)ZnSe quantum dots were promising red nanophosphors for NUV excitation and that a red LED made of QDs and a NUV excitation source was a highly efficient hybrid device

Parameterized Finite Element Modeling and Buckling Analysis of Six Typical Composite Grid Cylindrical Shells

Science.gov (United States)

Lai, Changliang; Wang, Junbiao; Liu, Chuang

2014-10-01

Six typical composite grid cylindrical shells are constructed by superimposing three basic types of ribs. Then buckling behavior and structural efficiency of these shells are analyzed under axial compression, pure bending, torsion and transverse bending by finite element (FE) models. The FE models are created by a parametrical FE modeling approach that defines FE models with original natural twisted geometry and orients cross-sections of beam elements exactly. And the approach is parameterized and coded by Patran Command Language (PCL). The demonstrations of FE modeling indicate the program enables efficient generation of FE models and facilitates parametric studies and design of grid shells. Using the program, the effects of helical angles on the buckling behavior of six typical grid cylindrical shells are determined. The results of these studies indicate that the triangle grid and rotated triangle grid cylindrical shell are more efficient than others under axial compression and pure bending, whereas under torsion and transverse bending, the hexagon grid cylindrical shell is most efficient. Additionally, buckling mode shapes are compared and provide an understanding of composite grid cylindrical shells that is useful in preliminary design of such structures.

AFSC/RACE/SAP/Daly: Juvenile red and blue king crab prey preference experiment conducted in the Kodiak Lab in 2014

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — This dataset is part of a laboratory experiment, which evaluated how varying ratios of prey species (year-0 blue and red king crabs) and habitat type (shell and...

On the shell model connection of the cluster model

International Nuclear Information System (INIS)

Cseh, J.; Levai, G.; Kato, K.

2000-01-01

Complete text of publication follows. The interrelation of basic nuclear structure models is a longstanding problem. The connection between the spherical shell model and the quadrupole collective model has been studied extensively, and symmetry considerations proved to be especially useful in this respect. A collective band was interpreted in the shell model language long ago as a set of states (of the valence nucleons) with a specific SU(3) symmetry. Furthermore, the energies of these rotational states are obtained to a good approximation as eigenvalues of an SU(3) dynamically symmetric shell model Hamiltonian. On the other hand the relation of the shell model and cluster model is less well explored. The connection of the harmonic oscillator (i.e. SU(3)) bases of the two approaches is known, but it was established only for the unrealistic harmonic oscillator interactions. Here we investigate the question: Can an SU(3) dynamically symmetric interaction provide a similar connection between the spherical shell model and the cluster model, like the one between the shell and collective models? In other words: whether or not the energy of the states of the cluster bands, defined by a specific SU(3) symmetries, can be obtained from a shell model Hamiltonian (with SU(3) dynamical symmetry). We carried out calculations within the framework of the semimicroscopic algebraic cluster model, in which not only the cluster model space is obtained from the full shell model space by an SU(3) symmetry-dictated truncation, but SU(3) dynamically symmetric interactions are also applied. Actually, Hamiltonians of this kind proved to be successful in describing the gross features of cluster states in a wide energy range. The novel feature of the present work is that we apply exclusively shell model interactions. The energies obtained from such a Hamiltonian for several bands of the ( 12 C, 14 C, 16 O, 20 Ne, 40 Ca) + α systems turn out to be in good agreement with the experimental

Diet of Nesting Red-Cockaded Woodpecker at Three Locations

Energy Technology Data Exchange (ETDEWEB)

Hanula, J.L.; Lipcomb, D.; Franzreb, K.E.; Loeb, S.C.

1998-12-03

The authors studied diets of nestling red-cockaded woodpeckers for two years on three sites in South Carolina and Georgia. Cameras recorded 33 different types of prey. Wood roaches were the most common, amounting to 50% of the prey. In addition, blueberries and saw fly larvae were collected by birds. Snail shells were also collected. Morista's index of diet overlap ranged from 0.94 to 0.99 for breeding males and females. We conclude that nestling diets are similar across the region.

Dossier Shell Eco-Marathon; Dossier Shell Eco-Marathon

Energy Technology Data Exchange (ETDEWEB)

Matla, P.

2012-05-15

Three articles address subjects concerning the annual race with highly energy efficient cars: the Shell Eco-Marathon. [Dutch] In 3 artikelen wordt aandacht besteed aan de ontwerpen voor de jaarlijkse race met superzuinige auto's, de Shell Eco-Marathon.

Dominant thermogravimetric signatures of lignin in cashew shell as compared to cashew shell cake.

Science.gov (United States)

Gangil, Sandip

2014-03-01

Dominant thermogravimetric signatures related to lignin were observed in cashew shell as compared to these signatures in cashew shell cake. The phenomenon of weakening of lignin from cashew shell to cashew shell cake was explained on the basis of changes in the activation energies. The pertinent temperature regimes responsible for the release of different constituents of both the bio-materials were identified and compared. The activation energies of cashew shell and cashew shell cake were compared using Kissinger-Akahira-Sunose method. Thermogravimetric profiling of cashew shell and cashew shell cake indicated that these were different kinds of bio-materials. Copyright © 2013 Elsevier Ltd. All rights reserved.

ZnO@MnO2 Core-Shell Nanofiber Cathodes for High Performance Asymmetric Supercapacitors.

Science.gov (United States)

Radhamani, A V; Shareef, K M; Rao, M S Ramachandra

2016-11-09

Asymmetric supercapacitors (ASCs) with aqueous electrolyte medium have recently become the focus of increasing research. For high performance ASCs, selection of cathode materials play a crucial role, and core-shell nanostructures are found to be a good choice. We successfully synthesized, ZnO@MnO 2 core-shell nanofibers (NFs) by modification of high-aspect-ratio-electrospun ZnO NFs hydrothermally with MnO 2 nanoflakes. High conductivity of the ZnO NFs and the exceptionally high pseudocapacitive nature of MnO 2 nanoflakes coating delivered a specific capacitance of 907 Fg -1 at 0.6 Ag -1 for the core-shell NFs. A simple and cost-effective ASC construction was demonstrated with ZnO@MnO 2 NFs as a battery-type cathode material and a commercial-quality activated carbon as a capacitor-type anode material. The fabricated device functioned very well in a voltage window of 0-2.0 V, and a red-LED was illuminated using a single-celled fabricated ASC device. It was found to deliver a maximum energy density of 17 Whkg -1 and a power density of 6.5 kWkg -1 with capacitance retention of 94% and Coulombic efficiency of 100%. The novel architecture of the ZnO@MnO 2 core-shell nanofibrous material implies the importance of using simple design of fiber-based electrode material by mere changes of core and shell counterparts.

Shell-like structures

CERN Document Server

Altenbach, Holm

2011-01-01

In this volume, scientists and researchers from industry discuss the new trends in simulation and computing shell-like structures. The focus is put on the following problems: new theories (based on two-dimensional field equations but describing non-classical effects), new constitutive equations (for materials like sandwiches, foams, etc. and which can be combined with the two-dimensional shell equations), complex structures (folded, branching and/or self intersecting shell structures, etc.) and shell-like structures on different scales (for example: nano-tubes) or very thin structures (similar

An ochered fossil marine shell from the mousterian of fumane cave, Italy.

Directory of Open Access Journals (Sweden)

Marco Peresani

Full Text Available A scanty but varied ensemble of finds challenges the idea that Neandertal material culture was essentially static and did not include symbolic items. In this study we report on a fragmentary Miocene-Pliocene fossil marine shell, Aspamarginata, discovered in a Discoid Mousterian layer of the Fumane Cave, northern Italy, dated to at least 47.6-45.0 Cal ky BP. The shell was collected by Neandertals at a fossil exposure probably located more than 100 kms from the site. Microscopic analysis of the shell surface identifies clusters of striations on the inner lip. A dark red substance, trapped inside micropits produced by bioeroders, is interpreted as pigment that was homogeneously smeared on the outer shell surface. Dispersive X-ray and Raman analysis identify the pigment as pure hematite. Of the four hypotheses we considered to explain the presence of this object at the site, two (tool, pigment container are discarded because in contradiction with observations. Although the other two ("manuport", personal ornament are both possible, we favor the hypothesis that the object was modified and suspended by a 'thread' for visual display as a pendant. Together with contextual and chronometric data, our results support the hypothesis that deliberate transport and coloring of an exotic object, and perhaps its use as pendant, was a component of Neandertal symbolic culture, well before the earliest appearance of the anatomically modern humans in Europe.

Extensions to a nonlinear finite-element axisymmetric shell model based on Reissner's shell theory

International Nuclear Information System (INIS)

Cook, W.A.

1981-01-01

Extensions to shell analysis not usually associated with shell theory are described in this paper. These extensions involve thick shells, nonlinear materials, a linear normal stress approximation, and a changing shell thickness. A finite element shell-of-revolution model has been developed to analyze nuclear material shipping containers under severe impact conditions. To establish the limits for this shell model, the basic assumptions used in its development were studied; these are listed in this paper. Several extensions were evident from the study of these limits: a thick shell, a plastic hinge, and a linear normal stress

Comparison of protoporphyrin IX content and related gene expression in the tissues of chickens laying brown-shelled eggs.

Science.gov (United States)

Li, Guangqi; Chen, Sirui; Duan, Zhongyi; Qu, Lujiang; Xu, Guiyun; Yang, Ning

2013-12-01

Protoporphyrin IX (PpIX), an immediate precursor of heme, is the main pigment resulting in the brown coloration of eggshell. The brownness and uniformity of the eggshell are important marketing considerations. In this study, 9 chickens laying darker brown shelled eggs and 9 chickens laying lighter brown shelled eggs were selected from 464 individually caged layers in a Rhode Island Red pureline. The PpIX contents were measured with a Microplate Reader at the wavelength of 412 nm and were compared in different tissues of the 2 groups. Although no significant difference in serum, bile, and excreta was found between the 2 groups, PpIX content in the shell gland and eggshell of the darker group was higher than in those of the lighter group, suggesting that PpIX was synthesized in the shell gland. We further determined the expression levels of 8 genes encoding enzymes involved in the heme synthesis and transport in the liver and shell gland at 6 h postoviposition by quantitative PCR. The results showed that expression of aminolevulinic acid synthase-1 (ALAS1) was higher in the liver of hens laying darker brown shelled eggs, whereas in the shell gland the expression levels of ALAS1, coproporphyrinogen oxidase (CPOX), ATP-binding cassette family members ABCB7 and ABCG2, and receptor for feline leukemia virus, subgroup C (FLVCR) were significantly higher in the hens laying darker brown shelled eggs. Our results demonstrated that hens laying darker brown shelled eggs could deposit more PpIX onto the eggshell and the brownness of the eggshell was dependent on the total quantity of PpIX in the eggshell. More heme was synthesized in the liver and shell gland of hens laying darker brown shelled eggs than those of hens laying lighter brown shelled eggs. High expression level of ABCG2 might facilitate the accumulation of PpIX in the shell gland.

The off-shell nucleon-nucleon interaction in the singlet s-state

International Nuclear Information System (INIS)

Groot, H. de

1975-01-01

This thesis studies the off-shell behaviour of the neutron-proton interaction in the singlet state. To generate phase-shift-equivalent potentials a particular type of inversion problem is solved. It requires the potential to contain a non-local, separable part which is supposed to describe part of the short-range interaction. A special solution of the general inversion problem that produces potentials consisting of two separable terms is studied. Criteria to accept or reject particular inversion solutions are discussed. Neutron-proton potentials in the 1 S 0 partial wave which form part of the input for the general inversion procedure are defined. Different local potential tails are chosen, as well as varying short-range interactions, both local and non-local. The input phase shifts are discussed including three extrapolations of the phase shifts at high energy. The half-shell transition matrix for the potentials defined is studied. Some problems introduced by the additional electromagnetic interaction in the proton-proton system is investigated. (Auth.)

A Coulomb-Like Off-Shell T-Matrix with the Correct Coulomb Phase Shift

International Nuclear Information System (INIS)

Oryu, Shinsho; Watanabe, Takashi; Hiratsuka, Yasuhisa; Togawa, Yoshio

2017-01-01

We confirm the reliability of the well-known Coulomb renormalization method (CRM). It is found that the CRM is only available for a very-long-range screened Coulomb potential (SCP). However, such an SCP calculation in momentum space is considerably difficult because of the cancellation of significant digits. In contrast to the CRM, we propose a new method by using an on-shell equivalent SCP and the rest term. The two-potential theory with r-space is introduced, which defines fully the off-shell Coulomb amplitude. (author)

Preparation of core-shell structured CaCO3 microspheres as rapid and recyclable adsorbent for anionic dyes

Science.gov (United States)

Zhao, Mengen; Chen, Zhenhua; Lv, Xinyan; Zhou, Kang; Zhang, Jie; Tian, Xiaohan; Ren, Xiuli; Mei, Xifan

2017-09-01

Core-shell structured CaCO3 microspheres (MSs) were prepared by a facile, one-pot method at room temperature. The adsorbent dosage and adsorption time of the obtained CaCO3 MSs were investigated. The results suggest that these CaCO3 MSs can rapidly and efficiently remove 99-100% of anionic dyes within the first 2 min. The obtained CaCO3 MSs have a high Brunauer-Emmett-Teller surface area (211.77 m2 g-1). In addition, the maximum adsorption capacity of the obtained CaCO3 MSs towards Congo red was 99.6 mg g-1. We also found that the core-shell structured CaCO3 MSs have a high recycling capability for removing dyes from water. Our results demonstrate that the prepared core-shell structured CaCO3 MSs can be used as an ideal, rapid, efficient and recyclable adsorbent to remove dyes from aqueous solution.

A numerical investigation of γ-Al2O3-water nanofluids heat transfer and pressure drop in a shell and tube heat exchanger

Directory of Open Access Journals (Sweden)

P. Shahmohammadi

2016-01-01

Full Text Available The effect of γ-Al2O3 nanoparticles on heat transfer rate, baffle spacing and pressure drop in the shell side of small shell and tube heat exchangers was investigated numerically under turbulent regime. γ-Al2O3-water nanofluids and pure water were used in the shell side and the tube side of heat exchangers, respectively. Since the properties of γ-Al2O3-water nanofluids were variable, they were defined using the user define function. The results revealed that heat transfer and pressure drop were increased with mass flow rate as well as baffle numbers. Adding nanoparticles to the based fluid did not have a significant effect on pressure drop in the shell side. The best heat transfer performance of heat exchangers was for γ-Al2O3-water 1 vol.% and higher nanoparticles concentration was not suitable. The suitable baffle spacing was 43.4% of the shell diameter, showing a good agreement with Bell-Delaware method.

Selective colors reflection from stratified aragonite calcium carbonate plates of mollusk shells.

Science.gov (United States)

Lertvachirapaiboon, Chutiparn; Parnklang, Tewarak; Pienpinijtham, Prompong; Wongravee, Kanet; Thammacharoen, Chuchaat; Ekgasit, Sanong

2015-08-01

An interaction between the incident light and the structural architecture within the shell of Asian green mussel (Perna viridis) induces observable pearlescent colors. In this paper, we investigate the influence of the structural architecture on the expressed colors. After a removal of the organic binder, small flakes from crushed shells show vivid rainbow reflection under an optical microscope. An individual flake expresses vivid color under a bright-field illumination while become transparent under a dark-field illumination. The expressed colors of the aragonite flakes are directly associated with its structural architecture. The flakes with aragonite thickness of 256, 310, and 353 nm, respectively, appear blue, green, and red under an optical microscope. The spectral simulation corroborates the experimentally observed optical effects as the flakes with thicker aragonite layers selectively reflected color with longer wavelengths. Flakes with multiple aragonite thicknesses expressed multi-color as the upper aragonite layers allow reflected colors from the lower layers to be observed. Copyright © 2015 Elsevier Inc. All rights reserved.

General theory for thermal pulses of finite amplitude in nuclear shell-burnings

Energy Technology Data Exchange (ETDEWEB)

Sugimoto, D [Tokyo Univ. (Japan). Coll. of General Education; Fujimoto, M Y

1978-09-01

Theory for thermal pulses of nuclear shell-burning is advanced to include the case of finite amplitude. The aims are to predict the progress of thermal pulse quantitatively and to obtain the peak values of the temperature and nuclear energy generation rate without making detailed numerical computation of stellar structure. In order to attain them the physical processes involved in the progress of the pulse are clarified using the concepts of the flatness of the shell source, which destabilizes nuclear burning, and the effect of radiation pressure, which stabilizes it. It is shown that the progress of the pulse can be predicted quantitatively when the pressure and the gravitational potential of the burning shell are specified for the onset stage of the pulse. The pulse height is determined mainly by the initial pressure; the higher initial pressure results in the higher pulse. Mass dependence is also obtained by approximating the gravitational potential by that of white dwarfs. The initial pressure is the quantity which is determined in the course of evolution preceding the pulse. The theory is shown to give a satisfactory agreement with numerical computations for a wide variety of the preceding evolutions, i.e., both for the case of the core in red giant stars and of the accreting white dwarfs.

Mechanical properties of two-way grid shells optimized considering roundness and elastic stiffness

International Nuclear Information System (INIS)

Ogawa, Toshiyuki; Yuta, Nishikawa; Rie, Tateishi; Ohsaki, Makoto

2002-01-01

A single-layer two-way grid shell defined by Bezier surface is optimized by coordinates of the control points as design variables. The purpose of this paper is to find optimal shapes considering roundness and elastic stiffness, and to investigate their mechanical properties. The distance of the center of curvature from the specified point is used for formulating the objective function for generating a round shape. Consider next a problem of minimizing the compliance as mechanical performance measure. The compliance is defined by the external work against the static loads applied to the nodes. The mechanically optimal shape is different from the round shape. Therefore, the multi objective optimization problem is formulated for optimizing the two objectives, which are roundness and the elastic stiffness defined by using the compliance. The constraint method is used for obtaining Pareto optimal solutions between the two objectives. We optimize single-layer two-way grid shells with square and rectangle plans. Mechanical properties of the optimal shapes are investigated by compliance and the distributions of axial force and bending moment. The round shape is significantly dominated by the bending moment and its compliance is large. The bending moment of the mechanically optimal shape is not very large, and the latticed shell has large stiffness through axial deformation. A trade-off shape is round enough, and the influence of the bending moment is smaller than that of the optimal round shape and the elastic stiffness is moderately large

Optimization of wall thickness and lay-up for the shell-like composite structure loaded by non-uniform pressure field

Science.gov (United States)

Shevtsov, S.; Zhilyaev, I.; Oganesyan, P.; Axenov, V.

2017-01-01

The glass/carbon fiber composites are widely used in the design of various aircraft and rotorcraft components such as fairings and cowlings, which have predominantly a shell-like geometry and are made of quasi-isotropic laminates. The main requirements to such the composite parts are the specified mechanical stiffness to withstand the non-uniform air pressure at the different flight conditions and reduce a level of noise caused by the airflow-induced vibrations at the constrained weight of the part. The main objective of present study is the optimization of wall thickness and lay-up of composite shell-like cowling. The present approach assumes conversion of the CAD model of the cowling surface to finite element (FE) representation, then its wind tunnel testing simulation at the different orientation of airflow to find the most stressed mode of flight. Numerical solutions of the Reynolds averaged Navier-Stokes (RANS) equations supplemented by k-w turbulence model provide the spatial distributions of air pressure applied to the shell surface. At the formulation of optimization problem the global strain energy calculated within the optimized shell was assumed as the objective. A wall thickness of the shell had to change over its surface to minimize the objective at the constrained weight. We used a parameterization of the problem that assumes an initiation of auxiliary sphere with varied radius and coordinates of the center, which were the design variables. Curve that formed by the intersection of the shell with sphere defined boundary of area, which should be reinforced by local thickening the shell wall. To eliminate a local stress concentration this increment was defined as the smooth function defined on the shell surface. As a result of structural optimization we obtained the thickness of shell's wall distribution, which then was used to design the draping and lay-up of composite prepreg layers. The global strain energy in the optimized cowling was reduced in2

Synthesis and characterization of water-dispersed CdSe/CdS core-shell quantum dots prepared via Layer-by-layer Method capped with carboxylic-functionalized poly(vinyl alcohol)

Energy Technology Data Exchange (ETDEWEB)

Ramanery, Fabio Pereira; Mansur, Alexandra Ancelmo Piscitelli; Mansur, Herman Sander, E-mail: hmansur@demet.ufmg.br [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Dept. de Metalurgia e Engenharia dos Materiais. Centro de Nanociencia, Nanotecnologia e Inovacao

2014-08-15

The main goal of this work was to synthesize CdSe/CdS (core-shell) nanoparticles stabilized by polymer ligand using entirely aqueous colloidal chemistry at room temperature. First, the CdSe core was prepared using precursors and acid-functionalized poly(vinyl alcohol) as the capping ligand. Next, a CdS shell was grown onto the CdSe core via the layer-by-layer technique. The CdS shell was formed by two consecutive monolayers, as estimated by empirical mathematical functions. The nucleation and growth of CdSe quantum dots followed by CdS shell deposition were characterized by UV-vis spectroscopy, photoluminescence (PL) spectroscopy and transmission electron microscopy (TEM). The results indicated a systematic red-shift of the absorption and emission spectra after the deposition of CdS, indicating the shell growth onto the CdSe core. TEM coupled with electron diffraction analysis revealed the presence of CdSe/CdS with an epitaxial shell growth. Therefore, it may be concluded that CdSe/CdS quantum dots with core-shell nanostructure were effectively synthesized.(author)

Phenotypic differentiation of the Red Sea gastropods in response to the environmental deterioration: Geometric morphometric approach

Science.gov (United States)

Abdelhady, Ahmed Awad

2016-03-01

The negative impacts of degradation in the coastal zone of the Red Sea are becoming well known in upper portions of the trophic web (e.g., humans and fish), but are less well known among the benthic primary consumers. In addition, the degree to which heavy metals are entering the trophic web can be better-quantified using macrobenthos. Two-gastropod genera encompassing Echinolittorina subnodosa and Planaxis sulcatus from three different localities on the Egyptian coast of the Red Sea were examined in order to deduce the impact of environmental deterioration on the morphology of shells. The examined sites include clean pristine, slightly polluted, and markedly polluted rocky shores. Phosphate/lead industry is the main source of pollution in this zone. Because landmarks on the rugose Echinolittorina are difficult to define and to ensure finer resolution of the analyses, a newly 'grid-based' landmarks was implemented. Both Canonical Variate Analysis (CVA) and Thin Plate Spline (TPS) were particularly capable to capture and terrace the minor morphological variations accurately. Two phenotypes portioned among the environmentally different populations were recognized and interpreted as ecotypes with many intermediate forms. The first ecotype has a higher spire and smaller aperture and dominating the pristine site North of Marsa Alam, whereas the second ecotype has a globular shell shape with big aperture and dominating the markedly polluted site. The intermediate forms dominating the slightly polluted site. The shape differences are interpreted as an adaptive differentiation to different metal concentrations. As the morphological variation between the two-ecotypes of both taxa is still minors, and both ecotypes occur together with many intermediate forms, the phenotypic divergence stage has not yet accomplished. The gradational shape change among the investigated populations was positively correlated with index of Pollution (IP). As the human activities were the main

D Central Line Extraction of Fossil Oyster Shells

Science.gov (United States)

Djuricic, A.; Puttonen, E.; Harzhauser, M.; Mandic, O.; Székely, B.; Pfeifer, N.

2016-06-01

Photogrammetry provides a powerful tool to digitally document protected, inaccessible, and rare fossils. This saves manpower in relation to current documentation practice and makes the fragile specimens more available for paleontological analysis and public education. In this study, high resolution orthophoto (0.5 mm) and digital surface models (1 mm) are used to define fossil boundaries that are then used as an input to automatically extract fossil length information via central lines. In general, central lines are widely used in geosciences as they ease observation, monitoring and evaluation of object dimensions. Here, the 3D central lines are used in a novel paleontological context to study fossilized oyster shells with photogrammetric and LiDAR-obtained 3D point cloud data. 3D central lines of 1121 Crassostrea gryphoides oysters of various shapes and sizes were computed in the study. Central line calculation included: i) Delaunay triangulation between the fossil shell boundary points and formation of the Voronoi diagram; ii) extraction of Voronoi vertices and construction of a connected graph tree from them; iii) reduction of the graph to the longest possible central line via Dijkstra's algorithm; iv) extension of longest central line to the shell boundary and smoothing by an adjustment of cubic spline curve; and v) integration of the central line into the corresponding 3D point cloud. The resulting longest path estimate for the 3D central line is a size parameter that can be applied in oyster shell age determination both in paleontological and biological applications. Our investigation evaluates ability and performance of the central line method to measure shell sizes accurately by comparing automatically extracted central lines with manually collected reference data used in paleontological analysis. Our results show that the automatically obtained central line length overestimated the manually collected reference by 1.5% in the test set, which is deemed

Colorful seashells: Identification of haem pathway genes associated with the synthesis of porphyrin shell color in marine snails

KAUST Repository

Williams, Suzanne T.; Lockyer, Anne E.; Dyal, Patricia; Nakano, Tomoyuki; Churchill, Celia K. C.; Speiser, Daniel I.

2017-01-01

Very little is known about the evolution of molluskan shell pigments, although Mollusca is a highly diverse, species rich, and ecologically important group of animals comprised of many brightly colored taxa. The marine snail genus Clanculus was chosen as an exceptional model for studying the evolution of shell color, first, because in Clanculus margaritarius and Clanculus pharaonius both shell and foot share similar colors and patterns; and second, because recent studies have identified the pigments, trochopuniceus (pink-red), and trochoxouthos (yellow-brown), both comprised of uroporphyrin I and uroporphyrin III, in both shell and colored foot tissue of these species. These unusual characteristics provide a rare opportunity to identify the genes involved in color production because, as the same pigments occur in the shell and colored foot tissue, the same color-related genes may be simultaneously expressed in both mantle (which produces the shell) and foot tissue. In this study, the transcriptomes of these two Clanculus species along with a third species, Calliostoma zizyphinum, were sequenced to identify genes associated with the synthesis of porphyrins. Calliostoma zizyphinum was selected as a negative control as trochopuniceus and trochoxouthos were not found to occur in this species. As expected, genes necessary for the production of uroporphyrin I and III were found in all three species, but gene expression levels were consistent with synthesis of uroporphyrins in mantle and colored foot tissue only in Clanculus. These results are relevant not only to understanding the evolution of shell pigmentation in Clanculus but also to understanding the evolution of color in other species with uroporphyrin pigmentation, including (mainly marine) mollusks soft tissues and shells, annelid and platyhelminth worms, and some bird feathers.

Colorful seashells: Identification of haem pathway genes associated with the synthesis of porphyrin shell color in marine snails

KAUST Repository

Williams, Suzanne T.

2017-10-30

Very little is known about the evolution of molluskan shell pigments, although Mollusca is a highly diverse, species rich, and ecologically important group of animals comprised of many brightly colored taxa. The marine snail genus Clanculus was chosen as an exceptional model for studying the evolution of shell color, first, because in Clanculus margaritarius and Clanculus pharaonius both shell and foot share similar colors and patterns; and second, because recent studies have identified the pigments, trochopuniceus (pink-red), and trochoxouthos (yellow-brown), both comprised of uroporphyrin I and uroporphyrin III, in both shell and colored foot tissue of these species. These unusual characteristics provide a rare opportunity to identify the genes involved in color production because, as the same pigments occur in the shell and colored foot tissue, the same color-related genes may be simultaneously expressed in both mantle (which produces the shell) and foot tissue. In this study, the transcriptomes of these two Clanculus species along with a third species, Calliostoma zizyphinum, were sequenced to identify genes associated with the synthesis of porphyrins. Calliostoma zizyphinum was selected as a negative control as trochopuniceus and trochoxouthos were not found to occur in this species. As expected, genes necessary for the production of uroporphyrin I and III were found in all three species, but gene expression levels were consistent with synthesis of uroporphyrins in mantle and colored foot tissue only in Clanculus. These results are relevant not only to understanding the evolution of shell pigmentation in Clanculus but also to understanding the evolution of color in other species with uroporphyrin pigmentation, including (mainly marine) mollusks soft tissues and shells, annelid and platyhelminth worms, and some bird feathers.

Molluscan shell colour.

Science.gov (United States)

Williams, Suzanne T

2017-05-01

The phylum Mollusca is highly speciose, and is the largest phylum in the marine realm. The great majority of molluscs are shelled, including nearly all bivalves, most gastropods and some cephalopods. The fabulous and diverse colours and patterns of molluscan shells are widely recognised and have been appreciated for hundreds of years by collectors and scientists alike. They serve taxonomists as characters that can be used to recognise and distinguish species, however their function for the animal is sometimes less clear and has been the focus of many ecological and evolutionary studies. Despite these studies, almost nothing is known about the evolution of colour in molluscan shells. This review summarises for the first time major findings of disparate studies relevant to the evolution of shell colour in Mollusca and discusses the importance of colour, including the effects of visual and non-visual selection, diet and abiotic factors. I also summarise the evidence for the heritability of shell colour in some taxa and recent efforts to understand the molecular mechanisms underpinning synthesis of shell colours. I describe some of the main shell pigments found in Mollusca (carotenoids, melanin and tetrapyrroles, including porphyrins and bile pigments), and their durability in the fossil record. Finally I suggest that pigments appear to be distributed in a phylogenetically relevant manner and that the synthesis of colour is likely to be energetically costly. © 2016 Cambridge Philosophical Society.

Sexual selection on land snail shell ornamentation: a hypothesis that may explain shell diversity

Directory of Open Access Journals (Sweden)

Schilthuizen Menno

2003-06-01

Full Text Available Abstract Background Many groups of land snails show great interspecific diversity in shell ornamentation, which may include spines on the shell and flanges on the aperture. Such structures have been explained as camouflage or defence, but the possibility that they might be under sexual selection has not previously been explored. Presentation of the hypothesis The hypothesis that is presented consists of two parts. First, that shell ornamentation is the result of sexual selection. Second, that such sexual selection has caused the divergence in shell shape in different species. Testing the hypothesis The first part of the hypothesis may be tested by searching for sexual dimorphism in shell ornamentation in gonochoristic snails, by searching for increased variance in shell ornamentation relative to other shell traits, and by mate choice experiments using individuals with experimentally enhanced ornamentation. The second part of the hypothesis may be tested by comparing sister groups and correlating shell diversity with degree of polygamy. Implications of the hypothesis If the hypothesis were true, it would provide an explanation for the many cases of allopatric evolutionary radiation in snails, where shell diversity cannot be related to any niche differentiation or environmental differences.

Dark-red-emitting CdTe0.5Se0.5/Cd0.5Zn0.5S quantum dots: Effect of chemicals on properties

International Nuclear Information System (INIS)

Yang, Ping; Zhang, Aiyu; Li, Xiaoyu; Liu, Ning; Zhang, Yulan; Zhang, Ruili

2013-01-01

CdTe 0.5 Se 0.5 /Cd 0.5 Zn 0.5 S core/shell quantum dots (QDs) with a tunable photoluminescence (PL) range from yellow to dark red (up to a PL peak wavelength of 683 nm) were fabricated using various reaction systems. The core/shell QDs created in the reaction solution of trioctylamine (TOA) and oleic acid (OA) at 300 °C exhibited narrow PL spectra and a related low PL efficiency (38%). In contrast, the core/shell QDs prepared in the solution of 1-octadecene (ODE) and hexadecylamine (HDA) at 200 °C revealed a high PL efficiency (70%) and broad PL spectra. This phenomenon is ascribed that the precursor of Cd, reaction temperature, solvents, and ligands affected the formation process of the shell. The slow growth rate of the shell in the solution of ODE and HDA made QDs with a high PL efficiency. Metal acetate salts without reaction with HDA led to the core/shell QDs with a broad size distribution. - Graphical abstract: CdTe 0.5 Se 0.5 /Cd 0.5 Zn 0.5 S quantum dots (QDs) with tunable photoluminescence, high PL efficiency, and high stability through organic synthesis, in which chemicals affected the properties of the QDs. Display Omitted - Highlights: • CdTe 0.5 Se 0.5 /Cd 0.5 Zn 0.5 S quantum dots created via organic synthesis. • Chemicals affected the properties of the quantum dots. • The quantum dots revealed high photoluminescence efficiency and stability. • The quantum dots with tunable photoluminescence in a range from yellow to dark red. • The QDs are utilizable for various applications such as biological labeling

Windows PowerShell 20 Bible

CERN Document Server

Lee, Thomas; Schill, Mark E; Tanasovski, Tome

2011-01-01

Here's the complete guide to Windows PowerShell 2.0 for administrators and developers Windows PowerShell is Microsoft's next-generation scripting and automation language. This comprehensive volume provides the background that IT administrators and developers need in order to start using PowerShell automation in exciting new ways. It explains what PowerShell is, how to use the language, and specific ways to apply PowerShell in various technologies. Windows PowerShell is Microsoft's standard automation tool and something that every Windows administrator will eventually have to understand; this b

TWO-DIMENSIONAL APPROXIMATION OF EIGENVALUE PROBLEMS IN SHELL THEORY: FLEXURAL SHELLS

Institute of Scientific and Technical Information of China (English)

无

2000-01-01

The eigenvalue problem for a thin linearly elastic shell, of thickness 2e, clamped along its lateral surface is considered. Under the geometric assumption on the middle surface of the shell that the space of inextensional displacements is non-trivial, the authors obtain, as ε→0,the eigenvalue problem for the two-dimensional"flexural shell"model if the dimension of the space is infinite. If the space is finite dimensional, the limits of the eigenvalues could belong to the spectra of both flexural and membrane shells. The method consists of rescaling the variables and studying the problem over a fixed domain. The principal difficulty lies in obtaining suitable a priori estimates for the scaled eigenvalues.

OGLE-2013-SN-079: A LONELY SUPERNOVA CONSISTENT WITH A HELIUM SHELL DETONATION

International Nuclear Information System (INIS)

Inserra, C.; Sim, S. A.; Smartt, S. J.; Nicholl, M.; Jerkstrand, A.; Chen, T.-W.; Wyrzykowski, L.; Fraser, M.; Blagorodnova, N.; Campbell, H.; Shen, K. J.; Gal-Yam, A.; Howell, D. A.; Valenti, S.; Maguire, K.; Mazzali, P.; Bersier, D.; Taubenberger, S.; Benitez-Herrera, S.; Elias-Rosa, N.

2015-01-01

We present observational data for a peculiar supernova discovered by the OGLE-IV survey and followed by the Public ESO Spectroscopic Survey for Transient Objects. The inferred redshift of z = 0.07 implies an absolute magnitude in the rest-frame I-band of M I ∼ –17.6 mag. This places it in the luminosity range between normal Type Ia SNe and novae. Optical and near infrared spectroscopy reveal mostly Ti and Ca lines, and an unusually red color arising from strong depression of flux at rest wavelengths <5000 Å. To date, this is the only reported SN showing Ti-dominated spectra. The data are broadly consistent with existing models for the pure detonation of a helium shell around a low-mass CO white dwarf and ''double-detonation'' models that include a secondary detonation of a CO core following a primary detonation in an overlying helium shell

OGLE-2013-SN-079: A LONELY SUPERNOVA CONSISTENT WITH A HELIUM SHELL DETONATION

Energy Technology Data Exchange (ETDEWEB)

Inserra, C.; Sim, S. A.; Smartt, S. J.; Nicholl, M.; Jerkstrand, A.; Chen, T.-W. [Astrophysics Research Centre, School of Mathematics and Physics, Queens University Belfast, Belfast BT7 1NN (United Kingdom); Wyrzykowski, L. [University of Warsaw, Astronomical Observatory, Al. Ujazdowskie 400-478 Warszawa (Poland); Fraser, M.; Blagorodnova, N.; Campbell, H. [Institute of Astronomy, University of Cambridge, Madingley Road, CB3 0HA Cambridge (United Kingdom); Shen, K. J. [Department of Astronomy and Theoretical Astrophysics Center, University of California, Berkeley, CA 94720 (United States); Gal-Yam, A. [Benoziyo Center for Astrophysics, Weizmann Institute of Science, 76100 Rehovot (Israel); Howell, D. A.; Valenti, S. [Las Cumbres Observatory Global Telescope Network, 6740 Cortona Drive, Suite 102 Goleta, CA 93117 (United States); Maguire, K. [European Southern Observatory for Astronomical Research in the Southern Hemisphere (ESO), Karl-Schwarzschild-Str. 2, 85748 Garching b. Munchen (Germany); Mazzali, P.; Bersier, D. [Astrophysics Research Institute, Liverpool John Moores University, Liverpool (United Kingdom); Taubenberger, S.; Benitez-Herrera, S. [Max-Planck-Institut für Astrophysik, Karl-Schwarzschild-Str. 1, 85741 Garching (Germany); Elias-Rosa, N., E-mail: c.inserra@qub.ac.uk [INAF - Osservatorio Astronomico di Padova, Vicolo dell' Osservatorio 5, I-35122 Padova (Italy); and others

2015-01-20

We present observational data for a peculiar supernova discovered by the OGLE-IV survey and followed by the Public ESO Spectroscopic Survey for Transient Objects. The inferred redshift of z = 0.07 implies an absolute magnitude in the rest-frame I-band of M{sub I} ∼ –17.6 mag. This places it in the luminosity range between normal Type Ia SNe and novae. Optical and near infrared spectroscopy reveal mostly Ti and Ca lines, and an unusually red color arising from strong depression of flux at rest wavelengths <5000 Å. To date, this is the only reported SN showing Ti-dominated spectra. The data are broadly consistent with existing models for the pure detonation of a helium shell around a low-mass CO white dwarf and ''double-detonation'' models that include a secondary detonation of a CO core following a primary detonation in an overlying helium shell.

Finite-difference analysis of shells impacting rigid barriers

International Nuclear Information System (INIS)

Pirotin, S.D.; Witmer, E.A.

1977-01-01

Nuclear power plants must be protected from the adverse effects of missile impacts. A significant category of missile impact involves deformable structures (pressure vessel components, whipping pipes) striking relatively rigid targets (concrete walls, bumpers) which act as protective devices. The response and interaction of these structures is needed to assess the adequacy of these barriers for protecting vital safety related equipment. The present investigation represents an initial attempt to develop an efficient numerical procedure for predicting the deformations and impact force time-histories of shells which impact upon a rigid target. The general large-deflection equations of motion of the shell are expressed in finite-difference form in space and integrated in time through application of the central-difference temporal operator. The effect of material nonlinearities is treated by a mechanical sublayer material model which handles the strain-hardening, Bauschinger, and strain-rate effects. The general adequacy of this shell treatment has been validated by comparing predictions with the results of various experiments in which structures have been subjected to well-defined transient forcing functions (typically high-explosive impulse loading). The 'new' ingredient addressed in the present study involves an accounting for impact interaction and response of both the target structure and the attacking body. (Auth.)

Revisiting chameleon gravity: Thin-shell and no-shell fields with appropriate boundary conditions

International Nuclear Information System (INIS)

Tamaki, Takashi; Tsujikawa, Shinji

2008-01-01

We derive analytic solutions of a chameleon scalar field φ that couples to a nonrelativistic matter in the weak gravitational background of a spherically symmetric body, paying particular attention to a field mass m A inside of the body. The standard thin-shell field profile is recovered by taking the limit m A r c →∞, where r c is a radius of the body. We show the existence of ''no-shell'' solutions where the field is nearly frozen in the whole interior of the body, which does not necessarily correspond to the 'zero-shell' limit of thin-shell solutions. In the no-shell case, under the condition m A r c >>1, the effective coupling of φ with matter takes the same asymptotic form as that in the thin-shell case. We study experimental bounds coming from the violation of equivalence principle as well as solar-system tests for a number of models including f(R) gravity and find that the field is in either the thin-shell or the no-shell regime under such constraints, depending on the shape of scalar-field potentials. We also show that, for the consistency with local gravity constraints, the field at the center of the body needs to be extremely close to the value φ A at the extremum of an effective potential induced by the matter coupling.

Transport comparison of multiwall carbon nanotubes by contacting outer shell and all shells.

Science.gov (United States)

Luo, Qiang; Cui, A-Juan; Zhang, Yi-Guang; Lu, Chao; Jin, Ai-Zi; Yang, Hai-Fang; Gu, Chang-Zhi

2010-11-01

Carbon nanotubes, particularly multiwall carbon nanotubes (MWCNTs) can serve as interconnects in nanoelectronic devices and integrated circuits because of their extremely large current-carrying capacity. Many experimental results about the transport properties of individual MWCNTs by contacting outer shell or all shells have been reported. In this work, a compatible method with integrated circuit manufacturing process was presented to compare the transport property of an individual multiwall carbon nanotube (MWCNT) by contacting outer shell only and all shells successively. First of the Ti/Au electrodes contacting outer shell only were fabricated onto the nanotube through the sequence of electron beam lithography (EBL) patterning, metal deposition and lift-off process. After the characterization of its transport property, focused ion beam (FIB) was used to drill holes through the same nanotube at the as-deposited electrodes. Then new contact to the holes and electrodes were made by ion-induced deposition of tungsten from W(CO)6 precursor gas. The transport results indicated that the new contact to all shells can clear up the intershell resistance and the electrical conductance of the tube can be improved about 8 times compared to that of by contacting outer shell only.

Hyperemic peripheral red marrow in a patient with sickle cell anemia demonstrated on Tc-99m labeled red blood cell venography

International Nuclear Information System (INIS)

Heiden, R.A.; Locko, R.C.; Stent, T.R.

1991-01-01

A 25-year-old gravid woman, homozygous for sickle cell anemia, with a history of recent deep venous thrombosis, was examined using Tc-99m labeled red blood cell venography for recurrent thrombosis. Although negative for thrombus, the study presented an unusual incidental finding: the patient's peripheral bone marrow was hyperemic in a distribution consistent with peripheral red bone marrow expansion. Such a pattern has not been documented before using this technique. This report supports other literature that has demonstrated hyperemia of peripheral red bone marrow in other hemolytic anemias. This finding may ultimately define an additional role of scintigraphy in assessing the pathophysiologic status of the sickle cell patient

On mass-shell parametric space renormalization of PHI3 theory in six dimensions

International Nuclear Information System (INIS)

Smith, A.W.

1977-05-01

An on mass shell, parametric space renormalization procedure for phi 3 theory in six dimensions is defined and its formal equivalence to the usual Lagrangian counter procedure demonstrated. Two loop contributions to the self-energy are used as an illustration of the method. (author)

PLGA-lecithin-PEG core-shell nanoparticles for controlled drug delivery.

Science.gov (United States)

Chan, Juliana M; Zhang, Liangfang; Yuet, Kai P; Liao, Grace; Rhee, June-Wha; Langer, Robert; Farokhzad, Omid C

2009-03-01

Current approaches to encapsulate and deliver therapeutic compounds have focused on developing liposomal and biodegradable polymeric nanoparticles (NPs), resulting in clinically approved therapeutics such as Doxil/Caelyx and Genexol-PM, respectively. Our group recently reported the development of biodegradable core-shell NP systems that combined the beneficial properties of liposomal and polymeric NPs for controlled drug delivery. Herein we report the parameters that alter the biological and physicochemical characteristics, stability, drug release properties and cytotoxicity of these core-shell NPs. We further define scalable processes for the formulation of these NPs in a reproducible manner. These core-shell NPs consist of (i) a poly(D,L-lactide-co-glycolide) hydrophobic core, (ii) a soybean lecithin monolayer, and (iii) a poly(ethylene glycol) shell, and were synthesized by a modified nanoprecipitation method combined with self-assembly. Preparation of the NPs showed that various formulation parameters such as the lipid/polymer mass ratio and lipid/lipid-PEG molar ratio controlled NP physical stability and size. We encapsulated a model chemotherapy drug, docetaxel, in the NPs and showed that the amount of lipid coverage affected its drug release kinetics. Next, we demonstrated a potentially scalable process for the formulation, purification, and storage of NPs. Finally, we tested the cytotoxicity using MTT assays on two model human cell lines, HeLa and HepG2, and demonstrated the biocompatibility of these particles in vitro. Our data suggest that the PLGA-lecithin-PEG core-shell NPs may be a useful new controlled release drug delivery system.

Modification of Ag shell on upconversion populating paths of NaYF{sub 4}:Yb{sup 3+},Er{sup 3+}@Ag nanocomposites

Energy Technology Data Exchange (ETDEWEB)

Sun, Jiao [Norman Bethune College of Medicine, Jilin University, Changchun, Jilin Province 130021 (China); Liu, Haipeng [Department of Plastic and Reconstructive Surgery, The First Hospital of JiLin University, Jilin Province 130021 (China); Wu, Di [Norman Bethune College of Medicine, Jilin University, Changchun, Jilin Province 130021 (China); Dong, Biao, E-mail: dongb@jlu.edu.cn [State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012 (China); Sun, Liankun [Norman Bethune College of Medicine, Jilin University, Changchun, Jilin Province 130021 (China)

2013-01-15

NaYF{sub 4}:Yb{sup 3+},Er{sup 3+}@Ag core-shell nanocomposites were prepared. Due to the outer shell of Ag, some modifications were found on the upconversion (UC) processes of NaYF{sub 4}:Yb{sup 3+},Er{sup 3+} core nanoparticles (NPs) caused by the co-interaction of surface effect, surface plasma absorption effect and local thermal effect under infrared radiation. Upon 980 nm excitation, the relative UC intensity of the green ({sup 2}H{sub 11/2}, {sup 4}S{sub 3/2}-{sup 4}I{sub 15/2}) to red ({sup 4}F{sub 9/2}-{sup 4}I{sub 15/2}) and the slope of power-dependence increased intensively, and three-photon population process for the green level appeared. -- Highlights: Black-Right-Pointing-Pointer NaYF{sub 4}:Yb{sup 3+},Er{sup 3+}@Ag core/shell nanocomposites were fabricated. Black-Right-Pointing-Pointer The coating of Ag outer shell leads to the increase of the green UCL. Black-Right-Pointing-Pointer Three-photon population process for the green level appeared after Ag coating.

A shell-neutral modeling approach yields sustainable oyster harvest estimates: a retrospective analysis of the Louisiana state primary seed grounds

Science.gov (United States)

Soniat, Thomas M.; Klinck, John M.; Powell, Eric N.; Cooper, Nathan; Abdelguerfi, Mahdi; Hofmann, Eileen E.; Dahal, Janak; Tu, Shengru; Finigan, John; Eberline, Benjamin S.; La Peyre, Jerome F.; LaPeyre, Megan K.; Qaddoura, Fareed

2012-01-01

A numerical model is presented that defines a sustainability criterion as no net loss of shell, and calculates a sustainable harvest of seed (<75 mm) and sack or market oysters (≥75 mm). Stock assessments of the Primary State Seed Grounds conducted east of the Mississippi from 2009 to 2011 show a general trend toward decreasing abundance of sack and seed oysters. Retrospective simulations provide estimates of annual sustainable harvests. Comparisons of simulated sustainable harvests with actual harvests show a trend toward unsustainable harvests toward the end of the time series. Stock assessments combined with shell-neutral models can be used to estimate sustainable harvest and manage cultch through shell planting when actual harvest exceeds sustainable harvest. For exclusive restoration efforts (no fishing allowed), the model provides a metric for restoration success-namely, shell accretion. Oyster fisheries that remove shell versus reef restorations that promote shell accretion, although divergent in their goals, are convergent in their management; both require vigilant attention to shell budgets.

Production of biodiesel from sunflower oil using highly catalytic bimetallic gold–silver core–shell nanoparticle

International Nuclear Information System (INIS)

Banerjee, Madhuchanda; Dey, Binita; Talukdar, Jayanta; Chandra Kalita, Mohan

2014-01-01

Bimetallic Gold–silver core–shell nanoparticles (Au@Ag NPs) were synthesized at room temperature, where gold nanoparticles (AuNPs) served as seeds for continuous deposition of silver atoms on its surface. The core–shell structure was examined by UV–vis spectroscopy, transmission electron microscopy (TEM) and energy dispersive X-ray (EDX) analysis. The catalytic activity of these nanoparticles toward biodiesel production from Sunflower oil through transesterification was studied. The confirmation for biofuel synthesis was performed using Fourier Transform Infra-Red (FTIR) spectroscopy. Fuel properties are determined by standard ASTM (American society for Testing and Materials) protocols. Our observations show that at certain catalyst concentration, temperature and reaction time, highest yield of biodiesel (86.9%) is attained. The fuel properties of the synthesized biofuel are at par with standard biofuel. Further, the catalyst showed sustained activity for 3 cycles of transesterification. - Highlights: • Gold–silver core–shell NPs were used for biofuel synthesis from sunflower oil. • At the optimized condition, biodiesel yield of 86.9% was achieved. • Fuel properties of the biofuel synthesized are at par with standard biofuel. • The catalyst showed sustained activity for 3 cycles of transesterification

Structural and electrical properties of TiO2/ZnO core–shell nanoparticles synthesized by hydrothermal method

International Nuclear Information System (INIS)

Vlazan, P.; Ursu, D.H.; Irina-Moisescu, C.; Miron, I.; Sfirloaga, P.; Rusu, E.

2015-01-01

TiO 2 /ZnO core–shell nanoparticles were successfully synthesized by hydrothermal method in two stages: first stage is the hydrothermal synthesis of ZnO nanoparticles and second stage the obtained ZnO nanoparticles are encapsulated in TiO 2 . The obtained ZnO, TiO 2 and TiO 2 /ZnO core–shell nanoparticles were investigated by means of X-ray diffraction, transmission electron microscopy, Brunauer, Emmett, Teller and resistance measurements. X-ray diffraction analysis revealed the presence of both, TiO 2 and ZnO phases in TiO 2 /ZnO core–shell nanoparticles. According to transmission electron microscopy images, ZnO nanoparticles have hexagonal shapes, TiO 2 nanoparticles have a spherical shape, and TiO 2 /ZnO core–shell nanoparticles present agglomerates and the shape of particles is not well defined. The activation energy of TiO 2 /ZnO core–shell nanoparticles was about 101 meV. - Graphical abstract: Display Omitted - Highlights: • TiO 2 /ZnO core–shell nanoparticles were synthesized by hydrothermal method. • TiO 2 /ZnO core–shell nanoparticles were investigated by means of XRD, TEM and BET. • Electrical properties of TiO 2 /ZnO core–shell nanoparticles were investigated. • The activation energy of TiO 2 /ZnO core–shell nanoparticles was about E a = 101 meV

Shell cracking strength in almond (Prunus dulcis [Mill.] D.A. Webb.) and its implication in uses as a value-added product.

Science.gov (United States)

Ledbetter, C A

2008-09-01

Researchers are currently developing new value-added uses for almond shells, an abundant agricultural by-product. Almond varieties are distinguished by processors as being either hard or soft shelled, but these two broad classes of almond also exhibit varietal diversity in shell morphology and physical characters. By defining more precisely the physical and chemical characteristics of almond shells from different varieties, researchers will better understand which specific shell types are best suited for specific industrial processes. Eight diverse almond accessions were evaluated in two consecutive harvest seasons for nut and kernel weight, kernel percentage and shell cracking strength. Shell bulk density was evaluated in a separate year. Harvest year by almond accession interactions were highly significant (p0.01) for each of the analyzed variables. Significant (p0.01) correlations were noted for average nut weight with kernel weight, kernel percentage and shell cracking strength. A significant (p0.01) negative correlation for shell cracking strength with kernel percentage was noted. In some cases shell cracking strength was independent of the kernel percentage which suggests that either variety compositional differences or shell morphology affect the shell cracking strength. The varietal characterization of almond shell materials will assist in determining the best value-added uses for this abundant agricultural by-product.

3D CENTRAL LINE EXTRACTION OF FOSSIL OYSTER SHELLS

Directory of Open Access Journals (Sweden)

A. Djuricic

2016-06-01

Full Text Available Photogrammetry provides a powerful tool to digitally document protected, inaccessible, and rare fossils. This saves manpower in relation to current documentation practice and makes the fragile specimens more available for paleontological analysis and public education. In this study, high resolution orthophoto (0.5 mm and digital surface models (1 mm are used to define fossil boundaries that are then used as an input to automatically extract fossil length information via central lines. In general, central lines are widely used in geosciences as they ease observation, monitoring and evaluation of object dimensions. Here, the 3D central lines are used in a novel paleontological context to study fossilized oyster shells with photogrammetric and LiDAR-obtained 3D point cloud data. 3D central lines of 1121 Crassostrea gryphoides oysters of various shapes and sizes were computed in the study. Central line calculation included: i Delaunay triangulation between the fossil shell boundary points and formation of the Voronoi diagram; ii extraction of Voronoi vertices and construction of a connected graph tree from them; iii reduction of the graph to the longest possible central line via Dijkstra’s algorithm; iv extension of longest central line to the shell boundary and smoothing by an adjustment of cubic spline curve; and v integration of the central line into the corresponding 3D point cloud. The resulting longest path estimate for the 3D central line is a size parameter that can be applied in oyster shell age determination both in paleontological and biological applications. Our investigation evaluates ability and performance of the central line method to measure shell sizes accurately by comparing automatically extracted central lines with manually collected reference data used in paleontological analysis. Our results show that the automatically obtained central line length overestimated the manually collected reference by 1.5% in the test set, which

Interpretation of the spectrum of the Red Rectangle

International Nuclear Information System (INIS)

Greenstein, J.L.; Oke, J.B.

1977-01-01

The strong infrared source centered on HD 44179 has been observed with the multichannel spectrophotometer from 0.35μ to 1.1μ. The stellar spectrum is anomalous. If we fit a model atmosphere suitable for a late B giant it must have a circumstellar shell. If it is a low-gravity F bright giant its reported slit spectrum suggests unusual composition. The total luminosity is high, from the far infrared fluxes. The nebula, the Red Rectangle, has been observed without stellar contamination. Largely of the reflection type, it is unusual in being considerably redder than the star. The surface brightness is interpreted from the first-order and exact theory of scattering by grains in an optically thick nebula, with the star in front. The color is ascribed to the variation of the albedo with frequency. An unusual feature is a broad upward rise in brightness of the nebula, centered at 6600 A, requiring a four-fold increase in albedo over a region 1700 A wide (full width at half maximum). The albedo is so high that the most favorable geometry must be assumed; otherwise the red maximum might require fluorescence. If the high reflectivity in the red is a feature of the dust grains, they have composition quite different from other reflection nebulae, meteorites, or planets

Refined 2D and Exact 3D Shell Models for the Free Vibration Analysis of Single- and Double-Walled Carbon Nanotubes

Directory of Open Access Journals (Sweden)

Salvatore Brischetto

2015-12-01

Full Text Available The present paper talks about the free vibration analysis of simply supported Single- and Double-Walled Carbon Nanotubes (SWCNTs and DWCNTs. Refined 2D Generalized Differential Quadrature (GDQ shell methods and an exact 3D shell model are compared. A continuum approach (based on an elastic three-dimensional shell model is used for natural frequency investigation of SWCNTs and DWCNTs. SWCNTs are defined as isotropic cylinders with an equivalent thickness and Young modulus. DWCNTs are defined as two concentric isotropic cylinders (with an equivalent thickness and Young modulus which can be linked by means of the interlaminar continuity conditions or by means of van der Waals interactions. Layer wise approaches are mandatory for the analysis of van der Waals forces in DWCNTs. The effect of van der Waals interaction between the two cylinders is shown for different DWCNT lengths, diameters and vibration modes. The accuracy of beam models and classical 2D shell models in the free vibration analysis of SWCNTs and DWCNTs is also investigated.

Local shell-to-shell energy transfer via nonlocal interactions in fluid ...

Indian Academy of Sciences (India)

However, the shell-to-shell energy transfer rate is found to be local and forward. .... interaction was strong, but the energy exchange occurred predominantly between ..... The wave-number range considered is in the inverse cascade regime.

Multi-shelled ZnCo2O4 yolk-shell spheres for high-performance acetone gas sensor

Science.gov (United States)

Xiong, Ya; Zhu, Zongye; Ding, Degong; Lu, Wenbo; Xue, Qingzhong

2018-06-01

In the present study, multi-shelled ZnCo2O4 yolk-shell spheres have been successfully prepared by using carbonaceous microspheres as templates. It is found that the multi-shelled ZnCo2O4 yolk-shell spheres based sensor shows optimal sensing performances (response value of 38.2, response/recovery time of 19 s/71 s) toward 500 ppm acetone at 200 °C. In addition, this sensor exhibits a low detection limit of 0.5 ppm acetone (response value of 1.36) and a good selectivity toward hydrogen, methane, ethanol, ammonia and carbon dioxide. Furthermore, it is demonstrated that acetone gas response of multi-shelled ZnCo2O4 yolk-shell spheres is significantly better than that of ZnCo2O4 nanotubes and ZnCo2O4 nanosheets. High acetone response of the multi-shelled ZnCo2O4 yolk-shell spheres is attributed to the enhanced gas accessibility of the multi-shell morphology caused by the small crystalline size and high specific surface area while the short response/recovery time is mainly related to the rapid gas diffusion determined by the highly porous structure. Our work puts forward an exciting opportunity in designing various yolk-shelled structures for multipurpose applications.

Tube-in-shell heat exchangers

International Nuclear Information System (INIS)

Richardson, J.

1976-01-01

Tube-in-shell heat exchangers normally comprise a bundle of parallel tubes within a shell container, with a fluid arranged to flow through the tubes in heat exchange with a second fluid flowing through the shell. The tubes are usually end supported by the tube plates that separate the two fluids, and in use the tube attachments to the tube plates and the tube plates can be subject to severe stress by thermal shock and frequent inspection and servicing are required. Where the heat exchangers are immersed in a coolant such as liquid Na such inspection is difficult. In the arrangement described a longitudinally extending central tube is provided incorporating axially spaced cylindrical tube plates to which the opposite ends of the tubes are attached. Within this tube there is a tubular baffle that slidably seals against the wall of the tube between the cylindrical tube plates to define two co-axial flow ducts. These ducts are interconnected at the closed end of the tube by the heat exchange tubes and the baffle comprises inner and outer spaced walls with the interspace containing Ar. The baffle is easily removable and can be withdrawn to enable insertion of equipment for inspecting the wall of the tube and tube attachments and to facilitate plugging of defective tubes. Cylindrical tube plates are believed to be superior for carrying pressure loads and resisting the effects of thermal shock. Some protection against thermal shock can be effected by arranging that the secondary heat exchange fluid is on the tube side, and by providing a thermal baffle to prevent direct impingement of hot primary fluid on to the cylindrical tube plates. The inner wall of the tubular baffle may have flexible expansible region. Some nuclear reactor constructions incorporating such an arrangement are described, including liquid metal reactors. (U.K.)

Stiffeners in variational-difference method for calculating shells with complex geometry

Directory of Open Access Journals (Sweden)

Ivanov Vyacheslav Nikolaevich

2014-05-01

Full Text Available We have already considered an introduction of reinforcements in the variational-difference method (VDM of shells analysis with complex shape. At the moment only ribbed shells of revolution and shallow shells can be calculated with the help of developed analytical and finite-difference methods. Ribbed shells of arbitrary shape can be calculated only using the finite element method (FEM. However there are problems, when using FEM, which are absent in finite- and variational-difference methods: rigid body motion; conforming trial functions; parameterization of a surface; independent stress strain state. In this regard stiffeners are entered in VDM. VDM is based on the Lagrange principle - the principle of minimum total potential energy. Stress-strain state of ribs is described by the Kirchhoff-Clebsch theory of curvilinear bars: tension, bending and torsion of ribs are taken into account. Stress-strain state of shells is described by the Kirchhoff-Love theory of thin elastic shells. A position of points of the middle surface is defined by curvilinear orthogonal coordinates α, β. Curved ribs are situated along coordinate lines. Strain energy of ribs is added into the strain energy to account for ribs. A matrix form of strain energy of ribs is formed similar to a matrix form of the strain energy of the shell. A matrix of geometrical characteristics of a rib is formed from components of matrices of geometric characteristics of a shell. A matrix of mechanical characteristics of a rib contains rib’s eccentricity and geometrical characteristics of a rib’s section. Derivatives of displacements in the strain vector are replaced with finite-difference relations after the middle surface of a shell gets covered with a grid (grid lines coincide with the coordinate lines of principal curvatures. By this case the total potential energy functional becomes a function of strain nodal displacements. Partial derivatives of unknown nodal displacements are

Manganese in the shell of the bivalve Mytilus edulis: Seawater Mn or physiological control?

Science.gov (United States)

Freitas, Pedro S.; Clarke, Leon J.; Kennedy, Hilary; Richardson, Christopher A.

2016-12-01

Manganese in the shell calcite of marine bivalves has been suggested to reflect ambient seawater Mn concentrations, thus providing a high-resolution archive of past seawater Mn concentrations. However, a quantitative relationship between seawater Mn and shell Mn/Ca ratios, as well as clear understanding of which process(es) control(s) shell Mn/Ca, are still lacking. Blue mussels, Mytilus edulis, were grown in a one-year duration field experiment in the Menai Strait, U.K., to study the relationship between seawater particulate and dissolved Mn2+ concentrations and shell calcite Mn/Ca ratios. Shell Mn/Ca showed a well-defined intra-annual double-peak, with maximum values during early spring and early summer and low values during autumn and winter. Seawater particulate Mn peaked during winter and autumn, with a series of smaller peaks during spring and summer, whereas dissolved Mn2+ exhibited a marked single maximum during late-spring to early-summer, being low during the remainder of the year. Consequently, neither seawater particulate Mn nor dissolved Mn2+ concentrations explain the intra-annual variation of shell Mn/Ca ratios. A physiological control on shell Mn/Ca ratios is evident from the strong similarity and timing of the double-peaked intra-annual variations of Mn/Ca and shell growth rate (SGR), the latter corresponding to periods of increased metabolic activity (as indicated by respiration rate). It is thus likely that in M. edulis SGR influences shell Mn/Ca by altering the concentration or activity of Mn2+ within the extra-pallial fluid (EPF), by changing the flux of Mn into or the proportion of protein bound Mn within the EPF. By linking shell Mn/Ca ratios to the endogenous and environmental factors that determine growth and metabolic activity, this study helps to explain the lack of a consistent relationship between shell Mn/Ca in marine bivalve shell calcite and seawater particulate and dissolved Mn2+ concentrations. The use of Mn content from M. edulis

Synthesis of Multicolor Core/Shell NaLuF4:Yb3+/Ln3+@CaF2 Upconversion Nanocrystals

Directory of Open Access Journals (Sweden)

Hui Li

2017-02-01

Full Text Available The ability to synthesize high-quality hierarchical core/shell nanocrystals from an efficient host lattice is important to realize efficacious photon upconversion for applications ranging from bioimaging to solar cells. Here, we describe a strategy to fabricate multicolor core @ shell α-NaLuF4:Yb3+/Ln3+@CaF2 (Ln = Er, Ho, Tm upconversion nanocrystals (UCNCs based on the newly established host lattice of sodium lutetium fluoride (NaLuF4. We exploited the liquid-solid-solution method to synthesize the NaLuF4 core of pure cubic phase and the thermal decomposition approach to expitaxially grow the calcium fluoride (CaF2 shell onto the core UCNCs, yielding cubic core/shell nanocrystals with a size of 15.6 ± 1.2 nm (the core ~9 ± 0.9 nm, the shell ~3.3 ± 0.3 nm. We showed that those core/shell UCNCs could emit activator-defined multicolor emissions up to about 772 times more efficient than the core nanocrystals due to effective suppression of surface-related quenching effects. Our results provide a new paradigm on heterogeneous core/shell structure for enhanced multicolor upconversion photoluminescence from colloidal nanocrystals.

Interelectron correlations in photoionization of outer shells near inner shell thresholds

International Nuclear Information System (INIS)

Amusia, M Ya; Chernysheva, L V; Drukarev, E G

2015-01-01

We have studied the role of virtual excitations of inner shells upon outer shell photoionization. The calculations were performed in the frames of the Random Phase Approximation with Exchange (RPAE) and its generalized version GRPAE that take into account variation of the atomic field due to electron elimination and the inner vacancies decay. We apply both analytic approximation and numeric computations. The results are presented for 3p electrons in Ar and for 4d-electrons in Pd near inner shells thresholds. The effect considered proved to be quite noticeable. (paper)

Wrinkling of Pressurized Elastic Shells

KAUST Repository

Vella, Dominic; Ajdari, Amin; Vaziri, Ashkan; Boudaoud, Arezki

2011-01-01

We study the formation of localized structures formed by the point loading of an internally pressurized elastic shell. While unpressurized shells (such as a ping-pong ball) buckle into polygonal structures, we show that pressurized shells

Adsorption of volatile organic compounds by pecan shell- and almond shell-based granular activated carbons.

Science.gov (United States)

Bansode, R R; Losso, J N; Marshall, W E; Rao, R M; Portier, R J

2003-11-01

The objective of this research was to determine the effectiveness of using pecan and almond shell-based granular activated carbons (GACs) in the adsorption of volatile organic compounds (VOCs) of health concern and known toxic compounds (such as bromo-dichloromethane, benzene, carbon tetrachloride, 1,1,1-trichloromethane, chloroform, and 1,1-dichloromethane) compared to the adsorption efficiency of commercially used carbons (such as Filtrasorb 200, Calgon GRC-20, and Waterlinks 206C AW) in simulated test medium. The pecan shell-based GACs were activated using steam, carbon dioxide or phosphoric acid. An almond shell-based GAC was activated with phosphoric acid. Our results indicated that steam- or carbon dioxide-activated pecan shell carbons were superior in total VOC adsorption to phosphoric acid-activated pecan shell or almond shell carbons, inferring that the method of activation selected for the preparation of activated carbons affected the adsorption of VOCs and hence are factors to be considered in any adsorption process. The steam-activated, pecan shell carbon adsorbed more total VOCs than the other experimental carbons and had an adsorption profile similar to the two coconut shell-based commercial carbons, but had greater adsorption than the coal-based commercial carbon. All the carbons studied adsorbed benzene more effectively than the other organics. Pecan shell, steam-activated and acid-activated GACs showed higher adsorption of 1,1,1-trichloroethane than the other carbons studied. Multivariate analysis was conducted to group experimental carbons and commercial carbons based on their physical, chemical, and adsorptive properties. The results of the analysis conclude that steam-activated and acid-activated pecan shell carbons clustered together with coal-based and coconut shell-based commercial carbons, thus inferring that these experimental carbons could potentially be used as alternative sources for VOC adsorption in an aqueous environment.

Instant Windows PowerShell

CERN Document Server

Menon, Vinith

2013-01-01

Get to grips with a new technology, understand what it is and what it can do for you, and then get to work with the most important features and tasks. A practical, hands-on tutorial approach that explores the concepts of PowerShell in a friendly manner, taking an adhoc approach to each topic.If you are an administrator who is new to PowerShell or are looking to get a good grounding in these new features, this book is ideal for you. It's assumed that you will have some experience in PowerShell and Windows Server, as well being familiar with the PowerShell command-line.

Coal option. [Shell Co

Energy Technology Data Exchange (ETDEWEB)

1978-01-01

This paper notes the necessity of developing an international coal trade on a very large scale. The role of Shell in the coal industry is examined; the regions in which Shell companies are most active are Australia, Southern Africa, Indonesia; Europe and North America. Research is being carried out on marketing and transportation, especially via slurry pipelines; coal-oil emulsions; briquets; fluidized-bed combustion; recovery of coal from potential waste material; upgrading of low-rank coals; unconventional forms of mining; coal conversion (the Shell/Koppers high-pressure coal gasification process). Techniques for cleaning flue gas (the Shell Flue Gas Desulfurization process) are being examined.

Re-characterization of the Red-lip Megalobulimus (Gastropoda: Strophocheilidae from Peru with description of a new species

Directory of Open Access Journals (Sweden)

Victor Borda

2013-12-01

Full Text Available Megalobulimus K. Miller, 1878 is a genus of land snails that includes the largest living snails in the Neotropics. The main goal of this paper was to review all species of Megalobulimus that have a red lip, and which are distributed in Peru. We carried out a detailed description of their shells and soft parts, and conducted a multivariate analysis on their shells and geographic distribution. There are two species reported from Peru, Megalobulimus capillaceus (Pfeiffer, 1855 and Megalobulimus separabilis (Fulton, 1903. Megalobulimus capillaceus is known to occur in three regions - San Martín, Huánuco and Cusco - but the Cusco population is undoubtedly different from all remaining populations, and is recognized herein as a new species, Megalobulimus florezi sp. nov. This species has a more elongated shell, penis club-shaped, epiphallus longer, and free oviduct longer than M. capillaceus. By contrast, the male genitalia of M. separabilis is filiform and does not present an external diverticulum in the free oviduct.

Nuclear shell theory

CERN Document Server

de-Shalit, Amos; Massey, H S W

1963-01-01

Nuclear Shell Theory is a comprehensive textbook dealing with modern methods of the nuclear shell model. This book deals with the mathematical theory of a system of Fermions in a central field. It is divided into three parts. Part I discusses the single particle shell model. The second part focuses on the tensor algebra, two-particle systems. The last part covers three or more particle systems. Chapters on wave functions in a central field, tensor fields, and the m-Scheme are also presented. Physicists, graduate students, and teachers of nuclear physics will find the book invaluable.

Wrinkling of Pressurized Elastic Shells

KAUST Repository

Vella, Dominic

2011-10-01

We study the formation of localized structures formed by the point loading of an internally pressurized elastic shell. While unpressurized shells (such as a ping-pong ball) buckle into polygonal structures, we show that pressurized shells are subject to a wrinkling instability. We study wrinkling in depth, presenting scaling laws for the critical indentation at which wrinkling occurs and the number of wrinkles formed in terms of the internal pressurization and material properties of the shell. These results are validated by numerical simulations. We show that the evolution of the wrinkle length with increasing indentation can be understood for highly pressurized shells from membrane theory. These results suggest that the position and number of wrinkles may be used in combination to give simple methods for the estimation of the mechanical properties of highly pressurized shells. © 2011 American Physical Society.

Magnetoliposomes based on nickel/silica core/shell nanoparticles: Synthesis and characterization

Energy Technology Data Exchange (ETDEWEB)

Rodrigues, Ana Rita O.; Gomes, I.T.; Almeida, Bernardo G. [Centro de Física (CFUM), Universidade do Minho, Campus de Gualtar, 4710-057 Braga (Portugal); Araújo, J.P. [IFIMUP/IN – Instituto de Nanociência e Nanotecnologia, R. Campo Alegre, 4169-007 Porto (Portugal); Castanheira, Elisabete M.S. [Centro de Física (CFUM), Universidade do Minho, Campus de Gualtar, 4710-057 Braga (Portugal); Coutinho, Paulo J.G., E-mail: pcoutinho@fisica.uminho.pt [Centro de Física (CFUM), Universidade do Minho, Campus de Gualtar, 4710-057 Braga (Portugal)

2014-12-15

In the present work, nickel magnetic nanoparticles with diameters lower than 100 nm, with and without silica shell, were synthesized by microheterogeneous templating. The magnetic properties of the nanoparticles show a typical ferromagnetic behavior with a coercive field of 80 Oe. Dry magnetoliposomes (DMLs) with diameter between 58 nm and 76 nm were obtained from the synthesis of nanoparticles in the presence of a lipid or surfactant layer, and aqueous magnetoliposomes (AMLs) were obtained by encapsulation of the nanoparticles in liposomes. FRET (Förster resonance energy transfer) experiments were performed to study the non-specific interactions between aqueous magnetoliposomes and giant unilamellar vesicles (GUVs), as models of cell membranes. It was possible to detect membrane fusion between GUVs and AMLs containing both NBD-C{sub 6}-HPC (donor) and the dye Nile Red (acceptor). - Highlights: • Magnetic nickel nanoparticles were synthesized in microheterogeneous media. • The nanoparticles were covered with a silica shell to improve biocompatibility. • Aqueous and dry magnetoliposomes were prepared, the latter with diameter around 70 nm. • Membrane fusion between magnetoliposomes and models of cell membranes was detected by FRET.

Magnetoliposomes based on nickel/silica core/shell nanoparticles: Synthesis and characterization

International Nuclear Information System (INIS)

Rodrigues, Ana Rita O.; Gomes, I.T.; Almeida, Bernardo G.; Araújo, J.P.; Castanheira, Elisabete M.S.; Coutinho, Paulo J.G.

2014-01-01

In the present work, nickel magnetic nanoparticles with diameters lower than 100 nm, with and without silica shell, were synthesized by microheterogeneous templating. The magnetic properties of the nanoparticles show a typical ferromagnetic behavior with a coercive field of 80 Oe. Dry magnetoliposomes (DMLs) with diameter between 58 nm and 76 nm were obtained from the synthesis of nanoparticles in the presence of a lipid or surfactant layer, and aqueous magnetoliposomes (AMLs) were obtained by encapsulation of the nanoparticles in liposomes. FRET (Förster resonance energy transfer) experiments were performed to study the non-specific interactions between aqueous magnetoliposomes and giant unilamellar vesicles (GUVs), as models of cell membranes. It was possible to detect membrane fusion between GUVs and AMLs containing both NBD-C 6 -HPC (donor) and the dye Nile Red (acceptor). - Highlights: • Magnetic nickel nanoparticles were synthesized in microheterogeneous media. • The nanoparticles were covered with a silica shell to improve biocompatibility. • Aqueous and dry magnetoliposomes were prepared, the latter with diameter around 70 nm. • Membrane fusion between magnetoliposomes and models of cell membranes was detected by FRET

Stability of charged thin shells

International Nuclear Information System (INIS)

Eiroa, Ernesto F.; Simeone, Claudio

2011-01-01

In this article we study the mechanical stability of spherically symmetric thin shells with charge, in Einstein-Maxwell and Einstein-Born-Infeld theories. We analyze linearized perturbations preserving the symmetry, for shells around vacuum and shells surrounding noncharged black holes.

Synthesis and characterization of noble metal–titania core–shell nanostructures with tunable shell thickness

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Bartosz Bartosewicz

2017-10-01

Full Text Available Core–shell nanostructures have found applications in many fields, including surface enhanced spectroscopy, catalysis and solar cells. Titania-coated noble metal nanoparticles, which combine the surface plasmon resonance properties of the core and the photoactivity of the shell, have great potential for these applications. However, the controllable synthesis of such nanostructures remains a challenge due to the high reactivity of titania precursors. Hence, a simple titania coating method that would allow better control over the shell formation is desired. A sol–gel based titania coating method, which allows control over the shell thickness, was developed and applied to the synthesis of Ag@TiO2 and Au@TiO2 with various shell thicknesses. The morphology of the synthesized structures was investigated using scanning electron microscopy (SEM. Their sizes and shell thicknesses were determined using tunable resistive pulse sensing (TRPS technique. The optical properties of the synthesized structures were characterized using UV–vis spectroscopy. Ag@TiO2 and Au@TiO2 structures with shell thickness in the range of ≈40–70 nm and 90 nm, for the Ag and Au nanostructures respectively, were prepared using a method we developed and adapted, consisting of a change in the titania precursor concentration. The synthesized nanostructures exhibited significant absorption in the UV–vis range. The TRPS technique was shown to be a very useful tool for the characterization of metal–metal oxide core–shell nanostructures.

On the possibility of wormhole formation due to quantum effects in the gravitational collapse of a small dust shell

Energy Technology Data Exchange (ETDEWEB)

Cruz P, G.; Minzoni, A.; Padilla, P. [Proyecto Universitario en Fenomenos Nolineales y Mecanica Instituto de Investigaciones en Matematicas Aplicadas y en Sistemas, Universidad Nacional Autonoma de Mexico, A.P. 20-726, 04510 Mexico, D.F. (Mexico); Rosenbaum, M.; Ryan, M.P. Jr. [Instituto de Ciencias Nucleares, Proyecto Universitario en Fenomenos Nolineales y Mecanica, Universidad Nacional Autonoma de Mexico, A.P. 70-543, 04510 Mexico, D.F. (Mexico); Smyth, N.F. [Department of Mathematics and Statistics, University of Edinburgh, The King' s Building, Mayfield Road, Edinburgh, Scotland, UK, EH9 3JZ (United Kingdom); Vukasinac, T. [Facultad de Economia, Universidad Michoacana de San Nicolas de Hidalgo, A.P. 2-82, 58030 Morelia, Michoacan (Mexico)

2003-07-01

In the present note we outline the main steps towards the analysis of wormhole formation during the quantum collapse of a spherical dust shell. We define the quantum observable {theta}, corresponding to the classical trace of the expansion tensor, and calculate its expected value in order to obtain information about the geometry of space-time around the shell. We show that the local quantum geometry represents a wormhole. (Author)

On the possibility of wormhole formation due to quantum effects in the gravitational collapse of a small dust shell

International Nuclear Information System (INIS)

Cruz P, G.; Minzoni, A.; Padilla, P.; Rosenbaum, M.; Ryan, M.P. Jr.; Smyth, N.F.; Vukasinac, T.

2003-01-01

In the present note we outline the main steps towards the analysis of wormhole formation during the quantum collapse of a spherical dust shell. We define the quantum observable Θ, corresponding to the classical trace of the expansion tensor, and calculate its expected value in order to obtain information about the geometry of space-time around the shell. We show that the local quantum geometry represents a wormhole. (Author)

G 126.1-0.8-14: A molecular shell related to Sh2-187

Science.gov (United States)

Cichowolski, S.; Pineault, S.; Gamen, R.; Ortega, M. E.; Arnal, E. M.; Suad, L. A.

2014-10-01

We present a multi-wavelength study of a region where a well defined molecular shell, named G 126.1-0.8-14, is observed. The distance of G 126.1-0.8-14 is about 1 kpc. Based on HI and CO data we analyze the atomic and molecular gas related to the structure and estimate its main physical properties. From the radio continuum and infrared data we analyze whether the emission associated with G 126.1-0.8-14 has a thermal origin. To disentangle the possible origin of the shell, and given the lack of catalogued O-type stars in the area, we observed with GEMINI the spectra of four OB stars located in projection inside the shell, to get their accurate spectral types and distances. The young HII region Sh2-187 is located onto the densest part of this molecular shell. A search for young stellar object candidates (cYSOs) was made using infrared point source catalogs. Several cYSOs are found spread out onto the shell. Based on all the available data, we discuss the possible origin of G 126.1-0.8-14 as well as its role in the formation of a new generation of stars.

Shell supports

DEFF Research Database (Denmark)

Almegaard, Henrik

2004-01-01

A new statical and conceptual model for membrane shell structures - the stringer system - has been found. The principle was first published at the IASS conference in Copenhagen (OHL91), and later the theory has been further developed (ALMO3)(ALMO4). From the analysis of the stringer model it can...... be concluded that all membrane shells can be described by a limited number of basic configurations of which quite a few have free edges....

Yolk-Shell Porous Microspheres of Calcium Phosphate Prepared by Using Calcium L-Lactate and Adenosine 5'-Triphosphate Disodium Salt: Application in Protein/Drug Delivery.

Science.gov (United States)

Ding, Guan-Jun; Zhu, Ying-Jie; Qi, Chao; Sun, Tuan-Wei; Wu, Jin; Chen, Feng

2015-06-26

A facile and environmentally friendly approach has been developed to prepare yolk-shell porous microspheres of calcium phosphate by using calcium L-lactate pentahydrate (CL) as the calcium source and adenosine 5'-triphosphate disodium salt (ATP) as the phosphate source through the microwave-assisted hydrothermal method. The effects of the concentration of CL, the microwave hydrothermal temperature, and the time on the morphology and crystal phase of the product are investigated. The possible formation mechanism of yolk-shell porous microspheres of calcium phosphate is proposed. Hemoglobin from bovine red cells (Hb) and ibuprofen (IBU) are used to explore the application potential of yolk-shell porous microspheres of calcium phosphate in protein/drug loading and delivery. The experimental results indicate that the as-prepared yolk-shell porous microspheres of calcium phosphate have relatively high protein/drug loading capacity, sustained protein/drug release, favorable pH-responsive release behavior, and a high biocompatibility in the cytotoxicity test. Therefore, the yolk-shell porous microspheres of calcium phosphate have promising applications in various biomedical fields such as protein/drug delivery. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Computation of two-dimensional isothermal flow in shell-and-tube heat exchangers

International Nuclear Information System (INIS)

Carlucci, L.N.; Galpin, P.F.; Brown, J.D.; Frisina, V.

1983-07-01

A computational procedure is outlined whereby two-dimensional isothermal shell-side flow distributions can be calculated for tube bundles having arbitrary boundaries and flow blocking devices, such as sealing strips, defined in arbitrary locations. The procedure is described in some detail and several computed results are presented to illustrate the robustness and generality of the method

Thermal Limits and Thresholds of Red Sea Biota

KAUST Repository

Chaidez, Veronica

2018-01-01

tropical systems. This has major consequences for organisms that may already find themselves at their thermal limits. The aim of this project was to define the thermal limits and thresholds of certain Red Sea species. Firstly, to better understand

Low Cost CaTiO3 Perovskite Synthesized from Scallop (Anadara granosa) Shell as Antibacterial Ceramic Material

Science.gov (United States)

Fatimah, Is; Nur Ilahi, Rico; Pratami, Rismayanti

2018-01-01

Research on perovskite CaTiO3 synthesis from scallop (Anadara granosa) shell and its test as material for antibacterial ceramic application have been conducted. The synthesis was performed by calcium extraction from the scallop shell followed by solid-solid reaction of obtained calcium with TiO2. Physicochemical character of the perovskite wasstudied by measurement of crystallinity using x-ray diffraction (XRD), diffuse-reflectance UV Visible spectrophotometry, scanning electrone microscope-energy dispersive x-ray (SEM-EDX) and Fourier-Transform InfraRed. Considering the future application of the perovskite as antibacterial agent, laboratory test of the peroskite as material in antibacterial ceramic preparation was also conducted. Result of research indicated that perovskite formation was obtained and the material demonstrated photocatalytic activity as identified by band gap energy (Eg) value. The significant activity was also reflected by the antibacterial action of formed ceramic.

A refined element-based Lagrangian shell element for geometrically nonlinear analysis of shell structures

Directory of Open Access Journals (Sweden)

Woo-Young Jung

2015-04-01

Full Text Available For the solution of geometrically nonlinear analysis of plates and shells, the formulation of a nonlinear nine-node refined first-order shear deformable element-based Lagrangian shell element is presented. Natural co-ordinate-based higher order transverse shear strains are used in present shell element. Using the assumed natural strain method with proper interpolation functions, the present shell element generates neither membrane nor shear locking behavior even when full integration is used in the formulation. Furthermore, a refined first-order shear deformation theory for thin and thick shells, which results in parabolic through-thickness distribution of the transverse shear strains from the formulation based on the third-order shear deformation theory, is proposed. This formulation eliminates the need for shear correction factors in the first-order theory. To avoid difficulties resulting from large increments of the rotations, a scheme of attached reference system is used for the expression of rotations of shell normal. Numerical examples demonstrate that the present element behaves reasonably satisfactorily either for the linear or for geometrically nonlinear analysis of thin and thick plates and shells with large displacement but small strain. Especially, the nonlinear results of slit annular plates with various loads provided the benchmark to test the accuracy of related numerical solutions.

Connections between the dynamical symmetries in the microscopic shell model

Energy Technology Data Exchange (ETDEWEB)

Georgieva, A. I., E-mail: anageorg@issp.bas.bg [Institute of Solid State Physics, Bulgarian Academy of Sciences, Sofia 1784 (Bulgaria); Drumev, K. P. [Institute for Nuclear Research and Nuclear Energy, Bulgarian Academy of Sciences, Sofia 1784 (Bulgaria)

2016-03-25

The dynamical symmetries of the microscopic shell model appear as the limiting cases of a symmetry adapted Pairing-Plus-Quadrupole Model /PQM/, with a Hamiltonian containing isoscalar and isovector pairing and quadrupole interactions. We establish a correspondence between each of the three types of pairing bases and Elliott’s SU(3) basis, that describes collective rotation of nuclear systems with quadrupole deformation. It is derived from their complementarity to the same LS coupling chain of the shell model number conserving algebra. The probability distribution of the S U(3) basis states within the pairing eigenstates is also obtained through a numerical diagonalization of the PQM Hamiltonian in each limit. We introduce control parameters, which define the phase diagram of the model and determine the role of each term of the Hamiltonian in the correct reproduction of the experimental data for the considered nuclei.

Statistical Mechanics of Thin Spherical Shells

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Andrej Košmrlj

2017-01-01

Full Text Available We explore how thermal fluctuations affect the mechanics of thin amorphous spherical shells. In flat membranes with a shear modulus, thermal fluctuations increase the bending rigidity and reduce the in-plane elastic moduli in a scale-dependent fashion. This is still true for spherical shells. However, the additional coupling between the shell curvature, the local in-plane stretching modes, and the local out-of-plane undulations leads to novel phenomena. In spherical shells, thermal fluctuations produce a radius-dependent negative effective surface tension, equivalent to applying an inward external pressure. By adapting renormalization group calculations to allow for a spherical background curvature, we show that while small spherical shells are stable, sufficiently large shells are crushed by this thermally generated “pressure.” Such shells can be stabilized by an outward osmotic pressure, but the effective shell size grows nonlinearly with increasing outward pressure, with the same universal power-law exponent that characterizes the response of fluctuating flat membranes to a uniform tension.

Temporal structures in shell models

DEFF Research Database (Denmark)

Okkels, F.

2001-01-01

The intermittent dynamics of the turbulent Gledzer, Ohkitani, and Yamada shell-model is completely characterized by a single type of burstlike structure, which moves through the shells like a front. This temporal structure is described by the dynamics of the instantaneous configuration of the shell...

Expert system development (ESD) shell

International Nuclear Information System (INIS)

Padmini, S.; Diwakar, M.P.; Rathode, N.C.; Bairi, B.R.

1991-01-01

An Expert System Development (ESD) Shell design implementation is desribed in detail. The shell provides high-level generic facilities for Knowledge Representation (KR) and inferencing and tools for developing user interfaces. Powerful set of tools in the shell relieves much of the programming burden in the ES development. The shell is written in PROLOG under IBM PC/AT. KR facilities are based on two very powerful formalisms namely, frames and rules. Inference Engine (IE) draws most of its power from unification and backward reasoning strategy in PROLOG. This basic mechanism is enhanced further by incorporating both forward and backward chaining of rules and frame-based inferencing. Overall programming style integrates multiple paradigms including logic, object oriented, access-oriented and imperative programming. This permits ES designer a lot of flexibility in organizing inference control. Creation and maintainance of knowledge base is a major activity. The shell, therefore, provides number of facilities to simplify these tasks. Shell design also takes note of the fact that final success of any system depends on end-user satisfaction and hence provides features to build use-friendly interfaces. The shell also provides a set of interfacing predicates so that it can be embedded within any PROLOG program to incorporate functionalilty of the shell in the user program. (author). 10 refs., 8 figs

Design of reinforced concrete plates and shells

International Nuclear Information System (INIS)

Schulz, M.

1984-01-01

Nowadays, the internal forces of reinforced concrete laminar structures can be easily evaluated by the finite element procedures. The longitudinal design in each direction is not adequate, since the whole set of internal forces in each point must be concomitantly considered. The classic formulation for the design and new design charts which bring reduction of the amount of necessary reinforcement are presented. A rational reinforced concrete mathematical theory which makes possible the limit state design of plates and shells is discussed. This model can also be applied to define the constitutive relationships of laminar finite elements of reinforced concrete. (Author) [pt

Structural Control of InP/ZnS Core/Shell Quantum Dots Enables High-quality White LEDs.

Science.gov (United States)

Ganesh Kumar, Baskaran; Sadeghi, Sadra; Melikov, Rustamzhon; Mohammadi Aria, Mohammed; Bahmani Jalali, Houman; Ow-Yang, Cleva; Nizamoglu, Sedat

2018-05-30

Herein, we demonstrate that the structural and optical control of InP-based quantum dots can lead to high-performance LEDs. Zinc sulphide (ZnS) shells passivate the InP quantum dot core and increase the quantum yield in green-emitting quantum dots by 13-fold and red-emitting quantum dots by 8-fold. The optimised quantum dots are integrated in the liquid-state to eliminate aggregation induced emission quenching and we fabricated white LEDs with warm, neutral, and cool white appearance by the down-conversion mechanism. The quantum dot-functionalized white LEDs achieve luminous efficiency up to 14.7 lm/W and colour-rendering index up to 80. The structural and optical control of InP/ZnS core/shell quantum dots enable 23-fold enhancement in luminous efficiency of white LEDs compared to ones containing only QDs of InP core. © 2018 IOP Publishing Ltd.

Design aids for stiffened composite shells with cutouts

CERN Document Server

Sahoo, Sarmila

2017-01-01

This book focuses on the free vibrations of graphite-epoxy laminated composite stiffened shells with cutout both in terms of the natural frequencies and mode shapes. The dynamic analysis of shell structures, which may have complex geometry and arbitrary loading and boundary conditions, is solved efficiently by the finite element method, even including cutouts in shells. The results may be readily used by practicing engineers dealing with stiffened composite shells with cutouts. Several shell forms viz. cylindrical shell, hypar shell, conoidal shell, spherical shell, saddle shell, hyperbolic paraboloidal shell and elliptic paraboloidal shell are considered in the book. The dynamic characteristics of stiffened composite shells with cutout are described in terms of the natural frequency and mode shapes. The size of the cutouts and their positions with respect to the shell centre are varied for different edge constraints of cross-ply and angle-ply laminated composite shells. The effects of these parametric variat...

Activated carbons prepared from hazelnut shells, walnut shells and peanut shells for high CO2 adsorption

Directory of Open Access Journals (Sweden)

Lewicka Katarzyna

2017-06-01

Full Text Available Research treats about producing activated carbons for CO2 capture from hazelnut shells (HN, walnut shells (WN and peanut shells (PN. Saturated solution of KOH was used as an activating agent in ratio 1:1. Samples were carbonized in the furnace in the range of temperatures 600°C–900°C. Properties of carbons were tested by N2 adsorption method, using BET equation, DFT method and volumetric CO2 adsorption method. With the increase of carbonization temperature specific surface area of studied samples increased. The largest surface area was calculated for samples carbonized at 900°C and the highest values of CO2 adsorption had samples: PN900 at 0°C (5.5 mmol/g and WN900 at 25°C (4.34 mmol/g. All of the samples had a well-developed microporous structure.

Alternating current dielectrophoresis of core-shell nanoparticles: Experiments and comparison with theory

Science.gov (United States)

Yang, Chungja

Nanoparticles are fascinating where physical and optical properties are related to size. Highly controllable synthesis methods and nanoparticle assembly are essential for highly innovative technological applications. Well-defined shaped and sized nanoparticles enable comparisons between experiments, theory and subsequent new models to explain experimentally observed phenomena. Among nanoparticles, nonhomogeneous core-shell nanoparticles (CSnp) have new properties that arise when varying the relative dimensions of the core and the shell. This CSnp structure enables various optical resonances, and engineered energy barriers, in addition to the high charge to surface ratio. Assembly of homogeneous nanoparticles into functional structures has become ubiquitous in biosensors (i.e. optical labeling), nanocoatings, and electrical circuits. Limited nonhomogenous nanoparticle assembly has only been explored. Many conventional nanoparticle assembly methods exist, but this work explores dielectrophoresis (DEP) as a new method. DEP is particle polarization via non-uniform electric fields while suspended in conductive fluids. Most prior DEP efforts involve microscale particles. Prior work on core-shell nanoparticle assemblies and separately, nanoparticle characterizations with dielectrophoresis and electrorotation, did not systematically explore particle size, dielectric properties (permittivity and electrical conductivity), shell thickness, particle concentration, medium conductivity, and frequency. This work is the first, to the best of our knowledge, to systematically examine these dielectrophoretic properties for core-shell nanoparticles. Further, we conduct a parametric fitting to traditional core-shell models. These biocompatible core-shell nanoparticles were studied to fill a knowledge gap in the DEP field. Experimental results (chapter 5) first examine medium conductivity, size and shell material dependencies of dielectrophoretic behaviors of spherical CSnp into 2D and

Rhythmic patterns in ancient shells: Can we reconstruct sub-annual cyclicity in trace element and stable isotope profiles from rudist bivalves?

Science.gov (United States)

de Winter, N.; Sinnesael, M.; Vansteenberge, S.; Goderis, S.; Snoeck, C.; Van Malderen, S. J. M.; Vanhaecke, F. F.; Claeys, P.

2017-12-01

Well-preserved shells of Torreites rudists from the Late Campanian Saiwan Formation in Oman exhibit fine internal layering. These fine (±20 µm) laminae are rhythmically bundled (±400 µm) and subdivide the shells' larger scale annual lamination (±15 mm), suggesting the presence of several interfering cycles in shell growth rate. The aim of the present study is to determine the duration and chemical signature of these rhythmic variations in shell composition. To achieve this, a range of micro-analytical techniques is applied on cross sections through the shells. Firstly, microscopy-based layer counting and colorimetric analysis are carried out on thin sections of shell calcite. Secondly, X-Ray Fluorescence (XRF) and Fourier Transform InfraRed (FTIR) mapping of cross sections of the shells reveal chemical and structural differences between laminae in 2D. Thirdly, high-resolution XRF (25 µm) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS; 10 µm) trace element profiles are used to quantify variations in chemical composition between shell laminae. Fourthly, annual chronology is established based on micro-sampled stable carbon and oxygen stable isotope measurements (250 µm) along the growth axis of the shells. Finally, spectral analysis routines are applied to extract rhythmic patterns matched to the shell laminae from the structural, chemical and colorimetric data. Combining these methods allows for a full evaluation of the structural and chemical characteristics as well as the timing of sub-annual lamination in rudist shells. The results of this study shed light on the external factors that influenced growth rates in rudist bivalves. A better understanding of the timing of deposition of these laminae allows them to be used to improve age models of geochemical records in rudist shells. Characterization of small scale variations in shell composition will characterize the uncertainties contained within lower resolution proxy records from

Monodisperse colloidal spheres for (Y,Eu2O3 red-emitting phosphors: establishment of processing window and size-dependent luminescence behavior

Directory of Open Access Journals (Sweden)

Qi Zhu, Ji-Guang Li, Xiaodong Li, Xudong Sun and Yoshio Sakka

2011-01-01

Full Text Available The urea-based homogeneous precipitation method was introduced in the preparation of monodisperse colloidal spheres for (Y0.95Eu0.052O3 red-emitting phosphors, and the processing window was defined. Particle size and shape are significantly affected by the ion concentration and the urea/RE3+ molar ratio R (RE3+=Y3++Eu3+. A low ion concentration is beneficial in forming monodisperse spheres and extending their formation domain. Increasing R results in a gradual change in the composition of spherical particles from the core-shell Eu(OHCO3@Y(OHCO3 structure to a homogeneous solid solution, thereby significantly lowering the calcination temperature at which precursors convert to oxides. Upon UV excitation into the charge-transfer band at 254 nm, the uniform phosphor spheres of (Y0.95Eu0.052O3 exhibit typical red emissions at 613 nm; the emission is stronger from larger particles mainly because of their smaller surface area. Both the luminescence intensity and quantum efficiency of the oxide phosphors increase with elevated calcination temperatures. The spherical shape and excellent dispersion of the precursor particles (~450 nm in diameter have been well retained after calcination at 1000 circleC for 4 h, and the resultant oxide phosphors exhibit external and internal quantum efficiencies of 50 and 82%, respectively.

Synthesis and Plasmonic Understanding of Core/Satellite and Core Shell Nanostructures

Science.gov (United States)

Ruan, Qifeng

Au nanospheres with molecular linkers. The plasmon resonances of the core/satellite nanostructures undergo red shifts in comparison to those of the sole Au cores, which is consistent with Mie theory analysis. As predicted by finite-difference time-domain simulations, the assembled core/satellite nanostructures exhibit large enhancements for Raman scattering. The facile growth of Au nanospheres and assembly of core/satellite nanostructures blaze a new way to the design of nanoarchitectures with desired plasmonic properties and functions. Coating semiconductors onto Au nanocrystals to form core shell configurations can increase the interactions between the two materials, benefiting from their large active interfacial area. The shell can also protect the Au nanocrystal core from aggregation, reshaping, and chemical corrosion. In this thesis, (Au nanocrystal core) (titania shell) nanostructures with tunable shell thicknesses were prepared by a facile wetchemistry method. Au nanocrystals with strong and tunable plasmon resonances in the visible and near-infrared regions can enhance and broaden the light utilization of TiO2 through the scattering/absorption enhancement, sensitization, and hot-electron injection. The integration of Au nanocrystals therefore hold the prospect of breaking the light-harvesting limit of TiO2 arising from its wide band gap. The resultant (Au core) (TiO2 shell) nanostructures were examined to be capable of efficiently generating reactive oxygen species under near-infrared resonant excitation. On the other hand, the transverse plasmon modes of Au nanorods, which are often too weak to be observed on scattering spectra, are enhanced by the TiO2 shell through energy transfer. With the increment of the shell thickness, the intensity of the transverse plasmon mode increases significantly and even becomes comparable with the longitudinal plasmon mode. Interestingly, both the transverse and longitudinal modes of the (Au core) (TiO2 shell) nanostructures

Mission analysis report for single-shell tank leakage mitigation

International Nuclear Information System (INIS)

Cruse, J.M.

1994-01-01

This document provides an analysis of the leakage mitigation mission applicable to past and potential future leakage from the Hanford Site's 149 single-shell high-level waste tanks. This mission is a part of the overall missions of the Westinghouse Hanford Company Tank Waste Remediation System division to remediate the tank waste in a safe and acceptable manner. Systems engineers principles are being applied to this effort. Mission analysis supports early decision making by clearly defining program objectives. This documents identifies the initial conditions and acceptable final conditions, defines the programmatic and physical interfaces and constraints, estimates the resources to carry out the mission, and establishes measures of success. The results of the mission analysis provide a consistent basis for subsequent systems engineering work

Tuning upconversion through energy migration in core-shell nanoparticles

KAUST Repository

Wang, Feng; Deng, Renren; Wang, Juan; Wang, Qingxiao; Han, Yu; Zhu, Haomiao; Chen, Xueyuan; Liu, Xiaogang

2011-01-01

Photon upconversion is promising for applications such as biological imaging, data storage or solar cells. Here, we have investigated upconversion processes in a broad range of gadolinium-based nanoparticles of varying composition. We show that by rational design of a core-shell structure with a set of lanthanide ions incorporated into separated layers at precisely defined concentrations, efficient upconversion emission can be realized through gadolinium sublattice-mediated energy migration for a wide range of lanthanide activators without long-lived intermediary energy states. Furthermore, the use of the core-shell structure allows the elimination of deleterious cross-relaxation. This effect enables fine-tuning of upconversion emission through trapping of the migrating energy by the activators. Indeed, the findings described here suggest a general approach to constructing a new class of luminescent materials with tunable upconversion emissions by controlled manipulation of energy transfer within a nanoscopic region. © 2011 Macmillan Publishers Limited. All rights reserved.

Tuning upconversion through energy migration in core-shell nanoparticles

KAUST Repository

Wang, Feng

2011-10-23

Photon upconversion is promising for applications such as biological imaging, data storage or solar cells. Here, we have investigated upconversion processes in a broad range of gadolinium-based nanoparticles of varying composition. We show that by rational design of a core-shell structure with a set of lanthanide ions incorporated into separated layers at precisely defined concentrations, efficient upconversion emission can be realized through gadolinium sublattice-mediated energy migration for a wide range of lanthanide activators without long-lived intermediary energy states. Furthermore, the use of the core-shell structure allows the elimination of deleterious cross-relaxation. This effect enables fine-tuning of upconversion emission through trapping of the migrating energy by the activators. Indeed, the findings described here suggest a general approach to constructing a new class of luminescent materials with tunable upconversion emissions by controlled manipulation of energy transfer within a nanoscopic region. © 2011 Macmillan Publishers Limited. All rights reserved.

Dyson shells: a retrospective

Science.gov (United States)

Bradbury, Robert J.

2001-08-01

More than 40 years have passed since Freeman Dyson suggested that advanced technological civilizations are likely to dismantle planets in their solar systems to harvest all of the energy their stars wastefully radiate into space. Clearly this was an idea that was ahead of its time. Since that time, dozens of SETI searches have been conducted and almost all of them have focused their attention on stars which by definition cannot be the advanced civilizations that Dyson envisioned. I will review the data that created the confusion between Dyson spheres and Dyson shells. The sources that disprove Dyson spheres while still allowing Dyson shells will be discussed. The use of outmoded ideas that have biased the few searches for Dyson Shells that have occurred will be pointed out. An update of the concept of Dyson shells to include our current knowledge of biotechnology, nanotechnology and computer science will be explored. Finally, an approach to setting limits on the abundance of Dyson shells in our galaxy using existing optical astronomical data and future optical satellites will be proposed.

Mussel Shell Impaction in the Esophagus

Directory of Open Access Journals (Sweden)

Sunmin Kim

2013-03-01

Full Text Available Mussels are commonly used in cooking around the world. The mussel shell breaks more easily than other shells, and the edge of the broken mussel shell is sharp. Impaction can ultimately cause erosion, perforation and fistula. Aside from these complications, the pain can be very intense. Therefore, it is essential to verify and remove the shell as soon as possible. In this report we describe the process of diagnosing and treating mussel shell impaction in the esophagus. Physicians can overlook this unusual foreign body impaction due to lack of experience. When physicians encounter a patient with severe chest pain after a meal with mussels, mussel shell impaction should be considered when diagnosing and treating the patient.

Image analysis method to quantify the effect of different treatments on the visual meat/shell ratio of half-shelled green lipped mussels (Perna canaliculus).

Science.gov (United States)

Kim, Min Geun; Alçiçek, Zayde; Balaban, Murat O; Atar, Hasan Huseyin

2014-04-01

Aquacultured green lipped mussel (Perna canaliculus) is the New Zealand export leader of seafood in terms of weight. Different treatments shrink mussel meat differently and affect the consumer perception of half-shelled mussels. In order to quantify this, digital images of half-shelled green lipped mussels subjected to two postharvest treatments (ultrahigh pressure (UHP) and heat treatment (HT)) and raw controls were taken. The ratio of the view area of the meat to that of the shell (labelled as 'visual condition index' (VCI)) was measured using image analysis. A polygonal region of interest was defined on the image to depict the boundary of the meat and to calculate the view area. Raw mussels had a VCI of 85%. HT mussels had a much reduced VCI of 41%, indicating shrinkage of the meat due to heat. UHP treatment used as a shucking method resulted in a VCI of 83%. Since VCI is one measure of quality for the consumer, this quantitative method can be used in the optimization of shucking treatment (HT or UHP). VCI can be used to optimize postharvest treatments to minimize meat shrinkage. This method can also be applied to other shellfish such as oysters and clams. © 2013 Society of Chemical Industry.

Mg/Ca of Continental Ostracode Shells

Science.gov (United States)

Ito, E.; Forester, R. M.; Marco-Barba, J.; Mezquita, F.

2007-12-01

low. The water bodies near Valencia, Spain, range from 200mg/L to 65g/L with both [Mg] and [Ca] increasing with TDS, but at different rates because of carbonate precipitation. The lowest Mg/Ca was 0.5 in a dilute spring and the highest 6.5 in an evaporation pond with temperature at all sites being similar and highly variable. The observed Mg/Ca of the shells from all sites was generally between 0.005 and 0.025, but at any one site the range was only about 0.01 even at sites with monthly data for a full year, so capturing a wider range of temperature. So, unlike the first example, the low Mg/Ca range at individual sites seems to preclude defining a shell Mg temperature relation. In fact, the data show that very different TDS and different solute Mg/Ca result in a narrow range of shell Mg/Ca, as though ,C. torosa lived at a site with low temperature variability. Of interest, calculation of shell metal distribution coefficients, Kd, shows it goes from 0.025 for the dilute water to 0.005 for saline waters indicating that Kd is TDS dependent at these sites because the solutes all lie on a single solute evolution trend. These examples illustrate what can happen if ionic chemistry and TDS of seawater changes on glacial to interglacial or longer timescales, or if the same thermometer is applied to coastal settings. Palacios-Fest, M.R., and Dettman, D.L., 2001, Geochimica et Cosmochimica Acta, v. 65, p. 2499-2507.

Plate shell structures of glass

DEFF Research Database (Denmark)

Bagger, Anne

to their curved shape. A plate shell structure maintains a high stiffness-to-weight ratio, while facilitating the use of plane structural elements. The study focuses on using laminated glass panes for the load bearing facets. Various methods of generating a plate shell geometry are suggested. Together with Ghent......, such as facet size, imperfections, and connection characteristics. The critical load is compared to that of a similar, but smoothly curved, shell structure. Based on the investigations throughout the study, a set of guidelines for the structural design of plate shells of glass is proposed....

Analysis Bounding Double Shell Tank (DST) Performance for the Hanford Tank Waste Operation Simulator Case 2

International Nuclear Information System (INIS)

SMITH, D.F.

2002-01-01

The purpose of this analysis is to compare the latest Tank Farm Contractor Operation and Utilization Plan (HNF-SD-WM-SP-012, Rev. 3) ''Case 2'' operating scenarios with a previous bounding analysis for the Double-Shell Tank (DST) System in order to provide a technical assessment against the current set of DST System performance requirements. A later update to HNF-SD-WM-SP-012 (i.e., Rev. 3A), released in late December 2001, did not impact the results of this analysis. This analysis provides technical support for revising the Performance Requirements for the Double-Shell Tank System, HNF-2168, Rev. 3, used as the basis for defining performance requirements noted in System Specification for the Double-Shell Tank System, HNF-SD-WM-TRD-007. Rev. 1

Optimised photocatalytic hydrogen production using core–shell AuPd promoters with controlled shell thickness

DEFF Research Database (Denmark)

Jones, Wilm; Su, Ren; Wells, Peter

2014-01-01

of these materials towards the reforming of alcohols for hydrogen production. The core–shell structured Au–Pd bimetallic nanoparticle supported on TiO2 has being of interest as it exhibited extremely high quantum efficiencies for hydrogen production. However, the effect of shell composition and thickness...... of the nanoparticles by a combination of X-ray absorption fine structure and X-ray photoelectron spectroscopy. Photocatalytic ethanol reforming showed that the core–shell structured Au–Pd promoters supported on TiO2 exhibit enhanced activity compared to that of monometallic Au and Pd as promoters, whilst the core......–shell Au–Pd promoters containing one ML equivalent Pd provide the optimum reactivity....

Nanostructued core–shell Sn nanowires @ CNTs with controllable thickness of CNT shells for lithium ion battery

Energy Technology Data Exchange (ETDEWEB)

Zhong, Yu; Li, Xifei; Zhang, Yong; Li, Ruying [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada); Cai, Mei [General Motors Research and Development Center, Warren, MI 48090-9055 (United States); Sun, Xueliang, E-mail: xsun@eng.uwo.ca [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada)

2015-03-30

Graphical abstract: - Highlights: • Sn nanowires encapsulated in CNTs directly grew on current collectors. • The thickness of CNTs were controlled via growth time, gas flow rate and synthesis temperature. • Thick CNTs contributed to a better capacity retention while thin CNTs led to a higher capacity. • The core–shell structures formed in one-step CVD process. - Abstract: Core–shell structure of Sn nanowires encapsulated in amorphous carbon nanotubes (Sn@CNTs) with controlled thickness of CNT shells was in situ prepared via chemical vapor deposition (CVD) method. The thickness of CNT shells was accurately controlled from 4 to 99 nm by using different growth time, flow rate of hydrocarbon gas (C{sub 2}H{sub 4}) and synthesis temperature. The microstructure and composition of the coaxial Sn@CNTs were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and high resolution transmission electron microscopy (HRTEM) techniques. Moreover, the Sn@CNTs were studied as anode materials for Li-ion batteries and showed excellent cycle performance. The capacity was affected by the thickness of outer CNT shells: thick CNT shells contributed to a better retention while thin CNT shells led to a higher capacity. The thin CNT shell of 6 nm presented the highest capacity around 630 mAh g{sup −1}.

Nanostructued core–shell Sn nanowires @ CNTs with controllable thickness of CNT shells for lithium ion battery

International Nuclear Information System (INIS)

Zhong, Yu; Li, Xifei; Zhang, Yong; Li, Ruying; Cai, Mei; Sun, Xueliang

2015-01-01

Graphical abstract: - Highlights: • Sn nanowires encapsulated in CNTs directly grew on current collectors. • The thickness of CNTs were controlled via growth time, gas flow rate and synthesis temperature. • Thick CNTs contributed to a better capacity retention while thin CNTs led to a higher capacity. • The core–shell structures formed in one-step CVD process. - Abstract: Core–shell structure of Sn nanowires encapsulated in amorphous carbon nanotubes (Sn@CNTs) with controlled thickness of CNT shells was in situ prepared via chemical vapor deposition (CVD) method. The thickness of CNT shells was accurately controlled from 4 to 99 nm by using different growth time, flow rate of hydrocarbon gas (C 2 H 4 ) and synthesis temperature. The microstructure and composition of the coaxial Sn@CNTs were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and high resolution transmission electron microscopy (HRTEM) techniques. Moreover, the Sn@CNTs were studied as anode materials for Li-ion batteries and showed excellent cycle performance. The capacity was affected by the thickness of outer CNT shells: thick CNT shells contributed to a better retention while thin CNT shells led to a higher capacity. The thin CNT shell of 6 nm presented the highest capacity around 630 mAh g −1

Extensions to a nonlinear finite element axisymmetric shell model based on Reissner's shell theory

International Nuclear Information System (INIS)

Cook, W.A.

1981-01-01

A finite element shell-of-revolution model has been developed to analyze shipping containers under severe impact conditions. To establish the limits for this shell model, I studied the basic assumptions used in its development; these are listed in this paper. Several extensions were evident from the study of these limits: a thick shell, a plastic hinge, and a linear normal stress. (orig./HP)

Single-shell tank interim stabilization project plan

Energy Technology Data Exchange (ETDEWEB)

Ross, W.E.

1998-03-27

Solid and liquid radioactive waste continues to be stored in 149 single-shell tanks at the Hanford Site. To date, 119 tanks have had most of the pumpable liquid removed by interim stabilization. Thirty tanks remain to be stabilized. One of these tanks (C-106) will be stabilized by retrieval of the tank contents. The remaining 29 tanks will be interim stabilized by saltwell pumping. In the summer of 1997, the US Department of Energy (DOE) placed a moratorium on the startup of additional saltwell pumping systems because of funding constraints and proposed modifications to the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) milestones to the Washington State Department of Ecology (Ecology). In a letter dated February 10, 1998, Final Determination Pursuant to Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) in the Matter of the Disapproval of the DOE`s Change Control Form M-41-97-01 (Fitzsimmons 1998), Ecology disapproved the DOE Change Control Form M-41-97-01. In response, Fluor Daniel Hanford, Inc. (FDH) directed Lockheed Martin Hanford Corporation (LNMC) to initiate development of a project plan in a letter dated February 25, 1998, Direction for Development of an Aggressive Single-Shell Tank (SST) Interim Stabilization Completion Project Plan in Support of Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement). In a letter dated March 2, 1998, Request for an Aggressive Single-Shell Tank (SST) Interim Stabilization Completion Project Plan, the DOE reaffirmed the need for an aggressive SST interim stabilization completion project plan to support a finalized Tri-Party Agreement Milestone M-41 recovery plan. This project plan establishes the management framework for conduct of the TWRS Single-Shell Tank Interim Stabilization completion program. Specifically, this plan defines the mission needs and requirements; technical objectives and approach; organizational structure, roles, responsibilities

Single-shell tank interim stabilization project plan

International Nuclear Information System (INIS)

Ross, W.E.

1998-01-01

Solid and liquid radioactive waste continues to be stored in 149 single-shell tanks at the Hanford Site. To date, 119 tanks have had most of the pumpable liquid removed by interim stabilization. Thirty tanks remain to be stabilized. One of these tanks (C-106) will be stabilized by retrieval of the tank contents. The remaining 29 tanks will be interim stabilized by saltwell pumping. In the summer of 1997, the US Department of Energy (DOE) placed a moratorium on the startup of additional saltwell pumping systems because of funding constraints and proposed modifications to the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) milestones to the Washington State Department of Ecology (Ecology). In a letter dated February 10, 1998, Final Determination Pursuant to Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) in the Matter of the Disapproval of the DOE's Change Control Form M-41-97-01 (Fitzsimmons 1998), Ecology disapproved the DOE Change Control Form M-41-97-01. In response, Fluor Daniel Hanford, Inc. (FDH) directed Lockheed Martin Hanford Corporation (LNMC) to initiate development of a project plan in a letter dated February 25, 1998, Direction for Development of an Aggressive Single-Shell Tank (SST) Interim Stabilization Completion Project Plan in Support of Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement). In a letter dated March 2, 1998, Request for an Aggressive Single-Shell Tank (SST) Interim Stabilization Completion Project Plan, the DOE reaffirmed the need for an aggressive SST interim stabilization completion project plan to support a finalized Tri-Party Agreement Milestone M-41 recovery plan. This project plan establishes the management framework for conduct of the TWRS Single-Shell Tank Interim Stabilization completion program. Specifically, this plan defines the mission needs and requirements; technical objectives and approach; organizational structure, roles, responsibilities

Material Distribution Optimization for the Shell Aircraft Composite Structure

Science.gov (United States)

Shevtsov, S.; Zhilyaev, I.; Oganesyan, P.; Axenov, V.

2016-09-01

One of the main goal in aircraft structures designing isweight decreasing and stiffness increasing. Composite structures recently became popular in aircraft because of their mechanical properties and wide range of optimization possibilities.Weight distribution and lay-up are keys to creating lightweight stiff strictures. In this paperwe discuss optimization of specific structure that undergoes the non-uniform air pressure at the different flight conditions and reduce a level of noise caused by the airflowinduced vibrations at the constrained weight of the part. Initial model was created with CAD tool Siemens NX, finite element analysis and post processing were performed with COMSOL Multiphysicsr and MATLABr. Numerical solutions of the Reynolds averaged Navier-Stokes (RANS) equations supplemented by k-w turbulence model provide the spatial distributions of air pressure applied to the shell surface. At the formulation of optimization problem the global strain energy calculated within the optimized shell was assumed as the objective. Wall thickness has been changed using parametric approach by an initiation of auxiliary sphere with varied radius and coordinates of the center, which were the design variables. To avoid a local stress concentration, wall thickness increment was defined as smooth function on the shell surface dependent of auxiliary sphere position and size. Our study consists of multiple steps: CAD/CAE transformation of the model, determining wind pressure for different flow angles, optimizing wall thickness distribution for specific flow angles, designing a lay-up for optimal material distribution. The studied structure was improved in terms of maximum and average strain energy at the constrained expense ofweight growth. Developed methods and tools can be applied to wide range of shell-like structures made of multilayered quasi-isotropic laminates.

Core-Shell-Corona Micelles with a Responsive Shell.

Science.gov (United States)

Gohy, Jean-François; Willet, Nicolas; Varshney, Sunil; Zhang, Jian-Xin; Jérôme, Robert

2001-09-03

A reactor for the synthesis of gold nanoparticles is one of the uses of a poly(styrene)-block-poly(2-vinylpyridine)-block-poly(ethylene oxide) triblock copolymer (PS-b-P2VP-b-PEO) which forms core-shell-corona micelles in water. Very low polydispersity spherical micelles are observed that consist of a PS core surrounded by a pH-sensitive P2VP shell and a corona of PEO chains end-capped by a hydroxyl group. The corona can act as a site for attaching responsive or sensing molecules. © 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Dark-red-emitting CdTe{sub 0.5}Se{sub 0.5}/Cd{sub 0.5}Zn{sub 0.5}S quantum dots: Effect of chemicals on properties

Energy Technology Data Exchange (ETDEWEB)

Yang, Ping, E-mail: mse_yangp@ujn.edu.cn; Zhang, Aiyu; Li, Xiaoyu; Liu, Ning; Zhang, Yulan; Zhang, Ruili

2013-08-15

CdTe{sub 0.5}Se{sub 0.5}/Cd{sub 0.5}Zn{sub 0.5}S core/shell quantum dots (QDs) with a tunable photoluminescence (PL) range from yellow to dark red (up to a PL peak wavelength of 683 nm) were fabricated using various reaction systems. The core/shell QDs created in the reaction solution of trioctylamine (TOA) and oleic acid (OA) at 300 °C exhibited narrow PL spectra and a related low PL efficiency (38%). In contrast, the core/shell QDs prepared in the solution of 1-octadecene (ODE) and hexadecylamine (HDA) at 200 °C revealed a high PL efficiency (70%) and broad PL spectra. This phenomenon is ascribed that the precursor of Cd, reaction temperature, solvents, and ligands affected the formation process of the shell. The slow growth rate of the shell in the solution of ODE and HDA made QDs with a high PL efficiency. Metal acetate salts without reaction with HDA led to the core/shell QDs with a broad size distribution. - Graphical abstract: CdTe{sub 0.5}Se{sub 0.5}/Cd{sub 0.5}Zn{sub 0.5}S quantum dots (QDs) with tunable photoluminescence, high PL efficiency, and high stability through organic synthesis, in which chemicals affected the properties of the QDs. Display Omitted - Highlights: • CdTe{sub 0.5}Se{sub 0.5}/Cd{sub 0.5}Zn{sub 0.5}S quantum dots created via organic synthesis. • Chemicals affected the properties of the quantum dots. • The quantum dots revealed high photoluminescence efficiency and stability. • The quantum dots with tunable photoluminescence in a range from yellow to dark red. • The QDs are utilizable for various applications such as biological labeling.

Biomineral repair of abalone shell apertures.

Science.gov (United States)

Cusack, Maggie; Guo, Dujiao; Chung, Peter; Kamenos, Nicholas A

2013-08-01

The shell of the gastropod mollusc, abalone, is comprised of nacre with an outer prismatic layer that is composed of either calcite or aragonite or both, depending on the species. A striking characteristic of the abalone shell is the row of apertures along the dorsal margin. As the organism and shell grow, new apertures are formed and the preceding ones are filled in. Detailed investigations, using electron backscatter diffraction, of the infill in three species of abalone: Haliotis asinina, Haliotis gigantea and Haliotis rufescens reveals that, like the shell, the infill is composed mainly of nacre with an outer prismatic layer. The infill prismatic layer has identical mineralogy as the original shell prismatic layer. In H. asinina and H. gigantea, the prismatic layer of the shell and infill are made of aragonite while in H. rufescens both are composed of calcite. Abalone builds the infill material with the same high level of biological control, replicating the structure, mineralogy and crystallographic orientation as for the shell. The infill of abalone apertures presents us with insight into what is, effectively, shell repair. Copyright © 2013 Elsevier Inc. All rights reserved.

Polymorphism of CaCO{sub 3} and microstructure of the shell of a Brazilian invasive Mollusc (Limnoperna fortunei)

Energy Technology Data Exchange (ETDEWEB)

Nakamura Filho, Arnaldo; Almeida, Arthur Correa de; Riera, Hernan Espinoza; Cardoso, Antonio Valadao, E-mail: nakamuraaf@gmail.com [Rede Tematica em Engenharia de Materiais (REDEMAT), Ouro Preto, MG (Brazil); Araujo, Joao Locke Ferreira de [Centro de Bioengenharia de Especies Invasoras de Hidreletricas(CBEIH), Belo Horizonte, MG (Brazil); Gouveia, Vitor Jose Pinto [Fundacao Centro Tecnologico de Minas Gerais (CETEC), Belo Horizonte, MG (Brazil); Carvalho, Marcela David de [Companhia Energetica de Minas Gerais (CEMIG), Belo Horizonte, MG (Brazil)

2014-08-15

Applying the theories of Materials Science and Engineering to describe the composition and hierarchy of microstructures that comprise biological systems could help the search for new materials and results in a deeper insight into evolutionary processes. The layered microstructure that makes up the freshwater bivalve Limnoperna fortunei shell, an invasive specie in Brazil, was investigated utilizing SEM and AFM for the determination of the morphology and organization of the layers; and XRD was used to determine the crystalline phases of the calcium carbonate (CaCO{sub 3}) present in the shell. The presence of the polymorphs calcite and aragonite were confirmed and the calcite is present only on the external side of the shell. The shell of L. fortunei is composed of two layers of aragonite with distinct microstructures (the aragonite prismatic layer and the aragonite sheet nacreous layer) and the periostracum (a protein layer that covers and protects the ceramic part of the shell). A new morphology of the calcite layer was found, below the periostracum, without defined form, albeit crystal (author)

Thermal Limits and Thresholds of Red Sea Biota

KAUST Repository

Chaidez, Veronica

2018-05-01

As ocean temperatures continue to rise, the effect of temperature on marine organisms becomes highly relevant. The Red Sea is the warmest sea and is rapidly warming with current surface temperatures (28 – 34 °C) already exceeding those of most tropical systems. This has major consequences for organisms that may already find themselves at their thermal limits. The aim of this project was to define the thermal limits and thresholds of certain Red Sea species. Firstly, to better understand the thermal regimes of the Red Sea, we looked at decadal trends in maximum sea surface temperature across the basin. Then, we tested the thermal capacities of Red Sea mangroves and zooplankton, two key ecological groups, by performing thermal stress experiments in the laboratory. We found that the Red Sea basin is warming faster than the global average (0.17 °C decade-1), the thermal limit of mangrove propagules is between 33 and 35 °C, and the limits among the most common zooplankton groups range from 30 to 36 °C. This project gives us a better understanding of how organisms respond to extreme temperatures and how they may be affected in a future, warmer, ocean.

Double Shell Tank (DST) Process Waste Sampling Subsystem Definition Report

International Nuclear Information System (INIS)

RASMUSSEN, J.H.

2000-01-01

This report defines the Double-Shell Tank (DST) Process Waste Sampling Subsystem (PWSS). This subsystem definition report fully describes and identifies the system boundaries of the PWSS. This definition provides a basis for developing functional, performance, and test requirements (i.e., subsystem specification), as necessary, for the PWSS. The resultant PWSS specification will include the sampling requirements to support the transfer of waste from the DSTs to the Privatization Contractor during Phase 1 of Waste Feed Delivery

Porous Core-Shell Nanostructures for Catalytic Applications

Science.gov (United States)

Ewers, Trevor David

Porous core-shell nanostructures have recently received much attention for their enhanced thermal stability. They show great potential in the field of catalysis, as reactant gases can diffuse in and out of the porous shell while the core particle is protected from sintering, a process in which particles coalesce to form larger particles. Sintering is a large problem in industry and is the primary cause of irreversible deactivation. Despite the obvious advantages of high thermal stability, porous core-shell nanoparticles can be developed to have additional interactive properties from the combination of the core and shell together, rather than just the core particle alone. This dissertation focuses on developing new porous core-shell systems in which both the core and shell take part in catalysis. Two types of systems are explored; (1) yolk-shell nanostructures with reducible oxide shells formed using the Kirkendall effect and (2) ceramic-based porous oxide shells formed using sol-gel chemistry. Of the Kirkendall-based systems, Au FexOy and Cu CoO were synthesized and studied for catalytic applications. Additionally, ZnO was explored as a potential shelling material. Sol-gel work focused on optimizing synthetic methods to allow for coating of small gold particles, which remains a challenge today. Mixed metal oxides were explored as a shelling material to make dual catalysts in which the product of a reaction on the core particle becomes a reactant within the shell.

Ge/Si core/shell quantum dots in alumina: tuning the optical absorption by the core and shell size

Directory of Open Access Journals (Sweden)

Nekić Nikolina

2017-03-01

Full Text Available Ge/Si core/shell quantum dots (QDs recently received extensive attention due to their specific properties induced by the confinement effects of the core and shell structure. They have a type II confinement resulting in spatially separated charge carriers, the electronic structure strongly dependent on the core and shell size. Herein, the experimental realization of Ge/Si core/shell QDs with strongly tunable optical properties is demonstrated. QDs embedded in an amorphous alumina glass matrix are produced by simple magnetron sputtering deposition. In addition, they are regularly arranged within the matrix due to their self-assembled growth regime. QDs with different Ge core and Si shell sizes are made. These core/shell structures have a significantly stronger absorption compared to pure Ge QDs and a highly tunable absorption peak dependent on the size of the core and shell. The optical properties are in agreement with recent theoretical predictions showing the dramatic influence of the shell size on optical gap, resulting in 0.7 eV blue shift for only 0.4 nm decrease at the shell thickness. Therefore, these materials are very promising for light-harvesting applications.

Studies of dust shells around stars

International Nuclear Information System (INIS)

Bedijn, P.J.

1977-01-01

This thesis deals with some aspects of circumstellar dust shells. This dust shell, emitting infrared radiation, is described by way of its absorptive and emissive properties as well as by the transfer of radiation through the dust shell itself. Model calculations are compared to experimental results and agree reasonably well. The author also discusses the dynamics of the extended shells of gas and dust around newly formed stars

A Phosphine-Free Route to Size-Adjustable CdSe and CdSe/CdS Core-Shell Quantum Dots for White-Light-Emitting Diodes.

Science.gov (United States)

Zhang, Yugang; Li, Guopeng; Zhang, Ting; Song, Zihang; Wang, Hui; Zhang, Zhongping; Jiang, Yang

2018-03-01

The selenium dioxide was used as the precursor to synthesize wide-size-ranged CdSe quantum dots (2.4-5.7 nm) via hot-injection route. The CdSe quantum dots are featured with high crystalline, monodisperse, zinc blende structure and wide emission region (530-635 nm). In order to improve the stability and quantum yield, a phosphine-free single-molecular precursor approach is used to obtain CdSe/CdS core/shell quantum dots. The CdSe/CdS quantum dots are highly fluorescent with quantum yield up to 65%, and persist the good monodispersity and high crystallinity. Moreover, the quantum dots white light-emitting-diodes are fabricated by using the resultant red emission core/shell quantum dots and Y3Al5O12:Ce3+ yellow phosphors as color-conversion layers on a blue InGaN chip. The prepared light-emitting-diodes show good performance with CIE-1931 coordinated of (0.3583, 0.3349), an Ra of 92.9, and a Tc of 4410 K at 20 mA, which indicate that the combination of red-emission QDs and yellow phophors as a promising approach to obtain warm WLEDs with good color rendering.

Covarying Shell Growth Parameters and the Regulation of Shell Shape in Marine Bivalves: A Case Study on Tellinoidea

Directory of Open Access Journals (Sweden)

Jean Béguinot

2014-01-01

Full Text Available Specific parameters characterising shell shape may arguably have a significant role in the adaptation of bivalve molluscs to their particular environments. Yet, such functionally relevant shape parameters (shell outline elongation, dissymmetry, and ventral convexity are not those parameters that the animal may directly control. Rather than shell shape, the animal regulates shell growth. Accordingly, an alternative, growth-based description of shell-shape is best fitted to understand how the animal may control the achieved shell shape. The key point is, in practice, to bring out the link between those two alternative modes of shell-shape descriptions, that is, to derive the set of equations which connects the growth-based shell-shape parameters to the functionally relevant shell-shape parameters. Thus, a preliminary object of this note is to derive this set of equations as a tool for further investigations. A second object of this work is to provide an illustrative example of implementation of this tool. I report on an unexpected negative covariance between growth-based parameters and show how this covariance results in a severe limitation of the range of interspecific variability of the degree of ventral convexity of the shell outline within the superfamily Tellinoidea. Hypotheses are proposed regarding the constraints possibly at the origin of this limitation of interspecific variability.

Pressure Shell Approach to Integrated Environmental Protection

Science.gov (United States)

Kennedy, Kriss J.

2011-01-01

The next generation of exploration mission human systems will require environmental protection such as radiation protection that is effective and efficient. In order to continue human exploration, habitat systems will require special shells to protect astronauts from hostile environments. The Pressure Shell Approach to integrated environmental (radiation) protection is a multi-layer shell that can be used for multifunctional environmental protection. Self-healing, self-repairing nano technologies and sensors are incorporated into the shell. This shell consists of multiple layers that can be tailored for specific environmental protection needs. Mainly, this innovation focuses on protecting crew from exposure to micrometeorites, thermal, solar flares, and galactic cosmic ray (GCR) radiation. The Pressure Shell Approach consists of a micrometeoroid and secondary ejecta protection layer; a thin, composite shell placed in between two layers that is non-structural; an open cavity layer that can be filled with water, regolith, or polyethylene foam; a thicker composite shell that is a structural load bearing that is placed between two layers; and a bladder coating on the interior composite shell. This multi-layer shell creates an effective radiation protection system. Most of its layers can be designed with the materials necessary for specific environments. In situ materials such as water or regolith can be added to the shell design for supplemental radiation protection.

Engineered inorganic core/shell nanoparticles

Energy Technology Data Exchange (ETDEWEB)

Mélinon, Patrice, E-mail: patrice.melinon@univ-lyon1.fr [Institut Lumière matière Université Claude Bernard Lyon 1 et CNRS et OMNT, Domaine Scientifique de la Doua, Bâtiment Léon Brillouin, 43 Boulevard du 11 Novembre 1918, F 69622 Villeurbanne (France); Begin-Colin, Sylvie [IPCMS et OMNT, 23 rue du Loess BP 43, 67034 STRASBOURG Cedex 2 (France); Duvail, Jean Luc [IMN UMR 6502 et OMNT Campus Sciences : 2 rue de la Houssinire, BP32229, 44322 Nantes Cedex3 (France); Gauffre, Fabienne [SPM et OMNT : Institut des sciences chimiques de Rennes - UMR 6226, 263 Avenue du General Leclerc, CS 74205, 35042 RENNES Cedex (France); Boime, Nathalie Herlin [IRAMIS-NIMBE, Laboratoire Francis Perrin (CEA CNRS URA 2453) et OMNT, Bat 522, CEA Saclay, 91191 Gif sur Yvette Cedex (France); Ledoux, Gilles [Institut Lumière Matière Université Claude Bernard Lyon 1 et CNRS et OMNT, Domaine Scientifique de la Doua, Bâtiment Alfred Kastler 43 Boulevard du 11 Novembre 1918 F 69622 Villeurbanne (France); Plain, Jérôme [Universit de technologie de Troyes LNIO-ICD, CNRS et OMNT 12 rue Marie Curie - CS 42060 - 10004 Troyes cedex (France); Reiss, Peter [CEA Grenoble, INAC-SPrAM, UMR 5819 CEA-CNRS-UJF et OMNT, Grenoble cedex 9 (France); Silly, Fabien [CEA, IRAMIS, SPEC, TITANS, CNRS 2464 et OMNT, F-91191 Gif sur Yvette (France); Warot-Fonrose, Bénédicte [CEMES-CNRS, Université de Toulouse et OMNT, 29 rue Jeanne Marvig F 31055 Toulouse (France)

2014-10-20

It has been for a long time recognized that nanoparticles are of great scientific interest as they are effectively a bridge between bulk materials and atomic structures. At first, size effects occurring in single elements have been studied. More recently, progress in chemical and physical synthesis routes permitted the preparation of more complex structures. Such structures take advantages of new adjustable parameters including stoichiometry, chemical ordering, shape and segregation opening new fields with tailored materials for biology, mechanics, optics magnetism, chemistry catalysis, solar cells and microelectronics. Among them, core/shell structures are a particular class of nanoparticles made with an inorganic core and one or several inorganic shell layer(s). In earlier work, the shell was merely used as a protective coating for the core. More recently, it has been shown that it is possible to tune the physical properties in a larger range than that of each material taken separately. The goal of the present review is to discuss the basic properties of the different types of core/shell nanoparticles including a large variety of heterostructures. We restrict ourselves on all inorganic (on inorganic/inorganic) core/shell structures. In the light of recent developments, the applications of inorganic core/shell particles are found in many fields including biology, chemistry, physics and engineering. In addition to a representative overview of the properties, general concepts based on solid state physics are considered for material selection and for identifying criteria linking the core/shell structure and its resulting properties. Chemical and physical routes for the synthesis and specific methods for the study of core/shell nanoparticle are briefly discussed.

Synthesis, structural characterization and dielectric properties of Nb doped BaTiO3/SiO2 core–shell heterostructure

International Nuclear Information System (INIS)

Cernea, M.; Vasile, B.S.; Boni, A.; Iuga, A.

2014-01-01

Highlights: • Optimal parameters for preparation by sol–gel of core–shell (BT-Nb 0.005 )/SiO 2 are presented in this paper. • Single crystalline BT-Nb 0.005 /SiO 2 core–shell composite with ∼34 nm shell thick was prepared. • The core–shell ceramic exhibits good dielectric properties and ferroelectric characteristics. -- Abstract: Perovskite complex ceramic oxides, BaTiO 3 doped with 0.5 mol%Nb 2 O 5 and then nanocoated with SiO 2 (abbreviated as BT-Nb 0.005 /SiO 2 ) was successful prepared using conventional sol–gel processing. Phase composition, particle morphology, structure, and electric properties of BT-Nb 0.005 core and BT-Nb 0.005 /SiO 2 core–shell were examined and compared, using X-ray diffraction, transmission electron microscopy and, dielectric and ferroelectric measurements. Core–shell composite with well-defined perovskite tetragonal phase of BaTiO 3 was achieved. Furthermore, single crystalline BT-Nb 0.005 /SiO 2 core–nanoshell heterostructure with ∼34 nm shell thick was prepared, which is a novelty in ferroelectrics field. The ferroelectric quality of BT-Nb 0.005 has suffered an alteration when the (BT-Nb 0.005 )/SiO 2 core–shell heterostructure was realized. One-dimensional BT-Nb 0.005 /SiO 2 core–shell heterostructure exhibits an improvement of dielectric losses and a decrease of dielectric constant, compared to uncoated BT-Nb 0.005 . The (BT-Nb 0.005 )/SiO 2 core–shell material could be interesting for application in the composite capacitors

42,000-year-old worked and pigment-stained Nautilus shell from Jerimalai (Timor-Leste): Evidence for an early coastal adaptation in ISEA.

Science.gov (United States)

Langley, Michelle C; O'Connor, Sue; Piotto, Elena

2016-08-01

In this paper, we describe worked and pigment-stained Nautilus shell artefacts recovered from Jerimalai, Timor-Leste. Two of these artefacts come from contexts dating to between 38,000 and 42,000 cal. BP (calibrated years before present), and exhibit manufacturing traces (drilling, pressure flaking, grinding), as well as red colourant staining. Through describing more complete Nautilus shell ornaments from younger levels from this same site (>15,900, 9500, and 5000 cal. BP), we demonstrate that those dating to the initial occupation period of Jerimalai are of anthropogenic origin. The identification of such early shell working examples of pelagic shell in Island Southeast Asia not only adds to our growing understanding of the importance of marine resources to the earliest modern human communities in this region, but also indicates that a remarkably enduring shell working tradition was enacted in this area of the globe. Additionally, these artefacts provide the first material culture evidence that the inhabitants of Jerimalai were not only exploiting coastal resources for their nutritional requirements, but also incorporating these materials into their social technologies, and by extension, their social systems. In other words, we argue that the people of Jerimalai were already practicing a developed coastal adaptation by at least 42,000 cal. BP. Copyright © 2016 Elsevier Ltd. All rights reserved.

External and internal shell formation in the ramshorn snail Marisa cornuarietis are extremes in a continuum of gradual variation in development.

Science.gov (United States)

Marschner, Leonie; Staniek, Julian; Schuster, Silke; Triebskorn, Rita; Köhler, Heinz-R

2013-05-17

Toxic substances like heavy metals can inhibit and disrupt the normal embryonic development of organisms. Exposure to platinum during embryogenesis has been shown to lead to a "one fell swoop" internalization of the shell in the ramshorn snail Marisa cornuarietis, an event which has been discussed to be possibly indicative of processes in evolution which may result in dramatic changes in body plans. Whereas at usual cultivation temperature, 26°C, platinum inhibits the growth of both shell gland and mantle edge during embryogenesis leading to an internalization of the mantle and, thus, also of the shell, higher temperatures induce a re-start of the differential growth of the mantle edge and the shell gland after a period of inactivity. Here, developing embryos exhibit a broad spectrum of shell forms: in some individuals only the ventral part of the visceral sac is covered while others develop almost "normal" shells. Histological studies and scanning electron microscopy images revealed platinum to inhibit the differential growth of the shell gland and the mantle edge, and elevated temperature (28 - 30°C) to mitigate this platinum effect with varying efficiency. We could show that the formation of internal, external, and intermediate shells is realized within the continuum of a developmental gradient defined by the degree of differential growth of the embryonic mantle edge and shell gland. The artificially induced internal and intermediate shells are first external and then partly internalized, similar to internal shells found in other molluscan groups.

Carbon isotopes in mollusk shell carbonates

Science.gov (United States)

McConnaughey, Ted A.; Gillikin, David Paul

2008-10-01

Mollusk shells contain many isotopic clues about calcification physiology and environmental conditions at the time of shell formation. In this review, we use both published and unpublished data to discuss carbon isotopes in both bivalve and gastropod shell carbonates. Land snails construct their shells mainly from respired CO2, and shell δ13C reflects the local mix of C3 and C4 plants consumed. Shell δ13C is typically >10‰ heavier than diet, probably because respiratory gas exchange discards CO2, and retains the isotopically heavier HCO3 -. Respired CO2 contributes less to the shells of aquatic mollusks, because CO2/O2 ratios are usually higher in water than in air, leading to more replacement of respired CO2 by environmental CO2. Fluid exchange with the environment also brings additional dissolved inorganic carbon (DIC) into the calcification site. Shell δ13C is typically a few ‰ lower than ambient DIC, and often decreases with age. Shell δ13C retains clues about processes such as ecosystem metabolism and estuarine mixing. Ca2+ ATPase-based models of calcification physiology developed for corals and algae likely apply to mollusks, too, but lower pH and carbonic anhydrase at the calcification site probably suppress kinetic isotope effects. Carbon isotopes in biogenic carbonates are clearly complex, but cautious interpretation can provide a wealth of information, especially after vital effects are better understood.

Dynamic centering of liquid shells

International Nuclear Information System (INIS)

Tsamopoulos, J.A.; Brown, R.A.

1987-01-01

The moderate-amplitude axisymmetric oscillations of an inviscid liquid shell surrounding an incompressible gas bubble are calculated by a multiple-time-scale expansion for initial deformations composed of two-lobed perturbations of the shell and a displacement of the bubble from the center of mass of the liquid. Two types of small-amplitude motion are identified and lead to very different nonlinear dynamic interactions, as described by the results valid up to second order in the amplitude of the initial deformation. In the ''bubble mode,'' the oscillations of the captive bubble and the liquid shell are exactly in phase and the bubble vibrates about its initial eccentric location. The bubble moves toward the center of the drop when the shell is perturbed into a ''sloshing mode'' of oscillation where both interfaces move out of phase. These results explain the centering of liquid shells observed in several experiments

Shells and Patterns

Science.gov (United States)

Sutley, Jane

2009-01-01

"Shells and Patterns" was a project the author felt would easily put smiles on the faces of her fifth-graders, and teach them about unity and the use of watercolor pencils as well. It was thrilling to see the excitement in her students as they made their line drawings of shells come to life. For the most part, they quickly got the hang of…

Analytic proof of partial conservation of seniority in j=9/2 shells

International Nuclear Information System (INIS)

Chong Qi; Xu, Z.X.; Liotta, R.J.

2012-01-01

A partial conservation of the seniority quantum number in j=9/2 shells has been found recently in a numerical application. In this paper an analytic proof for this problem is derived as an extension of the work [L. Zamick, P. Van Isacker, Phys. Rev. C 78 (2008) 044327]. We analyze the properties of the non-diagonal interaction matrix elements with the help of the one-particle and two-particle coefficients of fractional parentage (cfp's). It is found that all non-diagonal (and the relevant diagonal) matrix elements can be re-expressed in simple ways and are proportional to certain one-particle cfp's. This remarkable occurrence of partial dynamic symmetry is the consequence of the peculiar property of the j=9/2 shell, where all v=3 and 5 states are uniquely defined.

Four-loop on-shell integrals. MS-on-shell relation and g-2

Energy Technology Data Exchange (ETDEWEB)

Marquard, P.

2013-12-15

We present first results towards a full four-loop calculation for both the anomalous magnetic moment of the muon and the MS-on-shell relation. The calculation requires the detailed study of an up to now not considered class of diagrams, so-called on-shell diagrams, at four-loop order.

Recent developments in anisotropic heterogeneous shell theory

CERN Document Server

Grigorenko, Alexander Ya; Grigorenko, Yaroslav M; Vlaikov, Georgii G

2016-01-01

This volume focuses on the relevant general theory and presents some first applications, namely those based on classical shell theory. After a brief introduction, during which the history and state-of-the-art are discussed, the first chapter presents the mechanics of anisotropic heterogeneous shells, covering all relevant assumptions and the basic relations of 3D elasticity, classical and refined shell models. The second chapter examines the numerical techniques that are used, namely discrete orthogonalization, spline-collocation and Fourier series, while the third highlights applications based on classical theory, in particular, the stress-strain state of shallow shells, non-circular shells, shells of revolution, and free vibrations of conical shells. The book concludes with a summary and an outlook bridging the gap to the second volume.

Buckling Capacity Curves for Steel Spherical Shells Loaded by the External Pressure

Science.gov (United States)

Błażejewski, Paweł; Marcinowski, Jakub

2015-03-01

Assessment of buckling resistance of pressurised spherical cap is not an easy task. There exist two different approaches which allow to achieve this goal. The first approach involves performing advanced numerical analyses in which material and geometrical nonlinearities would be taken into account as well as considering the worst imperfections of the defined amplitude. This kind of analysis is customarily called GMNIA and is carried out by means of the computer software based on FEM. The other, comparatively easier approach, relies on the utilisation of earlier prepared procedures which enable determination of the critical resistance pRcr, the plastic resistance pRpl and buckling parameters a, b, h, l 0 needed to the definition of the standard buckling resistance curve. The determination of the buckling capacity curve for the particular class of spherical caps is the principal goal of this work. The method of determination of the critical pressure and the plastic resistance were described by the authors in [1] whereas the worst imperfection mode for the considered class of spherical shells was found in [2]. The determination of buckling parameters defining the buckling capacity curve for the whole class of shells is more complicated task. For this reason the authors focused their attention on spherical steel caps with the radius to thickness ratio of R/t = 500, the semi angle j = 30o and the boundary condition BC2 (the clamped supporting edge). Taking into account all imperfection forms considered in [2] and different amplitudes expressed by the multiple of the shell thickness, sets of buckling parameters defining the capacity curve were determined. These parameters were determined by the methods proposed by Rotter in [3] and [4] where the method of determination of the exponent h by means of additional parameter k was presented. As a result of the performed analyses the standard capacity curves for all considered imperfection modes and amplitudes 0.5t, 1.0t, 1.5t

Ni3Si(Al)/a-SiOx core shell nanoparticles: characterization, shell formation, and stability

Science.gov (United States)

Pigozzi, G.; Mukherji, D.; Gilles, R.; Barbier, B.; Kostorz, G.

2006-08-01

We have used an electrochemical selective phase dissolution method to extract nanoprecipitates of the Ni3Si-type intermetallic phase from two-phase Ni-Si and Ni-Si-Al alloys by dissolving the matrix phase. The extracted nanoparticles are characterized by transmission electron microscopy, energy-dispersive x-ray spectrometry, x-ray powder diffraction, and electron powder diffraction. It is found that the Ni3Si-type nanoparticles have a core-shell structure. The core maintains the size, the shape, and the crystal structure of the precipitates that existed in the bulk alloys, while the shell is an amorphous phase, containing only Si and O (SiOx). The shell forms around the precipitates during the extraction process. After annealing the nanoparticles in nitrogen at 700 °C, the tridymite phase recrystallizes within the shell, which remains partially amorphous. In contrast, on annealing in air at 1000 °C, no changes in the composition or the structure of the nanoparticles occur. It is suggested that the shell forms after dealloying of the matrix phase, where Si atoms, the main constituents of the shell, migrate to the surface of the precipitates.

Fabrication of Foam Shells for ICF Experiments

Science.gov (United States)

Czechowicz, D. G.; Acenas, O.; Flowers, J. S.; Nikroo, A.; Paguio, R. R.; Schroen, D. G.; Streit, J.; Takagi, M.

2004-11-01

The General Atomics/Schafer team has developed processes to fabricate foam shells targets suitable for ICF experiments. The two most common chemical systems used to produce foam shells have been resorcinol-formaldehyde (R/F) aerogel and divinylbenzene (DVB). Spherical targets have been made in the form of shells and beads having diameters ranging from approximately 0.5 mm to 4.0 mm, and having densities from approximately 100 mg/cc to 250 mg/cc. The work on R/F foam shells has been concentrated on 1) shell fabrication process improvement to obtain high yields ( ˜25%) and 2) depositing a reliable permeation barrier to provide shells for ongoing direct drive experiments at LLE. Development of divinylbenzene foam shells has been mainly directed towards Inertial Fusion Energy applications (at densities as low as 30 mg/cc) and recently for shells for experiments at LLE. Details of the relevant metrology and properties of these foams as well as the range of targets currently available will be discussed.

Radar attenuation in Europa's ice shell: Obstacles and opportunities for constraining the shell thickness and its thermal structure

Science.gov (United States)

Kalousová, Klára; Schroeder, Dustin M.; Soderlund, Krista M.

2017-03-01

Young surface and possible recent endogenic activity make Europa one of the most exciting solar system bodies and a primary target for spacecraft exploration. Future Europa missions are expected to carry ice-penetrating radar instruments designed to investigate its subsurface thermophysical structure. Several authors have addressed the radar sounders' performance at icy moons, often ignoring the complex structure of a realistic ice shell. Here we explore the variation in two-way radar attenuation for a variety of potential thermal structures of Europa's shell (determined by reference viscosity, activation energy, tidal heating, surface temperature, and shell thickness) as well as for low and high loss temperature-dependent attenuation model. We found that (i) for all investigated ice shell thicknesses (5-30 km), the radar sounder will penetrate between 15% and 100% of the total thickness, (ii) the maximum penetration depth varies laterally, with deepest penetration possible through cold downwellings, (iii) direct ocean detection might be possible for shells of up to 15 km thick if the signal travels through cold downwelling ice or the shell is conductive, (iv) even if the ice/ocean interface is not directly detected, penetration through most of the shell could constrain the deep shell structure through returns from deep non-ocean interfaces or the loss of signal itself, and (v) for all plausible ice shells, the two-way attenuation to the eutectic point is ≲30 dB which shows a robust potential for longitudinal investigation of the ice shell's shallow thermophysical structure.

Vibration of liquid-filled thin shells

International Nuclear Information System (INIS)

Kalnins, A.

1979-01-01

This paper describes the analysis of free and forced vibration of a thin, axisymmetric shell, which contains some liquid. The axis of symmetry is vertical. Only such vibration is considered which can be produced by a horizontal movement of the base of shell. The objective of this paper is to examine the response of the coupled shell-liquid system for a frequency range lying between zero and the lowest natural sloshing frequency of the liquid. The mass of the liquid is modeled by a stationary and one or more sloshing masses. It is shown how the stationary mass can be incorporated in the vibration analysis of the shell and how to natural frequency of the coupled shell-liquid system can be obtained from a simple formula, if the lowest natural frequency of the shell, plus the stationary mass of the liquid, can be determined. A numerical example is given. (orig.)

A Study on the Plasmonic Properties of Silver Core Gold Shell Nanoparticles: Optical Assessment of the Particle Structure

Science.gov (United States)

Mott, Derrick; Lee, JaeDong; Thi Bich Thuy, Nguyen; Aoki, Yoshiya; Singh, Prerna; Maenosono, Shinya

2011-06-01

This paper reports a qualitative comparison between the optical properties of a set of silver core, gold shell nanoparticles with varying composition and structure to those calculated using the Mie solution. To achieve this, silver nanoparticles were synthesized in aqueous phase from a silver hydroxide precursor with sodium acrylate as dual reducing-capping agent. The particles were then coated with a layer of gold with controllable thickness through a reduction-deposition process. The resulting nanoparticles reveal well defined optical properties that make them suitable for comparison to ideal calculated results using the Mie solution. The discussion focuses on the correlation between the synthesized core shell nanoparticles with varying Au shell thickness and the Mie solution results in terms of the optical properties. The results give insight in how to design and synthesize silver core, gold shell nanoparticles with controllable optical properties (e.g., SPR band in terms of intensity and position), and has implications in creating nanoparticle materials to be used as biological probes and sensing elements.

On-shell and half-shell effects of the coulomb potential in quantum mechanics

NARCIS (Netherlands)

Maag, Jan Willem de

1984-01-01

In dit proefschrift wordt de Coulomb potentiaal in de nietrelativistische quantummechanica bestudeerd. Met gebruik van een streng wiskundige beschrijving onderzoeken we, in het bijzonder, on-shell en off-shell eigenschappen. De overeenkomsten en de verschillen met het geval van een glad afgeschermde

Creep buckling of shell structures

International Nuclear Information System (INIS)

Miyazaki, Noriyuki; Hagihara, Seiya

2015-01-01

The present article contains a review of the literatures on the creep buckling of shell structures published from late 1950's to recent years. In this article, the creep buckling studies on circular cylindrical shells, spherical shells, partial cylindrical shells and other shells are reviewed in addition to creep buckling criteria. Creep buckling is categorized into two types. One is the creep buckling due to quasi-static instability, in which the critical time for creep buckling is determined by tracing a creep deformation versus time curve. The other is the creep buckling due to kinetic instability, in which the critical time can be determined by examining the shape of total potential energy in the vicinity of a quasi-static equilibrium state. Bifurcation buckling and snap-through buckling during creep deformation belong to this type of creep buckling. A few detailed descriptions are given to the bifurcation and snap-through type of creep buckling based on the present authors' works. (author)

Egg Shell and Oyster Shell Powder as Alternatives for Synthetic Phosphate: Effects on the Quality of Cooked Ground Pork Products.

Science.gov (United States)

Cho, Min Guk; Bae, Su Min; Jeong, Jong Youn

2017-01-01

This study aimed to determine the optimal ratio of natural calcium powders (oyster shell and egg shell calcium) as synthetic phosphate replacers in pork products. Ground pork samples were subjected to six treatments, as follows: control (-) (no phosphate added), control (+) (0.3% phosphate blend added), treatment 1 (0.5% oyster shell calcium powder added), treatment 2 (0.3% oyster shell calcium powder and 0.2% egg shell calcium powder added), treatment 3 (0.2% oyster shell calcium powder and 0.3% egg shell calcium powder added), and treatment 4 (0.5% egg shell calcium powder added). The addition of natural calcium powders resulted in an increase in the pH values of meat products, regardless of whether they were used individually or mixed. The highest cooking loss was observed ( p cooking loss in samples with natural calcium powder added was similar ( p >0.05) to that in the positive control samples. CIE L* values decreased as the amount of added egg shell calcium powder increased. CIE a* values were higher ( p egg shell powder (treatment 2 or 3) was effective for the improvement of textural properties of the pork products. The findings show that the combined use of 0.2% oyster shell calcium and 0.3% egg shell calcium should enable the replacement of synthetic phosphate in the production of cooked pork products with desirable qualities.

7 CFR 983.29 - Shelled pistachios.

Science.gov (United States)

2010-01-01

... 7 Agriculture 8 2010-01-01 2010-01-01 false Shelled pistachios. 983.29 Section 983.29 Agriculture... and Orders; Fruits, Vegetables, Nuts), DEPARTMENT OF AGRICULTURE PISTACHIOS GROWN IN CALIFORNIA, ARIZONA, AND NEW MEXICO Definitions § 983.29 Shelled pistachios. Shelled pistachios means pistachio...

Vibrations of Thin Piezoelectric Shallow Shells

Indian Academy of Sciences (India)

Abstract. In this paper we consider the eigenvalue problem for piezoelectric shallow shells and we show that, as the thickness of the shell goes to zero, the eigensolutions of the three-dimensional piezoelectric shells converge to the eigensolutions of a two-dimensional eigenvalue problem.

Patterning of the turtle shell.

Science.gov (United States)

Moustakas-Verho, Jacqueline E; Cebra-Thomas, Judith; Gilbert, Scott F

2017-08-01

Interest in the origin and evolution of the turtle shell has resulted in a most unlikely clade becoming an important research group for investigating morphological diversity in developmental biology. Many turtles generate a two-component shell that nearly surrounds the body in a bony exoskeleton. The ectoderm covering the shell produces epidermal scutes that form a phylogenetically stable pattern. In some lineages, the bones of the shell and their ectodermal covering become reduced or lost, and this is generally associated with different ecological habits. The similarity and diversity of turtles allows research into how changes in development create evolutionary novelty, interacting modules, and adaptive physiology and anatomy. Copyright © 2017 Elsevier Ltd. All rights reserved.

Characteristic analysis on the deformation behaviour of shell-like lattice structures subjected to follower forces; Judo kaju wo ukeru kosa arch kozo no daihenkei kyodo ni kansuru kenkyu

Energy Technology Data Exchange (ETDEWEB)

Fukuchi, N.; Okada, K. [Kyushu University, Fukuoka (Japan); Fujii, M. [Namura Shipbuilding Co. Ltd., Osaka (Japan); Shiraki, M. [Toyota Motor Corp., Aichi (Japan)

1998-09-04

The deformation mechanisms of submerged shell-like lattice structures with membrane are in principle of a non-conservative nature since the follower type hydrostatic pressure. In the region of large deformations, especially in the case of geometrically deep shell-like lattice structures, the system could be much more accurately defined in a mono-clinically convected coordinate description than the conventional spatial description. Also, a complete analysis of a non-conservative system requires a criterion since the system can have multiple ranges of stability and instability involving buckling and snapping. This paper presents the development of the governing equations for the finite deformations of shell-like lattices defined in a mono-clincally convected coordinate description and applies the same to different cases of lattice deformations. The validity of the formulations is verified for finite deformation. The examples of some geometrically special shell-like lattice structures are presented as well to show the feasibility of the present formulation. 5 refs., 11 figs.

Synthesis of Aqueous CdTe/CdS/ZnS Core/shell/shell Quantum Dots by a Chemical Aerosol Flow Method

Directory of Open Access Journals (Sweden)

Chen Dong

2009-01-01

Full Text Available Abstract This work described a continuous method to synthesize CdTe/CdS/ZnS core/shell/shell quantum dots. In an integrated system by flawlessly combining the chemical aerosol flow system working at high temperature (200–300°C to generate CdTe/CdS intermediate products and an additional heat-up setup at relatively low temperature to overcoat the ZnS shells, the CdTe/CdS/ZnS multishell structures were realized. The as-synthesized CdTe/CdS/ZnS core/shell/shell quantum dots are characterized by photoluminescence spectra, X-ray diffraction (XRD, energy-dispersive X-ray spectra (EDS, transmission electron microscopy (TEM, and high-resolution transmission electron microscopy (HRTEM. Fluorescence and XRD results confirm that the obtained quantum dots have a core/shell/shell structure. It shows the highest quantum yield above 45% when compared to the rhodamine 6G. The core/shell/shell QDs were more stable via the oxidation experiment by H2O2.

Signatures of shell evolution in alpha decay across the N = 126 shell closure

Science.gov (United States)

Rui-Wang; Wang, Rui-Yao; Qian, Yi-Bin; Ren, Zhong-Zhou

2017-06-01

Within the alpha-cluster model, we particularly investigate the alpha decay of exotic nuclei in the vicinity of the N = 126 neutron shell plus the Z = 82 proton shell. The systematics of alpha-preformation probability (P α ), as an indicator of the shell effect, is deduced from the ratio of the experimental decay width to the calculated one. Through the comparative analysis of the P α trend in the N = 124-130 isotonic chain, the N = 126 and Z = 82 shell closures are believed to strongly affect the formation of the alpha particle before its penetration. Additionally, the P α variety in Po and Rn isotopes is presented as another proof for such an influence. More importantly, it may be concluded that the expected neutron (or proton) shell effect gradually fades away along with the increasing valence proton (or neutron) number. The odd-even staggering presented in the P α value is also discussed. Supported by National Natural Science Foundation of China (11375086, 11535004, 11605089, 11120101005), Natural Science Youth Fund of Jiangsu Province (BK20150762), Fundamental Research Funds for the Central Universities (30916011339), 973 National Major State Basic Research and Development Program of China (2013CB834400), and a Project Funded by the Priority Academic Programme Development of JiangSu Higher Education Institutions (PAPD)

Shell film- and video catalogue 1996

International Nuclear Information System (INIS)

1996-01-01

An overview is given of films and videos that are available through 'Shell Nederland Filmcentrale' (Shell Netherlands Film Center), subdivided into the subjects (1) About Shell; (2) Health, Safety and Environment; (3) Science and Technology; (4) The History of Car(racing); and (5) Historical Overview. 5 ills

7 CFR 981.6 - Shelled almonds.

Science.gov (United States)

2010-01-01

... 7 Agriculture 8 2010-01-01 2010-01-01 false Shelled almonds. 981.6 Section 981.6 Agriculture... and Orders; Fruits, Vegetables, Nuts), DEPARTMENT OF AGRICULTURE ALMONDS GROWN IN CALIFORNIA Order Regulating Handling Definitions § 981.6 Shelled almonds. Shelled almonds mean raw or roasted almonds after...

Indentation of Ellipsoidal and Cylindrical Elastic Shells

KAUST Repository

Vella, Dominic

2012-10-01

Thin shells are found in nature at scales ranging from viruses to hens\\' eggs; the stiffness of such shells is essential for their function. We present the results of numerical simulations and theoretical analyses for the indentation of ellipsoidal and cylindrical elastic shells, considering both pressurized and unpressurized shells. We provide a theoretical foundation for the experimental findings of Lazarus etal. [following paper, Phys. Rev. Lett. 109, 144301 (2012)PRLTAO0031-9007] and for previous work inferring the turgor pressure of bacteria from measurements of their indentation stiffness; we also identify a new regime at large indentation. We show that the indentation stiffness of convex shells is dominated by either the mean or Gaussian curvature of the shell depending on the pressurization and indentation depth. Our results reveal how geometry rules the rigidity of shells. © 2012 American Physical Society.

Double containment shell for nuclear power plants

International Nuclear Information System (INIS)

Sykora, D.

1977-01-01

A double containment shell is proposed for nuclear power plants, especially those equipped with pressurized water reactors. The shell offers increased environmental protection from primary circuit accidents. The inner shell is built of steel or concrete while the outer shell is always built of concrete. The space between the two shells is filled with water and is provided with several manholes and with stiffeners designed for compensation for load due to the water hydrostatic pressure. Water serves the airtight separation of the containment shell inside from the environment and the absorption of heat released in a primary circuit accident. In case the inner shell is made of concrete, it is provided with heat-removal tubes in-built in its walls ensuring rapid heat transfer from the inside of the containment to the water in the interwall space. (Z.M.)

Seismic analysis of axisymmetric shells

International Nuclear Information System (INIS)

Jospin, R.J.; Toledo, E.M.; Feijoo, R.A.

1984-01-01

Axisymmetric shells subjected to multiple support excitation are studied. The shells are spatialy discretized by the finite element method and in order to obtain estimates for the maximum values of displacements and stresses the response spectrum tecnique is used. Finally, some numerical results are presented and discussed in the case of a shell of revolution with vertical symmetry axis, subjected to seismic ground motions in the horizontal, vertical and rocking directions. (Author) [pt

Creep analysis of orthotropic shells

International Nuclear Information System (INIS)

Mehra, V.K.; Ghosh, A.

1975-01-01

A method of creep analysis of orthotropic cylindrical shells subjected to axisymmetric loads has been developed. A general study of creep behaviour of cylindrical shells subjected to a uniform internal pressure has been conducted for a wide range of values of anisotropy coefficients and creep law exponent. Analysis includes determination of stress re-distribution, strain rates, stationary state stresses. Application of reference stress technique has been extended to analysis of shells. (author)

Fabricating a Homogeneously Alloyed AuAg Shell on Au Nanorods to Achieve Strong, Stable, and Tunable Surface Plasmon Resonances

KAUST Repository

Huang, Jianfeng

2015-08-13

Colloidal metal nanocrystals with strong, stable, and tunable localized surface plasmon resonances (SPRs) can be useful in a corrosive environment for many applications including field-enhanced spectroscopies, plasmon-mediated catalysis, etc. Here, a new synthetic strategy is reported that enables the epitaxial growth of a homogeneously alloyed AuAg shell on Au nanorod seeds, circumventing the phase segregation of Au and Ag encountered in conventional synthesis. The resulting core–shell structured bimetallic nanorods (AuNR@AuAg) have well-mixed Au and Ag atoms in their shell without discernible domains. This degree of mixing allows AuNR@AuAg to combine the high stability of Au with the superior plasmonic activity of Ag, thus outperforming seemingly similar nanostructures with monometallic shells (e.g., Ag-coated Au NRs (AuNR@Ag) and Au-coated Au NRs (AuNR@Au)). AuNR@AuAg is comparable to AuNR@Ag in plasmonic activity, but that it is markedly more stable toward oxidative treatment. Specifically, AuNR@AuAg and AuNR@Ag exhibit similarly strong signals in surface-enhanced Raman spectroscopy that are some 30-fold higher than that of AuNR@Au. When incubated with a H2O2 solution (0.5 m), the plasmonic activity of AuNR@Ag immediately and severely decayed, whereas AuNR@AuAg retained its activity intact. Moreover, the longitudinal SPR frequency of AuNR@AuAg can be tuned throughout the red wavelengths (≈620–690 nm) by controlling the thickness of the AuAg alloy shell. The synthetic strategy is versatile to fabricate AuAg alloyed shells on different shaped Au, with prospects for new possibilities in the synthesis and application of plasmonic nanocrystals.

Faraday Wave Turbulence on a Spherical Liquid Shell

Science.gov (United States)

Holt, R. Glynn; Trinh, Eugene H.

1996-01-01

Millimeter-radius liquid shells are acoustically levitated in an ultrasonic field. Capillary waves are observed on the shells. At low energies (minimal acoustic amplitude, thick shell) a resonance is observed between the symmetric and antisymmetric thin film oscillation modes. At high energies (high acoustic pressure, thin shell) the shell becomes fully covered with high-amplitude waves. Temporal spectra of scattered light from the shell in this regime exhibit a power-law decay indicative of turbulence.

Extraction of cellulose from pistachio shell and physical and mechanical characterisation of cellulose-based nanocomposites

Science.gov (United States)

Movva, Mounika; Kommineni, Ravindra

2017-04-01

Cellulose is an important nanoentity that have been used for the preparation of composites. The present work focuses on the extraction of cellulose from pistachio shell and preparing a partially degradable nanocomposite with extracted cellulose. Physical and microstructural characteristics of nanocellulose extracted from pistachio shell powder (PSP) through various stages of chemical treatment are identified from scanning electron microscopy (SEM), Fourier transform infra-red spectroscopy (FTIR), x-ray powder diffraction (XRD), and thermogravimetric analysis (TGA). Later, characterized nanocellulose is reinforced in a polyester matrix to fabricate nanocellulose-based composites according to the ASTM standard. The resulting nanocellulose composite performance is evaluated in the mechanical perspective through tensile and flexural loading. SEM, FTIR, and XRD showed that the process for extraction is efficient in obtaining 95% crystalline cellulose. Cellulose also showed good thermal stability with a peak thermal degradation temperature of 361 °C. Such cellulose when reinforced in a matrix material showed a noteworthy rise in tensile and flexural strengths of 43 MPa and 127 MPa, at a definite weight percent of 5%.

Double Shell Tanks (DST) and Waste Feed Delivery Project Management Quality Affecting Procedures Management Plan

International Nuclear Information System (INIS)

LUND, D.P.

2000-01-01

The purpose of the Double Shell Tanks (DST) and Waste Feed Delivery (WFD) Management Assessment Plan is to define how management assessments within DST h WFD will be conducted. The plan as written currently includes only WFD Project assessment topics. Other DST and WFD group assessment topics will be added in future revisions

The red supergiant population in the Perseus arm

Science.gov (United States)

Dorda, R.; Negueruela, I.; González-Fernández, C.

2018-04-01

We present a new catalogue of cool supergiants in a section of the Perseus arm, most of which had not been previously identified. To generate it, we have used a set of well-defined photometric criteria to select a large number of candidates (637) that were later observed at intermediate resolution in the infrared calcium triplet spectral range, using a long-slit spectrograph. To separate red supergiants from luminous red giants, we used a statistical method, developed in previous works and improved in the present paper. We present a method to assign probabilities of being a red supergiant to a given spectrum and use the properties of a population to generate clean samples, without contamination from lower luminosity stars. We compare our identification with a classification done using classical criteria and discuss their respective efficiencies and contaminations as identification methods. We confirm that our method is as efficient at finding supergiants as the best classical methods, but with a far lower contamination by red giants than any other method. The result is a catalogue with 197 cool supergiants, 191 of which did not appear in previous lists of red supergiants. This is the largest coherent catalogue of cool supergiants in the Galaxy.

Predicting transport survival of brindle and red rock lobsters Jasus edwardsii using haemolymph biochemistry and behaviour traits.

Science.gov (United States)

Simon, Cedric J; Mendo, Tania C; Green, Bridget S; Gardner, Caleb

2016-11-01

Mortality events during live transport of Jasus edwardsii rock lobsters are common around the time of season openings in Tasmania, with lobsters from deeper fishing areas with pale shell colouration (brindle) being perceived as more susceptible than shallow-water, red-coloured (red) lobsters. The aims of this study were to assess and predict the vulnerability of brindle and red lobsters to extended emersion exposure using pre- and post-emersion data which included 28 haemolymph biochemical parameters and 5 behaviour traits. No effect of lobster shell colour on haemolymph biochemistry, behaviour traits and their vulnerability to emersion was found. A combined survival of 97% after 40h and 57% after 64h in a first experiment, and 37% after 64h in a second experiment, was observed. Behaviour traits (i.e., righting response, tail flips and three reflex behaviours) were poor indicator of survival. Haemolymph parameters were either unaffected by emersion (e.g., Brix index, protein and lipids), affected by emersion but not associated with mortality (e.g., total haemocyte counts, calcium, magnesium, bicarbonate, glucose and uric acid), or associated with mortality following a recovery period (e.g., pH, the sodium to potassium ratio, urea, and the activity of amylase). A build-up of anaerobic end-products and nitrogenous waste most likely resulted in the mortality. A model based on lobster size and the pre-emersion concentration of haemolymph bicarbonate and haemocyanin was found to be a useful indicator of future survival. This study provides promising leads towards the development of a blood based vulnerability test for live crustacean prior transport. Copyright © 2016 Elsevier Inc. All rights reserved.

Heat exchanger, head and shell acceptance criteria

International Nuclear Information System (INIS)

Lam, P.S.; Sindelar, R.L.

1992-09-01

Instability of postulated flaws in the head component of the heat exchanger could not produce a large break, equivalent to a DEGB in the PWS piping, due to the configuration of the head and restraint provided by the staybolts. Rather, leakage from throughwall flaws in the head would increase with flaw length with finite leakage areas that are bounded by a post-instability flaw configuration. Postulated flaws at instability in the shell of the heat exchanger or in the cooling water nozzles could produce a large break in the Cooling Water System (CWS) pressure boundary. An initial analysis of flaw stability for postulated flaws in the heat exchanger head was performed in January 1992. This present report updates that analysis and, additionally, provides acceptable flaw configurations to maintain defined structural or safety margins against flaw instability of the external pressure boundary components of the heat exchanger, namely the head, shell, and cooling water nozzles. Structural and flaw stability analyses of the heat exchanger tubes, the internal pressure boundary of the heat exchangers or interface boundary between the PWS and CWS, were previously completed in February 1992 as part of the heat exchanger restart evaluation and are not covered in this report

Study of characterization of trace elements in marine shells of Sambaqui: correlation between recent and old shells

International Nuclear Information System (INIS)

Gomez, Mauro Roger Batista Pousada; Rocha, Flavio Roberto; Silva, Paulo Sergio Cardoso da

2013-01-01

Calcium carbonate of recent and ancient C. rhizophorae oyster shells was analyzed for the determination of trace elements by instrumental neutron activation analysis. The ancient shells belong to a Sambaqui located in Cananeia region, South of Sao Paulo state and the recent ones are from an oyster production farm in the same region Studies related to the element concentrations in molluscs shell has been done as a tentative of establishing the element concentrations with palio-environmental factor. In this study it was aimed to verify differences in the elemental constitution of recent and ancient oyster shells that present potential for being used as indicator of marine changes. Results indicated that the elements Br, Ce, La, Na, Sm and An are higher in recent shells and the elements Cr, Fe Sc and Th are higher in ancient shells. Statistical analyses performed indicated that the enrichment of the light rare earth elements related to Ca are possibly good candidates for these palio-environmental studies. (author)

Synthesis, characterization and biomedical application of multifunctional luminomagnetic core–shell nanoparticles

Energy Technology Data Exchange (ETDEWEB)

Yi, Changqing [Key Laboratory of Biochip Technology, Biotech and Health Centre, Shenzhen Research Institutes of City University of Hong Kong, Shenzhen (China); Key Laboratory of Sensing Technology and Biomedical Instruments (Guangdong Province), School of Engineering, Sun Yat-Sen University, Guangzhou (China); Liu, Lei [Key Laboratory of Biochip Technology, Biotech and Health Centre, Shenzhen Research Institutes of City University of Hong Kong, Shenzhen (China); College of Chemistry and Environmental Science, Chemical Biology Key Laboratory of Hebei Province, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis of Ministry of Education, Hebei University, Baoding (China); Li, Cheuk-Wing [Key Laboratory of Biochip Technology, Biotech and Health Centre, Shenzhen Research Institutes of City University of Hong Kong, Shenzhen (China); Zhang, Jinchao, E-mail: jczhang6970@163.com [Key Laboratory of Biochip Technology, Biotech and Health Centre, Shenzhen Research Institutes of City University of Hong Kong, Shenzhen (China); College of Chemistry and Environmental Science, Chemical Biology Key Laboratory of Hebei Province, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis of Ministry of Education, Hebei University, Baoding (China); Yang, Mengsu, E-mail: bhmyang@cityu.edu.hk [Key Laboratory of Biochip Technology, Biotech and Health Centre, Shenzhen Research Institutes of City University of Hong Kong, Shenzhen (China)

2015-01-01

It has been well-established that nanomaterials provide a robust framework into which two or more functional moieties can be integrated to offer multifunctional and synergetic applications. We report here the facile synthesis and systematical investigation of the luminomagnetic core–shell nanoparticles (NPs) with the magnetic Fe{sub 3}O{sub 4} core coated with a silica shell incorporating fluorescent [Ru(bpy){sub 3}]{sup 2+}. The luminomagnetic NPs were monodisperse and spherical in shape with a diameter of 60 ± 10 nm. The luminomagnetic NPs possessed not only the desirable optical signature of Ru(bpy){sub 3}{sup 2+} but also the distinctive magnetic profile of Fe{sub 3}O{sub 4}, where a strong red-orange emission and the super-paramagnetic characteristics with the saturation magnetization values ca. 10 emu/g were observed for the luminomagnetic NPs. As revealed by Alamar blue assay and flow cytometry analysis, the Fe{sub 3}O{sub 4} NPs decrease the cell viability of HepG2 by ca. 10%, while an increase by ca. 10% on HepG2 cell proliferation was revealed after the silica shell was coated onto Fe{sub 3}O{sub 4} NPs, suggesting that the silica shell serves as a protective layer to increase the biocompatibility of the luminomagnetic NPs. Confocal laser scanning microscopy, transition electron microscopy and magnetic resonance (MR) images confirmed that the luminomagnetic NPs can enter into the interiors of HepG2 cells without damage, highlighting their capabilities for simultaneous optical fluorescence imaging and T2 MR imaging. Taking advantage of versatility of silica shell towards different surface modification protocols, the luminomagnetic NPs were successfully functionalized with epidermal growth factor receptor (EGFR) antibody for HepG2 cell recognition. All the results illustrated that the luminomagnetic NPs should be a potential candidate for future cancer diagnosis and therapy. - Highlights: • The luminomagnetic NPs were prepared by a water-in-oil reverse

Analysis of Experimental Research on Cyclones with Cylindrical and Spiral Shells

Directory of Open Access Journals (Sweden)

Aleksandras Chlebnikovas

2012-12-01

Full Text Available The conducted investigation is aimed at providing information on air flow parameters in the cylindrical and spiral shell (devices are designed for separating solid particles from air flow having tangent flow inlet. Experimental research has employed multi-cyclones created by the Department of Environmental Protection at Vilnius Gediminas Technical University. The study is focused on investigating and comparing the distribution of the dynamic pressure of the airflow in six-channel cyclones inside the structures of devices. The paper establishes and estimates the efficiency of air cleaning changing air phase parameters using different particulate matters. The efficiency of the cyclone has been defined applying the weighted method based on LAND 28-98/M-08 methodology. The article presents the results of experimental research on the air cleaning efficiency of cylindrical and spiral shells using 20 µm glass and clay particulate matter under the initial concentration that may vary from 500 mg/m3 to 15 g/m3 using semi-rings with windows at different positions. The obtained results has shown that the maximum efficiency of the cylindrical shell increases up to 87,3 % while the initial concentration of glass makes 15 g/m3.Article in Lithuanian

A model for acoustic vaporization dynamics of a bubble/droplet system encapsulated within a hyperelastic shell.

Science.gov (United States)

Lacour, Thomas; Guédra, Matthieu; Valier-Brasier, Tony; Coulouvrat, François

2018-01-01

Nanodroplets have great, promising medical applications such as contrast imaging, embolotherapy, or targeted drug delivery. Their functions can be mechanically activated by means of focused ultrasound inducing a phase change of the inner liquid known as the acoustic droplet vaporization (ADV) process. In this context, a four-phases (vapor + liquid + shell + surrounding environment) model of ADV is proposed. Attention is especially devoted to the mechanical properties of the encapsulating shell, incorporating the well-known strain-softening behavior of Mooney-Rivlin material adapted to very large deformations of soft, nearly incompressible materials. Various responses to ultrasound excitation are illustrated, depending on linear and nonlinear mechanical shell properties and acoustical excitation parameters. Different classes of ADV outcomes are exhibited, and a relevant threshold ensuring complete vaporization of the inner liquid layer is defined. The dependence of this threshold with acoustical, geometrical, and mechanical parameters is also provided.

Gamma-Ray Bursts and Relativistic Shells: The Surface Filling Factor

International Nuclear Information System (INIS)

Fenimore, E.E.; Cooper, C.; Ramirez-Ruiz, E.; Sumner, M.C.; Yoshida, A.; Namiki, M.

1999-01-01

The variability observed in many complex gamma-ray bursts (GRBs) is inconsistent with causally connected variations in a single, symmetric, relativistic shell interacting with the ambient material (open-quotes external shocksclose quotes). Rather, either the central site must produce ∼10 50 ergs s -1 for hundreds of seconds (open-quotes internal shocksclose quotes), or the local spherical symmetry of the shell must be broken on an angular scale much smaller than Γ -1 , where Γ is the bulk Lorentz factor for the shell. The observed variability in the external shock models arises from the number of causally connected regions that (randomly) become active. We define the surface filling factor to be the ratio of the area of causally connected regions that become active to the observable area of the shell. From the observed variability in 52 BATSE bursts, we estimate the surface filling factor to be typically ∼5x10 -3 , although some values are near unity. We find that the surface filling factor, f, is ∼0.1ΔT/T in both the constant Γ phase (which probably produces the GRB) and the decelerating phase (which probably produces the X-ray afterglows). Here, ΔT is a typical timescale of variability, and T is the time since the initial signal. We analyze the 2 hr flare seen by ASCA 36 hr after the GRB and conclude that the surface filling factor must be small (10 -3 ) in the X-ray afterglow phase as well. Compared with the energy required for an isotropic shell, E iso , explanations for a low surface filling factor can either require more energy (f -1 E iso ∼10 56 ergs) or less energy [(ΔT/4T) 2 E iso ∼10 49 ergs]. Thus, the low filling factor cannot be used as a strong argument that GRBs must be internal shocks. copyright copyright 1999. The American Astronomical Society

Impact of off-diagonal cross-shell interaction on 14C

Science.gov (United States)

Yuan, Cen-Xi

2017-10-01

A shell-model investigation is performed to show the impact on the structure of 14C from the off-diagonal cross-shell interaction, 〈pp|V|sdsd〉, which represents the mixing between the 0 and 2ħω configurations in the psd model space. The observed levels of the positive states in 14C can be nicely described in 0-4ħω or a larger model space through the well defined Hamiltonians, YSOX and WBP, with a reduction of the strength of the 〈pp|V|sdsd〉 interaction in the latter. The observed B(GT) values for 14C can be generally described by YSOX, while WBP and their modifications of the 〈pp|V|sdsd〉 interaction fail for some values. Further investigation shows the effect of such interactions on the configuration mixing and occupancy. The present work shows examples of how the off-diagonal cross-shell interaction strongly drives the nuclear structure. Supported by National Natural Science Foundation of China (11305272), Special Program for Applied Research on Super Computation of the NSFC Guangdong Joint Fund (the second phase), the Guangdong Natural Science Foundation (2014A030313217), the Pearl River S&T Nova Program of Guangzhou (201506010060), the Tip-top Scientific and Technical Innovative Youth Talents of Guangdong special support program (2016TQ03N575), and the Fundamental Research Funds for the Central Universities (17lgzd34)

Thresholds of motion of shell debris under unidirectional flow: influence of faunal composition

Science.gov (United States)

Rieux, A.; Weill, P.; Mouazé, D.; Poirier, C.; Tessier, B.

2017-12-01

Quantifying bottom sediment erodibility is necessary to refine understanding of coastal processes and fossil records. Coastal sediments are partly composed of biogenic particles, which shape and density differ from rounded quartz grain and vary between species. Numerous studies have investigated the hydrodynamic behaviour of bioclastic sediments derived from reef-dwelling organisms, but research focusing on "cool-water carbonate" bioclastic particles (i.e. mollusc shell debris, calcareous algae, …) are rare. The present study aims in characterizing the influence of faunal composition on the entrainment threshold of mollusc shell debris from temperate regions. Shells have been sampled on shelly ridges in the southern coast of the Mont-Saint-Michel bay (NW France), before being ground and separated into individual sieve fractions. Eight species, representative of the local faunal composition, have been studied: four wild (cockle, furrow shell, saddle oyster, flat oyster), three reared (japanese oyster, mussel, manila clam) and one introduced (slipper limpet) species. Experiments for defining the threshold of motion of all samples were conducted in a small recirculating flume, under unidirectional current, and using an Acoustic Doppler Velocimeter Profiler. Critical bed shear stress values (τcr) were derived from velocity profiles in the boundary layer, by a logarithmic regression of the "law of the wall". Depending on the species, the evolution of τcr with increasing grain diameters follows either an asymptotic or a more linear trend. Differences between species can be discerned: saddle oyster, japanese oyster and flat oyster show the smallest τcr, slipper limpet, furrow shell and mussel have an intermediate τcr and cockle and manila clam the highest τcr. For the 2-3.15 mm fraction, τcr ranges from 0.38 N.m-2 (saddle oyster) to 2.13 N.m-2 (cockle). Oyster shells (japanese and flat oysters) are composed of foliated sheets of calcite, interbedded with soft

Foam shell project: Progress report

International Nuclear Information System (INIS)

Overturf, G.; Reibold, B.; Cook, B.; Schroen-Carey, D.

1994-01-01

The authors report on their work to produce a foam shell target for two possible applications: (1) as liquid-layered cryogenic target on Omega Upgrade, and (2) as a back-up design for the NIF. This target consists of a roughly 1 mm diameter and 100 μm thick spherical low-density foam shell surrounding a central void. The foam will be slightly overfilled with liquid D 2 or DT, the overfilled excess being symmetrically distributed on the inside of the shell and supported by thermal gradient techniques. The outside of the foam is overcoated with full density polymer which must be topologically smooth. The technology for manufacturing this style of foam shell involves microencapsulation techniques and has been developed by the Japanese at ILE. Their goal is to determine whether this technology can be successfully adapted to meet US ICF objectives. To this end a program of foam shell development has been initiated at LLNL in collaboration with both the General Atomics DOE Target Fabrication Contract Corporation and the Target Fabrication Group at LLE

Thin-shell wormholes in dilaton gravity

International Nuclear Information System (INIS)

Eiroa, Ernesto F.; Simeone, Claudio

2005-01-01

In this work we construct charged thin-shell Lorentzian wormholes in dilaton gravity. The exotic matter required for the construction is localized in the shell and the energy conditions are satisfied outside the shell. The total amount of exotic matter is calculated and its dependence with the parameters of the model is analyzed

The dorsal shell wall structure of Mesozoic ammonoids

Directory of Open Access Journals (Sweden)

Gregor Radtke

2017-03-01

Full Text Available The study of pristine preserved shells of Mesozoic Ammonoidea shows different types of construction and formation of the dorsal shell wall. We observe three major types: (i The vast majority of Ammonoidea, usually planispirally coiled, has a prismatic reduced dorsal shell wall which consists of an outer organic component (e.g., wrinkle layer, which is the first layer to be formed, and the subsequently formed dorsal inner prismatic layer. The dorsal mantle tissue suppresses the formation of the outer prismatic layer and nacreous layer. With the exception of the outer organic component, secretion of a shell wall is omitted at the aperture. A prismatic reduced dorsal shell wall is always secreted immediately after the hatching during early teleoconch formation. Due to its broad distribution in (planispiral Ammonoidea, the prismatic reduced dorsal shell wall is probably the general state. (ii Some planispirally coiled Ammonoidea have a nacreous reduced dorsal shell wall which consists of three mineralized layers: two prismatic layers (primary and secondary dorsal inner prismatic layer and an enclosed nacreous layer (secondary dorsal nacreous layer. The dorsal shell wall is omitted at the aperture and was secreted in the rear living chamber. Its layers are a continuation of an umbilical shell doubling (reinforcement by additional shell layers that extends towards the ventral crest of the preceding whorl. The nacreous reduced dorsal shell wall is formed in the process of ontogeny following a prismatic reduced dorsal shell wall. (iii Heteromorph and some planispirally coiled taxa secrete a complete dorsal shell wall which forms a continuation of the ventral and lateral shell layers. It is formed during ontogeny following a prismatic reduced dorsal shell wall or a priori. The construction is identical with the ventral and lateral shell wall, including a dorsal nacreous layer. The wide distribution of the ability to form dorsal nacre indicates that it is

Au@Ag core-shell nanocubes with finely tuned and well-controlled sizes, shell thicknesses, and optical properties.

Science.gov (United States)

Ma, Yanyun; Li, Weiyang; Cho, Eun Chul; Li, Zhiyuan; Yu, Taekyung; Zeng, Jie; Xie, Zhaoxiong; Xia, Younan

2010-11-23

This paper describes a facile method for generating Au@Ag core-shell nanocubes with edge lengths controllable in the range of 13.4-50 nm. The synthesis involved the use of single-crystal, spherical Au nanocrystals of 11 nm in size as the seeds in an aqueous system, with ascorbic acid serving as the reductant and cetyltrimethylammonium chloride (CTAC) as the capping agent. The thickness of the Ag shells could be finely tuned from 1.2 to 20 nm by varying the ratio of AgNO(3) precursor to Au seeds. We also investigated the growth mechanism by examining the effects of seeds (capped by CTAC or cetyltrimethylammonium bromide(CTAB)) and capping agent (CTAC vs CTAB) on both size and shape of the resultant core-shell nanocrystals. Our results clearly indicate that CTAC worked much better than CTAB as a capping agent in both the syntheses of Au seeds and Au@Ag core-shell nanocubes. We further studied the localized surface plasmon resonance properties of the Au@Ag nanocubes as a function of the Ag shell thickness. By comparing with the extinction spectra obtained from theoretical calculations, we derived a critical value of ca. 3 nm for the shell thickness at which the plasmon excitation of the Au cores would be completely screened by the Ag shells. Moreover, these Au@Ag core-shell nanocubes could be converted into Au-based hollow nanostructures containing the original Au seeds in the interiors through a galvanic replacement reaction.

Utilization possibilities of palm shell as a source of biomass energy in Malaysia by producing bio-oil in pyrolysis process

International Nuclear Information System (INIS)

Abnisa, Faisal; Daud, W.M.A. Wan; Husin, W.N.W.; Sahu, J.N.

2011-01-01

Agriculture residues such as palm shell are one of the biomass categories that can be utilized for conversion to bio-oil by using pyrolysis process. Palm shells were pyrolyzed in a fluidized-bed reactor at 400, 500, 600, 700 and 800 o C with N 2 as carrier gas at flow rate 1, 2, 3, 4 and 5 L/min. The objective of the present work is to determine the effects of temperature, flow rate of N 2 , particle size and reaction time on the optimization of production of renewable bio-oil from palm shell. According to this study the maximum yield of bio-oil (47.3 wt%) can be obtained, working at the medium level for the operation temperature (500 o C) and 2 L/min of N 2 flow rate at 60 min reaction time. Temperature is the most important factor, having a significant positive effect on yield product of bio-oil. The oil was characterized by Fourier Transform infra-red (FT-IR) spectroscopy and gas chromatography/mass spectrometry (GC-MS) techniques. -- Highlights: → This study reports the results of experimental investing of conversion palm shell into bio-oil by using pyrolysis and to find the optimum condition to produce the highest yield of bio-oil. → Several parameters which have effect to the process such as temperature, N 2 flow rate, reaction time and particle size is will be investigated in this study. → The outcome of this result will be important for abatement and control of increasingly waste palm shell storage problems any energy source to the world.

Ni(3)Si(Al)/a-SiO(x) core-shell nanoparticles: characterization, shell formation, and stability.

Science.gov (United States)

Pigozzi, G; Mukherji, D; Gilles, R; Barbier, B; Kostorz, G

2006-08-28

We have used an electrochemical selective phase dissolution method to extract nanoprecipitates of the Ni(3)Si-type intermetallic phase from two-phase Ni-Si and Ni-Si-Al alloys by dissolving the matrix phase. The extracted nanoparticles are characterized by transmission electron microscopy, energy-dispersive x-ray spectrometry, x-ray powder diffraction, and electron powder diffraction. It is found that the Ni(3)Si-type nanoparticles have a core-shell structure. The core maintains the size, the shape, and the crystal structure of the precipitates that existed in the bulk alloys, while the shell is an amorphous phase, containing only Si and O (SiO(x)). The shell forms around the precipitates during the extraction process. After annealing the nanoparticles in nitrogen at 700 °C, the tridymite phase recrystallizes within the shell, which remains partially amorphous. In contrast, on annealing in air at 1000 °C, no changes in the composition or the structure of the nanoparticles occur. It is suggested that the shell forms after dealloying of the matrix phase, where Si atoms, the main constituents of the shell, migrate to the surface of the precipitates.

Modification of MWCNT@TiO{sub 2} core–shell nanocomposites with transition metal oxide dopants for photoreduction of carbon dioxide into methane

Energy Technology Data Exchange (ETDEWEB)

Gui, Meei Mei [Low Carbon Economy (LCE) Group, Chemical Engineering Discipline, School of Engineering, Monash University, Jalan Lagoon Selatan, 46150 Bandar Sunway, Selangor (Malaysia); Chai, Siang-Piao, E-mail: chai.siang.piao@monash.edu [Low Carbon Economy (LCE) Group, Chemical Engineering Discipline, School of Engineering, Monash University, Jalan Lagoon Selatan, 46150 Bandar Sunway, Selangor (Malaysia); Mohamed, Abdul Rahman [Low Carbon Economy (LCE) Group, School of Chemical Engineering, Universiti Sains Malaysia, Engineering Campus, Seri Ampangan, 14300 Nibong Tebal, Pulau Pinang (Malaysia)

2014-11-15

Graphical abstract: - Highlights: • Metal oxide-doped MWCNT@TiO{sub 2} core–shell nanocomposites were prepared. • Red-shift of absorption band positions was observed in CuO- and Fe{sub 2}O{sub 3}-MWCNT@TiO{sub 2}. • Total methane formation of 0.93 μmol/g-catalyst was achieved using CuO-MWCNT@TiO{sub 2}. - Abstract: Titanium dioxide (TiO{sub 2}) doped with visible-light-responsive metal oxides has been widely reported for improving the visible light absorption performance of TiO{sub 2} and its photocatalytic activity. The metal oxides could function as ‘charge-carrier traps’ that transport electrons from TiO{sub 2} through the heterojunction of the TiO{sub 2}-metal oxides. In this work, the common transition metal oxides, i.e. FeO{sub x}, CuO{sub x}, NiO, CoO{sub x} and ZnO, were doped onto MWCNT@TiO{sub 2} core–shell nanocomposites. The effects of the metal oxide dopants on the photoactivity of the core–shell nanocomposites on CO{sub 2} reduction were studied. Characterization with diffuse-reflectance UV–vis showed significant improvement on visible light absorption after doping MWCNT@TiO{sub 2} with CuO{sub x}, FeO{sub x} and CoO{sub x} with the adsorption band-edge position red-shifted into the wavelength range of 480–630 nm. CuO-MWCNT@TiO{sub 2} appeared to be the most active one among all the studied photocatalysts, achieving a total methane formation of 0.93 μmol/g-catalyst.

A Lorentz covariant holoraumy-induced “gadget” from minimal off-shell 4D, N=1 supermultiplets

Energy Technology Data Exchange (ETDEWEB)

Gates, James S. Jr.; Grover, Tyler; Miller-Dickson, Miles David; Mondal, Benedict A.; Oskoui, Amir; Regmi, Shirash [Center for String and Particle Theory, Department of Physics, University of Maryland,College Park, MD 20742-4111 (United States); Ross, Ethan [Center for String and Particle Theory, Department of Physics, University of Maryland,College Park, MD 20742-4111 (United States); Department of Mathematics, University of Alberta, Edmonton, AB 3, T6G 2R3 (Canada); Shetty, Rajath [Center for String and Particle Theory, Department of Physics, University of Maryland,College Park, MD 20742-4111 (United States)

2015-11-17

Starting from three minimal off-shell 4D, N=1 supermultiplets, using constructions solely defined within the confines of the four dimensional field theory we show the existence of a “gadget” — a member of a class of metrics on the representation space of the supermultiplets — whose values directly and completely correspond to the values of a metric defined on the 1d, N=4 adinkra networks adjacency matrices corresponding to the projections of the four dimensional supermultiplets.

Radar attenuation in Europa's ice shell: obstacles and opportunities for constraining shell thickness and thermal structure

Science.gov (United States)

Kalousova, Klara; Schroeder, Dustin M.; Soderlund, Krista M.; Sotin, Christophe

2016-10-01

With its strikingly young surface and possibly recent endogenic activity, Europa is one of the most exciting bodies within our Solar System and a primary target for spacecraft exploration. Future missions to Europa are expected to carry ice penetrating radar instruments which are powerful tools to investigate the subsurface thermophysical structure of its ice shell.Several authors have addressed the 'penetration depth' of radar sounders at icy moons, however, the concept and calculation of a single value penetration depth is a potentially misleading simplification since it ignores the thermal and attenuation structure complexity of a realistic ice shell. Here we move beyond the concept of a single penetration depth by exploring the variation in two-way radar attenuation for a variety of potential thermal structures of Europa's ice shell as well as for a low loss and high loss temperature-dependent attenuation model. The possibility to detect brines is also investigated.Our results indicate that: (i) for all ice shell thicknesses investigated (5-30 km), a nominal satellite-borne radar sounder will penetrate between 15% and 100% of the total thickness, (ii) the maximum penetration depth strongly varies laterally with the deepest penetration possible through the cold downwellings, (iii) the direct detection of the ice/ocean interface might be possible for shells of up to 15 km if the radar signal travels through the cold downwelling, (iv) even if the ice/ocean interface is not detected, the penetration through most of the shell could constrain the deep shell structure through the loss of signal, and (v) for all plausible ice shells the two-way attenuation to the eutectic point is ≤30 dB which shows a robust potential for longitudinal investigation of the ice shell's shallow structure.Part of this work has been performed at the Jet Propulsion Laboratory, California Institute of Technology, under contract to NASA. K.K. acknowledges support by the Grant Agency of the

Stationary spherical shells around Kerr-Newman naked singularities

International Nuclear Information System (INIS)

Zdenek Stuchlik; Stanislav Hledik

1998-01-01

It is shown that in the field of some Kerr-Newman naked singularities a stationary spherical shell of charged dust can exist, with the specific charge being the same for all particles of the dusty shell. Gravitational attractions acting on the particles are balanced by electromagnetic repulsion in such a way that the shell is stable against radial perturbations. Particles of the shell move along orbits with constant latitude and radius. Rotation of the shell is differential. The shell is corotating relative to static observers at infinity, but it is counter rotating relative to the family of locally non-rotating observers. No such a shell can exist in the field of Kerr-Newman black holes. (authors)

Modeling plate shell structures using pyFormex

DEFF Research Database (Denmark)

Bagger, Anne; Verhegghe, Benedict; Hertz, Kristian Dahl

2009-01-01

A shell structure made of glass combines a light-weight structural concept with glass’ high permeability to light. If the geometry of the structure is plane-based facetted (plate shell structure), the glass elements will be plane panes, and these glass panes will comprise the primary load...... (plate shells and triangulated lattice shells) may not differ in complexity regarding the topology, but when it comes to the practical generation of the geometry, e.g. in CAD, the plate shell is far more troublesome to handle than the triangulated geometry. The free software tool “pyFormex”, developed...

The homeostasis of Plasmodium falciparum-infected red blood cells.

Directory of Open Access Journals (Sweden)

Jakob M A Mauritz

2009-04-01

Full Text Available The asexual reproduction cycle of Plasmodium falciparum, the parasite responsible for severe malaria, occurs within red blood cells. A merozoite invades a red cell in the circulation, develops and multiplies, and after about 48 hours ruptures the host cell, releasing 15-32 merozoites ready to invade new red blood cells. During this cycle, the parasite increases the host cell permeability so much that when similar permeabilization was simulated on uninfected red cells, lysis occurred before approximately 48 h. So how could infected cells, with a growing parasite inside, prevent lysis before the parasite has completed its developmental cycle? A mathematical model of the homeostasis of infected red cells suggested that it is the wasteful consumption of host cell hemoglobin that prevents early lysis by the progressive reduction in the colloid-osmotic pressure within the host (the colloid-osmotic hypothesis. However, two critical model predictions, that infected cells would swell to near prelytic sphericity and that the hemoglobin concentration would become progressively reduced, remained controversial. In this paper, we are able for the first time to correlate model predictions with recent experimental data in the literature and explore the fine details of the homeostasis of infected red blood cells during five model-defined periods of parasite development. The conclusions suggest that infected red cells do reach proximity to lytic rupture regardless of their actual volume, thus requiring a progressive reduction in their hemoglobin concentration to prevent premature lysis.

Amphiphilic core shell nanoparticles containing dense polyethyleneimine shells for efficient delivery of microRNA to Kupffer cells

Directory of Open Access Journals (Sweden)

Liu Z

2016-06-01

Full Text Available Zuojin Liu,1,* Dechao Niu,2,3,* Junyong Zhang,1 Wenfeng Zhang,1 Yuan Yao,2 Pei Li,2 Jianping Gong1 1Department of Hepatobiliary Surgery, The Second Affiliated Hospital of Chongqing Medical University, Chongqing, 2Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, 3Lab of Low-Dimensional Materials Chemistry, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, People’s Republic of China *These authors contributed equally to this work Abstract: Efficient and targeted delivery approach to transfer exogenous genes into macrophages is still a great challenge. Current gene delivery methods often result in low cellular uptake efficiency in vivo in some types of cells, especially for the Kupffer cells (KCs. In this article, we demonstrate that amphiphilic core–shell nanoparticles (NPs consisting of well-defined hydrophobic poly(methyl methacrylate (PMMA cores and branched polyethyleneimine (PEI shells (denoted as PEI@PMMA NPs are efficient nanocarriers to deliver microRNA (miRNA-loaded plasmid to the KCs. Average hydrodynamic diameter of PEI@PMMA NPs was 279 nm with a narrow size distribution. The NPs also possessed positive surface charges up to +30 mV in water, thus enabling effective condensation of negatively charged plasmid DNA. Gel electrophoresis assay showed that the resultant PEI@PMMA NPs were able to completely condense miRNA plasmid at a weight ratio of 25:1 (N/P ratio equal to 45:1. The Cell Counting Kit-8 assay and flow cytometry results showed that the PEI@PMMA/miRNA NPs displayed low cytotoxicity and cell apoptosis activity against the KCs. The maximum cell transfection efficiency reached 34.7% after 48 hours, which is much higher than that obtained by using the commercial Lipofectamine™ 2000 (1.7%. Bio-transmission electron microscope observation revealed that the PEI@PMMA NPs were mainly distributed in

Intrinsic Density Matrices of the Nuclear Shell Model

International Nuclear Information System (INIS)

Deveikis, A.; Kamuntavichius, G.

1996-01-01

A new method for calculation of shell model intrinsic density matrices, defined as two-particle density matrices integrated over the centre-of-mass position vector of two last particles and complemented with isospin variables, has been developed. The intrinsic density matrices obtained are completely antisymmetric, translation-invariant, and do not employ a group-theoretical classification of antisymmetric states. They are used for exact realistic density matrix expansion within the framework of the reduced Hamiltonian method. The procedures based on precise arithmetic for calculation of the intrinsic density matrices that involve no numerical diagonalization or orthogonalization have been developed and implemented in the computer code. (author). 11 refs., 2 tabs

Core–shell interaction and its impact on the optical absorption of pure and doped core-shell CdSe/ZnSe nanoclusters

Energy Technology Data Exchange (ETDEWEB)

Wang, Xinqin; Cui, Yingqi; Zeng, Qun; Yang, Mingli, E-mail: myang@scu.edu.cn [Institute of Atomic and Molecular Physics, Key Laboratory of High Energy Density Physics and Technology of Ministry of Education, Sichuan University, Chengdu 610065 (China); Yu, Shengping [College of Chemistry and Environment Protection Engineering, Southwest University for Nationalities, Chengdu 610041 (China)

2016-04-07

The structural, electronic, and optical properties of core-shell nanoclusters, (CdSe){sub x}@(CdSe){sub y} and their Zn-substituted complexes of x = 2–4 and y = 16–28, were studied with density functional theory calculations. The substitution was applied in the cores, the shells, and/or the whole clusters. All these clusters are characterized by their core-shell structures in which the core-shell interaction was found different from those in core or in shell, as reflected by their bondlengths, volumes, and binding energies. Moreover, the core and shell combine together to compose a new cluster with electronic and optical properties different from those of separated individuals, as reflected by their HOMO-LUMO gaps and optical absorptions. With the substitution of Cd by Zn, the structural, electronic, and optical properties of clusters change regularly. The binding energy increases with Zn content, attributed to the strong Zn–Se bonding. For the same core/shell, the structure with a CdSe shell/core has a narrower gap than that with a ZnSe shell/core. The optical absorption spectra also change accordingly with Zn substitution. The peaks blueshift with increasing Zn concentration, accompanying with shape variations in case large number of Cd atoms are substituted. Our calculations reveal the core-shell interaction and its influence on the electronic and optical properties of the core-shell clusters, suggesting a composition–structure–property relationship for the design of core-shell CdSe and ZnSe nanoclusters.

Some Differential Geometric Relations in the Elastic Shell

Directory of Open Access Journals (Sweden)

Xiaoqin Shen

2016-01-01

Full Text Available The theory of the elastic shells is one of the most important parts of the theory of solid mechanics. The elastic shell can be described with its middle surface; that is, the three-dimensional elastic shell with equal thickness comprises a series of overlying surfaces like middle surface. In this paper, the differential geometric relations between elastic shell and its middle surface are provided under the curvilinear coordinate systems, which are very important for forming two-dimensional linear and nonlinear elastic shell models. Concretely, the metric tensors, the determinant of metric matrix field, the Christoffel symbols, and Riemann tensors on the three-dimensional elasticity are expressed by those on the two-dimensional middle surface, which are featured by the asymptotic expressions with respect to the variable in the direction of thickness of the shell. Thus, the novelty of this work is that we can further split three-dimensional mechanics equations into two-dimensional variation problems. Finally, two kinds of special shells, hemispherical shell and semicylindrical shell, are provided as the examples.

Eggshell Biliverdin and Protoporphyrin Pigments in a Songbird: Are They Derived from Erythrocytes, Blood Plasma, or the Shell Gland?

Science.gov (United States)

Hargitai, Rita; Boross, Nóra; Hámori, Susanne; Neuberger, Eszter; Nyiri, Zoltán

Biliverdin and protoporphyrin pigments are deposited into the eggshell when the developing egg is in the shell gland. However, the site of synthesis of eggshell pigments is still uncertain, although it may influence the possible costs and potential functions of eggshell coloration in avian species. Eggshell pigments may be derived from red blood cells or be produced in other organs and then transferred to the shell gland, or they may be synthesized de novo in the shell gland. We studied in the canary (Serinus canaria) whether eggshell blue-green and brown pigmentations are associated with experimentally elevated anemia, female hematocrit level, immature erythrocyte percentage, and feces and plasma pigment levels during egg laying to find out the possible origin of eggshell pigments. We found no significant effects of hematocrit level or experimentally elevated anemia on intensity of eggshell blue-green and brown pigmentations; therefore, we consider it less likely that eggshell pigments are derived from erythrocytes. In addition, we found no significant associations between female feces biliverdin concentration during egg laying and intensity of eggshell blue-green pigmentation, suggesting that eggshell biliverdin may not originate from the spleen or liver. We found a negative association between plasma and feces protoporphyrin concentrations during egg laying and eggshell brown chroma. This result suggests that an increased production of protoporphyrin in the liver, which could have elevated plasma and feces protoporphyrin concentrations, could inhibit eggshell protoporphyrin pigmentation, probably through affecting enzymatic activities. We suggest that both pigments are produced de novo in the shell gland in the canary, but circulating pigment levels may influence shell gland pigment synthesis, thus connecting the physiological status of the female to eggshell coloration.

Studies on the bio production of monascus red pigment

International Nuclear Information System (INIS)

Emam, D.A.

2007-01-01

there is an increasing interest on natural pigments to replace some currently used synthetic dyes, since the latter have been associated with toxic effects in foods. the red pigment of the fungus Monascus is widely used in all the world as food additives or pharmaceuticals. although pigment production by Monascus spp.in chemically defined media is well documented, very few information is available about the use of agro-industrial wastes. in this regard, the present study has been devoted to investigate the effect of different parameters on red pigment production by the local isolated strain of M. purpureu, in an attempt to maximize the production, and also to develop a potential fermentation process for the production of red pigment using potato processing wastewater (PPW,waters used to wash the potato slices prior to cooking in chips and crisp manufacture) as cheap production medium

Determination of shell energies. Nuclear deformations and fission barriers

International Nuclear Information System (INIS)

Koura, Hiroyuki; Tachibana, Takahiro; Uno, Masahiro; Yamada, Masami.

1996-01-01

We have been studying a method of determining nuclear shell energies and incorporating them into a mass formula. The main feature of this method lies in estimating shell energies of deformed nuclei from spherical shell energies. We adopt three assumptions, from which the shell energy of a deformed nucleus is deduced to be a weighted sum of spherical shell energies of its neighboring nuclei. This shell energy should be called intrinsic shell energy since the average deformation energy also acts as an effective shell energy. The ground-state shell energy of a deformed nucleus and its equilibrium shape can be obtained by minimizing the sum of these two energies with respect to variation of deformation parameters. In addition, we investigate the existence of fission isomers for heavy nuclei with use of the obtained shell energies. (author)

Lessons Not Learned. The Other Shell Report 2004

International Nuclear Information System (INIS)

Harden, M.; Walker, N.; Griffiths, H.; Verweij, M.

2005-06-01

The third alternative Shell Corporate Social Responsibility (CSR) report is presented on behalf of several of the many communities that live on Shell's 'fencelines', next to Shell's refineries, depots and pipelines. This 2004 report builds on reports of the past two years 'Failing the Challenge', (2002) and 'Behind the Shine' (2003) which chronicled Shell's impacts around the world. It gives critical updates of Shell's performance over the past year

Salinity controls on Na incorporation in Red Sea planktonic foraminifera

Science.gov (United States)

Mezger, E. M.; de Nooijer, L. J.; Boer, W.; Brummer, G. J. A.; Reichart, G. J.

2016-12-01

Whereas several well-established proxies are available for reconstructing past temperatures, salinity remains challenging to assess. Reconstructions based on the combination of (in)organic temperature proxies and foraminiferal stable oxygen isotopes result in relatively large uncertainties, which may be reduced by application of a direct salinity proxy. Cultured benthic and planktonic foraminifera showed that Na incorporation in foraminiferal shell calcite provides a potential independent proxy for salinity. Here we present the first field calibration of such a potential proxy. Living planktonic foraminiferal specimens from the Red Sea surface waters were collected and analyzed for their Na/Ca content using laser ablation quadrupole inductively coupled plasma mass spectrometry. Using the Red Sea as a natural laboratory, the calibration covers a broad range of salinities over a steep gradient within the same water mass. For both Globigerinoides ruber and Globigerinoides sacculifer calcite Na/Ca increases with salinity, albeit with a relatively large intraspecimen and interspecimen variability. The field-based calibration is similar for both species from a salinity of 36.8 up to 39.6, while values for G. sacculifer deviate from this trend in the northernmost transect. It is hypothesized that the foraminifera in the northernmost part of the Red Sea are (partly) expatriated and hence should be excluded from the Na/Ca-salinity calibration. Incorporation of Na in foraminiferal calcite therefore provides a potential proxy for salinity, although species-specific calibrations are still required and more research on the effect of temperature is needed.

Red blood cells and polyelectrolyte multilayer capsules: natural carriers versus polymer-based drug delivery vehicles.

Science.gov (United States)

Kolesnikova, Tatiana A; Skirtach, Andre G; Möhwald, Helmuth

2013-01-01

Red blood cells (RBCs) and lipid-based carriers on the one hand and polymeric capsules on the other hand represent two of the most widely used carriers in drug delivery. Each class of these carriers has its own set of properties, specificity and advantages. Thorough comparative studies of such systems are reported here for the first time. In this review, RBCs are described in comparison with synthetic polymeric drug delivery vehicles using polyelectrolyte multilayer capsules as an example. Lipid-based composition of the shell in the former case is particularly attractive due to their inherent biocompatibility and flexibility of the carriers. On the other hand, synthetic approaches to fabrication of polyelectrolyte multilayer capsules permit manipulation of the permeability of their shell as well as tuning their composition, mechanical properties, release methods and targeting. In conclusion, properties of RBCs and polyelectrolyte multilayer capsules are reported here highlighting similarities and differences in their preparation and applications. In addition, their advantages and disadvantages are discussed.

Synthesis and Characterization of SiO2@Y2MoO6:Eu3+ Core-Shell Structured Spherical Phosphors by Sol-Gel Process.

Science.gov (United States)

Li, G Z; Liu, F H; Chu, Z S; Wu, D M; Yang, L B; Li, J L; Wang, M N; Wang, Z L

2016-04-01

SiO2@Y2MoO6:Eu3+ core-shell phosphors were prepared by the sol-gel process. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectra (EDS), transmission electron microscopy (TEM), photoluminescence (PL) spectra as well as kinetic decays were used to characterize the resulting SiO2@Y2MoO6:Eu3+ core-shell phosphors. The XRD results demonstrated that the Y2MoO6:Eu3+ layers on the SiO2 spheres crystallized after being annealed at 700 °C and the crystallinity increased with raising the annealing temperature. The obtained core-shell phosphors have spherical shape with narrow size distribution (average size ca. 640 nm), non-agglomeration, and smooth surface. The thickness of the Y2MoO6:Eu3+ shells on the SiO2 cores could be easily tailored by varying the number of deposition cycles (70 nm for four deposition cycles). The Eul+ shows a strong PL emission (dominated by 5D0-7F2 red emission at 614 nm) under the excitation of 347 nm UV light. The PL intensity of Eu3+ increases with increasing the annealing temperature and the number of coating cycles.

Properties of concrete containing coconut shell powder (CSP) as a filler

Science.gov (United States)

Leman, A. S.; Shahidan, S.; Nasir, A. J.; Senin, M. S.; Zuki, S. S. Mohd; Ibrahim, M. H. Wan; Deraman, R.; Khalid, F. S.; Azhar, A. T. S.

2017-11-01

Coconut shellsare a type of agricultural waste which can be converted into useful material. Therefore,this study was conducted to investigate the properties of concrete which uses coconut shell powder (CSP) filler material and to define the optimum percentage of CSP which can be used asfiller material in concrete. Comparisons have been made between normal concrete mixes andconcrete containing CSP. In this study, CSP was added into concrete mixes invaryingpercentages (0%, 2%, 4%, 6%, 8% and 10%). The coconut shell was grounded into afine powder before use. Experimental tests which have been conducted in this study include theslump test, compressive test and splitting tensile strength test. CSP have the potential to be used as a concrete filler and thus the findings of this study may be applied to the construction industry. The use of CSP as a filler in concrete can help make the earth a more sustainable and greener place to live in.

Sexual selection on land snail shell ornamentation: a hypothesis that may explain shell diversity

NARCIS (Netherlands)

Schilthuizen, M.

2003-01-01

Background: Many groups of land snails show great interspecific diversity in shell ornamentation, which may include spines on the shell and flanges on the aperture. Such structures have been explained as camouflage or defence, but the possibility that they might be under sexual selection has not

Shell coal gasification process

Energy Technology Data Exchange (ETDEWEB)

Hennekes, B. [Shell Global Solutions (US) Inc. (United States). Technology Marketing

2002-07-01

The presentation, on which 17 slides/overheads are included in the papers, explained the principles of the Shell coal gasification process and the methods incorporated for control of sulfur dioxide, nitrogen oxides, particulates and mercury. The economics of the process were discussed. The differences between gasification and burning, and the differences between the Shell process and other processes were discussed.

Cylindrical thin-shell wormholes

International Nuclear Information System (INIS)

Eiroa, Ernesto F.; Simeone, Claudio

2004-01-01

A general formalism for the dynamics of nonrotating cylindrical thin-shell wormholes is developed. The time evolution of the throat is explicitly obtained for thin-shell wormholes whose metric has the form associated with local cosmic strings. It is found that the throat collapses to zero radius, remains static, or expands forever, depending only on the sign of its initial velocity

Standardized CSR and climate performance: why is Shell willing, but Hydro reluctant?; Shell; Hydro

Energy Technology Data Exchange (ETDEWEB)

Boasson, Elin Lerum; Wettestad, Joergen

2007-06-15

This report aims to contribute to the ongoing discussion concerning whether CSR merely serves to streamline company rhetoric or also has an influence on actual efforts. We discuss the tangible effects of CSR instruments on the climate-related rules and performances of the two different oil companies Hydro and Shell. First we explore whether similar CSR instruments lead to similar climate-related rules and practices in the two companies. Both Hydro and Shell adhere to the Global Compact (GC), the Global Reporting Initiative (GRI), the Carbon Disclosure Project (CDP) and the Global Gas Flaring Reduction Public-Private Partnership (GGFR). The report concludes that the GC has not rendered any tangible effects in either of the companies. Concerning the other instruments, Hydro has only followed the instrument requirements that fit their initial approach, and refrained from all deviating requirements. Shell has been more malleable, but we have noted few effects on the actual emissions and business portfolio resulting from the instrument adherence. Second, we assess how the differing results of the similar CSR portfolio may be explained. The reluctant attitude of the leaders in Hydro and the strong CSR motivation of Shell's executives result in significant differences. Hydro executives are able to constrain the effects of the instrument adherence. With Shell we note the opposite pattern: Its leaders promoted the instruments to be translated into internal rules, but a general lack of hierarchical structures hinders them from governing the conduct of various sub-organisations. The very diversity of the Shell culture helps to explain why the efforts of its executives have resulted in limited impact. The strength of the Hydro culture makes the corporation resistant to the instruments. Moreover, Hydro is strikingly shielded by virtue of its strong position in Norway. In contrast, Shell is more strongly affected by the global field of petroleum and the global field of CSR

The influence of MOVPE growth conditions on the shell of core-shell GaN microrod structures

Science.gov (United States)

Schimpke, Tilman; Avramescu, Adrian; Koller, Andreas; Fernando-Saavedra, Amalia; Hartmann, Jana; Ledig, Johannes; Waag, Andreas; Strassburg, Martin; Lugauer, Hans-Jürgen

2017-05-01

A core-shell geometry is employed for most next-generation, three-dimensional opto-electric devices based on III-V semiconductors and grown by metal organic vapor phase epitaxy (MOVPE). Controlling the shape of the shell layers is fundamental for device optimization, however no detailed analysis of the influence of growth conditions has been published to date. We study homogeneous arrays of gallium nitride core-shell microrods with height and diameter in the micrometer range and grown in a two-step selective area MOVPE process. Changes in shell shape and homogeneity effected by deliberately altered shell growth conditions were accurately assessed by digital analysis of high-resolution scanning electron microscope images. Most notably, two temperature regimes could be established, which show a significantly different behavior with regard to material distribution. Above 900 °C of wafer carrier temperature, the shell thickness along the growth axis of the rods was very homogeneous, however variations between vicinal rods increase. In contrast, below 830 °C the shell thickness is higher close to the microrod tip than at the base of the rods, while the lateral homogeneity between neighboring microrods is very uniform. This temperature effect could be either amplified or attenuated by changing the remaining growth parameters such as reactor pressure, structure distance, gallium precursor, carrier gas composition and dopant materials. Possible reasons for these findings are discussed with respect to GaN decomposition as well as the surface and gas phase diffusion of growth species, leading to an improved control of the functional layers in next-generation 3D V-III devices.

Green synthesis of CuInS2/ZnS core-shell quantum dots by facile solvothermal route with enhanced optical properties

Science.gov (United States)

Jindal, Shikha; Giripunje, Sushama M.; Kondawar, Subhash B.; Koinkar, Pankaj

2018-03-01

We report an eco-friendly green synthesis of highly luminescent CuInS2/ZnS core-shell quantum dots (QDs) with average particle size ∼ 3.9 nm via solvothermal process. The present study embodies the intensification of CuInS2/ZnS QDs properties by the shell growth on the CuInS2 QDs. The as-prepared CuInS2 core and CuInS2/ZnS core-shell QDs have been characterized using a range of optical and structural techniques. By adopting a low temperature growth of CuInS2 core and high temperature growth of CuInS2/ZnS core-shell growth, the tuning of absorption and photoluminescence emission spectra were observed. Optical absorption and photoluminescence spectroscopy probe the effect of ZnS passivation on the electronic structure of the CuInS2 dots. In addition, QDs have been scrutinized using ultra violet photoelectron spectroscopy (UPS) to explore their electronic band structure. The band level positions of CuInS2 and CuInS2/ZnS QDs suffices the demand of non-toxic acceptor material for electronic devices. The variation in electronic energy levels of CuInS2 core with the coating of wide band gap ZnS shell influence the removal of trap assisted recombination on the surface of the core. QDs exhibited tunable emission from red to orange region. These studies reveal the feasibility of QDs in photovoltaic and light emitting diodes.

Safety studies conducted on pecan shell fiber, a food ingredient produced from ground pecan shells

Directory of Open Access Journals (Sweden)

Laurie Dolan

Full Text Available Use of pecan shell fiber in human food is presently limited, but could increase pending demonstration of safety. In a 91-day rat study, pecan shell fiber was administered at dietary concentrations of 0 (control, 50 000, 100 000 or 150 000 ppm. There was no effect of the ingredient on body weight of males or females or food consumption of females. Statistically significant increases in food consumption were observed throughout the study in 100 000 and 150 000 ppm males, resulting in intermittent decreases in food efficiency (150 000 ppm males only that were not biologically relevant. All animals survived and no adverse clinical signs or functional changes were attributable to the test material. There were no toxicologically relevant changes in hematology, clinical chemistry or urinalysis parameters or organ weights in rats ingesting pecan shell fiber. Any macroscopic or microscopic findings were incidental, of normal variation and/or of minimal magnitude for test substance association. Pecan shell fiber was non-mutagenic in a bacterial reverse mutation test and non-clastogenic in a mouse peripheral blood micronucleus test. Based on these results, pecan shell fiber has an oral subchronic (13-week no observable adverse effect level (NOAEL of 150 000 ppm in rats and is not genotoxic at the doses analyzed. Keywords: Pecan shell, Fiber, Rat, Diet, Toxicity, Mutagenicity

Electron spin resonance dating of shells from the sambaqui (shell mound) Capelinha, Sao Paulo, Brazil

International Nuclear Information System (INIS)

Kinoshita, A.; Figuty, L.; Baffa, O.

2006-01-01

Capelinha is a fluvial sambaqui (Brazilian Shell Mound) located in the Ribeira Valley in the State of Sao Paulo that is being studied. It is one of the oldest sambaquis located along a river dated so far in this region. The use of ESR to date other shells stimulated our group to apply this method to the Capelinha site. Shells from land snails (Megalobulimus sp.) obtained in two levels of excavations were analyzed; one of them was in contact with a skeleton that was dated by C-14. The archaeological doses obtained were (8.05±0.07) Gy and (9.50±0.03) Gy. Since the last site was previously dated by C-14 (Beta -Analytics, Beta 153988) giving: 8860 +/- 60 years BP (conventional age) and 10180 to 9710 years BP (calibrated age), the archaeological dose found for this shell was used to determine the local rate of (0.93 to 0.98) mGy/year, that aggress with other surveys done in the region. Using this dose rate the age of the second shell was found to be 8.14 to 8.73 ky BP that agrees with the stratigraphy of the site. (author)

Soft template synthesis of yolk/silica shell particles.

Science.gov (United States)

Wu, Xue-Jun; Xu, Dongsheng

2010-04-06

Yolk/shell particles possess a unique structure that is composed of hollow shells that encapsulate other particles but with an interstitial space between them. These structures are different from core/shell particles in that the core particles are freely movable in the shell. Yolk/shell particles combine the properties of each component, and can find potential applications in catalysis, lithium ion batteries, and biosensors. In this Research News article, a soft-template-assisted method for the preparation of yolk/silica shell particles is presented. The demonstrated method is simple and general, and can produce hollow silica spheres incorporated with different particles independent of their diameters, geometry, and composition. Furthermore, yolk/mesoporous silica shell particles and multishelled particles are also prepared through optimization of the experimental conditions. Finally, potential applications of these particles are discussed.

Antioxidant and Antihypertensive Effects of a Chemically Defined Fraction of Syrah Red Wine on Spontaneously Hypertensive Rats.

Science.gov (United States)

Figueiredo, Eugênia Abrantes de; Alves, Naiane Ferraz Bandeira; Monteiro, Matheus Morais de Oliveira; Cavalcanti, Clenia de Oliveira; Silva, Tania Maria Sarmento da; Silva, Telma Maria Guedes da; Braga, Valdir de Andrade; Oliveira, Eduardo de Jesus

2017-06-03

A particularly phenolic-rich fraction extracted from red wine from the São Francisco valley (Northeastern Brazil) was chemically characterized and its hypotensive and antioxidant effects on spontaneously hypertensive rats were studied both in vitro and in vivo. The liquid-liquid pH dependent fractionation scheme afforded a fraction with high content of bioactive phenolics such as flavonols, flavonol glycosides, phenolic acids and anthocyanins, whose identities were confirmed by liquid chromatography coupled to mass spectrometry analysis. Pretreatment of spontaneously hypertensive rats with this wine fraction at doses of 50 and 100 mg/kg by gavage. for 15 days was able to decrease mean arterial pressure and heart rate as well as decrease serum lipid peroxidation. The fraction at concentrations of 0.01-1000 µg/mL induced concentration-dependent relaxation of isolated rat superior mesenteric artery rings pre-contracted with phenylephrine and this effect was not attenuated by endothelium removal. Our results demonstrate it is possible for phenolic constituents of red wine that are orally bioavailable to exert in vivo hypotensive and antioxidant effects on intact endothelial function.

Antioxidant and Antihypertensive Effects of a Chemically Defined Fraction of Syrah Red Wine on Spontaneously Hypertensive Rats

Directory of Open Access Journals (Sweden)

Eugênia Abrantes de Figueiredo

2017-06-01

Full Text Available A particularly phenolic-rich fraction extracted from red wine from the São Francisco valley (Northeastern Brazil was chemically characterized and its hypotensive and antioxidant effects on spontaneously hypertensive rats were studied both in vitro and in vivo. The liquid-liquid pH dependent fractionation scheme afforded a fraction with high content of bioactive phenolics such as flavonols, flavonol glycosides, phenolic acids and anthocyanins, whose identities were confirmed by liquid chromatography coupled to mass spectrometry analysis. Pretreatment of spontaneously hypertensive rats with this wine fraction at doses of 50 and 100 mg/kg by gavage. for 15 days was able to decrease mean arterial pressure and heart rate as well as decrease serum lipid peroxidation. The fraction at concentrations of 0.01–1000 µg/mL induced concentration-dependent relaxation of isolated rat superior mesenteric artery rings pre-contracted with phenylephrine and this effect was not attenuated by endothelium removal. Our results demonstrate it is possible for phenolic constituents of red wine that are orally bioavailable to exert in vivo hypotensive and antioxidant effects on intact endothelial function.

WHAT IS THE SHELL AROUND R CORONAE BOREALIS?

Energy Technology Data Exchange (ETDEWEB)

Montiel, Edward J.; Clayton, Geoffrey C.; Marcello, Dominic C. [Dept. of Physics and Astronomy, Louisiana State University, Baton Rouge, LA 70803 (United States); Lockman, Felix J., E-mail: emonti2@lsu.edu, E-mail: gclayton@fenway.phys.lsu.edu, E-mail: dmarce1@tigers.lsu.edu, E-mail: jlockman@nrao.edu [National Radio Astronomy Observatory, Green Bank, WV 24944 (United States)

2015-07-15

The hydrogen-deficient, carbon-rich R Coronae Borealis (RCB) stars are known for being prolific producers of dust which causes their large iconic declines in brightness. Several RCB stars, including R Coronae Borealis (R CrB), itself, have large extended dust shells seen in the far-infrared. The origin of these shells is uncertain but they may give us clues to the evolution of the RCB stars. The shells could form in three possible ways. (1) They are fossil Planetary Nebula (PN) shells, which would exist if RCB stars are the result of a final, helium-shell flash, (2) they are material left over from a white-dwarf (WD) merger event which formed the RCB stars, or (3) they are material lost from the star during the RCB phase. Arecibo 21 cm observations establish an upper limit on the column density of H I in the R CrB shell implying a maximum shell mass of ≲0.3 M{sub ☉}. A low-mass fossil PN shell is still a possible source of the shell although it may not contain enough dust. The mass of gas lost during a WD merger event will not condense enough dust to produce the observed shell, assuming a reasonable gas-to-dust ratio. The third scenario where the shell around R CrB has been produced during the star’s RCB phase seems most likely to produce the observed mass of dust and the observed size of the shell. But this means that R CrB has been in its RCB phase for ∼10{sup 4} years.

Studies on Freezing of Shell-Fish-I

Science.gov (United States)

Song, Dae Jin; Konagaya, Shiro; Tanaka, Takeo

Ark shell, Anadara broughtonii(Shrenk), are commonly eaten raw or under-done in Korea, Japan, and East Asian countries. Along with a recent remarkable development of culture fisheries, Ark shell has become one of the commercially important shell-fish species. Transportation and storage of large quantities of shell-fish is becoming increasingly important. This work was begun with this background to make clear the effects of temperature and length of storage time on the quality of frozen stored ark shell. Results are as follows : (1) There was little chang in amounts of free and expressible drip from ark shell flesh frozen stored at -40°CdegC for 6 months. Water holding capacity of the same meat was almost constant over 6 months storage. However, a mounts of both drip increased markedly after 2 months storage at -10°C. (2) Protein extractibility of ark shell flesh tended to decrease gradually from the begining when stored at -10°C, while at -20°C, the protein extractibility was stable for 3 months before decreasing gradually. However at -40°C, the protein extractibility was stable for 6 months. It was found that paramyosin was very stable even when the ark shell was frozen stored at -10°C. (3) It was observed that ark shell flesh became tough when frozen. The toughness of ark shell flesh as measured by an instrument increased with frozen storage time and increased temperature. (4) In the smooth muscle, it was histologically observed that initial small ice crystals formed between muscle bundles grew larger during frozen storage. It was found that the higher the storage temperature, the bigger the ice crystals formed. Aggregation of some muscle fiber and empty spaces between muscle bundles were observd after thawed muscles frozen stored at relatively high temperature such as -10°C.

Atomistic tight-binding computations of the structural and optical properties of CdTe/CdX (X=S and Se)/ZnS core/shell/shell nanocrystals

Science.gov (United States)

Sukkabot, Worasak

2018-05-01

A study of CdTe/CdX (X=S and Se)/ZnS core/shell/shell nanocrystals is carried out using atomistic tight-binding theory and the configuration interaction method to provide information for applications in bioimaging, biolabeling, display devices and near-infrared electronic instruments. The calculations yield the dependences of the internal and external passivated shells on the natural behaviours of CdTe/CdX (X=S and Se)/ZnS core/shell/shell nanocrystals. The reduction of the optical band gaps is observed with increasing numbers of monolayers in the external ZnS shell due to quantum confinement. Interestingly, the optical band gaps of CdTe/CdS/ZnS core/shell/shell nanocrystals are greater than those of CdTe/CdSe/ZnS core/shell/shell nanocrystals. In the presence of an external ZnS-coated shell, electron-hole wave function overlaps, oscillation strengths, ground-state exchange energies and Stokes shift are improved, whereas ground-state coulomb energies and fine-structure splitting are reduced. The oscillation strengths, Stokes shift and fine-structure splitting are reduced with the increase in external ZnS shell thickness. The oscillation strengths, Stokes shift and fine-structure splitting of CdTe/CdS/ZnS core/shell/shell nanocrystals are larger than those of CdTe/CdSe/ZnS core/shell/shell nanocrystals. Reduction of the atomistic electron-hole interactions is observed with increasing external ZnS shell size. The strong electron-hole interactions are more probed in CdTe/CdS/ZnS core/shell/shell nanocrystals than in CdTe/CdSe/ZnS core/shell/shell nanocrystals.

Development of Mortar Simulator with Shell-In-Shell System – Problem of External Ballistics

Directory of Open Access Journals (Sweden)

A. Fedaravicius

2007-01-01

Full Text Available The shell-in-shell system used in the mortar simulator raises a number of non-standard technical and computational problems starting from the requirement to distribute the propelling blast energy between the warhead and the ballistic barrel, finishing with the requirement that the length of warhead's flight path must be scaled to combat shell firing tables. The design problem of the simulator is split into two parts – the problem of external ballistics where the initial velocities of the warhead must be determined, and the problem of internal ballistics – where the design of the cartridge and the ballistic barrel must be performed.

Three-dimensional flat shell-to-shell coupling: numerical challenges

Science.gov (United States)

Guo, Kuo; Haikal, Ghadir

2017-11-01

The node-to-surface formulation is widely used in contact simulations with finite elements because it is relatively easy to implement using different types of element discretizations. This approach, however, has a number of well-known drawbacks, including locking due to over-constraint when this formulation is used as a twopass method. Most studies on the node-to-surface contact formulation, however, have been conducted using solid elements and little has been done to investigate the effectiveness of this approach for beam or shell elements. In this paper we show that locking can also be observed with the node-to-surface contact formulation when applied to plate and flat shell elements even with a singlepass implementation with distinct master/slave designations, which is the standard solution to locking with solid elements. In our study, we use the quadrilateral four node flat shell element for thin (Kirchhoff-Love) plate and thick (Reissner-Mindlin) plate theory, both in their standard forms and with improved formulations such as the linked interpolation [1] and the Discrete Kirchhoff [2] elements for thick and thin plates, respectively. The Lagrange multiplier method is used to enforce the node-to-surface constraints for all elements. The results show clear locking when compared to those obtained using a conforming mesh configuration.

Three-dimensional flat shell-to-shell coupling: numerical challenges

Directory of Open Access Journals (Sweden)

Guo Kuo

2017-11-01

Full Text Available The node-to-surface formulation is widely used in contact simulations with finite elements because it is relatively easy to implement using different types of element discretizations. This approach, however, has a number of well-known drawbacks, including locking due to over-constraint when this formulation is used as a twopass method. Most studies on the node-to-surface contact formulation, however, have been conducted using solid elements and little has been done to investigate the effectiveness of this approach for beam or shell elements. In this paper we show that locking can also be observed with the node-to-surface contact formulation when applied to plate and flat shell elements even with a singlepass implementation with distinct master/slave designations, which is the standard solution to locking with solid elements. In our study, we use the quadrilateral four node flat shell element for thin (Kirchhoff-Love plate and thick (Reissner-Mindlin plate theory, both in their standard forms and with improved formulations such as the linked interpolation [1] and the Discrete Kirchhoff [2] elements for thick and thin plates, respectively. The Lagrange multiplier method is used to enforce the node-to-surface constraints for all elements. The results show clear locking when compared to those obtained using a conforming mesh configuration.

Structural shell analysis understanding and application

CERN Document Server

Blaauwendraad, Johan

2014-01-01

The mathematical description of the properties of a shell is much more elaborate than those of beam and plate structures. Therefore many engineers and architects are unacquainted with aspects of shell behaviour and design, and are not familiar with sufficiently reliable shell theories for the different shell types as derived in the middle of the 20th century. Rather than contributing to theory development, this university textbook focuses on architectural and civil engineering schools. Of course, practising professionals will profit from it as well. The book deals with thin elastic shells, in particular with cylindrical, conical and spherical types, and with elliptic and hyperbolic paraboloids. The focus is on roofs, chimneys, pressure vessels and storage tanks. Special attention is paid to edge bending disturbance zones, which is indispensable knowledge in FE meshing. A substantial part of the book results from research efforts in the mid 20th century at Delft University of Technology. As such, it is a valua...

Thermoluminescence analysis of irradiated oyster shells

International Nuclear Information System (INIS)

Cruz-Zaragoza, E.; Marcazzó, J.; Della Monaca, S.; Boniglia, C.; Gargiulo, R.; Bortolin, E.

2012-01-01

This paper reports the thermoluminescence (TL) analysis performed on the oyster shells powder. TL response of 60 Co gamma-rays irradiated samples were studied in the range from 80 Gy to 8 kGy doses. TL signal of irradiated shell powder was higher as compared to the unirradiated control samples, which allowed to identify the irradiated oysters. Results show that the oyster shells have good TL properties and can be useful for the identification of irradiated seafood as well as for the evaluation of the treatment dose. - Highlights: ► TL properties of irradiated oyster shell powder were studied. ► The SEM analysis shows that several elements are present in oyster shell powder. ► Calcite is the main component in the samples and β-calcite is also present. ► Following the European Standard EN 1788, the irradiated oyster can be identified. ► Determination of absorbed dose is possible by performing a preheat treatment.

On the growth and photocatalytic activity of the vertically aligned ZnO nanorods grafted by CdS shells

Science.gov (United States)

Zirak, M.; Moradlou, O.; Bayati, M. R.; Nien, Y. T.; Moshfegh, A. Z.

2013-05-01

We have studied systematically photocatalytic properties of the vertically aligned ZnO@CdS core-shell nanorods where the features were grown through a multistep procedure including sol-gel for the formation of ZnO seed layer, hydrothermal process to grow ZnO nanorods, and successive ion layer adsorption and reaction (SILAR) process to deposit CdS nanoshells onto the ZnO nanorods. Formation of the ZnO seed layer and vertically aligned ZnO nanorods (d ∼ 40 nm) with a hexagonal cross-section was confirmed by AFM and SEM imaging. Successful capping of ZnO nanorods with homogeneous CdS nanocrystallites (∼5 nm) was ascertained by HRTEM diffraction and imaging. Optical properties of the samples were also studied using UV-vis spectrophotometry. It was found that the absorption edge of the CdS shell has a red shift when its thickness increases. Photocatalytic activity of the samples was examined by photodecomposition of methylene blue under UV and visible lights where the maximum reaction rate constant was found to be 0.012 min-1 under UV illumination and 0.007 min-1 under visible light. The difference in catalytic activities of the ZnO@CdS core-shell nanorods under UV and visible irradiations was explained based upon the electronic structure as well as the arrangement of the energy levels in the ZnO@CdS core-shells. It is shown that the structure and photocatalytic efficiency of the samples can be tuned by manipulating the SILAR variables.

On the growth and photocatalytic activity of the vertically aligned ZnO nanorods grafted by CdS shells

International Nuclear Information System (INIS)

Zirak, M.; Moradlou, O.; Bayati, M.R.; Nien, Y.T.; Moshfegh, A.Z.

2013-01-01

We have studied systematically photocatalytic properties of the vertically aligned ZnO@CdS core–shell nanorods where the features were grown through a multistep procedure including sol–gel for the formation of ZnO seed layer, hydrothermal process to grow ZnO nanorods, and successive ion layer adsorption and reaction (SILAR) process to deposit CdS nanoshells onto the ZnO nanorods. Formation of the ZnO seed layer and vertically aligned ZnO nanorods (d ∼ 40 nm) with a hexagonal cross-section was confirmed by AFM and SEM imaging. Successful capping of ZnO nanorods with homogeneous CdS nanocrystallites (∼5 nm) was ascertained by HRTEM diffraction and imaging. Optical properties of the samples were also studied using UV–vis spectrophotometry. It was found that the absorption edge of the CdS shell has a red shift when its thickness increases. Photocatalytic activity of the samples was examined by photodecomposition of methylene blue under UV and visible lights where the maximum reaction rate constant was found to be 0.012 min −1 under UV illumination and 0.007 min −1 under visible light. The difference in catalytic activities of the ZnO@CdS core–shell nanorods under UV and visible irradiations was explained based upon the electronic structure as well as the arrangement of the energy levels in the ZnO@CdS core–shells. It is shown that the structure and photocatalytic efficiency of the samples can be tuned by manipulating the SILAR variables.

On the growth and photocatalytic activity of the vertically aligned ZnO nanorods grafted by CdS shells

Energy Technology Data Exchange (ETDEWEB)

Zirak, M. [Department of Physics, Sharif University of Technology, P.O. Box 11555-9161, Tehran (Iran, Islamic Republic of); Moradlou, O. [Department of Chemistry, Faculty of Sciences, Alzahra University, P.O. Box 1993893973, Tehran (Iran, Islamic Republic of); Bayati, M.R. [Department of Materials Science and Engineering, NC State University, Raleigh, NC 27695-7907 (United States); Nien, Y.T. [Department of Materials Science and Engineering, National Formosa University, Huwei District, Taiwan (China); Moshfegh, A.Z., E-mail: moshfegh@sharif.edu [Department of Physics, Sharif University of Technology, P.O. Box 11555-9161, Tehran (Iran, Islamic Republic of); Institute of Nanoscience and Nanotechnology, Sharif University of Technology, P.O. Box 14588-8969, Tehran (Iran, Islamic Republic of)

2013-05-15

We have studied systematically photocatalytic properties of the vertically aligned ZnO@CdS core–shell nanorods where the features were grown through a multistep procedure including sol–gel for the formation of ZnO seed layer, hydrothermal process to grow ZnO nanorods, and successive ion layer adsorption and reaction (SILAR) process to deposit CdS nanoshells onto the ZnO nanorods. Formation of the ZnO seed layer and vertically aligned ZnO nanorods (d ∼ 40 nm) with a hexagonal cross-section was confirmed by AFM and SEM imaging. Successful capping of ZnO nanorods with homogeneous CdS nanocrystallites (∼5 nm) was ascertained by HRTEM diffraction and imaging. Optical properties of the samples were also studied using UV–vis spectrophotometry. It was found that the absorption edge of the CdS shell has a red shift when its thickness increases. Photocatalytic activity of the samples was examined by photodecomposition of methylene blue under UV and visible lights where the maximum reaction rate constant was found to be 0.012 min{sup −1} under UV illumination and 0.007 min{sup −1} under visible light. The difference in catalytic activities of the ZnO@CdS core–shell nanorods under UV and visible irradiations was explained based upon the electronic structure as well as the arrangement of the energy levels in the ZnO@CdS core–shells. It is shown that the structure and photocatalytic efficiency of the samples can be tuned by manipulating the SILAR variables.

2.5D global-disk oscillation models of the Be shell star ζ Tauri. I. Spectroscopic and polarimetric analysis

Science.gov (United States)

Escolano, C.; Carciofi, A. C.; Okazaki, A. T.; Rivinius, T.; Baade, D.; Štefl, S.

2015-04-01

Context. A large number of Be stars exhibit intensity variations of their violet and red emission peaks in their H i lines observed in emission. This is the so-called V/R phenomenon, usually explained by the precession of a one-armed spiral density perturbation in the circumstellar disk. That global-disk oscillation scenario was confirmed, both observationally and theoretically, in the previous series of two papers analyzing the Be shell star ζ Tauri. The vertically averaged (2D) global-disk oscillation model used at the time was able to reproduce the V/R variations observed in Hα, as well as the spatially resolved interferometric data from AMBER/VLTI. Unfortunately, that model failed to reproduce the V/R phase of Br15 and the amplitude of the polarization variation, suggesting that the inner disk structure predicted by the model was incorrect. Aims: The first aim of the present paper is to quantify the temporal variations of the shell-line characteristics of ζ Tauri. The second aim is to better understand the physics underlying the V/R phenomenon by modeling the shell-line variations together with the V/R and polarimetric variations. The third aim is to test a new 2.5D disk oscillation model, which solves the set of equations that describe the 3D perturbed disk structure but keeps only the equatorial (i.e., 2D) component of the solution. This approximation was adopted to allow comparisons with the previous 2D model, and as a first step toward a future 3D model. Methods: We carried out an extensive analysis of ζ Tauri's spectroscopic variations by measuring various quantities characterizing its Balmer line profiles: red and violet emission peak intensities (for Hα, Hβ, and Br15), depth and asymmetry of the shell absorption (for Hβ, Hγ, and Hδ), and the respective position (i.e., radial velocity) of each component. We attempted to model the observed variations by implementing in the radiative transfer code HDUST the perturbed disk structure computed with a

Red-emitting SrIn2O4 : Eu3+ phosphor powders for applications in solid state white lamps

International Nuclear Information System (INIS)

Rodriguez-Garcia, C E; Perea-Lopez, N; Hirata, G A; Baars, S P den

2008-01-01

Red-emitting phosphor powders of SrIn 2 O 4 activated with Eu 3+ ions were fabricated by high pressure assisted combustion synthesis. X-ray diffraction analysis of these oxide phosphors revealed the formation of single-phase orthorhombic SrIn 2 O 4 for concentrations up to 4 at% Eu. A detailed photoluminescence (PL) and cathodoluminescence study showed bright red emission originated within the 5 D 0 → 7 F J intra-shell transitions of Eu 3+ . Furthermore, PL excitation spectroscopy revealed that an efficient energy transfer from the SrIn 2 O 4 host lattice onto the Eu ions is accomplished in addition to the excitation band peaked at 396 nm that directly excites the Eu ions, making this material an excellent candidate for applications in solid state white lamps. (fast track communication)

Local and global Casimir energies for a semitransparent cylindrical shell

International Nuclear Information System (INIS)

Cavero-Pelaez, Ines; Milton, Kimball A; Kirsten, Klaus

2007-01-01

The local Casimir energy density and the global Casimir energy for a massless scalar field associated with a λδ-function potential in a (3 + 1)-dimensional circular cylindrical geometry are considered. The global energy is examined for both weak and strong coupling, the latter being the well-studied Dirichlet cylinder case. For weak coupling, through O(λ 2 ), the total energy is shown to vanish by both analytic and numerical arguments, based both on Green's-function and zeta-function techniques. Divergences occurring in the calculation are shown to be absorbable by renormalization of physical parameters of the model. The global energy may be obtained by integrating the local energy density only when the latter is supplemented by an energy term residing precisely on the surface of the cylinder. The latter is identified as the integrated local energy density of the cylindrical shell when the latter is physically expanded to have finite thickness. Inside and outside the δ-function shell, the local energy density diverges as the surface of the shell is approached; the divergence is weakest when the conformal stress tensor is used to define the energy density. A real global divergence first occurs in O(λ 3 ), as anticipated, but the proof is supplied here for the first time; this divergence is entirely associated with the surface energy and does not reflect divergences in the local energy density as the surface is approached

An equations of motion approach for open shell systems

International Nuclear Information System (INIS)

Yeager, D.L.; McKoy, V.

1975-01-01

A straightforward scheme is developed for extending the equations of motion formalism to systems with simple open shell ground states. Equations for open shell random phase approximation (RPA) are given for the cases of one electron outside of a closed shell in a nondegenerate molecular orbital and for the triplet ground state with two electrons outside of a closed shell in degenerate molecular orbitals. Applications to other open shells and extension of the open shell EOM to higher orders are both straightforward. Results for the open shell RPA for lithium atom and oxygen molecule are given

Construction of carbon nanoflakes shell on CuO nanowires core as enhanced core/shell arrays anode of lithium ion batteries

International Nuclear Information System (INIS)

Cao, F.; Xia, X.H.; Pan, G.X.; Chen, J.; Zhang, Y.J.

2015-01-01

Highlights: • CuO/C core/shell nanowire arrays are prepared by electro-deposition + ALD method. • Carbon shell is favorable for structural stability. • CuO/C core/shell arrays show enhanced cycle stability and high capacity. - Abstract: Tailored metal oxide/carbon composite structures have attracted great attention due to potential synergistic effects and enhanced properties. In this work, novel CuO/C core/shell nanowire arrays are prepared by the combination of electro-deposition of CuO and atomic-layer-deposition-assisted formation of carbon nanoflakes shell. The CuO nanowires with diameters of ∼200 nm are homogenously coated by carbon nanoflakes shell. When evaluated as anode materials for lithium ion batteries (LIBs), compared to the unmodified CuO nanowire arrays, the CuO/C core/shell nanowire arrays exhibit improved electrochemical performances with higher capacity, better electrochemical reactivity and high-rate capability as well as superior cycling life (610 mAh g"−"1 at 0.5C after 290 cycles). The enhanced electrochemical performance is mainly attributed to the introduction of carbon flake shell in the core/shell nanowire arrays structure, which provides higher active material-electrolyte contact area, improved electrical conductivity, and better accommodation of volume change. The proposed method provides a new way for fabrication of high-performance metal oxides anodes of LIBs.

Recent shell-model results for exotic nuclei

Directory of Open Access Journals (Sweden)

Utsuno Yusuke

2014-03-01

Full Text Available We report on our recent advancement in the shell model and its applications to exotic nuclei, focusing on the shell evolution and large-scale calculations with the Monte Carlo shell model (MCSM. First, we test the validity of the monopole-based universal interaction (VMU as a shell-model interaction by performing large-scale shell-model calculations in two different mass regions using effective interactions which partly comprise VMU. Those calculations are successful and provide a deeper insight into the shell evolution beyond the single-particle model, in particular showing that the evolution of the spin-orbit splitting due to the tensor force plays a decisive role in the structure of the neutron-rich N ∼ 28 region and antimony isotopes. Next, we give a brief overview of recent developments in MCSM, and show that it is applicable to exotic nuclei that involve many valence orbits. As an example of its applications to exotic nuclei, shape coexistence in 32Mg is examined.

Off-shell distortions of multichannel atomic processes

Science.gov (United States)

Barrachina, R. O.; Clauser, C. F.

2017-10-01

Any multichannel problem can be reduced to a succession of two-body events. However, these basic building blocks of many-body theories do not correspond to elastic processes but are off-the-energy-shell. In view of this difficulty, the great majority of the Distorted-Wave models includes a subsidiary approximation where these off-shell terms are arbitrarily forced to lie on the energy shell. At a first glance, since the energy deficiency is negligible for high enough velocities, the on-shell assumption seems to be completely justified. However, for the case of Coulomb interactions, the two-body off-shell distortions have branch-point singularities on the on-shell limit. In this article we demonstrate that these singularities might produce sizeable distortions of multiple scattering amplitudes, mainly when dealing with ion-ion collisions. Finally, we propose a method of including these distortions that might lead to better results that removing them completely.

Constraints for system specifications for the double-shell and single-shell tank systems

International Nuclear Information System (INIS)

SHAW, C.P.

1999-01-01

This is a supporting document for the Level 1 Double-Shell and Single-Shell System Specifications. The rationale for selection of specific regulatory constraining documents cited in the two system specifications is provided. many of the regulations have been implemented by the Project Hanford Management Contract procedures (HNF-PROs) and as such noted and traced back to their origins in State and Federal regulations

Constraints for system specifications for the double-shell and single-shell tank systems

Energy Technology Data Exchange (ETDEWEB)

SHAW, C.P.

1999-05-18

This is a supporting document for the Level 1 Double-Shell and Single-Shell System Specifications. The rationale for selection of specific regulatory constraining documents cited in the two system specifications is provided. many of the regulations have been implemented by the Project Hanford Management Contract procedures (HNF-PROs) and as such noted and traced back to their origins in State and Federal regulations.

Ionization of inner shells of atoms taking account of outer shell rearrangement

International Nuclear Information System (INIS)

Amusia, M.Ya.

1977-01-01

The application of the general many-body theory and methods formulated with its help, in particular, the so-called random phase approximation with exchange (RPAE) and the many-body perturbation theory (MBPT) makes possible a description of ionization processes for many outer and intermediate shells of a number of atoms. This investigation of outer- and intermediate-shell ionization by photons and electrons demonstrates the collective character of these processes and the possibility of describing them by RPAE. 28 references

Stability of bubble nuclei through Shell-Effects

OpenAIRE

Dietrich, Klaus; Pomorski, Krzysztof

1997-01-01

We investigate the shell structure of bubble nuclei in simple phenomenological shell models and study their binding energy as a function of the radii and of the number of neutron and protons using Strutinsky's method. Shell effects come about, on the one hand, by the high degeneracy of levels with large angular momentum and, on the other, by the big energy gaps between states with a different number of radial nodes. Shell energies down to -40 MeV are shown to occur for certain magic nuclei. E...

Obtainment of calcium carbonate from mussels shell

International Nuclear Information System (INIS)

Hamester, M.R.R.; Becker, D.

2010-01-01

The mussels and oyster shell are discarded at environment, and this accumulation is causing negative consequences to ecosystem. Calcium carbonate is main constituent of the shell chemical composition. Aiming to reduce environmental aggression and generate income to shellfish producer, there was the possibility of using these shells as an alternative to commercial calcium carbonate. For this physics, chemicals and thermal properties were evaluated, using X-ray fluorescence, thermogravimetric analysis, size distribution, abrasiveness and scanning electronic microscopy. The results indicate that mussels shells have an initial degradation temperature higher than commercial calcium carbonate e same lost weight behavior and 95% of shell chemical composition is calcium carbonate. The sample size distribution was influenced by grinding condition and time as well as its abrasiveness. (author)

A design chart for long vacuum pipes and shells

International Nuclear Information System (INIS)

Krempetz, K.; Grimson, J.; Kelly, P.

1986-01-01

This paper presents a design chart to aid designers in the selection of a wall thickness for long cylindrical shells having atmospheric pressure outside the shell and a pressure less than atmospheric inside the shell. The chart indicates a conservative value for the minimum wall thickness for a given shell diameter and material when the shell is completely evacuated

The Colour Treatment: A Convergence of Art and Medicine at the Red Cross Russell Lea Nerve Home.

Science.gov (United States)

Berryman, Jim

2016-01-01

When the Red Cross opened its new convalescent home at Russell Lea in Sydney in 1919, it contained a coloured room designed for treating ‘nerve cases’. This room was painted by Roy de Maistre, a young artist, and was modelled on the Kemp Prossor colour scheme trialled at the McCaul Convalescent Hospital in London for the treatment of shell shock. Dubbed the ‘colour cure’ by the popular press, this unconventional treatment was ignored by the Australian medical profession. The story of de Maistre's colour experiment is not widely known outside the specialist field of Australian art history. Focusing on the colour room as a point of convergence between art and medicine in the context of the First World War, this article investigates Red Cross activities and the care of soldiers suffering from nervous conditions.

Statistical mechanics of microscopically thin thermalized shells

Science.gov (United States)

Kosmrlj, Andrej

Recent explosion in fabrication of microscopically thin free standing structures made from graphene and other two-dimensional materials has led to a renewed interest in the mechanics of such structures in presence of thermal fluctuations. Since late 1980s it has been known that for flat solid sheets thermal fluctuations effectively increase the bending rigidity and reduce the bulk and shear moduli in a scale-dependent fashion. However, much is still unknown about the mechanics of thermalized flat sheets of complex geometries and about the mechanics of thermalized shells with non-zero background curvature. In this talk I will present recent development in the mechanics of thermalized ribbons, spherical shells and cylindrical tubes. Long ribbons are found to behave like hybrids between flat sheets with renormalized elastic constants and semi-flexible polymers, and these results can be used to predict the mechanics of graphene kirigami structures. Contrary to the anticipated behavior for ribbons, the non-zero background curvature of shells leads to remarkable novel phenomena. In shells, thermal fluctuations effectively generate negative surface tension, which can significantly reduce the critical buckling pressure for spherical shells and the critical axial load for cylindrical tubes. For large shells this thermally generated load becomes big enough to spontaneously crush spherical shells and cylindrical tubes even in the absence of external loads. I will comment on the relevance for crushing of microscopic shells (viral capsids, bacteria, microcapsules) due to osmotic shocks and for crushing of nanotubes.

Symmetry chains for the atomic shell model. I. Classification of symmetry chains for atomic configurations

International Nuclear Information System (INIS)

Gruber, B.; Thomas, M.S.

1980-01-01

In this article the symmetry chains for the atomic shell model are classified in such a way that they lead from the group SU(4l+2) to its subgroup SOsub(J)(3). The atomic configurations (nl)sup(N) transform like irreducible representations of the group SU(4l+2), while SOsub(J)(3) corresponds to total angular momentum in SU(4l+2). The defining matrices for the various embeddings are given for each symmetry chain that is obtained. These matrices also define the projection onto the weight subspaces for the corresponding subsymmetries and thus relate the various quantum numbers and determine the branching of representations. It is shown in this article that three (interrelated) symmetry chains are obtained which correspond to L-S coupling, j-j coupling, and a seniority dependent coupling. Moreover, for l<=6 these chains are complete, i.e., there are no other chains but these. In articles to follow, the symmetry chains that lead from the group SO(8l+5) to SOsub(J)(3) will be discussed, with the entire atomic shell transforming like an irreducible representation of SO(8l+5). The transformation properties of the states of the atomic shell will be determined according to the various symmetry chains obtained. The symmetry lattice discussed in this article forms a sublattice of the larger symmetry lattice with SO(8l+5) as supergroup. Thus the transformation properties of the states of the atomic configurations, according to the various symmetry chains discussed in this article, will be obtained too. (author)

Shell model in large spaces and statistical spectroscopy

International Nuclear Information System (INIS)

Kota, V.K.B.

1996-01-01

For many nuclear structure problems of current interest it is essential to deal with shell model in large spaces. For this, three different approaches are now in use and two of them are: (i) the conventional shell model diagonalization approach but taking into account new advances in computer technology; (ii) the shell model Monte Carlo method. A brief overview of these two methods is given. Large space shell model studies raise fundamental questions regarding the information content of the shell model spectrum of complex nuclei. This led to the third approach- the statistical spectroscopy methods. The principles of statistical spectroscopy have their basis in nuclear quantum chaos and they are described (which are substantiated by large scale shell model calculations) in some detail. (author)

Mechanical stability of cylindrical thin-shell wormholes

Energy Technology Data Exchange (ETDEWEB)

Sharif, M. [University of the Punjab, Department of Mathematics, Lahore (Pakistan); Azam, M. [University of Education, Division of Science and Technology, Lahore (Pakistan)

2013-04-15

In this paper, we apply the cut and paste procedure to the charged black string for the construction of a thin-shell wormhole. We consider the Darmois-Israel formalism to determine the surface stresses of the shell. We take the Chaplygin gas to deal with the matter distribution on shell. The radial perturbation approach (preserving the symmetry) is used to investigate the stability of static solutions. We conclude that stable static solutions exist both for uncharged and charged black string thin-shell wormholes for particular values of the parameters. (orig.)

Horizon shells and BMS-like soldering transformations

Energy Technology Data Exchange (ETDEWEB)

Blau, Matthias [Albert Einstein Center for Fundamental Physics,Institute for Theoretical Physics, University of Bern,Sidlerstrasse 5, 3012 Bern (Switzerland); O’Loughlin, Martin [University of Nova Gorica,Vipavska 13, 5000 Nova Gorica (Slovenia)

2016-03-07

We revisit the theory of null shells in general relativity, with a particular emphasis on null shells placed at horizons of black holes. We study in detail the considerable freedom that is available in the case that one solders two metrics together across null hypersurfaces (such as Killing horizons) for which the induced metric is invariant under translations along the null generators. In this case the group of soldering transformations turns out to be infinite dimensional, and these solderings create non-trivial horizon shells containing both massless matter and impulsive gravitational wave components. We also rephrase this result in the language of Carrollian symmetry groups. To illustrate this phenomenon we discuss in detail the example of shells on the horizon of the Schwarzschild black hole (with equal interior and exterior mass), uncovering a rich classical structure at the horizon and deriving an explicit expression for the general horizon shell energy-momentum tensor. In the special case of BMS-like soldering supertranslations we find a conserved shell-energy that is strikingly similar to the standard expression for asymptotic BMS supertranslation charges, suggesting a direct relation between the physical properties of these horizon shells and the recently proposed BMS supertranslation hair of a black hole.

Axisymmetric vibrations of thick shells of revolution

International Nuclear Information System (INIS)

Suzuki, Katsuyoshi; Kosawada, Tadashi; Takahashi, Shin

1983-01-01

Axisymmetric shells of revolution are used for chemical plants, nuclear power plants, aircrafts, structures and so on, and the elucidation of their free vibration is important for the design. In this study, the axisymmetric vibration of a barrel-shaped shell was analyzed by the modified thick shell theory. The Lagrangian during one period of the vibration of a shell of revolution was determined, and from its stopping condition, the vibration equations and the boundary conditions were derived. The vibration equations were analyzed strictly by using the series solution. Moreover, the basic equations for the strain of a shell and others were based on those of Love. As the examples of numerical calculation, the natural frequency and vibration mode of the symmetrical shells of revolution fixed at both ends and supported at both ends were determined, and their characteristics were clarified. By comparing the results of this study with the results by thin shell theory, the effects of shearing deformation and rotary inertia on the natural frequency and vibration mode were clarified. The theoretical analysis and the numerical calculation are described. The effects of shearing deformation and rotary inertia on the natural frequency became larger in the higher order vibration. The vibration mode did not much change in both theories. (Kako, I.)

Red Fox as Sentinel for Blastomyces dermatitidis, Ontario, Canada.

Science.gov (United States)

Nemeth, Nicole M; Campbell, G Douglas; Oesterle, Paul T; Shirose, Lenny; McEwen, Beverly; Jardine, Claire M

2016-07-01

Blastomyces dermatitidis, a fungus that can cause fatal infection in humans and other mammals, is not readily recoverable from soil, its environmental reservoir. Because of the red fox's widespread distribution, susceptibility to B. dermatitidis, close association with soil, and well-defined home ranges, this animal has potential utility as a sentinel for this fungus.

A finite element for plates and shells

International Nuclear Information System (INIS)

Muller, A.; Feijoo, R.A.; Bevilacqua, L.

1981-08-01

A simple triangular finite element for plates and shells, is presented. Since the rotation fields are assumed independent of the displacement fields, the element allows one to solve thick shells problems. In the limit for thin shell, the Kirchoff-Love hypothesis is automatically satisfied, thus enlarging its range of application. (Author) [pt

Shell model Monte Carlo methods

International Nuclear Information System (INIS)

Koonin, S.E.

1996-01-01

We review quantum Monte Carlo methods for dealing with large shell model problems. These methods reduce the imaginary-time many-body evolution operator to a coherent superposition of one-body evolutions in fluctuating one-body fields; resultant path integral is evaluated stochastically. We first discuss the motivation, formalism, and implementation of such Shell Model Monte Carlo methods. There then follows a sampler of results and insights obtained from a number of applications. These include the ground state and thermal properties of pf-shell nuclei, thermal behavior of γ-soft nuclei, and calculation of double beta-decay matrix elements. Finally, prospects for further progress in such calculations are discussed. 87 refs

Seeing red to being red: conserved genetic mechanism for red cone oil droplets and co-option for red coloration in birds and turtles.

Science.gov (United States)

Twyman, Hanlu; Valenzuela, Nicole; Literman, Robert; Andersson, Staffan; Mundy, Nicholas I

2016-08-17

Avian ketocarotenoid pigments occur in both the red retinal oil droplets that contribute to colour vision and bright red coloration used in signalling. Turtles are the only other tetrapods with red retinal oil droplets, and some also display red carotenoid-based coloration. Recently, the CYP2J19 gene was strongly implicated in ketocarotenoid synthesis in birds. Here, we investigate CYP2J19 evolution in relation to colour vision and red coloration in reptiles using genomic and expression data. We show that turtles, but not crocodiles or lepidosaurs, possess a CYP2J19 orthologue, which arose via gene duplication before turtles and archosaurs split, and which is strongly and specifically expressed in the ketocarotenoid-containing retina and red integument. We infer that CYP2J19 initially functioned in colour vision in archelosaurs and conclude that red ketocarotenoid-based coloration evolved independently in birds and turtles via gene regulatory changes of CYP2J19 Our results suggest that red oil droplets contributed to colour vision in dinosaurs and pterosaurs. © 2016 The Author(s).

Semiclassical shell structure in rotating Fermi systems

International Nuclear Information System (INIS)

Magner, A. G.; Sitdikov, A. S.; Khamzin, A. A.; Bartel, J.

2010-01-01

The collective moment of inertia is derived analytically within the cranking model for any rotational frequency of the harmonic-oscillator potential well and at a finite temperature. Semiclassical shell-structure components of the collective moment of inertia are obtained for any potential by using the periodic-orbit theory. We found semiclassically their relation to the free-energy shell corrections through the shell-structure components of the rigid-body moment of inertia of the statistically equilibrium rotation in terms of short periodic orbits. The shell effects in the moment of inertia exponentially disappear with increasing temperature. For the case of the harmonic-oscillator potential, one observes a perfect agreement of the semiclassical and quantum shell-structure components of the free energy and the moment of inertia for several critical bifurcation deformations and several temperatures.

Core@shell@shell structured carbon-based magnetic ternary nanohybrids: Synthesis and their enhanced microwave absorption properties

Science.gov (United States)

Yang, Erqi; Qi, Xiaosi; Xie, Ren; Bai, Zhongchen; Jiang, Yang; Qin, Shuijie; Zhong, Wei; Du, Youwei

2018-05-01

High encapsulation efficiency of core@shell@shell structured carbon-based magnetic ternary nanohybrids have been synthesized in high yield by chemical vapor deposition of acetylene directly over octahedral-shaped Fe2O3 nanoparticles. By controlling the pyrolysis temperature, Fe3O4@Fe3C@carbon nanotubes (CNTs) and Fe@Fe3C@CNTs ternary nanohybrids could be selectively produced. The optimal RL values for the as-prepared ternary nanohybrids could reach up to ca. -46.7, -52.7 and -29.5 dB, respectively. The excellent microwave absorption properties of the obtaiend ternary nanohybrids were proved to ascribe to the quarter-wavelength matching model. Moreover, the as-prepared Fe@Fe3C@CNTs ternary nanohybrids displayed remarkably enhanced EM wave absorption capabilities compared to Fe3O4@Fe3C@CNTs due to their excellent dielectric loss abilities, good complementarities between the dielectric loss and the magnetic loss, and high attenuation constant. Generally, this strategy can be extended to explore other categories of core@shell or core@shell@shell structured carbon-based nanohybrids, which is very beneficial to accelerate the advancements of high performance MAMs.

Folding of non-Euclidean curved shells

Science.gov (United States)

Bende, Nakul; Evans, Arthur; Innes-Gold, Sarah; Marin, Luis; Cohen, Itai; Santangelo, Christian; Hayward, Ryan

2015-03-01

Origami-based folding of 2D sheets has been of recent interest for a variety of applications ranging from deployable structures to self-folding robots. Though folding of planar sheets follows well-established principles, folding of curved shells involves an added level of complexity due to the inherent influence of curvature on mechanics. In this study, we use principles from differential geometry and thin shell mechanics to establish fundamental rules that govern folding of prototypical creased shells. In particular, we show how the normal curvature of a crease line controls whether the deformation is smooth or discontinuous, and investigate the influence of shell thickness and boundary conditions. We show that snap-folding of shells provides a route to rapid actuation on time-scales dictated by the speed of sound. The simple geometric design principles developed can be applied at any length-scale, offering potential for bio-inspired soft actuators for tunable optics, microfluidics, and robotics. This work was funded by the National Science Foundation through EFRI ODISSEI-1240441 with additional support to S.I.-G. through the UMass MRSEC DMR-0820506 REU program.

Double shell planar experiments on OMEGA

Science.gov (United States)

Dodd, E. S.; Merritt, E. C.; Palaniyappan, S.; Montgomery, D. S.; Daughton, W. S.; Schmidt, D. W.; Cardenas, T.; Wilson, D. C.; Loomis, E. N.; Batha, S. H.; Ping, Y.; Smalyuk, V. A.; Amendt, P. A.

2017-10-01

The double shell project is aimed at fielding neutron-producing capsules at the National Ignition Facility (NIF), in which an outer low-Z ablator collides with an inner high-Z shell to compress the fuel. However, understanding these targets experimentally can be challenging when compared with conventional single shell targets. Halfraum-driven planar targets at OMEGA are being used to study physics issues important to double shell implosions outside of a convergent geometry. Both VISAR and radiography through a tube have advantages over imaging through the hohlraum and double-shell capsule at NIF. A number physics issues are being studied with this platform that include 1-d and higher dimensional effects such as defect-driven hydrodynamic instabilities from engineering features. Additionally, the use of novel materials with controlled density gradients require study in easily diagnosed 1-d systems. This work ultimately feeds back into the NIF capsule platform through manufacturing tolerances set using data from OMEGA. Supported under the US DOE by the LANS, LLC under contract DE-AC52-06NA25396. LA-UR-17-25386.

Synthesis of parallel and antiparallel core-shell triangular nanoparticles

Science.gov (United States)

Bhattacharjee, Gourab; Satpati, Biswarup

2018-04-01

Core-shell triangular nanoparticles were synthesized by seed mediated growth. Using triangular gold (Au) nanoparticle as template, we have grown silver (Ag) shellto get core-shell nanoparticle. Here by changing the chemistry we have grown two types of core-shell structures where core and shell is having same symmetry and also having opposite symmetry. Both core and core-shell nanoparticles were characterized using transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX) to know the crystal structure and composition of these synthesized core-shell nanoparticles. From diffraction pattern analysis and energy filtered TEM (EFTEM) we have confirmed the crystal facet in core is responsible for such two dimensional growth of core-shell nanostructures.

Is seniority a partial dynamic symmetry in the first νg9/2 shell?

Science.gov (United States)

Morales, A. I.; Benzoni, G.; Watanabe, H.; de Angelis, G.; Nishimura, S.; Coraggio, L.; Gargano, A.; Itaco, N.; Otsuka, T.; Tsunoda, Y.; Van Isacker, P.; Browne, F.; Daido, R.; Doornenbal, P.; Fang, Y.; Lorusso, G.; Patel, Z.; Rice, S.; Sinclair, L.; Söderström, P.-A.; Sumikama, T.; Valiente-Dobón, J. J.; Wu, J.; Xu, Z. Y.; Yagi, A.; Yokoyama, R.; Baba, H.; Avigo, R.; Bello Garrote, F. L.; Blasi, N.; Bracco, A.; Bruce, A. M.; Camera, F.; Ceruti, S.; Crespi, F. C. L.; Delattre, M.-C.; Dombradi, Zs.; Gottardo, A.; Isobe, T.; Kojouharov, I.; Kurz, N.; Kuti, I.; Lalkovski, S.; Matsui, K.; Melon, B.; Mengoni, D.; Miyazaki, T.; Modamio-Hoybjor, V.; Momiyama, S.; Napoli, D. R.; Niikura, M.; Orlandi, R.; Podolyák, Zs.; Regan, P. H.; Sakurai, H.; Sahin, E.; Sohler, D.; Schaffner, H.; Taniuchi, R.; Taprogge, J.; Vajta, Zs.; Wieland, O.; Yalcinkaya, M.

2018-06-01

The low-lying structures of the midshell νg9/2 Ni isotopes 72Ni and 74Ni have been investigated at the RIBF facility in RIKEN within the EURICA collaboration. Previously unobserved low-lying states were accessed for the first time following β decay of the mother nuclei 72Co and 74Co. As a result, we provide a complete picture in terms of the seniority scheme up to the first (8+) levels for both nuclei. The experimental results are compared to shell-model calculations in order to define to what extent the seniority quantum number is preserved in the first neutron g9/2 shell. We find that the disappearance of the seniority isomerism in the (81+) states can be explained by a lowering of the seniority-four (6+) levels as predicted years ago. For 74Ni, the internal de-excitation pattern of the newly observed (62+) state supports a restoration of the normal seniority ordering up to spin J = 4. This property, unexplained by the shell-model calculations, is in agreement with a dominance of the single-particle spherical regime near 78Ni.

Enhanced oxidation stability of quasi core-shell alloyed CdSeS quantum dots prepared through aqueous microwave synthesis technique.

Science.gov (United States)

Zhan, Hong-Ju; Zhou, Pei-Jiang; Ma, Rong; Liu, Xi-Jing; He, Yu-Ning; Zhou, Chuan-Yun

2014-01-01

Quasi core shell alloyed CdSeS quantum dots (QDs) have been prepared through a facile aqueous-phase route employing microwave irradiation technique. The optical spectroscopy and structure characterization evidenced the quasi core shell alloyed structures of CdSeS QDs. The X-ray diffraction patterns of the obtained CdSeS QDs displayed peak positions very close to those of bulk cubic CdS crystal structures and the result of X-ray photoelectron spectroscopy data re-confirmed the thick CdS shell on the CdSe core. The TEM images and HRTEM images of the CdSeS QDs ascertained the well-defined spherical particles and a relatively narrow size distribution. On the basis, the stability of the obtained QDs in an oxidative environment was also discussed using etching reaction by H2O2. The experiments result showed the as-prepared QDs present high tolerance towards H2O2, obviously superior to the commonly used CdTe QDs and core-shell CdTe/CdS QDs, which was attributed to the unique quasi core-shell CdSeS crystal structure and the small lattice mismatch between CdSe and CdS semiconductor materials. This assay provided insight to obtain high stable crystal structured semiconductor nanocrystals in the design and synthesis process.

The evolution of mollusc shells.

Science.gov (United States)

McDougall, Carmel; Degnan, Bernard M

2018-05-01

Molluscan shells are externally fabricated by specialized epithelial cells on the dorsal mantle. Although a conserved set of regulatory genes appears to underlie specification of mantle progenitor cells, the genes that contribute to the formation of the mature shell are incredibly diverse. Recent comparative analyses of mantle transcriptomes and shell proteomes of gastropods and bivalves are consistent with shell diversity being underpinned by a rapidly evolving mantle secretome (suite of genes expressed in the mantle that encode secreted proteins) that is the product of (a) high rates of gene co-option into and loss from the mantle gene regulatory network, and (b) the rapid evolution of coding sequences, particular those encoding repetitive low complexity domains. Outside a few conserved genes, such as carbonic anhydrase, a so-called "biomineralization toolkit" has yet to be discovered. Despite this, a common suite of protein domains, which are often associated with the extracellular matrix and immunity, appear to have been independently and often uniquely co-opted into the mantle secretomes of different species. The evolvability of the mantle secretome provides a molecular explanation for the evolution and diversity of molluscan shells. These genomic processes are likely to underlie the evolution of other animal biominerals, including coral and echinoderm skeletons. This article is categorized under: Comparative Development and Evolution > Regulation of Organ Diversity Comparative Development and Evolution > Evolutionary Novelties. © 2018 Wiley Periodicals, Inc.

References for HNF-SD-WM-TRD-007, ''System specification for the double-shell tank system: HNF-PROs, CFRs, DOE Orders, WACs''

International Nuclear Information System (INIS)

Shaw, C.P.

1998-01-01

HNF-SD-WM-TRD-O07, System Specification for the Double-Shell Tank System, (hereafter referred to as DST Specification), defines the requirements of the double-shell tank system at the Hanford Site for Phase 1 privatization. Many of the sections in this document reference other documents for design guidance and requirements. Referenced documents include Project Hanford Management Contract (PHMC) procedures (HNF-PROS), Codes of Federal Regulation (CFRs), DOE Orders, and Washington Administrative Codes (WACs). This document provides rationale for the selection and inclusion of HNF-PROS, CFRs, DOE Orders and WACs

Deriving the nuclear shell model from first principles

Science.gov (United States)

Barrett, Bruce R.; Dikmen, Erdal; Vary, James P.; Maris, Pieter; Shirokov, Andrey M.; Lisetskiy, Alexander F.

2014-09-01

The results of an 18-nucleon No Core Shell Model calculation, performed in a large basis space using a bare, soft NN interaction, can be projected into the 0 ℏω space, i.e., the sd -shell. Because the 16 nucleons in the 16O core are frozen in the 0 ℏω space, all the correlations of the 18-nucleon system are captured by the two valence, sd -shell nucleons. By the projection, we obtain microscopically the sd -shell 2-body effective interactions, the core energy and the sd -shell s.p. energies. Thus, the input for standard shell-model calculations can be determined microscopically by this approach. If the same procedure is then applied to 19-nucleon systems, the sd -shell 3-body effective interactions can also be obtained, indicating the importance of these 3-body effective interactions relative to the 2-body effective interactions. Applications to A = 19 and heavier nuclei with different intrinsic NN interactions will be presented and discussed. The results of an 18-nucleon No Core Shell Model calculation, performed in a large basis space using a bare, soft NN interaction, can be projected into the 0 ℏω space, i.e., the sd -shell. Because the 16 nucleons in the 16O core are frozen in the 0 ℏω space, all the correlations of the 18-nucleon system are captured by the two valence, sd -shell nucleons. By the projection, we obtain microscopically the sd -shell 2-body effective interactions, the core energy and the sd -shell s.p. energies. Thus, the input for standard shell-model calculations can be determined microscopically by this approach. If the same procedure is then applied to 19-nucleon systems, the sd -shell 3-body effective interactions can also be obtained, indicating the importance of these 3-body effective interactions relative to the 2-body effective interactions. Applications to A = 19 and heavier nuclei with different intrinsic NN interactions will be presented and discussed. Supported by the US NSF under Grant No. 0854912, the US DOE under

Development and applications of a flat triangular element for thin laminated shells

Science.gov (United States)

Mohan, P.

Finite element analysis of thin laminated shells using a three-noded flat triangular shell element is presented. The flat shell element is obtained by combining the Discrete Kirchhoff Theory (DKT) plate bending element and a membrane element similar to the Allman element, but derived from the Linear Strain Triangular (LST) element. The major drawback of the DKT plate bending element is that the transverse displacement is not explicitly defined within the interior of the element. In the present research, free vibration analysis is performed both by using a lumped mass matrix and a so called consistent mass matrix, obtained by borrowing shape functions from an existing element, in order to compare the performance of the two methods. Several numerical examples are solved to demonstrate the accuracy of the formulation for both small and large rotation analysis of laminated plates and shells. The results are compared with those available in the existing literature and those obtained using the commercial finite element package ABAQUS and are found to be in good agreement. The element is employed for two main applications involving large flexible structures. The first application is the control of thermal deformations of a spherical mirror segment, which is a segment of a multi-segmented primary mirror used in a space telescope. The feasibility of controlling the surface distortions of the mirror segment due to arbitrary thermal fields, using discrete and distributed actuators, is studied. The second application is the analysis of an inflatable structure, being considered by the US Army for housing vehicles and personnel. The updated Lagrangian formulation of the flat shell element has been developed primarily for the nonlinear analysis of the tent structure, since such a structure is expected to undergo large deformations and rotations under the action of environmental loads like the wind and snow loads. The follower effects of the pressure load have been included in the

Unified description of pf-shell nuclei by the Monte Carlo shell model calculations

Energy Technology Data Exchange (ETDEWEB)

Mizusaki, Takahiro; Otsuka, Takaharu [Tokyo Univ. (Japan). Dept. of Physics; Honma, Michio

1998-03-01

The attempts to solve shell model by new methods are briefed. The shell model calculation by quantum Monte Carlo diagonalization which was proposed by the authors is a more practical method, and it became to be known that it can solve the problem with sufficiently good accuracy. As to the treatment of angular momentum, in the method of the authors, deformed Slater determinant is used as the basis, therefore, for making angular momentum into the peculiar state, projected operator is used. The space determined dynamically is treated mainly stochastically, and the energy of the multibody by the basis formed as the result is evaluated and selectively adopted. The symmetry is discussed, and the method of decomposing shell model space into dynamically determined space and the product of spin and isospin spaces was devised. The calculation processes are shown with the example of {sup 50}Mn nuclei. The calculation of the level structure of {sup 48}Cr with known exact energy can be done with the accuracy of peculiar absolute energy value within 200 keV. {sup 56}Ni nuclei are the self-conjugate nuclei of Z=N=28. The results of the shell model calculation of {sup 56}Ni nucleus structure by using the interactions of nuclear models are reported. (K.I.)

Aqueous-phase synthesis and color-tuning of core/shell/shell inorganic nanocrystals consisting of ZnSe, (Cu, Mn)-doped ZnS, and ZnS

Energy Technology Data Exchange (ETDEWEB)

Choi, Jongwan; Yoon, Sujin [Department of Chemistry and Research Institute for Natural Science, Hanyang University, Seoul, 133-791 (Korea, Republic of); Kim, Felix Sunjoo, E-mail: fskim@cau.ac.kr [School of Chemical Engineering and Materials Science, Chung-Ang University, Seoul, 156-756 (Korea, Republic of); Kim, Nakjoong, E-mail: kimnj@hanyang.ac.kr [Department of Chemistry and Research Institute for Natural Science, Hanyang University, Seoul, 133-791 (Korea, Republic of)

2016-06-25

We report synthesis of colloidal nanocrystals based on ZnSe core, (Cu,Mn)-doped ZnS inner-shell, and ZnS outer-shell by using an eco-friendly method and their optical properties. Synthesis of core/shell/shell nanocrystals was performed by using a one-pot/three-step colloidal method with 3-mercaptopropionic acid as a stabilizer in aqueous phase at low temperature. A double-shell structure was employed with inner-shell as a host for doping and outer-shell as a passivation layer for covering surface defects. Copper and manganese were introduced as single- or co-dopants during inner-shell formation, providing an effective means to control the emission color of the nanocrystals. The synthesized nanocrystals showed fluorescent emission ranging from blue to green, to white, and to orange, adjusted by doping components, amounts, and ratios. The photoluminescence quantum yields of the core/doped-shell/shell nanocrystals approached 36%. - Highlights: • ZnSe/ZnS:(Cu,Ms)/ZnS core/(doped)shell/shell nanocrystals were synthesized in an aqueous phase. • Emission color of nanocrystals was controlled from blue to white to orange by adjusting the atomic ratio of Cu and Mn co-dopants. • Photoluminescence quantum yields of the colloidal nanocrystals approached 36%.

Conventional shell model: some issues

International Nuclear Information System (INIS)

Vallieres, M.; Pan, X.W.; Feng, D.H.; Novoselsky, A.

1997-01-01

We discuss some important issues in shell-model calculations related to the effective interactions used in different regions of the periodic table; in particular the quality of different interactions is discussed, as well as the mass dependence of the interactions. Mention is made of the recently developed Drexel University shell-model (DUSM). (orig.)

Modeling complicated rheological behaviors in encapsulating shells of lipid-coated microbubbles accounting for nonlinear changes of both shell viscosity and elasticity.

Science.gov (United States)

Li, Qian; Matula, Thomas J; Tu, Juan; Guo, Xiasheng; Zhang, Dong

2013-02-21

It has been accepted that the dynamic responses of ultrasound contrast agent (UCA) microbubbles will be significantly affected by the encapsulating shell properties (e.g., shell elasticity and viscosity). In this work, a new model is proposed to describe the complicated rheological behaviors in an encapsulating shell of UCA microbubbles by applying the nonlinear 'Cross law' to the shell viscous term in the Marmottant model. The proposed new model was verified by fitting the dynamic responses of UCAs measured with either a high-speed optical imaging system or a light scattering system. The comparison results between the measured radius-time curves and the numerical simulations demonstrate that the 'compression-only' behavior of UCAs can be successfully simulated with the new model. Then, the shell elastic and viscous coefficients of SonoVue microbubbles were evaluated based on the new model simulations, and compared to the results obtained from some existing UCA models. The results confirm the capability of the current model for reducing the dependence of bubble shell parameters on the initial bubble radius, which indicates that the current model might be more comprehensive to describe the complex rheological nature (e.g., 'shear-thinning' and 'strain-softening') in encapsulating shells of UCA microbubbles by taking into account the nonlinear changes of both shell elasticity and shell viscosity.

Modeling complicated rheological behaviors in encapsulating shells of lipid-coated microbubbles accounting for nonlinear changes of both shell viscosity and elasticity

International Nuclear Information System (INIS)

Li Qian; Tu Juan; Guo Xiasheng; Zhang Dong; Matula, Thomas J

2013-01-01

It has been accepted that the dynamic responses of ultrasound contrast agent (UCA) microbubbles will be significantly affected by the encapsulating shell properties (e.g., shell elasticity and viscosity). In this work, a new model is proposed to describe the complicated rheological behaviors in an encapsulating shell of UCA microbubbles by applying the nonlinear ‘Cross law’ to the shell viscous term in the Marmottant model. The proposed new model was verified by fitting the dynamic responses of UCAs measured with either a high-speed optical imaging system or a light scattering system. The comparison results between the measured radius–time curves and the numerical simulations demonstrate that the ‘compression-only’ behavior of UCAs can be successfully simulated with the new model. Then, the shell elastic and viscous coefficients of SonoVue microbubbles were evaluated based on the new model simulations, and compared to the results obtained from some existing UCA models. The results confirm the capability of the current model for reducing the dependence of bubble shell parameters on the initial bubble radius, which indicates that the current model might be more comprehensive to describe the complex rheological nature (e.g., ‘shear-thinning’ and ‘strain-softening’) in encapsulating shells of UCA microbubbles by taking into account the nonlinear changes of both shell elasticity and shell viscosity. (paper)

Molluscan shell evolution with review of shell calcification hypothesis

Czech Academy of Sciences Publication Activity Database

Furuhashi, T.; Schwarzinger, C.; Mikšík, Ivan; Smrž, Miloslav; Beran, A.

2009-01-01

Roč. 154, č. 3 (2009), s. 351-371 ISSN 1096-4959 Institutional research plan: CEZ:AV0Z50110509 Keywords : mollusca * shell * biomineralization Subject RIV: CE - Biochemistry Impact factor: 1.607, year: 2009

A Combined SAXS/SANS Study for the in Situ Characterization of Ligand Shells on Small Nanoparticles: The Case of ZnO.

Science.gov (United States)

Schindler, T; Schmiele, M; Schmutzler, T; Kassar, T; Segets, D; Peukert, W; Radulescu, A; Kriele, A; Gilles, R; Unruh, T

2015-09-22

ZnO nanoparticles (NPs) have great potential for their use in, e.g., thin film solar cells due to their electro-optical properties adjustable on the nanoscale. Therefore, the production of well-defined NPs is of major interest. For a targeted production process, the knowledge of the stabilization layer of the NPs during and after their formation is of particular importance. For the study of the stabilizer layer of ZnO NPs prepared in a wet chemical synthesis from zinc acetate, only ex situ studies have been performed so far. An acetate layer bound to the surface of the dried NPs was found; however, an in situ study which addresses the stabilizing layer surrounding the NPs in a native dispersion was missing. By the combination of small angle scattering with neutrons and X-rays (SANS and SAXS) for the same sample, we are now able to observe the acetate shell in situ for the first time. In addition, the changes of this shell could be followed during the ripening process for different temperatures. With increasing size of the ZnO core (d(core)) the surrounding shell (d(shell)) becomes larger, and the acetate concentration within the shell is reduced. For all samples, the shell thickness was found to be larger than the maximum extension of an acetate molecule with acetate concentrations within the shell below 50 vol %. Thus, there is not a monolayer of acetate molecules that covers the NPs but rather a swollen shell of acetate ions. This shell is assumed to hinder the growth of the NPs to larger macrostructures. In addition, we found that the partition coefficient μ between acetate in the shell surrounding the NPs and the total amount of acetate in the solution is about 10% which is in good agreement with ex situ data determined by thermogravimetric analysis.

Vibrio cholerae Colonization of Soft-Shelled Turtles.

Science.gov (United States)

Wang, Jiazheng; Yan, Meiying; Gao, He; Lu, Xin; Kan, Biao

2017-07-15

Vibrio cholerae is an important human pathogen and environmental microflora species that can both propagate in the human intestine and proliferate in zooplankton and aquatic organisms. Cholera is transmitted through food and water. In recent years, outbreaks caused by V. cholerae -contaminated soft-shelled turtles, contaminated mainly with toxigenic serogroup O139, have been frequently reported, posing a new foodborne disease public health problem. In this study, the colonization by toxigenic V. cholerae on the body surfaces and intestines of soft-shelled turtles was explored. Preferred colonization sites on the turtle body surfaces, mainly the carapace and calipash of the dorsal side, were observed for the O139 and O1 strains. Intestinal colonization was also found. The colonization factors of V. cholerae played different roles in the colonization of the soft-shelled turtle's body surface and intestine. Mannose-sensitive hemagglutinin (MSHA) of V. cholerae was necessary for body surface colonization, but no roles were found for toxin-coregulated pili (TCP) or N -acetylglucosamine-binding protein A (GBPA). Both TCP and GBPA play important roles for colonization in the intestine, whereas the deletion of MSHA revealed only a minor colonization-promoting role for this factor. Our study demonstrated that V. cholerae can colonize the surfaces and the intestines of soft-shelled turtles and indicated that the soft-shelled turtles played a role in the transmission of cholera. In addition, this study showed that the soft-shelled turtle has potential value as an animal model in studies of the colonization and environmental adaption mechanisms of V. cholerae in aquatic organisms. IMPORTANCE Cholera is transmitted through water and food. Soft-shelled turtles contaminated with Vibrio cholerae (commonly the serogroup O139 strains) have caused many foodborne infections and outbreaks in recent years, and they have become a foodborne disease problem. Except for epidemiological

Safety studies conducted on pecan shell fiber, a food ingredient produced from ground pecan shells.

Science.gov (United States)

Dolan, Laurie; Matulka, Ray; Worn, Jeffrey; Nizio, John

2016-01-01

Use of pecan shell fiber in human food is presently limited, but could increase pending demonstration of safety. In a 91-day rat study, pecan shell fiber was administered at dietary concentrations of 0 (control), 50 000, 100 000 or 150 000 ppm. There was no effect of the ingredient on body weight of males or females or food consumption of females. Statistically significant increases in food consumption were observed throughout the study in 100 000 and 150 000 ppm males, resulting in intermittent decreases in food efficiency (150 000 ppm males only) that were not biologically relevant. All animals survived and no adverse clinical signs or functional changes were attributable to the test material. There were no toxicologically relevant changes in hematology, clinical chemistry or urinalysis parameters or organ weights in rats ingesting pecan shell fiber. Any macroscopic or microscopic findings were incidental, of normal variation and/or of minimal magnitude for test substance association. Pecan shell fiber was non-mutagenic in a bacterial reverse mutation test and non-clastogenic in a mouse peripheral blood micronucleus test. Based on these results, pecan shell fiber has an oral subchronic (13-week) no observable adverse effect level (NOAEL) of 150 000 ppm in rats and is not genotoxic at the doses analyzed.

Preparation of paclitaxel/chitosan co-assembled core-shell nanofibers for drug-eluting stent

Energy Technology Data Exchange (ETDEWEB)

Tang, Jing; Liu, Yongjia [Instrumental Analysis Center, Shanghai Jiao Tong University, 200240 Shanghai (China); State Key Laboratory of Metal Matrix Composites, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 200240 Shanghai (China); Zhu, Bangshang, E-mail: bshzhu@sjtu.edu.cn [Instrumental Analysis Center, Shanghai Jiao Tong University, 200240 Shanghai (China); State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, 201620 Shanghai (China); Su, Yue; Zhu, Xinyuan [State Key Laboratory of Metal Matrix Composites, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 200240 Shanghai (China)

2017-01-30

Highlights: • The core-shell nanofibers (NFs) were made by the co-assembly of paclitaxel (PTX) and chitosan(CS). • The PTX/CS NFs have high PTX loading content, slow drug release and low adherence of platelets. • The PTX/CS NFs have low cytotoxicity and good haemocompatibility. • The PTX/CS NFs which could be easily coated on stents could have potential application for drug eluting stents. - Abstract: The paclitaxel/chitosan (PTX/CS) core-shell nanofibers (NFs) are easily prepared by co-assembly of PTX and CS and used in drug-eluting stent. The mixture solution of PTX (dissolved in ethanol) and CS (dissolved in 1% acetic acid water solution) under sonication will make the formation of NFs, in which small molecule PTX co-assembles with biomacromolecular CS through non-covalent interactions. The obtained NFs are tens to hundreds nanometers in diameter and millimeter level in length. Furthermore, the structure of PTX/CS NFs was characterized by confocal laser scanning microscopy (CLSM), zeta potential, X-ray photoelectron spectroscopy (XPS) and nanoscale infra-red (nanoIR), which provided evidences demonstrated that PTX/CS NFs are core-shell structures. The ‘shell’ of CS wrapped outside of the NFs, while PTX is located in the core. Thus it resulted in high drug loading content (>40 wt.%). The well-controlled drug release, low cytotoxicity and good haemocompatibility were also found in drug carrier system of PTX/CS NFs. In addition, the hydrophilic and flexible properties of NFs make them easily coating and filming on stent to prepare drug-eluting stent (DES). Therefore, this study provides a convenient method to prepare high PTX loaded NFs, which is a promising nano-drug carrier used for DES and other biomedical applications. The possible molecular mechanism of PTX and CS co-assembly and core-shell nanofiber formation is also explored. Statement of significance: We develop a convenient and efficient approach to fabricate core-shell nanofibers (NFs) through

Collapse analysis of toroidal shell

International Nuclear Information System (INIS)

Pomares, R.J.

1990-01-01

This paper describes a study performed to determine the collapse characteristics of a toroidal shell using finite element method (FEM) analysis. The study also included free drop testing of a quarter scale prototype to verify the analytical results. The full sized toroidal shell has a 24-inch toroidal diameter with a 24-inch tubal diameter. The shell material is type 304 strainless steel. The toroidal shell is part of the GE Model 2000 transportation packaging, and acts as an energy absorbing device. The analyses performed were on a full sized and quarter scaled models. The finite element program used in all analyses was the LIBRA code. The analytical procedure used both the elasto-plastic and large displacement options within the code. The loading applied in the analyses corresponded to an impact of an infinite rigid plane oriented normal to the drop direction vector. The application of the loading continued incrementally until the work performed by the deforming structure equalled the kinetic energy developed in the free fall. The comparison of analysis and test results showed a good correlation

Micromagnetic studies of three-dimensional pyramidal shell structures

International Nuclear Information System (INIS)

Knittel, A; Franchin, M; Fischbacher, T; Fangohr, H; Nasirpouri, F; Bending, S J

2010-01-01

We present a systematic numerical analysis of the magnetic properties of pyramidal-shaped core-shell structures in a size range below 400 nm. These are three-dimensional structures consisting of a ferromagnetic shell which is grown on top of a non-magnetic core. The standard micromagnetic model without the magnetocrystalline anisotropy term is used to describe the properties of the shell. We vary the thickness of the shell between the limiting cases of an ultra-thin shell and a conventional pyramid and delineate different stable magnetic configurations. We find different kinds of single-domain states, which predominantly occur at smaller system sizes. In analogy to equivalent states in thin square films we term these onion, flower, C and S states. At larger system sizes, we also observe two types of vortex states, which we refer to as symmetric and asymmetric vortex states. For a classification of the observed states, we derive a phase diagram that specifies the magnetic ground state as a function of structure size and shell thickness. The transitions between different ground states can be understood qualitatively. We address the issue of metastability by investigating the stability of all occurring configurations for different shell thicknesses. For selected geometries and directions hysteresis measurements are analysed and discussed. We observe that the magnetic behaviour changes distinctively in the limit of ultra-thin shells. The study has been motivated by the recent progress made in the growth of faceted core-shell structures.

Snap-Through Buckling Problem of Spherical Shell Structure

Directory of Open Access Journals (Sweden)

Sumirin Sumirin

2014-12-01

Full Text Available This paper presents results of a numerical study on the nonlinear behavior of shells undergoing snap-through instability. This research investigates the problem of snap-through buckling of spherical shells applying nonlinear finite element analysis utilizing ANSYS Program. The shell structure was modeled by axisymmetric thin shell of finite elements. Shells undergoing snap-through buckling meet with significant geometric change of their physical configuration, i.e. enduring large deflections during their deformation process. Therefore snap-through buckling of shells basically is a nonlinear problem. Nonlinear numerical operations need to be applied in their analysis. The problem was solved by a scheme of incremental iterative procedures applying Newton-Raphson method in combination with the known line search as well as the arc- length methods. The effects of thickness and depth variation of the shell is taken care of by considering their geometrical parameter l. The results of this study reveal that spherical shell structures subjected to pressure loading experience snap-through instability for values of l≥2.15. A form of ‘turn-back’ of the load-displacement curve took place at load levels prior to the achievement of the critical point. This phenomenon was observed for values of l=5.0 to l=7.0.

Continuum shell-model with complicated configurations

International Nuclear Information System (INIS)

Barz, H.W.; Hoehn, J.

1977-05-01

The traditional shell model has been combined with the coupled channels method in order to describe resonance reactions. For that purpose the configuration space is divided into two subspaces (Feshbach projection method). Complicated shell-model configurations can be included into the subspace of discrete states which contains the single particle resonance states too. In the subspace of scattering states the equation of motion is solved by using the coupled channels method. Thereby the orthogonality between scattering states and discrete states is ensured. Resonance states are defined with outgoing waves in all channels. By means of simple model calculations the special role of the continuum is investigated. In this connection the energy dependence of the resonance parameters, the isospin mixture via the continuum, threshold effect, as well as the influence of the number of channels taken into account on the widths, positions and dipole strengths of the resonance are discussed. The model is mainly applied to the description of giant resonances excited by the scattering of nucleons and photo-nucleus processes (source term method) found in reactions on light nuclei. The giant resonance observed in the 15 N(p,n) reaction is explained by the inclusion of 2p-2h states. The same is true for the giant resonance in 13 C(J = 1/2, 3/2) as well as for the giant resonance built on the first 3 - state in 16 O. By means of a correlation analysis for the reduced widths amplitudes an access to the doorway conception is found. (author)

Nanostructured core-shell electrode materials for electrochemical capacitors

Science.gov (United States)

Jiang, Long-bo; Yuan, Xing-zhong; Liang, Jie; Zhang, Jin; Wang, Hou; Zeng, Guang-ming

2016-11-01

Core-shell nanostructure represents a unique system for applications in electrochemical energy storage devices. Owing to the unique characteristics featuring high power delivery and long-term cycling stability, electrochemical capacitors (ECs) have emerged as one of the most attractive electrochemical storage systems since they can complement or even replace batteries in the energy storage field, especially when high power delivery or uptake is needed. This review aims to summarize recent progress on core-shell nanostructures for advanced supercapacitor applications in view of their hierarchical architecture which not only create the desired hierarchical porous channels, but also possess higher electrical conductivity and better structural mechanical stability. The core-shell nanostructures include carbon/carbon, carbon/metal oxide, carbon/conducting polymer, metal oxide/metal oxide, metal oxide/conducting polymer, conducting polymer/conducting polymer, and even more complex ternary core-shell nanoparticles. The preparation strategies, electrochemical performances, and structural stabilities of core-shell materials for ECs are summarized. The relationship between core-shell nanostructure and electrochemical performance is discussed in detail. In addition, the challenges and new trends in core-shell nanomaterials development have also been proposed.

Shell model Monte Carlo methods

International Nuclear Information System (INIS)

Koonin, S.E.; Dean, D.J.; Langanke, K.

1997-01-01

We review quantum Monte Carlo methods for dealing with large shell model problems. These methods reduce the imaginary-time many-body evolution operator to a coherent superposition of one-body evolutions in fluctuating one-body fields; the resultant path integral is evaluated stochastically. We first discuss the motivation, formalism, and implementation of such Shell Model Monte Carlo (SMMC) methods. There then follows a sampler of results and insights obtained from a number of applications. These include the ground state and thermal properties of pf-shell nuclei, the thermal and rotational behavior of rare-earth and γ-soft nuclei, and the calculation of double beta-decay matrix elements. Finally, prospects for further progress in such calculations are discussed. (orig.)

Fast neutron scattering near shell closures: Scandium

International Nuclear Information System (INIS)

Smith, A.B.; Guenther, P.T.

1992-08-01

Neutron differential elastic- and inelastic-scattering cross sections are measured from ∼ 1.5 to 10 MeV with sufficient detail to define the energy-averaged behavior of the scattering processes. Neutrons corresponding to excitations of 465 ± 23, 737 ± 20, 1017 ± 34, 1251 ± 20, 1432 ± 23 and 1692 ± 25 keV are observed. It is shown that the observables, including the absorption cross section, are reasonably described with a conventional optical-statistical model having energy-dependent geometric parameters. These energy dependencies are alleviated when the model is extended to include the contributions of the dispersion relationship. The model parameters are conventional, with no indication of anomalous behavior of the neutron interaction with 45 Sc, five nucleons from the doubly closed shell at 40 Ca

Computed tomographic evaluation of dinosar egg shell integrity

International Nuclear Information System (INIS)

Jones, J.C.; Greenberg, W.; Ayers, S.

1998-01-01

The purpose of this study was to determine whether computed tomography (CT) could be used to identify hatching holes in partially embedded dinosaur eggs. One Faveololithus and two Dendroolithus eggs were examined using a fourth generation CT scanner. The eggs were partially embedded in a fossilized sediment matrix, with the exposed portion of the shell appearing intact. In CT images of all three eggs, the shells appeared hyperdense relative to the matrix. Hatching holes were visible as large gaps in the embedded portion of the shell, with inwardly displaced shell fragments. It was concluded that CT is an effective technique for nondestructively assessing dinosaur egg shell integrity

Method of fabricating nested shells and resulting product

Science.gov (United States)

Henderson, Timothy M.; Kool, Lawrence B.

1982-01-01

A multiple shell structure and a method of manufacturing such structure wherein a hollow glass microsphere is surface treated in an organosilane solution so as to render the shell outer surface hydrophobic. The surface treated glass shell is then suspended in the oil phase of an oil-aqueous phase dispersion. The oil phase includes an organic film-forming monomer, a polymerization initiator and a blowing agent. A polymeric film forms at each phase boundary of the dispersion and is then expanded in a blowing operation so as to form an outer homogeneously integral monocellular substantially spherical thermoplastic shell encapsulating an inner glass shell of lesser diameter.

Electrochemical synthesis of 1D core-shell Si/TiO2 nanotubes for lithium ion batteries

Science.gov (United States)

Kowalski, Damian; Mallet, Jeremy; Thomas, Shibin; Nemaga, Abirdu Woreka; Michel, Jean; Guery, Claude; Molinari, Michael; Morcrette, Mathieu

2017-09-01

Silicon negative electrode for lithium ion battery was designed in the form of self-organized 1D core-shell nanotubes to overcome shortcomings linked to silicon volume expansion upon lithiation/delithiation typically occurring with Si nanoparticles. The negative electrode was formed on TiO2 nanotubes in two step electrochemical synthesis by means of anodizing of titanium and electrodeposition of silicon using ionic liquid electrolytes. Remarkably, it was found that the silicon grows perpendicularly to the z-axis of nanotube and therefore its thickness can be precisely controlled by the charge passed in the electrochemical protocol. Deposited silicon creates a continuous Si network on TiO2 nanotubes without grain boundaries and particle-particle interfaces, defining its electrochemical characteristics under battery testing. In the core-shell system the titania nanotube play a role of volume expansion stabilizer framework holding the nanostructured silicon upon lithiation/delithiation. The nature of Si shell and presence of titania core determine stable performance as negative electrode tested in half cell of CR2032 coin cell battery.

Shell model and spectroscopic factors

International Nuclear Information System (INIS)

Poves, P.

2007-01-01

In these lectures, I introduce the notion of spectroscopic factor in the shell model context. A brief review is given of the present status of the large scale applications of the Interacting Shell Model. The spectroscopic factors and the spectroscopic strength are discussed for nuclei in the vicinity of magic closures and for deformed nuclei. (author)

Optimal designs of mollusk shells from bivalves to snails.

Science.gov (United States)

Okabe, Takuya; Yoshimura, Jin

2017-02-10

Bivalve, ammonite and snail shells are described by a small number of geometrical parameters. Raup noted that the vast majority of theoretically possible shell forms do not occur in nature. The constraint factors that regulate the biased distribution of natural form have long since been an open problem in evolution. The problem of whether natural shell form is a result of optimization remains unsolved despite previous attempts. Here we solve this problem by considering the scaling exponent of shell thickness as a morphological parameter. The scaling exponent has a drastic effect on the optimal design of shell shapes. The observed characteristic shapes of natural shells are explained in a unified manner as a result of optimal utilization of shell material resources, while isometric growth in thickness leads to impossibly tight coiling.

Adaptative mixed methods to axisymmetric shells

International Nuclear Information System (INIS)

Malta, S.M.C.; Loula, A.F.D.; Garcia, E.L.M.

1989-09-01

The mixed Petrov-Galerkin method is applied to axisymmetric shells with uniform and non uniform meshes. Numerical experiments with a cylindrical shell showed a significant improvement in convergence and accuracy with adaptive meshes. (A.C.A.S.) [pt

Inner shell ionization accompanying nuclear collisions

International Nuclear Information System (INIS)

Sujkowski, Z.

1987-01-01

Selected phenomena leading to inner shell ionization and being of relevance for nuclear physics are discussed. The selection emphasizes the K-shell ionization induced in head-on collisions by fast light and medium-heavy ions. Cross-sections are reviewed. Effects of multiple inner shell ionization on the K X-ray spectra are illustrated with recent results. Implications for nuclear experiments are noted. Use of atomic observables as clocks for proton induced nuclear reactions is reviewed. Prospects for H.I. reactions are discussed. Preliminary experimental results on the direct K-shell ionization accompanying H.I. fusion reactions are presented. The post-collisional K-shell ionization due to internal conversion of γ-rays is discussed as the dominating contribution to the ionization for residues of dissipative nuclear reactions with Z > 40. Systematics of the corresponding K X-ray multiplicities are presented for rotational nuclei. These multiplicity values can be used for determining cross-sections for e.g. incomplete fusion reactions. Examples of such applications are given. Also discussed is the use of target K X-rays for normalization purposes and of the post-collisional, residue K X-rays in the studies of high spin phenomena. 96 references, 35 figures, 3 tables

Process to make core-shell structured nanoparticles

Science.gov (United States)

Luhrs, Claudia; Phillips, Jonathan; Richard, Monique N

2014-01-07

Disclosed is a process for making a composite material that contains core-shell structured nanoparticles. The process includes providing a precursor in the form of a powder a liquid and/or a vapor of a liquid that contains a core material and a shell material, and suspending the precursor in an aerosol gas to produce an aerosol containing the precursor. In addition, the process includes providing a plasma that has a hot zone and passing the aerosol through the hot zone of the plasma. As the aerosol passes through the hot zone of the plasma, at least part of the core material and at least part of the shell material in the aerosol is vaporized. Vapor that contains the core material and the shell material that has been vaporized is removed from the hot zone of the plasma and allowed to condense into core-shell structured nanoparticles.

Ballistic resistant article, semi-finished product for and method of making a shell for a ballistic resistant article

NARCIS (Netherlands)

Harings, Jules Armand Wilhelmina; Janse, Gerardus Hubertus Anna

2013-01-01

The invention relates to a ballistic resistant article, such as a helmet (1), comprising a double curved shell in turn comprising a stack (5) of layers (6) of an oriented anti-ballistic material, the layers comprising one or more plies and having a plurality of cuts (7), the ends of which define a

Red-emitting LaOF:Eu{sup 3+} phosphors: Synthesis, structure and their Judd–Ofelt analysis for LED applications

Energy Technology Data Exchange (ETDEWEB)

Dhananjaya, N., E-mail: ndhananjayas@gmail.com [Department of Physics, B. M. S. Institute of Technology and Management, Bangalore 560064 (India); Shivakumara, C.; Saraf, Rohit [Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560012 (India); Nagabhushana, H. [C. N. R. Rao Center for Advanced Materials, Tumkur University, Tumkur 572103 (India)

2016-03-15

Highlights: • Red-emitting LaOF:Eu{sup 3+} phosphors were synthesized via facile solid state route. • Judd–Ofelt intensity parameters and radiative properties were determined from PL data. • CIE color coordinates of LaOF:Eu{sup 3+} phosphor is close to the commercial red phosphors. • Eu{sup 3+}-activated LaOF phosphor is a potential candidate for the production of red component in white LEDs. - Abstract: In the present study, we have synthesized a series of La{sub 1−x}Eu{sub x}OF (0.01 ≤ x ≤ 0.09) phosphors by the conventional solid-state reaction route at relatively low temperature (500 °C) and shorter duration of 2 h. The compounds were crystallized in the rhombohedral structure with the space group R-3m (No. 166). Upon UV excitation (254 nm), the photoluminescence spectra exhibit characteristic luminescence {sup 5}D{sub 0} → {sup 7}F{sub J} (J = 1, 2, 3, and 4) intra-4f shell Eu{sup 3+} ion transitions. An intense red emission peak at 610 nm was observed due to electric dipole ({sup 5}D{sub 0} → {sup 7}F{sub 2}) transition. Judd–Ofelt theory was employed to evaluate various radiative parameters such as radiative emission rates, lifetime, branching and asymmetry ratios. CIE color coordinates confirmed the red emission of the phosphors. The luminescent results reveal that LaOF:Eu{sup 3+} phosphor can be used as potential candidate for developing red component in white LED applications.

Bending stresses in Facetted Glass Shells

DEFF Research Database (Denmark)

Bagger, Anne; Jönsson, Jeppe; Almegaard, Henrik

2008-01-01

A shell structure of glass combines a highly effective structural principle with a material of optimal permeability to light. A facetted shell structure has a piecewise plane geometry, and together the facets form an approximation to a curved surface. A distributed load on a plane-based facetted...... structure will locally cause bending moments in the loaded facets. The bending stresses are dependent on the stiffness of the joints. Approximate solutions are developed to estimate the magnitude of the bending stresses. A FE-model of a facetted glass shell structure is used to validate the expressions...

Amplitude structure of off-shell processes

International Nuclear Information System (INIS)

Fearing, H.W.; Goldstein, G.R.; Moravcsik, M.J.

1984-01-01

The structure of M matrices, or scattering amplitudes, and of potentials for off-shell processes is discussed with the objective of determining how one can obtain information on off-shell amplitudes of a process in terms of the physical observables of a larger process in which the first process is embedded. The procedure found is inevitably model dependent, but within a particular model for embedding, a determination of the physically measurable amplitudes of the larger process is able to yield a determination of the off-shell amplitudes of the embedded process

Type I Shell Galaxies as a Test of Gravity Models

Energy Technology Data Exchange (ETDEWEB)

Vakili, Hajar; Rahvar, Sohrab [Department of Physics, Sharif University of Technology, P.O. Box 11365-9161, Tehran (Iran, Islamic Republic of); Kroupa, Pavel, E-mail: vakili@physics.sharif.edu [Helmholtz-Institut für Strahlen-und Kernphysik, Universität Bonn, Nussallee 14-16, D-53115 Bonn (Germany)

2017-10-10

Shell galaxies are understood to form through the collision of a dwarf galaxy with an elliptical galaxy. Shell structures and kinematics have been noted to be independent tools to measure the gravitational potential of the shell galaxies. We compare theoretically the formation of shells in Type I shell galaxies in different gravity theories in this work because this is so far missing in the literature. We include Newtonian plus dark halo gravity, and two non-Newtonian gravity models, MOG and MOND, in identical initial systems. We investigate the effect of dynamical friction, which by slowing down the dwarf galaxy in the dark halo models limits the range of shell radii to low values. Under the same initial conditions, shells appear on a shorter timescale and over a smaller range of distances in the presence of dark matter than in the corresponding non-Newtonian gravity models. If galaxies are embedded in a dark matter halo, then the merging time may be too rapid to allow multi-generation shell formation as required by observed systems because of the large dynamical friction effect. Starting from the same initial state, the observation of small bright shells in the dark halo model should be accompanied by large faint ones, while for the case of MOG, the next shell generation patterns iterate with a specific time delay. The first shell generation pattern shows a degeneracy with the age of the shells and in different theories, but the relative distance of the shells and the shell expansion velocity can break this degeneracy.

Fossil shell emission in dying radio loud AGNs

Science.gov (United States)

Kino, M.; Ito, H.; Kawakatu, N.; Orienti, M.; Nagai, H.; Wajima, K.; Itoh, R.

2016-02-01

We investigate shell emission associated with dying radio loud AGNs. First, based on our recent work by Ito et al. (2015), we describe the dynamical and spectral evolution of shells after stopping the jet energy injection. We find that the shell emission overwhelms that of the radio lobes soon after stopping the jet energy injection because fresh electrons are continuously supplied into the shell via the forward shock, while the radio lobes rapidly fade out without jet energy injection. We find that such fossil shells can be a new class of target sources for SKA telescope. Next, we apply the model to the nearby radio source 3C84. Then, we find that the fossil shell emission in 3C84 is less luminous in the radio band while it is bright in the TeV γ-ray band and can be detectable by CTA. Data from STELLA

Inner-shell excitation of alkali-metal atoms

International Nuclear Information System (INIS)

Tiwary, S.N.

1987-06-01

Inner-shell excitation of alkali-metal atoms, which leads to auto-ionization, is reviewed. The validity of quantum mechanical approximation is analyzed and the importance of exchange and correlation is demonstrated. Basic difficulties in making accurate calculations for inner-shell excitation process are discussed. Suggestions are made for further study of inner-shell process in atoms and ions. (author). 26 refs, 4 figs, 1 tab

Effect of amino acids on red pigments and citrinin production in Monascus ruber.

Science.gov (United States)

Hajjaj, Hassan; François, Jean-Marie; Goma, Gérard; Blanc, Philippe J

2012-03-01

Amino acids were used as sole nitrogen sources to examine their effects on the production of water-soluble red pigments and citrinin by Monascus ruber ATCC 96218 cultivated on chemically defined media. In general, when glycine, tyrosine, arginine, serine, or histidine were used as sole nitrogen sources, they favored the production of red pigments, and restricted the synthesis of the mycotoxin. In contrast, the production of citrinin was enhanced in media supplemented with either glutamate, alanine, or proline. Histidine was found to be the most valuable amino acid as it resulted in the highest production of red pigments and almost completely eliminated the formation of mycotoxin. © 2012 Institute of Food Technologists®

Effect of shell thickness on the exchange bias blocking temperature and coercivity in Co-CoO core-shell nanoparticles

Science.gov (United States)

Thomas, S.; Reethu, K.; Thanveer, T.; Myint, M. T. Z.; Al-Harthi, S. H.

2017-08-01

The exchange bias blocking temperature distribution of naturally oxidized Co-CoO core-shell nanoparticles exhibits two distinct signatures. These are associated with the existence of two magnetic entities which are responsible for the temperature dependence of an exchange bias field. One is from the CoO grains which undergo thermally activated magnetization reversal. The other is from the disordered spins at the Co-CoO interface which exhibits spin-glass-like behavior. We investigated the oxide shell thickness dependence of the exchange bias effect. For particles with a 3 nm thick CoO shell, the predominant contribution to the temperature dependence of exchange bias is the interfacial spin-glass layer. On increasing the shell thickness to 4 nm, the contribution from the spin-glass layer decreases, while upholding the antiferromagnetic grain contribution. For samples with a 4 nm CoO shell, the exchange bias training was minimal. On the other hand, 3 nm samples exhibited both the training effect and a peak in coercivity at an intermediate set temperature Ta. This is explained using a magnetic core-shell model including disordered spins at the interface.

Shell Thickness Dependence of Interparticle Energy Transfer in Core-Shell ZnSe/ZnSe Quantum Dots Doping with Europium

Science.gov (United States)

Liu, Ni; Li, Shuxin; Wang, Caifeng; Li, Jie

2018-04-01

Low-toxic core-shell ZnSe:Eu/ZnS quantum dots (QDs) were prepared through two steps in water solution: nucleation doping and epitaxial shell grown. The structural and morphological characteristics of ZnSe/ZnS:Eu QDs with different shell thickness were explored by transmission electron microscopy (TEM) and X-ray diffraction (XRD) results. The characteristic photoluminescence (PL) intensity of Eu ions was enhanced whereas that of band-edge luminescence and defect-related luminescence of ZnSe QDs was decreased with increasing shell thickness. The transformation of PL intensity revealed an efficient energy transfer process between ZnSe and Eu. The PL intensity ratio of Eu ions ( I 613) to ZnSe QDs ( I B ) under different shell thickness was systemically analyzed by PL spectra and time-resolved PL spectra. The obtained results were in agreement with the theory analysis results by the kinetic theory of energy transfer, revealing that energy was transmitted in the form of dipole-electric dipole interaction. This particular method of adjusting luminous via changing the shell thickness can provide valuable insights towards the fundamental understanding and application of QDs in the field of optoelectronics.

Active constrained layer damping treatments for shell structures: a deep-shell theory, some intuitive results, and an energy analysis

Science.gov (United States)

Shen, I. Y.

1997-02-01

This paper studies vibration control of a shell structure through use of an active constrained layer (ACL) damping treatment. A deep-shell theory that assumes arbitrary Lamé parameters 0964-1726/6/1/011/img1 and 0964-1726/6/1/011/img2 is first developed. Application of Hamilton's principle leads to the governing Love equations, the charge equation of electrostatics, and the associated boundary conditions. The Love equations and boundary conditions imply that the control action of the ACL for shell treatments consists of two components: free-end boundary actuation and membrane actuation. The free-end boundary actuation is identical to that of beam and plate ACL treatments, while the membrane actuation is unique to shell treatments as a result of the curvatures of the shells. In particular, the membrane actuation may reinforce or counteract the boundary actuation, depending on the location of the ACL treatment. Finally, an energy analysis is developed to determine the proper control law that guarantees the stability of ACL shell treatments. Moreover, the energy analysis results in a simple rule predicting whether or not the membrane actuation reinforces the boundary actuation.

Java Application Shell: A Framework for Piecing Together Java Applications

Science.gov (United States)

Miller, Philip; Powers, Edward I. (Technical Monitor)

2001-01-01

This session describes the architecture of Java Application Shell (JAS), a Swing-based framework for developing interactive Java applications. Java Application Shell is being developed by Commerce One, Inc. for NASA Goddard Space Flight Center Code 588. The purpose of JAS is to provide a framework for the development of Java applications, providing features that enable the development process to be more efficient, consistent and flexible. Fundamentally, JAS is based upon an architecture where an application is considered a collection of 'plugins'. In turn, a plug-in is a collection of Swing actions defined using XML and packaged in a jar file. Plug-ins may be local to the host platform or remotely-accessible through HTTP. Local and remote plugins are automatically discovered by JAS upon application startup; plugins may also be loaded dynamically without having to re-start the application. Using Extensible Markup Language (XML) to define actions, as opposed to hardcoding them in application logic, allows easier customization of application-specific operations by separating application logic from presentation. Through XML, a developer defines an action that may appear on any number of menus, toolbars, and buttons. Actions maintain and propagate enable/disable states and specify icons, tool-tips, titles, etc. Furthermore, JAS allows actions to be implemented using various scripting languages through the use of IBM's Bean Scripting Framework. Scripted action implementation is seamless to the end-user. In addition to action implementation, scripts may be used for application and unit-level testing. In the case of application-level testing, JAS has hooks to assist a script in simulating end-user input. JAS also provides property and user preference management, JavaHelp, Undo/Redo, Multi-Document Interface, Single-Document Interface, printing, and logging. Finally, Jini technology has also been included into the framework by means of a Jini services browser and the

From Bash to Z shell in 5 min

CERN Multimedia

CERN. Geneva

2015-01-01

Chances are you're spending a good amount of your time working on a shell. While Bash is the standard shell on Linux, some alternatives exist. I'll show you how to switch to one of them (Z shell) and what benefits come with it.

Super-paramagnetic core-shell material with tunable magnetic behavior by regulating electron transfer efficiency and structure stability of the shell

Directory of Open Access Journals (Sweden)

Wenyan Zhang

Full Text Available In this work, a spherical nano core-shell material was constructed by encapsulating Fe3O4 microsphere into conductive polymer-metal composite shell. The Fe3O4 microspheres were fabricated by assembling large amounts of Fe3O4 nano-crystals, which endowed the microspheres with super-paramagnetic property and high saturation magnetization. The polymer-metal composite shell was constructed by inserting Pt nano-particles (NPs into the conductive polymer polypyrrole (PPy. As size and dispersion of the Pt NPs has an important influence on their surface area and surface energy, it was effective to enlarge the interface area between PPy and Pt NPs, enhance the electron transfer efficiency of PPy/Pt composite shell, and reinforced the shell’s structural stability just by tuning the size and dispersion of Pt NPs. Moreover, core-shell structure of the materials made it convenient to investigate the PPy/Pt shell’s shielding effect on the Fe3O4 core’s magnetic response to external magnetic fields. It was found that the saturation magnetization of Fe3O4/PPy/Pt core-shell material could be reduced by 20.5% by regulating the conductivity of the PPy/Pt shell. Keywords: Super-paramagnetic, Conductivity, Magnetic shielding, Structural stability

Shell Trumpets from Western Mexico

Directory of Open Access Journals (Sweden)

Robert Novella

1991-11-01

Full Text Available Marine shells have been used as musical instruments in almost all parts of the world (Izikowitz 1935, including Mesoamerica, where large univalves, also called conch shells in the literature, had a utilitarian function as trumpets. Their use is well documented in most cultural areas of Mesoamerica, as in Western Mexico, through their various occurrences in archaeological contexts and museums collections.

Thick-shell nanocrystal quantum dots

Science.gov (United States)

Hollingsworth, Jennifer A [Los Alamos, NM; Chen, Yongfen [Eugene, OR; Klimov, Victor I [Los Alamos, NM; Htoon, Han [Los Alamos, NM; Vela, Javier [Los Alamos, NM

2011-05-03

Colloidal nanocrystal quantum dots comprising an inner core having an average diameter of at least 1.5 nm and an outer shell, where said outer shell comprises multiple monolayers, wherein at least 30% of the quantum dots have an on-time fraction of 0.80 or greater under continuous excitation conditions for a period of time of at least 10 minutes.

P-shell hyperon binding energies

International Nuclear Information System (INIS)

Koetsier, D.; Amos, K.

1991-01-01

A shell model for lambda hypernuclei has been used to determine the binding energy of the hyperon in nuclei throughout the p shell. Conventional (Cohen and Kurath) potential energies for nucleon-nucleon interactions were used with hyperon-nucleon interactions taken from Nijmegen one boson exchange potentials. The hyperon binding energies calculated from these potentials compare well with measured values. 7 refs., 2 figs

A facile approach for cupric ion detection in aqueous media using polyethyleneimine/PMMA core-shell fluorescent nanoparticles

International Nuclear Information System (INIS)

Chen Jian; Zeng Fang; Wu Shuizhu; Su Junhua; Zhao Jianqing; Tong Zhen

2009-01-01

A facile approach was developed to produce a dye-doped core-shell nanoparticle chemosensor for detecting Cu 2+ in aqueous media. The core-shell nanoparticle sensor was prepared by a one-step emulsifier-free polymerization, followed by the doping of the fluorescent dye Nile red (9-diethylamino- 5H-benzo[alpha] phenoxazine-5-one, NR) into the particles. For the nanoparticles, the hydrophilic polyethyleneimine (PEI) chain segments serve as the shell and the hydrophobic polymethyl methacrylate (PMMA) constitutes the core of the nanoparticles. The non-toxic and biocompatible PEI chain segments on the nanoparticle surface exhibit a high affinity for Cu 2+ ions in aqueous media, and the quenching of the NR fluorescence is observed upon binding of Cu 2+ ions. This makes the core-shell nanoparticle system a water-dispersible chemosensor for Cu 2+ ion detection. The quenching of fluorescence arises through intraparticle energy transfer (FRET) from the dye in the hydrophobic PMMA core to the Cu 2+ /PEI complexes on the nanoparticle surface. The energy transfer efficiency for PEI/PMMA particles with different diameters was determined, and it is found that the smaller nanoparticle sample exhibits higher quenching efficiency, and the limit for Cu 2+ detection is 1 μM for a nanoparticle sample with a diameter of ∼30 nm. The response of the fluorescent nanoparticle towards different metal ions was investigated and the nanoparticle chemosensor displays high selectivity and antidisturbance for the Cu 2+ ion among the metal ions examined (Na + , K + , Mg 2+ , Ca 2+ , Zn 2+ , Hg 2+ , Mn 2+ , Fe 2+ , Ni 2+ , Co 2+ and Pb 2+ ). This emulsifier-free, biocompatible and sensitive fluorescent nanoparticle sensor may find applications in cupric ion detection in the biological and environmental areas.

A facile approach for cupric ion detection in aqueous media using polyethyleneimine/PMMA core-shell fluorescent nanoparticles.

Science.gov (United States)

Chen, Jian; Zeng, Fang; Wu, Shuizhu; Su, Junhua; Zhao, Jianqing; Tong, Zhen

2009-09-09

A facile approach was developed to produce a dye-doped core-shell nanoparticle chemosensor for detecting Cu(2+) in aqueous media. The core-shell nanoparticle sensor was prepared by a one-step emulsifier-free polymerization, followed by the doping of the fluorescent dye Nile red (9-diethylamino- 5H-benzo[alpha] phenoxazine-5-one, NR) into the particles. For the nanoparticles, the hydrophilic polyethyleneimine (PEI) chain segments serve as the shell and the hydrophobic polymethyl methacrylate (PMMA) constitutes the core of the nanoparticles. The non-toxic and biocompatible PEI chain segments on the nanoparticle surface exhibit a high affinity for Cu(2+) ions in aqueous media, and the quenching of the NR fluorescence is observed upon binding of Cu(2+) ions. This makes the core-shell nanoparticle system a water-dispersible chemosensor for Cu(2+) ion detection. The quenching of fluorescence arises through intraparticle energy transfer (FRET) from the dye in the hydrophobic PMMA core to the Cu(2+)/PEI complexes on the nanoparticle surface. The energy transfer efficiency for PEI/PMMA particles with different diameters was determined, and it is found that the smaller nanoparticle sample exhibits higher quenching efficiency, and the limit for Cu(2+) detection is 1 microM for a nanoparticle sample with a diameter of approximately 30 nm. The response of the fluorescent nanoparticle towards different metal ions was investigated and the nanoparticle chemosensor displays high selectivity and antidisturbance for the Cu(2+) ion among the metal ions examined (Na(+), K(+), Mg(2+), Ca(2+), Zn(2+), Hg(2+), Mn(2+), Fe(2+), Ni(2+), Co(2+) and Pb(2+)). This emulsifier-free, biocompatible and sensitive fluorescent nanoparticle sensor may find applications in cupric ion detection in the biological and environmental areas.

A facile approach for cupric ion detection in aqueous media using polyethyleneimine/PMMA core-shell fluorescent nanoparticles

Science.gov (United States)

Chen, Jian; Zeng, Fang; Wu, Shuizhu; Su, Junhua; Zhao, Jianqing; Tong, Zhen

2009-09-01

A facile approach was developed to produce a dye-doped core-shell nanoparticle chemosensor for detecting Cu2+ in aqueous media. The core-shell nanoparticle sensor was prepared by a one-step emulsifier-free polymerization, followed by the doping of the fluorescent dye Nile red (9-diethylamino- 5H-benzo[alpha] phenoxazine-5-one, NR) into the particles. For the nanoparticles, the hydrophilic polyethyleneimine (PEI) chain segments serve as the shell and the hydrophobic polymethyl methacrylate (PMMA) constitutes the core of the nanoparticles. The non-toxic and biocompatible PEI chain segments on the nanoparticle surface exhibit a high affinity for Cu2+ ions in aqueous media, and the quenching of the NR fluorescence is observed upon binding of Cu2+ ions. This makes the core-shell nanoparticle system a water-dispersible chemosensor for Cu2+ ion detection. The quenching of fluorescence arises through intraparticle energy transfer (FRET) from the dye in the hydrophobic PMMA core to the Cu2+/PEI complexes on the nanoparticle surface. The energy transfer efficiency for PEI/PMMA particles with different diameters was determined, and it is found that the smaller nanoparticle sample exhibits higher quenching efficiency, and the limit for Cu2+ detection is 1 µM for a nanoparticle sample with a diameter of ~30 nm. The response of the fluorescent nanoparticle towards different metal ions was investigated and the nanoparticle chemosensor displays high selectivity and antidisturbance for the Cu2+ ion among the metal ions examined (Na+, K+, Mg2+, Ca2+, Zn2+, Hg2+, Mn2+, Fe2+, Ni2+, Co2+ and Pb2+). This emulsifier-free, biocompatible and sensitive fluorescent nanoparticle sensor may find applications in cupric ion detection in the biological and environmental areas.

SHELL DISEASES AND TOXINS REGULATED BY LAW

Directory of Open Access Journals (Sweden)

Natalija Topić Popović

1999-06-01

Full Text Available There is a long tradition of cultivating shells in Croatia, and the shell industry has a good perspective of further development. Since shells are delicate organisms that require special breeding conditions and climate, they are also subject to many diseases. Bonamiosis, haplospioridiosis, marteiliosis, microcytosis and perkinsosis are stated by the International Bureau for Epizootics as shell diseases that, in keeping with law, must be reported, and iridovirosis as a disease of a potential international importance. The same diseases are regulated by the Veterinary Law from 1997 as infectious diseases prevention of which is of an interest for the Republic of Croatia. Although, according to the law, it does not have to be prevented, in this article the disease Mytilicola is also described. According to the Health Department Statute from 1994, eatable part of shells are being tested for toxins of some marine dinoflagelates that can damage human health, and these are PSP (Paralytic Shellfish Poison, DSP (Diarrhoeic Shellfish Poison and NSP (Neuroparalytic Shellfish Poison.

Vibrations of thin piezoelectric shallow shells: Two-dimensional ...

Indian Academy of Sciences (India)

R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

In this paper we consider the eigenvalue problem for piezoelectric shallow shells and we show that, as the thickness of the shell goes to zero, the eigensolutions of the three-dimensional piezoelectric shells converge to the eigensolutions of a two- dimensional eigenvalue problem. Keywords. Vibrations; piezoelectricity ...

Microsoft Hyper-V PowerShell automation

CERN Document Server

Menon, Vinith

2015-01-01

This book is great for administrators who are new to automating Hyper-V administration tasks using PowerShell. If you are familiar with the PowerShell command line and have some experience with the Windows Server, this book is perfect for you.

Acoustic coupling of two parallel shells in compressible fluid

International Nuclear Information System (INIS)

Gerges, S.N.Y.

1982-01-01

Modifications are done in the acoustic impedance for a vibrating shell, due to the pressure of another similar shell. The multi-analysis method of scattering is used. The results of the impedance in function of the shell radius, the wave length, the distance between the shell axis and its vibration models are presented. (E.G.) [pt

Inquiring into Red/Red Inquiring

Directory of Open Access Journals (Sweden)

Ken Gale

2013-05-01

Full Text Available This layered account of an inquiry into ‘red’ emerged out of a collective biography workshop. In the middle of the Wiltshire countryside, an international and interdisciplinary group of scholars gathered together to write and make other things and marks on paper that asked questions of, and into, the spaces between words, people, things and their environments. We did not set out to workshop or write into or paint ‘red’ but, rather, it was red that slipped in, uninvited, and painted and wrote us. Red arose as a blush or a stain seeping amongst us that became referenced obliquely by material objects, metaphors and fairytales. The stain spread, became noticeable through our weekend together and beyond it, creating another (bright red artery vein of connection to write with.

Semiclassical shell structure and nuclear double-humped fission barriers

Directory of Open Access Journals (Sweden)

A. G. Magner

2010-09-01

Full Text Available We derived the semiclassical trace formulas for the level density as sums over periodic-orbit families and isolated orbits within the improved stationary phase method. Averaged level-density shell corrections and shell-structure energies are continuous through all symmetry-breaking (bifurcation points with the correct asymptotics of the standard stationary phase approach accounting for continuous symmetries. We found enhancement of the nuclear shell structure near bifurcations in the superdeformed region. Our semiclassical results for the averaged level densities with the gross-shell and more thin-shell structures and the energy shell corrections for critical deformations are in good agreement with the quantum calculations for several single-particle Hamiltonians, in particular for the potentials with a sharp spheroidal shape. Enhancement of the shell structure owing to bifurcations of the shortest 3-dimensional orbits from equatorial orbits is responsible for the second well of fission barrier in a superdeformation region.

Plasma-column instabilities in a reversed-field pinch without a shell

Energy Technology Data Exchange (ETDEWEB)

Schmid, P.G.

1988-01-01

Plasma column instabilities in a Reversed Field Pinch (RFP) without a shell were investigated in the Colorado Reversatron RFP. The Reversatron RFP (aspect ration R/a = 50 cm/8cm) is a toroidal plasma containment device consisting of a vacuum chamber, a thick conducting shell, modular shells, magnetic field producing coils and diagnostics to characterize the plasma. RFP discharges were set up in the Reversatron in three different experimental configurations: with a thick conducting shell, with a modular shell and with no shell. In two of the configurations, a shell enclosed the plasma column to provide some plasma stability. A vertical magnetic field provided equilibrium in experiments without a shell. Data from discharges without a shell indicated that the plasma duration was greatly reduced and the plasma resistance increased compared to the discharges with a thick shell. Plasma position probes indicated large plasma centriod displacements corresponding to a n = 1 and a n = 3 kink coincident with the peak of the plasma current and the start of a discharge termination phase. The modular shell lengthened the discharge duration and lowered the plasma resistance to values intermediate between the plasma with a thick shell and the plasma with no shell. The modular shell suppressed the large plasma column displacements observed in the RFP plasma without a shell.

Plasma-column instabilities in a reversed-field pinch without a shell

International Nuclear Information System (INIS)

Schmid, P.G.

1988-01-01

Plasma column instabilities in a Reversed Field Pinch (RFP) without a shell were investigated in the Colorado Reversatron RFP. The Reversatron RFP (aspect ration R/a = 50 cm/8cm) is a toroidal plasma containment device consisting of a vacuum chamber, a thick conducting shell, modular shells, magnetic field producing coils and diagnostics to characterize the plasma. RFP discharges were set up in the Reversatron in three different experimental configurations: with a thick conducting shell, with a modular shell and with no shell. In two of the configurations, a shell enclosed the plasma column to provide some plasma stability. A vertical magnetic field provided equilibrium in experiments without a shell. Data from discharges without a shell indicated that the plasma duration was greatly reduced and the plasma resistance increased compared to the discharges with a thick shell. Plasma position probes indicated large plasma centriod displacements corresponding to a n = 1 and a n = 3 kink coincident with the peak of the plasma current and the start of a discharge termination phase. The modular shell lengthened the discharge duration and lowered the plasma resistance to values intermediate between the plasma with a thick shell and the plasma with no shell. The modular shell suppressed the large plasma column displacements observed in the RFP plasma without a shell

Clustering of 1p-shell nuclei in the framework of the shell model

International Nuclear Information System (INIS)

Kwasniewicz, E.

1991-01-01

The two- and three-fragment clustering of the 1p-shell nuclei has been studied in the framework of the shell model. The absolute probabilities of the required types of clustering in a given nucleus have been obtained by projecting its realistic shell-model wavefunction onto the suitable subspace of the orthonormal, completely antisymmetric two- or three-cluster states. With the aid of these data the selectivity in population of final states produced in multinucleon transfer reactions has been discussed. This problem has also been considered in the approach where the exchange of nucleons between clusters has been neglected. This has enabled to demonstrate the role of the complete antisymmetrization in predicting the intensities of states populated in multinucleon transfer reactions. The compact theory of the multinucleon one- and two-cluster spectroscopic amplitudes has been formulated. The examples of studying the nuclear structure and reactions with the aid of these spectroscopic amplitudes have been presented. (author)

Shell-like structures advanced theories and applications

CERN Document Server

Eremeyev, Victor

2017-01-01

The book presents mathematical and mechanical aspects of the theory of plates and shells, applications in civil, aero-space and mechanical engineering, as well in other areas. The focus relates to the following problems: • comprehensive review of the most popular theories of plates and shells, • relations between three-dimensional theories and two-dimensional ones, • presentation of recently developed new refined plates and shells theories (for example, the micropolar theory or gradient-type theories), • modeling of coupled effects in shells and plates related to electromagnetic and temperature fields, phase transitions, diffusion, etc., • applications in modeling of non-classical objects like, for example, nanostructures, • presentation of actual numerical tools based on the finite element approach.

Shell energy scenarios to 2050

International Nuclear Information System (INIS)

2008-01-01

Shell developed two scenarios that describe alternative ways the energy future may develop. In the first scenario (Scramble) policymakers pay little attention to more efficient energy use until supplies are tight. Likewise, greenhouse gas emissions are not seriously addressed until there are major climate shocks. In the second scenario (Blueprints) growing local actions begin to address the challenges of economic development, energy security and environmental pollution. A price is applied to a critical mass of emissions giving a huge stimulus to the development of clean energy technologies, such as carbon dioxide capture and storage, and energy efficiency measures. The result is far lower carbon dioxide emissions. Both these scenarios can help Shell to test their strategy against a range of possible developments over the long-term. However, according to Shell, the Blueprints' outcomes offer the best hope for a sustainable future, whether or not they arise exactly in the way described. However, with the right combination of policy, technology and commitment from governments, industry and society globally, Shell believes it can be realized. But achieving the targets will not be easy, and time is short. Clear thinking, huge investment, and effective leadership are required

Triggered Snap-Through of Bistable Shells

Science.gov (United States)

Cai, Yijie; Huang, Shicheng; Trase, Ian; Hu, Nan; Chen, Zi

Elastic bistable shells are common structures in nature and engineering, such as the lobes of the Venus flytrap or the surface of a toy jumping poppers. Despite their ubiquity, the parameters that control the bistability of such structures are not well understood. In this study, we explore how the geometrical features of radially symmetric elastic shells affect the shape and potential energy of a shell's stable states, and how to tune certain parameters in order to generate a snap-through transition from a convex semi-stable state to concave stable state. We fabricated a series of elastic shells with varying geometric parameters out of silicone rubber and measured the resulting potential energy in the semi-stable state. Finite element simulations were also conducted in order to determine the deformation and stress in the shells during snap-through. It was found that the energy of the semi-stable state is controlled by only two geometric parameters and a dimensionless ratio. We also noted two distinct transitions during snap-through, one between monostability and semi-bistability (the state a popper toy is in before it snaps-through and jumps), and a second transition between semi-bistability and true bistability. This work shows that it is possible to use a set of simple parameters to tailor the energy landscape of an elastic shell in order to generate complex trigger motions for their potential use in smart applications. Z.C. acknowledge support from Society in Science-Branco Weiss Fellowship, administered by ETH Zurich.

Diversity and Ecological Correlates of Red Fluorescence in Marine Fishes

Directory of Open Access Journals (Sweden)

Nils Anthes

2016-11-01

Full Text Available Marine environments at depths below -10 to -25 m are almost devoid of ambient red sunlight because water quickly attenuates long wavelengths. This stenospectral light environment presents unique opportunities for organisms that can transform ambient blue-green light into red light by fluorescence. Numerous marine fish species display intricate patterns of fluorescence. Because color vision is a key component of fish sensory ecology, several putative visual functions of red fluorescence have been proposed but are difficult to test experimentally. Here, we follow a comparative approach to assess the consistency between the phylogenetic distribution of red fluorescence with its presumed functions. We collected and analyzed the largest data set of red fluorescence in fishes to date, consisting of confirmed cases in 272 primarily diurnal fish species from 49 out of 90 surveyed fish families and 12 out of 21 surveyed fish orders, contrasted to 393 fish species with confirmed absence of red fluorescence. Based on a priori hypotheses on adaptive function, we compare the prevalence of red fluorescence among pre-defined sets of species based on ecological or biological characteristics while controlling for shared ancestry. When comparing between species, we find no evidence that red fluorescence is more prevalent in deep-water species, contrasting with our recent finding that fluorescence brightness increases with depth within species. There is also no evidence for a role in group-driven communication. Phylogenetic patterns are consistent, however, with three other predictions. First, fluorescence with a rather patchy distribution across the body occurred significantly more often among sit-and-wait predators or otherwise sedentary fish than in more mobile species, consistent with background matching for camouflage. Second, small, predatory fishes tended to show red fluorescent irides disproportionally often consistent with a proposed function in prey

Climatology of sea breezes along the Red Sea coast of Saudi Arabia

KAUST Repository

Khan, Basit

2018-04-25

Long-term near-surface observations from five coastal stations, high-resolution model data from Modern Era Retrospective-Analysis for Research and Applications (MERRA) and high-resolution daily sea surface temperature (SST) from National Ocean and Atmospheric Administration (NOAA) are used to investigate the climatology of sea breezes over the eastern side of the Red Sea region. Results show existence of separate sea breeze systems along different segments of the Red Sea coastline. Based on the physical character and synoptic influences, sea breezes in the Red Sea are broadly divided into three regions: the north and the middle Red Sea (NMRS), the Red Sea convergence zone (RSCZ) and the southern Red Sea (SRS) regions. On average, sea breezes developed on 67% of days of the 10-year study period. Although sea breezes occur almost all year, this mesoscale phenomenon is most frequent from May to October (78% of the total sea breeze days). The sea breeze frequency increases from north to south (equatorwards), and sea breeze characteristics appear to vary both temporally and spatially. In addition to land-sea thermal differential, coastline shape, latitude and topography, the prevailing northwesterly at NMRS region, the convergence of northwesterly and southeasterly wind system at RSCZ region and the northeast and southwest monsoon at SRS region play an important role in defining the sea breeze characteristics over the Red Sea.

Systematic study of shell effect near drip-lines

International Nuclear Information System (INIS)

Adhikari, S.; Samanta, C.

2004-01-01

The variation of nuclear shell effects with nucleon numbers is evaluated using the modified Bethe–Weizsaecker mass formula (BWM) and the measured atomic masses. The shell effects at magic neutron numbers N=8, 20, 28, 50, 82 and 126 and magic proton numbers Z=8, 20, 28, 50 and 82 are found to vary rapidly approaching the drip-lines. The shell effect due to one magic number increases on approaching another magic number. Thus, shell effects are not always negligible near the drip-lines. (author)

Inner-shell couplings in transiently formed superheavy quasimolecules

Energy Technology Data Exchange (ETDEWEB)

Verma, P [Kalindi College, University of Delhi, New Delhi 110008 (India); Mokler, P H [Max-Planck-Institut fuer Kernphysik, 69117 Heidelberg (Germany); Braeuning-Demian, A; Kozhuharov, C; Braeuning, H; Bosch, F; Hagmann, S; Liesen, D [GSI Helmholzzentrum fuer Schwerionenforschung, 64291 Darmstadt (Germany); Anton, J; Fricke, B [Universitaet Kassel, 34109 Kassel (Germany); Stachura, Z [Institute for Nuclear Physics, Cracow PL 31342 (Poland); Wahab, M A, E-mail: p.verma.du@gmail.com [Jamia Millia Islamia, Jamia Nagar, New Delhi 110025 (India)

2011-06-15

The inner-shell couplings for U{sup q+}-ions (73{<=}q{<=}91) moving moderately slow at {approx}69 MeV u{sup -1} and bombarding thin Au targets have been investigated. Having established the definite survival probability of incoming projectile K vacancies in these targets in an earlier publication, the transfer of these vacancies to the target K-shell due to inner-shell couplings has been studied. As the system is in the quasiadiabatic collision regime for the K-shell of collision partners, advanced SCF-DFS (self-consistent field-Dirac-Fock-Slater) multielectron level diagrams have been used for interpretation. Using a simple model, the L-K shell coupling interaction distance has been estimated and compared with level diagram calculations.

Isospin invariant boson models for fp-shell nuclei

International Nuclear Information System (INIS)

Van Isacker, P.

1994-01-01

Isospin invariant boson models, IBM-3 and IBM-4, applicable in nuclei with neutrons and protons in the same valence shell, are reviewed. Some basic results related to these models are discussed: the mapping onto the shell model, the relation to Wigner's supermultiplet scheme, the boson-number and isospin dependence of parameters, etc. These results are examined for simple single-j shell situations (e.g. f 7/2 ) and their extension to the f p shell is investigated. Other extensions discussed here concern the treatment of odd-mass nuclei and the classification of particle-hole excitations in light nuclei. The possibility of a pseudo-SU(4) supermultiplet scheme in f p -shell nuclei is discussed. (author) 4 figs., 3 tabs., 23 refs

Optical Bistability in Graded Core-Shell Granular Composites

International Nuclear Information System (INIS)

Wu Ya-Min; Chen Guo-Qing; Xue Si-Zhong; Zhu Zhuo-Wei; Ma Chao-Qun

2012-01-01

The intrinsic optical bistability (OB) of graded core-shell granular composites is investigated. The coated particles are made of cores with gradient dielectric function in c (r) = A(r/a) k and nonlinear shells. In view of the exponential distribution of the core dielectric constant, the potential functions of each region are obtained by solving the Maxwell equations, and the mathematical expressions of electric field in the shells and cores are determined. Numerical study reveals that the optical bistable threshold and the threshold width of the composite medium are dependent on the shell thickness, core dielectric exponent, and power function coefficient. The optical bistable width increases with the decreasing shell thickness and the power exponent and with the increasing power function coefficient

Preparation of tetrapod-like ZnO/TiO{sub 2} core-shell nanostructures as photocatalytic powder

Energy Technology Data Exchange (ETDEWEB)

Sartori, A.; Visentin, F.; De Zorzi, C.; Natali, M.; Gerbasi, R.; Rossetto, G. [ICIS-DPM-CNR, Padova (Italy); El Habra, N. [ICIS-DPM-CNR, Padova (Italy); Dipartimento di Scienze Chimiche, Padova (Italy); Garoli, D. [Dipartimento di Fisica, Padova (Italy); LANN, Padova (Italy); Casarin, M. [Dipartimento di Scienze Chimiche, Padova (Italy)

2011-08-15

The coupling of zinc oxide tetrapods (t-ZnO) with anatase TiO{sub 2} in the form of CVD coatings on ZnO nanotetrapods was investigated. t-ZnO/TiO{sub 2} core-shell structures, consisting of uniformly and completely TiO{sub 2} covered ZnO nanotetrapods, were characterized by scanning electron microscopy, X-ray diffraction and UV-Vis spectra. Photocatalytic activity, determined by degradation of a sodium methyl red solution, was found to be comparable to pure t-ZnO, while improved separation easiness was verified that makes the presented powders promising for wastewater treatment. (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Axisymmetric vibrations of thin shells of revolution

International Nuclear Information System (INIS)

Suzuki, Katsuyoshi; Kikuchi, Norio; Kosawada, Tadashi; Takahashi, Shin

1983-01-01

The problem of free vibration of axisymmetric shells of revolution is important in connection with the design of pressure vessels, chemical equipment, aircrafts, structures and so on. In this study, the axisymmetrical vibration of a thin shell of revolution having a constant curvature in meridian direction was analyzed by thin shell theory. First, the Lagrangian during one period of the vibration of a shell of revolution was determined by the primary approximate theory of Love, and the vibration equations and boundary conditions were derived from its stopping condition. The vibration equations were strictly analyzed by using the series solution. The basic equations for the strain and strain energy of a shell were based on those of Novozhilov. As the examples of numerical calculation, the natural frequency and vibration mode of the symmetrical shells of revolution fixed at both ends and supported at both ends were determined, and their characteristics were clarified. The theory and the numerical calculation ore described. Especially in the frequency curves, the waving phenomena were observed frequently, which were not seen in non-axisymmetric vibration, accordingly also the vibration mode changed in complex state on the frequency curves of same order. The numerical calculation was carried out in the large computer center in Tohoku University. (Kako, I.)

Microsoft Exchange Server PowerShell cookbook

CERN Document Server

Andersson, Jonas

2015-01-01

This book is for messaging professionals who want to build real-world scripts with Windows PowerShell 5 and the Exchange Management Shell. If you are a network or systems administrator responsible for managing and maintaining Exchange Server 2013, you will find this highly useful.

INTERNAL ROTATION OF THE RED-GIANT STAR KIC 4448777 BY MEANS OF ASTEROSEISMIC INVERSION

Energy Technology Data Exchange (ETDEWEB)

Di Mauro, M. P.; Cardini, D. [INAF, IAPS Istituto di Astrofisica e Planetologia Spaziali, Roma (Italy); Ventura, R.; Paternò, L. [INAF, Astrophysical Observatory of Catania, Catania (Italy); Stello, D. [Sydney Institute for Astronomy, School of Physics, University of Sydney (Australia); Christensen-Dalsgaard, J.; Hekker, S. [Stellar Astrophysics Centre, Department of Physics and Astronomy, Aarhus University, Ny Munkegade 120, DK-8000 Aarhus C (Denmark); Dziembowski, W. A. [Warsaw University Observatory, Al. Ujazdowskie 4, 00-478 Warsaw (Poland); Beck, P. G.; De Smedt, K.; Tkachenko, A. [Instituut voor Sterrenkunde, Katholieke Universiteit Leuven (Belgium); Bloemen, S. [Department of Astrophysics, IMAPP, Radboud University Nijmegen, P.O. Box 9010, NL-6500 GL, Nijmegen (Netherlands); Davies, G. R.; Garcia, R. A. [Laboratoire AIM, CEA/DSM-CNRS-Univ. Paris Diderot, IRFU/Sap, Centre de Saclay, F-91191 Gif-sur-Yvette Cedex (France); Elsworth, Y. [School of Physics and Astronomy, University of Birmingham (United Kingdom); Mosser, B. [LESIA, PSL Research University, CNRS, Universitè Pierre et Marie Curie, Université Denis Diderot, Observatoire de Paris, Meudon Cedex (France)

2016-01-20

We study the dynamics of the stellar interior of the early red-giant star KIC 4448777 by asteroseismic inversion of 14 splittings of the dipole mixed modes obtained from Kepler observations. In order to overcome the complexity of the oscillation pattern typical of red-giant stars, we present a procedure to extract the rotational splittings from the power spectrum. We find not only that the core rotates from a minimum of 8 to a maximum of 17 times faster than the surface, confirming previous inversion results generated for other red giants (Deheuvels et al.), but we also estimate the variation of the angular velocity within the helium core with a spatial resolution of 0.001R and verify the hypothesis of a sharp discontinuity in the inner stellar rotation. The results show that the entire core rotates rigidly and provide evidence for an angular velocity gradient around the base of the hydrogen-burning shell; however, we do not succeed in characterizing the rotational slope, due to the intrinsic limits of the applied techniques. The angular velocity, from the edge of the core, appears to decrease with increasing distance from the center, reaching an average value in the convective envelope of 68 ± 22 nHz. We conclude that a set of data that includes only dipolar modes is sufficient to infer quite accurately the rotation of a red giant not only in the dense core but also, with a lower level of confidence, in part of the radiative region and in the convective envelope.

Fast synthesis, formation mechanism, and control of shell thickness of CuS–polystyrene core–shell microspheres

International Nuclear Information System (INIS)

Zhao, Li-min; Shao, Xin; Yin, Yi-bin; Li, Wen-zhi

2012-01-01

Graphical abstract: Core–shell structure PSt/CuS were prepared using polystyrene which were modified by 3-methacryloxypropyltrimethoxysilane as template. The coating thickness of CuS can be controlled by the amount of 3-methacryloxypropyltrimethoxysilane and the UV–vis absorption intensity of PSt/CuS composite also changed with the coating thickness of CuS. Highlights: ► Core–shell structure PSt/CuS were prepared using silanol-modified polystyrene microspheres as template. ► The coating thickness of core–shell structure PSt/CuS can be controlled by a simple method. ► The UV–vis absorption intensity of PSt/CuS composite also changed with the coating thickness of CuS. -- Abstract: The silanol-modified polystyrene microspheres were prepared through dispersion polymerization. Then copper sulfide particles were grown on silanol-modified polystyrene through sonochemical deposition in an aqueous bath containing copper acetate and sulfide, released through the hydrolysis of thioacetamide. The resulting particles were continuous and uniform as characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Fourier transform infrared, thermogravimetric analysis and UV–vis absorption spectroscopy were used to characterize the structure and properties of core–shell particles. The results showed the coating thickness of CuS shell can be controlled by the amount of silanol and the UV–vis absorption intensity of PSt/CuS composite also changed with the coating thickness of CuS.

Strontium and fluorine in tuatua shells

International Nuclear Information System (INIS)

Trompetter, W.J.; Coote, G.E.

1993-01-01

This report describes the research to date on the elemental distributions of strontium, calcium, and fluorine in a collection of 24 tuatua shells (courtesy of National Museum). Variations in elemental concentrations were measured in the shell cross-sections using a scanning proton microprobe (PIXE and PIGME). In this paper we report the findings to date, and present 2-D measurement scans as illustrative grey-scale pictures. Our results support the hypothesis that increased strontium concentrations are deposited in the shells during spawning, and that fluorine concentration is proportional to growth rate. (author). 15 refs.; 13 figs.; 1 appendix

Unconstrained off-shell N=3 supersymmetric Yang-Mills theory

International Nuclear Information System (INIS)

Galperin, A.; Ivanov, E.; Kalitzin, S.; Ogievetsky, V.; Sokatchev, E.

1984-01-01

The harmonic superspace is used to build up an unconstrained off-shell formulation of N=3 supersymmetric Yang-Mills theory. The theory is defined in an analytic N=3 superspace having M 4 x(SU(3)/U(1)xU(1) as an even part. The basic objects are the analytic potentials which serve as gauge connections entering harmonic derivatives. The action is an integral over analytic superspace. The Lagrange density is surprisingly simple and it is gauge invariant up to total harmonic derivative. The equations of motion are integrability conditions on the internal space SU(3)/U(1)xU(1). The jumping over the ''N=3 barrier'' became possible due to the infinite number of auxiliary fields

The effectiveness of a standardized rose hip powder, containing seeds and Shells of Rosa canina, on cell longevity, skin wrinkles, moisture, and elasticity 

DEFF Research Database (Denmark)

Phetcharat, L; Wongsuphasawat, K; Winther, Kaj

2015-01-01

Objective: To evaluate the effects of a rose hip powder (Hyben Vital®) made from seeds and shells on cell senescence, skin wrinkling, and aging. Methods: A total of 34 healthy subjects, aged 35–65 years, with wrinkles on the face (crow’s-feet) were subjected to a randomized and double-blinded cli...... hip product on cell membranes of stored erythrocyte cells observed in this study may contribute to improve the cell longevity and obstructing skin aging. Keywords: rose hip seed and shell powder, cell longevity, wrinkles, aging skin, moisture, elasticity......Objective: To evaluate the effects of a rose hip powder (Hyben Vital®) made from seeds and shells on cell senescence, skin wrinkling, and aging. Methods: A total of 34 healthy subjects, aged 35–65 years, with wrinkles on the face (crow’s-feet) were subjected to a randomized and double...... longevity was measured in terms of leakage of hemoglobin through red cell membranes (hemolytic index) in blood samples kept in a blood bank for 5 weeks. Significance of all values was attained with P#0.05. Results: In the double-blinded study, the rose hip group showed statistically significant improvements...

Insights from the Shell Proteome: Biomineralization to Adaptation.

Science.gov (United States)

Arivalagan, Jaison; Yarra, Tejaswi; Marie, Benjamin; Sleight, Victoria A; Duvernois-Berthet, Evelyne; Clark, Melody S; Marie, Arul; Berland, Sophie

2017-01-01

Bivalves have evolved a range of complex shell forming mechanisms that are reflected by their incredible diversity in shell mineralogy and microstructures. A suite of proteins exported to the shell matrix space plays a significant role in controlling these features, in addition to underpinning some of the physical properties of the shell itself. Although, there is a general consensus that a minimum basic protein tool kit is required for shell construction, to date, this remains undefined. In this study, the shell matrix proteins (SMPs) of four highly divergent bivalves (The Pacific oyster, Crassostrea gigas; the blue mussel, Mytilus edulis; the clam, Mya truncata, and the king scallop, Pecten maximus) were analyzed in an identical fashion using proteomics pipeline. This enabled us to identify the critical elements of a "basic tool kit" for calcification processes, which were conserved across the taxa irrespective of the shell morphology and arrangement of the crystal surfaces. In addition, protein domains controlling the crystal layers specific to aragonite and calcite were also identified. Intriguingly, a significant number of the identified SMPs contained domains related to immune functions. These were often are unique to each species implying their involvement not only in immunity, but also environmental adaptation. This suggests that the SMPs are selectively exported in a complex mix to endow the shell with both mechanical protection and biochemical defense. © The Author 2016. Published by Oxford University Press on behalf of the Society for Molecular Biology and Evolution.

Quality Index Method developed for gutted and ungutted red tilapia (Oreochromis ssp

Directory of Open Access Journals (Sweden)

Nelson Gutiérrez G.

2015-01-01

Full Text Available Objective. To develop a Quality Index Method (QIM for gutted and ungutted red tilapia from aquaculture ponds. Materials and methods. 40 specimens of gutted red tilapia and 40 ungutted ones were located in foam polyethylene boxes within layers of ice and storage at 4°C. Three fish were randomly sampled on days 0, 3, 5, 8, 11, 14 and 17 for gutted tilapia, and on days 0, 3, 6, 9, 11, 14 and 16 for ungutted tilapia. A sensorial panel of 8 experts was formed to evaluate the product. With three samples each day with average points of the sensorial attributes proposed in the method, the quality index for gutted and ungutted red tilapia was obtained based on the storage time on ice. Results. The Quality Index Method obtained for gutted and ungutted red tilapia showed maximum values of 21 and 29, respectively. It was adjusted in an increasing lineal model with high correlation between the Quality Index and the storage time on ice. Conclusions. The developed model is useful to determine deterioration levels and to define storage and consumption time. For gutted red tilapia the panel rejected the fish after 8 - 11 days of storage whereas the ungutted red tilapia was rejected after 6 - 9 days.

Effect of supercritical water shell on cavitation bubble dynamics

International Nuclear Information System (INIS)

Shao Wei-Hang; Chen Wei-Zhong

2015-01-01

Based on reported experimental data, a new model for single cavitation bubble dynamics is proposed considering a supercritical water (SCW) shell surrounding the bubble. Theoretical investigations show that the SCW shell apparently slows down the oscillation of the bubble and cools the gas temperature inside the collapsing bubble. Furthermore, the model is simplified to a Rayleigh–Plesset-like equation for a thin SCW shell. The dependence of the bubble dynamics on the thickness and density of the SCW shell is studied. The results show the bubble dynamics depends on the thickness but is insensitive to the density of the SCW shell. The thicker the SCW shell is, the smaller are the wall velocity and the gas temperature in the bubble. In the authors’ opinion, the SCW shell works as a buffering agent. In collapsing, it is compressed to absorb a good deal of the work transformed into the bubble internal energy during bubble collapse so that it weakens the bubble oscillations. (paper)

Accidental degeneracy in photonic bands and topological phase transitions in two-dimensional core-shell dielectric photonic crystals.

Science.gov (United States)

Xu, Lin; Wang, Hai-Xiao; Xu, Ya-Dong; Chen, Huan-Yang; Jiang, Jian-Hua

2016-08-08

A simple core-shell two-dimensional photonic crystal is studied where the triangular lattice symmetry and the C6 point group symmetry give rich physics in accidental touching points of photonic bands. We systematically evaluate different types of accidental nodal points at the Brillouin zone center for transverse-magnetic harmonic modes when the geometry and permittivity of the core-shell material are continuously tuned. The accidental nodal points can have different dispersions and topological properties (i.e., Berry phases). These accidental nodal points can be the critical states lying between a topological phase and a normal phase of the photonic crystal. They are thus very important for the study of topological photonic states. We show that, without breaking time-reversal symmetry, by tuning the geometry of the core-shell material, a phase transition into the photonic quantum spin Hall insulator can be achieved. Here the "spin" is defined as the orbital angular momentum of a photon. We study the topological phase transition as well as the properties of the edge and bulk states and their application potentials in optics.

Artificially evolved functional shell morphology of burrowing bivalves

DEFF Research Database (Denmark)

Germann, D. P.; Schatz, W.; Hotz, Peter Eggenberger

2014-01-01

The morphological evolution of bivalves is documented by a rich fossil record. It is believed that the shell shape and surface sculpture play an important role for the burrowing performance of endobenthic species. While detailed morphometric studies of bivalve shells have been done...... dimensional (3D) objects, the first ever artificial evolution of a physical bivalve shell was performed. The result was a vertically flattened shell occupying only the top sediment layers. Insufficient control of the sediment was the major limitation of the setup and restricted the significance of the results...

Box-like gel capsules from heterostructures based on a core-shell MOF as a template of crystal crosslinking.

Science.gov (United States)

Ishiwata, Takumi; Michibata, Ayano; Kokado, Kenta; Ferlay, Sylvie; Hosseini, Mir Wais; Sada, Kazuki

2018-02-06

New polymer capsules (PCs) were obtained using a crystal crosslinking (CC) method on core-shell MOF crystals. The latter are based on the epitaxial growth of two isostructural coordination polymers which are then selectively crosslinked. Decomposition of the non-reticulated phase leads to new PCs, possessing a well-defined hollow cubic shape reflecting the heterostructure of the template.

Scanning the parameter space of collapsing rotating thin shells

Science.gov (United States)

Rocha, Jorge V.; Santarelli, Raphael

2018-06-01

We present results of a comprehensive study of collapsing and bouncing thin shells with rotation, framing it in the context of the weak cosmic censorship conjecture. The analysis is based on a formalism developed specifically for higher odd dimensions that is able to describe the dynamics of collapsing rotating shells exactly. We analyse and classify a plethora of shell trajectories in asymptotically flat spacetimes. The parameters varied include the shell’s mass and angular momentum, its radial velocity at infinity, the (linear) equation-of-state parameter and the spacetime dimensionality. We find that plunges of rotating shells into black holes never produce naked singularities, as long as the matter shell obeys the weak energy condition, and so respects cosmic censorship. This applies to collapses of dust shells starting from rest or with a finite velocity at infinity. Not even shells with a negative isotropic pressure component (i.e. tension) lead to the formation of naked singularities, as long as the weak energy condition is satisfied. Endowing the shells with a positive isotropic pressure component allows for the existence of bouncing trajectories satisfying the dominant energy condition and fully contained outside rotating black holes. Otherwise any turning point occurs always inside the horizon. These results are based on strong numerical evidence from scans of numerous sections in the large parameter space available to these collapsing shells. The generalisation of the radial equation of motion to a polytropic equation-of-state for the matter shell is also included in an appendix.

Coulomb ionization of inner shells by heavy charged particles

International Nuclear Information System (INIS)

Lapicki, G.

1975-01-01

The theory of inner-shell Coulomb ionization by heavy charged particles, of atomic number small compared to the target atomic number, is developed through the extension of work by Brandt and his coworkers for K shells to L shells. In slow collisions relative to the characteristic times of the inner shell electrons, the quantum-mechanical predictions in the plane-wave Born approximation (PWBA) can exceed experimental cross sections by orders of magnitude. The effects of the perturbation of the atom by and the Coulomb deflection of the particle during collisions are included in the theory. The perturbed atomic states amount to a binding of the inner-shell electrons to the moving particle in slow collisions, and to a polarization of the inner shells by the particle passing at large impact parameters during nonadiabatic collisions. These effects, not contained in the PWBA, are treated in the framework of the perturbed stationary state (PSS) theory for slow collisions and in terms of the harmonic oscillator model of Ashley, Brandt, and Ritchie for stopping powers in fast collisions. The effect of the Coulomb deflection of the particle in the field of the target nucleus on the cross sections is incorporated in the semiclassical approximation of Bang and Hansteen. Except for the lightest target atoms, the contribution of electron capture by the particles to inner-shell ionizations is shown to be negligible. The theory as developed earlier for the K shell, and here for L shells, agrees well with the vast body of experimental data on inner-shell Coulomb ionization by heavy charged particles

Note on off-shell relations in nonlinear sigma model

International Nuclear Information System (INIS)

Chen, Gang; Du, Yi-Jian; Li, Shuyi; Liu, Hanqing

2015-01-01

In this note, we investigate relations between tree-level off-shell currents in nonlinear sigma model. Under Cayley parametrization, all odd-point currents vanish. We propose and prove a generalized U(1) identity for even-point currents. The off-shell U(1) identity given in http://dx.doi.org/10.1007/JHEP01(2014)061 is a special case of the generalized identity studied in this note. The on-shell limit of this identity is equivalent with the on-shell KK relation. Thus this relation provides the full off-shell correspondence of tree-level KK relation in nonlinear sigma model.

Shell Scripting Expert Recipes for Linux, Bash and more

CERN Document Server

Parker, Steve

2011-01-01

A compendium of shell scripting recipes that can immediately be used, adjusted, and applied The shell is the primary way of communicating with the Unix and Linux systems, providing a direct way to program by automating simple-to-intermediate tasks. With this book, Linux expert Steve Parker shares a collection of shell scripting recipes that can be used as is or easily modified for a variety of environments or situations. The book covers shell programming, with a focus on Linux and the Bash shell; it provides credible, real-world relevance, as well as providing the flexible tools to get started

Dispersion of axially symmetric waves in fluid-filled cylindrical shells

DEFF Research Database (Denmark)

Bao, X.L.; Überall, H.; Raju, P. K.

2000-01-01

Acoustic waves normally incident on an elastic cylindrical shell can cause the excitation of circumferential elastic waves on the shell. These shells may be empty and fluid immersed, or fluid filled in an ambient medium of air, or doubly fluid loaded inside and out. Circumferential waves...... on such shells have been investigated for the case of aluminum shells, and their phase-velocity dispersion curves have been obtained for double fluid loading [Bao, Raju, and Überall, J. Acoust. Soc. Am. 105, 2704 (1999)]. Similar results were obtained for empty or fluid-filled brass shells [Kumar, Acustica 27......, 317 (1972)]. We have extended the work of Kumar to the case of fluid-filled aluminum shells and steel shells imbedded in air. These cases demonstrate the existence of circumferential waves traveling in the filler fluid, exhibiting a certain simplicity of the dispersion curves of these waves...

Integrable structure in discrete shell membrane theory.

Science.gov (United States)

Schief, W K

2014-05-08

We present natural discrete analogues of two integrable classes of shell membranes. By construction, these discrete shell membranes are in equilibrium with respect to suitably chosen internal stresses and external forces. The integrability of the underlying equilibrium equations is proved by relating the geometry of the discrete shell membranes to discrete O surface theory. We establish connections with generalized barycentric coordinates and nine-point centres and identify a discrete version of the classical Gauss equation of surface theory.

Ancient shell industry at Bet Dwarka island

Digital Repository Service at National Institute of Oceanography (India)

Gaur, A.S.; Sundaresh; Patankar, V.

for the manufacture of beads, bangles, etc. 12 . Shell species found at the sites include T. pyrum (cha nk), Chicoreus ramosus , Fasciolaria trapezium , Cypraea (cowries), Arabica arabica (cowries), Babylonia spirata , dentalium, mussel and Arca... muscles are attached. Average length of a shell can be up to 15 to 20 cm and width 10 ? 15 cm 8 . It provides a unique structure for the manufacture of several bangles from a single shell. The organ ism living inside is also edible...

Static quadrupole moments of first 2+ states in the 2s1d shell: a review of experiment and theory

International Nuclear Information System (INIS)

Spear, R.H.

1981-01-01

Available experimental information on the static electric quadrupole moments Q 2 + of the 2 + first excited states of even-mass nuclei in the 2s-1d shell is tabulated and critically reviewed, and adopted values are presented. The results reveal a well defined pattern for the variation of Q 2 + through the shell. Predictions of Q 2 + made from various nuclear models are tabulated and compared with experiment. For each nucleus the quantity and quality of the existing data for Q 2 + , together with the current theoretical significance of the result, are used as criteria to determine whether new experimental work is desirable

Isogeometric shell formulation based on a classical shell model

KAUST Repository

Niemi, Antti; Collier, Nathan; Dalcí n, Lisandro D.; Ghommem, Mehdi; Calo, Victor M.

2012-01-01

The authors future work is concerned with building an isogeometric finite element method for modelling nonlinear structural response of thin-walled shells undergoing large rigid-body motions. The aim is to use the model in a aeroelastic framework for the simulation of flapping wings.

Coulomb energy of uniformly charged spheroidal shell systems.

Science.gov (United States)

Jadhao, Vikram; Yao, Zhenwei; Thomas, Creighton K; de la Cruz, Monica Olvera

2015-03-01

We provide exact expressions for the electrostatic energy of uniformly charged prolate and oblate spheroidal shells. We find that uniformly charged prolate spheroids of eccentricity greater than 0.9 have lower Coulomb energy than a sphere of the same area. For the volume-constrained case, we find that a sphere has the highest Coulomb energy among all spheroidal shells. Further, we derive the change in the Coulomb energy of a uniformly charged shell due to small, area-conserving perturbations on the spherical shape. Our perturbation calculations show that buckling-type deformations on a sphere can lower the Coulomb energy. Finally, we consider the possibility of counterion condensation on the spheroidal shell surface. We employ a Manning-Oosawa two-state model approximation to evaluate the renormalized charge and analyze the behavior of the equilibrium free energy as a function of the shell's aspect ratio for both area-constrained and volume-constrained cases. Counterion condensation is seen to favor the formation of spheroidal structures over a sphere of equal area for high values of shell volume fractions.

Gradual growth of gold nanoseeds on silica for SiO2-gold homogeneous nano core/shell applications by the chemical reduction method

International Nuclear Information System (INIS)

Rezvani Nikabadi, H; Shahtahmasebi, N; Rezaee Rokn-Abadi, M; Bagheri Mohagheghi, M M; Goharshadi, E K

2013-01-01

In this paper, a facile method for the synthesis of gold nanoseeds on the functionalized surface of silica nanoparticles has been investigated. Mono-dispersed silica particles and gold nanoparticles were prepared by the chemical reduction method. The thickness of the Au shell was well controlled by repeating the reduction time of HAuCl 4 on silica/3-aminopropyltriethoxysilane (APTES)/initial gold nanoparticles. The prepared SiO 2 -gold core/shell nanoparticles were studied using x-ray diffraction, scanning electron microscopy, transmission electron microscopy (TEM), Fourier transform infrared spectroscopy and ultraviolet visible (UV-Vis) spectroscopy. The TEM images indicated that the silica nanoparticles were spherical in shape with 100 nm diameters and functionalizing silica nanoparticles with a layer of bi-functional APTES molecules and tetrakis hydroxy methyl phosphonium chloride. The gold nanoparticles show a narrow size of up to 5 nm and by growing gold nanoseeds over the silica cores a red shift in the maximum absorbance of UV-Vis spectroscopy from 524 to 637 nm was observed.

Vibrational analysis of submerged cylindrical shells based on elastic foundations

International Nuclear Information System (INIS)

Shah, A.G.; Naeem, M.N.

2014-01-01

In this study a vibration analysis was performed of an isotropic cylindrical shell submerged in fluid, resting on Winkler and Pasternak elastic foundations for simply supported boundary condition. Love's thin shell theory was exploited for strain- and curvature- displacement relationship. Shell problem was solved by using wave propagation approach. Influence of fluid and Winkler as well as Pasternak elastic foundations were studied on the natural frequencies of submerged isotropic cylindrical shells. Results were validated by comparing with the existing results in literature. Vibration, Submerged cylindrical shell, Love's thin shell theory, Wave propagation method, Winkler and Pasternak foundations. (author)